.~

~c~ ian 4, Re ~ 35

Emission Factor Develop for Stack Testinct of Scrubber Stack at Boral Bricks, Henderson Plant in F'ebruarv, 1996 by METCO ~ Kiln 1 Schedule: 42 cars/day 

### P~ 2
2,916 brick/car Brick Weight: 4.10 Ib/fired brick (verified by quality control reports)

= 42 saF 2,916 brisk 4.1 Ib I d ay I ton

day ~ saF brisk 1 24 hr 1 2000 Ib

= 10.46 ton/hr
Kiln 2 Schedule: 42 cars/day 2,955 brick/car Brick Weight: 4.10 Ib/fired brick (verified by quality control reports) Emission Factor DevelopmeM- _ 

# 1 _ O 

# 19

r; , j j

Total = 42 eaF 2,955 bask 4.1 Ib I day I ton day saf brisk 1 24 hr 1 2000 Ib

= 10.60 ton/hr

= 21.06 ton/hr
Emission Factor Develoament:

filterrable PM = [ Average Emission Rate (Ib PM / hr) ] [ Kiln Throughput (ton / hr) ]

= 10.19 Ib 1:w

kf 21.06 ton

filterable PM = 0.48 Ib/ton
Emission Factor Summary:

Pollutant Avg. Emission Rate Avg. Emission Factor PM 10.19 Ib/hr 0.48 Ib/ton NO,, 7.2 Ib/hr 0.34 Ib/ton HF(inlet) 14.501b/hr 0.691b/ton HF 0.95 Ib/hr 0.045 Ib/ton
Notes:

# T F i 

# MET: EnURonnTdTAC 

# o
P.O. Box 598

~ Addison. TX 75001 (214) 931-7127



### SOURCE EMISSIONS SURVEY



### OF BORAL BRICKS, INC. ABSORBER STACK (EPN-K) AND ABSORBER INLET DUCT HENDERSON, TEXAS
FEBRUARY 1996

FILE NUMBER 96-30 6

### ~ FMEEO 

## - Ermi ~~~



### TABLE OF CONTENTS


### PAGE 1 2 6 8 

### 11 15 16 INTRODUCTION SUMMARY OF RESULTS DISCUSSION OF RESULTS 

### DESCRIPTION OF SAMPLING LOCATIONS SAMPLING AND ANALYTICAL PROCEDURES DESCRIPTION OF TESTS APPENDICES A. Location of Sampling Points B. Source Emissions Calculations 

### C. Calibration Data D. Field Testing Data 

### E. Analytical Data F. Reference Method Monitor Data G. Chain of Custody H. Resumes of Test Personnel

96-30~

,

~ ~ 

# Vo

~

SOURCE EMISSIONS SURVEY BORAL BRICKS, INC. ABSORBER STACK (EPN-K) AND ABSORBER INLET DUCT 

## HENDERSON,TEXAS FILE NUMBER 96-30
INTRODUCTION 

### METCO Environmental, Dallas, Texas, conducted a source emissions survey of Borat Bricks, Inc., (ocated in Henderson, Texas, on February 14 and 15, 1996. The purpose of these tests was to determine the concentrations of particulate matter, hydrogen fluoride, and oxides of nitrogen being emitted to the atmosphere via the Absorber Stack (EPN-K). The concentrations of hydrogen fluoride were also determined at the Absorber Inlet Duct. The sampling followed the procedures set forth in the Appendix to the Code of Federal 

### Regulations, Title 40, Chapter I, Part 60, Methods 1, 2, 313, 4, 5, 7E, and 1313; and in the "Sampling Procedures Manual, Texas Air Control Board, Revised July 1985."

96-30

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# 3 O „ ~ 

# O co Q a E w 96-30 -2- 

# ~

# ri 

# MErco

SUMMARY OF RESULTS Absorber Stack (EPN-K)

' 29.92 "Hg, 68°F (760 mm Hg, 20°C)
96-30 -3- / 

### ~ Run Number 1 2 3

Date 02115/96 02115/96 0?J15/96 Time 0851-1005 1053-1207 1246-1400 Stack Flow Rate - ACFM 74

, 664 78 770 76 460 Stack Flow Rate - DSCFM' 40

, 417 42

, 890 41

, 675 % Water Va r-% Vol. 7.07 6.18 5.92 % CO -% Vol. 22 2.3 2.3 % -%Vol. 16.4 16.6 16.5 9

~ ° Excess Air 0 Sam lin Point 317 339 329 Stadc Tem erature -°F 436 440 441 Stack Pressure -'H 29.47 29.49 29.47 Percent Isokinetic 101.7 98.4 99.2 Volume D ry

Gas Sam led - DSCF' 39.123 40.159 39.339 Particulate Matter Emissions Probe & Filter Catch rains/dscf* 0.0252 0.0217 0.0260 rains/cf @ Stack Conditions 0.0136 0.0118 0.0141 Ibslhr 8.74 7.99 9.28 Tota1 Catch rains/dscf' 0.0313 0.0268 0.0277 rains/cf 0 Stack Conditions 0.0169 0.0145 0.0150 Ibs/hr 10.83 9.85 9.88 H dro en Fluoride - ,qg 6 , 980.4 6 , 521.7 6

, 942.9 H dro en Fluoride Emissions - m 7.6 6.9 7.5 H dro en Fluoride Emissions - Ibs/hr 0.95 0.92 0.97

# MeK:O.-

SUMMARY OF RESULTS

96-30 -4- 

# ~ Run Number Absorber Stack (EPN-K) 1 2 3 Oxides of Nitro en Emissions - m 23.6 24.2 24.8 Oxides of Nitro en Emissions - Ibs/hr 6.83 7.44 7.40 jl

### ~ 

# MElR,'.
- -O- r::rmAjtr6FP

~

SUMMARY OF RESULTS
Absorber Inlet Duct Run Number 1 2 3 Date 02/15/96 02/15/96 02/15/96 Time 0851-1003 1053-1205 1246-1358 % Water Va or -% Vol. 6.21 6.48 6.29 Volume Dry Gas Sam led - DSCF* 27.923 28.043 28.142 H dro en Fluoride - mg 82.044 70.517 68.976 H dro en Fluoride Concentrations - ppm 124.6 106.7 104.0 H dro en Fluoride Concentrations -Ibs/hr** 1 15.71 1 14.27 13.51 * 29.92'Hg, 68°F (760 mm Hg, 20°C) 

### *" Calculated using the flow rate measured during the corresponding tests on the Absorber Stack (EPN-tq.

96-30 

### -5- /

### r 

# l 

# p k:zellm ~ o

-7- 1



### DISCUSSION OF RESULTS

Bbsorber Stack (EPN-K) 

### The three tests for particulate matter, hydrogen fluoride, and oxides of nitrogen appeared to be valid representations of the actual emissions during the tests. AII leak checks performed on the sampling train, the pitot tubes, and the monitor sampling system showed no leaks before or after each test. The zero and calibration drift tests of the monitor were stable with no variations greater than 3.0 percent. The calibration error check, sampling system bias check, and NO 2 to NO conversion efficiency check performed on the reference method monitor prior to testing were valid. The indicative 

### parameters calculated from the field data were in close agreement. The moisture percentages for the three tests were within 10.6 percent of the mean value. The 

### measured flow rates (Q S ) for the tests were within 3.0 percent of the mean value. The rates of sampling for the three tests were within the spec'rfied limits (90 to 110 percent isokinetic). The greatest deviation from 100 percent isokinetic was 1.7 percent. 

### The calculated emissions (pounds per hour) of particulate matter for the three tests showed a range of -3.3 percent to +6.3 percent variation from the mean value. The calculated emissions (pounds per hour) of hydrogen fluoride for the three tests 

### showed a range of -2.8 percent to +2.5 percent variation from the mean value. The calculated emissions (pounds per hour) of oxides of nitrogen for the three tests 

### showed a range of -5.4 percent to +3.0 percent variation from the mean value.

96-30 -6-

# ~ M 

# E TO ~

Absorber Inlet Duct 

### The three tests for hydrogen fluoride appeared to be valid representations of the actual concentrations during the tests. AII leak checks performed on the sampling train showed no leaks before or after each test. The indicative parameters calculated from the field data were in close agreement. The moisture percentages for the three tests were within 2.4 percent of the mean value. 

### The calculated concentrations (pounds per hour) of hydrogen fluoride for the three tests 

### showed a range of -6.8 percent to +8.4 percent variation from the mean value.

96-30 -7- 

## ~

# ~ 

# Elm

~ 

# rco

DESCRIPTION OF SAMPLING LOCATIONS 

### The sampling location on the Absorber Stack (EPN-K) is 90 feet 6 inches above the ground. The sampling ports are located 40 feet (6.73 stack diameters) downstream from a constriction in the stack and 6 feet 5 1/2 inches (1.09 stack diameters) upstream from the outlet of the stack. 

### The sampling location on the Absorber Inlet Duct is approximately 30 feet above the ground. The sampling port is located in a transition zone of the inlet duct:



## b

96-30 -8 I

# ~ 

# METCOOPC

# MF-TCO

SAMPLING LOCATION
Absorber Inlet Duct



# 0 0

0 C9

Not to Scale 96-30 -10- 

# ~

# , MEMO.

SAMPLING AND ANALYTICAL PROCEDURES The sampling followed the procedures set forth in the Appendix to the Code of Federal 

### Regulations, Title 40, Chapter I, Part 60, Methods 1, 2, 313, 4, 5, 7E, and 1313; and in the °Sampling Procedures Manual, Texas Air Control Board, Revised July 1985. 0 A preliminary velocity traverse was made at each of the two ports on the Absorber Stack (EPN-K), in order to.determine the uniformity and magnitude of the flow prior to _ 

### testing. Several traverse points were checked for cyclonic flow and none was found to be present. Twelve traverse points were sampled from each of the two ports for a total of twenty-four traverse points. 

### The sampling trains were leak-checked at the nozzle at 15 inches of inercury vacuum before each test, and again after each test at the highest vacuum reading recorded during the test. This was done to predetermine the possibility of a diluted sample. 

### The pitot tube lines were checked for leaks before and after each test under both a vacuum and a pressure. The lines were also checked for clearance and the manometer was zeroed before each test. 

### An integrated orsat sample was collected and analyzed according to EPA Method 3B during each test on the stack.

96-30 -11- 

# ~~

# MEFC 

# O EnkA ~



### particulate Matter and Hydroaen Fluoride 

### Triplicate samples for particulate matter and hydrogen fluoride were collected on the stack. The samples were taken according to EPA Methods 1, 2, 3B, 4, 5, and 13B; and the "Sampling Procedures Manual, Texas Air Control Board, Revised July 1985." For each run, samples of three-minute duration were taken isokinetically at each of the twenty-four traverse points for a total sampling time of 72 minutes. Reagent blanks were submitted. 

### The " front-half " of the sampling train contained the following components: Stainless Steel Nozzle Heated Glass Probe @ 248°F t 25°F Heated Quartz Fiber Filter and Teflon Support @ 248°F t 25°F 

### The " back-half " of the sampling train contained the following components: Impinger 

### Number Contents 

### Amoljpf Parameter Collected 

### 1 HPLC Water 100 ml Particulate Matter and Hydrogen Fluoride 

### 2 HPLC Water 100 ml Particulate Matter and Hydrogen Fluoride 3 Empty -------- Moisture 4 Silica Gel 200 g Moisture 

### Particulate matter emissions were calculated from gravimetric analysis using both the " front-half ° and " back-half ° collections of the sampling train. 

## The hydrogen fluoride samples were analyzed by ion chromatography.
96-30 -12- /
~ 71 ;

# ri 

# MEFCO

Hvdroaen Fluoride Triplicate samples for hydrogen.fluoride were collected on the inlet duct. The samples 

### were taken according to EPA Methods 4 and 13B; and the `Sampling Procedures Manual, Texas Air Control Board, Revised July 1985." For each run, samples of twenty-four minute duration were taken isokinetically at each of the three traverse points for a total sampling time of 72 minutes. Data was recorded at five-minute intervals. Reagent blanks were submitted. 

### The " front-half " of the sampling train contained the following components: Heated Glass Probe @ 248°F t 25°F 

### Heated Glass Fiber Filter and Glass Support @ 248°F t 25°F The " back-half ` of the sampling train contained the following components: 

## 0 Impinger

Number Contents Anfoupt Parameter Collected 1 HPLC Water 200 ml Hydrogen Fluoride 2 HPLC Water 200 ml Hydrogen Fluoride 3 HPLC Water 200 ml Hydrogen Fluoride 4 Empty -------- Moisture 5 Silica Gel 200 g Moisture 

### The hydrogen fluoride samples were analyzed by ion chromatography.

96-30 -13- l 

### ~

# q ;- EIMER] '.0 ---i

Qxides of Nitrooep



### The oxides of nitrogen sampling was performed according to EPA Method 7E. A Thermo Environmental Model 10S Oxides of Nitrogen Analyzer (Serial Number 10S-49429-282) was used to monitor the concentrations of oxides of nitrogen during each run. The reference method analyzer was operated at a range of 0 to 100 parts per million. A multi-point calibration was perFormed on the reference method analyzer prior to testing. 'An analyzer calibration error check, a sampling system bias check, and 

### a NO 2 to NO conversion efficiency check were also conducted prior to testing. 

### After each run, the zero and calibration drift of the reference method monitor was checked. The calibration gases were as follows: Zero Nitrogen 

### 18.7 ppm NO in N 2 (ALM 40839) 46.2 ppm NO in N 2 (BAL 1881) 85.4 ppm NO in N 2

(ALM 38783) The reference method sampling system consisted of a heated probe, a heated glass fiber filter, a chilled condenser, and a teflon sample line. The calibration gases for the bias and drift checks were introduced upstream of the chilled condenser. Calibration gas certifications are included in Appendix G.

96-30 -14-

# ~ 

# ; 71 ~~

DESCRIPTION OF TESTS 

### Personnel from METCO Environmental arrived at the plant at 1:45 p.m. on Wednesday, February 14, 1996. After meeting with plant personnel, the equipment was moved onto the Absorber Stack (EPN-K) and Inlet Duct. The equipment was secured for the night and all work was completed at 5:30 p.m. On Thursday, February 15, work began at 7:00 a.m. The monitor was calibrated and the equipment was prepared for testing. The preliminary data was collected. The first set of tests for particulate matter, hydrogen fluoride, and oxides of nitrogen on the Absorber Stack (EPN-K) began at 8:51 a.m. Testing continued until the completion of the third set of tests at 2:00 p.m. The first test for hydrogen fluoride on the Absorber 

### Inlet Duct began at 8:51 a.m. Testing continued until the completion of the third test at 

### 0 1:58 p.m. 

### The monitor was calibrated and secured for transport. The equipment was moved off of the sampling locations and loaded into the sampling van. The samples were recovered and transported to METCO Environmental's laboratory in Dallas, Texas, for analysis and evaluation. Operations at Boral Bricks, Inc., Absorber Stack (EPN-K) and Inlet Duct ; located in Henderson, Texas, were completed at 4:15 p.m. on Thursday, February 15, 1996. 

# A?

. Billy J. ullins, Jr., P.E. President 96-30 -15- ~ p~

### ~

~ ~.

k 

# MEMO

APPENDICES
A. Location of Sampling Points B. Source Emissions Calculations 

### C. Calibration Data D. Field Testing Data 

### E. Analytical Data F. Reference Method Monitor Data G. Chain of Custody H. Resumes of Test Personnel

96-30 -16- I 

# ~

### ~

. . 

# ~ 

# MEMO

~ 

### APPENDIX A Location of Sampling Points Absorber Stack (EPN-K) 

### The sampling ports are located 40 feet (6.73 stack diameters) downstream from a constriction in the stack and 6 feet 5 1/2 inches (1.09 stack diameters) upstream from the outlet of the stack. The locations of the sampling points were calculated as follows:
Port and Wall Thickness = 61/4 inches Inside Stack Diameter = 71 3/8 inches
Point Number Percent of Diameter From Wall Distance From Wall 1 2.1 1 1/2 ° .2 6.7 4 13/16 ° 3 11.8 8 7/16 ° 4 17.7 12 5/8 ° 5 25.0 17 7/8 ° 6 35.6 25 7/16 ° 7 64.4 45 15/16 ° 8 75.0 53 1 /2 ° 9 82.3 58 3/4 " 10 88.2 62 15/16 " 11 93.3 66 9/16 ° 12 97.9 69 7/8 °

.s .M A-1 

# ~

# ~ 

# ElfT1ET
~ 

# Q

APPENDIX A Location of Sampling Points Absorber Stack (EPN-K)

• -

~ ~ •

•



### .. . • . . . • • . ..

96-30 A-2 l~ 

# MEFCO. ErmRoryrEMAL

APPENDIX A Location of Sampling Points Absorber Inlet Duct 

### The sampling port is located in a transition zone of the duct. The locations of the sampling points were calculated as follows:

Sample points 14' 12' 

### 10'

~ 

### Inlets ~ 

# O O

R~ 

### Angled probe to catch . 

### gas stream 

# ~ Hatch with port

Not to Scale 96-30 A-3 CA W)

# n METCOI



### APPENDIX B

I 

### Nomenclature and Equations 

## for Calculation of Source Emissions



### B-1 

## ~

# ,7 pEKo- 1m

NOMENCLATURE FOR CALCULATIONS English Metric 

### S,vmbol Units units Descri tion A. in. 2 m 2 Stack Area 

### C a „ gr/dscf* g/dscm* Particulate - probe, cyclone, and filter C ao gr/dscf* g/dscm* Particulate - total

gr/CF C~ 

### @ stack g/m 3 Particulate - probe, cyclone, and filter

conditions gr/CF C 8U C~ 

### stack g/m 3 Particulate - total

conditions 

### C aW Ibs/hr kg/hr Particulate - probe, cyclone, and filter C 'X Ibs/hr kg/hr Particulate - total C P Pitot Tube Calibration Factor D n in. m Sampling Nozzle Diameter %EA Percent Excess Air at sampling point g 32.174 ft/sec 2 Acceleration of Gravity %I Percent Isokinetic %M Percent Moisture in the stack gas by 

### volume M d Mole fraction of dry gas


### m f mg mg Particulate - probe, cyclone, and filter * 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-2r, 

# MEr

~ 

# o.

English Metric Svmbol Units Units pescri tion M watef 18 Ib/Ib-mole Molecular Weight of water 

### m, mg mg Particulate - total MW Ib/Ib-mole g/g-mole Molecular Weight of stack gas MW ak 28.96 Ib/ Molecular Weight of air

Ib-mole MW d Ib/Ib-mole g/g-mole Molecular Weight of dry stack gas P b "Hg mm Hg Barometric Pressure

Absolute P m "H 2 0 mm H 2 0 Orifice Pressure drop P S "H 

### g

Absoiute mm Hg Stack Pressure
OP "H 2 0 mm H 2 0 Velocity Head of stack gas P,td 29.92 "Hg 760 mm Hg Standard Barometric Pressure 

### Q a ACFM m 3 /hr Stack Gas Volume at actual stack conditions Q s DSCFM* dscm/hr* Stack Gas Volume at 29.92 "Hg, 528 0 R, dry R 21.83 "Hg- Universal Gas Constant ft 3 /Ib-mole° R T m ' F °C Average Gas Meter Temperature

* 29.92 "Hg, 68 0 F (760 tnm Hg, 20°C) B-3-, 

# MEI

0 English Metric



### Symbol 

## lJnb unb T, min min T 9 ° F °C T, td 528 0

R 293°K 

## V m ft 3 m 3
Vmstd dscf* dscm*
V s fpm m/sec 

## V W ml ml

Vw 9 ", scf* scm* pair 0.07521bS/ft 3 pWater 1 g/m I pman 62.321bs/ft 3 Descri t ~ on Net time of test 

### Stack Temperature Standard Temperature Volume of dry gas sampled @ meter conditions 

### Volume of dry gas sampled @ standard conditions Stack velocity @ stack conditions Total water collected in impingers and silica gel Volume of water vapor collected @ standard conditions Density of Air Density of Water Density of Manometer Fluid Standard Conditions: 29.92 "Hg, 68°F (760 mm Hg, 20°C)

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-4 

# ~■n 

# EIMER.
- .0-

EXAMPLE CALCULATIONS 

### 1. Volume of dry gas sampled at standard conditions.*

F b + Pm Vm sb = Vm TSw 

### 13.6 

# I T,,, + 460 

### Pstd
f , b + Pm Vm =

. 1765 

### Vm 13.6 

### = dscf std T

m + 460 

### Vmstd = dscf x 0.028317 = 

### dscm 

## f'i 2. Volume of water vapor collected at standard conditions.*

_ ( V w - gms 

### S0

2 - gms H 2 S) p,

~ t ~ R Tstd 

### Vwyas P M 453.6 std water 

### Vw gas = 0.0472 

### (V

w - gms S0

2 - gms H

2 S) = scf
Vw g . = scf x 0.028317 = 

### scm
3. Percent moisture in stack gas.


### %M = Vw9W 

### x 100 = %

Vmstd + Vwgas


### * 29.92 °Hg, 68°F (760 mm Hg, 20°C) B-5 

### o~ 7

# El~~

4. _:= Mole fraction of dry gas.

_ 100 - %M Md 100 

### 5. Average molecular weight of dry stack gas. MW 

# 1 0/0 

### COx 44 

### +%Ox 32 +%N x 

# d 28 +%CDx

28 Ibllb-mole d2 100 2 100 2 100 

### = g/g-mole 6. Molecular weight of stack gas.


### MW = MW

d x M d + 18 (1 

### - M



### ~ = Ibllb-mole = glg-mole
7. Percent excess air at sampling point.

_ 100 (%0 2 - 0.5% CO ) %~ 

### 0.265 (%N 2 ) - ((%0 2 ) 

### + 0.5 (%CO)]



### 8. Stack Pressure.

Stack Pressure °H O 

### P s = P b + 2 =° Hg Absolute

13.6 P s = °HgAbs. x25.4+mm Hg

* 29.92 °Hg, 68°F (760 mm Hg, 20°C) B-6 

## ~~

## ~ 

# MMETCO. E ff rM

9. - Stack velocity at stack conditions.

2 

### g'xP man xP std xMW

afr x 

### (T S +460) M2 

### V s = C P 60 12 x p alr x P. x MW x Tstd VA

— P average = fpm 

### ( T + 4E0) ~ 2 

### V s = 5,123.8 CP PS x MW FP average = fpm


### V s = fpm x 0.00508 = m/sec



### 10. Dry stack gas volume at standard conditions.*

1 Tsrd Ps 

### QS __ 144 

### V

. x 

### A . x M

d x T S + 460 x Psrd it Q


### _ 

### 0.123 V S x A. x M

d 

### x Ps = DSCFM S 

### T s + 460
Q $ = DSCFM x 1.6990 = dscm/hr


### 11. Actual stack gas volume at stack conditions. Q a = V s x AS = 144 ACFM 

### Q a = ACFM x 1.6990 

### = m 3

/hr

* 29.92 "Hg, 88°F (780 mm Hg, 20°C) 8-7 

# a

# ~ 

# HIMET 

# C O ~

12. :,.Percent isokinetic. /o o l Vm std x(T

s + 460) 

### x P

std x 

### 10 0 

### x 144 

### = n M d X T std x P s X T t X VS rrD 

### 4
/o 0 ! 1039 

### V

std x( T s + 460)



### _ M d x P s x T t X V. X D 

## ~

13. Particulate - probe, cyclone, and filter. 

# _ m 1 gr Ca" 

### r Vm std x 

### 64.8 mg

~ 

### C a „ = 0.0154 x m ' = gr/dscf' V std 

### C a „ = grldscf x 2.290 = 

### gldscm*


### 14. Particulate total. C ao = 0.0154 

### X m t

= grldscf std 

### C ao = gr/dsCf x 2.290 

### = g/dscm`

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-8 

# ~

# ~ 

# m ETCO_

15. Pasticulate - probe, cyclone, and filter at stack conditions.

~ 'S (Tsrd) 

### Ca ~ 

### _ C ~ x

~ 

### 'srd x ( T

S + 460) 

### x M

d

_ 17.65xC

a „x 

### P s xM d_ Cat 

### T

s + 460 9~ 

### CF
C at = grlCF x 2.290 

### = g/m 3
16. Particulate - total, at stack conditions. C 

### _ 17.65xC

~ xPsxMd



### _ ~ 

### CF au T

s + 460 g 

### C. = grICF x 2.290 = 

### g/m 3
17. Particulate - probe, cyclone, and filter. 

### C—C xQ x 60min x 1 Ib a 

### '"

~ 

### ' S 1 hr 7000 gr 

### C ayy = 0 

### .00857 

### x C,. x Q s

=!bs ✓ hr C aw = IbsJhr x 0.4536 = 

### kglhr 18. Particulate - total. Cax = 0.00857 

### x C. x Q S

= Ibs ✓ hr C a ,, = Ibs/hr x 0.4536 = 

### kglhr
* 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-9

~ 

## S /

# 7 MEIeo

EXAMPLE CALCULATIONS

Ibs/hr = mg_ 

### x 2.205 x 10 $ Ibs/mg x DSCFM* x 60 min/hr

Vm,, d
Vm,, d = Volume of dry gas sampled (dscf*) DSCFM* = Stack Flow Rate

ppm =

~ p.1g._ 

### x

24.04 

### Vm,td (m) MW 24.04 = Ideal Gas Constant liters/g-mole Vm,td = Volume of dry gas sampled (m 3 *) MW = Molecular Weight

.m.. .n. ,. -cular III - .W 

## Hy drogen Fluoride 20 

## . 0 

## 1

* 29.92 "Hg, 68°F (760 mm Hg, 20°C)

B-10 

## ~~

# n 

# ~ mETC0

6 EXAMPLE CALCULATIONS

Ibs/hr = ppm x CF x 60 min/hr x DSCFM` CF = Conversion Factor for ppm to Ibs/scf* Comp9und Conversion Factor 

### NO x 1.194 X 10''
29.92 °Hg, 68°F (760 mm Hg, 20°C)

s-i1 J 

### ~.~

# MuEo

~- - ~ , 

# ffm ~o~ ~

EXAMPLE CALCULATIONS 

### Equation 6C-1

Cr„e Cgas=(C
- C) 

### (i m - (i O Where: C g ,. = Effluent 

### gas concentration - dry basis (ppm)



### C= Average gas concentration indicated by gas 

### ana/yzer - dry basis (ppm) C o = Average of initia/ and final system calibration bias check responses for the zero gas (ppm) C m = Average of initial and final system calibration bias check responses for the upscale calibration gas (ppm) C,,, a = Actual concentration of the upscale calibration gas (ppm) 

### R

B-12 3-(r- 

### I 

# meco- ErMRonrnEnMc

SOURCE EMISSION SURVEY
JOB NUMBER: 96-30 JOB NAME: BORAL BRICKS LOCATION: HENDERSON, TEXAS UNIT TESTED: ABSORBER STACK ( EPN - K)
SOURCE EMISSION CALCULATIONS
SYMBOL DESCRIPTION

----------------------- -......................... UNITS --_---- ...... =1 I ----------------4 I RUN # 1 1

1 I I ---------------- -------

I 1 I I ------- -- -I -----------------

2 1 I -I

3 1 I I DATE I 1

I 1 I 02-15-96 1

I 02-15-96 1

I 02-1 5-96 1

I I 1 BEGIN I

1 I 1 I

0851 1 I

1053 1 I

12461 1 TIME I I I I I I I END I

1 I 1 I

1005 1 I

12071 I

1400 1 1 TIME I I I I I I I P(b) I

I BAROMETRIC PRESSURE I "Hg Abs. 1 I

29.491 I

29.52 1 I

29.50 1 1 1 1

1 (mm Hg) 1 1 (749)1

1 (750) I

1 (749)1

1 1 P(m) I ORIFICE PRESSURE DROP "H20 1 0.9191 0.966 1 0.9381 1 1 1

1 (mm H20) 1 1 (23.3)1

I (24.5)1

I (23.8)1

I I V(m) I VOLUME DRY GAS SAMPLED ft^3 1 40.346 1 41.5981 40.930 1 1 i 1 @ METER CONDITIONS

1 (m^3) 1 1 (1.142)1

1 (1.178)1

1 (1.159)1

1 I T(m) I AVERAGE GAS METER DEG.F 1 781 81 1 83 1 I I 1 TEMPERATURE

1 (DEG.C) 1 1 (26)1

1 (27)1

1 (28)1

1 1 V(m[std])' I VOLUME DRY GAS SAMPLED DSCF 1 39.1231 40.1591 39.3391 1 1 1

1® STANDARD CONDITIONS' (DSCM) 1 1 (1.108),I

1 (1.137)1

1 (1.114)1

1 1 V(w) I TOTAL WATER COLLECTED, ml 1 63.1 1 56.0 1 52.4 1 I 1 I I IMPINGERS & SILICA GEL I I I I I V(w[gas]) I VOLUME WATER VAPOR I SCF 1 I

2.978 1 I

2.643 1 I

2.473 1 I 1 COLLECTED @ STANDARD (SCM) 1 (0.084)1 (0.075)1 (0.070)1 I 1 CONDITIONS' I I I I I%M I MOISTURE IN STACK GAS % 1 7.07 1 6.181 5.92 1 1 1 BY VOLUME I I I I
' 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) B-13~ 

# p?lm
~ 

# rco

SOURCE EMISSION CALCULATIONS BORAL BRICKS HENDERSON,TEXAS ABSORBER STACK ( EPN - K ) SYMBOL DESCRIPTION UNITS ----------------4 ------------------------------------------------------- - ------ --I ---- - -------------- I --------------------I --------------------I Md 1 MOL FRACTION OF DRY GAS

I 1 I 0.9293 1

I 0.9382 1

I 0.9408 1

I CO2 I

I 1 I % 1

1 I

2.21 1 I

2.31 1 P

2.3 1 I 02 1

1 1 1 % 1

1 1

16.41 1 1

16.61 1 1

16.51 1 CO 1

I I 1 % 1

I 1

0.01 I 1

0.01 I 1

0.01 I N2 I

I 1 I % 1

I I

81.41 I I

81.1 1 I I

81.21 I %EA 1 EXCESS AIR @ SAMPLING %u 1 317.21 339.4 1 328.81

1 POINT I I I I UWd I

I MOLECULAR WEIGHT OF I LB/LB-MOLE 1 I 29.01 1 I

29.03 1 I

29.031 1 DRY STACK GAS 1 (g/g-MOLE) 1 1 (29.01)1

1 (29.03)1

1 (29.03)1

1 VIW I MOLECULAR WEIGHT OF LB/LB-MOLE 1 28.23 1 28.351 28.381

1 STACK GAS 1 (g/g-MOLE) 1 1 (28.23)1

1 (28.35)1

I (28.38)1

I )ELTA P I VELOCITY HEAD OF STACK 'H20 1 0.396 1 0.440 1 0.4141

1 GAS 1 (mm H20) 1 1 (10.1)1

1 (11.2)1

1 (10.5)1

1 7s I STACK TEMPERATURE DEG. F 1 436 1 440 1 441 1

1 1 (DEG. C) ( 1 (224)1

1 (227)1

1 (227)1

1 's I STACK PRESSURE 'Hg Abs. 1 29.47 1 29.49 1 29.47 1

1 1 (mm Hg) 1 1I (749) I

1 (749)1

1 (749)1

1 (s I STACK VELOCITY @ STACK FPM 1 2,687 1 2,835 1 2,752 1

i CONDITIONS 1 (m/SEC.) 1 1 (13.65)1

1 (14.40)1

1 (13.98)1

1 s I STACK AREA (SQ.INCHES) 1 4,001 1 4,001 1 4,001 1

I I (SQ.METERS) I 1 (2.58)1

1 (2.58)1

1 (2.58)1

1 )s I DRY STACK GAS VOLUME ® DSCFM 1 40,417 1 42,890 1 41,675 1

1 STANDARD CONDITIONS' 1 (DSCM/HR) 1 1 (68,668)1

1 (72,870)1

1 (70,806)1

1 )a I ACTUAL STACK GAS VOLUME ACFM 1 74,664 1 78,770 1 76,460 1

1 @ STACKCONDITIONS (m^3/HR) 1 (126,854)1 (133,830)1 (129,906)1 ' 68 Deg.F, 29.92'Hg (20 Deg.C, 760 mm Hg) B-14

# n

p 

# FIMET0. ErM 

# ROnnYnML

SOURCE EMISSION CALCULATIONS BORAL BRICKS 

### HENDERSON,TEXAS ABSORBER STACK ( EPN - K ) SYMBOL DESCRIPTION UNITS I -- ----------- I

--- -- --------- -- ---- --------------------I I ----------------4 I Tt I ---- ----------------------------- -- ---------------

I NET TIME OF TEST I MINUTES 1 I 72 1

I 72 1

i ----------------- -I

72 1 I i 1 Dn I

I SAMPLING NOZZLE DIAM. I IN. 1 I 0.260 1 I

0.260 1 I

0.260 1 I I I

i (m) 1 1 (0.007)1

1 (0.007)1

1 (0.007)1

1 1%1 1 1 PERCENT ISOKINETIC

I % 1 I 101.71

I 98.4 1

I 99.21

I I I Mf I

I PARTICULATE - PROBE, I mg 1 I 64.1 1 I

56.7 1 I

66.41 1 1 CYCLONE AND FILTER

I I I I

I I

I I

I I I Mt 1 I PARTICULATE - TOTAL

1 mg 1 1 79.41

1 69.9 1

1 70.7 1

1 1 1 Can 1

I PARTICULATE - PROBE, 1 gr/DSCF* 1 I

0.0252 1 1

0.0217 1 1

0.0260 1 i I 1 CYCLONE AND FILTER

1 (g/DSCM) 1 1 (0.0578)1

1 (0.0498)1

1 (0.0595)1

1 1 Cao I PARTICULATE - TOTAL gr/DSCF* 1 0.0313 1 0.0268 1 0.02771 I 1 I

1 (g/DSCM) 1 1 (0.0716)1

1 (0.0614)1

1 (0.0634)1

1 I Cat I PARTIC.-PROBE, CYCLONE gr/CF 1 0.0136 1 0:0118 1 0.0141 1 I I 1 AND FILTER @ STACK COND.

1 (g/m3) 1 1 (0.0312)1

1 (0.0270)1

1 (0.0323)1

1 1 Cau 1 PARTICULATE - TOTAL @ gr/CF 1 0.01691 0.0145 1 0.0150 1 I 1 STACK CONDITIONS (g/m3) 1 1 (0.0387)1 (0.0332)1 i (0.0344)1

1 I I Caw i

I PARTICULATE - PROBE, LBS/HR 1 1 8.74 1 7.991 9.28 1 1 1 CYCLONE AND FILTER (Kg/HR) 1 1 (3.96)1

1 (3.63)1

1 (4.21)1

1 1 I Cax 1

I PARTICULATE - TOTAL LBS/HR 1 10.831 9.851 9.881 1 1 (Kg/HR) 1 (4.91)1 (4.47)1 (4.48)1 * 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg)

B-15 

## ~~~ 

# MEMO

SOURCE EMISSION SURVEY
JOB NUMBER: 96-30 JOB NAME: BORAL BRICKS LOCATION: HENDERSON, TEXAS UNIT TESTED: ABSORBER INLET DUCT
SOURCE EMISSION CALCULATIONS
SYMBOL DESCRIPTION UNITS I ----------------4 ----- I RUN# I I I 1 1 1 I I 21 I 31

I I I 1 DATE 1 I I 1 02-15-96 1 I

02-15-96 1 i

02-15-96 1
I BEGIN 1 1 0851 1 1053 1 12461 1 TIME I I I I I I END 1 1 1003 1 12051 13581 1 TIME I I I I I 1 I I I P(b) I

I BAROMETRIC PRESSURE "Hg Abs. 1 I 29.49 1 29.521 I 29.501 1 1 1

I (mm Hg) 1 1 (749)1

1 (750) I

1 (749)1

1 1 P(m) I ORIFICE PRESSURE DROP "H20 1 0.5001 0.5001 0.5001 1 I 1

I (mm H20) 1 I (12.7)1

I (12.7)1

I (12.7)1

I I V(m) I VOLUME DRY GAS SAMPLED ft.A3 1 28.7191 28.974 1 29.096 1 1 1 1 @ METER CONDITIONS

1 (m^3) 1 1 (0.813)1

1 (0.820)1

1 (0.824)1

1 1 T(m) I AVERAGE GAS METER DEG.F 1 76 1 79 1 79 1 1 1 TEMPERATURE (DEG.C) 1 (24)1 (26)1 (26)1 1 1 1 V(m[std])* 1

I VOLUME DRY GAS SAMPLED 1 DSCF 1 1

27.923 1 1

28.043 1 28.142 1 I 1 @ STANDARD CONDITIONS* (DSCM) 1 1 (0.791)1 (0.794)1 1 (0.797)1

1 I 1 V(w) 1

I TOTAL WATER COLLECTED, ml 1 1 39.2 1 41.21 40.0 1 1 1 IMPINGERS & SILICA GEL I I I I I

I I I V(w[gas]) I

I VOLUME WATER VAPOR I SCF 1 I

1.8501 1.945 1 1.8881 1 1 COLLECTED ® STANDARD (SCM) 1 (0.052)1 (0.055)1 (0.053)1 1 1 CONDITIONS* I I I I I%M I MOISTURE IN STACK GAS % 1 6.21 1 6.48 1 6.291 1 1 BY VOLUME I I I I I Md I MOL FRACTION OF DRY GAS 1 0.9379 1 0.9352 1 0.9371 1 1 Tt I NET TIME OF TEST MINUTES 1 72 1 72 1 72 1 * 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) B_16 M

# ETCO

# m

APPENDIX C
Calibration Data



### Equipment

- 

### Calibration Pitot Tube #12-5-1 (17) 

### Factor 0.808 

### Calibration Date 

### 01/09/96 Pitot Tube #17-5-2 (71) 

### 0.806 12/29/95 Probe Tip #II-5 

### 0.260 01/03/96 Dry Gas Meter #17-1 (11) 

### 0.981 12129/95 Stack Unit Orifice #17-1 (11) 12/29/95 

### Digital Temperature Indicator #17-1 (11) 12/29/95 Dry Gas Meter #17-2 (17) 1.037 12/27/95 Stack Unit Orifice #17-2 

### (17) 12/28/95 Digital Temperature Indicator #17-2 (17) 12/27/95 Barometer #17-1 (6) 01/12196

96-30 C-1/

~

n ~ 

### I PITOT TUBE CALIBRATION

r

### Date: 4 _T'c<NU4r ~ 2 

### Time: /o o z

~ Pitot No.: i 2- 5'— / 

### T g : - 7 (p 

### ° F

Pitot Dimensions: ~ w .S ' Cpstd• 0 • 990 

# ~~~~~~ a 

# ~ MMVWVI.0 " .01 U. 

# M ~ ~ 

# W 

# , 

# M O

~ 

# M ~~~~r~,



# M .0 M - m ~ 

# ==== ~ 

# MMMMM ~



# ~ 

# Mase.

~~ 

# I M-,., ~ W~- 

# mmm m ~ 

# MMM 

# M M ~

Summary of Results: 

### Normal high side calibration factor ~ 

### D.53o8 

### variation + a.9'9%` ~ 

### variation - ~.'~ q ~• ✓ 

### Normal low side calibration factor

~ 

### $°

~ 

### . ✓ variation + variation- - I 3 ~•~ ✓ 

### Calibrator: Tm 5-kr-+

- i-- Checked By: C-2 i 1



### ~

I

# i

.



### ~ 

# rn PITOT TUBE CALIBRATION

~ ~ ; Date: 

# a c ) Q e C Pitot No.. 

## 1 q- .S

„ . 

### Pitot Dimensions: Time: 

## 1130 T,: 

## 70 ° F C Wd : 0.990



# ~ ' Calibration 

# = Slandard 

# ~ ~ 

# n Factor 

# E. amm c mm me m 

# mm mm ~~~ ~ 

# mmm oa ~~~~



# ~ m~r~r.~n~m~s~~r~ 

# rse mMn'ra mm
~ 

# :r.r.
~ 

# Hamr. ~



# ro

~~~ 

# imo m

~.~ 

# ==r. mm Summary of Results: 

### Normal high side calibration factor 

## Q.90t, ~ variation + 

## 4 - q°I variation - ~ 

### • ` ~ 

### Normal low side calibration factor 0. R f O

~ 

### variation + 

## variation /- ~ ✓ ~ 

## o 5 % Calibrator:

e



### _ 3 Checked B) 

# 4/1 M
i

~

~

~

# ~ 

# METCO ~ I U1ViROflf

~ f'(TAL

,



### ' NOZZLE CALIBRATION Nozzle Set No. 

# _U Date 

### 3 qL Calibrator: ~~""~-~mp 

### S m(

- 7 Ou blo q 1 2 3 4 5 6 Reading 1 

### ,

° Md

~



### O. 13 ,.IG9,

Q o

~ 

### 48 _ 

# o.aLn 0.3og Reading 2 

### 140 p. 1 1 1 p. i q 

# o. au.g ~ 

## (_ 0. 0 Reading 3 

### .1 I'1 r a. ©.iqy n. P

-QsQ
. ~(~ 

## 0•309 Reading 4 

### 0. lap 0.11a. 0-i 

### gg 0.a41) 

## ~ 

## OW9 Reading S 

### o.(IO w - 13 

## O.Iqa 0 •ISO .Wd) J Reading 6 Q. I f ~ .p 

## t) 17 3 

# n. Ig

~ 

# . ~ 

# g_ n. ~.~ 

# L p, 3pg Reading 7 

### d.lap Q.(l l O.19 

## o.q,4°► 

### O• 0•30$ Reading 8 . J Q



## . n I12. .(93 O, 

## a O• 30 Reading 9 

### 0.12.O O•D r d- . ~ 

## tQq 0 0.309 Reading 10 

### 0•1 ( ,~0 • 

## _ a 1

- 13

. 

## .

O Iqq 0.~4~3 .~ 

# o•3pg

!~ 9.0 ~ O.

~ - 1~• ~ O. I q q ~ O•'d.

~ F °l ~ 4•
~ (J

Average
7 8 9 10 11 12 Reading 1 

### o 

# 3ao -o. 3 ~ 

# I .•~ 

### O.L481 

### 0. 635 Reading 2 O.~~S 

## _0 359 o.4a3 O•l8G 

### 0.•0 Reading 3 ~~ ~.~L L 

## •O.4k4- 

## D. (tBU 0.L35 Reading 4 

### 0,3ID ,3 0 O - 3


## . O 4gb

.



## o L3y Reading S 

### a•3'11 

## 0.W 0,H TY 0.4m o , 635 Reading 6 

### n, I
~ 

### Ln 

## 0359 qU_ 

### p, Wo G.L
~ 

### S Reading 7 

### 0 .39b 0,3$ 0-4 

### ~ 

### q 0,L4M_ G. O 

### to Reading 8 

### O. 3a.rl 0,4rO 

## 4 A t 0 05 Reading 9 

### C ) ."3al 0.3S' ~ 

### o.yX3
~ 

### .t• Tr 6 

### 0.
~ 

### 3 Reading 10 

### () . 2
~ 

### - b 

## 0.413 O' y9 - I

~ — 

## 0.635 O, 3rl1 ~ 

### O. 3W O• 413 '' O. 480 ` ~ O.l~ ~ 

### Average C-4 1 ~EL as

IN 

### Dry Gas Aleter Calibration
Dry Gas Meter Number r! I Date: (a ag

oH ("H20) 

# C DG 0.5 O. 176 1.0 ~•~ 7 4 1.5 

# a.gsa 2.0 

## 0.98a 3.0 

## o•q 83 ; 

### 4.0 

## 0.183 _. Average 

### / 

### Q Ag 1 ~ Variation : + 

### O, ,Z0 

### ~ o ~



### - 0. S

~ 

### 70 ✓

Calibrator: ! Checked by:

C 

### DG @ 2 liters/min. = ,000

C-5 r 

### ~

# ~ 

# MEKO.

DRY GAS METER CALIBRATION
Meter Number: 1-7' ( 

## Calibrator: PAJ 

# ~ * Date: 

## I a: 2 S - 15

Calibration Factor (C oc ) _ Wet Test Meter Vmsrd 

### Dry Gas Meter Vmsrd

Run.No.: I a 

### O. 

### s O }

~~ 

### p Pb: 

## 0~ q, ~q 11H g Control Module Vacuum: 

## EO "Hg yVet Test Meter

(No. 

## ~ Meter Meter Temp. 

### 2' 1m Saadin9 IemlL P,n, R 

### eading 

### 1D D

- 

### tt P,,, 

## End 1' ~~ ~ 5.a~ 

## 7 cf 7 f ~ F — 

## o. So

~ 

## H2p 45~~ 88 

## c f ~~ ~ F - 1S o F 

## O.So vH 2 O Start ~~ 

## -

_ ~ 

### a.000 c 

## f 'lI 

## o F —o.8 

### 0

. H2p 

## y-
~ 

### FR .4
- 'f7 

## f 79 

## oF 15 oF O.So 

## «H20 Av . 

### I 3 9 

### 5a

~ 

### "

l ~ 

## f 7I J F ~~~ ✓ H 2 

## 0 5.3 

## Y 'I

~ 

## f ✓ 7 ~ 

## °F

_ B.So

~ 

## H 2 O

Wet Test Meter Vmsrd = 

### 17.65 x 5 • a ~~ 

# a
~ 

# ' 13.6 xo. 

### (C) =5, jo-a-dcsf

- 

### 7 ( + 460

+ 

### 0.50 i 

### Dry Gas Meter Vmsrd = 17.65 x5 •3 

### ~ ' I 

## °~~' 13.6 =~- ~~ 

### 9 dcsf 76 + 460



## - 

## c ~ 

## S.
~ 

## Oa = o,176 ., 

## -

C-6 • 

# ~~

# n MEMO

n .~ 

### DRY GAS METER CALIBRATION

Meter Number: 

### Date• 

## I a

- )L y - ~ 

## 15 , Calibrator: U

Smr"

~ 1


### ..

Calibration FactorC DG 

### ) = wet Test Meter Vmsrd

~ 

### Dry Gas Meter Vmsrd



### Run No.: 

### @ I• °o " N, o p b: vZ 917 "H9

~ 

### Controi Module Vacuum: 5 0 "Hg

\~ J



### 19 

### Wet Test Meter 

# (No. Meter T~ 

### = Haadltt9 IgmRa P,,, End 1114 S.oSo cf '7 1 "F - I. a0 "H 2 0 Start 07 0
- 0 0e ~ 

### cf ~ 

### F ~ a 

### O

•~ 

### ,H 2 Avg. cf
- 71 °F 1.2 0 H 2 0 

### Meter Temp. BeadIng 1D D-Ut P,,, 417.114' cf
- 77 "F 7 

### 1~ oF I- o o "H 2 0 W(.9 ff X f

?S 

### oF 7 ~ F- 

### oF 

### I . oo 

### WN O

f /_ _2 5; lacf 7` °F 1• 00 °H 2 0



# ~ 

# .av

✓ 

### Wet Test Meter Vm std = 17.65 x 5.060 

### a~•d~ 13.6 x D,g`( I(C) _ 

### ~ {; ` 

### ~ ), 

### ~ dcsf

- 

# 7 + + 460 (,00 f J 

### Dry Gas Meter Vm std = 17.65 x5 • la 

### b •6 

### ~ 13.6 

### = -7,s + 460 

### 5. o33 dcsf



# CDG _ 1- M I F


# _ 0~9~~ 

### s,o33 

# o. Y ~

# I 

# MEKO

DRY GAS METER CALIBRATION
Meter Number: P' 

## Calibrator: 

# f rAd 

# S hf

- t 

# ~ Date: Calibration Factor (C oG ) _ Wet Test Meter Vmsrd 

### Dry Gas Meter Vmsrd

U 

### Run No.• 

## @ 1-50 H. ) 0 p b : 

### _ 02` 

### ~ . b I 

### "H9 Control Module Vacuum: 

### S,d "Hg


### Wet Test Meter (No. 

### Qry Gas Meter Meter Meter Temp. 

### ?m@ Head3D9 Semp. .e,,, fleadina in

- 

### 0

- 

### Ut P,,, End Ja ~ O 10.0$3 cf 

### — 41 °F ""I. b'O MH 2 O if-
- 79- s6 0 cf °F ~ n °F 1- 50 °H 2 0 Start W5 

### 0. CM
~ f 

### 71 % F 1 

### - 

## 40

~ H 2 O 'T 6 ~ -~cf ~° F~° F 

### 1• 58 ✓ H 2 0 

### Avg. ~ 

### rj ~ 

### 0-08 3 cf ~ ~ 

### °F '" ~ 

### . ~ 

### 0 °H 2 0 ~0 , a~ ~ 

### ' cf 7 ' ~~ 

### j -°F ~~ 

## 5 "H 2 0



### Wet Test Meter Vmsrd = 17.65 x 10. 0 ?3 

## ~• ~ 13.6 

### x 0 q1' (C) = 9. Y).Jdcsf + 460

Dry Gas Meter Vm sb

= 17.65 x 10.Z1 

## ~ 'r



### ~ 

# .o +


### ~~. 61 13.6 

### ✓ csf

?? 

### + 460 

# 1 0.00 

# ~

CDG= 

## ~•~aa = 

# 4•1$ ~

c-s 1fl.0aL - 

# ~~ ~ 

## I

# ~ 

# MErCC

DRY GAS METER CALIBRATION

Run No.: ..

~ 

### ~ C~ ~ •O® 1 r~C 

### Calibrator: 5 "it

Wet Test Meter Vmsrd Dry 

### Gas Meter Vmsrd



### P b : 

## a l. 61 "H9 Control Module Vacuum: 

## 5•0 "Hg Meter Number: 

## I ~ 

## L! ( Date: 

## I 

## ~~ 8(&Is

Calibration Factor (C os ) =

.~.~ 

## Wet Test Meter (No. Meter Meter Temp. S!M Se1]]R. End 

### ~ 3 

### ~ 

# 1 O



### He.3S1!'n9 3 cf F

o— 

### ~ " H 2 

### 0 °~ Q~

y' ~f 80 o F 

### ~ 'S o F a



### ~ "H O 2 

### Start I_clj_Q 

## O.W of 

## '7
- 1

, 

### ~F

— 

## 2• 

## ~ ~ y 2 0 tf O. 

### ~'3'~ f~° 

## ~ °F 

## a• 

## ~ `` 

### ~ O Avg. 

### ~ ~j la 

## .la3 cf ~ ) °F 

### ~ • "H 2 0 10•a 1 F5 cf 

### ~ g °F ol• W"H 2 0



# _ a , 00

✓ 

### Wet Test Meter Vmsrd = 17.65 x j0 

## . la3 a ~ • 6 

### ~ + 13.6 

### + 460 

# x0.111 (C r

) _ J ,$S I 

# dcsf
~ ~
a.00 

# an' 13•6 Dry Gas Meter Vmsrd = 17.65 x lo•~~ 

### W =1Q.Q2$d sf + 460

CDO= 

# (o.a ~~

C-9

# r, M~r~ 

# „ co

DRY GAS METER CALIBRATION
Meter Number: 

### Date: Calibration Factor (C oG ) =



### Run No.: @'3 • 0 o I No , 

### Calibrator: 

# ~ M
Wet Test Meter Vms,d 

### Dry Gas Meter Vmsrd



### Pb= 

### 21.91 "Hg Control Module Vacuum: "Hg

It 

### Wet Test Meter (No. 

### 3 ) Meter 

### MM Haadia4 Semp. P-I„ End 3IS ]Q,5)$ cf °F "'31 0 "H 2 0 Start 3 

### ~ 

## a0 ~ cf ~~ 

### ~F 

### "3 - 1 C ' 7 ~ H 2 O Avg. 

# 11 ' 

### ~ cf 

### ~ 'I ° F

- 3 

### ~ °,/H20 

### )0,518 Meter 

### 8eadins SOa. , 37 i cf


## ~ 

# aI 1'7
- cf

✓
. 

### /Q, Sff cf Temp.

1D S2itt .B,,, v o ig °F 1'~ °F 3. 00- H 2 O 

# 8 0 °F ~S r °F ~ "h 2 0

.~ 

### .1 ~ 

### °F 3•00

- H 2 O



### + Wet Test Meter Vmstd = 17.65 

### x lo.518 a9' 13'6 

### x

031 1(Cr) dcsf + 460 

## Ioo Dry Gas Meter Vmsrd = 

### 17.65 x IO.Sp ~ 

### a~.t~~ + 

### 13'6 =10,3 ~a~ 

### dcsf



### ~ 9 + 460

cDa = 

# lo . 1 °1 a la.344 C_10 

# = 0.183 ~ 

# 4

# mErco- c

~ 

# 9

DRY GAS METER CALIBRATION

Meter Number: 

### 1
- 7-1 Calibrator: 

### au ( 5 7 r-, - kk 

### Date: tZlzq 

# l9s

Calibration Factor (C DG ) _ Wet Test Meter Vmsrd 

### Dry Gas Meter Vmsrd

r 

### Run No.: @ •d 20 

### p b : a 9 66 

### "Hg Control Module Vacuum: 

### S: o "Hg


### Wet Test Meter (No. 

### -5 ) Terr 

## !n Tr°F

7f . Meter 

### _T= Seadi4U IamRa Z„ End iO 3 7 / 0

. 23 fcf

- 7 2 -- °F — 3•go "1-1 2 0 Start /4PLr d.o d o 39 72- ✓ F -3. g' °H O

✓ z Avg. /O.z3rcf 7 2 °F -3 Sso "H 2 O Meter Reading 573. 7'sl cf G ~ 3-

~ z c ✓ /6 z 

### ~~ cf ip.



### 9sat P m 7 7 °F `/ 0 "H 2 0 

### 7 & 0 F. 46 0 H Z O °F 1/0 s,H2O



### Wet Test Meter Vm 17.65 

### x ( 

### 6. 23 s std — '7 Z + - 3 YO ,/ 

### 13.6 

### x o. Q9yC f ~ 

### y8'

~ 

### s? dcsf + 460 (

+ Z(.oa ~ 

### Dry Gas Meter Vmsrd = 17.65 x ra 2 f~~ z s c 

### c 13.6 

### _ 10 , p'!

~ 

### 3 dcsf 7 F + 460

CDG _ 

### ?' gI K 7

/ O• oS3
C-11 

# 44

# MEFCO- EwRonMErMc

DRY GAS METER CALIBRATION
Meter Number: Date: 

## 1 1 - Calibration Factor (C os ) = Calibrator: 

# fp, , ~
Wet Test Meter Vmsrd Dry Gas Meter Vmsrd

Run No.:

~ 

### h- P b : 

# a 9. tb » Hg Control Module Vacuum: 

# '-- o "Hg Wet Test Meter (No. 

### ~ ) 

# ,

~ 

# r1m

End laZ ,-, Start o 95 

### 1 Avg. L I Meter



### Saadip9 TemR. P-M Z, os G cf 72— °F -f. ZO °H Z O O.000 ct 

# k ~ 

### ~ 1.20



### ~ 2 0 2 .. o s 

### ~ ✓ cf 72— °F -/.zo YH 2 O Meter 

### Beadina SGZ.Soz cf 

### 5 60.730 

### ~ f z.o7z cf Temp.

!II -Qilt Q,,, 76 °F 7G °Fo .o c "H 2 0



### - L6—°F -7 6 O F 

### 0- O 1 ✓ H 2 0 7 4 o F a- a( "H20



### ~ q• 6~ + vZ 

### ~ dcsf 

### Wet Test Meter Vm sG 13.6



### srd = 17.65 x z.o

~ 

### + 460 x1 ' c03 (Cr} = z,



## a~ .b$ + °.o r / 

### Dry Gas Meter Vmsrd = 17.65 x a.o?z- 13.6 

### = Zoz . dc J sf 7 ~ 

### . + 460

COG 

## /, ovo

z-o Z
C-12 

# ,!!M

## ~ 

# ME-TCO

,



### DIGITAL TEMPERATURE INDICATOR NO. 

# 17 - 1

CALIBRATION DATA



### Date: 

# 19n i' IS
Mercury Temperature DTI 

### Med.i ilme (° F) (~ 

### Ambient Air j 3 

### ~ 7 Ice Bath 

### Boiling Water Z/z 

### z

~ 

### Oven ' Oven

~ 

### Oven /67 3 S 3 s"o

Oven 376 3 

### ~ ~ Meter Adjusted? Yes No 

### ~

Calibrator: fA

~ 

### za ~ 

### ''' Checked By: 

### 1~ --

' r r' 0 Z

C-14 

# Sa-

# .9

~ 

# MEFCC

Dry Gas Meter Calibration
Dry Gas Meter Number 

# fi-- .? Date: 

# IoZAoZ

~

i ~ 

# "rs

nH 

### ("H20) C 

### DG 0.s
~~ 

## O34
1.0 

## l, 03&
1.5 

## 1,C73y
2.0 

## 1,d36
3.0 

# 1 , 037 4.0 110 Average 

## 1, Q
- 37 / .o



### Variation: + 

### ~ 

## • q Zl

Calibrator: 

### Checked by :

C DG @ 2 liters/min.

C-15 

# ME

# n 

# METCO.

DRY GAS METER CALIBRATION
Meter Number: 

## 1 4 - a Calibrator: 

# Cilt Date

: 

## i 3-:13g

Calibration Factor (C oG ) _ Wet Test Meter Vmsrd 

### Dry Gas Meter Vmsrd

Run No.: 

## I @ 0 e5

- 0 i n 

# ~~}(~ P b : 

# a qr & /- "H9



### Control Module Vacuum: "Hg
Wet Test Meter 

### (No. 

# ~ Meter Meter Temp. 

### T.ime 8ead1o9 IsDOp, P_,,, BeadJD9 !II QW P

~ 

### „ End 1 - 3:Ya 5.yy5 - cf
~ ) °F --d , qn 

### "H z 0 

### ti a q 7 vg cf g I °F 79 °F 0 "H 2 0 Start 

### 13%30 0,00 ~f ~ ( ~ F - 0• c? "
~ 2 0 

## tIl9'.'/Q/ % f ~9 o F ~_oF 

### 0/5 ~ ~H 2 O Avg. ~ : la 5,'1gS cf ~ ~ aF -,d ,9
~~ H2p 5,3v'
~ i cf ~~ oF 0•5P °1-120 

## - 0, qDo Wet Test Meter Vmsrd = 17.65 

### x 

# 5 ,`(9S 13.6 ~ 

### xO, qql ( C ) _ 5'`, 3 'Wdcsf

~ i + 460



### D• 

### ~ 1 I' 0 

### D ry 

### Gas Meter Vms rd = 17.65 

### x h~ 3 ~~ 

### a°1-6 

### 1 + 13.6 

### dcsf 31 + 460



# C DG 

# __ 5 .

_ y . d3 1 /

C-16

# ~ 

# MEMO

DRY GAS METER CALIBRATION


### Meter Number: 

### I 

## ~ " a Date

: 

# I a 1 a

- I yif 

# ~ /

. 

# b

. 

# o / (Ii /, ._6Y ~ `L


# I Calibration Factor (C os ) _ Wet Test Meter Vmsrd 

### Dry Gas Meter Vmsrd

Run No.: 

## ~ C~3 ~'Q ~n ~~ d•y 

### P b : 

### a e i. G I »H9 Control Module Vacuum: "Hg 

### Wet Test Meter (No. 

## ~ )

L-Ij P-M ... (.30 "H Z O H 2 0 nH 2 0 Meter 

### e He3diaa ?emp. End 1 L1;y ~ 'S•3al cf - 4d °F Start 0Q
~ rf 

### ~ 

# a °F 

### 0:0 5.3a1 cf

`3d °F Avg. Meter Terr 

### Eeadi.n9 1n qYt.a7r4cf 'il

— °F 

### yq3. Jyv cf 

### S
-

.R °F 

### S• 13 ~ 

### cf 

### 10 Ip 

### So Pn

14 °F 0 0 "H 2 0

~ 

### 'le °F j, 00 /H 2 0 

### OF I- 00 "H 2 0 

### -),3d 0 + 1-1 

### Wet Test Meter Vmsrd = 17.65 

### x 5.3 ~ ~ 13.6 

### x 0 

# , 9o 

# 1 / (C r ) = j. dcsf

~ 

### -a + 460

+ 

## (, Oo ~ ✓ 

### Dry Gas Mefer Vmsrd = 17.65 x~ 

### , ( 3 ~ ~ 

### + 1 4 0 Li' 

### qj3dcsf

CIDG_ 

## 1, 036 ~

c-i7;! 

# METCO

DRY GAS METER CALIBRATION
Meter Number: 

## 11 -3 Calibrator: Date: 

### I Aq5 -



## Calibration Factor (C

oc ) _ Wet Test Mefer Vmsrd 

### Dry Gas Meter Vmsrd

Run No.: 

### 6I. Pb: 

# a °I, b 1 "Hg 

### Control Module Vacuum: 

### 5 - # 0 "Hg



### 9 Wet Test Meter (No. 3 ) Meter 

### 2tm@ Beaslln9 IemR. P-,► End ! tI%3t 10, 'f J9 cf "ta °F - • gc "H 2 0 Start 

# /y

~ 

# a0 0

-0 0 cf
~ 

# 'a O F 

# ' 11 90

~I 2 0 Avg. 

### 0 1 - I 

### l~ 10 ~~~ c ✓ f F 

### - I ,°



### IO "H 2 0 

### o► 

### - uC

Meter Temp. 

### Readin_a 

### in DJA Pn, Nya,a76cf °F °F 1 -5 7 0"H 2 0 c

~ 

### , f. 

## l q "F "F

~ 

### H 2 O 1 0 ' 34 7cf 

### W °F / -57) "H2 0

+ 

## -000 ~ 

### Wet Test Meter Vm std = 17.65 

### x tQ1"717 13.6 

### xo,qql ( . C f ) =1d 1 tlyydcsf + 460

+' 1 

### 6 

### ,i D ry 

### Gas Meter Vm + 460



### srd = 17.65 

### x 1 Q.39 ~ 

## 0 0 dcsf S'0

CDG _ 

# '0' YW

_ ~ ~ D 3 `f 

## Ic?

~ 

## lo0
c-i8 v

### Run No. 

## I a a , Oi n/7 

## ~ L 0 P b : 

# a q., ~ 

# l "Hg Control Module Vacuum: 

## ~~ "Hg 

# m

DRY GAS METER CALIBRATION
Meter Number: 

## I - 

## ~ "0 ;_ Date: 

## I 7

~ 

## -Na`? q 5 Calibrator: 

# ~

Calibration Factor (C os

) _ Wet Test Meter Vmsrd 

### Dry Gas Meter VmSra

I 

## Wet Test Meter (No. 

## 3 ) Meter T1II1S 8ead1114 Iemp. P

~ „ 

### End 1 S;1 y 10. 540 cf Ta ° F- a- 1 0 "H 2 0 Start 

## 15: 01 0.0 0 ,f - 

## }a. ~ F 

## - a, i

~ 

## O vH2O Avg. 0 ~ ~ a



### ( 0 , ~ 

### 1a cf ~'~ 

### OF - a. 14 H 2 O Meter Temp. 

### Hs adina 

### J,a S

- 

### Ul P,,, y s5macf `15' °F °F d ?.WH 2 0 

### ' r 

### lV$1 g 

### i

~ 

### p 

## S

- 0 'F `F 

## a ,0a `~ 

### 20 (0,

- ~ 

### 3cf 'c6"- a ✓ o F a,OaH 2 O

+ 13.6 

### Wet Test Meter Vrn srd

= 17.65 

### x 1o, 5 r



### ~ 0 7 a+ 460 

### x0'qq. (C ! ) = 10, a vf'dcsf

+ 

# a 

# _ vo Dry Gas Meter Vmsrd = 17.65 

### x 

## 0 , l ~ j a ~ ~ 13'6 = 9 f~~ 

# I csf j Ta + 460

C OO =

C-19

### Run No.: I a 3 f 0 1 n 

### 60 P b : 

## a~,~/ "Hg Control Module Vacuum: 5 . "Hg 

# ~ m~ 

# rco

~ DRY GAS METER CALIBRATION

Meter Number: 

### Calibrator: Date: Calibration Factor (C oG ) _ Wet Test Meter Vmsrd 

### Dry Gas Meter Vmsrd

yV _et• Test Meter 

### (No. 

## ~ a
Tme End 

### Start IS
~ t 

### g Avg. Meter

~ 

### eadinc IO , 9bT 6,00 

### 10 `16e( l Iemp. P-M cf 4a °F - 3 • 00 "H 2 0 ✓ f 

### ~~ F 3 

### ,~0

" 

### ~ 0

2 ° cf 7a-F - 3 ' 0 " H20 Meter Temp. 

### Readin_a lII .4st P,,,



### ~ Sfajncf °F - +q °F 3- 6 "H 2 0



### ~ 1a.~4q ✓ 

### ~ ~ o F 

### ~-`6 o F 

### 3.p -H2O W.yY3 cf °F 3-e ) "H 2 0



### 13.6 Wet Test Meter Vm - 17.65 

### x 10,96` ~ x(~ o~ 

# I I(C r ) = j5 ~ 

### dcsf Srd - + 

### ~ 460 '



### Dry Gas Meter Vmsrd = 17.65 

### x/p, 5 , y3 + 3, ~ ✓ dcsf $ S' + 460

~ coo - i v 11 5S 

### ~ ~ l~ 

### 0"3 7 ~ 

## CV.aa

~ 

## ( c-2o

# mErco- e'WIRonn-EnTnC

DRY GAS METER CALIBRATION
Meter Number: 

### Calibrator: 

# aeL Ut~
Date: j 

### Calibration Factor (C oci ) _ Wet Test Meter



### V msrd 

### Dry Gas Meter Vmsrd

Run No.: 

# 1 a LI

, 0 1
- ^ 1 40 P b : 

## oZ q, 6 / "Hg

Control Module Vacuum: 

## 5• - A "Hg

~ 

### Wet Test Meter 

## (No. ~ Meter 

### MM Seadin9 Iem°• P,,, End 

### I 1 1,5b1 cf °F - 3-IrO"H 2 0 Start 

### ~6~ 00•00



## J f - F - 3 

### JO J i 2 0 Avg. 

### O,Og I1,5771 cf °F H 2 0 Meter Temp. 

### Bea ~ 

### 1n DJuf P m y 9 

### b .i 9 ycf 

### 10 3 °F Sr4 °F 4 , 6 "H 2 0 

### '115.Ur cf

1* 

### 3 °F it°F 

### `l, o H20

~ 4's ` ~ ✓ °F << ~ 0 "1-1 2 0



### Wet Test Meter Vm 

## St?

srd = 

## 17.65 x ~ 

## ti, 1 } 13.6 

### x a,qq ~ 

## (C) _ ~ ~ ~ 0 

### dcsf
~-~ 

## + 460

~ 

### 1, 0 ✓ 

### a 9 •G~ + 13.6 

### Dry Gas Meter VmSrd = 

## 17.65 x( ~ 

### , ~ 

### ( r q ~ 9 

### =

+ 460 

### I, p + b y a dcsf



# Cl, 0~ 

## 1 

# 1. na ✓

.0 

# to. & tla

C_21 

# S ,

# MEK'o

DRY GAS METER CALIBRATION
Meter Number: 

### I Date: 

### k2•Na ~~~1 , ~~ 

### I 

# aj f 4 

# lv Ca i 'br 

### ator:
Wet Test Meter Vmsrd 

### Calibration Factor (C oG ) _ Dry Gas 

### Meter Vmsrd

Run No.: @ 

### pb: 02 ~~ 

### "H9 Control Module Vacuum: "Hg 

# n

~ 

### Wet Test Meter (No. Meter 

### Slm Eeadin9 Iemp, .e,,, End 9; 

### 14 a. .a33 cf -43 1 °F -130 "H Z p Start - Li a 

### 0.00

cf _'43" ' F - 1 

### -3 a "H 2 0 Avg. '3a 1033 cf 7 + 3° °F 1•3 0 "H Z O 

### Meter Temp.



### fieading : in S2t1t P,,, sd I. 3a8"cf ~ 

### 3 "F J3 °F 0.0fH 2 O 

## 4q9 , a69 cf 4.1_°F 12 °F 0- 0 

### f"H 2 0

- ~ 

### • OTI cf : ? -3° ° F o.o I"H 2 0 

# + ` j 6 Wet Test Meter Vmstd = 

### 17.65 x 

### q,4 3-3 D

~ 

### '3 + 460 x 

## l ' 0o3 (C f ) 

## 6 0 

## 4 Jcsf


## + o, 1 Dry Gas Meter Vmsrd = 

### 17.65 xa. 0
~ 

### 9 a~'~ 13.6 

### = a,03o.dcsf + 460



### c~ = a~ o ~ 

# a,U30 C_22 

# imYY~YO ~il~~~Y~O:~~~~~~ YWm ~f~a~YW~~YW~YR~ Y~~~~~~YO0OrO0~M ~_ ~Y~ ~Y~rr•~o~_Y~Y ~~~~ us~o~i~~ ~ ~~ ~ ~

# r,

8 

# d~ It:,K-v

DIGITAL TEMPERATURE INDICATOR NO.

CALIBRATION DATA



### Date: Mercury Temperature DTI 

### Media Iim. ~ (OE) 

### Ambient Air 1 

## 030 (9 1 ° F o F Ice Bath I D a.0 

# a°F 3d- 'F Boiling water 

## 0'

~ 

## l 5' a ~a -° ~ 0- 

## 13 ° F Oven 

## I. 

# oa 6,) v 

# rOven 

# 1 3 l 5 S OD°F 3 ya

~ 

## F Oven 

### ~ t

~~ 

## S 37 q°l= - 3 

## 76 ° ~ Oven 

## 3 6 ° Meter Adjusted? Yes No

— 

# /Y

Calibrator:

. ~ 

### Checked By: 

### ~~ 1

C-24 

# ri

## ---I

LI-i 

# ~ METCO --i~


# - 

# Scott Specia l 

# ty Gases, Inc.

® 1290 COMBERMERE STREET, TROY, MI 48083 (810) 589-2950 FAX:(810) 589-2134

~ CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS

Customer Assay Laboratory

, METCO ENVIRONMENTAL Scott Specialty Gases, Inc Purchase Order : 3067

Attn :!im Monfries 1290 Combermere Scott Project q 572186 16115 Dooley Road Troy, MI 48083 Dallas, TX 75244 ANALYTICAL INFORMATION ThIs certification was performed accordin g to EPA Traceability P ro tocol For Assay and Certifcation of Gsseous Calibration Standards; P ro cedure GI; Sepfember, 1993. Cylinder Number : ALM040839 Certificate Date : 10/26/94 Expiration Date : 10/26/96 Cylinder Pressure +: 1900 psig Previous Certificate Date : None ANAL,YZED CYL.INDER ComRonents Nitric Oxide Total Oxides of Nitrogen Certifled Concentration 18.72 ppm 19.10 ppm Analytical Uncertainty f1•/. NIST Directly Traceable Reference Value Only Balance Gas: Nitrogen +tb oot ase when eylinder prcssaue is 

# w a~ mr g saaces whieh at lesst ixlude Type Expiration Date Cylinder Number Concentration NTRM 1684 4/1/96 ALM-024582 95.2 ppm Nitric Oxide in Nitrogen



### ~ INSTRUMENTATION

Instrument/Model/Serial # Last Date Calibrated Analytical Principle NO : Horiba/OPE-235/483814 10/25/94 Chemiltuninescence

ANALYZER READINGS (ZP= Zero Gas R=Reference Gas T=Test Gas r=Correlation Coetticient) Components First Triad Analysis Second Triad Analysis Calibration Curve Nitric Oxide tHts:10119m Responto Urtits: mr polr. 10RGM Respanss Unils: mv tAKntr

~ WN •B:.C: 2 -Oi •!s 4 Z1-O.00 R1-95.20 T7 18.80 Z1a0.00 R1a95.20 Tt=18.70 r+=o.99999 NTRM 1684 R2-95.20 Z2-0.00 T2=18.70 R2=95.20 Z2=0.00 T2=18.70 Constams: A=0.000000000 Z3--0.00 T308.70 R3-
- 95.20 Z3=0.00 T308.70 R3=95.20 8=1.000000000 C=0.000000000 Avp. Cone. d Cust. CyL 18.73 ppm Arp. Cona ol Cust. Cyt 18.70 ppm 

### I I 

### I 0=0.000000000 E=0.000000000

Special Notes

Customa C-26~ ..i
... ~-~. •.~ .~ L ~ • .• ~ ;. .. : ~:i~.!~ -.. .. ., ,r..

.. . . • •
. . •,.:_ --- ,. ~ y '

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- ~ ', ' ~ :.~~;~i•;~ =.C: • ~.~Y, t , ; ~ ' ' a

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_ . t •

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~ ,,L:.;". . • ,' -r _ ; .: .: • • _ :, . a • .. - !1l'

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: 

# 0 : ~ 

# Scott S ecialtyi:G

~ 

# ses, Inc :. I?.,. ~. ~ 

# - . ~ . •. 1290 y

C

~ OMBERMERE STREET. TROY, MI 48083 ~ •. :: ( 810) 589-2950 FAX:(8 _ 10) 589-2134 .:

. ~ .. T . ' v ` ~r~~ t •

~ - !r,~.~Py 7 ~.~~~ ~ 7. ~ '. ~ - t3.

~ ' '(i • . !.. , • r
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~ 4 '?' ~.~~'~'~ 'n w . ~ ,.. ;'r .
.. ~t~ .Y` : .; . - _! ~ CERTIFICATE `:°

OF ANAL•YSIS EPA PROTOCO

~ t ` • ~ •'."

~ " '

~ • ;

~ . •

~ - .. - ~ ~ ; y., ~ ~ :.. _ ~ L GAS ,. ~ - :

~ '_ _ _ : '• • ~=:~~ ;:::= ~.`~ . •

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~ ' ~~ . L

~ :.. 'b•: ?► ;'. ' _ • l•`.: - ' ~ ~ • ' ' i

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. : Custome ~~~k'~,~~~:~~ ~ ~~'~ .'~'~~ : AssayL.aboratory ":

~ ':;;.'

~ '' —.; _4

. `

~ n Specialty GasesIncc: `_' Purchase Order .• r 2648 -`• - 16115 DOOLEY ROAD ~ _ , 1290 Combermere Scottct # 564105 DALLAS, TX 75244= ~; ~ _' Troy r 1~ 48083 Proje :_ti' ` ~

• ~ r. :

~ r

~ : '.

~~~

t,' -`_ ~ ; "-""' ~ .:
~ '

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_ . _ . , . _ , . . . • • _ ' •

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. . ' . . - . .

`~ ~ • ~ .~ '.- '... ~a , ~ '" ... ' :si.- • ~`~ :; :. ~•~ +.

~ INFORMATI

°

~ ANALYTICAL ~ :. ON ~~ . . . . . . • . This certifieation was perfomud aecordin g to EPA Traceability Protoeol For Assay and Certifieation of Cmseo ~ on Standards; P ro cedure Gl; September, 1993. us

_ linder Number :, BAL1881 - Certificate Date : 4/11/94 Expiration Date : 4/11/96 ~ nder Pressure +: 1900 psig Previous CertiGcate Date : None

.


## ~ -': 

## ~ _ . . . . •

~ —x.omponenu

- Nitric_ Oxide

Tota! Oxides of Nitrogen Certified Concentration 46.15 ppm Analvtical Uncertaintv+ f1•. NIST Directly Traceable 47.40 ppm Reference Value Only

~ . • -• 

## '~ '"• ..'
. ' ' • .. = Balance Gas: Nitrogen
r t -l Awalytical Do aa nse whea eylinder presutue is below I5 0 psis.

aecurxY is mdusive of asual lmowo error sourea M ~~ u least i nelude D

~ maon of tbe mea m smeat pnoeessa•

~ s• ~ t
~ FFF'RENCE STANDARi ~ Expiration Date Cylinder Number Concentration



## _ 1694 . 4/1/96

.



## ~

. . • • ALM-024622 •
. 95.3 ppm Nitrie Oxide in Nitrogen

.
3UMENTATION ment/ModeUSerial # . ion • ba%OPE-235/483814:'..

. - 

## ~ • 

## ~ ' Last Date Calibrated 4/5/94 ' Analytical Principle Chemiluminescence

(Z-Zero Gas R-Reference Gas T=Test Gas rmCorrdation CoeQicient) , Frst Triad Analysis :' Second Triad Analysis • Calibration Curve' -

# .~: 

# Scott Specialty 

# Ga ses, I 

# nc. 1290 COMBERMERE STREET, TROY, MI 48083 (810) 589-2950 FAX:(810) 589-2134 CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS Customer Assay Laboratory METCO ENVIRONMENTAL Scott Specialty Gases, Inc Purchase Order : 3067 Attn : Jim Monfries 1290 Combermere Scott Project N: 572186 16115 Dooley Road Troy, ,II 48083 Dallas, TX 75244 ANALYTICAL INFORMATION This certification was perfomled accordin g to EPA Traceability Protocol For Assay and Certification of Gaseous Calibration Standards; Procedure G1; September, 1993. ~

Cylinder Number : ALM038783 Cylinder Pressure + : 1900 psig
ANALYZED CYLINDER ComFonents Nitric O:ide Total Oxides of Nitrogen Certificate Date : 10/26/94 Previous Certificate Date : None

Certified Concentration 85.40 ppm 86.10 ppm Expiration Date : 10/26/96

Analvtical Uncertainty tl% NIST Directly Traceable Reference Value Only

~~ Balance Gas: Nitrogen +Do oot use whea rylindrr presssure is below 150 psig. aal •Aytieal aoeurxy is inelasrve of usual Imown error souroes whieh st leut inelude precision of the meuuremeat proeessa. REFERENCESTANDARD Type Expiration Date Cylinder Number Concentration NTRM 1684 4/1/96 AI.M-024582 95.2 ppm Nitric Oxide in Nitrogen

INSTRUMENTATION Instrument/ModeUSerial Il Last Date Calibrated Analytical Principle NO : Horiba/OPE-235/483814 10/25/94 Chemiluniinescence

ANALYZER READINGS (7
- uro Gas R=Reference Gas T=Test Gas r=Correlation CoelTicient) Components First Triad Analysis Second Triad Analysis Calibration Curve Nitric Oxide Oate:10l19f94 Rssporsse UrAs mv Date: 10/26J94 Resporw Urws mv CoKiwaooe_A•B:•Cs 2 •Di •t : 1 Z1•0.00 R1-9520 T1-S5.50 Z1.0.00 R1=95.20 T1-85.60 r-0.8B999 NTRM 1684 R2=95.20 Z2=0.00 T2=85.10 R2=95.20 Z2=0.00 T2=85.60 Corntarft: A=0.000000000 Z3=0.00 T3=85.00 R3=95.20 Z3=0.00 T3=85.60 R3--95.20 8=1.000000000 C=0.000000000 Avp. Cona of Cusi CyL 95.20 ppm Avy. Cona of Cust Cyt 85.60 ppm 0-0.000000000 E-0.000000000

WcoID_1 Special Notes

Customer C-28

# li M 

# ETC O ~ ~

APPENDIX D 

### Field Testing Data

g6-30 D-1 

### lp~P E

J v cc 

# ~ ~ 

### d 

# lL.

~

~ Y

O W 1,
w R ~

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Moisture Conteni : Final Weight

Initial Weight Increase Fnal Weight Initial Weight Increase Fnal Weight Initial Weight Increase Fnal Weight Initial Weight Increase Fnal WeightInitial WeightIncrease Fnal Weight Initial Weight Increase Final Weight Ini6al Weight Increase Water Weight Gain



# V. _ g SO Z = 

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### Increase Final Weight Initial Weight 

### Increase 

### 1 ,. ' Impinger Box No. Impinger 1

Impinger 2

Impinger 3

Impinger 4

Impinger 5

InVinger 6

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Moisture Conteni : Fnal Weight
~ Z ~' s Water Weipht Gain Impinger 1 

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Impinger 1 Final Weight Impinger 1

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MW, MW =



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~ 

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# aa Impinger 2 Fnal Weight G Impinger 3 0• 0

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Initial Weight q V. _ Increase 0. U Impinger 6 Impinger 4 Final Weight 4rign Impinger 7

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_ Initial Weight T 

### ~ _ ~ ---- 

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Moisture Content : %M = ~•~~ ~ M a = r SS` ~ MW

a = r MW =



### Pm Pb + 13.6 

### 1~ ~3.6 v 3
. ~ c 3 

### Vm

~ d 

### = 17.65 Vm _ 17.65 x ~q~~4 

### ± ,S p, ~


## ~ T m + 460 

## ~~ 5 a + 460
Vw a „ = 0.0472 x Vw = 0.0472 x
~ 

## !

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Initial Weight 

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### 11 M Impinger 3

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# V. _ Impinger 3 Fnal Weight g SO Z = Impinger 5 

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0 0S V m = 

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# ~ T i

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C P = Impinger 7 Fnal Weight P. = ' / 'H 2 0 ~ i 'Hg

1®itial Weight T. = o l °F
~

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### D 371 Moisturre Content : %M = M a MW

a = MW = ✓



### Pm Vm = 17.65 

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### x q ~ ± 1 

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+ 460 

### ~ - . 

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, % Moisture = Vw- 0 ,. x 100 = 

### ~ . 

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V% + Vw

9 „ V, = 5123.8 x x (pm ACFM:
~ 

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### x x x x( ) Z D-16 

## SCFM: i %EA: 

## mr 

### i 

# ~ ~o

APPENDIX E 

### Analytical Data

96-30 E-1 

# f- 5

# ~ I4ETCO Environmental Particulate Malysis Summary 

# m

~ .1, ' %--
• • j ~~L ~ ~ - / _ ~/ ~ 

### Date Analysis Coarpleted Unit Tested

- ~



### Run No. Particulate on Filter (mg) /~, ~ ~

, 

### ?4 , 

### 3 13 , ~ 

### P-r— 1+2-0 Particulate in Front wash (mg 

### , , ~


### , 

### 1'F (mg) Particulate in Impinger * 1 (mg) Atr (IDg) 

# I o. I 

## ~ RT/

. 

# ~Y~ 

# aL

~ 

# &

- ,



# ~ / llnalyst


### le • Less Acetone Residue

E-2r 'l 

### METCO Environmental Particulate Analysis EPA Method S

Stack Filters

_ Job Number Location



### Job Name ~ 

### Unit Tested
Desiccator Time In 530 3//6 

### Desiccator Time Out 

### VS Z ~ 

### Run No. 

# _L Filter No. r 37 Filter $ Particulate + Tare Weight (g) Tare Weight (g) 

# F ilter $ Particulate (g) Filter & Particulate Average (g) 

### D• S/ Initial Filter Weight (g) ,O / ~ 

### Total Particulate (mg) ~
Run No. Filter No. 

### Filter & Particulate + Tare Weight (g) Tare Weight (g) ✓ Filter & Particulate (g) 

### , 5 p O,S o Filter & Particulate Average (g) 

### Initial Filter Weight (g) ~ 

### Total Particulate (mg) ,3 ~
Run No. 

# ~_ Filter No. 

### Filter & Particulate + Tare Weight (g) Tare Weight (g) ~ Filter & Particulate (g) ~~ ✓ ,~ 3g jJ , s~~

Fi lter $ Particulate Average (g) S a;.38 ~ Initial Filter Weight (g) U. 5
- 1 0 a--

~ 

### Total Particulate (mg) ~

, - - 

### Analyst

E-3 1 

# A

# ~ METCO Environmental Particulate Analysis EPA Method S 

# ~ Stack Filters

Job Number 

### 74

0- d Location


## ~ Job Name 

## ,/3 ~~ ,~jl~ Unit Tested


### Desiccator Time In Des.iccator Time Out 

### /svl
Run No. ee& Filter No. 

### Filter & Particulate + Tare Weight (g) 

### Tare Weight (g)



# ~ Filter F, Particulate (g) Filter f, Particulate Average (g) 

### Q. S'OS
~ 

### Initial Filter Weight (g) Q, ~d ~ 

### Total Particulate (mg) 0,3 ~


### Run No. Filter No. Filter & Particulate + Tare Weight (g) Tare Weight (g) 

# r Filter $ Particulate (g) Filter f, Particulate Average (g) Initial Filter Weight (g) Total Particulate (mg)

Run No. Filter No. Filter F, Particulate + Tare Weight (g) Tare Weight (g) Filter f, Particulate (g) Filter $ Particulate Average (g) Initial Filter Weight (g) Total Particulate (mg)



## ~ Analyst

E-4 

# m

### ~ METCO Environmental Particulate Analysis EPA Niethod S

~ /4 ce0 ~1~ Front Wash



### ~ Job Number 

### ql - L ocation ~

Job Name Unit

. Desiccator Time In L Z. Des iccator Time Out 

### / 3 ZS ~ gs 2 2 Z 1
Run No. Volume (ml) 

### .2VO Final Weight (g) 

### / , 

### ~ , j /a , 6J 12 Initial Weight (g) 

### /a1,, !1,Zg /,2
~ , 

### ,/ 2gj Particulate Wei ht () 0 

### , d/d d 10

, 

### tO /o 0 2 Particulate Average (mg) Less Acetone Blank (mg) Total Particulate (mg)
Run No. 

### 2 Volume (ml) 

### / 94"o Final Wei ht ( ) Ilo Z 3 ( o . /A 7 ✓ Initial 1Veight (g) ,3! 6S67 

# Y Particulate Weight (g) Particulate Average (mg) 9, 1-- Less Acetone Blank (mg) Total Particulate (mg)

Run No. ~~ Volume (ml) l~ s Final Weight (g) lllfZ Initial Weight (g) Particulate Weight (g) 0 

### ~ 2 Particulate Average (mg) lo• ~ ~ Less Acetone Blank (mg) ~ Tota1 Particulate (mg) '

Acetone Blank Volume (ml) c ~ 50 Final Weight (g) 3 S Initial Iti'eight (g) 

### 1.33L/ Di fference (g) A Average (mg) 

## /,S ~ * mg/ 1 * Note: If greater than 7.9 mg/1, use 7.9 mg/l.


## ~ E-S Analyst ~~ /0 

### ~ METCO Environmental Particulate Analysis EPA Method S Back Half Analysis

--, Job Number 

### ~ — Q U /1 

# ~o~ tion
~~ r ~~ d~~, ~

Job Name O-el ~ Unit Tested Desiccator Time In 163° 217 V f L Zo Desiccator Time Out 

### /3 a y ro 9w zJ
Run No. Volume (ml) Final Weight (g) ~ 

## , g ,f

, 

# a a ✓ Ini tial {4eight (g) Particulate Weight (g) Particulate Average (mg) 

### .3

~ Less Ammonium Sulfate (mg)

— Total Particulate (mg)

~ Run No . A Vo lume (ml ),3.fy t 

### ~ Final Weight (g) Okg V 14 If, 

### ~ ✓ Initial Weight (g) 

## /W Particulate Weight (g) 

### 3 3 Particulate Average (mg) Less Ammonium Sulfate (mg)

~— Total Particulate (mg)
Run No. \. 

### ~ Volume (ml) Final Weight (g) 

## ~ ~ g' l „~ s ✓ Init ial W eight (g) Il a


# ~ Particulate Weight (g) Particulate Average (mg) Less Ammonium Sulfate (mg) ~— Total Particulate (mg)
Run No. Volume (ml) Final Weight (g) Initial Weight (g) 

# F Particulate 1Veight (g) Particulate Average (mg) Less Ammonium Sulfate (mg) Total Particulate (mg)

1 

# 4 --- Analyst £-7 0 

# ~

# HIM 

# Eric oErmRonaynTAC 

# ~

~

:j

### 0 5 10 15 20

20

10

,'11 uS 

### METCO ENVIRONMENTAL

Datk Rrpr• ~ ~ ccreed Qti 02/28 /199h 14 : 41: 24 ; Sample Name: R1 FILT KILN S'1'ACK 25ML Date: 02/28/10S6 11:07:49 ; 

### ; Data File : C:\DX\DATA\ANIONS\96-30\2-280011.D05 ; ; Method : C:\DX\METHOD\AS10.MET ; ACI Address: 1 System: 1 Inject#: 5 Detector:CDM-2 ; i; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ; ----------------------------------------------------------------------------- Calibration Volume Dilution Points Rate Start Stop Area Reject -------------------------------------------------------------------- ' : External 1 7022 5Hz 0.00 23.41 4000

~ 

### Component Report: Components Found

~ 

### Ret Component Area Height Concentration Time Name ppm ------------------------------------------------------------- 4.63 Fluoride 127000714 14276211 2.061 j

------------------------------------ 

### Totals 127000714 14276211 2.061 

# n

1 1 . 

### File: 2-280011.D05 Sampie: R1 FILT KILN STACK 25ML

Minutes 100%

80%

60%
40°,/0

20%

0%

£-9 q 

## ~

### 0 5 10 15 20 25 Minutes METCO ENVIRONMENTAL 

### Data keprocessed On 02/28/1996 14:42:41 ; Sample Name : R1 DIFW KILN STACK Date : 02/ 2'7/ 1996 12 : 04 : 00 ; ; Data File : C: \DX\DATA\ANIONS\96-30'\2-270021. DO1 ; 

### ; Method : C:\DX\METHOD\AS10.MET ; ACI Address: 1 System: 1 Inject#: 1 Detector:CDM-

~ 

### ' ; 

## a ; Analyst
. Column: AS10 .4mm, AG10 Gaurd Column ; ----------------------------------------------------------------------------- Calibration Volume Dilution Points Rate Start Stop Area Reject
-------------------------------------------------------------------- External cP
~ 

### S 1 1 13500 5Hz 0.00 25.35 4000 Component Report: Components Found i Ret Component Area Height Concentration Time Name ppm ------------------------------------------------------------- 4.63 Fluoride 238502126 27276624 3.871
~ 

### ------------------------------------ Totals 238502126 27276624 3.871 

# I

~ 

### Fle: 2-270021.D01 Sample: R1 DIFW K(LN STACK

~ 30

20 us
10

0 

### 100%



### m

.


### 60%

40%

20%



### 0%

F-in100

80 60 uS 40 20 0 

### File: 2-270001.D07 Sample: R1 BH+11 KILN STACK 2X 120

0 5 10 15 20 25 ~ 

# r4 i

. METCO ENVIFiONMENTAL 

### Data Reprocessed On 02/28/1996 14:44:06 

### _ ----------------------------------------------------------------------------- ; Sample Name: R1 BH+I1 kILN STACIi 2X Date: 02/27/1996 17:15:13 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-270001.D07 ; ; Method : C:\DX\METHOD\A0 '10.MET ; ; ACI Address: 1 System: l In : iect#: 7 Detector:CDM-2 ; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column

, 

### Calibration Volume Dilution Points Rate Start Stop Area Reject 

### ' -------------------------------------------------------------------- External 

### Ao yl 1 7500 5Hz 0.00 25.00 4000
~ - 

### Component Report: Components Found
:" A Ret Component Area Height Concentration Time Name ppm

' ------------------------------------------------------------- 

### 4.63 Fluoride 780813280 80415488 12.673 :.j ------------------------------------ 

### Totals 780813280 80415488 12.673

~ 100%

80%

60%

40%

20%

0%


### Minutes

E

- 11

### 100%

80%

60%

40%

20%

0% 

### Fi1e: 2-280001.D09 Sample: R1 12,3 KILN STACK

0 5 10 15 20 25 METCA ENVIRONMENTAL 

### Data Reproc:essed On 02/28/1996 14:45:46 ; Sample Name : Ri. 12,3 KILN STACK 

### Date : 02!28/1996 12 : 53: 00 ' ; Data File : C:\DX\DATA\ANIONS\96 =30'\2-2800U1.D09 ; ; Method : C:\DX\METHOD\AS10_1 •1ET ; ACI Address: 1 System: 1 Inject#: 9 Detector:CDM-2 ; ; Analyst
_ Column: AS10 ,4mm, AG10 Gaurd Column ;

----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

### Calibration Volume Dilution F'oints Rate Start Stop Area Reject
-------------------------------------------------------------------- External 1 1 7500 5Hz 0:00 25.00 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm
-------------------------------------------------- ----------- 4.63 Fluoride 80158578 9212411 1.301
------------------------------------ Totals 80158578 9212411 1.301 '1



### 30

20 uS 10

0

PAin.utes

E-12 

# q510 5 10 15 20 25 

### METCO ENVIRONMENTAL Data Reprocessed On 02/28/1996 14:53:29 ; Sample Name: R2 FILT KILN STACK 25ML Date: 02/28/1996 11:30 58 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-280001.D06 ; ; Method : C:\DX "METHOD\AS10.MET ; ; ACI Address: 1 System: 1 Inject#: 6 Detector:CDM-2 ; ; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ;

----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

### Calibration Volume Dilution Points Rate Start Stop Area Reject
-------------------------------------------------------------------- External ;LS 

### 1 1 6021 5Hz 0.00 25.09 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm -------------------------------------------------------------- 4.63 Fluoride 177207579 19993400 2.876
------------------------------------ Totals 177207579 19993400 2.876 Fle: 2-280001.D46 Sampie: R2 FILT KILN STACK 25ML 30

20

uS 10

0

Minutes

E-13 

# ey r - I

100%

80%

60%

40%

20%

0%0 5 10 15 20



### us 20 40

Kil

10

0 

### METCO ENVIRONMENTAL

Data Reprocessed On 02/28/1996 14:54:37 ; Sample Name: R2 DIFW KILN STACK Date: 02/27/1996 14:45:29 ; ; Data File : C:\ ,DX\DATA\ANIONS\96-30\2-'270031.D01 ; 

### ; Method : C:\DX\METHOD\A0 '10.MET ; ; ACI Address: 1 System: 1 Inject#: 1 Detector:CDM-'- 7 1 ; ; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ; 

### -----------------------------------=----------------------------------------- ----------------------------------------------------------------------------- Calibration Volume Dilution Points Rate Start Stop Area Reject


### -------------------------------------------------------------------- External ~!~"~ 

### 1 1 4500 5Hz 0.00 23.43 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm
------------------------------------------------------------- 

### 4.61 Fluoride 223330444 25198928 3.625


### ------------------------------------ Totals 223330444 25198928 3.625 

# 9

file: 2-270031.D01 Sampie: R2 DIF1N K1LtV STACK

Minutes

E=14 100%

80%

s0

~ io

40%

20%

0%

### 0 5 10 15 20 

## ~
,

,- I



### METCO ENVIRONMENTAL Data Reprocessed On 02/28/1996 14:56:05 ; Sample Name: R2 DIFW KILN STACK DUP Date: 02!27/1996 15:01:54 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-270001.D02 ; ; Method : C:\DX\METHOD\AS10.MET ; ACI Address: 1 System: 1 In,,iect#: 2 Detector:CDM-2 ; !; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; ' ----------------------------------------------------------------------------- ----------------------------------------------------------------------------- Calibration Volume Dilution Points Rate Start Stop Area Reject
-------------------------------------------------------------------- External 1 1 4500 5Hz 0.00 23_44 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm

------------------------------------------------------------- 

### 4.60 Fluoride 224331175 26786242 3.641
------------------------------------ Totals 224331175 25786242 3.641 

# m File: 2-270001.DQ2 Sample: R2 DiF1N KlLN STACK DUP

40

, 30

20 uS
10

0 100%

80%

SO%
40%

20%

0%
Minutes

E

- 15 +100%

:T ~ •.

60%

40%

20%

0% 

### Fle: 2-270001.D08 Sample: R2 BH+19 KlLN STACK 2X

0 5 10 15 20 25 METCO ENVIRONMENTAL 

### Data Reprocessed On 02/28/1996 14:57:40 ; Sample Name: R2 BH+I1 KILN STACK 2X Date: 02/27/1996 17:41:40 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-270001.D08 ; Method : C:\DX\METHOD\AS10.MET ~ 

### ACI Address: 1' System: 1 Inject#: 8 Detector:CDM-2 ; ; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ; Calibration Volume Dilution Points Rate Start Stop Area Reject External 35? 1 

### -------------------------------------------------------------------- 1* 7500 5H.:, 0.00 25.00 4000 

### Component Report: Components Found Ret Component Area Height Concentration ; Time Name
------------------------------------------------------------- ppm 4.63 Fluoride ' 453096413 48626777
------------------------------------ 7.354 Totals 453096413 48626777 7.354 ~ 

### I .;

~
100

80
60
uS 40
20
0



### Minutes

F -1 fi100%

80%

60%

40%

20%



### 0°0 0 5 10 15 20 25 Us 40 

### Fle: 2-270001.D09 Sample: R2 BH+11 KILN STACK 2X 100

20 ~ -X : e ;



### N METCO ENVIRONMENTAL

Data Reprocessed On 02/28/1996 15:01:01 ; Sample Name: R2 BH+I1 KILN STACK 2X DvP• Date: 02/27/1996 18:08:05 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-270001.D09 ; ; Method : C:\DX\METHOD\AS10.MET ; ; ACI Address: 1 System: 1 Inject#: 9 Detector:CDM-- ' , ; ; Analyst . Coltunn: AS10 ,4mm, AG10 Gaurd Column ; ----------------------------------------------------------------------------- Calibration Volume Dilution Points
-------------------------------------------------------------------- Rate Start Stop Area Reject External 1 1 7500 5Hz 0.00 25.00 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name
------------------------------------------------------------- ppm 4.63 Fluoride 455057069 48676116
------------------------------------ 7.386 Totals 455057069 48676116 7.386



### Minutes

E-17 

# ~ D '1

### File: 2-280001.D11 Sample: R2 12,3 KILN STACK

14 12 10 $ 6 

### uS 4 2 

### 0 -2 -4 100%
$0%

60%

40%

20%

0% 

### 0 5 10 15 20 25 

# .1

METCO ENVIRONMENTAL Data Reprocessed On 02/28/1996 15:09:27 ; Sample Name: R2 I2,3 KILN STACK Date: 02/28/1996 13:47:06 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-280001.U11 ; ; Method : C:'\DX\METHOD\AS10.11ET ; ; ACI Address: 1 System: 1 In,,iect#: 11 Uetector:CUM-2 ; ; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ; Calibration Volume Dilution Points Rate Start Stop Area Reject External - 10`1 1 -------------------------------------------------------------------- 

### 1 7500 5Hz 0.00 25.00 4000 ********************** Component Report: Components Found Ret Component Area Height Concentration Time Name
----------=-------------------------------------------------- 

### ppm 4.64 Fluoride

, 

### 65909582 7924593 1.070 ' Totals 65909582 ------------------------------------ 7924593 1.070 

# 0

Minutes

E-18 a 

## ~017

PZI7 100%
$0%

60%

40%

20%

0% uS 10



## n

-10 

### File: 2-280001.D07 Sample: R3 FILT KILN STACK 25ML 

# n

~



### METCO ENVIRONMENTAL Data Reprocessed On 02/28/1996 15:13:41
; . Sample Name: R3 FILT KILN STACK 25ML Date: 02/28/1996 11:54:24 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-280001.D07 ; Method : C:\DX\METHOD\AS10.MET ; ACI Address: 1 System: 1 Inject#: 7 Detector:CDM-2 ; ; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ; :+ Calibration Volume Dilution Points Rate .Start Stop Area Reject
-------------------------------------------------------------------- External 1 1 6000 5Hz 0.00 9_89 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm
------------- ----------------------------------------

- 

### --------

~ 

### 4.61 Fluoride 114010185 12831945 1.851
------------------------------------ Totals 114010185 12831945 1.851

~



### 0 1 2 3 4 5 6 7 8 9 Minutes


## E

- 

## 19 IA100%

80%

60%

40%

20%

0% 

### File: 2-270001.D03 Sample: R3 DIFVY KILN STACK

0 5 10 15 20 25 

### ~

~

IIETCO ENVIRONMENTAL 

### Data Reprocessed On 02/28/1996 15:18:19 ; Sample Name: R3 DIFW KILN STACK Date: 02/27/1996 15:23:21 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2- '70001.D03 ; ; Method : C:\DX\METHOD\A 'SlO.MET ; ACI Address: 1 System: 1 Inject#: 3 Detector:CDM-2 ; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; ----------------------------------------------------------------------------- 

### Calibration Volume Dilution Points Rate Start Stop Area Reject External -------------------------------------------------------------------- 

### 1 6000 5Hz 0.00 25.00 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name
------------------------------------------------------------- 

### ppm 4.61 Fluoride 

### j

------------------------------------ 

### 244031574 27952445 3.961 Totals 244031574 27952445 3.961

60 

### 50 40 30 uS 20 10 0 -10
Minutes

E-20 / a/

### 0 5 10 15 20 25



### 30 uS 20 10 60 50
rsliei



### 0 -10 

### METCU ENvIRUNMENTAL

Data Reprocessed Un 02/28/1996 15:19:58 ; Sample Name: R3 DUP DIFW KILN STACK Date: 02/27/1996 15:44:48 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-270001.D04 ; ; Method : C:\DX\METHOD\AS10.MET ; ; ACI Address: 1 System: 1 Inject#: 4 Detector:Cl?M--' ; ; Analyst
. Column: AS10 .4mm. AG10 Gaurd Column ; Calibration Volume Dilution Points Rate Start C

- itop Area Re,,iect
-------------------------------------------------------------------- External 1 1 6000 5H.: 0.00 25.00 4000 Component Report: Components Found Ret Component Area Height Concentration
.- Time Name ppm ------------------------------------------------------------- 4.60 Fluoride 245658097 27994352 3.987 I 

### ------------------------------------ Totals 245658097 27994352 3.987

~ 

### ~

;



### Fle: 2-270001.D04 Sample: R3 DUP DIFW KILN STACK

Minutes 100°,%

$O o ,~ o

60%

40%

20%

0%

E-Z1 ) DA100%

80 o ~ a

s0°io



### 40%
20%

0% 

### File: 2-270001.D10 Sampie: R3 BH+11 KILN STACK 2X

0 5 10 15 20 25 

### METCO ENVIRONMENTAL Data Reprocessed On 02/28/1996 15:21:26 ; Sample Name: R3 BH+I1 KILN STACK 2X Date: 02!27/1996 18:34:26 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-270001.D10 ; ; Method : C:\DX\METHOD\AS10.MET ; ; ACI Address: 1 System: 1 Inject#: 10 Detector:CDM-2 ; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ;
----------------------------------------------------------------------------- 

### Calibration Volume Dilution Points Rate Start Stop Area Reject

-------------------------------------------------------------------- 

### External 1 7500 5Hz 0.00 25.00 4000 Component Report: Components Found Ret Component _ Area Height Concentration Time Name ppm
------------------------------------------------------------- 

### 4.63 Fluoride 720486248 72745516 11.694

~ ------------------------------------ 

### Totals 720486248 72745516 11.694 ~

120

100 80 s0 us 40 20 0 -20

Minutes

E-22 /P °100%



### 80%

60%

40%

20%

0% 

### Fie: 2-270001.D11 Sample: R3 BH+11 KILN STACK 2X DUP

0 5 10 15 20 25 METCO ENVIRONMENTAL Data Reprocessed On 02/28/1996 15:23:54 ; Sample Name: R3 BH+I1 KILN STACK 2X DUP Date: 02/27/1996 19:00:51 ; ; Data File : C:\DY ,\DATA\ANIONS\96-30\2-270001.D11 ; ; Method : C:\DX\METHOD\AS10_MET ; ; ACI Address: 1 System: 1 Inject#: 11 Detector:CDM-2 ; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; Calibration Volume Dilution Points
-------------------------------------------------------------------- Rate Start Stop Area Reject External 1

. 

### 1 7500 5H.: 0.00 25.00 4000

~ 

### Component Report: Components Found Ret Component Area Height Concentration Time Name
------------------------------------------------------------- ppm 4.64 Fluoride 728918167 73301938
------------------------------------ 11.831 Totals 728918167 73301938 11.831 

# ~

100



### 80
60 uS 40
20 0



### Minutes

E-23 

# !p~20

uS 10

~ 

### METCO ENVIRONMENTAL

Data Reprocessed On 02/28/1996 15:25:51 ; Sample Name: R3 I2,3 KILN STACK Date: 02/28/1996 14:13:32 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2- '-:'80001.D1

~ 

### ' ; ; Method : C:\DX\METHOD\AS10.MET ; ; ACI Address: 1 System: 1 Injecttt: 12 Detector:CDM-2 ; ; Analyst . Column: AS10 .4mm. AG10 Gaurd Column ; -----------------------=----------------------------------------------------- ----------------------------------------------------------------------------- Calibration Volume Dilution Points Rate Start Stop Area Reject
-------------------------------------------------------------------- E 

### xternai 4000 Component Report: Components Found 

### ~

Ret Component Area Height Concentration Time Name ppm ------------------------------------------------------------- 4.63 Fluoride 92077963 10534162 1.495 j
------------------------------------ 

### Totals 92077963 10534162 1.495 Fie: 2-280001.D12 Sampie: R312,3 KILN STACK 100%



### 80%

60%



### 40%

20%

0% 0 5 10 15 20 25 Minutes

E-24 ~~ 

# r100%

80%



### 60%

40%

20%

0% 

### Fle: 2-280001.D01 Sample: R3 12,3 KILN STACK DUP

0 5 10 15 20 25 30 

### METCO ENVIRONMENTAL Data Reprocessed On 02/28/1996 15:28:00 ; Sample Name: R3 I2,3 KILN STACK DUP Date: 02/28/1996 14:39:33 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-280001.D01 ; ; Method : C: \DX\METHOD\AS10. MET 

### ; ACI Address: 1 System: 1 Inject#: 1 Detector:CDM-2 ; ; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ; Calibration Volume Dilution Points Rate Start Stop Area Reject
-------------------------------------------------------------------- E 

### xternal 1 1 5928 5Hz 0.00 30.87 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm ---------------------------------------------------------- 4.63 Fluoride 91038351 10500850 1.478
------------------------------------ Totals 91038351 10500850 1.478 

### ~

~



### 20

10 uS

0



### Minutes 

# Ib~ F-25100°,%



### 80%

60%

40%



### 20%

0% 120 100 80 uS 60 40 20 0 

### File: 2-280001.D03 Sample: CCV 20 PPM F STD 

### METCO ENVIRONMENTAL Data Reprocessed On 02/28/1996 09:56:24

- - ---------- 

### ; Sample Name: CCV 20 PPM F STD Date: 02/28/1996 09:46:29 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-280001.D03 ; ; Method : C:\DX\METHOD\AS10.MET ; ACI Address: 1 System: 1 Inject#: 3 Detector:CDM-2 ; ; Analyst . Column: AS10 ,4mm. AG10 Gaurd Column ; Calibration Volume Dilution Points
-------------------------------------------------------------------- 

### Rate Start Stop Area Reject External 1 1 6924 5Hz 0.00 28.85 4000 ********************** Component Report: Components Found Ret Component Area Height Concentration Time Name
------------------------------------------------------------- 

### ppm 4_56 Fluoride 1240303639 83011754
------------------------------------ 

### 20.131 Totals 1240303639 83011754 20.131

~ 

### `1

0 5 10 15 20 25 

### Minutes

£-26 

# /D `

### 0 5 10 15 20 W Fle: 2-280001.D02 Sample: CCV 5 PPM F STD

40

Kil
uS 20

10

X 100%

80%

60°l0

40°./0

20%

0% 

### METCO ENVIRONMENTAL ; Sample Name: CCV 5 PPM F STD Date: 02/28/1996 08:43:10 ; ; Data File : C:\DX\DATA\ANIONS\.96-30\2-280001.D02 ; ; Method : C:\DX\METHOD\AS10.MET ; ; ACI Address: 1 System: 1 In,iect#: Detector:CDM-2 ; ; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ; ----------------------------------------------------------------------------- 

### Calibration Volume Dilution Points Rate Start Stop Area Reject
-------------------------------------------------------------------- 

### External 1 1 7212 5Hz 0.00

~~ 

### 4.04 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm ------------------------------------------------------------- 

### 4.53 Fluoride 315690440 23811816 5.124
------------------------------------ Totals 315690440 23811816 5.124



### Minutes

E-27 

# ~ l~

### 0 5 10 15 20 

### r i ~



### METCO ENVIRONMENTAL Data Reprocessed On 02/28/1996 16:21:14 ; Sample Name: BL FILT KILN STACK 25ML Date: 02/28/1996 10:39:39 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-280001.D05 ; ; Method : C:\DX\METHOD\AS10.MET ; ; ACI Address: 1 System: 1 Inject#: 5 Detector:CDM-2 ; ; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ; Calibration Volume Dilution Points Rate Start Stop Area Reject

-------------------------------------------------------------------- 

### External 1 1 7183 5Hz 0.00 23.94. 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm

------------------------------------------------------------- 

### 4.63 Fluoride 20691457 2396176 0.336

------------------------------------ 

### Totals 20691457 2396176 0.33E $ Q F+le: 2-280001.D05 Sampie: BL FILT KILN STACK 25ML 7.0 6.0 5.0 

### 4.0 uS 3.0 

### 2.0 1.0 

### 0.0 -1.0 

### -2.0 

# I 100%



### 80%

60%
40°,/0

20%

0%
Minutes

E-28

## ri

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## O U J cc_ 

## E-29 

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uS 10

0 

### 0 100%

a0%

60%

40%

20%

0% 

### File: 2-270041.D01 Sampie: R1 COMP KILN INLET 50X

0 5 10 15 20 25 

### yETCO ENVIRONMENTAL Data Reprocessed On 02/29/1996 08:29:51 ; Sample Name: R1 COMP KILN INLET 50X Date: 02/28/1996 15:30:48 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-270041.D01 ; ; Method : C:\DX\METHOD\ASlO.MET

~ 

### ; ACI Address: 1 System: 1 In,iect#: 1 Detector:CDM-2 ; ; Analyst
. Column: ASIO ,4mm. AG10 Gaurd Column ; ----------------------------------------------------------------------------- Calibration Volume Dilution Points Rate Start Stop Area Reject
-------------------------------------------------------------------- External 1 1 6563 5Hz 0.00 27.34 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm ------------------------------------------------------------- 4.63 Fluoride 105566240 11498220 1.713
------------------------------------ Totals 105566240 11498220 1.713 

## ~

Minutes

E-30

### 0 5 10 15 20 25

20

uS 10



### L A?ETIC'0 ENV?RONMENTAL



### Data Reprocessed On 02/29/1996 08:31:21 ; Sample Name: R2 CUMP KILN INLET 50X Date: 02!2'8/1996 15:59:38 ; ; Data File : C: \DX\DATA\ANIC)NS'\96-30\':

~ *-27()041.DO' ; 

### ; Method : C:\DX\METHOD\AS10.MET ; ACI Address: 1 Svstem: 1 Inject#t: Detector:CI7M-

~ - ; 

### ; Analyst . Column: AS10 .4mm, AG10 Vaurd Column ; ----------------------------------------------------------------------------- Calibration Volume Dilution F'oints
-------------------------------------------------------------------- Rate Start Stop Area Reject External 1 1 7500 5Hz 0.00 25.00 4000 Component Report: Components Found F{et Component Area Height Concentration Time Name
------------------------------------------------------------- ppm 4.63 Fluoride 92205429 9790170
------------------------------------ 1.497 Totals 92205429 9790170 1.497 

## ~ .... i



### File: 2-270041.D02 Sample: R2 COMP KlLN INLET 50X

N-tinutes 100%

80%



### 60%
40%

20%

0°0

E-31 

# 1/P0 5 10 15 20

20

uS 10

02 

### METCO ENVIRONMENTAL

Data Reprocessed On 02/29/1996 08:32:30 ; Sample Name: R3 COMP KILN INLET 50X Date: 02!28/1996 16:29:08 ; ; Data File : C:\DX '\DATA\ANIONS\96-30\:. '-270041.D03 ; Method : C:\DX\METHOD\AS10.MET ~ 

### ACI Address: 1 System: 1 Inject#: Detector:CDM-2 ' Analyst
. Column: AS10 ,4mm. AG10 Gaurd Column ; Calibration Volume Dilution Points Rate Start Stop Area Reject External 1 1 -------------------------------------------------------------------- 

### 4341 5H:, 0.00 22.61 4000 

# ~

Component Report: Components Found Ret Component Area Height Concentration Time Name ppm
------------------------------------------------------------- 

### 4.63 Fluoride 77947036 8572066 1.265

------------------------------------ Totals 77947036 8572066 1.265

~ 

### Fle: 2-270041.D03 Sample: R3 COMP KILN INLET 50X

Minutes 100%

80%

60%

40%

20%

0%

E-32 / /,-$'-]

--, METCO ENVIFcONI•iENTAL 

### Data Reprocessed On 02/28/1996 16:57:12 ; Sample Name: DI BLNK Date: 02/28/1996 16:56:13 ; ; Data File : C:\DX\DATA\ANICNS\96-30\2-270041.D04 ; ; Method : C:\DX\i1ETHOD\AS10.MET ; ; ACI Address: 1 System: 1 In,ject#: 4 Detector:CDM-2 ; ; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ;

----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

### Calibration Volume Dilution Points Rate Start Stop Area Reject

- -------------------------------------------------------------------- 

### External 1 1 5928 5Hz 0.00 19.76 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm

-------------------------------------------------------------

------------------------------------ 

### 1 Totals 0 0 0.000

~ 

### Fle: 2-270041.D04 Sample: DI BLiVK

80%

60%
40% -2.0 20% -3.0 -4.0 0 2 4 6 8 10 12 14 16 18 Minutes 3.0 2.0 1.0 0.0 us -1.0 100%

0%

E-33

### METCO ENVIRONMENTAL Data Reprocessed On 02/29/1996 09:29:17 ; Sample Name: 0.5 PPM F STD Date: 02/27/1996 08:50:48 ; ; Data File : C:\.DX\DATA\ANIONS\96-30\2-270011.D01 ; ; Method : C:\DX\METHOD\AS10_MET ; ; ACI Address: 1 System: 1 Inject#: 1 Detector:CDM-2 ; ; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ; Calibration Volume Dilution Points Rate Start Stop Area Reject


### -------------------------------------------------------------------- External 1 1 3424 5Hz 0.00 27.84 4000 Component Fceport: Components Found ket Component Area Height Concentration Time Name ppm 

### ------------------------------------------------------------- 4.63 Fluoride 31579803 3407651 0.513
~ 

### ---------------------------------=-- ' Totals 31579803 3407651 0.513 

### 0 r 

## i

File: 2-270011. D01 Sample: 0.5 PPM F STD 100%

80%

60%

40%

20%

0% 14 12 10 8 6 uS 4 2 0 -2 -4 

### 0 5 10 15 20 25 Minutes

E-34100%

80%



### 60%

40%

20%



### 0% 

### File: 2-270011. D02 Sample: 1 PPM F STD

0 5 10 15 20 METCO ENVIRONMENTAL Data Reprocessed On 02/29/1996 09:30:21 ; Sample Name: 1 PF'M F STD Date: 02!27/1996 09:09:47 ; ; Data File : C:\DX\DATA ",ANIONS\96-30\

~ '-270011.D02 ; 

### ; Method : C:\DX\t •lETHUD\AS10.MET ; ; ACI Address: 1 System: 1 Inject#: 2 Detector:CDM-2 ; ; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ; ----------------------------------------------------------------------------- Calibration Volume Dilution Points Rate Start Stop Area Reject
-------------------------------------------------------------------- External 1 1 *4582 5H.; 0.00 23.86 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm ------------------------------------------------------------- 4.61 Fluoride 61266312 6993680 0.994
------------------------------------ Totals 61266312 6993680 0.994 

### n

~



### 20

10 uS



### 0

Minutes

E-3S 

# ~ 1 ( PuS 10

-i0 0 20 

### 30 Pile: 2-270001.D01 Sample: 2.5 PPM F STD

Lel

2 4 6 0 10 12 14 16 

### Minutes 100%

40% 80 ° ,~ 0

60%

20°ro

0°% 

### METCO ENVIRONMENTAL Data Reprocessed On 02/29/1996 09:24:34 ; Sample Name: 2.5 PPM F STD Date: 02/27/1996 08:33:50 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-270001.D01 ; ; Method : C:\DX\METHOD\AS10-MET ; ACI Address: 1 System:.l Inject#: 1 Detector:CDM-2 ; ; Analvst
. Column: AS10 ,4mm. AG10 Gaurd Column ; Calibration Volume

-------------------------------------------------------------------- 

### Dilution Points Rate Start Stop Area Reject External 1 1 3860 5Hz 0.00 16.08 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name ----------------------------------------=-------------------- 

### ppm 4.59 Fluoride 154627245 16083647

------------------------------------ 

### 2.510 Totals 154627245 16083647 2.510 

## — i

~

E-3b

# ~ 

# n

~

~ 

### ^ METCO ENVIRONMENTAL r~ --: 

### Data Reprocessed On 02/29/1996 09:40:28
----------------------------------------------------------------------------- --------------------------------------------------

~ 

### --------------------------- 

### Sample Name: 5 PPM F STD Date: 02/27/1996 09:22 : 

### 37 , ; Data File : C:\DX\DATA\ANIONS\96-30\2-270011.D03 ; ; Method : C:\DX\METHOD\AS10.MET ; ACI Address: 1 System: 1 Inject#: 3 Detector:CDM-2 ; ; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; -----------------------------------------------------------------------------

~ 

### Calibration Volume Dilution Points Rate Start Stop Area Reject
-------------------------------------------------------------------- 

### _ External 1 1 2804 5Hz 0.00 28.52 4000 Component Report: Components Found y Ret Component Area Height Concentration p}; Time Name ppm 

### ------------------------------------------------------------- 

### 4.55 Fluoride 312887144 23888614 5.078
- --------------------------------- - Totals 312887144 23888614 5_078



### Fle: 2-270011.D03 Sampie: 5 PPM F STD 50
40
30

~ :.

~ 20

uS 10
0
-10 0 5 10 15 20 25 Minutes 100%



### 80%

60%

40%

20°l0

0 ° fo

t 

# ~1~ E-37

### 0 5 10 15 20 25 METCO ENVIRONMENTAL Data Reprocessed On 02/29/1996 09:44:24 ; Sample Name: 10 PPM F STD Date: 02/27/1996 09:51:52 ; ' Data File : C:\DX\DATA\ANIONS\96-30\2-270011.D04 ; Method : C:\DX\METHOD\AS10.MET ; ; ACI Address: 1 System: 1 Inject#: 4 Detector:CDM-2 ; ; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ; Calibration Volume Dilution Points Rate Start Stop Area Reject External 1 ----------------------------_---------------------------------------- 

### 1 7587 5Hz 0.00 25.29 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name
----------------------------------------------=-------------- 

### ppm 4.55 Fluoride 620860998 44789113 10.077 Totals 620860998 44789113 10.077



### ~ File: 2-270011.D04 Sampie: 10 PPM F STD

100


### 80 

## eo
uS 40 20
0

Minutes 

# n

100%

80%

60%

40°b

20%

0%

E-38 

# ~r ~100%

80%

60°l0

40%

20%


### O% 120 100 80 60 uS 40 20 0 

### File: 2-270011.D05 Sample: 15 PPM F STD METCO ENVIRONMENTAL Data Reprocessed On 02/29/1996 09:46:19 ; Sample Name: 15 PPM F STD Date: 02/27/1996 10:23:11 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-270011.I }05 ; ; Method : C:\DX\METHOD\AS10.MET ; ; ACI Address: 1 System: 1 Inject#: 5 Detector:CDM-2 ; ; Analyst
. Column: AS10 .4mm, AG10 Gaurd Column ; ----------------------------------------------------------------------------- Calibration Volume Dilution Points Rate Start Stop Area Reject'
-------------------------------------------------------------------- External 1 1 8399 5Hz 0.00 28.00 4000 Comporritt Report: Components Found Ret Component Area Height Concentration Time Name ppm ----------------------------------------------=-------------- 4.56 Fluoride 915268612 68981260 14.856

~ 

### ------------------------------------

~ 

### Totals 915268612 68981260 14.856 

# q

0 5 10 15 20 25 Minutes

E-39 

# /9

### Fle: 2-270011.D06 Sample: 20 PPM F STD 100%

80% 

### 120 100 80 60 uS 40 20 0 60%

40%

20%

0% 

### 0 t1ETC0 Et•]VIRONMENTAL Data Reprocessed On 02/29/1996 09:48:53 ; Sample Name: 20 PPM F STD Date: 02/27/1996 11:03:59 ; ; Data File : C:\DX\DATA\ANIONS\96-30\2-270011.D06 ; ; Method : C:\DX\METH0D\AS10.MET ; 

### ; ACI Address: 1 System: 1 Inject#: 6 Detector:CDM-2 ; ; Analyst . Column:

----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

### AS10 ,4mm, AG10 Gaurd Column ; Calibration Volume Dilution Points -----------------------=-------------------------------------------- Rate Start Stop Area Reject External 1 1 11375 5Hz 0.00 37.92 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name
------------------------------------------------------------- ppm 4.56 Fluoride 1229176911 83261058
------------------------------------ 19.951 Totals 1229176911 83261058 19.951 

### ri

0 5 10 15 20 25 30 35 Minutes

E-40 

# 4/

### File: 2-280001.D03 Sample: CCV 20 PPM F STD

140 100%

80%

60%

40% ✓ 20%

0% 120 100 80 uS 60 40 20 0 -20 METCO ENITIRONMENTAL

Data Reprocessed On 02!29!1996 09:50:24 

### ; Sample Name: CCV 20 PPM F STD Date: 02! 2 8i1996 09:46:29 ' Data File : C:\DX\DATA\ANIONS\96-30\2 '-2S0001.D03 ; Method : C:\DX\METHOD\AS10.MET ; ACI Address: 1 System: 1 Inject#: 3 Detector:CDM-2 ; ; Analyst
. Column: AS10 ,4mm, AG10 Gaurd Column ; Calibration Volume
-------------------------------------------------------------------- Dilution Points Rate Start Stop Area Reject

, External 1 1 6924 5Hz 0.00 28.85 4000 Component Report: Components Found Ret Component Area Height Concentration Time Name
------------------------------------------------------------- ppm 4.56 Fluoride

~ 

### 1240303639 83011754 20.131

~ 

### Totals 1240303639 ------------------------------------

83011754 20.131 

## I 

# n ..J



### 0 5 10 15 20 25 Minutes

E-41 

# )a9-

# m; 

# ~ m --I Bw

APPENDIX F
Reference Method Monitor Data

96-30 F-1 

### 0-
~ ) -~~ 

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### ~ 

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# ax : o' J °O PP`Y'

96 030 MRF:L PF:ICKS 

### 1

~ F{ENDEfiSON TEXAS 

### S1N 105 ~ ~ 

### tqy a9 

### • a8 ~ KILN SCRUABER STACK Page



## ~ raoX 

## ,1, m ~. - ~ 

## ;a., j r 

### r o~ 

## Ch«j ~ 

### Q ~ C~ 

## ~ FF,4 02/15/96 07:12 -0.1C 02/15/96 02/I5/96 07:13

07:14 O.00

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### 9(,° 16 1113 A LG 02/i5/96 07:15 O.00 02/15/96 07:16 44.8C

~ 02/15/96 07:17 57.3C

. i 02/15/96 07:18 77.9C 02/15/96 07:19 86.1C 02/15/96 07:20 86.6C 02/15/96 02/15/96 07:21

07:22 86 .Ar.

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•_ 1 •ifr.15 (~b G~f ~~ ~ I}~ 1 S81 ' 02/15/96 07:31 46.1C PPn► I 02/15/96 07:32 : 46.IC

02/15/96 07:33 25.3C 02/15/96 07:34 11.5C

~ 02/15496 07:35 18.2C

02/15/96 07:36 18.7C 02/ 15/96 07:37 1q - 7 r ,~ aMO 

### 4 0 839 C~ ` L 02/15/96 07: 38 i s ~ 7C J a,' ~~ QP m ~ 02/ 15/96 07:39 18.7C 02/1,/.96 07: 40 10. iC 02/W96 07:41 0.2C 02/15/96 07:42 O.IC 02/15/96 07:44 26.2C 02/15/96 07:45 26.2C 0.2/15/96 07:46 26.2C 02/15/96 07:47 26.2C 02/15/96 07:48 26.2C 02/15/96 07:49 26.2C 02/15/96 07:50 26.2C 02/15/96 07:51 26.2C 02/15/96 07:52 26.2C 02/15/96 07:53 26.2C 02/15/96 07:54. 26.2C 02%15/96 07:55 26.2C 02%15/96 07:56 26.2C

# ~ ' 96 0

~ 0

FORAL PRICfCS HENDERSON TEXAS KILN SCRUBfiER STACK i'age . 2 

## Nox FFM 02/15/96 07:57 26.2C 02/15/96 07:58 26.1C 02/15/96 07:59 26.1C 02/15/96 08:00 26.IC 02/15/96 08:01 26.1C 02/15/96 08:02 26.1C 02/15/96 08:03 26.1C 02/15/96 08:04 26.IC 02/15/96 08:05 26.1C 02/15/96 08:06 26.1C 02/15/96 08:07 26.IC 02/15/96 08:08 26.1C 02/15/96 08:09 26.IC 02/15/96 •08:10 26.1C 02/15/96 08:11 26.IC 02/15/96 08:12 26.1C 02/15/96 08:13 26.IC 

### 02/15/96 ' 08:14 26.00 /f/Ct eD~l~' Ce02/15/96 08:15 26.00 02/15/96 08:16 22.6C 02/15/96 08:17 0.5C 02/15/96 08:18 .0.8C 02%15/96 08:19, 0.6C 

### 02/15/96 -- 08:20 0.5C Z er0 N7 02/15/96 08:21 0.5C 02/15/96 08:22 20.3C 02/15/96 08:23 43.2C 02/15/96 08:24 44.1C 02/15/96 08:25 44.IC 

### 02/15/96 08:26 144.1C y(o.s$ NC) 8/1-Wele , 02115/96 08:27 44.1C 02/15/96 08:28 26.2C 02115/96 08:29 1.7C 02/15/96 08:30 2.2C 02/15/96 08:31 0.8C 02/15/96 08:32 0.3C 02/15/96= 08:33 6.2C 02115/96 08:34 22.1C 02/15/96 08:35 23.1C
AVERAGES : 29.4 , 

### Bicas Gl.eok



### • . `\

~~ 

### . ., ' - .. F_

~ 

### 5~ ,

-a

~ Auxiliary Average Report

DCNID : 07 Site Name : KILN STK Aux Interval : 1 Date : 2/15/96

-------- --- ---------------------------------------------------- NOX Time F'F'M # 

# ~ -----------------------------------------------------------------------k-(I-a ----------------- 08:52 23.2000 08:53 22.9000 08:54 22.9000 08:55 23.1000 08:56 22.9000 08:57 22.6000 08:58 22.7000 08:59 22.8000 09:00 23.0000 09:01 23.1000 09:02 22.8000 09:03 22.8000 09:04 22.9000 09:05 23.0000 09:06 23.1000 09:07 23.1000 09:08 23.1000 09:09 23.1000 09:10 23.1000 09:11 23.1000 09:12 23.1000 09:13 23.0000 09:14 23.1000 09:15= .23.0000 09:16 22.4000 09:17 21.9000 09:18 21.8000 09:19 22.4000 09:20 22.7000 09:21 22.8000 09:22 22.9000 09:23 23.1000 09:24 23.2000 09:25 23.2000 - 09:26 23.1000 09:27 23.0000 09:28 23.2000 09:29 23.1000 09:30 23.0000 09:31 22.8000 09:32 22.9000 09:33 23.1000 09:34 23.2000 09:35 23.2000 09:36 23.1000 09:37 22.9000 09:38.. 23.0000 09:39 ... 23.0000 ~ 09:40..:. ° = 23.2000. 09:41 '' =23.1000 ` 09e.42: .. ~ ..22:9000 ; _ 09:43 • 22:9000 F=6 I ~(~~

..1 09:46 23.1000

09:47 23.1000 09:48 23.2000 09:49 23.2000 09:50 23.2000 09:51 22.7000 09:52 22.0000 09:53 21.7000 09:54 22.4000 09:55 22.6000 09:56 22.8000 09:57 23.0000 09:58 23.2000 09:59 23.1000 10:00 23.2000 10:01 23.2000 10:02 23.2000 10:03 23.3000 10:04 23.4000 10:05 23.2000 MAX . 23.4000 MIN

. 21.7000 AUG . 22.9392 SCANS: 74



## R

### iURAL PRICKS ec

;!;EN' Ll-ERcNN TUA;



## Wax

'02/15/96 it) .1 .3r C.I. Ar 2 15 6 1 0 1 4 Z-t c 6 0 2 15 , - 9 10: 15 5C 02/15/96 10: 16 :1. . 2C

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' 96 030 E+ORAL PRICKS HENDERSON TEXAS i KILN SCRUBBER STACK Page : 1 

## 91 0.s 

# Qun 3

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AVERAGES 0.5C 0.5C 0.4C O.ar o.5c N, 1.0C 8.4C 39.0C 44.IC 44.5C ~~ 44.7C y ~



### ~•~s ~ 44.7C

19.1



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APPENDIX G 

# U Chain of 

## Custody

96-30 G-1 

# --I

# n

_ - 

# r, : .

i 1 

# E?IMEM0.

CHAIN OF CUSTODY

Job # 96 ~ 3O Date Client 432: 2 0W Method 5 ~ 13e Location y~-~~ °

s~
- ~ Project Mgr. Unit
Number of Absorb. Initial

Containers Solution Volume p ~ , 3D2 S

,Q, Other Anatyses Filter Cont. ~~ X' Q ( JAZ r Z ~ ~F Front Wash Back Wash -1// ~r '~'~ 

### ' -'E ✓ f/F Impinger 1 Impinger 2 Impinger 3 Impinger 4 

### Sil. 6Q. Impinger 5 Blank 1 ~ ~• _ Bfank 2 NO x Other Special Instructions:

Run # ~ Recov. by • / ~ "// ~ Date Time 

### 11- 30 Location a 1 7 Run # 

### Z Recov. by i Date Z/S 6 Time/2-5 29 Location Run #

- ~ Recov. by r~ . / Date Z/j 96 Time 1 

### y 30 Location 1 , 4

4 let) I'F Run # Recov. by A Date Time Location Samples Rcvd. by 4;i l or transport. 4 TIme Time / ~~ d Sample Rcvd. at lab Date Sample Analyzed by — Date Time 

### D 9/s Sample Analyzed by 

### ~~ Date a 

### ~ Time 

### ~ Data Checked by .G , I DatejT--T-(Z Time G-2 /iS

~ 7Run # ~ Recov. by

Run # 

### 2 Recov. by Run #

- 3 Recov. by Run # Recov. by Date Tme 113 4
" ) Location /A*/- -, O Date Time 

### 12 S 0 Location /4~~e Date Z 5 9 lime /y

30 Location 15

4 1 0 -ka l; z ' Date Time Location



# mErco

CHAIN OF CUSTODY

r Job # 

### ~ 6 ' 3 

## o Date Client Method

~ 3 8 Location 7 7 ' Project Mgr. e4. Unit
~ f%

~ , ~ / 5'1.e

~ 3BE• ~ i•t/C ET 

## FA Number of Absorb. Initial Qonners Solution yolume pML SQz 2% Other Analvses Fifter Cont. Front Wash Back Was b•s e

~~ /SE Impinger 1

_ <., Impinger 2 

### D y •
~~ 

### 'f Impinger 3 D -Z• Za

~ "` ~ Impinger 4 Impinger 5 <5'/L• G ~ Blank 1

~ Blank 2 NO x Other r'- ,. . Special Instructions: 

# ~

Fli

Samples Rcvd. by ~ For transport. Date ~~ '' ~ 96 Time Sample Rcvd. at I by ate me Sample Analyzed by 

# ~ Date a a Q(i Time 

## ~ Sample Analyzed by Date Tme Data Checked by ~

`~~ Date Zl G Time b S G-3

# ~ MEFCO 004. EmpccfnEmAL

r;

APPENDIX H
Resumes of Test Personnel

96-30 H-1 /~~~

## 11 

# ~ CO."10-.

BILLY J. MULLINS, JR., President


### Education Post Graduate Study Environmental Engineering at

Southern Methodist University, Dallas, Texas 1970. M.S. 1969, New York University, New York, New York, in Civil Engineering (Air Resources). B.S. 1968, Texas Tech University, Lubbock, Texas, in Civil Engineering (Water Resources). Studies in Engineering at U.S. 

### Naval Academy, Annapolis, Maryland, 1963-1964.
Professional 

### Attended Short Course on Air Pollution Engineering at 

### Trainin

- 

### q the University of Texas at Austin, February 1970. Courses 

### Attended four-week management course presented by the



### American Management Association, 1976.
Certification 

### Registered Professional Engineer

Certified Visible Emissions Evaluator Certified Fallout Shelter Analyst Licensed Private Pilot (Multi-Engine-Land, Instrument) 

### Diplomat in the American Academy of Environmental Engineers Inductee into the Stack Sampling Hall of Fame
Professional Air & Waste Management Association - Past Chairman, Past Vice MembershiQs Chairman and Past Board of Directors

Southwest Section: Past Chairman, Consultants Committee; Past Chairman, Source Measurement Committee 

### Source Evaluation Society - Past President, Past Board of Directors American Management Association

H-2 

### l,`~G~

### ~ 

# m

MULLINS
Publications 

### Co-authored "Sulfur Compound Emissions of the

Petroleum Production Industry," December 1974. Co-authored "Field Procedure for Stabilizing Hydrogen Sulfide Samples to be Analyzed Using Modified Methylene Blue Technique," presented at the Conference on Ambient Air Quality Measurements, Austin, Texas, March 1975. Co-authored "Atmospheric Emissions Survey of the Sour Gas Industry," October 1975. Co-authored "Technique for Insuring the Validity of Samples for High Concentrations of Sulfur Dioxide Using the EPA Method 5 Sampling Train," presented at the Third National Conference on Energy and the 

## N Environment, College Comer, Ohio, September 1975. 

### Teaching Served as a lecturer in the Environmental Protection Experience 

### Agency's training course number 450, "Source Sampling



### for Particulate Pollutants," for two years from January 1974 to October 1975 and in March, 1992. Conducted a two-day training course entitled "Technical Assistance in Source Sampling" at lowa State University, Ames, lowa, for the Environmental Protection Agency,. October 1974. Conducted EPA's training course number 450, "Source 

### Sampling for Particulate Pollutants," for the EPA at Research Triangle Park, North Carolina, September 1975.

H-3 

### l

~ 

### 'l

### MULLINS

Teaching 

### Conducted a two-day short course entitled "Performing 

### Exgerience and Observing Source Sampling° at Dallas, Texas,

July 1976, May 1977, October 1977, November 1987 a 

### 1988; at Lake Charles, Louisiana, May 1977; at Caspei May 1977; and at Point Comfort, Texas, November 19 1 , Served as a lecturer in the Environmental Protection Agency's two-day seminar entitled 'Asphalt Industry 

### Environmental Solutions,' presented in Dallas, Texas, c March 21 and 22, 1979. Conducted a two-day short course entitled "Performing and Observing Source Sampling" in Phoenix, Arizona ii 1990 for the State of Arizona, Department of Environm

~ 

### in Lincoln, Nebraska, in March 1980 for the State of NE Quality Control Division. 

### Technical Directed and performed stack sampling on over Exaerience 

### 2000 sources of which over 500 were sampled simultar



### using more than one sampling train at several points in the flue gas stream: 1972-present. Directed and performed over 200 short-term ambient air 

### studies using mobile sampling vans and various ambient air sampling equipment. 1972-present. Designed, directed and operated over 20 permanent 

### ambient air networks of various size and duration for a variety of parameters. 1972-present. 

### Designed surface and underground drainage systems f residential subdivisions, public works projects, and shoppirig centers. 1969-1972. Designed several residential subdivisions including lot 

### layout, street design, drainage design, and utility desig 1969-1972. 

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### MULLINS


### Research Supervised and conducted a study made by the Hawaiian Proiects Sugar Planters' Association to characterize the emissions

for several bagasse-fired boilers. April-May 1976. Supervised and conducted a study made by the Rio 

### Grande Valley Sugar Growers, Inc. to determine the area affected by the burning of sugarcane fields prior to harvesting. November 1974-April 1975. Supervised and conducted a study by a lightweight 

### aggregate manufacturer to develop a material balance around the process through sampling and analysis of several parameters. November 1973. Conducted a study in New York City to attempt to 

### develop a correlation in the ambient air between carbon dioxide and sulfur dioxide to provide a tool for predicting air pollution episodes. January-May 1969. 

### Related Served as Chairman of the Engineering Foundation Conference on Proiects Stack Sampting and Source Evaluation in Santa Barbara, California,

1985. 

### Served as Session Chairman at the Engineering Foundation Conference on Stack Sampling and Source Evaluation in Hershey, Pennsylvania, 1984; in San Diego, California, 1993; and in Palm Coast, Florida, 1994. '1

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GORDON G. SMITH, Project Supervisor II


### Education B.S. 1988, University of Massachusetts, Amherst, Massachusetts, in

Environmental Design. A.S. 1986, Stockbridge School of Agriculture, Amherst, 

### Massachusetts, in Landscape Operations.
Professional Attended 40-hour Occupational and Environmental Training Program Training on Hazardous Materials (CFR 1910.120) Dallas, Texas, April 1992. Courses 

### Also attended an 8-hour refresher course, February 1995.
Certification 

### Certified Visible Emissions Evaluator '


### Technical Participated in the sampling of over 500 sources, including several of _ExQerience which were sampled simultaneously using more than. one sampling

train; and has supervised the sampling of over 250 sources, including three trial burns. 1992-present. 

### Experienced in the analysis of commercial calibration gas cylinders for CO 2 , 0 2 , NO X , S0 2 , CO, and H 2 S. . Experienced with Modified Method 5 Sampling Train (Method 0010). Experienced with VOST sampling procedure (Method 0030). 

### Experienced with calibration techniques for all field testing equipment. 

### Experienced with various multiple metal and acid gas sampling trains. Has performed on-site S0 2 analysis and H 2 S fuel gas analysis. ij

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JAMES M. GRUBBS, Environmental Technician II
Education Preventive Medical Specialist 1993, U.S. Army, Womack Army

Medical Center, R. Bragg, NC.
Professional Attended 8-hour Safe Hazardous Materials Transportation Training TraininQ Program (HM-126F and HM-181) Dallas, Texas, October 1994. Courses Attended Bill Mullins' Performing and Observing Source Sampling

Short Course; Dallas, Texas, January 1995.
Technical Participated in the sampling of over 50 sources, including Experience several of which were sampled simultaneously using more than

one sampling train. Thoroughly trained in all EPA testing procedures. 1993-present. Experienced with calibration techniques for all field testing equipment. Thoroughly trained in the operation and routine maintenance of the following: Anarad AR880 Oxides of Nitrogen Analyzer Anarad AR23 Oxygen Analyzer Anarad AR30C2 Sulfur Dioxide Analyzer Anarad AR50-0 Carbon Dioxide Analyzer

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### JEFFERY R. BRUNSON, Environmental Technician I



### Education B.S. 1995, Angelo State Unitversity, San Angelo, Texas, in Biology.
Technical Participated in the sampling of over 25 sources, including Exaerience several of which were sampled simultaneously using more than

one sampling train. Thoroughly trained in all EPA testing procedures. 1995-present.



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JEFFREY D. CROCKER, Environmental Technician I
Education 

### B.S. 1994, Stephen F. Austin University, Nacogdoches, Texas, in

Biology.
Technical 

### Participated in the sampling of over 25 sources, including several of Experience 

### which were sampled simultaneously using more than one sampling

train. Thoroughly trained in all EPA testing procedures. 1994-present.

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