### 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349



# Order Summary Report 

# Analytical Laboratory

Order Number: J12030116

Lab Contact: Jason C Perkins 

### Date: 3/23/2012 Customer Address: 253 Plant Allen Road Customer Name(s): BILL KENNEDY, RON LAWS, ALLEN STOWE, ROBBIN JOLLY, DON SCRUG

Belmont, NC 28012

Phone: 980-875-5348 Report Authorized By: (Signature)


### Program Comments: Please contact the Program Manager (Jason C Perkins) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Cert ificate of Analysis (sample re sults) under the qualifiers heading. All results are repo rted on a dry weight basis unless otherwise noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimatio n of the uncertainty of measurement for the results in the report isavailable upon request. This report shall not be reproduced, except in full, without the written consent of t he Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, A nalytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the follow ing State Certifications : North Carolina(DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.

## Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2012005462 ALLEN 04-Mar-12 9:24 AM Jeremy D. FGD Purge Eff 2012005463 ALLEN 04-Mar-12 8:13 AM Jeremy D. EQ Tank Eff 2012005464 ALLEN 04-Mar-12 8:20 AM JLD/JBW BioReactor 1 Inf 2012005465 ALLEN 04-Mar-12 8:20 AM JLD/JBW BioReactor 1 Inf BLANK 2012005466 ALLEN 04-Mar-12 9:40 AM JLD/JBW BioReactor 2 Inf 2012005467 ALLEN 04-Mar-12 9:40 AM JLD/JBW BioReactor 2 Inf BLANK 2012005468 ALLEN 04-Mar-12 8:30 AM JLD/JBW BioReactor 2 Eff 2012005469 ALLEN 04-Mar-12 8:30 AM JLD/JBW BioReactor 2 Eff BLANK 2012005470 ALLEN 04-Mar-12 10:15 AM Jeremy D. Filter Blk 9 Total Samples

### COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. The Vendor Laboratories have been qualified by the Analytical Laboratory Yes No 

# Technical Validation Review Checklist:

Yes No

Yes No



## Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody

Reviewed By: 

### Mary Ann Ogle Date: 

### 3/23/2012 Yes

Electronic Data Deliverable (EDD) Sent Separately

# Certificate of Laboratory Analysis This re port shall not be reproduced, excep t in full. 

## Order # J12030116

2012005462 Collection Date: 04-Mar-12 9:24 AM 

### Site: FGD Purge Eff Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst DF ALKALINITY Vendor Parameter COMPLETE V_PRISM 1 INORGANIC IONS BY IC Bromide 830 mg/L EPA 300.0 14-Mar-12 09:19 JAHERMA 50 500 Chloride 3000 mg/L EPA 300.0 14-Mar-12 09:19 JAHERMA 50 500 Sulfate 1200 mg/L EPA 300.0 14-Mar-12 09:19 JAHERMA 50 500 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 51.7 ug/L EPA 245.1 13-Mar-12 09:42 AGIBBS 2.5 50 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 2.50 ug/L EPA 245.1 13-Mar-12 11:07 AGIBBS 2.5 50 TOTAL RECOVERABLE METALS BY ICP Boron (B) 38.6 mg/L EPA 200.7 13-Mar-12 14:22 MHH7131 0.5 10 Calcium (Ca) 2490 mg/L EPA 200.7 13-Mar-12 14:22 MHH7131 0.1 10 Iron (Fe) 91.7 mg/L EPA 200.7 13-Mar-12 14:22 MHH7131 0.1 10 Lithium (Li) 0.182 mg/L EPA 200.7 13-Mar-12 14:22 MHH7131 0.05 10 Magnesium (Mg) 393 mg/L EPA 200.7 13-Mar-12 14:22 MHH7131 0.05 10 Manganese (Mn) 5.88 mg/L EPA 200.7 13-Mar-12 14:22 MHH7131 0.05 10 Potassium (K) 36.9 mg/L EPA 200.7 13-Mar-12 14:22 MHH7131 1 10 Sodium (Na) 25.8 mg/L EPA 200.7 13-Mar-12 14:22 MHH7131 0.5 10 DISSOLVED METALS BY ICP-MS Manganese (Mn) 5440 ug/L EPA 200.8 16-Mar-12 13:49 KRICHAR 10 10 Selenium (Se) 1090 ug/L EPA 200.8 16-Mar-12 13:49 KRICHAR 10 10 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 209 ug/L EPA 200.8 14-Mar-12 11:27 KRICHAR 10 10 Cadmium (Cd) < 10.0 ug/L EPA 200.8 14-Mar-12 11:27 KRICHAR 10 10 Chromium (Cr) 172 ug/L EPA 200.8 14-Mar-12 11:27 KRICHAR 10 10 Copper (Cu) 177 ug/L EPA 200.8 14-Mar-12 11:27 KRICHAR 10 10 Nickel (Ni) 181 ug/L EPA 200.8 14-Mar-12 11:27 KRICHAR 10 10 Selenium (Se) 6790 ug/L EPA 200.8 14-Mar-12 11:27 KRICHAR 10 10 Silver (Ag) < 10.0 ug/L EPA 200.8 14-Mar-12 11:27 KRICHAR 10 10 Zinc (Zn) 214 ug/L EPA 200.8 14-Mar-12 11:27 KRICHAR 10 10 SELENIUM SPECIATION Vendor Parameter Complete V_AS&C 1

# Certificate of Laboratory Analysis This re port shall not be reproduced, excep t in full. 

## Order # J12030116

2012005462 Collection Date: 04-Mar-12 9:24 AM 

### Site: FGD Purge Eff Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst DF TOTAL DISSOLVED SOLIDS Vendor Parameter Complete V_PACE 1 TOTAL SUSPENDED SOLIDS Vendor Parameter Complete V_PACE 1


### 2012005463 Collection Date: 04-Mar-12 8:13 AM 

### Site: EQ Tank Eff Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst DF MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 31.5 ug/L EPA 245.1 13-Mar-12 09:49 AGIBBS 2.5 50 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 2.50 ug/L EPA 245.1 13-Mar-12 11:09 AGIBBS 2.5 50 TOTAL RECOVERABLE METALS BY ICP Boron (B) 31.6 mg/L EPA 200.7 13-Mar-12 14:26 MHH7131 0.5 10 Calcium (Ca) 1610 mg/L EPA 200.7 13-Mar-12 14:26 MHH7131 0.1 10 Iron (Fe) 62.1 mg/L EPA 200.7 13-Mar-12 14:26 MHH7131 0.1 10 Lithium (Li) 0.129 mg/L EPA 200.7 13-Mar-12 14:26 MHH7131 0.05 10 Magnesium (Mg) 291 mg/L EPA 200.7 13-Mar-12 14:26 MHH7131 0.05 10 Manganese (Mn) 4.07 mg/L EPA 200.7 13-Mar-12 14:26 MHH7131 0.05 10 Potassium (K) 25.0 mg/L EPA 200.7 13-Mar-12 14:26 MHH7131 1 10 Sodium (Na) 20.3 mg/L EPA 200.7 13-Mar-12 14:26 MHH7131 0.5 10 DISSOLVED METALS BY ICP-MS Manganese (Mn) 3740 ug/L EPA 200.8 16-Mar-12 13:53 KRICHAR 10 10 Selenium (Se) 215 ug/L EPA 200.8 16-Mar-12 13:53 KRICHAR 10 10 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 141 ug/L EPA 200.8 14-Mar-12 11:30 KRICHAR 10 10 Cadmium (Cd) < 10.0 ug/L EPA 200.8 14-Mar-12 11:30 KRICHAR 10 10 Chromium (Cr) 115 ug/L EPA 200.8 14-Mar-12 11:30 KRICHAR 10 10 Copper (Cu) 128 ug/L EPA 200.8 14-Mar-12 11:30 KRICHAR 10 10 Nickel (Ni) 134 ug/L EPA 200.8 14-Mar-12 11:30 KRICHAR 10 10 Selenium (Se) 3560 ug/L EPA 200.8 14-Mar-12 11:30 KRICHAR 10 10 Silver (Ag) < 10.0 ug/L EPA 200.8 14-Mar-12 11:30 KRICHAR 10 10 Zinc (Zn) 155 ug/L EPA 200.8 14-Mar-12 11:30 KRICHAR 10 10

# Certificate of Laboratory Analysis This re port shall not be reproduced, excep t in full. 

## Order # J12030116

2012005464 Collection Date: 04-Mar-12 8:20 AM 

### Site: BioReactor 1 Inf Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst DF ALKALINITY Vendor Parameter COMPLETE V_PRISM 1 MERCURY 1631 Vendor Parameter Complete V_BRAND 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 1.00 ug/L EPA 245.1 13-Mar-12 09:51 AGIBBS 1 20 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 2.50 ug/L EPA 245.1 13-Mar-12 11:11 AGIBBS 2.5 50 TOTAL RECOVERABLE METALS BY ICP Boron (B) 32.3 mg/L EPA 200.7 13-Mar-12 14:30 MHH7131 0.5 10 Calcium (Ca) 1340 mg/L EPA 200.7 13-Mar-12 14:30 MHH7131 0.1 10 Iron (Fe) < 0.100 mg/L EPA 200.7 13-Mar-12 14:30 MHH7131 0.1 10 Lithium (Li) 0.056 mg/L EPA 200.7 13-Mar-12 14:30 MHH7131 0.05 10 Magnesium (Mg) 239 mg/L EPA 200.7 13-Mar-12 14:30 MHH7131 0.05 10 Manganese (Mn) 0.383 mg/L EPA 200.7 13-Mar-12 14:30 MHH7131 0.05 10 Potassium (K) 9.99 mg/L EPA 200.7 13-Mar-12 14:30 MHH7131 1 10 Sodium (Na) 18.6 mg/L EPA 200.7 13-Mar-12 14:30 MHH7131 0.5 10 DISSOLVED METALS BY ICP-MS Manganese (Mn) 376 ug/L EPA 200.8 16-Mar-12 13:57 KRICHAR 10 10 Selenium (Se) 68.3 ug/L EPA 200.8 16-Mar-12 13:57 KRICHAR 10 10 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 10.0 ug/L EPA 200.8 14-Mar-12 11:33 KRICHAR 10 10 Cadmium (Cd) < 10.0 ug/L EPA 200.8 14-Mar-12 11:33 KRICHAR 10 10 Chromium (Cr) < 10.0 ug/L EPA 200.8 14-Mar-12 11:33 KRICHAR 10 10 Copper (Cu) < 10.0 ug/L EPA 200.8 14-Mar-12 11:33 KRICHAR 10 10 Nickel (Ni) < 10.0 ug/L EPA 200.8 14-Mar-12 11:33 KRICHAR 10 10 Selenium (Se) 66.9 ug/L EPA 200.8 14-Mar-12 11:33 KRICHAR 10 10 Silver (Ag) < 10.0 ug/L EPA 200.8 14-Mar-12 11:33 KRICHAR 10 10 Zinc (Zn) < 10.0 ug/L EPA 200.8 14-Mar-12 11:33 KRICHAR 10 10 SELENIUM SPECIATION Vendor Parameter Complete V_AS&C 1

# Certificate of Laboratory Analysis This re port shall not be reproduced, excep t in full. 

## Order # J12030116

2012005465 Collection Date: 04-Mar-12 8:20 AM 

### Site: BioReactor 1 Inf BLANK Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst DF MERCURY 1631 Vendor Parameter Complete V_BRAND 1


### 2012005466 Collection Date: 04-Mar-12 9:40 AM 

### Site: BioReactor 2 Inf Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst DF ALKALINITY Vendor Parameter COMPLETE V_PRISM 1 MERCURY 1631 Vendor Parameter Complete V_BRAND 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 1.00 ug/L EPA 245.1 13-Mar-12 09:54 AGIBBS 1 20 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 2.50 ug/L EPA 245.1 13-Mar-12 11:14 AGIBBS 2.5 50 TOTAL RECOVERABLE METALS BY ICP Boron (B) 31.1 mg/L EPA 200.7 13-Mar-12 14:34 MHH7131 0.5 10 Calcium (Ca) 1280 mg/L EPA 200.7 13-Mar-12 14:34 MHH7131 0.1 10 Iron (Fe) 7.95 mg/L EPA 200.7 13-Mar-12 14:34 MHH7131 0.1 10 Lithium (Li) 0.055 mg/L EPA 200.7 13-Mar-12 14:34 MHH7131 0.05 10 Magnesium (Mg) 215 mg/L EPA 200.7 13-Mar-12 14:34 MHH7131 0.05 10 Manganese (Mn) 0.625 mg/L EPA 200.7 13-Mar-12 14:34 MHH7131 0.05 10 Potassium (K) 10.7 mg/L EPA 200.7 13-Mar-12 14:34 MHH7131 1 10 Sodium (Na) 17.5 mg/L EPA 200.7 13-Mar-12 14:34 MHH7131 0.5 10 DISSOLVED METALS BY ICP-MS Manganese (Mn) 599 ug/L EPA 200.8 16-Mar-12 14:01 KRICHAR 10 10 Selenium (Se) 14.6 ug/L EPA 200.8 16-Mar-12 14:01 KRICHAR 10 10 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 10.0 ug/L EPA 200.8 14-Mar-12 11:36 KRICHAR 10 10 Cadmium (Cd) < 10.0 ug/L EPA 200.8 14-Mar-12 11:36 KRICHAR 10 10 Chromium (Cr) < 10.0 ug/L EPA 200.8 14-Mar-12 11:36 KRICHAR 10 10 Copper (Cu) < 10.0 ug/L EPA 200.8 14-Mar-12 11:36 KRICHAR 10 10 Nickel (Ni) 17.3 ug/L EPA 200.8 14-Mar-12 11:36 KRICHAR 10 10 Selenium (Se) 16.7 ug/L EPA 200.8 14-Mar-12 11:36 KRICHAR 10 10 Silver (Ag) < 10.0 ug/L EPA 200.8 14-Mar-12 11:36 KRICHAR 10 10 Zinc (Zn) < 10.0 ug/L EPA 200.8 14-Mar-12 11:36 KRICHAR 10 10

# Certificate of Laboratory Analysis This re port shall not be reproduced, excep t in full. 

## Order # J12030116

2012005466 Collection Date: 04-Mar-12 9:40 AM 

### Site: BioReactor 2 Inf Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst DF SELENIUM SPECIATION Vendor Parameter Complete V_AS&C 1


### 2012005467 Collection Date: 04-Mar-12 9:40 AM 

### Site: BioReactor 2 Inf BLANK Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst DF MERCURY 1631 Vendor Parameter Complete V_BRAND 1


### 2012005468 Collection Date: 04-Mar-12 8:30 AM 

### Site: BioReactor 2 Eff Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst DF ALKALINITY Vendor Parameter COMPLETE V_PRISM 1 INORGANIC IONS BY IC Bromide 18 mg/L EPA 300.0 12-Mar-12 23:59 JAHERMA 5 50 Chloride 1600 mg/L EPA 300.0 12-Mar-12 23:59 JAHERMA 50 500 Sulfate 1300 mg/L EPA 300.0 12-Mar-12 23:59 JAHERMA 50 500 MERCURY 1631 Vendor Parameter Complete V_BRAND 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 1.00 ug/L EPA 245.1 13-Mar-12 09:56 AGIBBS 1 20 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 2.50 ug/L EPA 245.1 13-Mar-12 11:16 AGIBBS 2.5 50 TOTAL RECOVERABLE METALS BY ICP Boron (B) 29.3 mg/L EPA 200.7 13-Mar-12 14:38 MHH7131 0.5 10 Calcium (Ca) 1120 mg/L EPA 200.7 13-Mar-12 14:38 MHH7131 0.1 10 Iron (Fe) 0.743 mg/L EPA 200.7 13-Mar-12 14:38 MHH7131 0.1 10 Lithium (Li) < 0.050 mg/L EPA 200.7 13-Mar-12 14:38 MHH7131 0.05 10 Magnesium (Mg) 164 mg/L EPA 200.7 13-Mar-12 14:38 MHH7131 0.05 10 Manganese (Mn) 0.816 mg/L EPA 200.7 13-Mar-12 14:38 MHH7131 0.05 10 Potassium (K) 16.4 mg/L EPA 200.7 13-Mar-12 14:38 MHH7131 1 10 Sodium (Na) 14.8 mg/L EPA 200.7 13-Mar-12 14:38 MHH7131 0.5 10

# Certificate of Laboratory Analysis This re port shall not be reproduced, excep t in full. 

## Order # J12030116

2012005468 Collection Date: 04-Mar-12 8:30 AM 

### Site: BioReactor 2 Eff Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst DF DISSOLVED METALS BY ICP-MS Manganese (Mn) 776 ug/L EPA 200.8 16-Mar-12 14:05 KRICHAR 5 5 Selenium (Se) < 5.00 ug/L EPA 200.8 16-Mar-12 14:05 KRICHAR 5 5 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 5.00 ug/L EPA 200.8 14-Mar-12 11:39 KRICHAR 5 5 Cadmium (Cd) < 5.00 ug/L EPA 200.8 14-Mar-12 11:39 KRICHAR 5 5 Chromium (Cr) < 5.00 ug/L EPA 200.8 14-Mar-12 11:39 KRICHAR 5 5 Copper (Cu) < 5.00 ug/L EPA 200.8 14-Mar-12 11:39 KRICHAR 5 5 Nickel (Ni) 68.6 ug/L EPA 200.8 14-Mar-12 11:39 KRICHAR 5 5 Selenium (Se) < 5.00 ug/L EPA 200.8 14-Mar-12 11:39 KRICHAR 5 5 Silver (Ag) < 5.00 ug/L EPA 200.8 14-Mar-12 11:39 KRICHAR 5 5 Zinc (Zn) 6.41 ug/L EPA 200.8 14-Mar-12 11:39 KRICHAR 5 5 SELENIUM SPECIATION Vendor Parameter Complete V_AS&C 1


### 2012005469 Collection Date: 04-Mar-12 8:30 AM 

### Site: BioReactor 2 Eff BLANK Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst DF MERCURY 1631 Vendor Parameter Complete V_BRAND 1


### 2012005470 Collection Date: 04-Mar-12 10:15 AM 

### Site: Filter Blk Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst DF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 0.05 ug/L EPA 245.1 13-Mar-12 11:40 AGIBBS 0.05 1 DISSOLVED METALS BY ICP-MS Manganese (Mn) < 1.00 ug/L EPA 200.8 16-Mar-12 12:58 KRICHAR 1 1 Selenium (Se) < 1.00 ug/L EPA 200.8 16-Mar-12 12:58 KRICHAR 1 1

## March 14 , 201 2

Jay Perkins Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078 (704) 875-5 245 Project: Allen HAPS/MACT (Wastewater) (LIMS # J120 3011 6 )

Dear Mr. Perkins, Attached is the report associated with four (4) aqueous samples submitted for selenium speciation analysis on March 6 , 2012

. The samples were received in a sealed cooler at-0. 5 ° C on March 7 , 2012

. Selenium speciation analysis was performed via ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP-CRC-MS). Any issues associated with the analysis are addressed in the following report. If you have any questions, please feel free to contact me at your convenience.
Sincerely,

Russell Gerads Vice President Applied Speciation and Consulting, LLC

## Applied Speciation and Consulting, LLC Report prepared for: Jay Perkins Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078 Project: Allen HAPS/MACT (Wastewater) (LIMS # J1203011 6 )

March 14 , 2012

1. Sample Reception Four (4) aqueous samples in125mL HDPE bottles (provided by Applied Speciation and Consulting) were submitted for selenium speciation analysi s on March6 , 2012. The samples were received on March 7 , 201 2 in a sealed container at -0. 5 ° C. The samples were received in a laminar flow clean hood,void of trace metals contamination and ultra-violet radiation, and was designated a discrete sample identifier. An aliquot of each sample was filtered (0.45μm) and each filtrate w asstored in a secure, monitored cryofreezer (maintained at a temperature of -80 o

## C) until selenium speciation analysis could be performed via ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP- CRC -MS).

2. Sample Preparation All sample preparation is performed in laminar flow clean hoods known to be free from trace metals contamination. All applied water for dilutions and sample preservatives are monitored for contamination to account for any biases associated with the sample results. Selenium Speciation Analysis by IC-ICP-CRC-MS Prior to analysis, an aliquot of each sample was filtered with a syringe filter (0.45μm) and injected directly into a sealed autosampler vial. No further sample preparation was performed as any chemical alteration of a sample may shift the equilibrium of the system, resulting in changes in speciation ratios. 3. Sample Analysis All sample analysis is preceded by a minimum of a five-point calibration curve spanning the entire concentration range of interest. Calibration curves are performed at the beginning of each analytical day. All calibration curves, associated with each species of interest, are

## standardized by linear regression resulting in a response factor. All sample results are

instrument blank correctedto account for any operational biases associated with the analytical platform. Prior to sample analysis, all calibration curves are verified using second source standard s which are identified as initial calibration verification standards (ICV). Ongoing instrument performance is identified by the analysis of continuing calibration verification standards (CCV) and continuing calibration blanks (CCB) at a minimal interval of every ten analytical runs. Selenium Speciation Analysis by IC-ICP-CRC-MS Eachsample for selenium speciation analysis w asanalyzed by ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP- CRC -MS) on March 12, 2012. An aliquot of eachsample is injected onto an anion exchange column and mobilized by a basic (pH > 7) gradient. The eluting selenium species are then introduced into a radio frequency (RF) plasma where energy-transfer processes cause desolvation, atomization, and ionization. The ions are extracted from the plasma through a differentially-pumped vacuum interface and travel through a pressurized chamber ( CRC ) containing hydrogen gas which preferentially reacts with interfering ions of the same target mass to charge ratios (m/z). A solid-state detector detects ions transmitted through the mass analyzer and the resulting current is processed by a data handling system. Retention times for each eluting species are compared to known standards for species identification.

4. Analytical Issues The overall analyses went well and no significant analytical issues were encountered. All quality control parameters associated with this sample were within acceptance limits. The estimated method detection limits (eMDLs) for selenite, selenate, and selenocyanate are generated from replicate analyses of the lowest standard in the calibration curve. Not all selenium species are present in preparation blanks; therefore, eMDL calculations based on preparation blanks are artificially biased low. The eMDL for methylseleninic acid and selenomethionine is calculated from the average eMDL of selenite, selenate, and selenocyanate. The calibration does not contain methylseleninic acid or selenomethionine due to impurities in these standards which would bias the results for other selenium species.

## If you have any questions or concerns regarding this report, please feel free to contact me.

Sincerely,

Russell Gerads Vice President Applied Speciation and Consulting, LLC

### Sample Results

Sample ID Se(IV) Se(VI) SeCN MeSe(IV) SeMe Unknown Se Species (n) FGD Purge Eff 1310 52.1 17.9 29.5 ND (<2.3) 107 (2) BioReactor 1 Inf 9.02 35.2 ND (<0.39) 6.93 ND (<0.57) 8.06 (1) BioReactor 2 Inf 6.82 ND (<0.54) ND (<0.39) 0.79 ND (<0.57) 0.98 (1) BioReactor 2 Eff ND (<0.77) ND (<0.54) ND (<0.39) ND (<0.57) ND (<0.57) 0 (0) All results reflect the applied dilution and are reported in μg/L ND = Not detected at the applied dilution SeCN = Selenocyanate MeSe(IV) = Methylseleninic acid SeMe = Selenomethionine Unknown Se Species = Total concentration of all unknown Se species observed by IC-ICP-MS n = number of unknown Se species observed Report Generated by: Russell Gerads Applied Speciation and Consulting, LLC Selenium Speciation Results for Duke Energy Project Name: Allen HAPS/MACT (Wastewater)

Contact: Jay Perkins
Date: March 14, 2012 LIMS #J12030116

### Quality Control Summary - Preparation Blank Summary Analyte (μg/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL* eMDL 250x eMDL 1000x Se(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.003 0.77 3.1 Se(VI) 0.000 0.000 0.000 0.000 0.000 0.000 0.002 0.54 2.2 SeCN 0.000 0.000 0.000 0.000 0.000 0.000 0.002 0.39 1.5 MeSe(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.002 0.57 2.3 SeMe 0.000 0.000 0.000 0.000 0.000 0.000 0.002 0.57 2.3 eMDL = Estimated Method Detection Limit *Please see narrative regarding eMDL calculations
Quality Control Summary - Certified Reference Materials Analyte (μg/L) CRM True Value Result Recovery Se(IV) LCS 9.57 9.81 102.5 Se(VI) LCS 9.48 9.10 96.0 SeCN LCS 8.92 8.69 97.5 MeSe(IV) LCS 6.47 5.78 89.3 SeMe LCS 9.32 8.62 92.5 Applied Speciation and Consulting, LLC Selenium Speciation Results for Duke Energy Project Name: Allen HAPS/MACT (Wastewater)

Contact: Jay Perkins LIMS #J12030116 Date: March 14, 2012 Report Generated by: Russell Gerads

### Quality Control Summary - Matrix Duplicates Analyte (μg/L) Sample ID Rep 1 Rep 2 Mean RPD Se(IV) Batch QC 13.45 13.03 13.24 3.2 Se(VI) Batch QC 35.78 35.21 35.50 1.6 SeCN Batch QC ND (<0.39) ND (<0.39) NC NC MeSe(IV) Batch QC 14.55 14.92 14.74 2.5 SeMe Batch QC ND (<0.57) ND (<0.57) NC NC ND = Not detected at the applied dilution NC = Value was not calculated due to one or more concentrations below the eMDL *Sample concentrations are within 10x the eMDL
Quality Control Summary - Matrix Spike/ Matrix Spike Duplicate Analyte (μg/L) Sample ID Spike Conc MS Result Recovery Spike Conc MSD Result Recovery RPD Se(IV) Batch QC 1390 2168 155.0 1390 2101 150.2 3.2 Se(VI) Batch QC 1261 1313 101.3 1261 1307 100.8 0.5 SeCN Batch QC 1144 483.3 42.3* 1144 532.3 46.5* 9.6 *Low recovery is attributed to matrix induced species conversion Applied Speciation and Consulting, LLC Selenium Speciation Results for Duke Energy Project Name: Allen HAPS/MACT (Wastewater)

Contact: Jay Perkins LIMS #J12030116 Date: March 14, 2012 Report Generated by: Russell Gerads

### 3958 6 th

### Ave NW • Seattle, WA 98107 • T: 206-632-6206 • F: 206-632-6017 • www.brooksrand.com • brl@brooksrand.com 

## March 14, 2012
Duke Energy ATTN: Jay Perkins Scientific Support-Laboratory 13339 Hagers Ferry Road Huntersville NC 28078 jcperkins@duke-energy.com labcustomer@duke-energy.com
RE: Project DUK-HV1201 Client Project: J12030116 Dear Mr. Perkins, On March 7, 2012, Brooks Rand Labs (BRL) received three (3) wastewater samples and three (3) corresponding field blanks. Samples were logged-in for total mercury (Hg) analysis. All samples were received, prepared, analyzed, and stored according to BRL SOPs and EPA methodology. The results were blank-corrected as described in the calculations section of the applicable SOP(s) and may be evaluated using adjusted reporting limits to account for sample aliquot size. Please refer to the Sample Results page for sample-specific detection limits and other details. Aside from concentration qualifiers, all data was reported without qualification and all associated quality control sample results met the acceptance criteria. BRL, an accredited laboratory, certifies the reported results of all analyses for which BRL is NELAP accredited meet all NELAP requirements. For more details, see the Report Information page of the report. Please feel free to contact me if you have any questions regarding this report. Sincerely,

Tiffany Stilwater Project Manager tiffany@brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



## Definition of Data Qualifiers

(Effective 9/23/09) 

## Laboratory Accreditation BRL is accredited by the National Environmental Laboratory Accreditation Program (NELAP) through the State of Florida Department of Health, Bureau of Laboratories (E87982) and is certified to perform many environmental analyses. BRL is also certified by many other states to perform environmental analyses. For a current list of our accreditations /certifications, please visit our website at <http://www.brooksrand.com/default.asp?contentID=586>. Results reported relate only to the samples listed in the report. 

# Report Information

BLK BRL BS CAL CCV CRM D DUP ICV MSD ND NR PS REC RPD RSD SCV SOP 

### method blank Brooks Rand Labs laboratory fortified blank calibration standard continuing calibration verification certified reference material dissolved fraction duplicate initial calibration verification matrix spike duplicate non-detect non-reportable post preparation spike percent recovery relative percent difference relative standard deviation secondary calibration verification standard operating procedure MDL MRL MS



### method detection limit method reporting limit matrix spike

SRM T COC



### standard reference material total recoverable fraction chain of custody record 

## Common Abbreviations

These qualifiers are based on those previously utilized by Brooks Rand, Ltd., those found in the EPA SOW ILM03.0, Exhibit B, Section III, pg. B-18, and the USEPA Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses; USEPA; July 2002. These supersede all previous qualifiers ever employed by BRL. Detected by the instrument, the result is > the MDL but ≤the MRL. Result is reported and considered an estimate. B E 

### An estimated value due to the presence of interferences. A full explanation is presented in the narrative. H 

### Holding time and/or preservation requirements not met. Result is estimated. J 

### Estimated value. A full explanation is presented in the narrative. J-M 

### Duplicate precision (RPD) for associated QC sample was not within acceptance criteria. Result is estimated. J-N 

### Spike recovery for associated QC sample was not within acceptance criteria. Result is estimated. M 

### Duplicate precision (RPD) was not within acceptance criteria. Result is estimated. N 

### Spike recovery was not within acceptance criteria. Result is estimated. R 

### Rejected, unusable value. A full explanation is presented in the narrative. U 

### Result is ≤the MDL or client requested reporting limit (CRRL). Result reported as the MDL or CRRL. X 

### Result is not BLK-corrected and is within 10x the absolute value of the highest detectable BLK in the batch. Result is estimated. 

## Field Quality Control Samples Please be notified that certain EPA methods require the collection of field quality control samples of an appropriate type and frequency; failure to do so is considered a deviation from some methods and for compliance purposes should only be done with the approval of regulatory authorities. Please see the specific EPA methods for details regarding required field quality control samples.

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Sample Information

Report Matrix Type Received Sampled Sample Lab ID 

### 1210024-01 BioReactor 1 Inf 03/04/2012 03/07/2012 Sample Influent 1210024-02 BioReactor 1 Inf Hg Blk 03/04/2012 03/07/2012 Field Blank DIW 1210024-03 BioReactor 2 Inf 03/04/2012 03/07/2012 Sample Influent 1210024-04 BioReactor 2 Inf Hg Blk 03/04/2012 03/07/2012 Field Blank DIW 1210024-05 BioReactor 2 Eff 03/04/2012 03/07/2012 Sample Effluent 1210024-06 BioReactor 2 Eff Hg Blk 03/04/2012 03/07/2012 Field Blank DIW 

# Batch Summary

Analyte Prepared Analyzed Sequence Batch Lab Matrix Method 

### B120366 03/09/2012 03/12/2012 1200164 Water EPA 1631 Hg

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Sample Results

Sample Sequence Result MDL MRL Unit Batch

Qualifier Analyte Fraction

Report Matrix 

### BioReactor 1 Inf 

### ng/L 365 T 1200164 B120366 Influent 8.08 3.03 1210024-01 Hg
BioReactor 1 Inf Hg Blk 

### ng/L 0.15 T U 1200164 B120366 DIW 0.40 0.15 1210024-02 Hg

BioReactor 2 Eff 

### ng/L 127 T 1200164 B120366 Effluent 1.54 0.58 1210024-05 Hg
BioReactor 2 Eff Hg Blk 

### ng/L 0.15 T U 1200164 B120366 DIW 0.40 0.15 1210024-06 Hg

BioReactor 2 Inf 

### ng/L 260 T 1200164 B120366 Influent 8.16 3.06 1210024-03 Hg
BioReactor 2 Inf Hg Blk 

### ng/L 0.15 T U 1200164 B120366 DIW 0.40 0.15 1210024-04 Hg

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Accuracy & Precision Summary

Batch: 

### B120366

Analyte Result Units Native Spike REC & Limits RPD & Limits Method: 

### EPA 1631 Lab Matrix: 

### Water

Sample Certified Reference Material (1209009, NIST 1641d 1000x dilution) B120366-SRM1 

### 15.68 94% ng/L 85-115 Hg 14.73
Matrix Spike (1210024-01) B120366-MS3 

### 1212 116% ng/L 71-125 Hg 1773

365.2
Matrix Spike Duplicate (1210024-01) B120366-MSD3 

### 1212 107% ng/L 71-125 247% Hg 1658

365.2



# Method Blanks & Reporting Limits

Batch: 

### B120366
Method: 

### EPA 1631 Matrix: 

### Water Analyte: 

### Hg Result Units Sample 

### B120366-BLK1 ng/L 0.07 B120366-BLK2 ng/L 0.07 B120366-BLK3 ng/L 0.05 B120366-BLK4 ng/L 0.04 MDL: 

### 0.15 Average: 

### 0.06 Standard Deviation: 

### 0.02 Limit: 

### 0.10 Limit: 

### 0.50 MRL: 

### 0.40

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Instrument Calibration

Sequence: 

### 1200164 Method: 

### EPA 1631 Instrument: 

### THG-10 Date: 

### 03/12/2012 Total Mercury and Mercury Speciation by CVAFS
Analyte: 

### Hg REC & Limits Result True Value Lab ID Units 

### 1200164-IBL1 5.96 pg of Hg 1200164-IBL2 5.89 pg of Hg 1200164-IBL3 5.92 pg of Hg 1200164-IBL4 5.80 pg of Hg 1200164-CAL1 25.00 25.66 pg of Hg 103% 1200164-CAL2 100.0 96.61 pg of Hg 97% 1200164-CAL3 500.0 485.2 pg of Hg 97% 1200164-CAL4 2500 2636 pg of Hg 105% 1200164-CAL5 10000 9885 pg of Hg 99% 1200164-ICV1 1568 1473 pg of Hg 94% 85-115 1200164-CCV1 500.0 484.5 pg of Hg 97% 77-123 1200164-CCB1 12.9 pg of Hg 1200164-CCV2 500.0 475.1 pg of Hg 95% 77-123 1200164-CCV3 500.0 483.3 pg of Hg 97% 77-123 1200164-CCV4 500.0 491.9 pg of Hg 98% 77-123

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Sample Containers

Lab ID: 

### 1210024-01 Report Matrix: 

### Influent Sample Type: 

### Sample Received: 

### 03/07/2012 Sample: 

### BioReactor 1 Inf Collected: 

### 03/04/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71470160 10 Cooler

none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1210024-02 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 03/07/2012 Sample: 

### BioReactor 1 Inf Hg Blk Collected: 

### 03/04/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71470160 10 Cooler

none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1210024-03 Report Matrix: 

### Influent Sample Type: 

### Sample Received: 

### 03/07/2012 Sample: 

### BioReactor 2 Inf Collected: 

### 03/04/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71470160 10 Cooler

none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1210024-04 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 03/07/2012 Sample: 

### BioReactor 2 Inf Hg Blk Collected: 

### 03/04/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71470160 10 Cooler

none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1210024-05 Report Matrix: 

### Effluent Sample Type: 

### Sample Received: 

### 03/07/2012 Sample: 

### BioReactor 2 Eff Collected: 

### 03/04/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71470160 10 Cooler

none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1210024-06 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 03/07/2012 Sample: 

### BioReactor 2 Eff Hg Blk Collected: 

### 03/04/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71470160 10 Cooler

none n/a 250mL Bottle FLPE Hg-T

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Shipping Containers

Cooler Tracking No: 

### 4726 7966 9021 via FedEx Temperature: 

### ambient Coolant Type: 

### None Description: 

### Cooler Damaged in transit? 

### No Returned to client? 

### No Custody seals present? 

### No Custody seals intact? 

### No COC present? 

### Yes Received: 

### March 7, 2012 8:45

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.brooksrand.com

## March 12, 2012

LIMS USE: FR - TERRY WHITNER LIMS OBJECT ID: 92113411



## 92113411 Project: Pace Project No.: RE: Terry Whitner Duke Energy Carolinas, LLC PO Box 37929 DPEHS Charlotte, NC 28237

J12030116

Dear Terry Whitner: Enclosed are the analytical results for sample(s) received by the laboratory on March 06, 2012. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely,
Kevin Herring kevin.herring@pacelabs.com Project Manager

Enclosures

cc: Mr. Jay Perkins, Duke Energy



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### CERTIFICATIONS

Pace Project No.: Project: 92113411

J12030116

Asheville Certification IDs 2225 Riverside Dr., Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia Certification #: 00072 West Virginia Certification #: 356 Virgina/VELAP Certification #: 460147



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### SAMPLE ANALYTE COUNT

Pace Project No.: Project: 92113411

J12030116

Lab ID Sample ID Method Analytes Reported Laboratory Analysts 92113411001 FGD PURGE EFF SM 2540C 1 PASI-A SMW SM 2540D 1 PASI-A SMW



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### HITS ONLY

Pace Project No.: Project: 92113411

J12030116

Parameters Analyzed Result Lab Sample ID Report Limit Qualifiers Units Method Client Sample ID

92113411001 FGD PURGE EFF Total Dissolved Solids 39700 mg/L 03/08/12 13:13 500 SM 2540C Total Suspended Solids 7100 mg/L 03/09/12 12:38 250 SM 2540D



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### PROJECT NARRATIVE

Pace Project No.: Project: 92113411

J12030116

Method: Client: Duke Energy

SM 2540C

Date: March 12, 2012 Description: 2540C Total Dissolved Solids

General Information: 1 sample was analyzed for SM 2540C. All samples were received in acceptable condition with any exceptions noted below.
Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank: All analytes were below the report limit in the method blank with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/19999 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 731931) • Total Dissolved Solids
Additional Comments:



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### PROJECT NARRATIVE

Pace Project No.: Project: 92113411

J12030116

Method: Client: Duke Energy

SM 2540D

Date: March 12, 2012 Description: 2540D Total Suspended Solids

General Information: 1 sample was analyzed for SM 2540D. All samples were received in acceptable condition with any exceptions noted below.
Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank: All analytes were below the report limit in the method blank with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/20019 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 732655) • Total Suspended Solids
Additional Comments: This data package has been reviewed for quality and completeness and is approved for release.



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### ANALYTICAL RESULTS

Pace Project No.: Project: 92113411

J12030116
Sample: FGD PURGE EFF Lab ID: 92113411001 Collected: 03/04/12 09:24 Received: 03/06/12 11:11 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. Qual Report Limit 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 39700 mg/L 1 03/08/12 13:13 500 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 7100 mg/L 1 03/09/12 12:38 250



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 03/12/2012 04:36 PM Page 7 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### QUALITY CONTROL DATA

Pace Project No.: Project: 92113411

J12030116

QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/19999 SM 2540C SM 2540C 2540C Total Dissolved Solids Associated Lab Samples: 92113411001

Parameter Units Blank Result Reporting

Limit Qualifiers METHOD BLANK: 731928 Associated Lab Samples: 92113411001 Matrix: Water

Analyzed Total Dissolved Solids mg/L ND 25.0 03/08/12 13:01

Parameter Units LCS Result % Rec Limits Qualifiers % Rec Conc. 731929 LABORATORY CONTROL SAMPLE: LCS Spike
Total Dissolved Solids mg/L 236 250 94 80-120

Parameter Units Dup Result Qualifiers

RPD Result 92113392001 731930 SAMPLE DUPLICATE:

Total Dissolved Solids mg/L 8200 6 7760

Parameter Units Dup Result Qualifiers

RPD Result 92113409001 731931 SAMPLE DUPLICATE:

Total Dissolved Solids mg/L 9800 D6 13 11100



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 03/12/2012 04:36 PM Page 8 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### QUALITY CONTROL DATA

Pace Project No.: Project: 92113411

J12030116

QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/20019 SM 2540D SM 2540D 2540D Total Suspended Solids Associated Lab Samples: 92113411001

Parameter Units Blank Result Reporting

Limit Qualifiers METHOD BLANK: 732653 Associated Lab Samples: 92113411001 Matrix: Water

Analyzed Total Suspended Solids mg/L ND 2.5 03/09/12 12:34

Parameter Units LCS Result % Rec Limits Qualifiers % Rec Conc. 732654 LABORATORY CONTROL SAMPLE: LCS Spike Total Suspended Solids mg/L 260 250 104 80-120

Parameter Units Dup Result Qualifiers

RPD Result 92113272001 732655 SAMPLE DUPLICATE:

Total Suspended Solids mg/L 10 D6 25 7.8

Parameter Units Dup Result Qualifiers

RPD Result 92113393003 732656 SAMPLE DUPLICATE:

Total Suspended Solids mg/L 28.2 1 28.0



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 03/12/2012 04:36 PM Page 9 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### QUALIFIERS

Pace Project No.: Project: 92113411

J12030116

DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. LABORATORIES Pace Analytical Services - Asheville PASI-A ANALYTE QUALIFIERS

The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. D6



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 03/12/2012 04:36 PM Page 10 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### QUALITY CONTROL DATA CROSS REFERENCE TABLE

Pace Project No.: Project: 92113411

J12030116

Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92113411001 WET/19999 FGD PURGE EFF SM 2540C 92113411001 WET/20019 FGD PURGE EFF SM 2540D



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 03/12/2012 04:36 PM Page 11 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cert No. 37735 

# Case Narrative 03/13/2012

Duke Energy Corporation (04) Jay Perkins 13339 Hagers Ferry Road Huntersville, NC 28078 Project: Allen HAPS/MACT (Wastewater) Project No.: J12030116 Lab Submittal Date: 03/06/2012 Prism Work Order: 2030114 VA Certification No. 1287



### Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC.



### VP Laboratory Services Reviewed By

Data Qualifiers Key Reference: 

### HT Sample received and analyzed outside of the hold time.

Method Detection Limit MDL Below Reporting Limit BRL
Relative Percent Difference RPD


## * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 1 of 9

# Sample Receipt Summary 03/13/2012 

## Prism Work Order: 2030114 Client Sample ID Matrix Lab Sample ID Date Sampled Date Received 

### 2030114-01 03/04/12 2012005462/FGD Purge Eff 03/06/12 Water 2030114-02 03/04/12 2012005464/BioReactor 1 Inf 03/06/12 Water 2030114-03 03/04/12 2012005466/BioReactor 2 Inf 03/06/12 Water 2030114-04 03/04/12 2012005468/BioReactor 2 Eff 03/06/12 Water Samples received in good condition at 2.6 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 2 of 9

# Laboratory Report 03/13/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen HAPS/MACT (Wastewater) Duke Energy Corporation (04)

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2030114-01 Prism Work Order: 2030114 Time Collected: 03/04/12 09:24 Time Submitted: 03/06/12 16:25 2012005462/FGD Purge Eff


### J12030116

General Chemistry Parameters 7.1 *SM4500-H B P2C0135 1 3/7/12 14:00 JAB HT pH Units pH 47 *SM2320 B P2C0213 1 5.0 3/12/12 12:45 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2C0214 1 5.0 3/12/12 12:45 JAB mg/L 0.66 Carbonate Alkalinity 47 *SM2320 B P2C0215 1 5.0 3/12/12 12:45 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 3 of 9

# Laboratory Report 03/13/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen HAPS/MACT (Wastewater) Duke Energy Corporation (04)

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2030114-02 Prism Work Order: 2030114 Time Collected: 03/04/12 08:20 Time Submitted: 03/06/12 16:25 2012005464/BioReactor 1 Inf


### J12030116

General Chemistry Parameters 6.8 *SM4500-H B P2C0135 1 3/7/12 14:00 JAB HT pH Units pH 9.6 *SM2320 B P2C0213 1 5.0 3/12/12 12:45 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2C0214 1 5.0 3/12/12 12:45 JAB mg/L 0.66 Carbonate Alkalinity 9.6 *SM2320 B P2C0215 1 5.0 3/12/12 12:45 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 4 of 9

# Laboratory Report 03/13/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen HAPS/MACT (Wastewater) Duke Energy Corporation (04)

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2030114-03 Prism Work Order: 2030114 Time Collected: 03/04/12 09:40 Time Submitted: 03/06/12 16:25 2012005466/BioReactor 2 Inf


### J12030116

General Chemistry Parameters 6.3 *SM4500-H B P2C0135 1 3/7/12 14:00 JAB HT pH Units pH 26 *SM2320 B P2C0213 1 5.0 3/12/12 12:45 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2C0214 1 5.0 3/12/12 12:45 JAB mg/L 0.66 Carbonate Alkalinity 26 *SM2320 B P2C0215 1 5.0 3/12/12 12:45 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 5 of 9

# Laboratory Report 03/13/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen HAPS/MACT (Wastewater) Duke Energy Corporation (04)

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2030114-04 Prism Work Order: 2030114 Time Collected: 03/04/12 08:30 Time Submitted: 03/06/12 16:25 2012005468/BioReactor 2 Eff


### J12030116

General Chemistry Parameters 6.7 *SM4500-H B P2C0135 1 3/7/12 14:00 JAB HT pH Units pH 30 *SM2320 B P2C0213 1 5.0 3/12/12 12:45 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2C0214 1 5.0 3/12/12 12:45 JAB mg/L 0.66 Carbonate Alkalinity 30 *SM2320 B P2C0215 1 5.0 3/12/12 12:45 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 6 of 9

### 3/13/12 

## Level II QC Report

13339 Hagers Ferry Road Project No: J12030116 Project: Allen HAPS/MACT (Wastewater) Duke Energy Corporation (04)
Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 2030114 Time Submitted: 3/6/2012 4:25:00PM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control



### Batch P2C0135 - NO PREP LCS (P2C0135-BS1) 

### Prepared & Analyzed: 03/07/12 pH pH Units 6.91 6.860 99-101 101 LCS (P2C0135-BS2) 

### Prepared & Analyzed: 03/07/12 pH pH Units 6.87 6.860 99-101 100 Duplicate (P2C0135-DUP2) 

### Prepared & Analyzed: 03/07/12 Source: 2030114-04 pH pH Units 6.71 6.70 10 0.1 

### Batch P2C0213 - NO PREP Blank (P2C0213-BLK1) 

### Prepared & Analyzed: 03/12/12 Total Alkalinity mg/L BRL 5.0 LCS (P2C0213-BS1) 

### Prepared & Analyzed: 03/12/12 Total Alkalinity mg/L 257 5.0 250.0 90-110 103 LCS Dup (P2C0213-BSD1) 

### Prepared & Analyzed: 03/12/12 Total Alkalinity mg/L 258 5.0 250.0 200 90-110 103 0.4 

### Batch P2C0214 - NO PREP Blank (P2C0214-BLK1) 

### Prepared & Analyzed: 03/12/12 Carbonate Alkalinity mg/L BRL 5.0 LCS (P2C0214-BS1) 

### Prepared & Analyzed: 03/12/12 Carbonate Alkalinity mg/L 257 5.0 90-110

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 7 of 9

### 3/13/12 

## Level II QC Report

13339 Hagers Ferry Road Project No: J12030116 Project: Allen HAPS/MACT (Wastewater) Duke Energy Corporation (04)
Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 2030114 Time Submitted: 3/6/2012 4:25:00PM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control



### Batch P2C0214 - NO PREP LCS Dup (P2C0214-BSD1) 

### Prepared & Analyzed: 03/12/12 Carbonate Alkalinity mg/L 258 5.0 200 90-110 0.4 

### Batch P2C0215 - NO PREP Blank (P2C0215-BLK1) 

### Prepared & Analyzed: 03/12/12 Bicarbonate Alkalinity mg/L BRL 5.0 LCS (P2C0215-BS1) 

### Prepared & Analyzed: 03/12/12 Bicarbonate Alkalinity mg/L 257 5.0 250.0 90-110 103 LCS Dup (P2C0215-BSD1) 

### Prepared & Analyzed: 03/12/12 Bicarbonate Alkalinity mg/L 258 5.0 250.0 200 90-110 103 0.4

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 8 of 9Page 9 of 9