# Patent

## Title
Case hardened steel and method for producing same

## Abstract

A case hardened steel with excellent cold forgeability and excellent impact properties after case hardening processing contains C, Si, Mn, S, Cr, Al, Ti, Nb, B, and N, with the balance being iron and unavoidable impurities. Of precipitates containing Ti and/or Nb, precipitates having a size of not less than 20 μm2 are at a number density of not more than 1.0/mm2. Of precipitates containing Ti and/or Nb, precipitates having a size of more than 5 μm2 and less than 20 μm2 and containing Mn and S are at a number density of more than 0.7/mm2 and not more than 3.0/mm2. The ferrite fraction is more than 77% by area.

## Background
TECHNICAL FIELD
The present invention relates to a case hardened steel to serve as a raw material for mechanical parts to be case hardened and used in transportation equipment such as automobiles, construction machines, other industrial machines, etc., and also to a method for producing the same. The present invention particularly relates to a case hardened steel that shows excellent impact properties and excellent cold forgeability when case hardened for gears (shafted gears, etc.), shafts, bearings, and CVT pulleys, and also to a method for producing the same.
BACKGROUND ART
With respect to mechanical parts used for automobiles, construction machines, and other various industrial machines, parts that are required to have particularly high strength are conventionally subjected to a surface-hardening heat treatment (case hardening treatment) such as carburizing, carbonitriding, or nitriding. For these applications, usually, case hardened steels specified by JIS, such as SCr, SCM, and SNCM, are used. The steel is formed into a desired part shape by machining such as cutting or forging and then subjected to a surface-hardening heat treatment as mentioned above, followed by a finishing process such as polishing, whereby a part is produced.
In recent years, in such mechanical parts, it has been desired to reduce the production cost, shorten the lead time, and reduce the CO2 emission during production, for example. Accordingly, part-forming methods are being changed from conventional cutting or hot forging to cold forging, and excellent cold forgeability is thus required. In addition, in a case hardened steel specified by JIS, the coarsening of crystal grains occurs due to the surface-hardening heat treatment after cold forging. Thus, it is also important to suppress the coarsening of crystal grains. In order to solve the problem of the coarsening of crystal grains, there is a conventionally used technique in which elements such as Al, Nb, and Ti are added to finely disperse precipitates such as AlN, Nb (CN), and TiC, and such fine precipitates are used to stop the migration of the crystal grain boundary (e.g., Patent Documents 1 to 8).
Japanese Patent Application Laid-Open Publication Nos. 2007-217761, 2006-307271, 2006-307270, 2007-321211, 2004-183064, 11-335777, 2006-161142, and 2007-162128 each disclose that the coarsening of crystal grains can be prevented by controlling the number of Nb- and/or Ti-containing precipitates having a predetermined grain size or composition (carbides, carbon nitrides, etc.) within a predetermined range. Although the disclosures have some preventive effects on the coarsening of crystal grains, cold forgeability has not yet been sufficient.
SUMMARY OF THE INVENTION
Problems to be Solved by the Invention
The present invention has been accomplished in view of the above background. An object of the present invention is to provide a case hardened steel that has excellent cold forgeability while ensuring conventional equivalent properties for preventing the coarsening of crystal grains and also has excellent impact properties after a case hardening treatment, which are usually required for the mechanical parts mentioned above; and also provide a useful method for producing the case hardened steel.
Means for Solving the Problems
The case hardened steel of the present invention that has achieved the object mentioned above contains C: 0.05 to 0.3% (% by mass; hereinafter the same applies to chemical composition), Si: 0.01 to 0.6%, Mn: 0.20 to 1.0%, S: 0.001 to 0.025%, Cr: 1 to 2.5%, Al: 0.01 to 0.10%, Ti: 0.01 to 0.10%, Nb: 0.01 to 0.10%, B: 0.0005 to 0.005%, and N: 0.002 to 0.02%, with the balance being iron and unavoidable impurities, wherein, of precipitates containing Ti and/or Nb, precipitates having a size of not less than 20 μm2 are at a number density of not more than 1.0/mm2, wherein, of precipitates containing Ti and/or Nb, precipitates having a size of more than 5 μm2 and less than 20 μm2 and containing Mn and S are at a number density of more than 0.7/mm2 and not more than 3.0/mm2, and wherein the ferrite fraction is more than 77% by area.
It is also preferable that, as necessary, the case hardened steel of the present invention contains (a) Mo: not more than 2% (excluding 0%) or (b) Cu: not more than 0.1% (excluding 0%) and/or Ni: not more than 0.3% (excluding 0%). Depending on the kinds of elements contained, the properties of the case hardened steel are further improved.
The present invention also includes a method for producing the case hardened steel. The production method of the present invention is characterized in that a steel having the above chemical composition is subjected to casting at a cooling rate of not less than 2.5° C./min from 1500° C. to 800° C., blooming at a heating temperature of 1100 to 1200° C., first hot rolling at a rolling temperature of 970 to 1150° C., then cooling to Ac3 to 950° C., and further second hot rolling at a rolling temperature of Ac3 to 950° C.
Effect of the Invention
According to the present invention, the chemical composition of the steel is adjusted to a predetermined range, and also the form (size) and the number of composite precipitates, which are precipitates containing Ti and/or Nb and also containing Mn and S, are adjusted to predetermined ranges. As a result, it is possible to achieve excellent cold forgeability while ensuring conventional equivalent properties for preventing the coarsening of crystal grains, and also to achieve excellent impact properties after a surface-hardening heat treatment. Therefore, the case hardened steel of the present invention is useful as a raw material for various kinds of mechanical parts. In addition, use of the case hardened steel of the present invention allows the formation of a part by cutting to be replaced with cold forging, making it possible to achieve lead time shortening and cost reduction in the formation of a part.



BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a schematic diagram showing the form of a test piece for cold forgeability measurement in the Examples below;
FIG. 2 is a graph showing the heat treatment conditions for spheroidization in the Examples below;
FIG. 3 is a schematic diagram showing the form of a Charpy impact test piece used for the measurement of impact properties in the Examples below; and
FIG. 4 is a graph showing the carburizing treatment conditions in the Examples below.



MODE FOR CARRYING OUT THE INVENTION
In order to improve the cold forgeability of a case hardened steel and ensure impact properties after a surface-hardening heat treatment, the present inventors have conducted research focusing particularly on the chemical components of a steel and the existence form of precipitates (the size, the number, etc.). As a result, they have found that when the contents of the components C, Si, Mn, S, Cr, Al, Ti, Nb, B, and N are each appropriately controlled, and also the form (size) and the number density of composite precipitates, which are precipitates containing Ti and/or Nb and also containing Mn and S, (hereinafter referred to as “(Ti, Nb)-based composite precipitate”) are adjusted to predetermined ranges, improved cold forgeability can be achieved while ensuring conventional equivalent properties for preventing the coarsening of crystal grains, and further impact properties after a surface-hardening heat treatment can also be ensured. The present invention has thus been accomplished.
Hereinafter, the chemical components of the case hardened steel of the present invention will be described.
C: 0.05 to 0.3%
C is an element that is important in ensuring the core hardness necessary as a part. When the content is less than 0.05%, hardness is insufficient, leading to insufficient static strength as a part. Meanwhile, when the C content is too high, hardness is excessively increased, leading to a decrease in forgeability and machinability. Thus, the C content has been specified to be not less than 0.05% and not more than 0.3%. The C content is preferably not less than 0.10%, and more preferably not less than 0.15%. In addition, the C content is preferably not more than 0.27%, and more preferably not more than 0.25%.
Si: 0.01 to 0.6%
Si is an element that improves the softening resistance of the steel material and is effective in suppressing a decrease of the surface hardness of a part after case hardening. Therefore, it is necessary that the Si content is not less than 0.01%. The content is more preferably not less than 0.03%, and still more preferably not less than 0.05%. However, the excessive addition of Si increases the deformation resistance of the raw material, leading to a decrease in forgeability and machinability. Therefore, the Si content is specified to be not more than 0.6%. The content is more preferably not more than 0.55%, and still more preferably not more than 0.5%.
Mn: 0.20 to 1.0%
Mn functions as a deoxidizing agent. It is effective in reducing oxide-type inclusions to increase the internal quality of the steel material and is also effective in significantly enhancing hardenability during case hardening such as carburizing quenching. In addition, Mn forms MnS and causes composite precipitation with carbides, nitrides, or carbon nitrides (hereinafter referred to as “carbides and the like”) containing Nb and/or Ti. As a result, the deterioration of cold forgeability due to coarse carbides and the like containing Nb and/or Ti can be suppressed. Further, a low Mn content causes hot shortness, leading to a decrease in productivity. Thus, the Mn content has been specified to be not less than 0.20%. The Mn content is preferably not less than 0.30%, and more preferably not less than 0.35%. Meanwhile, when the Mn content is too high, this has adverse effects including an increase in deformation resistance during cold forging, significant banded segregation which increases the variation of the material quality, etc. Thus, the Mn content has been specified to be not more than 1.0%. The Mn content is preferably not more than 0.85%, and more preferably not more than 0.80%.
S: 0.001 to 0.025%
S is an element that binds to Mn, Ti, or the like to form MnS, TiS, or the like and is necessary to form composite precipitates containing Mn and Ti. Meanwhile, when the S content is too high, impact properties are adversely affected. Thus, the S content has been specified to be 0.001 to 0.025%. The S content is preferably not less than 0.005%, and more preferably not less than 0.010%. In addition, the S content is preferably not more than 0.022%, and more preferably not more than 0.020%.
Cr: 1 to 2.5%
Cr is an element necessary to obtain an effective case during case hardening such as carburizing. Meanwhile, when the Cr content is too high, over-carburizing is caused, whereby the sliding characteristics of a part after case hardening are adversely affected. Thus, the Cr content has been specified to be 1 to 2.5%. The Cr content is preferably not less than 1.2%, and more preferably not less than 1.3%. In addition, the Cr content is preferably not more than 2.2%, and more preferably not more than 2.0% (still more preferably not more than 1.9%).
Al: 0.01 to 0.10%
Al is an element that binds to N to form AlN and is effective in suppressing the growth of crystal grains in the steel material during a heat treatment. In addition, when Al is added in combination with the below-mentioned Ti or Nb, AlN undergoes composite precipitation with precipitates containing Ti or Nb, and this produces more stable preventive effects on the coarsening of crystal grains than in the case of separate precipitation. Meanwhile, when the Al content is too high, the amount of Al solid solution increases, leading to an increase in deformation resistance during cold forging. Thus, the Al content has been specified to be 0.01 to 0.10%. The Al content is preferably not less than 0.02%, and more preferably not less than 0.03%. In addition, the Al content is preferably not more than 0.09%, and more preferably not more than 0.08%.
Ti: 0.01 to 0.10%
Ti produces fine Ti carbides and the like (Ti (C, N)) in the steel and is effective in suppressing the coarsening of crystal grains during case hardening. Meanwhile, when the Ti content is too high, this leads to an increase in the production cost of the steel material or a decrease in cold forgeability and impact properties (impact strength represented by Charpy absorbed energy, etc.) due to the production of coarse Ti-based inclusions. Thus, the Ti content has been specified to be 0.01 to 0.10%. The Ti content is preferably not less than 0.02%, and more preferably not less than 0.03%. In addition, the Ti content is preferably not more than 0.09%, and more preferably not more than 0.08%.
Nb: 0.01 to 0.10%
Nb produces fine Nb carbides and the like (Nb (C, N)) in the steel and is effective in suppressing the coarsening of crystal grains during case hardening. Meanwhile, when the Nb content is too high, this leads to an increase in the production cost of the steel material or a decrease in cold forgeability and impact properties (impact strength, etc.) due to the production of coarse Nb-based inclusions. Thus, the Nb content has been specified to be 0.01 to 0.10%. The Nb content is preferably not less than 0.02%, and more preferably not less than 0.03%. In addition, the Nb content is preferably not more than 0.09%, and more preferably not more than 0.08%.
B: 0.0005 to 0.005%
B is effective in significantly improving the hardenability of the steel material even in a small amount. In addition, B is also effective in strengthening the crystal grain boundary and increasing impact strength. Meanwhile, when the B content is too high, the above effectiveness is saturated, and also B nitrides are likely to be formed, causing the deterioration of cold and hot workability. Thus, the B content has been specified to be 0.0005 to 0.005%. The B content is preferably not less than 0.0007%, and more preferably not less than 0.0010%. In addition, the B content is preferably not more than 0.004%, and more preferably not more than 0.0035%.
N: 0.002 to 0.02%
N is an element necessary to produce nitrides or carbon nitrides with Ti or Nb. However, when the N content is too high, this is likely to cause the coarsening of Ti-based nitrides, resulting in a decrease in impact strength and a decrease in cold forgeability due to increased deformation resistance. Thus, the N content has been specified to be 0.002 to 0.02%. The N content is preferably not less than 0.003%, and more preferably not less than 0.005%. In addition, the N content is preferably not more than 0.018%, and more preferably not more than 0.015%.
The basic components of the case hardened steel of the present invention are as mentioned above, and the balance is substantially iron. However, the presence of unavoidable impurities in the steel, which are introduced depending on the conditions including raw materials, materials, production facilities, etc., is naturally acceptable. Further, in the present invention, without interfering with the operation effects of the present invention, the following optional elements may also be contained. Depending on the kinds of elements contained, the properties of the case hardened steel can be further improved.
Mo: not more than 2% (excluding 0%)
Mo is effective in significantly improving hardenability during case hardening such as carburizing quenching and is also effective in improving impact strength. Thus, the Mo content is preferably not less than 0.01%, and more preferably not less than 0.05%. Meanwhile, when the Mo content is too high, the hardness of the steel material increases, leading to poor machinability. Thus, the Mo content is not more than 2%, more preferably not more than 1.5%, and still more preferably not more than 1.0% (particularly not more than 0.8%).
Cu: not more than 0.1% (excluding 0%) and/or Ni: not more than 0.3% (excluding 0%)
Cu and Ni are each an element that is more resistant to oxidation than Fe and thus improves the corrosion resistance of the steel material. Ni is also effective in improving the impact resistance of the steel material. Thus, the Cu content and the Ni content are each preferably not less than 0.01%, and more preferably not less than 0.05%. Meanwhile, when the Cu content is too high, the hot ductility of the steel material decreases, and when the Ni content is too high, the steel material cost increases. Thus, the Cu content is preferably not more than 0.1%, more preferably not more than 0.08%, and still more preferably not more than 0.05%. The Ni content is preferably not more than 0.3%, more preferably not more than 0.2%, and still more preferably not more than 0.1%. Cu and Ni may be used alone or in combination. However, in the case where Cu is added, it is preferable to also add Ni.
An object of the present invention is to obtain improved cold forgeability together with conventional equivalent properties for preventing the coarsening of crystal grains, and further obtain excellent impact properties after a surface-hardening heat treatment. According to the research of the present inventors, in order to obtain excellent impact properties, it is likely to be necessary to suppress the coarsening of crystal grains. For the suppression of the coarsening of crystal grains, it is necessary to finely disperse Ti and Nb carbides and the like. However, not all Ti and Nb carbides and the like are finely dispersed, and coarse carbides and the like also precipitate. Such coarse carbides and the like are harder than the matrix and adversely affect cold forgeability, and thus are undesirable. Thus, as a result of the research of the present inventors, it has been found that even in the case where carbides and the like are coarse, when they are composite precipitates of MnS with Ti carbides and the like and/or Nb carbides and the like ((Ti, Nb)-based composite precipitates), the deterioration of cold forgeability can be suppressed by MnS that is softer than the matrix.
Specifically, of precipitates containing Ti and/or Nb, the number density of precipitates having a size of more than 5 μm2 and less than 20 μm2 and containing Mn and S is specified to be more than 0.7/mm2 and not more than 3.0/mm2. The present invention targets at (Ti, Nb)-based composite precipitates having a size of more than 5 μm2 and less than 20 μm2. This is because properties for preventing the coarsening of crystal grains and cold forgeability are both greatly affected by Ti and/or Nb carbides and the like contained in composite precipitates of this size. That is, precipitates having a size of not more than 5 μm2 do not have much effect on cold forgeability. Meanwhile, originally, the adverse effects of precipitates having a size of not less than 20 μm2 on cold forgeability are extremely high. Therefore, by improving cold forgeability with precipitates having a size of more than 5 μm2 and less than 20 μm2, cold forgeability can be improved while maintaining the preventive effects on the coarsening of crystal grains. Although precipitates containing Ti and/or Nb themselves are hard, when (Ti, Nb)-based composite precipitates are formed by composite precipitation with soft MnS, the deformability as one precipitate can be improved. At the same time, owing to the effects of Ti and/or Nb carbides and the like, properties for preventing the coarsening of crystal grains during case hardening can be ensured. In order to sufficiently exhibit the improving effects on cold forgeability and properties for preventing the coarsening of crystal grains, of precipitates containing Ti and/or Nb, the number density of precipitates having a size of more than 5 μm2 and less than 20 μm2 and containing Mn and S is specified to be more than 0.7/mm2. The number density is preferably not less than 1.0/mm2, more preferably not less than 1.1/mm2, and still more preferably not less than 1.2/mm2. Meanwhile, even when precipitates are like this, excessive precipitation leads to insufficient strength after case hardening. Thus, the number density is specified to be not more than 3.0/mm2. The number density is preferably not more than 2.5/mm2, and more preferably not more than 2.0/mm2. In addition, of precipitates containing Ti and/or Nb, the number density of precipitates having a size of more than 5 μm2 and less than 20 μm2 and not containing Mn or S is about 1.0 to 10.0/mm2.
In addition, of precipitates containing Ti and/or Nb, precipitates having a size of not less than 20 μm2 (the upper limit of the size of precipitates is usually about 30 μm2) greatly adversely affect cold forgeability. Therefore, it is necessary to minimize the number of such precipitates. Therefore, of precipitates containing Ti and/or Nb, the number density of precipitates having a size of not less than 20 μm2 is specified to be not more than 1.0/mm2. Of precipitates containing Ti and/or Nb, the number density of precipitates having a size of not less than 20 μm2 is preferably not more than 0.9/mm2, and more preferably not more than 0.8/mm2. Incidentally, as long as the component system of the present invention and the below-mentioned production method are used, of precipitates containing Ti and/or Nb, precipitates having a size of not less than 20 μm2 usually do not contain Mn or S. However, the presence of Mn and S has no adverse effect and is also within the range of the present invention. The number of precipitates having a size of not less than 20 μm2 can be controlled by adjusting the amount of Ti and/or Nb added to the steel or by adjusting the heating temperature and heating time before blooming, the working temperature during hot rolling, and the like in the below-mentioned production method.
Incidentally, in the prior art, the number density of precipitates containing Ti and/or Nb and having a size of not more than 5 μm2 (and not less than 2 μm2 as described in the Examples below) is as follows: (i) composite precipitates containing Mn and S: about 0.0 to 0.5/mm2 and (ii) precipitates not containing Mn or S: about 0.1 to 1.5/mm2.
The case hardened steel of the present invention has a ferrite fraction of more than 77% by area. This is because when the ferrite fraction is low, cold forgeability is impaired. The ferrite fraction is preferably not less than 80% by area, more preferably not less than 82% by area, and still more preferably not less than 83% by area. In addition, the remaining structure other than the ferrite structure includes pearlite, bainite, martensite, etc., for example.
In the production of the case hardened steel of the present invention, in the series of steps including ingoting, casting, soaking, blooming, and hot rolling, it is particularly important that the cooling rate during casting is so high that the soaking temperature before blooming does not become too high. It is also important that hot rolling is performed in two states, and the temperature range in each stage is appropriately controlled. The detailed conditions of each step are as follows.
In casting, it is important to finely disperse MnS crystallized during cooling. Specifically, the cooling rate from 1500° C. to 800° C. during casting should be not less than 2.5° C./min. A cooling rate of not less than 2.5° C./min may be achieved, for example, by increasing the amount of mist, which is sprayed in the cooling zone during continuous casting, than usual. The cooling rate is preferably not less than 2.8° C./min, and more preferably not less than 3.0° C./min.
In heating before blooming (soaking), it is important to prevent the dissolution of MnS that has been finely dispersed at the time of cooling during casting, and the heating (soaking) temperature should be 1100 to 1200° C. The heating temperature is preferably not more than 1180° C., and more preferably not more than 1170° C. In addition, after blooming, cooling to room temperature is performed preferably at a rate of not more than 5° C./sec, and more preferably at a rate of not more than 3° C./sec. The heating time is not particularly limited, and is about 0 to 100 minutes at the soaking temperature, for example.
In hot rolling, it is important to perform rolling in two stages at different temperature ranges. In the first stage, MnS finely dispersed during casting is allowed to undergo composite precipitation with Ti and/or Nb carbides and the like. In the second stage, the ferrite fraction is ensured. Specifically, first hot rolling is performed at a working temperature of 970 to 1150° C., followed by cooling to Ac3 to 950° C., and then second hot rolling is performed at a working temperature of Ac3 to 950° C. The first working temperature is preferably 1000 to 1130° C., and more preferably 1020 to 1100° C. In addition, the second working temperature is preferably 800 to 930° C. The cooling rate from the first working temperature to the second working temperature is not particularly limited, and is about 10° C./sec, for example. It is preferable that the cooling rate after second rolling is not more than 5° C./sec so that no bainite or martensite is produced.
Examples
Hereinafter, the present invention will be described in further detail through examples. The present invention is not limited to the following examples, and, needless to say, any modification in the range of the purpose described above or below is within the technical scope of the present invention.
The steels having the chemical components shown in Tables 1 to 3 were ingoted in accordance with an ordinary ingoting method, cast, soaked, and hot forged (the blooming mentioned above was simulated), followed by cooling to room temperature (cooling rate: 5° C./sec). Subsequently, after reheating, first forging was performed (the first hot rolling mentioned above was simulated), followed by cooling to the second forging temperature (the second hot rolling mentioned above was simulated), and then second forging was performed, followed by cooling to room temperature (cooling rate: 5° C./sec), thereby giving a steel bar of 30 mm in diameter. The cooling rate (° C./min) during casting, the soaking temperature (° C.), the soaking time (min), and the first and second forging temperatures (° C.) are shown in Tables 1 to 3.








TABLE 1








Production Conditions










Blooming
Hot Rolling















Casting
Soaking

First
Second




Cooling
Tem-
Soak-
Forging
Forging



Chemical Components (% by mass)
Rate
per-
ing
Temper-
Temper-



* The balance: iron and unavoidable impurities
(° C./
ature
Time
ature
ature

























No.
C
Si
Mn
S
Cr
Al
Ti
Nb
B
N
Mo
Cu
Ni
min)
(° C.)
(min)
(° C.)
(° C.)




























1
0.19
0.07
0.73
0.011
1.94
0.031
0.040
0.040
0.0012
0.0050
0.08


2.5
1100
60
1000
950


2
0.18
0.05
0.46
0.010
1.42
0.030
0.038
0.075
0.0014
0.0036



3.0
1100
60
1000
950


3
0.21
0.36
0.44
0.008
1.40
0.029
0.056
0.076
0.0018
0.0062
0.11


2.5
1100
60
1050
900


4
0.21
0.40
0.40
0.007
1.61
0.030
0.056
0.079
0.0170
0.0073
0.10


2.5
1100
60
1050
900


5
0.19
0.05
0.52
0.010
1.66
0.082
0.083
0.072
0.0012
0.0088



3.5
1100
60
1000
950


6
0.18
0.08
0.60
0.012
1.89
0.029
0.046
0.049
0.0011
0.0045



2.5
1100
60
1000
950


7
0.19
0.08
0.47
0.009
1.39
0.065
0.034
0.064
0.0008
0.0033



2.5
1100
60
1000
925


8
0.17
0.09
0.57
0.017
1.65
0.089
0.039
0.079
0.0024
0.0151



3.0
1100
60
1050
925


9
0.18
0.07
0.69
0.013
1.45
0.079
0.033
0.032
0.0019
0.0081



2.5
1100
60
1050
950


10
0.19
0.01
0.58
0.017
1.60
0.049
0.034
0.081
0.0009
0.0108



3.0
1100
60
1000
900


11
0.18
0.09
0.66
0.018
1.56
0.065
0.083
0.048
0.0008
0.0119



3.0
1100
60
1000
950


12
0.18
0.09
0.71
0.019
1.78
0.056
0.083
0.052
0.0006
0.0146



3.0
1100
60
1000
950


13
0.19
0.09
0.71
0.018
1.62
0.059
0.075
0.074
0.0028
0.0148



3.0
1100
60
1050
950


14
0.18
0.02
0.56
0.014
1.76
0.051
0.057
0.073
0.0008
0.0089



2.5
1100
60
1050
950


15
0.18
0.07
0.67
0.020
1.65
0.089
0.082
0.029
0.0027
0.0141



2.5
1100
60
1050
950


16
0.17
0.40
0.47
0.020
1.84
0.038
0.049
0.051
0.0025
0.0133



2.5
1100
60
1050
900


17
0.18
0.44
0.45
0.019
1.65
0.039
0.055
0.038
0.0017
0.0048



2.5
1100
60
1000
950


18
0.18
0.04
0.67
0.017
1.55
0.033
0.084
0.078
0.0038
0.0089



3.5
1100
45
1000
925


19
0.18
0.10
0.64
0.015
1.70
0.070
0.063
0.088
0.0016
0.0172



3.0
1100
45
1000
925


20
0.19
0.09
0.63
0.009
1.85
0.082
0.033
0.078
0.0022
0.0079



2.5
1100
45
1000
950


21
0.17
0.07
0.67
0.016
1.49
0.043
0.079
0.082
0.0027
0.0170



2.5
1100
45
1050
950


22
0.19
0.02
0.48
0.018
1.36
0.086
0.087
0.082
0.0014
0.0094
0.12


3.0
1100
60
1050
900


23
0.19
0.37
0.70
0.011
1.79
0.077
0.064
0.071
0.0007
0.0107



2.5
1100
60
1050
950


24
0.18
0.06
0.61
0.016
1.61
0.063
0.063
0.031
0.0023
0.0088



2.5
1100
60
1050
950


25
0.18
0.02
0.61
0.011
1.42
0.040
0.040
0.029
0.0022
0.0039



2.5
1100
60
1000
950


26
0.20
0.10
0.65
0.020
1.85
0.029
0.072
0.052
0.0011
0.0038



3.5
1100
60
1050
950

















TABLE 2








Production Conditions









Hot Rolling











Blooming
First
Second















Casting
Soaking

Forging
Forging




Cooling
Tem-
Soak-
Tem-
Tem-



Chemical Components (% by mass)
Rate
per-
ing
per-
per-



* The balance: iron and unavoidable impurities
(° C./
ature
Time
ature
ature

























No.
C
Si
Mn
S
Cr
Al
Ti
Nb
B
N
Mo
Cu
Ni
min)
(° C.)
(min)
(° C.)
(° C.)





27
0.18
0.05
0.74
0.019
1.84
0.033
0.039
0.051
0.0032
0.0128



3.0
1100
60
1050
950


28
0.19
0.40
0.79
0.009
1.60
0.043
0.071
0.035
0.0005
0.0155



2.5
1100
60
1000
950


29
0.18
0.05
0.68
0.017
1.37
0.033
0.045
0.049
0.0020
0.0146



3.0
1100
45
1000
950


30
0.19
0.07
0.71
0.012
1.33
0.049
0.070
0.062
0.0022
0.0089



2.5
1100
45
1050
950


31
0.20
0.08
0.66
0.011
1.44
0.039
0.077
0.037
0.0009
0.0058



2.5
1100
45
1050
950


32
0.18
0.08
0.80
0.012
1.33
0.087
0.036
0.073
0.0023
0.0144



3.0
1100
45
1000
950


33
0.18
0.35
0.77
0.015
1.56
0.087
0.033
0.088
0.0012
0.0173


0.20
3.0
1100
60
1000
950


34
0.18
0.03
0.73
0.014
1.44
0.058
0.059
0.078
0.0039
0.0117



3.5
1100
60
1000
950


35
0.19
0.09
0.46
0.012
1.68
0.087
0.032
0.033
0.0009
0.0085



2.5
1100
60
1000
950


36
0.18
0.06
0.48
0.016
1.89
0.063
0.049
0.039
0.0014
0.0105

0.05

2.5
1175
60
1125
950


37
0.18
0.02
0.62
0.008
1.75
0.076
0.049
0.062
0.0009
0.0060



3.5
1100
60
1125
950


38
0.21
0.09
0.82
0.008
1.28
0.060
0.066
0.041
0.0018
0.0057



3.5
1100
60
1000
950


39
0.21
0.07
0.72
0.015
1.49
0.073
0.068
0.028
0.0012
0.0080



3.0
1100
60
1000
950


40
0.17
0.08
0.64
0.012
1.55
0.049
0.060
0.048
0.0026
0.0100
0.23


3.0
1100
60
1000
950


41
0.21
0.07
0.53
0.019
1.72
0.035
0.088
0.056
0.0035
0.0048



3.0
1100
60
1000
950


42
0.19
0.04
0.48
0.017
1.61
0.080
0.061
0.059
0.0020
0.0050
0.11


2.5
1100
60
1000
950


43
0.20
0.07
0.48
0.017
1.31
0.075
0.090
0.070
0.0032
0.0045
0.08


2.5
1100
60
1000
950


44
0.21
0.04
0.41
0.008
1.22
0.059
0.087
0.038
0.0008
0.0071
0.10


2.5
1100
60
1000
950


45
0.20
0.04
0.42
0.015
1.42
0.068
0.055
0.077
0.0011
0.0066
0.38
0.08
0.06
2.5
1100
60
1000
950


46
0.20
0.06
0.70
0.015
1.36
0.043
0.079
0.045
0.0007
0.0174
0.25
0.04

3.0
1100
60
1000
950


47
0.20
0.02
0.48
0.011
1.82
0.050
0.045
0.071
0.0005
0.0081



3.0
1100
60
1000
950


48
0.18
0.09
0.46
0.014
1.71
0.036
0.090
0.071
0.0039
0.0167



3.0
1100
60
1000
950


49
0.18
0.09
0.57
0.016
1.40
0.080
0.075
0.063
0.0037
0.0116



3.0
1100
60
1000
900

















TABLE 3








Production Conditions









Hot Rolling











Blooming
First
Second















Casting
Soaking

Forging
Forging




Cooling
Tem-
Soak-
Tem-
Tem-



Chemical Components (% by mass)
Rate
per-
ing
per-
per-



* The balance: iron and unavoidable impurities
(° C./
ature
Time
ature
ature

























No.
C
Si
Mn
S
Cr
Al
Ti
Nb
B
N
Mo
Cu
Ni
min)
(° C.)
(min)
(° C.)
(° C.)




























50
0.21
0.07
1.22
0.013
1.04
0.109
0.010
0.040
0.0006
0.0190
0.17
0.06
0.04
2.5
1100
60
—
950


51
0.21
0.35
0.44
0.008
1.40
0.029
0.056
0.076
0.0018
0.0062
0.11


3.0
1100
60
—
1100


52
0.20
0.08
0.45
0.007
1.02
0.033
0.062
0.072
0.0015
0.0068


0.01
3.0
1250
60
—
950


53
0.23
9.00
0.80
0.006
1.52
0.037
0.118
0.023
0.0012
0.0058
0.08


3.0
1100
60
—
950


54
0.18
0.07
0.28
0.012
3.12
0.038
0.059
0.066
0.0028
0.0062



3.0
1100
60
—
950


55
0.21
0.05
0.62
0.015
1.35
0.040
0.081
0.126
0.0021
0.0068



3.0
1100
60
—
950


56
0.18
0.05
0.74
0.019
1.84
0.033
0.039
0.051
0.0032
0.0128



3.0
1100
60
—
950


57
0.18
0.03
0.73
0.014
1.44
0.058
0.059
0.078
0.0039
0.0117



3.0
1100
60
—
950


58
0.19
0.07
0.45
0.018
1.06
0.028
0.044
0.021
0.0027
0.0046



2.0
1000
60
—
950


59
0.20
0.24
0.80
0.009
1.00
0.059
0.012
0.040
0.0030
0.0196



2.5
1320
180
1000
900


60
0.21
0.06
0.42
0.007
1.27
0.030
0.060
0.070
0.0018
0.0060



3.0
1300
30
—
950


61
0.20
0.13
0.50
0.012
1.07
0.015
0.069
0.087
0.0012
0.0054



2.5
1250
150
—
900









The obtained steel bar was subjected to measurement using the following methods.
(1) Measurement of Precipitates A longitudinal cross-section (plane parallel to the shaft center) of the obtained steel bar in the D/4 position (D is the diameter of the steel bar) was polished, and an arbitrary 10 mm×10 mm region was subjected to measurement using automatic EPMA. With respect to inclusions having a size of not less than 2 μm2, in the case where the Ti content was not less than 5 mass %, they were judged to “contain Ti”, while in the case where the Nb content was not less than 5 mass %, they were judged to “contain Nb”. Also for Mn and S, in the case where the contents were each not less than 5 mass %, they were judged to “contain Mn” or “contain S”. The detailed measurement conditions are as follows.
EPMA analyzer: JXA-8100 electron microprobe analyzer (manufactured by NEC Corporation)
Analyzer (EDS): System Six (manufactured by Thermo Fisher Scientific K.K.)
Accelerating voltage: 15 kV
Operation current: 4 nA
Observation magnification: ×200
(2) Measurement of Cold Forgeability
A φ20 mm×30 mm test piece was cut from the obtained steel bar as shown in FIG. 1, and subjected to spheroidization shown in FIG. 2, i.e., a heat treatment in which the test piece was heated to 740° C., maintained at the temperature for 4 hours, cooled to 650° C. at a cooling rate of 5° C./h, and then furnace-cooled from 650° C. to room temperature. The spheroidized test piece was subjected to an end-confined compression test at 50% rolling reduction to measure the deformation resistance (N/mm2).
(3) Measurement of Impact Properties
A test piece having the shape shown in FIG. 3 was obtained from the obtained steel bar. The test piece was gas-carburized under the carburizing conditions shown in FIG. 4 (carburizing-stage conditions=temperature: 950° C., time: 100 minutes, carbon potential: 0.8%, carburizing gas: propane; diffusion-stage conditions=temperature: 850° C., time: 60 minutes, carbon potential: 0.8%, carburizing gas: propane; quenching conditions=oil cooling to 80° C.), and then tempered at 160° C. for 180 minutes, followed by air cooling. The test piece after tempering was subjected to a Charpy impact test in accordance with JIS Z 2242 at normal temperature to measure the Charpy impact value (J/cm2).
(4) Observation of Structure
The steel bar was embedded in a supporting substrate in such a manner that a longitudinal cross-section (plane parallel to the shaft center) of the steel bar in the D/4 position (D is the diameter of the steel bar) was exposed. After polishing, the steel bar was immersed in a nital solution for about 5 seconds to cause corrosion. Subsequently, a 700 μm×900 μm region was observed and photographed under an optical microscope to identify the structure and measure the area factor.
(5) Measurement of Grain Size
A φ20 mm×30 mm columnar test piece was obtained from the steel bar, and the columnar test piece was compressed in the height direction at room temperature (compressibility: 85%, height: 3 mm), followed by carburizing and tempering under the same conditions as in (3) above (conditions given in FIG. 4), and the grain size was measured. The grain size was measured as follows. Using the carburized layer in a cross-section of the carburized and tempered test piece in the position at an equivalent strain of 1.2 as the position of microscopic examination, the cross-section was etched and observed under an optical microscope (magnification: ×200) to determine the grain size number of prior austenite grains in accordance with JIS G 0551.
The results are shown in Tables 4 to 6. Incidentally, Tables 4 to 6 also show the number of, of precipitates containing Ti and/or Nb, those outside the specified range of the present invention.









TABLE 4








Precipitates Containing Ti and/or Nb



















More than 5 μm2 and less








Not more than 5 μm2
than 20 μm2








Number Density
Number Density
Not less than 20 μm2

Average Size





(the number
(the number
Number Density (the number

(μm2), more



Deformation

of precipitates/mm2)
of precipitates/mm2)
of precipitates/mm2)

than 5 μm2



















Resistance at
Ferrite
Charpy

Without

Without

Without

without MnS



50%
Fraction
Impact

MnS ((Ti,

MnS

MnS

((Ti, Nb)-



Compression
(% by
Value
With MnS
Nb)-based
With MnS
((Ti, Nb)-based
With MnS
((Ti, Nb)-based
Grain
based


NO.
(N/mm2)
area)
(J/cm2)
(composite)
alone)
(composite)
alone)
(composite)
alone)
Size
alone)





















1
609
80
66.0
0.1
0.2
1.2
3.5
0.0
0.1
8.0
8.6


2
554
85
79.7
0.0
0.3
1.3
6.7
0.0
0.9
8.5
11.1


3
601
83
9.7
0.0
0.2
1.2
5.4
0.0
0.5
8.5
13.2


4
607
82
9.8
0.0
0.1
1.3
4.7
0.0
0.8
9.0
11.6


5
582
85
61.6
0.0
0.6
1.2
9.3
0.0
0.7
9.0
10.5


6
572
81
67.5
0.2
0.5
1.7
3.7
0.0
0.3
8.0
12.6


7
567
84
46.3
0.2
0.7
1.6
3.7
0.0
0.9
8.5
12.3


8
581
82
53.9
0.2
0.2
1.2
5.1
0.0
0.6
9.0
11.0


9
565
81
59.1
0.2
0.7
1.6
1.5
0.0
0.5
8.0
13.7


10
594
81
41.2
0.0
0.4
1.7
4.6
0.0
0.3
8.0
11.6


11
573
84
81.8
0.2
0.8
1.4
7.9
0.0
0.2
8.5
8.9


12
591
84
54.9
0.4
0.7
1.5
8.2
0.0
0.5
8.5
8.4


13
607
82
49.1
0.3
0.6
1.6
8.8
0.0
0.5
9.0
10.0


14
581
82
43.5
0.2
1.2
1.2
6.5
0.0
0.4
8.0
12.4


15
592
83
54.8
0.4
0.5
1.2
6.7
0.0
0.8
9.5
9.5


16
591
85
61.1
0.3
0.9
1.6
4.5
0.0
0.6
8.5
11.9


17
572
84
69.8
0.2
1.1
1.6
4.5
0.0
0.2
8.0
8.4


18
565
84
76.5
0.2
1.0
1.2
9.8
0.0
0.7
9.5
9.3


19
596
83
42.1
0.2
0.6
1.1
8.1
0.0
0.0
8.0
7.2


20
594
85
63.7
0.2
1.1
1.4
4.4
0.0
0.4
9.0
11.7


21
582
82
72.2
0.3
0.7
1.4
9.2
0.0
0.8
9.0
11.0


22
604
84
53.9
0.1
0.8
1.2
8.2
0.0
0.8
9.0
10.5


23
604
83
50.1
0.4
0.6
1.4
7.2
0.0
0.4
8.5
8.8


24
574
81
70.9
0.3
1.0
1.2
5.0
0.0
0.9
8.0
12.5


25
564
83
78.4
0.2
1.1
1.9
1.9
0.0
0.7
7.5
13.3


26
579
84
50.0
0.1
0.9
1.3
7.4
0.0
0.7
8.0
12.4


















TABLE 5








Precipitates Containing Ti and/or Nb



















More than 5 μm2 and less








Not more than 5 μm2
than 20 μm2








Number Density
Number Density
Not less than 20 μm2

Average Size





(the number
(the number
Number Density (the number

(μm2), more



Deformation

of precipitates/mm2)
of precipitates/mm2)
of precipitates/mm2)

than 5 μm2



















Resistance at
Ferrite
Charpy

Without

Without

Without

without MnS



50%
Fraction
Impact

MnS ((Ti,

MnS

MnS

((Ti, Nb)-



Compression
(% by
Value
With MnS
Nb)-based
With MnS
((Ti, Nb)-based
With MnS
((Ti, Nb)-based
Grain
based


NO.
(N/mm2)
area)
(J/cm2)
(composite)
alone)
(composite)
alone)
(composite)
alone)
Size
alone)





















27
598
82
58.9
0.1
1.0
1.8
3.1
0.0
0.4
8.0
12.2


28
610
80
44.8
0.1
0.7
1.2
6.4
0.0
0.8
8.0
11.0


29
578
80
46.9
0.0
0.2
1.7
3.7
0.0
0.3
7.5
12.4


30
570
85
61.8
0.3
0.4
1.1
8.0
0.0
0.4
8.5
9.4


31
594
85
66.0
0.3
1.1
1.2
7.2
0.0
0.7
8.5
9.8


32
583
82
60.8
0.2
0.3
1.3
4.4
0.0
0.4
8.0
10.3


33
600
82
45.7
0.2
0.5
1.3
4.9
0.0
0.9
8.0
11.8


34
578
84
62.4
0.4
1.3
1.1
7.6
0.0
0.1
8.5
7.2


35
574
83
44.4
0.4
0.7
1.6
1.5
0.0
0.1
7.5
10.6


36
578
85
66.1
0.0
0.3
1.5
3.8
0.0
0.8
8.0
12.3


37
560
81
68.6
0.0
0.4
1.2
5.2
0.0
0.6
8.5
8.9


38
588
84
49.0
0.2
0.8
1.2
5.9
0.0
0.6
8.5
12.1


39
596
84
45.1
0.0
0.8
1.1
5.6
0.0
0.8
8.0
13.3


40
609
82
76.2
0.3
0.7
1.3
5.7
0.0
0.0
8.5
12.5


41
583
84
43.2
0.1
1.0
1.3
8.9
0.0
0.7
8.5
12.6


42
584
85
52.2
0.1
1.1
1.2
6.7
0.0
0.9
8.0
12.7


43
603
84
38.2
0.0
0.2
1.2
10.0
0.0
0.1
9.5
8.2


44
599
81
42.2
0.0
0.2
1.1
8.4
0.0
0.1
8.0
7.5


45
601
81
43.2
0.1
0.8
1.1
7.3
0.0
0.8
8.5
11.5


46
594
80
45.2
0.1
0.9
1.0
7.5
0.0
0.8
8.5
11.3


47
599
83
37.4
0.4
1.4
1.5
4.9
0.0
0.9
8.5
12.9


48
588
84
43.8
0.0
0.7
1.3
10.0
0.0
0.8
9.5
11.8


49
568
82
55.4
0.1
0.1
1.2
8.1
0.0
0.6
9.0
10.2


















TABLE 6








Precipitates Containing Ti and/or Nb



















More than 5 μm2 and less








Not more than 5 μm2
than 20 μm2








Number Density
Number Density
Not less than 20 μm2

Average Size





(the number
(the number
Number Density (the number

(μm2), more



Deformation

of precipitates/mm2)
of precipitates/mm2)
of precipitates/mm2)

than 5 μm2



















Resistance at
Ferrite
Charpy

Without

Without

Without

without MnS



50%
Fraction
Impact

MnS ((Ti,

MnS

MnS

((Ti, Nb)-



Compression
(% by
Value
With MnS
Nb)-based
With MnS
((Ti, Nb)-based
With MnS
((Ti, Nb)-based
Grain
based


NO.
(N/mm2)
area)
(J/cm2)
(composite)
alone)
(composite)
alone)
(composite)
alone)
Size
alone)





















50
659
75
19.7
0.4
0.1
0.7
0.4
0.3
0.3
6.0
14.8


51
680
65
42.0
0.0
0.3
0.3
7.9
0.3
1.4
8.5
13.9


52
662
72
36.1
0.0
0.6
0.5
8.5
0.1
0.2
8.5
9.7


53
638
65
44.9
0.2
1.8
0.7
10.9
0.2
1.2
8.5
12.4


54
642
78
26.6
0.1
0.4
0.5
7.9
0.1
0.4
8.0
10.7


55
621
63
6.7
0.2
1.2
0.7
13.4
0.1
0.3
8.0
8.1


56
623
78
32.0
0.0
0.8
0.1
4.2
0.0
0.3
8.0
11.6


57
586
77
4.3
0.4
0.3
0.8
8.3
0.7
0.2
8.0
10.1


58
632
80
6.8
0.0
1.2
0.2
3.2
0.0
0.8
7.5
14.6


59
689
85
34.7
0.0
2.5
0.3
0.7
0.0
1.3
6.5
14.4


60
619
78
21.8
0.0
0.4
0.1
8.1
0.0
0.2
8.5
8.9


61
638
81
24.0
0.0
1.4
0.1
10.0
0.0
4.0
8.0
13.4









In Nos. 1 to 49, the component composition and the production method are appropriately controlled. Therefore, (Ti, Nb)-based composite precipitates having a size of more than 5 μm2 and less than 20 μm2 and (Ti, Nb)-based precipitates having a size of not less than 20 μm2 satisfy the requirements of the present invention, and also the ferrite fraction is more than 77% by area. As a result, excellent cold forgeability and impact properties are achieved. Incidentally, as shown in Tables 4 to 6, none of (Ti, Nb)-based precipitates having a size of not less than 20 μm2 in Nos. 1 to 49 contained Mn and S.
Meanwhile, In Nos. 50 to 61, at least either of the component composition and the production method did not satisfy the requirements of the present invention. As a result, at least either of cold forgeability and impact properties was insufficient.
In No. 50, the Mn and Al contents were high, and also forging, which is equivalent to hot rolling, was performed only under the second conditions. Therefore, (Ti, Nb)-based composite precipitates having a size of more than 5 μm2 and less than 20 μm2 and the ferrite fraction were insufficient, resulting in insufficient cold forgeability.
In No. 51, first forging was not performed, and also the second forging temperature was high. Therefore, (Ti, Nb)-based composite precipitates having a size of more than 5 μm2 and less than 20 μm2 and the ferrite fraction were insufficient, and also (Ti, Nb)-based precipitate having a size of not less than 20 μm2 were excessively formed, resulting in insufficient cold forgeability.
In No. 52, the soaking temperature before forging, which is equivalent to blooming, was high, and also first forging, which is equivalent to hot rolling, was not performed. Therefore, (Ti, Nb)-based composite precipitates having a size of more than 5 μm2 and less than 20 μm2 and the ferrite fraction were insufficient, resulting in insufficient cold forgeability.
In No. 53, the Ti content was high, and also first forging, which is equivalent to hot rolling, was not performed. Therefore, (Ti, Nb)-based composite precipitates having a size of more than 5 μm2 and less than 20 μm2 and the ferrite fraction were insufficient, and also (Ti, Nb)-based precipitate having a size of not less than 20 μm2 were excessively formed, resulting in insufficient cold forgeability.
In No. 54, the Cr content was high, and also first forging, which is equivalent to hot rolling, was not performed. Therefore, (Ti, Nb)-based composite precipitates having a size of more than 5 μm2 and less than 20 μm2 were insufficient, resulting in insufficient cold forgeability. In No. 55, the Nb content was high, and also first forging, which is equivalent to hot rolling, was not performed. Therefore, (Ti, Nb)-based composite precipitates having a size of more than 5 μm2 and less than 20 μm2 and the ferrite fraction were insufficient, resulting in insufficient cold forgeability and impact properties.
In No. 56, first forging, which is equivalent to hot rolling, was not performed. Therefore, (Ti, Nb)-based composite precipitates having a size of more than 5 μm2 and less than 20 μm2 and the ferrite fraction were insufficient, resulting in insufficient cold forgeability.
In No. 57, first forging, which is equivalent to hot rolling, was not performed. Therefore, the ferrite fraction was insufficient, resulting in insufficient impact properties.
In No. 58, the cooling rate during casting was low, the soaking temperature before forging, which is equivalent to blooming, was high, and also first forging, which is equivalent to hot rolling, was not performed. Therefore, (Ti, Nb)-based composite precipitates having a size of more than 5 μm2 and less than 20 μm2 were insufficient, resulting in insufficient cold forgeability and impact properties.
In No. 59, the soaking temperature before forging, which is equivalent to blooming, was high. Therefore, (Ti, Nb)-based composite precipitates having a size of more than 5 μm2 and less than 20 μm2 were insufficient, and also (Ti, Nb)-based precipitate having a size of not less than 20 μm2 were excessively formed, resulting in insufficient cold forgeability.
In Nos. 60 and 61, the soaking temperature before forging, which is equivalent to blooming, was high, and also first forging, which is equivalent to hot rolling, was not performed. Therefore, in both cases, (Ti, Nb)-based composite precipitates having a size of more than 5 μm2 and less than 20 μm2 were insufficient. Further, in No. 61, (Ti, Nb)-based precipitates having a size of not less than 20 μm2 were excessively formed. As a result, in both cases, cold forgeability was insufficient.

## Claims

1. A case hardened steel comprising, in mass %:
C: 0.05 to 0.3%,
Si: 0.01 to 0.6%,
Mn: 0.20 to 1.0%,
S: 0.001 to 0.025%,
Cr: 1 to 2.5%,
Al: 0.01 to 0.10%,
Ti: 0.01 to 0.10%,
Nb: 0.01 to 0.10%,
B: 0.0005 to 0.005%,
N: 0.002 to 0.02%, and
iron,
wherein:
a number density of precipitates that comprise Ti, Nb, or both and have a size of not less than 20 μm2 is not more than 1.0/mm2,
a number density of precipitates that comprise Mn, S, and at least one of Ti and Nb and have a size of more than 5 μm2 and less than 20 μm2 is more than 0.7/mm2 and not more than 3.0/mm2, and
a ferrite fraction is more than 77% by area.

2. The case hardened steel according to claim 1, further comprising Mo: more than 0% but not more than 2%.

3. The case hardened steel according to claim 1, further comprising at least one of
(i) Cu: more than 0% but not more than 0.1% and
(ii) Ni: more than 0% but not more than 0.3%.

4. A method for producing a case hardened steel, the method comprising:
subjecting a steel comprising, in mass %:
C: 0.05 to 0.3%,
Si: 0.01 to 0.6%,
Mn: 0.20 to 1.0%.
S: 0.001 to 0.025%,
Cr: 1 to 2.5%,
Al: 0.01 to 0.10%,
Ti: 0.01 to 0.10%,
Nb: 0.01 to 0.10%,
B: 0.0005 to 0.005%,
N: 0.002 to 0.02%, and
iron to casting at a cooling rate of not less than 2.5° C./min from 1500° C. to 800° C.,
blooming at a heating temperature of 1100 to 1200° C.,
first hot rolling at a rolling temperature of 970 to 1150° C. and then cooling to Ac3 to 950° C., and
a second hot rolling at a rolling temperature of Ac3 to 950° C.,

thereby obtaining the case hardened steel.