! f



# ( Martin Marietta Magnesia Specialties 

# ,M ====:::::'::::=:::====:::::

# ::===========::::====:::::::

# =::::**=::~:::;:====,=:"~** 755 LimeRoad Woodville, OH 43469 USA 

### Telephone: (419) 849-4200 Fax: (419) 849-4246 August 24, 2006
Mr. Jim 

### Orlemann, Manager Division ofAir

### Pollution Control Ohio Enviromnental ProtectionAgency Lazarus Govermnent Center Post Office

### Box 1049 Columbus, Ohio 43216-1049 RE: Supplemental Technical Information Responses for OEPA Review SIPRevision Requestfor Martin MarlettaMagnesia Specialtiest 

### LLC 

### DearMr. Orlemann: Per our prior discussions and correspondence, I 

### am providing the following information to supplement Martin Marietta Magnesia 

### Specialties, lLC 

### (MMMS) submittals ofMarch 21. 2006; December IS, 

### 2005; and October 14, 2005 regarding the requested OAC §3745-17·07 SIP revision. In your June 6, 2006 e-mail, you requested: (1) 

### a best engineering time frame for achieving a stable firing condition during kiln start·up; (2) submittal of past deviationreports relating to 

### kilnstart-ups and shutdowns and (3) atechnical definition of"start-up" for alime kiln. Start Up Time Frame 

### As MMMS has noted in

### thepast, a safekiln start-up is not definedby time ortemperature, butrather as stabilization ofthe combustion process. Specifically, the conltol equipment can be safely used once a stable flame has been established, following the introduction ofsolidfuel into the kiln. Based on a review ofkiln logs and ouroperating experience, MMMS has found that a steady state kiln condition can generally be 

### achieved within 6 bours ofthe introduction ofsolidfuel during the start-upprocedure. Clearly, there is 

### abalance thatmustbe establishedbetween maximizing productivity, by stabilizingdIe kiln ruing process as soon as possible, versus extending the service life ofthe kiln 

### equipmentandrefractories by methodically adhering to a gradualbeatup andrestartingprocedure. Kiln 

### Deviatiog Reports Enclosed arecopies of

### Title VCompliance Certification malfunctionreports for two lime kilns (pOlS 

### and P019) for theyears 2003 through 2005. As you will see in these reports, there are three primary types ofkiln operating issues, eachofwhichrequires eitherabrief. moderateorlong shutdown, andacorrespondingrestartof

### the lime kiln. A briefinterruption ofthe 

### electrostatic precipitator (ESP) control on die #1 kiln (POlS) 

### can arise due to process variation, when the solid fuel 

### supplied to a kiln fluctuates in a manner that results in over fueling or excessive combustiblesconcentrations inthekiln exhaust, power intermptions. etc. When unburned combustibles are detected at concenttallons between 1.00.41 and 

### 2.5% of

### the exhaustflow, as shown on a recording chart or computer screen in the kiln control room, the operator responds to early warning alarms and adjusts the fuel feeder speed. If 

### excess combustibles still become greater than 2.50/0, an electronic alann is automatically activated and a control device turns offthe ESP. The kiln operator immediately implements corrective actions, which may range from simply verifying that a "highcombustibles" eventbas passed, to adjusting theprocess controls. Once theprocess stabilizes, the ESP is turnedback on manually, witbill. a shortperiod oftime after the combustibles concentration has returned

## (



# ( SIP Revision Requcst for Martin Marictta August 

### 24, 2004j Page2of2



### to a nonnal range (less than 

### I%). 

### As previously stated in our SIP request, this type 

### of situation imposes an explosion risk, endangers employee safety 

### and could resultin catastrophic damage to ourprocess equipment. Such kilnopemting issues may persistfrom 2 

### to 30 

### minutes and lmve been reported to Ohio EPA, perOAC §3745-1S-06, 

### as either "out-of-service" or "malfunction" events in

### the past. Another setofsituationsthatcould require shuttingdown theESP (pOIS) 

### orbaghouse (pO 19) 

### control units wouldbe problems with mechanical equipment (i.e. ESP shorting, process fan issues, clogged plenums, etc.) which could necessitate the tmplanned, temporary idling ofthekiln-firingprocess for 

### a longerperiod oftime, perbaps 30 

### minutes to several bours. Ifpossible, tIle kiln is kept wann, so the rest81ttime will be minimized. Per OAC §3745-1S..06, 

### these events bave typically beenreportedto Obio EPA as either "ollt-of-service" or "malfunction" incidents too. Finally, kilns 

### and associated control equipment

### are sometimes shut down completely for eitherroutine oremergency maintenance. Once the kiln 

### is "cold", it must be 

### reheated quite gradually, generally starting witb the firing of natural gas, until replacement refractories have been sufficiently cured or warmed to preserve the effective service life ofthe unit and to assure safe conditions. TIus reheating procedure can**Ja~t** 

### for 24 

### to 36 

### hours. As noted in 

### previous submittals, solid fuel and stone feed wilt be 

### restarted only during the last few hours of

### the kiln startup (as evidenced by tIle kiln logs previously submitted). Per OAC §3745 M 

### 15-06, 

### these events have also been reported as "scheduled maintenance", "out-ot-service" or "ma1:/.\mction" events due to the apparentneed for an exemption. Definition ofStal"tMUn 

### for a"Lime 

### Kiln 

### OAC §3745-17-01 

### defines "start-up" as "the commencement offiring offuel burning equipment from a

### cold, nonfired condition." As noted, this definition is specific to filel burning equipment. While firing a

### lime kiln is similar to starting apiece offuel burning equipment, MMMS would suggestadistinctdefinitionfor a "limekiln start-up" as follows: "the point ofcommencement offiring the kiln 

### until such time as tlle process is 

### operathlg in a steady-state condition using its primaryfhel. Forthe purpose ofthis definition, steady-state is considered to be 

### present when the throughputs 

### ofprocess material, fuel, and combustion air have been stabilized in 

### a mamler tbat demonstmtes the combustionprocess will be consistently complete and safe, with

### an exhaustedcombustibles concentration withinthe established safety limits." We appreciate yourcontinued attention to tltis critical SIP exemption request. To thatend, please contactme ifyou have any questions regarding tIlis submittal.

## Re(\~Y,

# JOeL~:n EnvironmentalEngineer Enclosures (3)

- 

### withboth e-mail and hard copies Cc: Don Waltenneyer, OEPA-NWDO Joe Reilly, MMMS Woodville TimTawney, MMMS Woodville Yvonne Bailey, Esq., MMMRaleigh April Bott, Esq., Chester, Willcox & 

### Saxbe

MMMS Woodville SIP Ltrv.3.DOC 8/2412006

# ( 

# OHIO EPA TITLE V COMPLIANCE CERTIFICATION REVISED AS REQUESTED BY OEPA 07/27/06

Compliance Certification Section 1- Facility Information
Complete this section ofthe form only once for the facility (See Compliance Certification Section IV under the Clarifying Instructions at the end of**t~is** 

### document for important additional information in filling out this part ofthe Corm.)**A~** 

### FacilityName: 

### Martin Marietta Magnesia Specialties, LLC B. Facility Address: 755 

### Lime Road, Woodville, Ohio 43469 

### C. Facility ID[10 

### diglts]=_0_3-_7_2-_0_0_-0_1_27

_ 

### D. Date ofTitle V Permit Issuance: 06/20/03**-':"~--'---------------** 

# ( E. Reporting Period: 

### January through December of2005 

## Compliance Certification Section 11- General Terms and Conditions (Part I ofthe Permit) Complete this section oCthe form only once for the facUlty (See Compliance Certification Section II under the Clarifying Instructions at the end ofthis document for important additional information in filling out this part ofthe form.)


### F. Has your company complied with all the General Terms and

## Co~ditions stated inPart I(A) ofthe Title V permit?

__ YES 

# -X.- NO Ifno, indicate the paragraph numberfor each General Term and Condition for which compliance was not maintained, a description ofthe excursion/deviation, and a description ofthe corrective actionthat was takento ensure that compliance will be maintained inthe future.

Permit DescriptionofExcursioolDevfatlon CorrectiveAction Taken Term No. PartI.A.6.a Thepermittee must comply with all terms andconditions of Please see the emission source identifications listedbelow. this permit. 

### F002; See Partill.A.ill.l, Part rn.A.III.2, and Part III.A.1lI••3j F003; F004; F006 PartI1LA.Ll; F007 Part ill.A.I.I; F008; P004; POll; P013; POlS; See Partill.A.LI, andPART m.A.III.5; P019j SeePart UI.A. V.I.e.i1; P028 (insignificant source, per 8/12/05 "malfunction" notification for dust collector).

Marlin MariettaMagnesia Specialties, LLC REVISED MMMS WoodvilleTitle VCertification for 200S.doc Page 1 ofSO 713112006

# ( 

# omo EPA TITLE V COMPLIANCE CERTIFICATION REVISED AS REQUESTED BY OEPA 07/27/06

Compliance Certification Section ill
- 

## Facility Terms and Conditions (Part IT ofthe Permit) Complete this section ofthe form only once for the facility (See Compliance Certification Section 

### ill under the Clarifying Instructions at the end ofthis document for important additional information in filling out this part ofthe form.) 

### G. Provide for eachtenn and condition in PartILA "State and Federally Enforceable Section", by appropriate paragraph citation, abriefstatement ofhow certification ofcompliance has been determined for eachterm and condition and a summary ofall excursion/deviations thathave occurred during the compliance certificationperiod. Please place an "X" in only one ofthe two options below Each lEUlisted In Part II.A ofthe Title V permithas complied with each applicable requirement established in the listed Permit to Install (PTl) and 

### N/A each applicable requirement specified In OAC Chapter3745·17, OAC Chapter 3745·18, and/or OAC Cbapter3745·21. Exceptas indicated for each lEU listed in the following table below, each lEU listed in Part II.A ofthe Title Vpermit has eompiled with each 

### N/A applicable requirementestablished in the listed Permit to Install (PTI) and each applicable requirementspecified in OAC Chapter3745-17, OAC Chapter3745.18, and/orOAC Chapter3745-21. (please identifyeach intermittentcompliant lEU In a separaterow in the table below as applicable.) 

# ( Identify the Emission Continuous (C) LimitatioolControl Method Used to Determine Measure orthe Permit Compliance

# . orIntermittent ExcurslonslDeviations Term No. (I) Compliance?' Those Documented Within ExcurslonlDeviation Other (Explain the Nature, Duration, Reports Submitted to and Cause oftheExcurslonlDevlatlon, OEPA DistrictOffice As Well As Any CorrectiveAction orLocal AirAgency Taken) (Identify Date ofEach Re ort PartILA.l 40

### emPart63.53 (NESHAP) Part I Application 

### C Submitted Priorto 40 CFRPt63;AAAAA Part I Application Submittal Ma 15,2002 PartII.A.2 40 CFRPart63.53 (NESHAP) 

### N/A 40 CFR Pt63;AAAAA Part II Applieation Submittal Part 1I.A.3.a NESHAP
- PartII; Initial Notlficlltion Part II Application within 120 days after Subpart 

### C Submitted Prior to ·40 CFRPt63;AAAAA Promul ation Ma 32004 Part 1I.A3.b NESHAP
- Compliance Status Notification; 6l1-days following 

### N/A 40 CFRPt63;AAAAA re ulred com ilanee demonstration


### H. Any othermaterial infonnationthat may indicate non - compliance with one ormore ofthe above

- described applicable requirements for this facility mustbe described below: There was no othermaterial information to the best ofour knowledge.

Marlin Marietta Magnesia Specialties, LLC REViSED MMMS WoodvilleTitle VCertification for 2005.doc Page 2of50 713112006

# ( OHIO EPA TITLE V COMPLIANCE CERTIFICATION REVISED AS REQUESTED 

# BY OEPA 07/27/06 Complete this section ofthe form for each significant emissions unit. Emissions units with identical terms and conditions may be grouped together (See "Compliance Certification Section IV" under the "Clarifying Instructions" at the end ofthis document for important additional information in filling out this part ofthe form.) 

## POlS P. SignificantEmissions Unit ill 

### [4 characters]:



# ------------------- Q. 

### Provide for eachterm and condition in PartTIl.A "State and FederallyEnforceable Section" for the emission unit, by appropriate paragraph citation, abriefstatement ofhow certification ofcompliance has been determined for each term and condition and a summary ofall excursions/deviations that have occurred during the compliance certification period.' 

## Please addrows as necessary for eachEmission limitation/ControlMeasure specifiedinPartIILA.LI of thepermit. Identify the Emission Continuous (C) Limitation/Control Method Used to Determine Measure or the Permit Compliance' or Intermittent ExeurslonslDeviations Term No. (I) Compliance?' Those Documented Within Excursion/Deviation Other (Explain the Nature, Duration. Reports Submitted to and Cause oftbe ExcurslonlDevlatlon, OEPADistrictOffice As Well As Auy CorreetiveAction orLocal AirAgeney Taken) (Identify Date ofEach Re ort PARTUI.A.I.1 Inspections 5 dayslweek

- minimum 

### I**Ma~unction~Ou~o~** OAC 3745-17-07(A) Service; See Below 

# ( I'ART IILA.Ll PE Limitation: 79.9 Ib/br (Combined) 

### I Malfunctions/Out-ofOAC 3745-17-11(B) Scrvice; See Below PARTDI.A.I.1 SOl Limitation: 25.0 Ib S02lton of 

### C None OAC 3745-18-78(E)(1) product PARTIILA.1.1 Inspections 5 dayslweek

- minimum 

### C None OAC 3745-17-07(B)(1) PARTUI.A.Ll Employ RACM: III.A.I.2.b 

### C None O!\C 3745-l7-08(B) PARTlILA.I.2.a QAC 374S-17-U(A)(3): Combine PE 

### C None emissions CromPOlS and P019 PARTUlA.I.2.b.1 RACM: Enclosures (Buildings) and 

### C None hooding to minimlzc fugitive emissions PARTI1I.A.I.2.b.1I RACM: All fugitive dust captured 

### C Nonc within hulJdlug

- ventto ESP 110836 PART UlA.".l Only coal, petroleum coke, and/or 

### C None natural gas shall be burned. PARTUlA.D.2 SulfurContent ofCoal/Coke: less than 

### C None content measured atmost recent test PART 1II.A.UI.l Samplcs ofcoal/coke: analyze for 

### C None sulfur content and heatcontent. PART ID.A.DI.2 Mainlllin monthly: tollli quantity of 

### C None coaUcoke received; analytical resullJ PART III.A.III.J Egress Points: VE Observation 

### C None Inspections 5 days/week PARTUlA.IIL4 ESP: VE Observation Inspections 5 

### C None dayslweek Martin Marietta Magnesia PART III.A.III.5 ESP Opacity Observation: once/month 

### I None Specialties, LLC, missed the 40 CFR Part 60, App. A, Method 9 monthly Method 9 Opacity 

## ( observation for A ril 2005.

Martin Marietta Magnesia Specialties, LLC Page 30 of50 713112006 REVISED MMMS Woodville Title VCertification for 200S.doc

# (



# (

( \ 

# OHIO EPA TITLE V COMPLIANCE CERTIFICATION REVISED AS REQUESTED BY OEPA 07/27/06 Readings to be conducted at tile bel!inninl! oCtile montll. PART rn.A.rn.6 CLARIFICATION PARAGRAPH 

### N/A N/A I'ART III.A.IV.l FuelType BurnedDeviation; report 

### N/A All required reports within 30-days ofoccurrence submitted PARTIII.A.IV.2 SulfurContent Deviation: report 

### N/A All required reports within 45-days ofoccurrence submitted PART I1I.A.IV.J Quarterly Report: ESP Out-of-Sel"Viee 

### C All required reports Summaries submitted PARTIII.A.IV.4 Semiannual Report: Egress Point 

### C All required reports Deviation and Corrective Actions submitted PART ro.A.IV.S Semiannual Report: Baghouse 

### C All required reports Deviation and CorrectiveActions submitted PART III.A.IV.6 Semiannual Report: OpacityDeviation 

### C All required reports and CorrectiveActions submitted PART rn.A.V.l.a Emission testing to be conducted 

### C None within J-months after permit issued. PARTIII.A.V.l.b Emission testing: demonstrate 

### C None compliance with PE and S02, Opacity PARTIILA.V.I.e.1 PE Emission Rate: 40 CFR Part 60, 

### C None APPllDdlx A, Methods 1-5 PART III.A.V.l.e.il 20% Opacity (J-mIIl/6-mln averages): 

### C None 40 CFRPart 60, App. A, Method 9 PART rn.A.V.l.eJlI S02Emission Rate: 40 CFRPart 60 

### C None Appendix A, Methods 1-4 and 6 PARTIII.A.V.l.d ConductEmissionTests ator near 

### C None maximum capacities PART UloA.V.l.e Submit "Intent-to- Test" Notification 

### C None 30 days prior to proposed test date PARTrn.A.V.2.a Additional Information during testing: 

### C None Sulfur Contentcoal/coke burned PART m.A.V.2.b Addltlonallnformalion during testing: 

### C None PowerInput (kW) ofeachTR set. PART I1IoA.V.J.a Applicable Testing Requirements 

### C None PART III.A.V.3.b Applicable Tesling Requirements 

### C None PART rnoA.V.3.e ApplicableTesting Requirements 

### C NOlie \ PART In.A.V.3.d ApplicableTesting Requirements 

### C None PARTIILA.VI N/A (This permitdoes nothave any 

### N/A N/A mlseellaneous requirements) 

### R. 

### Any othermaterial infonnation thatmay indicate non-compliance with one or more ofthe abovedescribed applicable requirements for this facility must be describedbelow: PartIII.A.I.t Deviation Reports: Due to the safe operation ofthe #1 South Kiln, all 

### kiln shutdowns and startup**r~quire** 

### the bypassing ofthe ESP control system to prevent damage and explosion to the control system. Since the startup/shutdown regulation exemptions do not apply to our kiln operation, the properprocedure is to identify these occurrences as malfunctions. As indicated in the Quarterly Deviation Reports, the

Marlin Marietta Magnesia Specialties, LLC REVISED MMMS WoodvilleTitleV Certification for 200S.doc Page 31 ofSO 7/3112006

# OIDO EPA TITLE V COMPLIANCE CERTIFICATION ( REVISED AS REQUESTED BY OEPA 07/27/06 following is a list ofthose times ofshutdown/startup ofthe #1 South Kiln and "out-of-service" days during the reporting period:
A. 1st 

### QuarterDeviation Report for the period ofJanuary 1 t 

### 2005 through March 31, 2005 submitted by April30t 

### 2005: Malfunction Reports January 2005 116/2005: Both ESP Sections; 10-minutes; Power Outage 1125/2005: Both ESP Sections; I-hr; Low-TemperaturelHigh Combustible Safety Alarm 

### 1/2812005: Both ESP Sections; 10-minutes; Low-TemperaturelHigh Combustible Safety Alarm 112912005: Both ESP Sections; 15-minutes; Low-TemperaturelHigh Combustible Safety Alarm February 2005 

### 219/2005: Both ESP Sections; 10-minutes; Low-TemperaturelHigh Combustible Safety Alarm 2/1012005: Both ESP Sections; 30-minutes;Low-TemperaturelHigh Combustible Safety Alarm 

### 2/1112005: Both ESP Sections; 6-minutes;Low-TemperaturelHigh Combustible Safety Alarm 2/12/2005: Both ESP Sections; 45M minutes;LowM TemperaturelHigh Combustible Safety Alarm 2/14/2005: Both ESP Sections;**l~minutes;LowMTemperatureIHigh** Combustible Safety Alarm (02/17/2005): Email Notification; Shutdown/Startup No.1 South Kiln (P015); Repair ID& Coal Fan 2/2012005: Both ESP Sections; 15-minutes;LowM TemperaturelHigh Combustible Safety Alarm 2/23/2005: Both ESP Sections; I-hr;Low-TemperaturelHigh Combustible Safety Alarm 2/24/2005: Both ESP Sections; 25-minutcs;Low M TemperaturelHigh Combustible Safety Alarm 2128/2005: Both ESP Sections; 30-minutcs;Low-Temperature/High Combustible Safety Alarm 

# ( March 2005 3/212005: Both ESP Sections; 3D-minutes; Low-Temperature/High Combustible Safety Alarm 3/612005: Both ESP Sections; 45-minutcs;Low-TemperaturelHigh Combustible Safety Alarm 3n12005: Both ESP Sections; 8hr-50mlnutes;LowM TemperafurelHigh Combustible Safety Alarm 3/8/2005: Both ESP Sections;**2hrM3~minutes;Low-TemperaturelHigh** Combustible Safety Alarm 3/11/2005: Both ESP Sections; 7hr-15-minutes;Low-TemperaturelHigh Combustible Safety Alarm 3/14/2005: Both ESP Sections; I-hr;Low-TemperaturelHigh Combustible Safety Alarm (03/14/2005): Email Notification; Shutdown/Startup No.1 South Kiln (POlS); RepairlBalance Coal Fan 3/16/2005: Both ESP Sections; 2D-minutes;Low-TemperaturelHigh Combustible Safety Alarm 3/2012005: Both ESP Sections; 35-minutes;Low-TemperaturelHigh Combustible Safety Alarm 3/2512005: Both ESP Sections; 10-minutes;Low M TemperaturelHigh**Co~bustible** Safety Alarm 3/2712005: Both ESP Sections; 55-minutes;Low-TemperaturelHigh Combustible Safety Alarm 313012005: Both ESP Sections; 30-minutes;Low-TemperaturelHigh Combustible Safety Alarm


### B. 2nd 

### Quarter Deviation Report for theperiod ofApril 1, 2005 through June 30, 2005 submitted by July 31, 2005: Malfunction Reports April 2005 4/5/2005: Both ESP Sections; 22-minutes; Low-TemperaturelHigh Combustible Safety Alarm 4/8/2005: Both ESP Sections; 35-min; LowMTemperaturelHigh Combustible Safety Alarm 4/1412005: Both ESP Sections; 10-minutes; Low-TemperatureIHigh Combustible Safety Alarm (04/1512005): Email Notification; Shutdown No.1 South Kiln (POlS); Kiln and Coal Fan Repairs (04/29/2005): Email Notification; Startup No.1 South Kiln (POl5); Kiln and Coal Fan Repairs 413012005: Both ESP Sections; 

### lhr45-min; Low-TemperaturelHigh Combustible Safety 

### Alarm May 2005

Martin Marietta MagnesiaSpeelalCies, LLC REVISED MMMS Woodville TitleVCertification for200S.doc Page 32 of50 7/31/2006

## ( 

# OHIO EPA TITLE V COMPLIANCE.CERTIFICATION REVISED AS REQUESTED BY OEPA 07/27/06 512/2005: B

- Section; 30-minutes; PowerLoss

- Electrical Repairs 5/1312005: Both ESP Sections; I-hr; Power Outage 5/2312005: Both ESP Sections; 15-mlnutes;Low-TemperaturelHigh Combustible Safety Alarm 5/24/2005: Both ESP Sections; 30-minutes;Low-TemperaturelHigh Combustible Safety Alarm 5/2512005: Both ESP Sections; 20-minutcs;Low-TemperaturelHigh Combustible Safety Alarm 5/2612005: Both ESP Sections; 4-hrs; ID Fan Electrical Problems

- Electrical BreakerPanel 5129/2005: Both ESP Sections; 5-mlnutes; Low-rempel'aturelHigh CombUstible Safety Alarm June 2005 612/2005: Both ESP Sections; I-hr; Low-TemperaturelHigb Combustible Safety Alarm 6/312005: Both ESP Sections; 4-hrs; Safety Alarm

- Coal Fan Repair 6/14/2005: Both ESP Sections; 6hr-30minutes; Power Outage 6/15/2005: Both ESP Sections; 10-minutes; Low-TemperaturelHigh Combustible Safety Alarm 612112005: Both ESP Sections; 4hr-30-minutes; Safety Alarm

- Coal Fan Repair 612312005: Both ESP Sections; 8-minutes; Low-TemperaturelHigh Combustible Safety Alarm 6125/2005: A - Section; 3hr-30min; Electrical Problems A-Side

613012005: Both ESP Sections; 30-minutes; PowerOutage Scheduled Maintenance Reports ESP Out-of=Service Date· ESP Section Duration



# (

( 

# c. 3rd 

### Quarter**Dev~ation** 

### Report for the period ofJuly 1, 2005 through September 30, 2005 submitted by October 31, 2005: Malfunction Reports July 7/20 both sections, -1 hr., to clean ID fan. 7/21-22 both sections, -261/3 hrs., were shut down to fix shorted out wires. 7/27 both sections, -20 min., to repair combustibles analyzer-alarm system. 7131 both sections, 

### -5 min., to repair combustibles analyzer-alarm system. August 8/06 both sections, -25 min., to repair a broken combustibles analyzer. 8/13 both sections, -10 brs., to address a coal fan balancing (safety) issue. 8/13 both sections, -3 % hrs., due to a complete electrical power outage. 8/16 both sections, -2 1/4 hrs., to address a coal fan balancing (safety)**is~ue.** 8122 the"A" section, -3 5/6 hrs., to address dust clogging and shorting out ofESP. 8126 both sections, -2 1/2 hrs., to address a coal fan balancing (safety) issue. 8129 the "A" section, -42 hrs., to address dust clogging and shorting out ofESP. September 9/14 both sections, -15 min., to repair a broken combustibles analyzer (safety) problem. 9/19 the 

### ''B'' section, -36 hrs" to address an electrical failure with a broken ESP wire.

ESP Qut-of..seryjce


### D. 4th 

### QuarterDeviation Report for the period ofOctober 1,2005 through December31,2005 submitted by January 31, 2006: MalfunetjQD Reports October

MartinMarietta Magnesia Specialties, LLC REVISED MMMS WoodvilleTilleV Certification for 2005.doc Page 33 of50 713112006

# ( 

# omo EPA TITLE V COMPLIANCE CERTIFICATION REVISED AS REQUESTED BY OEPA 07/27/06 10/04 

### both sections, -45 min., because ofan unexpected coal pipe failure. 10/0S 

### both sections, -1 

### hr., shutdown & 

### startup to address a coal fan balancing (safety) issue. 10/06 

### both sections, -7 

### min., automatic ESP shutdown due to fueling variation (safety) issue. 10/17 

### both sections, -1 

### hr., unexpected outage resulting from coal fan and gas firing failures. 10118 both sections, -12 

### hrs., due to ill/coal fan vibration (safety) and ESP startup problems. 10/20 

### both sections, -S 

### hrs., becauseofthe failure ofan oil return pump on the #1 

### ball mill. 10/30 

### both sections, -1 

### hr., unanticipated shutdown due to cooler belt and gas firing issues. November 11/01 

### both sections, ...(j 

### 1/4 

### hrs., due to a bad coal fan bearing and normal kiln startup routine. 11/15 

### both sections, -S 

### hrs., shutdown for reducing coal fan speed to address kiln-ESP outages. 11/15 

### both sections, -S 

### min., automatic ESP shutdown due to fueling variation (safety) issue. 11/20 

### both sections, -2 

### min., automatic ESP shutdown due to fueling variation (safety) Issue. 11/29 

### both sections, -S 

### hrs., due to a ball mill motor failure and normal kiln startup routine. December 12/05 

### both sections, -3 

### min., automatic ESP shutdown due to fueling variation (safety) issue. 12/06 both sections, -13 

### min., automatic ESP shutdown due to fueling variation (safety) issue. 12/08 

### both sections, ...(j 

### hrs., due to excessive In 

### fan vibration (safety) and shutdown for repairs. 12/14 

### both sections, -4 min., automatic ESP shutdown due to fueling variation (safety) issue. 12/14 

### both sections, -4 min., automatic ESP shutdown due to fueling variation (safety) issue. 12/14 

### both sections, -10 

### min., automatic ESP shutdown due to fueling variation (safety) issue. 12/15 

### both sections, -10 

### min., automatic ESP shutdown due to fueling variation (safety) issue. 12/18 both sections, -S min., automatic ESP shutdown due to fueling variation (safety) issue. 12/19 

### both sections, -10 

### min., automatic ESP shutdown due to fueling variation (safety) issue. 12/20 

### both sections, -10 

### min., automatic ESP shutdown due to coal crusher fuel variation (safety). 12/22 

### both'sectlons, -SO 

### min., unplanned ESPshutdown due to frozen waterline on the ID fan. 12/26 

### both sections, -20 

### min.. automatic ESP shutdown due to fueling variation (safety) issue. Cleaning ofstones and dust on 08/24 

### resulted in visible particulate emissions for -1 

### hours. Stone feed chutes on this unit generated visible particulate emissions on 12/21/05 

### for -1 

### hour. Per discussions with OEPA, the required cleanup was completed and operating personnel were asked to maintain equipment and to keep quantities ofstone debris and dust from accumulating in this area. Operating personnel were asked to search for source of12/21 emissions and corrected the problem. Visible fugitive emissions were observed on 9/27, 9/28, 11/28, 12/13,12/19,12/20, 

### and 12/21. 

### OEPA was previously notified ofthe following "malfunetions" due to potential emissions issues:

ESP Out-or-Serylce



## ( ESP Section Duration

Martin Marietta MagnesiaSpecialties, LLC REVISED MMMS Woodville Title VCertification for 200S.doc Page 34 of50 7/31/2006

# OHIO EPA TITLE V COMPLIANCE CERTIFICATION ( REVISED AS REQUESTED BY OEPA 07/27/06
Compliance Certification Section IV

- Si2nificantEmissions Units Terms and Conditions

. (Part ill 

## ofthe Permit) Complete this section ofthe form for each significant emissions unit. Emissions units with identical terms and conditions may be grouped together (See "Compliance Certification Section IV" under the "Clarifying Instructions" at the end oftbis document for important additional information in filling out this part ofthe form.)


### P019 H. 

### SignificantEmissions Unit ill 

### [4 characters]:



# ----------------------- 1. 

### Provide for each tenn and condition in Partill.A "State and Federally Enforceable Section" for the emissionunit, by appropriate paragraph citation, a briefstatement ofhow certification ofcompliance has been determinedfor eachtenn and condition and a summary ofall excursions/deviations that have occurred during the compliance certificationperiod. 

## Please addrows as necessary for eachEmission limitation/ControlMeasure specifiedinPartIIIA.L 1 

## of thepermit. Identify the Emission Continuous (C) Limitation/Control Method Used to Determine Measure or the Pennit Compliance

### , orIntermittent ExeursionslDevlations TermNo. (I) Compliance?' Those Docnmcnted Within 

## ( ExcursionlDevlation Other (Explain the Nature, Duration, Reports Suhmltted to and Cause ofthe ExeursionIDevlatlon,

" OEPADistrict Office AsWcll As Any CorrectiveAction orLocal AirAgency Takeu) (Identify Date ofEach Re ort PARTIU.A.I.1 Inspections 5 dayslweek

- minimum 

## C None OAC 374S-17·07(A) PART IILA.I.1 PE Limitallon: 79.9Ib/hr (Combined) 

### I Malfunction Reports OAC 3745-17·1l(B) PARTIILA.I.1 802 Limitation: 25.0 Ib S02/ton of 

### I Malfunction Reports OAC 3745-1S-7S(F) product PART ill.A.I.1 Inspections 5 dayslweek

- minimum 

### C None OAC 3745-17-07(B)(1) PART ill.A.1.1 Employ RACM: llI.AJ.2.b 

## C None OAC 3745-17-DS(B) PARTill.A.I..2.a OAC 3745-17-11(A)(3): Combine PE 

### C None emissions from POlS and POl9 PARTill.A.I.2.b.i RACM: Enclosures (Buildings) and 

## C None hooding to minimize fugillve emissions PART ill.A.I.2.b.1I RACM: All fugItive dustcaptured 

## C None wltbin building

- vent to bh 111085 PARTill.A.II.1 MaintainPressure Drop Across 

## C None Baghouse: wIthin 6-16 Inches water PARTIII.A.1I.2 Only coal, petroleum coke, and/or 

### C None natural gas shall be burned. PARTIILA.II.3 SulfurContentofCoal/Coke: less than 

## C None content measured atmostrecent test PART II1.A.II1.1 Maintain and Record Pressure Drop: 

### C None Frequency: Weekly

- minimum ( \ Martin Marietta Magnesia Speclallles, LLC Page 36 ofSO 713112006 REVISED MMMS Woodville Title VCertificationfor 200S.docPARTm.A.I1U Samples ofcoal/coke: analyze for 

### C None sulfur content and heatcontent. PART III.A.I1I.J Maintain monthly: total quantity of 

### C None coal/coke received; analytical results PART IIIAnIA Egress Points: VE Observation 

### C None Inspectiollil 5 days/week PART I1I.A.III.5 Baghouse: VE Observation 

### C None Inspeellons 5 dayslweek PART 1II.A.IV.l Quarterly Report: PressureDrop 

### C All required reports Deviation and Corrective Action submitted PART III.A.IV.2 Fuel Type Burned Deviation; report 

### N/A All required reports within 30-days oCoccurrence submitted PART III.A.IV.3 SulfurContent Deviation: report 

### N/A AU required reports witbin 45·days ofoccnrrence submitted PART fiLA.IVA Semiannual Report: Egress Point 

### C All required reports Deviation and Corrective Aetions submitted PART III.A.IV.5 SemIannual Report: Baghouse 

### C All required reports Deviation and Corrective ActIons submitted PART 1II.A.IV.6 SemIannual Report: Opacity Deviation 

### C All requIred reports and Corrective Actions submitted PART IlIA V.l.a Emission testing to be conducted 

### C None wllldn 3-months aClerpermit issued. PART IIIAV.l.b Emission tesllng: demonstrate 

### C None compliance wUh PE and SOl, OpacIty PART liLA.V.l.c.1 PE Emission Rate: 40 CFR Part 60, 

### C None Appendix A, Methods 1-5 OEPA was notified on 9/26 & 9128 ofP019 baghonse bypassing due to #2 kiln" shutdown and startup. OEPA was notified 10/14 & PART III.A.V.l.c.1I 20% Opadty (3-min/6-mln averages): 

### I Malfunction 10126 ofP019 bagbouse 40 CFR Par/GO, App. A, Method 9 Reports bypassing due to #2 kiln" shutdown and startup. Shutdownsand&artupswere executed 

### in a way that minimized emissions and protected equipment. PART I1LA.V.l.c.1II S02 EmIssion Rate: 40 CFR PartGO 

### C**~one** Appendix A, Methods 1-4 and 6 PARTII1.A.V.l.d Conduct Emission Tests at ornear 

## C None Rlaximum capacities PARTm.A.V.l.e Submit "Intent-to--Tesf' Notification 

### C None 30 days prior to proposed test date PARTllLA.V.2.a AddilionallnCormation dudng testing: 

### C None Pressure Drop across baghollse PART m.A.V.2.b Additional Information durIng testing: 

### C None SulfurCllntent coal/eoke burned PART llLA.V.3.a Applicable Tesling Requirement 

### C None PART m.A.V.3.b Applicable Tesllng Reqnlrement 

### C None PART III.A.V.3.c Applicable Tesllng Requirement 

### C None PART liLA.V.3.d Applicable Tesllng Requirement 

### C None



# OHIO EPA TITLE V COMPLIANCE CERTIFICATION ( REVISED AS REQUESTED BY OEPA 07/27/06

(

Martin MarIetta Magnesia Specialties, LLC REVISED MMMS Woodville Title V Certification for200S.doc Page3? ofSO ?/31n.OO6

# OHIO EPA TITLE V COMPLIANCE CERTIFICATION ( REVISED AS RE UESTED BY OEPA 07/27/06 PARTIII.A.VI 

### N/A N/A 

## J. Any other material information that may indicate non-compliance with one or more ofthe abovedescribed applicable requirements for this facility must be described below:


### Part III.A.I.t Deviation Reports: Due to the safe operation ofthe #2 South Kiln, kiln startup requires the bypassing ofthe Baghouse control system to prevent damage and explosion to**~he** 

### control system. Since the startup/shutdown regulation exemptions do not apply to our kiln operation, the proper procedure is to identify these occurrences· as malfunctions. As indicated in the Quarterly Deviation Reports, the following is 

### a list ofthose times ofstartup ofthe #2 South Kiln during the reporting period:

Malfunction Reports 9/26 E-mail notificatIon for bypassing the P019 baghouse due to #2 kiln" hot spot" shutdown. 9/28 

### E-mail notification for bypassing theP019 baghouse due to #2 kiln" startup procedure. 10/14 E-mail notification for shutdown ofthe P019 kiln and baghouse for routIne maintenance. 10126 E-mail notification about the startup oftheP019 kiln and baghouse, 

### per 10/14 entry above. 

# (

( \ 

### Stone feed chutes on 

### this unit generated visible particulate emissions on 12/20/05**for~3** 

### hours. Operating personnel were asked to searchfor source of 12/20

### emissions and correctedthe problem.

Martin Marietta Magnesia Specialties, LLC REVISEDMMMS WoodvilleTitleVCertification for200S.doc Page 38 of50 713112006

## ( 

# OHIO EPA TITLE V COMPLIANCE CERTIFICATION

( 

## , 

# Compliance Certification Section 1- Facility InfOl'mation

. COln}>lete this section oftIte form only once fol' the facility (Sec Compliance Certification Section IV unclel' the Clarifying

Instructions at the end oftllis document for Jml)ol'fant I\cldl1l0nal information in ruling Ollt this pal't ofthe Co

### I'm.) 

## A. Faci!ity Na1l1e: 

## Martin Marietta Magnesia Specialties, LLC B. FacilityAddress: 755 Lime Rond, Woodville, Ohio 43469 C. Facility ID[lOdlgltsl:_0_3-

...... 7_2_-0_0_-0_1_2_7 

## D. Date ofTitle 

## VPennit

## Issuance: 06/20/03**,.....;.~--------------** 

## E, Repol:ting Period: January through December of2004

## COlt~pliance 

## Certification Section**I~** 

## - General Terms and Conditions (Part I 

# ofthe Permit)

. 

# . Complete this section ofthe form only once for the facility (See Compllanco Certification Section II uuder the Clnl'lfylng Instructlolls at the end oftIlls document for important adcli,tionalillfonnatioll in mUng out tltls POl'tofthe form.) 

## F. Has 

## yom compmly complied 

## with all the General Terms 

## and Conditions stated in

## PartI(A) ofthe 

## TitleV pelmit?

_ YES 

# ...x.-. NO**Ifno~** 

## indicate the paragraph 

## number for each General Term 

## and Condition for which compliancewas 

## not**maintained~** 

## a

## description ofthe 

## excursion/deviation, 

## and a 

## descliptioll ofthe 

## con-ective action that was taken 

## to ensure that 

## compliance 

## will bemaintained in the 

## future.

l'ofmit J)eslll'lllClOII ofExcurslolllDovlntion Corl'oct!nAclloll Tnltcn Tel'nlNo. PRl't I,A.G.n 'fIJe permitteemllst comply with all terms lind condlllolls of l'lense see the emission sourceldenllRealions lisled below.
I this penni!, 

### Emission Soul'ce lD: 1'015; 

### See !'al'tIII.A.I.1 EmissIon Sonrce ID: 1'019; 

### SeePal't 

### III.A.I.1

MII1'lin Marlettll Magnosla Sllcclnltlcs, LLC Pllge I 4/2512005

# OHIO 

# EPA TITLE V COMPLIANCE CERTIFICATION ( Compliance**Certific~tion** 

## Section III

- 

## Facility Terms and Conditions (Part IT ofthe Permit) Complete this section oftbe form only once for the facility (See Compliance Certification Section 

### ill under the Clarifying Instructions at the end ofthis document for important additional information ill filling out this part ofthe form.) 

### G. Provide for each term and condition in 

## Proi ILA "State and Federally Enforceable Sectionn
, 

### by appropriate paragraph citation, abriefstatement ofhow certification ofcompliance has been determined for each tenn and condition and a s.ummary ofall excursion/deviations that have occurred during the' compliance certification period. 

### Please place an "X" in only one ofthe two options below 

### N/A Each lEU listed In Part II.A oCtheTitle V pemut has complied with each applicable requirementestablished In the listed Pel'ndt to Install (pTl) and each applicable requirement specified In OAC Challter3745-17, OAC Chapter 3745.18, andJor OAC Chapter 3745·21. Except as Indicated for each lEU listed In the followIng table below, each lEU listedIn Part II.A ofthe TItleV pcrmit has compllcd with each 

### N/A applicable reqnlrcment established In the listed Permit to Install (pTI) and each applicable requirement spcclfied In OAC Chapter3745-17, OAC Chapter 3745-18, and/or OAC Challtcr3745·21. (pleasc Identify each Intermittent compliant lEU In a separaterow In the table below as applicable,)

Identify the Emission Method Used to Dctermlne Continuous (C) Limitation/Control Measure or the Pel'mlt Compliance

# . or Intermittent Excul'slonslDevlalions TernlNo. (l) Compliance?' ThoseDocumented Within Excnl"slonIDevllltlon Other (Explain the Nature, Duration, 

# ( Reports Submitted to and Cause ofthe ExcurslonIDevlatlon, OEPA District Office As WellAs Any Corrective Action orLocal All' Agency Taken) (Identify Date ofEach Re 011 PartIl.A.1 40 CFRPali 63.53 (NESHAP) PartI Application 

### C Submitted Prior to 40 CFRPt63;AAAAA PartI Application Submittal Ma 15,2002 Part I1.A.2 40 CFR Part 63.53 (NESHAP) 

### N/A 40 CFRPt 63jAAAAA Part II Application Submittal PartILA.3.a NESHAP

- Part IIj Initial Notification Part II Application wltbln 120 days after Subpart 

### C Submitted Prior to 40 CFR Pt 63;AAAAA Promul atlon Mn 32004 Partn.A.3.b NESRAP

- Compliance Status 40 CFRPt63;AAAAA Notlficatloll; 60-days following 

### N/A re ulred com lIance demonstration 

### H, Any othermaterial infonuation that may indicate non - compliance with one ormore ofthe above

- described applicable requirements for this facility must be described below: 

### There was no other material information to the best ofour knowledge.



## (

Martlll Mal'letta Magnesia Specialties, LLC Page 2 412512005

# ( 

# OHIO EPA TITLE V COMPLIANCE CERTIFICATION Compliance Certification Section IV

- Significant Emissions Units Terms and Conditions 

## (I)art III ofthe Permit) Complete this section oftbe fm'm for eacll significant emissions unit. Emissions units with identical terms and conditions may bo grouped togetlJer (See "Compliance Certification Section IV" under the "Clarifying Instmctlons" at the end oftbls document COl' important additional informntlon in mling out this part ofthe form.) 

## POlS 

## P. SignificantEmissions Unit ill 

## [4 characters]:



# -----------------------

(

( Q. 

## Provide for· each term and condition ill PartlILA "State and Federally Enforceable SectionU 

## for the emission unit, by 

## appropriate paragraph citation, a brief

## statementofhow cOliificatioll of

## compliance has been detel111ined for each term and condition and a summaryofall excursions/deviations that have occurred during the compliance certification period. 

## Please addrows as necessmy for each Emission limitation/ControlMeasure specifiedin Pm't IllA.I.] 

## of thepermit, Idelltlfy tho Emlssloll COlllhlllOUS (C) Llmltntlon/Conll'ol Mcthod Used to Detel'mllle MenslII'o ol'lhoPOI'mlt Compliance· or IntCl'lIllItellt Exctll'slolls/Devlnllous Tel'nlNo. (1) Compllnllce?· ThoseDoculllonted WlIhlll EXCUl'slolllDevlnlloll Olhol' (Explnlllllic Nnturc, DllI'nlloll, Rellol'ts Subllllltcd to Dlld ClIllse oftheExcursion/DevIatIon, OEPA D1sb'1cl Omell As Well As AllY COl'recllveActloll 01' L\lcnl Ah' Agelley Tnken) (Idenllfy })lIteofEneh Rc IOrt PART II1.A.I.l Insllccllims 5 dft)'slwcok"-mh!hIlIlDl 

### C· NOIIG OAC 374S-17·07(A) PARTnI,A,I.l I'ELhllilatlon: 79,9 Ib/hl' (Comblncd) 

### I Mnlfuncl1olls/0nt-oC· OAC 374S.17.11(ll) ServIce. SeelJclow PART III,A,I,1 802 Llmlllltlolll 25,0 Ib 802/toll of 

### I Mall'uncllonuOut-ol'- OAC 3745-1S.7S(E)(1) pl'ollllet ServIce; Sec Bclow l'AR'rlXl.A,I.l

. 11I811ccll0IIs 5 days/wcc\t- IIIlolonulI 

### C None OAC 3745-17·07(8)(1) PARTJII.A,I.1 Employ RACMr III.A.I.2.b 

### C Nonc OAC 3745-17-0S(8) OAC 374S·17·Jj (A)(3): Comblllo PE \ PART UI,A.I.:Z.a onlls510115 fa'om POIS lind 1'019 

### C NOlie l'ART II1.A,L2.b.1 .RACM: Elle105111'C5 (BUildings) and 

### C NOllo 1I00dlll010 11I111111I11:0 fngilln omissions PART III,A,I.2.b.11 RACM: All fngillve dnst capllII'cd 

### C None wllhlll blllldlllg

- VCllt 10 ESP#OS36 PART rn.A,II.l Dilly conI, plltrolclIlll coke, and/or 

### C Noue olltlll'lll gos shllll bll bUI·lIed. PART III,A,IU SuiI'llI' COlltent oCCOllI/ColIC: Icsslhan 

## C NOllo eoIIlent mOIlSlll"Od allllost I'eeont lest PAR1' III,A,IlI.1 Satnilles ofcolIl/eokol 1I11111yzefor 

### C Nono slIlfur clIutentand heatcontellt, Malnlahl mOllthly: tol,,1 qlllllltlty oC t l'ART 1IJ.A,III.2 

### C NOllo ,; eonlfcoke rccclvcd; anillytleal r/lSlllts )'AR'r 1II.A.III,3 Egl'oss Poillts: VE Obsel'VlIl1on 

### C NOllc Inspcctlons 5 day8Jlvoilk PART JII,A,m.4 ESPl VE Observilloll Inspoellons 5 

### C Nooe dRys/week PART m.A.III,S .li:81' Opnelly ObsCI'vallon: once/montb 

### C NOllo 40 CFR Pal't 60. AIIP, A. Mctbod 9

Mal'lIn MarIetta MaOllcsla SpecialtIes, LLC Page 28 412512005

## (



# ( 01rIO EPA TITLE V COMPLIANCE CERTIFICATION PART

## m.A.m.6 CLARIFICATION PAUAGRAPH 

### N/A N/A l'ART m.A.IV.1 FuelTyllc Ilm'ulld Devlll11011; I'ollol'! 

### N/A AlII'cqUh'cd 1'°1101'15 within 30-c1I1Ys ofOcelll'I'onCO snbmlttod P

An1' IJI.A.IV.2 8111fnr ContentDovlatlon: I'CIIOI't 

### N/A All roqllh'od 1'011l)l't8

.within 4S-days ofocenrl'ence submlttod PART IIl.A.IV.3 Qlllu'tcl'ly ROIIOI'II ESP Ont-of-Sol'vloo 

### C AI1I'oqub'od reports SlImmnl'lcs sUbmitted PARTI1I.A.IV.4 SomlnnnulIl ReIIOI'I: EgI'ola l'olnt 

### C All reqnh'ed roports Deviation 111\11 CorrcctlveActions snbmltted PART m.A.IV.S Scmlaunnal neporll Dnghousc 

### C' AIlI'cqub'ed 1'lli1ol'ts Dcvlnlloll nnd COI'I'cetlveActlolls submitted l"ARTIII.A.IV.6 Semlnllnual RcpOI'I: Opnelty Deviation 

### C Alll'Cqllh'ed roports lIlId COI'l'cellvcActiolls snbllllUed PAR'l'm.A.V.1.a**EmllSlollle.~tlug** to be condncted 

## C NOIIIl withIn 3-monlhs aftor Ilel'mll Issucd. PART m.A.V.I.b Ji:mlssloll lestlllg: dllmonsh'ato 

### C Noua comlllhl11ecwith PE nnd S02, Opacity PART m.A.V.t.c.1 PE Emission Rate: 40 CllR 1'111'160, 

### C Nouo AIIPcndlx A, Mothods 1-5 PART m.A.V.l.e.1I 20% Opllclly (3-minJ6-mlll nvenges): 

### C Nona 40 CFR 1'111'1 60, APP. A, Metllod !) l'ART m.A.V.I.c.1II 802 Emission Rate: 40 CFR 1'111'1 60 

### C None Alllllllldllc A, Methods 1-4 AIId 6 PART m.A.V.I.d Conduct Emlsslou Tesls at or ncar 

### C Nonq mnxlmum cnllacUles PART llI.A.V.l.o SubmUClrntcnl-to-TCsl" NotJncntlon 

### C NOllc 30 days pl'loI' to pl'oposcd tesl dnto PARTUI.A.V.2.11 AddltlollRllllfol'culltion clIlI'llIg lestlng: 

### C Nouc Sulfur COlltentcanl/eolco blll'ood J'ART 1II.A.V.2.b Addltloul\llufol'lIIatlall chll'lug testlngl 

### C Nonc Powel' II1IHII (kW) ofenehTIl. silt. l'ART III.A.V.3.a ApplicableTestingReqllh'cnlcnlS 

### C Nono PART UI.A.V.3.b AIlllllcnbleTesting Ucqllh'01l1Cllls 

### C None PART 1II.A..V.3.c Appllcnhle Testing Reqnlrcmeuts 

### C Nona 1)ARTIIT.A.V.3.c1**AIIIIII~lIble** Testing Re1lull'emcllts 

### C NonD MIA (Tills (lcrmlt docs not havo ally \ PARTnI.A.VI mlseellRIICOUs rcquh'o11lonls) 

### N/A N/A 

### R. 

## AllY othermaterial information thatmay indicate nOll-compliance with one ormore ofthe abovedescribed applicable requirements for this facility must be describedbelow: Part 

### lIl.A.I.l Deviation RellOl'tS: Due to the safe operation ofthe #1 South**J(ilIl~** 

### all kiln sImtclowns and startup l'equh'e tlte bypassing 

### ofthe ESP control system to prevent clamage and eXlliosion 

### to the control system. Since 

### the stnl'tllp/sl1l1tdown regulation exemptions do not apply to our kiln**operation~** 

### the prol)er procednre is to identify these occurrences as malfunctions. As indicated iu the Quarterly Deviation**Reports~** 

### tile following is a list ofthose times ofshutdown/startup ofthe #1 South Kiln and**"out~of-scrvice~l** 

### days during the reporting period:

.

Martin MRI'letta MlIgneslli**Slle~lnll1es,** LLC Page 29 412512005

### ESP Section Dtll'atlon Both 9-hl's 

### Kiln dmfVcoal fan tt'ipping cil'cllit

### breaker

- low temp. safety trigger Rectifier 

### B 30-nun ShOlt In 

### Rectifier 

### '(B"

- ESPWires Both 

### 7-h1'8 LowTemperatureSafety (Malf1.ll1ction called 2/23/2004) Both 

### 20-min High Combustibles Safety Both 30-min High Combustibles Safety Both lhl'-15min Higll Combustibles Safety Both 3hr-35min LowTemperature Safllty

- Balanced Coal 

### Fall Both 35-min LowTemperature Safety

- Lostfuel supply 

# (



# ( OHIO EPA TITLE V COMPLIANCE CERTIFICATION A. 1st 

### Quartel'Devlatioll Re}>ol't 

### foi- the period ofJanuary 1,2004 through March 31, 2004 

### submitted by AI>ril30, 2004: MaU\mctioll Reports 02/08/2004: ESP Rectifier 

### n Electrical Short, ShutdoWll #1 South !{fIn to Repah'

- t/2004001MR (MIlI'tln Mal'leUaID) 02123/2004: til South Kiln Coal Fall Vlbl'atlon, 

### Shutdown III 

### SO\lth J{lin 

### to Repah' -1!2004002MR (Mal'Un Marietta 11» 03125/2004: ESP RectifierA Electrical 811m'to Shutdown 

### tJ1 SOl\tll T<:IIn 

### to Repair

- tJ2004003MR (Martin MRl'lefta ID) ESP Olit-of-Sel'Vlce 

### 01/06/2004 02/0712004 02/23/2004 03/0612004 03/16/2004 03/20/2004 03/23/2004 03/27/2004


### B. 2nll 

### QU31'tm' Deviation Report for the period 

### ofApril 1, 2004 through June**30~** 

### 2004 submitted by 

## .July 31, 2004:

. Malfunctloll 

### Reports 06/25/2004: Natural Gas 8111)},ly 

### Line, 

### ShutdnWIl ill SontllKlI1I to 

### Repair M fJ200400SMR (Marlin Marietta Ill) 06/26/2004: Stftl'tllP #1 South 1{lhl M iJ2004006MR (Mal'tlll Mal'lettn ID)**~!Iedllle(l** Malntenanco 

### Renol'ts 04/2612004: Scheduled Malutcllllncc- Two Week Lettel' Not1f1callon. Sbutdown til SOlltl1 mItl il2004007MR (Martin Mlll'lettlllD),

. . 05/0212004: Scbechllc!) Maintenance

- Two 'wecl! Lettel' Notlflcatlon, St8l"l1l1>#1 South Kiln IJ2004008MR (Martin 

### Mnrlett.'1ID)



## ( ESP Out·of-Sel'vlcll 

### Date 

### 04/08/2004 

### 04/19/2004 04/22/2004 04/23/2004 05/07/2004 05/08/2004 

### 05117/2004 OS/20/2004 OS/21/2004 06/11/2004 06/12/2004 06/20/2004 

### 06121/2004 06/23/2004 

### 06/2512004 0612712004 ;ESP 

### Section Both Both Both Dotlt 

### Both Both Doth Both Both Both Both Both RectifierA Both Doth 

### RectifiefB Duration 1hr-20minLow Temp./High Combustible Safety

- Coal Supply 

### Fan 

### 5-1u1I Low Temperature Safety

- InconsistentFuel Feed 5-min' High Combustiblo Safety 5-miu Higb Combustible Snfdty Ibr-45min LowTemp.lHigh Comllllstible Safety

- Coal Supply Fan 

### Shr-4Smin LowTemp./High Combustible Safety

- No Fuel Supply 

### 1br Restal'tPower OutageDue to Electrical Storm

- Lightning 45-OOn LowTemp,/High Combustible Safety

- Kihl ID 

### Fan Shutdown 5-min LowTemp./High Combustible Safety

- Kihl ID 

### Fan Shutdown 

### l-lu' Low 1'emp,/High Combustible Safety

- Coal Supply

### Fan 20-mitl High Combustible Safety 5-mul High CQtnbustlble Safety 17hr/30min LowTemp.lHigh Combustible Safety

- OV01' Voltage to ESP 20-min High Combustible Safety 24-Ju' LowTemp.lHlgh Combustible Safety

- Inconsistent Gas Supply 2-min LowTemp./High Combustible Safety

- Power Surge

Martin Marietta Magnesia**Sl)cclnltle~.** LLC Page 30 4/2S/2005

## ( 

# OHIO 

# EPA TITLE V COMPLIANCE CERTIFICATION C. 3 1 '11 

### Quarter Deviation Reportfor tIle period of

## July**1~** 

### 2004 thl'ough September 30, 2004 

## submitted by October**31~** 

### 2004: Malfunction Renorts 07125/20041 Repair Coal SUI)pl)' Fan Bearing, Shutdown #1 South KlIn • f12004010MR 01/26/2004: RepairCoal Snpply Fan Bearing, Shutdown til South I<:Iln • f12004011MR 08/08/2004: 

### 1D Fall Falhu'c, Shutdown ill Sonth 

### Kiln· tlZ004013MR 08112/2004; 

### 1D Fan }rallurc. Stal'tllll fll SOllth KlIlI •fl2004014MR 09107/2004: RepairCoal Snpply Fan- SJmtclolVlI ill SOllth KlIII

- flio04016MR 09/07/2004; RCIIlIlrCoal SUPl11y Fan

- Stlll·tlll> til South 1(Ihl

- tl2004017MR ;ESP Ont-or-Servlce 

### Date 08/0112004 08115/2004 08/17/2004 

### 08/18/2004 08/22/2004 08/25/2004 09/03/2004 

### 09/05/2004 09/06/2004 

### ESP Section 

### Both Both 

### Both Both Both 

### Both Both Both Both 

### )}uratlon 

### 5-min Low Temp.lHigh Combustible Safety 20-mill Low Temp./High Comhustible Safety 15-min LowTemp./High Combustible Safety 10-mill Low Temp./Higlt Combustible Safety 5-min Low Temp./HighCombustible Safety 7-min Low Temp./High Combustible Snfety 5-min Low Tomp.lHigh Comhustible Safety I**O~mil1** 

### Low Tomp./High Comlmstible Snfety**10~mil1** 

### Low Temp.lHigh Combl1stible Safety


# ( D. 4th 

### Quarter Deviation Report for tIle 

### pel'lod ofOctober 1,2004 through December 31, 2004 submitted 

## by January**31~** 

### 2005: Malfunction Reports 10120/2004: Coni Slll>ply Fall Housing Repah'

- Shutdown/11 SOlltll Kiln· #2004019MR 10/2012004:**C~al** &11>pl)' Fall Housing Rellal\'- Stal'tnl) #1 

### South**Klh~** 

### •i12004020MR 10/23/2004: Replnce

## mFnn

- Shutdown illSouth Kiln· il2004021MR 10127/2004: Rc)l1ncll

## mFan

- Startlll) til South min

- il2004022MR 11/29/2004: Rebalance Coal FRl1lRcpnll'In Fall

- Slmtdown/Stnl·tup til South mill. tJ2004023MR 12121/2004: Repah' Coni Fall- SJmtdown/Startul) tit Soutil Kiln· i/2004024MR



# ( .,' ESP Ollt-oC-Serylce


## , !lilli! 10/1712004 

### 10/19/2004 10/20/2004 10/22/2004 11101/2004 11106/2004 11108/2004 11/14/2004 

# t"1122/2004 1113012004 12106/2004 1211012004 

### 12/13/2004 12/15/2004 12/16/2004 

### ESP 

### Section 

### Both Both 

### Both Both Both Both 

### Both Both Both Both 

### Both Both Both 

### Both Both Duration 

### 35.,mill Required cleaning ofID Fan 5·min LowTemp.tHigh Combustible Safety 20-mill Lostpowel' to ID 

### Fan \ 1**~hr** 

### Req\lit·oc1 balancing the COllI flln 

### 10·l11itl LowTemp./High Combustible Safety 10-min LowTemp./Higll Combustible Safety 5-min· Low Temp.lHigh Combustible Safety 20-min Required cleaning ofID Fan 1**O~min** 

### Lostpower to ID 

### Fan lO-min Lost

### power to ID Fan 5-min LowTemp.lHigh Comhustible Safety 1hr/40min LowTemp.lHigh Combustible Safety 5-min Low Temp.lHigh Combustible Safety 10-min Low Temp./High Combustible Safety is-min Low Temp./High Combustible**~nfety**

Mal'lIn Mal'letta Magllcsla Sl'el:laltlcs, LLC Page31 4/25/2005

# ( OHIO EPA TITLE V COMPLIANCE CERTIFICATION Compliance Certification Section IV

- SignificantEmissions Units Terms and Conditions (Partill ofthe Permit) Complete this section oftile form fOl' each signifieant emissions 

### unit. EmIssions units with 

### Identical terms Ilnd conditions may be gl'oupcd together (Sec "Compliance Certification Section IV" unde)' the "Clarifying Instructions" at tbe cud ofthis document for hnp()rtant additional information ill filling out tills pal't ofthe form.)


### H. 

## SignificantEmissions Ul1it ill [

## 4characters]: P019 

# r. Provide for each term and conditiQn in PartlILA 

## "State and Federally Enforceable Section" for the emission unit, by 

## appropriateparagraph citation, abrief

## statement ofhow certification ofcompliance has been determined for each term and condition and asummary ofall excursions/deviations thathave occurred during the compliance certification period. 

## Please addrows as neceSSQ1Y 

## for eachEmission limitation/ControlMeasure specifiedin PartIII.A.Ll of thepermit. Idemtl/)' the Emlssloll COlllhlllOIlS (C) L1l1lllatIOII/Contl'ol Molhod Uscel to Dolel'mlno Mcns\II'e 01' tllO l'el'mlt COllllllla\lce< 01' Inlol'mlttent ExcurslonslDevlnllolls Tel'mNo. (I) COlllllllallco?' '1'hose Documouted Within ExcUl'$lon/Dovlntlou Other (Explnln Iho Natul'c, DUl'Rtluu, nellOl'IS Submitted 10 anel CaUSD oftile Excul'slonlDevlallou, OEI'A Dlstl'lct Omce As Well As Any CUl'l'ccllveAction 

# ( orLocal All' Agency Taken) (Idontlfy Dnle ofEnell 

## no ort I'AR'r IlI.A.l.1 Inslloetlons 5 da3's/wook-mllllmuln 

### C None OAC 3745-17-07(A) PARl'II1.A.I.l PE Lhultnllun: 79.9Ib/bl· (Comblneel) 

### I Mnlt\mctlou RellOl'ls OAC 374S-17.11(B) I'ART IlI.A.I.t 802 LhllUallon: 25.0 III 802110n of 

### I MnlfllucUIln Rcpol'ls OAC 3'14S-18-78(F) IlI'educt l'ART 1lI.A.I.l Inspections 5 dnys/wecle

- IIIbJlunun 

## C NOllo OAC 374S-17-07(B)(t) PAR1' m.A.I.l Emliloy RACM: IU.A.I.Z.b 

## C NO,no OAC 374S-17-08(D) \ PART IlI.A.U.n OAC 3745-11-11 (A)(3)1 Comblnll PE 

### C None omissions fl'onl 1'015 nnd POl!> PART UJ.A.J.2.b.1 ItA-CMI Enclosures (Bnlldlngs) nud 

### C Noue huodlng to mlnlmlzo fuglllvil emissions PART IIl.A,U,b.1I HACMI All fllgillvo dust capllll'ed 

### C None within building

- vontto bh tI108S PART IlI.A.II.i Mlllutnin PI'cssln'enroll Across 

### C NOlie Daghollse: wltbln ll·1(j Inehcs watel' PARTJIJ.A.II.2 0111)' coni, Illltrolcnnl colle, ami/or 

### C None naillral gas shall be blll'lIed. PART m.A.II.3 SlIlCln' Content IIfConi/Coke: less IIlml 

### C NOlie COlllolI! measm'cd at lIIOS! recent lesl 

### ,'. Mailltain and Reeol'd PI·essUI'e Drop: 

### .:.:. PART III.A.m.l Frcquency: WccldY-lulnlmlllll 

### C None PAR'rIII.A.III.2 Snmples ofcOIIVcokel analyze for 

### C NOlie SlIlful' contentand hcnt content. 

## ( PART III.A,III.3 Mailltnhllllllllibly: tolnl qunntlty of 

### C Noue c1l8Vcoko I'ecelvedj annlytlenlreaults PART III.A.III.4 ElIl'ess Polnls: VE Observation 

## C NOlie Inspections 5 days/wcek

Marttll Marietta Magnesia Speclaltlcs, LLC Page 33 412512005

## (



# (

( 

# OHIO EPA TITLE V COMPLIANCE CERTIFICATION PAlrr IJI.A.m,5 Baghollsc: VE Obsel'vntlon 

### C Nonc Inspcctlolls 5 dny./week PART m.A.IV.l Quartel"y Repol't: PI'esSIII'CDl'op 

### C**Alll'I~qulrcd** I'CPOI'tS. Deviation and COrJ'ccllvllAetiOIl 811IJmltteli PART III.A.IV.Z Ji'uol Type BIII'ned Dcvlatloll; I'eport 

### N/A All rcqnh:ed rOllorls wlthlll 3D-days ofocelll'l'cnco slIlJtllltled PART m.A.IV.3 S"lflll' COlltClIt Dovilltlon: I'CPOl't 

### N/A Alll'oqllh'cd I'eports within 4S.days ofocelll'l'enco submitted PARTIII.A.lV.4 Semlnllnllnl RepOIt: :Egrcss Point 

### C All I'cquh'Olll'oporls Deviation and COl'l'ectlvc Actlons slIbmillcd I'AR1' III.A.IV.5 8cl\lloullllol Ropol't: nnllllollso 

### C Alll'eqllil'clll'cl'orts I>ovlntlon alld COl'l'ocllve Actlolls submlttcd PART 1II.A.IV.6 80111111111111111 Rcpol't: Opllclty Devlnlloll 

### C Alll'cqllh'cd I'cports lind Corl'octlveActions**8l1blllllt~d** PART lII.A.V.1.u Emlssloll testlug to be cOlldllcted 

### C None wlllllll 3-1\I01lths artel' pCl'llllt IsslIcd. PART III.A.V.l.b Emlssloll testlllgi domollsh'nte 

### C NOlie cOllllll1ullcelvlth PE nlld 802, Opnclty PAltT III.A.V.l.c.1 l'E Emlsslou Rntcl 40 CFRPm't 60, 

### C Nona Allpelldlx A, Methods 1-5 PART IlI.A.V.t.c,lI 20% OpacIty (3-lIIlu/6-1II111 avcl'ages): 

### C Nono 40 CFR l'ort 60, AIIII, A, Mcthod !) PART UI,A.V.I,e,U1 SOZEmlsrlou Rnto: 40 CFR l'ort 60 

### C NOlie Apllllndix A, Methods 1-4 ond 6 PART flU.V,I.d Condllr.tElIllsslon Tests at 01' IIcar 

### C NOllo maxi 11111111 capacities l'AR'r flU.V.l.o Submit Ulutent·to-Tcst" Notification 

### C NOlie 30 doys prlol' to Il1'ollosed test doto PARTm.A.V.2,a AddltionallnrOI'II\I\t!OIl during t051lng: 

### C NOIlD Pl'CSSl\l'ODI'OII OCI'OSS bnllhollsll PART IIU.V.2,b AddltloRlIl hlfol'llIatioll dlll'llIlI testing: 

### C Nonl) Sulflu'Contellt eool/coko blll'lIcll PARTm,A.V.3.1\ AppllcobleTesllng Uel}nlJoelllcnt 

### C None I'ART m.A.V.3.b AllllllcnbleTesting Rcqllh'cmellt 

### C None PAR,}' m.A.V.3.c Applicable Testlug Rcqllh'oment 

### C Nonc PART IlI.A.V,3.d A\lpllclIblaTesting**llcqlllr~lIIelll** 

### C NOllc



# . \ l'ART II1.A.VI N/A (This Ilel'mltdocs 1I0t hllVIl nny 

### N/A N/A IItisecllllncOIis l'eqlllrelllclIls) 

### J. 

## Any othermaterial information thatmay indicate non-compliance with one ormore ofthe above

- described applicablerequirements for this facility mustbe described below:

Part

### nI.A.I.t DevintJoli Reports: Due to the safe operution ofthe #2 Sonth KilJ1 t 

### kiln startup reqnires the bypassing ofthe BaghOlise contml system to prevent damage and explosion to tile control system. Since the startup/shutdown regulation exemptio.ns do not apply to our 

## kiln operationt the propel' procedure is to 

### idclltify these occurrences as malfnnctions. As Indicated in the 

### Quarterly Deviation Reports, the following is a list ofthose times ofstartup ofthe #2 South Kiln during the reporting pel'fod:

MnrtinMarietta Mngnesla Sileelnltics. LLC Page 34 4/25/2005

# ( 01110 EPA TITLE V COMPLIANCE CERTIFICATION Mnlfllllctloll Rlm0l'fS 04/1712004: StOl'tll}) No.2 Soutll I{llll- i12004004MR (Mal'tln Marletta ID) 07120/2004: RcpflirConi Supply Fall. Stal'tlllJ #2 Sontll Kiln

- #2004009MR 08/04/2004: RCIJalt· I<:lltlTJ1mlon. Stal'tup #2 Soutll mIn· #2004012MR 08/13/2004: ID Supply Fall Repah'

- Startllll #2 S01ltb Kiln· i12004015MR 10/0612004: RCllah' Coal SUllply Fan

- BYllaSS il2 Soutb min· iJ2004018MR



# (

(

Mlll'lIn Marietta Mllgncsla Slleclaltlcs, LLC Pagc35 4/25/2005

# ( 

# OHIO EPA TITLE V COMPLIANCE CERTIFICATION

Compliance Certification Section I - Facility Information
Complete this section ofthe form only once for the facility (See Compliance Certification Section IV uDder the Clarifying Instructions at the end ofthis document for important additional information in filling out this part ofthe form.) 

### A.. 

### B. 

## C. 

## D. E. 

# ( Facility Name: 

### Martin Marietta Magnesia Specialties, LLC Facility Address: '55 Lime Road, Woodville, 

### Ohio 43469 Facility 

### ID[IO digits): 

### 03-72-00-0127



# --------------------- Date ofTitle V Permit Issuance: 06/20/03 

# ;....;..-..;.,;..,:-------------- Reporting Period: 

### January through Decembel' of2003 

## Compliance Certification Section II

- General Terms and Conditions (Part I ofthe Permit) Complete this section ofthe COI'm only once for the facility (See Compliance Certification Section II under the Clarifying Instructions at the end oftbis document for important additional Information in filling out this pal't oftbe form.)


### F. Has your company complied with all the General Terms and Conditions stated in Part I(A) ofthe Title V permit?**~YES** 

### NO 

### Ifno, indicate the paragraph number for each General Term and Condition for which compliance was not maintained, a description ofthe excursion/deviation, and a description ofthe corrective action that was takento ensure that compliance will be maintained in the future.



# ( Pel'lnlt TernaNo. DeserlptloD ofExeurslonlDevlatlon Correetlve Aetion Taken

Martin Marietta Magnesia Specialties, !,LC Page 1 04/1512005

## ( 

# OHIO EPA TITLE V COMPLIANCE CERTIFICATION Compliance Certification Section III

- Facility Terms and Conditions (Part II ofthe Permit) Complete this section oftbe form only once for the facility (See Compliance Certification Section III under the Clarifying Instructions at the end ofthis document for important additional information in filling out this part ofthe form.) 

### G. Provide for eachterm and condition 

### in Pal't ILA "State and Federally Enforceable Section", by appropriate paragraph citation, a briefstatement ofhow certification ofcompliance has been determined for eachterm and condition and a summary ofall excursion/deviations that have occurred during the compliance certificationperiod.

. 

### Please place an "X" in only one ofthe two options below 

## N/A Each lEU listed In Part U.A oftile Title V permit has complied with elleh applicable requirement established In the listed Permit to Install (pTI) and each applicable requirement spedficd III OAC Chapter 3745-17, OAC ChApter 3745-18, and/or OAC Chapter 3745-21. Except as Indicated for each lEU 08ted In the fllDowlng table below, each lEU listed in PartII.A orelle Title V permit has complied with each 

## N/A applicable requirement established In tbe listed Permit to"lnstall (PTI) and each applicable requirementspeelfled In OAC Cllapter 3745-17, OAC Chapter 374S-18,lInd/lIrOAC Chapter3745-21. (Please identify each intermittentcompliant lEU in aseparate row In the table below as applicable.)

Identify the Emission Lhnltatlon/Colltrol Measure or tbe Permit Term No. Method Used to Deterndue Compliance' Continuous (C) orIntermittent (I) Compliance?' ExeurslonslDeviations 

# (

Partll.A.l 40

### cm Part63.53 (NESHAP) 

### C 40 CFR Pt 63;AAAAA Pal't I Application Submittal Partll.A.2 40 CFR Part 63.53 (NESHAP) 

### N/A 40 CFR Pt63;AAAAA Part II Application Submltta! PartII.A.3.a NESIIAP

- PartII; Initial Notification 40 CIIR Pt 63;AAAAA within 120 days after Subpart 

### N/A PI-omul atlon Pal'tII.A.3.b NESHAP

- Compliance Status 40 CFR PI 63;AAAAA Notlfieation; 60-days following 

## N/A re ulred eom lIance demonstratllln Those Documented Within· ExcurslllnJDevlatilln Reports Submitted to OEPA District Offiee or Local Air Agency (Identify Date ofEaeh Re ort Part I Application Submitted Prior tll

Mil 152002 Other (Explain the Nature, Duration, and Cau8e ofthe ExcursionIDevlatlon,

As Well As Any Correctlvc Action Taken)



## ( H. Any other material information that may indicate non - compliance with one 01' 

### more ofthe above

- described applicable requirements for this facility must be described below: 

### There was no other material information to the best ofour knowledge!

Martin Marietta Magnesia Specialties, LLC Page2 0411512005

## ( 

# OHIO EPA TITLE V COMPLIANCE CERTIFICATION Compliance Certification Section IV

- Significant Emissions Units Terms and Conditions' (Part III ofthe Permit) Complete this section ofthe form for each significant emissions unit. Emissions units with identical terms and conditions may be grouped together (See "Compliance Certification Section IV" under the "Clarifying Instructions" at the end ofthis document for important additional information in filling out this part ofthe form.) 

## POlS Q. 

### Significant Emissions Unit ID [4 characters]:



# -----------------------

(

( R. 

### Provide for eachterm and condition in 

### Part ill.A "State and FederallyEnforceable Section" for the emission unit, by appropriate paragraph citation, a briefstatement ofhow certification ofcompliance has been determined for eachterm and condition and a summary ofall excursions/deviations that have occun'ed during the compliance certificationperiod. 

## Please addrows as necessary for eachEmission /imitation/ControlMeasure specifiedin PartIlLA.Ii 

## of thepermit. Identifythe Emission Continuous (C) UmltatloDlCllDtrol MethodUsed to Determine Measure orthe Permit Compliance

# . orIntermittent Exeurslons/Devlatlons Term No. (I) Compliance?' Those Documented Within ExcurslonlDevlation Other (Explain the Nature, Duration, RepOl·ts Submitted to and Cause ofthe ExcurslonlDevlatlon, OEPA District Office As Well As Any Correctivc Action orLocal Air Agency l'aken) (Identify Date ofEReh Re ort PART llIoA.I.1 Inspections 5 days/week

- minimum 

### I Malfunctlons/Out-ofOAC 374S-17-61(A) Sel'Vleej See Below PART rIJ.A.1.I PE UndtRtlon: 79.9Ib/hr (Combined) 

### C None OAC 3745.17-II(B) PART llI.A.I.l 802 Limitation: 25.0 Ib 802/ton of 

### C None OAC 374S-IS-7S(E)(I) product PART III.A.I.l Inspections 5 daysfweek

- minimum 

### I MRlfunctlonHlOut-ofOAC 3745-17-67(B)(I) Service; See Below PART 1lI.A.I.l Employ RACM: I1I.A.I.2.b 

### C None OAC 3745-17-08(8) PART IILA.I.2.a OAC3745·17·11 (A)(3): Combine PE 

### C None emissions from PO)5 and POl9 PART 1II.A.1.2.b.1 RACM: Enclosures (Buildings) and 

### C None hooding to minimize fugitive emissions PART 1lI.A.I.2.b,lI RACM: All fugitive dustcaptnred 

### C None wltllin building

- vent to ESP#0836 PART IILA.I1.1 Only coal, petroleumcoke, and/or 

### C None natural gas sllall be burned. PART III.A.II.2 SulfurCoutentofCoaUCoke: less tban 

### C None content measured at mostreeent test PART IILA.III.) Samples ofeoalleoke: analyze for 

### C NOlie sulfurcontentand heatcontent. PART IlloA.I1I.2 Mainhiln monthly: total quantity of

. 

### C None coal/coke received; analytical results PART III.A.IIJ.3 Egress Points: VE Observation 

### C None Inspections 5 days/week PART IILA.IlI.4 ESP: VE Observation Inspections 5 

### C None dayslweek PART III.A.I1I.S ESP Opacity Observation: once/month 

### C None 40 CFR Part 60, App. A, Method 9

Martin Marietta Magnesia Specialties, LLC Page3() 04/1512005

## (



# c

( OHIO EPA TITLE V COMPLIANCE CERTIFICATION
PART III.A.III.6 CLARII1ICATION PARAGRAPH 

## N/A NlA
PART I1I.A.IV.1 Fuell'ype Burned Devilltion; rcport 

## N/A All required reports within 30·days ofoccurrence submitted PART I1I.A.IV.2 Sulfur ContentDeviation: report 

## N/A All required reports within 45·days ofoccurrence submitted PART III.A.IV.3 Quarterly Report: ESP Out-of·Service 

# e All required reports Summaries submitted PART IILA.IV.4 SellliamlUsl Report: Egress Point 

# e All required reports Devialion and Corrective Actions submilled PART I1I.A.IV.S SemiannualReport: Baghouse 

# e All required reports Deviation and Corredive Actions submitted PART III.A.IV •.6 SemiannualReport: Opacity Deviation 

# e All required reports and Corrective Adions submitted PART IILA.V.l.lI Emission testing to be condncted 

# e None within 3·months after permit Issued. PART III.A.V.I.b Emission testlug: demonstrate 

### C Nooe compliance with PE and 802, Opacity PE Emission Rate: 40 CFR Part 60, , PART III.A.V.I.c.1 Appendix A, Methods 1-5 

### C None PART lILA.V.I.c.1i 20% Opacity (3-miJI/6-min averages): 

### C None 40 CFR Part 60, App. A, Method 9 PARTliLA.V.I.cJII S02 Enllsslon Rate: 40 CFR Part 60 

# e None Appendl. A, Methods 1-4 and (; PART 1II.A.V.I.d Conduct Emission Tests lit or near 

# e None maximum capacltlcs PART I1I.A.V.I.e Submit "Intent-to-Test" Notification 

### C None 30 days prior to proposed tcst date PART I1I.A.V.2.a Additionalinrorlllatlon during testing: 

### C None SulfurContent coal/coke burned PART III.A.V.2.b Additional Information during testing: 

### C None Power Input (kW) ofeach "fR set. PART IlI.A.V.3.a Applicable Testing Requirements 

# e None
PART IILA.V.l.b Applicable Tes.ling Requirements 

### C None PARTIILA.V.3.e Applicable Tesllug Requirements 

### C None PARTlII.A.V.l.d Applicable Tesling Requirements 

### C None PART IILA.VI N/A (ThiJI permit does not have any 

## N/A N/A miscellaneous requirements) 

### S. Any other material information that may indicate non-compliance with one or more ofthe abovedescribed applicable requirements for this facility must be described below: Part I1I.A.I.1 Deviation Reports: Due to the safe operation ofthe #1 South Kiln, all kiln shutdowns and startup require the bypassing ofthe ESP control system to prevent damage and explosion to the control system. During the 3rd 

### Quarter, and as indicated in the 3rd 

### QuarterDeviation Report, the following is a list ofthose times ofshutdown

## 1st artup ofthe #1 South Kiln: A. 3rd 

### Quarter Deviation Report for the period ofJuly 1,2003 through September 30,2003 submitted by October 31,2003:

Martin Marlelta Magnesia Spel:ialties, LLC Page 31 04/1512005

# ( OHIO EPA TITLE V COMPLIANCE CERTIFICATION

7/01/03· Ii South Kiln: '1 Cooler Belt Malfunctioned, placed kiln on auxiliary power - removed solid fuel- 9 hours 7/08/03 -'1 & #2 South Kilns: Fire In Ball Mill Room cuased emergency shutdown of both kilns - 6 hours; 20 minutes to shutdown. 7/11/03 -'1 South Kiln Startup: ESP on bypass to reheat kiln until kiln reached operating temperature ·13 hours 7/25/03 ·'2 South Kiln Startup: Baghouse on bypass to reheat kiln until kiln reached operating temperature· 41 hours. 8/14/03

- Full Plant Power Outage· result of northeast grid ·10 minutes for plant (est.) • affected .1 South Kiln for 5 hours. 8122103

- Power Outage· Electrical storm downed Toledo Edison's lines. Affected'1 &'2 South Kilns 9 hours· Restarted '2 Kiln only. 8/30/03 •Ii South Kiln Startup: ESP on bypass to reheat kiln until kiln reached operating temperature· 13 hours. 

### B. 4th 

### QuarterDeviation Report for the period ofOctober 1, 2003 through December 31,2003 submitted by January 31, 2004: ' 11/22103: E;SP Rectifier B Electrical Short., Shutdown Ii South Kiln to Repair. ,2003015MR (Marttn Marietta 10) 1211/03: ESP Broken Module Wires. Shutdown .1 South Kiln to Repair. '2003010MR (Martin Marietta ID) 1214J03: Rectifier A· ESP electrical short. Shutdown #1 South Kiln to repair
- ,2003011MR (Martin Marietta 10) 12/10/03: ESP Module Electrical Problems. Shutdown #1 South Kiln to Repair
- .2003012MR (Martin Marietta 10). 12121/03: '1 South Kiln 10 Fan Repair/Balance. Shutdown '1 South KUn
- '2003013MR (Martin Marietta ID) 12127/03: ESP Module Electrical Problems. Shutdown'1 South Kiln to Repair· '2003014MR (Martin Marietta 10)


### Due to the safe operation ofthe #1 South Kiln, the ESP control system is protected by a high and low fuel combustibles safety shut"offto prevent damage to the ESP system. Therefore, the following "out-of"service" days during the reporting period is as follows: 

# (

('. 8/212003 8/3/2003 8/412003 8/6/2003 8/14/2003 811512003 8/19/2003 8/2212003 9/212003 9/3/2003 9/4/2003 9/18/2003 9/20/2003 Date 6/28103 7/112003 7/3/2003 7/612003 7/6/2003 7/21/2003 7/22/2003 7/23/2003 7/25/2003 7/27/2003 7/28/2003 7/30/2003

Both Both Both Both Both Both Both Both Both Both Both Both Both ESPSectlon Both 80th 80th Rect.B

Both 80th 80th 80th 80th Both Both Both

45min 20min 10mln 40min 5hrs 15min 8hrs-30min 9hrs 40min

1hr 2min 3mln 1hr-20mln Duration 1hr High combustible safety analyzer malfunctioned 1hr-20min. High combustible safety analyzer malfunctioned

5mln High combustible safety analyzer malfunctioned 35min Electrical Shortout 40min High combustible safety analyzer malfunctioned 4min High combustible safety analyzer malfunctioned

1hr Coal valve and fan unbalanced 4hrs Coal valve and fan unbalanced
- main!. Patched fan 20mln Temperature safety damper malfunctioned 30min High combustible safety analyzer malfunctioned 55min High combustible safety analyzer malfunctioned 10mln High combustible

### s~fety analyzer malfunctioned High combustible safety analyzer malfunctioned High combustible safety analyzer malfunctioned High combustible safety analyzer malfunctioned High combustible safety analyzer malfunctioned Power outage High combustible safety analyzer malfunctioned Kiln drive malfunction
- auxiliary fire
- no solid fuel
- no VE Power outage High combustible safety analyzer malfunctioned Coall.D. fan maintenance
- auxiliary file
- no solid fuel- no VE High combustible safety analyzEir malfunctioned High combustible safety analyzer malfunctioned Kiln drive malfunction
- auxiliary fire
- no solid fuel· no VE

Marlin Marietta Magnesia Speelaltles. LLC Page 32 04/151200S3hrs-35mln Kiln drive malfunction auxiliaryfire
- no solid fuel
- no VE 35mln High combustible safely analyzer malfunctioned Both Both 

# OHIO EPA TITLE V COMPLIANCE CERTIFICATION 9/23/2003 9/25/2003 

# (

10/6/2003 10/10/2003 10/1412003 11/3/2003 11/4/2003 11/5/2003 11/6/2003 11/18/2003 11/20/2003 11/21/2003 11/28/2003 11/30/2003 12/1/2003 121212003 12/4/2003 12/6/2003 12111/2003 12/19/2003 12/21/2003 1212712003 Both Both Both Both Both Both Both Rect.A

Both Both Both Rect.B

Both Both Both Both Both Both Both Both 1Q-mln 30·mln 5-mln 10-mln 5·mln 5·mln 5·mln 24-hr 5-min 5·min 3·hrs 24·hr 20-hr 5·hr 18-hr**1~mln** 15-mln 8-min 20-hr 12-hr High combustibles safety device
- coal fan repair· kiln on auxlJlary High combusllbles safety device High combustibles safety device High combustibles safety device High combustibles safety device High combusllbles safety device Analyzer Malfunclloned
- Safety ESP Rapper electrical problem ESP Module Electrical Wire Problem High combustibles safety device Maintenance on Coal and ID fan· kiln on aUlllJlary power ESP Rectifier B electrical problem ESP wire repair
- kiln shutdown Kiln trunlon repair. kiln on aUXiliary power Repairwork on kiln
- kiln shutdown High combusllbles safety device High combusllbles safety device Analyzer Malfunctioned
- Safety ID Fan repair
- kiln shutdown ESP broken wires kiln shutdown 

### (



# (

Martin Marietta Magnesia Speeialtles, LLC Page 33 0411.512005

# ( 

# OHIO EPA TITLE V COMPLIANCE CERTIFICATION Compliance Certification Section IV

- Significant Emissions Units Terms and Conditions (part III ofthe Permit) Complete this section ofthe form for each significant emissions unit. Emissions units with identical terms and conditions may be grouped together (See "Compliance Certification Section IV" under the "Clarifying Instructions" at the end ofthis document for important additional information in filling out this part ofthe form.)



## F. Significant Emissions Unit 1D [4 characters]: 

## POl9



# (

( G. Provide for each term and condition in 

### PartUI.A "State and Federally Enforceable Section" for the emission wit, b'y appropriate paragraph citation, a

# l!!!!1 statement ofhow certification ofcompliance has been determined for eachterm and condition and a summary ofall excursions/deviations that have occurred during the compliance certification period. 

## Please addrows as necessary for eachEmission limitation/ControlMeasure specifiedin PartIILA.Li 

## of thepermit. Identify the Emission Continuous (C) limitation/Control Method Used to Detel'Dllne Measure orthe Permit Compliance' or intermittent Excursions/Deviations Term No. (I) Compliance?' Thosc Doeumcnted Wltltln ExcurslollJDevlatlon Other (Explain the Natul"c, Duration, Reports Submitted to and Cause ofthe ExcursloDJDevlatlon, OEPA Dlstl'let Office As Well As Any Corrective Action or Local Air Agency Taken) (Identify Date ofEach Re ort PARTIII.A.I.1 Inspeetions S days/weck- minimum 

### I Malfunction Reports OAC 374S·17·07(A) PART III.A.1.l PE limitation: 79.9 'b/br (Combined) 

### C None OAe 3745·17·ll(D) PART m.A.I.l 802 Limitation: 25.0 Ib S02/ton of 

### C None OAC 374S-18-78(F) product PART 1Il.A.I.l Inspections 5 days/week

- minimum 

### I Malfunction Reports OAC 374S-17-07(8)(I) PART III.A.I.l Employ RACM: III.A.I.2.b 

### C None OAC 374S-17-08(B) PART III.A.I.2.a OAC374S-17-U(A)(3): Combine PE 

### C None emissions from POlS and P019 PART III.A.I.2.b.1 RACM: Enclosures (Buildings) and 

### C Nonc hooding to minimize fugitive emissions PART III.A.I.2.b.1I RACM: All fugitive dust cllptured 

### C NOlie within builcllng

- vent to bh #1085 PART IIU.n.1 Maintain Pressure Drop Across 

### C None Baghouse: within 6-16lnehes water PART III.A.II.2 Onlyeoal, petroleum coke, and/or 

### C None natural gas shall be burned. PART mA.II.J Sulfur Content ofCoal/Coke: less thaR 

### C None eontentmeasured at most recent test PART m.A,1I1.l Maintain and Record Pressure Drop: 

### C None Frequeney: Weekly

- minimum PART 1II.A.III.2 Samples ofeoal/eoke: analyze for 

### C None sulfur content and heat content. PART m.A.III.3 Malntllin monthly: total quantity of 

### C None eoalJeoke reeeived; analytical results PART III.A.IIM Egress Points: VE Observation 

### C None Inspections S days/wcek

Marlin Marietta Magnesia Specialties, LLC Page 35 04/1512005

## (



# (



# ( OHIO EPA TITLE V COMPLIANCE CERTIFICATION
PART III.A.III.5 Bagltollse: VE Observation 

### C None Inspedlons 5 daysJweek PART III.A.IV.I Quarterly Report: Pressul'e DI'op 

### C All required reports Devlatlou and Correetive Adion submitted PART III.A.IV.2 Fuel Type Burned Devlafion; repol't 

### N/A All required reports within JO-days ofoeeurl'enee snbmltted PART III.A.IV.3 SulfurContent Deviation: report 

### N/A All required reports within 4S-days ofoceurrenee submitted PART III.A.IV.4 Semiannual Report: Egress Poillt 

### C All requlred reports Deviation and COl'reellve Acfions submitted PART III.A.IV.S Semiannual Report: Baghouse 

### C All required reports Deviation and Correetlve Actions submitted PART IlI.A.IV.6 Semiannual Report: Opacity Deviatioll 

### C Ali required reports and Correetive Actions submitted PART In.A.V.I.a Emission testing to be coududed 

### C None within J-montbs after permitIssued. PART III.A.V.l.b Emission testing: demonstrate 

### C None compliance wltb PE and 802, Opacity PART III.A.V.l.c.1 PE Emission Rate: 40 CFR Part 60, 

### C None Appendix A, Methods I-S PART IILA.V.1.c.1I 20% Opaeity (3-mio/6-min averages): 

### C None 40 CFRPart 60, App. A, Method 9 PARTIII.A.V.I.c.ii1 S02 Emission Rate: 40 CFR Part 60 

### C None Appendill: A, Methods 1-4 and 6 PART IlI.A.V.l.d Conduct Emission Tests at or near 

### C None maximum eapacitles PART III.A.V.l.e Submit "Intent-to-Test" Notlftcatlou 

### C None JO days priorto proposed test date PART IlLA.V.2.a Additional informallon during tesllng: 

### C None Pressure Drop across bagbonse PART liLA.V.2.b Additional Information dul'1ng testing: 

### C None Suiful' Contentcoal/coke burned PART 1II.A.V.3.a ApplicableTesting Requirement 

### C None PART III.A.V.3.b Applleable 'festing Requirement 

### C None PART liLA.V.J.e Applicable Testing Requlremellt 

### C None PART III.A.V.3.d Applicable Testing Requlrement 

### C None PART III.A.VI N/A (This permit does not have any 

### N/A N/A miscellaneous requirements) 

### H. Any other material information that may indicate non-compliance with one or more ofthe abovedescribed applicable requirements for this facility must 

### be described below: 

### Part III.A.I.t Deviation Reports: Due to the safe operation orthe #2 

### South Kiln, kiln startup require the bypassing oCthe Baghouse control system to prevent damage and explosion to the control system. Since the startllp/shutdown regulation exemptions do not apply to our kiln 

### operation, the proper procedure is to identitY these occurrences as malfunctions. During the 3rd 

### Quarter, and as indicated in the 3rd 

### QuarterDeviation Report, the following is a list ofthose times ofstartup of the #2 

### South Kiln: 7/08103 -'1 & '2 South Kilns: Fire In Ball Mill Room cuased emergency shutdown of both kilns· 6 hours; 20 minutes to shutdown. 7/25/03 -'2 South Kiln Startup: Baghouse on bypass to reheat kiln until kiln reached operating temperature. 41 hours. 8J22/03 • Power Outage· Electrical storm downed Toledo Edlson·slines· Affected'1 & #2 South Kilns 9 hours· Restarted #2 Kiln only.

Mllrtlo Marietta Magnesia Speeiallles, LLC Pnge36 04/1512005

# ( Martin Marietta

# =M=a=9=n=e=s=l=a=S=p=e=c=l=a=lt=ie=s:::,=L=L=C==========**==~**
755 Lime Road, Woodville, OR 43469 USA Telephone: (419) 849-4200 Fax: (419) 849-4246


## October 2,2006 Jim Orlemann, Manager Division ofAil' Pollution Control Ohio Environmental Protection Agency Lazarus Govt. Center P.O. Box 1049 Columbus,OH 43216-1049
RE: OAC 3745-17-07 SIP Exemption Request for Martin Marietta Comments on OEPA's September 15tll 

### Interested Parties DRAFT 

## Dear Mr. Ol'1emann:
On September 15,2006, the Ohio Environmental Protection Agency provided draft language proposing a rule exemption for Martin MariettaMagnesia Specialties, LLC ("Martin Marietta") from the requirements ofO.A.C. §3745-17-07(A) during start-up and shutdown ofUme producing kilns at Martin Marietta's Woodville, Ohio facility ("Woodville facility"). Consistent with our September27t11 

## telephone conversation. Martin Marietta submits the following comments on this "interestedparties" DRAFT. First, Martin Mariettarespectfully requests that Ohio EPA delete the phrase "with a solid fuel" from subsection (A)(3)G)(ii) so that firing priorto the introduction ofsolid fuel will also be exempted. Our standard start-up procedure has stone feed beginning a couple hours before the solid fuel addition. This startup sequence was previously demonstrated by our 12115/05 submittal, which included a4/29/05 kiln log for the #1 kiln-ESP unit. Thus, the needed language would read: (ii) 

### The start-up ofany kiln equipped with an electrostatic precipitator, fl:om the time firing [DELETE

- with a solid fuel

- DELETE] begins until a stable firing condition is achieved, butnot longerthan six. hours from the time firing with a solid fuel begins. 

## Martin Marietta also requests that Ohio EPA add anew subparagraph (iv) to address shutdown oridling ofthe #1 kiln-ESP unit. As explained in Martin Marietta's 8/24/06 letter, the 2003- 2005 compliance certification malfwlction reports for both kilns showed a number of "shutdowntl 

## notifications.

## !
,



# (

( OAC 3745-17-07 SIP Exemption Request for Martin Marietta October 2, 2006 

### Page 2 of3 

### Though a kiln shutdown will usually be associated with a staliup (orrestarting), we respectfully requestthat OEPA consider adding the following language to specifically address akiln-ESP shutdown: U(iv) The shutdown ofany kiln equipped with an electrostatic precipitator (ESP), 

### afterthe temperature ofthe exhaust gases from the kiln 

### has dropped below six 

### hundred (600) 

### degrees Fahrenheit at the inlet of

### the ESP." 

### Please advise me ifyou have any questions on this submittal orneed additional assistance or informationto support Maltin Marietta's SIP exemption. Thankyou for your continued work on this important matter.
Sincerely, 

# JoefGreen Environmental Engineer

cc: Lee Burkleca, Ohio EPA-DAPC Tom Kalman, Ohio EPA-DAPC Don Waltermeyer, Ohio EPA-NWDO Joe Reilly, MMMS Woodville Tim Tawney, MMMS Woodville Yvonne Bailey, Esq., MMM Raleigh April Bott, Esq., Chester, Willcox & 

### Saxhe LLP

10·2-06 MMMS Response 

### Letter_vl.DOC

## (



# ( OAC 3745-17-07 SIP Exemption Request for Martin Marietta October 2, 2006 Page 3 of3

PROPOSED DRAFT REVISIONS OF OAC RULE 3745·17·07 Mattin Marietta Magnesia Specialties, LLC

COMPLETE TEXT

- October 2, 2006 (j) 

### The following kiln operations atthe "Martin Marietta Magnesia Specialties, Inc." facility (OEPA premise number 0372000127) located at 755 Lime Road, Woodville, Ohio, providedthatthe owner or operator maintains daily records which clearly documentthe dates, beginning times and ending times for the operations: (i) 

### The stalt-up ofany kiln equipped with abaghouse, until the stone feed to the kilnbegins. (ii) 

### The statt-up ofany kiln equipped with an electrostatic precipitator, from the time fIring [DELETE

- with asolid fuel- DELETE] begins until a stable frring condition is 

### achieved, butnot longerthan six hours from the time firing with a solid fuel begins. (iii) 

### The shutdown ofany kiln equipped with abaghouse, afterthe temperature ofthe exhaust gases from the kiln has dropped below two hundred fIfty degrees Fahrenheit atthe inlet ofthe baghouse. [ADDED (iv) The shutdown ofany kiln equipped with an electrostatic precipitator (ESP), after the temperature ofthe exhaustgases from the kiln has dropped below six hundred (600) degrees Fahrenheit at the inlet ofthe ESP.] Forthe purposes ofthis paragraph, "start-up" shall be defmed as the point ofcommencement offrring the kiln and /I

### stable fIring condition/I 

### shall be defmed as the firing condition that exists when the throughputs ofprocess material. fuel and combustion airhave been stabilized in amannerthat consistently results in complete combustion withinthe kiln and concentrations ofcombustibles within the exhaust gases from the kiln that are within established safety limits.

10-2-06 MMMS Response Letter_vl.DOC