## Report ofNOx Removal Measurements from an SNCR System at the St. Mary's Cement Dixon IL Facility



## Prepared By: 

## De-NOX Technologies, LLC 22 Partridge Lane East Hampstead, NH 03826

OCT 2005

## INTRODUCTION StMary's Cement Company operates three preheater-type kilns and one long-dry kiln in Dixon, IL. The Company contracted with De-NOx Technologies to evaluate the effectiveness ofan SNCR system for reducing NOx emissions at one ofthe preheater units. Testing was conducted during the week of03 October. The test apparatus consisted ofmultiple 500 gallon IBC's to store 19 wt% ammonia, DNT's dual fluid reagent atomi:dng injectors, a portable pump skid, compressed air control system, reagent distribution assembly, and various hoses in lieu ofpermanent piping. The pump skid contained flow meters to measure reagent flow. A portable gas analyzer was used to measure NOx reduction performance. SNCR requires injection ofeither ammonia or urea into the kiln gas atjustthe right temperature to react with NOx to form N2. Proper reagent atomization is also critical to assure complete dispersion and mixing with the NO molecule. The reaction requires a temperature of 1600 - 2000 degF, in the presence ofoxygen. The predominant ammonia-based reaction is described as follows:

AMMONIA+NITROGEN OXIDE +OXYGEN NITROGEN+ WATER
A simplified flow sheet ofthis facility is provided in Figure 1. There is no bypass, secondary air, or supplemental firing. The gas exiting the 

### kiln flows up through a series offour cyclone/preheaters. Thethree preheated kilns are combined into a common stack.

## TEST SCOPE**Al~D** 

## METHODOLOGY The objectives ofthe test were threefold: I. Optimize injection location and settings. 2. Generate stoichiometric performance curves, and 3. Generate continuous run data Reagent was injected in three vertical riser locations- hereinafter referred to as Upper, Middle and Lower. In all cases, the cross-sectional area ofthe duct was suitable for, at most, two injectors. Existing inspection doors**wer~** """'odified with ports for the injectors -in general the doors were located toward the comers ofthe duct with the ports angled to the center as much as possible. The time delay between the point ofinjection and reaction on the portable gas analyzer was less than one_minute. As such, rapid data collection was possible. In general, the gas analyzer probe was inserted for approximately 30 seconds - at which point the data was stable- and an instantaneous data point taken by printer. Baseline NOx datapoints were taken after every 2 or 3 test runs. Reagent flows of0.25, 0.5, 0.75, and 1.0 GPM were repeated to allow generation ofperformance curves.

- ..'·

## TEST RESULTS The summarized data is presented in Table 1 and Figures 2 and 3. The Upper Test Location had excellent results. Approximately 65% reduction was demonstrated at an NSR (molar ratio ofammonia to unabated NOx) of 1.0. Another way to look at this simplified statistic is that 65% ofthe reagent was utilized in the SNCR reaction with the other 35% lost to other ends (either: 1) unreacted ammonia slip gas, 2) reacted with SOX or solids, or 3) oxidized to NOx and then subsequently reduced to N2.). The Middle and Lower Test Locations had even better results. Approximately 80-85% reduction was demonstrated at an NSR of 1.0. Below 70% reduction, NOx reduction closely approaches perfect chemical efficiency- which is also translated to mean that ammonia slip to the lowest cyclone will be non-detectable and that overall chemical cost will be lowest. Clinker build-up is more prevalent in the lower riser. Such accumulations would have a detrimental effect on the SNCR injectors - either by slagging over/around the injectors or by physical damage from falling clinker. For these reasons, injectors should be located in the Middle Riser. Excellent results at this facility can be explained by the near perfect SNCR conditions in the riser. Main burner combustion is very good- evidenced by low CO in the riser (200 ppmv). The absence of"combustion-like" conditions in the riser keeps oxidation of a.11monia low. The residence time in the riser is also adequate - and begins to simulate , laboratory pipe-flow-apparatus conditions- as evidenced by the improvement going to··. the Middle location but no improvement going to the Lower location. Another interesting conclusion is that the ammonia has no apparent interaction with sulfur compounds in the riser. Given that S02 in the riser is approximately 2500 ppmv, ifammonia was consumed by reaction with sulfur compounds, it would have reduced the chemical efficiency ofthe SNCRreaction. This is not to saythat such a reaction would not occur atthe lower operating temperatures higher up in the tower, but that it does not occur at kiln outlet temperatures. Table 1 has the Raw and Summarized data. Figure

### 2 is a Chart ofthe unitless factors NSR- vs-% Nox Reduction Figure 3 is a Chart ofGPM - vs - % NOx Reduction

## CONCLUSIONS The following is concluded: 

## • • • • Performance was outstanding. NOx reductions in excess of50% can be reliably achieved at a reagent flow rate of0.5 GPM per unit. The Middle and Lower injection locations demonstrated similar performance, and superior to the Upper location. Considering the prevalence for clinker to build-up 

### in the lower elevations, the Middle Riser ports are recommended for permanent installation. System chemical efficiency was also excellent. Near-zero ammonia slip can be expected to exit the Stage IV (lowest) cyclone up to approximately 60% NOx reduction. Dixon should be aware that supplemental fuel firing in the riser will adversely effect NOx reduction.

### ------------------------------



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/'Gas Moisture 14 % / Stack Gas Flo 28,000 wscfm I TABLE 1 NH3 Density/ 0.934 SG Oct 2005 Dixon SNCR Testing NH3Conc I 19 wt% Assumed/1 Baseline Baseline Reagent Downcome Baseline Assumed sorn NH3 NOx NOx Overall Meter NO NO Baseline Corrected Mass Flow Mol Flow scfm mol/hr % % Location StartTime GPM ppmd ppmd · co co GPM lb/hr mollhr NSR NOx co I. ppm ppm Reduction Change I 9:48 1 220' 1023 206 212 1.03 481.5 5.4 26.6 4.5 1.21 76 -3 Upper Riser 19% ammonia 9:56 1 206 1023 228 212 1.03 481.5 5.4 28.6 4.5 1.21 80 8 2nozzles 10:09 1.5 173 1034 214 210 1.55 722.2 8.1 29.0 4.5 1.79 83 2 10:16 0.5 576 1034 219 210 0.52 240.7 2.7 29.0 4.5 0.60 44 4 10:16 1 267 956 221 222 1.03 461.5 5.4 26.8 4.2 1.29 70 0 10:24 0.5 595 956 216 222 0.52 240.7 2.7 26.6 4.2 0.65 36 -2 10:28 1 299 1099 207 202 1.03 481.5 5.4 30.6 4.6 1.13 73 2 10:34 1.5 172 1099 205 202 1.55 722.2 6.1 30.8 4.6 1.69 64 1 10:37 0.5 467 1033 180 206 0.52 240.7 2.7 28.9 4.5 0.60 53 -13 10:42 1 259 1033 196 206 1.03 461.5 5.4 28.9 4.5 1.20 75 -5 10:45 0.5 586 1064 196 201 0.52 240.7 2.7 30.4 4.7 0.57 46 -2 12:59 0.75 452 1088 197 204 0.77 361.1 4.0 30.5 4.7 0.85 58 -3 13:05 0.75 333 1020 192 177 0.77 361.1 4.0 28.6 4.4 0.91 67 8.5 13:10 0.75 363 1020 0.77 361.1 4.0 28.6 4.4 0.91 64 13:16 0.75 435 991 0.77 361.1 4.0 27.7 4.3 0.94 56 10:49 0.5 595 1064 203 201 0.52 240.7 2.7 30.4 4.7 0.57 45 1 lnj#1 Only 10:52 0.5 598 1064 197 201 0.52 240.7 2.7 30.4 4.7 0.57 45 -2 lnj#2 Only 10:56 0.5 594 936 183 181 0.52 240.7 2.7 26.2 4.1 0.66 3'/ 1 lnj #20nly 10:59 0.5 464 936 199 181 0.52 240.7 2.7 26.2 4.1 0.66 50 10 lnj#1 Only 13:20 0.25 649 1025 0.26 120.4 1.3 28.7 4.5 0.30 37 •13:59 1 223 ,-1,@()_ .. ·.; .. ' -247 284 ,1._03_ . 48,.5 .5.4 30.2 4.7 1.14 79 -13 Middle Riser 14:63 1 102 1026 "• 298 236 1.03 481.5 5.4 28.7 4.5 1.21 90 26 2 nozzles 14:06 0.5 455 1152 213 269 0.52 240.7 2.7 32.3 5.0 0.54 61 -21 14:10 0.5 491 1152 298 269 0.52 240.7 2.7 32.3 5.0 0.54 57 11 14:12 0.75 195 1034 305 300 0.77 . 361.1 4.0 29.0 4.5 0.90 81 2 14:16 0.75 248 1034 286 300 0.77 361.1 4.0 29.0 4.5 0.90 76 -5 14:19 1 68 1064 291 304 1.03 481.5 5.4 29.8 4.6 1.16 94 -4 14:23 0.5 456 1064 251 304 0.52 240.7 2.7 29.8 4.6 0.58 57 -17 14:27 0.25 865 1063 265 215 0.26 120.4 1.3 29.3 4.6 0.29 19 23 left lnj Only 14:31 0.25 764 1063 274 215 0.26 120.4 1.3 29.8 4.6 0.29 26 27 left lnj Only 14:33 0.25 768 1116 166 236 0.26 120.4 1.3 31.2 4.9 0.28 31 -20 Right lnj Only 15:38 1 30 1038 293 233 1.03 481.5 5.4 29.1 4.5 1.19 97 26 Lower Riser 15:48 0.5 500 1012 301 291 0.52 240.7 2.7 28.3 4.4 0.61 51 3 2 nozzles 15:48 0.75 173 1021 315 285 0.77 361.1 4.0 28.6 4.4 0.91 83 11 15:53 0.5 471 1021 293 285 0.52 240.7 2.7 28.6 4.4 0.61 54 3 15:55 0.75 192 1010 314 270 0.77 361.1 4.0 28.3 4.4 0.92 61 16 16:00 1 56 1010 299 270 1.03 481.5 5.4 28.3 4.4 1.22 94 11 16:03 0.5 362 1044 319 293 0.52 240.7 2.7 29.2 4.5 0,59 63 9 One Injector 16:07 0.5 362 1044 267 293 0.52 240.7 2.7 29.2 4.5 0.59 65 -2 One Injector 16:10 0.75 129 991 302 304 0.77 361.'-f 4.0 27.7 4.3 0.94 67 -1 One Injector 16:15 0.25 676 991 295 304 0.26 126:4 1.3 27.7 4.3 0.31 32 -3 One Injector 16:18 0.25 724 991 305 304 0.26 120.4 1.3 27.7 4.3 0.31 27 0 One Injector

## • ST MARYS CEMENT INC. (U.S.)**~YlARYS** 

### CERTIFIED MAIL NO 7005 0390 0000 6162 4966 Return Receipt Requested 

### April 26, 2006 Illinois Environmental Protection Agency Division ofAir Pollution Control Compliance Section (#40) P.O. Box 19276 Springfield, IL 62794-9276 RE: SNCR Pilot Test Application No. 05080006, ID No. 103806AAC Dear Sir or Madam: St Marys Cement Inc. (U.S.) Dixon Plant 1914White Oak Lane P.O. Box468 Dixon, illinois 61021 USA 815-284-3357

:**,~·: ~'**  -' '- __;' _,**~"«"**



### On October 12, 2005, St. Marys Cement, Inc. (SMC) received authorization to conduct pilot testing for Selective Non-Catalytic Reduction (SNCR) at the Dixon, Illinois plant. The pilot testing was performed in two phases; iterative testing and long-term testing. The iterative testing was performed to determine the optimal injection location and rate whereas the long-term testing was performed to confirm the iterative results and determine any process implications. Pilot testing for SNCR under the above referen'ced permit has concluded at the Dixon plant, effective the date ofthis submittal. Therefore, in accordance with the above referenced permit, SMC is submitting the attached reports detailing the findings ofthe SNCR pilot test project. The report for the iterative testing is included as Attachment A. The long-term testing report is included as Attachment B. Ifyou have any questions regarding the SNCR pilot study, please contact me at 815-284- 3357, ext. 118. Sincerely, ST. MARYS CEMENT, INC.

cc: IEPA/DAPC Peoria CERTIFIED MAIL NO 7005 0390 0000 6162 4973 

### USEPA Region V CERTIFIED MAIL NO 7005 0390 0000 6162 4980

www.stmaryscement.com

### ATTACHMENT A ITERATIVE TEST RESULTS

## Report ofNOx Removal Measurements from an SNCR System at the St. Mary's Cement Dixon IL Facility

Prepared By: De-NOX Technologies, LLC 22 Partridge Lane East Hampstead, NH 03 826

OCT 2005

## INTRODUCTION St.Mary's Cement Company operates three preheater-type kilns and one long-dry kiln in Dixon, IL. The Company contracted with De-NOx Technologies to evaluate the effectiveness ofan SNCR system for reducing NOx emissions at one ofthe preheater units. Testing was conducted during the week of03 October. The test apparatus consisted ofmultiple 500 gallon IBC's to store 19 wt% ammonia, DNT's dual fluid reagent atomizing injectors, a portable pump skid, compressed air control system, reagent distribution assembly, and various hoses in lieu ofpermanent piping. The pump skid contained flow meters to measure reagent flow. A portable gas analyzer was used to measure NOx reduction performance. SNCR requires injection ofeither ammonia or urea into the kiln gas atjust the right temperature to react with NOx to form N2. Proper reagent atomization is also critical to assure complete dispersion and mixing with the NO molecule. The reaction requires a temperature of 1600 - 2000 degF, in the presence ofoxygen. The predominant ammonia-based reaction is described as follows:

AMMONIA +NITROGEN OXIDE + OXYGEN NITROGEN+ WATER
A simplified flow sheet ofthis facility is provided in Figure 1. There is no bypass, secondary air, or supplemental firing. The gas exiting the kiln flows up through a series offour cyclone/preheaters. The three preheated kilns are combined into a common stack.

## TEST SCOPE AND METHODOLOGY The objectives ofthe test were threefold: 1. Optimize injection location and settings. 2. Generate stoichiometric performance curves, and 3. Generate continuous run data Reagent was injected in three vertical riser locations - hereinafter referred to as Upper, Middle and Lower. In all cases, the cross-sectional area ofthe duct was suitable for, at most, two injectors. Existing inspection doors were modified with ports for the injectors

- in general the doors were located toward the corners ofthe duct with the ports angled to the center as much as possible. The time delay between the point ofinjection and reaction on the portable gas analyzer was less than one minute. As such, rapid data collection was possible. In general, the gas analyzer probe was inserted for approximately 30 seconds - at which point the data was stable- and an instantaneous data point taken by printer. Baseline NOx datapoints were taken after every 2 or 3 test runs. Reagent flows of0.25, 0.5, 0.75, and 1.0 GPM were repeated to allow generation ofperformance curves.

## TEST RESULTS The summarized data is presented in Table 1 and Figures 2 and 3. The Upper Test Location had excellent results. Approximately 65% reduction was demonstrated at an NSR (molar ratio ofammonia to unabated NOx) of 1.0. Another way to look at this simplified statistic is that 65% ofthe reagent was utilized in the SNCR reaction with the other 35% lost to other ends (either: 1) unreacted ammonia slip gas, 2) reacted with SOX or solids, or 3) oxidized to NOx and then subsequently reduced to N2.). The Middle and Lower Test Locations had even better results. Approximately 80-85% reduction was demonstrated at an NSR of 1.0. Below 70% reduction, NOx reduction closely approaches perfect chemical efficiency - which is also translated to mean that ammonia slip to the lowest cyclone will be non-detectable and that overall chemical cost will be lowest. Clinker build-up is more prevalent in the lower riser. Such accumulations would have a detrimental effect on the SNCR injectors- either by slagging over/around the injectors or by physical damage from falling clinker. For these reasons, injectors should be located in the Middle Riser. Excellent results at this facility can be explained by the near perfect SNCR conditions in the riser. Main burner combustion is very good - evidenced by low CO in the riser (200 ppmv). The absence of"combustion-like" conditions in the riser keeps oxidation of ammonia low. The residence time in the riser is also adequate - and begins to simulate' laboratory pipe-flow-apparatus conditions - as evidenced by the improvement going to the Middle location but no improvement going to the Lower location. Another interesting conclusion is that the ammonia has no apparent interaction with sulfur compounds in the riser. Given that S02 in the riser is approximately 2500 ppmv, ifammonia was consumed by reaction with sulfur compounds, it would have reduced the chemical efficiency ofthe SNCR reaction. This is not to say that such a reaction would not occur at the lower operating temperatures higher up in the tower, but that it does not occur at kiln outlet temperatures. Table 1 has the Raw and Summarized data. Figure 2 is a Chart ofthe unitless factors NSR- vs - % Nox Reduction Figure 3 is a Chart ofGPM- vs - % NOx Reduction

## CONCLUSIONS The following is concluded:
• Performance was outstanding. NOx reductions in excess of50% can be reliably achieved at a reagent flow rate of0.5 GPM per unit. • The Middle and Lower injection locations demonstrated similar performance, and superior to the Upper location. Considering the prevalence for clinker to build-up in the lower elevations, the Middle Riser ports are recommended for permanent installation. '· • System chemical efficiency was also excellent. Near-zero ammonia slip can be expected to exit the Stage IV (lowest) cyclone up to approximately 60% NOx reduction. • Dixon should be aware that supplemental fuel firing in the riser will adversely effect NOx reduction.Gas Moisture 14% Stack Gas Flo 28,000 wscfm TABLE 1 NH3 Density 0.934 SG Oct 2005 Dixon SNCR Testing NH3 Cone 19 wt%**"'~--** Assumed Baseline Baseline Reagent DowncomE Baseline Assumed Sol'n NH3 NOx NOx Overall Meter NO NO Baseline Corrected Mass Flow Mol Flow scfm mol/hr % % Location StartTime GPM ppmd ppmd co co GPM lblhr mollhr NSR NOx co ppm ppm Reduction Change 9:48 220 1023 206 212 1.03 481.5 5.4 28.6 4.5 1.21 78 -3 Upper Riser 19% ammonia 9:58 206 1023 228 212 1.03 481.5 5.4 28.6 4.5 1.21 80 8 2nozzles 10:09 1.5 173 1034 214 210 1.55 722.2 8.1 29.0 4.5 1.79 83 2 10:16 0.5 576 1034 219 210 0.52 240.7 2.7 29.0 4.5 0.60 44 4 10:18 1 287 956 221 222 1.03 481.5 5.4 26.8 4.2 1.29 70 0 10:24 0.5 595 956 218 222 0.52 240.7 2.7 26.8 4.2 0.65 38 -2 10:28 1 299 1099 207 202 1.03 481.5 5.4 30.8 4.8 1.13 73 2 10:34 1.5 172 1099 205 202 1.55 722.2 8.1 30.8 4.8 1.69 84 1 10:37 0.5 487 1033 180 208 0.52 240.7 2.7 28.9 4.5 0.60 53 -13 10:42 1 259 1033 198 208 1.03 481.5 5.4 28.9 4.5 1.20 75 -5 10:45 0.5 586 1084 196 201 0.52 240.7 2.7 30.4 4.7 0.57 46 -2 12:59 0.75 452 1088 197 204 0.77 361.1 4.0 30.5 4.7 0.85 58 -3 13:05 0.75 333 1020 192 177 0.77 361.1 4.0 28.6 4.4 0.91 67 8.5 13:10 0.75 363 1020 0.77 361.1 4.0 28.6 4.4 0.91 64 13:16 0.75 435 99' 0.77 361.1 4.0 27.7 4.3 0.94 56 10.49 0.5 595 1084 203 201 0.52 240.7 2.7 30.4 4.7 0.57 45 1 lnj#1 Only 10:52 0.5 598 1084 197 201 0.52 240.7 2.7 30.4 4.7 0.57 45 -2 lnj #2 Only 10:56 0.5 594 936 183 181 0.52 240.7 2.7 26.2 4.1 0.66 37 1 lnj#20nly 10:59 0.5 464**~36** 199 181 0.52 240.7 2.7 26.2 4.1 0.66 50 10 lnj#1 Only 13:20 0.25 649 1025 0.26 120.4 1.3 28.7 4.5 0.30 37 13:59 1 223 1,080 247 284 1.03 481.5 5.4 30.2 4.7 1.14 79 -13 Middle Riser 14:03 1 102 1026 298 236 1.03 481.5 5.4 28.7 4.5 1.21 90 26 2 nozzles 14:06 0.5 455 1152 213 269 0.52 240.7 2.7 32.3 5.0 0.54 61 -21 14:10 0.5 491 1152 298 269 0.52 240.7 2.7 32.3 5.0 0.54 57 11 14:12 0.75 195 1034 305 300 0.77 361.1 4.0 29.0 4.5 0.90 81 2 14:16 0.75 246 1034 286 300 0.77 361.1 4.0 29.0 4.5 0.90 76 -5 14:19 1 68 1064 291 304 1.03 481.5 5.4 29.8 4.6 1.16 ! ' -4 14:23 0.5 456 1064 251 304 0.52 240.7 2.7 29.8 4.6 0.58 f./ -17 14:27 0.25 865 1063 265 215 0.26 120.4 1.3 29.8 4.6 0.29 19 23 Left lnj Only 14:31 0.25 764 1063 274 215 0.26 120.4 1.3 29.8 4.6 0.29 28 27 Left lnj Only 14:33 0.25 768 1116 188 236 0.26 120.4 1.3 31.2 4.9 0.28 31 -20 Right lnj Only 15:38 1 30 1038 293 233 1.03 481.5 5.4 29.1 4.5 1.19 97 26 Lower Riser 15:46 0.5 500 1012 301 291 0.52 240.7 2.7 28.3 4.4 0.61 51 3 2 nozzles 15:48 0.75 173 1021 315 285 0.77 361.1 4.0 28.6 4.4 0.91 83 11 15:53 0.5 471 1021 293 285 0.52 240.7 2.7 28.6 4.4 0.61 54 3 15:55 0.75 192 1010 314 270 0.77 361.1 4.0 28.3 4.4 0.92 81 16 16:00 1 56 1010 299 270 1.03 481.5 5.4 28.3 4.4 1.22 94 11 16:03 0.5 382 1044 319 293 0.52 240.7 2.7 29.2 4.5 0.59 63 9 One Injector 16:07 0.5 362 1044 287 293 0.52 240.7 2.7 29.2 4.5 0.59 65 -2 One Injector 16:10 0.75 129 991 302 304 0.77 361.1 4.0 27.7 4.3 0.94 87 -1 One Injector 16:15 0.25 676 991 295 304 0.26 120.4 1.3 27.7 4.3 0.31 32 -3 One Injector 16:18 0.25 724 991 305 304 0.26 120.4 1.3 27.7 4.3 0.31 27 0 One Injector

### INTRODUCTION St. Marys Cement, Inc. (SMC) operates a Portland cement manufacturing plant near Dixon, Illinois. The Dixon Plant includes three preheater kiln systems and a long dry kiln system. SMC performed a long-term pilot test evaluation for Selective NonCatalytic Reduction (SNCR) on the three preheater kiln systems during October 2005. The testing was done in accordance with the pilot test construction permit issued by the Illinois Environmental Protection Agency (Application No. 05080006, Facility ID No. 1

03806AAC). The long-term test consisted ofthree separate trial periods; October 18-19, October 25- 26, and October 26-29. However, due to unstable process conditions, the first trial period was excluded from the study. The three preheater kiln systems are vented to a common stack, which was equipped with a Continuous Emissions Monitoring System (CEMS) for the pilot test. The CEMS, rented from and installed by GE Energy Management Services, Inc. (GE Energy), was in operation from September 30, 2005 through November 22, 2005. The CEMS were utilized to determine the baseline and controlled levels of emissions for nitrogen oxides (NOx), sulfur dioxide (SOz), and carbon monoxide (CO). The main stack is also equipped with a Continuous Opacity Monitoring System (COMS). The COMS was not certified until after completion ofthe pilot testing, but was used as an indicator for particulate matter (PM) emissions impacts due to SNCR. ANALYTICAL PROCEDURES The following subsections detail the sampling and analytical procedures used for the long-term SNCR evaluation. CEMS Data Emissions of SOz, 

### NOx, and CO were determined with a CEMS operated in accordance with the procedures ofUSEPA Methods 6C, 7E, and 10, respectively. A gas sample was drawn from the exhaust stack through a filter and transported to a universal gas conditioner through a heated sample line. The gas conditioner removed the moisture from the gas stream and pumped a dry gas sample through a manifold flow system to a series ofinstruments. The CEMS included a TECO 42CHL NOx analyzer (SIN 42CHL-70591-366), a TECO 48 CO analyzer (SIN 0420107035), a TECO 43CHL S02 

### analyzer (SIN 43CHL-75704-380), and a Servomex 01420D oxygen and carbon dioxide analyzer (SIN 01420D-3497) as well as instruments for stack flow (Ashcroft XLdp Pitot Convertor, 

### SIN 81000180) and temperature (API400G Thermocouple Convertor, 

### SIN J 

### 051 158). All of the analyzers were calibrated on a daily basis using USEPA Protocol 1 certified gases. The analyzers were checked for calibration error by introducing

### zero and high range calibration gases. Copies of the daily calibration logs are included in Appendix A. 

### Exhaust gas sampling was performed continuously from September 30, 2005 through November 22, 2005. CEMS data outputs were recorded on data logger and laptop computer. The one-minute data logger readings were then analyzed using Microsoft Excel. The compiled data logger readings are included on compact disc (CD) in Appendix B. COMS Data The impact on PM em1ss10ns was determined with a COMS operated in accordance with the procedures ofUSEPA Method 9. The main stack COMS is a Monitor Labs Lighthawk 560 equipped with GE Energy's Data Acquisition and Handling System (DAHS) for data compilation, analysis and report generation. One-minute average data was extracted from the DAHS and incorporated into the Microsoft Excel data analysis spreadsheets which are included on CD in Appendix B. 

### Process Data The long-term test utilized a 19% aqua-ammonia solution as the SNCR reagent. The reagent injection rate and location used during the long-term test, as established during the iterative testing, were 0.5 gal/min and the lower riser position, respectively. The clinker production rate from each ofthe preheater kiln systems was extracted from the plant information system and incorporated into the Microsoft Excel data analysis spreadsheets which are included on CD in Appendix B. 

### RESULTS AND CONCLUSIONS The long-term SNCR test results and supplemental information required in the construction permit are presented in this section. Table 1 

### presents the mode-by-mode CEMS, COMS and process data summary for the entire data acquisition period. The entire data set is included on CD in Appendix B. Examples ofthe calculations used to determine the emissions rates are also included in Appendix B. As discussed above, the first SNCR mode and second baseline mode data were excluded from the analysis due to an upset on kiln system 1. The other five modes were used to determine the baseline and controlled emission rates as required under the construction permit. As shown by the data in Table 1, a 0.5 gal/min injection rate ofthe 19% aqua-ammonia solution yielded a NOx reduction of greater than 46 

### %. Figure 1 

### graphically presents the uncontrolled and controlled hourly average NOx data with test period trend lines. In addition, the use of SNCR did not result in an adverse impact to other pollutants and

### pollutant surrogates being monitored. Including upset conditions, the SNCR system was in operation for a total of about 105 hours. After accounting for COMS maintenance, no appreciable change in hourly average main stack opacity could be attributed to the use of SNCR, Figure 2. This result indicates that the use of SNCR under the conditions ofthe long-term pilot test will not have an impact on filterable or condensable PM emissions. Further, the reagent injection rate used for the long-term test had demonstrated at essentially 1 00% utilization during the iterative test, which supports the conclusion that no impact on condensable PM will occur due to SNCR. Finally, no adverse impacts on product quality were reported from the on-site analytical laboratory during the test period. Based on the iterative and long-term pilot testing, SNCR is a feasible technology for the purposes of reducing NOx emissions from the Dixon Plant preheater kiln systems. Further, SNCR represents a quite effective control technology under the pilot testing conditions. Based on the results ofthe long-term pilot testing, a 0.323 gal/min injection rate of 19% aqua ammonia would be required to achieve the 30% reduction in NOx emissions necessary to comply with the Illinois NOx SIP Rule.TABLE 1 LONG-TERM SNCR TEST RESULTS Operating Total Total Probe Stack

Mode Operating Operating co NOx 502 C02 02 Temp Flow Flow Flow Flow Temp NH40H Opacity Comments Days Hours ppm ppm ppm % % F deltaP acfm scfm dscfm F gpm % Baseline 1 18.19 436.6 178.01 715.93 6.76 12.26 13.39 314.3 0.16 177567 118371 116003 316.0 0 14.3 SNCR 1 1.11 26.7 179.67 803.88 4.63 12.36 13.19 313.7 0.16 175579 117090 114748 314.1 0.5 14.4 includes upset on kiln 1 Baseline 2 5.95 142.7 188.40 747.49 3.93 11.43 13.87 303.4 0.17 179723 121402 118973 316.8 0 14.7 includes upset on kiln 1 SNCR 2 0.66 15.8 134.65 424.63 0.55 11.50 13.88 315.0 0.18 184730 122956 120497 317.5 0.5 13.7 Baseline 3 0.30 7.2 137.42 612.47 1.22 11.59 14.12 317.1 0.17 181516 120494 118084 317.5 0 13.1 SNCR 3 2.58 61.8 139.88 331.38 2.67 11.45 13.89 315.3 0.18 185139 123194 120728 317.9 0.5 11.5 Baseline 4 24.30 583.1 155.00 612.03 5.06 11.70 13.26 307.8 0.18 187164 125781 123270 316.1 0 13.8 BASELINE 42.79 1026.9 164.91 657.28 5.80 11.94 13.32 310.7 0.18 182949 122521 120069 316.0 0 14.0 Baseline 1, 3, 4 SNCR 3.23 77.6 138.79 350.87 2.11 11.46 13.89 315.2 0.18 185053 123144 120680 317.8 0.5 11.9 SNCR 2, 3 %Reduction 15.8 46.6 63.6FIGURE1HOURLYAVERAGENOxEMISSIONS1200.0-,-----1000.0800.0"""'8Q.Q.'-'=.sa......600.0f.....=Q)C.!=Qu400.0·mo10/1010/2010/30111911/19DateI-···- -...-------------·-·--------··--·-------·-------I--BaselineNOx·····BaselineNOxTrend--SNCRNOx'"'"'"""'SNCRNOxTrendTABLE 1 LONG-TERM SNCR TEST RESULTS Operating Total Clinker

Mode Operating co NOx 802 Production Comments Hours lb/hr lb/hr lb/hr tons/hr "',·• Baseline 1 436.6 91.90 607.15 7.98 47.04

----· ...**--~--** -·--·--- SNCR 1 26.7 91.76 674.36 5.41 Baseline 2 142.7 99.76 650.14 4.76 SNCR 2 15.8 72.21 374.06 0.68 47.12 Baseline 3 7.2 72.22 528.72 1.47 47.10 SNCR 3 61.8 75.16 292.48 3.28 47.13 Baseline 4 583.1 85.03 551.53 6.35 46.87 BASELINE 1026.9 87.86 575.01 7.01 46.94 Baseline 1, 3, 4 !SNCR 77.6 74.56 309.05 2.75 47.13 SNCR 2, 3 :'Yo Reduction 15.1 46.3 60.8 lb/ton eli lb/ton eli lb/ton eli BASELINE 1.87 12.25 0.15 Baseline 1, 3, 4 SNCR 1.58 6.56 0.06 SNCR 2, 3

### APPENDIX A CALIBRATION DATA08: 0 810 100.3 -.03 14 312 .16 173813.1 116171 .L13848 08:0.._ 0 842 100.3 -.03 .14 312 .17 179328.8 119805 117409 Page 2 of 2 Minute Summary Report Environmental Systems Corporation 09/30/05 (continued) Logger Id 01 Logger Name : Logger 01 Interval 001M Param co NOX S02 C02 02 TEMP FLOW ACFM FLOW3 FLOW4 Units PPM PPM PPM % % DEGF DELTAP ACFM SCFM DSCFM Time**-----------------------------------------------~--------------------------------------------------------------** OB:09 0 848 100.3 -.03 .12 312 .16 175367.1 117125 114782 08:10 6 850 88.6 -.03 -.06 312 .16 174330.0 116436 114107 08:11 234 343 4.5 -.04 -.22 312 .17 177641.1 118644 116272 08:12 289 13 3.0 -.04 -.24 312 .16 176739.9 118068 115707 08:13 288 10 3.0 -.04 -.27 312 .16 176245.5 117733 115379 08:14 288 8 3.0 -.04 -.31 312 .16 176540.7 117903 115545 08:15 287 8 3.0 -.04 -.33 313 .16 175412.9 117112 114769 08:16 277 8 12.7 -.04 -.07 313 .16 176797.1 118046 115685 08:17 40 4 50.2 -.04 .27 313 .16 177634.4 118576 116204 08:18 0 0 50.8 -.04 .27 313 .17 178788.4 119242 116857 08:19 0 0 50.8 -.04 .26 314 .16 177778.1 118528 116158 08:20 0 0 50.9 -.04 .25 314 .17 178315.2 118894 116516 08:21 4 0 43.9 -.04 .31 313 .16 175631.4 117131 114789 08:22 415 1 . 9 -.04 .16 313 .16 176412.1 117670 115316 08:23 581 0 .3 -.04 .14 313 .16 175589.7 117137 114794 08:24 587 0 . 3 -.04 . 09 313 .17 178816.5 119297 116911 08:25 588 0 . 3 -.04 .05 313 .17 178415.3 119003 116623 08:26 590 0 . 3 -.04 .00 313 .16 176186.8 117550 115199 08:27 588 0 .2 -.03 2. 71 313 .16 175251.5 116891 114554 08:28 231 0 . 8 4.32 17.27 313 .17 178665.8 119183 116799 08:29 141 283 6.5 11.66 13.55 313 .16 172807.0 115262 112957 08:30 185 695 8.2 12.02 13.30 313 .16 175746.7 117206 114862 Max 910 1646 100.3 19.97 22.25 314 .24 211673.9 141394 138566 Min 0 0 . 0 -. 04 -.33 310 .14 172807.0 115262 112957 Mean 168 280 31.9 3.17 2.51 312 .16 178199.0 119052 116671 Recs 0061 0061 0061 0060 0060 0061 0061 0060 0060 0060 Data '<'
- Less than ##% Data, 'P' - Power Fail, 'D' - Disabled, 'l' - Out-of-Control, 'F' - Boiler Off-Line, Flags 'B' - Bad Status, 'C' - Calibration, 'M' - Maintenance, 'O' - Anal0g Overrange, 'U' - Analog Underrange, 'A' - Arithmetic Error, '+I
- Maximum, ,_, -Minimum, 'R' - Rate of Change, 'H' - High-High Alarm, 'L' - Low-Low Alarm, 'h' - High Alarm, I l t - Low Alarm, 'J' - High Rate of Change, 'j f - Low Rate of Change, 'V' - DIS #1 Obs, 'W' - DIS #2 Obs, 'X' - DIS #3 Obs, 'Y' - DIS #4 Obs, 'Z' - DIS #5 Obs, 'f' - Floor Exceeded, 'c' - Ceiling Exc.**Cur:r~** Date 09/30/05 Current Time 09:14 Minute Summary Report Environmental Systems Corporation 09/30/05 Logger Id 01 Logger Name : Logger 01 Interval 001M Param 

### co NOX 302 C02 02 TEMP FLOW ACFM FLOW3 FLOW4 Units PPM PPM PPM % '% DEGF DELTAP ACFM SCFM DSCFM Time 

### -------------------------------------------------------------------------------------------------------------- 07:30 0 0 .1 -.04 22.16 310 .16 177439.5 118816 116440 07:31 0 0 .1 -.04 D 310 .16 174629.5 116913 114575 07:32 0 0 . 0 -.04 22.25 310 .16 175618.0 117615 115263 07:33 0 0 .1 17.10 1. 52 310 .16 176545.3 118260 115895 07:34 0 0 .2 19.95 -.08 311 .16 176689.5 118268 115903 07:35 0 0 . 3 19.97 -.02 311 .17 1 7 9135.3 119907 117508 07:36 0 0 .2 D -.03 311 .17 178308.8 119275 116889 07:37 0 0 .2 18.09 -.04 312 .16 176560.9 118033 115672 07:38 0 0 .2 18.09 -.06 311 .16 172849.1 115571 113260 07:39 0 0 1.3 13.41 1. 00 311 .17 178574.2 119399 117011 07:40 0 516 90.5 -.01 .40 312 .17 178544.5 119329 116942 07:41 0 1563 100.3 -.03 .40 312 .17 179243.5 119765 117369 07:42 0 1646 100.3 -.03 .08 312 .17 178634.0 119376 116988 07:43 0 1604 100.3 -.03 -.14 311 .16 175554.3 117399 115051 07:44 0 1581 100.3 -.03 -.17 311 .16 176264.0 117906 115548 07:45 0 1585 100.3 -.03 -.19 311 .16 173212.0 115849 113532 07:46 0 1586 100.3 -.04 -.22 311 .17 178838.9 119647 117254 07:47 104 1571 71.9 -.03 .10 311 .16 176833.3 118327 115960 07:48 834 465 . 9 -.04 .15 311 .16 177003.2 118421 116053 .07:49 864 5 . 5 -.04 .14 312 .17 177826.7 118778 116402 07:50 909 2 . 5 -.04 .11 313 :16 174769.9 116650 114317 07:51 910 2 . 4 -.04 .06 313 .16 176393.0 117738 115383 07:52 891 1 9.9 -.04 .17 312 .17 178527.5 119308 116922 07:53 137 2 88.2 -.04 .48 312 .16 175253.4 117122 114780 07:54 0 2 90.9 -.04 .47 312 .16 176005.9 117595 1152_43 07:55 0 2 92.0 -.04 .47 312 .17 179663.8 120050 117649 07:56 0 2 92.5 -.04 .46 312 .16 176462. 8 117880 115522 07:57 3 2 38.7 -.03 11.45 312 .21 200372.2 133820 131143 07:58 0 0 .2 -.04 12.61 312 .24 211673.9 141394 138566 07:59 0 0 .1 -.04 12.52 312 .16 175867.9 117521 115170 08:00 0 0 .1 -.04 12.52 312 .16 176016.9 117622 115269 08:01 0 0 .2 9.32 3.19 312 .23 204736.0 136779 '1.34043 08:02 0 0 .2 12.69 .42 312 .14 A A A 08:03 0 0 . 3 12.71 .42 312 .16 177099.7 118384 116016 08:04 0 0 .2 12.72 .42 312 .17 180219.4 120426 118017 08:05 0 0 . 9 9.92 .38 312 .16 176932.7 118184 115820 08:06 0 277 84.5 -.01 .14 312 .16 175387.0 117197 114853

### Date: Plant: Location: CALIBRATION ERROR SillAMAR Y 

## S{• j/)-A r Y

## ~**t~**n-t.l VI 

### -J## f}1C),'~**K)~ S-/.~;:_**  Box Truck No: 

# iJox 7

_1900_

COz 

### _20_ 

# co _1000_**Calcul~tion:** 

### Zero 

### Mid High Zero 

### Mid High Zero 

### Mid High Zero Low 

### Mid High Zero 

### Mid High ------------- 0.0 0 

### ALM051231 852.4 ALM067047 1580



### ----------------- 0.0 ALM041765 50.09 ALM014908 91.23



### ------------- 0.0 ALM047694 12.71 

### /2' 7£. 

### ALM006050



### -------------- 0.0 

### D ALM059279 301.6 ALM056638 603.8 ALM030705 903.3 

# 9/o. c)



### ----------------- 0.0

AAL9140 12.5 Jz.

### ...)-z.. ALM022336 22.51 7__

## z. l.f' 

### CalGasValue -AnalyzerResponse xl00 Span 

### (Must be ::::; ±2%) (j•O 

## (). (5

- e>, $I

a' t

### .s....

- o, 

## o.s**o.o~-**



### I.L16 -D.(, 

### 7 

### l. 6'--lCu: Date 09/30/05 CUl. Time 09:56 Minute Summary Report Environmental Systems Corporation 09/30/05 Logger Id 01 Logger Name : Logger 01 Interval 001M Param 

### co NOX S02 C02 02 TEMP FLOW ACFM FLOW3 FLOW4 Units PPM PPM PPM % % DEGF DELTAP ACFM SCFM DSCFM Time 

## -------------------------------------------------------------------------------------------------------------- 08:56 21 304 5.2 .01 12.49 315 .19 188971.6 125757 123242 08:57 0 38 4.4 .00 12.50 315 .18 187598.4 124882 122384 08:58 0 24 3.9

## ~

# ~ 313 .18 185907.4 124121 121638 08:59 0 18

# ~ I. 94 3 315 .18 185496.6 123413 120944 09:00 

### (§2 16 12.52 .39 315 .17 182455.0 121414 118985 09:01 0 15 8.9 12.63 .00 315 .18 186028.6 123787 121311 09:02 0 13 8.4 12.65 . 00 315 .18 185085.0 123151 120688 09:03 0 11 8.0

### ~

# ~ 315 .17 180818.0 120328 117922 09:04 0 61 23.0 2.06 315 .19 190868.4 126989 124449 09:05 0 684 40.9 .01 .05 315 .18 186688.9 124240 121756 09:06 0 824 41.1 .00 .05 315 .17 182664.1 121615 119183 09:07 0 835 41.3 -.01 . 05 315 .18 184447.7 122770 120315 09:08 0 839 40.9 -.02 . 05 315 .18 183434.5 122085 11964.3 09:09 0 850 40.8 -.02 . 05 315 .18 183624.3 122185 119741 09:10 0 854 40.8 -.02 .05 315 .18 183583.7 122161 119718 09:11 43 

### (]]]_:) 27.6 -.02 . 03 315 .18 183366.5 122014 119574 09:12 551 244 5.5

### ~ . 02 316 .18 186902.0 124318 121832 09:13 587 14 5.3 -.03 . 02 316 .18 185651.1 123490 121020 09:14 585 9 5.2 -.03 . 02 316 .17 182578.3 121303 118877 09:15 590 7 5.0 -.03 . 02 316 .18 186027.0 123598 121126 09:16 603 6 4.8 -.03 . 02 315 .19 188731.9 125565 123054 09:17 607 6 4.7 -.03 .02 316 .18 185234.0 123168 120704 09:18 

### (§QD 5 4.6 -.03 .02 317 .19 190980.8 126820 124283 09:19 459 4 22.3 -.03 . 02 318 .19 189680.8 125842 123325 09:20 11 4 49.6 -.03 .01 317 .19 190903.5 126682 124148 09:21 1 4 51.4 -.03 .01 317 .19 188903.3 125405 122897 09:22 1 

## CD**~** 1. 69 2.43 311 .18 187122.0 125126 122623 Max 607 854 51.9 12.65 12.50 318 .19 190980.8 126989 124449 Min 0 4 3.5 -.03**-~-~** . 00 311 .17 180818.0 120328 117922 Mean 172 242 20.6 2.06 1. 88 315 .18 186064.9 123786 121310 Recs 0027 0027 0027 0027 0027 0027 0027 0027 0027 0027 Data '<'
- Less than ##% Data, 'P' - Power Fail, 'D' - Disabled, 'T' - Out-of-Control, 'F' - Boiler Off-Line, Flags 'B' - Bad Status, 'C' - Calibration, 'M' - Maintenance, '0' - Analog Overrange, 'U' - Analog Underrange, 'A' - Arithmetic Error, '+' - Maximum, ,_, - Minimum, 'R' - Rate of Change, 'H' - High-High Alarm, 'L' - Low-Low Alarm, 'h' - High Alarm, '1' - Low Alarm, 'J' - High Rate of Change, 1j'
- Low Rate of Change, 'V' - DIS #1 Obs, 'W' - DIS #2 Obs, 'X'
- DIS #3 Obs, 'Y' - DIS #4 Obs, 'Z' - DIS #5 Obs, 'f' - Floor Exceeded, 'c' - Ceiling Exc.Date: Plant: Location: Box Truck No:

_1900_



# co _lQ.QQ_

Calculation: Zero Mid Zero Mid Zero Mid Zero Mid Zero Mid CALIBRATION ERROR SUMMARY

0.0 ALM051231 852.4



### -·--------------- 0.0 

## g,_) ALM041765 50.09 S/·7



### ------------- 0.0 

### -o· 6 1 ALM047694 12.71 

### /2. f;...J 0.0 ALM056638 603.8 0.0 AAL9140 12.5 

# 12 . ..)
CalGasValue -AnalyzerResponse xl00 Span (Must be :-s; ±2%) - 0 1 2.) 

### 2,o



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### ,**o.J~** 

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### O.o

### Date: Plant: Location: Box Truck No:



### _1900_



# co _1000_

Calculation: CALIBRATION ERROR SUMMARY

# St~**~l( dQ;~**  

# q)

# 1\~o-v_**~ ~(J(_-~** **)~v--l_**

Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

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# 1

0.0 

## I**~~3S** ALM051231 852.4 ?,j) 

### 0.0 

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### ALM047694 12.71 

### I "l .**-~/** 

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# z;; ( 0.0 

### 0.() AAL9140 12.5 i ,, . ...-- 

### CalGasValue-AnalyzerResponse xl

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### ±2%) 

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# ). (s 1. . 

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## 7.'6"? 0·0

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### CALIBRATION ERROR SUMMARY Date: 

## 2_ 0 

## CT c) 

## c;--- Plant: Location: 

# --· Box Truck No:

# li&ll**iilt~llillll\lliii~lllli'':t!ll1~li!IIIILtfii** NOx Zero ------------- 0.0 

## f '1, 

# c_/ I() 

### _1900_ Mid ALM051231 852.4

## f3**~ !tJs:-~**  so2 Zero

100 Mid 

### C02 Zero _20_ Mid


### co Zero __lQQQ_ Mid 

### 02 Zero _25_ Mid
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## ~~5--- 

# I ()'··· 

### ALM041765 50.09 

## 5"32/5Zt9**~B.** 

### I

## vv**tV~**



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## 0 ALM047694 12.71 

## tJ_, 

## 7

-------------- 0.0 

## O.u ?J ALM056638 603.8

### l3~

----------------- 0.0 

### () AAL9140 12.5 

# /2,84.) CalGasValue -AnalyzerResponse x1 

### 00 Span (Must be**~** 

### ±2%) .,,l·Date: Plant: Location: Box Truck No:

..:::**:·:~:** ;. 

# ·if . _1900_



# co _1000_ 

### Oz _25_
Calculation: CALIBRATION ERROR SUMMARY 

# l

# ~ ( 31 o--f

Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mio Zero 

### Mid ····-:: 

### ...

. :•

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# m!ii~ 

# ·-····-· 0.0 ALM051231 852.4 0.0 ALM041765 50.09 

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# s 0.0 0. (; 0 

### ALM047694 12.71



### -------------- 0.0 () t 

## (-1'5:> ALM056638 603.8 

## ,CoO?

----------------- 0.0 

### 0. <-- 

### AAL9140 12.5**12-~** CalGasValue -AnalyzerResponse 

### xl00 Span (Must be**~** ±2%) iL.;:i::::O:.>:: •• ·•• ·

## [:::~~-§~

# .•••.CALIBRATION ERROR SUMMARY Date: Plant: 

# s:r JV\-t(l\S 

# CrfJ"-(N'TLocation:

# _u-----~-rx'-\"-o-~----- Box Truck No: 

# 7

----------------
_1900_



# co _1000_ Mid Zero 

### Mid Zero 

### Mid Zero Mid Zero 

### Mid 

### ALM051231
ALM041765
ALM047694

ALM056638

AAL9140 852.4 0.0 

## -I. ( 50.09

0.0 12.71 

## {2·7

0.0 603.8

0.0 

## 0.0 12.5


### Calculation: CalGasValue -AnalyzerResponse 

### xl00 Span · (Must be ::;; ±2%)

### Date: Plant: 

## s-1- /lf\. Location: 

# De }e-o·

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### n:::::::: a•

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## ---



# co _1000_

Calculation: Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid CALIBRATION ERROR SUMMARY



### 0.0 

# r& ALM051231 852.4 0.0 

## 0. 1 ALM041765 50.09 0.0 ALM047694 12.71 I 

## _.2 ".61 0.0 ALM056638 603.8 0.0 AAL9140 12.5 

### 11.

## .t.~B CalGasValue -AnalyzerResponse x

### 1 00 

## Span (Must be :s; 

### ±2%)

### Date: Plant: Location: 

### Box Truck No: CALIBRATION ERROR SUMMARY 

# to 0 

# c**-,~'J ~,--** 

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# r lf\ 

# 412_ 

# y 5 C'&t/Vl€/t/ 

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# .••..**:jj._f!~~i§p~~·:··** _1900_ 

## so2 _100_

### f.~.

# 9tv/ COz.



# co _1000_

_25_
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### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid 0.0 

## dO, A ALM051231 852.4 

## § 

# c:; 

# ex?/ fs-**----------~------** 

### 0.0

## 3.~/ ALM041765 50.09 

## 5G!.

# ~I**51-~t,** 0.0 

# 0 ALM047694 12.71 0.0 ALM056638 603.8 0.0 AAL9140 12.5 CalGasValue -AnalyzerResponse x

### 1 00 Span (Must be s;; 

### ±2%)

## ~**<.~**

### Date: Plant: Location: Box Truck No:



### _1900_ 

### SOz _100_ 

### COz 

## _m_ 

# co _1000_
_25_
Calculation: CALIBRATION ERROR SUMMARY 

# Jo[s(oS' ) 

# S1- tv\A(, .' )

Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid ..... ·.·.·.· .. ·.:··,·.·:-·:· 

### 0.0 ALM051231 852.4 0.0 

## Li,c ALM041765 50.09 

# tf8.7 0.0 

### -0,0} ALM047694 12.71

### /L.~ 0.0 

## () ALM056638 603.8 

# ;·crL 0.0 

### 0 

# .'-!7 AAL9140 12.5 

### 1

# 3. oq CalGasValue -AnalyzerResponse xl00 Span (Must be**~** 

### ±2%) ,'·

### Date: Plant: Location: Box Truck No:

Zero 

### _1900_ Mid 100 Mid



# co _j_QQQ_



### Calculation: Zero 

### Mid Zero 

### Mid Zero 

### Mid 

# 1CALIBRATION ERROR SUl\!IMARY



### 0.0 ALM051231 

# /577 J67/**-------~---------** 

### 0.0 

# (, 7 ALM041765 50.09 

## )o,**~** 

### 0.0 

# D ALM047694 12.71 0.0 ALM056638 603.8 

# I.SZ3S/t.vs0.0 AAL9140 12.5

# /l?/;2,~ CalGasValue -AnalyzerResponse x1 00 Span 

### (Must be ::::; ±2%) { -_.>·

### Date: Plant: Location: Box Truck No:



# co _1000_

_25_


### Calculation: . _)( y -:., v



# . I

Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid CALIBRATION ERROR SUMMARY

0.0 

## J( ALM051231 -&52 4_**~ ~jS~**  

# 1570 0.0

### I.~ ALM041765 50.09

### ~l. 

## Co
.; 

### 0.0 

# o,.,oo ALM047694 12.71

### I?_J.~

## 7 0.0 ALM056638 603.8 0.0 

# - o. ()<._ 

### AAL9140 12.5 

### I

## L I**··~** 

### CalGasValue -AnalyzerResponse xl00 £. 

### Span
'• '··:· 

### (Must be :::; ±2%) 

### I · ·**.~** 

### ' I\ !. \ ..... \ J ' \**~· ~** 

### Date: Plant: Location: Box TruckNo:



## co _1000_

Calculation: CALIBRATION ERROR SUMMARY**~·---·-·.** •, 

### · /r**X(~)\f'**



### Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid 0.0 

# 33 ALM051231 

# I**~6** 

## '1 /)/'] 0.0 [.f.o 

### ALM041765 50.09 

# 5LO 0.0**-El~OJ** 

### ALM047694 12.71 

## /2.1] 0.0 

# 0.0 ALM056638 603.8 

## i]Cf

# J 0.0 

# -o.3 AAL9l40 12.5 

## )2_. 

## lf_B_ CalGasValue -AnalyzerResponse xl

### 00 Span (Must be**~** 

### ±2%) -:"

# !if: 3 

# I

Date: Plant: Location: 

### Box Truck No:



### ..

# ···~iH ······•_. 

### NOx _1900_

C02

### ~- 

# co _1000_

Calculation: 

### CALIBRATION ERROR SUM1\1ARY

# I~ 

# /1-z 16c;-

Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid 0.0 ALM051231 -852.4-"

## /~79 

# /51)5 0.0 ALM041765 50.09 0.0 

# 6 '(')() ALM047694 12.71 0.0 () () 

### ALM056638 603.8 0.0 AAL9140**\.)2.~** 

## /Z'.l CalGasValue -AnalyzerResponse 

### xl00 Span (Must be ::;; 

### ±2%) ,•

# .;n:il !2,_,

## :;c __**;~;: ~0** 

CALIBRATION ERROR SUMMARY Date: 

# /0/ f3)

# OS (/ Plant: 

# 8r 'f'1AJ2.-i 

## S Location: 

# =b I 

## X (J-.,) BoxTruckNo:

# ------~r-----------
0.0 

# 2t.f
I 

### _1900_ 

### Mid ALM051231 852.4-

### /~7C7

## {r;'-1~ Zero 0.0 

# 6,2 Mid ALM041765 50.09 

## ..J.Y.t>

# lo.tr> Zero 0.0 

# o.oa Mid ALM047694 12.71 

## l 2 ,(o 

# I Zero 0.0 

### Mid ALM056638 603.8 Zero 0.0 _25_ 

### Mid AAL9140 12.5


### Calculation: CalGasValue -AnalyzerResponse xl00 Span (Must be 

## s ±2%) .,

### Date: Plant: Location: Box Truck No:


### NOx _1900_



# co _1000_



### Calculation: CALIBRATION ERROR SUMMARY 

# S-1

# (V'1vi~ t(_

# ~'/**Le_..tAU-~~­**

..\)( ,j ()v-.

### ~] 

# L.**~~:s-v**

Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid**:·--_,·:~:::::::** ·.·. ·:··· ......... .
.. ::: ·.::::·: :.-.:::::::. nnm 

### 0.0 

# ·0 ALM051231 

### {.$9 

# c( 0.0 ALM041765 50.09 { 

### 0.0 

# a.s ALM047694 12.71 0.0

. ALM056638 603.8 0.0 

## 0 AAL9140 12.5 

# 1:?/J

# I
CalGasValue -AnalyzerResponse x100 Span (Must be**~** 

### ±2%)

### CALIBRATION ERROR SUMMARY Date: Plant: Location: Box Truck No: 

# 'I

_1900_ 

### SOz

100



# co _lQillL_



### Calculation: 

## ------------------ ···:::::··::: ::.:::::::::··:·-:·::::::.·:·:·::::::·::::·:·: ::;:·::·

# H<ii:-tio':~}c:i,,:.:···:: -,.:::. • • :····:····· :_•••,_•.•.•...•

# _.:.···-~~{ :····:·:···:···,····:····,········ 

### Zero 0.0 

### Mid ALM051231 1_:) 1'-1 

### Zero 0.0 

### Mid ALM041765 50.09 Zero 0.0 

# ,_ o. 01. 

### Mid ALM047694 12.71 

### 11-.i_f Zero 0.0 

### Mid ALM056638 603.8 Zero 0.0 

### Mid AAL9140 12.5 CalGasValue -AnalyzerResponse x1 

### 00 Span (Must be :::; ±2%) r

### Date: Plant: Location: Box TruckNo:
NOx



### 1900**~-~** 

### SOz _100_ COz 

### _lQ_ 

## co _1000_
Oz 

### _25_


### Calculation: CALIBRATION ERROR SUMMARY 

# /D 

# l!'ifo

# s=: 7

Zero Mid Zero Mid Zero Mid Zero Mid Zero Mid 0.0 

# -1.-zl ALM051231 

### .--252.4- 

# It2'? 

## /-5"71 ... 0.0 

# /.0 ALM041765 50.09 

## t)(9,:v

------------- 0.0**/)~()** 

### ALM047694 12.71 

# /2.h

-------------- 0.0

### (J./'Z.~ ALM056638 603.8 

# t5L

----------------- 0.0 

### ().07 AAL9140 12.5 

# lZ.7 CalGasValue -AnalyzerResponse 

### x1 00 Span (Must be ::::: ±2%) 

### 0

## rfc~I>J.,**~)** -.:'".\) .(( '>. )**~~~** '··.I / I Z. ..::;Date: Plant: Location: Box Truck No:



### _1900_



# co _1000_

_25_.
Calculation: CALIBRATION ERROR SUMMARY 

## 12: (){) 

# Dl X()\-'\ ..

# TIZero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid 0.0 ALM051231**~** 

## /51'1 14CJq 0.0 

### 0 ALM041765**~** 

# 79., .;;-· !.j;;L,23



### 0.0 

## C> ALM047694 12.71 

# q_,**5~-** 0.0 ALM056638 603.8 0.0 AAL9140 12.5 

# I2·**~2..** CalGasValue -AnalyzerResponse 

### xl00 Span. (Must be ::::; ±2%)

## 'v~~ 3 .I't1 "- 

### Cj



## 2 t ) ve? 

### ,a, '-1.Date: Plant: Location:**~)** .. -\ LV



### Box Truck No: CALIBRATION ERROR SUMMARY /); .. 

### / \.._A...j 

# as

'''''i''''''''"l'''''''''''''"''''ll':'':'''''''' :**i:ii!~jb_:_.~_b_** .•

### ~ .•

### ~.''_:_h_::_:_t_•~_:.:_ - ,: 

# tiT::F : 

# a'' '**~m:**

# :::: '. : :::::**::::::':~** 

# ::::::: :::;''}' :**;}'~**

# ;: ' -

.•:·_.,·,•,:•_-_:_._:.,:_._D_,_-,·,·,·:·_:,.,iffi_._._,_ •. :_.' __ .,.:_·_, •. _ •.

### _._·-~,·-·-·-'_._,t_•,·,:,:_~,:_: __ ' __ •.

### ,._ll_,•_-,:_._._._-_c_'_,:_.,·,~,'.:·_'._: __

### -_:._.,l,!A,'_._:.·,:,._.,·_•.:~,•.·,••-•-'_:_ .•. _._ I_::_'

•• : .•. ·_;_, •.

## "_,·'_.:.~

__ ,·• .

## _~'_._._~,-.',··.n',·_,',•_=,y,-.',··_"'',._ .•=,:_z,•_ .•

## -~_,,_' __

## ,··s~.=,·_:_.•.r,·:_:_n_:_:,•.•_•_,··a·:,._,•,-_•,-_nY,·_._•.•.=,·_:,.,,._,n __ ,•.• __ ,·• __ ,·':·,·.F __ , .. _._.')

## ~=.-.-._: __,_•.-

.•_ ••

## _.,•.••·-·-·-·~--··••_l_':_z_x_._·.'a'Jt''~_···,•·-~-,-=·_,,T, __ • ..

## :u~r_.mJi•_•i._._,,L_ •• _._.r::_=_::_,_••:::• :: 

### :::'?:''::;;;;;;;::.,::•,::::..:::::::':,.::::::::::....: .. ,,, .. u

### ~, ••

### •:•··~~tt~~~

# .,_,.,**,,,,R~~,,,,,,}~,,,,,,,,u~,,,,.,,;, ~~~'·!t~!i![}'•-~~~~l~Pii~,--**  

# : .•**:~:9~§e~ni** 

## i:'F NOx 

### _1900_ 

### SOz _100_ 

### COz _20_ 

# co _1000_

_25_
Calculation: Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid 0.0 ALM051231 

### 852.4- 0.0 ALM041765 -S0.09 

# iz. c3

0.0 ALM047694 12.71 0.0 ALM056638 603.8 0.0 

### 0.<--J! AAL9140 12.5 CalGasValue --'AnalyzerResponse xi

### 00 Span (Must be**~** ±2%) I

ICALIBRATION ERROR SUM:MARY 

### Date: Plant: 

# 5/vl( Location: Box Truck No:

# _:]--------~-------- 

# •. ··,:::;·······.·····



## . . ri}Bf[ •.••• NOx 

### _1900_



# co __j_QQQ_

Calculation: Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid 0.0 ALM051231 ----&52.4 

### 0.0


### - CJ 

## ._8 ALM041765 _;)Q,09- 

### 0.0 ALM047694 12.71 0.0 

# O.c ALM056638 603.8 0.0 Q. 0 '-



### . AAL9140 12.5 CalGasValue -AnalyzerResponse x1 00 Span (Must be :s; 

### ±2%)-----------------



### CALIBRATION ERROR SUMMARY Date: 

# to(z2f6'5' Plant: Location: Box Truck No:

..... :·:·::·· :······.


# so2

100



## co 1000

_25_


### Calculation: v 

# l

Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero Mid Zero 

### Mid ·,·.-·:.. : .. 

# • 0.0 

# 2o ALM051231 

### -852.4 

## J)}'l

-

### ~-(~{1JJ~-----**1~71** I 

### 0.0 

### -'1-..- L 

### ALM041765 50.09' 

# Of2.6 9Z- 'L

## J 7 

### 0.0 

### -O.Gl ALM047694 12.71 

## £2,:51 0.0 ALM056638 603.8 

## CoOl 0.0 

### 0.03 AAL9140 12.5 CalGasValue -AnalyzerResponse 

### x1 

### 00 Span (Must be :s; 

### ±2%) .,_'-·-------



### Date: Plant: Location: Box Truck No:

NOx 

### 1900 

# so2

100



# co ____lQQQ_

25

--- 

### Calculation: CALIBRATION ERROR SUMJ\1ARY 

# s t- 

## MM '1/

## s- 

# ct::**t-i-,;;~;t(** 

# r**/~(X-~** 

# J:'L

Zero Mid 

### Zero Mid 

### Zero Mid 

### Zero Mid Zero Mid 

### 0.0 ALM051231
ALM041765 

# 7.2. 2 

## J 0.0 ALM047694 12.71 0.0 

# 0 ALM056638 603.8 0.0 AAL9140 12.5 CalGasValue -AnalyzerResponse xl00 Span (Must be :::;; ±2%) .,,'··
I 'CALIBRATION ERROR SUMMARY Date: 

## f

# 6(2 

# '-{{o-r: Plant: Location: BoxTruckNo:

# ---~~-------------

# j!ll~~·~~ .!

# iJ~!II-IIIlil~,~~~~ <

# llili~l ,]j:

SOz



### 100 COz 

### _20_ 

# co _j_QQQ_


### _25_
Calculation: Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid 0.0 ALM051231 852.-4 

## /57 

# '1 0.0 0.2..- 

### ALM041765**~Q9-** 

### 0.0 -0 d( 

### ALM047694 12.71 0.0 

## \ ALM056638 603.8 0.0 AAL9140 12.5 CalGasValue -AnalyzerResponse 

### xl00 

### Span (Must be:<:;; ±2%) f

ICALIBRATION ERROR SUMMARY Date: _/_() A'---z-"'---s--l-1

# o-'---'5"'------- Plant:

# ---'''--"'S_:_M--.::::~"-------- Location:

# -JOrL/-P-(..LLy~-z:yJ-=------- Box Truck No:

# ~·7**--~--------**



### SOz

100 

### COz _]Q_ 

# co**~1000_**


### _25_ Zero Mid 

### Zero Mid 

### Zero Mid 

### Zero Mid Zero Mid 

### 0.0 ALM051231 -&52.4 

### JL(

# 1 b 0.0 ALM041765 .....,.--j(J:09- 

# 1z... l-3 0.0 ALM047694 12.71 0.0 ALM056638 603.8 0.0 AAL9140 

## I 

## '1 /5/t 

# s-.8**d~.** 

## 3 

# o.o ) J.o'{

Calculation: CalGasValue -AnalyzerResponse x

### 100 Span (Must be::;; ±2%) l c. 

### 5 .4<**,_,.~--** 

# , rl.e**-~·evo**



## v· .e. ),l ..""'v-.. I

(

### Date: Plant: Location: Box Truck No:


### NOx 1900 :.;::.:<:



# co _1000_

_25_


### Calculation: 

### CALIBRATION ERROR SUMJ\1ARY 

# I I 

# t 0**Z~(u)"'**

· .. :.: .: : : .··. :::)·**(~:·i**.. : .....·.>. 

### Zero 

### Mid Zero 

### Mid Zero 

### Mid 0 

### Zero 

### Mid Zero Mid 0.0 

## 28 ALM051231 0.0 ALM041765 0.0 .:-- 0, 0 

### ALM047694 12.71 1 7... J b 

### 1 0.0 0 

### ALM056638 603.8 0.0 AAL9140 CalGasValue -AnalyzerResponse x1 00 

### Span (Must be :::-; ±2%) 

# ,

### CALIBRATION ERROR SUMMARY 

### Date: 

# i ()/21 ( () 

# J Plant:

## __,_..(5~/A___,C=----- Location: 

# U (K il 

### AJ Box Truck No: 

# _l_.L._______ _

SOz _100_



# co __j_QQQ_ 

### Zero 

### Mid ALM051231 Zero 

### Mid ALM041765 Zero 

### Mid ALM047694 Zero Mid ALM056638 Zero Mid AAL9140 0.0 

## -2.. 2 

# IIJD 0.0 (::) ,06 

### 12.71 

### /Z 

### ·7t

0.0 

## I 603.8 

## kub

0.0 

## o. z \**~** 

## 2? .(! ?'L-'5( Calculation: CalGasValue -AnalyzerResponse x1 

### 00 Span 

### (Must be**~** 

### ±2%) (e 

### .-e 

### evn**(/.(_C....~** 

# ..**(G!5~v-t** I



## .;e. -:z.e v

### o ;(t**),;t.::-~**......**~t,.** 

# D .) 

# \

. 

### Date: Plant: Location: Box Truck No:

1900



# co 1000

_25_


### Calculation: 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid CALIBRATION ERROR SillvfMARY

ALM051231
ALM041765
ALM047694

ALM056638

AAL9140 0.0

< 

### 58.89**~** 

## Ci''L '1 

## 5 0.0 12.71

0.0 603.8

0.0 

# 14J3

CalGasValue -AnalyzerResponse xl00 

### Span (Must be::::; ±2%) 

## "? t,..

## 1-:::::-~t**~** '"'

## -~t­ <:'_,r-J

l 

### 'Date: Plant: 

# .$0\C Location: Box Truck No:

SOz



### 100 COz 

## __m_ 

# co __j_QQQ_


### _25_
Calculation: 

# It Zero Mid Zero Mid Zero Mid Zero Mid Zero Mid CALIBRATION ERROR SUMMARY



### 0.0**~~** 

### ALM051231 0.0 

## - ().**~** 

### ALM041765 

# lf1- 7 0.0 

### -o.-u'-1 ALM047694 12.71 , l_ •

# _r 0.0 0,}-( 

### ALM056638 603.8

### ~ 

### l2_ 0.0 AAL9140 CalGasValue -AnalyzerResponse xlOO Span (Must be**~** ±2%) .::.:·:::·.:.:".:... :·:.: .·.

r 

## v

e 

## ·::t- c:."**~**
,, t:J "',1)_.,. • - ...... I .J**'~c** 

### Ve.c. /L,r,
IJ**~** -1::t..v\)**v~~)<:!V~** 

### -,

### Date: Plant: 

### Location: Box TruckNo:



### 1900 

### SOz _100_ 

### COz _1Q_ 

# co 1000
_25_
Calculation: CALIBRATION ERROR SUMMARY 

# 5 T Vl-1 

## 14·12 

## (s-**~.e.-._** 

## -f

# v I 

# x_c!l.,.-., 

# I<-
.--·· 

### 1(/.tJo

.· :.:..,:.::.·. 

### Zero 0.0

### ~~ Mid ALM051231 

### 8§2.4- 

# (

ctct r;**~~L'-s** Zero 0.0 0, 

### 2.. Mid ALM041765**~0.09-** 

## CJ2. 23'

## ~:?,4 Zero 0.0 Mid ALM047694 12.71 

# /) s-2 Zero 0.0 

### 0, () Mid ALM056638 603.8 

# ta6 Zero


### ----------------- 0.0 

# 0 Mid AAL9140 

### ....J.2..5-**~},t-!2.** 

### ,22,5! CalGasValue -AnalyzerResponse xl00 Span (Must**be~** 

### ±2%) ,,

..

### ""-Date: Plant: Location: Box TruckNo:



### 1900



# co 1000

Calculation: 

# 1

Zero Mid Zero Mid Zero Mid Zero Mid Zero Mid 

### CALIBRATION ERROR SUMJ\.1ARY

0.0 ALM051231**-~** 

### 0.0 ALM041765 0.0 -6.0\ 

### ALM047694 12.71 0.0 0 

### ALM056638 603.8 0.0 

## 0 AAL9140 CalGasValue -AnalyzerResponse·x1

### 00 Span (Must be 

## s ±2%) 

### I'CALIBRATIONERROR SUMMARY 

### Date: Plant:

## _S-'--_tl__,~"---"-c""'-"_____ _ 

### Location: ]_, ..____,___!

## _~w_.;;__

# ____ _ Box Truck No: 

## I**--~--------** NOx 

### 1900 SOz



### 100 COz _1Q_ 

# co 1000

Calculation: Zero 

### 0.0 Mid ALM051231 -8-52:'4- 

### if'(ry \::, Zero 

### 0.0 Q. '-/ 

### Mid ALM041765**~** 

# 72. ?3 Zero 

### 0.0



### - 6.1JJ5 Mid ALM047694 12.71 

## 1'2--5'3 Zero 

### 0.0 Mid ALM056638 603.8 

## (o04 Zero Mid 

### 0.0 

## o.**~I** 

### AAL9140**~ 27.7~**  

### CalGasValue -AnalyzerResponse xl

### 00 Span 

### (Must be 

## s ±2%) 

## tJo 

## c·r¢d'r J, 

## 4H· •' i..· . . I-------- --------------



### CALIBRATION ERROR SUMMARY Date: 

# :2AloV () 

# s--- Plant: 

# - Location: 

## /II 

# z j 

### BoxTruckNo:

# ---:?4---------~--- 

# l\tlll_l,\illlt111111lllil,ll&\; NOx 

## _J.2illL SOz _100_



# co _j_QQQ_



### _25_
Calculation: I 

### Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero Mid 

### ------------- 0.0 

# d6- ALM051231**.g.;;~** 

### '0 9'1(/



### ----------------- 0.0 

### 0 ALM041765 50.09 0.0 

# 0 ALM047694 12.71 0.0 

## 0 ALM056638 603.8 0.0 AAL9140 CalGasValue -AnalyzerResponse xl00 Span (Must be**~** 

### ±2%)

### CALIBRATION ERROR SUM11ARY 

### Date: 

# l J 

# /3tfv J**~~~. ~----------**  

### Plant: ___,{1-="

## .-'M-~C'-.__________ _ Location:

_ 1 

### _U--i!-'-k,_,O"-"'IV-=----------- Box Truck No: 

# 7

1900 

### SOz

100 

### COz _20_ 

# co 1000

_25_ 

## -----------------
Zero 

### Mid ALM051231 Zero 

### Mid ALM041765 Zero 

### Mid ALM047694 Zero 

### Mid ALM056638 Zero 

### Mid AAL9140 0.0 

## 30 '**~52.4** 

### 0.0 

### o. 

### I**~0.09** 

### 0.0 -. (j ..

### (5] 12.71

0.0 603.8 

## 1)83

0.0 J), ()) '



### · Calculation: 

### CalGasValue -AnalyzerResponse xl

### 00 Span 

### (Must**be~** 

### ±2%) --'I

### CALIBRATION ERROR SillviMARY 

### Dme:

# ~Lyt/~1~~-~~~--------- Plant:

## ~ 

## AA!;;: Location: \[) / ')( 

# <tv-J, Box TruckNo: 

# f**--~--------------** 

# t':'lll :. ·•.•. r:07•• 

### NOx 1900 

### SOz

100 

### COz ___1Q_ 

# co 1000


### Oz _25_
Calculation: Zero ------------- 0.0 

## :2

# .r Mid 

### ALM051231 -%52.4 

# o 3 

# 9' Zero 0.0 ()



### . Mid 

### ALM041765

Zero 

## o.o - 0 _

### o_5 Mid 

### ALM047694 12.71 

### )1.

## lot Zero 0.0 () 

### Mid 

### ALM05663 8 

### 603.8 

## &JZf Zero Mid 

### 0.0 

### 0·02.- AAL9140 .J..2..S- _?___?. 2. 

## J "2?-5"1 

### CalGasValue -AnalyzerResponse xlOO Span (Must be**~** 

### ±2%)**rt~b\.A-** T

### Date: Plant: Location: Box TruckNo: 

### CALIBRATION ERROR SUMJ\1ARY 

# s

# + v'lt1 

# 4-12 

# r5 (r

## ~:v'h FZ /\( 

# T 

# D;x o v'l

..... . . . . . . . · ..·.·-·..··-··· ...... ···-·· ····.·.,..·. ....... ......·.·..·.·.·-·-·..·.·.·.·•·..· ..

# 11111\tr!lflmt~til&t-lrtiiiiii111'11Jal:tl NOx 

## _l2illL SOz _100_ 

### COz _20_ 

# co 1000

_25_


### Calculation: Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid ------------- 0 0 ') '/

. o--" .,?-.... 

### ALM051231**~**



### ----------------- 0.0 /, '- ALM041765 50.09 _-1------+ 

### 0.0 

# v ALM047694 12.71 0.0 ALM056638 603.8 0.0 AAL9140 CalGasValue -AnalyzerResponse xl00 Span (Must be**~** 

### ±2%) ()CALIBRATIONERROR Sillvflv1ARY Date:

## ~A/dll 

## 0**~** Plant: 

### S}7(11 

# vl-t 

# is c**b-v~**

# r;rLocation:

# D.J:A~ BoxTruckNo:

## ~~+--------------- 

# II ····.···:: 

# ,,f(l**~** 

# ..... _1900_ 

### SOz _100_ 

### COz _N_ 

# co _1000_ Zero Mid Zero Mid Zero Mid Zero Mid ' Zero



### Nlid ....·.. :,:,.,::·:':··_:.

. :·: ,.._.,:.::-:::-::'-: :=:::-: 

### ALM051231
ALM041765
ALM047694

ALM05663'8

AAL9140 [l ', 

### L/

# z3

0.0 

# -22**~** 

## ffC/cf (/ 

# fJ**I~** 0.0 

### 0 50.09

0.0 

## {) 12.71

0.0 603.8

0.0 

### ()**~)** 

## 3 "' " . l, or_:...• 

### Calculation: CalGasValue -AnalyzerResponse xlOO Span (Must be**~** 

### ±2%)

### Date: Plant: Location: Box TruckNo:



### SOz

100 

### COz _lQ_ 

# co 1000

_25_
Calculation: CALIBRATION ERROR SUNIMARY 

## t 

# l [ 

# J (

# G~

Mid 

### Zero Mid 

### Zero Mid 

### Zero Mid 

### Zero 

### l\llid 0.0 

# 2_q ALM051231**~** 

## YSO V'{tf-1

0.0 

### O,Lf ALM041765 -5-G:-8§1 

### €fL. L-3, 

### 0.0 

## ....-o_.oc ALM047694 12.71 0.0 

# I ALM056638 603.8 0.0 O_.()J 

### AAL9140 CalGasValue -AnalyzerResponse xl 00 Span 

### (Must be ::; ±2%) .,**~.**

### Date: Plant: Location: 

### Box TruckNo:
NOx



### 1900 

### SOz _100_ 

### COz _20_ 

# co 1000


### Oz _25_


### Calculation: 

# n (>?/o5

Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid Zero 

### Mid CALIBRATIONERROR SUNlMARY



### 0.0 

# :ss ALM051231 852.4 

## 1Cff_ 1 

# x?..</ { 

### 0.0 

## I**~** 

## I ALM041765 ..5.0.,.G9-· 

### 12-13

0.0 

# -o. 0**~** 

### ALM047694 12.71 

# !7.-IPY 0.0 ALM056638 603.8 0.0 0. D\ 

### AAL9140 CalGasValue -AnalyzerResponse x

### 1 00 Span (Must be::;; 

### ±2%) ..,>·

### Date: Plant: Location: CALIBRATION ERROR SUMMARY 

# I 

# I I'!

# oU o 

# s-(tJ!Jc>tl Q 

## 5 - ; 

## 5

# r

# vvrft-12- 

# Y 5**~~Er-t** 

# r V;X t!v\. 

# :r=L. Box Truck No: 

# 7**----~-----------** 

# .·...**c.~m·**

_1900_ 

### SOz _100_ 

### COz _20_ 

# co**~1000_** 

### Zero 

### Nfid Zero 

### Nfid Zero 

### Nfid Zero 

### Nfid Zero 

### Nfid . . . 

## :<

# ,~ .

# :·l!'.:({j

# ~~-~t**rc':iiH-~i.** !} 0.0 

# /7 ALM051231
ALM041765 0.0 

## D ALM047694 12.71 

## ./J. {,j 0.0 

# 0 ALM056638 603.8

## ~ 

## rt-( 0.0 AAL9140 ]'(···· ::::;.(:•.:· 

## ..

.-.

0

J;l,L- 

## 2J,(j_t '.22,')?**b==========k======~========~~====~~~~~==========d** 

### Calculation: 

### CalGasValue -AnalyzerResponse xlOO Span 

### (Must be::::; ±2%)

### CALIBRATION ERROR SUM:MARY Date: 

## I 

## SIA/o U 

## c> .,--- Plant: )( 

## Vl1

# tl-h\: ·('5 

# C fC

# v~1 rr::-Nj--- Location: Box Truck No:



### 1900 

### SOz _100_ Zero 

### Mid Zero 

### Mid Zero 0.0 

## -;:<) ALM051231 852.4 • 

### 0.0**~** 

### ALM041765 -50.09 . 

# 9V. 17_ Cf'l. ( 0.0 () ..•.•..•. ·•. 

### .... . 

## ....... .

COz _20_ 

### Mid ALM047694 12.71 I;:(

# uSZ,. 

# co 1000 

### Oz _25_


### Calculation: Zero 

### Mid Zero 

### Mid 0.0 

## 0 ALM056638 603.8 I 

### 0.0 

### 0 AAL9140 CalGasValue -AnalyzerResponse x

### 1 00 Span (Must be 

### s; ±2%)

### Date: Plant: Location: 

### Box Truck No:
NOx 1900 

### SOz

100



# co 1000

_25_


### Calculation: Zero Mid Zero Mid Zero Mid Zero Mid Zero 

### Ivlid 

### CALlBRATION ERROR SUN.[MARY

ALM051231 0.0 ALM041765 0.0 ALM047694 12.71 

### \ 1 

### 'tiq 0.0 ALM056638 603.8

## -~C27 0.0 

### Q. 0"2 AAL9140 CalGasValue -AnalyzerResponse xl00 Span (Must**be~** 

### ±2%)

### Date: Plant: Location: Box Truck No: ·

1900 SOz



### 100 COz 

### _20_ 

# co _jQQQ_


### _25_
Calculation:**CALffiRATIONERRORS~Y** f ) 

# It 

# Iflq 

## I ('[ 

# r

Zero Mid 

### Zero Mid 

### Zero Mid 

### Zero Mid 

### Zero 

### J\!Iid 0.0 ALM051231 852.4 0.0 ALM041765 0.0 ALM047694 12.71 0.0 ALM056638 603.8 0.0 AAL9140 

### CalGasValue -AnalyzerResponse xlOO 

### Span (Must be:::; 

### ±2%)

### Date: Plant: Location: Box Truck No:

1900 

### SOz

100



# co 1000

_25_


### Calculation: 

### CALIBRATION ERROR SUMNIARY 

# 1tj1-1 (OS'

Mid 

### Zero Mid 

### Zero Mid 

### Zero Mid 

### Zero 

### !viid ALM051231 

### .::852.4 0.0 

# o. I ALM041765 

### 50.09 

## 'rl ') 0.0 ALM047694 12.71 0.0 ALM056638 .603.8-

### ~01l 0.0 AAL9140 

### 12.5 CalGasValue -AnalyzerResponse x1 00 Span (Must be::; 

### ±2%) ' .., ...: .·..;.**..:,:~··.•** -·---'

((_ ) /}n II\ 1 -

### Date: Plant: Location: Box Truck No:

1900



# co**~1000_**



### Calculation: CALIBRATION ERROR SUMNIARY 

# u 

# /z z_/o(-

Zero Mid Zero Mid Zero Mid Zero Mid Zero 

### JVIid 0.0 20 ALM051231 0.0 ALM041765 0.0 ALM047694 12.71 fz_**~;** 

### 0.0 

### 2 ALM056638 0.0 

### 0-Cf7

AAL9140 CalGasValue -AnalyzerResponse 

### xi00 Span (Must be:::; 

### ±2%)

### APPENDIXB ANALYTICAL DATA

### EXAMLPE CALCULATIONS Emission Rate, lblhr 

### Eppm X 

### MW X 

### Fscfm Eib/ 

## =___,__,______ _ /he 

### C where: E1blhr emission rate, lblhour Eppm emission rate, ppm 

### MW molecular weight ofpollutant Fscfm = 

### exhaust gas flow rate, scfm C conversion constant, 6422036 Emission Rate, lblhr
Eib/ E __ l_hhc lb/ - /ton 

### p where: Etb/ton Etblhr p = 

### emission rate, lb/ton clinker = 

### emission rate, lblhour = 

### production rate, tons/hour clinker Percent Reduction

where: R 

### Ec Eb = 

### percent reduction, % = 

### controlled emission rate = 

### baseline emission rate