Page 1 of 8 Revision date 08/27/2004 

# Material Safety Data Sheet

1. PRODUCT AND COMPA NY IDENTIFICATION

ADCOTE TM 76 FS

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Revision date: 08/27/2004

Supplier ROHM AND HAAS CHEMICALS LLC

A Subsidiary of The Dow Chemical Company

100 INDEPENDENCE MALL WEST

PHILADELPHIA

, PA 19106

- 2399 United States

For non

- emergency information contact: 215

- 592

- 3000

For non

- emergency information contact: 215

- 592

- 3000

Emergency telephone number

1 800 424 9300

Local Emergency telephone number

989

- 636

- 4400



### 2. COMPOSITION/INFOR MATION ON INGREDIENT S

Component CAS

- No. Concentration

Polyurethane resin Not Hazardous 59.0

- 61.0 %

Methylenebis(4

- phenyl isocyanate) 101

- 68

- 8 0.2%

Ethyl acetate 141

- 78

- 6 39.0

- 41.0 %



### 3. HAZARDS IDENTIFIC ATION

Emergency Overview



### Appearance

Form viscous liquid

Colour yellow

Odour Solvent odorADCOTE TM 76 FS

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Page 2 of 8 Revision date 08/27/2004 

### Hazard Summary WARNING !

FLAMMABLE LIQUID AND VAPOR.

INHALATION OF VAPOR OR MIST CAN CAUSE TH E FOLLOWING:

SHORTNESS OF BREATH

TIGHTNESS IN THE CHE ST

IRRITATING TO EYES A ND SKIN.

MAY CAUSE SENSITIZAT ION BY INHALATION AN D SKIN

CONTACT.

CLOSED CONTAINERS MA Y EXPLODE WHEN HEATE D OR

CONTENTS CONTAMINATE D WITH WATER.

PROLONGED OR REPEATE D OVEREXPOSURE TO TH E

SOLVENT(S) IN THIS M ATERIAL CAN CAUSE TH E FOLLOWIN G:

KIDNEY DAMAGE

LUNG DAMAGE

LIVER DAMAGE

HEART DAMAGE

CENTRAL NERVOUS SYST EM (CNS) EFFECTS

BLOOD CHANGES

Potential Health Effects

Primary Routes of Entry: Eye contact

Inhalation

Skin contact

Eyes: Material can cause the following:

Moderate irritation.

burning sensation

tearing

reddening

Skin: May cause sensitization by skin contact.

Material can cause the following:

Moderate irritation.

burning sensation

reddening

itching

Ingestion: Material can cause the following:

severe irritat ion of the mouth, throat, and digestive tract

diarrhea

nausea

vomiting

abdominal pain

Inhalation: Inhalation of vapor or mist can cause the following:

coughing

irritation of nose, throat, and lungs

tightness in the chest

shortness of breath

May cause severe allergic respiratory reaction.

Sensitization

Chronic Exposure: Long term exposure to diisocyanates may cause lung damage, including reduced

lung function, which may be permanent.

Prolonged or repeated overexposure to the solvent(s) in thi s material can cause the following:ADCOTE TM 76 FS

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Page 3 of 8 Revision date 08/27/2004 heart damage

Blood changes

central nervous system (CNS) effects

kidney damage

liver damage

lung damage

Methylenebis(4

- phenyl isocyanate) IRIS Not classifiable.



### 4. FIRST AID MEASURE S

Inhalation: Move to fresh air. If breathing is irregular or stopped, administer artificial respiration. Call a

physician immediately.

Skin contact: Take off all contaminated clothing immediately. Wash off immediately with soap and

plenty of water. If skin irritation persists, call a physician. Wash contaminated clothing before re

- use.

Eye contact: Flush eyes with water as a precaution. If eye irritation persists, consult a specialist.

Ingestion: Never give anything by mouth to an unconscious person. If a person vomits when ly ing on

his back, place him in the recovery position. Do not induce vomiting. Rinse mouth. Immediately give

large quantities of water to drink. Call a physician immediately.

Notes to physician

Bronchial constriction may develop after extensive exposure to isocyanates, even in individuals who

have not been shown tobe previously sensitized.



### 5. FIRE

- FIGHTING MEASURES

Flash point 0 °C ( 32.90 °F ) SETAFLASH CLOSED CUP SETAFLASH CLOSED

CUP

Thermal decomposition Heating or fire conditions liberates toxic gas.

Combustion Products: Hydrogen cyanide

Carbon monoxide

Carbon dioxide

Nitrogen dioxide

Suitable extinguishing

media: foam

carbon dioxide (CO2)

dry powder

Specific hazards during fire fighting: Vapors can travel to a source of ignition and flash back. Heated

material can form flammable or explosive vapors with air. Closed containers may rupture via pressure

build

- up when exposed to fire or extreme heat.

Special protective equipment for fire

- f ighters: Wear self

- contained breathing apparatus and

protective suit.

Further information: For safety reasons in case of fire, containers should be stored separately in

closed containments.

Cool closed containers exposed to fire with water spray.

EXPLOSI ON HAZARD. Fight advanced fires from a protected location.

Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with lo cal

regulations.



### 6. ACCIDENTAL RELEAS E MEASURES

Personal precautionsADCOTE TM 76 FS

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Page 4 of 8 Revision date 08/27/2004 Use personal protective equipment.

Refer to protective measures listed in sections 7 and 8.

MATERIAL IS A POTENTIAL SENSITIZER.

If exposed to material during clean

- up operations, IMMEDIATELY remove all contaminated clothing and

wash exposed skin areas with soap and water. See SECTION 4, First Aid Measures, for further

information.



### Environmental precautions

Do not flush into surfac e water or sanitary sewer system.



### Methods for cleaning up

Evacuate personnel to safe areas.

Remove all sources of ignition.

Ensure adequate ventilation.

Contain and collect spillage with non

- combustible absorbent material, (e.g. sand, earth, diatomaceous

earth, vermiculite) and place in container for disposal according to local / national regulations (see

section 13).



### 7. HANDLING AND STOR AGE

Handling

Provi de sufficient air exchange and/or exhaust in work rooms. Avoid exceeding of the given

occupational exposure limits (see section 8). In case of insufficient ventilation, wear suitable respiratory

equipment. Do not breathe vapours or spray mist. Wear per sonal protective equipment. For personal

protection see section 8. Keep away from heat and sources of ignition. Take necessary action to avoid

static electricity discharge (which might cause ignition of organic vapours). Ensure all equipment is

electri cally grounded before beginning transfer operations. May cause sensitization of susceptible

persons by skin contact. CONTAINERS MAY BE HAZARDOUS WHEN EMPTY. Since emptied

containers retain product residue follow all MSDS and label warnings even after co ntainer is emptied.

Storage

Storage conditions: Material can burn; limit indoor storage to approved areas equipped with automatic

sprinklers. Keep container tightly closed in a dry and well

- ventilated place. Keep away from heat and

sources of ignition. Electrical installations / working materials must comply with the technological safety

standards.



### 8. EXPOSURE CONTROLS / PERSONAL PROTECTIO N

Exposure limit(s)

Exposure limits are listed below, if they exist.

Component Regulation Type of listing Value

Methylenebis(4

- phenyl

isocyanate) Rohm and Haas TWA 0.005 ppm

Rohm and Haas 0.02 ppm

ACGIH TWA 0.005 ppm

OSHA_TRANS Ceiling 0.2 mg/m3 0.02 ppm

Component Regulation Type of listing Value

Ethyl acetate ACGIH TWA 1,440 mg/m3 400 ppm

OSHA_TRANS PEL 1,400 mg/m3 400 ppm

Z1A TWA 1,400 mg/m3 400 ppm

Rohm and Haas TWA 150 ppm

Rohm and Haas STEL 300 ppm

Eye protection: Use chemical splash goggles and face shield (ANSI Z87.1 or approved equivalent).

Eye protection worn must be compatible with respiratory protection system employed.ADCOTE TM 76 FS

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Page 5 of 8 Revision date 08/27/2004 Hand protection: Chemical

- resistant gloves should be worn whenever this material is handled. The

glove(s) listed below may provide protection against permeation. (Gloves of other chemically resistant

materials may not provide adequate protection): 4H Glove (Trademark of Safety 4 A/S of Denmark)

Butyl rubber Gloves should be removed and replaced immediately if there is any indication of

degradation or chemical breakthro ugh. Before removing gloves clean them with soap and water.

NOTE: Material is a possible skin sensitizer.

Skin and body protection: complete suit protecting against chemicals safety shoes

Respiratory protection: A respiratory protect ion program meeting OSHA 1910.134 and ANSI Z88.2

requirements or equivalent must be followed whenever workplace conditions warrant a respirator ‟ s use.

None required if airborne concentrations are maintained below the exposure limit listed in Exposure

Limi t Information. Above the exposure limit: Wear a properly fitted NIOSH approved (or equivalent)

self

- contained breathing apparatus in the pressure demand mode, OR full

- facepiece, airline respirator in

the pressure demand mode with emergency escape provisi on.

Hygiene measures: Wash hands before breaks and immediately after handling the product.

Protective measures: Facilities storing or utilizing this material should be equipped with an eyewash

facility and a safety shower.



### Engineering measures: Use e xplosion

- proof local exhaust ventilation with a minimum capture

velocity of 100 ft/min (0.5 m/sec) at the point of vapor evolution. Refer to the current edition of Industrial

Ventilation: A Manual of Recommended Practice published by the American Conferen ce of

Governmental Industrial Hygienists for information on the design, installation, use, and maintenance of

exhaust systems.



### 9. PHYSICAL AND CHEM ICAL PROPERTIES

Appearance

Form viscous liquid

Colour yellow

Odour Solvent odor

Flash point 0 °C ( 32.90 °F ) SETAFLASH CLOSED CUP SETAFLASH

CLOSED CUP

Water solubility insoluble

Relative density 1.02

VOC ’ s Not Determined

NOTE: The physical data presented above are typical values and should not be construed as a

specification.



### 10. STABILITY AND RE ACTIVITY

Hazardous reactions Stable under recommended storage conditions.

Avoid moisture.

Conditions to avoid Heat, flames and sparks. Exposure to water vapour.

Materials to avoid strong oxidizing agents water

Hazardous

decomposition products Hydrogen cyanide

Acetaldehyde

Isocyanate(s)ADCOTE TM 76 FS

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Page 6 of 8 Revision date 08/27/2004 polymerization Hazardous polymerization will also occur if contaminated with the

following:

- water (moisture)



### 11. TOXICOLOGICAL IN FORMATION

No toxicity data are available for this material.

Component: Diphenylmethane

- 4,4 ’

- di

- isocyanate

Acute oral toxicity LD50 mouse 2,200 mg/kg

Component: Diphenylmethane

- 4,4 ’

- di

- isocyanate

Acute oral toxicity LD50 rat > 15,000 mg/kg

Component: Ethyl acetate

Acute oral toxicity LD50 human 6,100 mg/kg

Component: Ethyl acetate

Acute oral toxicity LD50 rat 5,620 mg/kg

Component: Diphenylmethane

- 4,4 ’

- di

- isocyanate

Acute inhalation toxicity LC50 rat 4.0 h 369 mg/m3

Component: Diphenylmethane

- 4,4 ’

- di

- isocyanate

Acute dermal toxicity LD50 rabbit > 9,400 mg/kg

Component: Ethyl acetate

Mutagenicity

No mutagenic activity was observed in bacterial cells.



### 12. ECOLOGICAL INFOR MATION

There is no data available for this product.

Et hyl acetate

Ecotoxicity effects

Toxicity to fish LC50 Rainbow trout (Oncorhynchus mykiss) 96 h

484 mg/l

Toxicity to fish LC50 Fathead minnow (Pimephales promelas) 96 h

230 mg/l

Toxicity to algae EC50 Algae 96 h

2,000 mg/l

Toxicity to aquatic

invertebrates EC50 Daphnia magna 48 h

717 mg/l



### 13. DISPOSAL CONSIDE RATIONS

Environmental precautions: Do not flush into surface water or sanitary sewer system.



### Disposal

Waste Classification: D001

For disposal, incinerate this material at a facility that complies with local, state, and federal regulations.

(See 40 CFR 268)ADCOTE TM 76 FS

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### 14. TRANSPORT INFORM ATION



## DOT

Proper shipping name Resin solution

UN

- No UN 1866

Class 3

Packing group II

Reportable Quantity Ethyl acetate



## IMO/IMDG

Proper shipping name RESIN SOLUTION

UN

- No UN 1866

Class 3

Packing group II

Transportation classifications may vary by container volume and may be influenced by regional or

country variations in regulations



### 15. REGULATORY INFOR MATION

Workplace Classification

This product is considered hazardous under the OSHA Hazard Communication Standard (29 CFR

1910.1200).

This product is a „ controlled product ‟ under the Canadian Workplace Hazardous Materials Information

System (WHMIS).



### SARA TITLE III : Section 311/312 Cate gorizations (40CFR370): Fire Hazard

Acute Health Hazard

Chronic Health Hazard



### SARA TITLE III : Section 313 Information (40CFR372)

This product contains a chemical which is listedin Section 313 at or above de minimis concentrations.

The following listed chemicals are present: (Quantity present is found elsewhere on this MSDS.)

SARA Title III Components: Methylenebis(4

- phenyl isocyanate) 101

- 68

- 8



### CERCLA Information ( 40CFR302.4 )

This material is r egulated under the Comprehensive Environmental Response, Compensation and

Liability Act (CERCLA)and the Superfund Amendments and Reauthorization Act (SARA) Title III Section

304. This material is or contains chemical(s) listed in 40 CFR Table 302.4 or nond esignated RCRA ICR

substance(s). (Nondesignated ICR substances apply to materials that will not be reused.) The

Reportable Quantity(s) (RQ) are listed below. Releases in excess of its reportable quantity must be

reported to the National Response Center (1

- 800

- 424

- 8802) and to the appropriate state and local

emergency response organizations.

See Section 13, Disposal Considerations, Subsection Disposal, for CERCLA classification.

CERCLA Components: Ethyl acetate 141

- 78

- 6 5,000 lbs RQ



### US. Toxic Substances Control Act ( TSCA ) All components of this product are in compliance with

the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical

Substance Inventory.



### Pennsylvania

Any material listed as “ Not Hazard ous ” in the CAS REG NO. column of SECTION 2,

Composition/Information On Ingredients, of this MSDS is a trade secret under the provisions of the

Pennsylvania Worker and Community Right

- to

- Know Act.



### California (Proposition 65)ADCOTE TM 76 FS

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Page 8 of 8 Revision date 08/27/2004 This product contains trace le vels of a component or components known to the state of California to

cause cancer:

Components: m

- Tolylidene diisocyanate 26471

- 62

- 5

Propylene oxide 75

- 56

- 9



### 16. OTHER INFORMATIO N

Hazard Rating



### Health Fire Reactivity

HMIS 2* 3 1



### Legend

ACGIH American Conference of Governmental Industrial Hygienists

BAc Butyl acetate

OSHA Occupational Safety and Health Administration

PEL Permissible Exposure Limit

STEL Short Term Exposure Limit (STEL):

TLV Threshold Limit Value

TWA Time Weighted Average (TWA):

| Bar denotes a revision from prior MSDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information

and belief at the date of its publication. The information given is designed only as a guidance for safe

handling, use, processing, storage, transportation, disposal and release an d is not to be considered a

warranty or quality specification. The information relates only to the specific material designated and

may not be valid for such material used in combination with any other materials or in any process, unless

specified in the t ext.

Version: 2

. 1

Print Date: 11/08/2012

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