# APPENDIX VI

MATES III

FINAL REPORT

Summaries for the MATES III Fixed Monitoring Sites

# MATES III Final Report

Appendix VI-1 

# Appendix VI

Summaries for the MATES III Fixed Monitoring Sites

VI-1 Method Detection Limit (MDL) and Data Reportin g

For MATES III, guidance for determination of the Me thod Detection Limit (MDL) and data

reporting was taken from the U. S. EPA’s National A ir Toxics Pilot City Monitoring Program.

The MDL, as defined in 40 CFR Appendix B, Part 136, “Definition and Procedure for

Determination of the Method Detection Limit” was us ed. The MDL is defined as the minimum

concentration of a substance that can be measured a nd reported with 99% confidence that the

analyte concentration is greater than zero and is d etermined from analysis of a sample in a given

sample matrix containing the analyte (EPA, 2001) 1



# The AQMD Laboratory used this MDL determination met hod for the analyses conducted. It

consists of seven replicate analyses of a sample co ntaining the analyte of interest at a level not to

exceed five times the projected MDL. A standard de viation is determined using results of the

analysis. The standard deviation times 3.14 (from the Tables of Student’s t Values at the 99%

confidence level) is the reported MDL.

It was recognized by the Science Advisory Board (EP A, 2001) that just because a value is below

the MDL does not mean the Laboratory has not been a ble to measure a value, but rather the

measurement has less reliability than others above the MDL. From this study, it became the

convention for MATES III to report every value, eve n those below the MDL. These values were

flagged as being below the MDL but above the Limit of Detection (LoD). For analytes that had

concentrations that were below the LoD, no concentr ation is ascertained in the analysis; and the

data are reported as zero.

Particulate metals were measured by X-Ray Fluoresce nce (XRF), which exposes the Teflon

sample filter to X-rays to induce excitation and su bsequent florescence of the metals. For these

measurements the statistical counting error of the detected pulses is calculated. An advantage of

using this technique is that the analytical uncerta inty can be calculated every time an analysis is

performed. The detection level can also be determi ned during the calibration process using

single element thin film calibration standards. Fo r data reporting, the detection level is

substituted for negative or zero values. Negative values appear in some instances because

occasionally, the Teflon filters used for backgroun d subtractions are lower than the sample filter.

An uncertainty value is also reported for each data point.

In calculating the average concentrations, the repo rted analytical values are used. Other

reporting conventions include reporting a value equ al to 1⁄2 the MDL for all values below the

MDL. However, this can lead to potential biases in calculating average values.

To illustrate the effect of using 1⁄2 the MDL compare d to the analysis value, three examples are

presented. The following figures show the frequenc y distributions of reported data for benzene,

1,3-butadiene, and vinyl chloride.

1 

# Reference: Pilot City Air Toxics Measurements Summ ary, EPA454/R-01-003, February 2001

# MATES III Final Report

Appendix VI-2 

# Benzene

0 50 100 150 200 250 300 3500.060.200.340.480.620.750.891.031.171.311.451.591.731.862.002.142.282.422.562.702.842.973.113.253.39MoreCount 

# MDL = 0.1 ppb

Few data < MDL

Little effect of using 1⁄2 MDL

vs. analysis value



# 1,3-Butadiene

0 50 100 150 200 250 300 350 4000.000.040.080.120.160.200.240.290.330.370.410.450.490.530.570.610.650.690.730.780.820.860.900.940.98MoreCount 

# Most data < MDL, substantial non detects

Upward bias using 1⁄2 MDL MDL = 0.2 ppb

# MATES III Final Report

Appendix VI-3 The chart for benzene shows an example where very f ew data are below the MDL, and there is

little effect on the average of using 1⁄2 the MDL for data that are lower than the MDL.

The chart for 1,3 butadiene shows a considerable nu mber of values below the MDL. Here using

1⁄2 the MDL would bias the average upward. This beco mes more of a concern as ambient

concentrations decrease over time as a result of em issions reduction and may give an

inappropriate view of the actual trends in levels.

Vinyl chloride gives an example of a substance wher e very few data are at detectable levels.

Clearly, in this case, using 1⁄2 the MDL would bias t he average high.

Vinyl Chloride

0 500 1000 1500 2000 25000.000.050.100.150.200.250.300.350.400.450.500.550.600.650.700.750.800.850.900.951.00Count 

# Almost all data non detects

Upward bias using 1⁄2 MDL MDL = 0.2 ppb



# The station abbreviations used in the following tab les are listed below.

Station Abbreviation

Anaheim AN

Burbank BU

Central Los Angeles LA

Compton CO

Inland Valley San Bernardino SB

Huntington Park HP

North Long Beach NLB

Pico Rivera PR

Rubidoux RU

West Long Beach WLBMATES IIIFinal ReportAppendix VI-4Table VI-1Ambient Concentrations (ppb) of Carbonyls at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBAcetaldehyde Year 1Avg 1.28 1.96 2.09 1.56 1.79 1.33 1.30 1.68 1.64 1.41MDL = 0.1 SD 0.64 0.88 1.04 0.77 1.05 0.84 0.68 0.71 0.91 0.78N 119 118 119 118 118 112 120 119 117 11395% CI 0.11 0.16 0.19 0.14 0.19 0.16 0.12 0.13 0.16 0.14Max 3.73 5.00 5.22 4.15 4.71 4.00 3.88 3.90 4.134.52Min 0.05 0.10 0.54 0.33 0.24 0.03 0.05 0.37 0.360.21N< LoD 1 0 0 0 0 1 2 0 0 0N = ND 0 0 0 0 0 0 0 0 0 0AcetaldehydeYear 2Avg 1.31 1.95 1.69 1.52 1.98 1.31 1.75 1.43SD 0.64 0.84 0.82 0.94 0.98 0.71 0.87 0.86N 122 121 122 110 120 122 119 12095% CI 0.11 0.15 0.15 0.18 0.18 0.13 0.16 0.15Max 3.06 4.06 4.63 4.67 4.03 3.99 3.78 4.36Min 0.43 0.31 0.08 0.07 0.23 0.31 0.29 0.20N< MDL 0 0 1 1 0 0 0 0N = 0 0 0 0 0 0 0 0 0Acetone Year 1Avg 1.28 1.96 2.09 1.56 1.79 1.33 1.30 1.68 1.64 1.41MDL = 0.1 SD 0.64 0.88 1.04 0.77 1.05 0.84 0.68 0.71 0.91 0.78N 119 118 119 118 118 112 120 119 117 11395% CI 0.11 0.16 0.19 0.14 0.19 0.16 0.12 0.13 0.16 0.14Max 3.73 5.00 5.22 4.15 4.71 4.00 3.88 3.90 4.134.52Min 0.05 0.10 0.54 0.33 0.24 0.03 0.05 0.37 0.360.21N< MDL 1 0 0 0 0 1 2 0 0 0N = 0 0 0 0 0 0 0 0 0 0 0Acetone Year 2Avg 1.31 1.95 1.69 1.52 1.98 1.31 1.75 1.43SD 0.64 0.84 0.82 0.94 0.98 0.71 0.87 0.86N 122 121 122 110 120 122 119 12095% CI 0.11 0.15 0.15 0.18 0.18 0.13 0.16 0.15Max 3.06 4.06 4.63 4.67 4.03 3.99 3.78 4.36Min 0.43 0.31 0.08 0.07 0.23 0.31 0.29 0.20N< MDL 0 0 1 1 0 0 0 0N = 0 0 0 0 0 0 0 0 0MATES IIIFinal ReportAppendix VI-5Table VI-1Ambient Concentrations (ppb) of Organic Gases at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBFormaldehyde Year 1 Avg 2.91 3.73 4.47 3.17 3.39 4.08 3.84 3.49 3.47 3.19MDL = 0.1 SD 1.17 1.40 1.85 1.26 1.94 1.29 1.52 1.28 1.74 1.56N 119 118 119 118 118 83 120 119 117 11395% CI 0.21 0.25 0.33 0.23 0.35 0.28 0.27 0.23 0.31 0.29Max 7.25 6.81 10.11 7.56 8.08 8.49 8.76 6.85 7.8912.81Min 0.88 0.97 1.25 0.80 0.38 1.39 0.57 0.98 0.500.92N< MDL 0 0 0 0 0 0 0 0 0 0N = 0 0 0 0 0 0 0 0 0 0 0Year 2 Avg 2.99 3.84 4.02 2.94 3.81 3.56 3.53 3.36SD 1.29 1.64 1.93 1.56 2.00 1.66 1.73 1.50N 122 121 122 110 120 122 119 12095% CI 0.23 0.29 0.34 0.29 0.36 0.30 0.31 0.27Max 7.74 7.71 10.61 8.43 8.96 11.53 8.17 9.23Min 0.54 0.54 0.00 0.32 0.20 0.76 0.25 0.66N< MDL 0 0 1 0 0 0 0 0N = 0 0 0 1 0 0 0 0 0Methyl Ethyl Ketone Year 1 Avg 0.330.430.410.340.410.310.300.420.400.41MDL = 0.1 SD 0.260.270.240.260.270.240.230.300.240.41N 11911811911811811212011911711395% CI 0.050.050.040.050.050.040.040.050.040.08Max 1.071.201.071.221.061.030.881.321.042.40Min 0.020.030.040.010.000.000.000.000.000.02N< MDL 2173198152312712N = 0 0000151110Year 1Avg 0.210.300.220.230.320.170.310.23SD 0.160.210.110.180.170.120.160.21N 12212112211012012211912095% CI 0.030.040.020.030.030.020.030.04Max 0.971.060.540.950.780.710.731.19Min 0.030.030.000.000.060.010.070.00N< MDL 2992017533628N = 0 00110001MATES IIIFinal ReportAppendix VI-6Table VI-2Ambient Concentrations (ppb) of Organic Gases at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBBenzene Year 1 Avg 0.44 0.73 0.59 0.82 0.49 0.76 0.56 0.57 0.45 0.57MDL = 0.1 SD 0.28 0.42 0.30 0.70 0.24 0.46 0.35 0.32 0.25 0.44N 118 118 117 118 115 98 119 121 114 11495% CI 0.05 0.08 0.05 0.13 0.04 0.09 0.06 0.06 0.05 0.08Max 1.44 2.16 1.83 3.50 1.26 2.20 1.62 1.86 1.231.95Min 0.10 0.25 0.21 0.13 0.07 0.28 0.17 0.14 0.120.08N< MDL 0 0 0 0 2 0 0 0 0 1N = 0 0 0 0 0 0 0 0 0 0 0Year 2 Avg 0.42 0.69 0.57 0.78 0.49 0.48 0.43 0.50SD 0.33 0.44 0.31 0.67 0.24 0.34 0.26 0.38N 115 122 121 118 116 118 120 12095% CI 0.06 0.08 0.06 0.12 0.04 0.06 0.05 0.07Max 2.06 1.85 1.53 3.53 1.24 1.70 1.32 1.77Min 0.11 0.11 0.16 0.17 0.10 0.14 0.10 0.10N< MDL 0 0 0 0 0 0 0 0N = 0 0 0 0 0 0 0 0 01,3 Butadiene Year 1Avg 0.08 0.15 0.12 0.20 0.08 0.17 0.12 0.12 0.08 0.10MDL = 0.2SD 0.07 0.13 0.08 0.22 0.05 0.14 0.10 0.10 0.07 0.12N 118 118 117 118 115 98 119 121 114 11495% CI 0.01 0.02 0.02 0.04 0.01 0.03 0.02 0.02 0.01 0.02Max 0.32 0.56 0.42 1.02 0.24 0.71 0.48 0.49 0.310.50Min 0.00 0.00 0.03 0.00 0.00 0.02 0.02 0.03 0.000.00N< MDL 107 87 96 80 110 67 95 99 107 92N = 0 6 1 0 1 8 0 0 0 8 13Year 2Avg 0.04 0.12 0.09 0.14 0.04 0.07 0.04 0.06SD 0.06 0.13 0.08 0.17 0.04 0.08 0.06 0.09N 115 122 121 118 116 118 120 12095% CI 0.01 0.02 0.01 0.03 0.01 0.01 0.01 0.02Max 0.34 0.62 0.34 0.78 0.22 0.38 0.33 0.44Min 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00N< MDL 111 102 105 88 115 107 114 112N = 0 41 15 15 17 36 21 57 47MATES IIIFinal ReportAppendix VI-7Table VI-2Ambient Concentrations (ppb) of Organic Gases at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBCarbon Tetrachloride Year 1 Avg 0.080.080.080.080.080.080.080.070.070.07MDL = 0.05 SD 0.010.010.010.010.010.010.010.010.010.01N 1181181171181159811912111411495% CI 0.000.000.000.000.000.000.000.000.000.00Max 0.100.100.110.090.120.090.100.090.100.09Min 0.030.030.030.030.030.030.030.030.030.03N< MDL 2312223314N = 0 0000000000Year 2 Avg 0.090.090.090.090.090.090.090.09SD 0.010.010.010.010.010.010.010.01N 11512212111811611812012095% CI 0.000.000.000.000.000.000.000.00Max 0.120.110.110.110.130.110.110.12Min 0.060.060.060.060.060.070.060.06N< MDL 00000000N = 0 00000000Chloroform Year 1 Avg 0.030.050.030.030.030.030.030.040.030.03MDL = 0.1 SD 0.010.020.010.020.010.020.020.020.010.02N 1181181171181159811912111411495% CI 0.000.000.000.000.000.000.000.000.000.00Max 0.070.120.080.100.070.090.090.110.060.09Min 0.010.000.010.000.000.010.010.020.000.00N< MDL 11811411711711598119119114114N = 0 0101500011Year 2 Avg 0.030.050.040.030.030.030.030.03SD 0.010.030.020.020.010.020.010.02N 11512212111811611812012095% CI 0.000.000.000.000.000.000.000.00Max 0.080.130.090.090.070.070.070.07Min 0.000.000.000.000.000.000.000.00N< MDL 115116121118116118120120N = 0 33113251MATES IIIFinal ReportAppendix VI-8Table VI-2Ambient Concentrations (ppb) of Organic Gases at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLB1,2-Dibromoethane Year 1 Avg 0.000.000.000.000.000.000.000.000.000.00MDL = 0.2 SD 0.000.000.000.000.000.000.000.000.000.00N 1181181171181159811912111411495% CIMax 0.000.000.000.000.000.000.000.000.000.00Min 0.000.000.000.000.000.000.000.000.000.00N< MDL 11811811711811598119121114114N = 0 11811811711811598119121114114Year 2 Avg 0.000.000.000.000.000.000.000.00SD 0.000.000.000.000.000.000.000.00N 11512212111811611812012095% CI #NUM! 0.00#NUM! #NUM! #NUM! #NUM! #NUM! 0.00Max 0.000.030.000.000.000.000.000.02Min 0.000.000.000.000.000.000.000.00N< MDL 115122121118116118120120N = 0 1151211211181161181201191,2-Dichlorobenzene Year 1 Avg 0.000.000.000.000.000.000.000.000.000.00MDL = 0.3 SD 0.000.000.000.000.000.000.000.000.000.00N 1181181171181159811912111411495% CI 0.000.000.000.00Max 0.020.020.010.000.000.030.000.000.000.00Min 0.000.000.000.000.000.000.000.000.000.00N< MDL 11811811711811598119121114114N = 0 11711711611811594119121114114Year 2 Avg 0.000.000.000.010.000.000.000.00SD 0.010.010.010.020.000.010.000.01N 11512212111811611812012095% CI 0.000.000.000.000.000.000.000.00Max 0.070.070.070.220.030.070.030.06Min 0.000.000.000.000.000.000.000.00N< MDL 115122121117116118120120N = 0 110117115107111114115113MATES IIIFinal ReportAppendix VI-9Table VI-2Ambient Concentrations (ppb) of Organic Gases at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLB1,4-Dichlorobenzene Year 1 Avg 0.040.050.050.090.030.080.030.050.060.03MDL = 0.3 SD 0.020.030.030.080.020.050.030.040.050.03N 1181181171181159811912111411495% CI 0.000.010.000.010.000.010.000.010.010.01Max 0.130.180.170.420.100.320.120.260.260.16Min 0.000.000.010.010.000.020.000.000.000.00N< MDL 11811811711411597119121114114N = 0 610016092626Year 2 Avg 0.010.030.030.050.020.010.020.01SD 0.020.020.020.050.010.020.020.02N 11512212111811611812012095% CI 0.000.000.000.010.000.000.000.00Max 0.090.080.090.240.050.080.110.08Min 0.000.000.000.000.000.000.000.00N< MDL 115122121118116118120120N = 0 50232213365140581,2-Dichloroethane Year 1 Avg 0.000.000.000.000.000.000.000.000.000.00MDL = 0.1 SD 0.000.000.000.000.000.000.000.000.000.00N 1181181171181159811912111411495% CI #NUM! 0.00#NUM! 0.00#NUM! 0.000.00#NUM! #NUM! #NUM!Max 0.000.030.000.030.000.030.020.000.000.00Min 0.000.000.000.000.000.000.000.000.000.00N< MDL 11811811711811598119121114114N = 0 11811711711711595117121114114Year 2 Avg 0.000.000.000.000.000.000.000.00SD 0.000.000.000.000.000.000.000.00N 11512212111811611812012095% CI ! 0.00! ! 0.000.000.000.00Max 0.000.020.000.000.020.030.020.03Min 0.000.000.000.000.000.000.000.00N< MDL 115122121118116118120120N = 0 115121121118115115118118MATES IIIFinal ReportAppendix VI-10Table VI-2Ambient Concentrations (ppb) of Organic Gases at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLB1,2-Dichloropropane Year 1 Avg 0.000.000.000.000.000.000.000.000.000.00MDL = 0.2 SD 0.000.000.000.010.000.000.000.000.000.00N 1181181171181159811912111411495% CIMax 0.000.000.000.050.000.000.000.000.000.00Min 0.000.000.000.000.000.000.000.000.000.00N< MDL 11811811711811598119121114114N = 0 11811811711611598119121114114Year 2 Avg 0.000.000.000.000.000.000.000.00SD 0.000.000.000.000.000.000.000.00N 11512212111811611812012095% CI 0.000.000.000.000.00Max 0.020.030.020.020.000.000.000.03Min 0.000.000.000.000.000.000.000.00N< MDL 115122121118116118120120N = 0 114120120117116118120119Ethylbenzene Year 1 Avg 0.200.340.250.400.210.360.220.260.180.27MDL = 0.1 SD 0.160.220.140.370.130.250.170.170.120.22N 1181181171181159811912111411495% CI 0.030.040.030.070.020.050.030.030.020.04Max 0.811.160.851.880.691.220.750.930.591.13Min 0.030.100.080.070.020.110.040.070.020.04N< MDL 3106132301892621N = 0 0000000000Year 2 Avg 0.200.350.260.410.220.200.190.22SD 0.190.250.160.370.130.170.140.18N 11512212111811611812012095% CI 0.040.040.030.070.020.030.030.03Max 1.251.060.761.970.550.850.800.97Min 0.030.060.050.090.000.040.020.05N< MDL 40810320363533N = 0 00001000MATES IIIFinal ReportAppendix VI-11Table VI-2Ambient Concentrations (ppb) of Organic Gases at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBMethylene Chloride Year 1 Avg 0.220.350.360.320.180.321.900.290.190.21MDL = 0.1 SD 0.160.210.220.300.110.3411.760.250.110.20N 1181181171181159811912111411495% CI 0.030.040.040.050.020.072.110.050.020.04Max 0.991.151.372.850.592.97109.942.450.581.42Min 0.060.090.100.060.030.070.050.070.030.04N< MDL 69351944734668457874N = 0 0000000000Year 2 Avg 0.240.340.370.360.180.190.330.19SD 0.170.330.210.940.090.130.180.16N 11512212111811611812012095% CI 0.030.060.040.170.020.020.030.03Max 0.962.811.3010.250.480.690.911.08Min 0.040.030.070.050.000.040.060.00N< MDL 6241295566753383N = 0 00001001MATES IIIFinal ReportAppendix VI-12Table VI-2Ambient Concentrations (ppb) of Organic Gases at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBMethyl t-Butyl Ether Year 1 Avg 0.000.050.010.010.010.010.010.000.010.01MDL = 0.3 SD 0.010.340.010.020.020.020.010.010.010.02N 1181181171181159811912111411495% CI 0.000.060.000.000.000.000.000.000.000.00Max 0.073.350.070.090.110.070.050.060.070.13Min 0.000.000.000.000.000.000.000.000.000.00N< MDL 11811411711811398119121114113N = 0 1008691909085971009189Year 2 Avg 0.000.000.000.010.000.000.000.01SD 0.010.010.010.020.010.010.010.03N 11512212111811611812012095% CI 0.000.000.000.000.000.000.000.00Max 0.050.060.040.070.060.100.050.17Min 0.000.000.000.000.000.000.000.00N< MDL 115122121118116117120117N = 0 10711011010310210511195Perchloroethylene Year 1 Avg 0.050.110.060.140.040.090.040.060.030.04MDL = 0.1 SD 0.050.080.040.150.030.080.040.040.030.04N 1181181171181159811912111411495% CI 0.010.010.010.030.010.020.010.010.000.01Max 0.430.540.211.210.170.500.220.220.150.18Min 0.000.020.000.000.000.010.000.000.000.00N< MDL 101731056511071109105111105N = 0 7011701411524Year 2 Avg 0.050.090.050.110.050.040.030.04SD 0.060.090.040.130.030.040.020.04N 11512212111811611812012095% CI 0.010.020.010.020.010.010.000.01Max 0.460.790.200.910.160.190.110.19Min 0.000.000.000.000.000.000.000.00N< MDL 1028510178108108118111N = 0 167649242528MATES IIIFinal ReportAppendix VI-13Table VI-2Ambient Concentrations (ppb) of Organic Gases at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBStyrene Year 1 Avg 0.410.080.050.130.080.070.090.070.080.30MDL = 0.1 SD 0.750.110.040.130.070.050.100.050.070.33N 1181181171181159811912111411495% CI 0.130.020.010.020.010.010.020.010.010.06Max 3.220.810.200.900.370.270.430.270.421.41Min 0.000.000.000.010.000.020.000.010.000.00N< MDL 739110564837183958440N = 0 3430603054Year 2 Avg 0.290.100.060.180.070.100.080.32SD 0.700.140.080.220.070.160.110.50N 11512212111811611812012095% CI 0.130.020.010.040.010.030.020.09Max 3.780.600.411.330.390.780.623.69Min 0.000.000.000.010.000.000.000.00N< MDL 7688926385869147N = 0 463938019391414Toluene Year 1 Avg 1.552.681.842.891.732.871.601.971.531.98MDL = 0.1 SD 1.171.620.982.591.031.811.131.320.911.72N 1181181171181159811912111411495% CI 0.210.290.180.470.190.360.200.240.170.31Max 5.678.946.1113.195.558.685.457.014.068.44Min 0.260.830.600.470.140.970.330.530.210.10N< MDL 0000000000N = 0 0000000000Year 2 Avg 1.452.491.802.721.691.401.491.56SD 1.321.681.062.410.911.100.951.29N 11512212111811611812012095% CI 0.240.300.190.440.170.200.170.23Max 8.427.085.5012.654.485.585.506.69Min 0.330.170.350.520.090.280.110.28N< MDL 00001000N = 0 00000000MATES IIIFinal ReportAppendix VI-14Table VI-2Ambient Concentrations (ppb) of Organic Gases at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBTrichloroethylene Year 1 Avg 0.010.030.030.010.010.020.010.020.000.02MDL = 0.1 SD 0.020.030.030.020.020.020.020.030.010.03N 1181181171181159811912111411495% CI 0.000.010.000.000.000.000.000.000.000.00Max 0.090.150.130.110.080.120.090.120.040.13Min 0.000.000.000.000.000.000.000.000.000.00N< MDL 11811311211611597119116114111N = 0 77472767585170539246Year 2 Avg 0.010.020.020.010.010.010.000.01SD 0.020.030.040.020.020.010.010.04N 11512212111811611812012095% CI 0.000.010.010.000.000.000.000.01Max 0.180.130.330.080.070.050.030.36Min 0.000.000.000.000.000.000.000.00N< MDL 113116117118116118120119N = 0 89605078598110777(m+p)-Xylenes Year 1 Avg 0.781.360.971.570.791.440.850.970.680.93MDL = 0.2 SD 0.600.870.541.470.470.960.620.630.440.81N 1181181171181159811912111411495% CI 0.110.160.100.260.090.190.110.110.080.15Max 2.904.913.047.852.404.583.033.782.144.53Min 0.150.380.300.260.060.470.160.290.110.02N< MDL 0000500001N = 0 0000000000Year 2 Avg 0.671.250.911.430.710.680.620.72SD 0.640.890.551.270.400.570.440.62N 11512212111811611812012095% CI 0.120.160.100.230.070.100.080.11Max 4.033.752.486.252.002.922.503.23Min 0.130.220.200.320.040.130.040.15N< MDL 00001010N = 0 00000000MATES IIIFinal ReportAppendix VI-15Table VI-2Ambient Concentrations (ppb) of Organic Gases at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBo-Xylene Year 1 Avg 0.180.320.220.400.180.350.190.220.160.22MDL = 0.2 SD 0.160.240.150.420.120.270.170.160.110.21N 1181181171181159811912111411495% CI 0.030.040.030.080.020.050.030.030.020.04Max 0.751.280.942.260.631.320.830.970.571.21Min 0.030.080.050.050.010.100.020.060.020.03N< MDL 476172129041253840N = 0 0000000000Year 2 Avg 0.190.310.220.380.170.170.150.19SD 0.260.340.200.430.150.200.170.24N 11512212111811611812012095% CI 0.050.060.040.080.030.040.030.04Max 1.691.450.852.200.820.831.101.28Min 0.000.020.020.030.000.010.010.01N< MDL 6239503737626563N = 0 10001000Vinyl Chloride Year 1 Avg 0.000.000.000.000.000.000.000.000.000.00MDL = 0.2 SD 0.000.000.000.010.000.000.000.000.000.00N 1181181171181159811912111411495% CI 0.000.000.00Max 0.000.000.000.050.000.000.020.000.000.02Min 0.000.000.000.000.000.000.000.000.000.00N< MDL 11811811711811598119121114114N = 0 11811811711611598118121114113Year 2 Avg 0.000.000.000.000.000.000.000.00SD 0.000.000.000.000.000.000.000.00N 11512212111811611812011995% CI 0.000.000.000.000.00Max 0.000.020.010.020.020.000.000.03Min 0.000.000.000.000.000.000.000.00N< MDL 115122121118116118120119N = 0 115121120117115118120114MATES IIIFinal ReportAppendix VI-16Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBAluminum Year 1 Avg 2404247526532825482030232341323451473276MDL = 150 SD 1648116611941499288817621268181226832158N 11911011811511411611811811211395% CI 296218215274530321229327497398Max 997868086364773213002137336295149171259112824Min 213213213213255213213375458213N< MDL 0000000000Year 2 Avg 37584221432242446749402889484943SD 22191953178720433646189536312877N 11310811111311011211111495% CI 409368332377681351675528Max 117731312482061065817207116091735614555Min 21310866612132139141193213N< MDL 00000000AntimonyYear 1 Avg 2.53.72.92.42.02.32.12.82.11.9MDL= 2 SD 5.24.13.13.74.92.22.42.44.41.4N 11911011811511411611811811211395% CI 0.90.80.60.70.90.40.40.40.80.3Max 53.720.417.731.953.015.215.211.545.710.8Min 1.41.41.41.41.41.41.41.41.41.4N< MDL 102688797107941057910297year 2 Avg 2.64.03.52.21.72.41.91.9SD 3.24.03.32.11.12.61.31.9N 11310811111311011211111495% CI 0.60.80.60.40.20.50.20.3Max 19.017.814.812.710.016.89.217.2Min 1.41.41.41.41.41.41.41.4N< MDL 93626794968995101MATES IIIFinal ReportAppendix VI-17Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBArsenic Year 1 Avg 0.60.70.80.80.91.00.60.90.81.1MDL = 1 SD 0.50.60.80.70.91.20.61.00.84.8N 119.0110.0118.0115.0114.0116.0118.0118.0112.0113.095% CI 0.10.10.10.10.20.20.10.20.20.9Max 2.33.45.02.77.26.52.75.05.451.7Min 0.20.20.20.20.20.20.20.20.20.2N< MDL 94777679787193787883Year 2 Avg 0.50.70.60.60.80.70.80.7SD 0.40.60.70.80.60.70.70.7N 11310811111311011211111495% CI 0.10.10.10.10.10.10.10.1Max 2.32.74.25.83.14.24.25.0Min 0.20.20.20.20.20.20.20.2N< MDL 10273878974847681Barium Year 1Avg 53.875.785.365.481.881.455.173.776.958.6MDL = 17 SD 51.647.653.846.5169.349.536.142.2117.641.6N 11911011811511411611811811211395% CI 9.38.99.78.531.19.06.57.621.87.7Max 457.5366.5353.3245.91830.5300.0213.7210.11253.9201.1Min 10.011.810.110.010.010.010.015.510.010.0N< MDL 13324717189Year 2 Avg 55.378.192.660.366.655.976.454.1SD 45.444.451.944.036.835.937.544.1N 11310811111311011211111495% CI 8.48.49.78.16.96.77.08.1Max 227.1235.7247.9267.6204.1196.8183.8218.0Min 10.011.510.010.010.012.111.510.0N< MDL 114465262317MATES IIIFinal ReportAppendix VI-18Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBCadmium Year 1Avg 1.52.11.51.61.51.61.51.61.51.6MDL = 2 SD 0.93.60.90.80.80.90.80.90.81.0N 119.0110.0118.0115.0114.0116.0118.0118.0112.0113.095% CI 0.20.70.20.10.10.20.10.20.10.2Max 6.628.15.34.64.45.74.36.55.06.9Min 1.01.01.01.01.01.01.01.01.01.0N< MDL 989297878986103959485Year 2 Avg 1.61.51.51.41.71.61.61.5SD 0.90.80.70.71.80.90.90.8N 11310811111311011211111495% CI 0.20.10.10.10.30.20.20.1Max 4.64.64.13.817.55.44.64.6Min 1.01.01.01.01.01.01.01.0N< MDL 8987919683878791Calcium Year 1Avg 1220126614111298273816871149143650601839MDL = 5SD 8706246876661772115661771139291190N 11911011811511411611811811211395% CI 156117124122325210111128728219Max 575235173259325390751032433083656206147020Min 6919710183233858618536814N< MDL 0000000000Year 2 Avg 11801457152012652676118953721751SD 856848724697160970035081067N 11310811111311011211111495% CI 158160135129301130653196Max 531859153329372169234631161425590Min 137157174381170354135N< MDL 00001000MATES IIIFinal ReportAppendix VI-19Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBChromium Year 1Avg 2444794445MDL = 2SD 22345155338N 11911011811511411611811811211395% CI 0.40.50.50.71.02.70.80.60.51.5Max 15111420228334201578Min 1111111111N< MDL 81412641262268323450Year 2 Avg 24447454SD 23345435N 11310811111311011211111495% CI 0.40.60.50.70.90.70.50.9Max 1220182321171225Min 11111111N< MDL 7739284321502359Hexavalent Year 1Avg 0.140.150.180.250.190.180.160.160.420.19ChromiumSD 0.110.100.110.290.100.160.140.110.550.16MDL = 0.06 N 12111911811611711812012111011295% CI 0.020.020.020.050.020.030.020.020.100.03Max 0.670.50.521.770.520.911.070.693.541Min 0.010.030.020.030.020.030.030.030.010.03N< MDL 3322131661719152223N = 0 0000000000Year 2 Avg 0.140.150.150.250.180.140.380.22SD 0.110.120.110.240.130.100.450.21N 11611712111411211611511995% CI 0.020.020.020.040.020.020.080.04Max 0.680.750.791.670.690.622.191.16Min 0.020.010.020.0300.010.020N< MDL 3123211518251324N = 0 00001002MATES IIIFinal ReportAppendix VI-20Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBCobalt Year 1Avg 3444753454MDL = 1 SD 2222432333N 11911011811511411611811811211395% CI0.40.40.40.40.80.50.40.50.60.6Max 11101111181410171517Min 0.40.40.40.40.40.40.40.40.40.4N< MDL 3279161352271214Year 2 Avg 24435363SD 22224233N 11310811111311011211111495% CI 0.40.40.40.40.70.40.60.5Max 10119131991313Min 0.40.40.40.40.40.40.40.4N< MDL 30121018627520Copper Year 1 Avg 324656386016723353538MDL = 1SD 27263323889516196320N 11911011811511411611811811211395% CI 4.94.96.04.216.217.22.93.411.73.7Max 26519919814295949680101685105Min 3.513.310.39.91.526.23.58.53.53.8N< MDL 0000000000Year 2 Avg 3246563860233538SD 2726332388166320N 11911011811511411811211395% CI 4.94.96.04.216.22.911.73.7Max 26519919814295980685105Min 3.513.310.39.91.53.53.53.8N< MDL 00000000MATES IIIFinal ReportAppendix VI-21Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBIndium Year 1 Avg 2222222222MDL = 2 SD 1111111111N 11911011811511411611811811211395% CI 0.20.20.20.20.20.20.20.20.20.2Max 5657765667Min 1111111111N< MDL 78747974768682758173Year 2 Avg 22222222SD 11111111N 11310811111311011211111495% CI 0.20.20.20.20.20.20.20.2Max 764767610Min 11111111N< MDL 7179788269768578Iron Year 1 Avg 1567179720771774327722241570214328772114MDL = 1 SD 102678095195819631117881107815221448N 11911011811511411611811811211395% CI 184.3145.8171.7175.1360.3203.2158.9194.6282.0267.0Max 5796422848814910846857044724624462829825Min 203179167113277143189365306123N< MDL 0000000000Year 2 Avg 15012020213417313065158832872017SD 98811219461006163686114281272N 11310811111311011211111495% CI 182.2211.4176.1185.5305.7159.4265.7233.4Max 48887567532652567831494675336761Min 206371283600319307220N< MDL 00001000MATES IIIFinal ReportAppendix VI-22Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBLead Year 1Avg 6.910.715.713.017.322.710.014.712.512.0MDL = 5SD 5.56.38.512.116.823.87.39.211.79.3N 11911011811511411611811811211295% CI 1.01.21.52.23.14.31.31.72.21.7Max 38.937.846.575.9146.2156.037.648.489.845.5Min 3.03.03.03.03.03.03.03.03.03.0N< MDL 581611281962972122Year 2 Avg 6.29.814.610.313.98.411.49.4SD 5.85.18.87.88.95.97.57.1N 11310811111311011211111495% CI 1.11.01.61.41.71.11.41.3Max 51.424.454.945.060.631.841.539.1Min 3.03.03.03.03.03.03.03.0N< MDL 6222153415402337Manganese Year 1 Avg 19.020.525.225.261.832.019.427.347.728.8MDL = 1 SD 14.99.512.214.541.120.912.014.927.320.6N 11911011811511411611811811211395% CI 2.71.82.22.77.53.82.22.75.13.8Max 110.554.556.569.7191.599.652.686.7157.6140.5Min 0.80.54.31.93.53.00.83.92.34.6N< MDL 1100001000Year 2 Avg 18.122.726.125.058.619.952.429.9SD 13.914.512.216.036.112.924.338.3N 11310811111311011211111495% CI 2.62.72.32.96.72.44.57.0Max 78.3128.454.5101.9157.372.5115.1357.2Min 2.71.21.41.10.51.55.00.8N< MDL 00001001MATES IIIFinal ReportAppendix VI-23Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBMolybdenum Year 1Avg 4.64.14.53.83.84.04.04.53.94.9MDL = 2SD 5.44.65.14.03.44.84.24.14.35.9N 11911011811511411611811811211395% CI 1.00.90.90.70.60.90.80.70.81.1Max 26.324.725.329.623.628.123.422.322.228.2Min 1.01.01.01.01.01.01.01.01.01.0N< MDL 41353440253934243737Year 2 Avg 2.93.94.73.93.33.63.53.4SD 1.52.73.23.13.62.13.92.4N 11310811111311011211111495% CI 0.30.50.60.60.70.40.70.4Max 9.723.721.922.323.511.924.519.8Min 1.01.01.01.01.01.01.01.0N< MDL 3822143241284135Nickel Year 1Avg 4.54.45.56.44.27.87.35.23.612.1MDL = 1SD 3.12.46.73.42.95.74.12.72.46.8N 11911011811511411611811811211395% CI 0.60.41.20.60.51.00.70.50.51.2Max 15.017.169.821.113.229.719.217.411.234.5Min 0.20.40.80.40.20.40.40.80.20.2N< MDL 734216221152Year 2 Avg 4.03.55.46.13.76.93.910.5SD 2.01.93.53.72.33.52.96.0N 11310811111311011211111495% CI 0.40.40.70.70.40.60.51.1Max 11.210.317.521.49.716.827.626.4Min 0.80.40.20.20.20.20.20.8N< MDL 38459482MATES IIIFinal ReportAppendix VI-24Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBPalladium Year 1Avg 1.651.621.651.591.631.621.631.721.691.69MDL = 3SD 0.450.330.450.270.370.360.380.630.490.50N 11911011811511411611811811211395% CI 0000000000Max 4.643.443.803.043.213.804.285.634.645.40Min 1.501.501.501.501.501.501.501.501.501.50N< MDL 119110118115114116118117112112Year 2 Avg 1.711.711.611.621.681.611.671.60SD 0.540.570.290.410.430.350.510.34N 11310811111311011211111495% CI 00000000Max 4.644.553.444.613.523.483.843.44Min 1.501.501.501.501.501.501.501.50N< MDL 11310811111311016112111114PhosphorousYear 1 Avg 46.046.146.455.644.863.350.443.790.050.8MDL = 21 SD 30.326.830.933.531.033.833.927.174.234.4N 11911011811511411611811811211395% CI 55666665146Max 151.4126.1156.9160.4138.0159.3164.1143.1264.2197.0Min 15.015.015.015.015.015.015.015.015.015.0N< MDL 2923301340720283522Year 2 Avg 47.742.345.458.836.657.684.658.2SD 30.827.935.934.326.539.469.939.0N 11310811111311011211111495% CI 657657137Max 152.2124.0181.8151.4146.6200.1242.2191.5Min 15.015.015.015.015.015.015.015.0N< MDL 2929411045232319MATES IIIFinal ReportAppendix VI-25Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBPotassium Year 1Avg 4764724785178655824465311111622MDL = 2SD 52842839635416313862572491365673N 11911011811511411611811811211395% CI 95807265299704645253124Max 564645384191304017496371917421912140566618Min 31442422473326667449N< MDL 0000000000Year 2 Avg 4164484354486554101104482SD 219192186195359181534263N 11310811111311011211111495% CI 4036353667349948Max 12721251122810111844118024401387Min 888769219414385N< MDL 00001000Rubidium Year 1 Avg 1.20.91.11.02.71.31.01.43.81.6MDL = 1SD 1.20.70.70.82.21.20.81.22.61.8N 11911011811511411611811811211395% CI 0000000000Max 6.93.63.55.412.09.14.28.111.613.6Min 0.40.40.40.40.40.40.40.40.40.4N< MDL 1021021061045298106893587Year 2 Avg 1.00.90.91.02.30.94.21.2SD 0.90.80.60.71.80.82.21.1N 11310811111311011211111495% CI 00000000Max 5.04.62.73.88.15.38.44.6Min 0.40.40.40.40.40.40.40.4N< MDL 99100103104611022292MATES IIIFinal ReportAppendix VI-26Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBSelenium Year 1Avg 1.01.01.01.01.01.01.01.01.01.0MDL = 2SD 0.00.00.00.00.00.00.00.00.00.0N 11911011811511411611811811211395% CIMax 1.01.01.01.01.01.01.01.01.01.0Min 1.01.01.01.01.01.01.01.01.01.0N< MDL 119110118115114116118118112113Year 2 Avg 1.01.01.01.01.01.01.01.0SD 0.00.00.00.00.00.00.00.0N 11310811111311011211111495% CIMax 1.01.01.01.01.01.01.01.0Min 1.01.01.01.01.01.01.01.0N< MDL 113108111113110112111114Silicon Year 1 Avg 5398521960446132876867645294704295937341MDL = 275 SD 3217222527753047520532302864366251365083N 11911011811511411611811811211395% CI 578416501557955588517661951937Max 18978113031209217088242541716013400280002591831948Min 267267363267267267267747713267N< MDL 2101113001Year 2 Avg 484854455676544778205029100006264SD 29532460238227304070268940963879N 11310811111311011211111495% CI 544464443503761498762712Max 1557913873109321276920002132922096317742Min 2672672672672672671394267N< MDL52223401MATES IIIFinal ReportAppendix VI-27Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBSilver Year 1Avg 2.32.12.31.51.82.01.91.92.12.5MDL = 2SD 3.83.43.82.13.03.02.93.03.64.2N 11911011811511411611811811211395% CI 1110111111Max 18.417.617.918.425.318.317.618.118.818.5Min 1.21.21.21.21.21.21.21.21.21.2N< MDL 11098106112103104108108102102Year 2 Avg 1.21.51.71.51.61.21.91.4SD 0.21.62.71.72.40.13.51.3N 11310811111311011211111495% CI 00100010Max 2.717.222.015.017.02.325.314.5Min 1.21.21.21.21.21.21.21.2N< MDL 112101107106107111106109Strontium Year 1 Avg 12.013.216.813.820.618.411.514.025.616.5MDL = 2 SD 12.79.710.78.644.510.66.77.432.810.7N 11911011811511411611811811211395% CI 2222821162Max 126.395.591.263.6478.482.535.243.8339.964.4Min 1.01.01.01.01.01.01.01.01.01.0Capture 98.3%90.9%97.5%95.0%94.2%95.9%97.5%97.5%92.6%93.4%N< MDL 9435927773Year 2 Avg 11.613.016.612.315.711.324.614.9SD 12.76.98.16.39.26.411.39.1N 11310811111311011211111495% CI 21212122Max 118.934.338.737.339.039.745.749.6Min 1.51.12.31.01.01.52.71.0N< MDL 15034201MATES IIIFinal ReportAppendix VI-28Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBSulfur Year 1Avg 1623160516191775111018961842152712712029MDL = 21SD 10871015119112011035124212169979751259N 11911011811511411611811811211395% CI 195190215220190226219180181232Max 5229426947305802903955086416464476946738Min 139124140252702192521799212N< MDL 0000000001Year 2 Avg 1509138315081659925180912371967SD 8989331075108661711656611192N 11310811111311011211111495% CI 166176200200115216123219Max 38233827452847772877611128066090Min 1842022541212291141311N< MDL 0001100000Tin Year 1 Avg 2.54.44.53.22.84.93.215.52.23.1MDL = 3 SD 1.73.43.03.01.84.53.032.91.23.0N 11911011811511411611811811211395% CI 0111011601Max 10.826.715.417.510.821.719.4244.66.917.4Min 1.51.51.51.51.51.51.51.51.51.5N< MDL 89414579775384309077Year 2 Avg 2.54.24.43.32.63.72.63.3SD 1.72.52.92.91.73.61.63.4N 11310811111311011211111495% CI 00110101Max 10.113.112.811.910.018.38.819.1Min 1.51.51.51.51.51.51.51.5N< MDL 8436487478687679MATES IIIFinal ReportAppendix VI-29Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBTitanium Year 1Avg 148162180182262213149191275257MDL = 5SD 987481961609898104150654N 11911011811511411611811811211395% CI 181415182918181928121Max 6204263784717865114597886936967Min 418171817279192618N< MDL 1000000000Year 2 Avg 151170181173243150308181SD 10782809613995135195N 11310811111311011211111495% CI 2015151826182536Max 5604763545046335006531867Min 23131363194311N< MDL 00001000Vanadium Year 1 Avg 9.56.27.010.66.69.016.17.67.527.6MDL = 2 SD 7.94.45.47.05.16.510.45.66.018.3N 11911011811511411611811811211395% CI 1.40.81.01.30.91.21.91.01.13.4Max 34.918.125.340.822.836.559.530.427.186.0Min 1.21.21.21.21.21.21.21.21.21.2N< MDL 22283163120617254Year 2 Avg 8.55.56.410.75.915.47.525.5SD 5.24.25.27.24.09.54.518.1N 11310811111311011211111495% CI 1.00.81.01.30.71.80.83.3Max 22.124.526.435.017.142.619.699.6Min 1.21.21.21.21.21.21.21.2N< MDL 83034142626154MATES IIIFinal ReportAppendix VI-30Table VI-3Ambient Concentrations (ng/m3) of TSP Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBYttrium Year 1 Avg 0.550.520.490.510.770.520.510.510.760.59MDL = 1 SD 0.440.420.410.400.600.400.410.430.610.57N 11911011811511411611811811211395% CI 0000000000Max 2.321.781.941.922.811.901.961.933.103.88Min 0.200.200.200.200.200.200.200.200.200.20N< MDL 1019210410080981011027399Year 2 Avg 0.580.550.470.500.600.510.770.57SD 0.490.870.370.370.530.330.560.42N 11310811111311011211111495% CI 00000000Max 2.698.831.821.922.711.562.692.29Min 0.200.200.200.200.200.200.200.20N< MDL 949697101861007894Zinc Year 1 Avg 62.065.375.769.1104.1104.369.686.177.293.5MDL = 1 SD 43.231.132.345.465.568.041.462.353.0149.0N 11911011811511411611811811211395% CI 7.85.85.88.312.012.47.511.29.827.5Max 198.7155.5166.8251.8312.0364.3206.7362.3338.41553.5Min 4.213.014.79.96.920.25.918.215.012.0N< MDL 0000000000Year 2 Avg 55.166.981.564.2100.771.884.980.3SD 41.733.049.642.158.042.252.062.8N 11310811111311011211111495% CI 7.76.29.27.810.87.89.711.5Max 246.0180.6433.2248.7284.5205.1281.7312.8Min 11.26.59.11.90.810.112.38.8N< MDL 00001000MATES IIIFinal ReportAppendix VI-31Table VI-4Ambient Concentrations (ng/m3) of PM2.5 Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBAluminum Year 1Avg 52.060.277.361.578.355.864.161.265.578.0MDL = 1.2SD 99.9131.0178.0118.2162.5108.4141.9120.3159.4168.0N 12112011211811711712011611611395% CI 18233321292025222931Max 526.2710.81125.8699.1876.1673.2897.6785.71300.8951.4Min 17.517.517.517.517.517.517.517.517.517.5N< MDL 0000000000Year 2 Avg 70.4140.476.089.4163.1123.396.5136.0SD 126.8419.1132.2158.4205.3161.8147.9179.5N 11911911911612110812011595% CI 2375242937312633Max 773.04363.5797.91097.4925.6817.4675.1767.5Min 17.517.517.517.517.517.517.517.5N< MDL 00000000Antimony Year 1 Avg 0.70.70.70.70.90.70.70.70.90.7MDL = 1.4SD 0.50.50.50.52.30.50.50.52.10.5N 12112011211811711712011611611395% CI 0000000000Max 1.21.21.21.224.71.21.21.322.41.3Min 0.30.30.30.30.30.30.30.30.30.3N< MDL 121120112118116117120116115113Year 2 Avg 16.715.914.212.816.89.113.012.0SD 37.436.835.433.137.227.833.332.7N 11911911911612110812011595% CI 77667566Max 132.0132.1128.1126.8133.4139.1122.2137.5Min 0.30.30.30.30.30.30.30.3N< MDL 8685918582839689MATES IIIFinal ReportAppendix VI-32Table VI-4Ambient Concentrations (ng/m3) of PM2.5Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBArsenic Year 1Avg 0.740.650.660.680.730.750.590.770.780.83MDL = 0.2SD 0.730.700.690.660.910.710.680.920.830.75N 12112011211811711712011611611395% CI 0000000000Max 3.712.482.482.487.422.483.714.964.973.72Min 0.040.040.040.040.040.040.040.040.040.04N< MDL 57645858585468585446Year 2 Avg 0.740.650.660.680.730.590.780.83SD 0.730.700.690.660.910.680.830.75N 12112011211811712011611395% CI 00000000Max 3.712.482.482.487.423.714.973.72Min 0.040.040.040.040.040.040.040.04N< MDL 5764585858685446Barium Year 1Avg 24.628.028.123.036.025.024.928.426.522.2MDL = 10SD 34.732.228.725.9132.920.717.446.092.116.9N 12112011211811711712011611611395% CI 665524438173Max 354.5315.7243.6210.61450.0143.787.9486.2998.988.0Min 2.12.12.12.12.12.12.12.12.12.1N< MDL 31292636322822234238Year 2 Avg 33.337.032.031.533.726.127.223.4SD 28.829.925.026.628.524.025.624.9N 11911911911612110812011595% CI 55455555Max 143.1130.7121.9117.0147.3120.6131.8129.4Min 2.12.12.12.12.12.12.12.1N< MDL 2219242825323241MATES IIIFinal ReportAppendix VI-33Table VI-4Ambient Concentrations (ng/m3) of PM2.5Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBCadmium Year 1Avg 2.41.61.51.71.51.81.51.91.71.8MDL = 1SD 6.12.21.51.81.32.01.64.31.92.0N 12112011211811711712011611611395% CI 1000000100Max 65.616.17.411.16.212.48.744.611.29.9Min 0.50.50.50.50.50.50.50.50.50.5N< MDL 50524644454646484143Year 2 Avg 1.51.41.41.61.71.61.51.5SD 1.92.22.02.72.33.51.92.0N 11911911911612110812011595% CI 00000100Max 11.213.611.117.29.932.09.911.1Min 0.50.50.50.50.50.50.50.5N< MDL 7591818379807880Calcium Year 1Avg 96.7108.6115.894.8188.8105.391.3102.5189.3117.5MDL = 1SD 81.981.990.754.3168.6102.049.956.3157.877.4N 12112011211811711712011611611395% CI 1515171031189102914Max 740.1663.4600.7405.31557.8947.9297.9328.0748.4574.5Min 25.921.127.323.537.10.528.432.225.943.3N< MDL 0000010000Year 2 Avg 96.5139.489.393.2209.787.8198.3118.9SD 77.4176.447.668.9119.745.8167.765.4N 11911911911612110812011595% CI 14329132193012Max 635.61887.4255.3619.0685.7294.5817.5432.0Min 24.623.417.230.932.132.26.228.5N< MDL 00000000MATES IIIFinal ReportAppendix VI-34Table VI-4Ambient Concentrations (ng/m3) of PM2.5Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBChromium Year 1Avg 1.31.21.11.21.44.31.11.51.01.2MDL = 1SD 2.91.71.31.62.28.31.12.72.01.6N 12112011211811711712011611611395% CI 1000020000Max 28.514.88.713.617.343.36.217.321.012.4Min 0.30.30.30.30.30.30.30.30.30.3N< MDL 58575352514152535750Year 2 Avg 3.73.54.13.64.41.34.64.6SD 14.415.115.212.920.62.218.118.5N 11911911911612110812011595% CI 33324033Max 111.0117.3116.9121.8192.09.9118.2120.8Min 0.30.30.30.30.30.30.30.3N< MDL 7571616571767871CobaltYear 1 Avg 1.171.131.211.031.151.281.161.211.161.12MDL = 0.4 SD 0.790.900.790.700.730.880.780.870.700.65N 12112011211811711712011611611395% CI0.10.20.10.10.10.20.10.20.10.1Max 3.726.204.953.723.723.723.714.953.723.72Min 0.260.260.260.260.260.260.260.260.260.26N< MDL 33392842313035363029Year 2 Avg 0.831.041.041.011.160.901.061.27SD 0.780.990.950.850.980.810.911.22N 11911911911612110812011595% CI 0.10.20.20.20.20.20.20.2Max 3.696.183.713.714.943.693.726.16Min 0.260.260.260.260.260.260.260.26N< MDL 6858575450575746MATES IIIFinal ReportAppendix VI-35Table VI-4Ambient Concentrations (ng/m3) of PM2.5Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBCopper Year 1Avg 9.827.116.311.925.553.918.615.816.813.4MDL = 0.2SD 17.116.415.011.670.321.810.024.149.89.2N 12112011211811711712011611611395% CI 3.02.92.82.112.73.91.84.49.11.7Max 187.8180.7143.4107.8767.1146.254.4266.0544.260.7Min 1.26.23.72.52.50.23.71.22.52.5N< MDL 0000000000Year 2 Avg 12.327.215.312.933.520.421.015.8SD 7.512.19.29.0147.49.87.514.2N 11911911911612110812011595% CI 1.42.21.71.626.31.81.32.6Max 40.995.161.753.11638.050.742.0122.0Min 1.27.42.52.54.93.76.21.2N< MDL 00000000Indium Year 1 Avg 2.22.32.32.42.12.22.02.51.92.3MDL = 1 SD 2.62.62.42.62.02.52.52.72.12.5N 12112011211811711712011611611395% CI 0.50.50.40.50.40.40.40.50.40.5Max 13.612.412.411.211.111.111.111.19.913.6Min 0.30.30.30.30.30.30.30.30.30.3N< MDL 42363237333941374030Year 2 Avg 6.05.64.84.86.24.04.64.7SD 8.27.26.86.98.35.97.26.7N 11911911911612110812011595% CI 1.51.31.21.31.51.11.31.2Max 35.829.630.930.835.833.433.528.3Min 0.30.30.30.30.30.30.30.3Capture 97.5%97.5%97.5%95.1%99.2%88.5%98.4%94.3%N< MDL 4550525445496050MATES IIIFinal ReportAppendix VI-36Table VI-4Ambient Concentrations (ng/m3) of PM2.5Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBIron Year 1Avg 68.3111.9137.976.2151.395.482.3108.675.974.4MDL = 0.4SD 75.791.4117.083.2100.2120.191.592.764.594.3N 12112011211811711712011611611395% CI 13.516.321.715.018.221.816.416.911.717.4Max 413.5519.9687.4484.7448.2816.1441.0398.5291.6432.7Min 0.27.40.20.20.20.21.26.20.20.2N< MDL 50121100110Year 2 Avg 79.8144.3112.676.5176.069.592.779.9SD 99.4167.996.6101.2125.567.294.7118.5N 11911911911612110812011595% CI 17.930.217.418.422.412.716.921.7Max 561.31499.6582.0817.0822.9334.1538.8651.1Min 0.20.20.20.20.20.20.20.2N< MDL 11251012614Lead Year 1Avg 4.25.16.27.310.49.25.57.17.312.0MDL = 3 SD 4.24.23.87.714.011.74.56.29.160.5N 12112011211811711712011611611395% CI 0.80.70.71.42.52.10.81.11.711.2Max 33.434.719.857.0132.4112.724.754.477.0645.9Min 0.60.60.60.60.60.60.60.60.60.6N< MDL 59462238272245222941Year 2 Avg 3.65.04.86.09.64.36.04.3SD 2.43.53.55.811.53.95.43.9N 11911911911612110812011595% CI 0.40.60.61.02.10.71.00.7Max 11.217.316.136.986.720.933.518.5Min 0.60.60.60.60.60.60.60.6N< MDL 5641394223533754MATES IIIFinal ReportAppendix VI-37Table VI-4Ambient Concentrations (ng/m3) of PM2.5Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBManganese Year 1Avg 3.03.15.84.07.26.52.94.13.73.5MDL = 0.5SD 2.42.54.03.64.98.82.83.23.03.4N 12112011211811711712011611611395% CI 0.40.40.70.70.91.60.50.60.50.6Max 12.412.422.218.623.544.512.413.616.217.3Min 0.20.20.20.20.20.20.20.20.20.2N< MDL 1512513281781018Year 2 Avg 2.53.34.43.86.42.03.73.1SD 5.26.06.16.07.02.76.46.2N 11911911911612110812011595% CI 0.91.11.11.11.20.51.21.1Max 37.040.844.352.946.912.443.241.9Min 0.20.20.20.20.20.20.20.2N< MDL 5644383832533742Molybdenum Year 1 Avg 4.04.34.74.74.25.14.34.44.34.3MDL = 1 SD 1.92.02.12.42.03.12.72.12.02.0N 12112011211811711712011611611395% CI 0.30.40.40.40.40.60.50.40.40.4Max 8.711.19.913.69.923.516.19.99.98.7Min 0.31.21.20.30.30.30.30.30.31.2N< MDL 3003223220Year 2 Avg 4.54.94.74.95.14.44.75.0SD 2.42.82.42.53.52.42.32.6N 11911911911612110812011595% CI 0.40.50.40.50.60.40.40.5Max 13.619.816.014.833.512.412.314.8Min 0.30.31.20.30.30.31.20.3Capture 97.5%97.5%97.5%95.1%99.2%88.5%98.4%94.3%N< MDL 43033501MATES IIIFinal ReportAppendix VI-38Table VI-4Ambient Concentrations (ng/m3) of PM2.5Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBNickelYear 1 Avg 3.32.52.73.22.34.04.62.92.27.1MDL = 0.2SD 2.71.71.92.01.83.23.02.22.04.8N 12112011211811711712011611611395% CI 0.50.30.40.40.30.60.50.40.40.9Max 13.69.911.19.98.716.114.812.412.424.8Min 0.10.10.10.10.10.10.10.10.10.1N< MDL 376315468121Year 2 Avg 4.23.34.44.54.34.23.37.6SD 5.24.65.25.411.53.65.26.4N 11911911911612110812011595% CI 0.90.80.91.02.10.70.91.2Max 33.328.428.334.5120.218.532.138.2Min 0.10.10.10.10.10.10.10.1Capture 97.5%97.5%97.5%95.1%99.2%88.5%98.4%94.3%N< MDL 15271715278285Palladium Year 1 Avg 1.61.41.31.41.21.21.31.11.71.4MDL = 1.5 SD 2.21.51.41.61.31.31.61.22.01.5N 12112011211811711712011611611395% CI 0.40.30.30.30.20.20.30.20.40.3Max 13.69.97.48.77.48.79.97.48.77.4Min 0.30.30.30.30.30.30.30.30.30.3N< MDL 979490949797102999290Year 2 Avg 0.90.80.90.91.00.91.00.9SD 1.31.01.31.41.61.31.51.4N 11911911911612110812011595% CI 0.20.20.20.30.30.20.30.3Max 7.45.07.47.412.47.47.47.4Min 0.30.30.30.30.30.30.30.3N< MDL 1021031009910293102100MATES IIIFinal ReportAppendix VI-39Table VI-4Ambient Concentrations (ng/m3) of PM2.5Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBPhosphorous Year 1 Avg 25.223.927.331.726.832.231.029.622.334.5MDL = 12 SD 28.833.734.540.635.739.841.338.031.845.7N 12112011211811711712011611611395% CI 5.16.06.47.36.57.27.46.95.88.4Max 152.2214.2185.6198.1236.3184.0183.0221.6164.3315.5Min 3.13.13.13.13.13.13.13.13.13.1N< MDL 63726259645465567351Year 2 Avg 16.621.223.224.321.529.619.231.6SD 25.334.535.840.430.741.626.546.6N 11911911911612110812011595% CI 4.56.26.47.45.57.84.78.5Max 125.7167.2219.4216.6131.3204.2125.7243.9Min 3.13.13.13.13.13.13.13.1Capture 97.5%97.5%97.5%95.1%99.2%88.5%98.4%94.3%N< MDL 8078717474607762Potassium Year 1 Avg 98.2110.495.5104.7252.9121.976.6135.7190.070.7MDL = 1 SD 501.6442.1389.2337.11984.7306.8195.1727.31378.4178.2N 12112011211811711712011611611395% CI 89.479.172.160.8359.655.634.9132.4250.832.8Max 552647674081298621528298416017850148861553Min 0.30.30.30.30.30.30.30.30.30.3N< MDL 2313236215Year 2 Avg 64.683.650.762.884.146.784.248.2SD 97.294.189.481.279.446.6174.044.3N 11911911911612110812011595% CI 17.516.916.114.814.18.831.18.1Max 8636639127415732311585207Min 0.30.30.30.30.30.30.30.3N< MDL 61755479MATES IIIFinal ReportAppendix VI-40Table VI-4Ambient Concentrations (ng/m3) of PM2.5Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBRubidium Year 1 Avg 0.60.60.60.60.60.60.60.60.60.6MDL = 0.4 SD 0.60.60.60.60.60.60.60.60.60.6N 12112011211811711712011611611395% CI 0.10.10.10.10.10.10.10.10.10.1Max 1.21.21.21.21.21.21.21.31.21.3Min 0.10.10.10.10.10.10.10.10.10.1N< MDL 71726767707072696461Year 2 Avg 0.10.10.10.10.10.20.10.10.10.1SD 0.00.10.10.10.10.30.10.00.10.0N 119119119116121151085912011595% CI 0.00.00.00.00.00.10.00.00.00.0Max 0.11.21.21.21.21.21.20.11.20.1Min 0.10.10.10.10.10.10.10.10.10.1N< MDL 1191181171151201410759119115Selenium Year 1 Avg 0.60.60.60.70.60.60.60.60.70.7MDL = 1 SD 0.50.50.50.50.50.50.50.50.50.5N 12112011211811711712011611611395% CI 0.10.10.10.10.10.10.10.10.10.1Max 1.21.21.21.21.21.21.21.31.21.3Min 0.20.20.20.20.20.20.20.20.20.2N< MDL 71726767707072706661Year 2 Avg 0.20.20.20.20.20.20.20.2SD 0.00.10.00.10.10.00.00.0N 11911911911612110812011595% CI 0.00.00.00.00.00.00.00.0Max 0.21.20.21.21.20.20.20.2Min 0.20.20.20.20.20.20.20.2N< MDL 119118119115120108120115MATES IIIFinal ReportAppendix VI-41Table VI-4Ambient Concentrations (ng/m3) of PM2.5Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBSilicon Year 1 Avg 101133139105222134123148126143MDL = 160 SD 153182241164308218171240166235N 12112011211811711712011611611395% CI 27334530563931443043Max 8271173142711231716161981414408061804Min 36363636363636363636N< MDL 103909198719292858786Year 2 Avg 8218011179170111101150SD 145474187118213178157224N 11911911911612110812011595% CI 2685342238342841Max 1120430511058358051006924999Min 3636363636363636N< MDL 1059299101849010187Silver Year 1 Avg 1.00.80.91.10.90.90.90.90.90.9MDL = 1.2 SD 1.20.90.91.21.01.00.90.90.90.8N 12112011211811711712011611611395% CI 0000000000Max 8.77.46.28.76.27.47.46.25.05.0Min 0.20.20.20.20.20.20.20.20.20.2N< MDL 59636151606060585850Year 2 Avg 0.60.50.50.52.30.40.50.5SD 1.20.90.60.820.10.70.91.0N 11911911911612110812011595% CI 00004000Max 7.45.02.56.2221.84.96.27.4Min 0.20.20.20.20.20.20.20.2N< MDL 10410410410010397106105MATES IIIFinal ReportAppendix VI-42Table VI-4Ambient Concentrations (ng/m3) of PM2.5Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBStrontium Year 1 Avg 2.11.92.11.64.71.61.42.63.41.5MDL = 1 SD 9.37.67.25.238.24.92.813.825.53.0N 12112011211811711712011611611395% CI1.71.41.30.96.90.90.52.54.60.6Max 101.382.974.254.5414.552.019.8148.5275.821.1Min 0.20.20.20.20.20.20.20.20.20.2N< MDL 52484349394853485046Year 2 Avg 1.71.21.10.90.90.80.81.0SD 8.52.32.21.71.41.21.01.2N 11911911911612110812011595% CI1.50.40.40.30.30.20.20.2Max 91.517.319.713.68.66.26.27.4Min 0.20.20.20.20.20.20.20.2N< MDL 8577757589818364Sulfur Year 1 Avg 1485149715741627131917121744158012311792MDL = 12 SD 1344136714421477141716041571151012751619N 12112011211811711712011611611395% CI 239245267266257291281275232298Max 60935814629063421047869357924686284829065Min 6336333163108N< MDL 1221630190Year 2 Avg 13301360130514301160164211551773SD 1178133012931409104514529481507N 11911911911612110812011595% CI 212239232256186274170275Max 47565007552255834498736936207607Min 4333153332N< MDL 11310140MATES IIIFinal ReportAppendix VI-43Table VI-4Ambient Concentrations (ng/m3) of PM2.5Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBTin Year 1 Avg 0.81.01.21.21.01.41.07.90.81.2MDL = 1.5 SD 0.81.11.22.01.21.91.020.40.61.4N 12112011211811711712011611611395% CI 0.10.20.20.40.20.40.23.70.10.3Max 6.26.27.416.18.79.97.4116.44.98.7Min 0.30.30.30.30.30.30.30.30.30.3N< MDL 116108961091079911183114102Year 2 Avg 2.83.22.72.62.82.22.12.9SD 5.96.65.86.46.25.35.07.0N 11911911911612110812011595% CI 1.11.21.01.21.11.00.91.3Max 27.129.623.436.929.627.126.033.3Min 0.30.30.30.30.30.30.30.3N< MDL 969493939611934210095Titanium Year 1 Avg 16.719.422.324.523.319.024.120.817.821.4MLD = 3 SD 9.810.312.618.016.09.126.511.210.924.1N 12112011211811711712011611611395% CI 1.71.82.33.32.91.64.72.02.04.4Max 53.268.187.9101.6136.149.3120.063.196.9147.5Min 2.53.73.73.73.72.52.56.25.02.5N< MDL 1000011001Year 2 Avg 19.829.119.826.625.821.719.019.1SD 10.861.310.222.611.320.78.915.6N 11911911911612110812011595% CI 1.911.01.84.12.03.91.62.9Max 57.0629.259.1174.874.1118.749.690.4Min 4.91.23.76.24.96.13.73.7N< MDL 01000000MATES IIIFinal ReportAppendix VI-44Table VI-4Ambient Concentrations (ng/m3) of PM2.5Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBVanadium Year 1 Avg 6.94.24.87.53.76.011.75.64.019.8MDL = 1.2 SD 6.73.94.55.83.85.48.64.84.214.6N 12112011211811711712011611611395% CI 1.20.70.81.00.71.01.50.90.82.7Max 28.522.323.534.619.828.550.726.023.566.8Min 0.30.30.30.30.30.30.30.30.31.2N< MDL 714101176210160Year 2 Avg 6.74.14.67.53.711.23.719.2SD 4.93.94.16.03.38.23.014.7N 11911911911612110812011595% CI 0.90.70.71.10.61.50.52.7Max 21.020.923.430.816.150.712.387.5Min 0.30.30.30.30.30.30.30.3N< MDL 10302814318276Yttrium Year 1 Avg 1.11.31.21.31.01.31.21.21.11.2MDL = 0.2 SD 0.81.00.80.90.70.90.80.80.80.8N 12112011211811711712011611611395% CI 0.10.20.20.20.10.20.10.10.10.1Max 4.93.73.73.72.53.73.73.73.73.7Min 0.10.10.10.10.10.10.10.10.10.1N< MDL 30332725332527253325Year 2 Avg 1.00.90.91.00.81.21.01.1SD 1.11.01.01.11.01.31.21.0N 11911911911612110812011595% CI 0.20.20.20.20.20.20.20.2Max 5.03.74.95.04.96.26.23.7Min 0.10.10.10.10.10.10.10.1N< MDL 5965665673476544MATES IIIFinal ReportAppendix VI-45Table VI-4Ambient Concentrations (ng/m3) of PM2.5Components at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBZinc Year 1 Avg 22.721.346.830.953.936.527.340.733.128.1MDL = 0.2 SD 16.812.0245.936.039.138.922.555.537.728.7N 12112011211811711712011611611395% CI 3.02.245.56.57.17.04.010.16.95.3Max 75.579.32621.7236.8210.5223.8111.3361.9261.7152.2Min 3.75.05.03.73.71.23.76.24.92.5N< MDL 0000000000Year 2 Avg 19.221.626.127.459.326.330.726.1SD 12.513.027.223.697.124.132.030.1N 11911911911612110812011595% CI 2.22.34.94.317.34.55.75.5Max 73.175.4285.8128.11053.2180.6167.0188.6Min 3.74.96.13.76.23.71.23.7N< MDL 00000000MATES IIIFinal ReportAppendix VI-46Table VI-5Ambient PM10Carbon Concentrations (ug/m3) at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBPM10Year 1Avg 31.0336.8632.0534.6246.8436.4730.3535.7549.4735.06MassSD 13.7916.2213.5514.2623.7513.6211.5014.8024.5915.32N 11211111811811511911311810210795% CI 2.553.022.442.574.342.452.122.674.772.90Max 74.0092.0079.0090.00134.0073.0072.0085.00122.0080.00Min 3.005.004.004.007.006.005.005.004.009.00Year 2 Avg 30.5833.9829.6231.6253.7130.3755.2232.83SD 12.7812.3311.4511.8522.4911.9023.8814.35N 11811811610810911811111795% CI 2.312.222.082.244.222.154.442.60Max 92.0077.0068.0062.00115.0066.00123.0089.00Min 10.009.006.0011.009.009.008.006.00PM10Year 1 Avg 1.552.321.931.942.162.461.812.331.952.48Elemental CarbonSD 1.081.391.001.341.021.481.251.261.081.66N 11211011811711511811211810110795% CI 0.200.260.180.240.190.270.230.230.210.31Max 7.866.375.945.615.156.546.696.285.226.77Min 0.430.490.560.520.280.840.490.760.410.60Year 2 Avg 1.682.222.051.742.491.822.152.36SD 1.071.111.071.091.141.031.191.67N 11811811410810811811111595% CI 0.190.200.200.210.210.190.220.31Max 5.986.015.276.535.315.716.129.02Min 0.460.660.500.320.480.360.460.59MATES IIIFinal ReportAppendix VI-47Table VI-5Ambient PM10Carbon Concentrations (ug/m3) at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBPM10Year 1Avg 4.616.325.135.486.475.884.795.556.695.47Organic CarbonSD 1.893.451.673.132.463.082.322.152.703.40N 11211011811711511811211810110795% CI 0.350.650.300.570.450.550.430.390.530.65Max 11.7526.999.6822.1216.0519.6614.9413.9013.7017.79Min 2.131.382.482.091.982.661.772.502.372.11Year 2 Avg 5.266.675.415.488.155.178.015.33SD 2.622.662.013.083.112.813.273.41N 11811811410810811811111595% CI 0.470.480.370.580.590.510.610.62Max 15.5315.1111.4920.6115.7713.8716.7717.50Min 2.032.642.022.072.812.041.942.05PM10Year 1 Avg 6.178.647.067.428.628.336.607.898.647.94Total CarbonSD 2.884.682.604.363.284.443.523.293.584.96N 11211011811711511811211810110795% CI 1101111111Max 19.6133.3615.6127.1920.9725.9821.6320.1818.3224.56Min 2.641.873.242.652.314.142.583.572.992.74Year 2 Avg 6.948.897.467.2210.646.9810.167.68SD 3.543.392.863.813.943.574.104.70N 11811811410810811811111595% CI 11111111Max 20.3918.1315.1622.7318.8616.9819.7825.65Min 2.533.392.522.393.292.392.392.78MATES IIIFinal ReportAppendix VI-48Table VI-6Ambient PM2.5Carbon Concentrations (ug/m3) at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBPM2.5Mass Year 1Avg 17.7121.3419.4419.5021.3722.3518.4520.7423.4318.35SD 10.0813.1410.4610.6913.4612.559.8411.1515.419.80N 11711511011411211311310911311095% CI 1.832.401.951.962.492.311.822.092.841.83Max 64.0180.7968.4257.49102.1877.8661.1064.8690.7360.34Min 4.234.135.373.512.784.964.434.953.515.68Year 2 Avg 17.4020.5618.0118.2421.6517.1922.3818.34SD 9.2810.209.749.9613.129.2613.969.46N 11811811711611710612211795% CI 1.671.841.761.812.381.762.481.71Max 59.2658.7154.4755.61112.4055.75110.1849.74Min 4.644.035.064.345.273.712.074.85PM2.5Year 1 Avg 1.191.791.601.611.842.201.461.971.482.03Elemental CarbonSD 0.951.110.871.401.131.691.141.081.001.78N 12111911311811711811911611411195% CI 0.170.200.160.250.200.300.200.200.180.33Max 6.446.284.497.187.109.085.995.184.368.40Min 0.060.360.320.220.040.030.040.460.070.02Year 2 Avg 1.522.122.031.802.241.491.822.12SD 1.191.241.191.421.211.041.211.73N 12112211911711910912111795% CI 0.210.220.210.260.220.200.220.31Max 6.406.185.296.565.655.275.708.78Min 0.100.380.400.020.260.350.000.31MATES IIIFinal ReportAppendix VI-49Table VI-6Ambient PM2.5Carbon Concentrations (ug/m3) at the Fixed SitesMeasurement SitePollutant Period Statistic AN BU LA CP SB HP NLB PRRU WLBPM2.5Year 1Avg 5.987.686.627.117.548.336.247.066.476.21Organic CarbonSD 2.663.162.153.643.124.273.092.493.033.19N 12111911311811711811911611411195% CI 0101111011Max 16.1522.3513.3023.6516.2225.5118.8013.8418.0415.83Min 2.151.771.881.930.981.171.492.161.131.06Year 2 Avg 6.418.598.236.928.436.777.336.96SD 3.013.143.553.233.063.673.504.00N 12112211911711910912111795% CI 11111111Max 17.7319.5622.3217.7517.9919.8522.3719.96Min 2.422.892.601.962.372.331.812.37PM2.5Year 1Avg 7.179.478.228.729.3710.537.709.037.958.25Total Carbon SD 3.444.132.874.863.945.764.053.393.804.78N 12111911311811711811911611411195% CI 1111111111Max 22.5828.6317.3130.8321.4433.9624.7818.2221.1323.64Min 2.262.342.282.471.021.211.622.941.211.15Year 2 Avg 7.9310.7010.258.7210.688.269.159.08SD 3.934.024.334.483.874.414.345.19N 12112211911711910912111795% CI 11111111Max 21.7624.5524.5424.1820.8924.0824.6126.93Min 2.893.453.151.972.732.681.982.69