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# OAR Box 1413 Prepped by Ollie Stewart



## Document

Number: 

# IA) 11-1-7 5 Docket Number: 

# A-94-5 2

Printed 7/9/2008 3:11:23 PM

Sheet 74 of 114P. 2 

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## PERMI TT O OPERAT E Numbe r 001 6 Vali d Apri l 1 , 199 8 t o Marc h31 , 199 9 Thi s Permi t Ha s Bee n Issue d T o Th e Following : Compan yNam e / Address : Facilit yName / Address : Hydr o System s Inc . 5 0 Moreland Road Sim i Valley , CA9306 5 Hydr o System s Inc . 5 0 Moreland Roa d Sim i Valley , CA9306 5 Permissio nI s Hereb y Gran-be

dT o Operat e Th e Following : Thi s Facilit yFabricate s Tub s And Whirlpoo l Bath s FromFiberglas s Reinforce d Polyeste r Resin , Using Th e Followin g Equipment : SprayBooth s 1 - Beatti e Spra

yBooth , 12'5 " wid e X T 6" highX 10'0 " deep , 12,00 0 CFM capacity , "ge l coat " booth . Thi s boot hshal l b e equippe d wit ha Westate s carbo n adsorptio n systemcontaining 2,70 0 pound s o f activate d carbon . 1 - Bleeke r Spra

yBooth , 20'0 " wid e X i0'0
- highX 13'2 " deep , 24,000 0 CF M capacity , "chopper " booth . . _ Thi s boot hshal l b e equippe d wit ha Westate s carbo n adsorptio n system'cpntaining.S,40 0 pound s o f activate d carbon . 1
—Bleeke r " : Spra

yBooth , '^Mode l F-12-7 , yll' 5*1 ; wid e X 7'6"hig hX lO'.O " deep , 12,00 0 CFMcapacity,;->£cur£ng " ^both i Thi V boot hshal l b e equippe d wit ha ' Westate s carbo n adsorption * systemcontaining ",2,70 0 pound s o f activate d carbon . 

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an d Transfe r System

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- HighShea r Mi_xer / 750Jgallo n capacity,\ilhheated , close d to p wit ha loading hatch , equippe d with-^ n electri c motor'powering a highrpm.mi xblade . , • Resi n i s hardpipe d from."exempt; : re s i n storag e tank s int o th e highshea r .

Additive s suc has^aluminum'trihydrate^and wax ; vapo r suppressan t ?»_ ^ 4 - *•••.' .'4 - V

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ar e adde d to.!thi s mixer . ' • int o th e day . tank : ' J$': • • .&; • 'J

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VCAPC D Permi t t o Operat e Numbe r 001 6 Issue d T o Hydr o System s Inc . Vali d Apri l 1 , 199 8 t o Marc h31 , 199 9 Thi s Permi t Ha s Bee n Issued Subjec t T o Th e Following Conditions ; 1 . Permitte d Emissions : Tons/Yea r Pounds/Hour Reactiv e Organi c Compound s Particulat e Matte r 8.0 7 0.0 6 3.8 9

0.2 0 Th e Following Limit s Shal l No t B e Exceeded : Cleanup Material . 520. 0 gallon s pe r yea r Whic hContain s No Greate r Tha n 6.6 0 Lbs/Ga l o f RO C (No t Including Acetone ) Fiv e Exhaus t Point s 3. 0 ppm vo f RO C (Refe r t o Conditio n No . 7 ) Sand 1. 5 ton s pe r yea r Th e ter m"ppmv " refer s t o "part s pe r millio n b yvolume" . Th e term"ROC " refer s t o "Reactive Organi c Compounds, " a s define d i n APC D Rul e 2 .

• •'—T • I n orde r t o compl ywit hthes e conditions , th e permitte e shal l perfor m emission s monitoring a s require d byConditio n No.7 , an d maintai n record s and report s a s require d b yConditio n No. . 15 . Consumptio n level s fo r eac h materia l categor

yshow n abov e shal l b e totale d fo r eac hmonth . Th e monthly , record s shal l b e summe d fo r .th e previou s 1 2 month's . Total s for; : any^o f these'1 2 mont hperiod s i n exces s o f the . specified limit s shal l be; : considere d a violatio n o f thi s condition . ' • • .-ft. vi..,-> ^ •.Prf^r^to..(exceedin g thes e limits , thf e permitte e shal l appl yfor>y.a_nd'|-j- j -|p£«-:..••••• . ; receive',.; , a permi t modificatio nfroot'the.yDistrict . Suc ha napplication. isgJJr .

. sh^l:demonstrat e that ; th e permitte e wil l compl ywit hAPC D Rule'.;;26>|,New.£?;vA-...

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- Vappr i Suppressan t Requiremen t Fo r Polyeste r Resin s • • ' • ••?•••• mr- m^ •_S^';Al*^poiyester

resi nmaterial, ; excep t gelcoat , shal l b e vapo r suppressed* ^ ^ ; . witfr.ndj;les s tha n.0.730 % b y weigh t

suppressant . . Thi s requiremen t isy."- ; rjity. '•'$?. "apiplle d'k s Bes t Availabl e Contro l Technology " (BACT) . . v S " : % : ;: i 

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ystati c tests . Complying formulation s shall' , not' . •fr'
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VCAPC D Permi t t o Operat e Numbe r .001 6 Issue d T o Hydr o System s Inc . Vali d Apri l 1 , 199 8 t o Marc h31 , 199 9 a ) Ge l Coat s Fo r al l ge l coats , th e monome r conten t o f th e materia l shal l b e n o mor e tha n4 5 percen t b yweigh t a s applie d fo r pigmente d ge l coat s an d 5 0 percen t b yweigh t a s applie d fo r clea r ge l coats , a s determine d b y manufacturer' s specifications . Complyin g formulation s shal l no t b e thinne d o r dilute d wit han yRO C o r change d i n an ymanne r tha t ma yincreas e RO C emission s afte r testing , bu t prio r t o o r durin g application . b ) Applicatio n Metho d Properl yoperate d airless , air-assiste d airless , electrostatic , o r highvolume—lo wpressur e spra yequipmen t shal l b e used i n an yspray application , excep t fo r touch-u p o r repai r using a hand-held , air-atomize d spra

ygun utilizing a n attache d resi n containe r o f n o mor e tha n on e quar t capacity . c ) Cleanu

p Cleaning materia l use d o n lines , rollers , brushes , spra yequipmen t and personnel , and containing mor e tha n 1.6 7 pound s o f RO C pe r gallo n o f materia l a s applied , o r wher e th e initia l boiling poin t i s les s tha n 19 0 degree s Celsius , shal l b e limite d i n us e t o les s than 1 5 gallon s pe r calenda r wee k unles s a reclamatio n systemi s used . Residue s from on-sit e reclamatio n system s shal l contai n n o mor e than 2 0 percen t RO C b yweigh t and shal l b e disposed;o f i n a-manne r consisten t wit hy federal, . stat e and loca l hazardou s wast e regulations . Not e tha t thi s conditio n doe s no t appl y.t o th e ; • ROC. ' •.- . V v_i
- J' _e*use?b f acetone-asfaceton e i s not . a n - V '.$••..•• (•:.._• < •>•*-.•_=.•;.•/••••- . • .a-. . ••'•• : -'•,•>'• - • -i- z - .*&•'
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- ;..0 > . d ) Storag e O f ROC-Containin g ' Materials'. ^ 

# I . • Al l material s containin g reactiv e .organi c • compounds , .use d o r unused/'
-

- includin g bu t no t limite d t o semi-soli d v-or . liquid , polyester , resi n§•/ ': material s an d soli d o r liqui d cleanin g materials,;-shal l b e (store d i n closed , nonabsorben t container BJ-
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_ S?''.f e •'-»'• ' ,.•; - . .,& • e ^permitte e '.shal l compl y-.wit h• •i-.' j • - -' , ' ••7-V : .-.'v. - -.&•.*• • .7''
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# ; i fe •m Requiremen t Fo r Activate dCarbo nPanels'^i hSpra y^Booth s .; . fe ..:••«._•* - &•*;- • •••&' : *• « . :-.•

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- Th e applicatio no f resi no r ge l coat,'^an d -the/curing ' of/resi n "o r ger ; coa t r . r • . vV-.-- - • • • • • • ?. •*»-.'• ' -v**-*.*. " JUT.* , r--.-ji.Sf'" ' •"•?*% • -.^»»5S' . • -<*".'"• ' Sis-' : . - Ws shal l onl yb e conducte d i n eithe r the'^ge l coat^booth , ..the . "chopper," . . s£ ; 

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VCAPC D Permi t t o Operat e Numbe r 001 6 Issue d T o Hydr o System s Inc . Vali d Apri l 1 , 199 8 t o Marc h31 , 199 9 booth , o r th e "curing " booth . Eac ho f thes e booth s shal l b e equippe d wit h effectiv e activate d carbo n panel s a t th e boot hexhaust . Th e panel s shal l b e place d s o that , fo r eac hbooth , th e entir e boot hexhaus t passe s through activate d carbo n panels . Th e "ge l coat " boot hshal l b e equippe d wit hactivate d carbo n panel s whic h contain , o n a combine d basis , n o les s tha n 2,70 0 pound s o f activate d carbon . Th e "chopper " boot hshal l b e equippe d wit hactivate d carbo n panel s which , o n a combine d basis , contai n n o les s tha n 5,40 0 pound s o f activate d carbon . Th e "curing " boot hshal l b e equippe d wit hactivate d carbo n panel s which , o n a combine d basis , contai n n o les s tha n 2,70 0 pound s o f activate d carbon . Dail ymonitorin g o f eac hboot hexhaus t shal l b e conducte d a s specifie d i n Conditio n No . 7 . Record s o f carbo n pane l replacemen t shal l b e maintaine d a s specifie d i n Conditio n No . 15 . 6 . Cleanu

p Material s Al l clean-u

p shal l b e accomplishe d wit hnon-reactiv e organi c compoun d materials . Thi s conditio n i s applie d a s BACT . Not e tha t thi s conditio n doe s no t appl yt o th e us e o f aceton e a s acetone.i s no t a n ROC . 7 . Exhaus t Emission s Testin g

8 .

Pag e Th e following exhaus t point s shal l b e teste d for . reactiv e organi c compound emission s using a . HN Umode l ISP I 10 1 photoionizationVdetecto r '(PID) , o r equivalent,'jonce ; pe r shift : gelcoa t boot hstack , choppe r bbot hstack , curing-;So6 t hi" ; stack , /grindin g boot h.stack , an d material' , storage'^roo mfloor ; (H-2 ) £ven t &* $ Records " o f /th e monitoring .shall : b e ^maintained/a s Speci f ied/Siii 

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- ahd'-record s 'of such-re'blacement.'shal l be^maintairie d aS ' Jy specifie d in ; Conditio n No . 15. " Thi s conditio n i s applie d a s BAC T an d t o . ensure/compliance * wit hAPC D Rul e 51" , Nuisanc e Calibration"'o f Emissio n .Testin g Equipmen t •i&• : : M' JJfcJy'' yJy-' -•••< .- •-€/ ' '^ " .'- ' -i-^-7 - •->V* U ' •; L ^:,' - ' 7 - ••-.':'- : •. . : . V5/' - 

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Issue d T o Hydr o System s Inc . Vali d Apri l 1 , 199 8 t o Marc h31 , 199 9 P. 7

10 . Airflo wBalanc e Th e followin g measure s shal l b e take n t o maintai n a buildin g airflo w balance : a ) I f al l spra ybooth s ar e off , al l productio n door s shal l b e kep t closed . b ) Th e exhaus t fan s o f a t leas t tw o spra ybooth s shal l b e o n whe n an y spra yboot hi s i n operation . c ) A t leas t one , bu t n o mor e tha n one , productio n doo r shal l b e kep t ope n durin g an yspra yboot hoperation . d ) Th e southeas t productio n doo r (#1 ) shal l no t b e ope n whe n th e win d i s blowin g fro mth e west . ; e ) I f an ydoo r i s opene d an d th e telltail s poin t out , th e doo r shal l b e close d immediately . 11 . Requiremen t Fo r Telltail s A t Door s Telltail s shal l b e maintaine d o n al l thre e productio n are a doors .

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yloaded ; through
- 'th e hatches . Thi s conditio n i s applied ' as£BACT& : ->/".. & i; •

••AS-- 154V / Grindin g Operi^ons^-"^^;^!!^ ^ :JJ- J. .':'•' ' ' , "J- - ••' V "" - :•' ' The / us e o f i-the/igri'^-iing^obth'/fp r drillin g o f tub s : an d \bath s . i s "exempt'/ffb*-^-A-P ^ to^APCD/Rul e J 23.B.5 . However, 1 thei' , us"e 1 .'of;;^^the" ; bboth^ f o r iSuch.'purpose s shall ' b e • $.' conducted 7 witheffeetive/air/filter s in/plac e so/a s t o mitigat e emissions
o f particulat e matter./^Ehis^/condi'tion^i s applied : t o ensur e complianc e wit hAPC D .Paile/51>-.'NuisS_rice;/ ^ ^f ^ / .ik ' J ••:

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VCAPC D Permi t t o Operat e Numbe r 001 6 Issue d T o Hydr o System s Inc . Vali d Apri l 1 , 199 8 t o Marc h31 , 199 9 O n ADail yBasis : a ) Recor d th e result s o f monitorin g performe d pursuan t t o Conditio n No . 7. . Record s shal l includ e th e date , time , monitorin g location , emissio n leve l measure d (ppmv) , an d th e nam e o f th e perso n makin g th e measurements . b ) Calibrat e th e monitorin g instrumen t (PID ) usin g a certifie d calibratio n ga s correspondin g t o th e middl e o f th e instrumen t detectio n rang e (i.e . 5-1 5 pp ma s styrene) . Al l manufacturer' s instrumen t maintenanc e an d lam p replacemen t procedure s shal l b e followed . Als o recor d th e dat e an d tim e o f calibratio n an d an y necessar ymaintenanc e activit yo f th e instrument . Weekl yReports , Initiale d B yTh e Operator , Shal l Contain : c ) Th e manufacture r an d produc t numbe r o f eac hpolyeste r resi n materia l an d al l RO C containing material s whic har e added t o th e polyeste r resi n materia l (e.g . catalyst ) d ) Th e manufacture r an d produc t numbe r o f eac hcleaning materia l whic h contain s ROC s (typicall yinclude s emulsio n cleaner s sinc e thes e cleaner s typicall ycontai n some ROCs ) e ) Th e quantit yo f eac hpolyeste r resi n materia l use d and th e quantit yo f eac hRO C containing materia l whic hha s bee n adde d t o th e polyeste r ;/// resi n materia l • VV/f ) Maintai n record s o f cleaning material s bot hused , and recycled , an d

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VCAPC D Permi t t o Operat e Numbe r 001 6 Issue d T o Hydr o System s Inc . • Vali d Apri l 1 , 199 8 t o Marc h31 , 199 9 Th e Permitte e Shal l Als o Provide : k ) Acurren t summar yo f th e emissio n rat e o f eac hpolyeste r resi n materia l used a s th e RO C los s rat e i n gram s pe r squar e mete r 1 ) Th e corresponding polyeste r resi n materia l categor y(e. g resin , specialt yresin , pigmente d ge l coat , o r clea r ge l coat ) m ) Th e ge l time o f eac hpolyeste r resi n materia l n ) Fo r eac hcleaning material , th e permitte e shal l identif yth e RO C conten t i n pound s o f RO C pe r gallo n o f materia l a s applie d o ) Th e permitte e shal l suppl ydocumentatio n fro mth e materia l manufacture r t o suppor t thes e records . Documentatio n mus t als o b e provide d whic hidentifie s th e chemica l composition o f al l specialt y. resins . Withi n te n day s afte r receip t o f thi s permit , th e applican t maypetitio n th e Hearin g Boar d t o reviewan yne wo r modifie d conditio n o n th e permi t (Rul e 22) . Thi s permit , o r a copy , shal l b e poste d reasonabl yclos e t o th e subjec t equipmen t an

d shal l b e readil yaccessibl e t o inspection personne l (Rul e 19) . Thi s permi t i s no t transferabl e fromon e locatio n t o anothe r unles s th e equipmen t i s specificall yliste d a s bein g portabl e (Rul e 20) . I n relianc e upo n th e statemen t o f th e applican t tha t operatio n o f th e equipmen t describe d herei n shal l mee t th e requirement s ..as/specifle d i n the-.Rule s an

d .;!j>« ' Regulation s o f th e Air : Pollutio n Control ' District , permissio n i s .hereby , grante d .':•,-: , t o operate ; provided , howeve^ , th e permiissi'on ; gfaihted..hereb yshal l no t be'...
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# Scot tSpecialt

yGases > Scot t Environmenta l Technolog yInc . 260 0 CAJO N BLVD.
. SAN BERNARDINO
. C A9240 5 TEl'X : 510-100-883 1 (ScotGas )

FAX : 714-887-054 9 divisio n o

fPHONE : 714-887-257 1

HYDR O SYSTEM S 5 0 MORELAND ROAD SIM I VALLEY , C A9306 5 ATTN : LARR Y BURROUGH S Date: 8-25-8 9 Ou rProjec tNo. : You rP.O
. No. : _ 209 6

2437 6

Gentlemen : Than k yo u fo rchoosin g Scot tfo ryou rSpecialt yGa s needs
. Th e analyse s fo rth e gase s ordered , a s reporte d b you rlaboratory , ar e liste d below
. Result s ar e i n volum e percent , unles s otherwis e indicated
. ANALYTICA LREPOR T Cyl
. No. , CAL-1200 4

Cyl . No . Componen t **& • Analytica l Accuracy
. ±1 % Component Is o Butylen e
Ai r Concentration 9.14 2 PP M
Balanc e
, * # Analytica l ' % .t^ccufac y ^^Concentratio n * # Cyl
. No
.

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. No
. Componen t Analytica l Accuracy
. Componen t

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Analytica l Accuracy
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Analyst
. Approve d By

Th e onl yliabilit yofthi s Compan yfo rgas whic h fall s to compl y-julth thi s analysi s shal l be replacemen t thereofb yth e Compan yurithou t extr a cost .
PLUMSTEADVILLE . PENNSYLVANI A/ TROY , MICHIGA N /

HOUSTON , TEXA S /

WHEELING , ILLINOI S SOUT H PLAINFIELD , NE WJERSE Y/ FREMONT , CALIFORNI A/ WAKEFIELD , MASSACHUSETT S / LONGMONT , COLORAD O BOSTON . MASSACHUSETT S / BATO N ROUGE , LOUISIAN AP.1 1

MATERIA L SAFET Y DAT A SHEE T COATINGS , RESINS , AN D RELATE

D MATERIALS .NUFACTURER : CARGILL , IN C / CP D 230 1 CROSB Y RD . WAYZATA , MN . 5539 1 iT E O F PREP : 10/28/8 8 EMERGENC Y CONTACT : CHEMTRE C 1-800-424-930 0
SUPERSEDE S DATE : 10/28/8 8 iCTIO NI . PRODUC T IDENTIFICATIO N IODUCT NAME : 28 7 873 7 IODUCT CLASS : UNSATURATE D POLYESTE R RESI N
ECTIO NII . HAZARDOU S INGREDIENT S

* WARNING* THI S PRODUC T CONTAIN S ACHEMICAL(S ) KNOW N T O TH E STAT E O F CALIFORNI AT O CAUS E CANCER , O R BIRT H DEFECT S OR OTHE R REPRODUCTIVE HARM . * THI S PRODUC T MEET S REQUIREMENT S O F SCAQMD RUL E 116 2 * NGREDIENT CAS NO . LPH AMETHYLSTYREN E 98-83- 9

•TYREN E 100-42- 5 PERCENT TL V PPMMG/M 3 

### 1. 3

39. 2 SOURC E IDL H VAPO R PP MPRESSUR E (M MH g @68F ) 50.000 0 240.0 0 TWA/ACGI H N/ E 1.0 0 100.000 0 480.0 0 FEDERAL PE L 100.000 0 480.0 0 STEL/ACGI H 50.000 0 215.0 0 TWA/ACGI H 500 0 4.3 0 100.000 0 425.0 0 FEDERAL PE L 100.000 0 425.0 0 STEL/ACGI H LE L

1.9 0

1.1 0

IAZARDOU

S MATERIALS IDENTIFICATIO NSYSTE M 1EALTH: 2 * FLAMMABILITY : 3 IEACTIVITY : 1
SECTIO NIII . PHYSICAL DAT A SOILIN GRANGE : . 293-33 1 F SPECIFI C GRAVITY 1.08 0 VAPO R DENSITY (AIR-1) : 3.61 5 VOLATIL E ORGANI C CONTENT (VOC ) \PPEARANC E AN

D ODO R SOLUBILITY I NWATE R PERCEN T VOLATIL E BY VOL : 48.0 0 EVAPORATIO

NRAT E (n-Bu Ac-1) : .4 9 VAPOR PRESSUR E (M

MHg@68F) : 4.1 9 49 1 grams/lite r CLEA R LIGH T STRA

WCOLOR SOLUTION . ESSENTIALL Y NI L 5 3 SECTIO NIV . FIR E AN D EXPLOSIO

NHAZARD DAT

A 

# m

### es h Cherflico l Corporatio n 

# Materia l SafetyData She e

AniRTEC H COD E MO . C2001 P ORIGINA L ISSU E OATE : 10/18/0 5 REVISED : 3/8 9 I . lOENTiriCATIO N LM0A2-2 0 PRODUC TNAME : Unsaturate d Polyosto rResi n COMMO N NAME(S) * MR . LB , LAM . P . F . (Se e lndexlC200 1 (o rspecili c resi n DO THAZAR D CLASS : Flammabl e Liqui d formulations i n thi ? group ) UN/N ANO . UNJBS | FORMULA : DO TSHIPPIN G NAME : Resi n Solutio n Mixtur e ARISTEC H INFORMATIO N 1 EMERGENC Y1 ELhHHUN b NUMtJfc H

(412 ) 433-765 4 ( 8 a.m.. 5 p.m. . Mon.-Fri. i (412 ) 433-S8 H (O H Hou remergencies ) MANUFACTURER : Aristec h Chemica l Corporatio n GO O Gran t SI . Pittsburgh , P A15230*025 0 I I . INGREDIENT S AN D RECOMMENDE D OCCUPATIONA L EXPOSUR E LIMIT S

COMPONEN T Unsaturate s PoiyestB rBaso Maai n Styrune ' 

### % wr . 30-0 0 20*6 2 CA S NO .

Ceo attache d iiido n 100-42- 5 EXPOSUR E LIMIT S

OSHA-PE L Mon o Ctit- h TWA-5 0 pp m ST61.-1O 0 pp m ACGIH-TL V

Nnn * Estab . IWA-bOpp m STEL-10 0 pp m HAZAR D OATA

Flammable . Ma vb e toxi c i l absorbe d throug h ih e skin . PossiblyCarcinogenic . 'Styran a i s ir_eniit« d a s i SAfl ASactio n 3 t J to»i e thomica i III . PHYSICA L DAT A BOILIN G POIN T(° F ) (Stvrene ) 29 U MELTIN G POIN T(»F ) No t Applicabl e VAPOP I PHE33UF) E (m m Hg. ) (Ctyruno ) "VAPU H UbNSlT V(AIR* , l ) (Stymn*.* ) APPEARANC E AN O ODOR : Clea rviscou s liquid ; ahai p styrenaia d odo r 

### 3JSPECIFI C GRAVII i Y(H ? Q » 1 ) PERCENT . VOLATIL E B YVOLUM E (Styren e wt . % ) 2Q-< _Ci j No t Applica b 8QLUQH.U YI N WATC O Nqqlioit ;

IV . FIR E AN O EXPLOSIO N HAZAR D DAT A FLAMMABL E UMIT S (Stvrene ) FLAS H POIN T(metho d used ) PenskyMaiU m cloae d cu p OP T(Ctyrono ) EXTINGUISHIN G MtUt A Carho n dioxide , dr ychemica l (smal l (ires) ; loa m an O wate rlo g (larg o firca ) KPFClA I FIR E FIGHTIN G PROCEDURE S ' " Cn- M lank s an d drum s wil h water . Firefighter s shoul d wea rself-containe d prea.nin g equipment . U l 1.1 % Ue l

0.1 %

UNUSUA L nn c AN D EXPLOSIO N HAZARD S Hirj h t«.mp_»r.*ti ( r « nkposur e (o rextende d period s o l tim e w m resul t m spontane c uncuttltulle d exothermi c polymerization . V . REACTIVIT YDAT A Stabilit y .Unstable ,

Stabl e 

### J L COND I HUN S I O AVOID : Exposur e t o excessiv e hea t o rope n llame ; atorog c i n ope n containers : prolonge d storag e ( 6 monitis ) INCOMpATiniLIT Y(material s l o avoid ) Stron g aci<_3 . peroxido c an d otho roxidizin g arj»nt« ; HAZARDOU S UtCUMl'-OSlTIO N PRODUCT S Carbo n monoxioe . carbo n dioxide , lu wmolecula rweigh t hydrocorbonn . oryjn. c acid s

Ma yOccu rI X Hazardou s Polymerizatio n Wil l No t Occu r CONDITION S T O AVUIU : Exposur e t o heal , ope n dam e o rcontam.natio n wit h oxidizin g agents , avoi o storag e aoov e 3fl* C (i00"l) . Vt . SPIL L O R LEA KPROCEDURE S TnAN-jPORlAllO H EMERGENC E Cal l CHEMTRE C 1*00.42-1-930 0 STEP S T O B E TAKE N I N CAO C MATERIA L I S RELEASED : Romo« » al l ir-niiio n source s an d ooe n Hames . Increas e ventilatio i maximiz e vapo rdispersal . Dik e larg e spill s i o preven t runol l int o sewer s o rwaterways . Cove rspil l wii h inorgani c absorben t mat e (vermiculite ) Swee p u p an d plac e m labelle d drum . Styren e i s o n th e CERCL Ahazardou s substanc e list ot »980 . a s amen c an d reportabl e spill s mus t b e reporte d t o th e Nationa l Respons e Cente r In case of release to tha environment, report spills to 800-424-1)802, The National

Response

Center. WAST E DISPOSA L METHOD : •[~EP AWasi e Identificatio n N o OOQ i Oispos* ? 0 1 i n accordanc e wit n local , stat e 3n d to-iorn i regulations . An rh.-i.Mrctoi. s iv.is*' ? •(•r.iy'-fion xr.i/ / !,0i)-42-t-93-i6. thi}

RCRAHottm* / " /P.1 3

II . HEALT H HAZAR D DAT Aro.v«3lc rCrou p I MAJO R Fxposnn e MAZAH O



# M INHALATION [ X j CONTAC T| | CONTAC

T| | INGESTIO N FFCCT S O F OVEREXPOSURE : 'rimar yeffects o l thi s produc

t wil l probabl yb e du e to styrene . VHALATION:

Maycaus e drowsiness , nausea , headache , atlgue , narcosi s an d dizziness . Severe exposure maycaus e a contuse d stato . Irritatio n o l th e mucou s membranes o fth a uppe r espirator ytrac t ma yoccur . SKIN

CONTACT:

Irritatio n ma

yoccur , wit h prolonged exposur e possibl ydevelopin g t o dermatitis . I

feczema ou s develops , thi s mos

t ofte n occurs o n th a bac k o fhands , wrists an d forearms . Mayb a absorbe d throug h th e skin . EYE CONTACT: rritatlo n o

fth e mucou s rm.r-1i_.4ne3 . pai n an d rvdnacv*"*» yrvftcur . INGESTION:

Sore throat , abdomina l pai n an d vomitin g ma yoccur . MEDICALCONDITIONS AGGRAVATED

BY EXPOSURE:

Individual s wit h Chroni c respirator ycondition s (I.e. , asthma , cnroni c bron ihliio , omphytr-m n flic.) mavb e adversel yedecte d b yanyfum e at

oirbom o particulat e matte rexposure .

EMERGENC YAN O FIRS TAl O PROCEOURES : INHALATION:

Remov e fro m exposure . I

fbreathin g i s stoppe d o ri s difficult , administe rartificia l respiratio n o roxyge n a s indicated . See k medica l aid . t

fsymptom s o

fexposure persist , consul t physician . SKIN CONTACT:

Remove contaminate d clothing . Was h ski n thoroughl ywit h soa p an d water . IfIrritatio n occurs , see k medica l aid . EY E CONTACT-

Flus h wit h larg e amounts o fwater , lif

t uppe ran d lowe reyelid s occasionally . See k medica l aid . INGESTION. D

o no t Induoo vomiting . <?*-* k mf.dif.a l aid .
VIII . SPECIA L PROTECTIO N INFORMATIO N RESPIRATORY : Respirator yprotectio n approve d byNIOSH/MSH Afo rprotectio n against organi c vapors shoul d b e used to avoi d I inhalatio n o

fexcessiv

e ai rcontaminants . Appropriate respirato rselectio n dapond s o n th e typ e an d magnitud e o fexposure . SKIN : Chemica l resistance dat a fo rbarrie rmaterial s used shoul d b e determine d base d o n Ih e us e o fthi s product . Polyviny l alcohol , an d polyethylen e protectiv e garment s hav

e bee n recommende d lo rprotectio n against material s o t thi s chomlca l class . EYE : Employees shoul d be require d t o wea rchemica l safet

yglasse s t

o preven t eye contact . Atac e shiel d 9houl d b e use d whe n appropriate t

o prevnnt contac

t wit h *pi:i«h-*r i materials . VENTILATION : loca l exhaust ventilatio n shoul d be U3e d t o contro l th e amissio n o fai rcontaminants . Conaru i dilutio n ventilatio n ma yaSStS l Wit h U wiwjuctio n o l ai roor\iamir>3'< t rnnrnnlratlons . ( J I ME R PROTECT1VC EQUIPMENT : Em»«-j<»r.r y-*y e was h Station s an d delug e Safel yShower s Shuuk j 0< * availabl e i n tho wor k

a rva . IX . SPECIA L PRECAUTION S PRECAUTION S T O S E TAKE N I N HANDLIN G AN O STORAGE : Avoi d prolonged orrepeate d contact wit h th e skin . Avoi d ey e contact . Stor

e i n a coo l dr

yarea . D o no

t stor e i n direc

t sunlight . Wor k wit h adequate genera l an d loca l exhaust ventilatio n 1 0 minimize exposur e t o vapors . Bon d an d groun d containers lortransfe ro f thi s produc

t t o preven t stati c sparks . Styren e vapors are uninhibite d an d ma ycaus e blockag o o

fventilatio n venl s du e t o polymeriza tion . Periodi c Inspectio n ma yb e necessar

yto prevon t blockage . OTHE R COMMENTS : Rabbits givo n polyeste rresi n i n th e ey e develope d moderate cornea l injury , iiitl s an d cojunctiva l injur ywil h cornea l vascularization . Howover . al l oye

e noalod b

yda y2 1 (US S Toxicit

yTest Repor

t No . 4/-bQJ) . A(w

wwmbryotoxi c cfloctt . hav e bo*?-* . <*hnw n i n anima l studies . Ou

t result s arc oontlicting . Data nn human s ar

e inconclusiv

e (WH O Envir . Heait n Criteri a 20.82 , 1900) . Chromocoma l abarration s i n cultured pertpheia l lymphocytes occurrin g i n worknr s a t hig h concentration s have bee n reported (n u chang e i n workcrc a t to wlovois . IAR C Suppl . 4:229 . i982) . Thera has bea n insufficien t evidence to establis h a relationshi p wit h cancer , aiihoug n som e studies hav

e implied a n associate d ris k o l leukemi a an d lymphom a (WH O Envir . Healt h Criteri a 28:82 , 1983) . Styren e ma ycaus e changes i n enzymes (decrease d aenltnine . whil e increasin g blood uroa nitroge n (BUN ) an d SGPT . Toy . ADpl . Pharm . 75:346 , \984) . Medica l screenin g shoul d be don e to rthose wit h abnorma l CNS , chroni c respirator ysyste m disorders , ski n disease , kidneyan d live rdisorders .
This .nlftrmittioit

i j liken liQm sources ot

O n se d "PO " 0*H

Oeiisve- fI O Oe 'e'"at»'» . >ioxa>t*er. fititleen Cer-**'* ' Ovporafio i maKas no wai'inty
_ . m m o _oi>.ri_f c coimcine-i nf suiliricWf

.v a-ny ni in* ItMego./xQ

n - ihal .•nrM.ong . n

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rrxqy not 6 e 'AQ__'e

O unaQf paiiCv'a rcono.UonsP.1 4

AlllSTEC H COD E MO . C^OOi F IAR C lia s im-tdaslfled styren o fro m a Grou p 3 e\_b«t«.nc o to a Grou p ow, nnu i lahnln d a s "Possibl yCarcinc-qenl c to Humana! ' T ne wCiasSltlCatlo n 1 8 no

t baso d u n <tu

ysignifican t no

wevldono o tho

t ctyron o might b-

> cArclnng-tnir. , hut rniha ro n a broadcn i o fth a definitio n lo rth e (irou p 2ti Classification . Th a pfHVluu s (JeflMitip n onlycioaaifiod o oubotanoo ac Orwu p 2 Q it vutticion t f<*tcu genl c ovldence existe d i n anima l studios . Th e curren t definitio n accepts limited eviOt-nL o fio m anima l atudioa i t it i s ooupiod v

. ?upponln» j ftvlrtflnnn fro m otha rrelevan t studies . Industr ygroup s an d independen t researc h organization s ar e contestin g th e reclassificatio n du e l o th e curren t inconclusiv e seien t evidenc e linkin g styron o wit h cancer .P.1 5 

# SILMA R REPOR TO F ANALYSI S s K PLAST, C 

### CORPORATION Silma rResin s Divisio n L " 3 ^ ^"t h Va n Nes s Avenu e Hawthorn e -Californi a 9025 0 (213 ) 757-180 1 Fa

x(213 ) 241-572 5 

### D TO : M AHann a Resi n Dist
. Co
. P
. 0 . Bo x42 8 Lemont , I L6043 9 SHI P TO : Hydro System s 50MoorelandRoac l Sim i Valley , C

A9306 5

QUANTITY : ! O F ORDER : Q7-Jun-9 6 SHI P DATE : S/BIL LO F LADIN G NO. : 0040402 4 SHI P VIA : 'OME R ORDE R NO, : 5203 6 J NUMBER. : , 3-121 3 'UMBER : 2711H 6 'SI S NUMBER : 07/09/9 6 SI7Y@ 77 T(5 0 RPM. ) 192 CP S SfT Y@ 7T F (5 RPM. ) 50 4 CPS 6. 5 MINUTE S 8. 5 MINUTE S 27 0 T* JO-Jui-9 6 Odysse v



# 1 \o 

# ^u

1.0%HP-9 0 WE , RT : 3 PEAK' XOTHERM : 

## 'ST% : LIQUID : WS : (G/SQ.M ) S 35 % OR LES

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MATERIA L SAFET Y DAT AS h FO R COATING , RESINS , AN D RELATE D MATERIAL S Dat e o f Preparation
- 09-12-9 5 Prepare d by
Manufacture r Addres s .e n PuLma n

LILL Y INDUSTRIES , INC . 21 0 E . Alondr a E^ouLevar d Gardena , C A9024 8
T e lephone* : <310 ) 352-308 7 Night : (3i0 ) 352-308 7 Emergency* : (310 ) 352-308 7 Night : (800 ) 424-930 0 SECTIO NI PRODUC T IDENTIFICATIO N Manufa c turer ' Produc t Clas s Trad e Name : s Cod e Identification : POLYESTE R GE L COA T WHIT E BAS E 23-396 4 328396 4

HMI S Inform a t i on : HAZAR D INDEX : 4 = Health
- 2 Reac t i vi ty - 2 S&vere 3 = Se r i OU J F La.iima bi I i ty - 3 Persona L Protectiv e Equipment
- X 2 ~ Moderat e 1 TM Sligh t 0 TM Leas t As k you r superv i so r fo r spe c i a I i ze d han d I i n g d i re c t i on s a SECTIO NI I HAZARDOU S INGREDIENT S %STYREN E MONOME R O i %%B Y WT : 34.85 5 EXPOSUR E LIMI T ACGI H TL V

(TWA ) OSH APE L (TWA ) Car e i noge n VAPO R PRESSURE : 50.0 0 PP M 100.0 0 PP M 2B , IAR C CAS * 100--42- 5 9.5 0 MMH G@ 20 C

METHY L METHACRYLAT E 0 2 % B Y WT : EXPOSUR E I
. ACOH OS H A 2.00 0 .IMI T I TL V<TWA ) PE L(TUA ) VAPO R PRESSUR E *
. CAS * QO-62- 6

29.0 0 MMH G @ 20 C 

### 100.0 0 100.0 0 PP M

PP M

SE E DISCLAIME R O N REVERS E SID E 

# / sP.1 7

ENVIRONMENTA L DAT ASHEE T **** * MUS T NO T B E DETACHE D FROMMATERIAL SAFET Y DAT ASHEE T **** * <* * I F MSD S I S COPIE D AND REDISTRIBUTED , THI S NOTIC E MUS T B E ATTACHE D ** * \NUFACTURER : CARGILL , IN C / CP D DAT E O F LAS T CHANGE : 10/28/8 8 230 1 CROSB Y RD . WAYZATA , MN . 5539 1 XODUC T NAME : 28 7 873 7 RODUC T CLASS : UNSATURATE D POLYESTE R RESI N ECTIONI . RO D PRODUC T IDENTIFICATION/COMPOSITION COMPONEN

T CA S NUMBE R PERCENT

1 2 UNSATURATE

D POLYESTE

RRESI N ---TYPICA LDISTRIBUTIO NO FHAZARDOU

S COMPONENTS
ALPH AMETHYLSTYREN

E STYREN E MIXTUR E 10 0 98-83- 9 100-42- 5 1. 3

39. 2 IECTI0 NII . SAR ATITL EII IINFORMATIO N 'RO D P 1 2 EHS RQ(LBS )



## (* D EHS TP Q(LBS ) (*2 ) SE C 31 3

(*3 ) N O YE S 311/31 2 CATEGORIE S

(*4 ) 1 3 5 1 3 5 1 3 5 •FOOTNOTES
- "l = REPORTABL

EQUANTITYOFEXTREMEL YHAZARDOU

S SUBSTANCE , SAR

ASEC.302/30 4 n = THRESHOL

D PLANNINGQUANTITY , EXTREMEL YHAZARDOUS SUBSTANCE , SAR ASEC.30 2 * 3 = TOXI C CHEMICAL , SAR ASEC 31 3 * 4 = HAZAR

D CATEGOR

YFO RSAR ASEC . 311/31 2 REPORTIN G 1 = FIR EHAZAR

D 2 - SUDDE NRELEAS EOFPRESSUREHAZAR D 3 = REACTIV EHAZAR D 4 = IMMEDIATE(ACUTE ) HEALT HHAZAR

D 5 - DELAYE

D (CHRONIC ) HEALT HHAZAR

D SECTIO NIII . DISCLAIME R TH E INFORMATIONI NTHI S MSD S AN D ENVIRONMENTAL DATASHEE T WAS OBTAINE D FROMSOURCE S WHIC H W E BELIEVE AR E RELIABLE . HOWEVER , TH E INFORMATIO NI S PROVIDE D WITHOUT AN Y REPRESENTATIO

NO R WARRANTY . EXPRESSE D O R IMPLIED , REGARDIN

GIT S ACCURAC Y OR COMPLETENESS .



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JCTIO NIV . FIR E AND EXPLOSIO NHAZARD DATA287873 7 (CONT. ) .ASH POINT : 8 6 DEG . F SETAFLAS H FLAMMABILIT Y CLASS : FLAMMABL E LAMMABL E LIMIT S %B Y VOLUM E I NAI R A T 21 2 DEG . F : LOWE R EXPLOSIONLIMIT : 1.9 0 JPPE R EXPLOSIO

NLIMIT : 6.1 0 XTINGUISHIN

GMEDIA : Us e foam , carbo n dioxid e o r chemica l fir e fighting apparatus . PECIAL FIR E FIGHTIN GPROCEDURE S Kee p container s tightl yclosed . Isolat e fromheat , electrica l equipment , spark s an d ope n flame . Close d container s mayexplod e whe n expose d t o extreme heat . NUSUAL FIR E AN

D EXPLOSIONHAZARD S Th e us e o f self-containe d breathing apparatu s i s recommende d fo r fir e fighters . Wate r spra yma yb e use d fo r coolin g container s t o preven t possibl e pressur e build-up an d auto ignitio n o r explosio n whe n expose d t o extreme heat . Avoi d spreading burnin g liqui d wit hwate r use d fo r cooling . SECTIONV . HEALTH HAZARD DATA HRESHOL D LIMI T VALUE : Se e Sectio n II . FFECT S O F OVEREXPOSURE :

- - EYE S CONTACT : Sever e irritation , redness , tearing an d blurre d vision .

- - SKI NCONTACT : Prolonge d o r repeate d exposur e can caus e moderat e irritation , defattin g an

d dermatitis .

- - INHALATION : Excessiv e inhalatio n o f vapor s can caus e nasa l an d respiratory irritation , dizziness , weakness , fatigue , nause a an d headache . Highconcentration s ma yresul t i n narcosis . (Centra l Nervou s Systemdepression )

- - INGESTION : Ca n caus e gastrointestina l irritation , nausea , vomitin g an d diarrhea . Aspiratio n o f materia l int o lung s ca n caus e chemica l pneumoniti s whic hcan b e fatal . "hroni c exposur e ma ycaus e damag e t o the Centra l Nervou s System , inspirator

ySystem , Lungs , Eyes , Skin , Gastrointestina l Tract , -iver , Splee n an

d Kidneys . )THER HEALT H EFFECTS : iase d upo n a re-evaluatio n o f previou s negativ e and equivoca l dat a m d a n increase d incidenc e o f lun g tumor s afte r ora l administratio n L n youn g adul t mice , th e internationa l agenc yfo r researc ho n :ancer(IARC ) ha s liste d styren e amon g thos e material s fo r whic h :her e i s limite d evidenc e fo r carcinogenicit yi n animals . EMERGENCY AN

D FIRS T AI D PROCEDURE S

-- - EYE S CONTACT : Flus hwit hclean , lukewarmwate r fo r a t leas t 1 5 minutes , occasionall yliftin g the eyelids . Obtai n medica l attention .

-- - SKI NCONTACT :



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CTIONV . HEALT H HAZARD DAT A287873 7 (CONT. ) Remov e contaminate d clothing . Was haffecte d ski n area s thoroughl ywit hsoa p and water . Was hcontaminate d clothing thoroughl ybefor e re-use .

- INHALATION : Remov e t o fres hair . Appl yartificia l respiratio n o r administe r oxygen , i f necessary . Cal l a physicia n immediately .

- INGESTION : Keep perso n warm , quie t and ge t immediat e medica l attention . D o no t induc e vomiting , becaus e aspiratio n o f materia l int o the lung s fromvomitin g ca n caus e chemica l pneumoniti s whic h ca n b e fatal . SECTIONVI . REACTIVITY DAT A .ABILITY : Stabl e unde r norma l conditions . Avoi d exposur e t o excessiv e heat . [COMPATIBILITY : Avoi d contac t wit hstrong minera l acids , peroxide s an d polymerizatio n catalysts . .ZARDOUS POLYMERIZATION : Ca n Occur . SECTIONVII . SPIL L OR LEA K PROCEDURE S "EP S T O B E TAKE NI NCAS E MATERIAL I S RELEASE D O R SPILLED : Evacuat e al l non-essentia l personnel . Remov e al l source s o f ignition . Ventilat e th e area . Equi p employee s wit happropriat e protectio n equipmen t (Se e Sectio n VIII) . Dik e aroun d spille d material . Cove r spil l wit hiner t absorben t materia l and shove l wit hnon-sparkin g tool s int o container . Remov e container s t o a saf e are a and seal . \STE DISPOSAL METHOD : Wast e materia l mus t b e dispose d o f i n accordanc e wit hfederal , state , an

d loca l environmenta l regulatorycontrols . SECTIONVIII . SPECIAL PROTECTIO NINFORMATIO

N ESPIRATORY PROTECTION : Avoi d breathin g vapo r o r mist.I f exposur e mayo r doe s excee d occupationa l exposur e limit s (SEC.IV ) us e a NIOSH-approve d res pirato r t o preven t overexposure . I n accor d wit h29CF R 1910.13 4 us e eithe r a full-face , atmosphere-supplying respirato r o r air-purifyin g respirato r fo r organi c vapors . ENTILATION : Loca l exhaus t mus t b e sufficien t t o kee p airborn e vapo r concentration s belo wth e TL V limit . Exhaus t ai r maynee d t o b e cleane d b

yscrubber s o r filter s t o reduc e environmenta l contamination . 

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ECTIO NVIII . SPECIA L PROTECTIONINFORMATIO N287873 7 (CONT. ) ROTECTIVE GLOVES : Polyviny l alcoho l gloves . Y E PROTECTION : Splas hgoggles . THE R PROTECTIV

E EQUIPMENT : Polyviny l alcoho l apron. . Eye bat han d safet yshower . T o preven t repeate d o r prolonge d ski n contact , wea r imperviou s clothin g and boots . [AZARDOU S MATERIAL S IDENTIFICATIONSYSTEM : Se e firs t pag e o f MSDS . SECTIO NIX . SPECIAL PRECAUTIONS 'RECAUTION

S T O B E TAKE NI NHANDLIN GAND STORING : Drums : Protec t agains t physica l damage . Outsid e o r detache d storag e preferred . Bulk : Storag e shoul d b e i n standar d flammabl e liqui d storag e tanks . )THE R PRECAUTIONS : Al l equipmen t shoul d b e grounde d an d bonde d t o reduc e stati c electricit yhazard . Us e non-sparking tools . Overexposur e t o materia l ha s apparentl ybee n foun d t o caus e the following effect s i n laboratoryanimals : live r abnormalities , kidneydamage , lun g damage . RECEN T DAT AHA S SUPPORTE D TH E CHANG E INTH E CLASFICATIO N B Y IAR C O F STYREN E T O B E ASUSPECTE D CARCINOGEN . OTHE R COMMENT S -J e recommen

d tha t container s b e eithe r professionall yreconditione d for reus e b

ycertifie d firm s o r properl ydispose d o f b ycertifie d firms t o hel p reduc e th e possibilit yo f an accident . Disposa l o f nontainer s shoul d b e i n accordanc e wit happlicabl e federal , stat e and loca l law s an

d regulations . "Empty " drum s shoul d no t b e give n t o individuals . Th e informatio n i n thi s MSD S wa s obtaine d fro msource s whic hw e believe ar e reliable . However , the informatio n i s provide d withou t an yrepresentatio n o r warranty , expresse d o r implied , regarding it s accuracyo r completeness . The condition s o f handling , storage , us e an d disposa l o f the produc t ar e beyond ou r contro l and mayb e beyond our knowledge . Fo r thi s and othe r reasons , w e d o no t assum e responsibilit yan d expressl ydisclai m liabilit yfo r loss , damag e o r expens e arising ou t o f o r i n an yway connecte d wit hth e handling , storage , us e o r disposa l o f the product .



# / 9P.2 1 29 1 We . .dams Street Colton , C A9232 4 714/825-985 0 

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## CERTIFICAT E OF " COMPLIA N

Thi s documen t certi-fie a tha t ARISTEC H CHEMICAL CORPORATIO N resi n L B 1042-2 0 meet 3 Sout hCoas t Ai r Qualit yManagemen t District' s rul e No . 1162 , volatil e organi c compound measuremen t o f lea s tha n 6 0 gram s pa r squar e meter .



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