# Patent

## Title
Wet type sliding apparatus

## Abstract

This is a divisional of application Ser. No. 07/688,022, filed Apr. 19, 1991, now abandoned, which in turn is a C.I.P. of Ser. No. 07/512,041, filed Apr. 26, 1990, now abandoned.

## Background
This invention relates to the use of sulfonimide cure catalysts in combination with aminoplast crosslinkers and their use in curable compositions.

Alkyl and aryl sulfonic acids have found utility in industry as "strong acid" catalysts capable of activating acid-sensitive curable compositions to produce cured coatings, moulded articles or adhesives.

U.S. Pat. Nos. 3,927,141 and 4,118,437 disclose powder coating compositions containing alkoxyalkyl groups carrying aminoplasts which are cured with an acid catalyst including sulfonic acids, and U.S. Pat. No. 4,064,191 discloses organic solvent-based compositions thereof.

It is well known in the art that strong acids such as sulfonic generally favor rapid cure. However, it is suggested in U.S. Pat. No. 4,031,036, that acid strength alone does not always determine effectiveness of a catalyst in complex reactions. In many cases, strong acids produce less than "smooth" surfaces having a "sandpaper-like" appearance. Furthermore, because of the extreme reactivity of sulfonic acid catalysts, curable powders containing them have been unsatisfactory because of poor package stability. The poor package stability is associated with room temperature crosslinking of the curable powders catalyzed by the excessively strong sulfonic acid catalysts. As a result, the low temperature reaction often causes clumping and sintering or fusing of the powdered resin. These are undesirable because they impair fluidization of the powder during application contributing to the production of non-uniform coatings with diminished gloss.

As a partial solution for low temperature crosslinking, U.S. Pat. Nos. 4,510,290 and 4,281,075 disclose the use of latent-reactive sulfonic acid catalysts such as benzoin tosylates and beta-hydroxy tosylates, respectively. The chemistry of the beta-hydroxy tosylate latent acid catalysts is described in Ind. Eng. Chem. Prod. Res. Dev., 22, 440 (1983). Even though latent catalyst approach improves the shelf-life of the cure catalyst-containing powder coating compositions, the overall film properties and appearance of the cured films have been no better than non-latent sulfonic acid catalyzed systems because the active catalyst in both systems is the same: a sulfonic acid.

Powder coating technology is dominated by isocyanate crosslinked and epoxide crosslinked reaction systems which are of relatively high cost. Improved crosslinking systems based on aminoplast resins when used in combination with solid components offer cost attractive alternative powder coating formulations.

This invention provides sulfonimides as improved catalysts useful in the curing of aminoplast crosslinkable resin compositions with particular utility in powder coatings/formulations.

This invention is a curable composition comprising: groups, and crosslinking agents.

This invention is also a crosslinker/catalyst combination suitable for admixture with an aminoplast crosslinkable resin. The crosslinker/catalyst combination comprises:

This invention is also a catalyst/polyfunctional material combination suitable for admixture with aminoplast resins, said combination comprising: crosslinking agents.

This invention is also an improved method of coating substrates by applying to said substrates the curable coating compositions of the invention.

This invention is also a crosslinked article or coating formed from heat-activating the curable compositions of the invention.

The curable composition of this invention comprises: containing at least 2 crosslinkable groups, crosslinking agents,

The novel cure-catalysts of this invention are represented by the Formula:

wherein each of the R groups is, independently: of 1 to 20 carbon atoms, or mixtures thereof; or heterocyclic aromatic rings substituted by R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 groups, wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 groups are the same or different groups selected from a group consisting of hydrogen, fluoro, alkyl, fluoroalkyl, aryl, haloaryl, carboxy, mercapto, vinyl, chloro, bromo, cyano, nitro, sulfonyl, acyl, alkoxycarbonyl, alkoxy, perfluoroalkoxy, hydroxy, amino, acylamino, alkoxycarbonylamino, carbamoyl, aminocarbonyl, N-alkyl aminocarbonyl, and N,N-dialkylaminocarbonyl groups; or meaning as the alkyl and aryl groups (1) and (2) above; and

wherein the Z group of the formula sulfonimides as described in DeChristopher, P. J., et. al., J. Amer. Chem. Soc., Vol. 91 (9), p. 2384 (1969) and Curtis, V. A., et. al., Tetrahedron Lett., Vol. 12, p. 199 (1982).

Alkyl or aralkyl groups of (6) which are preferred as the substituent Z are those containing at least one hydrogen at the position beta to the point of attachment of the alkyl group to the nitrogen of the sulfonimide such that upon nucleophilic deacylation reaction of the acylated sulfonimide or upon heat-activated or base-catalyzed elimination or nucleophilic displacement reaction of the alkylated sulfonimide, an unsubstituted sulfonimide is obtained which sulfonimide is represented by the following formula:

Particularly useful are the sulfonimide cure-catalysts containing both alkyl and aryl groups such as the ortho- meta- and para- isomers of methyl tolyl sulfonimide, or mixtures thereof, the para isomer being preferred, and represented by the formula: ##STR1## wherein the alkyl group imparts solubility and the aryl group contributes to the higher melting point. This combination of substituents produces a solid cure catalyst which is well suited to powder coatings applications.

Diarylsulfonimides are similarly well suited for powder coatings applications because of their higher melting point. Particularly useful in this invention are the para-substituted diarylsulfonimide, having Formula: ##STR2## wherein X is selected from a group consisting of hydrogen, chloro, methyl, nitro, alkyl, amino, cyano, alkoxycarbonyl, carboxyl, acyl, N-alkylaminocarbonyl, and N,N-dialkylaminocarbonyl groups. In the above substituted diarylsulfonimide structure each X may also be substituted in the ortho- or meta- position.

Sulfonimides containing a plurality of imide groups are also usable as catalysts in the compositions of this invention, and can be of two types:

wherein n groups of the .paren open-st.R--SO.sub.2 NH--SO.sub.2 .paren close-st. units may be the same or different, and the R group in each of the n units is independently selected from the group consisting of: atoms; or carbocyclic or heterocyclic aromatic rings substituted by R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 groups, wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 groups are the same or different groups selected from a group consisting of hydrogen, fluoro, alkyl, fluoroalkyl, aryl, haloaryl, carboxy, mercapto vinyl, chloro, bromo, cyano, nitro, sulfonyl, acyl, alkoxycarbonyl, alkoxy, perfluoroalkoxy, hydroxy, amino, acylamino, alkoxycarbonylamino, carbamoyl, aminocarbonyl, N-alkylaminocarbonyl, and N,N-dialkylaminocarbonyl groups; or same meaning as the alkylene and arylene groups (a) and (b) above; and wherein n is 2 or greater; and

wherein P is either a polyfunctional group or a polymer backbone of a molecular weight greater than 500, and R is an alkyl or aryl group of 1 to 20 carbon atoms, and n is 2 or greater.

The amine salts of the sulfonimides of this invention are also usable as latent-reactive cure catalysts in the compositions of this invention. They are represented by the formula: ##STR3## wherein the R groups are, independently: a. a linear, branched, or cyclic alkyl, or fluoroalkyl group of 1 to about 10 carbon atoms, or mixture thereof; or or heterocyclic aromatic rings substituted by R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 groups, wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 groups are the same or different groups selected from a group consisting of hydrogen, fluoro, alkyl, fluoroalkyl, aryl, haloaryl, carboxy, mercapto, vinyl, chloro, bromo, cyano, nitro, sulfonyl, acyl, alkoxycarbonyl, alkoxy, perfluoroalkoxy, hydroxy, amino, acylamino, alkoxycarbonylamino, carbamoyl, aminocarbonyl, N-alkylaminocarbonyl, and N,N-dialkylaminocarbonyl groups, or meaning as the alkyl and aryl groups in (a) and (b) above.

One, two, or all three R groups of the amine part of the sulfonimide salts can be replaced with one, two or three hydrogen atoms to give secondary ammonium, primary ammonium, or ammonium salts, respectively. Like tertiary amine salts, these are usable in the compositions of the invention as latent-reactive cure catalysts.

The R group in the amine salts above can further be independently interrupted and substituted wtih heteroatoms or heteroatom-containing groups to produce amine salts such as those derived from N,N-dimethylethanolamine, triethanolamine, morpholine, 2-amino-2-methyl-1-propanol, N,N-dimethyl ethanolamine, N-methyl diethanolamine, ethanolamine, diethanolamine, and the like.

The preferred amine salts of the invention are derived from relatively low molecular weight amines which are sufficiently volatile to facilitate the expulsion of the free amines from the cured coatings either before or during the curing process.

Examples of the volatile amines are triethanolamine, diisopropylamine, triisopropylamine, in addition to the heteroatom-containing amines recited above.

The sulfonimide cure catalyst of this invention may take a latent reactive form such as an N-sulfonyl-substituted saccharin which is later reacted with a nucleophile such as ammonia, primary or secondary alcohols, mercaptans, or amines. For example: ##STR4## where, R is an alkyl or aryl group such as shown in the reference: Imai, Y. at. a., Nippon Kagaku Kaishi, No. 1, p. 111 (1982).

The molecular weight of the sulfonimide cure catalyst used in the crosslinker/catalyst ingredient is preferably high enough to make the sulfonimide catalyst a solid at ambient temperatures, and more preferably a solid at above ambient temperatures (viz., about 40.degree. C.) such as those which may be encountered in commercial in-plant storage or transportation environments.

The sulfonimide catalysts are generally prepared by the reaction of sulfonyl chlorides with a sulfonamide in the presence of a base. Typical preparatory methods are taught in U.S. Pat. Nos. 3,052,656 and 4,510,324, Federal Republic of Germany Patent Nos. 765,789, 1,265,157 and 1,235,300, and DDR Patent No. 9132.

Crosslinking agents of this invention are aminoplast crosslinkers commonly used in coatings, mouldings, and adhesives. The term "aminoplast" is defined herein as a class of resins prepared by the reaction of an amino group-containing compound and an aldehyde.

The reaction product of amino group-containing compounds and aldehydes is often reacted further with an alcohol to produce partially or fully alkylated derivatives. These derivatives are included in the "aminoplast" definition given above.

The term "aminoplast" as used in the context of this invention also includes phenoplasts (phenolic resins), specifically, the resole-type resins which are the reaction product of phenol and an aldehyde and have the further property of containing pendant hydroxymethyl or alkoxymethyl groups. Resole resins and resolated Novolak resins are examples of phenoplasts suitable as crosslinking agents (see, Kirk-Othmer, "Encyclopedia of Chemical Technology", Vol. 17, 3'd Edition, pages 384-390 (1985) and "Encyclopedia of Polymer Science and Engineering", Vol. 11, 2'd Edition, edited by Mark, Bikales, Overberger, and Menges, (1985) pages 45-57. Commercially avaiable phenoplasts are Bakelite.RTM. Phenolic Baking Resins sold by Union Carbide Company, Danbury, Conn., (U.S.A.).

In the preparation of aminoplasts from amino group-containing compounds and aldehydes and subsequent alkylation, dimeric and oligomeric products resulting from self-condensation reaction are often obtained. These oligomeric self-condensation products are also included in the "aminoplast" definition given above.

The aminoplast crosslinking agents of this invention are represented by the formula:

wherein the A group in A--(R).sub.n is an n-functional polyamino anchor molecule connected to n(R) groups via the nitrogens and includes the following systems represented by the formulae: ##STR5## wherein R.sup.1 and R.sup.2 are independently, hydrogen, alkyl or aryl groups of 1 to 10 carbon atoms; ##STR6## wherein R.sup.3 is an aliphatic or cycloaliphatic alkyl group, of 1 to 10 carbon atoms, such as methyl, ethyl, butyl, cyclohexyl and the like; or tolyl, naphthyl, and the like; or cumyl, and the like; ##STR7## wherein R is an alkylene or an arylene of 1 to 10 carbon atoms; ##STR8## (i) homopolymers containing acrylamide units of the formula: ##STR9## wherein R is hydrogen or alkyl and m is greater than 2, and copolymers thereof; ##STR10## (o) homopolymers containing carbamate units of the formula: ##STR11## wherein R is hydrogen or alkyl, and m is greater than 2, and copolymers thereof; about 10 carbon atoms, or a crosslinkable group such as --CH.sub.2 OH and --CH.sub.2 OR.sup.4 wherein R.sup.4 is an alkyl group of 1 to about 10 carbon atoms or an aminoplast group-containing oligomeric group provided that the total number of the crosslinkable groups per each aminoplast crosslinking agent is at least 2, and preferably more than 2; and anchor molecule A, and is 2 or greater.

The preferred crosslinking agents of this invention are substantially fully etherified, substantially fully methylolated, substantially monomeric aminoplast crosslinkers commonly used in coatings industry. They are characterized by having at least 2, preferably more than 2 crosslinkable groups per crosslinker molecule. It is well known in the art that the minimum number of crosslinkable functional groups required to effect crosslinking is 2 provided that the aminoplast-reactive polyfunctional material has more than 2 functional groups per each molecule. If, on the other hand, the aminoplast-reactive polyfunctional material has only 2 functional groups per each molecule, then each aminoplast crosslinking agent is required to have more than two crosslinkable groups per crosslinker molecule to be capable of producing a crosslinked network.

The most preferred aminoplast crosslinking agents of the invention are selected from a group consisting of substantially fully etherified, substantially fully methylolated, substantially monomeric glycoluril, melamine, benzoguanamine, cyclohexanecarboguanamine, urea, substituted linear and cyclic ureas, and mixtures thereof.

In addition to the substantially fully etherified, substantially monomeric amine-aldehyde aminoplast crosslinking agents described above, the non-etherified or partially etherified substantially fully methylolated or partially methylolated monomeric and oligomeric aminoplasts are also usable in the compositions of this invention. The unetherified or partially etherified aminoplasts generally cure faster than the fully methylolated and etherified aminoplasts in the presence of weaker acid catalyst and may be used advantageously in such cases.

The most preferred glycoluril crosslinkers of this invention are N-substituted glycolurils represented by the formula: ##STR12## wherein at least two of the R groups are selected from a group consisting of methoxymethyl, ethoxymethyl, propoxymethyl, butoxymethyl, pentoxymethyl, hexoxymethyl, heptoxymethyl, octoxymethyl, nonoxymethyl, decoxymethyl and mixtures thereof, and the remaining R groups are selected from hydrogen, alkyl, hydroxymethyl, and glycoluril group-containing oligomeric moieties.

While it is preferable to have 4 alkoxymethyl groups per each glycoluril crosslinking agent, under ordinary circumstances it may not be necessary to obtain the pure tetrasubstituted monomeric crosslinker N,N',N",N"'-tetraalkoxymethylglycoluril represented by formula: ##STR13## wherein R is an alkyl group of 1 to about 10 carbon atoms.

The monomeric tetraalkoxyglycolurils themselves are not considered to be resinous materials since they are, as individual entities, non-polymeric compounds. They are considered, however, to be potential resin-forming compounds when subjected to heat, and particularly when subjected to heat under acidic conditions. As a result of the described resin-forming ability, the substantially monomeric glycoluril crcsslinkiers of this invention may contain some higher oligomeric components such as dimers, trimers, and tetramers. The presence of modest amounts of these oligomeric forms is permissible and indeed beneficial in cases where a high melting solid crosslinker is desirable as it is the case in powder coatings.

An example of glycoluril crosslinker of this invention is POWDERLINK.RTM. 1174 Powder Crosslinking Agent, a product of American Cyanamid Company, Wayne, N.J., and has the following properties: ##STR14## Non Volatiles, minimum (% by weight): 98 Appearance: White to pale yellow granulated flakes

Another example of a glycoluril crosslinker of this invention is CYMEL.RTM. 1170 fully butylated glycoluril crosslinker, a product of American Cyanamid Company, Wayne, N.J., having the following properties:

An example of a urea crosslinker usable in this invention is BEETLE.RTM. 80 butylated urea-formaldehyde resin, a product of American Cyanamid company, Wayne, N.J., having the following properties:

* Foil Method (45.degree. C./45 min.).

The melamine-based aminoplast crosslinking agents are well known in the art and have been used extensively as effective crosslinkers in coatings.

Unlike the tetrafunctional glycolurils, alkoxymethylmelamine functionality can be a maximum of six in a crosslinkingly effective range of 2 to 6 alkoxymethyl groups per each melamine molecule.

Like the glycolurils, alkoxymethyl melamines can contain dimers, trimers, tetramers, and higher oligomers, each given combination of monomers and oligomers being preferred for a given application. For example, the lower viscosity monomer-rich compositions are preferred for solvent-based high solids coatings.

An example of the substantially fully etherified, substantially fully methylolated, substantially monomeric melamines usable in this invention is CYMEL.RTM. 303 melamine crosslinking agent, a product of American Cyanamid Company, Wayne, N.J., and has the following properties: ##STR15## Non-Volatiles (% by weight)*: 98 Color, Maximum (Gardner 1963): 1

* Foil Method (45.degree. C./45 min).

Another example of the substantially fully etherified, substantially fully methylolated, substantially monomeric melamines is CYMEL.RTM. 1168 melamine crosslinking agent, a product of American Cyanamid Company, Wayne, N.J. The alkyl group in CYMEL.RTM. 1168 consists essentially of a mixture of methyl and isobutyl groups. It has the following properties: ##STR16## Non-Volatiles (% by weight)*: 98 Color, maximum (Gardner 1963): 1

* Foil Method (45.degree. C./45 min).

An example of a substantially methylolated, partially etherified, substantially oligomeric melamine is CYMEL.RTM. 370 crosslinking agent, a product of American Cyanamid Company, Wayne, N.J. It has the following properties:

* Foil Method (45.degree. C./45 min)

As in melamines, the partially or fully methylolated or etherified alkyl and aryl guanamine aminoplasts, both in their monomeric and oligomeric forms, are usable as crosslinking agents in this invention, with the selection depending on the particular application or the properties desired in the product.

Benzoguanamine, cyclohexylcarboguanamine and acetoguanamine aminoplasts are especially preferred as crosslinkers in this invention. The benzoguanamine crosslinkers are represented by the formula: ##STR17## wherein R is an alkyl group of 1 to about 10 carbon atoms, or a mixture thereof. An example of a benzoguanamine-based crosslinking agent is CYMEL.RTM. 1123 Resin as described above, and wherein R is a mixture of methyl and ethyl groups.

The acetoguanamine-based crosslinkers are represented by the formula: ##STR18## wherein each R is independently an alkyl group of 1 to about 10 carbon atoms.

The cyclohexylcarboguanamine-based crosslinkers are represented by the formula: ##STR19## wherein each of the R groups is independently an alkyl group of 1 to about 10 carbon atoms, or a mixture thereof.

It is evident from the discussions above, that a person skilled in the art, in selecting the most suitable crosslinker for a particular application, may choose a mixture thereof which imparts a balance of properties desired for that particular application.

The aminoplast crosslinking agent (ii) is combined with the polyfunctional aminoplast-reactive ingredient (iii) in proportions that give weight ratio of the ingredients (ii):(iii) ranging from about 1:40 to about 3:1.

The weight ratio of the sulfonimide catalyst (i) to the aminoplast crosslinking agent (ii) is from about 1:4 to about 1:400.

The effective concentration of the sulfonimide cure catalyst is from about 0.01 to about 10 weight percent based on the total weight of resin solids. It is preferably from 0.3 to 0.8 weight percent of the total resin solids.

The optional ingredients present in the curable composition of the invention vary depending on the intended use of the cured article or film.

Suitable optional ingredients include fillers, ultraviolet light stabilizers, pigments, flow control agent, plasticizers, mold release agents, and corrosion inhibitors.

The composition of the invention may contain as an optional ingredient a liquid medium. Such a medium may be used to aid the uniform application and transport of the curable composition. Any or all of the ingredients of the composition may be contacted with the liquid medium. Moreover, the liquid medium may permit formation of a dispersion, emulsion, invert emulsion, or solution of the curable composition ingredients. Particularly preferred is a liquid medium which is a solvent for the curable composition ingredients (i), (ii), and (iii). Suitable solvents are selected from alcohols, ketones, ethers, esters, water, aliphatic hydrocarbons, aromatic hydrocarbons, halogenated hydrocarbons and mixtures thereof.

The novel curable powder coating composition of this invention comprises: crosslinking agents, containing at least 2 crosslinkable groups,

It is necessary that at least one of the powder coating ingredients (i), (ii), (iii) or (iv) be a solid, with the proviso that the solid ingredient(s) of the powder coating comopsition be capable of retaining the non-solid ingredient(s) to give a composition that as a whole is a solid.

A much preferred embodiment of the invention is a composition wherein the powder coating ingredients (i), (ii), (iii), and (iv) are all solids having the form of a flowable powder.

In recent years, powder coating technology has been the subject of considerable interest and commercial growth. Because powder coatings are all solids systems, they do not suffer from the solvent-related disadvantages of the solvent-based coatings systems. Powder coating minimizes the cost of shipping, storing, handling, and solvent waste disposal.

In powder coatings the ingredients used are essentially similar to conventional liquid coatings except that the powder coating composition is required to be a solid.

Preferred powder coating compositions are those wherein the ingredients (i), (ii), (iii) and (iv) are all solids. More particularly, the individual composition ingredients are as described below: sulfonimides of this invention having melting points ranging from about 40.degree. C. to about 250.degree. C., and more preferably ranging from about 80.degree. C. to about 180.degree. C. polyfunctional materials of this invention having a glass transitions (Tg) ranging from about 40.degree. C. to about 150.degree. C., and softening points ranging from about 40.degree. C. to about 150.degree. C., and more preferably ranging from about 80.degree. C. to about 140.degree. C.

It is preferable that the powder coating composition as a whole be a solid at ambient temperatures and that it remains solid up to about 40.degree. C. to preserve the powdery state of the curable composition and to prevent lumping.

Upon heating, however, these resins should become fluid to permit formation of low viscosity melts which allow efficient mixing of the components of the curable composition prior to crosslinking. It is desirable that the aminoplast-reactive resins become fluid at temperatures ranging from about 80.degree. C. to about 150.degree. C., and most preferably from about 100.degree. C. to about 140.degree. C. solid aminoplast crosslinking agents of this invention having melting or softening points ranging from about 40.degree. C. to about 150.degree. C., and more preferably from about 80.degree. C. to about 140.degree. C., and most preferably from about 100.degree. C. to about 120.degree. C.

Glycoluril type aminoplast crosslinking agents are particularly preferred because they are solids at ambient temperatures and generally have suitable melting points.

It is preferable that the solid aminoplast crosslinking agents are solids at ambient temperatures and that they remain solids up to about 40.degree. C. to preserve the powdery state of the curable composition and to prevent lumping. It is desirable that the aminoplast crosslinking agents become fluid at temperatures ranging from about 80.degree. C. to about 150.degree. C., and more preferably from 100.degree. C. to about 140.degree. C. optional ingredients such as benzoin at about 1 to 4 weight percent level. The composition may also include as a flow control agent ingredients such as Modaflow.RTM. Powder III Resin Modifier, a product of Monsanto Company, or Resiflow P-67 Flow Control Agent, a product or Estron Chemical, Inc. at about 1 to 2 weight percent level. Moreover, fillers and pigments such as titanium dioxide based pigments may be conventionally added to improve the appearance and properties of the coatings and articles formed from the compositions.

The polyfunctional material capable of reacting with an aminoplast crosslinking agent is one of three essential components required for the curable compositions of this invention. The other essential components are aminoplast crosslinking agents such as N,N',N",N"'-tetramethoxymethylglycoluril, and sulfonimide cure catalyst such as N-(methanesulfonyl)-p-toluenesulfonamide. The aminoplast-reactive functional groups of the polyfunctional material react, under cure conditions, with crosslinkable groups to produce a three dimensional crosslinked network such as those found in coatings, moulded articles and adhesives.

The aminoplast reactive functional groups are selected from a group comprising: amino groups, amido groups, carboxyl groups, mercapto groups, hydroxy groups, and combinations of any of the aforementioned functional groups. Reactive materials having a plurality of carboxy and/or hydroxy groups are particularly preferred in the practice of the invention.

Suitable polyfunctional hydroxy reactant materials may be epoxy or polyurethane prepolymers, alkyds, acrylic resins containing pendant or terminal carboxy or hydroxy functionalities, or polyester resins with pendant or terminal hydroxy or carboxy groups. These are described in greater detail below.

In cases where resins used in the formulations of this invention are intended for powder coating applications, the resins should be solids at ambient temperatures and should remain solids up to about 40.degree. C. to preserve the powdery state of the curable composition and prevent lumping. The aminoplast-reactive materials or resins used in the compositions of the invention preferably have a molecular weight of from about 100 to about 50,000. In the event that the aminoplast reactive material is in the form of an emulsion the molecular weight may be as high as about 5,000,000.

The hydroxyfunctional acrylio resins used in formulating the curable compositions of this invention preferably have molecular weights in the range of from about 500 to about 50,000 and hydroxyl group equivalent weights of from about 200 to 4,000. An examples of a suitable acrylic resin is JONCRYL.RTM. SCX-800 A acrylic resin, a product of S.C. Johnson and Sons, Inc., having the following physical and chemical properties:

Another example of a suitable acrylic resin is JONCRYL.RTM. BCX-800 B acrylic resin, a product of S.C. Johnson and Sons, Inc., having the following physical and chemical properties:

or JONCRYL.RTM. 500 acrylic resin, a product of S.C. Johnson and Sons, Inc., having the following properties:

* Mn=Number Average Molecular Weight.

** Mw=Weight Average Molecular Weight.

Commercially available acrylic resins are generally applicable for use in preparing the compositions of the invention. Selection of the optimum acrylic resin will depend on the user's desire to impart to the final cured product particular physical properties such as hardness, flexure, chemical and solvent resistance, and etc.

The hydroxy functional polyester resins used in formulating the curable compositions of this invention preferably have molecular weights in the range of from about 1,000 to 50,000 and hydroxyl group equivalent weights of from about 200 to 4,000.

An example of a suitable polyester resin is Arakote.RTM. 3109 solid hydroxyl terminated polyester powder coating resin, a product of Ciba-Geigy Corporation, Hawthorne, N.Y., having the following physical and chemical properties: Color               Colorless Solid OH Number:          27-32 ICI Viscosity at 200.degree. C. (Poise): 40 Glass Transition Temperature 66 (Tg) (.degree.C.): Equivalent Weight:  1900 ______________________________________

Another example of a suitable polyester resin is ALFTALAT.RTM. AN 745 hydroxyfunctional polyester resin, a product of Hoechst Corporation, having the following physical and chemical properties:

Another example of a suitable polyester resin is ARAKOTE.RTM. 3010 carboxyl-terminated polyester, a product of Ciba-Geigy Corporation, Ardsley, N.Y., having the following properties:

Another example of a suitable polyester resin is RUCOTE.RTM. 101 polyester resin, a product of Ruco Polymer Corporation, Hicksville, N.Y., having the following physical and chemical properties:

Another example of a suitable polyester resin is CARGILL 3000 polyester, a product of Cargill Corporation, having the following physical and chemical properties:

Upon cure, polyester resins give films of superior properties, as described in detail in the Examples. A wide variety of commercial polyester resins may be used for the aminoplast-reactive ingredient of the invention, provided such resins have the physical properties suitable for the intended application.

Other polyhydroxy functional compounds which are useful in the practice of the invention are diols, triols, tetraols, and higher polyhydroxy alcohols. Illustrative polyhydric alcohols are pentaerythritol dipentaerythritol, tripentaerythritol, trimethylolethane, trimethylolpropane, anhydroenneahepititol, 1,2,4-butanetriol, and 1,2,6-hexanetriol. These polyols can also be used to totally or partially replace the acrylic resin or polyester resin aminoplast-reactive ingredient of the composition of the invention. However, the film properties resulting from addition of such non-resinous ingredients sometimes are inferior and lack flexibility in the cured film final product.

Polyfunctional epoxy prepolymers, alkyds, and polyurethane prepolymers are also usable as hydroxyfunctional aminoplast-reactive materials.

Polyfunctional amides are also suitable as aminoplast-reactive components, provided they have the proper physical properties suitable for the intended use. For example, for powder coatings application, they are solids at up to about 40.degree. C. to allow the preparation of storage stable powders containing the aminoplast crosslinking agents. The crosslinked films and articles resulting from polyamide-containing curable compositions, however, have physical properties somewhat different (i.e. harder) than polyester and acrylic-based systems described above.

The catalyst/crosslinker combination of the invention is a uniform mixture of the following materials: groups.

Suitable sulfonimide cure catalysts (a) and aminoplast crosslinking agents (b) are as set out in the preceding sections. The components (a) and (b) can each be either liquids or solids. A particularly preferred catalyst/crosslinker combination is one wherein both the sulfonimide catalyst (a) and the aminoplast crosslinker (b) are both solids at 40.degree. C.

This invention is also an improved method of coating substrates by applying to substrates the coating composition of the invention.

This invention is a method of coating substrates using a liquid curable coating composition, where the composition contains the following ingredients: containing at least 2 crosslinkable groups, crosslinking agents, and

The liquid curable coating composition of the invention may be contacted with a substrate by spraying, padding, brushing, rollercoating, curtaincoating, flowco,ting, electrostatic spraying, electrocoating or dipping.

"Powder coating" is an art recognized process and is defined herein as a method of electrostatic powder-spraying wherein a finely divided solid coating material is electrostatically attracted to a surface of an article. Alternatively, the powder coating composition may be contacted with the substrate by immersing the substrate in fluidized bed of powder. The article covered with the powder is heated to at least the fusion temperature of the coating composition forcing it to flow out and form a coating which is cured by further application of heat.

The prior art powder coating process can be considerably improved by using as the coating material a low temperature heat-curable aminoplast coating composition comprising as essential ingredients:

The unexpectedly superior properties of the films formed from the powder coating compositions of the invention are their superior appearance manifested in gloss and smoothness, improved impact and corrosion resistance.

A typical procedure for using the compositions of the invention is as follows:

The substrates are coated with the powder coating composition of the invention and subjected to a temperature of from about 90.degree. C. to about 350.degree. C. to melt and spread the composition uniformly onto the substrate surface. Thereafter, the substrate is held at a temperature of from about 120.degree. C. to about 350.degree. C. to crosslink the composition and form the permanently cured coating.

The catalyst/polyfunctional material combination of the invention is a uniform mixture of the following materials: crosslinking agents.

Suitable sulfonimide cure catalysts (a) and suitable polyfunctional materials capable of reacting with aminoplast crosslinking agents (b) are set out in the preceeding sections.

The components (a) and (b) can each be either liquids or solids. A particularly preferred catalyst/polyfunctional material combination is one wherein the sulfonimide cure catalyst (a) and the polyfunctional material capable of reacting with aminoplast crosslinking agents (b) are both solids at 40.degree. C. In the preferred mode, components (a) and (b) are blended to form a masterbatch, which is then admixed with an aminoplast crosslinking agent. Optionally, the masterbatch is admixed with an aminoplast crosslinking agent and an additional amount of polyfunctional material.

The suitable weight ratio of the catalyst (a) to polyfunctional material (b) is in the range of from about 1:10,000 to about 9:1, with ratios of from about 3:1 to about 1:20 being preferred.

The solid sulfonimide cure catalyst/polyfunctional material combinations of the invention are prepared by a process comprising the steps of: polyfunctional material at a temperature sufficient to produce a uniform melt-mixed resinous material, to produce a solid, and catalyst/polyfunctional material combination usable in the improved method of powder coating described hereinbelow. COMBINATION

An improved method of coating substrates by contacting said substrates with a powder coating composition and thereafter heat curing said composition, wherein the improvement comprises: contacting said substrate with a curable powder coating composition comprising: capable of reacting with aminoplast crosslinking agents, containing at least 2 crosslinkable groups, of reacting with aminoplast crosslinking agents, and technology.

The improved method of powder coating employs a preblended mixture of the sulfonimide cure catalyst and the polyfunctional material which mixture is further blended with the remaining ingredients and the resulting powder is applied to substrates to be coated by methods well known in the art as "Powder Coating," defined and briefly described in a preceeding section entitled "A Method of Coating Using Powder Coating Compositions."

Suitable sulfonimide cure catalysts, and polyfunctional materials capable of reacting with aminoplast crosslinking agents are set out in the preceeding sections. The ratios of the ingredients are futher described below.

The sulfonimide cure catalyst/polyfunctional material combinations (i) are those previously described under the same title. In the masterbatch of catalyst/polyfunctional material combination (i), the suitable weight ratio of the sulfonimide cure catalyst to polyfunctional material is in the range of from about 1:10,000 to about 9:1, with a ratio of about 1:1 being preferred. The weight percent of the sulfonimide cure catalyst in the catalyst/polyfunctional material combination of ingredient (i) is from about 0.01 percent to about 90 percent, with 50 weight percent being preferred.

In the curable compositions of the improved method of powder coating, the weight percent of the sulfonimide cure catalyst/polyfunctional material ingredient (i) is in the range of 0.01 to 97.5 percent of the total weight of the resin-forming ingredients, with 1.0 percent being preferred. The weight ratio of the aminoplast crosslinking agent to total polyfunctional material is from about 1:40 to about 3:1, and the weight precent of the sulfonimide cure catalyst is in the range of 0.01 to about 10 weight percent of the total weight of the resin-forming ingredients.

"Resins-forming ingredients" are defined herein as the sum of the total polyfunctional material and the aminoplast crosslinking agent. Other ingredients are excluded from the above definition. INVENTION

The curable compositions of this invention containing the sulfonimide cure-catalyst of the invention can be heat cured (typically 90.degree. C. to 400.degree. C.) to produce crosslinked moulded articles, adhesives and coatings. Because of the polyfunctional nature of the reactants, the resulting product in this case is a crosslinked article in the form of a film such as adhesives and/or coatings or the form of an article such as molded products.

The heat-cured compositions of this invention may be employed as coatings for wire, appliances, automotive parts, furniture, pipes, machinery, and the like.

The heat-cured compositions may also be used to form solid articles such as cases, enclosures, and structural members.

The following Examples illustrate various embodiments of the invention.

p-Toluenesulfonyl chloride (38.2 g, 0.20 mole) was added, in five portions over a period of 90 minutes, to a heated (70.degree. C.) solution of methanesulfonamide (19.0 g, 0.20 mole) in aqueous sodium hydroxide (176 ml). Throughout the addition, a pH of 12 was maintained by frequent additions of aqueous 5% sodium hydroxide solution. After stirring for about 20 hours at about 70.degree. C., the reaction mixture was cooled to room temperature and acidified with concentrated hydrochloric acid to pH less than 1 and extracted with dichloromethane (3.times.200 ml). The organic layer was separated, dried (sodium sulfate) and concentrated to 150 ml. Addition of n-heptane (200 ml) gave highly pure methyl para-tolyl sulfonimide, also known as N-(methanesulfonyl)-p-toluenesulfonamide, a sulfonimide cure catalyst of the invention, as a white precipitate (18.3 g), m.p. 117.degree.-120.degree. C.

Example 1, Part A illustrates the preparation of a mixed aryl and alkyl group containing cure catalyst of this invention. article: N. N. Dykhanov, Zhur. Obshchei Khim., 29, 3602 (1959); Chemical Abstracts (54) 19577g (1960).

The procedure of EXAMPLE 1, PART A was followed with the exception that methanesulfonamide was replaced with an equivalent amount of p-toluenesulfonamide (34.2 g, 0.20 mole) and the extraction step was replaced by a purification step to give the symmetrical di-(p-toluene)sulfonimide, a sulfonimide cure catalyst of the invention, as a white solid of 96% purity, m.p. 171.degree.-173.degree. C.

EXAMPLE 1, PART B illustrates the preparation of the symmetrical di-(p-toluene)sulfonimide, which is another example of the sulfonimide cure catalysts of this invention.

A commercially available sulfonimide, N-(4-aminobenzenesulfonyl)benzenesulfonamide, a product of Aldrich Chemicals, Milwaukee, Wisc., was used as cure catalyst in the preparation of Composition C.

The procedure of EXAMPLE 1, PART A, was followed with the exception that methanesulfonamide and p-toluenesulfonyl chloride were replaced, respectively, with equivalent amounts of p-nitrobenzenesulfonamide and a solution of p-nitrobenzenesulfonyl chloride in acetone (50 ml). also, the extraction step was replaced with a purification step to give the symmetrical di-(4-nitrobenzene)sulfonimide, a sulfonimide cure catalyst of the invention, as an off-white solid of 98% purity, m.p. 238.degree.-240.degree. C.

EXAMPLE 1, PART D illustrates the preparation of another example of sulfonimide cure catalyst of this invention.

This example illustrates the preparation of powder coatings using the sulfonimide cure catalysts of the invention.

The following four curable compositions, Composition A, B, C, and D, were formulated using sulfonimide cure catalysts of this invention and thereafter cured at 190.degree. C. (20 min). 1. PREPARATION OF THE CURABLE COMPOSITIONS Weight (g) ______________________________________ A.   COMPOSITION A Arakote .RTM. 3109 Polyester (solid) 94.00 Powderlink .RTM. 1174 Crosslinking 6.00 Agent (solid) Sulfonimide Cure Catalyst of Example 1, 0.50 Part A Benzoin (a solid additive) 1.40 R960-48 .RTM. Titanium Dioxide Pigment 40.00 (product of DuPont Company, Wilmington, Delaware) Resiflow P-67 Flow Control Agent 1.30 (product of Estron Chemical, Inc. Culvert City, Ky) B.   COMPOSITION B Arakote  .RTM. 3109 Polyester (solid) 94.00 Powderlink .RTM. 1174 Crosslinking 6.00 Agent (solid) Sulfonimide Cure Catalyst of Example 1, 0.50 Part B Benzoin (a solid additive) 1.40 R960-48 Titanium Dioxide Pigment 40.00 Resiflow P-67 Plow Control Agent 1.25 C.   COMPOSITION C Arakote .RTM. 3109 Polyester (solid) 94.00 Powderlink .RTM. 1174 Crosslinking 6.00 Agent (solid) Sulfonimide Cure Catalyst of Example 1, 0.50 Part C Benzoin (a solid additive) 1.40 R960-48 Titanium Dioxide Pigment 40.00 Resiflow P-67 Flow Control Agent 1.25 D.   COMPOSITION D Arakote .RTM. 3109 Polyester (solid) 94.00 Powderlink .RTM. 1174 Crosslinking 6.00 Agent (solid) Sulfonimide Cure Catalyst of Example 1, 0.50 Part D Benzoin (a solid additive) 1.40 Titanium Dioxide Pigment 40.00 Resiflow P-67 Flow Control Agent 1.25 ______________________________________

A control composition was prepared as described above in Composition A with the exception that no cure catalyst was used.

All components were dry-blended in a Waring blender or a Welex mixer for small and larger scale runs, respectively. The dry-blended powder was then melt-mixed at about 90.degree. C. to 135.degree. C. for 1-5 minutes in a two roll mill to allow homogeneous mixing without allowing crosslinking to occur. The melt-mixed material was then chopped into smaller pieces in a blender mill or a pelletizer, and fed into a mill classifier where the chips were ground to a fine powder with particle size about 35 microns. The finely ground powder, charged with up to so KV power, was then sprayed through an electrostatic spray gun on grounded metal substrates, Bonderite.RTM. 1000 (a product of Parker Industries, Inc.) in a spray booth.

The electrostatically coated Bonderite 1000 substrates containing the curable compositions of the invention were then baked in an oven at 190.degree. C. to allow the powder to fuse, flow out and crosslink. These processes were analyzed by means of a viscometer and a rheometer.

TABLE 1 summarizes the cure conditions, the film properties resulting from curing the curable compositions and particularly the film appearance.

It is concluded from the results in EXAMPLE 2 that powder coatings prepared by using the curable compositions of this invention which contain the cure catalysts of this invention have excellent film properties and appearance. The control formulation without catalyst did not cure, showing the necessity of catalyst inclusion in the formulation. __________________________________________________________________________ POWDER COATINGS FROM CURABLE COMPOSITIONS OF THE INVENTION CURE CONDITIONS, FILM PROPERTIES AND APPEARANCE CURABLE COMPOSITIONS* Comp.  Comp.  Comp.  Comp. A      B      C      D __________________________________________________________________________ CURE CONDITIONS Catalyst of  Part A Part B Part C Part D Example 1 Weight of    0.50   0.50   0.50   0.50 Catalyst (g) Bale Temperature 190    190    190    190 (.degree.C.) Bake Time (min.) 20     20     20     20 FILM APPEARANCE Orange Orange Orange Orange Peel   Peel   Peel   Peel Microblisters Microblisters Microblisters Microblisters Craters       Pinholes Gel Seed FILM PROPERTIES Film Thickness 1.9-2.3 1.9-2.5 1.4-2.4 1.0-2.0 (mils) (ASTM D-1400-81) Film Thickness 0.048-0.058 0.048-0.064 0.036-0.061 0.025-0.050 (mm) (ASTM D-1400-81) Hardness, KHN.sub.25 13.0   11.7   10.2   12.2 ASTM (D-1474-85) MEK Rubs     200+   200+   200+   200+ (Double Rubs) Impact, F/R  160/160 160/160 160/160 160/160 in lb) (Front/Reverse) ASTM D-2794-82 Color, Tristim- -0.06  -0.03  0.00   0.02 ulus Gloss, 60.degree. 94.1   94.0   94.1   78.4 Gloss, 20.degree. 79.4   73.4   79.3   32.5 RESISTANCE PROPERTIES Humidity (60.degree. C.) 504    528    504    456 Time (hrs) ASTM D 4585-87 Appearance   No     No     No     Dense After Testing Change Change Change Micro- blisters Salt Spray,  1008   1008   1008   1032 Time (hrs) ASTM B-117 Creepage (mm) 3      0      0      0 Appearance** 9      9      9      9 after testing ASTM D-610 __________________________________________________________________________ *The control composition containing no catalyst did not cure well under the conditions of EXAMPLE 2. The film was removed completely in less than 2 MEK double rubs. **Scale is 1 to 10 where 10 is the best.

The experiments of EXAMPLE 2 were repeated with Compositions A, B, C, and D at the slightly lower temperature of 175.degree. C. Composition C did not cure well. The cure conditions, film properties and film appearance of the remaining compositions are summarized in TABLE 2.

It is concluded from the results in TABLE 2 that the curable compositions of this invention containing the sulfonimide cure catalysts are capable of curing at low temperatures (175.degree. C.) to produce powder coatings with excellent film properties and acceptable appearance. ______________________________________ Powder Coatings from Curable Compositions of the invention CURABLE COMPOSITIONS Comp.   Comp.        Comp. A       B            D ______________________________________ FILM        Orange    Orange       Orange APPEARANCE  Peel      Peel         Peel Micro-    Micro-       Micro- blisters  blisters     blisters Craters FILM PROPERTIES Film Thickness 1.8-2.8   2.5-3.5      1.5-2.5 (mils) Film Thickness 0.046-0.071 0.064-0.089  0.038-0.064 (mm) Hardness KHN.sub.25 11.8      12.7         10.5 MEK Rubs       20/200+ 10/200+   200+ Impact F/R (in-lb) 160/160   100-120/0-20 160/160 Color, Tristim- -0.06     -0.03        0.05 ulus Gloss, 60.degree. 67.4      68.3         58.9 Gloss, 20.degree. 47.3      38.3         24.5 RESISTANCE PROPERTIES Humidity (60.degree.C.), 456       288          192 Time (hrs) Appearance  Increased Increased    Increased after testing Microblis- Micro-       Micro- ters, some blisters     blisters loss of gloss Salt Spray, 1008      1008         1008 Time (hrs) Creepage (mm) 2         0            0 Appearance  9         9            9 (after testing) ______________________________________

Curable compositions E, F, and G were prepared and cured at 190.degree. C./20 min. by the method described in EXAMPLE 2. Weight (g) ______________________________________ COMPOSITION E Arakote .RTM. 3109 polyester (solid) 94.00 Powderlink .RTM. 1174 Crosslinking 6.00 Agent (solid) Sulfonimide cure catalyst of EXAMPLE 1, 0.30 PART A Benzoin (a solid additive) 1.40 R960-48 titanium dioxide pigment 40.00 Resiflow P-67 flow control agent 1.30 COMPOSITION F Arakote .RTM. 3109 polyester (solid) 94.00 Powderlink .RTM. 1174 Crosslinking 6.00 Agent (solid) p-Toluenesulfonic Acid Monohydrate (solid) 0.30 Benzoin (a solid additive) 1.40 OR 650 titanium dioxide pigment 40.00 Resiflow P-67 flow control agent 1.25 COMPOSITION G Arakote .RTM. 3109 polyester (solid) 94.00 Powderlink .RTM. 1174 Crosslinking 6.00 Agent (solid)            6.00 p-Toluenesulfonic acid monohydrate (solid) 0.20 Benzoin (a solid additive) 1.40 R960 48 titanium dioxide pigment 40.00 Modaflow III flow control agent 1.25 ______________________________________

TABLE 3 summarizes the film properties and appearance characteristics of the cured coatings obtained by curing the compositions E, F, and G.

It is concluded from the results in EXAMPLE 4 that the curable composition E of this invention containing the sulfonimide cure catalyst of EXAMPLE 1, PART A produces superior powder coatings when compared with curable compositions of the prior art such as compositions F and G containing p-toluenesulfonic acid catalyst commonly used in prior art. The prior art p-toluenesulfonic acid cured system gave unacceptable appearance, lower gloss, and failed in the salt spray test. __________________________________________________________________________ Comparison of Sulfonimide Cure Catalyst with p-Toluenesulfonic Acid in Powder Coatings CURABLE COMPOSITIONS Comp.    Comp.  Comp.  Comp.   Comp. E.sup.1  F.sup.2 G.sup.3 F.sup.4 G.sup.4 __________________________________________________________________________ FILM APPEARANCE Orange Peel Orange Peel Orange Peel Orange Peel Orange Peel Microblisters Microblisters Microblisters Microblisters Microblisters Pinholes Matted Craters Pinholes Gel Seeds     Gel Seed Craters Gel Seed FILM PROPERTIES Film Thickness  2.4-2.9  1.7-3.0 1.9-2.2 1.9-3.3 2.4-3.3 (mils) Film Thickness  0.061-0.074 0.043-0.076 0.048-0.056 0.048-0.084 0.061-0.084 (mm) Hardness KHN.sub.25 12.1     12.0   10.8   10.6    10.1 MEK Rubs           20/200+ 200+   200+   200+    200+ Impact F/R (in-lb) 160/160  160/160 45-50/45-50 60-80/80-100 140-160/40-60 Color, Tristim- -0.06    0.01   -0.05  -0.03   -0.02 ulus Gloss, 60.degree. 92.7     83.7   70.3   88.3    86.5 Gloss, 20.degree. 78.6     42.9   25.0   48.1    48.5 RESISTANCE PROPERTIES Humidity (60.degree. C.), 456      504    120 Time (hrs) Appearance      Increased No change Increased (after testing) Microblisters,  Microblisters slight loss of gloss Salt Spray,     1008     768    192 Time (hrs) Creepage (mm)   1        3      0 Appearance      9 (after testing) __________________________________________________________________________ .sup.1 0.3% N(Methanesulfonyl)-1-toluenesulfonamide cure catalyst, based on weight of resin solids. .sup.2 0.3% pToluenesulfonic acid monohydrate cure catalyst, based on weight of resin solids. .sup.3 0.2% pToluenesulfonic acid monohydrate cure catalyst, based on weight of resin solids. .sup.4 Repeat experiments.

Curable composition H was prepared by the method described in EXAMPLE 2. It was cured at 175 and 190.degree. C. by the method described in EXAMPLE 2. COMPOSITION H            Weight (g) ______________________________________ Alftalat .RTM. AN 745 polyester (solid) 94.00 Powderlink .RTM. 1174 Crosslinking 6.00 Agent (solid) Sulfonimide cure catalyst of EXAMPLE 1, 0.50 PART A Benzoin (a solid additive) 2.40 R960-48 titanium dioxide pigment 40.00 Resiflow III flow control agent 1.30 ______________________________________

TABLE 4 summarizes the film properties and appearance characteristics of the cured coatings obtained by curing composition H.

This example illustrates that a sulfonimide cure catalyst of the invention produces excellent powder coating with Alftalat.RTM. AN 745 as well as Arakote.RTM. 3109 polyesters at two different temperatures. ______________________________________ Powder Coatings with Alftalat .RTM. AN 745 and Powderlink .RTM. 1174 Cured with a Sulfonimide Cure Catalyst CURABLE COMPOSITION H 175.degree. C. Cure 190.degree. C. Cure ______________________________________ FILM APPEARANCE   Orange Peel Orange Peel Microblisters Microblisters FILM PROPERTIES Film Thickness    2.3-2.8     2.1-2.5 (mils) Film Thickness    0.058-0.071 0.053-0.064 (mm) Hardness, KHN.sub.25 10.9        10.5 MEK Rubs          200+        200+ Impact F/R (in-lb) 160/160     160/160 Color, Tristim-   -0.07       -0.06 ulus Gloss, 60.degree. 92.7        91.4 Gloss, 20.degree. 77.1        73.4 RESISTANCE PROPERTIES Humidity (60.degree. C.), 432         504 Time (hrs) Appearance        Increased   No (after testing)   Microblisters Change Salt Spray,       1070        1070 Time (hrs) Creepage (mm)     1           1 Appearance        No Change   No Change (after testing) ______________________________________

Curable compositions 1 was prepared by the method described in EXAMPLE 2. It was cured at 175 and 190.degree. C. by the method described in EXAMPLE 2. COMPOSITION I            Weight (g) ______________________________________ Rucote .RTM. 101 polyester (solid) 94.00 Powderlink .RTM. 1174 Crosslinking 6.00 Agent (solid) Sulfonimide cure catalyst of EXAMPLE 1, 0.50 PART A Benzoin (a solid additive) 2.40 R960-48 titanium dioxide pigment 40.00 Resiflow III flow control agent 1.30 ______________________________________

TABLE 5 summarizes the film properties and appearance characteristics of the cured coatings obtained by curing composition H.

This example illustrates that a sulfonimide cure catalyst of Example 1, Part A produces excellent powder coatings with Rucote.RTM. 101 as well as Alftalat.RTM. AN 745 and Arekote.RTM. 3109 polyesters at two different temperatures. ______________________________________ Powder Coatings with Rucote .RTM. 101 and Powderlink .RTM. 1174 Cured with a Sulfonimide Cure Catalyst CURABLE COMPOSITION I 175.degree. C. Cure 190.degree. C. Cure ______________________________________ FILM APPEARANCE   Orange Peel Orange Peel Microblisters Microblisters FILM PROPERTIES Film Thickness    2.0-2.6     1.7-2.4 (mils) Film Thickness    0.051-0.066 0.043-0.061 (mm) Hardness KHN.sub.25 11.9        10.8 MEK Rubs          200+        200+ Impact F/R (in-lb) 160/160     160/160 Color, Tristim-   -0.06       -0.07 ulus Gloss, 60.degree. 83.5        91.7 Gloss, 20.degree. 66.7        74.6 RESISTANCE PROPERTIES Humidity (60.degree. C.), 336         504 Time (hrs) Appearance        Some loss   No Change (after testing)   of gloss Salt Spray,       1070        1070 Time (hrs) Creepage (mm)     1           3 Appearance        Some blisters Some blisters (after testing) ______________________________________

An additional sulfonimide cure catalyst was prepared by the method of EXAMPLE 1, PART A, using the same reaction conditions but different reactants: and 4-chlorobenzenesulfonyl chloride.

Two additional curable compositions were prepared as follows: Weight (g) ______________________________________ COMPOSITION J Arakote .RTM. 3109 polyester (solid) 94.00 Powderlink .RTM. 1174 Crosslinking 6.00 Agent (solid) di-(Benzene)sulfonimide cure catalyst 0.30 Benzoin (a solid additive) 1.40 R960-48 titanium dioxide pigment 40.00 Resiflow P67 flow control agent 1.30 COMPOSITION K Arakote .RTM. 3109 polyester (solid) 94.00 Powderlink .RTM. 1174 Crosslinking 6.00 Agent (solid) di-(4-Chlorobenzene)sulfonimide 0.30 cure catalyst Benzoin (a solid additive) 1.40 R960-48 titanium dioxide pigment 40.00 Resiflow P-67 flow control agent 1.25 ______________________________________

Compositions J and K, along with Composition E from EXAMPLE 4 were cured at 190.degree. C./20 min by the method of EXAMPLE 2. The results are summarized in TABLE 6.

This example illustrates that both symmetrical and unsymmetrical sulfonimide cure catalyst of the invention are effective catalysts. It further illustrates that N-(methanesulfonyl)-p-toluenesulfonamide sulfonimide cure catalyst produces excellent film properties and acceptable appearance. ______________________________________ Effect of Symmetrical and Unsymmetrical Cure Catalyst on Film Properties and Appearance CURABLE COMPOSITIONS Comp.   Comp.     Comp. E       J         K ______________________________________ FILM         Orange    Orange    Orange APPEARANCE   Peel      Peel      Peel Micro-    Micro-    Micro- blisters  blisters  blisters Some      Wrinkles Wrinkles FILM PROPERTIES Film Thickness 2.4-2.9   2.0-3.0   1.8-2.2 (mils) Film Thickness 0.061-0.074 0.051-0.076 0.046-0.056 (mm) Hardness, KHN.sub.25 12.1      12.4      11.8 MEK Rubs        20/200+ 200+      200+ Impact F/R (in-lb) 160/160   160/160   110-120/40-50 Color, Tristim- -0.06     -0.04     0.05 ulus Gloss, 60.degree. 92.7      93.9      95.1 Gloss, 20.degree. 78.6      75.0      81.8 RESISTANCE PROPERTIES Humidity (60.degree. C.), 456       600       600 Time (hrs) Appearance   Loss of   No change No change after testing gloss Salt Spray,  1008      1008      1008 Time (hrs) Creepage (mm) 1         0         0 Appearance   9         9         9 after testing ______________________________________

This example illustrates that a large variety of non-sulfonimide compounds are unsuitable as catalysts in the composition of this invention, when compared to Composition E of Example 4 under the same conditions. The results are summarized in Table 7.

It is concluded from the results in Table 7 that Composition E containing the sulfonimide of Example 1, Part A, has better overall properties when compared with related catalyst systems. __________________________________________________________________________ COMPARISON OF FILM PROPERTIES OF SULFONIMIDES WITH OTHER CATALYSTS IN POWDER COATINGS GLOSS APPEARANCE MEK RUBS IMPACT, F/R 60.degree./20.degree. BEFORE TESTING __________________________________________________________________________ Composition E Containing 20/200+ 160/160 92.7/78.6 Orange Peel the Sulfonimide of                 Microblisters EXAMPLE 1, PART A ##STR20##     1/3    --      --   -- ##STR21##     1/5    --      --   -- ##STR22##     <1     --      --   -- NH.sub.2 SO.sub.3 H 1/12   --      --   -- ##STR23##     200+   160/120-140 71.8/23 Wrinkles Craters ##STR24##     200+   60-80/0-20 (Fail) 79.4/32.8 Orange Peel Microblisters Pinholes ##STR25##     50/200 50-60/0-5 29.4/6.4 Textured __________________________________________________________________________

This example illustrates that powder coating compositions of the invention containing sulfonimide cure catalyst of the invention cure faster and produce films with superior overall film properties and appearance characteristics than similar compositions containing benzoin tosylate as the cure catalyst.

The following curable compositions, Curable Composition L and Curable composition M, were formulated and thereafer cured at 175.degree. C. (20 min) and at 190.degree. C. (20 min.) the procedure of EXAMPLE 2. Weight (g) ______________________________________ COMPOSITION L Arakote .RTM. 3109 polyester (solid) 94.00 Powderlink .RTM. 1174 Crosslinking 6.00 Agent (solid) Sulfonimide Cure catalyst of 0.5 EXAMPLE 1, PART A Benzoin (a solid additive) 2.4 R960-48 titanium dioxide pigment 40.00 Resiflow P-67 flow control agent 1.3 COMPOSITION M Arakote .RTM. 3109 polyester (solid) 94.00 Powderlink .RTM. 1174 Crosslinking 6.0 Agent (solid) Benzoin tosylate (solid) 2.0 Benzoin (a solid additive) 1.4 R960-48 titanium dioxide pigment 40.00 Resiflow P-67 flow control agent 1.25 ______________________________________

Table 8 summarizes the film properties and appearance characteristics of the cured films obtained by curing the comparative pair (Compositions L and M) at 175.degree. C. Table 9 depicts the same at 190.degree. C.

It is concluded from the results in Tables 8 and 9 that films obtained by curing the compositions of the invention have superior film properties and appearance characteristics than similar films cured with benzoin tosylate. It can also be concluded that higher levels of benzene tosylate catalyst are needed to achieve cure compared to sulfonimide catalysts. ______________________________________ Comparison of a Sulfonimide Cure Catalyst of the Invention with Benzoin Tosylate in Powder Coatings Cured at 175.degree. C. Benzoin Sulfonimide* Tosylate Curable   Curable Comp. L   Comp. M ______________________________________ FILM APPEARANCE   Orange Peel Orange Peel Microblisters Microblisters FILM PROPERTIES Film Thickness    1.5-2.2     2.0-2.2 (mils) Film Thickness    0.038-0.056 0.051-0.059 (mm) Hardness, KHN.sub.25 11.3        11.9 MEK Rubs             20/200+   1/15 Impact F/R (in-lb) 160/160     20-30/0-5 Color, Tristim-   -0.06       -0.06 ulus Gloss, 60.degree. 81.1        92.4 Gloss, 80.degree. 56.5        79.5 RESISTANCE PROPERTIES Humidity (60.degree. C.), 504         96 Time (hrs) Appearance        No change   Loss of Gloss after testing Salt Spray,       888         528 Time (hrs) Creepage (mm)     3           0 Appearance        Blisters    Blisters after testing ______________________________________ *N-Methanesulfonyl-p-Toluenesulfonamide, sulfonimide catalyst of EXAMPLE 1, PART A ______________________________________ Comparison of a Sulfonimide Cure Catalyst of the Invention with Benzoin Tosylate in Powder Coatings Cured at 190.degree. C. Benzoin Sulfonimide* Tosylate Curable   Curable Composition L Composition M ______________________________________ FILM APPEARANCE Orange Peel Orange Peel Microblisters Microblisters FILM PROPERTIES Film Thickness 1.5-2.2     1.6-2.0 (mils) Film Thickness 0.038-0.056 0.041-0.056 (mm) Hardness, KHN.sub.25 11.2        11.6 MEK Rubs       200+        200+ Impact F/R (in-lb) 160/160     150-160/150-160 Color, Tristim- -0.05       -0.06 ulus Gloss, 60.degree. 93.5        94.4 Gloss, 80.degree. 74.9        83.4 RESISTANCE PROPERTIES Humidity (60.degree. C.), 504         264 Time (hrs) Appearance     No change   Increased after testing              Microblisters Salt Spray,    960         528 Time (hrs) Creepage (mm)  4           0 Appearance     Blisters    Blisters after testing ______________________________________ *N-Methanesulfonyl-p-Toluenesulfonamide, sulfonimide catalyst of EXAMPLE 1, PART A

This example illustrates that solvent-based coating compositions of the invention containing a sulfonimide cure catalyst cure at a rate comparable with sulfonic acid-cured compositions. Weight (g) ______________________________________ COMPOSITION N JONCRYL .RTM. 500 Acrylic 81.25 Resin (80% Solids) CYMEL .RTM. 1168 Crosslinking Agent 35.00 di-Benzenesulfonimide (52% Solution) 1.00 n-Butanol             20.00 Xylene                16.55 Non-Volatiles: 65 weight % Resin/Crosslinker Weight Ratio: 65/35 Catalyst based on resin solid: 0.5 Weight % COMPOSITION O JONCRYL .RTM. 500 Acrylic 81.25 Resin (80% Solids) CYMEL .RTM. 1168 Crosslinking Agent 35.00 p-Toluenesulfonic Acid (40 Wt % 0.75 Solution) n-Butanol             20.00 Xylene                16.55 Non-Volatiles: 65 Weight % Resin/Crosslinker Weight Ratio: 65/35 Catalyst based on resin solids: 0.3 Weight % ______________________________________

The curable compositions N and O were applied on Bonderite 100 Cold Roll Steel (CRS) substrate panels by means of a #46 wire cator applicator and were cured by heating at a cure schedule of 30 minutes at 121.degree. C. (250.degree. F.). The cured film was evaluated by standard methods widely accepted by the coatings industry. The physical properties of the cured films obtained by curing Composition N and Composition O are listed in Table 10. Table 10 shows that the composition cure rates are comparable. This is unexpected since the acidity of sulfonimide catalysts is lower than p-toluenesulfonic acid for comparable cures. The potlife is also improved and the appearance of the cured film is better.

It is concluded from this example that sulfonimide cure catalysts of this invention are effective catalysts in solvent-based coatings, and that they cure at a rate comparable to the widely used sulfonic acid catalysts. ______________________________________ Cure Response of Solvent-Based Coatings Comparison of Sulfonimide and Sulfonic Acid Catalysts COMPOSITION COMPOSITION N.sup.(a)   O.sup.(b) ______________________________________ Film Thickness Mils         1.65-1.75     1.65-1.75 mm           0.042-0.044   0.042-0.044 121.degree. C./30 min Cure Hardness, KHN.sub.25 8.0           9.0 MEK Rubs     200+          200+ 135.degree. C./30 min Cure Hardness, KHN.sub.25 9.7           9.6 MEK Rubs     .sup.  200+.sup.(c) 200+ 149.degree. C./30 min Cure Hardness, KHN.sub.25 10.1          10.0 MEK Rubs     200+          200+ ______________________________________ .sup.(a) Composition containing dibenzonesulfonimide. .sup.(b) Composition containing p-toluenesulfonic acid. .sup.(c) Film scratches off with difficulty using fingernail immediately after 200 double rubs (film scratched while wet with MEK).

This example illustrates lower yellowing of sulfonimide-cured compositions relative to sulfonic acid cured compositions in base coat/clear coat solvent-based coatings under overbake cure conditions.

The base coat was prepared by a procedure similar to the procedure described in Example 10 using the following ingredients and conditions: Weight (g) ______________________________________ Base Coat Formulation A JONCRYL .RTM. 500 Acrylic 60.00 Resin Solids (80% Solids) OR-650 Titanium Dioxide Pigment 80.00 Methyl Amyl Ketone      18.00 BYK .RTM. P 104-S Wetting Agent 0.80 (a product of Byk-Mallinckrodt Company, Wallingford, CT) Base Coat Formulation B JONCRYL .RTM. 500 Acrylic 40.00 Resin Solids (80% Solids) CYMEL .RTM. 303 Crosslinking Agent 20.00 n-Butanol               15.00 p-Toluenesulfonic Acid (40% Solution) 1.00 ______________________________________

After grinding Formulation A in a 3-roll mill, Formulation B was added to ground Formulation A, and applied to ED-3150A primed EP1-P60 panel, available from Advanced Coating Technologies, Hillsdale, Mo., using a #34 wire cator applicator. The resulting panels were cured at 121.degree. C. (250.degree. F.) for 15 minutes, and thereafter the clear topcoat Composition P and Composition Q (infra) were each applied to two separate panels coated with the base coat. Weight (g) ______________________________________ COMPOSITION P JONCRYL .RTM. 500 Acrylic 81.30 Resin (80% Solids) CYMEL .RTM. 1170 Crosslinking Agent 35.00 di-Benzenesulfonimide   0.52 n-Butanol               16.00 Xylene                  21.50 Non-Volatiles: 65 Wt. % Resin/Crosslinker Weight Ratio: 65/35 Catalyst based on Resin Solids: 0.5 Wt. % COMPOSITION Q JONCRYL .RTM. 500 Acrylic 81.30 Resin (80% Solids) CYMEL .RTM. 1170 Crosslinking Agent 35.00 p-Toluenesulfonic Acid  0.30 n-Butanol               16.00 Xylene                  21.50 Non-Volatiles: 65 Wt. % Resin/Crosslinker Weight Ratio: 65/35 Catalyst based on Resin Solids: 0.3 Wt. % ______________________________________

The clear coat Compositions P and Q were each applied onto base-coated panels using a #46 wire cator applicator and thereafter cured; first at 121.degree. C./30 minute cure followed by an additional 149.degree. C./30 minute cure, simulating overbake condition which commonly occur in a coating process. The results are summaried in Table 11.

It is concluded from the results in Table 11 that the solvent-based coatings compositions of the invention containing the novel sulfonimide cure catalysts of the invention have better overbake tolerance than sulfonic acid catalyzed compositions when cured under overbake conditions. ______________________________________ Yellowing of Solvent-Based Base-Coat/Clear-Coat Coatings Under Overbake Conditions Comparison of Sulfonimide and Sulfonic Acid Catalysts COMPOSITION COMPOSITION P.sup.(a)  Q.sup.(b) ______________________________________ Film Thickness mils/mm Base Coat      1.26/0.032   1.28/0.032 Clear Coat     1.59/0.040   1.48/0.038 Hardness, KHN.sub.25 (Clear Coat) 121.degree. C./30 min cure 0.8          8.0 121.degree. C./30 min cure + 9.3          10.3 149.degree. C./30 min overbake Yellow Index 121.degree. C./30 min cure -1.56        -1.28 121.degree. C./30 min cure + +2.18        +5.32 149.degree. C./30 min overbake Total Color Change 2.71         4.39 (difference of E) ______________________________________ .sup.(a) Composition containing dibenzonesulfonimide. .sup.(b) Composition containing ptoluenesulfonic acid.

This example illustrates an embodiment in which a 1:1 blend of sulfonimide cure catalyst and polyfunctional material is used to obtain Composition R, which is a curable composition containing catalyst/polyfunctional material combination of the invention.

A mixture of dibenzenesulfonimide (10.0 g) and Alftalat.RTM. AN745 solid polyester (10.0 g) was melt-mixed at 150.degree. C. The resinous material thus obtained was cooled to room temperature and the resulting solids crushed to give a catalyst/polyfunctional material combination usable in the method of the invention. COMPOSITION R           Weight (g) ______________________________________ Arakote .RTM. 3109 polyester (solid) 93.50 Powderlink .RTM. 1174 crosslinking agent (solid) 6.00 Catalyst/polyfunctional material combination 1.00 of this example as prepared above containing 1:1 weight ratio of dibenzene- sulfonimide and Alftalat .RTM. AN745 polyester Benzoin (a solid additive) 1.40 R960-48 Titanium dioxide pigment 40.00 Resiflow P67 flow control agent 1.30 ______________________________________

Composition R was cured at 190.degree. C./20 min by the method of EXAMPLE 2. The results are summarized in TABLE 12. As seen from Table 12, good film appearance (no wrinkles), film properties such as cure, impact, and gloss, and resistance properties such as resistance to humidity and salt spray are obtained. This embodiment, therefore, is within the scope of the invention. ______________________________________ Powder Coatings Prepared by Using a Catalyst/Polyfunctional Material Combination.sup.a in a Curable Composition (Composition R) ______________________________________ FILM APPEARANCE   Orange Peel, Microblisters, Microcraters in some areas, No Wrinkles FILM PROPERTIES Film Thickness (mils)            1.3-2.4 (mm)              0.033-0.061 Hardness, KHN.sub.25 11.2 MEK Rubs          200+ Impact F/R (in-lb) 160/160 Color, Tristimulus -0.08 Gloss, 60.degree.        95.3 20.degree.        83.3 RESISTANCE PROPERTIES Humidity (60.degree. C.), Time (hrs) 504 Appearance After Testing No Change Salt spray, Time (hrs) 1008 Creepage (mm)     0 Appearance After Testing No Change ______________________________________ a. Dibenzenesulfonimide/Alftalat .RTM. AN745 Polyester (1:1 weight ratio) combination at 1 wt % level based on total resin solids, corresponding to 0.5 wt % level of dibenzonesulfonimide based on total resin solids in Composition R.

The experiment of Example 12 was repeated with the following modifications: of dibenzenesulfonimide. 13, part 1 (above) instead of the dibenzenesulfonimide masterbatch in Composition R of Example 12. in Composition S with Alftalat.RTM. AN745 polyester. in Composition S with Rucote.RTM. 101 polyester.

Table 13 summarizes the results obtained by curing the compositions S, T, and U by the 190.degree. C./20 min protocol described in Example 12. The embodiments represented by Compositions S, T, and U, having good film properties, are also within the scope of the invention. __________________________________________________________________________ EXAMPLE 13 Powder Coatings Prepared by Using Phenyl-p-tolylsuflonimide/ Alftalat AN745 Polyester Combination COMPOSITION COMPOSITION COMPOSITION S          T        U __________________________________________________________________________ FILM APPEARANCE Orange Peel Orange Peel Orange Peel Microblisters Microblisters Microblisters Microcraters on edges FILM PROPERTIES Film Thickness (mils)          1.5-3.1    1.7-2.4  1.6-2.4 (mm)            0.038-0.079 0.043-0.061 0.041-0.061 Hardness, KHN.sub.25 11.8       11.3     11.1 MEK Rubs        200+       200+     200+ Impact F/R (in-lb) 160/160    160/160  160/160 Color, Tristimulus -0.09      -0.09    -0.09 Gloss, 60.degree.      93.2       94.0     91.1 20.degree.      72.3       72.3     75.4 RESISTANCE PROPERTIES Humidity (60.degree. C.), Time (hrs) 504        504      504 Appearance After Testing No Change  No Change No Change Salt Spray, Time (hrs) 1056       1056     528 Creepage (mm)   0          0        0 Appearance After Testing No Change  few blisters blisters __________________________________________________________________________

Although the present invention has been described with reference to certain preferred embodiments, it is apparent that modifications and changes thereof may be made by those skilled in the art, without departing from the scope of this invention as defined by the appended claims.

## Claims

1. A curable composition comprising: groups, and crosslinking agents, wherein the weight ratio of crosslinker to polyfunctional material (ii:iii) is from about 1:40 to about 3:1, and wherein the sulfonimide cure catalyst is selected from the group consisting of: wherein each of the R groups is, independently, selected from the group consisting of group of 1 to 20 carbon atoms, or mixtures thereof, heterocyclic aromatic rings substituted by R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 groups, wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 groups are the same or different groups selected from the group consisting of hydrogen, fluoro, alkyl, fluoroalkyl, aryl, haloaryl, carboxy, mercapto, vinyl, chloro, bromo, cyano, nitro, sulfonyl, acyl, alkoxycarbonyl, alkoxy, perfluoroalkoxy, hydroxy, amino, acylamino, alkoxycarbonylamino, carbamoyl, aminocarbonyl, N-alkyl aminocarbonyl and N,N-dialkyl aminocarbonyl groups, and meaning as the alkyl and aryl groups (a1) and (a2), and wherein the Z group is wherein n groups of the --(R'--SO.sub.2 NH--SO.sub.2)-- units may be the same or different, and the R' group in each of the n units is independently selected from the group consisting of 20 carbon atoms, carbocyclic or heterocyclic aromatic rings substituted by R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 groups, wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 groups are the same or different groups selected from the group consisting of hydrogen, fluoro, alkyl, fluoroalkyl, aryl, haloaryl, carboxy, mercapto, vinyl, chloro, bromo, cyano, nitro, sulfonyl, acyl, alkoxycarbonyl, alkoxy, perfluoroalkoxy, hydroxy, amino, acylamino, alkoxycarbonylamino, carbamoyl, aminocarbonyl, N-alkyl aminocarbonyl and N,N-dialkyl aminocarbonyl groups, and the same meaning as the alkylene and arylene groups (b1) and (b2); wherein P is a polyfunctional group or a polymer of a number average molecular weight greater than 500, R" is an alkyl or aryl group of 1 to 20 carbon atoms, and n is 2 or greater; and

2. The composition of claim 1 wherein the reactive group of the polyfunctional aminoplast reactive material (iii) is selected from a group consisting of carboxy, hydroxy, carbamate, amino, amido, mercapto group and mixtures thereof.

3. The composition of claim 2 wherein the polyfunctional material (iii) has a number average molecular weight between from about 100 to about 50,000.

4. The composition of claim 2 wherein the polyfunctional material (iii) is a solid at 40.degree. C.

5. The composition of claim 2 wherein the polyfunctional material is a hydroxy functional acrylic resin or a hydroxy functional polyester resin.

6. The composition of claim 2 wherein the polyfunctional material is a carboxy functional acrylic resin or a carboxy functional polyester resin.

7. The composition of claim 1 wherein the weight ratio of the sulfonimide catalyst (i) to the aminoplast crosslinking agent (ii) is from about 1:4 to about 1:400.

8. The composition of claim 1 wherein the sulfonimide cure catalyst is from about 0.01 to about 10 weight percent of the total weight of the resin forming ingredients in the composition.

9. The composition of claim 1 wherein the aminoplast resin (ii) is represented by the formula: wherein n is the number of R groups and is at least 2, A is a substituted polyamino anchor molecule connected to n(R) groups via the amino nitrogen, and each R is independently selected from the group consisting of hydroxymethyl, alkoxymethyl, an aminoplast containing oligomeric group, hydrogen, alkyl of 1 to 10 carbon atoms, and mixtures thereof; with the proviso that at least two R groups are selected from the group consisting of hydroxymethyl, alkoxymethyl, an aminoplast containing oligomeric group, and mixtures thereof.

10. The composition of claim 9 wherein the polyamino anchor molecule of A--(R).sub.n is derived from monomeric or oligomeric polyamino molecules selected from the group consisting of glycoluril, melamine, benzoguanamine, cyclohexanecarboguanamine, acetoguanamine, urea, substituted linear and cyclic ureas, polycarbamates, polyhydantoins, polyamides and mixtures thereof.

11. The composition of claim 9 wherein the aminoplast crosslinking agent (ii) is an N-substituted glycoluril represented by the formula: ##STR26## wherein at least two of the R groups are selected from the group consisting of hydroxymethyl, methoxymethyl, ethoxymethyl, propoxymethyl, butoxymethyl, pentoxymethyl, hexoxymethyl, heptoxymethyl, octoxymethyl, nonoxymethyl, decoxymethyl, and mixtures thereof, and the remaining R groups are hydrogen, alkyl, or glycoluril group-containing oligomeric moieties.

12. The composition of claim 11 wherein the number of the methoxymethyl groups is from about 2.5 to about 4.0.

13. The composition of claim 12 wherein the equivalent weight of the glycoluril is from about 79.5 to about 127.2.

14. The composition of claim 11 wherein the glycoluril crosslinking agent is represented by the formula: ##STR27##

15. The composition of claim 1 wherein the sulfonimide cure catalyst is represented by the formula: ##STR28## wherein X is independently selected from the group consisting of hydrogen, chloro, methyl, alkyl, nitro, amino, cyano, alkoxycarbonyl, carboxyl, acyl, M-alkylamino-carbonyl, and N,N-dialkylaminocarbonyl groups.

16. Composition of claim 15 wherein the sulfonimide cure catalyst is represented by the formula: ##STR29##

17. Composition of claim 15 wherein the sulfonimide cure catalyst is represented by the formula: ##STR30##

18. Composition of claim 15 wherein the sulfonimide cure catalyst is represented by the formula: ##STR31##

19. Composition of claim 1 wherein the sulfonimide cure catalyst is represented by the formula: ##STR32##

20. The composition of claim 1 contained in a liquid medium.

21. The composition of claim 20 wherein the medium is a solvent for ingredients (i), (ii), and (iii).

22. The composition of claim 21 wherein the solvent is selected from water, alcohols, ketones, ethers, esters, aliphatic hydrocarbons, aromatic hydrocarbons, halogenated hydrocarbons, and mixtures thereof.

23. The composition of claim 20 wherein the sulfonimide cure catalyst of ingredient (i) is represented by the formula: ##STR33## wherein X is independently selected from the group consisting of hydrogen, chloro, methyl, alkyl, nitro, amino, cyano, alkoxycarbonyl, carboxyl, acyl, N-alkylamino-carbonyl, and N,N-dialkylaminocarbonyl groups.

24. The composition of claim 23 wherein the sulfonimide cure catalyst is represented by the formula: ##STR34##

25. The composition of claim 23 wherein the sulfonimide cure catalyst is represented by the formula: ##STR35##

26. The composition of claim 23 wherein the sulfonimide cure catalyst is represented by the formula: ##STR36##

27. The composition of claim 20 wherein the sulfonimide cure catalyst is represented by the formula: ##STR37##

28. The composition of claim 1 wherein at least one of ingredients (i), (ii), and (iii) is a solid at 40.degree. C.

29. The composition of claim 28 wherein all of ingredients (i), (ii), and (iii) are solids.

30. The composition of claim 28 in the form of a flowable powder.

31. A solid object formed by thermally curing the composition of claim 1.

32. The composition of claim 1 comprising: wherein each of the R groups is, independently, selected from the group consisting of group of 1 to 20 carbon atoms, or mixtures thereof, heterocyclic aromatic rings substituted by R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 groups, wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 groups are the same or different groups selected from the group consisting of hydrogen, fluoro, alkyl, fluoroalkyl, aryl, haloaryl, carboxy, mercapto, vinyl, chloro, bromo, cyano, nitro, sulfonyl, acyl, alkoxycarbonyl, alkoxy, perfluoroalkoxy, hydroxy, amino, acylamino, alkoxycarbonylamino, carbamoyl, aminocarbonyl, N-alkyl aminocarbonyl and N, N-dialkyl aminocarbonyl groups, and meaning as the alkyl and aryl groups (a1) and (a2), and wherein the Z group is ##STR38## and (iii) a hydroxy functional polyester resin.