### Major **Area**

**Existing** 240.00 120.00 **New** 20.00 120.00

**Non Vinyl Chloride TOHAP WW Limit**

### Facility **Daily Average Number Non-VC Total HAP**  **Unit**

P1-Henry 1 8.20059ppm P1-Henry 2 5.7603 ppm P1-Henry 3 0.738ppm P1-Henry 4 3.2605 ppm P1-Henry 5 9.88136ppm P1-Henry 6 9.8442 ppm FPC SPVC 1 11.52 ppm FPC SPVC 2 30.328ppm FPC SPVC 3 3.967ppm WLCC 1 19.45255 ppm WLCC 2 27.04684ppm WLCC 3 29.402 ppm WLCC 4 25.95 ppm WLCC 5 25.883 ppm WLCC 6 27.9ppm Oxy DP 1 20.3181ppm Oxy DP 2 90.90002ppm Oxy DP 3 10.7832 ppm Oxy DP 4 9.5532 ppm Oxy DP 5 6.5697ppm Oxy DP 6 19.4795 ppm Oxy DP 7 10.3795 ppm Oxy DP 8 11.70059ppm P1-Ptown 1 58.06624ppm P1-Ptown 2 72.7676ppm P1-Ptown 3 50.1121ppm P1-Ptown 4 54.8209ppm P1-Ptown 5 44.512 ppm P1-Ptown 6 34.0242 ppm Shintech TX 1 51.874ppm Shintech TX 2 23.402 ppm Shintech TX 3 85.422 ppm Shintech TX 4 51.738ppm Shintech TX 5 156.347ppm Shintech TX 6 90.966ppm Shintech TX 7 63.872 ppm Shintech TX 8 8.96827ppm Shintech TX 9 45.60199ppm Shintech TX 10 66.3157ppm Shintech TX 11 9.9028ppm Shintech TX 12 40.8291ppm Oxy Pas 1 662.0917ppm Oxy Pas 2 867.1299ppm Oxy Pas 3 819.322 ppm Oxy Pas 4 499.0953 ppm Oxy Pas 5 274.1984ppm

### Facility **Daily Average Number Non-VC Total HAP**  **Unit**

Oxy Pas 6 632.06ppm Shintech TX 1 63.872 ppm Shintech TX 2 8.96827ppm Shintech TX 3 45.60199ppm Shintech TX 4 66.3157ppm Shintech TX 5 9.9028ppm Shintech TX 6 40.8291ppm Shintech TX 7 51.874ppm Shintech TX 8 23.402 ppm Shintech TX 9 85.422 ppm Shintech TX 10 51.738ppm Shintech TX 11 156.347ppm Shintech TX 12 90.966ppm Shintech AD 1 67.002 ppm Shintech AD 2 82.701ppm Shintech AD 3 80.363 ppm Shintech AD 4 84.7368ppm Shintech AD 5 127.098ppm Shintech AD 6 104.6169ppm Shintech PL 1 333.977ppm Shintech PL 2 68.821ppm Shintech PL 3 68.181ppm Shintech PL 4 34.20681ppm Shintech PL 5 36.57908ppm Shintech PL 6 31.428ppm FPC-TX 1 115.63 ppm FPC-TX 2 101.98ppm FPC-TX 3 82.87ppm GG-Plaquemine 1 709.7033 ppm GG-Plaquemine 2 201.0472ppm GG-Plaquemine 3 497.757ppm GG-Plaquemine 4 540.4278ppm GG-Plaquemine 5 119.1009ppm GG-Plaquemine 6 1643.8012ppm GG-Aberdeen 1 492.8067ppm GG-Aberdeen 2 199.23517ppm GG-Aberdeen 3 1091.2034ppm GG-Aberdeen 4 917.053 ppm GG-Aberdeen 5 1210.0102ppm GG-Aberdeen 6 1277.9633 ppm

### Top 5 Determination

**Row Labels Average of Non-VC Total HAP**  P1-Henry 6.280825 1 FPC SPVC 15.27166667 2 Oxy DP 22.46047625 3 WLCC 25.939065 4 P1-Ptown 52.38384 5 Shintech TX 57.93657167 6 Shintech AD 91.08628333 7 Shintech PL 95.53214833 8 FPC-TX 100.16 9 GG-Plaquemine 618.6395667 10 Oxy Pas 625.64955 11 GG-Aberdeen 864.7119617 12Major Existing Source Non-Vinyl Chloride Limit Calculation

**Facility Daily Average** 

**Number Non-VC Total** 

**HAP ln**  **Unit Rank**  P1-Henry 1 8.20059 2.104206 ppm 1 P1-Henry 2 5.7603 1.75099 ppm 1 P1-Henry 3 0.738 -0.30381 ppm 1 **Normal LN**  P1-Henry 4 3.2605 1.181881 ppm 1 Sample Size 29 29 P1-Henry 5 9.88136 2.29065 ppm 1 Compliance Avg Period 1 1 P1-Henry 6 9.8442 2.286882 ppm 1 Average 25.2800 2.81 FPC SPVC 1 11.52 2.444085 ppm 2 Median 19.4795 2.97 FPC SPVC 2 30.328 3.412071 ppm 2 Standard Deviation 22.2084 1.05 FPC SPVC 3 3.967 1.37801 ppm 2 Minimum 0.7380 -0.30 Oxy DP 1 20.3181 3.011512 ppm 3 Maximum 90.900 4.51 Oxy DP 2 90.90002 4.50976 ppm 3 Skewness 1.39 -0.83 Oxy DP 3 10.7832 2.377989 ppm 3 SE Skewness 0.455 0.455 Oxy DP 4 9.5532 2.256876 ppm 3 Skewness Test Non-normal Normal Oxy DP 5 6.5697 1.882468 ppm 3 Kurtosis 1.7 1.33 Oxy DP 6 19.4795 2.969363 ppm 3 SE Kurtosis 0.91 0.91 Oxy DP 7 10.3795 2.339833 ppm 3 Kurtosis Test Normal Normal Oxy DP 8 11.70059 2.459639 ppm 3 99.0% t-statistic for UPL 2.47 2.47 WLCC 1 19.45255 2.967978 ppm 4 99.0% UPL 81.008 230.7705 WLCC 2 27.04684 3.29757 ppm 4 WLCC 3 29.402 3.381063 ppm 4 average in variability analysis 25.2800 WLCC 4 25.95 3.256172 ppm 4 Avg MDL WLCC 5 25.883 3.253586 ppm 4 3x Max DL WLCC 6 27.9 3.328627 ppm 4 99.0% UPL 230.770 ppm P1-Ptown 1 58.06624 4.061584 ppm 5 **MA CT Floor Limit**  **240.00 ppm**  P1-Ptown 2 72.7676 4.287271 ppm 5 P1-Ptown 3 50.1121 3.914262 ppm 5

P1-Ptown 4 54.8209 4.004072 ppm 5 P1-Ptown 5 44.512 3.795759 ppm 5 P1-Ptown 6 34.0242 3.527072 ppm 5 **Existing Source Total Non-VC HA P determined by**  **Daily Samples** 

1) if the 3x RDL value is less than or equal to the calculated floor or emissions limit, use the calculated floor or emissions limit value for the rule making. 2) if the 3x RDL value is greater than the calculated floor or emissions limit, use the 3x RDL value as the floor or emissions limit adjusted for measurement variability for the rule makingMajor New Source Non-Vinyl Chloride Limit Calculation

**Facility Daily Average** 

**Number Non-VC Total** 

**HAP ln**  **Unit Rank**  P1-Henry 1 8.20059 2.104206 ppm 1 P1-Henry 2 5.7603 1.75099 ppm 1 P1-Henry 3 0.738 -0.30381 ppm 1 **Normal LN**  P1-Henry 4 3.2605 1.181881 ppm 1 Sample Size 6 6 P1-Henry 5 9.88136 2.29065 ppm 1 Compliance Avg Period 1 1 P1-Henry 6 9.8442 2.286882 ppm 1 Average 6.2808 1.55 Median 6.9804 1.93 Standard Deviation 3.7273 1.00 Minimum 0.7380 -0.30 Maximum 9.881 2.29 Skewness -0.57 -1.63 SE Skewness 1.000 1.000 Skewness Test Normal Normal Kurtosis SE Kurtosis 2.00 2.00 Kurtosis Test Normal Normal 99.0% t-statistic for UPL 3.36 3.36 99.0% UPL 19.828 179.5423

average in variability analysis 6.2808 Avg MDL 3x Max DL 99.0% UPL 19.828 ppm **MA CT Floor Limit**  **20.00 ppm**  **Existing Source Total Non-VC HA P determined by**  **Daily Samples** 

1) if the 3x RDL value is less than or equal to the calculated floor or emissions limit, use the calculated floor or emissions limit value for the rule making. 2) if the 3x RDL value is greater than the calculated floor or emissions limit, use the 3x RDL value as the floor or emissions limit adjusted for measurement variability for the rule makingArea Source Non-Vinyl Chloride Limit Calculation

**Facility Daily** 

**Average Non-VC** 

**Total HAP ln**  **Unit Rank**  Oxy DP 1 20.3181 3.011512 ppm 1 Oxy DP 2 90.90002 4.50976 ppm 1 Oxy DP 3 10.7832 2.377989 ppm 1 **Normal LN**  Oxy DP 4 9.5532 2.256876 ppm 1 Sample Size 8 8 Oxy DP 5 6.5697 1.882468 ppm 1 Compliance Avg Period 1 1 Oxy DP 6 19.4795 2.969363 ppm 1 Average 22.4605 2.73 Oxy DP 7 10.3795 2.339833 ppm 1 Median 11.2419 2.42 Oxy DP 8 11.70059 2.459639 ppm 1 Standard Deviation 28.0679 0.81 Minimum 6.5697 1.88 Maximum 90.900 4.51 Skewness 2.67 1.75 SE Skewness 0.866 0.866 Skewness Test Non-normal Non-normal Kurtosis 7.3 3.64 SE Kurtosis 1.73 1.73 Kurtosis Test Non-normal Non-normal 99.0% t-statistic for UPL 3.00 3.00 99.0% UPL 111.711 200.8016

average in variability analysis 22.4605 Avg MDL 3x Max DL 99.0% UPL 111.711 ppm **MA CT Floor Limit**  **120.00 ppm**  **Existing Source Total Non-VC HA P determined by**  **Daily Samples** 

1) if the 3x RDL value is less than or equal to the calculated floor or emissions limit, use the calculated floor or emissions limit value for the rule making.

2) if the 3x RDL value is greater than the calculated floor or emissions limit, use the 3x RDL value as the floor or emissions limit adjusted for measurement variability for the rule making