Testing for Hydrochloric Acid Gas Emissions

By 

EPA Method 321

CALIFORNIA PORTLAND CEMENT COMPANY

MOJAVE, CA

APRIL 2010

Submitted by:

Emission Monitoring Inc.

8901 Glenwood Ave.

Raleigh, NC 27617

Submitted to:

CALPORTLAND INC

9350 OAK CREEK ROAD

MOJAVE, CA 93501
ii

TABLE OF CONTENTS

SECTION PAGE

1. Introduction 1

1.1 Summary of Test Program

1.2 Test Program Organization

2.0 Source Description 4

2.1 Process Description

2.2 Control Equipment Description

3.0 Test Program 4

3.1 Objectives

4.0 Sample Locations 5

4.1 Flue Gas Sampling Location

5.0 Sampling and Analytical Procedures 6

5.1 Test Methods

6.0 Internal QA/QC Activities 8

6.1 QC Procedures

6.2 QA Procedures

6.3 QA/QC Checks for Data Reduction and Validation

TABLES

Table 1.2 Test Program Organization 1

Table 2.1 EPA Reporting Spreadsheet 3

Table 4.1 Test Location Data 5

Table 6.1 Method 321 QA Procedures 8

FIGURES

Figure 4.1 Kiln #3 Exhaust Stack Sampling Location 6

APPENDIX A METHOD 320/321 REPORT

APPENDIX B METHOD 3A DATA FOR OXYGEN

APPENDIX C METHOD 1 & 2 DATA FOR FLOW RATE
1

1.0 INTRODUCTION

1.1 Summary of Test Program

CalPortland conducted emissions testing for hydrochloric acid gas (HCl) at the Mojave, CA

facility in order to satisfy the EPA Section 114 request (under the CAA) dated February 3, 2010. 

Raw mill on and off testing was completed on March 30 and 31, 2010.

The test methods were specified Section 1.2 and Table 1.2 of Enclosure 2 attached to the EPA 

114 request (revision 2-20-2010). A summary of the test program is presented below. 

Test Method Test Runs and 

Duration

Target Analyte Process 

Condition

Method 320 3 – 1 hr Effluent Moisture & CO2 Raw Mill On

3 – 1 hr Raw Mill Off

Method 321 3 – 1 hr Hydrochloric Acid Gas (HCl) Raw Mill On

3 – 1 hr Raw Mill Off

Method 3A 3 – 1 hr Effluent Oxygen Raw Mill On

3 – 1 hr Raw Mill Off

Methods 1 & 2 Before/During 

M321 Runs

Effluent Velocity Raw Mill On

Raw Mill Off

The table below presents the testing program organization.

1.2 The Table below identifies the test program organization.

Personnel Title Contact Information Test Program 

Responsibilities

Jay Grady Cooperate 

Environmental 

Manager

626.852.6262

jgrady@calportland.com

CalPortland 

Corporate Contact

Mike Kirby Facility 

Environmental 

Manager

661.824.2401

mkirby@calportland.com

Mojave Plant 

Environmental 

Contact

Phil Kauppi FTIR Operator 989.772.5088

p.kauppi@pati-air.com

Tester

FTIR Operator and 

Methods 1 and 2 

Assistance

Laura Kinner 

Ph.D.

Consultant 919.781.3824

lkinner@emissionmonitoring.com

Test Program 

Coordinator

Methods 1-3A
2

Raw mill on testing was completed without incident. Immediately following Run 1 of mill off 

testing, the facility experienced a power failure due to high wind conditions. This resulted in a 

loss of feed to the system and non-representative operation for testing purposes. A period of 

about 5 hours was required to re-establish feed and combustion conditions so that testing could 

resume. Results for mill off operation were collected under representative conditions, however, 

flow rates were observed to be more variable than if the system had not experienced power 

failure.

Results from this test program are summarized in the spreadsheet provided by EPA and included 

herein as Table 1.2. 

Appendix A presents the entire Method 321/320 report for HCl, CO2 and moisture, Appendix B 

presents the Method 3A data for oxygen, and Appendix C presents the effluent velocity data and 

volumetric flowrate calculation results.
TABLE 1.2 EPA REPORTING SPREADSHEET

Company Name:

Facility Name: Mojave FacilityAddress: 9350 Oak Creek Rd Mojave CA 93501City: Mojave FacilityState: CaliforniaKiln ID:Kiln Type: Pre-Heater/ Pre-CalcinerIn-line Raw Mill: YesControl Device Configuration: 

Parameter

Sample #1

Sample #2

Sample #3

Avg. Units Test Method Used Test Locat

EPA Instructions

Select appropriate unit from list. If other is selected please describe units in column H at right. Enter the name of the Test Method used.

Indicate whether toccurred upstream downstream of a cdevice(s); list the device(s)

Sample Date (mm/dd/yyyy) 3/30/2010 3/30/2010 3/30/2010HCl Concentration - as measured - Wet Basis 6.3 6.3 5.8 6.1 ppmv Wet M321 Downstream of B

HCl Concentration Dry Basis 6.9 6.9 6.3 6.7 ppm v Dry M321 Downstream of B

Oxygen Concentration - dry basis 12.42 12.07 11.92 12.1 % M3A Downstream of B

CO2 Concentration - dry basis 19.1 19.1 19.1 19.1 % M3A Downstream of BHCl Concentration - dry corrected to 7% oxygen 11.2 10.8 9.8 10.6 ppm v dry at 7% O2 M321 Downstream of B

Exhaust Stream %Moisture 8.2 8.2 8.2 8.2 % M320 Downstream of B

Exhaust Flowrate 259,488 259,249 253,513 257,417 dscfm M1, 2, 3A, 320 Downstream of B

Exhaust Temperature 219 230 230 226 F T/C Downstream of B

Sample Date (mm/dd/yyyy) 3/31/2010 3/31/2010 3/31/2010

HCl Concentration - as measured - Wet Basis 57.3 66.8 68.1 64.1 ppmv Wet M321 Downstream of B

HCl Concentration Dry Basis 59.9 69.9 71.0 67.0 ppm v Dry M321 Downstream of B

Oxygen Concentration - dry basis 12.3 11.9 10.56 11.6 % M3A Downstream of B

CO2 Concentration - dry basis 21.7 16.7 19.7 19.3 % M3A Downstream of BHCl Concentration - dry corrected to 7% oxygen 96.9 108.0 95.5 100.1 ppm v dry at 7% O2 M321 Downstream of B

Exhaust Stream %Moisture 4.4 4.5 4.1 4.3 % M320 Downstream of B

Exhaust Flowrate 218,776 200,306 214,974 211,352 dscfm M1, 2, 3A, 320 Downstream of B

Exhaust Temperature 354 411 410 392 F T/C Downstream of B

Notes:

California Portland Cement Co.Kiln 1BaghouseEnter HCl concentration value in dry parts per million volume (ppmvd) corrected to 7% oxygen. If the test results are below detection limit, please note the detection limit in brackets (e.g., [< 0.010]). 

Method 320 data used for moisture and CO2 results reporting.
4

2.0 SOURCE DESCRIPTION

CalPortland Company operates a coal/coke fired (natural gas backup) pre-heater/pre-calciner 

cement kiln system with an in-line raw mill at its Mojave, CA facility. The kiln is rated for 1.5 

million tons per year clinker. Emissions are controlled by a fabric filter baghouse.

The Mojave facility is permitted to operate by the State of California under the Title-V 

Operating Permit Number 1003-V-2000, PSD Permit # 78-73 and Kern County APCD PTO # 

1003026M.

The physical address of the plant is: 9350 Oak Creek Road

Mojave, CA 93501

2.1 Process Description

Crushed and sized limestone feed and other raw materials are ground and mixed in the in-line 

raw mill system and fed into the preheater tower. The raw materials travel countercurrent to the 

process gases through the tower and are partially calcined before entering the rotary kiln. 

Fuels combusted in the pre-calciner and rotary kiln are comprised of coal, coke or natural gas. 

Fuel consumption approximates 3.2 Million BTU/short ton of clinker.

2.2 Control Equipment Description (H-5-6-DC1)

The pyroprocessing system is equipped with a 24 compartment dry fabric baghouse. The 

assembly contains 72 bags per module (1,728 total) and is sized for 400 to 440,000 ACFM. 

Kiln exhaust gas enters each the baghouse at a temperature of about 230-250 F. The cleaned gas 

passes through the single induced draft fan to an ID fan and attached 338 foot tall stack. 

3.0 TEST PROGRAM

3.1 Test Program Objectives

The objective of this test program was to collect valid HCl, O2, and moisture at the facility in 

order to report concentration levels of HCl corrected to a dry basis and 7% oxygen for both raw 

mill on and off operation. Effluent velocity and CO2 data were also collected so that effluent 

volumetric flowrates could be reported as requested by EPA.
5

4.0 SAMPLING LOCATION

The Kiln exhaust stack has four test ports (referred to as A-D) located 90° apart. General 

effluent conditions at the kiln stack are provided in Table 4-1. A digital image of the test

location is shown in Figure 4-1.

Table 4-1. Kiln # 3 Test Location Data

Test Location Data Measurement

Stack diameter 126.5 inches

Distance from sampling ports to upstream flow 

disturbances

>8 diameters

Distance from sampling ports to downstream flow 

disturbances

>2 diameters

Stack temperature** 220°F - 450°F

Flue gas flow rate, DSCFM** 200,000-260,000

Flue gas moisture, percent* 4 – 10%

Oxygen content, percent 10 – 14%

Carbon dioxide content, percent** 15-22%

*Depending on water spray for temperature control at baghouse inlet

** Depending on raw mill status

4.1 Flue Gas Sampling Locations

The Method 321/320/3A gas sampling probe was placed near the third velocity traverse point in 

Port C. The probe was removed during velocity traverses of this port. This sampling location 

met EPA Method 1 criteria for distance from the nearest flow disturbances and was found to be 

free of cyclonic flow having a <100 overall average angle.
6

Figure 4-1 Stack Sampling Location

5.0 TEST METHODS

5.1 Sampling Point Determination – EPA Method 1

The stack dimension was 126.5 inches ID and the number and location of the sampling and 

traverse points used are outlined in U.S. EPA Reference Method 1. 

5.2 Flue Gas Velocity and Volumetric Flow Rate - EPA Method 2

The flue gas velocity and volumetric flow rate during testing was determined according to the 

procedures outlined in U.S. EPA Reference Method 2. Velocity measurements were made using 

an S-type Pitot tube conforming to the geometric specifications outlined in Method 2 and 

assigned a coefficient of 0.84. Effluent gas temperatures were measured with chromel-alumel 

thermocouple attached to digital readout. 
7

5.3 Flue Gas Composition and Molecular Weight - EPA Method 3A

Flue gas analyses and calculation of oxygen concentrations was performed in accordance with 

EPA Method 3A. The O2 analyzer accepted sample post FTIR and shared the same sample 

extraction system. The oxygen analyzer received a dry sample as a conditioning unit was located 

upstream of the analyzer – post FTIR. 

Method 320 was used to provide CO2 concentrations on a wet basis. Method 320 was used to 

provide a moisture result so that CO2, and HCl results could be converted to a dry basis.

5.5 Method 321/320 – Hydrochloric Acid Gas and Moisture 

FT-IR data were collected using an On-Line Technologies Multi-Gas 2010 FT-IR spectrometer. 

A 4 ft., heated, 3/8 inch stainless steel probe, maintained at 180°C, was used to direct effluent 

gas from the stack to the FT-IR. A heated box, maintained at 180°C, containing the connection 

from the probe to the filter assembly, and to a 50 ft. heated, 3/8 inch transfer line was used for 

sample extraction on a hot and wet basis. The heated line was maintained at 180°C and all 

connecting fittings were insulated to prevent moisture condensation. A 0.1μ glass filter was used 

for particulate matter removal. 

All calibrations and spikes were delivered through the primary particulate matter filter.

The FTIR measurement system sampled effluent at a constant rate of greater than10 lpm from a 

single point within the stack. 

The FT-IR uses a temperature-controlled, 20.1meter multipass gas cell maintained at 180°C. 

Gas flows and sampling system pressures were monitored using a rotometer and pressure 

transducer. All data were collected at 0.5cm-1 resolution. Each spectrum was derived from the 

co addition of at least 64 scans. 

Data for HCl and moisture were collected continuously for each test, with a new data point 

generated about every seventy-two seconds. 

The minimum detectable concentration (MDC) of HCl for this measurement system and 

analytical algorithm was determined to be 0.2 ppm (v) wet based on analyzing water vapor 

spectra in the 5-10% range absent any HCl. The standard deviation of the results multiplied by 3 

was used in assigning the value for MDC. See ASTM D6348 for this procedure.
8

6.0 QUALITY CONTROL AND QUALITY ASSURANCE ACTIVITIES

6.1 Quality Control Procedures

The test methods employed in this program provided results on-site. No samples were generated 

for analyses by an off-site laboratory. 

The quality control measures for the FTIR measurement system consisted of: 1) ensuring that the 

temperature of the FTIR measurement cell, heated sample lines and probes were at 350oF or 

above, 2) ensuring that all connections between the probe, heated line and FTIR analyzer were

insulated to prevent moisture condensation, 3) ensuring that the pump had adequate capacity for 

the application, and 4) refining the analytical program prior to testing.

The elevated temperature and high relative flow rate through the measurement system minimizes

the HCl reactions and decrease measurement system passivation time. 

Ambient air was sampled before the start of testing to ensure that a stable “zero” reading is 

achieved for HCl (g). This procedure was also conducted post test to ensure sample lines are 

ready for subsequent testing programs. 

Direct calibrations with the calibration transfer standard (~100 ppm ethylene) and the HCl spike 

gases (~ 200 ppm HCl and ~ 50 ppm HCl both with ~ 4 ppm SF6) were performed before 

beginning testing to ensure a leak free system and system passivation for HCl.

For EPA Method 3A all zero, upscale and mid-point checks were conducted according to the 

method. Results provided were corrected for drift before using as the basis for correcting the 

HCl concentration results to 7% oxygen.

6.2 Quality Assurance procedures

The FTIR measurement system was challenged by conducting an ambient air zero, analyzing a 

CTS gas, analyzing HCl calibration gases and conducting HCl analyte spikes. Analyte spiking 

was conducted according to the procedures in Method 321. Namely, the resultant spike plus 

native concentration level approximated 2 times the actual native level, and the spike was ≤ 0.1 

of the total sample flow rate. All calibration and spike gases were delivered upstream of the 

particulate matter filter.

Table 6-1 Method 321 QA 

SPECTRAL FILES TO COLLECT PURPOSE

Background Optical “zero”

CTS – Direct FTIR Analyzer Check – 100 ppm ethylene

CTS – System FTIR Measurement System Check and 

Leak Check

HCl – Direct Cal Passivate system, determine direct value of 

cylinder HCl and SF6
9

Effluent Baseline HCl Background Concentration

Analyte Spike #1 QA Check of Entire Measurement System

Run 1 Effluent Data – 1 hr run

Analyte Spike #2 QA Check of Entire Measurement System

Run 2 Effluent Data – 1hr run

Analyte Spike #3 QA Check of Entire Measurement System

Run 3 Effluent Data – 1 hr run

Post Test Analyte Spike QA Check of Entire Measurement System

Post Test CTS Final Check of Analyzer

All calibrations and calibration checks required by Method 3A were conducted in the field and 

adherence to the method criteria were verified while on-site.

6.3 QA/QC Checks for Data Reduction and Validation

Method 321/320 is considered a “self validating” method because the analyte spiking procedure 

conducted in the field determines the accuracy of the entire measurement system for that 

particular flue gas matrix. Spikes for mill on were conducted using the ~50 ppm cylinder and 

spikes for mill off were conducted using the ~200 ppm cylinder so that resultant concentrations 

would be representative of the effluent concentration. 

Analyte spike recoveries were calculated in the field and all results were well within the method 

acceptance criteria.

6.4 Sample Identification 

Every Method 321 sample spectrum was identified with a unique file name.

All Method 3A sample runs had a unique identification number and all records of zero and 

calibration checks were documented.
10

APPENDIX A

METHOD 320/321 REPORT FROM PRISM ANALYTICAL TECHNOLOGIES 
1200 N. Fancher · Mount Pleasant, MI 48858 · (989) 772-5088 · Fax (989) 772-5870 

Cal Portland 

Mojave, California 

Emission Testing 

March 30 - 31, 2010 

Project No. 1663

Prepared For 

Emission Monitoring, Inc.

By 

Phillip J. Kauppi 

Chemist / FTIR Specialist 

April 16, 2010 
 

Cal Portland 

Mojave, California – Emission Testing 

March 30 - 31, 2010 

Project No. 1663 

Scope 

Prism Analytical Technologies, Inc. (PATI) was contracted by Emission Monitoring, Inc. (EMI) to 

conduct air emission testing at the Cal Portland Cement Plant, Mojave, California. Testing was 

performed March 30 - 31, 2010 to determine the concentrations of gaseous hydrogen chloride (HCl), 

carbon dioxide (CO2) and water (H2O) from the Main Stack while operating with and without the in-line 

raw mill. 

Extractive Fourier transform infrared (FTIR) spectrometry following US EPA Method 321 was 

performed to quantify the concentration levels of gaseous emissions from the Main Stack. Phillip 

Kauppi, PATI, performed FTIR data collection, data reduction and report generation. 

 

Procedures 

FTIR data were collected using an MKS MultiGas 2030 FTIR spectrometer, serial # 016252291. A 

heated, 8 ft., 3/8 inch diameter, stainless steel probe, maintained at 191°C, was used to direct effluent 

gas from the Main Stack to the FTIR. A heated filter box (191°C) contained the connection from the 

probe to the filter assembly to a 50 ft., heated, 3/8 inch, Teflon transfer line. A 0.1μ glass filter was used 

for particulate matter removal. 

The heated transfer line, held at 191°C, connected the probe/filter assembly to the FTIR. The FTIR was 

equipped with a temperature-controlled, 5.11 meter multipass gas cell maintained at 191°C. Gas flows 

and sampling system pressures were monitored using a rotometer and pressure transducer. All data were 

collected at 0.5cm-1 resolution. Each spectrum was derived from the coaddition of 60 scans, with a new 

data point generated every one minute. 

A calibration transfer standard (CTS), 100.0 ppm ethylene standard, was analyzed daily before and after 

testing. The concentration determined for all CTS runs were within ± 5% of the certified value of the 

standard. The ethylene was passed through the entire system (system purge) to determine the sampling 

system response time and to ensure that the sampling system was leak-free at the stack location. 

Nitrogen was purged through the sampling system before and after testing to confirm the system was 

free of contaminants. 

Direct FTIR measurements of two HCl/SF6 gas standards and the ethylene gas standard were made to 

confirm concentrations. The certified concentrations of the high HCl standard were 206.5 ppm HCl and 

4.11 ppm SF6. The determined cylinder concentration of HCl and SF6 were 181.1 ppm and 3.88 ppm, 

respectively. The certified concentrations of low HCl standard were 49.56 ppm HCl and 4.12 ppm SF6. 
prism analytical technologies, inc. 

Cal Portland, Mojave, CA - Emission Testing, March 30 - 31, 2010 

Project No. 1663 

 page 2 

The determined cylinder concentration of HCl and SF6 were 49.5 ppm and 3.80 ppm, respectively. The 

determined cylinder concentrations were the values used for all recovery calculations. 

HCl/SF6 standards were passed through the sampling system to determine the response time and confirm 

recovery. See the Main Stack FTIR QA/QC Data Appendix for results. 

HCl spiking was performed before and after each test run at the Main Stack to verify the ability of the 

sampling system to quantitatively deliver a sample containing HCl from the base of the probe to the 

FTIR. Analyte spiking assures the ability of the FTIR to quantify HCl in the presence of effluent gas. 

Stack samples were measured to determine the native HCl concentration to be used in the spike recovery 

calculations. The analyte spiking gas contained a low concentration of sulfur hexafluoride (SF6). The 

determined SF6 concentration in the spiked sample was used to calculate the dilution factor of the spike 

and thus used to calculate the concentration of the spiked HCl. The following equation illustrates the 

percent recovery calculation. 

ܨܦ ൌ ௌி଺ሺ௦௣௞ሻ

ௌி଺ሺௗ௜௥ሻ (Sec. 9.2.3 (3) USEPA Method 320) 

ܥܵ ൌ ܨܦ כ ܵ݌݅݇݁ሺ݀݅ݎሻ ൅ ܷ݊݌ݏ݅݇݁ሺ1 െ ܨܦሻ (Sec. 9.2.3 (4) USEPA Method 320) 

Due to the elevated native HCl concentrations of the Main Stack while operating with the raw mill off, 

the following calculation was used, which compares the calculated amount of HCl spiked into the system 

to the additional measured HCl in the spiked sa ple. m

ሻݎ݀݅ሺ݅݇݁݌ܵ כ ܨܦ ൌ ݅݇݁݀݌ܵ ݈ܥܪ

ሻܨܦ െ 1ሺ݅݇݁݌ݏܷ݊ െ ݈݁݌ܵܽ݉ ݅݇݁݀݌ܵ ൌ ݈ܥܪ ∆

ൌ ݕݎ݁ݒ݋ܴ݁ܿ %

݈ܥܪ∆

݅݇݁݌ܵ ݈ܥܪ

 DF = Dilution factor of the spike gas 

 SF6(dir) = SF6 concentration measured directly in undiluted spike gas

 SF6(spk) = Diluted SF6 concentration measured in a spiked sample 

 Spike(dir) = Concentration of the analyte in the spike standard measure by the FTIR directly 

 CS = Expected concentration of the spiked samples 

 Unspike = Native concentration of analytes in unspiked samples 

 HCl Spiked = Concentration of HCl spiked into the sample during analyte spiking 

Δ HCl = Difference between spiked sample and unspiked sample 

 
prism analytical technologies, inc. 

Cal Portland, Mojave, CA - Emission Testing, March 30 - 31, 2010 

Project No. 1663 

 page 3 

All analyte spikes were introduced using an instrument grade stainless steel rotometer. The spike target 

dilution ratio was 1:10 or less. All HCl spike recoveries were within the EPA Method 321 allowance of 

±30%. See Analyte Spike Summary Appendix for results. 

As part of the data validation procedure, reference spectra are manually fit to that of the sample spectra 

and a concentration is determined. The reference spectra are scaled to match the peak amplitude of the 

sample, thus providing a scale factor. The scale factor multiplied by the reference spectra concentration 

is used to determine the concentration value for the sample spectra. Sample pressure and temperature 

corrections are then applied to compute the final sample concentration. The manually calculated results 

are then compared with the software-generated results. The data is then validated if the two 

concentrations are within ± 5% agreement. If there is a difference greater than ± 5% the spectra are 

reviewed for possible spectra interferences or any other possible causes leading to misquantified data. 

Results and Discussion 

Detection Limits

The detection limit of each analyte was calculated following Annex A2 of ASTM D6348-3 

procedure using spectra that contained similar amounts of moisture. 

Table 1 - FTIR Detection Limits 

Analyte HCl  

(ppmv wet)

CO2

(%v)

H2O

(%v)

Det. Lim. 0.2 0.01 0.01

Results and Discussion 

The Main Stack – Raw Mill On

Three, 1-hour test runs were performed on The Main Stack while operating the in-line raw mill on 

March 30, 2010 (See Table 2 on following page for Test Run detail). Hydrogen chloride, CO2, and H2O 

was detected during the three test runs. Analyte spiking was performed before and after each test run to 

confirm the measurement system’s ability to deliver and quantify HCl (See Analyte Spike Summary 

Appendix for results). The HCl and CO2 concentration data were calculated on a wet volume basis. 

The sample and data collection followed the procedures outlined in USEPA Method 321 and PATI’s 

SOP 207. See the Main Stack FTIR Test Run Data appendix for all concentration data. 
prism analytical technologies, inc. 

Cal Portland, Mojave, CA - Emission Testing, March 30 - 31, 2010 

Project No. 1663 

 page 4 

Table 2. – Summary of FTIR Data, Main Stack – Raw Mill On 

Run 1, 10:30 – 11:30

3/30/2010

HCl

(ppmv wet)

CO2

(%v wet)

H2O

(%v)

Minimum 5.3 17.2 8.0

Maximum 6.9 17.8 8.3

Average 6.3 17.5 8.2

Run 2, 12:06 – 13:06

3/30/2010

HCl

(ppmv wet)

CO2

(%v wet)

H2O

(%v)

Minimum 5.3 17.2 8.0

Maximum 6.9 17.8 8.3

Average 6.3 17.5 8.2

Run 3, 13:40 – 14:40

3/30/2010

HCl

(ppmv wet)

CO2

(%v wet)

H2O

(%v)

Minimum 5.0 17.3 8.0

Maximum 6.3 18.0 8.4

Average 5.8 17.5 8.2

The Main Stack – Raw Mill Off

Three, 1-hour test runs were performed on The Main Stack while operating the in-line raw mill off 

March 31, 2010 (See Table 3 on for Test Run detail). Hydrogen chloride, CO2, and H2O was detected 

during the three test runs. Analyte spiking was performed before and after each test run to confirm the 

measurement system’s ability to deliver and quantify HCl (See Analyte Spike Summary Appendix for 

results). The HCl and CO2 concentration data were calculated on a wet volume basis. 

The sample and data collection followed the procedures outlined in USEPA Method 321 and PATI’s 

SOP 207. See the Main Stack FTIR Test Run Data appendix for all concentration data. 

Table 3. – Summary of FTIR Data, Main Stack – Raw Mill Off

Run 4, 7:20 – 8:20

3/31/2010

HCl

(ppmv wet)

CO2

(%v wet)

H2O

(%v)

Minimum 51.2 18.1 3.9

Maximum 61.9 21.9 4.6

Average 57.3 20.7 4.4

Run 5, 13:36 – 14:36

3/31/2010

HCl

(ppmv wet)

CO2

(%v wet)

H2O

(%v)

Minimum 55.2 14.5 3.5

Maximum 86.5 16.9 6.8

Average 66.8 15.9 4.5

Run 6, 14:54 – 15:54

3/31/2010

HCl

(ppmv wet)

CO2

(%v wet)

H2O

(%v)

Minimum 63.8 17.8 3.9

Maximum 72.7 20.1 4.3

Average 68.1 18.9 4.1
prism analytical technologies, inc. 

Cal Portland, Mojave, CA - Emission Testing, March 30 - 31, 2010 

Project No. 1663 

 page 5 

The following appendices include FTIR data and QA/QC procedures: 

- The Main Stack, Raw Mill On – FTIR Test Run Data 

- The Main Stack, Raw Mill Off – FTIR Test Run Data 

- The Main Stack FTIR QA/QC Data 

- Analyte Spike Summary 

- Gas Certificates and Field Notes 

- US EPA Method 321 Calculations 

Phillip J. Kauppi (electronic)________ Date: April 16, 2010

Phillip J. Kauppi 

Chemist / FTIR Specialist 

CalPortland_Mojave_1663.doc 
APPENDIX 

Main Stack – Raw Mill On 

FTIR Test Run Data 

 
Cal Portland Cement Company, Mojave, CA ‐ Test Run #1 ‐ FTIR Data

FTIR Spectrum Date Time

HCL           

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

FTIR Gas Cell

Temp (C)

FTIR Gas Cell

Pressure (Atm)

MILL_ON_R1_000265.LAB 3/30/2010 10:30:00 5.6 17.47 9.55 191.31 0.812

MILL_ON_R1_000266.LAB 3/30/2010 10:30:31 5.3 17.40 9.58 191.31 0.812

MILL_ON_R1_000267.LAB 3/30/2010 10:31:02 5.1 17.41 9.50 191.32 0.812

MILL_ON_R1_000268.LAB 3/30/2010 10:32:31 4.8 17.42 9.60 191.33 0.813

MILL_ON_R1_000269.LAB 3/30/2010 10:33:29 4.6 17.48 9.63 191.34 0.813

MILL_ON_R1_000270.LAB 3/30/2010 10:34:28 4.4 17.43 9.63 191.35 0.813

MILL_ON_R1_000271.LAB 3/30/2010 10:35:27 4.4 17.26 9.53 191.34 0.813

MILL_ON_R1_000272.LAB 3/30/2010 10:36:26 4.2 17.33 9.55 191.35 0.814

MILL_ON_R1_000273.LAB 3/30/2010 10:37:25 4.1 17.26 9.51 191.35 0.815

MILL_ON_R1_000274.LAB 3/30/2010 10:38:23 4.2 17.33 9.52 191.35 0.813

MILL_ON_R1_000275.LAB 3/30/2010 10:39:22 4.1 17.45 9.51 191.36 0.813

MILL_ON_R1_000276.LAB 3/30/2010 10:40:21 4.0 17.41 9.45 191.38 0.814

MILL_ON_R1_000277.LAB 3/30/2010 10:41:20 4.0 17.18 9.37 191.37 0.813

MILL_ON_R1_000278.LAB 3/30/2010 10:42:18 3.9 17.18 9.39 191.34 0.814

MILL_ON_R1_000279.LAB 3/30/2010 10:43:17 3.9 17.18 9.34 191.35 0.815

MILL_ON_R1_000280.LAB 3/30/2010 10:44:16 3.9 17.23 9.38 191.34 0.814

MILL_ON_R1_000281.LAB 3/30/2010 10:45:15 4.0 17.35 9.36 191.35 0.815

MILL_ON_R1_000282.LAB 3/30/2010 10:46:14 4.0 17.35 9.32 191.35 0.815

MILL_ON_R1_000283.LAB 3/30/2010 10:47:12 4.0 17.16 9.22 191.35 0.815

MILL_ON_R1_000284.LAB 3/30/2010 10:48:11 4.0 17.32 9.21 191.34 0.815

MILL_ON_R1_000285.LAB 3/30/2010 10:49:10 4.1 17.09 9.19 191.32 0.815

MILL_ON_R1_000286.LAB 3/30/2010 10:50:09 4.1 17.23 9.20 191.31 0.814

MILL_ON_R1_000287.LAB 3/30/2010 10:51:07 4.1 17.09 9.14 191.31 0.814

MILL_ON_R1_000288.LAB 3/30/2010 10:52:06 4.2 17.37 9.16 191.32 0.815

MILL_ON_R1_000289.LAB 3/30/2010 10:53:05 4.3 17.15 9.07 191.30 0.816

MILL_ON_R1_000290.LAB 3/30/2010 10:54:04 4.5 17.13 9.10 191.31 0.814

MILL_ON_R1_000291.LAB 3/30/2010 10:55:03 4.7 17.21 9.04 191.32 0.814

MILL_ON_R1_000292.LAB 3/30/2010 10:56:01 4.8 17.34 9.05 191.33 0.814

MILL ON R1 000293 LAB MILL_ON_R1_000293.LAB 3/30/2010 3/30/2010 10:57:00 10:57:00 4 9. 17 23 . 9 03 . 191 32 . 0 813 .

MILL_ON_R1_000294.LAB 3/30/2010 10:57:59 4.9 17.26 9.04 191.31 0.814

MILL_ON_R1_000295.LAB 3/30/2010 10:58:58 5.0 17.10 8.94 191.33 0.814

MILL_ON_R1_000296.LAB 3/30/2010 10:59:56 5.2 17.37 8.96 191.35 0.814

MILL_ON_R1_000297.LAB 3/30/2010 11:00:55 5.4 17.34 8.95 191.36 0.813

MILL_ON_R1_000298.LAB 3/30/2010 11:01:54 5.4 17.17 8.89 191.36 0.814

MILL_ON_R1_000299.LAB 3/30/2010 11:02:53 5.4 17.12 8.85 191.33 0.814

MILL_ON_R1_000300.LAB 3/30/2010 11:03:52 5.4 17.33 8.90 191.32 0.813

MILL_ON_R1_000301.LAB 3/30/2010 11:04:50 5.5 17.14 8.77 191.33 0.815

MILL_ON_R1_000302.LAB 3/30/2010 11:05:49 5.3 17.09 8.80 191.32 0.816

MILL_ON_R1_000303.LAB 3/30/2010 11:06:48 5.2 17.07 8.77 191.36 0.814

MILL_ON_R1_000304.LAB 3/30/2010 11:07:47 5.4 17.15 8.70 191.34 0.813

MILL_ON_R1_000305.LAB 3/30/2010 11:08:45 5.4 17.18 8.72 191.35 0.813

MILL_ON_R1_000306.LAB 3/30/2010 11:09:44 5.4 17.20 8.76 191.33 0.814

MILL_ON_R1_000307.LAB 3/30/2010 11:10:43 5.5 16.92 8.63 191.32 0.814

MILL_ON_R1_000308.LAB 3/30/2010 11:11:42 5.6 17.14 8.72 191.33 0.814

MILL_ON_R1_000309.LAB 3/30/2010 11:12:41 5.6 17.03 8.57 191.34 0.814

MILL_ON_R1_000310.LAB 3/30/2010 11:13:39 5.6 17.06 8.56 191.33 0.815

MILL_ON_R1_000311.LAB 3/30/2010 11:14:38 5.6 17.10 8.51 191.29 0.815

MILL_ON_R1_000312.LAB 3/30/2010 11:15:37 5.8 17.31 8.54 191.29 0.814

MILL_ON_R1_000313.LAB 3/30/2010 11:16:36 5.9 17.24 8.43 191.29 0.814

MILL_ON_R1_000314.LAB 3/30/2010 11:17:35 5.8 17.34 8.43 191.33 0.815

MILL_ON_R1_000315.LAB 3/30/2010 11:18:33 5.9 17.22 8.38 191.33 0.814

MILL_ON_R1_000316.LAB 3/30/2010 11:19:32 6.0 17.21 8.41 191.32 0.813

MILL_ON_R1_000317.LAB 3/30/2010 11:20:31 5.8 17.29 8.31 191.35 0.814

MILL_ON_R1_000318.LAB 3/30/2010 11:21:30 5.9 17.22 8.34 191.35 0.815

Prj. # 1663
Cal Portland Cement Company, Mojave, CA ‐ Test Run #1 ‐ FTIR Data

FTIR Spectrum Date Time

HCL           

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

FTIR Gas Cell

Temp (C)

FTIR Gas Cell

Pressure (Atm)

MILL_ON_R1_000319.LAB 3/30/2010 11:22:28 5.9 17.08 8.27 191.30 0.816

MILL_ON_R1_000320.LAB 3/30/2010 11:23:27 5.9 17.04 8.33 191.31 0.815

MILL_ON_R1_000321.LAB 3/30/2010 11:24:26 5.9 17.29 8.32 191.31 0.815

MILL_ON_R1_000322.LAB 3/30/2010 11:25:25 6.0 17.20 8.30 191.32 0.816

MILL_ON_R1_000323.LAB 3/30/2010 11:26:24 5.9 17.15 8.19 191.33 0.816

MILL_ON_R1_000324.LAB 3/30/2010 11:27:22 5.9 17.23 8.33 191.33 0.815

MILL_ON_R1_000325.LAB 3/30/2010 11:28:21 6.1 17.31 8.32 191.33 0.816

MILL_ON_R1_000326.LAB 3/30/2010 11:29:20 5.9 17.37 8.36 191.34 0.815

MILL_ON_R1_000327.LAB 3/30/2010 11:30:19 5.8 17.39 8.29 191.33 0.815

Minimum 3.9 16.9 8.2

Maximum 6.1 17.5 9.6

Average 5.0 17.2 8.9

Prj. # 1663
Cal Portland Cement Company, Mojave, CA ‐ Test Run #2 ‐ FTIR Data

FTIR Spectrum Date Time

HCL           

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

FTIR Gas Cell

Temp (C)

FTIR Gas Cell

Pressure (Atm)

MILL_ON_R2_000359.LAB 3/30/2010 12:05:43 5.3 17.56 8.24 191.32 0.812

MILL_ON_R2_000360.LAB 3/30/2010 12:06:42 5.5 17.42 8.23 191.32 0.812

MILL_ON_R2_000361.LAB 3/30/2010 12:07:41 5.5 17.39 8.25 191.32 0.813

MILL_ON_R2_000362.LAB 3/30/2010 12:08:39 5.7 17.43 8.22 191.32 0.816

MILL_ON_R2_000363.LAB 3/30/2010 12:09:38 5.8 17.62 8.28 191.29 0.816

MILL_ON_R2_000364.LAB 3/30/2010 12:10:37 5.9 17.46 8.24 191.30 0.815

MILL_ON_R2_000365.LAB 3/30/2010 12:11:36 5.8 17.48 8.24 191.31 0.816

MILL_ON_R2_000366.LAB 3/30/2010 12:12:34 5.7 17.63 8.19 191.30 0.816

MILL_ON_R2_000367.LAB 3/30/2010 12:13:33 5.7 17.71 8.18 191.34 0.816

MILL_ON_R2_000368.LAB 3/30/2010 12:14:32 5.7 17.63 8.10 191.33 0.817

MILL_ON_R2_000369.LAB 3/30/2010 12:15:31 5.6 17.67 8.10 191.33 0.817

MILL_ON_R2_000370.LAB 3/30/2010 12:16:30 5.8 17.48 8.03 191.34 0.818

MILL_ON_R2_000371.LAB 3/30/2010 12:17:28 5.8 17.78 8.01 191.35 0.818

MILL_ON_R2_000372.LAB 3/30/2010 12:18:27 6.0 17.52 8.14 191.34 0.817

MILL_ON_R2_000373.LAB 3/30/2010 12:19:26 5.6 17.53 8.07 191.35 0.817

MILL_ON_R2_000374.LAB 3/30/2010 12:20:25 5.7 17.45 8.12 191.34 0.817

MILL_ON_R2_000375.LAB 3/30/2010 12:21:24 5.8 17.45 8.12 191.31 0.817

MILL_ON_R2_000376.LAB 3/30/2010 12:22:22 6.0 17.48 8.07 191.31 0.818

MILL_ON_R2_000377.LAB 3/30/2010 12:23:21 6.1 17.40 8.12 191.32 0.819

MILL_ON_R2_000378.LAB 3/30/2010 12:24:20 6.1 17.41 8.17 191.32 0.818

MILL_ON_R2_000379.LAB 3/30/2010 12:25:19 6.4 17.60 8.10 191.35 0.817

MILL_ON_R2_000380.LAB 3/30/2010 12:26:17 6.6 17.52 8.08 191.35 0.817

MILL_ON_R2_000381.LAB 3/30/2010 12:27:16 6.6 17.42 8.10 191.35 0.818

MILL_ON_R2_000382.LAB 3/30/2010 12:28:15 6.6 17.39 8.17 191.34 0.818

MILL_ON_R2_000383.LAB 3/30/2010 12:29:14 6.7 17.54 8.12 191.37 0.817

MILL_ON_R2_000384.LAB 3/30/2010 12:30:13 6.6 17.57 8.16 191.37 0.818

MILL_ON_R2_000385.LAB 3/30/2010 12:31:11 6.7 17.34 8.24 191.36 0.817

MILL_ON_R2_000386.LAB 3/30/2010 12:32:10 6.7 17.19 8.22 191.34 0.818

MILL ON R2 000387 LAB MILL_ON_R2_000387.LAB 3/30/2010 3/30/2010 12:33:09 12:33:09 6 7. 17 32 . 8 28 . 191 34 . 0 817 .

MILL_ON_R2_000388.LAB 3/30/2010 12:34:08 6.5 17.22 8.24 191.33 0.818

MILL_ON_R2_000389.LAB 3/30/2010 12:35:06 6.5 17.24 8.27 191.33 0.818

MILL_ON_R2_000390.LAB 3/30/2010 12:36:05 6.4 17.26 8.24 191.35 0.818

MILL_ON_R2_000391.LAB 3/30/2010 12:37:04 6.4 17.24 8.14 191.36 0.818

MILL_ON_R2_000392.LAB 3/30/2010 12:38:03 6.6 17.28 8.13 191.35 0.818

MILL_ON_R2_000393.LAB 3/30/2010 12:39:02 6.6 17.52 8.17 191.37 0.818

MILL_ON_R2_000394.LAB 3/30/2010 12:40:00 6.5 17.54 8.13 191.36 0.818

MILL_ON_R2_000395.LAB 3/30/2010 12:40:59 6.7 17.53 8.17 191.36 0.818

MILL_ON_R2_000396.LAB 3/30/2010 12:41:58 6.7 17.53 8.12 191.32 0.819

MILL_ON_R2_000397.LAB 3/30/2010 12:42:57 6.8 17.54 8.12 191.34 0.818

MILL_ON_R2_000398.LAB 3/30/2010 12:43:55 6.6 17.58 8.17 191.31 0.818

MILL_ON_R2_000399.LAB 3/30/2010 12:44:54 6.6 17.69 8.20 191.28 0.818

MILL_ON_R2_000400.LAB 3/30/2010 12:45:53 6.7 17.55 8.16 191.29 0.817

MILL_ON_R2_000401.LAB 3/30/2010 12:46:52 6.4 17.58 8.14 191.31 0.818

MILL_ON_R2_000402.LAB 3/30/2010 12:47:51 6.3 17.49 8.15 191.30 0.817

MILL_ON_R2_000403.LAB 3/30/2010 12:48:49 6.4 17.46 8.14 191.33 0.818

MILL_ON_R2_000404.LAB 3/30/2010 12:49:48 6.5 17.55 8.12 191.30 0.817

MILL_ON_R2_000405.LAB 3/30/2010 12:50:47 6.5 17.54 8.15 191.30 0.818

MILL_ON_R2_000406.LAB 3/30/2010 12:51:46 6.5 17.46 8.17 191.31 0.818

MILL_ON_R2_000407.LAB 3/30/2010 12:52:45 6.5 17.34 8.14 191.29 0.817

MILL_ON_R2_000408.LAB 3/30/2010 12:53:43 6.5 17.37 8.22 191.29 0.817

MILL_ON_R2_000409.LAB 3/30/2010 12:54:42 6.5 17.50 8.18 191.29 0.817

MILL_ON_R2_000410.LAB 3/30/2010 12:55:41 6.5 17.33 8.07 191.30 0.817

MILL_ON_R2_000411.LAB 3/30/2010 12:56:40 6.5 17.39 8.16 191.34 0.817

MILL_ON_R2_000412.LAB 3/30/2010 12:57:38 6.6 17.52 8.14 191.33 0.817

Prj. # 1663
Cal Portland Cement Company, Mojave, CA ‐ Test Run #2 ‐ FTIR Data

FTIR Spectrum Date Time

HCL           

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

FTIR Gas Cell

Temp (C)

FTIR Gas Cell

Pressure (Atm)

MILL_ON_R2_000413.LAB 3/30/2010 12:58:37 6.5 17.56 8.14 191.31 0.817

MILL_ON_R2_000414.LAB 3/30/2010 12:59:36 6.4 17.54 8.10 191.32 0.817

MILL_ON_R2_000415.LAB 3/30/2010 13:00:35 6.5 17.56 8.12 191.33 0.817

MILL_ON_R2_000416.LAB 3/30/2010 13:01:34 6.6 17.50 8.03 191.33 0.817

MILL_ON_R2_000417.LAB 3/30/2010 13:02:32 6.7 17.43 8.10 191.33 0.818

MILL_ON_R2_000418.LAB 3/30/2010 13:03:31 6.6 17.34 8.12 191.33 0.818

MILL_ON_R2_000419.LAB 3/30/2010 13:04:30 6.4 17.50 8.08 191.34 0.817

MILL_ON_R2_000420.LAB 3/30/2010 13:05:29 6.5 17.50 8.06 191.33 0.817

MILL_ON_R2_000421.LAB 3/30/2010 13:06:27 6.9 17.54 8.13 191.35 0.817

Minimum 5.3 17.2 8.0

Maximum 6.9 17.8 8.3

Average 6.3 17.5 8.2

Prj. # 1663
Cal Portland Cement Company, Mojave, CA ‐ Test Run #3 ‐ FTIR Data

FTIR Spectrum Date Time

HCL           

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

FTIR Gas Cell

Temp (C)

FTIR Gas Cell

Pressure (Atm)

MILL_ON_R3_000456.LAB 3/30/2010 13:40:13 5.4 17.52 8.28 191.32 0.811

MILL_ON_R3_000457.LAB 3/30/2010 13:41:12 5.3 17.35 8.26 191.29 0.812

MILL_ON_R3_000458.LAB 3/30/2010 13:42:11 5.5 17.48 8.28 191.29 0.813

MILL_ON_R3_000459.LAB 3/30/2010 13:43:10 5.5 17.65 8.29 191.30 0.813

MILL_ON_R3_000460.LAB 3/30/2010 13:44:09 5.5 17.43 8.30 191.34 0.814

MILL_ON_R3_000461.LAB 3/30/2010 13:45:07 5.5 17.60 8.32 191.33 0.815

MILL_ON_R3_000462.LAB 3/30/2010 13:46:06 5.5 17.46 8.28 191.35 0.816

MILL_ON_R3_000463.LAB 3/30/2010 13:47:05 5.5 17.57 8.26 191.31 0.815

MILL_ON_R3_000464.LAB 3/30/2010 13:48:04 5.5 17.51 8.25 191.26 0.815

MILL_ON_R3_000465.LAB 3/30/2010 13:49:02 5.3 17.37 8.29 191.28 0.815

MILL_ON_R3_000466.LAB 3/30/2010 13:50:01 5.2 17.44 8.26 191.32 0.815

MILL_ON_R3_000467.LAB 3/30/2010 13:51:00 5.6 17.58 8.32 191.31 0.815

MILL_ON_R3_000468.LAB 3/30/2010 13:51:59 5.6 17.68 8.35 191.32 0.816

MILL_ON_R3_000469.LAB 3/30/2010 13:52:58 5.7 17.50 8.31 191.30 0.815

MILL_ON_R3_000470.LAB 3/30/2010 13:53:56 5.7 17.52 8.31 191.30 0.816

MILL_ON_R3_000471.LAB 3/30/2010 13:54:55 6.1 17.66 8.29 191.32 0.815

MILL_ON_R3_000472.LAB 3/30/2010 13:55:54 6.0 17.50 8.25 191.32 0.815

MILL_ON_R3_000473.LAB 3/30/2010 13:56:53 6.0 17.41 8.19 191.29 0.814

MILL_ON_R3_000474.LAB 3/30/2010 13:57:51 5.9 17.39 8.17 191.31 0.815

MILL_ON_R3_000475.LAB 3/30/2010 13:58:50 6.1 17.45 8.12 191.31 0.815

MILL_ON_R3_000476.LAB 3/30/2010 13:59:49 6.1 17.52 8.13 191.34 0.815

MILL_ON_R3_000477.LAB 3/30/2010 14:00:48 6.1 17.41 8.09 191.32 0.815

MILL_ON_R3_000478.LAB 3/30/2010 14:01:47 6.2 17.29 8.07 191.34 0.815

MILL_ON_R3_000479.LAB 3/30/2010 14:02:45 6.3 17.45 8.06 191.31 0.815

MILL_ON_R3_000480.LAB 3/30/2010 14:03:44 6.3 17.37 8.04 191.29 0.815

MILL_ON_R3_000481.LAB 3/30/2010 14:04:43 6.3 17.32 8.07 191.28 0.815

MILL_ON_R3_000482.LAB 3/30/2010 14:05:42 6.2 17.38 8.12 191.29 0.815

MILL_ON_R3_000483.LAB 3/30/2010 14:06:40 6.0 17.39 8.13 191.29 0.815

MILL ON R3 000484 LAB MILL_ON_R3_000484.LAB 3/30/2010 3/30/2010 14:07:39 14:07:39 6 1. 17 36 . 8 13 . 191 31 . 0 814 .

MILL_ON_R3_000485.LAB 3/30/2010 14:08:38 6.0 17.37 8.11 191.35 0.815

MILL_ON_R3_000486.LAB 3/30/2010 14:09:37 6.0 17.37 8.09 191.32 0.815

MILL_ON_R3_000487.LAB 3/30/2010 14:10:36 6.0 17.56 8.18 191.28 0.815

MILL_ON_R3_000488.LAB 3/30/2010 14:11:34 5.9 17.54 8.15 191.28 0.814

MILL_ON_R3_000489.LAB 3/30/2010 14:12:33 6.0 17.59 8.16 191.29 0.815

MILL_ON_R3_000490.LAB 3/30/2010 14:13:32 5.9 17.32 8.14 191.30 0.815

MILL_ON_R3_000491.LAB 3/30/2010 14:14:31 5.9 17.52 8.22 191.31 0.815

MILL_ON_R3_000492.LAB 3/30/2010 14:15:30 6.0 17.65 8.14 191.29 0.815

MILL_ON_R3_000493.LAB 3/30/2010 14:16:28 6.0 17.67 8.15 191.30 0.814

MILL_ON_R3_000494.LAB 3/30/2010 14:17:27 5.9 17.69 8.30 191.32 0.813

MILL_ON_R3_000495.LAB 3/30/2010 14:18:26 5.8 17.53 8.32 191.29 0.814

MILL_ON_R3_000496.LAB 3/30/2010 14:19:25 5.6 17.52 8.28 191.28 0.814

MILL_ON_R3_000497.LAB 3/30/2010 14:20:23 5.7 17.49 8.16 191.26 0.814

MILL_ON_R3_000498.LAB 3/30/2010 14:21:22 5.6 17.54 8.22 191.28 0.814

MILL_ON_R3_000499.LAB 3/30/2010 14:22:21 5.6 17.48 8.20 191.31 0.815

MILL_ON_R3_000500.LAB 3/30/2010 14:23:20 5.7 17.62 8.23 191.30 0.815

MILL_ON_R3_000501.LAB 3/30/2010 14:24:19 5.7 17.71 8.25 191.31 0.813

MILL_ON_R3_000502.LAB 3/30/2010 14:25:17 5.6 17.57 8.14 191.28 0.815

MILL_ON_R3_000503.LAB 3/30/2010 14:26:16 5.6 17.65 8.14 191.29 0.814

MILL_ON_R3_000504.LAB 3/30/2010 14:27:15 5.8 17.70 8.18 191.27 0.814

MILL_ON_R3_000505.LAB 3/30/2010 14:28:14 5.7 17.73 8.23 191.29 0.814

MILL_ON_R3_000506.LAB 3/30/2010 14:29:12 5.6 17.85 8.22 191.29 0.814

MILL_ON_R3_000507.LAB 3/30/2010 14:30:11 5.6 17.77 8.24 191.29 0.814

MILL_ON_R3_000508.LAB 3/30/2010 14:31:10 5.6 17.72 8.16 191.30 0.814

MILL_ON_R3_000509.LAB 3/30/2010 14:32:09 5.7 17.99 8.32 191.29 0.813

Prj. # 1663
Cal Portland Cement Company, Mojave, CA ‐ Test Run #3 ‐ FTIR Data

FTIR Spectrum Date Time

HCL           

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

FTIR Gas Cell

Temp (C)

FTIR Gas Cell

Pressure (Atm)

MILL_ON_R3_000510.LAB 3/30/2010 14:33:08 5.5 17.67 8.31 191.32 0.813

MILL_ON_R3_000511.LAB 3/30/2010 14:34:06 5.2 17.59 8.30 191.31 0.813

MILL_ON_R3_000512.LAB 3/30/2010 14:35:05 5.0 17.56 8.29 191.30 0.814

MILL_ON_R3_000513.LAB 3/30/2010 14:36:04 5.4 17.63 8.26 191.31 0.814

MILL_ON_R3_000514.LAB 3/30/2010 14:37:03 5.6 17.49 8.25 191.29 0.814

MILL_ON_R3_000515.LAB 3/30/2010 14:38:01 5.7 17.55 8.28 191.29 0.814

MILL_ON_R3_000516.LAB 3/30/2010 14:39:00 5.7 17.65 8.25 191.29 0.814

MILL_ON_R3_000517.LAB 3/30/2010 14:39:59 6.1 17.65 8.30 191.27 0.814

MILL_ON_R3_000518.LAB 3/30/2010 14:40:58 6.1 17.50 8.34 191.27 0.814

Minimum 5.0 17.3 8.0

Maximum 6.3 18.0 8.4

Average 5.8 17.5 8.2

Prj. # 1663
APPENDIX 

Main Stack – Raw Mill Off 

FTIR Test Run Data 

 
Cal Portland Cement Company, Mojave, CA ‐ Test Run #4 ‐ FTIR Data

FTIR Spectrum Date Time

HCL           

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

FTIR Gas Cell

Temp (C)

FTIR Gas Cell

Pressure (Atm)

MILL_OFF_R4_000639.LAB 3/31/2010 7:19:57 52.4 18.53 4.03 191.38 0.832

MILL_OFF_R4_000640.LAB 3/31/2010 7:20:56 52.1 18.41 4.01 191.38 0.833

MILL_OFF_R4_000641.LAB 3/31/2010 7:21:55 51.6 18.32 3.98 191.42 0.833

MILL_OFF_R4_000642.LAB 3/31/2010 7:22:53 51.7 18.13 3.96 191.40 0.833

MILL_OFF_R4_000643.LAB 3/31/2010 7:23:52 51.5 18.07 3.95 191.38 0.834

MILL_OFF_R4_000644.LAB 3/31/2010 7:24:51 51.7 18.06 3.94 191.40 0.834

MILL_OFF_R4_000645.LAB 3/31/2010 7:25:50 52.1 18.35 3.97 191.39 0.834

MILL_OFF_R4_000646.LAB 3/31/2010 7:26:49 52.3 18.29 3.99 191.38 0.834

MILL_OFF_R4_000647.LAB 3/31/2010 7:27:47 51.8 18.20 3.98 191.46 0.835

MILL_OFF_R4_000648.LAB 3/31/2010 7:28:46 51.3 18.18 3.94 191.45 0.835

MILL_OFF_R4_000649.LAB 3/31/2010 7:29:45 51.7 18.36 3.97 191.42 0.836

MILL_OFF_R4_000650.LAB 3/31/2010 7:30:44 51.7 18.20 3.96 191.41 0.836

MILL_OFF_R4_000651.LAB 3/31/2010 7:31:43 51.4 18.15 3.93 191.38 0.836

MILL_OFF_R4_000652.LAB 3/31/2010 7:32:41 51.2 18.26 3.95 191.38 0.836

MILL_OFF_R4_000653.LAB 3/31/2010 7:33:40 51.3 18.24 3.95 191.38 0.836

MILL_OFF_R4_000654.LAB 3/31/2010 7:34:39 54.7 19.62 4.23 191.38 0.836

MILL_OFF_R4_000655.LAB 3/31/2010 7:35:38 60.0 21.64 4.57 191.41 0.835

MILL_OFF_R4_000656.LAB 3/31/2010 7:36:36 58.5 21.54 4.60 191.38 0.835

MILL_OFF_R4_000657.LAB 3/31/2010 7:37:35 57.0 21.27 4.55 191.40 0.835

MILL_OFF_R4_000658.LAB 3/31/2010 7:38:34 55.3 20.30 4.38 191.38 0.835

MILL_OFF_R4_000659.LAB 3/31/2010 7:39:33 57.0 20.78 4.47 191.38 0.835

MILL_OFF_R4_000660.LAB 3/31/2010 7:40:32 59.3 21.71 4.61 191.38 0.835

MILL_OFF_R4_000661.LAB 3/31/2010 7:41:30 59.5 21.86 4.61 191.38 0.834

MILL_OFF_R4_000662.LAB 3/31/2010 7:42:29 59.0 21.55 4.57 191.39 0.835

MILL_OFF_R4_000663.LAB 3/31/2010 7:43:28 58.5 21.26 4.56 191.39 0.835

MILL_OFF_R4_000664.LAB 3/31/2010 7:44:27 58.6 21.40 4.55 191.36 0.835

MILL_OFF_R4_000665.LAB 3/31/2010 7:45:26 58.6 21.52 4.57 191.36 0.835

MILL_OFF_R4_000666.LAB 3/31/2010 7:46:24 59.7 21.66 4.55 191.37 0.835

MILL OFF R4 000667 LAB MILL_OFF_R4_000667.LAB 3/31/2010 3/31/2010 7:47:23 7:47:23 59 5. 21 51 . 4 57 . 191 36 . 0 835 .

MILL_OFF_R4_000668.LAB 3/31/2010 7:48:22 59.5 21.66 4.54 191.38 0.835

MILL_OFF_R4_000669.LAB 3/31/2010 7:49:21 59.2 21.66 4.57 191.38 0.834

MILL_OFF_R4_000670.LAB 3/31/2010 7:50:20 59.6 21.63 4.55 191.39 0.834

MILL_OFF_R4_000671.LAB 3/31/2010 7:51:18 59.3 21.52 4.54 191.38 0.834

MILL_OFF_R4_000672.LAB 3/31/2010 7:52:17 58.4 21.42 4.53 191.36 0.834

MILL_OFF_R4_000673.LAB 3/31/2010 7:53:16 58.0 21.49 4.51 191.38 0.834

MILL_OFF_R4_000674.LAB 3/31/2010 7:54:15 58.2 21.50 4.54 191.37 0.834

MILL_OFF_R4_000675.LAB 3/31/2010 7:55:13 58.5 21.59 4.57 191.43 0.834

MILL_OFF_R4_000676.LAB 3/31/2010 7:56:12 58.5 21.59 4.58 191.37 0.834

MILL_OFF_R4_000677.LAB 3/31/2010 7:57:11 58.3 21.64 4.56 191.42 0.833

MILL_OFF_R4_000678.LAB 3/31/2010 7:58:10 58.1 21.58 4.52 191.44 0.834

MILL_OFF_R4_000679.LAB 3/31/2010 7:59:09 58.8 21.53 4.54 191.42 0.834

MILL_OFF_R4_000680.LAB 3/31/2010 8:00:07 59.2 21.41 4.50 191.40 0.834

MILL_OFF_R4_000681.LAB 3/31/2010 8:01:06 59.1 21.51 4.49 191.37 0.833

MILL_OFF_R4_000682.LAB 3/31/2010 8:02:05 59.3 21.48 4.53 191.40 0.834

MILL_OFF_R4_000683.LAB 3/31/2010 8:03:04 60.0 21.56 4.52 191.40 0.834

MILL_OFF_R4_000684.LAB 3/31/2010 8:04:03 59.3 21.23 4.47 191.37 0.833

MILL_OFF_R4_000685.LAB 3/31/2010 8:05:01 59.9 21.66 4.53 191.37 0.834

MILL_OFF_R4_000686.LAB 3/31/2010 8:06:00 59.0 21.53 4.49 191.37 0.836

MILL_OFF_R4_000687.LAB 3/31/2010 8:06:59 59.1 21.68 4.53 191.41 0.836

MILL_OFF_R4_000688.LAB 3/31/2010 8:07:58 58.9 21.43 4.51 191.45 0.836

MILL_OFF_R4_000689.LAB 3/31/2010 8:08:57 58.7 21.47 4.50 191.38 0.836

MILL_OFF_R4_000690.LAB 3/31/2010 8:09:55 58.4 21.39 4.46 191.36 0.836

MILL_OFF_R4_000691.LAB 3/31/2010 8:10:54 59.4 21.70 4.52 191.35 0.836

MILL_OFF_R4_000692.LAB 3/31/2010 8:11:53 59.2 21.48 4.52 191.37 0.835

Prj. # 1663
Cal Portland Cement Company, Mojave, CA ‐ Test Run #4 ‐ FTIR Data

FTIR Spectrum Date Time

HCL           

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

FTIR Gas Cell

Temp (C)

FTIR Gas Cell

Pressure (Atm)

MILL_OFF_R4_000693.LAB 3/31/2010 8:12:52 59.9 21.82 4.54 191.39 0.835

MILL_OFF_R4_000694.LAB 3/31/2010 8:13:51 59.9 21.62 4.53 191.36 0.835

MILL_OFF_R4_000695.LAB 3/31/2010 8:14:49 60.7 21.72 4.56 191.35 0.835

MILL_OFF_R4_000696.LAB 3/31/2010 8:15:48 60.3 21.41 4.55 191.36 0.836

MILL_OFF_R4_000697.LAB 3/31/2010 8:16:47 61.0 21.65 4.55 191.35 0.836

MILL_OFF_R4_000698.LAB 3/31/2010 8:17:46 61.0 21.70 4.54 191.35 0.835

MILL_OFF_R4_000699.LAB 3/31/2010 8:18:44 61.1 21.66 4.55 191.38 0.835

MILL_OFF_R4_000700.LAB 3/31/2010 8:19:43 60.8 21.47 4.51 191.36 0.835

MILL_OFF_R4_000701.LAB 3/31/2010 8:20:42 61.9 21.73 4.56 191.36 0.835

Minimum 51.2 18.1 3.9

Maximum 61.9 21.9 4.6

Average 57.3 20.7 4.4

Prj. # 1663
Cal Portland Cement Company, Mojave, CA ‐ Test Run #5 ‐ FTIR Data

FTIR Spectrum Date Time

HCL           

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

FTIR Gas Cell

Temp (C)

FTIR Gas Cell

Pressure (Atm)

MILL_OFF_R5_000777.LAB 3/31/2010 13:36:16 77.8 14.55 5.86 191.40 0.837

MILL_OFF_R5_000778.LAB 3/31/2010 13:37:15 82.3 15.01 6.13 191.38 0.838

MILL_OFF_R5_000779.LAB 3/31/2010 13:38:14 83.8 15.41 6.28 191.40 0.838

MILL_OFF_R5_000780.LAB 3/31/2010 13:39:13 85.7 15.55 6.77 191.37 0.837

MILL_OFF_R5_000781.LAB 3/31/2010 13:40:11 86.5 15.62 6.83 191.42 0.837

MILL_OFF_R5_000782.LAB 3/31/2010 13:41:10 84.0 15.13 6.73 191.45 0.838

MILL_OFF_R5_000783.LAB 3/31/2010 13:42:09 80.6 14.94 6.54 191.38 0.839

MILL_OFF_R5_000784.LAB 3/31/2010 13:43:08 81.4 15.02 6.60 191.40 0.839

MILL_OFF_R5_000785.LAB 3/31/2010 13:44:07 80.2 14.94 6.49 191.39 0.839

MILL_OFF_R5_000786.LAB 3/31/2010 13:45:05 81.5 15.03 6.56 191.36 0.839

MILL_OFF_R5_000787.LAB 3/31/2010 13:46:04 82.0 15.37 6.56 191.36 0.839

MILL_OFF_R5_000788.LAB 3/31/2010 13:47:03 82.5 15.38 6.59 191.38 0.839

MILL_OFF_R5_000789.LAB 3/31/2010 13:48:02 81.7 15.24 6.56 191.41 0.838

MILL_OFF_R5_000790.LAB 3/31/2010 13:49:01 84.3 16.19 6.84 191.37 0.838

MILL_OFF_R5_000791.LAB 3/31/2010 13:50:00 78.6 15.80 6.34 191.35 0.838

MILL_OFF_R5_000792.LAB 3/31/2010 13:50:58 64.2 14.52 4.78 191.37 0.839

MILL_OFF_R5_000793.LAB 3/31/2010 13:51:57 65.9 14.72 4.72 191.46 0.839

MILL_OFF_R5_000794.LAB 3/31/2010 13:52:56 66.5 14.86 4.68 191.41 0.838

MILL_OFF_R5_000795.LAB 3/31/2010 13:53:55 66.9 15.02 4.70 191.41 0.839

MILL_OFF_R5_000796.LAB 3/31/2010 13:54:54 66.6 15.19 4.67 191.46 0.839

MILL_OFF_R5_000797.LAB 3/31/2010 13:55:52 66.3 15.15 4.68 191.40 0.838

MILL_OFF_R5_000798.LAB 3/31/2010 13:56:51 65.2 15.11 4.67 191.38 0.838

MILL_OFF_R5_000799.LAB 3/31/2010 13:57:50 63.1 15.32 4.36 191.37 0.838

MILL_OFF_R5_000800.LAB 3/31/2010 13:58:49 61.8 15.30 4.09 191.39 0.837

MILL_OFF_R5_000801.LAB 3/31/2010 13:59:48 60.9 15.31 4.06 191.41 0.837

MILL_OFF_R5_000802.LAB 3/31/2010 14:00:46 62.7 15.85 4.23 191.40 0.837

MILL_OFF_R5_000803.LAB 3/31/2010 14:01:45 63.7 16.28 4.35 191.39 0.837

MILL_OFF_R5_000804.LAB 3/31/2010 14:02:44 59.9 15.73 4.06 191.46 0.838

MILL OFF R5 000805 LAB MILL_OFF_R5_000805.LAB 3/31/2010 3/31/2010 14:03:43 14:03:43 55 9. 15 32 . 3 57 . 191 44 . 0 838 .

MILL_OFF_R5_000806.LAB 3/31/2010 14:04:42 55.2 15.05 3.47 191.41 0.838

MILL_OFF_R5_000807.LAB 3/31/2010 14:05:40 56.2 15.31 3.50 191.39 0.838

MILL_OFF_R5_000808.LAB 3/31/2010 14:06:39 58.0 15.59 3.54 191.35 0.838

MILL_OFF_R5_000809.LAB 3/31/2010 14:07:38 57.9 15.83 3.59 191.39 0.838

MILL_OFF_R5_000810.LAB 3/31/2010 14:08:37 59.3 16.14 3.64 191.39 0.837

MILL_OFF_R5_000811.LAB 3/31/2010 14:09:36 61.4 16.72 3.76 191.38 0.837

MILL_OFF_R5_000812.LAB 3/31/2010 14:10:34 62.2 16.85 3.75 191.38 0.837

MILL_OFF_R5_000813.LAB 3/31/2010 14:11:33 61.3 16.52 3.73 191.36 0.836

MILL_OFF_R5_000814.LAB 3/31/2010 14:12:32 61.7 16.41 3.75 191.36 0.836

MILL_OFF_R5_000815.LAB 3/31/2010 14:13:31 62.1 16.51 3.74 191.35 0.836

MILL_OFF_R5_000816.LAB 3/31/2010 14:14:30 62.3 16.58 3.76 191.32 0.837

MILL_OFF_R5_000817.LAB 3/31/2010 14:15:28 61.4 16.61 3.77 191.33 0.837

MILL_OFF_R5_000818.LAB 3/31/2010 14:16:27 60.9 16.48 3.75 191.36 0.837

MILL_OFF_R5_000819.LAB 3/31/2010 14:17:26 61.2 16.35 3.75 191.39 0.836

MILL_OFF_R5_000820.LAB 3/31/2010 14:18:25 60.8 16.25 3.73 191.38 0.837

MILL_OFF_R5_000821.LAB 3/31/2010 14:19:24 61.9 16.65 3.78 191.39 0.837

MILL_OFF_R5_000822.LAB 3/31/2010 14:20:23 61.1 16.41 3.76 191.42 0.836

MILL_OFF_R5_000823.LAB 3/31/2010 14:21:21 60.8 16.42 3.76 191.47 0.836

MILL_OFF_R5_000824.LAB 3/31/2010 14:22:20 62.2 16.56 3.78 191.39 0.836

MILL_OFF_R5_000825.LAB 3/31/2010 14:23:19 62.4 16.65 3.77 191.37 0.836

MILL_OFF_R5_000826.LAB 3/31/2010 14:24:18 62.6 16.56 3.78 191.35 0.836

MILL_OFF_R5_000827.LAB 3/31/2010 14:25:17 63.6 16.84 3.89 191.38 0.836

MILL_OFF_R5_000828.LAB 3/31/2010 14:26:15 61.9 16.46 3.75 191.39 0.836

MILL_OFF_R5_000829.LAB 3/31/2010 14:27:14 61.8 16.83 3.74 191.39 0.837

MILL_OFF_R5_000830.LAB 3/31/2010 14:28:13 61.3 16.52 3.72 191.47 0.838

Prj. # 1663
Cal Portland Cement Company, Mojave, CA ‐ Test Run #5 ‐ FTIR Data

FTIR Spectrum Date Time

HCL           

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

FTIR Gas Cell

Temp (C)

FTIR Gas Cell

Pressure (Atm)

MILL_OFF_R5_000831.LAB 3/31/2010 14:29:12 61.1 16.53 3.73 191.40 0.838

MILL_OFF_R5_000832.LAB 3/31/2010 14:30:10 61.4 16.46 3.69 191.44 0.838

MILL_OFF_R5_000833.LAB 3/31/2010 14:31:09 61.6 16.64 3.67 191.48 0.838

MILL_OFF_R5_000834.LAB 3/31/2010 14:32:08 61.8 16.68 3.68 191.41 0.837

MILL_OFF_R5_000835.LAB 3/31/2010 14:33:07 61.9 16.77 3.74 191.46 0.837

MILL_OFF_R5_000836.LAB 3/31/2010 14:34:06 62.5 16.70 3.72 191.40 0.836

MILL_OFF_R5_000837.LAB 3/31/2010 14:35:05 63.4 16.88 3.73 191.39 0.836

MILL_OFF_R5_000838.LAB 3/31/2010 14:36:03 63.1 16.91 3.73 191.36 0.836

Minimum 55.2 14.5 3.5

Maximum 86.5 16.9 6.8

Average 66.8 15.9 4.5

Prj. # 1663
Cal Portland Cement Company, Mojave, CA ‐ Test Run #6 ‐ FTIR Data

FTIR Spectrum Date Time

HCL           

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

FTIR Gas Cell

Temp (C)

FTIR Gas Cell

Pressure (Atm)

MILL_OFF_R6_000858.LAB 3/31/2010 14:54:52 64.1 17.99 3.96 191.39 0.837

MILL_OFF_R6_000859.LAB 3/31/2010 14:55:51 63.8 17.80 3.93 191.37 0.837

MILL_OFF_R6_000860.LAB 3/31/2010 14:56:50 64.3 17.86 3.95 191.39 0.837

MILL_OFF_R6_000861.LAB 3/31/2010 14:57:49 64.9 17.83 3.92 191.37 0.837

MILL_OFF_R6_000862.LAB 3/31/2010 14:58:48 65.2 18.02 3.95 191.36 0.837

MILL_OFF_R6_000863.LAB 3/31/2010 14:59:46 64.4 17.97 3.94 191.35 0.836

MILL_OFF_R6_000864.LAB 3/31/2010 15:00:45 64.9 18.15 3.97 191.36 0.836

MILL_OFF_R6_000865.LAB 3/31/2010 15:01:44 64.9 18.11 3.96 191.39 0.836

MILL_OFF_R6_000866.LAB 3/31/2010 15:02:43 66.4 18.46 4.05 191.42 0.836

MILL_OFF_R6_000867.LAB 3/31/2010 15:03:42 66.1 18.53 4.03 191.46 0.836

MILL_OFF_R6_000868.LAB 3/31/2010 15:04:40 66.6 18.67 4.05 191.45 0.836

MILL_OFF_R6_000869.LAB 3/31/2010 15:05:39 65.0 18.37 3.98 191.45 0.836

MILL_OFF_R6_000870.LAB 3/31/2010 15:06:38 66.6 18.60 4.04 191.38 0.836

MILL_OFF_R6_000871.LAB 3/31/2010 15:07:37 65.3 18.26 3.95 191.36 0.836

MILL_OFF_R6_000872.LAB 3/31/2010 15:08:36 65.9 18.63 4.05 191.36 0.836

MILL_OFF_R6_000873.LAB 3/31/2010 15:09:34 66.6 18.66 4.05 191.36 0.836

MILL_OFF_R6_000874.LAB 3/31/2010 15:10:33 67.5 18.81 4.10 191.37 0.836

MILL_OFF_R6_000875.LAB 3/31/2010 15:11:32 65.3 18.34 3.99 191.38 0.836

MILL_OFF_R6_000876.LAB 3/31/2010 15:12:31 66.3 18.64 4.04 191.38 0.836

MILL_OFF_R6_000877.LAB 3/31/2010 15:13:30 65.9 18.41 3.99 191.42 0.836

MILL_OFF_R6_000878.LAB 3/31/2010 15:14:28 66.3 18.47 4.05 191.41 0.836

MILL_OFF_R6_000879.LAB 3/31/2010 15:15:27 66.1 18.50 4.01 191.37 0.836

MILL_OFF_R6_000880.LAB 3/31/2010 15:16:26 65.9 18.44 4.02 191.39 0.836

MILL_OFF_R6_000881.LAB 3/31/2010 15:17:25 65.8 18.45 4.03 191.39 0.836

MILL_OFF_R6_000882.LAB 3/31/2010 15:18:24 65.9 18.46 4.04 191.42 0.836

MILL_OFF_R6_000883.LAB 3/31/2010 15:19:22 66.0 18.38 4.02 191.40 0.836

MILL_OFF_R6_000884.LAB 3/31/2010 15:20:21 66.3 18.66 4.06 191.41 0.836

MILL_OFF_R6_000885.LAB 3/31/2010 15:21:20 66.3 18.51 4.03 191.43 0.837

MILL OFF R6 000886 LAB MILL_OFF_R6_000886.LAB 3/31/2010 3/31/2010 15:22:19 15:22:19 66 3. 18 51 . 3 99 . 191 39 . 0 836 .

MILL_OFF_R6_000887.LAB 3/31/2010 15:23:18 66.6 18.39 3.99 191.39 0.838

MILL_OFF_R6_000888.LAB 3/31/2010 15:24:17 67.2 18.78 4.04 191.37 0.838

MILL_OFF_R6_000889.LAB 3/31/2010 15:25:15 67.9 18.96 4.08 191.38 0.837

MILL_OFF_R6_000890.LAB 3/31/2010 15:26:14 67.9 18.88 4.11 191.37 0.837

MILL_OFF_R6_000891.LAB 3/31/2010 15:27:13 67.9 18.95 4.11 191.38 0.837

MILL_OFF_R6_000892.LAB 3/31/2010 15:28:12 68.4 19.11 4.12 191.37 0.837

MILL_OFF_R6_000893.LAB 3/31/2010 15:29:11 68.4 19.11 4.14 191.37 0.837

MILL_OFF_R6_000894.LAB 3/31/2010 15:30:09 68.2 19.03 4.14 191.37 0.837

MILL_OFF_R6_000895.LAB 3/31/2010 15:31:08 68.9 18.85 4.13 191.36 0.837

MILL_OFF_R6_000896.LAB 3/31/2010 15:32:07 69.4 19.22 4.22 191.36 0.837

MILL_OFF_R6_000897.LAB 3/31/2010 15:33:06 69.2 19.13 4.26 191.38 0.837

MILL_OFF_R6_000898.LAB 3/31/2010 15:34:05 69.3 19.08 4.26 191.39 0.837

MILL_OFF_R6_000899.LAB 3/31/2010 15:35:03 69.8 19.19 4.26 191.40 0.836

MILL_OFF_R6_000900.LAB 3/31/2010 15:36:02 71.6 19.69 4.34 191.42 0.836

MILL_OFF_R6_000901.LAB 3/31/2010 15:37:01 70.2 19.35 4.29 191.40 0.836

MILL_OFF_R6_000902.LAB 3/31/2010 15:38:00 70.6 19.44 4.30 191.36 0.836

MILL_OFF_R6_000903.LAB 3/31/2010 15:38:59 70.9 19.38 4.33 191.36 0.835

MILL_OFF_R6_000904.LAB 3/31/2010 15:39:57 71.8 19.77 4.34 191.35 0.836

MILL_OFF_R6_000905.LAB 3/31/2010 15:40:56 70.2 19.52 4.29 191.35 0.836

MILL_OFF_R6_000906.LAB 3/31/2010 15:41:55 70.6 19.83 4.33 191.36 0.836

MILL_OFF_R6_000907.LAB 3/31/2010 15:42:54 71.2 19.79 4.30 191.37 0.836

MILL_OFF_R6_000908.LAB 3/31/2010 15:43:53 72.6 20.07 4.34 191.36 0.836

MILL_OFF_R6_000909.LAB 3/31/2010 15:44:51 70.3 19.52 4.22 191.37 0.836

MILL_OFF_R6_000910.LAB 3/31/2010 15:45:50 69.8 19.54 4.22 191.36 0.836

MILL_OFF_R6_000911.LAB 3/31/2010 15:46:49 71.7 19.88 4.27 191.39 0.836

Prj. # 1663
Cal Portland Cement Company, Mojave, CA ‐ Test Run #6 ‐ FTIR Data

FTIR Spectrum Date Time

HCL           

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

FTIR Gas Cell

Temp (C)

FTIR Gas Cell

Pressure (Atm)

MILL_OFF_R6_000912.LAB 3/31/2010 15:47:48 72.7 20.03 4.29 191.37 0.836

MILL_OFF_R6_000913.LAB 3/31/2010 15:48:47 72.2 19.78 4.20 191.40 0.838

MILL_OFF_R6_000914.LAB 3/31/2010 15:49:46 71.7 19.66 4.21 191.37 0.837

MILL_OFF_R6_000915.LAB 3/31/2010 15:50:44 70.5 19.67 4.17 191.37 0.837

MILL_OFF_R6_000916.LAB 3/31/2010 15:51:43 72.2 19.84 4.20 191.38 0.837

MILL_OFF_R6_000917.LAB 3/31/2010 15:52:42 71.4 19.83 4.18 191.37 0.832

MILL_OFF_R6_000918.LAB 3/31/2010 15:53:41 71.6 19.90 4.23 191.35 0.831

MILL_OFF_R6_000919.LAB 3/31/2010 15:54:40 71.1 20.14 4.28 191.36 0.830

Minimum 63.8 17.8 3.9

Maximum 72.7 20.1 4.3

Average 68.1 18.9 4.1

Prj. # 1663
APPENDIX 

Main Stack FTIR QA/QC Data 

 
Cal Portland Cement Company, Mojave, CA ‐ FTIR QAQC Data

Prj. # 1663Prj. 1663

100 0 CTS SYS RT 000043 LAB 3/30/2010 9:20:18 < < 87 1 87 1% 12

Nitrogen Direct

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

N2_DIR_000002BKG.LAB 3/30/2010 8:58:18 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5

N2_DIR_000003.LAB 3/30/2010 8:58:28 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5

N2_DIR_000004.LAB 3/30/2010 8:58:36 < 0.2 0.02 < 0.01 < 0.01 < 0.5

CTS, 100.0 ppm Ethylene Direct Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

Ethylene

Recovery (%)

100.0_CTS_DIR_000020.LAB 3/30/2010 9:03:54 < 0.2 < 0.01 < 0.01 < 0.01 99.3 99.3%

100.0_CTS_DIR_000021.LAB 3/30/2010 9:04:01 < 0.2 < 0.01 < 0.01 < 0.01 99.5 99.5%

100.0_CTS_DIR_000022.LAB 3/30/2010 9:04:09 < 0.2 0.03 < 0.01 < 0.01 99.4 99.4%

100.0_CTS_DIR_000023.LAB 3/30/2010 9:04:17 < 0.2 0.02 < 0.01 < 0.01 99.6 99.6%

100.0_CTS_DIR_000024.LAB 3/30/2010 9:04:25 < 0.2 0.01 < 0.01 < 0.01 99.4 99.4%

100.0_CTS_DIR_000025.LAB 3/30/2010 9:04:33 < 0.2 0.03 < 0.01 < 0.01 99.8 99.8%

181.1 ppm HCl / 3.88 ppm SF6 Direct Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

HCl Recovery

(%)

181.1_HCL_DIR_000036.LAB 3/30/2010 9:10:41 177.9 0.02 0.03 3.88 < 0.5 98.2%

181.1_HCL_DIR_000037.LAB 3/30/2010 9:10:49 178.4 0.03 < 0.01 3.89 < 0.5 98.5%

181.1_HCL_DIR_000038.LAB 3/30/2010 9:10:57 178.3 0.02 < 0.01 3.89 < 0.5 98.5%

181.1_HCL_DIR_000039.LAB 3/30/2010 9:11:05 178.1 < 0.01 0.03 3.89 < 0.5 98.4%

181.1_HCL_DIR_000040.LAB 3/30/2010 9:11:13 178.3 0.03 < 0.01 3.89 < 0.5 98.5%

CTS, 100.0 ppm Ethylene System Purge and Response Time Test

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

Ethylene

Recovery (%)

Response

Time* (sec)

100.0_CTS_SYS_RT_000041.LAB 3/30/2010 9:20:10 0.2 0.04 0.95 < 0.01 < 0.5 0.0% 4

100.0_CTS_SYS_RT_000042.LAB 3/30/2010 9:20:14 0.4 0.03 0.78 < 0.01 19.2 19.2% 8

100. _ _ _ _ . 0 CTS SYS RT 000043 LAB 3/30/2010 9:20:18 < 0 2. 0 0.4 0 1.3 < 0 0.1 87.1 87.1% 12

100.0_CTS_SYS_RT_000044.LAB 3/30/2010 9:20:22 < 0.2 < 0.01 0.04 < 0.01 96.8 96.8% 16

100.0_CTS_SYS_RT_000045.LAB 3/30/2010 9:20:26 < 0.2 < 0.01 0.03 < 0.01 97.6 97.6%

100.0_CTS_SYS_RT_000046.LAB 3/30/2010 9:20:30 < 0.2 0.03 0.02 < 0.01 97.7 97.7%

100.0_CTS_SYS_RT_000047.LAB 3/30/2010 9:20:34 < 0.2 < 0.01 < 0.01 < 0.01 98.3 98.3%

100.0_CTS_SYS_RT_000048.LAB 3/30/2010 9:20:38 < 0.2 < 0.01 0.02 < 0.01 98.2 98.2%

100.0_CTS_SYS_RT_000049.LAB 3/30/2010 9:20:41 < 0.2 0.02 < 0.01 < 0.01 97.9 97.9%

100.0_CTS_SYS_RT_000050.LAB 3/30/2010 9:20:45 < 0.2 < 0.01 < 0.01 < 0.01 97.9 97.9%

100.0_CTS_SYS_RT_000051.LAB 3/30/2010 9:20:50 < 0.2 < 0.01 < 0.01 < 0.01 98.3 98.3%

* Response Time = Time to recovery 95% of calibration gas delivered through the sampling system

Nitrogen System Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

N2_SYS_000052.LAB 3/30/2010 9:22:40 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5

N2_SYS_000053.LAB 3/30/2010 9:22:56 < 0.2 0.01 0.02 < 0.01 < 0.5

N2_SYS_000054.LAB 3/30/2010 9:23:11 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5

N2_SYS_000055.LAB 3/30/2010 9:28:41 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5
Cal Portland Cement Company, Mojave, CA ‐ FTIR QAQC Data

Prj. # 1663Prj. 1663

49 9 HCL SYS RT 000080 LAB 3/30/2010 50 40 8 < 82 3% 90

Main Stack Effluent, Mill On

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

MILL_ON_000056.LAB 3/30/2010 9:41:43 4.0 17.78 8.52 < 0.01 0.7

MILL_ON_000057.LAB 3/30/2010 9:42:14 4.3 17.67 8.47 < 0.01 0.7

MILL_ON_000058.LAB 3/30/2010 9:42:46 4.3 17.78 8.48 < 0.01 0.7

MILL_ON_000059.LAB 3/30/2010 9:43:17 4.4 17.67 8.55 < 0.01 0.7

MILL_ON_000060.LAB 3/30/2010 9:43:48 4.5 17.65 8.52 < 0.01 0.8

MILL_ON_000061.LAB 3/30/2010 9:44:20 4.7 17.63 8.52 < 0.01 0.8

MILL_ON_000062.LAB 3/30/2010 9:44:51 4.7 17.76 8.55 < 0.01 0.8

MILL_ON_000063.LAB 3/30/2010 9:45:22 4.8 17.80 8.69 < 0.01 0.6

MILL_ON_000064.LAB 3/30/2010 9:45:54 4.9 17.73 8.62 < 0.01 0.8

MILL_ON_000065.LAB 3/30/2010 9:46:25 4.8 17.78 8.55 < 0.01 0.8

MILL_ON_000066.LAB 3/30/2010 9:46:56 4.8 17.75 8.58 < 0.01 0.7

MILL_ON_000067.LAB 3/30/2010 9:47:28 4.9 17.87 8.65 < 0.01 0.7

MILL_ON_000068.LAB 3/30/2010 9:47:59 5.0 17.69 8.64 < 0.01 0.8

181.1 ppm HCl / 3.88 ppm SF6 System Purge & Response Time Test

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

HCl Recovery

(%)

Response

Time* (sec)

49.9_HCL_SYS_RT_000069.LAB 3/30/2010 9:49:05 11.4 15.90 7.84 0.29 0.5 22.9% 4

49.9_HCL_SYS_RT_000070.LAB 3/30/2010 9:49:13 11.2 1.15 0.63 3.53 < 0.5 22.6% 12

49.9_HCL_SYS_RT_000071.LAB 3/30/2010 9:49:21 23.2 0.08 0.09 3.77 < 0.5 46.8% 20

49.9_HCL_SYS_RT_000072.LAB 3/30/2010 9:49:29 29.5 0.05 0.04 3.78 < 0.5 59.5% 28

49.9_HCL_SYS_RT_000073.LAB 3/30/2010 9:49:36 33.1 0.05 0.04 3.79 < 0.5 66.8% 35

49.9_HCL_SYS_RT_000074.LAB 3/30/2010 9:49:44 35.2 0.02 0.02 3.80 < 0.5 71.0% 43

49.9_HCL_SYS_RT_000075.LAB 3/30/2010 9:49:52 36.7 0.04 0.02 3.80 < 0.5 74.0% 51

49.9_HCL_SYS_RT_000076.LAB 3/30/2010 9:50:00 38.0 0.02 0.03 3.79 < 0.5 76.6% 59

49.9_HCL_SYS_RT_000077.LAB 3/30/2010 9:50:08 39.0 0.02 0.05 3.79 < 0.5 78.6% 67

49.9_HCL_SYS_RT_000078.LAB 3/30/2010 9:50:16 39.7 < 0.01 0.04 3.79 < 0.5 80.2% 75

49.9_HCL_SYS_RT_000079.LAB 3/30/2010 9:50:24 40.1 0.02 0.03 3.79 < 0.5 81.0% 82

49. _ _ _ _ . 9 HCL SYS RT 000080 LAB 3/30/2010 9:50:31 9: 40.8 0 0.1 0 0.5 3 7.9 < 0 5. 82.3% 90

49.9_HCL_SYS_RT_000081.LAB 3/30/2010 9:50:39 41.1 0.02 < 0.01 3.79 < 0.5 83.0% 98

49.9_HCL_SYS_RT_000082.LAB 3/30/2010 9:50:47 41.6 0.04 0.02 3.79 < 0.5 83.9% 106

49.9_HCL_SYS_RT_000083.LAB 3/30/2010 9:50:55 41.9 0.01 0.02 3.80 < 0.5 84.6% 114

49.9_HCL_SYS_RT_000084.LAB 3/30/2010 9:51:03 42.4 < 0.01 0.02 3.80 < 0.5 85.6% 122

49.9_HCL_SYS_RT_000085.LAB 3/30/2010 9:51:11 42.8 0.01 0.02 3.80 < 0.5 86.3% 129

49.9_HCL_SYS_RT_000086.LAB 3/30/2010 9:51:18 43.0 0.03 0.02 3.80 < 0.5 86.7% 137

49.9_HCL_SYS_RT_000087.LAB 3/30/2010 9:51:26 43.1 < 0.01 < 0.01 3.80 < 0.5 87.0% 145

49.9_HCL_SYS_RT_000088.LAB 3/30/2010 9:51:34 43.5 0.02 0.03 3.80 < 0.5 87.7% 153

49.9_HCL_SYS_RT_000089.LAB 3/30/2010 9:51:42 43.3 0.01 0.01 3.80 < 0.5 87.3% 161

49.9_HCL_SYS_RT_000090.LAB 3/30/2010 9:51:50 43.4 0.04 0.04 3.80 < 0.5 87.6% 169

49.9_HCL_SYS_RT_000091.LAB 3/30/2010 9:51:58 43.5 0.03 0.02 3.79 < 0.5 87.8% 176

49.9_HCL_SYS_RT_000092.LAB 3/30/2010 9:52:05 43.7 0.01 0.02 3.79 < 0.5 88.2% 184

49.9_HCL_SYS_RT_000093.LAB 3/30/2010 9:52:13 43.9 < 0.01 < 0.01 3.79 < 0.5 88.5% 192

49.9_HCL_SYS_RT_000094.LAB 3/30/2010 9:52:21 44.0 0.03 0.01 3.79 < 0.5 88.8% 200

49.9_HCL_SYS_RT_000095.LAB 3/30/2010 9:52:29 44.0 < 0.01 0.05 3.79 < 0.5 88.9% 208

49.9_HCL_SYS_RT_000096.LAB 3/30/2010 9:52:37 44.3 < 0.01 < 0.01 3.79 < 0.5 89.4% 216

49.9_HCL_SYS_RT_000097.LAB 3/30/2010 9:52:45 44.3 < 0.01 0.02 3.79 < 0.5 89.4% 223

49.9_HCL_SYS_RT_000098.LAB 3/30/2010 9:52:52 44.2 < 0.01 0.02 3.79 < 0.5 89.2% 231

49.9_HCL_SYS_RT_000099.LAB 3/30/2010 9:53:00 44.6 < 0.01 0.02 3.79 < 0.5 89.9% 239

49.9_HCL_SYS_RT_000100.LAB 3/30/2010 9:53:08 44.4 0.01 0.03 3.79 < 0.5 89.7% 247

49.9_HCL_SYS_RT_000101.LAB 3/30/2010 9:53:16 44.6 0.02 0.02 3.79 < 0.5 89.9% 255

49.9_HCL_SYS_RT_000102.LAB 3/30/2010 9:53:24 44.7 0.02 < 0.01 3.80 < 0.5 90.2% 263

49.9_HCL_SYS_RT_000103.LAB 3/30/2010 9:53:32 44.8 < 0.01 < 0.01 3.79 < 0.5 90.5% 270

49.9_HCL_SYS_RT_000104.LAB 3/30/2010 9:53:39 44.9 < 0.01 < 0.01 3.79 < 0.5 90.5% 278

49.9_HCL_SYS_RT_000105.LAB 3/30/2010 9:53:48 44.9 0.02 0.01 3.80 < 0.5 90.7% 287

49.9_HCL_SYS_RT_000106.LAB 3/30/2010 9:53:55 45.1 0.01 < 0.01 3.80 < 0.5 91.0% 294

49.9_HCL_SYS_RT_000107.LAB 3/30/2010 9:54:03 45.2 < 0.01 0.01 3.79 < 0.5 91.1% 302
Cal Portland Cement Company, Mojave, CA ‐ FTIR QAQC Data

Prj. # 1663Prj. 1663

49 9 HCL SYS RT 000136 LAB 3/30/2010 57 46 1 < 93 1% 529

181.1 ppm HCl / 3.88 ppm SF6 System Purge & Response Time Test, Continued

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

HCl Recovery

(%)

Response

Time* (sec)

49.9_HCL_SYS_RT_000108.LAB 3/30/2010 9:54:11 45.0 0.02 0.03 3.80 < 0.5 90.8% 310

49.9_HCL_SYS_RT_000109.LAB 3/30/2010 9:54:19 45.2 0.02 0.02 3.79 < 0.5 91.2% 317

49.9_HCL_SYS_RT_000110.LAB 3/30/2010 9:54:26 45.2 0.01 0.03 3.80 < 0.5 91.2% 325

49.9_HCL_SYS_RT_000111.LAB 3/30/2010 9:54:34 45.6 < 0.01 < 0.01 3.80 < 0.5 92.0% 333

49.9_HCL_SYS_RT_000112.LAB 3/30/2010 9:54:42 45.3 0.02 < 0.01 3.80 < 0.5 91.4% 341

49.9_HCL_SYS_RT_000113.LAB 3/30/2010 9:54:50 45.5 < 0.01 0.01 3.79 < 0.5 91.9% 349

49.9_HCL_SYS_RT_000114.LAB 3/30/2010 9:54:58 45.4 < 0.01 0.02 3.79 < 0.5 91.6% 357

49.9_HCL_SYS_RT_000115.LAB 3/30/2010 9:55:06 45.5 < 0.01 0.03 3.79 < 0.5 91.9% 365

49.9_HCL_SYS_RT_000116.LAB 3/30/2010 9:55:14 45.8 < 0.01 0.02 3.80 < 0.5 92.5% 372

49.9_HCL_SYS_RT_000117.LAB 3/30/2010 9:55:21 45.7 < 0.01 < 0.01 3.79 < 0.5 92.1% 380

49.9_HCL_SYS_RT_000118.LAB 3/30/2010 9:55:29 45.9 0.01 0.02 3.79 < 0.5 92.6% 388

49.9_HCL_SYS_RT_000119.LAB 3/30/2010 9:55:37 45.7 0.01 0.03 3.79 < 0.5 92.2% 396

49.9_HCL_SYS_RT_000120.LAB 3/30/2010 9:55:45 45.7 0.01 < 0.01 3.79 < 0.5 92.1% 404

49.9_HCL_SYS_RT_000121.LAB 3/30/2010 9:55:53 45.6 < 0.01 < 0.01 3.80 < 0.5 92.0% 412

49.9_HCL_SYS_RT_000122.LAB 3/30/2010 9:56:01 45.8 < 0.01 0.02 3.80 < 0.5 92.4% 419

49.9_HCL_SYS_RT_000123.LAB 3/30/2010 9:56:08 45.7 0.03 0.03 3.79 < 0.5 92.3% 427

49.9_HCL_SYS_RT_000124.LAB 3/30/2010 9:56:16 45.9 0.02 < 0.01 3.79 < 0.5 92.6% 435

49.9_HCL_SYS_RT_000125.LAB 3/30/2010 9:56:24 46.1 0.01 < 0.01 3.79 < 0.5 93.0% 443

49.9_HCL_SYS_RT_000126.LAB 3/30/2010 9:56:32 46.0 0.02 < 0.01 3.80 < 0.5 92.8% 451

49.9_HCL_SYS_RT_000127.LAB 3/30/2010 9:56:40 45.9 0.02 0.01 3.80 < 0.5 92.7% 459

49.9_HCL_SYS_RT_000128.LAB 3/30/2010 9:56:48 46.0 < 0.01 0.03 3.80 < 0.5 92.9% 466

49.9_HCL_SYS_RT_000129.LAB 3/30/2010 9:56:56 46.0 < 0.01 0.01 3.79 < 0.5 92.7% 474

49.9_HCL_SYS_RT_000130.LAB 3/30/2010 9:57:03 45.9 < 0.01 0.01 3.79 < 0.5 92.6% 482

49.9_HCL_SYS_RT_000131.LAB 3/30/2010 9:57:11 45.9 0.03 0.03 3.80 < 0.5 92.5% 490

49.9_HCL_SYS_RT_000132.LAB 3/30/2010 9:57:19 46.0 < 0.01 < 0.01 3.80 < 0.5 92.8% 498

49.9_HCL_SYS_RT_000133.LAB 3/30/2010 9:57:27 45.9 0.02 0.03 3.79 < 0.5 92.7% 506

49.9_HCL_SYS_RT_000134.LAB 3/30/2010 9:57:35 46.0 0.02 0.04 3.80 < 0.5 92.9% 513

49.9_HCL_SYS_RT_000135.LAB 3/30/2010 9:57:42 45.9 < 0.01 0.01 3.79 < 0.5 92.6% 521

49. _ _ _ _ . 9 HCL SYS RT 000136 LAB 3/30/2010 9:57:50 9: 46.1 0 0.1 0 0.2 3 7.9 < 0 5. 93.1% 529

49.9_HCL_SYS_RT_000137.LAB 3/30/2010 9:57:58 46.2 < 0.01 0.03 3.79 < 0.5 93.2% 537

49.9_HCL_SYS_RT_000138.LAB 3/30/2010 9:58:06 46.2 0.03 0.03 3.80 < 0.5 93.3% 545

49.9_HCL_SYS_RT_000139.LAB 3/30/2010 9:58:14 46.0 < 0.01 0.02 3.79 < 0.5 92.8% 553

49.9_HCL_SYS_RT_000140.LAB 3/30/2010 9:58:22 46.3 0.03 < 0.01 3.80 < 0.5 93.5% 561

49.9_HCL_SYS_RT_000141.LAB 3/30/2010 9:58:29 46.3 < 0.01 0.01 3.79 < 0.5 93.3% 568

49.9_HCL_SYS_RT_000142.LAB 3/30/2010 9:58:37 46.2 0.03 0.02 3.79 < 0.5 93.3% 576

49.9_HCL_SYS_RT_000143.LAB 3/30/2010 9:58:45 46.4 0.02 < 0.01 3.80 < 0.5 93.6% 584

49.9_HCL_SYS_RT_000144.LAB 3/30/2010 9:58:53 46.0 0.03 0.01 3.80 < 0.5 92.9% 592

49.9_HCL_SYS_RT_000145.LAB 3/30/2010 9:59:01 46.3 < 0.01 0.03 3.80 < 0.5 93.4% 600

49.9_HCL_SYS_RT_000146.LAB 3/30/2010 9:59:09 46.2 < 0.01 0.02 3.79 < 0.5 93.2% 608

49.9_HCL_SYS_RT_000147.LAB 3/30/2010 9:59:17 46.3 0.02 0.01 3.79 < 0.5 93.4% 615

49.9_HCL_SYS_RT_000148.LAB 3/30/2010 9:59:24 46.3 < 0.01 0.04 3.80 < 0.5 93.5% 623

49.9_HCL_SYS_RT_000149.LAB 3/30/2010 9:59:32 46.4 0.01 < 0.01 3.80 < 0.5 93.6% 631

49.9_HCL_SYS_RT_000150.LAB 3/30/2010 9:59:40 46.5 < 0.01 0.06 3.79 < 0.5 93.8% 639

49.9_HCL_SYS_RT_000151.LAB 3/30/2010 9:59:48 46.5 < 0.01 0.02 3.79 < 0.5 93.7% 647

49.9_HCL_SYS_RT_000152.LAB 3/30/2010 9:59:56 46.5 0.01 < 0.01 3.80 < 0.5 93.8% 655

49.9_HCL_SYS_RT_000153.LAB 3/30/2010 10:00:04 46.5 0.02 0.02 3.80 < 0.5 93.8% 662

49.9_HCL_SYS_RT_000154.LAB 3/30/2010 10:00:11 46.6 0.02 < 0.01 3.79 < 0.5 93.9% 670

49.9_HCL_SYS_RT_000155.LAB 3/30/2010 10:00:19 46.5 < 0.01 0.02 3.80 < 0.5 93.8% 678

49.9_HCL_SYS_RT_000156.LAB 3/30/2010 10:00:27 46.6 0.01 0.02 3.80 < 0.5 93.9% 686

49.9_HCL_SYS_RT_000157.LAB 3/30/2010 10:00:35 46.4 0.02 0.02 3.80 < 0.5 93.7% 694

49.9_HCL_SYS_RT_000158.LAB 3/30/2010 10:00:43 46.4 < 0.01 < 0.01 3.79 < 0.5 93.7% 702

49.9_HCL_SYS_RT_000159.LAB 3/30/2010 10:00:51 46.6 0.02 0.04 3.79 < 0.5 94.1% 709

49.9_HCL_SYS_RT_000160.LAB 3/30/2010 10:00:58 46.7 < 0.01 < 0.01 3.80 < 0.5 94.3% 717

49.9_HCL_SYS_RT_000161.LAB 3/30/2010 10:01:06 46.6 < 0.01 0.03 3.79 < 0.5 93.9% 725

49.9_HCL_SYS_RT_000162.LAB 3/30/2010 10:01:14 46.7 < 0.01 0.03 3.80 < 0.5 94.3% 733

49.9_HCL_SYS_RT_000163.LAB 3/30/2010 10:01:22 46.6 0.03 < 0.01 3.79 < 0.5 93.9% 741
Cal Portland Cement Company, Mojave, CA ‐ FTIR QAQC Data

Prj. # 1663Prj. 1663

49 9 HCL SYS RT 000192 LAB 3/30/2010 10 09 48 1 < < 97 1%

181.1 ppm HCl / 3.88 ppm SF6 System Purge & Response Time Test, Continued

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

HCl Recovery

(%)

Response

Time* (sec)

49.9_HCL_SYS_RT_000164.LAB 3/30/2010 10:01:30 46.8 0.01 0.02 3.80 < 0.5 94.4% 749

49.9_HCL_SYS_RT_000165.LAB 3/30/2010 10:01:38 46.6 < 0.01 < 0.01 3.79 < 0.5 94.1% 756

49.9_HCL_SYS_RT_000166.LAB 3/30/2010 10:01:45 46.8 < 0.01 0.04 3.79 < 0.5 94.3% 764

49.9_HCL_SYS_RT_000167.LAB 3/30/2010 10:01:53 46.6 0.03 < 0.01 3.80 < 0.5 94.0% 772

49.9_HCL_SYS_RT_000168.LAB 3/30/2010 10:02:01 46.6 0.02 0.03 3.79 < 0.5 94.0% 780

49.9_HCL_SYS_RT_000169.LAB 3/30/2010 10:02:09 46.7 < 0.01 0.01 3.79 < 0.5 94.2% 788

49.9_HCL_SYS_RT_000170.LAB 3/30/2010 10:02:17 46.8 0.01 < 0.01 3.79 < 0.5 94.5% 796

49.9_HCL_SYS_RT_000171.LAB 3/30/2010 10:02:25 46.6 < 0.01 < 0.01 3.79 < 0.5 94.0% 803

49.9_HCL_SYS_RT_000172.LAB 3/30/2010 10:02:32 46.7 < 0.01 0.03 3.79 < 0.5 94.2% 811

49.9_HCL_SYS_RT_000173.LAB 3/30/2010 10:02:40 46.8 0.01 < 0.01 3.79 < 0.5 94.5% 819

49.9_HCL_SYS_RT_000174.LAB 3/30/2010 10:02:48 46.5 < 0.01 0.02 3.80 < 0.5 93.9% 827

49.9_HCL_SYS_RT_000175.LAB 3/30/2010 10:02:56 46.8 0.02 0.02 3.80 < 0.5 94.5% 835

49.9_HCL_SYS_RT_000176.LAB 3/30/2010 10:03:04 46.9 0.03 0.04 3.80 < 0.5 94.7% 843

49.9_HCL_SYS_RT_000177.LAB 3/30/2010 10:03:12 47.0 0.01 < 0.01 3.80 < 0.5 94.8% 850

49.9_HCL_SYS_RT_000178.LAB 3/30/2010 10:03:19 47.0 < 0.01 0.04 3.79 < 0.5 94.8% 858

49.9_HCL_SYS_RT_000179.LAB 3/30/2010 10:03:27 47.2 0.03 < 0.01 3.80 < 0.5 95.2% 866

49.9_HCL_SYS_RT_000180.LAB 3/30/2010 10:03:35 47.7 < 0.01 0.02 3.79 < 0.5 96.2%

49.9_HCL_SYS_RT_000181.LAB 3/30/2010 10:03:43 47.9 < 0.01 < 0.01 3.80 < 0.5 96.6%

49.9_HCL_SYS_RT_000182.LAB 3/30/2010 10:03:51 47.9 0.02 0.02 3.80 < 0.5 96.6%

49.9_HCL_SYS_RT_000183.LAB 3/30/2010 10:03:59 47.7 < 0.01 < 0.01 3.79 < 0.5 96.2%

49.9_HCL_SYS_RT_000184.LAB 3/30/2010 10:04:06 47.9 0.02 0.03 3.79 < 0.5 96.6%

49.9_HCL_SYS_RT_000185.LAB 3/30/2010 10:04:14 47.9 < 0.01 < 0.01 3.79 < 0.5 96.6%

49.9_HCL_SYS_RT_000186.LAB 3/30/2010 10:04:22 48.0 < 0.01 0.02 3.80 < 0.5 96.8%

49.9_HCL_SYS_RT_000187.LAB 3/30/2010 10:04:30 47.8 0.03 0.03 3.79 < 0.5 96.5%

49.9_HCL_SYS_RT_000188.LAB 3/30/2010 10:04:38 47.8 < 0.01 < 0.01 3.79 < 0.5 96.4%

49.9_HCL_SYS_RT_000189.LAB 3/30/2010 10:04:46 47.8 0.04 0.03 3.79 < 0.5 96.5%

49.9_HCL_SYS_RT_000190.LAB 3/30/2010 10:04:54 47.8 0.01 < 0.01 3.80 < 0.5 96.5%

49.9_HCL_SYS_RT_000191.LAB 3/30/2010 10:05:01 48.0 0.02 0.02 3.80 < 0.5 96.8%

49. _ _ _ _ . 9 HCL SYS RT 000192 LAB 3/30/2010 10:05:09 48.1 0 0.2 < 0 0.1 3 8.0 < 0 5. 97.1%

49.9_HCL_SYS_RT_000193.LAB 3/30/2010 10:05:17 48.0 < 0.01 0.02 3.79 < 0.5 96.8%

49.9_HCL_SYS_RT_000194.LAB 3/30/2010 10:05:25 48.1 0.02 < 0.01 3.79 < 0.5 97.0%

49.9_HCL_SYS_RT_000195.LAB 3/30/2010 10:05:33 48.0 0.01 < 0.01 3.79 < 0.5 96.9%

49.9_HCL_SYS_RT_000196.LAB 3/30/2010 10:05:41 47.9 < 0.01 0.03 3.80 < 0.5 96.7%

49.9_HCL_SYS_RT_000197.LAB 3/30/2010 10:05:49 47.8 0.02 0.03 3.80 < 0.5 96.5%

* Response Time = Time to recovery 95% of calibration gas delivered through the sampling system

Main Stack Effluent Prior to HCl Spike #1, Mill On

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

MILL_ON_000236.LAB 3/30/2010 10:17:56 6.3 17.66 9.30 < 0.01 0.7

MILL_ON_000237.LAB 3/30/2010 10:18:27 6.2 17.66 9.35 < 0.01 0.7

Average 6.3 < 0.01

HCl Spike #1 Using 49.56 ppm HCl / 3.80 ppm SF6

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

HCL_SPK1_MILL_ON_000257.LAB 3/30/2010 10:26:43 8.3 16.28 8.76 0.19 < 0.5

HCL_SPK1_MILL_ON_000258.LAB 3/30/2010 10:26:59 7.9 16.30 8.72 0.18 0.6

HCL_SPK1_MILL_ON_000259.LAB 3/30/2010 10:27:14 7.5 16.06 8.61 0.18 0.5

HCL_SPK1_MILL_ON_000260.LAB 3/30/2010 10:27:30 7.4 16.17 8.72 0.18 < 0.5

HCL_SPK1_MILL_ON_000261.LAB 3/30/2010 10:27:46 7.2 16.27 8.77 0.18 0.6

HCL_SPK1_MILL_ON_000262.LAB 3/30/2010 10:28:01 7.3 16.16 8.76 0.17 0.6

Average 7.6 0.18
Cal Portland Cement Company, Mojave, CA ‐ FTIR QAQC Data

Prj. # 1663Prj. 1663

Main Stack Effluent Post HCl Spike #1, Mill On

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

MILL_ON_000263.LAB 3/30/2010 10:28:57 6.2 17.37 9.42 < 0.01 0.7

MILL_ON_000264.LAB 3/30/2010 10:29:28 5.7 17.20 9.38 < 0.01 0.6

Average 5.9 < 0.01

Main Stack Effluent Prior to HCl Spike #2, Mill On

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

MILL_ON_R1_000326.LAB 3/30/2010 11:29:20 5.9 17.37 8.36 < 0.01 0.7

MILL_ON_R1_000327.LAB 3/30/2010 11:30:19 5.8 17.39 8.29 < 0.01 0.7

Average 5.9 < 0.01

HCl Spike #2 Using 49.56 ppm HCl / 3.80 ppm SF6

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

HCL_SPK2_MILL_ON_000344.LAB 3/30/2010 11:42:00 8.6 15.41 7.33 0.34 < 0.5

HCL_SPK2_MILL_ON_000345.LAB 3/30/2010 11:42:31 8.8 15.57 7.42 0.34 < 0.5

HCL_SPK2_MILL_ON_000346.LAB 3/30/2010 11:43:03 8.7 15.46 7.41 0.34 < 0.5

HCL_SPK2_MILL_ON_000347.LAB 3/30/2010 11:43:34 8.8 15.60 7.45 0.35 < 0.5

HCL_SPK2_MILL_ON_000348.LAB 3/30/2010 11:44:06 8.8 15.53 7.43 0.35 < 0.5

Average 8.8 0.34

Main Stack Effluent Post HCl Spike #2, Mill On

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

MILL_ON_000354.LAB 3/30/2010 11:50:43 5.8 17.32 8.54 < 0.01 0.7

MILL_ON_000355.LAB 3/30/2010 11:51:42 5.7 17.35 8.48 < 0.01 0.8

Average 5.8 < 0.01

Nitrogen Nitrogen System Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

N2_SYS_000356.LAB 3/30/2010 11:59:46 0.2 0.02 0.03 < 0.01 < 0.5

N2_SYS_000357.LAB 3/30/2010 12:00:02 < 0.2 0.02 0.02 < 0.01 < 0.5

N2_SYS_000358.LAB 3/30/2010 12:00:18 0.2 0.01 0.02 < 0.01 < 0.5

Main Stack Effluent Prior to HCl Spike #3, Mill On

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

MILL_ON_R2_000420.LAB 3/30/2010 13:05:29 6.5 17.50 8.06 < 0.01 0.7

MILL_ON_R2_000421.LAB 3/30/2010 13:06:27 6.9 17.54 8.13 < 0.01 0.6

Average 6.7 < 0.01

HCl Spike #3 Using 49.56 ppm HCl / 3.80 ppm SF6

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

HCL_SPK3_MILL_ON_000437.LAB 3/30/2010 13:16:57 8.3 16.54 7.71 0.15 < 0.5

HCL_SPK3_MILL_ON_000438.LAB 3/30/2010 13:17:28 8.4 16.69 7.87 0.13 < 0.5

HCL_SPK3_MILL_ON_000439.LAB 3/30/2010 13:18:00 7.9 16.95 7.89 0.11 0.6

HCL_SPK3_MILL_ON_000440.LAB 3/30/2010 13:18:31 7.9 16.57 7.76 0.16 < 0.5

HCL_SPK3_MILL_ON_000441.LAB 3/30/2010 13:19:02 7.8 16.48 7.72 0.15 < 0.5

HCL_SPK3_MILL_ON_000442.LAB 3/30/2010 13:19:34 7.6 16.53 7.70 0.15 < 0.5

Average 8.0 0.14
Cal Portland Cement Company, Mojave, CA ‐ FTIR QAQC Data

Prj. # 1663Prj. 1663

HCL SPK4 MILL ON 000551 15:01:17 1 16 53 28 6

Main Stack Effluent Post HCl Spike #3 Mill On

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

MILL_ON_000448.LAB 3/30/2010 13:25:57 6.4 17.62 8.18 < 0.01 0.8

MILL_ON_000449.LAB 3/30/2010 13:26:55 6.3 17.45 8.08 < 0.01 0.7

Average 6.3 < 0.01

Nitrogen System Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

N2_SYS_000450.LAB 3/30/2010 13:32:12 0.2 0.03 0.02 < 0.01 < 0.5

N2_SYS_000451.LAB 3/30/2010 13:32:28 0.2 0.02 0.02 < 0.01 < 0.5

N2_SYS_000452.LAB 3/30/2010 13:32:44 0.2 < 0.01 < 0.01 < 0.01 < 0.5

N2_SYS_000453.LAB 3/30/2010 13:32:59 < 0.2 0.02 0.04 < 0.01 < 0.5

N2_SYS_000454.LAB 3/30/2010 13:33:15 0.2 < 0.01 0.02 < 0.01 < 0.5

N2_SYS_000455.LAB 3/30/2010 13:33:31 < 0.2 < 0.01 0.02 < 0.01 < 0.5

Main Stack Effluent Prior to HCl Spike #4, Mill On

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

MILL_ON_R3_000517.LAB 3/30/2010 14:39:59 6.1 17.65 8.30 < 0.01 0.9

MILL_ON_R3_000518.LAB 3/30/2010 14:40:58 6.1 17.50 8.34 < 0.01 0.9

Average 6.1 < 0.01

HCl Spike #4 Using 49.56 ppm HCl / 3.80 ppm SF6

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

HCL_SPK4_MILL_ON_000547.LAB 3/30/2010 14:59:12 8.2 15.99 7.56 0.28 0.6

HCL_SPK4_MILL_ON_000548.LAB 3/30/2010 14:59:43 8.2 16.15 7.59 0.28 0.7

HCL_SPK4_MILL_ON_000549.LAB 3/30/2010 15:00:15 8.0 15.90 7.50 0.28 0.8

HCL_SPK4_MILL_ON_000550.LAB 3/30/2010 15:00:46 8.0 15.96 7.47 0.28 0.6

HCL SPK4 MILL ON 000551.LAB _ _ _ _ .LAB 3/30/2010 3/30/2010 15:01:17 8.1 16.02 7.53 0.28 0.6

Average 8.1 0.28

Nitrogen System Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

N2_SYS_000552.LAB 3/30/2010 15:07:32 0.3 < 0.01 < 0.01 < 0.01 < 0.5

N2_SYS_000553.LAB 3/30/2010 15:08:03 0.2 < 0.01 0.01 < 0.01 < 0.5

N2_SYS_000554.LAB 3/30/2010 15:08:34 < 0.2 0.02 0.02 < 0.01 < 0.5

CTS, 100.0 ppm Ethylene System Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

Ethylene

Recovery (%)

100.0_CTS_SYS_000555.LAB 3/30/2010 15:11:23 < 0.2 0.02 < 0.01 < 0.01 98.0 98.0%

100.0_CTS_SYS_000556.LAB 3/30/2010 15:11:31 < 0.2 0.02 < 0.01 < 0.01 98.4 98.4%

100.0_CTS_SYS_000557.LAB 3/30/2010 15:11:38 < 0.2 0.01 0.01 < 0.01 98.4 98.4%

100.0_CTS_SYS_000558.LAB 3/30/2010 15:11:46 < 0.2 < 0.01 0.01 < 0.01 98.2 98.2%

100.0_CTS_SYS_000559.LAB 3/30/2010 15:11:54 < 0.2 0.01 < 0.01 < 0.01 98.5 98.5%

100.0_CTS_SYS_000560.LAB 3/30/2010 15:12:02 < 0.2 0.01 0.03 < 0.01 98.3 98.3%

Nitrogen Direct

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

N2_DIR_000561.LAB 3/31/2010 6:25:30 < 0.2 0.01 0.01 < 0.01 < 0.5

N2_DIR_000562.LAB 3/31/2010 6:26:02 < 0.2 0.01 < 0.01 < 0.01 < 0.5

N2_DIR_000563.LAB 3/31/2010 6:26:33 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5

N2_DIR_000564BKG.LAB 3/31/2010 6:27:54 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5

N2_DIR_000565.LAB 3/31/2010 6:28:29 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5
Cal Portland Cement Company, Mojave, CA ‐ FTIR QAQC Data

Prj. # 1663Prj. 1663

HCL CO2 H2O SF6 Ethylene Ethylene Response

CTS, 100.0 ppm Ethylene Direct Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

Ethylene

Recovery (%)

100.0_CTS_DIR_000566.LAB 3/31/2010 6:30:59 < 0.2 < 0.01 < 0.01 < 0.01 98.5 98.5%

100.0_CTS_DIR_000567.LAB 3/31/2010 6:31:07 < 0.2 < 0.01 < 0.01 < 0.01 98.3 98.3%

100.0_CTS_DIR_000568.LAB 3/31/2010 6:31:15 < 0.2 < 0.01 < 0.01 < 0.01 98.4 98.4%

100.0_CTS_DIR_000569.LAB 3/31/2010 6:31:22 < 0.2 0.01 < 0.01 < 0.01 98.3 98.3%

100.0_CTS_DIR_000570.LAB 3/31/2010 6:31:30 < 0.2 < 0.01 < 0.01 < 0.01 97.9 97.9%

49.56 ppm HCl / 3.80 ppm SF6 Direct Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

49.56_HCL_DIR_000571.LAB 3/31/2010 6:34:55 46.3 < 0.01 < 0.01 3.86 < 0.5

49.56_HCL_DIR_000572.LAB 3/31/2010 6:35:10 46.3 < 0.01 < 0.01 3.86 < 0.5

49.56_HCL_DIR_000573.LAB 3/31/2010 6:35:26 46.3 < 0.01 < 0.01 3.87 < 0.5

49.56_HCL_DIR_000574.LAB 3/31/2010 6:35:42 46.5 < 0.01 < 0.01 3.86 < 0.5

49.56_HCL_DIR_000575.LAB 3/31/2010 6:35:57 46.6 < 0.01 < 0.01 3.86 < 0.5

49.56_HCL_DIR_000576.LAB 3/31/2010 6:36:13 46.7 < 0.01 < 0.01 3.87 < 0.5

49.56_HCL_DIR_000577.LAB 3/31/2010 6:36:29 46.7 < 0.01 < 0.01 3.87 < 0.5

49.56_HCL_DIR_000578.LAB 3/31/2010 6:36:44 46.9 < 0.01 < 0.01 3.87 < 0.5

49.56_HCL_DIR_000579.LAB 3/31/2010 6:37:00 46.8 < 0.01 < 0.01 3.87 < 0.5

49.56_HCL_DIR_000580.LAB 3/31/2010 6:37:16 46.9 < 0.01 < 0.01 3.87 < 0.5

Nitrogen System Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

N2_SYS_000581.LAB 3/31/2010 6:42:49 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5

N2_SYS_000582.LAB 3/31/2010 6:43:21 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5

N2_SYS_000583.LAB 3/31/2010 6:43:52 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5

CTS, 100.0 ppm Ethylene System Purge and Response Time Test

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

Ethylene

Recovery (%)

Response

Time* (sec)

100.0_CTS_SYS_RT_000590.LAB 3/31/2010 6:47:17 0.3 0.02 0.60 < 0.01 < 0.5 0.0% 4

100.0_CTS_SYS_RT_000591.LAB 3/31/2010 6:47:21 0.4 < 0.01 0.42 < 0.01 37.7 37.7% 8

100.0_CTS_SYS_RT_000592.LAB 3/31/2010 6:47:25 < 0.2 < 0.01 0.04 < 0.01 92.5 92.5% 12

100.0_CTS_SYS_RT_000593.LAB 3/31/2010 6:47:29 0.2 < 0.01 < 0.01 < 0.01 96.9 96.9% 16

100.0_CTS_SYS_RT_000594.LAB 3/31/2010 6:47:33 < 0.2 < 0.01 < 0.01 < 0.01 97.7 97.7%

100.0_CTS_SYS_RT_000595.LAB 3/31/2010 6:47:37 < 0.2 0.02 < 0.01 < 0.01 97.8 97.8%

100.0_CTS_SYS_RT_000596.LAB 3/31/2010 6:47:40 < 0.2 < 0.01 < 0.01 < 0.01 97.2 97.2%

100.0_CTS_SYS_RT_000597.LAB 3/31/2010 6:47:44 < 0.2 < 0.01 < 0.01 < 0.01 96.9 96.9%

100.0_CTS_SYS_RT_000598.LAB 3/31/2010 6:47:48 < 0.2 0.01 < 0.01 < 0.01 98.3 98.3%

100.0_CTS_SYS_RT_000599.LAB 3/31/2010 6:47:52 < 0.2 0.04 0.03 < 0.01 98.4 98.4%

100.0_CTS_SYS_RT_000600.LAB 3/31/2010 6:47:56 < 0.2 < 0.01 0.01 < 0.01 98.0 98.0%

Main Stack Effluent Prior to HCl Spike #5, Mill Off

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

MILL_OFF_000613.LAB 3/31/2010 7:01:00 48.8 18.27 4.03 < 0.01 1.6

MILL_OFF_000614.LAB 3/31/2010 7:01:31 49.0 18.39 4.03 < 0.01 1.8

Average 48.8 < 0.01
Cal Portland Cement Company, Mojave, CA ‐ FTIR QAQC Data

Prj. # 1663Prj. 1663

MILL OFF R4 000700 8:19:43 60 21 51 < 01 1

181.1 ppm HCl / 3.88 ppm SF6 System Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

HCl Recovery

(%)

181.1_HCL_SYS_000615.LAB 3/31/2010 7:07:30 173.3 0.01 < 0.01 3.81 < 0.5 95.7%

181.1_HCL_SYS_000616.LAB 3/31/2010 7:07:46 173.8 < 0.01 < 0.01 3.81 < 0.5 96.0%

181.1_HCL_SYS_000617.LAB 3/31/2010 7:08:02 174.1 < 0.01 0.02 3.81 < 0.5 96.1%

181.1_HCL_SYS_000618.LAB 3/31/2010 7:08:17 174.4 < 0.01 < 0.01 3.81 < 0.5 96.3%

181.1_HCL_SYS_000619.LAB 3/31/2010 7:08:33 174.6 < 0.01 < 0.01 3.81 < 0.5 96.4%

HCl Spike #5 Using 181.1 ppm HCl / 3.88 ppm SF6

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

HCL_SPK1_MILL_OFF_000621.LAB 3/31/2010 7:12:49 59.7 16.69 3.68 0.27 1.4

HCL_SPK1_MILL_OFF_000622.LAB 3/31/2010 7:13:05 58.9 16.52 3.66 0.27 1.3

HCL_SPK1_MILL_OFF_000623.LAB 3/31/2010 7:13:20 58.2 16.49 3.60 0.26 1.4

HCL_SPK1_MILL_OFF_000624.LAB 3/31/2010 7:13:36 58.5 16.69 3.64 0.26 1.3

HCL_SPK1_MILL_OFF_000625.LAB 3/31/2010 7:13:52 58.4 16.50 3.65 0.26 1.3

Average 58.7 0.26

Main Stack Effluent Post HCl Spike #2, Mill On

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

MILL_OFF_000626.LAB 3/31/2010 7:15:25 52.1 18.44 4.01 < 0.01 1.7

MILL_OFF_000627.LAB 3/31/2010 7:15:41 52.2 18.43 4.02 < 0.01 1.7

MILL_OFF_000628.LAB 3/31/2010 7:15:56 51.5 18.16 3.97 < 0.01 1.8

MILL_OFF_000629.LAB 3/31/2010 7:16:12 50.9 18.18 3.96 < 0.01 1.8

Average 51.7 < 0.01

Main Stack Effluent Prior to HCl Spike #6, Mill Off

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

MILL OFF R4 000700.LAB _ _ _ .LAB 3/31/2010 /31/2010 8:19:43 60.8 21.47 4.51 < 0.01 2.1

MILL_OFF_R4_000701.LAB 3/31/2010 8:20:42 61.9 21.73 4.56 < 0.01 2.2

Average 61.3 < 0.01

HCl Spike #6 Using 181.1 ppm HCl / 3.88 ppm SF6

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

HCL_SPK2_MILL_OFF_000710.LAB 3/31/2010 8:27:56 65.8 19.32 4.10 0.27 1.8

HCL_SPK2_MILL_OFF_000711.LAB 3/31/2010 8:28:27 66.6 19.72 4.15 0.26 1.8

HCL_SPK2_MILL_OFF_000712.LAB 3/31/2010 8:28:58 66.2 19.63 4.12 0.26 1.7

HCL_SPK2_MILL_OFF_000713.LAB 3/31/2010 8:29:30 66.4 19.42 4.08 0.26 1.7

HCL_SPK2_MILL_OFF_000714.LAB 3/31/2010 8:30:01 66.5 19.57 4.08 0.27 1.7

Average 66.3 0.27

Nitrogen System Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

N2_SYS_000715.LAB 3/31/2010 8:37:21 4.9 0.01 < 0.01 < 0.01 < 0.5

N2_SYS_000716.LAB 3/31/2010 8:37:52 4.2 < 0.01 < 0.01 < 0.01 < 0.5

N2_SYS_000717.LAB 3/31/2010 8:38:24 3.4 < 0.01 < 0.01 < 0.01 < 0.5

N2_SYS_000718.LAB 3/31/2010 8:38:55 3.1 < 0.01 < 0.01 < 0.01 < 0.5
Cal Portland Cement Company, Mojave, CA ‐ FTIR QAQC Data

Prj. # 1663Prj. 1663

Main Stack Effluent Prior to HCl Spike #8, Mill Off

Nitrogen System Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

N2_SYS_000773.LAB 3/31/2010 13:21:24 2.5 0.02 < 0.01 < 0.01 < 0.5

N2_SYS_000774.LAB 3/31/2010 13:21:56 2.2 < 0.01 < 0.01 < 0.01 < 0.5

N2_SYS_000775.LAB 3/31/2010 13:22:27 2.1 < 0.01 < 0.01 < 0.01 < 0.5

N2_SYS_000776.LAB 3/31/2010 13:22:58 1.9 < 0.01 < 0.01 < 0.01 < 0.5

Main Stack Effluent Prior to HCl Spike #7, Mill Off

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

MILL_OFF_R5_000837.LAB 3/31/2010 14:35:05 63.4 16.88 3.73 < 0.01 1.1

MILL_OFF_R5_000838.LAB 3/31/2010 14:36:03 63.1 16.91 3.73 < 0.01 1.2

Average 63.2 < 0.01

HCl Spike #7 Using 181.1 ppm HCl / 3.88 ppm SF6

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

HCL_SPK3_MILL_OFF_000851.LAB 3/31/2010 14:46:17 69.0 15.68 3.56 0.30 0.8

HCL_SPK3_MILL_OFF_000852.LAB 3/31/2010 14:46:48 69.3 16.01 3.59 0.30 0.9

HCL_SPK3_MILL_OFF_000853.LAB 3/31/2010 14:47:20 69.0 15.95 3.58 0.30 0.8

HCL_SPK3_MILL_OFF_000854.LAB 3/31/2010 14:47:51 68.9 15.94 3.59 0.30 0.9

HCL_SPK3_MILL_OFF_000855.LAB 3/31/2010 14:48:22 69.6 16.01 3.61 0.30 0.9

Average 69.1 0.30

Nitrogen System Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

N2_SYS_000856.LAB 3/31/2010 14:51:40 3.3 0.02 < 0.01 < 0.01 < 0.5

N2_SYS_000857.LAB 3/31/2010 14:52:11 2.8 < 0.01 < 0.01 < 0.01 < 0.5

Main                  Stack Effluent Prior to HCl Spike #8, Mill Off

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

MILL_OFF_R6_000918.LAB 3/31/2010 15:53:41 71.6 19.90 4.23 < 0.01 1.6

MILL_OFF_R6_000919.LAB 3/31/2010 15:54:40 71.1 20.14 4.28 < 0.01 1.5

Average 71.3 < 0.01

HCl Spike #8 Using 181.1 ppm HCl / 3.88 ppm SF6

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

HCL_SPK4_MILL_OFF_000922.LAB 3/31/2010 15:59:29 78.4 17.86 3.83 0.34 1.1

HCL_SPK4_MILL_OFF_000923.LAB 3/31/2010 16:00:01 78.6 17.88 3.82 0.34 1.1

HCL_SPK4_MILL_OFF_000924.LAB 3/31/2010 16:00:32 79.1 17.97 3.81 0.34 1.1

HCL_SPK4_MILL_OFF_000925.LAB 3/31/2010 16:01:03 78.5 17.83 3.79 0.34 1.2

HCL_SPK4_MILL_OFF_000926.LAB 3/31/2010 16:01:35 79.3 17.86 3.84 0.34 1.0

Average 78.8 0.34

Nitrogen System Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

N2_SYS_000927.LAB 3/31/2010 16:06:08 2.7 < 0.01 < 0.01 < 0.01 < 0.5

N2_SYS_000928.LAB 3/31/2010 16:06:39 2.3 < 0.01 < 0.01 < 0.01 < 0.5
Cal Portland Cement Company, Mojave, CA ‐ FTIR QAQC Data

CTS, 100.0 ppm Ethylene System Purge

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

Ethylene

Recovery (%)

100.0_CTS_SYS_000929.LAB 3/31/2010 16:08:16 1.9 0.01 < 0.01 < 0.01 98.0 98.0%

100.0_CTS_SYS_000930.LAB 3/31/2010 16:08:23 1.8 < 0.01 < 0.01 < 0.01 98.0 98.0%

100.0_CTS_SYS_000931.LAB 3/31/2010 16:08:31 1.7 < 0.01 < 0.01 < 0.01 98.8 98.8%

100.0_CTS_SYS_000932.LAB 3/31/2010 16:08:39 1.7 < 0.01 < 0.01 < 0.01 98.2 98.2%

100.0_CTS_SYS_000933.LAB 3/31/2010 16:08:47 1.5 0.01 < 0.01 < 0.01 98.6 98.6%

Nitrogen Direct

Spectrum Date Time

HCL          

(ppmv wet)

CO2       

(%v wet)

H2O

(%v)

SF6          

(ppmv wet)

Ethylene

(ppmv wet)

N2_DIR_000934.LAB 3/31/2010 16:23:26 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5

N2_DIR_000935.LAB 3/31/2010 16:24:29 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5

N2_DIR_000936.LAB 3/31/2010 16:25:32 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5

N2_DIR_000937.LAB 3/31/2010 16:26:34 < 0.2 < 0.01 < 0.01 < 0.01 < 0.5

Prj. # 1663Prj. 1663
APPENDIX 

Analyte Spike Summary 

 
CalPortland, Mojave, CA ‐ Ma

=

Source

HCl Spike

# Date

E

Be

ffluent HCl

fore Spike

Efflu

Afte

ent H

r Spik

Cl

e

SF6 

(Dir)

SF

(Di

6 

l) DF

HCl

(Dir)

HCl

(Exp)

HCl

(Obs)

Main Stack, Mill On 1 3/30/2010 6.3 5.9 3.80 0.18 0.0471 49.5 8.1 7.6 Main Stack, Mill On 2 3/30/2010 5.9 5.8 3.80 0.34 0.0908 49.5 9.8 8.8 Main Stack, Mill On 3 3/30/2010 6.7 6.3 3.80 0.14 0.0370 49.5 8.1 8.0 Main Stack, Mill On 4 3/30/2010 6.1 - 3.80 0.28 0.0733 49.5 9.0 8.1 

Source

HCl Spike

# Date

E

Be

ffluent HCl

fore Spike

Efflu

Afte

ent H

r Spik

Cl

e

SF6 

(Dir)

SF

(Di

6 

l) DF

HCl

(Dir)

HCl

(p 

Spiked

pm)

Main Stack, Mill Off 5 3/31/2010 48.8 51.7 3.88 0.26 0.0679 181.1 12.3 Main Stack, Mill Off 6 3/31/2010 61.3 - 3.88 0.27 0.0683 181.1 12.4 Main Stack, Mill Off 7 3/31/2010 63.2 - 3.88 0.30 0.0766 181.1 13.9 Main Stack, Mill Off 8 3/31/2010 71.3 - 3.88 0.34 0.0872 181.1 15.8 

KeyDir = Direct Concentration of Calibration Gas

Dil = Diluted Concent Concentration of Calibration GasDF = Dilution FactorExp = Expected Spike ConcentrationObs = Observed Spike Concentration

prj # 1663
APPENDIX 

Gas Certificates and Field Notes 

 
CERTIFICATE OF ANALYSIS

Grade of Product: PRIMARY STANDARD

Customer: LANSING

Part Number: X02NI99P15AD524 Reference Number: 32-112616961-1

Cylinder Number: SG9196919 Cylinder Volume: 144 Cu.Ft.

Laboratory: MIC - Royal Oak - MI Cylinder Pressure: 2015 PSIG

Analysis Date: Dec 04, 2007 Valve Outlet: 350

Product directly traceable to NIST ASTM Class 1 weights and/or NIST gas mixture reference materials.

ANALYTICAL RESULTS

Component Requested Actual Concentration Analytical

Concentration (Mole %) Uncertainity

ETHYLENE 100.0 PPM 100.0 PPM +/- 1%

NITROGEN Balance

Notes:

Signature on file

____________________________________

QA Approval

Page 1 of 32-112616961-1
CERTIFICATE OF ANALYSIS

Grade of Product: CERTIFIED STANDARD-SPEC

Customer: PRISM ANALYTICAL

Part Number: X03NI99C15A11P5 Reference Number: 82-124209097-1

Cylinder Number: CC316663 Cylinder Volume: 140.0 Cubic Feet

Laboratory: ASG - Riverton - NJ Cylinder Pressure: 2015 PSIG

Analysis Date: Mar 01, 2010 Valve Outlet: 330

Product composition verified by direct comparison to calibration standards traceable to NIST ASTM Class 1

weights and/or NIST gas mixture reference materials.

ANALYTICAL RESULTS

Component Requested Actual Concentration Analytical

Concentration (Mole %) Uncertainty

SULFUR HEXAFLUORIDE 4.000 PPM 4.120 PPM +/- 5%

HYDROGEN CHLORIDE 50.00 PPM 49.56 PPM +/- 2%

NITROGEN Balance

Notes:

Signature on file

____________________________________

Approved for Release

Page 1 of 82-124209097-1
CERTIFICATE OF ANALYSIS

Grade of Product: CERTIFIED STANDARD-SPEC

Part Number: X03NI99C15A6188 Reference Number: 82-124175033-1

Cylinder Number: CC281398 Cylinder Volume: 144 Cu.Ft.

Laboratory: ASG - Riverton - NJ Cylinder Pressure: 2000 PSIG

Analysis Date: Apr 30, 2009 Valve Outlet: 330

Product composition verified by direct comparison to calibration standards traceable to NIST ASTM Class 1

weights and/or NIST gas mixture reference materials.

ANALYTICAL RESULTS

Component Requested Actual Concentration Analytical

Concentration (Mole %) Uncertainty

SULFUR HEXAFLUORIDE 4.000 PPM 4.110 PPM +/- 5%

HYDROGEN CHLORIDE 200.0 PPM 206.5 PPM +/- 2%

NITROGEN Balance

Notes:

Signature on file

____________________________________

QA Approval

Page 1 of 82-124175033-1




APPENDIX 

US EPA Method 321 Calculations 
prism analytical technologies, inc. 

Calculations - Method 321, Low Moisture Sample Stream 

Estimating Noise Levels (Appendix C Addendum to Method 320/ Method 

321) 

RMSEST = RMSMAN TP (tss/tMAN)

1⁄2 (C.1, Method 320, 321)

tss = 64 sec (64 scans) signal integration period – sample spectra

tMAN = 32sec (32 scans) manufacturer’s signal integration time

TP = 6/10 = 0.6 manufacturer’s estimate of the fraction of 

the total infrared power transmitted by the 

adsorption cell and transfer optics from the 

interferometer to the detector

RMSMAN = 0.000025 root-mean-square noise level of the 

system, without the absorption cell and 

transfer optics, under those conditions 

necessary to yield the specified minimum 

instrumental linewidth

RMSEST = (0.000025) (0.6) (72/36)1⁄2

RMSEST = 0.0000212 abs 
prism analytical technologies, inc. 

Calculations - Method 321, Low Moisture Sample Stream 

Estimating Minimum Concentration Measurement Uncertainties (MAU and 

MIU) (Appendix D Addendum to Method 320/Method 321) 

MAU (Measurement uncertainty – analyte) 

MIU (Measurement uncertainty – interferant) 

MAUim = (RMS)(DLi)(AUi) [(FUm-FLm)/AAIim] (D.1, Method 320, 321) 

Set RMS = RMSEST 

RMS = 2.12 x 10-5 root-mean-square

DLi = 0.2 required detection limit

AUi = 0.2 analytical uncertainty limit

FUm = 2885 upper wavenumber position 

FLm = 2580 lower wavenumber position 

AAIim = 0.6859 band area of the analyte 

MAUim = (2.12x10-5)(0.2)(0.2) [(2885-2580)/0.6859] 

MAUim = 0.00038 = MIU 
11

APPENDIX B

METHOD 3A DATA FOR OXYGEN
CERTIFICATE OF ANALYSIS

Grade of Product: CERTIFIED STANDARD-SPEC

Customer: MT PLEASANT

Part Number: X03NI78C15A12C6 Reference Number: 32-112042779-1

Cylinder Number: SG9151452BAL Cylinder Volume: 152.2 CF

Laboratory: MIC - Royal Oak-32 - MI Cylinder Pressure: 2015 PSIG

Analysis Date: Mar 12, 2010 Valve Outlet: 590

Product composition verified by direct comparison to calibration standards traceable to NIST ASTM Class 1

weights and/or NIST gas mixture reference materials.

ANALYTICAL RESULTS

Component Requested Actual Concentration Analytical

Concentration (Mole %) Uncertainty

OXYGEN 10.00 % 10.01 % +/- 2%

CARBON DIOXIDE 12.00 % 11.98 % +/- 2%

NITROGEN Balance

Notes:

Signature on file

____________________________________

Approved for Release

Page 1 of 32-112042779-1
Oxygen Analyzer Readout

Run 1 Run 2 Run 3

Date 3/30/2010 3/30/2010 3/30/2010

Run Time 10:30-11:30 Run Time 12:05-13:05 Run Time 13:40-14:40

Clock Time O2 Value % Clock Time O2 Value % Clock Time O2 Value %

10:30 13.12 12:05 12.75 13:40 12.68

10:40 13.15 12:15 12.83 13:50 12.93

10:50 13.13 12:25 12.97 14:00 13.07

11:00 13.01 12:35 12.98 14:10 12.88

11:10 13.01 12:45 12.88 14:20 13.01

11:20 12.97 12:55 12.79 14:30 12.89

11:30 13.1 13:05 12.91 14:40 12.84

avg. 13.07 12.87 12.90

Run 3 Run 4 Run 5

Date 3/31/2010 3/31/2010 3/31/2010

Run Time 07:20-08:20 Run Time 13:40-14:40 Run Time 14:50-15:50

Clock Time O2 Value % Clock Time O2 Value % Clock Time O2 Value %

7:20 14.50 13:40 12.13 14:50 11.2

7:30 14.70 13:50 12.95 15:00 11.1

7:40 13.10 14:00 12.90 15:10 11.1

7:50 13.10 14:10 12.20 15:20 11.1

8:00 13.10 14:20 12.40 15:30 10.9

8:10 13.10 14:30 12.20 15:40 10.9

8:20 13.10 14:40 12.10 15:50 10.9

avg. 13.53 12.41 11.03
CalPortland - Method 3A Results and QA Calculations

Mojave, CAOxygenCAI Model 600PInstrument Span 25 User Input 

Cal Gases Cylinder ID

Zero 0.00 N2 - UHPMid 10.01 AirGas - SG9151452BALHigh 20.9 Ambient AirPRE-TESTAnalyzer Calibration Error - Direct Instrument Calibration

Tag Value Analyzer Response Absolute Difference % of Differnce from S

Zero Gas 0.00 -0.28 -0.28 Mid - Range 10.01 10.22 0.21 High - Range 20.92 21.15 0.23 Sampling System Bias - System Calibration

Direct Cal Analyzer Response Absolute Difference % of Diffrence from S

Zero Gas -0.28 0.30 0.58 Mid - Range 10.22 10.60 0.38 High - Range 21.15 21.06 -0.09 
CalPortland - Method 3A Results and QA Calculations

Mojave, CAPost Run 1Zero and Calibration Drift - Select either mid or high whichever closest to effluent concentration

Direct Cal Analyzer Response Absolute Difference % of Diffrence from S

Zero Gas -0.28 0.40 0.68 Mid - Range 10.22 10.60 0.38 

Post Run 2Zero and Calibration Drift - Select either mid or high whichever closest to effluent concentration

Direct Cal Analyzer Response Absolute Difference % of Diffrence from S

Zero Gas -0.28 0.45 0.73 Mid - Range 10.22 10.90 0.68 FinalZero and Calibration Drift - Select either mid or high whichever closest to effluent concentration

Direct Cal Analyzer Response Absolute Difference 

Zero Gas -0.28 0.44 0.72 Mid - Range 10.22 10.90 0.68 
 CalPortland - Method 3A Results and QA Calculations

Mojave, CAMETHOD 3A RESULTSAvg. Analyzer O2 Results Drift Corrected Value Run Times

% O2 % O2

Run 1 13.07 12.42 % 10:30-11:30Run 2 12.87 12.07 % 12:05-13:05Run 3 12.90 11.92 % 13:40-14:40

Avg. 12.14
CalPortland - Method 3A Results and QA Calculations

Mojave, CAOxygenCAI Model 600P

Instrument Span 25 User Input 

Cal Gases Cylinder ID

Zero 0.00 N2 - UHPMid 10.01 AirGas - SG9151452BALHigh 20.9 Ambient Air

PRE-TESTAnalyzer Calibration Error - Direct Instrument Calibration

Tag Value Analyzer Response Absolute Difference % of Differnce from Sp

Zero Gas 0.00 0.34 0.34 Mid - Range 10.01 10.22 0.21 High - Range 20.92 21.2 0.28 

Sampling System Bias - System Calibration

Direct Cal Analyzer Response Absolute Difference % of Diffrence from Sp

Zero Gas 0.34 1.10 0.76 Mid - Range 10.22 10.60 0.38 High - Range 21.2 21.9 0.70 
 CalPortland - Method 3A Results and QA Calculations

Mojave, CAPost Run 4Zero and Calibration Drift - 

Direct Cal Analyzer Response Absolute Difference % of Diffrence from Sp

Zero Gas 0.34 0.12 -0.22 Mid - Range 10.22 10.90 0.68 

Post Run 5Zero and Calibration Drift - 

Direct Cal Analyzer Response Absolute Difference % of Diffrence from Sp

Zero Gas 0.34 0.09 -0.25 Mid - Range 10.22 10.50 0.28 

FinalZero and Calibration Drift - Select either mid or high whichever closest to effluent concentration

Direct Cal Analyzer Response Absolute Difference 

Zero Gas 0.34 0.09 -0.25 Mid - Range 10.22 10.40 0.18 
CalPortland - Method 3A Results and QA Calculations

Mojave, CAMETHOD 3A RESULTSAvg. Analyzer O2 Results Drift Corrected Value Run Times

% O2 % O2

Run 1 13.07 12.30 % 6:45-7:00Run 2 12.41 11.90 % 13:40-14:40Run 3 11.03 10.56 % 14:55-15:55

11.59
12

APPENDIX C

METHOD 1 AND 2 RESULTS

FOR 

EFFLUENT VOLUMETRIC FLOWRATE
Appendix C - Method 1 Parameters

CalPortland - Method 1 

Mojave, CA

Meets EPA M1 criteria

Date 30-Mar-10

Location Stack

Run Time NS

Stack ID Kiln #1

Stack Diameter (ft) 10.54

Cross Sectional Area 87.28

Barometric Pressure " Hg NA

Stack Static Pressure " H2O NA

Pitot Tube #1 A-1

Pitot Tube Coefficient Cp 0.84

Nipple Length

Port Point Distance Ft Distance In. w/ Nipple 6.50

A - SW 1 0.5 5.6 12.07

2 1.5 18.6 25.10

3 3.1 37.3 43.82

B - SE 4 0.5 5.6 12.07

5 1.5 18.6 25.10

6 3.1 37.3 43.82

C - NE 1 0.5 5.6 12.07

2 1.5 18.6 25.10

3 3.1 37.3 43.82

D - NW 4 0.5 5.6 12.07

5 1.5 18.6 25.10

6 3.1 37.3 43.82
Appendix C - Method 2 Parameter Data

CalPortland - Method 1 & 2

Mojave, Ca

Date 30-Mar-10

Location Stack

Run Time 10:00-10:15

Stack ID 126.5 inches

Stack Diameter (ft) 10.54

Cross Sectional Area 87.28

Pitot Tube Coefficient Cp A-1

Calibration Date 23-Jun-05

Port Point Distance In Angle

A - SW 1 12.07 <10

2 25.10 <10

3 43.82 <10

B - SE 4 12.07 <10

5 25.10 <10

6 43.82 <10

C - NE 1 12.07 <10

2 25.10 <10

3 43.82 <10

D - NW 4 12.07 <10

5 25.10 <10

6 43.82 <10
CalPortland Effluent Flow Rate

Mojave, CA

Date 30-Mar-10 RUN 1

Location Stack Level 3

Run Time 10:00-10:15

Stack ID Stack

Stack Diameter (ft) 10.54

Cross Sectional Area 87.28

Barometric Pressure " Hg 27.26

Stack Static Pressure " H2O -1.2

Pitot Tube Coefficient Cp 0.84

Port Point Distance In DP SQRT DP Temp F

A - SW 1 5.57 1.2 1.10 212

2 18.60 1.5 1.22 228

3 37.32 1.5 1.22 231

B - SE 4 5.57 1.2 1.10 205

5 18.60 1.5 1.22 219

6 37.32 1.5 1.22 224

C - NE 1 5.57 1.2 1.10 220

2 18.60 1.3 1.14 200

3 37.32 1.5 1.22 233

D - NW 4 5.57 1.2 1.10 212

5 18.60 1.5 1.22 221

6 37.32 1.5 1.22 225

Average 1.17 219

Ps - abs flue gas pressure 27.17

Stack Gas Moisture Content % 8.2

Wet CO2 (Method 320) 17.5

Dry mole Fraction of flue gas 0.92

Molecular Weight % O2 % CO2 N2 MW

Md Dry 12.42 19.1 68.51 31.55

Ms Wet 30.44

Velocity f/sec 76.4

ACFM 400,280

SCFM Wet 282,623

SCFM Dry 259,448

PPM (v) wet HCl 6.3

tpy 44.4
CalPortland Effluent Flow Rate

Mojave, CA

Date 30-Mar-10 RUN 2

Location Stack Level 3

Run Time 11:30-11:45

Stack ID Stack

Stack Diameter (ft) 10.54

Cross Sectional Area 87.28

Barometric Pressure " Hg 27.26

Stack Static Pressure " H2O -1.2

Pitot Tube Coefficient Cp 0.84

Port Point Distance In DP SQRT DP Temp F

A - SW 1 5.57 1.50 1.22 218

2 18.60 1.60 1.26 225

3 37.32 1.30 1.14 226

B - SE 4 5.57 1.30 1.14 225

5 18.60 1.50 1.22 228

6 37.32 1.40 1.18 231

C - NE 1 5.57 1.20 1.10 220

2 18.60 1.40 1.18 220

3 37.32 1.30 1.14 225

D - NW 4 5.57 1.40 1.18 221

5 18.60 1.40 1.18 230

6 37.32 1.50 1.22 369

Average 1.18 230

Ps - abs flue gas pressure 27.17

Stack Gas Moisture Content % 8.2

Wet CO2 (Method 320) 17.5

Dry mole Fraction of flue gas 0.92

Molecular Weight % O2 % CO2 N2 MW

Md Dry 12.07 19.1 68.88 31.53

Ms Wet 30.43

Velocity f/sec 77.6

ACFM 406,175

SCFM Wet 282,283

SCFM Dry 259,249

PPM (v) wet HCl 6.3

tpy 44.3
CalPortland Effluent Flow Rate

Mojave, CA

Date 30-Mar-10 RUN 3

Location Stack Level 2

Run Time 13:10-13:25

Stack ID Stack

Stack Diameter (ft) 10.54

Cross Sectional Area 87.28

Barometric Pressure " Hg 27.26

Stack Static Pressure " H2O -1.2

CLC Pitot Tube #1

Pitot Tube Coefficient Cp 0.84

Port Point Distance In DP SQRT DP Temp F

A - SW 1 5.57 1.40 1.18 225

2 18.60 1.50 1.22 230

3 37.32 1.40 1.18 235

B - SE 4 5.57 1.60 1.26 217

5 18.60 1.30 1.14 233

6 37.32 1.40 1.18 232

C - NE 1 5.57 1.30 1.14 230

2 18.60 1.40 1.18 234

3 37.32 1.30 1.14 234

D - NW 4 5.57 1.30 1.14 226

5 18.60 1.40 1.18 232

6 37.32 1.50 1.22 236

Average 1.18 230

Ps - abs flue gas pressure 26.01

Stack Gas Moisture Content % 8.2

Wet CO2 (Method 320) 17.5

Dry mole Fraction of flue gas 0.92

Molecular Weight % O2 % CO2 N2 MW

Md Dry 11.92 19.1 69.01 31.53

Ms Wet 30.41

Velocity f/sec 79.3

ACFM 415,406

SCFM Wet 276,249

SCFM Dry 253,513

PPM (v) wet HCl 5.8

tpy 39.9
CalPortland Effluent Flow Rate

Mojave, CA

Date 31-Mar-10 RUN 4

Location Stack Level 3

Run Time 06:45-07:00 Immediately after this run lost power and 5 hour delay

Stack ID Stack

Stack Diameter (ft) 10.54

Cross Sectional Area 87.28

Barometric Pressure " Hg 26.90

Stack Static Pressure " H2O -1.3

Pitot Tube Coefficient Cp 0.84

Port Point Distance In DP SQRT DP Temp F

A - SW 1 5.57 1.10 1.05 350

2 18.60 1.20 1.10 358

3 37.32 1.20 1.10 364

B - SE 4 5.57 1.20 1.10 345

5 18.60 1.10 1.05 352

6 37.32 1.00 1.00 357

C - NE 1 5.57 1.20 1.10 347

2 18.60 1.00 1.00 350

3 37.32 1.10 1.05 358

D - NW 4 5.57 1.20 1.10 350

5 18.60 1.20 1.10 359

6 37.32 1.10 1.05 361

Average 1.06 354

Ps - abs flue gas pressure 26.81

Stack Gas Moisture Content % 4.4

Wet CO2 (Method 320) 20.7

Dry mole Fraction of flue gas 0.96

Molecular Weight % O2 % CO2 N2 MW

Md Dry 12.30 21.65 66.05 31.96

Ms Wet 31.34

Velocity f/sec 75.2

ACFM 393,901

SCFM Wet 228,845

SCFM Dry 218,776

HCl Results

PPM (v) Wet 57.3
CalPortland Effluent Flow Rate

Mojave, CA

Date 31-Mar-10 RUN 5

Location Stack Level 3

Run Time 13:20-13:35

Stack ID Stack

Stack Diameter (ft) 10.54

Cross Sectional Area 87.28

Barometric Pressure " Hg 26.90

Stack Static Pressure " H2O -1.2

Pitot Tube Coefficient Cp 0.84

Port Point Distance In DP SQRT DP Temp F

A - SW 1 5.57 1.00 1.00 394

2 18.60 1.00 1.00 409

3 37.32 1.00 1.00 417

B - SE 4 5.57 0.90 0.95 398

5 18.60 1.00 1.00 411

6 37.32 1.00 1.00 417

C - NE 1 5.57 0.90 0.95 410

2 18.60 1.00 1.00 419

3 37.32 1.00 1.00 421

D - NW 4 5.57 1.00 1.00 401

5 18.60 1.10 1.05 415

6 37.32 1.00 1.00 418

Average 1.00 411

Ps - abs flue gas pressure 26.81

Stack Gas Moisture Content % 4.5

Wet CO2 (Method 320) 15.9

Dry mole Fraction of flue gas 0.96

Molecular Weight % O2 % CO2 N2 MW

Md Dry 11.90 16.65 71.45 31.14

Ms Wet 30.55

Velocity f/sec 73.7

ACFM 386,009

SCFM Wet 209,744

SCFM Dry 200,306

HCl Results

PPM (v) Wet 66.8
CalPortland Effluent Flow Rate

Mojave, CA

Date 31-Mar-10 RUN 6

Location Stack Level 3

Run Time 14:40-14:55

Stack ID Stack

Stack Diameter (ft) 10.54

Cross Sectional Area 87.28

Barometric Pressure " Hg 26.90

Stack Static Pressure " H2O -1.2

Pitot Tube Coefficient Cp 0.84

Port Point Distance In DP SQRT DP Temp F

A - SW 1 5.57 1.00 1.00 404

2 18.60 1.00 1.00 424

3 37.32 1.20 1.10 434

B - SE 4 5.57 1.10 1.05 410

5 18.60 1.10 1.05 425

6 37.32 1.20 1.10 435

C - NE 1 5.57 1.10 1.05 310

2 18.60 1.20 1.10 320

3 37.32 1.20 1.10 435

D - NW 4 5.57 1.20 1.10 435

5 18.60 1.20 1.10 442

6 37.32 1.30 1.14 446

Average 1.07 410

Ps - abs flue gas pressure 26.81

Stack Gas Moisture Content % 4.1

Wet CO2 (Method 320) 18.9

Dry mole Fraction of flue gas 0.96

Molecular Weight % O2 % CO2 N2 MW

Md Dry 10.56 19.71 69.73 31.58

Ms Wet 31.02

Velocity f/sec 78.7

ACFM 412,152

SCFM Wet 224,164

SCFM Dry 214,974

HCl Results

PPM (v) Wet 68.1