# MONARCH CERAMIC TILE**FLORENCE,ALAB~** 

# EMISSION TEST REPORT KILN MAIN/KILN COOLER/PRESS DRYER

ERA&A Project No. 2003-0711A Prepared For: Mr. Steve Wiedenvax Monarch Ceramic Tile

834 Rickwood Road Florence,AUL 35630 Prepared By: E. ROBERTS 

# Alley& Associates INCORPORATED 

## 1931 Central Parkway 

## SW, Ste. 

## B Decatur,· AL 35601 (256) 351-0121

December 2003E. ROBERTS 

# Alley& ·Ass·ociates INCORPORATED


# .. , ... 

## ,., 

# .... .. , .. ·w *W .• ,,, .. ' -. '*MM 

### SECTION 1 INTRODUCTION SECTION2 RESULTS AND DISCUSSION SECTION3 TESTING METHODOLOGY APPENDIX A SUMMARY OF CALCULATIONS APPENDIXB FIELD DATA APPENDIXC LABORATORY DATA APPENDIXD QUALITY CONTROL DATA APPENDIXE PROCESS OPERATING DATA LIST OF TABLES 

# TABLE OF CONTENTS

" 

# ...

TABLE 2-1
...................................................... SUMMARY OF KILN MAIN TEST RESULTS TABLE 2-2
....................................... SUMMARY OF KILN COOLER TEST RESULTS TABLE 2-3
........................................ SUMMARY OF PRESS DRYER TEST RESULTS TABLE 3-1
...................................................... SOURCE TESTING METHODOLOGY TABLE A-1
...................... KILN MAIN- VOLUMETRIC FLOW RATE CALCULATIONS TABLE A-2
............................................. KILN MAIN- EMISSION CALCULATIONS TABLE A-3
.................. KILN COOLER- VOLUMETRIC FLOW RATE CALCULATIONS TABLE A-4
......................................... KILN COOLER·- EMISSION CALCULATIONS TABLE A-5
.................. PRESS DRYER- VOLUMETRIC FLOW RATE CALCULATIONS TABLE A-6 ......................................... PRESS DRYER-EMISSION CALCULATIONSE. ROBERTS 

# Alley& Associates INCORPORATED 

# SECTION I



# INTRODUCTIONE. ROBERTS



# Aile~& 

# Associates INCORPORATED 

# -· SECTION I INTRODUCTION
E. Roberts Alley & Associates, Inc. (ERA&A) was retained by Monarch Ceramic Tile (Monarch) to conduct particulate and carbon monoxide emission testing on the Kiln 1 Main and Cooler stacks and the Press Dryer 1 stack at its Florence, Alabama facility. The scope of work included conducting three one-hour particulate (EPA Reference Method 5) test runs and three one-hour carbon monoxide (EPA Reference Method 1 0) test runs on each source. The results of emission testing will allow Monarch to determine particulate and carbon monoxide emission factors for each source. ERA&A' s test team consisted of Jeremy Hutchens, Project Coordinator/Mobile Lab Operator, Ryan O'Dea, Meter Console Operator, Stacey Cunningham, Meter Console Operator, and Doug Daugherty. ERA&A's test team arrived onsite on December 9 for equipment setup and preliminary testing. The emission testing was initiated on December 11 and completed on December 12. Mr. Steve Wiederwax served as ERA&A' s onsite contact throughout the testing. There were no representatives from the Alabama Department of Environmental Management present for the emission testing.

c:\\Projects\i\1onarch\2003-0711A\EngineeringTestReport 1-1E. ROBERTS 

# Alley& 

# Associates
INCORPORATED 

# SECTIONl



# RESULTS AND DISCUSSIONE. ROBERTS



# Aile~& 

# Associates INCORPORATED ' HSe .. , 

## SECTION2 RESULTS AND DISCUSSION

· ··Cat · ···-,;· ·-

**---~;** · 1 · · 

# .. , 

### Tables 2-1 through 2-3 detail the emission testing results. Any 

### difference between. the calculated results contained in the appendices and the reported results in the summary table is due to rounding for presentation.


## TABLE2-1 Summary of Kiln Main Test Results
: ··: .. ,:··· ··: ." 

### ......

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### ., x;

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### . , .. · Date 12/11/03 12/11/03 12/11/03 

# ---- Start Time 12:34 14:17 15:55 

# ---- End Time 13:38 15:21 17:00 

# ---- Stack Gas Data Temperature, °F 463 467 466 465 Moisture,% 6.5 6.3 6.1 6.3 C0 2 Concentration, 

### % 2.4 2.5 2.4 2.4 0 2 Concentration,% 16.8 16.6 16.9 16.8 Velocity, ftlsec 55.1 54.5 55.4 55.0 VFR, x 10 3 dscfm 7.6 7.5 7.7 7.6 PM Emission Data Concentration, grains/dscf X l 0" 3 4.2 3.5 2.5 3.4 Emission Rate, lbs/hr 0.27 0.22 0.16 0.22 CO Emission Data Concentration, ppmvd 149 150 155 152 Concentration, ppmvd (C0 2 Corrected) 146 147 151 148 Emission Rate, lbs/hr 4.85 4.82 5.07 4.91

c:\\Projects\Monarch\2003-0711 A \EngineeringTestReport 2- IE. ROBERTS

# Aile~& 

# Associates INCORPORATED

r -\H ·.,**~** 

# SECTION2 RESULTS AND DISCUSSION
e §# §t ·g. 

## '*' TABLE2-2 Summary of Kiln Cooler Test Results
Date Start Time End Time Stack Gas Data Temperature, °F Moisture,% C0 2 

### Concentration, % 

### 0 2 

### Concentration, % Velocity, ftlsec VFR, x 10 4 

### dscfm PM Emission Data Concentration, grains/dscf X 1 0" 3 

### Emission Rate, lbs/hr CO Emission Data Concentration, ppmvd Emission Rate, lbs/hr

p:g @&g 49 &+ c:\\Projects\Monarch\2003-0711 A \EnginceringTcstReport 12/11/03 12/11/03 12/11/03 12:35 14:17 15:56 13:39 15:21 17:00 276 273 265 272 1.2 1.3 1.4 

### 1.3 0.0 0.0 0.0 0.0 21.0 21.0 21.0 21.0 79.3 79.5 79.0 79.3

1.8 1.8 1.8 1.8 1.3 1.3 0.9 1.2 0.20 0.19 0.15 0.18 7.6 10.9 10.7 9.7 0.59 0.85 0.84 0.76

414£ 4 p a & 2-2E. ROBERTS 

# Alle:f& Associates INCORPORATED

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# SECTION2 RESULTS AND DISCUSSION Mpf, ··- 

## TABLE2-3 

## Summary of Press Dryer 

## Test Results

Stack Gas Data Temperature, °F 

### 258 262 261 260 Moisture,% 

### 5.4 6.0 6.9 6.1 C0 2 Concentration, % 

### 2.0 1.5 2.5 2.0 0 2 Concentration, 

### % 

### 18.5 18.5 18.5 18.5 Velocity, ft/sec 

### 53.1 54.6 53.9 53.9' x 10 3 dscfm 

### 3.3 3.4 3.3 3.3 PM Emission Data Concentration, grains/ dscf X I 0" 3 

### 7.6 10.0 

### 9.9 9.3 Emission lbs/hr 

### 0.22 0.30 

### 0.28 0.27 CO Emission Data Concentration, ppmvd 

### 127 139 138 135 Concentration, ppmvd (C0 2 Corrected) 

### 125 137 134 132 Emission Rate lbs/hr 

### 1.81 2.02 1.94 1.92

c:\\Projects\Monarch\2003-0711 A\EngineeringTestReport 2-3E. ROBERTS



# ABe~& 

# Associates INCORPORATED 

# SECfiON3



# TESTI·NG METHODOLOGYE. ROBERTS



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# Associates INCORPORATED



### , 

# SECTION3 TESTING METHODOLOGY • 

### The emission-testing program was conducted in accordance with the U.S. EPA Reference Methods summarized in Table 3-1. Method descriptions are provided below while the quality assurance data are provided in the referenced appendices. 

### TABLE3-l SOURCE TESTING METHODOLOGY Appendix Reference Method Quality Method Description Control Parameter Number Comments 

### Volumetric Flow Rate 1-4 

### 3.1 D Oxygen/Carbon Dioxide 3A 3.2 D Instrumental Analysis Particulate Matter 5 3.3 D lsokinetic Sampling Carbon Monoxide 10 3.4 D Instrumental Analysis 

# 3.1 VOLUMETRIC FLOW RATE The velocity of the stack gas was determined in strict accordance with EPA Reference Method 2. A total of twenty-four traverse points were used to measure the Kiln Main and Kiln Cooler stack gas velocity pressures. A total of twelve traverse points were used to measure the Press Dryer stack gas velocity pressure. The static pressure of the stack gas was measured with the static side of a calibrated S- Type pi tot

**an~** 

### an inclined manometer. The oxygen and carbon dioxide concentrations were determined in accordance with EPA Reference Method 3. An 

### integrated bag sample was procured during each particulate test run and analyzed with either a Pyrite 02/C02 analyzer or CAl Model 300P 02/C02 analyzer. The moisture content was determined in accordance with EPA Reference Method 4. The impinger train consisted of four glass impingers: the first and second containing 1 00 mL of water; the third empty; and the fourth containing approximately 200 grams of silica gel. The impinger contents were measured or weighed before and after each 60-minute particulate run, and the volume or weight gain was used to determine the stack gas moisture content. The stack gas velocity pressure, temperature, oxygen and carbon dioxide concentrations, and moisture content were used to calculate the stack gas volumetric flow rate.

c:\\Projects\Monarch\2003-0711 A\EngineeringTestReport 3-1E. ROBERTS

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# Associates INCORPORATED 

# 3.2 OXYGEN/CARBON DIOXIDE 

## SECTION3 

# TESTING METHODOLOGY

The Kiln Main and Press Dryer integrated bag samples were analyzed by EPA Reference Method 3A using a CAl Model 300P 0 2 

### /C0 2 

### /CO analyzer. An 

### analyzer calibration was performed before the analysis of each bag sample using EPA Protocol 1 calibration gases. The bag sample was connected directly to the instrument and the concentration was recorded on a field data sheet by reading the display of the instrument. 

# 3.3 PARTICULATE MATTER The particulate testing was conducted in strict accordance with EPA Reference Method 5. The sampling system consisted of a stainless nozzle, stainless lined probe, pre-weighed glass-fiber filter, gas conditioning system, dry 

### gas meter and leak-free pump. The gas conditioning system is described in Section 3 .1. Three 60-minute test runs were conducted on the Kiln 1 Main and Cooler stacks and the Press Dryer 1 stack. The gas stream was sampled isokinetically by adjusting the sample flow rate to correspond to the flow conditions at each sampling (traverse) point. After each test run, the sample train was leak checked at a vacuum pressure equal to or greater than the maximum pressure reached during the test run. The probe and nozzle were rinsed with acetone after each run to remove the adhering particulate matter. The front half of the filter holder was also rinsed with acetone, and this rinse was added to the probe/nozzle rinse. The pre-weighed glass fiber filter was carefully removed and placed in its sample container. All containers were sealed, labeled, and liquid levels marked for transport to the laboratory. The mass of particulate matter collected in the probe and nozzle was determined by evaporating the acetone rinse in a pre-weighed glass beaker and then weighing the residue until a constant weight was obtained. The filter loading was determined by subtracting the final constant filter weight from the initial constant weight. The total particulate loading, which was used to calculate the concentration of particulate matter in the exhaust gas, was determined by adding these two weights. All weight measurements were made on the same balance (accurate to 0.01 mg). 

# 3.4 CARBON MONOXIDE The stack gas was withdrawn through a stainless sample probe, gas conditioning system, Teflon sample line, and to a CAl Model 300P 0 2 

### /C0 2 

### /CO analyzer or a TECO Model
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### sea•sa aaw ;;: 4**~At±¥&** 4·'4'4P 11 8&Aff 1 c:\\Projects\Monarch\2003-0711 A\EnginecringTestReport 3-2E. ROBERTS

# Aile~& 

# Associates INCORPORATED

d 

## SECTION3 TESTING METHODOLOGY

1 

### 48C CO analyzer. The gas conditioning system was a non-contact condenser used to remove the stack gas moisture. Data was acquired online and in strict accordance with EPA Reference Method 10. A total of three 60-minute test runs were performed on each stack. An 

### analyzer calibration and system recovery check were performed before testing was initiated. A system recovery check was also conducted following the completion of each 60-minute test run. Additional analyzer calibrations were conducted as needed. EPA Protocol 1 calibration gases were used to conduct analyzer calibrations and system recovery checks. Copies of all calibration gas certificates can be found in Appendix D.

c:\\Projects\Monarch\2003-0711 A \EngineeringTestReport 3-3

## . ___ z: s a_ E. ROBERTS 

# Aile!& Associates INCORPORATED J .


# APPENDIX A



# SUMMARY OF CALCULATIONSE. ROBERTS 

# Alle:f& Associates INCORPORATED 

# APPENDIX A SUMMARY OF CALCULATIONS *=. iA®atijfji§. %'"" .• 

## KILN MAIN/RUN 

## 1 SAMPLE CALCULATIONS Meter Pressure (Pm), in. Hg 

## Pm =



# Pb+------~- **------** 13. 6 in. H 2 

## 0/in. Hg where, Pb 

### = barometric pressure, in. Hg

**~H** 

### = Pressure differential of orifice in. H 2 0 

### P 

## = 3021 . 

### H 1

· 246 in.H 2 

### 0 

## = 3030. 

### H 

## m . zn. g 

## + . . zn. g 

### 13.6in.H 2 

## ()/in.Hg Absolute Stack Gas Pressure (Ps), in. Hg Ps 

### = Pb+---P.:..g
__ _ 13.6 in. H 2 0/in. Hg 

### where, Pb =barometric pressure, in. 

### Hg Pg =Static Pressure, 

### in. H 2 

### 0 

### P 

## = 3021 . 

### H 0

· 32 in.H 2 

### 0 

## = 3023 . 

### H 

## s . ln. 

### g 

## + . zn. g 13. 6 in. H 2 

## 0/in. Hg Standard Meter Volume (Vmstd), dscf

**~~** 

### d 17.647 

### °Rfin. Hg 

### x Y 

### x Vm 

### x Pm 

### rmn 

## = . Tm where, Y 

## = meter correction factor Vm =meter volume, cf Pm =meter pressure, in. Hg Tm 

### = meter temperature, 0 

### R 

### Vmstd 

# = 17.647 

## ° Rlin. Hg x 1.035 x 35.342 cf x 30.30 in. 

### Hg 

## = 37 . 102 dscf 527.2 °R
Standard Wet Volume (Vwstd), scf 3 Vwstd = 0. 04707 

## ft lmL x Vlc 

### where, VIc= volume of H 2 

### 0 collected, ml 

### Vwstd =0.04707 

# ft 3 

### /mL x 54.4 mL = 

### 2.561 scf

c:\\Projects\Monarch\2003-0711 A \EngineeringTestReport A-1E. ROBERTS

# Aile~& 

# Associates INCORPORATED 

# APPENDIX A SUMMARY OF CALCULATIONS

Moisture Fraction (Measured), (Bws) 

### Vwstd Bws = ------ 

## = 1.246 scf 

## = 0.065 (Vwstd 

## + Vmstd) 1.246 scf 

## + 37.102 dscf

Moisture 0 /o, 

### (Bws %) 

### where, Vwstd =standard wet volume, scf Vmstd =standard meter volume, dscf


### Bws 

## = Bws x 100 

## = 0.065 x 100 

## = 6.5% Molecular Weight (DRY) 

### (Md), lb/lb-mole Md = 

### {0.44 x% CO}+ 

### (0.32 x% OJ+ 

### {0.28 (100-% C0 2 

### -% 0}) 

## Md = 

### (0.44 

## x 2.4) 

## + (0.32 

## x 16.8) 

## + (0.28 (100- 2.4 -16.8)) = 

### 29.06 lb/lb- mole Molecular Weight (WET) (Ms), 

### lb/lb-mole Ms 

## = Md (1- Bws) + 18 (Bws) where, Md =molecular weight (DRY), lb/lb-mole Bws = moisture fraction, dimensionless 

### .Ms 

## = 29.06 lb/lb- mole (1- 

### 0. 065) 

### + 18 (0. 065) 

## = 28.34/b/lb- mole Average Velocity (Vs), ft/sec 

## ft (lbllb- mole) 

### (in. Hg)

### ~s Vs = 

### 85.49- x Cp x 

## .J Delta P avg. x 

### sec ( 0 

### R)(in. H 20) 

### Ps X 

### Ms where, Cp = pitot tube coefficient Delta P 

### = velocity head of stack gas, in. H 2 

### 0 Ts =absolute stack temperature, 0 

### R Ps =absolute stack gas pressure, in. Hg Ms 

## = molecular weight of stack gas, lb/lb-mole 

### ft (lb/lb

- mole) 

### (in. J-Ig) Vs=85.49- x 

### 0.84 x 

### 0.740 

## in.H 1 

## 0 x 

### sec ( 0 

### R)(in.H 2 

### 0) 30.23 

### in. 

## Hg x 28.34 lb/lb- mole Vs = 

### 55.1 ftlsec

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### '* ;;;p;+-499¥ 4 +1 6**~A-** AY c:\\Projects\Monarch\2003-0711 A\EngineeringTestRepon A-2E. ROBERTS



# Aile~& 

# Associates INCORPORATED 

## APPENDIX A SUMMARY OF CALCULATIONS * 

### Average Stack Gas Flow at Stack Conditions (Qa), acfm 

### Qa 

### = 60 sec/min x Vs x As where, Vs = 

### stack gas velocity, ftlsec As = 

### cross-sectional area of stack, ft 2 

### Qa 

## = 60 sec/min 

### x 55.1 ft/sec 

### x 4.28 ft 2 

## = 1.4 E 

## + 04 acfm Average Stack Gas Flow at Standard Conditions (Qs), dscfm

0 

### R Ps Qs=/7.647-- 

### x Qa 

### x (1-Bws) 

### xin. Hg Ts where, Qa 

### = average stack gas flow at stack conditions, 

### ftl /min Bws =moisture content (dimensionless) Ps =absolute stack gas pressure, in. Hg Ts =absolute stack temperature, 0 

### R 

### oR 1 

### E 0 acf 

### (1 0 065:} 

### 30

· 23 in. Hg
-- 7.6 

### E 

## + 03 dsc·hm Qs=17.647 X 

### .4 

## + 4- X
- · I X 

## 9230 R :1' 

### in. 

## Hg min Particulate Concentration (c 5 ), 

### grains/dscf 

### M n 

### x0.0154 c ------

s- 

### Vmstd where, Mn = particulate mass from filter and front half rinse, mg Vmstd =standard meter volume, dscf


### c = 

### 10.0 

### mgx 0.0154 

### grains/mg 

# = 4.2 

### E-03grainsldscf

s 

### 3 7.1 02 

### dscf Particulate Emission Rate (PMR), lbs/hr 

## PMR = 

## cs x Qs x60+7000 where, Qs = 

### volumetric flow rate, dscfm 

## Plv/R 

# = 4.2 

### E- 03 

### grains I dscf x 7.6 

### E 

## + 03 

### dscf /minx 60 min/ 

### hr 7000 

### grains I lb PMR 

## = 0.27 lbs/hr

c:\\ProJects\Monarch\2003-0711 A\EngineeringTestRepor1 A- 3E. ROBERTS 

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### w CO Concentration (Ceo (stack)), 

### ppmvd 

# * APPENDIX A SUMMARY OF CALCULATIONS

aa 

# *

Ceo (stack) 

## = Ceo (NDJR) x 

### (1- Feo2) where, 

### Ceo (stack) = CO cone. in stack, ppmvd Ceo (NDIR) =CO cone. measured by analyzer, ppmvd 

### Fcoz= Volume fraction ofC0 2 

### in sample, %/100 

### Ceo (stack) 

## = 149.2 ppmvd x (1
- (2. 411 00) 

# = 145.6 ppmvd CO Emission Rate (ER), lbs/hr ER = (Cx * MW x 

## * Qs 

## * 60 * 28.32) 

### I (24.04 

# * 10 E+06 

## * 454) where, Qs = volumetric flow rate, dscfm Ceo (stack) = CO concentration in stack, ppmvd MW = molecular weight, 28.01 gig-mole ER = (145.6f.LL/L*28.0lg!g-mole*7.6E+03*60minlhr*28.32L/ft 3 )/(24.04L/g-mole*lOE+06 f.LLIL*454gllb) ER = 4.85 lbslhr

h - ws

**~** 6Ai &A& A g 4& A &4?4 dr¥AW§S4 c:\\Projects\Monarch\2003-0711 A \EngineeringTestRcport A·4E. ROBERTS

# Aile~& 

# Associates INCORPORATED 

## APPENDIX A SUMMARY OF CALCULATIONS
TABLE A-t KILIN MAIN- VOLUMETRIC FLOW RATE CALCULATIONS
Run Number I 2 3 Average Date 12/1112003 12/11/2003 12/11/2003 

# ---

Square Root of Delta P, (in. H20)"'h 0.740 0.730 0.742 0.737 Pitot Tube Coefficient (Cp) 0.84 0.84 0.84 0.84 Barometric Pressure (Pb ), in. Hg 30.21 30.21 30.21 30.21 Static Pressure (Pg), in. H20 0.32 0.30 0.30 0.31 Stack Pressure (Ps), in. Hg 30.23 30.23 30.23 30.23 Stack Diameter, in. 28 28 28 28 Stack Cross-sectional Area, ft"2 4.28 4.28 4.28 4.28 Temperature (ts), °F 463.0 466.6 465.7 465.1 Moisture (Bws) 0.065 0.063 0.061 0.063 C02 Concentration (C02),% 2.4 2.5 2.4 2.4 02 Concentration (02),% 16.8 16.6 16.9 16.8 Molecular Weight (Ms), lb/lb-mole 28.34 28.36 28.39 28.36 Velocity (Vs), ftlsec 55.1 54.5 55.4 55.0 Volumetric Flow Rate

At Stack Conditions (Qa), ACFM 14!146 13,988 14,203 14,112 At Standard Conditions (Qs), DSCFM 7,646 7,540 7,684 7,623

c·\\Projects\Monarch\2003-0'7 llA\EngineeringTestReport A-5E. ROBERTS

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# Associates INCORPORATED 

## APPENDIX A 

## SUMMARY 

# OF CALCULATIONS *'6' Wt*M* ffib 8 Rfi±trit*g& ± $ e ±*e 

# , ..... '*.

. +id ¥E1 

## TABLEA-2 KILN MAIN- EMISSION CALCULATIONS Run Number 

### I 2 3 Mean Date 12111/2003 12/11/2003 12/11/2003 

# --- Clock Time 1234-1338 1417-1521 1555-1700 

# --- { .... .. .**·~~** 

### :

.. · 

# . ·:<D.Wu.t.D..AWA: ... . ..

., : ... . .. Process Rate, tonslhr 5.65 5.65 5.65 5.65 Run Time, min 60 60 60 60 Barometric Pressure, in. Hg 30.21 30.21 30.21 30.21 Meter Correction Factor 1.035 1.035 1.035 1.035 Orifice Calibration Value 1.913 1.913 1.913 1.913 Meter Volume, ft"3 35.342 34.932 35.496 35.257 Meter Temperature, °F 67.2 71.7 63.8 67.6 Meter Orifice Pressure, in. H20 1.246 1.216 1.245 1.236 Volume H20 Collected, mL 54.4 52.3 51.7 52.8 Nozzle Diameter, in 0.248 0.248 0.248 0.248 Area of Nozzle, ft"2 0.00034 0.00034 0.00034 0.00034**P~iculate** Mass, mg 10.0 8.2 6.0 8.1 Carbon Monoxide Concentration, ppmvd 149.2 150.4 154.9 151.5 ISOKINETIC DATA Standard' Meter Volume, 

### ft? 37.102 36.358 37.505 36.988 Standard Water Volume, 

# re 2.561 2.462 2.434 2.485 Moisture Fraction (Measured) 0.065 0.063 0.061 0.063 Meter Pressure·, in Hg 30.30 30.30 30.30 30.30 Volume at Nozzle, ft"3 68.62 67.43 69.30 68.45 Isokinetic Sampling, (1 00% +I- 1 0%) 103.1 102.4 103.7 103.0 Orifice Calibration Checks,(+/- 5%) 2.2 2.2 2.7 2.4 '· : j ... , .. '·:-·
... 

### .EMISSION·D:A:TA

.. . .-<;:: :'' ' . - . ' . - - . Particulate Concentration, grains/DSCF 4.2E-03 3.5E-03 2.5E-03 3.4E-03 Particulate Emission Rate, lbslhr 0.27 0.22 0.16 0.22 CO, ppmvd (C02 corrected) 145.6 146.6 151.2 147.8. CO Emission Rate, lbs/hr 4.85 4.82 5.07 4.91

Hh HQiiM c:\\Projecls\Monarch\2003-0711 A \EngineeringTesiReport A -6E. ROBERTS 

# Alle:y& Associates INCORPORATED 

# APPENDIX A SUMMARY OF CALCULATIONS
*Eifb 

### TABLEA-3 

## KILN COOLER- VOLUMETRIC FLOW RATE CALCULATIONS
Run Number 1 2 3 Average Date 12/1112003 12/11/2003 12/11/2003 

# ---

Square Root of Delta P, (in.**1-120)"~** 1.199 1.203 1.203 1.202 Pitot Tube Coefficient {Cp) 0.84 0.84 0.84 0.84 Barometric Pressure {Pb ), in. Hg 30.21 30.21 30.21 30.21 Static Pressure (Pg), in. H20 0.20 0.18 0.19 0.19 Stack Pressure (Ps), in. Hg 30.22 30.22 30.22 30.22 Stack Diameter, in. 31 31 31 31 Stack Cross-sectional Area, ft"2 5.24 5.24 5.24 5.24 Temperature (ts), °F 276.1 273.3 265.2 271.5 Moisture {Bws) 0.012 0.013 0.014 0.013 C02 Concentration (C02),% 0.0 0.0 0.0 0.0 02 Concentration (02), % 21.0 21.0 21.0 21.0 Molecular Weight {Ms), lb/lb-mole 28.71 28.70 28.68 28.70 Velocity (Vs), ftlsec 79.3 79.5 79.0 79.3 Volumetric Flow Rate

At Stack Conditions {Qa), ACFM 24,942 24,986 24,849 24,926 At Standard Conditions (Qs), DSCFM 17,853 17,925 18,005 17,927

c·\\Projects\Monarch\2003-07 I I A \EnginceringTestReport A -7E. ROBERTS

# Aile~& 

# Associates INCORPORATED 

## APPENDIX A SUMMARY OF CALCULATIONS

TABLEA-4 KILN COOLER- EMISSION CALCULATIONS Run Number 1 2 3 Mean Date 12/11/2003 12/1112003 12/1112003 

# --- Clock Time 1235-1339 1417-1521 1556-1700 

# --- .'**:-:r~, ~~**  ,_: ·: .· ·:**'~·** :·: :· ·: 

### .. ' ·'· 

# ·**.·~·.L•tttw:t>~x~··** 

# . '·. .. . ::**·~** :

. '. I Process Rate, tons/hr 5.65 5.65 5.65 5.65 Run Time, min 60 60 60 60 Barometric Pressure, in. Hg 30.21 30.21 30.21 30.21 Meter Correction Factor 0.997 0.997 0.997 0.997 Orifice Calibration Value 2.211 2.211 2.211 2.211 Meter Volume, ft"3 37.372 37.651 38.041 37.688 Meter Temperature, °F 50.0 56.8 57.5 54.8 Meter Orifice Pressure, in. H20 1.598 1.595 1.595 1.596 Volume H20 Collected, mL 9.9 11.1 12.2 11.1 Nozzle Diameter, in 0.187 0.187 0.187 0.187 Area ofNozzle, ft"2 0.00019 0.00019 0.00019 0.00019 Particulate Mass, mg 3.3 3.2 2.4 3.0 Carbon Monoxide Concentration, ppmvd 7.6 10.9 10.7 9.7

.**~-** 

### rsoKINETIC,DATA Standard Meter Volume, 

### ftl 39.100 38.873 39.223 39.066 Standard Water Volume, ft 3 0.466 0.522 0.574 0.521 Moisture Fraction (Measured) 0.012 0.013 0.014 0.013 Meter Pressure, 

### in Hg 30.33 30.33 30.33 30.33 Volume at Nozzle, ft"3 54.60 54.17 54.11 54.29 Isokinetic Sampling, (100% +/- 10%) 100.3 99.3 99.7 99.8 Orifice Calibration Checks,(+/- 5%) -0.6 -0.4 0.6 -0.1

·- ·. ·:c .. - ... ·. i;:
.**~-_,:** .. 

# ';·:eMisst0NtPAT**A-~--** .. ...**~** ,: Particulate Concentration, grains/DSCF 1.3E-03 1.3E-03 9.4E-04 1.2E-03 Particulate Emission Rate, lbs/hr 0.20 0.19 0.15 0.18 Carbon Monoxide Emission Rate, lbs/hr 0.59 0.85 0.84 0.76

;
. M&f?iht¥4¥4 RRW 1W¥ ,;, ? 

# '' c:\\Projects\Monarch\2003-0711 A\EngineeringTestReport A· 8E. ROBERTS 

# Alle:y& 

# Associates ll'tCORPORATED tt% 

## APPENDIX A 

# SUMl.'dARY OF 

# CALCULATIONS
M' iii 

### TABLEA-5 

## PRESS DRYER- VOLUMETRIC FLOW RATE CALCULATIONS
Run Number 1 2 3 Average Date 12/12/2003 12112/2003 12/12/2003 

# ---

Sguare Root of Delta P, (in. H20)"!4 0.811 0.828 0.819 0.820 Pitot Tube Coefficient (Cp) 0.84 0.84 0.84 0.84 Barometric Pressure (Pb ), in. Hg 30.28 30.28 30.28 30.28 Static Pressure (Pg), in. H20 0.44 0.38 0.39 0.40 Stack Pressure (Ps ), in. Hg 30.31 30.31 30.31 30.31 Stack Diameter, in. 16.5 17 17 17 Stack Cross-sectional Area, ft"2 1.48 1.48 1.48 1.48 Temperature (ts), °F 257.5 262.3 261.3 260.4 Moisture (Bws) 0.054 0.060 0.069 0.061 C02 Concentration (C02), % 2.0 1.5 2.5 2.0 02 Concentration (02),% 18.5 18.5 18.5 18.5 Molecular Weight (Ms), lb/lb-mole 28.46 28.32 28.38 28.38 Velocity (Vs), ftlsec 53.1 54.6 53.9 53.9 Volumetric Flow Rate

At Stack Conditions (Qa), ACFM 4,732 4,862 4,799 4,798 At Standard Conditions (Qs), DSCFM 3,336 3,381 3,313 3,343

c:\\Projects\Monarch\2003-0711 A\EngineeringTestRepon A-9E. ROBERTS 

# Alle1& Associates INCORPORATED 

# APPENDIX A SUMMARY OF CALCULATIONS
&e 

### =e e 

# * '5 

### TABLEA-6 PRESS DRYER- EMISSION CALCULATIONS Run Number 2 3 Mean Date 12/12/2003 12/12/2003 12/12/2003 Clock Time 845-949 1020-1124 155-1300 Run Time, min 60 60 60 60 Barometric Pressure, in. Hg 30.28 30.28 30.28 30.28 Meter Correction Factor 1.035 1.035 1.035 1.035 Orifice Calibration Value 1.913 1.913 1.913 1.913 Meter Volume, ft"3 38.057 37.524 37.564 37.715 Meter Temperature, °F 41.0 52.3 57.8 50.4 Meter Orifice Pressure, in. H20 1.508 1.435 1.427 1.457 Volume H20 Collected, mL 51.3 55.6 62.9 56.6 Nozzle Diameter, in 0.231 0.231 0.231 0.231 Area of Nozzle, ftA2 0.00029 0.00029 0.00029 0.00029 Particulate Mass, mg 20.7 27.4 25.9 24.7 Carbon Monoxide Concentration, ppmvd 127.2 139.3 137.5 134.7

. '··' - .... >· ·' IS0KINETIC.:E>ATA

.. Standard Meter Volume,

**~** 42.165 40.650 40.261 41.025 Standard Water Volume, ft 3 2.415 2.617 2.961 2.664 Moisture Fraction (Measured) 0.054 0.060 0.069 0.061 Meter Pressure, in Hg 30.39 30.39 30.38 30.39 Volume at Nozzle, ft"3 59.80 58.43 58.29 58.84 lsokinetic Sampling,{IOO% +/- 10%) 107.4 102.2 103.3 104.3 Orifice Calibration Checks, ( 

### +/- 5o/o) 2.0 2.7 2.7 2.5 Particulate Concentration, grains/DSCF 7.6E-03 l.OE-02 9.9E-03 9.3E-03 Particulate Emission Rate, lbslhr 0.22 0.30 0.28 0.27 CO, ppmvd (C02 corrected) 124.6 137.2 134.1 132.0 Carbon Monoxide Emission Rate, lbslhr 1.81 2.02 1.94 1.92



# "* UP ¥44

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## a E. ROBERTS 

# Aile'-& Associates INCORPORATED d -- .£.&
- . . . ....... jj JliiJW!Ji
. _ 

### as. s J..
.. ·-----·- ·


# APPENDIXB

.. 

# ·-·-, 

# .. Ti .. ,. -·-



# FIELD DATARun1 Analyzer Data Date 

### 12/11/2003 Company Monarch Tile Source !Kiln Main Run# 

### 1 

## I Time 

## co Time 

## co PPM PPM 12:35 143.7 13:18 146.9 12:36 143.6 13:19 147.4 12:37 141.4 13:20 149.3 12:38 139.6 13:21 151.2 12:39 145.7 13:22· 152.6 12:40 145.2 13:23 152.9 12:41 145.5 13:24 153.5 12:42 145.7 13:25 153.7 12:43 145.4 13:26 155.0 12:44 144.5 

## I 13:27 158.6 12:45 142.7 13:28 160.4 12:46 140.9 

## I 13:29 160.4 12:47 142.1 13:30 161.5 12:48 143.3 13:31 163.4 12:49 143.7 13:32 163.1 12:50 144.3 13:33 161.8 12:51 145.2 13:34 161.4 

## I 12:52 145.4 Average 

### 149.2 

### 12:53 145.2 12:54 145.3 12:55 145.8 12:56 145.2 12:57 145.5 12:58 145.8 12:59 145.6 

## --·--- -·----- 13:00 145.8 13:01 I 

### 146.4 

## I I 

### 13:02 147.2 13:03 148.1 13:04 148.3 13:05 148.6 13:06 148.6 I i I
... 

## ___ .,._ 

## ! +--- 

### 13:07 148.2 I 

## I I
··- ,____ 

## ________ 13:08 146.2 I 

## i !

- 13:09 147.6 I 

### 13:10 151.7 13:11 151.3 13:12 152.3 13:13 152.9 l 

### 13:14 152.6 

## I 13:15 152.4 13:16 151.8 13:17 149.7

Page 1Run 2 

### Analyzer Data Date 

### 12/11/2003 Company· Monarch 

### Tile Source Kiln Cooler Run# 

### 2 Time 

# co Time 

# co PPM .PPM 

### 14:17 150.7 15:00 

### 147.5 14:18 150.7 

## I 15:01 147.7 14:19 150.2 i 

### 15:02 147.7 I i I 

### 14:20 148.1 15:03 146.9 14:21 146.8 15:04 147.0 14:22 147.3 15:05 147.9 14:23 147.3 15:06 149.0 14:24 147.8 15:07 149.0 14:25 148.2 15:08 149.5 14:26 149.3 15:09 149.9 14:27 150.9 

## I 15:10 150.4 14:28 152.1 

## I 15:11 150.7 14:29 153.2 15:12 150.8 14:30 153.5 15:13 151.0 14:31 152.9 15:14 151.4 14:32. 153.4 I 

### 15:15 151.5 14:33 154.9 15:16 152.3



### -- 

# - 14:34 155.3 Average 

### 150.4 

### 14:35 155.9



### -- 

# -·---- 14:36 156.1 14:37 156.5 14:38 156.7 14:39 156.3, 14:40 155.6 j 

### 14:41 153.2 

### I



# - l 

### 14:42 150.6 l 

### 14:43 152.0 

## I 14:441 152.0 14:45, 152.6 14:46 151.9 14:47 151.4 14:481 150.8 

## ! 14:49 150.4 I 

### 14:50 . 149.3 I 

# ==i= -- 1-· 

## I 

## i -- 14:51 147.0 14:52 145.3 

## I 

# ·-r-·--r- ---f--· 

### -· 14:53, 145.4 I I 

### 14:54 145.6 I 

### 14:55 146.0 i 

### 14:56 147.0 

## I I 14:57 146.6 

### I I 

### 14:58 14.7.7 

## I 14:59 147.8 

### I 

## I ! Page 1Run 3 Analyzer Data Date 

### 12/11/2003 Company Monarch Tile Source Kiln Main Run# 

### 3 Time 

## co Time 

# co PPM PPM 

### 16:02 155.0 16:45 152.4 16:03 156.1 16:46 155.2 16:04 157.1 16:47 154.5 16:05 157.2 16:48 155.9



### ·- 16:06 158.6 I 

### 16:49 157.2 16:07 158.7 I 

### 16:50 157.0 16:08 157.8 16:51 157.2 16:09 157.4 16:52 156.7 16:10 157.4 16:53 156.2 16:11 159.0 16:54 154.2 16:12 159.3 16:55 151.7 16:13 158.7 16:56 152.9 16:14 159.0 16:57 153.8 16:15 159.3 16:58 154.2 16:16 159.3 16:59 154.4 16:17 158.6 17:00 153.5 16:18 158.4 17:01 153.3 16:19 157.4 Average 

### 154.9 16:20 156.5 16:21 155.5 153.7 --· **-·--~-** 

### --·. - 

# - 16:22 16:23 151.8 r---·--· 

### 16:24 150.8 16:25 151.7 i 

### 16:26 152.3 

## I 16:27 152.4 

## I 16:28 152.0 16:29! 153.0 16:30 155.1 I I 

### 16:31 153.2 

### i 16:32 152.2 16:33 152.6 16:34! 152.4 ! 

### 16:35 152.1 

## I l ! I 

### 16:36 152.8 I 

## ! 

## i 16:37 153.6 

## I i 16:38 153.8 

### I 16:39 153.7 16:40 153.7 I 

### i 

### 16:41 i 

### 153.7 

## I i 

### 16:42: 154.1 

## I I 

### I 

## ! 16:43i 151.4 

## i i 

### 16:44 147.7 j 

## i I 

## I I 

# l I 

## I I I Page 1Run1 Analyzer Data Date 

### 12/11/2003 Company Monarch Tile Source Kiln Cooler 

### Run# 

### 1 Time 

# co Time 

# co PPM PPM 

### 12:35:08 6.7 

### I ' 13:18:08 7.5 12:36:08 6.4 

## ! 13:19:08 7.7 12:37:08 6.2 13:20:.08 7.4 12:38:08 6.2 13:21:08 7.5 12:39:08 6.2 13:22:08 8.0 12:40:08 

### 6.0 13:23:08 8.4 12:41:08 6.3 13:24:08 8.4 12:42:08 6.8 13:25:08 8.5 12:43:08 7.1 13:26:08 8.0 12:44:08 7.5 13:27:08 7.8 12:45:08 7.2 13:28:08 8.0 12:46:08 7.0 13:29:08 7.7 12:47:08 7.1 13:30:08 7.8 12:48:08 6.9 13:31:08 8.1 

### 12:49:08 7.2 13:32:08 7.8 12:50:08 7.3 13:33:08 8.0 12:51:08 7.9 13:34:08 7.8 12:52:08 9.0 Average 

### 7.6 i 

## - I 

### 12:53:08 8.7 I



## -- _____ __t__ 

### 12:54:08 8.3 I 

# 1 ! .. - 

## -- ;-----···- 

### 12:55:08 8.7 

### I



# --- 12:56:08 I 

### 8.8 12:57:08 

### I**8~6** 

## I 

## I 12:58:08 8.3 12:59:08 8.3 13:00:08 8.4 

### I 13:01:08 8.0 13:02:08 8.0**--~·** 

### 13:03:08 7.8 I 

### 13:04:08 7.9 

## I 13:05:08 7.9 13:06:08 7.9 I I 

### 13:07:08 7.7 

## i 13:08:08 7.5 

## I 13:09:08 7.2 I I ! 

### 13:10:08 7.0 I 

## ! 13:11:08 6.9 

## I i 

### 13:12:08 6.9 

### I ! 

## I 13:13:08 

## I 7.1 

## I ! 

### ·-,------ .. 

### - 

# ··----,---- I i ·- - 

# l --1.- 

### - 

# T 13:14:08 

## I 7.3 13:15:08 

## I 7.2 I I i 

### 13:16:08 7.3 

# I 13:17:08 

### 7.3 

## I l I 

## i 

# I I I Page 1Run 2 

## I Analyzer Data Date 

### 12111/2003 Company Monarch Tile Source Kiln Main Run# 

### 2 Time 

# co Time 

# co PPM 

## I PPM 

## I 14:17:32 9.8 15:00:32 11.7 

## I 14:18:32 9.2 15:01:32 11.2 I 

### 14:19:32 9.1 15:02:32 11.4 14:20:32 9.4 15:03:32 11.7 14:21:32 9.5 15:04:32 11.7 14:22:32 9.4 15:05:32 12.0 14:23:32 10.5 

## I 15:06:32 11.7 14:24:32 10.6 j 15:07:32 11.2 

## I 14:25:32 10.5 15:08:32 11.4 

## ! 14:26:32 10.9 I 

### 15:09:32 11.7 

# i 14:27:32 11.1 

## I 15:10:32 11.5 I I 

### 14:28:32 11.0 15:11:32 11.1 14:29:32 11.2 15:12:32 10.7 14:30:32 11.2 15:13:32 10.1 

## I 14:31:32 11.4 15:14:32 10.1 14:32:32 11.0 15:15:32 9.9 

## I 14:33:32 10.6 15:16:32 9.7 

## I 14:34:32 10.7 Average 

### 10.9 

### 14:35:32 10.9 14:36:32 10.9



### -



# ~ 14:37:32 11.1 14:38:32 11.0 14:39:32 11.1 I 

### 14:40:32 11.2 I I i I f-
___ __j__
___ 

### 14:41:32 

# L ! 

### ------ 11.2 

## ---·- I 

### . 

### -- 1-- 

# --

14:42:32 11.3 I 

## I I 

### 14:43:32 11.3 

## I 14:44:32 11.4 14:45:32 I 11.2 14:46:32 j 

### 11.4 

## ! 14:47:32 

### ! 10.9 

### ! 

## I 14:48:32 

## ! 10.5 

## i 14:49:32 : 10.4 I 

### 14:50:32 

## ! .10.6 14:51:32 11.0



### - 14:52:32 10.7 14:53:32 10.5 14:54:32 10.5 14:55:32 10.9 

## I 14:56:32 10.7 

## I 

# I I 

# ! i I


### - I 

### 14:57:32 12.4 

## I I 

## I i ___L_ l 

### 14:58:32 12.4 I 

## i ! 

## I I I I 

### 14:59:32 12.1 

## I 

# I I


## ·- 

## I I 

### I I 

## I Page 1

### Run 3 Analyzer Data Date 

### 12/11/2003 Company Monarch Tile Source Kiln Cooler Run# 

### 3 

## I Time 

## co Time 

# co PPM I PPM 

## I 16:02:15 11.8 16:45:15 11.1 16:03:15 11.7 16:46:15 11.5 16:04:15 11.5 16:47:15 11.2 16:05:15 

### 11.7 16:48:15 

## I 11.2 16:06:15 11.5 16:49:15 

## I 11.1 16:07:15 11.3 16:50:15 11.1 16:08:15 11.5 

### I 

## I 16:51:15 11.1 16:09:15 11.4 16:52:15 11.2 

## I 16:10:15 11.3 16:53:15 11.2 I 

### 16:11:15 11.1 ( 

### 16:54:15 I 11.2 16:12:15 11.2 

## I 16:55:15 11.0 16:13:15 10.9 I 

### 16:56:15 10.8 

## I i 

### 16:14:15 10.9 

## I 16:57:15 10.7 16:15:15 10.8 

## I 16:58:15 10.5 16:16:15 10.7 

## I 16:59:15 10.3 16:17:15 10.5 17:00:15 10.2 16:18:15 10.6 17:01:15 10.0 16:19:15 

## I 10.5 

### Average 10.7 16:20:15 10.4 16:21:15 10.2 

## I 16:22:15 10.2 16:23:15

# 1~ -

# -~ 16:24:15 9.8

·- 

### 16:25:15 9.8 : 

## ! 

## ·--- 16:26:15 9.6

·-- 

### 16:27:15 9.6 I I 

### 16:28:15 9.8 

## l

--- 16:29:15 9.8 

# -+ 16:30:15 10.0 

## I 16:31:15! 10.3 

## i 16:32:15 

## i 10.5 I 

## ! I 

### 16:33:15 

## I 10.6 I 

## _J__ :**~16:34:15** I ! 

# - ! 

## -- 10.4 ! 

### 16:35:15 10.3 16:36:15 10.3 i I 

### 16:37:15 10.0 I 

## I 16:38:15 10.1 16:39:15 10.0 16:40:15 10.3 16:41:15 1 

### 10.3 

### i i [ I 

### 16:42:15 I 10.4 

## I I 

## I I i 

## ' I I 1 I : 

### 16:43:15 

### I 10.6 !

# +-----~· I 

# l ' I 

### 16:44:15 

## ! 10.7 

## I 

# I : 

# l -I ; I 

## I I I Page 1

### Run1 Analyzer Data Date 

### 12/12/2003 Company Monarch Tile 

### Source Dryer Run# 1

Time 

# co Time CO 

## PPM 

## I PPM 

### 8:46:34 146.0 9:29:34 119.0 8:47:34 149.3 9:30:34 118.3 8:48:34 151.2 9:31:34 117.2 8:49:34 154.5 9:32:34 116.6 8:50:34 152.8 9:33:34 115.5 8:51:34 144.2 9:34:34 114.9 8:52:34 136.7 9:35:34 113.8 8:53:34 135.9 9:36:34 113.5 8:54:34 133.9 9:37:34 114.1 8:55:34 134.0 9:38:34 112.6 8:56:34 134.7 

## ! 9:39:34 112.4 8:57:34 134,4 1 

### 9:40:34 111.4 8:58:34 134.5 

## ! 9:41:34 113.1 8:59:34 134.3 9:42:34 114.2 9:00:34 135.5 1 

### 9:43:34 114.2 9:01:34 136.6 

## I ! 

### 9:44:34 113.6**~~~--r~~~~------~----~--------~~~-r~~~r-------** 

### 9:02:34 137.2 9:45:34 113.7 9:03:34 137.7 Average 127.2 

### 9:04:34 127.5 1

## ~9~:0~5:~34~---1~2~6.~9~---------~------+-------~-----~---------~----- 9:06:34 136.6 I 

### 9:07:34 138.3 9:08:34 139.0 9:09:34 140.4 9:10:34 140.7 

## I**~~~~-r~~~~------~-----r------~----~------r------** 

### 9:11:34 140.5 9:12:34 140.5 9:13:34 140.3 9:14:34 138.5 

## I I 9:15:34 114.2 I 

### 9:16:34 109.0 

## I 9: 17: 34 

## l 113. 3 

## !

.. 

### 9: 

### 18: 34 118. 5 I 

## i . I : I



### ___

9_:1_9:_34_ 12o.s

## T~==----~----··· 

# .. I·_-
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# _____ L
_____

## -~_**----~=** 9:20:34 124.1
. 

## I l ' · 9:21:34 -· 120.0**~-----,** 

### ----· :**~----** 

### 9:22:34 113.6 9:23:34 116.2 9:24:34 117.9 9:25:34 120.2 9:26:34 120.7 9:27:34 120.8 9:28:34 120.7

Page 1Run 2 

## I 

## I Analyzer Data Date 

### 12/12/2003 Company Monarch Tile Source 

## I Dryer Run# 

### 2 Time 

# co Time 

# co PPM 

### PPM 

### 10:20:32 160.1



# ~ 11:03:32 137.2 10:21:32 161.7 11:04:32 137.7 10:22:32 156.2 11:05:32 137.7 10:23:32 154.1 

## l 11:06:32 137.2 10:24:32 150.6 11:07:32 136.6 10:25:32 147.6 11:08:32 136.6 10:26:32 144.7 11:09:32 136.7 10:27:32 144.3 11:10:32 137.3 10:28:32 143.3 I 

### 11:11:32 136.5 10:29:32 141.7 11:12:32 136.1 10:30:32 140.6 11:13:32 136.2 10:31:32 139.3 11:14:32 134.8 10:32:32 139.1 

## I 11:15:32 134.3 10:33:32 137.8 11:16:32

**~33.9** 

### 10:34:32 137.7 11:17:32 134.2 10:35·:32 138.5 

## I 11:18:32 131.2 10:36:32 139.0 11:19:32 111.4 10:37:32 1 

### 138.3 Average 

### 139.3 10:38:32 137.1 

# -1----· ----· 

### 10:39:32 137.1 

# . ·-··--t-·---- ._ .. __ .. --". -........ . ··- .!
.. ----· . 

### - -· .. 

### ---.-------- :-· ._ ...... 

### ····--- ·--- 

### 10:40:32 136.6


### . I 10:41:32 137.5 

# -+ ·---- :---- 

## ·-

.. 

## I I 

### 10:42:32 137.9 i 

### 10:43:32 137.6 I 

### ! j 

### 10:44:32 138.6 10:45:32 139.1 10:46:32 138.7 

### I 10:47:32 137.8 

## ! 10:48:32 138.0 10:49:321 140.5 10:50:32 140.2 10:51:32 

### I 139.4 10:52:32 139.0 I I 

### 10:53:32 138.2 I I 

# [ I 

### 10:54:32 

# l 138.3 

## ! I I 

### 10:55:32 

## l 140.2 ! 

## I 

## I l 

### 10:56:32 140.3 1 

## I 10:57:32 ! 

### 139.5 

## I 10:58:32 137.4 

### I 1 

### 10:59:32 136.6 I I 

### 11:00:32 137.2 

## I 

# I 11:01:32 137.4 

### I 

### ! ! 

### 11:02:32 

## l 137.1 I I 

# I l 

## I : 

## I Page 1Run 2 Analyzer Data Date 

### 12112/2003 Company Monarch Tile Source Dryer Run# 

### 2

Time 

## co Time 

## co PPM PPM 

### 10:20:32 160.1 11:03:32 

## I 137.2 10:21:32 161.7 11:04:32 

## I 137.7 10:22:32 156.2 11:05:32 137.7 10:23:32 154.1 11:06:32 137.2 10:24:32 150.6 

## I 11:07:32 136.6 10:25:32
. 147.6 11:08:32 136.6 10:26:32 144.7 

## I 11:09:32 136.7 10:27:32 144.3 11:10:32 137.3 10:28:32 143.3 11:11:32 136.5 10:29:32 141.7 11:12:32 136.1 10:30:32 140.6 11:13:32 136.2 10:31:32 139.3 11:14:32 134.8 10:32:32 139.1 11:15:32 134.3 10:33:32 137.8 11:16:32 

## I 133.9 10:34:32 137.7 11:17:32 134.2 10:35:32 138.5 11:18:32 131.2 10:36:32 139.0 

## I 11:19:32 111.4 10:37:32 138.3 

## I Average 

### 139.3 

### 10:38:32 137.1 10:39:32 137.1



## - 10:40:32 136.6 ' 

### 10:41:32 137.5 I 

### 10:42:32 137.9 10:43:32 137.6

·- 

### 10:44:32 138.6 I


## - 

## --- 10:45:32 139.1 I 

### 10:46:32 138.7 10:47:32 137.8 

## I 10:48:32 138.0 i 

### 10:49:32 140.5 

## I 10:50:32 

## i 140.2 10:51:32 139.4 10:52:32 139.0 

## I 

## I i 

### i I 

### 10:53:32 : 138.2 r I ! I I 

### 10:54:32 I 138.3 

# l I 

### I I I 

### 10:55:32 

## I 140.2 

## I I 10:56:32 140.3 j 

## ! 10:57:32 139.5 I I I t I 

### 10:58:32 

## ! 137.4 

## I I ' ! 

## i j 

### 10:59:32 i 

### 136.6 

## i ! j 

# L
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## I i i 

## -- 137.2 I I ! 

### I 

## : I ·--- - -· 11:01:32 

## I 137.4 

# L
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### 11:02:32 137.1 I l I ! i I

### .~ 

## I I 

### I ! 

## I I ' I Page 1Run 3**Anal~er** 

### Data Date 12/12/2003 

### Comp_any Monarch Tile Source D_ryer 

### Run# 3

Time 

## co Time 

## co PPM 

## I PPM 11:56:47 147.0 12:39:47 134.3 

### 11:57:47 144.4 

## I I 12:40:47 135.0 11:58:47 144.0 1 

### 12:41:47 133.7 1 

### 11:59:47 146.8 12:42:47 133.4 12:00:47 146.4 12:43:47 133.2 12:01:47
. 146.2 

## I I 

### 12:44:47 132.2 12:02:47 1
__ 

### 14_7_.4_-1---·------!-i ---+---------+--12_:4_5_:4_7--+--_13_3_.4___,
___ --1 

### 12:03:47 I 

### 147.8 12:46:47 134.4 

## !**-~~~~--------:~----~------~~~~~~~~~-------** 

### 12:04:47 145.2 I 

### 12:47:47 134.1 

## I 12:05:47 142.8 12:48:47 134.2 12:06:47 143.0**~** 

### 12:49:47 134.5 12:07:47 141.8 12:50:47 135.5 12:08:47 141.5 12:51 :47 135.5 12:09:47 141.0 

## I 12:52:47 135.5 12:10:47 140.4 12:53:47 136.4 12:11:47 140.6 12:54:47 136.2 12:12:47 140.9 12:55:47 135.7 12:13:47 140.5 Average 137.5 

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### 140.0

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# . : . .:..VE.LOCITY TRAVERSE DATA·· .-



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## 31 in Nipple length

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## .:z.;!i In Width of duct(rec) In Area of duct



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## ·~ 24 Duct > 24 t;;Juct . . 

# 1 : 20 24" 20 . < 24" . I: E! 16 16



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## j
. 12 12 8 4 

### s 6 7 8 8 4 56 7 8 Distance downstream ITom disturbance CIRCULAR DUCTS Traverse

point (Percent of stack diameter from number Inside wall to traverse eolnt} on a diameter 2 4 6 8 10 12 1 14.6 6.7 4.4 3.2 2.6 2.1 2 85.4 25.0 14.6 10.5 8.2 6·.7 3 75.0 29.6 19.4 14.6 11.8 4 93.3 70.4 32.3 22.6 17.7 5 87.4 67.7 34.2 25.0 6 95.6 80.6 65.8 35.6 7 89.5 77.4 64.4 8 96.8 85.4 75.0 9 91.8 82.3 10 97.4 88.2 11 93.3 12 97.9 RECTANGULAR DlJCTS 2 3 4 5 6 7 8 9 1 25.0 16.7 12.5 10.0 8.3 7.1 6.3 5.6 2 75.0 50.0 37.5 30.0 25.0 21.4 18.8 16.7 3 63.3 62.5 50.0 41.7 35.7 31.3 27.8 4 87.5 70.0 58.3 50.0 43.8 38.9 5 90.0 75.0 64.3 56.3 50.0 6 91.7 78.6 68.8 61.1 

### 7 92.9 81.3 72.2 

## a 93.8 83.3 9 94.4 10 11 12 METHOD 1 DATE
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METER CF (Y) o.'197 AMBIENT TEMP.

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TRAVERSE SAMPLE -CLOCI< VELOCITY DRY GAS STACK PROBE FILTER

POINT TIME TIME PRESSURE PRESSURE METER TEMP TEMP BOX TEMP Fy

NUMBER (Min.) (DP) {DH) ("F) (uF) (uF)

(in. H20) (ff) fb.c **~-----7-----+--~---+-----+--~~~------~~~~----+-~~~~~----+-~~-4~~L--+~~--~--~~~~~~~-r-7~~Z(L ~----------~~~~~--~~~~~------~--~~----+--~~~~---+~~~~~~~~~-7~~-;~~~~,_~~-;U~**  **~----~----;-~~--~--~~~~~------4-~~~---+--~~~~----+-~~-+~~--~~~--+-~~~~-+~~~~~~U3 -----~----;-~~--~--~~~~~------4-~~~--~--~~~~----~~~-+~~~;-~~--+-~~-r~-+~~~~7-~Lef**  **fi-----~----;-~.~--~------lr-~~~------4-~~~--~---L~~~----~~~-+~~~;-~~--+-~~-r~-+~~~~~~l~ ,-~----~---;~~~--~----+---~~--------+-~~~----~~~~~=-----+-~~~r-~----r-~~--+-~~-;~~~~--+-~~~**  l£c **~~~~----;-~~~-~--~~~~~------4-~~~---+--~~~~·----+-~~-+--~=-;-~~--+-~~~~-+~~~~~~l~** 2..fC **~----~~--~r-~~--~----+---~~~------+-~~~----~~~~~------+-~~--r-~~--~~~--+-~---;~~+-~r-+-~~--BL~** z '"f; **g-----~~---r~~--1------~--~~~----~--~~~--~--~~~~----+-~~-+~~~-r~~--~-~~_,~r-~~~r-~--~~s** -z.s· **~~~----+---~~------~~~~---+--~~~----~~~-~~~--~~~~-r~~-;~~~~-+~~~z>- ~----~----+--------~--~~~~~------4--L~~---+--~~~~----+-~~-+~~--,_~~--+-T:H---r~-+~~-r~~~zs~**  **r-------~---4--~~--~----+---~~~------+-~~~----~~~~~~----+-~~--~~~--~~~--+-~~~~~~~--+-~~~Z-5~**

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6o Delta H = <Delta **Pl(8~.~(Cpl CFDAli<Delta**  H@lCDnl 2 <Tm+460l (Ts+460)
ISOKI ETIC DATA SHEET Flue Gas Composition Oxygen,% Carbon Dioxide, % Nitrogen,% Z.St **~--~~--~~~~** Assumed

E. ROBERTS ALLEY AND ASSOCIATESIVIETI-tUU _.....r."' __ **ISOKI~ETIC** FIELD DATA

_.., CONSOLE 1.0. **f\'tc~l-..** /J Je METER CF (Y)

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(liF) PROBE TEMP ("F) FILTER BOX TEMP (F} **m--~~-----r--~--~~~-+-~~~------1-----~---~-~~~~---~~~~-+--~~~--~~~~~--~~-+~---r~--~** "i.- **M----~-----r~~--~----+---+~~------~--~~~-+--~uw~~----+-~~-r~~~~~~~~~~-~~~-+~---r~~~~' ~----~----~--~---~----+-~~~------1---~~~--~-~~~~----r-~~-+--~~-7~~-~~~--~~-+~r--r~~~Ll**  **~-----~-----;-~~--+------+---~~-----~-~~~--;---~~~~----r-~---+~~~~~~~~~L--;~--~~~~~~~~ .-------~----~~~~~-----+--~~~-------~--~~----~---~~~~----r-~~-+~~~~~~=-~~~--~~-+~~-r~~~~~**  **~----~----~~~----r-------+--~~~------~--~~----r----~~~~-------~~~-+~~~~~~~~~~--~~-r~~-r-=~~~~ r-----~-----r--~,_~------+--~~~------~~~~----~---~~~~----r-~~-+~_.=-~---~~~~~--~~-r?n~~--~--~u**  **A------~----+-~~--~---~~--~~------+---~~---+----~~~L---+-~~--+--~---r~~~+-~----r~-+~~~----~11 ~-----~------r--~--~------+----~~-------~--~~-----~---~~~~----r-~~-+~~~~~~~~~~--~~-+~----r~~~w**  t5f **ft-----~-----+--~~-+------+------~~--------~---~~~--+----~~~~--------+-~~~~~~~-1~~~-;--~--;-~~~---+~~--1~=** 1.5 **H-~~~------r~~~~------+------~~--------1----~~------+-----4~~~~---~~~-+~~~~~~--~~~--~~-+~.--r~~~~~** "'tf **~------=---~~---~~~--------+----~~-------~----~~----~---'~~~----r-~---+~~=-~~~~~~~--~~-~~~-r~~~,s n·-----~------r--~~~-----+--~~~~----~--~~~--+---~~~~~---+-~~-+~----~---~~~----~--~~-+-=~-r--~--1~;** 

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**~---------------r---~~-r-----+-------~~~----~--~~L---r---~~~~~--r-~~-+~~~~--~=-~--~--~~-r~~-r--~--1~j** "],! **~------~-----+-~~~~~----t-----~~~----+---~~~~--~~~~~--~~~-r~~~,_~~--+-~~-r~~~--~~~~** ·z..: **~----~-----r~~---r-----+--~~~~-------~--~~----r---_u~~~L---r-~~-+--a=~~---~~~--~--~~-r~r--r--~~L~ ._-··-----~--~~~~~-------+------~~~----~---~~----~--~~~~~---r-~~-+~~~~--~--~---~--~~-r~T--r~-----1I~**  7.5 **H------------~--~~~~--~-----~~-------4-~~~-----~--~~~~~L-----~~~-+~~~-+~~~-+--~o-+-77-r~~-r~~--t£**

K Factor = l • ( £a DP) --:) Ave sqrt(DH)

I. LL"S

Delta H = !Delta P)(893.94lfCpl 2 CFOA) 2 CDelta H@lfDn> 2 <Tm+460l (Ts-+460) :(c:-u

,.,...,,.?l **~t.-JL**
ISOKINETIC DATA SHEET **o.~** Flue Gas Composition Oxygen,% Carbon Dioxide, % Nitrogen,% Method **~** Orsat Assumed

E. ROBERTS ALLEY AND ASSOCIATES

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# ------ Date 

### 12 (,, 0 

### 3' Analytical Method 

## C,t ,.

**,'~:==<** Leak Check Good? {circle



# one)~ No Analysis Percent C0 2 Percent Total Percent 0 2 Percent N 2 Number Analysis Time (A) (B) 

### (B- A) (100-8) 

### 1

**~~·4s** 

### 0 

### .... ?/.0

**~** 

### 2 

### 0 

# ., Zf .-,4 3 

## n 

# '-

.... 

### Zf 

# ..-,q Average 

### n 

## """ '2.. (. 

### 0

**'7~** Run Number 

## 0'2 

## _....=;..-=---- Leak Check Good? (circle



### one~$/ No Analysis Number Analysis Time 

### 1 

### 2 

### 3

Run



### Number~tu:::;.J_,"'----- Leak Check Good? (circle one)(§) No Analysis Percent 

### C0 2 Percent Total Percent 

### 0 2 Percent N 2 Number Analysis Time (A) 

### 1 

### 0 2 

## n 3 

### 0 Average 

### () Acceptable differences for repeat analysis: if 

### C0 2 > 

### 4% then +/- 0.3% 

### if C0 2 < or= 

### 4% then +/- 

### 0.2% if 

### 0 2 > or= 

### 15°/o then +/- 

### 0.2% if 

### 0 2 < 15% then +/- 0.3% (B)



## ... 

# "-

**~'** (8- A) (100- B)



### ~7 

## "7C} 

# zl

**-~q** 

## 21 

## "1'1

- ...... 

# ,

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## .....

J.o

**~C)** ...... ( Ambient Check Oxygen



### _..,:!2~1.:-:. 

## o=---- Carbon Dioxide 

## 0
Report all values to the nearest 0.1 percent for Orsat Analysis. Report all values to the nearest 

### 0.5 percent for Fyrite-Analysis. Comments Method 3 E. ROBERTS ALLEY & ASSOCIATES

## CYCLONIC FLOW DATA CLIENT



## ~CJtqC~ 

# {\v SOURCE (.(.;_\"'



## ~w PROJECT NO. 

## :Jcp'3 · 

## 7tiA DATE 

### ('7./ U 

## I O'? ALLEY PERSONNEL



### ____;;,'Sl..;._~..;-~ ,li:;;.Q...;:;O ______ DUCT DIMENSION----- AREA
____ PITOT ID 

### # ____ AVG COEFFICIENT
____ BAR. PRESSURE
___ _ 

### SAMPLE 

### RUN# 0{ RUN# RUN#

POINT 

### ANGLE <b 

### 6P ANGLE$

**~p** 

### ANGLE<!> 6P 1 

# _t; i 

### 2 

# <.o { 3 

# 4 I 

# ' 4' 

## 5 

# I 5 

## l 

# I 6 J 

# \ I I 

### 7 

## 0 \ 8 

# 3 9 

# 7 10 

# s 

# I 11 

# v I 12 

## 5

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## 13 '-I 

# ' 14 

# s- 

# i 15 lJ, 

# I 16 /.':) j I 

### 17 a 

### l 

## t 18

**;~** \ 

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## 19 ........ 

# ' ..... t. l 

## 20 0



## ~ 21

**~I**



# ~ i 

## 22 .:5" i 

### ' 23 

# > I 24 

# t/ .t 25 

## 26 I 

### 27 28 

### 29 

### 30

Cyclonic Flow E. Roberts 

### Alley & Associates

### . 

## .. ...**~**

# f;~~~·.·•<: ..

# :,:~.:~;;·**-;:-::..·.~~-** .· ,

# ·~/·:-;_::~·:\;~[oc,~**r~i~~~·~:~ATt\** 

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# .i.J L
. SOURCE**:.···<;:ps.~. L')R\~)2···**  

## ...

.. 

## . . : PUCTOATA Oist from 1sr. wall to oufalde of port (-·/ hi Nipple length·
. j. 

### 5 · In
· Depth of duct 

### I Cz 

## c:; ln

V.Jidth cf duct{rec}**-~** ....... ----in Area ofduct 

### l.t.f{H 5 ··In 'LOCATION .OF**TRAV~SE** POlNIS Distance upstream of**disrurban~**

.... 111 l.O 1.5 2.0 2.0 l.S · 2.0

o-::

# rn~ 

# 1

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## •' D;?t >

## ;~ . . .

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· 9 

### f
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### ... 8 4 5 6 7 8 8 4 56 7 8 Distanca do.wnstream from disturbance CIRCUL.AR DUCTS Traveme

point (Percent 

## of stack diameter from number inside wall to traverne ooint} on a diameter 2 4 6 8 ]0**l~-** 1 14.6 6.7 4.4 3.2 2.6 2.1 2 85.4 25.0 14.6 10.5 8.2 

# e.z 3 75.0 .29.8 19.4: 14.6 11.8 4 93.3 70.4 32.3 22.6 17.7 5 87.4 67.7 34.2 25.0 6 95.6 

## ·ao:e 55.8 35.6 7 89.5 

## nA .64.4 

### a 96.8**~5.4** 75.0 9 9'1.8 82.3 10 97.4 88
. .2 11 --=· 93.3 12 97.9 RECTANGULAR DUCTS 2 3 4 5 6 7 

## a ·9 25.0 16.7 12.5 10,0 8.3 7.1 6.:3 5.5 

### '2 75.0 50.D 37.5 30.0 .25.0 21.4 18.8 '16:7 3 63.3 62.5 

### sa.o 41.7 · 35.7**3'1~3** 27_.8 4 87.5 70.0 58.3 50.0 43.8 38.9 5 9.0.0 75.0 64.3 56.3 50.0 6 91.7 78.6. 68.8' 61.1 

### 7 92.9 

## a··., 1 • ..s 72.2 8 93.8 83.3 

### e 94.4 10 1'1 12 ' 1')
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...**~** 

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# . . :;-( [' 

# j;::c.**·~)** 

# ·: . . '; 

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. 

## ·. . 

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### . Equivalent diameter 2 

### x depth x width

depth**~** width

Traverse Point



### ·1 2 3 

# I t 4 5 6 7 8 9 I '10 1

'10 11 12 5.0 4.5 4.2 15.0 13.6 '12.5 .25.0 22.7 20.6 35.0 31.8 29.2 45.0 40.9 37.5 55.0
. 50.0 45.8 

### ss.o 59.1 54.2 .i6.0 68.2 62.5 85.0 77.3 70.8 

### e·s.o 86.4 79.2 95.5 87.5 95.8 

# I ·oist 

# from ports 

### in nearest dlsturbaa up-· 

### limt**Jlr~m** 

## a**tt··~** 

## 1$. dia 

### t?J?**.~** MEASUReMENTS Distance 

# •• %of from inside**~** Diameter wall iE 

# 4. 

# 'i' ..... 

# . ., ... ( l
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---. **-~Fomn"'Al.:Dli::J** X...i"l _.iiU!iS.lHXT'lillf

## Method 3- Gas Analysis Data
Client



# _..LJ)\.o~:.~t.NL-=::::.';;...;' **~=---.....;~;....Jo· t~\xi""i----**  Location/Piant
__ £I.Jot.-J ...



### O.u:r.N=.I.C•W~+' .:..A""', <olaM- __ _ Source
__ 

### ....J12~tlr...l'~~~o"=~.P~!(_· ____ _ Run Number 

## b I Analysis Number Anal sis Time 

### 2 3

Run Number 

### f)?

**-~----** Analysis Number 

### 2 

### 3 Anal sis Time

Run Number 

# D

**~** Percent C0 2 Analysis Number Analysis Time A 

### 1 2 3
Acceptable differences 

### for repeat analysis: 

### if C0 2 > 4% then +/- 0.3% 

### if C0 2 <or= 

### 4% then +/- 

### 0.2% if 

### 0 2 > or 

# = 15% then +/- 

### 0.2% if 

### 0 2 < 

### 15% then+/- 

### 0.3% Analyst

**_:S..;;::...;.l4~--­** Date f 

# z1 t2/o3 Analytical Method 

# QtM 

# ,,('A v
Leak Check Good? (circle



## one~ No Percent Total 

### 8

Leak Check Good? (circle



## one)(~ No

0 0 0

Leak Check Good? (circle one) 

## t!{ii) No



### Ambient Check Oxygen 

# 21

**-~----** Carbon Dioxide f)



# ------ Report all values to the nearest 

### 0. 1 percent for Orsat Analysis. Report all values to the nearest 

### 0.5 percent for Fyrite Analysis. Comments Method 3 E. ROBERTS ALLEY & ASSOCIATES

## CYCLONIC FLOW 

## OAT A CLIENT



# ~~}'lt,/\!ttJlL"' -\, 

# U. SOURCE 

# <8 \>t\lfl \( DATE 

### {2../ 

## r.t/o



# ~ ALLEY PERSONNEL - 

### 'R. 0: 

## SL. .. PROJECTNO.



### ~-71tA DUCT



### DIMENSION-~=:;..._ __ _ AREA



### ~ PITOT ID 

### #'D-o<...{ AVG COEFFICIENT 

### 0

**·~** BAR. PRESSURE

**~** 

### SAMPLE 

### RUN# Ci 

### RUN# RUN#

POINT ANGLE <t> 

### ilP

**ANGLE~** 

### 6.P ANGLE <I>

**~p** 

## 1 <!) 

## D 2 

## 2. 

# (), s3 

### '$' 0."5 

### 4 t) 

### D 

### 5 b 0 

### 6 

## t (')
. I 

### 7 

## D D 8 

### D t-:"'\ 

## .._.., 9 

## 3 D

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## 10

**~** 0 I 

## 11 

## 0 

## 0 12 y

**0.~** 

## 13 0 0 •J4 

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**0.~** 

### 15 7 0,-:z 

# - 16 

### r..{ 

# n . ..:> 

## 17 0 

## (} 18

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## 0 20 0 

### () 

## 21 • r 

# i t) . 

### f .....

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## 22 I 

## 0.;) 1 

## 23 

## 3 I!).

**~** 

## 24 

# I i..f tJ 

# , f 

## 25 

## I 26 

## 27 28 29 

## 30

Cyclonic Flow E. Roberts Alley 

### & Associates__ _tt.. &b&LLLLcL
.... - ..**~t** _ m.i'ILL.LL.ifSILJ.L.Lli!!!l.!!WLL
... - L
... &L
.. &LL&a:&
__ -· _g _.&&£.& E. ROBERTS

INCORPORATED 

# APPENDIXC



# LABO·RATO:RY DATA

# Method 5 Laboratory

**~ta** 

## Facility Name: Project Number: 

# ,j?cJo3
.. Q'J 

## If 

# 4

. . 

## Source: 

# Ktln N\D,J 

# n Date: 1 

# ?.../u 

# lo

**~** 

## Run Number: I) 

## Filter Number: -f'l



## ~~3 

## Liquid Levels Marked- 

# (2 I N .A.mount of Liquid lost during transport: ·-.u:.WL.JA:L....-. ___________ _ 

## Filter Analvsis Initial filter weight (mg): 

# d54.

**~.** Final filter weight (mg); 

## {}.t;l.o

**~~7.o** 

# - - 

## ;)c;?. (.) Mass collected (mg):

**ti).~** 

## Probe/Nozzle Rinse
... !\nalvsis Actone·Volume (ml): l;)} 

# sInitial Beaker weight (g): 

# 1.1570, 

# l·

**~570,** 

# - - 

# L

**~7s:_?q** Final Beaker weight

**(g)~** 

# 1·

**7LP~** 

# I 

# J.1lfl'LI = f, ](,-;I 

## Mass collected (mg): 

# 1.-'d Blank Correction (mg):

--=" 

## Adjusted mass collected (mg): ._.,



# --?"o~f =- "" fQ.U 

# \V\·o t'·' 

### f.' 

## Condensable Analvsis Container Volume \ J• 

## Initial Beaker 

## weight (g): - 

## Final Beaker weight (g):



# ~ = Mass collected (mg):



# ~ Blank Correction (mg):



# ~--- ........_ 

# --..... Adjusted mass collected 

## (mg): ··, ....

**~-**



# ~ c:\\MyDocuments\Uploads\M5-2002Lab.A.nalysis E. Robens Alley P....:sociates, Inc.

# Method 5 Laboratory

**D~ta** 

## Facility Name: 

## Project Number: 

# doo3

**~** 

## 07114 Source: 

## Date: t? / 1 

## t / 

## o--;:. Run Number:

**0~** 

## Filter Number: 

## -#50> 

# f' Liquid Levels Marked
- 

# 6i) I N .Amount of Liquid 

## lost during transport:



# ._11~11:---------------- Filter _.c\nalvsis Initial filter weight (mg): 

## Final filter weight (mg): Mass collected (mg): 

## Probe/Nozzle ·runse 

## Analvsis Actone·volume (ml): Initial Beaker weight (g): Final Beaker weight (g): 

## Mass collected (mg): Blank Correction (mg): Adjusted mass 

## collected (mg): 

## Condensable Analvsis ;;Jtr;/.tp 

# ;)5/. ¥? 

# 3.o I'd 

# o (

**:J.L(~ ~**  

# '. 7cs-33 \'.d. ! 

# ·7lfl< I 

# f. 

# 7s-33

Container 

# Volun1e

**~·** 

## Initial Beaker weight



# (g~

**~~-** . 

### ......,_ 

## Final Beaker weight (g): Mass collected (mg): **""""'"'~-,--** 

## Blank Correction (mg): ..t\djusted mass collected 

## (mg):
c:\IJ\.1yDocuments\Uploads\1Vf5M2002LaoAnalysis 

# /.

**7'-{~** 

## J



# ----- /-7S33

E. Roberts A.Hey 

### A.ssociates 1 

### Inc. ..;:>'

# Method 5 Laboratory

**D~ta** 

## Facility Name: 

## Project Number: 

# dQc3
.. DJII4



## . . 

## Source: 

## Date: 12(11/o 

## 3 Run Number: 

# o3 Filter Number:

**5-=--~....:S":;..._..** 

## __ _ 

## Liquid Levels Marked

- 

# (jj) I N 

## .A.mount of Liquid lost 

## during transport: . 

# ....L!:.>I.!..IA:~------------ Filter Analvsis 

## Initial filter weight ( mg): 

# as /.q Final filter weight (mg):



# ~s-4. **~** 

# ::Jslf.q ..-- 

# - Q)S" 

## C./., Mass collected (mg):

**~.o** 

## Probe/Nozzle ·runse Anal:ysis Actone·Volume (ml):

**1~5.** 

## Initial Beaker weight (g): 

# l.ILfiS. {

**.{l(({~** 

# - 

# l' 7ttf5 Final Beaker 

## weight (g): 

# £. '7'5lS 

# f. 7<tl'i 

# =

**l·7~1~** 

## Mass collected 

## (mg):

**~·0** 

## Blank Correction (mg):

......::> 

## Adjusted mass

**C?oll~cted** 

## (mg): _,.



# --?"o~f:: (.p. 

# 0

**~~** l'.:

**t~ .~**  

## Condensable Analvsis 

## Container Volu..me Initial Beaker weight (g): = 

## Final Beaker weight 

## (g):



# ~- 

# - Mass collected (mg):



# ~

**~.~** 

## Blank Correction (mg): -."-..... -'-

**~** ......



### ~-<\djusted 

## mass collected ( 

## mg): -- ....

................. 

# '"'-

·- ...... c:\\MyDocuments\Up1oads\M5-2002LabAnalysis E. Roberts Alley .A.ssociates, Inc.

# Method 5 Laboratory

**D~ta** 

## Facility Name: 

## Project Number: 

# ;?Do:; .. 0711 

# A Source: 

## Date: 

## 12../t1!o3 Run 

## Number: 

# Ol Filter Number: Liquid Levels 

## Marked
- 

# 6i) I N .Amount 

## of Liquid lost during 

## transport: ........... 

# tl

...... ft.___ ___________ _ Filter Analvsis Initial filter 

## V\reight (mg): 

# c:05'0 I 

# LJ Final filter weight (mg): 

# d55.5

**;>s~.s** 

## - /)5S". 

# :;r Mass collected (mg): 

# . \ 

## Probe/Nozzle ·runse Analvsis

**.~.~ctone·volume** 

## (ml): 

# lt90 Initial Beaker weight (g): 

# l.

**74~5 l-llf<i~**  

## - 

# l- 7lf].s

## Final Beaker weight (g):

**\.1~1{** 

# 1.151/ 

# ----- - kiSt! Mass collected ( mg): 

# 3. d. Blank Correction (mg):

**~** 

## Adjusted mass collected 

## (mg): _,., 

# .,...,.oh-f :: 3 ·

**~ :J~.J**  

### t' 

## Condensable Analvsis

Final Beaker weight (g): 

# Container Volume

**~** 

# Initial Beaker weight



# (g)~

**~~:----**

**~~---**



### ~tfass 

## collected (mg): 

# Blank Correction (mg): Adjusted mass collected 

## (mg):
c:\\MyDocumems\Upioads\M5-2002LabAnalysis E. Rob:ns All::y Associates, Inc.

# Method 

# 5 Laboratory Dl!J,ta Facility Name:

. . 

## Source: Run Number: Liquid Levels Marked

- 

# 6i) I N 

## Project Number: 

# floc3
.. OJ 114 

## Date: 

# t2/ulo 3 Filter Number:

Alnount of 

## Liquid lost during transport:



# ·.......u:.M.LZ~~------------ Filter Anaivsis Initial filter weight (mg):

**~~#~** 

## Final filter weight (mg): 

# d.'S" <-i.

**~** 

### C)lt;t{.1 

# --- - ;Js:!f. 

## 3 Mass collected (mg): 

# o.s Probe/Nozzle Rinse
... 4.nal:ysis Actone·Volume (ml): 

## I

**~o** 

## Initial Beaker weight (g): 

# l. /J_Y,O 

# l· '7d.'ib 

# - /
.. /;;;. t.lo Final Beaker weight (g):·



## l.id.~l1 

# l
.

**'7d..'vl~** 

# -- =



# '-~~~~~ Mass collected (mg): 

# a.{ Blanl< Correction (mg): Adjusted mass collected (mg): 

# --7 oh- 

# r ::

**3~a** '" 

### fi' ! 

## Condensable 

## Analvsis Container Volume

**~** 

## Initial 

# Beaker weight



# (g~ Final Beaker weight (g):



# -~~-- ,_.



# ~---



# ~ssoolle~d~~: **------~---~~-------~**

**~-..**

**~-** 

### =
=


## Blank Correction (mg): 

## Adjusted mass collected 

## (1ng):
c:\\MyDocuments\Uploads\lvf5-2002LabAna1ysis E. Roberts Alley Associates, Inc. ......,

..

# Method 5 Laboratory Di;tta Facility Name: 

## Project Number: 

# W3 .. l1] 

## 114

. . 

## Source: 

## Date: {2/ 

## 1 t 

# lo?:> Run Number: Filter Number: -#



## ~? **~** 

## Liquid Levels Marked
- 

# 6i) I N Amount of Liquid lost during transport: --£,1;.)/.L....Ifl:.___ ___________ _ 

## Filter Analvsis Initial filter weight (mg):

**~s(,** 

## . Lp. 

## Final filter weight 

## (mg): 

# d5/.o {j5l· t) 

# - 

# as1. o Mass collected (mg): 

# 0·<-l Probe/NozzRe Rinse
... 4.naivsis Actone·volume (ml):. 

# I dO Initial Beaker weight (g): 

# l.i'15'5

**/.'1%$'~** 

## - 

# l. fi::5" 

# s Final Beaker weight (g): 

# l. 'f=61S 

# l. ']'157'5 

# -- - 

# 1 E 

## /<ir25' \ 

## Mass collected (mg): 

# d.
.. o Blank Correction (mg):

....:::0 

## Adjusted mass

**coll~cted** 

## (mg): ....:>



# --1o~f:; 

# 9..'-f p1 

### p ... 

## Condensable Analvsis Container Volume Initial Beaker weight (g): 

# - Final Beaker weight (g):



# ~ - Mass collected (mg):



# ----~ Blank Correction (mg): ·



# ~ -..

**~--** 

## i\djusted mass collected 

## (1ng): ·· ... ., ...

. , .................



### -~

......
c: \

\tviy Documents\ Up I oads\1vf5- 2 0 02Lab.Analysis E. Roberts Alley Associates, Inc.

# Method 5 Laboratory

**D~ta** 

## Facility Name: 

## Project Number: 

# floo3
.. 02 

## II 

# 4

. . 

## Source: 

## Date: 

## I 

# 2-/

**t~** { 

# o3 Run Number: 

# Dl Filter Number: -t-:1 

# s-

**~** 

### (q 

## Liquid Levels Marked

- 

# 6J I N 

## .A.mount of Liquid lost 

## during transport: 

# .-L:Il:WLJfl:'-------------- Filter Analvsis Initial 

## filter weight (mg):

**:J~t.(.** 

## 0 

## Final filter weight (mg): 

## @ 

# tt4.<6

**~to f.{,~**  

# - ;).{Qf.{.



### ~ 

## Mass collected (mg): tc?.

**~** 

## Probe/Nozzle Rinse Analvsis Actone·Volum.e (ml):



## ll~ Initial Beaker weight (g): 

# I .lltt/'1

**f.7~t(4t** 

# -- - /. ?(, tf'1 Final Beaker weight (g): 

# I. 174.'7> 

# l. f)L£'1> 

# - (.

**17tl~** 

## Mass collected (mg): 

# q·,q Blank Correction (mg):

"'"=' 

## Adjusted mass collected (mg): ....,.,



# -?o~f **~~·I** , .• 

# r. I· 

## Condensable Analvsis
. Container Volume Initial Beaker weight 

## (g): 

# - Final Beaker weight (g):



# ~ .. 

# -

.......... 

## Mass coil ected ( mg):



# ~"' Blank Correction (mg): **~** ....... ............ 

### -.._



## ---
...........

**~** .. 

## Adjusted mass collected (mg):

**~** 

## .. 

# ,

**~** c:\\JvfyDocum:nts\Uploads\M:S-2002LabAnalysis E. Roberr.s Alley A.ssociates: Inc.-=" 

# Method 5 Laboratory

**D·~ta** 

## Facility Name: Source: Run Number: Liquid Levels Marked
- 

# 6i) I N .t\.mount of Liquid lost during transport: Filter Analvsis 

## Initial :filter weight (mg): ;Lc;-S I



### ~ 

## Final 

## filter weight. (mg):



## ~ll. 

# d Mass collected (mg): 

# I Ls . \ Probe/Nozzle ·runse 

## Analvsis Actone·Volume (ml): 

# l'LO t 

## Initial Beaker weight (g): 

# l
.

**~~.J.:lGt** 

## Final Beaker weight 

## (g): J 

## :/"J(pd,. Mass collected (mg): 

# {\

**.~** 

## Blank Correction (mg): Adjusted mass

**coll~cted** 

## (mg): Condensable Analvsis 

# --=foh-f 

# = Container Volume

**(!n~** 

# _ Initial Beaker weight 

## (g):



# ~

**-~--** 

## Final Beaker weight (g): Mass collected (mg): 

# Blank Correction (mg):

**~~djusted** 

## mass collected (mg):
c:\\l'vfyDocumenrs\Uploads\M5·2002Lab.Analysis 

## Project Number:

**~3** 

# .. fD 

## 11 

# A Date: F.ilter Number:

**~~-a** 

# 1 -..-;;;......::.....----



## Q7/.

**~** 

## - 

# d/l. d



# l
. !Jtlf>J 

# - [_. 7 ';) Vt:J I 

# .I'Zud. 

# - \ ./o4»d 

# ---

**~7.~ ~**  

### p !'



### ....... 

# _ . .........._ 

## -.

E. Roberts Alley Associates, Inc. -.:='

...

# Method 5 Laboratory

**D~ta** 

## Facility Name: Project Number: 

# fJ.oo3
.. Q] 

# uti-

. . 

## Source:



# ~r<$5 

# Pry--<v Date: 

# 12/i-z.. {tJs Run Number:

**0~** 

## Filter Number: Liquid Levels Marked- 

# 6i) I 

## N Amount of 

## Liquid lost 

## during transport:

**._N~It** 

# ______________ _ Filter Analvsis Initial filter weight (mg): 

# ;).c:; '-(. 7 Final filter 

## weight (mg);

**~** 

# vo,. ';;l 

# dus. a 

# - - 

# :JC!2·

**~** 

## Mass collected (mg): 

# tt.f.s Probe/Nozzle Rinse Analvsis Actone·Volume (ml): 

# l:lO Initial Beaker weight (g): 

# I.!Cflt3 

# l.!tfv 1 = 

# L. ?f..{v 

## 1 Final Beaker weight (g):



## \.~51'7

**l·/~1'7** 

# -

**l:/~7/** 

## Mass collected (mg): 

# l {
. t-{ Blank Correction (mg):

--==" 

## Adjusted mass

**coll~cted** 

## (mg): ._,



# -?"o~f 

# =

**~.a, .l~**  (f 

### ... 

## Condensable 

## _4..nalvsis Container Volume 

## Initial Beaker weight (g): 

# - Final Beaker weight (g):



# ~ - .l\1ass collected (mg):



# ~ Blank Correction (mg): ......_____ 

# __

...........

**~._._** 

## Adjusted mass collected 

## (mg): ···, ....

.................



### ~, ...._ c:\\MyDocuments\Uploads\1vf..5-2002LabAnalysis 

### E. Roberts Alley 

### ..A..ssociates, Inc.. - ·····-· -- 2
.. . ;;;; ... !!ll!!!ll{!lfiA
. - . ·-- - . -· .• &. E. ROBERTS

# Aile~& 

# Associates INCORPORATED ··- -- .. -· ---- ----- £._
. ... . . . - .


# APPENDIXD



# QUALITY CONTROL DATA

## CARBON MONOXIDE- EPA REFERENCE METHOD 10 Monarch Tile, Kiln Main

## CARBON MONOXIDE- EPA REFERENCE METHOD 10 Monarch Tile, Kiln Cooler

1 - 1

## CARBON MONOXiDE- EPA REFERENCE METHOD 10 Monarch Tile, Dryer

## OXYGEN- EPA METHOD 3A INSTRUMENTAL ANALYSIS CALIBRATION DATA Plant

# ~~c.\o 

# 1\\e Date 

# tif I I ( 0

# ~ Concentration 

### Range 0:-- 

## 2. 

## ot1 tJ

### Location~~Kd~'~\n~~~~~~\~n 

## __________ _**Op~~or** 

## ____**~~t~~-----------------** Response Time () 

# fA_'& Q

# Ill~ "(J ..

# ~ Calibration Accuracy (Accuracy ± 

### 2% 

### of span ) %



# ---- Gas Type Cylinder Acrual Analyzer Gas Type Cylinder Actual Analyzer No. Concentration 

### ZERO 

## 0.0 HIGH 

## :;to 

# .o ZERO & 

### SPAN SYSTEM BIAS

GAS 

### TYPE ZERO

GAS 

### TYPE ZERO

.....



## ..**~#.:** 

## ..... , GAS TYPE 

### ZERO INITI.A.L FINAL RESPONSE RESPONSE



### . .. J!WITIAl TIMJW. FINAL TIME ! • .,.-., ......**~** INITIAL FINAL 

### RESPONSE RESPONSE No. Concentration 

## LO·O

(Accuracy± 5% of span)
___ % 

### (Drift ± 

### 3% of span) 

## o/o

GAS TYPE 

### ZERO INITIAL FINAL RESPONSE RESPONSE

JNJTlAL FINAL GAS TYPE RESPONSE RESPONSE 

### ZERO**rnl'ITW..~E ~.W.#**  .. "

### .ffin9AL:~&re 

## . .. GAS IN!Tli\L FINAL TYPE RESPONSE RESPONSE 

### ZERO

# I CARBON DI.OXIDE ·-EPA METHOD 3A 

### INSTRUMENTAL ANALYSIS CALIBRATION DATA Plant

## 01ctW~ 

# 7,{£ Date 

# IZ/1 I 

# {o3 Concentration Range () ... \ p !'>o 

### Location 

# /q \ n 

# mo i b 

### Operator 

# "J 

# t-1 Response Time 

# 0

# ~**~So** 

# ; Calibration Accuracy (Accuracy ± 

### 2% of span) %



# --- Gas Type Cylinder Actual Analyzer Gas Type Cylinder Actual Analyzer No. Concentration
ZERO 

# 0·0 HIGH 

### ZERO 

### & 

### SPAN SYSTEM BIAS**-~~.#** GAS TYPE ZERO

GAS TYPE ZERO**~-#** GAS TYPE ZERO ... :.·.· 

## ..**:.~····**

### .F-fN~Tf.¥? FINAL RESPONSE

INITIAL FINAL RESPONSE RESPONSE



### INITIAL TIME



## .**l?&~J7~** 

## ...... -- .... INITIAL FINAL RESPONSE RESPONSE No. Concentration



### (Accuracy ± 

### 5% of span) %



# --- (Drift± 3% of span) %



# ---

-····**IN~!f:l~·~·**



## . RW
.. #.**Fl~'tr~** 

### ... GAS INITIAL FINAL TYPE RESPONSE RESPONSE ZERO**I:N·I:rl~TM£** 

### RT TKT 

### # .... 

### F .... ·:'rroi:,

### ·.·~t:~.6 ••• .!'

### .~r·

....

### T,.::IME.·.~ .• ·.,·;.. . . . .••**:.'~~.~·** •.• : ................ '..**'!-~!'!~** ... .. GAS TYPE ZERO

### -~~-# .. INITIAL FINAL RESPONSE RESPONSE



### INITIAL TIME

### ~ 

## ....**F:lN~~Ji~-** 

## .. GAS INITIAL FINAL TYPE RESPONSE RESPONSE ZERO .,

### I I 

## OXYGEN- EPA METHOD 3A INSTRUMENTAL ANALYSIS CALffiRATION DATA Location 

# r I C"NZ.-1./1-o<:.. 

### e.. 

# A l Date 

# '"L-/tL../

**c~** 

### Operator 

# f'Lft:; Concentration Range 

## 2 5 

## % Response Tim.e
__ 

## t '_. c_G ______ _ 

### Calibration 

## Accuracy (Accuracy ± 

## 2% of span ) %
Gas Type
ZERO Cylinder Actual No. Concentration 

## 0 Ana1yzer 

## 0 HIGH 

# 16. 0 

### ./ (. 0 

### ZERO & SPAN SYSTEM BIAS

**INIT~** 

### tiMli07; .ll<ir

**.&~#.0** •n

**~** ' 1 •,. i· • • ..,...l. 

## _....,.,. ..........

**~~~ ~**  **.a.~** 

## .. ;..5:6,... GAS INmAL FINAL TYPE RESPONSE RESPONSE ZERO 

## o. 

# I (:J. 

# I
I 

# I J. C[ fv.._,d 

### IJ.Cf

·- ·- ··· · ..... - .. -. -- · ···-mmAL·1lliv'IE

**Tr::~'** 

# t

**R~·** #



### ~-:2 

## ..

**~** 

## ............ FINAL 

# tiNffi l_i,o.(
..

-.:= 

## ... ·;::•

GAS INITIAL FINAL TYPE RESPONSE RESPONSE ZERO 

## o. I 

# o. 1 

# M..:ol I 1
. 

# cr I I. 

# o; Gas Type
MID Cylinder Actual Ana1yzer No. Concentration ( 7_. 0



### (Accuracy ± 

### 5% 

## of span)
__ 

### % 

## (Drift ± 

### 3 

### °/o of span) 

### o/o

. . INITIAiil:

**~·(!)f:f'j**



# ... . . ' ,··::M··

**·.~.dt** 

### .... ,D.':t ...........................

**FIN~** 

### ·.'I . 

### .1..{!
.. 1.0 GAS INITIAL FINAL 

### TYPE RESPONSE RESPONSE ZERO 

### 0. 

# I (), 

## I 

# fot,'! I /).9 

## I J. 

# c; RW,N.#
__ ..... - ......



# ·-~. **,~·=··** 

# .. GAS . 

# I INITIAL FINAL TYPE 

## I RESPONSE RESPONSE ZERO 

## I I



# l.~#;: 

# .. . iNITIAL TIMlS:

**~·-··-** ··- -· FINAL TIME

...... 

### mnTJAt. T:IiN!E

**~.lJN** #

.. 

### FINAL

**~N.$·** 

# I GAS INITIAL FINAL TYPE RESPONSE RESPONSE GAS INITlAL FINAL TYPE RESPONSE RESPONSE ZERO 

# I ZERO 

# I I 

# I I

## ' \ 

### CARBON DIOXIDE- EPA METHOD 3A INSTRUMENTAL ANALYSIS CALIBRATION DATA Plant 

### yV\olAO-rc. k_



## ~~ 

## .le_ Location 

# ------------+------------ **F-"lc~~** 

# A/ Date 

## I 'l_ 

# /t 7- / C



## ~ i &. 

### Concentration Range __ 

## 2_o_/-=-"'-- 

# 1 : 6o 

### Response Time __________ _ Calibration Accuracy (Accuracy :t 

### 2o/o of span) ___ o/o

Gas Type
ZERO HIGH Cylinder Actual No. Concentration 

## 0 [( 10 

### ZERO & 

### SPAN SYSTEM BIAS

**Ru.N.~:a:~** !Nf!FIAL TIME ( ; Cj

**~** FIN:AL TiME

**~· ~.5:"6**  GAS INITIAL FINAL TYPE RESPONSE RESPONSE ZERO 

# o, I 

## o. l 1:.._. 

## \'-.uS"

**~lei.** 

## 17-.

**0~** 

### .RUN#



### ~""J INITlAL Tif:\1lE l 

## t: 1"

.. :FINAL TIME fjo€. GAS INITIAL FINAL TYPE RESPONSE RESPONSE ZERO 

### CJ I \ 

## o. l 

## (Ylid fL.. 

### u<) 11... LU INITIAL f-lME

**~UN#.** .f.:JNAL TI;tY.IE GAS ·INITIAL FINAL TYPE RESPONSE RESPONSE ZERO 

# I .A.nalyzer



## f(.o

..

I j Gas Type
MID Cylinder Actual No. Concentration 17...(1 Analyzer 

### J?.,. 

# oLJ

(Accuracy ± 

### 5% of span) %



## --- (Drift± 3o/o of span) o/o



## ---

..

**litn~t#** 

## ..

**.~?..** 

### ........... **ftN~ll?lAL** 

### TEME 

# q t 

## S6

.. :Wl'N·:AL TIME . J /. :.'3 

### o ... GAS INITIAL 

# ! FINAL TYPE RESPONSE I RESPONSE ! ZERO 

### 0· 

### l 

## I 0. ( \ I 

# - I t-A-•r/ l '"L 

### _c.) ll.. 

## 0¥ INITIAL TIME 

### RUN# FINAL TIME

... . 

### .. , .. . . GAS INITIAL FINAL TYPE RESPONSE RESPONSE ZERO



### INITIAL TIME RUN#

**Fl~~.TIM£** GAS INITIAL FINAL TYPE RESPONSE RESPONSE ZERO ! 

# l !STECGasDividerCalibrationMETHOD10Date:12/10/2003AnalyzerType:CAlModel300PCylinderGasConcentration499.4CALIBRATION1GASDIVIDERCALINSTRUMENTDIFFERENCEERRORSETTINGGASREADING(PPM)0/oo/oPPM(PPM)50249.7251.01.30.530149.8149.80.00.01049.949.4-0.5-1.1CALlBRATIONDIRECTTOANALYZERCALINSTRUMENTDIFFERENCEERRORGASREADINGPPMo/oPPMPPM50.249.8-0.4-0.8PROCEDURE:CALlBRATION2INSTRUMENTDIFFERENCEERRORREADING(PPM)%(PPM)251.21.50.6149.7-0.1-0.149.3-0.6-1.3INSTRUMENTDIFFERENCEERRORREADINGPPMo/oPPM49.7-0.4-0.8CALIBRATION3INSTRUMENTDIFFERENCEREADING(PPM)(PPM)251.01.3149.5-0.349.5-0.4INSTRUMENTDIFFERENCEREADINGPPMPPM49.8-0.4ConnectthedilutionandhighlevelcalibrationgasestotheSGD-710gasdivider.Connecttheoutlettothecalibrationgasline.FloWthemixedgasesaccordingtotheratiosprovidedintheabovetables.Repeattheprocedureforthreetrials.Theinstrumentandcalibrationgasvaluesmustagreewithin2%ateachgasdividersettingforeachofthethreetrials.Anadditionalmidlevelcalibrationgasshouldbefeddirectlyintotheanalyzerbypassingthegasdividersystem.Themid-levelcalibrationgasconcentrationistobewithin10%ofoneofthedilutionlevelstestedabove.Thedifferencebetweenthemid-levelcalibrationgasandtheaverageInstrumentresponseshallbewithin2%.ERROR%0.5-0.2-0.9ERROR%-0.8BOC GASES 

# Ill' BOC GASES 600 Union Landing Road Rlverton,NJ 08077

CUSTOMER Madison Gas&Gear 191 COCHRAN ROAD PO BOX 130 MADISON, AL 357580000 CUSTOMER PO NO: Previous Certification Date(s): (856) 829 7878

CYUNDERNO CC95706 EXJ:'IRATION DATE 22-May-2006 CERTIFICATION DATE 28-May-2003 CYUNDER PRESSURE 2000 pslg PRODUCT ID NO 24013607 LOT NUMBER 559540 

## ANALYTiCAL

**iNFORMAT~ON** ris callbration standard has been certified per the 1997 EPA Traceability Protocol, Document EPA-600/97/121, Using Procedure G1. All Values certified be +1·1% NIST Traceable.

Oompon.ent.S



### JA.fU3oN@.!SX1~E

**3~Y:GEN**

**~i)i:R0GcN**

Type NTAM 82745X SRM 2659A LOTIO 00060503 71-C-35 Do

**~ot** Use This Cylinder below 150 psi g. i.e. 1.0 Megapascal



### iqf~o:~~~r.

**~O.dQ.;~o.**

**Bh\·hANOE~.e~s· 1:9.~!%:** 

**.,9.9~"%** 

### CALIBRATiON STANDARDS USED iN ASSAY Cylinder No XC01B9578 CAL014654 Concentration 19.69 +1- 0.16 % C02/N2 20.92 +1- 0.11 % 02/N2 

### ANALYTICAL INSTRUMENTS USED IN ASSAY .I.

Instrument/Make/Model Analytical Principle Last Multipoint Calibration Siemens SE 00721 Siemens SE BN805 NonDispersive Infrared Paramagnetic
02 adjusted for C02 interference based on analytical data.

A ciivision of The BOC Group, Inc. ?age: 1 Of 1 .D:. Deiaware Corporatior; QA Approved 04/30/03 05/15/03 

### ;A!f~~v~~ili~

, I

**~ ~**  I 

## ·osi2a(o$

**05/2~JGS**

Expiration 02/01/04 07/14/04BOC GASES



## ~ 

# BOCGASES 1075 CINCLARE DRIVE PORT ALLEN.LA 70767 (225) 388 0900

CUSTOMER Madison Gas&Gear 19'l COCHRAN ROAD HUNTSVILLE. AL 358240000 CUSTOMER PO NO:

**·~revious** Certification

**Date{s)~**

**~** .

...... 

### r~E~:W.:tt$tiA:t,!ii· 

## ·OF t&NiAL:Y:S:Jts .;;i-· 

## · , · ·

**.~i?.:;** 

## f;-:op,pcq:J.

**G~~** 

# .... · · ... CYLINDER NO EXPIRATION DATE CE.RTIFICATION DATE CYLINDER PRESSURE PRODUCT 10 NO LOT NUMBER XC015438B 05-Aug·2005 06-Aug-2002 2000 psig 02004382 514840 

## ANALYTICAL INFORMATION •· :

**~.** , I

;s calib&a.tion standard has been certified· per the 1997 EPA Traceability Protocol, Document EPA-600/97/121, Using Procedure G1. All Values certified Je +/·1% NIST Traceable.



### ;~§)~r®~ **&1-~~:o*-ia~**

**~Jrr:ag>~a:r~.**

Type SRM 1678C

instrument/Make/Model Siemens/Uitramat 5E

0 age: 1 Of 1 LOTIO Do Not Use This Cylinder below 150 psig. i.e. 1.0 Megapascal 

### Anai yt 

## i c a"J:

**·R.·~ s~l**  t:f?;
· .

**:~eq4ested** Mixture

**·~et.tlfied**

.. · , . ··concen.tr.ati·oJ1

**-··~";"'.'.,•,** • • "' 'I 

## i_S5o.oo

**:p~m** ':.:BALANCE

**G4~:** :Analyticai

**:~ncertaintr**


### CALIBRATION STANDARDS USED IN ASSAY Cylinder No Concentration XF0005248 48.76 +/- 0.31 ppm CARBON MONOXIDE 

### ANALYTICAL INSTRUMENTS USED IN ASSAY Analytical Principle NonDispersive Infrared Last Multipoint Calibration 07/25/02 **~~ssay** _Dates

.........................

**~..** . ..... J.

Expiration 04/11/07

QAApprovad



# ~- **i;~~** ...

**~** "\:

**~** .. <\' \f,!lBOC GASES 

# AW'IBOC GASES 1075 CINCLARE DRIVE PORT ALLEN,LA 70767 (225) 388 0900**~-**

CUSTOMER Madison Gas&Gear 191 COCHRAN ROAD HUNTSVJL:LE, AL 358240000 CUSTOMER 6'0 NO: Previous Certification Date(s): 

## . ·;CER:Tl'FICATE ·OF**~L¥·S·I.S** 

## · ·:**~-** 

## ..**~:PA ~;-otoco-IL.**  

### $as CYLINDER 

### NO CC9658 EXPIRATION DATE OS.Aug.-2005 'CERTIFICATION DATE 06-Aug-2002 CYLINDER PRESSURE 2000 pslg PRODUCT 10 NO 24007729 LOT NUMBER 514196 

## ANALYTICAL INFORMATION is calibration standard has been certified per the 1997 EPA Traceability Protocol, Document EPA-600/97/121, Using Procedure G1. All Values certified be +/-1% NIST Traceable.**;io\RS®t~:~NOXI~.~~ 'J~TRe:G£:N** 

Type SRM 16808

I nstrumenUMake/Model Siemens/Uitramat SE LOTIO 2-H-102 Do Not Use This Cylinder below 150 psig. i.e. 1.0 Megapascal**.~giyticai** 

### :Results**~e·que~ed~ix'iure** ' cer;tlfled

.. ·**Con~centrafioh** 500.00 p_pm ·499.4-ppm I 'lj 

### ·BALANQE' .GAS**AnaJyfi~l** UnceJ#inty +/-1 .00% NI·$T Traceable 

### CALIBRATION STANDARDS USED IN ASSAY Cylinder No Concentration CLM009420 490.40 +/- 2.90 ppm CARBON MONOXIDE**AN~~YTICAL** 

### INSTRUMENTS USED IN ASSAY Analytical Principle NonDispersive Infrared Last Multipoint Calibration 07/25/02

.:"- .:.:1;-'t:ilu:- '.Ji Tl1c BOC :>r:)l.lp fnc Page: 1 Of 1**~** i**Jr."~:!\' ~\.'i'l"** **(·''r"fn·,r:--~~~\"Jr:** QAApproved**~say** Oates·

. -- .. :p]./30/02 & 08tb6102 ./
Expiration

04/07/07

. ;¢ ..:&PA Mli.thocl 5

iQJ. ti: c:-sooo**~ata: ---~----~---------------->**  ·i.ll.l. f: 13?6**BD~gt:ic** Proasura: 

## ----------> '1'hooz:D.ti.Cill c=.i tical**Vacu~::** 

## --->

1!1111

! ' ! !! !

---------------- OR! CAS**~TER ~ADINGS**  ----------------

Volume Volume VolUmCI Fin;a.l T10111p.rz. :l.H Ti:na IzU.tial li'.inal**~otal** C.:i.n H201 tnin) (cu !'tl Ccu !'tl {dag F) (dug Fl ldag F) Idea; F)

o.sl. l5.00 342.111 348.461 6.350 85 .o B.S.O B.S. 0 as.o l.OB 10.00 348.461 354.063 s. 602 B4. 0 B4 .0 8.4.0 84.0 1.8.5 . 10.00 354.063 361.263 '7.200 84.0 84.0 86.0 94.0 3.60 5 .DO :361.263 366.203 86.0 84.0 BS.O 84.0 .s.ss .s.oo 366.20.3 372..253 s.oso BG.Q 84 .o 510.0 84.0 9/3/0'3 !!!i'.PP (in, RgJ 14 .1.5 f:i.n, iig)

Orl.:!icg Sariall Cocff'iciant Vnc:uum Initial !'.il'lal Avar11.90 lnumbe::.ol (Julio above) (.i:n Hg) laag i') (dog FJ (c::img F)

llG4B 0.331 :!3.0 82.0 B2.0 82.0 C0!5 0.438 2l . .S 82.0 82.,0 82..0 DGG'3 0.562 20.0 62.0 82.0 82.0 Dc:;73 0. 790 12.0 82.0 B2.0 82..0 O.!i'.S$1 la.o 82.0 62.0 82.0

--- OR! ::AS HE'ZER

--- --------- ORIFICE

--------- -- DRY GAS HESB -- --------- ORI<ICt

---------

VOLUMi: VOI»Mi:**Vmt.G~d)** :cu ::'tl (litl2=5) e; .173**l'l~.a** s**.~62** 15.4. i 7 .o:n l9ll.O .4.!:33 136.9 .5. 942 lG!l.3 VOLUME:**VOL~** CORR CORR V::llltci) VC!"(.!I':Q} (CU !tJ 6.396 s**.6~i ?.2~0**  .s. 021 6.l7.9 lBl.l 159.6 20.5.0 l42.2 l7S.O VOLUMi:
V:r (C:\l :!tl £ • .SS! S.iiS 7.417 .S.l44 6.331 Ava:-aga Y 

## -------> y**'-'nl~:e** ila:::iation (nwnl:la:-) lnu:nba:::) l. 0.36 0. OO:i 1.032 -0.00.3 1. 030 -o. oo.s 1.039 0.003 1.040 o.oos
1.0:3.5

a:capta!:le -::olo=&nce o: indi v.i.cu11.l Vl1l UDa**~rem** :;hg avg::UqQ ill •-0. 02. dH@ Vnlucr Va.lue**·~r.:.n:.ioh** (in H20) cmm K20) (:..n <1201 1.833 H.SS -0.080 l. esc 47.24 -0.053 l.li32 49.06 0.018 1.95.'3 .cl9,6·l**li.O~O** l.9BB .50.51 0.075

l.Sl3

::'::r O:ri!ica Culibra.tion i'actor cilfll, -:ha ori!'ica cU.::'!GrllntJ.al prcassu::.oGI i.r. ir.:::has of li20 O:.lul.t equntas to 0. 75 cfm o!' aJ.:r 

## if (·'! \ (?

## a:GN.C:l:l·--~--J-+'--=L...4==~:;:;::..:=·..::.=oa.**"""~F~4:4i:c::~=·** 

## :;;... ........

________ _ 

## q_ ?-,r)::? Dllt£ : __ .. __ ... _. __ ....**_~;::** .... :;;;.; _____ _**~Co~** ': 20:0 lo=ial tl: 80707

I II I! I II

**~'rANT** CMPOR':ANT



# . I' II' II' APJ:X INS'rRDMZN'l'S Ei'A Mothcd S 522 Sarioo Motar Box Ca.li.l:lru.tion Pre-Teat

**or~fica** Mothcd English Motor Bcx Unita, Engliah K' FQctor FileNUIIQ: C:\My DcCWIIcnto\(Blua M. Bcx CAl.xlu)5220RPRS

**Ra~sod:** 7/25/95 Varoion: 2.2

Data: 

### -------------------------> Barcmotric Proaaura: 

### ---------->

**Thaoratic~** Criticul Vacuum:---> 8/3/03 30.07 (in. Bgo) 14.lS (in. Rg)

For VZLl.icl toat ruulto, tho Actual Vacuum ohould bo 1 to 2 in. Bg groatar than tho Theoretical Cdtical

**V~acuum** ohown a.bova. Tho C=itiCll.l. Orit'ioo Coot'fic.i.cnt, K', muat bo ontarecl in Enqliah unita, (t't) ""3• (dog R) "0.5/ ( (in.Rq) •tmin) I.

---------------- DRY GAS METER READINGS
---------------- -CRITICAL ORIFICE READINGSdH !l.n H20) 0.70 1.30 2.14 4.12 6.10 Timo Cr:ainl 15.00 lO.OO 10.00 s.oc s.oc Volume Voluma !ni Ulll Fl.nlll (cu ft) leu t't) Vcluma

**'l'o~** (CU ft) 6.506 5.799 7.471 5.164 6.342 lni tial 'l'OJIIPII. Final Tampo • Inlot OUtlGt lnlcat OUtllllt (ciog F) (clog' F'l (dog F) (dog F) 0:-i!ica Sorillll

**·(:~umber!** K' Ori.riao Actual -- Ambicant

**Tampar~~otul:'e** -- Coefficient Vacuum lru.t:l.al Fi.nlll Avaraqo Caec abavo) lin Hgo) ldag rJ (cia; F) (do!J Fl

-·- DRY

**~** MU'ER ---

VOLUME CORRECT:&L Vm(Dtd) (C\J !t) 6.328 5. 634 7.2.511 5. 028 6. 106 VOLVMZ CO!UU:C'l'J:D VmiGtd) (l:.tlii:'S) 179.2 159.5 205.6 142.4 l75.2 895.307 901.813 901. B13 907.612 907. 612 915. OB3 9l.S.083 920.247 5120.247 926.589 86.0 aa.o 09.0 91.0 93.0

--------- ORIFICE
---------
VOLUMe

COR.R Vcr(utd) (:U ft) 6.378 5.616 '1.209 4.998 6.145 VOLUME COR.R Vcr(stc!) Clite:s) 180.6 159.0 204.2 141.5 174.0 VOLUME NOMINAL

Vc: (CU ft} 6.589

**~.013** 1.468 S.lB2 6.383 85.0 86.0 87.0 08.0 851.0 a8.o SJO.D 91.0 93.0 96.0 06.0 87.0 se.o 89.0 89.0

-- DRY GAS MI:TER
-- CALIBRATION FACTOR y ValuD '/ariation (numb&r) (numDDr) l. 008 0.011 0. 997 0.000 o. 9.93 -o. oo4 0.994 -0.003 0.993 -C.004 DG48 DGS!I DG63 DG73 DGB1 0.331 0.430 0.562 0.700 0.959 22.0 20.4 18.3 lS .1 13.0 08.0 89.0 89.0 90.0 91.0

--------- ORIFICE
---------

**CAL:IBRA~ION** FAC'lOR dHt Vlllue {in H20l 2..119 2..251 2.245 2.244 2..1!16 Value 1 R::a.ation (IIIII H20} (in H20) 53.82 -0.0512 57.18 0.040 5'1.02 0,034 56.99 0.033 ss. 77 -o. o1s BB.O 89.0 90.0 90.0 91.0 BB.O BSil.O Blil.S 90.0 91. c

Ave--uga Y 

### -------> 0.997 2.211 56.16 

### <------- Average dHS

;:a: For C&librat:a.on Fa::or Y, tha rlltio

**o~** the reaCing of tho

**calibrn~ion** meter to tho d--y !Jns moto:-, accopcDblo

**~olaranca** o!

**1ndiviau~l** vu1uaa

**~rem** tho avgrago iu •-0.02. For

**Or~!1co** Calibration Faoto:- dHQ, tho

**ori~ice** di!!arlilntial prDoaura in inchos o! 820 that

**oqu~toa** to 0.75 cfm o! lllr

**a~** sa F and 29.512 a tolQr&nca of

**:a.neiv~du11.!** valuas from tho avorago :a.& •-0.2.



# Dn-::e:_1~( _3-+-/ 0_-,_:::>
__ _

### Sample Probe Calibration Inspected By: Inspection Date: 

# S.

**C,,tin~hd¥"1** Probe ID:

Pitot Tube Openings Damaged? Yes 

# I No 

# I \/ Pitot Tube

**AligJUI).~nt** OK? Yes 

# I ../ No! Calibration Required? Yes 

# I No 

## I .I External Tube Diameter (Dt)* Dt= 

### 0.375 *Dt must be between 3/16 abd 3/8 """"' Base-to-plane opening distances (Pa and Pb )* Pa= 0.4375 *Pa 

## = Pb Pb= 0.4375 Pa!Dt = 1.17 (Must be between 1.05 and 1.5) If pi tot does not meet the criteria specified above it must be repaired or calibrated in accordance with Sections 4.1.2 through 4.15 ofMethod 2.

**Base1in~** coefficient' of 0.84 applied to pitots that meet inspection criteria


### Target Reference Indicated Temp. Temp. 

### Temp. 

### Temp_. Difference lce-32F Ambient-70F



### ~L 

### Lf6 Hot Oil-150F 

### Boiling H 2 

### 0-212F Hot Oil-150F 

# L " (

,o "" • Hoo•H o•v "' ........ , ...................... ) Corrunents: Ofo 

### Difference
. Specification % Difference 

### < 

### 1.5

e.. ROBI!RTS



## Aile~& 

# Assoc·nates

### Date: Calibrated By:

Notes: 

### Nozzle Calibration

a: Three different nozzle diameters, each diameter must be within 0.001" b: DiffD =maximum difference between any two diameters 0.004 " c: D avg =average of01, 02, and 03

!:.ROBERTS 

# Alley& 

# Associates 111CORPORATtD

### Sample Probe Calibration Inspected By: Inspection Date: Probe ID:

Pitot Tube 

### Openin-gs Damaged? Pitot Tube

**Aligiun~nt** OK?
. 

### Calibration Required? 

### External Tube Diameter (Dt)* 

### *Dt must 

### be between 3/16 abd 3/8 Base-to-plane opening distances (Pa and Pb )* *Pa 

## = Pb 

### Yes 

# I Yes 

# I Yes 

# I No! 

## K" 1111 

### ,:>< No 

# I No 

# I 

# ?<' Dt= 0.375 

### Pa= 0.4375 

### Pb= 0.4375 Pa/Dt = 1.17 (Must 

### be between 1.05 and 1.5) lfpitot does not meet the criteria specified above it must be repaired or calibrated in accordance with Sections 4.1.2 through 4.15 of Method 2. Baseline coefficient of0.84 applied to pitots that meet inspection criteria
Target Reference Indicated Temp. Temp. Temll_. Temp. Difference Ice-32F Ambient-70F

**'-l~c,** 

### tf 3 Cl 

### 0 Hot Oil-150F Boiling H 2 0-212F

Hot Oil-150F 

## I 

# r· Comments: o/o. Difference Specification 0 % Difference 

### < 1.5

, •,•o"''
... ,,. .. , ... ,. , v•· • • , ...... :1

E. ROBERTS 

# Alley& Associates 111CORPORAT!D

### Date: Calibrated By:**.~**



### Notes: 

## Nozzle Calibration

G I**I~** ( 

## v.**I~~** 

## o. I 'rl

a: Three different nozzle diameters, each diameter must be within 0.001 11 b: DiffD;: ma."<imum difference between any two diameters 0·.004"

,.. D avg 

### = average of D I, 02, and 03

!. ROBI!.RT5 

# Alley& Associates 11'tCORPORI'71!.0

### Inspected By: 

### Sample Probe Calibration 

# 5. Cut'\J'llrfi 

# han Inspection Date: 

# J)·t:J. 

# o3 Probe ID:

Pitot Tube Openings Damaged? :Yes 

# I No! \7 

## .. Pitot Tube

**Ali~~nt** 

### OK? Yes 

# I ./ No 

# I Calibration Required? Yes 

# I No 

# I {/" 

### External Tube Diameter (Dt)* Dt= 0.375 *Dt 

### must be between 3/16 abd 3/8

......

**~ase-to-plane** 

### opening distances (Pa 

### and Pb )* 

### Pa= 0.4375 

### *Pa = 

### Pb .Pb= 0.4375 

### Pa/Dt 

## = 1.17 

### (Must be between 1.05 and 1.5) If pi tot does not meet the criteria specified above it must be repaired or calibrated in accordance with Sections 4.1.2 through 4.15 of Method 2. Baseline coefficient of 0.84 applied to pitots that meet inspection criteria.


### Target Reference Indicated. Temp. 

### o/o Temp. Temp. Temp. Difference Difference Specification 

### lce-32F Ambient-?OF 

## .3;:;J

**~~** 

### %Difference< 1.5 

### Hot Oil-ISOF Boiling H 2 

### 0-212F Hot Oi1-150F

. .

**-->··-·~-·** ....... .. . ...

**·----~** ...... , .. ,. .......... ,xx·-· ...... .__ .......... . .,., ...............

**···-~·** ..... '
........... '
..... , ..... , . ., ........ ·•··.·"
..... · .. '.:1

. ,._. ..... .... ... .. 

### ..... ' . .. ....

**...~. ·~**  ,, ...... ' .......

**,:~** :.·, . 

### Comments:

E.ROBI!l!TS



## AJllle~&. 

# Assoc'iates I N C: 0 R P 0 R 1\ T e .D

## Date: Calibrated By:

Notes: Nozzle Calibration

. ..**-~** •.·

{). 00'3



### .......



# I

a: Three different nozzle diameters, each diameter must be within 0.001" b: DiffD =maximum difference between any two diameters 0.004 ''

,.. 0 avg = average of D I, 02, and 03**~** RODI!RTS 

# Alley& Associates II'IC:ORPORA'!'I!D&
. E . ROBERTS 

# Alley& As · sociates INC OR PORATED && && ... E&S& 2 &&&&


# APPENDIXE



# PROCESS OPERA TINGIPRODUCTION DATA

### Monarch Ceramic Tile Process Data 

### 12/11/03 Source Rate Press 1 Dryer 7.07 tons/hour

### Monarch Ceramic Tile Process Data 12/12/03 Source 

### Kiln 1 

### Rate 

### 5.65 tons/hour 

# \