UNITED STATES ENVIRONMENTAL PROTECTION AGENCY QUICKLOOK ALL PARAMETERS May. 29, 2014 Report Request ID: 1218191 Report Code: AMP450NC

Selection Criteria Page 1 User ID:HSL

State County City Site Parameter POC AQCR UAR CBSA CSA EPA Region 04 GEOGRAPHIC SELECTIONS

PROTOCOL SELECTIONS Parameter Classification Parameter Method Duration ALL AGENCY SELECTIONS Arizona Department Of Environmental Quality Freeport McMoRan Miami, Inc. SELECTED OPTIONS

MERGE PDF FILES EVENTS PROCESSING AGENCY ROLE Option Type Option Value YES EXCLUDE REGIONALLY CONCURRED EVENTS

PQAO SORT ORDER

1 2 3 4 5 6 7 Order Column

STATE_CODE COUNTY_CODE SITE_ID PARAMETER_CODE POC DATES EDT_ID DATE CRITERIA

2013 Start Date End Date 2013 Tribal Code

APPLICABLE STANDARDS Standard Description CO 8-hour 1971 Lead 3-Month 2009 Lead 3-Month PM10 Surrogate 2009 Lead Quarterly 1978 NO2 Annual 1971 Ozone 8-Hour 2008 PM10 24-hour 2006 PM25 24-hour 2006 SO2 1-hour 2010UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014 QUICKLOOK ALL PARAMETERS

EXCEPTIONAL DATA TYPES EDT DESCRIPTION 0 1 2 5 NO EVENTS EVENTS EXCLUDED EVENTS INCLUDED EVENTS WITH CONCURRENCE EXCLUDEDUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 2 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

3 3

1 1 3 3 1 3 3

1

1 1 1 1 1

1 0053 0053

0053 0053 0053 0053 0053 0053 0053

0053

0053 0053 0053 0053 0053

0053 2013 2013

2013 2013 2013 2013 2013 2013 2013

2013

2013 2013 2013 2013 2013

2013 8059

337

29 29 8683 364 29 4032 167

5736

60 60 60 60 60

59 1027

165

31.6 666 924 251 17.5 65.0 12.9

.072

22.2 598 30 24 11.1

58 836

102

31.1 665 815 218 17.0 59.0 12.2

.070

21.7 596 27 22 10.2

43 750

90

30.7 664 721 115 12.1 53.0 12.0

.070

21.6 596 27 22 9.6

33 649

88

29.2 664 699 111 11.6 51.0 11.4

.069

21.0 596 26 22 8.7

32 21.2

20.7*

17.67* 658.1* 37.7 37.3 7.25* 6.75* 6.68*

.0521

8.48 592.0 15.9 13.0 5.43

19.21 HOUR 24-HR BLK AVG

24 HOUR 24 HOUR 1 HOUR 24-HR BLK AVG 24 HOUR 1 HOUR 24-HR BLK AVG

8-HR RUN AVG BEGIN HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR

24 HOUR 5

5

0 0 5 5 0 0 0

0

0 0 0 0 0

0 81102 81102

68105 68108 81102 81102 88101 88101 88101

44201

68105 68108 81102 85101 88101

81102 Parameter Site ID:

Site ID:

Site ID:

Site ID:04-003-0011

04-003-1005

04-005-1008

04-007-0008 Paul Spur

Douglas

Flagstaff

Payson City:

City:

City:

City: Cochise

Cochise

Coconino

Gila Unit County:

County:

County:

County: HOUSING AREA, PAUL SPUR

1445-1449 15TH STREET

755 W BONITO

204 W AERO DR Address:

Address:

Address:

Address: PM10 Total 0-10um STP PM10 Total 0-10um STP

Ambient Temperature Sample Baro Pressure PM10 Total 0-10um STP PM10 Total 0-10um STP PM2.5 - Local Conditions PM2.5 - Local Conditions PM2.5 - Local Conditions

Ozone Ambient Temperature Sample Baro Pressure PM10 Total 0-10um STP PM10 - LC PM2.5 - Local Conditions

PM10 Total 0-10um STP Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Degrees Centigrade Millimeters (mercury) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Parts per million Degrees Centigrade Millimeters (mercury) Micrograms/cubic meter (25 C) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (25 C) Meth

079 079

143 143 079 079 143 170 170

087

143 143 126 126 143

126 Cert& Eval

S S

S S S S S

S

S

S

SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 3 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

2 1 2

1 1 1

1

1 1

1 1

3 3 3 3 0053 0053 0053

0053 0053 1357

0053

0053 0053

0053 0053

0053 0053 0053 0053 2013 2013 2013

2013 2013 2013

2013

2013 2013

2013 2013

2013 2013 2013 2013 57

59 57

8729 8709 58

5865

7411 7398

7397 7412

8466 8472 355 8564 54

50 46

193.0 319.9 51

.082

205.0 734.9

171.0 322.0

310.0 1241.2 407 1798 40

36 34

139.0 312.3 27

.074

188.0 565.7

136.0 259.0

306.0 981.5 144 1448 37

29 33

128.0 252.4 25

.072

150.0 462.9

118.0 252.0

256.0 928.1 120 1274 33

28 30

117.0 222.8 25

.072

148.0 342.5

117.0 248.4

256.0 817.5 119 1261 18.5

16.7 16.0

20.72 9.17 12.8

.0559

21.64* 7.08

16.50* 4.13

50.45 18.99 42.4 43.424 HOUR 24 HOUR 24 HOUR

1 HOUR 1 HOUR 24 HOUR

8-HR RUN AVG BEGIN HOUR

1 HOUR 1 HOUR

1 HOUR 1 HOUR

1 HOUR 1 HOUR 24-HR BLK AVG 1 HOUR 0

0 0

0 0 0

0

0 0

0 0

0 0 5 5 81102 85101 85101

42401 42406 81102

44201

42401 42406

42401 42406

42401 42406 81102 81102 Parameter Site ID:

Site ID:

Site ID:

Site ID:

Site ID:

Site ID:

Site ID:04-007-0008

04-007-0009

04-007-0010

04-007-0011

04-007-0012

04-007-1001

04-007-1002 Payson

Miami

Tonto National Monument

Not in a city

Miami

Hayden

Not in a city City:

City:

City:

City:

City:

City:

City: Gila

Gila

Gila

Gila

Gila

Gila

Gila Unit County:

County:

County:

County:

County:

County:

County: 204 W AERO DR

4030 LINDEN STREET

SOUTH OF SR88

Cherry Flats Rd.

Sullivan ST & Davis Canyon

JAIL-CANYON DR, HAYDEN

SR 77 Address:

Address:

Address:

Address:

Address:

Address:

Address: PM10 Total 0-10um STP PM10 - LC PM10 - LC

Sulfur dioxide SO2 max 5-min avg PM10 Total 0-10um STP

Ozone

Sulfur dioxide SO2 max 5-min avg

Sulfur dioxide SO2 max 5-min avg

Sulfur dioxide SO2 max 5-min avg PM10 Total 0-10um STP PM10 Total 0-10um STP Micrograms/cubic meter (25 C) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Parts per billion Parts per billion Micrograms/cubic meter (25 C) Parts per million

Parts per billion Parts per billion Parts per billion Parts per billion Parts per billion Parts per billion Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Meth

126 126 126

060 060 197

087

592 592

592 592

000 000 079 079 Cert& Eval

S

S

S

S

S

S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 4 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

1 2 1 2 1 2

1 1 1 1 2 3 3

1

6 6 6 0053 0053 0053 0053 0053 0053

0053 0053 0053 1357 1357 0053 0053

0053

0053 0053 0053 2013 2013 2013 2013 2013 2013

2013 2013 2013 2013 2013 2013 2013

2013

2013 2013 2013 60

58 60 62 60 62

61 61 61 61 57 8535 354

5820

31 31 31 .501

.502 36.2 34.7 717 716

.091 32.2 684 55 54 405 129

.075

.16 6.03 6.88 .327

.319 35.7 34.6 715 715

.064 31.5 682 35 37 316 129

.074

.03 5.61 6.76 .281

.267 35.5 34.5 714 714

.054 30.5 682 34 35 309 79

.071

.03 5.49 6.48 .210

.191 34.5 34.2 714 714

.045 30.0 682 34 33 285 68

.071

.02 4.95 5.24 .0766

.0770 23.55 23.20 707.7 707.6

.0186 18.20 676.0 16.7 17.4* 22.9 22.5

.0535

.019 2.322 2.25324 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR

24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 1 HOUR 24-HR BLK AVG

8-HR RUN AVG BEGIN HOUR

24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0

0 0 0 0 0 0 0

0

0 0 0 14129 14129 68105 68105 68108 68108

14129 68105 68108 81102 81102 81102 81102

44201

42153 43205 43206 Parameter Site ID:

Site ID:

Site ID:

Site ID:04-007-1002

04-007-8000

04-012-8000

04-013-4003 Not in a city

Globe

Wenden

Phoenix City:

City:

City:

City: Gila

Gila

La Paz

Maricopa Unit County:

County:

County:

County: SR 77

SR 188 & US 60

ALAMO LAKE STATE PARK

33 W TAMARISK AVE, PHOENIX Address:

Address:

Address:

Address: Lead (TSP) LC Lead (TSP) LC Ambient Temperature Ambient Temperature Sample Baro Pressure Sample Baro Pressure Lead (TSP) LC Ambient Temperature Sample Baro Pressure PM10 Total 0-10um STP PM10 Total 0-10um STP PM10 Total 0-10um STP PM10 Total 0-10um STP

Ozone

Carbon disulfide Propylene Acetylene Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Degrees Centigrade Degrees Centigrade Millimeters (mercury) Millimeters (mercury) Micrograms/cubic meter (LC) Degrees Centigrade Millimeters (mercury) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Parts per million

Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

191 191 780 780 780 780

191 780 780 197 197 079 079

087

101 101 101 Cert& Eval

S S

S

S S

SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 5 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 31

31 31 31 31 31 31 31 30 31 31 31 31 31 31 31 31 .04

1.10 1.02 .31 .04 .04 .00 .07 2.36 .41 .55 .72 .73 2.66 .08 .12 .00 .04

1.08 .99 .00 .04 .04 .00 .07 2.25 .38 .45 .21 .72 .52 .07 .12 .00 .04

1.02 .90 .00 .04 .04 .00 .00 2.10 .33 .43 .18 .70 .25 .07 .11 .00 .04

.95 .72 .00 .04 .04 .00 .00 1.93 .33 .43 .15 .69 .24 .07 .11 .00 .032

.404 .434 .010 .039 .042 .000 .005 1.175 .253 .290 .041 .621 .223 .040 .097 .00024 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43208 43218 43233 43372 43373 43396 43438 43441 43505 43560 43702 43704 43801 43802 43803 43804 43806 Parameter Site ID:04-013-4003 Phoenix City: Maricopa Unit County: 33 W TAMARISK AVE, PHOENIX Address: Freon 114 1,3-Butadiene n-Octane Methyl tert-butyl ether Tert-amyl methyl ether tert-Butyl ethyl ether Ethyl acrylate Methyl methacrylate Acrolein - Unverified Methyl isobutyl ketone Acetonitrile Acrylonitrile Chloromethane Dichloromethane Chloroform Carbon tetrachloride Bromoform Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 6 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 31

31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 .36

.04 .00 .03 .07 .23 .00 .02 .00 .19 .73 .03 0 .01 .00 .08 .07 .36

.00 .00 .01 .06 .10 .00 .02 .00 .19 .71 .03 0 .01 .00 .00 .05 .35

.00 .00 .01 .06 .10 .00 .01 .00 .18 .63 .02 0 .01 .00 .00 .00 .32

.00 .00 .01 .06 .09 .00 .01 .00 .18 .62 .02 0 .01 .00 .00 .00 .278

.001 .000 .005 .030 .046 .000 .006 .000 .167 .543 .004 .0 .010 .000 .003 .00424 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43811 43812 43813 43814 43815 43817 43818 43819 43820 43821 43823 43824 43826 43828 43829 43830 43831 Parameter Site ID:04-013-4003 Phoenix City: Maricopa Unit County: 33 W TAMARISK AVE, PHOENIX Address: Trichlorofluoromethane Chloroethane 1,1-Dichloroethane Methyl chloroform Ethylene dichloride Tetrachloroethylene 1,1,2,2-Tetrachloroethane Bromomethane 1,1,2-Trichloroethane 1,1,2-Trichloro-1,2,2- trifluoroethane Dichlorodifluoromethane Trichloroethylene 1,1-Dichloroethylene Bromodichloromethane 1,2-Dichloropropane trans-1,3-Dichloropropene cis-1,3-Dichloropropene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 7 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 31

31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 .01

.00 .01 .01 .02 .00 .00 .00 11.20 4.40 19.88 3.47 4.23 .94 2.93 1.02 .00 .01

.00 .01 .01 .02 .00 .00 .00 8.00 4.24 14.98 2.84 3.08 .89 2.90 .96 .00 .01

.00 .01 .01 .02 .00 .00 .00 7.28 3.96 14.63 2.58 2.86 .86 2.84 .75 .00 .01

.00 .01 .01 .02 .00 .00 .00 6.80 3.42 12.74 2.34 2.84 .74 2.49 .61 .00 .009

.000 .008 .012 .016 .000 .000 .000 3.444 2.005 7.445 1.249 1.342 .366 1.242 .281 .00024 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43832 43835 43836 43838 43839 43843 43844 43860 45109 45201 45202 45203 45204 45207 45208 45220 45801 Parameter Site ID:04-013-4003 Phoenix City: Maricopa Unit County: 33 W TAMARISK AVE, PHOENIX Address: Dibromochloromethane Chloroprene Bromochloromethane trans-1,2-Dichloroethylene cis-1,2-Dichloroethene Ethylene dibromide Hexachlorobutadiene Vinyl chloride m/p Xylene Benzene Toluene Ethylbenzene o-Xylene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene Styrene Chlorobenzene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 8 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

6 6 6 6

6 7 3 3 3 3 3 3 3 3 3 3 0053 0053 0053 0053

0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013

2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 31

31 31 31

29 3 58 58 58 58 58 58 58 58 58 58 .07

.08 .49 .05

.00 .00 287.000 4.7200 10.9000 5.6900 11.100 1.4500 5.1000 3.5200 .446 2.5500 .07

.08 .47 .00

.00 .00 272.000 4.1400 7.4200 5.3600 11.100 .9850 4.9400 3.4000 .256 2.3800 .07

.08 .38 .00

.00 .00 263.000 3.8100 6.0400 4.6400 10.800 .9530 4.0900 3.2800 .232 2.3400 .07

.08 .36 .00

.00

241.000 3.7900 6.0300 4.3900 10.100 .8310 3.7800 3.2200 .157 2.3200 .069

.078 .217 .002

.000* .000* 93.4138 2.23476 1.26971 2.33216 6.4459 .34120 .84594 1.60574 .0355 1.3671924 HOUR

24 HOUR 24 HOUR 24 HOUR

24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 45805 45806 45807 45810

12115 12115 17141 17147 17148 17149 17150 17151 17158 17159 17160 17201 Parameter Site ID:

Site ID:04-013-4003

04-013-9997 Phoenix

Phoenix City:

City: Maricopa

Maricopa Unit County:

County: 33 W TAMARISK AVE, PHOENIX

4530 N 17TH AVENUE Address:

Address: 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2,4-Trichlorobenzene

Chromium VI (TSP) STP Chromium VI (TSP) STP Naphthalene (TSP) STP Acenaphthene (TSP) STP Acenaphthylene (TSP) STP Fluorene (TSP) STP Phenanthrene (TSP) STP Anthracene (TSP) STP Retene (TSP) STP 9-fluorenone (TSP) STP Cyclopenta[cd]pyrene (TSP) STP Fluoranthene (TSP) STP Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Meth

101 101 101 101

920 920 118 118 118 118 118 118 118 118 118 118 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 9 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

3 3 3 3 3 3 3 3 3 3 3 3 1

6 7 1 1 1 1 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053

0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013

2013 2013 2013 2013 2013 2013 58

58 58 58 58 58 58 58 58 58 58 58 7672

61 7 7713 7687 8410 7625 2.1200

.8190 .317 .1290 .594 1.530 .415 .619 .102 .788 .699 .9510 2.0

.11 .05 7.8 9.0 216.1 274.0 1.5400

.6930 .316 .1050 .488 1.290 .297 .606 .100 .674 .638 .6750 1.9

.06 .04 6.6 8.7 215.6 230.0 1.4000

.6740 .270 .0985 .463 1.010 .272 .522 .099 .628 .615 .6740 1.9

.05 .03 6.4 8.6 214.5 195.0 1.3700

.5280 .232 .0742 .357 .954 .246 .466 .074 .590 .477 .5010 1.9

.04 .03 5.5 7.4 214.1 195.0 .84448

.16606 .0673 .01376 .0811 .2217 .0525 .1116 .0126 .1522 .1058 .12725 .42

.026 .027* 1.90* 1.06 28.01 13.8124 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 8-HR RUN AVG END HOUR 24 HOUR 24 HOUR 1 HOUR 1 HOUR 1 HOUR 1 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 17204 17208 17211 17212 17215 17220 17223 17224 17231 17237 17242 17243 42101

42153 42153 42401 42406 42600 42601 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Pyrene (TSP) STP Chrysene (TSP) STP Coronene (TSP) STP Perylene (TSP) STP Benzo[a]anthracene (TSP) STP Benzo[b]fluoranthene (TSP) STP Benzo[k]fluoranthene (TSP) STP Benzo[e]pyrene (TSP) STP Dibenzo[a,h]anthracene (TSP) STP Benzo[g,h,i]perylene (TSP) STP Benzo[a]pyrene (TSP) STP Indeno[1,2,3-cd]pyrene (TSP) STP Carbon monoxide

Carbon disulfide Carbon disulfide Sulfur dioxide SO2 max 5-min avg Reactive oxides of nitrogen (NOy) Nitric oxide (NO) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Nanograms/cubic meter (25 C) Parts per million Parts per billion Carbon Parts per billion Carbon Parts per billion Parts per billion Parts per billion Parts per billion Meth

118 118 118 118 118 118 118 118 118 118 118 118 588

101 101 592 592 591 000 Cert& Eval

S

SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 10 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

1 1 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 7625

7625 15 1 15 1 15 1 15 1 15 1 15 1 15 1 15 1 72.0 323.0 200.00 254.00 .17 .17 .09 .09 .09 .09 .09 .09 .20 .09 7.26 6.98 4.00 2.61 62.0

269.0 172.00

.17

.09

.09

.09

.09

6.96

3.83 59.0

250.0 167.00

.17

.09

.09

.09

.09

6.87

3.45 59.0

240.0 161.00

.17

.09

.09

.09

.09

6.33

3.34 16.98

30.68 137.827* 254.000* .167* .167* .094* .094* .094* .094* .094* .094* .101* .094* 5.297* 6.980* 2.573* 2.610*1 HOUR 1 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 42602 42603 43102 43102 43141 43141 43142 43142 43143 43143 43144 43144 43145 43145 43202 43202 43203 43203 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Nitrogen dioxide (NO2) Oxides of nitrogen (NOx) Total NMOC (non-methane organic compound) Total NMOC (non-methane organic compound) n-Dodecane n-Dodecane Tridecene Tridecene n-Tridecane n-Tridecane Propyne Propyne 1-Octene 1-Octene Ethane Ethane Ethylene Ethylene Parts per billion Parts per billion Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

000 000 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert& Eval

SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 11 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 6 7 8 9 6 7 8 9 6 7 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 15

1 61 7 15 1 61 7 15 1 61 7 15 1 15 1 15 8.48

3.34 7.02 6.27 1.33 .87 7.00 5.62 1.32 .50 .05 .04 4.03 1.26 2.30 .92 .28 5.70

6.48 2.68 1.22

6.94 2.10 1.27

.04 .04 3.01

1.99

.21 4.76

5.88 2.09 1.21

5.78 1.42 1.06

.04 .03 2.75

1.99

.19 4.58

5.64 1.31 1.04

5.48 1.26 1.05

.04 .03 2.09

1.92

.18 3.773*

3.340* 2.317 2.235* .823* .869* 2.085 1.874* .766* .501* .033 .034* 1.866* 1.260* 1.205* .922* .113*24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43204 43204 43205 43205 43205 43205 43206 43206 43206 43206 43208 43208 43212 43212 43214 43214 43216 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Propane Propane Propylene Propylene Propylene Propylene Acetylene Acetylene Acetylene Acetylene Freon 114 Freon 114 n-Butane n-Butane Isobutane Isobutane trans-2-Butene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 101 101 126 126 101 101 126 126 101 101 126 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 12 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 6 7 8 9 8 9 8 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 1

15 1 61 7 15 1 15 1 2 15 1 15 1 15 1 15 .22

.10 .05 1.33 1.14 .34 .00 4.08 1.42 11.40 .50 .21 .41 .09 .40 .16 .11 .10

1.18 .46 .31

4.00

9.20 .37

.41

.35

.11 .05

1.11 .36 .26

3.79

.33

.32

.27

.11 .05

1.11 .22 .20

3.19

.32

.30

.24

.11 .216*

.056* .049* .382 .367* .104* .000* 2.423* 1.420* 10.300* .222* .210* .207* .094* .174* .164* .105*24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43216 43217 43217 43218 43218 43218 43218 43220 43220 43221 43224 43224 43225 43225 43226 43226 43227 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: trans-2-Butene cis-2-Butene cis-2-Butene 1,3-Butadiene 1,3-Butadiene 1,3-Butadiene 1,3-Butadiene n-Pentane n-Pentane Isopentane 1-Pentene 1-Pentene 2-Methyl-1-butene 2-Methyl-1-butene trans-2-Pentene trans-2-Pentene cis-2-Pentene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 101 101 126 126 126 126 126 126 126 126 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 13 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 8 9 8 9 6 7 8 9 8 9 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 1

15 1 15 1 15 1 15 1 61 7 15 1 15 1 15 1 .11

.50 .22 1.80 .52 1.79 .58 1.28 .74 1.38 1.39 .75 .33 .09 .09 .51 .29 .50

1.62

1.66

1.26

1.17 .66 .62

.09

.40 .40

1.25

1.25

.97

1.16 .55 .53

.09

.37 .34

1.17

1.20

.84

1.00 .34 .50

.09

.34 .105*

.264* .221* .887* .515* .917* .580* .736* .740* .461 .520* .397* .325* .094* .094* .270* .288*24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43227 43228 43228 43230 43230 43231 43231 43232 43232 43233 43233 43233 43233 43234 43234 43235 43235 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: cis-2-Pentene 2-Methyl-2-butene 2-Methyl-2-butene 3-Methylpentane 3-Methylpentane n-Hexane n-Hexane n-Heptane n-Heptane n-Octane n-Octane n-Octane n-Octane 4-Methyl-1-pentene 4-Methyl-1-pentene n-Nonane n-Nonane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 101 101 126 126 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 14 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 15

1 15 1 15 1 15 1 15 1 15 1 15 1 15 1 15 .09

.09 .74 .29 .50 .12 2.76 .68 .51 .13 .22 .22 .09 .09 .82 .16 1.87 .09

.63

.46

2.11

.48

.22

.09

.76

1.79 .09

.49

.40

2.10

.38

.22

.09

.56

1.61 .09

.48

.38

2.01

.34

.22

.09

.52

1.29 .094*

.094* .371* .291* .242* .124* 1.765* .682* .244* .132* .223* .223* .094* .094* .372* .159* 1.004*24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43236 43236 43238 43238 43242 43242 43243 43243 43244 43244 43245 43245 43246 43246 43247 43247 43248 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: 2-Ethyl-1-butene 2-Ethyl-1-butene n-Decane n-Decane Cyclopentane Cyclopentane Isoprene Isoprene 2,2-Dimethylbutane 2,2-Dimethylbutane 1-Hexene 1-Hexene 2-Methyl-1-pentene 2-Methyl-1-pentene 2,4-Dimethylpentane 2,4-Dimethylpentane Cyclohexane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 15 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 1

15 1 15 1 15 1 15 1 15 1 15 1 15 1 15 1 .62

1.89 .88 3.64 1.64 1.41 .70 .53 .19 .77 .39 .09 .09 1.27 .33 1.73 .49 1.85

3.39

1.30

.52

.74

.09

1.20

1.53 1.36

2.48

1.17

.37

.60

.09

.98

1.21 1.19

2.36

.99

.37

.58

.09

.82

1.06 .616*

.977* .877* 1.904* 1.640* .824* .700* .275* .186* .431* .387* .094* .094* .677* .327* .847* .488*24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43248 43249 43249 43250 43250 43252 43252 43253 43253 43256 43256 43257 43257 43261 43261 43262 43262 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Cyclohexane 3-Methylhexane 3-Methylhexane 2,2,4-Trimethylpentane 2,2,4-Trimethylpentane 2,3,4-Trimethylpentane 2,3,4-Trimethylpentane 3-Methylheptane 3-Methylheptane alpha.-Pinene alpha.-Pinene beta.-Pinene beta.-Pinene Methylcyclohexane Methylcyclohexane Methylcyclopentane Methylcyclopentane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 16 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 15

1 15 1 15 1 15 1 15 1 15 1 15 1 15 1 15 3.14

2.55 .20 .09 .09 .09 .09 .09 1.10 .31 3.23 1.32 .09 .09 .09 .09 1.97 3.14

.09

.09

.09

.98

3.00

.09

.09

1.87 2.19

.09

.09

.09

.82

2.33

.09

.09

1.56 2.18

.09

.09

.09

.67

2.22

.09

.09

1.36 1.833*

2.550* .101* .094* .094* .094* .094* .094* .545* .305* 1.736* 1.320* .094* .094* .094* .094* 1.076*24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43263 43263 43279 43279 43282 43282 43283 43283 43284 43284 43285 43285 43289 43289 43290 43290 43291 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: 2-Methylhexane 2-Methylhexane 1-Nonene 1-Nonene 3-Methyl-1-butene 3-Methyl-1-butene Cyclopentene Cyclopentene 2,3-Dimethylbutane 2,3-Dimethylbutane 2-Methylpentane 2-Methylpentane trans-2-Hexene trans-2-Hexene cis-2-Hexene cis-2-Hexene 2,3-Dimethylpentane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 17 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 8 9 8 9 8 9 6 7 6 7 6 7 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 1

15 1 15 1 15 1 15 1 15 1 61 7 61 7 61 7 .75

.62 .44 .09 .09 .09 .09 .09 .09 .28 .09 .37 .20 .04 .04 .04 .04 .55

.09

.09

.09

.09

.20 .00 .04 .04 .04 .04 .54

.09

.09

.09

.09

.18 .00 .04 .04 .04 .04 .47

.09

.09

.09

.09

.15 .00 .04 .04 .04 .04 .746*

.324* .440* .094* .094* .094* .094* .094* .094* .106* .094* .020 .029* .039 .039* .042 .042*24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43291 43292 43292 43298 43298 43299 43299 43328 43328 43330 43330 43372 43372 43373 43373 43396 43396 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: 2,3-Dimethylpentane 2-2-3-Trimethylpentane 2-2-3-Trimethylpentane 1-Decene 1-Decene 1-Undecene 1-Undecene 1-Heptene 1-Heptene Dodecene Dodecene Methyl tert-butyl ether Methyl tert-butyl ether Tert-amyl methyl ether Tert-amyl methyl ether tert-Butyl ethyl ether tert-Butyl ethyl ether Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 101 101 101 101 101 101 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 18 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

6 7 6 7 30 31 32 30 31 32 30 31 32 6 7 30 31 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 61

7 61 7 60 6 43 60 6 43 60 6 43 56 6 60 6 .29

.00 .23 .20 4.4 4.7 5.7 5.8 6.1 5.9 1.0 1.1 1.2 3.24 2.25 1.224 1.152 .12

.00 .15 .08 4.3 3.6 4.9 5.5 3.3 5.7 1.0 .8 1.2 2.79 2.03 1.080 .732 .08

.00 .12 .00 4.3 3.4 4.4 5.4 3.2 4.5 .9 .7 1.0 2.73 1.53 1.068 .700 .00

.00 .10 .00 4.1 3.4 4.4 5.2 3.0 4.3 .9 .6 .9 2.71 1.52 1.052 .516 .008

.000* .017 .040* 3.16 3.47* 3.44* 3.08 3.00* 2.61* .60 .62* .56* 1.511 1.513* .6342 .6160*24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43438 43438 43441 43441 43502 43502 43502 43503 43503 43503 43504 43504 43504 43505 43505 43510 43510 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Ethyl acrylate Ethyl acrylate Methyl methacrylate Methyl methacrylate Formaldehyde Formaldehyde Formaldehyde Acetaldehyde Acetaldehyde Acetaldehyde Propionaldehyde Propionaldehyde Propionaldehyde Acrolein - Unverified Acrolein - Unverified Butyraldehyde Butyraldehyde Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 101 101 101 202 202 202 202 202 202 202 202 202 101 101 202 202 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 19 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

32 30 31 32 30 31 32 30 31 32 30 31 32 30 31 32 30 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 43

60 6 43 60 6 43 60 6 43 60 6 43 60 6 43 60 1.152

.0 .0 .0 .7 .7 .9 .5 .5 .5 .8 .6 1.6 22.0 18.2 19.2 2.2 1.148

.0 .0 .0 .7 .4 .8 .4 .3 .5 .7 .6 1.2 18.3 11.5 17.8 2.0 1.092

.0 .0 .0 .6 .4 .8 .4 .3 .5 .7 .5 1.2 18.2 10.9 17.6 1.9 1.020

.0 .0 .0 .6 .3 .7 .4 .2 .5 .6 .4 1.1 17.9 9.5 15.9 1.9 .5392*

.01 .01* .03* .36 .39* .30* .25 .27* .18* .40 .41* .76* 9.58 9.52* 10.00* 1.123 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43510 43513 43513 43513 43517 43517 43517 43518 43518 43518 43528 43528 43528 43551 43551 43551 43552 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Butyraldehyde Isovaleraldehyde Isovaleraldehyde Isovaleraldehyde Hexanaldehyde Hexanaldehyde Hexanaldehyde Valeraldehyde Valeraldehyde Valeraldehyde Crotonaldehyde Crotonaldehyde Crotonaldehyde Acetone Acetone Acetone Methyl ethyl ketone Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

202 202 202 202 202 202 202 202 202 202 202 202 202 202 202 202 202 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 20 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

31 32 6 7 6 7 6 7 6 7 6 7 6 7 6 7 6 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 6

43 61 7 61 7 61 7 61 7 61 7 61 7 61 7 61 2.0

3.0 .56 .44 .64 1.10 .81 .65 .83 .77 1.50 .49 .16 .11 .13 .10 .01 1.2

3.0 .47 .37 .63 .87 .72 .00 .77 .66 1.38 .46 .14 .10 .12 .10 .01 1.1

2.3 .46 .31 .61 .73 .55 .00 .76 .64 1.35 .42 .13 .10 .12 .10 .01 .9

2.2 .46 .27 .58 .66 .44 .00 .76 .61 1.20 .40 .13 .10 .12 .10 .01 1.01*

1.33* .296 .297* .410 .681* .041 .093* .614 .633* .431 .356* .071 .086* .099 .096* .00124 HOUR 3 HOURS 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43552 43552 43560 43560 43702 43702 43704 43704 43801 43801 43802 43802 43803 43803 43804 43804 43806 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Methyl ethyl ketone Methyl ethyl ketone Methyl isobutyl ketone Methyl isobutyl ketone Acetonitrile Acetonitrile Acrylonitrile Acrylonitrile Chloromethane Chloromethane Dichloromethane Dichloromethane Chloroform Chloroform Carbon tetrachloride Carbon tetrachloride Bromoform Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

202 202 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 21 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

7 6 7 6 7 6 7 6 7 6 7 6 7 6 7 6 7 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 7

61 7 61 7 61 7 61 7 61 7 61 7 61 7 61 7 .01

.38 .34 .21 .12 .00 .00 .03 .02 .08 .06 .29 .31 .01 .01 .03 .02 .01

.36 .31 .19 .03 .00 .00 .03 .02 .07 .06 .27 .12 .01 .00 .02 .01 .00

.36 .30 .14 .00 .00 .00 .03 .02 .07 .06 .20 .09 .01 .00 .02 .01 .00

.34 .30 .12 .00 .00 .00 .02 .01 .07 .05 .17 .06 .01 .00 .02 .01 .003*

.276 .284* .016 .021* .000 .000* .011 .013* .032 .039* .078 .097* .001 .001* .007 .010*24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43806 43811 43811 43812 43812 43813 43813 43814 43814 43815 43815 43817 43817 43818 43818 43819 43819 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Bromoform Trichlorofluoromethane Trichlorofluoromethane Chloroethane Chloroethane 1,1-Dichloroethane 1,1-Dichloroethane Methyl chloroform Methyl chloroform Ethylene dichloride Ethylene dichloride Tetrachloroethylene Tetrachloroethylene 1,1,2,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Bromomethane Bromomethane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 22 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

6 7 6 7 6 7 6 7 6 7 6 7 6 7 6 7 6 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 61

7 61 7 61 7 61 7 61 7 61 7 61 7 61 7 61 .00

.00 .20 .19 .66 .57 .03 .03 0 0 .04 .01 .00 .00 .18 .00 .21 .00

.00 .19 .18 .66 .56 .03 .02 0 0 .03 .01 .00 .00 .09 .00 .09 .00

.00 .19 .18 .65 .55 .03 .00 0 0 .03 .01 .00 .00 .00 .00 .08 .00

.00 .19 .18 .65 .54 .03 .00 0 0 .03 .01 .00 .00 .00 .00 .06 .000

.000* .163 .170* .521 .523* .003 .007* .0 .0* .011 .010* .000 .000* .004 .000* .00724 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43820 43820 43821 43821 43823 43823 43824 43824 43826 43826 43828 43828 43829 43829 43830 43830 43831 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: 1,1,2-Trichloroethane 1,1,2-Trichloroethane 1,1,2-Trichloro-1,2,2- trifluoroethane 1,1,2-Trichloro-1,2,2- trifluoroethane Dichlorodifluoromethane Dichlorodifluoromethane Trichloroethylene Trichloroethylene 1,1-Dichloroethylene 1,1-Dichloroethylene Bromodichloromethane Bromodichloromethane 1,2-Dichloropropane 1,2-Dichloropropane trans-1,3-Dichloropropene trans-1,3-Dichloropropene cis-1,3-Dichloropropene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 23 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

7 6 7 6 7 6 7 6 7 6 7 6 7 6 7 6 7 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 7

61 7 61 7 61 7 61 7 61 7 61 7 61 7 61 7 .00

.02 .01 .00 .00 .01 .01 .07 .03 .02 .02 .00 .00 .04 .03 .00 .00 .00

.01 .01 .00 .00 .01 .01 .03 .01 .02 .02 .00 .00 .04 .02 .00 .00 .00

.01 .01 .00 .00 .01 .01 .01 .01 .02 .02 .00 .00 .04 .00 .00 .00 .00

.01 .01 .00 .00 .01 .01 .01 .01 .02 .02 .00 .00 .02 .00 .00 .00 .000*

.009 .009* .000 .000* .008 .008* .013 .014* .016 .016* .000 .000* .003 .007* .000 .000*24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43831 43832 43832 43835 43835 43836 43836 43838 43838 43839 43839 43843 43843 43844 43844 43860 43860 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: cis-1,3-Dichloropropene Dibromochloromethane Dibromochloromethane Chloroprene Chloroprene Bromochloromethane Bromochloromethane trans-1,2-Dichloroethylene trans-1,2-Dichloroethylene cis-1,2-Dichloroethene cis-1,2-Dichloroethene Ethylene dibromide Ethylene dibromide Hexachlorobutadiene Hexachlorobutadiene Vinyl chloride Vinyl chloride Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 24 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 1

6 7 8 9 6 7 8 6 7 8 9 6 0053 0053 0053 0053 0053

0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013

2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 15

1 15 1 8358

61 7 15 1 61 7 15 61 7 15 1 61 .29

.25 .56 .11 .084

9.76 9.76 4.20 1.56 5.21 5.30 1.87 35.35 19.18 9.34 4.12 3.57 .28

.53

.081

9.76 5.09 3.78

5.14 2.57 1.57 22.54 9.66 8.40

3.38 .26

.40

.080

7.82 3.85 2.96

4.77 1.84 1.28 14.84 7.63 6.34

2.74 .23

.38

.079

6.77 2.53 2.85

4.54 1.45 1.15 14.84 5.55 6.28

2.49 .160*

.250* .272* .109* .0481

3.221 3.706* 2.137* 1.560* 1.980 2.029* .995* 7.415 7.420* 4.957* 4.120* 1.22624 HOUR 24 HOUR 24 HOUR 24 HOUR 8-HR RUN AVG BEGIN HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 43954 43954 43960 43960 44201

45109 45109 45109 45109 45201 45201 45201 45202 45202 45202 45202 45203 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: n-Undecane n-Undecane 2-Methylheptane 2-Methylheptane Ozone m/p Xylene m/p Xylene m/p Xylene m/p Xylene Benzene Benzene Benzene Toluene Toluene Toluene Toluene Ethylbenzene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per million Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 087

101 101 126 126 101 101 126 101 101 126 126 101 Cert& Eval

SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 25 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

7 8 9 6 7 8 9 6 7 8 9 6 7 8 9 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 7

15 1 61 7 15 1 61 7 15 1 61 7 15 1 15 1 3.38

1.39 .42 3.94 3.90 1.61 .65 1.15 1.20 .55 .10 3.74 3.72 1.69 .74 .44 .07 1.79

1.28

3.91 2.04 1.47

1.04 .56 .47

3.55 1.70 1.44

.30 1.51

1.05

3.02 1.54 1.25

.93 .54 .28

2.82 1.51 1.11

.26 .96

1.04

2.66 .94 1.11

.74 .27 .27

2.35 .90 1.10

.24 1.359*

.720* .420* 1.285 1.470* .880* .650* .364 .442* .217* .100* 1.191 1.355* .934* .740* .181* .069*24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 45203 45203 45203 45204 45204 45204 45204 45207 45207 45207 45207 45208 45208 45208 45208 45209 45209 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Ethylbenzene Ethylbenzene Ethylbenzene o-Xylene o-Xylene o-Xylene o-Xylene 1,3,5-Trimethylbenzene 1,3,5-Trimethylbenzene 1,3,5-Trimethylbenzene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,2,4-Trimethylbenzene 1,2,4-Trimethylbenzene 1,2,4-Trimethylbenzene n-Propylbenzene n-Propylbenzene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

101 126 126 101 101 126 126 101 101 126 126 101 101 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 26 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 8 9 8 9 6 7 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 15

1 15 1 15 1 15 1 15 1 61 7 12 1 15 1 15 .00

.00 .45 .07 1.00 .44 .12 .12 .10 .10 1.34 .98 .00 .00 .47 .19 .49 .00

.44

.95

.12

.10

.92 .33 .00

.36

.48 .00

.34

.86

.12

.10

.85 .29 .00

.28

.45 .00

.33

.66

.12

.10

.77 .14 .00

.27

.38 .000*

.000* .169* .073* .493* .440* .120* .120* .103* .103* .277 .303* .000* .000* .205* .186* .258*24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 45210 45210 45211 45211 45212 45212 45218 45218 45219 45219 45220 45220 45220 45220 45225 45225 45228 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Isopropylbenzene Isopropylbenzene o-Ethyltoluene o-Ethyltoluene m-Ethyltoluene m-Ethyltoluene m-Diethylbenzene m-Diethylbenzene p-Diethylbenzene p-Diethylbenzene Styrene Styrene Styrene Styrene 1,2,3-Trimethylbenzene 1,2,3-Trimethylbenzene Benzene, 1-ethenyl-4-methyl Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 101 101 126 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 27 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 30 31 32 30 31 32 30 31 32 6 7 6 7 6 7 6 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 1

60 6 43 60 6 43 56 6 34 61 7 61 7 61 7 61 .10

.8 .9 1.0 .0 .0 .0 .7 .6 1.0 .07 .00 .07 .07 .08 .08 .49 .8

.5 .8 .0 .0 .0 .7 .4 1.0 .00 .00 .07 .07 .08 .08 .47 .8

.4 .8 .0 .0 .0 .6 .4 .9 .00 .00 .07 .07 .08 .08 .46 .8

.4 .8 .0 .0 .0 .5 .3 .9 .00 .00 .07 .07 .08 .08 .41 .101*

.42 .44* .45* .01 .01* .05* .33* .36* .66* .001 .000* .069 .069* .078 .078* .20324 HOUR 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 3 HOURS 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 45228 45501 45501 45501 45503 45503 45503 45504 45504 45504 45801 45801 45805 45805 45806 45806 45807 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Benzene, 1-ethenyl-4-methyl Benzaldehyde Benzaldehyde Benzaldehyde 2,5-Dimethylbenzaldehyde 2,5-Dimethylbenzaldehyde 2,5-Dimethylbenzaldehyde Tolualdehydes Tolualdehydes Tolualdehydes Chlorobenzene Chlorobenzene 1,2-Dichlorobenzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 202 202 202 202 202 202 202 202 202 101 101 101 101 101 101 101 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 28 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

7 6 7 1 1 1 1 7 7 1 7 7 7 1 7 3 3 1 1 1 1 1 1 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 7

61 7 8753 8753 8753 8753 120 120 121 120 120 120 121 120 8702 365 61 61 61 61 61 61 .44

.00 .00 13.6 360.0 119 96 31.0 46.0 38.9 38.7 740 750 740 743 4985 262 8.170 1.650 .2400 1.1500 7.7 1.9100 .38

.00 .00 12.6 360.0 118 96 30.6 45.2 37.1 37.1 740 746 738 741 1301 165 7.950 1.300 .1100 .2800 7.1 1.0400 .19

.00 .00 12.6 360.0 118 96 30.4 45.2 36.8 36.8 739 746 738 740 799 117 7.800 1.120 .0700 .2600 7.1 .9600 .16

.00 .00 11.5 360.0 118 96 30.4 44.2 36.8 36.7 738 745 738 740 740 111 6.410 1.080 .0600 .2600 6.3 .8900 .221*

.000 .000* 2.59 175.11 74.2 35.3 15.20 31.48 23.23 23.18 728.2 735.4 730.0 731.2 30.7 30.2 2.8111 .4856 .03244 .11851 2.58 .3895124 HOUR

24 HOUR 24 HOUR 1 HOUR 1 HOUR 1 HOUR 1 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 1 HOUR 24-HR BLK AVG 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 5 0 0 0 0 0 0 45807 45810 45810 61103 61104 62101 62201 68103 68104 68105 68105 68106 68107 68108 68108 81102 81102 85102 85103 85105 85110 85112 85113 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: 1,4-Dichlorobenzene 1,2,4-Trichlorobenzene 1,2,4-Trichlorobenzene Wind Speed - Resultant Wind Direction - Resultant Outdoor Temperature Relative Humidity Ambient Min Temperature Ambient Max Temperature Ambient Temperature Ambient Temperature Sample Min Baro Pressure Sample Max Baro Pressure Sample Baro Pressure Sample Baro Pressure PM10 Total 0-10um STP PM10 Total 0-10um STP Antimony PM10 LC Arsenic PM10 LC Beryllium PM10 LC Cadmium PM10 LC Chromium PM10 LC Cobalt PM10 LC Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Knots Degrees Compass Degrees Fahrenheit Percent relative humidity Degrees Centigrade Degrees Centigrade Degrees Centigrade Degrees Centigrade Millimeters (mercury) Millimeters (mercury) Millimeters (mercury) Millimeters (mercury) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Meth

101 101 101 020 020 021 012 810 810 143 810 810 810 143 810 122 122 202 202 202 202 202 202 Cert& Eval

S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 29 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

1 1 1 1 1 3 1 3 3 7 7 7 7 7 7 7 7 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 61

61 61 61 61 8615 121 332 8001 119 119 119 119 119 119 119 119 .0109 113.000 4.540 .0400 1.010 4530.0 40.5 44.9 454.0 .056 .004 1.240 .284 .032 .027 .954 .077 .0080

40.900 4.380 .0400 .730 1111.0 29.2 29.5 167.0 .056 .003 .634 .030 .008 .019 .431 .073 .0074

33.500 4.220 .0400 .500 708.0 23.5 29.0 166.0 .040 .002 .424 .030 .008 .016 .310 .073 .0070

32.800 2.930 .0400 .490 653.0 18.6 27.8 145.0 .037 .002 .274 .030 .008 .015 .227 .061 .00332 17.9933 1.4952 .01651 .2092 21.74 8.41 7.15* 7.18 .0201 .0004 .0934 .0099 .0036 .0016 .0902 .006724 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 1 HOUR 24 HOUR 24-HR BLK AVG 1 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 85129 85132 85136 85142 85154 86101 88101 88101 88101 88102 88103 88104 88107 88109 88110 88111 88112 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Lead PM10 LC FRM/FEM Manganese PM10 LC Nickel PM10 LC Mercury PM10 LC Selenium PM10 LC PM10-2.5 - Local Conditions PM2.5 - Local Conditions PM2.5 - Local Conditions PM2.5 - Local Conditions Antimony PM2.5 LC Arsenic PM2.5 LC Aluminum PM2.5 LC Barium PM2.5 LC Bromine PM2.5 LC Cadmium PM2.5 LC Calcium PM2.5 LC Chromium PM2.5 LC Micrograms/cubic meter (LC) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Nanograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Meth

202 202 202 202 202 185 143 170 170 811 811 811 811 811 811 811 811 Cert& Eval

S

S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 30 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 119

119 119 119 119 119 119 119 119 119 119 119 119 119 119 119 119 .003

.121 1.290 .044 .023 .876 .009 .021 .028 .004 .441 .008 .002 .035 .079 .013 3.520 .002

.016 .338 .043 .023 .486 .005 .017 .015 .003 .228 .008 .001 .029 .035 .005 1.810 .002

.015 .328 .043 .023 .341 .005 .017 .009 .003 .108 .008 .001 .029 .035 .002 1.270 .002

.015 .311 .043 .023 .279 .005 .017 .008 .003 .077 .008 .001 .020 .019 .002 .783 .0008

.0056 .0632 .0067 .0093 .1292 .0011 .0097 .0028 .0004 .0225 .0058 .0010 .0130 .0074 .0017 .280324 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 88113 88114 88115 88117 88118 88126 88128 88131 88132 88136 88140 88152 88154 88160 88161 88164 88165 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Cobalt PM2.5 LC Copper PM2.5 LC Chlorine PM2.5 LC Cerium PM2.5 LC Cesium PM2.5 LC Iron PM2.5 LC Lead PM2.5 LC Indium PM2.5 LC Manganese PM2.5 LC Nickel PM2.5 LC Magnesium PM2.5 LC Phosphorus PM2.5 LC Selenium PM2.5 LC Tin PM2.5 LC Titanium PM2.5 LC Vanadium PM2.5 LC Silicon PM2.5 LC Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Meth

811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 31 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 119

119 119 119 119 119 119 119 120 120 120 120 120 120 120 120 120 .019

.043 .068 1.410 .001 4.320 .477 .019 1.42 .57 4.27 5.31 10.900 2.340 10.300 1.960 2.330 .019

.027 .015 .954 .001 .674 .387 .012 1.21 .40 .32 4.33 8.730 2.170 9.010 1.700 2.240 .019

.022 .013 .867 .001 .329 .327 .012 1.07 .39 .27 4.14 7.640 2.140 7.160 1.530 1.930 .019

.020 .006 .792 .001 .326 .327 .012 1.03 .30 .23 3.23 6.960 2.110 6.960 1.290 1.770 .0077

.0080 .0021 .3242 .0010 .1355 .0861 .0032 .393 .117 .087 .751 2.3905 .5957 2.2612 .2483 .579024 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 88166 88167 88168 88169 88176 88180 88184 88185 88301 88302 88303 88306 88355 88357 88370 88374 88375 Parameter Site ID:04-013-9997 Phoenix City: Maricopa Unit County: 4530 N 17TH AVENUE Address: Silver PM2.5 LC Zinc PM2.5 LC Strontium PM2.5 LC Sulfur PM2.5 LC Rubidium PM2.5 LC Potassium PM2.5 LC Sodium PM2.5 LC Zirconium PM2.5 LC Ammonium Ion PM2.5 LC Sodium Ion Pm2.5 LC Potassium Ion PM2.5 LC Total Nitrate PM2.5 LC OC CSN_Rev Unadjusted PM2.5 LC TOT EC CSN_Rev Unadjusted PM2.5 LC TOT OC CSN_Rev Unadjusted PM2.5 LC TOR OC1 CSN_Rev Unadjusted PM2.5 LC OC2 CSN_Rev Unadjusted PM2.5 LC Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Meth

811 811 811 811 811 811 811 811 812 812 812 812 839 840 838 841 841 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 32 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

7 7 7 7 7 7 7 7 7 7

1 1

3 3

3 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053

0053 0053

0053 0053

0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013

2013 2013

2013 2013

2013 120

120 120 120 120 120 120 120 120 119

8740 8740

8568 356

8679 2.720

1.380 2.730 3.240 5.110 .211 .010 3.290 3.40 40.4

1.56 .06

568 208

1375 2.550

1.340 1.850 2.810 3.630 .144 .010 1.570 2.57 27.2

1.51 .06

559 86

1196 2.450

1.280 1.100 2.550 3.210 .137 .009 .901 2.56 22.6

1.51 .06

429 84

1024 2.380

1.270 .753 2.480 2.940 .137 .009 .895 2.34 19.5

1.51 .06

369 81

766 .7565

.4315 .2469 .7246 .9066 .0640 .0016 .3757 .928 8.67

.346 .016

21.2 20.8

29.024 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR

1 HOUR 1 HOUR

1 HOUR 24-HR BLK AVG

1 HOUR 0

0 0 0 0 0 0 0 0 0

0 0

0 0

5 88376 88377 88378 88380 88383 88384 88385 88388 88403 88502

63301 63302

81102 81102

81102 Parameter Site ID:

Site ID:

Site ID:

Site ID:04-013-9997

04-013-9998

04-015-1003

04-019-0001 Phoenix

Phoenix

Bullhead City

Ajo City:

City:

City:

City: Maricopa

Maricopa

Mohave

Pima Unit County:

County:

County:

County: 4530 N 17TH AVENUE

600 N 40TH ST & FILLMORE ST,PHOENIX

BULLHEAD CITY 990 HWY 95

AZ HWY DEPT YARD-WELL RD, AJO Address:

Address:

Address:

Address: OC3 CSN_Rev Unadjusted PM2.5 LC OC4 CSN_Rev Unadjusted PM2.5 LC OP CSN_Rev Unadjusted PM2.5 LC TOR EC CSN_Rev Unadjusted PM2.5 LC TOR EC1 CSN_Rev Unadjusted PM2.5 LC EC2 CSN_Rev Unadjusted PM2.5 LC EC3 CSN_Rev Unadjusted PM2.5 LC OP CSN_Rev Unadjusted PM2.5 LC TOT Sulfate PM2.5 LC Acceptable PM2.5 AQI & Speciation Mass

Solar radiation Ultraviolet radiation

PM10 Total 0-10um STP PM10 Total 0-10um STP

PM10 Total 0-10um STP Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Langleys/minute Langleys/minute Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Meth

841 841 842 831 841 841 841 826 812 810

011 011

079 079

079 Cert& Eval

S S

SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 33 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

3

3 3

1 8 9 8 9 8 9 8 9 8 9 8 9 0053

0053 0053

0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013

2013 2013

2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 363

8695 363

2193 15 42 15 42 15 42 15 42 15 42 15 42 299

5627 421

23.3 230.00 209.00 .39 .39 .09 .09 .09 .30 .09 .09 .40 .09 141

1738 363

21.5 228.00 175.00 .17 .17 .09 .09 .09 .09 .09 .09 .09 .09 100

1555 254

17.2 183.00 168.00 .17 .17 .09 .09 .09 .09 .09 .09 .09 .09 99

1539 201

15.8 168.00 165.00 .17 .17 .09 .09 .09 .09 .09 .09 .09 .09 28.7

40.8 40.4

4.35* 137.660* 101.167* .182* .172* .094* .094* .094* .099* .094* .094* .115* .094*24-HR BLK AVG

1 HOUR 24-HR BLK AVG

1 HOUR 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 5

5 5

0 0 0 0 0 0 0 0 0 0 0 0 0 81102

81102 81102

42600 43102 43102 43141 43141 43142 43142 43143 43143 43144 43144 43145 43145 Parameter Site ID:

Site ID:

Site ID:04-019-0001

04-019-0020

04-021-8001 Ajo

Rillito

Queen Valley City:

City:

City: Pima

Pima

Pinal Unit County:

County:

County: AZ HWY DEPT YARD-WELL RD, AJO

8840 W ROBINSON STREET, RILLITO

10 S QUEEN ANN QUEEN VALLEY Address:

Address:

Address: PM10 Total 0-10um STP

PM10 Total 0-10um STP PM10 Total 0-10um STP

Reactive oxides of nitrogen (NOy) Total NMOC (non-methane organic compound) Total NMOC (non-methane organic compound) n-Dodecane n-Dodecane Tridecene Tridecene n-Tridecane n-Tridecane Propyne Propyne 1-Octene 1-Octene Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Parts per billion Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

079

079 079

574 126 126 126 126 126 126 126 126 126 126 126 126 Cert& Eval

S

S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 34 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 15

42 15 42 15 42 15 42 15 42 15 42 15 42 15 42 15 4.85

5.41 2.06 2.18 1.70 2.04 .79 1.20 .34 .25 .92 6.94 .94 1.59 .25 .31 .05 4.51

5.10 2.04 2.08 1.38 1.79 .65 .76 .27 .25 .64 .67 .22 .59 .23 .29 .05 4.38

4.95 1.80 2.04 1.27 1.55 .47 .75 .24 .25 .44 .67 .21 .29 .15 .26 .05 3.64

4.84 1.73 2.01 1.19 1.47 .42 .62 .11 .25 .37 .61 .21 .28 .05 .25 .05 3.246*

3.142* 1.515* 1.501* .996* .916* .316* .342* .145* .126* .327* .405* .192* .169* .082* .120* .049*24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43202 43202 43203 43203 43204 43204 43205 43205 43206 43206 43212 43212 43214 43214 43216 43216 43217 Parameter Site ID:04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: Ethane Ethane Ethylene Ethylene Propane Propane Propylene Propylene Acetylene Acetylene n-Butane n-Butane Isobutane Isobutane trans-2-Butene trans-2-Butene cis-2-Butene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 35 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 42

15 42 15 42 5 15 15 42 15 42 15 42 15 42 15 42 .11

.00 .00 22.30 57.80 .38 27.90 .33 .25 .09 .09 .08 .18 .11 .11 .23 .33 .05

.00 .00 1.19 7.69 .34 3.91 .27 .19 .09 .09 .08 .08 .11 .11 .09 .09 .05

.00 .00 .72 .84 .29 .99 .09 .09 .09 .09 .08 .08 .11 .11 .09 .09 .05

.00 .00 .53 .62 .27 .30 .09 .09 .09 .09 .08 .08 .11 .11 .09 .09 .050*

.000* .000* 1.803* 1.782* .299* 2.295* .119* .098* .094* .094* .082* .084* .105* .105* .103* .100*3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43217 43218 43218 43220 43220 43221 43221 43224 43224 43225 43225 43226 43226 43227 43227 43228 43228 Parameter Site ID:04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: cis-2-Butene 1,3-Butadiene 1,3-Butadiene n-Pentane n-Pentane Isopentane Isopentane 1-Pentene 1-Pentene 2-Methyl-1-butene 2-Methyl-1-butene trans-2-Pentene trans-2-Pentene cis-2-Pentene cis-2-Pentene 2-Methyl-2-butene 2-Methyl-2-butene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 36 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 15

42 15 42 15 42 15 42 15 42 15 42 15 42 15 42 15 1.09

1.04 .55 .47 .43 .35 .33 .13 .09 .09 .25 .12 .09 .09 .10 .10 1.74 .30

.60 .33 .46 .35 .34 .13 .13 .09 .09 .05 .05 .09 .09 .10 .10 .10 .22

.36 .19 .33 .18 .32 .13 .13 .09 .09 .05 .05 .09 .09 .10 .10 .03 .17

.34 .14 .31 .09 .26 .13 .13 .09 .09 .05 .05 .09 .09 .10 .10 .03 .193*

.159* .156* .106* .132* .114* .147* .135* .094* .094* .066* .055* .094* .094* .096* .096* .152*24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43230 43230 43231 43231 43232 43232 43233 43233 43234 43234 43235 43235 43236 43236 43238 43238 43242 Parameter Site ID:04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: 3-Methylpentane 3-Methylpentane n-Hexane n-Hexane n-Heptane n-Heptane n-Octane n-Octane 4-Methyl-1-pentene 4-Methyl-1-pentene n-Nonane n-Nonane 2-Ethyl-1-butene 2-Ethyl-1-butene n-Decane n-Decane Cyclopentane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 37 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 41

15 42 15 42 15 42 15 42 15 42 15 42 15 42 15 42 .75

.45 .62 .29 .31 .22 .22 .09 .09 .16 .16 1.19 .68 .23 1.67 .75 .81 .24

.33 .61 .05 .17 .22 .22 .09 .09 .16 .16 .10 .42 .23 .47 .41 .52 .07

.33 .60 .05 .11 .22 .22 .09 .09 .16 .16 .10 .24 .23 .23 .40 .47 .03

.33 .59 .05 .05 .22 .22 .09 .09 .16 .16 .10 .10 .23 .23 .21 .40 .056*

.247* .321* .068* .062* .223* .223* .094* .094* .159* .159* .171* .123* .226* .266* .193* .173*3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43242 43243 43243 43244 43244 43245 43245 43246 43246 43247 43247 43248 43248 43249 43249 43250 43250 Parameter Site ID:04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: Cyclopentane Isoprene Isoprene 2,2-Dimethylbutane 2,2-Dimethylbutane 1-Hexene 1-Hexene 2-Methyl-1-pentene 2-Methyl-1-pentene 2,4-Dimethylpentane 2,4-Dimethylpentane Cyclohexane Cyclohexane 3-Methylhexane 3-Methylhexane 2,2,4-Trimethylpentane 2,2,4-Trimethylpentane Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 38 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 15

42 15 42 15 42 15 42 15 42 15 42 15 42 15 42 15 .34

.42 .09 .09 .61 .78 .09 .09 .71 .12 .31 .34 1.22 1.88 .42 .09 .09 .29

.41 .09 .09 .43 .54 .09 .09 .12 .12 .17 .24 1.20 1.45 .09 .09 .09 .29

.27 .09 .09 .28 .34 .09 .09 .12 .12 .07 .19 1.20 1.44 .09 .09 .09 .22

.24 .09 .09 .09 .27 .09 .09 .12 .12 .07 .18 .81 1.35 .09 .09 .09 .136*

.136* .087* .087* .163* .137* .094* .094* .163* .124* .096* .091* .552* .622* .116* .094* .094*24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43252 43252 43253 43253 43256 43256 43257 43257 43261 43261 43262 43262 43263 43263 43279 43279 43282 Parameter Site ID:04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: 2,3,4-Trimethylpentane 2,3,4-Trimethylpentane 3-Methylheptane 3-Methylheptane alpha.-Pinene alpha.-Pinene beta.-Pinene beta.-Pinene Methylcyclohexane Methylcyclohexane Methylcyclopentane Methylcyclopentane 2-Methylhexane 2-Methylhexane 1-Nonene 1-Nonene 3-Methyl-1-butene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 39 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 42

15 42 15 42 15 42 15 42 15 42 15 42 15 42 15 42 .09

.09 2.06 .53 .51 3.17 2.43 .09 .09 .09 .09 .42 .18 .09 .20 .09 .09 .09

.09 .09 .16 .28 1.14 2.13 .09 .09 .09 .09 .18 .18 .09 .09 .09 .09 .09

.09 .09 .06 .21 .95 1.50 .09 .09 .09 .09 .18 .18 .09 .09 .09 .09 .09

.09 .09 .06 .20 .75 1.43 .09 .09 .09 .09 .18 .18 .09 .09 .09 .09 .094*

.094* .141* .101* .094* .767* .739* .094* .094* .094* .094* .195* .179* .094* .096* .094* .094*3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 43282 43283 43283 43284 43284 43285 43285 43289 43289 43290 43290 43291 43291 43292 43292 43298 43298 Parameter Site ID:04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: 3-Methyl-1-butene Cyclopentene Cyclopentene 2,3-Dimethylbutane 2,3-Dimethylbutane 2-Methylpentane 2-Methylpentane trans-2-Hexene trans-2-Hexene cis-2-Hexene cis-2-Hexene 2,3-Dimethylpentane 2,3-Dimethylpentane 2-2-3-Trimethylpentane 2-2-3-Trimethylpentane 1-Decene 1-Decene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 40 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 8 9 8 9 1

8 9 8 9 8 9 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053

0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013

2013 2013 2013 2013 2013 2013 15

42 15 42 15 42 15 42 15 42 5819

15 42 2 4 15 42 .56

.09 .35 .09 .09 .09 .11 .11 .11 .11 .079

.83 .66 .00 .00 2.08 6.82 .09

.09 .09 .09 .09 .09 .11 .11 .11 .11 .077

.31 .49 .00 .00 .86 2.56 .09

.09 .09 .09 .09 .09 .11 .11 .11 .11 .075

.23 .31

.00 .79 1.03 .09

.09 .09 .09 .09 .09 .11 .11 .11 .11 .073

.22 .30

.00 .73 1.03 .125*

.094* .111* .094* .094* .094* .111* .111* .109* .109* .0566

.156* .104* .000* .000* .602* .623*24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 8-HR RUN AVG BEGIN HOUR 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 0

0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 43299 43299 43328 43328 43330 43330 43954 43954 43960 43960 44201

45109 45109 45201 45201 45202 45202 Parameter Site ID:04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: 1-Undecene 1-Undecene 1-Heptene 1-Heptene Dodecene Dodecene n-Undecane n-Undecane 2-Methylheptane 2-Methylheptane Ozone m/p Xylene m/p Xylene Benzene Benzene Toluene Toluene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per million Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 087

126 126 126 126 126 126 Cert& Eval

SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 41 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 9 8 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 15

42 15 42 15 42 15 42 15 42 15 42 15 42 15 42 15 .23

.20 .21 .30 .10 .10 1.72 .83 .15 .07 .00 .00 .07 .07 .06 .06 .12 .11

.20 .13 .28 .10 .10 .60 .74 .07 .07 .00 .00 .07 .07 .06 .06 .12 .09

.09 .13 .23 .10 .10 .26 .62 .07 .07 .00 .00 .07 .07 .06 .06 .12 .00

.09 .09 .17 .10 .10 .10 .49 .07 .07 .00 .00 .07 .07 .06 .06 .12 .029*

.016* .037* .044* .100* .100* .251* .182* .075* .069* .000* .000* .073* .073* .056* .056* .120*24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 45203 45203 45204 45204 45207 45207 45208 45208 45209 45209 45210 45210 45211 45211 45212 45212 45218 Parameter Site ID:04-021-8001 Queen Valley City: Pinal Unit County: 10 S QUEEN ANN QUEEN VALLEY Address: Ethylbenzene Ethylbenzene o-Xylene o-Xylene 1,3,5-Trimethylbenzene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene 1,2,4-Trimethylbenzene n-Propylbenzene n-Propylbenzene Isopropylbenzene Isopropylbenzene o-Ethyltoluene o-Ethyltoluene m-Ethyltoluene m-Ethyltoluene m-Diethylbenzene Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Meth

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 Cert& EvalUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 42 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

9 8 9 8 9 8 9 8 9 1 1 1 2

1 2 1 2 1 3 3 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053 0053

0053 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013 2013

2013 2013 2013 2013 2013 2013 2013 42

15 42 15 41 15 42 15 42 8754 8754 8754 8754

58 56 58 56 58 6594 274 .12

.10 .10 .00 .00 .07 .18 .31 .10 24.7 360.0 115 100

31.3 30.9 667 667 89 985 272 .12

.10 .10 .00 .00 .07 .16 .10 .10 23.5 360.0 114 100

29.8 29.7 666 667 87 872 174 .12

.10 .10 .00 .00 .07 .07 .10 .10 23.5 360.0 114 100

29.1 29.4 666 667 86 853 137 .12

.10 .10 .00 .00 .07 .07 .10 .10 22.7 359.0 113 100

29.0 28.6 666 667 84 796 130 .120*

.103* .103* .000* .000* .074* .078* .114* .101* 6.52 152.66 72.1 30.8

18.09 17.81 662.8 663.1 35.7 46.5 45.8*3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 24 HOUR 3 HOURS 1 HOUR 1 HOUR 1 HOUR 1 HOUR

24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR 1 HOUR 24-HR BLK AVG 0

0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 5 5 45218 45219 45219 45220 45220 45225 45225 45228 45228 61103 61104 62101 62201

68105 68105 68108 68108 81102 81102 81102 Parameter Site ID:

Site ID:04-021-8001

04-023-0004 Queen Valley

Nogales City:

City: Pinal

Santa Cruz Unit County:

County: 10 S QUEEN ANN QUEEN VALLEY

300 N MORLEY AVE Address:

Address: m-Diethylbenzene p-Diethylbenzene p-Diethylbenzene Styrene Styrene 1,2,3-Trimethylbenzene 1,2,3-Trimethylbenzene Benzene, 1-ethenyl-4-methyl Benzene, 1-ethenyl-4-methyl Wind Speed - Resultant Wind Direction - Resultant Outdoor Temperature Relative Humidity

Ambient Temperature Ambient Temperature Sample Baro Pressure Sample Baro Pressure PM10 Total 0-10um STP PM10 Total 0-10um STP PM10 Total 0-10um STP Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Parts per billion Carbon Knots Degrees Compass Degrees Fahrenheit Percent relative humidity Degrees Centigrade Degrees Centigrade Millimeters (mercury) Millimeters (mercury) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Meth

126 126 126 126 126 126 126 126 126 020 020 021 012

143 143 143 143 126 122 122 Cert& Eval

S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 43 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

1 1 2 3 3 3 3

1 1 1 1 1

1

1

1 0053 0053 0053 0053 0053 0053 0053

0053 0053 0053 0053 0053

0053

0053

0053 2013 2013 2013 2013 2013 2013 2013

2013 2013 2013 2013 2013

2013

2013

2013 58

58 56 234 5632 65 1695

58 58 55 54 58

5876

5682

30 81

35.0 34.2 59.4 337.0 75.3 397.0

37.8 639 51 43 9.7

.071

.079

34.1 79

25.5 25.7 55.2 251.0 43.4 287.0

37.1 639 27 22 8.4

.069

.076

32.4 76

21.6 21.0 38.0 220.0 41.7 247.0

36.3 638 25 20 8.4

.066

.074

31.9 75

18.9 18.2 36.0 182.0 39.4 199.0

35.3 638 24 20 7.1

.065

.073

31.9 31.7

9.91 9.63 8.73* 8.76* 14.51* 15.76

16.58 632.9 11.9 10.1 4.14

.0490

.0509

22.88*24 HOUR 24 HOUR 24 HOUR 24-HR BLK AVG 1 HOUR 24-HR BLK AVG 1 HOUR

24 HOUR 24 HOUR 24 HOUR 24 HOUR 24 HOUR

8-HR RUN AVG BEGIN HOUR

8-HR RUN AVG BEGIN HOUR 24 HOUR 0

0 0 5 5 0 0

0 0 0 0 0

0

0

0 85101 88101 88101 88101 88101 88501 88501

68105 68108 81102 85101 88101

44201

44201

68105 Parameter Site ID:

Site ID:

Site ID:

Site ID:04-023-0004

04-025-2002

04-025-8033

04-027-8011 Nogales

Prescott Valley

Prescott

Yuma City:

City:

City:

City: Santa Cruz

Yavapai

Yavapai

Yuma Unit County:

County:

County:

County: 300 N MORLEY AVE

7501 E. CIVIC CIRCLE, PRESCOTT VALLEY

330 Grove Avenue

2323 S ARIZONA AVE Address:

Address:

Address:

Address: PM10 - LC PM2.5 - Local Conditions PM2.5 - Local Conditions PM2.5 - Local Conditions PM2.5 - Local Conditions PM2.5 Raw Data PM2.5 Raw Data

Ambient Temperature Sample Baro Pressure PM10 Total 0-10um STP PM10 - LC PM2.5 - Local Conditions

Ozone

Ozone Ambient Temperature Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Degrees Centigrade Millimeters (mercury) Micrograms/cubic meter (25 C) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Parts per million

Parts per million Degrees Centigrade Meth

126 143 143 170 170 731 731

143 143 126 126 143

047

087

143 Cert& Eval

S S S S

S

S

S

SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 44 of 55 P O C PQAO Year # Obs1st Max Value 2nd Max

Value 3rd Max

Value 4th Max

Value Arith.

Mean DurationEDT

1 3 3 1 3 3 0053 0053 0053 0053 0053 0053 2013 2013 2013 2013 2013 2013 30

8578 363 30 3946 164 764

3687 640 26.7 213.0 38.5 762

2768 228 24.4 111.0 17.0 760

2601 220 16.0 106.0 16.0 758

2445 187 14.3 102.0 15.7 752.9*

41.5 41.1 8.84* 6.10* 6.05*24 HOUR 1 HOUR 24-HR BLK AVG 24 HOUR 1 HOUR 24-HR BLK AVG 0

5 5 0 5 5 68108 81102 81102 88101 88101 88101 Parameter Site ID:04-027-8011 Yuma City: Yuma Unit County: 2323 S ARIZONA AVE Address: Sample Baro Pressure PM10 Total 0-10um STP PM10 Total 0-10um STP PM2.5 - Local Conditions PM2.5 - Local Conditions PM2.5 - Local Conditions Millimeters (mercury) Micrograms/cubic meter (25 C) Micrograms/cubic meter (25 C) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Micrograms/cubic meter (LC) Meth

143 079 079 143 170 170 Cert& Eval

S S S S SUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 45 of 55 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

12115 14129 17141 17147 17148 17149 17150 17151 17158 17159 17160 17201 17204 17208 17211 17212 17215 17220 17223 17224 17231 17237 17242 17243 42101 42153 42401 42401 42401 42406 42406 42406 42600 920

191 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 118 588 101 000 060 592 000 060 592 574 LO-VOL-XONTECH 920 or 924

Hi-Vol Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 Hi Vol/PUF-XAD-2 INSTRUMENTAL CANISTER SUBAMBIENT PRESSURE MULTIPLE METHODS INSTRUMENTAL Instrumental MULTIPLE METHODS INSTRUMENTAL Instrumental Instrumental ION CHROMATOGRAPH UV VISIBLE Inductively Coupled Plasma-Mass Spectrometry Acid filter extraction with nitric and hydrochloric acid GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 GCMS TO-13 Gas Filter Correlation Ecotech EC9830T MULTI DETECTOR GC MULTIPLE METHODS PULSED FLUORESCENT Ultraviolet Fluorescence EC9850T MULTIPLE METHODS PULSED FLUORESCENT Ultraviolet Fluorescence EC9850T Chemiluminescence Thermo Electron 42C-Y, 42i-YUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 46 of 55 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

42600 42601 42602 42603 43102 43141 43142 43143 43144 43145 43202 43203 43204 43205 43205 43206 43206 43208 43212 43214 43216 43217 43218 43218 43220 43221 43224 43225 43226 43227 43228 43230 43231 43232 591

000 000 000 126 126 126 126 126 126 126 126 126 101 126 101 126 101 126 126 126 126 101 126 126 126 126 126 126 126 126 126 126 126 Instrumental

MULTIPLE METHODS MULTIPLE METHODS MULTIPLE METHODS SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED Canister Subambient Pressure SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED Chemiluminescence Ecotech EC9843 MULTIPLE METHODS MULTIPLE METHODS MULTIPLE METHODS CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID Multi Detector GC CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FIDUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 47 of 55 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

43233 43233 43234 43235 43236 43238 43242 43243 43244 43245 43246 43247 43248 43249 43250 43252 43253 43256 43257 43261 43262 43263 43279 43282 43283 43284 43285 43289 43290 43291 43292 43298 43299 101

126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 126 CANISTER SUBAMBIENT PRESSURE

SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FIDUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 48 of 55 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

43328 43330 43372 43373 43396 43438 43441 43502 43503 43504 43505 43510 43513 43517 43518 43528 43551 43552 43560 43702 43704 43801 43802 43803 43804 43806 43811 43812 43813 43814 43815 43817 43818 126

126 101 101 101 101 101 202 202 202 101 202 202 202 202 202 202 202 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 SS CANISTER PRESSURIZED

SS CANISTER PRESSURIZED Canister Subambient Pressure Canister Subambient Pressure Canister Subambient Pressure Canister Subambient Pressure Canister Subambient Pressure SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB CANISTER SUBAMBIENT PRESSURE SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB Canister Subambient Pressure Canister Subambient Pressure Canister Subambient Pressure CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID Multi Detector GC Multi Detector GC Multi Detector GC Multi Detector GC Multi Detector GC HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION MULTI DETECTOR GC HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION Multi Detector GC Multi Detector GC Multi Detector GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GCUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 49 of 55 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

43819 43820 43821 43823 43824 43826 43828 43829 43830 43831 43832 43835 43836 43838 43839 43843 43844 43860 43954 43960 44201 44201 45109 45109 45201 45201 45202 45202 45203 45203 45204 45204 45207 101

101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 101 126 126 047 087 101 126 101 126 101 126 101 126 101 126 101 CANISTER SUBAMBIENT PRESSURE

CANISTER SUBAMBIENT PRESSURE Canister Subambient Pressure Canister Subambient Pressure CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE Canister Subambient Pressure CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED INSTRUMENTAL INSTRUMENTAL CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC Multi Detector GC Multi Detector GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC Multi Detector GC MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID ULTRA VIOLET ULTRA VIOLET ABSORPTION MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FIDUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 50 of 55 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

45207 45208 45208 45209 45210 45211 45212 45218 45219 45220 45220 45225 45228 45501 45503 45504 45801 45805 45806 45807 45810 61103 61104 62101 62201 63301 63302 68103 68104 68105 68105 68105 68106 126

101 126 126 126 126 126 126 126 101 126 126 126 202 202 202 101 101 101 101 101 020 020 021 012 011 011 810 810 143 780 810 810 SS CANISTER PRESSURIZED

CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED CANISTER SUBAMBIENT PRESSURE SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SS CANISTER PRESSURIZED SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB SILICA-DNPH-CART-KI O3 SCRUB CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE CANISTER SUBAMBIENT PRESSURE Canister Subambient Pressure INSTRUMENTAL INSTRUMENTAL INSTRUMENTAL INSTRUMENTAL INSTRUMENTAL INSTRUMENTAL Met One SASS Met One SASS R & P Model 2000 PM-2.5 FEM Air Sampler INSTRUMENTAL Met One SASS Met One SASS MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID MULTI DETECTOR GC CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID CRYOGENIC PRECONCENTRATION GC/FID HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION HPLC ULTRAVIOLET ABSORPTION MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC MULTI DETECTOR GC Multi Detector GC VECTOR SUMMATION VECTOR SUMMATION SPOT READING LEVEL 1 HYGROSCOPIC PLASTIC FILM PYRANOMETER UV RADIOMETER (PHOTOMETER) Electronic Electronic Electronic ELECTRONIC ElectronicUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

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Page 51 of 55 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

68107 68108 68108 68108 81102 81102 81102 81102 85101 85102 85103 85105 85110 85112 85113 85129 85132 85136 85142 85154 86101 88101 88101 88102 88103 88104 88107 88109 88110 88111 88112 88113 88114 810

143 780 810 079 122 126 197 126 202 202 202 202 202 202 202 202 202 202 202 185 143 170 811 811 811 811 811 811 811 811 811 811 Met One SASS

R & P Model 2000 PM-2.5 FEM Air Sampler INSTRUMENTAL Met One SASS INSTRUMENTAL-R&P SA246B-INLET INSTRUMENT MET ONE 4 MODELS R - P Co Partisol Model 2000 Thermo Partisol Model 2000-D Dichot R - P Co Partisol Model 2000 R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon R&P Model 2000 PM10 Teflon Met One BAM-1020 System R & P Model 2000 PM-2.5 Air Sampler w/VSCC Met One BAM-1020 Mass Monitor w/VSCC Met One SASS Teflon Met OneSASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Barometric Sensor Barometric Sensor Barometric Sensor BAROMETRIC SENSOR Barometric Sensor TEOM-GRAVIMETRIC BETA ATTENUATION Gravimetric GRAVIMETRIC Gravimetric ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS ICP/MS Paired Gravimetric Difference Gravimetric Beta Attenuation Energy dispersive XRF Energy dispersive XRF Energy dispersive XRF Energy dispersive XRF Energy dispersive XRF Energy dispersive XRF Energy dispersive XRF Energy dispersive XRF Energy Dispersive XRFUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 52 of 55 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

88115 88117 88118 88126 88128 88131 88132 88136 88140 88152 88154 88160 88161 88164 88165 88166 88167 88168 88169 88176 88180 88184 88185 88301 88302 88303 88306 88355 88357 88370 88374 88375 88376 811

811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 811 812 812 812 812 839 840 838 841 841 841 Met One SASS Teflon

Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Teflon Met One SASS Nylon Met One SASS Nylon Met One SASS Nylon Met One SASS Nylon URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone InlEnergy dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Energy Dispersive XRF Ion Chromatography Ion Chromatography Ion Chromatography Ion Chromatography OC1+OC2+OC3+OC4+(OP(TOT))=(88374+88375+88376+88377+88388) EC1+EC2+EC3-(OP(TOT))=(88383+88384+88385-88388)) OC1+OC2+OC3+OC4+(OP(TOR))=(88374+88375+88376+88377+88378) IMPROVE_A IMPROVE_AUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 53 of 55 PARAMETER METHOD

CODE COLLECTION METHOD ANALYSIS METHOD METHODS USED IN THIS REPORT

88377 88378 88380 88383 88384 88385 88388 88403 88501 88502 841

842 831 841 841 841 826 812 731 810 URG 3000N w/Pall Quartz filter and Cyclone Inl

URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl URG 3000N w/Pall Quartz filter adn Cyclone Inl URG 3000N w/Pall Quartz filter adn Cyclone Inl URG 3000N w/Pall Quartz filter adn Cyclone Inl URG 3000N w/Pall Quartz filter and Cyclone Inl Met One SASS Nylon Met-One BAM-1020 W/PM2.5 SCC Met One SASS Teflon IMPROVE_A IMPROVE_A IMPROVE_A TOR EC1+EC2+EC3-(OP(TOR))=(88383+88384+88385-88378)) IMPROVE_A IMPROVE_A IMPROVE_A IMPROVE_A TOT Ion Chromatography Beta Attenuation GravimetricUNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 54 of 55 PQAOS USED IN THIS REPORT

PQAO AGENCY DESCRIPTION 0053 1357 Arizona Department Of Environmental Quality Freeport McMoRan Miami, Inc.UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AIR QUALITY SYSTEM May. 29, 2014

Note: The * indicates that the mean does not satisfy summary criteria. QUICKLOOK ALL PARAMETERS

Page 55 of 55 M N

S

U

X Y The monitoring organization has revised data from this monitor since the

most recent certification letter received from the state. The certifying agency has submitted the certification letter and required summary reports, but the certifying agency and/or EPA has determined that issues regarding the quality of the ambient concentration data cannot be resolved due to data completeness, the lack of performed quality assurance checks or the results of uncertainty statistics shown in the AMP255 report or the certification and quality assurance report. The certifying agency has submitted the certification letter and required summary reports. A value of "S" conveys no Regional assessment regarding data quality per se. This flag will remain until the Region provides an "N" or "Y" concurrence flag. Uncertified. The certifying agency did not submit a required certification letter and summary reports for this monitor even though the due date has passed, or the state's certification letter specifically did not apply the certification to this monitor. Certification is not required by 40 CFR 58.15 and no conditions apply to be the basis for assigning another flag value The certifying agency has submitted a certification letter, and EPA has no unresolved reservations about data quality (after reviewing the letter, the attached summary reports, the amount of quality assurance data submitted to AQS, the quality statistics, and the highest reported concentrations). MEANING CERTIFICATION EVALUATION AND CONCURRENCE FLAG MEANINGS

FLAG