# Patent

## Title
Method of manufacturing color cathode ray tube screen

## Abstract

Methods of making an improved high performance x-ray system having a rotating anode therein are available. The anode includes an improved target/stem connection which reduces tube failure due to anode assembly imbalance. Methods of bonding a metallic target and a metal stem to form a composite rotating x-ray tube target are also available. In these procedures an insert of an alloy, for example, tantalum or its alloys , is placed between the target and the niobium-alloy stem and then bonded thereto to produce a composite x-ray tube target/stem having a high remelt temperature and bond strength which retains its balance throughout the manufacturing process and during x-ray tube operations.

## Background
This application is related to commonly assigned U.S. patent application Ser. No. 08/272,063 (RD-22,771) of Benz et al., filed Jul. 8, 1994, and U.S. patent application Ser. No. 08/272,064 (RD-23,774) of Eggleston et al., filed Jul. 8, 1994, and incorporated by reference herein.

The present invention relates to methods for making equipment for diagnostic and therapeutic radiology and, more particularly, to methods for making high performance targets used in x-ray generating equipment, such as computerized axial tomography (C.A.T.) scanners. More particularly, the invention is directed to methods for making high performance rotating x-ray tube anode structures having metal to metal bonding between the target and stem. Most particularly, it relates to methods for joining a molybdenum-alloy disk to a niobium-alloy anode stem portion wherein tantalum-alloy inserts are used as the bonding material.

X-ray tube performance can be affected by the balance of the anode assembly. Specifically, during x-ray tube manufacturing, it is important to be able to balance the anode assembly and have it stay balanced during completion of the manufacturing cycle and during operation of the x-ray tube. As the size of x-ray tube targets has increased to six and one half inch (6 1/2") and beyond, it has proved difficult to maintain this balance and thus, reduced manufacturing yields and shortened operational lives have been experienced. Field evaluation of failed x-ray tubes has indicated that the imbalance of the anode assembly has occurred in the region of the attachment of the target to the stem or shaft.

In producing new and improved targets for rotary anode x-ray application, it is not only necessary for the target/stem connection to survive a more rigorous environment in the x-ray tube but it must also be able to survive more rigorous manufacturing processes such as the vacuum firing at temperatures up to about 1500 degree(s) C. This requires that the improved connection provide the following benefits: properties of the TZM alloy which can lose significant strength at about 2000 degree(s) C. bond through the additional manufacturing steps such as vacuum firing to about 1500 degree(s) C. excursions during normal x-ray tube operation up to 1500 degree(s) C. for extended periods of time.

For a particular set of bonding metals, such as in diffusion bonding, to work under the above parameters, it must have certain inherent properties. The first would be that the metals do not have a eutectic or peritectic reaction with the TZM target layer. Ultimately, the bond metals used, such as in diffusion bonding, should form only a simple binary solid solution with the molybdenum in the TZM alloy.

A basic rule in bonding dissimilar materials is that for a bond to occur there must be some intermixing of the elements between the two materials. Also, for this bond to have significant strength, the gradation of intermixing should approximate that of a binary diffusion couple where the two materials diffuse together in equal portions.

Conventional stem/target connections, to the extent they may be viable in conventional x-ray imaging systems, face a much more severe test in connection with the use of graphite members in x-ray tubes used in medical computerized axial tomography a (C.A.T.) scanners. For the formation of images, medical C.A.T. scanner typically requires an x-ray beam of about 2 to 8 seconds duration. Such exposure times are much longer than the fractions-of-a-second exposure times typical for conventional x-ray imaging systems. As a result of these increased exposure times, a much larger amount of heat (generated as a by-product of the process of x-ray generation in the target region) must be stored and eventually dissipated by the rotating anode.

Recently, the problem related to anode assembly failure due to imbalance reached a critical point. Due to the tremendous stresses undergone by the larger diameter x-ray tubes during continuous operation, the average tube life had been approximately 30,000 scan-seconds, utilizing the conventional threaded stem, Belleville washer mechanical connection. Since approximately 20% of the failures were related to anode assembly imbalance, the need for methods of making an improved anode assembly having a more durable target/stem connection that would eliminate the imbalance while maintaining the effectiveness of the target became apparent. Such methods for making such an anode assembly desirably would provide sufficient balance during the operation life of the target while reducing significantly, if not eliminating, entirely anode assembly balance problems.

In carrying out the present invention in preferred forms thereof, we provide improved methods for making an x-ray anode assembly for use in x-ray tubes, such as those incorporated in diagnostic and therapeutic radiology machines, for example, computer tomography scanners. Illustrated embodiments of the resulting x-ray anode assembly made utilizing the invention disclosed herein, are in the form of an x-ray system having an x-ray tube which includes the improved anode assembly.

Each x-ray tube is normally enclosed in an oil-filled protective casing. A glass envelope contains a cathode plate, a rotating disk target and a rotor that is part of a motor assembly that spins the target. A stator is provided outside the tube proximate to the rotor and overlapping therewith about two-thirds of the rotor length. The glass envelope is enclosed in an oil-filled lead casing having a window for the x-rays that are generated to escape the tube. The casing in some x-ray tubes may include an expansion vessel, such as a bellows.

X-rays are produced when, in a vacuum, electrons are released, accelerated and then abruptly stopped. This takes place in the x-ray tube. To release electrons, the filament in the tube is heated to incandescence (white heat) by passing an electric current through it. The electrons are accelerated by a high voltage (ranging from about ten thousand to in excess of hundreds of thousands of volts) between the anode (positive) and the cathode (negative) and impinge on the anode, whereby they are abruptly slowed down. The anode, usually referred to as the target, is often of the rotating disc type, so that the electron beam is constantly striking a different point on the anode perimeter. The x-ray tube itself is made of glass, but is enclosed in a protective casing that is filled with oil to absorb the heat produced. High voltages for operating the tube are supplied by a transformer. The alternating current is rectified by means of rectifier tubes (or "valves") in some cases by means of barrier-layered rectifiers.

For therapeutic purposes--e.g., the treatment of tumors, etc.--the x-rays employed are in some cases generated at much higher voltages (over 4,000,000 volts). Also, the rays emitted by radium and artificial radiotropics, as well as electrons, neutrons and other high speed particles (for instance produced by a betatron), are used in radio therapy.

In accordance with one aspect of the present invention there is provided a method for making an X-ray system having an x-ray tube having a metallic target and a stem bonded together to result in a composite rotating x-ray tube target.

One aspect of the present invention includes a method for bonding a target to a stem for use in a rotating x-ray tube, comprising the steps of: pressing and sintering the target; forging the target at a temperature of about 1400.degree. C. to about 1700.degree. C.; providing a machined Ta-alloy insert; inserting the Ta-alloy insert into the target; stress relief annealing the combined target insert from a temperature of about 1500.degree. C. to about 1900.degree. C. for a sufficient time to diffusion bond the Ta-alloy insert into the TZM target; machining the combined target insert; providing an Nb-alloy shaft; inserting the Nb-alloy shaft into the target; and final heat treating the shaft/target combination from about 1200.degree. C. to about 1500.degree. C. for a time sufficient to diffusion bond the Ta-alloy insert and into the Nb-alloy shaft.

In another aspect of the present invention, the coefficient of thermal expansion of the stem material is greater than the coefficient of thermal expansion of the insert material which is in turn greater than the coefficient of thermal expansion of the target material.

In yet another aspect of the present invention, the insert of a tantalum based alloy is co-produced with the metallic target during manufacture of the target. The processing produces a diffusion bond between the insert and the target. It is desirable that the insert be a powder alloy compatible with, for example, the processing steps used in the manufacture of the target including: powder making, die pressing, sintering, forging, annealing, and coating or brazing to a graphite back. Such a material should be able to maintain a small grain size, high strength and good ductility during this combination of process steps, such as , for example, Ta. The insert material could also be chosen from the group comprising: Ta-10W (Ta, 10W); T-111 (Ta, 8W, 2Hf); T-222 (Ta, 9.6W, 2.4Hf, 0.01C); ASTAR-811C (Ta, 8W, 1Re, 1Hf, 0.025C); GE-473 (Ta, 7W, 3Re); Ta-2.5W (Ta, 2.5W); and Ta-130 (Ta with 50-200 ppm Y) .

The stem or stud is preferably manufactured from Nb or an Nb-based alloy, to take advantage of the combination of high strength and low thermal conductivity. The stem material could also be chosen from a group comprising: CB-752 (Nb, 10W, 2.5Zr); C129Y (Nb, 10W, 10Hf, 0.1Y); FS-85 (Nb, 28Ta, 11W, 0.8Zr); and C103 (Nb, 10, Hf, 1Ti, 0.7Zr). C103 is preferred.

In one possible method, the stem and insert are slightly tapered so that sufficient contact pressure between the two is established to facilitate the diffusion bonding therebetween. This pressure is preferably provided by press-fitting the stem into the target. The diffusion bonding between the stem and the target via the insert is preferably accomplished by vacuum annealing for a sufficient time (about 3 hours) at a sufficient temperature (preferably higher than 1150.degree. C.) and at a sufficient contact pressure (preferably greater than 10,000 psi) to effectuate diffusion bonding.

Accordingly, an object of the present invention is to provide a method for making an x-ray system including an improved x-ray tube having increased scan life.

Another object of the present invention is to provide a method for making an improved x-ray tube having a scan life of at least 40,000 scan-seconds.

A further object of the present invention is to provide a method for making an x-ray tube having an improved anode assembly which maintains proper balance during the life of the tube.

A still further object of the present invention is to provide a method for making a metal to metal bonded connection between the target and the stem that will prevent anode assembly imbalance for at least 40,000 scan-seconds.

Another object of the present invention is to provide a method for making a target stem attachment configuration that results in improved manufacturing yields.

A further object of the present invention is to provide a method for making an improved target/stem attachment having fewer parts.

Other objects and advantages of the invention will be apparent from the following description, the accompanying drawings and the appended claims.

FIG. 1a is a plan view of a representative x-ray system;

FIG. 1b is a sectional view with parts removed of the x-ray system of FIG. 1a;

FIG. 2 is a schematic representation of another representative x-ray system having an x-ray tube positioned therein;

FIG. 3 is a partial perspective view of a representative x-ray tube with parts removed, parts in section, and parts broken away;

FIG. 4 is a sectional view of one embodiment of an x-ray tube target/stem connection resulting from the method of the present invention;

FIG. 5a is a process diagram illustrating one prior art method of attaching a target to a stem; and

FIGS. 5-e are process diagrams illustrating the methods utilized to attach the target to the stem in the method of the present invention.

A representative x-ray system in which an x-ray tube made, in accordance with the present invention, by one preferred method thereof could be used, is illustrated as generally designated by the numeral 20 in FIGS. 1a, 1b and 2. As can be seen, the system 20 comprises an oil pump 22, an anode end 24, a cathode end 26, a center section 28 positioned between the anode end and the cathode end, which contains the x-ray tube 30. A radiator 32 for cooling the oil is positioned to one side of the center section and may have fans 34 and 36 operatively connected to the radiator 32 for providing cooling air flow over the radiator as the hot oil circulates therethrough. The oil pump 22 is provided for circulating the hot oil through the system 20 and through the radiator 32, etc. As shown in FIG. 1b, electrical connections are provided in the anode receptacle 42 and the cathode receptacle 44.

As shown in FIG. 2, the x-ray system 20 comprises a casing 52 preferably made of aluminum and lined with lead and a cathode plate 54, a rotating target disc 56 and a rotor 58 enclosed in a glass envelope 60. A stator 43 is positioned outside the glass envelope 60 inside the lead lined casing 52 relative to the rotor 58. The casing 52 is filled with oil for cooling and high voltage insulation purposes as was explained above. A window 64 for emitting x-rays is operatively formed in the casing 52 and relative to the target disc 56 for allowing generated x-rays to exit the x-ray system 20.

Referring to FIG. 3, there is shown the cathode 54 positioned inside the glass envelope 60. As is well known, inside the glass envelope there is a vacuum of about 10.sup.-5 to about 10.sup.-9 torr. The electricity generates x-rays that are aimed from the cathode filament 68 to the anode target or the top of the target disc 56. The target disc is conventionally connected to a rotating shaft 61 at one end by a Belleville nut 63 and by another nut at the other end 64. A front bearing 66 and a rear bearing 68 are operatively positioned on the shaft 61 and are held in position in a conventional manner. The bearings 66 and 68 are usually lubricated and are susceptible to failure at high operating temperatures.

A preload spring 70 is positioned about the shaft 61 between the bearings 66, 68 for maintaining load on the bearings during expansion and contraction of the anode assembly. A rotor stud 72 is utilized to space the end of the rotor most proximate the target 56 from the rotor hub 74. The bearings, both front 66 and rear 68, are held in place by bearing retainers 78 and 80. The rotor assembly also includes a stem ring 82 and a stem 84 all of which help to provide for the rotation of the rotor 58 with the target 56.

The temperature in the area of the filament 68 can get as high as about 2500.degree. C. Other temperatures include about 1100.degree. C. near the center of the rotating target 56, which rotates at about 10,000 rpm. Temperatures of the focal spot on the target 56 can approximate 3200.degree. C. and temperatures on the outside edge of the rotating target 56 approach about 1300.degree. C. The temperature in the area of the rotor hub 74 approaches 700.degree. C. and of the front bearing approaches 450.degree. C. maximum. Obviously, as one moves from the target 56 to the rotor 58 and stator 43, the temperature appears to decrease.

During operation of some x-ray systems having larger diameter targets, severe protocol users have maximized usage of the system by making as many scans at high peak power in as short a time as possible. One of the problems with utilizing any x-ray system in this continuous type of operation is the amount of heat that is generated, which may in fact destroy the bearings 66, 68, especially the front bearing 66.

If the x-ray tube target 56 and rotor 58 were allowed to continue to rotate at 10,000 rpm between scans, the bearings would wear out prematurely and cause the tube to fail. Thus, if it appears that there would to be more than 60 seconds between scans, the x-ray system operating control system software is programmed to brake the rotor by rapidly slowing it completely down to zero (0) rpm. However, when ready to initiate a scan, the control system software is programmed to return the target and the rotor to 10,000 rpm as quickly as possible. These rapid accelerations and brakes are utilized because, among other reasons, there are a number of resonant frequencies that must be avoided during the acceleration from zero (0) to 10,000 rpm and the brake from 10,000 rpm to zero (0) rpm. In order to pass through these resonant frequencies both immediately before a scan or a series of scans and after a scan or series of scans as fast as possible, the x-ray system applies maximum power to bring the target, or anode, to 10,000 rpm or down to zero (0) rpm in the least amount of time possible.

It should be noted that the x-ray tube target and rotor can be accelerated to 10,000 rpm from a dead stop in about 12 to about 15 seconds and slowed down at about the same rate. Vibration from the resonant frequencies is a problem, if the tube is allowed to spin to a stop without braking.

It has been found that during these rapid accelerations to 10,000 rpm and the immediate braking from 10,000 rpm to zero, stresses, mechanical as well as thermal, impact on the rotor 58 and the target/stem connection. These stresses may contribute to anode assembly imbalance which is believed to have caused premature failure in about twenty (20) percent of recent GE x-ray tube failures. It has been determined that these imbalance problems are most likely caused by changes that occur in the area of the target 56/stem 84 attachment.

Referring now to FIG. 4, therein is shown a representative target/stem combination made in accordance with the method of the present invention, generally designated by the reference numeral 100. The target/stem combination 100 comprises the target 102, preferably made of molybdenum alloy TZM, and, a focal track 104, operatively connected to the target by conventional metallurgical means for reflecting the x-rays generated by the cathode 68 through the window 64 (as shown in FIG. 2). An insert 106 for diffusion bonding to the stem 108 is co-processed with the target 102 during the manufacture thereof. The target is preferably a powder-metallurgy-alloy preferably compatible with all processes used for target manufacture including: powder making, die pressing, sintering, forging, annealing, and coating or brazing to a graphite back (not shown). The insert alloy should also be able to maintain a small grain size, high strength and good ductility during the combination of process steps utilized during the manufacture of the target which includes the insert being operatively connected to the internal portion of the target along seam 110. One such material is tantalum. The insert could also be selected from a group of materials comprising: Ta-10W (Ta, 10W); T-111 (Ta, 8W, 2Hf); T-222 (Ta, 9.6W, 2.4Hf, 0.01C); ASTAR-811C (Ta, 8W, 1Re, 1Hf, 0.025C); GE-473 (Ta, 7W, 3Re); Ta-2.5W (Ta, 2.5W); and Ta 130 (Ta with 50-200 ppm Y) or other metals which meet the above criteria and which can maintain the bond between the stem and the target for at least about 40,000 scan seconds.

One advantage of the materials for both the stem and the insert mentioned above is that the coefficient of thermal expansion of the stem material is greater than the coefficient of thermal expansion of the insert material which is in turn greater than the coefficient of thermal expansion of the target material. In order to achieve effective diffusion bonding between all three components, intimate contact between adjacent components at the temperature for diffusion bonding is required. The difference of the coefficient of thermal expansion stated above at diffusion bonding temperatures results in a compressive pressure between the components (stem, insert and target) thereby ensuring the necessary intimate contact.

The stem 108 is preferably made of Nb and more preferably from an Nb-based alloy chosen from the group comprising: CB-752 (Nb, 10W, 2.5Zr); C129Y (Nb, 10W, 10Hf, 0.1Y); FS-85 (Nb, 28Ta, 11W, 0.8Zr); C103 (Nb, 10, Hf, 1Ti, 0.7Zr), of which C103 is most preferred, or other metals which can maintain the bond between the stem and the target for at least about 40,000 scan seconds when used as described above. The stem end 112 which would make contact with the insert 106 is slightly tapered as is the insert 106. This tapering is to facilitate press fitting the stem 108 into the insert 106 so that sufficient pressure between the two for diffusion bonding is provided. The stem 108 may have a flange 114 which also diffusion bonds with insert 106. The stem may also have a hollow center 116 to reduce the conduction of heat down the stem to the rotor and bearings.

During the manufacture of the prior art target/stem combination (see FIG. 3), as illustrated in FIG. 5a, the first step 150 was to press and sinter the TZM target at about 2200.degree. C. in vacuum or at a conventional temperature. Next, the target was forged 152 at about 1400.degree. C. to about 1600.degree. C. After forging, a stress relief anneal 154 was performed at a temperature of about 1500.degree. C. to about 1900.degree. C. in a vacuum. After the stress relief anneal, the target was machined 156. Thereafter, as optional steps, the target was first labeled/inspected/cleaned 158 and then graphite was brazed 160 (at a temperature of about 1700.degree. C. to about 1800.degree. C.) to the TZM target. Then the target or the optional target/graphite combination was final machined 162 prior to final heat treatment 164 at which point the stem 72 was attached 166 to the target 56 by washer 63, as shown in FIG. 3.

Utilizing the insert 106 and stem 108 of the present invention, in one manufacturing method, as illustrated in FIG. 5b, the first step of the process is to press and sinter 180 the TZM target 102. Separately, the Ta alloy insert 106 is first formed 181 and then machined 182. Next, the target is forged 184 and the insert 106 is inserted 186 into the target 102 followed by the stress relief anneal step 188 at about 1500.degree. C. to about 1900.degree. C. for diffusion bonding of the Ta alloy to the TZM target. The combination is machined 190. Optionally, the combination can be labeled/inspected/cleaned 192 and graphite can be brazed 193 to the TZM target prior to the final combination being machined 194.

Separately, the shaft 108 is formed 196 of, preferably, an Nb-alloy, and is inserted 198 into the target 102 where it undergoes final heat treat 200 at about 1200.degree.-1500.degree. C. to form the target/shaft combination 100.

Alternatively, the Nb-alloy shaft, after insertion 198 into the target, is EB welded 202 to the target to the form the target/stem combination 100, prior to final heat treat 200.

In another alternative method, the Nb-alloy shaft is coated 204 and then inserted 198 into the target 102 and the combination then undergoes final heat treatment 200.

In yet another possible method, as illustrated in FIG. 5c, the machined 194 target undergoes the final heat treat 200 at 1200.degree.-1500.degree. C. and is then EB welded 202 to the shaft 108.

In an alternate method, the first steps are the same as the previous methods including the forging 184 of the target. Next, a coated Ta-alloy insert is machined and inserted 210 into the target followed by the stress relief anneal 188 to diffusion bond the Ta-alloy insert to the TZM, as explained above.

In another alternative method, as illustrated in FIG. 5d, the target is pressed and sintered 180 and the Ta-alloy insert is separately machined and press fitted 212 into the target. The combination is then forged 222 at 1400.degree.-1700.degree. C. It is then stress relief annealed 188 at 1500.degree. C. to approximately 1900.degree. C., machined 194, and then an Nb-alloy shaft 108 is inserted according to one of the four situations described below.

In yet another alternative method, as illustrated in FIG. 5e, the target is pressed and sintered with the insert 214 in a single step. The combination is then forged 222 at 1400.degree.-1700.degree. C. It is then stress relief annealed 188 at 1500.degree. C. to approximately 1900.degree. C., machined 194, and then an Nb-alloy shaft 108 is inserted according to one of the four situations described below.

As shown in FIGS. 5b-e, after the target/insert combination has been final machined 194, one of the following four processes is performed thereon.

After the formation 181 of the preferably, Nb-alloy shaft, the shaft is inserted 198 into the target and the combination then undergoes final heat treat 200 at 1200.degree. C.-1500.degree. C. in order to diffusion bond the Ta-target insert to the Nb-shaft.

An alternative method of attaching the formed shaft to the target alloy combination is to EB weld 202 the Nb-alloy shaft to the target and thereafter heat treat 200 the combination at the temperature range mentioned above to complete the diffusion bonding between the Ta and the Nb. A third method is, as shown in FIG. 5c, after the Nb-alloy shaft is formed 181, to final heat treat 200 at the temperature ranges mentioned above and then the Nb-alloy shaft is EB welded 202 to the target followed by a machining step 201.

As illustrated in FIG. 5c, a final alternative method is, after the forming of the Nb-alloy shaft 181, the shaft is coated 204 and thereafter inserted 230 into the target followed by final heat treat 200 at the temperature ranges mentioned above for the diffusion bonding of the Ta to the Nb via the coating. In all of these possible methods, the final step is machining 201, if necessary.

Of the processes mentioned above, there are certain advantages to processing the materials in specific orders. For example, an advantage of co-sintering the target and the insert is that the powders of the two alloys will intermix near the interface. This will provide a larger surface area for interdiffusion between the alloys. Sintering, which is performed at 2200.degree. C. provides additional interdiffusion because of the higher temperature.

An advantage of inserting the insert into the target before forging is that the mechanical work resulting from the forging increases the surface area between the parts. This particular process will also break up the contacting surfaces and create new interface surfaces which should enhance interdiffusion.

An advantage of inserting the insert into the target after forging is that heating of the target, which is required for the forging operation, might be easier if the insert is not forged with the target.

An advantage of inserting the stem into the target/insert combination prior to heat treatment is that the diffusion bonding, upon exiting heat treatment, creates the final bond. Thus, no additional steps or processes are required to ensure the fastening of the stem to the insert/target combination.

An advantage of electron beam welding the stem into the insert before heat treatment is that the materials used provide for a strong weld, which will assist in overcoming any weaknesses in the diffusion bond. Also, electron beam welding before heat treatment is believed to assist in the correct location of the stem in the target.

An advantage of electron beam welding the stem into the insert after heat treatment is that the relative position of the stem and the insert will not be altered by the high temperature exposure. Additionally, the stem material would not be weakened by the high temperature exposure.

As mentioned above, at least one of the possible processes requires that an insert Ta-alloy be coated. The term "coating" in this case is used to refer to a "consumable braze" or a "diffusion enhancer." In this particular method, a thin layer of metal between the two contacting surfaces (e.g., a shaft of, for example, C103 and an insert of, for example, Ta-10W can enhance the interdiffusion between the two metals. If the Nb and Ta-alloy surfaces are placed in contact at elevated temperatures, interdiffusion occurs. Nb atoms diffuse into the Ta-alloy and Ta atoms diffuse into the Nb-alloy. However, both Ta and Nb alloys will diffuse faster in Ti (as an example) than Ta or Nb. If a thin layer of Ti is placed between the contacting surfaces, both Ta and Nb atoms will rapidly diffuse into the Ti coating and intermingle. The Ti atoms will concurrently diffuse into the Ta-alloy and Nb-alloy metals. As the Ti diffuses away, it leaves a region of mixed Ta and Nb-alloys, thereby enhancing the diffusion bond that could be accomplished with the two alloys alone. The key to the use of the coating is that it must be thin enough so that after a reasonable amount of time most of the coating will have diffused into the two base metals (e.g. Nb and Ta-alloy). Also, the rate of diffusion of the Ta and Nb in the coating layer, for example Ti, must be higher than in Nb and Ta, respectively.

In one specific experiment of the above coating on a diffusion couple, after approximately 3 hours at about 1400.degree. C. with a 1 .mu.m Ti coating thickness, no Ti-rich regions existed. Where the Ti coating was placed, a region of Ta, Nb and Ti now exists e.g. while coating may have been 1 .mu.m in thickness, after diffusion bonding, no Ti-rich (i.e. percent Ti>50%) region exists, but Ti is present at some level more than 10.mu.m from the original interface.

Specifically, when bonding C103 to Ta10W with no coating at 1300.degree. C. for about three hours, it was found that there was less than 4 microns of interdiffusion. However, when bonding C103 to Ta-10W with a 1 micron Ti coating at 1300.degree. C. for about three hours, it was found that there was about 10 microns of interdiffusion.

Examples of potential coating materials includes: titanium; niobium-titanium alloys; aluminum; and titanium-vanadium-zirconium alloys (zirconium at less than 30 atom percent).

While the above list of potential coatings should appear adequate, any coating material should provide for the enhanced diffusion of Nb, Ta and into the coating material. Any coating material when combined with Nb, Ta and Mo should remain solid after heat treatment conditions. Any elements in the coating should have at least some level of solubility in Nb, Ta and Mo alloys or other materials chosen for the stem, the insert and the target, respectively.

After the above process, the connection along seam 110 and between walls 120, 121 and 122 provides for a unitary construction of target 102 and stem 106 which is more resistant to structural changes during the stressing caused by the above mentioned severe protocol uses. Since it has been determined that the imbalance problems were, most likely, caused by changes that occur in the area of the target/stem attachment, the illustrated methods of making and resulting constructions are believed to reduce the relative changes in position between the stem and target and thereby significantly reduce the imbalance problems.

While the methods disclosed herein constitute preferred embodiments of the invention, it is to be understood that the invention is not limited to these precise methods, and that changes may be made therein without departing from the scope of the invention which is defined in the appended claims.

## Claims

1. The method for bonding a target to a stem for use in a rotating x-ray tube anode comprising the steps of: 1400.degree. C. to about 1700.degree. C.; 1500.degree. C. to about 1900.degree. C.; to about 1500.degree. C. wherein a combined stem target is interdiffused to each other wherein the coefficient of thermal expansion of the stem material is greater than the coefficient of thermal expansion of the insert material which is in turn greater than the coefficient of thermal expansion of the target material.

2. The method of claim 1, wherein the shaft is EB welded to the target prior to the final heat treat step.

3. The method of claim 1, wherein the shaft is EB welded to the target after the final heat treat step.

4. The method of claim 1, wherein the shaft is coated prior to insertion into the target and before the final heat treat step.

5. The method of claim 4, wherein the coating comprises a material selected from the group consisting of: titanium-vanadium-zirconium alloys (zirconium at less than 30 atom percent) placed between the contacting surfaces.

6. The method of claim 4, wherein the coating is sufficiently thin so that after a sufficient temperature exposure, most of the coating has been diffused into the two base metals.

7. The method of claim 1, wherein the insert comprises a Ta-alloy.

8. The method of claim 7, wherein the insert comprises a material chosen from the group consisting of: ASTAR-811C (Ta, 8W, 1Re, 1Hf, 0.025C); GE-473 (Ta, 7W, 3Re); Ta-2.5W (Ta, 2.5W); and Ta-130 (Ta with 50-200 ppm Y) a Ta-alloy.

9. The method of claim 1, wherein the stem comprises a Nb-alloy.

10. The method of claim 9, wherein the stem comprises a material chosen from the group consisting of: 11W, 0.8Zr); and C103 (Nb, 10, Hf, 1Ti, 0.7Zr).

11. A method for bonding a target to a stem for use in a rotating x-ray tube, comprising the steps of: 1700.degree. C.; about 1500.degree. C. to about 1900.degree. C.; to about 1500.degree. C. for a time sufficient to diffusion bond the insert into the target and into the shaft wherein the coefficient of thermal expansion of the stem material is greater than the coefficient of thermal expansion of the insert material which is in turn greater than the coefficient of thermal expansion of the target material.

12. The method of claim 11, wherein prior to forging the target at 1400.degree. C. to 1700.degree. C., the insert is inserted and press fitted into the target.

13. The method of claim 11, wherein the shaft is EB welded to the target prior to the final heat treat step of claim 1.

14. The method of claim 11, wherein the shaft is EB welded to the target after the final heat treat step of claim 1.

15. The method of claim 11, wherein the insert is coated prior to insertion into the target and before the stress relief anneal step.

16. The method of claim 15, wherein the coating comprises a material is selected from the group consisting of: titanium-vanadium-zirconium alloys (zirconium at less than 30 atom percent) placed between the contacting surfaces.

17. The method of claim 16, wherein the coating is sufficiently thin so that after a sufficient temperature exposure, most of the coating has been diffused into the two base metals.

18. The method of claim 11, wherein the shaft is coated prior to insertion into the target and before the final heat treat step.

19. The method of claim 18, wherein the coating comprises a material selected from the group consisting of: titanium-vanadium-zirconium alloys (zirconium at less than 30 atom percent) placed between the contacting surfaces.

20. The method of claim 19 wherein the coating is sufficiently thin so that after a sufficient temperature exposure, most of the coating has been diffused into the two base metals.

21. The method of claim 1, wherein the insert comprises a Ta-alloy.

22. The method of claim 21, wherein the insert comprises a material chosen from the group consisting of: ASTAR-811C (Ta, 8W, 1Re, 1Hf, 0.025C); GE-473 (Ta, 7W, 3Re); Ta-2.5W (Ta, 2.5W); and Ta-130 (Ta with 50-200 ppm Y) a Ta-alloy.

23. The method of claim 11, wherein the stem comprises a Nb-alloy.

24. The method of claim 23, wherein the stem comprises a material chosen from the group consisting of: 11W, 0.8Zr); and C103 (Nb, 10, Hf, 1Ti, 0.7Zr).

25. The method of claim 11, wherein a diffusion enhancer is placed between the contacting surfaces.

26. The method of claim 25, wherein the diffusion enhancer is sufficiently thin so that after a sufficient amount of time, most of the coating has been diffused into the two base metals.