.~ 

~c~ian 4, Re~ 35 

Emission Factor Develop for Stack Testinct of Scrubber Stack at Boral Bricks, Henderson Plant in F'ebruarv, 1996 

by METCO ~ 

Kiln 1 

Schedule: 42 cars/day 

P~ 2 

2,916 brick/car 

Brick Weight: 4.10 Ib/fired brick (verified by quality control reports) 

= 42 saF 2,916 brisk 4.1 Ib I day I ton 

day ~ saF brisk 1 24 hr 1 2000 Ib 

= 10.46 ton/hr 

Kiln 2 

Schedule: 42 cars/day 

2,955 brick/car 

Brick Weight: 4.10 Ib/fired brick (verified by quality control reports) 

Emission Factor DevelopmeM- _ 1 _ O 

r; ,j j 19 

Total 

= 42 eaF 2,955 bask 4.1 Ib I day I ton 

day saf brisk 1 24 hr 1 2000 Ib 

= 10.60 ton/hr 

= 21.06 ton/hr 

Emission Factor Develoament: 

filterrable PM = [ Average Emission Rate (Ib PM / hr) ] 

[ Kiln Throughput (ton / hr) ] 

= 10.19 Ib 1:w 

kf 21.06 ton 

filterable PM = 0.48 Ib/ton 

Emission Factor Summary: 

Pollutant Avg. Emission Rate Avg. Emission Factor 

PM 10.19 Ib/hr 0.48 Ib/ton 

NO,, 7.2 Ib/hr 0.34 Ib/ton 

HF(inlet) 14.501b/hr 0.691b/ton 

HF 0.95 Ib/hr 0.045 Ib/ton 

Notes: 
T Fi

MET: EnURonnTdTAC o 

P.O. Box 598 

~ Addison. TX 75001 

(214) 931-7127 

SOURCE EMISSIONS SURVEY 

OF 

BORAL BRICKS, INC. 

ABSORBER STACK (EPN-K) AND 

ABSORBER INLET DUCT 

HENDERSON, TEXAS 

FEBRUARY 1996 

FILE NUMBER 96-30 

6 
~ 

FMEEO 

- Ermi~~~ 

TABLE OF CONTENTS 

PAGE 

1 

2 

6 

8 

11 

15 

16 

INTRODUCTION 

SUMMARY OF RESULTS 

DISCUSSION OF RESULTS 

DESCRIPTION OF SAMPLING LOCATIONS 

SAMPLING AND ANALYTICAL PROCEDURES 

DESCRIPTION OF TESTS 

APPENDICES 

A. Location of Sampling Points 

B. Source Emissions Calculations 

C. Calibration Data 

D. Field Testing Data 

E. Analytical Data 

F. Reference Method Monitor Data 

G. Chain of Custody 

H. Resumes of Test Personnel 

96-30 
~ 

, 

~ 

~ 

Vo 

~ 

SOURCE EMISSIONS SURVEY 

BORAL BRICKS, INC. 

ABSORBER STACK (EPN-K) AND 

ABSORBER INLET DUCT 

HENDERSON,TEXAS 

FILE NUMBER 96-30 

INTRODUCTION 

METCO Environmental, Dallas, Texas, conducted a source emissions survey of Borat 

Bricks, Inc., (ocated in Henderson, Texas, on February 14 and 15, 1996. The purpose 

of these tests was to determine the concentrations of particulate matter, hydrogen 

fluoride, and oxides of nitrogen being emitted to the atmosphere via the Absorber Stack 

(EPN-K). The concentrations of hydrogen fluoride were also determined at the 

Absorber Inlet Duct. 

The sampling followed the procedures set forth in the Appendix to the Code of Federal 

Regulations, Title 40, Chapter I, Part 60, Methods 1, 2, 313, 4, 5, 7E, and 1313; and in 

the "Sampling Procedures Manual, Texas Air Control Board, Revised July 1985." 

96-30 
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96-30 -2- ~ 
ri MErco 

SUMMARY OF RESULTS 

Absorber Stack (EPN-K) 

' 29.92 "Hg, 68°F (760 mm Hg, 20°C) 

96-30 -3- / 

~ 

Run Number 1 2 3 

Date 02115/96 02115/96 0?J15/96 

Time 0851-1005 1053-1207 1246-1400 

Stack Flow Rate - ACFM 74 , 664 78 770 76 460 

Stack Flow Rate - DSCFM' 40 , 417 42 , 890 41 , 675 

% Water Va r-% Vol. 7.07 6.18 5.92 

% CO -% Vol. 22 2.3 2.3 

% -%Vol. 16.4 16.6 16.5 

9~° Excess Air 0 Sam lin Point 317 339 329 

Stadc Tem erature -°F 436 440 441 

Stack Pressure -'H 29.47 29.49 29.47 

Percent Isokinetic 101.7 98.4 99.2 

Volume D Gas Sam led - DSCF' ry 39.123 40.159 39.339 

Particulate Matter Emissions 

Probe & Filter Catch 

rains/dscf* 0.0252 0.0217 0.0260 

rains/cf @ Stack Conditions 0.0136 0.0118 0.0141 

Ibslhr 8.74 7.99 9.28 

Tota1 Catch 

rains/dscf' 0.0313 0.0268 0.0277 

rains/cf 0 Stack Conditions 0.0169 0.0145 0.0150 

Ibs/hr 10.83 9.85 9.88 

H dro en Fluoride - ,qg 6 , 980.4 6 , 521.7 6 , 942.9 

H dro en Fluoride Emissions - m 7.6 6.9 7.5 

H dro en Fluoride Emissions - Ibs/hr 0.95 0.92 0.97 
MeK:O.- 

SUMMARY OF RESULTS 

96-30 -4- ~ 

Run Number 

Absorber Stack (EPN-K) 

1 2 3 

Oxides of Nitro en Emissions - m 23.6 24.2 24.8 

Oxides of Nitro en Emissions - Ibs/hr 6.83 7.44 7.40 jl 
~ MElR,'.--O- r::rmAjtr6FP~ 

SUMMARY OF RESULTS 

Absorber Inlet Duct 

Run Number 1 2 3 

Date 02/15/96 02/15/96 02/15/96 

Time 0851-1003 1053-1205 1246-1358 

% Water Va or -% Vol. 6.21 6.48 6.29 

Volume Dry Gas Sam led - DSCF* 27.923 28.043 28.142 

H dro en Fluoride - mg 82.044 70.517 68.976 

H dro en Fluoride Concentrations - ppm 124.6 106.7 104.0 

H dro en Fluoride Concentrations -Ibs/hr** 1 15.71 1 14.27 13.51 

* 29.92'Hg, 68°F (760 mm Hg, 20°C) 

*" Calculated using the flow rate measured during the corresponding tests on the 

Absorber Stack (EPN-tq. 

96-30 -5- 

/ 
rl pk:zellm~o 

-7-1 

DISCUSSION OF RESULTS 

Bbsorber Stack (EPN-K) 

The three tests for particulate matter, hydrogen fluoride, and oxides of nitrogen 

appeared to be valid representations of the actual emissions during the tests. AII leak 

checks performed on the sampling train, the pitot tubes, and the monitor sampling 

system showed no leaks before or after each test. The zero and calibration drift tests 

of the monitor were stable with no variations greater than 3.0 percent. The calibration 

error check, sampling system bias check, and NO2 to NO conversion efficiency check 

performed on the reference method monitor prior to testing were valid. The indicative 

parameters calculated from the field data were in close agreement. The moisture 

percentages for the three tests were within 10.6 percent of the mean value. The 

measured flow rates (QS) for the tests were within 3.0 percent of the mean value. The 

rates of sampling for the three tests were within the spec'rfied limits (90 to 110 percent 

isokinetic). The greatest deviation from 100 percent isokinetic was 1.7 percent. 

The calculated emissions (pounds per hour) of particulate matter for the three tests 

showed a range of -3.3 percent to +6.3 percent variation from the mean value. 

The calculated emissions (pounds per hour) of hydrogen fluoride for the three tests 

showed a range of -2.8 percent to +2.5 percent variation from the mean value. 

The calculated emissions (pounds per hour) of oxides of nitrogen for the three tests 

showed a range of -5.4 percent to +3.0 percent variation from the mean value. 

96-30 -6- 
~ M~ ETO

Absorber Inlet Duct 

The three tests for hydrogen fluoride appeared to be valid representations of the actual 

concentrations during the tests. AII leak checks performed on the sampling train 

showed no leaks before or after each test. The indicative parameters calculated from 

the field data were in close agreement. The moisture percentages for the three tests 

were within 2.4 percent of the mean value. 

The calculated concentrations (pounds per hour) of hydrogen fluoride for the three tests 

showed a range of -6.8 percent to +8.4 percent variation from the mean value. 

96-30 -7- ~ 
~ Elm~rco 

DESCRIPTION OF SAMPLING LOCATIONS 

The sampling location on the Absorber Stack (EPN-K) is 90 feet 6 inches above the 

ground. The sampling ports are located 40 feet (6.73 stack diameters) downstream 

from a constriction in the stack and 6 feet 5 1/2 inches (1.09 stack diameters) upstream 

from the outlet of the stack. 

The sampling location on the Absorber Inlet Duct is approximately 30 feet above the 

ground. The sampling port is located in a transition zone of the inlet duct: 

b 

96-30 -8 I 
~ METCOOPC 
MF-TCO 

SAMPLING LOCATION 

Absorber Inlet Duct 

0 0 

0 C9 

Not to Scale 

96-30 -10- ~ 
, MEMO. 

SAMPLING AND ANALYTICAL PROCEDURES 

The sampling followed the procedures set forth in the Appendix to the Code of Federal 

Regulations, Title 40, Chapter I, Part 60, Methods 1, 2, 313, 4, 5, 7E, and 1313; and in 

the °Sampling Procedures Manual, Texas Air Control Board, Revised July 1985. 0 

A preliminary velocity traverse was made at each of the two ports on the Absorber 

Stack (EPN-K), in order to.determine the uniformity and magnitude of the flow prior to _ 

testing. Several traverse points were checked for cyclonic flow and none was found to 

be present. Twelve traverse points were sampled from each of the two ports for a total 

of twenty-four traverse points. 

The sampling trains were leak-checked at the nozzle at 15 inches of inercury vacuum 

before each test, and again after each test at the highest vacuum reading recorded 

during the test. This was done to predetermine the possibility of a diluted sample. 

The pitot tube lines were checked for leaks before and after each test under both a 

vacuum and a pressure. The lines were also checked for clearance and the 

manometer was zeroed before each test. 

An integrated orsat sample was collected and analyzed according to EPA Method 3B 

during each test on the stack. 

96-30 -11- ~~ 
MEFCO EnkA~ 

particulate Matter and Hydroaen Fluoride 

Triplicate samples for particulate matter and hydrogen fluoride were collected on the 

stack. The samples were taken according to EPA Methods 1, 2, 3B, 4, 5, and 13B; and 

the "Sampling Procedures Manual, Texas Air Control Board, Revised July 1985." For 

each run, samples of three-minute duration were taken isokinetically at each of the 

twenty-four traverse points for a total sampling time of 72 minutes. Reagent blanks 

were submitted. 

The " front-half " of the sampling train contained the following components: 

Stainless Steel Nozzle 

Heated Glass Probe @ 248°F t 25°F 

Heated Quartz Fiber Filter and Teflon Support @ 248°F t 25°F 

The " back-half " of the sampling train contained the following components: 

Impinger 

Number Contents Amoljpf Parameter Collected 

1 HPLC Water 100 ml Particulate Matter and 

Hydrogen Fluoride 

2 HPLC Water 100 ml Particulate Matter and 

Hydrogen Fluoride 

3 Empty -------- Moisture 

4 Silica Gel 200 g Moisture 

Particulate matter emissions were calculated from gravimetric analysis using both the 

" front-half ° and " back-half ° collections of the sampling train. 

The hydrogen fluoride samples were analyzed by ion chromatography. 

96-30 -12- / 

~ 

71; 
ri MEFCO 

Hvdroaen Fluoride 

Triplicate samples for hydrogen.fluoride were collected on the inlet duct. The samples 

were taken according to EPA Methods 4 and 13B; and the `Sampling Procedures 

Manual, Texas Air Control Board, Revised July 1985." For each run, samples of 

twenty-four minute duration were taken isokinetically at each of the three traverse 

points for a total sampling time of 72 minutes. Data was recorded at five-minute 

intervals. Reagent blanks were submitted. 

The " front-half " of the sampling train contained the following components: 

Heated Glass Probe @ 248°F t 25°F 

Heated Glass Fiber Filter and Glass Support @ 248°F t 25°F 

The " back-half ` of the sampling train contained the following components: 

0 Impinger 

Number Contents Anfoupt Parameter Collected 

1 HPLC Water 200 ml Hydrogen Fluoride 

2 HPLC Water 200 ml Hydrogen Fluoride 

3 HPLC Water 200 ml Hydrogen Fluoride 

4 Empty -------- Moisture 

5 Silica Gel 200 g Moisture 

The hydrogen fluoride samples were analyzed by ion chromatography. 

96-30 -13- l~ 
q;- EIMER]'.0 

---i 

Qxides of Nitrooep 

The oxides of nitrogen sampling was performed according to EPA Method 7E. A 

Thermo Environmental Model 10S Oxides of Nitrogen Analyzer (Serial Number 

10S-49429-282) was used to monitor the concentrations of oxides of nitrogen during 

each run. The reference method analyzer was operated at a range of 0 to 100 parts 

per million. A multi-point calibration was perFormed on the reference method analyzer 

prior to testing. 'An analyzer calibration error check, a sampling system bias check, and 

a NO2 to NO conversion efficiency check were also conducted prior to testing. After 

each run, the zero and calibration drift of the reference method monitor was checked. 

The calibration gases were as follows: 

Zero Nitrogen 

18.7 ppm NO in N2 (ALM 40839) 

46.2 ppm NO in N2 (BAL 1881) 

85.4 ppm NO in N2 (ALM 38783) 

The reference method sampling system consisted of a heated probe, a heated glass 

fiber filter, a chilled condenser, and a teflon sample line. The calibration gases for the 

bias and drift checks were introduced upstream of the chilled condenser. 

Calibration gas certifications are included in Appendix G. 

96-30 -14- 
~ ;71~~ 

DESCRIPTION OF TESTS 

Personnel from METCO Environmental arrived at the plant at 1:45 p.m. on Wednesday, 

February 14, 1996. After meeting with plant personnel, the equipment was moved onto 

the Absorber Stack (EPN-K) and Inlet Duct. The equipment was secured for the night 

and all work was completed at 5:30 p.m. 

On Thursday, February 15, work began at 7:00 a.m. The monitor was calibrated and 

the equipment was prepared for testing. The preliminary data was collected. The first 

set of tests for particulate matter, hydrogen fluoride, and oxides of nitrogen on the 

Absorber Stack (EPN-K) began at 8:51 a.m. Testing continued until the completion of 

the third set of tests at 2:00 p.m. The first test for hydrogen fluoride on the Absorber 

Inlet Duct began at 8:51 a.m. Testing continued until the completion of the third test at 

0 1:58 p.m. 

The monitor was calibrated and secured for transport. The equipment was moved off 

of the sampling locations and loaded into the sampling van. The samples were 

recovered and transported to METCO Environmental's laboratory in Dallas, Texas, for 

analysis and evaluation. 

Operations at Boral Bricks, Inc., Absorber Stack (EPN-K) and Inlet Duct ;located in 

Henderson, Texas, were completed at 4:15 p.m. on Thursday, February 15, 1996. 

. A? 

Billy J. ullins, Jr., P.E. 

President 

96-30 -15- ~ p~ 
~ 

~ 

~. 

k 

MEMO 

APPENDICES 

A. Location of Sampling Points 

B. Source Emissions Calculations 

C. Calibration Data 

D. Field Testing Data 

E. Analytical Data 

F. Reference Method Monitor Data 

G. Chain of Custody 

H. Resumes of Test Personnel 

96-30 -16- I~ 
~ . . ~ MEMO 

~ 

APPENDIX A 

Location of Sampling Points 

Absorber Stack (EPN-K) 

The sampling ports are located 40 feet (6.73 stack diameters) downstream from a 

constriction in the stack and 6 feet 5 1/2 inches (1.09 stack diameters) upstream from 

the outlet of the stack. The locations of the sampling points were calculated as follows: 

Port and Wall Thickness = 61/4 inches 

Inside Stack Diameter = 71 3/8 inches 

Point 

Number 

Percent of Diameter 

From Wall 

Distance 

From Wall 

1 2.1 1 1/2 ° 

.2 6.7 4 13/16 ° 

3 11.8 8 7/16 ° 

4 17.7 12 5/8 ° 

5 25.0 17 7/8 ° 

6 35.6 25 7/16 ° 

7 64.4 45 15/16 ° 

8 75.0 53 1 /2 ° 

9 82.3 58 3/4 " 

10 88.2 62 15/16 " 

11 93.3 66 9/16 ° 

12 97.9 69 7/8 ° 

.s .M A-1 

~ 
~ ElfT1ET~Q 

APPENDIX A 

Location of Sampling Points 

Absorber Stack (EPN-K) 

• - 

~ ~ • 

• 

.. . • . . . • • . .. 

96-30 A-2 l 
~ MEFCO. 

ErmRoryrEMAL 

APPENDIX A 

Location of Sampling Points 

Absorber Inlet Duct 

The sampling port is located in a transition zone of the duct. The locations of the 

sampling points were calculated as follows: 

Sample points 

14' 

12' 

10' 

~ Inlets ~ 

O O 

R~ 

Angled probe to catch . 

gas stream 

~ 

Hatch with 

port 

Not to Scale 

96-30 A-3 

CA W) 
n METCOI 

APPENDIX B 

I Nomenclature and Equations 

for 

Calculation of Source Emissions 

B-1 ~ 
,7 pEKo- 1m 

NOMENCLATURE FOR CALCULATIONS 

English Metric 

S,vmbol Units units Descri tion 

A. in.2 m2 Stack Area 

Ca„ gr/dscf* g/dscm* Particulate - probe, cyclone, and filter 

Cao gr/dscf* g/dscm* Particulate - total 

gr/CF 

C~ @ stack g/m3 Particulate - probe, cyclone, and filter 

conditions 

gr/CF 

C8U C~ stack g/m3 Particulate - total 

conditions 

CaW Ibs/hr kg/hr Particulate - probe, cyclone, and filter 

C'X Ibs/hr kg/hr Particulate - total 

CP Pitot Tube Calibration Factor 

Dn in. m Sampling Nozzle Diameter 

%EA Percent Excess Air at sampling point 

g 32.174 ft/sec2 Acceleration of Gravity 

%I Percent Isokinetic 

%M Percent Moisture in the stack gas by 

volume 

Md Mole fraction of dry gas 

mf mg mg Particulate - probe, cyclone, and filter 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-2 
r, MEr ~o. 

English Metric 

Svmbol Units Units pescri tion 

Mwatef 18 Ib/Ib-mole Molecular Weight of water 

m, mg mg Particulate - total 

MW Ib/Ib-mole g/g-mole Molecular Weight of stack gas 

MWak 28.96 Ib/ Molecular Weight of air 

Ib-mole 

MWd Ib/Ib-mole g/g-mole Molecular Weight of dry stack gas 

Pb "Hg mm Hg Barometric Pressure 

Absolute 

Pm "H20 mm H20 Orifice Pressure drop 

PS "Hg 

Absoiute 

mm Hg Stack Pressure 

OP "H20 mm H20 Velocity Head of stack gas 

P,td 29.92 "Hg 760 mm Hg Standard Barometric Pressure 

Qa ACFM m3/hr Stack Gas Volume at actual stack 

conditions 

Qs DSCFM* dscm/hr* Stack Gas Volume at 29.92 "Hg, 

528 0 R, dry 

R 21.83 "Hg- Universal Gas Constant 

ft3/Ib-mole° R 

Tm ' F °C Average Gas Meter Temperature 

* 29.92 "Hg, 68 0 F (760 tnm Hg, 20°C) B-3 
-, MEI 

0 

English Metric 

Symbol lJnb unb 

T, min min 

T9 ° F °C 

T,td 528 0R 293°K 

Vm ft3 m3 

Vmstd dscf* dscm* 

Vs fpm m/sec 

VW ml ml 

Vw9", scf* scm* 

pair 0.07521bS/ft3 

pWater 1 g/m I 

pman 62.321bs/ft3 

Descri t~on 

Net time of test 

Stack Temperature 

Standard Temperature 

Volume of dry gas sampled @ meter 

conditions 

Volume of dry gas sampled @ standard 

conditions 

Stack velocity @ stack conditions 

Total water collected in impingers and 

silica gel 

Volume of water vapor collected @ 

standard conditions 

Density of Air 

Density of Water 

Density of Manometer Fluid 

Standard Conditions: 29.92 "Hg, 68°F (760 mm Hg, 20°C) 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-4 

~ 

■ 
n EIMER.-.0- 

EXAMPLE CALCULATIONS 

1. Volume of dry gas sampled at standard conditions.* 

Fb+ Pm 

Vmsb= Vm TSw 13.6 I T,,, + 460 Pstd 

f,b+Pm 

Vm = 1765 . Vm 13.6 = dscf std Tm+ 460 

Vmstd = dscf x 0.028317 = dscm 

f'i 2. Volume of water vapor collected at standard conditions.* 

_ ( Vw - gms S02- gms H2S) p,~t~ R Tstd 

Vwyas 

P M 453.6 std water 

Vwgas = 0.0472 (Vw - gms S02 - gms H2S) = scf 

Vwg. = scf x 0.028317 = scm 

3. Percent moisture in stack gas. 

%M = Vw9W x 100 = % 

Vmstd + Vwgas 

* 29.92 °Hg, 68°F (760 mm Hg, 20°C) B-5 

o~ 7 
El~~ 

4. _:= Mole fraction of dry gas. 

_ 100 - %M 

Md 100 

5. Average molecular weight of dry stack gas. 

MW 10/0COx 44 +%Ox 32 +%N xd28 +%CDx 28 Ibllb-mole 

d2 100 2 100 2 100 

= g/g-mole 

6. Molecular weight of stack gas. 

MW = MWdx Md+ 18 (1 - M~ = Ibllb-mole = glg-mole 

7. Percent excess air at sampling point. 

_ 100 (%02- 0.5% CO) 

%~ 0.265 (%N2) - ((%02) + 0.5 (%CO)] 

8. Stack Pressure. 

Stack Pressure °H O 

Ps= Pb+ 2 =° Hg Absolute 

13.6 

Ps = °HgAbs. x25.4+mm Hg 

* 29.92 °Hg, 68°F (760 mm Hg, 20°C) B-6 ~~ 
~ MMETCO. EffrM 

9. - Stack velocity at stack conditions. 

2g'xPman xPstd xMWafr x (TS +460) M2 

Vs= CP 60 

12 x palrx P. x MW x Tstd 

VA—P average = fpm 

( T + 4E0) ~2 

Vs= 5,123.8 CP PS x MW FP average = fpm 

Vs= fpm x 0.00508 = m/sec 

10. Dry stack gas volume at standard conditions.* 

1 Tsrd Ps 

QS 

__ 

144 

 V. x A. x Mdx 

TS+ 460 x Psrd 

it 

Q _ 0.123 VSx A. x Md x Ps = DSCFM 

S Ts+ 460 

Q$= DSCFM x 1.6990 = dscm/hr 

11. Actual stack gas volume at stack conditions. 

Qa= V s x AS= 

144 

ACFM 

Qa= ACFM x 1.6990 = m 3/hr 

* 29.92 "Hg, 88°F (780 mm Hg, 20°C) 8-7 a 
~ HIMET~ CO

12.:,.Percent isokinetic. 

/o

o l Vmstd x(Ts + 460) x Pstd x 100 x 144 

= 

n 

Md X Tstd x Ps X Tt X VS rrD 

4 

/o0 ! 1039 Vstd x( Ts + 460) 

_ 

Md x Ps x Tt X V. X D~ 

13. Particulate - probe, cyclone, and filter. 

_ m 1 gr 

Ca" 

r 

Vmstdx 64.8 mg 

~ Ca„ = 0.0154 x mV ' = gr/dscf' 

std 

Ca„ = grldscf x 2.290 = gldscm* 

14. Particulate total. 

Cao = 0.0154 X mt = grldscf 

std 

Cao= gr/dsCf x 2.290 = g/dscm` 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-8 

~ 
~ m ETCO_ 

15. Pasticulate - probe, cyclone, and filter at stack conditions. 

~'S (Tsrd) 

Ca~ 

_ 

C~ x ~'srd x ( TS+ 460) 

x Md 

_17.65xCa„x Ps xMd_ 

Cat Ts+ 460 9~CF 

Cat= grlCF x 2.290 = g/m 3 

16. Particulate - total, at stack conditions. 

C_ 17.65xC~ xPsxMd _ ~CF au Ts+ 460 g 

C. = grICF x 2.290 = g/m 3 

17. Particulate - probe, cyclone, and filter. 

C—C xQ x

60min x1 Ib 

a'" ~' S 1 hr 7000 gr 

Cayy = 0.00857 x C,. x Qs=!bs✓hr 

Caw= IbsJhr x 0.4536 = kglhr 

18. Particulate - total. 

Cax = 0.00857 x C. x QS= Ibs✓hr 

Ca,, = Ibs/hr x 0.4536 = kglhr 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-9 

~S / 
7 MEIeo 

EXAMPLE CALCULATIONS 

Ibs/hr = mg_ x 2.205 x 10$ Ibs/mg x DSCFM* x 60 min/hr 

Vm,,d 

Vm,,d = Volume of dry gas sampled (dscf*) 

DSCFM* = Stack Flow Rate 

ppm =~p.1g._ x 24.04 

Vm,td (m) MW 

24.04 = Ideal Gas Constant liters/g-mole 

Vm,td = Volume of dry gas sampled (m3*) 

MW = Molecular Weight 

.m.. .n. ,. -cular III - .W 

Hydrogen Fluoride 20. 01 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) 

B-10 ~~ 
n ~mETC0 

6 

EXAMPLE CALCULATIONS 

Ibs/hr = ppm x CF x 60 min/hr x DSCFM` 

CF = Conversion Factor for ppm to Ibs/scf* 

Comp9und Conversion Factor 

NOx 1.194 X 10'' 

29.92 °Hg, 68°F (760 mm Hg, 20°C) 

s-i1 J~.~ 
MuEo

~-

- ~, ~ ffm~o~ 

EXAMPLE CALCULATIONS 

Equation 6C-1 

Cr„e Cgas=(C - C) 

(im - (iO 

Where: Cg,. = Effluent gas concentration - dry basis (ppm) 

C= Average gas concentration indicated by gas ana/yzer - 

dry basis (ppm) 

Co= Average of initia/ and final system calibration bias check 

responses for the zero gas (ppm) 

Cm= Average of initial and final system calibration bias check 

responses for the upscale calibration gas (ppm) 

C,,,a= Actual concentration of the upscale calibration gas (ppm) 

R 

B-12 3-( 
r-I 

meco- ErMRonrnEnMc 

SOURCE EMISSION SURVEY 

JOB NUMBER: 96-30 

JOB NAME: BORAL BRICKS 

LOCATION: HENDERSON, TEXAS 

UNIT TESTED: ABSORBER STACK ( EPN - K) 

SOURCE EMISSION CALCULATIONS 

SYMBOL DESCRIPTION 

----------------------- -......................... 

UNITS 

--_---- ...... I ----------------4 =1 

I RUN # 

1 

1 

1 

I 

I 

---------------- I ------- 

1 I 

I 

------- -- -I ----------------- 

2 1 

I 

-I 

3 1 

I 

I DATE 

I 

1 

I 

1 

I 

02-15-96 1 

I 

02-15-96 1 

I 

02-1 5-96 1 

I 

I 

1 BEGIN 

I 

1 

I 

1 

I 

0851 1 

I 

1053 1 

I 

12461 

1 TIME 

I 

I I I I I 

I END 

I 

1 

I 

1 

I 

1005 1 

I 

12071 

I 

1400 1 

1 TIME I I I I I 

I 

I P(b) 

I 

I BAROMETRIC PRESSURE 

I 

"Hg Abs. 1 

I 

29.491 

I 

29.52 1 

I 

29.50 1 

1 

1 

1 

1 

(mm Hg) 1 

1 

(749)1 

1 

(750) I 

1 

(749)1 

1 

1 P(m) I ORIFICE PRESSURE DROP "H20 1 0.9191 0.966 1 0.9381 

1 

1 

1 

1 

(mm H20) 1 

1 

(23.3)1 

I 

(24.5)1 

I 

(23.8)1 

I 

I V(m) I VOLUME DRY GAS SAMPLED ft^3 1 40.346 1 41.5981 40.930 1 

1 

i 

1 @ METER CONDITIONS 

1 

(m^3) 1 

1 

(1.142)1 

1 

(1.178)1 

1 

(1.159)1 

1 

I T(m) I AVERAGE GAS METER DEG.F 1 781 81 1 83 1 

I 

I 

1 TEMPERATURE 

1 

(DEG.C) 1 

1 

(26)1 

1 

(27)1 

1 

(28)1 

1 

1 V(m[std])' I VOLUME DRY GAS SAMPLED DSCF 1 39.1231 40.1591 39.3391 

1 

1 1 

1® STANDARD CONDITIONS' (DSCM) 1 

1 

(1.108),I 

1 

(1.137)1 

1 

(1.114)1 

1 

1 V(w) I TOTAL WATER COLLECTED, ml 1 63.1 1 56.0 1 52.4 1 

I 1 

I I 

IMPINGERS & SILICA GEL I I I I 

I V(w[gas]) I VOLUME WATER VAPOR 

I 

SCF 1 

I 

2.978 1 

I 

2.643 1 

I 

2.473 1 

I 1 COLLECTED @ STANDARD (SCM) 1 (0.084)1 (0.075)1 (0.070)1 

I 1 CONDITIONS' I I I I 

I%M I MOISTURE IN STACK GAS % 1 7.07 1 6.181 5.92 1 

1 1 BY VOLUME I I I I 

' 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) B-13 
~ p?lm~rco 

SOURCE EMISSION CALCULATIONS 

BORAL BRICKS 

HENDERSON,TEXAS 

ABSORBER STACK ( EPN - K ) 

SYMBOL DESCRIPTION UNITS 

----------------4 ------------------------------------------------------- - ------ --I ---- - -------------- I --------------------I --------------------I 

Md 1 MOL FRACTION OF DRY GAS 

I 

1 

I 

0.9293 1 

I 

0.9382 1 

I 

0.9408 1 

I 

CO2 

I 

I 

1 

I 

% 1 

1 

I 

2.21 

1 

I 

2.31 

1 

P 

2.3 1 

I 

02 

1 

1 

1 

1 

% 1 

1 

1 

16.41 

1 

1 

16.61 

1 

1 

16.51 

1 

CO 

1 

I 

I 

1 

% 1 

I 

1 

0.01 

I 

1 

0.01 

I 

1 

0.01 

I 

N2 

I 

I 

1 

I 

% 1 

I 

I 

81.41 

I 

I 

81.1 1 

I 

I 

81.21 

I 

%EA 1 EXCESS AIR @ SAMPLING %u 1 317.21 339.4 1 328.81 

1 POINT I I I I 

UWd 

I 

I MOLECULAR WEIGHT OF 

I 

LB/LB-MOLE 1 

I 

29.01 1 

I 

29.03 1 

I 

29.031 

1 DRY STACK GAS 

1 

(g/g-MOLE) 1 

1 

(29.01)1 

1 

(29.03)1 

1 

(29.03)1 

1 

VIW I MOLECULAR WEIGHT OF LB/LB-MOLE 1 28.23 1 28.351 28.381 

1 STACK GAS 

1 

(g/g-MOLE) 1 

1 

(28.23)1 

1 

(28.35)1 

I 

(28.38)1 

I 

)ELTA P I VELOCITY HEAD OF STACK 'H20 1 0.396 1 0.440 1 0.4141 

1 GAS 

1 

(mm H20) 1 

1 

(10.1)1 

1 

(11.2)1 

1 

(10.5)1 

1 

7s I STACK TEMPERATURE DEG. F 1 436 1 440 1 441 1 

1 

1 

(DEG. C) ( 

1 

(224)1 

1 

(227)1 

1 

(227)1 

1 

's I STACK PRESSURE 'Hg Abs. 1 29.47 1 29.49 1 29.47 1 

1 

1 

(mm Hg) 1 

1I 

(749) I 

1 

(749)1 

1 

(749)1 

1 

(s I STACK VELOCITY @ STACK FPM 1 2,687 1 2,835 1 2,752 1 

i CONDITIONS 

1 

(m/SEC.) 1 

1 

(13.65)1 

1 

(14.40)1 

1 

(13.98)1 

1 

s I STACK AREA (SQ.INCHES) 1 4,001 1 4,001 1 4,001 1 

I 

I 

(SQ.METERS) I 

1 

(2.58)1 

1 

(2.58)1 

1 

(2.58)1 

1 

)s I DRY STACK GAS VOLUME ® DSCFM 1 40,417 1 42,890 1 41,675 1 

1 STANDARD CONDITIONS' 

1 

(DSCM/HR) 1 

1 

(68,668)1 

1 

(72,870)1 

1 

(70,806)1 

1 

)a I ACTUAL STACK GAS VOLUME ACFM 1 74,664 1 78,770 1 76,460 1 

1 @ STACKCONDITIONS (m^3/HR) 1 (126,854)1 (133,830)1 (129,906)1 

' 68 Deg.F, 29.92'Hg (20 Deg.C, 760 mm Hg) B-14 
n 

p 

FIMET0. ErMROnnYnML 

SOURCE EMISSION CALCULATIONS 

BORAL BRICKS 

HENDERSON,TEXAS 

ABSORBER STACK ( EPN - K ) 

SYMBOL DESCRIPTION UNITS 

I ----------------4 -- ----------- I --- -- --------- -- ---- I --------------------I 

I Tt 

I 

---- ----------------------------- -- --------------- 

I NET TIME OF TEST 

I 

MINUTES 1 

I 

72 1 

I 

72 1 

i 

----------------- -I 

72 1 

I 

i 

1 Dn 

I 

I SAMPLING NOZZLE DIAM. 

I 

IN. 1 

I 

0.260 1 

I 

0.260 1 

I 

0.260 1 

I 

I 

I 

i 

(m) 1 

1 

(0.007)1 

1 

(0.007)1 

1 

(0.007)1 

1 

1%1 

1 

1 PERCENT ISOKINETIC 

I 

% 1 

I 

101.71 

I 

98.4 1 

I 

99.21 

I 

I 

I Mf 

I 

I PARTICULATE - PROBE, 

I 

mg 1 

I 

64.1 1 

I 

56.7 1 

I 

66.41 

1 1 CYCLONE AND FILTER 

I 

I 

I 

I 

I 

I 

I 

I 

I I 

I Mt 

1 

I PARTICULATE - TOTAL 

1 

mg 1 

1 

79.41 

1 

69.9 1 

1 

70.7 1 

1 

1 

1 Can 

1 

I PARTICULATE - PROBE, 

1 

gr/DSCF* 1 

I 

0.0252 1 

1 

0.0217 1 

1 

0.0260 1 

i 

I 

1 CYCLONE AND FILTER 

1 

(g/DSCM) 1 

1 

(0.0578)1 

1 

(0.0498)1 

1 

(0.0595)1 

1 

1 Cao I PARTICULATE - TOTAL gr/DSCF* 1 0.0313 1 0.0268 1 0.02771 

I 

1 

I 

1 

(g/DSCM) 1 

1 

(0.0716)1 

1 

(0.0614)1 

1 

(0.0634)1 

1 

I Cat I PARTIC.-PROBE, CYCLONE gr/CF 1 0.0136 1 0:0118 1 0.0141 1 

I 

I 

1 AND FILTER @ STACK COND. 

1 

(g/m3) 1 

1 

(0.0312)1 

1 

(0.0270)1 

1 

(0.0323)1 

1 

1 Cau 1 PARTICULATE - TOTAL @ gr/CF 1 0.01691 0.0145 1 0.0150 1 

I 1 STACK CONDITIONS (g/m3) 1 

1 

(0.0387)1 (0.0332)1 

i 

(0.0344)1 

I 1 

I Caw 

i 

I PARTICULATE - PROBE, LBS/HR 1 

1 

8.74 1 7.991 9.28 1 

1 1 CYCLONE AND FILTER (Kg/HR) 1 

1 

(3.96)1 

1 

(3.63)1 

1 

(4.21)1 

1 1 

I Cax 

1 

I PARTICULATE - TOTAL LBS/HR 1 10.831 9.851 9.881 

1 1 (Kg/HR) 1 (4.91)1 (4.47)1 (4.48)1 

* 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) 

B-15 ~~ 
~ MEMO 

SOURCE EMISSION SURVEY 

JOB NUMBER: 96-30 

JOB NAME: BORAL BRICKS 

LOCATION: HENDERSON, TEXAS 

UNIT TESTED: ABSORBER INLET DUCT 

SOURCE EMISSION CALCULATIONS 

SYMBOL DESCRIPTION UNITS 

I ----------------4 ----- 

I RUN# I 

I I 

1 1 1 

I I 

21 

I 

31 

I 

I I 

1 DATE 1 

I I 

1 02-15-96 1 

I 

02-15-96 1 

i 

02-15-96 1 

I BEGIN 1 1 0851 1 1053 1 12461 

1 TIME I I I I I 

I END 1 1 1003 1 12051 13581 

1 TIME 

I 

I I 

I 

I 1 

I 

I 

I P(b) 

I 

I BAROMETRIC PRESSURE "Hg Abs. 1 

I 

29.49 1 29.521 

I 

29.501 

1 

1 

1 

I 

(mm Hg) 1 

1 

(749)1 

1 

(750) I 

1 

(749)1 

1 

1 P(m) I ORIFICE PRESSURE DROP "H20 1 0.5001 0.5001 0.5001 

1 

I 

1 

I 

(mm H20) 1 

I 

(12.7)1 

I 

(12.7)1 

I 

(12.7)1 

I 

I V(m) I VOLUME DRY GAS SAMPLED ft.A3 1 28.7191 28.974 1 29.096 1 

1 

1 

1 @ METER CONDITIONS 

1 

(m^3) 1 

1 

(0.813)1 

1 

(0.820)1 

1 

(0.824)1 

1 

1 T(m) I AVERAGE GAS METER DEG.F 1 76 1 79 1 79 1 

1 1 TEMPERATURE (DEG.C) 1 (24)1 (26)1 (26)1 

1 1 

1 V(m[std])* 

1 

I VOLUME DRY GAS SAMPLED 

1 

DSCF 1 

1 

27.923 1 

1 

28.043 1 28.142 1 

I 1 @ STANDARD CONDITIONS* (DSCM) 1 

1 

(0.791)1 (0.794)1 

1 

(0.797)1 

I 1 

1 V(w) 

1 

I TOTAL WATER COLLECTED, ml 1 

1 

39.2 1 41.21 40.0 1 

1 1 IMPINGERS & SILICA GEL I I I 

I 

I 

I I 

I V(w[gas]) 

I 

I VOLUME WATER VAPOR 

I 

SCF 1 

I 

1.8501 1.945 1 1.8881 

1 1 COLLECTED ® STANDARD (SCM) 1 (0.052)1 (0.055)1 (0.053)1 

1 1 CONDITIONS* I I I I 

I%M I MOISTURE IN STACK GAS % 1 6.21 1 6.48 1 6.291 

1 1 BY VOLUME I I I I 

I Md I MOL FRACTION OF DRY GAS 1 0.9379 1 0.9352 1 0.9371 1 

1 Tt I NET TIME OF TEST MINUTES 1 72 1 72 1 72 1 

* 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) B_16 M 
m ETCOAPPENDIX C 

Calibration Data 

Equipment - Calibration 

Pitot Tube #12-5-1 (17) 

Factor 

0.808 

Calibration Date 

01/09/96 

Pitot Tube #17-5-2 (71) 0.806 12/29/95 

Probe Tip #II-5 0.260 01/03/96 

Dry Gas Meter #17-1 (11) 0.981 12129/95 

Stack Unit Orifice #17-1 (11) 12/29/95 

Digital Temperature 

Indicator #17-1 (11) 12/29/95 

Dry Gas Meter #17-2 (17) 1.037 12/27/95 

Stack Unit Orifice #17-2 (17) 12/28/95 

Digital Temperature 

Indicator #17-2 (17) 12/27/95 

Barometer #17-1 (6) 01/12196 

96-30 C-1 
/ 

~ 

n 

~ I 

PITOT TUBE CALIBRATION 

rDate: 4 _T'c<NU4r ~2 Time: /o o z 

~ Pitot No.: i 2- 5'— / Tg: -7 (p ° F 

Pitot Dimensions: ~w .S ' Cpstd• 0• 990 

~~~~~~ 

a ~MMVWVI.0 ".01 U. 

M ~ ~ W , 

MO ~M ~~~~r~, 

M.0 M- m~ 

====~MMMMM~ 

~Mase.~~I 

M-,., ~ W~- 

mmmm~MMMMM~ 

Summary of Results: 

Normal high side calibration factor 

~ 

D.53o8 

variation + a.9'9%`~ 

variation - ~.'~ q ~• ✓ 

Normal low side calibration factor ~ $°~. ✓ 

variation + 

variation- - I 3 ~•~ ✓ 

Calibrator: Tm 5-kr-+-i-- 

Checked By: 

C-2 

i 1 

~ 

I 
i . 

~ 

rn 

PITOT TUBE CALIBRATION 

~ 

~ 

; 

Date: ac) Q e C 

Pitot No..1 q- .S 

„ . 

Pitot Dimensions: 

Time: 1130 

T,: 70 ° F 

CWd: 0.990 

~ ' 

Calibration =Slandard 

~ ~ n Factor 

mm E. amm c me m mmmm ~~~ ~ 

mmm oa ~~~~ 

~

m~r~r.~n~m~s~~r~rse mMn'ra mm~:r.r.~Hamr.~ 

ro ~~~imo 

~.~

m 

==r. mm 

Summary of Results: 

Normal high side calibration factor Q.90t, ~ 

variation + 4 - q°I 

variation - ~• `~ 

Normal low side calibration factor 0. R f O 

~ variation + 

variation /- 

~ ✓ 

~ 

o 5 % 

Calibrator: 

e_ 3Checked B) 4/1 

M 

i 

~ 

~ 

~ 
~ METCO 

~ I U1ViROflf~f'(TAL 

, 

' NOZZLE CALIBRATION 

Nozzle Set No._U 

Date 3 qL Calibrator: ~~""~-~mp S m(-7 Ou blo q 

1 2 3 4 5 6 

Reading 1 ° Md , O. 13 ~ ,.IG9,Q o~ 48 _ o.aLn 0.3og 

Reading 2 140 p. 1 11 p. i q o. au.g ~(_ 0. 0 

Reading 3 .1 I'1 ra. ©.iqy n. P-QsQ ~(~ . 0•309 

Reading 4 0. lap 0.11a. 0-i gg 0.a41) ~ OW9 

Reading S o.(IO w-13 O.Iqa 0 •ISO .Wd) J 

Reading 6 Q. I f~.p t) 17 3 n. Ig~. ~g_ n. ~.~ L p, 3pg 

Reading 7 d.lap Q.(l l O.19 o.q,4°► O• 0•30$ 

Reading 8 . J Q n I12. .

.(93 O, a O• 30 

Reading 9 0.12.O O•D rd- ~ tQq . 0 0.309 

Reading 10 0•1(,~0 _ a 1• -13. O Iqq . 0.~4~3 .~ o•3pg 

!~ 9.0 ~ 

O. ~ -1~• ~ O. I q q ~ O•'d.~F °l ~ 4• ~(J Average 

7 8 9 10 11 12 

Reading 1 o 3ao -o. 3 ~ I .•~ O.L481 0. 635 

Reading 2 O.~~S _0 359 o.4a3 O•l8G 0.•0 

Reading 3 ~~ ~.~L L •O.4k4- D. (tBU 0.L35 

Reading 4 0,3ID ,3 0 O - 3 O 4gb . o L3y .

Reading S a•3'11 0.W 0,H TY 0.4m o, 635 

Reading 6 n, I ~Ln 0359 qU_ p,Wo G.L ~ S 

Reading 7 0 .39b 0,3$ 0-4~q 0,L4M_ G. Oto 

Reading 8 O. 3a.rl 0,4rO 4 A t 0 05 

Reading 9 C) ."3al 0.3S'~ o.yX3 ~.t• Tr 6 0. ~ 3 

Reading 10 () . 2~-b 0.413 

~

O' y9-I 

— 

0.635 

O, 3rl1 ~ O. 3W O• 413 '' O. 480 `~ O.l~ ~ 

Average 

C-4 1 ~ 
EL as 

IN 

Dry Gas Aleter Calibration 

Dry Gas Meter Number r! I 

Date: (a ag 

oH 

("H20) CDG 

0.5 O. 176 

1.0 ~•~ 74 

1.5 a.gsa 

2.0 0.98a 

3.0 o•q 83 ; 

4.0 0.183 _. 

Average 

/ 

Q Ag 1 

~ 

Variation : +O, ,Z0 ~o ~ 

- 0. S ~ 70 ✓ 

Calibrator: 

! 

Checked by: 

CDG@ 2 liters/min. = ,000 

C-5 r~ 
~ 

MEKO. 

DRY GAS METER CALIBRATION 

Meter Number: 1-7' ( Calibrator: PAJ ~ * 

Date: I a: 2 S - 15 

Calibration Factor (Coc) _ Wet Test Meter Vmsrd 

Dry Gas Meter Vmsrd 

Run.No.: I a O.sO }~~ p Pb: 0~ q, ~q 11H

g 

Control Module Vacuum: EO "Hg 

yVet Test Meter (No. ~ 

Meter Meter Temp. 

2'1m Saadin9 IemlL P,n, Reading 1D D-tt P,,, 

End 1'~~ ~ 5.a~7 cf 7 f ~ F — o. So ~H2p 45~~ 88 c f ~~ ~ F -1S o F O.So vH2O 

Start ~~_-~ a.000cf 'lI oF —o.80 .H2p y-~FR .4-'f7 f 79 oF 15 oF O.So «H20 

Av . I 3 9 5a ~"l ~f 7I J F ~~~ ✓H20 5.3Y'I ~f 7~ ✓ °F _ B.So ~H2O 

Wet Test Meter Vmsrd = 17.65 x 5• a ~~ a~ ' 13.6 xo. (C) =5, jo-a-dcsf 

-7 ( + 460 

+0.50 i 

Dry Gas Meter Vmsrd = 17.65 x5 •3~' I °~~' 13.6 =~- ~~ 9 dcsf 

76 + 460 

c - ~ 

S. ~ Oa = o,176 ., 

- 

C-6 • ~~ 
n MEMO 

n .~ 

DRY GAS METER CALIBRATION 

Meter Number: 

Date• I a-)L y - ~15 

, 

Calibrator: U Smr"~ 1 .. 

Calibration FactorCDG) = 

wet Test Meter Vmsrd 

~ Dry Gas Meter Vmsrd 

Run No.: @ I• °o " N, o pb: vZ 917 "H9 

~ 

Controi Module Vacuum:5 0"Hg 

\~J 

19 

Wet Test Meter(No. 

Meter 

T~= Haadltt9 IgmRa P,,, 

End 1114 S.oSo cf '7 1 "F- I. a0 "H20 

Start 07 0-0 0e ~cf ~F ~ a •~ ,H2 O 

Avg. cf -71 °F 1.20 H20 

Meter Temp. 

BeadIng 1D D-Ut P,,, 

417.114' cf -77 "F 7 1~ oF I- oo "H20 

W(.9 ff Xf?S oF7~F-oF I. ooWN O f /_ _2 

5; lacf 7` °F 1• 00 °H20 

~.av 

✓ 

Wet Test Meter Vmstd= 17.65 x 5.060 a~•d~ 13.6 x D,g`( I(C) _ ~{; `~ ),~dcsf 

-7 + + 460 

(,00 

f J 

Dry Gas Meter Vmstd = 17.65 x5• la b •6~ 13.6 = 

-7,s + 460

5. o33 dcsf 

CDG _ 1-MIF _ 0~9~~ 

s,o33 

o. Y~ 
I 

MEKO 

DRY GAS METER CALIBRATION 

Meter Number: P' Calibrator: frAd Shf-t~ 

Date: 

Calibration Factor (CoG) _ Wet Test Meter Vmsrd 

Dry Gas Meter Vmsrd 

U 

Run No.• @ 1-50 H.) 0 pb: _ 02`~ . b I "H9 

Control Module Vacuum: S,d"Hg 

Wet Test Meter (No. Qry Gas Meter 

Meter Meter Temp. 

?m@ Head3D9 Semp. .e,,, fleadina in -0-Ut P,,, 

End Ja~O 10.0$3 cf —41 °F ""I. b'O MH2O if--79- s6 0 cf °F ~n °F 1-50°H20 

Start W5 0. CM~f 71 % F 1 - 40~H2O 'T 6~ -~cf ~° F~° F 1• 58✓H20 

Avg. ~ rj ~ 0-083 cf ~ ~ °F '" ~ . ~0 °H20 ~0 , a~ ~' cf '7~~j -°F ~~ 5 "H20 

Wet Test Meter Vmsrd = 17.65 x 10.0?3 ~• ~ 13.6 x 0q1' (C) = 9. Y).Jdcsf 

+ 460 

Dry Gas Meter Vmsb= 17.65 x 10.Z1 ~ 

'r 

+ ~ .o 

~~. 61 13.6 ✓ csf 

?? + 460 1 0.00~ 

CDG= ~•~aa = 4•1$ ~ 

c-s 

1fl.0aL - 

~~ 

~ 

I 
~ MErCC 

DRY GAS METER CALIBRATION 

Run No.: ..~ ~ C~ ~ •O®1 r~C 

Calibrator: 5 "it 

Wet Test Meter Vmsrd 

Dry Gas Meter Vmsrd 

Pb: a l. 61"H9 

Control Module Vacuum: 5•0"Hg 

Meter Number:I~L! ( 

Date: I ~~8(&Is 

Calibration Factor (Cos) = 

.~.~ 

Wet Test Meter(No. 

Meter Meter Temp. 

S!M Se1]]R. 

End ~ 3 ~ 1 

He.3S1!'n9 O

3 cf F o—~ " H20 °~ Q~ y' ~f 80 o F ~'S o F a ~ "H O 2 

Start I_clj_Q O.Wof '7- 1 ,~F — 2•~~y20 tf O.~'3'~ f~° ~ °F a•~``~O 

Avg. ~ ~j la.la3 cf ~) °F ~• "H20 10•a 1F5 cf ~g °F ol• W"H20 

_a,00 ✓ 

Wet Test Meter Vmsrd = 17.65 x j0. la3 a~ •6~ + 13.6 

+ 460 

x0.111 (Cr) _ J ,$S I dcsf 

~ 

~ 

a.00 

an' 13•6 Dry Gas Meter Vmsrd = 17.65 x lo•~~ 

W 

=1Q.Q2$d sf 

+ 460 

CDO= 

(o.a ~~ 

C-9 
r, M~r~co „

DRY GAS METER CALIBRATION 

Meter Number: 

Date: 

Calibration Factor (CoG) = 

Run No.: @'3 •0oI No 

, 

Calibrator: ~ M 

Wet Test Meter Vms,d 

Dry Gas Meter Vmsrd 

Pb= 21.91 "Hg 

Control Module Vacuum: "Hg 

It 

Wet Test Meter(No.3) 

Meter 

MM Haadia4 Semp. P-I„ 

End 3IS ]Q,5)$cf °F "'310 "H20 

Start 3 ~ a0~cf ~~~F "3 -1C'7~H2O 

Avg. 11 ' ~cf ~'I ° F - 

 3 ~ 

°,/H20 

)0,518 

Meter 

8eadins 

SOa., 37 i cf 

~aI 1'7-cf 

✓. 

/Q, Sff cf 

Temp. 

1D S2itt .B,,, 

voig °F 1'~ °F 3.00-H2O 

80 °F ~Sr °F ~"h 20 

.~.1 ~ °F 3•00 -H2O 

+ 

Wet Test Meter Vmstd = 17.65 x lo.518 a9' 13'6 x 031 1(Cr) dcsf 

+ 460 

Ioo 

Dry Gas Meter Vmsrd = 17.65 x IO.Sp~

a~.t~~ + 13'6 =10,3 ~a~dcsf 

~9 + 460 

cDa = lo . 1 °1 a 

la.344 

C_10 

= 0.183~ 

4 
mErco- 

~9 c 

DRY GAS METER CALIBRATION 

Meter Number:1-7-1 Calibrator:au ( 57r-,-kk 

Date: tZlzq l9s 

Calibration Factor (CDG) _ Wet Test Meter Vmsrd 

Dry Gas Meter Vmsrd 

r 

Run No.: @ •d 20 pb: a 9 66 "Hg 

Control Module Vacuum:S: o"Hg 

Wet Test Meter(No.-5 ) 

Terr 

!n 

Tr°F 

7f

. 

Meter 

_T= Seadi4U IamRa Z„ 

End iO3 7 /0.23 fcf -7 2-- °F — 3•go "1-120 

Start /4PLr d.o d o 39 72- ✓ F -3. g' °H O 

✓ z 

Avg. /O.z3rcf 72 °F -3 Sso "H2O 

Meter 

Reading 

573. 7'sl cf 

~ G3-~z✓ c

/6 z~~ cf 

ip. 

9sat Pm 

7 7 °F `/0 "H20 

7 & 0F. 460HZO 

°F 

1/0 

 s,H2O 

Wet Test Meter Vm 17.65 x (6. 23 s std — '7 Z 

+- 3 YO 

,/ 13.6 x o. Q9yC

f ~ 

y8'~s? dcsf 

+ 460 ( 

+ Z(.oa ~ 

Dry Gas Meter Vmsrd = 17.65 x ra 2 f~~ z s c c 13.6 _ 10, p'!~3 dcsf 

7 F + 460 

CDG _ ?' gIK 7 

/ O• oS3 

C-11 44 
MEFCO- EwRonMErMc 

DRY GAS METER CALIBRATION 

Meter Number: 

Date: 1 1 - 

Calibration Factor (Cos) = 

Calibrator: fp,,~ 

Wet Test Meter Vmsrd 

Dry Gas Meter Vmsrd 

Run No.: ~ h- Pb: a 9. tb »

Hg 

Control Module Vacuum: '-- o "Hg 

Wet Test Meter (No. ~ ) 

, 

~ 

r1m 

End laZ,-, 

Start o951 

Avg. L I 

Meter 

Saadip9 TemR. P-M 

Z, osG cf 72— °F -f. ZO °HZO 

O.000 ct k~ ~ 1.20~20 

2.. o s~✓cf 72— °F -/.zo YH2O 

Meter 

Beadina 

SGZ.Soz cf 

560.730 ~f 

z.o7z cf 

Temp. 

!II -Qilt Q,,, 

76 °F 7G °Fo .o c "H20 

-L6—°F -7 6 O F 0- O 1 ✓H20 

7 4 o F a- a( "H20 

~q• 6~ + 

Wet Test Meter Vm sG vZ~ dcsf 13.6 

srd = 17.65 x z.o ~

+ 460 x1' c03(Cr} 

= z, 

a~.b$ + 

 °.o r / 

Dry Gas Meter Vmsrd = 17.65 x a.o?z- 13.6 = Zoz

. 

 dcJsf 

7 ~ . + 460 

COG 

/, ovo 

z-o Z 

C-12 ,!!M 

~ 

ME-TCO, 

DIGITAL TEMPERATURE INDICATOR NO.17-1 

CALIBRATION DATA 

Date: 19ni' IS 

Mercury 

Temperature DTI 

Med.i ilme (° F) (~ 

Ambient Air j 3~ 7 

Ice Bath 

Boiling Water Z/z z 

~ Oven 

' Oven 

~ Oven /67 3 S 3 s"o 

Oven 376 3~ ~ 

Meter Adjusted? Yes No ~ 

Calibrator: fA~za ~''' 

Checked By: 1~ --'r r' 0 Z 

C-14 

Sa- 
.9 

~ 

MEFCC 

Dry Gas Meter Calibration 

Dry Gas Meter Number fi--.? 

Date:IoZAoZ~i ~"rs 

nH 

("H20) CDG 

0.s ~~ O34 

1.0 l, 03& 

1.5 1,C73y 

2.0 1,d36 

3.0 1 , 037 

4.0 110 

Average 1, Q -37 / 

.o 

Variation: + ~ • qZl 

Calibrator: 

Checked by : 

CDG @ 2 liters/min. 

C-15 ME 
n METCO. 

DRY GAS METER CALIBRATION 

Meter Number: 1 4- a Calibrator: Cilt 

Date: i 3-:13g 

Calibration Factor (CoG) _ Wet Test Meter Vmsrd 

Dry Gas Meter Vmsrd 

Run No.: I @ 0 e5-0 i n ~~}(~ Pb: a qr & /- "H9 

Control Module Vacuum: "Hg 

Wet Test Meter(No. ~ 

Meter Meter Temp. 

T.ime 8ead1o9 IsDOp, P_,,, BeadJD9 !II QW P~„ 

End 1 -3:Ya 5.yy5- cf ~) °F --d ,qn "Hz0 tiaq 7vg cf g I °F 79 °F 0 "H20 

Start 13%30 0,00 ~f ~ ( ~F - 0• c? "~20 tIl9'.'/Q/ %f ~9 oF ~_oF 0/5~ ~H2O 

Avg. ~ : la 5,'1gS cf ~ ~ aF -,d ,9 ~~H2p 5,3v'i ~ cf ~~ oF 0•5P °1-120 

- 0, qDo 

Wet Test Meter Vmsrd = 17.65 x5,`(9S 13.6 

~ xO, qql (C) _ 5'`, 3 'Wdcsf 

~i + 460 

D•~I'1 0 

Dry Gas Meter Vms rd = 17.65 x h~3~~ 

a°1-6 1 + 13.6 dcsf 

31 + 460 

C DG 

__ 5 . _ y . d3 1/ 

C-16 
~ 

MEMO 

DRY GAS METER CALIBRATION 

Meter Number: I ~ " a 

Date: I a 1 a -I yif 

~ / 

. b . o /(Ii /,

._6Y~ `L 

I 

Calibration Factor (Cos) _ Wet Test Meter Vmsrd 

Dry Gas Meter Vmsrd 

Run No.: ~ C~3 ~'Q ~n ~~d•y Pb: a ei. G I »H9 

Control Module Vacuum: "Hg 

Wet Test Meter (No. ~ ) 

L-Ij 

P-M 

... (.30 "HZO 

H20 

nH2

0 

Meter 

e He3diaa ?emp. 

End 1 L1;y~ 'S•3al cf -4d °F 

Start 0Q~rf ~ a°F 

0:0 5.3a1 cf `3d °F Avg. 

Meter Terr 

Eeadi.n9 1n 

qYt.a7r4cf 'il— °F 

yq3. Jyv cf S-.R °F 

S• 13~ cf 10 

IpSo Pn 

14 °F 00"H20 

~'le °F j, 00/H20 

OF I-00 "H20 

-),3d0 

+ 

1-1

Wet Test Meter Vmsrd = 17.65 x 5.3~ ~ 

13.6 x 0, 9o1 / (Cr) = j. dcsf 

~-a + 460 

+ 

(, Oo ~ ✓ 

Dry Gas Mefer Vmsrd = 17.65 x~, ( 3 ~ ~ + 1 4 0 Li' qj3dcsf 

CIDG_ 

1, 036 ~ 

c-i7 
;! 

METCO 

DRY GAS METER CALIBRATION 

Meter Number: 11 -3 Calibrator: 

Date: I Aq5- 

Calibration Factor (Coc) _ Wet Test Mefer Vmsrd 

Dry Gas Meter Vmsrd 

Run No.: 6I. Pb: a °I, b 1 "Hg 

Control Module Vacuum:5-# 0"Hg 

9 

Wet Test Meter(No.3) 

Meter 

2tm@ Beaslln9 IemR. P-,► 

End ! tI%3t 10, 'f J9 cf "ta °F - • gc "H20 

Start /y ~a0 0 -00cf ~'a O F ' 11 90 ~I20 

Avg. 0 1- I l~ 10 ~~~ ✓cf F - I,°IO "H20 

o ►- uC 

Meter Temp. 

Readin_a in DJA Pn, 

Nya,a76cf °F °F 1-570"H20 

c~,f. lq "F "F ~H2O 

1 0 ' 347cf W °F / -57) "H20 

+ 

-000 ~ 

Wet Test Meter Vmstd = 17.65 x tQ1"717 13.6 xo,qql (.Cf) =1d 1 tlyydcsf 

 + 460 

+' 1 6 ,i 

Dry Gas Meter Vm 

+ 460 srd = 17.65 x 1 Q.39 ~ 00 dcsf S'0 

CDG _ '0' YW _ ~ ~ D 3 `f 

Ic? ~ lo0 

c-i8 v 
Run No. I a a, Oi n/7~L 0 Pb: aq., ~ l "Hg 

Control Module Vacuum: ~~ "Hg 

m 

DRY GAS METER CALIBRATION 

Meter Number:I -~ "0 

;_ 

Date: I 7~-Na`? q 5 

Calibrator: ~ 

Calibration Factor (Cos) _ Wet Test Meter Vmsrd 

Dry Gas Meter VmSra 

I 

Wet Test Meter(No.3 ) 

Meter 

T1II1S 8ead1114 Iemp. P~„ 

End 1 S;1 y 10. 540 cf Ta ° F- a- 1 0 "H20 

Start 15: 01 0.0 0 ,f -}a.~F - a, i~OvH2O 

Avg. 0 ~ ~ a ( 0, ~1a cf ~'~ OF - a. 14H2O 

Meter Temp. 

Hsadina J,a S-Ul P,,, 

y s5macf `15' °F °F d?.WH20 

' rlV$1 g i~p S-0 'F `F a,0a`~20 

(0, -~3cf 'c6"- a ✓ o F a,OaH2O 

+ 13.6 Wet Test Meter Vrnsrd= 17.65 x 1o, 5 r~0 

7 a+ 460 x0'qq. (C!) = 10, a vf'dcsf 

+ 

a _ vo 

Dry Gas Meter Vmsrd = 17.65 x 0, l~ j a ~ ~ 

 13'6 =

9 

 f~~I csf 

j Ta + 460 

COO = 

C-19 
Run No.: I a 3f 0 1 n 60 Pb: a~,~/ "Hg 

Control Module Vacuum: 5 . "Hg 

~ 

m~rco 

~ DRY GAS METER CALIBRATION 

Meter Number: Calibrator: 

Date: 

Calibration Factor (CoG) _ Wet Test Meter Vmsrd 

Dry Gas Meter Vmsrd 

yV_et• Test Meter (No. ~a 

Tme 

End 

Start IS~ tg 

Avg. 

Meter 

~eadinc 

IO ,9bT 

6,00 

10 `16e( 

l Iemp. P-M 

cf 4a °F - 3 • 00 "H20 

✓f ~~F " 3 ,~0 ~ 2 0 

cf 7a-F - 3 ' 0 " ° H20 

Meter Temp. 

Readin_a lII .4st P,,, 

~ Sfajncf °F -+q °F 3-6 "H20 

~1a.~4q ✓ ~ ~oF ~-`6oF 3.p -H2O 

W.yY3 cf °F 3-e) "H20 

13.6 Wet Test Meter Vm - 17.65 x 10,96`~ x(~ o~ I I(Cr) = j5 ~ dcsf Srd - + ~ 460 ' 

Dry Gas Meter Vmsrd = 17.65 x/p, 5,y3 

+ 3,~ ✓ 

dcsf 

$ S' + 460 

~ 

coo - i v 11 5S~ ~ 

l~ 0"3 7~ 

CV.aa ~( 

c-2o 
mErco- e'WIRonn-EnTnC 

DRY GAS METER CALIBRATION 

Meter Number: Calibrator: aeL Ut~ 

Date: j 

Calibration Factor (Coci) _ Wet Test MeterVmsrd 

Dry Gas Meter Vmsrd 

Run No.: 1 a LI, 0 1- ^ 1 40 Pb: oZ q, 6 / "Hg 

Control Module Vacuum:5•-A"Hg 

~ 

Wet Test Meter(No. ~ 

Meter 

MM Seadin9 Iem°• P,,, 

End I 1 1,5b1 cf °F - 3-IrO"H20 

Start ~6~ 00•00J f - F - 3JO J i20 

Avg. O,Og I1,5771 cf °F H20 

Meter Temp. 

Bea~ 1n DJuf Pm 

y 9 b .i9ycf 10 3 °F Sr4 °F 4, 6 "H20 

'115.Urcf1*3 °F it°F `l, o H20 

~ 4's `~ ✓ °F << ~ 0 "1-120 

Wet Test Meter Vm St? srd = 17.65 x ~ ti, 1 } 13.6 x a,qq ~ (C) _ ~ ~ ~ 0 dcsf 

~-~ + 460 

~ 1, 0 ✓ 

a9•G~ + 13.6 Dry Gas Meter VmSrd = 17.65 x( ~ , ~ (r q ~9 = 

+ 460 

I, p + b yadcsf 

Cl, 0~ 1 1. na ✓ 

.0 

to. & tla 

C_21 S, 
MEK'o 

DRY GAS METER CALIBRATION 

Meter Number:I 

Date: k2•Na ~~~1 ,

~~ 

Ca iI 'brator: 

v ajf4lWet Test Meter Vmsrd Calibration Factor (CoG) _ 

Dry Gas Meter Vmsrd 

Run No.: @ pb: 02~~ "H9 

Control Module Vacuum: "Hg 

n 

~ 

Wet Test Meter(No. 

Meter 

Slm Eeadin9 Iemp, .e,,, 

End 9; 14 a..a33 cf -43 1 °F -130 "HZp 

Start - Li a0.00cf _'43" ' F - 1-3 a "H20 

Avg. '3a 1033 cf 7+3° °F 1•30 "HZO 

Meter Temp. 

fieading : in S2t1t P,,, 

sd I. 3a8"cf ~ 3 "F J3 °F 0.0fH2O 

4q9, a69 cf 4.1_°F 12 °F0- 0f"H20 

-~• OTI cf :?

-3° °F o.o I"H20 

+ ` j 6 Wet Test Meter Vmstd = 17.65 x q,4 3-3 D 

~'3 + 460 

x l ' 0o3 (Cf) 604 Jcsf 

+ o, 1 

Dry Gas Meter Vmsrd = 17.65 xa. 0 ~9 a~'~ 13.6 = a,03o.dcsf 

+ 460 

c~ = a~ o ~ 

a,U30 

C_22 im 
YY~YO ~il~~~Y~O:~~~~~~ 

YWm ~f~a~YW~~YW~YR~ 

Y~~~~~~YO0OrO0~M 

~_~Y~~Y~rr•~o~_Y~Y 

~~~~ us~o~i~~ ~ ~~ ~

~ 
r, 

8 

d~It:,K-v 

DIGITAL TEMPERATURE INDICATOR NO. 

CALIBRATION DATA 

Date: 

Mercury 

Temperature DTI 

Media Iim.~ (OE) 

Ambient Air 1 030 (9 1 °F oF 

Ice Bath I D a.0 a°F 3d- 'F 

Boiling water 0'~ l 5' a ~a-° ~ 0- 13 °F 

Oven I. oa 6,) v rOven 1 3 l 5 S OD°F 3 ya~F 

Oven ~ t~~S 37 q°l= -3 76°~ 

Oven 3 6 ° 

Meter Adjusted? Yes No — /Y 

Calibrator: 

. ~ 

Checked By: ~~ 1 

C-24 

ri 
---I 

LI-i 

~ METCO 

--i 
~ 

- Scott Specialty Gases, Inc. 

® 1290 COMBERMERE STREET, TROY, MI 48083 (810) 589-2950 FAX:(810) 589-2134 

~ CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS 

Customer Assay Laboratory 

, METCO ENVIRONMENTAL Scott Specialty Gases, Inc Purchase Order : 3067 

Attn :!im Monfries 1290 Combermere Scott Project q 572186 

16115 Dooley Road Troy, MI 48083 

Dallas, TX 75244 

ANALYTICAL INFORMATION 

ThIs certification was performed accordin g to EPA Traceability Protocol For Assay and Certifcation of Gsseous 

Calibration Standards; Procedure GI; Sepfember, 1993. 

Cylinder Number : ALM040839 Certificate Date : 10/26/94 Expiration Date : 10/26/96 

Cylinder Pressure +: 1900 psig Previous Certificate Date : None 

ANAL,YZED CYL.INDER 

ComRonents 

Nitric Oxide 

Total Oxides of Nitrogen 

Certifled Concentration 

18.72 ppm 

19.10 ppm 

Analytical Uncertainty 

f1•/. NIST Directly Traceable 

Reference Value Only 

Balance Gas: Nitrogen 

+tb oot ase when eylinder prcssaue is wa~mr gsaaces whieh at lesst ixlude 

Type Expiration Date Cylinder Number Concentration 

NTRM 1684 4/1/96 ALM-024582 95.2 ppm Nitric Oxide in Nitrogen 

~ INSTRUMENTATION 

Instrument/Model/Serial # Last Date Calibrated Analytical Principle 

NO : Horiba/OPE-235/483814 10/25/94 Chemiltuninescence 

ANALYZER READINGS (ZP= Zero Gas R=Reference Gas T=Test Gas r=Correlation Coetticient) 

Components First Triad Analysis Second Triad Analysis Calibration Curve 

Nitric Oxide tHts:10119m Responto Urtits: mr polr. 10RGM Respanss Unils: mv tAKntr ~WN •B:.C:2-Oi •!s4 

Z1-O.00 R1-95.20 T7 18.80 Z1a0.00 R1a95.20 Tt=18.70 r+=o.99999 NTRM 1684 

R2-95.20 Z2-0.00 T2=18.70 R2=95.20 Z2=0.00 T2=18.70 Constams: A=0.000000000 

Z3--0.00 T308.70 R3--95.20 Z3=0.00 T308.70 R3=95.20 8=1.000000000 C=0.000000000 

Avp. Cone. d Cust. CyL 18.73 ppm Arp. Cona ol Cust. Cyt 18.70 ppm II I 0=0.000000000 E=0.000000000 

Special Notes 

Customa 

C-26 
~ ..i ... ~-~.•.~ 

.~ L ~• .• ~;. .. :~:i~.!~ -.. .. ., ,r.. .. 

. . • • . . •,.:_ --- ,. ~y 

 ' ~+r}~ ~ X.-~ ', ' ~ :.~~;~i•;~ =.C: •

~.~Y,t,;~ ' ' a_: r= .ri • _ . t • .. ~ . - ~: ~ ' -. : v

. j . ~ ~ ' • . . 

'? .5~ :. f • 3 ~ ' ~ •;~'Z' ' .. '~,,L:.;". . • ,' -r_ ; .: 

.: • • 

_ :, . 

a • .. - !1l' l- t~'. • 

_ • ~y., . ~'~ .~ 

~•t,' w• •:t..c•• ~ ' C `'•G~ ~.~~ •_ : }' '~l' . .. •R •_~_ - • ! . C• . , G. . ~ - ~ '• _ . ~. j~:~ . t• , ~•'.: -L , . ;' • :_ ._3 , .;:=•r ~~.., ~ _ ` ~. ; • • : : , r ati a• . .: -- •• -" ~_~'~ •• • }•.t ~ _ _?. , w ~ •. 

:0: ~ :. Scott S ecialtyi:G I?.,. ~ses, Inc ~. 

~ . •. 1290 yC~OMBERMERE STREET. TROY, MI 48083 ~ - . ~ •. :: ( 810) 589-2950 FAX:(8_ 10) 589-2134 .: 

. ~.. T. ' v `~r~~ t • ~-!r,~.~Py7~.~~~~ 7.~'.~-t3.~' '(i • . !.. , • r.. .. .~ • . • ' ... , yJ4' i w • t~`: •.•..'i,' 

. ta • , "~ .•a : _ a ~ _ /.- .':S. .- r: '~-1s1' i ~~ '- ~"'•y -u ~i~ :. ~.?' ~.~~~f ~,.;,'t ..r~ ~~ ~ 'F.. ~.a . :.S;S • . . ! ••~ , _ - . ~f i ~~?r • ~t •... 

~•y...w a ~ •.7~•_ _ . +.:. ~ :t' : ,~;,;•'; ~ • . • .-• ~ - - . •~E'; ) . ••': _, .~-, ~ ti • ~ -~ •' ~• . :.^ `_ ~ - •'z; 

_ ._•' •• • _ 

,, ~r ~~. •.~ri 

 . ~ ~~~ '•.C~:y~ ,%4 ~'?'~.~~'~'~ 'n w. ~,.. ;'r . ..~t~ .Y` : .; . - _! 

~ 

CERTIFICATE OF ANAL•YSIS EPA PROTOCO `:° ~ t ` • ~•'."~" '~ • ;~. • ~- .. -~ ~; y., ~ ~:.. _ ~ L GAS ,. ~ - :~'_ _ _ : '• •~=:~~ ;:::=~.`~ . • 

. ~ ` • ~ ' ~ ti.. ~7 .':~I?'~~~ '

. L~:.. 'b•: ?► ;'. ' _ • l•`.: ' ' i ~•'•5 „ . .. '}r. t .: , j: r - ' ~ ~ • ..•f.:. ' ~ • . . . r: ~ •' : . ~n ~ ~ s' ~ ~c•~;••: 

 ' t x a~1.?~. • ' ttir .a - . ~ t. ' . ~ . .` • '' •-+.' . : 

Custome~~~k'~,~~~:~~ ~ ~~'~ .'~'~~: AssayL.aboratory ":~':;;.'~'' —.; _4. `~n Specialty GasesIncc: `_' Purchase Order .• r 2648 -`• - 16115 DOOLEY ROAD ~ _ 

DALLAS, TX 75244= , 1290 Combermere Scottct # 564105 ~; ~ _' Troyr 1~ 48083 Proje 

:_ti' `~ •~ r. : ~ r ~: '.~~~t,' -`_~ 

; "-""'~ .:~ ' ~ ;1 _ . _ . , . _ , . . . • • _ ' • 

~ 

. . . _ ' '~_.:~:.- 

_ .e. ~' . • ' : = : - . • 4. , . ' • - . . 

' . . - . . `~ ~ • ~ .~'.- '...~a,~ '" ...'

:si.- • ~`~:; :. ~•~

+. 

~ :. ° ~ ANALYTICAL INFORMATI ON ~ ~~ . . . . . . • . 

This certifieation was perfomud aecordin g ~ 

to EPA Traceability Protoeol For Assay and Certifieation of Cmseo on Standards; Procedure Gl; September, 1993. us _ 

~ 

linder Number :, BAL1881 - Certificate Date : 4/11/94 Expiration Date : 4/11/96 nder Pressure +: 1900 psig Previous CertiGcate Date : None . ~-': ~_ . . . . • 

~ 

—x.omponenu 

- Nitric_ Oxide 

Tota! Oxides of Nitrogen 

Certified Concentration 

46.15 ppm 

Analvtical Uncertaintv+ 

f1•. NIST Directly Traceable 47.40 ppm Reference Value Only 

~ . • -• '~'"• ..' . ' ' • .. 

= Balance Gas: Nitrogen 

r t-lAwalytical

Do aa nse whea eylinder presutue is below I5 0 psis. 

aecurxY is mdusive of asual lmowo error sourea M ~~ u least inelude D ~maon of tbe meamsmeat pnoeessa• 

~s• ~t 

~ 

FFF'RENCE STANDARi~ 

Expiration Date Cylinder Number Concentration 

_ 

 1694 . 4/1/96 . ~ . . • • 

ALM-024622 

• . 

95.3 ppm Nitrie Oxide in Nitrogen 

. 

3UMENTATION 

ment/ModeUSerial # . 

ion•ba%OPE-235/483814:'.. 

. - ~ • ~ ' 

Last Date Calibrated 

4/5/94 ' 

Analytical Principle 

Chemiluminescence 

(Z-Zero Gas R-Reference Gas T=Test Gas rmCorrdation CoeQicient) 

, Frst Triad Analysis :' Second Triad Analysis • Calibration Curve' - 
.~: Scott Specialty Gases, Inc. 

1290 COMBERMERE STREET, TROY, MI 48083 (810) 589-2950 FAX:(810) 589-2134 

CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS 

Customer Assay Laboratory 

METCO ENVIRONMENTAL Scott Specialty Gases, Inc Purchase Order : 3067 

Attn : Jim Monfries 1290 Combermere Scott Project N: 572186 

16115 Dooley Road Troy, ,II 48083 

Dallas, TX 75244 

ANALYTICAL INFORMATION 

This certification was perfomled accordin g to EPA Traceability Protocol For Assay and Certification of Gaseous 

Calibration Standards; Procedure G1; September, 1993. 

~ 

Cylinder Number : ALM038783 

Cylinder Pressure + : 1900 psig 

ANALYZED CYLINDER 

ComFonents 

Nitric O:ide 

Total Oxides of Nitrogen 

Certificate Date : 10/26/94 

Previous Certificate Date : None 

Certified Concentration 

85.40 ppm 

86.10 ppm 

Expiration Date : 10/26/96 

Analvtical Uncertainty 

tl% NIST Directly Traceable 

Reference Value Only 

~~ 

Balance Gas: Nitrogen 

+Do oot use whea rylindrr presssure is below 150 psig. 

•Aytieal aoeurxy is inelasrve of usual Imown error souroes whieh st leut inelude precision of the meuuremeat proeessa. aal 

REFERENCESTANDARD 

Type Expiration Date Cylinder Number Concentration 

NTRM 1684 4/1/96 AI.M-024582 95.2 ppm Nitric Oxide in Nitrogen 

INSTRUMENTATION 

Instrument/ModeUSerial Il Last Date Calibrated Analytical Principle 

NO : Horiba/OPE-235/483814 10/25/94 Chemiluniinescence 

ANALYZER READINGS (7-uro Gas R=Reference Gas T=Test Gas r=Correlation CoelTicient) 

Components First Triad Analysis Second Triad Analysis Calibration Curve 

Nitric Oxide Oate:10l19f94 Rssporsse UrAs mv Date: 10/26J94 Resporw Urws mv CoKiwaooe_A•B:•Cs2•Di •t :1 

Z1•0.00 R1-9520 T1-S5.50 Z1.0.00 R1=95.20 T1-85.60 r-0.8B999 NTRM 1684 

R2=95.20 Z2=0.00 T2=85.10 R2=95.20 Z2=0.00 T2=85.60 Corntarft: A=0.000000000 

Z3=0.00 T3=85.00 R3=95.20 Z3=0.00 T3=85.60 R3--95.20 8=1.000000000 C=0.000000000 

Avp. Cona of Cusi CyL 95.20 ppm Avy. Cona of Cust Cyt 85.60 ppm 0-0.000000000 E-0.000000000 

WcoID_1 

Special Notes 

Customer 

C-28 
li M~ ETCO

~ 

APPENDIX D 

Field Testing Data 

g6-30 D-1 

lp~ 
P

E 

J v cc 

~ ~ d lL. 

~ 

~ Y 

W 1, O 

w R ~ ~ d 

m m 

cc aaa 

~ 

, 

~ 

n. 

a~ 

4 

~ 

~ ~ n o —m > > o a) 

~ -5oC ~ aOcn 

~ 

.~ 

~ V U 

~ o0 

Vj 

~ 

Y 

d 

J N 

U J 

a n- c e ~~ A =t ~ ~

0 

~ I 

O ~v ~ 

z ~ ~ 

1x J 

 co 

~ ~ X 

~ O ,C 

s 

¢ o ~ 

a~ I 

N, 

o ~ ~ z E ~ ~ 

u ~ 

m 

1~ 

o o 

a 

\ 

N 

1 

Z O_ Q ~ 

~ N~ 

d o° Oo~° 

cc 

'o.. m ¢ 

> 

\ 

~ 

l 

O~ 

"° 1y) 

„ AN ~ 

>~ 

CD 

~ vi _ 

0 

1~ 

~ ¢ 

Q 

~ 

'-• 

xWd 

~LL 

o m 

(~N.~ Nn 

C.0 d 7-CD 

CD °t.' 

=E~ m~.h ~ mm 

~~~~~ 

p\ 

NN'vNN ~ N 

a

E

°a~~!~ ~~~ah~~~y a i ni ~j Nn~i~ 

NNNN N NNc~ NN 

~ELL a~° 4~ 

II N N'NN ~ NN 

\,, a00\ ~ 

1~ . \Q 00 ~ 

NNN ~ NI,jN ~[V N 

~n►° ° 

~ '~C7 c n >x 

~ \a \9 ~ ~1 M) •? ~ ~ ~ 

U=U 

'~- 

W ~ ~ ~ ~ 1 _ O \I 

\ 

•I 

1 ~ 

"~ ~ 1 ` W ~ ~ 

I 

W I'~ 

0 

S

=m \O ~~N ~r ~ o0~0 ~~° ~0 

o ° ~ o 0 o p O--Z " Q o 

~ .=M . MMM 

0 0 0 4 4 0 ~ 0 0 0 p 

~ i N R1 \' O ~ ~' ~ \9 ~Q N ~ m ~ ~ n` '~o ~ 

~ 

a

ll

o 0o txa (4 00 

N 

po oa ~p eo Oo bo 

~~~~ 

~

a

~a~.~, N \ 

o%Zl00000 ~ 000 ~ oo 0000 

D-2 1.4 ~ 
Impinger Box No. / 7 - 1 

t-1 

Impinger 1 

, 

Impinger 2 

Impinger 3 

Impinger 4 

Impinger 5 

Impinger 6 

~ Impinger 7 

Moisture Conteni: 

Final Weight 

Initial Weight 

Increase 

Fnal Weight 

Initial Weight 

Increase 

Fnal Weight 

Initial Weight 

Increase 

Fnal Weight 

Initial Weight 

Increase 

Fnal Weight 

Initial WeightIncrease 

Fnal Weight 

Initial Weight 

Increase 

Final Weight 

Ini6al Weight 

Increase 

Water Weight Gain 

V. _ 

g SOZ= V. _ 

pb = Z~ 09v 

V. 

V„= ./ ✓ 

P. 

Avg ep = D•39~ ✓ 

Impinger 1 ~' S 

/ Z 

Impinger 2 —_ 

3. O 

Impinger 3 

Impinger 4 ~~ 7 

Impinger 5 —_ 

Impinger 6 

%COz 

%02 

%CO = 4• O '~ 

%NZ 

A. 

D, = 0•26b ~ T, _ 72 ~ 

Z9 y;7- Hg 

539 °R Va °R 

~ 

~ tf.I 

38 • S 

3. 1. 

i3 

/D. z 

Lq ~6 IS' 

3~ 

1 

AvgFM= 49• 6Z 7✓ 

CP = p," ✓ 

P. = —0.30 r"N0 

T.  = 78✓ '17 

T,= 

%M = 7- 0 7 ~ Md = D• 92 91 MWd = 29. MW 

Impinger 7 

Total 0~3• k- = V 

w 

Pm 

Vm = Pb + 13.6 _ +~~ 9 39 /2.3 sfi' 

~d 17.65 Vm T + 460 - 17.65 x yo 3y6 Z9, f~ 13.6 _ D-s~i3 s tm 

`~ 7g + 460 

Vw9as = 0.0472 x Vw = 0.0472 x 63- sft' 

% Moisture =_Vwan x 100 = Z. 9 79 x 100 = 7.0 -77- ~% 

Vw9„ 39./23 + Z,97$ 

Vs = 5123.8 X a g06 S96 x 

~ - z9, y~ x zg.z3 _~ -- 

°i°i = 1.039 x 39, 103 x 896 __ /Ol, 9- °~~ 

Z687 xo490,9,3 x Z9, /7-z x 72 X(0'z60 )Z 

D-3 

ACFM: 7y 66V 

SCFM: 

%EA: 3/ ~• Z ~ 

/I C/ 
~ 

1.

E 

~ 

~ 

Cl 

~ 

W 

Li 

k 1-- 

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n.

E 

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~ 

z 

Q ~ ~ 

~~~~ ~~IIIII ~IIIIIIIIII 

% ~~~~ 01111~~11111 IIII 

1", Ix~IIIIIIIIIIII~III 

, .~~~~~~ ~~~~~ ~~~~ 

D-4 I~ 
Pb= 29. tZ ✓ 

V. 

P. 

 - D• 96~~- 

Avg AP = O• y~C.~i 

AvgAP = 01 666 

C = ©. $08 ri 

P. .,,-HO 

T. g/"6F T. _ WO .,- -F 

Fnal Weight 

Initial Weight 

Increase 

Fnal Weight 

Initial Weight 

Increase 

Final Weight 

Initial Weight 

Increase 

1 ,. 

' Impinger Box No. 

Impinger 1 

Impinger 2 

Impinger 3 

Impinger 4 

Impinger 5 

InVinger 6 

~ -- 

Impinger 7 

Moisture Conteni: 

Fnal Weight ~Z~' s 

Water Weipht Gain 

Impinger 1 3~ • y 

Initial Weight s80.1 

Increase 3$. S/ Impinger 2 

Fnal Weight 6 36 •0 Im in er 3 P 9 D ~ 9 

.~. 

Initial Weight 11.q 

Increase 8 • / Impinger 4 

8, 6 

Fnal Weight g S02= Impinger 5 ----- 

lnitial Weight VI. = 

Increase D• p Impinger 6 

Fnal Weight ~ Impinger 7 

Initial Weight 8' .4 

Increase g . 6 Total 5~ •" V. = 

%COZ 

.~ 

= 0.3 

%02 = /6.6 ., 

-Y.Co 

~ = g/0 ~ 

A. = 00 .~- 

pq = 40. 26 a ~-- 

Tt =7 z ~ 

Z - 0 ?-- 'Hg 

S~/ — 0R 

900 '-- OR 

%M = 93gZ ~ g~ Ma = D. MWd= Z9• 032 MW = Z~- 3S' 

Pb + 13.6 ~1/S9S +~'9 'i~0- /S9 ~ 

Vm~d= 17.65 Vm = 17.65 ~ Z9,.SZ 13.6 D, S~g ctm Tm+ 460 g~ + 460 

Vw9s = 0.0472 x Vw = 0.0472 x S~ • D = 2• ~O y3~ s#t' 

'% Moisture =_ Vwq„ x 100 = 2. 6 y3 x 100 = ~o• ~g ✓ % 

Vm~, + Vw9„ + 

,= 5123.8 x D' 80$ 90U x = -- V ~~6~ 28 3~ ipm 79 ACFM: 770 ~ /Z/, ~19 x zg• 35 

~ SCf M: yZ ~ 90 ✓ 

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Impinger Box No. / 7- - / 

Impinger 1 Fina) Weight ~S~' Z 

Water Weight Gain 

Impinger 1 `7 

Initial Weight ~ 

Incnease Impinger 2 8,0 

Impinger 2 Fnal Weight 6 y7 o Impinger 3 a 0 

Initial Weight 9. 

Increase $. O Impinger 4 

V. = 

Impinger 3 Final Weight 0 g 802 = Impinger 5 

Initial Weight Li g8.0 V. = 

Incnease Z , () Impinger 6 

Impinger 4 Fnal Weight $0?. 3 Impinger 7 

Initial Weight ~Zo 

Increase Total S? ~ Lj` _ v w 

Impinger 5. Fnal Weght pb = Z9 50v%COZ _ 2. 3 ✓ 

Initial Weight V. = q°OZ = /d -S~ 

Increase V. = %C0 = 0, 0 v 

P. = %N2 = g/. 2 ~ 

impinger 6 Fnal Weight Avg AP = D• y/ v A. _ 4/DO / ✓ 

Initial Weight D. = 0• 060 

Incn'ase AvgF = D• 6~Z'' Tt = 7Z ✓ 

Cp = p, 8~(0 ✓ 

Impinger 7 Fnal Weight P. - —O• 00 .,-N0 'Hg 

_ Initial Weight T. _ $3 -~— °F OR 

Incnease ' T.* _ ~~~ ` --°F O/'✓ 'R 

✓ 

Moisture Content: %M Md= o -quy S MWa= Z9• D2 Mw 

Pb + Pm 0.9.3~ ,3 9, 33 9~, 

Vm 17.65 Vm 13.6 _ 17.65 nd = x~/0, 930 Z9, SD 13.6 

Tm+ 460 = D. SS/~ cfm 

$,3 + 460 

Vw9 „ = 0.0472 x Vw = 0.0472 x S~ .~ I = d.4 ri 3 sft' 

% Moisture = _Vwo ,. x 100 L1l3 x 100 

V% + Vwo„ 39. 33 9+`) LI13 

so~ 90/ o.d~z ~r1s x a `

~ 

5123.8 x 0' = fpm ACFM: 

Z9 y? x 

 . SCFM: 

; %l =,.039 x 39..0

9 x 90l _~°~! 

, g ~ o.Citibo x97sa. x z9.

~l;zx 7Z x(o, ?Zo)Z %EA: 3Z8 

D-9 ~~~ 
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D-10 / Y/ 
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millillillillillill, millillaillillillill 

D-11 
, 

Impinger Box No. 

75p, z 

Water Weight Gain 

Impinger 1 Final Weight Impinger 1 

Initial Weight 

Incr+ease Impinger 2 _ 

Impinger 2 Fnal Weight ~~~' y Impinger 3 ).0 ` 

Initial Weight 703 ,0 

Increase Li• 0 Impinger 4 C) 

6gg' 9- 

VM= 

Impinger 3 Fnal Weight g S02= Impinger 5 

Initial Weight 6 $$, ~ 

Increase G• 

V. = 

Impinger 6 

Impinger 4 Fnal Weight O y'O Impinger 7 

Initial Weight Sa y D 

Increase o' O Total V 

M 

Impinger 5 . Fnal Weight S0$• 0 Pb = 90I.4C1 -" %COZ = ' ✓ 

Initial Weight QO 1• 6' V. = _a-g 1 1 ~ %02 

Increase V,r=~_✓ %CO 

P. = O.~ %NZ 

Impinger 6 Fnal Weight Avg AP = - •' A. = y00 ( ✓ 

Initial Weight D. = — -~ 

Increase AvgF _ ` ✓ Tt ra 

CP= — ✓ 

Impinger 7 Final Weight P. _ ' • ,:'@HZO ' 'Hg 

Initial Weight T. _ '1 1. ✓ °F s3 L °R 

~ 

, 

Increase Ts - — 

" ✓°F " °R 

Moisture Content %M = ~• l ~ Ma= 

✓ ~ 

MW, MW = 

P+ 

b Pm 

13.6 + 

q, 

v~ 

3,! c3 

Vm ~,d = 17.65 Vm _ 17.65 xag.~ t~ o~ , c~ 13.~6 

~- 4 = (~ 88 s fm Tm+ 460 7 (, + 460 i 

Vw9IS = 0.0472 x Vw = 0.0472 x sft' 

% Moisture = Vw- x 100 = ~ . g S O x 100 = v% 

vrr4,d + vwo„ a`).9 a 3+ 

V. = 5123.8 x x = f fpm 

 ~ 

ACFM: -' 

x ~ 

SCFM: 

%I = 1,039 x x - % ~ 

x x x x( )Z %EA: 1— 

D-12 

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9. 

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V ~ 

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r~ 

4 

~ 

Impinger Box No. / S. 3 

Water Weiqht Gain 

Impinger 1 Final Weight Impinger 1 ~, r 

Initial Weight 

Increase `~-A~ ~ Impinger 2 aa 

Impinger 2 Fnal Weight G Impinger 3 0• 0 

Initial Weight 

Increase `3 . a Impinger 4 

V. - 

Impinger 3 • Fnal Weight 69 1. ~J g SOZ = Impinger 5 

Initial Weight q V. _ 

Increase 0. U Impinger 6 

Impinger 4 Final Weight 4rign Impinger 7 

Initial Weight `f`7f3• 

Increase 0• U Total ~'1 ~, ~ ~ V 

M 

Impinger 5 . Fnal Weight Pb= .S '' 'kCO2 = - ✓ 

Initial Weight V,°= qlg. '1L( -' %02 

Increase ~ , a V. = %CO 

P, = O SOO ✓ %N2 

~ 

_ 

Impinger 6 Fnal Weight Avg AP = - A. = 

! ' Initial Weight D. = 

Increase Avg aP = ~ ~ T, = ~_✓ 

CP= ~ 

Impinger7 Fnal Weight P, _ " /-HzO ~'Hg 

_ Initial Weight T~ _ ~ ----°F °R 

' Increase T, = V / °F " / °R 

Moisture Content: %M = ~•~~ ~ Ma= r SS`~ MWa= r MW = 

Pm 

Pb+ 13.6 ~3.6 1~

v 

3.~c

3 

Vm~d= 17.65 Vm _ 17.65 x ~q~~4 ,S ± 

p,~ 

~ 

Tm + 460 ~~ 5a+ 460 

Vwa„ = 0.0472 x Vw = 0.0472 x ~! ~• a' = I, cl ~I ~~ sft3 

% Moisture = Vw x 

~ 

100 = ) ~ y S x 100 = y °a 

V~ m, + Vw9„ ~.80~l3 + ) ,C,u5 

V, =`5123.8 x ACFM: y ~ 

- • x 

✓ SCFM: -` ✓ 

%1 = 1,039 x x 

x x x x( )Z %EA: ~ 

D-14 (1~ 
'1 

a 

~ a r 

_ -0 Z 

0 

a 

~ m 

m 

. ~ 

0 Z 

o 

~ ~ o 

p

y 

. 

O O »oc

~ oocn 

^ § E `v 

a~ 

o ~ 

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O LD rL 

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Y 

J 

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Q Q[L li 

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co 

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D-15 fw 
ri 

Impinger Box No. I D -~ 

1~3- O 

Waler Wei

nal 

qht Gain 

Impinger 1 F Weight Impinger 1 

Initial Weight 7 1 3 ~, 

Increase /~01 ,L( Impinger2 

Impinger 2 Fnal•Weight 11 M Impinger 3 

Initial Weight :3A I 

Increase Impinger 4 V. _ 

Impinger 3 Fnal Weight g SOZ= Impinger 5 S, S 

Initial Weight G83 1 V. _ 

Increase 1. ( Impinger 6 ~ 

Impinger 4 Fnal Weight Sd S• I Impinger 7 

Initial Weight 56 ,3 .5 

Increase /1 (o Total 4040 = V. 

Impinger 5 . Fnal Weight /01 Pb= ~°I. %CO2 

Initial Weight 000S Vm= Q.pi,C~1 ~o ~ %02 

Increase $~. S V. - ~aG .0 ✓ x - °kC0 

P. = O..SOO,,, %NZ= J ~ 

Impinger 6 Fnat Weight Avg AP = — ✓ A. = ZIIOU I•✓ 

Initial Weight Dp= `' r/ 

Increase AvgAP = — ~ Ti_ 

CP= 

Impinger 7 Fnal Weight P. = ' /'H20 ~ i'Hg 

1®itial Weight T. = ol °F ~_ ~ °R 

Increase Tf= °F / °R 

D 371 

Moisturre Content: %M = Ma MWa= MW = ✓ 

Pm 

Vm = 17.65 Vm Pb + 13.6 _ 17.65 x q ~ ± 1~ ~$ .~~v

sft3 

~d Tm + 460 ~- .~9(D ~I ~O = ~scfin 

r7 ci + 460 

Vw9„ = 0.0472 x Vw = 0.0472 x 4 b. o _ _ I, , ✓ sft' 

~p , 

% Moisture = Vw-0,. x 100 = ~ . ~00 x 100 = 

f 

% 

V% + Vw9„ 

V, = 5123.8 x x (pm ACFM: ~ 

x 

~ %1 = 1,039 x x 

x x x x( )Z 

D-16 

SCFM: i 

%EA: 

m 
ri ~ ~o 

APPENDIX E 

Analytical Data 

96-30 E-1 

f- 5 
~ 

I4ETCO Environmental 

Particulate Malysis Summary 

m~.1, ' %-- 

• • j~~L ~ ~- / _~/ ~ 

Date Analysis Coarpleted 

Unit Tested 

- ~ 

Run No. 

Particulate on Filter (mg) /~, ~ ~ ,?4, 3 13 , ~ 

P-r— 1+2-0 

Particulate in Front wash (mg 

, , ~ 

, 

1'F (mg) 

Particulate in Impinger * 1 (mg) 

Atr (IDg) I o. I ~ 

RT/ 

. ~Y~ aL~&- , 

~/ 

llnalyst 

le 

• Less Acetone Residue 

E-2 
r'l METCO Environmental 

Particulate Analysis EPA Method S 

Stack Filters 

_ Job Number Location 

Job Name ~ Unit Tested 

Desiccator Time In 530 3//6 

Desiccator Time Out VS Z ~ 

Run No._L Filter No. r 37 

Filter $ Particulate 

+ Tare Weight (g) 

Tare Weight (g) 

F ilter $ Particulate (g) 

Filter & Particulate Average (g) D• S/ 

Initial Filter Weight (g) ,O / ~ 

Total Particulate (mg) ~ 

Run No. Filter No. 

Filter & Particulate 

+ Tare Weight (g) 

Tare Weight (g) ✓ 

Filter & Particulate (g) , 5 p O,S o 

Filter & Particulate Average (g) 

Initial Filter Weight (g) ~ 

Total Particulate (mg) ,3 ~ 

Run No. ~_ Filter No. 

Filter & Particulate 

+ Tare Weight (g) 

Tare Weight (g) ~ 

Filter & Particulate (g) ~~,~ 3g ✓ jJ ,s~~ 

Fi lter $ Particulate Average (g) S a;.38 ~ 

Initial Filter Weight (g) U. 5-1 0 a-- ~ 

Total Particulate (mg) ~ 

, - - 

Analyst 

E-3 1 

A 
~ METCO Environmental 

Particulate Analysis EPA Method S 

~ Stack Filters 

Job Number 740- d Location 

~ Job Name ,/3~~ ,~jl~ Unit Tested 

Desiccator Time In 

Des.iccator Time Out /svl 

Run No. ee& Filter No. 

Filter & Particulate 

+ Tare Weight (g) 

Tare Weight (g) 

~ Filter F, Particulate (g) 

Filter f, Particulate Average (g) Q. S'OS ~ 

Initial Filter Weight (g) Q, ~d ~ 

Total Particulate (mg) 0,3 ~ 

Run No. Filter No. 

Filter & Particulate 

+ Tare Weight (g) 

Tare Weight (g) 

r Filter $ Particulate (g) 

Filter f, Particulate Average (g) 

Initial Filter Weight (g) 

Total Particulate (mg) 

Run No. Filter No. 

Filter F, Particulate 

+ Tare Weight (g) 

Tare Weight (g) 

Filter f, Particulate (g) 

Filter $ Particulate Average (g) 

Initial Filter Weight (g) 

Total Particulate (mg) 

~ 

Analyst 

E-4 m 
~ METCO Environmental 

Particulate Analysis EPA Niethod S 

~ /4 ce0~1~ Front Wash 

~ Job Number ql - Location ~ 

Job Name Unit 

. 

Desiccator Time In L Z. 

Des iccator Time Out / 3ZS ~ gs2 2 Z 1 

Run No. Volume (ml) .2VO 

Final Weight (g) / , ~, j /a , 6J 12 

Initial Weight (g) /a1,, !1,Zg /,2~ ,,/ 2gj 

Particulate Wei ht () 0 , d/d d 10, tO /o02 

Particulate Average (mg) 

Less Acetone Blank (mg) 

Total Particulate (mg) 

Run No. 2 Volume (ml) / 94"o 

Final Wei ht ( ) Ilo Z 3 (o. /A 7 ✓ 

Initial 1Veight (g) ,3! 6S67Y 

Particulate Weight (g) 

Particulate Average (mg) 9, 1-- 

Less Acetone Blank (mg) 

Total Particulate (mg) 

Run No. ~~ Volume (ml) l~ s 

Final Weight (g) lllfZ 

Initial Weight (g) 

Particulate Weight (g) 0~ 2 

Particulate Average (mg) lo• ~ ~ 

Less Acetone Blank (mg) ~ 

Tota1 Particulate (mg) ' 

Acetone Blank Volume (ml) c~50 

Final Weight (g) 3 S 

Initial Iti'eight (g) 1.33L/ 

Di fference (g) A 

Average (mg) /,S ~ 

* mg/ 1 

* Note: If greater than 7.9 mg/1, use 7.9 mg/l. 

~ 

E-S Analyst ~~/ 
0 

~ METCO Environmental 

Particulate Analysis EPA Method S 

Back Half Analysis 

--, Job Number ~ — Q U /1 ~o~tion ~~r ~~ d~~, ~ 

Job Name O-el ~ Unit Tested 

Desiccator Time In 163° 217 Vf LZo 

Desiccator Time Out /3 ay ro 9w zJ 

Run No. Volume (ml) 

Final Weight (g) ~ , g ,f , a a ✓ 

Initial {4eight (g) 

Particulate Weight (g) 

Particulate Average (mg) .3 ~ 

Less Ammonium Sulfate (mg) — 

Total Particulate (mg) ~ 

Run No . A Vo lume (ml ),3.fy t ~ 

Final Weight (g) Okg V 14 If, ~ ✓ 

Initial Weight (g) /W 

Particulate Weight (g) 3 3 

Particulate Average (mg) 

Less Ammonium Sulfate (mg) ~— 

Total Particulate (mg) 

Run No. \.~ Volume (ml) 

Final Weight (g) ~ ~ g' l „~ s ✓ 

Initial Weight (g) Ila 

~ Particulate Weight (g) 

Particulate Average (mg) 

Less Ammonium Sulfate (mg) ~— 

Total Particulate (mg) 

Run No. Volume (ml) 

Final Weight (g) 

Initial Weight (g) 

F Particulate 1Veight (g) 

Particulate Average (mg) 

Less Ammonium Sulfate (mg) 

Total Particulate (mg) 

14 --- 

Analyst £-7 0~ 
HIMEricoErmRonaynTAC 

~ 

~ 

:j 
0 5 10 15 20 

20 

10 

,'11 

uS 

METCO ENVIRONMENTAL 

Datk Rrpr• ~ ~ ccreed Qti 02/28 /199h 14 : 41: 24 

; Sample Name: R1 FILT KILN S'1'ACK 25ML Date: 02/28/10S6 11:07:49 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-280011.D05 ; 

; Method : C:\DX\METHOD\AS10.MET ; 

ACI Address: 1 System: 1 Inject#: 5 Detector:CDM-2 ; 

i; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

----------------------------------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- ' 

: External 1 7022 5Hz 0.00 23.41 4000 

~ 

Component Report: Components Found 

~ Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

4.63 Fluoride 127000714 14276211 2.061 

j ------------------------------------ 

Totals 127000714 14276211 2.061 

n 

11 . File: 2-280011.D05 Sampie: R1 FILT KILN STACK 25ML 

Minutes 

100% 

80% 

60% 

40°,/0 

20% 

0% 

£-9 q~ 
0 5 10 15 20 25 

Minutes 

METCO ENVIRONMENTAL 

Data keprocessed On 02/28/1996 14:42:41 

; Sample Name : R1 DIFW KILN STACK Date : 02/ 2'7/ 1996 12 : 04 : 00 ; 

; Data File : C: \DX\DATA\ANIONS\96-30'\2-270021. DO1 ; 

; Method : C:\DX\METHOD\AS10.MET ; 

ACI Address: 1 System: 1 Inject#: 1 Detector:CDM- ~' ; 

a ; Analyst . Column: AS10 .4mm, AG10 Gaurd Column ; 

----------------------------------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External cP~ S 1 1 13500 5Hz 0.00 25.35 4000 

Component Report: Components Found 

i Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

4.63 Fluoride 238502126 27276624 3.871 

~ ------------------------------------ 

Totals 238502126 27276624 3.871 

I 

~ 

Fle: 2-270021.D01 Sample: R1 DIFW K(LN STACK 

~ 

30 

20 

us 

10 

0 

100% 

m. 

60% 

40% 

20% 

0% 

F-in 
100 

80 

60 

uS 

40 

20 

0 

File: 2-270001.D07 Sample: R1 BH+11 KILN STACK 2X 

120 

0 5 10 15 20 25 

~ 

r4i. 

METCO ENVIFiONMENTAL 

Data Reprocessed On 02/28/1996 14:44:06 

_ ----------------------------------------------------------------------------- 

; Sample Name: R1 BH+I1 kILN STACIi 2X Date: 02/27/1996 17:15:13 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-270001.D07 ; 

; Method : C:\DX\METHOD\A0'10.MET ; 

; ACI Address: 1 System: l In:iect#: 7 Detector:CDM-2 ; 

, Analyst . Column: AS10 ,4mm, AG10 Gaurd Column 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

' -------------------------------------------------------------------- 

External Aoyl 1 7500 5Hz 0.00 25.00 4000 

~ - Component Report: Components Found 

:"A Ret Component Area Height Concentration 

Time Name ppm 

' ------------------------------------------------------------- 

4.63 Fluoride 780813280 80415488 12.673 

:.j ------------------------------------ 

Totals 780813280 80415488 12.673 

~ 

100% 

80% 

60% 

40% 

20% 

0% 

Minutes 

E -11 
100% 

80% 

60% 

40% 

20% 

0% 

Fi1e: 2-280001.D09 Sample: R1 12,3 KILN STACK 

0 5 10 15 20 25 

METCA ENVIRONMENTAL 

Data Reproc:essed On 02/28/1996 14:45:46 

; Sample Name : Ri. 12,3 KILN STACK Date : 02!28/1996 12 : 53: 00 ' 

; Data File : C:\DX\DATA\ANIONS\96=30'\2-2800U1.D09 ; 

; Method : C:\DX\METHOD\AS10_1•1ET 

; ACI Address: 1 System: 1 Inject#: 9 Detector:CDM-2 ; 

; Analyst _ Column: AS10 ,4mm, AG10 Gaurd Column ; 

----------------------------------------------------------------------------- 

----------------------------------------------------------------------------- 

Calibration Volume Dilution F'oints Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 1 7500 5Hz 0:00 25.00 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

-------------------------------------------------- ----------- 

4.63 Fluoride 80158578 9212411 1.301 

------------------------------------ 

Totals 80158578 9212411 1.301 

'1 

30 

20 

uS 

10 

0 

PAin.utes 

E-12 

q51 
0 5 10 15 20 25 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/28/1996 14:53:29 

; Sample Name: R2 FILT KILN STACK 25ML Date: 02/28/1996 11:30 58 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-280001.D06 ; 

; Method : C:\DX"METHOD\AS10.MET ; 

; ACI Address: 1 System: 1 Inject#: 6 Detector:CDM-2 ; 

; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

----------------------------------------------------------------------------- 

----------------------------------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External ;LS 1 1 6021 5Hz 0.00 25.09 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

-------------------------------------------------------------- 

4.63 Fluoride 177207579 19993400 2.876 

------------------------------------ 

Totals 177207579 19993400 2.876 

Fle: 2-280001.D46 Sampie: R2 FILT KILN STACK 25ML 

30 

20 

uS 

10 

0 

Minutes 

E-13 ey 

r-I 

100% 

80% 

60% 

40% 

20% 

0% 
0 5 10 15 20 

us 

20 

40 

Kil 

10 

0 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/28/1996 14:54:37 

; Sample Name: R2 DIFW KILN STACK Date: 02/27/1996 14:45:29 ; 

; Data File : C:\,DX\DATA\ANIONS\96-30\2-'270031.D01 ; 

; Method : C:\DX\METHOD\A0'10.MET ; 

; ACI Address: 1 System: 1 Inject#: 1 Detector:CDM-'-71 ; 

; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

-----------------------------------=----------------------------------------- ----------------------------------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External ~!~"~ 1 1 4500 5Hz 0.00 23.43 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

4.61 Fluoride 223330444 25198928 3.625 

------------------------------------ 

Totals 223330444 25198928 3.625 

9 

file: 2-270031.D01 Sampie: R2 DIF1N K1LtV STACK 

Minutes 

E=14 

100% 

80% 

s0~io 

40% 

20% 

0% 
0 5 10 15 20 

~ 

, 

,-I 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/28/1996 14:56:05 

; Sample Name: R2 DIFW KILN STACK DUP Date: 02!27/1996 15:01:54 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-270001.D02 ; 

; Method : C:\DX\METHOD\AS10.MET ; 

ACI Address: 1 System: 1 In,,iect#: 2 Detector:CDM-2 ; 

!; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

' ----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 1 4500 5Hz 0.00 23_44 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

4.60 Fluoride 224331175 26786242 3.641 

------------------------------------ 

Totals 224331175 25786242 3.641 

m 

File: 2-270001.DQ2 Sample: R2 DiF1N KlLN STACK DUP 

40 

, 30 

20 

uS 

10 

0 

100% 

80% 

SO% 

40% 

20% 

0% 

Minutes 

E-15 + 
100% 

:T~ •. 

60% 

40% 

20% 

0% 

Fle: 2-270001.D08 Sample: R2 BH+19 KlLN STACK 2X 

0 5 10 15 20 25 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/28/1996 14:57:40 

; Sample Name: R2 BH+I1 KILN STACK 2X Date: 02/27/1996 17:41:40 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-270001.D08 

; Method : C:\DX\METHOD\AS10.MET 

 

~ ACI Address: 1' System: 1 Inject#: 8 Detector:CDM-2 ; 

; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

External 35? 1 

-------------------------------------------------------------------- 

1* 7500 5H.:, 0.00 25.00 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

; Time Name 

------------------------------------------------------------- 

ppm 

4.63 Fluoride 

' 

453096413 48626777 

------------------------------------ 

7.354 

Totals 453096413 48626777 7.354 

~ I 

.; 

~ 

100 

80 

60 

uS 40 

20 

0 

Minutes 

F -1 fi 
100% 

80% 

60% 

40% 

20% 

0°0 

0 5 10 15 20 25 

Us 40 

Fle: 2-270001.D09 Sample: R2 BH+11 KILN STACK 2X 

100 

20 

~-X 

: e; 

N 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/28/1996 15:01:01 

; Sample Name: R2 BH+I1 KILN STACK 2X DvP• Date: 02/27/1996 18:08:05 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-270001.D09 ; 

; Method : C:\DX\METHOD\AS10.MET ; 

; ACI Address: 1 System: 1 Inject#: 9 Detector:CDM--', ; 

; Analyst . Coltunn: AS10 ,4mm, AG10 Gaurd Column ; 

----------------------------------------------------------------------------- 

Calibration Volume Dilution Points 

-------------------------------------------------------------------- 

Rate Start Stop Area Reject 

External 1 1 7500 5Hz 0.00 25.00 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name 

------------------------------------------------------------- 

ppm 

4.63 Fluoride 455057069 48676116 

------------------------------------ 

7.386 

Totals 455057069 48676116 7.386 

Minutes 

E-17 ~D 

'1 
File: 2-280001.D11 Sample: R2 12,3 KILN STACK 

14 

12 

10 

$ 

6 

uS 4 

2 

0 

-2 

-4 

100% 

$0% 

60% 

40% 

20% 

0% 

0 5 10 15 20 25 

.1 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/28/1996 15:09:27 

; Sample Name: R2 I2,3 KILN STACK Date: 02/28/1996 13:47:06 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-280001.U11 ; 

; Method : C:'\DX\METHOD\AS10.11ET ; 

; ACI Address: 1 System: 1 In,,iect#: 11 Uetector:CUM-2 ; 

; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

External -10`1 1 

-------------------------------------------------------------------- 

1 7500 5Hz 0.00 25.00 4000 

********************** Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name 

----------=-------------------------------------------------- 

ppm 

4.64 Fluoride 

, 65909582 7924593 1.070 

' Totals 65909582 

------------------------------------ 

7924593 1.070 

0 

Minutes 

E-18 

a

~ 
017 

PZI7 

100% 

$0% 

60% 

40% 

20% 

0% 

uS 10 

n 

-10 

File: 2-280001.D07 Sample: R3 FILT KILN STACK 25ML 

n 

~ 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/28/1996 15:13:41 

; . Sample Name: R3 FILT KILN STACK 25ML Date: 02/28/1996 11:54:24 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-280001.D07 ; 

Method : C:\DX\METHOD\AS10.MET ; 

ACI Address: 1 System: 1 Inject#: 7 Detector:CDM-2 ; 

; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

:+ Calibration Volume Dilution Points Rate .Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 1 6000 5Hz 0.00 9_89 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------- ---------------------------------------- --------- 

~ 4.61 Fluoride 114010185 12831945 1.851 

------------------------------------ 

Totals 114010185 12831945 1.851 

~ 

0 1 2 3 4 5 6 7 8 9 

Minutes 

E-19 IA 
100% 

80% 

60% 

40% 

20% 

0% 

File: 2-270001.D03 Sample: R3 DIFVY KILN STACK 

0 5 10 15 20 25 

~ 

~ 

IIETCO ENVIRONMENTAL 

Data Reprocessed On 02/28/1996 15:18:19 

; Sample Name: R3 DIFW KILN STACK Date: 02/27/1996 15:23:21 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2- '70001.D03 ; 

; Method : C:\DX\METHOD\A'SlO.MET 

; ACI Address: 1 System: 1 Inject#: 3 Detector:CDM-2 ; 

Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

----------------------------------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

External 

-------------------------------------------------------------------- 

1 6000 5Hz 0.00 25.00 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name 

------------------------------------------------------------- 

ppm 

4.61 Fluoride 

j ------------------------------------ 

244031574 27952445 3.961 

Totals 244031574 27952445 3.961 

60 

50 

40 

30 

uS 

20 

10 

0 

-10 

Minutes 

E-20 /

a/ 
0 5 10 15 20 25 

30 

uS 

20 

10 

60 

50 

rsliei 

0 

-10 

METCU ENvIRUNMENTAL 

Data Reprocessed Un 02/28/1996 15:19:58 

; Sample Name: R3 DUP DIFW KILN STACK Date: 02/27/1996 15:44:48 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-270001.D04 ; 

; Method : C:\DX\METHOD\AS10.MET ; 

; ACI Address: 1 System: 1 Inject#: 4 Detector:Cl?M--' ; 

; Analyst . Column: AS10 .4mm. AG10 Gaurd Column ; 

Calibration Volume Dilution Points Rate Start C-itop Area Re,,iect 

-------------------------------------------------------------------- 

External 1 1 6000 5H.: 0.00 25.00 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

.- Time Name ppm 

------------------------------------------------------------- 

4.60 Fluoride 245658097 27994352 3.987 

I ------------------------------------ 

Totals 245658097 27994352 3.987 

~ 

~ 

; 

Fle: 2-270001.D04 Sample: R3 DUP DIFW KILN STACK 

Minutes 

100°,% 

$Oo,~o 

60% 

40% 

20% 

0% 

E-Z1 ) DA 
100% 

80o~a 

s0°io 

40% 

20% 

0% 

File: 2-270001.D10 Sampie: R3 BH+11 KILN STACK 2X 

0 5 10 15 20 25 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/28/1996 15:21:26 

; Sample Name: R3 BH+I1 KILN STACK 2X Date: 02!27/1996 18:34:26 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-270001.D10 ; 

; Method : C:\DX\METHOD\AS10.MET ; 

; ACI Address: 1 System: 1 Inject#: 10 Detector:CDM-2 ; 

Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

----------------------------------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 7500 5Hz 0.00 25.00 4000 

Component Report: Components Found 

Ret Component _ Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

4.63 Fluoride 720486248 72745516 11.694 

~ ------------------------------------ 

Totals 720486248 72745516 11.694 

~ 

120 

100 

80 

s0 

us 

40 

20 

0 

-20 

Minutes 

E-22 /P ° 
100% 

80% 

60% 

40% 

20% 

0% 

Fie: 2-270001.D11 Sample: R3 BH+11 KILN STACK 2X DUP 

0 5 10 15 20 25 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/28/1996 15:23:54 

; Sample Name: R3 BH+I1 KILN STACK 2X DUP Date: 02/27/1996 19:00:51 ; 

; Data File : C:\DY,\DATA\ANIONS\96-30\2-270001.D11 ; 

; Method : C:\DX\METHOD\AS10_MET ; 

; ACI Address: 1 System: 1 Inject#: 11 Detector:CDM-2 ; 

Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

Calibration Volume Dilution Points 

-------------------------------------------------------------------- 

Rate Start Stop Area Reject 

External 1 

. 

1 7500 5H.: 0.00 25.00 4000 

~ 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name 

------------------------------------------------------------- 

ppm 

4.64 Fluoride 728918167 73301938 

------------------------------------ 

11.831 

Totals 728918167 73301938 11.831 

~ 

100 

80 

60 

uS 40 

20 

0 

Minutes 

E-23 

!p~ 
20 

uS 10 

~ 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/28/1996 15:25:51 

; Sample Name: R3 I2,3 KILN STACK Date: 02/28/1996 14:13:32 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2- '-:'80001.D1 ~' ; 

; Method : C:\DX\METHOD\AS10.MET ; 

; ACI Address: 1 System: 1 Injecttt: 12 Detector:CDM-2 ; 

; Analyst . Column: AS10 .4mm. AG10 Gaurd Column ; 

-----------------------=----------------------------------------------------- ----------------------------------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

Externai 4000 

Component Report: Components Found 

~ 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

4.63 Fluoride 92077963 10534162 1.495 

j ------------------------------------ 

Totals 92077963 10534162 1.495 

Fie: 2-280001.D12 Sampie: R312,3 KILN STACK 100% 

80% 

60% 

40% 

20% 

0% 

0 5 10 15 20 25 

Minutes 

E-24 ~~r 
100% 

80% 

60% 

40% 

20% 

0% 

Fle: 2-280001.D01 Sample: R3 12,3 KILN STACK DUP 

0 5 10 15 20 25 30 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/28/1996 15:28:00 

; Sample Name: R3 I2,3 KILN STACK DUP Date: 02/28/1996 14:39:33 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-280001.D01 ; 

; Method : C: \DX\METHOD\AS10. MET 

; ACI Address: 1 System: 1 Inject#: 1 Detector:CDM-2 ; 

; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 1 5928 5Hz 0.00 30.87 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

---------------------------------------------------------- 

4.63 Fluoride 91038351 10500850 1.478 

------------------------------------ 

Totals 91038351 10500850 1.478 

~ 

~ 

20 

10 

uS 

0 

Minutes 

Ib~ 

F-25 
100°,% 

80% 

60% 

40% 

20% 

0% 

120 

100 

80 

uS 60 

40 

20 

0 

File: 2-280001.D03 Sample: CCV 20 PPM F STD 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/28/1996 09:56:24 

- - ---------- 

; Sample Name: CCV 20 PPM F STD Date: 02/28/1996 09:46:29 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-280001.D03 ; 

; Method 

; ACI Address: 1 System: 1 Inject#: 3 

: C:\DX\METHOD\AS10.MET 

Detector:CDM-2 ; 

; Analyst . Column: AS10 ,4mm. AG10 Gaurd Column ; 

Calibration Volume Dilution Points 

-------------------------------------------------------------------- 

Rate Start Stop Area Reject 

External 1 1 6924 5Hz 0.00 28.85 4000 

********************** Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name 

------------------------------------------------------------- 

ppm 

4_56 Fluoride 1240303639 83011754 

------------------------------------ 

20.131 

Totals 1240303639 83011754 20.131 

~ 

`1 

0 5 10 15 20 25 

Minutes 

£-26 /D ` 
0 5 10 15 20 

W Fle: 2-280001.D02 Sample: CCV 5 PPM F STD 

40 

Kil 

uS 

20 

10 

X 

100% 

80% 

60°l0 

40°./0 

20% 

0% 

METCO ENVIRONMENTAL 

; Sample Name: CCV 5 PPM F STD Date: 02/28/1996 08:43:10 ; 

; Data File : C:\DX\DATA\ANIONS\.96-30\2-280001.D02 ; 

; Method : C:\DX\METHOD\AS10.MET ; 

; ACI Address: 1 System: 1 In,iect#: Detector:CDM-2 ; 

; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

----------------------------------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 1 7212 5Hz 0.00 ~~ 4.04 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

4.53 Fluoride 315690440 23811816 5.124 

------------------------------------ 

Totals 315690440 23811816 5.124 

Minutes 

E-27 l~ ~ 
0 5 10 15 20 

ri ~ 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/28/1996 16:21:14 

; Sample Name: BL FILT KILN STACK 25ML Date: 02/28/1996 10:39:39 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-280001.D05 ; 

; Method : C:\DX\METHOD\AS10.MET ; 

; ACI Address: 1 System: 1 Inject#: 5 Detector:CDM-2 ; 

; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 1 7183 5Hz 0.00 23.94. 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

4.63 Fluoride 20691457 2396176 0.336 

------------------------------------ 

Totals 20691457 2396176 0.33E 

$ Q F+le: 2-280001.D05 Sampie: BL FILT KILN STACK 25ML 

7.0 

6.0 

5.0 

4.0 

uS 3.0 

2.0 

1.0 

0.0 

-1.0 

-2.0 

I 

100% 

80% 

60% 

40°,/0 

20% 

0% 

Minutes 

E-28 
ri 

p- 

~jf1lETCQ ~ 

~ 

~ ~ ~ J = ~ O ~ ~ 

Z ~ O ~ 

L 

CD 

m 

L ~ CL 

co Cb 0 

C N N E Y o fl. 

Q 

~ ~ U 

~ 0 V0 E 

U a Tt~ 

~ 

~t; Co cv, 

U— T T T 

5 LO m LaI 

U E 0 °~y~' o 

~ > m W T 

X 

1~ 

U 0 

L M W 

O O O 

~ m = U U U 

o I- o z z ;_, z 

m w cis 

O U J cc_ 

E-29 

ilI) 
20 

uS 

10 

0 

0 

100% 

a0% 

60% 

40% 

20% 

0% 

File: 2-270041.D01 Sampie: R1 COMP KILN INLET 50X 

0 5 10 15 20 25 

yETCO ENVIRONMENTAL 

Data Reprocessed On 02/29/1996 08:29:51 

; Sample Name: R1 COMP KILN INLET 50X Date: 02/28/1996 15:30:48 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-270041.D01 ; 

; Method : C:\DX\METHOD\ASlO.MET ~ 

; ACI Address: 1 System: 1 In,iect#: 1 Detector:CDM-2 ; 

; Analyst . Column: ASIO ,4mm. AG10 Gaurd Column ; 

----------------------------------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 1 6563 5Hz 0.00 27.34 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

4.63 Fluoride 105566240 11498220 1.713 

------------------------------------ 

Totals 105566240 11498220 1.713 

~ 

Minutes 

E-30 
0 5 10 15 20 25 

20 

uS 10 

L 

A?ETIC'0 ENV?RONMENTAL 

Data Reprocessed On 02/29/1996 08:31:21 

; Sample Name: R2 CUMP KILN INLET 50X Date: 02!2'8/1996 15:59:38 ; 

; Data File : C: \DX\DATA\ANIC)NS'\96-30\': ~*-27()041.DO' ; 

; Method : C:\DX\METHOD\AS10.MET 

; ACI Address: 1 Svstem: 1 Inject#t: Detector:CI7M- ~- ; 

; Analyst . Column: AS10 .4mm, AG10 Vaurd Column ; 

----------------------------------------------------------------------------- 

Calibration Volume Dilution F'oints 

-------------------------------------------------------------------- 

Rate Start Stop Area Reject 

External 1 1 7500 5Hz 0.00 25.00 4000 

Component Report: Components Found 

F{et Component Area Height Concentration 

Time Name 

------------------------------------------------------------- 

ppm 

4.63 Fluoride 92205429 9790170 

------------------------------------ 

1.497 

Totals 92205429 9790170 1.497 

~ 

.... i 

File: 2-270041.D02 Sample: R2 COMP KlLN INLET 50X 

N-tinutes 

100% 

80% 

60% 

40% 

20% 

0°0 

E-31 1/P 
0 5 10 15 20 

20 

uS 10 

02 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/29/1996 08:32:30 

; Sample Name: R3 COMP KILN INLET 50X Date: 02!28/1996 16:29:08 ; 

; Data File : C:\DX'\DATA\ANIONS\96-30\:.'-270041.D03 

; Method : C:\DX\METHOD\AS10.MET ~ ACI Address: 1 System: 1 Inject#: Detector:CDM-2 ' 

Analyst . Column: AS10 ,4mm. AG10 Gaurd Column ; 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

External 1 1 

-------------------------------------------------------------------- 

4341 5H:, 0.00 22.61 4000 

~ 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

4.63 Fluoride 77947036 8572066 1.265 

------------------------------------ 

Totals 77947036 8572066 1.265 

~ 

Fle: 2-270041.D03 Sample: R3 COMP KILN INLET 50X 

Minutes 

100% 

80% 

60% 

40% 

20% 

0% 

E-32 / /,-$ 
'-] 

--, 

METCO ENVIFcONI•iENTAL 

Data Reprocessed On 02/28/1996 16:57:12 

; Sample Name: DI BLNK Date: 02/28/1996 16:56:13 ; 

; Data File : C:\DX\DATA\ANICNS\96-30\2-270041.D04 ; 

; Method : C:\DX\i1ETHOD\AS10.MET ; 

; ACI Address: 1 System: 1 In,ject#: 4 Detector:CDM-2 ; 

; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

----------------------------------------------------------------------------- 

----------------------------------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

- -------------------------------------------------------------------- 

External 1 1 5928 5Hz 0.00 19.76 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

------------------------------------ 

1 Totals 0 0 0.000 

~ Fle: 2-270041.D04 Sample: DI BLiVK 

80% 

60% 

40% 

-2.0 

20% 

-3.0 

-4.0 

0 2 4 6 8 10 12 14 16 18 

Minutes 

3.0 

2.0 

1.0 

0.0 

us 

-1.0 

100% 

0% 

E-33 
METCO ENVIRONMENTAL 

Data Reprocessed On 02/29/1996 09:29:17 

; Sample Name: 0.5 PPM F STD Date: 02/27/1996 08:50:48 ; 

; Data File : C:\.DX\DATA\ANIONS\96-30\2-270011.D01 ; 

; Method : C:\DX\METHOD\AS10_MET ; 

; ACI Address: 1 System: 1 Inject#: 1 Detector:CDM-2 ; 

; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 1 3424 5Hz 0.00 27.84 4000 

Component Fceport: Components Found 

ket Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

4.63 Fluoride 31579803 3407651 0.513 

~ ---------------------------------=-- 

' Totals 31579803 3407651 0.513 

0 

ri 

File: 2-270011. D01 Sample: 0.5 PPM F STD 

100% 

80% 

60% 

40% 

20% 

0% 

14 

12 

10 

8 

6 

uS 4 

2 

0 

-2 

-4 

0 5 10 15 20 25 

Minutes 

E-34 
100% 

80% 

60% 

40% 

20% 

0% 

File: 2-270011. D02 Sample: 1 PPM F STD 

0 5 10 15 20 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/29/1996 09:30:21 

; Sample Name: 1 PF'M F STD Date: 02!27/1996 09:09:47 ; 

; Data File : C:\DX\DATA ",ANIONS\96-30\ ~'-270011.D02 ; 

; Method : C:\DX\t•lETHUD\AS10.MET ; 

; ACI Address: 1 System: 1 Inject#: 2 Detector:CDM-2 ; 

; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

----------------------------------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 1 *4582 5H.; 0.00 23.86 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

4.61 Fluoride 61266312 6993680 0.994 

------------------------------------ 

Totals 61266312 6993680 0.994 

n 

~ 

20 

10 

uS 

0 

Minutes 

E-3S 

~ 1

(P 
uS 10 

-i0 

0 

20 

30 Pile: 2-270001.D01 Sample: 2.5 PPM F STD 

Lel 

2 4 6 0 10 12 14 16 

Minutes 

100% 

40% 

80°,~0 

60% 

20°ro 

0°% 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/29/1996 09:24:34 

; Sample Name: 2.5 PPM F STD Date: 02/27/1996 08:33:50 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-270001.D01 ; 

; ACI Address: 1 System:.l Inject#: 1 

; Method : C:\DX\METHOD\AS10-MET 

Detector:CDM-2 ; 

; Analvst . Column: AS10 ,4mm. AG10 Gaurd Column ; 

Calibration Volume 

-------------------------------------------------------------------- 

Dilution Points Rate Start Stop Area Reject 

External 1 1 3860 5Hz 0.00 16.08 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name 

----------------------------------------=-------------------- 

ppm 

4.59 Fluoride 154627245 16083647 

------------------------------------ 

2.510 

Totals 154627245 16083647 2.510 

—i 

~ 

E-3b 
~ 

n 

~ 

~^ METCO ENVIRONMENTAL r~--: 

Data Reprocessed On 02/29/1996 09:40:28 

----------------------------------------------------------------------------- -------------------------------------------------- 

~ 

--------------------------- 

Sample Name: 5 PPM F STD Date: 02/27/1996 09:22 : 37 , 

; Data File : C:\DX\DATA\ANIONS\96-30\2-270011.D03 ; 

; Method : C:\DX\METHOD\AS10.MET ; 

ACI Address: 1 System: 1 Inject#: 3 Detector:CDM-2 ; 

; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

----------------------------------------------------------------------------- 

~ Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

_ External 1 1 2804 5Hz 0.00 28.52 4000 

Component Report: Components Found 

y Ret Component Area Height Concentration 

p}; Time Name ppm 

------------------------------------------------------------- 

4.55 Fluoride 312887144 23888614 5.078 

- --------------------------------- 

- Totals 312887144 23888614 5_078 

Fle: 2-270011.D03 Sampie: 5 PPM F STD 

50 

40 

30 

~:. 

~ 20 

uS 

10 

0 

-10 

0 5 10 15 20 25 

Minutes 

100% 

80% 

60% 

40% 

20°l0 

0°fo 

t E-37 ~1~ 
0 5 10 15 20 25 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/29/1996 09:44:24 

; Sample Name: 10 PPM F STD Date: 02/27/1996 09:51:52 ; 

' Data File : C:\DX\DATA\ANIONS\96-30\2-270011.D04 

; Method : C:\DX\METHOD\AS10.MET 

 

; 

; ACI Address: 1 System: 1 Inject#: 4 Detector:CDM-2 ; 

; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

External 1 

----------------------------_---------------------------------------- 

1 7587 5Hz 0.00 25.29 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name 

----------------------------------------------=-------------- 

ppm 

4.55 Fluoride 620860998 44789113 10.077 

Totals 620860998 44789113 10.077 

~ 

File: 2-270011.D04 Sampie: 10 PPM F STD 

100 

80 

eo 

uS 40 

20 

0 

Minutes 

n 

100% 

80% 

60% 

40°b 

20% 

0% 

E-38 ~r ~ 
100% 

80% 

60°l0 

40% 

20% 

O% 

120 

100 

80 

60 

uS 

40 

20 

0 

File: 2-270011.D05 Sample: 15 PPM F STD 

METCO ENVIRONMENTAL 

Data Reprocessed On 02/29/1996 09:46:19 

; Sample Name: 15 PPM F STD Date: 02/27/1996 10:23:11 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-270011.I}05 ; 

; Method : C:\DX\METHOD\AS10.MET ; 

; ACI Address: 1 System: 1 Inject#: 5 Detector:CDM-2 ; 

; Analyst . Column: AS10 .4mm, AG10 Gaurd Column ; 

----------------------------------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject' 

-------------------------------------------------------------------- 

External 1 1 8399 5Hz 0.00 28.00 4000 

Comporritt Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

----------------------------------------------=-------------- 

4.56 Fluoride 915268612 68981260 14.856 

~ ------------------------------------ 

~ Totals 915268612 68981260 14.856 

q 

0 5 10 15 20 25 

Minutes 

E-39 /9 
Fle: 2-270011.D06 Sample: 20 PPM F STD 

100% 

80% 

120 

100 

80 

60 

uS 

40 

20 

0 

60% 

40% 

20% 

0% 

0 

t1ETC0 Et•]VIRONMENTAL 

Data Reprocessed On 02/29/1996 09:48:53 

; Sample Name: 20 PPM F STD Date: 02/27/1996 11:03:59 ; 

; Data File : C:\DX\DATA\ANIONS\96-30\2-270011.D06 ; 

; Method : C:\DX\METH0D\AS10.MET ; 

; ACI Address: 1 System: 1 Inject#: 6 Detector:CDM-2 ; 

; Analyst . Column: 

----------------------------------------------------------------------------- 

----------------------------------------------------------------------------- 

AS10 ,4mm, AG10 Gaurd Column ; 

Calibration Volume Dilution Points 

-----------------------=-------------------------------------------- 

Rate Start Stop Area Reject 

External 1 1 11375 5Hz 0.00 37.92 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name 

------------------------------------------------------------- 

ppm 

4.56 Fluoride 1229176911 83261058 

------------------------------------ 

19.951 

Totals 1229176911 83261058 19.951 

ri 

0 5 10 15 20 25 30 35 

Minutes 

E-40 4/ 
File: 2-280001.D03 Sample: CCV 20 PPM F STD 

140 100% 

80% 

60% 

40% 

✓ 

20% 

0% 

120 

100 

80 

uS 60 

40 

20 

0 

-20 

METCO ENITIRONMENTAL 

Data Reprocessed On 02!29!1996 09:50:24 

; Sample Name: CCV 20 PPM F STD Date: 02!28i1996 09:46:29 

' Data File : C:\DX\DATA\ANIONS\96-30\2'-2S0001.D03 

; Method 

; ACI Address: 1 System: 1 Inject#: 3 

: C:\DX\METHOD\AS10.MET 

Detector:CDM-2 ; 

; Analyst . Column: AS10 ,4mm, AG10 Gaurd Column ; 

Calibration Volume 

-------------------------------------------------------------------- 

Dilution Points Rate Start Stop Area Reject 

, External 1 1 6924 5Hz 0.00 28.85 4000 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name 

------------------------------------------------------------- 

ppm 

4.56 Fluoride 

~ 

1240303639 83011754 20.131 

~ Totals 1240303639 

------------------------------------ 

83011754 20.131 

I 

n 

..J 

0 5 10 15 20 25 

Minutes 

E-41 )a9- 
m;~m 

--I 

Bw 

APPENDIX F 

Reference Method Monitor Data 

96-30 F-1 

0-~) -~ 
~ mErco 
~ E?lm

~~co. 
ll~ax : o' J °O PP`Y' 

96 030 

MRF:L PF:ICKS 1 

~ F{ENDEfiSON TEXAS S1N 105 ~ ~tqy a9 • a8~ 

KILN SCRUABER STACK 

Page 

~ raoX Q ,1, m~.-~ ;a., jr ro~ Ch«j~ ~ C~ 

~ FF,4 

02/15/96 07:12 -0.1C 

02/15/96 

02/I5/96 

07:13 

07:14 

O.00 

O.oc 9(,° 16 1113ALG 

02/i5/96 07:15 O.00 

02/15/96 07:16 44.8C 

~ 02/15/96 07:17 57.3C . 

i 02/15/96 07:18 77.9C 

 02/15/96 07:19 86.1C 

02/15/96 07:20 86.6C 

02/15/96 

02/15/96 

07:21 

07:22 

86 .Ar. 

ab.zc gG• ~ ~^' 

No Cy ~~ hLmO 3$163 

02/15/96 07:23 86.5C 

02/15/96 07:24 86.5C 

~ 02/15/96 - 07:25 86.00 

02/15/96 07:26 86.1C 

.02/15/96 07:27 57.6C 

02/15%96 07:28 28.1C 

j 02/15/96 07:29 46.3C 

•_ 1•ifr.15 (~b G~f ~~ ~ I}~ 1 S81 ' 02/15/96 07:31 46.1C PPn► 

I 02/15/96 07:32 : 46.IC 

02/15/96 07:33 25.3C 

02/15/96 07:34 11.5C 

~ 02/15496 07:35 18.2C 

02/15/96 07:36 18.7C 

02/ 15/96 07:37 1q - 7r ,~ aMO 4 0 839 C~ ` L 

02/15/96 07: 38 i s~ 7C J a,'~~ QP m ~ 

02/ 15/96 07:39 18.7C 

02/1,/.96 07: 40 10. iC 

02/W96 07:41 0.2C 

02/15/96 07:42 O.IC 

02/15/96 07:44 26.2C 

02/15/96 07:45 26.2C 

0.2/15/96 07:46 26.2C 

02/15/96 07:47 26.2C 

02/15/96 07:48 26.2C 

02/15/96 07:49 26.2C 

02/15/96 07:50 26.2C 

02/15/96 07:51 26.2C 

02/15/96 07:52 26.2C 

02/15/96 07:53 26.2C 

02/15/96 07:54. 26.2C 

02%15/96 07:55 26.2C 

02%15/96 07:56 26.2C 
~ 

' 96 0 ~ 0 

FORAL PRICfCS 

HENDERSON TEXAS 

KILN SCRUBfiER STACK 

i'age . 2 

Nox 

FFM 

02/15/96 07:57 26.2C 

02/15/96 07:58 26.1C 

02/15/96 07:59 26.1C 

02/15/96 08:00 26.IC 

02/15/96 08:01 26.1C 

02/15/96 08:02 26.1C 

02/15/96 08:03 26.1C 

02/15/96 08:04 26.IC 

02/15/96 08:05 26.1C 

02/15/96 08:06 26.1C 

02/15/96 08:07 26.IC 

02/15/96 08:08 26.1C 

02/15/96 08:09 26.IC 

02/15/96 •08:10 26.1C 

02/15/96 08:11 26.IC 

02/15/96 08:12 26.1C 

02/15/96 08:13 26.IC 

02/15/96 ' 08:14 26.00 /f/Ct eD~l~' Ce02/15/96 08:15 26.00 

02/15/96 08:16 22.6C 

02/15/96 08:17 0.5C 

02/15/96 08:18 .0.8C 

02%15/96 08:19, 0.6C 

02/15/96 -- 08:20 0.5C Z er0 N7 

02/15/96 08:21 0.5C 

02/15/96 08:22 20.3C 

02/15/96 08:23 43.2C 

02/15/96 08:24 44.1C 

02/15/96 08:25 44.IC 

02/15/96 08:26 144.1C y(o.s$ NC) 8/1-Wele, 

02115/96 08:27 44.1C 

02/15/96 08:28 26.2C 

02115/96 08:29 1.7C 

02/15/96 08:30 2.2C 

02/15/96 08:31 0.8C 

02/15/96 08:32 0.3C 

02/15/96= 08:33 6.2C 

02115/96 08:34 22.1C 

02/15/96 08:35 23.1C 

AVERAGES : 29.4 

, 

Bicas Gl.eok 

• . `\~~ . ., ' - .. F_ ~5 
~ 

, 

-a 

~ 

Auxiliary Average Report 

DCNID : 07 Site Name : KILN STK Aux Interval : 1 Date : 2/15/96 

-------- --- ---------------------------------------------------- 

NOX 

Time F'F'M # ~ 

-----------------------------------------------------------------------k-(I-a ----------------- 

08:52 23.2000 

08:53 22.9000 

08:54 22.9000 

08:55 23.1000 

08:56 22.9000 

08:57 22.6000 

08:58 22.7000 

08:59 22.8000 

09:00 23.0000 

09:01 23.1000 

09:02 22.8000 

09:03 22.8000 

09:04 22.9000 

09:05 23.0000 

09:06 23.1000 

09:07 23.1000 

09:08 23.1000 

09:09 23.1000 

09:10 23.1000 

09:11 23.1000 

09:12 23.1000 

09:13 23.0000 

09:14 23.1000 

09:15= .23.0000 

09:16 22.4000 

09:17 21.9000 

09:18 21.8000 

09:19 22.4000 

09:20 22.7000 

09:21 22.8000 

09:22 22.9000 

09:23 23.1000 

09:24 23.2000 

09:25 23.2000 - 

09:26 23.1000 

09:27 23.0000 

09:28 23.2000 

09:29 23.1000 

09:30 23.0000 

09:31 22.8000 

09:32 22.9000 

09:33 23.1000 

09:34 23.2000 

09:35 23.2000 

09:36 23.1000 

09:37 22.9000 

09:38.. 23.0000 

09:39 ... 23.0000 ~ 

09:40..:. ° = 23.2000. 

09:41 '' =23.1000 ` 

09e.42:

.. ~..22:9000 ; _ 

09:43 • 22:9000 F=6 I ~(~ 
~ 

..1 

09:46 23.1000 

09:47 23.1000 

09:48 23.2000 

09:49 23.2000 

09:50 23.2000 

09:51 22.7000 

09:52 22.0000 

09:53 21.7000 

09:54 22.4000 

09:55 22.6000 

09:56 22.8000 

09:57 23.0000 

09:58 23.2000 

09:59 23.1000 

10:00 23.2000 

10:01 23.2000 

10:02 23.2000 

10:03 23.3000 

10:04 23.4000 

10:05 23.2000 

MAX . 23.4000 

MIN . 21.7000 

AUG . 22.9392 

SCANS: 74 

R 
iURAL PRICKS 

;!;EN'Ll-ERcNN TUA; ec 

Wax 

'02/15/96 it) .1 .3r C.I. Ar 

2 15 6 1 0 1 4 Z-t c 6 

0 2 15 ,- 9 10: 15 5C 

02/15/96 10: 16 :1. . 2C 

)2/15/9- ic- - 17 3--1 . ac 

02/15/ ~ 6 10: 18 43. . FIC 

02/15/96 10: 10 44. 2C 

02/15/96 10 -. 2c). 44 : 4C 

02/.15/96 10:21 A/0 

02/15/96 10:22 44.; 5C 

IrV 

'ri 1W 

ZrT. 

'A* 

X, • ZI ,

f,7. 
;I 

.i 

' 96 030 

E+ORAL PRICKS 

HENDERSON TEXAS 

i KILN SCRUBBER STACK 

Page : 1 

91 0.s 

Qun 3 

NOX 

PPM 

02/15/96 14:07 

02/15/96 14:08 

02/15/96 14:09 

02/15/96 14:10 

02/15/96 14:11 

02/15/96 14:12 

02/15/96 14:13 

02/15/96 14:14 

02/15/96 14:15 

02/15/96 14:16 

02/15/96 14:17 

02/15/96 •14:18 

AVERAGES 

0.5C 

0.5C 

0.4C 

O.ar 

o.5c N, 

1.0C 

8.4C 

39.0C 

44.IC 

44.5C ~~ 

44.7C y 

~ 

~•~s ~ 

44.7C 

19.1 

a 
E?lrr~~ 

rco 

APPENDIX G 

U Chain of Custody 

96-30 G-1 

--I 
n_- 

r, : . 

i 1 

E?IMEM0. 

CHAIN OF CUSTODY 

Job # 96 ~ 3O Date 

Client 432:20W Method 5~13e 

Locationy~-~~°s~- ~ Project Mgr. 

Unit 

Number of Absorb. Initial 

Containers Solution Volume p~, 3D2 ,Q, S Other Anatyses 

Filter Cont. ~~ X' Q(JAZrZ ~ ~F 

Front Wash 

Back Wash -1// ~r '~'~-'E ' ✓ f/F 

Impinger 1 

Impinger 2 

Impinger 3 

Impinger 4 Sil. 6Q. 

Impinger 5 

Blank 1 ~ ~• _ 

Bfank 2 

NOx 

Other 

Special Instructions: 

Run # ~ Recov. by • /~"//~ Date Time 11-30 Location a 1 7 

Run # Z Recov. by i Date Z/S 6 Time/2-529Location 

Run # -~ Recov. by r~ . / Date Z/j 96 Time 1y30 Location 1,44let) I'F 

Run # Recov. by A Date Time Location 

Samples Rcvd. by 4;il or transport. 

4TIme 

 Time /~~d

Sample Rcvd. at lab Date

Sample Analyzed by — Date Time D 9/s 

Sample Analyzed by ~~ Date 

~ 

a Time ~ 

Data Checked by .G , I DatejT--T-(Z Time 

G-2 

/iS ~7 
Run # ~ Recov. by 

Run # 2 Recov. by 

Run # -3 Recov. by 

Run # Recov. by 

Date Tme 1134") Location /A*/--,O 

Date Time 12 S 0 Location /4~~e 

Date Z 5 9 lime/y30Location 15410-ka l;z' 

Date Time Location 

mErco 

CHAIN OF CUSTODY 

r Job # ~6'3o Date 

Client Method ~3 8 

Location 77' Project Mgr. e4. 

Unit ~f%~,~/ 5'1.e~3BE•~ i•t/CET 

FA 

Number of Absorb. Initial 

Qonners Solution yolume pML SQz 2% Other Analvses 

Fifter Cont. 

Front Wash 

Back Was b•s e~~/SE 

Impinger 1 

_ <., Impinger 2 D y • ~~'f 

Impinger 3 D -Z• Za~"` ~ 

Impinger 4 

Impinger 5 <5'/L• G~ 

Blank 1 

~ Blank 2 

NOx 

Other 

r'- 

,. . Special Instructions: 

~ 

Fli 

Samples Rcvd. by ~ For transport. Date ~~''~96Time 

Sample Rcvd. at I by ate me 

Sample Analyzed by ~Date a a Q(i Time ~ 

Sample Analyzed by Date Tme 

Data Checked by `~~ ~ Date Zl G Time b S 

G-3 
~ MEFCO

004. 

EmpccfnEmAL 

r; 

APPENDIX H 

Resumes of Test Personnel 

96-30 H-1 

/~~~ 
11 

~ CO."10-. 

BILLY J. MULLINS, JR., President 

Education Post Graduate Study Environmental Engineering at 

Southern Methodist University, Dallas, Texas 1970. 

M.S. 1969, New York University, New York, New York, 

in Civil Engineering (Air Resources). 

B.S. 1968, Texas Tech University, Lubbock, Texas, in Civil 

Engineering (Water Resources). Studies in Engineering at U.S. 

Naval Academy, Annapolis, Maryland, 1963-1964. 

Professional Attended Short Course on Air Pollution Engineering at 

Trainin -q the University of Texas at Austin, February 1970. 

Courses 

Attended four-week management course presented by the 

American Management Association, 1976. 

Certification Registered Professional Engineer 

Certified Visible Emissions Evaluator 

Certified Fallout Shelter Analyst 

Licensed Private Pilot (Multi-Engine-Land, Instrument) 

Diplomat in the American Academy of Environmental Engineers 

Inductee into the Stack Sampling Hall of Fame 

Professional Air & Waste Management Association - Past Chairman, Past Vice 

MembershiQs Chairman and Past Board of Directors 

Southwest Section: Past Chairman, Consultants Committee; Past 

Chairman, Source Measurement Committee 

Source Evaluation Society - Past President, Past Board of Directors 

American Management Association 

H-2 

l,`~G~ 
~ m 

MULLINS 

Publications Co-authored "Sulfur Compound Emissions of the 

Petroleum Production Industry," December 1974. 

Co-authored "Field Procedure for Stabilizing Hydrogen 

Sulfide Samples to be Analyzed Using Modified 

Methylene Blue Technique," presented at the Conference 

on Ambient Air Quality Measurements, Austin, Texas, 

March 1975. 

Co-authored "Atmospheric Emissions Survey of the Sour 

Gas Industry," October 1975. 

Co-authored "Technique for Insuring the Validity of 

Samples for High Concentrations of Sulfur Dioxide Using 

the EPA Method 5 Sampling Train," presented at the 

Third National Conference on Energy and the 

N Environment, College Comer, Ohio, September 1975. 

Teaching Served as a lecturer in the Environmental Protection 

Experience Agency's training course number 450, "Source Sampling 

for Particulate Pollutants," for two years from 

January 1974 to October 1975 and in March, 1992. 

Conducted a two-day training course entitled "Technical 

Assistance in Source Sampling" at lowa State University, 

Ames, lowa, for the Environmental Protection Agency,. 

October 1974. 

Conducted EPA's training course number 450, "Source 

Sampling for Particulate Pollutants," for the EPA at 

Research Triangle Park, North Carolina, September 1975. 

H-3 

l ~ 'l 
MULLINS 

Teaching Conducted a two-day short course entitled "Performing 

Exgerience and Observing Source Sampling° at Dallas, Texas, 

July 1976, May 1977, October 1977, November 1987 a 

1988; at Lake Charles, Louisiana, May 1977; at Caspei 

May 1977; and at Point Comfort, Texas, November 19 1, 

Served as a lecturer in the Environmental Protection 

Agency's two-day seminar entitled 'Asphalt Industry 

Environmental Solutions,' presented in Dallas, Texas, c 

March 21 and 22, 1979. 

Conducted a two-day short course entitled "Performing 

and Observing Source Sampling" in Phoenix, Arizona ii 

1990 for the State of Arizona, Department of Environm ~ 

in Lincoln, Nebraska, in March 1980 for the State of NE 

Quality Control Division. 

Technical Directed and performed stack sampling on over 

Exaerience 2000 sources of which over 500 were sampled simultar 

using more than one sampling train at several points in 

the flue gas stream: 1972-present. 

Directed and performed over 200 short-term ambient air 

studies using mobile sampling vans and various ambient 

air sampling equipment. 1972-present. 

Designed, directed and operated over 20 permanent 

ambient air networks of various size and duration for a 

variety of parameters. 1972-present. 

Designed surface and underground drainage systems f 

residential subdivisions, public works projects, and 

shoppirig centers. 1969-1972. 

Designed several residential subdivisions including lot 

layout, street design, drainage design, and utility desig 

1969-1972. 

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MULLINS 

Research Supervised and conducted a study made by the Hawaiian 

Proiects Sugar Planters' Association to characterize the emissions 

for several bagasse-fired boilers. April-May 1976. 

Supervised and conducted a study made by the Rio 

Grande Valley Sugar Growers, Inc. to determine the area 

affected by the burning of sugarcane fields prior to 

harvesting. November 1974-April 1975. 

Supervised and conducted a study by a lightweight 

aggregate manufacturer to develop a material balance 

around the process through sampling and analysis of 

several parameters. November 1973. 

Conducted a study in New York City to attempt to 

develop a correlation in the ambient air between carbon 

dioxide and sulfur dioxide to provide a tool for 

predicting air pollution episodes. January-May 1969. 

Related Served as Chairman of the Engineering Foundation Conference on 

Proiects Stack Sampting and Source Evaluation in Santa Barbara, California, 

1985. 

Served as Session Chairman at the Engineering Foundation 

Conference on Stack Sampling and Source Evaluation in Hershey, 

Pennsylvania, 1984; in San Diego, California, 1993; and in Palm 

Coast, Florida, 1994. 

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GORDON G. SMITH, Project Supervisor II 

Education B.S. 1988, University of Massachusetts, Amherst, Massachusetts, in 

Environmental Design. 

A.S. 1986, Stockbridge School of Agriculture, Amherst, 

Massachusetts, in Landscape Operations. 

Professional Attended 40-hour Occupational and Environmental Training Program 

Training on Hazardous Materials (CFR 1910.120) Dallas, Texas, April 1992. 

Courses Also attended an 8-hour refresher course, February 1995. 

Certification Certified Visible Emissions Evaluator ' 

Technical Participated in the sampling of over 500 sources, including several of 

_ExQerience which were sampled simultaneously using more than. one sampling 

train; and has supervised the sampling of over 250 sources, 

including three trial burns. 1992-present. 

Experienced in the analysis of commercial calibration gas cylinders 

for CO2, 02, NOX, S02, CO, and H2S. . 

Experienced with Modified Method 5 Sampling Train (Method 0010). 

Experienced with VOST sampling procedure (Method 0030). 

Experienced with calibration techniques for all field testing 

equipment. 

Experienced with various multiple metal and acid gas sampling 

trains. 

Has performed on-site S02analysis and H 2S fuel gas analysis. 

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JAMES M. GRUBBS, Environmental Technician II 

Education Preventive Medical Specialist 1993, U.S. Army, Womack Army 

Medical Center, R. Bragg, NC. 

Professional Attended 8-hour Safe Hazardous Materials Transportation Training 

TraininQ Program (HM-126F and HM-181) Dallas, Texas, October 1994. 

Courses Attended Bill Mullins' Performing and Observing Source Sampling 

Short Course; Dallas, Texas, January 1995. 

Technical Participated in the sampling of over 50 sources, including 

Experience several of which were sampled simultaneously using more than 

one sampling train. Thoroughly trained in all EPA testing procedures. 

1993-present. 

Experienced with calibration techniques for all field testing equipment. 

Thoroughly trained in the operation and routine maintenance of the 

following: 

Anarad AR880 Oxides of Nitrogen Analyzer 

Anarad AR23 Oxygen Analyzer 

Anarad AR30C2 Sulfur Dioxide Analyzer 

Anarad AR50-0 Carbon Dioxide Analyzer 

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JEFFERY R. BRUNSON, Environmental Technician I 

Education B.S. 1995, Angelo State Unitversity, San Angelo, Texas, in Biology. 

Technical Participated in the sampling of over 25 sources, including 

Exaerience several of which were sampled simultaneously using more than 

one sampling train. Thoroughly trained in all EPA testing procedures. 

1995-present. 

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JEFFREY D. CROCKER, Environmental Technician I 

Education B.S. 1994, Stephen F. Austin University, Nacogdoches, Texas, in 

Biology. 

Technical Participated in the sampling of over 25 sources, including several of 

Experience which were sampled simultaneously using more than one sampling 

train. Thoroughly trained in all EPA testing procedures. 

1994-present. 

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