P.o. Pltt.barah, PA 15251-6399, Athl. TSCA Uoer Fee. 

Part I - OENDAL INFOllMATION 

You mal pJOvide the C'llneatiy correct Chemlal Ablllrada (CA) Name of the new ch..1ClII BIlbaLutce, eve. If you dUM the IdenUty _ COllfideatlal. Yo.. may 

aatll.odu .nUI..reo- 10 'lIbmlt chelllkalideatity iAlormolliloa for you, but 

your "bmbaloa will aot be coraplde lIlId lAe review will aol beglllllam EPA 

l'l!CIlI_ th. IIllollUlloa. A IeItoer a IIlIpped of YOIII'.lIb....loa sll.ould ' ~youTS _ fee WeaUflaliOllllumbe. You mal.ubllllt _ onSi.al 

• d two copl_ ofthlllIII&e lacI'Ildbii aU leIt dlia. IfJOIl claimed ally 

Inf_adon .. colLfldeau.u. a "'1liiie aaaitiud copy mlilt abo be nbmltted. 

Part D - HUMAN JSXPOSUKE AND ENVIRONMENTAL RELEASE 

Ifthere areRVeral_ufactuft,. p.-In" or _ opeGllionato be desaibeof III 

Part II, Mdl.,.. A .... B ofthll notice, reproduce the aec:tIoDli as needed. 

partm-USTOFA1TAatMENTS 

Allach addlliOllal_heeta Ifthere la.ot enonp s,-to a.nawer a question fully. 

Labe1 uch coathluatiOllalaeet willa the coml!llpoadlnl HCtIOll hudlng. In Part 

DI.li.JI 0.- oIItacluBeIltl, ally .... d... or other d... _d ally optional 

Infol1Milo.lnduded In lAe lloik£ 

OPTIONAL INPOJlMATION 

'YOII ...,. IIldude ally InfoftlUltloa thlll yoa wut 'EPA to coulder 111 evalllolll", 

the 11_nbat.uKe. Oa PIlle 11 of thll £0-., .p_la.. beea pmyWed (or you 10 

dMCl'lbe poIlutloa p..."nt!OIl mwl recydlnllalo..alloa you IlII)' ....ve rqJaMlng the n_.abltmoe. 

So-ailed "blndin,- bGlr__Included throughout tllil £Om loryou 10 IIldlc.ate 

JOur wiUlngn_to bebooACI to CIUtaIa ltilleme. you lUke la'.... aotlor,. nch 

... us.e" produc:tioa vol_, protec:tlve eIlulpm"t ••• TII.Ia option II IIltended to red.-.1111 that IOlItIaeI1_lIIptJ1y the development of _tordl!!l1l or 

Slglliflcmt New UNJllllell. Except I.. the case of ellernplioa appllcallou "ach u 

'lMEA, LVE., LOItEX) when! cataI.lu-atJoa provided In .uda noUflcoIIIlon III 

bllldlni OIllAe IIlItalttawhea ..Asncy approY5 the _ptlon application, 

checId", a badlal bGlr lal.....otIce by Itlelf proll.lblt tile submllter 

froa &oIIIardevilll1oS fro.. tlae lafoDlUlllOll (except da...lClIIldeat!ty) reported In 

thelona. 

CONPlDJSN11ALITY CLAIMS 

'Y011 may cIaIIII .yInfomWloa In iJllI aotke .._lId.lIal. To _It a clal .. 

on the form. IIUIIk.'"tile «...fldelltlal bGlr ..... to tbe h,lo......loa tb. you dUm 

as conlld_tIal. To _rt a cIaI.. In an .attachment, drcle or bradcet the 

illfonaatloll)'Ou clallII .. confldeatW. «)'911 dalm lofprmatigp 10 tb, patl,. u 

G9Pftdgtlal ypg mwd akg prgYid. a MPUIzc4 nnlOD of'lac lUlU...Clpclu!jiDS idt.1cl!m...lIl. fill' addltloullMtrudiOlla Oft clalmlnslnlorm;dloa _ 

_lIdeutUJ., JRd llae Instructlou MaIlUal. 

[i] Mark 00 If my IDfonn&l!oft la this aotlce II claimed u confidellllal. 

EPA FORM mo..25 (Rev. 5-95) 

/ 


PUBLIC COpy 

to!llXtAIPPN'ved. O.M.B. No. :lJ1'O-OO12. Approval Expires 

U. S. ENVIRONMENTAL PROTECTION AGENCY 

ft EPA PREMANUFACTURE o NOTICE 

AGENCY USE ONLY 

FOR NEW CHEMICAL SUBSTANCES 

DOCUMENT CONTROL OFFICER 

OFFICE OF POLLUTION PREVENTION 

AND TOXIC SUBSTANCES, 7407 

U.S. E.P.A.401 M STREET, SW 

Enter the total number of pages 

in the Premanufacture Notice 

Company S~tized 

•You mal pmvide alllafomUilion ~1I_ed iA iJll. £0_ 10 IlI.e extent tlu! It I. bow. to or_nably UCIIlI:Llln.able by you. Make _aab1e "moll.If you 

aot meactual daL1. 

• Belore)'01l _plete thk fona, yoa .hould IUlllile "Iuil1ldion. Manual for Preatallufactun! Notification" (lAe IlIBtmdlOlll MaIlaa] Is avallable from the 

Substaa_CoGtnll Ad (TSCA) laformoliloa Service by alII", 202-55f..1404i, or fulo, 202.-55f..5603). 

·If a _ fee ...been remitted for tll.ls notice (400 CfK '100045), tndkate In the boxes above tile Ts.._rfee Identification .wnberyoa un lenerated. 

R_..tter. youuerfee 10 Il'llmber mult abo appur on you r coltl!llpondln, fee rmnllbnor,. wll.ldlia IeIIt to: EPA, H Q Aemaatill, Opemtlo...Bruch lrI'.....z'",. 

'Il!STDATAANOomERDATA 

Yo... are ~ulred 10 ....bmlt iIllI ..data a your ~IIor coatrol ...d to provide a de8Criptioa of iIllI other data ~a to or _auly 

ascerWnabJe by you, If tII_d....... reIoIIIed to tlae IaNlth &ad 

envll'llllDUmtaleffec:U of lAe .aufadun!, p_in"dlatr:lbatloll 

In .,..MIIl-=e, ..... or dlllpo&;1l of.lI.e a_dlemlal StlIIldard 

nt~n! dtltlou may belIubmllted for d... la tile opea Kleatlflc 

Uierolilift. Onppkk19t!jata (wriHq ig bIU.b). Pot IIUIImKl..of data • 

mllll be nbmitted If the)' do Pot .,peariD the opcu Iltcpb&rc. \'011 should 

cleUIyld..tlfy wW......d...ill OIl the nbataace or oa an anal"" AlIO, 

the chemk:.U composltloa oftile leted 1IUIIenal Jhould be characterized. 

FolioMft, are examplea of tat d....... otller daL1. Data ahould be 

lIubmltted acc:oldlng to the reqnlrementl of 5no.SO of the Premaufacture 

Notlflc:.1l:loa lb.1e (40 crR Part 720). 

Test Data (Check Bdow aDylnduded iD tlllII aotice) 

• Enviroamadal fate d;d. D Yes 

• Health effed:s d ..... D YM 

• Environmental dfeda data 0 Yea 

• PhyakallCheDlIClll Properties'[iJ Yea 

• Otherdata 0 Yes

JlI8k_mn.. 

Sll1IdaNlac:tivlty 

TIWIIl data DOt III tile 

or coatrol of Ille ...., "A phyalal aIld che!nlc.ll propenlell worbheet II louted on the l.g.ge 

of tbll form. c..... 

TYPE OF NOTICE (Check Oaly One) i;;

-."'­

, IiU 	 PMN (P"'!l'uufactuJ:e Notia.) W 

o 	lNTERMEDlAn:l'MN (jubmlited lu sequence with flDal prelud 

PMN) ~ 

o SHUN (Significant New UK NoUae) 


o TMJiA (Teat Marketing Ex_plloa Application) 


LVE tLow VolltJlle ElI_pilon). 411 CfK 7%3.SO (d(ll 


o LOREX tLow ReleaseJl.ow Exposure ElIempt!oll)" 723.so(d(%) 


o LVE ModlfiQtJoll 0 LOREX Mcdlfic!.'!.ioa 


o 

IS nns A CONSOLIDATED PMN? 0 Yes

/I of chemical" ____ 


(Prenotice Commonlcallon /I nII!"lred, enler II oft page 3) 


Replaces previous editions of EPA Form 
Public reporting burden for this collectioo of information is estimated to average 110 hours per response, indudlng lime for reviewing lnstructl.oru 

searching existing data sources, gathering and maintaining the data needed, and completing and reviewing the collection of information. Send 

comments regarding the burden estimate or any other aspect of this colledioo of information, including suggestions for redudtlg this burden, 

to QUeI, Information Policy Branch, PM-223, U.S. Environmental Protection Agency, 401 M. St., S.W." Washington, D.C. 20%0; and to the Office ( 

Mana&ement and Bud.slet. Paperwork Redudion Act (2!TlO-OO12), WasIrlngton, D.C. 20503. 

CERTIFICATION 

I certify that to the best of my knowledge and belief: 

1. 	 The company named in Part I, section A, subsection la of this nonce form intends to manufacture or import lor a 


commercial purpose, other than in small quantities solely for research and development, the substance identified in 


Part I, Section B. 


2. 	 All information provided. in this notice is complete and truthful as of the date of submission. 

3. 	 I am submitting With this notice all test data in my possession or control and a description of all other data known to 


or reasonably ascertainable by me as required by §720.50 of the Premanufacture Notification Rule. 


Additional Certification Statements: 

If you are submitting a PMN, Intermediate PMN, Consolidated PMN, or SNUN, check the following user fee certification 

statement that appUes: 

S The Company named in Part I, Section A has remitted. the fee of $2500 specified in 40 CFR 700.45 (b), or 

o 	The Company named in Part (, Section A has remitted. the fee of $1000 for an Intermediate PMN (defined @ 40 CPR 700.4: ) in 

accordance with 40 CPR 700.45(b), or 

o The Company named in Part [, Section A is a small business concern under 40 CFR 700.43 and has remitted 


a fee of $100 in accordance with 40 CPR 700.45 (b). 


Ifyou are submitting a low volume exemption (LVB) application in accordance with 40 CFR 723.50 (c) (l) or a Low 


releue and low eKposure exemption (LoREX) application in accordance with 40 CFR 723.50 (c) (2), check the following 


certification statements: 


o The manufacturer submitting this notice intends to manufacture or import the new chemical substance for 

commercial purposes, other than in small quantities solely for research and development, under the terms 


of 40 CFR 723.50. 


o The manufacturer is familiar with the terms of this section and will comply with those terms; and 

o The new chemical substance for which the notice is submitted meets all applicable exemption conditions. 

o If this application is for an LVE in accordance with 40 CFR 723.50 (c)(1), the manufacturer intends to commence 


manufacture of the exempted substance for commercial purposes within 1 year of the date of the expiration of the 


30 day review period. 


The accuracy of the statements you make in this notice should reflect your best prediction of the anticipated facts regarding the chemiall 

substance described herein. Any knowing and willful misinterpretation is subject to aiminal penalty pursuant to 18 USC lOOt. r-C-o-n-fi-d-en-ti-iill-~-II 

Signature of agent - (if appUc.ab(e) Date

FORM EPA '7710-25 (Rev. 5-95) 	 Page 2 
lao Person 

Submitting 

Notice 

(in U.S.) 

b. Agent (if 

applicable) 

Part I - GENERAL INFORMATION 

Dr. James E. Mumby 

VANTICO INC. 

address (number 

1 Fields Lane 

City, State, ZIP Code 

Brewster, NY 10509 

Name of authorized. official 

Mailing address (number and street) 

City, State, ZIP Code 

Director, E H & S 

Telephone 

c. If you are submitting this notice as part of a joint submission, mark (X) this box. ----------------. 

Joint Name of authorized official 

Submitter 

(if applicable) 

2. Technical 

Contact 

(in U.S.) 

Mailing address (number and street) 

City, State, Code 

Name 

-Dr J 

Company 

Vantico Inc. 

Mailing address (number and street) 

281 Fields Lane 

City, State, ZIP Code 

Br 0509 

if you have had a prenotice commWlication (PO concerning this notice 

and EPA assigned a PC Number 10 the notice, enter the number. 

if you previously submitted an exemption application for the chemical 

substance covered by this notice, enter the exemption number assigned 

by EPA. if you previously submitted a PMN for this substance enter the 

PMN number assigned by EPA (i.e. withdrawn or incomplete). 

---,l>~ 

If you have submitted. notice of Bona fide intent to manufacture or 

import for the chemical substance covered by this notice, enter the 

notice number assigned by EPA. >­

Type of Notice - Mark (X) 1·0 

D 

Manufacture 

Only 

Position 

Telephone 

Position 

Director E H & S 

Telephone I 

I 914 785-3382 

2 Import . Only 

Mark 00 

lfnone 

Mark (X) 

if none 

Mark (X) 

if none 

D BindingOptIon 

Mark (x) 

3. D Both 

FORM EPA 7710-25 (Rev. 5-95) Page 3 
Part I -- GENERAL INFORMA nON - Continued 

Section B _ CHEMICAL IDENTITY INFORMATION- You.1IIt p-ovtdea C1.II'!:I!lItly camdO!emk.U Abtitrac:ls (CA) lWM of • baaed on the nlIIthCollective Index (9C) 01. CA nornendaiure 

00 "Confidential" box next to any ileal you claim as 

Complete either item1 (Clas.l or 2l11bstancea) or 2 (Polymen) as appropriate. Complete all other items. 

If another person will submit chemical identity information for you (for either item 1 or 2), mark 00 the box at the risl!t. 

and address of that in a continuation sheet. ..... 

1. Clas.l or 2 chemicalsubltallc:ea (for definitions of class 1 and class 2 substano!s, see the Instructions Manual) 

a. Class ofsubstance - Mark 00 1 gJ Oa!llll or 2 0 <lass 2 

b. ClIemical name (Currently correct Qem1cal Abstracts (eA) Name that Is consistent with TSCA Invenlory listings for similar SUI)8taDCleS. 

For Oass 1 substano!s a CA Index Name must be provided. For Class 2 substances either a CA Index Name or CA Preferred Name 

be provided. whichever is appropriate based on CA 9C nomenclature rules and conventions.). 

c. Please identlly which method you used to develop or obtain the spedlied chemical Indentity Information reported In this notice: 


(chedc one).
[i] Method 1 (CAS Inventory Expert Servk.e - a copy of the Identification DMethod2 (Other Source) 

report obtained from the CAS Expert Service must be 

submitted as an attachment to 

d. Molecular formula and CAS Registry Number (if a number already exists for the substance) 

e. For a dalll substance, provide a complete and correct chemical structure diagram. For a clan 2 substance - (1) List the immediate 


precursor substances with their respective CASRegIstry Numbers. (2) Describe the nature of the re.:tion 01' proc:ese. (3) Indicate the 


range of compoaition and the typical oomposlHon (where appropriate). (4) Provide a correct representative or partial chemical 


structure diawam, all complete as can be known, if one can be reasonably ascertatned. 


Mark (X) this box if attach a continuation sheel. 

FORM EPA 771~25 (Rev. 5-95) Page 4 
Part 1.- GENERAL INFORMATION ..- Continued 

~ Section B - CHEMICAL IDENTITY INFORMATION - Continued 

2. Polymers (For a definition of polymer, see the Instructions Manual.) A/tJf .4,<f?h . ~b/e (AI/A) ~;~ a. Indicate the number-average weight of the lowest molecular weight composition of the polymer you intend to manufacture. 

Indicate muimum weight percent of low molecular weight species (not including residual monomers, reactants, or solvents) below 

500 and below 1.IlOO absolute molecular weight of that composition. 

Desaibe the method. of meuurement or the bam for your estimates: GPC 0 OtherD :(Specify) 

I) lowat number average molecu1arweight: 

i1) maximum weljJht " below 500 molecular weight: 

Jill maximum weljJht " below 1000 molecul.ar-welght:

o Mark 00 this box 1.f you attach a continuation sheet. 

b. You must make ~te confidentiality claims for monomer or other reactant identity, composition information, and residual information. 

Mark (X) the 'Confidential" box next to any item you claim lIS confidential.

AItfP ­ Provide the sped..fic chemical name and CAS Registry Number (if a number exists) of each monomer or other reactant used In the 

manufacture of the polymer. 

(2) - Mark (X) this column if entry in column (1) is confidential. 

(3) - Indicate the typical weight percent of each monomer or other reactant in the polymer. 

(4) - Mark (X) the identity column ifyou want. monomer or other reactant used at two weight percent or Ie•• to be listed as part of the 

polymer clesaiption on the TSCA Chemical Substance Inventory. 

(5) - Mark (X) this column 1.f entries in columns (3) and (4) are confidential. 

(6) - Indicate the maximum weight pen:ent of each monomer or other reactant that may be present as a residual in the polymer lIS 

manufactured. for commerda1 purposes. 

(7) - Mark (X) this column if entry in column (6) is confidential. 

Monomer or other reactant and CAS Registry Number Confi- Typical Identity Conti- Maximum 

dential composition Marie (X) dential residual I~ :. (1) (2) (3) (4) (5) (6) (I 

AlIA % % 

% % 

% % 

% % 

% % 

'% 'It. 

'1'0 % 

o Mark (X) this box if you attach a continuation sheet. 

c. Please identify which method you used. to develop or obtain thespedfied chem.lcalldentity information reported.. in this notice. (check one). D Method 1 (CAS Inventory E~t Service - a copy of the identlflcation report D Method 2 (other source) 

obtained. from CA Inventory Expert Service must be submitted as 

an attachment to this notice) 

d. The currently correct OIemica1 Abstracts (CA) name for the polymer that.ls consistent with TSCA Inventory listings for similar polymers. 

/V/R 

e. Provide a correct representative or partial chemical structure diagram, as complete as can be known, If one can be reasonably ascertained. 

IV/A 

o Mark (X) this box if you attach a continuation sheet. 

FORM EPA 7711>-25 (Rev. 5-95) PageS 
Part I -- GENERAL INFORMATION - Continued 

Section C - PRODUCTION, IMPORT, AND USE INFORMATION: 

Mark 00 the "Confidential" box next to any item you claim as confidential. 

1. Production volume ­ Estimate the maximum production volume during the first 12 months of production. Also estimate the 

maximum production volume for any consecutive 12-month period during the first three years of production. Estimates should b eon 

100% new chemical substance basis. For aLow Volume Exemption appliaUion, if you choose to have your nona rtroiewed at a lower produc ion 

volume than 10,000 kg/yr, specify the 'VOlume and mark (x) in the binding box. If granted, you art! bound to this volume.. 

Maximum first 12-month production (kg/yr) Maximum 12-month production (kg/yr) Conti­ 'Bbulbl~ 

(100% new chemical substance basis) (100% new chemical substance basis) 

dential ~(~ 

X 

l. Use Iniormation - You must make separate confidentiality claims for the description of the category of use, the percent of production volume 

devoted to each category, the formulation of the new substance, and other use information. Mark (X) the "Contidential~ Box next to any item you 

claim as confidential. a. (1) ­ Describe each Intended category 01 we of the new chemical substance by function and application. 

(2) - Mark 00 thJs column if entry In column (I) is confidential business information (CBI). 

(3) - Indicate your willingness to have the Information provided in column (1) binding. 

(4) ­ Estimate the percent of total production for the first three years devoted to each category of use. (5) ­ Mark 00 thJs column If entry In column (4) is confidential business Information (CBI). 

(6) ­ Estimate the percent of the new substance as formulated in mixtures, suspensions, emulsions, solutions, or gels as manufactured for commercial purposes at sites under your control associated with each category of use. 

(7) - Mark 00 this column Ifentry In column (6) is confidenlial business information (CBl). 

(8) ­ Indicate 'lr. of product volume expected for the listed "use" sectors. Mark more than one box if appropriate. Mark 

00 to indicate your willingness to have the use type provided in (8) binding. 

(9) - Mark 00 th. column if entry{ies} in column (8) is (are) confidential business Information (CBI). 

Category of use (1) CBI BI.d1a1l Produc- CBI %in CB1 'lr. of substance expected per use :Dr 

(by function and application i.e. a dispersive dye for Opllo. tion % Form­ (8) MMk(x) ulation finishing polyester fibers) l:sIte­ Il.:Oll- Indus- Com­ ~inding (2) (3) (4) (5) (6) (7) limited sumer trial merclal Option (9) 

Resin for electronic laminates % X % X X 

Adhesive Resin % X % X X 

Encapsulants Resin % X % X X 

Composites Resin % X % X X 

% % 

% % 

% % 

"If you have identified a "consumer" use, please provide on a continuation sheet a detailed description of the use(s) of this chemical 

substance in consumer products. In addition include estimates of the concentration of the new chemical substance as expected in 

consumer products and descnbe the chemical reactions by which this substance loses its identity in the consumer product. 

o Mark 00 thIs box if you attach a continuation sheet. 

b. Generic If you claim category of use description In subsection 2a as confidential, enter a generic desaiption of that 

use category. the Inatructions Manual lor examples of generic use descriptions. 

description 

AI/A. 

o Mark 00 this box If you attach a continuation sheet. 

3. Hazard Information - Include in the notice a copy of reasonable facsimile of any hazard warning statement, label, material safety data sheet, Billdl '8 

or other information which will be hrOvided to any person who is reasonably likely to be exposed to this substance regarding protective I~(xl . equipment or practices for the safe andling, transport, use, or disposal of the new substance. Ust in part III hazard information you include. 

Mark 00 this box if vau attach hazard information. /v1.'~<' P4-4-t!S /1/-/ R' 

FORM EPA 7710-25 (Rev.S-95) Page 7 

6 

Complete section A fOIl' each type of manufacture, procesaing. 01' use operation involving the new chemical8Ubatan~ Itindustrial sites you 

Importel'l do not have to complete this section for operations oul8ide the U.S.; however, you may stin have reporting requiremenl8 if there are further ind.ustrial proceuing or use operations after import. You must describe these operations. See instructions manuaL 

~ 

Part II -- HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE 

Section A - INDUSTRIAL SITES CONTROLLED BY THE SUBMI'I"I EK 

of the site at which the will occur. 

Name 

Ie: IMPORT ONLY 

City, County, State, ZIP Code 

If the same operation will occur at more than one site, enter the number of sites. IdentIfy the 


additional sites on /I continuation sheet, and If any 01 the sites have signifiamtly dIfferent 


production rates or operations, include aU the information requested in this section for those 


attach a continuation sheet. 

b. Type­ Nt A 


Mark (X) o Manufacturing O Processing o Use 


1. Batch 

2. Continuous 

Hours/day 

d. Process description Mark (Xl to ind.icate your willingnesa to bave your procell description binding. 

(1) 	Diagram the major unit operation steps and chemical conversions. include interim storage and transport containers (specify-e.g. 5 gallon pails, 

gallon drum, rail car, tank truck, etc.). 

(2) Provide the identity, the approximate weight (by kg/day or kg/batch on an 100% new chemical substance basis), and entry point of all 

materials and leedstocb (including reactants, solvents, and catalysts, etc.), and of aU products. recycle streams, and wastes. Include cleaning 

chemicals (note frequency if not used daily or per batch.). 

(3) Identify by number the points of release, including small or intermittant releases, to the environment of the new chemical substance. 

N / A 

o Mark ()() this box if you attach a continuation sheet. 

FORM EPA '7710-25 (Rev. 5-95) 	 PageS 

1 
Part II - HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE - Continued 

• Section A - INDUSTRIAL SITES CONTROLLED BY THE SUBMII I J:iK ­ Continued 

2. Occupational ElCpOSW'e ­ You must make ~ate confidentiality claims for the deea1ption of worker activity, physical form ofthe new chemical 

substaru:e, number of workers exposed, and uratton of adivity. Mark 00 the "Confidential" box next to any item you claim as confidential. 

(1) - Desaibe the activities (e.g. bag dumping, tote filling, Wlloading drums, sampling, cleaning, etc.) in which workers may be exposed to the 

substance. 

(2) - Mark (X) this column if entry in column (1) is confidential business information (CBI). 

(3) - Desaibe any proliective equipment and engineering controls used to protect workers. 

Not Applicable 

(4) and (6) -lndic:ate you willingness to have the information provided in column (3) or (5) binding. '. 

(5) -Indicate the physlcal formes) of the new chemical substance (e.g. solid: crystal, granule, powder, or dust) and % new chemical substance (if pm: of a mixture) at the time of exposure. 

(7) - Mark 00 this column if entry in column (5) is confidential business information (CBl). 

(8) ­ Estimate the maximum number of workers involved in each activity for all sites combined. 

(9) - Mark 00 this column ifentry in column (8) is confidential business information (CBI). 

(10) and (11) - Estimate the maximum duration of the activity for any worker in hours per day and days b. year. 

(12) - Mark 00 this column if entries In columns (10) and (11) are confidential bu9iness informatton (CB ). 

Worker activity CBI Protectlv. Eqal..-IJ BIIldIIl, rnyalclu rormt~1 "lIldla, CBI tol CBI Maximum duration :BI 

(e.g. bag dumping, filling drums) EIlgineed"8 Contra .. O.ptIOli (e.g.soUd:powder) Pplloa WCII'ken 

MArk",) and'Jl, new ~(x) Exposed HIs/day Days/yr 

en (2) (3) (4) 1Ub8*:~ce (t.) I'TI (8) (9) (10) (11\ 12) 

N / A 

D Mark (X) this box if you attach a oontinuation sheet. 

3. Environmental Releue and DIapoul- You mustmake separate confidentiality claims for the release number and the amOlmt of the new 

substance released and other release and disposal information. Mark 00 the "Confidential" box next to each itemlc0Uclaim as confidential. 

(1) - Enter the number of each release point identified in the process description, part II. section A, subsection 1 (3). . 

a> - Fstimate the amount of the new substance released (a) dtrectlJ:nthe environment or (b) into control technology (in kg/day or kg/batch). 

(3) - Mark 00 this column if entries in columns (1) and (2) are co tlal business information (CBI). 

(4) - Identify the media of release Le. stack air, fugitive air (optional_instruction Manual), surface water, on·site or off·site land or ineineratim , 

PO'IW, or other (please specify) to which the new sub!ltan~ will be released from that release point. 

(5) - a. Describe control technology, if any, ,and oontrol efficiency that will be used to limit the release of the new substance to the environment. 

For releases disposed of on land, characterize the disposal method and state whether it is approved for disposal of RCRA hazardous waste. 

On a continuation sheet, for each site describe any additional disposal methods that will be used and whether the waste is subject to 

secondary or tertiary olHlite treatment. b. FBtimate the amount released to the environment after control technology (in kg/day). 

(6) - Mark 00 this column ifentries in columns (4) and (5) are confidential business Information (CHI). 

(7) - Identify the destlnatlon(s) of releases to water. Pleage supply NPDFS (National Pollutant Discharge Elimination Syslmn) numbers for dire.: 

disc::hargers or NPDES numbers of the PO'IW (Publicly Owned Treatment Works). Mark 00 if the POTW name or NPDFS # Is confidential 

business information (CBI). 

Release Amolmt of new substance CBI IMedia of Control technology and efficiency (you may wish to optionally aUach efficiency data) f:BI Number relea ;ed release 

•.g. atock all' I DIAd"'• (1) (2a) (2b) (3) (4) (Sa) : Mort (Jr) (Sb) 6) 

I 

N / A I 

r 

I 

I 

I 

I 

I 

I 

I 

I 

I 

(7) Mark (X) the o POIW provide name(s) below: CBI o Navigable o Other - Specify provide NPDES j Bl 

destinatlon(s) of N/A - waterway 

releases to water. 

o Mark 00 this box if you attach a continuation sheet. 

FORM EPA 7710-25 (Rev. 5-95) Page 9 

B I 
Part II - HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE - Continued 

~ Section B - INDUSTRIAL SITES CONTROLLED BY O1HERS 

Complete section B for typical processing or use operationsinvolving the new chemical substance at sites you do not amtrol.Importers do not haVl to 

complete tI.Us section for operations outside the U.s.; however, you must report any processing or use activities after import See the Instructions 

Manual Compltt4! 4 sep.,.u section B far ,1Idr type of processing, or Itse opmtion intlOlving 1M new chemiaU subsf4na. Ifthe same operation is perforn ed 

at more than one site describe the typical operation common to these sllI!s. ldenlify additional sites on a continuation sheet. 

1. Operatioa Deaaiptioa • To claim information in this section as confidential, circle or bracket the speclfic Information that you claim as confidential 

(1) - Diajp'am the major unif operation steps and chemical conversions, including interim storage and transport containers (specify- e.g. 5 gallon pi Ius, 

55gallon drums, rail cars, tank trucks, etc). On the diagram, Identify by letter and briefly describe each worker activity. (2) .: Provide the identity, 

the approximate wel.gbt (by kg/day or kg/Mich, on an 100% new chemical substance basis), and entry point ofall feedstocks (including reactants 

solvents and catalysts, etc) and of all products, recycle strelUll!l, and wasll!s. Include cleaning chemicals (note frequency if not used daily or per 

batch). (3) ­ Identify by number the points of release, including small or intermittent releases, to the environment of the new chemicalsubstanc:e. 

'" p.._-th•• " ..... (~="'" to ....1ily "'Io<aO~ of......'5~. =_000.ho"" [ 1 c D~fiDE 

35 to 75 % PMN resin 'OEste; t N q

+ 

25 to 65 % solvent + other resins 

t 

Copper-clad laminate or printed wiring boasd ,.. Curing operation 

[!] 0 CD 1 

Finished article 

o Mark (X) this box if you attach a continuation sheet. 

2. Worker Expo.urelEDvironmentallleleaae 

(1) - From the diagram above, provide the letter for each worker activity. Complete 2-8 for each worker activity described. 

(2) ­ Estimate the number of workers exposed for all sill!s combined. 

(4) - Estimate the typical duration of exposure per worker In (a> MUll! per day and (b) days per year. 

(6) - Describe physical form of exposure and % new chemical substance (If In mixture), and any protective equipment and engineering controls us 

to protect workers. 

(7) ­ Estimate the percent of the new substance uformulated when packaged or used as a final product. 

(9) - From the process diagram above, enter the number of eadl release point. Complete 9-13 for each release point Identified. 

(10) Estimate the amount of the new substance released (a) directly to the environment or (b) Into control technology to the environment 

(in kg/day or kg/batdl). 

(12) - Describe media ofreleue i.e. stack air, fugitive air (optional-see Instructions Manual), surface water, on-slte or olf-site land or Incineration. 

POlW, or other (speclly) and control technology, if any, that wlll be used to lImlt the releaee of the new substance to the environment. 

(14) -- Identify byproducts which may result hom the operation. 

(3), (5), (8), (11), (13) and (15) - Mark (X) this column if any of the proceeding entries are confidential business information (CBl). 

Letter #of CBI Duration CBI Protective Equip. / I%m CBl Release Amount of CBI Media of Release :BI 

of Workers of Engineering Controls/ Form- Number New &:Control 

Ac:t- Exposed Exposure Physical Form and 'l{. ulation Substance Technology ivity new substance Released 

I I 

(1) (2) (3) (4a) I (4b) (5) (6) (7) (8) (9) (lOa) I (lOb) (l1 (12) 13) 

I I 

A .., 8 I 30 gloves,goggles X 1 0 I lkg L. Lined landfill I apron.exhaust I day I 

I gloves,goggle N/A N/A I N/A N/A B 2 8 I 30 exhaus X I 

I apron, I 

I ~ollect residu() I A 2 8 I 30 ~olvent X 1 0 I 0 incineration 

I system I 

I ~ontrol Drums I 

B 2 8 I 30 jX 1 0 I 0 incineration 

I ~fter emptying I i 

(14) - Byproducts: None 5) 

[2S] Mark (X) thls box if you attach a continuation sheet. 

FORM EPA mO-25 (Rev. 5-95) Page 10 

L 

Part II - HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE ­ Continued 

~ Section B - INDUSTlUAL SITES CONTROLLED BY O'IHERS 

Complete section B for typical processing or use operations involving the new chemical substana! at !lites you do not oontroLImporters do not havE to 

complete this section for operations out9ide the U.s.; however, you must report any processing or use activities after import. See the Instructions 

Manual Conrpleh! II'",."" sectiDn II far etU:1I type of",.acming, or use opmtiDn inrol'Ding Urt MID clrnrriall subst.nce. Hthe same operation is perfom ed 

at more than one site describe the typical operation common to these sites. Identily additional sites on a continuation sheet. 

1. Operation Dacription • To claim information in this section as oonlidential, circle or bracket the sped.fic Information that you claim as ooniidenlial 

(1) - Diagnun the major unit operation steps and chemical oonversions, Including interim storage and transport containers (specify- e.g. 5 gallon p ins, 

55gaIIon drums, raIl cars, tank trucks, etc). On the diagram, Identily by letter and briefly desaibe each worker activity. (2) -~ Provide the Identity, 

the approximate weight (by kglday or kg/batch, on an 100% new chemical substance basis), and entry point of all feedstocks (Including reactants 

solvents and catalysts, etc) and of all products, recycle streams, and wastes. Include cleaning chemicals (note frequency If not used daily or per 

batch). (3) -identify by number the poinls of release, including small orIntermittent releases, to the environment of the new chemical substance. 

(4) ~--~.:~"::::--OO"!don<fy _do .. " th......M. -'"".....), b • .JCC'6~~rntN WI 1heat 

o 

o 

Hot melt fPlication to adhesive or enc.psulant sUwte 

Curing operation 

D Mark (X) this box if you attach a continuation sheet. 

2. Worker ExpolUn.IEIlvirollmental Rele•• 

(1) ­ From the diagram above, provide the letter for each worker activity. Complete 2-8 for each worker activity descr:\bed. 

(2) - Fstimate the number of worken exposed for an sites combined. 

(4) ­ Estimate the typical duration of exposure per worker in (a) hours per day and (b) days per year. 

(6) - Desaibe phy!lical form of exposure and % new chemical substance (if in mixture), and any protective equipment and engineering oontrols us~ 

to protect workers. 

(7) - Fstimate the percent of the new substance as formulated when packaged or used as a final product. 

(9) - From the process diagram above, enter the number of each release point. Complete 9-13 for: each release point Identified. 

(10) - Estimate the aDtOW\t of the new substance released (a) directly to the environment or: (b) into control technology to the environment 

(In kg/day or kg/batch). 

(12) Desaibe media ofrelease I.e. stack air, fugitive air (optional-see Instructions Manual), surface water, on-site or off-eite land or incineration, 

POIW, or other (sped.fy) and oontrol technology, if any, that will be used to limit the release of the new substance to the environment. 

(14) -Identify byproducts which may result &om the operation. 

(3), (5), (8), (11), (13) and (15) - Mark 00 thJs column If any of the prooeedlng entries are conIidenlial business information (CBI). 

Letter # of CDI Duration CDI Protective Equip. Ii'" in CBI Release Amount of CBI Media of Release 

of Workers of EngineeringControlsl Form- Number New &:Contro1 

Act- Exposed Expoeure Pby9ical Form and % ulation Substance Technology 

ivity new substance Released 

(1) (2) (3) (4a) : (4:b) (5) (6) (7) (8) (9) (lOa): (lOb) (11 (12) 

I I 

8 I 30 gloves. goggles X 1 0 I 1kg 

I apron, exhaust ~dav 

Landfill or A 2 incineration 

B 2 8 I gloves, goggles I 

I I )0 apron, ex h aust X N/A N/A IN/A I N/A 

. I collect residu 1 100 1 0 I 

A 2 8 I 30 0 incineration I 

I solvent system I 

I control drums I 

I 100 1 0 I 0 incineration 

A 2 8 I 30 after emptying I 

(14) - Byproducls: 

None 

f12(j Mark (X) this box If you attach a oontinuation sheet. 

FORM EPA 77l0-2S (Rev. 5-95) Page10 a 

IIJ 

::81 

13) 

5) 

~L 
Part II - HUMAN EXPOSURE AND ENVIRONMENTAL RELEASE - Continued 

• Section B - INDUSTRIAL SITES CONrROLLED BY OTHERS 

Complete section B for typical processing or use operations involving the new chemical substance at sites you do not amtrol.Importers do not haVE to 

complete this sectl.on for operations outside the US.; however, you must report any processLng or use activities after imporl See the Instructions 

Manual. Compltk a sq",.,. sectiml Bfur each type of processillg, or Ilse opmdiml illoolt1illg the lInD chemic4l SllbsUIIICt. U the same operation Is perforn ed 

at more than one site describe the typical operation common to these sites. Identify additional sites on a COI\tinuation sheel 

1. Operatioo Description - To claim information in this section as confidential, circle or bracket the specific information that you claim as oonfidential 

(1) ­ Diagram the major unit operation steps and chemical oonversions, including interim storage and transport containers (specify- e.g. 5 gallon PI ils, 

55gallon drums, rail cars, tank trucks, etc). On the diagram, Identify by letter and briefly describe each worker activity. (2) ­ Provide the identity, 

the approximate weight (by kg/day or kg/batch, on an lOO'JI. new chemical substance basis), and entry point of all feedstocks (including reactants 

solvents and catalysts, etc) and of all products, recycle streams, and wastes. Include cleaning chemicals (note frequency if not used daily or per 

batch). (3) -Identify by number the points of release, including!lIl\all or inlennittent releases, to the environment of the new chemical substance. 

'" ......a ....."'hit~' ~be, 10 """'Illy'" _.~oi"_""'~, ~"'~.oo....." oIaL ro~trtj~T 

A 

35 % Formulatinn containing the PMN chemical 

+ 

65 % Carbon or glass fiber 

Prepreg L operation > Molding and curing operation 

~ 0 0 

Finished 

1

article 

D Mark 00 this box if you attach a continuation sheet. 

2. Worker Expo.urelEnvircmmenlal Relea. 

(1) ­ From the diagram above, provide the letter for each worker activity. Complete 2-8 for each worker activity described. 

(2) ­ Estimate the number of workers exposed for all sites combined. 

(4) ­ Estimate the typical duration of exposure per worker in (a) hours per day and (b) days per year. 

(6) ­ Describe physical form of exposure and 'JI. new chemical substance (If In mixture), and any protective equipment and engineering controls us i!d

to protect workers. 

(7) ­ Estimate the percent of the new substance as formu1ated when packaged or used as a final product. 

(9) ­ From the process diagram above, enter the number of each release point. Complete 9-13 for each release point identified. 

(10) ­ Estimate the amount of the new substance released (a) directly to the environment or (b) into COI\trol technology to the environment 

(in kg/day or kg/batch). 

(12) ­ Describe media of release i.e. stack air, fugitive air (optional-see Instructions Manual), surface water, on-site or off-site land or incineration, 

POIW, or other (specify) and control technology, if any, that will be used to limit the release of the new substance to the environment. 

(14) ­ Identify byproducts which may result from the operation. 

(3), (5), (8), (11), (13) and (15) - Mark 00 this column if any of the proceeding enbies are confidential business information (CBO. 

Letter # of CBI Duration CBI Protective Equlp. / "'in CBI Release Amount of CBI Media of Release CDI 

of Workers of Engineering Controls/ Form- Number New &:Control 

Act- Exposed Exposure Physical Form arid 'JI. u1ation Substance Technology ivity new substance Released 

I 

(lOa) : (lOb) (1) (2) (3) (4a) I (4b) (5) (6) (7) (8) (9) (11 (12) 13) 

I 

gloves, goggles I 

I lkg .X 1 0 I lined landfill A 2 8 I 30 apron, exhaust I/day I • 

2 8 

I 30 gloves,goggles B I X N/A :N/A N/A

apron, exhaust I I 

A 2 8 I 30 collect residu 1 1 0 I 

I solvent .X I 0 incineration 

I system I 

I I 

A 2 8 I 30 control drums 1 0 I 

I after emptyingj X I 0 incineration 

(14) - Byproducts: None ~5) 

D Mark (X) this box if you attach a continuation sheet. 

FORM EPA 771()'25 (Rev. 5-95) Page 10 b 

II 
OPTIONAL POLLUTION PREVENTION INFORMATION 

To claim information in this section as confidential circle or bracket the specific information that you claim as confidential. 

In this section you may provide information not reported elsewhere in this form regarding your 

efforts to reduce or minimize potential risks associated with activities surrounding 

manufacturing, processing, use and disposal of the PMN substance. Please include new 

information pertinent to pollution prevention, including source reduction, recycling. activities 

and safer processes or products available due to the new chemical substance. Source reduction 

includes the reduction in the amount or toxicity of chemical wastes by technological 

modification, process and procedure modification, product reformulation, raw materials 

substitution, and/or inventory control. Recycling refers to the reclamation of useful chemical 

components from wastes that would otherwise be treated or released as air emissions or water 

discharges, or land disposal. Descriptions of pollution prevention, source reduction and 

recycling should emphasize potential risk reduction subsequent to compliance with existing 

regulatory requirements and can be either quantitative or qualitative. The EPA is interested in 

this information to assess overall net reductions in toxicity or environmental releases and 

exposures, not the shifting of risks to other environmental media or non-environmental areas 

(e.g., occupational or consumer exposure). In addition, information on the relative cost or 

performance characteristics of the PMN substance to potential alternatives may be provided. 

All information provided in this section will be taken into consideration during the review 

of this substance. See the revised Instructions Manual that includes a Pollution Prevention 

manual for guidance and examples. 

Describe the expected net benefits, such as (1) an overall reduction in risk to human health or the environment; (2) a reduction in 

the volume manufactured; (3) a reduction in the generation of waste materials through recycling. source reduction or other 

means; (4) a reduction in potential toxicity or human exposure and/or environmental release; (5) an increase in product 

performance, a decrease in the cost of production and/or improved operation efficiency of the new chemical substance in 

comparison to existing chemical substances used in similar applications; or (6) the extent to which the new chemical substance 

may be a substitute for an existing substance that poses a greater overall risk to human health or the environment. 

Benefits are as follows: 

The PMN material is more resistant to heat and moisture than the current 

epoxy systems being used in the target applications. This yielas a I 

longer lifetime in harsh environments, which reduces waste. It provides i 

less outgassing than current systems, which also reduCes waste. 

In addition, the higher glass transition teuperature of the PMN material allows 

higher solder temperatures with lower amounts of lead in the solder used. 

o Mark (X) this box if you attach a continuation sheet. 

FORM EPA 7710-25 (Rev.5-95l Page 11 

It I 
I 

Part III .8 LIST OF ATTACHMENTS 

Attach continuation sheets for sectI.orul of the form and test data and other data (including physical/chemical properties and 

structure/activity information), and optional information after this page. Qearly identify the attachment and the section of the form to 

which it relates, if appropriate. Number consecutively the pages of the attachments. In the column below, enter the inclusive page 

numbers of each attachment. 

Mark (X) the 'Confidential- box next to any attachment name you claim as confidential. Read the Instruction. Manual for tdance on how to claim any information in an attachment as confidential. You must include with the sanitized copy of the notice 

arm a sanitized version of any attachment in which you claim information as confidential. 

Attachment name 

Material Safety Data Sheet (MSDS) 


Physical and Chemical Properties Worksheet 


Infrared spectrum of PMN substance 

HPLC analysis of the PMN substance 

CAS Inventory Expert Se~vice Report CAS INdex name 

". 

' 

Attachment Cot ft· 

page number(s) dentilll 

14-18 


13 


19 


20 


21 


o Mark 00 this box if you attach a continuation sheet. Enter the attachment name and number. 

FORM EPA mO-25 (Rev. 5-95) Page 12 
I 

PHYSICAL AND CHEMICAL PROPERTIES WORKSHEET 

To assist EPA's review of phr.sical and chemical properties data, please complete the following worksheet for data you provide 

and include it in the notice. dentify the property measured, the page of the notice on which the property appears, the value 

01 the property, the units in which the property is meuured (as necessary), and whether or not the properutis claimed as confidential The physical state of the neat substance should be provided. These measured propertiea sho be for the neat (100% 

pure) chemical substance. Properties that are measured for mixtures or formulations should be so noted (~ PMN substance in _).You 

are not required to submit this wor1csheet; however, EPA strongly recommends that you do so, as it will simplify review and ensure 

that confidential Information is properly protected. You should submit this worksheet as a supplement to your submission of test 

data. This worksheet Is not a substitute for submission of test data. 

Property Value MaluIlHl Conti Mark (X) if Page or d ltill provided number

(e) J::k(i() (a) (b) (Morl!) (d) 

X 16 _ X (5) __ 0) __ W M Physical state of neat substance 

Vapor pressure "C X 16 low E @ Temperature Torr 

X 16 1.15 g/cm3 M

Solubility 

Density /reIative density 

"C X 16 insoluble M @ Temperature 


Solvent 
 gil 

22 °C X 16 insoluble "C M Solubility in waler @Temperature 

Melting temperalure X 16 30 "C M

Boiling/subllmation e torr pressure temperalure 


19 & 


Spectra (infrared, NMR) X 11 
 M X

Dissociation constant 


Particle size distribution 


Octanol/water partition ooeffldent 

Henry's Law constant 

Volltallzation from waler 

Volitalization from soil 

pH @ concentration 

Flammability 

Explodabillty 

Adsorption/c:oeffident 

Other - Spedfy 

; 

Page 1 

I 

'va()ti
 Vantico Inc. 

North America 

Polymer Specialties 

281 Fields Lane 

Brewster, NY 10509 

8am to 4:30pm Phone: (914) 785-3000 

24-Hour HealthlEnvlronmental Emergency Phone: 1·888-354-3323 

MSDS No: 12869 Effective Date: 118/02 Material Safety Data Sheet 

1. PRODUCT IDENTIFICATION 

Trade Name: RD 2001-091 

Chemical Family: Benzoxazine 

Health 2 

Flammability 1 

Reactivity 0 

Protective Equipment X 

HMISRATING 

2. COMPOSITION I INFORMATION ON INGREDIENTS 


OSHA Hazardous Ingredients: ACGIH TWA and OSHA PEL for aniline have a skin notation. 


0 CAS No. CHEMICAL IDENTITY EXPOSURE LIMITS CARCINOGEN 

S STATUS 

H ACGIH~ OSHA MFR. IARC NTP OSHA 

A TWA I ST PEL I STEL 

Confidential Benzoxazine NE I NE NE I NE NE NR NR NR 

NE =Not Established NR Not Reviewed * =OSHA Hazardous Ingredient 

3. HAZARDS IDENTIFICATION 

Emergency Overview: Caution! The toxicological properties of this compound have not been fully investigated. May be toxic if 

swallowed, inhaled, or absorbed through the skin. May cause liver, kidney and nervous system damage. 

Primary Route(s) of Entry: Dermal, inhalation. 

4. FIRST AID MEASURES 

Ingestion: Ifswallowed, immediately give at least 3-4 glasses of water, but do not induce vomiting. If vomiting occurs, give fluids 

again. Do not give anything by mouth to an unconscious or convulsing person. Get immediate medical attention. Have physician 

determine whether vomiting or stomach evacuation is necessary. 

Printed: 12113/2002 Page 1 of 5 
RD 2001·091 Vantico Inc. 

Effective Date: 1/8/02 Polymer Specialties 

Skin: For skin contact, wash affected areas with plenty of water, and soap, if available. for several minutes. Get medical attention if 

irritation occurs. 

Inhalation: Ifinhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing 

becomes difficult. 

Eyes: For eye contact, flush eyes with plenty of water for several minutes. Get medical attention if irritation occurs. 

Overexposure Effects: Overexposure to this material can cause skin and eye irritation and allergic skin reactions. Overexposure to 

aniline can result in methemoglobinemia, a blood disorder characterized by reduced ability of the blood to carry oxygen. Symptoms 

of overexposure include headache. nausea. weakness, irritability, drowsiness, bluish discoloration and unconsciousness. Chronic 

overexposure to aniline can result in liver and kidney damage. 

Medical Conditions Aggravated by Exposure: Allergy, eczema or skin conditions. 

Additional Information: Wash contaminated clothing prior to reuse. 

5. FIRE FIGHTING MEASURES 

Flash Point: > 200°F (> 93°C) 


Flash Point Method Used: Closed Cup (similar product) 


Fire Fighting Extinguishing Media: Carbon dioxide. foam. dry chemical. water spray. 

Fire Fighting Equipment: Use self-contained breathing apparatus. 

Fire and Explosion Hazards: Decomposition and combustion products may be toxic. At high temperatures aniline may produce 

poisonous vapors and form explosive mixtures with air. 

6. ACCIDENTAL RELEASE MEASURES 

Accidental Release Measures: Sweep or vacuum and place into closable container for disposal. Wear protective equipment 

specified below. 

7. HANDLING AND STORAGE 

Precautions: Avoid contact with eyes. skin and clothing. Avoid breathing dust and vapors of heated material. Use with adequate 

ventilation. Remove contaminated non-impervious clothing, wash before reuse. Individuals should wash thoroughly after handling. 

Avoid dusty conditions. Dust suspended in air may be a fire and explosion hazard. For industrial use only. 

Storage Information: Store in cool. dry are in sealed containers. Keep containers closed to prevent moisture absorption and 

contamination. 

8. EXPOSURE CONTROLS / PERSONAL PROTECTION 


Personal Protective Equipment: Wear coveralls. 


Skin Protection: Wear impervious gloves. 


Printed: 12113/2002 Page 2 of 5 
RD 2001-091 Vantico Inc. 

Effective Date: 1/8/02 Polymer Specialties 

Respiratory Protection: Use NIOSH approved dust respirator, if needed. Use respiratory equipment approved by NIOSH for 


protection against aniline mists and vapors, if necessary. 


Eye Protection: Wear chemical goggles if eye contact is possible. 


Engineering Controls: Work in well ventilated areas. 


9. PHYSICAL AND CHEMICAL PROPERTIES 

Color: Yellow 

Odor: No Discemable Odor 

Physical State: Solid 

Solnbility in Water: Insoluble 

Vapor Pressure: Not determined, but low at ambient temperatures 

Specific Gravity: 1.15 

Melting Point: 30°C (86 OF) 

pH: Not Determined 

Percent Volatile: Negligible. 

10. STABILITY AND REACTIVITY 


Stability: Stable. 


Incompatibility: Strong oxidizing agents. 


Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. aldehydes, nitrogen oxides. 


Hazardous Polymerization: Will not occur. 


n. TOXICOLOGICAL INFORMATION 


Acute Oral Effects (LD50): (Rat): 250 mg/kg - Toxic by ingestion (aniline). 


Acute Dermal Toxicity (LD50): (Rabbit): 820 mg/kg - Toxic by skin contact (aniline). 


Inhalation Toxicity (LC50): (Mouse): 175 ppm/7 hr. (aniline). 


Sensitization: Potential sensitizer. 


Carcinogenicity: IARC has classified aniline in Group 3, "not classifiable as to its carcinogenicity in humans." 


Skin Irritation: Not evaluated. 


Eye Irritation: Not evaluated. 


Chronic Exposure Effects: Chronic overexposure to aniline can result in liver and kidney damage. NIOSH has concluded that 


overexposure to o-toluidine and aniline was associated with bladder cancers among workers producing rubber antioxidants. In a 

National Toxicology Program (NTP) two-year feeding study, aniline hydrochloride was carcinogenic to rats. There are no other 

known chronic effects associated with this material. 

Printed: 12/13/2002 Page 3 of 5

'Ie 16 
RD 2001-091 Vantico Inc. 

Effective Date: 118/02 Polymer Specialties 

12. ECOLOGICAL INFORMATION 


Additional Information: No ecological information available. 


13. DISPOSAL CONSIDERATIONS 


Waste Disposal Method: Dispose in accordance with federal, state and local regulations. 


14. TRANSPORT INFORMATION 

Department of Transportation: Not regulated. 

15. REGULATORY INFORMATION 

US Federal Regulations: 

Occupational Safety and Health Act (OSHA): This Material Safety Data Sheet (MSDS) has been prepared in compliance with 

the federal OSHA Hazard Communication Standard 29 CFR 1910.1200. This product is not considered to be a hazardous chemical 

under that standard. 

Resource Conservation and Recovery Act (RCRA): Not a hazardous waste under RCRA (40 CPR 261). 

SARA Title III: Section 304 . CERCLA: Reportable Quantity (RQ) for aniline is 5,000 lb. 

SARA Title III: Section 313 Toxic Chemical List (TCL): This product is (or contains) a toxic chemical for routine annual 'Toxic 

Chemical Release Reporting' under Sec. 313 (40 CPR 372). This information must be included in all MSDS's that are copied and 

distributed for this material. 

CAS Number: 62-53-3 

Chemical Name: Aniline 

Concentration: 0.1% Maximum 

TSCA Section 8(b) - Inventory Status: This chemical substance is not included on the TSCA Inventory and is transmitted to you 

solely for research and development purposes and may not be used, processed or distributed for a commercial purpose. In 

accordance with 40 CPR 720.36 of the Premanufacture Notification rule, this substance may only be used by, or directly under the 

supervision of, technically qualified indi viduals. 

State Regulations: 

California Proposition 65: Warning! This product contains a chemical known to the state of California to cause cancer. 

CAS No: 62-53-3 

Chemical Name: Aniline 

16. OTHER INFORMA TION 

MSDSNo: 12869 

Printed: 12/13/2002 Page 4 of 5 
RD 2001·091 Vantico Inc. 

Effective Date: 118102 Polymer Specialties 

Prepared By: M. Slattery 

Approved By: James E. Mumby 

Title: Director, Product Safety 

Other Information: For further information, contact Product Safety personnel at (914) 785-3000. 

Disclaimer: The following supercedes Buyer's documents. SELLER MAKES NO REPRESENTATION OR WARRANTY, 

EXPRESS OR IMPLIED, INCLUDING OF MERCHANT ABILITY OR FITNESS FOR A PARTICULAR PURPOSE. No 

statements herein are to be construed as inducements to infringe any relevant patent. Under no circumstances shall Seller be liable 

for incidental, consequential or indirect damages for alleged negligence, breach of warranty. strict liability, tort or contract arising in 

connection with the product(s). Buyer's sole remedy and Seller's sole liability for any claims shall be Buyer's purchase price. Data 

and results are based on controlled or lab work and must be confirmed by Buyer by testing for its intended conditions of use. The 

product(s) has not been tested for, and is therefore not recommended for, uses for which prolonged contact with mucous membranes, 

abraded skin. or blood is intended; or for uses for which implantation within the human body is intended. 

Printed: 12113/2002 Page 5 of 5 
r 


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Individual Sample Report 

Reported by User: System Roject Name: Y2002 

SAMPLE INFORMATION 

Sarrple Name: [ J Acqured By: System

SarrpJe Type: Date Acquired: 6/271021:01 :15 FM 

Vial: 55 BisOxACN

Injection #: 1 CON FlO ENTI AL~t~ =:Sds:~: 6/27/023:36:59 FM 

Sarrple Weight 102.00000 A-ocessing ~thod: aniline 

Run lime: 40.0 Mnutes Channel Name: 248701annel 1 

Sarrple Set Name: 20627 A-oc. Chnl. Deser.: 254nm 

CONFIDENTIAL 

Report l\fethod: Default Individual Report A-inted 3:37:50 Page: 1 of 1 

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