# Patent

## Title
Silicone water block for electrical cable

## Abstract

Du Pont Impact tester was used. The test was carried out at 20.degree. C., at an impact load of 1 kg using a 1/2 inch diameter hammer, at a drop height of 20 cm.

## Background
## Claims

1. A photo-curable coating composition consisting essentially of (a) a photo-curable monomer or polymer having a plurality of ethylenically unsaturated groups in the molecule, and (b) an adduct of a polyisocyanate compound, an isocyanate group-blocking agent and a photo-polymerizable alcohol having at least one ethylenically unsaturated group; said component (a) being free of free or blocked isocyanate groups; wherein the total number of ethylenically unsaturated groups possessed by said components (a) and (b) is at least 4, said composition being photo-curable by activating radiation and subsequently further curable by heat to form a finished film.

2. The photo-curable coating composition of claim 1 wherein said photo-curable monomer or polymer (a) has at least one hydrogen atom active with respect to isocyanate.

3. The photo-curable coating composition of claim 1 wherein the ratio of the number of blocked isocyanate group to the number of ethylenically unsaturated group of said component (b) ranges between 0.01 and 10.

4. The photo-curable coating composition of claim 1 wherein the proportion of said components (a) and (b) is adjusted so that the blocked isocyanate equivalent ranges between 0.02 and 5 per 1,000 g of their mixture on a dry basis.

5. The photo-curable coating composition of claim 1 further comprising a photo-sensitizer, and a volatile solvent free of active hydrogen atoms.

6. The photo-curable coating composition of claim 1 which is opaque to activating light.

7. A composition of claim 1 wherein said polyisocyanate compound is derived from dimethylenediisocyanate, tetramethylenediisocyanate, hexamethylenediisocyanate, dimer acid diisocyanate, isophoronediisocyanate, xylylenediisocyanate, tolylenediisocyanate, polymers of these isocyanate compounds, their condensates with water, or their adducts with trimethylolethane or trimethylolpropane.

8. A composition of claim 7 wherein said polyisocyanate is blocked by a secondary or tertiary alcohol, an active methylene compound, an oxime, a lactam, a phenol or a heterocyclic hydroxyl compound.

9. A composition of claim 8 wherein said polymerizable unsaturated alcohol is 2-hydroxyethyl acrylate, hexanediol monoacrylate, glycerol diacrylate, pentaerythritol triacrylate, a methacrylate corresponding to these esters, allyl alcohol, or a bisphenol A epoxy resin/acrylic acid adduct.

10. A composition of claim 1, wherein component (a) is a bisphenol A epoxy resin/acrylic acid adduct, diallyl phthalate, bis(2-acryloxyethoxyethyl)phthalate, trimethylpropane triacrylate or pentaerythritol tetracrylate.

11. A composition of claim 8, wherein the isocyanate group blocking agent is isopropanol, tertiary butanol, dialkyl malonate, acetylacetone, alkyl acetoacetate, acetoxime, methyl ethyl ketoxime, cyclohexanone oxime, .epsilon.-caprolactam, 3-hydroxy-pyridine, 8-hydroxyquinoline, or 8-hydroxyquinaldine.

12. A composition of claim 8, wherein the isocyanate group blocking agent is phenol, chlorophenol, cresol, p-tertbutylphenol, p-sec-butylphenol, p-sec-amylphenol, p-octylphenol, or p-nonylphenol.

13. A method of forming a protective coating on a surface which comprises the steps of applying the photo-curable coating composition of claim 1 on said surface to form a film, exposing the film to the irradiation of light having a wavelength from 200 to 500 nm for a sufficient length of time to cure the film, and heating the film at a temperature above 100.degree. C. for a period over 10 seconds.

14. A method of claim 13 wherein the photo-curable coating composition of claim 15 is used.

15. A method of forming a protective coating on a surface comprising the steps of applying the photo-curable coating composition of claim 2 on said surface to form a film, exposing the film to the irradiation of light having a wavelength from 200 to 500 nm for a sufficient length of time to cure the film, and heating the film at a temperature above 100.degree. C. for a period over 10 seconds.

16. A method of forming a protective coating on a surface comprising the steps of applying the photo-curable coating composition of claim 3 on said surface to form a film, exposing the film to the irradiation of light having a wavelength from 200 to 500 nm for a sufficient length of time to cure the film, and heating the film at a temperature above 100.degree. C. for a period over 10 seconds.

17. A method of forming a protective coating on a surface comprising the steps of applying the photo-curable coating composition of claim 4 on said surface to form a film, exposing the film to the irradiation of light having a wavelength from 200 to 500 nm for a sufficient length of time to cure the film, and heating the film at a temperature above 100.degree. C. for a period over 10 seconds.

18. A method of forming a protective coating on a surface comprising the steps of applying the photo-curable coating composition of claim 5 on said surface to form a film, exposing the film to the irradiation of light having a wavelength from 200 to 500 nm for a sufficient length of time to cure the film, and heating the film at a temperature above 100.degree. C. for a period over 10 seconds.