## FMMI Miami Smelter, CALPUFF simulations for Arizona Regional Haze FIP NPRM, January 2014

CALPUFF point and buoyant line source parameters, extracted from CALPUFF.INP files Used to test whether it makes a difference how the fugitive emissions are characterized.

lbhr_gs 7.936647913

## FMMI Miami Smelter, CALPUFF simulations for Arizona Regional Haze FIP NPRM, January 2014 sjb 2013-08-23, updated 2014-01-27 **NOTE: These model runs use outdated August 2013 emission estimates.** CALPUFF point and buoyant line source parameters, extracted from CALPUFF.INP files Used to test whether it makes a difference how the fugitive emissions are characterized.FMMI CALPUFF source input parameters, Aug. 2013 **Line source parms:** Ln SRCNAM

**Facility and control scenario Stack parameters**  Pn SRCNAM
task**facility fac**  **units ctrl**  **EPA ctrl**  **controls applied CA** **LPUFF input file Source**  **# SRCNA** **M** WFreeport McMoran Smelter

FMMIunits1-5 WRAP(none) src06_az_010101.inp 1 AZ15 WFreeport McMoran Smelter

FMMIunits1-5 WRAP(none) src06_az_010101.inp 2 AZ16 WFreeport McMoran Smelter

FMMIunits1-5 WRAP(none) src06_az_010101.inp 3 AZ17 WFreeport McMoran Smelter

FMMIunits1-5 WRAP(none) src06_az_010101.inp 4 AZ19 WFreeport McMoran Smelter

FMMIunits1-5 WRAP(none) src06_az_010101.inp 5 AZ20 E Freeport McMoran Smelter

FMMIAZ15 base pbase (none) cf_FMMI_pbase_2001.inp 1 main E Freeport McMoran Smelter

FMMIAZ19 base pbase (none) cf_FMMI_pbase_2001.inp 2 roof_con_pt E Freeport McMoran Smelter

FMMIAZ20 base pbase (none) cf_FMMI_pbase_2001.inp 3 roof_ELF_pt E Freeport McMoran Smelter

FMMIAZ15 ctrl1 pctrl1 (none; add conv. em)cf_FMMI_pctrl1_2001.inp 1 main E Freeport McMoran Smelter

FMMIAZ19 ctrl1 pctrl1 85% converter to control cf_FMMI_pctrl1_2001.inp 2 roof_con_pt E Freeport McMoran Smelter

FMMIAZ20 ctrl1 pctrl1 (none) cf_FMMI_pctrl1_2001.inp 3 roof_ELF_pt E Freeport McMoran Smelter

FMMIAZ15 ctrl2 pctrl2 (none; add furn, em.)cf_FMMI_pctrl2_2001.inp 1 main E Freeport McMoran Smelter

FMMIAZ19 ctrl2 pctrl2 (none) cf_FMMI_pctrl2_2001.inp 2 roof_con_pt E Freeport McMoran Smelter

FMMIAZ20 ctrl2 pctrl2 85% furnace to control cf_FMMI_pctrl2_2001.inp 3 roof_ELF_pt E Freeport McMoran Smelter

FMMIAZ15 base base (none) cf_FMMI_base_2001.inp 1main E Freeport McMoran Smelter

FMMIAZ19 base base (none) cf_FMMI_base_2001.inp 2roof_convrtr E Freeport McMoran Smelter

FMMIAZ20 base base (none) cf_FMMI_base_2001.inp 3roof_ELF E Freeport McMoran Smelter

FMMIAZ15 ctrl1 ctrl1 (none; add conv. em)cf_FMMI_ctrl1_2001.inp 1main E Freeport McMoran Smelter

FMMIAZ19 ctrl1 ctrl1 85% converter to control cf_FMMI_ctrl1_2001.inp 2roof_convrtr E Freeport McMoran Smelter

FMMIAZ20 ctrl1 ctrl1 (none) cf_FMMI_ctrl1_2001.inp 3roof_ELF E Freeport McMoran Smelter

FMMIAZ15 ctrl2 ctrl2 (none; add furn, em.)cf_FMMI_ctrl2_2001.inp 1main E Freeport McMoran Smelter

FMMIAZ19 ctrl2 ctrl2 (none) cf_FMMI_ctrl2_2001.inp 2roof_convrtr E Freeport McMoran Smelter

FMMIAZ20 ctrl2 ctrl2 85% furnace to control cf_FMMI_ctrl2_2001.inp 3roof_ELF pbase, pctrl: fugitives modeled as point sources**Beg. X**

**Coordinate Beg. Y** 

**Coordinat End. X** 

**Coordinat End. Y** 

**Coordinat Release** 

**Height Base** 

**Elevation** blue= changed relative to base

x y HS z DS VS TS DW **Emissions, g/s X**  **Coordinat Y** 

**Coordinat Stack** 

**Height Base** 

**Elevation Stack** 

**Diameter Exit Vel.** 

**(m/s) Exit** 

**Temp. Bldg.** 

**Dwash SO2**  **SO4** -1280.01 -631.582 60.96 1095.76 1.83 24.08 323.15 0 0 0 -1280.01 -631.582 76.2 1095.76 6.71 3.93 309.26 0 0 0 -1280.01 -631.582 19.51 1095.76 1.77 7.68 644.26 0 0 0.85 -1280.01 -631.582 10 1095.76 10 0.1 295 0 0 3.15 -1280.01 -631.582 10 1095.76 10 0.1 295 0 0 0.58 -1280.116 -631.518 65 1085 2.111 20 297.2 0 43.22 0 -1280.06 -631.648 31.18 1085 17.29 16.6 312 0 1487.1 0 -1280.042 -631.679 52.43 1085 10.88 10.16 316 0 34.9 0 -1280.116 -631.518 65 1085 2.111 20 297.2 0 47.3 0 -1280.06 -631.648 31.18 1085 17.29 16.6 312 0 223.1 0 -1280.042 -631.679 52.43 1085 10.88 10.16 316 0 34.9 0 -1280.116 -631.518 65 1085 2.111 20 297.2 0 43.31 0 -1280.06 -631.648 31.18 1085 17.29 16.6 312 0 1487.1 0 -1280.042 -631.679 52.43 1085 10.88 10.16 316 0 5.2 0 -1280.116 -631.518 65 1085 2.111 20 297.2 0 43.22 0 -1280.087 -631.636 -1280.03 -631.659 31.18 1085 1487.1 0 -1280.05 -631.698 -1280.04 -631.677 52.43 1085 34.9 0 -1280.116 -631.518 65 1085 2.111 20 297.2 0 47.3 0 -1280.087 -631.636 -1280.03 -631.659 31.18 1085 223.1 0 -1280.05 -631.698 -1280.04 -631.677 52.43 1085 34.9 0 -1280.116 -631.518 65 1085 2.111 20 297.2 0 43.31 0 -1280.087 -631.636 -1280.03 -631.659 31.18 1085 1487.1 0 -1280.05 -631.698 -1280.04 -631.677 52.43 1085 5.2 0= changed relative to base **% change relative to base**

**NOX HNO3** **NO3 PMF**  **PMC EC**  **SOA PM sum**  **SO2 SO4**  0 0 2.57 0 0 5.83 0 0 0.52 0 0 6.12 0 0 0 0 0 0 2.57 3.15 0 0 6.12 0.58 0 0 0 0 0 0 2.57 9.4%

-- 3.15 0 0 6.12 -85.0%

-- 0.58 0 0 0

-- -- 0 0 0 2.57 0.2%

-- 3.15 0 0 6.12

-- -- 0.58 0 0 0 -85.1%

-- 0 0 0 2.57 3.15 0 0 6.12 0.58 0 0 0 0 0 0 2.57 9.4%

-- 3.15 0 0 6.12 -85.0%

-- 0.58 0 0 0

-- -- 0 0 0 2.57 0.2%

-- 3.15 0 0 6.12

-- -- 0.58 0 0 0 -85.1%

--**% change relative to base**

**NOX HNO3**  **NO3 PMF**  **PMC EC**  **SOA PM sum** **VS TS** 

-- -- -- -- -- --

-- -- -- -- -- --

-- -- -- -- -- --

-- -- -- --

-- -- -- --

-- -- -- --

-- -- -- --

-- -- -- --

-- -- -- --

-- -- -- --

-- -- -- --

-- -- -- --blue= changed relative to base

**PM speciation Emissions, lb/hr** 

**SO4 PMF**  **PMC EC**  **SOA** 

### SO2 **SO4** 

### NOX **HNO3 NO3** 

343.02 0.00 0.00 0 0 11802.59 0.00 25.00 0 0 276.99 0.00 4.60 0 0 375.40 0.00 0.00 0 0 1770.67 0.00 25.00 0 0 276.99 0.00 4.60 0 0 343.74 0.00 0.00 0 0 11802.59 0.00 25.00 0 0 41.27 0.00 4.60 0 0 343.02 0.00 0.00 0 0 11802.59 0.00 25.00 0 0 276.99 0.00 4.60 0 0 375.40 0.00 0.00 0 0 1770.67 0.00 25.00 0 0 276.99 0.00 4.60 0 0 343.74 0.00 0.00 0 0 11802.59 0.00 25.00 0 0 41.27 0.00 4.60 0 0**PMF PMC**  **EC SOA**  **PM sum TS, deg F** 

20.40 75.29 48.57 101.93 0.00 109.13 20.40 75.29 48.57 101.93 0.00 109.13 20.40 75.29 48.57 101.93 0.00 109.13 20.40 75.29 48.57 0.00 20.40 75.29 48.57 0.00 20.40 75.29 48.57 0.00**FMMI CALPUFF run times**

fugitives as buoyant line sources buoyant line / point 3 scenarios scenario start end hours time ratio hours base_2001 8/23/2013 20:39 8/25/2013 12:00 39.3 4.63 117.3 ctrl1_2001 8/25/2013 12:32 8/27/2013 3:54 39.4 4.63 ctrl2_2001 8/27/2013 4:25 8/28/2013 19:02 38.6 4.58 base_2002 8/23/2013 20:39 8/25/2013 6:41 34.0 4.68 102.1 ctrl1_2002 8/25/2013 7:11 8/26/2013 17:13 34.0 4.67 ctrl2_2002 8/26/2013 17:43 8/28/2013 3:48 34.1 4.67 base_2003 8/23/2013 20:39 8/25/2013 8:49 36.2 4.74 108.2 ctrl1_2003 8/25/2013 9:21 8/26/2013 21:30 36.2 4.73 ctrl2_2003 8/26/2013 22:02 8/28/2013 9:57 35.9 4.70 fugitives as point sources scenario start end hours hours pbase_2001 8/29/2013 13:45 8/29/2013 22:15 8.5 25.4 pctrl1_2001 8/29/2013 22:508/30/2013 7:20 8.5 pctrl2_2001 8/30/2013 7:55 8/30/2013 16:21 8.4 pbase_2002 8/29/2013 13:45 8/29/2013 21:02 7.3 21.9 pctrl1_2002 8/29/2013 21:35 8/30/2013 4:52 7.3 pctrl2_2002 8/30/2013 5:24 8/30/2013 12:42 7.3 pbase_2003 8/29/2013 13:45 8/29/2013 21:23 7.6 22.9 pctrl1_2003 8/29/2013 21:588/30/2013 5:36 7.6 pctrl2_2003 8/30/2013 6:11 8/30/2013 13:49 7.63 scenarios

days **average ratio**  4.9 **36.4 4.7** 

4.3

4.5

days average 1.1 7.8

0.9

1.0