### Name: Phillip J Yates

Title: Production Manager Company: FPL Sign Date: 6/25/2010 Name: Thomas K. Graham Title: Director of Operations Company: Air Hygiene International, Inc. Sign Date: 6/9/2010 Permitted Facility Representative / Date Testing Company Representative / Date



## Martin Energy Center, Unit #1, Information Collection Request Final Test Report for

/ / Based on information and belief formed after reasonable inquiry, I certify that the statements and information in this test report are true, accurate, and complete. I have reviewed all testing details and results in this test report and hereby certify that the test report is authentic and accurate.

Tuesday, February 15, 2011 Page 1 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 Facility Information: Martin Energy Center 21900 SW Warfield Boulevard, SR 710

Indiantown FL34956 Contact:Augie De La Vega Phone: (305) 242-3896 Fax: Email: augie.de.la.vega@fpl.com Testing Company: Air Hygiene International, Inc. 5634 S. 122nd East Ave, Suite F

Tulsa OK74146 Contact:Thomas Graham Phone:(918) 307-8865 Fax: (918) 307-9131 Email: tom@airhygiene.com

Air Permit Number: 0850001-018-AV Permitted Source ID/Name: Foster Wheeler, Wall Fired Boiler PMR1 Permitted Maximum Process Rate: 863.3 MW Max. Normal Operation Process Rate: 800 MW Target Process Test Rate 800 MW

Description of the source (including control equipment). Please see the attachments for source or process flow diagram: Florida Power and Light Company (FPL) operates two oil fired electric utility steam generating units of Foster Wheeler design, designated as Units PMR1 and PMR2. The facility is located at 21900 Southwest Warfield Boulevard, State Route 710 in Indiantown, Florida. Unit PMR1 and PMR2 are of identical design and consists of two wall fired boilers and ancillary equipment designed to generate 863.3 megawatts (MW) of electricity each with rated heat inputs of 8,650 million British thermal units per hour (MMBtu/hr) based on high heating value (HHV). Fuel oil consumption is rated at 600,000 pounds per hour. Unit PMR1 and PMR2 utilize low nitrogen oxide (NOx) burner technology to control NOx emissions and cyclone separators to control particulate matter (PM) emissions. Emission testing will be conducted from platforms on the independent stacks of each unit. Industry/SCC/NAIS221112

Sampling Location Information:

Test Parameter Information: AFS #:0850001 FRS #:110008320566

SCC / Description10100401 External Combustion Boilers - Electric Generation - Residual Oil - Grade 6 Oil: Normal Firing

The following state and federal regulations that apply to the proposed testing:

Location Round

Duct Diam. Distance from upstream dist. Distance from

downstream dist. Number of

Traverse Ports Equiv. Diam Min.Travers Points Rect. Duct Length /Width PMR1 - D/F 357.4 4524 876 4 0 24 0 0 PMR1 - Gases 357.4 4524 876 4 0 1 0 0 PMR1 - Metals357.4 4524 876 4 0 24 0 0 PMR1 - PM 357.4 4524 876 4 0 12 0 0

Target Parameter Test Method Number of

Test Runs Test Run

Duration Sample

Points Comments Location Regulation Description Compound Limit Unit Not applicable.



### Tuesday, February 15, 2011 Page 2 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 Target Parameter Test Method Number of

Test Runs Test Run

Duration Sample

Points Comments Location % H2O Method 1 - 4 3 480 24 PMR1 - D/F 2,3,7,8-TCDD Method 23 3 480 24 PMR1 - D/F 1,2,3,7,8-PeCDD Method 23 3 480 24 PMR1 - D/F 1,2,3,4,7,8-HxCDD Method 23 3 480 24 PMR1 - D/F 1,2,3,6,7,8-HxCDD Method 23 3 480 24 PMR1 - D/F 1,2,3,7,8,9-HxCDD Method 23 3 480 24 PMR1 - D/F 1,2,3,4,6,7,8-HpCDD Method 23 3 480 24 PMR1 - D/F OCDD Method 23 3 480 24 PMR1 - D/F 2,3,7,8-TCDF Method 23 3 480 24 PMR1 - D/F 1,2,3,7,8-PeCDF Method 23 3 480 24 PMR1 - D/F 2,3,4,7,8-PeCDF Method 23 3 480 24 PMR1 - D/F 1,2,3,4,7,8-HxCDF Method 23 3 480 24 PMR1 - D/F 1,2,3,6,7,8-HxCDF Method 23 3 480 24 PMR1 - D/F 2,3,4,6,7,8-HxCDF Method 23 3 480 24 PMR1 - D/F 1,2,3,7,8,9-HxCDF Method 23 3 480 24 PMR1 - D/F 1,2,3,4,6,7,8-HpCDF Method 23 3 480 24 PMR1 - D/F 1,2,3,4,7,8,9-HpCDF Method 23 3 480 24 PMR1 - D/F OCDF Method 23 3 480 24 PMR1 - D/F Total Dioxins Method 23 3 480 24 PMR1 - D/F Total Furans Method 23 3 480 24 PMR1 - D/F 3,3',4,4'-TCB (PCB77) Method 23 3 480 24 PMR1 - D/F 3,4,4',5-TCB (PCB81) Method 23 3 480 24 PMR1 - D/F 2,3,3',4,4'-PeCB (PCB105) Method 23 3 480 24 PMR1 - D/F 2,3,4,4',5-PeCB (PCB114) Method 23 3 480 24 PMR1 - D/F 2,3',4,4',5-PeCB (PCB118) Method 23 3 480 24 PMR1 - D/F 2',3,4,4',5-PeCB (PCB123) Method 23 3 480 24 PMR1 - D/F 3,3',4,4',5-PeCB (PCB126) Method 23 3 480 24 PMR1 - D/F 2,3,3',4,4',5/2,3,3',4,4',5'-

HxCB (PCBs156/157) Method 23 3 480 24 PMR1 - D/F
2,3',4,4',5,5'-HxCB (PCB167)Method 23 3 480 24 PMR1 - D/F 3,3',4,4',5,5'-HxCB (PCB169)Method 23 3 480 24 PMR1 - D/F 2,3,3',4,4',5,5'-HpCB

(PCB189) Method 23 3 480 24 PMR1 - D/F

O2 Method 3A O2 3 480 24 PMR1 - D/F Co2 Method 3A CO2 3 480 24 PMR1 - D/F % H2O Method 1 - 4 3 120 1 Determined after initial stratification test PMR1 - Gases

Carbon Monoxide Method 10 3 120 1 Determined after initial stratification test PMR1 - Gases
Total organic compounds

(TOC) as Propane Method 25A 3 120 1 Determined after initial stratification test PMR1 - Gases

O2 Method 3A O2 3 120 1 Determined after initial stratification test PMR1 - Gases

Co2 Method 3A CO2 3 120 1 Determined after initial stratification test PMR1 - Gases

Sulfur Dioxide Method 6C 3 120 1 Determined after initial stratification test PMR1 - Gases
Nitrogen oxides (NOx) Method 7E 3 120 1 Determined after initial stratification test PMR1 - Gases

% H2O Method 1 - 4 3 240 24 PMR1 - MetalsSelenium Method 29 3 240 24 PMR1 - MetalsManganese Method 29 3 240 24 PMR1 - Metals


### Tuesday, February 15, 2011 Page 3 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010

The following describes any modifications and/or deviations to the applicable test methods. If alternative methods were requested, see the attachments for documentation of request AND approval, including dates. PM Run All - reduced to 2 hour runs to avoid high vacuum, did not pull required volumes.
PM Run 1 - oily substance in organic backhalf.

Lead Method 29 3 240 24 PMR1 - MetalsFilterable Particulate Method 29 3 240 24 PMR1 - MetalsCobalt Method 29 3 240 24 PMR1 - MetalsCadmium Method 29 3 240 24 PMR1 - MetalsChromium Method 29 3 240 24 PMR1 - MetalsNickel Method 29 3 240 24 PMR1 - MetalsCo2 Method 3A CO2 3 240 24 PMR1 - MetalsO2 Method 3A O2 3 240 24 PMR1 - Metals% H2O Method 1 - 4 3 120 12 Run times vary based on method calculations PMR1 - PM

Filterable Particulate OTM - 27/28 3 120 12 Run times vary based on method calculations PMR1 - PM

Filterable PM2.5 OTM - 27/28 3 120 12 Run times vary based on method calculations PMR1 - PM
Inorganic (Aqueous)

Condensible Part. OTM - 27/28 3 120 12 Run times vary based on method calculations PMR1 - PM
Organic Condensible

Particulate OTM - 27/28 3 120 12 Run times vary based on method calculations PMR1 - PM

Total PM2.5 OTM - 27/28 3 120 12 Run times vary based on method calculations PMR1 - PM

Total Particulate OTM - 27/28 3 120 12 Run times vary based on method calculations PMR1 - PM

O2 Method 3A O2 3 120 12 Run times vary based on method calculations PMR1 - PM

Co2 Method 3A CO2 3 120 12 Run times vary based on method calculations PMR1 - PM



### Tuesday, February 15, 2011 Page 4 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 Sampling / Stack Data Results Summary


### Location PMR1 - D/F - Method 23 Average Run Number PMR1-23-1 PMR1-23- 2 PMR1-23-3

Test Date 4/6/2010 4/7/2010 4/8/2010 Run Start Time 9:15:00 AM2:15:00 PM11:48:00 AM Run Finish Time 5:15:00 PM 10:15:00 PM 7:48:00 PM

Net Run Time, minutes 480 480 480 Dry Gas Meter Volume Sampled, dscf 342.102 316.770 317.751 325.541 Moisture Content of Stack Gas, % 8.97 10.18 9.37 9.507 Moisture Saturation at Stack Gas Temperature, % 100.00 100.00 100.00 100.000 Carbon Dioxide, % 13.03 13.01 13.11 13.050 Oxygen, % 4.58 4.5 4.55 4.543 Average Stack Gas Temperature, °F 338.50 342.96 348.75 343.403 Dry Volumetric Flow Rate, dry scfm 1,506,480.31,366,774.5 1,384,716.81,419,323.86 7 Actual Wet Volumetric Flue Gas Flow Rate, acfm 2,475,461.12,314,108.9 2,344,205.72,377,925.23 3 Percent Isokinetic of Sampling Rate, % 96.7 98.7 97.7 97.700 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Fw 10320 10320 10320 10,320.000 Fc 1420 1420 1420 1,420.000



### Location PMR1 - Gases - Method 10 Average Run Number 1-CO-1 1-CO-2 1-CO-3 Test Date 4/6/2010 4/6/2010 4/6/2010 Run Start Time 10:23:11 AM 12:23:11 PM 4:36:41 PM

Run Finish Time 12:22:41 PM4:36:11 PM 7:42:41 PM Carbon Dioxide, % 12.99 13.17 13.21 13.123 Oxygen, % 4.47 4.54 4.49 4.500 Dry Volumetric Flow Rate, dry scfm 1506474 1506474 15064741,506,474.00 0 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Moisture, % 8.98 8.98 8.98 8.980 Fuel Type Oil Oil Oil Fw 10320 10320 10320 10,320.000 Fc 1420 1420 1420 1,420.000



### Tuesday, February 15, 2011 Page 5 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010
Location PMR1 - Gases - Method 25A Average Run Number 1-THC-1 1-THC-2 1-THC-3 Test Date 4/6/2010 4/6/2010 4/6/2010 Run Start Time 10:23:11 AM 12:23:11 PM 4:36:41 PM

Run Finish Time 12:22:41 PM4:36:11 PM 7:42:41 PM Carbon Dioxide, % 12.99 13.17 13.21 13.123 Oxygen, % 4.47 4.54 4.49 4.500 Dry Volumetric Flow Rate, dry scfm 1506474 1506474 15064741,506,474.00 0 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Moisture, % 8.98 8.98 8.98 8.980 Fuel Type Oil Oil Oil Fw 10320 10320 10320 10,320.000 Fc 1420 1420 1420 1,420.000



### Location PMR1 - Gases - Method 3A CO2 Average Run Number 1-CO2-1 1-CO2-2 1-CO2-3 Test Date 4/6/2010 4/6/2010 4/6/2010 Run Start Time 10:23:11 AM 12:23:11 PM 4:36:41 PM

Run Finish Time 12:22:41 PM4:36:11 PM 7:42:41 PM Carbon Dioxide, % 12.99 13.17 13.21 13.123 Oxygen, % 4.47 4.54 4.49 4.500 Dry Volumetric Flow Rate, dry scfm 1506474 1506474 15064741,506,474.00 0 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Moisture, % 8.98 8.98 8.98 8.980 Fuel Type Oil Oil Oil Fw 10320 10320 10320 10,320.000 Fc 1420 1420 1420 1,420.000



### Tuesday, February 15, 2011 Page 6 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010
Location PMR1 - Gases - Method 3A O2 Average Run Number 1-O2-1 1-O2-2 1-O2-3 Test Date 4/6/2010 4/6/2010 4/6/2010 Run Start Time 10:23:11 AM 12:23:11 PM 4:36:41 PM

Run Finish Time 12:22:41 PM4:36:11 PM 7:42:41 PM Carbon Dioxide, % 12.99 13.17 13.21 13.123 Oxygen, % 4.47 4.54 4.49 4.500 Dry Volumetric Flow Rate, dry scfm 1506474 1506474 15064741,506,474.00 0 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Moisture, % 8.98 8.98 8.98 8.980 Fuel Type Oil Oil Oil Fw 10320 10320 10320 10,320.000 Fc 1420 1420 1420 1,420.000



### Location PMR1 - Gases - Method 6C Average Run Number 1-SO2-1 1-SO2-2 1-SO2-3 Test Date 4/6/2010 4/6/2010 4/6/2010 Run Start Time 10:23:11 AM 12:23:11 PM 4:36:41 PM

Run Finish Time 12:22:41 PM4:36:11 PM 7:42:41 PM Carbon Dioxide, % 12.99 13.17 13.21 13.123 Oxygen, % 4.47 4.54 4.49 4.500 Dry Volumetric Flow Rate, dry scfm 1506474 1506474 15064741,506,474.00 0 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Moisture, % 8.98 8.98 8.98 8.980 Fuel Type Oil Oil Oil Fw 10320 10320 10320 10,320.000 Fc 1420 1420 1420 1,420.000



### Tuesday, February 15, 2011 Page 7 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010
Location PMR1 - Gases - Method 7E Average Run Number 1-NOx-1 1-NOx-2 1-NOx-3 Test Date 4/6/2010 4/6/2010 4/6/2010 Run Start Time 10:23:11 AM 12:23:11 PM 4:36:41 PM

Run Finish Time 12:22:41 PM4:36:11 PM 7:42:41 PM Carbon Dioxide, % 12.99 13.17 13.21 13.123 Oxygen, % 4.47 4.54 4.49 4.500 Dry Volumetric Flow Rate, dry scfm 1506474 1506474 15064741,506,474.00 0 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Moisture, % 8.98 8.98 8.98 8.980 Fuel Type Oil Oil Oil Fw 10320 10320 10320 10,320.000 Fc 1420 1420 1420 1,420.000



### Location PMR1 - Metals - Method 29 Average Run Number PMR1-29-1 PMR1-29- 2 PMR1-29-3

Test Date 4/7/2010 4/8/2010 4/8/2010 Run Start Time 2:32:00 PM 8:32:00 AM 5:31:00 PM

Run Finish Time 6:32:00 PM 12:32:00 PM 9:31:00 PM

Net Run Time, minutes 240 240 240 Dry Gas Meter Volume Sampled, dscf 154.179 156.378 148.957 153.171 Moisture Content of Stack Gas, % 10.20 10.40 10.36 10.320 Moisture Saturation at Stack Gas Temperature, % 100.00 100.00 100.00 100.000 Carbon Dioxide, % 13.01 13.11 13.11 13.077 Oxygen, % 4.5 4.55 4.55 4.533 Average Stack Gas Temperature, °F 346.67 342.79 347.92 345.793 Dry Volumetric Flow Rate, dry scfm 1,350,111.91,340,540.0 1,258,404.81,316,352.23 3 Actual Wet Volumetric Flue Gas Flow Rate, acfm 2,296,970.42,283,176.1 2,158,190.82,246,112.43 3 Percent Isokinetic of Sampling Rate, % 97.2 99.3 100.8 99.100 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Fw 10320 10320 10320 10,320.000 Fc 1420 1420 1420 1,420.000



### Tuesday, February 15, 2011 Page 8 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010
Location PMR1 - PM - OTM - 27/28 Average Run Number PMR1- 27/28-1 PMR1-

27/28-2 PMR1-

27/28-3 Test Date 4/7/2010 4/8/2010 4/9/2010 Run Start Time 8:43:00 AM2:12:00 PM 9:49:00 AM Run Finish Time 1:00:00 PM5:06:00 PM12:37:00 PM Net Run Time, minutes 123 124 125 Dry Gas Meter Volume Sampled, dscf 40.193 42.821 41.633 41.549 Moisture Content of Stack Gas, % 9.17 9.14 9.20 9.170 Moisture Saturation at Stack Gas Temperature, % 100.00 100.00 100.00 100.000 Carbon Dioxide, % 13.01 13.11 13.11 13.077 Oxygen, % 4.5 4.55 4.55 4.533 Average Stack Gas Temperature, °F 338.25 350.67 346.17 345.030 Dry Volumetric Flow Rate, dry scfm 1,419,597.71,364,555.3 1,384,838.91,389,663.96 7 Actual Wet Volumetric Flue Gas Flow Rate, acfm 2,337,099.52,312,018.8 2,339,607.62,329,575.30 0 Percent Isokinetic of Sampling Rate, % 99.4 109.3 103.8 104.167 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Fw 10320 10320 10320 10,320.000 Fc 1420 1420 1420 1,420.000



### Tuesday, February 15, 2011 Page 9 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 Emissions Summary


### Location: PMR1 - D/F - Method 23 Compound: 1,2,3,4,6,7,8-HpCDD Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000052 0.000000008 0.0000000031 0.000 lb/mmBtuO2 3.94E-13 6.52E-13 2.53E-13 0.000 ng/dscm 5.37E-04 8.92E-04 3.45E-04 0.001 ng/dscm@7%O2 4.57E-04 7.56E-04 2.93E-04 0.001 

### Compound: 1,2,3,4,6,7,8-HpCDF Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.00000000648 0.0000000074 0.00000000405 0.000 lb/mmBtuO2 4.91E-13 6.03E-13 3.30E-13 0.000 ng/dscm 6.69E-04 8.25E-04 4.50E-04 0.001 ng/dscm@7%O2 5.70E-04 6.99E-04 3.83E-04 0.001 

### Compound: 1,2,3,4,7,8,9-HpCDF Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000039 0.000000003 0.0000000021 0.000 lb/mmBtuO2 2.96E-13 2.45E-13 1.71E-13 0.000 ng/dscm 4.03E-04 3.35E-04 2.33E-04 0.000 ng/dscm@7%O2 3.43E-04 2.84E-04 1.98E-04 0.000 

### Compound: 1,2,3,4,7,8-HxCDD Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000015 0.000000002 0.0000000014 0.000 lb/mmBtuO2 1.14E-13 1.63E-13 1.14E-13 0.000 ng/dscm 1.55E-04 2.23E-04 1.56E-04 0.000 ng/dscm@7%O2 1.32E-04 1.89E-04 1.33E-04 0.000 

### Compound: 1,2,3,4,7,8-HxCDF Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000015 0.0000000038 0.0000000012 0.000 lb/mmBtuO2 1.14E-13 3.10E-13 9.78E-14 0.000 ng/dscm 1.55E-04 4.24E-04 1.33E-04 0.000 ng/dscm@7%O2 1.32E-04 3.59E-04 1.13E-04 0.000 

### Compound: 1,2,3,6,7,8-HxCDD Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000032 0.00000000259 0.0000000023 0.000 lb/mmBtuO2 2.43E-13 2.11E-13 1.87E-13 0.000 ng/dscm 3.30E-04 2.89E-04 2.56E-04 0.000 ng/dscm@7%O2 2.81E-04 2.45E-04 2.18E-04 0.000 

### Compound: 1,2,3,6,7,8-HxCDF Average



### Tuesday, February 15, 2011 Page 10 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010
RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000028 0.0000000014 0.0000000011 0.000 lb/mmBtuO2 2.12E-13 1.14E-13 8.97E-14 0.000 ng/dscm 2.89E-04 1.56E-04 1.22E-04 0.000 ng/dscm@7%O2 2.46E-04 1.32E-04 1.04E-04 0.000 

### Compound: 1,2,3,7,8,9-HxCDD Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000018 0.0000000036 0.0000000014 0.000 lb/mmBtuO2 1.37E-13 2.93E-13 1.14E-13 0.000 ng/dscm 1.86E-04 4.01E-04 1.56E-04 0.000 ng/dscm@7%O2 1.58E-04 3.40E-04 1.33E-04 0.000 

### Compound: 1,2,3,7,8,9-HxCDF Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.00000000293 0.000000003 0.00000000118 0.000 lb/mmBtuO2 2.22E-13 2.45E-13 9.62E-14 0.000 ng/dscm 3.03E-04 3.35E-04 1.31E-04 0.000 ng/dscm@7%O2 2.58E-04 2.84E-04 1.11E-04 0.000 

### Compound: 1,2,3,7,8-PeCDD Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000033 0.0000000025 0.0000000019 0.000 lb/mmBtuO2 2.50E-13 2.04E-13 1.55E-13 0.000 ng/dscm 3.41E-04 2.79E-04 2.11E-04 0.000 ng/dscm@7%O2 2.90E-04 2.36E-04 1.79E-04 0.000 

### Compound: 1,2,3,7,8-PeCDF Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000038 0.0000000027 0.0000000011 0.000 lb/mmBtuO2 2.88E-13 2.20E-13 8.97E-14 0.000 ng/dscm 3.92E-04 3.01E-04 1.22E-04 0.000 ng/dscm@7%O2 3.34E-04 2.55E-04 1.04E-04 0.000 

### Compound: 2,3,3',4,4',5,5'-HpCB (PCB189) Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.00000000561 0.0000000072 0.0000000035 0.000 lb/mmBtuO2 4.25E-13 5.87E-13 2.85E-13 0.000 ng/dscm 5.79E-04 8.03E-04 3.89E-04 0.001 ng/dscm@7%O2 4.93E-04 6.81E-04 3.31E-04 0.001 

### Compound: 2,3,3',4,4',5/2,3,3',4,4',5'-HxCB (PC Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000129 0.000000015 0.0000000122 0.000 lb/mmBtuO2 9.78E-13 1.22E-12 9.94E-13 0.000 ng/dscm 1.33E-03 1.67E-03 1.36E-03 0.001 ng/dscm@7%O2 1.13E-03 1.42E-03 1.16E-03 0.001



### Tuesday, February 15, 2011 Page 11 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 Compound: 2,3,3',4,4'-PeCB (PCB105) Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.000000401 0.000000483 0.000000261 0.000 lb/mmBtuO2 3.04E-11 3.94E-11 2.13E-11 0.000 ng/dscm 4.14E-02 5.39E-02 2.90E-02 0.041 ng/dscm@7%O2 3.53E-02 4.57E-02 2.47E-02 0.035 

### Compound: 2,3',4,4',5,5'-HxCB (PCB167) Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.000000017 0.000000026 0.0000000176 0.000 lb/mmBtuO2 1.29E-12 2.12E-12 1.43E-12 0.000 ng/dscm 1.76E-03 2.90E-03 1.96E-03 0.002 ng/dscm@7%O2 1.50E-03 2.46E-03 1.67E-03 0.002 

### Compound: 2,3,4,4',5-PeCB (PCB114) Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000463 0.000000033 0.00000002 0.000 lb/mmBtuO2 3.51E-12 2.69E-12 1.63E-12 0.000 ng/dscm 4.78E-03 3.68E-03 2.22E-03 0.004 ng/dscm@7%O2 4.07E-03 3.12E-03 1.89E-03 0.003 

### Compound: 2,3',4,4',5-PeCB (PCB118) Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.00000114 0.00000126 0.000000695 0.000 lb/mmBtuO2 8.65E-11 1.03E-10 5.66E-11 0.000 ng/dscm 1.18E-01 1.40E-01 7.73E-02 0.112 ng/dscm@7%O2 1.01E-01 1.19E-01 6.57E-02 0.095 

### Compound: 2',3,4,4',5-PeCB (PCB123) Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.000000023 0.0000000219 0.000000014 0.000 lb/mmBtuO2 1.74E-12 1.79E-12 1.14E-12 0.000 ng/dscm 2.37E-03 2.44E-03 1.56E-03 0.002 ng/dscm@7%O2 2.02E-03 2.07E-03 1.33E-03 0.002 

### Compound: 2,3,4,6,7,8-HxCDF Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000046 0.00000000543 0.0000000033 0.000 lb/mmBtuO2 3.49E-13 4.43E-13 2.69E-13 0.000 ng/dscm 4.75E-04 6.05E-04 3.67E-04 0.000 ng/dscm@7%O2 4.05E-04 5.13E-04 3.12E-04 0.000 

### Compound: 2,3,4,7,8-PeCDF Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.00000000603 0.0000000017 0.0000000033 0.000 lb/mmBtuO2 4.57E-13 1.39E-13 2.69E-13 0.000



### Tuesday, February 15, 2011 Page 12 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 ng/dscm 6.23E-04 1.90E-04 3.67E-04 0.000 ng/dscm@7%O2 5.31E-04 1.61E-04 3.12E-04 0.000 

### Compound: 2,3,7,8-TCDD Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000018 0.0000000026 0.0000000023 0.000 lb/mmBtuO2 1.37E-13 2.12E-13 1.87E-13 0.000 ng/dscm 1.86E-04 2.90E-04 2.56E-04 0.000 ng/dscm@7%O2 1.58E-04 2.46E-04 2.18E-04 0.000 

### Compound: 2,3,7,8-TCDF Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000023 0.0000000015 0.0000000021 0.000 lb/mmBtuO2 1.74E-13 1.22E-13 1.71E-13 0.000 ng/dscm 2.37E-04 1.67E-04 2.33E-04 0.000 ng/dscm@7%O2 2.02E-04 1.42E-04 1.98E-04 0.000 

### Compound: 3,3',4,4',5,5'-HxCB (PCB169) Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.00000000069 0.0000000048 0.00000000065 0.000 lb/mmBtuO2 5.23E-14 3.91E-13 5.30E-14 0.000 ng/dscm 7.12E-05 5.35E-04 7.23E-05 0.000 ng/dscm@7%O2 6.06E-05 4.53E-04 6.15E-05 0.000 

### Compound: 3,3',4,4',5-PeCB (PCB126) Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.000000007 0.0000000046 0.0000000058 0.000 lb/mmBtuO2 5.31E-13 3.75E-13 4.73E-13 0.000 ng/dscm 7.23E-04 5.13E-04 6.45E-04 0.001 ng/dscm@7%O2 6.16E-04 4.35E-04 5.48E-04 0.001 

### Compound: 3,3',4,4'-TCB (PCB77) Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.00000022 0.000000247 0.000000108 0.000 lb/mmBtuO2 1.67E-11 2.01E-11 8.80E-12 0.000 ng/dscm 2.27E-02 2.75E-02 1.20E-02 0.021 ng/dscm@7%O2 1.93E-02 2.33E-02 1.02E-02 0.018 

### Compound: 3,4,4',5-TCB (PCB81) Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000111 0.0000000151 0.00000000777 0.000 lb/mmBtuO2 8.42E-13 1.23E-12 6.33E-13 0.000 ng/dscm 1.15E-03 1.68E-03 8.64E-04 0.001 ng/dscm@7%O2 9.79E-04 1.42E-03 7.35E-04 0.001 

### Compound: OCDD Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3


### Tuesday, February 15, 2011 Page 13 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 Mass_mg 0.000000021 0.000000025 0.000000021 0.000 lb/mmBtuO2 1.59E-12 2.04E-12 1.71E-12 0.000 ng/dscm 2.17E-03 2.79E-03 2.33E-03 0.002 ng/dscm@7%O2 1.85E-03 2.36E-03 1.98E-03 0.002 

### Compound: OCDF Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.000000018 0.0000000093 0.0000000041 0.000 lb/mmBtuO2 1.37E-12 7.58E-13 3.34E-13 0.000 ng/dscm 1.86E-03 1.04E-03 4.56E-04 0.001 ng/dscm@7%O2 1.58E-03 8.81E-04 3.88E-04 0.001 

### Compound: Total Dioxins Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.0000000378 0.00000004629 0.0000000334 0.000 lb/mmBtuO2 2.87E-12 3.77E-12 2.72E-12 0.000 ng/dscm 3.90E-03 5.16E-03 3.71E-03 0.004 ng/dscm@7%O2 3.32E-03 4.37E-03 3.15E-03 0.004 

### Compound: Total Furans Average RunNumber PMR1-23-1 PMR1-23-2 PMR1-23-3 Mass_mg 0.00000005234 0.00000003923 0.00000002353 0.000 lb/mmBtuO2 3.97E-12 3.20E-12 1.92E-12 0.000 ng/dscm 5.40E-03 4.37E-03 2.62E-03 0.004 ng/dscm@7%O2 4.60E-03 3.70E-03 2.23E-03 0.004



### Location: PMR1 - Gases - Method 10 Compound: Carbon Monoxide Average Run 1-CO-1 1-CO-2 1-CO-3 lb/mmBtuO2 3.63E-01 4.28E-01 4.52E-01 0.414 ppm 4.27E+02 5.01E+02 5.32E+02 486.667 ppm@7%O2 3.61E+02 4.26E+02 4.51E+02 412.667



### Location: PMR1 - Gases - Method 25A Compound: Total organic compounds (TOC) as Average Run 1-THC-1 1-THC-2 1-THC-3 lb/mmBtuO2 -6.07E-05 1.35E-03 9.39E-04 0.001 ppm -4.54E-02 1.00E+00 7.01E-01 0.552 ppm@7%O2 -3.84E-02 8.50E-01 5.94E-01 0.469



### Location: PMR1 - Gases - Method 6C Compound: Sulfur Dioxide Average Run 1-SO2-1 1-SO2-2 1-SO2-3 lb/mmBtuO2 6.74E-01 6.80E-01 6.74E-01 0.676 ppm 3.47E+02 3.49E+02 3.47E+02 347.667 ppm@7%O2 2.94E+02 2.97E+02 2.94E+02 295.000



### Tuesday, February 15, 2011 Page 14 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010

Location: PMR1 - Gases - Method 7E 

### Compound: Nitrogen oxides (NOx) Average Run 1-NOx-1 1-NOx-2 1-NOx-3 lb/mmBtuO2 2.96E-01 2.96E-01 3.01E-01 0.298 ppm 2.12E+02 2.11E+02 2.16E+02 213.000 ppm@7%O2 1.79E+02 1.79E+02 1.83E+02 180.333



### Location: PMR1 - Metals - Method 29 

### Compound: Antimony Average RunNumber PMR1-29-1 PMR1-29-2 PMR1-29-3 Mass_mg 0.289 0.278 0.243 0.270 Elb/hr 3.35E-01 3.15E-01 2.72E-01 0.307 lb/mmBtuO2 4.84E-05 4.60E-05 4.22E-05 0.000 mg/dscm 6.62E-02 6.28E-02 5.76E-02 0.062 mg/dscm@7%O2 5.61E-02 5.34E-02 4.90E-02 0.053 

### Compound: Arsenic Average RunNumber PMR1-29-1 PMR1-29-2 PMR1-29-3 Mass_mg 0.0174 0.0159 0.015 0.016 Elb/hr 2.02E-02 1.80E-02 1.68E-02 0.018 lb/mmBtuO2 2.91E-06 2.63E-06 2.61E-06 0.000 mg/dscm 3.99E-03 3.59E-03 3.56E-03 0.004 mg/dscm@7%O2 3.38E-03 3.05E-03 3.03E-03 0.003 

### Compound: Beryllium Average RunNumber PMR1-29-1 PMR1-29-2 PMR1-29-3 Mass_mg 0.0018 0.00178 0.00131 0.002 Elb/hr 2.08E-03 2.02E-03 1.46E-03 0.002 lb/mmBtuO2 3.01E-07 2.95E-07 2.28E-07 0.000 mg/dscm 4.12E-04 4.02E-04 3.11E-04 0.000 mg/dscm@7%O2 3.49E-04 3.42E-04 2.64E-04 0.000 

### Compound: Cadmium Average RunNumber PMR1-29-1 PMR1-29-2 PMR1-29-3 Mass_mg 0.000532 0.000516 0.000366 0.000 Elb/hr 6.16E-04 5.85E-04 4.09E-04 0.001 lb/mmBtuO2 8.91E-08 8.55E-08 6.36E-08 0.000 mg/dscm 1.22E-04 1.17E-04 8.68E-05 0.000 mg/dscm@7%O2 1.03E-04 9.95E-05 7.38E-05 0.000 

### Compound: Chromium Average RunNumber PMR1-29-1 PMR1-29-2 PMR1-29-3 Mass_mg 0.018 0.016 0.014 0.016 Elb/hr 2.08E-02 1.81E-02 1.56E-02 0.018 lb/mmBtuO2 3.01E-06 2.65E-06 2.43E-06 0.000 mg/dscm 4.12E-03 3.61E-03 3.32E-03 0.004



### Tuesday, February 15, 2011 Page 15 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 mg/dscm@7%O2 3.49E-03 3.07E-03 2.82E-03 0.003 

### Compound: Cobalt Average RunNumber PMR1-29-1 PMR1-29-2 PMR1-29-3 Mass_mg 0.226 0.212 0.197 0.212 Elb/hr 2.62E-01 2.40E-01 2.20E-01 0.241 lb/mmBtuO2 3.78E-05 3.51E-05 3.43E-05 0.000 mg/dscm 5.18E-02 4.79E-02 4.67E-02 0.049 mg/dscm@7%O2 4.39E-02 4.07E-02 3.97E-02 0.041 

### Compound: Filterable Particulate Average RunNumber PMR1-29-1 PMR1-29-2 PMR1-29-3 Mass_mg 188.7 164.7 160.4 171.267 Elb/hr 2.19E+02 1.87E+02 1.79E+02 195.000 lb/mmBtuO2 3.16E-02 2.73E-02 2.79E-02 0.029 mg/dscm 4.32E+01 3.72E+01 3.80E+01 39.467 mg/dscm@7%O2 3.66E+01 3.16E+01 3.23E+01 33.500 

### Compound: Lead Average RunNumber PMR1-29-1 PMR1-29-2 PMR1-29-3 Mass_mg 0.0559 0.0547 0.049 0.053 Elb/hr 6.48E-02 6.20E-02 5.48E-02 0.061 lb/mmBtuO2 9.36E-06 9.06E-06 8.52E-06 0.000 mg/dscm 1.28E-02 1.24E-02 1.16E-02 0.012 mg/dscm@7%O2 1.08E-02 1.05E-02 9.86E-03 0.010 

### Compound: Manganese Average RunNumber PMR1-29-1 PMR1-29-2 PMR1-29-3 Mass_mg 0.286 0.26 0.239 0.262 Elb/hr 3.31E-01 2.95E-01 2.67E-01 0.298 lb/mmBtuO2 4.79E-05 4.31E-05 4.16E-05 0.000 mg/dscm 6.55E-02 5.87E-02 5.67E-02 0.060 mg/dscm@7%O2 5.55E-02 4.99E-02 4.82E-02 0.051 

### Compound: Nickel Average RunNumber PMR1-29-1 PMR1-29-2 PMR1-29-3 Mass_mg 2.75 2.45 2.17 2.457 Elb/hr 3.19E+00 2.78E+00 2.42E+00 2.797 lb/mmBtuO2 4.61E-04 4.06E-04 3.77E-04 0.000 mg/dscm 6.30E-01 5.53E-01 5.15E-01 0.566 mg/dscm@7%O2 5.34E-01 4.70E-01 4.38E-01 0.481 

### Compound: Selenium Average RunNumber PMR1-29-1 PMR1-29-2 PMR1-29-3 Mass_mg 0.0399 0.0201 0.0175 0.026 Elb/hr 4.62E-02 2.28E-02 1.96E-02 0.030 lb/mmBtuO2 6.68E-06 3.33E-06 3.04E-06 0.000 mg/dscm 9.14E-03 4.54E-03 4.15E-03 0.006


### Tuesday, February 15, 2011 Page 16 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010

Process Run Data mg/dscm@7%O2 7.75E-03 3.86E-03 3.53E-03 0.005



### Location: PMR1 - PM - OTM - 27/28 Compound: Filterable Particulate Average RunNumber PMR1-27/28-1 PMR1-27/28-2 PMR1-27/28-3 Mass_mg 41 42.57 44.27 42.613 lb/mmBtuO2 2.63E-02 2.57E-02 2.75E-02 0.027 

### Compound: Filterable PM2.5 Average RunNumber PMR1-27/28-1 PMR1-27/28-2 PMR1-27/28-3 Mass_mg 28.3 33.425 31.4 31.042 lb/mmBtuO2 1.82E-02 2.02E-02 1.95E-02 0.019 

### Compound: Inorganic (Aqueous) Condensible Pa Average RunNumber PMR1-27/28-1 PMR1-27/28-2 PMR1-27/28-3 Mass_mg 1.504 0 0.93 0.811 lb/mmBtuO2 9.66E-04 0.00E+00 5.79E-04 0.001 

### Compound: Organic Condensible Particulate Average RunNumber PMR1-27/28-1 PMR1-27/28-2 PMR1-27/28-3 Mass_mg 148.981 1.031 0.806 50.273 lb/mmBtuO2 9.57E-02 6.24E-04 5.01E-04 0.032 

### Compound: Total Particulate Average RunNumber PMR1-27/28-1 PMR1-27/28-2 PMR1-27/28-3 Mass_mg 191.485 43.601 46.006 93.697 lb/mmBtuO2 1.23E-01 2.64E-02 2.86E-02 0.059 

### Compound: Total PM2.5 Average RunNumber PMR1-27/28-1 PMR1-27/28-2 PMR1-27/28-3 Mass_mg 178.785 34.456 33.136 82.126 lb/mmBtuO2 1.15E-01 2.08E-02 2.06E-02 0.052



### Tuesday, February 15, 2011 Page 17 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 Process Run Data



### Run Name Value UOM Comments Target Value 1 Residual Oil (No. 6) Burned 57898 gal/hr Methods 6c, 7e, 10, and 25a; Run RM-1 and FTIR-1; Date - 4/6/2010; Start - 10:23; End - 12:22 0



### 10Residual Oil (No. 6) Burned 58126 gal/hr Method 027/028; Run PM-1; Date - 4/7/2010; Start - 08:43; End - 13:00 0

11Residual Oil (No. 6) Burned 57950 gal/hr Method 027/028; Run PM-2; Date - 4/8/2010; Start - 14:12; End - 17:06 0

12Residual Oil (No. 6) Burned 58184 gal/hr Method 027/028; Run PM-3; Date - 4/9/2010; Start - 09:49; End - 12:37 0

2 Residual Oil (No. 6) Burned 57928 gal/hr Methods 6c, 7e, 10, and 25a; Run RM-2 and FTIR-2; Date - 4/6/2010; Start - 12:23; End - 16:36 0

3 Residual Oil (No. 6) Burned 57971 gal/hr Methods 6c, 7e, 10, and 25a; Run RM-3 and FTIR-3; Date - 4/6/2010; Start - 16:36; End - 19:42 0



### 4 Residual Oil (No. 6) Burned 57921 gal/hr Method 23; Run D/F-1; Date - 4/6/2010; Start - 09:15; End - 19:23 0

5 Residual Oil (No. 6) Burned 58155 gal/hr Method 23; Run D/F-2; Date - 4/7/2010; Start - 14:15; End - 23:21 0

6 Residual Oil (No. 6) Burned 57950 gal/hr Method 23; Run D/F-3; Date - 4/8/2010; Start - 11:48; End - 20:42 0

7 Residual Oil (No. 6) Burned 58097 gal/hr Method 29; Run M-1; Date - 4/7/2010; Start - 14:32; End - 19:18 0



### Tuesday, February 15, 2011 Page 18 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 8 Residual Oil (No. 6) Burned 57994 gal/hr Method 29; Run M-2; Date - 4/8/2010; Start - 08:32; End - 13:27 0

9 Residual Oil (No. 6) Burned 58009 gal/hr Method 29; Run M-3; Date - 4/8/2010; Start - 17:31; End - 22:18 0

1 Average Heat Input 7266 MMBtu/hr Methods 6c, 7e, 10, and 25a; Run RM-1 and FTIR-1; Date - 4/6/2010; Start - 10:23; End - 12:22 0



### 10Average Heat Input 7295 MMBtu/hr Method 027/028; Run PM-1; Date - 4/7/2010; Start - 08:43; End - 13:00 0

11Average Heat Input 7273 MMBtu/hr Method 027/028; Run PM-2; Date - 4/8/2010; Start - 14:12; End - 17:06 0

12Average Heat Input 7305 MMBtu/hr Method 027/028; Run PM-3; Date - 4/9/2010; Start - 09:49; End - 12:37 0

2 Average Heat Input 7269 MMBtu/hr Methods 6c, 7e, 10, and 25a; Run RM-2 and FTIR-2; Date - 4/6/2010; Start - 12:23; End - 16:36 0

3 Average Heat Input 7275 MMBtu/hr Methods 6c, 7e, 10, and 25a; Run RM-3 and FTIR-3; Date - 4/6/2010; Start - 16:36; End - 19:42 0



### 4 Average Heat Input 7269 MMBtu/hr Method 23; Run D/F-1; Date - 4/6/2010; Start - 09:15; End - 19:23 0

5 Average Heat Input 7298 MMBtu/hr Method 23; Run D/F-2; Date - 4/7/2010; Start - 14:15; End - 23:21 0

6 Average Heat Input 7274 MMBtu/hr Method 23; Run D/F-3; Date - 4/8/2010; Start - 11:48; End - 20:42 0



### Tuesday, February 15, 2011 Page 19 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 7 Average Heat Input 7292 MMBtu/hr Method 29; Run M-1; Date - 4/7/2010; Start - 14:32; End - 19:18 0

8 Average Heat Input 7278 MMBtu/hr Method 29; Run M-2; Date - 4/8/2010; Start - 08:32; End - 13:27 0

9 Average Heat Input 7281 MMBtu/hr Method 29; Run M-3; Date - 4/8/2010; Start - 17:31; End - 22:18 0

1 Steam Output 5220 1000 lb Methods 6c, 7e, 10, and 25a; Run RM-1 and FTIR-1; Date - 4/6/2010; Start - 10:23; End - 12:22 0



### 10Steam Output 5230 1000 lb Method 027/028; Run PM-1; Date - 4/7/2010; Start - 08:43; End - 13:00 0

11 Steam Output 5176 1000 lb Method 027/028; Run PM-2; Date - 4/8/2010; Start - 14:12; End - 17:06 0

12Steam Output 5172 1000 lb Method 027/028; Run PM-3; Date - 4/9/2010; Start - 09:49; End - 12:37 0

2 Steam Output 5220 1000 lb Methods 6c, 7e, 10, and 25a; Run RM-2 and FTIR-2; Date - 4/6/2010; Start - 12:23; End - 16:36 0

3 Steam Output 5222 1000 lb Methods 6c, 7e, 10, and 25a; Run RM-3 and FTIR-3; Date - 4/6/2010; Start - 16:36; End - 19:42 0

4 Steam Output 5220 1000 lb Method 23; Run D/F-1; Date - 4/6/2010; Start - 09:15; End - 19:23 0

5 Steam Output 5232 1000 lb Method 23; Run D/F-2; Date - 4/7/2010; Start - 14:15; End - 23:21 0



### Tuesday, February 15, 2011 Page 20 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 6 Steam Output 5174 1000 lb Method 23; Run D/F-3; Date - 4/8/2010; Start - 11:48; End - 20:42 0

7 Steam Output 5230 1000 lb Method 29; Run M-1; Date - 4/7/2010; Start - 14:32; End - 19:18 0

8 Steam Output 5194 1000 lb Method 29; Run M-2; Date - 4/8/2010; Start - 08:32; End - 13:27 0

9 Steam Output 5170 1000 lb Method 29; Run M-3; Date - 4/8/2010; Start - 17:31; End - 22:18 0

1 Unit Gross Electrical Output 804 MWg Methods 6c, 7e, 10, and 25a; Run RM-1 and FTIR-1; Date - 4/6/2010; Start - 10:23; End - 12:22 0



### 10Unit Gross Electrical Output 804 MWg Method 027/028; Run PM-1; Date - 4/7/2010; Start - 08:43; End - 13:00 0

11Unit Gross Electrical Output 801 MWg Method 027/028; Run PM-2; Date - 4/8/2010; Start - 14:12; End - 17:06 0

12Unit Gross Electrical Output 801 MWg Method 027/028; Run PM-3; Date - 4/9/2010; Start - 09:49; End - 12:37 0

2 Unit Gross Electrical Output 804 MWg Methods 6c, 7e, 10, and 25a; Run RM-2 and FTIR-2; Date - 4/6/2010; Start - 12:23; End - 16:36 0

3 Unit Gross Electrical Output 804 MWg Methods 6c, 7e, 10, and 25a; Run RM-3 and FTIR-3; Date - 4/6/2010; Start - 16:36; End - 19:42 0

4 Unit Gross Electrical Output 804 MWg Method 23; Run D/F-1; Date - 4/6/2010; Start - 09:15; End - 19:23 0



### Tuesday, February 15, 2011 Page 21 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 5 Unit Gross Electrical Output 804 MWg Method 23; Run D/F-2; Date - 4/7/2010; Start - 14:15; End - 23:21 0

6 Unit Gross Electrical Output 801 MWg Method 23; Run D/F-3; Date - 4/8/2010; Start - 11:48; End - 20:42 0

7 Unit Gross Electrical Output 804 MWg Method 29; Run M-1; Date - 4/7/2010; Start - 14:32; End - 19:18 0

8 Unit Gross Electrical Output 802 MWg Method 29; Run M-2; Date - 4/8/2010; Start - 08:32; End - 13:27 0

9 Unit Gross Electrical Output 801 MWg Method 29; Run M-3; Date - 4/8/2010; Start - 17:31; End - 22:18 0

1 Unit Net Electric Generation 772 MWn Methods 6c, 7e, 10, and 25a; Run RM-1 and FTIR-1; Date - 4/6/2010; Start - 10:23; End - 12:22 0



### 10Unit Net Electric Generation 773 MWn Method 027/028; Run PM-1; Date - 4/7/2010; Start - 08:43; End - 13:00 0

11Unit Net Electric Generation 769 MWn Method 027/028; Run PM-2; Date - 4/8/2010; Start - 14:12; End - 17:06 0

12Unit Net Electric Generation 769 MWn Method 027/028; Run PM-3; Date - 4/9/2010; Start - 09:49; End - 12:37 0

2 Unit Net Electric Generation 772 MWn Methods 6c, 7e, 10, and 25a; Run RM-2 and FTIR-2; Date - 4/6/2010; Start - 12:23; End - 16:36 0

3 Unit Net Electric Generation 772 MWn Methods 6c, 7e, 10, and 25a; Run RM-3 and FTIR-3; Date - 4/6/2010; Start - 16:36; End - 19:42 0



### Tuesday, February 15, 2011 Page 22 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010

APCD Run Data

Process Lab Run Data 4 Unit Net Electric Generation 772 MWn Method 23; Run D/F-1; Date - 4/6/2010; Start - 09:15; End - 19:23 0

5 Unit Net Electric Generation 772 MWn Method 23; Run D/F-2; Date - 4/7/2010; Start - 14:15; End - 23:21 0

6 Unit Net Electric Generation 769 MWn Method 23; Run D/F-3; Date - 4/8/2010; Start - 11:48; End - 20:42 0

7 Unit Net Electric Generation 773 MWn Method 29; Run M-1; Date - 4/7/2010; Start - 14:32; End - 19:18 0

8 Unit Net Electric Generation 770 MWn Method 29; Run M-2; Date - 4/8/2010; Start - 08:32; End - 13:27 0

9 Unit Net Electric Generation 769 MWn Method 29; Run M-3; Date - 4/8/2010; Start - 17:31; End - 22:18 0



### Run Name Value UOM Comments Target Value 1 LOW NOX BURNERS 179NOx Emissions 0


### 2 LOW NOX BURNERS 182NOx Emissions 0
3 LOW NOX BURNERS 183NOx Emissions 0
1 CYCLONE SEPARATORS 10.7 Opacity 0


### 2 CYCLONE SEPARATORS 12.4 Opacity 0
3 CYCLONE SEPARATORS 12.5 Opacity 0

Run Name Value UOM Comments 

### 2 Fuel Chlorine Content 88 mg/kg 2 Fuel Fluorine Content 40 mg/kg 2 Fuel Antimony Content 1.4 mg/kg 2 Fuel Arsenic Content 0.075 mg/kg 

### 2 Fuel Beryllium Content 0.01 mg/kg 2 Fuel Cadmium Content 0.007 mg/kg 2 Fuel Chromium Content 0.079 mg/kg 

### 2 Fuel Cobalt Content 1.1 mg/kg
Tuesday, February 15, 2011 Page 23 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 2 Fuel Lead Content 0.33 mg/kg 

### 2 Fuel Manganese Content 1.4 mg/kg 2 Fuel Nickel Content 12.8 mg/kg 2 Fuel Selenium Content 0.03 mg/kg 2 Fuel Sulfur Content 6350 mg/kg 

### 2 Fuel Proximate Analysis (Carbon) 88.2 % 2 Fuel Proximate Analysis (Hydrogen) 10.33 % 2 Fuel Proximate Analysis (Nitrogen) 0.5 % 

### 2 Fuel Proximate Analysis (Oxygen) 0.5 % 2 Fuel Proximate Analysis (Sulfur) 0.609 % 3 Fuel Higher Heating Value 18500 Btu/lb 3 Fuel Moisture 0.924 % 

### 3 Fuel Mercury Content 0.002 mg/kg 3 Fuel Chlorine Content 75 mg/kg 3 Fuel Fluorine Content 40 mg/kg 

### 3 Fuel Antimony Content 1.3 mg/kg 3 Fuel Arsenic Content 0.083 mg/kg 3 Fuel Beryllium Content 0.008 mg/kg 3 Fuel Cadmium Content 0.007 mg/kg 

### 3 Fuel Chromium Content 0.086 mg/kg 3 Fuel Cobalt Content 1 mg/kg 3 Fuel Lead Content 0.33 mg/kg 

### 3 Fuel Manganese Content 1.3 mg/kg 3 Fuel Nickel Content 12.5 mg/kg 3 Fuel Selenium Content 0.03 mg/kg 3 Fuel Sulfur Content 6150 mg/kg 

### 3 Fuel Proximate Analysis (Carbon) 87.75 % 3 Fuel Proximate Analysis (Hydrogen) 10.4 % 3 Fuel Proximate Analysis (Nitrogen) 0.5 % 

### 3 Fuel Proximate Analysis (Oxygen) 0.5 % 3 Fuel Proximate Analysis (Sulfur) 0.632 % 1 Fuel Higher Heating Value 18500 Btu/lb 1 Fuel Moisture 0.36 % 

### 1 Fuel Mercury Content 0.002 mg/kg 1 Fuel Chlorine Content 79 mg/kg 1 Fuel Fluorine Content 40 mg/kg 

### 1 Fuel Antimony Content 1.3 mg/kg 1 Fuel Arsenic Content 0.079 mg/kg 1 Fuel Beryllium Content 0.009 mg/kg 1 Fuel Cadmium Content 0.006 mg/kg 

### 1 Fuel Chromium Content 0.1 mg/kg 1 Fuel Cobalt Content 1 mg/kg 1 Fuel Lead Content 0.32 mg/kg



### Tuesday, February 15, 2011 Page 24 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 1 Fuel Manganese Content 1.4 mg/kg 

### 1 Fuel Nickel Content 13.4 mg/kg 1 Fuel Selenium Content 0.03 mg/kg 1 Fuel Sulfur Content 6530 mg/kg 1 Fuel Proximate Analysis (Carbon) 88.27 % 

### 1 Fuel Proximate Analysis (Hydrogen) 10.52 % 1 Fuel Proximate Analysis (Nitrogen) 0.5 % 1 Fuel Proximate Analysis (Oxygen) 0.5 % 

### 1 Fuel Proximate Analysis (Sulfur) 0.606 % 2 Fuel Higher Heating Value 18500 Btu/lb 2 Fuel Moisture 0.59 % 2 Fuel Mercury Content 0.001 mg/kg



### Tuesday, February 15, 2011 Page 25 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010 Sampling / Stack Data Results Detail


### Location PMR1 - D/F - Method 23 Average Run Number PMR1-23-1 PMR1-23-2 PMR1-23-3 Test Date 4/6/2010 4/7/2010 4/8/2010 Run Start Time 9:15:00 AM 2:15:00 PM11:48:00 AM Run Finish Time 5:15:00 PM10:15:00 PM 7:48:00 PM Net Traversing Points 24 24 24 Net Run Time, minutes 480 480 480 Nozzle Diameter, inches 0.25 0.25 0.25 0.250 Pitot Tube Coefficient 0.84 0.84 0.84 0.840 Dry Gas Meter Calibration Factor 0.987 0.987 0.987 0.987 Barometric Pressure, inches of Mercury 30.18 29.85 29.8 29.943 Average Orifice Meter Differential, inches H2O 1.96 1.63 1.66 1.750 Dry Gas Meter Volume Sampled, cubic feet 351.530 329.990 331.480 337.667 Average Dry Gas Meter Temperature, °F 82.73 83.79 83.69 83.403 Dry Gas Meter Volume Sampled, dscf 342.102 316.770 317.751 325.541 Total Moisture Liquid collected, g 715.9 763 697.9 725.600 Volume of Water Vapor, standard cubic feet 33.70 35.91 32.85 34.153 Moisture Content of Stack Gas, % 8.97 10.18 9.37 9.507 Moisture Saturation at Stack Gas Temperature, % 100.00 100.00 100.00 100.000 Dry Mole Fraction 0.9103 0.8982 0.9063 0.905 Carbon Dioxide, % 13.03 13.01 13.11 13.050 Oxygen, % 4.58 4.5 4.55 4.543 Carbon Monoxide & Nitrogen, % 82.39 82.49 82.34 82.407 Fuel Factor 1.25 1.26 1.25 Dry Molecular Weight, lb/lb-Mole 30.27 30.26 30.28 30.270 Wet Molecular weight, lb/lb-Mole 29.17 29.01 29.13 29.103 Flue Gas Static Pressure, inches of H2O 1 1 1 1.000 Absolute Flue Gas Pressure, inches of Mercury 30.25 29.92 29.87 30.013 Average Stack Gas Temperature, °F 338.50 342.96 348.75 343.403 Average Velocity Head, inches of H2O 0.7516221288 149470.642482887

4336080.656072276

636916 0.683
Average Stack Gas Velocity, feet/second 59.22 55.36 56.08 56.887 Stack Cross-Sectional Area, square feet 696.685 696.685 696.685 696.685 Dry Volumetric Flow Rate, dry scfm 1,506,480.3 1,366,774.5 1,384,716.81,419,323.8 67 Actual Wet Volumetric Flue Gas Flow Rate, acfm 2,475,461.1 2,314,108.9 2,344,205.72,377,925.2 33 Percent Isokinetic of Sampling Rate, % 96.7 98.7 97.7 97.700 Percent Excess Air, % 26.7 26.0 26.5 26.400 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Round Duct Diameter, inches 357.4 357.4 357.4 Rectangular Duct Width, inches 0 0 0 Rectangular Duct Length, inches 0 0 0 Fw 10320 10320 1032010,320.000 Fc 1420 1420 1420 1,420.000



### Tuesday, February 15, 2011 Page 26 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010
Location PMR1 - Gases - Method 10 Average Run Number 1-CO-1 1-CO-2 1-CO-3 Test Date 4/6/2010 4/6/2010 4/6/2010 Run Start Time 10:23:11 AM12:23:11 PM 4:36:41 PM Run Finish Time 12:22:41 PM4:36:11 PM 7:42:41 PM Carbon Dioxide, % 12.99 13.17 13.21 13.123 Oxygen, % 4.47 4.54 4.49 4.500 Fuel Factor 1.32 1.32 1.32 Dry Volumetric Flow Rate, dry scfm 1506474 1506474 15064741,506,474.0 00 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Moisture, % 8.98 8.98 8.98 8.980 Analyzer Make THERMO THERMO THERMO Analyzer Model 48i 48i 48i Analyzer Serial Number INST-CO0017 INST-CO0017 INST-CO0017 Operating Range 1109 1109 1109 1,109.000 Operating Units ppm ppm ppm No. Readings/Avg. 240 240 240 240.000 Calibration Set 5 5 5 5.000 Calibration Pre Zero Cylinder ID ALM031337ALM031337ALM031337 Calibration Pre Zero Cylinder Instrument Response 7.8 10.6 10.71 9.703 Calibration Pre Zero Cylinder Bias 0.66 0.91 0.92 0.830 Calibration Pre Zero Cylinder Drift Calibration Pre High Cylinder ID ALM042523- COALM042523

-COALM042523-

CO Calibration Pre High Cylinder Instrument Response 553 547.13 544.67 548.267 Calibration Pre High Cylinder Bias 0.09 -0.44 -0.66 -0.337 Calibration Pre High Cylinder Drift Calibration Post Zero Cylinder ID ALM031337ALM031337ALM031337 Calibration Post Zero Cylinder Instrument Response 10.6 10.71 10.87 10.727 Calibration Post Zero Cylinder Bias 0.91 0.92 0.93 0.920 Calibration Post Zero Cylinder Drift 0.25 0.01 0.01 0.090 Calibration Post High Cylinder ID ALM042523- COALM042523

-COALM042523-

CO Calibration Post High Cylinder Instrument Response 547.13 544.67 542.06 544.620 Calibration Post High Cylinder Bias -0.44 -0.66 -0.9 -0.667 Calibration Post High Cylinder Drift 0.53 0.22 0.24 0.330 Cavg 430.06 499.28 526.63 485.323 Cavg Units ppmvd ppmvd ppmvd Cgas 427.19 501.1819 531.7489 486.707 Cgas Units ppmvd ppmvd ppmvd Fuel Type Oil Oil Oil Fw 10320 10320 1032010,320.000 Fc 1420 1420 1420 1,420.000 Cgasw 0 0 0 0.000 Cgasw Units ppmvw ppmvw ppmvw



### Tuesday, February 15, 2011 Page 27 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010
Location PMR1 - Gases - Method 25A Average Run Number 1-THC-1 1-THC-2 1-THC-3 Test Date 4/6/2010 4/6/2010 4/6/2010 Run Start Time 10:23:11 AM12:23:11 PM 4:36:41 PM Run Finish Time 12:22:41 PM4:36:11 PM 7:42:41 PM Carbon Dioxide, % 12.99 13.17 13.21 13.123 Oxygen, % 4.47 4.54 4.49 4.500 Fuel Factor 1.32 1.32 1.32 Dry Volumetric Flow Rate, dry scfm 1506474 1506474 15064741,506,474.0 00 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Moisture, % 8.98 8.98 8.98 8.980 Analyzer Make VIG VIG VIG Analyzer Model 20 20 20 20.000 Analyzer Serial Number INST-TH0007 INST-TH0007 INST-TH0007 Operating Range 50 50 50 50.000 Operating Units ppm ppm ppm No. Readings/Avg. 240 240 240 240.000 Calibration Set 6 6 6 6.000 Calibration Pre Zero Cylinder ID ALM031337ALM031337ALM031337 Calibration Pre Zero Cylinder Instrument Response 0.15 0.31 0.32 0.260 Calibration Pre Zero Cylinder Bias 0.26 0.58 0.6 0.480 Calibration Pre Zero Cylinder Drift Calibration Pre High Cylinder ID CC115743 CC115743 CC115743 Calibration Pre High Cylinder Instrument Response 14.23 14.1 14.13 14.153 Calibration Pre High Cylinder Bias 0 -0.26 -0.2 -0.153 Calibration Pre High Cylinder Drift Calibration Post Zero Cylinder ID ALM031337ALM031337ALM031337 Calibration Post Zero Cylinder Instrument Response 0.31 0.32 0.36 0.330 Calibration Post Zero Cylinder Bias 0.58 0.6 0.68 0.620 Calibration Post Zero Cylinder Drift 0.32 0.028.000000000 00001E-02 0.140
Calibration Post High Cylinder ID CC115743 CC115743 CC115743 Calibration Post High Cylinder Instrument Response 14.1 14.13 14.1 14.110 Calibration Post High Cylinder Bias -0.26 -0.2 -0.26 -0.240 Calibration Post High Cylinder Drift 0.26 0.06 0.06 0.127 Cavg 0.19 1.19 0.95 0.777 Cavg Units ppmvw ppmvw ppmvw Cgas -0.0454 1.0031 0.7006 0.553 Cgas Units ppmvd ppmvd ppmvd Fuel Type Oil Oil Oil Fw 10320 10320 1032010,320.000 Fc 1420 1420 1420 1,420.000 Cgasw

- 4.1334768568 3531E-020.913043478

260870.637676950

998185 0.503

Cgasw Units ppmvw ppmvw ppmvw



### Tuesday, February 15, 2011 Page 28 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010
Location PMR1 - Gases - Method 3A CO2 Average Run Number 1-CO2-1 1-CO2-2 1-CO2-3 Test Date 4/6/2010 4/6/2010 4/6/2010 Run Start Time 10:23:11 AM12:23:11 PM 4:36:41 PM Run Finish Time 12:22:41 PM4:36:11 PM 7:42:41 PM Carbon Dioxide, % 12.99 13.17 13.21 13.123 Oxygen, % 4.47 4.54 4.49 4.500 Fuel Factor 1.32 1.32 1.32 Dry Volumetric Flow Rate, dry scfm 1506474 1506474 15064741,506,474.0 00 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Moisture, % 8.98 8.98 8.98 8.980 Analyzer Make THERMO THERMO THERMO Analyzer Model 410i 410i 410i Analyzer Serial Number INST-C2-0010 INST-C2- 0010 INST-C2-

0010 Operating Range 19.3 19.3 19.3 19.300 Operating Units % % % No. Readings/Avg. 240 240 240 240.000 Calibration Set 2 2 2 2.000 Calibration Pre Zero Cylinder ID ALM031337ALM031337ALM031337 Calibration Pre Zero Cylinder Instrument Response 0.12 -0.04 0.03 0.037 Calibration Pre Zero Cylinder Bias 0.52 -0.31 0.05 0.087 Calibration Pre Zero Cylinder Drift Calibration Pre High Cylinder ID AAL12025- CO2AAL12025-

CO2 AAL12025-

CO2 Calibration Pre High Cylinder Instrument Response 8.72 8.57 8.45 8.580 Calibration Pre High Cylinder Bias 0.31 -0.47 -1.09 -0.417 Calibration Pre High Cylinder Drift Calibration Post Zero Cylinder ID ALM031337ALM031337ALM031337 Calibration Post Zero Cylinder Instrument Response -0.04 0.03 0.11 0.033 Calibration Post Zero Cylinder Bias -0.31 0.05 0.47 0.070 Calibration Post Zero Cylinder Drift 0.83 0.36 0.42 0.537 Calibration Post High Cylinder ID AAL12025- CO2AAL12025-

CO2 AAL12025-

CO2 Calibration Post High Cylinder Instrument Response 8.57 8.45 8.7 8.573 Calibration Post High Cylinder Bias -0.47 -1.09 0.21 -0.450 Calibration Post High Cylinder Drift 0.78 0.62 1.3 0.900 Cavg 12.62 12.61 12.71 12.647 Cavg Units %vd %vd %vd Cgas 12.9967 13.1706 13.2122 13.127 Cgas Units %vd %vd %vd Fuel Type Oil Oil Oil Fw 10320 10320 1032010,320.000 Fc 1420 1420 1420 1,420.000 Cgasw 0 0 0 0.000 Cgasw Units %vw %vw %vw



### Tuesday, February 15, 2011 Page 29 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010
Location PMR1 - Gases - Method 3A O2 Average Run Number 1-O2-1 1-O2-2 1-O2-3 Test Date 4/6/2010 4/6/2010 4/6/2010 Run Start Time 10:23:11 AM12:23:11 PM 4:36:41 PM Run Finish Time 12:22:41 PM4:36:11 PM 7:42:41 PM Carbon Dioxide, % 12.99 13.17 13.21 13.123 Oxygen, % 4.47 4.54 4.49 4.500 Fuel Factor 1.32 1.32 1.32 Dry Volumetric Flow Rate, dry scfm 1506474 1506474 15064741,506,474.0 00 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Moisture, % 8.98 8.98 8.98 8.980 Analyzer Make THERMO THERMO THERMO Analyzer Model 42i-HL 42i-HL 42i-HL Analyzer Serial Number INST-N2-0002 INST-N2- 0002 INST-N2-

0002 Operating Range 21.1 21.1 21.1 21.100 Operating Units % % % No. Readings/Avg. 240 240 240 240.000 Calibration Set 1 1 1 1.000 Calibration Pre Zero Cylinder ID ALM031337ALM031337ALM031337 Calibration Pre Zero Cylinder Instrument Response 0.08 0.31 0.34 0.243 Calibration Pre Zero Cylinder Bias 0.28 1.37 1.52 1.057 Calibration Pre Zero Cylinder Drift Calibration Pre High Cylinder ID AAL12025-O2AAL12025- O2 AAL12025-

O2 Calibration Pre High Cylinder Instrument Response 12.1 12.23 12.32 12.217 Calibration Pre High Cylinder Bias -0.05 0.57 1 0.507 Calibration Pre High Cylinder Drift Calibration Post Zero Cylinder ID ALM031337ALM031337ALM031337 Calibration Post Zero Cylinder Instrument Response 0.31 0.34 0.39 0.347 Calibration Post Zero Cylinder Bias 1.37 1.52 1.75 1.547 Calibration Post Zero Cylinder Drift 1.09 0.15 0.23 0.490 Calibration Post High Cylinder ID AAL12025-O2AAL12025- O2 AAL12025-

O2 Calibration Post High Cylinder Instrument Response 12.23 12.32 12.04 12.197 Calibration Post High Cylinder Bias 0.57 1 -0.33 0.413 Calibration Post High Cylinder Drift 0.62 0.43 1.33 0.793 Cavg 4.61 4.81 4.75 4.723 Cavg Units %vd %vd %vd Cgas 4.4629 4.5413 4.4908 4.498 Cgas Units %vd %vd %vd Fuel Type Oil Oil Oil Fw 10320 10320 1032010,320.000 Fc 1420 1420 1420 1,420.000 Cgasw 0 0 0 0.000 Cgasw Units %vw %vw %vw



### Tuesday, February 15, 2011 Page 30 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010
Location PMR1 - Gases - Method 6C Average Run Number 1-SO2-1 1-SO2-2 1-SO2-3 Test Date 4/6/2010 4/6/2010 4/6/2010 Run Start Time 10:23:11 AM12:23:11 PM 4:36:41 PM Run Finish Time 12:22:41 PM4:36:11 PM 7:42:41 PM Carbon Dioxide, % 12.99 13.17 13.21 13.123 Oxygen, % 4.47 4.54 4.49 4.500 Fuel Factor 1.32 1.32 1.32 Dry Volumetric Flow Rate, dry scfm 1506474 1506474 15064741,506,474.0 00 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Moisture, % 8.98 8.98 8.98 8.980 Analyzer Make THERMO THERMO THERMO Analyzer Model 43i-HL 43i-HL 43i-HL Analyzer Serial Number INST-S2-0005 INST-S2- 0005 INST-S2-

0005 Operating Range 959 959 959 959.000 Operating Units ppm ppm ppm No. Readings/Avg. 240 240 240 240.000 Calibration Set 3 3 3 3.000 Calibration Pre Zero Cylinder ID ALM031337ALM031337ALM031337 Calibration Pre Zero Cylinder Instrument Response 1.93 1.58 0.92 1.477 Calibration Pre Zero Cylinder Bias -0.02 -0.06 -0.13 -0.070 Calibration Pre Zero Cylinder Drift Calibration Pre High Cylinder ID CC66246 CC66246 CC66246 Calibration Pre High Cylinder Instrument Response 438.1 420.17 426.52 428.263 Calibration Pre High Cylinder Bias -0.15 -2.02 -1.35 -1.173 Calibration Pre High Cylinder Drift Calibration Post Zero Cylinder ID ALM031337ALM031337ALM031337 Calibration Post Zero Cylinder Instrument Response 1.58 0.92 0.75 1.083 Calibration Post Zero Cylinder Bias -0.06 -0.13 -0.14 -0.110 Calibration Post Zero Cylinder Drift 0.04 0.07 0.01 0.040 Calibration Post High Cylinder ID CC66246 CC66246 CC66246 Calibration Post High Cylinder Instrument Response 420.17 426.52 425.75 424.147 Calibration Post High Cylinder Bias -2.02 -1.35 -1.43 -1.600 Calibration Post High Cylinder Drift 1.87 0.677.999999999 99998E-02 0.873
Cavg 347.86 344.97 345.24 346.023 Cavg Units ppmvd ppmvd ppmvd Cgas 346.6071 348.5286 346.5914 347.242 Cgas Units ppmvd ppmvd ppmvd Fuel Type Oil Oil Oil Fw 10320 10320 1032010,320.000 Fc 1420 1420 1420 1,420.000 Cgasw 0 0 0 0.000 Cgasw Units ppmvw ppmvw ppmvw



### Tuesday, February 15, 2011 Page 31 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010
Location PMR1 - Gases - Method 7E Average Run Number 1-NOx-1 1-NOx-2 1-NOx-3 Test Date 4/6/2010 4/6/2010 4/6/2010 Run Start Time 10:23:11 AM12:23:11 PM 4:36:41 PM Run Finish Time 12:22:41 PM4:36:11 PM 7:42:41 PM Carbon Dioxide, % 12.99 13.17 13.21 13.123 Oxygen, % 4.47 4.54 4.49 4.500 Fuel Factor 1.32 1.32 1.32 Dry Volumetric Flow Rate, dry scfm 1506474 1506474 15064741,506,474.0 00 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Moisture, % 8.98 8.98 8.98 8.980 Analyzer Make THERMO THERMO THERMO Analyzer Model 42i-HL 42i-HL 42i-HL Analyzer Serial Number INST-N2-0002 INST-N2- 0002 INST-N2-

0002 Operating Range 1110 1110 1110 1,110.000 Operating Units ppm ppm ppm No. Readings/Avg. 240 240 240 240.000 Calibration Set 4 4 4 4.000 Calibration Pre Zero Cylinder ID ALM031337ALM031337ALM031337 Calibration Pre Zero Cylinder Instrument Response 1.17 2.33 1.9 1.800 Calibration Pre Zero Cylinder Bias 0.02 0.13 0.09 0.080 Calibration Pre Zero Cylinder Drift Calibration Pre High Cylinder ID ALM042523- NOxALM042523

-NOxALM042523-

NOx Calibration Pre High Cylinder Instrument Response 550.55 540.82 533.11 541.493 Calibration Pre High Cylinder Bias -0.09 -0.96 -1.66 -0.903 Calibration Pre High Cylinder Drift Calibration Post Zero Cylinder ID ALM031337ALM031337ALM031337 Calibration Post Zero Cylinder Instrument Response 2.33 1.9 1.95 2.060 Calibration Post Zero Cylinder Bias 0.13 0.09 0.09 0.103 Calibration Post Zero Cylinder Drift 0.11 0.04 0 0.050 Calibration Post High Cylinder ID ALM042523- NOxALM042523

-NOxALM042523-

NOx Calibration Post High Cylinder Instrument Response 540.82 533.11 539.82 537.917 Calibration Post High Cylinder Bias -0.96 -1.66 -1.05 -1.223 Calibration Post High Cylinder Drift 0.87 0.7 0.61 0.727 Cavg 212.6 208.64 212.66 211.300 Cavg Units ppmvd ppmvd ppmvd Cgas 212.0381 211.2166 215.6472 212.967 Cgas Units ppmvd ppmvd ppmvd Fuel Type Oil Oil Oil Fw 10320 10320 1032010,320.000 Fc 1420 1420 1420 1,420.000 Cgasw 0 0 0 0.000 Cgasw Units ppmvw ppmvw ppmvw



### Tuesday, February 15, 2011 Page 32 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010
Location PMR1 - Metals - Method 29 Average Run Number PMR1-29-1 PMR1-29-2 PMR1-29-3 Test Date 4/7/2010 4/8/2010 4/8/2010 Run Start Time 2:32:00 PM8:32:00 AM 5:31:00 PM Run Finish Time 6:32:00 PM12:32:00 PM 9:31:00 PM Net Traversing Points 24 24 24 Net Run Time, minutes 240 240 240 Nozzle Diameter, inches 0.25 0.25 0.25 0.250 Pitot Tube Coefficient 0.84 0.84 0.84 0.840 Dry Gas Meter Calibration Factor 0.979 0.979 0.979 0.979 Barometric Pressure, inches of Mercury 29.85 29.74 29.71 29.767 Average Orifice Meter Differential, inches H2O 1.50 1.44 1.29 1.410 Dry Gas Meter Volume Sampled, cubic feet 163.920 163.420 157.840 161.727 Average Dry Gas Meter Temperature, °F 90.31 78.85 85.63 84.930 Dry Gas Meter Volume Sampled, dscf 154.179 156.378 148.957 153.171 Total Moisture Liquid collected, g 372.2 385.7 365.8 374.567 Volume of Water Vapor, standard cubic feet 17.52 18.15 17.22 17.630 Moisture Content of Stack Gas, % 10.20 10.40 10.36 10.320 Moisture Saturation at Stack Gas Temperature, % 100.00 100.00 100.00 100.000 Dry Mole Fraction 0.898 0.896 0.8964 0.897 Carbon Dioxide, % 13.01 13.11 13.11 13.077 Oxygen, % 4.5 4.55 4.55 4.533 Carbon Monoxide & Nitrogen, % 82.49 82.34 82.34 82.390 Fuel Factor 1.26 1.25 1.25 Dry Molecular Weight, lb/lb-Mole 30.26 30.28 30.28 30.273 Wet Molecular weight, lb/lb-Mole 29.01 29.00 29.01 29.007 Flue Gas Static Pressure, inches of H2O 1 1 1 1.000 Absolute Flue Gas Pressure, inches of Mercury 29.92 29.81 29.78 29.837 Average Stack Gas Temperature, °F 346.67 342.79 347.92 345.793 Average Velocity Head, inches of H2O 0.6301237495 639220.622965809

2407850.552692675

012846 0.602
Average Stack Gas Velocity, feet/second 54.95 54.62 51.63 53.733 Stack Cross-Sectional Area, square feet 696.685 696.685 696.685 696.685 Dry Volumetric Flow Rate, dry scfm 1,350,111.9 1,340,540.0 1,258,404.81,316,352.2 33 Actual Wet Volumetric Flue Gas Flow Rate, acfm 2,296,970.4 2,283,176.1 2,158,190.82,246,112.4 33 Percent Isokinetic of Sampling Rate, % 97.2 99.3 100.8 99.100 Percent Excess Air, % 26.0 26.5 26.5 26.333 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Round Duct Diameter, inches 357.4 357.4 357.4 Rectangular Duct Width, inches 0 0 0 Rectangular Duct Length, inches 0 0 0 Fw 10320 10320 1032010,320.000 Fc 1420 1420 1420 1,420.000



### Tuesday, February 15, 2011 Page 33 of 34

### Martin Energy Center, Unit #1, Information Collection Request
6/25/2010
Location PMR1 - PM - OTM - 27/28 Average Run Number PMR1-27/28-1 PMR1- 27/28-2PMR1-27/28-

3 Test Date 4/7/2010 4/8/2010 4/9/2010 Run Start Time 8:43:00 AM 2:12:00 PM 9:49:00 AM Run Finish Time 1:00:00 PM 5:06:00 PM12:37:00 PM Net Traversing Points 12 12 12 Net Run Time, minutes 123 124 125 Nozzle Diameter, inches 0.172 0.172 0.172 0.172 Pitot Tube Coefficient 0.8 0.8 0.8 0.800 Dry Gas Meter Calibration Factor 0.987 0.979 0.979 0.982 Barometric Pressure, inches of Mercury 30.18 29.77 29.71 29.887 Average Orifice Meter Differential, inches H2O 0.40 0.40 0.40 0.400 Dry Gas Meter Volume Sampled, cubic feet 40.720 45.230 43.450 43.133 Average Dry Gas Meter Temperature, °F 73.08 83.79 76.21 77.693 Dry Gas Meter Volume Sampled, dscf 40.193 42.821 41.633 41.549 Total Moisture Liquid collected, g 86.3 91.6 89.7 89.200 Volume of Water Vapor, standard cubic feet 4.06 4.31 4.22 4.197 Moisture Content of Stack Gas, % 9.17 9.14 9.20 9.170 Moisture Saturation at Stack Gas Temperature, % 100.00 100.00 100.00 100.000 Dry Mole Fraction 0.9083 0.9086 0.908 0.908 Carbon Dioxide, % 13.01 13.11 13.11 13.077 Oxygen, % 4.5 4.55 4.55 4.533 Carbon Monoxide & Nitrogen, % 82.49 82.34 82.34 82.390 Fuel Factor 1.26 1.25 1.25 Dry Molecular Weight, lb/lb-Mole 30.26 30.28 30.28 30.273 Wet Molecular weight, lb/lb-Mole 29.14 29.16 29.15 29.150 Flue Gas Static Pressure, inches of H2O 1 1 1 1.000 Absolute Flue Gas Pressure, inches of Mercury 30.25 29.84 29.78 29.957 Average Stack Gas Temperature, °F 338.25 350.67 346.17 345.030 Average Velocity Head, inches of H2O 0.7380687531 017950.701890213

8414340.721110942

307571 0.720
Average Stack Gas Velocity, feet/second 55.91 55.31 55.97 55.730 Stack Cross-Sectional Area, square feet 696.685 696.685 696.685 696.685 Dry Volumetric Flow Rate, dry scfm 1,419,597.7 1,364,555.3 1,384,838.91,389,663.9 67 Actual Wet Volumetric Flue Gas Flow Rate, acfm 2,337,099.5 2,312,018.8 2,339,607.62,329,575.3 00 Percent Isokinetic of Sampling Rate, % 99.4 109.3 103.8 104.167 Percent Excess Air, % 26.0 26.5 26.5 26.333 F-Factor, dscfm/MMBtu @ %O2 9190 9190 9190 9,190.000 Round Duct Diameter, inches 357.4 357.4 357.4 Rectangular Duct Width, inches 0 0 0 Rectangular Duct Length, inches 0 0 0 Fw 10320 10320 1032010,320.000 Fc 1420 1420 1420 1,420.000



### Tuesday, February 15, 2011 Page 34 of 34