# Safety Data Sheet

Revision date : 2012/08/06 Page: 1/9

Version: 1.1 (30474365/SDS_GEN_US/EN)



## 1. Product and Company Identification

Company 24 Hour Emergency Response Information

CHEMTREC: 1-800-424-9300



## 2. Hazards Identification

Emergency overview

CAUTION:

Harmful if swallowed.

CONTAINS MATERIAL WHICH MAY CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA. Prolonged exposure may cause serious damage to health. Refer to MSDS Section 7 for Dust Explosion information.

State of matter: solid Colour: white to slightly yellow

Odour: odourless

Potential health effects

Primary routes of exposure: Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases.

Acute toxicity: Virtually nontoxic after a single skin contact. Virtually nontoxic after a single ingestion.

Irritation / corrosion: Not irritating to the skin.

Assessment other acute effects: Based on the available information there is no specific target organ toxicity to be expected after a single

exposure.

Sensitization: Skin sensitizing effects were not observed in animal studies.

Chronic toxicity:

Carcinogenicity: None of the components in this product at concentrations greater than 0.1% are listed by IARC; NTP, OSHA or ACGIH as a carcinogen.

# Safety Data Sheet

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Version: 1.1 (30474365/SDS_GEN_US/EN)

Repeated dose toxicity: The substance may cause damage to the kidney even after repeated ingestion of low
doses, as shown in animal studies. After repeated exposure the prominent effect is local irritation.

Reproductive toxicity: No data available concerning reproduction toxicity.

Teratogenicity: No data available concerning teratogenic effects.

Genotoxicity: The substance was not mutagenic in bacteria. The substance induced chromosomal aberrations in a mamalian cell culture test. The substance was not mutagenic in studies with mammals.

Signs and symptoms of overexposure: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known.

Potential environmental effects

Aquatic toxicity: Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Releases to

the environment are to be avoided.



## 3. Composition / Information on Ingredients

CAS Number Content (W/W) Chemical name Trade Secret 1.0 - 100.0 % Acetophenone derivative



## 4. First-Aid Measures

General advice: Remove contaminated clothing.

If inhaled: If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention.

If on skin: Wash thoroughly with soap and water.

If irritation develops, seek medical attention.

If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open.

Seek medical attention.

If swallowed: Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek medical attention. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions.

Note to physician

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.



## 5. Fire-Fighting Measures

Flash point: Study does not need to be conducted.

# Safety Data Sheet

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Version: 1.1 (30474365/SDS_GEN_US/EN)

Autoignition: not determined
Lower explosion limit: not determined
Upper explosion limit: not determined
Flammability: not highly

flammable (Directive 92/69/EEC, A.10)

Self-ignition temperature: not self-igniting (Directive 92/69/EEC, A.16) not self-igniting

Suitable extinguishing media: dry powder, foam

Unsuitable extinguishing media for safety reasons:

carbon dioxide

Additional information: Avoid whirling up the material/product because of the danger of dust explosion.

Hazards during fire-fighting: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire.

Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.

Further information: Dusty conditions may ignite explosively in the presence of an ignition source causing flash fire.



## 6. Accidental release measures

Personal precautions: Avoid dust formation. Use personal protective clothing.

Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.

Cleanup: Avoid raising dust. For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Contain with dust binding material and dispose of.



## 7. Handling and Storage

Handling

General advice: Breathing must be protected when large quantities are decanted without local exhaust ventilation.

Closed containers should only be opened in well-ventilated areas.

Protection against fire and explosion: Avoid dust formation. Take precautionary measures against static discharges.

Storage

General advice: Keep container tightly closed and dry; store in a cool place.

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Version: 1.1 (30474365/SDS_GEN_US/EN)



## 8. Exposure Controls and Personal Protection

Advice on system design:

Work in well ventilated areas. Do not breathe dust.

Personal protective equipment

Respiratory protection: Wear a NIOSH-certified (or equivalent) respirator with an APF factor of 25, as needed to mitigate exposure.

Hand protection: Chemical resistant protective gloves

Eye protection: Safety glasses with side-shields. Wear face shield if splashing hazard exists.

Body protection: Wear chemical resistant gloves and protective clothing.

General safety and hygiene measures: Wear protective clothing as necessary to minimize contact. Handle in accordance with good industrial hygiene and safety practice. Eye wash fountains and safety showers must be easily accessible.



## 9. Physical and Chemical Properties

Form: powder

Odour: odourless

Colour: white to slightly yellow pH value: not applicable Melting point: 84.3 °C (OECD Guideline 102) Boiling point: 332.7 °C (OECD Guideline 103) Vapour pressure: < 0.016 hPa ( 25 °C) (Directive 92/69/EEC, A.4) Density: 1.195 g/cm3 ( 20 °C) (Directive 92/69/EEC, A.3) Relative density: No data available. Bulk density: approx. 700 kg/m3
Vapour density: The product is a non-volatile solid.
Partitioning coefficient noctanol/water (log Pow): 2.3 (OECD Guideline 117)

Viscosity, dynamic: Study does not need to be conducted.

Particle size:

No data available. Solubility in water: 9.9 mg/l ( 20 °C) Solubility in other solvents: insoluble



## 10. Stability and Reactivity

Conditions to avoid: Avoid light. Avoid electro-static discharge.

Substances to avoid: strong acids, strong bases, strong oxidizing agents

Hazardous reactions: Dust explosion hazard.

Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated.

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Version: 1.1 (30474365/SDS_GEN_US/EN)

Oxidizing properties: not fire-propagating (calculated)



## 11. Toxicological information

Acute toxicity

Information on: Acetophenone derivative Assessment of acute toxicity: Virtually nontoxic after a single skin contact. Virtually nontoxic after a single ingestion.

----------------------------------

Oral: Type of value: LD50 Species: rat Value: > 2,000 mg/kg (OECD Guideline 423) No mortality was observed.

Inhalation: Type of value: LC50

not determined

Dermal: Type of value: LD50 Species: rat Value: > 2,000 mg/kg (OECD Guideline 402) No mortality was observed.

Irritation / corrosion

Information on: Acetophenone derivative Assessment of irritating effects: Not irritating to eyes and skin.

----------------------------------

Skin: Species: rabbit

Result: non-irritant

Method: OECD Guideline 404

Eye: Species: rabbit

Result: non-irritant

Method: OECD Guideline 405

Sensitization

Information on: Acetophenone derivative

Assessment of sensitization: Skin sensitizing effects were not observed in animal studies.

---------------------------------- Mouse Local Lymph Node Assay (LLNA) Species: mouse Result: Non-sensitizing.

Method: OECD Guideline 429

Repeated dose toxicity

Information on: Acetophenone derivative Assessment of repeated dose toxicity: The substance may cause damage to the kidney even after repeated ingestion of low doses, as shown in

animal studies.

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Version: 1.1 (30474365/SDS_GEN_US/EN)

After repeated exposure the prominent effect is local irritation.

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Genetic toxicity

Information on: Acetophenone derivative The substance was not mutagenic in bacteria. The substance induced chromosomal aberrations in a mamalian cell culture test. The substance was not mutagenic in studies with mammals.

----------------------------------

Reproductive toxicity

Information on: Acetophenone derivative No data available concerning reproduction toxicity.

----------------------------------

Development:

Information on: Acetophenone derivative No data available concerning teratogenic effects.

----------------------------------

Aspiration Hazard:

not applicable

Other Information:

Health effects on animals were reported after prolonged exposure.



## 12. Ecological Information

Fish

Acute: OECD 203; ISO 7346; 92/69/EEC, C.1 Brachydanio rerio/LC50 (96 h): 3.5 mg/l

Chronic:

No data available.

Aquatic invertebrates

Acute: OECD Guideline 202, part 1 Daphnia magna/EC50 (48 h): 0.56 mg/l

Chronic:

No data available.

Aquatic plants

Toxicity to aquatic plants: OECD Guideline 201 Algae/EC50 (72 h): > 100 mg/l

Microorganisms

Toxicity to microorganisms: OECD Guideline 209 activated sludge/EC50 (3 h): > 100 mg/l

Degradability / Persistence Biological / Abiological Degradation Test method: OECD 301B; ISO 9439; 92/69/EEC, C.4-C

# Safety Data Sheet

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Version: 1.1 (30474365/SDS_GEN_US/EN)

Degree of elimination: (28 d) Evaluation: Not readily biodegradable.

Hydrolysis Test method: OECD Guideline 111 (abiotic) pH7 Half-life: > 1 a (25 °C)

Bioaccumulation

Bioconcentration factor < 20

Environmental mobility: Transport between environmental compartments: OECD Guideline 121 adsorption/water - soil

KOC: 104 log KOC: 2.02

Other adverse effects:

Do not discharge product into the environment without control.



## 13. Disposal considerations

Waste disposal of substance: Do not discharge into drains/surface waters/groundwater. Dispose of in accordance with national, state and local regulations.

Container disposal: Dispose of in accordance with national, state and local regulations. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers.



## 14. Transport Information

Land transport

USDOT

Not classified as a dangerous good under transport regulations

Sea transport

IMDG

Hazard class: 9 Packing group: III

ID number: UN 3077 Hazard label: 9, EHSM Marine pollutant: YES Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains HYDROXYPHENONE DERIVATIVE)

Air transport

IATA/ICAO

Hazard class: 9 Packing group: III

ID number: UN 3077

# Safety Data Sheet

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Version: 1.1 (30474365/SDS_GEN_US/EN)

Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains HYDROXYPHENONE DERIVATIVE)



## 15. Regulatory Information

Federal Regulations

Registration status:

Chemical TSCA, US released; restriction on quantity / not listed

OSHA hazard category: This material is classified as hazardous under OSHA regulations.;

EPCRA 311/312 (Hazard categories): Chronic;

CERCLA RQ CAS Number Chemical name

1000 LBS 108-88-3 Toluene 100 LBS 95-50-1; 142-82-5 1,2-dichlorobenzene; heptane

State regulations

CA Prop. 65: There are no listed chemicals in this product.



## 16. Other Information

NFPA Hazard codes: Health : 1 Fire: 1 Reactivity: 0 Special: none

HMIS III rating Health: 1¤ Flammability: 1 Physical hazard: 0

NFPA and HMIS use a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the substance possesses essentially no hazard; a rating of four indicates extreme danger. Although similar, the two ratingsystems are intended for different purposes, and use different criteria. The NFPA system was developed to provide an onthe-spot alert to the hazards of a material, and their severity, to emergency responders. The HMIS system was designed to communicate workplace hazard information to employees who handle hazardous chemicals.

We support worldwide Responsible Care® initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products.

MSDS Prepared by:

MSDS Prepared on: 2012/08/06

IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE

RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR

# Safety Data Sheet

Revision date : 2012/08/06 Page: 9/9

Version: 1.1 (30474365/SDS_GEN_US/EN)

IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT

INFRINGING THE INTELLECTUAL PROPERTY RI GHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY

HEREUNDER ARE GIVEN GRATIS AND WE ASSUM E NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING

GIVEN AND ACCEPTED AT YOUR RISK. Due to the merger of all Material Safety Data Sheets have been reassessed on the basis of consolidated information. This may have result ed in changes of the Material Safety Data Sheets. In case you have questions concerning such changes please contact us at the address mentioned in Section I.

END OF DATA SHEET