# Polyvinyl Chloride and Copolymers (PVC) Production

Beyond The Floor Analysis

Resins

April 6, 2011

Worksheet Name BTF Calcs TO Cost Summary Dryer Summary Emission Point Flow Rate Data Non-CBI Production Information CostIndex DataforPollutant Concentrations

# Polyvinyl Chloride and Copolymers (PVC) Production

Beyond The Floor Analysis

Description Summary of Beyond the Floor Impacts - Resins Air Compliance Advisor Program Input-Outputs for Thermal Oxidizers Dryer Flow Rate Estimation for Facilities Facility Submitted Dryer Information Non-CBI Resin Production Information Chemical Engineering Cost Index OxyVinyls Dryer Stack Test DataVinyl Chloride Total Organic HAP (fraction) Vinyl Chloride Total Organic HAP DSCFM

Formosa Delaware 15.4 28.1 0.98 15.1 27.5 101,882 PolyOne Henry 9.1 9.1 0.98 9.0 8.9 89,343 PolyOne Pedricktown 9.9 15.0 0.98 9.7 14.7 92,477

Dow Midland 0.3 52.7 0.98 0.320 51.65 15,357 Formosa Baton Rouge 0.9 78.9 0.98 0.913 77.31 652,045 Formosa Point Comfort 0.2 26.6 0.98 0.206 26.10 1,112,865 Georgia Gulf Aberdeen 0.3 51.1 0.98 0.310 50.08 711,606 Georgia Gulf Plaquemine 1.5 247.6 0.98 1.503 242.62 852,674 OxyVinyls Deer Park 0.2 14.4 0.98 0.236 14.13 391,854 OxyVinyls Pasadena 1.5 235.5 0.98 1.452 230.76 1,493,747 OxyVinyls Pedricktown 0.3 23.3 0.98 0.287 22.79 249,219 Shintech Addis 0.8 111.8 0.98 0.745 109.54 443,578 Shintech Freeport 0.4 54.5 0.98 0.368 53.40 2,272,752 Shintech Plaquemine 0.4 56.5 0.98 0.378 55.37 924,775 We stlake Calvert City 0.4 60.0 0.98 0.364 58.80 782,065 We stlake Geismar 0.5 3.9 0.98 0.5 3.82 407,528 42.1 1068.9 41.3 1047.5 Totals Resins Beyond-The-Floor Analysis Estimated Dry er Flow Rate Company Facility BTF Reductions, tons/yr TO Redux Part 63 Part 63 Floor Emissions, tons/yrFormosa Delaware

PolyOne Henry PolyOne Pedricktown

Dow Midland Formosa Baton Rouge Formosa Point Comfort Georgia Gulf Aberdeen Georgia Gulf Plaquemine OxyVinyls Deer Park OxyVinyls Pasadena OxyVinyls Pedricktown Shintech Addis Shintech Freeport Shintech Plaquemine We stlake Calvert City We stlake Geismar Totals Resins Beyond-The-Floor Analysis

Company Facility Moisture Temperature Supp Fuel Electricity Vinyl Chloride Total Organic HAP % oF 2010 2010 Ft^3/yr kW h/yr

3.657 6.690 8.9 130.6 $3,917,879 $1,469,462 122,680,858 6,770,114 2.175 2.167 8.9 130.6 $2,409,618 $936,040 107,847,525 5,936,871 2.355 3.571 8.9 130.6 $3,620,766 $1,010,244 111,536,304 6,145,171

0.078 12.548 8.9 130.6 $676,134 $250,951 18,210,000 1,020,481 0.222 18.784 8.9 130.6 $21,998,070 $8,470,901 786,867,987 43,328,714 0.050 6.340 8.9 130.6 $37,255,660 $14,355,682 1,344,871,287 73,950,429 0.075 12.167 8.9 130.6 $23,879,753 $6,966,456 859,376,238 47,286,571 0.365 58.945 8.9 130.6 $28,336,452 $8,307,374 1,026,528,053 56,660,571 0.057 3.433 8.9 130.6 $13,078,777 $3,877,817 473,485,149 26,038,857 0.353 56.063 8.9 130.6 $49,987,856 $14,504,200 1,801,709,571 99,260,286 0.070 5.538 8.9 130.6 $8,572,627 $2,511,001 300,841,584 16,560,714 0.181 26.614 8.9 130.6 $14,712,950 $4,368,024 534,287,129 29,476,000 0.090 12.973 8.9 130.6 $75,297,743 $22,002,896 2,746,501,650 151,025,714 0.092 13.452 8.9 130.6 $31,313,481 $9,035,925 1,116,996,700 61,451,714 0.089 14.287 8.9 130.6 $26,105,744 $7,640,876 944,408,581 51,968,571 0.120 0.929 8.9 130.6 $13,573,966 $4,028,385 492,574,257 27,080,429 354,737,476 $ 109,736,235

$ 12,788,722,871 703,961,210 Stream Parameters Pollutant Mass Flow Rate - ACA Input lb/hr Secondary Impacts TO TCI TO TA CRTO Cost Summary

TCI (2008 Dollars) Total Ann. Costs (2008 Dollars)

TCI (2010 Dollars) Total Ann. Costs (2010 Dollars)

Include in Summation (x=yes) x x

Baton Rouge Delaware Program Inputs Hours of Operation (per year) 8400 8400 Total Dryer Exhaust Flow Rate (SCFM) 715,746.09 111,835.33 Total Dryer Exhaust Flow Rate (DSCFM) 652,045 101,882 Stream Temperature (F) 130.6 130.6 VC Flow Rate (lb/hr) (Assumed ALL TOH) 19 7 Op. Labor Cost 34.6 34.6 Electricity

Cost ($/kW h) 0.07 0.07 Interest Rate 0.07 0.07 Equipm ent Life 20 20 Program Outputs Min % O2 Required 19.8 Op. Temp (R) 2660 Auxiliary Air Req (CFM) 0 Min Fuel Req (CFM) 1534 Auxiliary Fuel Req (CFM) 1561 243 Auxiliary Fule Req (Ft^3 per year) 786867987 122680858 Electricity

Requirments (kW h/y r) 43328714 6770114 Auxiliary Fuel Cost ($/y r) $2,384,210 Equipm ent Cost* 1.37E+07 Auxilary Equipm ent Cost 0 Total Equipment Cost 1.37E+07 Instrumentation Cost 1.37E+06 Sales Tax $412,341 Freight Cost $687,235 Purchased Equipment Cost 1.62E+07 Foundation Cost 1.30E+06 Equipm ent Erection Cost 2.27E+06 Electrical Cost $648,750 Piping Cost $324,375 Insulation Cost $162,188 Painting Cost $162,188 Direct Installation Cost 4.87E+06 Total Direct Capital Cost 2.11E+07 Engineering Cost 1.62E+06 Field Cost $810,938 Contractor Cost 1.62E+06 Start Up Cost $324,375 Performance Test Cost $162,188 Contingencies Cost $486,562 FormosaTotal Indirect Capital Cost 5.03E+06

Total Capital Investment (2008 Dollars) 2.61E+07 4.65E+06 Total Capital Investment (2010 Dollars) $21,998,070.20 $3,917,879.20 Operating Labor $18,152 $18,152 Supervisory

Labor $2,723 $2,723 Maintenance Labor $19,968 $19,968 Maintenance Materials $19,968 $19,968 Replacement Parts $0 $0 Utilities 5.42E+06 $845,631 Electricity** 3.03E+06 $473,908 Total Direct Annual Cost 5.48E+06 $906,441 Overhead $36,486 $36,486 Adm inistrative Charges $522,244 $93,012 Property Taxes $261,122 $46,506 Insurance $261,122 $46,506 Capital Recovery

Factor 0.0943929 0.0943929 Capital Recovery 2.46E+06 $438,984 Total Indirect Annual Cost 3.55E+06 $661,495 Recovery

Credit $0 $0 Total Annualized Cost (2008 Dollars) 9.02E+06 1.57E+06

2010 Cost Calculations Overhead (2010 Dollars) $36,486.1 $36,486.1 Adm inistrative Charges (2010 Dollars) $439,961.40 $78,357.58 Property Taxes (2010 Dollars) $219,980.70 $39,178.79 Insurance (2010 Dollars) $219,980.70 $39,178.79 Capital Recovery

Factor 0.0943929 0.0943929 Capital Recovery

(2010 Dollars) $2,076,461.64 $369,819.98 Total Indirect Annual Cost (2010 Dollars) $2,992,871 $563,021 Recovery

Credit Total Annualized Cost (2010 Dollars) $8,470,901 $1,469,462

* - Does not include auxialiary equipm ent ** - Represented as subpart of Utilities$413,923,096 In-Cell Calculation

$143,507,188 Note: use "x" in include in summation line to select which facilities are included in the industry total cost estimate $348,707,092 $107,789,951

x x x x

Point Comfort Ab erdeen Plaquemine Deer Park

8400 8400 8400 8400 1,221,585.88 781,126.75 935,975.66 430,135.87 1,112,865 711,606 852,674 391,854 130.6 130.6 130.6 130.6 6 12 59 3 34.6 34.6 34.6 34.6 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 20 20 20 20

2668 1705 2037 939 1344871287 859376238 1026528053 473485149 73950429 47286571 56660571 26038857 Georgia Gulf4.42E+07 2.83E+07 3.36E+07 1.55E+07

$37,255,660.49 $23,879,753.46 $28,336,451.51 $13,078,776.98 $18,152 $18,152 $18,152 $18,152 $2,723 $2,723 $2,723 $2,723 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $0 $0 $0 $0 9.25E+06 5.91E+06 7.08E+06 3.26E+06 5.18E+06 3.31E+06 3.97E+06 1.82E+06 9.31E+06 5.97E+06 7.14E+06 3.32E+06 $36,486 $36,486 $36,486 $36,486 $884,466 $566,916 $672,719 $310,497 $442,233 $283,458 $336,360 $155,248 $442,233 $283,458 $336,360 $155,248 0.0943929 4.17E+06 2.68E+06 3.18E+06 1.47E+06 5.98E+06 3.85E+06 4.56E+06 2.12E+06 $0 $0 $0 1.53E+07 9.82E+06 1.17E+07 5.44E+06

$36,486.1 $36,486.1 $36,486.1 $36,486.1 $745,113.21 $477,595.07 $566,729.03 $261,575.54 $372,556.60 $238,797.53 $283,364.52 $130,787.77 $372,556.60 $238,797.53 $283,364.52 $130,787.77 0.0943929 0 0 0 $3,516,669.83 $0.00 $0.00 $0.00 $5,043,382 $991,676 $1,169,944 $559,637

$14,355,682 $6,966,456 $8,307,374 $3,877,817Note: use "x" in include in summation line to select which facilities are included in the industry total cost estimate

x x x

Pasadena Pedricktown Henry Pedricktown Ad dis

8400 8400 8400 8400 8400 1,639,677.95 273,566.42 98,070.98 101,512.07 486,913.81 1,493,747 249,219 89,343 92,477 443,578 130.6 130.6 130.6 130.6 130.6 56 6 2 4 27 34.6 34.6 34.6 34.6 34.6 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 20 20 20 20 20

3575 597 214 221 1060 1801709571 300841584 107847525 111536304 534287129 99260286 16560714 5936871 6145171 29476000 OxyVinyls PolyOne5.93E+07 1.02E+07 2.86E+06 4.30E+06 1.75E+07

$49,987,855.94 $8,572,627.45 $2,409,617.74 $3,620,766.00 $14,712,950.14 $18,152 $18,152 $18,152 $18,152 $18,152 $2,723 $2,723 $2,723 $2,723 $2,723 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $0 $0 $0 $0 $0 1.24E+07 2.07E+06 $742,359 $768,117 3.68E+06 6.95E+06 1.16E+06 $415,581 $430,162 2.06E+06 1.25E+07 2.13E+06 $803,169 $828,927 3.74E+06 $36,486 $36,486 $36,486 $36,486 $36,486 1.19E+06 $203,518 $57,206 $85,959 $349,291 $593,367 $101,759 $28,603 $42,979 $174,646 $593,367 $101,759 $28,603 $42,979 $174,646

5.60E+06 $960,532 $269,990 $405,694 1.65E+06 8.01E+06 1.40E+06 $420,887 $614,098 2.38E+06

2.05E+07 3.54E+06 1.22E+06 1.44E+06 6.13E+06

$36,486.1 $36,486.1 $36,486.1 $36,486.1 $36,486.1 $999,757.12 $171,452.55 $48,192.35 $72,415.32 $294,259.00 $499,878.56 $85,726.27 $24,096.18 $36,207.66 $147,129.50 $499,878.56 $85,726.27 $24,096.18 $36,207.66 $147,129.50

0 0 0 0 0 $0.00 $0.00 $0.00 $0.00 $0.00 $2,036,000 $379,391 $132,871 $181,317 $625,004

$14,504,200 $2,511,001 $936,040 $1,010,244 $4,368,024x x x x Dow Freeport Plaquemine Midland Calvert City

8400 8400 8400 8400 2,494,788.06 1,015,120.66 16,857.21 858,468.96 2,272,752 924,775 15,357 782,065 130.6 130.6 130.6 130.6 13 13 13 14 34.6 34.6 34.6 34.6 0.07 0.07 0.07 0.07 0.07 0.07 0.07 0.07 20 20 20 20

5449 2216 36 1874 2746501650 1116996700 18210000 944408581 151025714 61451714 1020481 51968571 Shintech Westlake8.94E+07 3.72E+07 $802,586 3.10E+07

$75,297,742.59 $31,313,480.66 $676,133.88 $26,105,743.64 $18,152 $18,152 $18,152 $18,152 $2,723 $2,723 $2,723 $2,723 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $19,968 $0 $0 $0 $0 1.89E+07 7.69E+06 $126,610 6.50E+06 1.06E+07 4.30E+06 $71,434 3.64E+06 1.90E+07 7.75E+06 $187,420 6.56E+06 $36,486 $36,486 $36,486 $36,486 1.79E+06 $743,395 $16,052 $619,761 $893,801 $371,698 $8,026 $309,881 $893,801 $371,698 $8,026 $309,881

8.44E+06 3.51E+06 $75,758 2.93E+06 1.20E+07 5.03E+06 $144,348 4.20E+06

3.10E+07 1.28E+07 $331,768 1.08E+07

$36,486.1 $36,486.1 $36,486.1 $36,486.1 $1,505,954.85 $626,269.61 $13,522.68 $522,114.87 $752,977.43 $313,134.81 $6,761.34 $261,057.44 $752,977.43 $313,134.81 $6,761.34 $261,057.44

0 0 0 0 $0.00 $0.00 $0.00 $0.00 $3,048,396 $1,289,025 $63,531 $1,080,716

$22,002,896 $9,035,925 $250,951 $7,640,876x

Geismar

8400 447,341.31 407,528 130.6 1 34.6 0.07 0.07 20

977 492574257 27080429 Westlake1.61E+07

$13,573,965.65 $18,152 $2,723 $19,968 $19,968 $0 3.39E+06 1.90E+06 3.45E+06 $36,486 $322,252 $161,126 $161,126

1.52E+06 2.20E+06

5.65E+06

$36,486.1 $271,479.31 $135,739.66 $135,739.66

0 $0.00 $579,445

$4,028,385Min Max Avg

Formosa Baton Rouge 9 323,496 240,226 Formosa Delaware 2 Formosa Point Com fort 1 Formosa Point Com fort SPVC 3 Georgia Gulf Aberdeen 7 Georgia Gulf Plaquem ine 16 Oxy Vinyls Deer Park 2 Oxy Vinyls Pasadena 7 325,468 Oxy Vinyls Pedricktown 3 81,055 PolyOne Henry 7 154,826 96,576 76,007,292 PolyOne Pedricktown 2 39,809,584 Shintech Addis 1 Shintech Freeport 1 Shintech Plaquem ine 1 Dow Midland 1 21,600,000 We stlake Calvert City 5 1,100,000,000 We stlake Geismar 1 33,000 76,000 44,250 476,390,000

*Estimate from Survey

Subm ission Annual Production (Lbs)

Average of Avg Dry

Flow Rate per Lb Sum of Dryer Flow Rates (DSCFM) Number of Dryers* Facility CompanyCompany Name Facility Name ProcessUnitID

Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Formosa Plastics Corporation USA Formosa Plastics Corporation Baton Rouge P-1 Baton Rouge Sum Oxy Vinyls, LP Oxy Viny ls Pasadena P-3 Oxy Vinyls, LP Oxy Viny ls Pasadena P-4 Oxy Vinyls, LP Oxy Viny ls Pasadena P-5 Oxy Vinyls, LP Oxy Viny ls Pasadena P-6 Oxy Vinyls, LP Oxy Viny ls Pasadena P-7 Oxy Vinyls, LP Oxy Viny ls Pasadena P-8 Oxy Vinyls, LP Oxy Viny ls Pasadena P-9 Pasadena Sum Oxy Vinyls, LP Oxy Viny ls Pedricktown P-1 Oxy Vinyls, LP Oxy Viny ls Pedricktown P-2 Oxy Vinyls, LP Oxy Viny ls Pedricktown P-2 Pedricktown Sum PolyOne Corporation PolyOne Henry P-2 PolyOne Corporation PolyOne Henry P-3 PolyOne Corporation PolyOne Henry P-4 PolyOne Corporation PolyOne Henry P-4 PolyOne Corporation PolyOne Henry P-5 Henry Sum We stlake Chemical Corporation We stlake Geismar P-1 Geismar SumEm issionPointID Control Equip Desc Process Equip Desc MinOfMinOfFlowRateMin_Dscfm

MaxOfMaxOfFlowRateMax_Dscfm EP-10 Scrubber Resin Dryer 0 28310 EP-11 Scrubber Resin Dryer 0 55500 EP-13 Scrubber Resin Dryer 48350 48350 EP-6 Scrubber Resin Dryer 0 45909 EP-7 Scrubber Resin Dryer 0 45909 EP-8 Scrubber Resin Dryer 0 45909 EP-9 Scrubber Resin Dryer 0 53609 48350 323496 EP-319 Fabric Filter Resin Dryer EP-419 Fabric Filter Resin Dryer EP-519 Fabric Filter Resin Dryer EP-619 Fabric Filter Resin Dryer EP-719 Fabric Filter Resin Dryer EP-819 Fabric Filter Resin Dryer EP-919 Fabric Filter Resin Dryer 0 0 EP-102 Scrubber Resin Dryer 0 33455 EP-201 Scrubber Resin Dryer 0 25800 EP-202 Scrubber Resin Dryer 0 21800 0 81055 EP-2 Fabric Filter Resin Dryer 4500 102900 EP-2 Fabric Filter Resin Dryer 6786 EP-2 Fabric Filter Resin Dryer 7800 EP-3 Fabric Filter Resin Dryer 8500 EP-2 Fabric Filter Resin Dryer 28840 4500 154826 EP-4 Resin Dryer 33000 76000 33000 76000AvgOfAvgOfFlowRateAvg_Dscfm 24715 48720 48350 36721 33672 28174 19874 240226 43278 43278 43278 43278 43278 43278 65800 325468 2200

2200 44650 6786 7800 8500 28840 96576 44250 442502008 Production From Survey Company Name CertainTeed Corporation Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP PolyOne Corporation PolyOne Corporation The Dow Chemical Company Union Carbide Corporation We stlake Chemical Corporation We stlake Chemical Corporation

2006 Capacity

Information

CompanyName CertainTeed Corporation Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Formosa Plastics Corporation USA Georgia Gulf Corporation Georgia Gulf Corporation Oxy Vinyls, LP Oxy Vinyls, LP Oxy Vinyls, LP PolyOne Corporation PolyOne Corporation Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office Shintech, Inc. Corporate Office The Dow Chemical Company Union Carbide Corporation We stlake Chemical Corporation We stlake Chemical CorporationFacility Name

Lake Charles Poly me r Plant Formosa Plastics Corporation Baton Rouge Formosa Plastics Corporation Deleware City Formosa Plastics Corporation Point Comfort - PVC Unit Formosa Plastics Corporation, Point Comfort - Specialty Poly viny l Chloride (SPVC) Unit Oxy Vinyls Deer Park Oxy Vinyls Pasadena Oxy Vinyls Pedricktown PolyOne Henry PolyOne Pedricktown Dow Midland - SARAN Resins Union Carbide Texas City We stlake Calvert City We stlake Geismar

FacilityName Lake Charles Formosa Baton Rouge Formosa Deleware City Formosa Point Comfort Formosa (SPVC) Unit Georgia Gulf Aberdeen Georgia Gulf Plaquemine Oxy Vinyls Deer Park Oxy Vinyls Pasadena Oxy Vinyls Pedricktown PolyOne Henry PolyOne Pedricktown Shintech Addis Shintech Freeport Shintech Plaquem ine Dow Midland Union Carbide Texas City We stlake Calvert City We stlake GeismarSum OfProduction_LbsOfResin 447348640

76007291.85 39809584 21600000 41990283 1100000000 476390000

US Tons (x1000) Lbs

240.30358 480,607,160 458.56096 917,121,920 71.65015 143,300,300 782.6401 1,565,280,200

500.44874 1,000,897,480 599.65664 1,199,313,280 275.5775 551,155,000 1050.50143 2,101,002,860 175.26729 350,534,580 62.83167 125,663,340 65.03629 130,072,580 311.95373 623,907,460 1598.3495 3,196,699,000 650.3629 1,300,725,800

70.54784 141,095,680 400.13853 800,277,060 286.6006 573,201,2001999 2008 2010

CE Index 392.1 619.3 539.1 Equipment 436.8 761 641.1 Heat exchangers and tanks 371.5 784.2 587.3 Process machinery 437.5 680.7 610.3 pipe, valves & fittings 540.9 881.5 796.1

Process instruments 364.3 457.8 420.5 pumps and compressors 657.8 872.9 903.4 electrical equipment 336.1 468.1 468.4 structural supports & misc. 415.6 843.9 660 Construction Labor 295 325.3 330.2 Buildings 382.9 529.8 500.5 Engineering and Supervision 339.5 352.3 342.4

Aug. 99' Final Aug . 08 Final Feb. '10 Final CE IndexCompany Facility Emission Point Compound Run1 (ppbv) Run 2 (ppbv)

Oxy Vinyls Pedricktown

DR-1H Rotary

Dryer 2-Propanone 849 1820 Oxy Vinyls Pedricktown

DR-1H Rotary

Dryer Viny l Chloride 126 137 Oxy Vinyls Pedricktown

DR-1H Rotary

Dryer Toluene 207 264 Oxy Vinyls Pedricktown

DR-1H Rotary

Dryer 2-propanol 161 254 Oxy Vinyls Pedricktown

DR-1H Rotary

Dryer Ethanol 106 140 Oxy Vinyls Pedricktown

DR-1H Rotary

Dryer Carbon Disulfide 108 173 Oxy Vinyls Pedricktown

DR-1H Rotary

Dryer Methylene Chlordie(Dichloromethane) 54 79 Oxy Vinyls Pedricktown

DR-1V Second Stage Venturi Viny l Chloride 449 456 Oxy Vinyls Pedricktown

DR-1V Second Stage Venturi 2-Propanone 27 28 Oxy Vinyls Pedricktown

DR-1V Second Stage Venturi Chloroethane 12.5 12.2 Oxy Vinyls Pedricktown

DR-2v First Stage Venturi Viny l Chloride 3 Oxy Vinyls Pedricktown

DR-2v First Stage Venturi Ethanol Oxy Vinyls Pedricktown

DR-2v First Stage Venturi chloroethane Oxy Vinyls Pedricktown

DR-2v First Stage Venturi 2-propanone 4.4 Oxy Vinyls Pedricktown

DR-2v First Stage Venturi Toluene

Data Company Facility Compound Min of Avg of Runs Max of Avg of Runs

Average of Avg of Runs Oxy Vinyls Pedricktown

2-propanol 170 170 170 2-Propanone 8.2 890.3333333 308.0666667 Carbon Disulfide 95.66666667 95.66666667 95.66666667 Chloroethane 12.53333333 13.2 12.86666667 Ethanol 28 98 63 Methylene Chlordie(Dichloromethane) 46 46 46 Toluene 3.5 235.5 119.5 Vinyl Chloride 48.4 439 265.9111111

Compound HC (Kj/mol) Btu/SCF* LFL (%) 2-propanol 1834 2014.887623 2.2 2-Propanone 1659 1822.627353 2.6 Carbon Disulfide 1076.9 1183.114766 1.3 Chloroethane 1284.9 1411.629829 3.8 Ethanol 1235 1356.808186 3.3 Methylene Chlordie(Dichloromethane) 513.88 564.5640411 14 Toluene 3734 4102.284832 1.2 Vinyl Chloride 1178 1294.18627 3.6 * SCF = 1 atm 25C Perry's Perry'sRun 3 (ppbv) Avg of Runs Percent Percent Add Use Data? 2 890.3 45.9% 45.9% x 668 310.3 16.0% 61.9% x

235.5 12.1% 74.0% x 95 170.0 8.8% 82.8% x 48 98.0 5.1% 87.8% x 6 95.7 4.9% 92.8% x 5 46.0 2.4% 95.1% x 412 439.0 87.0% 87.0% x 22 25.7 5.1% 92.1% x 12.9 12.5 2.5% 94.6% x 93.8 48.4 44.2% 44.2% x 28 28.0 25.6% 69.8% x 13.2 13.2 12.1% 81.9% x 12 8.2 7.5% 89.4% x 3.5 3.5 3.2% 92.6% x

Min of Flow (DSCFM)Max of Flow (DSCFM) Avg of Flow (DSCFM) Avg Temp 18,022 48,251 37,033 130.6 18,022 48,251 37,033 130.6 18,022 48,251 37,033 130.6 18,022 48,251 37,033 130.6 18,022 48,251 37,033 130.6 18,022 48,251 37,033 130.6 18,022 48,251 37,033 130.6 18,022 48,251 37,033 130.6

Auto Ignition Temps (Cel)

Auto Ignition (Far) 399 750.2 465 869 90 194 518.85 965.93 356 672.8 615 1139 535.85 996.53 471.85 881.33 Perry'sRun 1 Date Run 2 Date Run 3 Date Run 1 Flow (DSCFM) Run 2 Flow (DSCFM)

Run 3 Flow (DSCFM)

Avg Flow (DSCFM)

Run 1 Temp (F) Run 2 Temp (F) 8/9/2007 8/9/2007 8/9/2007 36,637 37,174 37,692 37,168 141 140 8/9/2007 8/9/2007 8/9/2007 36,637 37,174 37,692 37,168 141 140 8/9/2007 8/9/2007 8/9/2007 36,637 37,174 37,692 37,168 141 140 8/9/2007 8/9/2007 8/9/2007 36,637 37,174 37,692 37,168 141 140 8/9/2007 8/9/2007 8/9/2007 36,637 37,174 37,692 37,168 141 140 8/9/2007 8/9/2007 8/9/2007 36,637 37,174 37,692 37,168 141 140 8/9/2007 8/9/2007 8/9/2007 36,637 37,174 37,692 37,168 141 140 8/8/2007 8/8/2007 8/8/2007 18,122 18,021 17,922 18,022 117 116 8/8/2007 8/8/2007 8/8/2007 18,122 18,021 17,922 18,022 117 116 8/8/2007 8/8/2007 8/8/2007 18,122 18,021 17,922 18,022 117 116 8/7/2007 8/7/2007 8/7/2007 48,418 48,782 47,553 48,251 121 131 8/7/2007 8/7/2007 8/7/2007 48,418 48,782 47,553 48,251 121 131 8/7/2007 8/7/2007 8/7/2007 48,418 48,782 47,553 48,251 121 131 8/7/2007 8/7/2007 8/7/2007 48,418 48,782 47,553 48,251 121 131 8/7/2007 8/7/2007 8/7/2007 48,418 48,782 47,553 48,251 121 131

Average Moisture 8.902222 % Average Temperature 130.6Run 3 Temp (F) Avg Temp Run 1 Moisture (%) Run 2 Moisture (%)

Run 3 Moisture (%)

Run 1 CO2 % Run 2 CO2 % Run 3 CO2 % Run 1 O2 % 137 139.3333 11.5 12.4 11 0.6 0.61 0.47 20 137 139.3333 11.5 12.4 11 0.6 0.61 0.47 20 137 139.3333 11.5 12.4 11 0.6 0.61 0.47 20 137 139.3333 11.5 12.4 11 0.6 0.61 0.47 20 137 139.3333 11.5 12.4 11 0.6 0.61 0.47 20 137 139.3333 11.5 12.4 11 0.6 0.61 0.47 20 137 139.3333 11.5 12.4 11 0.6 0.61 0.47 20 114 115.6667 5.4 5.1 5.1 0.4 0.54 0.6 20.3 114 115.6667 5.4 5.1 5.1 0.4 0.54 0.6 20.3 114 115.6667 5.4 5.1 5.1 0.4 0.54 0.6 20.3 130 127.3333 6.2 6.4 9.3 0.28 0.37 0.37 20.4 130 127.3333 6.2 6.4 9.3 0.28 0.37 0.37 20.4 130 127.3333 6.2 6.4 9.3 0.28 0.37 0.37 20.4 130 127.3333 6.2 6.4 9.3 0.28 0.37 0.37 20.4 130 127.3333 6.2 6.4 9.3 0.28 0.37 0.37 20.4Run 2 O2% Run 3 O2% Run 1 PM (gr/dscf) Run 2 PM (gr/dscf)

Run 3 PM (gr/dscf) 20 20.2 0.0025 0.0022 0.0018 20 20.2 0.0025 0.0022 0.0018 20 20.2 0.0025 0.0022 0.0018 20 20.2 0.0025 0.0022 0.0018 20 20.2 0.0025 0.0022 0.0018 20 20.2 0.0025 0.0022 0.0018 20 20.2 0.0025 0.0022 0.0018 20.3 20.2 0.0034 0.0036 0.0039 20.3 20.2 0.0034 0.0036 0.0039 20.3 20.2 0.0034 0.0036 0.0039 20.1 20.2 0.0028 0.003 0.0015 20.1 20.2 0.0028 0.003 0.0015 20.1 20.2 0.0028 0.003 0.0015 20.1 20.2 0.0028 0.003 0.0015 20.1 20.2 0.0028 0.003 0.0015