## EMISSIONS TEST REPORT
BIG BEND POWER STATION FACILITY ID NUMBER 0570039 UNIT #1
MERCURY EMISSIONS SURVEY

Prepared for: Tampa Electric Company P.O. Box 111 Tampa, Florida 33601-0111

Prepared By: Tampa Electric Company Environmental, Health, & Safety Air Services Group

### TABLE OF CONTENTS
1.0 INTRODUCTION 1 2.0 SUMMARIZED DATA 2 3.0 SOURCE DESCRIPTIONS/TEST PROCEDURES 3 4.0 FIGURES TEST LOCATION 5

APPENDIX A DATA ANALYSIS Big Bend Unit 1 02/27/2009 Big Bend Unit 1 03/02/2009 Big Bend Unit 1 03/06/2009 Big Bend Unit 1 03/09/2009 Big Bend Unit 1 03/24/2009 Big Bend Unit 1 04/01/2009

## 1.0 INTRODUCTION During 2009, Tampa Electric Company’s Environmental, Health, & Safety Air Services Group performed numerous Mercur y (Hg) sampling/analysis tests as a part of an overall Hg survey at Big Bend Station. This report summarizes the activities at Big Bend Unit #1.

1

## 2.0 SUMMARIZED DATA EXECUTIVE SUMMARY Tampa Electric Company

Big Bend Power Station Mercury Testing Program Big Bend Power Station Common Stack 1 Wet (Unit 1 only) Test Date Test Duration, hrs Test Method c Concentration, ug/scm 02/27/2009 (a) 24 App K 2.04 02/27/2009 (b) 24 App K 2.05 03/02/2009 (a) 48 App K 1.96 03/02/2009 (b) 48 App K 1.90 03/06/2009 (a) 72 App K 2.31 03/06/2009 (b) 72 App K 2.17 03/09/2009 (a) 48 App K 1.33 03/09/2009 (b) 48 App K 1.31 03/24/2009 (a) 102 App K 1.87 03/24/2009 (b) 102 App K 1.81 04/01/2009 (a) 120 App K 1.50 04/01/2009 (b) 120 App K 1.42 c App K refers to 40CFR75 Appendix K – Quality assurance and Operating Procedures for Sorbent Trap Monitoring Systems.

2

## 3.0 SOURCE DESCRIPTIONS/TEST PROCEDURES Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM coordinates East 361.9 North 3075.0. The Boiler No. 1 sa mpling location consists of a shared circular stack 29.83 feet in diameter with four sa mple ports located 90 degrees apart on the stack circumfe rence. These ports are located downstream of the electrostatic prec ipitator and the FGD scrubber. The sampling ports were determined to be 8.77 diameters downstream of the transition ductwork and 2.43 diameters ups tream of the stack exit. During this test, Boiler No. 2 was not operating, and was isolated from the FGD module. A diagram of the stack sampling location is included in Figur e 1 along with other pertinent information on the test site.

Boiler No. 1 is serviced by an electrostati c precipitator for the control of flyash emissions, and a flue gas desulfurization (FGD) system for control of sulfur dioxide emissions.

Sampling was conducted using an Apex Instruments XC-6000 EPC Appendix K Sorbent Trap Monitoring Syst em. Sorbent traps were an alyzed in-house using an Ohio-Lumex RA – 915 + Zeeman Mercury Spectrometer with a RP-M324 attachment. Details of operations, cali brations, and Quality Assurance/Control activities are presented in th e appendices by test date,

3

## 4.0 FIGURES

4FIGURE 1 EXHAUST STACK 426.5 ’ EL. BIG BEND GENERATING STATION

BOILERS 1 and 2

OUTLET 

## N

PORT LOCATION PLAN

REVISED 1-18-00 COMMON STACK1 - WET TEST LOCATION

STACK DIAMETERS DOWNSTREAM FROM DISTURBANCE = 8.77
STACK DIAMETERS UPSTREAM FROM DISTURBANCE = 2.43
STACK DIAMETER = 29.8333 FT. ID. STACK AREA = 699.0246 SQ. FT.
PORT LENGTH’S = 62 IN. 499 ’ EL.

165 ’ EL. 261.5 ’

FGD

PRESSURIZED ANNULUS 72.5 ’

A

B C D

9 ’ EL.

5

### APPENDIX A DATA ANALYSISBIG BEND UNIT 1 02/27/2009Ohio Lumex Zeeman Mercur y

S p ectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration

n g Area Area/n g Pass/Fail

2000 241000 120.500 Pass 1000 127000 127.000 Pass

500 60200 120.400 Pass 100 11100 111.000 Pass

50 5610 112.200 Pass 10 1210 121.000 Pass Mean (Area/ng): 118.683 Standard Deviation: 6.0307 Relative Standard Deviation: 5 Pass Inverse of Mean, A: 0.00843

Area Pass/Fail Blank 52 Pass 500 n g Check 65200 Pass Unknown QA Tra p 470000
Value for unknown is: 4000 n g

Percent Recover y

is: 99 % QC has: Passed Appendix K Mercury Analyzer Caibration

Calculated n g

Calculated n g 46 91 16-Mar-09

494 1040 1980

3960 549 0.4 9.9No Description C, ng/g Area Maximum Time BB-CSO1W-24-48-72 hr. traps-03-16-09 1 condition 500 477 56700 8880 9:58:02 AM 2 Std__2000 2030 241000 35700 10:00:05 AM 3 Std__1000 1070 127000 14800 10:02:24 AM 4 Std__500 507 60200 15300 10:04:38 AM 5 Std__100 93 11100 1380 10:06:40 AM 6 Std__50 47 5610 1120 10:08:42 AM 7 Std__10 10 1210 271 10:10:42 AM 8 BLANK 0.4 52 5 10:12:57 AM 9 TRAP# 23721-A-SEC 1-24hr 1310 156000 7080 10:31:40 AM 10 SEC 2-A-24hr 2.5 296 24 10:36:37 AM 11 TRAP#23655-B-SEC 1-24hr 1300 155000 10900 10:44:15 AM 12 SEC 2-B-24hr 20 2420 254 10:48:42 AM 13 TRAP#43349-A-SEC 1-48hr 2520 299000 25300 10:59:21 AM 14 SEC 2-A-48hr 49 5880 370 11:04:22 AM 15 TRAP#43304-B-SEC 1-48hr 2440 290000 25900 11:11:44 AM 16 SEC-2-B-48hr 38 4590 321 11:17:12 AM 17 CCV-500 549 65200 10700 11:22:53 AM 18 TRAP#43311-A-SEC 1-72hr 4150 493000 32100 11:29:42 AM 19 SEC-2-A-72hr 144 17100 1660 11:34:58 AM 20 TRAP#43313-B-SEC 1-72hr 3860 458000 44000 11:41:13 AM 21 SEC-2-B-72hr 183 21800 1250 11:46:06 AM 22 Std__5000 5000 594000 43500 11:58:39 AM 23 QCS-4000 3960 470000 31400 12:03:14 PM 24Environmental, Health, & Safet y A ir Services Group

23721 23655
1310 1300

2.5 20
0.2% PASSED 1.5%

1.3125 1.32 643.657 642.757 2.04 2.05 Sample Mercury Concentration © ug 

### / scm ug 

### / scm Sample Mercury Concentration © L Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng SAMPLE A SAMPLE B
TRAP ID TRAP ID
ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*)BIG BEND UNIT 1 03/02/2009Ohio Lumex Zeeman Mercur y

S p ectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration

n g Area Area/n g Pass/Fail

2000 241000 120.500 Pass 1000 127000 127.000 Pass

500 60200 120.400 Pass 100 11100 111.000 Pass

50 5610 112.200 Pass 10 1210 121.000 Pass Mean (Area/ng): 118.683 Standard Deviation: 6.0307 Relative Standard Deviation: 5 Pass Inverse of Mean, A: 0.00843

Area Pass/Fail Blank 52 Pass 500 n g Check 65200 Pass Unknown QA Tra p 470000
Value for unknown is: 4000 n g

Percent Recover y

is: 99 % QC has: Passed Appendix K Mercury Analyzer Caibration

Calculated n g

Calculated n g 46 91 16-Mar-09

494 1040 1980

3960 549 0.4 9.9No Description C, ng/g Area Maximum Time BB-CSO1W-24-48-72 hr. traps-03-16-09 1 condition 500 477 56700 8880 9:58:02 AM 2 Std__2000 2030 241000 35700 10:00:05 AM 3 Std__1000 1070 127000 14800 10:02:24 AM 4 Std__500 507 60200 15300 10:04:38 AM 5 Std__100 93 11100 1380 10:06:40 AM 6 Std__50 47 5610 1120 10:08:42 AM 7 Std__10 10 1210 271 10:10:42 AM 8 BLANK 0.4 52 5 10:12:57 AM 9 TRAP# 23721-A-SEC 1-24hr 1310 156000 7080 10:31:40 AM 10 SEC 2-A-24hr 2.5 296 24 10:36:37 AM 11 TRAP#23655-B-SEC 1-24hr 1300 155000 10900 10:44:15 AM 12 SEC 2-B-24hr 20 2420 254 10:48:42 AM 13 TRAP#43349-A-SEC 1-48hr 2520 299000 25300 10:59:21 AM 14 SEC 2-A-48hr 49 5880 370 11:04:22 AM 15 TRAP#43304-B-SEC 1-48hr 2440 290000 25900 11:11:44 AM 16 SEC-2-B-48hr 38 4590 321 11:17:12 AM 17 CCV-500 549 65200 10700 11:22:53 AM 18 TRAP#43311-A-SEC 1-72hr 4150 493000 32100 11:29:42 AM 19 SEC-2-A-72hr 144 17100 1660 11:34:58 AM 20 TRAP#43313-B-SEC 1-72hr 3860 458000 44000 11:41:13 AM 21 SEC-2-B-72hr 183 21800 1250 11:46:06 AM 22 Std__5000 5000 594000 43500 11:58:39 AM 23 QCS-4000 3960 470000 31400 12:03:14 PM 24Environmental, Health, & Safet y A ir Services Group

43349 43304 2520 2440

49 38
1.9% PASSED 1.6%

2.569 2.478
1312.279 1307.627
1.96 1.90 Sample Mercury Concentration © ug 

### / scm ug 

### / scm Sample Mercury Concentration © L Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng SAMPLE A SAMPLE B
TRAP ID TRAP ID
ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*)BIG BEND UNIT 1 03/06/2009Ohio Lumex Zeeman Mercur y

S p ectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration

n g Area Area/n g Pass/Fail

2000 241000 120.500 Pass 1000 127000 127.000 Pass

500 60200 120.400 Pass 100 11100 111.000 Pass

50 5610 112.200 Pass 10 1210 121.000 Pass Mean (Area/ng): 118.683 Standard Deviation: 6.0307 Relative Standard Deviation: 5 Pass Inverse of Mean, A: 0.00843

Area Pass/Fail Blank 52 Pass 500 n g Check 65200 Pass Unknown QA Tra p 470000
Value for unknown is: 4000 n g

Percent Recover y

is: 99 % QC has: Passed Appendix K Mercury Analyzer Caibration

Calculated n g

Calculated n g 46 91 16-Mar-09

494 1040 1980

3960 549 0.4 9.9No Description C, ng/g Area Maximum Time BB-CSO1W-24-48-72 hr. traps-03-16-09 1 condition 500 477 56700 8880 9:58:02 AM 2 Std__2000 2030 241000 35700 10:00:05 AM 3 Std__1000 1070 127000 14800 10:02:24 AM 4 Std__500 507 60200 15300 10:04:38 AM 5 Std__100 93 11100 1380 10:06:40 AM 6 Std__50 47 5610 1120 10:08:42 AM 7 Std__10 10 1210 271 10:10:42 AM 8 BLANK 0.4 52 5 10:12:57 AM 9 TRAP# 23721-A-SEC 1-24hr 1310 156000 7080 10:31:40 AM 10 SEC 2-A-24hr 2.5 296 24 10:36:37 AM 11 TRAP#23655-B-SEC 1-24hr 1300 155000 10900 10:44:15 AM 12 SEC 2-B-24hr 20 2420 254 10:48:42 AM 13 TRAP#43349-A-SEC 1-48hr 2520 299000 25300 10:59:21 AM 14 SEC 2-A-48hr 49 5880 370 11:04:22 AM 15 TRAP#43304-B-SEC 1-48hr 2440 290000 25900 11:11:44 AM 16 SEC-2-B-48hr 38 4590 321 11:17:12 AM 17 CCV-500 549 65200 10700 11:22:53 AM 18 TRAP#43311-A-SEC 1-72hr 4150 493000 32100 11:29:42 AM 19 SEC-2-A-72hr 144 17100 1660 11:34:58 AM 20 TRAP#43313-B-SEC 1-72hr 3860 458000 44000 11:41:13 AM 21 SEC-2-B-72hr 183 21800 1250 11:46:06 AM 22 Std__5000 5000 594000 43500 11:58:39 AM 23 QCS-4000 3960 470000 31400 12:03:14 PM 24Environmental, Health, & Safet y A ir Services Group

43311 43313 4150 3860

144 183 3.5% PASSED 4.7%

4.294 4.043 1861.539 1865.841
2.31 2.17 Sample Mercury Concentration © ug 

### / scm ug 

### / scm Sample Mercury Concentration © L Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng SAMPLE A SAMPLE B
TRAP ID TRAP ID
ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*)BIG BEND UNIT 1 03/09/2009Ohio Lumex Zeeman Mercur y

S p ectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration

n g Area Area/n g Pass/Fail

2000 244000 122.000 Pass 1000 128000 128.000 Pass

500 61900 123.800 Pass 100 11500 115.000 Pass

50 6190 123.800 Pass 10 1180 118.000 Pass Mean (Area/ng): 121.77 Standard Deviation: 4.6293 Relative Standard Deviation: 4 Pass Inverse of Mean, A: 0.00821

Area Pass/Fail Blank -21 Pass 4000 n g Check 57200 Pass Unknown QA Tra p 5020
Value for unknown is: 150 n g

Percent Recover y

is: 27 % QC has: Failed Appendix K Mercury Analyzer Caibration

Calculated n g 1-May-09

502 1030 1980

93

Calculated n g

41 3650 -0.2 9.6 50No Description M, mg C, ng/g Area Maximum Time BB-CS1W -(4-5 DAY)-05-01-09 1 condition 2000 1 2060 252000 23100 8:59:25 AM 2 BLANK 1 -0.2 -21 5 9:01:30 AM 3 Std__2000 1 2000 244000 25200 9:04:01 AM 4 Std__1000 1 1050 128000 17000 9:06:19 AM 5 Std__500 1 508 61900 11600 9:08:26 AM 6 Std__100 X 1 82 10000 978 9:11:19 AM 7 Std__50 X 1 45 5560 656 9:13:02 AM 8 Std__10 1 9.7 1180 130 9:14:56 AM 9 Std__100 X 1 80 9860 868 9:18:28 AM 10 Std__100 X 1 371 45200 9650 9:22:56 AM 11 Std__100 X 1 84 10300 993 9:29:27 AM 12 Std__100 1 94 11500 1030 9:43:16 AM 13 Std__50 1 50 6190 1080 9:47:33 AM 14 TRAP#43305-sec1a - 4 day 1 820 100000 13300 10:12:58 AM 15 SEC 1b 1 787 95900 14800 10:17:03 AM 16 SEC 2 1 0.6 67 8 10:19:13 AM 17 TRAP#43343-sec1a - 4day 1 657 80100 8020 10:25:43 AM 18 SEC 1b 1 927 113000 12100 10:28:23 AM 19 SEC 2 1 2.8 337 28 10:30:22 AM 20 TRAP#43293-sec1a - 4 day 1 2570 314000 27600 10:37:10 AM 21 SEC 1b 1 2570 314000 34600 10:40:55 AM 22 SEC 2 1 25 3140 199 10:42:50 AM 23 TRAP#43318-sec1a - 4 day 1 3470 423000 43100 10:50:21 AM 24 SEC 1b 1 1550 190000 16600 10:53:17 AM 25 SEC 2 1 10 1240 86 10:55:26 AM 26 TRAP#23699-sec1a - 5 day 1 3180 388000 36300 11:01:49 AM 27 SEC 1b 1 230 28100 2120 11:05:14 AM 28 SEC 2 1 12 1480 66 11:07:57 AM 29 SEC 3-SPIKE 150ng 1 41 5020 445 11:12:50 AM 30 TRAP#43324-sec1a - 5 day 1 1540 188000 18100 11:22:28 AM 31 SEC 1b 1 2610 318000 16600 11:25:09 AM 32 SEC 2 1 469 57200 4520 11:27:51 AM 33 QCS 4000ng 1 3650 445000 30500 11:30:33 AM 34 1Environmental, Health, & Safet y A ir Services Group

43305 43343 1607 1584

0.6 2.8
0.0% PASSED 0.2%

1.6076 1.5868
1206.792 1210.217
1.33 1.31 Sample Mercury Concentration © ug 

### / scm ug 

### / scm Sample Mercury Concentration © L Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng SAMPLE A SAMPLE B
TRAP ID TRAP ID
ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*)BIG BEND UNIT 1 03/24/2009Ohio Lumex Zeeman Mercur y

S p ectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration

n g Area Area/n g Pass/Fail

2000 244000 122.000 Pass 1000 128000 128.000 Pass

500 61900 123.800 Pass 100 11500 115.000 Pass

50 6190 123.800 Pass 10 1180 118.000 Pass Mean (Area/ng): 121.77 Standard Deviation: 4.6293 Relative Standard Deviation: 4 Pass Inverse of Mean, A: 0.00821

Area Pass/Fail Blank -21 Pass 4000 n g Check 57200 Pass Unknown QA Tra p 5020
Value for unknown is: 150 n g

Percent Recover y

is: 27 % QC has: Failed Appendix K Mercury Analyzer Caibration

Calculated n g 1-May-09

502 1030 1980

93

Calculated n g

41 3650 -0.2 9.6 50No Description M, mg C, ng/g Area Maximum Time BB-CS1W -(4-5 DAY)-05-01-09 1 condition 2000 1 2060 252000 23100 8:59:25 AM 2 BLANK 1 -0.2 -21 5 9:01:30 AM 3 Std__2000 1 2000 244000 25200 9:04:01 AM 4 Std__1000 1 1050 128000 17000 9:06:19 AM 5 Std__500 1 508 61900 11600 9:08:26 AM 6 Std__100 X 1 82 10000 978 9:11:19 AM 7 Std__50 X 1 45 5560 656 9:13:02 AM 8 Std__10 1 9.7 1180 130 9:14:56 AM 9 Std__100 X 1 80 9860 868 9:18:28 AM 10 Std__100 X 1 371 45200 9650 9:22:56 AM 11 Std__100 X 1 84 10300 993 9:29:27 AM 12 Std__100 1 94 11500 1030 9:43:16 AM 13 Std__50 1 50 6190 1080 9:47:33 AM 14 TRAP#43305-sec1a - 4 day 1 820 100000 13300 10:12:58 AM 15 SEC 1b 1 787 95900 14800 10:17:03 AM 16 SEC 2 1 0.6 67 8 10:19:13 AM 17 TRAP#43343-sec1a - 4day 1 657 80100 8020 10:25:43 AM 18 SEC 1b 1 927 113000 12100 10:28:23 AM 19 SEC 2 1 2.8 337 28 10:30:22 AM 20 TRAP#43293-sec1a - 4 day 1 2570 314000 27600 10:37:10 AM 21 SEC 1b 1 2570 314000 34600 10:40:55 AM 22 SEC 2 1 25 3140 199 10:42:50 AM 23 TRAP#43318-sec1a - 4 day 1 3470 423000 43100 10:50:21 AM 24 SEC 1b 1 1550 190000 16600 10:53:17 AM 25 SEC 2 1 10 1240 86 10:55:26 AM 26 TRAP#23699-sec1a - 5 day 1 3180 388000 36300 11:01:49 AM 27 SEC 1b 1 230 28100 2120 11:05:14 AM 28 SEC 2 1 12 1480 66 11:07:57 AM 29 SEC 3-SPIKE 150ng 1 41 5020 445 11:12:50 AM 30 TRAP#43324-sec1a - 5 day 1 1540 188000 18100 11:22:28 AM 31 SEC 1b 1 2610 318000 16600 11:25:09 AM 32 SEC 2 1 469 57200 4520 11:27:51 AM 33 QCS 4000ng 1 3650 445000 30500 11:30:33 AM 34 1Environmental, Health, & Safet y A ir Services Group

43293 43318 5140 5020

25 10 0.5% PASSED 0.2%

5.165 5.03 2767.708 2775.731
1.87 1.81 SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) PASSED

Normalized Total Hg Mass (M*) ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug TRAP ID TRAP ID
ng Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng SAMPLE A SAMPLE B

Sample Mercury Concentration © ug 

### / scm ug 

### / scm Sample Mercury Concentration © LBIG BEND UNIT 1 04/01/2009Ohio Lumex Zeeman Mercur y

S p ectrometer Model Number: RA-915+/RP-M234 Serial Number: 902/2007 Calibration Date: Profile 1 Calibration

n g Area Area/n g Pass/Fail

2000 244000 122.000 Pass 1000 128000 128.000 Pass

500 61900 123.800 Pass 100 11500 115.000 Pass

50 6190 123.800 Pass 10 1180 118.000 Pass Mean (Area/ng): 121.77 Standard Deviation: 4.6293 Relative Standard Deviation: 4 Pass Inverse of Mean, A: 0.00821

Area Pass/Fail Blank -21 Pass 4000 n g Check 57200 Pass Unknown QA Tra p 5020
Value for unknown is: 150 n g

Percent Recover y

is: 27 % QC has: Failed Appendix K Mercury Analyzer Caibration

Calculated n g 1-May-09

502 1030 1980

93

Calculated n g

41 3650 -0.2 9.6 50No Description M, mg C, ng/g Area Maximum Time BB-CS1W -(4-5 DAY)-05-01-09 1 condition 2000 1 2060 252000 23100 8:59:25 AM 2 BLANK 1 -0.2 -21 5 9:01:30 AM 3 Std__2000 1 2000 244000 25200 9:04:01 AM 4 Std__1000 1 1050 128000 17000 9:06:19 AM 5 Std__500 1 508 61900 11600 9:08:26 AM 6 Std__100 X 1 82 10000 978 9:11:19 AM 7 Std__50 X 1 45 5560 656 9:13:02 AM 8 Std__10 1 9.7 1180 130 9:14:56 AM 9 Std__100 X 1 80 9860 868 9:18:28 AM 10 Std__100 X 1 371 45200 9650 9:22:56 AM 11 Std__100 X 1 84 10300 993 9:29:27 AM 12 Std__100 1 94 11500 1030 9:43:16 AM 13 Std__50 1 50 6190 1080 9:47:33 AM 14 TRAP#43305-sec1a - 4 day 1 820 100000 13300 10:12:58 AM 15 SEC 1b 1 787 95900 14800 10:17:03 AM 16 SEC 2 1 0.6 67 8 10:19:13 AM 17 TRAP#43343-sec1a - 4day 1 657 80100 8020 10:25:43 AM 18 SEC 1b 1 927 113000 12100 10:28:23 AM 19 SEC 2 1 2.8 337 28 10:30:22 AM 20 TRAP#43293-sec1a - 4 day 1 2570 314000 27600 10:37:10 AM 21 SEC 1b 1 2570 314000 34600 10:40:55 AM 22 SEC 2 1 25 3140 199 10:42:50 AM 23 TRAP#43318-sec1a - 4 day 1 3470 423000 43100 10:50:21 AM 24 SEC 1b 1 1550 190000 16600 10:53:17 AM 25 SEC 2 1 10 1240 86 10:55:26 AM 26 TRAP#23699-sec1a - 5 day 1 3180 388000 36300 11:01:49 AM 27 SEC 1b 1 230 28100 2120 11:05:14 AM 28 SEC 2 1 12 1480 66 11:07:57 AM 29 SEC 3-SPIKE 150ng 1 41 5020 445 11:12:50 AM 30 TRAP#43324-sec1a - 5 day 1 1540 188000 18100 11:22:28 AM 31 SEC 1b 1 2610 318000 16600 11:25:09 AM 32 SEC 2 1 469 57200 4520 11:27:51 AM 33 QCS 4000ng 1 3650 445000 30500 11:30:33 AM 34 1Environmental, Health, & Safet y A ir Services Group

23699 43324 3410 4150
12 469
0.4% PASSED 11.3%

150

41
27.3% FAILED 3.422 4.619 2276.998 3256.203 1.50 1.42 Sample Mercury Concentration © ug 

### / scm ug 

### / scm Sample Mercury Concentration © L Appendix K Emissions Calculations

SECTION 3 Spike Recovery (M3) SECTION 3 Recovery Percentage (%R) SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2)

ng ng SAMPLE A SAMPLE B
TRAP ID TRAP ID
ng

Total Sample Volume (Vt) SECTION 2 Breakthrough (%B) SECTION 3 Spike Value (Ms)

Normalized Total Hg Mass (M*) ng

ug ng

SECTION 3 Spike Recovery (M3)

L ng SECTION 3 Spike Value (Ms) ng

ug Total Sample Volume (VT) SECTION 3 Recovery Percentage (%R) ng SECTION 1 HG MASS (M1) SECTION 2 HG MASS (M2) SECTION 2 Breakthrough (%B) FAILED

Normalized Total Hg Mass (M*)