Advanced Membrane Filtration Technology for Cost Effective 

Recovery of Fresh Water from Oil & Gas Produced Brine 

Technical Progress Report 

For the period January through December 2005, (Revised June, 2006) 

David B Burnett 

Revised Report Issued July 2006. 

DOE Project Number: DE-FC26-03NT15427 

Texas A&M University 

Harold Vance Department of Petroleum Engineering 

Texas Experimental Engineering Station (TEES) 

DISCLAIMER 

This report was prepared as an account of work sponsored by an agency of the United States Government. 

Neither the United States Government nor any agency thereof, nor any of their employees, makes any 

waranty, express or implied, or assumes any legal liability or responsibility for the accuracy, 

completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that 

its use would not infringe privately owned rights. Reference herein to any specific commercial product, 

process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or 

imply its endorsement, recommendation, or favoring by the United States Government or any agency 

thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the 

United States Government or any agency thereof. 
ABSTRACT 

This study is developing a comprehensive study of what is involved in the desalination of 

oil field produced brine and the technical developments and regulatory changes needed to 

make the concept a commercial reality. It was originally based on “conventional” 

produced water treatment and reviewed (1) the basics of produced water management, (2) 

the potential for desalination of produced brine in order to make the resource more useful 

and available in areas of limited fresh water availability, and (3) the potential beneficial 

uses of produced water for other than oil production operations. Since we have begun 

however, a new area of interest has appeared that of brine water treatment at the well site. 

Details are discussed in this technical progress report. 

One way to reduce the impact of O&G operations is to treat produced brine by 

desalination. The main body of the report contains information showing where oil field 

brine is produced, its composition, and the volume available for treatment and 

desalination. This collection of information all relates to what the oil and gas industry 

refers to as “produced water management”. It is a critical issue for the industry as 

produced water accounts for more than 80% of all the byproducts produced in oil and gas 

exploration and production. The expense of handling unwanted waste fluids draws scarce 

capital away for the development of new petroleum resources, decreases the economic 

lifetimes of existing oil and gas reservoirs, and makes environmental compliance more 

expensive to achieve. 

More than 200 million barrels of produced water are generated worldwide each day; this 

adds up to more than 75 billion barrels per year. For the United States, the American 

Petroleum Institute estimated about 18 billion barrels per year were generated from 

onshore wells in 1995, and similar volumes are generated today. Offshore wells in the 

United States generate several hundred million barrels of produced water per year. 

Internationally, three barrels of water are produced for each barrel of oil. Production in 

the United States is more mature; the US average is about 7 bamels of water per barrel of 

oil. Closer to home, in Texas the Permian Basin produces more than 9 barrels of water 

per barrel of oil and represents more than 400 million gallons of water per day processed 

and re-injected. 
Table of Contents 

ABSTRACT ..................................................................................................................................... 3 

INTRODUCTION ............................................................................................................................. 5 

Background Information ..................................................................................................... 5 

Managing Produced Water ..................................................................................... 5 

Produced Water Volumes and Composition 5 

Brackish Water Produced in Texas Oil and Gas Wells 6 

EXECUTIVE SUMMARY 

EXPERIMENTAL 

Desalination Efficiency 

Operating Cost and Power Usage. 

RESULTS AND DISCUSSION ............ .................................... .. Desahnahon Workshops ........................................................................................................................... 15 

CONCLUSIONS ............................................................................................................................ 16 

Schedule for 2006 Activity ............................................................................................................. 16 

Ultrafiltration Membranes ........................................................................................................................ 16 

Hollow Fiber Microfilter Membranes ...................................................................................................... 16 

REFERENCES .............................................................................................................................. 17 

.. 

TABLES AND FIGURES 

Figure 1. Location of active gas wells in Texas 7 

Figure 2. Diseibution of produced water sites in Texas ................................................................................. 8 

Table 1 Representative power costs of desalination of oil field brine. .................................................. 10 

Figure 3. Tne small scale membrane test rig. ............................................................................................... 11 

Table 2. Salt Rejection Efficiency .............................................................................................................. 12 

Figure 4. The A&M Mobile Desalination Unit 14 

Table 3. Representative power costs of desalination of oil field brine. .................................................. 14 
Advanced Membrane Filtration Technology for Cost Effective Recovery 

of Fresh Water from Oil & Gas Produced Brine 

DOE Project Number: DE-FC26-03NT15427 

INTRODUCTION 

Background Information 

Oil and gas operations on leases that have been on production for extended time produce 

copious amounts of brine water along with the associated oil and gas. Produced water, 

(any water that is present in a reservoir with the hydrocarbon resource) is produced to the 

surface with the crude oil or natural gas. Not only in Texas, but world-wide, the oil and 

gas industty is experiencing increased volume of produced water handled in both onshore 

and offshore petroleum production operations. The resulting operational costs and 

environmental issues are a major concern, especially with the possibility of further 

reduction in the oil content allowed in the discharged water (offshore operations), as well 

as the fact that produced water contains a number of undesirable toxic components. 

To speed up the adoption of technology, the industry has established a number of 

techniques for handling produced water in both mature fields and in new and planned 

developments. These practices take into consideration the nature of the water, technology 

limitations, both emission to the atmosphere and discharges into the sea, nature of the 

discharges, safety concerns and cost, as well as establishing any environmental gains in 

each case. Most operators, big and small, handle produced water management in the 

same way. (Most often in Texas however, the option is brine injection back into the 

producing formation.) 

Management of water issues is a major emphasis of the DOE’S Oil and Gas 

Environmental Program administered by the National Energy Technology Laboratory’s 

National Petroleum Technology Office. Water issues include several concerns: 

injection water, produced water (including Coalbed Natural Gas-CBNG) and its effects 

on the environment, treatment of waste water, and the availability of water in and lands. 

NETL currently has 26 projects grouped under Water Management Approaches and 

Analysis, Water Management Technologies, and Coalbed Methane and Produced Water. 

The shared goal of all of these projects is to ensure that water produced through oil and 

gas development does not adversely impact the environment and that it is put to 

beneficial uses where possible. 

Managing Produced Water 

Produced Water Volumes and Composition 

The volume of produced water from oil and gas wells in Texas (conventional production) 

is increasing yearly as fields mature and oil production decreases. A majority of the fields 

in Texas that are still producing petroleum exhibit slowly increasing gas-water ratios or 
water-oil ratios. This means that the total liquid production tends to stay constant while 

the oil or gas volume gradually decreases. The implication for those considering the use 

of brine for a field is that there is little likelihood of water production ceasing, only that 

the field and the wells comprising the field may no longer be economical to operate. Only 

then is the well shut in and abandoned. 

With high prices for petroleum, economic recovery of oil and gas allows O&G operators 

to keep wells on production for longer and longer times. The most recent well 

abandonment statistics from the TRC show that fewer that 3% of the wells in Texas were 

abandoned in 2005. Out of 227,796 wells, 6,688 were abandoned and their permits 

ended. Figure 1 shows how broadly distributed the gas wells in Texas are. 

Figure 2 shows the statewide distribution of produced brine. Distribution of produced 

water is shown for three categories of brine. Approximately 1/3 of the sites represent 

brines with salinity less than 10,000 ppm tds. This is brackish water and can be treated 

for only slightly more expense than brackish ground water resources in Texas. The 

advantage of this is that the cost of producing this water is zero (paid for by the oil and 

gas production). The degree of difficulty in treating this brackish water is discussed in the 

following section. 

Brackish Water Produced in Texas Oil and Gas Wells 

Many of the producing fields in Texas discharge water having less than 10,000 ppm tds 

(total dissolved solids). Figure 2 shows the state divided into Water Planning Districts. 

Each district has a number of producing wells that discharge brackish water (<10,000 

ppm tds), saline water (10,000 to 50,000 pprn tds), and hyper-saline water (250,000 ppm 

tds). The locations of the fields are shown with salinity represented by a different color.. 

The entries on the map do not contain all of the information listed in the U.S.G.S. data 

base. There is not a 1:l correspondence of the map to the tabular list as many of the 

locations do not have latitude and longitude position locations. For more detailed 

information, the USGS database should be referenced. The best source for this 

information for those planning studies of desalination of produced water should refer to 

the records of each county being considered. 
RAILROAD COMMISSION of 1 'EXAS 

Figure 1. Location of active gas wells in Texas. 

There are approximately 300,000 oil and gas wells, 2/3 of these wells are on production. 

The majority of these wells produce water that is usually re-injected to maintain 

pressure and production [13]. 

Desalination of oil field brackish brine may be less expensive because of the disposal 

options available to the water treatment operator. 
Legend 

e 

n 

ToM Oissofved Solids > 50.000 ppin 0 3s 80 120 180 245 

S?d~i)Isnenilt~ LBMld*r# 

Toial Oissdved Solids E 10.000 PPm 

T&I Dissolved Solids between 30.000 and 50,000 ppm 

Figure 2. Distribution of produced water sites in Texas. 

Approximately 1/3 of the sites represent brines with salinity less than 10,000 ppm tds and 

can be classified as “brackish water”. Detailed maps of wells producing brackish water in 

each Water Resource Planning District are available from the A&M desalination group. 

Texas producing fields are representative of most major, mature production areas in the 

US. because it has long been one of the top petroleum producing states in the nation. As 

fields have matured, more brine water is produced along with the petroleum resource. 

More brine water is being re-injected as well, to sustain production, prevent subsidence, 

and to dispose of excess produced brine. Texas has long been stmggling with a lack of 

water resources and as the population of the state grows, more demand is being placed 
upon surface and ground water sources of fresh water. As these issues become more 

important, more attention is turning to recovery of fresh water from these brine 

byproducts of O&G activity. 

Specific research needs are harder to prioritize. For the past five years A&M has worked 

to find technologies to employ in desalination and to outline ways to establish a value for 

the resource that is recovered by this treatment. The research has found that the 

technology is available to desalinate certain brines produced in petroleum operations. 

However, that technology needs to be improved, the value of fresh water and local water 

supply needs must be established, and the environmental and regulatory issues associated 

with beneficial use must be addressed. 

EXECUTIVE SUMMARY 

Goals of Project 

The ovemding goal is to develop improved RO (reverse osmosis) membrane filtration 

technology for treating waste water produced during oil and gas production operations. A 

specific goal is to identify technology that can reduce the cost of membrane filtration. 

Objectives 

The objectives include evaluation of a new pre-treatment technology using combinations 

of liquid-liquid centrifuges, organoclay absorbents, microfiltration, and the evaluation 

and modification of different oil resistant membrane materials and membrane types. We 

are also developing a dynamic model using variable feed flow, trans-membrane 

pressures, and recycling ratios to permit optimization of a process design. Studies have 

experimentally validated models and the equipment process trains. 

Investigators 

Performing the work is a team from the Harold Vance Department of Petroleum 

Engineering. Dr. Maria Barmfet and her graduate assistants are designing the process 

models, while David Bumett and his associates are constmcting the filtration train and 

testing its operation. Leading the pilot plant operation of the team is Mr. Carl Vavra. 

Program funds have provided a graduate assistanceship and the education of one Masters 

Student, Mr. Scott Beech who will graduate in August 2006. 

Experience has shown that membranes can be effective pre-treatment techniques and RO 

membranes can provide desalination at less cost than the cost of brine disposal. Testing 

has also shown that desalinating brackish oil field brine is more expensive that 

desalination of BGW but concentrate disposal will be less expensive. Newer desalination 

technology is also continuing its advance in the field of industrial, food, and 

pharmaceutical industries. 

The A&M Mobile Desalination Unit was constructed to test both pre-treatment by 

membranes and RO desalination at field sites. Different types of membranes are tested 

and RO salt rejection efficiency can be determined directly. It is equipped to run either 
__.. : 

Salinity of Feed 

Brine, tds (ppm) 

single stage or multi-stage membrane treatments and can be configured either for parallel 

or series membrane flows. The unit is shown in Figure 3 in Washington County, Texas in 

2006. 

I 

Power Costs Kw Hr per 1,000 gal. Permeate 

Pre- RO Operating Operating 

treatment desalination Cost, $ per Cost, $ per hhl 

1,000 gal. 

Figure 10. The A&M Mobile 

Desalination Unit. 

The unit is shown at a well site in 

Washington County, Texas in 

early 2006. The unit took brine 

from the fiberglass storage tank 

(shown on the right of the 

picture) performed pre-treatment 

by micro-filtration, then desalination by RO. Fresh water 

was directed to the tank to the left 

rear of the unit. 

Contaminated 

Surface water 

-1,500 tds. 

Gas well produced 

brine - 3,600 tds. 

In addition to testing the capability of different types of membranes, the unit has power 

transformers to utilize oil field power and an electrical meter to measure power 

consumption, one of the highest cost factors in desalination. The cost of desalination is 

directly related to the power used to pump brine past the filters. As salinity increases, 

power consumption rises. Data from four different field sites are given for comparison, 

collected on four types of saline feed brines. Table 4 shows this comparison of electrical 

power costs. 

$.65 $1.25 $1.90 $0.08 

$2.50 $2.00 $4.50 $0.19 

Oil well produced 

brine -50,000 tds 

$2.20 $6.00 $8.20 $0.34 

Gas well produced 

brine - 35,000 tds 

$2.00 (est.) $4.20 (est.) $6.20 (est.) $0.26 
The information in the Table should be used for estimates only. The prime performance 

monitor should be salt rejection efficiency, then operating cost. Two types of pretreatment micro-filters were used. In addition, a new low pressure RO filter was 

employed in the oil well test. Salt rejection efficiency of the low pressure membrane was 

lower than the filter used earlier. 

The energy cost of operating the desalination facility represents roughly one-third of the 

total operating costs. Using one of the examples given in Table 4, for desalination on-site 

of brackish produced water from a gas well, the total operating costs would he less than 

$10 per 1,000 gallons of fresh water produced ($.42 per bbl). For comparison, the 

operator of the well pays approximately $1.50 per barrel to tmck the water to a 

commercial salt water disposal well. For this example, the field data indicate that a 

dedicated desalination unit on the site could reduce the water hauling volume by 50% and 

the total water hauling costs by almost 20%. For this example, the land owner was 

offered the fresh water for no cost. Under some circumstances, the fresh water represents 

income to the operator. 

EXPERIMENTAL 

Field Trials 

In the fall of 2004, tests were run on new membrane types, new backwashing procedures 

and new cleaning procedures were planned to extend operating time of the filters. A 

small scale flat sheet membrane test work station was constrncted to use in the pilot plant. 

The unit operates either at low or high pressures and tests membrane performance with 

less effort than with large scale systems. The unit is being used to evaluate the 

performance of new types of low pressure membrane. It will also be used to evaluate new 

types of cleaning materials being developed in a separate DOE project. 

Figure 3. The small 

scale membrane test 

rig. 

This unit can test separation 01 

fluids of five liters volume or 

greater. The system allows 

operations to 1,000 psi with flal 

membrane sheets. This unit is 

being used to test actual field 

produced water brought to the 

pilot plant from Key Energy’s 

Grimes County disposal well. 
The project will continue a three-year A&M program studying the beneficial re-use of 

produced water resources from oil and gas operations. We expect that new materials and 

procedures, when used to desalinate produced water, will reduce treatment costs by 50% 

or greater. 

Testing using our prototype portable units has shown that membrane filtration technology 

can treat such brines and recover fresh water for beneficial use at a cost comparable to 

disposal. Now new technology has been developed that offers the potential to allow RO 

desalination to be employed for large-volume systems and to recover a greater fraction of 

fresh water from the produced brine. The technology offers significant savings in 

produced water management costs to operators, while the resulting fresh water can be 

used for rangeland and habitat restoration, stream flow augmentation, or treatment of 

saline ground waters threatening fresh water aquifers. 

Efficiency of Desalination Unit 

Desalination Efficiency 

RO membranes are chosen on the basis of salt rejection, longevity, and efficient 

transmembrane pressure (TMP). The membrane being used for the majority of the testing 

program has performed well over a range of salinities and overall brine compositions. 

Table 1 shows the results of a one-pass throughput using membrane “DM. 

Table 2. Salt Rejection Efficiency 

Raw 

Analyte Feed RO filter Reduction 

permeate 

Alkalnntv, Total 

as CaCO3’ ...... 188 34 

%03 ,,, , ,, < 1.2 1 

Hydroxide ........... as ...... OH: . . < 1 1 

gwum I ..73 . . 1 

HC03 41 

Carbonate as ............ 

............. 

,Conductivity I 33000. 2270 ................................ 

2 

23 

5 

Sodium ............ ’ 11570 416 .............. n ’ 87 34 

~ 1664 4 ......... 

.... ......... 

P H 7 .......................... 6.1 .. Solids, Total i 

Dissolved 

TDWl80 C 38300 1291 

82% 

81% 

n/d 

nid 

93% 

99% 

97% 

98% 

96% 

96% 

61% 

99% 

91% 
The example shown in the Table reveals that permeate from the RO treatment of a saline 

produced water will likely meet NPDES standards for potable use. 

Operating Cost and Power Usage 

The two major cost components of oil field brine desalination are (1) removal of 

suspended solids (pre-treatment) and (2) removal of dissolved solids (desalination). 

Desalination costs of saline brines are similar to conventional seawater desalination. 

Estimated costs for several seawater desalination facilities along the California coast 

range from $2.25 to $3.70 per 1,000 gallons ($711 to $1171 per acre-foot), a substantial 

decrease from the 1993 cost estimates of $3.17 to $12.70 per 1,000 gallons ($1000 to 

$4000 per acre-foot). During the same period, the cost of water from other sources in 

California has steadily increased. In 1991, the Metropolitan Water District of Southern 

California (“MWD) paid approximately $27 per acre-foot for water delivered from the 

Colorado River and $195 per acre-foot for water from the California Water Project. Now, 

MWD pays an average of $460 per acre-foot for delivered water. 

In Texas, the’three proposed desalination facilities on the Gulf Coast have cost estimates 

ranging from $3.58 to $4.23 per 1,000 gallons ($1,000 to $1,300 per acre-foot). These 

cost estimates include a “transference” cost representing the cost to deliver raw water to 

the RO facility and to deliver fresh water to existing municipal water lines. The estimates 

also include amortization of the facility (-25 years) and operation and maintenance costs. 

The economic justification for desalination of oil field brine is entirely different than the 

cited examples. O&G production savings would come from the deferred cost of disposal 

of the excess brine from operating facilities. Enhanced oil recovery processes also require 

water that must have relatively low salinity. Rather than utilize fresh water from ground 

water sources, the industry has tried desalination of produced water extensively. One 

large-scale program to desalinate brackish produced water was in Crockett County Texas. 

Marathon Oil Company constructed and operated a facility producing 714,000 gallons 

per day (17,000 barrels per day) to supply feed water for steam flooding operations. The 

cost of the water treatment (no infrastructure costs) was reportedly less than $2.50 per 

1,000 gallons. The steam flood was projected to boost oil production in the Yates Field 

by more than 100,000 barrels of oil. The facility was deactivated when more advanced oil 

recovery technology was developed. 

More recently, pilot tests of a produced water treatment by membrane technology was 

performed in the Burgan Field, Kuwait to test the removal of dispersed oil. Over a fivemonth period the unit operated at an oil rejection efficiency of 83% to 89%. 

Experience has shown that membranes can be effective pre-treatment techniques and RO 

membranes can provide desalination at less cost than the cost of brine disposal. Testing 

has also shown that desalinating brackish oil field brine is more expensive that 

desalination of BGW but concentrate disposal will be less expensive. Newer desalination 

technology is also continuing its advance in the field of industrial, food, and 

pharmaceutical industries. 

The A&M Mobile Desalination Unit was constructed to test both pre-treatment by 

membranes and RO desalination at field sites. Different types of membranes are tested 

and RO salt rejection efficiency can be determined directly. It is equipped to run either 
single stage or multi-stage membrane treatments and can he configured either for parallel 

or series membrane flows. The unit is shown in Figure 4 in Washimtoton Countv, Texas. 

$.65 

$2.50 

$2.20 

C, 

$1.25 $1.90 $0.08 

$2.00 $4.50 $0.19 

$6.00 $8.20 $0.34 

Figure 4. The A&M Mobile 

Desalination Unit. 

The unit is shown at a well site in 

Washington County, Texas. The 

unit took brine from the 

fiberglass storage tank (shown on 

the right of the picture) 

performed pre-treatment by 

micro-filtration, then desalination 

by RO. Fresh water was directed 

to the tank to the left rear of the 

unit. 

$2.00 (est.) 

RESULTS AND DISCUSSION 

$4.20 (est.) $6.20 (est.) $0.26 

In addition to testing the capability of different types of membranes, the unit has power 

transformers to utilize oil field power and an electrical meter to measure power 

consumption, one of the highest cost factors in desalination. The cost of desalination is 

directly related to the power used to pump brine past the filters. As salinity increases, 

power consumption rises. Data from four different field sites are given for comparison, 

collected on four types of saline feed brines. Table 2 shows this comparison of electrical 

power costs. 

Table 3. Representative power costs of desalination of oil field brine. 

Salinity of Feed 

Brine, tds (ppm) 

Contaminated 

Surface water 

-1,500 tds. 

Gas well produced 

brine - 3,600 tds. 

Oil well produced 

brine -50.000 tds 

Gas well produced 

brine - 35,000 tds 

Power Costs Kw Hr per 1,000 gal. Permeate I 

Pre- Operating Operating 
The information in the Table should be used for estimates only. The prime performance 

monitor should be salt rejection efficiency, then operating cost. Two types of pretreatment micro-filters were used. In addition, a new low pressure RO filter was 

employed in the oil well test. Salt rejection efficiency of the low pressure membrane was 

lower than the filter used earlier. 

The energy cost of operating the desalination facility represents roughly one-third of the 

total operating costs. Using one of the examples given in Table 2, for desalination on-site 

of brackish produced water from a gas well, the total operating costs would be less than 

$10 per 1,000 gallons of fresh water produced ($.42 per bbl). For comparison, the 

operator of the well pays approximately $1.50 per barrel to truck the water to a 

commercial salt water disposal well. For this example, the field data indicate that a 

dedicated desalination unit on the site could reduce the water hauling volume by 50% and 

the total water hauling costs by almost 20%. For this example, the land owner was 

offered the fresh water for no cost. Under some circumstances, the fresh water represents 

income to the operator. 

Desalination Workshops 

TWRI and GPRI are teaming with the Food Protein R&D Science Center to propose 

establishment of an industrial waste water membrane treatment and desalination center. The 

center will allow industrial separation sciences programs to be separated &om the food science 

research center, provide research capability on new membrane techniques, and allow outreach 

teaching opportunities. 

The Membrane Technology Workshop was conducted by the Food Protein Science 

Center in March. Attendance was up 50% with 37 people in attendance. Those 

interested in attending this four day course next year can find more information and 

register at 

http:llfoodprotein.tamu.eduiseparationslsc~iucomin~.~tm 

Regulatory Relief 

We are also working with the TRC (Texas Railroad Commission), the regulatory agency 

for the oil and gas industry in Texas, and with the TCEQ (Texas Commission on 

Environmental Quality), the agency responsible for clean water regulations in Texas. The 

barriers to adoption of desalination of waste water, brackish ground water and oil field 

produced brine include political issues, community perception issues, and technical 

issues. The Governor and the TWDB have provided leadership for the State in 

developing desalination programs in Texas. However, lack of public funding, 

environmental, and regulatory issues related to desalination of produced water (and other 

inland saline waters) inhibit technology advancement of this resource. Public perception 

and acceptance of the advantages of RO desalination is unclear. Cost reduction 

advancements in technology are slowed by a lack of a clear “path to market” of new 

products and processes. Supplemental state government funding for demonstration 

projects (both sea water desalination and inland BGW desalination) is lacking. With these 

issues affecting the market for commercial development, it is clear that a more concerted 
effort is needed to develop new water resources from desalination, address conveyance 

issues associated with water transfer, and be prepared to meet the demand for the new 

resource if it were to be made available. Some selected issues are discussed below. 

The Texas Commission on Environmental Quality has been working with other state 

agencies to streamline regulations for the permitting process for disposal in deepunderground injection wells of brine produced by desalination operations. Applicants for 

permits to dispose of brine from desalination in injection wells must meet the current 

requirements for disposing of hazardous waste in Class I injection wells, including brine 

from desalination if it is classified as a waste material from “either industrial or municipal 

facilities”. Since injection wells have been used for disposal of salt water associated with 

oil and gas operations for almost a century, (as Class 2 wells), it is hoped that new 

cooperative efforts in desalination will allow deep injection wells into oil and gas fields 

for brine byproduct use in enhanced oil recovery operations. Recent private meetings 

between TCEQ and the TRC may have removed the roadblock. 

CONCLUSIONS 

Local issues that communities would identify as barriers include the perception that 

desalinated produced water is not pure enough for consumption by humans or livestock 

and that there might be environmental drawbacks to its use for plants, range, and habitat 

sustainability. It” is suggested however, that advanced technology and an improved 

regulatory climate will increase the likelihood of adoption of PWDS by water use groups 

in the state. 

Schedule for 2006 Activity 

The program calls for a research project to evaluate the treatment ofbrine generated in oil 

fields (produced water) with ultrafiltration membranes. The characterization of various 

ultrafiltration membranes for oil and suspended solids removal from produced water will 

be studied to test whether they could be a possible pretreatment method. The research 

will be designed to measure the effect of pressure and flow rate on membrane 

performance of produced water treatment of three commercially available membranes for 

oily water. Oil and suspended solids removal are to be measured by using turbidity and 

oil in water measurements taken periodically. 

Ultrafiltration Membranes 

Hollow Fiber Microfilter Membranes 

One of the new pre-treatment techniques scheduled for evaluation will be capillary 

hollow fiber membranes. Capillary (hollow) fiber elements are comprised entirely of the 

filtration medium itself (no backing material as in the other configurations that all utilize 

sheet membrane), although most fibers have a “skin” of the medium on one or both 

surfaces. 

The fiber outside diameters range from about 1 to 2 mm, with IDS in the 0.5 to 1.8mm 

range. The flow path can be either outside-in or inside-out (lumen feed); however, for all 

wastewater applications, the outside-in flow is favored, to minimize fouling. 
Capillary fiber membrane elements only apply to microfiltration (MF) and ultrafiltration 

(UF) applications (one company, Norit X- Flow, introduced a nanofiltration element, but 

has subsequently withdrawn it from the market). A problem in definition must be 

addressed in discussing MF and UF. Many membrologists use pore size to define these 

processes, with MF pore sizes ranging from 0.1 to 1.0 micrometers (microns), and UF 

membranes possessing MWCO characteristics ranging from about 1,000 to 1,000,000. 

Other experts prefer to define these processes based on their function: MF removes 

suspended solids only, while UF removes dissolved organic solute based on molecular 

weight. MWCO is Molecular Weight Cutoff (expressed in Daltons), and is the smallest 

molecular weight of an organic compound retained by a specific UF membrane. It is 

extremely difficult to relate pore size in microns (p) to MWCO in Daltons. A major 

problem is that organic molecules vary significantly in shape and size, not always in 

direct proportion to molecular weight. Although there are a number of charts and tables 

available which relate molecular weight to pore size, there is little agreement among 

them. 

REFERENCES