# Patent

## Title
Detergent bar composition and manufacturing process comprising colloidal

## Abstract

This application is a continuation-in-part of application Ser. No. 09/497,239 filed Feb. 3, 2000 now abandoned which is a continuation-in-part of patent application Ser. No. 09/430,492 filed Oct. 29, 1999 abandoned, which is a continuation-in-part of application Ser. No. 09/371,431 filed Aug. 10, 1999 abandoned.

## Background
The present invention is directed to transparent/translucent moisturizing/cosmetic/personal cleansing bars (hereinafter "cleansing bars") having a melting point of at least 55.degree. C. and increased hardness/durability, primarily due to the bars containing polyhydric solvents, in an amount of about 15% to about 65% by weight, preferably about 25% to about 65% by weight, including (A) one or more polyhydric solvents that include at least three hydroxyl groups, in an amount of 5% by weight to about 35% by weight, and (B) one or more polyhydric solvents that include two hydroxyl groups, e.g., diols or glycols, in an amount of about 10% by weight to about 30% by weight. The transparent/translucent cleansing bars contain about 4% to about 13% by weight water, preferably about 4% to about 12% water, most preferably about 7% to about 12% water. The transparent/translucent cleansing bars lose less water with time via atmospheric evaporation and have increased durability and avoid melting and deformation during shipping and handling while maintaining transparency/translucency. The bars are manufactured by forming a molten composition in liquid form, and pouring the molten composition into a mold to harden, upon cooling. The bar can be manufactured without a monohydric alcohol, or may contain a monohydric alcohol in relatively small amounts, e.g., 0.1% to 4%, preferably 0.5% to 2% by weight, for increased clarity. The bars can be manufactured to include relatively high foam, as personal cleansing/moisturizing bars, or may contain low foam surfactants as moisturizing/facial cleansing/cosmetic bars.

Transparent personal cleansing bars are well known in the art. They are prepared by dissolving soap in a combination of water soluble solvents (normally urea and/or polyhydric alcohols) with the addition of surfactants to improve the cleansing and lathering characteristics of the product. Water is also part of the composition and is incorporated into the bars by the direct addition of water or added from the surfactants or soap that form part of the cleansing bars.

A common problem with transparent personal cleansing bars is that they have a melting point of about 50.degree. C., which is too close to the temperatures that are reached during shipping or storage of the products. When shipped or stored at temperatures approaching 50.degree. C., the solid personal cleansing bars either melt or become sufficiently soft to deform. Another common problem of the personal cleansing bars is that they lose more weight than regular, opaque cleansing bars due to their relatively higher content of water, and the presence of volatile solvents, such as monohydric alcohols, e.g., ethanol.

U.S. Pat. No. 5,041,234 to Instone, et al. discloses a transparent personal cleansing bar which contains greater than 40 percent by weight of soap (high soap bar). Like other "high soap" transparent bars, the bars disclosed by Instone et al. have good lather, low smear, and good bar hardness. Such high soap level transparent bars, however, are rather harsh to the skin. Another drawback to such bars is that their processing generally require the use of at least about 5% by weight volatile, short chain monohydric alcohols, or require special milling to obtain transparency.

Transparent bars which contain lower levels of soap are also known in the art. "Lower soap" transparent bars contain less than 40 percent by weight of soap. U.S. Pat. No. 5,002,685 to Chambers et al. discloses a transparent bar made with 25% to 34% by weight soap, 5% to 15% by weight monohydric alcohol, 15% to 30% by weight sugar and/or cyclic polyol, and 15% to 30% by weight water. Unfortunately, transparent bars which require the use of at least about 5% by weight monohydric alcohols are prone to excessive weight loss due to the volatile nature of most monohydric alcohols. Such transparent bars are also more expensive to prepare and require special equipment designed to accommodate the explosion hazard associated with most monohydric alcohols.

Zyngier et al. U.S. Pat. No. 5,703,025 discloses a monohydric alcohol-free process for making pour molded transparent and translucent cleansing bars that have good hardness, are mild to the skin, low smearing and good lathering. These bars, however, require at least 14% by weight water, particularly 14% to 32% by weight water, and preferably more than 20% by weight water, so that the bars melt and deform at a relatively low temperature, e.g., about 50.degree. C., and readily lose weight via water evaporation at room temperature and pressure. As stated in the '025 patent, "The water level within the personal cleansing bars prepared by the process of the present invention is critical to obtain a transparent bar having desirable hardness characteristics. When the water is less than about 14 parts by weight of the bar, the bar may not be transparent."

A transparent/translucent cleansing bar containing 20% by weight water loses about 17% of its original weight when exposed to room temperature for three weeks, whereas a bar containing only 10% by weight water only loses about 7.5% of its original weight under the same, standard temperature (room temperature) and pressure conditions.

In brief, the present invention is directed to a composition and a method of preparing a transparent/translucent moisturizing/cosmetic/personal cleansing bar containing polyhydric solvents, in an amount of about 15% to about 65% by weight, preferably about 25% to about 65% by weight, including one or more polyhydric solvents that include at least three hydroxyl groups, in an amount of 5% by weight to about 35% by weight, and one or more polyhydric solvents that include two hydroxyl groups, e.g., diols or glycols, in an amount of about 10% by weight to about 30% by weight. The transparent/translucent cleansing bars contain a final water content of about 13% by weight or less, preferably about 4% to about 12%, more preferably about 7% to about 12% water, thereby increasing the melting temperature of the bar to prevent melting and reduce deformation during storage and handling, increasing its hardness and durability, and substantially reducing the tendency of the bar to lose weight over time by evaporation of water by exposure to room temperature.

Accordingly, one aspect of the present invention is to provide a transparent/translucent moisturizing/cosmetic/personal cleansing bar that is more durable, has a relatively high melting point, and a lower water content than prior art personal cleansing bars, while maintaining clarity (transparency).

Another aspect of the present invention is to provide a transparent/translucent moisturizing/cosmetic/personal cleansing bar that is less susceptible to being deformed by heat and/or pressure and includes a combination of polyhydric solvents (1) having three or more hydroxyl groups; and (2) two hydroxyl groups, while providing a bar having a minimum amount of water (4-13% by weight) so that hydrolyzable bar components, such as antibacterial components, e.g., triclocarban (TCC), maintain more of their efficacy, for longer periods of time.

The FIGURE is a graph that compares the hardness, in Newtons, of the preferred bar composition of the present invention (Example 6--PREFERRED) to the same composition containing 17.7% by weight water, prior to dehydration (Example 6--FORMED).

The transparent/translucent personal cleansing bars of the present invention include the following components, after manufacture and may contain additional additives, such as antibacterial agents, dyes, perfumes, fillers, polymers, silicones, encapsulated materials, and the like: More       Most Range  Preferred Preferred  Preferred %        %         %          % water-soluble polyhydric  15-65    25-65     30-55      35-50 solvent(s), 3.sup.+ -OH, e.g.,     5-35    10-30     15-25      17-22 glycerine, sugar alcohols, e.g., sorbitol and the like 2-OH, e.g.,           10-30    15-30     20-30      22-27 propylene glycol, polyethylene glycol, dipropylene glycol monohydric alcohol,    0-4    0.5-3     0.5-2     0.75-1.5 e.g., ethanol soap                   5-35     8-30     10-25      10-15 surfactant(s)          5-40     5-30      8-25      10-20 water                  4-13     4-12      7-12      10-12

The term "soap", for purposes of describing this component of the transparent/translucent cleansing bar of the present invention, has the meaning as normally understood by those skilled in the art: monovalent salts of fatty monocarboxylic acids having a carbon chain length of from 12 to 24, preferably from 14 to 18 carbon atoms. These monovalent salts would normally be sodium salts, although some cations, such as K, Mg or alkanolammonium ions could be used. The preferred insoluble fatty acid soap is at least 90% by weight, more preferably at least 95% by weight selected from the group consisting of sodium myristate, sodium palmitate, sodium stearate and mixtures of any two or more thereof. Other insoluble soaps, particularly higher fatty acid insoluble soaps, can also be used.

This invention relates to the transparent cleansing/cosmetic compositions of the present invention, in a solid form, and method of manufacturing same. The transparent/translucent cosmetic/moisturizing cleansing bars of the present invention have a reduced water content, thereby increasing the melting point of the bars to at least about 60.degree. C., preferably at least about 65.degree. C., with reduced weight loss and increased durability and hardness.

The products of this invention can be prepared with reduced water content, for example, by using anhydrous polyhydric alcohols and/or anhydrous surfactants or by removing water from the composition initially formed with a higher water content.

Significant performance improvements are obtained by combining water-soluble polyhydric solvents having at least three hydroxyl groups (3.sup.+ -OH) with water-soluble polyhydric solvents having two hydroxyl groups (2-OH). Significant performance improvements also are obtained by reducing the water content to a maximum of about 13% by weight, preferably in the range of about 4% to about 12% by weight, more preferably about 7% to about 12% by weight, most preferably about 10% to about 12% by weight water. The melting point of the bar is increased to at least 55.degree. C., which is above the temperatures that are expected to be reached during shipping and storage, thus avoiding melting and deformation of the personal cleansing bars.

Another benefit to the composition of the present invention is the reduction of weight loss. A bar containing about 20% by weight water loses about 17% of its original weight when exposed to room temperature (25.degree. C.) for three weeks, whereas a bar with a water content of 10% by weight only loses about 7.5% of its original weight under the same conditions.

The bars of the present invention, include about 5% to about 40% by weight surfactants, preferably about 5% to about 30% by weight, more preferably about 8% to about 25%, most preferably about 10% to about 20% by weight surfactants.

The surfactant can be an anionic surfactant, a cationic surfactant, a nonionic surfactant, an ampholytic or amphoteric surfactant or a compatible mixture of surfactants.

Suitable anionic surfactants include, but are not limited to, compounds in the classes known as alkyl sulfates, alkyl ether sulfates, alkyl ether sulfonates, sulfate esters of an alkylphenoxy polyoxyethylene ethanol, alpha-olefin sulfonates, beta-alkoxy alkane sulfonates, alkylaryl sulfonates, alkyl monoglyceride sulfates, alkyl monoglyceride sulfonates, alkyl carbonates, alkyl ether carboxylates, fatty acids, sulfosuccinates, sarcosinates, oxtoxynol or nonoxynol phosphates, taurates, fatty taurides, fatty acid amide polyoxyethylene sulfates, isethionates, or mixtures thereof. Additional anionic surfactants are listed in McCutcheon's Emulsifiers and Detergents, 1993 Annuals, (hereafter McCutcheon's), McCutcheon Division, MC Publishing Co., Glen Rock, N.J., pp. 263-266, incorporated herein by reference. Numerous other anionic surfactants, and classes of anionic surfactants, are disclosed in Laughlin et al. U.S. Pat. No. 3,929,678, incorporated herein by reference.

The cleansing bars of the present invention also can contain nonionic surfactants. Typically, a nonionic surfactant has a hydrophobic base, such as a long chain alkyl group or an alkylated aryl group, and a hydrophilic chain comprising a sufficient number (i.e., 1 to about 30) of ethoxy and/or propoxy moieties. Examples of classes of nonionic surfactants include ethoxylated alkylphenols, ethoxylated and propoxylated fatty alcohols, polyethylene glycol ethers of methyl glucose, polyethylene glycol ethers of sorbitol, ethylene oxide-propylene oxide block copolymers, ethoxylated esters of fatty (C.sub.8 -C.sub.18) acids, condensation products of ethylene oxide with long chain amines or amides, and mixtures thereof. Fatty alcohol ethoxylates (FAE) are preferred for dissolving antibacterial compounds, such as triclocarban (TCC).

Exemplary nonionic surfactants include, but are not limited to, methyl gluceth-10, PEG-20 methyl glucose distearate, PEG-20 methyl glucose sesquistearate, C.sub.11-15 pareth-20, ceteth-8, ceteth-12, dodoxynol-12, laureth-15, PEG-20 castor oil, polysorbate 20, steareth-20, polyoxyethylene-10 cetyl ether, polyoxyethylene-10 stearyl ether, polyoxyethylene-20 cetyl ether, polyoxyethylene-10 oleyl ether, polyoxyethylene-20 oleyl ether, an ethoxylated nonylphenol, ethoxylated octylphenol, ethoxylated dodecylphenol, or ethoxylated fatty (C.sub.6 -C.sub.22) alcohol, including 3 to 20 ethylene oxide moieties, polyoxyethylene-20 isohexadecyl ether, polyoxyethylene-23 glycerol laurate, polyoxy-ethylene-20 glyceryl stearate, PPG-10 methyl glucose ether, PPG-20 methyl glucose ether, polyoxyethylene-20 sorbitan monoesters, polyoxyethylene-80 castor oil, polyoxyethylene-15 tridecyl ether, polyoxyethylene-6 tridecyl ether, laureth-2, laureth-3, laureth-4, PEG-3 castor oil, PEG 600 dioleate, PEG 400 dioleate, and mixtures thereof.

Numerous other nonionic surfactants are disclosed in McCutcheon's Detergents and Emulsifiers, 1993 Annuals, published by McCutcheon Division, MC Publishing Co., Glen Rock, N.J., pp. 1-246 and 266-272; in the CTFA International Cosmetic Ingredient Dictionary, Fourth Ed., Cosmetic, Toiletry and Fragrance Association, Washington, D.C. (1991) (hereinafter the CTFA Dictionary) at pages 1-651; and in the CTFA Handbook, at pages 86-94, each incorporated herein by reference.

In addition to anionic and nonionic surfactants, cationic, ampholytic, and amphoteric surfactants can be used in the cleansing bars of the present invention. Cationic surfactants include amine oxides, for example.

Ampholytic surfactants can be broadly described as derivatives of secondary and tertiary amines having aliphatic radicals that are straight chain or branched, and wherein one of the aliphatic substituents contains from about 8 to 18 carbon atoms and at least one of the aliphatic substituents contains an anionic water-solubilizing group, e.g., carboxy, sulfonate, or sulfate. Examples of compounds falling within this description are sodium 3-(dodecylamino)propionate, sodium 3-(dodecylamino)-propane-1-sulfonate, sodium 2-(dodecylamino)ethyl sulfate, sodium 2-(dimethylamino)octadecanoate, disodium 3-(N-carboxymethyl-dodecylamino)propane-1-sulfonate, disodium octadecyliminodiacetate, sodium 1-carboxymethyl-2-undecylimidazole, and sodium N,N-bis(2-hydroxyethyl)-2-sulfato-3-dodecoxypropylamine.

More particularly, one class of ampholytic surfactants include sarcosinates and taurates having the general structural formula ##STR1## ampholytic surfactants, is C.sub.11 through C.sub.21 alkyl, R.sup.2 is hydrogen or C.sub.1 -C.sub.2 alkyl, Y is CO.sub.2 M or SO.sub.3 M, M is an alkali metal, and n is a number 1 through 3.

Another class of ampholytic surfactants is the amide sulfosuccinates having the structural formula ##STR2##

The following classes of ampholytic surfactants also can be used: ##STR3##

Additional classes of ampholytic surfactants include the phosphobetaines and the phosphitaines.

Specific, nonlimiting examples of ampholytic surfactants useful in the present invention are sodium coconut N-methyl taurate, sodium oleyl N-methyl taurate, sodium tall oil acid N-methyl taurate, sodium palmitoyl N-methyl taurate, cocodimethylcarboxymethylbetaine, lauryldimethylcarboxymethylbetaine, lauryldimethylcarboxyethylbetaine, cetyldimethylcarboxymethylbetaine, lauryl-bis-(2-hydroxyethyl)carboxymethylbetaine, oleyldimethylgammacarboxypropylbetaine, lauryl-bis-(2-hydroxypropyl)-carboxyethylbetaine, cocoamidodimethylpropylsultaine, stearylamidodimethylpropylsultaine, laurylamido-bis-(2-hydroxyethyl)propylsultaine, disodium oleamide PEG-2 sulfosuccinate, TEA oleamido PEG-2 sulfosuccinate, disodium oleamide MEA sulfosuccinate, disodium oleamide MIPA sulfosuccinate, disodium ricinoleamide MEA sulfosuccinate, disodium undecylenamide MEA sulfosuccinate, disodium wheat germamido MEA sulfosuccinate, disodium wheat germamido PEG-2 sulfosuccinate, disodium isostearamideo MEA sulfosuccinate, cocoamphoglycinate, cocoamphocarboxyglycinate, lauroamphoglycinate, lauroamphocarboxyglycinate, capryloamphocarboxyglycinate, cocoamphopropionate, cocoamphocarboxypropionate, lauroamphocarboxypropionate, capryloamphocarboxypropionate, dihydroxyethyl tallow glycinate, cocamido disodium 3-hydroxypropyl phosphobetaine, lauric myristic amido disodium 3-hydroxypropyl phosphobetaine, lauric myristic amido glyceryl phosphobetaine, lauric myristic amido carboxy disodium 3-hydroxypropyl phosphobetaine, cocoamido propyl monosodium phosphitaine, lauric myristic amido propyl monosodium phosphitaine, and mixtures thereof.

The transparent bar prepared according to the process of the present invention comprises from about 15% to about 65% by weight, preferably about 25% to about 65% by weight, more preferably from about 30% to about 55% by weight, most preferably about 35% to about 50% by weight of a combination of water-soluble polyhydric organic solvents including (A) about 5% to about 35% by weight water-soluble polyhydric solvent(s) having three or more hydroxyl groups (3.sup.+ -OH), and (B) about 10% to about 30% by weight polyhydric solvent(s) having two hydroxyl groups (2-OH). Preferred water soluble organic polyols having two hydroxyl groups (2-OH) include those selected from the group consisting of: propylene glycol; dipropylene glycol; butylene glycol; ethylene glycol; 1,7-heptanediol; monoethylene glycols, polyethylene glycols, polypropylene glycols of up to 8,000 molecular weight; mono-C.sub.1-4 alkyl ethers of any of the foregoing; and mixtures thereof. Preferred water-soluble polyhydric solvents that have at least three hydroxyl groups (3.sup.+ -OH) include glycerine, and any sugar alcohol, such as sorbitol.

Examples of suitable sugar alcohols include:

Tetritols:

Erythritol, threitol, D-threitol, L-threitol, and D,L-threitol.

Pentitols:

Ribitol, arabinitol, D-arabinitol, L-arabinitol, D,L-arabinitol and xylitol.

Hexitols:

Allitol, dulcitol (galacitol), glucitol, sorbitol, (D-glucitol), L-glucitol, D,L-glucitol, D-mannitol, L-mannitol, D,L-mannitol, altritol, D-altritol, L-altritol, D,L-altritol, iditol, D-iditol, and L-iditol.

Disaccharide alcohols:

Maltitol, lactitol and isomalt.

The fatty acid soap used in the present invention comprises sodium soaps. However, low levels of non-sodium soaps such as potassium, magnesium, and/or triethanolammonium (TEA) soaps are permissible. Such non-sodium soaps, when used, are preferably used at a level of from 0% to 10% by weight, preferably from 0% to 5% by weight of the bar soap.

The transparent/translucent bars of the present invention also can contain optional ingredients well known to persons skilled in the art. Such optional ingredients typically are present, individually, from 0% to about 5%, by weight, of the composition, and, collectively, from 0% to about 20%, by weight, of the composition.

Suitable optional ingredients include dyes, fragrances and one or more antibacterial compounds(s), that are present in a sufficient amount to perform their intended function and do not substantially adversely affect the transparency of the composition.

Classes of optional ingredients include, but are not limited to, dyes, fragrances, pH adjusters, thickeners, fillers, viscosity modifiers, buffering agents, foam stabilizers, antioxidants, foam enhancers, chelating agents, opacifiers, sanitizing or anti-microbial agents, preservatives, polymers, silicones, encapsulated materials, and similar classes of optional ingredients known to persons skilled in the art.

Specific classes of optional ingredients include alkanolamides as foam boosters and stabilizers; gums and polymers as thickening agents; inorganic phosphates, sulfates, and carbonates as buffering agents; EDTA and phosphates as chelating agents; and acids and bases as pH adjusters.

Examples of preferred classes of basic pH adjusters are ammonia; mono-, di-, and tri-alkyl amines; mono-, di-, and tri-alkanolamines; alkali metal and alkaline earth metal hydroxides; and mixtures thereof. However, the identity of the basic pH adjuster is not limited. and any basic pH adjuster known in the art can be used. Specific, nonlimiting examples of basic pH adjusters are ammonia; sodium, potassium, and lithium hydroxide; monoethanolamine; triethylamine; isopropanolamine; diethanolamine; and triethanolamine.

Examples of preferred classes of acidic pH adjusters are the mineral acids and polycarboxylic acids. Nonlimiting examples of mineral acids are hydrochloric acid, nitric acid, phosphoric acid, and sulfuric acid. Nonlimiting examples of polycarboxylic acids are citric acid, glycolic acid, and lactic acid. The identity of the acidic pH adjuster is not limited and any acidic pH adjuster known in the art, alone or in combination, can be used.

In accordance with a preferred embodiment of manufacturing the moisturizing/cosmetic/personal cleansing bars of the present invention, the solvents and surfactants are added in an open agitated reaction vessel at atmospheric pressure and at a temperature sufficient to melt the fatty acids, generally at least about 70.degree. C., e.g., 70.degree. C. to 80.degree. C. The fatty acid(s) then are added, followed by raising the temperature to at least about 80.degree. C., e.g., 80-90.degree. C., prior to the addition of a neutralizing agent, preferably a sodium base, e.g., NaOH, in an amount sufficient to provide 100% neutralization of the fatty acids, to form the soap, in situ. It should be understood that the soap, i.e., sodium myristate, sodium palmitate, and/or sodium stearate, can be added in pre-manufactured form instead of being formed, in situ. At this stage of the manufacturing process, if the water content of the mixture is above 13% by weight, the temperature of the reaction mixture is raised to at least about 90.degree. C., preferably 90.degree. C. to 100.degree. C. to evaporate sufficient water to provide a composition having 4-13% by weight water, most preferably about 10-12% by weight water. It should be noted that during the above-described water evaporation or dehydration step of the manufacturing process, a small portion of the propylene glycol or other relatively low boiling solvents may evaporate together with the water. However, it has been found in the following examples that only about 0.5-2.0% of the propylene glycol is lost via evaporation during the dehydration step, and such solvent evaporation can be compensated for by the initial addition of 0.5-2.0% extra propylene glycol or other relatively low boiling polyhydric solvents at any stage of manufacture.

It should also be noted that the above-described dehydration step is unnecessary if one or more of the solvents and/or surfactants is added in anhydrous form (see Examples 3, 4, 7 and 10). Further, the dehydration step can be carried out at much lower temperatures by using a sealed reaction vessel at a pressure below atmospheric (under vacuum).

As well known in the art, the more volatile optional ingredients, such as dyes, fragrances and monohydric alcohols, should be added to the composition after cooling the molten composition, e.g., to 70.degree. C. or below, so that the volatile components are not lost to evaporation.

The cleansing bars of the present invention can be manufactured by adding the soap in sodium salt form, or the fatty acid(s) can be added together with a sodium base, such as sodium hydroxide to form the soap in situ. As shown in the following examples, the moisturizing/cosmetics cleansing bars of the present invention have sufficient clarity to provide at least 85% light transmission, generally 85-95% light transmission. In accordance with another important feature of the present invention, when the bars are frozen and then thawed (Freeze/Thaw), the clarity remains at least 90%, preferably at least 95% of its original clarity compared to about 80% clarity after Freeze/Thaw of prior art bars containing 17.7% water (see Example 6--PREFERRED vs. Example 6--FORMED). The following examples show the compositions in percentages by weight of materials added to an agitated reaction vessel designated as "ADDED"; the composition formed from the materials added, designated "FORMED"; and the final composition after removal of water, if any, designated "FINAL":

In the following examples, when the soap is made in situ by reaction of fatty acid(s) with a caustic solution, e.g., NaOH, it is preferred to add the caustic solution before the addition of the fatty acid(s) to prevent formation of gels or lumps, which would increase manufacturing time. It has also been found that color degradation is minimized by adding any sorbitol only when the percent free fatty acid(s) is in the range of about 0.1% to about 2%, preferably in the range of 0.2% to 1.5%, more preferably in the range of 0.5% to 1.0% free fatty acid(s), based on the total weight of free fatty acids and neutralized fatty acids. The following is the preferred sequence of addition: glycerine and the surfactant(s); fully neutralize the later-added fatty acids, e.g., about 95% of the required amount of caustic solution, e.g., NaOH; 80.degree. C. but below 100.degree. C.; indicator, and adjust, if required, to 0.1 to 2.0% by weight, preferably 0.2 to 1.5% (most preferred 0.5% to 1.0%) based on the total weight of free fatty acids and neutralized fatty acids, as lauric acid, adding more caustic solution or more fatty acid, e.g., stearic acid; solvents, and mix well; the batch to about 99 to 102.degree. C. with good agitation while preventing the batch from boiling. Of course, water removal under reduced pressure would require lower temperatures, the temperature depending upon the degree of applied vacuum; to 80.degree. C. Add the remaining caustic solution for complete neutralization of the fatty acids and any optional ingredients. ADDED Propylene Glycol         22.8 Glycerine                15.3 Sorbitol (70%)           15.8 Sorbitol (100%)           0.0 SLES (70%)               12.0 AOS* (40%)                0.0 FAE** (100%)              0.0 Myristic acid             7.3 Stearic acid             11.1 H.sub.2 O                 9.9 NaOH (50%)                5.8 TOTAL                   100.0 FORMED Propylene Glycol         22.8 Glycerine                15.3 Sorbitol (100%)          11.1 SLES (100%)               8.4 AOS* (100%)               0.0 FAE** (100%)              0.0 NaMyristate               8.0 NaStearate               12.0 Total Water              22.5 TOTAL                   100.0 CLARITY                  86/90 MELTING POINT (.degree. C.)     50 FINAL H.sub.2 O Removed        13.0 Propylene Glycol         26.2      Polyhydric Solvents: 54.5% 2-OH: 26.2% 3.sup.+ -OH: 28.3% Glycerine                17.6 Sorbitol                 12.7 SLES                      9.7 AOS*                      0.0 FAE**                     0.0 NaMyristate               9.2 NaStearate               13.8 Final Water              10.9 TOTAL                   100.1 *alpha olefin sulfonate **fatty alcohol ethoxylate CLARITY    84/90 MELTING POINT (.degree. C.)   60 Dry Sorbitol (no need to remove water) ADDED Propylene Glycol         26.0 Glycerine                17.0 Sorbitol (70%)            0.0 Sorbitol (100%)          13.7 SLES (70%)               12.7 AOS* (40%)                0.0 FAE** (100%)              0.0 Myristic acid            10.0 Stearic acid             12.7 H.sub.2 O                 0.0 NaOH (50%)                7.3 TOTAL                    99.4 FORMED Propylene Glycol         26.0 Glycerine                17.0 Sorbitol (100%)          13.7 SLES (100%)               8.9 AOS* (100%)               0.0 FAE** (100%)              0.0 NaMyristate              11.0 NaStearate               13.7 Total Water               9.1 TOTAL                    99.4 FINAL H.sub.2 O Removed         0 Propylene Glycol         26.0      Polyhydric Solvents: 56.7% 2-OH: 26.0% 3.sup.+ -OH: 30.7% Glycerine                17.0 Sorbitol                 13.7 SLES                      8.9 AOS*                      0.0 FAE**                     0.0       8.9 Surfactants NaMyristate              11.0 NaStearate               13.7      24.7 Soap Final Water               9.1       9.1 Water TOTAL                    99.4      99.4 Total *alpha olefin sulfonate **fatty alcohol ethoxylate CLARITY    85/90 MELTING POINT (.degree. C.)   60 High Level Of Surfactant ADDED Propylene Glycol         20.4 Glycerine                 5.0 Sorbitol (70%)            0.0 Sorbitol (100%)          10.6 SLES (70%)               13.4 AOS* (40%)                0.0 FAE** (100%)             25.0 Myristic acid             8.5 Stearic acid             10.8 H.sub.2 O                 0.0 NaOH (50%)                6.2 TOTAL                    99.9 FORMED Propylene Glycol         20.4 Glycerine                 5.0 Sorbitol (100%)          10.6 SLES (100%)               9.4 AOS* (100%)               0.0 FAE** (100%)             25.0 NaMyristate               9.3 NaStearate               11.7 Total Water               8.5 TOTAL                    99.9 FINAL H.sub.2 O Removed         0 Propylene Glycol         20.4      Polyhydric Solvents: 36.0% 2-OH: 20.4% 3.sup.+ -OH: 15.6% Glycerine                 5.0 Sorbitol                 10.6 SLES                      9.4 AOS*                      0.0 FAE**                    25.0      34.4 Surfactants NaMyristate               9.3 NaStearate               11.7      21.0 Soap Final Water               8.5       8.5 Water TOTAL                    99.9      99.9 TOTAL *alpha olefin sulfonate **fatty alcohol ethoxylate CLARITY    82/90 MELTING POINT (.degree. C.)   62 Very Low Water Content, Low Foaming, Facial Cleanser ADDED Propylene Glycol         26.1 Glycerine                17.2 Sorbitol (70%)            0.0 Sorbitol (100%)          12.6 SLES (70%)                0.0 AOS* (40%)                0.0 FAE** (100%)             12.4 Myristic acid            10.6 Stearic acid             13.4 H.sub.2 O                 0.0 NaOH (50%)                7.7 TOTAL                   100.0 FORMED Propylene Glycol         26.1 Glycerine                17.2 Sorbitol (100%)          12.6 SLES (100%)               0.0 AOS* (100%)               0.0 FAE** (100%)             12.4 NaMyristate              11.6 NaStearate               14.5 Total Water               5.6 TOTAL                   100.0 FINAL H.sub.2 O Removed         0 Propylene Glycol         26.1      Polyhydric Solvents: 55.9% 2-OH: 26.1% 3.sup.+ -OH: 29.8% Glycerine                17.2 Sorbitol                 12.6 SLES                      0.0 AOS*                      0.0 FAE**                    12.4       12.4 Surfactants NaMyristate              11.6 NaStearate               14.5       26.1 Soap Final Water               5.6       5.6 Water TOTAL                   100.0      100.0 TOTAL *alpha olefin sulfonate **fatty alcohol ethoxylate CLARITY    84/90 MELTING POINT (.degree. C.)   62 PEG-2ME ADDED Propylene Glycol         16.4 Glycerine                 0.0 Sorbitol (70%)           19.5 Sorbitol (100%)           0.0 PEG-2ME*                 10.4 SLES (70%)               19.6 AOS** (40%)               0.0 FAE*** (100%)             0.0 Myristic acid            11.0 Stearic acid             14.1 H.sub.2 O                 0.0 NaOH(50%)                 8.0 Ethanol                   1.0 TOTAL                   100.0 FORMED Propylene Glycol         16.4 Glycerine                 0.0 Sorbitol (100%)          13.7 PEG-2ME*                 10.4 SLES (100%)              13.7 AOS** (100%)              0.0 FAE*** (100%)             0.0 NaMyristate              12.1 NaStearate               15.2 Ethanol                   1.0 Total Water              17.6 TOTAL                   100.0 FINAL H.sub.2 O Removed         7.0 Propylene Glycol         17.6      Polyhydric Solvents: 43.5% 2-OH: 28.8% 3.sup.+ -OH: 14.7% Glycerine                 0.0 Sorbitol                 14.7 PEG-2ME*                 11.2 SLES                     14.8 AOS**                     0.0 FAE***                    0.0       14.8 Surfactants NaMyristate              13.0 NaStearate               16.4       29.4 Soap Ethanol                   1.0 Final Water              11.3       11.3 Water TOTAL                   100.0      100.0 TOTAL *polyethylene 2 glycol methyl ether **alpha olefin sulfonate ***fatty alcohol ethoxylate CLARITY   83/90 MELTING POINT (.degree. C.)   62 (Preferred Embodiment) ADDED Propylene Glycol              25.1 Glycerine                     6.0 Sorbitol (70%)               18.4 Sorbitol (100%)               0.0 SLES (70%)                   18.4 AOS* (40%)                    0.0 FAE** (100%)                  0.0 Myristic acid                10.3 Stearic acid                 13.1 H.sub.2 O                     1.2 NaOH (50%)                    7.5 TOTAL                       100.0 FORMED Propylene Glycol              25.1 Glycerine                     6.0 Sorbitol (100%)              12.9 SLES (100%)                  12.9 AOS* (100%)                   0.0 FAE** (100%)                  0.0 NaMyristate                  11.3 NaStearate                   14.2 Total Water                  17.7 TOTAL                       100.0 FINAL                                   PREFERRED H.sub.2 O Removed   5.0                     7.5                    10.0 Propylene Glycol  26.4 Polyhydric          27.1 Polyhydric          27.9 Polyhydric Solvents: 46.3%         Solvents: 47.5% Solvents: 47.9% 2-OH:     26.4%         2-OH:     27.1%         2-OH: 27.9% Glycerine         6.3 3.sup.+ -OH: 19.9%     6.5 3.sup.+ -OH: 20.4%     6.7 3.sup.+ -OH: 20.0% Sorbitol         13.6                    13.9                    14.3 SLES             13.6                    13.9                    14.3 AOS*              0.0                     0.0                     0.0 FAE**             0.0                     0.0                     0.0 NaMyristate      11.9                    12.2                    12.5 NaStearate       14.9                    15.3                    15.7 Final Water      13.3                    11.0                     8.5 TOTAL           100.0                   100.0                   100.0 0% H.sub.2 O 5% H.sub.2 O 7.5% H.sub.2 O 10.0% H.sub.2 O FORMED      REMOVED     REMOVED     REMOVED     REMOVED CLARITY     85/90       83/90       81/90       79/90 MELTING     50          56          62          64 POINT (.degree. C.) HARDNESS    16.2                    22.5 (N) Freeze/Thaw 72/90                   78/80 Weight Loss 10%                     4% *alpha olefin sulfonate **fatty alcohol ethoxylate Dry Sorbitol (no need to remove water) ADDED Propylene Glycol         27.1 Glycerine                 6.5 Sorbitol (70%)            0.0 Sorbitol (100%)          13.9 SLES (70%)               18.6 AOS* (40%)                0.0 FAE** (100%)              0.0 Myristic acid            11.3 Stearic acid             14.4 H.sub.2 O                 0.0 NaOH (50%)                8.2 TOTAL                   100.0 FORMED Propylene Glycol         27.1 Glycerine                 6.5 Sorbitol (100%)          13.9 SLES (100%)              13.0 AOS* (100%)               0.0 FAE** (100%)              0.0 NaMyristate              12.4 NaStearate               15.6 Total Water              11.5 TOTAL                   100.0 FINAL H.sub.2 O Removed         0 Propylene Glycol         27.1      Polyhydric Solvents: 47.5% 2-OH: 27.1% 3.sup.+ -OH: 20.4% Glycerine                 6.5 Sorbitol                 13.9 SLES                     13.0 AOS*                      0.0 FAE**                     0.0       13.0 Surfactants NaMyristate              12.4 NaStearate               15.6       28.0 Soap Final Water              11.5       11.5 Water TOTAL                   100.0      100.0 TOTAL *alpha olefin sulfonate **fatty alcohol ethoxylate CLARITY   81/90 MELTING POINT (.degree. C.)   60 ADDED Propylene Glycol         24.3 Glycerine                 5.7 Sorbitol (70%)           17.5 Sorbitol (100%)           0.0 SLES (70%)               14.3 AmphoAcetate (30%)        8.6 FAE* (100%)               0.0 Myristic acid             9.9 Stearic acid             12.6 H.sub.2 O                 0.0 NaOH (50%)                7.2 TOTAL                   100.1 FORMED Propylene Glycol         24.3 Glycerine                 5.7 Sorbitol (100%)          12.3 SLES (100%)              10.0 AmphoAcetate (100%)       2.6 FAE* (100%)               0.0 NaMyristate              10.9 NaStearate               13.6 Total Water              20.8 TOTAL                   100.1 FINAL H.sub.2 O Removed         9.0 Propylene Glycol         26.7      Polyhydric Solvents: 46.4% 2-OH: 26.7% 3.sup.+ -OH: 19.8% Glycerine                 6.3 Sorbitol                 13.5 SLES                     11.0 AmphoAcetate (100%)       2.8 FAE*                      0.0       13.8 Surfactants NaMyristate              11.9 NaStearate               15.0       26.9 Soap Final Water              12.9       12.9 Water TOTAL                   100.1      100.1 TOTAL *fatty alcohol ethoxylate CLARITY   81/90 MELTING POINT (.degree. C.)   62 ADDED Propylene Glycol         22.4 Glycerine                 5.1 Sorbitol (70%)           16.0 Sorbitol (100%)           0.0 SLES (70%)                0.0 AOS* (40%)               29.4 FAE** (100%)              0.0 Myristic acid             9.0 Stearic acid             11.5 H.sub.2 O                 0.0 NaOH (50%)                6.6 TOTAL                   100.0 FORMED Propylene Glycol         22.4 Glycerine                 5.1 Sorbitol (100%)          11.2 SLES (100%)               0.0 AOS* (100%)              11.8 FAE** (100%)              0.0 NaMyristate               9.9 NaStearate               12.4 Total Water              27.2 TOTAL                   100.0 FINAL H.sub.2 O Removed        18.0 Propylene Glycol         27.3      Polyhydric Solvents: 47.2% 2-OH: 27.3% 3.sup.+ -OH: 19.9% Glycerine                 6.2 Sorbitol                 13.7 SLES                      0.0 AOS*                     14.3 FAE**                     0.0 NaMyristate              12.0 NaStearate               15.2 Final Water              11.2 TOTAL                    99.9 *alpha olefin sulfonate **fatty alcohol ethoxylate CLARITY   81/90 MELTING POINT (.degree. C.)   58 High Soap Level - Added In Pellet Form (as Na salt) ADDED Propylene Glycol      24.1 Glycerine              5.8 Sorbitol (70%) Sorbitol (100%)       12.6 SLES (70%)            17.0 AOS* (40%)             0.0 Soap Pellets (75%)**    10.0 Myristic acid         10.1 Stearic acid          13.0 H.sub.2 O              0.0 NaOH (50%)             7.4 TOTAL                100.0 FORMED Propylene Glycol      24.1 Glycerine              6.5 Sorbitol (100%)       12.6 SLES (100%)           11.9 AOS* (100%)            0.0 Soap                   7.5 NaMyristate           11.1 NaStearate            14.1 Total Water           12.0 TOTAL                 99.7 FINAL H.sub.2 O Removed      2.0 Propylene Glycol      24.6 Polyhydric Solvents: 44.1% 2-OH:             24.6% Glycerine              6.6   3.sup.+ -OH:      19.5% Sorbitol              12.9 SLES                  12.1 AOS*                   0.0   12.1 Surfactants FAE****                7.7 NaMyristate           11.3 NaStearate            14.3   33.3              Soap Final Water           10.2   10.2              Water TOTAL                 99.7   99.7              TOTAL *alpha olefin sulfonate **C.sub.12 0.2% C.sub.14 3.0% C.sub.16 31.0% C.sub.18 16.0% C.sub.18-1 *** 45.0% C.sub.18-2 *** 4.0% C.sub.18-3 *** 1.0% ***fatty alcohol ethoxylate ****number of double bonds in C.sub.18 acid CLARITY 78/90 MELTING POINT (.degree. C.) 62

## Claims

1. A transparent, pour molded solid bar comprising, by weight: having three or more hydroxyl groups, and about 10% to about 30% having two hydroxyl groups;

2. The solid bar of claim 1, further including a monohydric alcohol in an amount of 4% by weight or less.

3. The solid bar of claim 1 comprising, by weight: three or more hydroxyl groups, and about 15% to about 30% having two hydroxyl groups;

4. The solid bar of claim 3, further including a monohydric alcohol in an amount 0.5-3%.

5. The solid bar of claim 3, comprising, by weight: three or more hydroxyl groups, and about 20% to about 30% having two hydroxyl groups;

6. The solid bar of claim 5, further including a monohydric alcohol in an amount of 0.5-2%.

7. The solid bar of claim 5, comprising, by weight: three or more hydroxyl groups, and about 22% to about 27% having two hydroxyl groups;

8. The solid bar of claim 7, further including a monohydric alcohol in an amount of 0.75-1.5%.

9. The solid bar of claim 1, wherein the soap is at least 90% selected from the group consisting of sodium myristate, sodium plamitate, sodium stearate, and mixtures thereof.

10. The solid bar of claim 9, wherein the soap is at least 95% by weight saturated.

11. The solid bar of claim 1, further including in a total concentration less than 20% by weight total, and less than 5% individually, additives selected from the group consisting of dyes, fragrances, antibacterial compounds, pH adjusters, thickeners, fillers, viscosity modifiers, buffering agents, foam stabilizers, antioxidants, foam enhancers, chelating agents, anti-microbial agents, preservatives, polymers, silicones, encapsulated materials, and mixtures thereof.

12. The solid bar of claim 9, wherein the soap contains an antibacterial compound that is triclocarban.

13. A method of making a transparent, pour molded bar comprising the steps of: about 5% to about 35% having three or more hydroxyl groups, and about 10% to about 30% having two hydroxyl groups; molten mixture contains more than 13% by weight water; and

14. The method of claim 13, wherein at least one component of the bar selected from the group consisting of a water-soluble polyhydric solvent and a surfactant is added to the mixture in anhydrous form, such that the mixture is 13% by weight or less water, such that dehydrating the molten mixture is unnecessary.

15. The method of claim 13, wherein the soap is formed in situ by the addition of fatty acids and a base to form the sodium salt of the fatty acids.

16. The method of claim 13, wherein the water content of the molten mixture comprises greater than 13% to 30% by weight water, and the molten mixture is dehydrated before or after disposing the mixture in the shaped mold.

17. The method of claim 16, wherein the mixture comprises: 30% having three or more hydroxyl groups, and about 15% to bout 30% having two hydroxyl groups;

18. The method of claim 13, wherein the mixture comprises:

19. The method of claim 17, wherein the molten mixture further includes a monohydric alcohol in an amount of 4% by weight or less.

20. The method of claim 17, wherein the water content of the mixture comprises more than 12% by weight water to about 30% by weight water, and the method includes a dehydration step.

21. The method of claim 13, wherein the mixtures comprises: 25% having three or more hydroxyl groups, and about 20% to about 30% having two hydroxyl groups;

22. The method of claim 13, wherein the mixture comprises: 22% having three or more hydroxyl groups, and about 22% to about 27% having two hydroxyl groups;

23. The method of claim 21, wherein the molten mixture includes a monohydric alcohol in an amount of 4% by weight or less.

24. The method of claim 17, wherein the water content of the mixture comprises more than 13% by weight water to about 30% by weight water, and the method includes a dehydration step.

25. The method of claim 23, wherein the amount of monohydric alcohol is 0.5% to about 3% by weight of the mixture.

26. The method of claim 13, wherein the mixture comprises: three or more hydroxyl groups, and about 20% to about 30% having two hydroxyl groups;

27. The method of claim 26, wherein the mixture further includes 0.5-2% by weight of a monohydric alcohol.

28. The method of claim 13, wherein the mixture comprises:

29. The method of claim 28, wherein the mixture includes a monohydric alcohol in an amount of 0.5-2% by weight.

30. The method of claim 13, wherein the mixture comprises:

31. The method of claim 13, wherein the mixtures comprises:

32. The method of claim 30, wherein the molten mixture includes a monohydric alcohol in an amount of 0.75-1.5% by weight.

33. The method of claim 13, wherein step (a) is performed in accordance with the following sequence of steps: about 2%, based on the total weight of free fatty acids, and neutralized fatty acids by the addition of more alkali or more fatty acid;