## UNITED STATES ENVIRONMENTAL PROTECTION AGE N CY

WASHINGTON, D.C

. 20460

MEMORANDUM

Date: 11/18/2014 OFFICE OF CHEMICAL SAFETY AND

POLLUTION PREVENTION



## S U BJECT: Ch l orpyrifos Acute and Steady State Dietary (Food Only) Exposure Analysis to

Support Registration Review

PC Code: 059101 DP Barcode : D424486

Decision No.:**Cf?~)l(,** 

## Reg i stration No.: NA

Petition No.: NA Regulatory Action : Registration Review

Risk Assessment Type: Dietary Case No.: NA

TXR No.: None CAS No

. : 2921-88

- 2

MRID No .: None 40 CFR : 40 CFR 180.342



## FROM: Danette Drew

, Chemist 

## !

..

# j) Risk Assessment Branch V 

## Nil

THROUGH:

And: Health Effects Division (HED, 7509P)

Sheila Piper,

# ChemisJ~ Thurston Morton, Chemist /,{.

Dietary Exposure Science Aavisory Council (

Michael Metzger, Branch Chief ('

Risk Assessment Branch V 

## NII (/

Health Effects Division (HED, 7509PJ 

# /

TO: Joel Wolf, Chemical Review Manager

Tom Myers, Team Leader

Risk Managemen t and Implementation Branch II

Pesticide Re-evalu at ion Division (7508P)

Page I of53

### Chlorpyrifos Dietary Exposure DP Number: 0424486



## Executive Summary



## Acute and s teady state dietary (food only) exposure analyses for chlorpyrifos were conducted

using the Dietary Exposure Evaluation Model (DEEM) and Calendex software with the Food

Commodity Intake Database (FCID). This software uses 2003-2008 food consumption data

from the U.S. Department of Agriculture's (USDA's) National Health and Nutrition

Examination Survey, What We Eat in America, (NHANES/WWE IA)

. The most recent previous

dietary assessment was performed in 2011 to support chlorpyrifos registration review (D.

Soderberg, 6/30/11, D388166, Chlorpyrifos: Revised Acute (Probabilistic) and Chronic Dietary

Exposure and Risk Assessments for Food Only (with and without Food Handling Use included)

and for Water Only for the Registration Review Action

- Typical Use Rates/Water Included).

This current analysis reflects the latest consumption data as well as more recent food monitoring

and percent crop treated data.

This analysis was performed for the purpose of obtaining food exposure values for use in the

chlorpyrifos physiologically-based pharmacokinetic-pharmacodynamic (P BPK-PD) modeling as

part of EPA's revised human health risk assessment (HHRA, D424485 ) for chlorpyrifos. Unlike

the previous chlorpyrifos d ietary assessment (D388166; 2011), this memorandum does not

include risk estimates (exposure as a percent of the reference dose or populat i on adjusted dose)

but only presents th e resulting dietary exposure values, and only for the index population

s ub groups relevant to the revised chlorpyrifos HHRA. In the revised HHRA

, the chlorpyrifos

exposure from food sources are compared to the doses calculated by the PBPK-PD model to

cause inhibition of acetylcholinesterase (AChE) activity per population subgroup; red blood cell

cho line sterase inhi bition (ChEI) is the toxicological endpoint of concern for chlorpyrifos

exposures.

All re s id ues i n food are assumed to be paren t chlorpyrifos since the chlorpyrifos oxon is not

typically found in foods in monitoring data or crop field trials. Food exposures are based only

upon field and live stock use of chlorpyrifos and do not incorporate potential exposure from food

handling establishment (FHE) uses since th ere are no currently registered FHE us es.

Th i s memorandum was reviewed by two peer reviewers of the DESAC per the current DESAC

Standard Operating Procedure (SOP).

Acute and Steady State Dietary (Food Only) Expo sure Re sults and Characterization

Both th e acute and steady s tate di e ta ry exposure analyses are highly refined. The lar ge majority

of food re sidues used were based u pon U.S. Department of Agriculture's Pesticide Data

Program (PDP) monitoring data except in a few instances where no appropriate PDP data were

available. The B iologica l and Economic Analysis Division (BEAD) of OPP provided percent

crop treated information. Food processing factors from sub mit ted studies were used as

appropriate.

For the acute analysis using DEEM, th e highest exposed population subgroup was children 1

- 2

years old at 0.000423 mg/kg/day at the 99.9 1 h 

## percentile of exposure.

Page 2 of 53

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 3 of 53 

## Organophosphates may exhibit a phenomenon known as steady state acetylcholinesterase

(AChE) inhibition which is the most sensitive endpoint for all lifestages. After repeated dosing

at the same dose, the amount of AChE inhibition in a g iven dose remains consistent across

duration. For chlorpyrifos steady state, at the 99.9 th 

## percentile of exposure, the highest exposed

population subgroup was children 1

- 2 y ears old at 0.0002 42 mg/kg , using Calendex.

I

. Residue Information

Ch lorpyrifos is an organophosphate insecticide that has numerous uses on a wide variety of

crops

, ornamentals and turf. Chlorpyrifos is also used as an adult mosquitocide and in livestock

ear tags to control flies. Tolerances are established f or residues of chlorpyr ifos on c rops and

livestock commodities ( 40 CFR 180.342 ). There is also a tolerance for food handling uses

although there do not appear to be any active registrations for this use. The residue of concern in

food and livestock commodities is the parent compound chlorpyrifos

. The oxon metabolite is

generally not found in food monitoring data or field trials.

Sufficient information was available to conduct highly refined assessments . C hlorpyrifos is

routinely included in PDP monitoring. For crops /foods n ot tested by PDP, translations have been

made from tested crops. Occasionally, older PDP data has been used where it represented the

best estimate of real residues ; the years of PDP data used were from 1998 to 2012. Field trial

data or tolerances have be en used for a very few crops where translations from PDP data were

not possible. The same data were used for both the acute and steady state analyses

. In fact, the

acute analysis in DEEM and the steady state analysis in Calendex both used the identical in put

file. Most input residues for the acute and steady state analyses were incorporated as residue data

files (RDFs) and the analyses were performed probabilistically. The processing ( residue

reduction or concentration) factors were taken directly from the previ ous assessment (D388166 ;

2011 ) ; empirical factors came from guideline studies and a non

- guideline cooking study.

Attachment 1 describes in detail the input (residue data sources, processing factors, anticipated

residues (ARs) based on either Residue Data Files (RDFs) or point estimates) for the crop and

livestock commodities. Attachment 4 contains the acute (and steady state) food only residue input

file.

F ood exposures are based only upon field use of chlorpyrifos and do not incorporate potential

exposure from f

ood h andling e stablishment (FHE) u ses since BEAD did not identify any

registered FHE uses (although there are FHE tolerances established for residu es of chlorpyrifos

on all foods that do not have a higher tolerance from field uses). The previous (2011) dietary risk

assessment did include a chronic analysis for FHE use based on <2% establishments treated

(BEAD could not confirm that there was any actu al usage although there was a registered use at

the time) and half the analytical limit of detection ( 1⁄2 LOD ; 0.01 ppm) based on all nondetectable

residues in a chlorpyrifos FHE study. That analysis resulted in a chronic dietary exposure of

0.000009 mg/kg f

or children ages 1

- 2 years old (highest exposed population subgroup). Using

any exposure values in the risk assessment based on a non

- registered use would be considered an

overestimate of risk . Nonetheless, the exposure from any potential FHE uses may be considered

insignificant compared to exposures from field uses.

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 4 of 53 

## From PDP data it appea rs that chlorpyrifos is either applied illegally to a variety of crops or that

residues occur on several crops that are rotated in after use of chlorpyrifos on a leg ally registered

crop , or contamination is occurring by other means . Data on crops without tolerances are not

ordinarily included in EPA assessments. Omission of residues on these crops may lead to some

underestimation of exposure. However, the only commo dity with a relatively high percentage of

detects and with a fairly high maximum chlorpyrifos residue level, cilantro, would not be

expected to result in appreciable consumption levels and would not be expected to have a

significant impact on dietary expos ure. Attachment 2 lists il legal residues found by PDP on

crops which do not have a chlorpyrifos registered use or tolerance

.

I I

. Percent Crop Treated Information

B EAD has provided a Screening Level Usage Analysis ( SLUA ; May 1, 2014 ), a list of percent

crop treated estimates to be used for this assessment , which is i ncluded as Attachment 3

. A

separate memorandum ( DP#345255, Addendum to the Screening Level Use Analysis and Update

to the Percent of Food Handling Establishments Treated Esti mates

, full text found in D388166,

2011 , Attachment 3 ) details percent crop treated estimates for food handling establishments and

kiwifruit.

III . Drinking Water Data

This analysis does not include drinking water as the chlorpyrifos PBPK

- PD model predicts ChEI

separately for food and water sources of exposure.

I V. DEEM

- FCID Program and Consumption Information

A chlorpyrifos acute dietary exposure analysis w as conducted using the DEEM

- FCID, Version

3.16, which incorporates 2003

- 2008 consumption data from USDA’s NHANES/WWEIA. The

data are based on the reported consumption of more than 20,000 individuals over two non

consecutive survey days. Foods “as consumed” (e.g., apple pie) are linked to EPA

- defined food

commodities (e.g., apples, peeled fru it

- cooked; fresh or N/S; baked; or wheat flour

- cooked;

fresh or N/S, baked) using publicly available recipe translation files developed jointly by

USDA/ARS and EPA. For chronic exposure assessment, consumption data are averaged for the

entire U.S. pop ulation and within population subgroups. However, for acute exposure

assessment, consumption data are retained as individual consumption events . Based on analysis

of the 2003

- 2008 WWEIA consumption data, which took into account dietary patterns and

surve y respondents, HED concluded that it is most appropriate to include the following

population subgroups: the general U.S. population, all infants (<1 year old), children 1

- 2,

children 3

- 5, children 6

- 12, youth 13

- 19, adults 20

- 49, females 13

- 49, and adults 50

- 99 years

old.

For an acute exposure assessment, individual one

- day food consumption data are used on an

individual

- by

- individual basis. The reported consumption amounts of each food item can be

multiplied by a residue point estimate and summed to obta in a total daily pesticide exposure for a

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 5 of 53 

## deterministic exposure assessment, or “matched” in multiple random pairings with residue values

and then summed in a probabilistic assessment.

V. CALENDEX

- FCID Program

A chlorpyrifos steady state dietary exposure analysis w as conducted using Calendex

- FCIDTM

. Calendex provides a focus detailed profile of potential exposures to individuals across a calendar

year. A calendar

- based approach provides the ability to estimate daily exposures from multiple

sources over time to an individual and is in keeping with two key tenets of agg regate risk

assessment: 1) that exposures when aggregated are internally consistent and realistic; and 2) that

appropriate temporal and geographic linkages or correlations/asso ciations between exposure

scenarios are maintained

. Calendex also enables HED to identify potential risks caused by co

occurrence of exposures from multiple routes and pathways (e.g., near simultaneous same

- day

exposures throug h drinking water and residen tial uses)

. For chlorpyrifos, only food exposures

were estimated. An aggregate with water and/or residential exposures was not performed for this

exercise.

HED’s steady state assessment considers the potential risk from a 21

- day exposure duration

using a 3

- week rolling average (sliding by day) across the year. For this assessment, the same

food residue values used in the acute assessment were used for the 21

- day duration. In the

Calendex software, one diary for each individual in the WWEIA is selected to be paired with a

randomly selected set of residue values f or each food consumed

. The steady state analysis

calculated exposures for the sentinel populations for infant, child, youth, and adult (infants <1 yr,

children 1

- 2 yrs, children 6

- 12 yrs, females 1 3

- 49 yrs).

VI . Toxicological Information

This analysis was performed for the purpose of obtaining food exposure values for use in the

chlorpyrifos physiologically

- based pharmacokinetic

- pharmacodynamic (PBPK

- PD) modeling as

part of EPA’s revised human health risk assessment (HHRA, D424485) for chlorpyrifos . Unlike

the previous chlorpyrifos dietary assessment (D388166; 2011) , this memorandum does not

include risk estimates ( exposure as a percent of the reference dose or population adjusted dose )

bu t only presents the resulting dietary exposure values, and only for the index population

subgroups relevant to the revised chlorpyrifos HHRA. In the revised HHRA, the chlorpyrifos

exposure from food sources are compared to the doses calculated by the PBPK

- PD model to

cause inhibition of acetylcholinesterase (AChE) activity per population subgroup; red blood cell

cholinesterase inhibition (ChEI) is the toxicological endpoint of concern for chlorpyrifos

exposures.

V I I

. Results/Discussion

Results of Acute Dietary (Food Only) Exposure Analysis

For acute food only exposure, the highest exposed population subgroup was children 1

- 2 years

old at 0.000423 mg/kg/day at the 99.9 th 

## percentile of exposure. See Attachment 5, acute food

only results.

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 6 of 53 *The subpopulation with the highest exposure estimates

.



## Results of Steady State Dietary (Food Only) Exposure Analysis

For the steady state dietary exposure analyses, children 1

- 2 years old was the population

subgroup with the highest estimated exposure of 0.000242 mg/kg (average of 0.000189 mg/kg)

at the 99.9 th 

## percentile of exposure. See Attachment 6 , examples of steady state (food only)

results.

*The subpopulation with the highest exposure estimates



### Table 1

. DEEM Results of Acute Dietary (Food Only ) Exposure

Analysis for Chlorpyrifos

.

Population Subgroup 95 th



### Percentile 9 9 th



### Percentile 9 9.9 th



### Percentile

Exposure

(mg/kg/day) Exposure

(mg/kg/day) Exposure

(mg/kg/day)

General U.S. Population 0.000031 0.000064 0.000197

All Infants (<1 year old) 0.000050 0.000088 0.000273

Children 1

- 2 years old* 0.000082 0.000143 0.000423

Children 3

- 5 years old 0.000062 0.000107 0.000319

Children 6

- 12 years old 0.000040 0.000072 0.000189

Youth 13

- 19 years old 0.000024 0.000042 0.000126

Adults 20

- 49 years old 0.000021 0.000042 0.000167

Adults 50

- 99 years old 0.000022 0.000044 0.000186

Females 13

- 49 years old 0.000021 0.000041 0.000150

Table 2

. Calendex Results of Steady State Dietary (Food Only) Exposure Analysis for Chlorpyrifos

Population Subgroup 50 th 

### Percentile 70 th 

### Percentile 95 th 

### Percentile 99.9 th 

### Percentile

Max. Exposure

( mg/kg )

[ave ] Max. Exposure

(mg/kg )

[ave] Max.

Exposure

(mg/kg )

[ave] Max. Exposure

(mg/kg )

[ave]

All Infants (< 1 year old) 0.000011

[0.000010] 0.00002

[0.00002] 0.000045

[0.000044 ] 0.000186

[0.00014 ]

Children ( 1

- 2 years old ) * 0.000027

[0.000027] 0.000038

[0.000037] 0.000072

[0.000069] 0.000242

[0.000189]

Children (6

- 12 years old) 0.000014

[0.000013] 0.000019

[0.000018] 0.000039

[0. 000038] 0.000128

[0.000096]

Females ( 13

- 49 years old ) 0.000007

[0.000007] 0.000009

[0.000009] 0.000018

[0.000018] 0.000075

[0.000057]

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 7 of 53 

## VI I I

. Characterization of Inputs/Outputs

This is a highly refined assessment, using monitoring data for almost all crops, using extensive

percent crop treated information, and using a large set of processing and cooking factors. Most

input residues for the acute and steady state analyses were in corporated as residue distribution

files (RDFs) and the analyses were performed probabilistically. See Attachment 1 which details

all of the input assumptions.

IX

. Conclusions

Both the acute and steady state dietary (food only) exposure analyses for chlorpyrifos were

highly refined and incorporated monitoring data for almost all crops/foods, used extensive

percent crop treated information, and used a large set of processing and cooking factors. The

analyses were performed probabi listically.

This analysis was performed for the purpose of obtaining food exposure values for comparison

with PBPK

- PD modeling predictions of doses causing red blood cell cholinesterase inhibition as

part of the chlorpyrifos registration review prelimina ry human health risk assessment. Unlike the

previous chlorpyrifos dietary assessment, this memorandum does not include risk estimates

( exposure as a percent of the population adjusted dose, or PAD ) but only presents the resulting

dietary exposure values fo r the relevant population subgroups. This analysis does not include

drinking water as the PBPK

- PD model predicts ChEI inhibition from exposures to the

chlorpyrifos oxon metabolite in water independent of exposures of chlorpyrifos from food

sources.

X

. L ist of Attachments

1. Summary of Data and Residue Estimates Used in the Dietary Analyses.

2. List of Residue Found by PDP on Crops for Which Use of Chlorpyrifos is Not R egistered.

3. SLUA from BEAD.

4. Acute (and Steady Stat e) Food only Residue Input File

5 . Acute ( Food Only ) Result File

6. Examples of Steady State (Food Only) Result Files

### Page 8 of 53 

## Attachment 1 . Data Sources and Residue Estimates Used in the Dietary Exposure Analyses

Table A1a

. Data Sources and Residue Estimates for Chlorpyrifos Dietary Analysis

Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

Root and Tuber Vegetables (CG 1)

Beet, sugar/molasses B Sugar beet

tolerance(1.0)

adjusted w/ calculated

processing factor

(0.02) NA NA 10 20 0.004

Radish, root NB/PB Sweet Potato PDP

2008, 2009, 2010 1454/47 0.0013 100 100 RDF

(Potato_Sweet)

Total Samples=1454,

Total Detects=47,

Total LODs=1407,

Total Zeros=0

Rutabaga NB/PB Sweet Potato PDP

2008, 2009, 2010 

### 1454/47 0.0013 100 100 RDF

(Potato_Sweet)

Sweet Potato NB/PB Sweet Potato PDP

2008, 2009, 2010 

### 1454/47 0.0013 0.15

(peeling

factor) 100 100 RDF

(Potato_Sweet)

Sweet Potato, baby

food NB/PB Sweet Potato, baby

food, PDP 2010, 2011 776/0 0.0014 100 100 RDF

(Potato_Sweet_BF)

Total Samples=776,

Total Detects=0,

Total LODs=776,

Total Zeros=0

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 9 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

Turnip, root NB/PB Sweet Potato PDP

2008, 2009, 2010 

### 1454/47 0.0013 100 100 RDF

(Potato_Sweet)

Yam NB Sweet Potato PDP

2008, 2009, 2010 1454/47 0.0013 0.15

(peeling

factor) 100 100 RDF

(Potato_Sweet)

Leaves of Root and Tuber Vegetables (CG2)

Radish, top PB Kale PDP 2006, 2007,

2008 802/36 0.0019 100 100 RDF

(Kale)

Total Samples=802,

Total Detects=36,

Total LODs=766,

Total Zeros=0

Turnip, top PB Kale PDP 2006, 2007,

2008 802/36 0.0019 100 100 RDF

(Kale)

Bulb Vegetables (CG3)

Onion, bulb NB/PB Onion Bulb PDP

2011, 2012 744/0 0.0078 40 50 RDF

(Onion_Bulb)

Total Samples=744,

Total Detects=0,

Total LODs=372,

Total Zeros=372

Onion, bulb, dried B Onion Bulb PDP

2011, 2012 744/0 0.0078 9.0 dried 40 50 0.0039

Leafy Vegetables except Brassica Vegetables (CG 4)

Brassica Cole Leafy Vegetables (CG5) [CROP GROUP TOLERANCE EXISTS]

Broccoli NB/PB Broccoli PDP 2006,

2007, 2008 1475/108 0.0006 0.94

(cooking) 45 60 RDF

(Broccoli)

Total Samples=1475,

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 10 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

Total Detects=108,

Total LODs=777,

Total Zeros=590

Broccoli rabi NB Kale PDP 2006, 2007,

2008 802/36 0.0019 

### 0.83

(cooking) 100 100 RDF

(Kale)

Broccoli Chinese NB Broccoli PDP 2006,

2007, 2008 1475/108 0.0006 0.94

(cooking)

100 100 RDF

(Broccolito_chinese)

Total Samples=1475,

Total Detects=108,

Total LODs=1367,

Total Zeros=0

Brussels sprouts NB/PB Cabbage PDP 2010,

2011 1483/0 0.0135 

### 0.83

(cooking)

100 100 RDF

(Cabbageto_sprouts_

napa_kohlrabi)

otal Samples=1483,

Total Detects=0,

Total LODs=1483,

Total Zeros=0

Cabbage NB/PB Cabbage PDP 2010,

2011 1483/0 0.0135 

### 0.83

(cooking)

15 25 RDF

(Cabbage)

Total Samples=1483,

Total Detects=0,

Total LODs=371,

Total Zeros=1112

Cabbage, Chinese,

bok choy PB Kale PDP 2006, 2007,

2008 802/36 0.0019 

### 0.83

(cooking) 100 100 RDF

(Kale)

Cabbage, Chinese,

mustard NB/PB Broccoli PDP 2006,

2007, 2008 1475/108 0.0006 0.94

(cooking) 100 100 RDF

(Broccolito_chinese)

Cabbage, Chinese, NB/PB Cabbage PDP 2010, 1483/0 0.0135 

### 0.83 100 100 RDF

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 11 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

napa 2011 

### (cooking) (Cabbageto_sprouts_

napa_kohlrabi)

Cauliflower NB/PB Cauliflower PDP

2011,2012 923/0 0.0015 0.94

(cooking)

40 60 RDF

(Cauliflower)

Total Samples=923,

Total Detects=0,

Total LODs=554,

Total Zeros=369

Collard PB Collard PDP

2006,2007,2008 679/22 0.0021 

### 0.83

(cooking)

100 100 RDF

(Collard)

Total Samples=679,

Total Detects=22,

Total LODs=657,

Total Zeros=0

Kale PB Kale PDP 2006, 2007,

2008 802/36 0.0019 

### 0.83

(cooking) 100 100 RDF

(Kale)

Kohlrabi NB Cabbage PDP 2010,

2011 1483/0 0.0135 

### 0.83

(cooking)

100 100 RDF

(Cabbageto_sprouts_

napa_kohlrabi)

Mustard green PB Kale PDP 2006, 2007,

2008 802/36 0.0019 

### 0.83

(cooking) 100 100 RDF

(Kale)

Rape green PB Kale PDP 2006, 2007,

2008 802/36 0.0019 

### 0.83

(cooking) 100 100 RDF

(Kale)

Legume Vegetables Succulent and Dried(CG6) [CROP GROUP TOLERANCE EXISTS; except soybean]

Bean, seed /dry pea B Bean FT

LOD/tolerance (0.05

ppm) <0.05 0.025 < 2.5 5 0.00125

Bean, succulent PB Bean green PDP 1480/14 0.0017 < 2.5 5 RDF

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 12 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

2007, 2008 (Bean_Green_Fresh)

Total Samples=1480,

Total Detects=14,

Total LODs=60, Total

Zeros=1406

Bean, succulent,

babyfood PB Bean green baby food

PDP 2010, 2011 776/0 0.0014 < 2.5 5 RDF

(Bean_Green_BF)

Total Samples=776,

Total Detects=0,

Total LODs=39, Total

Zeros=737

Bean, succulent,

frozen PB Bean green frozen

PDP 2005 555/1 0.0023 < 2.5 5 RDF

( Bean_Green_Froze

n)

Total Samples=555,

Total Detects=1,

Total LODs=27, Total

Zeros=527

Bean, succulent,

canned PB Bean green canned

PDP 2003, 2004 928/0 0.0024 < 2.5 5 RDF

(Bean_Green_Canne

d)

Total Samples=928,

Total Detects=0,

Total LODs=46, Total

Zeros=882

Pea, snap PB Pea snap PDP 2011,

2012 1487/46 0.0015 100 100 RDF

(Pea_Snap)

Total Samples=1487,

Total Detects=46,

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 13 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

Total LODs=1441,

Total Zeros=0

Pea, snap, seed B Pea snap PDP 2011,

2012 1487/46 0.0015 100 100 0.0016

Pea, succulent

(sweet peas, fresh or

frozen) PB Pea sweet frozen

PDP 2006 744/0 0.0021 < 2.5 < 2.5 RDF

(Pea_Sweet_Frozen)

Total Samples=744,

Total Detects=0,

Total LODs=19, Total

Zeros=725

Pea, canned PB Pea sweet canned

PDP 2003, 2004 729/0 0.0019 < 2.5 < 2.5 RDF

(Pea_Sweet_Canned

)

Total Samples=729,

Total Detects=0,

Total LODs=18, Total

Zeros=711

Pea, baby food PB Pea sweet canned

PDP 2003, 2004 729/0 0.0019 < 2.5 < 2.5 RDF

(Pea_Sweet_Canned

)

Soybean B Soybean PDP 2011 300/8 0.0015 5 10 RDF

(Soybean_Grain)

Total Samples=300,

Total Detects=8,

Total LODs=22, Total

Zeros=270

Soybean, oil B Soybean PDP 2011 300/8 0.0015 0.14 5 10 0.00016

Fruiting Vegetable (CG8)

Pepper bell NB/PB Pepper bell PDP 1671/146 0.0086 <2.5 5 RDF

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 14 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

2010, 2011, 2012 (Pepper_Bell)

Total Samples=1671,

Total Detects=146,

Total LODs=0, Total

Zeros=1525

Pepper non

- bell NB/PB Pepper non

- bell PDP

2010, 2011 739/65 0.0014 <2.5 5 RDF

(Pepper_Nonbell)

Total Samples=739,

Total Detects=65,

Total LODs=0, Total

Zeros=674

Cucurbit Vegetables (CG9)

Cucumber NB/PB Cucumber PDP 2009,

2010 1488/50 0.0008 <2.5 5 RDF

(Cucumber)

Total Samples=1488,

Total Detects=50,

Total LODs=24, Total

Zeros=1414

Pumpkin NB/PB Winter Squash PDP

2011, 2012 928/4 0.003 0.32

(cooking) <2.5 5 RDF

(Squash_Winter_Fre

sh)

Total Samples=928,

Total Detects=4,

Total LODs=42, Total

Zeros=882

Pumpkin seed B Winter Squash PDP

2011, 2012 928/4 0.003 <2.5 5 0.0002

Citrus (CG10) [CROP GROUP TOLERANCE EXISTS]

Citron NB Orange PDP 2009, 1488/11 0.0014 100 100 RDF

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 15 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

2010 (Orangeto_othercitru

s)

Total Samples=1488,

Total Detects=11,

Total LODs= 1477

, Total Zeros=0

Citrus hydrid NB Orange PDP 2009,

2010 1488/11 0.0014 100 100 RDF

(Orangeto_othercitru

s

Grapefruit NB/PB Grapefruit PDP 2005,

2006 1485/24 0.0018 20 35 RDF

(Grapefruit)

Total Samples=1485,

Total Detects=24,

Total LODs=496,

Total Zeros=965

Grapefruit juice NB OJ PDP 2004, 2005,

2006 1517/4 0.002 1.17 20 35 RDF

(Orange_Juice)

Total Samples=1517,

Total Detects=4,

Total LODs=527,

Total Zeros=986

Kumquat PB Orange PDP 2009,

2010 1488/11 0.0014 100 100 RDF

(Orangeto_othercitru

s

Lemon NB/PB Orange PDP 2009,

2010 1488/11 0.0014 35 60 RDF

(Orangeto_lemon)

Total Samples=1488,

Total Detects=11,

Total LODs=882,

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 16 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

Total Zeros=595

Lemon juice PB OJ PDP 2004, 2005,

2006 1517/4 0.002 1.11 35 60 RDF

(Orange_Juiceto_Le

mon)

Total Samples=1517,

Total Detects=4,

Total LODs=906,

Total Zeros=611

Lemon peel PB Orange PDP 2009,

2010 1488/11 0.0014 15 35 60 RDF

(Orangeto_lemon)

Lime NB Orange PDP 2009,

2010 1488/11 0.0014 100 100 RDF

(Orangeto_othercitru

s

Lime juice PB OJ PDP 2004, 2005,

2006 1517/4 0.002 1.11 100 100 RDF

(Orange_Juiceto_Lim

e)

Total Samples=1517,

Total Detects=4,

Total LODs= 1530,

Total Zeros=0

Orange NB/PB Orange PDP 2009,

2010 1488/11 0.0014 20 35 RDF

(Orange)

Total Samples=1488,

Total Detects=11,

Total LODs=510,

Total Zeros=967

Orange juice PB OJ PDP 2004, 2005,

2006 1517/4 0.002 20 35 RDF

(Orange_Juice)

Total Samples=1517,

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 17 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

Total Detects=4,

Total LODs=527,

Total Zeros=986

Orange peel PB Orange PDP 2009,

2010 1488/11 0.0014 15 20 35 RDF

(Orange)

Pummelo NB Orange PDP 2009,

2010 1488/11 0.0014 100 100 RDF

(Orangeto_othercitru

s

Tangerine NB Tangerine PDP 2011,

2012 1426/4 0.005 10 20 RDF

(Tangerine)

Total Samples=1426,

Total Detects=4,

Total LODs=281,

Total Zeros=1141

Tangerine juice PB OJ PDP 2004, 2005,

2006 1517/4 0.002 1.28 10 20 RDF

(Orange_Juiceto_Ta

ngerine)

Total Samples=1517,

Total Detects=4,

Total LODs=299,

Total Zeros=1214

Pome Fruits (CG11)

Apple (unpeeled) NB/PB Apple PDP 2009,

2010 1488/19 0.0007 55 65 RDF

(Apple_Fresh)

Total Samples=1488,

Total Detects=19,

Total LODs=948,

Total Zeros=521

Apple (peeled) NB/PB Apple PDP 2009, 1488/19 0.0007 0.15 55 65 RDF

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 18 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

2010 (peeling

factor) (Apple_Fresh)

Apple, dried B Apple PDP 2009,

2010 1488/19 0.0007 1.2

55 65 0.0006

Apple juice PB Apple PDP 2009,

2010 1488/19 0.0007 0.15 55 65 RDF

(Apple_Fresh)

Apple sauce PB Apple sauce PDP

2006 714/0 0.001 55 65 RDF

(Apple_Sauce)

Total Samples=714,

Total Detects=0,

Total LODs=464,

Total Zeros=250

Apple, baby food PB Apple baby food PDP

2012 396/0 0.0005 55 65 RDF

(Apple_Sauce_BF)

Total Samples=396,

Total Detects=0,

Total LODs=257,

Total Zeros=139

Pear NB/PB Pear PDP 2009, 2010 1485/10 0.0015 0.15 15 30 RDF

(Pear )

Total Samples=1485,

Total Detects=10,

Total LODs=436,

Total Zeros=1039

Pear, dried B Pear PDP 2009, 2010 1485/10 0.0015 0.93 15 30 0.0005

Pear, baby food PB Pear baby food PDP

2010, 2011 776/0 0.0006 15 30 RDF

(Pear _BF)

T otal Samples=776,

Total Detects=0,

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 19 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

Total LODs=233,

Total Zeros=543

Pear, canned PB Pear canned PDP

1999, 2000 737/0 0.0023 15 30 RDF

(Pear_Canned)

Total Samples=737,

Total Detects=0,

Total LODs=221,

Total Zeros=516

Pear, juice PB Pear PDP 2009, 2010 1485/10 0.0015 0.15 15 30 RDF

(Pear )

Stone Fruit (CG12)

Cherry PB Cherry PDP 2007 419/0 0.0014 0.59

(canning)

1.16

(cooking) 30 45 RDF

(Cherry)

Total Samples=419,

Total Detects=0,

Total LODs=189,

Total Zeros=230

Cherry juice PB Cherry PDP 2007 419/0 0.0014 0.3 (grape

juice) 30 45 RDF

(Cherry)

Cherry baby food PB Cherry PDP 2007 419/0 0.0014 0.59

(canning)

1.16

(cooking) 30 45 RDF

(Cherry)

Nectarine NB Nectarine PDP 2007,

2008 1235/156 0.0025 10 20 RDF

(Nectarine)

Total Samples=1235,

Total Detects=156,

Total LODs=91, Total

Zeros=988

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 20 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

Peach NB/PB Peach PDP 2006,

2007, 2008 1261/218 0.0038 0.52

(canning)

0.50

(cooking) 25 40 RDF

(Peach_Fresh)

Total Samples=1261,

Total Detects=218,

Total LODs=286,

Total Zeros=757

Peach, dried B Peach PDP 2006,

2007, 2008 1261/218 0.0038 7.0 dried 25 40 0.0038

Peach, canned NB/PB Peach canned PDP

2003, 2004 1485/0 0.005 25 40 RDF

(Peach_Canned)

Total Samples=1485,

Total Detects=0,

Total LODs=594,

Total Zeros=891

Peach, baby food PB Peach baby food PDP

2012 777/4 0.0027 25 40 RDF

(Peach_BF)

Total Samples=777,

Total Detects=4,

Total LODs=307,

Total Zeros=466

Peach juice PB Peach canned PDP

2003, 2004 1485/0 0.005 25 40 RDF

(Peach_Canned)

Plum NB/PB Plum PDP 2011, 2012 840/12 0.003 10 15 RDF

(Plum)

Total Samples=840,

Total Detects=12,

Total LODs=114,

Total Zeros=714

Plum, baby food PB Plum PDP 2011, 2012 840/12 0.003 10 15 RDF

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 21 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

(Plum)

Prune, fresh NB Plum PDP 2011, 2012 840/12 0.003 10 15 RDF

(Plum)

Prune, dried PB Plum prune PDP

2005, 2006

377/0 0.0027 10 15 RDF

(Plum_Prune)

Total Samples=377,

Total Detects=0,

Total LODs=57, Total

Zeros=320

Prune juice PB Plum prune PDP

2005, 2006 377/0 0.0027 0.28 10 15 RDF

(Plum_Prune)

Berries (CG13)

Cranberry PB Cranberry PDP 2006 316/71 0.0023 100 100 RDF

(Cranberry)

Total Samples=316,

Total Detects=71,

Total LODs=245,

Total Zeros=0

Cranberry, dried PB Cranberry PDP 2006 316/71 0.0023 100 100 RDF

(Cranberry)

Cranberry, juice PB Cranberry PDP 2006 316/71 0.0023 0.3 (grape

juice) 100 100 RDF

(Cranberry)

Grape PB Grape PDP 2009,

2010 1489/17 0.0029 10 20 RDF

(Grape_Fresh)

Total Samples=1489,

Total Detects=17,

Total LODs=281,

Total Zeros=1191

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 22 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

Grape juice PB Grape juice PDP 2008 745/0 0.0029 10 20 RDF

(Grape_Juice)

Total Samples=745,

Total Detects=0,

Total LODs=149,

Total Zeros=596

Grape, raisin PB Grape raisin PDP

2006,2007 744/5 0.0026 10 20 RDF

(Grape_Raisin)

Total Samples=744,

Total Detects=5,

Total LODs=144,

Total Zeros=595

Grape, wine and

sherry PB Grape juice PDP 2008 745/0 0.0029 10 20 RDF

(Grape_Juice)

Kiwifruit NB Kiwifruit Tolerance

(2.0) NA NA 0.15

(peeling

factor) 1 2.5 RDF

(Kiwi )

TOTALZ=975

TOTALNZ=25

Strawberry PB Strawberry PDP 2008,

2009 1485/17 0.003 20 35 RDF

(Strawberry_Fresh)

Total Samples=1485,

Total Detects=17,

Total LODs=503,

Total Zeros=965

Strawberry, frozen PB Strawberry frozen

PDP 1998, 1999,

2000 155/0 0.0028 20 35 RDF

(Strawberry_Frozen)

Total Samples=155,

Total Detects=0,

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 23 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

Total LODs=54, Total

Zeros=101

Strawberry juice PB Strawberry PDP 2008,

2009 1485/17 0.003 0.3 (grape

juice) 20 35 RDF

(Strawberry_Fresh)

Tree Nuts (CG14)

Almond PB Almond PDP 2007,

2008 547/232 0.0005 25 40 RDF

(Almond)

Total Samples=547,

Total Detects=232,

Total LODs=0, Total

Zeros=315

Almond oil B Almond PDP 2007,

2008 547/232 0.0005 2.0 25 40 0.0018

Hazelnut (filbert) PB Almond PDP 2007,

2008

547/232 0.0005 15 25 RDF

(Almond)

Total Samples=547,

Total Detects=232,

Total LODs=0, Total

Zeros=315

Pecan PB Almond PDP 2007,

2008

547/232 0.0005 30 40 RDF

(Almond)

Total Samples=547,

Total Detects=232,

Total LODs=0, Total

Zeros=315

Walnut PB Almond PDP 2007,

2008

547/232 0.0005 45 55 RDF

(Almondto_walnut)

Total Samples=547,

Total Detects=232,

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 24 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

Total LODs=69, Total

Zeros=246

Cereal Grains (CG15)

Corn, field (bran, flour,

meal, starch) B Corn grain PDP 2007,

2008 1300/311 0.0005 0.22

(processing/

endosperm

washing) <2.5 5 0.0007

Corn, pop B Corn grain PDP 2007,

2008 1300/311 0.0005 <2.5 5 0.0007

Corn syrup B Corn Syrup PDP

1998, 1999 454/0 0.0005 <2.5 5 0.0005

Corn, sweet NB/PB Corn Sweet PDP

2008, 2009, 2010 1301/0 0.0065 10 20 RDF

(Corn_Sweet_Fresh)

Total Samples=1301,

Total Detects=0,

Total LODs=260,

Total Zeros=1041

Corn, sweet canned NB/PB Corn Sweet canned

PDP 2001, 2002 723/0 0.002 10 20 RDF

(Corn_Sweet_Canne

d)

Total Samples=723,

Total Detects=0,

Total LODs=145,

Total Zeros=578

Sorghum syrup B Wheat Grain PDP

2005, 2006 1361/8 0.003 0.05 <1 <2.5 0.0004

Wheat grain B Wheat Grain PDP

2005, 2006 1361/8 0.003 2.7 (germ)

3 (bran) 5* 10* RDF

(Wheat_Grain)

Total Samples=1361,

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 25 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

Total Detects=8,

Total LODs=1353,

Total Zeros=0

Wheat flour B Wheat Grain PDP

2005, 2006 1361/8 0.003 0.145 5 10 0.0031

Herbs and Spices (CG19)

Oilseeds

Cottonseed oil B Cotton FT (D21646) 0.375 <2.5 <2.5 0.003

Sunflower seed B Sunflower FT

( 

### D220463) 5/5 0.25 5 10 0.0012

Sunflower oil B Sunflower FT

( 

### D220463) 5/5 0.25 2.5 5 10 0.0012

Miscellaneous

Asparagus, fresh NB Asparagus PDP 2008,

2009, 2010 1488/41 0.0081 0.94

(cooking) 40 60 RDF

(Asparagus)

Total Samples=1488,

Total Detects=41,

Total LODs=852,

Total Zeros=595

Asparagus, frozen PB Asparagus PDP 2008,

2009, 2010 1488/41 0.0081 0.94

(cooking) 40 60 RDF

(Asparagus)

Asparagus, canned PB Asparagus canned

PDP 2003 354/6 0.0019 40 60 RDF

(Asparagus_Canned)

Total Samples=354,

Total Detects=6,

Total LODs=206,

Total Zeros=142

Banana PB Banana PDP 2012 559/1 0.0025 100 100 RDF

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 26 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

(Banana)

Total Samples=559,

Total Detects=1,

Total LODs=558,

Total Zeros=0

Banana, dried B Banana PDP 2012 559/1 0.0025 3.9 dried 100 100 0.0025

Banana baby food NB/PB Banana PDP 2012 559/1 0.0025 100 100 RDF

(Banana)

Fig NB Fig tolerance (0.01) NA NA 100 100 0.01

Peanut B Peanut FT 5/2 0.01 5 15 0.0011

Peanut oil B Peanut FT 5/2 0.01 2 5 15 0.0011

Peanut butter B Peanut butter PDP

2006 739/0 0.0135 5* 15* 0.014

Peppermint B Peppermint tops

tolerance (0.8) NA NA 100 100 0.8

Peppermint oil B Peppermint oil

tolerance (8.0) NA NA 100 100 8.0

Meat, Milk, Eggs

Beef, meat** NA Beef meat PDP 2009 292/0 0.0005 0.5

(cooking) 0.0005

Beef, meat, dried NA Beef meat PDP 2009 292/0 0.0005 1.92 0.0005

Beef, fat

NA Beef fat PDP 2009 292/0 0.0005 

### 0.5

0.0005

Beef (meat

byproducts, liver,

kidney) NA Beef liver PDP 2001,

2002 624/0 0.0014 

### 0.5

0.0014

Milk, fat NA Butter,cream PDP

2012 792/3 0.0005 RDF

(Milk_CreamButter)

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 27 of 53 Commodity DEEM Food

Form/

(Classification 1 ) Data Source No. of

Samples/

No. of

Detectable

Residues 1⁄2

LOQ/LOD

(ppm) Processing

Factors % CT Anticipated Residue

Estimates/Tolerance

(ppm)

Ave Max. Acute (and Steady

State)

(Tol., AR, or RDF

w/filename )

Total Samples=792,

Total Detects=3,

Total LODs=789,

Total Zeros=0

Milk, non

- fat (non

- fat

solids, water, sugar) NA Milk PDP 2011 743/0 0.0006 0

Pork, meat NA Pork meat PDP 2005 352/0 0.0004 0.5 0.00038

Pork, fat NA Pork fat PDP 2005 352/1 0.0007 0.5 RDF

(Pork_Fat)

Total Samples=352,

Total Detects=1,

Total LODs=351,

Total Zeros=0

Pork (meat

byproducts, liver,

kidney) NA Pork meat PDP 2005 352/0 0.0004 0.5 0.00038

Poultry, meat NA Chicken meat PDP

2006 1310/0 0.0008 0.5 0.00075

Poultry, fat NA Chicken fat PDP

2000, 2001 631/0 0.0049 0.5 0.0049

Poultry (meat

byproducts, liver,

kidney) NA Chicken meat PDP

2006 1310/0 0.0008 0.5 0.00075

Eggs NA Egg PDP 2010, 2011 742/0 0.0015 0.0015

NB= Not Blended; PB=Partially Blended; B=Blended



### * 100% CT assumed for blended commodities when using monitoring data for that specific commodity.

** Values for all beef commodities are applied to beef, goat, sheep, game

, and rabbit commodities.

### Page 28 of 53



## GENERAL RESIDUE INFORMATION:

Residue Distribution Files ( RDFs ) : RDFs were created where appropriate in accordance with

The US EPA , HED, DESAC guidance document for Dietary Exposure Analysis , November 2011.

T ranslation from commodities with monitoring data to other commodities were also performed

where appropriate in accordance w ith the 9/12/2012 USEPA SOP 2000.1 ( Guidance for

Translation of Field Trail Data from Representative Commodities in the Crop Group Regulation

to Other Commodities in Each Crop Group/Subgroup, HED Standard Operating Procedure

2000.1 )

. The section below brie fly summarizes the data source used per commodity. For details

regarding how RDFs were created with regard to number of actual detects, number and level of

1⁄2 LODs (for treated nondetects) and number of zeros (for untreated nondetects), and for the

percent crop treated estimates, and other assumptions such as peeling, cooking, or processing

factors, please see Table A1a above

. For full details on the source of the processing, peeling, and

cooking factors, see D388166, 2011.

Percent Crop Treated (%CT) : %CT estimates were taken from BEADs May 1, 2014 SLUA

report. A separate memorandum ( DP#345255, Addendum to the Screening Level Use Analysis

and Update to the Percent of Food Handling Establishments Treated Estimates

, full text found

in D388166, 2011 , Attac hment 3 ) details %CT estimates for food handling establishments and

kiwifruit. For the acute and steady state anticipated residues the maximum %CT estimates were

incorporated. A very conservative default 100% CT was assumed for commodities that do not

appear on BEADs SLUA report, unless otherwise stated. For crops reported as <2.5% treated,

the 2.5 value was used. %CT information, where appropriate, were incorporated into the RDF

construction and the point estimate residue calculations.

Residue Data So urce by Crop Group (CG)

Root and Tuber Vegetables ( CG 1)

PDP data exist only for sweet potatoes

. 2008

- 2010 PDP data for fresh sweet potatoes had

detectable residues. 2010

- 2011 PDP data for sweet po tato baby food had no detects. The fresh

sweet potato data were translated to radish root, rutabaga, turnip root and yam. RDFs were created

for these commodities

. For sweet potato baby food, the PDP data for the baby food was used to

create an RDF file. A peeling factor was used for fresh sweet potatoes and yams.

For sugar beets (consumed as processed blended commodities sugar and molasses), a processing

factor of 0.02 was applied to the tolerance of 1 ppm and corrected for 20% crop treated to come

up with a residue of 0.004 ppm (see D388166, 2011).

Leaves o f R oot and Tuber Vegetables (CG 2)

In the absence of a more appropriate source of data for root and tuber leaves, the PDP residue data

for kale (see leafy Brassica below) were translated to radish tops and turnip tops. This translation

should be very conservative as there were detectable residues on kale.

Bulb Vegetables (CG3)

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 29 of 53 

## PDP analyzed a total of 744 bulb onion samples in 2011 and 2012 with no detects. An RDF file

was created for bulb onions. A point estimate residue was created for the blended commodity dried

onion and a drying factor was used.

Brassica Cole Leafy Vegetables (CG5)

A crop group tolerance exists for chlorpyrifos on brassica c ole leafy vegetables (CG5) so all crops

in this group were included in the a nalysis. PDP data exist for broccoli, kale, cabbage, cauliflower

and collards (2006

- 2011) with detectable residues found on broccoli, kale, and collards. The

appropriate PDP data were translated to other cole commodities as follows: broccoli was translated

to Chinese broccoli and Chinese mustard cabbage; cabbage was translated to Brussels sprouts,

Chinese napa cabbage, and kohlrabi; kale was translated to broccoli rabi, Chinese bok choy

cabbage, mustard greens and rape greens. Cooking factors were applied t o the cooked food forms

in DEEM/Calendex

.

Legume Vegetables Succulents and Dried (CG6)

PDP data (2003

- 2011) were available for green beans (fresh, baby food, frozen and canned) with

detectable residues in fresh green beans. RDFs were created for individu al food forms.

PDP data (2011

- 2012) for snap peas, with detectable residues, were used to create an RDF for

snap peas and a point estimate for the blended commodity snap pea seed.

PDP data (2003

- 2 012) were available for sweet peas (frozen, canned, and baby food) with no

detectable residues. The frozen pea data were u sed to create RDFs for fresh and frozen peas. The

canned pea data were used to create RDFs for canned peas and for baby food. The baby food

data were not used because of the very high levels of detection in that dataset (LODs up to 0.15

ppm vs. up to 0.004 ppm for canned peas) . Using inflated LODs may miss actual residues and

can skew the exposure estimate (using inflated 1/2LODs in the RDF for treated nondetects ).

PDP data (2011) with detectable residues for soybeans were used to create an RDF for soybean

commodities and to create a point estimate for the blended commodity soybean oil.

For the blended commodity dry bean seed or dry pea, the tolerance for chlorpyrifos on dry beans

was u sed to calculate a point estimate residue . The tolerance is based on nondetectable residues

in the dry bean field trials.

Fruiting Vegetable (CG8)

PDP data (2010

- 2012) exist for both bell pepper and non

- bell pepper with detectable residues.

Individual RD Fs were created from these data for peppers.

Cucurbit Vegetables (CG9)

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 30 of 53 

## PDP data (2009

- 2012) are available for cucumbers and winter squash with detectable residues.

The cucumber data were used to create a cucumber RDF. The winter squash data were translat ed

to pumpkin. A cooking factor was applied to cooked pumpkin foods. The winter squash data

were also used to create a point estimate residue for the blended commodity pumpkin seed.

Citrus (CG10)

A crop group tolerance exists for chlorpyrifos on citrus (CG10 ) so all crops in this group were

included in the analysis. PDP data exist for oranges (2009

- 2010), grapefruit (2005

- 2006), tangerine

(2011

- 2012) and orange juice (2004

- 2006 and 2010

- 2012) with some detectable residues found

except in 2011

- 2012 orange juice. Orange data were translated to citron, citrus hybrid, kumquat,

lemon (and peel), lime, orange peel, and pummelo. Orange juice data were translated to other

juices using adjustment factors as spelled out in DESAC policy: 1.17 for grapefruit juice, 1 .11 for

lime juice and lemon juice and 1.28 for tangerine juice. The 2004

- 2006 orange juice data were

used as the 2010

- 2012 dataset had a high LOD value (up to 0.02 ppm vs. 0.004 ppm for 2004

- 06

dataset)

. Using inflated LODs may miss actual residues and can skew the exposure estimate (using

inflated 1/2LODs in the RDF for treated nondetects). RDFs were generated for all citrus

commodities. Drying factors were used for peels.

Pome Fruits (CG11)

There are PDP data for apples [ fresh (2009

- 2010) , apple sauc e (2006) and baby food (2012 ) and

apple juice (2007

- 2008) ] with detectable residues only in fresh apples. The fresh apple data were

used to create RDFs for apple and apple juice and a point estimate for dried apples (including a

drying factor)

. PDP analyze d a total of 740 apple juice samples during the years 2007

- 8. Of

these samples, none contained detectable residue levels. Since there were no detects the

estimated residues are based upon the LOD, not upon real residues, yet apple juice is a critical

com modity for exposure. Therefore the data (with actual residues) for the 2009

- 2010 apples

, along with a processing factor for juicing, was used for apple juice, which will yield a more

realistic estimate of the actual exposure. A peeling factor was applied to apples eaten peeled.

Apple sauce and apple baby food RDFs were based on their respective PDP data.

There are also PDP data for pears [fresh (2009

- 2010), canned (1999

- 2000), and baby food (2010

- 2011)]. The data were used to create RDFs for their respect ive food forms. In the case of pear

juice, the fresh pear data were used, with a juicing factor. There are PDP data for pear juice but

there was an insufficient number of samples. Fresh pear data were also used for dried along with

a drying factor. A peeli ng factor was used for fresh pears eaten peeled.

Stone Fruit (CG12)

PDP data are available for fresh cherries (2007) with no detects and were used to create RDFs

for cherry food commodities including cherry juice and cherry baby food, along with the

appropriate juicing, canning and cooking factors.

PDP data for nectarines (2007

- 2008), with detectable residues, were used for RDFs for nectarine

commodities.

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 31 of 53 

## PDP peach data [fresh (2006

- 2008), canned (2003

- 2004), and baby food (2012)] were used to

crea te RDFs for the respective peach food forms. Detectable residues were found in fresh

peaches and, to a lesser extent, peach baby food. Fresh peach data were used for a blended dried

peach point estimate residue , which incorporated a drying factor. Cooked fresh peaches included

a canning or cooking factor. Canned peach data were translated to peach juice.

There are PDP data for plums (2011

- 2012) with detectable residues and prunes (2005

- 2006) with

no detectable residues. These data were used to create RDFs for their respective food forms. The

prune data were used for prune juice with a factor applied.

Berries (CG13)

PDP data for fresh cranberries (2006) with detectable residues were used for RDFs for cranberry

foods, dried cranberry and cranberry juice. A juicing factor was applied.

There are PDP data for grape [fresh (2009

- 2010), juice (2008) and raisin (2006

- 2007) ] with

detectable residues in grape and raisin. The data were used to create RDFs for their respective

food forms. In addition, grape juice da ta were translated to wine and sherry.

For kiwifruit the tolerance level was used to create an RDF incorporating %CT. A peeling factor

was also applied.

There are PDP data for fresh strawberries (2008

- 2009) and frozen strawberries (1998

- 2000),

with detec table residues in fresh strawberries. RDFs were generated from the PDP data for the

respective food forms. Fresh strawberry data were also used for juice, with a juicing factor

applied.

Tree Nuts (CG14)

There are PDP data for almonds (2007

- 2008) with det ectable residues. The data were used to

create RDFs for almond, hazelnut, pecan and walnut. The data were also used to calculate a point

estimate residue for the blended commodity almond oil which included a processing factor.

Cereal Grains (CG15)

PDP data for corn grain (2007

- 2008), with detectable residues, were used to create point estimate

residues for field corn blended commodities such as meal, bran, flour and starch. A processing

(endosperm washing) factor was applied. The corn grain data wer e also used for popcorn. A

point estimate for corn syrup was also calculated based on PDP data for corn syrup (1998

- 1999)

with no detects.

There are also PDP data on sweet corn [fresh (2008

- 2010) and canned (2001

- 2002)] with no

detects. These data were u sed to create RDFs for the respective food forms.

The PDP data (2005

- 2006) for wheat grain, with detectable residues, were used to create RDFs

for wheat grain commodities. Processing factors were used for wheat germ and wheat bran. The

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 32 of 53 

## wheat grain data w ere used to calculate a point estimate residue for the blended commodity

wheat flour, along with a processing factor. Although PDP analyzed wheat flour samples dur ing

the years 2003

- 2004, none contai ned detectable residue levels. T he use of high LODs from

datasets would lead to an overestimate in actual exposure. The wheat grain data provides a more

realistic estimate o f residues on wheat flour

.

Wheat grain PDP data were also translated to sorghum syrup along with a processing factor.

Oilseeds

A p oint e stimate residue for cottonseed oil was calculated based on field trail data for cotton with

a processing factor applied. Sunflower field trial residues were used to calculate point estimate

residues for sunflower seeds and sunflower oil. A processing facto r was applied for oil.

Miscellaneous

PDP data are available for asparagus [fresh (200 8

- 2010) and canned (2003)] with detectable

residues and were used to generate RDFs for the respective food forms. A cooking factor was

applied to cooked asparagus.

PDP data are available for banana (2012) with one detectable residue. The data were used to

create RDFs for banana food forms including baby food. The data were also used to calculate a

point estimate residue for blended dried bananas along with a drying f actor.

For figs, the point estimate residue was based on the tolerance level for chlorpyrifos on figs.

For peanuts and peanut oil, the residues from the peanut field trials were used to generate point

estimate residue values. A processing factor was used for peanut oil. PDP data on peanut butter

(2006; no detectable residue) was used to generate point estimate value.

Tolerance level residues were assumed for peppermint and peppermint oil.

Meat, Milk, Eggs

PDP data (2009; no detects) for beef meat w ere used to calculate a point estimate for beef meat

and dried beef. PDP data for beef liver (2001

- 2002; no detects) were used to calculate point

estimates for beef meat byproducts, liver and kidney. The residue values for beef commodities

were also applie d to goat, sheep, game, and rabbit commodities.

PDP data for pork meat (2005; no detects) were used to calculate a point estimate for pork meat

and was also translated to pork meat byproducts, liver and kidney. PDP data for pork fat (2005;

one detect) wer e used to generate an RDF for pork fat.

PDP data for chicken meat (2006; no detects) were used to calculate a point estimate residue for

poultry meat and was translated to poultry meat byproducts, liver and kidney. PDP data for

chicken fat (2000

- 2001; no detects) were used to generate an RDF for poultry fat.

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 33 of 53 

## A cooking factor was applied to all cooked meat

- based food forms in DEEM/Calendex.

The PDP data for eggs (2010

- 2011; no detects) were used to calculate a point estimate residue.

The PDP data for but ter, cream (2012; three detects) were used to create an RDF for all milkfat

food forms.

For non

- fat milk (non

- fat solids, water, sugar) products residues were assumed to be all zero,

based upon no chlorpyrifos detections in thousands of samples in three sampling programs: a

market basket study performed by DAS, USDA PDP pesticide monitoring samples and in FDA

monitoring. In 2004

- 5 PDP tested 1485 milk samples and had no detects. In 2011 PDP tested

743 milk samples with no detects (LOD of 0.0012 ppm). In 2005 and 2007 PDP tested a total of

1011 samples of heavy cream (about 37% fat) with no detects at an LOD of 1 ppb. In 2003 PDP

tested 732 samples of butter (81% fat) with an LOD of 1.6 ppb and had one trace detect at 2.7

ppb. In 2012 there were three de tects out of 792 butter/cream samples (LOD of 1.2 ppb). We

note that chlorpyrifos is hydrophobic (log Ko/w = 4.7) and so is expected to concentrate in the

fatty (butter, heavy cream) portions of milk. Thus there is strong evidence that no residues (or

vir tually none) occur in lower fat milk products.

Attachment 2

. PDP F indings of Residues (2009

- 2012*) on Crops for Which Chlorpyrifos is

Not Registered.

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 34 of 53 

## Table A2.

YEAR COMMODITY

NAME 1 Number

of

Samples

Tested Number of

Samples with

Measurable

Residues %

Detects Minimum

Concentration

Determined

(ppm) Maximum

Concentration

Determined

(ppm) Average

Concentration

for Detects

(ppm) Ave

half

LOD

2010

-

2012 Cantaloupe 1482 3 0.2 0.005 0.014 0.008 0.004

2008

-

2010 Catfish 1479 105 7 0.0034 0.04 0.004 0.0005

2009

-

2010 Cilantro 739 218 29 0.022 0.67 0.017 0.0006

2009 Green onions 558 7 1.3 0.002 0.067 0.02 0.0006

2010

-

2011 Lettuce 1487 2 0.1 0.002 0.078 0.074 0.0012

2010 Mango 372 1 0.3 0.005 0.005 0.005 0.0015

2009 Spinach 744 15 2 0.0035 0.061 0.01 0.0016

2010

-

2011 Spinach, frozen 389 4 1 0.024 0.031 0.026 0.01

2012 Summer squash 186 1 0.5 0.02 0.02 0.02 0.02

2011

-

2012 Tomato, cherry 1466 13 0.9 0.005 0.047 0.011 0.0015

*2008

- 201 2 for catfish

1 there are no tolerances for residues of chlorpyrifos on these commodities



## Attachment 3

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 35 of 53 

### Date: May 1, 2014

Screening Level Estimates of Agricultural Uses of Chlorpyrifos (059101)

Sorted Alphabetically

Reporting Years: 2004

- 2012

Average Percent Crop Treated

Crop Lbs. A.I. Average Maximum

1 Alfalfa 500,000 5 10

2 Almonds 400,000 25 40

3 Apples 300,000 55 65

4 Asparagus 20,000 40 60

5 Beans, Green 3,000 <2.5 5

6 Broccoli 90,000 45 60

7 Brussels Sprouts* 4,000 NC NC

8 Cabbage 10,000 15 25

9 Canola 40,000 10 10

10 Cantaloupes+ 2,000 <2.5 5

11 Cauliflower 20,000 40 60

12 Cherries 70,000 30 45

13 Corn 1,400,000 <2.5 5

14 Corn (Seed Treatment) <500 <1 <2.5

15 Cotton 90,000 <2.5 <2.5

16 Cotton (Seed Treatment) 1,000 <2.5 5

17 Cucumbers 3,000 <2.5 5

18 Dry Beans/Peas 9,000 <2.5 5

19 Grapefruit 50,000 20 35

20 Grapes 200,000 10 20

21 Hazelnuts 7,000 15 25

22 Lemons 80,000 35 60

23 Lettuce+ 4,000 <2.5 <2.5

24 Nectarines 8,000 10 20

25 Onions 60,000 40 50

26 Oranges 500,000 20 35

27 Peaches 60,000 25 40

28 Peanuts 200,000 5 15

29 Pears 20,000 15 30

30 Peas, Green 2,000 <2.5 <2.5

31 Pecans 300,000 30 40

32 Peppers 2,000 <2.5 5

33 Pistachios+ 2,000 <2.5 <2.5

34 Plums/Prunes 20,000 10 15

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 36 of 53 35 Potatoes 3,000 <1 <2.5

36 Pumpkins 2,000 <2.5 5

37 Sorghum 10,000 <1 <2.5

38 Sorghum (Seed Treatment) <500 <1 <2.5

39 Soybeans 1,500,000 5 10

40 Soybeans (Seed Treatment) <500 <1 <2.5

41 Squash+ 1,000 <2.5 5

42 Strawberries 10,000 20 35

43 Sugar Beets 100,000 10 20

44 Sunflowers 50,000 5 10

45 Sweet Corn 100,000 10 20



## 46 Tangelos 2,000 10 15



## 47 Tangerines 7,000 10 20



## 48 Tobacco 80,000 15 20



## 49 Tomatoes+ 3,000 <2.5 <2.5



## 50 Walnuts 400,000 45 55



## 51 Watermelons+ 1,000 <2.5 <2.5



## 52 Wheat 400,000 5 10



## 53 Wheat (Seed Treatment) <500 <1 <2.5

All numbers are rounded.

<500: less than 500 pounds of active ingredients.

<2.5: less than 2.5 percent of crop is treated.

<1: less than 1 percent of crop is treated.

* Based on CA DPR data only (80% or more of U.S. acres grown are in California)

NC: not calculated, only pounds a.i. available.

+: Crops not known to be listed on active end use product registrations or as Section 18 emergency

exemptions when this report was run.

SLUA data sources include:

USDA

- NASS (United States Department of Agriculture's National Agricultural Statistics Service)

Private Pesticide Market Research

California DPR (Department of Pesticide Regulation)

These results reflect amalgamated data developed by the Agency and are rel easable to the public.



## Attachment 4

. Acute (and Steady State) Residue Input file

Filename: C: \ Users \ ddrew \ Documents \ DEEM_Version_3_16 \ ResidueFiles \ Scenario1 \ Chlorpyrifos_FoodOnly

noFHE.R08

Chemical: Chlorpyrifos (Parent Only)

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 37 of 53 RfD(Chronic): .00003 mg/kg bw/day NOEL(Chronic): .03 mg/kg bw/day [Note: placeholder only, not

used]

RfD(Acute): .00036 mg/kg bw/day NOEL(Acute): .36 mg/kg bw/day [Note: placeholder only, not

used]

Date created/last modified: 08

- 18

- 2014/10:54:45 Program ver. 3.16, 03

- 08

- d

Comment: chlorpyrifos (parent only); food only (no FHE)

----------------------------------------------------------------------------------- RDL indices and parameters for Monte Carlo Analysis:

Index Dist Parameter #1 Param #2 Param #3 Comment

# Code

----- ---- ------------ -------- -------- ------- 1 6 Potato_Sweet.rdf

2 6 Potato_Sweet_BF.rdf

3 6 Onion_Bulb.rdf

4 6 Broccolito_chinese.rdf

5 6 Cabbageto_sprouts_napa_kohlrabi.rdf

6 6 Broccol i.rdf

7 6 Cabbage.rdf

8 6 Cauliflower.rdf

9 6 Collards.rdf

10 6 Kale.rdf

11 6 Soybean_Grain.rdf

12 6 Bean_Green_Fresh.rdf

13 6 Bean_Green_Frozen.rdf

14 6 Bean_Green_Canned.rdf

15 6 Bean_Green_BF.rdf

16 6 Pea_Snap.rdf

17 6 Pea_Sweet_Frozen.rdf

18 6 Pea_Sweet_Canned.rdf

19 6 Pea_BF.rdf

20 6 Bean_Garbanzo.rdf

21 6 Pepper_Bell.rdf

22 6 Pepper_Nonbell.rdf

23 6 Cucumber.rdf

24 6 Squash_Winter_Fresh.rdf

25 6 Orangeto_othercitrus.rdf

26 6 Orangeto_lemon.rdf

27 6 Orange_Juiceto_tangerine.rdf

28 6 Orange_Juiceto_lemon.rdf

29 6 Orange_Juiceto_lime.rdf

30 6 Grapefruit.rdf

31 6 Orange.rdf

32 6 Orange_Juice.rdf

33 6 Tangerine.rdf

34 6 Apple_Fresh.rdf

35 6 Apple_Juice.rdf

36 6 Apple_Sauce.rdf

37 6 Pear.rdf

38 6 Pear_Canned.rdf

39 6 Pear_BF.rdf

40 6 Pear_Juice.rdf

41 6 Cherry.rdf

42 6 Nectarine.rdf

43 6 Peach_Fresh.rdf

44 6 Peach_Canned.rdf

45 6 Plum.rdf

46 6 Plum_Prune.rdf

47 6 Apple_Sauce_BF.rdf

48 6 Almond.rdf

49 6 Almondto_walnut.rdf

50 6 Peach_BF.rdf

51 6 Corn_Sweet_Fresh.rdf

52 6 Corn_Sweet_F rozen_Cooked.rdf

53 6 Corn_Sweet_Canned.rdf

54 6 Wheat_Grain.rdf

55 6 Wheat_Flour.rdf

56 6 Pork_Fat.rdf

57 6 Milk.rdf

58 6 Chicken_Meat.rdf

59 6 Asparagus.rdf

60 6 Asparagus_Canned.rdf

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 38 of 53 61 6 Banana.rdf

62 6 Cranberry.rdf

63 6 Grape_Fresh.rdf

64 6 Grape_Juice.rdf

65 6 Grape_Raisin.rdf

66 6 PeanutButter.rdf

67 6 Strawberry_Fresh.rdf

68 6 Strawberry_Frozen.rdf

69 6 Milk_CreamButter.rdf

70 6 kiwi.rdf

EPA Crop Commodity Name Def Res Adj.Factors RDLComment

Code Grp (ppm) #1 #2 Pntr

---------- ---- ------------------------------- ---------- ------ ------ --- -------

01010 52000 1A Beet, sugar 0.004000 1.000 1.000

0101052001 1A Beet, sugar

- babyfood 0.004000 1.000 1.000

0101053000 1A Beet, sugar, molasses 0.004000 1.000 1.000

0101053001 1A Be et, sugar, molasses

- babyfood 0.004000 1.000 1.000

0101314000 1AB Radish, roots 1.000000 1.000 1.000 1 Potato

Full comment: Potato_Sweet.rdf

0101327000 1AB Rutabaga 1.000000 1.000 1. 000 1 Potato

Full comment: Potato_Sweet.rdf

0101388000 1AB Turnip, roots 1.000000 1.000 1.000 1 Potato

Full comment: Potato_Sweet.rdf

0103366000 1CD Sweet potato

210

- Cooked; Fresh or N/S; Cook Meth N/S

1.000000 0.150 1.000 1 Potato

Full comment: Potato_Sweet.rdf

211

- Cooked; Fresh or N/S; Baked

1.000000 0.150 1.000 1 Potato

Full comment: Potato_Sweet.rdf

212

- Cooked; Fresh or N/S; Boiled

1.000000 0.150 1.000 1 Potato

Full comment: Potato_Sweet.rdf

213

- Cooked; Fresh or N/S; Fried

1.000000 0.150 1.000 1 Potato

Full comment: Potato_Sweet.rdf

215

- Cooked; Fres h or N/S; Boiled/baked

1.000000 0.150 1.000 1 Potato

Full comment: Potato_Sweet.rdf

240

- Cooked; Canned; Cook Meth N/S

1.000000 0.150 1.000 1 Potato

Full comment: Potato_Sweet.rdf

242

- Cooked; Canned; Boiled 1.000000 0.150 1.000 1 Potato

Full comment: Potato_Sweet.rdf

0103366001 1CD Sweet potato

- babyfood

211

- Cooked; Fresh or N/S; Baked

1.000000 1.000 1.000 2 Potato

Full comment: Potato_Sweet_BF.rdf

240

- Cooked; Canned; Cook Meth N/S

1.000000 1.000 1.000 2 Potato

Full comment: Potato_Sweet_BF.rdf

0103406000 1CD Yam, true 1.000000 0.150 1.000 1 Potato

Full comment: Potato_Sweet.rdf

0200315000 2 Radish, tops 1.000000 1.000 1.000 10 Kale.r

Full comment: Kale.rdf

0301165000 3A Garlic, bulb 1.000000 1.000 1.000 3 Onion_

Full comment: Onion_Bulb.rdf

0301165001 3A Garlic, bulb

- babyfood 1.000000 1.000 1.000 3 Onion_

Full comment: Onion_Bulb.rdf

0301237000 3A Onion, bulb 1.000000 1.000 1.000 3 Onion_

Full comment: Onion_Bulb.rdf

0301237001 3A Onion, bulb

- babyfood 1.000000 1.00 0 1.000 3 Onion_

Full comment: Onion_Bulb.rdf

0301238000 3A Onion, bulb, dried 0.003900 9.000 1.000

0301238001 3A Onion, bulb, dried

- babyfood 0.003900 9.000 1.000

0301338000 3A Shallot, bulb 1.000000 1.000 1.000 3 Onion_

Full comment: Onion_Bulb.rdf

0501061000 5A Broccoli

110

- Uncooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 6 Brocco

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 39 of 53 Full comment: Broccoli.rdf

210

- Cooked; Fresh or N/S; Cook Meth N/S

1.000000 0.940 1.000 6 Brocco

Full comment: Broccoli.rdf

211

- Cooked; Fres h or N/S; Baked

1.000000 0.940 1.000 6 Brocco

Full comment: Broccoli.rdf

212

- Cooked; Fresh or N/S; Boiled

1.000000 0.940 1.000 6 Brocco

Full comment: Broccoli.rdf

213

- Cooked; Fresh or N/S; Fried

1.000000 0.940 1.000 6 Brocco

Full comment: Broccoli.rdf

220

- Cooked; Frozen; Cook Meth N/S

1.000000 0.940 1.000 6 Brocco

Full comment: Broccoli.rdf

221

- Cooked; Frozen; Baked 1.000000 0.940 1.000 6 Brocco

Full comment: Broccoli.rdf

222

- Cooked; Frozen; Boiled 1.000000 0.940 1.000 6 Brocco

Full comment: Broccoli.rdf

232

- Cooked; Dried; Boiled 1.000000 0.940 1.000 6 B rocco

Full comment: Broccoli.rdf

242

- Cooked; Canned; Boiled 1.000000 0.940 1.000 6 Brocco

Full comment: Broccoli.rdf

0501061001 5A Broccoli

- babyfood 1.000000 0.940 1.000 6 Brocc o

Full comment: Broccoli.rdf

0501062000 5A Broccoli, Chinese 1.000000 0.940 1.000 4 Brocco

Full comment: Broccolito_chinese.rdf

0501064000 5A Brussels sprouts

110

- Uncooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 5

212

- Cooked; Fresh or N/S; Boiled

1.000000 0.830 1.000 5

222

- Cooked; Frozen; Boil ed 1.000000 0.830 1.000 5

0501069000 5A Cabbage

110

- Uncooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 7 Cabbag

Full comment: Cabbage.rdf

150

- Uncooked; Cured etc; Cook Meth N/S

1.000000 1.000 1.000 7 Cabbag

Full comment: Cabbage.rdf

210

- Cooked; Fresh or N/S; Cook Meth N/S

1.000000 0.830 1.000 7 Cabbag

Full comment: Cabbage.rdf

211

- Cooked; Fresh or N/S; Baked

1.000000 0.830 1.000 7 Cabbag

Full comment: Cabbage.rdf

212

- Cooked; Fresh or N/S; Boiled

1.000000 0.830 1.000 7 Cabbag

Full comment: Cabbage.rdf

213

- Cooked; Fre sh or N/S; Fried

1.000000 0.830 1.000 7 Cabbag

Full comment: Cabbage.rdf

221

- Cooked; Frozen; Baked 1.000000 0.830 1.000 7 Cabbag

Full comment: C abbage.rdf

230

- Cooked; Dried; Cook Meth N/S

1.000000 0.830 1.000 7 Cabbag

Full comment: Cabbage.rdf

232

- Cooked; Dried; Boiled 1.000000 0.830 1.000 7 Cabbag

Full comment: Cabbage.rdf

240

- Cooked; Canned; Cook Meth N/S

1.000000 0.830 1.000 7 Cabbag

Full comment: Cabbage.rdf

24 2

- Cooked; Canned; Boiled 1.000000 0.830 1.000 7 Cabbag

Full comment: Cabbage.rdf

245

- Cooked; Canned; Boiled/baked

1.000000 0.830 1.000 7 Cabbag

F ull comment: Cabbage.rdf

250

- Cooked; Cured etc; Cook Meth N/S

1.000000 0.830 1.000 7 Cabbag

Full comment: Cabbage.rdf

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 40 of 53 255

- Cooked; Cured etc; Boiled/baked

1.000000 0.830 1.000 7 Cabbag

Full comment: Cabbage.rdf

0501071000 5A Cabbage, Chinese, napa

110

- Uncooked; Fres h or N/S; Cook Meth N/S

1.000000 1.000 1.000 5 Cabbag

Full comment: Cabbageto_sprouts_napa_kohlrabi.rdf

150

- Uncooked; Cured etc; Cook Meth N/S

1.000000 1.000 1.000 5 Cabbag

Full comment: Cabbageto_sprouts_napa_kohlrabi.rdf

210

- Cooked; Fresh or N/S; Cook Meth N/S

1.000000 0.830 1.00 0 5 Cabbag

Full comment: Cabbageto_sprouts_napa_kohlrabi.rdf

213

- Cooked; Fresh or N/S; Fried

1.000000 0.830 1.000 5 Cabbag

Full comment: Cabbageto_sprout s_napa_kohlrabi.rdf

221

- Cooked; Frozen; Baked 1.000000 0.830 1.000 5 Cabbag

Full comment: Cabbageto_sprouts_napa_kohlrabi.rdf

0501072000 5A Cabbage, Chinese, mustard

110

- Uncooked; Fresh or N/S ; Cook Meth N/S

1.000000 1.000 1.000 4 Brocco

Full comment: Broccolito_chinese.rdf

150

- Uncooked; Cured etc; Cook Meth N/S

1.000000 1.000 1.000 4 Brocco

Full comment: Broccolito_chinese.rdf

210

- Cooked; Fresh or N/S; Cook Meth N/S

1.000000 0.940 1.000 4 Brocco

Full comment: Broccolito_chinese.rdf

213

- Cooked; Fresh or N/S; Fried

1.000000 0.940 1.000 4 Brocco

Full comment: Broccolito_chinese.rdf

2 21

- Cooked; Frozen; Baked 1.000000 0.940 1.000 4 Brocco

Full comment: Broccolito_chinese.rdf

0501083000 5A Cauliflower

110

- Uncooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 8 Caulif

Full comment: Cauliflower.rdf

150

- Uncooked; Cured etc; Cook Meth N/S

1.000000 1.000 1.000 8 Caulif

Full comment: Caulifl ower.rdf

210

- Cooked; Fresh or N/S; Cook Meth N/S

1.000000 0.940 1.000 8 Caulif

Full comment: Cauliflower.rdf

211

- Cooked; Fresh or N/S; Baked

1.000000 0.940 1.000 8 Caulif

Full comment: Cauliflower.rdf

212

- Cooked; Fresh or N/S; Boiled

1.000000 0.940 1.000 8 Cau lif

Full comment: Cauliflower.rdf

213

- Cooked; Fresh or N/S; Fried

1.000000 0.940 1.000 8 Caulif

Full comment: Cauliflower.rdf

221

- Cooked; Frozen; Baked 1.000000 0.940 1.000 8 Caulif

Full comment: Cauliflower.rdf

222

- Cooked; Frozen; Boiled 1.000000 0.940 1.000 8 Caulif

Full comment: Cauliflower.rdf

242

- Cooked; Canned; Boiled 1.000000 0.940 1.000 8 Caulif

Full comment: Cauliflower.rdf

250

- Cooked; Cured etc; Cook Meth N/S

1.000000 0.940 1. 000 8 Caulif

Full comment: Cauliflower.rdf

0501196000 5A Kohlrabi 1.000000 0.830 1.000 5 Cabbag

Full comment: Cabbageto_sprouts_napa_kohlrabi.rfd

0502063000 5B Broccoli raab 1.0000 00 0.830 1.000 10 Kale.r

Full comment: Kale.rdf

0502070000 5B Cabbage, Chinese, bok choy

110

- Uncooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 10 Kale.r

Full comment: Kale.rdf

150

- Uncooked; Cured etc; Cook Meth N/S

1.000000 1.000 1.000 10 Kale.r

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 41 of 53 Full comment: Kale.rdf

210

- Cooked; Fresh or N/S; Cook Meth N/S

1.000000 0.830 1.000 10 Kale.r

Full comment: Kale.rdf

213

- Cooked; Fresh or N/S; Fried

1.000000 0.830 1.00 0 10 Kale.r

Full comment: Kale.rdf

221

- Cooked; Frozen; Baked 1.000000 0.830 1.000 10 Kale.r

Full comment: Kale.rdf

0502117000 5B Collards

110

- Uncooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 9 Collar

Full comment: Collards.rdf

212

- Cooked; Fresh or N/S; Boiled

1.000000 0.830 1.000 9 Collar

Full comment: Collards.rdf

222

- Cooked; Frozen; Boiled 1.000000 0.830 1.000 9 Collar

Full comment: Collards.rdf

242

- Cooked; Canned; Boiled 1.000000 0.830 1.000 9 Collar

Full comment: Collards.rdf

0502194000 5B Kale

212

- Cooked; Fresh or N/S; Boiled

1.000000 0.830 1.000 10 Kale.r

Full comment: Kale.rdf

222

- Cooked; Frozen; Boiled 1.000000 0.830 1.000 10 Kale.r

Full comment: Kale.rdf

242

- Cooked; Canned; Boiled 1.000000 0.830 1.00 0 10 Kale.r

Full comment: Kale.rdf

0502229000 5B Mustard greens

110

- Uncooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 10 Kale.r

Full comment: Ka le.rdf

212

- Cooked; Fresh or N/S; Boiled

1.000000 0.830 1.000 10 Kale.r

Full comment: Kale.rdf

222

- Cooked; Frozen; Boiled 1.000000 0.830 1.000 10 Kale.r

Full comment: Kale.rdf

242

- Cooked; Canned; Boiled 1.000000 0.830 1.000 10 Kale.r

Full comment: Kale.rdf

0502318000 5B Rape greens 1.000000 0.830 1.000 10 Kale.r

Full comment: Kale.rdf

0502389000 5B Turnip, greens 1.000000 1.000 1.000 10 Kale.r

Full comment: Kale.rdf

0600347000 6 Soybean, seed 1.000000 1.000 1.000 11 Soybea

Full comment: Soybean_Grain.rdf

0600349000 6 Soybean, soy milk 1.000000 1.000 1.000 11 Soybea

Full comment: Soybean_Grain.rdf

0600349001 6 Soybean, soy milk

- babyfood or in 1.000000 1.000 1.000 11 Soybea

Full c omment: Soybean_Grain.rdf

0600350000 6 Soybean, oil 1.000000 0.140 1.000 11 Soybea

Full comment: Soybean_Grain.rdf

0600350001 6 Soybean, oil

- babyfood 1.000000 0.140 1.000 11 Soybea

Full comment: So ybean_Grain.rdf

0601043000 6A Bean, snap, succulent

110

- Uncooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 12 Bean_G

Full comment: Bean_Green_Fresh.rdf

210

- Cooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 12 Bean_G

Full comment: Bean_Green_Fresh.rdf

211

- Cooked; Fresh or N/S; Baked

1.000000 1.000 1.000 12 Bean_G

Full comment: Bean_Green_Fresh.rdf

212

- Cooked; Fresh or N/S; Boiled

1.000000 1.000 1.000 12 Bean_G

Full comment: Bean_Green_Fresh.rdf

213

- Cooked; Fresh or N/S; Fried

1.000000 1.000 1.000 12 Bean_G

Full comment: Bean_Green_Fresh.rdf

215

- Coo ked; Fresh or N/S; Boiled/baked

1.000000 1.000 1.000 12 Bean_G

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 42 of 53 Full comment: Bean_Green_Fresh.rdf

220

- Cooked; Frozen; Cook Meth N/S

1.000000 1.000 1.000 12 Bean_G

Full comment: Bean_Green_Fresh.rdf

221

- Cooked; Frozen; Baked 1.000000 1.000 1.000 13 Bean_G

Full comment: Bean_Gree n_Frozen.rdf

222

- Cooked; Frozen; Boiled 1.000000 1.000 1.000 13 Bean_G

Full comment: Bean_Green_Frozen.rdf

232

- Cooked; Dried; Boiled 1.000000 1.000 1.000 12 Bean_G

Full comm ent: Bean_Green_Fresh.rdf

240

- Cooked; Canned; Cook Meth N/S

1.000000 1.000 1.000 14 Bean_G

Full comment: Bean_Green_Canned.rdf

242

- Cooked; Canned; Boi led 1.000000 1.000 1.000 14 Bean_G

Full comment: Bean_Green_Canned.rdf

0601043001 6A Bean, snap, succulent

- babyfood 1.000000 1.000 1.000 15 Bean_G

Full comment: Bean_Green_BF.rdf

0601257000 6A Pea, edible podded, succ ulent 1.000000 1.000 1.000 17 Pea_Sw

Full comment: Pea_Sweet_Frozen.rdf

0601349500 6AB Soybean, vegetable 1.000000 1.000 1.000 11 Soybea

Full comment: Soybean_Grain.rdf

0602031000 6B Bean, broad, succulent 1.000000 1.000 1.000 12 Bean_G

Full comment: Bean_Green_Fresh.rdf

0602033000 6B Bean, cowpea, succulent 1.000000 1.000 1.000 20 Bean_G

Full comment: Bean_Garbanzo.rdf

0602037000 6B Bean, lima, succulent

210

- Cooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 12 Bean_G

Full comment: Bean_Green_Fresh.rdf

212

- Cooked; Fresh or N/S; Boiled

1.000000 1.000 1.000 12 Bean_G

Full comment: Bean_Green_Fresh.rdf

213

- Cooked; Fresh or N/S; Fried

1.000000 1.000 1. 000 12 Bean_G

Full comment: Bean_Green_Fresh.rdf

220

- Cooked; Frozen; Cook Meth N/S

1.000000 1.000 1.000 12 Bean_G

Full comment: Bean_Green_Fresh.rdf

221

- Cooked; Frozen; Baked 1.000000 1.000 1.000 13 Bean_G

Full comment: Bean_Green_Frozen.rdf

222

- Cooked; Frozen; Boiled 1.000000 1.000 1.000 13 Bean_G

Full comment: Bean_Green_Fro zen.rdf

240

- Cooked; Canned; Cook Meth N/S

1.000000 1.000 1.000 14 Bean_G

Full comment: Bean_Green_Canned.rdf

242

- Cooked; Canned; Boiled 1.000000 1.000 1.000 14 Bean_G

Full comment: Bean_Green_Canned.rdf

0602255000 6B Pea, succulent

110

- Uncooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 17 Pea_Sw

Full comment: Pea_Sweet_Frozen.rdf

210

- Cooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 17 Pea_Sw

Full comment: Pea_Sweet_Frozen.rdf

211

- Cooked; Fresh or N/S; Baked

1.000000 1.000 1.000 17 Pea_Sw

Full comment: Pea_Sweet_Frozen.rdf

212

- Cooked; Fresh or N/S; Boiled

1.000000 1.000 1.000 17 Pea_Sw

Full comment: Pea_Sweet_Frozen.rdf

213

- Cooked; Fresh or N/S; Fried

1.000000 1.000 1. 000 17 Pea_Sw

Full comment: Pea_Sweet_Frozen.rdf

221

- Cooked; Frozen; Baked 1.000000 1.000 1.000 17 Pea_Sw

Full comment: Pea_Sweet_Frozen.rdf

222

- Cooked; Frozen; Boiled 1.000000 1.000 1.000 17 Pea_Sw

Full comment: Pea_Sweet_Frozen.rdf

232

- Cooked; Dried; Boiled 1.000000 1.000 1.000 17 Pea_Sw

Full comment: Pea_Sweet_Frozen.rdf

240

- Cooked; Canned; Cook Met h N/S

1.000000 1.000 1.000 18 Pea_Sw

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 43 of 53 Full comment: Pea_Sweet_Canned.rdf

242

- Cooked; Canned; Boiled 1.000000 1.000 1.000 18 Pea_Sw

Full comment: Pea _Sweet_Canned.rdf

0602255001 6B Pea, succulent

- babyfood 1.000000 1.000 1.000 18 Pea_Sw

Full comment: Pea_Sweet_canned.rdf

0602259000 6B Pea, pigeon, succulent

212

- Cooked; Fresh or N/S; Boiled

1.000000 1.000 1.000 18 Pea_Sw

Full comment: Pea_Sweet_Canned.rdf

242

- Cooked; Canned; Boiled 1.000000 1.000 1.000 18 Pea_Sw

Full comment: Pea_Sweet_Canned.rdf

060303000 0 6C Bean, black, seed 0.001250 1.000 1.000

0603032000 6C Bean, broad, seed 0.001250 1.000 1.000

0603034000 6C Bean, cowpea, seed 0.001250 1.000 1.000

0603035000 6C Bean, great northern, seed 0.001250 1.000 1.000

0603036000 6C Bean, kidney, seed 0.001250 1.000 1.000

0603038000 6C Bean, lima, seed 0.001250 1.000 1.000

0603039000 6C Bean, mung, seed 0.001250 1.000 1.000

0603040000 6C Bean, navy, seed 0.001250 1.000 1.000

0603041000 6C Bean, pink, seed 0.001250 1.000 1.000

0603042000 6C Bean, pinto, seed 0.001250 1.000 1.000

0603098000 6C Chickpea, seed 0.001250 1.000 1.000

0603098001 6C Chickpea, seed

- babyfood 0.001250 1.000 1.000

0603099000 6C Chickpea, flour 0.001250 1.000 1.000

0603182000 6C Guar, seed 0.001250 1.000 1.000

0603182001 6C Guar, seed

- babyfood 0.001250 1.000 1.000

0603203000 6C Lentil, seed 0.001250 1.000 1.000

0603256000 6C Pea, dry 0.001250 1.000 1.000

0603256001 6C Pea, dry

- babyfood 0.001250 1.000 1.000

0603258000 6C Pea, pigeon, seed 0 .001250 1.000 1.000

0603348000 6C Soybean, flour 1.000000 1.000 1.000 11 Soybea

Full comment: Soybean_Grain.rdf

0603348001 6C Soybean, flour

- babyfood 1.000000 1.000 1.000 11 Soybea

Full comment: Soybean_Grain.rdf

0802270000 8B Pepper, bell 1.000000 1.000 1.000 21 Pepper

Full comment: Pepper_Bell.rdf

0802270001 8B Pepper, bell

- babyfood 1.000000 1.000 1.000 21 Pepper

Full comment: Pepper_Bell .rdf

0802271000 8B Pepper, bell, dried 1.000000 1.000 1.000 21 Pepper

Full comment: Pepper_Bell.rdf

0802271001 8B Pepper, bell, dried

- babyfood 1.000000 1.000 1.000 21 Pepper

Full comment: Pepper_Bell.rdf

080227200 0 8BC Pepper, nonbell 1.000000 1.000 1.000 22 Pepper

Full comment: Pepper_Nonbell.rdf

0802272001 8BC Pepper, nonbell

- babyfood 1.000000 1.000 1.000 22 Pepper

Full comment: Pepper_Nonbell.rdf

0802273000 8BC Pepper, nonbell, dried 1.000000 1.000 1.000 22 Pepper

Full comment: Pepper_Nonbell.rdf

0902135000 9B Cucumber 1.000000 1.000 1.000 23 Cucumb

Full comment: Cucumber.rdf

0902308000 9B Pumpkin 1.000000 0.320 1.000 24 Squash

Full comment: Squash_Winter_Fresh.rdf

0902309000 9B Pumpkin, seed 0.000200 1.000 1.000

1001106000 10A Citron 1.000000 1.000 1.000 25 Orange

Full comment: Orangeto_othercitrus.rdf

1001107000 10A Citrus hybrids 1.000000 1.000 1.000 25 Orange

Full comment: Orangeto_othercitrus.rdf

1001240000 10A Orange 1.000000 1.000 1.0 00 31 Orange

Full comment: Orange.rdf

1001241000 10A Orange, juice 1.000000 1.000 1.000 32 Orange

Full comment: Orange_Juice.rdf

1001241001 10A Orange, juice

- babyfood 1.000000 1.000 1.000 32 Orange

Full comment: Orange_Juice.rdf

1001242000 10A Orange, peel 1.000000 15.000 1.000 31 Orange

Full comment: Orange.rdf

1001369000 10A Tangerine 1.000000 1.000 1.000 33 Tanger

Full comment: Tan gerine.rdf

1001370000 10A Tangerine, juice 1.000000 1.280 1.000 27 Orange

Full comment: Orange_Juiceto_Tangerine.rfd

1002197000 10B Kumquat 1.000000 1.000 1.000 25 Orange

Full comment: Orange to_othercitrus.rdf

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 44 of 53 1002199000 10B Lemon 1.000000 1.000 1.000 26 Orange

Full comment: Orangeto_lemon.rdf

1002200000 10B Lemon, juice 1.000000 1.110 1.000 28 Orange

Full comment: Orange_Juiceto_lemon.rdf

1002200001 10B Lemon, juice

- babyfood 1.000000 1.110 1.000 28 Orange

Full comment: Orange_Juiceto_lemon.rdf

1002201000 10B Lemon, peel 1.000000 15.000 1.000 26 Ora nge

Full comment: Orangeto_lemon.rdf

1002206000 10B Lime 1.000000 1.000 1.000 25 Orange

Full comment: Orangeto_othercitrus.rdf

1002207000 10B Lime, juice 1.000000 1.110 1.000 29 Orang e

Full comment: Orange_Juiceto_lime.rdf

1002207001 10B Lime, juice

- babyfood 1.000000 1.110 1.000 29 Orange

Full comment: Orange_Juiceto_lime.rdf

1003180000 10C Grapefruit 1.000000 1.000 1.000 30 Gra pef

Full comment: Grapefruit.rdf

1003181000 10C Grapefruit, juice 1.000000 1.170 1.000 32 Orange

Full comment: Orange_Juice.rdf

1003307000 10C Pummelo 1.000000 1.000 1.000 25 Orange

Full c omment: Orangeto_othercitrus.rdf

1100007000 11 Apple, fruit with peel 1.000000 1.000 1.000 34 Apple_

Full comment: Apple_Fresh.rdf

1100008000 11 Apple, peeled fruit 1.000000 0.150 1.000 34 Apple_

Full commen t: Apple_Fresh.rdf

1100008001 11 Apple, peeled fruit

- babyfood 1.000000 0.150 1.000 34 Apple_

Full comment: Apple_Fresh.rdf

1100009000 11 Apple, dried 0.000600 1.200 1.000

1100009001 11 Apple, dried

- babyfo od 0.000600 1.200 1.000

1100010000 11 Apple, juice 1.000000 0.150 1.000 34 Apple_

Full comment: Apple_Fresh.rdf

1100010001 11 Apple, juice

- babyfood 1.000000 0.150 1.000 34 Apple_

Full comment: Apple_Fresh.rdf

1100011000 11 Apple, sauce 1.000000 1.000 1.000 36 Apple_

Full comment: Apple_Sauce.rdf

1100011001 11 Apple, sauce

- babyfood 1.000000 1.000 1.000 47 Apple_

Full comment: Apple_Sauce_BF.rdf

1100266000 11 Pear

110

- Uncooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 37 Pear.r

Full comment: Pear.rdf

210

- Cooked; Fresh or N/S; Cook Meth N/S

1.000000 0.150 1.000 37 Pear.r

Full comment: Pear.rdf

211

- Cooked; Fresh or N/S; Baked

1.000000 0.150 1.000 37 Pear.r

Full comment: Pear.rdf

240

- Cooked; Canned; Cook Meth N/S

1.000000 1.000 1.000 38 Pear_C

Full comment: Pear_Ca nned.rdf

1100266001 11 Pear

- babyfood 1.000000 1.000 1.000 39 Pear_B

Full comment: Pear_BF.rdf

1100267000 11 Pear, dried 0.000500 0.930 1.000

1100268000 11 Pear, juice 1.000000 0.150 1.000 37 Pear.r

Full comment: Pear.rdf

1100268001 11 Pear, juice

- babyfood 1.000000 0.150 1.000 37 Pear.r

Full comment: Pear.rdf

1201090000 12A Cherry

110

- Uncooked; Fresh or N/S; Cook Me th N/S

1.000000 1.000 1.000 41 Cherry

Full comment: Cherry.rdf

120

- Uncooked; Frozen; Cook Meth N/S

1.000000 1.000 1.000 41 Cherry

Full comment: Cherry.rdf

210

- Cooked; Fresh or N/S; Cook Meth N/S

1.000000 1.160 1.00 0 41 Cherry

Full comment: Cherry.rdf

211

- Cooked; Fresh or N/S; Baked

1.000000 1.160 1.000 41 Cherry

Full comment: Cherry.rdf

213

- Cooked; Fresh or N/S; Fried

1.000000 1.160 1.000 41 Cherry

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 45 of 53 Full comment: Cherry.rdf

223

- Cooked; Frozen; Fried 1.000000 1.160 1.000 41 Cherry

Full comment : Cherry.rdf

240

- Cooked; Canned; Cook Meth N/S

1.000000 0.590 1.000 41 Cherry

Full comment: Cherry.rdf

241

- Cooked; Canned; Baked 1.000000 0.59 0 1.000 41 Cherry

Full comment: Cherry.rdf

1201090001 12A Cherry

- babyfood 1.000000 0.590 1.000 41 Cherry

Full comment: Cherry.rdf

1201091000 12A Cherry, juice 1.000000 0.300 1.000 41 Ch erry

Full comment: Cherry.rdf

1201091001 12A Cherry, juice

- babyfood 1.000000 0.300 1.000 41 Cherry

Full comment: Cherry.rdf

1202230000 12B Nectarine 1.000000 1.000 1.000 42 Nectar

Full comment: N ectarine.rdf

1202260000 12B Peach

110

- Uncooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 43 Peach_

Full comment: Peach_Fresh.rdf

120

- Uncooked; Frozen; Cook Meth N/S

1.000000 1.000 1.000 43 Peach_

Full comment: Peach_Fresh.rdf

130

- Uncooked; Dried; Cook Meth N/S

1.000000 1.000 1.000 43 Peach_

Full comment: Peach_Fresh.rdf

210

- Cooked; Fresh or N/S; Cook Meth N/S

1.000000 0.500 1.000 43 Peach_

Full comment: Peach_Fresh.rdf

211

- Cooked; Fresh or N/S; Baked

1.000000 0.500 1.000 43 Peach_

Full comment: Peach_Fresh.rdf

213

- Cooked; Fr esh or N/S; Fried

1.000000 0.500 1.000 43 Peach_

Full comment: Peach_Fresh.rdf

223

- Cooked; Frozen; Fried 1.000000 0.500 1.000 43 Peach_

Full comme nt: Peach_Fresh.rdf

230

- Cooked; Dried; Cook Meth N/S

1.000000 0.500 1.000 43 Peach_

Full comment: Peach_Fresh.rdf

240

- Cooked; Canned; Cook Meth N/S

1.000000 0.520 1.000 44 Peach_

Full comment: Peach_Canned.rdf

1202260001 12B Peach

- babyfood 1.000000 0.520 1.000 50 Peach_

Full comment: Peach_BF.rdf

1202261000 12B Peach, dried 0.003800 7.000 1.000

1202261001 12B Peach, dried

- babyfood 0.003800 7.000 1.000

1202262000 12B Peach, juice 1.000000 1.000 1.000 44 Peach_

Full comment: Peach_Canned.rdf

1202262001 12B Peach, juice

- babyfood 1.000000 1.000 1.000 44 Peach_

Full comment: Peach_Canned.rdf

1203285000 12C Plum 1.000000 1.000 1.000 45 Plum.r

Full com ment: Plum.rdf

1203285001 12C Plum

- babyfood 1.000000 1.000 1.000 45 Plum.r

Full comment: Plum.rdf

1203286000 12C Plum, prune, fresh 1.000000 1.000 1.000 45 Plum.r

Full comment: Plum.rdf

1203286001 12 C Plum, prune, fresh

- babyfood 1.000000 1.000 1.000 45 Plum.r

Full comment: Plum.rdf

1203287000 12C Plum, prune, dried 1.000000 1.000 1.000 46 Plum_P

Full comment: Plum_Prune.rdf

1203287001 12C Plum, prune, dried

- babyfood 1.000000 1.000 1.000 46 Plum_P

Full comment: Plum_Prune.rdf

1203288000 12C Plum, prune, juice 1.000000 0.280 1.000 46 Plum_P

Full comment: Plum_Prune.rdf

1203288001 12C Plum, prune, juice

- babyfood 1.000000 0.280 1.000 46 Plum_P

Full comment: Plum_Prune.rdf

1304175000 13D Grape 1.000000 1.000 1.000 63 Grape_

Full comment: Grape_Fresh.rdf

1304176000 13D Grape, juice 1.000000 1.00 0 1.000 64 Grape_

Full comment: Grape_Juice.rdf

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 46 of 53 1304176001 13D Grape, juice

- babyfood 1.000000 1.000 1.000 64 Grape_

Full comment: Grape_Juice.rdf

1304179000 13D Grape, wine and sherry 1.000000 1.000 1.000 64 Grape_

Full comment: Grape_Juice.rdf

1304195000 13D Kiwifruit, fuzzy 2.000000 0.150 1.000 70 kiwi.r

Full comment: kiwi.rdf

1307130000 13G Cranberry 1.000000 1.000 1.000 62 Cranbe

Full comment: Cranberry.rdf

1307130001 13G Cranberry

- babyfood 1.000000 1.000 1.000 62 Cranbe

Full comment: Cranberry.rdf

1307131000 13G Cranberry, dried 1.000000 1.000 1.000 62 Cranbe

Full comment: Cranberry.rdf

1307132000 13G Cranberry, juice 1.000000 0.300 1.000 62 Cranbe

Full comment: Cranberry.rdf

1307132001 13G Cranberry, juice

- babyfood 1.000000 0.300 1.000 62 Cranbe

Full comment: Cranberry.rdf

1307 359000 13G Strawberry

110

- Uncooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 67 Strawb

Full comment: Strawberry_Fresh.rdf

120

- Uncooked; Froze n; Cook Meth N/S

1.000000 1.000 1.000 67 Strawb

Full comment: Strawberry_Fresh.rdf

211

- Cooked; Fresh or N/S; Baked

1.0 00000 1.000 1.000 67 Strawb

Full comment: Strawberry_Fresh.rdf

223

- Cooked; Frozen; Fried 1.000000 1.000 1.000 68 Strawb

Full comment: Strawberry_Frozen.rdf

230

- Cooked; Dried; Coo k Meth N/S

1.000000 1.000 1.000 67 Strawb

Full comment: Strawberry_Fresh.rdf

240

- Cooked; Canned; Cook Meth N/S

1.00000 0 1.000 1.000 67 Strawb

Full comment: Strawberry_Fresh.rdf

1307359001 13G Strawberry

- babyfood 1.000000 1.000 1.000 67 Strawb

Full comment: Strawberry_Fresh.rfd

1307360000 13G Strawberry, juice 1.000000 0.300 1.000 67 Strawb

Full comment: Strawberry_Fresh.rdf

1307360001 13G Strawberry, juice

- babyfood 1.000000 0.300 1.000 67 Strawb

Full comment: Strawberry_Fresh.rdf

1400003000 14 Almond 1.00 0000 1.000 1.000 48 Almond

Full comment: Almond.rdf

1400004000 14 Almond, oil 0.001800 2.000 1.000

1400155000 14 Hazelnut 1.000000 1.000 1.000 48 Almond

Full comment: Almond.rd f

1400269000 14 Pecan 1.000000 1.000 1.000 48 Almond

Full comment: Almond.rdf

1400391000 14 Walnut 1.000000 1.000 1.000 49 Almond

Full comment: Almondto_walnut.rdf

1500120000 15 Corn, field, flour 0.000700 0.220 1.000

1500120001 15 Corn, field, flour

- babyfood 0.000700 0.220 1.000

1500121000 15 Corn, field, meal 0.000700 0.220 1.000

1500121001 15 Corn, fiel d, meal

- babyfood 0.000700 0.220 1.000

1500122000 15 Corn, field, bran 0.000700 0.220 1.000

1500123000 15 Corn, field, starch 0.000700 0.220 1.000

1500123001 15 Corn, field, starch

- bab yfood 0.000700 0.220 1.000

1500124000 15 Corn, field, syrup 0.000500 1.000 1.000

1500124001 15 Corn, field, syrup

- babyfood 0.000500 1.000 1.000

1500125000 15 Corn, field, oil 0 .000700 4.500 1.000

1500125001 15 Corn, field, oil

- babyfood 1.000000 4.500 1.000

1500126000 15 Corn, pop 0.000700 1.000 1.000

1500127000 15 Corn, sweet

110

- Uncooked; Fres h or N/S; Cook Meth N/S

1.000000 1.000 1.000 51 Corn_S

Full comment: Corn_Sweet_Fresh.rdf

140

- Uncooked; Canned; Cook Meth N/S

1.000000 1.000 1.000 51 Corn_S

Full comment: Corn_Sweet_Fresh.rdf

210

- Cooked; Fresh or N/S; Cook Meth N/S

1.000000 1 .000 1.000 52 Corn_S

Full comment: Corn_Sweet_Frozen_Cooked.rdf

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 47 of 53 211

- Cooked; Fresh or N/S; Baked

1.000000 1.000 1.000 52 Corn_S

Full comment: Corn_Sweet_Fr ozen_Cooked.rdf

212

- Cooked; Fresh or N/S; Boiled

1.000000 1.000 1.000 52 Corn_S

Full comment: Corn_Sweet_Frozen_Cooked.rdf

213

- Cooked; Fresh or N/S; F ried

1.000000 1.000 1.000 52 Corn_S

Full comment: Corn_Sweet_Frozen_Cooked.rdf

220

- Cooked; Frozen; Cook Meth N/S

1.000 000 1.000 1.000 52 Corn_S

Full comment: Corn_Sweet_Frozen_Cooked.rdf

221

- Cooked; Frozen; Baked 1.000000 1.000 1.000 52 Corn_S

Full comment: Corn_Sweet_Frozen_Cooked.rdf

222

- Cooke d; Frozen; Boiled 1.000000 1.000 1.000 52 Corn_S

Full comment: Corn_Sweet_Frozen_Cooked.rdf

232

- Cooked; Dried; Boiled 1.000000 1.000 1.000 52 Corn_S

Full comment: Corn_Sweet_Frozen_Cooked.rdf

240

- Cooked; Canned; Cook Meth N/S

1.000000 1.000 1.000 53 Corn_S

Full comment: Corn_Sweet_Canned.rdf

242

- Cooked; Canned; Boiled 1.000000 1.000 1.000 53 Corn_S

Full comment: Corn_Sweet_Canned.rdf

243

- Cooked; Canned; Fried 1.000000 1.000 1.000 53 Corn_S

Full comment: Corn_Sweet_Canned.rdf

1500127001 15 Corn, sweet

- babyfood 1.000000 1.000 1.000 53 Corn_S

Full comment: Corn_Sweet_Canned.rdf

1500345000 15 Sorghum, syrup 0.000400 0.050 1.000

1500381000 15 Triticale, flour 0.003100 0.140 1.000

1500381001 15 Tr iticale, flour

- babyfood 0.003100 0.140 1.000

1500401000 15 Wheat, grain 1.000000 1.000 1.000 54 Wheat_

Full comment: Wheat_Grain.rdf

1500401001 15 Wheat, grain

- babyfood 1.000000 1.000 1.0 00 54 Wheat_

Full comment: Wheat_Grain.rdf

1500402000 15 Wheat, flour 0.003100 0.140 1.000

1500402001 15 Wheat, flour

- babyfood 0.003100 0.140 1.000

1500403000 15 Wheat, germ 1.000000 2.700 1.000 54 Wheat_

Full comment: Wheat_Grain.rdf

1500404000 15 Wheat, bran 1.000000 3.000 1.000 54 Wheat_

Full comment: Wheat_Grain.rdf

2002364000 20B Sunflower, seed 0.001200 1.000 1.000

2002365000 20B Sunflower, oil 0.001200 2.500 1.000

2002365001 20B Sunflower, oil

- babyfood 0.001200 2.500 1.000

2003128000 20C Cottonseed, oil 0.003000 0.375 1.0 00

2003128001 20C Cottonseed, oil

- babyfood 0.003000 0.375 1.000

3100044000 31 Beef, meat 0.000500 0.500 1.000

3100044001 31 Beef, meat

- babyfood 0.000500 0.500 1.000

3100 045000 31 Beef, meat, dried 0.000500 1.920 1.000

3100046000 31 Beef, meat byproducts 0.001400 0.500 1.000

3100046001 31 Beef, meat byproducts

- babyfood 0.001400 0.500 1.000

3100047000 31 B eef, fat 0.000500 0.500 1.000

3100047001 31 Beef, fat

- babyfood 0.000500 0.500 1.000

3100048000 31 Beef, kidney 0.001400 0.500 1.000

3100049000 31 Beef, liver 0.001400 0.500 1.000

3100049001 31 Beef, liver

- babyfood 0.001400 0.500 1.000

3200169000 32 Goat, meat 0.000500 0.500 1.000

3200170000 32 Goat, meat byproducts 0.001400 0.500 1.000

3200171000 32 Goat, fat 0.000500 0.500 1.000

3200172000 32 Goat, kidney 0.001400 0.500 1.000

3200173000 32 Goat, live r 0.001400 0.500 1.000

3400290000 34 Pork, meat 0.000380 0.500 1.000

3400290001 34 Pork, meat

- babyfood 0.000380 0.500 1.000

3400291000 34 Pork, skin 0.000380 0.500 1.000

3400292000 34 Pork, meat byproducts 0.000380 0.500 1.000

3400292001 34 Pork, meat byproducts

- babyfood 0.000380 0.500 1.000

3400293000 34 Pork, fat 1 .000000 0.500 1.000 56 Pork_F

Full comment: Pork_Fat.rdf

3400293001 34 Pork, fat

- babyfood 1.000000 0.500 1.000 56 Pork_F

Full comment: Pork_Fat.rdf

3400294000 34 Pork, kidney 0.000380 0.500 1.0 00

3400295000 34 Pork, liver 0.000380 0.500 1.000

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 48 of 53 3500339000 35 Sheep, meat 0.000500 0.500 1.000

3500339001 35 Sheep, meat

- babyfood 0.001400 0.500 1.000

3500 340000 35 Sheep, meat byproducts 0.001400 0.500 1.000

3500341000 35 Sheep, fat 0.000500 0.500 1.000

3500341001 35 Sheep, fat

- babyfood 0.000500 0.500 1.000

3500342000 35 S heep, kidney 0.001400 0.500 1.000

3500343000 35 Sheep, liver 0.001400 0.500 1.000

3600222000 36 Milk, fat 1.000000 1.000 1.000 69 Milk_C

Full comment: Milk_C reambutter.rdf

3600222001 36 Milk, fat

- baby food/infant formu 1.000000 1.000 1.000 69 Milk_C

Full comment: Milk_Creambutter.rdf

3800221000 38 Meat, game 0.000500 0.500 1.000

3900312000 39 Rabbit, meat 0.000500 0.500 1.000

4000093000 40 Chicken, meat 0.000750 0.500 1.000

4000093001 40 Chicken, meat

- babyfood 0.000750 0.500 1.000

4000094000 40 Chicken, liver 0.000750 0.500 1.000

4000095000 40 Chicken, meat byproducts 0.000750 0.500 1.000

4000095001 40 Chicken, meat byproducts

- babyfoo 0.000750 0.500 1.000

4000096000 40 Chicken, f at 0.004900 0.500 1.000

4000096001 40 Chicken, fat

- babyfood 0.004900 0.500 1.000

4000097000 40 Chicken, skin 0.004900 0.500 1.000

4000097001 40 Chicken, skin

- babyfood 0.004900 0.500 1.000

5000382000 50 Turkey, meat 0.000750 0.500 1.000

5000382001 50 Turkey, meat

- babyfood 0.000750 0.500 1.000

5000383000 50 Turkey, liver 0 .000750 0.500 1.000

5000383001 50 Turkey, liver

- babyfood 0.000750 0.500 1.000

5000384000 50 Turkey, meat byproducts 0.000750 0.500 1.000

5000384001 50 Turkey, meat byproducts

- babyfood 0.000750 0.5 00 1.000

5000385000 50 Turkey, fat 0.004900 0.500 1.000

5000385001 50 Turkey, fat

- babyfood 0.004900 0.500 1.000

5000386000 50 Turkey, skin 0.004900 0.500 1.000

5000386001 50 Turkey, skin

- babyfood 0.004900 0.500 1.000

6000301000 60 Poultry, other, meat 0.000750 0.500 1.000

6000302000 60 Poultry, other, liver 0.000750 0.500 1.000

6000303000 60 Poultry, other, meat byproducts 0.000750 0.500 1.000

6000304000 60 Poultry, other, fat 0.004900 0.500 1.000

6000305000 60 Poultry, other, skin 0.004900 0.500 1.000

7000145000 70 Egg, wh ole 0.001500 0.500 1.000

7000145001 70 Egg, whole

- babyfood 0.001500 0.500 1.000

7000146000 70 Egg, white 0.001500 0.500 1.000

7000146001 70 Egg, white (solids)

- babyfood 0.001500 0.500 1.000

7000147000 70 Egg, yolk 0.001500 0.500 1.000

7000147001 70 Egg, yolk

- babyfood 0.001500 0.500 1.000

9500019000 O Asparagus

110

- Uncooked; Fresh or N/S; Cook Meth N/S

1.000000 1.000 1.000 59 Aspara

Full comment: Asparagus.rdf

212

- Cooked; Fresh or N/S; Boiled

1.000000 0.940 1.000 59 Aspara

Full comment: Asparagus.rdf

213

- Cooked; Fresh or N/S; Fried

1.000000 0.940 1.000 59 A spara

Full comment: Asparagus.rdf

222

- Cooked; Frozen; Boiled 1.000000 0.940 1.000 59 Aspara

Full comment: Asparagus.rdf

242

- Cooked; Canned; Boiled 1.000000 1.000 1.000 60 Asp ara

Full comment: Asparagus_Canned.rdf

9500023000 O Banana 1.000000 1.000 1.000 61 Banana

Full comment: Banana.rdf

9500023001 O Banana

- babyfood 1.000000 1.000 1.000 61 Banana

Full comment: Banana.rdf

9500024000 O Banana, dried 0.002500 3.900 1.000

9500024001 O Banana, dried

- babyfood 0.002500 3.900 1.000

9500153000 O Fig 0.010000 1.000 1.000

9500154000 O Fig, dried 0.010000 1.000 1.000

9500177000 O Grape, leaves 1.000000 1.000 1.000 63 Grape_

Full comment: Grape_Fresh.rdf

9500178000 O Grape, raisin 1.000000 1.000 1.000 65 Grape_

Full comment: Grape_Raisin.rdf

9500263000 O Peanut 0.001100 1.000 1.000

9500264000 O Peanut, butter 0.014000 1.000 1.000

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 49 of 53 9500265000 O Peanut, oil 0.001100 2.000 1.000

9500275000 O Peppermint 0.800000 1.000 1.000

9500276000 O Peppermint, oil 8.000000 1.000 1.000

9500283000 O Plantain 1.000000 1.000 1.000 61 Banana

Full comment: Banana.rdf

9500284000 O Plantain, dried 0.002500 3.900 1.000

9500352000 O Spearmint 0.800000 1.000 1.000

950 0353000 O Spearmint, oil 8.000000 1.000 1.000



## Attachment 5. Acute (Food Only) Result File

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 50 of 53 US EPA Ver. 3.18, 03

- 08

- d

DEEM

- FCID ACUTE Analysis for CHLORPYRIFOS (PARENT ONLY) NHANES 2003

- 2008 2

- Day

Residue file: Chlorpyrifos_FoodOnly noFHE.R08 Adjustment factor #2 NOT used.

Analysis Date: 09

- 11

- 2014/12:29:49 Residue file dated: 08

- 18

- 2014/10:54:45

NOEL (Acute) = 1.000000 m g/kg body

- wt/day [NOTE: placeholder only, not used]

RAC/FF intake summed over 24 hours

MC iterations = 1000; MC list in residue file; MC seed = 10; RNG = MS VB

Run Comment: "chlorpyrifos (parent only); food only (no FHE)"

===============================================================================

Summary calculations

-- per capita:

95th Percentile 99th Percentile 99.9th Percentile

Exposure MOE Exposure MOE E xposure MOE

---------- -------- ---------- -------- ---------- -------- Total US Population:

0.000031 32594 0.000064 15715 0.000197 5078

All Infants:

0.000050 20178 0. 000088 11315 0.000273 3665

Children 1

- 2:

0.000082 12189 0.000143 6999 0.000423 2362

Children 3

- 5:

0.000062 16151 0.000107 9333 0.000319 3133

Children 6

- 12:

0.000040 25104 0.000072 13834 0.000189 5288

Youth 13

- 19:

0.000024 42447 0.000042 23857 0.000126 7937

Adults 20

- 49:

0.000021 47188 0.000042 23575 0.000167 5999

Adults 50

- 99:

0.000022 46380 0.000044 22962 0.000186 5377

Female 13

- 49:

0.000021 48163 0.000041 24676 0.000150 6652



## Attachment 6. Examples of Steady State (Food Only) Result File s

( Showing Day of Highest Exposure )

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 51 of 53 

### INFANTS < 1 yr old

CALENDEX

- FCID Analysis for CPFS SS INFANTS FOODONLY NOFHE

Analysis Date 08

- 19

- 2014/08:14:14/0

Exposure analysis for 3 combined weeks: starting on day 3

Exposure amounts adjusted for body weight

Dietary Residue file:

C: \ Users \ ddrew \ Documents \ DEEM_Version_3_16 \ ResidueFiles \ Scenario1 \ Chlorpyrifo

s_FoodOnly noFHE.R08 Last saved: 8/18/2014 10:54:45 AM

D ietary Adjustment factor #2 NOT used.

Dietary Matching File not used.

No non

- dietary (residential) analysis

No PRZM

- EXAMS analysis

RfD Oral = 0.00003 mg/kg

- BodyWt/day [NOTE: used as placeholder only]

Est'd max exposure: Oral = 0.01 mg/kg

- BodyWt/day

MC it erations = 10 MC seed = 10 RNG = Microsoft VB

NHANES Stat Wghts used.

Analyst Comments:

-----------------------------------------------------------------------------

Population parameters: Infants (<1 yr) All Seasons

All Regions Sex: M F

- all

All R aces

Nursing Status: Nursing and Non

- Nursing

Summary calculations (mg/kg

- BodyWt/day, per capita):

Mean 95th Percentile 9 9th Percentile 99.9th Percentile

Exposure Exposure Exposure Exposure

---------- --------- ---------- ---------

Dietary Exposure

0.000015 0.000044 0.000083 0.000186



### CHILDREN 1

- 2 yrs old

CALENDEX

- FCID Analysis for CPFS SS FOODONLY NOFHE

Analysis Date 08

- 18

- 2014/12:31:23/0

Exposure analysis for 3 combined weeks: starting on day 82

Exposure amounts adjusted for body weight

Dietary Residue file:

C: \ Users \ ddrew \ Documents \ DEEM_Version_3_16 \ ResidueFiles \ Scenario1 \ Chlorpyrifo

s_FoodOnly noFHE.R08 Last saved: 8/18/2014 10:54:45 AM

Dietary Adjustment factor #2 NOT used.

Dietary Matching File not used.

No non

- dietary (residential) analysis

No PRZM

- EXAMS analysis

RfD Oral = 0.00003 mg/kg

- BodyWt/day [Note: used as placeholder only]

Est'd max exposure: Oral = 0.01 mg/kg

- BodyWt/day

MC it erations = 10 MC seed = 10 RNG = Microsoft VB

NHANES Stat Wghts used.

Analyst Comments:

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 52 of 53 ----------------------------------------------------------------------------- Population parameters: Children 1

- 2 All Seasons

All Regions Sex: M F

- all

All Race s

Nursing Status: Nursing and Non

- Nursing

Summary calculations (mg/kg

- BodyWt/day, per capita):

Mean 95th Percentile 99th Percentile 99.9th Percentile

Exposure Exposure Exposure Exposure

---------- --------- ---------- ---------

Dietary Exposure

0.000033 0.000070 0.000118 0.000242



### CHILDREN 6

- 12 yrs old

CALENDEX

- FCID Analysis for CPFS SS Y6

- 12 FOODONLY

Analysis Date 10

- 30

- 2014/07:34:51/0

Exposure analys is for 3 combined weeks: starting on day 92

Exposure amounts adjusted for body weight

Dietary Residue file: E: \ chlorpyrifos \ working dietary

files \ Chlorpyrifos_FoodOnly noFHE.R08 Last saved: 9/2/2014 11:39:36 AM

Dietary Adjustment factor #2 NOT used.

Dieta ry Matching File not used.

No non

- dietary (residential) analysis

No PRZM

- EXAMS analysis

NOEL Oral = 1 mg/kg

- BodyWt/day

Est'd max exposure: Oral = 0.01 mg/kg

- BodyWt/day

MC iterations = 10 MC seed = 10 RNG = Microsoft VB

NHANES Stat Wghts used.

Analyst Comments:food only

- no FHE

----------------------------------------------- ------------------------------

Population parameters: Children 6

- 12 All Seasons

All Regions Sex: M F

- all

All Races

Summary calculations (mg/kg

- BodyWt/day, per capita):

Mean 95th Percentile 99th Percentile 99.9th Percentile

Exposure Exposure Exposure Exposure

---------- --------- ---------- ---------

Dietary Exposure

0.000017 0.000038 0.000 059 0.00 0 128



### FEMALES 13

- 49 yrs old

CALENDEX

- FCID Analysis for CPFS SS F13_49 FOODONLY NOFHE

### Chlorpyrifos Dietary Exposure DP Number: D424486

Page 53 of 53 Analysis Date 08

- 19

- 2014/10:14:05/0

Exposure analysis for 3 combined weeks: starting on day 32

Exposure amounts adjusted for body weight

Dietary Residue file:

C: \ Users \ ddrew \ Documents \ DEEM_Version_3_16 \ ResidueFiles \ Scenario1 \ Chlorpyrifo

s_FoodOnly noFHE.R08 Last saved: 8/18/2014 10:54:45 AM

Dietary Adjustment factor #2 NOT used.

Dietary Matching File not used.

No non

- dietary (residential) analysis

No PRZM

- EXAMS analysis

RfD Oral = 0.00003 mg/kg

- BodyWt/day [Note: used as placeholder only]

Est'd max exposure: Oral = 0.01 mg/kg

- BodyWt/day

MC iterations = 10 MC seed = 10 RNG = Microsoft VB

NHANES Stat Wghts used.

Analyst Comments:

--------------------- -------------------------- ------------------------------

Population parameters: Females (13

- 49) All Seasons

All Regions Sex: F

- all

All Races

Summary calculations (mg/kg

- BodyWt/day, per capita):

Mean 95th Percentile 9 9th Percentile 99.9th Percentile

Exposure Exposure Exposure Exposure

---------- --------- ---------- ---------

Dietary Exposure

0.000008 0.000018 0.000029 0.000075