# Support Documents for

Significant New Use Rule (SNUR) on

Premanufacture Notice (PMN)

P-10-290

EPA Docket EPA

- HQ

- OPPT -2011-0577

# Index

A-001 Structure Activity Team (SAT) Report for

PMN P-10-290

A-002 Initial Review Engineering Report for

PMN P-10-290

A-003 Initial Review Exposure Report for

PMN P-10-290

# A-001

Structure Activity Team (SAT) Report

for PMN P-10-290

# A-002

Initial Review Engineering Report

for PMN P-10-290

### TEST DATA REVIEW ENGINEERING REPORT

P-10-0290

Post-Focus Draft Revision 3 7/19/2010

ENGINEER: Arnold \ BCS PV (kg/yr):

Revision Notes/Assessment Overview:

SUBMITTER: Reichhold, Inc. (submitter)

USE:

OTHER USES:

MSDS: Yes LABEL : N o

Gen Eqpt: Eng Controls: good general ventilation should be sufficient to control airborne levels of irritating vapors. Local ventilation may be required during certain operations. // Eye/Face: wear safety glasses with side shields and a faceshield or goggles and a faceshield. // Skin: gloves made of neoprene. Chemical resistant apron.

boots. Respirator: in case of insufficient ventilation wear suitable respiratory equipment

. Health Effects: Eye: mild eye irritant. // Skin: Mild skin irritant. Repeated exposure may cause skin dryness or cracking. // Inhalation: vapors and/or aerosols which may be formed at elevated temperatures may be irritating to eyes and respiratory tract. // Ingestion: swallowing may irritate the mouth, throat, and stomach. Ingestion is not an anticipated route of exposure for this material in industrial use

. TLV/PEL : - none established

CRSS: (3/29/2010):

Chemical Name:

S-H2O: 0.00276 g/L @

VP: 1.0E-6 torr @

MW: Physical State and Misc CRSS Info:

Neat: Liquid (Est.) Mfg:

Proc/Form: End Use:

Submitted Data: WS = Insoluble ; Specific Gravity = 1.08-1.12; Flash Point > 93 °C. Estimated Data: BP = 487 °C (EPI); VP = 5.8E-8 torr (EPI); WS = 0.00276 g/L (EPI); logP = 4.62 (EPI). The EPI estimations were performed for the

Consumer Use: N oSAT (concerns): (3/30/2010):

Related Cases and Misc SAT Info:

Migration to groundwater: N egligible PBT rating: P 2 B 1 T 1

. Health: 1-2, Dermal, Inhalation

Eco: 3, Water (All releases to water with a CC = 8 ppb)

OCCUPATIONAL EXPOSURE RATING: 2-3B

NOTES & KEY ASSUMPTIONS: Generated by the 06/07/2005 version of ChemSTEER.

POLLUTION PREVENTION CONSIDERATIONS:

P2 Claim :

P2 REC:

EXPOSURE -BASED REVIEW:P-10-0290

PROC/USE:

Number of Sites/Location:

Basis:

Process Description:



## ENVIRONMENTAL RELEASES ESTIMATE SUMMARY

IRER Note: The daily releases listed for any source below may coincide with daily releases from the other sources

to the same medium.

Output 2:

to:

from:

basis:

Conservative:

to:

from:

basis:

High End:

to:

from:

basis:

Output 2

to:from: Coating Using Hand-Held Spray Gun

basis:



## RELEASE TOTAL

OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY

Tot. # of workers exposed via assessed routes:

Dermal:

Exposure to High End: Number of workers (all sites) with Dermal exposure

Basis:

Inhalation:

Exposure to Upper Bound : Number of workers (all sites) with Inhalation exposure : Basis:



## INHALATION MONITORING DATA REVIEW

1) Uncertainty (estimate based on model, regulatory limit, or data not specific to industry): Yes 2) (a) Exposure level > 1 mg/day? Yes (b) Hazard Rating for health of 2 or greater? N o Inhalation Monitoring Data Desired? N oP-10-0290

MFG:

Number of Sites/Location:

Basis:

Process Description:



## ENVIRONMENTAL RELEASES ESTIMATE SUMMARY

IRER Note: The daily releases listed for any source below may coincide with daily releases from the other sources

to the same medium. N ote, SAT concerns for dermal, inhalation, and releases to water with CoC = 8 ppb. Incineration releases < 28,000 kg/site-day; air releases negligible (VP < 0.001 torr); migration to groundwater = negligible; releases to water are possible due to the unclear releases media from equipment cleaning

.

Conservative:

to:

from:

basis:

Output 2:

to : (submission)

from:

basis:



## RELEASE TOTAL

OCCUPATIONAL EXPOSURES ESTIMATE SUMMARY

Tot. # of workers exposed via assessed routes:

Dermal:Exposure to High End: Number of workers (all sites) with Dermal exposure:

Basis:

Dermal:

Exposure to High End:

Number of workers (all sites) with Dermal exposure : Basis:

.

# A-003

Initial Review Exposure Report

for PMN P-10-290

### POST FOCUS EXPOSURE REPORT

Updated according to updated engineering report, Post-Focus Draft Revision 3,

7/19/2010.

Chemical ID: P-10-0290 Reviewer: Delpire/SS

Results Table: Dose, Concentration, and Days Exceeded Results Summary

Exposure Scenario 1 Water Landfill Stack Air Fugitive Air

Drinking Water Fish Ingestion

ADR LADD ADR LADD 7Q10 4

CC = 8 PDM
Days

Exceeded LADD ADR LADD ADR LADD

Release

activity(ies) 2 ;

exposure calculation(s) 3 mg/kg/day m g/kg/day mg/kg/day mg/kg/day μg/l # Days mg/kg/day m g/kg/day mg/kg/day m g/kg/day mg/kg/day

PROC/USE: Max

ADR --- --- ---

PROC/USE: Max

LADD --- --- ---

1 Exposure scenario titles consist of release activity followed by exposure calculation abbreviation. 2 Release activities are from engineering report's Manufact uring (Mfg), Processing (Proc) and Use release activity labels.Multiple release activities are combined in one exposu re scenario if their releases occur at same location. 3 Exposure calculations are Acute Dose Rate (ADR), Lifetime Average Daily Dose (LADD), and Probabilistic Dilution Model (PDM). There may be one, two, or all th ree exposure calculations per exposure scenario. CC is the aquatic concentration of concern. 4 This column displays concentration values for the 7Q10 streamflow, which is defined as the average daily streamflow of the seven consecutive days of lowest flow within a ten year period.

Remarks:



### Results Table: Exposure Based (X B)/Persistent (P2B2) Criteria

Fate test recommendations?: (default is NA)POST FOCUS EXPOSURE REPORT

Chemical ID: P-10-0290 Assessor: Delpire/SS

ENVIRONMENTAL RELEASES

Scenario#:1 Number of Release Sites:

Release Activity: PROC/USE: Max ADR

Release Description: WATER LANDFILL

Non-

(k

N/A/0

(kgPOST FOCUS EXPOSURE REPORT

Chemical ID: P-10-0290

INHALATION EXPOSURE ESTIMATES (POST-TREATMENT)

SCENARIO #: 1 RELEASE AC TIVITY:PROC/USE: Max ADR

RELEASE DESCRIPTION:

METHOD OF CALCULATION: Screen3

EXPOSED POPULATION: Adult

Number of Sites:

Per Site Fugitive Release: 15.00 kg/site/day

Fugitive Release Days per Year: days

% Removal via Fugitive Release: 0.00 %

Total Fugitive Release: kg/yr

Max Annual Average Air Concentration (Fugitive): 110.00 μg/ m 3

Max 24 Hour Average Air Concentration(Fugitive): 2050.00 μg/ m 3

Per Site Stack Release: NA kg/site/day

Stack Release Days per Year: NA days

% Removal via Stack Release: 99.90 %

Total Stack Release: NA kg/yr

Max Annual Average Air Con centration (Stack): 0.00 μg/m 3

Max 24 Hour Average Air Concentration (Stack): 0.00 μg/m 3

ASSUMPTIONS

Exposure Units Results (Stack) Results (Fugitive) ED (years) AT (years) BW (kg) Inh. Rate (m 3 /hr)

Cancer

LADD pot (mg/kg/day)

LADC pot (mg/m 3 ) NA

Acute

ADR pot

(mg/kg/day)

Inhalation Comments:Stack Parameter Data Fugitive Parameter Data

Stack Height 10.00 Release Height: 3.00 m

Inside Stack

Diameter: 0.10 Length of Release Opening: 10.00 m

Stack Gas Exit Velocity: 0.10 Width of Release Opening: 10.00 m

Stack Gas Temperature: 293.00

Meteorological and Terrain Information:

Surrounding Land Use: Rural

Terrain Height: 0.00 m

Distance to Residence of Interest: 100.00 m

Meteorological Class: Full

Stability Class: NA

Wind Speed: NA

Do wnwash Information:

Facility Length: NA m

Facility Width: NA m

Facility Height: NA mPOST FOCUS EXPOSURE REPORT

Chemical ID: P-10-0290 Assessor: Delpire/SS

ENVIRONMENTAL RELEASES

Scenario#:2 Number of Release Sites:

Release Activity: PROC/USE: Max LADD

Release Description: WATER LANDFILL

Non-sludge/Sludge STACK FUGITIVE

Total Releases:

(k g/yr) (kg/yr) (kg/yr) (kg/yr)

Non-sludge/Sludge

Release Days/yr:

Per Site Release:

(kg /site/day) (kg/site/day) (kg/site/day) (kg/site/day)

Remarks:POST FOCUS EXPOSURE REPORT

Chemical ID: P-10-0290

INHALATION EXPOSURE ESTIMATES (POST-TREATMENT)

SCENARIO #: 2 RELEASE ACTIVITY:PROC/USE: Max LADD

RELEASE DESCRIPTION:

METHOD OF CALCULATION: Screen3

EXPOSED POPULATION: Adult

Number of Sites:

Per Site Fugitive Release: 3750.00 kg/site/day

Fugitive Release Days per Year: days

% Removal via Fugitive Release: 0.00 %

Total Fugitive Release: kg/yr

Max Annual Average Air Concentration (Fugitive): 110.00 μg/ m 3

Max 24 Hour Average Air Concentration(Fugitive): N/A μg/m 3

Per Site Stack Release: NA kg/site/day

Stack Release Days per Year: NA days

% Removal via Stack Release: 99.90 %

Total Stack Release: NA kg/yr

Max Annual Average Air Con centration (Stack): 0.00 μg/m 3

Max 24 Hour Average Air Concentration (Stack): N/A μg/m 3

ASSUMPTIONS

Exposure Units Results (Stack) Results (Fugitive) ED (years) AT (years) BW (kg) Inh. Rate (m 3 /hr)

Cancer

LADD pot (mg/kg/day)

LADC pot (mg/m 3 ) NA

Acute

ADR pot

(mg/kg/day)

Inhalation Comments:Stack Parameter Data Fugitive Parameter Data

Stack Height 10.00 Release Height: 3.00 m

Inside Stack

Diameter: 0.10 Length of Release Opening: 10.00 m

Stack Gas Exit Velocity: 0.10 Width of Release Opening: 10.00 m

Stack Gas Temperature: 293.00

Meteorological and Terrain Information:

Surrounding Land Use: Rural

Terrain Height: 0.00 m

Distance to Residence of Interest: 100.00 m

Meteorological Class: Full

Stability Class: NA

Wind Speed: NA

Do wnwash Information:

Facility Length: NA m

Facility Width: NA m

Facility Height: NA m