# Patent

## Title
Method for reducing crosstalk in image sensors using implant technology

## Abstract

The present disclosure provides an image sensor semiconductor device. A semiconductor substrate having a first-type conductivity is provided. A plurality of sensor elements is formed in the semiconductor substrate. An isolation feature is formed between the plurality of sensor elements. An ion implantation process is performed to form a doped region having the first-type conductivity substantially underlying the isolation feature using at least two different implant energy.

## Background
BACKGROUND
In semiconductor technologies, image sensors include a plurality of sensor elements, or pixels, formed in a semiconductor substrate. The sensor elements are used for sensing a volume of exposed light projected towards the semiconductor substrate. The sensor elements can be formed on the front side of the substrate and light can be projected towards the front side or the backside of the substrate to reach the sensors. However, light targeted for one sensor element (and the electrical signal induced thereby) may spread to other sensor elements, which causes crosstalk. Improvements of the image sensors and/or the corresponding substrate are desired.



BRIEF DESCRIPTION OF THE DRAWINGS
Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is emphasized that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
FIG. 1 is a diagram illustrating an exemplary image sensor.
FIG. 2 is a cross section of image sensor in FIG. 1.
FIG. 3 is a cross section of image sensor in FIG. 2 with ion implantation.
FIG. 4 is a flow diagram of a first exemplary process for reducing crosstalk in image sensors using ion implantation.
FIG. 5 is a flow diagram of a second exemplary process for reducing crosstalk in image sensors using ion implantation.
FIG. 6 is a cross section of image sensor formed using the second exemplary process.
FIG. 7 is a graph illustrating relationships between crosstalk and the depth of doped regions.



DETAILED DESCRIPTION
It is to be understood that the following disclosure provides many different embodiments, or examples, for implementing different features of the invention. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed. Moreover, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed interposing the first and second features, such that the first and second features may not be in direct contact.
Referring to FIG. 1, a semiconductor device 100 includes a semiconductor substrate 110. The substrate 110 includes silicon in a crystalline structure. The substrate 110 may include various p-type doped regions and/or n-type doped regions configured and coupled to form various devices and function features. All doping may be implemented using a process such as ion implantation or diffusion in various steps and techniques. The substrate 110 may include other features such as an epi layer, a semiconductor on insulator (SOI) structure, or combinations thereof.
The semiconductor device 100 includes sensor elements 120 (also referred to as pixels) formed in and/or on the front surface 115 of the semiconductor substrate 110. In one embodiment, the sensor elements 120 may be disposed on the front surface 115 and extend into the semiconductor substrate 110. The sensor elements 120 each include a light-sensing region (also referred to as an image sensing region or photo-sensing region) which may be a doped region having N-type and/or P-type dopants formed in the semiconductor substrate 110 by a method such as diffusion or ion implantation. The light-sensing region may have a doping concentration ranging between about 1014 and 1021 atoms/cm3. The light-sensing region may have a surface area ranging between about 10% and 80% area of the associated sensor element, being operable to receive radiation (e.g., light) from an object to be imaged. Examples of sensor elements 120 include photodiodes, complimentary metal-oxide-semiconductor (CMOS) image sensors, charged coupling device (CCD) sensors, active sensors, passive sensors, and/or other devices diffused or otherwise formed in the substrate 110. In the context of the CMOS image sensors, a pixel may include a photodiode and at least one transistor. As such, the sensor elements 120 may comprise conventional and/or future-developed image sensing devices.
In the present embodiment, the semiconductor device 100 includes a plurality of sensor elements 120 disposed in an array. The plurality of sensor elements 120 may be designed to have various sensor types. For example, one group of sensor elements may be CMOS image sensors and another group of sensor elements may be passive sensors. Moreover, the sensor elements 120 may include color image sensors and/or monochromatic image sensors. The device 100 is designed to receive light 125 directed towards the backside surface of the semiconductor substrate 110 during operations, eliminating the design requirements for preventing obstruction of the optical paths by objects on the front side such as gate features and metal features, and maximizing the exposure of the light-sensing region to the illuminated light. The substrate 110 may be relatively thin so that the light directed through the back surface thereof may effectively reach the sensor elements 120.
A cross section of image sensor in FIG. 1 is described below with reference to FIG. 2. In the present embodiment, the semiconductor substrate 110 has a first type conductivity, for example, a P-type substrate. In an alternative embodiment, the semiconductor substrate 110 may have a second type conductivity, for example, an N-type substrate. In addition, the semiconductor substrate 110 may include various doped regions each having an N-type or P-type, such as an N-well or P-well. Furthermore, in the present embodiment, the plurality of sensor elements 120 are photodiodes that are formed by implanting N-type dopant into a P-type substrate. Pinned photodiodes may be formed by forming a P-type pinned layer over the surface of the N-type photodiodes.
Isolation features 125 are positioned between the plurality of sensor elements 120. In the present embodiment, the isolation features 125 are dielectric-filled trench structures, such as shallow trench isolation (STI) structures, for device technologies that are below 35 um. Furthermore, the semiconductor device 100 may include an oxide layer 140 lining the side walls of the isolation features 125. The oxide layer 140 is interposed between the dielectric-filled isolation features 125 and the semiconductor substrate 110.
Currently, when light is projected towards the front or back side of the substrate 110 to reach the plurality of sensor elements 120, the light may spread from one sensor element to another sensor element through the semiconductor substrate 110 below the isolation features 125, which creates crosstalk. Furthermore, as the pixel pitch of the sensor elements shrinks, crosstalk between the pixels is exacerbated. In order to reduce crosstalk between the plurality of sensor elements 120, aspects of the present disclosure utilize an ion implantation technology to form a doped region below the isolation features 125. The doped region may be a first-type doped region, such as P-type doped region. The depth of the doped region is preferably greater than the depth of the sensor elements. In this way, crosstalk between the sensor elements may be effectively reduced.
A cross section of the image sensor in FIG. 2 with ion implantation is described below with reference to FIG. 3. In an illustrative embodiment, ion implantation is performed over the isolation trenches 130 to form the doped regions 160 below the isolation trenches 130. The ion implantation may be performed with a tilt angle from about 0 to about 90 degrees. The range of energy to apply in the ion implantation is between about 400 to 1500 KeV with a preferred range of between about 600 to 900 KeV. By implanting ions with different energy values, different depth of the doped regions 160 may be achieved. A higher energy value provides a deeper ion implantation, for example, in the center of the doped regions 160. A lower energy value provides a shallow implantation, for example, doped regions 160 around the sidewall of the isolation trenches 130.
Since the semiconductor substrate 110 in this illustrative embodiment is a P-type substrate, P-type dopant 150, such as boron, is implanted below the isolation trenches 130 to form P-type doped regions 160. The dosage of boron used in the implantation is from about 1×1012 to about 1×1014 atoms/cm2, with a preferred dosage of between about 1×1013 to 3×1013 atoms/cm2. After the implantation, the concentration of doped regions 160 may be from about 1×1015 to about 1×1019 atoms/cm3. It is noted that in some embodiments, the concentration of doped regions 160 may be relatively low, since high concentrations of P-type dopant can cause out-diffusion into the N-type sensor elements 120, which may result in dark current and saturation voltage degrade. On the other hand, the concentration of doped regions 160 may be relatively high, since crosstalk may not be effectively reduced with a low concentration of dopant. Accordingly, one skilled in the art can choose a desired dopant concentration for their specific device.
Typically, the depth d1 of the sensor elements 120 is between about 0.3 um to 0.8 um. In order to effectively reduce crosstalk between the sensor elements 120, the depth d2 of the doped regions 160 is preferably greater than the depth d1 of the sensor elements, for example, for sensor elements 120 having a junction depth of about 0.5 um to about 1.0 um, the depth d2 of the doped regions 160 is at least greater than about 1.0 um or twice the depth d1 of the sensor elements 120. By having a depth d2 greater than the junction depth d1 of the sensor elements 120, the doped regions 160 may effectively reduce cross-talk between the sensor elements 120.
In this example, the depth d1 of the sensor elements 120 is measured from the upper surface of the semiconductor device 100 to the lower surface of the sensor elements 120. The depth d2 of the doped regions is measured from the upper surface of the semiconductor device 100 to the back surface of the semiconductor substrate 110.
In addition, the depth d2 of the doped regions 160 is also preferably greater than the depth d3 of the isolation trenches 130. The width w1 of the doped regions 160 is wider than the width w2 of the upper portion of the isolation trenches 130 and the width w3 of the lower portion of the isolation trenches 130.
Referring to FIG. 4, a flow diagram of a first exemplary process for reducing crosstalk in image sensors using ion implantation is depicted. The process begins at step 200 by providing a substrate having a plurality of sensor elements formed therein. Next, the substrate is patterned to form isolation trenches 130 at step 220. The substrate may be patterned using processes known in the art or techniques to be developed in the future. One example is by applying a photoresist layer on the substrate and patterned using a lithography process. Then, etching is performed on the substrate to form the isolation trenches 130. In one illustrative embodiment, the isolation trenches 130 formed are shallow trench isolation (STI) features.
Once the isolation trenches 130 are formed, the process continues to step 240 where an oxide layer 140 is formed over the substrate 110 lining the side walls of the isolation trenches 130. The oxide layer 140 may be formed by a thermal process such as rapid thermal annealing (RTA).
The process then continues to step 260 to perform annealing of the semiconductor substrate 110. An ion implantation is performed at step 280 over the isolation trenches 130 to form doped regions 160 below the isolation trenches 130. The doped regions 160 may be formed by implantation methods known in the art. In an illustrative embodiment, boron 150 is used as dopants to form the doped region and is implanted with an energy ranges from about 400 to 1500 KeV and a tilt angle from about 0 to about 90 degrees. The dosage of boron used is from about 1×1012 to 1×1014 atoms/cm2.
At step 300, isolation trenches 130 are filled with dielectric material to form shallow trench isolation (STI) features. One method of filling is by performing a high density plasma (HDP) chemical vapor deposition (CVD) to fill the isolation trenches 130. Once the isolation trenches 130 are filled, isolation features, such as isolation features 125, are formed, the process continues to step 320, where a chemical mechanical planarization (CMP) is performed to planarize the substrate 110, such that the upper surface of the isolation features 125 is substantially coplanar with the front surface of the semiconductor substrate 110.
Referring to FIG. 5, a flow diagram of a second exemplary process for reducing crosstalk in image sensors using ion implantation is depicted. The process begins at step 360 where a substrate is provided having a plurality of sensor elements formed therein. Next, at step 380, the substrate is patterned to form isolation trenches 130. The substrate may be patterned using processes known in the art or techniques to be developed in the future. One example is by applying a photoresist layer on the substrate and patterned using a lithography process. Then, etching is performed on the substrate to form the isolation trenches 130.
Once the isolation trenches 130 are formed, the process continues to step 400 where an oxide layer may be formed over the substrate 110 lining the side walls of the isolation trenches 130. The oxide layer 140 may be formed by a thermal process such as rapid thermal annealing (RTA). The process then continues to step 420 to perform annealing of the oxide layer. At step 440, isolation trenches are filled with dielectric material. One method of filling is by performing a high density plasma (HDP) chemical vapor deposition (CVD) to fill the isolation trenches. Once the isolation trenches 130 are filled, isolation features are formed, the process continues to step 460, where a chemical mechanical planarization (CMP) is performed to planarize the substrate 110, such that the upper surface of the isolation features is substantially coplanar with the front surface of the semiconductor substrate 110.
An ion implantation is performed at step 480 over the isolation trenches 130 to form doped regions 160 below the isolation trenches 130. The doped regions 160 are formed by implantation methods known in the art. In an illustrative embodiment, boron is used as dopants to form the doped region and is implanted with an energy ranges from about 400 to 1500 KeV and a tilt angle from about 0 to about 90 degrees. The dosage of boron used is from about 1×1012 to 1×1014 atoms/cm2.
A cross section of image sensor formed using the second exemplary process is described below with reference to FIG. 6. In this illustrative embodiment, the isolation trenches 130 of semiconductor device 100 are filled prior to the ion implantation. The isolation trenches 130 may be filled using a high density plasma (HDP) chemical vapor deposition (CVD) process commonly known in the art. The isolation trenches 130 may be filled with suitable material including dielectric, metal, an opaque material, or combination thereof. After the isolation trenches 130 are filled, isolation features, such as isolation features 125, are formed, a chemical mechanical planarization (CMP) is performed to planarize the substrate 110, such that the upper surface of the isolation features 125 is coplanar with the front surface of the semiconductor substrate 110.
The doped regions 160 may be formed by implantation methods known in the art. In this illustrative embodiment, boron 150 is used as dopants to form the doped region and is implanted with an energy range of between about 400 to 1500 KeV and a tilt angle from about 0 to about 90 degrees. The dosage of boron used is between about 1×1012 to 1×1014 atoms/cm2. By implanting ions with different energy values, different depth of the doped regions 160 may be achieved. A higher energy value provides a deeper ion implantation, for example, in the center of the doped regions 160. A lower energy value provides a shallow implantation, for example, doped regions 160 around the sidewall of the isolation trenches 125.
In order to effectively reduce crosstalk between the sensor elements 120, the depth d2 of the doped regions 160 is preferably greater than the depth d1 of the sensor elements 120. For example, the depth d1 of the sensor elements 120 is from about 0.3 to 0.8 um. The depth d2 of the doped regions 160 is preferably greater than about 1 um or about twice the depth d1 of the sensor elements 120. By having a depth d2 greater than the junction depth d1 of the sensor elements 120, the doped regions 160 may effectively reduce cross-talk between the sensor elements 120. In this example, the depth d1 of the sensor elements 120 is measured from the upper surface of the semiconductor device 100 to the lower surface of the sensor elements 120. The depth d2 of the doped regions 160 is measured from the upper surface of the semiconductor device 100 to the back surface of the semiconductor substrate 110. The depth d2 of the doped regions 160 is also preferably greater than the depth d3 of the isolation features. In addition, the width w1 of the doped regions 160 is wider than the width w2 of the upper portion of the isolation features and the width w3 of the lower portion of the isolation features.
In addition to semiconductor substrate 110, semiconductor device 100 may comprise a second semiconductor substrate 170 under the semiconductor substrate 110. The second semiconductor substrate 170 also has a first-type conductivity, for example P-type conductivity. The concentrate of the second semiconductor substrate 170 is higher than the first semiconductor substrate 110. For example, the second semiconductor substrate 170 may be a heavy doped P-type substrate (P+) while semiconductor substrate 110 may be a lightly doped P-type substrate (P−).
Referring to FIG. 7, a graph illustrating relationships between crosstalk and the depth of doped regions is depicted. Graph 600 includes a X-axis 620 indicating the number of electrons that pass between sensor elements. Graph 600 also includes a Y-axis 640 indicating the depth of the doped region in um. As shown in graph 600, the number of electrons decreases as the depth of the doped region increases. In other words, the amount of crosstalk is reduced with a deeper doped region. In this example, the amount of crosstalk is reduced with the depth of the doped region being greater than 1 um. Therefore, by implanting ions to form doped regions 160, the amount of crosstalk between the plurality of sensor elements is reduced.
In addition to forming isolation features such as shallow trench isolation, isolation features such as local oxidation of silicon (LOCOS) may be formed. In that process, a layer of silicon nitride is deposited and patterned to serve as an oxidization barrier. The layer is etched to allow thermal oxide growth. After thermal oxidization, the nitride and the barrier oxide is removed to expose bare silicon surface regions ready for device formation. The ion implantation process to form the doped regions 160 between the sensor elements 120 may be implemented after the formation of LOCOS. Alternatively, the ion implantation may be implemented after the patterned barrier layer is formed but prior to the thermal oxide growth.
Thus, the present disclosure provides an image sensor semiconductor device. The semiconductor device includes a plurality of sensor elements formed within a semiconductor substrate; a plurality of isolation regions formed between the plurality of sensor elements; and a plurality of doped regions formed substantially underlying the plurality of isolation regions in the semiconductor substrate.
The present disclosure also provides an image sensor semiconductor device. The image sensor semiconductor device include a substrate having a front surface and a back surface; a plurality of sensor elements formed on the front surface of the substrate; a plurality of isolation regions disposed horizontally between the plurality of sensor elements; and a plurality of doped regions disposed vertically under the plurality of isolation regions in the substrate.
Each of the plurality of sensor elements may be selected from the group consisting of complementary metal-oxide-semiconductor (CMOS) image sensor, charge-coupled device sensor, active pixel sensor, passive pixel sensor, and combinations thereof. The depth of the plurality of doped regions is preferably greater than the depth of the plurality of sensor elements.
The present disclosure also provides a method to fabricate a semiconductor device. The method includes: providing a semiconductor substrate; forming a plurality of sensor elements within the semiconductor substrate; forming a plurality of isolation features between the plurality of sensor elements; and performing an ion implantation process to form a plurality of doped regions substantially underlying the plurality of isolation features.
The forming of the plurality of isolation features include etching the substrate to form a plurality of isolation features and filling the plurality of isolation features with a dielectric material. The etching may be plasma etching, wet etching, and combinations thereof. The filling of the plurality of isolation features may include performing a high density plasma chemical vapor deposition process. In addition, an oxide layer is formed over the substrate and an annealing process is performed on the oxide layer. The annealing process may be selected from the group consisting of a thermal annealing, a laser annealing, and a combination thereof.
The method of fabricating the semiconductor device further comprises planarizing the substrate before or after the filling of the plurality of isolation features. The planarizing of the substrate may include performing a chemical mechanical planarization on the substrate, such that the upper surface of the isolation features is coplanar with the front surface of the semiconductor substrate.
The foregoing has outlined features of several embodiments so that those skilled in the art may better understand the detailed description that follows. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions and alterations herein without departing from the spirit and scope of the present disclosure.

## Claims

1. A method of fabricating a semiconductor device, comprising:
providing a semiconductor substrate having a first-type conductivity, the substrate having a first side and an opposing second side;
forming a plurality of sensor elements in the semiconductor substrate adjacent the first side;
forming an upwardly open recess in the substrate through the first side, the recess having a maximum width;
performing an ion implantation process through the first side and a surface of the substrate within the recess to form a doped region having the first-type conductivity using at least two different implant energies, the doped region extending the entire thickness of the semiconductor substrate from the first side to the second side of the semiconductor substrate and having a portion that is located below the recess; and
thereafter, filling the recess with a dielectric material;
wherein the portion of the doped region is wider than the maximum width of the recess.

2. The method of claim 1, further including planarizing the dielectric material using a chemical mechanical polishing process, and wherein the forming the recess includes etching the substrate.

3. The method of claim 1, wherein the filling the recess includes performing a high density plasma chemical vapor deposition process.

4. The method of claim 1, further including:
forming an oxide layer over the surface of the semiconductor substrate within the recess; and
performing an annealing process on the oxide layer.

5. A method of fabricating a semiconductor device, comprising:
providing a semiconductor substrate having a first-type conductivity;
forming a plurality of sensor elements in the semiconductor substrate;
forming an isolation feature between the plurality of sensor elements, the isolation feature having a maximum width, wherein the forming the isolation feature includes etching the semiconductor substrate to form an isolation trench and completely filling the isolation trench with a dielectric material; and
after forming the isolation feature, performing an ion implantation process to form a doped region having the first-type conductivity substantially underlying the isolation feature using at least two different implant energies that range from about 400 KeV to about 1500 KeV, wherein the isolation trench is completely filled with the dielectric material while the ion implantation process is performed;
wherein the performing the ion implantation process is carried out so that a concentration of the doped region is in a range from about 1×1015 atoms/cm3 to about 1×1019 atoms/cm3, and the doped region underlying the isolation feature has a width that is greater than the maximum width of the isolation feature.

6. The method of claim 5, wherein the two different implant energies are in a range from about 600 KeV to about 900 KeV.

7. The method of claim 5, wherein the performing the ion implantation process includes using an implant dosage that is in a range from about 1×1012 atoms/cm2 to about 1×1014 atoms/cm2.

8. The method of claim 5, wherein the forming the plurality of sensor elements is carried out so that the plurality of sensor elements each include a depth that is in a range from about 0.3 um to about 0.8 um.

9. The method of claim 8, wherein the performing the ion implantation process is carried out so that the doped region has a further depth that is about twice the depth of the plurality of the sensor elements.

10. A method of fabricating a semiconductor device, comprising:
providing a substrate having a first-type conductivity, the substrate having a front surface and a back surface;
forming a nitride layer over the front surface of the substrate;
forming an opening in the nitride layer to expose a first region of the substrate;
forming a dielectric isolation feature in the first region;
removing the nitride layer;
implanting a dopant having the first type conductivity into a second region of the substrate to form a dopant region, the second region being located below the first region, the dopant region extending the entire thickness of the substrate from the front surface to the back surface of the substrate; and
forming first and second pixels in third and fourth regions of the substrate, respectively;
wherein the first region is disposed between the third and fourth regions, and wherein the forming the dielectric isolation feature and the implanting are carried out so that a portion of the second region that is closest to the back surface is wider than the dielectric isolation feature, and wherein the implanting is carried out using at least two different implantation energies.

11. The method of claim 10, wherein the forming the dielectric isolation feature includes growing silicon oxide through thermal oxidation.

12. The method of claim 10, wherein the implanting includes implanting the dopant using an implantation energy that is in a range from about 400 KeV to about 1500 Kev and an implant dosage that is in a range from about 1×1012 atoms/cm2 to about 1×1014 atoms/cm2.

13. The method of claim 10, wherein the forming the first and second pixels is carried out so that the first and second pixels each include a depth that is in a range from about 0.3 um to about 0.8 um.

14. The method of claim 13, wherein the implanting is carried out so that a combined depth of the first and second regions is about twice the depth of one of the first pixel and the second pixel.

15. The method of claim 1, wherein the performing the ion implantation process is carried out so that the doped region has an approximately rectangular shape.

16. The method of claim 10, wherein the second region extends closer to the back surface of the substrate than the third and fourth regions.

17. A method of fabricating a semiconductor device, comprising:
providing a substrate having a first-type conductivity, the substrate having a front side and an opposing back side;
forming a trench in the substrate through the front side;
forming a liner oxide layer on a surface of the trench;
implanting, through the trench and the liner oxide layer, a plurality of dopant ions having the first type conductivity into the substrate, thereby forming an implanted region that at least partially surrounds sidewalls of the trench but is substantially non-conformal to the trench, wherein a first lateral dimension of the implanted region measured immediately below the trench is not substantially different from a second lateral dimension of the implanted region measured at a depth substantially below the trench, wherein the implanted region extends the entire thickness of the substrate from the front side to the back side of the substrate;
filling the trench with a dielectric material after the implanting; and
forming first and second radiation-sensing regions in the substrate, the first and second radiation-sensing regions being formed on opposite sides of the implanted region.

18. The method of claim 17, wherein the implanted region has substantially uniform lateral dimensions throughout a majority portion of the implanted region, the majority portion including a first sub-portion that surrounds the trench and a second sub-portion that is located below and substantially away from the trench.

19. The method of claim 17, wherein the liner oxide layer is on opposing sidewalls of the trench and in physical contact with the implanted region.

20. The method of claim 10, further comprising forming a trench through the front surface in the first region of the substrate,
wherein forming the dielectric isolation feature includes forming the dielectric isolation feature in the trench of the first region, the dielectric isolation feature completely filling the trench, and
wherein implanting the dopant having the first type conductivity into the second region of the substrate occurs after forming the dielectric isolation feature in the trench of the first region and while the trench is completely filled with the dielectric isolation feature.