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Martin Marietta

Magnesia Specialties ,M

====:::::'::::=:::====:::::::===========::::====:::::::=::::=::~:::;:====,=:"~

755 LimeRoad

Woodville, OH 43469 USA

Telephone: (419) 849-4200

Fax: (419) 849-4246

August 24, 2006

Mr. Jim Orlemann, Manager

Division ofAir Pollution Control

Ohio Enviromnental Protection Agency

Lazarus Govermnent Center

Post OfficeBox 1049

Columbus, Ohio 43216-1049

RE: Supplemental Technical Information Responsesfor OEPA Review

SIP Revision Request for Martin Marletta Magnesia Specialtiest LLC

Dear Mr. Orlemann:

Per our prior discussions and correspondence, I am providing the following information to supplement Martin

Marietta Magnesia Specialties, lLC (MMMS) submittals of March 21. 2006; December IS, 2005; and October 14,

2005 regarding the requested OAC §3745-17·07 SIP revision. In your June 6, 2006 e-mail, you requested: (1) a

best engineering time frame for achieving a stable firing condition during kiln start·up; (2) submittal of past

deviation reports relating to kiln start-ups and shutdowns and (3) a technical definition of"start-up" for a lime kiln.

Start Up Time Frame

As MMMS has noted in the past, a safe kiln start-up is not defined by time or temperature, but rather as stabilization

of the combustion process. Specifically, the conltol equipment can be safely used once a stable flame has been

established, following the introduction ofsolid fuel into the kiln. Based on a review ofkiln logs and our operating

experience, MMMS has found that a steady state kiln condition can generally be achieved within 6 bours of the

introduction ofsolid fuel during the start-up procedure. Clearly, there is a balance that must be established between

maximizing productivity, by stabilizing dIe kiln ruing process as soon as possible, versus extending the service life

ofthe kiln equipment and refractories by methodically adhering to a gradual beatup and restarting procedure.

Kiln Deviatiog Reports

Enclosed are copies ofTitle V Compliance Certification malfunction reports for two lime kilns (pOlS and P019) for

the years 2003 through 2005. As you will see in these reports, there are three primary types ofkiln operating issues,

each ofwhich requires either a brief. moderate or long shutdown, and a corresponding restart ofthe lime kiln.

A brief interruption of the electrostatic precipitator (ESP) control on die #1 kiln (POlS) can arise due to process

variation, when the solid fuel supplied to a kiln fluctuates in a manner that results in over fueling or excessive

combustibles concentrations in the kiln exhaust, power intermptions. etc. When unburned combustibles are detected

at concenttallons between 1.00.41 and 2.5% ofthe exhaust flow, as shown on a recording chart or computer screen in

the kiln control room, the operator responds to early warning alarms and adjusts the fuel feeder speed. If excess

combustibles still become greater than 2.50/0, an electronic alann is automatically activated and a control device

turns off the ESP. The kiln operator immediately implements corrective actions, which may range from simply

verifying that a "highcombustibles" event bas passed, to adjusting the process controls. Once the process stabilizes,

the ESP is turned back on manually, witbill. a short period oftime after the combustibles concentration has returned
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SIP Revision Requcst for Martin Marictta

August 24, 2004j

Page2of2

to a nonnal range (less than I%). As previously stated in our SIP request, this type of situation imposes an

explosion risk, endangers employee safety and could result in catastrophic damage to our process equipment. Such

kiln opemting issues may persistfrom 2 to 30 minutes and lmve been reported to Ohio EPA, per OAC §3745-1S-06,

as either "out-of-service" or "malfunction" eventsin the past.

Anotherset ofsituationsthat could require shutting down the ESP (pOIS) or baghouse (pO19) control units would be

problems with mechanical equipment (i.e. ESP shorting, process fan issues, clogged plenums, etc.) which could

necessitate the tmplanned, temporary idling ofthe kiln-firing process for a longer period oftime, perbaps 30 minutes

to several bours. Ifpossible, tIle kiln is kept wann, so the rest81t time will be minimized. Per OAC §3745-1S..06,

these events bave typically been reported to Obio EPA as either "ollt-of-service" or "malfunction" incidentstoo.

Finally, kilns and associated control equipment are sometimes shut down completely for either routine or emergency

maintenance. Once the kiln is "cold", it must be reheated quite gradually, generally starting witb the firing of

natural gas, until replacement refractories have been sufficiently cured or warmed to preserve the effective service

life of the unit and to assure safe conditions. TIus reheating procedure can Ja~t for 24 to 36 hours. As noted in

previous submittals, solid fuel and stone feed wilt be restarted only during the last few hours of the kiln startup (as

evidenced by tIle kiln logs previously submitted). Per OAC §3745M 15-06, these events have also been reported as

"scheduled maintenance", "out-ot-service" or "ma1:/.\mction" events due to the apparent need for an exemption.

Definition of Stal"tMUn for a"Lime Kiln

OAC §3745-17-01 defines "start-up" as "the commencement of firing offuel burning equipment from acold, nonfired condition." As noted, this definition is specific to filel burning equipment. While firing a lime kiln is similar

to starting a piece offuel burning equipment, MMMS would suggest a distinct definition for a "lime kiln start-up" as

follows: "the point of commencement offiring the kiln until such time as tlle process is operathlg in a steady-state

condition using its primary fhel. For the purpose ofthis definition, steady-state is considered to be present when the

throughputs of process material, fuel, and combustion air have been stabilized in a mamler tbat demonstmtes the

combustion process will be consistently complete and safe, with an exhausted combustibles concentration within the

established safety limits."

We appreciate your continued attention to tltis critical SIP exemption request. To that end, please contact me ifyou

have any questions regarding tIlis submittal.

Re(\~Y,

JOeL~:n Environmental Engineer

Enclosures (3) - with both e-mail and hard copies

Cc: Don Waltenneyer, OEPA-NWDO

Joe Reilly, MMMS Woodville

Tim Tawney, MMMS Woodville

Yvonne Bailey, Esq., MMM Raleigh

April Bott, Esq., Chester, Willcox & Saxbe

MMMS Woodville SIP Ltr v.3.DOC 8/2412006
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OHIO EPA TITLE V COMPLIANCE CERTIFICATION

REVISED AS REQUESTED BY OEPA 07/27/06

Compliance Certification Section 1- Facility Information

Complete this section ofthe form only once for the facility (See Compliance Certification Section IV under the Clarifying

Instructions at the end of t~is document for important additional information in filling out this part ofthe Corm.)

A~ Facility Name: Martin Marietta Magnesia Specialties, LLC

B. Facility Address: 755 Lime Road, Woodville, Ohio 43469

C. Facility ID[10 diglts]=_0_3-_7_2-_0_0_-0_1_27 _

D. Date ofTitle V Permit Issuance: 06/20/03

-':"~--'---------------

( E. Reporting Period: January through December of2005

Compliance Certification Section 11- General Terms and Conditions

(Part I ofthe Permit)

Complete this section oCthe form only once for the facUlty (See Compliance Certification Section II under the Clarifying

Instructions at the end of this document for important additional information in filling out this part ofthe form.)

F. Has your company complied with all the General Terms and Co~ditions stated in Part I(A) ofthe Title V

permit? __ YES -X.- NO

Ifno, indicate the paragraph number for each General Term and Condition for which compliance was

not maintained, a description ofthe excursion/deviation, and a description ofthe corrective action that

was taken to ensure that compliance will be maintained in the future.

Permit Description ofExcursioolDevfatlon Corrective Action Taken Term No.

PartI.A.6.a The permittee must comply with all terms and conditions of Please see the emission source identifications listed below.

this permit.

F002; See Part ill.A.ill.l, Part rn.A.III.2, and Part III.A.1lI••3j F003; F004; F006 Part I1LA.Ll;

F007 Part ill.A.I.I; F008; P004; POll; P013; POlS; See Part ill.A.LI, and PART m.A.III.5;

P019j See Part UI.A. V.I.e.i1; P028 (insignificantsource, per 8/12/05 "malfunction" notification for dust collector).

Marlin Marietta Magnesia Specialties, LLC

REVISED MMMS Woodville Title VCertification for 200S.doc

Page 1ofSO 713112006
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omo EPA TITLE V COMPLIANCE CERTIFICATION

REVISED AS REQUESTED BY OEPA 07/27/06

Compliance Certification Section ill- Facility Terms and Conditions

(Part IT ofthe Permit)

Complete this section ofthe form only once for the facility (See Compliance Certification Section ill under the Clarifying

Instructions at the end ofthis document for important additional information in filling out this part ofthe form.)

G. Provide for each tenn and condition in Part ILA "State and Federally Enforceable Section", by

appropriate paragraph citation, a briefstatement ofhow certification ofcompliance has been determined

for each term and condition and a summary of all excursion/deviations that have occurred during the

compliance certification period.

Please place an "X" in only one ofthe two options below

Each lEU listed In Part II.A ofthe Title V permit has complied with each applicable requirement established in the listed Permit to Install (PTl) and

N/A each applicable requirement specified In OAC Chapter 3745·17, OAC Chapter 3745·18, and/or OAC Cbapter 3745·21.

Except as indicated for each lEU listed in the following table below, each lEU listed in Part II.A ofthe Title V permit has eompiled with each

N/A applicable requirement established in the listed Permit to Install (PTI) and each applicable requirementspecified in OAC Chapter 3745-17, OAC

Chapter 3745.18, and/or OAC Chapter3745-21. (please identify each intermittent compliant lEU In a separate row in the table below as applicable.)

( Identify the Emission Continuous (C) LimitatioolControl Method Used to Determine

Measure or the Permit Compliance. orIntermittent ExcurslonslDeviations

Term No. (I) Compliance?'

Those Documented

Within

ExcurslonlDeviation Other (Explain the Nature, Duration,

Reports Submitted to and Cause ofthe ExcurslonlDevlatlon,

OEPA District Office As Well As Any Corrective Action

or Local Air Agency Taken)

(Identify Date ofEach

Re ort

PartILA.l 40 emPart 63.53 (NESHAP) PartI Application

C Submitted Prior to 40 CFR Pt 63;AAAAA Part I Application Submittal Ma 15,2002

PartII.A.2 40 CFR Part 63.53 (NESHAP)

40 CFR Pt63;AAAAA PartII Applieation Submittal N/A

Part1I.A.3.a NESHAP- Part II; Initial Notlficlltion Part IIApplication

within 120 days after Subpart C Submitted Prior to ·40 CFR Pt 63;AAAAA Promul ation Ma 32004

Part 1I.A3.b NESHAP- Compliance Status

40 CFR Pt63;AAAAA Notification; 6l1-days following N/A re ulred com ilanee demonstration

H. Any other material infonnation that may indicate non - compliance with one or more ofthe above -

described applicable requirements for this facility must be described below:

There was no other material information to the best of our knowledge.

Marlin Marietta Magnesia Specialties, LLC

REViSED MMMS Woodville Title V Certification for 2005.doc

Page 2 of50 713112006
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OHIO EPA TITLE V COMPLIANCE CERTIFICATION

REVISED AS REQUESTED BY OEPA 07/27/06

Complete this section ofthe form for each significant emissions unit. Emissions units with identical terms and conditions may

be grouped together (See "Compliance Certification Section IV" under the "Clarifying Instructions" at the end of this

document for important additional information in filling out this part ofthe form.)

P. Significant Emissions Unit ill [4 characters]: POlS ------------------- Q. Provide for each term and condition in Part TIl.A "State and Federally Enforceable Section" for the

emission unit, by appropriate paragraph citation, a briefstatement ofhow certification of compliance has

been determined for each term and condition and a summary ofall excursions/deviations that have

occurred during the compliance certification period.' Please add rows as necessaryfor each Emission

limitation/Control Measure specified in Part IILA.LI ofthe permit.

Identify the Emission Continuous (C) Limitation/Control Method Used to Determine

Measure or the Permit Compliance' or Intermittent ExeurslonslDeviations

Term No. (I) Compliance?'

Those Documented

Within

Excursion/Deviation Other (Explain the Nature, Duration.

Reports Submitted to and Cause oftbe ExcurslonlDevlatlon,

OEPA District Office As Well As Auy Correetive Action

or Local AirAgeney Taken)

(Identify Date ofEach

Re ort

PARTUI.A.I.1 Inspections 5 dayslweek- minimum I Ma~unction~Ou~o~

OAC 3745-17-07(A) Service; See Below

( I'ART IILA.Ll PE Limitation: 79.9 Ib/br (Combined) I Malfunctions/Out-ofOAC3745-17-11(B) Scrvice; See Below

PART DI.A.I.1 SOl Limitation: 25.0 Ib S02lton of C None OAC 3745-18-78(E)(1) product

PART IILA.1.1 Inspections 5 dayslweek - minimum C None OAC3745-17-07(B)(1)

PARTUI.A.Ll Employ RACM: III.A.I.2.b C None O!\C 3745-l7-08(B)

PART lILA.I.2.a QAC 374S-17-U(A)(3): Combine PE C None emissions Crom POlS and P019

PART UlA.I.2.b.1 RACM: Enclosures (Buildings) and C None hooding to minimlzc fugitive emissions

PART I1I.A.I.2.b.1I RACM: All fugitive dust captured C Nonc within hulJdlug - vent to ESP 110836

PART UlA.".l Only coal, petroleum coke, and/or C None natural gas shall be burned.

PART UlA.D.2 Sulfur Content ofCoal/Coke: less than C None content measured at most recent test

PART 1II.A.UI.l Samplcs of coal/coke: analyze for C None sulfur content and heat content.

PART ID.A.DI.2 Mainlllin monthly: tollli quantity of C None coaUcoke received; analytical resullJ

PART III.A.III.J Egress Points: VE Observation C None Inspections 5 days/week

PART UlA.IIL4 ESP: VE Observation Inspections 5 C None dayslweek

Martin Marietta Magnesia

PART III.A.III.5 ESP Opacity Observation: once/month I None Specialties, LLC, missed the

40 CFR Part 60, App. A, Method 9 monthly Method 9 Opacity

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observation for A ril 2005.

Martin Marietta Magnesia Specialties, LLC Page 30 of50 713112006

REVISED MMMS Woodville Title VCertification for 200S.doc
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\

OHIO EPA TITLE V COMPLIANCE CERTIFICATION

REVISED AS REQUESTED BY OEPA 07/27/06

Readings to be conducted at tile

bel!inninl! oCtile montll.

PART rn.A.rn.6 CLARIFICATION PARAGRAPH N/A N/A

I'ART III.A.IV.l FuelType Burned Deviation; report N/A All required reports

within 30-days of occurrence submitted

PART III.A.IV.2 Sulfur Content Deviation: report N/A All required reports

within 45-days ofoccurrence submitted

PART I1I.A.IV.J Quarterly Report: ESP Out-of-Sel"Viee C All required reports

Summaries submitted

PART III.A.IV.4 Semiannual Report: Egress Point C All required reports

Deviation and Corrective Actions submitted

PART ro.A.IV.S Semiannual Report: Baghouse C All required reports

Deviation and Corrective Actions submitted

PART III.A.IV.6 Semiannual Report: Opacity Deviation C All required reports

and Corrective Actions submitted

PART rn.A.V.l.a Emission testing to be conducted C None within J-months after permit issued.

PART III.A.V.l.b Emission testing: demonstrate C None compliance with PE and S02, Opacity

PART IILA.V.I.e.1 PE Emission Rate: 40 CFR Part 60, C None APPllDdlx A, Methods 1-5

PART III.A.V.l.e.il 20% Opacity (J-mIIl/6-mln averages): C None 40 CFR Part 60, App. A, Method 9

PART rn.A.V.l.eJlI S02 Emission Rate: 40 CFRPart 60 C None Appendix A, Methods 1-4 and 6

PART III.A.V.l.d Conduct Emission Tests at or near C None maximum capacities

PART UloA.V.l.e Submit "Intent-to-Test" Notification C None 30 days prior to proposed test date

PART rn.A.V.2.a Additional Information during testing: C None Sulfur Content coal/coke burned

PART m.A.V.2.b Addltlonallnformalion during testing: C None Power Input (kW) of each TR set.

PART I1IoA.V.J.a Applicable Testing Requirements C None

PART III.A.V.3.b Applicable Tesling Requirements C None

PART rnoA.V.3.e Applicable Testing Requirements C NOlie

\

PART In.A.V.3.d Applicable Testing Requirements C None

PARTIILA.VI N/A (This permit does not have any N/A N/A mlseellaneous requirements)

R. Any other material infonnation that may indicate non-compliance with one or more ofthe abovedescribed applicable requirements for this facility must be described below:

Part III.A.I.t

Deviation Reports:

Due to the safe operation of the #1 South Kiln, all kiln shutdowns and startup r~quire the bypassing

ofthe ESP control system to prevent damage and explosion to the control system. Since the

startup/shutdown regulation exemptions do not apply to our kiln operation, the proper procedure is

to identify these occurrences as malfunctions. As indicated in the Quarterly Deviation Reports, the

Marlin Marietta Magnesia Specialties, LLC

REVISED MMMS Woodville Title V Certification for 200S.doc

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OIDO EPA TITLE V COMPLIANCE CERTIFICATION

( REVISED AS REQUESTED BY OEPA 07/27/06

following is a list ofthose times ofshutdown/startup ofthe #1 South Kiln and "out-of-service" days

during the reporting period:

A. 1st Quarter Deviation Report for the period ofJanuary 1t 2005 through March 31, 2005

submitted by April30t 2005:

Malfunction Reports

January 2005

116/2005: Both ESP Sections; 10-minutes; Power Outage

1125/2005: Both ESP Sections; I-hr; Low-TemperaturelHigh Combustible Safety Alarm

1/2812005: Both ESP Sections; 10-minutes; Low-TemperaturelHigh Combustible Safety Alarm

112912005: Both ESP Sections; 15-minutes; Low-TemperaturelHigh Combustible Safety Alarm

February 2005

219/2005: Both ESP Sections; 10-minutes; Low-TemperaturelHigh Combustible Safety Alarm

2/1012005: Both ESP Sections; 30-minutes;Low-TemperaturelHigh Combustible Safety Alarm

2/1112005: Both ESP Sections; 6-minutes;Low-TemperaturelHigh Combustible Safety Alarm

2/12/2005: Both ESP Sections; 45Mminutes;LowMTemperaturelHigh Combustible Safety Alarm

2/14/2005: Both ESP Sections; l~minutes;LowMTemperatureIHighCombustible Safety Alarm

(02/17/2005): Email Notification; Shutdown/Startup No.1 South Kiln (P015); Repair ID& Coal Fan

2/2012005: Both ESP Sections; 15-minutes;LowMTemperaturelHigh Combustible Safety Alarm

2/23/2005: Both ESP Sections; I-hr;Low-TemperaturelHigh Combustible Safety Alarm

2/24/2005: Both ESP Sections; 25-minutcs;LowMTemperaturelHigh Combustible Safety Alarm

2128/2005: Both ESP Sections; 30-minutcs;Low-Temperature/High Combustible Safety Alarm

( March 2005

3/212005: Both ESP Sections; 3D-minutes; Low-Temperature/High Combustible Safety Alarm

3/612005: Both ESP Sections; 45-minutcs;Low-TemperaturelHigh Combustible Safety Alarm

3n12005: Both ESP Sections; 8hr-50mlnutes;LowMTemperafurelHigh Combustible Safety Alarm

3/8/2005: Both ESP Sections; 2hrM3~minutes;Low-TemperaturelHighCombustible Safety Alarm

3/11/2005: Both ESP Sections; 7hr-15-minutes;Low-TemperaturelHigh Combustible Safety Alarm

3/14/2005: Both ESP Sections; I-hr;Low-TemperaturelHigh Combustible Safety Alarm

(03/14/2005): Email Notification; Shutdown/Startup No.1 South Kiln (POlS); RepairlBalance Coal Fan

3/16/2005: Both ESP Sections; 2D-minutes;Low-TemperaturelHigh Combustible Safety Alarm

3/2012005: Both ESP Sections; 35-minutes;Low-TemperaturelHigh Combustible Safety Alarm

3/2512005: Both ESP Sections; 10-minutes;LowMTemperaturelHigh Co~bustibleSafety Alarm

3/2712005: Both ESP Sections; 55-minutes;Low-TemperaturelHigh Combustible Safety Alarm

313012005: Both ESP Sections; 30-minutes;Low-TemperaturelHigh Combustible Safety Alarm

B. 2nd Quarter Deviation Report for the period ofApril 1, 2005 through June 30, 2005 submitted

by July 31, 2005:

Malfunction Reports

April 2005

4/5/2005: Both ESP Sections; 22-minutes; Low-TemperaturelHigh Combustible Safety Alarm

4/8/2005: Both ESP Sections; 35-min; LowMTemperaturelHigh Combustible Safety Alarm

4/1412005: Both ESP Sections; 10-minutes; Low-TemperatureIHigh Combustible Safety Alarm

(04/1512005): Email Notification; Shutdown No.1 South Kiln (POlS); Kiln and Coal Fan Repairs

(04/29/2005): Email Notification; Startup No.1 South Kiln (POl5); Kiln and Coal Fan Repairs

413012005: Both ESP Sections; lhr 45-min; Low-TemperaturelHigh Combustible Safety Alarm

May 2005

Martin Marietta Magnesia SpeelalCies, LLC

REVISED MMMS Woodville Title VCertification for 200S.doc

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(

OHIO EPA TITLE V COMPLIANCE.CERTIFICATION

REVISED AS REQUESTED BY OEPA 07/27/06

512/2005: B - Section; 30-minutes; Power Loss- Electrical Repairs

5/1312005: Both ESP Sections; I-hr; Power Outage

5/2312005: Both ESP Sections; 15-mlnutes;Low-TemperaturelHigh Combustible Safety Alarm

5/24/2005: Both ESP Sections; 30-minutes;Low-TemperaturelHigh Combustible Safety Alarm

5/2512005: Both ESP Sections; 20-minutcs;Low-TemperaturelHigh Combustible Safety Alarm

5/2612005: Both ESP Sections; 4-hrs; ID Fan Electrical Problems - Electrical Breaker Panel

5129/2005: Both ESP Sections; 5-mlnutes; Low-rempel'aturelHigh CombUstible Safety Alarm

June 2005

612/2005: Both ESP Sections; I-hr; Low-TemperaturelHigb Combustible Safety Alarm

6/312005: Both ESP Sections; 4-hrs; Safety Alarm - Coal Fan Repair

6/14/2005: Both ESP Sections; 6hr-30minutes; Power Outage

6/15/2005: Both ESP Sections; 10-minutes; Low-TemperaturelHigh Combustible Safety Alarm

612112005: Both ESP Sections; 4hr-30-minutes; Safety Alarm - Coal Fan Repair

612312005: Both ESP Sections; 8-minutes; Low-TemperaturelHigh Combustible Safety Alarm

6125/2005: A - Section; 3hr-30min; Electrical Problems A-Side

613012005: Both ESP Sections; 30-minutes; PowerOutage

Scheduled Maintenance Reports

ESP Out-of=Service

Date· ESP Section Duration

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c. 3rd Quarter Dev~ation Report for the period ofJuly 1, 2005 through September 30, 2005

submitted by October 31, 2005:

Malfunction Reports

July

7/20 both sections, -1 hr., to clean ID fan.

7/21-22 both sections, -261/3 hrs., were shut down to fix shorted out wires.

7/27 both sections, -20 min., to repair combustibles analyzer-alarm system.

7131 both sections, -5 min., to repair combustibles analyzer-alarm system.

August

8/06 both sections, -25 min., to repair a broken combustibles analyzer.

8/13 both sections, -10 brs., to address a coal fan balancing (safety) issue.

8/13 both sections, -3 % hrs., due to a complete electrical power outage.

8/16 both sections, -2 1/4 hrs., to address a coal fan balancing (safety) is~ue.

8122 the"A" section, -3 5/6 hrs., to address dust clogging and shorting out ofESP.

8126 both sections, -2 1/2 hrs., to address a coal fan balancing (safety) issue.

8129 the "A" section, -42 hrs., to address dust clogging and shorting out ofESP.

September

9/14 both sections, -15 min., to repair a broken combustibles analyzer (safety) problem.

9/19 the ''B'' section, -36 hrs" to address an electrical failure with a broken ESP wire.

ESP Qut-of..seryjce

D. 4th Quarter Deviation Report for the period of October 1,2005 through December 31,2005

submitted by January 31, 2006:

MalfunetjQD Reports

October

Martin Marietta Magnesia Specialties, LLC

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omo EPA TITLE V COMPLIANCE CERTIFICATION

REVISED AS REQUESTED BY OEPA 07/27/06

10/04 both sections, -45 min., because of an unexpected coal pipe failure.

10/0S both sections, -1 hr., shutdown & startup to address a coal fan balancing (safety) issue.

10/06 both sections, -7 min., automatic ESP shutdown due to fueling variation (safety) issue.

10/17 both sections, -1 hr., unexpected outage resulting from coal fan and gas firing failures.

10118 both sections, -12 hrs., due to ill/coal fan vibration (safety) and ESP startup problems.

10/20 both sections, -S hrs., because ofthe failure ofan oil return pump on the #1 ball mill.

10/30 both sections, -1 hr., unanticipated shutdown due to cooler belt and gas firing issues.

November

11/01 both sections, ...(j 1/4 hrs., due to a bad coal fan bearing and normal kiln startup routine.

11/15 both sections, -S hrs., shutdown for reducing coal fan speed to address kiln-ESP outages.

11/15 both sections, -S min., automatic ESP shutdown due to fueling variation (safety) issue.

11/20 both sections, -2 min., automatic ESP shutdown due to fueling variation (safety) Issue.

11/29 both sections, -S hrs., due to a ball mill motor failure and normal kiln startup routine.

December

12/05 both sections, -3 min., automatic ESP shutdown due to fueling variation (safety) issue.

12/06 both sections, -13 min., automatic ESP shutdown due to fueling variation (safety) issue.

12/08 both sections, ...(j hrs., due to excessive In fan vibration (safety) and shutdown for repairs.

12/14 both sections, -4 min., automatic ESP shutdown due to fueling variation (safety) issue.

12/14 both sections, -4 min., automatic ESP shutdown due to fueling variation (safety) issue.

12/14 both sections, -10 min., automatic ESP shutdown due to fueling variation (safety) issue.

12/15 both sections, -10 min., automatic ESP shutdown due to fueling variation (safety) issue.

12/18 both sections, -S min., automatic ESP shutdown due to fueling variation (safety) issue.

12/19 both sections, -10 min., automatic ESP shutdown due to fueling variation (safety) issue.

12/20 both sections, -10 min., automatic ESP shutdown due to coal crusher fuel variation (safety).

12/22 both'sectlons, -SO min., unplanned ESP shutdown due to frozen waterline on the ID fan.

12/26 both sections, -20 min.. automatic ESP shutdown due to fueling variation (safety) issue.

Cleaning ofstones and dust on 08/24 resulted in visible particulate emissions for -1 hours.

Stone feed chutes on this unit generated visible particulate emissions on 12/21/05 for -1 hour.

Per discussions with OEPA, the required cleanup was completed and operating personnel were asked to maintain

equipment and to keep quantities ofstone debris and dust from accumulating in this area.

Operating personnel were asked to search for source of12/21 emissions and corrected the problem.

Visible fugitive emissions were observed on 9/27, 9/28, 11/28, 12/13,12/19,12/20, and 12/21.

OEPA was previously notified ofthe following "malfunetions" due to potential emissions issues:

ESP Out-or-Serylce

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ESP Section Duration

Martin Marietta Magnesia Specialties, LLC

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OHIO EPA TITLE V COMPLIANCE CERTIFICATION

( REVISED AS REQUESTED BY OEPA 07/27/06

Compliance Certification Section IV - Si2nificant Emissions Units Terms and Conditions

. (Part ill of the Permit)

Complete this section ofthe form for each significant emissions unit. Emissions units with identical terms and conditions may

be grouped together (See "Compliance Certification Section IV" under the "Clarifying Instructions" at the end oftbis

document for important additional information in filling out this part ofthe form.)

H. Significant Emissions Unit ill [4 characters]: P019

----------------------- 1. Provide for each tenn and condition in Part ill.A "State and Federally Enforceable Section" for the

emission unit, by appropriate paragraph citation, a briefstatement of how certification ofcompliance

has been determined for each tenn and condition and a summary of all excursions/deviations that have

occurred during the compliance certification period. Please add rows as necessaryfor each Emission

limitation/Control Measure specified in Part IIIA.L1 ofthe permit.

Identify the Emission Continuous (C) Limitation/Control Method Used to Determine

Measure or the Pennit Compliance, or Intermittent ExeursionslDevlations

Term No. (I) Compliance?'

Those Docnmcnted

Within

(

ExcursionlDevlation Other (Explain the Nature, Duration,

Reports Suhmltted to and Cause of the ExeursionIDevlatlon, " OEPA District Office As Wcll As Any CorrectiveAction

or Local AirAgency Takeu)

(Identify Date ofEach

Re ort

PARTIU.A.I.1 Inspections 5 dayslweek- minimum C None OAC374S-17·07(A)

PART IILA.I.1 PE Limitallon: 79.9Ib/hr (Combined) I Malfunction Reports OAC3745-17·1l(B)

PART IILA.I.1 802 Limitation: 25.0 Ib S02/ton of I Malfunction Reports OAC 3745-1S-7S(F) product

PART ill.A.I.1 Inspections 5 dayslweek- minimum C None OAC 3745-17-07(B)(1)

PART ill.A.1.1 Employ RACM: llI.AJ.2.b C None OAC 3745-17-DS(B)

PART ill.A.I..2.a OAC 3745-17-11(A)(3): Combine PE C None emissions from POlS and POl9

PART ill.A.I.2.b.i RACM: Enclosures (Buildings) and C None hooding to minimize fugillve emissions

PART ill.A.I.2.b.1I RACM: All fugItive dust captured C None wltbin building- vent to bh 111085

PART ill.A.II.1 Maintain Pressure Drop Across C None Baghouse: wIthin 6-16 Inches water

PART III.A.1I.2 Only coal, petroleum coke, and/or C None natural gasshall be burned.

PART IILA.II.3 Sulfur Content ofCoal/Coke: less than C None content measured at most recent test

PART II1.A.II1.1 Maintain and Record Pressure Drop: C None Frequency: Weekly - minimum

(

\

Martin Marietta Magnesia Speclallles, LLC Page 36 ofSO 713112006

REVISED MMMS Woodville Title VCertification for 200S.doc
PART m.A.I1U Samples of coal/coke: analyze for C None sulfur content and heat content.

PART III.A.I1I.J Maintain monthly: total quantity of C None coal/coke received; analytical results

PART IIIAnIA Egress Points: VE Observation C None Inspectiollil 5 days/week

PART I1I.A.III.5 Baghouse: VE Observation C None Inspeellons 5 dayslweek

PART1II.A.IV.l Quarterly Report: Pressure Drop C All required reports

Deviation and Corrective Action submitted

PART III.A.IV.2 Fuel Type Burned Deviation; report N/A All required reports

within 30-days oC occurrence submitted

PART III.A.IV.3 Sulfur Content Deviation: report N/A AU required reports

witbin 45·days of occnrrence submitted

PART fiLA.IVA Semiannual Report: Egress Point C All required reports

Deviation and Corrective Aetions submitted

PART III.A.IV.5 SemIannual Report: Baghouse C All required reports

Deviation and Corrective ActIons submitted

PART 1II.A.IV.6 SemIannual Report: Opacity Deviation C All requIred reports

and Corrective Actions submitted

PART IlIAV.l.a Emission testing to be conducted C None wllldn 3-months aCler permit issued.

PART IIIAV.l.b Emission tesllng: demonstrate C None compliance wUh PE and SOl, OpacIty

PART liLA.V.l.c.1 PE Emission Rate: 40 CFR Part 60, C None Appendix A, Methods 1-5

OEPA was notified on 9/26 &

9128 ofP019 baghonse

bypassing due to #2 kiln"

shutdown and startup.

OEPA was notified 10/14 &

PART III.A.V.l.c.1I 20% Opadty (3-min/6-mln averages): I Malfunction 10126 ofP019 bagbouse

40 CFR Par/GO, App. A, Method 9 Reports bypassing due to #2 kiln"

shutdown and startup.

Shutdownsand&artupswere

executed in a way that minimized

emissions and protected

equipment.

PART I1LA.V.l.c.1II S02 EmIssion Rate: 40 CFR Part GO C ~one Appendix A, Methods 1-4 and 6

PART II1.A.V.l.d Conduct Emission Tests at or near C None Rlaximum capacities

PARTm.A.V.l.e Submit "Intent-to--Tesf' Notification C None 30 days prior to proposed test date

PARTllLA.V.2.a AddilionallnCormation dudng testing: C None Pressure Drop across baghollse

PART m.A.V.2.b Additional Information durIng testing: C None Sulfur Cllntent coal/eoke burned

PART llLA.V.3.a Applicable Tesling Requirement C None

PART m.A.V.3.b Applicable Tesllng Reqnlrement C None

PART III.A.V.3.c Applicable Tesllng Requirement C None

PART liLA.V.3.d Applicable Tesllng Requirement C None

OHIO EPA TITLE V COMPLIANCE CERTIFICATION

( REVISED AS REQUESTED BY OEPA 07/27/06

(

Martin MarIetta Magnesia Specialties, LLC

REVISED MMMS Woodville Title V Certification for 200S.doc

Page3? ofSO ?/31n.OO6
OHIO EPA TITLE V COMPLIANCE CERTIFICATION

( REVISED AS RE UESTED BY OEPA 07/27/06

PARTIII.A.VI N/A N/A

J. Any other material information that may indicate non-compliance with one or more ofthe abovedescribed applicable requirements for this facility must be described below:

Part III.A.I.t Deviation Reports:

Due to the safe operation of the #2 South Kiln, kiln startup requires the bypassing of the

Baghouse control system to prevent damage and explosion to ~he control system. Since the

startup/shutdown regulation exemptions do not apply to our kiln operation, the proper

procedure is to identify these occurrences· as malfunctions. As indicated in the Quarterly

Deviation Reports, the following is a list ofthose times ofstartup ofthe #2 South Kiln during the

reporting period:

Malfunction Reports

9/26 E-mail notificatIon for bypassing the P019 baghouse due to #2 kiln" hot spot" shutdown.

9/28 E-mail notification for bypassing the P019 baghouse due to #2 kiln" startup procedure.

10/14 E-mail notification for shutdown of the P019 kiln and baghouse for routIne maintenance.

10126 E-mail notification about the startup oftheP019 kiln and baghouse, per 10/14 entry above.

(

(

\

Stone feed chutes on this unit generated visible particulate emissions on 12/20/05 for~3 hours.

Operating personnel were asked to search for source of 12/20 emissions and corrected the problem.

Martin Marietta Magnesia Specialties,LLC

REVISED MMMS Woodville Title V Certification for 200S.doc

Page 38 of50 713112006
(

OHIO EPA TITLE V COMPLIANCE CERTIFICATION

(

,

Compliance Certification Section 1- Facility InfOl'mation

. COln}>lete this section of tIte form only once fol' the facility (Sec Compliance Certification Section IV unclel' the Clarifying

Instructions at the end of tllis document for Jml)ol'fant I\cldl1l0nal information in ruling Ollt this pal't of the CoI'm.)

A. Faci!ity Na1l1e: Martin Marietta Magnesia Specialties, LLC

B. Facility Address: 755 Lime Rond, Woodville, Ohio 43469

C. Facility ID[lOdlgltsl:_0_3-......7_2_-0_0_-0_1_2_7

D. Date ofTitle V Pennit Issuance: 06/20/03

,.....;.~--------------

E, Repol:ting Period: January through December of2004

COlt~pliance Certification Section I~ - General Terms and Conditions

(Part I ofthe Permit) . . Complete this section of the form only once for the facility (See Compllanco Certification Section II uuder the Clnl'lfylng

Instructlolls at the end of tIlls document for important adcli,tionalillfonnatioll in mUng out tltls POl't of the form.)

F. Has yom compmly complied with all the General Terms and Conditions stated in Part I(A) ofthe Title V

pelmit? _ YES ...x.-. NO

Ifno~ indicate the paragraph number for each General Term and Condition for which compliancewas

not maintained~ a description ofthe excursion/deviation, and a descliptioll ofthe con-ective action that

was taken to ensure that compliance will be maintained in the future.

l'ofmit J)eslll'lllClOII ofExcurslolllDovlntion Corl'oct!n Aclloll Tnltcn Tel'nlNo.

PRl't I,A.G.n 'fIJe permitteemllst comply with all terms lind condlllolls of l'lense see the emission sourceldenllRealions lisled below.

I this penni!,

Emission Soul'ce lD: 1'015; See !'al'tIII.A.I.1

EmissIon Sonrce ID: 1'019; See Pal't III.A.I.1

MII1'lin Marlettll Magnosla Sllcclnltlcs, LLC Pllge I 4/2512005
OHIO EPA TITLE V COMPLIANCE CERTIFICATION

( Compliance Certific~tion Section III- Facility Terms and Conditions

(Part IT ofthe Permit)

Complete this section of tbe form only once for the facility (See Compliance Certification Section ill under the Clarifying

Instructions at the end of this document for important additional information ill filling out this part ofthe form.)

G. Provide for each term and condition in Proi ILA "State and Federally Enforceable Sectionn

, by

appropriate paragraph citation, a briefstatement ofhow certification of compliance has been determined

for each tenn and condition and a s.ummary of all excursion/deviations that have occurred during the'

compliance certification period.

Please place an "X" in only one of the two options below

N/A

Each lEU listed In Part II.A oCthe Title V pemut has complied with each applicable requirement established In the listed Pel'ndt to Install (pTl) and

each applicable requirementspecified In OAC Challter 3745-17, OAC Chapter 3745.18, andJor OAC Chapter 3745·21.

Except as Indicated for each lEU listed In the followIng table below, each lEU listed In Part II.A ofthe TItle V pcrmit has compllcd with each

N/A applicable reqnlrcment established In the listed Permit to Install (pTI) and each applicable requirementspcclfied In OAC Chapter3745-17, OAC

Chapter 3745-18, and/or OAC Challtcr 3745·21. (pleasc Identify each Intermittent compliant lEU In a separate row In the table below as applicable,)

Identify the Emission

Method Used to Dctermlne Continuous (C) Limitation/Control

Measure or the Pel'mlt Compliance. or Intermittent Excul'slonslDevlalions

TernlNo. (l) Compliance?'

Those Documented

Within

Excnl"slonIDevllltlon Other (Explain the Nature, Duration,

( Reports Submitted to and Cause ofthe ExcurslonIDevlatlon,

OEPA District Office As Well As Any Corrective Action

or Local All' Agency Taken)

(Identify Date ofEach

Re 011

PartIl.A.1 40 CFR Pali 63.53 (NESHAP) Part I Application

C Submitted Prior to 40 CFRPt63;AAAAA Part I Application Submittal Ma 15,2002

Part I1.A.2 40 CFR Part 63.53 (NESHAP)

40 CFR Pt 63jAAAAA Part II Application Submittal N/A

Part ILA.3.a NESHAP - Part IIj Initial Notification Part IIApplication

wltbln 120 days after Subpart C Submitted Prior to 40 CFR Pt 63;AAAAA Promul atlon Mn 32004

Part n.A.3.b NESRAP - Compliance Status

40 CFRPt63;AAAAA Notlficatloll; 60-days following N/A re ulred com lIance demonstration

H, Any other material infonuation that may indicate non - compliance with one or more ofthe above -

described applicable requirements for this facility must be described below:

There was no other material information to the best of our knowledge.

(

Martlll Mal'letta Magnesia Specialties, LLC Page 2 412512005
( OHIO EPA TITLE V COMPLIANCE CERTIFICATION

Compliance Certification Section IV - Significant Emissions Units Terms and Conditions

(I)art III ofthe Permit)

Complete this section of tbe fm'm for eacll significant emissions unit. Emissions units with identical terms and conditions may

bo grouped togetlJer (See "Compliance Certification Section IV" under the "Clarifying Instmctlons" at the end of tbls

document COl' important additional informntlon in mling out this part of the form.)

P. Significant Emissions Unit ill [4 characters]: POlS -----------------------

(

(

Q. Provide for· each term and condition ill Part lILA "State and Federally Enforceable SectionU for the

emission unit, by appropriate paragraph citation, a briefstatement ofhow cOliificatioll of compliance has

been detel111ined for each term and condition and a summary of all excursions/deviations that have

occurred during the compliance certification period. Please add rows as necessmyfor each Emission

limitation/Control Measure specified in Pm't IllA.I.] ofthe permit,

Idelltlfy tho Emlssloll COlllhlllOUS (C) Llmltntlon/Conll'ol Mcthod Used to Detel'mllle

MenslII'o ol'lho POI'mlt Compliance· or IntCl'lIllItellt Exctll'slolls/Devlnllous

Tel'nlNo. (1) Compllnllce?·

Those Doculllonted

WlIhlll

EXCUl'slolllDevlnlloll Olhol' (Explnlllllic Nnturc, DllI'nlloll,

Rellol'ts Subllllltcd to Dlld ClIllse ofthe Excursion/DevIatIon,

OEPA D1sb'1cl Omell As Well As AllY COl'recllveActloll

01' L\lcnl Ah' Agelley Tnken)

(Idenllfy })lIte ofEneh

Rc IOrt

PART II1.A.I.l Insllccllims 5 dft)'slwcok"-mh!hIlIlDl C· NOIIG OAC 374S-17·07(A)

PARTnI,A,I.l I'E Lhllilatlon: 79,9 Ib/hl' (Comblncd) I Mnlfuncl1olls/0nt-oC·

OAC 374S.17.11(ll) ServIce. See lJclow

PART III,A,I,1 802 Llmlllltlolll 25,0 Ib 802/toll of I Mall'uncllonuOut-ol'-

OAC 3745-1S.7S(E)(1) pl'ollllet ServIce; Sec Bclow

l'AR'r lXl.A,I.l . 11I811ccll0IIs 5 days/wcc\t- IIIlolonulI C None OAC 3745-17·07(8)(1)

PART JII.A,I.1 Employ RACMr III.A.I.2.b C Nonc OAC3745-17-0S(8)

OAC 374S·17·Jj (A)(3): Comblllo PE \

PART UI,A.I.:Z.a onlls510115 fa'om PO IS lind 1'019 C NOlie

l'ART II1.A,L2.b.1 .RACM: Elle105111'C5 (BUildings) and C NOllo 1I00dlll010 11I111111I11:0 fngilln omissions

PART III,A,I.2.b.11 RACM: All fngillve dnst capllII'cd C None wllhlll blllldlllg- VCllt 10 ESP #OS36

PART rn.A,II.l Dilly conI, plltrolclIlll coke, and/or C Noue olltlll'lll gos shllll bll bUI·lIed.

PART III,A,IU SuiI'llI' COlltent oC COllI/ColIC: Icsslhan C NOllo eoIIlent mOIlSlll"Od allllost I'eeont lest

PAR1' III,A,IlI.1 Satnilles of colIl/eokol 1I11111yze for C Nono slIlfur clIutent and heat contellt,

Malnlahl mOllthly: tol,,1 qlllllltlty oC t

l'ART 1IJ.A,III.2 C NOllo ,;

eonlfcoke rccclvcd; anillytleal r/lSlllts

)'AR'r 1II.A.III,3 Egl'oss Poillts: VE Obsel'VlIl1on C NOllc Inspcctlons 5 day8Jlvoilk

PART JII,A,m.4 ESPl VE Observilloll Inspoellons 5 C Nooe dRys/week

PART m.A.III,S .li:81' Opnelly ObsCI'vallon: once/montb C NOllo 40 CFR Pal't 60. AIIP, A. Mctbod 9

Mal'lIn MarIetta MaOllcsla SpecialtIes, LLC Page 28 412512005
(

(

01rIO EPA TITLE V COMPLIANCE CERTIFICATION

PART m.A.m.6 CLARIFICATION PAUAGRAPH N/A N/A

l'ART m.A.IV.1 Fuel Tyllc Ilm'ulld Devlll11011; I'ollol'! N/A AlII'cqUh'cd 1'°1101'15

within 30-c1I1Ys of Ocelll'I'onCO snbmlttod

PAn1' IJI.A.IV.2 8111fnr Content Dovlatlon: I'CIIOI't N/A All roqllh'od 1'011l)l't8 .within 4S-days ofocenrl'ence submlttod

PART IIl.A.IV.3 Qlllu'tcl'ly ROIIOI'II ESP Ont-of-Sol'vloo C AI1I'oqub'od reports

SlImmnl'lcs sUbmitted

PART I1I.A.IV.4 SomlnnnulIl ReIIOI'I: EgI'ola l'olnt C All reqnh'ed roports

Deviation 111\11 Corrcctlve Actions snbmltted

PART m.A.IV.S Scmlaunnal neporll Dnghousc C' AIlI'cqub'ed 1'lli1ol'ts

Dcvlnlloll nnd COI'I'cetlve Actlolls submitted

l"ARTIII.A.IV.6 Semlnllnual RcpOI'I: Opnelty Deviation C Alll'Cqllh'ed roports

lIlId COI'l'cellvcActiolls snbllllUed

PAR'l'm.A.V.1.a EmllSlollle.~tlug to be condncted C NOIIIl withIn 3-monlhs aftor Ilel'mll Issucd.

PART m.A.V.I.b Ji:mlssloll lestlllg: dllmonsh'ato C Noua comlllhl11ec with PE nnd S02, Opacity

PART m.A.V.t.c.1 PE Emission Rate: 40 CllR 1'111'160, C Nouo AIIPcndlx A, Mothods 1-5

PART m.A.V.l.e.1I 20% Opllclly (3-minJ6-mlll nvenges): C Nona 40 CFR1'111'1 60, APP. A, Metllod !)

l'ART m.A.V.I.c.1II 802 Emission Rate: 40 CFR 1'111'1 60 C None Alllllllldllc A, Methods 1-4 AIId 6

PART m.A.V.I.d Conduct Emlsslou Tesls at or ncar C Nonq mnxlmum cnllacUles

PART llI.A.V.l.o SubmUClrntcnl-to-TCsl" NotJncntlon C NOllc 30 days pl'loI' to pl'oposcd tesl dnto

PARTUI.A.V.2.11 AddltlollRllllfol'culltion clIlI'llIg lestlng: C Nouc Sulfur COlltent canl/eolco blll'ood

J'ART 1II.A.V.2.b Addltloul\llufol'lIIatlall chll'lug testlngl C Nonc Powel' II1IHII (kW) of eneh TIl. silt.

l'ART III.A.V.3.a Applicable TestingReqllh'cnlcnlS C Nono

PART UI.A.V.3.b AIlllllcnble Testing Ucqllh'01l1Cllls C None

PART 1II.A..V.3.c Appllcnhle Testing Reqnlrcmeuts C Nona

1)ARTIIT.A.V.3.c1 AIIIIII~lIble Testing Re1lull'emcllts C NonD

MIA (Tills (lcrmlt docs not havo ally \

PARTnI.A.VI mlseellRIICOUs rcquh'o11lonls) N/A N/A

R. AllY other material information that may indicate nOll-compliance with one or more ofthe abovedescribed applicable requirements for this facility must be described below:

Part lIl.A.I.l

Deviation RellOl'tS:

Due to the safe operation ofthe #1 South J(ilIl~ all kiln sImtclowns and startup l'equh'e tlte bypassing

of the ESP control system to prevent clamage and eXlliosion to the control system. Since the

stnl'tllp/sl1l1tdown regulation exemptions do not apply to our kiln operation~ the prol)er procednre is

to identify these occurrences as malfunctions. As indicated iu the Quarterly Deviation Reports~ tile

following is a list ofthose times ofshutdown/startup ofthe #1 South Kiln and "out~of-scrvice~l days

during the reporting period: .

Martin MRI'letta MlIgneslli Slle~lnll1es, LLC Page 29 412512005
ESP Section Dtll'atlon

Both 9-hl's Kiln dmfVcoal fan tt'ipping cil'cllit breaker- low temp. safety trigger

Rectifier B 30-nun ShOlt InRectifier '(B" - ESP Wires

Both 7-h1'8 Low Temperature Safety (Malf1.ll1ction called 2/23/2004)

Both 20-min High Combustibles Safety

Both 30-min High Combustibles Safety

Both lhl'-15min Higll Combustibles Safety

Both 3hr-35min Low Temperature Safllty - Balanced Coal Fall

Both 35-min Low Temperature Safety - Lost fuel supply

(

(

OHIO EPA TITLE V COMPLIANCE CERTIFICATION

A. 1st Quartel'Devlatioll Re}>ol't foi- the period ofJanuary 1,2004 through March 31, 2004

submitted by AI>ril30, 2004:

MaU\mctioll Reports

02/08/2004: ESP Rectifier n Electrical Short, ShutdoWll #1 South !{fIn to Repah' - t/2004001MR (MIlI'tln Mal'leUa ID)

02123/2004: til South Kiln Coal Fall Vlbl'atlon, Shutdown III SO\lth J{lin to Repah' -1!2004002MR (Mal'Un Marietta 11»

03125/2004: ESP Rectifier A Electrical 811m'to Shutdown tJ1 SOl\tll T<:IIn to Repair - tJ2004003MR (Martin MRl'lefta ID)

ESP Olit-of-Sel'Vlce

01/06/2004

02/0712004

02/23/2004

03/0612004

03/16/2004

03/20/2004

03/23/2004

03/27/2004

B. 2nll QU31'tm' Deviation Report for the period ofApril 1, 2004 through June 30~ 2004 submitted

by .July 31, 2004: .

Malfunctloll Reports

06/25/2004: Natural Gas 8111)},ly Line, ShutdnWIl ill SontllKlI1I to Repair M fJ200400SMR (Marlin Marietta Ill)

06/26/2004: Stftl'tllP #1 South 1{lhl M iJ2004006MR (Mal'tlll Mal'lettn ID)

~!Iedllle(l Malntenanco Renol'ts

04/2612004: Scheduled Malutcllllncc- Two Week Lettel' Not1f1callon. Sbutdown til SOlltl1 mItl

il2004007MR (Martin Mlll'lettlllD), . .

05/0212004: Scbechllc!) Maintenance - Two 'wecl! Lettel' Notlflcatlon, St8l"l1l1> #1 South Kiln

IJ2004008MR (Martin Mnrlett.'1ID)

(

ESP Out·of-Sel'vlcll

Date

04/08/2004

04/19/2004

04/22/2004

04/23/2004

05/07/2004

05/08/2004

05117/2004

OS/20/2004

OS/21/2004

06/11/2004

06/12/2004

06/20/2004

06121/2004

06/23/2004

06/2512004

0612712004

;ESP Section

Both

Both

Both

Dotlt

Both

Both

Doth

Both

Both

Both

Both

Both

Rectifier A

Both

Doth

RectifiefB

Duration

1hr-20min Low Temp./High Combustible Safety - Coal Supply Fan

5-1u1I Low Temperature Safety - Inconsistent Fuel Feed

5-min' High Combustiblo Safety

5-miu Higb Combustible Snfdty

Ibr-45min Low Temp.lHigh Comllllstible Safety - Coal Supply Fan

Shr-4Smin Low Temp./High Combustible Safety - No Fuel Supply

1br Restal't Power Outage Due to Electrical Storm- Lightning

45-OOn Low Temp,/High Combustible Safety - Kihl ID Fan Shutdown

5-min Low Temp./High Combustible Safety - Kihl ID Fan Shutdown

l-lu' Low 1'emp,/High Combustible Safety - Coal Supply Fan

20-mitl High Combustible Safety

5-mul High CQtnbustlble Safety

17hr/30min Low Temp.lHigh Combustible Safety - OV01' Voltage to ESP

20-min High Combustible Safety

24-Ju' Low Temp.lHlgh Combustible Safety- Inconsistent Gas Supply

2-min Low Temp./High Combustible Safety - Power Surge

Martin Marietta Magnesia Sl)cclnltle~. LLC Page 30 4/2S/2005
( OHIO EPA TITLE V COMPLIANCE CERTIFICATION

C. 31'11 Quarter Deviation Report for tIle period ofJuly 1~ 2004 thl'ough September 30, 2004

submitted by October 31~ 2004:

Malfunction Renorts

07125/20041 Repair Coal SUI)pl)' Fan Bearing, Shutdown #1 South KlIn •f12004010MR

01/26/2004: Repair Coal Snpply Fan Bearing, Shutdown til South I<:Iln •f12004011MR

08/08/2004: 1D Fall Falhu'c, Shutdown ill Sonth Kiln· tlZ004013MR

08112/2004; 1D Fan }rallurc. Stal'tllll fll SOllth KlIlI • fl2004014MR

09107/2004: Repair Coal Snpply Fan- SJmtclolVlI ill SOllth KlIII - flio04016MR

09/07/2004; RCIIlIlr Coal SUPl11y Fan - Stlll·tlll> til South 1(Ihl - tl2004017MR

;ESP Ont-or-Servlce

Date

08/0112004

08115/2004

08/17/2004

08/18/2004

08/22/2004

08/25/2004

09/03/2004

09/05/2004

09/06/2004

ESP Section

Both

Both

Both

Both

Both

Both

Both

Both

Both

)}uratlon

5-min Low Temp.lHigh Combustible Safety

20-mill Low Temp./High Comhustible Safety

15-min Low Temp./High Combustible Safety

10-mill Low Temp./Higlt Combustible Safety

5-min Low Temp./High Combustible Safety

7-min Low Temp./High Combustible Snfety

5-min Low Tomp.lHigh Comhustible Safety

IO~mil1 Low Tomp./High Comlmstible Snfety

10~mil1 Low Temp.lHigh Combl1stible Safety

(

D. 4th Quarter Deviation Report for tIle pel'lod of October 1,2004 through December 31, 2004

submitted by January 31~ 2005:

Malfunction Reports

10120/2004: Coni Slll>ply Fall Housing Repah' - Shutdown /11 SOlltll Kiln· #2004019MR

10/2012004: C~al &11>pl)' Fall Housing Rellal\'- Stal'tnl) #1 South Klh~ •i12004020MR

10/23/2004: ReplncemFnn - Shutdown ill South Kiln· il2004021MR

10127/2004: Rc)l1ncll mFan - Startlll) til South min - il2004022MR

11/29/2004: Rebalance Coal FRl1lRcpnll'In Fall - Slmtdown/Stnl·tup til South mill. tJ2004023MR

12121/2004: Repah' Coni Fall- SJmtdown/Startul) tit Soutil Kiln· i/2004024MR

(

.,'

ESP Ollt-oC-Serylce

, !lilli!

10/1712004

10/19/2004

10/20/2004

10/22/2004

11101/2004

11106/2004

11108/2004

11/14/2004

t"1122/2004

1113012004

12106/2004

1211012004

12/13/2004

12/15/2004

12/16/2004

ESP Section

Both

Both

Both

Both

Both

Both

Both

Both

Both

Both

Both

Both

Both

Both

Both

Duration

35.,mill Required cleaning ofID Fan

5·min Low Temp.tHigh Combustible Safety

20-mill Lost powel' to ID Fan \

1~hr Req\lit·oc1 balancing the COllI flln

10·l11itl Low Temp./High Combustible Safety

10-min Low Temp./Higll Combustible Safety

5-min· Low Temp.lHigh Combustible Safety

20-min Required cleaning ofID Fan

1O~min Lost power to ID Fan

lO-min Lost power to ID Fan

5-min Low Temp.lHigh Comhustible Safety

1hr/40min Low Temp.lHigh Combustible Safety

5-min Low Temp.lHigh Combustible Safety

10-min Low Temp./High Combustible Safety

is-min Low Temp./High Combustible ~nfety

Mal'lIn Mal'letta Magllcsla Sl'el:laltlcs, LLC Page 31 4/25/2005
( OHIO EPA TITLE V COMPLIANCE CERTIFICATION

Compliance Certification Section IV - Significant Emissions Units Terms and Conditions

(Part ill ofthe Permit)

Complete this section oftile form fOl' each signifieant emissions unit. EmIssions units with Identical terms Ilnd conditions may

be gl'oupcd together (Sec "Compliance Certification Section IV" unde)' the "Clarifying Instructions" at tbe cud of this

document for hnp()rtant additional information ill filling out tills pal't ofthe form.)

H. Significant Emissions Ul1it ill [4 characters]: P019

r. Provide for each term and conditiQn in Part lILA "State and Federally Enforceable Section" for the

emission unit, by appropriate paragraph citation, a briefstatement ofhow certification ofcompliance

has been determined for each term and condition and a summary of all excursions/deviations that have

occurred during the compliance certification period. Please add rows as neceSSQ1Yfor each Emission

limitation/Control Measure specified in Part III.A.Ll ofthe permit.

Idemtl/)' the Emlssloll COlllhlllOIlS (C) L1l1lllatIOII/Contl'ol Molhod Uscel to Dolel'mlno

Mcns\II'e 01' tllO l'el'mlt COllllllla\lce< 01' Inlol'mlttent ExcurslonslDevlnllolls

Tel'mNo. (I) COlllllllallco?'

'1'hose Documouted

Within

ExcUl'$lon/Dovlntlou Other (Explnln Iho Natul'c, DUl'Rtluu,

nellOl'IS Submitted 10 anel CaUSD oftile Excul'slonlDevlallou,

OEI'A Dlstl'lct Omce As Well As Any CUl'l'ccllve Action

( or Local All' Agency Taken)

(Idontlfy Dnle of Enell

no ort

I'AR'r IlI.A.l.1 Inslloetlons 5 da3's/wook-mllllmuln C None OAC 3745-17-07(A)

PARl'II1.A.I.l PE Lhultnllun: 79.9Ib/bl· (Comblneel) I Mnlt\mctlou RellOl'ls OAC 374S-17.11(B)

I'ART IlI.A.I.t 802 LhllUallon: 25.0 III 802110n of I MnlfllucUIln Rcpol'ls OAC 3'14S-18-78(F) IlI'educt

l'ART 1lI.A.I.l Inspections 5 dnys/wecle - IIIbJlunun C NOllo OAC 374S-17-07(B)(t)

PAR1' m.A.I.l Emliloy RACM: IU.A.I.Z.b C NO,no OAC 374S-17-08(D) \

PART IlI.A.U.n OAC 3745-11-11(A)(3)1 Comblnll PE C None omissions fl'onl 1'015 nnd POl!>

PART UJ.A.J.2.b.1 ItA-CMI Enclosures (Bnlldlngs) nud C Noue huodlng to mlnlmlzo fuglllvil emissions

PART IIl.A,U,b.1I HACMI All fllgillvo dust capllll'ed C None within building- vont to bh tI108S

PART IlI.A.II.i Mlllutnin PI'cssln'enroll Across C NOlie Daghollse: wltbln ll·1(j Inehcs watel'

PART JIJ.A.II.2 0111)' coni, Illltrolcnnl colle, ami/or C None naillral gas shall be blll'lIed.

PART m.A.II.3 SlIlCln' Content IIfConi/Coke: less IIlml C NOlie COlllolI! measm'cd at lIIOS! recent lesl

,'. Mailltain and Reeol'd PI·essUI'e Drop: .:.:.

PART III.A.m.l Frcquency: WccldY-lulnlmlllll C None

PAR'r III.A.III.2 Snmples of cOIIVcokel analyze for C NOlie SlIlful' content and hcnt content.

( PART III.A,III.3 Mailltnhllllllllibly: tolnl qunntlty of C Noue c1l8Vcoko I'ecelvedj annlytlenlreaults

PART III.A.III.4 ElIl'ess Polnls: VE Observation C NOlie Inspections 5 days/wcek

Marttll Marietta Magnesia Speclaltlcs, LLC Page 33 412512005
(

(

(

OHIO EPA TITLE V COMPLIANCE CERTIFICATION

PAlrr IJI.A.m,5 Baghollsc: VE Obsel'vntlon C Nonc Inspcctlolls 5 dny./week

PART m.A.IV.l Quartel"y Repol't: PI'esSIII'C Dl'op C Alll'I~qulrcd I'CPOI'tS.

Deviation and COrJ'ccllvllAetiOIl 811IJmltteli

PART III.A.IV.Z Ji'uol Type BIII'ned Dcvlatloll; I'eport N/A All rcqnh:ed rOllorls

wlthlll 3D-days ofocelll'l'cnco slIlJtllltled

PART m.A.IV.3 S"lflll' COlltClIt Dovilltlon: I'CPOl't N/A Alll'oqllh'cd I'eports

within 4S.days ofocelll'l'enco submitted

PARTIII.A.lV.4 Semlnllnllnl RepOIt: :Egrcss Point C All I'cquh'Olll'oporls

Deviation and COl'l'ectlvc Actlons slIbmillcd

I'AR1' III.A.IV.5 8cl\lloullllol Ropol't: nnllllollso C Alll'eqllil'clll'cl'orts

I>ovlntlon alld COl'l'ocllve Actlolls submlttcd

PART 1II.A.IV.6 80111111111111111 Rcpol't: Opllclty Devlnlloll C Alll'cqllh'cd I'cports

lind Corl'octlve Actions 8l1blllllt~d

PART lII.A.V.1.u Emlssloll testlug to be cOlldllcted C None wlllllll 3-1\I01lths artel' pCl'llllt IsslIcd.

PART III.A.V.l.b Emlssloll testlllgi domollsh'nte C NOlie cOllllll1ullce lvlth PE nlld 802, Opnclty

PAltT III.A.V.l.c.1 l'E Emlsslou Rntcl 40 CFR Pm't 60, C Nona Allpelldlx A, Methods 1-5

PART IlI.A.V.t.c,lI 20% OpacIty (3-lIIlu/6-1II111 avcl'ages): C Nono 40 CFR l'ort 60, AIIII, A, Mcthod !)

PART UI,A.V.I,e,U1 SOZ Emlsrlou Rnto: 40 CFR l'ort 60 C NOlie Apllllndix A, Methods 1-4 ond 6

PART flU.V,I.d Condllr.t ElIllsslon Tests at 01' IIcar C NOllo maxi 11111111 capacities

l'AR'r flU.V.l.o Submit Ulutent·to-Tcst" Notification C NOlie 30 doys prlol' to Il1'ollosed test doto

PARTm.A.V.2,a AddltionallnrOI'II\I\t!OIl during t051lng: C NOIlD Pl'CSSl\l'O DI'OII OCI'OSS bnllhollsll

PART IIU.V.2,b AddltloRlIl hlfol'llIatioll dlll'llIlI testing: C Nonl) Sulflu'Contellt eool/coko blll'lIcll

PARTm,A.V.3.1\ Appllcoble Tesllng Uel}nlJoelllcnt C None

I'ART m.A.V.3.b Allllllcnble Testing Rcqllh'cmellt C None

PAR,}' m.A.V.3.c Applicable Testlug Rcqllh'oment C Nonc

PART IlI.A.V,3.d A\lpllclIbla Testing llcqlllr~lIIelll C NOllc

. \

l'ART II1.A.VI N/A (ThisIlel'mlt docs 1I0t hllVIl nny N/A N/A IItisecllllncOIis l'eqlllrelllclIls)

J. Any other material information that may indicate non-compliance with one or more ofthe above -

described applicable requirements for this facility must be described below:

Part nI.A.I.t DevintJoli Reports:

Due to the safe operution of the #2 Sonth KilJ1t kiln startup reqnires the bypassing of the

BaghOlise contml system to prevent damage and explosion to tile control system. Since the

startup/shutdown regulation exemptio.ns do not apply to our kiln operationt the propel'

procedure is to idclltify these occurrences as malfnnctions. As Indicated in the Quarterly

Deviation Reports, the following is a list of those times ofstartup ofthe #2 South Kiln during the

reporting pel'fod:

Mnrtin Marietta Mngnesla Sileelnltics. LLC Page 34 4/25/2005
( 01110 EPA TITLE V COMPLIANCE CERTIFICATION

Mnlfllllctloll Rlm0l'fS

04/1712004: StOl'tll}) No.2 Soutll I{llll- i12004004MR (Mal'tln Marletta ID)

07120/2004: Rcpflir Coni Supply Fall. Stal'tlllJ #2 Sontll Kiln - #2004009MR

08/04/2004: RCIJalt· I<:lltl TJ1mlon. Stal'tup #2 Soutll mIn· #2004012MR

08/13/2004: ID Supply Fall Repah' - Startllll #2 S01ltb Kiln· i12004015MR

10/0612004: RCllah' Coal SUllply Fan - BYllaSS il2 Soutb min· iJ2004018MR

(

(

Mlll'lIn Marietta Mllgncsla Slleclaltlcs, LLC Pagc35 4/25/2005
(

OHIO EPA TITLE V COMPLIANCE CERTIFICATION

Compliance Certification Section I - Facility Information

Complete this section of the form only once for the facility (See Compliance Certification Section IV uDder the Clarifying

Instructions at the end of this document for important additional information in filling out this part ofthe form.)

A..

B.

C.

D.

E.

(

Facility Name: Martin Marietta Magnesia Specialties, LLC

Facility Address: '55 Lime Road, Woodville, Ohio 43469

Facility ID[IO digits): 03-72-00-0127

--------------------- Date ofTitle V Permit Issuance: 06/20/03 ;....;..-..;.,;..,:--------------

Reporting Period: January through Decembel' of 2003

Compliance Certification Section II - General Terms and Conditions

(Part I of the Permit)

Complete this section ofthe COI'm only once for the facility (See Compliance Certification Section II under the Clarifying

Instructions at the end of tbis document for important additional Information in filling out this pal't of tbe form.)

F. Has your company complied with all the General Terms and Conditions stated in Part I(A) ofthe Title V

permit? ~YES NO

Ifno, indicate the paragraph number for each General Term and Condition for which compliance was

not maintained, a description ofthe excursion/deviation, and a description ofthe corrective action that

was taken to ensure that compliance will be maintained in the future.

(

Pel'lnlt

TernaNo. DeserlptloD ofExeurslonlDevlatlon Correetlve Aetion Taken

Martin Marietta Magnesia Specialties, !,LC Page 1 04/1512005
(

OHIO EPA TITLE V COMPLIANCE CERTIFICATION

Compliance Certification Section III - Facility Terms and Conditions

(Part II of the Permit)

Complete this section of tbe form only once for the facility (See Compliance Certification Section III under the Clarifying

Instructions at the end of this document for important additional information in filling out this part of the form.)

G. Provide for each term and condition in Pal't ILA "State and Federally Enforceable Section", by

appropriate paragraph citation, a briefstatement of how certification ofcompliance has been determined

for each term and condition and a summary ofall excursion/deviations that have occurred during the

compliance certification period. .

Please place an "X" in only one ofthe two options below

N/A Each lEU listed In Part U.A oftile Title V permit has complied with elleh applicable requirement established In the listed Permit to Install (pTI) and

each applicable requirement spedficd III OAC Chapter 3745-17, OAC ChApter 3745-18, and/or OAC Chapter 3745-21.

Except as Indicated for each lEU 08ted In the fllDowlng table below, each lEU listed in PartII.A orelle Title V permit has complied with each

N/A applicable requirement established In tbe listed Permit to"lnstall (PTI) and each applicable requirementspeelfled In OAC Cllapter 3745-17, OAC

Chapter 374S-18,lInd/lIr OAC Chapter 3745-21. (Please identify each intermittent compliant lEU in a separate row In the table below as applicable.)

Identify the Emission

Lhnltatlon/Colltrol

Measure or tbe Permit

Term No.

Method Used to Deterndue

Compliance'

Continuous (C)

or Intermittent

(I) Compliance?'

ExeurslonslDeviations

(

Partll.A.l 40 cmPart 63.53 (NESHAP)

40 CFR Pt 63;AAAAA Pal't I Application Submittal C

Partll.A.2 40 CFR Part 63.53 (NESHAP)

40 CFR Pt63;AAAAA Part II Application Submltta! N/A

Part II.A.3.a NESIIAP - Part II; Initial Notification

40 CIIR Pt 63;AAAAA within 120 days after Subpart N/A

PI-omul atlon

Pal't II.A.3.b NESHAP - Compliance Status

40 CFR PI 63;AAAAA Notlfieation; 60-days following N/A re ulred eom lIance demonstratllln

Those Documented

Within·

ExcurslllnJDevlatilln

Reports Submitted to

OEPA District Offiee

or Local Air Agency

(Identify Date of Eaeh

Re ort

Part I Application

Submitted Prior tll

Mil 152002

Other (Explain the Nature, Duration,

and Cau8e ofthe ExcursionIDevlatlon,

As Well As Any Correctlvc Action

Taken)

(

H. Any other material information that may indicate non - compliance with one 01' more ofthe above -

described applicable requirements for this facility must be described below:

There was no other material information to the best ofour knowledge!

Martin Marietta Magnesia Specialties, LLC Page 2 0411512005
(

OHIO EPA TITLE V COMPLIANCE CERTIFICATION

Compliance Certification Section IV - Significant Emissions Units Terms and Conditions'

(Part III of the Permit)

Complete this section ofthe form for each significant emissions unit. Emissions units with identical terms and conditions may

be grouped together (See "Compliance Certification Section IV" under the "Clarifying Instructions" at the end ofthis

document for important additional information in filling out this part ofthe form.)

Q. Significant Emissions Unit ID [4 characters]: POlS -----------------------

(

(

R. Provide for each term and condition in Part ill.A "State and Federally Enforceable Section" for the

emission unit, by appropriate paragraph citation, a briefstatement ofhow certification ofcompliance has

been determined for each term and condition and a summary ofall excursions/deviations that have

occun'ed during the compliance certification period. Please add rows as necessaryfor each Emission

/imitation/Control Measure specified in Part IlLA.Ii ofthe permit.

Identify the Emission Continuous (C) UmltatloDlCllDtrol Method Used to Determine

Measure or the Permit Compliance. or Intermittent Exeurslons/Devlatlons

Term No. (I) Compliance?'

Those Documented

Within

ExcurslonlDevlation Other (Explain the Nature, Duration,

RepOl·ts Submitted to and Cause ofthe ExcurslonlDevlatlon,

OEPA District Office As Well As Any Correctivc Action

or Local Air Agency l'aken)

(Identify Date ofEReh

Re ort

PART llIoA.I.1 Inspections 5 days/week - minimum I Malfunctlons/Out-ofOAC 374S-17-61(A) Sel'Vleej See Below

PART rIJ.A.1.I PE UndtRtlon: 79.9Ib/hr (Combined) C None OAC 3745.17-II(B)

PART llI.A.I.l 802 Limitation: 25.0 Ib 802/ton of C None OAC 374S-IS-7S(E)(I) product

PART III.A.I.l Inspections 5 daysfweek - minimum I MRlfunctlonHlOut-ofOAC 3745-17-67(B)(I) Service; See Below

PART 1lI.A.I.l Employ RACM: I1I.A.I.2.b C None OAC 3745-17-08(8)

PART IILA.I.2.a OAC3745·17·11(A)(3): Combine PE C None emissions from PO)5 and POl9

PART 1II.A.1.2.b.1 RACM: Enclosures (Buildings) and C None hooding to minimize fugitive emissions

PART 1lI.A.I.2.b,lI RACM: All fugitive dust captnred C None wltllin building - vent to ESP #0836

PART IILA.I1.1 Only coal, petroleum coke, and/or C None natural gassllall be burned.

PART III.A.II.2 Sulfur Coutent ofCoaUCoke: less tban C None content measured at most reeent test

PART IILA.III.) Samples of eoalleoke: analyze for C NOlie sulfur content and heat content.

PART IlloA.I1I.2 Mainhiln monthly: total quantity of . C None coal/coke received; analytical results

PART III.A.IIJ.3 Egress Points: VE Observation C None Inspections 5 days/week

PART IILA.IlI.4 ESP: VE Observation Inspections 5 C None dayslweek

PART III.A.I1I.S ESP Opacity Observation: once/month C None 40 CFR Part 60, App. A, Method 9

Martin Marietta Magnesia Specialties, LLC Page3() 04/1512005
(

c

(

OHIO EPA TITLE V COMPLIANCE CERTIFICATION

PART III.A.III.6 CLARII1ICATION PARAGRAPH N/A NlA

PART I1I.A.IV.1 Fuell'ype Burned Devilltion; rcport N/A All required reports

within 30·days ofoccurrence submitted

PART I1I.A.IV.2 Sulfur Content Deviation: report N/A All required reports

within 45·days ofoccurrence submitted

PART III.A.IV.3 Quarterly Report: ESP Out-of·Service e All required reports

Summaries submitted

PART IILA.IV.4 SellliamlUsl Report: Egress Point e All required reports

Devialion and Corrective Actions submilled

PART I1I.A.IV.S SemiannualReport: Baghouse e All required reports

Deviation and Corredive Actions submitted

PART III.A.IV•.6 SemiannualReport: Opacity Deviation e All required reports

and Corrective Adions submitted

PART IILA.V.l.lI Emission testing to be condncted e None within 3·months after permit Issued.

PART III.A.V.I.b Emission testlug: demonstrate C Nooe compliance with PE and 802, Opacity

PE Emission Rate: 40 CFR Part 60, ,

PART III.A.V.I.c.1 Appendix A, Methods 1-5 C None

PART lILA.V.I.c.1i 20% Opacity (3-miJI/6-min averages): C None 40 CFR Part 60, App. A, Method 9

PART liLA.V.I.cJII S02 Enllsslon Rate: 40 CFR Part 60 e None Appendl. A, Methods 1-4 and (;

PART 1II.A.V.I.d Conduct Emission Tests lit or near e None maximum capacltlcs

PART I1I.A.V.I.e Submit "Intent-to-Test" Notification C None 30 days prior to proposed tcst date

PART I1I.A.V.2.a Additionalinrorlllatlon during testing: C None SulfurContent coal/coke burned

PART III.A.V.2.b Additional Information during testing: C None Power Input (kW) of each "fR set.

PART IlI.A.V.3.a Applicable Testing Requirements e None

PART IILA.V.l.b Applicable Tes.ling Requirements C None

PARTIILA.V.3.e Applicable Tesllug Requirements C None

PARTlII.A.V.l.d Applicable Tesling Requirements C None

PART IILA.VI N/A (ThiJI permit does not have any N/A N/A miscellaneous requirements)

S. Any other material information that may indicate non-compliance with one or more ofthe abovedescribed applicable requirements for this facility must be described below:

Part I1I.A.I.1

Deviation Reports:

Due to the safe operation ofthe #1 South Kiln, all kiln shutdowns and startup require the bypassing

ofthe ESP control system to prevent damage and explosion to the control system. During the 3rd

Quarter, and as indicated in the 3rd Quarter Deviation Report, the following is a list ofthose times

ofshutdown1startup ofthe #1 South Kiln:

A. 3rd Quarter Deviation Report for the period ofJuly 1,2003 through September 30,2003

submitted by October 31,2003:

Martin Marlelta Magnesia Spel:ialties, LLC Page 31 04/1512005
(

OHIO EPA TITLE V COMPLIANCE CERTIFICATION

7/01/03· Ii South Kiln: '1 Cooler Belt Malfunctioned, placed kiln on auxiliary power - removed solid fuel- 9 hours

7/08/03 -'1 & #2 South Kilns: Fire In Ball Mill Room cuased emergency shutdown of both kilns - 6 hours; 20 minutes to shutdown.

7/11/03 -'1 South Kiln Startup: ESP on bypass to reheat kiln until kiln reached operating temperature ·13 hours

7/25/03 ·'2 South Kiln Startup: Baghouse on bypass to reheat kiln until kiln reached operating temperature· 41 hours.

8/14/03 - Full Plant Power Outage· result of northeast grid ·10 minutes for plant (est.) • affected .1 South Kiln for 5 hours.

8122103 - Power Outage· Electrical storm downed Toledo Edison's lines. Affected'1 &'2 South Kilns 9 hours· Restarted '2 Kiln only.

8/30/03 • Ii South Kiln Startup: ESP on bypass to reheat kiln until kiln reached operating temperature· 13 hours.

B. 4th Quarter Deviation Report for the period of October 1, 2003 through December 31,2003

submitted by January 31, 2004: '

11/22103: E;SP Rectifier B Electrical Short., Shutdown Ii South Kiln to Repair. ,2003015MR (Marttn Marietta 10)

1211/03: ESP Broken Module Wires. Shutdown .1 South Kiln to Repair. '2003010MR (Martin Marietta ID)

1214J03: Rectifier A· ESP electrical short. Shutdown #1 South Kiln to repair - ,2003011MR (Martin Marietta 10)

12/10/03: ESP Module Electrical Problems. Shutdown #1 South Kiln to Repair - .2003012MR (Martin Marietta 10).

12121/03: '1 South Kiln 10 Fan Repair/Balance. Shutdown '1 South KUn - '2003013MR (Martin Marietta ID)

12127/03: ESP Module Electrical Problems. Shutdown'1 South Kiln to Repair· '2003014MR (Martin Marietta 10)

Due to the safe operation of the #1 South Kiln, the ESP control system is protected by a high and

low fuel combustibles safety shut"offto prevent damage to the ESP system. Therefore, the

following "out-of"service" days during the reporting period is as follows:

(

(

'.

8/212003

8/3/2003

8/412003

8/6/2003

8/14/2003

811512003

8/19/2003

8/2212003

9/212003

9/3/2003

9/4/2003

9/18/2003

9/20/2003

Date

6/28103

7/112003

7/3/2003

7/612003

7/6/2003

7/21/2003

7/22/2003

7/23/2003

7/25/2003

7/27/2003

7/28/2003

7/30/2003

Both

Both

Both

Both

Both

Both

Both

Both

Both

Both

Both

Both

Both

ESPSectlon

Both

80th

80th

Rect.B

Both

80th

80th

80th

80th

Both

Both

Both

45min

20min

10mln

40min

5hrs

15min

8hrs-30min

9hrs

40min

1hr

2min

3mln

1hr-20mln

Duration

1hr High combustible safety analyzer malfunctioned

1hr-20min. High combustible safety analyzer malfunctioned

5mln High combustible safety analyzer malfunctioned

35min Electrical Shortout

40min High combustible safety analyzer malfunctioned

4min High combustible safety analyzer malfunctioned

1hr Coal valve and fan unbalanced

4hrs Coal valve and fan unbalanced - main!. Patched fan

20mln Temperature safety damper malfunctioned

30min High combustible safety analyzer malfunctioned

55min High combustible safety analyzer malfunctioned

10mln High combustible s~fety analyzer malfunctioned

High combustible safety analyzer malfunctioned

High combustible safety analyzer malfunctioned

High combustible safety analyzer malfunctioned

High combustible safety analyzer malfunctioned

Power outage

High combustible safety analyzer malfunctioned

Kiln drive malfunction - auxiliary fire - no solid fuel - no VE

Power outage

High combustible safety analyzer malfunctioned

Coall.D. fan maintenance - auxiliary file - no solid fuel- no VE

High combustible safety analyzEir malfunctioned

High combustible safety analyzer malfunctioned

Kiln drive malfunction - auxiliary fire - no solid fuel· no VE

Marlin Marietta Magnesia Speelaltles.LLC Page 32 04/151200S
3hrs-35mln Kiln drive malfunction auxiliary fire - no solid fuel - no VE

35mln High combustible safely analyzer malfunctioned

Both

Both

OHIO EPA TITLE V COMPLIANCE CERTIFICATION

9/23/2003

9/25/2003 (

10/6/2003

10/10/2003

10/1412003

11/3/2003

11/4/2003

11/5/2003

11/6/2003

11/18/2003

11/20/2003

11/21/2003

11/28/2003

11/30/2003

12/1/2003

121212003

12/4/2003

12/6/2003

12111/2003

12/19/2003

12/21/2003

1212712003

Both

Both

Both

Both

Both

Both

Both

Rect.A

Both

Both

Both

Rect.B

Both

Both

Both

Both

Both

Both

Both

Both

1Q-mln

30·mln

5-mln

10-mln

5·mln

5·mln

5·mln

24-hr

5-min

5·min

3·hrs

24·hr

20-hr

5·hr

18-hr

1~mln

15-mln

8-min

20-hr

12-hr

High combustibles safety device - coal fan repair· kiln on

auxlJlary

High combusllbles safety device

High combustibles safety device

High combustibles safety device

High combustibles safety device

High combusllbles safety device

Analyzer Malfunclloned - Safety

ESP Rapper electrical problem

ESP Module Electrical Wire Problem

High combustibles safety device

Maintenance on Coal and ID fan· kiln on aUlllJlary power

ESP Rectifier B electrical problem

ESP wire repair - kiln shutdown

Kiln trunlon repair. kiln on aUXiliary power

Repair work on kiln - kiln shutdown

High combusllbles safety device

High combusllbles safety device

Analyzer Malfunctioned - Safety

ID Fan repair - kiln shutdown

ESP broken wires kiln shutdown

(

(

Martin Marietta Magnesia Speeialtles, LLC Page 33 0411.512005
(

OHIO EPA TITLE V COMPLIANCE CERTIFICATION

Compliance Certification Section IV - Significant Emissions Units Terms and Conditions

(part III of the Permit)

Complete this section ofthe form for each significant emissions unit. Emissions units with identical terms and conditions may

be grouped together (See "Compliance Certification Section IV" under the "Clarifying Instructions" at the end ofthis

document for important additional information in filling out this part of the form.)

F. Significant Emissions Unit 1D [4 characters]: POl9

(

(

G. Provide for each term and condition in Part UI.A "State and Federally Enforceable Section" for the

emission wit, b'y appropriate paragraph citation, a l!!!!1 statement ofhow certification ofcompliance

has been determined for each term and condition and a summary ofall excursions/deviations that have

occurred during the compliance certification period. Please add rows as necessaryfor each Emission

limitation/Control Measure specified in Part IILA.Li ofthe permit.

Identify the Emission Continuous (C) limitation/Control Method Used to Detel'Dllne

Measure or the Permit Compliance' or intermittent Excursions/Deviations

Term No. (I) Compliance?'

Thosc Doeumcnted

Wltltln

ExcurslollJDevlatlon Other (Explain the Natul"c, Duration,

Reports Submitted to and Cause of the ExcursloDJDevlatlon,

OEPA Dlstl'let Office As Well As Any Corrective Action

or Local Air Agency Taken)

(Identify Date of Each

Re ort

PARTIII.A.I.1 Inspeetions S days/weck- minimum I Malfunction Reports OAC 374S·17·07(A)

PART III.A.1.l PE limitation: 79.9 'b/br (Combined) C None OAe 3745·17·ll(D)

PART m.A.I.l 802 Limitation: 25.0 Ib S02/ton of C None OAC 374S-18-78(F) product

PART 1Il.A.I.l Inspections 5 days/week - minimum I Malfunction Reports OAC374S-17-07(8)(I)

PART III.A.I.l Employ RACM: III.A.I.2.b C None OAC374S-17-08(B)

PART III.A.I.2.a OAC374S-17-U(A)(3): Combine PE C None emissions from POlS and P019

PART III.A.I.2.b.1 RACM: Enclosures (Buildings) and C Nonc hooding to minimize fugitive emissions

PART III.A.I.2.b.1I RACM: All fugitive dust cllptured C NOlie within builcllng - vent to bh #1085

PART IIU.n.1 Maintain Pressure Drop Across C None Baghouse: within 6-16lnehes water

PART III.A.II.2 Onlyeoal, petroleum coke, and/or C None natural gas shall be burned.

PART mA.II.J Sulfur Content ofCoal/Coke: less thaR C None eontent measured at most recent test

PART m.A,1I1.l Maintain and Record Pressure Drop: C None Frequeney: Weekly - minimum

PART 1II.A.III.2 Samples ofeoal/eoke: analyze for C None sulfur content and heat content.

PART m.A.III.3 Malntllin monthly: total quantity of C None eoalJeoke reeeived; analytical results

PART III.A.IIM Egress Points: VE Observation C None Inspections S days/wcek

Marlin Marietta Magnesia Specialties, LLC Page 35 04/1512005
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OHIO EPA TITLE V COMPLIANCE CERTIFICATION

PART III.A.III.5 Bagltollse: VE Observation C None Inspedlons 5 daysJweek

PART III.A.IV.I Quarterly Report: Pressul'e DI'op C All required reports

Devlatlou and Correetive Adion submitted

PART III.A.IV.2 Fuel Type Burned Devlafion; repol't N/A All required reports

within JO-days of oeeurl'enee snbmltted

PART III.A.IV.3 Sulfur Content Deviation: report N/A All required reports

within 4S-days of oceurrenee submitted

PART III.A.IV.4 Semiannual Report: Egress Poillt C All requlred reports

Deviation and COl'reellve Acfions submitted

PART III.A.IV.S Semiannual Report: Baghouse C All required reports

Deviation and Correetlve Actions submitted

PART IlI.A.IV.6 Semiannual Report: Opacity Deviatioll C Ali required reports

and Correetive Actions submitted

PART In.A.V.I.a Emission testing to be coududed C None within J-montbs after permit Issued.

PART III.A.V.l.b Emission testing: demonstrate C None compliance wltb PE and 802, Opacity

PART III.A.V.l.c.1 PE Emission Rate: 40 CFR Part 60, C None Appendix A, Methods I-S

PART IILA.V.1.c.1I 20% Opaeity (3-mio/6-min averages): C None 40 CFRPart 60, App. A, Method 9

PARTIII.A.V.I.c.ii1 S02 Emission Rate: 40 CFR Part 60 C None Appendill: A, Methods 1-4 and 6

PART IlI.A.V.l.d Conduct Emission Tests at or near C None maximum eapacitles

PART III.A.V.l.e Submit "Intent-to-Test" Notlftcatlou C None JO days prior to proposed test date

PART IlLA.V.2.a Additional informallon during tesllng: C None Pressure Drop across bagbonse

PART liLA.V.2.b Additional Information dul'1ng testing: C None Suiful' Content coal/coke burned

PART 1II.A.V.3.a Applicable Testing Requirement C None

PART III.A.V.3.b Applleable 'festing Requirement C None

PART liLA.V.J.e Applicable Testing Requlremellt C None

PART III.A.V.3.d Applicable Testing Requlrement C None

PART III.A.VI N/A (This permit does not have any N/A N/A miscellaneous requirements)

H. Any other material information that may indicate non-compliance with one or more ofthe abovedescribed applicable requirements for this facility must be described below:

Part III.A.I.t Deviation Reports:

Due to the safe operation orthe #2 South Kiln, kiln startup require the bypassing oCthe

Baghouse control system to prevent damage and explosion to the control system. Since the

startllp/shutdown regulation exemptions do not apply to our kiln operation, the proper

procedure is to identitY these occurrences as malfunctions. During the 3rd Quarter, and as

indicated in the 3rd Quarter Deviation Report, the following is a list of those times ofstartup of

the #2 South Kiln:

7/08103 -'1 & '2 South Kilns: Fire In Ball Mill Room cuased emergency shutdown of both kilns· 6 hours; 20 minutes to shutdown.

7/25/03 -'2 South Kiln Startup: Baghouse on bypass to reheat kiln until kiln reached operating temperature. 41 hours.

8J22/03 • Power Outage· Electrical storm downed Toledo Edlson·slines· Affected'1 & #2 South Kilns 9 hours· Restarted #2 Kiln only.

Mllrtlo Marietta Magnesia Speeiallles, LLC Pnge36 04/1512005
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Martin Marietta

=M=a=9=n=e=s=l=a=S=p=e=c=l=a=lt=ie=s:::,=L=L=C========== ==~

755 Lime Road, Woodville, OR 43469 USA

Telephone: (419) 849-4200 Fax: (419) 849-4246

October 2,2006

Jim Orlemann, Manager

Division ofAil' Pollution Control

Ohio Environmental Protection Agency

Lazarus Govt. Center

P.O. Box 1049

Columbus,OH 43216-1049

RE: OAC 3745-17-07 SIP Exemption Request for Martin Marietta

Comments on OEPA's September 15tll Interested Parties DRAFT

Dear Mr. Ol'1emann:

On September 15,2006, the Ohio Environmental Protection Agency provided draft language

proposing a rule exemption for Martin Marietta Magnesia Specialties, LLC ("Martin Marietta")

from the requirements ofO.A.C. §3745-17-07(A) during start-up and shutdown ofUme

producing kilns at Martin Marietta's Woodville, Ohio facility ("Woodville facility"). Consistent

with our September 27t11 telephone conversation. Martin Marietta submits the following

comments on this "interested parties" DRAFT.

First, Martin Marietta respectfully requests that Ohio EPA delete the phrase "with a solid fuel"

from subsection (A)(3)G)(ii) so that firing prior to the introduction ofsolid fuel will also be

exempted. Our standard start-up procedure has stone feed beginning a couple hours before the

solid fuel addition. This startup sequence was previously demonstrated by our 12115/05

submittal, which included a 4/29/05 kiln log for the #1 kiln-ESP unit. Thus, the needed language

would read:

(ii) The start-up ofany kiln equipped with an electrostatic

precipitator, fl:om the time firing [DELETE - with a solid fuel - DELETE]

begins until a stable firing condition is achieved, but not longer than

six. hours from the time firing with a solid fuel begins.

Martin Marietta also requests that Ohio EPA add a new subparagraph (iv) to address shutdown

or idling ofthe #1 kiln-ESP unit. As explained in Martin Marietta's 8/24/06 letter, the 2003-

2005 compliance certification malfwlction reports for both kilns showed a number of

"shutdowntl notifications.
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OAC 3745-17-07 SIP Exemption Request for Martin Marietta

October 2, 2006

Page 2 of3

Though a kiln shutdown will usually be associated with a staliup (or restarting), we respectfully

request that OEPA consider adding the following language to specifically address a kiln-ESP

shutdown:

U(iv) The shutdown of any kiln equipped with an electrostatic precipitator

(ESP), after the temperature ofthe exhaust gases from the kiln has dropped

below six hundred (600) degrees Fahrenheit at the inlet ofthe ESP."

Please advise me if you have any questions on this submittal or need additional assistance or

information to support Maltin Marietta's SIP exemption. Thank you for your continued work on

this important matter.

Sincerely,

JoefGreen

Environmental Engineer

cc: Lee Burkleca, Ohio EPA-DAPC

Tom Kalman, Ohio EPA-DAPC

Don Waltermeyer, Ohio EPA-NWDO

Joe Reilly, MMMS Woodville

Tim Tawney, MMMS Woodville

Yvonne Bailey, Esq., MMM Raleigh

April Bott, Esq., Chester, Willcox & Saxhe LLP

10·2-06 MMMS Response Letter_vl.DOC
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OAC 3745-17-07 SIP Exemption Request for Martin Marietta

October 2, 2006

Page 3 of3

PROPOSED DRAFT REVISIONS OF OAC RULE 3745·17·07

Mattin Marietta Magnesia Specialties, LLC

COMPLETE TEXT - October 2, 2006

(j) The following kiln operations at the "Martin Marietta Magnesia

Specialties, Inc." facility (OEPA premise number 0372000127) located at

755 Lime Road, Woodville, Ohio, provided that the owner or operator

maintains daily records which clearly document the dates, beginning

times and ending times for the operations:

(i) The stalt-up ofany kiln equipped with a baghouse, until the stone

feed to the kiln begins.

(ii) The statt-up ofany kiln equipped with an electrostatic

precipitator, from the time fIring [DELETE - with a solid fuel- DELETE]

begins until a stable frring condition is achieved, but not longer than

six hours from the time firing with a solid fuel begins.

(iii) The shutdown ofany kiln equipped with a baghouse, after the

temperature ofthe exhaust gases from the kiln has dropped below two

hundred fIfty degrees Fahrenheit at the inlet ofthe baghouse.

[ADDED (iv) The shutdown of any kiln equipped with an electrostatic precipitator

(ESP), after the temperature ofthe exhaust gases from the kiln has dropped

below six hundred (600) degrees Fahrenheit at the inlet ofthe ESP.]

For the purposes ofthis paragraph, "start-up" shall be defmed as the

point ofcommencement offrring the kiln and /Istable fIring condition/I

shall be defmed as the firing condition that exists when the

throughputs ofprocess material. fuel and combustion air have been

stabilized in a manner that consistently results in complete combustion

within the kiln and concentrations of combustibles within the exhaust

gases from the kiln that are within established safety limits.

10-2-06 MMMS Response Letter_vl.DOC