13339 Hagers Ferry Road

Huntersville, NC 28078-7929

McGuire Nuclear Complex - MG03A2

Phone: 980-875-5245 Fax: 980-875-4349

Order Summary Report

Analytical Laboratory

Order Number: J13070052

Project Name:

Lab Contact: Jason C Perkins

Date: 8/13/2013

Customer Address: 8320 NC Hwy 150 East

Customer Name(s): NATHAN CRAIG/ JOSH QUINN

Mail Code: Marshall Steam Station

Terrell, NC 28682

Phone: 980-875-5348

Report Authorized By:

(Signature)

Program Comments:

Please contact the Program Manager (Jason C Perkins) with any questions regarding this report.

Data Flags & Calculations:

Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality

system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) 

under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data 

included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the 

subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have

been qualified by Duke Energy to perform these analyses except where noted.

Data Package:

This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of 

the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except 

in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The 

order of individual sections within this report is as follows:

Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,

Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & 

Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)

Certification:

The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina 

(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of 

specific methods. 

Jason C Perkins

Analytical Laboratory 

Page 1 of 20 
Sample ID's & Descriptions:

Sample ID Plant/Station

Collection 

Date and Time Collected By Sample Description

2013015272 MARSHALL 01-Jul-13 8:55 AM illegible BOTTOM ASH SLUICE

2013015273 MARSHALL 01-Jul-13 9:12 AM G.LONG SERVICE/INTAKE WATER

2013015274 MARSHALL 01-Jul-13 8:50 AM G.LONG ASH BASIN

2013015275 MARSHALL 01-Jul-13 8:13 AM G.LONG BLANK

4 Total Samples

Analytical Laboratory 

Page 2 of 20 
COC and .pdf report are in agreement with sample totals 

and analyses (compliance programs and procedures).

All Results are less than the laboratory reporting limits.

All laboratory QA/QC requirements are acceptable.

Yes No

Technical Validation Review

Checklist:

Yes No

Yes No

Report Sections Included:

Job Summary Report Sub-contracted Laboratory Results

Sample Identification Customer Specific Data Sheets, Reports, & Documentation

Technical Validation of Data Package Customer Database Entries

Analytical Laboratory Certificate of Analysis

Analytical Laboratory QC Report

Chain of Custody

Reviewed By: Therona T James Date: 8/13/2013

Electronic Data Deliverable (EDD) Sent Separately

Analytical Laboratory 

Page 3 of 20 
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J13070052

2013015272

Collection Date: 01-Jul-13 8:55 AM

Site: BOTTOM ASH SLUICE

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION

Oil and Grease < 5 mg/L EPA 1664B 5 1 07/10/2013 07:15 TJA7067

BIOCHEMICAL OXYGEN DEMAND (BOD) - (Analysis Performed by Prism Labs)

Vendor Parameter Complete Vendor Method V_PRISM

AMMONIA (COLORIMETRIC)

Ammonia (Colorimetric) 0.054 mg-N/L EPA 350.1 0.02 1 07/08/2013 11:49 BGN9034

NITRITE + NITRATE (COLORIMETRIC)

Nitrite + Nitrate (Colorimetric) 0.318 mg-N/L EPA 353.2 0.01 1 07/08/2013 11:05 BGN9034

TOTAL KJELDAHL NITROGEN (COLORIMETRIC)

Total Kjeldahl Nitrogen 

(Colorimetric)

< 0.15 mg-N/L EPA 351.2 0.15 1 07/10/2013 13:59 TLINN

TOTAL PHOSPHORUS (COLORIMETRIC)

Total Phosphorus (Colorimetric) 0.047 mg-P/L EPA 365.1 0.005 1 07/09/2013 08:41 BGN9034

INORGANIC IONS BY IC

Chloride 6.6 mg/L EPA 300.0 0.1 1 07/09/2013 17:03 JAHERMA

Sulfate 14 mg/L EPA 300.0 1 10 07/09/2013 17:03 JAHERMA

TOTAL RECOVERABLE METALS BY ICP

Aluminum (Al) 1.23 mg/L EPA 200.7 0.05 10 07/12/2013 14:24 DJSULL1

Magnesium (Mg) 2.19 mg/L EPA 200.7 0.05 10 07/12/2013 14:24 DJSULL1

Silicon (Si) 5.94 mg/L EPA 200.7 0.1 10 07/12/2013 14:24 DJSULL1

TOTAL RECOVERABLE METALS BY ICP-MS

Thallium (Tl) < 1 ug/L EPA 200.8 1 1 07/17/2013 11:06 DJSULL1

Vanadium (V) 6.42 ug/L EPA 200.8 1 1 07/17/2013 11:06 DJSULL1

Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Element One)

Vendor Parameter Complete Vendor Method V_ELE1

SULFIDE - (Analysis Performed by Element One)

Vendor Parameter Complete Vendor Method V_ELE1

TOTAL DISSOLVED SOLIDS

TDS 66 mg/L SM2540C 25 1 07/02/2013 14:14 SWILLI3

Analytical Laboratory 

Page 4 of 20 
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J13070052

2013015273

Collection Date: 01-Jul-13 9:12 AM

Site: SERVICE/INTAKE WATER

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION

Oil and Grease < 5 mg/L EPA 1664B 5 1 07/10/2013 07:15 TJA7067

BIOCHEMICAL OXYGEN DEMAND (BOD) - (Analysis Performed by Prism Labs)

Vendor Parameter Complete Vendor Method V_PRISM

AMMONIA (COLORIMETRIC)

Ammonia (Colorimetric) 0.046 mg-N/L EPA 350.1 0.02 1 07/08/2013 11:52 BGN9034

NITRITE + NITRATE (COLORIMETRIC)

Nitrite + Nitrate (Colorimetric) 0.148 mg-N/L EPA 353.2 0.01 1 07/08/2013 11:07 BGN9034

TOTAL KJELDAHL NITROGEN (COLORIMETRIC)

Total Kjeldahl Nitrogen 

(Colorimetric)

0.19 mg-N/L EPA 351.2 0.15 1 07/10/2013 14:00 TLINN

TOTAL PHOSPHORUS (COLORIMETRIC)

Total Phosphorus (Colorimetric) 0.018 mg-P/L EPA 365.1 0.005 1 07/09/2013 08:38 BGN9034

INORGANIC IONS BY IC

Chloride 27 mg/L EPA 300.0 1 10 07/09/2013 16:44 JAHERMA

Sulfate 17 mg/L EPA 300.0 1 10 07/09/2013 16:44 JAHERMA

TOTAL RECOVERABLE METALS BY ICP

Aluminum (Al) 0.373 mg/L EPA 200.7 0.005 1 07/12/2013 14:20 DJSULL1

Magnesium (Mg) 6.88 mg/L EPA 200.7 0.005 1 07/12/2013 14:20 DJSULL1

Silicon (Si) 4.17 mg/L EPA 200.7 0.01 1 07/12/2013 14:20 DJSULL1

TOTAL RECOVERABLE METALS BY ICP-MS

Thallium (Tl) < 1 ug/L EPA 200.8 1 1 07/17/2013 11:03 DJSULL1

Vanadium (V) 1.53 ug/L EPA 200.8 1 1 07/17/2013 11:03 DJSULL1

Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Element One)

Vendor Parameter Complete Vendor Method V_ELE1

SULFIDE - (Analysis Performed by Element One)

Vendor Parameter Complete Vendor Method V_ELE1

TOTAL DISSOLVED SOLIDS

TDS 150 mg/L SM2540C 25 1 07/02/2013 14:14 SWILLI3

Analytical Laboratory 

Page 5 of 20 
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J13070052

2013015274

Collection Date: 01-Jul-13 8:50 AM

Site: ASH BASIN

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

SULFIDE - (Analysis Performed by Element One)

Vendor Parameter Complete Vendor Method V_ELE1

2013015275

Collection Date: 01-Jul-13 8:13 AM

Site: BLANK

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

TOTAL RECOVERABLE METALS BY ICP

Aluminum (Al) < 0.005 mg/L EPA 200.7 0.005 1 07/12/2013 14:16 DJSULL1

Magnesium (Mg) < 0.005 mg/L EPA 200.7 0.005 1 07/12/2013 14:16 DJSULL1

Silicon (Si) 0.010 mg/L EPA 200.7 B 0.01 1 07/12/2013 14:16 DJSULL1

TOTAL RECOVERABLE METALS BY ICP-MS

Thallium (Tl) < 1 ug/L EPA 200.8 1 1 07/17/2013 10:59 DJSULL1

Vanadium (V) < 1 ug/L EPA 200.8 1 1 07/17/2013 10:59 DJSULL1

Qualifiers:

B Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in 

sample is less than 10X the concentration in the method blank. Analyte concentration in sample could be 

due to contamination.

Analytical Laboratory 

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This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample 

Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed 

according to the referenced methods. 

Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case 

narrative.

NC Certification No. 402

SC Certification No. 99012

NC Drinking Water Cert No. 37735

Case Narrative

07/11/2013

Duke Energy Corporation

Jay Perkins

13339 Hagers Ferry Road

Huntersville, NC 28078

Project: MSS Bottom Ash Sluice

Project No.: J13070052

Lab Submittal Date: 07/01/2013

Prism Work Order: 3070008

VA Certification No. 460211

DoD ELAP: L-A-B Accredited Certificate No. L2307

ISO/IEC 17025: L-A-B Accredited Certificate No. L2307

Please call if you have any questions relating to this analytical report.

Respectfully,

PRISM LABORATORIES, INC.

VP Laboratory Services

Angela D. Overcash Reviewed By Robbi A. Jones For Angela D. Overcash

President/Project Manager

Data Qualifiers Key Reference:

D RPD value outside of the control limits.

MDL Method Detection Limit

BRL Below Reporting Limit

RPD Relative Percent Difference

*

Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and 

reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 6

Analytical Laboratory 

Page 14 of 20 
Sample Receipt Summary

07/11/2013

Prism Work Order: 3070008

Client Sample ID Lab Sample ID Matrix Date Sampled Date Received

2013015272/Bottom Ash Sluice 0.3m 3070008-01 Water 07/01/13 07/01/13

2013015273/Service/ Intake Water 0.3m3070008-02 Water 07/01/13 07/01/13

Samples received in good condition at 5.0 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 6

Analytical Laboratory 

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Laboratory Report

07/11/2013

Parameter Result Batch

ID

Report

Limit

Analysis

Date/Time

Dilution Method

Factor

Units MDL Analyst

13339 Hagers Ferry Road Project No.: 

Duke Energy Corporation Project: MSS Bottom Ash Sluice

Huntersville, NC 28078

Attn: Jay Perkins

Sample Matrix: Water

Client Sample ID: 

Prism Sample ID: 3070008-01

Prism Work Order: 3070008

Time Collected: 07/01/13 08:55

Time Submitted: 07/01/13 15:55

2013015272/Bottom Ash Sluice 

J13070052

General Chemistry Parameters

Biochemical Oxygen Demand BRL mg/L 2.0 1 *SM5210 B 7/3/13 8:55 MES P3G0133

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 6

Analytical Laboratory 

Page 16 of 20 
Laboratory Report

07/11/2013

Parameter Result Batch

ID

Report

Limit

Analysis

Date/Time

Dilution Method

Factor

Units MDL Analyst

13339 Hagers Ferry Road Project No.: 

Duke Energy Corporation Project: MSS Bottom Ash Sluice

Huntersville, NC 28078

Attn: Jay Perkins

Sample Matrix: Water

Client Sample ID: 

Prism Sample ID: 3070008-02

Prism Work Order: 3070008

Time Collected: 07/01/13 09:12

Time Submitted: 07/01/13 15:55

2013015273/Service/ Intake Wate

J13070052

General Chemistry Parameters

Biochemical Oxygen Demand 2.3 mg/L 2.0 1 *SM5210 B 7/3/13 9:10 MES P3G0133

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 6

Analytical Laboratory 

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7/11/13

Level II QC Report

13339 Hagers Ferry Road Project No: J13070052

Duke Energy Corporation Project: MSS Bottom Ash Sluice

Huntersville, NC 28078

Attn: Jay Perkins

Prism Work Order: 3070008

Time Submitted: 7/1/2013 3:55:00PM

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

 Analyte Limit Notes 

General Chemistry Parameters - Quality Control

Batch P3G0133 - NO PREP

Blank (P3G0133-BLK1) Prepared & Analyzed: 07/03/13 

Biochemical Oxygen Demand BRL 2.0 mg/L

LCS (P3G0133-BS1) Prepared & Analyzed: 07/03/13 

Biochemical Oxygen Demand 178 2.0 mg/L 198.0 90 85-115

Duplicate (P3G0133-DUP1) Source: 3070008-02 Prepared & Analyzed: 07/03/13 

Biochemical Oxygen Demand 3.60 2.0 mg/L 2.30 44 30 D

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 6

Analytical Laboratory 

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Analytical Laboratory 

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