mbe ;fflf[unicipal ~utboritp 

Members of the Board 

FRANK BAZZONE 

DALE R. McCALL 

REGIS T. MCLAUGHLIN 

LUETHEL NESBIT 

NICKOU.S SHERMENTI 

August 12, 2010 

of tbt «:itp of :ffitlltte-port 

100 Atlantic Avenue 

McKeesport, PA 15132 

Office: (412) 673·8276 

Fax: (412) 673-4283 

www.mckeesport-macm.org 

Mr. Kevin Halloran, Water Quality Specialist Supervisor 

Water Management 

Pennsylvania Department of Environmental Protection 

400 Waterfront Drive 

Pittsburgh, PA 15222-4745 

Dear Mr. Halloran; 

Municipal Authority of the City of McKeesport 

Analysis of Gas Well Wastewaters 

As Required Under the 

PA DEP Administrative Order Dated October 23, 2008 

Joseph E. Rost 

Executive Director 

Phone (412) 673-9701 

Please find enclosed copies of the laboratory analyses of fourteen (14) wells owned by 

Chesapeake Energy for the parameters specified in the Administrative Order. The wells are 

identified as #627253, #627264, #831608, #627377, and #831881, #627254, #627262, 

#626748/627005, #831201(pit water), #831201(drill water), #.831600, #832033(pit water), 

#832033(drill water), #627255, #900557, #831879. 

The Authority is currently accepting gas well water from three companies, Huntley & Huntley, 

Chesapeake Energy, and CNX Gas. Wastewaters from new wells accepted by the plant are in the 

process of being analyzed by Environmental Service Laboratories (ESL) located in Indiana, PA. 

As the results are received by the Authority copies will be forwarded to your office. 

If you have any questions, please contact me at (412) 673-9701 ext. 12. 

Sincerely, 

cc: Michael C. Shenieb, KLH Engineers, Inc. 

Chad Harsh, EPA 
~be ;!fmuniripal ~utboritp 

Members of the Board 

FRANK BAZZONE 

DALE R. MCCALL 

REGIS T. MCLAUGHLIN 

LUETHEL NESBIT 

NICKOLAS J. SHERMENTI 

August 12, 2010 

Mr. Chad Harsh 

NPDES Enforcement Branch 

Water Protection Division 

of tbe QCitp of ;iflllc11\.re~port 

100 Atlantic Avenue 

McKeesport, PA 15132 

Office: (412) 673-8276 

Fax: (412) 673-4283 

www.mck-macm.org 

U.S. Environmental Protection Division 

1650 Arch Street 

Philadelphia, P A 19103 

Dear Mr. Harsh: 

Joseph E. Rost 

Executive Director 

Phone (412) 673-9701 

As requested in your letter dated February 19, 2009, enclosed is a copy of the Authority's latest 

submittal to the Pennsylvania Department of Environmental Protection in response to its order 

issued October 23, 3008. This Order was issued relative to the gas well water that the Authority 

has received for treatment. 

If you have any questions, please contact me at (412) 673-9701 x12. 

Sincerely, 

Enclosures 
Tba City of McKeespOrt 

100 Atlantic A11enue 

McKeesport, Pennsylvania 15132 

IIETVRN ADDRESS, FOLD A TOOTlE) 

--------CEiitiFiEii .. ------

lfl /lll/1/ll l/ II Ill 

POST4LSERVICE 

l - 7002 203Q 0002 8073 3485 

Ava 1 _ 

--:> ?o,0 l£t\ft\1l \\E

lf.QUi.S

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. 

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PRIORITY® 114 PRIORITY"' fWl fi! PRIORITY'" 

MIJIL (I; 1 i! MIJIL l ! AJI Jl II 

'Prltl,.,rt!' _ ..... I ... ,._.._.........,_. 
ENVIRONMENTAL SERVICE 

LABORATORIES, INC. SAMPLE REQUEST CHAIN OF CUSTODY 

HEADQUARTERS: 

1803 Philadelphia Sl 

Indiana, PA 15701 

(724) 463-TEST 

(724) 465-4209 

)0 SOUTI-IERN DMSION: 1276 Bentleyville Road Van Voorhis, PA 15366 (724) 258-TEST 

(724) 258-8376 

FOR INTERNAL LABORATORY USE ONLY 

Sample Identification ESL# 

4-/-10 

Date/ Time Date/ Tome 

N OF CUSTODY SEAL BROKEN: Yes No 

D 

P R r:: F_- . '\ .,...·-, . ._...1 

4oC 

CONTAINER 

y 

Matrix # of Containers 

WN WN 2 WN 

ww ww 2 ww 

ww 

ww 2 

WN 2 

Water 2 

N 

N 

N 

N/?, 

Container Type 

Preservative 

Plastic Liter 

none 

---

Plastic Liter 

none 

---

Plastic Liter 

HN03 

Plastic Liter 

H2SO, 

Plastic Liter 

HN03 

---

Amber Glass L 

HCI 

-

Amber Glass L 

H2so. 

Amber VOA Vials 

none 

---

AmberVOA 

HCI 

R

M

Company/Name: ;., 

Address: --'90

/ /....J · -rtr: !Contact 

£b:-n.-..t 7 - .. - Phone: 

Contact Person: 

_R_e_ce-iv-ed--B-y:-(-SI-gM-tu_rn_) ________ 

Fax: 
= =- ::. =====:a_ ....... _ -N= = = r- =- ==== s = 

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=RVICE LABORATORIESI INC. 

103 Philadelphia Street Indiana, PA 15 701 

24)-463-TEST FAX (724)-465-4209 

Report of Analysis 

1mple Start Date: 

!ceipt Date: 

!port Date: 

Chesapeake Appalachia, LLC 

900 Pennsylvania A venue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/1/2010 3:00PM 

4/2/2010 I :46 PM 

5/18/2010 

Analyte Analyst 

Acidity to pH=8.3 BF 

Alkalinity to pH=4.5 JML 

Biological Oxygen Demand 05 szc 

Chemical Oxygen Demand ZTR 

Ammonia as N I Distilled AID 

Chloride BF 

Kjeldahl Nitrogen as N MAD 

pH (SM) LL 

Sulfate ASTM ZTR 

Total Nitrate+ Nitrite as N MAD 

Aluminum- ICP GJT 

Arsenic-ICP GJT 

Barium- ICP GJT 

Beryllium - ICP GJT 

Boron MAD 

Cadmium- ICP GJT 

Calcium - ICP GJT 

Chromium- ICP GJT 

Cobalt- ICP GJT 

Copper- ICP GJT 

Hardness GJT 

Analysis 

Date 

04/15/2010 

04/12/2010 

04/07/2010 

04/07/2010 

04/19/2010 

04/08/2010 

04/15/2010 

04/05/2010 

04/08/2010 

04/09/2010 

04/22/2010 

04/20/2010 

04/20/2010 

04/19/2010 

04/07/2010 

04/20/2010 

04/20/2010 

04/19/2010 

04/19/2010 

04/19/2010 

04/22/2010 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Sample 

Result 

10 09232 

Waste Water 

Grab 

CLIENT (Client) 

627253 Pit Water 

Units Method 

ND mg/1 as CaC03 SM23IOB 

42290 mg/1 as CaC03 SM2320B 

588.0 mg/1 SM5210B 

6040.0 mg/1 SM5220 D 

8.97 mg/1 SM4500NH3B & I 

966.3 mg/1 SM4500ClC 

71.3 mg/1 SM4500Norg-C,D 

8.40 su SM 4500H-B 

ND mg/1 D516-02 

* mg/1 SM4500N03E 

38.000 mg/1 200.7/6010 

ND mg/1 200.7/6010 

3.800 mg/1 200.7/6010 

O.Dl8 mg/1 200.7/6010 

2.72 mg/1 SM 4500B-B 

ND mg/1 200.7/6010 

14818.000 mg/1 200.7/6010 

ND mg/1 200.7/6010 

1.402 mg/1 200.7/6010 

1.006 mg/1 200.7/6010 

45050 mg/1 SM2340B 

RPL 

2 

20 

2.0 

2000.0 

0.10 

1.0 

50.9 

0.01 

25000 

0.05 

1.000 

1.000 

0.500 

0.010 

1.00 

0.500 

50.000 

0.010 

0.010 

0.010 

1 

>mments: 

Osmotic Pressure and Nitrate/Nitrite could not be analyzed due to matrix of the sample. 04/09/10 MAD 

Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 

IND=Not Detected 

~ote: DEP Certification #s 32-00382 

1ta Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Paoe 1 of 3 
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= ... .1!1 -------- = ="""",......,., 11:. = = ... 

------- ..- =. =-- ...... 'r=';;;:...=~ -=.-,==-.;;;ii""- =""'" = ;;-=.;; '-- ,. I II'K"".. • '-- .,.. I'-- I - • II. W 11'-~l .IWI-1. II ... 

:RVICE LABORATORIES, INC. 

:03 Philadelphia Street, Indiana, PA 15701 

24)-463-TEST FAX (724)-465-4209 

Report of Analysis 

arne: 

mple Start Date: 

!Ceipt Date: 

!port Date: 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

411/2010 3:00PM 

4/2/201 0 1 :46 PM 

5/18/2010 

Analyte Analyst 

Iron- ICP GJT 

Iron,Disso lved-I CP GJT 

Lead-ICP GJT 

Lithium - ICP GJT 

Magnesium-ICP GJT 

Manganese - ICP GJT 

Mercury DRM 

Nickel- ICP GJT 

Selenium-ICP GJT 

Silver-ICP GJT 

Sodium- ICP GJT 

Strontium- ICP GJT 

Zinc- ICP GJT 

Osmotic Pressure MAD 

Detergents, MBAS ZTR 

Ethylene Glycol MetPeak 

Oil and Grease - HEM CLM 

Phenolics, as Phenol MAD 

Percent Total Solids DRM 

Specific Conductance LL 

Total Dissolved Solids (TDS) LMB 

Analysis 

Date 

04/19/2010 

04/19/2010 

04/19/2010 

04/20/2010 

04/22/2010 

04/22/2010 

04/15/2010 

04/19/2010 

04/19/2010 

04/19/2010 

04/20/2010 

04/20/2010 

04/19/2010 

04/09/2010 

04/02/2010 

04/09/2010 

04/19/2010 

04/19/2010 

04/07/2010 

04/05/2010 

04/07/2010 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Sample 

Result 

7.082 

* 

0.070 

ND 

1954.800 

168.000 

ND 

2.364 

0.112 

ND 

1298.200 

65.000 

5.276 

10 09232 

Waste Water 

Grab 

CLIENT (Client) 

627253 Pit Water 

Units Method 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 245.1 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

* mOs/kg OSP 

2.010 mg/1 SM5540C 

<25.000 mglkg 300.0 M 

ND mg/1 1664A 

ND mg/1 420.1 

38 % SM2540B 

2358 uS/em SM 2510B 

3200 mg/1 SM2540C 

RPL 

0.020 

0.010 

0.010 

50.000 

50.000 

0.500 

0.0200 

0.010 

0.020 

0.010 

50.000 

1.000 

0.010 

100 

2.000 

25.000 

5.0 

5.000 

5 

I 

25 

>mments: 

Osmotic Pressure and Nitrate/Nitrite could not be analyzed due to matrix of the sample. 04/09/10 MAD 

Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-0040 I 

IND=Not Detected 

~ate: DEP Certification #s 32-00382 

3ta Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X= User defined data qualifier. 

Paoe 2 of 3 
. - -- --- ......... - -- --- -- - - ; ~ i \ I! ur-\ E\. i & ii i: ~ i ; A ii I - ,. I liE'" a I I - 1'1 I .-I - I - I I I 11 Y I 1'&. ~ I 11 I Y I -I 11 II lL-

~RVICE LABORATORIES~ INC. 

103 Philadelphia Street Indiana, PA 15701 

24)-463-TEST FAX (724)-465-4209 

Report of Analysis 

1me: 

1m pie Start Date: 

~ceipt Date: 

~port Date: 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/1/2010 3:00PM 

4/2/2010 1:46PM 

5/18/2010 

Analyte Analyst 

Total Suspended Solids LMB 

Radiologicals enchma 

I) Benzene RO 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

04/07/2010 490400 

04/16/2010 * 

04/07/2010 ND 

10 09232 

Waste Water 

Grab 

CLIENT (Client) 

627253 Pit Water 

Units Method 

mg/1 SM2540D 

mgll RAD-CTDHS 

ug!L 624/8260B 

RPL 

5 

0.000 

49.00 

47) Toluene RO I 04/07/2010 I ND ug!L 624/8260B j 49.00 ] 

Jmments: 

Osmotic Pressure and Nitrate/Nitrite could not be analyzed due to matrix ofthe sample. 04/09/10 MAD 

Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 

llote: DEP Certification #s 32-00382 

3ta Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

jND=Not Detected 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Paoe 3 of 3 
APR-28-2010 11:08 AM --• ..... lf"U •• '' lo' II'' ... I I ..... ~, ~I"'""' 

4 777 Saucon Creek Road 

Center Valley, PA 18034-9004 

PHONE (610) 974·8100~ 

FAX (610) 974-8104 

SEND DATA TO: 

NAME: 

COMPANY: 

ADDRESS: 

PHONE: 

FAX: 

Mike Moyer 

Environmental Service Laboratories, Inc 

1803 Philadelphia St 

Indiana, PA 15701 

(724) 463w837B 

(724) ·465-4209 

TEST REPORT 

WO#: 

PAGE: 

PO#: 

PWS 10# 

Work Order: 1 0041 002 

10041002 

1 of 2 

DAS0406201 0 

RECEIVED FOR LAB BY: MAK DATE: 04/08/2010 9:05 Page 1 of2 

SAMPLE: 10 OCJ232 Lab 10: 10041002-DOI'lA arab 

SAMPLED BY: David A. stiles Sample Time 04/0112010 15:00 

IW BWl1 !.l1m1. MQA JJ.al1l ~ MC.b Ma!)!&li Slill 6Di~lll ;[l!j 6DJJm..:. 

Groaa Alpha 913.3 :1: S19.8 701.10 pCllkg EPA900.0 04113110 8:45 04/18/10 BPS-CV 

Gross Beta 781.2 t 233.15 87!1.20 pCI/kg EPA900.0 04/13/10 8:45 04/116/10 BPS-CV 

·-· -- ·· .. . . ··-·-- ·---·- ··--•--•v ....... •--- · .... ·- ·----- ··-.. ·----·-·-· .. -- ..... 

REMARKS: 

The above test procedure• meet all the requirements of NELAC and relate only to these samples. 

• CV .. Benchmark Analytics, Inc. Center Valley, PA; SA= Benchmark Analytlcs, Inc. Sayre, PA 

MANAGER ·· -·- --- -~~--- -- .... -·-· --··· ---· ·~- DATE: _ _ 1~~B!.Jfl .. ~~ -- ·· · 
-- -- --- .-... - -- --- -- - - ~~;\:iu~;\i!ii!;:!\.~TA i . -I. . -... Y . I .... ..... .. ....,. . . I -

••WI ...... -I - . -••• 

. -,. . SERVICE LABORATORIES/ INC. 

1803 Philadelphia Street, Indiana, PA 15701 

(724)-463-TEST FAX (724)-465-4209 

Report of Analysis 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

1) Benzene 

47) Toluene 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/1/2010 

4/2/2010 1 :46 PM 

5/18/2010 

Analyte Analyst 

RO 

RO 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

04/07/2010 ND 

04/07/2010 ND 

10 09233 

Waste Water 

Grab 

CLIENT (Client) 

Trip Blank 

Units Method 

ug/L 624/8260B 

ug/L 624/8260B 

RPL 

1.00 

1.00 

:::omments: 

IND=Not Detected 

DEP Certification #s 32-00382 

)ata Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 1 of 1 
ENVIRONMENTAL SERVICE 

LABORATORIES. INC. SAMPLE REQUEST & CHAIN OF CUSTOD

HEADQUARTERS: 

1 803 Philadelphia Sl 

Indiana, PA 15701 

(724) 463-TEST 

(724) 465-4209 

,_OUTHERN DMSION: 76 Bentleyville Road 

Y-an Voorhis, PA 15366 

(724) 258-TEST D P F~~ t:~~- s t;: f::-\ \/:\~·.,~r f <.:.) r 1 

(724) 258-8376 

FOR INTERNAL LAB ORA TORY USE ONLY 

TEMP< 4°C 

COf\1TAii\JER 

Sample Identification ESL# Matrix # of Containers 

TRIP BLANK 1// YP"/Qf?}...-j .......-:: ,~ ,~ ~ --' 

. THESE SERVICE CHARGES WILL ACCRUE AT THE RATE OF 1 112% PER MONTH (18% PER ANNUM OR THE MAXIMUM ALLOWED BY LAW.) 

THE UNDERSIGNED PURCHASER AGREES TO PAY, IN THE EVENT HIS ACCOUNT BECOMES DELINQUENT AND IS TURNED OVER TO ANY 

FOR COU.ECTION, REASONABLE AITORNEY'S FEES PLUS ALL COURT AND AITENDANT COLLECTION COSTS. 

I . I v ~. • . ~' \e--' 

.... 

••- · · ·. \ "l ' f'V ./ ... ) I 

vwv 

-

vwv 2 

-

vwv 

-

vwv 

-

vwv 2 

-

vwv 

-

vwv 

-

vwv 2 

-

vwv 2 

-

Water 2 

f\J 

N 

N 

i\ I I J' '~iA Container Type 

Preservative 

Plastic Liter 

none 

Plastic Liter 

none 

Plastic Liter 

HN03 

Plastic Liter 

H2SO, 

Plastic Lller 

HN03 

Amber Glass L 

HCI 

Amber Glass L 

H2S04 

Amber VOA Vials 

none 

Amber VOA Vials 

HCI 

AmberVOA ~-- r- 

:-> 9

,{"' '%~) · ~//?? /.? ~ !Contact Person: 

Contact Person: 

By: (Signature) Date/ Time (Signature) Date/ Time 

OF CUSTODY SEAL BROKEN: Yes No 
. - -- --- ....... - -- --- -- - - • "'I. = ... Ill" =-=.=r-ooo. ~ ......... =-- ~ =-=- ...... = I ~ ;; ';a. ;; ; =-=~ 'a ~-";.;; -.... :t; =- ;":1. ;; ;; ;;-;. ;; I U .... I _.... II U ,., • .--- • ~ • - • I I W Y I 1'-.......,. I 11 I WI -I W II .__ 

ERVICE LABORATORIES/ INC. 

l03 Philadelphia Street Indiana, PA 15701 

24)-463-TEST FAX (724)-465-4209 

Report of Analysis 

arne: 

1m pie Start Date: 

eceipt Date: 

eport Date: 

Chesapeake Appalachia, LLC 

900 Pennsylvania A venue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/7/2010 3:15PM 

4/9/20 I 0 I :20 PM 

5/13/2010 

Analyte Analyst 

Acidity to pH=8.3 BF 

Alkalinity to pH=4.5 ZTR 

Biological Oxygen Demand 05 szc 

Chemical Oxygen Demand MAD 

Ammonia as N I Distilled MAD 

Chloride LL 

Kjeldahl Nitrogen as N MAD 

pH(SM) LL 

Sulfate ASTM ZTR 

Total Nitrate +Nitrite as N MAD 

Aluminum - ICP GJT 

Arsenic-ICP GJT 

Barium- ICP GJT 

Beryllium- ICP GJT 

Boron MAD 

Cadmium- ICP GJT 

Calcium - ICP GJT 

Chromium - ICP GJT 

Cobalt- ICP I GJT 

Copper- ICP GJT 

Hardness GJT 

Analysis 

Date 

04/15/2010 

04/2112010 

04/14/2010 

04/14/2010 

04/30/2010 

04/2112010 

04/30/2010 

04/13/2010 

04/19/2010 

05/ll/2010 

04/22/2010 

04/20/2010 

04/20/20 10 

04/19/2010 

04/14/2010 

04/20/2010 

04/20/2010 

04/1912010 

04/19/2010 

04/19/2010 

04/20/2010 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Sample 

Result 

lO 09991 

Waste Water 

Grab 

CLIENT (Client) 

627264 Pit Water 

Units Method 

ND mg/1 as CaC03 SM2310B 

109 mg/1 as CaC03 SM2320B 

312.0 mg/I SM5210B 

886.0 mg/1 SM5220 D 

29.42 mg/I )M4500NH3B & [ 

12477.1 mg/1 SM4500ClC 

12.5 mg/I SM4500Norg-C,D 

8.98 su SM 4500H-B 

220 mg/1 D516-02 

ND mg/1 SM4500N03;E 

4.500 mg/1 200.7/6010 

ND mg/1 200.7/6010 

3.700 mg/1 200.7/6010 

ND mg/1 200.7/6010 

ND mg/1 SM 4500B-B 

ND mg/1 200.7/6010 

481.100 mg/1 200.7/6010 

ND mg/1 200.7/6010 

ND mg/1 200.7/6010 

ND mg/1 200.7/6010 

1495 mg/1 SM2340B 

RPL 

2 

20 

2.0 

200.0 

1.00 

1.0 

5.2 

O.Ql 

50 

0.05 

1.000 

1.000 

0.500 

0.500 

0.25 

0.500 

50.000 

0.500 

0.500 

0.500 

1 

omments: Dilutions utilized for BOD analysis did NOT meet the laboratories acceptance criteria of at least 2 mg!L 

DO depletion (loss). Ethylene Glycol subcontracted to Metrohm-Peak Radiologicals done by Benchmark 

Analytical, PADEP Lab ID: 39-00401 

IND=Not Detected 

Note: DEP Certification #s 32-00382 

:Jta Qualifiers: D =The reported value is from dilution. E =Estimated value. S =Surrogate out of control limits. 

R =Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

8 = Analyte was detected in both sample and methods blank. X= User defined data qualifier. 

Paae 1 of 3 
-- -- --- .-.. - -- --- -- - - ·=-=· ===--:~=.== =-r:.::l-=-2. = 

• 11'\.i \I i i#l ii'\i i\li i"- iu i a i I I • 1J I I'~ I • 11J I-I • II 9.-

ERVICE LABORATORIES, INC. 

303 Philadelphia Street Indiana, PA 15701 

'24)-463-TEST FAX (724)-465-4209 

Report of Analysis 

arne: 

tmple Start Date: 

eceipt Date: 

eport Date: 

Chesapeake Appalachia, LLC 

900 Pellllsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/7/2010 3:15PM 

4/9/2010 I :20 PM 

5/13/2010 

Analyte Analyst 

Iron- ICP GJT 

Iron,Dissolved-ICP GJT 

Lead-ICP GJT 

Lithium - ICP GJT 

Magnesium-ICP GJT 

Manganese - ICP GJT 

Mercury DRM 

Nickel- ICP GJT 

Selenium-ICP GJT 

Silver-ICP GJT 

Sodium- ICP GJT 

Strontium - ICP GJT 

Zinc- ICP GJT 

Osmotic Pressure MAD 

Detergents, MBAS TL 

Ethylene Glycol MetPeal< 

Oil and Grease - HEM CLM 

Phenolics, as Phenol MAD 

Specific Conductance LL 

Total Dissolved Solids (TDS) CLM 

Total Suspended Solids CLM 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

04/19/2010 4.200 

04/19/2010 ND 

04/19/2010 ND 

04/20/2010 ND 

04119/2010 71.400 

04/19/2010 ND 

04/15/2010 ND 

04/19/2010 ND 

04/19/2010 ND 

04/19/2010 ND 

04/20/2010 7110.900 

04/20/2010 16.100 

04/19/2010 ND 

04/09/2010 652 

04/09/2010 3.075 

04/19/2010 <25.250 

04/23/2010 ND 

04/19/2010 ND 

04/13/2010 32118 

04/14/2010 28000 

04/14/2010 8040 

10 09991 

Waste Water 

Grab 

CLIENT (Client) 

627264 Pit Water 

Units Method 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 245.1 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mOs/kg OSP 

mg/1 SM5540C 

mg/kg 300.0 M 

mg/1 1664A 

mg/1 420.1 

uS/em SM 2510B 

mg/1 SM2540C 

mg/1 SM2540D 

RPL 

1.000 

1.000 

0.500 

50.000 

50.000 

0.500 

0.0008 

0.500 

1.000 

0.500 

50.000 

1.000 

0.500 

100 

1.000 

25.250 

5.0 

0.500 

I 

25 

5 

omments: Dilutions utilized for BOD analysis did NOT meet the laboratories acceptance criteria of at least 2 mg/L 

DO depletion (loss). Ethylene Glycol subcontracted to Metrohm-Peak Radiologicals done by Benchmark 

Analytical, PADEP Lab ID: 39-00401 

IND=Not Detected 

•\late: DEP Certification #s 32-00382 

3ta Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Paae 2 of 3 
= =. i'i .5 i ===-..-...'e..~ i iii. iii==~ i=:= s i 

• I'd VI~~ Jiu nil r-iu i .£a i I I. W' .............. ····-·.II .... 

ERVICE LABORATORIES, INC. 

303 Philadelphia Street Indiana, PA 15701 

'24)-463-TEST FAX {724)-465-4209 

Report of Analysis 

arne: 

ample Start Date: 

eceipt Date: 

eport Date: 

Radiologicals 

1) Benzene 

47) Toluene 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/7/2010 3:15PM 

4/9/20 I 0 1 :20 PM 

5/13/2010 

Analyte Analyst 

enchma 

RO 

RO 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

04/18/2010 * 

04/09/2010 ND 

04/09/2010 16.40 

10 09991 

Waste Water 

Grab 

CLIENT (Client) 

627264 Pit Water 

Units Method 

mg!l RAD-CTDHS 

ug/L 624/8260B 

ug/L 624/8260B 

RPL 

0.000 

10.00 

10.00 

omments: Dilutions utilized for BOD analysis did NOT meet the laboratories acceptance criteria of at least 2 mg/L 

DO depletion (loss). Ethylene Glycol subcontracted to Metrohm-Peak Radiologicals done by Benchmark 

Analytical, PADEP Lab ID: 39-00401 

IND=Not Detected 

"Jote: DEP Certification #s 32-00382 

3fa Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Paae 3 of 3 
(n(9af?4t'~ 

LAB ID: 39-00401 

SEND DATA TO: 

NAME: Mike Moyer 

BENCHMARK ANAL YTICS, INC. 

4777 Saucon Creek Road 

Center Valley, PA 18034-9004 

PHONE (610) 974-8100 

FAX (610) 974-8104 

COMPANY: Environmental Service Laboratories, Inc 

ADDRESS: 1803 Philadelphia St 

PHONE: 

FAX: 

Indiana, PA 15701 

(724) 463-8378 

(724) 465-4209 

TEST REPORT . 

WO#: 

PAGE: 

PO#: 

PWS ID# 

Work Order: 10041613 

10041613 

1 of 1 

DAS04122010 

10 09991, 1010025 

RECEIVED FOR LAB BY: MAK DATE: 04/13/2010 8:45 Page I ofl 

SAMPLE: 10 09991 

SAMPLED BY: Client 

Test 

Gross Alpha 

Gross Beta 

REMARKS: 

Lab 10: 10041613-001A Grab 

Sample Time 04/0712010 15:15 

&lil!l1 Uncert. MDA Units 

37.98 :t: 52.12 210.10 pCVL 

734.5 ± 89.06 187.40 pCi/L 

Method 

EPA 900.0 

EPA 900.0 

MQ!.. Analysis Start Analysis End ~ 

04/14110 8:55 04/1B/10 BPS-CV 

04114110 8:55 04118/10 BPS-CV 

The above test procedures meet all the requirements of NELAC and relate only to these samples. 

* CV =Benchmark Analytics, Inc. Center Valley, PA; SA= Benchmark Analytics, Inc. Sayre, PA 

MANAGER -----------~--~·~~~~~--__________________ DATE: ____ £0 0 ____ _ 
. - -- --- ..-... - -- --- -- - - ;~i\J!u~ ~!\..ia~a;:~;TA i I ·-

I W ............ W I I'-,.._, ·-····· I 11 I W I - .... I W ·-· II 1LERVICE LABORATORIES, INC. 

!03 Philadelphia Street Indiana, PA 15 70 l 

24)-463-TEST FAX (724)-465-4209 

Report of Analysis 

1me: 

1m pie Start Date: 

~ceipt Date: 

~port Date: 

- I) Benzene 

47) Toluene 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/7/2010 

4/9/2010 1 :20 PM 

4112/2010 

Analyte Analyst 

RO 

RO 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

04/09/2010 ND 

04/09/2010 ND 

10 09992 

Waste Water 

Grab 

CLIENT (Client) 

Trip Blank 

Units Method 

ug!L 624/8260B 

ug!L 624/8260B 

RPL 

1.00 

1.00 

Jmments: IND=Not Detected 

DEP Certification #s 32-00382 

1/a Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 1 of 1 
ENVIRONMENTAL SERVICE 

LABORATORIES. INC. 

HEADQUARTERS: EI SOUl"HERN DIVISION: 

SAMPLE REQUEST & CHAIN OF CUSTOD

1603 Philadelphia Sl 

Indiana, PA 15701 

(724) 463-TEST 

(724) 465-4209 

1276 Bentleyville Road 

Van Voorhis, PA 15366 

(724) 258-TEST 

(724) 258-6376 

FOR INTERNAL LABORATORY USE ONLY 

D P R ~:.:) :: R \/'1:-\-r i e,:;~ i\t Tr::: I\Fp·· < 4'"£· ( _ I\ I ~ """ 

COI\JTAH-.JER 

Sample Identification ESL# Matrix # of Containers 

TRIP BLANK I//) //)"),1'-j.........:::: 1.........:::: =--

, ____ 

~ 

--1 

THESE SERVICE CHARGES WILL ACCRUEATTHE RATE OF 1112% PER MONTH (1B'Yo PER ANNUM OR THE MAXIMUM AlLOWED BY LAW.) 

THE UNDERSIGNED PURCHASER AGREES TO PAY,IN THE EVENT HIS ACCOUNT BECOMES DELINQUENT AND IS TURNED OVER TO ANY 

ATIORNEY FOR COLLECTIOI-I. REASONABLEATIORNEY'S FEES PLUS ALL COURT AND ATIENDANT COLLECTION COSTS. 

•i)'lc 

r===~6~,~~~~~~~----------~·~LC~K7'~~--~~'--4' 

I ~u sfe'iBy ~e 6atel Jnme 

Date/ Time (Signature) 

N OF CUSTODY SEAL BROKEN: Yes No 

vwv 

-

vwv 2 

-

vwv 

-

vwv 

-

vwv 2 

-

vwv 

-

vwv 

-

vwv 2 

-

vwv 2 

-

Water 2 

Date/ Time 

f\1 

N N'A. I' 

N 

Container Type 

Preservative 

Plastic Liter 

none 

---

Plastic Liter 

none 

Plastic Liter 

HN03 

Plastic Liter 

H2so. 

---

Plastic Liter 

HN03 

Amber Glass L 

HCI 

Amber Glass L 

H2so. 

Amber VOA Vials 

none 

Amber VOA Vials 

HCI 

Amber VOA Vials 

HCI 

Phone: 

Fax: 

I~ C

·~ 
-- -- --- ..-.. - -- --- -- - - - ... !ill 'I:. ~ = =-=~ =. = = .e =--a:.. =-=- .z. = 

· • u \1 i i#i J iu nn r- iu ; .a ; • I 'W W' I I'-~ I .IW'I -I. 1• ·-

ERVICE LABORATORIES, INC. 

3 03 Philadelphia Street Indiana, PA 15 701 

'24)-463-TEST FAX (724)-465-4209 

Report of Analysis 

arne: 

ample Start Date: 

eceipt Date: 

eport Date: 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/12/2010 12:00 PM 

4/13/2010 4:27PM 

5/13/2010 

Analyte Analyst 

Acidity to pH=8.3 BF 

Alkalinity to pH=4.5 JML 

Biological Oxygen Demand 05 szc 

Chemical Oxygen Demand MAD 

Ammonia as N I Distilled ZTR 

Chloride ZTR 

Kjeldahl Nitrogen as N MAD 

pH (SM) LL 

Sulfate ASTM ZTR 

Total Nitrate+ Nitrite as N MAD 

Aluminum - ICP GJT 

Arsenic-ICP GJT 

Barium -ICP GJT 

Beryllium - ICP GJT 

Boron MAD 

Cadmium- ICP GJT 

Calcium- ICP GJT 

Chromium - ICP GJT 

Cobalt- ICP GJT 

Copper- ICP GJT 

Hardness GJT 

Analysis 

Date 

04/15/2010 

04/22/2010 

04/19/2010 

04/19/2010 

05/12/2010 

04/15/2010 

04/30/2010 

04/14/2010 

04/19/2010 

05/11/2010 

04/27/2010 

04/23/2010 

04/23/2010 

04/27/2010 

04/14/2010 

04/23/2010 

04/27/2010 

04/23/2010 

04/23/2010 

04/23/2010 

04/27/2010 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Sample 

Result 

10 10266 

Waste Water 

Grab 

CLIENT (Client) 

831608 Pit Water 

Units Method 

ND mg/1 as CaC03 SM2310B 

2523 mg/1 as CaC03 SM2320B 

732.0 mg/1 SM5210B 

9270.0 mg/1 SM5220 D 

34.98 mg/1 SM4500NH3B & I 

1869.1 mg/1 SM4500CIC 

18.3 mg/1 SM4500Norg-C,D 

9.51 su SM4500H-B 

140 mg/1 D516-02 

0.22 mg/1 SM4500N03E 

230.350 mg/1 200.7/6010 

ND mg/1 200.7/6010 

2.550 mg/1 200.7/6010 

ND mg/1 200.7/6010 

0.34 mg/1 SM4500B-B 

ND mg/1 200.7/6010 

1300.050 mg/1 200.7/6010 

0.350 mg/1 200.7/6010 

ND mg/1 200.7/6010 

1.200 mg/1 200.7/6010 

4433 mg/1 SM2340B 

RPL 

2 

20 

2.0 

2000.0 

0.90 

1.0 

5.1 

0.01 

50 

0.05 

0.500 

0.500 

0.250 

0.250 

0.25 

0.250 

25.000 

0.250 

0.250 

0.250 

I 

omments: Ethylene Glycol subcontracted to Metrohm-Peak Radiologicals done by Benchmark Analytical, PADEP 

Lab ID: 39-00401 

IND=Not Detected 

llote: DEP Certification #s 32-00382 

3ta Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect conta)ner. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 1 of 3 
---- --- .-,._ -- ------- :i\a~;;n~ ~e~,~~~iTA i I 

-·-I • , 1J •• I ...... 

~nr .. ~ ·-· 

I • I 1J ···-·- I -I • II ·-· ,_ 

ERVICE LABORATORIES, INC. 

m3 Philadelphia Street, Indiana, PA 15 701 

'24)-463-TEST FAX (724)-465-4209 

arne: 

Report of Analysis 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 10266 

Waste Water 

Grab 

1mple Start Date: 

eceipt Date: 

eport Date: 

Chesapeake Appalachia, LLC 

900 Pennsylvania A venue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/12/2010 12:00 PM 

4/13/2010 4:27PM 

5/13/2010 

Client Sample ID: 

CLIENT (Client) 

831608 Pit Water 

Analyte Analyst Analysis Sample Units Method 

Date Result 

Iron- ICP GJT 04/23/2010 1406.050 mg/1 200.7/6010 

Iron,Dissolved-ICP GJT 04/23/2010 0.700 mg/1 200.7/6010 

Lead-ICP GJT 04/23/2010 0.550 mg/1 200.7/6010 

Lithium- ICP GJT 04/23/2010 ND mg/1 200.7/6010 

Magnesium-ICP GJT 04/27/2010 288.250 mg/1 200.7/6010 

Manganese - ICP GJT 04/23/2010 33.700 mg/1 200.7/6010 

Mercury DRM 04/15/2010 ND mg/1 245.1 

Nickel- ICP GJT 04/23/2010 1.150 mg/1 200.7/6010 

Selenium-ICP GJT 04/23/2010 ND mg/1 200.7/6010 

Silver-ICP GJT 04/23/2010 ND mg/1 200.7/6010 

Sodium- ICP GJT 04/27/2010 1160.400 mg/1 200.7/6010 

Strontium - ICP GJT 04/27/2010 11.700 mg/1 200.7/6010 

Zinc- ICP GJT 04/23/2010 2.750 mg/1 200.7/6010 

Osmotic Pressure MAD 04/20/2010 109 mOs/kg OSP 

Detergents, MBAS TL 04/15/2010 5.080 mg/1 SM5540C 

Ethylene Glycol MetPea~ 04/19/2010 <25.000 mg/kg 300.0 M 

Oil and Grease - HEM CLM 04/27/2010 7.8 mg/1 1664A 

Phenolics, as Phenol MAD 04/29/2010 ND mg/1 420.1 

Specific Conductance LL 04/14/2010 4930 uS/em SM 2510B 

Total Dissolved Solids (TDS) LMB 2000 mg/1 SM2540C 

Total Suspended Solids I LMB I 04115/2010 I 122900 mg/1 SM2540D 

RPL 

0.500 

0.500 

0.250 

25.000 

25.000 

0.250 

0.0020 

0.250 

0.500 

0.250 

25.000 

0.500 

0.250 

100 

0.800 

25.000 

5.0 

0.500 

I 

25 

5 

omments: Ethylene Glycol subcontracted to Metrohm-Peak Radiologicals done by Benchmark Analytical, PADEP 

Lab ID: 39-00401 

IND=Not Detected 

Note: DEP Certification #s 32-00382 

gfa Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 2 of 3 
-- -- --- ....-....- -- --- --- - - =. =: = = =-=...--..:. .. = :e $ cr- =. =-=- s = 

•ru v ii#l .uun.nt-iu i ~ i • I 11 Y I I 'to. ........ I 11 I Y I-I 11 II .... 

)ERVICE LABORATORIES, INC. 

803 Philadelphia Street Indiana, PA 15 701 

724)-463-TEST FAX (724)-465-4209 

Report of Analysis 

fame: 

ample Start Date: 

~eceipt Date: 

~eport Date: 

Radiologicals 

1) Benzene 

47) Toluene 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/12/2010 12:00 PM 

4/13/2010 4:27PM 

5/13/2010 

Analyte Analyst 

enchma 

RO 

RO 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

04/22/2010 * 

04/14/2010 ND 

04/14/2010 18.50 

10 10266 

Waste Water 

Grab 

CLIENT (Client) 

831608 Pit Water 

Units Method 

mg/1 RAD-CTDHS 

ug/L 624/82608 

ug/L 624/82608 

RPL 

0.000 

10.00 

10.00 

)mments: Ethylene Glycol subcontracted to Metrohm-Peak Radiologicals done by Benchmark Analytical, PADEP 

Lab ID: 39-00401 

jND=Not Detected 

IJote: DEP Certification #s 32-00382 

1ta Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X= User defined data qualifier. 

Page 3 of 3 
:---=. = --• 11 --- a =r-"\1111.~-.. ......... - --=r e. e..-~ --- --

•~ .& - -

E 

!!!I ru \I 1 l#i Ji'\i nn ;..r i'U 1 a; -. . , .. , ~ ... , . -. . .. 

·-

)ERVICE LABORATORIES, INC. 

803 Philadelphia Street, Indiana, PA 15701 

724)-463-TEST FAX (724)-465-4209 

Report of Analysis 

~arne: 

:ample Start Date: 

leceipt Date: 

teport Date: 

I) Benzene 

47) Toluene 

Chesapeake Appalachia, LLC 

900 PeiUlsylvania A venue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/12/2010 

4/13/2010 4:27PM 

4/15/2010 

Analyte Analyst 

RO 

Analysis 

Date 

04/14/2010 

I RO I 04/14/2010 I 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Sample 

Result 

ND 

ND 

10 10267 

Waste Water 

Grab 

CLIENT (Client) 

Trip Blank 

Units Method 

ug/L 624/8260B 

ug!L 624/8260B 

RPL 

1.00 

1.00 

Jmments: 

IND=Not Detected 

DEP Certification #s 32-003 82 

lta Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected In both sample and methods blank. X= User defined data qualifier. 

Page 1 of 1 
L...l '~'-<j./'<--'-L ,..._,.___ 

LAB 10: 39-00401 

SEND DATA TO: 

NAME: Mike Moyer 

BENCHMARK ANAL YTICS, INC. 

4777 Saucon Creek Road 

Center Valley, PA 18034-9004 

PHONE (610) 974-8100 

FAX (610) 974-8104 

COMPANY: 

ADDRESS: 

Environmental Service Laboratories, Inc 

1803 Philadelphia St 

PHONE: 

FAX: 

Indiana, PA 15701 

(724) 463-8378 

(724) 465-4209 

TEST REPORT 

WO#: 

PAGE: 

PO#: 

PWSID# 

Work Order: 10042307 

10042307 

1 of 1 

DAS03152010 

1010268, 10 10266, 10 10102 

RECEIVED FOR LAB BY: MAK DATE: 04/16/2010 8:35 Page I of l 

SAMPLE: 10 10266 

SAMPLED BY: Client 

:rrn . 

Gross Alpha 

Gross Beta 

REMARKS: 

Lab 10: 1 0042307-002A Grab 

Sample Tlme 04/121201012:00 

Result Uncert. MDA Units 

3022 ± 676.6 1058.00 pCUL 

4172 ± 404.4 717.70 pCi/L 

Method 

EPA900.0 

EPA900.0 

MCL Analysis Start Analysis End Analyst * 

04/19/10 8:55 04122/10 BPS-CV 

04/19/1 o 8:55 04122/10 BPS-CV 

!he a~ove test procedure~ meet all the requirements of NELAC and relate only to these samples. 

CV- Benchmark Analytics, Inc. Center Valley, PA; SA= Benchmark Analytics, Inc. Sayre, PA 

MANAGER ----~-----= -- ~~~~·--____________________ DATE: ----~_20 0 ____ _ 
ENVIRONMENTAL SERVICE 

LABORATORIES. INC. SAMPLE REQUEST & CHAIN OF CUSTOD

HEADQUARTERS: 

1 803 Philadelphia Sl 

Indiana, PA 15701 

(724) 463-TEST 

(724) 465-4209 

1276 BenUeyville Road 

Van Voorhis, PA 15366 

(724) 258-TEST 

(724) 258-8376 

FOR INTERNAL LABORATORY USE ONLY 

D P f~ E ~st \/ /\·r·! ~~-~ TE.iv1P < 4oC 

COi'·

JTAI\'~ER ~ R

f'-l N NiA 

N 

Sample Identification I ESL# Matrix # of Containers Container Type 

TRIP BlANK 1//1 //) ')~1-=== , __ ~ 

~ 

~ 

THESE SERVICE CHARGES Will. ACCRUE AT THE RATE OF 1 112% PER MONTH (18% PER ANNUM OR THE MAXIMUM ALLOWED BY LAW.) 

UNDERSIGNED PURCHASER AGREES TO PAY, IN THE EVENT HIS ACCOUNT BECOMES DEUNQUENT AND IS TURNED OVER TO ANY 

FOR COlLECTION. REASONABLE ATIORNEY'S FEES PLUS ALL COURT AND ATIENDANT COLLECTION COSTS. 

4-- C(- [{) 15'30 

() 

Date/ Time 

OF CUSTODY SEAL BROKEN: Yes No 

WIV 

-

WIV 2 

-

WIV 

-

ww 

-

WIV 2 

-

WIV 

-

WIV 

-

ww 2 

-

WIV 2 

-

Water 2 

uateJ Time 

PresetVative 

Plastic Liter 

none 

- --

Plastic Liter 

none 

Plastic Liter 

HN03 

Plastic Liter 

Hzso. 

Plastic Liter 

HN03 

Amber Glass L 

HCI 

Amber Glass L 

H2so. 

Amber VOA Vials 

none 

Amber VOA Vials 

HCI 

Amber VOA Vials 
- -- --- ~ - -- --- -- - - 101:1, =·:Jill..,..,.~~=--=--=-=- & = ~;;~;;;;::a,_:;r ~-... =a;;!'!!!!!!!!l;"-;;;; ;'Wt. = . -,. . --.. . -...... - . -. -. I .. 1J' II'~ I ........... II ·-

:RVICE LABORATORIES, INC. 

03 Philadelphia Street Indiana, PA 15 701 

24)-463-TEST FAX (724)-465-4209 

Report of Analysis 

tme: 

mple Start Date: 

:ceipt Date: 

~port Date: 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/9/2010 3:30PM 

4/13/2010 4:37PM 

5/20/2010 

Analyte Analyst 

Acidity to pH=8.3 BF 

Alkalinity to pH=4.5 JML 

Biological Oxygen Demand 05 szc 

Chemical Oxygen Demand MAD 

Ammonia as N I Distilled MAD 

Chloride ZTR 

Kjeldahl Nitrogen as N MAD 

pH(SM) LL 

Sulfate ASTM ZTR 

Total Nitrate+ Nitrite as N MAD 

Alwninurn - ICP GJT 

Arsenic-ICP GJT 

Bariwn- ICP GJT 

Beryllium - ICP GJT 

Boron MAD 

Cadmium- ICP GJT 

Calcium- ICP GJT 

Chromium - ICP GJT 

Cobalt- ICP GJT 

Copper- ICP GJT 

Hardness GJT 

Analysis 

Date 

04/15/2010 

04/22/2010 

04/19/2010 

04/19/2010 

05/04/2010 

04/15/2010 

04/30/2010 

04/14/2010 

04/19/2010 

05/11/2010 

04/27/2010 

04/23/2010 

04/23/2010 

04/27/2010 

04114/2010 

04/23/2010 

04/27/2010 

04/23/2010 

04/23/2010 

04/23/2010 

04/27/2010 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Sample 

Result 

10 10268 

Waste Water 

Grab 

CLIENT (Client) 

627377 Pit Water 

Units Method 

ND mg/1 as CaC03 SM2310B 

664 mg/1 as CaC03 SM2320B 

162.0 mg/1 SM5210B 

1215.0 mg/1 SM5220 D 

5.05 mg/1 SM4500NH3B & I 

23468.6 mg/1 SM4500CIC 

18 .8 mg/1 SM4500Norg-C,D 

11.67 su SM 4500H-B 

525 mg/1 D516-02 

ND mg/1 SM4500N03E 

9.850 mg/1 200.7/6010 

ND mg/1 200.7/6010 

3.950 mg/1 200.7/6010 

ND mgll 200.7/6010 

ND mg/1 SM 45008-B 

ND mg/1 200.7/6010 

677.750 mg/1 200.7/6010 

ND mg/1 200.7/6010 

ND mg/1 200.7/6010 

ND mg/1 200.7/6010 

1692 mg/1 SM2340B 

RPL 

2 

20 

2.0 

200.0 

0.08 

1.0 

4.9 

0.01 

125 

0.05 

0.500 

0.500 

0.250 

0.250 

0.25 

0.250 

25.000 

0.250 

0.250 

0.250 

1 

1mments: Ethylene Glycol subcontracted to Metrohrn-Peak Dilutions utilized for BOD analysis did not meet 

laboratories acceptance criteria of at least 2 mg/L depletion (loss) Radiologicals done by Benchmark 

Analytical, PADEP Lab ID: 39-00401 

jND=Not Detected 

~ote: DEP Certification #s 32-00382 

1ta Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

8 = Analyte was detected in both sample and methods blank. X= User defined data qualifier. 

Pace 1 of 3 
-- -- --- ...-.... - -- --- -- - - • =._ Ill '1:. •• =-""=l~ &. II .. .1t1 ...- 11:. ·~ & 1: 

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ERVICE LABORATORIES, INC. 

303 Philadelphia Street, Indiana, PA 15 701 

'24)-463-TEST FAX (724)-465-4209 

Report of Analysis 

arne: 

tmp1e Start Date: 

eceipt Date: 

eport Date: 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/9/2010 3:30PM 

4/13/2010 4:37PM 

5/20/2010 

Analyte Analyst 

Iron- ICP GJT 

lron,Dissolved-ICP GJT 

Lead-ICP GJT 

Lithium - ICP GJT 

Magnesiwn-ICP GJT 

Manganese- ICP GJT 

Mercury DRM 

Nickel- ICP GJT 

Selenium-ICP GJT 

Silver-ICP GJT 

Sodium- ICP GJT 

Strontium - ICP GJT 

Zinc- ICP GJT 

Osmotic Pressure MAD 

Detergents, MBAS TL 

Ethylene Glycol MetPeak 

Oil and Grease - HEM CLM 

Phenolics, as Phenol AID 

Specific Conductance LL 

Total Dissolved Solids (TDS) LMB 

Total Suspended Solids LMB 

Analysis 

Date 

04/23/2010 

04/23/2010 

04/23/2010 

04/27/2010 

04/27/2010 

04/23/2010 

04/15/2010 

04/23/2010 

04/23/2010 

04/23/2010 

04/27/2010 

04/27/2010 

04/23/2010 

04/20/2010 

04/15/2010 

04/19/2010 

04/27/2010 

05/17/2010 

04/14/2010 

04/15/2010 

04/15/2010 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Sample 

Result 

13 .800 

0.550 

ND 

ND 

ND 

0.300 

ND 

ND 

ND 

ND 

15726.000 

31.550 

ND 

10 10268 

Waste Water 

Grab 

CLIENT (Client) 

627377 Pit Water 

Units Method 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 245.1 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

mg/1 200.7/6010 

1225 mOslkg OSP 

7.880 mg/1 SM5540C 

<26.00 mglkg 300.0 M 

ND mg/1 1664A 

ND mg/1 420.1 

59800 uS/em SM 2510B 

39500 mg/1 SM2540C 

476 mgll SM2540D 

RPL 

0.500 

0.500 

0.250 

25.000 

25.000 

0.250 

0.0020 

0.250 

0.500 

0.250 

500.000 

0.500 

0.250 

100 

0.800 

5.000 

5.0 

0.500 

1 

25 

5 

omments: Ethylene Glycol subcontracted to Metrohm-Peak Dilutions utilized for BOD analysis did not meet 

laboratories acceptance criteria of at least 2 mg/L depletion (loss) Radiologicals done by Benchmark 

Analytical, PADEP Lab ID: 39-00401 

IND=Not Detected 

Note: DEP Certification #s 32-00382 

:~ta Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Paae 2 of 3 
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:RVICE LABORATORIES, INC. 

l03 Philadelphia Street Indiana, PA 15701 

24)-463-TEST FAX (724)-465-4209 

Report of Analysis 

1me: 

mple Start Date: 

:ceipt Date: 

:port Date: 

Radiologicals 

1) Benzene 

47) Toluene 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/9/2010 3:30PM 

4/13/2010 4:37PM 

5/20/2010 

Analyte Analyst 

enchmru 

RO 

RO 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

04/22/2010 * 

04/14/2010 ND 

04/14/2010 18.20 

10 10268 

Waste Water 

Grab 

CLIENT (Client) 

627377 Pit Water 

Units Method 

mg/1 RAD-CTDHS 

ug/L 624/8260B 

ug/L 624/8260B 

RPL 

0.000 

10.00 

10.00 

mments: Ethylene Glycol subcontracted to Metrohm-Peak Dilutions utilized for BOD analysis did not meet 

laboratories acceptance criteria of at least 2 mg/L depletion (loss) Radiologicals done by Benchmark 

Analytical, PADEP Lab ID: 39-00401 

IND=Not Detected 

lote: DEP Certification #s 32-00382 

ta Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Paoe 3 of 3 
C1?e5clp~ t'e 

LAB ID: 39-00401 

SEND DATA TO: 

NAME: Mike Moyer 

BENCHMARK ANAL YTICS, INC. 

4777 Saucon Creek Road _ 

Center Valley, PA 18034-9004 

PHONE (610) 974-8100 

FAX (61 0) 974-8104 

COMPANY: 

ADDRESS: 

Environmental Service Laboratories, Inc 

1803 Philadelphia St 

PHONE: 

FAX: 

Indiana, PA 15701 

(724) 463-8378 

(724) 465-4209 

TEST REPORT 

WO#: 

PAGE: 

PO#: 

PWS ID# 

Work Order: 10042307 

10042307 

1 of 1 

DAS03152010 

10 10268, 10 10266, 10 10102 

RECEIVED FOR LAB BY: MAK DATE: 04/16/2010 8:35 Page 1 ofl 

SAMPLE: 1010268 

SAMPLED BY: Client 

:wt . 

Gross Alpha 

Gross Beta 

REMARKS: 

Lab ID: 10042307-00tA Grab 

Sample Time 04/09/2010 15:30 

Result ~ MQ& Units 

126.1 ± 128.4 473.60 pCi/L 

1295 ± 166.6 352.40 pCVL 

Method 

EPA 900.0 

EPA900.0 

MCL Analvsls Start Anarvs'is End Analvst • 

04/19/10 8:55 04/22110 BPS-CV 

04/19/10 8:55 04122/10 BPS-CV 

The above test procedures meet all the requirements of NELAC and relate only ~o these samples. 

* cv =Benchmark Analytics, Inc. Center Valley, PA; SA= Benchmark Analyt1cs, Inc. Sayre, PA 

MANAGER ----------~~~~~~~· ____________________ DATE: --~5.~~a~Ol~O ____ _ 
---=. --=:. ~==""""'=~~==:a~=. --- ........ - -- --- •--- e - = - "'rd \II~~ Jii'\; i\li r i'\1 I a i 

.................................... 

;ERVICE LABORATORIES, INC. 

803 Philadelphia Street Indiana, PA 15 701 

724)-463-TEST FAX (724)-465-4209 

Report of Analysis 

a me: 

ample Start Date: 

eceipt Date: 

eport Date: 

1) Benzene 

47) Toluene 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

4/9/2010 

4/13/2010 4:37PM 

4/15/2010 

Analyte Analyst 

RO 

RO 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

04/14/2010 ND 

04/14/2010 ND 

10 10269 

Waste Water 

Grab 

CLIENT (Client) 

Trip Blank 

Units Method 

ug/L 624/8260B 

ug/L 624/8260B 

RPL 

1.00 

1.00 

mments: 

jND=Not Detected 

DEP Certification #s 32-00382 

'a Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X= User defined data qualifier. 

Page 1 of 1 
ENVIRONMENTAL SERVICE 

LABORATORIES. INC. SAMPLE REQUEST & CHAIN 

HEADQUARTERS: 

1 803 Philadelphia Sl 

Indiana, PA 15701 

(724) 463-TEST 

(724) 46>4209 

SOUlliERN DMSION: 

1276 BenHeyville Road 

Van Voorhis, PA 15366 

(724) 258-TEST 

(724) 258-8376 

FOR INTERNAL LABORATORY USE ONLY 

Sample Identification ESL# 

TRIP BLANK 1/ /} / h'77..f::'l ,..........-- ow 1---

D 

1_. 

~ 

--I 

I . THESE SERVICE CHARGES WILL ACCRUE AT THE RATE OF I 112% PER MONTH (18,., PER ANNUM OR THE MAXIMUM ALLOWED BY LAW.) 

THE UNDERSIGNED PURCHASER AGREES TO PAY, IN THE EVENT HIS ACCOUNT BECOMES DEUNQUENT AND IS TURNED OVER TO ANY 

ATIORNEY FOR COLLECTION .. REASONABLE ATIORNEY'S FEES PLUS ALL COURT AND ATIENDANT COLLECTION COSTS. 

4 .. / :;-- 10 rso o 

5 

Date/ Time 

N OF CUSTODY SEAL BROKEN: Yes No ~ f~ E ~~3 t:; F\\/t~lTi C/ f\! TEMP ::::: ·4°C N C()t\J'u ll\ co .,...\...-! . I, ,,! .Jl_! \ Matrix # of Containers WN -WN .,t'3 -WN -iNw -WN 2 -WN -WN -WN 2 -WN 2 -Water 2 N Container Type Preservative Plastic Liter none Plastic Liter none Plastic Liter HN03 Plastic Liter H2SO, Plastic Liter HN03 Amber Glass L HCI Amber Glass L H2SO, Amber VOA Vials none Amber VOA Vials HCI Amber VOA Vials HCI Company/Name: Person: f' I I

. -.u

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