# mbe ;fflf[unicipal

**~utboritp**
Members of the Board FRANK BAZZONE DALE R. McCALL REGIS T. MCLAUGHLIN LUETHEL NESBIT NICKOU.S SHERMENTI 

## August 12, 2010 

# of tbt 

# «:itp of :ffitlltte-port 100 Atlantic Avenue 

### McKeesport, PA 15132 

### Office: (412) 673·8276



### Fax: (412) 673-4283 www.mckeesport-macm.org



## Mr. Kevin Halloran, Water Quality Specialist Supervisor Water Management Pennsylvania Department of Environmental Protection 400 Waterfront Drive Pittsburgh, PA 15222-4745 

## Dear Mr. Halloran; Municipal Authority of the City of McKeesport 

## Analysis of Gas Well Wastewaters As Required Under the PA DEP Administrative Order Dated October 23, 2008 Joseph E. Rost Executive Director Phone (412) 673-9701



## Please find enclosed copies ofthe laboratory analyses of fourteen (14) wells owned by Chesapeake Energy for the parameters specified in the Administrative Order. The wells are identified as #627253, #627264, #831608, #627377, and #831881, #627254, #627262, #626748/627005, #831201(pit water), #831201(drill water), #.831600, #832033(pit water), 

## #832033(drill water), #627255, #900557, #831879. The Authority is currently accepting gas well water from three companies, Huntley & 

## Huntley, Chesapeake Energy, and CNX Gas. Wastewaters from new wells accepted by the plant 

## are in the process of being analyzed by Environmental Service Laboratories (ESL) located in Indiana, PA. As the results are received by the Authority copies will be forwarded to your office. If 

## you have any questions, please contact me at (412) 673-9701 ext. 12. Sincerely,

cc: Michael 

## C. Shenieb, 

## KLH Engineers, 

## Inc. Chad 

## Harsh, EPA

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# ;!fmuniripal

**~utboritp**
Members of the Board FRANK BAZZONE DALE R. MCCALL REGIS T. MCLAUGHLIN LUETHEL NESBIT NICKOLAS J. SHERMENTI



### August 12, 2010

Mr. Chad Harsh NPDES Enforcement Branch Water Protection Division 

# of tbe QCitp 

# of

**;iflllc11\.re~port** 100 Atlantic Avenue McKeesport, PA 15132 Office: (412) 673-8276

Fax: (412) 673-4283 www.mck-macm.org



### U.S. Environmental Protection Division 1650 Arch Street Philadelphia, PA 19103 Dear Mr. Harsh: Joseph E. Rost Executive Director Phone (412) 673-9701



### As requested in your letter dated February 19, 2009, enclosed is a copy of the Authority's latest submittal to the Pennsylvania Department of Environmental Protection in response to its order issued October 23, 3008. This Order was issued relative to the gas well water that the Authority has received for treatment. If you have any questions, please contact me at (412) 673-9701 x12. Sincerely,

EnclosuresTbaCityofMcKeespOrt100AtlanticA11enueMcKeesport,Pennsylvania15132IIETVRNADDRESS,FOLDATOOTlE)--------CEiitiFiEii..------lfl/lll/1/lll/IIIll1/lll/llllllll/1111POST4LSERVICE111/lllllllllli/111l-7002203Q00028073348519103Ava1_--:>?o,0l£t\ft\1l\\E&aftlf.QUi.Sl£.9tv\V.C\f\M\-W-6\\NPDf£\A.S.\\oSDWMS\-vcc+.U.S.POSTAGEPAIDMCKEESPO."!T.PAAUG13.'10AMOUNT$10.4500039237-1I'PRIORITY®114PRIORITY"'fWlfi!PRIORITY'"l1flfiJMIJIL(I;1i!MIJILl!AJIJlIII..--'Prltl,.,rt!'_.....I...,._.._.........,_.ENVIRONMENTALSERVICELABORATORIES,INC.SAMPLEREQUESTCHAINOFCUSTODYPAGEOFHEADQUARTERS:1803PhiladelphiaSlIndiana,PA15701(724)463-TEST(724)465-4209)0SOUTI-IERNDMSION:1276BentleyvilleRoadVanVoorhis,PA15366(724)258-TEST(724)258-8376FORINTERNALLABORATORYUSEONLYSampleIdentificationESL#4-/-10Date/TimeDate/TomeNOFCUSTODYSEALBROKEN:YesNoDPRr::F_-.'\.,...·-,.._...14oCCONTAINERyMatrix#ofContainersWNWN2WNwwww2wwwwww2WN2Water2NNNN/?,ContainerTypePreservativePlasticLiternone---PlasticLiternone---PlasticLiterHN03PlasticLiterH2SO,PlasticLiterHN03---AmberGlassLHCI-AmberGlassLH2so.AmberVOAVialsnone---AmberVOAHCIRECEIVEDMAY2 42010REGULATORYAnalysisRequestedpH,SC,Choride,Sulfate,OsmoticPressure,Alkalinity,AcidityTSS,TDS,DissolvedIron,Boron,BOD,MBASSurfactantsAI,As,Ba, Be,Cd,Cr,Co, Cu,Fe,Pb,Mg,Mn,Hg,Ni,Se,Ag,Sr,Zn,Li,Na,Ca,HardnessNitrate+Nitrite,TKN,Ammonia,CODGrossAlpha,GrossBetaOil&GreaseTotalPhenolicsEthyleneGlycolBenzene,Toluene:""TiBenzene,TolueneCompany/Name:;.,AppalacLLC.Address:--'901l'PegsylvaniaAvenue//....J·-rtr:!Contact£b:-n.-..t7-..-Phone:ContactPerson:_R_e_ce-iv-ed--B-y:-(-SI-gM-tu_rn_)________Fax:= 

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# =RVICE LABORATORIESI INC. 103 Philadelphia Street Indiana, PA 15 701 

## 24)-463-TEST FAX (724)-465-4209 

## Report of Analysis

1mple Start Date: !ceipt Date: !port Date: Chesapeake Appalachia, LLC 900 Pennsylvania A venue Attn: 

### Mr. Eric Gillespie Charleston, WV 25302 4/1/2010 3:00PM 4/2/2010 I :46 PM 5/18/2010 Analyte Analyst Acidity to pH=8.3 BF Alkalinity to pH=4.5 JML Biological Oxygen Demand 05 

## szc Chemical Oxygen Demand ZTR Ammonia as N 

### I Distilled 

### AID Chloride BF Kjeldahl Nitrogen as N MAD pH (SM) LL Sulfate ASTM ZTR Total Nitrate+ Nitrite as N MAD Aluminum- ICP GJT Arsenic-ICP GJT Barium- ICP GJT Beryllium

- ICP GJT Boron MAD Cadmium- ICP GJT Calcium

- ICP GJT Chromium- ICP GJT Cobalt- ICP GJT Copper- ICP GJT Hardness GJT Analysis Date 04/15/2010 04/12/2010 04/07/2010 04/07/2010 04/19/2010 04/08/2010 04/15/2010 04/05/2010 04/08/2010 04/09/2010 04/22/2010 04/20/2010 04/20/2010 04/19/2010 04/07/2010 04/20/2010 04/20/2010 04/19/2010 04/19/2010 04/19/2010 04/22/2010 Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID:

Sample Result 10 09232 Waste Water Grab CLIENT (Client) 627253 Pit Water

Units Method 

### ND mg/1 as CaC03 SM23IOB 42290 mg/1 as CaC03 SM2320B 588.0 mg/1 SM5210B 6040.0 mg/1 SM5220 D

8.97 mg/1 SM4500NH3B & 

### I 966.3 mg/1 SM4500ClC 71.3 mg/1 SM4500Norg-C,D 8.40 

## su SM 4500H-B 

### ND mg/1 D516-02



## * mg/1 SM4500N03E 38

. 000 mg/1 200.7/6010



### ND mg/1 200.7/6010 3.800 mg/1 200.7/6010 O.Dl8 mg/1 200.7/6010 2.72 mg/1 SM 4500B-B ND mg/1 200.7/6010 14818.000 mg/1 200.7/6010 ND mg/1 200.7/6010 1.402 mg/1 200

. 7/6010 1.006 mg/1 200.7/6010 45050 mg/1 SM2340B 

### RPL 2 20 2.0 2000.0

0.10

1.0 50.9 0.01 25000

0

. 05 1.000 1.000 0.500 0

. 010

1.00 0.500 50.000 0

. 010 0

. 010 0.010 1

>mments: 

### Osmotic Pressure and Nitrate/Nitrite could not be analyzed due to matrix of the sample. 04/09/10 MAD Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 IND=No t Detected

**~ote:** DEP Certification #s 32-00382

1ta Qualifiers : D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits

. R = Sample received out of holding time

. H = Sample analyzed out of holding time

. C = Sample received in incorrect container

. B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. Paoe 1 of 3

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# :RVICE LABORATORIES, INC. :03 Philadelphia Street, Indiana, PA 15701 

## 24)-463-TEST FAX (724)-465-4209 

## Report of Analysis

arne:

mple Start Date: !Ceipt Date: !port Date: Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 411/2010 3:00PM 4/2/201 0 1 : 46 PM 5/18/2010 Analyte Analyst
Iron- ICP GJT Iron,Dissolved- ICP GJT Lead-ICP GJT Lithium

- ICP GJT Magnesium- ICP GJT Manganese

- ICP GJT Mercury DRM Nickel- ICP GJT Selenium-ICP GJT Silver-ICP GJT Sodium- ICP GJT Strontium- ICP GJT Zinc- ICP GJT Osmotic Pressure MAD Detergents, MBAS ZTR Ethylene Glycol MetPeak Oil and Grease

- HEM CLM Phenolics, as Phenol MAD Percent Total Solids DRM Specific Conductance LL Total Dissolved Solids (TDS) LMB Analysis Date 04/19/2010 04/19/2010 04/19/2010 04/20/2010 04/22/2010 04/22/2010 04/15/2010 04/19/2010 04/19/2010 04/19/2010 04/20/2010 04/20/2010 04/19/2010 04/09/2010 04/02/2010 04/09/2010 04/19/2010 04/19/2010 04/07/2010 04/05/2010 04/07/2010 Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID:

Sample Result 7.082



## * 0

. 070 ND 1954.800 168.000

ND 2.364 0.112 ND 1298.200

65.000 5.276 10 09232 Waste Water Grab CLIENT (Client) 627253 Pit Water

Units Method mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 245.1 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 

## * mOs/kg OSP 2.010 mg/1 SM5540C <25.000 mglkg 300.0 M



## ND mg/1 1664A ND mg/1 420

. 1 38 % SM2540B 2358 uS/em SM 2510B 3200 mg/1 SM2540C RPL 0.020 0.010 0.010 50.000 50.000 0.500 0.0200 0.010 0.020 0.010 50.000

1.000 0.010

100 2.000 25.000

5.0 5.000



### 5 I 25

>mments: Osmotic Pressure and Nitrate/Nitrite could not be analyzed due to matrix of the sample. 04/09/10 MAD Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-0040 I I N

D=

Not Dete cted

**~ate:** DEP Certification #s 32-00382

3ta Qualifiers: D =The reported value is from dilution

. E = Estimated value. S = Surrogate out of control limits. R = Sample received out of hold i ng time

. H = Sample ana l yzed out of holding time

. C = Sample received in incorrect container. B = Analyte was detected in both sample and methods blank

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## ~RVICE **LABORATORIES~** 

# INC. 103 Philadelphia Street Indiana, PA 15701 

## 24)-463-TEST FAX (724)-465-4209 

## Report of Analysis
1me:



### 1m pie Start Date:

**~ceipt** 

### Date:

**~port** 

### Date: Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 4/1/2010 3:00PM 4/2/2010 1:46PM 5/18/2010 Analyte Analyst Total Suspended Solids LMB Radiologicals enchma 

### I) Benzene RO Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID:
Analysis Sample

Date Result 04/07/2010 490400 04/16/2010 

## * 04/07/2010 ND 10 09232 Waste Water Grab CLIENT (Client) 627253 Pit Water

Units Method mg/1 SM2540D mgll RAD-CTDHS ug!L 624/8260B RPL 5 0.000 49

. 00 47) Toluene RO 

# I04/07/2010 

# I ND ug!L 624/8260B 

### j 49.00 ]

Jmments: 

### Osmotic Pressure and Nitrate/Nitrite could not be analyzed due to matrix ofthe sample. 04/09/10 MAD Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401

llote: DEP Certification #s 32-00382

3ta Qualifiers: D =The reported value is from dilution. E = Estimated value

. S = Surrogate out of control limits. jND=Not Detected

R = Sample received ou t of holding time

. H = Sample analyzed out of holding time. C 

## =Sample received in incorrect container

. B = Analyte was detected in both sample and methods blank

. X 

### = User defined data qualifier. Paoe 3 of 3APR-28-2010 11:08 AM

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## 4

# 777 Saucon Creek Road Center Valley, PA 18034-9004 PHONE (610)

**974·8100 ~**  

## FAX (610) 974-8104 SEND DATA TO: NAME: COMPANY: ADDRESS:

PHONE: FAX : Mike Moyer Environmental Service Laboratories, Inc 

### 1803 Philadelphia St Indiana, PA 15701 

### (724) 463w837B (724) ·465-4209 

## TEST REPORT WO#: PAGE: PO#: PWS 10# Work 

## Order: 1 0041 002



### 10041002 1 of 2 DAS0406201 0

RECEIVED FOR LAB BY: MAK DATE: 

### 04/08/2010 9:05 Page 1 of2
SAMPLE: 10 OCJ232 Lab 10: 10041002-DOI'lA arab SAMPLED BY: David A. stiles Sample Time 04/0112010 15:00



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### 6DJJm..:. Groaa Alpha 913.3 :1: S19.8 701.10 pCllkg EPA900.0 04113110 8:45 04/18/10 

### BPS-CV Gross Beta 

### 781.2 t 233.15 87!1.20 pCI/kg EPA900.0 04/13/10 8:45 04/116/10 

### BPS-CV

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REMARKS:

The above test procedure• meet all the requirements of NELAC and relate only to these samples. 

### • CV

.. Benchmark Analytics, Inc. Center Valley, PA; 

### SA= Benchmark 

### Analytlcs, Inc. 

### Sayre, PA



### MANAGER



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# SERVICE LABORATORIES/ INC. 1803 Philadelphia Street, Indiana, PA 15701 

## (724)-463-TEST FAX (724)-465-4209 Report of Analysis
Name:

Sample Start Date: Receipt Date: Report Date:

1) Benzene 47) Toluene Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 4/1/2010 4/2/2010 1:46 PM 5/18/2010 Analyte Analyst 

### RO RO Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID:

Analysis Sample

Date Result 04/07/2010 

### ND 04/07/2010 

### ND 10 09233 Waste Water Grab CLIENT (Client) Trip Blank

Units Method ug/L 624/8260B ug/L 624/8260B 

### RPL 1.00 1.00

:::omments: I ND=Not Detected

DEP Certification #s 32-00382
)ata Qualifiers: D = The reported value is from dilution. E 

### = Estimated value. S = Surrogate out of control limits. R 

## =Sample received out of holding time. H 

## =Sample analyzed out of holding time. C 

## =Sample received in incorrect container. B 

## =Analyte was detected in both sample and methods blank. X 

## = User defined data qualifier. Page 1 of 1ENVIRONMENTAL SERVICE LABORATORIES. INC. SAMPLE REQUEST & CHAIN OF CUSTODY RECEI\!Ed- OF _1_ .

HEADQUARTERS:

1 803 Philadelphia Sl Indiana, PA 15701 (724) 463-TEST (724) 465-4209 , _OUTHERN DMSION:

**76** Bentleyville Road

Y-an Voorhis, PA 15366

(724) 258-TEST D P **F~~ t:~~-**  s t;: f::-\ **\/:\~·.,~r** f <.:.) r 1

(724) 258-8376

FOR INTERNAL LAB ORA TORY USE ONLY TEMP< 4°C COf \1 TAii\JE R

Sample Identification ESL# Matrix # of Containers

TRIP BLANK 1// YP"/Qf?}...-j .......-:: **,~ ,~**  **~** --'

. THESE SERVICE CHARGES WILL ACCRUE AT THE RATE OF 1 112% PER MONTH (18% PER ANNUM OR THE MAXIMUM ALLOWED BY LAW . )

THE UNDERSIGNED PURCHASER AGREES TO PAY, IN THE EVENT HIS ACCOUNT BECOMES DELINQUENT AND IS TURNED OVER TO ANY

FOR COU.ECTION, REASONABLE AITORNEY'S FEES PLUS ALL COURT AND AITENDANT COLLECTION COSTS.

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Water 2 f\J N N i\ I I J' **'~iA** Container Type Preservative Plastic Liter none Plastic Liter none Plastic Liter HN0 3 Plastic Liter H2SO, Plastic Lller HN0 3 Amber Glass L HCI Amber Glass L

H 2 S0 4 Amber VOA Vials none Amber VOA Vials HCI MAY 2 4 2010 REGULATORY Analysis Requested

pH, SC, Choride, Sulfate,

Osmotic Pressure, Alkalinity, Acidity

TSS, TDS, Dissolved Iron,

Boron, BOD, MBAS Surfactants

AI, As, Ba, Be, Cd, Cr, Co, Cu, Fe, Pb, Mg,

Mn, Hg, Ni, Se, Ag, Sr, Zn, Li, Na, Ca. Hardness Nitrate+Nitrite, TKN, Ammonia, COD
Gross Alpha , Gross Bela

Oil & Grease Total Phenolics Ethylene Glycol Benzene, Toluene AmberVOA

**~-- r-**  _ Benzene, Toluene # Appalachia, LLC.

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By : (Signature) Date/ Time (Signature) Date/ Time

OF CUSTODY SEAL BROKEN: Yes No · .

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# ERVICE LABORATORIES/ INC. l03 

## Philadelphia Street Indiana, PA 15701 

## 24)-463-TEST FAX (724)-465-4209 

## Report of Analysis

arne:

1m pie Start Date : eceipt Date: eport Date: Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Cha rleston, WV 25302 4/7/2010 3:15PM 4/9/20 I 0 I :20 PM 5/13/2010 Analyte Analyst Acidity to pH=8.3 BF Alkalinity to pH=4.5 ZTR Biological Oxygen Demand 05 

## szc Chemical Oxygen Demand MAD Ammonia as N 

### I Distilled MAD Chloride LL Kjeldahl Nitrogen as N MAD pH(SM) LL Sulfate ASTM ZTR Total Nitrate +Nitrite as N MAD Aluminum

- ICP GJT Arsenic-ICP GJT Barium- ICP GJT Beryllium- ICP GJT Boron MAD Cadmium- ICP GJT Calcium

- ICP GJT Chromium

- ICP GJT Cobalt- ICP 

# I GJT Copper- ICP GJT Hardness GJT Analysis Date 04/15/2010 04/21120 1 0 04/14/2010 04/14/2010 04/30/2010 04/2112010 04/30/2010 04/13/2010 04/19/2010 05/ll/2010 04/22/2010 04/20/2010 04/20/20 1 0 04/19/2010 04/14/2010 04/20/2010 04/20/2010 04/1912010 04/19/2010 04/19/2010 04/20/2010 Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID:

Sample Result lO 09991 Waste Water Grab CLIENT (Client) 627264 Pit Water

Units Method
ND mg/1 as CaC03 SM2310B 109 mg/1 as CaC03 SM2320B 312

. 0 mg/I SM5210B 886.0 mg/1 SM5220 D 29.42 mg/I )M4500NH3B & [ 12477.1 mg/1 SM4500ClC

12.5 mg/I SM4500Norg-C,D 8.98 

## su SM 4500H-B 220 mg/1 D516-02 ND mg/1 SM4500N03;E 4.500 mg/1 200.7/6010 ND mg/1 200.7/6010 3.700 mg/1 200.7/6010 ND mg/1 200

. 7/6010 ND mg/1 SM 4500B-B ND mg/1 200.7/6010 481.100 mg/1 200.7/6010

ND mg/1 200

. 7/6010 ND mg/1 200.7/6010 ND mg/ 1 200.7/6010 1495 mg/1 SM2340B 

### RPL 2 20 2.0 200.0

1.00 1.0 5.2 

### O.Ql 50 0

. 05 1.000 1.000 0.500 0

. 500 0.25 0.500 50

. 000 0.500 0.500 0.500 1

omments : Dilutions utilized for BOD analysis did NOT meet the laboratories acceptance criteria of at least 2 mg!L DO depletion (loss). Ethylene Glycol subcontracted to Metrohm-Peak Radiologicals done by Benchmark Analytical, PADEP Lab ID : 39-00401 IN D=Not Detected

Note: DEP Certification #s 32-00382

:Jta Qualifiers: D =The reported value is from dilution

. E =Estimated value. S =Surrogate out of control limits. R =Sample received out of hold i ng time

. H = Sample analyzed out of holding time

. C = Sample received in incor rect container. 8 = Analyte was detected in both sample and methods blank

. X= User defined data qualifier. Paae 1 of 3

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# 9.- ERVICE LABORATORIES, INC. 303 Philadelphia Street Indiana, PA 15701 

## '24)-463-TEST FAX (724)-465-4209 

## Report of Analysis

arne:

tmple Start Date: eceipt Date: eport Date: Chesapeake Appalachia, LLC 900 Pellllsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 4/7/2010 3:15PM 4/9/2010 I :20 PM 5/13/2010 Analyte Analyst
Iron- ICP GJT Iron,Dissolved-ICP GJT Lead-ICP GJT Lithium

- ICP GJT Magnesium- ICP GJT Manganese

- ICP GJT Mercury DRM Nickel- ICP GJT Selenium-ICP GJT Silver-ICP GJT Sodium- ICP GJT Strontium

- ICP GJT Zinc- ICP GJT Osmotic Pressure MAD Detergents, MBAS TL Ethylene Glycol MetPeal< Oil and Grease

- HEM CLM Phenolics, as Phenol MAD Specific Conductance LL Total Dissolved Solids (TDS) CLM Total Suspended Solids CLM Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID:
Analysis Sample

Date Result 04/19/2010 4.200 04/19/2010 

### ND 04/19/2010 ND 04/20/2010 

### ND 04119/2010 71.400 04/19/2010 

### ND 04/15/2010 

### ND 04/19/2010 

### ND 04/19/2010 ND 04/19/2010 ND 04/20/2010 7110.900 04/20/2010 16.100 04/19/2010 ND 04/09/2010 652 04/09/2010 3.075 04/19/2010 <25.250 04/23/2010 ND 04/19/2010 ND 04/13/2010 32118 04/14/2010 28000 04/14/2010 8040 10 09991 Waste Water Grab CLIENT (Client) 627264 Pit Water

Units Method mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200

. 7/6010 mg/1 245.1 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mOs/kg OSP

mg/1 SM5540C mg/kg 300.0 M mg/1 1664A mg/1 420.1 uS/em SM 2510B mg/1 SM2540C mg/1 SM2540D RPL 1.000 1.000 0.500 50.000 50.000 0.500 0

.0008 0.500 1.000 0

. 500 50

. 000 1.000 0

. 500

100 1.000 25

.250

5.0 0.500 I 

### 25 5

omments: Dilutions utilized for BOD analysis did NOT meet the laboratories acceptance criteria of at least 2 mg/L DO depletion (loss). Ethylene Glycol subcontracted to Metrohm-Peak Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 IND=Not Detected

• \late : DEP Certification #s 32-00382

3ta Qualifiers: D 

## = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits

. R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B 

## = Analyte was detected in both sample and methods blank. X 

## = User defined data qualifier

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## '24)-463-TEST FAX {724)-465-4209 Report of Analysis

arne:

ample Start Date: eceipt Date: eport Date:

Radiologicals 1) Benzene 47) Toluene Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 4/7/2010 3:15PM 4/9/20 I 0 1 :20 PM 5/13/2010 Analyte Analyst enchma



### RO RO Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID:
Analysis Sample

Date Result 04/18/2010 

## * 04/09/2010 ND 

### 04/09/2010 16.40 10 09991 Waste Water Grab CLIENT (Client) 627264 Pit Water

Units Method mg!l 

### RAD-CTDHS ug/L 624/8260B ug/L 624/8260B 

### RPL 0.000 10.00 10.00



### omments: 

### Dilutions utilized for BOD analysis did NOT meet the laboratories acceptance criteria of at least 2 mg/L DO depletion (loss). Ethylene Glycol subcontracted to Metrohm-Peak Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 IND=Not Detected

"Jote: DEP Certification #s 32-00382

3fa Qualifiers : D 

## = The reported value is from dilution. E 

## = Estimated value. S = Surrogate out of control limits. R = Sample received out of holding time. H 

## = Sample analyzed out of holding time. C 

## = Sample received in incorrect container

. B 

### =Analyte was detected in both sample and methods blank

. X = User defined data qualifier

. Paae 3 of 3

# (n(9af?4t'~ LAB ID: 39-00401

SEND DATA TO: NAME: 

### Mike Moyer 

### BENCHMARK ANAL YTICS, INC. 4777 Saucon Creek Road Center Valley, PA 18034-9004 PHONE (610) 974-8100

FAX (610) 974-8104

COMPANY: Environmental Service Laboratories, Inc ADDRESS: 1803 Philadelphia St

PHONE: FAX: Indiana, PA 15701 

### (724) 463-8378 (724) 465-4209 

### TEST REPORT
. WO#: PAGE: 

### PO#: PWS ID# Work Order: 10041613

10041613 

### 1 of 

### 1 DAS04122010

10 09991, 1010025 RECEIVED FOR LAB BY: MAK DATE: 04/13/2010 8:45 

### Page I ofl
SAMPLE: 10 09991 SAMPLED BY: Client

Test Gross Alpha Gross Beta

REMARKS: Lab 10: 10041613-001A Grab Sample Time 04/0712010 15:15 

### &lil!l1 Uncert. MDA Units 37.98 :t: 52.12 210.10 pCVL 734.5 ± 89.06 187.40 pCi/L Method EPA 900.0 EPA 900.0 MQ!.. Analysis Start Analysis End**~** 04/14110 8:55 04/1B/10 BPS-CV 04114110 8:55 04118/10 BPS-CV

The above test procedures meet all the requirements of NELAC and relate only to these samples. * CV =Benchmark Analytics, Inc. Center Valley, PA; SA= Benchmark Analytics, Inc. Sayre, PA

MANAGER

# --------**--- ~--~** **·~ ~~** **~~ --**  __________________ DATE:

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## 24)-463-TEST FAX (724)-465-4209 

## Report of Analysis
1me:

1m 

### pie Start Date:

**~ceipt** 

### Date:

**~port** 

### Date:



# - I) Benzene

47) 

### Toluene Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 4/7/2010 4/9/2010 1:20 PM 4112/2010 

### Analyte Analyst 

### RO RO Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID:


### Analysis Sample

Date Result 04/09/2010 

### ND 04/09/2010 ND 10 09992 Waste Water Grab CLIENT (Client) Trip 

### Blank

Units Method ug!L 624/8260B 

### ug!L 624/8260B 

### RPL 1.00 1.00

Jmments: I ND=Not Dete c ted

DEP Certification #s 32-00382

1/a Qualifiers: D =The reported value is from dilution

. E = Estimated value

. S = Sur rogate out of control limits. R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B 

## = Analyte was detected in both sample and methods blank. X 

## =User defined data qualifier

. Page 1 of 1ENVIRONMENTAL SERVICE LABORATORIES. INC. HEADQUARTERS: EI SOUl"HERN DIVISION: SAMPLE REQUEST & CHAIN OF CUSTODY RECE!VED- OF -

1603 Philadelphia Sl Indiana, PA 15701 (724) 463-TEST (724) 465-4209 1276 Bentleyville Road
Van Voorhis, PA 15366 (724) 258- TEST (724) 258-6376

FOR INTERNAL LABORATORY USE ONLY D P R **~:.:)** :: R \/'1:-\-r i **e,:;~** i\t

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THE UNDERSIGNED PURCHASER AGREES TO PAY,IN THE EVENT HIS ACCOUNT BECOMES DELINQUENT AND IS TURNED OVER TO ANY

ATIORNEY FOR COLLEC T IOI-I. REASONABLEATIORNEY'S FEES PLUS ALL COURT AND ATIENDANT COLLECTION COSTS .

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Plastic Liter HN0 3 Amber Glass L HCI Amber Glass L H2so. Amber VOA Vials none Amber VOA Vials HCI Amber VOA Vials HCI Phone : Fax: MAY 2 4 2010 REGULATORY Analysis Requested

pH , SC, Choride, Sulfate,

Osmotic Pressure, Alkalinity, Acidity

TSS, TDS. Dissolved Iron,

Boron, BOD, MBAS Surfactants

AI, As, Ba, Be, Cd, Cr, Co, Cu, Fe, Pb, Mg,

Mn, Hg, Ni, Se, Ag, Sr, Zn, li, Na, Ca, Hardness Nitrate+Nitrite, TKN, Ammonia, COD
Gross Alpha, Gross Beta

Oil & Grease Total Phenolics Ethylene Glycol Benzene, Toluene Benzene, Toluen;!

**I~ Ch~ape~t<e**  Appalachia, LLC.

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## '24)-463-TEST FAX (724)-465-4209 Report of Analysis

arne:

ample Start Date: eceipt Date: eport Date: Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: 

### Mr. Eric Gillespie Charleston, WV 25302 4/12/2010 12:00 PM 4/13/2010 4:27PM 5/13/2010 Analyte Analyst Acidity to pH=8.3 BF Alkalinity to pH=4.5 JML 

### Biological Oxygen Demand 05 

## szc Chemical Oxygen Demand MAD Ammonia as N 

### I Distilled ZTR Chloride ZTR Kjeldahl Nitrogen as N MAD pH (SM) LL Sulfate ASTM ZTR Total Nitrate+ Nitrite as N MAD Aluminum

- ICP GJT Arsenic-ICP GJT Barium -ICP GJT Beryllium

- ICP GJT Boron MAD Cadmium- ICP GJT Calcium- ICP GJT Chromium

- ICP GJT Cobalt- ICP GJT Copper- ICP GJT Hardness GJT Analysis Date 04/15/2010 04/22/2010 04/19/2010 04/19/2010 05/12/2010 04/15/2010 04/30/2010 04/14/2010 04/19/2010 05/11/2010 04/27/2010 04/23/2010 04/23/2010 04/27/2010 04/14/2010 04/23/2010 04/27/2010 04/23/2010 04/23/2010 04/23/2010 04/27/2010 Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID:

Sample Result 10 10266 Waste Water Grab CLIENT (Client) 831608 Pit Water

Units Method ND mg/1 as CaC03 SM2310B 2523 mg/1 as CaC03 SM2320B 732.0 mg/1 SM5210B 9270

. 0 mg/1 SM5220 D 34.98 mg/1 SM4500NH3B & 

### I 1869.1 mg/1 SM4500CIC

18.3 mg/1 SM4500Norg-C,D 9.51 

## su SM4500H-B 140 mg/1 D516-02 0.22 mg/1 SM4500N03E 230.350 mg/1 200.7/6010

ND mg/1 200.7/6010 2.550 mg/1 200.7/6010 

### ND mg/1 200.7/6010 0.34 mg/1 SM4500B-B ND mg/1 200.7/6010 1300.050 mg/1 200.7/6010

0.350 mg/1 200.7/6010 ND mg/1 200.7/6010 1.200 mg/1 200.7/6010 4433 mg/1 SM2340B 

### RPL 2 20 2.0 2000

. 0

0.90

1.0 5.1 0.01 50 

### 0.05 0.500 0.500 0.250 0.250 0.25 0.250 25.000 0.250 0.250 0.250 

### I

omments: 

### Ethylene Glycol subcontracted to Metrohm-Peak Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 IND=Not Detected

llote: DEP Certification #s 32-00382

3ta Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect conta)ner. B 

## = Analyte was detected in both sample and methods blank. X 

## = User defined data qualifier. Page 1 of 3

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## 15 701 

## '24)-463-TEST FAX (724)-465-4209

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## Report of Analysis Sample ID#: Sample Type: Sample Source: Sampler: 10 10266 Waste Water Grab 1mple Start Date: eceipt Date: eport Date: Chesapeake Appalachia, LLC 900 Pennsylvania A venue Attn: Mr. 

### Eric Gillespie Charleston, WV 25302 4/12/2010 12:00 PM 4/13/2010 4 :27PM 5/13/2010 Client Sample ID: CLIENT (Client) 831608 Pit Water

Analyte Analyst Analysis Sample 

### Units Method Date Result Iron- ICP GJT 04/23/2010 1406

.050 mg/1 200

. 7/6010 Iron,Dissolved-ICP GJT 04/23/2010 0

. 700 mg/1 200.7/6010 Lead-ICP GJT 04/23/2010 0.550 mg/1 200

. 7/6010 Lithium- ICP GJT 04/23/2010 ND 

### mg/1 200.7/6010 Magnesium-ICP GJT 04/27/2010 288

. 250 mg/1 200.7/6010 Manganese

- ICP GJT 04/23/2010 33

. 700 mg/1 200.7/6010 Mercury DRM 04/15/2010 ND mg/1 245.1 Nickel- ICP GJT 04/23/2010 1.150 mg/1 200.7/6010 Selenium-ICP GJT 04/23/2010 ND 

### mg/1 200.7/6010 Silver-ICP GJT 04/23/2010 ND 

### mg/1 200.7/6010 Sodium- ICP GJT 04/27/2010 1160.400 mg/1 200.7/6010 Strontium

- ICP GJT 04/27/2010 11.700 mg/1 200.7/6010 Zinc- ICP GJT 04/23/2010 2.750 mg/1 200.7/6010 Osmotic Pressure MAD 04/20/2010 109 mOs/kg OSP Detergents, MBAS TL 04/15/2010 5.080 mg/1 SM5540C Ethylene Glycol

**MetPea~** 

### 04/19/2010 <25.000 mg/kg 300.0 M Oil and Grease

- HEM CLM 04/27/2010 7.8 mg/1 1664A Phenolics, as Phenol MAD 04/29/2010 ND mg/1 420.1 Specific Conductance LL 04/ 14/2010 4930 uS/em SM 2510B Total Dissolved Solids (TDS) LMB 2000 mg/1 SM2540C Total Suspended Solids 

# I LMB 

# I04115 /2010 

# I 122900 mg/1 SM2540D 

### RPL 0

. 500 0

. 500 0

.250 25

. 000 25

.000 0

.250 0.0020 0

. 250 0

. 500 0

. 250 25

. 000 0

. 500 0

. 250

100 0.800 25

. 000

5

.0 0.500 I 

### 25 5

omments: 

### Ethylene Glycol subcontracted to Metrohm-Peak Radiologicals done by Benchmark Analytical, PADEP Lab ID : 39-00401 IND=Not Detected

Note: DEP Certification #s 32-00382

g fa Qualifiers : D = The reported value is from dilution

. E 

## = Estimated value

. S 

## = Surrogate out of control limits

. R 

## = Sample received out of holding time. H 

## = Sample analyzed out of holding time. C = Sample received in incorrect container. B 

## = Analyte was detected in both sample and methods blank

. X = User defined data qualifier

. Page 2 of 3

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## 724)-463-TEST FAX (724)-465-4209 

## Report of Analysis
fame:

ample Start Date:

**~eceipt** 

### Date:

**~eport** 

### Date:

Radiologicals 1) Benzene 47) Toluene Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 4/12/2010 12:00 PM 4/13/2010 4:27PM 5/13/2010 Analyte Analyst enchma

RO RO Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID:
Analysis Sample

Date Result 04/22/2010 

## * 04/14/2010 ND 

### 04/14/2010 18.50 10 10266 Waste Water Grab CLIENT (Client) 831608 Pit Water

Units Method 

### mg/1 RAD-CTDHS ug/L 624/82608 ug/L 624/82608 RPL 

### 0.000 10.00 10.00

)mments: 

### Ethylene Glycol subcontracted to Metrohm-Peak Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 j ND=Not Detected

IJote: DEP Certification #s 32-00382

1ta Qualifiers: D = The reported value is from dilution

. E 

## = Estimated value. S 

## =Surrogate out of control limits. R 

## =Sample received out of holding time

. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B 

## = Analyte was detected in both sample and methods blank. X= User defined data qualifier. Page 3 of 3

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## Report of Analysis

**~arne:**


### :ample Start Date: leceipt Date: teport Date:

I) Benzene 47) Toluene Chesapeake Appalachia, LLC 900 PeiUlsylvania Avenue Attn: Mr. Eric Gillespie Charleston , WV 25302 4/12/2010 4/13/2010 4 :27PM 4/15/2010 Analyte Analyst RO Analysis Date 04/14/2010 

# I RO 

# I 04/14/2010 

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Sample Result

ND ND 10 10267 Waste Water Grab CLIENT (Client) Trip Blank

Units Method ug/L 624/8260B 

### ug!L 624/8260B RPL 1.00 1.00

Jmments: I ND=Not Detected

DEP Certification #s 32-003 82

lta Qualifiers : D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits

. R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container

. B = Analyte was detected In both sample and methods blank. X= User defined data qualifier

. 

### Page 1 of 

### 1L...l

**'~'-<j./'<--'-L** 

## ,..._,.___ LAB 10: 39-00401

SEND DATA TO: NAME: Mike Moyer 

## BENCHMARK ANALYTICS, INC. 4777 Saucon Creek Road Center Valley, PA 18034-9004 PHONE (610) 974-8100

FAX (610) 974-8104

COMPANY: ADDRESS: Environmental Service Laboratories, Inc 

### 1803 Philadelphia St

PHONE: FAX: Indiana, 

### PA 15701 

### (724) 463-8378 (724) 465-4209 TEST REPORT WO#: PAGE: 

### PO#: PWSID# 

### Work Order: 10042307

10042307 1 of 

### 1 

### DAS03152010

1010268, 10 10266, 10 10102 RECEIVED FOR LAB BY: MAK DATE: 

### 04/16/2010 8:35 Page 

### I of 

### l

SAMPLE: 10 10266 SAMPLED BY: Client



## :rrn
. Gross Alpha Gross Beta

REMARKS: Lab 10: 10042307-002A Grab Sample Tlme 04/121201012:00 Result Uncert

. MDA Units 3022 ± 676

. 6 1058.00 pCUL 4172 ± 404

. 4 717.70 pCi/L Method EPA900.0 EPA900.0 MCL Analysis Start Analysis End Analyst * 04/19/10 8:55 04122/10 BPS-CV 04/19/1 

## o 8:55 04122/10 BPS-CV

!he



### a~ove test



### procedure~ meet all the requirements of NELAC and relate only to these samples.

CV- Benchmark Analytics, Inc. Center Valley, PA; SA= Benchmark Analytics, Inc. Sayre, PA

MANAGER



# -- **--~-----=**

**-- ~~~~·** 

**--** ____________________ DATE:



# -- **-- ~_20** 

**0** ____ _ENVIRONMENTAL SERVICE LABORATORIES. INC. SAMPLE REQUEST & CHAIN OF CUSTODY PAGE O F

HEADQUARTERS:

1 803 Philadelphia Sl Indiana, PA 15701 (724) 463-TEST (724) 465-4209 1276 BenUeyville Road
Van Voorhis

, PA 15366 (724) 258- TEST (724) 258-8376

FOR

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THESE SERVICE CHARGES Will. ACCRUE AT THE RATE OF 1 112% PER MONTH (18% PER ANNUM OR THE MAXIMUM ALLOWED BY LAW.)

UNDERSIGNED

PURCHASER AGREES TO PAY, IN THE EVENT HIS ACCOUNT BECOMES DEUNQUENT AND IS TURNED OVER TO ANY

FO

R COlL ECT ION . REA S ONABLE ATIORNE Y' S FEES PLUS ALL COURT A N D ATI EN D ANT C OLLEC T ION COSTS .

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Pressure, Alkal i nity, Acidity

TSS, TDS, Dissolved Iron, Boron,

BOD, MBAS Surfactants

AI, As, Ba, Be, Cd, Cr. Co, Cu. Fe, Pb, Mg,

Mn,

Hg, Ni, Se, Ag, Sr, Zn, li, Na , Ca, Hardness Nitrate+Nitrite, TKN, Ammonia, COD
Gross Alpha, Gross Beta

Oil & Grea se Total Phenolics Ethylene Gly co l Benzen e, To l u e n e
Ben z ene , Tolu e n e

**hes ~e**  **ake** Appalachia, LLC.

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## Report of Analysis

tme:

mple Start Date: :ceipt Date:

**~port** 

### Date: Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: 

### Mr. Eric Gillespie Charleston, WV 25302 4/9/2010 3:30PM 4/13/2010 4:37PM 5/20/2010 Analyte Analyst Acidity to pH=8.3 BF Alkalinity to pH=4.5 JML Biological Oxygen Demand 05 

## szc Chemical Oxygen Demand MAD Ammonia as N I 

### Distilled 

### MAD Chloride ZTR Kjeldahl Nitrogen as N MAD pH(SM) LL Sulfate ASTM ZTR Total Nitrate+ Nitrite as N 

### MAD Alwninurn

- ICP GJT Arsenic-ICP GJT Bariwn- ICP GJT Beryllium

- ICP GJT Boron MAD Cadmium- ICP GJT Calcium- ICP GJT Chromium

- ICP GJT Cobalt- ICP GJT Copper- ICP GJT Hardness GJT Analysis Date 04/15/2010 04/22/2010 04/19/2010 04/19/2010 05/04/2010 04/15/2010 04/30/2010 04/14/2010 04/19/2010 05/11/2010 04/27/2010 04/23/2010 04/23/2010 04/27/2010 04114/2010 04/23/2010 04/27/2010 04/23/2010 04/23/2010 04/23/2010 04/27/2010 Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID:

Sample Result 1 0 10268 Waste Water Grab CLIENT (Client) 627377 Pit Water

Units Method ND mg/1 as CaC03 SM2310B 664 mg/1 as CaC03 SM2320B 162.0 mg/1 SM5210B 1215.0 mg/1 SM5220 D 5.05 mg/1 SM4500NH3B & 

### I 23468.6 mg/1 SM4500CIC

18

. 8 mg/1 SM4500Norg-C,D 11.67 

## su SM 4500H-B 525 mg/1 D516-02 ND mg/1 SM4500N03E 9.850 mg/1 200.7/6010 ND mg/1 200.7/6010 3.950 mg/ 1 200

. 7/6010 ND mgll 

### 200

. 7/6010 ND mg/1 SM 45008-B ND mg/ 1 200.7/6010 677.750 mg/1 200.7/6010

ND mg/ 1 200.7/6010 ND mg/1 200.7/6010 ND mg/1 200.7/6010 1692 mg/ 1 SM2340B 

### RPL 2 20 2.0 200.0 0.08 1.0 4.9 0.01 125 0.05 0.500 0.500 0.250 0.250 0.25 0.250 25.000 0.250 0.250 0.250 

### 1

1mments: 

### Ethylene Glycol subcontracted to Metrohrn-Peak Dilutions utilized for BOD analysis did not meet laboratories acceptance criteria of at least 2 mg/L depletion (loss) Radiologicals done by Benchmark Analytical , PADEP Lab ID: 39-00401 jND=Not Detected

**~ote:** DEP Ce rtific at ion #s 32- 00382

1ta Qualifiers: D =The reported value is from dilution

. E = Estimated value. S = Surrogate out of control lim i ts. R = Sample received out of holding time. H = Sample analyzed out of holding time

. C = Sample received in incorrect container. 8 = Analyte was detected in both sample and methods blank

. X= User defined data qualifier. Pace 1 of 3

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## Report of Analysis

arne:

tmp1e Start Date: eceipt Date: eport Date: Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 4/9/2010 3:30PM 4/13/ 2 010 4 : 37PM 5/20/ 2 010 Analyte Analyst
Iron- ICP GJT lron,Dissolved-ICP GJT Lead-ICP GJT Lithium

- ICP GJT Magnesiwn-ICP GJT Manganese- ICP GJT Mercury DRM Nickel- ICP GJT Selenium-ICP GJT Silver-ICP GJT Sodium- ICP GJT Strontium

- ICP GJT Zinc- ICP GJT Osmotic Pressure MAD Detergents, MBAS TL Ethylene Glycol MetPeak Oil and Grease

- HEM CLM Phenolics, as Phenol AID Specific Conductance LL Total Dissolved Solids (TDS) LMB Total Suspended Solids LMB Analysis Date 04/23/2010 04/23/2010 04/23/2010 04/27/2010 04/27/2010 04/23/2010 04/15/2010 04/23/2010 04/23/2010 04/23/2010 04/27/2010 04/27/2010 04/23/2010 04/20/2010 04/15/2010 04/19/2010 04/27/2010 05/17/2010 04/14/2010 04/15/2010 04/15/2010 Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID:

Sample Result 13

. 800 0.550



### ND ND 

### ND 0.300 

### ND ND ND ND 15726.000

31.550

ND 10 10268 Waste Water Grab CLIENT (Client) 627377 Pit Water

Units Method mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 245.1 mg/1 200

. 7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200

. 7/6010 mg/1 200.7/6010 mg/1 200.7/6010 1225 mOslkg OSP 7

. 880 mg/1 SM5540C <26.00 mglkg 300

. 0 M

ND mg/1 1664A ND mg/1 420

. 1 59800 uS/em SM 2510B 39500 mg/1 SM2540C

476 mgll SM2540D 

### RPL 0.500 0

. 500 0

.250 25.000 25.000 0

.250 0.0020 0.250 0.500 0

. 250 500.000

0

. 500 0

. 250

100 0

. 800 5

.000

5.0 0.500 1 25 5

omments: 

### Ethylene Glycol subcontracted to Metrohm-Peak Dilutions utilized for BOD analysis did not meet laboratories acceptance criteria of at least 2 mg/L depletion (loss) Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 I ND=Not Detected

Note: DEP Certific ation #s 32-00382

**:~ta** Qualifiers : D 

## = The reported value is from dilution. E 

## = Estimated value. S 

## =Surrogate out of control limits

. R 

## =Sample received out of holding time

. H 

## =Sample analyzed out of holding time

. C 

## = Sample received in incorrect container

. B 

## =Analyte was detected in both sample and methods blank. X 

## = User defined data qualifier

. Paae 2 of 3

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# ll.- :RVICE LABORATORIES, INC. l03 

## Philadelphia Street Indiana, PA 15701 

## 24)-463-TEST FAX (724)-465-4209 

## Report of Analysis
1me:

mple Start Date: :ceipt Date: :port Date:

Radiologicals 1) Benzene 47) Toluene Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 4/9/2010 3:30PM 4/13/2010 4:37PM 5/20/2010 Analyte Analyst enchmru

RO RO Samp le ID # : Samp le Type: Sample Source: Sampler: Client Sample ID:
Analysis Sample

Date Result 04/22/2010 

## * 04/14/2010 

### ND 04/14/2010 18.20 10 10268 

### W

aste Water Grab CLIENT (Client) 627377 Pit Water

Units Method mg/1 RAD-CTDHS ug/L 624/8260B ug/L 624/8260B 

### RPL 0

.000 10.00 10.00

mments: Ethylene Glycol subcontracted to Metrohm-Peak Dilutions utilized for BOD analysis did not meet laboratories acceptance criteria of at least 2 mg/L depletion (loss) Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 I ND=Not Detected

lote: DEP Certification #s 32-00382

ta Qualifiers: D =The reported value is from dilution. E = Estimated value

. S = Surrogate out of control limits. R = Sample received out of holding time

. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. Paoe 3 of 3

# C1?e5clp~ 

# t'e LAB ID: 39-00401

SEND 

### DATA TO: NAME: Mike Moyer 

## BENCHMARK ANAL YTICS, INC

. 4777 Saucon Creek Road

_ Center 

## Valley, PA 18034-9004 PHONE (610) 974-8100

FAX (61 0) 974-8104

COMPANY: ADDRESS: Environmental Service Laboratories, Inc 1803 Philadelphia St

PHONE: FAX: Indiana, 

### PA 15701 

### (724) 463-8378 (724) 465-4209 

### TEST REPORT WO#: PAGE: 

### PO#: PWS ID# Work Order: 10042307

10042307 1 of 1 DAS03152010



### 10 10268, 10 10266, 10 10102 RECEIVED FOR LAB BY: MAK DATE: 04/16/2010 8:35 

### Page 1 

### ofl

SAMPLE: 1010268 SAMPLED BY: Client



## :wt
. Gross Alpha Gross Beta

REMARKS: Lab ID: 10042307-00tA Grab Sample Time 04/09/2010 15:30 Result

**~** MQ& Units 126.1 ± 128.4 473.60 pCi/L 1295 ± 166.6 352.40 pCVL Method EPA 900.0 EPA900.0 MCL Analvsls Start Anarvs 'is End Analvst • 04/19/10 8:55 04/22110 BPS-CV 04/19/10 8 : 55 04122/10 BPS-CV

The above test procedures meet all the requirements of NELAC and relate only

**~o** these samples. * 

## cv =Benchmark Analytics, Inc

. Center Valley, PA; SA= Benchmark Analyt1cs, Inc. Sayre, PA

MANAGER



# ------ **----~ ~~**  **~~~~ ·**  ____________________ DATE:



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## i'\1 I a i 

# .................................... ;ERVICE LABORATORIES, INC. 803 Philadelphia Street Indiana, PA 15 701 

## 724)-463-TEST FAX (724)-465-4209 

## Report of Analysis

a me:

ample Start Date: eceipt Date: eport Date:

1) Benzene 47) Toluene Chesapeake Appalachia, LLC 900 Pennsylvania Avenue 

### Attn: Mr. Eric Gillespie Charleston, 

### WV 25302 4/9/2010 4/13/2010 4:37PM 4/15/2010 Analyte Analyst RO RO Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID:
Analysis Sample

Date Result 04/14/2010 

### ND 04/14/2010 ND 10 10269 Waste Water Grab CLIENT (Client) Trip Blank

Units Method 

### ug/L 624/8260B 

### ug/L 624/8260B 

### RPL 1.00 1.00

mments: jND=Not Detected

DEP Cert ification #s 32-00382

'a Qualifiers : D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. R 

## =Sample received out of holding time. H 

## =Sample analyzed out of holding time. C 

## =Sample received in incorrect container

. B = Analyte was detected in both sample and methods blank. X= User defined data qualifier. Page 1 of 1ENVIRONMENTAL SERVICE LABORATORIES. INC. SAMPLE REQUEST & CHAIN

HEADQUARTERS:

1 803 Philadelphia Sl

Indiana, PA 15701 (724) 463-TEST (724) 46>4209 SOUlliERN DMSION:
1276 BenHeyville Road

Van Voorhis, PA 15366 (724) 258- TEST (724) 258-8376

FOR INTERNAL LABORATORY USE ONLY

Sample Identification ESL#

TRIP BLANK 1/ /} / h'77..f::'l ,..........-- ow 1--- D 1_.

**~** --I

I . THESE SERVICE CHARGES WILL ACCRUE AT THE RATE OF I 112% PER MONTH (18,., PER ANNUM OR THE MAXIMUM ALLOWED BY LAW . )

THE UNDERSIGNED PURCHASER AGREES TO PAY, IN THE EVENT HIS ACCOUNT BECOMES DEUNQUENT AND IS TURNED OVER TO ANY

ATIORNEY FOR COLLECTION . . REASONABLE ATIORNEY'S FEES PLUS ALL COURT AND ATIENDANT COLLECTION COSTS .

4 .. / :;-- 10 rso o
5
Date/ Time

N OF CUSTODY SEAL BROKEN: Yes No **~ f~**  E **~~3** t:; **F\\/t~lTi** C/ f\! N TEMP ::::: · 4°C

C ()t\J'u ll\ co .,...\...-! . I, ,,! .Jl_! \ Matrix # of Containers

WN -

WN .,t'3

-

WN -

iNw -

WN 2

-

WN -

WN -

WN 2

-

WN 2

-

Water 2 N Container Type Preservative Plastic Liter none Plastic Liter none Plastic Liter HN0 3 Plastic Liter

H 2 SO, Plastic Liter HN0 3 Amber Glass L HCI Amber Glass L

H 2 SO, Amber VOA Vials none Amber VOA Vials HCI Amber VOA Vials HCI Company/Name: Person: f' I I'\

. -.u-·. PAGE_OF_ RECEI\lED JUN I 4 2010 REGULATORY Analysis Requested

pH, SC, Choride . Sulfate ,

Osmo tic: Pressure . Al kalinity , A ci di ty

TSS, TDS, Dissolved Iron,

Boron, BOD, MBAS Surf;;;=tants

AJ, As, Ba, Be , Cd, Cr, Co, Cu, Fe, Pb, Mg,

Mn, Hg, Ni, Se, Ag, Sr, Zn, Li, Na Ca, Hardness

Nitra te +Nitrite, TKN , Ammonia, COD
Gross Alpha, Gross Beta

Oil & Grease Total Phenolics Ethylene Glyc:ol Benzene, Toluene

- .

**~-** .. **~-** '

, Cliesal?_eake Appalachia, LLC.

I **~**