### 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349



# Order Summary Report 

# Analytical Laboratory

Order Number: J13070052 Project Name:

Lab Contact: Jason C Perkins 

### Date: 8/13/2013 Customer Address: 8320 NC Hwy 150 East Customer Name(s): NATHAN CRAIG/ JOSH QUINN

Mail Code: Marshall Steam Station Terrell, NC 28682
Phone: 980-875-5348 Report Authorized By: (Signature) 

### Program Comments: Please contact the Program Manager (Jason C Perkins) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used asinformation only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report isavailable upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions.The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Jason C Perkins

## Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2013015272 MARSHALL 01-Jul-13 8: 55 AM illegible BOTTOM ASH SLUICE 2013015273 MARSHALL 01-Jul-13 9:12 AM G.LONG SERVICE/INTAKE WATER 2013015274 MARSHALL 01-Jul-13 8:50 AM G.LONG ASH BASIN 2013015275 MARSHALL 01-Jul-13 8:13 AM G.LONG BLANK 4 Total Samples

### COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No 

# Technical Validation Review Checklist:

Yes No
Yes No


## Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Ce rtificate of Analysis Analytical Laboratory QC Report Chain of Custody

Reviewed By: 

### Therona T James Date: 

### 8/13/2013 Electronic Data Deliverable (EDD) Sent Separately

# Certificate of Laboratory Analysis This re port shall not be reproduced, exce pt in full. 

## Order # J13070052

2013015272 Collection Date: 01-Jul-13 8:55 AM 

### Site: BOTTOM ASH SLUICE Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam ple #:

Analyst DF OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L EPA 1664B 07/10/2013 07:15 TJA7067 5 1 BIOCHEMICAL OXYGEN DEMAND (BOD) - (Analysis Performed by Prism Labs) Vendor Parameter Complete Vendor Method V_PRISM AMMONIA (COLORIMETRIC) Ammonia (Colorimetric) 0.054 mg-N/L EPA 350.1 07/08/2013 11:49 BGN9034 0.02 1 NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.318 mg-N/L EPA 353.2 07/08/2013 11:05 BGN9034 0.01 1 TOTAL KJELDAHL NITROGEN (COLORIMETRIC) Total Kjeldahl Nitrogen (Colorimetric) < 0.15 mg-N/L EPA 351.2 07/10/2013 13:59 TLINN 0.15 1 TOTAL PHOSPHORUS (COLORIMETRIC) Total Phosphorus (Colorimetric) 0.047 mg-P/L EPA 365.1 07/09/2013 08:41 BGN9034 0.005 1 INORGANIC IONS BY IC Chloride 6.6 mg/L EPA 300.0 07/09/2013 17:03 JAHERMA 0.1 1 Sulfate 14 mg/L EPA 300.0 07/09/2013 17:03 JAHERMA 1 10 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 1.23 mg/L EPA 200.7 07/12/2013 14:24 DJSULL1 0.05 10 Magnesium (Mg) 2.19 mg/L EPA 200.7 07/12/2013 14:24 DJSULL1 0.05 10 Silicon (Si) 5.94 mg/L EPA 200.7 07/12/2013 14:24 DJSULL1 0.1 10 TOTAL RECOVERABLE METALS BY ICP-MS Thallium (Tl) < 1 ug/L EPA 200.8 07/17/2013 11:06 DJSULL1 1 1 Vanadium (V) 6.42 ug/L EPA 200.8 07/17/2013 11:06 DJSULL1 1 1 Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 66 mg/L SM2540C 07/02/2013 14:14 SWILLI3 25 1

# Certificate of Laboratory Analysis This re port shall not be reproduced, exce pt in full. 

## Order # J13070052

2013015273 Collection Date: 01-Jul-13 9:12 AM 

### Site: SERVICE/INTAKE WATER Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam ple #:

Analyst DF OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L EPA 1664B 07/10/2013 07:15 TJA7067 5 1 BIOCHEMICAL OXYGEN DEMAND (BOD) - (Analysis Performed by Prism Labs) Vendor Parameter Complete Vendor Method V_PRISM AMMONIA (COLORIMETRIC) Ammonia (Colorimetric) 0.046 mg-N/L EPA 350.1 07/08/2013 11:52 BGN9034 0.02 1 NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 0.148 mg-N/L EPA 353.2 07/08/2013 11:07 BGN9034 0.01 1 TOTAL KJELDAHL NITROGEN (COLORIMETRIC) Total Kjeldahl Nitrogen (Colorimetric) 0.19 mg-N/L EPA 351.2 07/10/2013 14:00 TLINN 0.15 1 TOTAL PHOSPHORUS (COLORIMETRIC) Total Phosphorus (Colorimetric) 0.018 mg-P/L EPA 365.1 07/09/2013 08:38 BGN9034 0.005 1 INORGANIC IONS BY IC Chloride 27 mg/L EPA 300.0 07/09/2013 16:44 JAHERMA 1 10 Sulfate 17 mg/L EPA 300.0 07/09/2013 16:44 JAHERMA 1 10 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 0.373 mg/L EPA 200.7 07/12/2013 14:20 DJSULL1 0.005 1 Magnesium (Mg) 6.88 mg/L EPA 200.7 07/12/2013 14:20 DJSULL1 0.005 1 Silicon (Si) 4.17 mg/L EPA 200.7 07/12/2013 14:20 DJSULL1 0.01 1 TOTAL RECOVERABLE METALS BY ICP-MS Thallium (Tl) < 1 ug/L EPA 200.8 07/17/2013 11:03 DJSULL1 1 1 Vanadium (V) 1.53 ug/L EPA 200.8 07/17/2013 11:03 DJSULL1 1 1 Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 150 mg/L SM2540C 07/02/2013 14:14 SWILLI3 25 1

# Certificate of Laboratory Analysis This re port shall not be reproduced, exce pt in full. 

## Order # J13070052

2013015274 Collection Date: 01-Jul-13 8:50 AM 

### Site: ASH BASIN Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam ple #:

Analyst DF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 

### 2013015275 Collection Date: 01-Jul-13 8:13 AM 

### Site: BLANK Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam ple #:

Analyst DF TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) < 0.005 mg/L EPA 200.7 07/12/2013 14:16 DJSULL1 0.005 1 Magnesium (Mg) < 0.005 mg/L EPA 200.7 07/12/2013 14:16 DJSULL1 0.005 1 Silicon (Si) 0.010 mg/L EPA 200.7 07/12/2013 14:16 B DJSULL1 0.01 1 TOTAL RECOVERABLE METALS BY ICP-MS Thallium (Tl) < 1 ug/L EPA 200.8 07/17/2013 10:59 DJSULL1 1 1 Vanadium (V) < 1 ug/L EPA 200.8 07/17/2013 10:59 DJSULL1 1 1



### Qualifiers: B Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample is less than 10X the concentration in the method blank. Analyte concentration in sample could be due to contamination.

### This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cert No. 37735 

# Case Narrative 07/11/2013

Duke Energy Corporation Jay Perkins 13339 Hagers Ferry Road Huntersville, NC 28078 Project: MSS Bottom Ash Sluice Project No.: J13070052 Lab Submittal Date: 07/01/2013 Prism Work Order: 3070008 VA Certification No. 460211 DoD ELAP: L-A-B Accredited Certificate No. L2307 ISO/IEC 17025: L-A-B Accredited Certificate No. L2307



### Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC.



### VP Laboratory Services Reviewed By Angela D. Overcash Robbi A. Jones For Angela D. Overcash President/Project Manager

Data Qualifiers Key Reference: 

### D RPD value outside of the control limits.

Method Detection Limit MDL Below Reporting Limit BRL Relative Percent Difference RPD 

## * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 1 of 6

# Sample Receipt Summary 07/11/2013 

## Prism Work Order: 3070008 Client Sample ID Matrix Lab Sample ID Date Sampled Date Received 

### 3070008-01 07/01/13 2013015272/Bottom Ash Sluice 0.3m 07/01/13 Water 3070008-02 07/01/13 2013015273/Service/ Intake Water 0.3m 07/01/13 Water Samples received in good condition at 5.0 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 2 of 6

# Laboratory Report 07/11/2013

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: MSS Bottom Ash Sluice Duke Energy Corporation
Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 3070008-01 Prism Work Order: 3070008 Time Collected: 07/01/13 08:55 Time Submitted: 07/01/13 15:55 2013015272/Bottom Ash Sluice 

### J13070052

General Chemistry Parameters BRL *SM5210 B P3G0133 1 2.0 7/3/13 8:55 MES mg/L Biochemical Oxygen Demand

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 3 of 6

# Laboratory Report 07/11/2013

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: MSS Bottom Ash Sluice Duke Energy Corporation
Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 3070008-02 Prism Work Order: 3070008 Time Collected: 07/01/13 09:12 Time Submitted: 07/01/13 15:55 2013015273/Service/ Intake Wate 

### J13070052

General Chemistry Parameters 2.3 *SM5210 B P3G0133 1 2.0 7/3/13 9:10 MES mg/L Biochemical Oxygen Demand

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 4 of 6

### 7/11/13 

## Level II QC Report

13339 Hagers Ferry Road Project No: J13070052 Project: MSS Bottom Ash Sluice Duke Energy Corporation Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 3070008 Time Submitted: 7/1/2013 3:55:00PM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control



### Batch P3G0133 - NO PREP Blank (P3G0133-BLK1) 

### Prepared & Analyzed: 07/03/13 Biochemical Oxygen Demand mg/L BRL 2.0 LCS (P3G0133-BS1) 

### Prepared & Analyzed: 07/03/13 Biochemical Oxygen Demand mg/L 178 2.0 198.0 85-115 90 Duplicate (P3G0133-DUP1) 

### Prepared & Analyzed: 07/03/13 Source: 3070008-02 Biochemical Oxygen Demand mg/L 3.60 2.0 2.30 30 D 44

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 5 of 6

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