### TS-S081UY ( CBI )



## The attached MSDS will be us ed for the commercial product containing the New Chemical S ubstance. The specific language concerning warnings and managemen t practices in the MSDS are driven primarily by ( CBI ) A ttachment 5 Page 1/5TS-S081UY CONFIDENTIAL

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Page 1 CBI



# MATERIAL SAFETY DATA SHEET 

# CBI

SECTION 1: CHEMICAL PRODUCT & COMPANY IDENTIFICATION
( DAIKIN ) TRADE NAME: (CBI) CHEMICAL FAMILY: Fluoroalkyl acrylate copolymer (solution) Manufacturer/Supplier: (CBI) PHONE: (CBI) FAX: (CBI) 

### SECTION 2: HAZARDS IDENTIFICATION
PHYSICAL DESCRIPTION: (CBI) POTENTIAL HEALTH EFFECTS: May cause eye, skin and res piratory irritation. May be harmful if swallowed. EMERGENCY OVERVIEW: Primary hazard occurs in the even t of high temperature exposure, whether by fire or processing. At temperature above 200 ° C (392 ° F), inhaling thermal decomposition products could result in chills, headaches, nausea, breathing discomfort, cough or sore throat. These symptoms generally disappear within 24 - 48 hours. Above 500 ° C (930 ° F), hydrogen fluoride, perfluoroisobutylene and ca rbonyl fluoride are produced; inhalation under these conditions may result in serious lung irritation. HMIS RATINGS: Health : 3 Flammability : 3 Reactivity : 0



### SECTION 3: INFORMATION ON INGREDIENTS

COMPONENT CAS. NO. WT% OSHA (PEL) (STEL) (IDLH) HAZARDOUS INGREDIENTS (CBI) (CBI) (CBI) (CBI ) (CBI) (CBI) NON-HAZARDOUS INGREDIENTS FLUOROALKYL ACRYLATE COPOLYMER (CBI) (CBI) (CBI) (CBI) (CBI) *All ingredients in quantities > 1% (0.1% for carcinogens or teratogens) that are potentially hazardous per OSHA definitions.

OSHA PEL’s may vary from state to state.



### SECTION 4. FIRST AID PROCEDURES
EYE CONTACT: Immediately flush with large amounts of water for 10 - 15 minutes. If irritation occurs, get medical attention. SKIN CONTACT: Wash affected a rea with soap and water. Remove contaminated clothing. INGESTION: Consult a physician immediately. INHALATION: Leave the contaminated area and seek fresh air. If breathing is difficult, contact a physician. If decomposition gases are inhaled, move to fresh air and get medical attention. NOTE TO PHYSICIANS: In the event of inhalation of gases ge nerated by high temperature decomposition of the product, treat for hydrogen fluoride inha lation. Excessive exposure to th ermal degradation products could Attachment 5 Page 2/5

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Page 2 result in delayed pulmonary edema in some cases, and on very high exposure, damage to the liver and kidneys.


### SECTION 5. FIRE FIGHTING MEASURES
FLASH POINT (METHOD USED): 22 ° C (72 ° F) FLAMMABLE LIMITS: LEL: 1.2 vol% UEL: 7.6 vol% IGNITION TEMPERATURE: 370.0 ° C (698 ° F) HAZARDOUS COMBUSTION PRODUCTS: Toxic and corro sive products, including Hydrofluoric Acid, Perfluoroisobutylene, and Carbonyl Fl uoride may be formed by at very high temperatures. EXTINGUISHING MEDIA: CO 2 or dry chemical. Do not use water. PROTECTIVE EQUIPMENT: Use NIOSH/MSHA approved self-contained breathing apparatus (SCBA) and full bunker gear.


### SECTION 6. ACCIDENTAL RELEASE MEASURES
Ensure cleanup is done only by trained personnel we aring appropriate personal protective equipment. Ventilate area and cover with absorbent material. Liquids must be cleaned up promptly before they dry. Collect the spilled material in a container and seal. Spilled material is a slipping hazard. Runoff from fire fighting efforts involving this material may contain hydrofluoric acid. Depending on the concentration, this should be contained and t reated prior to discharge.


### SECTION 7. HANDLING & STORAGE HANDLING: Avoid contact with skin or eyes. Do not breathe vapor or spray. Use only in well ventilated areas. Safety showers and eyewashes should be available in the work area. Ensure good ventilation in the workplace. Close containers after each use. Wash hands thoroughly after hand ling. Wash clothing after use. Keep away from heat, sparks and ignition so urces. Protect against electrostatic charges. Electrically ground all equipment when handling th is product and use only non-sparking tools. If smoking tobacco becomes contaminated by this material, exposure to toxic gases through inhalation can occur. Therefore, do not smoke in the work a reas and wash hands and face after hand ling in order to avoid transfer of the material onto smoking materials.

STORAGE: Do not store with flammable materi als, such as solvents or oils. Do not allow material to be exposed to excessive heat. Store material at 0 ° C (32 ° F) to 40 ° C (104 ° F) in a dry place. Keep material away from sparks and flames. Keep container tightly closed when not in use.TS-S081UY CONFIDENTIAL

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### SECTION 8. EXPOSURE CONTROLS & PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY PROTECTION: Appropriate respiratory protect ion required when hand spray apparatus is used to apply this material. If material is heated above 200 ° C, use a positive pressure airsupplied respirator or self-contained breathing apparatus (SCBA). EYE PROTECTION: Safety glasses with side shields or goggles. PROTECTIVE CLOTHING: When there is potential for skin contact, wear chemical resistant gloves, pants and jacket. VENTILATION: Use local exhaust ventilation. OTHER PROTECTIVE EQUIPMENT: Safety shower and eyewas h station should be accessible in the work area.



### SECTION 9. PHYSICAL & CHEMICAL PROPERTIES
PHYSICAL STATE: (CBI) VAPOR PRESSURE: (CBI) DENSITY: (CBI) SOLUBILITY IN WATER: (CBI) BOILING POINT : (CBI) FLASH POINT (METHOD USED): 22 ° C (72 ° F) IGNITION TEMPERATURE: 370.0 ° C (698 ° F) EVAPORATION RATE (Butyl acetate=1): Approx. 1



### SECTION 10. STABILITY & REACTIVITY
STABILITY: Stable at room temperature in closed containers under normal condition. CONDITIONS TO AVOID: Excessive heat, sparks , open flame, electrostatic discharge HAZARDOUS POLYMERIZATION: Will not occur INCOMPATIBILITIES: No ne reasonably foreseeable



### SECTION 11. TOXICOLOGICAL INFORMATION

ACUTE EFFECTS OF EXPOSURE EYE CONTACT: May cause eye irritation INGESTION: Not evaluated INHALATION: May cause respiratory irritation. Norma lly, inhalation problems are not expected (unless sprayed or heated). When thermally decomposed, deco mposition products of this fluoropolymer may cause polymer fume fever. CHRONIC EFFECTS OF EXPOSURE: No data available CARCINOGENICITY: None of the components in this material is listed by NTP or OSHA. OTHER POTENTIAL HAZARDS (OF THE PURE MATERIALS): Excessive exposure to thermal degradation products could result in delayed pulmona ry edema in some cases, and on very high exposure, damage to the liver and kidneys. These s ubstances may include: perfluoroisobutylene (TLV = 10 ppb), carbonyl fluoride (TLV = 2 ppm TWA, 5 ppm STEL), hydrogen fluoride (TLV = 3 ppm, Ceiling). Attachment 5 Page 4/5TS-S081UY CONFIDENTIAL

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### SECTION 12. ECOLOGICAL INFORMATION

ECOTOXICITY: No Data BIODEGRADABILITY: No Data 

### SECTION 13. DISPOSAL CONSIDERATIONS
Comply with Federal, State, a nd Local regulations concerning health and environ ment when disposing of materials. Regulations may also apply to empty containers, liners, or rinsate. DO NOT INCINERATE unless incinerator is capable of scrubbing hydrogen fluoride and other ac idic combustion products.


### SECTION 14. TRANSPORT INFORMATION
UN “Model Regulation”: (CBI) CANADIAN TRANSPORTATION OF DANGEROUS GOODS (TDG): Not applicable



### SECTION 15. REGULATORY INFORMATION
TSCA: The TSCA status of this product has not yet been determined; as such, use of this product should be restricted to research and development work only. OTHER: States such as Pennsylvan ia, New Jersey, California, Vermont, Ma ssachusetts and Rhode Island may hav e specific requirements or components of this product listed; consult specific state regulatory requirements for additional information.


### SECTION 16. OTHER INFORMATION For additional information, refer to the American Conf erence of Governmental Industrial Hygienists (ACGIH) documentation of TLV’s (Threshold Limit Values) for i ndividual components, Fluoropo lymers Safe Handling Guide published by The Society of the Plastics Industry, and the DOT Emergency Response Guidebook. Attachment 5 Page 5/5