prepared. The date on attached sheets n~ to match the date· noted below. 

General Reference 287.54 

Date Prepared/Revised 219111 

c. Physical Appearance 

- 1 -

't.". 

EPA Generator 
c. 

d. 

a. 

c. 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

Phone 

waste 

Name 

Address Line 1 

Address Line 1 

Addres~ City State ZIP 

Municipality 

rrtle 

Phone 

Name 

to processing or cfiSposal 0 cu yd 181 gal 

processing or 

-2 -

(check one) 

D ton (check one) 
Fonn Submitted: 0 Form 26R 

0 Other (specify) 

Date Submitted: 

0 I certify the Information required In Section B-2, Chemical Analysis was supplied to the Department for the year _and has not changed. 

Fonn Submitted: 0 Form 26R 

0 Other (specify) 

Date Submitted: 

0 I certify the Information required In Section B-3, Process Description and Schematic, was supplied to the Department for the year_ and has not changed. 

Fonn Submitted: 0 Form 26R 

0 Other (specify) 

Date Submitted: 

Name of Responsible Official 

Bernhardt Kissel 

Signature Date 1 

-3-
Brine fluids are composited within the storage production tank or tank battery at each 

well site where gas production is occurring. Each automatic or manual ejection of 

formation fluids is deposited into the tank(s) and added to the previously ejected and 

stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP 

permitted waste disposal facilities on different schedules determined by individual well 

characteristics. Grab samples of the composited fluids were obtained at the 

represented well pads directly from the storage tank drain ports. All drain ports had 

small "built in• containment and storage "buckets• capable of retaining small amounts of 

lost fluids. 

Samples were obtained with bottle sets prepared at the laboratory which contained 

appropriate preservatives, as necessary, depending on the specific test run requested. 

All chain of custody and handling/holding time requirements were met. In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot 

portions at the laboratory. 

Flowback samples were composited to the extent possible during the flowback process 

primarily during times where safety issues did not override sample collection 

requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers 

and smaller aliquot portions at the laboratory or on the well location upon completion of 

the composite sampling process. Samples were distributed into bottle sets prepared at 

the laboratory which contained appropriate preservatives, as necessary, depending on 

the specific test run requested. All chain of custody and handling/holding time 

requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and 

combined into a composite sample for analyses at the laboratory. On several wells, 

cuttings from the vertical portion of the well bore were segregated from cuttings from 

the target Marcellus Formation and separate testing was completed on both sample 

composites. In some earlier cases during the utilization of open pits, composite 

samples were obtained from inactive drill pits. Safety concerns usually limited the 

randomness of the composite sample and composite grid sample positions were varied 

to the extent possible. 

Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned 

and reused from well to well. 
Form 26R: Section B3a 

WASTE GENERATION PROCESS 

Pit Water "Drill Fluids" 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and formation fluids. These fluids are brought to 

the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are 

mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

· Flowback: "Fracing Fluid" 

Flowback is produced from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the 

formation fractures. 

Production Fluid "Brine" 

During the production of natural gas, formation pressures bring remnant frac fluids, 

during the initial production phase, and formation fluids to the surface along with 

produced gas. 
Well I. D.# (various) Well I.D.#.(various) 

-0-

,,/ ~ -o.- /~, /1' 

I\ 1 

\ / Well I. D.# (various) 

\ I ::b/ 

\ I /II' 

\ I / 

\ I // 

\ I // 

. \ I / 

Weq I. D.# (various) \ 1 // 

\\/ / \ I / 

-a-/ " 

rY --:,_/ '<" 0~\:~ -~ ~ Mobile Tank Truck 

\__,) 1 00 . 0 

~f'"O~vc .. :tt~.l\ Oc\.1-tt\~~:- \OA~S ~~ ( 

Ji S brine (TYP.) 

- COUNTYB 

COUNTY A 

_ s Road Transport 

Landfill Or"' 

trtu.+~GA+ 'P\W\t 

ote: 

Process producing waste: Gas well produced 

fluids (brines) are typically produced· in 

conjuction wi.th natural gas. These fluids 

are brought to the surface utilizing either 

mechanical or physical lift procedures. 

(.) 

~ w 

:r: 

(.) 

C/') 

z 

0 

~ 1-

0:: 

0 

0... 

C/') 

z 

~ 1-

~ ~ ~ 

I i lC -

~ (.'.1 -

ru i I! ~! l~ 

~I . ~ 

~ 
ENVIRONMENTAL SERVICE SAMPLE REQUEST & CHAIN OF CUSTODY PAGE_LoF.:::: 

LABORATORIES, INC. ~ 

HEADQUARTERS: 

cp 

SOUTHERN DIVISION: 

1803 Philadelphia St. 1278 BenUeyvllle Road D Indiana, PA 15701 VanVoorhis, PA 15368 

{724) 463·TEST (724) 258-TEST 

(724) 465-4209 (724) 258~378 REC'D FEB -4 Z009 

FOR INTERNAL LABORATORY USE ONLY 

Sample Type 

Sample ldentlflcaUon ESL# Composite Grab Matrix f# of Containers Container Type Analysis Requested 

~ Date~orr Time~ D~ nm_, PrwMfY81Mt 

t}esirn'l~ O'er ~ ~ 1/J:>f>J orzas ww 1 Plastic Uter pH, SC, Chorida, Sulfala, 

otoor ---· --- nona Osmotle 1'.-unt, Alkallnll¥. Acidity 

1'1{£ ---- ---- I ww 2 Plastic Liter TSS, TDS, Olsaolved Iron, 

---- --- none BOI'CXl, BOD, MBAS SUrfactanta 

---- ---- ww 1 Plastic Liter AI, Aa, Ba, Be, Cd, Cr, Co, Cu, Fe, Pb, Mg 

---- ---- HNO~ Mn, Hg, Nl, Sa, Ag, Sr, Zn, Ll, Na, Ce, Hatcrn ~$ 

---- ---- ww 1 Plastic Uter 

---- ----

HaS04 Nltrate+Nitrlte, TKN, Ammonia, COD 

----- ---- ww 2 Plastic Utar 

--- ---- HNOs 

Groaa Alpha, Gross Bate 

---- ---- ww 1 Amber Glass L 

Oli&Grease 

---- ----

HCf 

---- ---- ww 1 Amber Glass L 

----- ---- H~04 Total Phenolics 

---- ---- ww 2 Amber VOA Vials Elhylena Glycol 

---- ---- nona 

~ 

--- ww 2 Amber VOA Vials Benzene. Toluene lr , 

---- ----- u• lr HCI 

TRIP BLANK ocr ___.....-: ~ 

~ -;::::::::::- Water 2 Amber VOA Vials Benzene, Toluene 

01011 

--- --- HCI 

Tli& UNDERSIGNED PURCHASER HEREBY AGREEs 'TO PAY SERVICE CHARGES ON ACCOUNTS~ a1 DAYS OLD. Project Notea: 

1. THESE SERVICE CKARGESWIU.ACCRUEATlHE RATE OF 11121' PER loiCNTit (1K PER ANJM.I ORTHE~AUOWEO BYLAW.) 

2. THE UNDERSIGNED PURCHASER AGREES TO PAY, IN THE EVENT tllS ACCOUNT III!COMES DELINCIUENT N4D IS TURNED 0\IEI\ TO Nl'f 

ATTORNEY FOR C~Cl]gN. REASONABLE AlTORNEV'S FEES PUISAI.L COURT AND ATT&NDAHT COLLECTIOH COSTS. 

7/l,~ff/d~ /kk-9 l~A"" Company/Nama: XTOENERGY 

IS5mpled By.7'iatu~ /oall!f11me • 

1 /;?..!rJ t::t I I I() Lj(~ 1/;~t;Cf 1110 Address: 395 AIRPORT ROAD 

R~ ,/t~arn:, ~By: (Sigralln) 

/ !tXme//"~ INDIANA, PA 15701 

1!/0 ~. ~ L22_ .. Relinquished By. (Signature) ~la/1ima d By. (Bigratute) ( Da1el Tlme 

Conlact Person: MR. MIKE HAHN 

Rellnqlllshad By. (Sigrwlure) Oalel Tlme Receiwld By. (Siptunl) Date/ Time Phone: (724) 349-0600 

CHAIN OF CUSTODY SEAL BROKEN: Yes - No Fax: (724) 349-8489 

"''( -/,,./~/ ~~) £.5' 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

1/12/2009 7:05 AM 

1/12/2009 11:54 AM 

l/30/2009 

Analyte 

Acidity to pH=8.3 

Alkalinity to pH=4.5 

Biological Oxygen Demand 05 

Chemical Oxygen Demand 

Ammonia as N I Distilled 

Chloride 

Kjeldahl Nitrogen as N 

pH(SM) 

Sulfate (ASTM) 

Total Nitrate+ Nitrite as N 

Aluminum· ICP 

Arseoic-ICP 

Barium ·ICP 

Beryllium- ICP 

Boron 

Cadmium - ICP 

Calcium- ICP 

Chromium- ICP 

Cobalt-ICP 

Copper- ICP · 

Hardness 

Iron- ICP 

Analyst 

MS 

MS 

MAD 

ES 

AID 

MS 

AID 

JH 

KM 

JFW 

GJT 

GJT 

GJT 

GJT 

ES 

GJT 

OJT 

GJT 

GJT 

GJT 

GJT 

GJT 

Comments; Radiologicals done by Benchmark Analytical 

Note; DEP Certification #s 32-00382 

Analysis 

Date 

Ol/13fl009 

01/1412009 

01/17/2009 

0111612009 

01/16/2009 

01/13/2009 

01/15fl009 

01/12/2009 

01/16/2009 

01129/2009 

01127/2009 

01127/2009 

01127/2009 

0112712009 

01/20/2009 

01/2712009 

01/27/2009 

0112712009 

01/27/2009 

01/27/2009 

01/27/2009 

01/2712009 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Sample 

Result 

09 01008 

WasteWater 

Grab 

CLIENT (Client) 

Osterling 8165 

Units Method 

ND mg/1 as CaC03 SM2310B 

171 mg/1 as CaC03 SM2320B 

43.0 mg/1 SM5210B 

627.5 mg/1 SM5220D 

40.19 mWJ ~M4SOONH3B & r 

33165.0 mg/1 SM4500ClC 

52.3 mgll SM4500Norg-C,D 

6.80 su SM4500H-B 

ND mg/1 D516-02 

6.10 mg/1 SM4500N03E 

ND mg/1 200.7/6010 

ND mg/1 200.7/6010 

117.800 mg/1 200.7/6010 

ND mg/1 200.7/6010 

9.75 mg/1 SM4500B-B 

ND mg/1 200.7/6010 

2687.700 mg/1 200.7/6010 

NO mg/1 200.7/6010 

NO mgll 200.7/6010 

ND mgll 200.7/6010 

7926 mg/1 SM23408 

32.600 mgll 200.7/6010 

MDL 

l 

20 

2.0 

500.0 

0.99 

1.0 

52.3 

0.01 

5 

0.50 

1.000 

1.000 

0.500 

0.500 

6.25 

0.500 

50.()00 

0.500 

0.500 

0.500 

1 

1.000 

[ND=Not Detected 

Page 1 of3 
Report of Analysis 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

111212009 7:05AM 111212009 11:54 AM 

1/30/2009 

Analyte 

Iron,Dissolved-ICP 

Lead-ICP 

Lithium - ICP 

Magnesium-ICP 

Manganese - ICP 

Mercury 

Nickel- ICP 

Selenium-ICP Silver-ICP Sodium-ICP 

Strontium - ICP 

Zinc-ICP 

Osmotic Pressure 

Detergents, MBAS 

Ethylene Glycol 

Oil and Grease - HEM 

Phenolics, as Phenol 

Specific Conductance 

Total Dissolved Solids (TDS) 

Total Suspended Solids 

Radiologicals 

Analyst 

GJT GJT 

GJT 

GJT 

GJT 

DMM 

GJT 

GJT 

GJT GJT 

GJT 

GJT 

ES 

11.. 

CLM 

AID 

AC 

MAD 

MAD 

enchma 

RO 

Comments: Radiologicals done by Benchmark Analytical 

Note: DEP Certification #s 32..{)03 82 

SampleiD#: Sample Type: Sample Source: Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

01/27/2009 ND 01/27/2009 ND 

01/27/2009 ND 01/27/2009 295.000 

01/27/2009 1.700 01/22/2009 ND 

01/27/2009 ND 

01/27/2009 ND 

01/27/2009 ND 

01/29/2009 15576.000 01/29/2009 330.000 

Olfl.7fl.009 ND 

01/14/2009 1530 01/14/2009 1.110 

01/2212009 171.003 

01/16/2009 8.1 

.01/19/2009 ND 

Ol/13fl.009 67400 

01/19/2009 58900 01/19/2009 251 

01/16/2009 * 

Ol/16fl.009 14.70 

09 01008 

Waste Water 

Grab 

CLIENT (Client) 

Osterling 8165 

Units Method 

mgll 200.7/6010 

mWJ. 200.7/6010 

mgll 200.7/6010 

mgll 200.7/6010 

mWJ. 200.7/6010 

mgll 245.1 mg/1 200.7/6010 

mgll 200.7/6010 

mgll 200.7/6010 

mgll 200.7/6010 

mgll 200.7/6010 

mgll 200.7/6010 

mOslkg OSP 

mgll SM5540C 

mglkg 300.0M 

mgll 1664A 

mgll 420.1 

uS/em SM2510B 

mgll SM2540C 

mgll SM2540D 

mg/1 RAD-CTDHS 

ug/L 624/8260B 

MDL 

1.000 

0.500 

50.000 

50.000 

0.500 

0.0002 

0.500 

1.000 

0.500 

500.000 

10.000 

0.500 

1000 

0.100 

5.000 

5.0 

0.050 

l 

25 

5 

0.000 

10.00 

IND=Not Detected 

Page 2 of3 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

47) Toluene 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

1/1212009 7:05 AM 

1/12/2009 11:54 AM 

1130/1009 

Analyte 

Report of Analysis 

SampleiD#: Sample Type: Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

RO 0111612009 11.70 

Comments: Radiologicals done by Benclunark Analytical 

DEP Certification #s 32-00382 

09 01008 

WasteWater 

Grab 

CLIENT (Client) Osterling 8165 

Units Method 

ug/L 624/8260B 

MDL 

10.00 

jND=Not Detected 

Page3 of3 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

1) Benzene 

47) Toluene 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

1112/2009 

1112/2009 11:54 AM 

1121/2009 

Analyte 

Note: DEP Certification #Is 32-003 82 

Report of Analysis 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

RO 01/16/2009 NO 

RO 01/16/2009 NO 

09 01011 

Waste Water 

Grab 

CLIENT (Client) 

Trip Blank 

Units Method 

ug!L 624/82608 

ug/L 624/82608 

MDL 

1.00 

1.00 

IND=Not Detected 

Page 1 of 1 
.. . PO#: 

PVvSID# 

1 of1 

Paso 1oft 

\ .• ~-• ..:....~~~~''""''"""'"'-.· -..:....:..........,· . ..:.=~ ,__,_,.._ .. _ ---.:.....----_.__.; __ ,_... __ ,.:_;.._~ .. ... _~_ SAMPLE: 08 01008 t..b JO: DW111SI54-002A Grab SAMPLED BY: David A. Stile Sampl• Tlma 0111212009 7:05 

Dol!! ~ Uocart. MOA 

Grot• Alpha ~78.9 :1: 365.8 1316 

.ua!l! 

pCIIL. EPASOO.O 

MAthrut ~ .anaM!Is ~tatt ~!llh!!i! E~ ~ 01116109 8:45 01120109 BP&-CV Gross Beta ·16.90 :t AM.9 1698 pCIIL EPA900.0 01/16109 8:45 01120109 BPS-CV -··--.-- . .... . .... . ·---· . . - _____ ... 

.. ..... ~~ ··~~ ~--......... --...._ 

. -: 

···.· 

.. 

-~~-

DATE: --~~n~l~~-00_9 ____ _