# ® - BORAL BRICKS, INC. 500 Northridge Road • Suite 300 Atlanta, GA 30350 Telephone 770-645-4500 • Facsiniile 770-645-2888

www.boralbricks.com 

# II--D-105 April 10, 1998 Bruce C. Jordan, Director Attn: Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 Subject: MACT Infonmation Collection Request Response Submittal for Boral Bricks, Inc. Dear Sirs: Boral Bricks, Inc. is pleased to submit the enclosed completed Structural Clay Products MACT Information Collection Requests for its remaining 6 facilities. These 6 ICRs complete Boral's submittal which totals 18 facility locations. As before, we would like to stress that Boral Bricks is committed to working with EPA to help develop an appropriate MACT standard for our industry. To this end, we have chosen to complete Enciosure 2, believing that it provides the most focused, industry specific information available. It should be noted that in completing the ICRs we have used the best available information for each of our facilities. While most of Boral's understanding and subsequent completion of Enclosure 2 was developed from the instructions provided by EPA, several items required further clarification and interpretation. Many of these items were discussed with Mr. Bill Neuffer through our environmental consultant, Mr. 011ie Fick with CH2M HILL. Although these items are highlighted in the completed ICRs, there are several that warrant specific mention in this letter. They are as follows: Based on a February 25, 1998, telephone conversation between Mr. Fick and Mr. Neuffer, Boral understands that details on fugitive emission sources need not be included in the ICR unless there is specific test data available to support emission estimates. The HAP emission infonmation requested in Table 5 is being submitted through the enclosure of source test and mass balance data (Appendix B). As allowed in the Enclosure 2 instructions, Boral considers the submission of relevant sections of applicable data to be preferable to providing emission estimates. Boral has reviewed all applicable and available data and has excerpted those sections relative to HAP and HAP surrogate emissions to include in Appendix B. EPA will note, however, that the quality and consistency of the data and supporting documentation varies widely among the various plants and states. This is largely because environmental affairs for many Boral facilities has been historically managed at the plant level. This has only changed within the last 2 years.


# BRICKSTUDIO. /

n~~~ sowu srt

~ cKs~ 

### VIr. ,Bruce Jordan

April 10, 1998 Page 2 Where appropriate, Boral has used Title V permit application information in completing the ICRs. However, Boral believes that the methods used to estimate emissions for penmitting purposes are different from those necessary in the development of a MACT standard. Therefore, the emissionestimates used in the Title V applications are not included in the ICRs except where actual plantspecific data was available. Boral is in agreement with the Brick Industry Association in their recommendation not to use the AP-42 emission factors to estimate emissions. Once again, we consider these factors to be inappropriate for use in the development of a MACT standard. We very much appreciate Mr. Neuffer's time and assistance in answering our questions and providing further clarification where needed. Boral Bricks looks forward to working with EPA during the interpretation of the enclosed ICRs and the future. development of the MACT standard. If you have any questions or comments please feel free to contact Mr. David Johnson at (334) 480-2487 or me at (770) 645-4500. 

### Sincerely, 

# ,&w~ ~~ 

# / Edward M. Thebaud Vice President - Manufacturing
cc: Dennis Brown David Johnson Mary Ann Keon

~ 

# `"`~,~ •a ~ ~` ~ T . r . =~:l~1t~',~+~ °~~ 'n!



# EPA MACT Information Collection

,._ •, ~ -.; ;•'
~ €" ~ . ~
- 

## ;"q""'

~ , ;~, ~'`z~+!r~d~+•„~ 

## : - .. ~ ~ ~'~ 

## `.`.

5 -

~ " • _'~.-~~~~~'~'~~ ti: 4- ~ ~ rv. _- .

..-a-, — y~ ~.v.~.~

~ 

## ` - - 

## _ q • : ~

~ " - - •r- ~ ~ "-• . - -

M

-..n. ~ - __— . z
~ — - ~ . -- ~•~ -•-•—•—.

I ~ ~

, 7 

# ~

~

, . r, - - ~ '~^~~ --•` ~ 1:

- ~=~ + __
— - ~- ~ t' ~

at.. <.a: - . - c . . y _ --- :- . : - d -. tt. ~ . •'- ..

~ 

### r

- .',

~ . : ~ ~ ~ •'°!!' •.'L' _

~ x-+"

~ '~ _ . . '±v, ~ _ : -

. _. .♦ _ . . ,.. . . _ , _;. _ . ~ - •~

~ $

-~_~.-~ 

# <. -

~ 

# ,•-

~ 

# -- - _ ~ 

# - .. - ~ '~ 

# . .-. „ ~ ~ 

# _- _ ~ ~ ~

~ ~



# 0l 1"U

# • MACT Information Collection Request Response from Boral Bricks, Inc.

Table of Contents 

# • Information Collection Request


# • • Appendix A - MSDS's

• Appendiz B - Test Data



# 1l

### Enclosure 2

INFORMATION REQUEST FOR BRICK AND

STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS I. Instructions Please return the completed information request to: Bruce C. Jordan, Director Attn: Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at (919) 541-5435. 

### This information request should be completed for each facility that manufactures brick and structural clay products, including facilities that are not major sources. Information is requested for all processes at your plant that emit hazardous air pollutants (HAP's), including those processes that are not associated with brick and structural clay products manufacturing. Sections II through VII request information specific to brick and structural clay products manufacturing, and Section VIII requests information on emissions of HAP's from other processes located at the facility. Processes that may emit HAP's include those processes that use or handle any materials that contain a HAP compound, all processes with elevated temperatures, and all other processes in which HAP compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is included as Attachment 1 to this information request. Atta.chment 2 provides background information on the requirements of the Clean Air Act and explains how the information requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations and acronyms used in this information request. Several tables are provided throughout the information request for your convenience in answering the questions. An example response is given (shaded first column or row) in each table. If additional space is needed to respond, please make copies of applicable pages. If necessary, please make copies of this information request for additional facilities. No additional emission testing or monitoring is required to respond to this request. 

# amm

- 

### 71M.! 

## oi •!1!•F •! A. Name of company Boral Bricks- Inc. Name of facility Marshall Plant

Page 1 of 29

J~ ..

### Facility address: No. and street 1902 N. Franklin St. City Marshall State TX_ Zip 75670 Latitude and longitude coordinates of plant: 32 0 33'35" 94 0 22'05" Standard Industrial Classification (SIC) Code(s) of brick and structural clay products manufacturing operations 3251 Dun and Bradstreet No. 00-327-5682 Total No. of employees for company > 1,500 for facility 36 (If facility is a foreign subsidiary or if company has foreign subsidiaries, include number of employees not based in the U.S.). Please complete the following shift information for the facility: Shift No. of employees Hours per shift Days per year 

## 1 34 9 260 2 1 (kiln operation) 8 365 3 1 (kiln operation) 8 365 B. Respondent name Guiomar Obregon Respondent title Anal,yst Respondent address (if different from above) and telephone number: • . • street 500 Nor 

## t hr



## i dge C•,d Suite 300 

### City Atlanta State GA_ Zip 30350 Telephone No. ( 770 ) 6454500 Name and telephone number of technical contact person (if different from above) Name David Johnson Telephone No. (33A) 480-2487

~ •r~~. •~ •~ 

### ••-

~ 

### • •_• ~~ ..~• ~ 

### •• .• - -.- ~~ •~ 

### _ ... ~ 

### .._ ~ 

### A. Please provide copies of relevant parts of all operating permits and permit applications for your facility. Relevant parts include the sections that providespecific information and data on: processes that emit HAP's; the use of HAPPage 2 of 29 

# 6 7

### containing substances; emission levels for HAP and surrogate pollutants (i.e., VOC for organic HAP's and PM for metal and other particulate HAP's); emission control device design and operation; monitoring and operation and maintenance (O&M) procedures for control devices; and generation and releases of other media such as wastewater and solid waste that are associated with the operation of air pollution controls for brick and structural clay products manufacturing processes. If the operating permit or application contains the same information requested in any part of this questionnaire, you may respond to the requested information by referencing the page or section of the permit/application to avoid duplication. If you reference your permit or application, you must supplement your response with all of the additional information requested in this questionnaire that is not included in the permit or permit application. If you prefer, you may submit the requested information from your permit/application on a 3-1/2 inch diskette. B. If any source or emission unit at this facility is subject to a New Source Performance Standard or other Federal emission standard, please identify the source and applicable standard. Examples of applicable NSPS include 

### 40 CFR 60, Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing Plants, and 

### 40 CFR 60, Subpart UUU- Standards of Performance for Calciners and Dryers in Mineral Industries.

' 1M, = ~ ~ M "t M .

~~~~~ •~ 

### A. Please provide the 1997 production rates and the current production capacity for each type of brick and structural clay product manufactured (e.g., structural brick, clay sewer pipes, structural clay tile, etc.). Note that production data should be provided in units of tons per year (tons/yr). Product 1997 production (tons) Production capacity (tons/yr) Brick (fired weight) 63,222 66,845

Page 3 of 29 

# 7

### B. Please proviciU the type and amount of each raw material and body additive used in 1997 for m_ , ~ 

### n}afacturing 4.; r ick and structural clay products at your facility. Examples include clays, shale, and a.ny additives that are mixed into the raw material prior to forming. Indicate additives by chemical compound, rather than by trade name. If the information requested is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. Raw material/body additive Amount used in 1997 (tons/yr) Clays (wet weight) 76,000 Iron oxide (dry weight) 110 Manganese (dry weight) ~ 

### 35

C. If available, please provide a copy of the MSDS's for the raw materials and additives listed above. See Appendix A D. If available, please provide chemical analyses, including fluorine, metals, and organic content, of the raw materials listed above. See Appendix B(Raw material analysis)

Page 4 of 29 

# 0

### E. Using Table 1, 

### please provide information on the consumption and HAP composition of all glazes and colorants that contain HAP's or HAP precursors and that your facility applies to brick and structural clay products. Indicate whether the coatings are glazes or colorants. Also indicate the type of product that the coatings are applied to and the total weight of coatings used in 1997. If the glazes or colorants are formulated at your facility indicate so and provide the production capacity. List each ingredient of the glaze or colorant. Beside each ingredient, indicate the total amount of the ingredient used in 1997. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. F. In the space below, please indicate any glazes or colorants used by your facility that do not contain HAP's and are substitutes for HAP-containing glazes or colorants used by your industry. Indicate which HAP-containing materials the non-HAP glazes or colorants replace. Describe any limitations on the use of those substitute glazes or colorants.

G. If your facility colors brick and structural clay products by flashing, please indicate the types of substances used to flash the products and the amounts of those substances used in 1997.

H. If available, please provide a copy of the MSDS's for the glazes and colorants used by your facility. If your facility prepares its own glaze, please provide any available MSDS's for the glaze ingredients. See Appendix A
Page 5 of 29 

# 0

### TABLE 1. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND COLOR.ANTS

the table is contained in your facility iperating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. Page 6 of 29

### / ' ~ 

### • • ! • ~ 

### !W s
~ ~ 

### MM UT ' V OM MI MOM-3
~ 

### •



### A. Please provide a simple process flow diagram for each brick and structural clay product manufacturing process line. An example process flow diagram is provided in Figure 1. A diagram of the plant layout with all processes and emission points clearly labeled is also acceptable. Assign a unique identification number (ID No.) for each process that has associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. Please identify aU emission points, including those that do not emit HAP's. For emission points that are vented to an air pollution control device (APCD), assign an ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information request for any responses that pertain to any process or emission point.

Page 7 of 29



## ~~E— 

## Z J ~ 

### J J ~ 

# 2 a
Q ~ 

# 20
v/ LL 

## Y u ~ 

# U W
~ 

# V m0 J ~



# ~ 

# a O

~ \ W ~ N 4-i 0 ~ ~ ~ 

# a ee tm

U

ol ~ 

### 7 N C N 

# W ----------- 6 ----- 

### ~ 0 N ~ 

### y

t ffi



### ~ ~ f --- ----- 'c Y

iz t

rn c
. ~

c . c C9 ~



## c O1 m m« -6 N a~ m p d

~ i P ~ } tl! Y

.2
m "C ~ 

### m .~ m ;~ ~ ~ Q LL 

### ~ J S t tll
~ U a`>

~

~ L N 2 U 

### Y U 

### H

~
~ 

### 3 G

W O ~ J O O ~ ~ ~ 

### w ~ ?

~ 

# :10

d 

# a 0 U m N



## 0

~

~~

### B. Using Tables 2A and 2B, please provide current production rates, production capacities, and related information for each type of equipment used in brick and structural clay product manufacturing. In Table 2A, provide the requested information for only those sources that are known or expected to emit HAP's. In Table 2B, provide the requested information for all thermal processing, such as drying and firing sources. For combustion sources that use different fuels, Table 2B should be completed for each type of fuel. For example, if a kiln typically is fired with gas, but periodically is fired with oil, one column in Table 2B should be completed for the kiln when fired with gas, and another column should be completed for the same kiln when fired with oil. Provide the data in the units listed for each row.

Page 9 of 29 

## 1-3~ ca 

### a

~ ~ w 0 i .~ 0 U

~ ~ N y R d 

# a •n

.~ G"
~ y .~

~ 

### a ~ ca 0 'O 

### R w ~ 41



### N (4-4 0 0 ~
~ C~ 

## a A ~ 

# U W

~ 

### N w
~

~ H 0 ~ .~ b a~ .~ ~ a 0 U

.~ N

~ ~ ~
~

.~
y a~ c w 

# ° o ~

~

~ 

## yw a

O F, ~

~ N

~ ~ + ~ G O O O 

# z
a~
~ V a7~ ~

~ a> 

### a r

~ 

### .

• o, a ~ U ~ G O ~ V1 ~ I• ~ •1 

# z o ~ A 

### a y w O a + U C7 ~/]

~ -. ~ •
' U G

•~ ~ /~+ • y ~ /1 .~'

Q y 

### Q 4W p„

• 

### d ~ 

### y 

# •°
~ 

# _

. `w °

Gl/

### O O O • y f- ~ b ~ ^C 

### y •.y ~ 

### U N Qa 

### a ~ 

# O ° b

~ 

# o

~ 

# v

~ 

## x U

~ U


### ~~ 

## O
p..D

~~ Q U

~ , 

# 0 

# a~ 

# > v
y N 

## O 1.. O ~ U ~
bD pq O\ 

### N

~

~ c~ 

## a y N

C6 y ~ N U 

## O O

U

.. ~ .G U '~ , d 

# o

~ ~ U 

# 3 U 

# ~ o ~ a U m ~ 

### ,d C i '.r y 

### U y O 4-4 y 

## ~ ~ " " > N 

## ~ ~~ ~ C 

### O

y ~ v y i ,~ ~ ^d • ~ 

## °a • ~' 

## ~ o ~ o 

## ~ ~ O y 

## ++ .~ 

## "d ~~~.~•~

~

~.~•~~ a

` " i V O ~•~.~ 

### U O N U 

## t 

# u •~ ~ ~

a 4" ~ y ~ 

## ~ 

# o _" y

~ y r•+
~•~ ~a~



# ~ ~ 45 a W o on on 

### ~

/157

## U H W C/] 

# z a ~

~ 

### ~ 

### A

~


### ~ cn ~ 

## W U

~ 

## a 

## a d 

# ~ W H

~ N W 

## a ~¢ 

### H ~ .~ i o~ 0 ~

~

~ U
~ O ~
~ ... "Cy

NT 

### ~ v, ti ., a .+ o. 

# xz ~

~ CA 

## z •• N N

Ld Ca ~ ~ ~ ~ y+ C%~ .-r

~ 

## 3 p ° C7 x ~ 

## a, a

¢ „ ~~ 

## b
~ M 

## „ ~ 

## ., o -d 

### 0~ 

## 3 z cn z z v1

•~ ~ ~ ~ ~ ~~ •• 3 ° a z 

## i ~ ~ 

# M z ° o a



# za o a 

# za ~ 

### M~ ~ 

### ~ ~ 

### o 

## w

~~

•~ ~i ~ 

# a
cn~



## ~ o En


### ~ 

# o •y U y ~ U ~ 

# O ~ o

~ ~ U 

# ^ a tb 

## ,

E! o 0 ,0

~ ~ ~ u~. ~G y ~ C • G ~ O ' f"' " 4 ~ $.4 

## ° ~ c~
w
C d



## ~ -• 

## c

ri c•; ~ r vi ~c ~ o0 0; a a ~ A a. 

### (ON 

# N (4-4 0 

# N_

~ c~ 

# a

/6

### C. Using Table 3, 

### please provide information on procedures used to monitor the process operating rate for each of the pieces of equipment and HAP emission sources listed in Tables 2A and 2B. Use the same HAP emission source types and equipment ID numbers you listed in Tables 2A to 2B.

• Indicate whether you monitor process rate 

### or not.
• Provide a summary of process rate monitoring procedures 

### that describes how process rate is measured for the particular piece of equipment. Include where 

### the rate is monitored (i.e., rate of material fed, rate of material discharged, or material production rate), the units used to measure process rate (e.g., lb/hr or pieces/hr), and how 

### the process data is recorded, 

### i.e., manually, automatically (e.g., computer - printout or stored to disk, or not at all). If you monitor process rate at both the feed and discharge ends of the equipment, indicate so. Indicate the type of monitor, equipment, or instrument used 

### to measure process operating rate. Indicate the monitoring frequency 

### or how often process rate measurements are made. If instruments are used to measure process throughput, indicate in the monitor accuracy 

### column the accuracy of the instrument. The monitor accuracy could be listed in terms of a percentage of the throughput (f 1 percent), mass per unit time (f21b/hr), number of pieces per unit time (f 10 pieces/hr), or other appropriate units.

• Indicate the frequency 

### that the monitor is calibrated.

• Provide data in the units listed for each row.

Page 13 of 29 

# 17.~

~ 0 ~ .~ 

### w 

# ~

~ ~

~ 

## a

~ w 

## O G O

• 

### U y
~ ~ 

### .~

~

~ ~
~ ~ 

## w 

# ~
~ 

### E ~ 

### O

~



### ~ on 

### .S 

# w Q~ O N b 0; A ~ 

## a ~ 

### 0 2 

### CA 

## 0 U 

### e`a a~ 

## a d .~ o~ 

### ~ .~

~ 

## a
L' ~ 

### .~

~ w ~ O1

N w O
a~ c~ 

## a

.~ w ~
~ 

### Q w 

### U 

# a C7

~ 0 H ~ 

### 0 

### W


# ~ ~ ~ 

## W 

## U

~ a4 

# w

~



## ~ ~ ~ M 

## w 

# a ~ H ~ O 

## O C



## z¢ z¢ z¢ ¢ C 

## w z`

'C a~ C

~ ~ Cd U U e U d • ~ •_ ~ ' .•-w C7

~ 

# zw zw z¢ z¢
~ ~ ~ •_ ~ ~ ~ ~ .E

N
~ 

## z¢ z¢

~ Ir

e~d Cd ~ 

## oa oo, 5 E : ~~ ~~ z¢ z¢ ~ w N • ~ V s. vi
~ .0 ~ 0 N a

O Cr ~" ~ CS' y •~ ~ •C ~ ~ ~ ` ^~ ~ „~ y E

„ NNai



### -v N •~e 

## yn~~ a

~ O v'rn u. .~ 

### w, •o U ~ r•+ rn p 

### x 4 4, ~ ~ • ~ +...D U 

## a ~



## O N L

. , 

## _ ~ ~ O .~ ~ ~ C @ ~ 0 V ~ ~ 'a
•S E 0.0 0. 7 w O

C Z 

## cn z O 

### z ~ 

### ~ 

## a cr 

### o o s 

# o
> 

## Q 0 0 z z ei

~. I..i N 

### a z w 

# w

.~ ;

~ ~ o 

### .y 0 ~ 

### .'! ai y~ 

### 40. .

~

•

/ r~ ! •! • ~ ~ .o- im i*--' ~ •~ ~'! ~ l l' !! •!

~ • 1



### A. Use the process flow diagrams developed for your facility and Table 4 to provide the following information for each HAP emission source at your facility. ' Define HAP emission source type in terms of equipment, such as dryers, kilns, etc. As in the process flow diagram, you may group multiple pieces of similar equipment. ' Use the same equipment ID numbers indicated on the process flow diagram(s). ' If the emission source vents inside a building or to outside ambient air without first passing through a control device, place a check mark in the uncontrolled column. ' If the emission source vents inside a building or to outside ambient air after passing through a fabric filter, dry injection fabric filter, or scrubber, place the . APCD ID number(s) in the column corresponding to the APCD type. ' If the emission source vents through a control device type not listed in Table 4, indicate the control device type in the other control column and place the APCD ID number in the appropriate cell. ' In the emission test data column, place a"yes" or "no" in the appropriate cell to indicate whether the specific source has been tested for any pollutants, including any HAP's, VOC, PM, or opacity.

Page 15 of 29 

## l /
~

# z 

# o_

~
~ 

### a 

### a 0 

## a

~ 

# Q v~ W U
~ ~ 

# O O

~ ~ ~ ~ 

# w

~ 

# x 

# w O
~ 

## ~ ~
~

~

~ 

# w a

~ F~ 

### ¢ 

## H ¢ 

# Q

~ ~

~ 

# z O
~

~ W 

# w O 

# H

~ 

## a 

# ~ a d > Q 

# z ¢ H 

# z ~ 

# a_

~ 

### d 

## a 0 

# x H O 

### U b ~ [ 

## z z U

y ~ U ~ ' ct s ~ a 

## W «s y ". 

## b 0 U
~ . N C 'U F.

~ J U v p i • .~

I.. ~ ~ 2
~

o ~

• U ~ 

## w „

. C J . 0 

# A `~

~ w
b 

# 0
U C 

### .`~
A
~ C
~ o M 

### A a z c

~ 

### i

a~

~ 

## y 5 O\ N 4- O

~ 

# o ~ ~ ~ 

## a



# mo

### B. Using Table 5, please provide information on stack parameters and emission estimates for each emission point at your facility that is known or expected to emit HAP's. Provide information for all APCD's, including those that exhaust inside the building. Include data for each inlet and outlet, if available, as indicated in the table. If you have more than one inlet to an APCD, provide data for each of the inlets. Provide data in the units listed for each row. Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal HAP's or VOC for organic HAP's. Emission estimates may consist of measurements reported in emission test reports or may be calculated using mass balances, emission factors, engineering judgement, or other estimation methods. Provide the emission estimates as emission factors in units of lb of pollutant emitted per ton of product (lb/ton). Provide complete copies of any emission test reports or other reports that document measurements of emissions. Test reports and other emission measurement documents should include the following information: process identification; location of sampling point; stack diameter, temperature, and flow rate; test method, including analytical procedures; number of test runs; emission concentration, emission rate, percent oxygen, and percent moisture for each test run; process operating rate; type of APCD; and APCD operating parameters. However, test reports with incomplete documentation may still be useful and should also be submitted. You do not need to fill out Table 5 for emission points that are covered by an emission test report that is included in your submittal. If emission test reports are not available, provide calculations that support your emission estimate, including the basis for all assumptions in the estimate. Note that emission estimates are needed for all HAP's that the facility emits or has the potential to emit. (Please refer to the HAP list in Attachment 1.) If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 17 of 29

.~ 

# -r~ 

### i

W W

~ 

## H ~ 3 7 ^'
.~

•--~ !''] 

### U ° C" r 

## ° ^

~ ~



## H



# o ~ 

# 0 o 0 0

~ ~ o

~ 

## O O O O O

~ U 

## ++ O

O N

~ ~

~ a~ ~ a O

~ ~ 

## a

^ s ;

,SE U U ~ ¢ • ~ \ Q

` y ~ •~

. f+ y tA ~ C~ ^' Li a U + ~
~ C ~ •~ '" U ~ ' ' " VI N L ~ ~~ V bA N t cd

. U

? ~ - ~ v, v, C7 ~o ~o C7 C7 C7

~ W -• cS ri ~ vS a a ~ a 1

~ 0 ri o0 0; Q1 N 4.4 0 00

~ a~ ~ ~ 

### a

o~~ r 6~ ir 7

~ 

# z

~

~ ~ ~ Q 

# w

F-r y 

# o z 0 U

... 

## ~ ~ A

O ~ 

### a 

# O ; 

# ~ O W 

# ~ = C 

# z

~ 

### o. 

# z 0 

### O O 

## w 

# z
~



# ~ 0 

### z
~ y 

## /1 - bA

~ ~ • i..i N y 

## _ •~ Cd Y 

### s q 

### ~ y d Q

~ [ a

N o

• 

### y • ~ ~ C y~Cj ~• a~ a ¢ a ¢ ~0 ~
~ = ~ ~ ~~ o o •~~; ~ ~ 

### w . ~ 

### aa •-, . ~ ~ o ~ 

## CN N 4.4 O O~ ~
~ ~ ~ 

## a

~ ~ ~

~ 

### w O

~ ~ ~ N .~

~ 

### Q\ 

### N G= 00

~
~ 

## U 'fl Q
~ 

# zz
: n z ' z 

# 191

### C. Using Tables 6A through 61), please provide design and operating data for each APCD associated with all dryers, kilns, and any other brick and structural clay products manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of APCD's. Use Table 6D for other types of APCD's. When using Table 6D, please specify the type of control device and 2 to 4 key design or operating parameters for the device. Provide data in the units listed for each row. If the information requested in Tables 6A through 6D is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the tables.

Page 20 of 29 

# ,-2 ~ai

~ 

### ° ~ 0 oD
~

~ 

### r o~ ~ ~ U 4"

~ .+

~ •~

U y

U d 

## A W °~ CL 

### a y d U H ~

bA U rT

~ ,

~

~ th~ o

C/]


# x a cn °

e~ • U

~ 

## a ~ 

# v

N ~

.~.~ ~V •~ O~U rn \/ ~"i y

~ ~ 3 ~ •~



### ~ 

# ° o 

### ~ 0 

### a~~i 

# Z o ~ ~ ~ •° .~ ~ E l A 

## ~ o ~ .~ ~ w ~ a ~ a •~ ~ a •~ ~ .~ ,~, ~ 

### c ' ~ ~ °~ ~ °' 42 

### 'w' cz W ¢ U 5 a~ W oN N 4- O ~ N

~ c~ 

### a

0V1

~ W L l~ a ~ w 

### U
~ Q 

## w 

# z

~ ~ H 

### U 

## W 7 —. G

W 

## La ~G ~ 

### W a Q F~

~ 0 a~

~ 0

~ n 

## s

~ ~ i
~ ~

.~ .~

~.
~ 0
~ 

### 0

.~ U N y Q~ ld

. V
.. .~ C0

~ Q~

~ ~ ~ 

## w ~ ~ 0 ~ ~
~ ~ a bA

~ a~ p ~ U o y 

### o a. 

## z ¢ w ~

~ 0 ~ .5 b 

## .9 0 ~ H .~ ..fl N

~ W ~

~ 

# a .5 oa

~ ° ., ~ ~ •'' 3 y ' ~ o ~

pq O o '~ 

# ., o 

# , . ° gp A ON N 4-i O N N d) to c 

## a



# -0-W



### w

~ ~ ~ C~ 

### U

~ 

## U ~o 

# w 

# a I ~ ~
~ ~ ~ ~ ~ .~

~ 

### a

~ ~ 0 c 0 .~ 

# U N y 

# _N
.a ~ ~ 

# a ~
~ a~ U F". U tr 

### W w A 

### 5

~ 

## A

.. ~
. 

### ~ ~ t]. a~ op 

# a ° z .~
~ ~ ° ~ .5 b a~ .5 ~ 0 0 U y .~

~ ~ ~ 7

~ ° ~ •~ 'a. ' ~.~ "~~ ~ Ir .,~~ Q~ 

### "90 

# n
U o0 00 5

4 r ~ hr G1 N 4-4 O M N

~ Lt 

### a,



### ,~L~~



### W U
~
~ 

### W 

## A a O

~ H 

# z 0 

### U

~ W

~ 

### O A

~ W 

### a M W

~ ~ a

~ ~ ~

~ ~ t a : 4 < t C .+ C E c E 1 c C 

# ._ t

a a 

# : a c e a w ~ ~ ~ 

### E 

## c

~ 

# €

~ b t:

• L 

## c c v

~ .` 

## w L

~ C

. a C 

## Q

~ 

## R " Z 

## C U u. .~

~ ~ a~ 

# O G
y

y 

## 4 m 

# a Q. a a ~

... ... ... ... .5

~ w 

### (ZIN N 4, 0

~ N

~ «S 

## a

~ 

### ~

~ 0 bn 

### .9 47



# m

### D. Using Table 7, please provide the following information on current monitoring procedures for each of the control devices listed in Tables 6A to 6D: parameters monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices used (e.g., differential pressure transducer, thermocouple), and recordkeeping practices (e.g., manually recorded in log book, continuously recorded by electronic data acquisition system). Describe briefly other operation and maintenance (O&M) procedures for each control device. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.



### e - siumfm e C Mm--ro ! -

~ 

### t- i.m wsm- - U ,-ro - Fm A. Please describe all pollution prevention practices (i.e., process modifications, such as re-use of discarded or rejected materials, or any practice that prevents or reduces the amount of air emissions, or the generation and release of solid waste or wastewater associated with the operation of air pollution controls). If the information requested here is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below.

Page 25 of 29

,~

W 

### a

~ H ~

~ tu 0
~ e 

### U w

= ~ 

### a O C I I I I I I a t4 o to I I I I I I o
•c I I I I I I ~ 

# U_

N

a

. ~ i i i i i i o N
a c lu i I I I I I I r 

# C_

~~ I I I I I I • 

### ~

I I I I I I I I I I I I 

### ~ ~•~

Ir ~i ~

~ •~
~ 

# w
~ A 

# o a • 

# u z a • ~ 

### w ON N ~ O
~ N
~ c~ 

## a

3~~

~ ~ A W 

### U

~ 

### a

~ 

# ~ O A 

# ~ C7 

# ~ O 

### H 

# z

~ ~ 

### W 

# U_

~ 

### W 

## A 

# a H 

# z 0 

### U n 

# W W



### ~ F~ 

# ^

~ 

### ~ A O ~ 'd 

### Q

... ~ ¢

N U 'O 17 ~ C O U

y 

# U

~ 6

~ .

,~ o • , 

# I I I I I I I I
•~ i i i i i i i i

i i i i i i

i i i i

i i i i

i i
i i i i i i i i



### I I I I I I I I 

## a I I I I I I I I [ I I I I I I I I

I I I I I I I I b o I I I I I I I I oG I I I I I I I I

o? I I

I I I I

I I I I

I I I I

I I H'tu I 1 I I I I I I b I I I I I I I I



### I I I I I I

I I I I

I I I I

I I I I I I I I I I I I I I I I I I I I I I I I I I
u o I I I I I I I I



# ~ O 

### I I

I I I I

I I I I

I I I I

I I A A d ° 

## uz i c~ N 

### 4-4 O 

### n N b O A c~ 

### a

~

~ 0 ~ C 0 v

~
~ ~ a 

### ~ 

## u

~ 

## u n
~ 

# u

~ 

# e 3 ~ u ~

31kvill 

## • • • ~ ~ 

## _i . i.

! • 1!! • • ! • ! • - ! " !

~ 

## _!
~ 

## • . ~ 

## _! !

. ~ 

## ._ _ • ~ 

## , • - - A. Using Table 8, please identify all other processes or operations at this facility that are not addressed in Items II through VII above and that are potential sources of HAP emissions. Estimate total annual emissions of each HAP emitted by these collocated processes. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 28 of 29 

## '3Z

### TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCES

Process/emission source/SIC Code(s) HAP's emitted 

# I Estimated annual emissions, tons

Vehicle Maintenance and Refueling in Support of Brick Operations--- Vehicle maintenance and refueling in support of Boral Brick's manufacturing and sales operations take place at this plant but are not otherwise identified or reported in this ICR because there is no emission data. No Data 

# I Not Applicable



### SIC 3251 Quality Control Testing Lab in Support c Brick Manufacturing-- A small quality control testing laboratory operation takes place at this plant but is not otherwise identified or reported on this ICR because there are no emissions data. No Data 

# I Not Applicable

Page 29 of 29
2/ RARSIIAW/FI I.TROL 

### NATERIAL SAFETY DATA SIiEET CODE : 541-032 

### I'1tUUUCT NAME L-6570 Yellow Body Stain, 11-33-84-WP DATE: 09/23/86
-- SECTION I -- IDENTIFICATION 

## SUPPLIER'S NAtlE Harshaw/Filtrol Partnership 

## ADDRESS 30100 Chagrin Blvd.

Cleveland, Oltio 44124 

### CAS'No. 68186-90-3 

### U.N. No. Not applicable 

### D.O.T. CLASSIFICATION .Not regulated 

### EHfiRGENCY TELEFI(ONE 216/292-9200 

## CIEENICAL NAME Chrome Antimony Titaoium Buff Rutile; C.I. Pigment Brown 24
FORtiULA C. I. 77310



### --- SECTION II -- 1(AZARDOUS INGREDIENTS OF HIXTURES


### Ha 

## terial or Com 

## o

p nent Crystalline quartt 114808-60-7j** Chromium III oxide as Cr [ 12018-01-8 1*e 

### Antimony oxide as Sb 112036-21-4 [+* 

### Titanium oxide 

### 113463-67-71*

- h **See Section V. T11RES1fOLD LIHIT VALUE 

### ACGIN, 1986-67* OSIIA PEL* Proprietary 0.1 mg/m 3 , 0.59 mg/m 3 6

reapirable reepirable Proprietary 0.5 mg/ma i mg/m 3 Propcietary 0.5 mg/m 3 0.5 mg/m 3 

### Proprietary 

### 5 mg/m 3 0 15 mg/m 3



### reepirable *Unless otherwise noted, all values are reported as Time-Weighted Averages (TWA'3)1,' and total dust (particiilatea only).

~~ 

### • SECTION III -- PHYSICAL DATA 

### BOILING POINT Not applicable 

### HELTING POINT Not appliCable 

### SPECIFIC GRAVITY (1120=1) Not available 

### VAPOR PRESSURE Not applicable 

### V 

## A'POR DENSITY (Air=1) Not applicable 

## SOLUBILITY IN H 20 (% by Wt.) Insoluble

~ 

## VOLATILES BY VOLl1ME Not aliplicable E_V 

## APORATION RA1'E (Dutyl Acetate=l) Not applicable ' 

### APPEARANCE AND ODOR Fiiie yellow-buff pouder; odorless



### ' SECTION IV -- FIRE AND EXPLOSION DATA . Not a tire or explosion,hazard. 

### SECTION V-- 11EALTII 1LAZARD DATA 

## THRESIIOLD LIHIT VALUE (_TLV)/ PERHISSIBLE EXPOSURE LIHIT (P_EL) See Section II above. These valuea maynot be applicable ae the constituents are homogeneously and ionically interdiffused to form a cryatalline matrix of r itile. F~



# 3`~EfEfCTS UF 0VF.tif;Xrf)SUnF, 

### Eye cantect _ 

### cniiArn 1ritat inn. in eontact c:rusps irrftat-I.nre; ltching And allergic reactions are posqible. nIs al!tion rnnnem Irrllnl lt+rs rir the r.•wplratery trnct anol mINy cnuee 

### dl.eabling, progressiva prrlmonnry fibrosis due to .the free cluartz silica. 

### Symptoms incllide cough, dyspnea, wheezing, and impairment of pulmonary functioh. Progression of symptoms can continue efter dust exposure ceasea. 

### In es g tion is harmEul. 

### Note : AlthouRh indastriAl handling of this product has been good, the toxicological properties have not been flllly investigated. Chr 

### onic : Chromium and certain compounds have been lieted at+ carcinogenic, both in'animals and humnns by'the National Toxicology Program (NTP) and the International Agency for Research an Cancer (IARC). Some Cr (VZ) compounds 

### are identi(ied as lurig ctrrinogens by toxicological studies. F,vidence of Cr(III) comporind carclnogenicity in animale and hrAmens ie inconclusive. This product contains Cr (II1). 

### Chronic : Long ter+rt inhalati.on studfes indicate antimony oxide cauaee m+llignant lung tumors in lahoratory rats. 

### EltERGEN CY AND FIAST AID PROC 

### EDURES Eye end Skin cv_nt 

### ac t: [mmi-riintely Ei.ueh Pyee aith water to remove perticlea. Cell a 

# __.____.._.... physiciart if irritrtion develops. Wash skin with soap and water. Inhalation: Remove tn freah nir. IE breathing is difficult., give oxygen. Cail a physician. 

### — nATE: 09/23/86 --- SFCTION VI -- REACTIVITY DATA CODF: 54I-032 = v 

### DITI0N9 CONTRIBUTING T O INSTABILITY None expected AaCOMPATIBILIT4 None exl+ectetl 

### IlAZARDOUS DECOLIPOSITION PRODUC rS None expected. ` °— 

### - SFCTION VIL -- SPILL OR LEAK PROCF,DURES - - — 

### eTEPS TO BE TAKEN IN CASE MATERIAL is RELEASED OR SPILLED Contain spillage end scoop up or vacuum. Avoid dusting. Notification of the National ' F 

### • Reaponse Center (800/424-8802) may be reqisired. Refer to EPA. DOT and applicable atate nnd local reqltlations tor cur,rent response information. 

### It is recomnlended that each user establish a spill prevention r conttol and collntermeenure plen (SPCC). Slich plan ahould include procedures applicable to proper stor.nRe, control and clearr-up of spills, including reuse or dinposel as nppropriate (see wgqte dispos;rl methrir,l, iiclow). WASTE DISpOSAI. PIETIIUD Fecler:rl, st:ite anel local di.sposal laws and regulations will 

### determine theproper

~ 

### waRte riisposal procedure. A7,1 waste materials should be reviewed to determine tlle applicah.le haxards (testing may be necessary). Disposal reqrrirrments are dPpendent on tlle hnzar.d classifitation and will vary by Iocatiort and the type oE disposal selecterl. Some: aastp materials are amenable to recycle/reuse. - --" -- SECTiON VIII -- PROTECTIVE EQUIPMENT 

### VENTI L 

### ATION Ceneral•; local exliauat ventilation es necessary to control dust. PERSUNAL E'ROTECTIVE EQtI_IPNENT Cl i 

### emical goRgles.



# _.---- Gl.oves

A NIOSiI/MSiIA approvcd sespirator as necessary 

### Borly protection as necessary to prevent skin contact.

~ 

# ./
Vn7xQ 7H}Tf)4 al4efii QF—j-A—ttv T1,n71 7c-rtT~

----- --- SEC3'IUtV IX -- SPECIAL PRECAU

- tIONS 

### Avoid breathing dust

. Wash thoroughly 

### after hindllnR
. Avoid contact 

### with eye4, skin and clothing. Keep container closed. 

### Keep awsy from foocl and feed products. Use with adegitate ventitation.

-- - -- - - ~ ~ ~~~ ~~~ 

### ----- SFCTION X -- PF.RSONNF.L SANPLING PROCEDURE — ~ , 

### For metallic componenta: Refer to N10S11 Manual 4f Analytical Nethods, 3rd Edition, Volume 1, lletfioc! 7300. 

### Information pcesented lierein It

~ 

### s been compiled from sourcee considered to l)e dependableand is eccurate acod reliAble to the beet of our knowledge and belief but is not guaranteed to be eo. Slnce tonditions of use ere beyond our control, we make no warranties, 

### expreRsed or implied, except those that may be contained in our written contract of eale or acknowledgement. DATE; 09/23/H6 CODE: 541-032 " PRODUCT: L-6570 Ye11oW Body Stain
!

fip.,T T4,0717C-nT 1f"T1fQ RN?fflQ O1M'i

~ T

### F" - 

## Material Safety Data Sheet Substance Identification r ntity 

### : MANGANESE DIOXIDE cas # : 1313-13-9 , rade Names: 13rlckox, GranuSpeck

.. .. . . . . . Manufaclurer: The Prince Manufacturing Co. Emergency: Chemlrec One Prince Plaza 1-800A24-9300 Quincy, IL 62301 

### 217-222-8854 Component.s and Contaminants Chg r mlcal Name: 

### V 4 ,g,S 0 SZ§J-IA PEL AGGIfi TLV 

### Percent Manganese Compound ( as Mn) 7439-96-5 5 mg/O (C) 5 mg/m' (C) 51-55% Mn Iron Oxlde 1309-37-1 -- -- 1-5% Fe Z O, 

### Sllica. Crystalline Quartz (respirable) 14808-60-7 0.1 mglm 3 0.1 mglm' (TWA) 1-5% SiO z Aluminum Oxlde (non-Gbrous) (respirable fraction) 1344-28-1 5 mg/m' 5 mglm ~ (TWA) 1-7% AI 2 0 3 Barium Oxide 1304-28-5 --- --• 0,2-2% Ba0 

### Physicai Data 8olling Point: NA Speciflc Gravity (H a 0=1): 5.0 Vapor Pressure (mmlHg): NA Melting Point: 535° C Vapor Denstty (Air—fl: NA Evaporatlon Ftate (Butyl Acetate=l): NA Solubllity In Water: Insoluble Appearance and Odor: black to-brownish black, no odor 

## Fire and Explosion Hazard Data sh Pointt Not cornbUstlble ,.ammable Limlts: LEL NA UEL NA 

### ctinguishing Medla: Foarn, CO 2 , dry chemical or water. Qpecial Fire Pighting Procedures: In the event of fire, wear ftll) protective clothing and NIOSH-approved seif-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Unusual Fire and explosion hazards: Not combuslible, but substance is a slrong oxidizer and its heal of reaction with reducing agents or cornbustibies rnay cause ignition. 

### Increases the ftammability of any combustible substance. 

### Reactivity Data Stabllity: Stable under ordinary conditions of use and storage. T Conditions to avoid: Do not heat or grind In the presence of easily oxidizabie subslarices or organic matter. Incompatlbility (rnaterials to avoid): Easily oxidizable substances, sulfur, suifides, phospliides, hydrophosphides, chlorates, peroxides, aluminum powder, rubidium acetylide, potassiur'n azide, chiorine triCluoride. Reacts with Itydrochloric acid lo form corrosive chlorine gas. Hazardous Decomposition or Byproducts: Upon heating it decomposes to form manganese sesquioxide and oxygen which facilitates combustion. Hazardous Polymerizatfon: Vlfill not occur. 

## Health Hazard Data Route of f=ntry: INHALATION: May Irritate the respiratory tract. May increase the incidence of upper respiratory infections (pneumonia). Prolonged exposure to silica dusl may result in siticosis, a ribrotic lung disease. SKIN: May cause irritation.

, INGESTION: May cause abdominal pain and nausea. Manganese

dioxide dust Is poorl absorbed through lhe gut. 

# 07 Manganese Dioxidi, Pop: t 1zeYiewed Juiy 1996 Unchangcd sincc Julv 1+>, ~

### Health Hazard Data

i Hazards (Acute and Chronlc): Chronic exposure and inhalalion of excessive manganese dust may cause disorders of the central nervous system. inogenicity: NTP: No IARC Monographs: Yes (Silica) Signs and Symptoms of Exposure: Early symptoms of manganese loxicity include sluggishriess, sleepiness. and weakness in legs. Syrnptoms of silicosis include impaired pulmonary function and wheezing. Aggravation of Pre-exlsting Conditlons: Persons with Pmpaired respiratory function may be more susceptible to the effecl of this substance. Emergency and Flrst Aid Procedures: IF INHALED, remove to fresh'air and seek medical altenlion for any breathing difficulty, IN CASE OF SKIN CONTACT, wash with soap & waler. Seek medical altention If red 8 irritated. IN CASE OF EYE CONTACT, flush eyes immediately wilh water for at leasl 15 minutes. Seek medical atlenlibn If irritatfon persists. IF INGESTED, induce vomiting irnmedialely by giving two glasses of water and sticking ftnger down lhroat. Never give anylhing by nioulh to an unconscious person. Call a physician immediately. 

### Precautions for Safe Handling and Use Material Release or Splll Precautlons: Should a spill occur, ventilate area. Clean-up personnel require respiralory proteclion. Recover unconlamEnated material for use. Vacuum or sweep 

### remaining malerial, keeping dust to a minimum. Isolate wet material from dry and store away from combuslibie materials. • Waste Dlsposal Method: Dispose of unreciaimable material In a-RCRA-approved waste facility. 

### Handling and Storing Precautions: Manganese dioxide is classifred as an oxidizer and should be stored in a dry place away from combUsilibes and sources of high heal. Protect conlainers from damage and keep closed when not in use. o

. l► —c Precautlons: Obserye ood personal hygiene. Wash after handling, 

### Control Measures Respiralory Protectlon: Use NIOSH approved particulate respirator if dust generalion occurs or is anlicipaled. OSHA standard 1910.134 or ANSI Z86.2-1980 specifications are recommended. Ventilation: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limils. Local e
- •:hausl is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it inlo lhe general work area. Please refer to the ACGIH document, "Industrial Ventilalion, A Manual of Recommended Practices', most recenl edilion, for delails. Protective Gloves: Yes Eye Protection: Safety goggles are recommended. Other Protective Clothing or Equlpment: Use olher prolective equipment when necessary in order lo avoid prolonged exposure lo skin. Work and Hygienic Practices: Observe good personal hygiene. Wash after liandling. 

### SARA Titte III Section 313 Supplier Notification 'rhis product contains the following loxic chemicals subJect lo the reporting requiremenls of section 313 of lhe Emergency Planning and Communily Rlght-to-Know Act of 1986 and of 40 CFR 372.45: Corroonent CAS # % by Weiglit Manganese Dioxide 1313-13-9 51-55% Mn Barium Oxide 1304-28-5 0.1-1.6% [3a T,. nformalion must be Included In all MSDS's thal are copied and dislributed for lhis material.



## ~ ' Mhun6aocsc Uioxid.. t'agc Z
n ~ , s - L ^ ~ ~^ ~ - lirei ~w~ d hJv In

~ R_ Iln ~l~~ nurrl cinrr lul

~ ' I

~~ G _APR-el2-1 ~9~ 12:51 BUR(-1L BRiCKS J 334 480 2415 P.02/03

. ~ 

### TEXAS AIR CONTROL BOARD LABORATORX 6330 Nighway 290 Easti Austin, Texas 78723 .•t+;j
ACL Number: 3491 Status: complete Priority: standard Property Sampled: Henderson Clay Products, Inc. Addres,: P. 0. Hox 1129 Henderson, Texa3 75653' City: Marshall County: Harriaon Region: 12 Sampled by: George F. Daugherty Date Samplea: 4-18-84 Adjacent Sources: no Number ot samples: 7 Number of reference aaMples or blanks: 0 Analy3i9 ReQuested: total fluorides, total sulfur in weight percent Number of 9amp1e3 received: 7 Date ReceYved: 4-27-84 Number of reference samples or bianks received: 0 Conditfon: o.k. Assigned to: Vince Anselmo As9igned Qy: John Key Analyais to be performed: total fluorides d: total.suifur percent 

### If transferred between sectiona, Date Tranaferred: By: To: Date Analysi9 Completed• 07-

~ 

### 03-8Y { !,` Analysis Per!'ormed by: Juan J. Rios and Nilliatt White ~ 

### ' 

## _~~ ~ I 

### ' 

## ,~ . . 

### Date Reported: ,



### 07-11-8 4
~ 

## / "^~''~ 

### Approved by: Maxine Jenka e ~ 

### Deacription of Samplea: 5 plastic baga- c wi inside label as fo lows: 1. white clay from Bell Cutoff Rd, pit 2; white sand from Bell Cutoff Rd: pit 3. red clay from Macadonia Rd. pit u: iron oxide sand from Macadonia Rd. pit S. broken grog (fired brick) 2 formed bricka 1. one fir• ,

ed (t'inished) brick 

### 2; one green (unt'ired) brick

Nhy were the samplea taken? 11hat do you hope to learn?: we are trying to learn 

### amount of fluoride and sulfur in the materiala in order to estimate pooaible emis9ions when brieks are rired in kilns. A190 need to know which raw raaterials may have the awst tluoride & sulfur.

Hou uill the analytical results be used? What act3on is depepdent on these resuita?: there•i3 a permit pending for a new brick kiln at this plant.. Would be very u9erul to have an idea of possible emis9ions: it' significant, we may require stack sampling.

L~APR-02-1998 12:51 BORAL BRICKS 0 334 480 2415 P.03iO3 

### Laboratory Analysis 

### Procedure: The sample9 were heated at 105 degree9 centigrade un'til dry.

Sample9 yere crushed and eieved into 200 Mesh particles. A quantity of each sample tnat did not exceed one gram was placed in tared nickel crucibles. Ten mL of 5N sodium hydroxide was added. The crucibles were placed in an oven at 120 degrees Centigrade until the liquid evaporated. The crucibles were tnen placed in a£urnace and heated to 600' degrees centigrade and then cooled. The crucible content3 were taken into solution by adding 20 mL of distilled waCer and warming on a hot plate. 1'hree normal hydrochloric acid was added to bring the pH ot' the solution to 8-9. The solutiori was transferred to 100 mVpolypropylene volumetric flask and diluted to the mark with distilled water. The solution was filtered through dry Ulhatman No. 40 paper wnich removed interfering cations as insoluble oxides. A£luoride specific ion eleetrode wa9 used to determine the concentration of.the standard solutions and the unknowns. Precision was measured with auplicate samples and the recovery ot the procedure was tested using spiked solution. Results: Fiuoride Analyeis

Sample Micrograms fluoride/gram sample
01 white clay l"rom Bell Cuto£f Road pit 123 y2 white 9and trom 9e11 Cutort' Road pit' 109 

## a3 red clay !'rora Macadonia Road pit 190 u4 Lron oxide 9and t'rom Macadonia Road pit 226 #5 Droken grog (rired brick) 22

fired (finished) brick 16 

## green (unfired) brick 274
Precisiont 9% Recoverability: 104x 

### MDL: 7 micrograms fluoride/gram sample

Sulfur Analysie Procedure: The samples were pulverized, dried overnight ln a 50 degree Centi,grade oven and analyzed i'or sulfur with the LECO 132 Sulfur Determinator. The basis ot this.method is combustion at 2500 degree9 Fahrenheit in an oxygen atmosphere and measurement o£ the infrared absorption of the sulfur oxides produced. A thin layer of vanadium pentoxide was placed on top of the samples td premote combustion.

Sultur Analysis Result9: Sample Suirur Content D1 white clay From Bell Cutof£ Road p! t 0.1895 

### 02 white sand from Bell Cutot£ Road pit , n: d. ( none detected) 

### 03 red clay from Macadonia Road pit 0..233% ll++ 

### iron oxide sand from Macadonia Ri :ad pit 0:0115 M5 broken grog (fired brick) n: d.



## fired (tinished) brick n, d,. 

### green (unfired) brick 0.123% 

### minimum detection limit is .oiox sul£ur precision Is 4%



# ~~ Tf1TAI P M

# iGPCrla` ~ 

# !Z

A CC,vutuT N0. lf H- 00t $-3

STACK EMISSIONS SURVEY BORAL HENDERSON CLAY PRODUCTS MARSHALL BRICK PLANT MARSHALL, TEXAS JUNE 1986



# ~ 

# eCvuKT 90 .

4'' 

# ~"- ° ~~=~' ~

FILE NUMBER 8660-607

Prepared By: Western Environmental Services and Testing, Inc.

P.O. Box 7513 Beaumont, Texas 77706 

### (409) 899-4515

### SUMMARY OF RESULTS Kiln Stack Fluoride Test Runs

Run Number 4 6 7 'Stack Flow Rate - ACFM 12993 13179 13173 Stack Flow Rate - DSCFM* 7110 7171 7161 X Water Vapor -% Volume 11.49 11.44 11.69 x CO Z - X Volume 3.0 2.5 2.5 % 0 2 - X Volume 16.0 15.8 15.8 z Excess Air At Sampling Poiat 293 270 270 Particulates Probe,Cqclone & Filter Gatch (Can) 

### grains/dscf* ---- :A - 

### ----- ----- grains/cf

- at Stack Conditions (C a t) 

### lbs/hr (C aw ) ---- ----- ---- Total Catch (C ) graias/dscf* aa ----- ----- ----- graias/cf at Stack Conditions (Cau) ----- ---° °-- 

### Ibs/hr (Cax) ---- ----- -----

* 68°F., 29.92 "Hg (20 ° C., 760 mm Hg) 

### 8660-607 -4-

`?" ~

### SUrIlKARY OF RESULTS Kiln Stack

Fluorides
Run 4 Run 6 Run 7 Impinger #1 (mg) 42.63 39.46 38.43 Impinger #2 (mg) 5.55 7.10 6.75 Total (mg) 48.18 46.56 45.18 Total lbs/hr 4.36 4.25 4.06

8660-607 -5- , ! 

## v?r~'.~ 

# .,._ , ~ 

# '^'

~ 

# _. ~ 

# ---, ---- ~ 

# — — r_ , r~.~ —~ 

# • -"

~ 

# ":

~ 

# _:

~ 

# .. ~ 

# "-°,',`_

~ 

# ,. .

- ~ , ,~ ..y. .. ~ - _ ~ -~ . _ . ,. . :• F . ~~

'.

~ . .~~~ I-.

~~~ ~s i-

~ s t~ • _ y , .~ - t

_

~ . ~ - • . [^ ~ . 

# EPA iVIACT Information Collection



# Request Response

_ . .. .-....,,~._-::•:F~:y-'s.~t,,, - .. ~~ 

### _. ~ 

### , . _ . ~ `~ 

### - _• . ~

i ~ , ~

_ ~±~~'~ _'~. ~ 

### .+-.'+ ~.-~ 

### _ _ ~ y • ~ '.+~x_ ~ ~



### _ .. ~ 

### • • ~ i I

.~ - -. . __. ~ _ t -_ ~~ . "- _-- - ~ - - ,

. :A r '

_ ✓ ~ a. .: .+, - -

~ . ~_,~'~~. a .~n T ~ 

### _ -.r ~► 

### _ ... Fi t ~~ +~-~ 

### • • •



### ,. ~ 

### . -..•v , { , ~~ +f.

__ . ~ ' ~ _ -_ – .



### _

—T--- ='_±f

• .- ~ J!51 ~~~; .,a ~•~a ~

— –` '

~ - •~~.a~ , y

~ . ~ - - ' 

### ~ i 4 ,. 

### ~ -= ~

-- ._-- .. .. .. -. . .- . . ~ :r!. ~ r --..`

_ _ -_

~ :-
_ - ,•, i ~ i v ~ , ~ • - _ - ; , .e• ~ :... . z ; -. ~ . _ .. - ~ Sa_ ~4

~ .,,y ~ b-. . . ~ • _, _ . - . _ .

~ ~ y 1

~ _ e '°..
. _ ~ ~-~ . _.. ~ y-- , .. ~ .M1

_ ~ ••
_ . . _-. ~ . - .. .. _ _ . - _ ' ~ ~ ~ ~ 'u`u:'s:C.' -. : • ~ , : ~ ~

ti..

ti

# MACT Information Collection Request Response from Boral Bricks, Inc.
Table of Contents • Information Collection Request • Appendiz A - MSDS's • Appendiz B - Test Data

)1S

### Enclosure 2
INFORMATION REQUEST FOR BRICK AND

STRUCTURAL CLAY PRODUCTS MANU F':it:TURING OPERATIONS I. Instructions Please return the completed information request to: Bruce C. Jordan, Director Attn: Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 If you need

~ 

### ; tarification of any question or item, please contact Mr. Bill Neuffer of EPA at (919) 541-5435. 

### This information request should be completed for each facility that manufactures brick and structural clay products, including facilities that are not major sources. Information is requested for all processes at your plant that emit hazardous air pollutants (HAP's), including those processes that are not associated with brick and structural clay products manufacturing. Sections II through VII request information specific to brick and structural clay products manufacturing, and Section VIII requests information on emissions of HAP's from other processes located at the facility. Processes that may emit HAP's include those processes that use or handle any materials that contain a HAP compound, all processes with elevated temperatures, and all other processes in which HAP compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is included as Attachment 1 to this information request. Attachment 2 provides background information on the requirements of the Cle

~ 

### = Air Act and explains how the information requested in this questionnaire will be used EPA. Attachment 3 is a list of abbreviations and acronyrns used in this information request. Several tables are provided throughout the information request for your convenience in answering the questions. An example response is given (shaded first colummm or row) in each table. If additional space is needed to respond, please make copies of applicable pages. If necessary, please make copies of this information request for additional facilities. No additional emission testing or monitoring is required to respond to this request. II. General Facility Information A. Name of company Boral Bricks, Inc. Name of facility Phenix City, Plants 1 and 2

Page 1 of 30 

# Wb

### Facility address: No. and street 100 Brickyard Road, Plant 1 City Phenix City State Alabama Zip 36865 Latitude and longitude coordinates of plant: Lat 

# M 32°24'3.88" . Long (W) 85°00' 12.88" Standard Industrial Classification (SIC) Code(s) of brick and structural clay products manufacturing operations 3251 Dun and Bradstreet No. 00-327-5682 Total No. of employees for company > 1,500 for facility 74 (If facility is a foreign subsidiary or if compa.ny has foreign subsidiaries, include number of employees not based in the U.S.). Please complete the following shift information for the facility: Shift No. of employees Hours per shift Days per year 1 38 (manufacturing, main- 8- 12 359

tenance, etc ... ) 

### 1 Kiln Fireman g 365 2 33 (manufacturing, main- 8- 12 359

tenance, etc ... ) 

### 1 Kiln Fireman 8 365 3 1 Kiln Fireman 8 365
B. Respondent name Andrew S.R. Wichers Respondent title Regional Safety Manager Respondent address (if different firom above) and telephone number: No. and street P.O. Box 1178 City Columbus State GA Zip 31902-1178 Telephone No. (334) 480-2407 Name and telephone number of technical contact person (if different from above) Name David Johnson Telephone No. (334) 480-2487
Page 2 of 30 

# 47

### III. Informa.tion on Operating Permits and Applicable Federal Emission Standards

A. Please provide copies of relevant parts of all operating permits and permit applications for your facility. Relevant parts include the sections that provide specific information and data on: processes that emit HAP's; the use of HAP- containing substances; emission levels for HAP and surrogate pollutants (i.e., VOC for organic HAP's and PM for metal and other particulate HAP's); emission control device design and operation; monitoring and operation and maintenance (O&M) procedures for control devices; and generation and releases of other media such as wastewater and solid waste that are associated with the operation of air pollution controls for brick and structural clay products manufacturing processes. If the operating permit or application contains the same 3- , . formation requested in any part of this questionnaire, you may respond to the requested information by referencing the page or section of the permit/application to avoid duplication. Ifyou reference your permit or application, you must supplement your response with all of the additional information requested in this questionnaire that is not included in the permit or permit application. If you prefer, you may submit the requested information from your permit/application on a 3-1/2 inch di.skette. B. If any source or emission unit at this facility is subject to a New Source Performance Standard or other Federal emission standard, please identify the source and applicable standard. Examples of applicable NSPS include 40 CFR 60, Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers in Mineral Industries. 40 CFR 60 Subpart 00060.670-60-676 Standards of Performance for non-metallic mineral processing_alant => all belt conveyors. 40 CFR 82 Subpart F 82.150-82.166 Recycling and Emissions Reduction => Refrigerators and Air conditioners. IV. Brick and Structural Clav Products Production and Raw Material Consumption Information A. Please provide the 1996 production rates and the current production capacity for each type of brick and structural clay product manufactured (e.g., structural brick, clay sewer pipes, structural clay tile, etc.). Note that production data should be provided in units of tons per year (tons/yr). Product 1996 pre>: +.::.tion (tons) Production capacity (tons/yr) Face Brick (fired weight) 10'

~ 

### 7 133,361 Page 3 of 30 

# 61?

### B. Please provide the type and amount of each raw material and body additive used in 1996 for manufacturing brick and structural clay products at your facility. Examples include clays, shale, and any additives that are mixed into the raw material prior to forming. Indicate additives by chemical compound, rather than by trade name. If the information requested is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. Raw materiaUbody additive Amount used in 1996 (tons/yr) Calcium Lignosolfulnate 106 (wet weight) Manganese, 325 Mesh 7(Dry Weight) Ochre 548 69 (Dry Weight) Hallmark Fireclay 1,200 (Wet Weight) Kaolin, Eufaula 45 (Wet Weight) Rome Shale 13,390 (Wet Weight) Clay (mined locally) 109,300 (Wet Weight)

C. If available, please provide a copy of the MSDS's for the raw materials and additives listed above. See Appendiz A D. If available, please provide chemical analyses, including fluorine, metals, and organic content, of the raw materials listed above. See Appendiz B

Page 4 of 30



## ~~

### E. Using Table 1, 

### please provide information on the consumption and HAP composition of all glazes and colorants that contain HAP's or HAP precursors and that your facility applies to brick and structural clay products. Indicate whether the coatings are glazes or colorants. Also indicate the type of product that the coatings are applied to and the total weight of coatings used in 1996. If the glazes or colorants are formulated at your facility indicate so and provide the production capacity. List each ingredient of the glaze or colorant. Beside each ingredient, indicate the total amount of the ingredient used in 1996. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. F. In the space below, please indicate any glazes or colorants used by your facility that do not contain HAP's and are substitutes for HAP-containing glazes or colorants used by your industry. Indicate which HAP-containing materials the non-HAP glazes or colorants replace. Describe any limitations on the use of those substitute glazes or colorants. NONE

G. If your facility colors brick and structural clay products by flashing, please indicate the types of substances used to flash the products and the amounts of those substances used in 1996. Substance Amount used in 1996 Units Mecify) Natural Gas Unknown — Not Measured Not applicable Propane Gas (,backup fuel) Unknown — Not Measured Not applicable
H. If available, please provide a copy of the MSDS's for the glazes and colorants used by your facility. If your facility prepares its own glaze, please provide any available MSDS's for the glaze ingredients. See Appendiz A



### Page 5 of 30 

# wo

# I Type (e.g., glaze, colorant)

Type of product glazed or colored 1996 consumption (tons/yr) 

# I Produced at facility? (yes/no) 

# I Production capacity (tons/yr) Total usage (weight) of each ingredient (that is a HAP, contains a HAP, or is a HAP precursor) in 1996 Coatings/Coiorants
Brick

957
No
N/A 

# I Tota11996 Ingredient usage, tons
Gleason ball clay 8.55 Green chromium 0.44 oxide Ochre 548 dark 68.88 Manganese 6.89 Zinc oxide 7.30 TABLE 1. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND COLORANTS

Page 6 of 30 

# J1

### V. Description of Brick and Structural Clay Product Manufacturing Processes

A. Please provide a simple process flow diagram for each brick and structural clay product nianufacturing process line. An example process flow diagram is provided in Figure 1. A diagram of the plant layout with all processes and emission points clearly labeled is also acceptable. Assign a unique identification number (ID No.) for each process that has associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. 

### Please identify all emission points, including those that do not emit HAP's. For emission points that are vented to an air poflution control device (APCD), assign an ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information request for any responses that pertain to any process or emission point.



### Page 7 of 30
5--2-N ~ 

### 3 y LJJ C C C n
~ ~ 1a ~ ------ ~ ~ ~ ~ 

### W LL. X liOaUn W 

## C E

~ 

# S o~ 2 

# N_
y

~ ~ 3 a ~ Clq

Q li (Q (O Q

O 

### 2 ' C14 o Ch 0

~ a~ 

### v a~ 

## Li c 

### 0 Q



# a • ~ y ;• y ~

r r C ~ 

### U



# _ ~ 

# S,`

p ~ 

# ~ Ay 

# ~ m d 

# ~ Y IL ~ a3 v

~ U

C~ 40 

### ~ y ~ ~ ~ v m y 

## m O 

## ~ z a ~ tE y >. O T U ~ ~ 

# °? t4 ~ t x LL W ~

~ 

# v r 

# m .0 C E a Y ~ t
a~~ ~ L.

~
~ ~ ~ O 

# 3 N ^ ~.+ ~Q ~
L +' ~ 

## c A Q' 

# w ~ Vj ... v~ c
L 

## a~ u

~ L
~ L 

### C M ~ 0 M 4-. ~ 00

~ CL. 0 

# N



# I

~ 

# l r

c~

~ 

### Y c~ c F

~ -


# r vl 

### O c O 2



# 5

- 3

# .-.

. ~ 

### u

~ 

## L

~
~ ~

... rr C~ L O 

### u a~ A 

## v C

~ O 

# G. o
~ 

# c, s ~ ~ ~ a ~ 

# 'u a~ a ~ `..

~ ~ 

# '"

~ +' ~ C bD ~ :

~ 

# a A y 

# 3 a
o ~ a ~ 

# _ ri, a H ~ 

### y y "'

~ 

# U
s~ 

### , re 

# a '"a
~ s 

# a
~

~ ~

.., L ~

... ~ L O ~

~~

### B. Using 

### Tables 2A 

### and 213, please provide current production rates, production capacities, and related information for each type of equipment used in brick and structural clay product manufacturing. In Table 2A, provide the requested information for only those sources that are known or expected to emit HAP's. In Table 213, provide the requested information for all thermal processing, such as drying and firing sources. For combustion sources that use different fuels, Table 2B should be completed for each type of fuel. For example, if a kiln typically is fired with gas, but periodically is fired with oil, one column in Table 2B should be completed for the kiln when fired with gas, and another column should be completed for the same kiln when fired with oil. Provide the data in the units listed for each row.

Page 10 of 30 

# ,5str Q ~ G.

~ {~. .~ Y
~ Q U y .~

~ A
~ s 4.I

~ Q~

~ ~ ~ ~ 

# 0 

# u cko

CA ~ ~ ~

G V c~

•~ t Q ~ H

x
~ Y • ~ o C ~
~ y Q o ~ a ~ y y

Y ~ a a ~ N ca ~ 

# QY g U O ~
En s- ~ 

## w~ a~ 0 ~o .~ .~ 

# a w p, .G o H 

# b ' _T

0.. c U as vC M 4.i O

~--~ a~

~ 

## a

Q N 

# a

~ 

# H ~ U

a~

~ V] C'n S. ¢ S 1~ . U i .~ 3 U C ~ N [S:7 Cn

w -o

C ~

c



### - 1 j 9 '8 ~ 

### U

v~i m~vi~ v~ ~ 3 ~ v w v~i ~ W ~

~ Q (Q ' 4d W ~ •~ ~ (O ~ '~ ~/
~ ~ 0 cn f , r , i ' U ~ 'Q ~ 

### t, •
~ ~ Q~ ir U7 ~ 

### V C
~ 

### Q

~ ~ •" •D C~ U C V ~ y 

# W a u

° ci~ v

3~ i

~ U i C 

## .0 3 UU

~ -



### _ . y ~ 

### _ F"! ;8 

# . - 

# . .::.._

, 

# .-.
~ 

# . _. .. - --- - .,:.: - - - - =-

~~ 

# .._:.:.

~ 

# _,...=:

~ 

# := - - -

- - ~ 

# - - z 

### ,.. . - ~ L



# n .

~ ~

~ 

### nz 

# . ~ 

# _.:.: ................:-:. w. 

### W 

# . ... .. .. --•_- _

- ......_._._.:_. - - - - -

_ _.. . _ _ _ ,::.:..

W . 

### . . _ 

### _.: _._:_. . ._ _:._:•.,.:.:v_

. .. .. . _......__......,__


### .... . ~ 

### ,... ~ e 

### .... .. .. ... ..._ .,.z+

~~ 

### _....._...,;. ~s~~~ 

### _:,.

~ 

### '.

_ _.::_.. . . ~ ......_ ...... ::.....:... 

### - _

.::

~ .: : - -



### .. . .. _ . . _ _ - - -

~ 

### - _ _ -: ... U 

## o 

## z

~ ~ ~



### 4 

# o m Q 

# a, 

# z 1 6 

# B z

~ .: C E~ Q G c
~ : 

# N

### a ~
Y w ~ ~ ~° .cn Q Q • ~ Y

m ~ ~ 

## a 

# _.

H - -- - .--i

~ 

### v 

# z N 4-
Y `¢ • a M

~ Y Q~ ~ ~•d ad Y a

1V

, 

## , .....: F ~ ~ 

# .-.

. _._ ........... .... ._ 

### , :. . Q _ . - - :..:....: ....,.

_ - ..... _. . :. .-: ~ .:.. . .



### H 

# w o ~



# ° Y' G c ~ °o

aci c 

## d p, A

~ 

### o v 

### PA a~ ~ 

### . 

# z

° o

~ ~ 

## , y

~ A— V F ~r C~ y 0.Y ~.,~ •~

~ 

# - a,

~ •s a 

### , • a . ~ ~. SZ~ 3 ~


### ~ ~U w c

p , • 

# v A
~ ~ x oc~ ~

~~ o~ 0 o • ~

06 C ~ 

### on ~ .r c ~ w a ~ a 0

~ 

## >,

~

~ Y

• ~ Y I ~ 

## z z cn cn 

## a

ON 

### cz N z 3.0 Z co z 

### U c~ ar ~ O ~
~ b 

### N
~ cC

~ 0 U y 

### .n .c

.~ .~ 

## +. ...

. b o U ~

Q' F (U r ~

~ 4-4 ~~

4 

## - o 0

~ 

## a o C n ,o 0 •a V U y U U y

~ ~ ~ a
~

~



# ~ >, a.

~ y ~ 0 U ~, • O

•~ -~

CZ ~ G ~ O M f4- 0 

# N_

~ LV cs.



## J-7

## NOTE 1

Except as otherwise indicated, Boral Bricks does not possess process-specific data that would allow estimates to be niade of the types or quantities of HAPs contained in the materials or of the resulting HAP emissions. Sections 10.5, 11.3 and 11.19.1 of AP42 provide generally available information on the pollutants that may be emitted Srom sawdust dryers, clay products processes and sand and gravel processes respectively.11w AP42 data are considered indicative of the types of I-iAPs that M be emitted from processes at this plant but are not considered indicative of the quantities of HAPs emitted. 

## NOTE 2 Fugitive emissions occur at several points throughout this plant. Boral Bricks has no data on these emissions, and is not including fugitive 

## sources per Feb. 25, 1998 telephone conversation between 011ie Fick (Consultant to Boral Bricks) and Bill Neuffer of the EPA. C. Using Table 3, 

## please provide information on procedures used to monitor the process operating rate for each of the pieces of equipment and HAP emission sources listed in Tables 2A and 2B. Use the same HAP emission source types and equipment ID numbers you listed in Tables 2A to 2B. .

• Indicate whether you monitor process rate 

## or not.
• Provide a summary of process rate monitoring procedures that 

## describes how process rate is measured for the particular piece of equipment. Include where 

## the 'rate is monitored (i.e., rate of material fed, rate of material discharged, or material production rate), the units used to measure process rate (e.g., lb/hr or pieces/hr), and how the process data is recorded, i.e., 

## manually, automatically (e.g., computer - printout or stored to disk, or not at all). If you monitor process rate at both the feed and discharge ends of the equipment, indicate so. Indicate the type of monitor, equipment, or instrument used 

## to measure process operating rate.

• Indicate the ::: aitoring frequency or 

## how often process rate measurerr.::::; ;, are made.

• If instruments are used to measure process throughput, indicate in the monitor accuracy column the accuracy of the instrument. The monitor 

## accuracy could be listed in terms of a percentage of the throughput (f 

## 1 percent), mass per unit time (f2 lb/hr), number of pieces per unit time (f 

## 10 pieces/hr), or other appropriate units.

• Indicate th. -quency that the monitor is calibrated.

• Provide da % the units listed for each row.

Page 13 of 30 3—r

### ~ ~ .ri

~ .~ C O U 

### .~

~

~ s
~

~
~
C 

# 'ro

~ 

### ~ Y a~ 

# C_

~ 

# O s ~ Y

~ 4+ ~ 

# a ~

E ~ U ~ ~ 

## o y

a~ 0 0 C
~ • i U + N y 

### ~ U s ... 

## 8 u g r , ~ 

### $' c ~ O ~ y ~

7.r ~ W >
~ T ~ O ~ o ~ '~ p 

### 5 .~ O ~ 

## .5 0 y b •' .+ ~ 

## . 4. ~ 

## n. 

# s 0

. O U 

### N A

~ 

## a

~
rA 

# v 0 

### Q A O
b ~
~ O

M

~ 

## 0

~

c~ 

### a

M W
~

~ L l~ 

### 0 y
•C y 6
z eo z ca ~ 

# a z as



### ~ f =

~:;~ 

# _:_=-=_': •.. o

~ '~ 

## C •..~ 

## C c

E." ' ~
_ ,:: ~ - 3 t '-=':;: = 7j • ~~• ~ ~ ~ 7

Vl C/] vl

•D 41 

# °_:

~ 

# _ ,.

~ 

# _ : :_

-~ ~ f/1 

# .,a ° r/

~ ~ ~ .a ~ 

# . +

• ~ ~ ~~'-T - ~ • ~+ ~ ~ ~ 1+ L+ 0

. 6. C =- ' 

### ~: : 

### _~ ~ .+ ... 

### ~ .~C O ~ •ar c~

~ . '



### ~ G s ~

0 a. - 

### ~ U ~ ++ 

# c

• ~
4 ~ 

### o y yy cn O 

### o • :~~-~ c v~i a~~ 

## 3 o w ~ e~~i

~~ 

## :.: a ~ 

## o>a'v ~ 

## os°'

~ .: y i

2 F f

- + _ ~ + Fr a+ •-y, U a' •

~ , a+ ..r N -: ~~ - ~ f ~ ~ ~ ~~_W ~ ~ • `. ~ V
~ a~ a'Ay

~ = =

~



### az a+ ~

-VK ' T 

### ~ 

## ... - a c

~ ~ C ~ ~

~ 5 ~ ~

~ ~ ~ ~ rA E ~ 0

'A ` ri ri~ U v~ ~ 

# _[i p ,I



## 5--1

### VI. Identification of Brick and Structural Clay Product Manufacturing Emission Points

A. Use the process flow diagrams developed for your facility and Table 4 

### to provide the following information for each HAP emission source at your facility. • Define HAP emission source type 

### in terms of equipment, such as dryers, kilns, etc. As in the process flow diagram, you may group multiple pieces of similar equipment. • Use the same equipment ID numbers indicated on the process flow diagram(s). • If th , s emission source vents inside a building or to outside ambient air without firs: passing through a control device, place a check mark in the uncontrolled column. • If the emi.ssion source vents inside a building or to outside ambient air after passing through a fabric filter, dry injection fabric filter, or scrubber, place the APCD ID number(s) in the column corresponding to the APCD type. • If the emission source vents through a control device type not listed in Table 4, indicate the control device type in the other control column and place the APCD ID number in the appropriate cell. • In the emission test data column, place a"yes" or "no" in the appropriate cell to indicate whether the specific source has been tested for any pollutants, including any HAP's, VOC, PM, or opacity.

Page 15 of 30 

# WN71i

~ 

### w a

~ 

## z E 

# o~

~ 

### E ~ t 

## a t

'' a E 

# a; rx t

~ ~

~ 

## t w ~ U~



# ~ t c 

# Oi
z~ 

# o ' ~

~



## ~ /~ 1~ 4 

### 0 `

I ~ tiz 

### j, U 

### Z~ O~~, Z Z 7

— 

### Z Z

~ ^ • ~ H

~ C O

r o
~ U y

. ;.;_'.:; :

~
O' l ~

~ . L4

w

~ 

### - > -

-

. .. ....... :- 

## ~ I. 

## ~ y ..:..: ... . ::.. . .... ~~ : .. -



## x x x _` - "a%v

~ ; Y

- o

- J y _yv5' •~ i s '~

_ ':f::d ~ '=T

rA 

### .:.: .. ...,_. . ;. CD M 14- C

~

~ ~ 

# a

~O ~

### B. Using Table 5, 

### please provide information on stack parameters and emission estimates for each emission point at your facility that is known or expected to emit HAP's. Provide information for all APCD's, including those that exhaust inside the building. Include data for each inlet and outlet, if available, as indicated in the table. If you have more than one inlet to an APCD, provide data for each of the inlets. Provide data in the units listed for each row. Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal HAP's or VOC for organic HAP's. Emission estimates may consist of measurements reported in emission test reports or may be calculated using mass balances, emission factors, engineering judgement, or other estimation methods. Provide the emission estimates as emission factors in units of lb of pollutant emitted per ton of product (lb/ton). Provide complete copies of any emission test reports or other reports that document measurements of emissions. 

### Test reports and other emission measurement documents should include the following information: process identification; location of sampling point; stack diameter, temperature, and flow rate; test method, including analytical procedures; number of test runs; emission concentration, emission rate, percent oxygen, and percent moisture for each test run; process operating rate; type of APCD; and APCD operating parameters. However, test reports with incomplete documentation may still be useful and should also be submitted. You do not need to fill out Table 5 for emission points that are covered by an emission test report that is included in your submittal. If emission test reports are not available, provide calculations that support your emission estimate, including the basis for all assumptions in the estimate. 

### Note that emission estimates are needed for all HAP's that the facility emits or has the potential to emit. (Please refer to the HAP list in Attachment 1.) If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 17 of 30 

## (o Z0 0 0 O

C-4

I

0

cn

00 0 0 

# I 

# ca I
r4 

### 7a

.... .. .. .. 

# -

-----

... ........



### 2 A

. 4J ,



# >

03 U ' 

### S as

rA

06 

### on



# a~ ~
~ a~ ~
~ ~

y
~

~ U 1
. 11
.. 7 O

~ T

C U 

## E ~ 4. O ~

~ y ! U a!

...

` n . E N vc c Co G N
~ ~ a~+ 

# N • a e

00 ~ z ~ y u 

### o Q `- ~ 

### Y z o ~ 

# 8
C II y c
'- 4 0 M 4-i O O~ .-.

~ b0 cC 0.

~ O ` ~Za 

# z (A z in CA 0 

### 8.1t cn rA W) tn 0 0 

# 0.

cd cn

O M 

# z

en

0 0 0 0 0

rn V3

00



### H . l

Z~ O 0 C>
04 9 m LO


## q 7 

## j j

G3

do t-z 06 C~



## lo~c R 4;

~ a~ s cc ~ 

### .€

~ 

### a a~ s ., w 0 cn 

### 0 ~Y

~ Q~ ~
~ .~ c~ N 

## s_

~ 

## c a ~ /r W ~ ~ ?. eo ~ ~ O ~ «~ .~

~ ~. 00 C .~

~ 

### 0 y

~ U w F,
~ O C 

### U' N ~

~ G O ~ y U 

### E N ^ N ~ N ~ G 

# z " 0 y ¢ ~ ' O ~ ~ a.+ C' i ~ • CO N 'O

~ 

### z .

~t~ O

M 4-. O r. N U CO cC 0. ~ ~ :. 0
~ u 

# t I =1=1

1

~ -1 

### O
~ y

~ 7

~ -1
~ U C
~ rn

+.r

~ 7 r~ .~ 

# w O .r

~ +r
~

~ U

~ O r.~



## ai ai w 

# ~ Q' y

~ ~ O •y ' O ~



# a. ~ 

### ~ 

# A .4A

~ . y i ~ y 

# yee ~ y~ 

# y

~



# C ~•~ ¢ ~= a0

a


# _ C a' 6 Ci ~

.. W G ~4~Z ~ CO — — 

# ° I I- I I ~ 

### W a 

# ~ F-~



# a

### C. Using Tables 6A through 61), 

### please provide design and operating data for each APCD

associated with all dryers, kilns, and any other brick and structural clay products manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of APCD's. Use Table 6D for other types of APCD's. When using Table 61), please specify the type of control device and 2 to 4 key design or operating parameters for the device. Provide data in the units listed for each row. If the information requested in Tables 6A through 6D is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the tables.

Page 22 of 30 07C R C `+ F.
~ C .+ R I.n F+
1.. ~ a
~ c ~ ~ 0
~ c 0 U N y N

~ C1. a ~ a~ ~ «, c~ c a~ ~i

.. a~ I.n T

~ C C ~ 0 T

~ 

### a 00 C cd ~ O . O y T
U
L ~ ~ T C _
~
cc b+ r Q i V y .~

.~ ~ y ~ ~ 

### c

' z ~..~ ~ r~ ~ 4; Q ~

• y ~ + Lti y C O

~~ OD

~ C

~ .— 7= C) M 4.r O M N O b0 as 0.

~ "'~ ~
, i

~

~ ~ : ~ ~
~

~ : i ~ 

## f.

.„
:s

. .., 

### : o 

## e cn

~ / W 

### W

~ ~ 

## w U 

## ~ ~ 

## w 

# z
~ H 

### U 

### ~ 

# z ~
~ 

## A C~ ~ 

### W
~ Q H c ~ s
~ a~ s Y cO ~ Y .~

~ a u s Y w 0 ~ e 0

. Y

~ y

0 M 

### w O ~ N

~ ~ 

### a



## &7

~ 

## F~ a

~ ~ ~ 

## u
~
~ 

### a 'u a ~ n

3 ~ ~ ~ ~ 3 ~
~ ~ ~ Y N L ' Y 

# C_

~ Y Ii^ ~

~

~ ~w 0 M 

### w O v'i N 0~ 4 c ~ 

## n,

~ ~ Y

~ s Y Y
~ O

~ .rn

~ .1. ~


# 20

### ~ ~ N

~ 00 c 1!~ ~ 

### W 

# U_

~ W 

### Ca W C pC

~ 

### Ci C.~ ~ 

### y a~ s ~ ca L a.+ .~ Q 4.)
0 y

~ .y 

### y N

.~

. O

~ RI al
t' . N 

# w

~ > ~ 8 ~ °> i 

### .~ C d C .~

~ C c u j?

~ 

### U w

~ C
~ d Cd U d ~ L

. 

### 0 Q O 

### z ~

~ 

### .~ 1 R ~ 6
a s

.

C 

### ~ 6


### ~ ~ o
N

a

~ 0



### M 4.. ~ O

~ D N (U b0 (Z 0.



# -21

### D. Using Table 

### 7, please provide the following information on current monitoring procedures for each of the control devices listed in Tables 6A to 6D: parameters monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices 

### used (e.g., differential pressure transducer, thermocouple), and recordkeeping practices 

### (e.g., manually recorded in log book, continuously recorded by electronic data acquisition system). Describe briefly other operation and maintenance (O&M) procedures for each control device. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table. VII. Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing

### A. Please describe afl pollution prevention practices (i.e., process modifications, such as reuse of discarded or rejected materials, or any practice that prevents or reduces the amount of air emissions, or the generation and release of solid waste or wastewater associated with the operation of air pollution controls). If the information requested here is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. Pollution Prevention Practices: This facilty: 1 Recycles waste heat from the kiln to heat the dryers and to a lesser de e g_ r e, the holding rooms. 2 Recycles floor sweeyings and scrap/waste clay into the brick body: 3. Recycles green brick into the body. 4 Recycles off spec brick (grog) into the brick body. 5. Recycles sand coating into the brick body. 6. Recycles wash water into the body.



### Page 27 of 30 

# 7z~

~ ~ 

# a a F ti

~ cd a~ s 3 O 00 C C:.

0 M 4-~ C 00 N N bA cz 

## a.



# '23

### VIII. 

### Information on Processes Other Than Brick and Structural Clay Products Manufacturing

Processes A. Using 

### Table 8, please identify all other processes or operations at this facility that are not addressed in Items II through VII above and that are potential sources of HAP emissions. Estimate total annual emissions of each HAP emitted by these collocated processes. If the information requested in the table is contained in your facility's operating permit, you ma.y reference the applicable sections of the permit rather than filling out the table.

Page 29 of 30 

# 7V

### TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCES

Process/enussion source/SIC Code(s) HA.P's emitted Estiniated annual emissions, tons

### EXAMPLE: MiningSIC trace metals (Cr, Mn, Ni compou nds) 0.2

Concrete block plant (Plant 2): A concrete block plant is located on this plant site and is owned and operated by Boral Bricks. Boral has no emissions data on this process.



### SIC 3271 No Data No Data

Quality testing lab in support of brick nmanufacturing: A small quality control testing laboratory operation takes place at this plant but is not otherwise identified or reported in this ICR because there are no emissions data available.



## SIC 3251 No Data No Data



## SIC

SIC If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.
Page 30 of 30 

## 7~

### h,Saferlal Safety Dala Sheet

May b1 used 10 CaMply wit11 OS}{A's Hazard Cocnrnunk - atlon Standard, 29 CFFi 1910.1200. Standard musl bo consulted lor 3peclflc rtaqultram•nb. 

### U.S. Depertment ot Labor Occupatlonal Sjif•ty •nd HeaIth Adminittratlon (Non-Mandatary Form) Form Approv•d OM8 No. 1 2 18-0072 

# ~

IOENTTfY (Aa t13od on laDd anC LhQ lVoro: Brank spacsa an nor p.mwtad. r any Ir•m b na arpycaoio. or n q 548 1 U chre ln/orm•oan b avsjlaDk, an• 30•cra m us! D• ma rfc M t o ndKa • T , Scctlon 1 AAanufactut•r's Nam• Em•rq• j I ~ o ~ , 

### Saud -hern Color ac Chemical

,► .6d( • ss (Numoer. Strr t C,1'y. St a th, an0 11P Cod•) T rl a p~«~ • N w~~r ~r ~ a t

~ ort s86- 

## ~ 16(i 1404 ) P.O. Box 

### 1507 oal. Prrroara
~ 

### 7 Swisher Drive May 21 1986 Si9nature o1 Prepuer (apdonaq , Cartersville, Georgia 30120 Stctlon II -- Haz9rdous Ingredlents/ldantity Informatlon , Olh•r Llrnils Hasardous Compon•Ms (Sp•c i M1c CMmk.sJ Id•ni t ty, Common Nam• {31) OSHA PEL ACOIH TLV R•comm•ndW

~ 1 loona M548 Ochre (Fe20I-XH20)Natural Iron Ox3de1 Non Established; lOmg/L None

Note: Ochre is 'listed as Hazardous because of t'he nuisance dust that may be created in handling t e pro uct. 

### CASM 1343

- 8 

### 1

- 

### 3

I 1 .

Sectlon III — Phyalcal/Chemlcal Characteristics f3arnq Pan1 Specdio (3ravity (H30 • 1) N/A 3.2-3.6 Vapor Pr•ssur• (mm Hq.) M•Itlny Point N/A ' N/A Vapor Oransity (AIR • 1) EvaporaUon Rats N A I (8utq1 Ac•tnts • 11 1 N/A So+uaH6ty in vYaur



### Insoluble Appearance and Odor



### Yellow Powder - No Odor Section IV

—Fire and Exploslon Hazard Oata Flasn 

### Pouu (MUncd Usod) N/A Flammabl• Umits LEL UEL • N/A N/A

. . - N/A Sp+ciaJ Fr• Fiqht,ng Proc•dur•fa None Required'
Unutuat Fi• and Expbswn Hazird• None
tR•produc• locally) OSHA 174, $•pL 1S8` 

# 76tttc+llit-ll ~-t~~ odotan • t fbtd 3 NO N tq3p

~ ttd orugi6RHMioM a321In63M 3NON tutwdjnb3 Jo bw14tot0 oAlt-Mtad ttWti0 'Iri NOI,Ld 0 'M NOI ,Ld 0

- --- uo n. 'wto )d *d3 teAqp eAn-%410'd 3NON mno I a32iIna 3NON R.ruedS 'Iv NOI,LdO lsnty,r3 Rml uolletfw$A 031S3J`JnS ,LnH 'IvNOI,LdO SI 

## isna 3JN`dSInN 2l03 a3A0addV 2l0LH>!iIdS3M (Od11 Ar- , +dg) uo"lo)d AJotttdsIy oainseoW loiluoo -- IIIA uo11oaS

- — tuoll4SllYleyl0 ',LSna 3AISS33X3 3,LY3i30 !(JYfiM SNOI,L'dn,Lls aIOAV 6uuolS Put OugPutH ul w
- 4tl +B ol tuonna+,d TII3aN'd'i a3A02iddH NV NI 'IVSOdSIa 3.LS'JM QI'IOS 'I'dW2iON ' PO41tYl Rtodslp etssM

' •i5na 30 NOI,LV3213 311.L 3ZIWINIW OZ S30I,LOvud JNId33X3SnOFt 3005 3Sn WINdS ic P+teelek! el RVeleyy est0 W u0411 eg ol tdttS ocn Pua 6u IIP ueH oleg jol suollneoaJ d -- IIA u 0 11 30 S
a3MInMii 3NON a,nptoad pry lenj put Aou96nw= 

### 1 . ' NMONN 3NON •)ntod:S Aq PoitAsi08y Anvouso tuqlipuo0 It>wPl

~ ssoj a-TnIstow 34 anp bUTClOPqO ao p t♦ tntod z3 lo t;woidu,Ag pue suO,S a3,L

~ S 

## L 'I ,LON a3,LSI'I

~ I.ON LP O 1eIn

~ H rHSO LtyatioaroW Otlr1 Ld1N
~ t11

~ 'u
~ bouu

~ t0

UNON

~ (xuQy'J Out umY) i0ltrtH yx*IH MojTer+s Iou op paqaosqe aq louue0 'szHg Z OW .01 A'I,L-3snp aouesinN

Luons

~ bul LuI

~ IS LuolulryiN JImr3 p ItMi^o1i 

### w1 8 0 PJ87VH U11eoFl — FA uoIIoeS

NMON:i 3NON u""+6uA0d P!ar of wotllPuoO Moa0 Atn 

# I tnoOnziH

• slx+DoddB io uofl!iodumO0 tnoPrsrrH 3NON (P/oAy ol qeueleNf) AIt11411tdut•o2ul

hQt1S uMoux auoN P?OAr a fton!wo-J I I olam:un I Nqctts -- rlea A1 1A Ilo*ab — A uo11DoS 

# -77J 

# Material Safety Data Sheet
Substance Identification Identity: IRON CHROMITE CAS #: 1308-38-9 Trade Names: CHROMOX Manufacturer: The Prince Manufacturing Company Emergency: Chemtrec One Prince Plaza 1-800-424-9300 Quincy, IL 62301 

### 217-222-8854 

## Components and Contaminants Chemical Name CAS # 

### OSIiA PEL ACGIH TLV Percent Chromium Cr" 7440-47-3 0.5 mg/m 3 0.5 mg/m 3 (TWA) 30-45% Cr Silica, Crystalline Quartz respirable dust 14808-60-7 0.1 mg/m 3 0.1 mg/m 3 (TWA) 1.2% Si0 2 

## Physical Data Boiling Point: NA Specific Gravity (11 2 0 =1): 4.4 Vapor Pressure (mm/Hg): NA Melting Point: 3350 - 4000° F Vapor Density (Air=1): NA Evaporation Rate (Butyl Acetate=l): NA Solubility in Water. insoluble Appearance and Odor. black powder, no odor. 

## Fire and Explosion Hazard Data Flash Point: Not combustible Flammable Limits: LEL NA UEL NA Extinguishing Media: ' Foam, CO 2 , or dry chemical or water. Special F'ire Fighting Procedures: In the event of fire, wear full protective clothing and NIOSH-approved selfcontained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Unusual F'ire and explosion hazards: Not combustible. 

## Reactivity Data Stability: Stable under ordinary conditions of use and storage. Conditions to avoid: None Known " Incompatibility (materials to avoid): None Known. Hazardous Decomposition or Byproduds: None Known. Hazardous Polymerization: Will not occur. 

## Health Hazard Data Route of Entry: INHALATION: May cause delayed respiratory disease if dust is inhaled over a prolonged period of time. - S KIN: No. INGESTION: Ingestion of Iron Chromite may cause abdominal pain and nausea. ...._ .

Iron Chromite, Page 1

Ap-. :9

~ -: 

### 71-)".

### Health Hazards (Acute and Chronic):

Carcinogenicity: Signs and Symptoms of Eaposure: Aggravation of Pre-existing Conditions: 

## Health Hazard Data (ront.) Respiratory disease may result from prolonged overexposure. Can cause eye initation. NTP: No IARC Monographs: Yes (Silica)Excessive inhalation of dust may result in shortness of breath and reduced pulmonary function. Symptoms of silicosis include impaired pulmonary function and wheezing.Persons with impaired respiratory function may be more susceptible to the effect of this substance. Emergency and First Aid Procedures: IF INHALED, remove to fresh air and seek medical attention for any breathing difficulty.IN CASE OF SRIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. IN CASE OF EYE CONTACT, flush eye.s imme:liately with water for at least 15 minutes. Seek medical attention if irritation persists. IF INGESTED, induce vomiting immediately by giving two glasses of waterand sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. 

## Precautions for Safe Haindling and Use Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratory protection. Recover uncontaminated material for use. Vacuum or sweep remaining material, keeping dust to a minimum. Waste Disposal Method: Dispose of unreclaimable material in a RCRA=approved waste facility. Handling and Storing Precautions: Protect containers from damage and keep closed when not in use. Other Precautions: Observe good personal hygiene. Wash after handt'mg. 

## Control Measures Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or is anticipated. OSHA standard 1910.134 or ANSI Z.88.2-1980 specifications are ' recommended. Venti7ation: A system of local and / or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust is generally preferred because it can control the emissions of the cqntaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation, A Manual of Recommended Prac-

— tices', most recent edition, for detaiLs. Protective Gloves: Yes Eye Protecxion: Safety goggles are recommended. Other Protedive Clothing or Equipment: Use other protective equipment when necessary in order to avoid prolonged exposure to skin. Work and Hygienic Practices: Observe good personal hygiene. Wash after handling.



## . . -- - SAR.A Title III Section 313 Supplier Noti6cation This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-to Know Act of 1986 and of 40 CFR 372.45: ComRgnent CAS # % b„yWei¢ht 

### Iron Chromite 1308-38-9 30 - 35% Cr This informatioa must be included in all MSDS's that are copied and distnbuted for this material. -

Iron Chromite, Page 2

April 1991 -7 

# ~

### ividturlal oale(y uata %)neet

May be used Io comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Staridard must be consulted for specific requirements. 

### U.S. Department of Labor /

~ 

### _, Occupational Safety and Health Administration ``; (Non-Mandatory Form) ', Form Approved D OM8 N o . 1218-0072 CAS# 11115-91-6 IDENTITY (As Used on Label and List) I Note: Blank spaces are not permitted. 11 any item is not applicable, or no 

### IRON MANGANESE OXIDE BLACK (I320/3 18 inlamatron is availabee, the space must be martced to indica'e mat. 

### Section I CHEMICAL FORMULA - Fe2 0 3 Mn2 0 Manufacturer's Name Emergency Telephone Number 

### 404 386-4766 Address (Number, Street, City, State, and ZIP Code) Telephone Number for Information 

### 7 Swisher Drive (404) 386-4766 Cartersville, GA 30120 Date Prepared 

### September 21, 1987 Signature of Preparer (opdonal) Section II — Hazardous Ingredients/Identity Information Other Limits Hazardous Components (Specific Chemical Identity; t.',ommon Name(s)) OSHA PEL ACGIH TLV Recommended (opLCna/) 

### HAZARDOUS INGREDIENTS - NO ADDITIONAL INGREDIENTS IRON OXIDE FUMES as Fe 5mg/m' _ RESPIRABLE DUST 5tng/m 3 

### MANGANESE COMPOUNDS 5mA/ta 3 (CEILING, AS Mn)

Section III — Physical/Chemical Characteristics Boiling Point Specific Gravity (HZO - 1) 

### N/A 4.8-5 Vapor Pressure (mm Hg.) Meltlng Point Vapor Density (A1R - 1) Evaporatieon Rate (8utyf Acetate - 1) Sotubility in water 

### . INSOLUBLE Appearance and Odor 

### BLACK POWDER - ODORLESS Section IV — Fire and Expiosion Hazard Data Flash Point Flammable Limita UEL



### N/A N/A 

### N/A I N/A Ex6nguishing Media 

### WATER DRY CHEMICAL • Special Fre Fghting Procedures NnNF: Unusual Fire and Explooion Hazards 

### • NONE
(Reproduce locally) HAZARDOUS MATERIALS IDENTIFICATION SYSTEMS (HMIS) OSHA 174, Sept. 19B5



### HEALTH 0 FLAMMABILITY 0 REACTIVITY 0 ti1J1 

### D >ection V — Reactivity Data tability Unstable Conditions lo Avoid 

### NONE

Slable • X icompatibility (Materia/s to Avord) 

### NONE KNOWN azardous Decomposition or Byproducts , NnNF uNnLflU azardous May Occur Conditions to Avoid olymerization NONE

Will Not Occur X ection VI — Health Hazard Data oute(s) of Entry: Inhalation?YES Skin? NO ingestion? YES ealth Hazards (Acute and Chronic) ANGA_NESE IG CHEMTCAL.L.Y RF.ATED AS PART OF THIS ST B E PI tKFr1T CRYSTAL

, OVER EXPOSURE TO 

### '0 MANGANESE IN AN UNREACTED FORM MAY RESULT IN CHRONIC MANGANESE POISONING(MANGANISM) THE 'ENTRAL NERVOUS SYSTEM IS THE CHIEF SITE OF EFFECT. TO DATE THESE TYPES OF EFFECTS HAVE NOT arcinogenicity: NTP? NO IARC Monographs? NO OSHA Regulated? NO 

### EEN ASSOCIATED WITH THI$ PRODUCT. gns and Symptoms of Exposure XCESSTVR FxPOSttRF TO ATRRORNR TN1ST WTT.T. RFqIJT.T TN FFFFCT SIMIT AR TO THAT OF NUISANCE TYPE 

### UST THAT IS PARTICULATE MAY REDUCE VISIBILITY AND/OR CAUSE UNPLEASANT DEPOSITS IN THE EYES, edical Conditions E 

## ~R~

AND NOSE . INJURY TO THE SKIN OR MUCOUS MEMBRANES CAN OCCUR BY DIRECT :nerally Aggravated u re

~~ A1UT

~ +AT Ar•TTA1T nD aV DT/•nDAttQ CYT c f+i L'A cTN/c l

~~~ c`c'

~ nv - emra=Qa

~ sysm eeyxxvu vse as sesvvsevvv vicexiti vaxrrv * +ss ~ QF 

### DUST. nergenry and Frst Aid Procedures ICTN r'ntyTer`T — WeCN L1TTtI gnev ANn t,JATER EYE CONTACT — FLUSH WTTN t.ARGE AMOUNTS OF WATER • 

### ONSULT PHYSICIAN. INHALATION — REMOVE FROM DUSTY AREA. 3ction VII — Precautions for Safe Hangling and Use ips to Be Taken in Case Material Is Released or Spilled 

### ANDLE AS NORMAL SOLID WASTE, SCOOP UP BY SOME MEANS AND PLACE IN A WASTE CONTAINER

aste Disposal Method 

### ASTE MATERIAL CAN BE BURIED IN A APPROVED LANDFILL OR HANDLED AS INERT WASTE IN ACCORDANCE ITH FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. -cautiona to Be Taken in Handling and Storing 

### TORE DRY AT AMBIENT TEMPERATURE AWAY FROM FOOD AND DRINK.
her PrecautlOn! 

### NONE
!ction VIII — Control Measures spiratory Prvtectlon (SpecA'y Type) [OSH APPROVED FOR DUSTS, MISTS AND FUtdES. DO 

### NOT EXCEED USE LIMITS OF THE RESPIRATOR. ntilation Mechanicel (GerteraQ )tective Gloves Eye Protectlon 

### IBBER, CLOTH OR PLASTIC GLOVES SAFETY GLASSES ier Protective Clothing or Equipment 

### N/A rk/Hygienk Practices 

### ) NOT STORE NEAR FOOD AND DRINK. WASH EXPOSED SKIN FOR HYGIENE PURPOSES. Pftf Z • u.eo,ro.: ,rel.491-521/45775

"M

## MATERIAL SAFETY DATA SHEET
Section I - Product Identification The Georgia Marble Com p 

## any 1201 Roberts Boulevard, Buildin g 

## 100 Kennesaw, Georgia 30144-3619 Emergency Telephone: (770) 421-6508 Prepared by: Trevor G. Lamond, Technical Director Trade Name: Ground limestone/ Calcium carbonate Production Locations: Marble Hill, Ga, Sylacauga, AI Chemical Identity: Product consists of ground limestone (CAS Number: 1317-65-3), which is a natural peoduct composed of Calcium Carbonate (CAS Number 471-34-1) and from 1-3% Magnesium Carbonate (CAS Number 546-93-0) together with various other natural ingredients at trace levels. 

## Section II - Hazardous Inaredients

~ 

## Hazardous Materials Identification System Health Hazard 0 Flammability Hazard 0 Reactivi ty 

## Hazard 0 Personaf Protection E Hazardous Inaredients TLV (mg/m ) Silica, Quartz Calcium Carbonate Dust .1 (Respirable Dust) 10 (Nuisance Dust) This product typically contains less than 0.3% crystalline silica. In addition, there are also small but detectable amounts of the following other naturally occurring chemicals that are known to the State of California to cause cancer, birth defects or other reproductive harm. This warning is provided in the absence of definitive testing to prove that these risks do not exist. These amounts are typical quantities and may vary slightly with different lots. 

# Pz

## Chemical Name Typical Amount CAS Number

Arsenic Lead Less than 1 ppm Less than 1 ppm 7440-38-2 7439-92-1


## Section III - Physical/Chemical Characteristics Appearance and Odor: Fine, White Powder; No Odor Boiling Point: N/A Specific Gravity: 2.71 Vapor Pressure: N/A Evaporation Rate: N/A Vapor Density: N/A (Butyl Acetate = 1) Solubility in Water: Slight Melting Point: N/A



## Section IV - Fire and Explosion Hazard Data Flash Point: N/A Flammable Limits: N/A Fire Extinguishing Media: N/A Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None



## Section V - Reactive Data This material is stable. Incompatibility: May react with acids to liberate carbon dioxide. This material will not polymerize. Hazardous Decomposition By-Products: None



## Section Vl - Health Hazard Data Calcium Carbonate, the main component of limestones and marbles, is not on the NTP, IARC, or OSHA lists of carcinogens and there are no health effects associated with prolonged exposure to pure calcium carbonate. Crystalline silica (sand), 

## a trace component of many limestone and marble powders, in its res irable form has been listed by IARC as a Type 1 carcinogen and the NT P P has stated that crystalline silica is reasonably anticipated to be a carcinogen. Also, prolonged exposure to crystalline silica has been found to cause silicosis, a noncancerous lung disease. 

## Exposure: Inhalation: Can be irritating to the respiratory tract. e Contact: Mild irritation. 

# R in Contact: No effect. Ingestion: Minimal efFect. 

## First Aid: 

## J"- "3

## Inhalation: Remove from area of exposure and to fresh air area.

Eye Contact: Flush eyes with water for 10 minutes. If irritation

persists, obtain medical attention. Skin Contact: Wash from skin with mild soap and water. Ingestion: Ingestion should not cause any significant health

problems. Section VII - Spill or Leak Procedure Spill or Leak: Respiratory protection should be worn during clean

up to protect from airborne dust. Measures should be taken to reduce airborne dust during clean up. Waste Disposal: Shovel up material and dispose of in landfill.

Comply with applicable federal, state and local regulations:

. 

## Section VIII

- 

## Special Protection Respiratory Protection: NIOSH/OSHA/MSHA approved dust respirator if T.L.V. is exceeded. Ventilation: ' 

## Local exhaust: As required for dust to maintain airborne dust below the TLV. Mechanical: As required for dust. Eye Protection: Safety glasses or goggles. Special Protection: None required. Date Prepared: March 3. 1998



# ?6/

# georgia marbie company
nw wOvAta+S 1201 roberts boulevard, building 100 • kennesaw, georgia 30144-3619

" STONE PR00LCn fax: (770)421-6507 (770)421-6500


# MA TERIAL SAFETY DA TA SMEET
Section I - Product Identification The Georgia Marble Compan 1201 Roberts Boulevard, Building 100 Kennesaw, Georgia 30144-3619

,.a 

## Lmergency e ephone: 7 421- 557 enneth J. Meeks, Safety and Training Manager Risk Management Chemical Name: Calcium Carbonate Chemical Family.• Marb/e; Limestone; DolomitE Chemical Fonnula: CaCO 3 ; CaCO 3 i MgCO 3 CAS Number. 471-34-1 Trade Name: :

Section ll - Hazardous Ingredients Hazardous Materials ldentification S s y tem Health Hazard 0 Flammability Hazard 0 Reactivity hlazard 0 Personal Protection E Hazardous /ngredients TLV (1VIg/M ) Silica, Quartz Calcium Carbonate Dust ,1 (Respirab/e Dust) 10 (Nuisance Dust) Calcium Carbonate may contain crystalline silica at levels between 0.01 % and 1.5% and varies naturally. There are a/so small, but detectable amounts, of the following other naturally occurring chemica/s that are known to the State of Califomia to cause cancer, birth defects or other reproductive hamn. This warning is provided in the absence of definitive testing to prove that these risks do not exist. These amounts are typical quantities and may vary slightly with different jobs. Chemical Name Typical Amount CAS Number Arsenic Less than 1 ppm 7440-38-2 Lead Less than 1 ppm 7439-92-1 ?J

## Section lll - Physical/Chemical Characteristics

Appearance and Odor Fine, White Powder; No Odor Boiling Point: Vapor Pressure: Vapor Density: Solubility in Water N/A Sp ecific Gravity: 2.71 N/A Evaporation Rate: N/A N/A (Butyl Acetate 

## = 1) Slight Me/ting Point: N/A Section IV - Fire and Explosion Hazard Data Flash Point: N/A Flammable Limits: N/A Fire Extinguishin g

. Media: N/A 6nusu al p ecial Fire Fight,ng Procedures: None Fire and Explosion Hazards: None

Section V - Reactive Data This material is stable. lncompatibility: Reacts with strong acids to liberate carbon dioxide. This material will not po/ymerize. Hazardous Decomposition By-Products: None

Section VI - Health Hazard Data Calcium Carrbonate is not on the N. T. P., 1.A. R. C., or OSHA lists of carcinogens. Cry stalline silica, a trace component of Calcium Carbonate, has been listed by IARC as carcinogenic to experimental animals and has developed limited evidence for carclnogenicity to humans, however, IARC has detennined that the carcinogenicity to humans is neither certain or proven. Prolonged, repeated inha/ation of crystalline silica can cause silicosis, a noncancerous /ung disease. Exvosure: Inha/ation: Can be irritating to the respiratory tract. Eye Contact: Mild inYitation. Skin Contact: No effect. ingestion: Minima/ effect. First Aid: Inha/ation: Remove from area of exposure and to fresh air area. Eye Contact: Flush eyes with water for 10 minutes. !f initation obtain medical attention. %sists, Skin Contact: sh from skin with mild soap and water. Ingestion: Ingestion should not cause any significant health

problems. 

# •,

# Section Vll - Spil! or Leak Procedures

Spill or Leak: Respiratory protection should be worn during clean

up to protect from airborne dust. Measures should be taken to reduce airborne dust during clean up. Waste Disposal: Shovel up material and dispose of in landfill.

Comp1y with applicable federal, state and local regulations. 

## Section Vill - Special Protection Respiratory Protection: NIOSH/OSHA/MSHA approved dust respirator if T. L. V. is exceeded. Ventilation: Local exhaust: As required for dust to maintain airborne dust below the TLV. Mechanical: As required for dust. Eye Protection: Safety glasses or goggles. Special Protection: None required. Date Prepared: March 4.1998 

## Prepared by Safety Department



# N

### MATERIAL SAFETY DATA SHEET
tNDUSTRIAS SULFAMEX, S.A. Distributor - North America :ampico, Mexico AGROMEX, INC: 

### Mobile, Alabama FOR HEALTH HAZARD INFORMATION, CALL: -(205) 

### 443-5665 Date of Revision: •'03/12/90 msaamaaaaamassaaaassasaaaaaaasaasaasaaaaasasasmamsamasmamssaaaasammsaaass3a a=; 

### - Product Name: TECMANGAM (R) Soluble Manganese Sulfate - Synonym: Manganese Sulfate (81-83.8 ) 

### - Formula: Mixture

msaasassssssaamsss 3


### = saaaseo=a=a=asaasss3aaaxassmsasastsssaassesassassaaasava= : 

### SECTION II. PRODUCT AND COMPONENT HA2ARD DATE 

### A. COMPONENTS: 

### Approx.
_ •_ c Percent TLV** CAS Reg.No..

~ 

### . *Manganese Sulfate.83.8 5 mg/m3 (as Mn) 7785-87-7`•_:.: Magnesium Sulfate 2.0 None 7487-88-9 = Calcium Sulfate .5 None - - 7788-18-9 - Water 1.0 None 7732-18-5

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - i - - - - - - - 

### *Principal hazardous componertt ~ 

### `•- **See Section VI-A for additional'information on exposure limit
. s. PRECAUTIONARY LABEL STATEMENTS: . WARNING! MAY BE HARMFUL IF INHALED ,

CAUSES IRRITATION Avoid breathing dust. 

### Avoid contact with eyes. Avoid prolonged.or repeated contact with skin.
.... Use with adequate ventilation.
_ Wash'.thoroughly .after handling. :

.

. . . . • - 

### FIRST_AID ,

-_ In case of contact, 

### immediately flush eyes with plenty of water for at least 15 _minutes. ,-; Call -;',a physician.;, iWash ' skin with soap and plenty of .: water.... ,Wash 'clothing before: reuse. 

### -' In case of irritation of eyes, nose, and throat, 

### remove from exposure,.treat symptomatically, and call a physician if.symptoms persist.► ° ~



### _ MSDS 001:1
- . . .. . . .. • -- ... :: ..

~ i ~~ 

### '03/11/90 a • . .. . t•'t. . . . . _. 

### B.



# 0-

### Since emptied packages retain product residue, follow label warnings even after

~



### package is emptied. Notice: Manganese Sulfate may discolor ornamental surfaces, rock, tile, masonry, etc. Contact with these surfaces should be avoided. If contact'occurs, wash area immediately with water.
_
aaa
~ aaaaaasiaa

~ a aassasa
~ aaaaasaass:aassaasasaasaiasasiaasasaaasaasasa:saisaasassa s 

### SECTION III. PHYSICAL DATA '•s <. .- 

### - Appearance and Odor: White to cream-colored powder, practically odorless. - Boiling Point: Not applicable. 

## - Specific gravity (H20 - 1): 0.81 at 20`/20`C - Vapor Pressure: Not applicable. - Percent Volatile by Volume: Not applicable. - Vapor Density (Air a 1): Not applicable. - Evaporation Rate: Not applicable. - Solubility in Water: Appreciable (approx. 99X).

' - aii a ~ aiaiiiaaaailifiaaaliiaaiaaalaaiaaia!liiisiiiisaaiia iiiaiiala!liaaaaiaaiaifiia

, , . , _ . '

. . . ~ :. .: •
. 

### SECTION IV. FIRE AND EXPLOSION HAZARD DATA 

### - Flash Point: Not applicable (Noncombustible). - Flammable Limits: Not applicable. 

### - Extinguishing Agent: Use appropriate agent for surrounding fire. - Special Fire-Fighting Procedures: None known to Sulfamex. -=-•

~ 

### = -= - Unusual Fire and Explosion Hazards: None known to Sulfamex. • - ;' ~_~ asaasassisisaasasaissssaassasasiasaasaaaaaa=sssaisataiaasaaaaaisassalsasasassssas! 

### SECTION V. REACTIVITY DATA 

### - -+

~ 

### - - Stability: Stable. 

### - Incompatibility: None known to SulfameY. - Hazardous Decomposition Products: Decomposes to oxides of manganese and sulfur.

, - Hazardous Polymerization: Will not occur. "' . : . : : 7 , .t'1::

ssls asssssa msaassasssssassasssaassaa sxia ssss aassasasassisa:ssassssassssisasaaisasas

. , ._._ . _ . •.. . . . _ .:: . • ~ . • 

### SECTION VI. TOXICITY AND HEALTH 

### A. EXPOSURE LIMITS i ~ 

### a?'•

~ 

### _- ~ 

### J .
• • '

~ 5:2wJ

~ L.Z'J.a 

### - OSHA Permissible Eaposure Limit (PEL): . Kanganese sulfate (as Ma):.`-"i 5 mg/m3-C. 

### - Threshold Limit Value (TLV) : Pfanganese Sulfate (as Mn):' .=5mg/K3-C, ACGIH, 1982. 

### - A NIOSH industrial hygiene analytical method-for manganeseis'availa6le:. (1) - An industrial hygiene analytical method for Manganese Sulfate'is avsilable to health and safety professionals upon request. ~" ~~ 

### :;' =` ~i~ 

### ==r:.''i.I•Ya 

# _ , ~ :~ 

# :: : ~ 

# tr 

# .y_

~ 

# =.
B. EXPOSURE EFFECTS - '—
_ ~ ~ --- 

### 7 4.1 

### Inhalation: May be harmful if inhaled. May cause irritation of the nasal passages. Eyes: Dust may cause irritation. Skin: Prolonged or repeated contact may cause irritation. l 

### 03/12/90 ' MSDS: 001:1C. SKIN AlVll x ~ Yt ricuiauiiv.v



### Safety glasses should be worn in any type of industrial operation. Protective gloves should be worn. _:..
D. OTHER CONTROL MEASURES An eye bath and washing facilities should be available. Wash thoroughly after handling. iisasisssi ssssisssssasassssasasssaaaz=saxassaasaszssasa:ssas:asaaaeasssassisassaiii 

### SECTION VIII. SPECIAL STORAGE AND HANDLING PRECAUTIONS 

### Since emptied packages retain product residue, follow label warnings evea after package is emptied. ii ii i issi i ssisi is liss i!!i !i i s iisas i i ilasi sssi sazs saaa i si sslsls:ii s iisiis saisii ssiss 

### SECTION IX. SPILL, LEAK, AND DISPOSAL PRACTICES Steps to be taken in case material is released or spilled 

### : Collect and contain f:r salvage or disposal. Waste Disposal Method 

### : Landfill. Observe all federal, state, and local laws concerning health and environment.

sassxsa ssasasssssass=sa=sasaszsxsasaasaaasaa=s===s=sxzxsassasmaszsassssssaassasaslis 

### SECTION X. ENVIRONMENTAL EFFECTS DATA A. StAM4SARY: This product has not been tested for environmental effects. However, some laboratory test data and published data (7,8) are available for all of the major components of this product, and these data have been used to provide the following estimate of environmental impact:' This product has a low biological oxygen demand, and it is expected to cause little oxygea depletioa in aquatic systems. It is expected to have a low - potential to affect aquatic organisms, secondary waste treatment micro— organisms, and the germination and growth of some plants. If diluted with a large amount of water, this product released directly or indirectly into the environment is not expected to have a significant impact.


### SECTION XI. TRANSPORTATION DOT Hazard Classification: Not regulated'-by"DOT
s:sss ssssssslassssssasssssssassssssssssaalsals:sa:sasaa:sssslsssssslsassls:ssls:asss 

### SECTION XII. REFERENCES 1 

### 1. NIOSH Manual of AnalyticalMethods , 2nd Edition, Volume 2. Issued by the - „ National Institute for Occupational Safety and Health. Washington, U.S._;

~ — ~ 

### Government Printing Office, 1977, Method S5. `

• • +" ~ 

### 2. H..C. Hodge and J. H. St4rner, Tabulation of toxicity classes. AmInd:

~ 

### ". Hyg. Assoc. Q. 1949; 10:93-96.

~ -
MSDS: 001:1 03/12/90


# • . qa

### C: FIRST AID

Inhalation 

### : Remove from exposure. Treat symptomatically, and get medi&al attentioa if symptoms persist. I 

### Eyes: Immediately flush with plenty of water for at least 15 minutes and get medical attentioa. ' Skin: Immediately wash with soap and plenty of water. Wash contaminated 

### clothing before reuse. D. ANIMAL TOXICITY DATA The composition of this product varies from one batch to another; however, toxicity data felt to be representative of this variable product are provided 

### below: Toxicity Test Scecies Result (2) 

### Classification (3) Acute oral LD50 Rat 1600-3200 mg/kg Slightly To:

~ 

### :,: Acute oral LD50 Mouse 800-1600 mg/kg Slightly Tox: Dermal LD50 Guinea pig >1000 mg/kg Skin irritation Guinea pig Slight Eye irritation Rabbit Moderate In the 1930's, manganese ore mining and processing operations were studied,.and it was determined that chronic overexposure to manganese ore dust produced a disease of the nervous system with symptoms similar to Parkinson's diesease:tremor, rigidity of facial expression, stooped posture, and stiffness and slow

### ness of movements. (4) Other reported illnesses include pneumonia and metal fume fever. (5) Although these effects in humans have occurred from exposure to manganese ore, manganese dioxide, and finely divided manganese, a thorough search of the world medical lfterature has disclosed no reports of such effects occurrinfrom exposure to manganese sulfate, the form of manganese present in Tecma Eastman Chemical Products, Inc. reported that no neurotoxicity, pulmonary disease, nor metal fume fever have been seen in Eastman employees who have worked with Tecmangam for many years, although irritation of the nasal mucous membrances, skin irritation, and eye irritatioa have been observed.' (6) r,

~ . sasss=asssaaaasssasssssssasssasssass

~ ssassaasasssassasassssasasaaaasaassssasssaaa 

### SECTION.VII. PERSONAL YROTECTION AND CONTROLS A. RESPIRATORY PROTECTION

.: ~ . .. 

### An appropriate NIOSH-approved respirator for dust should be worn if needed. B. VENTILATION . General: Recommend at least 10 air changes per hour for good general room. ventilation. Local Exhaust: Recommended to control dust. See Section VI-A for information on exposure limits. Maintain workroom air concentrations below irritating levels.
MSDS 001:1 03/12/90



# . q1(, 

### 3. R.H. Flinn, cc eu. %o•..4-+y.. ..".. 6 ....—



### Public Health Bulletin No. 247 

### , 1940. 4. A. xamilton and H.L. Hardy, Industrial Toxicology 

### . Acton, MA, Publishing Sciences Group, Inc., 1914, pp 127-130. 5. Battele's Columbus Laboratories, Wafer Quality Critical Data Book Volume - 3- Effe _cts of Chemicals on Aquatic Life 

### , Selected data from the literature through 1968. Washington, U.S. Environmental Protection Agency, Project 

### No. 18050 GWV, Contract No. 68

- 

### 01

- 

### 007, May 1911. 6. J.E. McKee and H.W. Wolf, Editors. Water Quality Criteria 

### , Publ. No. 3-A (Revised). State of California, 1963.
sasaasssaassas:ss:sss:asaaasaaaa:aaazzsa=_szsza==xs3asssssasaaaaaaaaasss:a:ssaasss 

### The information contained herein is . furnished without warranty of any kind. Users should consider these data only as a supplement to other information gathered by them and must make independ?nt determinations of suitability and completeness of information from all sources .to assure proper use aad disposal of these materials and the safety and health of employees and customers.

asssasassasssssasasassasaasasasssasassssssssassssaasssssssaaassss:sssssssssssasssa

MSDS': 001:1 03/ 12/90



# . . . • g7

~. .•

. .. ~ . ... .. - ~ _ • ~V,j~.~-~i~ •r ~~••~•~7~/ ~
.~.~ +1t1. • _-'- ' ~ .

t~ (J

~ ZH .r..7 . .1? _ — .
~ ~ - :I= ~~ * j. t ~ ~ .'- .—=a • . .u

~ : • : : ..7 .. ..:

. 

### _ ''

~ ~ i•' _.J rf. '~••~~ 

### •
~. • 7..~1 i

~ 

### :J_

~ 

### s _i~•


### . i~~7i~`- ~^ ~ 

# ?4 i . - _ ~ _~i~sc~A 

### =•i-

~ 

### '


# _ _ _ ... .__• - . ' , r
. ~ -: c:: - • .5

~ 1: -..- i

~ :'

~ i.+ Trl:

~ TQy ' — -+- - ---

~ _, _•

~ — :

~ 1'.-- ?J•.fv.. : • t:i•:•:
- ' , —r ''_ - , .:

.. ~ . . ~ •... . ..i'. _'•:.

~ .~ ' ~
. _ • E, ~ ~ • }t~+ • •r:n' ~~~ '~ .7• ' ~ ~



### . ._ ' 

### _ . ~ •1 

### ' '

_ ~ 

### i .

~ 

### il '

. ~ 

### N :. -.. .... . ' l • ~ • — ...... i ., ...-.

. • -_ ,a, _.. ,.
3.. - i~ S7_J•.i_'_.. • ..- . - • .. ~ •- - . . .. .-.-'....

... ~ 1l./ -

. . . • . ..... •
. . • . . r • - _.I . . . • . .- •

~ :1 .J . 3 .

. ~ . - . •_ .. . . _ . :
. . ... • )

. . . . .. . . _lii ~ .~ . . . . 1 ~ . _ ii.

_ ~ .. ' - . .. _ ... .. ~ .

.. • . '

. . . . . 1 r

. . . .•. ~ .... . • .
. . . i - . . . , .-t - . . _ ..



# .._ ..

~ - 

# ... .... _.7`

. . '.

. . . . ~ 

# ... . ' .

7 • . . •. . ' , . ~ .. .♦

1 i ' _ ' •

~ • - ~ - . 1

~ •:. .1 1 l r . ~ • 1

`,\

## AlRICAN MICROTR.ACE

. .. MSDS

~ 

### (',PneralInPormation Product Name:

- ;Maa=Gto®,' 1 Mah'*fo ®'AS"-` MoIecular Formula: MnSO4H2O Chemical Name: Manganese Sulfate Monohydrrate Molecular Weight• 169.01
Contact: American MicroTrace Phone: (800) 544-3155



### 569 Central Dtive, Suite 201 or: (402) 729-6191 

### V'irginia Beach, \/A 23454 Date Lssued: 2/27/91 Fax Phone No: (804) 463-8156 For Emergency Assistance Involving Chemicals - Call Chemtrec (800) 424-9300

! 

### ComponenC Manganese Sulfate Monohydrate CAS NUMBER: Permissible Air Concentration: Manganese Sulfate Monohydrate 5 mg/m 3 Ceiling (ACGII-D (As Mn) Percent: 90

~ 

### /o 7785-87-7 Ferric Oxide - 5 mg/tn 3 1.5°rb 

### 1309-37-1 Aluminum Sulfate 12 mg/m 3 1.5% 1344-28-1 Silica Dioxide 5 mg/m 3 1.0 0 /0 7440-21-3

c First A3d Measures Ingestion: If large amounts are ingested, if victim is consaous, immediately give 2 to 4 glasses of water, and induce

vomiting by touching finger to back of throac Do not give carbonates. Get nffedical attention t 

# _,.. ,..:

~ 

# ; Y

immediately. 

### ~ t ' i . ~~ ~ Eye Contact: If eye irritation exists, flush thoroughly with plain water. Skin Contact If sidn irritation exists, wash with soap and water. D. 

### xazards Information JAN 31 I999- ' "Health EfPects" Inhalation: May crause irritation of nasal membranes and upper respirat tra Ingestion: of large amounts may be harmful. Eyes: Contact may Skin: Contact may cause irritatiorL -- -W1 -.— Medical Conditions Possibly Aggravated: Respiratory problems could be aggravated by inhalation of dust Unusual Chronic ?oadclty: Some manganese compounds are known to cause acute and chronic toxidty which primarily involves the central nesvous system, however, there are no known reports of such effects from exposure to manganese sulfate. Chronic exposure to silica dust may cause silicosis, a fiberotic lung disease. "Fire and Explosion Data•• Flash Point: N/A , Fire and E.eplosion Hazard: Negligible fire and explosion hazard in dust form when exposed to heat of flame Flammable Iimit• N/A Unusual Fi1e and Explosioa Harards: None 5/15/91 

# °r.3

## L Precautions/Procedures

Fire Exdnguishing Agents Recommended: CDry chemical, carbon dioxide, water spray or foam) as appropriate ! for surrounding mateiiaL Fire E_Ytingui.shing Agents to Avoid: None Spedal Fire Fighting Precautions: Use self contained breathing apparatus Eng3neering Controls: Use containment and/or local exhaust ventilat3on to control dust Normal Handling: Avoid contact with eyes, skin, and clothing. Avoid breathing dust Maintain good

housekeeping practices. Storage: Keep dry Spill or Leak: Collect and contain for salvage or disposal. Vacvum or sweep keeping dust to a minimum. Special Precautions/Procedures/IabeLs Instructions: See "Normal Handling" Note label signal words'Warnin¢1• Personal Hygiene: Wash thoroughly after handling and before eating or smoking.

;•L- - r •L n - 

### Respiratory Protection: Use NIOSH -,MSHA approved dust respirator if irritation exists or in dus ty areas which ----- e:cceed mg/m3 _ - 

### Eyes and Face: Glasses, goggles, or face shields are recommended if initation eaists. Hands, Arm.s, and Body: Gloves and protective clothing should be used if irritat9on exists. Other Clothing a.nd Equipment: None

~ 

### Phvsical Data Description: Light Tan to Pale Gray Material PH: 3.0-5.0 ® 109•6 Solution Boiling Point-- N/A ' Vapor Pressvre & Deasity: N/A

_ Solubility in Water. 50% by weight Melting Point: Decomposes above 450° C.

• K= n , ~ . . 

### Stability: Stable under normal temperatures and pressures. Polymetiration: Will not occur Incompatibllities: None Decomposition: Thermal decomposition may release toxic fumes of manganese. Possibly ozides of sulfur. L Environmental 

### EPA Hazardous Substance: Yes DOT Hazard Class: N.O.S. Orm E NA 9188 RQ RCRA Status of Unufed Material: Not listed 

# J. °e

Rerenccs 

# .. -. _ . Federal RQ Quantity: 1000 LB/454 KG Waste Disposal Method: Landfill or field appliccation at agronomic rates
Permissible concentrat3oa references: "TLV'' -"'Tlueshold Limit Values for Cheniical and Physical - - Agents in the Work Environment' 1084-85 (ACGIIO Harard Informatlon References: "Merck Index" lOth Edition, 1983. Merck and Company, Inc. i_ ~ MK • i_ • tiT.- . •• 

### Thi.s chemical may be subject to the reporting requirements of Section 313 of Title III of 49 CFR 372 of the Emergeney Plann3ng and Community Right-To-Know Act

Ibic matertal sa,/'ety sbeet is ofjered solely for your informatton and investigation. It provides no 

### warranties ettber express or impltect; and assumes 

### no responsibtlity for tbe accurary or completeness of tbe data contatned berein 5/15/91 

# eW

## MATERIAL SAFETY DATA SHEET ZINOX NPCA - EBfIS HAZARD RATL\G Health I Flammability 0 Reactivity 0 Maximum Personal Protection E SECTION I :vtA`'UFACTC:RER 

### EMERGENCY TELEPHONE CHEMIC4L NAME TRADE NAME CHEMIC4L F.aMILY FORMULA CAS N UMBER AMERICAN CHEMET CORPORATION P.O. Box 1160 East Helena, MT 59635 (406) 227-5302 ATTN: W. H. Porter or Dan Brimhall Zinc Oxide ZINOX Zinc Oxide Zn0 1314-13-2 SECTIO\' II HAZARDOUS INGREDIENTS PEL + TLV ZItiC OXIDE °c RESPIRABLE DUST 5 mg/m' 97.0 0(T)ypical) (94.5% 'v1in.) TOTAL DUST 10 mg/m' Exposure is governed by the 8 hour TN4:a established for Zinc Oxide. Zine Oxide is not carcinogenic material as listed by OSHA (39CFR1910) or ACGIH (Appendix A. Threshc'.d L imit V_!_es `or Chetnica] S_bstances 1984-!9S5). SECTION III PH1'SICAL DAT:4 Boiling Point (f): Specific Gravity: Vapor Pressure: Percent Volatile by volume (9): NA H 0=1 5.6 NA 0% N'apor Densiry: Evaporation Rate: Solubiliry in VVater: Melting Point: Appearance and Odor: NA NA Less than 1%. 3590`F Fine poader. Cream yellow. No odor. SECTION IV FIRE & EXPLOSION IiAZARD DATA ~ Flash Point F)ammable Limits LEL UEL NA NA NA Extinguishing Media: NA

, ecial Fre Fghtin g Procedures: None known

- ual Fire Fehtins Procedures: None knoa•n. ' SECTION V . HEALTH HAZARD DATA Threshold Limit Value: See Section II Signs, Symptoms, and Effects of Overexposure: Nausea, chills, diarrhea. May cause upper respiratory irritation; skin irritation (oxide pox); fever, eye irritation w°ith redness, pain and conjunctii•itis; preexisting lung diseases may be aggravated by exposure. Could result in respiratory irritadon; preexisting lung diseases may be aggra- %ated by extosure. Could result in respiratory disease if over exposed on a chronic basis. _ Primary Routes of Entry: Inhalation and/or ingestion. Emergency artd Fm Aid Procedure: Remove to fresh air. Lay patient down. Cover w•ith blanket. If irritated, flush eyes and skin w•ith large volumes of fresh uater for 15 minutes. Refer to MD. SECI'ION VI REACTIVITY DATA Stable x Unstable Conditions and Materials to Avoid: Mass build up under reactive conditions such as but not limited to acids. Zinc Oxide may react violently w'ith strong reductants such as orgaeic compeu:tds, i.^.cluding ch:o; inated rubber at tempeatures over 4'0°F, (a Flammability toaction with linseed oii uac reported once), and metals including but not limited to Mg. Hazardous Decomposition Producu: Above melting point (3590°F) zine fumes may result. Hazardous Polymerization: wll not ottvr. SECTION VII SPILL OR LEAK PROCEDURES Steps to be taken in case material is released or spilled. Clean up with vaccum or conventional tools. Avoid dusting. Waste Disposal Method: Approved land fill. SECTION VIII SPECIAL PROTECTION INFOR.N4ATION Respiratory Proteaion: Cartridge q'pe filter or approved dust mask. Refer to Respiratory Protective devices approved by Bureau of Mines Circttlar IC 8436. Ventilation: To keep below listed TLV in Seaion II, use general dilut9on type ventilation. Protective Gloves: Wear if skin contact is probable and skin is sensitive.

. Eye Proteaion: Safety glasses or goggles. Other Protective Equipment: Lon¢ sleeve shirts if contact is probable and skin is sensitive. qECT10N IX SPECIAL PRECAUTIOINS :cautions :o be taken in handling and storing: Keep lids tiehtly sealed. Store in cool, dry place. .her Preca::ions: Do not take internallv. Avoid prolonged contact u•ith skin. Wash with soap and uater after contact. . SECTION X SARA TITLE IIIThis produca contains a zinc compound (Zine Oxide) and is subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act cf 1986 and 10 CFR Part 372. Date: 5`.arch I, 1989 (Rev. 4) ~~ i.~ . 

# _ ' . . '~ i ~ 

# LO

P.O. Box 1178 Columbus, GA 31902-1178 Telephone 334/291-0930 • Facsimile 334/291-3237

MEMORANDUM To: David Ousley, Alabama Department of Environmental Management From: Robert Maner, Environmental ManagN , YV a AV-- , Re: Fluorine Mass Balance Date: May 28, 1996 In our conversation last week, you suggested it might be beneficial to perform a fluorine mass balance on a dried and fired brick from Boral plants in Phenix City. I leamed that a fluorine mass balance had been performed while these plants operated as Bickerstaff Clay Products. I have summarized the results below. Plant/ Product Main Body

Coastituent dried brick

fluorine content fued brick

fluorine content fluorine

evolved •/.

evolved emission factot

Ob HF / ton ware Atlanta, GA Plant Shale 606 ppm 280 ppm 326 pom 53.8 0.69 Bessemer Buff Bod Shale 679 ppm 339 ppm 340 ppm . 50.1 0.72 Bessemer Standard Red Shale 603 ppm 166 ppm 437 ppm 72.5 0.92 Phenix City Plant 1 Alluvial Clay 454ppm 84 ppm 370 ppm 81.5 0.78 Phenix Ci Plant 3 Alluvial Cla 348 pM 1 56 R2m 292 22M 84.9 0.61 1) A bufi body brick describes a Gghter color bricJc as a result of lowet iron conteat in raw materials. 'I1te raw materiai may alao have a higher alumina content and higher mahaing temperatute. 2) The emission factor is developed using the following formula:
= fluorine evolved (ppm) x 2000 QbJton) x 20 Ib HF 1,000,000 x 19 Ib F

= 292 Faets-gueaae 2000 Ib 20 Ib HF 1,000,000 ton 19 l" 0.61 Ib HF / ton fired ware 

### These mass batance results were produced by Clemson University using a pyrohydrolysis test and are relatively consistent with mass balance results for other Boral plants. The Phenix City Plant 3 stack test that I referenced in the earlier emissions inventory for the Phenix City plants was also conducted by Clemson University. An emission factor of 0.451b HF / ton of fired ware is produced by dividing the average emission rate by the production rate during the test. This is 74% of the emission factor produced from mass balance data for tthe same plant. This is consistent with experience that shows actual stack emissions to be approximately 65% of predicted maximum emissions using the mass balance technique ("Monitoring for Hydrogen Fluoride Emissions in the Ceramic Manufacturing," Ceramfc Induslry Magazfne, 143 (1) p. 3840 (1994). 

### The emission factor derived from the stack test at Plant 3 appears to be the most conservative emission factor (produces the lowest estimated emissions) based on the compilation of all data. The potentdal production of each plant coupled with this emission factor produces potential emissions of hydrogen fluoride in excess of ten tons per year. Based on this estimate, I will continue to assume that our manufacturing sites are Title V major sources. If you have any questions, please call me at 334-480-2487.



# 01-

# t

~ 

# " • :;:

~ 

# ;,i

~ 

# .s.::.= -

~ 

# -..-

~ 

# . _ _ -s , .:~~ 

# " ;:E_'

~.~ - ~ 

# _-...
~ 

# .

, ... ~ r...w- - . -..-r.- .. ~.~ .—t,r--• 

# EPA iVIACT Information Collection

Request Response

}

;

~ ~ ~:~ ~~ 

## rl•...Ya...

. . . _ ~ 

## . R

_ . _ , •
~ ~ 

## • • ~ 

## ..R:

~ 

## i- .y_ ~!~ 

## .. .. ~ 

## _..__ ~ 

## -_ __ _. .n.• .__ . _ ~

~

~ -- ,r. ~~ - • - -- - _ _ ~ ,.: . z
. ~ -- ,

## ► ; .#

~~ . t ...

~ ,

~ ~ ' ~ ~ ~ ~~ , ~ ty ~~~ - 

## • • ' • /

~ ~ i 7



## .

i

~ 

## - ._ ~ 

## .. ~ 

## •-•.w-.+-, . ., ~ 

## - . - + , n --- -- - _. _ ,

~ ?

# MA.CT Information Collection Request Response from - Boral Bricks, Inc.

Table of Contents 

# • Information Collection Request • Appendiz A - MSDS's • Appendi.g B - Test Data

Ik

### Enclosure 2

INFORMATION REQUEST FOR BRICK AND STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS 

### I. Instructions Please return the completed information request to: Bruce C. Jordan, Director Attn: Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at (919) 541-5435. This information request should be completed for each facility that manufactures brick and structural clay products, including facilities that are not major sources. Information is requested for all processes at your plant that emit hazardous air pollutants (HAP's), including those processes that are not associated with brick and structural clay products manufacturing. Sections 

## II through VII request information specific to brick and structural clay products manufacturing, and Section VIII requests information on emissions of HAP's from other processes located at the facility. Processes that may enut HAP's include those processes that use or handle any materials that contain a HAP compound, all processes with elevated temperatures, and all other processes in which HAP compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is included as Attachment 1 to this information request. Attachment 2 provides background information on the requirements of the Clean Air Act and explains how the information requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations and acronyms used in thi.s information request. Several tables are provided throughout the information request for your convenience in answering the questions. An example response is given (shaded first column or row) in each table. If additional space is needed to respond, please niake copies of applicable pages. If necessary, please make copies of this information request for additional facilities. No additional emission testing or monitoring is required to respond to this request. 

### II. General Facility Information A. Name of company 

### Boral Bricks, Inc. Name of facility 

### Phenix City. Plant 3

Page 1 of 24 

# W

### Facility address: No. and street 100 Brickyard Road, Plant 3 City Phenix City State AL Zip 36869 Latitude and longitude coordinates of plant: Lat: 32 1 24'03.88" N 

### Long: 85° 00' 12.88" W 

### Standard Industrial Classification (SIC) Code(s) of brick and structural clay products manufacturing operations 3251 Dun and Bradstreet No. 00-327-5682 Total No. of employees for company > 1,500 for facility 33 (If facility is a foreign subsidiary or if company has foreign subsidiaries, include number of employees not based in the U.S.). Please complete the following shift information for the facility: Shift No. of employees Hours per shift Days per year 1 26 8- 12 359 days

- 

### 25 employees 365 days

- 

### 1 employee 2 6 8- 10 359 days

- 

### 5 employees 365 days

- 

### 1 employee 3 1 8 365 B. Respondent name Andrew S.R. Wichers Respondent title Regional Safety Manager Respondent address (if different from above) and telephone number: No. and street P.O. Box 1178 City Columbus State GA Zip 3 1 902-1 1 78 Telephone No. (334) 480-2407 Name and telephone number of technical contact person (if different from above) Name David Johnson Telephone No. ( 334 ) 480-2487
Page 2 of 24 

# let

### I1I. Information on Operating Permits and Applicable Federal Emission Standards



### A. Please provide copies of relevant parts of all operating permits and permit appGcations for your facility. Relevant parts include the sections that provide specific information and data on: processes that emit HAP's; the use of HAP- containing substances; emission levels for HAP and surrogate pollutants (i.e., VOC for organic HA.P's and PM for metal and other particulate HAP's); emission control device design and operation; monitoring and operation and maintenance (O&M) procedures for control devices; and generation and releases of other niedia such as wastewater and solid waste that are associated with the operation of air pollution controls for brick and structural clay products manufacturing processes. If the operating permit or application contains the same information requested in any part of this questionnaire, you may respond to the requested information by referencing the page or section of the permit/appGcation to avoid duplication. 

### If you reference your permit or application, you must supplement your response with all of the additional information requested in this questionnaire that is not included in the permit or permit application. If you prefer, you may submit the requested information from your permit/application on a 3-1/2 inch diskette. B. If any source or emission unit at this facility is subject to a New Source Performance Standard or other Federal emission standard, please identify the source and applicable standard. Exa.mples of applicable NSPS include 40 CFR 60, Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers in Mineral Industries. No NSPS ayylicability determination has been made for this facility at this time.



### IV. Brick and Structural Clay Products Production and Raw Material Consmption Information 

### A. Please provide the 1996 production rates and the current production capacity for each type of brick and structural clay product manufactured (e.g., structural brick, clay sewer pipes, structural clay tile, etc.). Note that production data should be provided in units of tons per year (tons/yr). Product 1996 production (tons) Production capacity (tons/yr) Brick (Fired Weight) 122,491 135,289

Page 3 of 24 /D(

### B. Please provide the type and amount of each raw material and body additive used in 1996 for manufacturing brick and structural clay products at your facility. Examples include clays, shale, and any additives that are mixed into the raw material prior to forming. Indicate additives by chemical compound, rather than by trade nanze. If the information requested is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the informa.tion below.
Raw materiaVbody additive Amount used in 1996 (tons/yr) Lignosol (Additive A) (wet weight) 198 Rome Shale (wet weight) 11,475 Hallmark Fire Clay (wet weight) 894 Kaolin-Eufaula (wet weight) 227 Clay (mined locally) (wet weight) 128,000

C. If available, please provide a copy of the MSDS's for the raw materials and additives listed above. See Appendiz A D. If available, please provide chemical analyses, including fluorine, metals, and organic content, of the raw materials listed above. See Appendia B

Page 4 of 24 

# lD z

### E. vsing Table 1, please provide information on the consumption and HAP composition of all glazes and colorants that contain HAP's or HAP precursors and that your facility applies to brick and structural clay products. Indicate whether the coatings are glazes or colorants. Also indicate the type of product that the coatings are applied to and the total weight of coatings used in 1996. If the glazes or colorants are formulated at your facility indicate so and provide the production capacity. List each ingredient of the glaze or colorant. Beside each ingredient, indicate the total amount of the ingredient used in 1996. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. F. In the space below, piease indicate any glazes or colorants used by your facilit:, hat do not contain HAP's and are substitutes for HAP-containing glazes or colorai;r.:; used by your industry. Indicate which HAP-conta 

### ining materials the non-HAP glazes or colorants replace. Describe any limitations on the use of those substitute glazes or colorants.

G. If your facility colors brick and structural clay products by flashing, please indicate the types of substances used to flash the products and the amounts of those substances used in 1996. 

### Substance Amount used in 1996 Units specifyl Natural Gas Unknown - Not Measured Not Applicable Propane Gas back-uy fuell Unknown - Not Measured Not Applicable
H. If available, please provide a copy of the MSDS's for the glazes and colorants used by your facility. If your facility prepares its own glaze, please provide any available MSDS's for the glaze ingredients. See Appendiz A Page 5 o f 24 

## /D3

### Type of product glazed or

colored 1996 consumption (tons/yr) I Produced at facility? (yes/no) I Production capacity (tons/yr) Total usage (weight) of each ingredient (that is a HAP, contains a HAP, or is a HAP precursor) in 1996 Brick

179
kme 

### Not Applicable
Ingredient Total 1996

usage, tons

Iron Chr 

### o nu 

### te Green Chromium Oxide 

### Zinc Oxide Manganese 325 Mesh

Liniestone GA Dolomitic 

## Manganese Sulphate OA ~

24.12
0.90
1.75 

### :1Zix?
88.23 

### TABLE 1. CONSLTMPTION AND HAP 

### COMPOSITION OF GLAZES AND COi.nRANTS I Type (e.g., glaze, colorant) EXAMPLE: ColorantlCoatings Glaze

Page 6 of 24 

# /'
~ 

# el

### If additional space is required, please make copies of this page. If the information requested in

the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the perrnit (or application) rather than filling out the table.

Page 7 of 24 

### j 0 ~

# e

~ 

### M ~ C

~ 

# A p y 

# o ~
L Q, y a~

.~ 

## d~ > 

# 0 0

~ ~ 

# rA It



## N w C 00 

### a, co 

### a ~ ~

~ +M y

~



# e ~

• °~ ` °~ ~ •~ 3 

### x > v

~ S •~ ~
E ~

.

. ~

b

~ aq ~ • ftS 

### ~ ~ • ~ ~ ~ N

• - - C%I 

### •~ . ~ •~+ ~ ~ ~ ~

~ 

### - V



# w ~ C/]

U • y C/] ~ ',~ .r Q Q G ~

~ 

# ^ ^

~

. ^ ,



### ~ .~ : - • 

### ~ ° ~ ---

~ fX 

### p, 

### ~ x ~

~ ~ N

~
bo O .. •~ •--•► V] 

## a~ ~ U

~ ~ 

### '~ co

~ 

## o a ~ ~ U
~ 

### ~ 3 "
G ~ O o Cd Y rn . ar o

~ U



## lD tocli

w 1-4 00 00 eq
7 ~ m E E e

. . .

O 

# G.

CL

0

cn ai

C 0 

### O

, It CA

0.
G. 

### O co

cis 0



### O

Cd



## 107`~ ~ O 

# ,fl ~ •~ o

~ n ' ~ • •+ ~ O v ~ y
~ 

### ~ •U 

### ~ U ~ .~ .~ un U 

### ~ •~ CA 

### ~ U Cd R, ~ U C U O
~ N N U) ~ U a~ 

### U_ 4~ ° 

## C;3 ~ ed ' 

## v O 

## +3 y a °o.. ~ 

## - N n ~ 

## Cd ~

.., C8

, O —

~ O •~ ~ ~

C d 0 ~ O "' ~ U ~ O

~ c~ O Cn Q. • ~ 4~ ~ V N U +' U 

# F Q ~ 

# N~ .2> si, 

# z c~


# ~~ 

# o z ~ ~ O



# ° ~'~
~ C '~ « 

### > S "O oo 

### ~, ~ 

# >, •v ~ p 

### .~ c~ cl 

### a cts 

### ~ in 

### ~ O v'i 

### ~ N cn C Q"d U



## .-- ~ • ~ y
~ 

## 2 U cd 

# ~ 

# o

~ N

~ ], CA , d > f-

~ • O 

# ~ 4) 

## ~ •-+ 

## ~ U 

### T - ~ • 

### r., 4-i

O 

### c ~~ ' ca . ~ d •'
,. ., ~ V~ 

# ~ CA 

# o >

.~ y U 

### ~ 4) ~ y 

### ' • ~ •~~~~w,~ 

### . ~ ~ ~

os r

A .~~ +-' 

### ~ > U CA y '—' 'C U d' . 

### ~ •~ U 

### wEC,3 w. ~~ 

# x w°m 

## jvY

### .~

~ y 

### a 

# 0

~
~ ~ i~ 

### U W 

### A

~
.~ 

### cts

~ 

### 0 U CO)



### -d o

w ~

~



## ~ on


### ~ Q, 4-4 

### ~ '

~ rn .y `~ o


### co • o a. 

## y y ~ U 

## ~ ~ a~ U U 

### a ~ ~ •~ ¢,

~


### ~ I tu 

### ~
s~



# ~ w ~


## ~ y ~ o ~ 

# o ~ ~ ~ N

~ +- O .~
~ ao cz P. •v a ~ a~ 00 y

N ~ ~ U U ~ • ~ V ~

.r .G ~ •-- ~ CD

~ ~ CA Q



## 8 U U U

S M ~ 

# ~ r U + 

# z 0 

### ~ .~ ~ Un

~' •~ ~° .~ 

### r., M \p ~ +.+ U U



# _ -

~ 

# .9;. -

_ 

# . ._- -

..

. _' ~"

~ -,~ - 

# _ I~ i 

# - a 

# _ _:..

,_ .... :.-. _....._... ~ 

# =_ = -=::

. - 

# :_ -- . ~ 

# . H_=_=__:: 

# '—_ _; Q

,'. 

# _- • 

# p, ; .... , - - - - ~ 

### w .
_. 

### _ .- 

### . . • 

### . .. .._ .._..... ... ~ 

### ..-.. :._.:=:. _ ..:.: .. - . ... . .... . ~ 

### .::_ 

# ~_ ,•,•, ::'~~i~:'~ .- -#r:.. - 

### - _ -

. . . .__..... 

## .... .......__--.. 

## ... ,....- . ;.. 

# ~

''.._ . ..--..:._ 

## . .. . .:

~ 

## .:. -.:... - --- - --- 

## _.... .. . _.......... 

# ,. -... _._ . ..... . .. .. 

# ,.._..._... . ... ..... ..__...-_...._. ..... _.. _ _........ 

# ,.:. :..
.... . .... - .-.......

~ 

## ..... .. _.... . ....... . 

# . .:..._..:: ..... . ..._ ='

_. 

## - - a 

# ,.. - _. :.:. ..::. -- - 

# :. .: - 0 

# - ~ 

## -- 

# - - - 

# - -

. . .. ...... . .. .. ...... ... . .. -- -

~

,a 

### sz

~ ~ , ~ ~ L'A 

### y ^

- ~ •g t..



## ~ CQ C Q p q• 

## ~ ~ ~ 'b ~ .~ • 

## ~ 

# A ~, ~ ~ ~



### E ~ ~



### a •~ a~

~ ~ 

### .r >, a

•~ 

### a• ~ ~ 

# : a ~ 

# A 3 .~ o 

# 0

. b 

### i ° 

### ~ Ci_



### _ ~ ~ V W ~.~ A~ d ~ ~ ~cL 

### t ~ ~ a~ i 

### x4 

### o • 

### ~ oo C ~ 

### U ~ 

# U F~ 

### W

~ 

### ~

~ 

# W

~ ~ A 

# v

~ C/] 

### W U

~ 

### ¢

~ 

### W

~

~ 

### N 

# W

~ 

# i

m C. .r 

# /DI~ T c

~ e
. ~ C 0 U y 4)

~ a .~ .. N
~ a.+ C N

~ p 3 ~ ` C O y cC ~
~ 

## y w ~ c ~ o 4. ~ Vl 

## ~

~ ~ 

## y E ~ o L

v ~ 

## ` o 0 

## ~ y 0 O.

~ •!

~ 

### E u 

## a .e 

### O ~ H ~



# ~ cc L E 

### a, O ~ y 

# O a 00 0 C 

### ~ cc 

## w a ~ o H

a L ~

a

.!: 4•. 0 

# .~

~ ~ 

### E y 

## n.

~ = .~ 

### ~ 

## .=

~ ]. y

~ 0 b ~ 

# = ~ N W 0 C 1 4

~ .^.0 ca 

### a.

M W 

# a ~ C T O•~ ~ ~■

u .D



## U ~



## U .D



## U a a 

## ca a a 

## a o~~ c c c
O U w

t t t V .0

V C cr

o O •fl ~ t~. ~ O 7 `

M ` y . ~ •'d

a -C A'C
~ o ~ ~ '~ ~ " - •• Y~C
~~ '" >,0
~ GI. O + ~~ '~ Q~ L C ~ 

# Fi W "' ~' ~ ~l O ci .Y U~ U«~. 0 cd ~ ~ D U p, C o y a ~ E_~ ~

0 , 4 0 "' = y 

### E YM.. ~ d y ~ •~ ~ ~ ~ o L o ~ . -. i C G

C vl 0.4) *_ ~ O ~~ O d O ~ O>~ G U ~ cc rr L VI `
. Q i~ ~ _.' ~ ^ ~ C.' ~ .~ ~ ~ • ~ W 'L 

## _~~~

o~ 

# o

.. 

# -----=-

_ 

## Z ~ 

# _ _.-

~ 

# ':'_. =4.4_ •: _:_.;_-,-__ V

~ 

# l

~ 

# V

G z ~ • e 

## d . _
. . -• ~ ,_, „_, ~ --~ N ~ i Lt cr .l

s. ~ Q u •v 'G ca '_C 0 ~ ~' C Q~ ,-.. .°n x•L

G~ i ~0 ~ (/~ ~ ~ C/1 Q o O

=- (Yi G ~ 3 E"•



## //D

### ~

W a 

# ~ T 

### O

(N/1 w ~ ~ :. ~

o j 0 y 0 ~ 0 0 0 C cl F Z fr z Z z ~

~ u] '* cn E

~ 

### 0

~ .

. :....,.,,.



### s7

~ -. - 

### ~ ---

----- 

### ~

~ 

### U

- ~
~

, +r 0-4

~ 

### ¢ --

~ 

# .1 w d

_ 

# z ~

--- - 

### a 

# o X X X X

~ 

# v - ---_- -

a =-= - 

# z o

~ 

# --_ -- o _.... _-_

~ y

• r/ y l L' CL 6- c N ~ 0 M

~ ~ 

## a

/~~~ W a

~ ¢ H +. i

~ 00 

### Y C 

### r ¢ z



## ~ ~ v ~ p ❑ p o

G

. C

Y ~ N

r N

~ C ~

~ 3



# ~ _ ~ a

~ 

### / l y b 

### ^ ~ ~ ^ ~ h O C C ~ C ~ C ~ ~ p ~ ~•C II II II II 0 

## ~ ~ ~ ~ ~ = 

# z >! _

.. _ --

~ `. - _ -
^

_. __ ;. :• ~`~ ~ 

# . .;:.__,_._._ ~ 

## .•:_... ,. ... ...

... . ... . •.::; ~~ 

## .. .. ~ 

## : __- ,.... ...: ... - - . .
_ . '
. ..... ~~ : ~ :'~► 

## ._-r::,..:-_::-

rw '



### _ - - -

~

~ 00

r
y O ar



### . rA z / ~ ~y ~ • N ~ 46

~ 

### 0 ~ z 

## u

• G~ VI y b' ~ y L Ci ~ 1 ^ N ~

y ~ ~ y

.~~' p i

~. Q ~ 0 ~. ~ — w ~ ~ ~

3 ~

~ c 

## .T. V ,~ d ~Q @~
~ p,

~ o C/] ` ~ -' ~ C/ ~ ~A v ~ 1 • fl ~ ~ R7 ~ ~ ~ ~ ~ Q • o .~ ~~ ~ ~ v ~ L Ict N 4. O

~ ~
~

~ 

## a



# pzn

~
~ 

## ~ 

# o z

° z ° ~

z 

# zz z



# ~ Z 

# z z 

# ¢¢ zz 

# ¢

z Q ~

~ 

# o 

# zz z 

# zz z o ~

c 

## .. 

# °

z ° z 

# Q

z 

# zz z

~ 

# z O 

### a



## ~



# z ~ 

## o 

# °z°z ¢¢ 

# zz z ~ 

### W y

~ 

# °

z 

# zz z 

# ;i fL4 

# ~ 1I ii

~ N

.-. + b+ ~ ~ O V1 + .+ (d

~ 

### rz O • ~ y y 

### ~ ~ y N ~~ ~ •~

~ + ~
y '~ ~ ~

~ y



### . y '~ ~ a •~ ~ ~ a y 

### ~

~
C ^ ~ ~
~

~ s
~ ~ ~ 

## .~

a ~ ~ ~ 0 y

~ 

## .~

~
.~ 

## ~

. Q a

~ a~ s 

# u U
~ ~ 

### w
~ ~ 0


# ~

~ ~ .~

~ 

### 0 

### 'v w

~ 

# >,

~ c N

y ~

..~ ~

¢ ~

N

a.+

.+ 

## ~ 

# z c o ❑ II a ~ ~ ~ N ~ 0 kn 0 

### ~ 

## a



## .1

~ 

## 3

### 0
z ~ C ~ 

## U t

~ 

## ' Y cn o y 

## yz y 

# C _
y~

~ ., ~ C

~ , 

### Q ~ ~ •~ Q ~ ~_ ~

0 

### x 

### 79 ~ W 

# a ~ H « w ~ 0
~

.. ~ 

### a

~ „ C 3 3 3 

### o t11 C C C ~ 

### , o 

### ~ o 

### _, • ` `



### ~ v~

z

M

~ •y ~ ~ 

# z

. L 

### _

- - a+

. y

- 41 :.'

.

_ ... :..... ~ .

; 

## _ ..: -- a_ _ - _ _- -- - - -- ---

- -- --- ----

~



# _ 

# m

~ 

# .. ~ ~ a ~ s ~ b ~



### ° ~ o

.~ cc 

### H U
~ ~ a ~ ~ ~ a ~ ~ C7 

# ~ N 

### w 0

~ ~
~ f~ 

### a

/ ~~r
~
~ 

# N

~ O H

~ .~ • Q
N ~ 

## z o u ~ a z y ~

V -v

~ O 

# ; z c u

~ 

## z C

c~ s_ ~ N t A

~ 

# . . ~ N d
~ t a.. O y 

### 0

. ~

~
~ 

# a
d

~
~ s 

## U G 

### W
~ ~ ~ C 

### O 

## .€ a 00 G ~

~ 

### 0 T ~

N 4.~ O ~

~ 03 

### a,

c 0 4 0

. 7

~ G

~ .~
~ 

## U
.~ 

# _N

~ ~

~ 

### s

~ ~ ~

cc 

# ~ (U 

# L_

4~ 7 c O y 

## °o s.5 ~ :. 

### a O

~ 

# °

Q ~ 

## w ~

O ~

~ 

# O a 

# 0 0 

# ' p

z p z ° z a



## z z ~ 

# w 

# zz z 

# a a z z z z ~ 

### _



# ,_. . . ... _ . .:.. ..._. ~ 

# .. . ... ...

_ ~ 

# ......... - - - ..... _.... , . .. . , . :. . - - -

... . ........ ... . ......,.__.-. .-..

~ 

# ....., .:..

_ ,... ~ 

# .. ~ 

# .; :.. , . ..,. .. . ... . _ - :...:._.,::_'.:.
z w r
~ V OD

~ N

~ ..i w
-~

'' y O O eO ~ J ~ U ~•.~

Y ~ 

# N
«+ cc

.~ I fA •~
- ~ ~ (y .~

~ 0•y
~ 6~
• 

### y y . G H •~

~ « ~ t ~ • cn , 

# _ c

~ ~ y ~ ~ ~ 0] 

### c ^



### ;~ 

# s` Q ^ W 

# a
~ ~ 

# L_

4 a

~ t C .( 4 4 d 1 c C

. c C a a s a c ~ w 4
~ 0
~ C i 

# .~

0 c .} 

### a a c ~ ~ = .~ 

# w
~ c ~ c

~ 00 !'"

~ ] v1 N t

~ -. _ ~ ~ .~ • ~ •~ 

## d ° x a

OO e ~ ni ~ ~ `^ y c C~ ~ y '~

m ~ Q



## A w O



## = O .. ; ~



## " ... LS. v 

## •d z x R ~ di 

# ~ N

~ OU 

# 4h •~ 

# 3 = ~ 

# .g '
00

~ ~ ~ ° y ~ ~ ~ ~ ~ ~ U ~ • CC

.~
h o ~ c

~ «. 

# L U

~ L

~ Q~ n.

~ •

N 4-~ O 00 ~
~ ~ c~ t~.

ai
~ 

## ~

~ ~
~ 0 ao c



## 116~ a) a ~ 5

'a N
~ 7

y ~

• A ~

~ y W ~ C O L ~ ~ C

~ ~ ry)

~ W F-~ W

.., W 

### U G~ Q 

## w 

# z c ~ ~ ~
~ 

# z

~ 

### v N
~ 0

~ ~
~ ~ cl 

### a

~ 0 ~



## // ~~ ~ W
~ ~ ~ ~ 

## U

~ 

## U

~ W W

. r

.. ~! ~ U ~ 4. 7 O A _C

~ C ~ C O U

~ D ~ a ~ 

# C_

~ 

## n u ~
~ . ~ y

c ~
~ 5 ~ : o
u ~ 

### _ c Itt N 

### 4, 0 0 N a~ ~ ~ 0.



## IltVI

W 

### U I~

~ 

### W A 

## a O 

## aa H 0 

### U

~ W 

# x H O A ~O 

### w 

## a

~ c ~ ~ Y {. ~ L R~ b. a.+

. ~

~ a u ~ Y ~I 0 y C 0

. Y

~ N

~ ~
~
. Q a c~ a~ s Y ~ U ~ i.n 

## w Q~

~ ~ 

### E 

## 0

.~ a 00 C .~ ~ ~ 

## 0 y

~ 

### U w t

~ 3
~ 

# 'g

_ ~ 4
; o ~ Y ~ lu
~ 

# e o Y o
~ op
.~ .E

~ 4=. ~ N w O

~ N 4) bD cz 

## a

N ~ 

### ~
. Q Q Q Y O 

# z 

# 0 ~

.. .. ., .. 

### o d Y 

### i Y Y 

### u Y 

# a z
~ Y
4) ' cil



## Il/`

### D. Using Table 7, please provide the following information on cunent monitoring procedures for each of the control devices listed in Tables 6A to 61): parameters monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices used (e.g., differential pressure transducer, thermocouple), and recordkeeping practices (e.g., manually recorded in log book, continuously recorded by electronic data acquisition system). Describe briefly other operation and maintenance (O&M procedures for each control device. If the information requested in the table i.s contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table. VII. Pollution Prevention Practices for Brick and Structural Clay Products ManufacturingA. Please describe all pollution prevention practices (i.e., process modifications, such as reuse of discarded or rejected materials, or any practice that prevents or reduces the amount of air emissions, or the generation and release of solid waste or wastewater associated with the operation of air pollution controls). If the information requested here is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. This facility: 1) reuses waste heat from the kiln to heat the dryers (and to a lesser degLee the holdin rooms)• 2) recycles floor sweepings and scrap/waste clay back into the brick body; 3) rec c

yy les areen brick back into the brick body; and 4) recycles off-spec brick Qrog) back into the brick body.

Page 22 of 24 

## 120~

~ Q 

### W 

### U O ~ 

## a
~ ~ O Q ¢ t7

~ ~ 

### H 

# z

~
~ 

# w U

~ 

## > W 

## Q a

~ H 

# z O U

~ W 

## a
~ H ~ ~ ~ 

### s 5 0 00 c 

### w c~ L N L ~ ~

~

~ . L 

# w 0

~ 0 .~ H

0 ~ ~ ~ ~ ~ ~ 0 a ~ ~
U It

N O

~ 

## N b~0 cC 

## a ~
~ 

### 0 

## zs ~ 

## u > ~

c ~ ~

C.~ U C

• V . C 

### ~ 

# a E
L a
~ O e 

# E o. .~ 

## v
~

. O .~ 0 ~ 

### ¢ z

~

~ 

### a e a 

# s b 

### 3
~ 

# ¢ z

~ 

### ~ ~.~ F > ~ Q 

# z

e ~ 

### o a ° i

..,

z

W2~ a~ o 

### E z

0 d 

### Uz

~ c



### /z/

### TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCES 

# I Process/emission source/SIC Code(s) 

# I HAP's eniitted 

# I Estimated annual emissions, 

# I
tons

Not Applicable



### SIC

SIC

SIC

SIC If the information requested in the table i.s contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.
Page 24 of 24 /ZZ

### ivtdterlal oale(y vata Jneet

May be used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Staridard must be consulted for specific requirements. IDENTITY (As Used on Label and LJst) 

### IRON MANGANESE OXIDE BLACK #320/318 U.S. Department of Labor Occupational Safety and Health Administration (Non-Mandatory Form ) Form Approved 

### D OMB No. 1218 -0072 

### CAS# 11115-91-6

Notc: 8/ank spaces are not permltted tl any item is not applicable, or no infovmation is evailabte, the space must be marked to indica'e that. Section I 

### CHEMICAL FORtiULA - Fe2 0 3 Mn2 0 3 Manufaclurer's Name Emergency Telephone Number 

### 404 3336-4766 Address (Number, Street, City. State, and I!P Code) Telephone Number for Information 

### 7 Swisher Drive (404) 386-4766 Cartersville, GA 30120 Date Prepared 

### September 21, 1987 Signature of Preparer (optlonal) Section 11 — Hazardous Ingredients/identity Informatlon Other Limits Hazardous Components (Spec i Bc Chemical Identity; Common Name(s)) OSHA PEL ACGIH TLV Recommended % (optional) 

### HAZARDOUS INGREDIENTS - NO ADDITIONAL INGREDIENTS
IRON OXIDE FUM.ES as Fe 5mg/m' 

### RESPIRABLE DUST 5mg/m 3 MANGANESE COMPOUNDS 5mq/m 3 

### (CEILING r

AS Mn)

Section III

— Physical/Chemit:al Characteristics Boieng Point Specific Gravily (H20
- 1) 

### N/A 4,8-5 Vapor Pressure (mm Hg.) Meltfng Poitnt Vapor Density (AIR
- 1) Evaporation Rate (Butyl Acetate
- 1) Sdubility in water 

### .INSOLUBLE Appearance and Odor 

### BLACK POWDER

- 

### ODORLESS S e ct i on I V — Fire and Explosion Hazard Data Flash Poir>; 

### N/A N/A N/A ( N/A Extinguishing Media 

### WATER DRY CHEMICAL 

### • Special Fre FtghUng Prooedures Nt1NF Unusual Fre and Explosqn Hazard.l 

### NONE
(Reproduce locally) . HAZARDOUS MATERIALS 

### IDENTIFICATION SYSTEMS (HMIS) OSHA 174, Sept. 

### 1985

HEALTH 0 FLAMMABILITY 

### 0 REACTIVITY 0 

# /z3

### , D ;ection V — Reactivity Data lability Unstable Conditions to Avoid 

### NONE

Stable 

### X )compatibility (Materials to Avold) 

### NONE KNOWN azardous Decomposition or Byproducts •

~ ection VI — Health Hazard Data oute(s) of Entry: Inhalation?YES Sk1n? NO Ingestion? YES ealth Hazards (Acute and Chronic) 'AN ,AN .S . IS CHEMTCALLYREATED AS PART OF THIS ST AT.R PTGMENT CRY TAt OVER EXPOSURE TO 

### '0 MANGANESE IN AN UNREACTED FORM MAY RESULT IN CHRONIC MANGANESE POISONING(MANGANISM) THE :ENTRAL NERVOUS SYSTEM IS THE CHIEF SITE OF EFFECT. TO DATE THESE TYPES OF EFFECTS HAVE NOT arcinogenicity: NTP? NO IARC Monographs? NO OSHA Regulated? NO 

### EEN ASSOCIATED WITH THIS PRODUCT. gns and Symptoms of Ezposure X('F.SSTVR EXPOSttRF TO AIRAO N. D 1ST WITI RF.S T.T IN FFFVCT SIMTIAR TO THAT OF NUISANCE TYPE 

### UST THAT IS PARTICULATE MAY REDUCE VISIBILITY AND/OR CAUSE UNPLEASANT DEPOSITS IN THE EYES, edical Conditions E ~IR~ I~

AND NOSE. INJURY TO THE SKIN OR MUCOUS 

### E MBRANES CAN OCCUR BY DIRECT

~ neralty Aggravated y t"pos ure 94.r VAl

~ iT/+AT A/•TTAN !

~ D DY DTnA DAt1Q Q PTIy n7 L`A1yT1* ~ ATL'!`CCQADV r.AD DCA ~,~ QI+

- -- sClim iiyiiyi, y!■ ai iei00ltVtlO yie'

~ ' ,i yaa:a z a -- p ia-

~ eear 

### DUST. nergency and Frst A1d Procedures KTULCf]NTACT — LteCld tJTTH SneD eNn GIATFR EYE CONTACT — FLUSH WITH LARGE AMOUNTS OF WATER • 

### ONSULT PHYSICIAN. INHALATION — REMOVE FROM DUSTY AREA. ection VII — Precautlons for Safe Hangling and 

### Us e eps to Be Taken In Case Material Is Released or Spilled 

### ANDLE AS NORMAL SOLID WASTE, SCOOP UP BY SOIME MEANS AND PLACE IN A WASTE CONTAINER

aste Disposal Method 

### ASTE MATERIAL CAN BE BURIED IN A APPROVED LANDFILL OR HANDLED AS INERT WASTE IN ACCORDANCE ITH FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGUL

to Be Taken in Handlfng and 

### TO DRINK
her Precautions 

### NONE _. ection VIII — Control Measunrs -spiratory Protectlon (Speclly Type) 

### IOSH APPROVED FOR DUSTS, MISTS AND FUMES. DO NOT EXCEED USE LIMITS OF THE RESPIRATOR. ntilation I Local

Mechanicel (Generaq :)tective Gloves Eye Protection 

### JBBER, CLOTH OR PLASTIC GLOVES 

# I SAFETY GLASSES ier Protective Ctothing or Equipment 

### N/A )rk/Hygienic Pr8ctice3 

### ) NOT STORE NEAR FOOD AND DRINK. WASH EXPOSED SKIN FOR HYGIENE PURPOSES . Pe" Z • u.earo: , ose_a91-s29/AS17S

# Material Safety Data Sheet
Substance Identification Identity. 

## IRON CHROMITE Trade Names: CHROMOX Manufacturer: The Prince Manufacturing Company One Prince Plaza Quincy, IL 62301 217-222-8854 CAS #: 1308-38-9
Emergenry: Chemtrec

1-800-424-9300 

## Components and Contaminants Chemical Name CAS# OSHA PEL ACGIH TLV Percent Chromium Cr+ 3 7440-47-3 OS mg/m 3 OS mg/m 3 (TWA) 30-45% Cr Silica, Crystalline Quartz respirable dust 14808-60-7 0.1 mg/m 3 0.1 mg/m 3 ('I'WA) 1.2% Si0 2 

## Physical Data Boili.ng Point: NA Specific Gravity (H = O =1): 4.4 Vapor Pressure (mm/Hg): NA Melting Point: 3350

- 

### 4000° F Vapor Density (Air=1): NA Evaporation Rate (Butyl Acetate =1): NA Solubility in Water. insoluble Appearance and Odor black powder, no odor. 

## Fire and Explosion Hazard Data Flash Point: Not combustible Flammable Limits: LEL NA UEL NA Extinguishing Media: ' 

### Foam, CO V or dry chemical or water. Special F'ire Fighting Procedures: In the event of fire, wear full protective clothing and NIOSH-approved selfcontained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Unusual F'ire and explosion hazards: Not combustible. 

## Reactivity Data Stabilit}+: Stable under ordinary conditions of use and storage. Conditions to avoid: None Known ". Incompatibility (materials to avoid): None Known. Hazardous Decomposition or Byproducts: None Known. Hazardous Polymerization: Will not occur. 

## Health Hazard Data Route of Entry: INHALATION: May cause delayed respiratory disease if dust is inhaled over a prolonged period of time. SKIN: No. INGESTION: Ingestion of Iron Chromite may cause abdominal pain and nausea. 

### _..._ .

Iron Chromite, Page 1

April 1991 

# /'!2Jr

## Health Hazard Data (rottt.)

Health Hazards (Acute and Chronic): Respiratory disease may result from prolonged overexposure. Can cause eye irritation. Carcinogenicity. NTP: No IARC Monographs: Yes (Silica) Signs and Symptoms of Ezposure: Excessive inhalation of dust may result in shortness of breath and reduced pulmonary function. Symptoms of silicosis include impaired pulmonary function and wheezing.Aggravation of Pre-existing Conditions: Persons with impaired respiratory function may be more susceptible to the effect of this substance. Emergency and First Aid Procedures: IF INHALED, remove to fresh, air and seek medical attention for any breathing difficulty.IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. IN CASE OF EYE CONTACT, flush eyes imme:liately with water for at least 15 minutes. Seek medical attention if irritation persists. IF INGESTED, induce vomiting immediately by gi-ving two glasse: " water and sticking finger down throat. Never give anything by mouth to :::

~ 

### :aconscious person. Call a physician immediately. 

## Precautions for Safe Handling and Use Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratory protection. Recover uncontaminated material for use. Vacuum or sweep remaining material, keeping dust to a minimum. Waste Disposal Method: Dispose of unreclaimable material in a RCRA=approved waste facility. - Handling and Storing Precautions: Protect containers from damage and keep closed when not in use. Other Precautions: - Observe good personal hygiene. Wash after haadling. 

## Control Measures Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or is anticipated. OSHA standard 1910.134 or ANSI Z88.2-1980 speeifications are ' recommended. ' Ventilation: A system of local and / or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust is generally preferred because it can control the emissions of the cpntaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation, A Manual of Recommended Prac-

— tices', most recent edition, for detaiLs. Protective Gloves: Yes Eye Protection: Safety goggles are recommended. . Other Protective Clothing or Equipment: Use other protective equipment when necessary in order to avoid prolonged exposure to skin. Work and Hygienic Practices: Observe good personal hygiene. Wash after handling.



## - SARA Title III Section 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Plaaning and Community R3ght-to Know Act of 1986 and of 40 CFR 372.45: Component CAS # % by Weii}ht Iron Chromite 1.308-38-9 30 - 35% Cr 

### This information must be included in all h: 's that are copied and distributed for this m,ttriaL —

iron Chromite, Page 2

April 1991 f 

### ~~

### Material Safety Data Sheet

May ba ussd lo oomply wilh OSIIA'rt Flazard Communkallon Slandald, 29 CFfi 1910.1200. Standard musl bo consulted lor specHlc rraqulrKnents. 

### U.S. Department of Labor Occupstlonal Saf•ty and Health Adminittratlon INon-Mandatory Form) Form Approvod OM8 No. 1218-0072 IOEPITTTY (Aa Uad on LibM and LktQ I Noro: Bran#
~ .csa an nor p.

~ rrvrtrr.0. 1' any A'•m ia nor wpkcao+a. or q 5481 Ochre hhartn•aon lt av&,laD)v, cn• sp&C• musf be mark•d to nd; ca'• c Sectlan I 1.1LnUfac1ur44'3 Nam• Em•(q•I

~ 

### (Y+ ~+~b Sa j 

### fiern Color ac Chemical

,► Gdrau (Numos•. SvwoC C)y, Stan, an0 ZIP Cod•) T•I• or~ • N w~o~. ~r i~,~ at

~ at t4o4) j86- 

## ~ /66 P.O. Box 15 0 7 Oala Praparad , 7 Swisher Drive May 21 1986 

### Cartersville, Georgia 30120 Si4nalur• 01 Pr•puK (qodanaq 

# L!

~ 

# , k 

### Se•ction 11 -- Huarilous Ingredlentslldentlty Inlormatlon , Other Limits Huardou>t Compon•M1 (Sp•c i Bc Cn•m" I d•nt l ty; Common Nun•(st) OSHA PEL ACO1H TlV Rrrcomm•nd•d K loo! M548 Ochre (Fe?0-1-XH2O)Natural Iron Oxider Non Established; lOmg/L None

Note: Ochre is • listed as Hazardous because of t•he nuisance dust that may be created in handling t e pro uct. CASt4 1343

- 8 1

- 3

1 ( .

Sec(lon III — Physlcal/Chemical Characterisllcs Bai,ng PaM Sp•cifiC dravity (H = O . I) 

### N/A 3.2-3.E Vapor Prossurra (mrn Hq.) M41lln9 PoirM N/A • N/A Vapor Oansity (AIA • 1) Evaporatbn Ftale N A I (8utyl /ketate • 11 N/A Sduafity in Water



### Insoluble App•atancta and Oda



### Yellow Powder - No Odor Sectlon IV -- Fire end Exploslon Hazard Data Ftash Paru (M•Ihod Us•d) N/A Flammablra Umils LEL UEL • 

### N/ A 

### N /A Esunquisfwnq MWita N/A r-- -- - — - - — — - — - - : Sp+c,aJ Fra FiqhbnQ Procedu(t+s None Required '
Unusua! Fr• and Explosan Hazsrdlt No ne
IF•producfa locally) OSHA 174, 3apl Ig 

### /,;2 7ttcs+ittt-llr-rw ~ o~e~~ • t •Bed 3NON ie

~ p ~ e1d Q32iIn63a 3NON lvewdtnb3 )o 5un4tq0 •AIt>•tad i614j0 TINOI•LdO

~~~ d ~~ 3 'I
~ fNOI•LdO Aqo •nruep,d • 3NON ~~ 43ilIna32&N•NQ ~1 ~V~ +YI - - -- "'' ~ R 3NON R ~ I 'IfINOI,LdO I

. S sneVY3 Rm1 U ontiT I V•A 631MJ°JnS ,LnB 'IKNOI,LdO SI .Lsna 3JNVSInN L103 03A0Mdd'd aO,Lh2iIdS3M (odtl Ar>@'dS) uo"totd kotendsrd cainseoyy I0Jlu03 -- IIIA u 0 11 3 ;S

- - tuo!1n 

## ~~~~ teV10 ',LSna 3AISS33X3 3,LH3210 lIJIHM SNOI,I,vn,LIS QIOAY 8uvo1S Pvt 6utIDvtH w veM*1 19 ol euo!intm,d
TII3aNV'I a3A02iddV NY NI 7t1SOdSIa 31SYt•1 aI'IOS 7HW2iON ' DNIeYY Rtods!p •ueμ

' ',LSnQ 30 NOI,LV33J 3111 3ZIWINIW 01 S30I10V2id JNId33X3SnOf( QOOJ 3Sn PeII!dS to

peteeleF! e1 IeYeteyy eit0 ul uenvl e9 0l td•tS oan pue 6ullAueH a1sS jol s u ollneoaJd — IIA uol1DaS
Q3td I na32s< 3 NON sa , npow)d D!Y Icn ~ pue Aouv6nw: 

### 1 . ' NMONX 3NON •intod:3 Aq paleAsIGBr Anviouso tuol11Pu0D R*"YI

~ ssoj 9a64slotu oa anp oulciaeLlo xo SSaUAlp mtntod :3 ;o twotduiRg pve tu8±S

. ~ 1 03,L,S
~ ,LON a3,LSI'I ,LON LP+leln k! YHSO Cei+°1 W OHYI Ld1N

. -
r (wua+to Due IumY) tpir?vH utReH MojjeMB 

### lou op paqaosqe aq jouue, 's-lH9 'I OW •Oi AU-zsnp aauesinN

Luonsebul lu!lS 0 0 9e1*Wl :A+ni3 lo It?etnoti 

### NleCI pJMH 411 89 11 — M uOIlaaS

~ 

### x 9* 0 OpNrM NMON:{ 3NOPi UOPTIuM 1 40d D!onr ol 1UGTIIDuoO troa0 Aeyr 

# I tnoP,ersH

• ttonpaW8 jo uofl!sadwaoo tnopt*reH

. • 3NON {OJaAY o! eleuolriY) Rllliqlledwoou) hCRI IS uMOUx t3uoN v,oAr a won!au00 

# I I t,lan:un Nr•c+,s s1s0 MIAIlOsoy — A uo11DaS



## /;-V

## MATERIAL SAFETY DATA SHEET
Section I - Product Identification The Georgia Marble Company 1201 Roberts Boulevard, Building 100 Kennesaw, Georgia 30144-3619 Emergency Telephone: (770) 421-6508 Prepared by: Trevor G. Lamond, Technical Director Trade Name: Ground limestone/ Calcium carbonate Production Locations: Marble Hill, Ga, Sylacauga, AI Chemical Identity: Product consists of ground limestone (CAS Number: 1317-65-3), which is a natural ptoduct composed of Calcium Carbonate (CAS Number471-34-1) and from 1-3% Magnesium Carbonate (CAS Number 546-93-0) together with various other natural ingredients at trace levels. 

## Section II - Hazardous Ingredients

Hazardous Materials Identification System Health Hazard 0 Flammability Hazard 0 Reactivity Hazard 0 Personaf Protection E 

## Hazardous Ingredients TLV (mg/m; ) Silica, Quartz .1 (Respirable Dust) Calcium Carbonate Dust 10 (Nuisance Dust) This product typically contains less than 0.3% crystalline silica. : In addition, there are also small but detectable amounts of the following other naturally occurring chemicals that are known to the State of California to cause cancer, birth defects or other reproductive harm. This warning is provided in the absence of definitive testing to prove that these risks do not exist. These amounts are typical quantities and may vary slightly with different lots. 

# /p-f

## Chemical Name

Arsenic Lead 

## Typical Amount Less than 1 ppm Less than 1 ppm 

## CAS Number 7440-38-2 7439-92-1



## Section III - Physical/Chemical Characteristics Appearance and Odor: Fine, White Powder; No Odor Boiling Point: N/A Specific Gravity: 2.71 Vapor Pressure: N/A Evaporation Rate: N/A Vapor DensIter: N/A (Butyl Acetate = 1) Solubility in Slight Melting Point: N/A



## Section IV - Fire and Explosion Hazard Data Flash Point: N/A Flammable Limits: N/A Fire Extinguishing Media: N/A Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None 

## ection V - Re active Data This material is stable. Incompatibility: May react with acids to liberate carbon dioxide. This material will not polymerize. Hazardous Decomposition By-Products: None



## Section-Vl - Health Hazard Data Calcium Carbonate, the main component of limestones and marbles, is not on the NTP, IARC, or OSHA lists of carcinogens and there are no health effects associated with prolonged exposure to pure calcium carbonate. Crystalline silica (sand), a trace component of many limestone and marble powders, in its res irable form has been listed by IARC as a Type 1 carcinogen and the NT p P has stated that crystalline silica is reasonably anticipated to be a carcinogen. Also, prolonged exposure to crystalline silica has been found to cause silicosis, a noncancerous lung disease. 

## Exposure: Inhalation: Can be irritating to the respiratory tract. 

# R e Contact: Mild irritation. in Contact: No effect. Ingestion: Minimal effect. 

## First Aid: 

## 130

## Inhalation: Remove from area of exposure and to fresh air area.

Eye Contact: Flush eyes with water for 10 minutes. If irritation

persists, obtain medical attention. Skin Contact: Wash from skin with mild soap and water. Ingestion: Ingestion should not cause any significant health

problems. Sec tio n VII - Snill o r Leak Procedures Spill or Leak: Respiratory protection should be worn during clean

up to protect from airborne dust. Measures should be taken to reduce airborne dust during clean up. Waste Disposal: Shovel up material and dispose of in landfill.

Comply with applicable federal, state and local regulations. Section VIII

- 

## Special Protection Respiratory Protection: NIOSH/OSHA/MSHA approved dust respirator if T.L.V. is exceeded. Ventilation: Local exhaust: As required for dust to maintain airborne dust below the TLV. Mechanical: As required for dust. Eye Protection: Safety glasses or goggles. Special Protection: None required. Date Prepared: March 3. 1998



# 131

# C georgia marble c«T,pany
TNE NROVATOpS 1201 rober[s boulevard, building 100 • kennesaw, georgia 30144-3619 N STOME °A00UCTS fax: (770)421-6507 (770) 421-6500


# MATERIAL SAFETYDATA SHEET
Section I - Product Identification The Georgia Marble Compan y 

## 1201 Roberts Boulevard, Buildin g 

## 100 Kennesaw, Georgia 30144-3619 Emergency Telephone: (770) 421-6557 lCenneth J. Meeks, Safety and Training Manager Risk Management Chemical Name: Calcium Carbonate Chemical Family: Marble; Limestone; Dolomite Chemical Formula: CaCO 3 ; CaCO 3 ; MgCO 3 CAS Number. 471-34-1 Trade Name: Section 11- Hazardous Ingredients

Hazardous Materials Identification System 

## Health Hazard 0 Flammabili

~ 

## t y 

## Hazard 0 Reactivit y 

## Hazard 0 Persona/ Protection E Hazardous Ingredients TLV (Mg/M 1 

## Silica, Quartz Calcium Carbonate Dust .1 (Respirab/e Dust) 10 (Nuisance Dust) Calcium Carbonate may contain crystalline silica at leve/s between 0.01 % and 1.5% and varies naturally. There are a/so small, but detectab/e amounts, of the followin g 

## other naturally occunin g 

## chemica/s that are known to the State of Califomia to cause cancer, birth defects or other reproductive harm. This waming is provided in the 

## absence of definitive testing to prove that these risks do not exist. These amounts are typical quantities and may vary slightly with different jobs. Chemical Name Typical Amount CAS Number 

## Arsenic Less than 1 ppm 7440-38-2 Lead Less than 1 ppm 7439-92-1 l 3 z

## Section 11l - Physical/Chemical Characteristics

Appearance and Odor. Fine, White Powder; No Odor Boiling Point: N/A S p ecific Gravity: 2.71 Vapor Pressure: N/A Eva p oration 

## Rate: N/A Densit y : Vapor N/A (Butyl Acetate = ZA Solubility in 

## Water.

~ 

## Slight Melt 

## i ng Point:



## Section IV

-



## Fire and Explosion Hazard Data Flash Point: N/A Flammable Limits: N/A Fire Extinguishin g .

Media: N/A S p ecial F 

## i re Fight/ng Procedures: None unusual Fire and Explosion Hazards: None



## Section V

-



## Reactive Data This material is stable. Incompatibilit y : Reacts with strong acids to liberate carbon dioxide. This matenal will not polymerize. Hazardous Decomposition By-Products: None



## Section VI - Hea/th Hazard Data Calcium Carbonate is not on the N. T. P., I.A. R. C., or 

## OSHA lists of carcinogens. C ry stalline silica, a trace component of Calcium Carbonate, has been listed b y IARC as carcinogenic to experimental animals and has developed limited evidence for carclnogenicity to humans, however, lARC has determined that the carcinogenicity to humans is neither certain or 

# proven. Prolonged, repeated inhalation of crystalline silica can 

## cause silicosis, a noncancerous lung disease. 

## Exposure: Inhalation: 

## Can be irritating to the respiratory tract. E y e 

## Contact: Mild irritation. Skin Contact: No effect. Ingestion: Minima/ effect. 

## First Aid: Inhalation: Remove from area of exposure and to fresh air 

## area. Eye Contact: Flush 

## eyes with water for 10 minutes. If irritation

% 

## sists, obtain medical attention. Skin Contact: sh from skin with mild 

## soap and water. Ingestion: Ingestion should not 

# cause any significant health

problems.



## 133

## Section Vll - Spill_or Leak Procedures

Spill or Leak: Respiratory protection should be wom during clean

up to protect from airborne dust. Measures should be taken to reduce airborne dust during clean up. Waste Disposal: Shovel up material and dispose of in landfill.

Comp1y wlth applicable federal, state and local regulation s. 

## Section Vlll

- 

## Special Protection Respiratory Protection: N10SH/OSHA/MSHA approved dust respirator if T.L. V. is exceeded. Ventilation: Local exhaust: As required for dust to maintain airborne dust below the TLV. Mechanical: As required for dust. E'ye Protection: Safety g/asses or goggles. Special Protection: None required. Date Prepared:

March 4.1998

Prepared by Safety Department



## /3V

### MATERIAL SAFETY DATA SHEET
?NDUSTRIAS SULFAMEX, S.A. Distributor - North America •ampico, Mexico AGROMEX, INC: Mobile, Alabama FOR HEALTH HAZARD INFORMATION, CALL: -(205) 

### 443-5665 . Date of Revision: •'03/12/90
assssa :aaasasaasaaassamaaoaaaaaaaa sa=saza=ssassassassasaasaasssasasmaaa ssasa

~ = 

### - Product Name: TECMANGAM (R) Soluble Manganese Sulfate - Synonym: Manganese Sulfate (81-83.8 ) 

### - Formula: Mixture r ~

t E a 

### SCTION II. PRODUCT AND COMPONENT HA2ARD DATE 

### A. COMPONENTS: 

### Approx. Percent TLV** CAS Reg.No. ~ 

### *Manganese Sulfate 83.8 5 mg/m3 (as Mn) : 7785-87-7 

### Magnesium Sulfate •2.0 None . ; 7487-88-9 = Calcium Sulfate 65 None - 7788-18-9 - Water 1.0 None 7732-18-5 *Principal hazardous component **See Section VI-A for additional information on expoeure limits. B. PRECAUTIONARY LABEL STATEMENTS: ._ 

# ; , . . . . . .- _ . '
_ , •_..

. WARNING! MAY BE HARMFUL IF INHALED j

CAUSES IRRITATION ;• ' Avoid breathing dust. 

### Avoid contact with eyes. Avoid prolonged or repeated contact with skin.
... 

### Use with adequate ventilation. w Wash',thoroughly .after handling.
~

. .. . . .. . . . 

### FIRST AID

~ 

### ,_ In case of contact, 

### immediately flush eyes with plenty o£ water for at least 15 minutes. •:_Ca11 •;',a ,physician.;, -Wash ' skin with soap and plenty of . : 'water..

- ,Wash

~ 

### clothing before : reuse. 

### In case of irritation of eyes, nose, and throat, 

### remove from exposure,,treat symptomatically, and call a physician if.symptoms persist. r ,: 4

_ _. .. ir1SDS . 001:1 -



### , - 

### 03/11/90

, ~ 

### . . .

.. ,.



## • _ /35• '1 . 

### Since emptied packages retain product residue, follow label warnings even after

~



### package is emptied. Notice: Manganese Sulfate may discolor ornamental surfaces, rock, tile, masonry, etc. Contact with these surfaces should be avoided. If contact occurs, wash area immediately with water. _
iss

~ asssissasasslasasisisaass

~ asssssaasassssassisaslsassisisaasisaa

~ lsassailsiaas a
•'.► . 

### SECTION III. PHYSICAL DATA - - -'=• - "="r
~ • y.J . 

### - Appearance and Odor: White to cream-colored powder, practically odorless. - Boiling Point: Not applicable. 

## - Specific gravity (H20 = 1): 0.81 at 20 ° /20`C - Vapor Pressure: Not applicable. - Percent Volatile by Volume: Not applicable. - Vapor Density (Air - 1): Not applicable. - Evaporation Rate: Not applicable. - Solubility ia Water: Appreciable (approx. 99X).

=- !lssiisaasaaaisiiisasasssassssisasssasissiassaiizaaasasaaasssas:sssasassisssssliss

, ' • '

. . . ' . .: . , 

### SECTION IV. FIRE AND EXPLOSION HAZARD DATA 

### - Flash Poiat: Not applicable (Noncombustible). - Flammable Limits: Not applicable. 

### - Extinguishing Agent: Use appropriate agent for surrounding fire. - Special Fire-Fighting Procedures: None known to Sulfamex. :-• '= - - Unusual Fire and Explosion Hazards: None known to Sulfamex.' ....•'_ .- . ~~_~

J

### SECTION V. REACTIVITY DATA 

### .- ':

~ 

### • - Stability: Stable. 

### - Incompatibility: None known to Sulfamea. - Hazardous Decomposition Products: Decomposes to oxides of manganese and sulfur.

, - Hazardous Polymerizatioa: Will not occur. "- . : . : : -.t'

~ 

### `

~ 

### `"'. _ : . •

assasasasssssssasszaassiasaaszasss

~ is=msssssssslssassasssssassalslasssssssaslislss!

. . - - - • . . _ :.':
. - ~ 'j . . 

### SECTION VI. TOXICITY AND HEALTH A. EXPOSURE LIMITS

. • . . ~ . -.. :`,z:. ~ a"c.:•
~ .. 

### - OSHA Permissible Eaposure Limit (PEL): . Manganese sulfate (as "lin):.`•

- 't6~.~ , `. 

### 5 mg/m3-C. - _ . • _ ._ . _ .. - ... > : ._ : T i :

~ 

### ...:ri: r x . ~~ . 

### - Threshold Limit Value (TLV): Manganese Sulfate (as'Mn):'

~ 

### 5mg/M3-C, ACGIH, 1982. 

### - A NIOSfl industrial hygiene analytical method_for.manga'nese • is'available:, (1) - An industrial hygiene analytical method for Manganese Sulfate is available r, :+. i . ?. ~ .:.3- ~ii~ S :r:. i`a
~ '.'i.2 

### to health aad safety professionals upon request. ... -.
.. B. EXPOSURE EFFECTS _ 

### Inhalation: May be harmful if inhaled. May cause irritation'of the nasal passages. Eyes: Dust may cause irritation. Skin: Prolonged or repeated contact may cause irritation. 

### e 03/12/90 - MSDS: 001:1

. 

# !3~C. SKIN A1dD 9;Ya rtcvicvllv v



### Safety glasses should be worn in any type of industrial operatioa. Protective 

### gloves should be worn. _... D. OTHER CONTROL MEASURES An eye bath and washing facilities should be available. Wash thoroughly after handling.
as:aasas sasaasaasassasasaaaaasssssaasassssaassaassasasasasassassasssaasaaslaasaaaas 

### SECTION VIII. SPECIA.L STORAGE AND HANDLING PRECAUTIONS 

### Since emptied packages retain product residue, follow label warniags even after package is emptied.
aaaa saiaasiaaaisasiiiasass

~ saaaaaasaaaaaasiasassaasasasaassaaasaaaaaaiasaasiasasaii 

### SECTION IX. SPILL, LEAK, AND DISPOSAL PRACTICES Steps to be taken in case material is released or spilled: Collect and contain f:r salvage or disposal. Waste Disposal Method: Landfill. Observe all federal, state, and local laws concerning health and environment.
a ssaa saasaasamasasxa=ssassssszaas=smassaa=so=ss=asa==ss:saoass=sssssisaasss:sisosszs 

### SECTION X. ENVIRONMENTAL EFFECTS DATA A. SUIrMARY: This product has not beea tested for eavironmeatal effects. However, some laboratory test data aad published data (7,8) are available for all of the major compoaents of this product, and these data have been used to provide the followiag estimate of environmeatal impact:" This product has a low biological oxygen demand, and it is expected to cause little oxygen depletioa in aquatic systems. It is expected to have a low - potential to affect aquatic organisms, secondary waste treatment micro— organisms, and the germination and growth of some plants. If diluted with a large amount of water, this product released directly or indirectly into the environment is not expected to have a significant impact. a


### SECTION XI. TRANSPORTATION DOT Hazard Classification: Not regulated'-by"DOT ssss:sssssssassssss:ss:assssssssssssassssassssaa3aasssasasass:asssas !ia! 

### SECTION XII. REFERENCES 1. NIOSH Manual of AnalyticalMethods , 2nd Edition, Volume 2. Issued by the r: National Institute for Occupatioa.al Safety and Health. Washiagton, U.S. r
~ 

### Government Printing Office, 1971, Method S5. =. 2. H..C. Hodge and J. H. St4rner, Tabulation of toxicity classes. Am_Ind:

~ 

### ". Hyg. Assoc. Q. 1949; 10:93-96. rMSDS: 001:1 

### 03/12/90


# ' 137

### C: FIRST AID

Inhalation: Remove from exposure. Treat symptomatically, and get medic'al attention if symptoms persist. I 

### Eyes 

### : Immediately flush with plenty of water for at least 15 minutes and get medical attention. ' Skin 

### : Immediately wash with soap and plenty of water. Wash contaminated clothing before reuse. D. ANIMAI. TOXICI,TY DATA The compdsition of this product varies from one batch to another; however, toxicity data felt to be representative of this variable product are provided below: Toxicity Test Species Result 2) Classification (3) 

### Acute oral LDgO Rat 1600-3200 mg/kg Slightly Toxic Acute oral LD50 Mouse 800-1600 mg/kg Slightly Toxic Dermal LD50 Guinea pig >1000 mg/kg Skin irritation Guinea pig Slight Eye irritation Rabbit Moderate In the 1930's, manganese ore mining and processing operations were studied,.and it was determined that chronic overexposure to manganese ore dust produced a disease of the nervous system with symptoms similar to Parkinson's diesease: ' tremor, rigidity of facial expression, stooped posture, and stiffness and slowness of movements. (4) Other reported illnesses include pneumonia and metal fume fever. (5) Although these effects in humans have occurred from exposure to manganese ore, manganese dioxide, and finely divided manganese, a thorough search of the world medical lfterature has disclosed no reports of such effects occurrinFrom exposure to manganese sulfate, the form of manganese present in Tecmangam-r Eastman Chemical Products, Inc. reported that no neurotoxicity, pulmonary disease, nor metal fume fever have been seen in Eastman employees who have worked with Tecmangam for many years, although irritation of the nasal mucous membrances, skin irritation, and eye irritation have been observed. (6)

s~ . sssassssasssaaassasaasasaassaassasasssassasssssassassssasssassssssssasassaaasasas 

### SECTION.VII. PERSONAL 1'ROTECTION AND CONTROLS 

### A. BTSPIRATORY PROTECTION An appropriate NIOSH-approved respirator for dust should be worn if needed. B. VENTILATION 

### General: Recommend at least 10 air changes per hour for good general room ventilation. Local Exhaust: Recommended to control dust. See Section VI-A for - information on exposure limits. Maintain workroom air concentrations below irritating levels.
MSDS 001:1 03/12/90

• ~ lJ~~3. R.H. Flinn, cc A

~ L .



### Public Health Bulletin No. 247 

### , 1940. 4. A. Hamilton and H.L. Hardy, Industrial Toxicology 

### . Acton, MA, Publishing Sciences Group, Inc., 1914, pp 127-130. 5. Battele's Columbus Laboratories, Wafer Quality Critical Data Book Volume - _3 - Effects of Chemicals on Aquatic Life 

### , Selected data from the literature through 1968. Washington, U.S. Environmeatal Protectioa Agency, Project No. 18050 GWY, Contract No. 68-01-007, May 1971. 6. J.E. McKee and H.W. Wolf, Editors. Water Quality Criteria 

### , Publ. No. 3-A (Revised). State of California, 1963.

s s ssaassssassasas::asssassassssaxaaaassasxsasaa=aassxmasssssaasasa:sssasas=sasssss 

### The information contained herein is furnished without warranty of any kind. Users should consider these data only as a supplement to other information gathered by them and must make independ?nt determinations of suitability and completeness of information from all sources ,to assure proper use and disposal of these materials aad the safety and health of employees and customers.

Safiisissasasssassasasiaas saasa

~ saisa=ass sis aassailsa sassasaa asssissassas aassaasaa

MSDS : "001 : 1 

### 03/12/90 

## )3S

## • . . . . .. ' • .

. .. . . ~ 

## .. • . i e ~ ~ .i -t:. `.

~ , - ~ ~ i~ +- ~ :i

~ -{ ^ f , . a •. '

. . . . ' .

' sr~ .G....a. .
.. . ?•vJ-.1 .`•..ri ~~ ' ~~~.L~.~ . •.: '1

~ . 1.

~ ...t ~~~
~ .. _ 3 t

~ (.

~ 'i..

~ iH

. .,. .i •.a __ 'n:

.. - ' •`l ~ _- ~ !_ .S ~# • * ~ .y~ r = . . - -v .. . ...:.. ..: . ~~ • ` ~ r = ~ •

~ ~ 

# a_' = '1 vG'

~ 

### 37 ~'1 

### 3 `Sd • ~ L~ 

# :•. - .

~ 

# . . `' • 1

- • 

# i a

.•:IiTS

~ .I:.. ~~~ tr.'... ~ ii:.- .''_ :r ~lJ?~ ~°-' ".
~

.a-7r'SC7:

~ 'T7

~ :•r

~ ..j' .. — i ----+.- ~ i.- 't

~ _..._...•



## . _ _ ~ 

## . . _ , . A!

, _ -1

~ 

## i'S.J ~, ~ .!'~ 

## .. : , t :1`. . •
~ 

## ' •

.... ~ 

## . . • ... • .ti ~~~l~.~ _~ 

## _ =t

~ 

## •..
~ .. •1- ~ 

## •.L.

~ 

## ' L r? M1•• 3~ , 

## 1: ~N • ~iV • .~ 

## -' ', •

~ j 

## . • • ' .__.._ ~ i_._._. 1 -- .. . ...

~.a~:~ _a•.:•r•...

~ . .' ._ . . --•--' - _ . . . . . ., .,.r..... .._ . ._. ~

.~ .. . ....... .. - . '

~ ... . ....I

. .. . ~ . .. ~:~a~ .i . 3. .- . . •.. .. - - '

, . ... J
. . . . ... . . _1
~. ~ .• - . • t .

. i

~ i

.. ~~ • . • . _ ... .. '

. . . .... .•.... 1- -.•..Y':?.. ._ • •

~ .._ ?.. f •

. ..i. ,;31 _.._ y . '

..

.. _ .. ._ • ... . ._ . _. 7'

. . ~ ~ , _ •._. . , . . . C . .. . . _ . ~ _ ~ . .. _ . . . _ _ . _. ~ ~ ~ ~ . .♦ ,i . . ~ _ ~ _ ~ . I
~ _. ~ _ 2
~ • 3 : ..
~ = S _:
~ ~. ~ 3 .
~ 3 -
~ . _. . -. . . . _ ~ i ~ : '. _ . _

_

t'

. • . i

~ . . . • I •
. .. ."]♦ . ' . . I

# 7'V 7 f 

# ~~ - AlriERICAN MICROTRACE



# MSDS

Product Name:':Maa=Gfo®`Man=Gro'® AS" 

### ~ Chemical Name: Manganese Sulfate Monohydrate
Contact American MicroTrace

569 Central Drive, Suite 201 Virginla Beach, VA 23454 Fax Phone No: (804) 463-8156 Molecular Formula: MnSO4H2O Molecular Weight: 169.01 Phone: (800) 544-3155 or: (402) 729-6191 

### Date Issued 2/27/91 For Emergency Assistance Involving Chemicals - Call Chemtrec (800) 424-9300

i.s IC IT. 

### Component.

• Manganese Sulfate Monohydrate CAS NUMBER PermLssible Air Concentration: Manganese Sulfate Monohydrate 5 mg/m 3 Ceiling (ACGIH) (As Mn) Percent.• 90'/0 7785-87-7 Ferric Oxide - 5 mg/ 1113 1.5% 1309-37-1 

### Aluminum Sulfate 12 mg/m 3 1.5% 1344-28-1 Silica Dioxide 5 mg/m 3 1.0 0 /0 7440-21-3 G 

### First Aid Measures Ingestion: If large amounts are ingested, if victim is conscious, immediately give 2 to 4 glasses of water, and induce

vomiting by touching finger to back of throat Do not give carbonates. - Get rffedica.l attention immediately.

~ rt •• ~~; ~ , c ~ . 

### Eye Contact• If eye irritation exists, flush thoroughly with plain water. Skin Contact.• If sldn irritation e•ai.sts, wash with soap and water. D. 

### xarards Tnformation J~ 3~ ""'Health Effects"
_ . ... . 

### Inhalation: 

### May cause irritation of nasal membtanes and upper respiratory tra Ingestion: of large amounts may be harmfiil. Eyes: Contact maySkin: Contact may ccause imtation. -- - +r'` Mediccal Conditions Possibly Aggravated: Respiratory problems could be ag,gravated by inhalation of dust Unusval Chronic Tox.idty: Some manganese compounds are known to cause acute and chronic toaiary which primarily invobes the central nervous system, however, there are no known reports of such effects from exposure to manganese sulfate. Chronic exposure to silica dust may cause silicosis, a fibero[ic lung disease. "Fire and Explosion Data•• Flash Point: N/A , Fire and Explosion Harard: Negligible fue and explosion hazard in dust form when exposed to heat of tlame Flammable Iimit N/A Unusual Fire and Explosion Haaards: None 5/15/91 

### i1-11e)~ 

### precrautions/Procedures

Fire Extingui.shing Agents Recommended: CDry chemical, carbon dioxide, water spray or foam) as appropriate

~ 

### for surrounding materiaL

. Fire Estingu.ishing Agents to Avoid: None Spec3al Fire Fighting Precautions: Use self conta:.-.-

~ 

### d breathing appamtus Englaeering Controls: Use containment and/or loc-al exhaust ventilation to control dust Normal HandlIag: Avoid contact with eyes, sidn, and clothing. Avoid breathing dust. Ma3ntain good

housekeeping practices. Storage: Keep dty SpLll or Leak: Collect and contain for salvage or disposal. Vacuum or sweep keeping dust to a minimum. Special Precautions/Procedures/Labels Instructions: See "Normal Handling" Note label signal words'Warning!' Personal Hygiene: Wash thoroughly after handling and before eating or smoking. E )Personal Protedive EqWpment Respiratory Protec.:on: Use NIOSH-,MSHA approved dust respirator if irritation exists or in dusry areas which --- -- ezceed mg/m 3 .. - Eyes and Face: Glasses, goggles, or face shields are recommended if irritation exists. Ha.nds, Arms, and Body: Gloves and protective clothing should be used if ircitation exists. Other Clothing and EquipmenL• None fr. Physical Data Descript3on: Light Tan to Pale Gray hlaterial Boiling Point• N/A ' Solubility in Water: 50a/a by weight

•:~W• ~ ~..: 

### PHs 3.0-5.0 ® 10 0 /o Solution Vapor Pressure & Density: N/A

_ Melting Poinh Decomposes above 450° C.


### Stability: Stable under normal temperatures and pressures. Polymeriration: Will not occur Incompatibilities: None Decomposition: Thennal decomposition may release toxic fumes of manganese. Possibly o:ades of sulfiu I Environmental 

### EPA Fiazardous Substance: Yes Federal RQ Quantity: 1000 LB/454 KG DOT Hazard Class: N.O.S. Orm E NA 9188 RQ Waste Disposal Method: LandPill or field RCRA Status of Unused MaterIaL• Not listed application at agronomic rates Refzrences 

### -... _ . --. ~ .., 

### PearmLssiblle eoncentratioa references: "'I'LV" -"Threshold Limit Values for Chemicral and Physical --. -_ Agents in the Work Environment' 1084-85 GACG" Harard Information References: "Merck Index" 10th Edition, 1983. Merck and Company, Inc. & AdditionalInformation 

### This chemical may be subject to the reporting requ'uements of Section 313 of Tide III of 49 CFR 372 of the Emergeney Planning and Communiry Right-To-Know Act

Tbis matertal safety sbeet is o,(jered solely foryour informatton and investigattort It provldes no warranties ettber express or impliecl; and 

### assumes no responsibllity for the accurary or completeness of tbe data contained beretn, 5/15/91

`
~ t!

### INIATERIAL SAFETY DATA SHEET ZINOX NPCA - FLNi1S HAZARD RA7Z\G Health I Flammabiliry p Reactivity 0 Maximum Personal Protection E -)ECTION I MANL'FACTL'RER EMERGENCY TELEPHONE CHE'v1ICAL NAME TRADE NAME CHE1IICAL F.aMILY FORM U LA CAS NUMBER AMERICAN CHE:vSET CORPORATION P.O. Box 1160 East Helena, MT 59635 (406) 227-5302 ATTN: W. H. Porter or Dan Brimhall Zinc Oxide ZINOX Zinc Oxide Zn0 1314-13-2 SECTION II ELkZARDOUS INGREDIENTS PEL + TLV ZI`C OXIDE 1 7C RESPIR.ABLE DUST 5 mg/m' 97.090 (Typical) (94.5% Min.) TOTAL DUST 10 mg/m 3 Exposure is governed by the 8 hour TWA established for Zine Oxide. Zinc Oxide is not carcinogenic material as listed by OSHA (29CFRI910) or ACGIH (Appendix A. Threshold L imit V_!aes ,`or Che:nical Substances 1984-1985). SECTION III PHl'SICAL DATA Boiling Point (f): Specific Gravity: Vapor Pressure: Percent Volatile by volume (90): NA H ; 0=1 5.6 NA p% Vapor Density: Evaporation Rate: Solubiliry in Water: hielting Point: Appearance and Odor: NA NA Less than 1 k. 3590 °F Fine powder. Cream yellow

. No odor

. SECTION IV FIRE & E.XPLOSION HAZARD DATA Flash Point Flammable Limits 

### LEL UEL NA NA NA Extinguishing Media: NA '+ecial Fre Fahting Procedures: None known aal Fre Fi¢htins Procedures: None know'n. aECTION V HEALTH HAZARD DAT.s► Threshold Limit Value: See Section tI Signs, Symptoms, and Effects of Overexposure: Nausea, chills, diarrhea. May cause upper respiratory irritation; skin irritation (oxide pox); fever, eye irritation With redness, pain and conjunctivitis; preexisting lung diseases may be aggravated by exposure. Could result in respiratory irritation; preexisting lung diseases ntay be aggra- %ated by exposure. Could result in respiratory disease if over exposed on a chronic basis. _ Primary Routes of Entry: Inhalation and/or ingestion. Emergency and Frst Aid Procedure: Remove to fresh air. Lay patient down. Cover With blanket. If irritated, flush eyes and skin with large volumes of fresh water for 15 minutes. Refer to MD. SECTION VI REACTIVITY DATA Stable X Unstable Conditions and Materials to Avoid: Mass build up under reactive conditions such as but not limited to acids. Zinc Oxide may react violently a'ith strong reductaats such as orgar.ic compounds, including chlo:inated rt:bber at temperatures over 420°F, (a Flammability rr.action w•ith linseed oii was reported once), and ntetals includirtg but not limited to Mg. Hazardous Decomposition Products: Above melting point (3590°F) zinc fumes may result. Hazardous Polvnurization: Will not occur. SEC'rION VII SPILL OR LEAK PROCEDURES Steps to be taken in case material is released or spilled. Clean up w'ith vaccum or conventional tools. Avoid dusting. Waste Disposal Method: Approved land fill. SECTION VIII SPECIAL PROTECTION INFOR:'1TATION Respitatory Protection: Cartridge type filter or approved dust mask. Refer to Respiratory Protective devices approved by Bureau of Mines Circular IC 8436. Ventilation: To keep below listed TLV in Section 11, use general dilution type ventilation. Protective Gloves: Wear if skin contact is probable and skin is sensiave. Eye Protection: Safety glasses or goggles. Other Protective Equipment: Long sleeve shirts if contact is probable and skin is sensitive. SECTION IX SPECIAL PRECAUTIOi\S .autions to be taken in handling and storing: Keep lids tightly sealed. Store in cool, dry place. ier Precautions: Do not take internally. Avoid prolon¢ed contact w•ith skin. R'ash with soap and water after contact. SECTION X SARA TITLE IIIThis product contains a zinc compound (Zinc Oxide) and is subject to the reporting requirements of Section 313 of 'I itle III of the Superfund Amendments and Reauthoriration Act o f

1986 and 40 CFR Part 372. Date: IMarch I, 1989 (Rev. 4)



### ~ FY 

### ~ '

# 1

. . . .



# . •

~ 

# .

P.O. Box 1178 Columbus, GA 31902-1178 Telephone 3341291-0930 - Facsimile 3341291-3237

ul u 1' • 1iT 

### To: David Ousley, Alabama Department of Environmental Management From: Robert Maner, Environmental Managn Re: Fluorine Mass Balance Date: May 28, 1996 In our conversation last week, you suggested it might be beneficial to perfotm a fluorine mass balance on a dried and fired brick from Boral plants in Phenix City. I learned that a fluorine mass balance had been performed while these plants operated as Bickerstaff Clay Products. I have summarized the results below. Plant/ Product Main Body

Constituent dried bricJc

fluorine content fired brick

tluorine content fluorine

evolved '/•

evolved emission faaor

Ob Fff / ton ware Atlanta, GA Plant Sbale 606 ppm 280 ppm 326 opm 53.8 0.69 Bessemer Buff Bod Shale 679 ppm 339 ppm 340 pom . 50.1 0.72 Bessemer Standard Red Shale 603 ppm 166 ppm 437 ppm 72.5 0.92 Phenix City Plant I Alluvial Clay 454ppm 84 ppm 370 ppm 81.5 0.78 Pheaix City Plant 3 Alluvial CI 348 po 56 22m 292 m 

# 1 84.9 0.61 1) A buff body brick desaibes a lighter color brick as a result of lower iron centent in raw materials. The raw material may aLso have a higher alumina content and higher matucing tempesariue. 2) The emission factor is developed using the following formula:
= fluorine evolved (ppm) x 2000 pb/ton) x 20 Ib HF 1,000,000 x 19 Ib F

= 292 paFts gaeFiAe 2000 Ib 20 Ib HF 1,000,000 ton 19 I ~ F 0.61 lb HF / ton fired ware 

### These mass balance results were produced by Clemson University using a pyrohydrolysis test and are relatively consistent with mass balance results for other Boral plants. The Phenix City Plant 3 stack test that I referenced in the earlier emissions inventory for the Phenix City plants was also conducted by Clemson University. An emission factor of 0.45 lb HF / ton of fired ware is produced by dividing the average emission rate by the production rate during the test. This is 74% of the emission factor produced from mass balance data for the same plant. This is consistent with experience that shows actual stack emissions to be approximately 65% of predicted maximum emissions using the mass balance technique ("Monitoring for Hydrogen Fluoride Emissions in the Ceramic Manufacturing," Ceramic Industry Magazine, 143 (1) p. 38-40 (1994). 

### The emission factor derived from the stack test at Plant 3 appears to be the most conservative emission factor (produces the lowest estimated emissions) based on the compilation of all data. The potential production of each plant coupled with this emission factor produces potential emissions of hydrogen fluoride in excess of ten tons per year. Based on this estimate, I will continue to assume that our manufacturing sites are Title V major sources. If you have any questions, please call me at 334-480-2487.


## /q~3R. - ~ ; s - " -

,~ ;t,~-~.-~ .. . - • .. ~ -, , ~ ; :-'

~ ,^y =~'- ~ ~ ;'•

~~ ^,.,

~ .

T~z ~

. . ~ ' ~ _ . •:, ~ 

# EPA iVIACT Information C

~ 

### 1 

# Request Response

• . ~ . }T: _ ~ ._ ~ . 4 ..-

; ;r•m,,, ~.~_ ~~• ~.. ~ 1 -._. ~ ,.....+ ~ : '

. ~ . } ~ --- -

..• ~ , _ _ -. ~,r~,.~,~ - ; ~, ~~~ .

,ti - - - -• ~ ., ' ~ - - - - ~ __, ,•.- - - - -

ti

..+• y ~.~_ ~ _ . _ _ -. + ~~ -t. g-r ~~~_ : ..- y- '~ ~ - _ ~ - " - -. 3.-

.- - -- - ' *-. - -- - - ~ • - - -- -' ,. ~ . _ . .. -. A 

# ti
b
bf ~

F ~

~ ~•. ~.~ 

## ,,., , ... _.__.. ~ ~~-~ 

## '..--:-•.- ~'~ 

## - - _.- - - - .

I

, .~ ~ . — - . . ~..~4~.4~~ ., . ., ~ :r . •:_'

~ y.,

~ -..

~ _ _ . `

~ - ._ , - .

r - - ,. ~ T ~ '• ~ a - al

~ eT --.. —_ - ~

4 ~ ~

~ ~



## •]'llr!

# MACT Information Collection Request Response from Boral Bricks, Inc.

Table of Contents 

# • Information Collection Request • Appendiz A - MSDS's

J ~~

### Enclosure 2

INFORMATION REQUEST FOR BRICK AND STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS Instroctionc 

### Please return the completed information request to: Bruce C. Jordan, Director Attn: Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at (919) 541-5435. 

### This information request should be completed for each facility that manufactures brick and structural clay products, including facilities that are not major sources. Information is requested for all processes at your plant that emit hazardous air pollutants (HAP's), including those processes that are not associated with brick and structural clay products manufacturing. Sections II through VII request information specific to brick and structural clay products manufacturing, and Section VIII requests information on emissions of HAP's from other processes located at the facility. Processes that may emit HAP's include those processes that use or handle any materials that contain a HAP compound, all processes with elevated temperatures, and all other processes in which HAP compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is included as Attachment 1 to this information request. Attachment 2 provides background information on the requirements of the Clean Air Act and explains how the information requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations and acronyms used in this information request. Several tables are provided throughout the information request for your convenience in answering the questions. An example response is given (shaded first column or row) in each table. If additional space is needed to respond, please make copies of applicable pages. If necessary, please make copies of this inforniation request for additional facilities. No additional emission testing or monitoring is required to respond to this request. II. General Facility Information A. Name of company Bora:, .'

~ 

### qks, Inc. Nanie of facility Phen
~ 

### _ City. Plant 4

Page 1 of 31 

# iLA,

### Facility address: No. and street 100 Brickyard Road, Plant 4 

### City Phenix City 

### State Alabama 

### Zip 36865 

### Latitude and longitude coordinates of plant: Lat (N) 32° 23' 46", Long (W) 85 0 00'29" 

### Standard Industrial Classification (SIC) Code(s) of brick and structural clay products manufacturing operations 3251 

### Dun and Bradstreet No. 00-327-5682 

### Total No. of employees for company > 1,500 

### for facility 101 

### (If facility is a foreign subsidiary or if company has foreign subsidiaries, include number of employees not based in the U.S.). Please complete the following shift information for the facility: Shift No. of employees Hours per shift Days per year 1 89



## 1 8- 12 

## 8 359



## 365 2 5



## 3 8 —12 

## 8 359



## 365 3 3 8 365 B. Respondent name Andrew Wichers 

### Respondent title Re,gional SafM Manager 

### Respondent address (if different from above) and telephone number: No. and street 100 Brickyard Road 

### City Phenix Ci ,

t ~ 

### State AL 

### Zip 36865 

### Telephone No. (334) 480-2407 

### Name and telephone number of technical contact person (if different from above) Name David Johnson 

### Phone No. (334) 480-2487


### Page 2 of 31 /`/7

### III. Information on Onerating Permits and Applicable Federal Emission Standards

A. Please provide copies of relevant parts of all operating permits and permit applications for your facility. Relevant parts include the sections that provide specific information and data on: processes that emit HAP's; the use of HAP- containing substances; emission levels for HAP and surrogate pollutants (i.e., VOC for organic HAP's and PM for metal and other particulate HAP's); emission control device design and operation; monitoring and operation and maintenance (O&M) procedures for control devices; and generation and releases of other media such as wastewater and solid waste that are associated with the operation of air pollution controls for brick and structural clay products manufacturing processes. If the operating permit or application contains the same information requested in any part of this questionnaire, you may respond to the requested information by referencing the page or section of the permit/application to avoid duplication. If you reference your permit or application, you must supplement your response with all of the additional information requested in this questionnaire that is not included in the permit or permit application. If you prefer, you may submit the requested information from your permit/application on a 3-1/2 inch diskette. B. If any source or emission unit at this facility is subject to a New Source Performance Standard or other Federal emission standard, please identify the source a.nd applicable standard. Examples of applicable NSPS include 

### 40 CFR 60, Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing Plants, and 

### 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers in Mineral lndustries. No NSPS applicability determination has been made for this facility at this time

IV. Brick and Structural Cla,y Products Production and Raw Material Consumption Information A. Please provide the 1996 production rates and the current production capacity for each type of brick and structural clay product manufactured (e.g., structural brick, clay sewer pipes, structural clay tile, etc.). Note that production data should be provided in units of tons per year (tons/yr). Product 1996 prodt,

~ 

### : -:on (tons) Production capacity (tons/yr) Bricks (Fired Weight) 199,464 228,601 Page 3 of 31 

## / C/P

### B. Please provide the type and amount of each raw material and body additive used in 1996 for manufacturing brick and structural clay products at your facility. Examples include clays, shale, and any additives that are mixed into the raw material prior to forming. Indicate additives by chemical compound, rather than by trade name. If the information requested is contained in your facilit}rs operating permit, you may reference the applicable sections of the permit rather than providing the information below.
Raw niateriaUbody additive Amount used in 1996 (tons/yr) Lignosol (wet weight) 260 Manganese Sulphate (dry weight) 0.15 Manganese 325 Mesh (dry weight) 2.58 MRC Grog 48 Mesh (dry weight) 10.80 Ochre 548 Dark (dry weight) 25.03 Redart Clay (dry weight) 23.13 Hallmark Fire Clay (wet weight) 3,750 Mary Lee Grace Chapel Clay (wet weight) 1,000 Rome Shale (wet weight) 27,200 Clay (local mines) (wet weight) 197,000

C. If available, please provide a copy of the MSDS's for the raw materials and additives listed above. See Appendia A
D. If available, please provide chemical analyses, including fluorine, metals, and organic content, of the raw materials listed above. Not Available

Page 4 of 31 

## ld~

### E. Using Table 1, 

### please provide information on the consumption and HA.P composition of all glazes and colorants that contain HAP's or HAP precursors and that your facility applies to brick and structural clay products. Indicate whether the coatings are glazes or colorants. Also indicate the type of product that the coatings are applied to and the total weight of coatings used in 1996. If the glazes or colorants are formulated at your facility indicate so and provide the production capacity. List each ingredient of the glaze or colorant. Beside each ingredient, indicate the total amount of the ingredient used in 1996. If the informa.tion requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. F. In the space below, please indicate any glazes or colorants used by your facility that do not contain HAP's and are substitutes for HAP-containing glazes or colorants used by your industry. Indicate which HAP-containing materials the non-HAP glazes or colorants replace. Describe any limitations on the use of those substitute glazes or colorants. None

G. If your facility colors brick and structural clay products by flashing, please indicate the types of substances used to flash the products and the amounts of those substances used in 1996. Substance Amount used in 1996 Units (specify) Natural Gas Unknown — Not Measured Not Applicable Propane (back-up fuel) Unknown — Not Measured Not Applicable
H. If available, please provide a copy of the MSDS's for the glazes and colorants used by your facility. If your facility prepares its own glaze, please provide any available MSDS's for the glaze ingredients. See 

### Appendix A 

### Page 5 of 31 /S-Z)

### TABLE 1. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND COr.nua 

### NTR

I Type (e.g., glaze, colorant) EXAMPLE: Colorant/Coatings Glaze - 

# I Type of product glazed or colored Stractural tile Brick 

# 1,982 1996 consumption (tons/yr) I Produced at facility? (yes/no) I Production capacity (tons/yr) Total usage (weight) of each ingredient (that is a HAP, contains a HAP, or is a HAP precursor) in 1996 

# 1,140 r":



# _., '

_ - .. 

# -: -_ . --
_ 

### Totat 1996 Ingredient : `: ` us
~ 

### ge, toas:



# , • -_- ._..._ . _

_ . Cr203 _..

0.?.3 Coa 0.18

_ . 

# MQo, _

- _.. .-_ ----- - --

_ ;:=_. _::_ _

. :.,

~ 

# - .:

~ 

# ; ------------_- - -

,. ,. 

# - - --- -- No

Not Applicable

Total 1996 Ingredient usage, tons

Iron Chromite 

# 1.75 Lim e 

### stone 

# 34.73 Manganese 

# 0.15 Sulphate 

### Mangane se 325 2.58 

### Ochre 548 25.03 

### Zinc Oxide 

# 4.55

If additional space is required, please make copies of this page. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table.

Page 6 of 31 

## 1
~ 

## -f

### V. 

### Description of Brick and Structural Clay Product Manufacturing Processes

A. Please provide a simple process flow diagram for each brick and structural clay product manufacturing process line. An example process flow diagram is provided in Figure 1. A diagram of the plant layout with all processes and emission points clearly labeled is also acceptable. Assign a unique identification number (ID No.) for each process that has associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. Please identify all emission points, including those that do not emit HAP's. For emission points that are vented to an air pollution control device (APCD), assign an ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are uncontrolled, assign an ID No. to the uncontrofled stack (e.g., S-1) or building roof vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information request for any responses that pertain to any process or emission point.

Page 7 of 31 

# 1S LVf ~



### C ~

~ 1 a- 

## vU U) U)

~ C (7 

### N

.` O > 0 N Qt ~ O rn

~ c~ U



### N Q fl. O 

# _ Y U

~ m ~ ~

~ N fl. 

## Y } L
~ O fn o.

t ` o O C 

## O 2 aL l0 

## _O ~ 

### u- O ~ 

### c ~ b

o 0 i0
~ c 

# 8 W t 

### I r ; I ~

rn 

### c_ 

# U U

aD



## ~ 

# Y
Uco

~ ~


### ~ 

## 0 a Q

0 6 

### iL C~1

~ ~ • 

# = O c

~ 

# .. O ~ ~ m 

## U ` m r

O 

## F' • M Q 

### c. o 00 a~ 

# a a
N ~ ~ 

### Z.~ ; .5

~ 

### . G ~ ~ ~ ~ v • 0

~ 3

~ 

### H ,. ~ 

### cm

c ~ ~ t+ lV 

### ~~ rn ~ Y CC/) 

# ._ v a ~

~ C

ct a 

## c'a in

.

~ L 

# ,~~ ._-...---- ~



## — - 

# ~ ~a m t~ ~
l0 v v 

# ~~a ~ 

# U

(n v ~

•~ ~ 

## A a' 

# w
C L ' O (g ^ 

### (n — LA CfU

~ ~ J ~ ~ ~ ~ O L ~ — L

Qr m 

## /5 3r•,

~



### 0



### 11~ o o v-

~ 

# U = 7 

# m 0 

### d N .~ 

### O 

# > ~ (~
~ 

### V C ~

~

~ V 

### Cl) ~

D7 C~

~

~ c 

# U U

a~ ~ 'CL a ~ Y 

# U (n

m ~ ~ C 

## 0 Q
ad Y V a R ~

~ 

### 5 ~ 

# O £

~ 

### E - a 

## L O C ~ 

# _ O

~ e0 m Y t~

~ 

# 3 y o ~ ~ c LL O O •` C (D O 

### W t 

# I N I

~ .. C 

## U '2 E a U) ~

~ 

# ° o,
V ~ L 

# a 1°

~ ~ 0 w

~ : m 

## : r w a 3 ~ M 4-. 0 O~ ~ aS 

### a



## EV

~ 

## C ... S 

# Aa 3 '

y ~ y

~

~ 

# L L ~ 

## a M 

## /5 `Y

### B. Using Tables 2A and 2B, please provide current production rates, production capacities, and related information for each type of equipment used in brick and structural clay product manufacturing. In Table 2A, provide the requested information for only those sources that are known or expected to emit HAP's. In Table 213, provide the requested information for all thermal processing, such as drying and firing sources. For combustion sources that use di$'erent fuels, Table 2B should be completed for each type of fuel. For example, if a kiln typically is fired with gas, but periodically is fired with oil, one column in Table 2B should be completed for the kiln when fired with gas, and another column should be completed for the same kiln when fired with oil. Provide the data in the units listed for each row.

Page 10 of 31 l3 - ~0 z

~

~ O z rn~ 

# Q
N W 

### a

~ J ~ ~
~ 

### x N ~ o 

## a z x rA

~ ~ 

# n c ~

oo ~ ~•~~v ~ 00 

### F ~X~

~ U ~+ U.. U + N

~ . 9 •-~ 

## w 

## ca °q 

## •ti•c

~~ 

## o E

y o :/] ^ • D € L r ' xj •C O 

### Z

~ y 

### --



## ---- - - - - - - j1 

# ^ ,. 4 .:...
.... _ :'

.... ... . . .

. . ..:.: ~ :...:.•::: '" ~:'~~~~::~~~~"'~~~:' .....: : .

~ __.::_......: - ~ ...:: .

_ 

# - .:: : ;. 

# . - .. : ~


# _

. ,~

~ : _ 

# - -

~ . 

# - - _., : . . .:: .;..,.._ . .:..: ; :.:._.:..-.:...... - _ -. ..: - - _

=_= - -- 

# :.:........::.-:_.::_._: .::...__.

~~ 

# .:.-

~. . ~ 

# -: '_::

. ;:~:~ 

# .'":_..

~;

~ "~~- ~ 

# -•---- -

~ 

# _=:

~ 

# .. m a;

,~ 

# .:_ 

# _ _—_.._.

.... 

# ....-._. 

# ._.

~ 

# ._--_ -:-_.:_-__:::

~'~`.~, t ,~ 

# ...:

~ 

# --._...... _ ' __---- -- -

~~ 

# --.'

~ 

# '_.:

~~ 

# _ --_ . -_ _ -- - - --- -=-

0

~ m 

### w ~ ~


### z •~ ~ .~ ~ 

## z b • ~ ~ ~ 0 ~ 

## _c

~ c .~ c 0 U H .~

~ ~
~ 

## s_ C_

~ y ~ ~ ~ ~ c o ~ •€ ~ ~ ~
4w ~ c

## o

~

~

~ U

cs, y ~ ~ 

## a X i

y ~ C
03
~ y ~

co ~ ~ o 

## s • 

# _ •

.. ~

~ cc 

# aY = 3 y g U C F. N

~ N
~ 

## a~ 0 0

~ ~ 

# Q .5 0 a~ N 

### o = G. R . 4. M ~ O

~
~ U'0 cC 

## o.

/}—b

### ~ ~ ~ .~ 

## w

~

~ 

### .S 

# ^o

a~ cO . ~ o ~ U U

... N .~ ~

~ C1Q



### N ~ y ~

~
U r ~„~ O • 

# ~

•~ L]. 

# ~ U '+ ~ o . ~ .

•~ O o

~ 0 

### ~ ~ a 

# . a "

~

U U 

## a~

w ~ ~ 

## ~ •~ y"

~ 

### o ;b_• ~~: ~ ~ b M w 

### 0 N



### ~
~ 

### a



# ~ w a

~ 

# `

o

~ c ~ °. a

. ^ ~ e 3 •°

~ Y ~

3 •" ~ ~ C ~ o o `~ ' Z' oo c "



### v

S~ M 

# z z z

O ~ ~

~..~ ~ ~ N = ^ Y 

### F ~ V 

### F~ ~ 

## N ~~

,, 0. 

### z~ 00 

### N , r 

### z , r 

### z 00 

### ~ ~=z ~



### ~ c

Y d 

# U V ~ 

# ^



# _ a a a



# c. ° 3 N 

# °' 

# 0
z 

# z z z ° ii 

# v_ n . ° 1 IT w ~ ~ ~ ~a o ' o 0 3 

### c•, o z 

### 3 z z z


# _ _ o

cis V O tti lm f/] ^ p



### ~ E '•~ „~ .--i 

# a. G. 

# z
~ ~ 

# EO

Vl y ~ Y ~ cn ~ y ~ •~ , ' ~ o 9
w1 m o .-

/,5 

### ~...



### ~ ~ 

## O C ~ 

### ,o

... ~ ~ 

## ~ o U 

### ~ 

# U o

~ o 

## 0 0 o (U a~ ~ (,
U ~ 

## .~ o GQ y

F.~ 

### 0 ; 

### 0 ~ O



## o U

~ O ~

N y
~ .0 

### a~ Q 

# a > Q. W y ~ ~

~ O


### ~ 0

~ S.

,,~ a~ 4) 

# o z

~ "o 

## ~ ~
~ > U CA

...

~ 

### N 

# H 

# z 

# ° M 

### ~ 0 M

~
~ 

### a ,

~ 

### F 

# ° z 0 ~ O 

# :C >
~ •~ U ~ V 

## ~v~ ~ ~•5

~ b



### a~ 

### 3 c. ~ ~ ; 

### _o O > ,- ti :d
c~ 'd • ~ ~ N ~

~ H ~ 

### C4 o ~



## aw ~ ~ 

## o 0 C13 O cd O O v

` n i

~ 

# Cd •

~~~ 

# • > n. a~•~ ~~

Cd "'Cy C,b ~ •~ ~ CG 'b


### CA

~ N

~ 0 ^CAN o , y , 

### ti

CA~ ~

~ b~4-4~



### o

- 

### v a, .15 cd c-, i-+ O G" cd 

## WE 9 InCs

/ 5-f

### C. Using Table 3, please provide information on procedures used to monitor the process operating rate for each of the pieces of equipnzent and HAP emission sources listed in Tables 2A and 2B. Use the same HAP emission source types and equipment ID numbers you listed in Tables 2A to 2B. Indicate whether you monitor process rate or not. Provide a summary of process rate monitoring procedures that descn'bes how process rate is measured for the particular piece of equipment. Include where the rate is monitored (i.e., rate of material fed, rate of material discharged, or niaterial production rate), the units used to measure process rate (e.g., lb/hr or pieceslhr), and how the process data is recorded, i.e., manually, automatically (e.g., conYputer - printout or stored to disk, or not at all). If you monitor process rate at both the feed and discharge ends of the equipment, indicate so. Indicate the type of monitor, equipment, or instrument used to measure process operating rate.
• Indicate the monitoring frequency or how often process rate measurements are made.
• If instruments are used to measure process throughput, indicate in the monitor accuracy cohunn the accuracy of the instrument. The monitor accuracy could be listed in terms of a percentage of the throughput (t 1 percent), mass per unit time (t2lb(hr), number of pieces per unit time (f 

### 10 pieces/hr), or other appropriate units.
• Indicate the frequency that the monitor is cahbrated.

• Provide data in the units listed for each row.

Page 14 of 31 /5 9~ ~ T C

~ .~ e 0 V y .~
~ CC 

### N ~ C

_ ~
~ ~
~ ~ C O y

~ C s 

## 4) o



# ... ~ 

# a ~ ~ + S •'

.Y. 

## ~ ' V R
N G. X ~ y L 0 0 y C O ~

~ 

### .., 

### ~ 

## a
~ 

## E a) 

# _ .. g V O ~ 

## ~ ~

~ 

### E a ~ 

# w°

~ 

# = O ~ 00 

### m 

## € a

~ > = 0 cj 0

q; 0 cC a ~ ~ 0 y N 

## 0 V N

~ y ~

~ .? y 

## U ca 

# a
,o 'G 

## co 

# = M

~ 0

~ c~ 

## a

M 

## a ~ H ~ •^ C U U U V U

. o ~ ~ • a •~ • Q •

a •¢
0 

### z 0



### z 0 

### z 0



### z 0 

### z

z z .2. z

U

•~ • 7 ~ ~ ~ T ~

y ~ E E CA ' H•~

v ~

•~ O •.~
•Y ~ •~ f

y •Y ~ ,

n \ 0 y

~ " \ C7 y : ~ .1 ~ i O.'Q y. t1.Q 0



### ~ c 

### ~° c 

### ~° ~ `" 

### ~~~ `o

, 

### , w — Q ~ 

### ,,, a q ~ M 

### t ~ C , ,

~ a ~ a 0 ~ N C' ~ y ~ C N~ N C y
~ V ~ C~ ~ ~ ~ . 5 .+ V ~ U ~.~+ ~ ~ ~ V m ~ 4. y

Q 4- y Q ~~ y y,>

C_.o ~ .0 4-, s.

0,0 "a ~ y 0 >

c c_ ~ o ~ c~ ~ ~ d? y ~,~ ~ Q • ~ T ~ G

~ r e~e ~ c `~i ~ ~ a s ~ `~ 

## c, . C rA a ~~ ~ ~~ y y 'd U

~ ~ iaL ~

ay U

a6~~:, O y 3 y~ V1 y y~



# o~ o~ o ia` 

# ~ -° ia` 

# ~ v E ~ y y ccsS. 

### s- cd

.+ 

### ~ c) a ;d
~ ~ ~ ~ a ~ ~ ~ ~ w ~ ~ a~ 0 y ~ ~ C%~ 

# a~ - O ~

• C ~ .••~ C 

# o y "~ j 

# S a

N N N rq eq 

### °' j G] 

# oq Q~ ~ , y ~•~ ~ ~ ~ ~ ;0 E-- P. V) U E

### o a x i 5 0 

## / 0v

### VI. Identification of Brick and Structural Clay Product Manufacturing Emission Points

A. Use the process flow diagrams developed for your facility and Table 4 

### to provide the foflowing information for each HAP emission source at your facility. • Define HAP emission souree type 

### in terms of equipment, such as dryers, kilns, etc. As in the process flow diagram, you may group multiple pieces of similar equipment. • Use the same equipment ID numbers indicated on the process flow diagram(s). • If the emission source vents inside a building or to outside ambient air without first passing through a control device, place a check mark in the uncontrolled column. • If the emission source vents inside a building or to outside ambient air after passing through a fabric filter, dry injection fabric filter, or scrubber, place the APCD ID number(s) in the column corresponding to the APCD type. • If the emission source vents through a control device type not listed in Table 4, indicate the control device type in the other control column and place the APCD ID number in the appropriate cefl. • In the emission test data column, place a"yes" or "no" in the appropriate cell to indicate whether the specific source has been tested for any pollutants, including any HAP's, VOC, PM, or opacity.

Page 16 of 31 16 

# r~

W
~--~

~ 'a = o



### ~ i 

# z Z z Z Z Z z w Ca °

~ o
~ o ~ U

~ 4. U ~ 

### n ~

.., ~

~

~. ~ ,....... __

• 0 ~ ......'.._..

. .. . ..:.: ..-._...._....._..

. .. ..: : •~ ~

~ •i•, ..~ - w ~ ~ > - ¢ L •V Ir ^

, n ti . . . ' _...._ ... . ..... ....

~ ... ....

. .. _ _._... .::. :...

, Tl

. ..... ...... ...___ ~ :F _

---_-

___ __ r. 

## w _- 

## : : ~., ~ 

## .-. ::::.-:;.:'' C' 

### U ~ ~ ~w 

## E Y -~ ~ N 

## F E~—• 

## O ci. 

# S

. • y ~ cd F" ~ ~ ~ L•

• U ~ ~ ~ ~ ~ ~~~~ •~ C L~ ~ •L N L~ N 2 w m W E- u. V U c.La EM 

### w O
N bA cC 

## a

16 Z

### B. Using Table 5, please provide information on stack parameters and emission estimates for each emission point at your facility that is known or expected to emit HAP's. Provide information for all APCD's, including those that exhaust inside the building. Include data for each inlet and outlet, if available, as indicated in the table. If you have more than one inlet to an APCD, provide data for each of the inlets. Provide data in the units listed for each row. Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal HAP's or VOC for organic HAP's. Emission estimates may consist of measurements reported in emission test reports or may be calculated using mass balances, emission fa.ctors, engineering judgement, or other estimation methods. Provide the emission estimates as emission factors in units of lb of poflutant emitted per ton of product (lb/ton). Provide complete copies of any emission test reports or other reports that document measurements of emissions. Test reports and other emission measurement documents should include the following information: process identification; location of sampling point; stack diameter, temperature, and flow rate; test method, including analytical procedures; number of test runs; emission concentration, emission rate, percent oxygen, and percent moisture for each test nm; process operating rate; type of APCD; and APCD operating parameters. However, test reports with incomplete documentation may still be useful and should also be submitted. You do not need to fill out Table 5 for emission points that are covered by an emission test report that is included in your submittal. If emission test reports are not available, provide calculations that support your emission estimate, including the basis for all assumptions in the estimate. Note that emission estiniates are needed for all HAP's that the facility emits or has the potential to emit. (Please refer to the HAP list in Attachment 1.) If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 18 of 31 

## 163

# ~

~ -+

~

~ W 

## a ~ H ir ~ O C

- C C C 34 C C

~ Z

~ 0 

## " a 

# z

~ O ~ 

## z

~
~ 

## ~ z

~ ~ 7 0 C p 0 p ~ M 

## ; ; 

### z 

## CA
~ 

# =

~ 

## ° a

z

.. ~ ~ y 

### C O



### 5 32 O 

### -5 

# w z

. y 

# U v Y



# N

~ N ~ z

M

~ p ~ ~ 00 

## ~ 

# p w V] y ~ y C ~~ • •~ y ~ v

p ~ ^ (~
• ..

y i •y ~ F ~ j

~ ~ ../ y ~ 

### 0 WW ~ ~ •~ "



### y ~ •~ w 

### ~ ~ ~ y ~ ~

r 'C p e.

~ . ' ~ Y

U 0_Q 

### G_ 'O • ~ ~ a w ~'~ '' j rn . O d0 R.

•~ ~ C/ 5 V ~ ~ ~ V V

L ~

— N M tt v1 C4 C
~ 0

~ O f'
- Z 00 O ~ M

~ 0 a, ~

~ ~ CC 

### a



## /bY~ 

## ~ ~ 0 y ~

~ c G

• C 

## O~ c O~ N ~

y ~

b ~

~ o ~ z m 

### r

_ ~ L ~ .1: 4.. ~ L

. ~

~ 

# _.
~ s 

# .. w 

# 0

y .~
y
~
.~ ~ U 

# a cl u s
..
~ 

# _ ~ 

# w ~ ~ ~ ~ ~ 0

~


### .~ o

. ~


## _ .~ c0
~ 0 y ~

M 4-+ O O N N CA 

# a, R V 

## c~ L ~ 

## O ~ 

## ~ ~

_ .~ G O V

.~ V .a
~ ~


## ~ y ~ 

# o ~

.+ 0 ~ C O •~, ~ 

## =ZE h W 

# a

~ ~ 

# °

z ° z 

# ° z o z z

~ 

# °

z ° 

# z 

# ° z z z

~ 

# 0

r ~ 

# ° z ° z 

# ° z _ .. 

# z z

w 

# °

z ° z 

# ° z o ' z z

.. = 

# °

z z z

w
~ 

## o 

# °

z ° z

~ 

# " zz

OD
~ v ~ ~ '~ ~ ~ •~ •• V C O

~ _ .y C ~ y

• y y •"

~ y V \ ~ ~ v/ y .

~ ~ ~ / y
y H 

### ~



# w i • ^ ~ y "CJ . L" G.. LU E a. ~.Z~ o m N00 A ~
0



### /6.5-

# ~ ~ C7

~ 

### W a


### ~ U pp N ~ ~ ~ 

## a z F



## =5 .7 :5
i N +r ~ 

### $ ~ a z


## °o 5 0



### .9 .5 .9 

# = ~ .~y Y 

### ~ 1 Oo i1
w
y a~~ ey ~

rA i. w
(~ 'O O 'p



### 78 R cnv e° i v ~ i M 

### w 0

~ N

~ C~ 0 cv 0.



## '4,&. 1 W 

# z
V N 

### W

~ 

# ~ H ~ U N 8 O y ~

~ C G

O~ N LL O OG ~O y O 

### o }' U ~ b 

### e z
~ 

### n :°. C]

~ 

## z . c 

### m y ~ 

### u s
~ ~ 

### E 

## u a 

## u 

## s 

## w 0 H 0 .~

~
~
~ a 

### a 

### . ~
~ s

~ 

# u 

# a 0 4 1 U w 1 ~ 7 O ~ ~
~ C .~ C 0 U

.~ U

~ U s 

### v U C N W

~ ~
~
~ 

### 0 

# .~

~ 

## a

~ c r.

M 

## w 0 N N 

### v b0 ca 

# a

~ :E

~ o ~ R ~

~ y 

### w ~

v~

~ 

## - - 

## E-= w « 0 0



## w a

~ Q 

# o zz z z z

= Ca La C ~ 

### Q Q
~ 

# zz z z z

L 0 Q Q 

## o zz z z z



# .. = o0 0 ¢ Q

~ 

## zz z z z

~ 

## o 

# °

z ° z 

# °

z z z

~ 

# ~ zz °



# z z z

00 N

~ ~ ~ 0 ~ •y ,b ~ ~ O L5

' • 0 .. y c .. .^ Vl

— 

### ~ ~ ~ 

# w~~~

~ ~ y 

### c~ ~ z LU 

# °a=x o -


# /6-7

### C. Using Tables 6A through 61), please provide design and operating data for each APCD

associated with all dryers, kilns, and any other brick and structural clay products manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of APCD's. Use Table 6D for other types of APCD's. When using Table 6D, please specify the type of control device and 2 to 4 key design or operating parameters for the device. Provide data in the units listed for each row. If the information requested in Tables 6A through 6D is contained in your facility's operating permit, you niay reference the applicable sections of the permit rather than filling out the tables.

Page 23 of 31 /( ?'~ M
~ O

~ N

~ OD c~ 0.
y
~ 

## .0 w

~ 

### .5

~ V

.~

~
~ ~ .L: 

# _C

~ 

### ~ S~ 

## p u w ~ C o 

### 'y ao L . 

### e 

### ; ec Q
1 0 W a



### ~ ¢ H .~

~ ~~~ £ 

# -.- :

~ 

# • .S.

`



# _ k T ( 

# -•-. . -oi -3T7



# ._ ~ 

# . _ - - ~ - ~~

.,

T

~ 

## /6 r

## ~

~

~.~ .1 u .0 ~

... u
~ .S

~ ~ ~ 

# S S _~ o f'

• y ~
W ~ C

~ C 4. E cn
~ W H

~

— 

### E-

~ . ~

~~ 

# _ ~ ~

_ ~ ~~_ ~

3-

~

~

. "



### l

~ ~ M 4.. ~ O tn N

~ b4 c~ 0.



## 17V~ ~ W
~

~ ~ U ~ 

### U
~ 

### W 

## W I

~ ~ .S

~ ,S ~

~ h

~

. ° 3
~ ~

~ .r 5

~ ~ ~ 0

~ 

## C ~ L ~ M 4-. O

~ 

### o N a~ 

## 00 ca

~ 

## .

/ 17/~ s b ~ ~

~ s .,

.~ ~ ~ .~ w 0 N C~ r 0 .~

N .~ ~ .~ a 

### m

'a 

### .S ~ ~ N .~

~ ~ ~ ~ 

### .S

~ 

# ~ S~



# ~ o 'y ao

~ t: t:. ~ 

### W U
~ ~ 

### W 

## A 

# a O x H 

# z 0 U C~

~ E--' 

### 0 A ~O 

### W a
~ H ~ ~ ~ .~ 

### a a 

# z 0

~

4. ~ 

# n. a a a a:,
~ M 

# w G r— N
~ c~ 

### CL



# 1,7z

### D. Using Table 7, please provide the following information on current nionitoring procedures for each of the control devices listed in Tables 6A to 61): parameters monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices used (e.g., differential pressure transducer, thermocouple), and recordkeeping practices (e.g., manually recorded in log book, continuously recorded by electronic data acquisition system). Describe briefly other operation and maintenance (O&M) procedures for each control device. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table. VII. 

### Pollution Prevention Practices for Brick and Structural Clay Products ManufacturingA. Please describe all pollution prevention practices (i.e., process modifications, such as reuse of discarded or rejected materials, or any practice that prevents or reduces the amount of air emissions, or the generation and release of solid waste or wastewater associated with the operation of air pollution controls). If the information requested here is contained in your facility's operating permit, you may reference the applicable sections of the pernzit rather than providing the information below. 

### This facility: 1) reuses waste heat from the kiln to heat the dryers (and to a lesser degree, the holdin r

g ooms), 2 recycles floor sweepings and scrap/waste clay back into the brick body: 3) recycles green brick back into the brick body; and 4) recycles off-sQec brick grog) back into the brick body.

Page 28 of 31 173~



## w 

# a ~ _ +~ _ .--_, • ! :-u: ..' :..~~i:~:~~.~ = :



# =y":

~ 

# ,'' 41

y 

# G C

~ 

# _ _ _ _ __ _ _ _-_ • j ~

~ 

# ____-

~ 

# _ ~~ 

# .--- _ 

# __ -•'?• •' ~ 

# 0

V 

# ' -

~~ 

# :r

.._m

. , 

# y
•~ 

# _ - -

~~ 

# 'iY;':

~ 

# : €
r~,


# _ ~a 

### =F 

# __,__ :

__ ; F a

~

r'...



# - - . -_ - _-- -

' L.. - W'

~:~~..~ • _--_ __ _

y

~ c _

1..

_



### -

~ 

### a z

z



## o v

~ 

### a Q 

# T T

C1 • ~ 

# 1.L1

. . CO J 4 ~ r

~ ~
~

~

~ ~ ~ ~ 

# €

~ 

# .

!.••. M w O D\ N

~ ~ 0.



## 12K

### VIII. Information on Processes Other Than Brick and Structural Clay Products Manufacturing Processes A. Using Table 8, please identify all other processes or operations at this facility that are not addressed in Itenms II through VII above and that are potential sources of HAP emissions. Estimate total annual emissions of each HAP emitted by these collocated processes. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 30 of 31 

## 125,

## TABLE 8. ESTIMATED ANNUAL HAP EIvIISSIONS FR OM O 

## THER SOURCES

Process/emission source/SIC Code(s) HAP's emitted Estiniated annual emissions
, tons 

## e me#a ~ 

## _ 

# _: .-.:...._ v= ..

~ 

## Not Applicable

SIC



## I SIC



## I SIC

SIC 

## If the infonnation requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.
Page 31 of 31 1710

# Material Safety Data Sheet
Substance Identification Identity: IRON CHROMITE CAS #: L308-38-9 Trade Names: CHROMOX Manufacturer: 'Ibe Prince Manufacturing Company Emergency: Chemtrec One Prince Plaza 1-800-424-9300 Quincy, IL 62301 

### 217-222-8854 

## Components and Contaminants Chemical Name CA 

### S # OSHA PEL ACGIH TLV Percent Chromium Cr+' 7440-47-3 0.5 mg/m 3 0.5 mg/m 3 (TWA) 30-45% Cr Silica, Crystalline Quartz respirable dust 14808-60-7 0.1 mg/m 3 0.1 mg/m 3 (TWA) 1.2% Si0 2 

## Physical Data Boiliag Point: NA Specific Gravity (H = 0=1): 4.4 Vapor Pressure (mm/Hg): NA Melting Point: 3350 - 4000° F Vapor Density (Air =1): NA Evaporation Rate (Butyl Acetate =1): NA Solubility in Water. insoluble Appearance and Odor: black powder, no odor. ! ~ 

## Fire and Explosion Hazard Data F7ash Point: Not combustible Flammable Limits: LEL NA UEL NA Extinguishing Media: ` Foam, CO Z , or dry chemical or water. Specia.l F'ire )~ighting Procedures: In the event of fire, wear full protective clothing and NIOSH-approved selfcontained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Unusual F'ire and explosion hazards: Not combustible. 

## Reactivity Data Stability: Stable under ordinary conditions of use and storage. Conditions to avoid: None Known ' Incompatibility (materials to avoid): None Known. Hazardous Decomposition or Byproducts: None Known. Hazardous Polymerizatioa Will not occur. 

## Health Hazard Data Route of Entry: INHALATION: May cause delayed respiratory disease : if dust is inhaled over a prolonged period of ttme. S KIN: No. INGESTION: Ingestion of Iron Chromite may cause abdominal pain and nausea. ...._ .

Iron Chromite, Page 1

A^=l 1991 /7 ~

## Health Hazard Data (ront.)

Health Hazards (Acute and Chronic): Respiratory disease may result from prolonged overexposure. Can cause eye irritation. Carcinogenicity: NTP: No IARC Monographs: Yes (Silica) Signs and Symptoms of Exposure: Excessive inhalation of dust may result in shortness of breath and reduced pulmonary function. Symptoms of silicosis include impaired pulmonary function and wheezing.Aggravation of Pre-existing Conditions: Persons with impaired respiratory function may be more susceptible to the effect of this substance. Emergency and F'irst Aid Procedures: IF INHALED, remove to fresh air and seek medical attention for any breathing difficulty. IN CA.SE OF SKIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. IN CASE OF EYE CONTACT, flush eyes immP

~ 

### iately with water for at least 15 minutes. Seek medical attendon if irritation persists. IF INGESTED, induce vomiting immediately by giving two glasses of waterand sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. 

## Precautions for Safe Handling and Use Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratory protection. Recover uncontaminated material for use. Vacuum or sweep remaining material, keeping dust to a minimum. Waste Disposal Method: Dispose of unreclaimable material in a RCRA=approved waste faci7ity. Handling and Storing Precautions: Protect containers from damage and keep closed when not in use. Other Precautions: Observe good personal hygiene. Wash after handfing. 

## Control Measures Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or is anticipated. OSHA standard 1910.134 or ANSI Z,88.2-1980 specifications are recommended. Venti'Iation: A system of local and / or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work aiea. Please refer to the ACGIH document, "Industrial Ventilation, A Manual of Recommended Prac-

~ 

### tices', most recent edition, for detaiLs. Protedive Gloves: Yes Eye Protection: Safety goggles are recommended. Other Protedive Clothing or Equipment: Use other protective equipment when necessary in order to avoid prolonged exposure to skin. Work and Hygienic Practices: Observe good personal hygiene. Wash after handling.



## -- - SARA Title III Section 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-to Know Act of 1986 and of 40 CFR 372.45: Compgnent CA 

### S # % by Weight Iron Chromite 1308-38-9 30 - 35% Cr This information must be included in all MSDS's that are copied and distributed for this material. —

Iron Ctiomite, Page 2

April 1991 

## / ?,P

## tiSalerlal Safety Data Sheet

Mlay tH used lo comply wilh OSIIA's tivard Communlcalbn SlttnOard, 29 CFH 19 10. 1 Slandard musi till con3ulled lor speci(!c rrrqulrementa. 

### U.S. Depariment of Labor Occupotlonal Safety and Health Adminittrtatlon (Non-Mandatory Form) Form Approv•d OM8 No. 1718-0077 IOEHTTT7 (Ai Uad a^ L" and UsiJ hbro: At&',t spxsi r+n nor pamvrriPd r any rr•m 4 no( acpMcao+a. or M 5481 Ochre h/arrn.0 0 n b a vrLr,.b.r, a n• sp•cQ mus t b• mark•d to ndici•rr o Sestlon 1 Mu,ulactufw'1 Nam• Em•(q•

~ 

### +U ~ 

### !
~ 

# _ hern Color ac Chemical AdCr a s.f (NurnDar. S'trr t, Ca'y. 57 a m an0 I1P C.od•) T• I• w~o~ • N ~,r~~c~. ~r a t,on P.O. Box 15 0 7 t404 ) j8b- 

### ~+~ Oata Prtpurrd , 7 Swisher Drive may 21 1986 SiQnalur• or Prrrpu•r (optianaQ

. 

### Cartersville, Georgia 30120 

## 1 

# ~ . / 

# ~ " Sectlon II -- Haiardoua Ingredlents/ldenllty Informatlon 01h•r Limits Huudous Component• (Sp•cihc Ct14rnlco! Id•ntHy , Common Nam•(s)) OSHA PEL ACOIH TLV Rocommand•d 4 (oo M548 Ochre (Fe7O-4-XH20)Natural Iron Oxider Non Established; lOmg/L None

Note: Ochre is • listed as liazardous because of t

- he nuisance dust 

### that may be created in handling t e pro uct. CASN 1343- 8 1- 3

t l

.

Sectlon III — Phyalcal/Chemlca) Characteristics 8alinq PaM Sp•ciAC Oraviry (H = O . I) N/A 3.2-3.E Vapor Prrtssur• (mm Hq.) M•Illny Poirr N/A ' N/A Vapor Ortnsity (A A • 1) Evaporatlon Rala N A (eutyl Ae.tat. . 1) N/A 9oluoitity n Watu



### Insoluble App•uanc• and Odar



### Yellow Powder - No Odor Secllon IV — Fire and Exploalon Hazard Data Flasln Poani (MaIhod Us•d) N/A Flammablra Umits LEL UEL 

### N/A 

# I N/A Erunquisttinq 6A•dia N/A Sp•cial Fwrt Fi9hunQ Procedur•t None Required •

UnutuaJ Fita tlnd Expbsion Hu1ro• None
(R•ptoduc• locally) OSHA 111, $•pl. 1i.
/ / 

### ~ttti

~ ,lt

~ - 11
~ - ~w~ o~ ettn • ~ •~~d 3NON S1211De,d a32iIn632i 3NON

_ wrwdtnb3 ,o Eu!A41010 •ntuato,d m.,tip

TdNOI,LdO
~~~ d r ~ 3 'MNOI,LdO Aa0 r^n-%*told
• 3NON » ~ a32fIna3?&
~ NQ
~ 1 1Rb1utW+Y+1

3 NON 'IFiNOI " ,Ld ~ O Ro•dS rnrVv3 Rwl uonetrr.,.A o3,LS39`JnS ,Lne 'IvNOISdO SI ,LSna 3JNvSInN 2103 a3A0Mdd'd aO.LfRiIdS38 (od 4 1 A1'

~ +eS) uoluvlatd

~ Gote,as

~ y tojnceow 10Jlu03 -- IIIA u 0 11o 2 S

•,Lsna 3AISS30X3 3d.t13210 IiJI'HM sNOI1,'dn,LIS QIOAV 6uuolS Put 6uIIPutH ul uOKtl 18 ol tuo!int:a,d TII3aNtfl a3A0iiddW N'd NI '1KSOdSIa 3,LSVM aI'IOS 'Itf1Wi30N • Po4It+Fy Rsods!Q •tst/H

' •,Lsna 30 NOI3,V32iJ 3111 3ZIWINIW OZ S3JI,LJtf2id JNId33X3SnOFi Q009 3Sn P+II!dS jo PesrrNti rl Rvrteyy rst0 u1 ur>{el r9 ot sdrtS acn Pue 6u I1P ueH oleS jol cuollneDaJ d — IIA uollzaS
a 3Zi I n2532t 3 NON s t,npto oid pry ltnd put hur6»wq



### , 1 . NMONX 3NON •inrod:3 Aq poic,%r,Gby ntnurE) tuoUlPuoO ItvaYI

~ 

### ssoj a ~n~ 

### siout o ~ a~ 

### p u e4o

~ 

### o p , •,ntodi3 lo tiwoldwxg pVt ttu6!g

• N 031 ~ ,TAN a3,LSI'I ~ LON ' lP ol rin >i YHSO Lr W OHVI 1d1N

~ +!2!ur
~ +!n0

' (x*++10 Dts umy) tPtrttH 4tRrH MojjeMs 

### Iou op paqaosqe aq louue0 •s.XHB 'I 0!"1 .Oi A'I,L-asnQ aouestnN

tuonsr6ul l.uI

~ IS !uo!

~ r►tyt ~ .Gtu3 Ic (tHr+oi;! V1ea PJMH 411e 0 11 — i>r1 UollOOS

- xtr

~ 0 IoN Ipm NMON:{ 3N014 U"nurt++

~ d

P!a+`I o1

~ i11Dw0 1n=0

~ Ityr tnoG+ereH

• tf~x+Dn,ditB io vop!sodwoor0 rno0,rrrH 3NON (P/oAy ol rlrurlr Y) ll1llqtltdwo 2 ul

urtoux auoN Pfo^V ol ruoft!PUOO I I rlcmsun I N-"tS sl*a

~ IIMtOtod — A uoilDoS 

# m

### ividtertal Jafety uata ,, )neet

May be used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Staridard must be consulted for specific requirements. D IDENTITY (As Used on Label and List) 

### I R 

### ON MANGANESE OXIDE BLACK #320/318 U.S. Department of Labor /

~


### _ ` Occupational Safety and Health Administrat i on `` ' ; j „ (Non-Mandatory Form) Form Approved OM8 No. 1218-0072 CAS# 1 1 11 5-41 -4 Noto: Blank spaces are not permifted. d any item is not app/icab/e, or no i n l ormation is availab l e, th e space must be marke d to in d i ca ' e th at. Section 1 CHEMICAL FORMULA - Fe2 0 3 Mn2 0 3 Manufacturer's Name Emergency Telephone Number 

### 404 386-4766 Address (Number, Street • City, State, and Z/P

~ Code) 

### Drive Telephone Number for Information 

### (404) 386-4766 7 Swisher Cartersville, GA 30120 Date Prepared 

### September 21, 1987 Signature of Preparer (optiona/) Section 11 — Hazardous Ingredients/ldentity Information Other Limits Hazardous Components (Specific Chemical Identity; Comrnon Name(s)) OSHA PEL ACGIH TLV Recommended %(optional) 

### HAZARDOUS INGREDIENTS - NO ADDITIONAL INGREDIENTS IRON OXIDE FUMES as Fe 5mg/m' RESPIRABLE DUST 5mg/tn 3 

### MANGANESE COMPOUNDS 5taq/m 3 (CEILING, AS Mn)

Section 111 — Physical/Chemical Characteristics Boifing Point SpecifiC Gravity (H20 - 1) 

### N/A 4.8-5 Vapor Pressure (mm Hg.) Meftiny Poirtt Vapor Density (A1R - 1) Evaporation Rate (BuM Acetete - 1) Saubility in water 

### INSOLUBLE Appearance end Odor 

### BLACK POWDER - ODORLESS Section IV — Fire and Explosion Hazerd Data Flash Point (Method LEL' I UEL



### N/A N/A I N/A I N/A Extinguishirg Media 

### WATER DRY CHEMICAL • Special Fre FighUng Procedures Nl)NF Unusual Fre and Ezplosion Hazarda 

### . NONE (Reproduce localty) HAZARDOUS MATERIALS IDENTIFICATION SYSTEMS (HMIS) OSHA 174, Sept. 1985 HEALTH 0 FI.A?QtABILITY 0 REACTIVITY 0



### ~~~

### , D ;ection V — Reactivity Data tability I Unstable I I Conditions to Avoid



## I IXI icompatibility (Mateiials 10 Avoid) 

### NONE KNOWN azardous Oecomposition or Byproducts •

ection VI — Health Hazard Data oute(s) of Entry: Inhalation?YES Skin? NO Ingestion? YES ealth Hazards (Acute and Chnonic) 

### fANGANESE IS C EMICALLY R_F.ATED AS P RT OF THIS ST BLE PIGMFNT CRYSTAL OVER EXPOSURE TO '4 MANGANESE IN AN UNREACTED FORM MAY RESULT IN CHRONIC MANGANESE POISONING(MANGANISM) T 

### HE ;ENTRAL NERVOUS SYSTEM IS THE CHIEF SITE OF EFFECT. TO DATE THESE TYPES OF EFFECTS HAVE NOT arcinogenicity: NTP? NO WRC Monographs? NO OSHA Regulated? NO 

### EEN ASSO C 

### IATED WITH THIS PRODUCT. gns and Symptoms of Exposure 

### XCESSIVE EXPOSIIRE TO AIRRORNE DU4T WILL RESUL.T IN EFFECT 

### SIMILAR TO T1iAT OF NUISANCE TYPE UST THAT IS PARTICULATE MAY REDUCE VISIBILITY AND/OR CAUSE UNPLEASANT DEPOSITS IN THE EYE 

### S, edical Conditions EAR

~

S __ AND NOSE . INJURY TO THE SKIN OR MUCOUS MEMBRANES CAN OCCUR BY DIRECT :neralty Aggravate

~ 6y t "pvs 

### ure ~ y.nVAfyT/
~ AT AnTTAL7 AD 4V DT/`/1DAiTQ QVT

~ I* l ~~A 

### N TAir TE'('G'CCADV 

### Or+ cmv:aa svem srorrv: ~ oce as cesvtrssvw-vcr 

### DUST. nergency and Frst Aid Procedures gTU CONTACT _liAqH WTTu SppP ANn rJpTPg EYE CONTACT — FLUSH WITH LARGE AMOUNTS OF WATER • 

### ONSULT PHYSICIAN. INHALATION — REMOVE FROM DUSTY AREA. ection VII — Precautlons for Safe Hano11ng and Use 3ps to Be Taken in Case Material Is Released or Spilled 

### ANDLE AS NORMAL SOLID WASTE, SCOOP UP BY SOME MEANS AND PLACE IN A WASTE CONTAINER.

aste Oisposal Method 

### ASTE MATERIAL CAN BE BURIED IN A APPROVED LANDFILL OR HANDLED AS INERT WASTE IN ACCORDANCE ITH FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. -cautions to Be Taken in HandGng and Storing 

### TORE DRY AT AMBIENT TEMPERATURE AWAY FROM FOOD AND DRINK.
her Precautiorts 

### NONE _. -iction VIII — Control Measums spiratory Protection (Speclfy Type) 

### IO_SH_ APPROVED FOR DUSTS, MISTS AND _FUt-tES. _DO NOT EXCEED USE LIMITS OF THE RESPIRATOR. ntitation X

Mechanical ChL 7 nective Gloves Eye Protection 

### IBBER, CLOTH OR PLASTIC GLOVES SAFETY GLASSES )er Protective Ctothing or Equipment 

### N/A ;rWHygienic Practices 

### ) NOT STORE NEAR FOOD AND DRINK. WASH EXPOSED SKIN FOR HYGIENE PURPOSES. Pop Z • U.DO.tO.: toe!-491-52 9/45 7 73 

# l f2--

## MATER/AL SAFETY DATA SHEET
Section I - Product Identification The Georgia Marble Com p 

## any' 1201 Roberts Boulevard, Buildin g 

## 100 Kennesaw, Georgia 30144-3619 Emergency Telephone: (770) 421-6508 Prepared by: Trevor G. Lamond, Technical Director Trade Name: Ground limestone/ Calcium carbonate Production Locations: Marble Hill, Ga, Sylacauga, AI Chemical Identity: Product consists of ground limestone (CAS Number: 1317-65-3), which is a natural peoduct composed of Calcium Carbonate (CAS Number 471-34-1) and from 1-3% Magnesium Carbonate (CAS Number 546-93-0) together with various other natural ingredients at trace levels. Section II - Hazardous Inaredients

Hazardous Materials Identification System Health Hazard 0 Flammability Hazard 0 Reactivity Hazard 0 Personaf Protection E Hazardous In,aredients TLV (mg/m' ) Silica, Quartz Calcium Carbonate Dust .1 (Respirable Dust) 10 (Nuisance Dust) This product typically contains less than 0.3% crystalline silica. : In addition, there are also small but detectable amounts of the following other naturally occurring chemicals that are known to the State of California to cause cancer, birth defects or other reproductive harm. This warning is provided in the absence of definitive testing to prove that these risks do not exist. These amounts are typical quantities and may vary slightly with different lots. l8~~

## Chemical Name

Arsenic Lead 

## Typical Amount Less than 1 ppm Less than 1 ppm 

## CAS Number 7440-38-2 7439-92-1



## Section III - Physical/Chemical Characteristics Appearance and Odor: Fine, White Powder; No Odor Boiling Point: N/A Specific Gravity: 2.71 Vapor Pressure: N/A Evaporation Rate: N/A Vapor DensIter: N/A (Butyl Acetate = 1) Solubility in Slight Melting Point: N/A



## Section IV - Fire and Explosion Hazard Data Flash Point: N/A Flammable Limits: N/A Fire Extinguishing Media: N/A Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None



## Section V - Reactive Data This material is stable. Incompatibility: May react with acids to liberate carbon dioxide. This material will not polymerize. Hazardous Decomposition By-Products: None



## Section-Vl - Health Hazard Data Calcium Carbonate, the main component of limestones and marbles, is not on the NTP, IARC, or OSHA lists of carcinogens and there are no health effects associated with prolonged exposure to pure calcium carbonate. Crystalline silica (sand), a trace component of many limestone and marble powders, in its respirable form has been listed by IARC as a Type 1 carcinogen and the NTP has stated that crystalline silica is reasonably anticipated to be a carcinogen. Also, prolonged exposure to crystalline silica has been found to cause silicosis, a noncancerous lung disease. 

## Exposure: Inhalation: Can be irritating to the respiratory tract. 

# R e Contact: Mild irritation. in Contact: No effect. Ingestion: Minimal effect. 

## First Aid:

i 

# lw

## Inhalation: Remove from area of exposure and to fresh air area.

Eye Contact: Flush eyes with water for 10 minutes. If irritation

p 

## ersists, obtain medical attention. Skin Contact: Wash from skin with mild soap and water. Ingestion: Ingestion should not cause any significant health

problems. 

## Section VI I - 

## Spill or Leak Procedures Spill or Leak: Respiratory protection should be worn during clean

up to protect from airborne dust. Measures should be taken to reduce airborne dust during clean up. Waste Disposal: Shovel up material and dispose of in landfill.

Comply with applicable federal, state and local regulations. Section VIII - Special Protection Respiratory Protection: NIOSH/OSHA/MSHA approved dust respirator if T.L.V. is exceeded. Ventilation: Local exhaust: As required for dust to maintain airborne dust below the TLV. Mechanical: As required for dust. Eye Protection: Safety glasses or goggles. Special Protection: None required. Date Prepared: March 3. 1998

~~~/

# C georgia marble company nK MNOVATaa 1201 rober[s boulevard, building 100 • kennesaw, georgia 30144-3619

" STONE °A00LLn fax:770 421-6507

[ ) (770)421-6500


# 1VIATERIAL SAFETYDATA SHEET
Section I - Product Identification The Georgia 

## Marble Compan y 

## 1201 Roberts Boulevard, Buildin g 

## 100 Kennesaw, Georgia 

## 30144-3619 Emergency Telephone: (770) 421-6557 

## Kenneth J. Meeks, Safety and Training Manager Risk Management Chemical 

# Name: Calcium Carbonate Chemical Family: Marble; Limestone; Dolomite Chemical Formula: CaCO 3 ; CaCO 3 ; 

## MgCO 3 CAS Number. 471-34-1 Trarla A/amz
### Section 

## Il - Hazardous 

## Ingredients

Hazardous Materials ldentification System Health Hazard 0 Flammabilit

y 

## Hazard 0 Reactivit y 

## Hazard 0 Persona/ Protection E Hazardous /ngredients TLV (My/M ) Silica, Quartz Calcium Canbonate Dust 

## .1 (Respirab/e Dust) 10 (Nursance Dust) Calcium Carbonate 

## may contain crystalline silica at levels between 0.01 % and 1.5% and varies naturally. There are a/so 

## sma11, but detectab/e amounts, of the followin g 

## othernaturally occurrin g 

## chemica/s that are known to the State of Califomia to 

# cause cancer, birth defects or other reproductive harm. This waming is provided in the absence 

## of definitive testing to prove that these risks do not exist. These 

## amounts are typical quantities and may vary slightly with different jobs. 

## Chemical Name Taical Amount CAS Number Arsenic Less 

## than 1 ppm 7440-38-2 Lead Less 

# than lppm 7439-92-1 

## ~~

## Section Ill - Physical/Chemical Characteristics

Appearance and Odor. Fine, White Powder; No Odor Boiling Point: N/A S ecifc Gravity: 2.71 Vapor Pressure: N/A EPa p 

## oration Rate: N/A Vapor Densit y 

## : ~ 

## N/A (Butyl Acetate = 1 ) 

## Solubility in Water. Slight Meltmg Point: N/A



## Section !V

-



## Fire and Explosion Hazard Data Flash Point: N/A Flammable Limits: N/A Fire Extinguishin g 

## Media: N/A S p 

## ecial F 

# i re Fighting Procedures: None lJnusual Fire and Explosion Hazards: None



## Section V - Reactive Data This material is stable. Incompatibility: Reacts with strong acids to liberate canbon dioxide. This material will not polymerize. Hazardous Decomposition By-Products: None



## Section V!

-



## Health Hazard Data Calcium Carbonate is not on the N. T. P., I.A. R. C., or OSHA lists of carcinogens. C ry 

## stalline silica, a trace component of Calcium Carbonate, has been 

## listed b y 

## IARC as 

## carcinogenic to experimental animals and has developed limited evidence for carcrnogenicity to humans, however, /ARC 

## has determined that the carcinogenicity to humans is neither certain or proven. Prolonged, repeated inhalation of crystalline silica can cause silicosis, a noncancerous lung disease. Exposure: Inhalation: 

## Can be irritating to the respiratory tract. E y 

## e Contact: Mild irritation. Skin Contact: No effect. Ingestion: Minimal effect. First Aid: Inha/ation: Remove from area 

## of exposure and to fresh air area. Eye Contact: Flush eyes 

## with water for 10 minutes. If irritation

Mr ssih 

# st f 

# s r 

# ' obtain medical attention. Skin Contact: om skin with mild soap and water. Ingestion: Ingestion should not 

## cause any significant health

problems. 

# %CX2

## Section Vil - Spill or Leak Procedures

Spill or Leak: Respiratory protection should be worn during clean

up to protect from airborne dust. Measures should be taken to reduce airborne dust during clean up. Waste Disposal: Shovel up material and disp ose of in landfill.

Comp1y with applicable federal, state and local regulation s. Section Vlll - Special Protection Respiratory Protection: NIOSH/OSHA/MSHA approved dust respirator if T. L. V. is exceeded. Ventilation: Local exhaust: As required for dust to maintain airborne dust below the TLV. Mechanical: As required for dust. Eye Protection: Safety glasses or goggles. Special Protection: None required. Date Prepared: March 4.1998 Prepared by Safety Department



# /ft

### MATERIAL SAFETY DATA SHEET
TNDUSTRIAS SULFAMEX, S.A. Distributor - North America ampico, Mexico AGROMEX, INC: 

### Mobile, Alabama FOR HEALTH HAZARD INFORMATION, CALL: -(205) 

### 443-5665. Date of Revision: ••03/12/90 ass:aasaaaasaaasaaaaasaaamaaaaassas3aaasasaaasaaaaaaasaaassaasasassasaasaaa a=: 

### - Product Name: TECMANGAM (R) Soluble Manqanese Sulfate - Synonym: Manqanese Sulfate (81-83.8 ) 

### - Formula: Mixture
a s a s x a=¢ s s s a a a a a a a a c a= a a a e= 3 

### SECTION II. PRODUCT AND COMPONENT HAZARD DATE 

### A. COMPONENTS: Approx. 

### Percent TLV** CAS Req.No.. ~ 

### *Manqanese Sulfate . 83.8 5 mq/m3 (as Mn) 7785-87-7 

### Maqnesium Sulfate .2.0 None ; 7487-88-9 Calcium Sulfate .5 None - 7788-18-9 Water 1.0 None

---------------------- - ---------------------- --- 

### 7732-18-5

-- ---- 

### *Principal hazardous component **See Section VI-A for additional information on exposure limits. PRECAUTIONARY LABEL STATEMENTS: WARNING! MAY BE HARMFUL IF INHALED

CAUSES IRRITATION Avoid breathing dust.
. ~ 

### • . 

### Avoid contact with eyes. Avoid prolonqed or repeated contact with skin. - 

### Use with adequate ventilation.
_ Wash•,thorouqhly .after handlinq.



### . .. . . .. . . 

### FIRST AID:..: In case of contact,. 

### immediately flush eyes with plenty 61water for at least 15 minutes. ,;: Call .:',a ,physician., : _Wash skin with soap and plenty of .: water. ,Wash

~ 

### clothinq before : reuse. 

### In case of irritation of eyes, nose, and "throat, 

### remove from exposure,.treat symptomatically, and call a physician if.symptoms persist.

. . _ _... MSDS 001:1 . 

### '03/lt/90

. ,;. . . ~
. .. .

,. - ,..



# • . !
~ 

# f' B.

### Since emptied packages retain product residue, follow label warnings even after

package is.emptied. 

### Notice: Manganese Sulfate may discolor ornamental surfaces, rock, tile, masonry, etc. Contact with these surfaces should be avoided. If contact occurs, wash area immediately with water.

asasssaass ssa s assassaaaaassss s a aasaaaaa:asaaaasaa

~ aassaasasaasas
~ aasaaasaasaaasa sa

• ~~'. 

### SECTION III . PHYSICAL DATA 

### - = • - ,' :±
~ 

### ?., - 

### - Appearance and Odor: White to cream-colored powder, practically odorless. ~ 

### - Boiling Point: Not applicable. 

## - Specific gravity (H20 = 1): 0.87 at 20`/20`C - Vapor Pressure: Not applicable. - Percent Volatile by Volume: Not applicable. - Vapor Density (Air - 1): Not applicable. - Evaporation Rate: Not applicable. - Solubility in Water: Appreciable (approx. 99X).

• a:ssaasaaaa

~ sssssssasssasaassssasssasssasassssssasaassasaaasa:sssasaassssasas:ssas
' • • • •. 

### SECTION IV. FIRE AND EXPLOSION HAZARD DATA 

### - Flash Point: Not applicable (Noncombustible). - Flammable Limits: Not applicable. 

### - Extinguishing Agent: Use appropriate agent for surrounding fire. - Special Fire-Fighting Procedures: None known to Sulfamex. ==-•

~ 

### : -' - Unusual Fire and Explosion Hazards: None known to Sulfamex.'. saaaaasssassasasasaasssaassasssaa:sssaaasaa

~ ssssassaasasaasasssaassssaasasaasasaas

- . J . • 

### SECTION V. REACTIVITY DATA - Stability: Stable. 

### - Incompatibility: None known to Sulfamez. - Hazardous Decomposition Products: Decomposes to oxides of manganese and sulfur.

, - Hazardous Polymerization: Will not occur. -

sss:assasasassssasssssssssasssssaasssssssaasaasssasasasasssssssaassssssssasasssssss

. - - - . . '

. . ~ - ..':

. j . •



### SECTION VI. TOXICITY AND HEALTH A. EXPOSURE LIMITS it:. J C.^ J 

### - OSHA Permissible Exposure Limit (PEL):. Manganese sulfate (asIa): 5 mg/m3-C. 

### - Threshold Limit Value (TLV): Manganese Sulfate (as'Mn):--=5mg/K3-6,

~ 

### = ACGIH, 1982. ;::.._.... ;; r.~~ 

### - A NIOSH industrial hygiene analytical method_for manganeseis'available:
. (1) - An industrial hygiene analytical method for Manganese Sulfate is available to health and safety professionals upon request. ' 7

~~ 

### ' = ~i~= ~ 

### '''• 1 • Y z = 

### B. EXPOSURE EFFECTS 

### Inhalation : May be harmful if inhaled. May cause irritation of the nasal passages. 

### Eyes : Dust may cause irritation. 

### Skin: Prolonged or repeated contact may cause irritation. 03/12/90 • MSDS: 001:1 

## r

... . IC10-C. SKIN AND EYa rnUlc.t.,.lva



### Safety'glasses should be worn in any type of industrial operation. Protective 

### gloves should be worn. _.-.. D. OTHER CONTROL MEASURES An eye bath and washing facilities should be available. Wash thoroughly after handling.
sssaaassssasasaasasassassaassassssaasoasasassssaa
~ ss:sasasassasasaxs:zaassssasssaas 

### SECTION VIII. SPECIAL STORAGE AND HANDLING PRECAUTIONS 

### Since emptied packages retain product residue, follow label warnings even after package is emptied.
aaasassssasasaaaa ~ aasaassasaaaasaasaasass:sasaszsss:sssasasassssssssaaaassasaaaaass 

### SECTION IX. SPILL, LEAK, AND DISPOSAL PRACTICES Steps to be takea in case material is released or spilled 

### : Collect and contain f:r salvage or disposal. Waste Disposal Method 

### : Landfill. Observe all federal, state, and local laws concerning health and environment. sasassaszzsasaazssss=a3ssssssssna=sassaassaaasas=saassmaassass=saaasassxssassssassss 

### SECTION X. ENVIRONMENTAL EFFECTS DATA A. SUP4iARY: This product has not been tested for environmental effects. However, some laboratory test data and published data (7,8) are available for all of the major.components of tFiis product, and these data have been used to provide the following estimate of environmental impact: This product has a low biological oxygen demand, and it is expected to cause little oxygen depletion in aquatic systems. It is expected to have a low -potential to affect aquatic organisms, secondary waste treatment microorganisms, and the germination and growth of some plants. If diluted with a large amount of water, this product released directly or indirectly into the environment is not expected to have a significant impact.
ssasasssssassszsssssssaaassasssssssasssssxssasaaasasasasssssaasasassssaaaasssassassa 

### SECTION %I. TRANSPORTATION - - - - DOT Hazard Classification: Not regulated".by-DaT as:sasssssasssssssssss:aa:sa::aasssass:aaassaaasssasasasasssssas:assssaasass:sssssss 

### SECTION BII. REFERENCES , 

### 1. NIOSH Manual of AnalyticalMethods , 2nd Edition, Volume 2. Issued by the : National Institute for Occupational Safety and Health. Washington, U.S. ; ~ ; ~ 

### Government Printing Office, 1977, Method S5. 2. H..C. Hodge and J. H. St4rner, Tabulation of toxicity classes. Am _. Ind: Y



### " Hyg. Assoc. Q. 1949; 10:93-96.

~ 

### -
MSDS: 001:1 

### 03/12/90


# ' /~~

### C: FIRST AID

Inhalation: Remove from exposure. Treat symptomatically, and get medieal attention if symptoms persist. I 

### Eyes 

### : Immediately flush with plenty of water for at least 15 minutes aad get medical attention. ' Skia 

### : Immediately wash with soap and plenty of water. Wash contaminated clothing before reuse. D. ANIMAL TOXICITY DATA The composition of this product varies f rom oae batch to another; however, toxicity data felt to be representative of this variable product are provided below: Toxicity

Teat Species Result (2) Clasaification (3) 

### Acute oral LD50 Rat 1600-3200 mg/kg Slightly Toxic Acute oral LD50 Mouse 800-1600 mg/kg Slightly Toxic Dermal LD50 Guinea pig >1000 mg/kg Skin irritation Guinea pig Slight Eye irritation Rabbit Moderate In the 1930's, manganese ore mining and processing operatioas were studied,.and it was determined that chronic overexposure to manganese ore dust produced a disease of the nervous system with symptoms similar to Parkinson's diesease: ' tremor, rigidity of facial expression, stooped posture, and stiffaess and slow

### ness of movements. (4) Other reported illnesses include pneumonia and metal fume f ever. (5) Although these effects in humans have occurred from exposure to manganese ore, manganese dioxide, and finely divided manganese, a thorough search of the world medical lfterature has disclosed no reports of such effects occurring,-from exposure to manganese sulf ate, the form of manganese present in Tec Eastman Chemical Products, Inc. reported that no neurotoxicity, pulmonary disease, nor metal fume fever have been seen in Eastman employees who have worked with Tecmangam for many years, although irritation of the nasal mucous membrances, skin irritation, and eye irritatioa have been observed. (6)
s t • ' liiisiiliiii79ialisii=iiiiiiiii=iiiiiii=Siiiiii'SSi

~~ iiiii! iiiiisiiiiiiiiisaisiiia 

### SECTION.VII. PERSONAL rROTECTION AND CONTROLS A. R.ESPIRATORY PROTECTION An appropriate NIOSH-approved respirator for dust should be worn if needed. B. VENTILATION ' 

### General: Recommend at least 10 air changes per hour for good general room ventilation. Local Exhaust: Recommended to control dust. See Section VI-A for information on exposure limits. Maintain workroom air conceatrations below irritating levels.
MSDS 001:1 03/12/90 

# j qz

.

### ' 3 R. 

### H . Flian, c !

~ 1 . VU. ~ui~ •a.a..6....-- - "--- - o - -

~ C. 

### Public Health Bulletin No. 247 

### , 1940. .4. A. Hamiltoa aad H.L. Hardy, Industrial Toxicology 

### . Acton, MA, Publishing Sciences Group, Inc., 1974, pp 127-130. 5. Battele's Columbus Laboratories, Wafer Quality Critical Data Book Volume - 3- Effects of Chemicals on Aquatic Life 

### , Selected data from the literature through 1968. Washingtoa, U.S. Eavironmental Protection Agency, Project 

### No. 18050 GWV, Contract No. 68

- 

### 01

- 

### 007, 

## May 1971. 6. J.E. 14cKee and H.W. uolf, Editors. Water Quality Criteria 

### , Publ. No. 3-A (Revised). State of California, 1963.

ss ssasssssss:ssas:sasssssa:s:saaaaaa=sssa=aaaasaa:aassass:ssas:sssssas:sassss:ssss 

### The information coatained herein is furnished without warranty of any kind. Users should consider these data only as a supplemeat to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources .to assure proper use and disposal of these materials and the safety and health of employees and customers.

~ ss ssssss:s:ssssss:sass:sssasssssssssssassssss:s:sss:ssss:sass:s:sas:ssassssas:sss

MSDS : '001 : 1 

### 03/12/90. .. • ~ ~ ~ - - .:':_:+i:- .• J '. . ~ i t' _
. . • • r ~~ ;\ • ' + .1 ~ - . .t ~ l • -- ~~ '~• . ._• .:
~

~ _ .G....a. . ~ ..._
_ _•...-

.. - rVJ _.1 • ~~M1~~ =_' .a. ~~.~~+•~ tt•-• ~ r• 1, .•3-

~ l r.. ~~ _



# t'C

~ - :~ 

# H
... .i

~ 

# .-, _- 3 • _ .3

~ 

# ..._ . .,1! _.—

. ~ 

# !- :t , # • rk~i~:~ j 

# -;;• , --u ..; ..... ... . •a '• •. , . -. ~~ 

# .. :_•

~ 

# _.:, . , ; a.._7_

~ 

### .:. -- 

### Z 

## ±. ati0° 

## = ~~ 

## ':s :CiSL:.

~ 

### :_.

~ 

### t;'



## . ~ 

### .'° 9

~ 

### ?O

~ 

### B2'JdB

~ 

### , ; ,31!'_il;t

~~ 

### ' : i-_ -,.

~ 

### '...! t5:. ~ ~ 

### =- ='al.?? • —'

- -~ +^- 

### + 

## - . - ~ -a'r

.~ 

## sc

~ 

## iA=i ~°- ~ ~•~' w 

## '• ,.. ~ 

## _'_,

- ' ~ 

## —,. ... ~.~ 

## .;_. J - - - - ' .
. 

## . -;------.____

~ 

## ..... ~~



## l:

~ 

## *;.
~ 

## . - • -- _ ; _- r



### . . _ tr-... ._ 1 t ~ 

### _ t 

## ,-._.`..,-_.- =~ 

## t:r•::
. -. ,' ~ 

## . -

•- •. ~ . . ~ . . . • .. .4Y ~'~~ : 'l : ~ •.. r ' f . ~ .\'

~ M \•
.. .=1 .'7•S• .• ~ . .



### - . ~ J 

### _._ 

## '

_ ~ 

### •+- •
~~ _ }t 

### - : ~ i.~~.~~ :~ 

### .:'.. __.

_ .... . _.a•s

~ 

### _w .._ _.. . ... - •
~ 

### _..... ~ 

### a_...-. 1s - ..-

~ 

### - - ~



### . _ ._ _..-.-.

~ 

### -_..=_._c:c......-.._

~ 

### --_=-.__r_.._.`

~ 

### .....:_,_».,:--

. .. . _. ~ 

### ..-. .. . ..

. . ~ 

### .. . .-:..I

. . - . . , . .. ._:

~~ 

### _i

. •?_ , • . .._ -. ' . . .. , . . ... ~ 

### -_ . . , .. . . _i

~. ~ 

### -. ' - "

. . . • . _ ..: .. ~ 

### . - ' - _ . •
~ 

### ' •

~ 

### . • . ic. .:(1 _.

.. . ' . . . 1_

~ 

### .. . ...- ... . • . . - . .. . . . -.. .. . . . . .. ; ... _ _[.

. . - _ t• - . ~ ~ ' ~ 

### - - ~ 

### .- .. . . .._.._-... ..-. _•7

~ 

### '..

~ 

### • .. : .- . _ ~ 

### • .-__ ~ 

### _ .- ...__.-. _:•.

~~ 

### .:a=

~ 

### xc•

~ 

### :..-= z.a

~ 

### _.:_s aa.

~ 

### . _ •
~ 

### ' - . .. . .

['

J 1 ~ - ~ I -~ 

### .. •.:• 1 :..9

- ♦

## ~ 

# 7 AMERICAN MICROTRACE



# MSDS.

~ 

### Generallnformation Product Na.me:':14ian=Gro®, 1 'LM2h=Gro'®'t1S"' ~ 

### Molecular Formula: MnSO41-12O Chemical Name: hianganese Sulfate Monohydrate Molecular WeighL• 169.01
ContacL• Ametican tifiaoTrace Phone: (800) 544-3155



### 569 Central Drive, Suite 201 

### or: (402) 729-6191 Virginia Beach, \/A 23454 Date Lssued: 2/27/91 Fax Phone No: (804) 463-8156 For Emergency Assistance Involving Chemicals - Ca11 Chemtrec 

### (800) 424-9300

s . ~ ~. s~• ~ "~ 

### ComponenG Manganese Sulfate Monohydrate CAS NUMBER Permissible Air Concentration: Manganese Sulfate Monohydrate 5 mg/m 3 Ceiling (ACGII-i) (
~ 

### As Mn) Percent: 90% 7785-87-7 FerYic Oxide - 5 mg/m 3 1.5% 1309-37-1 Aluminum Sulfate 12 mg/m 3 1.5 0 /o 1344-28-1 Silica Dioxide 5 mg/m 3 1.0 0 /0 7440-21-3 G 

### First Aid Measures Ingestion: If large amounts are ingested, if victim is conscious, immediately give 2 to 4 glasses of water, and induce

vomiting by touching finger to back of throat. Do not give carl,)onates. Get iffedical attention immediately. ~ ~ l • f\ ``~ ~~ ~ 

### Eye Contact If eye irritation eaists, flush thoroughly with plain water. V'K n 17 Skin ContacL• If skin irritation eaists, wash with soap and water. D. 

### Harards Information J A
~ 

### ,' 3 ~ 19~ ' 

### 'THealth Effects" H
~ ` 

### Inhalallon: May cause irritation of nasal membtanes and upper respiratory tra ' ~~ ~ w 

### Ingestion: of large amounts may be harmful. Eyes: Contact may ~~a 

### tatio Sk9n: Contact may crause irritation. -- +r "" Mediral Conditions Possibly Aggravated: Respiratory problems could be aggravated by inhalation of dust Unusual Chronic Toa.idty: Some manganese compounds are known to cause acvte and chronic toxiciry which primarily involves the central nervous system, however, there are no known reports of such effects from eaposure to manganese sulfate. Chronic exposure to silica dust may cause silicosis, a fiberotic lung disease. "Fire and Eaplosion Data•• Flash Point: N/A , Fire and Exxplosion Harard: Negligible fire and explosion hazard in dust form when exposed to heat of flame Flammable I3mit N/A Unusual Fire and Explosion Hazards: None 5/15/91



### ~~~

## E.

F4re Extinguishing Agents Recommended: (Dry chemical, crarbon dioxide, water spray or foarn) as appropriate for surrounding materiaL Fire Estingu.ishing Agents to Avoid: None Spedal Fire Fighting Precautions: Use self contained breathing apparatus Engineering Controls: Use containment and/or local exhaust ventilation to control dust Nor

- mal Handling: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Maintain good

housekeeping practices.

. 

### Storage: Keep dry Spill or I,eak: Collect and contain for salvage or disposal. Vacvum or sweep keeping dust to a minimum. Spedal Precautions/Procedures/Iabels Instruct3ons: See "Normal Handling" Note label signal words •Waming!' Personal Hygieae: Wash thoroughly after handling and before eating or smoking. w

fTf.1 ~Li~-~'~ /_ /! ~'~

. . ~ l

~ l'• / // • 

### Respiratory Protection: Use NIOSH ,MSHA approved dust res_pirator if irritation exists or in dusty areas which ---

- J - e:rceed mg/m 3 . ~ ~ Eyes and Face: Glasses, goggles, or face shields are recommended if irrftation exists. Ha.nds, Arms, and Body: Gloves and protective clothfng should be used if ircitation exists. Other Clothing and Equipment: None

~ 

### Physical Data Description: L;ght Tan to Pale Gray hlaterial Boiling Point: N/A ' Solubility in Water: 50% by weight

: ' ~ Y • ~ ~.~ 

### PIL- 3.0

- 

### 5.0 ® 109'o Solution Yapor Pressure & Density: N/A

_ Melting Poi;nt Decomposes above 450° C.
Stabllity: Stable under normal temperatures and pressures. Polymeriration: WIll not occur Inco mpati'biliti es: Iv'one Decomposition: Thermal decomposition may release toxic fumes of manganese. Possibly ozides of sulfur. I Environmental 

### EPA Harardous Substance: Yes Feder'al RQ Quantity: 1000 LB/454 KG DOT Ha7ard Cla.ss: N.O.S. Orm E NA 9188 RQ Waste Disposal Method: Landfill or field RCRA Status of Unused MateriaL• Not listed applicration at agronomic rates 

### J

. Permi.ssible concentradoa references: "TI.V' -"Threshold Limit Values for Cheniical and Physical -- -. - Agents in the Work Environment' 1084-85 (ACGIIA Harard Information References: "Merck Index" lOth Edition, 1983. Merck and Company, Inc. & Additionallnformation 

### This chemical may be subject to the reporting requirements of Section 313 of Title III of 49 CFR 372 of the Emergency Planning and Community Right-To-Know Act

Thts rnatertal safety sbeet is o,,(fered solelyforyour infornratton and tnvestigation. It provfdes no warranties eitber express or impiteci; and assumes no respottsibility for the accurary or completeness of tbe data corrtatned berein. 5/15/91 

### l ~.~SECTION I

MANUFACTURER
EMERGENCY TELEPHONE CHEMICAL NAME TRADE NAME CHE1vIIC4L F.Ah4ILY FORMULA C4S NU?v1BER NPCA - FLMIS HAZARD RATL\G Health I 

### MATERIAL SAFETY DATA SHEET Flat"tnability o Reactivity 0 ZINOX Maximum Personal Protection E AMERICAN CHE'vIET CORPORATION P.O. Box 1160 East Helena, MT 59635 (406) 227-5302 ATTN: W. H. Porter or Dan Brimhall Zinc Oxide ZINOX Zinc Oxide Zn0 1314-13-2 SECTION II fiXZARDOUS INGREDIE.\TS PEL + TLV ZINC OXIDE c RESPIRABLE DUST 5 mg/m 3 97.0 ro(Tj•pical) (94.5% Min.) TOTAL DUST 10 mg/m' Exposure is _rnerned by the 8 hour TI

~ A established for Zinc Oxide. Zinc Oxide is not carcinogenic material as listed by OSHA (29CFR1910) or ACGIH (Appendiz A. Threshold Limit u_!ues ,°or Chemical Substances 1984-1985). SECTION III PHI'SICAL DATA Boiling Point (f): Specific Gravity: Vapor Pressure: Percent Volatile by volume (90): NA H : 0=1 5.6 NA Oq Vapor Density: Evaporation Rate: Solubiliry in Water: Melting Point: Appearance and Odor: NA NA Less than 1%. 3590`F Fine powder. Cream yellow No odor

. SECTION IV FIRE & EXPLOSION HAZARD DATA
~ Flash Point Flammable Limits LEL UEL NA NA NA Extinguishing Media: NA ecial Fre Fghting Procedures: None known. ual Fre Fahtin¢ Procedures: None knoun. SECTION V HEaLTH HAZARD DATA Threshold Limit Value: See Section II Signs, Symptoms, and Effecu of Overexposure: Nausea, chills, diarrhea. May cause upper respiratory irritation; skin irritation (oxide pox); fever, eye irritation v%ithredness, pain and conjunctivitis; preexisdng lung diseases may be aggra%ated by exposure. Could result in respiratory irritation; preexisting lung diseases may be aggravated by exposure. Could result in respiratory disease if over ezposed on a chronic basis. _ Primary Routes of Entry: Inhalation and/or ingestion. Emergency and Frst Aid Prcredure: Remave to fresh air. Lay patient down. Cover with blanket. If irritated, }]ush eyes and skin with large volumes of fresh water for 15 minutes. Refer to !v[D. SECTION VI REACTIVITY DATA Stable X Unstable Conditions and Materials to Avoid: Mass build up under reactive conditions such as but not limited to acids. Zinc Oxide may react violently with strong reductartts such as organic cempounds, i.^.cluding chlorinated ruaber at temperatures over 4'0°F, (a Flammabiliry rcaccion u•ith linseed oii %ac reported once), and metals including but not limited to Mg. Hazardous Decomposition Pr+oduar: Above melting point (3590°F) zinc fumes may result. Hazardous Polymerization: Will not occur. SECTION VII SPILL OR LEAK PROCEDL'RES Steps to be taken in case material is released or spilled. Clean up with vaccum or conventional tools. Avoid dusting. Waste Disposal Method: Approved land fill. SECTION VIII SPECIAL PROTECTION L1'FORIVIATIOIV Respiratory Protection: Canridge type filter or approved dust mask. Refer to Respiratory Protective devices approved by Bureau of Mines Circutar IC 8436. Ventilation: To keep below listed TLV in Section II, ase general dilution type ventilation. Proteaive Gloves: Wear if skin contact is probable and skin is sensitive.

. Eye Protection: Safety glasses or goggles. Other Protective Equipment: Long sleeve shirts if contact is probable and skin is sensitive. SECTION IX SPECIAL PRECAUTIOTS =autions to be taken in handling and storing: Keep lids tishtly sealed. Store in cool, dry place. .her Precautions: Do not take internallv. Avoid prolonaed contact with skin. A'ash with soap and Water after contact. SECTION X SARA TITLE IIIThis product contains a zinc compound (Zinc Oxide) and is subject to the reporting requirements of Section 3 L3 of Title lI1 of the Superfund Amendments and Reautho-ization Act of 1986 and 40 CFR Part M. Date: tifarch 1, 1989 (Rev. 4) ~ ll~.~ ~ ~ 

### ,,,, . ~ ~ 

### • _ ; _

~ 

### ^

~ 

### _ - -: ~ ~ s, ~ 

### - s'-`" ~'~"~'~ 

### "` -a;

~ -~-~ 

### ' .

,

. ~ ,._~ ~ 

### .,: .

~ 

### - _ , . _ -- ~ ~ 

### -.._ ~ 

### -a- -

~ 

### •.ti:-., :

~~ 

### —' .

9 

# EPA MACT Information Collection 

# Request Response

• ^` ~ ;`

~ "' ~

-.. -...•, ~..~'~ ~.,~;, ~ - d~ ;;,4,

~~ ~'~ `-~ _~•~~ - ~ "'—t

~ .`.

~ .a ~

i-a''' ~- ~ ~+' ~ .T ~'~ _~_

~

F 

### .. _-ts ~.~;'~ °'~-;c' 

### _1i. _ _ _ -..

~ y 

### . ,, _ .. _ • . ~ ~

_ . . ~ +•+.y

~ r. iy_ .-a'

~ r' ~ i ..L ~ . YPc.

4 ~ ~ L - 4

_ 

# .-. . ~ 

# •:_.:

~~-~~ ~ 

# , _.-. d

~ - J_i ~ ,: , l..!5s ~~~4

j

. y " 

### r _

. 

### ,+ sx.'L ~!~

i ~ •"nJw- 1 ~K

.

~ - ~ T 

# R

~ - 1

_ .. ti _ , • -- -

- --. - ~,.~
. ~~ — -- ~ 

# _t

~ 

# ... ~ .. ~ a_. ' 9}—

~ +:_ a ~ •,—, ._-

~

~ } ~

~

- 1 ~ 

# ' • '

_ . .;.. #

. ~ ~~~ ~ 

# ,. .. :.

~ 

# • • , ~ 

# • ,

1 ~ 

## _ . -- • - ."`-9'! ~'•~ 

## - x...r -..

~ 

## wt +

~ 

## ++-_ :

~ 

## _-.- - . . ~ 

## . . - 

## , q

~ 

## -.

~ ~ .~

- 

## ,~ — K 

## ~ _T__a• 

## ~

~

# MACT Information Collection Request Response from Boral Bricks, Inc.

Table of Contents • Information Collection Request • Appendiz A - MSDS's

/ 9y

### Enclosure 2

INFORMATION REQUEST FOR BRICK AND STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS 

### Instructions Please return the completed informa.tion request to: Bruce C. Jordan, Director Attn: Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of'Air Quality Planning and Standards Research _i"angle Park, North Carolina 27711 If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at (919) 541-5435. 

### Thi.s information request should be completed for each facility that manufactures brick and structural clay products, including facilities that are not major sources. Information is requested for all processes at your plant that emit hazardous air pollutants (HAP's), including those processes that are not associated with brick and structural clay products manufacturing. Sections II through VII request information specific to brick and structural clay products manufacturing, and Section VIII requests information on emissions of HAP's from other processes located at the facility. Processes that may emit HAP's include those processes that use or handle any ma.terials that contain a HAP compound, all processes with elevated temperatures, and all other processes in which HAP compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is included as Attachment 1 to this information request. Attachment 2 provides background information on the requirements of the Clean Air Act and explains how the information requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations and acronyms used in this information request. Several tables are provided throughout the information request for your convenience in answering the questions. An example response is given (shaded first column or row) in each table. If additional space is needed to respond, please make copies of applicable pages. If necessary, please make copies of this informa.tion request for additional facilities. No additional emission testing or monitoring is required to respond to this request. II. 

### General Facility Information A. Name of company 

### Bora1 Bricks Inc. Name of facility 

### Muskog_ee Plant

Page 1 of 28

~~ S

### Enclosure 2
Facility address: No. and street 3101 West 53` d Street South City Muskogee State Oklahoma Zip74401 Latitude and longitude coordinates of plant: Lat 35°40'53" N, Long 95°24'35" W Standard Industrial Classification (SIC) Code(s) of brick and structural clay products manufacturing operations 3 Dun and Bradstreet No. 00-327-5682 Total No. of employees for company >1,500 for facility 4 (If facility is a foreign subsidiary or if company has foreign subsidiaries, include number of employees not based in the U.S.). Please complete the following shift information for the facility: Shift No. of employees Hours per shift Days per year 

### 1 41 (Admin, Maintenance, 8-12 360

Manufacturing, Mining) 1 Kiln Fireman g 365 

### 2

— 

### 3 amtenance persomel 8 360

1 Kiln Fireman 8 365 3 1 Kiln Fireman 8 365
B. Respondent name Andrew S.R. Wichers Respondent title Regional Safety Manager Respondent address (if different from above) and telephone number: No. and street P.O. Box 1178 City Columbus State GA Zip 3 1 902-1 1 78 Telephone No. (334) 480-2407 Name and telephone number of technical contact person (if different from above) Name David Johnson Telephone No. (334) 480-2487

Page 2 of 28

~~

### Enclosure 2

III. Information on Operating Permits and Apnlicable Federal Emission Standards A. Please provide copies of relevant parts of all operating permits and permit applications for your facility. Relevant parts include the sections that provide specific information and data on: processes that emit HAP's; the use of HAP- containing substances; emission levels for HAP and surrogate pollutants (i.e., VOC for organic HAP's and PM for metal and other particulate HAP's); emission control device design and operation; monitoring and operation and maintenance (O&M) procedures for control devices; and generation and releases of other media such as wastewafer and solid waste that are associated with the operation of air pollution controls for brick and structural clay products manufacturing processes. If the operating permit or application contains the same information requested in any part of this questionnaire, you may respond to the requested information by referencing the page or section of the permit/application to avoid duplication. If you reference your permit or application, you must supplement your response with all of the additional information requested in this questionnaire that is not included in the permit or permit application. If you prefer, you may submit the requested information from your permit/application on a 3-1/2 inch diskette. 

### B. If any source or emission unit at this facility is subject to a New Source Performance Standard or other Federal emission standard, please identify the source and applicable standard. Examples of applicable NSPS include 

### 40 CFR 60, Subpart 000 - Standards of



### Performance for Nonmetallic Mineral Processing Plants, and 

### 40 CFR 60, Subpart UUU - Standards of 

### Performance for Calciners and Dryers in Mineral Industries. Based on the Title V Permit application, the followina sources are subject to NSPS: All belt conveyors 40 CFR 60 Subpart 00060.670-676 Standards of Performance for non-metallic mineral Qrocessing plant• Refrigerators and Air conditioners 40 CFR 82 Subpart F 82.150- 82.166 Recycling_& Emissions Reduction. 

### IV. Brick and Structural Ck Products Production and Raw Material Consumntion Informa.tion A. 

### Please provide the 1996 production rates and the current production capacity for each type of brick and structural clay product manufactured (e.g., structural brick, clay sewer pipes, structural clay tile, etc.). Note that production data should be provided in units of tons per year (tons/yr). Product 1996 production (tons) Production capacity (tons/yr) Brick (fired weight) 127,743 138,621
Page 3 of 28

0 

### 20 tl

### Enclosure 2

B. Please provide the type and amount of each raw material and body additive used in 1996 for manufacturing brick and structural clay products at your facility. Examples include clays, shale, and any additives that are mixed into the raw material prior to forming. Indicate additives by chemical compound, rather than by trade name. If the information requested is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. Raw materiaUbody additive Amount used in 1996 (tons/yr) Barium Carbonate (dry weight) 33.85 P+K Fire Clay (wet weight) 18,393 Blue Shale Clay (wet weight) 78,007 Yellow Shale Clay (wet weight) 49,736 Porter Fire Clay (wet weight) 13,343

C. If available, please provide a copy of the MSDS's for the raw materials and additives listed above. See Appendiz A D. If available, please provide chemical analyses, including fluorine, metals, and organic content, of the raw materials listed above. Not Available

Page 4 of 28 ,--)dZ

### Enclosure 2

E. Using Table 1, please provide information on the consumption and HAP composition of all glazes and colorants that contain HAP's or HAP precursors a.nd that your facility applies to brick and structural clay products. Indicate whether the coatings are glazes or colorants. Also indicate the type of product that the coatings are applied to and the total weight of coatings used in 1996. If the glazes or colorants are formulated at your facility indicate so and provide the production capacity. List each ingredient of the glaze or colorant. Beside each ingredient, indicate the total amount of the ingredient used in 1996. If the information requested in the table is contained in your facility's operating permit or permit application, you niay reference the applicable sections of the permit (or application) rather than filling out the table. F. In the space below, please indicate any glazes or colorants used by your facility that do not contain HAP's and are substitutes for HAP-containing glazes or colorants used by your industry. Indicate which HAP-containing materials the non-HAP glazes or colorants replace. Describe a.ny limitations on the use of those substitute glazes or colorants. 

## NONE

G. If your facility colors brick and structural clay products by flashing, please indicate the types of substances used to flash the products and the amounts of those substances used in 1996. Substance Amount used in 1996 Units (specify) Natural Gas Unknown Not Applicable

H. If available, please provide a copy of the MSDS's for the glazes and colorants used by your facility. If your facility prepares its own glaze, please provide any available MSDS's for the glaze ingredients. See Appendiz A

Page 5 of 28


## a1
~ 

## 3

### Enclosure 2

TABLE 1. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND



## COLORANTS Type (e.g., glaze, colorant) EXAMPM Coatings/Colorants Glaze . Type of product glazed or Stractural tile Brick colored 1996 consumption (tons/yr) 1,140` 349 Produced at facili ~



### t3' (Y es/no ) ;. 

### Yes No Production capacity (tons/yr) , 

### N/A Total usage (weight) of each Totat 1996- Tota11996 ingredient (that is a HAP, 

## :.; In gredzent " usage, ; .tens=' Ingredient usage, tons contains a HAP, or is a HAP ;- 

### recursor in 1996 

## P ) = _ _ 

## 6s1l' cl

~~ 

## `:: = :

. ..... -: -; 

## 63

~ 

## = _ Manganese 8.78 

## :: Cr ~o~ a.2~ :: 

### Soda Ash 30.93 

# vEl
~ 

# `:: > ; ; . =
... ... .. 

# '' ' ' _13 ~ f~ 

# ;;°- ;- _;-. S thetic Red



## Yn 0.25



# ...... ....... ..... .: .. .. 

# - Iron xi e 

# Nt

~~ 

# - >' :' - ... . ' ` O.00r :;';:

..

If additional space is required, please make copies of this page. If the information requested in the table is contained in your facility's operating permit or permit application, you ma.y reference the applicable sections of the permit (or application) rather than filling out the table.

Page 6 of 28 

### '; 2 C</","

### Enclosure 2

V. Description of Brick and Structural Clay Product Mqnufacturipg P,Locesses A. Please provide a siniple process flow diagrarn for each brick and structural clay product manufacturing process line, An example process $ow diagram is provided in Figure 1. A diagram of the plant layout with all processes atxi emission points clearly labeled is also acceptable. Assign a unique identification numbex (ID No.) for each proeess that has associated emissions (e.g., TK-1 for tugnel kiln no. l) asd each emiasion point. Please identify

~



### 11 eruission points, including those that do not emit HAP's. For emission points that are vented to an air polllrtion control device (APCD), assign an ID No. to the APCI] (e.g., BH-1 for baghouse no. 1). For emission points that are uncontrolled, assign an ID No. to the uneorrtrolled stack (e.g., S-1) or building roof vent (e.g., RV-1). Use these same ID Plos. throaghout the rest of the infarmation request for any responses that pertain to uny process or emission point.

Page 7 of 28
'=P-D-

~ 

### --

### rn

_ Vl ~ 

### ?U

~ ~ (D a) LL Q Q

a) a. Y U O 

### ;+1
otf 1
~oa L C

~ o ~ t ~ U ~ ~ ~

~ 

### (D a)Uc 0 a 

### Q

rn c ' v 

# L ^ X W

cd rn_

. ~ 

# o~ U a~ U

0 6 0) O)a C. 

### U CO ~.~ ~

~ .~ 

## m d 

### L 0 ~ ~ 

# .~

~ ~ 3

~ 4

~ ~ C 

## 'a

.~ m

~

' 

### L 7 r.~ 

### c~ ~ 3 C ~4
~

a~ ~ C ~ :3

~
~ 

### U) m

~ rn ~ ' '~ v U i c C/) U) a~ m ~ 

### 0 c ~ a ~ U JC 0 ~ U 0 3 ~ 

### .--, O y

0 c~ ~

~ 

# a o W ~ ~

~ T , ~ ^

•~ 

### .. `. U N N

• L a) >

, 

### u



### ~ a 

### a 0 

# _ m L. C



# v aE

~ ~ 

### `a _c. Y } ' ~ ~ ' o ~ 

### a

.~ `o c O 1

00 N

: M M oO u. Q a~ .0 

### CC c ~
~ ---

### ► a? ' ca

~ 

# A --

~ 

# a , 3

~ Q
~ 

### ~ a ~ ~ 

## N L 

### ( 1 ) ~ ; --- 

### ~ ~ ------- 

### ~ 

### --► a

~ ..,

~ ~

~ M O I I Q
' ~ 2 ------- ^; --► 

# 0

_

~ 

## ) 0b

## Enclosure 2

B. Using Tabiea 2A and 2B, please provide cwtrent production rates, production capacities, and related information for each type of equipment used in brick and struetural elay product manu.facturing. Tn Table 2A, provide the requested 'mforcmation for only those sources t.hat are known or expected to emit HAP's. In Table ?B, provide the requested informa.tion for all thermal processing, such as drying and firing sources. For combustion sour+ces that use different fuels, Table 2B should be completed for each type of fuel. For example, if a kfln typically is fuvd with gas, but periodicatly is fired with oil, one eolumn in Tabte 2B should be completed for the kilts when fired wi#h gas, an,d another cokgrxi shoukt be completed for the same kiln when fred with oil. Prsovide the data in tln~ writs listed for each row.

Pap 9 of 28

~v~~ . 0 0

~ c_ b a ~ a .~ Y a 0 U ti

. ~

~ CC Y N
~ G 'O N Y ~ N
~ C N w C O y

~ y U ~ O u"

3 N O Q 

### . O

~ C y

a~ i ca

.~ q Y
•~ ~ U C". 

### O ~+

~ w U N

O ~ 

# .o >, ~ cl N ❑ .' U O +~ pq rA t=

U N a~ a 

# a „
0 0

o ~ a~ 

# a a o ~ co 

# a. ~ 

# o N

~ Il -o

. o

~ , 

# M_ , ti 

## ca A LL

~ ~ 

## w O
~ a> 

# 'a 0 U

~ af

~ N ~ ce N a b

~ ~. .~

~ a~ ~.
~ U c~ ~

~ ❑ O ^G
~ 

### w
~ 00 N 4-i 

# O O_

~ bA c~ 

### a

~ 

## N W 

### ~
~ E--+



# m l

## U F~ W

rA 

# x 

# z °

~ 

### ~

~ o ~ ~ 0 ~

~
~

~



### ~



## ~ b b 0 ~ O G 

## z 

## ~ ~ A cr 

### ~ o ~ o ~ on

.~ ~ c~ ~. ~ o, 

### 0 ~ ~ ~ U

~

~ O ~

.~ 'O N . ' t " .J
. c~ ~ 0 U y

..~ Cd (Z



### .d o U tw H 

# ~

~ a'

~ 

### o ~ c0
4-.

•

~ "' r+-
~ rn po p Q. 

### •S v U vi ' u n N

~ ~ ~ In C13

U

ct

~ ~ O ~ 

### o ~ ~ 00



### N

~ +r O
N

~ ~ 

# wI I I I ~

..

~
p. Li ~

o ~ ~Rp

# w©m

~ 

# m ~ ~ ^ a - ~ O ~ N ~ 

### O '


### y _ 

# 0 ^ O ~ Cd ~ 3 ~ ~ z cn
^

~ ~ ~ ~ ` ~' z

=° 47 Ci ,
~ ~ ~

~ ~4 

### '`- : ~ 

### : , e ~ ~ 

### t/}.

~ ~



### _ ~~ 

### ,• ~ 

### O+ : Sk ~ ~ .` ~~ ~ ~~:. -. :;;i ~ - . ~ .'. ~

~ 

# o~ z 0 ~o 2 ~ A ~ h * 

## x v i4 ~ yZ , • O +, s., O ~••~ O

Q+ O-~ O,~ •~

-~ ~ 

## o 

# ~ p b

o ~ 06 c ~ ~ a~



### ~ 

## G f

### The following notes are used in Tables 2A and 2B:



## NOTE 1 Except as otherwise indicated, Boral Bricks does not possess process-specific data that would allow estimates to be made of the types or quantities of HAPs contained in the materials or of the resulting HAP emissions. Sections 10.5, 11.3 and 11.19.1 of AP-42 provide generally available information on the pollutants that may be emitted from sawdust dryers, clay products processes and sand a.nd gravel processes respectively. The AP-42 data are considered indicative of the types of HAPs that MU be emitted from processes at this plant but are not considered indicative of the quantities of HAPs emitted. 

## NOTE 2 Fugitive emissions occur at several points throughout this plant. Boral Bricks has no data on these emissions, and is not including fugitive sources per Feb. 25, 1998 telephone conversation between 011ie Fick (Consultant to Boral Bricks) and Bill Neuffer of the EPA.

Page 12 of 28

o~ ~~

### C. Using Table 3, please provide information on procedures used to monitor the process

operating rate for each of the pieces of equipment and HAP emission sources listed in Tables 2A and 2B. Use the same HAP emission source types a.nd equipment ID numbers you listed in Tables 2A to 2B. Indicate whether you monitor process rate or not.

Provide a summary of process rate monitoring procedures that describes how process rate is measured for the particular piece of equipment. Include where the rate is monitored (i.e., rate of material fed, rate of material discharged, or material production rate), the units used to measure process rate (e.g., lb/hr or pieces/hr), and how the process data is recorded, i.e., manually, automatically (e.g., computer - printout or stored to disk, or not at all). If you monitor process rate at both the feed and discharge ends of the equipment, indicate so. Indicate the type of monitor, equipment, or instrument used to measure process operating rate. Indicate the monitoring frequency or how often process rate measurements are made. If instruments are used to measure process throughput, indicate in the monitor accuracy column the accuracy of the instrument. The monitor accuracy could be listed in terms of a percentage of the throughput (f 1 percent), mass per unit time (±21b/hr), number of pieces per unit time (t 10 pieces/hr), or other appropriate units. Indicate the frequency that the monitor is calibrated. Provide data in the units listed for each row.

Page 13 of 28 

# a(~~

w ~

W NJ

L+ .•

N r

.w7 O

~ V

~ y ~ • ~ 

## ; ~ •~ y ~ ~

; ~ A • r 

## ~ 

# r~

` 

# ~ 

# ~ 

# ; w i~

~ ,~
, 00 N

~ 0 ~r ~ 0 C~ 

## a 78 

# ;-;

~ T --

~ ~ ;.::, 

# = -':

0 ~ ,,-~ .•-j__. --- • ~ f ~ l y ' • ~ 

### •[ ~ 

### Kj_:..:.

~ 

### .,::-_:: . ~~



### fj • ~ ~ 

## 1 ~ _.~ 

# ,_ •: ~ _ ~ 

# •C --_ __ v c ~ ~

~ 

## = 

# ~

J f:'.. • ~ •~

C p
. ~'~ •~ V " C v •C 

# ~•~~ _ ~

~••~ ~ dE~ ~ j ., • N

~ ~ 

### - O ~ 

# < _~.~ °ye ~ 

### .~~~ ro 

## A ~ a 65 

# ~ "0 Za~ ~ 

### ' ~ ~,~m ~~,, ~• ° ~~W ~

p ~ ~ vi

s ~ ~~~ ~ ~~~~•~ ~ ~ ~ cc


## ~w ~

~ c t rA
F+ ,. N 4 

# EZ

•~ , _ 4 y • ~
~ ~ d 

## i2 F

— S 

## ,4-(Z

## VI.



## Identification of Brkk azd Struclura4 Clay Pxoducl N. .tKturin Er

~ 

## ' ion Points A. Use the process flow diagrams developed for your f$cility artd Table 4 to provide the following information for each HAP emission source at yottr facility. Define HAP emisston stiarce type in terms of equipsnent, such as dryers, kiMs, etc. As in the process flow diagram, you may group multiple pieces of similar equipment. Use the same equipment ID numbers :=wated on the process flow diagram(s). If th ~: ~~ 

## urce vents imside a frrst ugh a control device, cohunn. Ag 

## or to outside ambient air without e a check mazk in the uncontrolled If tle emissiari

~ 

## ,)uree vents inside a 1-. 1 or to outside atnbient air after passing through a fabric $her, dry in?t. fabric filter, or scruk

~ 

## ber, place the APCD Ifa nwnbe,r(s) in the cohum t° i .)onding to the APCD type. If the em ission source vents throuY: .=ytrol device type not listed in Table 4, indicate the control device type in other control cokimn and p*e the APCD ID number iQ the wropriate celL In the emission test data cohnm, place a"yes" or "no" m the appropriate cell to indicate whether the specific se -,. -T has been tested f,or any pollutants, uuchiding any HAP's, VOC, PM, c i:city.

Page 15 of 28



# ,, - ~ 

# 13

# _O

~ a 

## a 

# a

~ ~ 

### W U 

## ~ ~ 

# O

~ 

### ~ C/I 

### ~



## ~ O

~

~
~ 

# w a ~ ~

~ ~ o b ~ a
~ ~ N

a~ 

# Z Z Z

~ 

# > ° W

H ~ ~ o /\ U
COO


### O ~ 

### cn ~



# _ w O

a ~--~ U

, U ~ . ~ w 

## a ~
~ U



# ~

:

. . .:.. ..:.. :.. .. .

~ U 

## a ~ 

# w 

# - a

~ Q ~ = H ~ o ~z

~ 

# - W 

# = ,:.; __.._. ;. - _::

~ 

# =_--

~ U F. . ......... .:..

~ O ~ O ~ ~ W:.: _ ...

W::. O c

~ 

## o 00 N 4-4 O

to 

### ~ c 

## w



# ,-v(

### B. Using Table 5, please provide informa.tion on stack parameters and emission estimates for each emission point at your facility that is known or expected to emit HAP's. Provide information for all APCD's, including those that exhaust inside the building. Include data for each inlet and outlet, if available, as indicated in the table. If you have more tha.n one inlet to an APCD, provide data for each of the inlets. Provide data in the units listed for each row. Provide emission estima.tes for any HAP's or HAP surrogates, such as PM for metal HAP's or VOC for organic HAP's. Emi.ssion estimates may consist of measurements reported in emission test reports or may be calculated using mass balances, emission factors, engineering judgement, or other estimation methods. Provide the emission estima.tes as emission factors in units of lb of pollutant emitted per ton of product (lb/ton). Provide complete copies of any emission test reports or other reports that document measurements of emissions. Test reports and other emission measurement documents should include the following information: process identification; location of sampling point; stack diameter, temperature, and flow rate; test method, including analytical procedures; number of test runs; emission concentration, emission rate, percent oxygen, and percent moisture for each test run; process operating rate; type of APCD; and APCD operating parameters. However, test reports with incomplete documentation may still be useful and should also be submitted. You do not need to fill out Table 5 for emission points that are covered by an emission test report that is included in your submittal. If emission test reports are not available, provide calculations that support your emission estimate, including the basis for all assumptions in the estimate. Note that eniission estimates are needed for all HAP's that the facility emits or has the potential to emit. (Please refer to the HAP list in Attachment 1.) If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 17 of 28

~ 0 

## 2 (.5~ W 

### a

~ ~ ~ 

### ~ 0 0
oo
G ~ C ~ 2 H ~ •-- ~ G

. Q , 

## 'z

~ o

O N ~ ° z o ~ M ~ • o ~ ~ •~ fl ^~ z

w ~ T+ O O O O 0

~
~ O ~ V M ~ N y

C Q z

~ ~ ;

~ ' -

:. ... .. 7 M `:.: : .. pC:. . O!;:. ,:.

~e 

### • ~

~ 

## n ~ :



### . . ~ 

### ; ;

~ . 

### .. A : ..... .. - ... 

# . . ~

. 

## •a ; ~ 

## ;: : _ , 

## ;:.. .;; - 

## ; ~ - ... $ 

# c : °

_ ; > ~ ,: ~ ,;.. .. N": ;:.::::::.' : *"ic: ::. ; :. ...

~ a+
~ ^ U to
cto 4 ~ > c

to

Cd

~

.. 

### ~ co. ~ v~ ~ r. ~ ~ ,a ~ • •^ " w

~ -1 • F i"~
~ ~+ Y w~ y~ Vl

rn 6" ~ • b L+ Q ~ ~ (1 go pQ
a cl v) 4n 'v~

'> : C ~ Z Z ca C7 a C~ i C7 ^ N ~ •; ~ vi a 00 N 4-i O 00

~
~

~
~



### ~/~

### r.

~

.~

.. ~ ~ .~

~ 

## a
~ ~ 

## w 0 ~ 0 .~

~

~ ~

~ ~ ~ .~ ~ U ❑ U N 3.
~ ~
~ ~ ~ 

# ~ a cu

~ !~

~ N
~ 00 

### N w O

~

~ ~ 

### a

~

~ O rA ~ N C G y

~ a 

### N Q'

~ 

# z 

# o z
b ~

~ 

### ' d ~ O 

## z
~ A 

## m z ~ ~I

~

.~ ~

W .~

~ ~ N

~

~ 

## c N y N

~

o ~ ~Y

Y O +' ~ O •~, ~ ~ •~

~ 

# w p 

# ~ p z 4d ¢4

~ 

## Z zz zZ

~ A ~ 

# zz

~ 

# zz zz

° 

# z zz

~ 

# O F



# ~ 

# z zz zz

~ 

# zz oA 

# ¢Q

zz zz az

~:~ . - •.:T:9:_.

~ -: . ~~ :.,

~ ::-:u:y.._ __. ......,: _.. ~ .. . .. . . ,: . ..

_. ~ :•'

~~ ,..-,.... ..:

~ ..:.<..:. 

# _ _ 

## ,:.. ._... ... ,...:..

~ 

# ..

r:

~ =i

. ':._':

~ :~ _..:.'`

_ ,,.. , .. 

# -'

. . ..,. ... . _
_ ~h~~ - 9irJ= 'L+::

. :,`

.. ~ - .xi _ :: .!!.,

~ .. - ~ •E'
__ _ - _ _ a - 

# :l-' st.: 

# -

~ 

# •..:r

~ 

# : :.

... .,.,.,. . _. ... -. .. ~ .__. , :!_.:

~ dc:...

~ ...

....... . :.... . ~ _-. ....._ a

_ x .:..: :.:.:



### ..... .{ ...

.... 

# .. .. - - . .. .. " , .... .:.. _:

~~ 

# .:

~ 

# ::

~ :-.-..: ~~ 

### . ._ ........:.:....:.:

~ . _. . :: . . ...: ., 

# _ .. . .. ....... ~ .:

~ . ,.::,,::_ ...:::.

~ :.:
~ - ., ~ ":'

~ '

__ 

# _ _ - - - - s~ 1L=

~ ' - _ ~ :':L:;i — 

### . __:y. _ _ _ -

~ ",: - _ - : ~^~ °.k..: -- - i:il

~ 

# .,.r

~ 

# .. __ _ ~ 

# ';,: -.t=. •

. ~ I ~» w .: ~ ..T?.:_:.

~ :.,:Z. ~ ~L~

- 

# - - - -

~ .

~ .. v +~ -. ::..

~ _::x ~ ~~ a:.._• ~ . T : .:.

~ _..:

. . d._:._

~ . T. _ _..:_ .. . n:: :

~ . :__ •.. . ~ .k ::

~ _:n ..:.:

~ v.
. . ..:. _ i

.

. . -.:Y ".. s 

# ... ~ :~ 

# ... ..:..:..:_.., ,~ :.. ..3:!ei:_ -_

-'

~ .::
-
~ • _
_ 

# _ _ _ 1S



# ....... ::

~ 

# _ .-, .... ... ..... . . 

# -^' F ::::
~ . ~ 

# _ .. 

# .: . ........ 

# - -- :.. 

# r_.

-_ .. .... ._. _s ..:.......... ~ ~ .:.:-... . ....-:w._.! ~ .. .r!Y..^Y]• ~_~_~ ::..., .. ... ~ -.:

~ .. ..._..:..:.-._...T...... ~ _ i. __.. r.-.. . .. .::....

~ !
.. .1 n:. ... 

### .. . . ...c. .. . .._.._... .~ _.. ...:..... 

### _... _.... ..:

~ 

### -_:.:

._... ..... .. ~ 

# ........ .... ...:

_• ._.. -: 4 _

~ .. •

~ :... ._._...,._..........., 

### .....

.......... 

### _ .. . 

### .-.:_:::..::.. 

# - - - Y:_+-- ~ _~ n x_

_ 

### ,k

~ 

### _:-,` c

~ , 

### :_: I

~ 

### i.=..' '

- _ '~ ::'.. ... i. ..:

- Y - _ _ - -


### _ __ ._•'r

~ 

### _,''

~ 

### " 

# - - -

_ - _ -


### __ ,_ .:[ . ..... . .,..

. __~. ~ -1k ..

... .::.....:..'.:_....: ;i-:-.::..ra.._

~ i::_c .F...

. ._ ~ : ::...... . .. .:.::.

~ ..:.'..:::'.'^' . . . ..::

~ ..:i...... •: - ~ _'

~ ::_

~ _f'.:.

~ :•;_yi::
_ ~~~ ..

...: -• ~ 1 : t : 

### __ •~`~~ ..• - 

# Q °, •'
_ p , ~ +- ft ~ , M1 :':f - ~~ 1 • ~ i A*~ ~ y ~^ 4 'f ~. ~ .
w~ • v, ~ ' 

# _ . .: - ~ K3 1 

# : ' u .' • ' R ~rF~~ :~± ' 

### n -

_ +1•

~~ - 

### . _ - r 

# _ ..•..--,, '+{

~

~ •~ y U ~ ~

~ v •~ 

# ..y-

~ 

# .. ~::. y

~ ~ ~ ~ 

### Q ° ,a"~ '~ ~„~ •a cd y ~ 1

~ 

# o ~ ^ - ~

~

~ kn 

# a

~

a~~

## C. Using Tabtes 6A #hrough 6D, please pravide design and operating data for each APCD

associated with atl dryers, kins, and any other brick and structural clay products manu£acturing source that may emit HAP's. Use Tables 6A to 6C for speciflc types of APCD's. Use Tabie 6D for other iypes of APCD's. When using Table 61), pkase specify the type of controi device and 2 to 4 key design or operating parameters for tlte device. Provide data in the wtits listed for each row. Yf the information requested in Tables 6A through 6D is contained in your facility's operating permit, you my reference the applicable sections ofthe perinit rather than Ming out the ta.bles.

Page 20 of 28 

# a le

# ~ dD ~ 

# m 0

~

~ U w

~ A

~
~

~

~ U

.~.

~ O
~ N C

~

~
.~

~

. 1..1 ~ Q ~

~ O 00 N

~ O

~ N
~ c~ 

## a - -- I 

### --- ----- -

~ 

### - -- -- - - -------- -- - --_

~ 

### __----- ---- ----- -- -

~
I •~ ~ i

.,

~ ~

~

~ 

### I I

~ 

## I

I

~ I I

~ I .1
~ 

# •;
~ I ~ I ; 

## i 

# • i

~ . ~

-_ ~ 

# .--. _ 't = -i. ✓

~ ~; ~.~~~y~ ~ ~ 

# ;U""

~



# F ?

~~ .~:° f

~ r o ~ c

. ~ `~ -'4~~ 

# _ ,i

~ FiTi° .s $

` ~"~~r' ~ F

~ . ~

~ ? ~ e ~
~ ~ ~ i

~ '''- I ~ ~ g '" ~ '° ~ -~ '~~ 8 R ~ g ~ . ^F'.;. ~ ~~

~-~~, t . ~£ d ~
~ ~ —~'` ~"

~ ~ ;~ ~ ~~• ~~ `'~ $.."`' ~ '

✓ ~ { 

## ~~ ,., ti ~ i 

## ~ ~_

~ 'T^. 'i •• 3 ~ >. ~ d.-

_ f

~ . " 4-y. '}w ~ ' ~. d~~ 4 ,• i i i

~ I ~

•■ •' ~ 1 .1 i I ~ _ ~ 

# I • -1 1 ,1 - 1 I I •• I

~ / /c ~ ~ ~ ~ a~ r
~

~ .

~ ~ 

### a a~ ~
~ 0

y
~ a ~1

~ ' ~
~ ' U C 7

~ n u ~ a u

~ n u 3 S u . y

.~ : 5 0

~

# ; w00 N 4- O N N N bA cd C~ r

~~ bCA
~ W
~ ~ ~ CL~ t.i U. 00 N 4-i O M N
~ bA c~ 

## a

~ U

~ +..i
~ O ~

~ cd ❑ O U y

~ cd a~ N

~ a-~ Q 'G U Ld rn ~ ~ O R • ~ ~ cC y
w ~ O O

• y o0 4.w

v~o~ ~~

W U

~

~ W

~ a 0 

## x H 0 

### U

~

~ H O Q
~ W

~ c

~ v

~ ~

~
~ ~ ~ ~ 

### .~
~ ss.

~
~ ~ 

# w 0
~ ❑ 0 .~ U N ti N
~ ca U (],

~ . CC N .L +.+ N U C N 

# w

~ C c O C ~ 0 ~ 00



### N ~ 4-i

~ O b0 N Q ~

0 ~
~ U W F, 7

~ + C 'O N C .a [C C O U = .~

~ ~ .~ ~ ~ ~

~ ~ ai 

# o ~ c~ ~

~ 

## Y 0 c o

. w .r IL". N ~ C~ U .~ Q O 

# z 0

a, ¢ o 

## z A ~ 

# a

r'i d' vi

a~~.

### D. Using Table 7, please provide the foflowing information on current monitoring

procedures for each of the control devices listed in Tables 6A to 61): parameters monitored (e.g., baghouse pressure drop), monitoring frsquency, monitoting devices used (e.g., differential pressure trausducer, thermocouple), and necordkeeping practices (e.g., nianually recorded in log book, continuously recorded by electronie d$ta acquisition system). Describe briefly other operation and maiurtenance (O&IV) procedures for each control device. If the information requested in the table is cotrtained in your facility's operating permit, you may referenee the applicable sections of tbe permit rather than filling out the table. VII. Pollution Prevention Pragtices for Brick and Structural Clay Products ManufacturingA. Please describe all pollution prevention practices (i.e., process rnodifications, such as reuse of discarded or rejected materials, or any practice that prevents or reduves the amount of air emissions, or the generation and release of solid waste or wastewater associated with the operation of air pollution controls). If the infortnation rec}uested here is contained in your facili#y's operating permit, you may reference the applicable sections of the permit rather than providing the ittfprmation below. This fac' I) recycles waste heat from the kiln to heat the d=s and to a ksset degree, xhe holding room; 2) recycles floor swgepings and sarap/wastB clay into the brick body: 3) recycies green bricic into the brick bodY: 4) r

~ 

### ecYeles waste slurry into the brick body: 5) receySIQ offspec brick (,grog) into the brick body; 6) reeycles sand coating into the briock body 7) recy,cles wash w.ater into the brick body

Page 25 of 28 

# ,_)

~ 

# ,:;)3VI

~ 

### A U 

# a

~ 

### 0

~

~ ~ 

### 0 w



### ~ 

## w A

~ 

# z 0 U

~ 

### W 

## a

~ ¢ H 

# }i.4•

~ 

# 'af_:

~ 

# i_

_

- - , ~

: :'!

~ i + ~'~.

~ .: :~: . v ' 1 ~i i ~3!~3~ .:^'T ~.~ .. "

• b ~:~ ~ 

# ...:

~ 

# T ..._..' _

_ 1 # O 7 ~

i . ~.



# _ _.-

~~ . ~ .:.. y.. . c 3 ti.: S:_L .G ~ =:'. ~

.~al~°~:~ -

_ ~ y -.' ~ ,•.:... c: :.: ~ . - ~ ~ ~ 

### •:_

~ l



### i! :' ti_ '

.~i

- 

### fi::i'r {{:

~ . : = i~ 

### -.,_

~ 

# 5'• -:f! .: ':

~ 

# .N K ..r.h-=

~~ i~~• i:r~ -•~~' i:.: ~ :..

• ~ o~`,~~~.-.~r'

'~'~1 '•~ -• _

a "~~',~~

_ ~ 

### - ni

~ 

### Y}

~ 

### ;T ;

~ 

### .•• ::,

. rrp ~ ..".

'. ~ s

_ - _ '
-

"'- i: - ? , H T 4 ~ • 7

•~ ~_~~~ p ~~~ ~ A ~

- ~ 

### ..i r :

~ 

### :.
_

E



### o~ w

a~ 'ev

61 x r .. .. ~ •~
_ _ 

# A 00 N ~ W N

~ ce3 

# a

### VIII. Information on Processes Ot 

### 4: : Than Brick and Structural Clay Products Manufacturing

Processes 

### A. Using Table 8, 

### please ide:;tify all other processes or operations at this facility that are not addressed in Items II through VII above and that are potential sources of HAP emissions. Estimate total annual emissions of each HAP emitted by these collocated processes. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table. Mining in support of brick manufacturinQ (Brick SIC Code: 3251) See Table 8

Page 27 of 28

### TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER S 

### Oi TRC'F IR



### Process/emission source/SIC Code(s) HAP's emitted Estimated annual emissions, tons 

## EXAMPLEc: 

## Mining SIC 

## trace metals (Cr, 

## Mn ; 

## Ni conEpounds). _ 

### 0.2

Mining in Support of Brick Manufacturing: Some of the raw materials used by this plant are obtained from an adjacent mine that is owned by Boral Bricks. All material is transported to the facility for processing. No mine data are reported in this ICR because Boral Bricks has no emissions data. 

### SIC 3251 

### No data No data

SIC

SIC If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 28 

### of 28 

# m

# iviaterial 

# batety ata

~ 

# 5hee Substance Identification Identity: MANGANESE DIOXIDE . CAS #: 1313-13-9 Trade Names:

-

~ 

### 'Brickox, GranuSpeck , Manufacturer: The Prince Manufacturing Company Emergenry: Chemtrec One Prince Plaza 1-800-424-9300 

### Quincy, IL 62.

'i01 

### 217-2?2-8854 

# Components and Contaminants Chemical Name CAS # OSHA PBL ACGIH TLV P rc n Manganese Compound (as Mn) 7439-96-5 5 mg/m 3 (C) 5 mg/m 3 (C) 51-55% Mn Iron Oxide 1309-37-1 --- --- 1-5% Fe2O3 Silica, Crystalline Quartz (respirable) 14508-60-7 0.1 mg/m 3 0.1 mg/m 3 (TWA) 1-5% Si0 = Aluminum Oxide (non-fibrous) (respirable fractioh) 1344-28-1 5 mg/m 3 15 mg/m 3 (TWA) 1-7% Al 2 0 3 Barium Oxide 1304-28-5 -- --- 0.2-2% Ba0 

# Physical Data Boiling Point: NA Specific Gravity (H = O =1): 5.0 Vapor Pressure (mm/Hg): NA Melting Point: (Decomposes) 535° C Vapor Density (Air=1): NA Evaporation Rate (Butyl Acetate =1): NA Solubility in Water: insoluble Appearance and Odor: black to browaish black, no odor 

## Fire and Explosion Hazard Data Flash Point: Not combustible Flammable Limits: LEL NA UEL NA Extinguishing Media: Foam, CO 2 , or dry chemical. Special Fire Fighting Procedures: In the event of fire, wear full protective clothing and MOSH-approved selfcontained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Unusual Fire and explosion hazards: Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. Increases the flammability of any combustible substance. 

# Reactivity Data Stability: Stable under ordinary conditions of use aad storage. Conditions to avoid: Do not heat or grind in the presence of easily oxidizable substances or organic matter. Incompatibility (materials to avoid): Easily oxidizable substances, sulfur, sulfides, phosphides, hydrophospliides, chlorates, peroxides, aluminum powder, rubidium acetylide, potassium a7ide, chlorine tritluoride. Reacts with hydrochloric acid to form corrosive chlorine gas. Hazardous Decomposition or Byproducts: Upon heating it decomposes to form manganese sesquioxide and oxygen which facilitates combustion. Hazardous Polymerization: Will not occur.

Manganese Dio)dde, Page : Reviewed October 1994 Unchanged since July 1991


### ~Z'~Z~7~ 

## Health Hazard Data

Route of Entry: INHALATION: May irritate the respiratory tract. May increase the incidL:nc;: of upper respiratory infections (pneumonia). Prolonged exposure to silica du,t may result in silicosis, a fibrotic lung disease. SKIN: May cause irritation. 1NGESTION: May cause abdominal pain and nausea. Manganese dioxid;2 dust is poorly absorbed through the gut. ' 

### Hcalth Hazards (Acute and Chronic): Chronic exposure and inhalation of excessive manganese dust may cause disorders of the central nervous system. Carcinogenicity: NTP: No IARC Monographs: Yes (Siliea) Signs and Symptoms of Exposure: Early symptoms of manganese toxicity include sluggishness, sleepiness, and weakness in legs. Symptoms of silicosis include impaired pulmonary function and wheezing. Aggravation of Pre-existing Conditions: Persons with impaired respiratory function may be more susceptible to the ef

### fect of this substance. Emergency and First Aid Procedures: IF INHALED, remove to fresh air and seek medical attention for any breathin_ difficulty. -IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. IN CASE OF EYE CONTACT, flush eyes immediately with water for at least 15 minutes. Seek medical attention if irritation persists. IF INGESTED, induce vomiting immediately by giving two glasses of waterand sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. 

## Precautions for Safe Handling and Use Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel require respirator} protection. Recover uncontaminated material for use. Vacuum or sweep remaining material, keeping dust to a minimum. Isolate wet material from drv and store away from combustible materials. Waste Disposal Method: Dispose of unreclaimable material in a RCRA-approved waste facility. Handling and Storing Precautions: Manganese dioxide is classified as an oxidizer and should be stored in a dr
. , place away from combustibles and sources of high heat. Protect containers from damage and keep closed when not in use. Other Precautions: Observe good personal hygiene. Wash after handling. 

# Control Measures Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or isanticipated. USBM approved schedule 21B respirator or equal is recommended. Ventilation: A system of local and / or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Indust-rial Ventilation, A Manual of Recommended Practices", most recent edition, for details. Protective Gloves: Yes Eye Protection: Safety goggles are recommended. Other Protective Clothing or Equipment: Use other protective equipment when necessary in order to avoid prolonged exposure to skin. Work and Hygienic Practices: Observe good personal hygiene. Wash after handling.



## SARA Title III Section 313 Supplier Notification This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emereency Planning and Community Right-to Know Act of 1986 and of 40 CFR 372.45: Component CAS # % by Weieht 

### Manganese Dioxide 1313-13-9 51- 55% Mn Barium Oxide 1304-28-5 0.1-1.8% Ba This information must be included in all MSDS's that are copied and distributed for this material. Manganese Dioxide, Page 2 Reviewed October 1994 Unchanged since Jul,v 1991



# mi~ 'da-_RIaL 3A=°_77 DaTA 

### SODI ONATE + 

# m c 

# m DA VERSION PRINTED FOR ............... 497 -19 -8 EFFECTIVE: 02/03/94 

## DELTA DISTRIBUTORS ATTN: WAYNE WRIGHT 10319 E. 54TH ST. TULSA OK 74146 NTED: 09/07/94



# COPY,

~



### PRODUCTNAME .............: SYNONYMS.................: 

## INFORMATION PROVIDED BY..: 11. CHEMICAL PRODUCT/COMPANY IDENTIFICATION SOD I UM,,,,

~ 

### ARBONA-TE:.

~ 

### -„ANHYIIQ. ti![,'Y- .. ~;~ .. ..,c. ~ ._ .r .:• 

### 50DA SH,_SOIIII

~ M:

~ 

### .CiAR 

### BON ~ ^ NH. DROUS"1 FMC

- `WYOM I G

N CORPORAT I ON ,- 1735 MARKET STREET
~ 

## PHILADELPHIA, PA 19103

~ 

### (800) 253-7632 (800) 424-9300 (303) 595-9048 CALL COLLECT' (307) 875-2580 CALL COLLECT

. 

## 2. COMPOSITION/INFORMATION ON INGREDIENTS 97-19-8 SODIUM CARBONATE 99.8% :. EMERGENCY PHONE NUMBERS CHEMTREC..............: MEDICAL...............: PLANT/OTHER ........... :

CAS # AND COMPONENTS ..... : 

## . HAZARD IDENTIFICATION EMERGENCY OVERVIEW ....... :

HEALTHEFFECTS ........ ...: 

## WHITE GRANULAR SOLID. PRODUCT IS NON-COMBUSTIBLE. REACTS WITH ACIDS TO RELEASE CARBON DIOXIDE AND HEAT. IRRITATING TO THE EYES. CONTINUOUS CONTACT MAY IRRITATE SKIN. DIRECT CONTACT WITH THE PRODUCT CAUSES 

## IRRITATION OF THE EYES AND CONTINUOUS CONTACT MAY CAUSE SKIN IRRITATION (RED, DRY, CRACKED SKIN) . 

## EXCESSIVE LEVELS OF AIRBORNE DUST MAY IRRITATE THE MUCOUS MEMBRANES AND UPPER RESPIRATORY 

## TRACT.

-------- 

## "
---------------- 14. FIRST AID MEASURES EYES ............. ........: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES, LIFTING THE UPPER AND LOWER LIDS OCCASIONALLY. SEE A MEDICAL DOCTOR IMMEDIATELY. SKIN .....................: WASH WITH PLENTY OF WATER FOR 15 MINUTES. IF IRRITATION OCCURS AND PERSISTS, OBTAIN MEDICAL ATTENTION. INHALATION ...............: REMOVE FROM EXPOSURE. IF DISCOMFORT OCCURS AND PERSISTS, OBTAIN MEDICAL ATTENTION. INGESTION ................: RINSE MOUTH WITH WATER. DILUTE BY GIVING 1 OR 2 GLASSES OF WATER. DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. SEE A MEDICAL DOCTOR IMMEDIATELY. NOTES TO PHYSICIAN ....... : WHILE INTERNAL TOXICITY IS LOW, IRRITANT EFFECTS OF HIGH CONCENTRATIONS MAY PRODUCE (CONTINUED) PAGE 01 

## ~ -SI"'-=--' J AT " SOD I UM CARBONATE 

## 497 -19 -8 U.S./CANADA VERSION EFFECTIVE: 02/03/94 PRINTED: 09/07/94 4. FIRST AID MEASURES ------------- ORNEAL OPACITIES AND VESICULAR SKIN EACTIONS IN HUMANS WITH ABRADED SKIN ONLY. REATMENT IS SYMPTOMATIC AND SUPPORTIVE. -------------------- 15. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA ...... : SPECIAL FIREFIGHTING ..... : PROCEDURES DEGREE OF FIRE AND ....... : EXPLOSION HAZARD HAZARDOUS DECOMPOSITION..: PRODUCTS 'WATER, WATER,FOG, CARBON DIOXIDE (CO2), RY CHEMICAL. WEAR FULL PROTECTIVE CLOTHING AND SELF CONTAINED BREATHING APPARATUS. NOT APPLICABLE. EATED TO DECOMPOSITION, IT EMITS FUMES OF SODIUM OXIDE.

~ 

## 6. ACCIDENTAL RELEASE MEASURES PROCEDURE FOR RELEASE....: WEEP UP AND RECYCLE INTO PROCESS IF OR SPILL CONTAMINATION DOES NOT PRESENT A PROBLEM. USE PPROPRIATE PROTECTIVE EQUIPMENT IF DUST IS GENERATED DR CONTACT WITH EYES OR SKIN IS XPECTED. FLUSH RESIDUES AND LIQUID TD HOLDING REA FOR NEUTRALIZATION BEFORE DISCHARGE. HANDLING AND STORAGE _----------__----__---- HANDLING ................. SE AIR CONVEYING/MECHANICAL SYSTEMS FOR BULK RANSFER TO STORAGE. FDR MANUAL HANDLING OF BULK RANSFER USE MECHANICAL VENTILATION TO REMOVE IRBORNE DUST FROM RAILCAR, SHIP OR TRUCK. USE PPROVED RESPIRATORY PROTECTION WHEN VENTILATION YSTEMS ARE NOT AVAILABLE. SELECTION OF ESPIRATORS IS BASED ON THE DUST CLOUD ENERATED. VENTILATION ..............: RDVIDE GENERAL MECHANICAL AND/OR LOCAL EXHAUST ENTILATION TO PREVENT RELEASE OF AIRBORNE DUST INTO THE WORK ENVIRONMENT. APPROVED RESPIRATDRY RDTECTION SHOULD BE USED WHEN AIRBORNE DUST IS EXPECTED TO BE RELEASED. STORAGE ..................: TORE IN A COOL DRY AREA, AWAY FROM ACIDS. 18. EXPOSURE CONTROLS/PERSONAL PROTECTION ====== CONTROL MEASURES.........: INIMIZE EYE AND SKIN CONTACT BY USING PPROPRIATE PROTECTIVE EQUIPMENT. USE LOCAL OR ENERAL ROOM VENTILATION TO CONTROL AIRBORNE UST THAT MAY BE GENERATED INTO THE WORK NVIRONMENT. RECOMMENDED PERSONAL (CONTINUED) PAGE 02

## USE APPROVED DUST RESPIRATORS FOR LOW LEVELS OF AIRBORNE DUST. HIGH CONCENTRATIONS MAY REQUIRE AIR SUPPLIED SYSTEMS. USE CUP TYPE. CHEMICAL GOGGLES. 

## USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT. ARM PROTECTORS AND APRONS. IF CLOTHING BECOMES CONTAMINATED REMOVE AND LAUNDER BEFORE REUSE. INDUSTRIAL SAFETY SHOES. . PHYSICAL AND CHEMICAL PROPERTIES 1 DEGREES C(13b4 DEGREES F) COMPOSES 

## T APPLICABLE T APPLICABLE ITE. SOLID GRANULAR DORLESS .509 3.2 MAXIMUM. 

## DT APPLICABLE DT APPLICABLE NOT APPLICABLE 11.4 

## NOT APPLICABLE DENSE GRADES,0.86-1.121 NOT APPLICABLE ONCOMBUSTIBLE OT APPLICABLE OT APPLICABLE OT APPLICABLE 

## OT APPLICABLE OT APPLICABLE OT AVAILABLE LIGHT GRADES.0.70-0.90 

### SODIUM CARBONATE 497 —19 —8 EFFECTIVE: 02/03/94 PRINTED: 09/07/9 . EXPOSURE CONTROLS/PERSONAL PROTECTION ====== 

## PROTECTIVE EQUIPMENT RESPIRATORY........:


## EYES ...............: 

## GLOVES .............: 

## SPECIAL CLOTHING...: AND EQUIPMENT FOOTWEAR ...........:
MELTING/FREEZING POINT...: 

### BOILING 

## POINT .... ........s VAPOR PRESSURE ........... : 

## VAPOR DENSITY (AIR=1) .... : ROOM TEMPERATURE ......... : APPEARANCE AND STATE 

## ODOR .....................: 

## SPECIFIC GRAVITY (H2O=1).: SOLUBILITY IN H20 y BY WT: % VOLATILES ..............: EVAPORATION RATE.........: (BUTYL ACETATE=1) PH(AS IS) ...............a PH (lY. SOLUTION).........: 

### ODOR THRESHOLD .......... .: DENSITY (G/ML)...........: 

## PARTITIDN COEFFICIENT....: N—OCTANOL/WATER 

### FLASH POINT ..............: AUTOIGNITION TEMPERATURE.s 

## FLAMMABLE LIMITS UPPER..: (AIR) LOWER..: EXPLOSIVE PROPERTIES.....: 

## OXIDIZING PROPERTIES.....: SOLUBILITY ...............: 

## — FAT SOLUBILITY (SOLVENT — OIL)



## -------------------------- ~ 

## 10. STABILITY AND REACTIVITY --------------------- 

## STABILITY................a STABLE HAZARDOUS POLYMERIZATION.: WILL NOT OCCUR CONDITIONS TO AVOID ...... : CONTACT WITH ACIDS EXCEPT UNDER CONTROLLED CONDITIONS. MATERIALS TO AVOID ....... : ALUMINUM POWDER. ACIDS, FLUORINE, MOLTEN LITHIUM. MAJOR CONTAMINANTS THAT..: (CONTINUED) PAGE 03

### ,.. _. ,. _ 3.4=_ 77 :;.. 7 .. SODIUM CARBONATE ~ 

### —19 — U.S./CANADA VERS 

## EFFECTIVE: 02/03/94 PRI NTED: 09/07/94



## ----------- 10. STABILITY AND REACTIVITY CONTRIBUTE TO INSTABILITY NONE INCOMPATIBILITY...........: REACTS WITH ACIDS WITH RELEASE OF LARGE VOLUMES OF CARBON DIOXIDE GAS AND HEAT. HAZARDOUS DECOMPOSITION..: NONE PRODUCTS SENSITIVITY TO MECH......: INONE IMPACT SENSITIVITY TO STATIC .... s NONE DISCHARGE 111. TOXICOLOGICAL INFORMATION -- ------ EYECONTACT ..............: SKIN CONTACT .............:

SKIN ABSORPTION........... INHALATION...............: INGESTION................: ACUTE EFFECTS FROM ....... : OVEREXPOSURE
CHRONIC EFFECTS FROM.....: OVEREXPOSURE (EFFECTS CONSIDERED INCLUDE: SENSITIVITIES, CARCINOGENICITY, TERATOGENICITY. MUTAGENICITY. SYNERGISTIC . PRODUCTS. AND ANY MEDICAL CONDITIONS GENERALLY RECOGNIZED AS BEING AGGRAVATED BY EXPOSURE.) 3EVERE IRRITANT (RABBIT) rOXICOLOGY 23:281-291 (1982) VON—IRRITATING TO INTACT SKIN. MINOR IRRITATION MAY OCCUR ON ABRADED SKIN. VON—SENSITIZING (GUINEA PIG) rOXICOL. APPL. PHARMACOL. 31:481-490 (1975) VO DATA AVAILABLE. _C50 = 2.3 MG/L (RAT,2 HR.) ENVIRON 3ES 31:138 (1983). _D50 = 4090 MGlKG (RAT) (RTECS 1985-6). MAY CAUSE SEVERE IRRITATION OF THE EYES. [NCLUDING CORNEAL OPACITIES. DUSTS AND MISTS 4RE IRRITATING TO THE SKIN. MUCOUS MEMBRANES 4ND UPPER RESPIRATORY TRACT. MAY CAUSE INFLAMMATION OF THE MUCOUS MEMBRANES IN THE RESPIRATORY TRACT AND OF THE SKIN.

ECOLOGICAL INFORMATION ENVIRONMENTAL FATE ....... : BIODEGRADABILITY DOES NOT APPLY TO INORGANIC UBSTANCES. NO OTHER DATA AVAILABLE. ENVIRONMENTAL EFFECTS .... : 96 HR. LC50 (DAPHNIA MAGNA) a 265-565 MG/L. 6 HR. LC50 (BLUEGILL SUNFISH) = 300-320 MG/L.
( CONT I NUED ) PAGE 04A3•

### SODIUM CARBONATE 

### 497 -19 -8 

## NA DA VERSION 

## PRINT : 09/07/94 

## DISPOSAL CONSIDERATIONS =___-----_-_-_--_-- WASTE DISPOSAL METHOD .... : SALVAGE AS MUCH MATERIAL AS POSSIBLE AND RETURN TO PROCESS IF CONTAMINATION DOES NOT PRESENT A PROBLEM. DISPOSE IN AN APPROVED LANDFILL IN ACCORDANCE WITH ACCEPTED GOVERNMENTAL REGULATIONS. 

## ------------"--------=====114. TRANSPORT INFORMATION --------------- 

## DOT PROPER SHIPPING NAME.: IATA .....................: 

### IMDG
....... ................ 

## DOT CLASSIFICATION.......: DOT LABELS ...............: 

### DOT MARKING ..............: 

### DOT PLACARD ..............: 

### UN NUMBER ................: 

## HAZARDOUS SUBSTANCE/RQ ... : 49 STCC NUMBER ........... : 

## PRECAUTIONS TO BE TAKEN..: IN TRANSPORTATION OTHER SHIPPING...........: 

## INFORMATION SODIUM CARBONATE NOT APPLICABLE NOT APPLICABLE NON HAZARDOUS NOT APPLICABLE 

## NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE BWEEP UP, RETURN TO CONTAINER AND MARK AS WASTE FOR DISPOSAL. 50DIUM CARBONATE IS GENERALY REGARDED AS SAFE, (GRAS) WHEN USED WITH CURRENT GOOD INANUFACTURING PRACTICES.

-------------- 

## "
----------- I15. REGULATORY INFORMATION -------------------------- OSHA EXPOSURE LIMITS SUBSTANCE(S) ........... : OSHA PEL—TWA .......... : STEL 

## .... ... ... ...s CEILING. ..... ....s SKIN DESIGNATION.: ACGIH TLV—TWA .......... : STEL 

## ..... . ....... : CEILING...... .... : SKIN DESIGNATION.: TARGET ORGAN EFFECTS ..... : CARCINOGENIC POTENTIAL ... : REGULATED BY OSHA ...... : LISTED ON NTP REPORT ... : IARC GROUP 1, 2A, 2B...: U.S. EPA REQUIREMENTS RELEASE REPORTING CERCLA (40 CFR 302) LISTED SUBSTANCE(S)....: RQ

............... CATEGORY.........: RCRA WASTE NO....: 

## SODIUM CARBONATE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE EYE NO NO NO



## NOT LISTED NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE o ! 

### ~ , 33 

## (CONTINUED) PAGE 05

### SODIUM CARBONATE 

# P i 

### l I = 497 —19 — .S./CANADA V EFFECTIVE: 02/03/9 PRINTED 

### : 09/07/9 -------------------------= 115. REGULATORY INFORMATION =____-----_--_------ 

### UNLISTED SUBSTANCE(S)..:

RQ


### ............... CHARACTERISTIC...s RCRA WASTE NO .... : 

### SARA TITLE III SEC 313 (40 CFR 372) ........... : 

### LISTED TOXIC CHEMICAL..; INVENTORY REPORTING 

### SARA TITLE III SEC 311/312 (40 CFR 370) SUBSTANCE(S)...........a HAZARD CATEGORY ........ : PLANNING THRESHOLD ..... a EMERGENCY PLANNING 

### SARA TITLE III SEC 302-303 (40 CFR 355) 

### LISTED SUBSTANCE(S)....: a 

### .....................• 

### PLANNING THRESHOLD.....: U.S. TSCA STATUS.........: 

### CANADA 

## INGREDIENT DISCLOSURE LIST SUBSTANCE(S) ........... : CONTROLLED PRODUCT ....... : H 

## AZARD SYMBOLS ........... : CLASS & DIVISION ....... : PRODUCT IDENTIFICATION N0: DOMESTIC SUBSTANCE LIST..: CEPA PRIORITY LIST ....... : CARCINOGENICITY ACGIH APPENDIX A ....... : A1 — CONFIRMED HUMAN...a A1 — SUSPECTED HUMAN...: IARC GROUP 1 OR 2 ........ : LABEL LANGUAGE (US/CANADA) HEALTH.................:
PHYSICAL...............: HANDLING AND STORAGE...: FIRST 

## AID ..............:

STATE REGULATIONS ........ : OT APPLICABLE OT APPLICABLE OT APPLICABLE OT APPLICABLE
T LISTED

SODIUM CARBONATE IMMEDIATE (ACUTE) HEALTH HAZARD (IRRITANT) 10,000 POUNDS

OT APPLICABLE OT APPLICABLE OT APPLICABLE ISTED
ODIUM CARBONATE ES OXIC LASS D. DIVISION 21 SUBDIVISION B. OT APPLICABLE ISTED OT LISTED T LISTED T LISTED T LISTED
UST MAY CAUSE SEVERE IRRITATION OF EYES AND LIGHT IRRITATION OF NOSE AND THROAT. REPEATED ONTACT MAY CAUSE REDNESS AND DRYs CRACKED SKIN. OT APPLICABLE 0 NOT STORE CLOSE TO ACIDS. WEAR EYE ROTECTION AND APPROVED DUST RESPIRATOR WHEN XCESSIVE DUST IS PRESENT. N CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH ATER FOR AT LEAST iS MINUTES. IF IRRITATION ERSISTS. OBTAIN MEDICAL ATTENTION. FLUSH SKIN ITH WATER. ALIFORNIA PROPOSITION 65: SAFE WATER AND TOXIC NFORCEMENT ACT OF 1986, THE FOLLOWING CHEMICALS AVE BEEN DETECTED. (CONTINUED) PAGE O6 

# ~+4ATEA1AL .> SODIUM CARBONATE 

## 497 -19 -

-- -------------- =115. REGULATORY INFORMATION ARSENIC,PPM AS AS203 = 0.03 TOTAL CHROMIUM,PPM CR = 0.03 LEAD,PPM PB ..... ..... _ <1 CADMIUM,PPM CD....... _ <0.1 ALL OTHER LISTED CHEMICALS ARE NOT DETECTED OR NOT SUSPECTED TO BE PRESENT. , 16. OTHER INFORMATION PRODUCT USES .............: GLASS MANUFACTURE, DETERGENT MANUFACTURE, SODIUM CHEMICALS AND CARBONATE CHEMICALS MANUFACTURE, PULP AND PAPER, BRINE TREATMENT, WATER HARDNESS REMOVAL, PH ADJUSTMENT IN WATER OR WASTE WATER, FLUE GAS DESULFURIZATION, COAL TREATMENT, ION EXCHANGE RESIN REGENERATION. NFPA 704 HEALTH..............: FLAMMABILITY ........ : REACTIVITY.......... : SPECIAL HAZARD ...... : (DEGREE OF HAZARD 0 = NO HAZARD 4 = SEVERE HAZARD)
as=sos=asss=sasss=a=ssss=scsa=as=sc==ssaoao==s 

## THE CONTENTS AND FORMAT OF THIS MSDS ARE IN ACCORDANCE WITH OSHA HAZARD COMMUNICATION AND CANADA'S WORKPLACE HAZARDOUS MATERIAL INFORMATION SYSTEM (WHMIS).

~ 

## J 7 PAGE 0703/06/98 08:23 17217 222 8854 PRINCE Lab 

### Q 002 

# Material Safety Data Sheet Substance Identification 

### Merifih/: SYNiHET1C RED IRON OXiDE Cas # : 1309-37-1 Trade Names: 

# '1 7

' 56 e ~ 

# F 6 ~ Manufacturer: The Prince Manufacturing Co. Emergency: Chemtrec

One Prince Plaza 1-800-424-9300 Quincy, IL 62301 217-222-8854 

### Components and Contaminants Chemical Name: CAg:R Q3HA PEL ACGIH TLV Percerrt Iron Oxide 1309-37-1 -- — 80-95% Fe 2 0 3 Par6cle.s not otherwise Regulated

_ Total 15 mg/m' 15 mg1m 3 (TWA) Respirable Fraction 5 mg/m' 5 m4/m 3 (i'WA) 

### Physical Data Boiting Point NA speciFc Gravity (H2 0 -'): 4.8-5.3 Vapor Pg ure (mm/Hg): NA Melting Poiint: > 1700° C 

### Vapor Density (Air=1): NA Evaporation RatU (But)ti Aaetate-l): NA Solubitity in Water. insoluble 

### Appearance and Odor: red to reddish-brown powder, no odor. 

### Fire and Explosion Hazard Data Fiash Point: Not combustible Fiammable Limits: LEL NA UEL NA 

### ExHnguishing Media: Foam, CO 2 , dry chemicaf or water. Speclal Fire Fighting Procedunes: In the event of 6re, wear fuN pmtec6ve clothing and NIOSH-appnoved self-contained bnaathing apparatus with full face piece operabed in the pressur+e demand or other posi6ve fxessure mode. 

### Unusuai Fire and expiosion hazards: Not combustible. 

### Reactivity Data Stability: Stable under ordinary conditions of use and storage. Conditbns to avoid: None Knawn. 

### lncompatfbility (maberlals to avoid): Aluminum, Ethylene Oxide, Hydrazine, Caidum Hypoctdorite, Perlormic Acid, 13romine PentaRouride. Hazardous Decomposidon or Byproducts: None Known. Hazardous Poflm

~ erizaUon: Wili not occur. 

### Health Hazard Data Route of Entry: MiHALATION: May cause irrittation of mucous membrane if dust is inhaled over a prolonged period of time. SK1N: No. INGESTI!ON: Ingestion of mineral compounds may cause abdominal 

### pain and nausea.

Synthetic Red Iron Oxide, Page 1 Revbwad J* 1996 Unahartged since June 1991 PW-06-1998 08:34 217 222 8E354 95% P' 02 

### ~ 3~~03/06/98 08:23 '0217 222 8854 PRINCE Lab Q 003



### Health Hazard Data (cont.) Heatth Hazards (Acute and Chronic): Can cause eye irritation. Injury to skin may occur by direct mechanical action. Carcinogenicity: NTP: No IARC Monographs: No Signs and Symptoms of Exposure: Excessive inhalation of dust may result in shortness of breath and reduced pulmonary function. Iron oxide fum has been linked to siderosis which is considered to be a benign pneumoconiosis that exhibits no adverse health effects. To the best of our knowledge, this condition has not been observed after prolonged exposure to iron oxide pigments. Aggravation of Pre-existing Conditions: None Known. Emergency and First Aid Procedures: IF INHALED, remove to fresh air and seek medical attention for any breathing difflcully. IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical attention if ned S irritated. 

### IN CASE OF EYE CONTACT, flush eyes immediately with water for at least 15 minutes. Seek medical attention if irritation pensists. IF INGESTED, induce vomiting immediately by giving two glasses of water and sticking finger down thnoat Never give anything by mouth to an unconscious person. Call a physician immediately. 

## Precautions for 3afe Handting and Use Material Release or Splll Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratary protection. Recwer uncontaminated material for use. Vacuum or sweep remaining material, keeping dust to a minimum. 

### Waste Disposai Method: Dispose of unredaimable material in a RCRArapproved waste facitity. Handling and Storing Precautions: Protect containers from damage and keep closed when not in use. 

### Other Pnmautions: Observe good personal hygiene. Wash after handling. Contro! Nleasures . Respiratory Protection: Use NIOSH approved pardculate respirator if dust generation occurs or is anticipated. OSHA standard 1910.134 or ANSt Z88.2-1980 specifications are recommended. Ventilation: A system of kwal and/or general exhaust is recommended to keep employee exposures below the Airbome Exposure Limits. Local exhaust is generalgr preferr+ed because R can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industr'ra! Ventilation, A Manual of Recommended Practices", most recent edition, for details. Protective Gloves: Yes Eye Pr+otection: Safety goggles are recommended. 

### Other Protective Clothing or Equipment: Use other protective equipment when necessary in order to avoid probnged exposurre to skin. 

### Work and Hygienic Praatices: Observe good personal hygiene. Wash after handling. SARA Title Ili Section 313 Supplier Notiflcation This product does 1g# contain chemicals subject to the reporting re 

### and Community Right to-Know Act of 1966 and of 40 CFR 372.45: This information must be included in all MSDS's that are copied and distribubed far this material.

syntlmtic Red Iron Oxdd0. Page 2 Reviewed July 1996 Unchanged since June 1991 MAR-06-1998 08:34 217 222 8854 95% P.03


### ,~ 

## z 3703/06/98 08:24 '0217 222 8854 PRINCE Lab 

### 9 004 

## Material Safety Data Sheet Subatance Identification )dentity: MANGANESE OXIDE CAS # : 1317-35-7 Trade Names: Brickox, Trimanganese Tetraoxide 

### Manufacturer. The Prince Manufacturing Co. Emergency: Chemtnrc

One Prince Plaza 1-800-424-9300 Qufncy, IL 62301 217-222-8854 

### Components and Contaminants chemlcsI Name: GAS a' o5F1A PEL ACGIH TLV Pen:en Manganese Compound ( as Mn) 7439-96-5 5 mg/m 3 (C) 5 mg/m 3 (C) 68-70% Mn Iron Oxide 1309-37-1 — -- 2-4% Fe 1 0 3 Silica, Crystalline Quartz (respirable) 14808-60-7 0.1 mg/m' 0.1 mg/m 3 ('TWA) 0.5-1 % SiO Z Aluminum Oxide (nonfibrous) (respirable fraction) 1344-28-1 5 mg/m' 5 mg/m 3 (TWA) 1-2% AI 2 0, Magnesium Oxide (respirabie) 1309-484 5 mg/m 3 5 mg/m' (TWA) 1-2% Mg0 

### Physicai Data Boiling Point: NA Specific Gravity (14 2 0=1): 4.8 

### Vapor Pressure (mnft): NA Melting Point: 1564° C Vapor Density (Air-1): NA Evaporstton Rate (Butyl Acetateal): NA Soiubility in Water. insoluble 

### Appearance and Odor. brvHm tD broamish bladc. no odor Fire and Explosion Hazard Data Flash Point: Not combustibfe 

### Flammable Llmits: LEL NA UEL NA Extinguishing Media: tJse exdnguishing media appropriate for surrounding fire. Special Fire Fighting Procedures: In the event of fine, wem fuN protiective dothing and NIOSH-approved self-contained breathing apparatus with full face piece oper°ated in the pressure demand or other positive pressure mode. 

### Unusual Fire and explosion hazards: Not combustible, but substance is an oxidizer and its heat of n:action with reducing agents or combustibles may cause ignition. Increases the flammabiliiy of any combusU'bie substance. 

### Reactivity Data Stabiiity: Stabie under ordinary conditions of use and storage. 

### Conditlons to avoid: Do not heat or grind in the presence of easiiy oxdizab(e substances or organic matter. 

### Incompadbility (materlals Eo avold): Easily oxid'¢able substances, suiiur, sulfides, phosphides, hydrophosphides, chlorates, peroxides, aluminum powder, rubidium acetyNde, potassium azide, chlorine trifluoride. Reads with 

### hydrochloric add to forTn corrosive chlorine gas. Hazardous Decomposltbn or Byproducb: None icnamrn. Hazardous Polymerization: Will not occur. 

### Health Hazard Data Route of Entry: INHALATION: May irritate the respiratory tracf. May increase the incidence of upper respiratory infeclions (pneumonia). Prolonged 

### exposure to silica dust may resutt in silicosis, a fibrotic lung disease. SKIN: May cause irritation. 

### INGESTION: May cause abdominal pain and nauses. Manganese dioxide dust is poorly absorbed thnwgh the gut.

Mangama Oxide. >ap I september 1997 MAf2-06-1998 08:35 217 222 8854 94% P.04



# ~03i06i98 08:25 0217 222 8854 PRINCE Lab Q005



### Health Haiard Data Healtlt Hazards (Acute and Chronic): Chronic exposure and inhalation of excessive manganese dust may cause disorders of the central nervous system. 

### Carcinogenicity: Signs and Symptoms of Exposure: Aggravation of Pre-existing Conditilons: Emergency and Fin:t Aid Procedures: NTP: No IARC Monographs: Yes (Siiica) 

### Earty symptoms of manganese toxicity include sluggishness, sleepiness, and weakness in legs. Symptoms of silicosis inciude impaired pulmonary function and wheezing. 

### Persons with impaired respiratory function may be more susceptibie to the etfect of this substance. 

### IF INHALED, remove to fresh air and seek medical attention for any breathing diffecutty. IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical attention if red & inftated. iN CASE OF EYE CONTACT, flush eyes immediately with water for at least 15 minutes. Seek medipl attention if irritation persists. 

### IF INGESTED, induce vomiting immediately by giving two glasses of water and sticking 5nger down throat Never give anything by mouth to an unconscious person. Cali a physician immediately. 

### Precautions for Safe Handling and Use iNaterial Release or Should a spill occur, ventilate area. Clean-up personnel nequire respiratory protection. Recover uncontaminated materiai fw use. Vacuum or sweep 

### nemaining material, keeping dust to a minimum. Isolate wet traterial frorn dry and store away from combustibte msterials. 

### Waste Disposal Method: Dispose of unreclaimable material in a RCRA-approved wasbe facility. Handling and Storing Precaudons: Manganese dioxide is dassified as an oxidizer and shouid be stored in a dry place away from combusitibes and sources of high heat. Protect containets ftom damage and keep cbsed when not in use. 

### Other Precautions: Observe good personal hygiene. Wash after handling. Control Measures 

### Respiratory Protection: Use NJOSH appraved padticulate respirator if dust generation occuss or is ant+cipated. OSl-!A standard 1910.134 or ANSI 288.2-1980 specifications are recommended. Yendlation: A system of kxcal and/or general exhaust is necommended to keep 

### employee exposunrs below the Airbome Exposure Limits. Locai exhaust is generaAy preferred because k can control the emissions of the contaminant 

### at its source, preventing dispension of it into the general work area. Please refer to the ACGIH document, "Industrial Ven6(atm, A Manual of 

### Recommended Practices", most recent edition, for details. Protecthre Gloves: Yes Eye Protection: Safety goggles are recommended. 

### Other Protectin e Clothing or Equipnrertt: Use other protective equipment when necessary in order to avoid prolonged exposure to skin_ 

### Work and Hysienic Practices: Obserye good personal hygiene. Wash after hand6ng. 

### SARA Title III Section 313 Supplier Notification This producx contains the foUowing toxic dhemkmis subject to the ne

~ 

### iporting requirements of section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 and of 40 CFR 372.45: Comoonent CAS # 96 bv Weiaht Manganese Oxide 1317-35-7 68-70% Mn This information must be included in all MSDS's that ar+e copied and distributed for this material.

Maogause dxide, Page 2 Scptsmbcr 1997
MAl2-06-1998 08:36 217 222 8854 92% P. 05 

## ~ 3~~ -. at` ~ ••_r -r• _. ~-~ 't - . ' . ~ - ' ~ .r ". • . - ~ . 

# . ~ •. ~ ~ .

- 4 •-Q,..., ~ r- - .r -- = - = .r ~ .: ~ .-.,-. ~ .,- ~ -.



# EPA iVIACT Information Collection

_ 

# ~ Request Response

~ ;

~ ~ 

# ---• ~'~~ '' ~.~ ` L 

# ..

- ~---~~,~~ 

# n -- ~.~ .,~:_ ~ 

# -}

..,,, ~,~ ~ ,, 

# . .., ~ 

# _

~► ~ 

# 4-. - • .

~,~ ~ 

# _ _ _ _ _ -. _ 

# ._.r_
_ ",

~ 

# 'Y:

~ ;► : ., 4 

### `

_ N. 7 :-

~ f

. t

~ 1 •._. ~ , , . .. : , ~-~

r - •~_ . _ _ _ —

_ — _ . .+•`

- i~~_. ~ y~r - .w'+

~ 'iS
~ „ ~~~ - - ~ " ~ - . Y ~ \ y
~ T • . . ~ ` ~ SS.... ~• s~r~r' ~ ..

i 

# Borai t



# I kugusta e_ 3 end

U

1 r

# MACT Information Collection Request Response from Boral Brick,s, Inc.
Table of Contents • Information 'Collection Request • Appendix A - MSDS's • Appendix B - Test Data



# aq(

### Enclosure 2
INFORMATION REQUEST FOR BRICK AND

STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS I. Instructions 

### Please return the completed information request to: Bruce C. Jordan, Director Attn: Bill Neuffer Emission Standards Division (MD-13) U. S. Environmental Protection Agency Office of Air Quality Planning and Standards Research Triangle Park, North Carolina 27711 If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at (919) 541-5435. 

### This information request should be completed for each facility that manufactures brick and structural clay products, including facilities that are not major sources. Information is requested for all processes at your plant that emit hazardous air pollutants (HAP's), including those processes that are not associated with brick and structural clay products manufacturing. Sections II through VII request information specific to brick and structural clay products manufacturing, and Section VIII requests information on emissions of HAP's from other processes located at the facility. Processes that may emit HAP's include those processes that use or handle any materials that contain a HAP compound, all processes with elevated temperatures, and all other processes in which HAP compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is included as Attachment 1 to this information request. Attachment 2 provides background information on the requirements of the Clean Air Act and explains how the information requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations and acronyms used in this information request. Several tables are provided throughout the information request for your convenience in answering the questions. An example response is given (shaded first column or row) in each table. If additional space is needed to respond, please make copies of applicable pages. If necessary, please make copies of this information request for additional facilities. No additional emission testing or monitoring is required to respond to this request. To M
- . I W-M Wil ro_e M1 0

, riT W 

### A. Name of company Boral Bricks. Inc 

### Name of facility Augusta Plants 3& 5


### Page 1 of 39

c~ 

# V-2--

### Facility address: No. and street 1630 Athern Road City Augusta State GA Zip 30901 Latitude and longitude coordinates of plant: Lat. 33° 27' 17" Long. 81° 57' 32" Standard Industrial Classification (SIC) Code(s) of brick and structural clay products manufacturing operations 3251 Dun and Bradstreet No. 003275682 Total No. of employees for company >1,500 for facility 225 (If facility is a foreign subsidiary or if company has foreign subsidiaries, include number of employees not based in the U.S.). Please complete the following shift information for the facility: Shift No. of employees Hours per shift Days per year 1 186 10 252 2 10 10 252 3 5 10 252 B. Respondent name Guiomar Obregon Respondent title Analyst Respondent address (if different from above) and telephone number: No. and street 500 Northridge Road, Suite 300 City Atlanta State GA Zip 30350 Telephone No. (770) 645-4500 Name and telephone number of technical contact person (if different from above) Name David Johnson Telephone No. (334) 480-2487 III. Information on Operating Permits and Applicable Federal Emission Standards A. Please provide copies of relevant parts of all operating permits and permit applications for your facility. Relevant parts include the sections that provide specific information and data on: processes that emit HAP's; the use of HAP- containing Page 2 of 39 

# ,P,43

### specific information and data on: processes that emit HAP's; the use of HAPcontaining substances; emission levels for HAP and surrogate pollutants (i.e., VOC for organic HAP's and PM for metal and other particulate HAP's); emission control device design and operation; monitoring and operation and maintenance (O&M) procedures for control devices; and generation and releases of other media such as wastewater and solid waste that are associated with the operation of air pollution controls for brick and structural clay products manufacturing processes. If the operating permit or application contains the same information requested in any part of this questionnaire, you may respond to the requested information by referencing the page or section of the permit/application to avoid duplication. If you reference your permit or application, you must supplement your response with all of the additional information requested in this questionnaire that is not included in the permit or permit application. If you prefer, you may submit the requested information from your pennit/application on a 3-1/2 inch diskette. B. If any source or emission unit at this facility is subject to a New Source Performance Standard or other Federal emission standard, please identify the source and applicable standard. Examples of applicable NSPS include 40 CFR 60, Subpart 000 - Standards of Performance for Nonmetallic Mfneral Processing Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers fn Mineral lndustries.

:i ,.T• u_ t.., ' .•. ' •• •r@ .oT- ;. 5. v,•• ~ 

### ro

~ 

### • •• 

## I nforination 

### A. Please provide the 1996 production rates and the current production capacity for each type of brick and structural clay product manufactured (e.g., structural brick, clay sewer pipes, structural clay tile, etc.). Note that production data should be provided in units of tons per year (tons/yr). Product 1996 production (tons) Production capacity (tons/yr) Brick (fired weight) 315,600 tons 340,900 ton/yr

Page 3 of 39

;~ `t`ZLi 

### B. Please provide the type and amount of each raw material and body additive used in 1996 for manufacturing brick and structural clay products at your facility. Examples include clays, shale, and any additives that are mixed into the raw material prior to forming. Indicate additives by chemical compound, rather than by trade name. If the information requested is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the information below. Raw material/body additive Amount used in 1996 (tons/yr) Cordova clay (wet weight) 9,700 Albion Kaolin (wet weight) 13,300 Bond Kaolin (wet weight) 9,600 Shale (wet weight) 19,100 Merry clay (wet weight) 354,300 Sawdust (as received) 10,000 Manganese ND Marble dust ND Fines ND

C. If available, please provide a copy of the MSDS's for the raw materials and additives listed above. See Appendix A. D. If available, please provide chemical analyses, including fluorine, metals, and organic content, of the raw materials listed above. Not available.

Page 4 of 39


## a~~

### E. Using Table 1, please provide information on the consumption and HAP composition of all glazes and colorants that contain HAP's or HAP precursors and that your facility applies to brick and structural clay products. Indicate whether the coatings are glazes or colorants. Also indicate the type of product that the coatings are applied to and the total weight of coatings used in 1996. If the glazes or colorants are formulated at your facility indicate so and provide the production capacity. List each ingredient of the glaze or colorant. Beside each ingredient, indicate the total amount of the ingredient used in 1996. If the information requested in the table is contained in your facility's operating permit or permit application, you may reference the applicable sections of the permit (or application) rather than filling out the table. F. In the space below, please indicate any glazes or colorants used by your facility that do not contain HAP's and are substitutes for HAP-containing glazes or colorants used by your industry. Indicate which HAP-containing materials the non-HAP glazes or colorants replace. Describe any limitations on the use of those substitute glazes or colorants. None

G. If your facility colors brick and structural clay products by flashing, please indicate the types of substances used to flash the products and the amounts of those substances used in 1996. Substance Amount used in 1996 Units (snecifvl Natural Gas Unknown - Not Measured Not Applicable Sawdust Unknown - Not Measured Not Applicable
H. If available, please provide a copy of the MSDS's for the glazes and colorants used by your facility. If your facility prepares its own glaze, please provide any available MSDS's for the glaze imr-pdients. See Appendix A.

Page 5 of 39

,~ 

# 2 q6

### TABLE 1. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND COLORANTS

Page 6 of 39 

# otq7

### If additional space is required, please make copies of this page. If the information requested in

the table is contained in your facility's ope

~ 

### ;Fing permit or permit application, you may reference the applicable sections of the permit (or ap} `:.

- :ation) rather than filling out the table.

Page 7 of 39


## -z ~~

### A. Please provide a simple process flow diagram for each brick and structural clay product manufacturing process line. An example process flow diagram is provided in Figure 1. A diagram of the plant layout with all processes and emission points clearly labeled is also acceptable. Assign a unique identification number (ID No.) for each process that has associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. Please identify aU emission points, including those that do not emit HAP's. For emission points that are vented to an air pollution control device (APCD), assign an ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information request for any responses that pertain to any process or emission point.

Page 8 of 39


# a~ 

# F

# Add Mix Clay Process -



# ~ i ) Clay Storage Clay Unloading p Apron Feeder 0 Clay Crusher Clay Storage Clay Unloading Clay Feeder Bays (14) Bins (4) 

# ~
q 

# ~ i I 3
.



## Primary Side Raw Material Receiving

, Clay Storage Clay Unloading Clay Clay Feeders (3) Crushers (6) Clay Grinder

Clay Cage Mill Clay Shaker 

# ~ Screens (8)

Processed Clay Clay Loading

Storage Bays(20) Clay Feeders (12)



## Plant 1, Shapes 

# O 0 Pug Mill Feeders (2) Pug Mills (2) 

# I FExtruders (2) Texturing (2) Shapes Hand-Set on Carts To Plant 3 or 5 for Drying and Firing


## Plants 3& 5, Sand Preparation

Rotary Coating To Sand Coating and Sand Storage Hoppers (3) Flow Bin Mixers (2) Bins (2) Texturing Plants 1, 3, (RM-1, RM-2) and 5

Ground Base Bag Mix Caly Additives s 3



# ~ Hopper Screening Hopper Fluid Bed Dryer



### Page 9 of 39



## ---- ------- -- --- _. .

~ 

## -- Boral Bricks Augusta Plants Process Flow Diagaram Plant 1, Clay Preparation and Shaping Process and Plants 3& 5, Sand Preparation ProcessTruck wfth Dry

Processed Sawdust Fro m Processed Clay Storage or Shap(ng Process

I Brick Ifor ent



# Boral Bricks Augusta Plants Process Flow Diagaram Page 10 of 39 

# Plant 3

.~.~ ~From Processed

Clay Storage or Shaping Process Packaged Brick to Yard tor Shfpment



# (7 `;

Truck wlth Dry

Sawdust



## ~

~ 

### Page 11 of 39 

## Boral Bricks Augusta Plants Process Flow Diagaram Plant 5 -) , 2—

### B. Using Tables 2A and 2B, please provide current production rates, production capacities, and related information for each type of equipment used in brick and structural clay product manufacturing. In Table 2A, provide the requested information for only those sources that are known or expected to emit HAP's. In Table 213, provide the requested information for all thermal processing, such as drying and firing sources. For combustion sources that use difPerent fuels, Table 2B should be completed for each type of fuel. For example, if a kiln typically is fired with gas, but periodically is fired with oil, one column in Table 2B should be completed for the kiln when fired with gas, and another column should be completed for the same kiln when fired with oil. Provide the data in the units listed for each row.

Page 12 of 39

~ 

# 53cn

~ H 

## a ~ 

# w a O



### ~ 

# U ~w 0 ~
~ 

# j ~ 0 X 

## aw 

# ¢W

~ 

# z~ ~z W W 

### U



# ~ 

# a av 

## W W

~ 

## 3~



# ~ 

# W
Q ~ 

# w ~ ~ U

F-~ v ~ 0

0 

### u ~
~ G4 ~ ~ •~ ~ N ~ O a. N

~

N

~ 

# o Q ~. •~ a ~ 

# , z

~ A ~ 

# z

N v~ o ~ 

# ^ :+ o F 

### ~ CL X 

### ~ ~~ o v~ z F~ U cn ~


### C A ~ e0 

# V]
~ 

# N

O 

### ; ~ ~ z
~ + 

### •~ ,.•; 

### ~ z ~ cn v

~

00 

### ei 

# o

~ 

### Z H ~~ E=v~i Uv~i o v~i in

0 

# z ° ~

r u •• 3 O 4 

# z h p ~ • d , 3 y 'C 

## ~ Li G 

### ~ O ~ C

~ 

# u e

. ~ e 0
~ N .~ 

### .D
~ ~

~ ~ ~ H

~ ~
~ O ~ 

### o ~



## ~ o



### E •~ ~ V

~ ~ M

= ~ ~a •~ a~ o ` o ~ c~ 

# 3 ~ •= a o " ~ • U

V

~ j y ~ Q

~ U .' • 'C 

# •_ ~ ~ o ~ vl 4di %1

O ~ a~ 

# w

~ 0 

# '' C ~ 

## o K

~ .~ 

# 0 .5

~ .5 0

~ y > ~

. c:.. 

# asV

### The following notes are used in Tables 2A and 2B:

NOTE 1 Fugitive emissions occur at several points throughout this plant. Boral Bricks has no data on these emissions, and is not including fugitive sources per Feb. 25, 1998 telephone conversation between 011ie Fick (Consultant to Boral Bricks) and Bill Neuffer of the EPA.
NOTE 2 Except as otherwise indicated, Boral Bricks does not possess process-specific data that would allow estimates to be made of the types or quantities of HAPs contained in the materials or of the resulting HAP emissions. Sections 10.5, 11.3 and 11.19.1 of AP-42 provide generally available information on the pollutants that may be emitted from sawdust dryers, clay products processes and sand and gravel processes respectively. The AP-42 data are considered indicative of the types of HAPs that 

## mav

be emitted from processes at this plant but are not considered indicative of the quantities of HAPs emitted.

Page 14 of 39

~~

### ~ ~ ~ a~ ~ ~ O 

### c

~ 

# w 

# ~ a,

M w 4-4
„ o ~ kn 

# w ~ ~ ~ 

### ~ ~ ~ 

### 0 a

~ 

### a' H

~ 0 y N

• 

### V U y ~

~ 

### V N 

## a~

.., 

## ~ a

~ C ~

w ~ 

# ce a

~ 

# N >°, o +. ... • 

## ~ -o 

## ~ a~ 

# ^

CQ 

### N W 

## a a~ 

### H w H ~

~

u



### ~ ~ 0 F, 

### i2 N N

. 

### ~ + p 

## z z 

# z

5 LL ~ C7 ~ ~ u N N 

# U z 

### z a ~ 

# = o

N ~ ~ ~ z

~ 

# . z ~

~ ~

N ~ ~



### Ch z 'z - z ,



# a., ~ 

# 6i.3

~
~ ~ ~ ~
~ ~

. ~ .I

~ y

~ 

## w
~ ~ Fr U
~ «f ~.

.. ...



### ~ y L~

. U
O 

### ~ O

... .r U ~ 

### u ~
~ U 

### a ~ u
a~ U

~ r U w 

# w a~ w >, c~
~ 0 

### 0 ~ ~ ..,



### ~ oN M 4-i O

~ D

... U bA 0 CL D

4

1

1



### lm N 

### W W ~ Q~



### ~ z5 /"~ ~z 

### ~
~ ~ 

# iN

0 N 

## z 

# N
~ 

# 4)

~



### ~ ~ y ~ N 

# U o ; ~ z ~ 

## Q I ~ 

# a I M z ~ 

# a I ~ z ~ ~

+~

~

~ 0

~

. ,.. ~

~

~ 

### ~ 

# ~

~ 

# y_

o ~ H 

## y y ~ ~ N cd 

# a u
~ 

## a 

# w ~

... C) ~ , N ~

~ . 

# w . ~

~ y o ~



### ~

~ Q~ M 4.n 0 ~ 

### ~ ~ 

## a ~ 

### .~ w 0 

# y

~ +
~

~ U N y ~


## z z

{

~ (

~ 

# i
~ E

~
~ 

## c 

# c E s. 

### a 0

; F

~ ~ 

# n 5_
o ~ M N ~ z

~ 

### F yi ~


# 1~

0 v

~ + .-. 

### o



# `~ ~ .5 ~ o~ ~ o.~ o.~ •~ o

... 

## vi o c ~ eq ~; ~ , • 

## p N C. ~° c ~ A~, '
t ~j ~. ~ • p, y ~ 1~ U '~ ;.. Q+ p., ~ .~ ..r



# FE ' 

## 4 z . x

~ 

## L U E
~ 

## a

~~ S~

### C. Using Table 3, please provide information on procedures used to monitor the process operating rate for each of the pieces of equipment and HAP emission sources listed in Tables 2A and 2B. Use the same HAP emission source types and equipment ID numbers you listed in Tables 2A to 2B.
• Indicate whether you monitor process rate or not.
• Provide a summary of process rate monitoring procedures that describes how process rate is measured for the particular piece of equipment. Include where the rate is monitored (i.e., rate of material fed, rate of material discharged, or material production rate), the units used to measure process rate (e.g., lb/hr or pieces/hr), and how the process data is recorded, i.e., manually, automatically (e.g., computer - printout or stored to disk, or not at all). If you monitor process rate at both the feed and discharge ends of the equipment, indicate so.
• Indicate the type of monitor, equipment, or instrument used to measure process operating rate. Indicate the monitoring frequency or how offten process rate measurements are made. If instruments are used to measure process throughput, indicate in the monitor accuracy column the accuracy of the instrument. The monitor accuracy could be listed in terms of a percentage of the throughput ( ~ 

### 1 percent), mass per unit time (t21b/hr), number of pieces per unit time (f 10 pieces/hr), or other appropriate units.
• Indicate the frequency that the monitor is calibrated.
• Provide data in the units listed for each row.

Page 18 of 39

~~ 

# 1N ld 

### C1.
i~ 

### O ai 

## 'c. O U

~ N 

### d G N .5 

### Q' 

# w
.~

~ y 

### n.

~ 

### O

~ 

### V

~ w

.~ 

### ~ M 4.4 O 

### Cl

~ 

### _ Q an cC a.



### M W 1~

~ F o~ 

## oa oa >
Z a ~ C

. ~ 

# _ _ U
p Q ~ Da y 

### z~ z zrA 

### ~

pp y ~ ~ y ~ • C O td 

### G_ d
41 

### ~ z~ {r 

# w ~ 

# •
y f 

# O p ~ 

# d

C O U 1-0 F 

### O ~ ¢
~ z~ ~y y ~ w

CL

~ AS t ' y E -v ~ .xa i[

v V f N • ~ y 

## X .s ~ L

~ ` . ~ a

. . ~ ~
• ~ S. fA

rA N V1 S e ~ t

~ ~ ++ -C 4) cn ~ 00) 

## z a` a 3 a` • 

## ~ v ~ a
" ~ w G y 7 V %1 H 

# ~ ~ ~ ~ °' o z ~



# a 0 E

~ ° 00 a ... ~



## ..... . ~

~ 

# y

_ o ` a ___-= Q w rA 

# A F a

~ 

# 6a

### v y o ~ ~ o

~ 

### yw

~ 

### . 

### v LV O ~
U y ~ G y 

## `o 0 3 °

~ 9 ~ 

## 5 ~ v 9:6 

# u

~ C U 

### n r

~ 

### . 

## _E z~ y ~


### a.5
~ y ~ ki 

### a
~ 0

~ 

## 0
~

~ 

### ?: a 

### u

.~

~ ~ 

## .= U 

### a y
~ O b

~ ~ 

### (7~ fn 4.r O O N U tb Cl 

## a O .5

C4 

## ~ A 

# w U a C7

~ 0 H

~ O 

# w L

~ 

### cn Cn 

# w U a A ' 

### A. w O

~ 

## ~ ~ ~ M W 

### a
~ Z 

# U 

# _ v G



# z z z ~ 

# C = y ~ 

# y Z 

## z~ z z~

C V 

## e0 N 0 

## O = ~ 

## C' U C ~ ~« o o a •~

~ 

### E-Ei o 

### o — a. 

## z cl

~ 

## y

,

_U p •6 n ~ O. y 4' ~ c ~ C V a, f ~O ~ a ~"~ V • b i r' J

~.+ 

### ; c ~ O cm



### ~ 

# . °• a'

~ 

# ' . ~ 

# °' -v ~' O U C ~ U '

U •' a

~

. CA 

### L 8 E~ 

# a o ~ 

### a 3a:

~ 

### v z a
~ o c . 

## ~ 

# o o y 5 ~ ~ =a~~ o ' V1 V1 

## °' A i

~ 

## z 4) ' ~ I ~
a Z



### .~

• 

# y C ~ L ~ 

# a •r 

# Q ~
a . ~ .. ~ . .:......

~ •~ 

# a = c 

# _ ~ ~' . •~



### ~ C./ I~ 

### E a 0 ~ ~

~ 00 

### 5
CL 0 N
~ 

## q ~

ld a

~ w

~ 

# ° N Y 

## . Q G U

~ d
~ 

# n.
N .~ Q' Y

.~ v 

### d ~ .~ G ,O

~ ~ ~ 0*1 M 

### w 0 N N to cti 

### a

ri 

### W a ` e T ~ ~ •o ~ _ ~ ~ o O 4 5 z z~ ~ ~ b .5

a zCA z~ ~ ~

a ~4: o ° a ~ U Z ~ fr ~ _ ,0 9 Y Fr C. ~ ~ • ~II

~ z~ ~ ~ w r.~ ~ V N U b ~ +0 ,+ a~

u U ++ N ~+ V•• ~ W ~ U ~ 40~y~ 3

V o. rA O C

Z ~ a, ~ ~N .~
~ o ~ y O ~ ~ y ca Sa ~ z ~ ., ~s. C 40. Ir ~ O . T. a z M '; N E .y l0 . O ~ ~ ~ ~ w = .5 N U Q ~ ~ •0 a~ d

. ~



## ~ 

# 6z• ' 1 • ! • i M I e.! • r. 1". OTI 1/"I . u.rf 1 ' 1! • ! ~ • ! 

### A. Use the process flow diagrams developed for your facility and Table 4 to provide the following information for each HAP emission source at your facility. • Define HAP emission source type in terms of equipment, such as dryers, kilns, ete. As in the process flow diagram, you may group multiple pieces of similar equipment. • Use the same equipment ID numbers indicated on the process flow diagram(s). • If the emission source vents inside a building or to outside ambient air without first passing through a control device, place a check mark in the uncontrolled column. • If the emission source vents inside a building or to outside ambient air after passing through a fabric filter, dry injection fabric filter, or scrubber, place the APCD ID number(s) in the column corresponding to the APCD type. • If the emission source vents through a control device type not listed in Table 4, indicate the control device type in the other control column and place the APCD ID number in the appropriate cell. • In the emission test data column, place a"yes" or "rio" in the appropriate cell to indicate whether the specific source has been tested for any pollutants, including any HA.P's, VOC, PM, or opacity.

Page 22 of 39
,~L 

### (43

# I

~ 

# L w

~ 

## b 0 U C 

# ;D O C

~ 

## w T O ~ ~ ~

. ~ w N y 

# z ~ 

# z Iz I>" l>. 1z 0 

# 1z 0 

# 1z 0 

# 1z

~ 

## O ~


## a W 

# az ~ O Q~ ~ 

# W W U 

### ZDO O ~ 

# z

~

..~ 

## W ~ 

# a ¢

~ 

### Q 

# w ¢ O



## ~ 

# W

~ 

# a

~ 

## ~ 

# a

~ 

# a a ~ 

# Ho U ~

G U w ~ d

~ ~ 

### a



## ~ I~ 2 ~

~ y .-~-~ . 0 .5 •= 

### ~

~ 5



# A o N a ~ 

## ~

. ,+4+" A 0 H ~ ~W F• F•• t" F-

N V L r ON K1 

### w 0 M 

## N
0~ 4 

# a

~ v \

### B. Using Table 5, 

### please provide information on stack parameters and emission estimates for each emission point at your facility that is known or expected to emit HAP's. Provide information for all APCD's, including those that exhaust inside the building. Include data for each inlet and outlet, if available, as indicated in the table. If you have more than one inlet to an APCD, provide data for each of the inlets. Provide data in the units listed for each row. Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal HAP's or VOC for organic HAP's. Emission estimates may consist of ineasurements reported in emission test reports or may be calculated using mass balances, emission factors, engineering judgement, or other estimation methods. Provide the emission estimates as emission factors in units of lb of pollutant emitted per ton of product (lb/ton). Provide complete copies of any emission test reports or other reports that document measurements of emissions. 

### Test reports and other emission measurement documents should include the following information: process identification; location of sampling point; stack diameter, temperature, and flow rate; test method, including analytical procedures; number of test runs; emission concentration, emission rate, percent oxygen, and percent moisture for each test run; process operating rate; type of APCD; and APCD operating parameters. However, test reports with incomplete documentation may still be useful and should also be submitted. You do not need to fill out Table 5 for emission points that are covered by an emission test report that is included in your submittal. If emission test reports are not available, provide calculations that support your emission estimate, including the basis for all assumptions in the estimate. 

### Note that emission estimates are needed for all HAP's that the facility emits or has the potential to emit. (Please refer to the HAP list in Attachment 1.) If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 24 of 39~



### W 

# a ~ H m m m m m X X
~ 

## O C C C y C y C y 

## rn ~ b ~
O~ C

~ I •` ' ~ a 

### N

~ 

### A A ° •' ,~ ~ 

# n =

.r
~ 

## 3 O

~ 5 y 

## w [

~ ~ ~ O

.~
~ 

## a



# = .~ a 1 40 ~ 

# o ~ z ~ " ~ U

L41 v a y

Vl

~ •y ~ O ~ U ~ e U O v O ~ L V °~ Q ~ ~+ ~•-~ o 

## v o ew "° ~ v a~ ~ W ~ 

## . o E o °:

v v~1 ~ N in v~i 

## `°. °°

~ ~ M 

### 4.4 0
~ N N b0 c~ 

## a

c~ ``'L/ L7,t tm L d
~ ~ a+ .~

~ 

### N
~ 

### f1..i O y R7 O .~ y .L~ f0 U



### ~ ~ ~ ~ 

### E 0

~ ~ a+

.~

~ ~ ~ 

### u, 

### ° oo

~ O y . 4 +

O 

## 3zz 

# zz n.

Inu

~ u U C U w U L.
~ G
~ O T ~ .~

~. bn .5 

### ~

~

. O y
~

~ 

### U w

~ O >•. 

### .5 .5
~ 

### a 

### U y

~

~ 

### .5 b b~ + 

# u O 

### N 1~ y

. ~ O ~

L .S

~ 

# =. iE O%

M 

### w O

~ N a~ 

### dn c~ rs,

~ w 

## a

L ~¢ C'^ ~ w ~+ ~ Q


### _d
~ I..y

~ a~ + ~ 0

~ .r
~ 0

. ~

~

~
~

~ O rr

= ~r ~
~

~ .. d C i.r



### N V b0,5 y

~ L.

v ~ ~

~ y Q y

y y ~~ v •~ • ~ y b~ + y 

### Oy ,'t, G ° „ a> y c ~



### w m
- ~•~ —: _ c ~

~~ 7V'f w 

## a ~¢ F~ ~ 

# w
~ 

## o a z Q z Q z a z a z



# w 'z 'z = ~ 

### o ~ ° 

# e u 3 0 N ~ V

F C C C 

# w o 0 0 0 0

~ o N ~ ch C3 W O
f~ cn N rr

r 40
~ ~ O

w 

# w C r ~

~ .r 

## °
~ °~ 

# ' 'o E 

# z
..

o •°- ° ^ ~ 

## a Y ^ c ~~ S ~ ar 

## o

~ ~ • y ~ O ~ '^" V ~ e ~ ~ U ° .

~

+ ° "' • ( y

~ + y y O ~ a.~+ ~.~i C~ ~ Q ~ ~ a • y ~ ~ i

N ~ yv' ` ~ t0 ' ~ ~ ~ 

# o to 

# v Q w ~ ~ 

# 14y U •v_ ~ ~Q ~ 

# E o ~

~ ~ 

### n v

~ 

### i ° ~ `~ ~ 

### a .c >.°—_° C7 Z .a C7 C7 C7 o cc > tC ~ l- 00 Q ~ M 4. ~ O

~ N

~ bD

~ 

## a

~ ~~~ ~ ~ ~ ~ ~

.. .~ GL w 'J w 

### O C O .~ U ~ N N

~ A U a a A U
~ N U C V
~ ~
~ A C G ..7 0 ~ ~ .r 

### bU C ea N Q. O y
~ U W

~ . 7 T C

F U

. ~ U .S o C w U



### ~ 0 ~ 

### n .s 00 

### ~

U •C a, 

### ~

~ 

# z z ~ 

# o b„ ~~~~ ~ zz;r.'. ON

M 

### w O

~ 

### N

~ c~ 

## a

vi 

### W r-a
~

~ 

# w 0 O

y

... ~. O rr

~ 7

~

~.+ N C

.,


### d r ~ O

d O rw

~r Y ir
~ ~

~ r
~ G

~


### y ~.5 y ~ ~

~ C u y O C O O w V

y p

A q e ` p

~ 0

~ y y '~ •~ ~y a~.~ Vl N



### ' y '~ '~Or~ W • ~ ~~7 ~ ia~

_ . y

.

• c~ ~ •~ O


# _ p ~



# oab•- , ~ 

# -. ~ 

# W 

# o _

~~~I



### te; W a

~ H ~

~ N 

# o z z z z z

0 0 = 

# m m m m m

L y


# O O O O O

y

y ~ ~

, N 

# o Cn r7 G m M 3 r ir d
~. ~ O

~ d 

### a ,.,

=

~ r

~ C o
Q ~ • ~ ~ S. ~ ~y, y ~ V ~ ~ ~ ~ y Q. 

# A 3 ° t=

cn w, t- oe C ~ 

### a-, M 4r O O\ N O a4 c0 

## a



## ,9-.?aP71 L. ~
~
~

~ .+ .~

~ d
~ 0 C 0 .~
~ N d

.~ ~ U 4 

### a ~ u ~ u U C N 

## w

~ ~ ~ ~ $ 0 0 ~

~ r .~

~ . Oq .5 ~
~ 0 N 

### r4
U w
~ O .5

o C 

## L" U

O ~ 

## a ~

~ 

### E r

o. ~ m,Q



### ~ 

# zzs ~ v„ n „on

~ o Q~ .S O\ M 44 O O M a~ ~ c~ 

### a

~ ~ Q 

# Fi l l.

d ~ 1.y

L+ ~ ~.+ O ~

~ + ~ a

..

N
~ D 0

~ ~

~

~ = y
~ 

### O

+r 

# _Y
G



### y

~

~ 

# ~ ~ o ~' ~ vi cd

y N N
~ v • C. • i/l o, ~,~ N N (~

: • 

# o . _

C ~ -? /

### C. Using Tables 6A through 6D, please provide design and operating data for each

APCD associated with all dryers, 

## kilns, and any other brick and structural clay products manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of APCD's. Use Table 6D for other types of APCD's. When using Table 61), please specify the type of control device and 2 to 4 key design or operating parameters for the device. Provide data in the units listed for each row. If the information requested in Tables 6A through 6D is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the tables.

Page 31 of 39

"-;q I 

### -72--~ ~ 1r

~ ~ .~ C3. U W O C O

. 

### ~ N

` 

### Q ^
V W a
~ 

# H ~

~

F U



## ~ b0 

# ~ U



### ~ N OU ' 

### .~ 

# .~ v

~ _^ dn U b 3 e`y~ 3 3 ~ O C ~ ON ; c° O V Z
2~ a o E■ 3 ~

.. ~ Y ° .° ~°° u" °°° o 0 3 b C~v ~ ~ QFGQ4 00 aL1a ~ M 7 A

N

~ ~ ~ 3 = •° ~ z o ~ ~ ~ ~ •~ -o ~a• 5 00 v ° ° = •5 = w ~ ~ " b •~ C 'v ~+ ii a] Q U

0 W as l*1 

### w O N M v cw cd 

### a,
7R
V N W 4 7 O

~ 5 ~o w 5
~ c 0 U H w
~ ~

~ 5 b
~ 

### 7 

## u

.. ~ ; 

### o~ 

# w~ 5 ° u °D
. tir 

## ,;2 73C*l
~ W
~ a ~ 

## w U

~ -.y W

~ 

## w 

# z ~ U 

### ti >4 04 

## A

~ ~ W a 

### ~ Q F ~ 

### ~ ~ 

# u
~ ar

. ~

~

~ W Q

~ ~
. y V U H N .D Cd ~ . Q !~

~ N U
~ ~ 

## w I U r

C 0
~ ~ 

### .~

~ GG V ~

~ = o 

### a N 

## = 0 z ~

~ 

## .5

~ 

## .5 9 a 0 ~ N .~

~ H ~ 

# o N o ~ 

# S ° •" o e

~ 

## «,

~ p ; •.. 

### ~- 4C. 0 

### ~ ~ ~ b • 

### ~ : ~ ii ii a0 Q U 5

— N I- 00 T o ~ o. aN K1 4..i O M M 

### ~ C~ 

## a

~
~ 

### ~ O

~ 

## .5

~

v~ ~7C/J
~ 

### W

~ ~
~ 

# U

~ 

### U ~o 

### W a GQ

~

~ O
~ s 

### 5 0
~ e ~ 

# u
~ ~ ~ .~

~. ~ ~

~ . 0

~ 0 .~ U

~ l N

~
~ ~ U

. Q

~

~7 N U G N ~. w V

~ ~ D

~ 

## .~

~ 

### . 

# a o

~ N o ~ + ~

~ 

## U w fr 0

~ .5

~ ~ .5
~ a 0 V N .~

~ ~ y ~

~ N b `~ • ~ 3 ~ ~~ • o ~ Q' o ~

~ •~' ~'~ ' v ~

p~ p O tO O ~:~ Q `~ ~ y

~ ~ ~~. F~ . LJ' ' ~.~„ O ~ ~ ~ ~ v ~• ~ 

# 0 b
~ ,

° b ~ 

### o a~ 

### .a :O ~~ 

### w: F- 5 ~ ~ 

### •. 

## U o i° o o

~ o g

-- N M

~ t v1

~ O I ~ 00 ~ «• ~ M ~ 0
~ M
~ c~ 

## a

~ ~~~ ~ ~ ~ ~ ~ w .~

~. 

### u s' a w 

### 0 N C O .~ V N y N .D
~ V 

### a a 

### ~ w ~

~ V G 

### u ~ 

### w V

~ C G

~ ~ ~ M

~ 

## € o pp M 5 ~ 

### ~ 

# a a 0 N r~ 

# , V

~ y 7 O A 5
~ 5
~ C

~ 

# H_ _d

~
~ ~7 5 v N

~

~ L
~ 

### o ~ o ~ 5 ° S •S

~ !r: v~ W 

### U ~ ~ W 

### A

~ 

### 0

~ L 

# z 0 U

~ W 

# H O 

# Q

~ 

### a W

~ ~ Q~ e: ~

~ 

# = .~ 

### a ~ ~ 0 

# z

3

4 1 2

c

L: 

## ;?- -7k

### D. Using Table 7, please provide the following information on current monitoring

procedures for each of the control devices listed in Tables 6A to 61): parameters monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices used (e.g., differential pressure transducer, thermocouple), and recordkeeping practices (e.g., manually recorded in log book, continuously recorded by electronic data acquisition system). Describe briefly other operation and maintenance (O&M) procedures for each control device. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table. 

# PIM9 06Mo 1 

### ' - M, e INU 

### MM . : IM. 

### A. Please describe all pollution prevention practices (i.e., process modifications, such as re-use of discarded or rejected materials, or any practice that prevents or reduces the amount of air emissions, or the generation and release of solid waste or wastewater associated with the operation of air pollution controls). If the information requested here is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than providing the infonmation below.

Page 36 of 39

,; 

### ~ --;27~

~ t ~ ,
t~ 

### W W Q 

### H 0 0

~ G •= c ~ s 'C



### = a 

### U > ~ 

### ev;, ~ ~ 

### > `~ o 0



# w ri v w U a 

# O I I I I I I

0 1 I I I t I • ~ I I I 1 I I a t t Q t t s t z t t z t t t t t t t t t t

s t t t t t

t t
~
s t t t t i t t
w ~ 

# ° y~ ~

~ • v t t t t t t 'i

~


## ~ .~ I I I I a I I • 

## ~

~
~•~

~ 

### o t t ~~ t t

t t t

t s t t s 

### t t 1

t t t s •`



## ~ E 

## ~ °• I I 

## ~ >> I I I I = 

## V > m c C

. Q 

# °z €
N 

# w

~ as M 

## w O 

## n M dfl

~ 0.

,: ~ - /1?,kthil 1 •111 c• 1 • 1 ~ • ~ 1 " rl e.l M4 •_1 • ~ l. i._ ~ NM. Ue.l .r- i, t 1' 

# • ' A. Using Table 8, please identify all other processes or operations at this facility that are not addressed in Items II through VII above and that are potential sources of HAP emissions. Estimate total annual emissions of each HAP emitted by these collocated processes. If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 38 of 39

~-~~

### TABLE 8. ESTIMATED ANNiJAL HAP EMiSSInNS FRnM nTkF.R

~ 

### nr rRCFc

Process/emission source/SIC Code(s) HAP's emitted Estimated annual emissions, tons 

### EXAMPLE: Mining SIC trace metals (Cr, Mn, Ni compoands). 0.2

Quality testing lab in support of brick manufacturing: A small quality control testing laboratory operation takes place at this plant but is not otherwise identified or reported in this ICR because there are no emissions data available.

SIC 3251 No Data No Data



### SIC

SIC

SIC If the information requested in the table is contained in your facility's operating permit, you may reference the applicable sections of the permit rather than filling out the table.

Page 39 of 39



### ~~~

## APPENDIX A MATERIAL SAFETY DATA SHEETS

## -Pa-ge 1 

## OF 2 MATERIAL SAFEIY 

## DM SHEEr sEcrioN I iDan

- EFiCATION OF PRODUCT ManaLfactLm

- er f 

## s Name: Merry Brothers Brick Emergency Telephcne Number



### A 

## Division Of 

## Boral Bricks INC. 404-722-6831 Address (Number,Street, Cityp State, zip Code) C.A.S. No. P.O. Box 1957 (13) Augusta, GA. 30913 1332-58-7 

## Chemical Name, Identity Merry Clay 

## Chemical, Family, Pynonyrs, EIC. 

## HYdrous aLluminun silicate-Silica S=ON 

## II KUMUAL 

## OR CCM¢'ONFN11 -t 

## Formula Al203 2Si02 2H20 

## T'rade Name 

## Ver C. A. 

### S. No. H.M..I.S. 

### Clay/ Shale 50 - 75 11332-58-7 

### Health Hazard o 

## Free Silica (Quartz) 

## Si02 25 - 50 14808-60-7 

### Flarmrability Hazar o Reactivity Hazard 0 

### Personal Protection 

## t I 

## SECrION III PHYSICAL DM 

## Appearance and Odor: Tan Powder when anourd, Enthy Odor, Especially When Wet. Boi-ling Point(F): N. A. 

## Specific Gravity (Water--1): 2.6. 

## Vapor - 

## Pressure (m Hg) 

## N. A. 

## Percent Volatile (By 

## Volume): N.A. q. 

## N

. - Evaporation 

## Pate (Drtyl .7apor Density' acetate=1 Solubi1ity In

. Water:

. Insoiub1fi' - Evaporation Rate '(Ethyl6thei, A,= SECMON 

## IV EXPLOSION.DATA FLish Point (Specify MeUlod) Flanimable Limits 

# Ladex. ..(Degrees"FWwer6_it);. on P 

## e N 

# FliW Ectirquishin

- g Milia' 

# lq

~ 

# 'T -i 3.

A 

# P" , 1%C Uvi - 

### "(X?,


# L Msa E:e 7 ty % 

## "M;R 

# e

~ 

## i 1



# __ q

Wj ._&_zrge,,to , resporjsibl& q- 1 , 5t- at"a • -sut 1 

## 6' ;,e llt,at

~



## jthgi Rdjr:eE_;X.F:TAlth6_x i 

## the =

- oir '4i :: rar-1 1 0 w ]"~~ 

## 44,-- V~ 

### '- .. -1-'

~ 

### ..' e V.,.-10 F. u 

## f rom
- : so 

## e ito' ooqtAixi e d , ~ 

## , veibddhic WilO r -i i

~ - 

## b&li'Viiid ;j5e'

- , , reiliib1:o , !3 . r to: c a kihd,

- e -- xp ax-L 3 

## an _a.p 

# ye

## Paa a e 2 of 2

3 ,

:17 

## SECrION V HEALTH 

## HkZAM DATA 

## lffweshold Limit Value (TLV): 1.0 

## mg/M3 (ACGIH & OSHA) 

## p e nd_ssable EVosure Limit - 

## Tvtal Dist: , 3.0 

## mg/M3 (ACGIH) 

## Permissable Exposure Limit - 

## Re•pirable Dust: 1. 0 

## mg/M3 (OSHA)
Route of Ehtry: Lmgs (Breathing) 

## Effects of Overexposure: Prolonged Irihalation May Cause Lung Injury (SIMCOSIS) in scme cases. 

## EYrerger l icy and Fu

- st Aid Procedures: Wash dust fron skin with soap and water.

Flush cut eyes with generous a=unts of water. SECrION VI REACrVM DAMN Stability: Unstable 

## 140 

## Conditions to Avoid: N.A.

Stable YES 

## IncaTpatability (Material to Avoid): None Hazardous 

## Decarposition Products: None
Hazardous Polymerization 

## Will not oocur. SECnON 

## VII SPILL OR LEAK PFCCEDURES 

## Steps to be, taken in case Material •is Released or SpiUad: 

## Sweep up or VacLm and rexLse. : 

## If Contamimted,"". in suitable. contairex Waste Disposal Mett

- 10d: MaY bs 

## disPOsed Of 

## in an aRx'Oved 

# Iani if 

# i ll Fli6ility.

- -. in. )ordance with Applicable Federal,, State and Local Regulationd..

- ~



### vii SPECIAL PRO 

## INFOEVA0N T1 ....SECrION ify;;Ype ?ve Respiratory Prot on; dVcb • 

### 5r , 1 

### .4 

## on.. 5-YeSD 

# :.
4 j 4. Lz~
tt " 

# WA Hm Gloves y - q Pii~~ 

### -.0



## aon:: ~ 

# N'M -
f-3. I 

## ot I •- 

## I x sp EC iW 

## PRE c Auri oN s i7incJ:*,,

## f"N

ot 

## -

In. 

# Material Safe'QData SheeL

7 

# -Substance Identification • 

# bW &DIOMDEr 

## ~ ; • CAS #: 1313-13-9 

### TradeNamm Brickor, GranuSpcA' 

### tr M CC • 

### Manufacturer. ThePrlj ~ 

### 6-Nlanuracturi n 

### CompAny ti ~ 

### er en 9 9 

### cr. Che' Oue 

### Prince' P"

- 

### 24 

## 1

- 

## 806

- 

## 4

- 

### 9300 

### OuLncy, 217-=-n% 

# 'Components and Contaminants Chemical Na-me 

### CAS # OSHA P ACGrK TLV P;rcen 

### MangaDese Compound (as W) 7439-96-5 5 m-,Jml (c) 

### 5 mglml (c) 51-55% 

### Ma Iron Oxide 1309-37-1 — 1-5% 

### Fe, 0 3 

### SiUca, CrystaMne Quartz (respirable) 14WS-60-7. 0 

### o ~ I M 3 0 . 1 

### mg/m3 (IWA) 1-5% 

### si 2 

### Aluminwn Oxide 

### (non-fibrous) M3 

### (respinble fractioa) 1344-28-1 15 mg/m'('I'A) 14% 

### AI s O, 

### Barium Oxide 1304-28-5 02-2% BaO 

# Physical Data BoWng Point NA 

### Spedfic Gravity ~ 

### I.O = 1): 5.0 

### Vapor Prewwc (mm/Hg): NA 

### Melting Point (Decomfos c ") 53Y 

## C""'. - Vapor Density (Air = 1): 

## NA Evaporation Rate (Bury A e Acetate %;1): NA 

### SolubMty in Water. Appearance and Odw. 

### black to brownish black, no odor



# Fire and Explosion 

# Hazard Data Flash Point: Not conibuttible Flammable Llmitsi* LEL NA 

### ir EA:tingiishiag Media. Foarm, CO., or dry chemicaL Special Fire F4hting Procedur= In 

### the eveat of fire, wtu full protective clqthing and 

### NIOSH-approved seLfcontained breathing apparatus with fuU fice piece operated in the pressure demand or other positive pressure mode. Unusual Fire and explosion hazards. Not combust • bte, but substance is a strong oxidizer and its heat of reiction wUreducing agents or combusti'bles may cause ipitioiL Increase-s the flammabWq of any combustllc substance. 

# Reactivity Data. Stabilit)r Stable under ordinary concfidons of use and storage. .1 

### Conditions to avoidL Do not heat or grind in the presence of easily oxidizable substa&es or organic IncompatlbWq (materials to avoid): matter. EasUy oxidizable substances, sulfur, sulrid'ei, 'phosphides, hydrophosphides ' J:;:: 

### chlorates, peroxides, aluminurn powder, rubidlum'acetyii4e, potassium azide, chlorine trifluoride. Reacts with hy4roc!49ric acid to form coftosive chlorine gaL Han 

### dous Decomposition or Byproducts: Upoa beating it decomposes to'form i mangan' " c

s - esquioxide and oWa which facxlitates combustion. .7 -; Ltj 

### Hazardous 

### Polymerization:. vrlu 

### not occur.

Manp , = Dicr! ' , pa;t I

## Health Hazard Data Route of Entry: iNNA1aTION: May irritate the respiratory tracL May cxrcase the incddence of upper respiratory infectioas (pneumonia). Prolonged aposure to u7ica dust"

_. __.. may result in silicosis, a fibrodc lung distase. _._-, ... ,.. 

### .. ~ 

### SKIN: May cause irritation. _... _ INGESTION: May cause abdominal pain and nausea. 'sfanganese dioxide dust is poorly absorbed through the gut. Health I-iaaatds (Acute and Chronic): Chronic exposure and inhalation of excessive manganese dn_st may cause d'u-

. -- - - --- - - - - . - --- orders of the central nervous system. - - Carc3nogenidty: NTP: No IA.RC Monographs: Yes (30ica) Signs and Symptoms of Exposure: Early symptoms of manganese toxicity include slugg

~ 

### shncss, aleepincsa, aad, ::: .. •

- weakness ia legs. Symptoms of silicosi.s incl de impaired palmonary funcdoa ._--. -. .

and wheea.ng
. . 1 ~ 

### . . Aggravation of Pre-existing Conditiou.s: Persons with impaired respiratory function may be more susceptible to the effect of this subscance. Emergenry and First Aid Procedures: IF LNHALED, remove to fresh air and seek medical attencioa for any breathing difficulty. ,

_ IN CASE OF SKIN COi`ITACT, wash with soap & water. Seek medical atten-

~ 

### tion if red & irritated. LY CASE OF EYE CONTACT, flush eyes immediately ocich water for at least 15 minutes. Seek medical attention if imtation persists. IF INGESTED, induce vomiting immediately by giving tsro glasses of water and sticking finger down throat. Never give anything bp moath to an uncon-

. sdous person. Call a physicdaa immediately.



## _ Precautions for Safe Handling and Use Material Release or Spill Precantions: Should a spill occur, venti7ate area. Clean-up personnel require respiratory protection. Recover uncontaminated material for use. Vacuum or sweep •... -, remaining material, keeping dust to a minimum.• Isolate vtt material from dr' ^ ; , .;,: : , : : • ,

~ 

### Waste Disposal Method: and store aaray fiom combusti'ble materials. t Dispose of unreclaimable material in a RCRA-approved aaste faciIity. ;~. r:;; 

### radling and Storing Precaution.s: Manganese dioadde is dassified as an oAdizer and shoald be stored in a dry

~ 

### _- ------ ----- `- - p 

### lace away from combustibles and sources of high heat. Protect containers
- damage in from and keep closed w6en not use. Other Precautions: -- -- --- - Observe good personal hygiene. Wash aher handling.

- ~ 

### =-
: A -


## - Control Measures : Respiratory Protedion: ::,: . Use NIOSH approved particulate respirator if dust gmsation occurs or is

_ ,,.,, .;; ;;:.::,;;;, •, .,,; ;:,,; anticipated. USBM approved schedule 21B respiratot or equal is recommended. ,VentY'lation: A system of locai and / or general exizaust ia recommendad to keep employee

, 

### 1t;t,.;: ~ 

### .; ;,;;.; :: ;; ;.i .• ; exposures below the Airborne Exposure Limita. Local ezbaust is generally preferred because it can control tbe emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document,'Industrial Ventilation, A Manaal of Recomniended Pradices', most recent edition, for detat7s. _. • - 

### Protective Gloves:
.. . - .. . Yes _d

~ 

### Z Eye Proteciion: wi:, Safety goggles are recommended. Other Protedive Clothing or Equipment: Use other protective equipment whea necessary ia order to avoid prolonged : c:••,.L

~ 

### . ,:':r ~ ~ ::;~ ~ 

### ,. :.; X:`M;t:.. exposure to skin. _Work and Hygienic Practices: Observe good persoaal hygiene. Wash after handling.

~ ;f "i "C ' • • • •



## SARA Title III Section 313 Supplier Notification This product'contains the fonowing toxie chemicals subject to the reporting requirements of section 313 of the Emergency Plaaning and Community Right-to Know Act of 1986 and of 40 CFR 372.45: = e ~ CAS # 7gby Weight

. 

### Mangaaese Dioxide 1313-13-9 51- 55% Ma 'aslum Oadde 1344-•23-5 0.1- 1.8% Ba ' _his inforaation must be included in 3!1 titSDS's tbat are coricd ar.d dis.ribu:cd for th's m3terial. N(l=;:_cc Diocde. Page 2 July 1991.

,~~ •

# The T1111beI'llll',Il, 

# Yiie Materiai Safety Data Slieet TRADE NAME 

## Wood Dust SYNONYMS 

## None CAS. NO. 

## None DESCRIPTION 

## Particles generated by any manual or mechanical cutting or abrasion process performed on wood. PHYSICAL DATA 

### Boiling 

## Point ........................ Not Applicable Specific Gravity ..................... Variable (Dependent on wood species and moisture content.) Vapor Density ........................ Not Applicable % Volatiles by Vol ................... Not Applicable Melting Point ........................ Not Applicable Vapor Pressure ....................... Not Applicable Solubility in Water (% By Wt.)....... Insoluble pH................................... Not Applicable Appearance and.Odor .................. Light to dark colored granular solid. Color and odor are dependent on the wood species and time since dust was generated. FIRE AND EXPLOSION DATA 

## Flash Point .......................... Not Applicable Autoignition Temperature ............. Variable (typically 400 - 500• F) Explosive Limits in Air .............. 40 grams/m' (LEL) Extinguishing Media .................. Water, CO„ Sand Special Fire Fighting Procedures..... Use water to wet down wood dust to reduce the likelihood of ignition or dispersion of dust into the air. Remove burned or-wet - - - dust to open area after extinguished.

### Inhalation.............................. May cause nasal dryness, irritation and obstruction. Coughing, wheezing and sneezing; sinusitis and prolonged colds have also been reported. Chronic Effects ......................... Wood dust, depending 

## • on species, may cause dermatitis on prolonged, repetitive contact; may cause respiratory sensitization and/or irritation. Prolonged exposure ' to wood dust has

been reported by some observers to be associated with nasal cancer. Wood dust is not listed 

## as a carcinogen by IARC, NTP, ACGIH or OSHA. REACTIVITY DATA 

## Conditions Contributing ................. Stable under normal to Instability conditions. I 

## ncompatibility.......................... Avoid contact with oxidizing agents and drying oils. Avoid open flame. . 

## Product may ignite at temperatures in excess of 400°F. Hazardous Decomposition ................. Thermal oxidative Products degradation of wood produces irritating and toxic fumes . and 

## gases, including CO, aldehydes and organic acids. Conditions Contributing to ...........::. Not Applicable Polymerization



## ~ 

# 7

## Unusual Fire and Explosion 

## Hazard....... Wood dust is a. strong to severe explosion hazard if a 

## dust "cloud" contacts an ignition source. HEALTH EFFECTB INFORMATION 

### E 

## xposure Limit .......................... ACGIH TLVM: TWA - 5.0 mg/m s ; STEL(15 min.) - 10 mg/m 3 

## (softwood); TWA - 1.0 mg/ms 

## (certain hardwoods such as beech and oak)
1 

## See footnote below concerning OSHA PEL: OSHA 

## PELs for wood dust TWA 

## - 5.0 mg/m 3 ; 

## STEL (15 min.) - 10 mg/m 3 (all 

## soft and hard woods, except Western red cedar) ; Western red cedar: TWA - 2.5 mg/m 3

. 

## Skin and Eye Contact ..................... Wood dust can cause' eye irritation. Various species of wood dust can elicit allergic contact dermatitis in sensitized individuals. Ingestion ............................... Not Applicable Ski 

## n Absorption ......................... Not K,nown to Occur

1 

## Although OSHA's Air,-,^ontaminants Rule, including OSHAts wood dust PELs, was struck down in AFL-CIO v: OSHA, 965 F. 2d 962 (i1th.Cir. 1992), 

## a number of states have incorpor.ated those provisions in their state plans. Additiomally, OSHA has 

## announced that it nay cite companies under the OSH Act general duty clause ur.der aopropriate circumstances for non-compliance with these levels.

### PRECADTIONB AND BAFE HANDLING



## Avoid eye contact. Avoid repeated or prolonged contact with skin. Careful bathing and clean clothes are indicated after exposure. Avoid prolonged or repeated breathing of wood dust in the air. Avoid contact with oxidizing agents and drying oils. Avoid open flame. ' GENERALLY APPLICABLE CONTROL MEASUREB 

## Ventilation: Provide adequate general and local exhaust

ventilation to maintain healthful working conditions. Wear goggles or safety glasses. Other protective equipment such as gloves and approved dust respirators may be needed depending upon dust conditions. EMERGENCY AND FIRST AID PROCEDIIRES 

## Eyes........ Flush with water to remove dust particles. If

irritation persistis, get medical attention. Skin........ If a rash or persistent irritation or dermatitis

occur, get medical advice where applicable before returning to work where wood dust is present. Inhalation.. Remove to fresh air. If persistent irritation,

severe coughing, or breathing difficulties occur,.get medical advice before returning to work where wood dust is present. Ingestion... Not applicable BPILL

~ 

### [,LEAR CLEAN IIP PROCEDIIREB_ 

## Sweep or vacuum spills for recovery or disposal; avoid creating dust conditions. Provide good ventilation where dust conditions may occur. Place recovered wood dust in a' container for proper disposal. IMPORTANT 

## : The information and data contained herein are believed to be accurate and'

~ 

## 5i`ave been compiled from sources believed to be reliable. It is offered for your consideration, investigation and verification. AF&PA makes no warranty of any kind, express or implied, concerning the accuracy or completeness of the infornation and data herein. AF&PA will not be liable for claims relating to any party's use of or reliance on information and data contained herein regardless of whether it is claimed that the infornation and data are inaccurate, incomplete or otrerwise misleading.



## ~~ 

# f

## Wood Dust IIacacd Labc:l 

# Caution! Wood Dust (For all Untreated Wood and Untreated Wood Products) Sawing, sanding or machining wood products can produce wood dust that can cause a flammable or explosive hazard. Wood dust may cause lung, upper respiratory tract, eye and skin 

## irritation. some Wood species may cause dermatitis and/or respiratory aller.gic effects. * Avoid dust contact with ignition source. * Sweep or vacuum dust for recovery or disposal. * Avoid prolonged or repeated breathing or wood dust in air. * Avoid dust contact with eyes and skin. * First Aid: In case of contact, flush eyes and skin with water. If.irritation persists, call a physician. For additional information, see the Wood Dust Material Safty Data Sheet. 

# THE TIlVLBERMEN, INC. P. O. BOX 107 CAMAX GA 30807 (706) 465-3506

~J~

# .._.. . .... .. S MATERIAL SAFETY DATA SHEET
Page: 1 

### Date Prepared: October 18, 1993


# PRODUCT NAME OCHRE 1. CHEMICAL PRODUCT AND COMPANY-=IDENTIFICATION Product Identifier: Ochre CAS No.: 1343-81-3 

### General Use: Pigmenting Agent Product Description: Natural Iron Oxide, N548 Ochre, #404 Ochre, /808 Ochre MANUFAC'TURER: NEW RIVERSIDE OCHRE COMPANY, INC. P. O. Box 460 Cartersville, Georgia 30120 Contact: Mary Nell Miller (404) 382-4568


## 2. COMPOSPTION/INFORMATION ON INGREDIEN'TS

-
~~ 

# .. .._.. _ -

Ocl

~ 

### reis go . ethite, a naturally occurring inorganic iron oxide. Componoats preseat at levels greater than 196 are: 

### Wt. % CAS Registry ,i! HFe0 1 52-63 1310-14-1 Si0 = 20-29 14808-60-7 Ma0 = 1. 54.0 1313-13-9


## 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: ... Poses little or no immediate bazard. Not absorbed by the body.
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200): EXPOSURE LIMITS 8 Hrs. TWA OSHA-PEL ' ACGIH TLV RESPIRABLE DUST TOTAL DUST (TABLE 2) (1991-1992) SiO ; 0.1 mg/m' 0.1 mglm 3

,~ 

### 7- 7l

### Page: 2 Date Prepared: October 18, 1993 

### POTENTIAL HEAI.TI-i EFFECTS: IIv'HALATION: lahalation of the dust may cause mechanical irritation to the respiratory tract. Excessive exposure above the TLV can give mild pulmonary irritation. Long term over-exposure to silica causes silicosis. 'Riis product is considered a carcinogen by IARC because it contains crystalline silica at levels greater than 0.196. EYE CONTACT: Will result in no specific effects other than general particulate irritation in the eye. SKIN CONTACT: Not absorbed by the body. Skin contact may cause mechanical irritation due to abrasion. INGESTION: Not absorbed by the body. CHRONIC: See INHALATION above. "



### 4. FIRST AID MEASURES INHALATION: Remove victim from the area where TLV has been exceeded. If victim not breathing, give artificiai respiration. Call a physician. Remediate work area as described in Section S. EYE CONTACI': Flush eyes with large amounts of water until irritation subsides. If irritation persists, get medical attention. . J 

### SIQN CONTACT: Wash with soap and water. Get medical attention if irritation develops. IIr'GESTION: If conscious, give large quantities of water to induce vomiting. Get medical attention. 

## S. FIRE FIGHTING MEASURP,S FLASHPOINT: Non-flammable. EX'I'IIdGUISHING MBDIA: As appropriate for sursounding combustibles. Product does not bum or support combustion. Not a fire or explosion haurd. FIRE FIGHTING EQUIPMENT: Respiratory and eye protection roquired for fire fighting personnel. 

### 6. ACCIDENTAL RELEASE MEASURES GENERAL: Refer to local, state, or federal regulations for specific disposal information. Pursvant to 40 CFR Part 261 of the Resources Conservation and Recovery Act (RCRA) regulations currently in effect, discarded iron oxide would not be classified as a hazardous waste. LAND SPILL: Vacuum or scoop up spilled material for recovery or disposal, avoid dusting conditions and use good ventilation. Wetting the spill area with water spray may help to keep airbom dust levels down. WATER SPILL: Product is inert and stable. Decomposition and polymerization will not accur. `

~~ J" Z

### Page: 3 Date Prepared: October 18, 1993 

## 7. HANDLING AND STORAGE STORAGE TEMPERATURE: Ambient STORAGE PRESSURE: Atmospheric GENERAL: Mainta; i packaging intact until ready for use. See Section S.


## 8. EXPOSURE CONTROL/PERSONAL PROTECTION ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airbom levels below recommended exposure limits. Provide mechanicai ventilation of conflned spaces. PERSONAL PROTECTION: Eye Protection: Safety glasses or dust tight goggles. Skin Protection: Rubber, cloth, or plastic gloves if appropriate for job conditions. Respirator: If exposure limits are excerded and appropriate NIOSH dust respirator should



### be used.


## 9. PHYSICAL AND CHEMICAL PROPERTIES Specific Gravity (Absolute): 3.5 Solubility in Water: <0.556 PH/10% Solution: 8.5 Average Particle Diameter (Microns): 2 Bulk Density - Loose/Lbs. Cu. Ft.: 55 Odor: None Appearance: Solid Yellowish/Brown Powder 

## 10. STABILITY AND REACTIVITY GENERAL: 'Iliis product is stable and hazardous polymerization will not occur. INCOMPA'IEBLE MATERIALS AND CONDTTIONS TO AVOID: None HAZARDOUS DECOMPOSITION: None


## 11. REGULATORY INFORMATION DISPOSAL: Natural iron oxides are not harardous wastes per 40 CFR 261.24 or 261.3. However, the user should consult with the state environment regulatory agency before disposing of this material. SPILL REPORTING: Natuaal iron oxides are not CERCLA hazardous substances, per 40 CFR 301.4. These are not on the list of harardous substances under the Clean Water Act (40 CFR 116 and 40 CFR 117), nor are they included on the list of Extremely Hazardous Substances under SARA, 40 CFR 355

~ Appendix A. Thus, there are no Federal reporting requirements in the event of release of these materials.



### ~~~

### Page: 4

, Date Prepared: October 18, 1993

SARA REPORTING: Natural iron oxides are not subject to the reporting requirements of Section 304 of SARA, since they are not Extremely Hzzardous Substances. In addition, these iron oxides are not subject to the reporting requirements of Section 313 of SARA. However, due to the presence of up to S 96 silica - quartz, natural iron oxides are regulated as mixtures under the reporting requirements of Sections 311 and 312 of SARA.



## 12. MANUFACTURERS CONTACT REPRESENTATIYE Mary Nell Miller (404) 3824568

- 

### 'Ihis information is furnished without wananty, expressed or implied, except that it is accurate to the best knowledge of New Riverside Ochre Company. lnc. and New Riverside Ochre Company, lnc. assumes no legal responsibility for use or reliance upon the information presented.

-~



# ~

;•.

~ 

### I7lll ~

_ 

### \ ~ 

# • , ~ 

# _

`\ ..^_ • ``

'.~ 

# : ----. J.. ~
~

~ •
~ •

•~--~ • • /, ~

.. ~-

\ 1 , 7 1 O N 1 W 1 o O ot 1 o n O 1 O T N W 0` X :r:

_ ••+ 1 C.. E•• ~ S 1 1 O V 1 1

~ +► OV r • < p W
o ~ >- w . la. t-• N w o N Z h•1 IJ9 • C. W Ir r < O w•C OC O Y• 1 ~ C7 .s N -+ 1 ••+ O Q.` C1Lr_ ' ! GC • W

~ CL p.. J .w W<Fr.] w c. 1 N "- ~ t•• 1 r r 1 ! O , W 0•
~ v r 0~ 1 m ~ •'q 0 . cc 1 W 3c-9 1 • t r. ~ .ki 0 1 C. W 1 .7 ~ S
_ 11 f'! G'i

~ Z W WL"O O G[<

~ G N wbd— N<..i V

~ ~ ~ r .. r

. V i] :. ~ _.•r W 7C 4 Z W 1 V
.. .•. V !• OL ! Q. W~ r..r

~r ~ ~~~+ O 1 a. oc oc o ru • x s s/•, ~ ~ cr a r •e < ~ ••• r 1 V Z W O 06 W r 1 V7c'f 1•• ~ 'J pc.c 1 y ~ r O w r. ~ Ct

. = ••• W. W Ct Z W y OG ! 1 Z CL .! rr0 

# y C= = ~ o V ie s <~~ es

WiOL/

r •.iW+ i o

t+ lfa Z 7Si4 Z t ~ 0 Z rr V7 • W:ai 1 WO ~ s s t' )i X ii = 0..•r 1< O! V W OC u 1= V

f. W V <'SX..7Cy GC +.7 r W 1 V 1 r O Ot

7C ... •. V . W r i 4. Ot 1 H . t!f Ot

. X C>> t. O PC O N ~~ O 4.. O C !a7 .-. DO':7 O1 V•<r0 Y e•v0 Z fY r VfNC'f VV1 ~ +r O. If =W••r V = "7 W47:d }• 1 iOr..7U9Ci 1 Z V_G N V , NyN ~ wOi00Z

. ~ CxW i ~ 5 1 O G O

. < O f-• 11•1 Z


# ___ .•.. 1 GD f L1C Z o-•

~ 

# . r W O . ~ OO.Vr 

# y 1< Cr O ! Wr ~ 0 7 0 <. Oa foc 1 1 V S r

N 1 OWiW•ti 1 W w=YC! w, ~ 1 y r 7C7C! 1 r ~ 3=r.V..7 . V X C:.a00 S! 1 f W y '~~ 000 J 1 m = rp 1 Z O_ "+fa7 Oc
~ •• w ~ • i Z ii N •O O =•••• Qt OL aC •C • O< OC C'f r V 1< X L1C ~ . Z O :J V •..^.. W ~ lWNyr 1 F O OV ~ V . 1 ~ ,; ae s o -, VCJJ OC . >«.asWr 1 ~ v M•1 .. ~~ O : ~ { w •. ~ < r a ~ c ; m c' ~ w ~~ v ..

.. r ,-, o• o ° Ic c: ~ o

r e . ^J ~ ~ > O W z.0 v o e• 1.., 1 ae . ~ , W s ~ e t a W i }. =•-•S ~ N N C<04 Z 7 N o ~ O~ 1 O ••+O Z V i' C. 7C . ' 1 V

~ • 1•'1 O O S f 1 CC !+ .Z O Z Y • S •• O[ N•-• ! Gi r W O , r 1 ~ '.~ ! V •• fPl V ..]<

_ V O NZ Y <OW • L V • O YL i

= •• V ~ ~r 0 •f •C3fOL •. V.. ~ i/1 Ga O -••••

6 F • _O Z .. ..+• !
.. v ~ i ~ •-. f_ r V 2 ~ Z

F , 0+1ZL •• U ~ {.. V =r --• 4 ••.G'} W ..{i O 9• 2 '- N• O ~ i t!Y L U^

. ~ _ 4 ' • •

~ + G' ~ :i: Q o .-• S F -' — o • : r — :. ~ . . _ Q , Gn ... , CG :'7 Z F o C't V • F_— ~ o F V—FI-t+• , G

~ XS:..:x ••-•
~ c
~ ; , _ • ~

C :...1 ~ ~ LZ.~] _~~ Z

~ j UJ = L-06Z Z[••. O • - , ~ r~ C:.] 4. = ~ t

~ Ur••

~ e••
~ r+ 41

~ 7 F •-O OL fr0 f ` • .. f

~ •• • ~ = L L L S F

_ ~ •.~ O •-- 4 O t •-• , :r L ~ .- 1 ~ .... Y S { ...

. [-- -\ ~ ~. c..t O t-

. V7 ...: a 4. F :.. = f • :J i ••• _ •-•

~ 7 7C < < • Oe C 2 2lOZ= <O --3 w V C O L 7C L U:.7 ~ -~ S 6• ~ -• G L
. G O C+• ^
. ~ V C p ~ . Y, ~ r N j "f V Gl
_
- . • c^, ~ Cc CCV0 ~ ' ~ ~ — -" O J C ; i- - 5.

~ ..C.:7 Oc 24i O O • y4. , o F x s ' G ~ c.J — ~ r•••• 7C G'7 Vi —

. G ~ F t> s 7C s u Z , c~ O w u (/-•.~ < C

. K V

~ lY--• L O d O 1 O w :i -C ~

~
~
~

Z. • 

## v o
~ f ~ J e•t V ~ Vf v q • p r L ~ W • :.i • J ~ p • W O ~ V • J U J • N+ s t- s • t7 Z Z • r O

~ O ' + • i

O y U -C W y K J • O = 'Y •ff
~ C • rn vs U J O • O

- f y = y p • 06 q

~ .. •

~ { w

~ N V • W N G • O W ~ 1 Z X V J • t w F o 6. a W ~ W t9 O J J • OL .. +7 O O 'JD • O L

~ ] v vf J • f.. Oc 2 C'f L. e

~ .• i

0 /1 < G ~ ~~ • S G N •-+ W r z G Q l••• F O S p r ~ Y. G .-+ •• ~ 1•-• ~ C 2 4 — C - a•• O

~ 7 T• O c. ~ cJ ` 1 E- ~ t~ •~

2 •-•• Z ~ 4 C ~ 1 G ~

~ W ~ 

### •

~ w o Sz ~ V "' Z • C N Oe f ~ V• 1 ~ Z 7C ~ < q • o o ~ v c c.$ c► r W O C C ~ W Z • ! V i O N

_ • _f

~ C7 UY•. q G O

. ilif • O[ZJ OY O V G = . 00 r ~ ' W y O

~ !- O V W ~ W -• V W O S O F GC • ~ ~O = • N +Z F + G r•• W < q • q r q f N 6. J ~ i Z r • Q_ fr Z ~ V~q .O. V C

~ O..7 ~ I "' V S ~ W ~ ,Z Vf • !• Vf OL N r•+ N • < = ~ o s w ~ .. w • = ~ w tZV u Z ~ ~ q ~ ZZN ~ f ._ ~ N So- 0 ••t ~ A '~ O C

.

W .. t
~ G 2 N W ~

• O_ • QiZ Gt6 f .t Z i7 ! O •• Y ~ • ~ 'J' C J • qJ•C • 00[J N i

G H i OV4 q G O 0-3 C dig 06 • = Z!. •(.+ 6. L

~~ ' tA f W G ` W t
~ . < • O W O ~ O

~ i • N = S OC G .• ~ < .: o W ~ • t~ f ~~ oVO ~ J Z W GC • •.>i'J ro z • 4+ V G t tEZ otW• ~ < 0+ WMm Z O • aCff— f<f 7C ?• 4.
~ }. N i W.T. • O

.. '

~ i V_< 1-• •_f V W!C J V ~ Z • Z r Ge

7C • WfO.+ .CX O_ . < =4+V1Z ~q/• Z

. ~ OC O • V riY<W..7N ~ 01'!q OZN O O OC •.-+ a ~ S> J

~ 3, f N Oc .••• 7C J Ot .•r r N 4. 4. • X QVim S G • f x O W Z O

• O W < W f 7C • V V V W U Vf .r 6 W cc . f •Cqf<J=o+ O[ ; W fOGT ZW= - X ..7 w . rtZh•

~ •••rs• O c ++ rOa<f G •qNw pq Z• • tZWi<
~ 4. ~ 4. ZON ••qq.CZ G ~ O • C a-. .•7 q> G'f U9 Z • W w 9" O O f
~ •

i ••. Z

. ~ VZ>O t 00 '_' .•^ GO0 0 Z.. }' ~t f /f<~F ~ Z 2 • •••• G + i Oe L ~ J • N 0= ~ i.Jqr

~ i V w O

~ t •••f7 > •~ V1 WG Of..J, ~0.~ ~ i G ai F i VS JC}•0. W fOZO =r G i7C. V C0f. 1 7 Z W O. • ~ C a w C z • x w 6 ~ o C•-+ OC w Ot W >W

. ••f• ~ ••O>O= » W • ••. 'CFOGC VwZri.7 .•C9 OW 4 .W?. S[ C.9 • wONrt i'-Ci0 •

=YC = J ••iN ~ O wVN =i OL6.W 2 • ••+ZSZ Ot> >C ••G . NFZ o xou -. a +12 C N aC --• Y F- C—UC ^ -~ t'~ • 6:A d O t..• W :..1 w :J PC \ N t ~ ~ .~ C !~ N C •.•O ZY•--• W JN t'7
. •.•7C<N

~ .-.O Zt: X Z Z { p W U X V- 4 i 6 •- C L t L U C K = '•' ~ -- Y• U O W Z w p Z•°•• O C. ~ W_ C. ~ X S O {•-t7 F Oe ...FOUF O ~ O~ c•••ZYJ t-•.W p ~ W t» ~ 1•••

. C ~ t W W ~ y G
. ~ ...C.r ~ Z= .. =W _.r,:+ -r t> > N ~ •-• V••+ F C9 ~ <•-•• C7 ~ J E- O ~ O i. Z [...UC XK ..2=W7 F- <OC:...4•Y O'Jd ...: 4CF G 60W +> >OC.7 ~ x:-
~ c . xF•-CJ ¢ F4i L , ZYNU {x —s4 :..) r yC .•-• O i ~ ~ L - Y ^

~ • :.. :4 a... z > . v . . c.o r 

## ~ t/,. •}/!J ~

~ :3 <•~ • • OC • O Z <•••• V Z

o C ~ f Y ~ Z

~ + • < Y

~ :J1J V Or JJY O OC^i ` GL '+7 W V V J < K.X F• W f r W • 6 ~ N ~ -'~ .: Z i xOCr O f W < NV W 4 i r Z Z Z f i < 4+ V ~••~ f W OL ..] G O r C. O 6 i
~ . i..> 7 J O^J .0 F• r i•• N L.. O rr ..] 7C < f O •C = Z C_] = C'' C 'lJ li' W Y ~ W XSO Z_ Q . W ZC! Z> •Cr Z

~~ Y :+]

~ r OD O! •• - J t O[ V W OOC f :.7 <=- J Z= 47 Vi N9 - O Z OL N.r / f •- 6• < W ta. <•-+ Z Z .0 f r Z V•• i f Nf W 7i O < W Z Gc OC G

~ ✓ f C 4. .r O W ^. ~ Z W O o•• V7 ! r Z •C •-+ Y 2 "'OOW 

## e i'r

~ .1N . 0

7C C Z r-+ tA OC9 - ZWZ C<•JY ' 'C pG O NZZ L. - oc V O VO J V mC !-< ~ O YZ • i

~ 0 V y j~ ~ . V j V , 2-WW -ASr K Z ..]i.-. GcZr W 2_JY ~ o t•7.9W W Z W < Wft'f WWr N= r.Z 6• O 3[ i- GC Z 9••• Z W 9C f t W f O Z O p iA r O.+ ~ 04 OlOZ dNJ+:h7 <Or 4'! •C=f G•-+W .CZ < W S +1Z Z J O Z>.0 r•yNr V_ ••+ `+ ~ S>r VW VOC 7C SO•j C0=

- WCO ~ 0~ 7Gi r_ 04•Z Wr O i Z r•••.G 4.V^• ~ O

~ + i♦ W W fJ W O

~ + h. i 2• C W W
~ •. f_V U7 t V f ~ aC '• J OC r = = O O •C O S!•• td =

~ i •O ~ 7C i W < 7CN ' ZJ =OC r V

~ •• O[O < CO OlO+i ..4V J = .+r0 N < O ••+ ta 7 rW < O '3 Z J fr. W r-r

. ..i OL Z N r J V _\ • Ga > Vf = U! GL ..3 ! i GC W O N .0 W Vf = i Z•••• ••+ tPl w O i' !•• W WZ 7C0 at+ ~ O O 410v n Of0 O OaO. JZ ZZO 0 = •-+W i s Z • 07.•^ ~ c.LW zr 4•LL Wo on• ~ +7 41Zt'1

. .7 N_ W < =O!. OOt yJ =7C•-• i0 f7 f>_ < O S Z
~ •• O 69 N !•• .! O i O Nf O Ir

. < S r JZYt N O.
~ i

W^C1 O.

= r ~

n•~ .! W J

OL 2 W `~•~• WNW L=

=7C W N

m pfit ~ Oi n = ~ <N •-+W

~ r o r V zOLr voC1 o•C OfkR oW W49t r :ri V i <•Ci OLr+ V= Or 6.= G970 Oc N

. ~ c Y 7C 'J+ J 7C < J . N. G. Z Ot O

~ 4•• = f O^ J 7S GC K 0 •••• r•7 Z 4. Q1 O = d W r V•+ h•,. W

.. '1

. W = Z CX .T+ OC (A J O < tlf W = O!• O ~ V1 ~ • h• V S N> .r O •••• Z O O W 'L W W rr U. W 7C Q CI C Oc f ^009 CWa•. = f S<O[ '.•+ri fZr =Wa••• YO Ob[ OW WYOZ '+1 < W Cle r O r CL• 0•• Gi O = s-3 o V W J Z C ) Gc W 1 ••• 00 O< +- v+ o aa oc ~ oe c J - < o r A. W. s z oc z — z <- W a in W c

~ Wr 4J0 'S cNr

- zi rJ + Wo GO IA C

~ GCJ< W> <'l t ~ f X Z V W - r+
~ •d Y o!. t ~ o <.+ Y O s z s v W n• ••. o.•r :d .••. d z O o [.i OL < J Z W C.0 .•• ~ W W r .-7 7 '+7 t:d 7c V p ' O Vf V ^ OG fA CC > f V S GC < J V ta7 Z W O. ~ •~ CksSrO p y ••Vd' WWr .4< r H Z.L

~ ••• • OL iV Wpm flNC

~ YW VGCW Nt•• W V1 .a70 rr + t ~ • ir

~ r NWr VO 0 69

~ GOt Or O^O J CfdG•W <W< W< t•: OSVN + O Z W'L +: V=CY afZ < ZVf r Zi=!' • fNr OG• •CCr+ .T. .r • fC9 V90J V70>f + WO XGCi >_ »O•! r W ^! WG. >:d = fZVf GZ .C C..7 W.••WH 9 ~ Oc G. W! O d:V W = O OL • .i O =>>• Vf O O O r••• r i.••• O

.. \ ]fJ ~ W }• pC O.VNO. GJ }• V = J OC<W O.y.Y..0 Or t

~ . O T. 49 O 2 Oc 7C 7C J r S O W " •'+ J J O ••+ CJ W f W Ca 7C O tX f r•+ W O U! Vf 7C 2t - <=W

~ l•- WW pOe-] OYC.CS ZiW YZ Zr ZW OY< O.= r i \J

JCOi ••2 VCYC '7 Vr r V! O =O OYG C7Z :AO= C..+• V W O SW • Va••'< W r. Wfi' WOZN i f Y> Or _W •• •_••+ '.'] Y• 4J

~ e ... p = W O=.••• O W !-• ir r O . = W N .-.. OG V J O Z

C.: it F ~ Z C•• T• Oe W W G .r Oe W.+ 7C r •- Z Z 7•• OC V ~ :a. F Oc .• e• ~ .`..

~ Ge ~ O G.S W X:..iO
. ~ O XC Z.-. •-. W C.... F-+ Z:..10 •G_ V9 ^ aC O.•• =1= C^. C<V 7C O YN S Oc O--•<L t •G>O CCOZ--
- ' 7C - O }.. ^» O L O = CO tnYG F C 0000 :..; . ,.;..: Z L U c.: C[-- .. ..., i y ff1► CL 4: N G. K.•7 1 .-. •¢ • G x V] M. f U.9 7C v ~ ^ ,,: V C a• _^. C

~ :..: L F -- _ ~ O•- 7C = O •• ^ O X X•-• t •-- L Z "' O X ~ F.= 2 Z ..+ Oc U k- :,-= V > W "- '_ f..rG.W dv rOCOZ V6. W L. O wW OWX

_ ••%_ = =->- 4•-+O X a O V••+X O- W AC O 6- - S= Vl CL. L\C L ZCC 004i F••••' F- WCcV C V^- < :.7V C04l ' f-- F W V Z G6F •• OFO ^UZ

~ ta:iGt Z 7C Z Z Q.•..• r3 ZF• h•7C ^ ..••-•: OLZ G3 Z

.. r^C W-j G 7CG=<ac ...: YL': ,J t f: F O C.-• W W = < W.Z •Z O W Z i N... .-. C.-. f W W= N .] OC O ^ Z G= C ...7 F Z O 6 G

~ + O--f--O « f•id •-•N J f O< atr O 0+1J r4.r+4'10

L F-- _ ~

_ Z i C O-

~ • - V=O'Y F V S 47= W C t- COOC2 F=Z V .-:O 4 7 V Lt^. !-..O "3 r•G= cc i!7 .•+•t V 02 .: --<V s•-.[ F'+-+: F C.[:.=>= ~

K= OL .•. Y S •••• ~ cL - Z= = c: r C • ~ tfl C •• ) f W V V. CJ H .r 4!-• 3< V C U^'
~~

a ~ a :•i ~ i

0 J O t O J :.i <

. ~

, +

2 , w • oc '

. • . w '
, z .. • r w a • .. a- o. . . o 

## y t ' ° 3."n 

## o ~ rN a' A° o = r:i 0 : : ^ y id OC : C! W ° Oi : : J h V i

~ . » ra • s ~ s r~r~ • . cu z



### o = • Met ICm • • W ~ z ° o ~ 

### oo ►+♦ ~ : : °` 1 > p >~ ~ o 6 ~ ~ Q ~ 1
~ / • •

~ e, v • ~i s~ . W i ~i
. . N

~ M O~i~ H ~ o ~ i : } SW C~ p y ' r i •O iY•7 N < ~ 6 tf Z p O !

~ p Y...G ~ • e W t ~ y ~ \ 04 ~ J Z

~ " ♦ •

• .

• V V Oc Z .. < •

• a • Cp OO i .. ... ~ r 7 ~ z p ; ; ~ 

## c W ~ i i i ~ N • r • O • di V FX x O t J !+ ^ Z f. fG w O

O. , :J C1 t t9

.f. S

V! i~ G i

Vf t• S . O • V ~ • ... .t i i y V 0[ , W W r d fA O 6f . Y •.! •$

• Q J P Z i ~~OZO~ OV ~~ •° dS

O O

r W 0.

Vf ..7Vi JNOn. .•

• O • fb i ` Z J V y ' .•• ~ ~ 1 i • F . • ~ s SC Ot ~ '= (j ~ i. Z ^ L

l i7 ~o~ !°•• W ~ G S V •

• i O G9WV • •< . w sW J r~ M.

~ `jo

~ V ^O t M M N oo • Z

i< Ov !+

N . • a~ f., . O♦ N . y • S • J wF

J.t Y OC d p ~ ^ ! ~ ON J t• l 

## a O m y r !.••• M • O

• r •

• O V r. l y 0yi j ! r c Z .i Z G aC e ~ ae . ._ wrOfJ. ~ N01 ...1 . t :G ~ i :.7i.i♦ =^ a ~ C
.. ~~ t

O.
.. '7 w w

OI VI • Ot < y W •+ 9.2 CS

.3 ~ ti

J f+ •i • O s

.. 2 Q J

i.a O L7 y 7C 14 ~ .T. .+ F i• =N ~ O

!- V1 * AS m W !d ~ o .-2 r•-. > m_ .•. w w o o♦ w , y 1 •• N! r z W ~r+<et • V
. a r-, 6. ~ dswJC7 x i 70 • <sz F O F .t JtSf•. . • •

• y Oy

VI C9lt Jm^W 91NF10m

~ Y N VECt^ C. rVV • . 9G♦ O O tf "' M •• .'r F' N O~••• L' f. 2 • • S y 3 .]N6 ••W

W Oc J :!S 0. 41 O O <O N[i `t• V at C

LJ dCCO

O LJ R-w •

.,. • • •.7

.. ~ ! ..0 0••yM

~ _ zC— r r-.. ~ c• r rC cr'f .•. O ` 2 O •-• ` r. Y .
... . e• • ~ d

(i ~ Gc :.J .. 'i .•• W Y- ~ f p .. 4
. I .•-• C i.. :... VI J•• = O r O • s Z O 2 L . aC O••••

~ C .L .•. . ~ O

~ a 1- 1C OOtA.•+ ~ tv •6_ 7L i! W i • O t1 S _ 1•• ? • 5 N 6. Z 

# ."._

~ ~ 4 .~ ^ F '

~ 

# ..... ~ • 

# •

. 

# •

_ _ 

# ..0•1 ._—'-_ ••

~~ — f 

# ^.' . _^ —__ •• Y[ d O ~ ~ • 47 ! CL J O r Y

.. ~ id 2 • 69

. 2 i

~ •.•.L

~ l , .7hi O O U'1 N0 i t i • t- • O

~ ~ s• - ~e ~ t ~ 2 ..••

. . . .. . N • • O - ~

. . Y
~ • S

. r = .••• O

~ OJ ci • 7c O • .•• 6 _

F- ~ i

-- . Y•(..' F

~~ •• O == r."i W J.

~ .i F• oc Lr• ~ • . . _ /~ /] t.j ~ = o J.... - x x O

-~• O G[ V~ •• r~ . G. JN! :.~ -

N > O
~ •iJt • o.i V W H<

.. ~ tNx

~ .! Y7

. m4.2 1.. t
. e] • u Y r=~ 

## 2

~ w

~ 4

. ~

• 3 ~ W • > • ~ f •~ . f • O A. LYO C,L w V9 Z C O

Zr Z40 V ~wR. OOC•C N S Z 0. OOL r U9 6= f W o 9- _ O ~ O ►+ O .+ 6 Z= .+ S w r Q

V t U7 C fC~' 1•x^ i Z Z ~ W U. •~•~ O .+ i W w J ^• O Z FH w w s.: .j ■- a. . Z n :. ac w V oc Z V < .[ 3 oe N =rZ >a<~. Q C O < J Wa 'c 4ie .r W WZVf f =Wf WNN< ,,,, - .r O~ OL. J W = Z /•r ~ S S.•~ 3 ~i G hi r f V W 6. O N Z V Vt CtJVS • < N

... f-• 0►+=V WT M < J WO O~W .-~ w o G. Z ! s J .••~ o-•• .r 4. 4. W v r. ►r W < .r o r 7[ .-. a C. w o_ w_ z t w Q ~ . 'i i+ ~ ~C f = Z w G. 7C i.l < a
, t!f WAC O. U. r G1 S W ►+ Z w w x C r t~•• ~ 1.'f Q .0 O X < r W t/f a V w Z OC O~C N • < r O • V O < S V ' O O Q Oe C oc G C•••• O •C oN zw •! ~-a fr1 - r SJr < .~ a i+ w o w0 z X N ►r_ .-+paZ J t+ •C 4 i+~►+w ~ < Z N COO fJ ••+ OC V. 'i w GL K ►+ w J L7 V t~ 0. Z Z 6 if! f'.i v .Z ~ • .Z = ►'• .Z ••+ J W •r ! w J W W r •+ Vf 0. f Vf3 t a t+ .•. =Oe V2~ W ~ Vf 7'

. Z.r•• 0 0 N O Oi N'f GC GG :J O r• L'1 • Z J w 3. W.-• OC O O WOCO<rw tA0 wOtO
. - W 4Q1 O<G.V+Y VJOi ~ < f w" OCW~-.ai rt ~wV O <W 0.W O. a Jt < ~•• r< O[ i S Ot !+ I W Q O

_ '> Q y w - W .0 Oc .0 w J OC Y i O W-3 w Vf V O V a ►~+ OC V r-+ r+ V 0.~ ~•+ V - .3 N < r •C 7C N .L..1• W~p~ OrwN a 0. w Ww0+1'0. <O WwW O Y.•+ w p J ~NO O~•+M= ~ ~C Vf 7. ••+ Nw<... =Z ►+ N O Vf :Vr

7 w O 0.w W r j f! O.w Oc 1-0 •-7 ~C < QO OZiA VNG~si+.•• •• ~ ~ V ~ wfOtV_C~ = Wr ~ W t0. JOGG 0. O V.0 r < O••^ 7C O o • ffC = O~ V ii z Ot Gt W pL = X pQ }~-. O Oi t•~ f" tA O - ~ O <.•7 C~ 4+ •-• O O Q < J 0. Z f 0. +• N 0. ~a WOW N< V ~C <0.rS ~.. i^' w7,+.,.wS61 r wOY •i w wa oao<r ►-~ < ~ ca.•Wi-< .e~ • c~~~ o Nx .eoc< _W Z ,L, '~ ~ S~ G~•z•~ = N .-~i r-. r CY t }. O~ J.r •< OC O[ Oc J r. • r7 r O.

i q 4,So.•W N, Jr~SWr p J~.+w Y r0 N i C9 ~ Y_~O f~3J '-' N 4N1rN0 O~iC N f.0.<OG..V.iCiA A. i=~.d •t~< M. [.J7 OieOC S>.Z-• ON =.~^J VlQ« w f0 7C 7W =W N OC Otaw a W 0.=S W W W 0.V f t0 _ ^'W J S< 7C W O= f V1 Oi Q 0. Ot a Q pC OC Gc U! < a r f k+ G

V f W w • V Y ! w 6 V Y W •^•• 0. O t~•+ < O GC Q TG r O ,C V! N9 C OG Z OL O[

. '~ .. V OL Z LL GC 2 V O < Vf w= W 7C 4 w . W w rC = f/! - r ••+ 2••a Q►+ u•• ►+ C ►+ Z W W < r O PC f W re~f .'<
_ =iG<.0 -C < YW<Z« t YWr T f.>S 0.R`W < w O Y•-. V r W N ~ tr ~ C►• ••° •C r . Z W.••• < 7C Z W 0. a J9 Z OcfWOWY J G QtOZ ~ O V~ ZO O.-+ ►+V.-• r. ~G 0~00 •~W VOtJXSH CO Z Z7CWp ^ .~ W OG.+OWOW W GGr+GCN ~ rW WtA ~f• O tW fW O < i~ r-.V w f•. OwwVVr O Ow0.0 OC fw <SZN N tA •-'G.iAf• w J MJ GC ...i 0.•r.00w • 3 .JW a4,Or W <OC GGf.+W W Q cr r tr m Vf Y• < O f f"' W a C. W OG a . w w r w O. a F• W OC < W:J ►+ O im >= OZOCOCOmN ~ N NraJ S WG. OC . 2d.3C.. ~.i 01 0.0C 1- LYfP! O. r17. f W•-.c~OS r > >OC= W or=47 ►+.^.pW W> >CS41 ~•-~Sa< O Rfc7 Vfa2 f O w ••+ G G.0 Vf N 0. J 00 -C V C. V C9 {A V7 W Q ri C1 •C 6. W w 0 0W N Z Oc r O< • W 5~. ~J r O ►+ .0 i3. O .r 96 O O OC OC JM-- OW CL• .. CiW>r o Y 'O~Y ~wl+: YSYw>•f~ Yo7C ySY< ez a~NO•• cios " z z z X zz z z < z_ S O. 41 G. O --• G. -C OC ~ i -C It t ~ < .0 i < t .t •C < t ►+ .0 ..! ••+ :--c.-.. f..t t.7 Oe L'1 .j O. W . C~ < < 7C W U9 L.7~ oCOG 7c 470..G. ~• ..7 ~ ~ ~ . . Z F~^.. W Vf0

OG 6 t-• 6 r+ r+ e-• r~ r~ 4.: .••. '~ O O S ht F 7C = = 7C L CL F O~ 47 ~ f• ••6 2 VIZ V-7C YO ~+% \ \ \ \ G V.^-. -+= 7~ +_ V Z

.. ... . o• -+ O ...1 Z = ~ '^ .-. .•. i. V U ~: ..] ~ 4 ~

e~. :... 3 F 6 Oe O[ C Ge CZ C'f ~-• l-- L C-- _ Fr F E-34: V -V :.7-"• L ~ G.7 G~~ O O •C ~--• Z ' V ~ v v ..V. Ia7 4. J d •` w.t .0 J Z r~ w S O F C U C7 U U C.7 Cr v7 +7 C'7 4: X ocot-xoo-F-~J
.. ac F ~ E- :... Y• .~ t Z ~.3 :..1 O ✓ f

c-1o~n •c ~e ~ ~ o w 'o Z~<c :~: cm c.j c..: > 4> O J

~ 1 G
V 

### i

0 O d•. O S ..i :3 <

# =

y 

# N i_

O Ot
.e p N S O F W , 

# 14

_

~ 

# f o i.

~ 

# _< _ f a' • - a r.i o :J ~ . us
~ i` C F • Y O• W 6=

~ l+ J3 Z C y d ~ 0 .7~ .\-. 

### m ~=N~ V i c ~ S 7 .•

f •+ ••+ = y :J W aC \ Z G V Z ! O • ~ :Z Of

~ N O J W 4 W W O CL ~•-~ w 1 N 0 _ ~ i+ O N f~ +S W

f W W

ONat ~ N ~ ~ i N i.• ~ C! Ci 67 S ~ L.
~ _ > OY• C W=0.ZW i O h O N hO ~ .Z •Z ~ 0._ W.• = •.H
~ = •+ '

~~ ~w N Z

~ •.JO V it r Z •.N ON'L'

~ _ +7 i ..i S W

~ •. h O Ot 07 o
~ n =F > M r.0= ~~ lZi.:NOC7C V ~ ~

A = C i W07 W N W N Vf Ot tr OWZZH ~ " f

~ O ~ W > NscO

O .Y L r+

Z wh0 0

y
~ •-++ ~ •

. = ••O i c = tV.

~

.. O t y rf V ~ ~

!-• t

f 'f Y..

0 .7 t ! d W ..! t ' .i ~ t!

O -~ O

~ . ' 06 OL V .0 V N!+
~ ••, O. G N i••. ~ j,. ii5.! O XiS ~ J2"
~ N O OC N

~ t G[ .••• W O< O O LL

AC p ~ -. W G[ W ~ h~ i h Oc 7. + L= Z6 =O OC hOs W 4.W 941•^= N\ OOWiWti w V W O V Ot O ~ O *- ..i Z= C9 ..7 r ~ f oZ W W 4.o i o = — = !O t OC! SWI" w ~ OiOtVfht ~ n.f !-•Vi WJW VffAr L9 0 c y I N Zr.. r ~ .r y < W t•+ S m W t O O W! h > OL O~ ,G. Y U:O OahW W r>OCrI.'
~ < WN = 4i ..7! =^4 CLOC L 3N ~ C-o z dc ~ s~~ oe< mrzo=oc c < 6:... N o_o J.<LS— •cO t+: 0e1.. s.^!S FZ ~ ZY Wo_CeF i~ -:•. ~ w= c= 4— Zoe sca Z ..s_F sF_z r- osr`oca

~ c a Z 4 --• = t- -r ~ O

G

- ' OFZ C+10 FU FFtr :n N Y F F Ot C -J ! = f = • U]C U O 3 ~ J C7 ~ ae O Vf2

~ •fF[ O i.7Cf "tj 2 O 47 Z Z O••+ Z 6 Z Z 6 •.-. T•-:.1 C

~ Y 6 OCl.0
~ C ~ =6..-.0 S

CD t- 6.OD F ~ L OG ~ ~ ..i t'1

OS O -3

W 4id ¢ y7 2

41 t'7 ._.

# A 16

Material Safety Data Sheet

AMERICAN MINERALS PRODUCT: 

### 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF PRUSSIA, PA 19406 MSDS: AMCHROMITE 

### Phone: Health & Safety Info 215/337-1100 Date: 1/4/90 Revision: 12/92 HEALTH HAZARD 2 - Moderate FLAHMABILITY HAZARD 0 - Minimal REACTIVITY HAZARD 0 - Minimal PERSONAL PROTECTION B- Glasses & Gloves 

### National Paint and Coatings Association Hazardous Material Identification System

SECTION I. MATERIAL IDENTIFICATION 

### Chemical Name: Chromite Common Names: Chrome Ore, Chromite, Chromite Ore, Iron Chromite, Iron Chromite Ore Description: Chromite is a mineral composed of a natural oxide of ferrous iron and chromium, with varying amounts of magnesium and aluminum substituting for the iron and chromium respectively. It has the general formula of (Fe,Hg)O•(Cr,Fe,Al) 2 0 3 . CASf: 1308-31-2 

### Distributor: American Minerals Phone: 215/337-1100 SECTION II. INGREDIENTS AND HAZARDS Ingredient Name: CAS Numbers Percent: Exposure Limits: Chrome Ore 1308-31-2 100 For Chromium (III) Compounds as /Cr/ ACGIH TLV:TWA is 0.5mg/m 3 . This would equate to a chrome ore dust exposure 1.62mg/m 3

for of a chrome ore containing 45% Cr 2 0 3 . OSHA Typical Chemical Analysis, Wt.t PEL:TWA for Chromium (III) Si0 2 1-5 Compounds Final PEL 0.5mg/m 3 . Fe0 15-25 FOR ORE PROCESSING 

### - ACGIH A1 0 3 10-20 TLV:TWA - 0.05mg/m . For ore Mg 

### ~ 10-20 processing, chrome ore is Ca0 0-1 listed as a Human Carcinogen. Cr 2 0 3 35-45 

### The oxides shown in the "Typical Chemical Analysis• do not exist as free, uncombined oxides, but exist in complex mineralogical combinations.
I SECTION III. PHYSICAL DATA I Appearance and Odor: Chrome ore is'usually bl•ack, but does show some variation from iron-black to brownish black with some brown streaks. Various grades can vary from large pieces down to fine powders. Chrome ore is odorless. Apparent Density: 4.3 - 4.5 g/cc. (37 lbs/gal) Water Solubility (t): O, Insoluble in Water Melting Point: >3400°F % volatile by volume: 0 

### _ Page 1 --- MSDS continues on page 2 --- Page 1 

# 3orMaterial Safety Data Sheet A1IERICAN MINERALS PRODUCT: CHROHE ORE 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF PRUSSIA, PA 19406 MSDS: AHCHROHITE Phone: Health & Safety Info 215/337-1100 Date: 2/14/92 Revision: 12/92

I SECTION IV. FIRE AND EXPLOSION DATA I 

### Extinguishing Media: Chrome ore is not combustible. Use extinguishing media appropriate to combustibles in the surrounding area. Unusual fire or explosion hazards: None Hazardous decomposition Products: None
I SECTION V. REACTIVITY DATA I 

### Stability: Chrome ore is an inert and stable mineral. Hazardous polymerization will not occur. Chemical incompatibilities: Chrome ore can react at high temperature with molten alkalies and alkali vapors forming water soluble chromium salts. Storage: Chrome ore is stable under all normal conditions of storage.
I SECTION VI. HEALTH HAZARD INFORMATION I Summary of risks: Exposure to chrome ore presents a low order of risk. The primary health hazard is the excessive inhalation of dust generated during handling operations. health hazards such as: hexavalent chromium compounds produce a corrosive action on any skin and mucous membranes they contactp chromite salts are human and experimental carcinogens of the lungs, nasal cavity and paranasal sinus, and are also experimental carcinogens of the stomach and larynx; the hexavalent (VI) chromium compounds are more toxic than the trivalent (III) compounds. Eczematous dermatitis has been reported for some trivalent chromium compounds. A competent industrial hygienist should be consulted for evaluation of potential health hazards associated with specific chemical processes involving the use of chrome ore. Nedical conditions which may be aggravated by contact: The excessive inhalation of mineral dust may aggravate pr.e-existir.g chronic lung'conditions such as, but not limited to, bronchitis, emphysema, and asthma. Target organs: Upper Respiratory System Primary entry route: Inhalation Acute Effects: The excessive inhalation of mineral dust can cause a transitory upper

respiratory irritation. Chronic Effects: The chromitl:n in chrome ore i.g in the trivalent (III) form. Trivalent 

### Chrome oxide (Cr 2 0 3 ) is repvrted tb have a low order of toxicity. The IARC - Cancer Review: Animal - Inadequate Evidence. Chrome ore is listed as a human carcinogen in ore 

### processing.
Page 2--- HEaI.TH HAZARD INFORMATION continues on page 3 --- Page 2



### 3~'~z

### Naterial Safety Data Sheet AMERICAN HINERALS PRODUCT: CHROME ORE 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF PRUSSIA, PA 19406 MSDS: AMCHROt•tITE Phone: Health & Safety Info 215/337-1100 Date: 2/14/92 Revision: 12/92 

### I HEALTH HAZARD INFORHATION continued from page 2 

### 1 Signs & symptoms of overexposure: Eye contact: Physical Irritation Skin contact: Possible irritation from repeated or prolonged contact to

individuals sensitive to mineral dust. inhalation: Upper respiratory irritation. First aid: Eye contact: Flush eyes, including under the eyelids, with large amounts of

water. If irritation persists, seek medical attention. Skin contact: Wash with mild soap and water. Inhalation: Remove to fresh air. Ingestion: No data available.

SECTION VII. SPILL, LEAK AND DISPOSAL PROCEDURES 

### Spill / Leak procedures: Chrome ore is unreactive and insoluble in water and acids. Reuse all spilled material whenever possible. Thoroughly cleanup spilled material and place into a suitable container, being careful to avoid creating dusty conditions. If conditions warrant clean-up personnel should wear approved respiratory protection, gloves, and goggles to prevent irritation from contact and/or inhalation. Waste management / Disposal: Chrome ore is not biodegradable, and does not exhibit any characteristics of a hazardous waste. It is insoluble by EPA's SW-846 TCLP methodology. It is suitable for landfill disposal. However, used debris containing chromium must be evaluated for the Characteristic of Toxicity to determine the method of disposal. Follow all local, state and federal regulations for proper disposal. 

# I SECTION VIII. SPECIAL PROTECTION INFORMATION 

# I Personal protective equipment: 

### The use of safety glasses, gloves, and long sleeve clothing is recommended. Workplace Considerations= Ventilation: 

### Provide adequate general ventilation and local ventilation in both sufficient volume and air 

### flow patterns to keep air contaminant concentration levels below allowable limits.

Page 3--- MSDS continues on page 4 --- Page 3 

## jU•j

### Material Safety Data Sheet AMERICAN MINERALS PRODUCT: CHROME ORE 901 EAST EIGHTH AVENUE, P.O.BOX 1569 KING OF PRUSSIA, PA 19406 MSDS: AMCHROMITE 

### Phone: Health & Safety Info 215/337-1100 Date: 2/14/92 Revision: 12/92

I SECTION IX. REGULATORY INFOR.MATION I SARA TITLE III INFORMATIONi 

### The product is 100% chrome ore CAS11308-31-2, which is composed of up to 42s Chromium and reportable under SARA TITLE III Section 313. Chrome ore is included because of definition given in 40 CFR Ch.l Part 372.65 on chromium compounds. Chrome ore is not listed under SARA TITLE III Sections 302 and 304. TSCA INVENTORY: 

### Chrome ore is listed on the chemical Substance Inventory of the Toxic Substances Control Act (TSCA). 

### DOT Class: Not Regulated SECTION X. REFERENCES Sax, N. Irving: Dangerous Properties of Industrial Materials, Seventh Edition, Van Nostrand Reinhold Co., Inc., 1989.

### Kirk, R. and Othmer, D., Encvclopedia of Chemical TechnoloQY, Third Edition, WileyInterscience, New York, NY 1980. Clansky, K.B., Suscect Chemicals Sourcebook, 1992-2 Edition, Roytech Publications, Bethesda, Maryland. Sax, N.Irving and Lewis,R.J. Hawlev's Condensed Chemical Dictionarv, Eleventh Ed., Van Nostrand Reinhold Co.,Inc., NY
I SECTION XI. ACRONYMS/DEFINITIONS USED IN THIS MSDS I ACGIH: CASif: IARC 3 mg/m : NFPA: OSHA: PEL: SARA: Title III: 

### Section 302: Section 304: . Section 313: TC Rule: TCLP: TLV: TSCA: TWA: American Conference of Governmental Industrial Hygienists

CAS Registration Number is an assigned number to identify a material. CAS stands for Chemical Abstract Service. International Agency for Research on Cancer Milligrams per cubic meter National Fire Protection Association Occupational Safety and Health Administration Permissible Exposure Limit (OSHA) Superfund Amendments and Reauthorization Act Emergency Planning and Ccmmu:iity Right to Kr.ow Act Extremely Hazardous , Substances ~ Emergency Release Toxic Chemicals - Reporting Toxicity Characteristic Rule Toxicity Characteristic Leaching Procedure Threshold Limit Value (ACGIH) Toxic Substances Control Act Time Weighted Average = 8 hours Prepared/revised by: A.G.Nighswander, December 9, 1992 Although reasonable care has been taken in the preparation of the information contained herein, American Minerals extends no warranties, makes no representation and assumes no responsibility as to the accuracy or suitability of such information for application to purchaser's intended purposes or for consequences.of its use. ` Page 4 --- End of MSDS 

### --- Page 4 

# 3~ ~

# I 

# s

. ~ 

# .I

., i

--~ 

# I ~ .uuv- ruX,l TO 82-14247241369 P.02 _ •s .

; • - `

. 

### ftIl1 IXkRWa OaCp11"

, 

# BsCtion Y

~ 

# produot,Iftttification Ths Godrqia Xarblo Comisany 

## 1201 Robsrts $oulevArd Huildirbg loo - Xemdsaw. GeOrqia 30144-3619 FSdSryarncy Taiophono: (404) 421-6557 ~ 

## 3tannath .J. Maake 

## Rf sk D4ansq.r ~ 

## Chomiatil Name: CalciWa Cdrbonata Chamiaal Familys 2ssrblat Limtstonot Dolamit• G9 Numbers 471-34-1 Trade Name t Plus 5 

# A r-a/ sBectiors 11 - Has<ardous Znoradiant,s

~.~.~.. 

# ggsardous Matorials 

# __ st

Idantifiaation ey em 

# . Haalth Hasard 0 !'lasmaability xazarQ 0 

# Raactivitiy Hazard o Pernonal Frotaction s 

## Hazard_.. Inci.dilats TLV L,x•qL: 

# 6ilioa, Quarts calcium CArborato Dust .1 (Rospirabls Dust) 30 (Nuisanc• Du*t) Calaium Caxiborvate may cantain crystallina silica at lwe3.e 

# bstwson 0,01% arld i.M anQ varies natvrally. 7*ha" ara algo small but datactabl• amounts of ths follovis7q 

# othar naturally occurrinq aheastioals thaC are knawn to tha etata of Caiifornia to cauoa aatioer, birth dafsats or , otbar rteproduativo harm. Rhis warni.nq is p 

## xroviaed in the absonca 

## of definitiv s tvsting to prov 

## o that theao ri.sks do tsot 

# oxist. Thoso amounta aro typical 4uantitiss and may vary r aliqhtly With differant lots. 

## Ciiamir,al xame TYOieai Amount .' 

## Ca$ Numbar 

# llraenia Lesa then lppm 7440-38-1 Lsad - Lises thaxt ippm 7439-92-1

~ 

# 3~~i 1 1 36 FRah1 GA MARgLE - CORP tW TO 82-14847241369 P.03

JLN-0'7- i 99 i ^

- a ..



# saation ZZI -

~ 

## aranca ar ~ 

## d odor: soili nc Points K/

~ 

## 1 

# Vapox Pressurss N/A Vapor Densitys N/A solubility in 14ater: 

## phyAica]JChemical charactQriatics Fins, 4Ih.l.te Fowdsr s No Odor



# Specitic aravity: 2.71 I'Vaporation Ratet N/A 

# sIiqht rsalttin4 Point: s ~ l 

# N/a

~ 

## gaGtion i

~ 

## V 

# - Fire and Sxplosion Na$a



# - rd DatA Flash Points N/l► 

## llammabia Limits: it/A Firs Exti.nqvishirig Xedia: N/A , 

# spaciai Firs Fi9htinq Frocsdursas Nona unugual Fira and bcploeion Hazardss Norie

sootl.on _9 - RaaotiYa Data

- 

## Thia material is stable. Thi ~s~ 

# matiriii t will ~ 

# ot polyim
~ 

# iriso „g ac ~ 'ds to libarats carbon dioxide. Muardous Deacartposition Sy-Produ.atat Hons

SActian VI - 8salth llaaard Datta 

# _ Calcium Carbonata is riot ott ths N. T. P. , Io A. R. C. , or OM 

# liats of aarairoqans. CrYtitaliina sil 

# ica a t 

# racs c aupo 

# nant cara Caloium t Cax'kvna►ts imettital animals listod



## ha ~ d 

## ia
~ 

## ti aa 

# limit ~ o 

# evidance s t~ 

# caroinoqQnicity to humana, howsvs
~ 

# r, wc has dat.srmised that ths caroirncgenioity to humans is naither cartaitt or provar:. 

## Pmlonqed rspsatod it>hAlation of ox
~ 

## ystal

- line siiica oan vausm sillposis, a norlaancerma lurjq diasaso. ESCDOsure: 

# Inhalation: b'y ~ 

## tbntaat ~ 

## • gk.in Coritact: Zt
~ 

### asticnt 

# Can bs 3.rritatinq to

Kild irritatian. !Io af taat. 

## xinimal .ffact. ths x'aspiratory tract.

Firat Aid 

# Z a at on: Remov lkom aroa ot exDosurs and to tresh air area. bys Contaot: llush eyss with wataz tor lo minutas. rt irritation

persista, obtain medical attantion. ekin Contact: Waah fr= skin with mild aoap and wata.r. SnQeatioon: Inqastion ahould not caua• any sicmificant health



## problema. 

# ,36 b

### _ _. .....w.. .,.. ~ ~.~ 

### iu tfd-14e47241369 . ..P.Oa ..



## Sa`n y2Z - Apiil or Leak Progeduras, 

# spiil or Laa}c: Respiratory protoction should bi rrorn durinq claan up

to protect lrom airborne flust. Measurss should be taks.n to rraduc.e airborr» dust durinq ciaan up. Wast• Dispos.al: Shovel up matecial and dispo 

# ~~ 'o 

# ~ a lxai f ili. comply 

# with applicable ledaral

, 

# st.a

~ 

# requlatitons. ssction V'IYI - S,mial Prot,rction 

## R.rupiratory Protections X208H/o$xAA4M approvad duet t"pirator i! 

## T.L.V. i. 4xo..4eQ. Yentilation: Lxal axhduott ~ 

## Ar requirad !or dust to maintain airbwne duat beloa tha TLV. 

## Mc.hanicalt As raquired for dust. Eya protection t Salety qlassotr or qvqqlsa. 

## 6pecial Prbtectiont None t•equired. Dete Frepaxadt ~



## 7une 7.- ].991_ 

## Fnperid by Safaty Dapartment



# ~

. 

## I

.~ v~~ . . f ~ l c ni . ~.;~ a~ ~ ., . c .a ..... 1 .-., •, . . . ~ . . .

` • ` 

### ~ HATBRIAL SAFBTY DATA SllB{T l ~u~ 

### Ceraei Color t Cben cal 1lfg. Co. 13tD 

## ~ Greet i 11t11 

## ~ v 

# e aue 

### Ney BrigIlton, PA 15066 (112) 846-4000 DATB: D10o. 3 1 1991

• 

### SSC"tIOM I • IDBHTIPICATI01 PQODOCT: 1513 C861fICAL NAKE: NBTAL OLIDt BORNOLA: Co Al204 CAS 10: 66166•86-I

. 

### SBCTION II • HAZARDOOS IIiGRBDIE9TS OF MIITORYS ABDI81iT }XT . PBL- jyY-Ji

~ 

### ` ,18 Cobalt 40 t .1 kg/Mj 1 ngjK 3 

## Cobalt Alu in a 

## te B1uQ Spin 1 an • inor y 

## ani i ent, is a reaction p 

## rodact of bi Il tenper tpre • ca I 

## ieation in 

# ~n~ eidig 

# ~u~ed ( to l fora d a ci 

# ~

ystaY 

# ~ ine e marii 

# ~ g~f~~

SQiaelvaryiag aaountb are beocgen 

# ~ cusly an 

# ~ ionicat 

# ~ y

nlefa oterYis noted, allvalnes.are r ported as Tiee-NeigLted Alerages TRa o ani tota 

# l dust- particulates onlyg. SBCTION III - PHiSICAL DATA g 

## o113n q 

## Point; N t ap v 

## icable S pe 

## clfic G;avity 

# ~ 9 2 0=1 ; 9 

## t applicable x 

## eltin point: got a Oa 

# ~ l Va or 

# ~ ressure- 11ot 

# ~~p f icab 

# l e 

## va r• essit ZAi 

# ~ 1 : Aot a p 

## li able " 

# l v

~ 

## o r~ t}pn 

## ~ ate 

## ~Bn~~ l ltet t 

## ~ =l 

## ~ : Not applicable ilo i ity Yater: nsolab 

## ~ e , APPBARIIkB ?.ND ODOY - inert odorless blue porder SBCTIOIt 5

- 

### FIRs 1lltD 11PLOSI01 BAZAYD DA1l 

### Hot a fire or explosioa Aaiatd. 

## HMIS HAEAAD CLASSIPICDTIOY HealtIl: 1 Flaneable: 0 1 Reactivity: 0 SBC?IOH 

## 1 - RBACTI9I2I DATA ;

—- ~
. 

## STABILITY: Generall coesidered stable ' POLIlM1EATI0b: tot eipected to occur AvOID: 

# l one expecte 

# i A V 

### OID: Not applicable

~ 

### Naterials to A•roi
~ 

### il Bcze ex 

# D ?cted

_ BA:As?OuS

~ 

### SCOy: SITIG;i OR BY P30!'JCTS t

~ 

### Cce ekYecced



# -?aP

### Page 2 

## S6CTION YI - R6ALT9 RAtARD DATA 10uTE5 OF BNTRY: Byes? YBS Skin? TBS Inbalation? TBS Ingestion? THS BPF3CTS OF 07816IPOSURg: •811 CONTACT na Canse irrltation StIti CONTACT 

## ~ o l 

## op ed or.repe ted conta0t sa 

## ~ cause irritation. IBBAI,ATIOH cagses l 

## ~ rrta t 

## ion p 

## ~ the res irato y ract. 

## ~ S o toes inslade ouah d y 

## s nea, vbeetin g 

## , aod lo alrnent.of p 

## uloonary tunctio . Prog ~ e S 

## slon,o 6y 

## a po ~ ~ n cpntinu e 

## a~ tef dust ~ x G 

## o ure ceases. • : 

## IN ~ BSTIQN 1 harsful. llo t 

## e- A ~ tbou b indastrla h3n ~~ ing o ~ thls product has bezn gao ~ , the toxlcological properties g ave not been fully inves ~ igated. CAt ~ INO ~ ENIC IARC? HO OSHA? NO 1513 • CAS 68186-86-1 E I. 17346 is not listed as a carcinogen in the NAP, IARC, or OSRA listings. B!43RGSHCY AND FIRST AID PROC$DUR ~ :; B y 

## B

~ 

### 1 

## D$XIH,CONTACT: Iaaediate 

## ~
, 

## flush eyes vith plenty of yater for at least 1S ainutes. Call a plysican. Flusd skla ~ ith 9ater. IN9A! ~ ATION: R e 

## moae to,flesb air. lf.breathin 4 

## is difficult, 9 

## ive oxy ep. Call a phy e 

## i s 

## an. INGBSTION: Induce voalting. Ner:r glve aaytning by noutb to 3a uncon 

## ~ clars person. Cait a physiciaa. SBMOH YII - PR3CADTIOHS FOR SAFB BaNDLIHG AND DSE 

# N BPS,TO B$ TAAEII I CASB NATERIA5 IS RBL3ASBD OA SPjLLBD n t 

## ala s 111 d 

## ge aa scoo ,u p 

## or ~ a c 

## uui. Avoid dustin . Aotification of t 

## h ¢ 

## Bational Res onse Center 00-124- ~ 8 Q 

## 2) oa be req 

## ~ ir2d. ?eier to BPA, DOT and y appllcable state and local regulatl o bas for current :es D 

## onse lnforna t 

## ~ oa. It ls rec4 mtad 

## ~ d tbat ea 

## ~ h user :gtablisl a s 

## ~ ill preveaticn, control 

## ~ nd counters 

## ~ asu;e lapt 

# ~ sPtc 

## l . such 

# g lan shoul 

## ~ :ac ude rpce u 

## ~ es a 

## ~~ ica 

## ~ le to q o 

## ~ et to a 

## ~ e, control an clean-up o spillg, lac uding reuse r dis osa as a 

# p ro 

# B riate see l 

## ste isposa Y tbo 

## ~, ~e o~r~. YA TB 

# $ 1SPOSAL M& 9 

# p D F eral state da 1 al d 

### i osal,law 

## 3 and r 

## ean ldtion rill 4 

### ete i e tb p o er,raste disposal roc dare. 

## A~ vasEe aaterla s °



## s~ oold 

## ~~ r QleYed t 

## 4 d ten 

## l ne t 

## ~ e. 1rCab 

## ~ e 

## ~ asBr s 

## ~t~ stln 

## ~ na 

## y .be ne es ar 

## Y ~ . 

# ~ ~ Is sal re ulremeat are de en 

## ~ de 

## ~ t pn tbe 

## ~ aiaTd c 

## 1 assi 

## ~~~ ati n and ril 

## ~ vary by .ocatioa an 

## ~ t~ e type of is 

## ~ osal segected. 

## ~

Soee vas 

## ~ e Qaterials are aoenable to recyc 

## ~ elreuse.

SBCTI09 YIII - SPBCIAL PROT8CTI08 IBFORXATIOB t3SPIRA;ORY PRO?BCTI 

## ~ H A NIOSRL_OSHa approve respirator as necessary vBlirl TO 

## 6enerocal xhaust ventilation as necessary to control any air contaainants to vitbin their TLYS, in the nse ol fbrs pro 

## ~ act. tOTICT I 

## YB 10 0 

## IPMBNT beaical oq 

## les as p 

## eeded to prevent irritation.

~ 

### p 

## ber or g ne~ rene loves. R ~ ~~~Igc N tzgR A s l ~ e B 

# l essary to prevent skin contact. rol breat5in . 

## ~ st. roi 

## ~ .cont ct 

## ~it~ e es skin and clotbing. se - vith a 

## ~ equate ve 

## ~ tilatioa.

SBCTI01 II - SPBCIAL PRBCAOTIONS i GOY8Rg118ltT RHGOLA1I09s 

## aandiing, ship ia and storing reca t 

## ~ ons:



## ~ n 

## ~ ccordance wrt$ $oo 

## ~ ind 

## ~ strial 

## ~~ actice ha 

## ~ dle ritA car 

## ~ ~ nd,a9oid nnasc9ssar gers p on$1 contact. Wasb tbor aghly a ter han ing aab be ore eating, rinkin or osin tob 

## l c o ro acts. For iadustrial use only. SBCTIOH 313 SOPPLIBA HOTIFICATIOY . Tbis p 

## roduct contai0s the tollorip 9 

## to;ic chenicals sub 1 

## ' ct t Q 

## tb r e 

## po t 

## tin q 

## re ~ 

### u 

## irenents of Section 313 of tbe e4ergency Planning and Coeeuni[y Right-to-Inor Act 0 ~ 1986 an ~ of 30 CFI< 37i: PBR CBNT BY CAS; CHBNICAL HAHB 96IG9T 1?07•96-6 

## Cobalt Oxide !6 t



## _ tbis i ~ for:atic, ~ aust be incleded in all NSDS's that are copied atd distributed for t9is aatetial. :t:



# 3?)SPotymeri=ation . .-, 

# MATERIAL S ' 

# AFETY

PATA'SHEET-.'.'' 191 0 .

e DA1 E PfIEP AR ED 12 

### / 8 6 EMERGENCY HAZAf1D f1AT ING rwt 4 - Ex1PEME 7 - FaGH 1 2 - AAOOEAAtE M•Lr ~ •r•crM1 1 • SLIGIIT O - INSIGNIFICANT s.tc ✓ c •!Aro 

### 13TH STREET S 11TH AVBNUE, NEN BRICHTON, PA 15066 412-846'-4000 ✓ SECTION I- PROOUCTION INFORMATION: SINGLE SUBSTANCE 0 MIXTURE O 

### Chem+ca+ Neme 3 CAS No. COBALT ( I I) CARBONATE, BAS IC .. CAS 12 6 0 2- 2 3- 2] Trade Name & Synonyms 

### Sphaerocobaltite, cobalt spar Chemicat Insoluble cobalt com ounds lOnemicet 

### C H Co O H 0• 2CoC0 .3Co(OH) .li Family P l formute 2 

### 6 5 12 ' 2' 3 2 SECTION 11 - HAZARDOUS INGREDIENTS AND/OR C HARACTERISTICS

~ 

### Cobalt Carbonate, Basic - CAS 1112 

### 6 02-2 

### 3- 2J 

### - 83-84$

~ 

### Water of Crystallization - 

### CAS 117732

- 

### 18

- 

### 5J - 

### 16

- 

### 17$

SECTION III - PHYSICAL DATA Mellin9 Poinl( •F) NA Speclrc Gravity (H20 -1) gm/cc @ 25°C 4.13 Boitiny Point ( • F) 

### Decomposes NA Percent Volatlte by Volume (•

~ .) 

### NA 9utk Density (LBSIPer CuiFt.) 

### NDA PH 

### Slightly alkal ine i+i(y in water 

### Insoluble Appearance and Odor AI 

### MOSt purp is , pink pow er; tdo no . irritanE
~ —



## It has no odor. SECTION IV - REACTIVITY DATA Stabitity [Unstabte IConditlons to Avoid

lable X I NA - - lncompatability (Materiais to Avrd 

### e ) acts with acids, releasinq CO 2 . HaZardous Decomposition Products 

### Toxic fumes and metal
. oxides may be present during decanposition.

SECTION V ; = FIRE ANO EXPLOSION HAZARD DATA Flash Point (Method Used) pA Flemmeble Llmlts NA LeL NA Uel NA Eatinfluishiny Media 

### CO,; dry chemical preferred. Spectal Fire F19htiny Procedures



## Avoid flushing with water to sewer or stream. Wlien large quantities are involved, wear self-contained

_ breathing apparatus. Ur,usual Fire and Exptosion Hazerds



### During decomposition, may emit toxic fumes and metal oxi
~ 

### es.'EC ! ION VI - HEALTH HAZARD DATA ' =posuretumits 3 t 11L`GIH 3 

### LV: G. i m/m (Cobalt metal fume TwA: 0.1 /m (Cobalt metal Cetting: NDA "t ot overelposure and uSt IIT ~ uS 

## N ausea and vomiting if swallowed. Possible dermatitis, conjunctivitis, 

## bronchitis. hronic' May cause polycythemia. +edlcal Conditlons a99ravaled by exposurra 

### Pre-existing allergies, resp 

### iratoyy disQase. 'mer9ency flrst Aid Procedures 

### ee pFiysician ~ 

### or eye, skin, nose or tl)roat irritation.



# _ y e Flush with copious amounts of water (und er l-ids)--for--1S--minutes ;kin 

### Wash thoroughly with water and soap. nhalation 

### Remove to fresh air, Aid in hrpa hina i f. , Pce 

### ssar_y-and_ca ll-p 

### h-y."c-ian.— ngestion 

### Give two glasses water and induce vcmiting. Call physician. )THER HEALTH INFORMATION: 1S T E0: OC arcinogen OTeralogen Otilutagen Q+pther Su spect 

### carcinogen, hematotoxin

. >ECTION VII - SPECIAL PROTECTION INFORMATION - PRODUCTION AND/OR MAINTENANCE OPERATIONS lespiratory Prolectlon (Specily Type) 

### N IOSEi-approved f or toXic dus ts .
entitation local Exhaust Speciat 

### Suction Non 

## e Mechanical (General) Other



## Fan None

- i 0 ve Gloves . iEye ProtecGon -- 

### ubbg ~ o ~ 

### i_th impEZVious_>roating Face mask or gog 

### g les )tn otecli v e E q ui ent 

## .:'requenfTy laundered work clothes. ;ECTION VIII - SPILL OR LEAK PROCEDURES ;IepstobeTakenlnCaseMalerialisReleasedorSpilled 

### Wearing protective gear, sweep up for recycle ar ~ 

### ispa
~ 

### al. D ~>~at

- flu~}i

- tb

- 

### sewe c ~ 

### or - sEream;

- foxic fo

- planEs

- and
~ 

### isFi. -- yaste Disposal Method 

## Recycle or send to facility approved by local, state, and federal authorities for toxic metals disposal. ;ECTION IX - SPECIAL PRECAUTIONS •recnuttons to be taken in Handling and Slorin9 

## Keep tightly closed in cool and dry area.

,

, )ther Precautions! 

## Avoid breathing and use adequate ventilation. Maintain clean work area. Shower with soap after work sliift. ;ECTION X - TRANSPORTATION DATA:

~ c•Shi

~ pingName RO t4az,1d t;l.iss 10 g(^9CFt7 112-101) r'0B11LT C11RBO

~ lATE rll ~ N11 _. N11 abc pQciA1 Inlormation tlone

NA - NOT AprtiCAeLE NOA • NO OAIA AVAILAfILE LESS flIAn ~ . 6
~ Of
~ F. Irinrl fulremenl 

### NONE (not regulated by DOT)Ceramics 

# 40

CY 71

~ TnwOKE N

~ VEER:

.. - nintory %l(.1rmation: KAO) 648-8165 QWsextays Q50on-5:00pa 

### Knv

~ 

### qnncy Telephone Number: (610) 643-S!85 

### (24 • 4

- z-) 3 N7 

### Ki, q Roan, lo•t Cwster, PA 1910)

WD 

### syqQNynoi 

### p Czain Pin:< 

## 4 1 ~ : OAVE AND SYNTSY18. !A0162

?"T OF 

### "REPARATION: "ARED BY: 

### .16y Oster, Environmental, HeAfWa6d 

### Sil Q.tekki ician

7- 

### 00yers s-ould use 

### •5is infoymitfo'n 

### onjyjas,> Aupplemant to other information get"erat by them, adogghould qgFe,fhdependent judgements a - •

of this iniormation to.An=•Ukje':

~ 

### pr.Opei - Use and protect the healt:-, A*! 

### SAVIty cl 

### employee•. This information is lurnished without warranty, and 

### zov use as Ana prcduct not in conlarmance with this Material Safety Data 3-lem, cr in combination with •ny other prcduct or process, is the onsponstaility of 

### the user.

--------------------- ----------------------- 

### i:-113 - - :ODUC7 !2 FORMED BY HIGH TEMPERATURE CALCINATION. THEREFORE, IT MAY No

- i

- ':'I - t A~ , 

### Y OF THE PROPERTIES OF THE FOLLOWING SETAL CO•POUNDS LISTED.

,:-- 

### WT% CAS-4 ACGIH TLV OSHA PEL Alumirum 85-95 -------- 10 mq1m3 (b) 5 mg/m3 (a) Wnganegq 6•i0 -------- 5 mg/m3 (C) 5 mg/M3 

### :1 later 

### lo 29 CFR 1910.1013 (Arsenic Stordard), 29 CFR 1910-1025 (Lead Svnn6aed) and 29 OFR 1910.1027 (Cadmium Standard) for more information. (CO Cailing Limit Value 

### veoo••nb•e Oac•io^:

. .. ... ... .... .... .... ... ..... ............................

tm fv zzov rn • FAY fo rm gzmpngr,.. ... .... ..

:70XSCN NATTHEY CERAMICS INC.

-- - -- --------------- ------------------------------------------------------------

- - - ....... - - - - - ....... - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -----



## W 700,19WASAWS . .... . . .. ...- D7AG177 (AIR • 10.

-3 .:7KT VCLATTLE 

### 1Y VOLUME Mn

~ 10 toolicadiQ 7
. 0 

### 711TY 1N ~ 

### ATER:

. —7nole OPOIANANCE AND ODOR: 2-mon pctder, no cdor

------------------------------- ------------------------------------------ §,Pg±g ................... --------------- -~ 39 POIMT (METHOD USED): it applicable `40 AA7:X001SW7NS MEWA: a 400 oto 10. 

### Antsrial will not burn, however, SAO& m&y We" I "us - Od to cool down metal containers. % Tn=A! 71RE FIGHTING

fighters shculd wear Self - ConGARIBMthing Apparatus. Use watar s7jay to ccul metal containers. Use
. , . 

### w ~ 

### niii ~ 

### approaching advanced or mAssive fires. Run off from •ire control may cause environmental pollution. LQ

~ SWAL F:RE AND EXPLOSION HAZARDS: 7cxic fumes way be evolved during a firs.

----------------------------------------------------------------------------------------- ------------------------- -----------------------------

ROUT". - E - S 

### OF EX•OSURE: i n X.o Eyes: Nio Inhalation: 

### Yes Ingestion: 

### Yes 74?GET ORGAN(S) EFFECTS: 

### Aluminum

- 

### Not available ma nganese -R es pi ra tory system, Central Nervous System, blood, kidneys CARCINOGENWITY STATUS: 74e foij•wing con7•und(s) ire listed as carcinogens by NTP, !ARC, CSVA cr a!!:



### Vone 7 7-=S I. OVEREXPOSURE: 7tto 7c

~ :.ntty: •mis comoound is low in acute toxicity with an LD50 of -V n . . " 

### _ ' .;n 2,W mg/Kq 

### oral rat. Conic vn

~ ±City: Long term exposure to Csdojua compounds may rusult 0 - :

~ nd 

### increased risk of cincer of the lung and prostate. staidard 29 cFR 19W.1027 !or 

### more information. c 

### onjnun

~ 

### s any 

### cAuse lunq cAniar. voloc 

### to 1 23Q 1: 12

### Cefamics •

. . ... ........ .... ... ... .... . .. .. ...



### 77A lco&162 004SON NATTHEY CERAMICS INC.

. . . . .... .... .... .... . .. ... ........... .........



## —.5wAgnA

..................... 707-IM AND FIRS7 •ATZ PRCG7DjRzS% FIVSK with plenty of water for 15 Minutes. Zf irritation qsrv!SIE ~ 

### a ohysician.

. An 

### case 0~ 

### con tect, wash skin with soap ort water. Alcove
~7~ 70ns? 710thing and S~ 'Ces. AaW or 

### clean properly toicre rEnse'. AIAV004 Ro-ove to Tres> air. Gi-e actilicial - aspiralion A! nzt -St

~ vnq. TV 

### nreathing is difficolt, give oxygon. ContacL a whysician :30tion: oi"a milk 

### or watar. Do not indoce vemiling i! verson • is Contact a ph•ztcian inmediately.

77AT:

~ 17y (choose one): 

### jUNSTABLVI : .* (x)STABL - -1nPA71SZLITY (MATERIALS TO A01DOW. ' I Acidic conditions and acids 14AWRDOGS DECOMPOS171ON PRODUCTS i

- at applicable 

### )TAY O -QW, PAZARDOUS POLYMERIZATION (choosdo 'CC' R ;_ ( 

### Y )
. 

### WII ~ 

### LANOT C Ur

----------------------------------- ---------------------------------
------------------- --------------------- ?7a•5 TO BE TAKEN 1N CASE MATERIAL 1S RELEASED OR SPILLED: iTVACUAte 

### area. Use appropriate personal protective equipment during clean •9z Use a wet moo or 

### vacu"m cleaner equiped with a HEPA filter. Prevent *ntry into waterways. 

### If reportable quantity is exceeded, contact the Notional Response Center. NASTE DIEPOSAL METHOD: allow 

### all Federal, State and Local regulations for removal and disposal.

------------------------------------------------------------------------------
------------------- 

### RES 0 7RATORY PROTECTION (SPECIFY TYPE): A XZ0SH/MShA approved respirator with HEPA filter represents the minimum 7 .4021 of oratection. 

### See OSHA 29 CFR 1910.134 for respirator fit, selectioi

- i %nt "se,

LWAL !AKAUST: 

### At souvne 

### of gvno ~,~ 

### Ior to ramove dust from breAthir , :7 zGne..

~ =%TCAL VWHAAI ~ w Accup
~ nhlw 

### for

### '

Ceramicl

----'- ... ... ' ......... ' ....... --' ' '' '-

. MATTHEY CERAMICS INC. - - '-_----'-----_---------_-------- --- '------------- .... .... ....... --_ -'-
--... ........ .... ... _'--_-_-------_--------_-_'-'--'_ ' 7>0ver ar& eye jath. Dispcsable csveralls to nrc,54t '^

--- ... ............... ..................................... ... ... --------------------------------------------------- ' -' ---'-------- -------------------------

75 BE TAKEN 1N KANDLING AHD STORINW. -,.`nlej, closed containers. Prevent noisturs inside ccntaisyrs, -- '- ~ 

### Oj7C%TION% 'ov eat, trink or smoke while using this material. Use i ~ 

### acccrdance witi-I

~ 

### ^'-,O 'ntustnial hygiene standards.

~ 

### --- ---------------------------------------------------------------------------

-- / ' `- ~~ 

### ^ ' ' r7L ~ 

### -172RY '

- ~ ~ 

### SAa'zs: Cooponents on `^ 

### n.

~ 

### ;l? 7ttla 71I Section 313 Re

Manga:ese Compounds --_'_-_--_---____--------___-_

~ 

### = ----_-_--_-_----__----_ --------_--_-_---_- ~~~tig~_~ 

### I_ ..................... |11247-TO-KNOW INFORMATION:

~ 

### cSMQ:ent '2~1''Pigoent Red 231 68186-99-2 ' !"`ilfo'niw Proposition 65:

~~~~~ 

### z oateriaI does not contain any ingredients that are known to the State

~ 

### ol , California to cause cancer or reproductive toxicity. PrPoge§ ---------------------------- REFERENCES: PA

~ 

### "!ays California Code of Regulations.

~ 73 

### 6& Pocket Guide to Chemical Harards. 2 0 ~ 0 

### 1 1910.1000, Z-tables

~ 

### -77 ~ 

### T.'/ Yen Waicial Substances and PhysicaI Agents.

~ 

### .' ' K ~Z '

## APPENDIX B Source Test Data



# 3/46

## ENGINEERING EMISSION TESTING FOR BORAL BRICKS, INC. AUGUSTA, GEORGIA SEPTEMBER 10-11,1991

Submitted By: AIR SYSTEMS TESTING, INC. P.O. Box 6278 Marietta, GA 30065 (404) 426-0447

BRUCE LAWRIE



# 317

## E.P.A. TEST PROCEDURES

The testing procedures followed were according to Methods 1, 2, 5, 7, 8, 9, and 

## 13; for location of sampling points; measuring of stack gas velocity and volumetric flow rate; determination of particulate concentrations; determination of NOX concentrations; determination of SO: emission concentrations; 

## determination of opacity emissions; and determination of fluoride emission concentrations. These methods can be found in the 

## Code of Federal Regulations, Title 40, Parts 53-60, revised as of July 1, 1990. 

## Method 1, determination of number and location of sampling points, was used to calculate the location of the twelve points used on each traverse. EPA Method 2 was used to calculate the stack gas velocity and volumetric flow rate. The S-type pitot tube on the pitot-probe assembly was fabricated according to design criteria in Method 2 that allows a pitot coefficient of 0.84 to be used in 

## the calculations. Stack gas temperatures used in the velocity calculations were obtained with a type "K" thermocouple and digital thermometer. Leak checks were performed on the pitot-manometer assembly after each test and showed no leak. Method 5, Determination of Particulate Emission Concentrations, was used to determine particulate emissions. The sampling train consisted of a calibrated nozzle, union, heated glass liner, glass fiber filter and filter holder, four impingers, umbilical cord, pump, and control console. Impinger outlet and dry gas meter temperatures were monitored throughout the test with type "K" 

## thermocouples. The dry gas meter in the control console was calibrated against a Rockwell S-415 test meter that had been standardized with a Rockwell #1464 Bell Prover.

4 

### 3 ~~

## SUMMARY OF TEST RESULTS TK-2 - Fluorides Test #2 Test #4 Volume C Meter (Vm): 26.547 26.035 Sqrt Deita P: 0.388 0.360 Sampling Time (min): 45 45 Barometric Pressure (Pb): 30.05 30.05 Delta H (H): 1.13 0.99 Volume in Impingers (mis): 9.5 10.0 Stack Pressure (Ps): 30.05 30.05 Stack Temperature (Ts): 668 662 Meter Coefficient (Y): 1.007 1.007 Pitot Coefficient (Cp): 0.84 0.84 Meter Temperature (Tm): 563 570 Area Stack (As): 7.47 7.47 Area Nozzle (An): 0.000524 0.000524 Percent CO2 (96): 0.0 0.0 Percent 02 (96): 21.0 21.0 Percent N2 (96): 79.0 79.0 Milligrams Fluoride: 3.3 3.8 Average Molecular Weight Dry (Md): 28.84 28.84 28.84 Volume Water (Vwstd): 0.45 0.47 0.46 Volume Gas Sampled (Vmstd): 25.239 24.440 24.840 Wet Fraction (Bws): 0.017 0.019 0.018 Molecular Weight Wet (Ms): 28.65 28.64 28.64 Volume Gas Sampled (Vma): 32.357 31.098 31.727 Stack Gas Velocity, (Vs): 24.54 22.68 23.61 Volumetric Flowrate (Qs): 8,580 7,987 8,284 Volumetric Flowrate (Qa): 11,000 10,163 10,582 Grainloading, gr/dscf: 0.002 0.002 0.002 Fluoride Emission Rate, #/Hour: 0.15 0.16 0.16 Percent Isokinetic Sampling: 93.2 97.0 95.1



# 3i9

## SUMMARY OF TEST RESULTS TK-2 - Particulates Test #1 Test #3 Volume 0 Meter (Vm): 25.505 25.384 Sqrt Delta P: 0.365 0.346 Sampling Time (min): 45 45 Barometric Pressure (Pb): 30.05 30.05 Delta H (H): 1.00 0.90 Volume in Impingers (mis): 8.5 10.0 Stack Pressure (Ps): 30.05 30.05 Stack Temperature (Ts): 673 673 Meter Coefficient (Y): 1.007 1.007 Pitot Coefficient (Cp): 0.84 0.84 Meter Temperature (Tm): 553 570 Area Stack (As): 7.47 7.47 Area Nozzle (An): 0.000524 0.000524 Percent CO2 (96): 0.0 0.0 Percent 02 (96): 21.0 21.0 Percent N2 (96): 79.0 79.0 Milligrams: 11.2 20.0 Average Molecular Weight Dry (Md): 28.84 28.84 28.84 Volume Water (Vwstd): 0.40 0.47 0.44 Volume Gas Sampled (Vmstd): 24.679 23.824 24.252 Wet Fraction (Bws): 0.016 0.019 0.018 Molecular Weight Wet (Ms): 28.67 28.63 28.65 Volume Gas Sampled (Vma): 31.829 30.832 31.330 Stack Gas Velocity, (Vs): 23.17 21.98 22.57 Volumetric Flowrate (Qs): 8,051 7,611 7,831 Volumetric Flowrate (Qa): 10,384 9,850 10,117 Grainloading, gr/dscf: 0.007 0.013 0.010 Emission Rate, #/Hour: 0.48 0.85 0.66 Percent Isokinetic Sampling: 97.2 99.2 98.2



## :3ZC3

## SUMMARY OF TEST RESULTS Plant #5 - Fluorides Test #7 Test #8 Volume 0 Meter (Vm): 38.259 38.199 Sqrt Delta P: 0.701 0.669 Sampling Time (min): 45 45 Barometric Pressure (Pb): 30.05 30.05 Delta H (H): 2.58 2.38 Volume in Impingers (mis): 41.0 43.0 Stack Pressure (Ps): 30.05 30.05 Stack Temperature (Ts): 910 910 Meter Coefficient (Y): 1.022 1.022 Pitot Coefficient (Cp): 0.84 0.84 Meter Temperature (Tm): 578 573 Area Stack (As): 28.27 28.27 Area Nozzle (An): 0.000475 0.000475 Percent CO2 (96): 2.0 2.0 Percent 02 M: 18.0 18.0 Percent N2 M: 80.0 80.0 Milligrams Fluoride: 43.0 45.0 Average Molecular Weight Dry (Md): 29.04 29.04 29.04 Volume Water (Vwstd): 1.93 2.02 1.98 Volume Gas Sampled (Vmstd): 36.086 36.326 36.206 Wet Fraction (Bws): 0.051 0.053 0.052 Molecular Weight Wet (Ms): 28.48 28.46 28.47 Volume Gas Sampled (Vma): 65.235 65.809 65.522 Stack Gas Velocity, (Vs): 51.91 49.56 50.73 Volumetric Flowrate (Qs): 48,705 46,401 47,553 Volumetric Flowrate (Qa): 88,048 84,062 86,055 Grainloading, gr/dscf: 0.018 0.019 0.019 Fluoride Emission Rate, #/Hour: 7.68 7.60 7.64 Percent Isokinetic Sampling: 98.1 103.6 100.8



# 3 z/

## SUMMARY OF TEST RESULTS Plant #5 - Particulates Test #5 Test #6 Volume C Meter (Vm): 39.736 39.437 Sqrt Delta P: 0.700 0.699 Sampling Time (min): 45 45 Barometric Pressure (Pb): 30.05 30.05 Delta H (H): 2.54 2.55 Volume in Impingers (mis): 37.0 35.0 Stack Pressure (Ps): 30.05 30.05 Stack Temperature (Ts): 919 917 Meter Coefficient (Y): 1.022 1.022 Pitot Coefficient (Cp): 0.84 0.84 Meter Temperature (Tm): 578 575 Area Stack (As): 28.27 28.27 Area Nozzle (An): 0.000475 0.000475 Percent CO2 (%): 2.0 2.0 Percent 02 (%): 18.0 18.0 Percent N2 (%): 80.0 80.0 Milligrams: 38.9 29.7 Average Molecular Weight Dry (Md): 29.04 29.04 29.04 Volume Water (Vwstd): 1.74 1.65 1.69 Volume Gas Sampled (Vmstd): 37.475 37.388 37.431 Wet Fraction (Bws): 0.044 0.042 0.043 Molecular Weight Wet (Ms): 28.55 28.57 28.56 Volume Gas Sampled (Vma): 67.962 67.501 67.732 Stack Gas Velocity, (Vs): 52.03 51.87 51.95 Volumetric Flowrate (G?s): 48,661 48,736 48,698 Volumetric Flowrate (G?a): 88,248 87,988 88,118 Grainloading, gr/dscf: 0.016 0.012 0.014 Emission Rate, #/Hour: 6.68 5.12 5.90 Percent Isokinetic Sampling: 101.9 101.5 101.7

322

## SAMPLING PROCEDURES



## The sampling locations for the testing were on a specially constructed platforms on the exhaust stacks. A wooden platform was used on each of the test ports to support the filter/impinger box while the probe traversed the stack. Prior to each test, the sampling train was assembled for testing. An 80°k isopropanol solution was placed in impinger one, and a 396 hydrogen peroxide solution in impingers two and three. 200.0 grams (g) of silica gel was placed in impinger number 4. The probe was secured in the sampling box, the filter holder assembly was installed, and the system was ready for pre-test leak checks. After each test, leak checks were performed on each sampling train and each side of the pitot tubes. In each of the test repetitions, all leak checks were within the allowable limitations. Next, the train was disassembled. The filter holder was removed and sealed to prevent loss of particulate matter. The probe and nozz(e were cleaned with reagent grade acetone, with all sample exposed surfaces brushed and rinsed at least six times to insure all particulate matter was removed. This rinse was saved in a 500 ml polyethylene bottle. Next, the contents of impingers two and three were measured with a graduated cylinder, and saved for further analysis. The silica gel was returned to its container and sealed.

6 

# sZ3

## Method 8, Determination of Sulfur Dioxide Emissions from Stationary Sources,

was used to determine S02 concentrations. The particulate test train was modified by replacing the distilled water normally used in the first two impingers 

## with a 80°6 isopropanol solution in impinger one, and a 396 hydrogen peroxide solution in impingers two and three. Method 13B, Determination of Fluoride Emission Concentrations, was used to 

## determine fluoride emissions. The sampling train consisted of a calibrated nozzle, union, probe with 316 stainless steel liner heated with 50 feet of 0.4 

## ohms per foot of nichrome wire, three impingers, Whatman number one filter and filter holder, silica gel impinger, umbilical cord, pump, and control console. 

# ~ Impinger outlet and dry gas meter temperatures were monitored throughout the

test with type "K" thermocouples. The dry gas meter in the control console was


# ~ calibrated against a Rockwell S-415 test meter that had been standardized with

a Rockwell #1464 Bell Prover.

5 

# 32 

# ~

## /~ 

# t2 1 °i 94

~ 

## ST" AC, r, T6rS i 

## FAX ANb FACTS

~ 

## umr 5 FROM CLEMSON


## THE CERAMIC CENTER CLEMSON UNIVERSlTY, P. 0. BOX 340908 CLEMSOfV, SC 29634-0908 TEL: 803-656-1094 FAX: 803-656-1095



## DATE PAGES 

## i~ c1M) 

## ~~ Cove 

## ~ 

# C/ / 

# ~~~Je~a

. 

# rO:

. h , -~ 

## ,.,



# ~ FAX NO: ( 

# 70 6 

# 7- 2

, Q 3 0 Z-

. 

# FROM. 

# p 

# ~ ^ L lo

. 

# J

SUBJECT: r- 

## a~ ~ QSu 

## ~ 7".!' Zr 

## MESSAGE 

# 44, ~-f — ~~ e i. ^ 

## ~ o vA h,, 

## ~ ~ ~ L ✓ . ~ ~ S" +c o 

## ~

ire C 4 , 4 t," ' 1 4 "ka r r- C r LA'T$► ( --{~ ~ C f* ~ G` . 1 ~ '~ [)1'T ~ '1

~ 

# BRfCK: SMARTER THAN YOU THINK!

~~~

~ ~

. I

~ — Hf

~ 

## (,A, 3

~

Y z~ /



# ~ Z.5

### ,5 '95 05:45PM CU CERAMIC CENTER P.5 

# E E q u

u tl ~ c. Q O O c Q ') ~ cl ~~ 

## N N ~ 

## p N

~ 

## O t7 W c ~ O

~ c2

O ~ y2 ~ ~ p~> > a ~~ 

# oti w E.S F.S EOa v ~ N O o



## ~ mr•.car

O t- M V 

### rmt,- c'M ill 1~- et a 

### ?vNMri000co tT 

### ooci N N N cM ti 

### e cot-.caInc 1 t`oq c -~

m e- tn v- ca pp Q) O O c' ~ ~ Q c`~ Q O O ~ N 0 e- CO ~ - O'i c ~ Gn ~ ~ N cD t[ ~ ~-

1` t n u'~ O O ~~ to O ++ N~ T O N e'~ r

~ ~•• O eTto O O O f` `Cf' G) Ict v Q N. v O Q O N u7 ch c•'M Cn O V- 00 cD e- O ~ cD e- ~~ et[) ~~ a0 ~

O N ~ N 00

eC Q)eC f ~ r ' ~ CU CO cD N ~ C q O Q O O M t

0 O N 0 CO N N ~ O N ca tA ~ tD O W N ~ o O 11~ O O '• ~ " - a-

~ O r cf Q O p tn p tn O et v v 'CT O O O w `c!' N cV t- m i` 1.- f- 1.- N 

## ~ CD

M c9 t0Pep LOrN e r cC G c0 O f , O CJ 117 C Ln N m N' I,, N GO

e6 "7eO C)

N q M C) 6 O ~ tN ~ 17 O U*) O O© r cri e'M o N d N 0') N m0 N t0 tQ 00 1 ~ O W nl N O r y t!> p tti Q ~ p N N Q } ~ O CO W N cD etCOf
~ v000e7 vCOin tt ~ 'CtOtOMf

, tiO.ta V O Oa=c70 0 0 O~ CO ~ N ~ cOe ~ - C ~rO~N~O•~ tic, O OOWNC

O '. F. O e

~ 7 c' ~ 

# o N p (U N eh O cn GD 0 e—

Ntn00 (p NtnO crltiet'OOON chtDtOe qqe- LDtClttCWttClpe- - ~ ca f ~ ta t ~ '~T Q j e~ 00 f~ C~ ~T N~~j CU O 00 O e"')
~ O
~ D Cd f` cD ~ C'~ ti Q tn ~ #CQf` pt ~'~!'0 00 0~00~ e-COe- 0fNC0
~ Nta
~~ cOO (jJMO

c'' ~ c'7 ~ N ~ N c'~ ~ ~ G')
~ 'Q r-

~ `''7 O O O Op

~ ~ g Z ~ 

# a ~

~ 

### O to O O et ul) ul) cJ 1 1 - C* O O Ov `Q' h ea m ti(D w t0 ~ 

### IL e-00 te—mNr-tif-- M O 

## m= O O CO Q



### CONNC7NG0000 O? 

### W ~ 00O';t. ~ 0 

### 4 09 e- CC t- e- N CO 0 CO 

### ~ O W M N ~ O c') c? 

### O N O N C ) O

~ O)pO 

### tZ 

## ~ p



# " E

~ .. N 

### E0- 

# E v ° J~_~ Nv~ v CL o~ '~ 

# ca .c a

~ E ° ' ~ 

# c, E v

~~ 

# U O Z ~ 

## ~ 

# ~ t a 

# .. .. Q

~ 

# ° V
~ 

# c c c ~ 

# EcnaEOEx

~ 

# U.. ~ 

# cJ) z m 

# m u Q u ~ 

# o m m > O r > Q(nmQ>(nCn Cl. QQQ.G.c.d. 

### V

y ~ O Q. .C2. " . v 

# c'o> ~~~aN~ 

# 'r cn o3NN ~Q~ 

# iL,

~~ 

# ,o .v 

# m _ c_ ~ ~ 

### o 3 ~ 

### `o ~ 

# c y (u

~ 

## iL1L y U U 0

fn 

## 5 0 (D 0 Q ) O

- 5 75 c 

## u E Eu. u E x E E

- E

. ~ 

## c: a ~ ~ = c.) > > • ~ ~ ~ ~ ~ 0 O O ~ a O ~ O O ti- cti -re a ~ L > > ~ ~ > n n Q

## BORAL BRICK PLANT #5 - FLUORIDES

, r •yJ 

## '..;olume @ Meter (Vm): ' I Sqrt Delta P: 'timpling Tlme (min): Barometric Pressure 

# (Pbar): Avg Delta H: Volume in impingers (mis): Stack Pressure (Ps): Stack Temperature (Ts): Meter Coefficient (Y): Pitot Coefficient (Cp); Meter Temperature (Tm): Area Stack (As): 

# Area Nozzle (An): Percent CO2 (%): Percent 02 (%): Percent N2 (%); Fluoride (mg): Test #4 Test #5 41.364 40.379 0.784 0,775 60 60 30.10 30.10 1.55 1.50 62.0 57.7 30.15 30.14 880 889 0.9874 0.9874 0.84 0.84 554 558 28.27 28.27 0.000334 0.000334 2.0 2.0 18.0 18,0 80.0 80.0 85.8 75.9 Test #6

40.692 ft^3 0.770 60 min 30.10 inHg 1.46 64.1 mis 

## 30.13 inHg 883 R 0.9874 0.84 545 R 28,27 ft^2 0.000334 ft^2 2.0 % 18.0 % 80.0 % 82.1 mg 

## Molecular Weight Dry (Md): Volume Water (Vwstd): lume Gas Measured (Vmstd): Wet Fraction (Bws): Molecular Weight Wet (Ms): 

# Volume Gas Sampled (Vma): Stack Gas Velocity (Vs): Volumetric 

# Flowrate (Qs): , Volumetric Flowrate (Qa): Total HF (mg): 

# HF Concentration (cs): 

# HF Emissions rate (pmr): Percent Isokinetic Sampling: 29.04 29.04 29.04 2.92 

## 2.71 3.02 39.32 38.10 39.32 0.0691 0.0665 0.0712 28.3 28.3 28,3 68.7 68.3 67,7 57.2 56.8 56.3 58216 57260 57151 97054 96441 95595 90.35 79.92. 

## 86.45 2.30 2.10 2.20 17.69 15.89 16.62 101.7 100.0 103.9 Average 29.04 lblibmol 2.88 scf 38.91 scf 0.0689 28.3 lb/lbmol. 68.2 ft^3 56.8 - ftls 57542 scfm 96363 scfm 85.57 mg 2.20 mg/dscf 16.73 lb/h 101.9 %



# 3, 2

? 2

## BORAL BRICK PLANT #5 - CHLORIDES

~ 

## /olume @ Meter (Vm): 

# Q Sqrt Delta P: Sainpling Time (min): Barometric Pressure (Pbar): Avg Delta H: Volume in impingers (mis): Stack Pressure (Ps): Stack Temperature (Ts): Meter Coefficient (Y): Pitot Coefficient (Cp): Meter Temperature (Tm): 

# Area Stack (As): Area Nozzle (An): Percent CO2 (%): 

## Percent 02 (%): Percent N2 (%): Chloride (mg): Molecular Weight Dry (Md): Volume Water (Vwstd): N" ime Gas Measured (Vrnstd): V1ret Fraction (Bws): Molecular Weight Wet (Ms): 

# Volume Gas Sampled (Vma): Stack Gas Velocity (Vs): Volumetric Flowrate (Qs): . Volumetric Flowrate (Qa): Total HCI (mg): HCI Concentration (cs): HCI Emissions rate (pmr): Percent Isokinetic Sampling: Test #4 Test #5 Test #6 41.364 40.379 40.692 ft^3 0,784 0.775 0.770 ' 60 60 60 min 30.10 30.10 30.10 inHg 1.55 1.50 . 1.46 62.0 57.7 64.9 mis 30.15 30.14 30.13 inHg 

# 880 889 883 R 0,9874 0.9874 0.9874 0.84 0.84 0.84 

# 554 558 545 R 28.27 28.27 28.27 ft^2 0.000334 0.000334 0.000334 ft^2 

## 2.0 2.0 2.0 % 18.0 18.0 18.0 % 80.0 80.0 80.0 % 42.9 38.1 40.4 mg.

, 

# Average 29.04 29.04 29.04 29.041b/lbmol 2.92 2.71 3.02 2.88 scf 39.32 38.10 39.32 38.91 scf 0.0691 0,0665 0,0712 0.0689 

## 28.3 28.3 28.3 28.31bltbmol 68.7 68.3 67.7 68.2 ft"3 57.2 5618 56.3 56.8 ft/s 58216 57260 57151 57542 scfm 

# 97054 96441 95595 96363 scfm 44:10 39.17 41.53 41.60 mg 1.12 1.03 1.06 1.07 mg/dscf 8.64 7.79 7.99 8.141b/h 101.7 100.0 103.9 10 9.9 %



# .3

~ 

# '