__________________________________________________________________________________________

Page 1 of 10 

## Safety Data Sheet

Copyright,2015, { }

. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing {

} products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is

obtained from { } , and (2 ) neither the copy nor the original is resold or otherwise distributed with the

intention of earning a profit thereon.

I ssue Date: 02/18/15 Supercedes Date: Initial Issue



## Section 1:

1.1. Product identifier

{ }

Product Identification Numbers

{ }

1.2. Recommended use and restrictions on use

Recommended use : Experimental use only

1.3. Supplier’s details

{ }

1.4. Emergency telephone number

{ }



## Section 2 :

2.1. Hazard classification

Carcinogenicity: Category 2.

2.2. Label elements

Signal word

Warning

Symbols

Health Hazard |

Pictograms

Hazard Statements

Suspected of causing cancer.

Precautionary Statements

Prevention:

Obtain special instructions before use.__________________________________________________________________________________________

Page 2 of 10 Do not handle until all safety precautions have been read and understood.

Wear protective gloves.

Response:

IF exposed or concerned: Get medical advice/attention.

Storage:

Store locked up.

Disposal:

Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3. Hazards not otherwise classified

None.

25% of the mixture consists of ingredients of unknown acute oral toxicity.

25% of the mixture consists of ingredients of unknown acute dermal toxicity.

25% of the mixture consists of ingredients of unknown acute inhalation toxicity.



## Section 3 :

Ingredient C.A.S. No. % by Wt

Water 7732

- 18

- 5 70

- 80

Perfluorobutanesulphonamide and polyoxyalkylene

containing polyurethane Trade Secret* 20

- 30

Methyl isobutyl ketone 108

- 10

- 1 < 0.3

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade

secret.



## Section 4 :

4.1. Description of first aid measures

Inhalation:

Remove person to fresh air. If you are concerned, get medical advice.

Skin Contact:

Wash with soap and water. If you are concerned, get medical advice.

Eye Contact:

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get

medical attention.

If Swallowed:

Rinse mouth. If you are concerned, get medical advice.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment requi red

Not applicable.



## Section 5 :

5.1. Suitable extinguishing media

Material will not burn. Use a fire fighting agent suitable for the surrounding fire.__________________________________________________________________________________________

Page 3 of 10 5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By

- Products

Substance Condition

Carbon monoxide During Combustion

Carbon dioxide During Combustion

Hydrogen Fluoride During Combustion

Irritant Vapors or Gases During Combustion

Oxides of Nitrogen During Combustion

Toxic Vapor, Gas, Particulate During Combustion

5.3. Special protective actions for fire

- fighters

When fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full prote ctive

clothing, including helmet, self

- contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants,

bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.



## Section 6 :

6.1. Personal precautions, protective equipment and emergency procedures

Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical a nd

health hazards , respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions

Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or

bodies of water.

6.3. Meth ods and material for containment and cleaning up

Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially

available inorganic absorbent material. Mix in sufficient absorbent until it appears dry . Remember, adding an absorbent

material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.

Place in a closed container approved for transportation by appropriate authorities. Clean up res idue with an appropriate

solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions

on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.



## Section 7 :

7.1. Precautions for safe handling

Do not breathe thermal decomposition products. Do not handle until all safety precautions have been read and understood.

Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke

when using th is product. Wash thoroughly after handling. Avoid release to the environment. Use personal protective

equipment (gloves, respirators, etc.) as required.

7.2. Conditions for safe storage including any incompatibilities

No special storage requirements.



## Section 8 :

8.1. Control parameters

Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not availa ble

for the component.

Ingredient C.A.S. No. Agency Limit type Additional Comments__________________________________________________________________________________________

Page 4 of 10 Methyl isobutyl ketone 108

- 10

- 1 ACGIH TWA:20 ppm;STEL:75 ppm A3: Confirmed animal

carcin.

Methyl isobutyl ketone 108

- 10

- 1 OSHA TWA:410 mg/m3(100 ppm)

ACGIH : American Conference of Governmental Industrial Hygienists

AIHA : American Industrial Hygiene Association

CMRG : Chemical Manufacturer's Recommended Guidelines

OSHA : United States Department of Labor

- Occupational Safety and Health Administration

TWA: Time

- Weighted

- Average

STEL: Short Term Exposure Limit

CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls

Provide appropriate local exhaust when product is heated. Use general dilution ventilation and/or local exhaust ventilation to

control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation i s

not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

None require d.

Skin/hand protection

Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the

results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the

substance or mixture, freq uency and duration, physical challenges such as temperature extremes, and other use conditions.

Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective

clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.

Gloves made from the following material(s) are recommended: Polymer laminate

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part

of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respira tor

type(s) to reduce inhalation exposure:

During heating:

Use a positive pressure supplied

- ai r respirator if there is a potential for over exposure from an uncontrolled release,

exposure levels are not known, or under any other circumstances where air

- purifying respirators may not provide

adequate protection.

Half facepiece or full facepiece air

- purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.



## Section 9 :

9.1. Information on basic physical and chemical properties

General Physical Form: Liquid

Odor, Color, Grade: Pale yellow liquid with an odor of solvent

Odor threshold No Data Available

pH No Data Available

Melting point No Data Available

Boiling Point 212 oF

Flash Point No flash point

Evaporation rate No Data Available__________________________________________________________________________________________

Page 5 of 10 Flammability (solid, gas) Not Applicable

Flammable Limits(LEL) No Data Available

Flammable Limits(UEL) No Data Available

Vapor Pressure < 2 mmHg [@ 68 oF]

Vapor Density No Data Available

Density 1.06 g/ml

Specific Gravity 1.06 g/cm3

Solubility in Water Slight (less than 10%)

Solubility

- non

- water No Data Available

Partition coefficient: n

- octanol/ water No Data Available

Autoignition temperature No Data Available

Decomposition temperature No Data Available

Viscosity < 300 centipoise

Average particle size No Data Available

Bulk density No Data Available

Hazardous Air Pollutants No Data Available

Molecular weight No Data Available

Volatile Organic Compounds No Data Available

Percent volatile 75 %

Softening point No Data Available

VOC Less H2O & Exempt Solvents No Data Available



## Section 1 0 :

10.1. Reactivity

This material may be reactive with certain agents under certain conditions

- see the remaining headings in this section.

10.2. Chemical stability

Stable.

10.3. Possibility of hazardous reactions

Hazardous polymerization will not occur.

10.4. Co nditions to avoid

Sparks and/or flames

10.5. Incompatible materials

None known.

No Data Available

10.6. Hazardous decomposition products

Substance Condition

None known.

Ref er to section 5.2 for hazardous decomposition products during combustion.

Extreme heat arising from situations such as misuse or equipment failure can generate hydrogen fluoride as a decomposition

product.__________________________________________________________________________________________

Page 6 of 10 

## Section 1 1 :

The information below may not be consistent with the material classification in Section 2 if specific ingredient

classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be

reflected in the material cla ssification and/or the signs and symptoms of exposure, because an ingredient may be

present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be

relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:

May cause additional health effects (see below).

Skin Contact:

Contact with the skin during product use is not expected to result in significant irritation.

Eye Contact:

Contact with the eyes during product use is not expected to result in significant irritation.

Ingestion:

May cause additional health effects (see b elow).

Additional Health Effects:

Carcinogenicity:

Contains a chemical or chemicals which can cause cancer.

Ingredient CAS No. Class Description Regulation

Methyl isobutyl ketone 108

- 10

- 1 Grp. 2B: Possible human carc. International Agency for Research on Cancer

Additional Information:

The health hazards of this material are not completely known. Conservative safe handling measures should be followed (as

described in sections 7 and 8), and appropriate first aid measures (as described in section 4) should be taken if exposure

occurs.

Tox icological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or

the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Dermal No data available; calculated ATE > 5,000 mg/kg

Overall product Inhalation

Vapor(4 hr) No data available; calculated ATE > 50 mg/l

Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg

Methyl isobutyl ketone Dermal Rabbit LD50 > 16,000 mg/kg

Methyl isobutyl ketone Inhalation

Vapor (4

hours) Rat LC50 >8.2,<16.4 mg/l

Methyl isobutyl ketone Ingestion Rat LD50 3,038 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation__________________________________________________________________________________________

Page 7 of 10 Name Species Value

Methyl isobutyl ketone Rabbit Mild irritant

Serious Eye Damage/Irritation

Name Species Value

Methyl isobutyl ketone Rabbit Mild irritant

Skin Sensitization

Name Species Value

Methyl isobutyl ketone Guinea

pig Not sensitizing

Respiratory Sensitization

For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity

Name Route Value

Methyl isobutyl ketone In Vitro Not mutagenic

Carcinogenicity

Name Route Species Value

Methyl isobutyl ketone Inhalation Multiple

animal

species Carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test Result Exposure

Duration

Methyl isobutyl ketone Inhalation Not toxic to female reproduction Multiple

animal

species NOAEL 8.2

mg/l 2 generation

Methyl isobutyl ketone Ingestion Some positive male reproductive data

exist, but the data are not sufficient for

classification Rat NOAEL

1,000

mg/kg/day 13 weeks

M ethyl isobutyl ketone Inhalation Some positive male reproductive data

exist, but the data are not sufficient for

classification Multiple

animal

species NOAEL 8.2

mg/l 2 generation

Methyl isobutyl ketone Inhalation Some positive developmental data exist,

b ut the data are not sufficient for

classification Mouse NOAEL 12.3

mg/l during

organogenesi

s

Target Organ(s)

Specific Target Organ Toxicity

- single exposure

Name Route Target Organ(s) Value Species Test Result Exposure

Duration

Methyl isobutyl ketone Inhalation central nervous

system depression May cause drowsiness or

dizziness Human LOAEL 0.10

mg/l 2 hours

Methyl isobutyl ketone Inhalation respiratory irritation May cause respiratory irritation Human NOAEL 0.9

mg/l 7 minutes

Methyl isobutyl ketone Inhalation vascular system Some positive data exist, but the

data are not sufficient for

classification Dog NOAEL Not

available not available

Methyl isobutyl ketone Ingestion central nervous

system depression May cause drowsiness or

dizziness Rat LOAEL 900

mg/kg not applicable

Specific Target Organ Toxicity

- repeated exposure

Name Route Target Organ(s) Value Species Test Result Exposure__________________________________________________________________________________________

Page 8 of 10 Duration

Methyl isobutyl ketone Inhalation liver Some positive data exist, but the

data are not sufficient for

classification Rat NOAEL 0.41

mg/l 13 weeks

Methyl isobutyl ketone Inhalation heart Some positive data exist, but the

data are not sufficient for

classification Multiple

animal

species NOAEL 0. 8

mg/l 2 weeks

Methyl isobutyl ketone Inhalation kidney and/or

bladder Some positive data exist, but the

data are not sufficient for

classification Multiple

animal

species NOAEL 0.4

mg/l 90 days

Methyl isobutyl ketone Inhalation respiratory system All data are negative Multiple

animal

species NOAEL 4.1

mg/l 14 weeks

Methyl isobutyl ketone Inhalation endocrine system |

hematopoietic

system All data are negative Multiple

animal

species NOAEL 0.41

mg/l 90 days

Methyl isobutyl ketone Inhalation nervous system All data are negative Multiple

animal

species NOAEL 0.41

mg/l 13 weeks

Methyl isobutyl ketone Ingestion endocrine system |

hematopoietic

system | liver |

kidney and/or

bladder Some positive data exist, but the

data are not sufficient for

cl assification Rat NOAEL

1,000

mg/kg/day 13 weeks

Methyl isobutyl ketone Ingestion heart | immune

system | muscles |

nervous system |

respiratory system All data are negative Rat NOAEL

1,040

mg/kg/day 120 days

Aspiration Hazard

Name Value

Methyl isobutyl ketone Some positive data exist, but the data are not sufficient for

classification

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information

on this material and/or its comp onents.



## Section 1 2 :

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material

and/or its components.



### Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on th is material

and/or its components.



## Section 1 3 :

13.1. Disposal methods

Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Incinerate in a permitted waste incineration facility. Dispose of waste product in a permitted industrial waste facility.

Proper destruction may req uire the use of additional fuel during incineration processes. Combustion products will include

halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers

used for transporting and handling ha zardous chemicals (chemical substances/mixtures/preparations classified as Hazardous

as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise

defined by applicable waste regulations. Consult wi th the respective regulating authorities to determine the available

treatment and disposal facilities.__________________________________________________________________________________________

Page 9 of 10 EPA Hazardous Waste Number (RCRA): Not regulated



## Section 1 4 :

For Transport Information, please visit http:// { } .com/Transportinfo



## Section 1 5 :

15.1. US Federal Regulations

Contact { } for more information.

311/312 Hazard Categories:

Fire Hazard

- No Pressure Hazard

- No Reactivity Hazard

- No Immediate Hazard

- No Delayed Hazard

- Yes



### 15.2. State Regulations

Contact { } for more information.



### 15.3. Chemical Inventories

This material is not listed on the TSCA inventory and should be used for research and development purposes only under the

direct supervision of a technically qualified individual.

Contact { } for more information.



### 15.4. International Regulations

Cont act { } for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.



## Section 1 6 :

NFPA Hazard Classification

Health: 3 Flammability: 0 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address

the hazards that are presented by short

- term, acute exposure to a material under conditions of fire , spill, or similar

emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also includ e

the toxic properties of combustion or decomposition products that are known to be generated in significant qu antities.

HMIS Hazard Classification

Health: *3 Flammability: 0 Physical Hazard: 0 Personal Protection: X

- See PPE section.

Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical haz ards

in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use

and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III

prog ram. HMIS® is a registered mark of the Ameri can Coatings Association (ACA).

I ssue Date: 02/18/15 Supercedes Date: Initial Issue

DISCLAIMER: The information in this Safety Data Sheet (SD S) is believed to be correct as of the date issued. { Company } {

} MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED

WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF__________________________________________________________________________________________

Page 10 of 10 PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the { }

product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors t hat

can affect the use and application of a { } product, some of which are uniquely wi thin the user's

knowledge and control, it is essential that the user evaluate the { } product to determine whether it is

fit for a particular purpose and suitable for user's method of use or application.

{ } provides information in electronic form as a serv ice to its customers. Due to the remote

possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, {

} makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be

as current as the information in the SDS available directly from { }