Bora! Bricks, Inc. .Smyrna, Georgia

Run Number SUMMARY

OF RESULTS Trigon Project No. ¢0•-012 'i• Kiln No., If EPA METHOD

26A Determination of Hydrogen Halides & Halogens with Particulate

Emissions 2 3 Average Sample Identification Date: 0

Ps

AH

V•t•VcVWCBwsP•Mm
%C02 %C0

M•

z•PSTsVsAQ,,QswD. Net Time of Test, minutes Sample Time, 24-hour clock Barometric Pressure, in. Hg Static Pressure, in. Hg Stack Pressure, Absolute, in. Hg Actual Meter Volume Sampled, cu. f•. Avg. Delta H, in. H:0 Avg. Gas Meter Temp., Deg. F Voltmae Sampled at Stand. Cond., cu• ft. Volume of Water Collected,

ml Volume of Water Vapor at Std. Cond.,SCF Moisture Content of Gas Stream Percent Moisture in Stack Mole Fraction of Dry Gas Percent Oxygen, Dry Percent Carbon Dioxide, Dry Percent Carbon Monoxide,

Dry Mole. Wt. Stack Gas, Dry Basis, lb/lb mote Mole. Wt. Stack Gas, Wet Basis, lb/lb mole Pitot Tube Constant Avg. Sqrt. Delta P, in. H20 Avg. Staek Temp., Deg. F Avg. Stack Velocity, fl/sec Area Stack, • Gas Volume Flow, Dry Std. Cond. CFM Actual Gas Volume Flow, CFM Gas Volume Flow, Wet Std. Cond., CFM Sample Nozzle Diameter,

inches Area of Nozzle, • Percent Isokinetic 5012-01

5012-02

5012-03 02/08/05 02/08/05

11/2/04 60 60

60 1215-1316 1424-1528

1611-1717 29.23 29.23

29.23

29.23 0.018 0.018

0.018

0.018 29.248 29.248

29.248

29.248 51.238 50.853

51.42i

51.171 2.04 2.03

2.08

2.05 72.0 66.9

64.8

67.9 49.935 50.038

50.806

50.260 101.7 114.2

115.3

110.4 4.79 5.38

5.43

5.20 0.088 0.097

0.097

0.094 ,8.8 9.7

9.7

9.4 0.912 0.903

0.903

0.906 14.96 14.81

,14.85

14.87 3.37 3.44

3.40

3.41 0.00 0.00

0.00

0.00 29.138 29.143

29.138

29.140 28.163 28.062

28.062

28.096 0.84 0.84

0.84

0.84 0.704 0.676

0.699

0.693 509.2 513.8

"509.3

510.8 54.8 52.9

54.6

54.1 10.50 10.50

10.50

10.50 16784 ,15934

16535

16418 34540 "33294

"34371

34069 18394 17647

18302

18114 0.311 0.314

0.311

0.312 0.00053 0.00054

0.00053

0.00053 98.7 I02.2

102.0

101.0
Trigon Engineering Consultants, Inc.Boral Bricks, Inc. Smyrna, Georgia Trigon Project No.

E Hydrogen MwHC1 m.gHC1 C•C•c•ChwE P•,•e

Production

Rate, tons/hr Run Number Front Half Analysis Non-Condensible

Particulate

Matter Non-Condensible Catch, mg 29.2

26.5

25.1

26.9 Non-Condensible Concentration,

gr/dsef

0.0090

0.0082

0.0076

0.0083 Non-Condensible Concentration,

gr/acf

0.0088

0.0080

0.0075

0.0081 Non-Condensible Emission Rate, lbs/hr

,1.30

,1.

1.08

I. 16 Non-Condensible Emission Rate, lbs/ton

0.I05

0.091

0.088

0.095 Chloride Concentration

and Emission Rate Molecular Weight of Hydrogen Chloride, g/mole

36.46

36.46

36.46

36.46 Hydrogen Chloride Catch, ug 5,408

10,341

8,640

8,130 Hydrogen Chloride Concentration,

ppmv

2.52

4.81

3.96

3.77 Hydrogen Chloride Concentration,

mg/dscm

3.82

7.30

6.01

5.71 Hydrogen Chloride Concentration,

gr/dsef

0.0017

0.0032

0.0026

0.0025 Hydrogen Chloride Emission Rate, lbs/hr

0.24

,0.43

,0.37

0.35 Hydrogen Chloride Emission Rate, lbs/ton

0.020

0.035

0.030

0.028 Hydrogen Fluoride Concentration

and Emission Rate MwHF

c•

CAwE SUMMARY

OF RESULTS EPA METHOD

26A Determination of Hydrogen Halides & Halogens with Particulate

Emissions 12.29 12.29

12.29

12.29 2 3 Average

Molecular Weight of Hydrogen Flouride, g/mole

20.01

20.01

20.01

20.01 Hydrogen Flouride Catch, ug

239,277

242,130

252,924

244,777 Hydrogen Fluoride Concentration,

ppmv

203.47

205.47

211.39

206.77 Hydrogen Fluoride Concentration,

mg/dscm

169.23

170.89

175.81

171.98 Hydrogen Fluoride Concentration,

gr/dscf

0.0738

0.0745

0.0767

0.0750 Hydrogen Fluoride Emission Rate, lbs/hr

10.61

t0.18

10.86

10.55 Hydrogen Fluoride Emission Rate, lbs/ton.

0.864

0.828

0.884

0.859

046-05-012 Kiln No.

Trigon Engineering Consultants, Inc.Boral Bricks, Inc. Smyrna, Georgia Trigon Project No. 046-05-012 Kiln No. SUMMARY OF RESULTS EPA METHOD

26A Determination of Hydrogen Halides & Halogens with Particulate

Emissions Run Number 2 Oxides of Nitrogen Concentrations

and Emission Rates Cmeas NOx Concentration,

ppm dry 30.50

29.78 Ca NOx Concentration,

lbs/dscf 3.64E-06

3.56E-06 CAw NOx Emission Rate, lbs/hr 3.67

3.40 E NOx Emission Rate, Ibs/ton 0.298

0.277 Total Gaseous Organics Concentrations

and Emission Rates MWC Cmeas CcCc rood Cmethane CdCd methane Cd total

CON CAN CAW E

CON CAN CAW E

CON CAN CAW E 3 Average

29.75 30.01 3.55E-06 3.58E-06 3.52 3.53 0.287 0.287
Mole Weight &Carbon, g/mole 12.01

12.01

12.0I Ot'ganic Concentration,

ppm as propane (wet)

4.11

4.20

4.48 Organic Concentration,

ppm as carbon (wet)

12.33

12.60

13.43 Non-methane Cone., ppm as carbon (wet)

5.66

4.69

6.91 Methane Concentration,

ppm as Carbon (wet)

6.67

7.91

6.52 Nonmethane Concentration,

ppm as carbon (dry)

6.20

5. I9 7.65 Methane Concentration,

ppm as carbon (dry)

7.31

8.76

7.22 Total VOC Concentration,

ppm as carbon (dry)

13.51

13.95

14.87 Nonmethane Nonmethane Concentration,

mg/dsem as C

3. 0 2.59

3.82 Nonmethane Concentration,

gr/dscf as carbon

0.0014

0.0011

0.0017 Nonmethane Emission Rate, lbsPar

0.19

0.15

0.24 Nonmethane Emission Rate, lbs/ton

0.016

0.013

0.019 Methane Methane Concentration,

mg/dsem as C

3.65

4.37

3.60 Methane Concentration,

gr/dsef as carbon

0.0016

0.0019

0.0016 Methane Emission Rate, lbs/hr 0.230

0.261

0.223 Methane Emission Rate, lbs/ton 0.019

0.021

0.018 Total VOC Concentration Total VOC Coneen•ation,

mg/dscm as C

6.75

6.97

7.42 Total VOC Concentration,

gr/dscfas carbon

0.0029

0.0030

0.0032 Total VOC Emission Rate, lbs/hr

0.424

0.416

0.460 Total VOC Emission Rate, Ibs/ton

0.035

0.034

0.037

12.01 4.26 12.79 5.75 7.036.357.76 14.11

3.17 0.0014 0.20 0.016

3.88 0,0017 0.238 0.019

7.05 0.003 0.433 0.035

Tfigon Engineering Consultants,Boral Bricks, Inc. Smyrna, Georgia Trigon Project No.
SUMMARY OF RESULTS EPA METHOD

26A Determination of Hydrogen Halides & Halogens with Particulate

Emissions Example Calculations

Run 1 Stack Pressure, Absolute, in. Hg PS Pbar + P• Volume Sampled at Stand. Cond., cu. ft. 17.647 * V• * (Pu, + AH / 13,6) VST D

Tu + 460 Volume of Water Vapor at Std. Cond.,SCF Vwc 0.04709 * Vc Moisture Content of Gas Stream Vwc VsrD + Vwc Percent Moisture in Stack 100 * Vwc PMV Vs•ro + Vwc Mole Fraction of Dry G•s 100 P•rv 100 Mole. Wt. Stack Gas, Dry Basis, Ib/lb mole Ma 0.44 * %CO2 + 0,32 * %O• + 0,28 * (100 %CO /•4ole. Wt. Stack Gas, Wet Basis, lb/lb mole Ms Ma * (1 B•) + 18.0 * B•,= Avg. Stack Velocity, ft/see

(T + 460) Vs 85.49 * Ca * APS * SQRT

(Ps * Gas Volume Flow, Dry Std. Cond, CFM 1058.82 * Vs * A Ps * (1 B•) Ts + 460 Actual Gas Volume Flow, CFM Q^=Vs* A* 60-- Gas Volume Flow, Wet Std. Cond., CFM Qsw Qso* [1/(1-Bws)] Area of Nozzle, ft A, ((D, / 2) ^• * 3.14159)/144 Percent Isokinetie 0.0945

* (Ts + 460) * Vsr• o*v•*P•* (1 -B•)* A• 29.248

49.935

4,79

0.088

8.8

0.912

29.138
28.163

54.8

16784

34540
18394
0.00053

98.7 046-05-012 Kiln No.

Trigon Engineering Consultants, Inc.Boral Bricks, Inc. Trigon Project No. 046-05-012 Smyrna, Georgia Kiln No. SUMMARY OF RESULTS EPA METHOD

26A Determination of Hydrogen Halides & Halogens with Particulate

Emissions Front Half Analysis Non-Condensible

Particulate

Matter Non-Condensible Concentration,

gr/dscf (At Standard Conditions) Cs 0.0154 * • / Vs-m Non-Condensible Concentration,

gr/acf (At Standard Conditions) Ca 0.0154 * m• / V• Non-Condensible Emission Rate, lbs/hr (At Standard Conditions) CA•v 0.00857 * C, * Qst• Hydrogen Chloride Concentration

and Emission Rate Hydrogen Chloride Concentration,

ppmv Cs Cm / MwHCI * 24.05408 Hydrogen Chloride Concentration,

mg/dscm Cm m•sHCI*0.001/Vsra

* 0.0283160502 Hydrogen Chloride Concentration,

gr/dsof Cs 0.0154 * m•Hcl "0.001/Vs.m Hydrogen Chloride Emission Rate, lbs/hr (At Standard Conditions) C,•v 0.00857 * Cs * Qs• NOX Concentration,

ppm dry C• Cm / MwCl2 * 24.05408 NOX Concentration,

lbs/dsof Cra mnClz *0.00I/Vsm

* 0.0283160502 NOX Emission Rate, lbs/hr Cs 0.0154 * lr•Clz *0.001/VsrD NOX Emission Rate, lbs/hr E CAW/Prate= Standard Conditions

68 Deg. F, 29.92 in. Hg 0.0090

0+0088

1.30

2.52
3.82
0.0017

30.50
3.64E-06

3.67
0.298

Trigon Engineering Consultants, Inc.Run Number SUMMARY

OF RA•SULTS Determination of Carbon Dioxide Emissions EPA Method 3A Boral Bricks, Inc. Smyrna, Georgia Kiln No. 1

1

2

3

Avg

Date: 0PbarPgPs'M

VSTDv¢VwcBws

%0•%CO2 MdMsepAPS

VsA Net Time of Test, minutes Barometric Pressure,

in. Hg Static Pressure,

in. Hg Stack Pressure,

Absolute,

in. Hg Actual Meter Volume Sampled,

cu. ft. Avg. Delta H, in. H20 Avg. Gas Meter Temp., Deg. F Volume Sampled

at Stand. Cond., cu. ft. Volume of Water Collected,

ml Volume of Water Vapor at Std. Con&, SCF Moisture Content of Gas Stream Percent Moisture

in Gas Stream Mole. Fraction

of Dry Gas Percent Oxygen,

Dry Percent Carbon Dioxide,

Dry Mole. Wt. Stack Gas, Dry Basis, lb/lb mole Mole. Wt. Stack Gas, Wet Basis, lb/lb mole Pitot Tube Constant Avg. Sqrt. Delta P, in. H20 Avg. Stack Temp., Deg. F Avg. Stack Velocity,

ft/sec Area Stack, ft 2 02/08/05

02/08/05

02/08/05

---. 60 60

60 29.23 29.23

29.23

29.23 0.018 0.018

0.018

0.018 29.248 29.248

29.248

29.248 51.238 50.853

51.421

51.171 2.04 2.03

2.08

2.05 72.0 66.9

64.8

67.9 49.935 50.038

50.806

50.260 101.7 114.2

115.3

110.4 4.79 5.38

5.43

5.20 0.088 0.097

0.097

0.094 8.8 9.7

9.7

9.4 0.912 0.903

0.903

0.906 15.0 14.8

14.8

14.9 3.4 3.4

3.4

3.4 29.I38 29.143

29.138

29.140 28.163 28.062

28.062

28.096 0.84 0.84

0,84

0.84 0,704 0.676

0.699

0.693 509.2 513.8

509.3

510,8 54.83 52.85

54,56

54.08 10.499 10.499

10.499

10.499SUMMARY OF RESULTS Determination of Carbon Dioxide Emissions EPA Method 3A Boral Bricks, Inc. Smyrna, Georgia Kiln No. 1 Q•D Gas Volume Flow, Dry Std. Cond. CFM Actual Gas Volume Flow, CFM F Factor, dsef/million

Btu Percent Excess Air Heat Input Rate, million Btu/hr Production Rate, tons/hr Carbon Dioxide Concentrations

and Emission

Rates Cmeas Cmeas MwcCon

CAw CO2 Concentration,

% dry t CO2 Concentration,

ppm dry • Mole Weight of CO2, g/mole CO2 Coneenta-ation,

mg/dscm CO2 Concentration,

gr/dscf CO2 Emission

Rate, lbs/hr CO2 Emission

Rate, lbs/million

Btu CO2 Emission

Rate, lbs/ton 16784

15934

16535

16418 34540 33294

34371

34069 8710 8710

8710

87i0 179.3 172.6

174.5

I75.4 32.9 32.0

33.0

32.6 12.66 12.66

12.66

12.66

3.37 3.44

3.40

3.41 33740 34430

33980

34050 44.01 44.01

44.01

44.01 61726 62989

62166

62294 26.98 27.53

27.17

27.23 3881.5 3760.4

3851.1

3831.7 118,0 117.6

116.8

117.5 306.6 297.0

304.2

302.7Example Calculations

Run 1 Stack Pressure,

Absolute,

in. Hg Ps--- Phil+ Pg SUMMARY

OF RESULTS Determination of Carbon Dioxide Emissions EPA Method 3A Boral Bricks, Inc. Smyrna, Georgia Kiln No. 1

Volume Sampled

at Stand. Cond., cu. ft. 17.647 * VM * (P•r + AH/13.6) TM + 460 Volume of Water Vapor at Std. Cond., SCF Vwc 0.04709 * Vc Moisture Content of Gas Stream Vwc Vsm + Vwc Percent Moisture

in Gas Stream 100 * Vwc VSTD + Vwc Mole. Fraction

of Dry Gas 100 P•v I00 Mole. Wt. Stack Gas, Dry Basis, lb/lb mole Ma 0.44 * %CO2 + 0.32 * %02+ 0.28 * (100 %CO2 %02) Mole. Wt. Stack Gas, Wet Basis, lb/lb mole Ms Ma * (1 Bws) + 18.0 * B,• 29.248

49.9

4.79

0.088

8.8

0.912

29.138
28.163SUMMARY OF RESULTS Determination of Carbon Dioxide Emissions EPA Method 3A Boral Bricks, Inc. Smyrna, Georgia Kitn No. 1 Avg. Stack Velocity,

fl/sec

(Ts + 460) Vs 85.49 * Cp * APS * SQRT
Gas Volume Flow, Dry Std. Cond. CFM 1058.82 * Vs * A * Ps * (1 QSD---•

.................................................. Ts

+ 460 Actual Gas Volume Flow, CFM QA Vs* A* 60 Percent Excess Air (%02 (0.5 * %CO)) PEA .................................................. * 100 0.264 * %N 2 -(%02 (0.5 * %CO)) Heat Input Rate, million Btu/hr 60 * QsD

(20.9 %02) TC ......................... * Fd

(20.9) C(J2 Concentration,

mg/dsem (At Standard

Conditions) CoN ppm dry * Molecular

weight / 24.055 CO2 Concentration,

gr/dscf (At Standard

Conditions) C• Cmeas * 0.0004371 CO2 Emission

Rate, lbs/hr (At Standard

Conditions) CAw Qso * 60 * C,• Standard Conditions

68 Deg. F, 29.92 in. Hg
• Bias Corrected

Results 54.8

16784

34540

179.3

32.9

61726

2.70E+01

3881.5Boral Bricks, Inc. Smyrna, Georgia Trigon Project No. 046-05-012 Kiln No. 2

Run Number SUMMARY

OF RESULTS EPA METHOD

26A Determination of Hydrogen Halides & Halogens with Particulate

Emissions 2 3 Average Sample IdentL•cation Dam: 0 Net Time of Test, minutes Sample Time, 24-hour clock Barometric Pressare, in. Hg Static Pressure, in. Hg Stack Pressure, Absolute, in. Hg Actual Meter Volume Sampled, eu. ft. Avg. Delta H, in. Hz0 Avg. Gas Meter Temp., Deg. F Volume Sampled at Stand. Cond., cu. ft. Volume of Water Collected,

ml Volume of Water Vapor at Std. Cond.,SCF Moisture Content of Gas Stream Percent Moisture in Stack Mole Fraction of Dry Gas Percent Oxygen, Dry Percent Carbon Dioxide, Dry Percent Carbon Monoxide,

Dry Mole, Wt. Stack Gas, Dry Basis, lb/lb mole Mole. Wt. Stack Gas, Wet Basis, lb/lb mole Pitot Tube Constant Avg. Sqrt. Delta P, in. H20 Avg. Stack Temp., Deg. F Avg. Stack Velocity, it/see Area Stack, ft Gas Volume Flow, Dry Stck Con& CFM Actual Gas Volume Flow, CFM Gas Volume Flow, Wet Std. Cond., CFM Sample Nozzle Diameter,

inches Area &Nozzle,

• Percent Isokinetie 5012-04

5012-05

5012-06 02t09/05 02/09/05

02/09/05 60 60

60 0900-1003 1050-1154

1225-1330 29.06 29.06

29.06

29.06 0.020 0.020

0.020

0.020 29.080 29.080

29.080

29.080 48.713 48.793

50.126

49.211 1.84 1.92

1.94

1.90 73.6 68.7

76.3

72.9 47.034 47.558

48.167

47.586 114.8 116.2

116.3

115.8 5.41 5.47

5.48

5.45 0,103 0.103

0.102

0.103 10.3 10.3

10.2

10.3 0.897 0.897

0.898

0.897 14.48 14.39

14.46

14.44 3.62 3.64

3.59

3.62 0.00 0.00

0.00

0.00 29,157 29.158

29.152

29.156 28.007 28.007

28.014

28.009 0.84 0.84

0.84

0.84 0.647 0.667

0.657

0.657 505.9 503.2

502.6

503.9 50.6 52.1

51.3

51.3 I0,50 10.50

10.50

10.50 15183 15671

15469

15441 31864 32798

32315

32326 16929 17474

17227

17210 0.3t4 0.311

0.314

0.313 0.00054 0.00053

0.00054

0.00053 100.9 100.7

•01.4

101.0
Tfigon Engineering Consultants, Inc.Boral Bricks, Inc. Smyrna, Georgia Trigon Project No, 046-05-012 Kiln No. 2 SUMMARY OF I•J•SULTS EPA METHOD

26A Determination of Hydrogen Halides & Halogens with Particulate

Emissions Pr•e Production

Rate, tons/hr 12.29

12.29 Run Number 2 Front Half Analysis Non-Condensible

Particulate

Matter m, Non-Condensible

Catch, mg 26.4

31.2 C.• Non-Condensible

Concentration,

gr/d•cf

0.0086

0.0101 C• Non-Condensible

Concentration,

gr/acf

0.0083

0.0098 C•w Non-Condensible

Emission Rate, lbs/hr

I. 12 1.36 E Non-Condens•le

Emission Rate, lbs/ton

0.092

0. 10 Hydrogen Chloride Concentration

and Emission Rate Molectdar Weight of Hydrogen Chloride, #mole Hydrogen Chloride Catch, ug Hydrogen Chloride Concentration,

ppmv Hydrogen Chloride Concentration,

mg/dscm Hydrogen Chloride Concentration,

gr/dsef Hydrogen Chloride Emission Rate, lbsPar Hydrogen Chloride Emiss!ol,• Rate, lbsAon Fluoride Concentration

and Emission Rate Molecular Weight of Hydrogen Flouride, g/mole Hydrogen Flouride Catch, ug Hydrogen Fluoride Concentration,

ppmv Hydrogen Fluoride Concentration,

mg/dscm Hydrogen Fluoride Concentration,

gr/dscf Hydrogen Fluoride Emission Rate, lbs/hr Hydrogen Fluoride Emission Rate, lbs/ton MwHC1 m•HCl c•C•c•

Hydrogen MwHF
C•C•c•

E t2.29

12.29 3 Average

27.1 28.2 0.0087 0.0091 0.0083 0.0088 1.15 1.21 0.093 0.098
36.46 36,46

36.46

36.46 8,316 5,927

7,857

7,367 4.12 2.90

3.80

3.61 6.24 4.40

5.76

5.47 0.0027 0.0019

0.0025

0.0024 0.35 ,0.26

0.33

0,32 0.029 0.02

0.027

0.026

20.01 20.01

20.01

20.0i 247,326 240,187

245,317

244,277 223.28 214.45

216.26

218.00 185.71 178.36

179.86

181.31 0.0810 0.0778

0.0784

0.0791 10.54 10.45

10.40

t0.46 0.857 0.850

0.846

0.851..

Trigon Engineering Consultants, Inc.BoraI Bricks, Inc. Smyrna, Georgia Trigon Project No. 046-05-012 Kiln No. 2 SUMMARY OF RESULTS EPA METHOD

26A Detetanination of Hydrogen Halides & Halogens with Particulate

Emissions Run Number 2 Oxides of Nitrogen Concentrations

and Emission Rates NOx Concentration,

ppm dry 32.25

32.63 NOx Concentration,

Ibs/dscf 3.85E-06

3.90E-06 NOx Emission Rate, lbs/hr 3.5t

3.66 NOx Emission Rate, lbs/ton 0.285

0.298 Total Gaseous Organics Concentrations

and Emission Rates MWC Cmeas CeCc rood Cmethane CdCd methane Cd total

CON CAN CAW

CON CAN CAW E

CON CAN CAW E Mole Weight of Carbon, g/mole 12.01

12.01 Organic Concentration,

ppm as propane (wet)

5.02

4.60 Organic Concentration,

ppm as carbon (we0

15.06

13.79 Non-methane Cone., ppm as carbon (wet)

7.24

6.18 Methane Concentration,

ppm as Carbon (wet)

7.82

7.61 Nonmethane Concentration,

ppm as carbon (dry)

8.07

6.89 Methane Concentration,

ppm as carbon (dry)

8.72

8.49 Total VOC Concentration,

ppm as carbon (dry)

16.79

15.37 Nonmethane Nonmethane Concentration,

mg/dscm as C

4.03

3.44 Nonmethane Concentration,

gr/dscf as carbon

0.0018

0.0015 Nonmethane Emission Rate, lbs/hr

0.23

0.20 Noranethane Emission Rate, lbs/ton

0.019

0.016 Methane Methane Concentration,

mg/dscm as C

4.35

4.24 Methane Concentration,

gr/dscf as carbon

0.0019

0.0019 Methane Emission Rate, lbs/hr 0.248

0.249 Methane Emission Rate, lbs/ton 0.020

0.020 Total VOC Concentration Total VOC Concentration,

mg/dsem as C

8.38

7.67 Total VOC Concentration,

gr/dsef as carbon

0.0037

0.0034 Total VOC Emission Rate, lbs/hr

0.477

0.45 Total VOC Emission Rate, lbs/ton

0.039

0.037

3 Average

32.00 32.29 3,82E-06 3.86E-06 3.55 3.57 0.289 0.291
12,01 12,01 5,.02 4,88 15,07 14,64 7,27 6,89 7,80 7,74 8.09 7.68 8.69 8.63 16.78 16.31

4.04 3,84 0.0018 0.0017 0.23 0.22 0.019 0.018

4.34 4.31 0.0019 0.0019 0.251 0.249 0.020 0.020
8,38 8,15 0,0037 0,004 0,486 0,471 0.040 0,038

Trigon Engineering Consultants, Inc.Boral Bricks, Inc. Smyrna, Georgia Trigon Project No. 046-05-012 Kiln No. 2 SUMMARY OF RESULTS EPA METHOD

26A DetermLnati0n of Hydrogen Halides & Halogens with Particulate

Emissions Example Calculations

Run I Stack Pressure, Absolute, in. Hg Ps Pbar + Pg Volume Sampled at Stand. Cond., cu. ft. t7.647 * VM * (Pb•, + AH / 13.6) Vs• .......................................... TM

+ 460 Volume of Water Vapor at Std. Cond.,SCF Vwc 0.04709 * Vc Moisture Content of Gas Stream Wwc Bw8 Vsro + Vwc Percent Moisture in Stack 100 Vwc VSTD + Vwc Mole Fraction of Dr3, Gas 100 P•rv Mro 100 Mole. Wt. Stack Gas, Dry Basis, lb/!b mole Ma 0.44 * %CO2 + 0.32 %02+ 0.28 * (100 %CO2 %O.•) Mole. Wt. Stack Gas, Wet Basis, lb/lb mole Ms '= Ma * (1 B•) + 18.0 * B•, Avg. Stack Velocity, ft/sec

(Ts + 460) Vs 85.49 * Cp * APS SQRT

(Ps * M3 Gas Volume Flow, Dry Std. Con& CFM i058.82 * Vs * A * Ps * (l B,vs) %+460 Actual Gas Volume Flow, CFM Q^=Vs*A* 60-- Gas Volume Flow, Wet Std. Cond., CFM Qsw Qso* [1/(1-B•)] Area of Nozzle, • A• ((D, / 2) °- * 3.14159)/144 Percent Isokinetie 0.0945

* (Ts + 460) * VsrD 0* Vs*es*(1

B,•) * A. 29.080

47.034

5.41

•103

10.3

0.897

29.157
28.007

50.6

15183

31864
16929
0.00054

100.9

Trigon Engineering Consultants, Inc.Boral Bricks, Inc. Tfigon Project No. 046-05-012 •myma, Georgia Kiln No. 2 SUMMARY OF RESULTS EPA METHOD

26A Determination of Hydrogen Halides & Halogens with Particulate

Emissioals Front Half bmalysis Non-Condensible

Partieulate

Matter Non-Condens•le Concentration,

gr/dsef (At Standard Conditions) Cs-- 0.0t54 * n%/VsTt,= Non-Coadensible Concentration,

gr/acf (At Standard Conditions) C•, 0.0154 n% / Vu Non-Condensible Emission Rate, lbs/hr (At Standard Conditions) CAw 0.00857 * C• * QsD Hydrogen Chlo..ride Concentration

and Emission Rate Hydrogen Chloride Concentration,

ppmv Ca Cm / MwHCI * 24.05408 Hydrogen Chloride Concentration,

mg/dscm C,1 m,gHCI*0.001

/ Vsro * 0.0283160502 Hydrogen Chloride Concentration,

gr/dscf Cs 0.0154 * n%•Hc1 *0.001/Vs.m Hydrogen Chloride Emission Rate, lbs/hr (At Standard Conditions) CAw 0.00857 C+ * QsD NOX Concentration,

ppm dry C C• / MwCt2 * 24.05408 NOX Concentration,

lbs/dscf C•a m•C12 *0.001/V•r

• * 0.0283160502-- NOX Emission Rate, lbs/hr Cs 0.0154 * rn•Cl• *0.001/VSTO NOX Emission Rate, ibs/hr F, CAW/Prate Standard Conditions

68 Deg. F, 29.92 in. Hg 0.0086

0.0083

1.12

4.12
6.24
0.0027

0.35
32.25
3.85E-06
3.51
0.285

Trigon Engineering Consultants, Me.Run Number SUMMARY

OF RESULTS Determination of Carbon Dioxide Emissions EPA Method 3A Boral Bricks, Inc. Smyrna, Georgia Kiln No. 2

1

2

3

Avg

Date: 0P•

Ps

%VSTDVcVwcBws
MFt,%02%CO2 MdMsCpAPSTsVsA Net Time of Test, minutes Barometric Pressure,

in. Hg Static Pressure,

in. Hg Stack Pressure,

Absolute,

in. Hg Actual Meter Volume Sampled,

cu. ft. Avg. Delta H, in. H20 Avg. Gas Meter Temp., Deg. F Volume Sampled

at Stand. Cond., cu. ft. Volume of Water Collected,

ml Volume of Water Vapor at Std. Cond., SCF Moisture Content of Gas Stream Percent Moisture

in Gas Stream Mole. Fraction

of Dry Gas Percent Oxygen,

Dry Percent Carbon Dioxide,

Dry Mole. Wt. Stack Gas, Dry Basis, lb/lb mole Mole. Wt. Stack Gas, Wet Basis, lb/lb mole Pitot Tube Constant Avg. Sqrt. Delta P, in. H20 Avg. Stack Temp., Deg. F Avg. Stack Velocity,

ft/sec Area Stack, ft2 02/09/05 6029.06 0.020 29.080 48.713 1.8473.6 47.034 114.8 5.41 0.103 10.3 0.897 14.53.6 29.157 28.007 0.84 0.647 505.9 50.58 10.499

02/09/05 6029.06 0.020 29.080 48.793 1.9268°7 47.558 116.2 5.47 0.103 10.3 0.897 14.43.6 29.158 28.007 0.84 0.667 503.2 52.07 10.499

02/09/05 6029.06 0.020 29.080 50.126 1.94 76.3 48.167 116.3 5.48 0.102 10.2 0.898 14.53.6 29.152 28.014 0.84 0.657 502.6 51.30 10.499

29.06 0.020 29.080 49.211 1.90 72.9 47.586 115.8 5.45 0.I03 10.3 0.897 I4.43.6 29.156 28.009 0.84 0.657 503.9 51.32 10.499SUMMARY OF RESULTS Determination of Carbon Dioxide Emissions EPA Method 3A Boral Bricks, Inc. Smyrna, Georgia Kiln No. 2 QSD

PeA

Prate Gas Volume Flow, Dry Std. Cond. CFM Actual Gas Volume Flow, CFM F Factor, dscf/million

Btu Percent Excess Air Heat Input Rate, million Btu/hr Production Rate, tons/hr Carbon Dioxide

Concentrations

and Emission

Rates

MwcCoN

C•wE.E CO2 Concentration,

% dry CO2 Concentration,

ppm dry * Mole Weight of CO2, g/mole CO2 Concentration,

mg/dsem CO2 Concentration,

gr/dscf CO2 Emission

Rate, lbs/hr CO2 Emission

Rate, lbs/million

Btu CO2 Emission

Rate, lbs/ton 15183

15671

15469

15441 31864 32798

32315

32326 8710 8710

8710

8710 158.3 155.0

157.7

157.0 32.1 33.6

32.9

32.9 1.2.66 12.66

12.66

12.66

3.62 3.64

3.59

3.62 36150 36430

35890

36157 44.01 44.01

44.01

44.01 66135 66648

65660

66148 28.91 29.13

28.70

28.91 3762.2 3913.1

3805.3

3826.7 117.0 116.4

115.8

116.4 297.2 309.1

300.6

302.3Example Calculations

Run 1 Stack Pressure,

Absolute,

in. Hg Ps Pba• + Pg SUMMARY

OF RESULTS Determination of Carbon Dioxide Emissions EPA Method 3A Boral Bricks, Inc. Smyrna, Georgia Kiln No. 2

Voltmae Sampled

at Stand. Con&, cu. ft. 17.647 * VM * (Pb• + All / 13.6) VSTD TM + 460 Volume of Water Vapor at Std. Cond., SCF Vwc-- 0.04709 * V¢ Moisture Content of Gas Stream Vwc Bws Vsvo + Vwc Percent Moismre•in

Gas Stream 100 * Vwc VsTD + Vwc Mole. Fraction

of Dry Gas 100 P•v MFD 100 Mole. Wt. Stack Gas, Dry Basis, lb/ib mole Md 0.44 * %CO 2 + 0.32 * %Oz + 0.28 * (100 %CO2 %02) Mole. Wt. Stack Gas, Wet Basis, lb/lb mole Ms Md * (1 Bws ) + t 8.0 * B,• 29.080

47.0

5.41

0.103

10.3

0,897

29.157

28.007SUMMARY OF RESULTS Determination of Carbon Dioxide Emissions EPA Method 3A Boral Bricks, Inc. Smyrna, Georgia Kiln No. 2 Avg. Stack Velocity,

ft/sec

(% + 460) Vs 85.49 * Cp * APS * SQRT

(Ps * Ms) Gas Volume Flow, Dry Std. Con& CFM 1058.82 * Vs * A * Ps * (I B•)

SD Ts + 460 AetuaI Gas •/olume Flow, CFM Q^ Vs * A * 60 Percent Excess Air (%02 (0.5 * %CO)) P• ................................................. * 100 0.264 * %N2 -(%02 (0.5 * %CO)) Heat Input Rate, million Btu/hr 60 * QsD

(20.9 %02) TC

......................... * Fd

(20.9) •C(J2 Concentration,

gr/dsef (At Standard

Conditions) Ca Cmeas * 7.263 E-08 CO2 Emission

Rate, lbs/hr (At Standard

Conditions) CAw Qso * 60 * ca Standard Conditions

68 Deg. F, 29•92 in. Hg Bias Corrected

Results 50.6

15183

31864

158.3

32.1

2.89E+01

3762.2