### 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 

# Order Summary Report 

# Analytical Laboratory

Order Number: J12030004

Lab Contact: Jason C Perkins 

### Date: 3/14/2012 Customer Address: 253 Plant Allen Road Customer Name(s): BILL KENNEDY, RON LAWS, ALLEN STOWE, ROBBIN JOLLY, DON SCRUG

Belmont, NC 28012

Phone: 980-875-5348 Report Authorized By: (Signature)


### Program Comments: Please contact the Program Manager (Jason C Perkins) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.

## Sample ID's & Descriptions:

Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2012004885 ALLEN 29-Feb-12 10:05 AM BS FGD Purge Eff 2012004886 ALLEN 29-Feb-12 8:55 AM BS EQ Tank Eff 2012004887 ALLEN 29-Feb-12 11:02 AM BS BioReactor 1 Inf 2012004888 ALLEN 29-Feb-12 11:02 AM BS BioReactor 1 Inf BLANK 2012004889 ALLEN 29-Feb-12 10:40 AM BS BioReactor 2 Inf 2012004890 ALLEN 29-Feb-12 10:40 AM BS BioReactor 2 Inf BLANK 2012004891 ALLEN 29-Feb-12 10:50 AM BS BioReactor 2 Eff 2012004892 ALLEN 29-Feb-12 10:50 AM BS BioReactor 2 Eff BLANK 2012004893 ALLEN 29-Feb-12 10:50 AM BS Filter Blk 9 Total Samples

### COC and .pdf report are in agreement with sample totals

and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. The Vendor Laboratories have been qualified by the Analytical Laboratory Yes No



# Technical Validation Review Checklist:

Yes No

Yes No



## Report Sections Included:

Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody

Reviewed By: 

### DataBase Administrator Date: 

### 3/14/2012 Yes

Electronic Data Deliverable (EDD) Sent Separately

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12030004

2012004885 Collection Date: 29-Feb-12 10:05 AM 

### Site: FGD Purge Eff Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF ALKALINITY Vendor Parameter complete V_PRISM 1 INORGANIC IONS BY IC Bromide 30 mg/L EPA 300.0 05-Mar-12 18:13 JAHERMA 5 50 Chloride 2700 mg/L EPA 300.0 05-Mar-12 18:13 JAHERMA 100 1000 Sulfate 1600 mg/L EPA 300.0 05-Mar-12 18:13 JAHERMA 100 1000 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 34.7 ug/L EPA 245.1 06-Mar-12 11:54 AGIBBS 2.5 50 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 2.5 ug/L EPA 245.1 09-Mar-12 09:51 AGIBBS 2.5 50 DISSOLVED METALS BY ICP Manganese (Mn) 4.71 mg/L EPA 200.7 07-Mar-12 14:36 DJSULL1 0.02 4 TOTAL RECOVERABLE METALS BY ICP Boron (B) 39.2 mg/L EPA 200.7 12-Mar-12 11:58 DJSULL1 0.5 10 Calcium (Ca) 2150 mg/L EPA 200.7 12-Mar-12 11:58 DJSULL1 0.1 10 Iron (Fe) 96.7 mg/L EPA 200.7 12-Mar-12 11:58 DJSULL1 0.1 10 Lithium (Li) 0.182 mg/L EPA 200.7 12-Mar-12 11:58 DJSULL1 0.05 10 Magnesium (Mg) 336 mg/L EPA 200.7 12-Mar-12 11:58 DJSULL1 0.05 10 Manganese (Mn) 5.41 mg/L EPA 200.7 12-Mar-12 11:58 DJSULL1 0.05 10 Potassium (K) 30.8 mg/L EPA 200.7 12-Mar-12 11:58 DJSULL1 1 10 Sodium (Na) 22.8 mg/L EPA 200.7 12-Mar-12 11:58 DJSULL1 0.5 10 DISSOLVED METALS BY ICP-MS Selenium (Se) 224 ug/L EPA 200.8 07-Mar-12 13:42 MHH7131 10 10 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 202 ug/L EPA 200.8 06-Mar-12 13:17 KRICHAR 10 10 Cadmium (Cd) < 10 ug/L EPA 200.8 06-Mar-12 13:17 KRICHAR 10 10 Chromium (Cr) 162 ug/L EPA 200.8 06-Mar-12 13:17 KRICHAR 10 10 Copper (Cu) 199 ug/L EPA 200.8 06-Mar-12 13:17 KRICHAR 10 10 Nickel (Ni) 187 ug/L EPA 200.8 06-Mar-12 13:17 KRICHAR 10 10 Selenium (Se) 1150 ug/L EPA 200.8 06-Mar-12 13:17 KRICHAR 10 10 Silver (Ag) < 10 ug/L EPA 200.8 06-Mar-12 13:17 KRICHAR 10 10 Zinc (Zn) 208 ug/L EPA 200.8 06-Mar-12 13:17 KRICHAR 10 10 SELENIUM SPECIATION Vendor Parameter Complete V_AS&C 1

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12030004

2012004885 Collection Date: 29-Feb-12 10:05 AM 

### Site: FGD Purge Eff Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF TOTAL DISSOLVED SOLIDS Vendor Parameter Complete V_PACE 1 TOTAL SUSPENDED SOLIDS Vendor Parameter Complete V_PACE 1


### 2012004886 Collection Date: 29-Feb-12 8:55 AM 

### Site: EQ Tank Eff Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 15.9 ug/L EPA 245.1 06-Mar-12 11:56 AGIBBS 2.5 50 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 2.5 ug/L EPA 245.1 09-Mar-12 09:53 AGIBBS 2.5 50 DISSOLVED METALS BY ICP Manganese (Mn) 2.61 mg/L EPA 200.7 07-Mar-12 14:40 DJSULL1 0.02 4 TOTAL RECOVERABLE METALS BY ICP Boron (B) 31.0 mg/L EPA 200.7 12-Mar-12 11:15 DJSULL1 0.5 10 Calcium (Ca) 1350 mg/L EPA 200.7 12-Mar-12 11:15 DJSULL1 0.1 10 Iron (Fe) 59.3 mg/L EPA 200.7 12-Mar-12 11:15 DJSULL1 0.1 10 Lithium (Li) 0.128 mg/L EPA 200.7 12-Mar-12 11:15 DJSULL1 0.05 10 Magnesium (Mg) 217 mg/L EPA 200.7 12-Mar-12 11:15 DJSULL1 0.05 10 Manganese (Mn) 3.26 mg/L EPA 200.7 12-Mar-12 11:15 DJSULL1 0.05 10 Potassium (K) 20.4 mg/L EPA 200.7 12-Mar-12 11:15 DJSULL1 1 10 Sodium (Na) 17.0 mg/L EPA 200.7 12-Mar-12 11:15 DJSULL1 0.5 10 DISSOLVED METALS BY ICP-MS Selenium (Se) 62.7 ug/L EPA 200.8 07-Mar-12 13:46 MHH7131 10 10 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 125 ug/L EPA 200.8 06-Mar-12 13:20 KRICHAR 10 10 Cadmium (Cd) < 10 ug/L EPA 200.8 06-Mar-12 13:20 KRICHAR 10 10 Chromium (Cr) 95.5 ug/L EPA 200.8 06-Mar-12 13:20 KRICHAR 10 10 Copper (Cu) 139 ug/L EPA 200.8 06-Mar-12 13:20 KRICHAR 10 10 Nickel (Ni) 133 ug/L EPA 200.8 06-Mar-12 13:20 KRICHAR 10 10 Selenium (Se) 639 ug/L EPA 200.8 06-Mar-12 13:20 KRICHAR 10 10 Silver (Ag) < 10 ug/L EPA 200.8 06-Mar-12 13:20 KRICHAR 10 10 Zinc (Zn) 153 ug/L EPA 200.8 06-Mar-12 13:20 KRICHAR 10 10

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12030004

2012004887 Collection Date: 29-Feb-12 11:02 AM 

### Site: BioReactor 1 Inf Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF ALKALINITY Vendor Parameter complete V_PRISM 1 MERCURY 1631 Vendor Parameter Complete V_BRAND 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 1 ug/L EPA 245.1 06-Mar-12 11:59 AGIBBS 1 20 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 2.5 ug/L EPA 245.1 09-Mar-12 09:55 AGIBBS 2.5 50 DISSOLVED METALS BY ICP Manganese (Mn) 0.517 mg/L EPA 200.7 07-Mar-12 14:44 DJSULL1 0.02 4 TOTAL RECOVERABLE METALS BY ICP Boron (B) 25.2 mg/L EPA 200.7 12-Mar-12 11:19 DJSULL1 0.5 10 Calcium (Ca) 1120 mg/L EPA 200.7 12-Mar-12 11:19 DJSULL1 0.1 10 Iron (Fe) < 0.1 mg/L EPA 200.7 12-Mar-12 11:19 DJSULL1 0.1 10 Lithium (Li) < 0.05 mg/L EPA 200.7 12-Mar-12 11:19 DJSULL1 0.05 10 Magnesium (Mg) 161 mg/L EPA 200.7 12-Mar-12 11:19 DJSULL1 0.05 10 Manganese (Mn) 0.538 mg/L EPA 200.7 12-Mar-12 11:19 DJSULL1 0.05 10 Potassium (K) 8.02 mg/L EPA 200.7 12-Mar-12 11:19 DJSULL1 1 10 Sodium (Na) 13.9 mg/L EPA 200.7 12-Mar-12 11:19 DJSULL1 0.5 10 DISSOLVED METALS BY ICP-MS Selenium (Se) 52.3 ug/L EPA 200.8 07-Mar-12 13:50 MHH7131 10 10 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 10 ug/L EPA 200.8 06-Mar-12 13:23 KRICHAR 10 10 Cadmium (Cd) < 10 ug/L EPA 200.8 06-Mar-12 13:23 KRICHAR 10 10 Chromium (Cr) < 10 ug/L EPA 200.8 06-Mar-12 13:23 KRICHAR 10 10 Copper (Cu) < 10 ug/L EPA 200.8 06-Mar-12 13:23 KRICHAR 10 10 Nickel (Ni) < 10 ug/L EPA 200.8 06-Mar-12 13:23 KRICHAR 10 10 Selenium (Se) 43.5 ug/L EPA 200.8 06-Mar-12 13:23 KRICHAR 10 10 Silver (Ag) < 10 ug/L EPA 200.8 06-Mar-12 13:23 KRICHAR 10 10 Zinc (Zn) < 10 ug/L EPA 200.8 06-Mar-12 13:23 KRICHAR 10 10 SELENIUM SPECIATION Vendor Parameter Complete V_AS&C 1

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12030004

2012004888 Collection Date: 29-Feb-12 11:02 AM 

### Site: BioReactor 1 Inf BLANK Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF MERCURY 1631 Vendor Parameter Complete V_BRAND 1


### 2012004889 Collection Date: 29-Feb-12 10:40 AM 

### Site: BioReactor 2 Inf Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF ALKALINITY Vendor Parameter complete V_PRISM 1 MERCURY 1631 Vendor Parameter Complete V_BRAND 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 1 ug/L EPA 245.1 06-Mar-12 00:01 AGIBBS 1 20 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 2.5 ug/L EPA 245.1 09-Mar-12 09:58 AGIBBS 2.5 50 DISSOLVED METALS BY ICP Manganese (Mn) 0.649 mg/L EPA 200.7 07-Mar-12 14:48 DJSULL1 0.02 4 TOTAL RECOVERABLE METALS BY ICP Boron (B) 27.3 mg/L EPA 200.7 12-Mar-12 11:23 DJSULL1 0.5 10 Calcium (Ca) 1100 mg/L EPA 200.7 12-Mar-12 11:23 DJSULL1 0.1 10 Iron (Fe) 6.24 mg/L EPA 200.7 12-Mar-12 11:23 DJSULL1 0.1 10 Lithium (Li) < 0.05 mg/L EPA 200.7 12-Mar-12 11:23 DJSULL1 0.05 10 Magnesium (Mg) 159 mg/L EPA 200.7 12-Mar-12 11:23 DJSULL1 0.05 10 Manganese (Mn) 0.691 mg/L EPA 200.7 12-Mar-12 11:23 DJSULL1 0.05 10 Potassium (K) 10.6 mg/L EPA 200.7 12-Mar-12 11:23 DJSULL1 1 10 Sodium (Na) 14.0 mg/L EPA 200.7 12-Mar-12 11:23 DJSULL1 0.5 10 DISSOLVED METALS BY ICP-MS Selenium (Se) < 10 ug/L EPA 200.8 07-Mar-12 13:54 MHH7131 10 10

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12030004

2012004889 Collection Date: 29-Feb-12 10:40 AM 

### Site: BioReactor 2 Inf Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 10 ug/L EPA 200.8 06-Mar-12 13:26 KRICHAR 10 10 Cadmium (Cd) < 10 ug/L EPA 200.8 06-Mar-12 13:26 KRICHAR 10 10 Chromium (Cr) < 10 ug/L EPA 200.8 06-Mar-12 13:26 KRICHAR 10 10 Copper (Cu) < 10 ug/L EPA 200.8 06-Mar-12 13:26 KRICHAR 10 10 Nickel (Ni) 18.9 ug/L EPA 200.8 06-Mar-12 13:26 KRICHAR 10 10 Selenium (Se) < 10 ug/L EPA 200.8 06-Mar-12 13:26 KRICHAR 10 10 Silver (Ag) < 10 ug/L EPA 200.8 06-Mar-12 13:26 KRICHAR 10 10 Zinc (Zn) < 10 ug/L EPA 200.8 06-Mar-12 13:26 KRICHAR 10 10 SELENIUM SPECIATION Vendor Parameter Complete V_AS&C 1


### 2012004890 Collection Date: 29-Feb-12 10:40 AM 

### Site: BioReactor 2 Inf BLANK Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF MERCURY 1631 Vendor Parameter Complete V_BRAND 1


### 2012004891 Collection Date: 29-Feb-12 10:50 AM 

### Site: BioReactor 2 Eff Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF ALKALINITY Vendor Parameter complete V_PRISM 1 INORGANIC IONS BY IC Bromide 21 mg/L EPA 300.0 05-Mar-12 21:54 JAHERMA 5 50 Chloride 1800 mg/L EPA 300.0 05-Mar-12 21:54 JAHERMA 100 1000 Sulfate 1700 mg/L EPA 300.0 05-Mar-12 21:54 JAHERMA 100 1000 MERCURY 1631 Vendor Parameter Complete V_BRAND 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 1 ug/L EPA 245.1 06-Mar-12 00:03 AGIBBS 1 20 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) < 2.5 ug/L EPA 245.1 09-Mar-12 10:00 AGIBBS 2.5 50

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12030004

2012004891 Collection Date: 29-Feb-12 10:50 AM 

### Site: BioReactor 2 Eff Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF DISSOLVED METALS BY ICP Manganese (Mn) 0.800 mg/L EPA 200.7 07-Mar-12 14:52 DJSULL1 0.02 4 TOTAL RECOVERABLE METALS BY ICP Boron (B) 32.8 mg/L EPA 200.7 12-Mar-12 11:26 DJSULL1 0.5 10 Calcium (Ca) 1120 mg/L EPA 200.7 12-Mar-12 11:26 DJSULL1 0.1 10 Iron (Fe) 0.920 mg/L EPA 200.7 12-Mar-12 11:26 DJSULL1 0.1 10 Lithium (Li) < 0.05 mg/L EPA 200.7 12-Mar-12 11:26 DJSULL1 0.05 10 Magnesium (Mg) 187 mg/L EPA 200.7 12-Mar-12 11:26 DJSULL1 0.05 10 Manganese (Mn) 0.851 mg/L EPA 200.7 12-Mar-12 11:26 DJSULL1 0.05 10 Potassium (K) 13.0 mg/L EPA 200.7 12-Mar-12 11:26 DJSULL1 1 10 Sodium (Na) 14.6 mg/L EPA 200.7 12-Mar-12 11:26 DJSULL1 0.5 10 DISSOLVED METALS BY ICP-MS Selenium (Se) < 5 ug/L EPA 200.8 07-Mar-12 13:58 MHH7131 5 5 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 5 ug/L EPA 200.8 06-Mar-12 13:29 KRICHAR 5 5 Cadmium (Cd) < 5 ug/L EPA 200.8 06-Mar-12 13:29 KRICHAR 5 5 Chromium (Cr) < 5 ug/L EPA 200.8 06-Mar-12 13:29 KRICHAR 5 5 Copper (Cu) < 5 ug/L EPA 200.8 06-Mar-12 13:29 KRICHAR 5 5 Nickel (Ni) 128 ug/L EPA 200.8 06-Mar-12 13:29 KRICHAR 5 5 Selenium (Se) < 5 ug/L EPA 200.8 06-Mar-12 13:29 KRICHAR 5 5 Silver (Ag) < 5 ug/L EPA 200.8 06-Mar-12 13:29 KRICHAR 5 5 Zinc (Zn) 7.85 ug/L EPA 200.8 06-Mar-12 13:29 KRICHAR 5 5 SELENIUM SPECIATION Vendor Parameter Complete V_AS&C 1


### 2012004892 Collection Date: 29-Feb-12 10:50 AM 

### Site: BioReactor 2 Eff BLANK Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF MERCURY 1631 Vendor Parameter Complete V_BRAND 1

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J12030004

2012004893 Collection Date: 29-Feb-12 10:50 AM 

### Site: Filter Blk Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg) 0.07 ug/L EPA 245.1 09-Mar-12 10:02 AGIBBS 0.05 1 DISSOLVED METALS BY ICP Manganese (Mn) 0.007 mg/L EPA 200.7 07-Mar-12 14:28 DJSULL1 0.005 1 DISSOLVED METALS BY ICP-MS Selenium (Se) < 1 ug/L EPA 200.8 07-Mar-12 12:11 MHH7131 1 1

### This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cert No. 37735 

# Case Narrative 03/09/2012

Duke Energy Corporation (04) Jay Perkins 13339 Hagers Ferry Road Huntersville, NC 28078 Project: Allen HAPS/MACT (Wastewater) Project No.: J12030004 Lab Submittal Date: 03/01/2012 Prism Work Order: 2030016 VA Certification No. 1287



### Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC.



### VP Laboratory Services Reviewed By

Data Qualifiers Key Reference: 

### HT Sample received and analyzed outside of the hold time.

Method Detection Limit MDL Below Reporting Limit BRL
Relative Percent Difference RPD


## * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 1 of 9

# Sample Receipt Summary 03/09/2012 

## Prism Work Order: 2030016 Client Sample ID Matrix Lab Sample ID Date Sampled Date Received 

### 2030016-01 02/29/12 2012004885/FGD Purge Eff 03/01/12 Water 2030016-02 02/29/12 2012004887/BioReactor 1 Inf 03/01/12 Water 2030016-03 02/29/12 2012004889/BioReactor 2 Inf 03/01/12 Water 2030016-04 02/29/12 2012004891/BioReactor 2 Eff 03/01/12 Water Samples received in good condition at 3.4 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 2 of 9

# Laboratory Report 03/09/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen HAPS/MACT (Wastewater) Duke Energy Corporation (04)

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2030016-01 Prism Work Order: 2030016 Time Collected: 02/29/12 10:05 Time Submitted: 03/01/12 13:50 2012004885/FGD Purge Eff


### J12030004

General Chemistry Parameters 7.0 *SM4500-H B P2C0028 1 3/1/12 14:50 JAB HT pH Units pH 46 *SM2320 B P2C0106 1 5.0 3/6/12 13:30 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2C0107 1 5.0 3/7/12 15:50 JAB mg/L 0.66 Carbonate Alkalinity 46 *SM2320 B P2C0108 1 5.0 3/6/12 13:30 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 3 of 9

# Laboratory Report 03/09/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen HAPS/MACT (Wastewater) Duke Energy Corporation (04)

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2030016-02 Prism Work Order: 2030016 Time Collected: 02/29/12 11:02 Time Submitted: 03/01/12 13:50 2012004887/BioReactor 1 Inf


### J12030004

General Chemistry Parameters 6.4 *SM4500-H B P2C0028 1 3/1/12 14:50 JAB HT pH Units pH BRL *SM2320 B P2C0106 1 5.0 3/6/12 13:30 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2C0107 1 5.0 3/7/12 15:50 JAB mg/L 0.66 Carbonate Alkalinity BRL *SM2320 B P2C0108 1 5.0 3/6/12 13:30 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 4 of 9

# Laboratory Report 03/09/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen HAPS/MACT (Wastewater) Duke Energy Corporation (04)

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2030016-03 Prism Work Order: 2030016 Time Collected: 02/29/12 10:40 Time Submitted: 03/01/12 13:50 2012004889/BioReactor 2 Inf


### J12030004

General Chemistry Parameters 6.3 *SM4500-H B P2C0028 1 3/1/12 14:50 JAB HT pH Units pH 28 *SM2320 B P2C0106 1 5.0 3/6/12 13:30 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2C0107 1 5.0 3/7/12 15:50 JAB mg/L 0.66 Carbonate Alkalinity 28 *SM2320 B P2C0108 1 5.0 3/6/12 13:30 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 5 of 9

# Laboratory Report 03/09/2012

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: Project: Allen HAPS/MACT (Wastewater) Duke Energy Corporation (04)

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: Prism Sample ID: 2030016-04 Prism Work Order: 2030016 Time Collected: 02/29/12 10:50 Time Submitted: 03/01/12 13:50 2012004891/BioReactor 2 Eff


### J12030004

General Chemistry Parameters 7.0 *SM4500-H B P2C0028 1 3/1/12 14:50 JAB HT pH Units pH 46 *SM2320 B P2C0106 1 5.0 3/6/12 13:30 JAB mg/L 0.66 Total Alkalinity BRL *SM2320 B P2C0107 1 5.0 3/7/12 15:50 JAB mg/L 0.66 Carbonate Alkalinity 46 *SM2320 B P2C0108 1 5.0 3/6/12 13:30 JAB mg/L 0.66 Bicarbonate Alkalinity

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 6 of 9

### 3/9/12 

## Level II QC Report

13339 Hagers Ferry Road Project No: J12030004 Project: Allen HAPS/MACT (Wastewater) Duke Energy Corporation (04)
Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 2030016 Time Submitted: 3/1/2012 1:50:00PM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control



### Batch P2C0028 - NO PREP LCS (P2C0028-BS1) 

### Prepared & Analyzed: 03/01/12 pH pH Units 6.86 6.860 99-101 100 Duplicate (P2C0028-DUP1) 

### Prepared & Analyzed: 03/01/12 Source: 2030016-04 pH pH Units 6.68 6.95 10 4 

### Batch P2C0106 - NO PREP Blank (P2C0106-BLK1) 

### Prepared & Analyzed: 03/06/12 Total Alkalinity mg/L BRL 5.0 LCS (P2C0106-BS1) 

### Prepared & Analyzed: 03/06/12 Total Alkalinity mg/L 259 5.0 250.0 90-110 104 LCS Dup (P2C0106-BSD1) 

### Prepared & Analyzed: 03/06/12 Total Alkalinity mg/L 256 5.0 250.0 200 90-110 102 1 

### Batch P2C0107 - NO PREP Blank (P2C0107-BLK1) 

### Prepared: 03/06/12 Analyzed: 03/07/12 Carbonate Alkalinity mg/L BRL 5.0 LCS (P2C0107-BS1) 

### Prepared: 03/06/12 Analyzed: 03/07/12 Carbonate Alkalinity mg/L 259 5.0 90-110 LCS Dup (P2C0107-BSD1) 

### Prepared: 03/06/12 Analyzed: 03/07/12 Carbonate Alkalinity mg/L 256 5.0 200 90-110 1

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 7 of 9

### 3/9/12 

## Level II QC Report

13339 Hagers Ferry Road Project No: J12030004 Project: Allen HAPS/MACT (Wastewater) Duke Energy Corporation (04)
Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 2030016 Time Submitted: 3/1/2012 1:50:00PM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control



### Batch P2C0108 - NO PREP Blank (P2C0108-BLK1) 

### Prepared & Analyzed: 03/06/12 Bicarbonate Alkalinity mg/L BRL 5.0 LCS (P2C0108-BS1) 

### Prepared & Analyzed: 03/06/12 Bicarbonate Alkalinity mg/L 259 5.0 250.0 90-110 104 LCS Dup (P2C0108-BSD1) 

### Prepared & Analyzed: 03/06/12 Bicarbonate Alkalinity mg/L 256 5.0 250.0 200 90-110 102 1

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

### Page 8 of 9Page 9 of 9

## March 09, 2012

LIMS USE: FR - TERRY WHITNER LIMS OBJECT ID: 92113217



## 92113217 Project: Pace Project No.: RE: Terry Whitner Duke Energy Carolinas, LLC PO Box 37929 DPEHS Charlotte, NC 28237

J12030004

Dear Terry Whitner: Enclosed are the analytical results for sample(s) received by the laboratory on March 01, 2012. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely,
Kevin Herring kevin.herring@pacelabs.com Project Manager

Enclosures

cc: Mr. Jay Perkins, Duke Energy



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### CERTIFICATIONS

Pace Project No.: Project: 92113217

J12030004

Asheville Certification IDs 2225 Riverside Dr., Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia Certification #: 00072 West Virginia Certification #: 356 Virgina/VELAP Certification #: 460147



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### SAMPLE ANALYTE COUNT

Pace Project No.: Project: 92113217

J12030004

Lab ID Sample ID Method Analytes Reported Laboratory Analysts 92113217001 FGD PURGE EFF SM 2540C 1 PASI-A SMW SM 2540D 1 PASI-A SMW



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### HITS ONLY

Pace Project No.: Project: 92113217

J12030004

Parameters Analyzed Result Lab Sample ID Report Limit Qualifiers Units Method Client Sample ID

92113217001 FGD PURGE EFF Total Dissolved Solids 5240 mg/L 03/06/12 09:42 500 SM 2540C Total Suspended Solids 2890 mg/L 03/07/12 11:23 125 SM 2540D



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### PROJECT NARRATIVE

Pace Project No.: Project: 92113217

J12030004

Method: Client: Duke Energy

SM 2540C

Date: March 09, 2012 Description: 2540C Total Dissolved Solids

General Information: 1 sample was analyzed for SM 2540C. All samples were received in acceptable condition with any exceptions noted below.
Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank: All analytes were below the report limit in the method blank with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### PROJECT NARRATIVE

Pace Project No.: Project: 92113217

J12030004

Method: Client: Duke Energy

SM 2540D

Date: March 09, 2012 Description: 2540D Total Suspended Solids

General Information: 1 sample was analyzed for SM 2540D. All samples were received in acceptable condition with any exceptions noted below.
Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank: All analytes were below the report limit in the method blank with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments: This data package has been reviewed for quality and completeness and is approved for release.



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### ANALYTICAL RESULTS

Pace Project No.: Project: 92113217

J12030004
Sample: FGD PURGE EFF Lab ID: 92113217001 Collected: 02/29/12 10:05 Received: 03/01/12 12:45 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. Qual Report Limit 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 5240 mg/L 1 03/06/12 09:42 500 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 2890 mg/L 1 03/07/12 11:23 125



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 03/09/2012 03:11 PM Page 7 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### QUALITY CONTROL DATA

Pace Project No.: Project: 92113217

J12030004

QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/19965 SM 2540C SM 2540C 2540C Total Dissolved Solids Associated Lab Samples: 92113217001

Parameter Units Blank Result Reporting

Limit Qualifiers METHOD BLANK: 730689 Associated Lab Samples: 92113217001 Matrix: Water

Analyzed Total Dissolved Solids mg/L ND 25.0 03/06/12 09:42

Parameter Units LCS Result % Rec Limits Qualifiers % Rec Conc. 730690 LABORATORY CONTROL SAMPLE: LCS Spike
Total Dissolved Solids mg/L 264 250 106 80-120

Parameter Units Dup Result Qualifiers

RPD Result 92113217001 730713 SAMPLE DUPLICATE:

Total Dissolved Solids mg/L 5140 2 5240



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 03/09/2012 03:11 PM Page 8 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### QUALITY CONTROL DATA

Pace Project No.: Project: 92113217

J12030004

QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/19986 SM 2540D SM 2540D 2540D Total Suspended Solids Associated Lab Samples: 92113217001

Parameter Units Blank Result Reporting

Limit Qualifiers METHOD BLANK: 731322 Associated Lab Samples: 92113217001 Matrix: Water

Analyzed Total Suspended Solids mg/L ND 2.5 03/07/12 11:23

Parameter Units LCS Result % Rec Limits Qualifiers % Rec Conc. 731323 LABORATORY CONTROL SAMPLE: LCS Spike Total Suspended Solids mg/L 280 250 112 80-120

Parameter Units Dup Result Qualifiers

RPD Result 92113217001 731324 SAMPLE DUPLICATE:

Total Suspended Solids mg/L 2890 0 2890

Parameter Units Dup Result Qualifiers

RPD Result 92113099003 731325 SAMPLE DUPLICATE:

Total Suspended Solids mg/L ND ND



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 03/09/2012 03:11 PM Page 9 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### QUALIFIERS

Pace Project No.: Project: 92113217

J12030004

DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. LABORATORIES Pace Analytical Services - Asheville PASI-A



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 03/09/2012 03:11 PM Page 10 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### QUALITY CONTROL DATA CROSS REFERENCE TABLE

Pace Project No.: Project: 92113217

J12030004

Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92113217001 WET/19965 FGD PURGE EFF SM 2540C 92113217001 WET/19986 FGD PURGE EFF SM 2540D



### REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 03/09/2012 03:11 PM Page 11 of 11 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

### 3958 6 th

### Ave NW • Seattle, WA 98107 • T: 206-632-6206 • F: 206-632-6017 • www.brooksrand.com • brl@brooksrand.com 

## March 9, 2012
Duke Energy ATTN: Jay Perkins Scientific Support-Laboratory 13339 Hagers Ferry Road Huntersville NC 28078 jcperkins@duke-energy.com labcustomer@duke-energy.com
RE: Project DUK-HV1201 Client Project: J12030004 Dear Mr. Perkins, On March 2, 2012, Brooks Rand Labs (BRL) received three (3) wastewater samples and three (3) corresponding field blanks. Samples were logged-in for total mercury (Hg) analysis. All samples were received, prepared, analyzed, and stored according to BRL SOPs and EPA methodology. The results were blank-corrected as described in the calculations section of the applicable SOP(s) and may be evaluated using adjusted reporting limits to account for sample aliquot size. Please refer to the Sample Results page for sample-specific detection limits and other details. The Duke sample labels did not match the condition of the samples once samples were fully oxidized. The sample labeled BioReactor 1 Inf was perfectly clear after preparation while the Bioreactor 2 Inf Hg Blk was darker. The Duke labels were peeled back and another sample label indicated sample BioReactor 1 Inf was a “blank” sample andBioreactor 2 Inf Hg Blk was indeed a field sample. The labels on the field blank samples did not indicate which were from BioReactor 1 Inf and Bioreator 2 Inf however. Both blank samples were non-detects. Aside from concentration qualifiers, all data was reported without qualification and all associated quality control sample results met the acceptance criteria. BRL, an accredited laboratory, certifies the reported results of all analyses for which BRL is NELAP accredited meet all NELAP requirements. For more details, see the Report Information page of the report. Please feel free to contact me if you have any questions regarding this report. Sincerely,

Tiffany Stilwater Project Manager tiffany@brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



## Definition of Data Qualifiers

(Effective 9/23/09) 

## Laboratory Accreditation BRL is accredited by the National Environmental Laboratory Accreditation Program (NELAP) through the State of Florida Department of Health, Bureau of Laboratories (E87982) and is certified to perform many environmental analyses. BRL is also certified by many other states to perform environmental analyses. For a current list of our accreditations /certifications, please visit our website at <http://www.brooksrand.com/default.asp?contentID=586>. Results reported relate only to the samples listed in the report. 

# Report Information

BLK BRL BS CAL CCV CRM D DUP ICV MSD ND NR PS REC RPD RSD SCV SOP 

### method blank Brooks Rand Labs laboratory fortified blank calibration standard continuing calibration verification certified reference material dissolved fraction duplicate initial calibration verification matrix spike duplicate non-detect non-reportable post preparation spike percent recovery relative percent difference relative standard deviation secondary calibration verification standard operating procedure MDL MRL MS



### method detection limit method reporting limit matrix spike

SRM T COC



### standard reference material total recoverable fraction chain of custody record 

## Common Abbreviations

These qualifiers are based on those previously utilized by Brooks Rand, Ltd., those found in the EPA SOW ILM03.0, Exhibit B, Section III, pg. B-18, and the USEPA Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses; USEPA; July 2002. These supersede all previous qualifiers ever employed by BRL. Detected by the instrument, the result is > the MDL but ≤the MRL. Result is reported and considered an estimate. B E 

### An estimated value due to the presence of interferences. A full explanation is presented in the narrative. H 

### Holding time and/or preservation requirements not met. Result is estimated. J 

### Estimated value. A full explanation is presented in the narrative. J-M 

### Duplicate precision (RPD) for associated QC sample was not within acceptance criteria. Result is estimated. J-N 

### Spike recovery for associated QC sample was not within acceptance criteria. Result is estimated. M 

### Duplicate precision (RPD) was not within acceptance criteria. Result is estimated. N 

### Spike recovery was not within acceptance criteria. Result is estimated. R 

### Rejected, unusable value. A full explanation is presented in the narrative. U 

### Result is ≤the MDL or client requested reporting limit (CRRL). Result reported as the MDL or CRRL. X 

### Result is not BLK-corrected and is within 10x the absolute value of the highest detectable BLK in the batch. Result is estimated. 

## Field Quality Control Samples Please be notified that certain EPA methods require the collection of field quality control samples of an appropriate type and frequency; failure to do so is considered a deviation from some methods and for compliance purposes should only be done with the approval of regulatory authorities. Please see the specific EPA methods for details regarding required field quality control samples.

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Sample Information

Report Matrix Type Received Sampled Sample Lab ID 

### 1209039-01 BioReactor 1 Inf Hg Blk 02/29/2012 03/02/2012 Filter Blank FGD Wastewater 1209039-02 BioReactor 2 Inf Hg Blk 02/29/2012 03/02/2012 Field Blank DIW 1209039-03 BioReactor 2 Inf 02/29/2012 03/02/2012 Sample FGD Wastewater 1209039-04 BioReactor 1 Inf 02/29/2012 03/02/2012 Sample FGD Wastewater 1209039-05 BioReactor 2 Eff 02/29/2012 03/02/2012 Sample FGD Wastewater 1209039-06 BioReactor 2 Eff Hg Blk 02/29/2012 03/02/2012 Field Blank FGD Wastewater 

# Batch Summary

Analyte Prepared Analyzed Sequence Batch Lab Matrix Method 

### B120330 03/05/2012 03/07/2012 1200150 Water EPA 1631 Hg

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Sample Results

Sample Sequence Result MDL MRL Unit Batch

Qualifier Analyte Fraction

Report Matrix 

### BioReactor 1 Inf 

### ng/L 115 T 1200150 B120330 FGD Wastewater 8.08 3.03 1209039-04 Hg
BioReactor 1 Inf Hg Blk 

### ng/L 0.15 T U 1200150 B120330 FGD Wastewater 0.40 0.15 1209039-01 Hg

BioReactor 2 Eff 

### ng/L 90.7 T 1200150 B120330 FGD Wastewater 0.82 0.31 1209039-05 Hg
BioReactor 2 Eff Hg Blk 

### ng/L 0.15 T U 1200150 B120330 FGD Wastewater 0.40 0.15 1209039-06 Hg

BioReactor 2 Inf 

### ng/L 147 T 1200150 B120330 FGD Wastewater 8.16 3.06 1209039-03 Hg
BioReactor 2 Inf Hg Blk 

### ng/L 0.15 T U 1200150 B120330 DIW 0.40 0.15 1209039-02 Hg

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Accuracy & Precision Summary

Batch: 

### B120330

Analyte Result Units Native Spike REC & Limits RPD & Limits Method: 

### EPA 1631 Lab Matrix: 

### Water

Sample Certified Reference Material (1209009, NIST 1641d 1000x dilution) B120330-SRM1 

### 15.68 106% ng/L 85-115 Hg 16.56
Matrix Spike (1209036-03) B120330-MS1 

### 3.027 97% ng/L 71-125 Hg 3.52

0.60
Matrix Spike Duplicate (1209036-03) B120330-MSD1 

### 3.024 111% ng/L 71-125 2412% Hg 3.96

0.60



# Method Blanks & Reporting Limits

Batch: 

### B120330
Method: 

### EPA 1631 Matrix: 

### Water Analyte: 

### Hg Result Units Sample 

### B120330-BLK1 ng/L 0.06 B120330-BLK2 ng/L 0.07 B120330-BLK3 ng/L 0.05 B120330-BLK4 ng/L 0.04 MDL: 

### 0.15 Average: 

### 0.06 Standard Deviation: 

### 0.01 Limit: 

### 0.10 Limit: 

### 0.50 MRL: 

### 0.40

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Instrument Calibration

Sequence: 

### 1200150 Method: 

### EPA 1631 Instrument: 

### THG-10 Date: 

### 03/07/2012 Total Mercury and Mercury Speciation by CVAFS
Analyte: 

### Hg REC & Limits Result True Value Lab ID Units 

### 1200150-IBL1 4.98 pg of Hg 1200150-IBL2 2.87 pg of Hg 1200150-IBL3 5.90 pg of Hg 1200150-IBL4 8.16 pg of Hg 1200150-CAL1 25.00 22.94 pg of Hg 92% 1200150-CAL2 100.0 95.16 pg of Hg 95% 1200150-CAL3 500.0 521.4 pg of Hg 104% 1200150-CAL4 2500 2580 pg of Hg 103% 1200150-CAL5 10000 10740 pg of Hg 107% 1200150-ICV1 1568 1656 pg of Hg 106% 85-115 1200150-CCV1 500.0 398.7 pg of Hg 80% 77-123 1200150-CCB1 8.23 pg of Hg 1200150-CCB2 5.38 pg of Hg 1200150-CCV2 500.0 475.2 pg of Hg 95% 77-123 1200150-CCV3 500.0 513.8 pg of Hg 103% 77-123 1200150-CCV4 500.0 500.6 pg of Hg 100% 77-123 1200150-CCV5 500.0 505.6 pg of Hg 101% 77-123 1200150-CCV6 500.0 517.0 pg of Hg 103% 77-123

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Sample Containers

Lab ID: 

### 1209039-01 Report Matrix: 

### FGD Wastewater Sample Type: 

### Filter Blank Received: 

### 03/02/2012 Sample: 

### BioReactor 1 Inf Hg Blk Collected: 

### 02/29/2012
Comments: 

### Duke Label did not matcht the field label Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71470160 10 Cooler

none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1209039-02 Report Matrix: 

### DIW Sample Type: 

### Field Blank Received: 

### 03/02/2012 Sample: 

### BioReactor 2 Inf Hg Blk Collected: 

### 02/29/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71470160 10 Cooler

none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1209039-03 Report Matrix: 

### FGD Wastewater Sample Type: 

### Sample Received: 

### 03/02/2012 Sample: 

### BioReactor 2 Inf Collected: 

### 02/29/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71470160 10 Cooler

none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1209039-04 Report Matrix: 

### FGD Wastewater Sample Type: 

### Sample Received: 

### 03/02/2012 Sample: 

### BioReactor 1 Inf Collected: 

### 02/29/2012
Comments: 

### Duke Label did not match the field label Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71470160 10 Cooler

none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1209039-05 Report Matrix: 

### FGD Wastewater Sample Type: 

### Sample Received: 

### 03/02/2012 Sample: 

### BioReactor 2 Eff Collected: 

### 02/29/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71470160 10 Cooler

none n/a 250mL Bottle FLPE Hg-T

Lab ID: 

### 1209039-06 Report Matrix: 

### FGD Wastewater Sample Type: 

### Field Blank Received: 

### 03/02/2012 Sample: 

### BioReactor 2 Eff Hg Blk Collected: 

### 02/29/2012 Ship. Cont. pH P-Lot Preservation Lot Size Container Des 

### A 71470160 10 Cooler

none n/a 250mL Bottle FLPE Hg-T

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

### Project ID: 

### DUK-HV1201

PM: 

### Tiffany Stilwater Client PM: 

### Jay Perkins Client PO: 

### 141391



# Shipping Containers

Cooler Tracking No: 

### 4726 7966 8963 via FedEx Temperature: 

### ambient Coolant Type: 

### None Description: 

### Cooler Damaged in transit? 

### No Returned to client? 

### No Custody seals present? 

### No Custody seals intact? 

### No COC present? 

### Yes Received: 

### March 2, 2012 8:45

3958 6th Avenue NW Seattle WA 98107 ·P(206) 632-6206 ·F(206) 632-6017 ·brl@brooksrand.com ·www.brooksrand.com

## March 9 , 201 2

Jay Perkins Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078 (704) 875-5 245 Project: Allen HAPS/MACT (Wastewater) (LIMS # J12030004)

Dear Mr. Perkins , Attached is the report associated with four (4) aqueous samples submitted for selenium speciation analysis on March 1 , 2012

.The samples were received in a sealed cooler at-0.3 ° C on March 2 , 2012

.Selenium speciation analysis was performed via ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP-CRC-MS). Any issues associated with the analysis are addressed in the following report. If you have any questions, please feel free to contact me at your convenience.
Sincerely,

Russell Gerads Vice President Applied Speciation and Consulting, LLC

## Applied Speciation and Consulting, LLC Report prepared for: Jay Perkins Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078 Project: Allen HAPS/MACT (Wastewater) (LIMS # J1 2030004)

March 9 , 2012

1. Sample Reception Four (4) aqueous samples in125mL HDPE bottles (provided by Applied Speciation and Consulting) were submitted for selenium speciation analysi s on March1 , 2012. The samples were received on March 2 , 201 2 in a sealed container at -0.3 ° C. The samples were received in a laminar flow clean hood,void of trace metals contamination and ultra-violet radiation, and was designated a discrete sample identifier. An aliquot of each sample was filtered (0.45μm) and each filtrate w asstored in a secure, monitored cryofreezer (maintained at a temperature of -80o

## C) until selenium speciation analysis could be performed via ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP- CRC -MS).

2. Sample Preparation All sample preparation is performed in laminar flow clean hoods known to be free from trace metals contamination. All applied water for dilutions and sample preservatives are monitored for contamination to account for any biases associated with the sample results. Selenium Speciation Analysis by IC-ICP-CRC-MS Prior to analysis, an aliquot of each sample was filtered with a syringe filter (0.45μm) and injected directly into a sealed autosampler vial. No further sample preparation was performed as any chemical alteration of a sample may shift the equilibrium of the system, resulting in changes in speciation ratios. 3. Sample Analysis All sample analysis is preceded by a minimum of a five-point calibration curve spanning the entire concentration range of interest. Calibration curves are performed at the beginning of each analytical day. All calibration curves, associated with each species of interest, are

## standardized by linear regression resulting in a response factor. All sample results are

instrument blank correctedto account for any operational biases associated with the analytical platform. Prior to sample analysis, all calibration curves are verified using second source standards which are identified as initial calibration verification standards (ICV). Ongoing instrument performance is identified by the analysis of continuing calibration verification standards (CCV) and continuing calibration blanks (CCB) at a minimal interval of every ten analytical runs. Selenium Speciation Analysis by IC-ICP-CRC-MS Eachsample for selenium speciation analysis w asanalyzed by ion chromatography inductively coupled plasma collision reaction cell mass spectrometry (IC-ICP- CRC -MS) on March 2, 2012. An aliquot of each sample is injected onto an anion exchange column and mobilized by a basic (pH > 7) gradient. The eluting selenium species are then introduced into a radio frequency (RF) plasma where energy-transfer processes cause desolvation, atomization, and ionization. The ions are extracted from the plasma through a differentially-pumped vacuum interface and travel through a pressurized chamber (CRC) containing hydrogen gas which preferentially reacts with interfering ions of the same target mass to charge ratios (m/z). A solid-state detector detects ions transmitted through the mass analyzer and the resulting current is processed by a data handling system. Retention times for each eluting species are compared to known standards for species identification.

4. Analytical Issues The overall analyses went well and no significant analytical issues were encountered. All quality control parameters associated with this sample were within acceptance limits. The estimated method detection limits (eMDLs) for selenite, selenate, and selenocyanate are generated from replicate analyses of the lowest standard in the calibration curve. Not all selenium species are present in preparation blanks; therefore, eMDL calculations based on preparation blanks are artificially biased low. The eMDL for methylseleninic acid and selenomethionine is calculated from the average eMDL of selenite, selenate, and selenocyanate. The calibration does not contain methylseleninic acid or selenomethionine due to impurities in these standards which would bias the results for other selenium species.

## If you have any questions or concerns regarding this report, please feel free to contact me.

Sincerely,

Russell Gerads Vice President Applied Speciation and Consulting, LLC

### Sample Results
Sample ID Se(IV) Se(VI) SeCN MeSe(IV) SeMe Unknown Se Species (n) FGD Purge Eff 188 33.5 2.3 3.0 ND (<1.4) 0 (0) BioReactor 1 Inf 4.52 33.6 ND (<0.30) 1.05 ND (<0.34) 1.23 BioReactor 2 Inf 3.94 3.80 0.49 0.35 ND (<0.34) 0.70 (1) BioReactor 2 Eff ND (<0.40) ND (<0.32) ND (<0.30) ND (<0.34) ND (<0.34) 0 (0) All results reflect the applied dilution and are reported in μg/L ND = Not detected at the applied dilution SeCN = Selenocyanate MeSe(IV) = Methylseleninic acid SeMe = Selenomethionine Unknown Se Species = Total concentration of all unknown Se species observed by IC-ICP-MS n = number of unknown Se species observed Report Generated by: Russell Gerads Applied Speciation and Consulting, LLC Selenium Speciation Results for Duke Energy Project Name: Allen HAPS/MACT (Wastewater)

Contact: Jay Perkins
Date: March 9, 2012 LIMS #J12030004

### Quality Control Summary - Preparation Blank Summary Analyte (μg/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL* eMDL 250x eMDL 1000x Se(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.002 0.40 1.6 Se(VI) 0.000 0.091 0.000 0.000 0.023 0.046 0.001 0.32 1.3 SeCN 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.30 1.2 MeSe(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.001 0.34 1.4 SeMe 0.000 0.000 0.000 0.006 0.001 0.003 0.001 0.34 1.4 eMDL = Estimated Method Detection Limit *Please see narrative regarding eMDL calculations
Quality Control Summary - Certified Reference Materials Analyte (μg/L) CRM True Value Result Recovery Se(IV) LCS 9.57 9.76 102.0 Se(VI) LCS 9.48 9.17 96.7 SeCN LCS 8.92 9.23 103.5 MeSe(IV) LCS 6.47 5.88 90.8 SeMe LCS 9.32 8.65 92.8 Applied Speciation and Consulting, LLC Selenium Speciation Results for Duke Energy Project Name: Allen HAPS/MACT (Wastewater)

Contact: Jay Perkins LIMS #J12030004 Date: March 9, 2012 Report Generated by: Russell Gerads

### Quality Control Summary - Matrix Duplicates Analyte (μg/L) Sample ID Rep 1 Rep 2 Mean RPD Se(IV) Batch QC 2.1 3.7 2.9 53.8* Se(VI) Batch QC ND (<1.3) 3.5 NC NC SeCN Batch QC 5.1 4.5 4.8 12.6 MeSe(IV) Batch QC ND (<1.4) ND (<1.4) NC NC SeMe Batch QC ND (<1.4) ND (<1.4) NC NC ND = Not detected at the applied dilution NC = Value was not calculated due to one or more concentrations below the eMDL *Sample concentrations are within 10x the eMDL
Quality Control Summary - Matrix Spike/ Matrix Spike Duplicate Analyte (μg/L) Sample ID Spike Conc MS Result Recovery Spike Conc MSD Result Recovery RPD Se(IV) Batch QC 5560 5661 101.8 5560 5573 100.2 1.6 Se(VI) Batch QC 5045 4892 97.0 5045 4775 94.6 2.4 SeCN Batch QC 4575 4107 89.7 4575 4134 90.3 0.7 Applied Speciation and Consulting, LLC Selenium Speciation Results for Duke Energy Project Name: Allen HAPS/MACT (Wastewater)

Contact: Jay Perkins LIMS #J12030004 Date: March 9, 2012 Report Generated by: Russell Gerads