2714 Exchange Drive 

Wilmington, NC 28405 

Ph.: 910-794-1613 

1 / 2 

 

 

18 October 2010 

 

Bill Kissel 

ATC, Inc. 

1630 Dale Earnhardt Blvd 

Kannapolis, NC 28083

Ph.: 800-733-3193 

Email: bkissel@atc-net.net 

Subject: Certificate of Results 

Dear Bill; 

Attached to this narrative are the analytical results you requested on samples submitted 

for the determination of polychlorinated dibenzo-p-dioxins and dibenzofurans. The insert 

below summarizes the relevant information pertaining to your project. In particular, QC 

annotations bring to your attention specific analytical observations and assessments made 

during the sample handling and data interpretation phases. A brief description of the 

report’s components is provided. 

Project Information Summary When applicable, see QC Annotations for details

Client Project No. P-10124

AP Project No. P2695

Analytical Protocol Method 23

No. Samples Submitted 9

No. Samples Analyzed 9

No. Laboratory Method Blanks 1

No. OPRs / Batch CS3 1

No. Outstanding Samples 0

Date Received 27-Sep-2010

Condition Received see below

Temperature upon Receipt (C) 4

Extraction within Holding Time yes

Analysis within Holding Time yes

Data meet QA/QC Requirements yes

Exceptions see below

Analytical Difficulties see below
2714 Exchange Drive 

Wilmington, NC 28405 

Ph.: 910-794-1613 

2 / 2 

 

Analytical Perspectives remains committed to serving you in the most effective manner. 

Should you have any questions or need additional information and technical support, 

please do not hesitate to contact us. Thank you for choosing Analytical Perspectives as 

part of your analytical support team. 

Sincerely, 

Heather Steele, Ph.D. 

Project Manager 

QC Annotations: 

1. Please see the attached appendices for a list of data qualifiers and lab identifiers 

that may be contained in the report.
APPENDIX A: DATA QUALIFIERS / DATA ATTRIBUTES 

* The reported concentration exceeds the calibration range (upper point of the calibration 

curve).1

> Indicates high recoveries. Shown with the numeric value at the top of the range.1

B The analyte is found in the method blank, at a level that is <=10x the sample 

concentration.

C 

Two or more congeners co-elute. In EDDs C denotes the lowest IUPAC congener in a 

co-elution group and additional co-eluters for the group are shown with the number of the 

lowest IUPAC co-eluter. 

E The reported concentration exceeds the calibration range (upper point of the calibration 

curve). 

EMPC 

Represents an Estimated Maximum Possible Concentration. EMPC’s arise in cases where 

the signal/noise ratio is not sufficient for peak identification (the determined ionabundance ratio is outside the allowed theoretical range), or where there is a co-eluting 

interference. 

ETH Indicates the presence of a diphenyl ether that appears to interfere with the quantitation of 

a furan. The reported concentration is the maximum. 

H/h If the standard recovery is below the method or SOP specified value “H” is assigned. If 

the obtained value is less than half the specified value “h” is assigned.1

J Indicates that an analyte has a concentration below the reporting limit (lowest point of the 

calibration curve). 

ND Indicates a non-detect. 

NR Indicates a value that is not reportable. 

PR Due to interference, the associated congener is poorly resolved. 

QI Indicates the presence of a quantitative interference. 

Ra The new ratio – [Ra] -- for 2,3,7,8-TCDD following the 37Cl4-2,3,7,8-TCDD correction is 

shown between squared brackets in the DL column.1

SI 

Denotes “Single Ion Mode” and is utilized for PCBs where the secondary ion trace has a 

significantly elevated noise level due to background PFK. Responses for such peaks are 

calculated using an EMPC approach based solely on the primary ion area(s) and may be 

considered estimates.1

U The analyte was not detected. The estimated detection limit (EDL) may be reported for 

this analyte. 

V The labeled standard recovery was found to be outside of the method control limits. 

X Indicates results reported from reinjection, refractionation, or repeat analyses. 

APPENDIX B: LAB ID IDENTIFIERS

AR Indicates use of the archived portion of the sample extract. 

CU Indicates a sample that required additional clean-up prior to MS injection/processing. 

D Indicates a dilution of the sample extract. The number that follows the “D” indicates the 

dilution factor. 

DE Indicates a dilution performed with the addition of ES (extraction standard) solution. 

DUP Designation for a duplicate sample. 

MS Designation for a matrix spike. 

MSD Designation for a matrix spike duplicate. 

RJ Indicates a reinjection of the sample extract. 

S Indicates a sample split. The number that follows the “S” indicates the split factor. 

1

Denotes data qualifiers/attributes whose use will be phased out over time 
 P2695 - TEQ

Project ID: P-10124 

Sample SummaryPart 1 

Analyte 0_8210_ MB001 Plant 5 Inlet-R1 Plant 5 Inlet-R2 Plant 5 Inlet-R3 Plant 5 Outlet-R1 Plant 5 Outlet-R2 Plant 5 Outlet-R3 Plan

Oven

pg pg pg pg pg pg pg pg 

2,3,7,8-TCDD (1.79) 50.1 45.2 34.3 60.2 29.4 [33.8] (1.71,2,3,7,8-PeCDD (2.12) 75.2 63.9 66.4 92.3 42.6 61.7 (1.71,2,3,4,7,8-HxCDD (2.09) 32 21.6 23.4 28 16.8 20.6 (1.71,2,3,6,7,8-HxCDD (2.06) 49.2 32.1 31.3 [36.6] 20.4 29.4 (1.61,2,3,7,8,9-HxCDD (2.14) 60.6 44.3 38 49.5 29.2 41.3 (1.81,2,3,4,6,7,8-HpCDD (2.48) 247 162 139 135 91 108 13OCDD (4.95) 1500 1030 809 563 421 549 372,3,7,8-TCDF (1.3) 14.4 10.7 [5.02] 4.29 5.58 [3.02] [31,2,3,7,8-PeCDF (1.43) 15.1 17.7 7.81 [2.36] [3.4] [2.68] 3.72,3,4,7,8-PeCDF (1.32) 9.13 [8.37] 6 5.98 6.89 5.68 5.81,2,3,4,7,8-HxCDF (1.38) 11.5 12.7 8.14 4.19 [3.98] 3.74 6.01,2,3,6,7,8-HxCDF (1.27) 11.6 14.5 [6.55] 4.37 [5] [2.63] 5.4 2,3,4,6,7,8-HxCDF (1.26) 9.5 9.99 [4.9] 4.85 5.76 [4.22] [5.41,2,3,7,8,9-HxCDF (1.66) (2.18) (1.85) (1.66) (1.48) (1.82) (2.73) (1.81,2,3,4,6,7,8-HpCDF (1.5) 27.4 32.8 19.2 11.6 12.2 12 111,2,3,4,7,8,9-HpCDF (2.08) 4.56 4.2 (1.99) (1.76) (2.27) (3.31) (2.6OCDF (3.57) [10.3] 14.8 (3.07) [6.56] 6.95 [6.83] [3.1ITEF TEQ (ND=0; EMPC=0) 0.00 116 95.6 83.4 121 63.4 45.0 4.5ITEF TEQ (ND=0; EMPC=EMPC) 0.00 116 99.8 85.0 125 64.5 79.9 5.4ITEF TEQ (ND=DL/2; EMPC=0) 2.48 116 96.1 83.7 121 63.7 47.2 6.4ITEF TEQ (ND=DL/2; EMPC=EMPC) 2.48 116 99.9 85.1 125 64.6 80 7.1ITEF TEQ (ND=DL; EMPC=EMPC) 4.96 116 100 85.2 125 64.7 80.2 8.7Checkcode 943-130 181-473 154-978 861-712 399-397 126-168 589-525 634-Lab ID MB1_8210_DF_SDS P2695_8210_001 P2695_8210_002 P2695_8210_003 P2695_8210_004 P2695_8210_005 P2695_8210_006 P2695_82

( ) = DL[ ] = EMPC
 P2695 - WHO-2005-TEQ

Project ID: P-10124 

Sample SummaryPart 1 

Analyte 0_8210_ MB001 Plant 5 Inlet-R1 Plant 5 Inlet-R2 Plant 5 Inlet-R3 Plant 5 Outlet-R1 Plant 5 Outlet-R2 Plant 5 Outlet-R3 Plan

Oven

pg pg pg pg pg pg pg pg 

2,3,7,8-TCDD (1.79) 50.1 45.2 34.3 60.2 29.4 [33.8] (1.71,2,3,7,8-PeCDD (2.12) 75.2 63.9 66.4 92.3 42.6 61.7 (1.71,2,3,4,7,8-HxCDD (2.09) 32 21.6 23.4 28 16.8 20.6 (1.71,2,3,6,7,8-HxCDD (2.06) 49.2 32.1 31.3 [36.6] 20.4 29.4 (1.61,2,3,7,8,9-HxCDD (2.14) 60.6 44.3 38 49.5 29.2 41.3 (1.81,2,3,4,6,7,8-HpCDD (2.48) 247 162 139 135 91 108 13OCDD (4.95) 1500 1030 809 563 421 549 372,3,7,8-TCDF (1.3) 14.4 10.7 [5.02] 4.29 5.58 [3.02] [31,2,3,7,8-PeCDF (1.43) 15.1 17.7 7.81 [2.36] [3.4] [2.68] 3.72,3,4,7,8-PeCDF (1.32) 9.13 [8.37] 6 5.98 6.89 5.68 5.81,2,3,4,7,8-HxCDF (1.38) 11.5 12.7 8.14 4.19 [3.98] 3.74 6.01,2,3,6,7,8-HxCDF (1.27) 11.6 14.5 [6.55] 4.37 [5] [2.63] 5.4 2,3,4,6,7,8-HxCDF (1.26) 9.5 9.99 [4.9] 4.85 5.76 [4.22] [5.41,2,3,7,8,9-HxCDF (1.66) (2.18) (1.85) (1.66) (1.48) (1.82) (2.73) (1.81,2,3,4,6,7,8-HpCDF (1.5) 27.4 32.8 19.2 11.6 12.2 12 111,2,3,4,7,8,9-HpCDF (2.08) 4.56 4.2 (1.99) (1.76) (2.27) (3.31) (2.6OCDF (3.57) [10.3] 14.8 (3.07) [6.56] 6.95 [6.83] [3.1WHO-2005 TEQ (ND=0; EMPC=0) 0.00 151 126 115 165 83.0 74.3 3.2WHO-2005 TEQ (ND=0; EMPC=EMPC) 0.00 151 129 116 169 84.0 109 4.1WHO-2005 TEQ (ND=DL/2; EMPC=0) 2.86 151 127 115 166 83.3 76.5 5.5WHO-2005 TEQ (ND=DL/2; EMPC=EMPC) 2.86 151 129 116 169 84.1 109 6.2WHO-2005 TEQ (ND=DL; EMPC=EMPC) 5.73 151 129 117 169 84.2 109 8.3Checkcode 943-130 181-473 154-978 861-712 399-397 126-168 589-525 634-Lab ID MB1_8210_DF_SDS P2695_8210_001 P2695_8210_002 P2695_8210_003 P2695_8210_004 P2695_8210_005 P2695_8210_006 P2695_82

( ) = DL[ ] = EMPC
 P2695 - Totals

Project ID: P-10124 

Sample SummaryPart 2 

Analyte 0_8210_ MB001 Plant 5 Inlet-R1 Plant 5 Inlet-R2 Plant 5 Inlet-R3 Plant 5 Outlet-R1 Plant 5 Outlet-R2 Plant 5 Outlet-R3 Plan

Oven

pg pg pg pg pg pg pg pg 

TotalsTCDDs 0 2070 2290 1670 2310 1170 1430 28 PeCDDs 0 1300 1260 1180 1600 820 1040 56HxCDDs 0 910 642 664 782 439 545 63 HpCDDs 0 578 385 334 336 221 268 40OCDD 0 1500 1030 809 563 421 549 37TCDFs 0 247 337 158 208 207 94 82PeCDFs 0 90.6 111 50.7 60.5 53.7 42.1 44HxCDFs 0 78.1 88 36.9 31.4 12.8 3.74 26HpCDFs 0 38.6 43.3 27.8 14.3 15.7 12 11OCDF 0 10.3 14.8 0 6.56 6.95 6.83 3.1Total PCDD/Fs (ND=0; EMPC=0) 0.00 6,810 6,200 4,930 5,900 3,370 3,990 39Total PCDD/Fs (ND=0; EMPC=EMPC) 0.00 6,910 6,240 5,040 6,000 3,480 4,160 46Total PCDD/Fs (2378-X ND=DL; EMPC=EMPC) 34.4 6,910 6,240 5,050 6,010 3,490 4,170 47Total 2378s (ND=0; EMPC=0) 0.00 2,120 1,520 1,180 963 688 831 83Total 2378s (ND=0.5; EMPC=0) 17.2 2,120 1,520 1,190 968 693 843 92Total 2378s (ND=1; EMPC=0) 34.4 2,120 1,520 1,190 972 697 854 10Total 2378s (ND=0; EMPC=1) 0.00 2,130 1,530 1,200 1,010 700 885 95Total 2378s (ND=0.5; EMPC=1) 17.2 2,130 1,530 1,200 1,010 702 888 10Total 2378s (ND=1; EMPC=1) 34.4 2,130 1,530 1,210 1,010 704 891 10Checkcode 943-130 181-473 154-978 861-712 399-397 126-168 589-525 634-Lab ID MB1_8210_DF_SDS P2695_8210_001 P2695_8210_002 P2695_8210_003 P2695_8210_004 P2695_8210_005 P2695_8210_006 P2695_82

( ) = DL[ ] = EMPC
 P2695 - Others

Project ID: P-10124 

Sample SummaryPart 3 

Analyte 0_8210_ MB001 Plant 5 Inlet-R1 Plant 5 Inlet-R2 Plant 5 Inlet-R3 Plant 5 Outlet-R1 Plant 5 Outlet-R2 Plant 5 Outlet-R3 Plan

Oven

pg pg pg pg pg pg pg pg 

Other PCDD/Fs (ND=0, EMPC=0)Other TCDD 0 2020 2240 1640 2250 1140 1430 28 Other PeCDD 0 1230 1200 1110 1510 777 983 56Other HxCDD 0 768 544 571 705 372 454 63 Other HpCDD 0 331 223 195 202 130 161 27Other TCDF 0 232 327 158 204 202 94 82Other PeCDF 0 66.4 93.3 36.9 54.6 46.8 36.4 35Other HxCDF 0 41.6 50.8 26.8 18 7.08 0 15 Other HpCDF 0 6.58 6.28 8.61 2.77 3.48 00Other PCDD/Fs (ND=0, EMPC=EMPC)Other TCDD 0 2020 2240 1660 2250 1140 1450 40Other PeCDD 0 1230 1200 1110 1510 777 983 63Other HxCDD 0 768 544 571 705 397 477 63 Other HpCDD 0 331 223 195 202 130 161 27Other TCDF 0 280 332 198 239 227 154 10Other PeCDF 0 89.6 104 61.8 71.5 78.6 46.6 50Other HxCDF 0 48.2 60.2 29.2 18 24.9 12.7 18Other HpCDF 0 11.5 11.4 8.61 5.81 5.38 00Checkcode 943-130 181-473 154-978 861-712 399-397 126-168 589-525 634-Lab ID MB1_8210_DF_SDS P2695_8210_001 P2695_8210_002 P2695_8210_003 P2695_8210_004 P2695_8210_005 P2695_8210_006 P2695_82

( ) = DL[ ] = EMPC
 P2695 - DLs

Project ID: P-10124 

Sample SummaryPart 5 (DLs) 

Analyte 0_8210_ MB001 Plant 5 Inlet-R1 Plant 5 Inlet-R2 Plant 5 Inlet-R3 Plant 5 Outlet-R1 Plant 5 Outlet-R2 Plant 5 Outlet-R3 Plan

Oven

pg pg pg pg pg pg pg pg 

2,3,7,8-TCDD 1.79 2.19 1.95 2.02 1.63 2.46 3.33 1.71,2,3,7,8-PeCDD 2.12 3.48 4.48 4.43 3.76 3.34 5.11 1.71,2,3,4,7,8-HxCDD 2.09 2.31 1.89 1.62 1.68 2.39 2.61 1.71,2,3,6,7,8-HxCDD 2.06 2.34 1.77 1.72 1.71 2.16 2.66 1.61,2,3,7,8,9-HxCDD 2.14 2.42 2.09 1.76 1.96 2.5 2.78 1.81,2,3,4,6,7,8-HpCDD 2.48 4.14 4.28 3.68 2.81 3.85 4.7 2.0OCDD 4.95 4.04 3.2 4.05 3.17 3.74 5.76 3.02,3,7,8-TCDF 1.3 1.74 1.53 1.56 1.21 1.46 2.59 1.81,2,3,7,8-PeCDF 1.43 1.69 1.41 1.35 1.34 2.9 2.78 1.82,3,4,7,8-PeCDF 1.32 1.51 1.38 1.37 1.25 2.67 2.4 1.71,2,3,4,7,8-HxCDF 1.38 1.63 1.41 1.21 1.09 1.42 2.23 1.31,2,3,6,7,8-HxCDF 1.27 1.58 1.41 1.1 1.03 1.35 2.08 1.32,3,4,6,7,8-HxCDF 1.26 1.81 1.38 1.28 1.19 1.45 2.28 1.41,2,3,7,8,9-HxCDF 1.66 2.18 1.85 1.66 1.48 1.82 2.73 1.81,2,3,4,6,7,8-HpCDF 1.5 1.83 1.95 1.4 1.21 1.53 2.14 1.81,2,3,4,7,8,9-HpCDF 2.08 2.41 2.4 1.99 1.76 2.27 3.31 2.6OCDF 3.57 3.39 3.14 3.07 2.56 3.09 3.91 2.1Total TCDD 1.79 2.19 1.95 2.02 1.63 2.46 3.33 1.7Total PeCDD 2.12 3.48 4.48 4.43 3.76 3.34 5.11 1.7Total HxCDD 2.09 2.35 1.91 1.69 1.78 2.34 2.67 1.7Total HpCDD 2.48 4.14 4.28 3.68 2.81 3.85 4.7 2.0Total TCDF 1.3 1.74 1.53 1.56 1.21 1.46 2.59 1.8Total PeCDF 1.37 1.6 1.39 1.36 1.29 2.78 2.59 1.8 Total HxCDF 1.38 1.78 1.5 1.3 1.18 1.5 2.31 1.4Total HpCDF 1.76 2.09 2.15 1.66 1.45 1.86 2.66 2.2Checkcode 943-130 181-473 154-978 861-712 399-397 126-168 589-525 634-Lab ID MB1_8210_DF_SDS P2695_8210_001 P2695_8210_002 P2695_8210_003 P2695_8210_004 P2695_8210_005 P2695_8210_006 P2695_82
4.96

116

100

85.2

125

64.7

80.2

8.79 

0

20406080

100120140

pg

0_8210_MB001 Plant 5 Inlet-R1 Plant 5 Inlet-R2 Plant 5 Inlet-R3 Plant 5 Outlet-R1 Plant 5 Outlet-R2 Plant 5 Outlet-R3 Plant 5 Oven-R1 Plant 5 Oven-R2 P

ITEF-TEQ

Project ID: P-10124

P2695

NNNNN
5.73

151

129

117

169

84.2

109

8.39 

0

20406080

100120140160180

pg

0_8210_MB001 Plant 5 Inlet-R1 Plant 5 Inlet-R2 Plant 5 Inlet-R3 Plant 5 Outlet-R1 Plant 5 Outlet-R2 Plant 5 Outlet-R3 Plant 5 Oven-R1 Plant 5 Oven-R2 P

WHO-2005-TEQ

Project ID: P-10124

P2695

NNNNN
34.4

6,910

6,240

5,050

6,010

3,490

4,170

479 4

0

1000200030004000500060007000

pg

0_8210_MB001 Plant 5 Inlet-R1 Plant 5 Inlet-R2 Plant 5 Inlet-R3 Plant 5 Outlet-R1 Plant 5 Outlet-R2 Plant 5 Outlet-R3 Plant 5 Oven-R1 Plant 5 Oven-R2 Pla

Totals

Project ID: P-10124

P2695

Total PCDD/Fs (ND=0; ETotal PCDD/Fs (ND=0; ETotal PCDD/Fs (2378-X N
Method Specification Limits: Tetra-Hexa ES: 40-130%, Hepta-Octa ES: 25-130% (F = fail)

77-104

81-102

79-96

78-95

80-101

79-100

72-94

76-101

78-97

76-97

78-98

79-98

75-93

78-97

7

0

102030405060708090

100

% Rec.

13C-TCDD

13C-PeCDD

13C-HxCDD

13C-HxCDD

13C-HxCDD

13C-HpCDD

13C-OCDD

13C-TCDF

13C-PeCDF

13C-PeCDF

13C-HxCDF

13C-HxCDF

13C-HxCDF

13C-HxCDF

13C-HpCDF

Mean Recoveries of Extraction Standards (N=10)

Project ID: P-10124

P2695 M
Method Specification Limits: Tetra-Octa SS: 70-130% (F = fail)

96-100

96-101

97-102

99-103

96

0

20406080

100120

% Rec.

37Cl-TCDD

13C-PeCDD

13C-PeCDF

13C-HxCDF

13C-HpCDF

Mean Recoveries of Sampling Standards (N=10)

Project ID: P-10124

P2695 M





Sample ID: 0_8210_MB001 

Client Data Sample Data Laboratory Data Software 

Name: Analytical Testing Consultants, Inc. Matrix: Air Lab Project ID: P2695 Date Rec

Project ID: P-10124 Weight/Volume: 1 Lab Sample ID MB1_8210_DF_SDS Date ExtDate Collected: n/a QC Batch No: 8210 Date Ana

Split: 2 Dilution: - Time Ana

Analyte Conc. (pg) DL (pg) EMPC (pg) Qualifiers Standard ES Rec

2378-TCDD ND 1.79 ES 2378-TCDD 9512378-PeCDD ND 2.12 ES 12378-PeCDD 95123478-HxCDD ND 2.09 ES 123478-HxCDD 88123678-HxCDD ND 2.06 ES 123678-HxCDD 8123789-HxCDD ND 2.14 ES 123789-HxCDD 921234678-HpCDD ND 2.48 ES 1234678-HpCDD 89OCDD ND 4.95 ES OCDD 832378-TCDF ND 1.3 ES 2378-TCDF 9612378-PeCDF ND 1.43 ES 12378-PeCDF 9123478-PeCDF ND 1.32 ES 23478-PeCDF 92123478-HxCDF ND 1.38 ES 123478-HxCDF 86123678-HxCDF ND 1.27 ES 123678-HxCDF 88234678-HxCDF ND 1.26 ES 234678-HxCDF 88123789-HxCDF ND 1.66 ES 123789-HxCDF 871234678-HpCDF ND 1.5 ES 1234678-HpCDF 891234789-HpCDF ND 2.08 ES 1234789-HpCDF 84OCDF ND 3.57 ES OCDF 80

Totals Standard SS/AS R

SS 37Cl-2378-TCDD 98

Total TCDD ND 1.79 ND SS 12347-PeCDD 97Total PeCDD ND 2.12 ND SS 12346-PeCDF 10Total HxCDD ND 2.09 ND SS 123469-HxCDF 99Total HpCDD ND 2.48 ND SS 1234689-HpCDF 96

AS 1368-TCDD 95

Total TCDF ND 1.3 ND AS 1368-TCDF 93Total PeCDF ND 1.37 NDTotal HxCDF ND 1.38 NDTotal HpCDF ND 1.76 ND

Total PCDD/Fs ND NDITEF TEQsTEQ: ND=0 0 0 

TEQ: ND=DL/2 2.48 2.48 TEQ: ND=DL 4.96 4.96 

 Tel: +1 910 794-1613 (Fax: -3919); Toll-Free 866 846-8290 

Checkcode: 943-130 AP D/F 2010 Rev. L Report Created: 15-
Sample ID: Plant 5 Inlet-R1 

Client Data Sample Data Laboratory Data Software 

Name: Analytical Testing Consultants, Inc. Matrix: Air Lab Project ID: P2695 Date Rec

Project ID: P-10124 Weight/Volume: 1 Lab Sample ID P2695_8210_001 Date ExtDate Collected: 18 Sep 2010 QC Batch No: 8210 Date Ana

Split: 2 Dilution: - Time Ana

Analyte Conc. (pg) DL (pg) EMPC (pg) Qualifiers Standard ES Rec

2378-TCDD 50.1 [Ra=0.80] ES 2378-TCDD 8512378-PeCDD 75.2 ES 12378-PeCDD 84123478-HxCDD 32 J ES 123478-HxCDD 84123678-HxCDD 49.2 J ES 123678-HxCDD 83123789-HxCDD 60.6 ES 123789-HxCDD 901234678-HpCDD 247 ES 1234678-HpCDD 83OCDD 1500 ES OCDD 822378-TCDF 14.4 ES 2378-TCDF 8212378-PeCDF 15.1 J ES 12378-PeCDF 823478-PeCDF 9.13 J ES 23478-PeCDF 8123478-HxCDF 11.5 J ES 123478-HxCDF 84123678-HxCDF 11.6 J ES 123678-HxCDF 84234678-HxCDF 9.5 J ES 234678-HxCDF 81123789-HxCDF ND 2.18 ES 123789-HxCDF 851234678-HpCDF 27.4 J ES 1234678-HpCDF 831234789-HpCDF 4.56 J ES 1234789-HpCDF 82OCDF EMPC 10.3 J ES OCDF 79

Totals Standard SS/AS R

SS 37Cl-2378-TCDD 96

Total TCDD 2070 2070 SS 12347-PeCDD 98Total PeCDD 1300 1300 SS 12346-PeCDF 97Total HxCDD 910 910 SS 123469-HxCDF 98Total HpCDD 578 578 SS 1234689-HpCDF 96

AS 1368-TCDD 90

Total TCDF 247 295 AS 1368-TCDF 86Total PeCDF 90.6 114Total HxCDF 78.1 84.7Total HpCDF 38.6 43.4

Total PCDD/Fs 6810 6910ITEF TEQsTEQ: ND=0 116 116 

TEQ: ND=DL/2 116 116 TEQ: ND=DL 116 116 

 Tel: +1 910 794-1613 (Fax: -3919); Toll-Free 866 846-8290 

Checkcode: 181-473 AP D/F 2010 Rev. L Report Created: 15-
Sample ID: Plant 5 Inlet-R2 

Client Data Sample Data Laboratory Data Software 

Name: Analytical Testing Consultants, Inc. Matrix: Air Lab Project ID: P2695 Date Rec

Project ID: P-10124 Weight/Volume: 1 Lab Sample ID P2695_8210_002 Date ExtDate Collected: 18 Sep 2010 QC Batch No: 8210 Date Ana

Split: 2 Dilution: - Time Ana

Analyte Conc. (pg) DL (pg) EMPC (pg) Qualifiers Standard ES Rec

2378-TCDD 45.2 [Ra=0.79] ES 2378-TCDD 9112378-PeCDD 63.9 ES 12378-PeCDD 88123478-HxCDD 21.6 J ES 123478-HxCDD 86123678-HxCDD 32.1 J ES 123678-HxCDD 87123789-HxCDD 44.3 J ES 123789-HxCDD 931234678-HpCDD 162 ES 1234678-HpCDD 94OCDD 1030 ES OCDD 892378-TCDF 10.7 ES 2378-TCDF 8712378-PeCDF 17.7 J ES 12378-PeCDF 8423478-PeCDF EMPC 8.37 J ES 23478-PeCDF 8123478-HxCDF 12.7 J ES 123478-HxCDF 91123678-HxCDF 14.5 J ES 123678-HxCDF 90234678-HxCDF 9.99 J ES 234678-HxCDF 92123789-HxCDF ND 1.85 ES 123789-HxCDF 911234678-HpCDF 32.8 J ES 1234678-HpCDF 901234789-HpCDF 4.2 J ES 1234789-HpCDF 91OCDF 14.8 J ES OCDF 84

Totals Standard SS/AS R

SS 37Cl-2378-TCDD 99

Total TCDD 2290 2290 SS 12347-PeCDD 98Total PeCDD 1260 1260 SS 12346-PeCDF 10Total HxCDD 642 642 SS 123469-HxCDF 10Total HpCDD 385 385 SS 1234689-HpCDF 10

AS 1368-TCDD 92

Total TCDF 337 343 AS 1368-TCDF 84Total PeCDF 111 130Total HxCDF 88 97.4Total HpCDF 43.3 48.4

Total PCDD/Fs 6200 6240ITEF TEQsTEQ: ND=0 95.6 99.8 

TEQ: ND=DL/2 96.1 99.9 TEQ: ND=DL 96.5 100 

 Tel: +1 910 794-1613 (Fax: -3919); Toll-Free 866 846-8290 

Checkcode: 154-978 AP D/F 2010 Rev. L Report Created: 15-
Sample ID: Plant 5 Inlet-R3 

Client Data Sample Data Laboratory Data Software 

Name: Analytical Testing Consultants, Inc. Matrix: Air Lab Project ID: P2695 Date Rec

Project ID: P-10124 Weight/Volume: 1 Lab Sample ID P2695_8210_003 Date ExtDate Collected: 18 Sep 2010 QC Batch No: 8210 Date Ana

Split: 2 Dilution: - Time Ana

Analyte Conc. (pg) DL (pg) EMPC (pg) Qualifiers Standard ES Rec

2378-TCDD 34.3 [Ra=0.75] ES 2378-TCDD 7612378-PeCDD 66.4 ES 12378-PeCDD 80123478-HxCDD 23.4 J ES 123478-HxCDD 78123678-HxCDD 31.3 J ES 123678-HxCDD 77123789-HxCDD 38 J ES 123789-HxCDD 791234678-HpCDD 139 ES 1234678-HpCDD 79OCDD 809 ES OCDD 722378-TCDF EMPC 5.02 J ES 2378-TCDF 7512378-PeCDF 7.81 J ES 12378-PeCDF 7723478-PeCDF 6 J ES 23478-PeCDF 76123478-HxCDF 8.14 J ES 123478-HxCDF 77123678-HxCDF EMPC 6.55 J ES 123678-HxCDF 79234678-HxCDF EMPC 4.9 J ES 234678-HxCDF 75123789-HxCDF ND 1.66 ES 123789-HxCDF 771234678-HpCDF 19.2 J ES 1234678-HpCDF 781234789-HpCDF ND 1.99 ES 1234789-HpCDF 73OCDF ND 3.07 ES OCDF 71

Totals Standard SS/AS R

SS 37Cl-2378-TCDD 98

Total TCDD 1670 1700 SS 12347-PeCDD 99Total PeCDD 1180 1180 SS 12346-PeCDF 98Total HxCDD 664 664 SS 123469-HxCDF 10Total HpCDD 334 334 SS 1234689-HpCDF 97

AS 1368-TCDD 75

Total TCDF 158 203 AS 1368-TCDF 7Total PeCDF 50.7 75.6Total HxCDF 36.9 50.8Total HpCDF 27.8 27.8

Total PCDD/Fs 4930 5040ITEF TEQsTEQ: ND=0 83.4 85 

TEQ: ND=DL/2 83.7 85.1 TEQ: ND=DL 84 85.2 

 Tel: +1 910 794-1613 (Fax: -3919); Toll-Free 866 846-8290 

Checkcode: 861-712 AP D/F 2010 Rev. L Report Created: 15-
Sample ID: Plant 5 Outlet-R1 

Client Data Sample Data Laboratory Data Software 

Name: Analytical Testing Consultants, Inc. Matrix: Air Lab Project ID: P2695 Date Rec

Project ID: P-10124 Weight/Volume: 1 Lab Sample ID P2695_8210_004 Date ExtDate Collected: 18 Sep 2010 QC Batch No: 8210 Date Ana

Split: 2 Dilution: - Time Ana

Analyte Conc. (pg) DL (pg) EMPC (pg) Qualifiers Standard ES Rec

2378-TCDD 60.2 [Ra=0.74] ES 2378-TCDD 9812378-PeCDD 92.3 ES 12378-PeCDD 95123478-HxCDD 28 J ES 123478-HxCDD 9123678-HxCDD EMPC 36.6 J ES 123678-HxCDD 93123789-HxCDD 49.5 J ES 123789-HxCDD 971234678-HpCDD 135 ES 1234678-HpCDD 10OCDD 563 ES OCDD 92378-TCDF 4.29 J ES 2378-TCDF 9612378-PeCDF EMPC 2.36 J ES 12378-PeCDF 9423478-PeCDF 5.98 J ES 23478-PeCDF 91123478-HxCDF 4.19 J ES 123478-HxCDF 97123678-HxCDF 4.37 J ES 123678-HxCDF 97234678-HxCDF 4.85 J ES 234678-HxCDF 93123789-HxCDF ND 1.48 ES 123789-HxCDF 91234678-HpCDF 11.6 J ES 1234678-HpCDF 971234789-HpCDF ND 1.76 ES 1234789-HpCDF 97OCDF EMPC 6.56 J ES OCDF 92

Totals Standard SS/AS R

SS 37Cl-2378-TCDD 96

Total TCDD 2310 2310 SS 12347-PeCDD 98Total PeCDD 1600 1600 SS 12346-PeCDF 96Total HxCDD 782 819 SS 123469-HxCDF 99Total HpCDD 336 336 SS 1234689-HpCDF 96

AS 1368-TCDD 94

Total TCDF 208 243 AS 1368-TCDF 92Total PeCDF 60.5 79.8Total HxCDF 31.4 31.4Total HpCDF 14.3 17.4

Total PCDD/Fs 5900 6000ITEF TEQsTEQ: ND=0 121 125 

TEQ: ND=DL/2 121 125 TEQ: ND=DL 121 125 

 Tel: +1 910 794-1613 (Fax: -3919); Toll-Free 866 846-8290 

Checkcode: 399-397 AP D/F 2010 Rev. L Report Created: 15-
Sample ID: Plant 5 Outlet-R2 

Client Data Sample Data Laboratory Data Software 

Name: Analytical Testing Consultants, Inc. Matrix: Air Lab Project ID: P2695 Date Rec

Project ID: P-10124 Weight/Volume: 1 Lab Sample ID P2695_8210_005 Date ExtDate Collected: 18 Sep 2010 QC Batch No: 8210 Date Ana

Split: 2 Dilution: - Time Ana

Analyte Conc. (pg) DL (pg) EMPC (pg) Qualifiers Standard ES Rec

2378-TCDD 29.4 [Ra=0.71] ES 2378-TCDD 9612378-PeCDD 42.6 J ES 12378-PeCDD 95123478-HxCDD 16.8 J ES 123478-HxCDD 94123678-HxCDD 20.4 J ES 123678-HxCDD 93123789-HxCDD 29.2 J ES 123789-HxCDD 961234678-HpCDD 91 ES 1234678-HpCDD 93OCDD 421 ES OCDD 82378-TCDF 5.58 J ES 2378-TCDF 9312378-PeCDF EMPC 3.4 J ES 12378-PeCDF 9123478-PeCDF 6.89 J ES 23478-PeCDF 91123478-HxCDF EMPC 3.98 J ES 123478-HxCDF 92123678-HxCDF EMPC 5 J ES 123678-HxCDF 92234678-HxCDF 5.76 J ES 234678-HxCDF 92123789-HxCDF ND 1.82 ES 123789-HxCDF 941234678-HpCDF 12.2 J ES 1234678-HpCDF 921234789-HpCDF ND 2.27 ES 1234789-HpCDF 90OCDF 6.95 J ES OCDF 8

Totals Standard SS/AS R

SS 37Cl-2378-TCDD 9

Total TCDD 1170 1170 SS 12347-PeCDD 97Total PeCDD 820 820 SS 12346-PeCDF 99Total HxCDD 439 463 SS 123469-HxCDF 10Total HpCDD 221 221 SS 1234689-HpCDF 98

AS 1368-TCDD 89

Total TCDF 207 232 AS 1368-TCDF 88Total PeCDF 53.7 88.9Total HxCDF 12.8 39.6Total HpCDF 15.7 17.6

Total PCDD/Fs 3370 3480ITEF TEQsTEQ: ND=0 63.4 64.5 

TEQ: ND=DL/2 63.7 64.6 TEQ: ND=DL 64 64.7 

 Tel: +1 910 794-1613 (Fax: -3919); Toll-Free 866 846-8290 

Checkcode: 126-168 AP D/F 2010 Rev. L Report Created: 15-
Sample ID: Plant 5 Outlet-R3 

Client Data Sample Data Laboratory Data Software 

Name: Analytical Testing Consultants, Inc. Matrix: Air Lab Project ID: P2695 Date Rec

Project ID: P-10124 Weight/Volume: 1 Lab Sample ID P2695_8210_006 Date ExtDate Collected: 18 Sep 2010 QC Batch No: 8210 Date Ana

Split: 2 Dilution: - Time Ana

Analyte Conc. (pg) DL (pg) EMPC (pg) Qualifiers Standard ES Rec

2378-TCDD EMPC [Ra=0.90] 33.8 ES 2378-TCDD 8212378-PeCDD 61.7 ES 12378-PeCDD 86123478-HxCDD 20.6 J ES 123478-HxCDD 88123678-HxCDD 29.4 J ES 123678-HxCDD 90123789-HxCDD 41.3 J ES 123789-HxCDD 911234678-HpCDD 108 ES 1234678-HpCDD 91OCDD 549 ES OCDD 852378-TCDF EMPC 3.02 J ES 2378-TCDF 8012378-PeCDF EMPC 2.68 J ES 12378-PeCDF 8223478-PeCDF 5.68 J ES 23478-PeCDF 83123478-HxCDF 3.74 J ES 123478-HxCDF 88123678-HxCDF EMPC 2.63 J ES 123678-HxCDF 86234678-HxCDF EMPC 4.22 J ES 234678-HxCDF 85123789-HxCDF ND 2.73 ES 123789-HxCDF 891234678-HpCDF 12 J ES 1234678-HpCDF 891234789-HpCDF ND 3.31 ES 1234789-HpCDF 87OCDF EMPC 6.83 J ES OCDF 85

Totals Standard SS/AS R

SS 37Cl-2378-TCDD 99

Total TCDD 1430 1480 SS 12347-PeCDD 98Total PeCDD 1040 1040 SS 12346-PeCDF 9Total HxCDD 545 568 SS 123469-HxCDF 10Total HpCDD 268 268 SS 1234689-HpCDF 10

AS 1368-TCDD 76

Total TCDF 94 157 AS 1368-TCDF 75Total PeCDF 42.1 55Total HxCDF 3.74 23.3Total HpCDF 12 12

Total PCDD/Fs 3990 4160ITEF TEQsTEQ: ND=0 45 79.9 

TEQ: ND=DL/2 47.2 80 TEQ: ND=DL 49.4 80.2 

 Tel: +1 910 794-1613 (Fax: -3919); Toll-Free 866 846-8290 

Checkcode: 589-525 AP D/F 2010 Rev. L Report Created: 15-
Sample ID: Plant 5 Oven-R1 

Client Data Sample Data Laboratory Data Software 

Name: Analytical Testing Consultants, Inc. Matrix: Air Lab Project ID: P2695 Date Rec

Project ID: P-10124 Weight/Volume: 1 Lab Sample ID P2695_8210_007 Date ExtDate Collected: 18 Sep 2010 QC Batch No: 8210 Date Ana

Split: 2 Dilution: - Time Ana

Analyte Conc. (pg) DL (pg) EMPC (pg) Qualifiers Standard ES Rec

2378-TCDD ND 1.77 ES 2378-TCDD 9012378-PeCDD ND 1.76 ES 12378-PeCDD 89123478-HxCDD ND 1.77 ES 123478-HxCDD 86123678-HxCDD ND 1.68 ES 123678-HxCDD 89123789-HxCDD ND 1.88 ES 123789-HxCDD 921234678-HpCDD 13.4 J ES 1234678-HpCDD 91OCDD 37.8 J ES OCDD 872378-TCDF EMPC 3 J ES 2378-TCDF 8612378-PeCDF 3.72 J ES 12378-PeCDF 8523478-PeCDF 5.89 J ES 23478-PeCDF 84123478-HxCDF 6.01 J ES 123478-HxCDF 87123678-HxCDF 5.4 J ES 123678-HxCDF 86234678-HxCDF EMPC 5.4 J ES 234678-HxCDF 88123789-HxCDF ND 1.86 ES 123789-HxCDF 881234678-HpCDF 11.4 J ES 1234678-HpCDF 891234789-HpCDF ND 2.63 ES 1234789-HpCDF 89OCDF EMPC 3.15 J ES OCDF 84

Totals Standard SS/AS R

SS 37Cl-2378-TCDD 98

Total TCDD 28 40.9 SS 12347-PeCDD 10Total PeCDD 56.7 63.1 SS 12346-PeCDF 98Total HxCDD 63 63 SS 123469-HxCDF 10Total HpCDD 40.8 40.8 SS 1234689-HpCDF 98

AS 1368-TCDD 93

Total TCDF 82.7 109 AS 1368-TCDF 87Total PeCDF 44.7 60.5Total HxCDF 26.4 35.6Total HpCDF 11.4 11.4

Total PCDD/Fs 391 465ITEF TEQsTEQ: ND=0 4.56 5.4 

TEQ: ND=DL/2 6.42 7.1 TEQ: ND=DL 8.28 8.79 

 Tel: +1 910 794-1613 (Fax: -3919); Toll-Free 866 846-8290 

Checkcode: 634-960 AP D/F 2010 Rev. L Report Created: 15-
Sample ID: Plant 5 Oven-R2 

Client Data Sample Data Laboratory Data Software 

Name: Analytical Testing Consultants, Inc. Matrix: Air Lab Project ID: P2695 Date Rec

Project ID: P-10124 Weight/Volume: 1 Lab Sample ID P2695_8210_008 Date ExtDate Collected: 18 Sep 2010 QC Batch No: 8210 Date Ana

Split: 2 Dilution: - Time Ana

Analyte Conc. (pg) DL (pg) EMPC (pg) Qualifiers Standard ES Rec

2378-TCDD ND 2.7 ES 2378-TCDD 9812378-PeCDD ND 2.75 ES 12378-PeCDD 94123478-HxCDD ND 3.16 ES 123478-HxCDD 89123678-HxCDD ND 3.25 ES 123678-HxCDD 91123789-HxCDD ND 3.09 ES 123789-HxCDD 951234678-HpCDD EMPC 8.43 J ES 1234678-HpCDD 93OCDD EMPC 27.5 J ES OCDD 872378-TCDF EMPC 3.49 J ES 2378-TCDF 9612378-PeCDF ND 3.61 ES 12378-PeCDF 9223478-PeCDF ND 3.61 ES 23478-PeCDF 92123478-HxCDF ND 2.02 ES 123478-HxCDF 94123678-HxCDF ND 2.06 ES 123678-HxCDF 92234678-HxCDF ND 2.05 ES 234678-HxCDF 88123789-HxCDF ND 2.63 ES 123789-HxCDF 941234678-HpCDF ND 2.31 ES 1234678-HpCDF 941234789-HpCDF ND 3.29 ES 1234789-HpCDF 91OCDF ND 2.96 ES OCDF 83

Totals Standard SS/AS R

SS 37Cl-2378-TCDD 97

Total TCDD 59 72.4 SS 12347-PeCDD 97Total PeCDD 62.6 81.2 SS 12346-PeCDF 99Total HxCDD 90.3 90.3 SS 123469-HxCDF 10Total HpCDD 27.8 36.2 SS 1234689-HpCDF 98

AS 1368-TCDD 92

Total TCDF 36 71.1 AS 1368-TCDF 94Total PeCDF ND 3.61 NDTotal HxCDF 4.43 4.43Total HpCDF ND 2.74 ND

Total PCDD/Fs 280 383ITEF TEQsTEQ: ND=0 0 0.461 

TEQ: ND=DL/2 4.16 4.43 TEQ: ND=DL 8.32 8.41 

 Tel: +1 910 794-1613 (Fax: -3919); Toll-Free 866 846-8290 

Checkcode: 876-500 AP D/F 2010 Rev. L Report Created: 15-
Sample ID: Plant 5 Oven-R3 

Client Data Sample Data Laboratory Data Software 

Name: Analytical Testing Consultants, Inc. Matrix: Air Lab Project ID: P2695 Date Rec

Project ID: P-10124 Weight/Volume: 1 Lab Sample ID P2695_8210_009 Date ExtDate Collected: 18 Sep 2010 QC Batch No: 8210 Date Ana

Split: 2 Dilution: - Time Ana

Analyte Conc. (pg) DL (pg) EMPC (pg) Qualifiers Standard ES Rec

2378-TCDD ND 2.03 ES 2378-TCDD 1012378-PeCDD ND 2.31 ES 12378-PeCDD 10123478-HxCDD ND 1.87 ES 123478-HxCDD 9123678-HxCDD ND 1.81 ES 123678-HxCDD 9123789-HxCDD ND 1.99 ES 123789-HxCDD 101234678-HpCDD 9.41 J ES 1234678-HpCDD 95OCDD EMPC 26.2 J ES OCDD 942378-TCDF ND 2.26 ES 2378-TCDF 1012378-PeCDF ND 2.46 ES 12378-PeCDF 9623478-PeCDF ND 2.08 ES 23478-PeCDF 96123478-HxCDF 3.86 J ES 123478-HxCDF 95123678-HxCDF 3.2 J ES 123678-HxCDF 96234678-HxCDF 5.01 J ES 234678-HxCDF 93123789-HxCDF ND 2.77 ES 123789-HxCDF 91234678-HpCDF 8.79 J ES 1234678-HpCDF 991234789-HpCDF ND 1.9 ES 1234789-HpCDF 9OCDF EMPC 4.26 J ES OCDF 90

Totals Standard SS/AS R

SS 37Cl-2378-TCDD 98

Total TCDD ND 13.6 SS 12347-PeCDD 95Total PeCDD 17.2 17.2 SS 12346-PeCDF 10Total HxCDD 20.7 31.7 SS 123469-HxCDF 98Total HpCDD 9.41 22.1 SS 1234689-HpCDF 97

AS 1368-TCDD 10

Total TCDF 21.5 27.8 AS 1368-TCDF 10Total PeCDF 5.73 10.4Total HxCDF 14.8 25.1Total HpCDF 8.79 8.79

Total PCDD/Fs 98.1 187ITEF TEQsTEQ: ND=0 1.39 1.42 

TEQ: ND=DL/2 4.11 4.14 TEQ: ND=DL 6.83 6.85 

 Tel: +1 910 794-1613 (Fax: -3919); Toll-Free 866 846-8290 

Checkcode: 591-982 AP D/F 2010 Rev. L Report Created: 15-