Maricopa CountyAirQualityDepartmentJune3,2014OfficeofthcDirector\VIIim\Vi!ey1ietorOUINc,nh(.CntrnAve,nieAdinistratorDeborahJordenSuiteI5ou1’Iiut1j,85uu4OfficeoftheRegional9AirDivision(Il2-5fl6-6443-dik75HawthorneStreet502-372-5440—SanFrancisco,CA94105-3901DearMrs.Jorderi2013DataCertificationLetterThepurposeofthisletteristosatisfytheconditionsoftheCodeofFederalRegulationTitle40Pai:c58fordatacertification1.MaricopaCountyAirQualityDepartmentiscertifyingcertifiesthatthe2013ambientconcentrationdataandthequalityassurancedataarecompletelysubmittedtoAQS,andthattheambientdataareaccuratetothebestofourknowledgerakingintoconsiderationthequalityassurancefindings.2.AQSReportCertificationEvaluationandConcurrenceAMP600)forCO,NO2,SO2,ozone,lead,PM0andPM2.5monitoringdataIFyouhaveanyquestionpleasecontactBenDavisat(602)258-5155#221Sincerely,DennisDickersonActingDirectorCC.VFletcherCloverEPAR-9MeredithKurpiusEPAR-9EricC.MasseyADEQLindyBauer,MAGProtecüngourmostvital,naturalteSOUtcctntWW5’tiuilflc040gcyL.aUNITED STATES ENVIRONNENTA1 PROTECTION AGENCY

User ID RI)? CERTIFICATION S ALUATOE riND CONCURRENCE
Report Request ID: 1218418 Report Code: AXPSOO

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— _____

May. 30, 2014 GEOGRAPIUC SELECTIONS Tribal EPA 

# L Code State County Site Parameter POC City AQCR LIAR CESA CSA Region

P?OT0COL SELECTIONE 

### I Paratneter 

### I

——__________

— I Maricopa County Air QualLty 

### LCS5icbdh1 Parameter Method DuratioJ
cRITERIA

SELECTED OPTIONS Optton Type

— _______

Option Value MERGE PUP FILES YES

AGENCY ROLE CERTIFYING
DATE CRITERIA

Start L3ate End Date 20:3 2013

Selection Criteria Page 1

# Data Evaluation and Concurrence Report Summary 2014 

## Certification Year: 2013 

## Certifying Agency (CA): Maricopa County Air Quality (0643) 

## Pollutants in Report: Monitors Monitors Recommended for Monitors NOT Recommended Parameter Name Code Evaluated Concurrence by AQS for Concurrence by AQS Carbon monoxide 42101 12 12 0 Lead (TSP) LC 14129 2 0 2 Nitrogen dioxide (N02) 42602 4 4 0 Ozone 44201 18 18 0 PMlGTotalO-1OumSTP 81102 16 16 0 PM2.5

- 

## Local Conditions 88101 9 0 9 Sulfur dioxide 42401 2 2 0 

## PQAOs in Report: PQAO Name PQAO Code TSA Date Mancopa County Air Quality 0643 

# Summary of ‘N flags for all pollutants: AQS Cert. Agency Parameter Recommended Recommended 

# PQAO Code AQS Site-ID POC Reason forAQS Recommendation 0643 14129 04-013-4018 1 N Flow Rate Audit completeness < 

### 65%. 0643 14129 04-013-4018 1 N PQAO-Level Lead Analysis criteria not mel 0643 14129 04-013-4018 2 N PQAO-Level Lead Analysis criteria not met. 0643 88101 04-013-0019 1 N Flow Rate Audit completeness < 

### 65%. 0643 88101 04-013-0019 2 N Flow Rate Audit completeness < 

### 65%. 0643 88101 04-013-0019 3 N Flow Rate Audit completeness < 

### 65%. 0643 88101 04-013-9812 3 N PQAO-Level Collocation criteria not met. 0643 88101 04-013-1003 3 N PQAO-Level Collocation criteria not met. 0643 88101 04-013-1004 3 N PQAO-Level Collocation criteria not met. 0643 88101 04-013-2001 3 N PQAO-Level Collocation criteria not met. 0643 88101 04-013-4003 3 N PQAO-Level Collocation criteria not met. 0643 88101 04-013-4005 3 N PQAO-Level Collocation criteria not met. 0643 88101 04-013-0019 3 N PQAO-Level Collocation criteria not met. 

## Signature of Monitonng Organization Representative:

Page 1 of 1

# Data Evaluation and Concurrence Reportfor Gaseous Pollutants Certifying Year 2013 Certifying Agency Code Maricopa County Air Quality (0643) Parameter Carbon monoxide (42101) (ppm) ________



# PQAO Name Maricopa County Air Quality (0643) 

# QAPP Approval Date 07/14/2011 NPAP Audit Summary: Number ofValid Audits NPAP Bias Criteria Met 

### 1 0 

### V

oiData One Point Quality Check AnnuaIPE NPAP Concur. FIag AQS POC Monitor Mean Mm Max Exceed. Outlier Perc. Precision Bias Complete Bias Complete Bias PQAO Level QAPP Aqs Rec CA. Rec Epa Site ID Type Count Count Comp Criteria APPI-.j Flag Flag Eval. p4-013-0019 I SLAMS 0527 0.250 4.600 0 0 98 2.99 +1-2.38 100 0.38 100 0.00 Y V V 04-013-1003 1 SLAMS 0.322 0.250 1.800 0 0 99 1.57 .2.00 100 2.58 100 V V V 4-013-1004 1 SLAMS 0401 0.250 2.300 0 0 99 1.42 +1.81 100 3.33 100 V Y V J4-0I3-2001 1 SLAMS 0.412 0.250 1.900 0 0 99 1.90 +2.86 100 3.38 100 V V V l4-013-3002 SLAMS 0.398 0.250 2.800 0 0 99 2.09 -2.17 100 1.28 100 V V V 4-013-3003 1 SLAMS 0.376 0.250 1.800 0 0 99 1.39 +2.63 100 1.45 100 V V V p4-013-3010 1 SLAMS 0.520 0.250 3.300 0 0 99 1.90 +3.49 100 1.77 100 Y V Y p4-013-4003 1 SLAMS 0.499 0.250 3.500 0 0 99 0.82 +2.41 93 3.11 100 V V V {04-O134004 I SLAMS 0.352 0.250 2.100 0 0 97 1.38 

### 1.47 100 

### 2.38 100 V V V 1 SLAMS 0.399 0.250 2.200 0 0 99 1.91 +3.73 100 2.65 100 V V V p4-O134Ol0 I SLAMS 0.272 0.250 1.200 0 0 99 1.13 +1.61 93 2.75 100 V V V 3-4011 1 SLAMS 0.251 0.250 0.900 0 0 99 2.90 -2.94 100

- 0.29 100 Y V V

# Data Evaluation and Concurrence Reportfor Gaseous Pollutants Certifying Year 

## Certifying Agency Code Parameter PQAO 

## Name ‘QAPP 

## Approval 

## Date NPAP 

## Audit Summary:

Qs Sit. LU k4-ola-oolg 1 SLAMS )4—013..3002 6 SLAMS 04-013-3010 1 SLAMS 34-0I3-4011 I SLAMS 

## 2013

Number ofValid Audits

One Point Quality Check Precision Bias Complete

0 98

- 4.76 +1-4.02 100 2.06 0 97 388 +1-3 22 96

- 1.56 0 98 4.54 +/-3.79 100 3.39 0 98 16.28 +‘-8.75 100

- 1.24 

## Maricopa 

## County Air Quality (0643) Nitrogen dioxide (N02) (42602) (ppb) 

## Maricopa County Air Quality 

## (0643) 

## 07/14/2011

NPAP Bias Cxiteria Met 1 -2.6455

Routine flata POC Monitor Mean Mm Max Exceed. Outlier Perc. Type Count Count Cornp.J Y

18.0 1.0 69.0 19.7 1.0 63.0 24.6 0.0 81.0 8.4 0.0 40.0 I Annual PE Bias Complete NPAP[Concur.Flag Bias PQAO Level QAPP Aqs Rec CA Rec Epa Criteria 

# Appr.I Flag Flag Eval. 100

- 2.65 

### V I V 100 V V Y 100 V Y Y 100 Y V V 

## ---I

# Data Evaluation and Concurrence Report for Gaseous Pollutants Certifying 

# Year 2013 Certifying 

# Agency Code 

# Maricopa County Air Quality (0643) Parameter Ozone1201) (ppm) 

## PQAO 

# Name Maricopa County Air Quality 

## (0643) QAPP Approval Date 07/14/2011 NPAP Audit Summary: Number ofValid Audits NPAP Bias Criteria Met
4 2.08333 Y

Routine Data One Point Quality Check Annual PE NPAP Concur. Flag

- jQS POC Monitor Mean Mm Max Exceed. Outlier Perc. Precision Bias Complete Bias Complete Bias PQAO Level QAP Aqs Rec CA Rec Epa rite ID Type Count Count Comp. Criteria Appr. Flag Flag Eval. kJ4-o1a-o019 1 SLAMS 0.054 0.018 0.102 0 0 98 2.09 +1-1.64 100 0.14 100 2.78 Y Y Y

— — 24-013-1003 1 SLAMS 0.063 0.024 0097 0 0 99 1.90 +/-1.62 100 1.00 100 Y Y V 4-013-10O4 I SLAMS 0.057 0.014 0097 0 0 99 1.92 ÷1-1.51 100 1.97 100 V V V D4-013-1010 1 SLAMS 0.063 0.021 0.096 0 0 99 2.20 +1-1.78 100

- 0.03 100 V Y V p4-013-2001 1 SLAMS 0.060 0.023 0.092 0 0 99 1.82 +1-1.41 100 1.32 100 V Y V 34-013-2005 I SLAMS 0.059 0.028 0.096 0 0 98 2.29 +1-1.96 96 0.16 100 V V V )4-013-3002 1 SLAMS 0.052 0.015 0.096 0 0 99 1.76 +/-1.62 100

- 1.27 100 Y V V 34-013-3003 I SLAMS 0.053 0.017 0.098 0 0 99 2.26 +1-1.76 100

- 0.13 100 V Y V 4-0I3-4003 1 SLAMS 0.054 0.024 0.095 0 0 99 1.99 +/-182 96 1.42 100 V V Y J4-013-4004 1 SLAMS 0.059 0.019 0.088 0 0 99 1.71 +/-1.30 100

- 0.09 100 1.37 V V Y 14-013-4005 1 SLAMS 0.057 0.018 0.096 0 0 99 2.02 +1-1.79 100 0.76 100 V V V 34-013-4008 SLAMS 0.063 0.027 0084 0 0 99 2.59 +1-2.07 100

- 0.85 100 V V V )4-0I3-4010 1 SLAMS 0.058 0.021 0.090 0 0 98 1.64 +1-1.66 100 0.81 100 Y V V 4-013-4011 1 SLAMS 0.050 0.010 0.069 0 0 96 1.47 ÷1-1.17 100

- 1.82 100 V V V J4-013-9508 1 SLAMS 0064 0032 0.085 0 0 97 2.22 +1-1.95 100

- 121 100 V V Y 04-013-9702 1 SLAMS 0.057 0.024 0.102 0 0 99 2.30 +1-1.82 100 0.71 100 1.39 V V Y 4-013-97C4 1 SLAMS 0.057 0.026 0.089 0 0 96 2.82 +1-2.20 100 0.14 100 V V V D4-013-9706 1 SLAMS 0.060 0.025 0.093 0 0 99 2.97 +1-2.34 100

- 5.25 100 5.56 V V Y

# Data Evaluation and Concurrence Report for Gaseous Pollutants Certifying Year 2013 Certifying 

## Agency Code Maricopa County Air Quality (0643) Parameter

- 

## Sulfur dioxide (42401) 

## (ppb) __________________________________________



## [PQAO Name Maricopa 

# County Air Quality (0643) QAPP Approval Date 07/14/2011

NPAP Audit Summary: Number ofValid Audits NPAP Bias Criteria Met 

### 0 V

Routine Data OnePottQua5tyCheck rAnnuaiP 

## I NPAP 

# J Concur. Flag LQS 

### POC Monitor Mean 

### Mm Max Exceed. Outlier Perc. Precision 

### Bias Complete Bias Complete Bias PQAO Level QAP Aqs Rec CA Rec Epa tte ID Type 

# L Count Count Comp.

__ — Criteria Appr.i Flag Flag EvaL

- p4-013-3002 4 SLAMS 1.2 0.0 9.0 0 99 2.49 -4.03 100

- 2.02 100 

### Y 

### Y Y 4-013-98121 SLAMS 1.1 0.0 140 0 95 

### 2.62 -4.54

- 100

- 2.92 100

# Data Evaluation and Concurrence Report for Particulate Matter Certifying 

# Year:2013 Certifying Agency: Maricopa County Air Quality (0643) 

## PMIO Total 0-lOum STP (81102) CONTINUOUS PQAO 

# Name: Maricopa County Air Quality (0643) 

## Quality Assurance Project Plan Approval Date: 07/14/201 1 Monitors Summaries
Routine Data (uglm3) 

## Monitor Exceed.Outlier % Count Complete 1 Flow RateVenfication

0/ 

## Bias Complete - Flow 

### Rate Audit Concurrence Flag 

### % QAPP AQS Rec

## CA Rec EPA Bias Complete Appr. 

# a !2EVal. AQS Site ID 04-013-0019
04.01 

## 3-1 003 04-013-1004 

## 04-013-2001 04-013-3002 04-013-3003 104-013-3010 04-013-4003 04-013-4004 04-013-4005 04-013-4006 04-013-4009 04-013-4010 04-013-4011 O4-01 3-4016

04-013-9812 POC ]yg Mean Mm Max Count 1 

## SLAMS 36.59 -9.0 0 100 

## +1-1.01 100 -1.41 70 V Y 1 

## SLAMS 29.35 -8.0 0 

## 98 +1-156 100 

## -0.02 100 V Y 1 

### SLAMS 

## 26.44 -2.0 ** 

### 0 97 +1-2.08 

## 100 +0.63 70 V V 1 SLAMS 28.26 -5.0 0 98 +1-0.71 

## 100 -0.18 100 V Y 4 SLAMS 32.39 -5.0 ***** 

### 0 

### 97 +1-0.61 100 -0.12 100 V Y 1 

## SLAMS 26.46 -3.0 * 

### 0 

### 98 +1-0.73 

## 100 +027 100 V Y 1 SLAMS 

## 41.93 -5.0 ** 

### 0 

## 99 +J-2.75 

## 100 +2.06 70 V Y 

## I SLAMS 39.10 -7.0 ** 

### 0 

## 98 +1-0.77 

## 100 +0.06 100 

## V Y I SLAMS 28.95 -8.0 

### 0 

## 99 +1.76 100 +0.43 

## 100 V Y 1 SLAMS 28.77 -3.0 ** 

## 0 99 +1-109 

## 100 -0.15 100 V V 1 SLAMS 35.09 -8.0 0 98 -1.43 100 -1.01 100 V V I 

## SLAMS 42.89 -6.0 0 

## 97 ÷1-0.89 100 +0.61 100 V V I 

## SLAMS 25.33 

## -6.0 946.0 0 99 +/-0.93 100 -1.04 100 V V 1 SLAMS 40.77 -9.0 0 95 -1.00 100 -1.12 100 V Y 1 SPECIAL 24.17 -80 0 97 +/-0.76 100 +0.70 100 V V PURPOSE I 

## SLAMS 40.58 -8.0 0 98 +0.86 100 +0.88 100 V 

## V

# Data Evaluation and Concurrence Report for Particulate Matter

145 1 1 1 170 1 181 2 182 4 

# Vlonitors Summaries

Monitor AQS Site ID POCMethod 

# ] Mean 04-013-0019 1 145 

## SLAMS 10.17 04-013-0019 2 145 SLAMS 8.99 04-013-0019 3 

## 1811 SLAMS 10.63 170 04-013-1003 3 182 SLAMS 5.74 

## 04-013-1004 3 

## 170 SLAMS 8.07 04-013-2001 3 181 SLAMS 7.56 04-013-4003 3 182 SLAMS 9.64 04-013-4005 3 182 SLAMS 8.74 04-013-9812 3 181/ SLAMS 10.64

I 

## 182

-_____

-- - 

## 100 16.52 

## 18.18 Y 

## 0 N 

# o N 

# o N

Routine Data 

### (ugim3) Flow Rate Audit 

## Exceed. Outlier % Max Count Count Complete; Bias Complete 76.0 0 95 -1.24 50 16.0 0 73 -1.13 50J 433.6 0 89 -1.68 50 

## Y Y V V N V V N

N N NA.Y NIY Nj; Y Y 

## Certifying Year: 2013 Certifying Agency: Maricopa County 

## Air 

## Quality (0643) Parameter: PM2.5

- 

## Local Conditions (88101) QAO 

## Name: Maricopa County Air Quality 

## (0643) 

## Quality Assurance Project Plan Approval Date: 07/14/2011 Collocation Summary # Sites # Sites CV 

## Criteria Method # Sites Req Collocated Collocated Est CV UB Met 9

1 1 1 

## 0 0 0 

## PEP Summary # # Audited # PEP # PEP % Methods Methods Required Submitted Complete 4 0 8 

## 8 100 

## Criteria Bias Met? +0.62 V



## Mm

.6 4.0 

## -4.6 Collocation 

## PEP Concurrence Flag 

### % PQAO 

## PQAO QAPP 

## AQS RecCA 

## Rec EPA ________



## CV Complete Cnt. Me Crit. Me Appr. Eval. 18.18 100 

## V V N N

-10.0 173.8 0 98 +0.63 100 -2.0 464.4 0 97 -0.95 100 -4.2 456.0 0 99 +0.64 100 

## -4.8 787.0 0 96 +0.86 100 

## -5.4 244.0 0 98 +0.41 100 

## -8.6 586.0 

## 0 97 +0.49 100 V Y 

## Y Y 

## N N 

## V N Y N YN VN_

# Data Concurrence and Evaluation Report for Lead Certification Year 2013 Certifying Agency Name: Maricopa County Air Quality (0643) Lead (TSP) LC (14129) PQAO Nanie: Mancopa County Air Quality (0643) Quality Assurance Project Plan Approval Date: 07/14/2011 Collocation Summary: Number of Numberof Number Colloc Sites Actual Percent CV Criteria of Sites Required Colloc Sites Collocated Est CV MU Met 1 1 1 100 4.98 6.87 V Analysis Audit Summary: Number Number Percent Criteria Required Submitted Complete Bias Met 24 0 0 N Monitors Not Recoamended for Certification I Routine Data (ug/m’3) flow Rate Audit Collocation PEP Lead Certification Monitor Exceed. Outlier Percent Percent Percent PQAO PQAO Analysis QAPP AQS CA Rec EPA AQS Site-ID Type Mean Mm Max Count Count Camp. Bias Comp. CV IJB Comp. Cr8. Met Crit. Met Cnt. Met Appr. Rec. V Value Eval. 04-013-4018 1 SLAMS 0.029 0.006 0.071 0 Cl 95 -0.10 50 6.87 70 V V N V

- N 04-0134018 2 SLAMS 0.027 0.009 0.058 0 0 70 -2.32 70 V V N V N PEP Summary Number of Number of Number of Number of Methods PEP Audits Audits Percent Criteria Methods Audited Required Submitted Complete Bias Met 1 0 1 0 0 V