2540=P""r.f.:BWM0347 Rev.1/2011 **pennsylvania** - !lEFIIRTMENT
OF EIMRONMEHTAL PROTEC11,0N COMMONWEALTH

OF PENNSYLVANIA DEPARTMENT

OF ENVIRONMENTAL PROTECTION BUREAU OF WASTE MANAGEMENT FORM

· 26R CHEMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT

· ey THE GENERA TOR This must accurately C9f11pleted.
All required
must be

. typed or legibly printed
In the spaces provided.

If additional space is necessary,

' identify each attached sheet as Fonn 26R, **refe~nce** the item number and identify the date prepared. The date on attached sheets **n~** to match the date

· noted below. General Reference 287.54 Date Prepared/Revised

219111 c. Physical Appearance

- 1

- 't.".

Notes EPA Generator2540.PM-BWM0347 Rev.112011 a. the waste, as specified

in the instructions,

Is attached. c. d. a. c. Address Une
1 Address Une
1 Address City State ZIP Municipality Phone waste Name Address Line

1 Address Line

1 **Addres~** City State ZIP Municipality rrtle Phone Name
to processing

or cfiSposal 0 cu yd 181 gal processing
or -2

- (check one) D ton (check one)2540-PM-BWM0347 Rev.1/2011 I certify, under penalty of law, that

I have personally examined and am familiar with the Information submitted

In this Annual Report and all attached documents and that based upon my Inquiry of those Individuals Immediately responsible
for obtaining the lnfonnation,

I verify that the submitted lnfonnation

Is true, accurate and complete
to the best of my knowledge.

I understand that the submission

of false infonnation herein
is made subject to the penalties
of 18 Pa. C.S. §4904, relating to unsworn falsification

to authorities, which include fine and imprisonment Check the following,

If applicable: 0

I certify the lnfonnation required

In Section B-1, General Properties was supplied
to the Department
for the year _and has not changed. Fonn Submitted:

0 Form 26R 0 Other (specify) Date Submitted: 0

I certify the Information required

In Section B-2, Chemical Analysis was supplied
to the Department
for the year _and has not changed. Fonn Submitted:

0 Form 26R 0 Other (specify) Date Submitted: 0

I certify the Information required

In Section B-3, Process Description and Schematic, was supplied
to the Department for the year_ and has not changed. Fonn Submitted:

0 Form 26R 0 Other (specify) Date Submitted: Name of Responsible Official Bernhardt Kissel Signature

Date

1 -3-February

8, 2011 Form 26R: Section B2b WASTE SAMPLING METHODS

I• All samples were obtained
as grab type samples with
a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are composited within the storage production tank or tank battery at each well site where gas production

is occurring. Each automatic
or manual ejection
of formation fluids
is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal
at various PaDEP permitted waste disposal facilities on different schedules determined
by individual well characteristics. Grab samples
of the composited fluids were obtained
at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in• containment and storage "buckets• capable
of retaining small amounts
of lost fluids. Samples were obtained with bottle sets prepared
at the laboratory which contained appropriate preservatives,

as necessary, depending
on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions
at the laboratory. Flowback samples were composited

to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions
at the laboratory

or on the well location upon completion

of the composite sampling process. Samples were distributed into bottle sets prepared
at the laboratory which contained appropriate preservatives,

as necessary, depending
on the specific test run requested.
All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process
at various times and combined into a composite sample for analyses
at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed
on both sample composites.

In some earlier cases during the utilization
of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness

of the composite sample and composite grid sample positions were varied to the extent possible. Pit water (drill fluid) is currently discharged

to closed containment and is re-conditioned and reused from well to well.February

9, 2011 Form 26R: Section B3a WASTE GENERATION PROCESS Pit Water "Drill Fluids" Remnant drill fluids are generated

in the well bore during the penetration

of the drill stem as it intercepts both ground water and formation fluids. These fluids are brought
to the surface along with the drill cuttings, pieces of the intercepted rock strata, by the return flow system of the drilling process. Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are mixed with sawdust
to absorb remnant fluid and loaded out for disposal
at a landfill. Fluids are currently stored
in closed containers

to be processed for reuse. · Flowback: "Fracing Fluid" Flowback

is produced from all fluids that flow back to surface during the "hydrofracing" process which occurs under pressure and results
in the setting of a propant within the formation fractures

. Production Fluid "Brine" During the production

of natural gas, formation pressures bring remnant frac fluids, during the initial production phase, and formation fluids to the surface along with produced gas.Well I. D.# (various) Well I.D.# . (various) ,,/

**~** -0- -o.- **/~,** /1' I\ 1 \ / Well I. D.# (various) \ I ::b/ \ I /II' \ I / \ I // \ I // . \ I / Weq I. D.# (various) \ 1 // \\/ / \ I / -a-/ " rY --:,_/ '<" **0~\:~ -~**  **~** Mobile Tank Truck \__,) 1 00 . 0 **~f'"O~vc** .. **:tt~.l\ Oc\.1-tt\~~:-**  **\OA~S ~~**  ( Ji S brine (TYP.)

- COUNTYB

COUNTY A _ s Road Transport Landfill Or"' **trtu.+~GA+** 'P\W\t ote: Process producing waste: Gas well produced fluids (brines) are typically produced · in conjuction wi.th natural gas. These fluids are brought to the surface utilizing either mechanical or physical lift procedures.

(.) **~** w :r: (.) C/') z 0 **~** 1- 0:: 0 0... C/') z **~** 1- **~ ~**  **~** I i - lC

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# ENVIRONMENTAL SERVICE SAMPLE REQUEST 

# & CHAIN OF CUSTODY PAGE_LoF.:::: 

# LABORATORIES, INC.

**~** 

# HEADQUARTERS: 

# cp SOUTHERN DIVISION: 1803 

# Philadelphia St. 1278 BenUeyvllle 

# Road 

# D Indiana, 

# PA 15701 VanVoorhis, 

# PA 15368 {724) 463·TEST (724) 258- 

# TEST 

# REC'D FEB -4 Z009 (724) 465-4209 (724)

**258~378** 

# FOR INTERNAL LABORATORY USE ONLY 

# Sample Type Sample ldentlflcaUon ESL# 

# Composite Grab Matrix 

# f# of 

# Containers Container Type 

# Analysis Requested

**~** 

# Date~orr 

# Time~ 

# D~ 

# nm_, PrwMfY81Mt



# t}esirn'l~ 

# O'er

**~** 

# ~ 

# 1/J:>f>J 

# orzas ww 1 

# Plastic Uter pH, 

# SC, Chorida, Sulfala, 

# otoor 

# --- · 

# --- nona Osmotle 1'.-unt, 

# Alkallnll¥. Acidity 

# 1'1{£ 

# ---- ---- I 

# ww 2 

# Plastic Liter TSS, TDS, 

# Olsaolved Iron, 

# ---- 

# --- none BOI'CXl, 

# BOD, MBAS SUrfactanta



# ---- ---- ww 1 

# Plastic Liter AI, Aa, Ba, 

# Be, Cd, Cr, Co, 

# Cu, Fe, Pb, Mg 

# ---- ---- **HNO~** 

# Mn, Hg, Nl, 

# Sa, Ag, 

# Sr, Zn, 

# Ll, Na, Ce, Hatcrn

**~$** 

# ---- ---- ww 1 Plastic Uter 

# ---- ---- HaS04 Nltrate+Nitrlte, TKN, Ammonia, COD



# ----- 

# ---- ww 2 Plastic Utar



# --- ---- HNOs Groaa Alpha, Gross Bate


# ---- ---- ww 1 Amber Glass L Oli&Grease


# ---- 

# ---- HCf



# ---- ---- ww 1 Amber Glass L



# ----- 

# ---- **H~0**



# 4 

# Total Phenolics


# ---- ---- ww 2 Amber VOA Vials Elhylena Glycol


# ---- ---- nona



# ~ 

# --- ww 2 

# Amber VOA Vials Benzene. Toluene 

# lr 

# , 

# ---- ----- u• lr HCI 

# TRIP BLANK 

# ocr ___.....-:

**~**



# ~ 

# -;::::::::::- Water 

# 2 Amber VOA Vials Benzene, 

# Toluene 

# 01011 

# --- --- HCI Tli& UNDERSIGNED PURCHASER HEREBY AGREEs 

# 'TO PAY SERVICE CHARGES ON

**ACCOUNTS~** 

# a1 DAYS OLD. 

# Project Notea : 1. THESE SERVICE CKARGESWIU.ACCRUEATlHE 

# RATE OF 

# 11121' PER loiCNTit 

# (1K PER ANJM.I

**ORTHE~AUOWEO** 

# BYLAW.) 2. 

# THE UNDERSIGNED 

# PURCHASER AGREES TO PAY, IN THE EVENT tllS 

# ACCOUNT III!COMES DELINCIUENT 

# N4D IS TURNED 0\IEI\ 

# TO Nl'f



# ATTORNEY FOR

**C~Cl]gN.** 

# REASONABLE 

# AlTORNEV'S FEES PUISAI.L COURT AND ATT&NDAHT 

# COLLECTIOH COSTS.



# 7/l,~ff/d~ /kk-9

**l~A""** Company/Nama: 

# XTOENERGY IS5mpled



# By.7'iatu~ /oall!f11me •



# Lj(~ **1/;~t;Cf** 1 

# /;?..!rJ t::t 

# I I I() 

# 1110 Address: 

# 395 AIRPORT ROAD



# R~



# ,/t~arn:, **~By:** (Sigralln) 

# /



# !tXme//"~ INDIANA, PA 15701 

# 1!/0

**~. ~**  

# L22_ 

# .. Relinquished By. (Signature)



# ~la/1ima d 

# By. (Bigratute) 

# ( 

# Da1el Tlme 

# Conlact Person: 

# MR. MIKE HAHN Rellnqlllshad 

# By. (Sigrwlure) 

# Oalel Tlme Receiwld By. (Siptunl) 

# Date/ Time 

# Phone : 

# (724) 349-0600 CHAIN OF CUSTODY SEAL BROKEN: Yes 

# - No 

# Fax: 

# (724) 349-8489 

# "''(

**-/,,./~/ ~~)**  

# £.5'**~** -N.Vi gflNM t=-N-T 4i -

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I I'..,

I 11 I W" I - 11 II ,. SERVICE LABORATORIES,
INC. 1803 Phlladelphla Street, Indiana, PA 15 701 (724)-463-lEST

FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: XTOEnergy 395 Airport Road Indiana, PA 15701 1/12/2009 7:05 AM 1/12/2009 11:54 AM l/30/2009 Analyte Acidity to pH=8.3 Alkalinity

to pH=4.5 Biological Oxygen Demand 05 Chemical Oxygen Demand Ammonia

as N I Distilled Chloride Kjeldahl Nitrogen

as N pH(SM) Sulfate (ASTM) Total Nitrate+ Nitrite as N Aluminum· ICP Arseoic-ICP Barium ·ICP Beryllium- ICP Boron Cadmium

- ICP Calcium- ICP Chromium- ICP Cobalt-ICP Copper- ICP

· Hardness Iron- ICP

Analyst MS MS MAD ES AID MS AID JH KM JFW GJT GJT GJT GJT ES GJT OJT GJT GJT GJT GJT GJT Comments; Radiologicals done by Benchmark Analytical Note; DEP Certification

#s 32-00382 Analysis Date Ol/13fl009 01/1412009 01/17/2009 0111612009 01/16/2009 01/13/2009 01/15fl009 01/12/2009 01/16/2009 01129/2009 01127/2009 01127/2009 01127/2009 0112712009 01/20/2009 01/2712009 01/27/2009 0112712009 01/27/2009 01/27/2009 01/27/2009 01/2712009 SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Sample Result

09 01008 WasteWater Grab CLIENT (Client) Osterling 8165 Units Method ND mg/1 as CaC03 SM2310B 171 mg/1 as CaC03 SM2320B 43.0 mg/1 SM5210B 627.5 mg/1 SM5220D 40.19 mWJ **~M4SOONH3B**

& r 33165.0 mg/1 SM4500ClC 52.3 mgll SM4500Norg-C,D 6.80

su SM4500H-B ND mg/1 D516-02 6.10 mg/1 SM4500N03E ND mg/1 200.7/6010 ND mg/1 200.7/6010 117.800 mg/1 200.7/6010 ND mg/1 200.7/6010 9.75 mg/1 SM4500B-B ND mg/1 200.7/6010 2687.700
mg/1 200.7/6010 NO mg/1
200

. 7/6010 NO mgll 200.7/6010 ND mgll 200.7/6010 7926 mg/1 SM23408 32.600 mgll 200.7/6010 MDL

l 20 2.0 500.0 0.99 1.0 52.3 0.01 5 0.50 1.000 1.000 0.500 0.500 6.25 0.500 50.()00 0.500 0.500 0.500 1 1.000 [ND=Not Detected Page

1 of3;;;=f\rv-·N••-=-N-T•-Lt...IK\...•..i'J!t.ASERVICELABORATORIES,INC.1803PhiladelphiaS1reet,Indiana,PA15701(724)-463-lESTFAX(724)-465-4209ReportofAnalysisName:SampleStartDate:ReceiptDate:ReportDate:XTOEnergy395AirportRoadIndiana,PA157011112120097:05AM11121200911:54AM1/30/2009AnalyteIron,Dissolved-ICPLead-ICPLithium-ICPMagnesium-ICPManganese-ICPMercuryNickel-ICPSelenium-ICPSilver-ICPSodium-ICPStrontium-ICPZinc-ICPOsmoticPressureDetergents,MBASEthyleneGlycolOilandGrease-HEMPhenolics,asPhenolSpecificConductanceTotalDissolvedSolids(TDS)TotalSuspendedSolidsRadiologicalsAnalystGJTGJTGJTGJTGJTDMMGJTGJTGJTGJTGJTGJTES11..CLMAIDACMADMADenchmaROComments:RadiologicalsdonebyBenchmarkAnalyticalNote:DEPCertification#s32..{)0382SampleiD#:SampleType:SampleSource:Sampler:ClientSampleID:AnalysisSampleDateResult01/27/2009ND01/27/2009ND01/27/2009ND01/27/2009295.00001/27/20091.70001/22/2009ND01/27/2009ND01/27/2009ND01/27/2009ND01/29/200915576.00001/29/2009330.000Olfl.7fl.009ND01/14/2009153001/14/20091.11001/2212009171.00301/16/20098.1.01/19/2009NDOl/13fl.0096740001/19/20095890001/19/200925101/16/2009*Ol/16fl.00914.700901008WasteWaterGrabCLIENT(Client)Osterling8165UnitsMethodmgll200.7/6010mWJ.200.7/6010mgll200.7/6010mgll200.7/6010mWJ.200.7/6010mgll245.1mg/1200.7/6010mgll200.7/6010mgll200.7/6010mgll200.7/6010mgll200.7/6010mgll200.7/6010mOslkgOSPmgllSM5540Cmglkg300.0Mmgll1664Amgll420.1uS/emSM2510BmgllSM2540CmgllSM2540Dmg/1RAD-CTDHSug/L624/8260BMDL1.0000.50050.00050.0000.5000.00020.5001.0000.500500.00010.0000.50010000.1005.0005.00.050l2550.00010.00IND=NotDetectedPage2of3i=i'ii'it..i"ia5;:::--::;r:.iii.i•.\iViKUI".,1tN!ALSERVICELABORATORIES,INC.1803PhiladelphiaStreet,Indiana,PA15701(724)-463-TESTFAX(724)-465-4209Name:SampleStartDate:ReceiptDate:ReportDate:47)TolueneXTOEnergy395AirportRoadIndiana,PA157011/12120097:05AM1/12/200911:54AM1130/1009AnalyteReportofAnalysisSampleiD#:SampleType:SampleSource:Sampler:ClientSampleID:AnalystAnalysisSampleDateResultRO011161200911.70Comments:RadiologicalsdonebyBenclunarkAnalyticalDEPCertification#s32-003820901008WasteWaterGrabCLIENT(Client)Osterling8165UnitsMethodug/L624/8260BMDL10.00jND=NotDetectedPage3of3;;;;;;;;; - •• •• D.#';. N• •;;;;;;;;; N::w:

-

i tNVI
.... VI
.. Mt ... lA;. SERVICE LABORATORIES,
INC. 1803 Philadelphia Street, Indiana, PA 15 701 (724}-463-TEST

FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: 1) Benzene 47) Toluene XTOEnergy 395 Airport Road Indiana, PA 15701 1112/2009 1112/2009 11:54 AM 1121/2009 Analyte Note: DEP Certification

#Is 32-003 82 Report of Analysis SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO 01/16/2009
NO RO 01/16/2009
NO

09 01011 Waste Water Grab CLIENT (Client) Trip Blank Units Method ug!L 624/82608 ug/L 624/82608 MDL 1.00 1.00 IND=Not Detected Page

1 of 1LAB 10 #: 39-00401 BENCHMARK ANAL YTICS. INC. 4777 saucon Creek Road CenterValley,

PA 18034-9004 . ..

. : ·:·: :: /'>::
,. ::_ . :·. ·.

' PHONE.(610} 974-8100 **'.:?;;y: :.::.:;**  **~j; :<:!**  FAX (610) 974-8104

. 7.

; **/;~l ·~/!**  **:~~; :::~**  **;** < . ' _ : : : · ·.. ... . . .. . PO#: PVvSID# Work Order: 09011554 09011554 1 of1 Paso 1oft \

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.. ... **_~_** SAMPLE:

08 01008

t..b JO
: DW111SI54-002A
Grab SAMPLED BY: David A. Stile Sampl• Tlma 0111212009 7:05 Dol!! **~** Uocart. MOA .ua!l! MAthrut **~** .anaM!Is **~tatt ~!llh!!i!**  **E~ ~**  Grot• Alpha **~78.9**

:1: 365.8 1316 pCIIL. EPASOO.O 01116109 8:45 01120109 BP&-CV Gross Beta ·16.90

:t AM.9 1698 pCIIL EPA900.0 01/16109 8:45 01120109 BPS-CV -·
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DATE: **--~~n~l~~-00_9** ____
_