# 1 MEMORANDUM

TO: Jim Eddinger, U.S. Environmental Protection Agency, OAQPS

FROM: Amanda Singleton and Graham Gibson, ERG

DATE: April 2010

SUBJECT: Development of Baseline Emission Factors for Boilers and Process Heaters at Commercial, Industrial, a nd Institutional Facilities

1.0 INTRODUCTION

This memorandum discusses the processes usedto develop baseline emission factors for boilers and process heaters base d on data reported by industry in the 2008 Questionnaire for Boilers, Process Heaters, Incinerators and Other Combustion Units (ICR No. 2286.01, OMB Control No. 2060-0616, EPA Form No. 5900-122) and the 2009 Test Plan for Boilers and Process Heaters (ICR No. 2286.03, OMB Control No. 2060-0616, EPA Form No. 5900-122). ERG developed two databases: 1) a comprehensive survey databa se containing all data reported by industry during the 2008 Combus tion Survey (herein referred to as the Survey Database 1 

# ) and 2) a comprehensive emission database containing all the stack test resu lts, continuous emissions monitoring system (CEMS) data, and fuel analys is data reported in the 2008 Combustion Survey and the 2009 Phase II Test Plan (herein referred to as the Emission Database 2 

# ). A data dictionary and description of all the fields contained in the Survey Database are summarized in another

memorandum 3 

# . The standardization of reported emissi on data in both the Survey and Emission

Databases is also described in another memorandum 4



# . The development of baseline emission factors fo llowed a four-step process: First, a list of unique combustion units reported in the Surv ey Database was compiled. Next, the reported

fuels combusted and control devices installed were categorized. Third, for all units reporting emission data, all available emission data for eac h particular combustion unit were averaged and

# 2 assigned a unit-specific baseline emission factor. Fi nally, to fill data gaps at units not reporting emission data, the emission data from other units assigned to the same fuel, control device, and combustor design categories were averaged to develop an average baseline emission factor for similar types of units. Baseline emission factors were developed for 23 specific pollutants based on the fuel and

control device combinations or fuel and co mbustor design combinations utilized by the combustion devices reported in the questionnai re. These emission factors will be used to

determine the control devices necessary to meet emission limits and to estimate potential

emission reductions for the National Emi ssion Standards for Hazardous Air Pollutants (NESHAP) for boilers and process heaters at Industrial, Commercial, and Institutional facilities.

This memorandum is organized as follows:

1.0 Introduction

2.0 Grouping Data According to Fuel Type, Control Device, and Combustor Design

3.0 Development of Unit-Specific Emission Factors

4.0 Development of Average Baseline Emission Factors

5.0 Baseline Averages for Area Sources

6.0 References Appendix A: Glossary Appendix B: Fuel and Control Device Groupings Appendix C: Estimated Percent Reduc tions from Control Device Groupings Appendix D: Baseline Emission Factors for Bo ilers and Process Heat ers at Major Sources Appendix E: Baseline Emission Factors for Boilers at Area Sources

NOTE: Technical terms and acronyms used in the text, tables, and appendices of this memorandum are described in Appendix A

.

# 3 2.0 GROUPING DATA ACCORDING TO FU EL TYPE, CONTROL DEVICE, AND

COMBUSTOR DESIGN

The first step of the baseline emission factor process involved targe ting select pollutants, developing a comprehensive list of all combus tion units reported in the questionnaire, and categorizing combustion units according to sta ndardized fuel groups, control devices, and combustor designs reported the questionnaire. The pr ocedures used to characterize the qualitative data from the questionnaire into appropriate groups are discusse d in this section.

2.1 Pollutants

Baseline emission factors are specific to a certai n type of pollutant. Th is analysis targeted 23 different pollutants, all of wh ich are listed in Table 1. Alth ough data were reported for more than 24 pollutants, baseline emission factors were only developed for those listed in Table 1 because these pollutants represen t pollutants regulated under Sec tion 112 of the Clean Air Act, as amended in 1990 (CAA), they represent surrogates for pollutants regulated under the CAA, or they represent pollutants that EPA uses to quantify the human health benefits resulting from a rulemaking.

# 4 Table 1: Pollutants Assigned Baseline Emission Factors

Pollutant

Antimony (Sb) Arsenic (As)

Beryllium (Be) Cadmium (Cd)

Carbon Monoxide (CO) Chlorine (Cl 2 

# )

Chromium (Cr) Cobalt (Co)

Filterable Particulate Matter (total) (PM-filter) Formaldehyde

Filterable Particulate Matter of less than 2.5 microns (PM 2.5 

# ) Hydrogen Fluoride (HF)

Hydrogen Chloride (HCl) Manganese (Mn)

Lead (Pb) Nickel (Ni)

Mercury (Hg) Selenium (Se)

Oxides of Nitrogen (NO x 

# ) Total Hydrocarbons (THC)

Sulfur Dioxide (SO 2 

# ) Total Mass Dioxins/Furans (PCDD/PCDF)

Volatile Organic Compounds (VOC)

2.2 Developing a Comprehensive List of Combustion Units

Each record in the Data: Unit Design/Operation table of the Survey Database correlates to a single combustion unit. The information for th is table was derived from Section II.B of the Questionnaire. 5 

# In addition, small, gas-fired boilers or process heaters were reported under Section II.A of the Questionnaire. The definition of a small, gas-fired co mbustion unit is any unit firing natural gas, propane, liquefied petroleum gas (LPG), or refinery gas with a design capacity less than 10 million British thermal units pe r hour (MMBtu/hr). These groups of small combustion units, each treated as a single combus tion unit for the purpose of developing baseline emission factors, are only present in the Data: GCP and Combustion Controls table of the

# 5 Survey Database. An inventory was generated containi ng all the combustion units in the Data: Unit Design/Operation table as well as the small, gas-fired units in the Data: GCP and Combustion

Controls table. This inventory was then filtered to include only combustion units classified as boilers or process heaters at major sources of hazardous air pollutant (HAP) emissions. This resulted in a total of 13,555 unique boilers and pro cess heaters, with 7,034 of these being small, gas-fired units.

2.3 Fuel Categories

The Questionnaire provided a drop-down list co ntaining 134 different fu els and materials,

and it also allowed users to self-r eport additional types of fuels and materials not included in the list. These fuels were categori zed into one of the 11 fuel cat egories listed in Table 2. A list mapping each fuel category in Table 2 to specific fuel types reported in the survey can be found

in Table B.1 of Appendix B

. Because many boilers and process heaters fire multiple types of fuels, a fuel hierarchy was established to assi gn each multi-fuel boiler and process heater to a specific fuel category. For units firing multiple fuels, fuel categorie s were assigned based on the percentage of the total heat input contributed by each fuel. A threshold of 25 percent was used to assign a fuel category based on the hierarchy listed in Table 2. For example, if the total heat input at a unit consisted of 80 percent coal and 20 percent natural gas, it was placed in the Coal category because the unit was combusting at least 25 percent coal on a heat input basis. For a combustion unit to be classified as any fuel lower in the hierarchy, each of the fuels ranked higher must all contribute less than 25 percent to the unit’s total heat input. For example, if a combustion unit’s total heat input was composed of 20 percent coal and 80 percent na tural gas, it was placed in the Natural Gas category.

# 6 Table 2: Categorical Fuel/Material Hierarchy

Rank Fuel Category

1 Coal

2 Bagasse

3 Wet Biomass

4 Dry Biomass

5 Heavy Liquids

6 Light Liquids

7 Process Gases

8 Natural Gas & Other NonProcess Gases

9 Natural Gas at Metal Furnaces

10 Other Fuels

11 Waste

For baseline purposes, petroleum coke wa s included in the Coal category. Any unspecified type of biomass was assumed to be dry biomass. The liquid fuel categories encompass both fossil- and non-fossil-derived fuel s in liquid form, such as sludges. Emission data from tests conducted while combusting waste were not included in ba seline calculations.

2.4 Control Device Categories

Control devices reported in the Questionnaire were categorized according to their ability to remove certain types of pollu tants. Because certain control de vices target different types of pollutants, the pollutants themselves were fi rst categorized into groups. Table 3 shows the groupings created for these pollutants.

# 7 Table 3: Pollutant Groupings Category Constituent Pollutants

Hydrogen Chloride (HCl)

Hydrogen Fluoride (HF)

Chlorine (Cl 2 

# ) Inorganic HAP and SO 2



# Sulfur Dioxide (SO 2 

# )

Mercury (Hg) Mercury (Hg)

Filterable Particulate Matter Particulate Matter (PM) PM 2.5


# Antimony (Sb)

Arsenic (As)

Beryllium (Be)

Cadmium (Cd)

Chromium (Cr)

Cobalt (Co)

Lead (Pb)

Manganese (Mn)

Nickel (Ni) Non-Mercury Metallic HAP

Selenium (Se)

Carbon Monoxide (CO)

FormaldehydeOrganic HAP and CombustionBased Pollutants

Oxides of Nitrogen (NO x 

# )

# 8 Category Constituent Pollutants

Total Hydrocarbons (THC)
Volatile Organic Compounds (VOC)

Total Mass Dioxins/Furans Total Mass Dioxins/Furans (PCDD/PCDF)

Control devices were reported in many separate sections in the Questionnaire. All control device data reported with the emission te st and CEMS data, as well as in the Data: Control

Device table in the Survey Database, were iden tified for each combustion unit. Each control configuration reported for a boiler or process heater was further categorized to reflect only the

control device or devices that are effective at removing any of the pollutants in Table 3. Control

devices that have little or no e ffect on any of the pollutants listed in Table 3 were classified as having no control equipment installed. For exampl e, selective catalytic reduction (SCR) is not effective in reducing the concen tration of any pollutants listed in Table 3. Thus, any combustion unit that employed SCR was classified as ha ving no air pollution control device (APCD). Similarly, if a combustion unit reported a control c onfiguration of an elect rostatic precipitator coupled with SCR, the “total baseline control” wa s standardized to “Electrostatic Precipitator.” Further, if a unit reported more than one control device that was effective at removing a particular pollutant, the most effi cient control device was included inthe “total baseline control.” For example, if a unit reported a multiclone and electrostatic precipitator, the total baseline control was standardized to “Electrostatic Precipitator.” These standardized control configurations were classified into groups based on their

effectiveness in the removal of the pollutants listed in Table 3. Control groups were created for Inorganic HAP and SO 2 

# , Metallic HAP, Mercury, and Particul ate Matter. Because add-on control technologies reported in the Ques tionnaire do not achieve reductions in dioxin/furan, organic HAP, CO, or THC, no control groups were assigned to the Organic HAP group. For each group of pollutants, control devices were ranked accord ing to their effectiven ess and assigned to a group. The lowest numbered groups represent the best -performing controls for a particular set of

# 9 pollutants. For example, a wet scrubber is recogn ized to be the most effective control device at removing acid gases in the Inorganic HAP and SO 2 

# group. Thus, a wet scrubber would be assigned to “Control Group 1” for those pollutants. A wet scrubber is also expected to remove modest amounts of particulate matter and meta llic HAP, and it was assigned to “Control Group 3” for the Metallic HAP group, behind spray drye r/fabric filter and spray dryer/electrostatic precipitator control conf igurations. A list of the standard ized “total baseline control” configurations and their groupi ngs for Inorganic HAP and SO 2 

# , Mercury, Particulate Matter, and

Metallic HAP can be found in Tables B.2.A through B.2.D, respectively, of Appendix B.

2.5 Combustor Designs

Because the formation of organic HAP is influenced by the design of a combustion chamber, boilers and process heaters firing solid fuels were classified according to combustor design. Combustor design categories depended onthe fuel category to which the unit was assigned. Table 4 lists the combustor design s ubcategories within ea ch fuel category.

# 10 Table 4: Combustor Designs Fuel Category Combustor Designs

Fluidized Bed

Pulverized Coal Coal

Stoker/Sloped Grate/Other

Dutch Oven/Suspension Burner

Fluidized Bed

Fuel Cell

Gasifier Bagasse, Wet Biomass, and Dry Biomass

Stoker/Sloped Grate/Other

Residual/Heavy Liquids N/A

Distillate/Light Liquids N/A

Process Gases N/A

Natural Gas N/A

Other Non-Process Gases N/A

Other Fuels N/A

Stoker boiler designs include spreader stokers , overfeed stokers, and mass feed stokers. These boilers feed fuel to a grate, and forced air and combustion controls coordinate the air and fuel supply to the boiler. Pulverized coal boile rs pulverize the coal down to a powder and then inject the powdered fuel and air into the co mbustion chamber, where the fuel combusts in suspension. Both Dutch ovens and suspension burn ers are often designed to handle fuels with higher moisture contents (e.g., logging and timber residue, bagasse). In Dutch ovens, the fuel is distributed onto grates, and air flows up thr ough the grates to provide oxygen for combustion, cool the grates, and dry the fuel. Underfire air partially burns the fuel, and then combustion of

# 11 the volatile gases is completed ina secondary chamber. For suspen sion burners, fuel particles are combusted after being pneumatically suspended in an airstream. Combustion units were assigned to a combus tor design based on the information reported

in the Data: Unit Design/Operation table of the Survey Database. If a unit did not enter combustor design information, or if the combustor design was reported as a type other than those listed above, it was placed in the Stoker/Sloped Gr ate/Other category, as st oker designs represent the majority of boilers and process heat ers designed to burn biomass or coal. Some emission data represents more than one combustion unit. Inthese cases, the combustor design for each individual combustion unit was reviewed. If all of the units shared the same combustor design, that common combustor de sign was used to characterize the data. If the multiple combustion units represented multiple co mbustor designs, the data was not used for

baseline calculations because itdid not belong to any combustor design subcategory. Instead, its combustor design category was labele d as “Multiple Combustor Designs.” Sometimes a combustion unit reported more th an one type of combustor design in the Survey Database, and a hierarchy was used to cl assify that unit in one of the combustor design categories. For coal units, the hierarchy was pul verized coal units, followed by fluidized beds and then stokers. Other designs not classified as pulverized coal , stoker, or flui dized bed were included in the stoker design category. For biom ass units, the hierarchy was fluidized bed, followed by stokers (including slope d grate), Dutch ovens and suspension burners, fuel cells, and then gasifiers. Other designs not classified as stoker, fluidized bed, fu el cell, Dutch oven, or gasifiers were included in the stoker category.

3.0 DEVELOPMENT OF UNIT-SPECIFIC EMISSION FACTORS

Before an average baseline emission factor c ould be developed for a particular pollutant, each combustion unit was first assigned its own unit-specific emission factor, where data were available. The process of assigning unit-specific emission factors is discussed in this section.

# 12 3.1 Selecting the Data Source for Unit-Specific Data Averages

Emission data was reported in several sec tions of the 2008 Combustion Survey, and some sources reported additional emission data under the 2009 Phase II ICR Test Plan. Only emission

data that could be standardized to common un its of measured were used to determine unitspecific emission factors. The procedures used to standardize emission data are discussed in

another memorandum. 4 

# Standardized emission test data , CEMS monitoring data, and fuel analysis data were averaged for each boiler reporting these data. For units reporting multiple types of emission data, Table 5 shows the hierarc hy for determining which data source was used

as the basis for the baseline emissi ons at the boiler or process heater.

Table 5: Hierarchy for Determining Uni t-Specific Baseline Emission Factors
Rank Condition

1 If a unit had emission test averages and CEMS data averages, and the values were within the same order of magnitude, CEMS and emission test averages were averaged together.
2 If a unit had emission test and CEMS da ta averages, and the values were not within the same order of magnitude, only the emissi on test average was used.
3 If a unit had only an emission testaverage, that value was used.

4 If a unit had only CEMS data, the averag e of the reported CEMS data was used.

5 If an uncontrolled unit designed to burnliquid fuels had no emission test or emission monitoring data but reported fu el analysis data for metallic HAP, mercury, or chlorine (standardized to hydr ogen chloride), the average of all the standardized fuel analysis data in the unit’s fuel cate gory (light or heavy liquid) was assigned as the unit’s baseline emission factor.

6 Boilers or process heaters with no emission test or CEMS data, as well as liquidfired units with no fuel analysis data, were not assigned a unit-specific emission factor and were assigned to an average ba seline emission factor, as discussed in Section 4.

3.2 Assigning Appropriate Fuels and Control Devices

Similar to how unit-specific emission factor values came from different data sections of the survey, fuel and control device data were often reported in multiple sections of the survey.

Tables 6 and 7 show the hierarchies used to de termine the fuel and control device, respectively,

# 13 for each unit-specific emission factor.

Table 6: Hierarchy for Determining Fuel s for Unit-Specific Emission Factors
Rank Source

1 If emission test or CEMS data were av ailable, the fuels reported during these tests or monitoring periods were used. Tests on multiple fuels or control configurations were assigned separate reco rd identifiers, as discussed in Section 3.1.1
2 Small, gas-fired units (as defined in Section 2.2 above) located at refineries (NAICS code 324) were assumed to be combusting refinery gas.
3 The remaining small, gas-fired units (a s defined in Section 2.2 above) were assumed to be combusting natural gas.

4 A combination of all fuels listed as being routinely combusted for that specific combustion unit, as listed in the Data: Materials Combusted table of the Survey Database.
5 The fuel associated with the design capaci ty of the combustion unit, as listed in the Data: Unit Design/Operation table of the Survey Database.

6 A combination of all fuels listed as bei ng combusted for that specific facility, as listed in the Data: Fuel Analysis Background Information table of the Survey Database.

Table 7: Hierarchy for Determining Control De vices for Unit-Specific Emission Factors

Rank Source

1 If emission test or CEMS data were avai lable, the control de vices reported to be installed during these tests or monitoring periods were used. Tests on multiple fuels or control configurations were a ssigned separate recordidentifiers, as discussed in Section 3.1.1.

2 A combination of all current control de vices reported to be installed on the combustion unit, as listed in the Data: Control Device table of the Survey Database.
3 If no control device information was re ported for a combustion unit, it was assumed to have no add-on control devices.

4 Because cyclones are often considered integral equipment to a boiler and not an add-on control device, units combusting co al and/or biomass that did not report having any controls installed were assu med to have a cyclone installed for metallic HAP and particulate matter control. The “total baseline control” category for these units remained classifi ed as having no HAP control, but solid fuel boilers without reported controls and with cyclone/multiclone reported controls assigned to the same control group for metallic HAP and particulate matter. .

# 14 After the preferred data source for fuels co mbusted and control devices installed were determined, the reported fuels were assigned to fuel categories described in Section 2.3, and the reported control devices were assigned to c ontrol groups, as described in Section 2.4. These categories allowed baseline emission factors to bedeveloped for each combination of fuel and

control device. Several times, combustion units reported diffe rent fuel and control configurations

associated with emission data than the controls and fuels reported with monitoring data. In these cases, the fuel and control device data from both sources were reviewed, and the data deemed most representative of current operations were assigned to the unit. Routinely combusted fuels were reported in the Data: Materials Combusted table of the Survey Database. Current control device data were reported in the Data: Control Device table of the Survey Database. The fuel and control information reported with the testi ng and monitoring data were compared to these tables to determine the most representativefuel and control conf iguration. Emission and monitoring data for alternate fuel or control configurations at th e unit were not considered when calculating a unit-specific baseline emission fact or, but they were included when calculating average baseline emission factors for units with si milar fuel and control de vice configurations.

3.3 Emission Test and CEMS Data Averages

Emission data averages were created using the standardized data in the Data: Emissions

Test and Data: CEMS tables of the Emission Database. If a unit reported the results of a stack test to be non-detect, the detec tion limit was used as the basis for the average. Emission test data were available for all pollutants listed in Ta ble 3 of this memorandum. Monitoring data was reported in the Survey Database on a daily average basis for CO, SO 2 

# , NOx, and Filterable PM. Facilities were unable to report emission monitoring data as non-de tect in the Survey Database because the template to enter CEMS data required a numerical value. Many combustion units reported emission test information for multiple fuel and control configurations. For example, some units reported contro l configurations that represent current control configurations presently installed on the unit, as well as control device configurations that were installed prior to complying w ith the 2004 vacated NESHAP for Industrial, Commercial, and Institutional Boilers and Process Heaters. Other units th at tend to operate on

# 15 multiple fuel types may have reported multiple stack tests; for example, one unit may have reported a test based on firing natural gas and another reported a test while firing fuel oil. To appropriately group emission test and monitoring data, a reco rd identifier wa s created to distinguish between different combinations of fuel and control device configurations. Next, the average (mean) of all the emission test runs with the same record identifier was calculated. For combustion units with only one fu el and control device combination, the record number was assigned as “1.” For combustion units with multiple combinations of fuel and control device configurations, additional record numbers were assigned. For example, if a

combustion unit with a wet scrubbe r reported two emission tests, on e burning coal and the other burning oil, two record identifiers were given. The coal/wet scrubber co mbination was assigned a record number of “1,” whereas the oil/wet scrubber combination was assigned a “2.” The maximum number of record identifiers assigned to a combustion unit was four, representing four unique combinations of fuel type and control device configurations. An average (mean) of all the monitoring data with the same record identifier was also calculated. For most sources, this was a 30-day av erage, but some sources reported multiple 30- day periods in the Survey Database. For combus tion units that reported both emission test and monitoring data with similar fuel and control configurations, the same record identifier was used

for both sets of data to allow the two datasets to be average d, when deemed appropriate. The

calculated means for the emission test and monito ring data were compare d, and if the mean of each dataset was on the same order of magnitude, the emission test and emission monitoring data were averaged together and assi gned to the unit-specific baseline emission factor. If the emission test and emission monitoring data were not of the same order of magnitude, only the average

emission test data were used to establish baseli ne emissions for the unit. An order of magnitude

was defined to be within a factor of 10.

3.4 Fuel Analysis Data Averages

The process of standardizing mercury and chlo rine fuel analysis concentrations into

standardized emission factors is discussed in another memorandum4 

# . Fuel analysis data from uncontrolled liquid fuels were standardized for chlorine (converted to HCl), Hg, and other metals (Sb, As, Be, Cd, Cr, Co, Pb, Mn, Ni, Se). Because these HAP are fuel-based contaminants and

# 16 not products of combustion, the constituents withinthe fuel are expected to be emitted in the exhaust gas. Because the liquid fuels are ofte n delivered to a facility a nd used in multiple combustion units at the facility, fuel analysis data were re ported in the Survey and Emission Databases at the facility level. As a result, unit-specific emission averages could not be ge nerated. Instead, a list of uncontrolled combustion units designed to burn liquid fuels and that also reported combusting liquid fuels as per Section 2.3 above was develope d from the Survey Database. Next, all of the fuel analysis data for liquid fuels at facilities with an uncontrolled liqui d unit were identified and classified as either heavy or light liquids according to Table B.1 of Appendix B of this memorandum. Because purchased liquid fuels, such as fuel oils 1 through 6, are subject to ASTM specifications and are expected to be relatively homogenous from delivery to delivery, fuel analysis averages were not calculated fo r a specific facility or unit. Instead, each uncontrolled liquid unit was assigned to an average baseline emission factor that was calculated by taking the mean of all the standardized fuel anal ysis data for bio liquids, diesel fuel, jet fuel, kerosene, and #2 and #4 oil for uni ts in the light liquid fuel category, and the mean of all standardized fuel analysis data for black liquor, #5 and #6 oil, r ectified methanol, red oil, and onspec used oil for units in the h eavy liquid category. For example, f acilities A and B each have an uncontrolled unit combusting distillate liquid fuel, and each facility also reported fuel analysis

data for chlorine. Both combustion units woul d have each been assigned the same HCl fuel analysis average generated for light liquids. An interquartile range (IQR) analysis was performed for HCl and Hg since baseline emissions of both pollutants directly affect the estimated impacts analysis for this rulemaking. An IQR analysis is used to determine dispersi on of data points in a range, and to eliminate outlying data points from consideration. A da ta average excluding outly ing data points was generated for HCl and Hg for both the Heavy and Light Liquid fuel categories. These averages

were used as the unit-level baseline emission f actors for each applicable liquid-fired combustion

unit. The results of this analysis are presented in Appendices D-5a through D-5d. Some fuel analysis data were reported as a mi xture of fuels. If a liquid fuel was reported as a mixture, the corresponding data were not used to generate an average. Fuel analysis data for any type of sludge was not used to ca lculate fuel analysis averages.

# 17 4.0 DEVELOPMENT OF AVERAGE BA SELINE EMISSION FACTORS

For units that did not report emission test, CEMS, or fuel analysis data for one of the pollutants in Table 1, average baseline emission f actors were developed using data from other boilers and process heaters with similar controls, fuels, and com bustor designs. In several cases, it was possible for certain pollutants to be based on unit-specific data (whe re data was reported), and the data gaps not reported were filled with average baseline emission factors. The process of identifying data suitable for use in an average baseline emission factor and calculating the average baseline emission factors is discussed in this section.

4.1 Baseline Criteria

Baseline averages were developed to represen t emissions from units firing similar fuel types that have similar control devices. Any emission test or emission monitoring data reported in the Survey Database when combusting any amount of waste ma terial were not included in baseline average calculations. Fuel analysis data for liquid wastes, orfuel analysis data that were reported for a combination of liquid fuels and waste, were not used in baseline average

calculations. The definition of waste is detailed in another memorandum7 

# . While baseline averages were calculated for the “Other” fuel category, they were not usedbecause all the units in the boiler and process heater inventory were assigned to one of the other nine fuel categories

in Table 3.

4.2 Development of Averages To calculate an average baseline emission f actor for each polluta nt, all unit-specific emission factors assigned in secti on 3.0 were averaged for similar gr oups of controls, fuel types, and combustor designs. Because inorganic HAP and SO 2 

# , metallic HAP, Hg, and PM are fuelbased HAP that can be controlled with add- on pollution control devices, the unit-specific emission factors were averaged across all units with a common fuel category and control group. Formaldehyde, NO x 

# , and CO, are combustion-based pollu tants, and their emissions are influenced by the design of the combus tion chamber. Further, emissions of NO x 

# and CO can be affected by NO x 

# controls such as low-NO x 

# burners, overfire-air, or fl ue gas recirculation. As a

# 18 result, the unit-specific emission factors were av eraged across all units with a common fuel category, combustor design, and NO x 

# control configuration. Baseline averages for THC and PCDD/PCDF are also driven primarily by the de sign of the combustion chamber, and the unitspecific emission factors were averages across all units with a comm on fuel and combustor design category. Based on the data reported unde r Phase II, emissions of THC and PCDD/PCDF at units firing natural gas and refinery gas differed significantly depe nding on whether the unit was equipped with NO x 

# controls, so baseline emission factors for THC and PCDD/PCDF at these gas-fired units were established by averagi ng data from other gas-fired units with similar

NO x 

# control configurations.

4.3 Filling Data Gaps

After calculating average emission factors for each of the pollutants in Table 1 for the unique combinations of fuels, control device s, and combustor designs, there were some pollutants that did not have any emission data available to calculate an average baseline emission factor. For inorganic HAP and SO 2 

# , metallic HAP, Hg, and PM, control efficiencies were assigned to the control groups based on literature available on the pollutant removal efficiencies of various control devices. A list of the pollu tant-specific percent reductions can be found in Appendix C. The percentages list ed in Appendix C are the expect ed reductions a given control device could achieve compared with the level of emissions without control devices installed. There were no data gaps for the organic HAP pollutants for gaseous and liquid fuels. The average baseline formaldehyde emissions from coal-fired fluidized bed boilers were approximated using the average emission from coal -fired stoker/sloped gr ate/other boilers. For THC, formaldehyde, and NO x 

# emissions from Dutch oven/suspension burners firing wet biomass, the baseline emissions were approximated using the emissions from Dutch oven/suspension burners firing dry biomass. For th e one unit that was classified as a gasifier burning dry biomass, its emissions assigned to the emissions from the dry biomass “Stoker/Sloped Grate/Other” category because gasifier is an “other ” type of unit. Data gaps in the Bagasse fuel category were filled using the Wet Biomass averages from the same subcategory because Bagasse is consideredto be a very wet type of biomass.

# 19 4.4 Review of Outlier Data

After baseline emission factors were developed for each possible subcategory, the average values were reviewed to look for uncharacteristically high or lo w values. Unexpectedly high or low values were flagged, and the individual data points that comprised the average were investigated. An example of a flagged value for a given pollutant would be if the uncontrolled

baseline emission factor was lower than that of any other control group for that same pollutant and the same fuel category. The unit-specific averages were inspected fo r these flagged values to determine if a problem existed with any of the re ported data used in the averag e. Data were disregarded from the analysis when errors were identified in units of measure, fuels burned, or control devices installed. In addition, if emission monitoring data was reported during periods of start-up, shutdown, or malfunction, these data were excludedfrom the analysis. When possible, changes were made to the reported data in the Emissi on Database, and the updated values were used to

recalculate baseline emission factor s. If reported data wa s identified as an outli er, it was not used in the average baseline emission calculations bu t was used for a unit’s site-specific baseline

emission factor. In addition to reviewing the average baseline values for outliers, the full range of unitspecific emission data was also reviewed to iden tify any uncharacteristically high or low values that could over or underestimate the expectedemission reduction estima tes resulting from the proposed rule.

4.5 Establishing Baseline Emissions for PM 2.5 

# and VOCs

Baseline emission factors for particul ate matter less than 2.5 microns (PM 2.5 

# ) were estimated as a percentage of filterable PM baselines. PM 2.5 

# is a select portion of total filterable PM based on particle size, so it is correct to assume that a portion of total filterable PM will always be PM 2.5 

# . The ratios of PM 2.5 

# to total filterable PM were based on reported emission test data for both pollutants, and were specific to fuel types and control devices. The fractions of

PM 2.5 

# ranged from 0.07 to 1. Details on the fractions for each fuel and control device group are presented in Appendix D-3. Using the fuel category and control de vice configuration assigned to

# 20 each unit, a baseline emission factor for PM 2.5 

# was estimated by multiplying the appropriate

PM 2.5 

# fraction by the filterable PM baseline emission factor assigned to the unit. Similar to the method used to generate PM 2.5 

# baseline emission factors, VOC emission factors were generated as a portion of THC base line emissions. Monitoring data reported from

Phase II Test Plan was used to calculate an average (mean) VOC-to-THC ratio that could be applied to all THC baseline emission factors. Only data from Phase II Test Plan was used because it was the only source of data that co rrelated THC and VOC data points over a multi-day period. VOC ratios were not calculated for eachsubcategory because there were only data available for six total boilers and process heat ers. A VOC-to-THC ratio was generated for each monitoring data point that was not noted to be during a period of start-up, shutdown, or malfunction. A statistical quartile analysis was performed on the se t of ratios to remove any outliers. The remaining ratios were then averag ed to obtain a total VOC -to-THC ratio, which was applied to each THC baseline emi ssion factor subcategory. It was assumed that this ratio would not fluctuate between different fuel categories or control devices. Based on monitoring data available from these six sources, THC emissions are composed of 57 percent VOCs. The data used to calculate this percenta ge is presented in Appendix D-4.

4.6 Establishing Baseline Emission s for Total Mass Dioxins/Furans

Baseline emission averages for total mass dioxi ns/furans were calculated differently than the rest of the pollutants due to the way dioxin/fu ran data was reported in the Emission Database. Facilities were able to report a total mass emission value or to tal mass values for 17 individual dioxin/furan congeners and a group of “other congeners.” Table 8 lists the dioxin/furan congeners used to calculate total dioxin/furan emissions.

# 21 Table 8: Dioxin/Furan Congeners Total Mass Dioxin/Furan Congeners

1,2,3,4,6,5,7,8 OCDD 1,2,3,7,8 PeCDD

1,2,3,4,6,5,7,8 OCDF 1,2,3,7,8 PeCDF

1,2,3,4,6,7,8 HpCDD 1,2,3,7,8,9 HxCDD

1,2,3,4,6,7,8 HpCDF 1,2,3,7,8,9 HxCDF

1,2,3,4,7,8 HxCDD 2,3,4,6,7,8 HxCDF

1,2,3,4,7,8 HxCDF 2,3,4,7,8 PeCDF

1,2,3,4,7,8,9 HpCDF 2,3,7,8-TCDD

1,2,3,6,7,8 HxCDD 2,3,7,8-TCDF

1,2,3,6,7,8 HxCDF Other Congeners

Only Phase II Test Plan data was used to ge nerate dioxin/furan averages because Phase I data was not received for individual congeners, and data reported in Phas e I were not reported on a total mass basis. For each emission test, a tota l mass dioxin/furan value was generated for each run. If the facility reported a total dioxin/furan value or detection limit, it was used. If no

numerical value or detection limit was provided, the sum of the values of the congeners listed in

Table 8 was used to calculate a total mass of dioxin/furan emissi ons. The total dioxin/furan value for each run was averaged to get a test averag e specific to a combustion unit. These averages were used as unit-specific emission factor s for their respective combustion units. To calculate average baseline emission factors, these test averages were averaged across units in the same fuel and combustor design. Ba seline emission factors were not generated for Toxic Equivalent (TEQ) dioxins/furans. Baselin e emission factors for total mass dioxins/furans for major and area sources are presented in Appendices D-1 and E, respectively.

# 22 5.0 BASELINE AVERAGES FOR AREA SOURCES

Although a small number of area source facili ties with boilers and process heaters reported emission data in the Survey Database, ther e were not sufficient data available to create a separate set of baseline emissi on averages for area source boilers. Instead, the average baseline

emission factors calculated for ma jor source boilers and process heaters were used to establish

the baseline emissions from area source model units used to estimate the impacts of the proposed rulemaking. Based on data available in the Survey Data base, Title V permits for area source boilers,

and data from the National Forest Service Fu els for Schools program, most boilers at area

sources are uncontrolled 1,8 

# . Furthermore, the distribution of control devices on solid fuel area source boilers units in Pennsylvania and Wiscons in indicate that 8 pe rcent of wood/biomass boilers greater than 10 MMBtu/hr inthese two states do not have a ny listed control, and the other 92 percent have an mechanical collector (e.g., multiclone, cyclone) control device installed. Moreover, 53 percent of coal boilers in Penns ylvania do not have any listed control. The remaining boilers firing solid fuels at area source s have a mechanical collector control device. Using this information on control devices, we as signed average baseline emission factors for the area source model units according to Table 9 below.

# 23 T 

# able 9: Baseline Emission Factor Assignments to Area Source Boilers Area Source Model

Unit Pollutant Type Corresponding Major Source Baseline Emission Factor Category

Fuel-based pollutants Average of wet and dry biomass for cyclone/multiclone controlled Biomass Combustion-based pollutants Average of wet and dry biomass stokers with NO x 

# control

Fuel-based pollutants Cyclone/multiclone controlled coal Coal Combustion-based pollutants Coal stokers with NO x 

# control

Residual

Liquid Fuel- and combustion-based pollutants Uncontrolled heavy liquid

Distillate

Liquid Fuel- and combustion-based pollutants Uncontrolled light liquid
Notes: Fuel-based pollutants include: PM , Hg, metallic HAP, inorganic HAP, and SO 2 

# . Combustion-based pollutants include: THC, CO, PCDD/PCDF, and formaldehyde.

# 24 6.0 REFERENCES

1. Survey Database containing Results of the 2008 Questionnaire for Boilers, Process Heaters, & Other Combus tion Units (ICR No. 2286.01).

2. Emissions Database for Boilers and Process Heaters Containing Stack Test, CEM, & Fuel Analysis Data Reported under ICR No. 2286.01 & ICR No. 2286.03 (version 5).

3. McClutchey.S, and G. Gibson, ERG. Data Dictionary for Boiler, Process Heater, and Other Combustion Unit Survey Databases. April 2010.

4. Gibson, G., ERG. Standardization of Reporte d Data from the Questionnaire for Boilers, Process Heaters, Incinerators a nd Other Combustion Units, April 2010.

5. U.S. Environmental Protection Agency. 2008 Qu estionnaire for Boilers, Process Heaters, Incinerators and Other Combustion Units (ICR No. 2286.01, OMB Control No. 2060- 0616, EPA Form No. 5900-122).

6. Singleton, A., ERG. MACT Floor Analysis for the Industrial, Commercial, Institutional Boilers and Process Heaters National Emissi on Standards for Hazardous Air Pollutants – Major Source, April 2010.

# 25 APPENDIX A

GLOSSARY

# 26 Table A.1: Glossary

Term Description APCD Air pollution control device. An add-on exhaus t stack technology that reduces the concentrations of HAP in exhaust gas. Btu British thermal unit. A unit of measurement for energy.

CO Carbon monoxide. A common pollutant produced due to the incomplete combustion of fuel. HAP Hazardous air pollutant. See Table 1 for a list of all HAP associated with this rulemaking effort. Hg Mercury. This abbreviation is us ed to refer to both the mercury pollutant itself as well as the pollutant group created for it. Inorganic A pollutant category that is comprised of the pollutants hydrogen chloride (HCl), hydrogen fluoride (HF), and chlorine (Cl 2 

# ). LPG Liquefied petroleum gas. A hydrocarbon fuel derived from petroleum, stored under pressure in the liquid phase. Metallic HAP A pollutant category that is comprised of the pollutants antimony (Sb), arsenic (As), beryllium (Be) , cadmium (Cd), chromium (Cr), cobalt (Co), lead (Pb), manganese (Mn), nickel (Ni), and selenium (Se). MMBtu/hr One million British thermal units per hour. A unit of measurement for thermal energy. NO x 

# Nitrogen oxides. A grouping of binary compounds composed of the elements nitrogen and oxygen, includ ing nitric oxide (NO), nitrogen dioxide (NO 2 

# ), nitrous oxide (N 2 

# O), dinitrogen trioxide (N 2 

# O 3 

# ), dinitrogen tetroxide (N 2 

# O 4 

# ), and dinitrogen pentoxide (N 2 

# O 5 

# ). Organic An organic compound is char acterized as any compound containing carbon, not including carbonates, carbon oxides, cyanides, and allotropes of carbon. For this analys is, organic refers to a pollutant category that is comprised of the pollutants formaldehyde, volatile organic compounds, and total hydrocarbons (THC). PCDD/PCDF The total mass of polychlorin ated dibenzodioxins /polychlorinated dibenzofurans. The sum of reported masses for 18 congeners including: 1,2,3,4,6,5,7,8 OCDD; 1,2,3,4,6,5,7,8 OCDF; 1,2,3,4,6,7,8 HpCDD; 1,2,3,4,6,7,8 HpCDF; 1,2,3,4,6,7,8,9 OCDD; 1,2,3,4,7,8 HxCDD; 1,2,3,4,7,8 HxCDF; 1,2,3,4,7,8,9 HpCDF; 1,2,3,6,7,8 HxCDD; 1,2,3,6,7,8 HxCDF; 1,2,3,7,8 PeCDD; 1,2,3,7,8 PeCDF; 1,2,3,7,8,9 HxCDD; 1,2,3,7,8,9 HxCDF; 2,3,4,6,7,8 HxCDF; 2,3,4,7,8 PeCDF; 2,3,7,8-TCDD; and 2,3,7,8-TCDF. PM Filterable particulate matter (all sizes).

PM 2.5 

# A portion of total filterable particulate matter consisting of particles less than or equal to 2.5 μm in diameter.

# 27 Term Description

SO 2 

# Sulfur dioxide. A common polluta nt produced from the combustion of fuels with high sulfur content. TEQ An alternative method for quantif ying the toxicity of dioxin/furan congeners relative to the conge ner 2,3,7,8-TCDD. TEQ values used in this analysis are based on th e 2005 World Health Organization toxic equivalency factors. THC Total hydrocarbons. Refers to the total sum of hydrocarbon compounds emitted during an emission test, standardized using propane as the reference compound. VOC Volatile organic compound. Any compound of carbon, excluding carbon monoxide, carbon dioxide, car bonic acid, metallic carbides or carbonates, and ammonium carbonate, which participates in atmospheric photochemical reactions.

# 28 APPENDIX B

Fuel and Control Device Groupings

# 29 Table B.1: Fuel Category Constituents
Rank Fuel Category Inclusive Fuels

1 Coal Anthracite Coal Bituminous Coal Petroleum Coke Sub-bituminous Coal
2 Bagasse Bagasse

3 Wet Biomass Wood: Bark Wood: Unadulterated Timber

4 Dry Biomass Hog Fuel Plant-based Agricultural Residue Sanderdust Unspecified Biomass 1 

# Wood: Lumber

5 Residual/Heavy Liquids Alcohol: Ethanol Alternative Liquid Fuel Black Liquor Deinking Residuals Hexane Industrial Sludge Mixed liquid residues No. 5 Fuel oil No. 6 Residual oil Other Petroleum-based Oils Process coproduct liquid Rectified methanol Red oil (steam stripper steam condensate, incl terpenes, terpenoids, methanol, TRS) Tall oil, tall oil derivatives Turpentine Used Petroleum-based Oils (unknown spec) Used Petroleum-based Oils (on-spec)

6 Distillate/Light Liquids Animal Fat/Oils/Tallow Bio liquids Diesel fuel Jet Fuel JP-8 Aviation Fuel Kerosene No. 2 Distillate No. 4 Fuel oil Vegetable Oil yellow grease (used cooking oil)

# 30 Rank Fuel Category Inclusive Fuels

7 Process Gases Acid Gas Biogas Blast Furnace Gas CO gas Coke Oven Gas Ethane Isobutane Landfill Gas Methane Noncondensable Gas (includes stripper offgas) Petrochemical process gas Process coproduct gas Process Gas Pulp mill gas

8 Natural Gas & Other Non-Process Gases Hydrogen LPG Natural Gas Pilot Gas Propane Refinery gas
9 Natural Gas at Metal Furnaces 2 

# Natural Gas

10 Other Fuels Knots and Knotter Rejects Nitrile pitch residue Paper and Paper Residues Paper Pellets Process coproduct solid Reinjection char Stripper condensate Tire Derived Fuel (TDF) with metals removed Wax

# 31 Rank Fuel Category Inclusive Fuels

11 Waste 1,4-butanediol Boiler Cleaning agents Cardboard Cellulose fuel (balcones cubes) Coal Refuse Construction/Demolition Derived Material Contraband Envirofuel pellets/cubes Filters Fuel cubes (paper diaper clippings/refuse) Municipal Sludge Oily Paper Residues Oily Rags Paint Rags/Residues Plastics Refuse Refuse Derived Fuel (RDF) Resin Solid Residues Screen Rejects Spent Alcohol Tar Tire Derived Fuel (TDF) without metals removed Tires (whole) Toluene Used Petroleum-based Oils (off-spec) Used Solvents Waste Derived Liquid Fuel Wood: Treated

1 

## Unspecified biomass was reported in the questio nnaire as “Biomass” and was assumed to be dry.
2 

## Metals furnaces treat natural gas before combustion causing in increase in the amount of some pollutants in the fuel. While the fuel is still natural ga s, the chemical makeup of varies be tween metal furnaces and other types of combustion units. Resulting emissions are not comparable between metal furnaces and other units combusting traditional natural gas.

# 32 Table B.2.A: Inorganic and SO 2 

# Control Groupings Control Group Control Device

1 Spray Dryer Wet Scrubber Wet Scrubber

2 Dry Scrubber Dry Scrubber (Lime Injection) Scrubber (unknown)

3 Dry Sorbent Injection Duct Sorbent Injection Furnace Sorbent Injection Wet Lime Injection Wet Sorbent Injection

4 Venturi Scrubber

5 Activated Carbon Adsorption or Injection Cyclone or Multiclone Dry Electrostatic Granular Filter Electrified Filter Bed (EFB) Electrostatic Precipitator Fabric Filter Mist Eliminator No HAP APCD Control

# 33 Table B.2.B: Mercury (Hg) Control Groupings Control Group Control Device

1 Activated Carbon Adsorption or Injection

2 Fabric Filter/Dry Srubber (Lime Injection)/SNCR Fabric Filter/Wet Lime Injection Fabric Filter/Dry Scrubber Fabric Filter/Dry Sorbent Injection Fabric Filter/Duct Sorbent Injection Fabric Filter/Furnace Sorbent Injection Fabric Filter/Spray Dryer Fabric Filter/Wet Scrubber

3 Fabric Filter

4 Wet Scrubber

5 Venturi Scrubber

6 Cyclone or Multiclone Dry Electrostatic Granular Filter Dry Scrubber Dry Sorbent Injection Duct Sorbent Injection Electrified Filter Bed (EFB) Electrostatic Precipitator Mist Eliminator No HAP APCD Control Scrubber (unknown) Spray Dryer

# 34 Table B.2.C: Particulate Matter (PM) Control Groupings Control Group Control Device

1 Fabric Filter

2 Electrified Filter Bed (EFB) Electrostatic Precipitator

3 Venturi Scrubber

4 Wet Scrubber

5 Cyclone or Multiclone Dry Electrostatic Granular Filter

6 Activated Carbon Adsorption or Injection Dry Scrubber Dry Sorbent Injection Duct Sorbent Injection Mist Eliminator No HAP APCD Control Scrubber (unknown) Spray Dryer

# 35 Table B.2.D: Metallic HAP Control Groupings Control Group Control Device

1 Fabric Filter

2 Electrified Filter Bed (EFB) Electrostatic Precipitator

3 Venturi Scrubber

4 Wet Scrubber

5 Cyclone or Multiclone Dry Electrostatic Granular Filter

6 Activated Carbon Adsorption or Injection Dry Scrubber Dry Sorbent Injection Duct Sorbent Injection Mist Eliminator No HAP APCD Control Scrubber (unknown) Spray Dryer

# 36 APPENDICES C, D, E

(See Excel spreadsheets)

## 654321

Coal 0% 10% 50% 95% 95% 99% Bagasse 0% 10% 50% 95% 95% 99% Wet Biomass 0% 10% 50% 95% 95% 99% Dry Biomass 0% 10% 50% 95% 95% 99% Heavy Liquid 0% 10% 50% 95% 95% 99% Light Liquid 0% 10% 50% 95% 95% 99% Gas 1 0% 10% 50% 95% 95% 99% Gas 2 0% 10% 50% 95% 95% 99%

Coal 0% 9% 9% 82.35% 66.54% 87.13% Bagasse 0% 0% 10% 75% 75% unknown Wet Biomass 0% 0% 10% 75% 75% unknown Dry Biomass 0% 0% 10% 75% 75% unknown Heavy Liquid 0% 0% 10% 75% 75% unknown Light Liquid 0% 0% 10% 75% 75% unknown Gas 1 0% 0% 10% 75% 75% unknown Gas 2 0% 0% 10% 75% 75% unknown

Coal 0% 92.5% 95% 95% 98% 99% Bagasse 0% 40% 90% 90% 98% 99% Wet Biomass 0% 40% 90% 90% 98% 99% Dry Biomass 0% 45% 85% 85% 98% 99% Heavy Liquid 0% 80% 94% 94% 98% 99% Light Liquid 0% 80% 94% 94% 98% 99% Gas 1 0% 75% 50% 98% 98% 99% Gas 2 0% 75% 50% 98% 98% 99%

Coal - 0% 0% 70% 95% 95% Bagasse - 0% 0% 70% 95% 95% Wet Biomass - 0% 0% 70% 95% 95% Dry Biomass - 0% 0% 70% 95% 95% Heavy Liquid - 0% 0% 70% 95% 95% Light Liquid - 0% 0% 70% 95% 95% Gas 1 - 0% 0% 70% 95% 95% Gas 2 - 0% 0% 70% 95% 95%

Coal - 0% 0% 0% 43% 43% Bagasse - 0% 0% 0% 43% 43% Wet Biomass - 0% 0% 0% 43% 43% Dry Biomass - 0% 0% 0% 43% 43% Heavy Liquid - 0% 0% 0% 43% 43% Light Liquid - 0% 0% 0% 43% 43% Gas 1 - 0% 0% 0% 43% 43% Gas 2 - 0% 0% 0% 43% 43% Metals (Sb, As, Be, Cd, Co, Cr, Pb, Mn, Ni, Se) 1 

# Appendix C: Estimated Emission Reductions for Baseline Emission Factors Percent Reduction for Control Group:

Mercury (Hg) 2

- 3



## Particulate Matter (PM) 1



## Hydrogen Chloride (HCl) 4

- 5



## Hydrogen Fluoride (HF) 4

- 5 

## Fuel Category

## 654321 

# Appendix C: Estimated Emission Reductions for Baseline Emission Factors Percent Reduction for Control Group: Fuel Category

Coal - 0% 0% 0% 87% 87% Bagasse - 0% 0% 0% 87% 87% Wet Biomass - 0% 0% 0% 87% 87% Dry Biomass - 0% 0% 0% 87% 87% Heavy Liquid - 0% 0% 0% 87% 87% Light Liquid - 0% 0% 0% 87% 87% Gas 1 - 0% 0% 0% 87% 87% Gas 2 - 0% 0% 0% 87% 87%

Coal - 0% 0% 70% 95% 95% Bagasse - 0% 0% 70% 95% 95% Wet Biomass - 0% 0% 70% 95% 95% Dry Biomass - 0% 0% 70% 95% 95% Heavy Liquid - 0% 0% 70% 95% 95% Light Liquid - 0% 0% 70% 95% 95% Gas 1 - 0% 0% 70% 95% 95% Gas 2 - 0% 0% 70% 95% 95% Sulfur Dioxide (SO2) 4

- 5 

## Chlorine (Cl2) 4

- 5

5 

## http://www.deq.state.mi.us/aps/downloads/permits/CFPP/2007/297- 07/PC%20Boiler%20Case%20by%20Case%20MACT%20final.pdf 1 

## AP-42

2 

## http://www.epa.gov/ttn/atw/utility/hgwhitepaperfinal.pdf

3 

## http://www.icac.com/files/public/hgcontrol010305.pdf

4 

## http://www.icac.com/i4a/pages/index.cfm?pageid=3401Appendix D-1: Major Source Baseline Emission Factors for Organic HAP and CO for Existing UnitsFuel Category1Combustor Design2NOx Control?3Total # of Units inSubcategoryTHC(ppm @ 3%as Propane)THC # ofData PointsTotal MassDioxins/Furans(ng/dscm @7% O2)Total MassDioxins/Furans # ofData PointsCO (ppm @3% O2)CO # of DataPointsFormaldehyde(ppm @ 3% O2)Formaldehyde #of Data PointsNOx (ppm @3% O2)NOx # ofData PointsYes18.3 1 0.081 - 26.8 1No3053.8 19 1.714 11 99.4 27Yes7057.1 31 0.277 8 183.7 43No11632.0 15 0.524 4 275.5 16Yes33179.8 5 0.081 4 187.0 11No 328 459.7 52 1.207 13 272.0 36Yes56819.9 5 1.388 1 116.9 -No93722.4 5 2.181 2 357.7 -Yes-No-Yes-No2767.2 - 1.3 - 94.3 -Yes-No-Yes-No -Yes-No4976.4 2 0.739 - 357.7 -Yes1151.7 1 0.828 1 171.0 1No7114.7 2 0.040 2 112.0 3Yes-No12767.2 7 1.337 2 94.3 4Yes-No-Yes26524.6 7 0.240 1 116.9 9No 121 911.3 56 0.917 13 153.4 20Yes4522.1 2 0.127 - 83.8 2No40274.5 5 0.739 6 357.7 3Yes296.7 2 0.071 1 81.5 2No218.7 2 0.453 3 162.7 4Yes-No12276.6 8 0.742 6 147.2 6Yes-No1625.4 - 2.1 - 115.1 1Yes16207.2 10 0.127 2 126.9 9No 156 625.4 51 2.147 12 153.3 18Yes5615.1 13 0.019 4 179.1 9No 217 108.3 14 0.155 6 170.6 15Yes7124.3 48 0.467 3 31.0 17No 482 1975.1 40 0.176 5 127.2 10Yes18871.65 21 33.5 472 0.242 6 35.7 262No 8896 10.74 6 70.6 366 1.487 8 54.4 123Yes15694.09 2 102.0 3 0.805 3 87.7 3No 593 106.59 6 601.9 13 0.589 5 108.0 6Yes81165.5 62 0.107 4 42.2 34No 11852.4 41 0.005 3 31.3 34Notes:Yellow Cells:Where there is no reported data for a coal subcategory, the baseline average for coal/stoker was used to fill the data gap.Where there is no reported data for a bagasse subcategory, the baseline averages from thesame wet biomass subcategory were used to fill the data gaps. Where there is no reported data for a wet biomass subcategory, the baseline averages from the same dry biomass subcategory were used to fill the data gaps. Wherethere is no reported data for a dry biomass subcategory, the baseline average for dry biomass/stoker was used to fill the datagaps.Gas 1 -Gas 1Metals Furnaces-0.917 7Gas 2 -Heavy Liquid -Light Liquid -Dry BiomassDutch Oven/Susp BurnerFBFuel CellGasifierStoker/Sloped Grate/OtherWet BiomassDutch Oven/Susp BurnerFBFuel CellGasifierStoker/Sloped Grate/OtherBagasseDutch Oven/Susp BurnerFBFuel CellGasifierStoker/Sloped Grate/Other1.981.873.55CoalFBPCStoker/Sloped Grate/Other18.616.4518.614.026.455.405.402.9631.2518.6114.592.903.33101214--8.25-31-7119351460.3630.4630.4438.7940.56558.790.4010.5651.3811.3810.2930.7728.7940.1830.2770.1570.16291010--0.791-316315-27586Fuel Category Non-Hg Metals Control Category Total # of Unitsin SubCategory As (lb/MMBtu) As # of Data Points Be (lb/MMBtu) Be # of Data Points Cd (lb/MMBtu) Cd # of Data Points Co (lb/MMBtu) Co # of Data Points

1 234 7.06E-05 64 2.57E-06 66 4.91E-06 64 5.12E-05 23 2 255 4.47E-04 95 3.21E-06 83 8.72E-06 87 3.76E-06 6 3 23 7.97E-05 10 2.89E-06 10 4.73E-06 10 2.33E-05 2 4 5 1.14E-04 5 1.32E-06 5 5.72E-06 5 5.92E-06 3 5 61 2.48E-04 13 8.38E-06 11 4.48E-06 13 1.06E-05 -

1 - 1.01E-07 - 8.94E-09 - 3.83E-08 - 2.46E-08 -
2 2 5.06E-07 - 4.47E-08 - 1.92E-07 - 4.41E-06 -
3 - 7.96E-06 2 2.42E-07 2 1.99E-06 2 1.86E-06 - 4 14 5.06E-06 1 4.47E-07 1 1.92E-06 1 1.23E-06 -
5 - 9.10E-06 - 8.05E-07 - 3.45E-06 - 2.21E-06 -

1 1 5.93E-07 - 2.74E-07 - 6.40E-08 - 2.46E-08 - 2 83 4.16E-06 28 6.26E-07 26 1.67E-06 27 4.41E-06 10 3 27 2.41E-05 19 6.77E-07 19 4.46E-06 19 1.86E-06 3 4 17 2.97E-05 8 1.37E-05 5 3.20E-06 9 1.23E-06 - 5 43 4.95E-06 11 3.21E-05 10 7.09E-06 11 2.21E-06 1

1 8 6.64E-06 5 6.05E-08 5 9.29E-07 5 3.03E-07 3 2 96 1.60E-05 27 1.19E-07 25 8.21E-07 29 4.49E-07 8 3 12 7.35E-04 5 2.99E-07 5 7.55E-06 5 7.81E-06 2 4 12 8.80E-05 5 1.55E-06 5 5.78E-05 6 1.12E-06 - 5 105 1.91E-05 22 1.91E-07 22 6.00E-06 24 2.02E-06 4

1 5 2.09E-05 2 2.48E-06 2 1.18E-05 2 2.57E-06 2 2 2 2.88E-06 2 1.20E-07 2 8.85E-08 2 1.03E-07 1
3 3 2.27E-06 - 1.09E-06 - 1.23E-06 - 5.29E-06 -
4 1 2.27E-05 - 1.09E-05 - 1.23E-05 - 5.29E-05 -
5 3 4.08E-05 - 1.96E-05 - 2.21E-05 - 9.52E-05 - 6 259 4.54E-05 54 2.18E-05 51 2.46E-05 56 1.06E-04 23
1 3 1.71E-06 - 5.71E-07 - 2.57E-07 - 2.09E-07 -
2 2 8.57E-06 - 2.85E-06 - 1.28E-06 - 1.05E-06 -
3 - 8.57E-06 - 2.85E-06 - 1.28E-06 - 1.05E-06 -
4 - 8.57E-05 - 2.85E-05 - 1.28E-05 - 1.05E-05 -
5 9 1.54E-04 - 5.14E-05 - 2.31E-05 - 1.88E-05 - 6 539 1.71E-04 120 5.71E-05 121 2.57E-05 212 2.09E-05 58
1 6 1.58E-08 - 4.98E-10 - 1.47E-09 - 4.64E-09 -
2 16 7.88E-08 - 2.49E-09 - 7.34E-09 - 2.32E-08 -
3 2 7.88E-08 - 2.49E-09 - 7.34E-09 - 2.32E-08 -
4 11 7.88E-07 - 2.49E-08 - 7.34E-08 - 2.32E-07 -
5 16 1.42E-06 - 4.48E-08 - 1.32E-07 - 4.17E-07 - 6 10732 1.58E-06 9 4.98E-08 7 1.47E-07 11 4.64E-07 5
1 2 2.47E-08 - 1.57E-06 - 5.42E-09 - 3.14E-08 -
2 - 1.24E-07 - 7.86E-06 - 2.71E-08 - 1.57E-07 -
3 - 1.24E-07 - 7.86E-06 - 2.71E-08 - 1.57E-07 -
4 - 1.24E-06 - 7.86E-05 - 2.71E-07 - 1.57E-06 -
5 - 2.22E-06 - 1.41E-04 - 4.88E-07 - 2.83E-06 - 6 747 2.47E-06 7 1.57E-04 7 5.42E-07 7 3.14E-06 7
1 3 2.19E-08 - 7.32E-10 - 7.54E-08 - 4.84E-09 -
2 2 1.10E-07 - 3.66E-09 - 3.77E-07 - 2.42E-08 -
3 - 1.10E-07 - 3.66E-09 - 3.77E-07 - 2.42E-08 -
4 - 1.10E-06 - 3.66E-08 - 3.77E-06 - 2.42E-07 -
5 - 1.97E-06 - 6.59E-08 - 6.79E-06 - 4.36E-07 - 6 194 2.19E-06 7 7.32E-08 6 7.54E-06 7 4.84E-07 5 

## Appendix D-2: Major Source Baseline Emission Factors for Fuel-Based HAP and SO2 for Existing Units

Coal

Bagasse

Wet Biomass

Gas 2 Gas 1 (Other) Dry Biomass

Heavy Liquid

Light Liquid

Gas 1 (NG Only)Fuel Category 

## Appendix D-2

Coal

Bagasse

Wet Biomass

Gas 2 Gas 1 (Other) Dry Biomass

Heavy Liquid

Light Liquid

Gas 1 (NG Only) Cr (lb/MMBtu) Cr # of Data Points Ni (lb/MMBtu) Ni # of Data Points Mn (lb/MMBtu) Mn # of Data Points Pb (lb/MMBtu) Pb # of Data Points Sb (lb/MMBtu) Sb # of Data Points Se (lb/MMBtu) Se # of Data Points

4.90E-05 64 4.70E-05 64 7.05E-04 65 5.28E-05 68 9.72E-05 24 9.51E-05 64 1.14E-04 94 2.06E-04 96 1.29E-04 96 2.96E-05 94 2.92E-06 6 4.72E-03 92 5.31E-05 10 9.94E-05 10 9.28E-05 10 1.40E-04 10 1.98E-05 2 2.57E-05 10 1.62E-05 5 2.18E-05 5 9.54E-05 4 1.11E-04 5 1.87E-05 3 1.80E-05 5 5.07E-05 13 1.07E-04 13 3.80E-04 11 1.81E-04 13 3.36E-05 - 1.16E-04 11 3.74E-05
1.45E-06 - 2.37E-06 - 1.24E-06 - 4.27E-07 - 4.05E-08 - 9.06E-08 - 7.25E-06 - 1.19E-05 - 5.15E-04 1 2.14E-06 - 1.29E-06 - 4.53E-07 - 5.47E-06 2 6.36E-06 2 1.72E-04 2 2.35E-05 2 1.15E-06 - 3.40E-07 2 7.25E-05 1 1.19E-04 1 6.18E-05 2 2.14E-05 1 2.02E-06 - 4.53E-06 1 1.31E-04 - 2.14E-04 - 1.11E-04 - 3.84E-05 - 3.64E-06 - 8.15E-06 -

4.78E-07 - 6.00E-07 - 8.82E-06 - 1.08E-06 - 4.05E-08 - 4.03E-08 - 7.02E-06 28 7.72E-06 27 3.06E-04 29 9.63E-06 28 1.29E-06 10 2.51E-06 26 1.24E-05 19 3.94E-05 18 2.06E-04 21 1.21E-04 19 1.15E-06 3 4.04E-06 19 2.39E-05 9 3.00E-05 9 4.41E-04 10 5.40E-05 9 2.02E-06 - 2.02E-06 5 1.75E-05 11 4.74E-05 10 3.31E-03 22 3.88E-05 11 3.64E-06 1 3.34E-05 11

1.21E-05 5 7.85E-06 5 5.18E-04 5 1.07E-05 5 4.09E-07 3 2.00E-06 5 3.42E-06 29 4.45E-06 27 2.84E-04 39 1.01E-05 29 4.22E-07 8 2.52E-06 24 5.35E-05 5 2.05E-05 5 7.30E-04 8 7.60E-04 5 2.59E-05 2 8.78E-06 5 1.87E-04 6 1.57E-04 6 5.90E-03 6 1.70E-03 6 1.37E-06 - 6.23E-05 5 2.10E-05 24 1.35E-05 22 2.83E-03 31 1.20E-04 24 2.47E-06 4 2.67E-06 19

2.06E-05 2 1.18E-05 2 2.42E-05 2 3.04E-05 2 5.94E-06 2 5.05E-06 2 1.54E-06 2 1.27E-04 2 1.06E-05 2 1.50E-06 2 1.12E-07 1 1.04E-05 2 2.59E-06 - 1.21E-04 - 2.86E-04 - 4.34E-06 - 4.43E-06 - 3.05E-06 - 2.59E-05 - 1.21E-03 - 2.86E-03 - 4.34E-05 - 4.43E-05 - 3.05E-05 - 4.66E-05 - 2.17E-03 - 5.15E-03 - 7.81E-05 - 7.97E-05 - 5.49E-05 - 5.18E-05 55 2.41E-03 55 5.72E-03 53 8.68E-05 56 8.86E-05 23 6.10E-05 48
2.64E-06 - 2.35E-06 - 1.60E-04 - 3.21E-06 - 1.37E-06 - 2.08E-06 - 1.32E-05 - 1.18E-05 - 8.00E-04 - 1.61E-05 - 6.86E-06 - 1.04E-05 - 1.32E-05 - 1.18E-05 - 8.00E-04 - 1.61E-05 - 6.86E-06 - 1.04E-05 - 1.32E-04 - 1.18E-04 - 8.00E-03 - 1.61E-04 - 6.86E-05 - 1.04E-04 - 2.38E-04 - 2.12E-04 - 1.44E-02 - 2.89E-04 - 1.23E-04 - 1.88E-04 - 2.64E-04 213 2.35E-04 123 1.60E-02 123 3.21E-04 212 1.37E-04 59 2.08E-04 121
2.32E-07 - 2.92E-07 - 1.38E-07 - 8.94E-09 - 6.46E-09 - 4.07E-09 - 1.16E-06 - 1.46E-06 - 6.92E-07 - 4.47E-08 - 3.23E-08 - 2.04E-08 - 1.16E-06 - 1.46E-06 - 6.92E-07 - 4.47E-08 - 3.23E-08 - 2.04E-08 - 1.16E-05 - 1.46E-05 - 6.92E-06 - 4.47E-07 - 3.23E-07 - 2.04E-07 - 2.09E-05 - 2.63E-05 - 1.25E-05 - 8.05E-07 - 5.81E-07 - 3.67E-07 - 2.32E-05 10 2.92E-05 13 1.38E-05 12 8.94E-07 10 6.46E-07 7 4.07E-07 8
8.38E-08 - 1.66E-08 - 2.19E-08 - 1.99E-07 - 8.45E-09 - 1.33E-07 - 4.19E-07 - 8.29E-08 - 1.10E-07 - 9.97E-07 - 4.22E-08 - 6.67E-07 - 4.19E-07 - 8.29E-08 - 1.10E-07 - 9.97E-07 - 4.22E-08 - 6.67E-07 - 4.19E-06 - 8.29E-07 - 1.10E-06 - 9.97E-06 - 4.22E-07 - 6.67E-06 - 7.54E-06 - 1.49E-06 - 1.97E-06 - 1.80E-05 - 7.60E-07 - 1.20E-05 - 8.38E-06 7 1.66E-06 7 2.19E-06 7 1.99E-05 7 8.45E-07 7 1.33E-05 6
3.28E-08 - 3.61E-08 - 7.93E-08 - 4.52E-08 - 3.58E-08 - 3.53E-08 - 1.64E-07 - 1.80E-07 - 3.97E-07 - 2.26E-07 - 1.79E-07 - 1.76E-07 - 1.64E-07 - 1.80E-07 - 3.97E-07 - 2.26E-07 - 1.79E-07 - 1.76E-07 - 1.64E-06 - 1.80E-06 - 3.97E-06 - 2.26E-06 - 1.79E-06 - 1.76E-06 - 2.95E-06 - 3.25E-06 - 7.14E-06 - 4.07E-06 - 3.22E-06 - 3.18E-06 - 3.28E-06 7 3.61E-06 7 7.93E-06 7 4.52E-06 7 3.58E-06 6 3.53E-06 6Fuel Category 

## Appendix D-2

Coal

Bagasse

Wet Biomass

Gas 2 Gas 1 (Other) Dry Biomass

Heavy Liquid

Light Liquid

Gas 1 (NG Only) Hg Control Category Total # of Unitsin SubCategory Hg (lb/MMBtu) Hg # of Data Points PM Filterable Control Category Total # of Unitsin SubCategory PM Filterable (lb/MMBtu) PM # of Data Points

1 2 2.00E-06 2 1 234 2.75E-02 144 2 41 1.57E-06 16 2 255 4.90E-02 150 3 191 5.36E-06 88 3 23 1.25E-01 13 4 13 3.19E-06 8 4 5 9.92E-02 6 5 23 6.17E-06 8 5 61 2.23E-01 34 6 308 3.14E-05 147
1 - no % reduction known 1 - 1.46E-02 -
2 - 2.43E-08 - 2 2 1.28E-02 2
3 - 2.43E-08 - 3 - 6.98E-02 2 4 14 3.69E-06 4 4 14 1.46E-01 13
5 - 9.73E-08 - 5 - 8.77E-01 - 6 2 9.73E-08 1
1 - no % reduction known 1 1 2.24E-03 -
2 - 3.41E-07 - 2 83 8.11E-02 49
3 1 3.41E-07 - 3 27 1.20E-01 14 4 18 1.89E-06 7 4 17 1.12E-01 8 5 27 2.17E-06 11 5 43 2.45E-01 21 6 125 1.36E-06 29
1 - no % reduction known 1 8 1.08E-02 5
2 3 5.21E-07 2 2 96 3.00E-02 51
3 5 1.68E-06 4 3 12 7.69E-02 8
4 13 7.46E-07 3 4 12 1.66E-01 6
5 14 4.27E-06 3 5 105 3.23E-01 26 6 198 9.79E-07 35
1 - no % reduction known 1 5 9.65E-03 2
2 - 2.42E-07 - 2 2 7.87E-02 3
3 5 2.42E-07 - 3 3 2.50E-02 2
4 1 8.71E-07 - 4 1 4.60E-03 -
5 3 9.67E-07 - 5 3 2.41E-02 1 6 264 9.67E-07 61 6 259 7.67E-02 37
1 - no % reduction known 1 3 2.05E-04 -
2 - 6.28E-07 - 2 2 3.12E-03 6
3 3 6.28E-07 - 3 - 1.23E-03 -
4 - 2.26E-06 - 4 - 1.23E-03 -
5 - 2.51E-06 - 5 9 4.10E-03 - 6 550 2.51E-06 228 6 539 2.05E-02 28
1 - no % reduction known 1 6 7.19E-05 -
2 2 1.36E-07 - 2 16 1.44E-04 -
3 6 1.36E-07 - 3 2 1.44E-04 -
4 11 4.91E-07 - 4 11 3.59E-03 -
5 2 5.46E-07 - 5 16 1.80E-03 - 6 10762 5.46E-07 12 6 10732 7.19E-03 127
1 - no % reduction known 1 2 1.04E-04 -
2 - 2.71E-07 - 2 - 2.08E-04 - 3 2 2.71E-07 - 3 - 2.08E-04 -
4 - 9.76E-07 - 4 - 5.19E-03 -
5 - 1.08E-06 - 5 - 2.60E-03 - 6 747 1.08E-06 7 6 747 1.04E-02 10
1 - no % reduction known 1 3 1.10E-04 - 2 3 4.98E-07 2 2 2 2.21E-04 -
3 - 3.17E-07 - 3 - 2.21E-04 -
4 - 1.14E-06 - 4 - 5.52E-03 -
5 - 1.27E-06 - 5 - 2.76E-03 - 6 196 1.27E-06 7 6 194 1.10E-02 13Fuel Category 

## Appendix D-2

Coal

Bagasse

Wet Biomass

Gas 2 Gas 1 (Other) Dry Biomass

Heavy Liquid

Light Liquid

Gas 1 (NG Only) Inorganic Control Category Total # of Unitsin SubCategory HCl (lb/MMBtu) HCl # of Data Points HF (lb/MMBtu) HF # of Data Points Cl2 (lb/MMBtu) Cl2 # of Data Points SO2 (ppm @ 3% O2) SO2 # of Data Points

1 18 3.49E-02 17 8.33E-05 8 1.33E-03 4 146.9 15 2 16 2.79E-04 4 4.97E-05 2 4.00E-05 1 98.1 10 3 41 5.70E-02 21 8.08E-04 7 7.20E-05 8 173.9 24 4 23 4.18E-03 6 2.44E-03 2 9.78E-04 3 269.0 7 5 480 1.12E-01 263 3.01E-03 33 3.26E-03 185 765.0 86

1 14 2.10E-03 3 7.03E-05 - 2.14E-03 3 2.7 -
2 - 3.63E-04 - 7.03E-05 - 2.41E-04 - 2.7 -
3 - 2.18E-03 - 1.23E-04 - 1.85E-03 - 16.2 -
4 - 7.25E-03 - 3.26E-05 - 1.85E-03 - 46.4 - 5 2 7.25E-03 2 1.23E-04 - 1.85E-03 1 53.9 -

1 18 3.89E-03 6 7.03E-05 - 3.70E-04 1 2.7 - 2 2 9.27E-04 2 7.03E-05 - 2.48E-04 - 2.7 -
3 - 2.03E-03 - 1.23E-04 - 1.91E-03 - 16.2 - 4 27 6.80E-03 9 3.26E-05 3 1.91E-03 - 46.4 4 5 124 6.78E-03 26 1.23E-04 11 1.91E-03 5 53.9 17

1 15 3.39E-04 3 1.60E-04 - 4.78E-04 - 3.8 - 2 1 1.45E-03 2 5.87E-05 1 4.78E-04 - 6.8 1 3 1 1.30E-02 3 4.71E-04 2 3.67E-03 - 46.4 3 4 14 3.78E-03 6 5.09E-04 3 3.67E-03 - 51.0 7 5 202 7.70E-03 38 2.81E-04 14 3.67E-03 11 76.2 18

1 1 3.45E-04 - 9.56E-05 - 8.26E-05 - 9.1 -
2 6 3.45E-04 - 9.56E-05 - 8.26E-05 - 9.1 - 3 - 2.07E-03 - 1.68E-04 - 6.36E-04 - 54.4 -
4 3 6.90E-03 - 1.68E-04 - 6.36E-04 - 27.1 1 5 263 6.90E-03 59 1.68E-04 9 6.36E-04 6 181.3 16

1 - 1.43E-04 - 1.53E-04 - 4.41E-04 - 4.0 - 2 1 1.43E-04 - 1.53E-04 - 4.41E-04 - 4.0 -
3 - 8.57E-04 - 2.69E-04 - 3.39E-03 - 24.1 -
4 - 2.86E-03 - 2.69E-04 - 3.39E-03 - 80.4 - 5 552 2.86E-03 225 2.69E-04 5 3.39E-03 4 80.4 11

1 11 2.62E-05 - 4.17E-03 - no data - 0.2 -
2 5 2.62E-05 - 4.17E-03 - no data - 0.2 -
3 - 1.57E-04 - 7.31E-03 - no data - 1.5 -
4 2 5.24E-04 - 7.31E-03 - no data - 4.9 - 5 10765 5.24E-04 9 7.31E-03 8 no data - 4.9 39

1 - 4.06E-05 - 1.87E-04 - no data - 0.1 -
2 1 4.06E-05 - 1.87E-04 - no data - 0.1 -
3 - 2.44E-04 - 3.29E-04 - no data - 0.8 -
4 - 8.13E-04 - 3.29E-04 - no data - 2.5 - 5 748 8.13E-04 9 3.29E-04 8 no data - 2.5 6

1 - 6.29E-05 - 9.72E-05 - no data - 2.3 - 2 1 7.00E-04 1 9.72E-05 - no data - 2.3 - 3 3 4.68E-03 2 1.70E-04 - no data - 13.7 -
4 - 1.26E-03 - 1.70E-04 - no data - 45.8 - 5 195 1.26E-03 8 1.70E-04 6 no data - 45.8 7

### Notes:

Metals/PM Control Groups: It was assumed that all coal and biomass units had at least a cyclone or multiclone installed for metals and PM control. Control groups 5 and 6 for metal and PM emissions from solid-fuel boilers were mer g ed to g ether into a sin g le control g rou p ( 5 )

. Green cells: Whenever there is not an uncontrolled average but there is an average for another control group, the percent reductions were used to back-calculate an uncontrolled average. Additional data gaps were filled by applying percent reductions to the calculated uncontrolled average (see % Reductions tab). Uncontrolled baseline averages that were back-calculated and the averages based on those values appear as g reen cells.

Orange cells: Where there is no reported data for bagasse, the wet biomass baseline average from the same control group was used to fill the data gaps. Yellow cells: Whenever there is an average based on reported data for the uncontrolled group (i.e., control group 6 for Mercury), any data gaps for that pollutant were filled using percent reductions applied to the uncontrolled average (see % Reductions tab). Baseline averages that were calculated using percent reductions based on a reported uncontrolled average appear as yellow cells.Appendix D-3: Ratios of PM2.5 to Total Filterable PM Based on Fuel and ControlFuel CategoryControlFraction ofFilterable PMthat is PM 2.5 Reason Source Note:Gas 1 ALL 1Particulate matter from natural gas combustion has been estimated to be less than 1micrometer in size and has filterable and condensable fractions. http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s04.pdfGas 2 ALL 1Particulate matter from natural gas combustion has been estimated to be less than 1micrometer in size and has filterable and condensable fractions. http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s04.pdfHeavy Liquid Uncontrolled 0.56 Table 1.3-5 distribution of particle size in industrial boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdfHeavy Liquid Multiclone 0.22 Table 1.3-5 distribution of particle size in industrial boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdfHeavy Liquid Electrostatic Precipitator 0.41 Table 1.3-4 distribution of particle size in utility boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdfHeavy Liquid Scrubber 0.97 Table 1.3-4 distribution of particle size in utility boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdfLight Liquid ALL 0.12 Table 1.3-6 distribution of particle size in industrial boilers for distillate oils http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdfBiomass Uncontrolled 0.76 Table 1.6-5 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s06.pdfApplied to wet biomass, dry biomass, andbagasse fuel categories.Biomass Multiclone 0.16 Table 1.6-5 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s06.pdfWithout flyash re-injection; applied to wetbiomass, dry biomass, and bagasse fuelcategories.BiomassElectrostatic Precipitator/Electrified Filter Bed 0.65 Table 1.6-5 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s06.pdfApplied to wet biomass, dry biomass, andbagasse fuel categories.Biomass Scrubber 0.98 Table 1.6-5 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s06.pdfApplied to wet biomass, dry biomass, andbagasse fuel categories.Coal Uncontrolled 0.07 Table 1.1-9 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s01.pdfUsed spreader stoker values from AP-42 for allcombustor designs.Coal Multiclone 0.27 Table 1.1-9 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s01.pdfUsed spreader stoker values from AP-42 for allcombustor designs; value is for without flyash reinjection.Coal Electrostatic Precipitator 0.61 Table 1.1-9 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s01.pdfUsed spreader stoker values from AP-42 for allcombustor designs.Coal Baghouse 0.26 Table 1.1-9 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s01.pdfUsed spreader stoker values from AP-42 for allcombustor designs.

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
WVDuPont Washington Works P05 10/7/2009 5:00:21 AM 0.34381323 0.000251548 

## 0.000732 yes
WVDuPont Washington Works P05 10/6/2009 10:00:15 PM 0.344576659 0.000256677 

## 0.000745 yes
WVDuPont Washington Works P05 10/7/2009 8:00:24 AM 0.360740978 0.000484122 

## 0.001342 yes
WVDuPont Washington Works P05 10/8/2009 8:00:46 AM 0.329648796 0.000493776 

## 0.001498 yes
WVDuPont Washington Works P05 9/27/2009 3:00:54 PM 0.147489247 0.000247915 

## 0.001681 yes

WVDuPont Washington Works P05 9/28/2009 2:00:04 AM 0.148978914 0.000254813 

## 0.00171 yes
WVDuPont Washington Works P05 9/24/2009 6:00:51 PM 0.283334953 0.000488471 

## 0.001724 yes
WVDuPont Washington Works P05 9/24/2009 7:00:52 PM 0.277256972 0.000478063 

## 0.001724 yes
WVDuPont Washington Works P05 10/6/2009 9:00:14 PM 0.337156378 0.000767346 

## 0.002276 yes
WVDuPont Washington Works P05 9/24/2009 8:00:53 PM 0.298784616 0.000740574 

## 0.002479 yes
WVDuPont Washington Works P05 9/26/2009 1:00:30 PM 0.43101433 0.001077453 

## 0.0025 yes
WVDuPont Washington Works P05 9/25/2009 3:00:11 PM 0.140338347 0.000471791 

## 0.003362 yes
WVDuPont Washington Works P05 9/28/2009 1:00:04 AM 0.145179443 0.000732098 

## 0.005043 yes
WVDuPont Washington Works P05 9/30/2009 11:00:55 AM 0.225811534 0.001189867 

## 0.005269 yes
WVDuPont Washington Works P05 9/24/2009 3:00:48 PM 0.216452416 0.001153772 

## 0.00533 yes
WVDuPont Washington Works P05 9/28/2009 2:00:15 PM 0.197589816 0.001177285 

## 0.005958 yes
WVDuPont Washington Works P05 9/24/2009 5:00:50 PM 0.289667246 0.001963694 

## 0.006779 yes
WVDuPont Washington Works P05 10/6/2009 3:00:09 PM 0.258561117 0.001770252 

## 0.006847 yes

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
WVDuPont Washington Works P05 10/12/2009 5:00:20 PM 0.194572199 0.001354111 

## 0.006959 yes
WVDuPont Washington Works P05 9/24/2009 10:00:44 AM 0.274374984 0.002325032 

## 0.008474 yes
WVDuPont Washington Works P05 9/29/2009 1:00:36 PM 0.233769825 0.001989305 

## 0.00851 yes
WVDuPont Washington Works P05 10/7/2009 10:00:26 AM 0.505524356 0.004384948 

## 0.008674 yes
WVDuPont Washington Works P05 9/28/2009 12:00:13 PM 0.121327483 0.001199647 

## 0.009888 yes
WVDuPont Washington Works P05 9/25/2009 5:00:12 PM 0.426068376 0.004774536 

## 0.011206 yes
WVDuPont Washington Works P05 10/4/2009 4:00:27 PM 0.658496965 0.009609755 

## 0.014593 yes
WVDuPont Washington Works P05 9/25/2009 6:00:13 PM 0.426969441 0.006349776 

## 0.014872 yes
WVDuPont Washington Works P05 9/27/2009 6:00:56 PM 0.145791811 0.002205559 

## 0.015128 yes
WVDuPont Washington Works P05 9/26/2009 10:00:28 AM 0.434142408 0.007412962 

## 0.017075 yes
WVDuPont Washington Works P05 10/7/2009 9:00:25 AM 0.478946682 0.008913989 

## 0.018612 yes
WVDuPont Washington Works P05 9/25/2009 7:00:14 PM 0.429981631 0.009154937 

## 0.021291 yes
WVDuPont Washington Works P05 9/27/2009 8:00:47 AM 0.369515136 0.008187488 

## 0.022157 yes
WVDuPont Washington Works P05 9/24/2009 12:00:46 PM 0.297926351 0.006953059 

## 0.023338 yes
WVDuPont Washington Works P05 9/28/2009 3:00:05 AM 0.15448463 0.003963445 

## 0.025656 yes
WVDuPont Washington Works P05 10/5/2009 11:00:44 AM 0.373815964 0.009669351 

## 0.025867 yes
WVDuPont Washington Works P05 9/29/2009 4:00:38 PM 0.188741765 0.005696384 

## 0.030181 yes TXDibollTem ple-Inland PB-44 0900-1000 2.477278137 0.083700023 

## 0.033787 yes

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
WVDuPont Washington Works P05 9/25/2009 3:00:00 AM 0.195685242 0.006794388 

## 0.034721 yes
WVDuPont Washington Works P05 9/27/2009 9:00:48 AM 0.155571377 0.00571872 

## 0.036759 yes
WVDuPont Washington Works P05 9/25/2009 4:00:12 PM 0.940857368 0.035008684 

## 0.037209 yes WABoeingR enton BOIL04 08/07/09 20:00 1.610931851 0.064103566 normal 

## 0.039793 yes
WVDuPont Washington Works P05 9/24/2009 11:00:45 AM 0.309345524 0.01297871 

## 0.041955 yes
WVDuPont Washington Works P05 9/26/2009 2:00:21 AM 0.424479831 0.017837754 

## 0.042023 yes
WVDuPont Washington Works P05 9/26/2009 7:00:25 AM 0.44944557 0.020243201 

## 0.04504 yes
WVDuPont Washington Works P05 9/25/2009 8:00:15 PM 0.440596868 0.020142684 

## 0.045717 yes TXDibollTem ple-Inland PB-44 1000-1100 5.371799357 0.261031121 

## 0.048593 yes
WVDuPont Washington Works P05 9/24/2009 9:00:43 AM 0.330668777 0.017114282 

## 0.051757 yes ARDomtarIn dustries PB1 8/28/2009 9:00:00 AM 254.2082867 13.23415716 Normal 

## 0.05206 yes
WVDuPont Washington Works P05 9/25/2009 2:00:10 PM 0.141854399 0.007735277 

## 0.05453 yes TXDibollTem ple-Inland PB-44 1600-1700 3.224265328 0.176433347 

## 0.05472 yes
WVDuPont Washington Works P05 10/5/2009 12:00:45 PM 0.381809679 0.021718138 

## 0.056882 yes TXDibollTem ple-Inland PB-44 1700-1800 3.447991163 0.198474571 

## 0.057562 yes

ARDomtarIn dustries PB1 8/28/2009 10:00:00 AM 39.44418223 2.271092684 Normal 10:02 - 10:56 calibration 10:02 - 10:56 calibration 

## 0.057577 yes

VAPhilipMorr isPark500 B3 10/14/2009 11:00:00 PM 6.748646209 0.394765343 Normal 

## 0.058495 yes VAPhilipMorr isPark500 B3 10/16/2009 4:00:00 AM 6.212565489 0.386603235 Normal 

## 0.062229 yes VAPhilipMorr isPark500 B3 10/16/2009 8:00:00 AM 6.170910347 0.392359133 Normal 

## 0.063582 yes
WVDuPont Washington Works P05 9/25/2009 10:00:17 PM 0.441787404 0.028298376 

## 0.064054 yes

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
WVDuPont Washington Works P05 9/25/2009 11:00:18 PM 0.444844111 0.029161883 

## 0.065555 yes
WVDuPont Washington Works P05 9/26/2009 6:00:24 AM 0.451126096 0.030864141 

## 0.068416 yes
WVDuPont Washington Works P05 9/25/2009 9:00:16 PM 0.447122332 0.031565943 

## 0.070598 yes
WVDuPont Washington Works P05 9/29/2009 3:00:37 PM 0.210934293 0.015516887 

## 0.073563 yes

VAPhilipMorr isPark500 B3 10/14/2009 10:00:00 PM 6.883619134 0.526353791 Normal 

## 0.076465 yes WABoeingR enton BOIL04 08/07/09 19:00 0.833881145 0.064181952 normal 

## 0.076968 yes
WVDuPont Washington Works P05 9/25/2009 1:00:09 PM 0.142398434 0.011059161 

## 0.077663 yes VAPhilipMorr isPark500 B3 10/16/2009 6.609112222 0.515470979 Normal 

## 0.077994 yes
WVDuPont Washington Works P05 9/26/2009 9:00:27 AM 0.483747108 0.038228677 

## 0.079026 yes VAPhilipMorr isPark500 B3 10/16/2009 1:00:00 AM 6.524791647 0.519280084 Normal 

## 0.079586 yes VAPhilipMorr isPark500 B3 10/16/2009 2:00:00 AM 6.524791647 0.519280084 Normal 

## 0.079586 yes
WVDuPont Washington Works P05 9/26/2009 12:00:19 AM 0.443628477 0.035793467 

## 0.080683 yes VAPhilipMorr isPark500 B3 10/16/2009 3:00:00 AM 6.391632634 0.519280084 Normal 

## 0.081244 yes VAPhilipMorr isPark500 B3 10/16/2009 5:00:00 AM 6.25847362 0.519280084 Normal 

## 0.082972 yes TXDibollTem ple-Inland PB-44 2200-2300 46.24435158 3.865714628 

## 0.083593 yes VAPhilipMorr isPark500 B3 10/16/2009 7:00:00 AM 6.125314607 0.519280084 Normal 

## 0.084776 yes VAPhilipMorr isPark500 B3 10/16/2009 6:00:00 AM 6.080383245 0.515470979 Normal 

## 0.084776 yes
WVDuPont Washington Works P05 9/26/2009 5:00:23 AM 0.449827262 0.039269257 

## 0.087299 yes ARDomtarIn dustries PB1 8/28/2009 8:00:00 AM 331.9240538 29.05523924 Normal 

## 0.087536 yes

ARDomtarIn dustries PB1 9/3/2009 10:00:00 AM 90.21831949 7.904916421 Normal 10:06 - 10:59 calibration 10:06 - 10:59 calibration 

## 0.08762 yes TXDibollTem ple-Inland PB-44 2300-2400 33.35778011 2.932160964 

## 0.0879 yes TXDibollTem ple-Inland PB-44 0800-0900 3.350885318 0.299883959 

## 0.089494 yes

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
WVDuPont Washington Works P05 9/25/2009 6:00:03 AM 0.141247896 0.013058334 

## 0.09245 yes
WVDuPont Washington Works P05 9/25/2009 4:00:01 AM 0.144064735 0.013326539 

## 0.092504 yes TXDibollTem ple-Inland PB-44 0500-0600 2.66124099 0.260072374 

## 0.097726 yes TXDibollTem ple-Inland PB-44 0300-0400 2.639055145 0.27550492 

## 0.104395 no
WVDuPont Washington Works P05 10/7/2009 12:00:28 PM 0.377381417 0.039459148 

## 0.10456 no WABoeingR enton BOIL04 08/08/09 07:00 1.656109253 0.173377926 normal 

## 0.10469 no
WVDuPont Washington Works P05 9/29/2009 2:00:37 PM 0.22427682 0.02356681 

## 0.105079 no
WVDuPont Washington Works P05 9/24/2009 8:00:42 AM 0.281209332 0.031438094 

## 0.111796 no
WVDuPont Washington Works P05 9/26/2009 8:00:26 AM 0.440445452 0.050541387 

## 0.114751 no TXDibollTem ple-Inland PB-44 0600-0700 23.27220514 2.676590346 

## 0.115012 no TXDibollTem ple-Inland PB-44 0800-0900 2.368370854 0.275867867 

## 0.11648 no WABoeingR enton BOIL04 10/12/09 19:00 8.690953947 1.0125 normal 

## 0.1165 no
WVDuPont Washington Works P05 9/24/2009 5:00:39 AM 0.276888971 0.03228716 

## 0.116607 no ARDomtarIn dustries PB1 9/3/2009 9:00:00 AM 76.71393513 9.328315957 Normal 

## 0.121599 no TXDibollTem ple-Inland PB-44 0200-0300 2.946379435 0.360227822 

## 0.122261 no ARDomtarIn dustries PB1 9/7/2009 9:00:00 AM 2.939672212 0.361406765 Normal 

## 0.122941 no TXDibollTem ple-Inland PB-44 2300-2400 2.960537203 0.370703506 

## 0.125215 no ARDomtarIn dustries PB1 9/8/2009 9:00:00 PM 19.30257772 2.450525585 Normal 

## 0.126953 no TXDibollTem ple-Inland PB-44 2200-2300 2.924538253 0.371646466 

## 0.127079 no TXDibollTem ple-Inland PB-44 0600-0700 2.591934639 0.331702623 

## 0.127975 no
WVDuPont Washington Works P05 10/7/2009 3:00:30 PM 0.512101794 0.065783071 

## 0.128457 no TXDibollTem ple-Inland PB-44 0100-0200 2.902714391 0.37444603 

## 0.128999 no
WVDuPont Washington Works P05 9/26/2009 11:00:29 AM 0.430956828 0.056020065 

## 0.12999 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 10/12/09 14:00 10.37738417 1.351083546 normal 

## 0.130195 no WABoeingR enton BOIL04 08/08/09 04:00 3.231519487 0.42078441 normal 

## 0.130213 no
WVDuPont Washington Works P05 10/7/2009 11:00:27 AM 0.383781853 0.050034851 

## 0.130373 no
WVDuPont Washington Works P05 9/26/2009 1:00:20 AM 0.433991152 0.056909361 

## 0.13113 no ARDomtarIn dustries PB1 9/9/2009 2:00:00 AM 28.65486495 3.76021568 Normal 

## 0.131224 no ARDomtarIn dustries PB1 9/9/2009 1:00:00 AM 25.39922618 3.346052062 Normal 

## 0.131738 no

ARDomtarIn dustries PB1 9/8/2009 11:00:00 PM 19.49680143 2.572452672 Normal 

## 0.131942 no WABoeingR enton BOIL04 10/17/09 00:00 13.90136481 1.839306529 normal 

## 0.132311 no
WVDuPont Washington Works P05 9/25/2009 7:00:04 AM 0.141968553 0.019031191 

## 0.134052 no
WVDuPont Washington Works P05 9/25/2009 5:00:02 AM 0.14357423 0.01931251 

## 0.134512 no ARDomtarIn dustries PB1 9/9/2009 25.43962148 3.451900681 Normal 

## 0.13569 no WABoeingR enton BOIL04 08/08/09 12:00 2.70090301 0.368428094 normal 

## 0.136409 no ARDomtarIn dustries PB1 9/9/2009 6:00:00 AM 16.02517083 2.233734216 Normal 

## 0.139389 no TXDibollTem ple-Inland PB-44 10/08/2009 0000-0100 2.779101791 0.387562719 

## 0.139456 no WABoeingR enton BOIL04 10/15/09 14:00 11.49963383 1.612288539 normal 

## 0.140203 no

ARDomtarIn dustries PB1 9/8/2009 12:00:00 PM 14.16174023 1.994243339 Normal 

## 0.140819 no

ARDomtarIn dustries PB1 9/9/2009 11:00:00 AM 20.67752821 2.920318487 Normal 

## 0.141232 no WABoeingR enton BOIL04 10/08/09 04:00 5.965155485 0.846096964 normal 

## 0.14184 no WABoeingR enton BOIL04 08/08/09 00:00 2.628765629 0.375312577 normal 

## 0.142771 no ARDomtarIn dustries PB1 9/7/2009 6:00:00 AM 3.517678961 0.504151293 Normal 

## 0.143319 no ARDomtarIn dustries PB1 9/9/2009 3:00:00 AM 17.78731303 2.59398877 Normal 

## 0.145834 no TXDibollTem ple-Inland PB-44 0700-0800 2.77044903 0.411570858 

## 0.148557 no ARDomtarIn dustries PB1 9/9/2009 5:00:00 AM 17.49576062 2.611641634 Normal 

## 0.149273 no WABoeingR enton BOIL04 10/14/09 16:00 18.64376549 2.789746106 normal 

## 0.149634 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/08/09 09:00 5.508663029 0.824566539 normal 

## 0.149685 no ARDomtarIn dustries PB1 9/9/2009 9:00:00 AM 18.72294168 2.802818977 Normal 

## 0.1497 no
WVDuPont Washington Works P05 9/26/2009 3:00:21 AM 0.440257279 0.06591558 

## 0.149721 no ARDomtarIn dustries PB1 9/9/2009 8:00:00 AM 19.36503458 2.901451469 Normal 

## 0.149829 no ARDomtarIn dustries PB1 9/9/2009 2:00:00 PM 31.95216676 4.788609428 Normal 

## 0.149868 no ARDomtarIn dustries PB1 9/9/2009 7:00:00 AM 18.51192045 2.785223284 Normal 

## 0.150456 no WABoeingR enton BOIL04 10/08/09 02:00 5.065758468 0.762282769 normal 

## 0.150478 no ARDomtarIn dustries PB1 9/9/2009 4:00:00 AM 18.75841491 2.823338189 Normal 

## 0.15051 no

VAPhilipMorr isPark500 B3 10/16/2009 10:00:00 AM 7.79138303 1.17869157 Normal 

## 0.151281 no

ARDomtarIn dustries PB1 9/8/2009 10:00:00 PM 20.36586172 3.090771906 Normal 

## 0.151762 no WABoeingR enton BOIL04 10/12/09 22:00 11.73720468 1.791617701 normal 

## 0.152644 no WABoeingR enton BOIL04 08/07/09 22:00 12.06991516 1.860818886 normal 

## 0.15417 no WABoeingR enton BOIL04 08/08/09 05:00 6.547536053 1.013573277 normal 

## 0.154802 no WABoeingR enton BOIL04 10/12/09 18:00 9.701721661 1.501848289 normal 

## 0.154802 no TXDibollTem ple-Inland PB-44 0900-1000 5.958479655 0.923467727 

## 0.154984 no WABoeingR enton BOIL04 10/12/09 15:00 7.658678924 1.192957506 normal 

## 0.155765 no TXDibollTem ple-Inland PB-44 0400-0500 2.663756142 0.415010306 

## 0.155799 no WABoeingR enton BOIL04 08/08/09 14:00 9.286632375 1.45294001 normal 

## 0.156455 no WABoeingR enton BOIL04 10/13/09 04:00 0.675316824 0.106190823 normal 

## 0.157246 no WABoeingR enton BOIL04 10/15/09 18:00 5.517271723 0.869646539 normal 

## 0.157623 no WABoeingR enton BOIL04 10/12/09 17:00 10.03559211 1.588026316 normal 

## 0.158239 no WABoeingR enton BOIL04 08/20/09 00:00 13.62513676 2.156688336 normal 

## 0.158287 no ARDomtarIn dustries PB1 9/9/2009 1:00:00 PM 29.49321071 4.694129835 Normal 

## 0.15916 no ARDomtarIn dustries PB1 9/9/2009 3:00:00 PM 23.67397822 3.773039952 Normal 

## 0.159375 no WABoeingR enton BOIL04 08/07/09 23:00 6.430668479 1.026887434 normal 

## 0.159686 no ARDomtarIn dustries PB1 9/7/2009 3:00:00 AM 7.324120416 1.171294587 Normal 

## 0.159923 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 1900-2000 3.273631674 0.526619394 

## 0.160867 no TXDibollTem ple-Inland PB-44 2100-2200 3.183911271 0.512186866 

## 0.160867 no TXDibollTem ple-Inland PB-44 0400-0500 2.953970891 0.475292396 

## 0.160899 no WABoeingR enton BOIL04 08/07/09 21:00 11.4490323 1.847790741 normal 

## 0.161393 no
WVDuPont Washington Works P05 9/26/2009 4:00:22 AM 0.457809994 0.073998656 

## 0.161636 no

ARDomtarIn dustries PB1 9/6/2009 12:00:00 PM 7.359644472 1.192193006 Normal 

## 0.161991 no ARDomtarIn dustries PB1 9/8/2009 7:00:00 PM 23.25132805 3.782612297 Normal 

## 0.162684 no WABoeingR enton BOIL04 08/08/09 06:00 10.14493389 1.653829235 normal 

## 0.16302 no WABoeingR enton BOIL04 10/08/09 00:00 3.215655376 0.526082474 normal 

## 0.1636 no WABoeingR enton BOIL04 10/08/09 08:00 3.995092604 0.654517356 normal 

## 0.16383 no ARDomtarIn dustries PB1 9/8/2009 8:00:00 PM 26.78654541 4.401583427 Normal 

## 0.164321 no WABoeingR enton BOIL04 10/08/09 15:00 6.841390047 1.12593773 normal 

## 0.164577 no WABoeingR enton BOIL04 10/14/09 13:00 8.997079776 1.493925348 normal 

## 0.166046 no

ARDomtarIn dustries PB1 9/9/2009 10:00:00 AM 18.75222054 3.126834876 Normal 10:05 - 10:59 calibration 10:05 - 10:59 calibration 

## 0.166745 no WABoeingR enton BOIL04 10/16/09 19:00 11.21625 1.872726378 normal 

## 0.166965 no WABoeingR enton BOIL04 10/08/09 13:00 4.371969809 0.730073638 normal 

## 0.16699 no WABoeingR enton BOIL04 10/12/09 21:00 10.68500426 1.78943626 normal 

## 0.167472 no WABoeingR enton BOIL04 09/27/09 09:00 10.8397928 1.823162486 normal 

## 0.168192 no WABoeingR enton BOIL04 10/15/09 15:00 13.08471177 2.200889106 normal 

## 0.168203 no WABoeingR enton BOIL04 10/08/09 06:00 6.038358008 1.016835923 normal 

## 0.168396 no WABoeingR enton BOIL04 10/08/09 01:00 5.32473388 0.899097027 normal 

## 0.168853 no

ARDomtarIn dustries PB1 9/8/2009 10:00:00 AM 17.40414927 2.942670098 Normal 10:05 - 10:59 calibration 10:05 - 10:59 calibration 

## 0.169079 no ARDomtarIn dustries PB1 9/8/2009 1:00:00 PM 14.75377333 2.495265265 Normal 

## 0.169127 no ARDomtarIn dustries PB1 9/6/2009 3:00:00 PM 5.890082042 0.996819233 Normal 

## 0.169237 no ARDomtarIn dustries PB1 9/8/2009 7:00:00 AM 10.26913731 1.738081279 Normal 

## 0.169253 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 10/16/09 03:00 15.20903214 2.576399853 normal 

## 0.169399 no WABoeingR enton BOIL04 10/13/09 06:00 9.303953346 1.581221299 normal 

## 0.169952 no WABoeingR enton BOIL04 10/17/09 06:00 12.67995822 2.160663554 normal 

## 0.1704 no WABoeingR enton BOIL04 10/16/09 16:00 18.64419367 3.177967599 normal 

## 0.170453 no WABoeingR enton BOIL04 10/14/09 14:00 9.095887748 1.55106383 normal 

## 0.170524 no WABoeingR enton BOIL04 10/13/09 09:00 8.43821446 1.442330239 normal 

## 0.170928 no WABoeingR enton BOIL04 10/14/09 19:00 13.05888012 2.233394179 normal 

## 0.171025 no ARDomtarIn dustries PB1 9/8/2009 5:00:00 PM 15.27421136 2.616904275 Normal 

## 0.171328 no ARDomtarIn dustries PB1 9/6/2009 3:00:00 AM 3.678784015 0.631867121 Normal 

## 0.17176 no TXDibollTem ple-Inland PB-44 1800-1900 3.359511075 0.577246898 

## 0.171825 no ARDomtarIn dustries PB1 9/7/2009 2.85412589 0.491465409 Normal 

## 0.172195 no ARDomtarIn dustries PB1 9/6/2009 4:00:00 AM 7.86070328 1.370279042 Normal 

## 0.17432 no ARDomtarIn dustries PB1 9/8/2009 9:00:00 AM 18.46110165 3.227758747 Normal 

## 0.174841 no WABoeingR enton BOIL04 10/15/09 17:00 5.850996555 1.033228346 normal 

## 0.17659 no ARDomtarIn dustries PB1 9/7/2009 4:00:00 AM 6.466528593 1.151665935 Normal 

## 0.178096 no WABoeingR enton BOIL04 10/12/09 20:00 10.74839475 1.914921561 normal 

## 0.178159 no WABoeingR enton BOIL04 10/14/09 17:00 16.7124612 2.995742794 normal 

## 0.179252 no WABoeingR enton BOIL04 10/15/09 01:00 7.557488012 1.355278495 normal 

## 0.179329 no ARDomtarIn dustries PB1 9/6/2009 9:00:00 PM 2.082206152 0.3734582 Normal 

## 0.179357 no WABoeingR enton BOIL04 10/08/09 09:00 3.873158474 0.695304475 normal 

## 0.179519 no

ARDomtarIn dustries PB1 9/6/2009 11:00:00 AM 6.859092197 1.231694794 Normal 

## 0.179571 no WABoeingR enton BOIL04 10/15/09 03:00 8.572015265 1.540027084 normal 

## 0.179658 no WABoeingR enton BOIL04 10/08/09 03:00 4.026768158 0.727395451 normal 

## 0.18064 no WABoeingR enton BOIL04 08/08/09 16:00 4.77641743 0.866353058 normal 

## 0.181381 no WABoeingR enton BOIL04 08/19/09 00:00 10.09986237 1.838176456 normal 

## 0.182 no WABoeingR enton BOIL04 10/16/09 00:00 13.57490308 2.47413873 normal 

## 0.182258 no ARDomtarIn dustries PB1 9/6/2009 2:00:00 PM 6.26325752 1.143130012 Normal 

## 0.182514 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 10/16/09 15:00 16.01966802 2.925680561 normal 

## 0.182631 no WABoeingR enton BOIL04 10/12/09 23:00 11.14651591 2.036898696 normal 

## 0.182739 no

ARDomtarIn dustries PB1 9/6/2009 11:00:00 PM 2.97378059 0.547814495 Normal 

## 0.184215 no ARDomtarIn dustries PB1 9/6/2009 6:00:00 AM 7.088848141 1.306713588 Normal 

## 0.184334 no WABoeingR enton BOIL04 08/13/09 22:00 8.832212552 1.629928904 normal 

## 0.184544 no WABoeingR enton BOIL04 10/16/09 02:00 16.28567192 3.021706335 normal 

## 0.185544 no WABoeingR enton BOIL04 10/07/09 23:00 12.33057473 2.288252487 normal 

## 0.185575 no ARDomtarIn dustries PB1 9/6/2009 1:00:00 PM 6.857373442 1.274557207 Normal 

## 0.185867 no WABoeingR enton BOIL04 10/16/09 01:00 11.90864483 2.215492512 normal 

## 0.186041 no WABoeingR enton BOIL04 10/15/09 07:00 14.35591246 2.671557864 normal 

## 0.186095 no WABoeingR enton BOIL04 10/13/09 00:00 3.913252481 0.728732084 normal 

## 0.186222 no WABoeingR enton BOIL04 10/14/09 15:00 14.74457237 2.750808761 normal 

## 0.186564 no ARDomtarIn dustries PB1 9/8/2009 8:00:00 AM 14.38683858 2.684241198 Normal 

## 0.186576 no WABoeingR enton BOIL04 08/08/09 15:00 10.00954388 1.87581061 normal 

## 0.187402 no WABoeingR enton BOIL04 10/15/09 08:00 13.67652604 2.564983298 normal 

## 0.187546 no ARDomtarIn dustries PB1 9/7/2009 1:00:00 AM 2.948534521 0.553014101 Normal 

## 0.187556 no ARDomtarIn dustries PB1 9/8/2009 2:00:00 PM 15.65538768 2.94050181 Normal 

## 0.187827 no WABoeingR enton BOIL04 09/27/09 08:00 10.36140676 1.950359869 normal 

## 0.188233 no WABoeingR enton BOIL04 10/15/09 02:00 8.164293619 1.53813353 normal 

## 0.188398 no

ARDomtarIn dustries PB1 9/7/2009 10:00:00 AM 3.505753517 0.660968368 Normal 10:05 - 10:59 calibration 10:05 - 10:59 calibration 

## 0.188538 no
WVDuPont Washington Works P05 9/25/2009 8:00:04 AM 0.177411391 0.033553207 

## 0.189127 no WABoeingR enton BOIL04 10/13/09 02:00 8.097162358 1.532326649 normal 

## 0.189242 no ARDomtarIn dustries PB1 9/7/2009 8:00:00 AM 3.058344633 0.57982504 Normal 

## 0.189588 no WABoeingR enton BOIL04 10/12/09 16:00 12.11267544 2.302105263 normal 

## 0.190058 no WABoeingR enton BOIL04 10/06/09 02:00 4.995368898 0.952614707 normal 

## 0.1907 no ARDomtarIn dustries PB1 9/10/2009 5:00:00 AM 4.939701268 0.942025774 Normal 

## 0.190705 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/08/09 03:00 7.81658841 1.491689114 normal 

## 0.190836 no WABoeingR enton BOIL04 10/07/09 22:00 10.4747481 1.999420005 normal 

## 0.19088 no WABoeingR enton BOIL04 10/07/09 16:00 10.20708997 1.951625398 normal 

## 0.191203 no ARDomtarIn dustries PB1 9/10/2009 4.3458559 0.832600426 Normal 

## 0.191585 no WABoeingR enton BOIL04 08/11/09 02:00 7.661620728 1.468180816 normal 

## 0.191628 no WABoeingR enton BOIL04 10/13/09 05:00 4.533909875 0.871293575 normal 

## 0.192173 no ARDomtarIn dustries PB1 9/8/2009 6:00:00 PM 16.5934599 3.1893394 Normal 

## 0.192205 no WABoeingR enton BOIL04 08/11/09 00:00 7.818888071 1.503092784 normal 

## 0.192239 no WABoeingR enton BOIL04 10/15/09 12:00 12.17035237 2.347077151 normal 

## 0.192852 no WABoeingR enton BOIL04 09/26/09 21:00 6.291876744 1.220453718 normal 

## 0.193973 no
WVDuPont Washington Works P05 10/5/2009 5:00:49 PM 0.342543309 0.066576918 

## 0.194361 no WABoeingR enton BOIL04 08/21/09 16:00 2.097527067 0.40898622 normal 

## 0.194985 no WABoeingR enton BOIL04 10/15/09 09:00 15.05091268 2.945490873 normal 

## 0.195702 no
WVDuPont Washington Works P05 9/24/2009 1:00:36 AM 0.281182928 0.055062761 

## 0.195825 no WABoeingR enton BOIL04 10/06/09 06:00 5.385113442 1.056418639 normal 

## 0.196174 no WABoeingR enton BOIL04 10/13/09 12:00 8.811795339 1.730910415 normal 

## 0.196431 no ARDomtarIn dustries PB1 9/8/2009 4:00:00 PM 13.39679273 2.632908039 Normal 

## 0.196533 no WABoeingR enton BOIL04 10/14/09 21:00 12.27779042 2.413465298 normal 

## 0.196572 no WABoeingR enton BOIL04 10/08/09 11:00 7.23078744 1.427062431 normal 

## 0.197359 no WABoeingR enton BOIL04 10/15/09 19:00 5.273692364 1.043349318 normal 

## 0.19784 no WABoeingR enton BOIL04 10/06/09 05:00 4.366903888 0.866456346 normal 

## 0.198414 no WABoeingR enton BOIL04 10/14/09 20:00 9.529929525 1.892804154 normal 

## 0.198617 no WABoeingR enton BOIL04 10/14/09 22:00 17.26344036 3.435248209 normal 

## 0.19899 no ARDomtarIn dustries PB1 9/11/2009 2:00:00 AM 4.51958843 0.901536316 Normal 

## 0.199473 no WABoeingR enton BOIL04 08/11/09 12:00 11.8534121 2.366929481 normal 

## 0.199683 no ARDomtarIn dustries PB1 9/9/2009 4:00:00 PM 9.893640823 1.986366292 Normal 

## 0.200772 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 10/13/09 07:00 6.304523054 1.269836545 normal 

## 0.201417 no WABoeingR enton BOIL04 10/16/09 18:00 15.20492381 3.063627427 normal 

## 0.201489 no WABoeingR enton BOIL04 10/07/09 14:00 7.287216608 1.46989407 normal 

## 0.201709 no WABoeingR enton BOIL04 10/17/09 11:00 12.74324192 2.570421156 normal 

## 0.201709 no ARDomtarIn dustries PB1 9/6/2009 8:00:00 PM 2.813511427 0.568217625 Normal 

## 0.20196 no WABoeingR enton BOIL04 10/09/09 05:00 5.372987827 1.086374032 normal 

## 0.202192 no WABoeingR enton BOIL04 08/17/09 10:00 12.42889189 2.530679088 normal 

## 0.203613 no WABoeingR enton BOIL04 09/28/09 09:00 10.43986745 2.125802651 normal 

## 0.203624 no WABoeingR enton BOIL04 10/17/09 10:00 18.82923849 3.834211557 normal 

## 0.203631 no WABoeingR enton BOIL04 10/07/09 18:00 4.961722782 1.010459572 normal 

## 0.203651 no ARDomtarIn dustries PB1 9/11/2009 5:00:00 AM 4.888780051 0.995729884 Normal 

## 0.203677 no WABoeingR enton BOIL04 08/11/09 09:00 10.77464369 2.199607506 normal 

## 0.204147 no WABoeingR enton BOIL04 10/13/09 08:00 6.100065789 1.246973684 normal 

## 0.20442 no
WVDuPont Washington Works P05 10/7/2009 1:00:29 PM 0.379553901 0.077694198 

## 0.204699 no WABoeingR enton BOIL04 10/16/09 04:00 13.35026061 2.740105225 normal 

## 0.205247 no WABoeingR enton BOIL04 09/28/09 03:00 6.67666504 1.376545499 normal 

## 0.206173 no ARDomtarIn dustries PB1 9/10/2009 7:00:00 PM 4.216628336 0.871121099 Normal 

## 0.206592 no ARDomtarIn dustries PB1 9/6/2009 5:00:00 AM 5.704340437 1.178627793 Normal 

## 0.206619 no ARDomtarIn dustries PB1 9/8/2009 5:00:00 AM 1.63924014 0.339502922 Normal 

## 0.20711 no WABoeingR enton BOIL04 10/15/09 04:00 17.62987805 3.65308204 normal 

## 0.20721 no WABoeingR enton BOIL04 08/11/09 11:00 12.066112 2.503111875 normal 

## 0.20745 no ARDomtarIn dustries PB1 9/8/2009 3:00:00 PM 14.59780014 3.029228332 Normal 

## 0.207513 no

ARDomtarIn dustries PB1 9/9/2009 12:00:00 PM 18.46365976 3.838645868 Normal 

## 0.207903 no WABoeingR enton BOIL04 10/08/09 10:00 6.273285907 1.309034711 normal 

## 0.208668 no WABoeingR enton BOIL04 10/16/09 14:00 19.78073482 4.127834849 normal 

## 0.20868 no WABoeingR enton BOIL04 10/07/09 20:00 12.91459659 2.696485325 normal 

## 0.208794 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/14/09 13:00 9.719005281 2.030421221 normal 

## 0.208912 no WABoeingR enton BOIL04 10/16/09 08:00 14.28368505 2.987850695 normal 

## 0.209179 no WABoeingR enton BOIL04 10/16/09 05:00 3.263705602 0.683354083 normal 

## 0.20938 no WABoeingR enton BOIL04 10/15/09 11:00 17.89496662 3.753160237 normal 

## 0.209733 no
WVDuPont Washington Works P05 9/24/2009 4:00:38 AM 0.281679979 0.059280002 

## 0.210452 no WABoeingR enton BOIL04 10/13/09 10:00 5.928765086 1.247733756 normal 

## 0.210454 no WABoeingR enton BOIL04 08/21/09 23:00 12.74435698 2.683237251 normal 

## 0.210543 no WABoeingR enton BOIL04 10/13/09 23:00 13.68278009 2.884545232 normal 

## 0.210816 no WABoeingR enton BOIL04 10/08/09 05:00 6.924359794 1.461941509 normal 

## 0.21113 no

ARDomtarIn dustries PB1 9/7/2009 11:00:00 PM 1.871044496 0.395159373 Normal 

## 0.211197 no WABoeingR enton BOIL04 10/16/09 21:00 17.30145747 3.656616818 normal 

## 0.211347 no WABoeingR enton BOIL04 10/14/09 23:00 15.97810077 3.381234873 normal 

## 0.211617 no WABoeingR enton BOIL04 10/16/09 06:00 7.066045488 1.49757887 normal 

## 0.21194 no WABoeingR enton BOIL04 10/06/09 09:00 6.808392988 1.447634224 normal 

## 0.212625 no ARDomtarIn dustries PB1 9/6/2009 5:00:00 PM 4.262513922 0.910018332 Normal 

## 0.213493 no WABoeingR enton BOIL04 10/06/09 13:00 7.757289068 1.658033749 normal 

## 0.213739 no WABoeingR enton BOIL04 10/07/09 21:00 11.37080463 2.432391732 normal 

## 0.213916 no WABoeingR enton BOIL04 10/15/09 00:00 11.84528904 2.533933194 normal 

## 0.213919 no

VAPhilipMorr isPark500 B3 10/1/2009 11:00:00 AM 5.407344369 1.15721429 Normal 

## 0.214008 no WABoeingR enton BOIL04 10/14/09 18:00 13.82757206 2.963414634 normal 

## 0.214312 no WABoeingR enton BOIL04 08/11/09 07:00 10.84938258 2.325512679 normal 

## 0.214345 no WABoeingR enton BOIL04 10/15/09 10:00 15.11265534 3.244018355 normal 

## 0.214656 no WABoeingR enton BOIL04 10/14/09 00:00 11.0970011 2.383971649 normal 

## 0.21483 no WABoeingR enton BOIL04 10/13/09 17:00 10.4646527 2.250496141 normal 

## 0.215057 no WABoeingR enton BOIL04 10/07/09 08:00 9.849747807 2.120921053 normal 

## 0.215327 no WABoeingR enton BOIL04 10/07/09 19:00 8.649340145 1.863109689 normal 

## 0.215405 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 09/26/09 10:00 8.341129386 1.801184211 normal 

## 0.21594 no WABoeingR enton BOIL04 10/09/09 09:00 7.478420534 1.615413025 normal 

## 0.21601 no ARDomtarIn dustries PB1 9/6/2009 1:00:00 AM 4.315931374 0.932478066 Normal 

## 0.216055 no WABoeingR enton BOIL04 09/27/09 06:00 8.304902223 1.795714806 normal 

## 0.216223 no WABoeingR enton BOIL04 08/08/09 02:00 7.224494937 1.566386762 normal 

## 0.216816 no ARDomtarIn dustries PB1 8/28/2009 4:00:00 AM 5.383599255 1.168196206 Normal 

## 0.216992 no WABoeingR enton BOIL04 10/14/09 01:00 14.01380178 3.04677991 normal 

## 0.217413 no ARDomtarIn dustries PB1 9/6/2009 6:00:00 PM 3.082529791 0.670710821 Normal 

## 0.217585 no WABoeingR enton BOIL04 08/13/09 01:00 9.987109586 2.176812944 normal 

## 0.217962 no WABoeingR enton BOIL04 09/26/09 22:00 7.463859905 1.627683327 normal 

## 0.218075 no ARDomtarIn dustries PB1 9/11/2009 4.890059866 1.070584499 Normal 

## 0.218931 no ARDomtarIn dustries PB1 9/10/2009 6:00:00 AM 3.599417309 0.789018087 Normal 

## 0.219207 no WABoeingR enton BOIL04 10/12/09 13:00 10.13681607 2.222256961 normal 

## 0.219226 no WABoeingR enton BOIL04 09/27/09 10:00 10.58722505 2.325579024 normal 

## 0.219659 no ARDomtarIn dustries PB1 9/6/2009 7:00:00 PM 3.520418336 0.773634505 Normal 

## 0.219756 no ARDomtarIn dustries PB1 9/10/2009 1:00:00 AM 4.346431497 0.957170197 Normal 

## 0.22022 no WABoeingR enton BOIL04 08/11/09 10:00 9.414619246 2.077757101 normal 

## 0.220695 no WABoeingR enton BOIL04 10/16/09 23:00 18.10409519 4.013826012 normal 

## 0.221708 no WABoeingR enton BOIL04 09/26/09 23:00 4.04129989 0.896902234 normal 

## 0.221934 no WABoeingR enton BOIL04 10/06/09 15:00 8.392962782 1.863555338 normal 

## 0.222038 no ARDomtarIn dustries PB1 9/11/2009 9:00:00 AM 4.917672684 1.092653714 Normal 

## 0.222189 no ARDomtarIn dustries PB1 9/11/2009 1:00:00 AM 4.707187943 1.046556364 Normal 

## 0.222332 no WABoeingR enton BOIL04 09/27/09 05:00 8.681088857 1.932672979 normal 

## 0.22263 no WABoeingR enton BOIL04 10/17/09 02:00 7.921571376 1.764013279 normal 

## 0.222685 no WABoeingR enton BOIL04 10/17/09 05:00 6.564533383 1.46284028 normal 

## 0.22284 no WABoeingR enton BOIL04 10/15/09 21:00 8.315258642 1.85511645 normal 

## 0.223098 no WABoeingR enton BOIL04 10/17/09 01:00 18.01643689 4.023672268 normal 

## 0.223333 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/19/09 03:00 1.055905859 0.235910762 normal 

## 0.22342 no WABoeingR enton BOIL04 09/27/09 04:00 7.722708765 1.727631354 normal 

## 0.223708 no ARDomtarIn dustries PB1 9/7/2009 2:00:00 PM 4.235578973 0.947696547 Normal 

## 0.223747 no

ARDomtarIn dustries PB1 9/6/2009 10:00:00 PM 2.822554032 0.633886518 Normal 

## 0.224579 no

ARDomtarIn dustries PB1 9/5/2009 10:00:00 PM 2.546520796 0.572157096 Normal 

## 0.224682 no
WVDuPont Washington Works P05 9/24/2009 2:00:37 AM 0.281332352 0.063276388 

## 0.224917 no WABoeingR enton BOIL04 08/21/09 22:00 3.763971544 0.847653624 normal 

## 0.225202 no WABoeingR enton BOIL04 10/08/09 14:00 4.177067255 0.94306505 normal 

## 0.225772 no WABoeingR enton BOIL04 10/06/09 14:00 7.188920371 1.62395701 normal 

## 0.225897 no WABoeingR enton BOIL04 09/27/09 03:00 4.495820604 1.015593303 normal 

## 0.225897 no WABoeingR enton BOIL04 08/18/09 21:00 2.700792855 0.610101554 normal 

## 0.225897 no WABoeingR enton BOIL04 09/28/09 13:00 7.840913108 1.771502209 normal 

## 0.225931 no WABoeingR enton BOIL04 09/28/09 14:00 8.920462308 2.016799219 normal 

## 0.226087 no WABoeingR enton BOIL04 08/12/09 10:00 14.06060174 3.179918949 normal 

## 0.226158 no ARDomtarIn dustries PB1 9/11/2009 6:00:00 AM 5.042359194 1.140892965 Normal 

## 0.226262 no WABoeingR enton BOIL04 10/15/09 05:00 14.17140468 3.207491639 normal 

## 0.226335 no WABoeingR enton BOIL04 09/27/09 22:00 5.795333817 1.311988389 normal 

## 0.226387 no WABoeingR enton BOIL04 08/17/09 09:00 10.48206546 2.380554057 normal 

## 0.227107 no ARDomtarIn dustries PB1 9/6/2009 9:00:00 AM 4.427053698 1.006754096 Normal 

## 0.22741 no WABoeingR enton BOIL04 10/07/09 15:00 9.528268034 2.167513731 normal 

## 0.227482 no WABoeingR enton BOIL04 09/28/09 08:00 4.903579762 1.11726882 normal 

## 0.227848 no ARDomtarIn dustries PB1 9/10/2009 5:00:00 PM 7.596419293 1.734727494 Normal 

## 0.228361 no WABoeingR enton BOIL04 10/06/09 08:00 7.543092105 1.726578947 normal 

## 0.228895 no ARDomtarIn dustries PB1 9/8/2009 4:00:00 AM 3.310809512 0.75846859 Normal 

## 0.229089 no WABoeingR enton BOIL04 08/21/09 15:00 7.991474501 1.831929047 normal 

## 0.229235 no WABoeingR enton BOIL04 08/13/09 15:00 9.996853575 2.291958864 normal 

## 0.229268 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/12/09 03:00 9.718090274 2.231796885 normal 

## 0.229654 no WABoeingR enton BOIL04 10/17/09 07:00 18.49933317 4.249303805 normal 

## 0.2297 no WABoeingR enton BOIL04 10/06/09 10:00 3.629676391 0.836410885 normal 

## 0.230437 no WABoeingR enton BOIL04 10/09/09 10:00 4.989906496 1.151619094 normal 

## 0.23079 no WABoeingR enton BOIL04 10/08/09 21:00 7.301299705 1.685611193 normal 

## 0.230865 no WABoeingR enton BOIL04 10/17/09 04:00 2.510854197 0.579764359 normal 

## 0.230903 no WABoeingR enton BOIL04 10/14/09 03:00 15.15078918 3.500056283 normal 

## 0.231015 no WABoeingR enton BOIL04 10/08/09 20:00 4.697097567 1.085706562 normal 

## 0.231144 no ARDomtarIn dustries PB1 9/7/2009 7:00:00 AM 3.27672018 0.758485399 Normal 

## 0.231477 no ARDomtarIn dustries PB1 9/11/2009 3:00:00 AM 4.582672756 1.063118166 Normal 

## 0.231986 no TXDibollTem ple-Inland PB-44 0500-0600 4.367034027 1.013606174 

## 0.232104 no WABoeingR enton BOIL04 08/11/09 08:00 14.81759647 3.440044101 normal 

## 0.232159 no WABoeingR enton BOIL04 10/15/09 20:00 4.206782032 0.977010309 normal 

## 0.232246 no WABoeingR enton BOIL04 08/14/09 05:00 11.39096652 2.6502588 normal 

## 0.232663 no ARDomtarIn dustries PB1 8/28/2009 6:00:00 AM 5.988135116 1.394960021 Normal 

## 0.232954 no WABoeingR enton BOIL04 08/14/09 01:00 9.227864838 2.152727718 normal 

## 0.233286 no ARDomtarIn dustries PB1 9/10/2009 3:00:00 AM 4.675155583 1.092714761 Normal 

## 0.233728 no WABoeingR enton BOIL04 10/13/09 20:00 12.13871563 2.843661249 normal 

## 0.234264 no WABoeingR enton BOIL04 08/11/09 04:00 7.274810499 1.706037042 normal 

## 0.234513 no WABoeingR enton BOIL04 10/17/09 03:00 2.331792106 0.54688404 normal 

## 0.234534 no ARDomtarIn dustries PB1 9/7/2009 4:00:00 PM 4.284036362 1.005011212 Normal 

## 0.234594 no ARDomtarIn dustries PB1 9/6/2009 4:00:00 PM 3.48160543 0.816888238 Normal 

## 0.23463 no WABoeingR enton BOIL04 10/13/09 11:00 2.490982589 0.585827347 normal 

## 0.235179 no WABoeingR enton BOIL04 10/16/09 20:00 17.15701953 4.039356503 normal 

## 0.235435 no WABoeingR enton BOIL04 09/27/09 21:00 7.271298984 1.714049347 normal 

## 0.235728 no WABoeingR enton BOIL04 09/26/09 18:00 6.272851959 1.481277213 normal 

## 0.236141 no WABoeingR enton BOIL04 10/08/09 07:00 7.848489526 1.853980154 normal 

## 0.236221 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 10/05/09 22:00 5.223138892 1.235441483 normal 

## 0.236532 no WABoeingR enton BOIL04 09/28/09 10:00 9.315330154 2.203580337 normal 

## 0.236554 no WABoeingR enton BOIL04 10/08/09 12:00 6.761686303 1.599720177 normal 

## 0.236586 no WABoeingR enton BOIL04 10/14/09 09:00 11.43001107 2.71055699 normal 

## 0.237144 no WABoeingR enton BOIL04 10/14/09 02:00 14.71756106 3.493644358 normal 

## 0.237379 no WABoeingR enton BOIL04 10/09/09 16:00 6.721761022 1.600702444 normal 

## 0.238137 no WABoeingR enton BOIL04 10/13/09 16:00 12.93612986 3.080733676 normal 

## 0.23815 no WABoeingR enton BOIL04 08/21/09 14:00 8.638293734 2.067728672 normal 

## 0.239368 no

ARDomtarIn dustries PB1 9/10/2009 10:00:00 PM 4.302771509 1.030615261 Normal 

## 0.239524 no WABoeingR enton BOIL04 10/16/09 17:00 16.91522828 4.058350515 normal 

## 0.239923 no ARDomtarIn dustries PB1 8/28/2009 5:00:00 AM 3.812176787 0.915834684 Normal 

## 0.240239 no ARDomtarIn dustries PB1 9/10/2009 2:00:00 AM 4.912625743 1.180628962 Normal 

## 0.240325 no WABoeingR enton BOIL04 10/09/09 14:00 7.358343957 1.769330718 normal 

## 0.240452 no WABoeingR enton BOIL04 10/15/09 06:00 5.114432493 1.233026706 normal 

## 0.241088 no ARDomtarIn dustries PB1 9/7/2009 5:00:00 AM 4.148736657 1.002074634 Normal 

## 0.241537 no WABoeingR enton BOIL04 10/07/09 17:00 6.552448454 1.5889838 normal 

## 0.242502 no WABoeingR enton BOIL04 08/25/09 10:00 10.56687361 2.564700665 normal 

## 0.242711 no WABoeingR enton BOIL04 10/13/09 03:00 5.655894378 1.373195425 normal 

## 0.24279 no TXDibollTem ple-Inland PB-44 1600-1700 55.35781348 13.44065683 

## 0.242796 no WABoeingR enton BOIL04 09/28/09 15:00 10.00297685 2.432679162 normal 

## 0.243196 no WABoeingR enton BOIL04 10/13/09 21:00 11.93771512 2.904254852 normal 

## 0.243284 no WABoeingR enton BOIL04 09/27/09 00:00 3.594460186 0.876082071 normal 

## 0.243731 no VAPhilipMorr isPark500 B3 11/12/2009 5:00:00 AM 1.503477829 0.366444446 Normal 

## 0.243731 no WABoeingR enton BOIL04 10/13/09 15:00 10.29023815 2.510723009 normal 

## 0.243991 no ARDomtarIn dustries PB1 9/8/2009 1:00:00 AM 2.676347925 0.653571379 Normal 

## 0.244203 no WABoeingR enton BOIL04 10/13/09 19:00 11.69245687 2.857844121 normal 

## 0.244418 no WABoeingR enton BOIL04 08/14/09 10:00 7.593977677 1.85625414 normal 

## 0.244438 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
ARDomtarIn dustries PB1 9/11/2009 4:00:00 AM 4.748200057 1.164536451 Normal 

## 0.245259 no

ARDomtarIn dustries PB1 9/8/2009 11:00:00 AM 9.890925669 2.429534369 Normal 

## 0.245633 no
WVDuPont Washington Works P05 9/24/2009 7:00:41 AM 0.26258899 0.064650326 

## 0.246203 no WABoeingR enton BOIL04 08/11/09 03:00 16.33255489 4.023672268 normal 

## 0.246359 no

ARDomtarIn dustries PB1 9/11/2009 10:00:00 AM 5.050936602 1.244765064 Normal 10:37 - 10:59 final bias check 10:37 - 10:59 final bias check 

## 0.246442 no WABoeingR enton BOIL04 10/15/09 13:00 11.74774792 2.895344406 normal 

## 0.24646 no WABoeingR enton BOIL04 08/17/09 00:00 12.35874755 3.052375122 normal 

## 0.246981 no ARDomtarIn dustries PB1 9/7/2009 2:00:00 AM 4.099300437 1.016398382 Normal 

## 0.247944 no VAPhilipMorr isPark500 B3 10/15/2009 1:00:00 AM 7.594875346 1.884764543 Normal 

## 0.248163 no WABoeingR enton BOIL04 09/28/09 02:00 6.164325109 1.534179971 normal 

## 0.24888 no WABoeingR enton BOIL04 10/05/09 23:00 6.924359794 1.741430327 normal 

## 0.251493 no WABoeingR enton BOIL04 09/28/09 00:00 6.027296043 1.517117733 normal 

## 0.251708 no WABoeingR enton BOIL04 08/22/09 07:00 6.32181114 1.591914423 normal 

## 0.251813 no TXDibollTem ple-Inland PB-44 2000-2100 3.820533346 0.962313881 

## 0.251879 no WABoeingR enton BOIL04 08/08/09 01:00 7.707278786 1.943280267 normal 

## 0.252136 no WABoeingR enton BOIL04 08/25/09 08:00 10.85425721 2.737117517 normal 

## 0.25217 no VAPhilipMorr isPark500 B3 10/15/2009 2:00:00 AM 7.34377084 1.856198848 Normal 

## 0.252758 no WABoeingR enton BOIL04 09/28/09 12:00 9.292994626 2.350464094 normal 

## 0.252929 no

ARDomtarIn dustries PB1 9/10/2009 11:00:00 PM 4.767137563 1.206299502 Normal 

## 0.253045 no TXDibollTem ple-Inland PB-44 0900-1000 5.433099821 1.37560601 

## 0.25319 no VAPhilipMorr isPark500 B3 10/15/2009 9:00:00 AM 6.69826814 1.697879964 Normal 

## 0.25348 no

VAPhilipMorr isPark500 B3 10/15/2009 11:00:00 PM 6.707511246 1.700222911 Normal 

## 0.25348 no WABoeingR enton BOIL04 09/28/09 06:00 8.17128866 2.072120766 normal 

## 0.253586 no WABoeingR enton BOIL04 08/08/09 08:00 8.265189169 2.098308605 normal 

## 0.253873 no WABoeingR enton BOIL04 10/07/09 10:00 9.46255584 2.402416697 normal 

## 0.253887 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier

ARDomtarIn dustries PB1 9/9/2009 10:00:00 PM 4.445859273 1.129283632 Normal 

## 0.254008 no ARDomtarIn dustries PB1 9/8/2009 2.008709189 0.510438731 Normal 

## 0.254113 no WABoeingR enton BOIL04 10/16/09 22:00 16.4958627 4.200501044 normal 

## 0.25464 no

ARDomtarIn dustries PB1 9/7/2009 11:00:00 AM 2.76093075 0.703071278 Normal 

## 0.25465 no WABoeingR enton BOIL04 08/10/09 15:00 12.24941617 3.12236968 normal 

## 0.254899 no

ARDomtarIn dustries PB1 9/9/2009 11:00:00 PM 4.137095748 1.055059823 Normal 

## 0.255024 no WABoeingR enton BOIL04 10/08/09 23:00 8.462807319 2.159336854 normal 

## 0.255156 no ARDomtarIn dustries PB1 9/10/2009 7:00:00 AM 1.688780378 0.430910169 Normal 

## 0.255161 no WABoeingR enton BOIL04 08/12/09 07:00 12.81857143 3.274594993 normal 

## 0.255457 no WABoeingR enton BOIL04 10/06/09 00:00 3.183861495 0.813468739 normal 

## 0.255498 no WABoeingR enton BOIL04 08/17/09 03:00 8.144265914 2.081579787 normal 

## 0.255588 no WABoeingR enton BOIL04 08/22/09 01:00 5.68135255 1.454767184 normal 

## 0.25606 no ARDomtarIn dustries PB1 9/7/2009 1:00:00 PM 3.823997727 0.980102758 Normal 

## 0.256303 no
WVDuPont Washington Works P05 9/24/2009 12:00:35 AM 0.283100049 0.072569295 

## 0.256338 no WABoeingR enton BOIL04 08/13/09 06:00 7.521550074 1.932547865 normal 

## 0.256935 no WABoeingR enton BOIL04 08/14/09 03:00 12.57629602 3.231649485 normal 

## 0.256964 no WABoeingR enton BOIL04 08/25/09 06:00 6.358818898 1.635944882 normal 

## 0.257272 no VAPhilipMorr isPark500 B3 10/15/2009 1:00:00 PM 7.38483541 1.901796716 Normal 

## 0.257527 no WABoeingR enton BOIL04 08/14/09 02:00 13.19591193 3.40134429 normal 

## 0.257757 no WABoeingR enton BOIL04 09/28/09 11:00 8.6892253 2.241152243 normal 

## 0.257923 no WABoeingR enton BOIL04 08/12/09 09:00 9.635140966 2.487786222 normal 

## 0.258199 no WABoeingR enton BOIL04 08/11/09 01:00 12.93791621 3.343594267 normal 

## 0.258434 no ARDomtarIn dustries PB1 9/6/2009 3.203722508 0.831001509 Normal 

## 0.259386 no ARDomtarIn dustries PB1 9/11/2009 7:00:00 AM 5.196484191 1.350788397 Normal 

## 0.259943 no

VAPhilipMorr isPark500 B3 11/11/2009 11:00:00 PM 2.148182197 0.558484278 Normal 

## 0.25998 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier

VAPhilipMorr isPark500 B3 11/11/2009 10:00:00 PM 2.182877077 0.567504251 Normal 

## 0.25998 no WABoeingR enton BOIL04 08/19/09 07:00 3.140494904 0.816465676 normal 

## 0.25998 no ARDomtarIn dustries PB1 9/6/2009 7:00:00 AM 4.49020177 1.167673744 Normal 

## 0.260049 no WABoeingR enton BOIL04 10/09/09 15:00 8.17128866 2.125802651 normal 

## 0.260155 no WABoeingR enton BOIL04 10/07/09 00:00 3.073769353 0.799829331 normal 

## 0.260211 no ARDomtarIn dustries PB1 9/11/2009 8:00:00 AM 5.053030236 1.315309111 Normal 

## 0.260301 no WABoeingR enton BOIL04 09/27/09 07:00 8.576891645 2.234075155 normal 

## 0.260476 no WABoeingR enton BOIL04 10/14/09 04:00 11.37593152 2.963240059 normal 

## 0.260483 no WABoeingR enton BOIL04 10/16/09 07:00 11.7034357 3.050507769 normal 

## 0.260651 no WABoeingR enton BOIL04 08/18/09 07:00 10.73720545 2.802194404 normal 

## 0.26098 no WABoeingR enton BOIL04 08/25/09 12:00 7.321297616 1.913423446 normal 

## 0.26135 no TXDibollTem ple-Inland PB-44 0300-0400 29.46750896 7.703618701 

## 0.261428 no TXDibollTem ple-Inland PB-44 0600-0700 3.575209219 0.934818066 

## 0.261472 no WABoeingR enton BOIL04 10/15/09 16:00 14.34492834 3.750826902 normal 

## 0.261474 no WABoeingR enton BOIL04 10/07/09 07:00 9.875428676 2.585144108 normal 

## 0.261775 no WABoeingR enton BOIL04 08/10/09 16:00 13.84871959 3.633354633 normal 

## 0.26236 no VAPhilipMorr isPark500 B3 10/15/2009 6:00:00 PM 6.873476711 1.804148428 Normal 

## 0.26248 no VAPhilipMorr isPark500 B3 10/15/2009 7:00:00 PM 6.873476711 1.804148428 Normal 

## 0.26248 no VAPhilipMorr isPark500 B3 10/15/2009 9:00:00 PM 6.873476711 1.804148428 Normal 

## 0.26248 no VAPhilipMorr isPark500 B3 10/15/2009 5:00:00 PM 6.924268686 1.817480293 Normal 

## 0.26248 no VAPhilipMorr isPark500 B3 10/15/2009 8:00:00 PM 6.924268686 1.817480293 Normal 

## 0.26248 no VAPhilipMorr isPark500 B3 10/15/2009 7:00:00 AM 6.966198865 1.828486115 Normal 

## 0.26248 no VAPhilipMorr isPark500 B3 10/15/2009 6:00:00 AM 7.018592058 1.842238267 Normal 

## 0.26248 no VAPhilipMorr isPark500 B3 10/15/2009 8:00:00 AM 7.071779327 1.856198848 Normal 

## 0.26248 no VAPhilipMorr isPark500 B3 10/15/2009 4:00:00 PM 7.189903846 1.887204142 Normal 

## 0.26248 no VAPhilipMorr isPark500 B3 10/15/2009 3:00:00 PM 7.723226072 2.027190425 Normal 

## 0.26248 no WABoeingR enton BOIL04 08/12/09 00:00 13.82235042 3.628498715 normal 

## 0.26251 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 1000-1100 3.231587824 0.848456591 

## 0.262551 no WABoeingR enton BOIL04 10/17/09 08:00 5.568155566 1.461941509 normal 

## 0.262554 no WABoeingR enton BOIL04 10/13/09 22:00 13.3364618 3.502198825 normal 

## 0.262603 no WABoeingR enton BOIL04 10/13/09 13:00 7.792081442 2.049390408 normal 

## 0.263009 no ARDomtarIn dustries PB1 9/10/2009 9:00:00 PM 4.850419225 1.276248737 Normal 

## 0.263121 no WABoeingR enton BOIL04 10/13/09 18:00 9.321455347 2.454112459 normal 

## 0.263276 no WABoeingR enton BOIL04 10/07/09 13:00 5.576070777 1.46810653 normal 

## 0.263287 no WABoeingR enton BOIL04 08/12/09 01:00 6.108199436 1.609468907 normal 

## 0.263493 no ARDomtarIn dustries PB1 9/5/2009 9:00:00 PM 1.868125848 0.492813945 Normal 

## 0.263801 no WABoeingR enton BOIL04 09/27/09 12:00 4.968691385 1.314372955 normal 

## 0.264531 no WABoeingR enton BOIL04 08/17/09 02:00 11.40700722 3.018397161 normal 

## 0.264609 no WABoeingR enton BOIL04 08/12/09 12:00 11.55213181 3.059867452 normal 

## 0.264875 no WABoeingR enton BOIL04 09/27/09 11:00 6.030799951 1.597710946 normal 

## 0.264925 no WABoeingR enton BOIL04 10/09/09 11:00 7.235399483 1.916956789 normal 

## 0.264941 no VAPhilipMorr isPark500 B3 11/12/2009 9:00:00 AM 1.334184915 0.354744526 Normal 

## 0.265889 no VAPhilipMorr isPark500 B3 11/12/2009 8:00:00 AM 1.368671819 0.363914199 Normal 

## 0.265889 no WABoeingR enton BOIL04 08/07/09 18:00 1.206933236 0.320909758 normal 

## 0.265889 no WABoeingR enton BOIL04 10/08/09 16:00 7.781075678 2.070849994 normal 

## 0.266139 no WABoeingR enton BOIL04 10/09/09 04:00 9.140185094 2.43417014 normal 

## 0.266315 no WABoeingR enton BOIL04 10/13/09 14:00 7.129772977 1.900578543 normal 

## 0.266569 no WABoeingR enton BOIL04 10/07/09 09:00 8.576891645 2.287267421 normal 

## 0.266678 no WABoeingR enton BOIL04 08/24/09 14:00 7.114086892 1.900338733 normal 

## 0.267123 no

VAPhilipMorr isPark500 B3 10/15/2009 10:00:00 PM 6.892976702 1.8447426 Normal 

## 0.267626 no VAPhilipMorr isPark500 B3 10/20/2009 2:00:00 PM 4.162952464 1.119604273 Normal 

## 0.268945 no ARDomtarIn dustries PB1 9/10/2009 9:00:00 AM 1.554337274 0.418570348 Normal 

## 0.269292 no ARDomtarIn dustries PB1 9/1/2009 4:00:00 PM 25.9585118 6.997833607 Normal 

## 0.269578 no WABoeingR enton BOIL04 10/14/09 07:00 10.62303012 2.870303624 normal 

## 0.270196 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 10/09/09 03:00 4.981342627 1.347820983 normal 

## 0.270574 no VAPhilipMorr isPark500 B3 10/15/2009 3:00:00 AM 7.288537906 1.973826715 Normal 

## 0.270812 no WABoeingR enton BOIL04 10/09/09 13:00 6.695611193 1.814447717 normal 

## 0.270991 no WABoeingR enton BOIL04 08/25/09 02:00 5.347634554 1.451191939 normal 

## 0.271371 no WABoeingR enton BOIL04 10/15/09 23:00 12.28590463 3.34564354 normal 

## 0.272316 no WABoeingR enton BOIL04 09/28/09 05:00 7.797846943 2.124804101 normal 

## 0.272486 no VAPhilipMorr isPark500 B3 11/15/2009 5:00:00 PM 2.967208919 0.809985536 Normal 

## 0.272979 no WABoeingR enton BOIL04 08/17/09 13:00 8.772332885 2.394662104 normal 

## 0.272979 no VAPhilipMorr isPark500 B3 11/15/2009 6:00:00 PM 2.947793212 0.804685457 Normal 

## 0.272979 no WABoeingR enton BOIL04 10/09/09 00:00 3.921842556 1.071008815 normal 

## 0.273088 no WABoeingR enton BOIL04 08/17/09 07:00 9.250175288 2.530679088 normal 

## 0.273582 no WABoeingR enton BOIL04 08/14/09 15:00 9.938205569 2.725367349 normal 

## 0.274231 no WABoeingR enton BOIL04 08/24/09 15:00 4.471044537 1.226958661 normal 

## 0.274423 no ARDomtarIn dustries PB1 9/1/2009 5:00:00 PM 32.53447624 8.935515344 Normal 

## 0.274648 no ARDomtarIn dustries PB1 9/10/2009 2:00:00 PM 6.89130148 1.893007385 Normal 

## 0.274695 no ARDomtarIn dustries PB1 9/9/2009 9:00:00 PM 4.37588772 1.203830972 Normal 

## 0.275106 no ARDomtarIn dustries PB1 9/10/2009 4:00:00 PM 7.929638525 2.182821289 Normal 

## 0.275274 no ARDomtarIn dustries PB1 9/10/2009 6:00:00 PM 6.228463803 1.714684197 Normal 

## 0.275298 no WABoeingR enton BOIL04 08/14/09 14:00 10.76583692 2.96505956 normal 

## 0.275414 no WABoeingR enton BOIL04 08/19/09 05:00 4.858588754 1.339581036 normal 

## 0.275714 no VAPhilipMorr isPark500 B3 10/15/2009 5:00:00 AM 7.153564982 1.973826715 Normal 

## 0.275922 no VAPhilipMorr isPark500 B3 10/15/2009 4:00:00 AM 7.100164228 1.959092266 Normal 

## 0.275922 no

VAPhilipMorr isPark500 B3 10/15/2009 11:00:00 AM 7.163289514 1.976509928 Normal 

## 0.275922 no

VAPhilipMorr isPark500 B3 10/15/2009 12:00:00 PM 7.38483541 2.037639338 Normal 

## 0.275922 no VAPhilipMorr isPark500 B3 10/15/2009 2:00:00 PM 7.442382719 2.053517913 Normal 

## 0.275922 no WABoeingR enton BOIL04 10/07/09 11:00 6.045638298 1.668730741 normal 

## 0.276022 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 10/05/09 21:00 6.920108068 1.912248557 normal 

## 0.276332 no WABoeingR enton BOIL04 09/28/09 01:00 6.716218146 1.863109689 normal 

## 0.277405 no WABoeingR enton BOIL04 09/26/09 11:00 4.227484438 1.17451483 normal 

## 0.277828 no WABoeingR enton BOIL04 10/09/09 01:00 2.501643434 0.695304475 normal 

## 0.277939 no VAPhilipMorr isPark500 B3 11/12/2009 1.989161286 0.554080748 Normal 

## 0.27855 no WABoeingR enton BOIL04 08/13/09 05:00 6.540407938 1.821830209 normal 

## 0.27855 no VAPhilipMorr isPark500 B3 11/12/2009 1:00:00 AM 1.791421506 0.499000345 Normal 

## 0.27855 no VAPhilipMorr isPark500 B3 11/14/2009 7:00:00 PM 2.394412998 0.666963586 Normal 

## 0.27855 no WABoeingR enton BOIL04 10/07/09 12:00 3.59225724 1.000623023 normal 

## 0.27855 no VAPhilipMorr isPark500 B3 10/20/2009 1:00:00 PM 3.98789872 1.110828931 Normal 

## 0.27855 no WABoeingR enton BOIL04 08/19/09 12:00 7.501331209 2.101750429 normal 

## 0.280184 no WABoeingR enton BOIL04 08/13/09 12:00 7.88012756 2.210337299 normal 

## 0.280495 no ARDomtarIn dustries PB1 9/10/2009 4:00:00 AM 5.005003371 1.406659096 Normal 

## 0.281051 no

VAPhilipMorr isPark500 B3 10/15/2009 10:00:00 AM 7.028133108 1.976509928 Normal 

## 0.281228 no WABoeingR enton BOIL04 10/15/09 22:00 12.34089973 3.474322138 normal 

## 0.281529 no WABoeingR enton BOIL04 08/19/09 01:00 10.52531907 2.968705275 normal 

## 0.282054 no WABoeingR enton BOIL04 10/09/09 06:00 4.697616408 1.325454545 normal 

## 0.282155 no

ARDomtarIn dustries PB1 9/5/2009 11:00:00 PM 2.448279946 0.692366443 Normal 

## 0.282797 no WABoeingR enton BOIL04 08/17/09 05:00 5.935747423 1.685611193 normal 

## 0.283976 no VAPhilipMorr isPark500 B3 11/15/2009 4:00:00 PM 2.848520562 0.809985536 Normal 

## 0.284353 no ARDomtarIn dustries PB1 9/9/2009 7:00:00 PM 4.289588542 1.22183607 Normal 

## 0.284838 no WABoeingR enton BOIL04 08/14/09 08:00 9.454542552 2.696485325 normal 

## 0.285205 no WABoeingR enton BOIL04 10/05/09 20:00 5.212119612 1.49327275 normal 

## 0.2865 no WABoeingR enton BOIL04 08/14/09 04:00 12.34089973 3.538661437 normal 

## 0.286743 no WABoeingR enton BOIL04 08/12/09 08:00 10.5629565 3.031378717 normal 

## 0.286982 no WABoeingR enton BOIL04 08/25/09 11:00 7.693037694 2.209090909 normal 

## 0.287155 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/14/09 00:00 7.96205081 2.286848306 normal 

## 0.287219 no WABoeingR enton BOIL04 08/11/09 13:00 9.68087245 2.784138609 normal 

## 0.287592 no WABoeingR enton BOIL04 08/13/09 02:00 8.633814433 2.49083947 normal 

## 0.288498 no ARDomtarIn dustries PB1 8/29/2009 2:00:00 AM 14.42374051 4.166581095 Normal 

## 0.28887 no WABoeingR enton BOIL04 08/11/09 06:00 8.184237267 2.366929481 normal 

## 0.289206 no WABoeingR enton BOIL04 10/14/09 05:00 6.176234951 1.787260124 normal 

## 0.289377 no ARDomtarIn dustries PB1 9/8/2009 3:00:00 AM 2.011924742 0.582569456 Normal 

## 0.289558 no WABoeingR enton BOIL04 08/08/09 13:00 3.423878735 0.993845394 normal 

## 0.290269 no WABoeingR enton BOIL04 10/06/09 12:00 6.362434211 1.854473684 normal 

## 0.291472 no ARDomtarIn dustries PB1 9/8/2009 2:00:00 AM 2.711073269 0.791905259 Normal 

## 0.2921 no WABoeingR enton BOIL04 10/08/09 19:00 5.369686655 1.569437208 normal 

## 0.292277 no WABoeingR enton BOIL04 08/12/09 02:00 13.58944772 3.972459499 normal 

## 0.292319 no
WVDuPont Washington Works P05 9/24/2009 3:00:37 AM 0.282645912 0.082654939 

## 0.292433 no WABoeingR enton BOIL04 08/12/09 15:00 6.600548938 1.933734496 normal 

## 0.292966 no ARDomtarIn dustries PB1 9/2/2009 5:00:00 PM 16.93370552 4.961583656 Normal 

## 0.293 no ARDomtarIn dustries PB1 9/10/2009 8:00:00 PM 5.157223259 1.513991412 Normal 

## 0.293567 no WABoeingR enton BOIL04 08/14/09 11:00 9.377904832 2.753581704 normal 

## 0.293624 no TXDibollTem ple-Inland PB-44 1700-1800 62.86951373 18.49946861 

## 0.294252 no WABoeingR enton BOIL04 08/14/09 12:00 9.789127237 2.884545232 normal 

## 0.294668 no ARDomtarIn dustries PB1 8/28/2009 7:00:00 AM 3.310731574 0.977304648 Normal 

## 0.295193 no WABoeingR enton BOIL04 10/08/09 22:00 5.89515502 1.743572835 normal 

## 0.295764 no WABoeingR enton BOIL04 08/19/09 09:00 3.838657759 1.136660946 normal 

## 0.296109 no VAPhilipMorr isPark500 B3 11/15/2009 3:00:00 PM 2.711969755 0.804685457 Normal 

## 0.296716 no
WVDuPont Washington Works P05 9/22/2009 9:00:00 AM 0.712684354 0.211729728 

## 0.297088 no ARDomtarIn dustries PB1 9/1/2009 8:00:00 PM 27.52827383 8.184065544 Normal 

## 0.297297 no ARDomtarIn dustries PB1 9/7/2009 9:00:00 PM 1.693830877 0.503681983 Normal 

## 0.297363 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 09/27/09 20:00 4.782426143 1.424068491 normal 

## 0.297771 no WABoeingR enton BOIL04 08/17/09 08:00 13.71380671 4.087347842 normal 

## 0.298046 no WABoeingR enton BOIL04 08/14/09 06:00 7.197770146 2.145958543 normal 

## 0.298142 no WABoeingR enton BOIL04 10/09/09 12:00 5.796141471 1.729618077 normal 

## 0.298409 no ARDomtarIn dustries PB1 8/31/2009 6:00:00 PM 9.713838928 2.90476671 Normal 

## 0.299034 no WABoeingR enton BOIL04 08/12/09 13:00 11.5001708 3.439862374 normal 

## 0.299114 no WABoeingR enton BOIL04 08/22/09 02:00 4.487602605 1.34369624 normal 

## 0.299424 no WABoeingR enton BOIL04 10/09/09 02:00 3.249734492 0.974021779 normal 

## 0.299723 no

VAPhilipMorr isPark500 B3 11/13/2009 10:00:00 PM 1.465720505 0.439682226 Normal 

## 0.299977 no VAPhilipMorr isPark500 B3 11/12/2009 2:00:00 AM 1.606430183 0.481891872 Normal 

## 0.299977 no VAPhilipMorr isPark500 B3 11/12/2009 3:00:00 AM 1.61752124 0.485218932 Normal 

## 0.299977 no VAPhilipMorr isPark500 B3 11/12/2009 4:00:00 AM 1.61752124 0.485218932 Normal 

## 0.299977 no ARDomtarIn dustries PB1 9/2/2009 4:00:00 PM 10.50702859 3.15466425 Normal 

## 0.300243 no
WVDuPont Washington Works P05 9/22/2009 12:00:03 PM 0.799270487 0.240307501 

## 0.300659 no WABoeingR enton BOIL04 08/13/09 09:00 7.204357686 2.166089728 normal 

## 0.300664 no WABoeingR enton BOIL04 10/06/09 01:00 3.791717147 1.143180264 normal 

## 0.301494 no WABoeingR enton BOIL04 08/19/09 06:00 3.719948485 1.126628235 normal 

## 0.302861 no WABoeingR enton BOIL04 08/13/09 14:00 8.118323947 2.463320274 normal 

## 0.303427 no ARDomtarIn dustries PB1 9/1/2009 3:00:00 PM 15.29390967 4.658663213 Normal 

## 0.304609 no WABoeingR enton BOIL04 08/20/09 06:00 0.702215701 0.213939839 normal 

## 0.304664 no WABoeingR enton BOIL04 09/27/09 13:00 4.579833091 1.396632801 normal 

## 0.304953 no WABoeingR enton BOIL04 10/14/09 08:00 8.958692506 2.736097142 normal 

## 0.305413 no ARDomtarIn dustries PB1 9/2/2009 7:00:00 PM 18.15632794 5.551929257 Normal 

## 0.305785 no

ARDomtarIn dustries PB1 9/10/2009 12:00:00 PM 4.935399062 1.510546139 Normal 

## 0.306064 no WABoeingR enton BOIL04 08/12/09 21:00 3.929381556 1.205811173 normal 

## 0.30687 no WABoeingR enton BOIL04 09/28/09 07:00 4.790445508 1.470883652 normal 

## 0.307045 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/25/09 07:00 4.019569219 1.234683358 normal 

## 0.307168 no ARDomtarIn dustries PB1 9/8/2009 6:00:00 AM 2.987125617 0.917677771 Normal 

## 0.307211 no WABoeingR enton BOIL04 08/20/09 01:00 8.544662894 2.626122047 normal 

## 0.307341 no WABoeingR enton BOIL04 10/06/09 16:00 6.071130923 1.869687347 normal 

## 0.307964 no WABoeingR enton BOIL04 08/17/09 14:00 7.155975744 2.207629548 normal 

## 0.308502 no WABoeingR enton BOIL04 08/13/09 10:00 7.193358666 2.21970581 normal 

## 0.308577 no WABoeingR enton BOIL04 08/18/09 10:00 8.447890548 2.613261508 normal 

## 0.309339 no ARDomtarIn dustries PB1 9/3/2009 1:00:00 AM 22.26028196 6.892679479 Normal 

## 0.30964 no

ARDomtarIn dustries PB1 9/7/2009 10:00:00 PM 1.917723961 0.594622432 Normal 

## 0.310067 no VAPhilipMorr isPark500 B3 11/14/2009 9:00:00 PM 2.492726612 0.773252114 Normal 

## 0.310203 no VAPhilipMorr isPark500 B3 11/15/2009 1:00:00 AM 2.492726612 0.773252114 Normal 

## 0.310203 no VAPhilipMorr isPark500 B3 11/15/2009 2:00:00 PM 2.611143849 0.809985536 Normal 

## 0.310203 no VAPhilipMorr isPark500 B3 11/14/2009 5:00:00 PM 2.508432665 0.778124184 Normal 

## 0.310203 no

VAPhilipMorr isPark500 B3 11/14/2009 11:00:00 PM 2.508432665 0.778124184 Normal 

## 0.310203 no VAPhilipMorr isPark500 B3 11/15/2009 2.524339507 0.783058539 Normal 

## 0.310203 no WABoeingR enton BOIL04 08/22/09 12:00 2.760753861 0.857857318 normal 

## 0.310733 no WABoeingR enton BOIL04 08/22/09 00:00 6.649939677 2.067728672 normal 

## 0.310939 no

VAPhilipMorr isPark500 B3 10/20/2009 12:00:00 PM 3.532930312 1.102189212 Normal 

## 0.311976 no WABoeingR enton BOIL04 10/14/09 12:00 6.113998545 1.909117362 normal 

## 0.312253 no WABoeingR enton BOIL04 08/14/09 09:00 8.182301178 2.555257732 normal 

## 0.312291 no ARDomtarIn dustries PB1 9/5/2009 4:00:00 PM 4.0994765 1.281292071 Normal 

## 0.31255 no WABoeingR enton BOIL04 08/12/09 11:00 9.201099104 2.879115805 normal 

## 0.31291 no ARDomtarIn dustries PB1 8/29/2009 3:00:00 AM 7.67330777 2.402316012 Normal 

## 0.313074 no ARDomtarIn dustries PB1 9/10/2009 3:00:00 PM 6.436195487 2.016861374 Normal 

## 0.313362 no ARDomtarIn dustries PB1 9/10/2009 8:00:00 AM 1.723249826 0.540107739 Normal 

## 0.313424 no WABoeingR enton BOIL04 10/07/09 06:00 2.887811776 0.906473241 normal 

## 0.313896 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
ARDomtarIn dustries PB1 8/28/2009 2:00:00 AM 2.74326226 0.861232448 Normal 

## 0.313945 no WABoeingR enton BOIL04 08/21/09 13:00 8.848021694 2.781935166 normal 

## 0.314413 no WABoeingR enton BOIL04 09/27/09 14:00 2.486768728 0.783434588 normal 

## 0.315041 no WABoeingR enton BOIL04 08/16/09 10:00 5.818180032 1.837047771 normal 

## 0.315743 no TXDibollTem ple-Inland PB-44 0200-0300 22.18301814 7.019271628 

## 0.316425 no ARDomtarIn dustries PB1 9/9/2009 5:00:00 PM 4.889369648 1.547565936 Normal 

## 0.316516 no WABoeingR enton BOIL04 10/06/09 03:00 3.095646715 0.981123979 normal 

## 0.316937 no ARDomtarIn dustries PB1 9/3/2009 4:00:00 AM 19.64349032 6.226446982 Normal 

## 0.316973 no WABoeingR enton BOIL04 08/14/09 16:00 7.817469894 2.483150651 normal 

## 0.317641 no WABoeingR enton BOIL04 08/27/09 10:00 11.35211306 3.607091643 normal 

## 0.317746 no WABoeingR enton BOIL04 08/25/09 05:00 5.138139592 1.633934628 normal 

## 0.318001 no ARDomtarIn dustries PB1 9/1/2009 7:00:00 PM 33.3592817 10.6183104 Normal 

## 0.318302 no WABoeingR enton BOIL04 08/26/09 11:00 7.908294925 2.519955872 normal 

## 0.318647 no ARDomtarIn dustries PB1 9/1/2009 6:00:00 PM 33.10605771 10.54987846 Normal 

## 0.318669 no WABoeingR enton BOIL04 08/19/09 11:00 5.032720913 1.610456554 normal 

## 0.319997 no ARDomtarIn dustries PB1 9/9/2009 8:00:00 PM 3.990116565 1.276939849 Normal 

## 0.320026 no ARDomtarIn dustries PB1 9/3/2009 3:00:00 AM 23.68851216 7.601467176 Normal 

## 0.320893 no ARDomtarIn dustries PB1 9/3/2009 2:00:00 AM 22.29461858 7.154644326 Normal 

## 0.320914 no ARDomtarIn dustries PB1 8/31/2009 4:00:00 PM 26.47017725 8.527445735 Normal 

## 0.322153 no WABoeingR enton BOIL04 08/12/09 06:00 9.514151753 3.066839912 normal 

## 0.322345 no ARDomtarIn dustries PB1 9/1/2009 9:00:00 PM 20.32129695 6.556239379 Normal 

## 0.322629 no ARDomtarIn dustries PB1 9/4/2009 6:00:00 AM 20.40393074 6.591291756 Normal 

## 0.32304 no ARDomtarIn dustries PB1 8/27/2009 7:00:00 AM 2.491931752 0.808090471 Normal 

## 0.324283 no VAPhilipMorr isPark500 B3 11/13/2009 7:00:00 PM 1.344560061 0.436948305 Normal 

## 0.324975 no VAPhilipMorr isPark500 B3 11/13/2009 8:00:00 PM 1.344560061 0.436948305 Normal 

## 0.324975 no VAPhilipMorr isPark500 B3 11/13/2009 9:00:00 PM 1.344560061 0.436948305 Normal 

## 0.324975 no VAPhilipMorr isPark500 B3 11/15/2009 6:00:00 AM 2.052353998 0.666963586 Normal 

## 0.324975 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 11/15/2009 8:00:00 AM 2.052353998 0.666963586 Normal 

## 0.324975 no VAPhilipMorr isPark500 B3 11/14/2009 6:00:00 PM 2.409596802 0.783058539 Normal 

## 0.324975 no VAPhilipMorr isPark500 B3 10/19/2009 5:00:00 PM 3.431647351 1.11519934 Normal 

## 0.324975 no WABoeingR enton BOIL04 08/22/09 09:00 5.920989187 1.924173015 normal 

## 0.324975 no VAPhilipMorr isPark500 B3 11/12/2009 6:00:00 AM 1.493096529 0.485218932 Normal 

## 0.324975 no VAPhilipMorr isPark500 B3 11/12/2009 7:00:00 AM 1.524678535 0.495482292 Normal 

## 0.324975 no VAPhilipMorr isPark500 B3 11/14/2009 6:00:00 AM 1.701863205 0.553062867 Normal 

## 0.324975 no

VAPhilipMorr isPark500 B3 11/14/2009 11:00:00 AM 2.065368688 0.671193034 Normal 

## 0.324975 no VAPhilipMorr isPark500 B3 11/14/2009 3:00:00 PM 2.394412998 0.778124184 Normal 

## 0.324975 no VAPhilipMorr isPark500 B3 11/14/2009 8:00:00 PM 2.394412998 0.778124184 Normal 

## 0.324975 no VAPhilipMorr isPark500 B3 11/15/2009 2:00:00 AM 2.394412998 0.778124184 Normal 

## 0.324975 no VAPhilipMorr isPark500 B3 11/14/2009 4:00:00 PM 2.424972846 0.788055368 Normal 

## 0.324975 no VAPhilipMorr isPark500 B3 11/15/2009 8:00:00 PM 2.757705754 0.89618522 Normal 

## 0.324975 no VAPhilipMorr isPark500 B3 11/15/2009 7:00:00 PM 2.793327466 0.907761383 Normal 

## 0.324975 no WABoeingR enton BOIL04 10/09/09 08:00 3.107437063 1.009839126 normal 

## 0.324975 no VAPhilipMorr isPark500 B3 10/19/2009 6:00:00 PM 3.458867009 1.124045046 Normal 

## 0.324975 no WABoeingR enton BOIL04 10/14/09 10:00 5.241958763 1.707083947 normal 

## 0.325658 no ARDomtarIn dustries PB1 9/2/2009 8:00:00 PM 16.09832176 5.243176529 Normal 

## 0.325697 no WABoeingR enton BOIL04 08/22/09 10:00 7.846394919 2.567863838 normal 

## 0.327267 no WABoeingR enton BOIL04 08/26/09 01:00 10.41145345 3.412074083 normal 

## 0.327723 no ARDomtarIn dustries PB1 9/3/2009 23.08120189 7.564453297 Normal 

## 0.327732 no ARDomtarIn dustries PB1 9/10/2009 1:00:00 PM 6.512385494 2.144315316 Normal 

## 0.329267 no TXDibollTem ple-Inland PB-44 1900-2000 45.82101417 15.11006514 

## 0.329763 no ARDomtarIn dustries PB1 9/2/2009 9:00:00 PM 18.87144938 6.226270639 Normal 

## 0.329931 no WABoeingR enton BOIL04 08/14/09 07:00 9.173427835 3.027658321 normal 

## 0.330047 no

ARDomtarIn dustries PB1 9/2/2009 10:00:00 PM 19.9593507 6.62555227 Normal 

## 0.331952 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 09/27/09 23:00 4.550335644 1.510660343 normal 

## 0.331989 no ARDomtarIn dustries PB1 9/6/2009 8:00:00 AM 5.06024685 1.684888047 Normal 

## 0.332966 no WABoeingR enton BOIL04 08/17/09 11:00 6.373057262 2.128414844 normal 

## 0.333971 no WABoeingR enton BOIL04 08/21/09 17:00 3.145719539 1.050875215 normal 

## 0.334065 no TXDibollTem ple-Inland PB-44 1800-1900 63.38142259 21.19869976 

## 0.334462 no WABoeingR enton BOIL04 08/13/09 07:00 6.236443981 2.101750429 normal 

## 0.337011 no ARDomtarIn dustries PB1 9/3/2009 9:00:00 PM 8.386497593 2.828637679 Normal 

## 0.337285 no WABoeingR enton BOIL04 08/18/09 23:00 3.328622674 1.124559256 normal 

## 0.337845 no ARDomtarIn dustries PB1 9/4/2009 7:00:00 PM 26.19326857 8.853456744 Normal 

## 0.338005 no WABoeingR enton BOIL04 08/13/09 03:00 6.284291672 2.124498957 normal 

## 0.338065 no WABoeingR enton BOIL04 10/07/09 05:00 5.855994156 1.981161573 normal 

## 0.338313 no

ARDomtarIn dustries PB1 9/2/2009 11:00:00 PM 20.34602664 6.884458121 Normal 

## 0.338369 no WABoeingR enton BOIL04 08/13/09 13:00 5.267216014 1.783332924 normal 

## 0.338572 no WABoeingR enton BOIL04 08/13/09 23:00 7.730787923 2.619675994 normal 

## 0.338863 no TXDibollTem ple-Inland PB-44 1103-1203 1.441400932 0.488511698 

## 0.338915 no

VAPhilipMorr isPark500 B3 11/15/2009 11:00:00 PM 2.694341308 0.91366264 Normal 

## 0.339104 no VAPhilipMorr isPark500 B3 10/19/2009 3:00:00 PM 3.237706172 1.097919986 Normal 

## 0.339104 no VAPhilipMorr isPark500 B3 11/15/2009 9:00:00 PM 2.659761409 0.901936449 Normal 

## 0.339104 no

VAPhilipMorr isPark500 B3 11/15/2009 10:00:00 PM 2.676938822 0.907761383 Normal 

## 0.339104 no

VAPhilipMorr isPark500 B3 11/15/2009 12:00:00 PM 2.747929689 0.931834689 Normal 

## 0.339104 no VAPhilipMorr isPark500 B3 10/19/2009 4:00:00 PM 3.140389226 1.064919394 Normal 

## 0.339104 no

VAPhilipMorr isPark500 B3 11/14/2009 10:00:00 PM 2.622452331 0.889284782 Normal 

## 0.339104 no

ARDomtarIn dustries PB1 9/7/2009 12:00:00 PM 3.340404983 1.134442235 Normal 

## 0.339612 no WABoeingR enton BOIL04 08/20/09 07:00 5.873276434 1.998192312 normal 

## 0.340218 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/17/09 15:00 7.155906857 2.440152372 normal 

## 0.340998 no WABoeingR enton BOIL04 08/27/09 06:00 13.29820983 4.535524578 normal 

## 0.341063 no

VAPhilipMorr isPark500 B3 11/15/2009 10:00:00 AM 2.342905485 0.79945481 Normal 

## 0.341224 no VAPhilipMorr isPark500 B3 11/14/2009 1:00:00 PM 2.252013146 0.768440193 Normal 

## 0.341224 no VAPhilipMorr isPark500 B3 11/14/2009 2:00:00 PM 2.294854097 0.783058539 Normal 

## 0.341224 no VAPhilipMorr isPark500 B3 11/15/2009 3:00:00 AM 2.280393332 0.778124184 Normal 

## 0.341224 no WABoeingR enton BOIL04 08/27/09 11:00 11.16132223 3.812791381 normal 

## 0.341607 no
WVDuPont Washington Works P05 9/23/2009 8:00:31 PM 0.315193996 0.107717372 

## 0.341749 no WABoeingR enton BOIL04 08/17/09 01:00 5.62328582 1.924173015 normal 

## 0.342179 no WABoeingR enton BOIL04 08/19/09 10:00 6.756245079 2.314000984 normal 

## 0.342498 no
WVDuPont Washington Works P05 9/22/2009 11:00:02 AM 1.012011696 0.346614549 

## 0.342501 no WABoeingR enton BOIL04 08/25/09 09:00 10.16601868 3.482860654 normal 

## 0.342598 no ARDomtarIn dustries PB1 9/9/2009 6:00:00 PM 5.155523909 1.768226393 Normal 

## 0.342977 no VAPhilipMorr isPark500 B3 11/14/2009 9:00:00 AM 1.938334332 0.666963586 Normal 

## 0.344091 no VAPhilipMorr isPark500 B3 11/14/2009 8:00:00 AM 1.953374909 0.672138915 Normal 

## 0.344091 no

VAPhilipMorr isPark500 B3 11/14/2009 10:00:00 AM 1.963073256 0.67547603 Normal 

## 0.344091 no ARDomtarIn dustries PB1 9/1/2009 2:00:00 PM 9.997563238 3.444971947 Normal 

## 0.344581 no WABoeingR enton BOIL04 10/17/09 09:00 5.37522602 1.853980154 normal 

## 0.344912 no ARDomtarIn dustries PB1 9/5/2009 5:00:00 PM 4.276163108 1.475950211 Normal 

## 0.345158 no WABoeingR enton BOIL04 08/24/09 21:00 1.698601612 0.587616023 normal 

## 0.345941 no WABoeingR enton BOIL04 08/19/09 02:00 5.027879086 1.741430327 normal 

## 0.346355 no
WVDuPont Washington Works P05 9/23/2009 10:00:33 PM 0.313749763 0.108752834 

## 0.346623 no ARDomtarIn dustries PB1 9/4/2009 8:00:00 AM 16.06924513 5.583109916 Normal 

## 0.347441 no ARDomtarIn dustries PB1 9/4/2009 2:00:00 AM 9.606869029 3.341349544 Normal 

## 0.347808 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
WVDuPont Washington Works P05 9/23/2009 9:00:32 PM 0.277852037 0.096677863 

## 0.347947 no VAPhilipMorr isPark500 B3 11/14/2009 4:00:00 AM 1.588405658 0.553062867 Normal 

## 0.348187 no VAPhilipMorr isPark500 B3 11/14/2009 5:00:00 AM 1.598470013 0.556567149 Normal 

## 0.348187 no VAPhilipMorr isPark500 B3 11/14/2009 3:00:00 AM 1.60866169 0.560115762 Normal 

## 0.348187 no TXDibollTem ple-Inland PB-44 2100-2200 54.63706135 19.03622893 

## 0.348412 no ARDomtarIn dustries PB1 9/4/2009 3:00:00 AM 10.56561851 3.682327238 Normal 

## 0.34852 no ARDomtarIn dustries PB1 8/28/2009 2.543773641 0.887322103 Normal 

## 0.348821 no ARDomtarIn dustries PB1 9/3/2009 8:00:00 PM 7.060563771 2.463630988 Normal 

## 0.348928 no ARDomtarIn dustries PB1 9/5/2009 8:00:00 PM 2.107624509 0.73575844 Normal 

## 0.349094 no WABoeingR enton BOIL04 08/25/09 03:00 3.510597933 1.226958661 normal 

## 0.349501 no ARDomtarIn dustries PB1 9/4/2009 7:00:00 AM 22.70311838 7.996826907 Normal 

## 0.352235 no ARDomtarIn dustries PB1 9/4/2009 1:00:00 AM 8.689260615 3.078593399 Normal 

## 0.354299 no

VAPhilipMorr isPark500 B3 11/12/2009 10:00:00 AM 1.334184915 0.472992701 Normal 

## 0.354518 no

VAPhilipMorr isPark500 B3 11/12/2009 11:00:00 AM 1.334184915 0.472992701 Normal 

## 0.354518 no VAPhilipMorr isPark500 B3 10/19/2009 7:00:00 PM 3.145676738 1.11519934 Normal 

## 0.354518 no VAPhilipMorr isPark500 B3 11/13/2009 2:00:00 PM 1.224897804 0.434248442 Normal 

## 0.354518 no VAPhilipMorr isPark500 B3 11/13/2009 3:00:00 PM 1.232513389 0.436948305 Normal 

## 0.354518 no

VAPhilipMorr isPark500 B3 11/15/2009 11:00:00 AM 2.594058027 0.919640522 Normal 

## 0.354518 no VAPhilipMorr isPark500 B3 11/15/2009 1:00:00 PM 3.254109548 1.153640733 Normal 

## 0.354518 no

VAPhilipMorr isPark500 B3 10/20/2009 11:00:00 AM 3.108978675 1.102189212 Normal 

## 0.354518 no WABoeingR enton BOIL04 08/26/09 02:00 9.464957684 3.35842512 normal 

## 0.354827 no WABoeingR enton BOIL04 08/13/09 16:00 9.041277614 3.21017673 normal 

## 0.355058 no WABoeingR enton BOIL04 08/10/09 23:00 4.36423561 1.550116094 normal 

## 0.355186 no WABoeingR enton BOIL04 10/09/09 07:00 3.391248307 1.206175058 normal 

## 0.355673 no ARDomtarIn dustries PB1 9/7/2009 3:00:00 PM 3.243132754 1.153861545 Normal 

## 0.355786 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
ARDomtarIn dustries PB1 9/4/2009 4:00:00 AM 13.22081587 4.731883495 Normal 

## 0.357912 no ARDomtarIn dustries PB1 8/27/2009 6:00:00 AM 2.93826038 1.053160523 Normal 

## 0.35843 no WABoeingR enton BOIL04 08/13/09 11:00 5.935662117 2.129723349 normal 

## 0.358801 no ARDomtarIn dustries PB1 9/4/2009 5:00:00 AM 11.44896863 4.108413197 Normal 

## 0.358846 no

VAPhilipMorr isPark500 B3 11/14/2009 12:00:00 PM 2.166373665 0.778124184 Normal 

## 0.359183 no VAPhilipMorr isPark500 B3 11/15/2009 5:00:00 AM 2.166373665 0.778124184 Normal 

## 0.359183 no VAPhilipMorr isPark500 B3 10/19/2009 9:00:00 PM 2.738269715 0.983539415 Normal 

## 0.359183 no VAPhilipMorr isPark500 B3 11/15/2009 4:00:00 AM 2.180111392 0.783058539 Normal 

## 0.359183 no WABoeingR enton BOIL04 08/17/09 12:00 5.240108962 1.884975514 normal 

## 0.359721 no WABoeingR enton BOIL04 08/21/09 18:00 2.629045919 0.947708975 normal 

## 0.360476 no

ARDomtarIn dustries PB1 9/10/2009 11:00:00 AM 1.718592593 0.620130129 Normal 

## 0.360836 no WABoeingR enton BOIL04 08/27/09 08:00 11.44789442 4.147896859 normal 

## 0.362328 no TXDibollTem ple-Inland PB-44 1600-1700 4.976849171 1.81862582 

## 0.365417 no VAPhilipMorr isPark500 B3 11/13/2009 1:00:00 AM 0.89194831 0.326093439 Normal 

## 0.365597 no VAPhilipMorr isPark500 B3 11/13/2009 2:00:00 AM 0.89194831 0.326093439 Normal 

## 0.365597 no VAPhilipMorr isPark500 B3 11/14/2009 7:00:00 AM 1.826822872 0.667880579 Normal 

## 0.365597 no WABoeingR enton BOIL04 09/26/09 12:00 1.850551984 0.679209026 normal 

## 0.367031 no WABoeingR enton BOIL04 08/11/09 16:00 7.393937124 2.717971264 normal 

## 0.367595 no

ARDomtarIn dustries PB1 9/1/2009 10:00:00 PM 29.4874709 10.88216507 Normal 

## 0.369044 no

ARDomtarIn dustries PB1 9/4/2009 11:00:00 AM 8.694362109 3.219172103 Normal 

## 0.37026 no

ARDomtarIn dustries PB1 9/4/2009 10:00:00 AM 5.543843909 2.052925059 Normal 10:04 - 10:59 calibration 10:04 - 10:59 calibration 

## 0.370307 no ARDomtarIn dustries PB1 9/3/2009 2:00:00 PM 7.994735619 2.964841457 Normal 

## 0.370849 no WABoeingR enton BOIL04 08/20/09 03:00 2.953167137 1.095782881 normal 

## 0.371053 no

VAPhilipMorr isPark500 B3 10/19/2009 12:00:00 PM 2.889019891 1.072981739 Normal 

## 0.3714 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 10/19/2009 8:00:00 PM 3.002691432 1.11519934 Normal 

## 0.3714 no ARDomtarIn dustries PB1 9/4/2009 9:00:00 AM 17.57397389 6.530515353 Normal 

## 0.371602 no ARDomtarIn dustries PB1 9/5/2009 1:00:00 PM 3.742705789 1.391905086 Normal 

## 0.371898 no

ARDomtarIn dustries PB1 9/5/2009 11:00:00 AM 3.584825432 1.335065432 Normal 

## 0.372421 no WABoeingR enton BOIL04 08/18/09 11:00 6.478422407 2.412723707 normal 

## 0.372425 no ARDomtarIn dustries PB1 8/27/2009 4:00:00 AM 2.782849514 1.038933529 Normal 

## 0.373334 no

VAPhilipMorr isPark500 B3 10/1/2009 12:00:00 PM 6.858095297 2.571587311 Normal 

## 0.374971 no

VAPhilipMorr isPark500 B3 11/13/2009 11:00:00 PM 1.465720505 0.549602782 Normal 

## 0.374971 no VAPhilipMorr isPark500 B3 11/14/2009 2:00:00 AM 1.474948111 0.553062867 Normal 

## 0.374971 no VAPhilipMorr isPark500 B3 11/14/2009 1:00:00 AM 1.484293583 0.556567149 Normal 

## 0.374971 no VAPhilipMorr isPark500 B3 11/14/2009 1.493757283 0.560115762 Normal 

## 0.374971 no WABoeingR enton BOIL04 09/28/09 04:00 1.702760774 0.642605289 normal 

## 0.37739 no ARDomtarIn dustries PB1 9/3/2009 4:00:00 PM 6.33418843 2.390926216 Normal 

## 0.377464 no WABoeingR enton BOIL04 10/14/09 06:00 3.370501652 1.273720788 normal 

## 0.377902 no
WVDuPont Washington Works P05 9/22/2009 1:00:04 PM 0.700707215 0.264921406 

## 0.378077 no

ARDomtarIn dustries PB1 8/26/2009 10:00:00 PM 2.346531715 0.887713651 Normal 

## 0.378309 no

ARDomtarIn dustries PB1 9/1/2009 10:00:00 AM 7.191488609 2.725101074 Normal 10:05 - 10:55 calibration 10:05 - 10:55 calibration 

## 0.378934 no VAPhilipMorr isPark500 B3 11/15/2009 7:00:00 AM 2.039503591 0.773252114 Normal 

## 0.379137 no

VAPhilipMorr isPark500 B3 10/19/2009 10:00:00 PM 2.594150257 0.983539415 Normal 

## 0.379137 no WABoeingR enton BOIL04 08/10/09 17:00 2.738755823 1.040151998 normal 

## 0.37979 no WABoeingR enton BOIL04 09/27/09 15:00 1.47418217 0.56009181 normal 

## 0.379934 no WABoeingR enton BOIL04 08/26/09 00:00 6.634542138 2.521313389 normal 

## 0.380028 no ARDomtarIn dustries PB1 9/6/2009 2:00:00 AM 3.075938324 1.173302176 Normal 

## 0.381445 no WABoeingR enton BOIL04 09/27/09 02:00 1.500392585 0.572388222 normal 

## 0.381492 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 10/19/2009 2:00:00 PM 3.368177278 1.284933707 Normal 

## 0.381492 no TXDibollTem ple-Inland PB-44 0500-0600 30.06555288 11.47593581 

## 0.381697 no ARDomtarIn dustries PB1 9/1/2009 1:00:00 PM 10.34181759 3.947800793 Normal 

## 0.381732 no

ARDomtarIn dustries PB1 9/1/2009 12:00:00 PM 12.41725594 4.775242616 Normal 

## 0.384565 no WABoeingR enton BOIL04 08/25/09 14:00 8.522583661 3.293415354 normal 

## 0.386434 no ARDomtarIn dustries PB1 9/3/2009 6:00:00 AM 5.992606535 2.324985757 Normal 

## 0.387976 no WABoeingR enton BOIL04 10/05/09 19:00 2.327926964 0.903518997 normal 

## 0.388122 no VAPhilipMorr isPark500 B3 11/3/2009 0.635282723 0.247741146 Normal 

## 0.38997 no VAPhilipMorr isPark500 B3 11/3/2009 2:00:00 AM 0.635282723 0.247741146 Normal 

## 0.38997 no VAPhilipMorr isPark500 B3 11/2/2009 2:00:00 AM 0.712369006 0.277802477 Normal 

## 0.38997 no VAPhilipMorr isPark500 B3 11/1/2009 7:00:00 AM 0.732729054 0.285742283 Normal 

## 0.38997 no VAPhilipMorr isPark500 B3 11/1/2009 8:00:00 AM 0.732729054 0.285742283 Normal 

## 0.38997 no

VAPhilipMorr isPark500 B3 11/13/2009 12:00:00 PM 1.120466718 0.436948305 Normal 

## 0.38997 no

VAPhilipMorr isPark500 B3 11/13/2009 10:00:00 AM 1.127477312 0.439682226 Normal 

## 0.38997 no

VAPhilipMorr isPark500 B3 11/13/2009 11:00:00 AM 1.127477312 0.439682226 Normal 

## 0.38997 no

VAPhilipMorr isPark500 B3 11/12/2009 12:00:00 PM 1.229514936 0.479473828 Normal 

## 0.38997 no VAPhilipMorr isPark500 B3 11/3/2009 7:00:00 AM 0.644369042 0.251284537 Normal 

## 0.38997 no VAPhilipMorr isPark500 B3 11/1/2009 9:00:00 AM 0.729749512 0.284580351 Normal 

## 0.38997 no

ARDomtarIn dustries PB1 9/1/2009 11:00:00 PM 15.47748485 6.051428665 Normal 

## 0.390983 no WABoeingR enton BOIL04 08/25/09 01:00 3.493698279 1.366708166 normal 

## 0.391192 no

ARDomtarIn dustries PB1 9/3/2009 11:00:00 AM 5.371458283 2.103956163 Normal 

## 0.391692 no ARDomtarIn dustries PB1 8/28/2009 3:00:00 AM 3.463160098 1.35822878 Normal 

## 0.392193 no TXDibollTem ple-Inland PB-44 0100-0200 4.873571967 1.923410511 

## 0.394661 no WABoeingR enton BOIL04 10/06/09 19:00 2.245166606 0.886224826 normal 

## 0.394726 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/20/09 02:00 7.734013279 3.07626706 normal 

## 0.397758 no VAPhilipMorr isPark500 B3 10/19/2009 1:00:00 PM 3.121117497 1.244804225 Normal 

## 0.398833 no WABoeingR enton BOIL04 08/11/09 14:00 15.91059105 6.352995822 normal 

## 0.399294 no

ARDomtarIn dustries PB1 9/4/2009 12:00:00 PM 7.71894846 3.085329641 Normal 

## 0.399709 no WABoeingR enton BOIL04 08/24/09 13:00 5.379628044 2.151410743 normal 

## 0.399918 no ARDomtarIn dustries PB1 8/27/2009 8:00:00 AM 3.007502736 1.207292494 Normal 

## 0.401427 no

VAPhilipMorr isPark500 B3 10/1/2009 10:00:00 AM 22.58531624 9.066640608 Normal 

## 0.40144 no WABoeingR enton BOIL04 08/26/09 13:00 8.403948335 3.373677767 normal 

## 0.40144 no WABoeingR enton BOIL04 10/06/09 11:00 1.707988456 0.687550043 normal 

## 0.40255 no WABoeingR enton BOIL04 08/13/09 00:00 5.822343291 2.356219393 normal 

## 0.404686 no WABoeingR enton BOIL04 10/07/09 03:00 3.169005255 1.282854699 normal 

## 0.404813 no ARDomtarIn dustries PB1 9/4/2009 9:00:00 PM 6.617640801 2.682360304 Normal 

## 0.405335 no VAPhilipMorr isPark500 B3 11/13/2009 4:00:00 PM 1.344560061 0.546185381 Normal 

## 0.406219 no VAPhilipMorr isPark500 B3 11/13/2009 5:00:00 PM 1.344560061 0.546185381 Normal 

## 0.406219 no VAPhilipMorr isPark500 B3 11/13/2009 6:00:00 PM 1.352972774 0.549602782 Normal 

## 0.406219 no WABoeingR enton BOIL04 08/11/09 15:00 11.19144139 4.547068076 normal 

## 0.406299 no WABoeingR enton BOIL04 08/27/09 09:00 10.71534076 4.356339166 normal 

## 0.406552 no TXDibollTem ple-Inland PB-44 2100-2200 2.281243054 0.929241648 

## 0.40734 no WABoeingR enton BOIL04 08/13/09 08:00 5.451196613 2.222430044 normal 

## 0.407696 no

ARDomtarIn dustries PB1 9/3/2009 10:00:00 PM 5.184532872 2.119756247 Normal 

## 0.408862 no WABoeingR enton BOIL04 08/12/09 16:00 5.711991905 2.339094812 normal 

## 0.409506 no

ARDomtarIn dustries PB1 8/27/2009 11:00:00 AM 1.809171765 0.742196342 Normal 

## 0.410241 no VAPhilipMorr isPark500 B3 10/19/2009 1:00:00 AM 2.757018603 1.131741364 Normal 

## 0.410495 no VAPhilipMorr isPark500 B3 10/18/2009 8:00:00 PM 2.735087024 1.122738568 Normal 

## 0.410495 no VAPhilipMorr isPark500 B3 10/19/2009 2.735087024 1.122738568 Normal 

## 0.410495 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 10/18/2009 7:00:00 PM 2.713501615 1.113877874 Normal 

## 0.410495 no TXDibollTem ple-Inland PB-44 0400-0500 31.52477461 12.95731979 

## 0.41102 no WABoeingR enton BOIL04 10/14/09 11:00 2.611569446 1.074296942 normal 

## 0.411361 no ARDomtarIn dustries PB1 9/3/2009 5:00:00 AM 7.724569905 3.19014754 Normal 

## 0.412987 no

ARDomtarIn dustries PB1 8/27/2009 11:00:00 PM 2.896975972 1.201203552 Normal 

## 0.41464 no

ARDomtarIn dustries PB1 9/3/2009 11:00:00 PM 4.754791814 1.9745815 Normal 

## 0.415282 no WABoeingR enton BOIL04 08/27/09 02:00 10.78121375 4.495485134 normal 

## 0.416974 no

ARDomtarIn dustries PB1 8/31/2009 11:00:00 PM 4.962486726 2.072136895 Normal 

## 0.41756 no ARDomtarIn dustries PB1 9/7/2009 5:00:00 PM 2.372333488 0.991216909 Normal 

## 0.417824 no WABoeingR enton BOIL04 08/13/09 04:00 5.26075555 2.210337299 normal 

## 0.420156 no
WVDuPont Washington Works P05 10/20/2009 10:00:05 AM 0.800968022 0.337245221 

## 0.421047 no ARDomtarIn dustries PB1 9/3/2009 3:00:00 PM 6.800228438 2.864777557 Normal 

## 0.421277 no TXDibollTem ple-Inland PB-44 0100-0200 3.140507554 1.327357958 

## 0.422657 no ARDomtarIn dustries PB1 9/5/2009 9:00:00 AM 3.865240874 1.638401845 Normal 

## 0.423881 no WABoeingR enton BOIL04 08/12/09 18:00 4.325265546 1.834794554 normal 

## 0.424204 no
WVDuPont Washington Works P05 9/23/2009 11:00:34 PM 0.281520602 0.119485355 

## 0.424428 no ARDomtarIn dustries PB1 9/7/2009 6:00:00 PM 1.479157336 0.628645616 Normal 

## 0.425003 no WABoeingR enton BOIL04 08/27/09 00:00 10.05046222 4.289493764 normal 

## 0.426796 no WABoeingR enton BOIL04 08/27/09 05:00 10.63645362 4.543443725 normal 

## 0.427158 no

ARDomtarIn dustries PB1 9/1/2009 11:00:00 AM 9.235491363 3.951237161 Normal 

## 0.427832 no
WVDuPont Washington Works P05 9/22/2009 10:00:01 AM 0.643063611 0.275254795 

## 0.428037 no

ARDomtarIn dustries PB1 9/3/2009 12:00:00 PM 5.673928187 2.44058247 Normal 

## 0.43014 no

ARDomtarIn dustries PB1 8/31/2009 10:00:00 PM 4.713746219 2.03564024 Normal 

## 0.431852 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/27/09 01:00 11.26836757 4.867131328 normal 

## 0.431929 no TXDibollTem ple-Inland PB-44 10/06/2009 0000-0100 27.5530781 11.93160631 

## 0.433041 no VAPhilipMorr isPark500 B3 11/13/2009 9:00:00 AM 1.014729581 0.439682226 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/12/2009 8:00:00 PM 1.009714929 0.437509377 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/12/2009 9:00:00 PM 1.009714929 0.437509377 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/13/2009 3:00:00 AM 1.009714929 0.437509377 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/12/2009 6:00:00 PM 1.055923117 0.457531381 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/12/2009 3:00:00 PM 1.091605839 0.472992701 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/12/2009 5:00:00 PM 1.091605839 0.472992701 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/12/2009 2:00:00 PM 1.099033751 0.476211214 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/12/2009 4:00:00 PM 1.099033751 0.476211214 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/12/2009 1:00:00 PM 1.106563442 0.479473828 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 10/18/2009 5:00:00 PM 2.492013519 1.079789208 Normal 

## 0.4333 no

VAPhilipMorr isPark500 B3 10/19/2009 11:00:00 PM 2.594150257 1.124045046 Normal 

## 0.4333 no

VAPhilipMorr isPark500 B3 11/12/2009 10:00:00 PM 1.003441849 0.434791252 Normal 

## 0.4333 no

VAPhilipMorr isPark500 B3 11/12/2009 11:00:00 PM 1.003441849 0.434791252 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/13/2009 1.003441849 0.434791252 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/13/2009 4:00:00 AM 1.003441849 0.434791252 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/13/2009 5:00:00 AM 1.003441849 0.434791252 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/13/2009 6:00:00 AM 1.003441849 0.434791252 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/13/2009 7:00:00 AM 1.003441849 0.434791252 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/13/2009 8:00:00 AM 1.003441849 0.434791252 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 11/12/2009 7:00:00 PM 1.016066935 0.440261701 Normal 

## 0.4333 no VAPhilipMorr isPark500 B3 10/19/2009 2:00:00 AM 2.654485033 1.150188099 Normal 

## 0.4333 no ARDomtarIn dustries PB1 9/2/2009 6:00:00 PM 4.476715056 1.941033352 Normal 

## 0.433584 no ARDomtarIn dustries PB1 9/5/2009 8:00:00 AM 3.680265827 1.600252935 Normal 

## 0.43482 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 10/15/2009 7.673915699 3.33995113 Normal 

## 0.435234 no

ARDomtarIn dustries PB1 9/4/2009 10:00:00 PM 4.792180429 2.092496355 Normal 

## 0.436648 no ARDomtarIn dustries PB1 8/25/2009 4:00:00 AM 1.731263472 0.756746714 Normal 

## 0.437107 no ARDomtarIn dustries PB1 9/4/2009 2:00:00 PM 9.206680807 4.025703102 Normal 

## 0.437259 no ARDomtarIn dustries PB1 9/5/2009 2:00:00 AM 4.057816305 1.776065829 Normal 

## 0.43769 no ARDomtarIn dustries PB1 8/27/2009 4:00:00 PM 3.905503588 1.710296331 Normal 

## 0.43792 no ARDomtarIn dustries PB1 9/3/2009 5:00:00 PM 3.793144494 1.662854459 Normal 

## 0.438384 no VAPhilipMorr isPark500 B3 10/18/2009 9:00:00 PM 2.879038973 1.263080889 Normal 

## 0.438716 no

VAPhilipMorr isPark500 B3 10/18/2009 10:00:00 PM 2.879038973 1.263080889 Normal 

## 0.438716 no

VAPhilipMorr isPark500 B3 10/18/2009 11:00:00 PM 2.339355094 1.026312856 Normal 

## 0.438716 no WABoeingR enton BOIL04 08/25/09 13:00 4.897565313 2.156688336 normal 

## 0.440359 no
WVDuPont Washington Works P05 9/23/2009 4:00:28 PM 0.362094658 0.159613871 

## 0.440807 no WABoeingR enton BOIL04 08/18/09 00:00 5.106674844 2.25325647 normal 

## 0.441238 no WABoeingR enton BOIL04 08/16/09 09:00 4.316907216 1.91107511 normal 

## 0.442695 no VAPhilipMorr isPark500 B3 10/29/2009 8:00:00 PM 1.571571189 0.696438039 Normal 

## 0.443148 no VAPhilipMorr isPark500 B3 10/29/2009 9:00:00 PM 1.584236444 0.702050617 Normal 

## 0.443148 no WABoeingR enton BOIL04 08/23/09 11:00 0.121063412 0.053648964 normal 

## 0.443148 no VAPhilipMorr isPark500 B3 11/13/2009 1:00:00 PM 1.224897804 0.542810552 Normal 

## 0.443148 no VAPhilipMorr isPark500 B3 10/29/2009 1:00:00 PM 1.597106203 0.70775382 Normal 

## 0.443148 no WABoeingR enton BOIL04 08/24/09 23:00 1.692811466 0.75016538 normal 

## 0.443148 no VAPhilipMorr isPark500 B3 10/29/2009 4:00:00 PM 1.610188086 0.713551026 Normal 

## 0.443148 no VAPhilipMorr isPark500 B3 10/29/2009 5:00:00 PM 1.610188086 0.713551026 Normal 

## 0.443148 no VAPhilipMorr isPark500 B3 10/29/2009 6:00:00 PM 1.610188086 0.713551026 Normal 

## 0.443148 no TXDibollTem ple-Inland PB-44 2000-2100 2.701142765 1.199937593 

## 0.444233 no

VAPhilipMorr isPark500 B3 10/16/2009 11:00:00 AM 4.701696656 2.095451681 Normal 

## 0.44568 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
ARDomtarIn dustries PB1 9/4/2009 8:00:00 PM 5.171991491 2.311547013 Normal 

## 0.446936 no

ARDomtarIn dustries PB1 8/25/2009 11:00:00 AM 1.608670205 0.719960412 Normal 

## 0.44755 no WABoeingR enton BOIL04 08/26/09 05:00 5.672017641 2.539845645 normal 

## 0.447785 no ARDomtarIn dustries PB1 8/25/2009 8:00:00 AM 1.79819091 0.807786832 Normal 

## 0.449222 no ARDomtarIn dustries PB1 8/27/2009 5:00:00 AM 2.828591436 1.27150464 Normal 

## 0.449519 no VAPhilipMorr isPark500 B3 10/29/2009 8:00:00 AM 1.887489149 0.849304584 Normal 

## 0.449965 no

VAPhilipMorr isPark500 B3 10/29/2009 11:00:00 AM 1.887489149 0.849304584 Normal 

## 0.449965 no ARDomtarIn dustries PB1 9/5/2009 7:00:00 AM 4.311867583 1.942708701 Normal 

## 0.450549 no WABoeingR enton BOIL04 08/26/09 12:00 7.254672692 3.269281876 normal 

## 0.450645 no

ARDomtarIn dustries PB1 9/4/2009 11:00:00 PM 3.954757837 1.785897825 Normal 

## 0.451582 no WABoeingR enton BOIL04 08/18/09 13:00 4.034167585 1.821830209 normal 

## 0.4516 no ARDomtarIn dustries PB1 9/2/2009 2:00:00 AM 5.240523992 2.36863602 Normal 

## 0.451985 no ARDomtarIn dustries PB1 8/31/2009 9:00:00 AM 8.538647664 3.863767264 Normal 

## 0.452503 no ARDomtarIn dustries PB1 8/26/2009 2:00:00 PM 1.392389887 0.630597609 Normal 

## 0.452889 no
WVDuPont Washington Works P05 9/23/2009 5:00:29 PM 0.29538388 0.134058288 

## 0.453844 no
WVDuPont Washington Works P05 10/7/2009 2:00:29 PM 0.381995185 0.173416516 

## 0.453976 no ARDomtarIn dustries PB1 8/25/2009 7:00:00 AM 1.947086878 0.884868571 Normal 

## 0.454458 no VAPhilipMorr isPark500 B3 10/19/2009 6:00:00 AM 2.076677932 0.944815557 Normal 

## 0.454965 no VAPhilipMorr isPark500 B3 10/20/2009 2:00:00 AM 2.128034657 0.968181064 Normal 

## 0.454965 no VAPhilipMorr isPark500 B3 10/29/2009 3:00:00 AM 2.160322423 0.982870864 Normal 

## 0.454965 no VAPhilipMorr isPark500 B3 10/29/2009 2:00:00 AM 2.177872095 0.990855348 Normal 

## 0.454965 no TXDibollTem ple-Inland PB-44 1200-1300 3.309469293 1.506203991 

## 0.455119 no WABoeingR enton BOIL04 10/06/09 21:00 1.500428415 0.683354083 normal 

## 0.455439 no TXDibollTem ple-Inland PB-44 0100-0200 13.04940847 5.944457589 

## 0.455535 no TXDibollTem ple-Inland PB-44 1300-1400 2.620568756 1.195643665 

## 0.456253 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 10/20/2009 2.430750207 1.11519934 Normal 

## 0.458788 no VAPhilipMorr isPark500 B3 10/19/2009 3:00:00 AM 2.527611916 1.159638342 Normal 

## 0.458788 no
WVDuPont Washington Works P05 9/25/2009 12:00:08 PM 0.143844181 0.066008225 

## 0.458887 no TXDibollTem ple-Inland PB-44 0100-0200 24.76591985 11.37494772 

## 0.459298 no

ARDomtarIn dustries PB1 9/5/2009 10:00:00 AM 3.507703085 1.613043644 Normal 10:09 - 10:59 calibration 10:09 - 10:59 calibration 

## 0.459858 no WABoeingR enton BOIL04 08/12/09 05:00 4.006098369 1.845524347 normal 

## 0.460679 no WABoeingR enton BOIL04 08/27/09 12:00 7.32891625 3.380611971 normal 

## 0.46127 no

VAPhilipMorr isPark500 B3 10/20/2009 10:00:00 AM 2.727451614 1.259554808 Normal 

## 0.461806 no VAPhilipMorr isPark500 B3 10/18/2009 6:00:00 PM 2.630458714 1.214762859 Normal 

## 0.461806 no WABoeingR enton BOIL04 08/26/09 09:00 4.819707574 2.226335495 normal 

## 0.461923 no ARDomtarIn dustries PB1 8/29/2009 5:00:00 PM 4.701176253 2.173714174 Normal 

## 0.462377 no TXDibollTem ple-Inland PB-44 10/31/2009 0000-0100 2.561600152 1.187804948 

## 0.463696 no WABoeingR enton BOIL04 09/26/09 13:00 1.227095486 0.57169551 normal 

## 0.465893 no

ARDomtarIn dustries PB1 8/26/2009 10:00:00 AM 0.959834176 0.447599039 Normal 10:14 - 10:59 calibration 10:14 - 10:59 calibration 

## 0.46633 no

ARDomtarIn dustries PB1 9/6/2009 10:00:00 AM 6.78712577 3.167564957 Normal 10:07 - 10:59 calibration 10:07 - 10:59 calibration 

## 0.466702 no ARDomtarIn dustries PB1 8/27/2009 9:00:00 PM 2.198450817 1.02626186 Normal 

## 0.466811 no ARDomtarIn dustries PB1 9/2/2009 8.974333174 4.190835157 Normal 

## 0.46698 no ARDomtarIn dustries PB1 8/26/2009 3:00:00 AM 1.38365131 0.649123163 Normal 

## 0.469138 no ARDomtarIn dustries PB1 8/25/2009 6:00:00 AM 2.049063938 0.962032307 Normal 

## 0.469498 no

VAPhilipMorr isPark500 B3 9/21/2009 11:00:00 AM 11.30927529 5.32274818 Normal 

## 0.470653 no ARDomtarIn dustries PB1 8/25/2009 9:00:00 AM 1.82454141 0.8597234 Normal 

## 0.4712 no ARDomtarIn dustries PB1 8/26/2009 8:00:00 AM 1.072712071 0.506113726 Normal 

## 0.471808 no ARDomtarIn dustries PB1 8/27/2009 9:00:00 AM 1.682747611 0.795090603 Normal 

## 0.472495 no

ARDomtarIn dustries PB1 9/5/2009 12:00:00 PM 3.206272218 1.516811314 Normal 

## 0.473076 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/25/09 15:00 5.336608503 2.526148931 normal 

## 0.473362 no ARDomtarIn dustries PB1 8/15/2009 7:00:00 PM 4.304946566 2.040170756 Normal 

## 0.473913 no WABoeingR enton BOIL04 08/17/09 06:00 3.431694043 1.629928904 normal 

## 0.474963 no ARDomtarIn dustries PB1 8/15/2009 5:00:00 PM 3.434277843 1.634227052 Normal 

## 0.475858 no ARDomtarIn dustries PB1 9/1/2009 8:00:00 AM 4.51505871 2.15299057 Normal 

## 0.476847 no ARDomtarIn dustries PB1 8/26/2009 1:00:00 PM 1.540178398 0.734447159 Normal 

## 0.476858 no ARDomtarIn dustries PB1 9/3/2009 6:00:00 PM 3.357689996 1.602915167 Normal 

## 0.477386 no

ARDomtarIn dustries PB1 8/18/2009 11:00:00 AM 4.292289966 2.054672281 Normal 

## 0.478689 no ARDomtarIn dustries PB1 9/4/2009 1:00:00 PM 6.296426968 3.017706994 Normal 

## 0.479273 no ARDomtarIn dustries PB1 8/26/2009 9:00:00 PM 1.503280412 0.721759376 Normal 

## 0.480123 no WABoeingR enton BOIL04 10/06/09 07:00 0.738745392 0.354735807 normal 

## 0.480187 no WABoeingR enton BOIL04 08/14/09 17:00 3.105530191 1.492356406 normal 

## 0.480548 no WABoeingR enton BOIL04 08/22/09 08:00 0.849005898 0.408483657 normal 

## 0.481132 no ARDomtarIn dustries PB1 9/5/2009 6:00:00 PM 2.063694356 0.993968155 Normal 

## 0.481645 no ARDomtarIn dustries PB1 9/3/2009 8:00:00 AM 5.432720933 2.620617613 Normal 

## 0.482377 no WABoeingR enton BOIL04 09/21/09 10:00 22.43777948 10.82948458 normal 

## 0.482645 no WABoeingR enton BOIL04 08/12/09 14:00 12.59949096 6.087997049 normal 

## 0.483194 no WABoeingR enton BOIL04 08/22/09 14:00 2.170798232 1.052811003 normal 

## 0.484988 no ARDomtarIn dustries PB1 9/5/2009 3:00:00 AM 4.36727732 2.126969504 Normal 

## 0.487024 no VAPhilipMorr isPark500 B3 10/19/2009 4:00:00 AM 2.340469062 1.140890636 Normal 

## 0.487462 no

VAPhilipMorr isPark500 B3 11/2/2009 10:00:00 AM 0.568331796 0.277040374 Normal 

## 0.487462 no

VAPhilipMorr isPark500 B3 11/2/2009 12:00:00 PM 0.568331796 0.277040374 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/29/2009 6:00:00 AM 1.728257939 0.84246074 Normal 

## 0.487462 no

VAPhilipMorr isPark500 B3 10/29/2009 12:00:00 PM 1.728257939 0.84246074 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/20/2009 4:00:00 AM 1.98616568 0.968181064 Normal 

## 0.487462 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 10/29/2009 4:00:00 AM 2.016300928 0.982870864 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/29/2009 9:00:00 AM 2.016300928 0.982870864 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/19/2009 5:00:00 AM 2.198304968 1.071590987 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/18/2009 4:00:00 PM 2.473093089 1.205539861 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/17/2009 2:00:00 PM 2.879038973 1.40342321 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/17/2009 3:00:00 PM 2.879038973 1.40342321 Normal 

## 0.487462 no WABoeingR enton BOIL04 10/07/09 01:00 3.142677855 1.531937249 normal 

## 0.487462 no WABoeingR enton BOIL04 08/19/09 20:00 0.17512564 0.085367163 normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/31/2009 9:00:00 PM 0.286083214 0.139454806 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/3/2009 9:00:00 AM 0.522975241 0.25493076 Normal 

## 0.487462 no

VAPhilipMorr isPark500 B3 11/3/2009 10:00:00 AM 0.522975241 0.25493076 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/2/2009 3:00:00 AM 0.565406427 0.275614367 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/2/2009 4:00:00 AM 0.565406427 0.275614367 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/2/2009 8:00:00 AM 0.565406427 0.275614367 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/2/2009 1:00:00 PM 0.572848586 0.279242139 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/2/2009 2:00:00 PM 0.572848586 0.279242139 Normal 

## 0.487462 no

VAPhilipMorr isPark500 B3 10/30/2009 10:00:00 AM 1.413516068 0.689035917 Normal 

## 0.487462 no

VAPhilipMorr isPark500 B3 10/29/2009 11:00:00 PM 1.417369849 0.69091449 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/30/2009 1.417369849 0.69091449 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/29/2009 7:00:00 AM 1.742297676 0.849304584 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/29/2009 2:00:00 PM 1.742297676 0.849304584 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/29/2009 3:00:00 PM 1.742297676 0.849304584 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/29/2009 7:00:00 PM 1.742297676 0.849304584 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/3/2009 6:00:00 AM 0.519208111 0.253094425 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/3/2009 8:00:00 AM 0.52679705 0.256793747 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/2/2009 0.569895205 0.277802477 Normal 

## 0.487462 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 11/2/2009 1:00:00 AM 0.569895205 0.277802477 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/1/2009 4:00:00 PM 0.8975992 0.437545849 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/1/2009 5:00:00 PM 0.8975992 0.437545849 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/20/2009 1:00:00 AM 1.976669822 0.96355219 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/20/2009 8:00:00 AM 2.001794288 0.975799422 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/17/2009 4:00:00 PM 2.85631749 1.392347342 Normal 

## 0.487462 no

VAPhilipMorr isPark500 B3 10/19/2009 11:00:00 AM 3.026592266 1.475349891 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/29/2009 2.304343918 1.123280987 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/29/2009 1:00:00 AM 2.304343918 1.123280987 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 10/17/2009 5:00:00 PM 2.833949598 1.381443836 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/3/2009 1:00:00 AM 0.508226178 0.247741146 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/3/2009 3:00:00 AM 0.508226178 0.247741146 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/3/2009 4:00:00 AM 0.508226178 0.247741146 Normal 

## 0.487462 no VAPhilipMorr isPark500 B3 11/3/2009 5:00:00 AM 0.508226178 0.247741146 Normal 

## 0.487462 no WABoeingR enton BOIL04 08/18/09 12:00 3.917046955 1.914761555 normal 

## 0.488828 no ARDomtarIn dustries PB1 9/5/2009 3:00:00 PM 4.650571103 2.274461707 Normal 

## 0.489071 no TXDibollTem ple-Inland PB-44 0800-0900 2.36535523 1.156992656 

## 0.489141 no ARDomtarIn dustries PB1 9/4/2009 3:00:00 PM 4.390954824 2.152713099 Normal 

## 0.490261 no WABoeingR enton BOIL04 10/05/09 18:00 1.884296942 0.92389537 normal 

## 0.490313 no ARDomtarIn dustries PB1 9/5/2009 6:00:00 AM 4.099711721 2.011559308 Normal 

## 0.490659 no ARDomtarIn dustries PB1 9/7/2009 7:00:00 PM 2.44254751 1.199673423 Normal 

## 0.491157 no ARDomtarIn dustries PB1 8/24/2009 5:00:00 PM 3.58088051 1.762930141 Normal 

## 0.492318 no WABoeingR enton BOIL04 09/21/09 08:00 23.00142095 11.3315525 normal 

## 0.492646 no WABoeingR enton BOIL04 08/18/09 09:00 5.158540083 2.541402304 normal 

## 0.492659 no ARDomtarIn dustries PB1 9/3/2009 7:00:00 PM 2.891190305 1.427026507 Normal 

## 0.493578 no ARDomtarIn dustries PB1 9/5/2009 7:00:00 PM 4.04661955 1.9986158 Normal 

## 0.493898 no ARDomtarIn dustries PB1 9/5/2009 1:00:00 AM 4.417065025 2.182628756 Normal 

## 0.494136 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 09/21/09 11:00 23.98994587 11.87949165 normal 

## 0.495186 no TXDibollTem ple-Inland PB-44 1900-2000 2.763938451 1.368968388 

## 0.495296 no ARDomtarIn dustries PB1 9/3/2009 7:00:00 AM 5.564962588 2.775868485 Normal 

## 0.498812 no WABoeingR enton BOIL04 08/26/09 08:00 4.361570591 2.179521251 normal 

## 0.49971 no ARDomtarIn dustries PB1 9/5/2009 3.826292922 1.914766109 Normal 

## 0.500423 no ARDomtarIn dustries PB1 9/5/2009 4:00:00 AM 3.648142336 1.829280003 Normal 

## 0.501428 no WABoeingR enton BOIL04 09/21/09 09:00 15.65330173 7.879213084 normal 

## 0.503358 no WABoeingR enton BOIL04 08/12/09 22:00 4.028109898 2.027930823 normal 

## 0.503445 no ARDomtarIn dustries PB1 8/18/2009 8:00:00 PM 5.650159786 2.845310319 Normal 

## 0.503581 no WABoeingR enton BOIL04 09/21/09 04:00 36.32229901 18.33296192 normal 

## 0.50473 no ARDomtarIn dustries PB1 8/29/2009 7:00:00 AM 3.576111038 1.805485864 Normal 

## 0.504874 no WABoeingR enton BOIL04 08/22/09 13:00 2.038566867 1.031325064 normal 

## 0.505907 no ARDomtarIn dustries PB1 8/17/2009 7:00:00 AM 6.01969259 3.05514718 Normal 

## 0.507525 no WABoeingR enton BOIL04 08/26/09 06:00 3.125637189 1.588009322 normal 

## 0.508059 no WABoeingR enton BOIL04 08/16/09 06:00 2.274009549 1.15668952 normal 

## 0.508656 no TXDibollTem ple-Inland PB-44 0200-0300 4.581152492 2.333462727 

## 0.509362 no ARDomtarIn dustries PB1 9/5/2009 2:00:00 PM 2.604933979 1.33177384 Normal 

## 0.511251 no ARDomtarIn dustries PB1 8/29/2009 4:00:00 AM 3.687667367 1.885446084 Normal 

## 0.511284 no ARDomtarIn dustries PB1 8/26/2009 7:00:00 AM 1.250486043 0.640218678 Normal 

## 0.511976 no ARDomtarIn dustries PB1 8/29/2009 6:00:00 PM 5.032590102 2.578809853 Normal 

## 0.512422 no

VAPhilipMorr isPark500 B3 10/17/2009 12:00:00 PM 2.713501615 1.392347342 Normal 

## 0.513118 no VAPhilipMorr isPark500 B3 10/17/2009 7:00:00 PM 2.713501615 1.392347342 Normal 

## 0.513118 no

VAPhilipMorr isPark500 B3 10/28/2009 10:00:00 PM 2.851298861 1.463053631 Normal 

## 0.513118 no ARDomtarIn dustries PB1 8/15/2009 4:00:00 PM 4.133844896 2.122558555 Normal 

## 0.513459 no WABoeingR enton BOIL04 09/21/09 07:00 27.23265234 13.98770902 normal 

## 0.513637 no WABoeingR enton BOIL04 08/27/09 07:00 6.093048363 3.130390816 normal 

## 0.513764 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 09/21/09 05:00 21.64213762 11.12892882 normal 

## 0.514225 no ARDomtarIn dustries PB1 8/26/2009 6:00:00 PM 1.869585924 0.96246055 Normal 

## 0.514799 no
WVDuPont Washington Works P05 9/23/2009 7:00:30 PM 0.293243022 0.150974665 

## 0.514845 no ARDomtarIn dustries PB1 8/27/2009 2:00:00 PM 1.250738201 0.644284192 Normal 

## 0.515123 no

ARDomtarIn dustries PB1 8/31/2009 10:00:00 AM 24.57045371 12.6700651 Normal 

## 0.515663 no

VAPhilipMorr isPark500 B3 10/28/2009 11:00:00 PM 2.428791838 1.253588471 Normal 

## 0.516137 no VAPhilipMorr isPark500 B3 10/17/2009 8:00:00 AM 2.371713145 1.224128066 Normal 

## 0.516137 no

VAPhilipMorr isPark500 B3 10/17/2009 10:00:00 AM 2.390141787 1.233639764 Normal 

## 0.516137 no VAPhilipMorr isPark500 B3 10/18/2009 2:00:00 PM 2.447183127 1.263080889 Normal 

## 0.516137 no

VAPhilipMorr isPark500 B3 10/19/2009 10:00:00 AM 2.253425209 1.163075328 Normal 

## 0.516137 no ARDomtarIn dustries PB1 8/31/2009 5:00:00 PM 5.605484352 2.898738764 Normal 

## 0.517125 no

ARDomtarIn dustries PB1 8/18/2009 10:00:00 PM 4.763975499 2.474345898 Normal 

## 0.519387 no WABoeingR enton BOIL04 10/06/09 04:00 1.157024438 0.601606288 normal 

## 0.51996 no VAPhilipMorr isPark500 B3 10/19/2009 9:00:00 AM 2.060910907 1.071590987 Normal 

## 0.51996 no VAPhilipMorr isPark500 B3 10/19/2009 7:00:00 AM 2.076677932 1.079789208 Normal 

## 0.51996 no VAPhilipMorr isPark500 B3 10/19/2009 8:00:00 AM 2.092688069 1.088113837 Normal 

## 0.51996 no VAPhilipMorr isPark500 B3 10/20/2009 3:00:00 AM 2.144779594 1.11519934 Normal 

## 0.51996 no

VAPhilipMorr isPark500 B3 10/29/2009 10:00:00 AM 2.177872095 1.132406112 Normal 

## 0.51996 no ARDomtarIn dustries PB1 9/7/2009 8:00:00 PM 1.907923469 0.995051979 Normal 

## 0.521537 no ARDomtarIn dustries PB1 8/31/2009 4:00:00 AM 4.819830271 2.513965836 Normal 

## 0.521588 no WABoeingR enton BOIL04 10/06/09 18:00 1.91426917 1.002452761 normal 

## 0.523674 no VAPhilipMorr isPark500 B3 10/29/2009 5:00:00 AM 1.872279433 0.982870864 Normal 

## 0.524959 no VAPhilipMorr isPark500 B3 10/20/2009 7:00:00 AM 1.873552963 0.983539415 Normal 

## 0.524959 no VAPhilipMorr isPark500 B3 10/17/2009 7:00:00 AM 1.813662993 0.952099607 Normal 

## 0.524959 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 10/16/2009 7:00:00 PM 3.627325986 1.904199214 Normal 

## 0.524959 no TXDibollTem ple-Inland PB-44 0200-0300 3.140507554 1.650940851 

## 0.525692 no ARDomtarIn dustries PB1 8/31/2009 7:00:00 AM 6.637622743 3.494755564 Normal 

## 0.526507 no
WVDuPont Washington Works P05 9/22/2009 3:00:05 PM 0.553685529 0.291556734 

## 0.526575 no

ARDomtarIn dustries PB1 8/27/2009 10:00:00 AM 1.598773192 0.841989851 Normal 10:09 - 10:53 calibration 10:09 - 10:53 calibration 

## 0.526647 no WABoeingR enton BOIL04 09/21/09 03:00 32.7873821 17.28406445 normal 

## 0.527156 no ARDomtarIn dustries PB1 8/24/2009 3:00:00 PM 3.900395641 2.059269635 Normal 

## 0.527964 no WABoeingR enton BOIL04 09/27/09 01:00 0.902957081 0.47727934 normal 

## 0.528574 no

ARDomtarIn dustries PB1 8/30/2009 11:00:00 AM 3.573853579 1.892008882 Normal 

## 0.529403 no ARDomtarIn dustries PB1 8/31/2009 5:00:00 AM 6.460808021 3.42476087 Normal 

## 0.530082 no WABoeingR enton BOIL04 08/24/09 22:00 1.494950386 0.793031974 normal 

## 0.530474 no TXDibollTem ple-Inland PB-44 0900-1000 4.386001526 2.328824927 

## 0.530968 no TXDibollTem ple-Inland PB-44 0700-0800 3.102529551 1.649832911 

## 0.53177 no

VAPhilipMorr isPark500 B3 10/29/2009 10:00:00 PM 1.571571189 0.835725647 Normal 

## 0.531777 no ARDomtarIn dustries PB1 9/1/2009 1:00:00 AM 4.616320427 2.45898487 Normal 

## 0.532672 no

ARDomtarIn dustries PB1 8/26/2009 12:00:00 PM 1.406515737 0.750718098 Normal 

## 0.533743 no ARDomtarIn dustries PB1 8/17/2009 9:00:00 AM 4.376462819 2.339714067 Normal 

## 0.534613 no WABoeingR enton BOIL04 09/21/09 06:00 10.84648352 5.798922368 normal 

## 0.534636 no ARDomtarIn dustries PB1 8/25/2009 3:00:00 AM 1.585007656 0.848562751 Normal 

## 0.535368 no ARDomtarIn dustries PB1 9/2/2009 1:00:00 AM 5.522710662 2.961143582 Normal 

## 0.536176 no VAPhilipMorr isPark500 B3 10/17/2009 1:00:00 PM 2.879038973 1.543765531 Normal 

## 0.536209 no VAPhilipMorr isPark500 B3 10/17/2009 6:00:00 PM 2.833949598 1.51958822 Normal 

## 0.536209 no ARDomtarIn dustries PB1 8/26/2009 5:00:00 AM 1.128909196 0.606286283 Normal 

## 0.537055 no ARDomtarIn dustries PB1 8/31/2009 1:00:00 AM 5.325738436 2.868645832 Normal 

## 0.538638 no ARDomtarIn dustries PB1 9/4/2009 5.013967224 2.705959476 Normal 

## 0.539684 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 0700-0800 3.098862227 1.675262789 

## 0.540606 no ARDomtarIn dustries PB1 9/2/2009 3:00:00 AM 3.983868457 2.155038008 Normal 

## 0.540941 no VAPhilipMorr isPark500 B3 10/30/2009 8:00:00 AM 1.285830973 0.696438039 Normal 

## 0.541625 no

VAPhilipMorr isPark500 B3 10/17/2009 11:00:00 AM 2.550554638 1.381443836 Normal 

## 0.541625 no VAPhilipMorr isPark500 B3 10/17/2009 8:00:00 PM 2.550554638 1.381443836 Normal 

## 0.541625 no VAPhilipMorr isPark500 B3 10/30/2009 3:00:00 AM 1.265595248 0.685477868 Normal 

## 0.541625 no VAPhilipMorr isPark500 B3 10/30/2009 1:00:00 AM 1.275632864 0.69091449 Normal 

## 0.541625 no VAPhilipMorr isPark500 B3 10/30/2009 2:00:00 AM 1.275632864 0.69091449 Normal 

## 0.541625 no VAPhilipMorr isPark500 B3 10/30/2009 4:00:00 AM 1.275632864 0.69091449 Normal 

## 0.541625 no VAPhilipMorr isPark500 B3 10/30/2009 5:00:00 AM 1.275632864 0.69091449 Normal 

## 0.541625 no VAPhilipMorr isPark500 B3 10/30/2009 6:00:00 AM 1.275632864 0.69091449 Normal 

## 0.541625 no VAPhilipMorr isPark500 B3 10/30/2009 7:00:00 AM 1.275632864 0.69091449 Normal 

## 0.541625 no VAPhilipMorr isPark500 B3 10/30/2009 9:00:00 AM 1.282264211 0.694506192 Normal 

## 0.541625 no

VAPhilipMorr isPark500 B3 10/30/2009 11:00:00 AM 1.282264211 0.694506192 Normal 

## 0.541625 no VAPhilipMorr isPark500 B3 10/18/2009 3:00:00 PM 2.570685741 1.392347342 Normal 

## 0.541625 no VAPhilipMorr isPark500 B3 10/20/2009 9:00:00 AM 2.573735513 1.393999175 Normal 

## 0.541625 no ARDomtarIn dustries PB1 8/29/2009 4:00:00 PM 5.284148302 2.862228057 Normal 

## 0.541663 no TXDibollTem ple-Inland PB-44 1900-2000 1.682230176 0.911370602 

## 0.541763 no ARDomtarIn dustries PB1 8/31/2009 6:00:00 AM 5.960540726 3.245210093 Normal 

## 0.544449 no VAPhilipMorr isPark500 B3 9/17/2009 5:00:00 PM 4.451435129 2.425190394 Normal 

## 0.544811 no ARDomtarIn dustries PB1 9/1/2009 9:00:00 AM 4.025544476 2.193852653 Normal 

## 0.544983 no TXDibollTem ple-Inland PB-44 0200-0300 2.717284004 1.483417696 

## 0.545919 no WABoeingR enton BOIL04 08/26/09 10:00 3.576911225 1.957549523 normal 

## 0.547274 no ARDomtarIn dustries PB1 8/28/2009 1:00:00 AM 1.962310324 1.075181032 Normal 

## 0.547916 no VAPhilipMorr isPark500 B3 10/18/2009 1:00:00 PM 2.285053992 1.253112608 Normal 

## 0.548395 no ARDomtarIn dustries PB1 8/25/2009 1:00:00 AM 1.816624515 0.997730554 Normal 

## 0.549222 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
ARDomtarIn dustries PB1 8/26/2009 9:00:00 AM 0.948587949 0.521526185 Normal 

## 0.549792 no WABoeingR enton BOIL04 08/17/09 22:00 3.677908969 2.02296831 normal 

## 0.550032 no WABoeingR enton BOIL04 08/11/09 05:00 1.18426494 0.652117805 normal 

## 0.550652 no ARDomtarIn dustries PB1 8/26/2009 7:00:00 PM 2.250954233 1.239493334 Normal 

## 0.550652 no TXDibollTem ple-Inland PB-44 1600-1700 2.475109274 1.363379121 

## 0.550836 no

ARDomtarIn dustries PB1 8/14/2009 11:00:00 AM 3.724359735 2.05278474 Normal 

## 0.551178 no WABoeingR enton BOIL04 08/13/09 21:00 2.175139569 1.199529873 normal 

## 0.551473 no ARDomtarIn dustries PB1 8/26/2009 6:00:00 AM 1.205508013 0.66491339 Normal 

## 0.551563 no ARDomtarIn dustries PB1 8/25/2009 7:00:00 PM 1.656474275 0.915588662 Normal 

## 0.552733 no ARDomtarIn dustries PB1 8/26/2009 4:00:00 AM 1.270097948 0.702268987 Normal 

## 0.552925 no ARDomtarIn dustries PB1 8/29/2009 7:00:00 PM 3.958864065 2.193881075 Normal 

## 0.554169 no WABoeingR enton BOIL04 08/17/09 18:00 3.767499085 2.092771878 normal 

## 0.55548 no

ARDomtarIn dustries PB1 9/2/2009 12:00:00 PM 2.422052224 1.346117191 Normal 

## 0.555775 no
WVDuPont Washington Works P05 9/23/2009 6:00:29 PM 0.287996148 0.160136688 

## 0.556038 no WABoeingR enton BOIL04 08/16/09 11:00 2.876032175 1.600702444 normal 

## 0.556566 no VAPhilipMorr isPark500 B3 11/1/2009 3:00:00 PM 1.047199066 0.583394465 Normal 

## 0.5571 no WABoeingR enton BOIL04 08/22/09 03:00 0.615945085 0.343142927 normal 

## 0.5571 no VAPhilipMorr isPark500 B3 10/20/2009 5:00:00 AM 2.017672422 1.124045046 Normal 

## 0.5571 no VAPhilipMorr isPark500 B3 10/20/2009 6:00:00 AM 2.017672422 1.124045046 Normal 

## 0.5571 no VAPhilipMorr isPark500 B3 10/16/2009 5:00:00 PM 2.88527527 1.607386481 Normal 

## 0.5571 no

VAPhilipMorr isPark500 B3 10/30/2009 10:00:00 PM 1.038541667 0.578571429 Normal 

## 0.5571 no WABoeingR enton BOIL04 08/25/09 04:00 1.389282379 0.773969034 normal 

## 0.5571 no WABoeingR enton BOIL04 08/26/09 14:00 7.393277424 4.123383937 normal 

## 0.557721 no

ARDomtarIn dustries PB1 8/18/2009 10:00:00 AM 4.472604851 2.497481577 Normal 10:04 - 10:57 calibration 10:04 - 10:57 calibration 

## 0.558395 no ARDomtarIn dustries PB1 9/2/2009 9:00:00 AM 3.044005347 1.699908972 Normal 

## 0.558445 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 1000-1100 2.374852447 1.332908671 

## 0.56126 no TXDibollTem ple-Inland PB-44 2200-2300 2.189601449 1.228955476 

## 0.561269 no ARDomtarIn dustries PB1 8/15/2009 3:00:00 PM 6.077771867 3.415095345 Normal 

## 0.561899 no ARDomtarIn dustries PB1 8/24/2009 6:00:00 PM 2.763250289 1.557905401 Normal 

## 0.563795 no ARDomtarIn dustries PB1 8/16/2009 3:00:00 PM 9.48061389 5.349110514 Normal 

## 0.564216 no ARDomtarIn dustries PB1 9/3/2009 1:00:00 PM 3.69484994 2.084786637 Normal 

## 0.564241 no VAPhilipMorr isPark500 B3 10/17/2009 1:00:00 AM 2.713501615 1.531582076 Normal 

## 0.56443 no VAPhilipMorr isPark500 B3 10/17/2009 2.735087024 1.543765531 Normal 

## 0.56443 no TXDibollTem ple-Inland PB-44 1800-1900 3.841889498 2.171449477 

## 0.565204 no ARDomtarIn dustries PB1 8/25/2009 4:00:00 PM 1.65437429 0.936409145 Normal 

## 0.56602 no TXDibollTem ple-Inland PB-44 1000-1100 5.706175912 3.234552581 

## 0.566851 no WABoeingR enton BOIL04 08/18/09 01:00 2.841779164 1.615245781 normal 

## 0.568392 no WABoeingR enton BOIL04 08/18/09 15:00 0.264138354 0.150217098 normal 

## 0.568706 no ARDomtarIn dustries PB1 9/1/2009 5:00:00 AM 3.606489468 2.05106786 Normal 

## 0.568716 no

ARDomtarIn dustries PB1 8/25/2009 10:00:00 AM 2.104191023 1.197078974 Normal 10:23 - 10:59 calibration 10:23 - 10:59 calibration 

## 0.568902 no TXDibollTem ple-Inland PB-44 2100-2200 1.601612587 0.914290144 

## 0.570856 no TXDibollTem ple-Inland PB-44 0100-0200 8.508901541 4.869083725 

## 0.572234 no ARDomtarIn dustries PB1 8/26/2009 5:00:00 PM 1.669404411 0.957265248 Normal 

## 0.573417 no VAPhilipMorr isPark500 B3 10/17/2009 9:00:00 PM 2.427869866 1.392347342 Normal 

## 0.573485 no

VAPhilipMorr isPark500 B3 10/17/2009 10:00:00 PM 2.427869866 1.392347342 Normal 

## 0.573485 no ARDomtarIn dustries PB1 8/25/2009 8:00:00 PM 1.572505805 0.90240263 Normal 

## 0.573863 no WABoeingR enton BOIL04 08/12/09 23:00 2.705758764 1.554866389 normal 

## 0.574651 no ARDomtarIn dustries PB1 8/24/2009 4:00:00 PM 4.306468973 2.479522667 Normal 

## 0.575767 no VAPhilipMorr isPark500 B3 10/16/2009 4:00:00 PM 2.999890585 1.728212703 Normal 

## 0.576092 no ARDomtarIn dustries PB1 8/15/2009 8:00:00 PM 4.959757275 2.857637792 Normal 

## 0.576165 no TXDibollTem ple-Inland PB-44 1215-1315 1.409358893 0.814293374 

## 0.577776 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
ARDomtarIn dustries PB1 8/25/2009 5:00:00 AM 2.350606417 1.358599086 Normal 

## 0.577978 no ARDomtarIn dustries PB1 8/31/2009 3:00:00 AM 3.772696358 2.18238727 Normal 

## 0.578469 no ARDomtarIn dustries PB1 9/1/2009 6:00:00 AM 3.922693496 2.269509816 Normal 

## 0.578559 no ARDomtarIn dustries PB1 9/2/2009 3:00:00 PM 3.168125389 1.838365837 Normal 

## 0.580269 no ARDomtarIn dustries PB1 8/27/2009 3:00:00 AM 1.741664056 1.013510474 Normal 

## 0.581921 no ARDomtarIn dustries PB1 8/16/2009 5:00:00 AM 6.101981724 3.551691871 Normal 

## 0.582055 no TXDibollTem ple-Inland PB-44 1100-1200 2.927262354 1.705160245 

## 0.58251 no ARDomtarIn dustries PB1 8/30/2009 1:00:00 PM 8.232590583 4.796394467 Normal 

## 0.582611 no TXDibollTem ple-Inland PB-44 2300-2400 1.519478227 0.885987426 

## 0.583087 no ARDomtarIn dustries PB1 8/26/2009 8:00:00 PM 1.727941667 1.009049295 Normal 

## 0.58396 no WABoeingR enton BOIL04 08/16/09 07:00 2.223164479 1.298304918 normal 

## 0.58399 no

ARDomtarIn dustries PB1 8/25/2009 12:00:00 PM 2.090911193 1.221605708 Normal 

## 0.584246 no VAPhilipMorr isPark500 B3 10/16/2009 6:00:00 PM 2.74788121 1.607386481 Normal 

## 0.584955 no VAPhilipMorr isPark500 B3 11/1/2009 8:00:00 PM 0.706758034 0.41342155 Normal 

## 0.584955 no VAPhilipMorr isPark500 B3 11/1/2009 9:00:00 PM 0.706758034 0.41342155 Normal 

## 0.584955 no VAPhilipMorr isPark500 B3 11/2/2009 9:00:00 AM 0.710414745 0.415560561 Normal 

## 0.584955 no VAPhilipMorr isPark500 B3 11/1/2009 6:00:00 PM 0.712369006 0.416703715 Normal 

## 0.584955 no

VAPhilipMorr isPark500 B3 11/1/2009 11:00:00 PM 0.718069782 0.420038412 Normal 

## 0.584955 no VAPhilipMorr isPark500 B3 11/1/2009 3:00:00 AM 0.726794103 0.425141746 Normal 

## 0.584955 no VAPhilipMorr isPark500 B3 11/1/2009 6:00:00 AM 0.732729054 0.428613425 Normal 

## 0.584955 no

VAPhilipMorr isPark500 B3 10/16/2009 11:00:00 PM 2.142238117 1.253112608 Normal 

## 0.584955 no

VAPhilipMorr isPark500 B3 10/18/2009 11:00:00 AM 2.142238117 1.253112608 Normal 

## 0.584955 no VAPhilipMorr isPark500 B3 10/17/2009 4:00:00 AM 2.15927923 1.263080889 Normal 

## 0.584955 no VAPhilipMorr isPark500 B3 11/1/2009 7:00:00 PM 0.695797146 0.407009926 Normal 

## 0.584955 no

VAPhilipMorr isPark500 B3 11/1/2009 10:00:00 PM 0.701234761 0.410190685 Normal 

## 0.584955 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 10/16/2009 9:00:00 PM 2.790250759 1.632170755 Normal 

## 0.584955 no VAPhilipMorr isPark500 B3 10/17/2009 9:00:00 AM 2.811931515 1.644853018 Normal 

## 0.584955 no ARDomtarIn dustries PB1 8/31/2009 3:00:00 PM 4.504771594 2.635526562 Normal 

## 0.585052 no ARDomtarIn dustries PB1 8/27/2009 8:00:00 PM 2.640721643 1.549587063 Normal 

## 0.586804 no ARDomtarIn dustries PB1 8/31/2009 8:00:00 PM 10.11016291 5.937442264 Normal 

## 0.587275 no WABoeingR enton BOIL04 09/21/09 02:00 23.59321014 13.87691658 normal 

## 0.588174 no TXDibollTem ple-Inland PB-44 1300-1400 1.584800151 0.932358818 

## 0.588313 no WABoeingR enton BOIL04 09/26/09 17:00 0.931078668 0.548861004 normal 

## 0.589489 no TXDibollTem ple-Inland PB-44 2200-2300 1.461035635 0.861590582 

## 0.589712 no ARDomtarIn dustries PB1 8/18/2009 9:00:00 PM 4.428473024 2.614441139 Normal 

## 0.590371 no ARDomtarIn dustries PB1 8/25/2009 6:00:00 PM 1.643717719 0.971832271 Normal 

## 0.59124 no ARDomtarIn dustries PB1 8/27/2009 3:00:00 PM 1.808576439 1.069622568 Normal 

## 0.591417 no VAPhilipMorr isPark500 B3 10/16/2009 3:00:00 PM 3.112793692 1.847232854 Normal 

## 0.593432 no VAPhilipMorr isPark500 B3 10/16/2009 8:00:00 PM 3.233721242 1.918995188 Normal 

## 0.593432 no

ARDomtarIn dustries PB1 8/16/2009 10:00:00 AM 20.49161626 12.18592825 Normal 10:04 - 10:59 calibration 10:04 - 10:59 calibration 

## 0.594679 no TXDibollTem ple-Inland PB-44 1400-1500 1.533078772 0.912780499 

## 0.59539 no WABoeingR enton BOIL04 08/26/09 07:00 3.214831255 1.914761555 normal 

## 0.595603 no ARDomtarIn dustries PB1 8/31/2009 7:00:00 PM 5.365180066 3.196379057 Normal 

## 0.595764 no VAPhilipMorr isPark500 B3 10/17/2009 2:00:00 AM 2.570685741 1.531582076 Normal 

## 0.595787 no ARDomtarIn dustries PB1 9/1/2009 7:00:00 AM 3.313942332 1.981080524 Normal 

## 0.597802 no WABoeingR enton BOIL04 08/27/09 03:00 5.562865004 3.32676449 normal 

## 0.598031 no WABoeingR enton BOIL04 08/19/09 15:00 2.166806815 1.297509193 normal 

## 0.598812 no TXDibollTem ple-Inland PB-44 0902-1002 1.218967143 0.731251852 

## 0.599895 no VAPhilipMorr isPark500 B3 10/17/2009 6:00:00 AM 1.827755484 1.096568679 Normal 

## 0.599954 no VAPhilipMorr isPark500 B3 10/17/2009 5:00:00 AM 1.842067239 1.105155069 Normal 

## 0.599954 no ARDomtarIn dustries PB1 8/21/2009 8:00:00 AM 37.82395732 22.69304031 Normal 

## 0.599965 no ARDomtarIn dustries PB1 8/25/2009 5:00:00 PM 1.769265197 1.0619126 Normal 

## 0.6002 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
ARDomtarIn dustries PB1 8/29/2009 8:00:00 AM 3.538425739 2.123887946 Normal 

## 0.600235 no TXDibollTem ple-Inland PB-44 0400-0500 3.127771994 1.883775751 

## 0.602274 no ARDomtarIn dustries PB1 9/5/2009 5:00:00 AM 2.909257256 1.753640456 Normal 

## 0.602779 no TXDibollTem ple-Inland PB-44 1002-1103 1.194271878 0.719919918 

## 0.602811 no ARDomtarIn dustries PB1 8/29/2009 1:00:00 PM 6.478269345 3.912336803 Normal 

## 0.603917 no ARDomtarIn dustries PB1 8/16/2009 6:00:00 AM 5.523696619 3.338811596 Normal 

## 0.604452 no
WVDuPont Washington Works P05 9/23/2009 10:00:22 AM 0.349523292 0.211291243 

## 0.604513 no ARDomtarIn dustries PB1 8/18/2009 6:00:00 PM 4.593806919 2.777573492 Normal 

## 0.604634 no ARDomtarIn dustries PB1 8/25/2009 2:00:00 AM 1.806882698 1.092805902 Normal 

## 0.604802 no WABoeingR enton BOIL04 08/20/09 08:00 1.506865653 0.9114734 normal 

## 0.60488 no ARDomtarIn dustries PB1 8/20/2009 9:00:00 AM 15.17077884 9.191302534 Normal 

## 0.605856 no

ARDomtarIn dustries PB1 8/27/2009 12:00:00 PM 1.879553173 1.139218725 Normal 

## 0.606111 no

ARDomtarIn dustries PB1 8/19/2009 10:00:00 AM 9.528604774 5.778440907 Normal 10:05 - 10:55 calibration 10:05 - 10:55 calibration 

## 0.606431 no ARDomtarIn dustries PB1 8/26/2009 4:00:00 PM 1.690228376 1.025539974 Normal 

## 0.606746 no ARDomtarIn dustries PB1 8/15/2009 6:00:00 PM 4.207609351 2.553990084 Normal 

## 0.606993 no TXDibollTem ple-Inland PB-44 1702-1802 1.43879328 0.873396332 

## 0.607034 no TXDibollTem ple-Inland PB-44 1900-2000 1.53034696 0.931432554 

## 0.608641 no TXDibollTem ple-Inland PB-44 1500-1600 1.172023319 0.713433661 

## 0.60872 no

ARDomtarIn dustries PB1 8/16/2009 11:00:00 AM 9.852440357 6.000579318 Normal 

## 0.609045 no ARDomtarIn dustries PB1 9/2/2009 1:00:00 PM 2.169041773 1.321502968 Normal 

## 0.609257 no WABoeingR enton BOIL04 08/24/09 16:00 0.792415062 0.482840672 normal 

## 0.609328 no

VAPhilipMorr isPark500 B3 10/30/2009 12:00:00 PM 1.130812854 0.689035917 Normal 

## 0.609328 no VAPhilipMorr isPark500 B3 10/30/2009 2:00:00 PM 1.130812854 0.689035917 Normal 

## 0.609328 no VAPhilipMorr isPark500 B3 10/30/2009 1:00:00 PM 1.13979041 0.694506192 Normal 

## 0.609328 no VAPhilipMorr isPark500 B3 10/30/2009 4:00:00 PM 1.177172844 0.717284356 Normal 

## 0.609328 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 10/30/2009 7:00:00 PM 1.186904762 0.723214286 Normal 

## 0.609328 no VAPhilipMorr isPark500 B3 10/30/2009 8:00:00 PM 1.196798933 0.729243081 Normal 

## 0.609328 no VAPhilipMorr isPark500 B3 10/30/2009 9:00:00 PM 1.196798933 0.729243081 Normal 

## 0.609328 no

VAPhilipMorr isPark500 B3 10/17/2009 11:00:00 PM 2.285053992 1.392347342 Normal 

## 0.609328 no

VAPhilipMorr isPark500 B3 10/18/2009 12:00:00 PM 2.285053992 1.392347342 Normal 

## 0.609328 no VAPhilipMorr isPark500 B3 10/30/2009 3:00:00 PM 1.148911652 0.70006402 Normal 

## 0.609328 no VAPhilipMorr isPark500 B3 10/30/2009 6:00:00 PM 1.148911652 0.70006402 Normal 

## 0.609328 no VAPhilipMorr isPark500 B3 10/30/2009 5:00:00 PM 1.158180058 0.70571152 Normal 

## 0.609328 no

VAPhilipMorr isPark500 B3 10/16/2009 10:00:00 PM 2.232200607 1.360142296 Normal 

## 0.609328 no WABoeingR enton BOIL04 08/19/09 18:00 0.263330888 0.160454879 normal 

## 0.609328 no ARDomtarIn dustries PB1 8/17/2009 6:00:00 AM 4.745841256 2.893170922 Normal 

## 0.609622 no TXDibollTem ple-Inland PB-44 1400-1500 1.545846388 0.942945025 

## 0.609986 no TXDibollTem ple-Inland PB-44 1500-1600 2.771563157 1.692270647 

## 0.610583 no WABoeingR enton BOIL04 09/19/09 10:00 45.0291467 27.51495338 normal 

## 0.611048 no ARDomtarIn dustries PB1 8/20/2009 8:00:00 AM 29.34682156 17.93389725 Normal 

## 0.611102 no

ARDomtarIn dustries PB1 8/30/2009 12:00:00 PM 7.112565882 4.349881761 Normal 

## 0.611577 no

ARDomtarIn dustries PB1 8/19/2009 11:00:00 AM 13.87639539 8.494532562 Normal 

## 0.612157 no

ARDomtarIn dustries PB1 8/31/2009 1:00:00 PM 10.06406011 6.164776699 Normal 13:04 - 13:55 calibration for 8/30 13:04 - 13:55 calibration for 8/30 

## 0.612554 no ARDomtarIn dustries PB1 8/18/2009 5:00:00 PM 4.661882671 2.857075488 Normal 

## 0.612859 no

ARDomtarIn dustries PB1 9/10/2009 10:00:00 AM 3.696186176 2.266236648 Normal 10:05 - 10:59 calibration 10:05 - 10:59 calibration 

## 0.613128 no ARDomtarIn dustries PB1 8/30/2009 3:00:00 AM 11.93370877 7.320986401 Normal 

## 0.613471 no TXDibollTem ple-Inland PB-44 0300-0400 2.69824229 1.655751682 

## 0.613641 no TXDibollTem ple-Inland PB-44 10/02/09 0000-0100 2.421368809 1.486489348 

## 0.613905 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
ARDomtarIn dustries PB1 8/31/2009 8:00:00 AM 5.13798163 3.156333397 Normal 

## 0.614314 no ARDomtarIn dustries PB1 8/18/2009 2:00:00 AM 4.491836407 2.761045712 Normal 

## 0.614681 no ARDomtarIn dustries PB1 8/16/2009 1:00:00 PM 7.281502376 4.478666541 Normal 

## 0.615075 no TXDibollTem ple-Inland PB-44 10/17/2009 0000-0100 13.91112102 8.559421272 

## 0.615293 no TXDibollTem ple-Inland PB-44 1500-1600 1.369157654 0.843368534 

## 0.615976 no

ARDomtarIn dustries PB1 8/15/2009 10:00:00 PM 4.571959818 2.821011085 Normal 

## 0.617024 no TXDibollTem ple-Inland PB-44 1800-1900 1.494563339 0.922383538 

## 0.617159 no TXDibollTem ple-Inland PB-44 1700-1800 1.477140366 0.911632181 

## 0.61716 no TXDibollTem ple-Inland PB-44 2000-2100 1.579215976 0.976397936 

## 0.61828 no ARDomtarIn dustries PB1 8/16/2009 4:00:00 PM 11.63037826 7.194607332 Normal 

## 0.618605 no TXDibollTem ple-Inland PB-44 2200-2300 3.617918894 2.240632035 

## 0.619315 no TXDibollTem ple-Inland PB-44 1600-1700 1.616914129 1.001425637 

## 0.619344 no ARDomtarIn dustries PB1 8/25/2009 1.89477871 1.17386525 Normal 

## 0.619526 no TXDibollTem ple-Inland PB-44 1800-1900 2.154311237 1.33583962 

## 0.620077 no ARDomtarIn dustries PB1 9/2/2009 2:00:00 PM 2.760472676 1.718271025 Normal 

## 0.622455 no ARDomtarIn dustries PB1 8/26/2009 3:00:00 PM 1.942071555 1.209279869 Normal 

## 0.622675 no WABoeingR enton BOIL04 08/26/09 15:00 5.415877816 3.373677767 normal 

## 0.622924 no TXDibollTem ple-Inland PB-44 1800-1900 3.177471567 1.981036589 

## 0.623463 no WABoeingR enton BOIL04 08/26/09 03:00 3.979206174 2.486262404 normal 

## 0.624814 no

ARDomtarIn dustries PB1 8/24/2009 10:00:00 PM 1.944726436 1.21621143 Normal 

## 0.625389 no ARDomtarIn dustries PB1 8/15/2009 9:00:00 PM 5.236927358 3.278927413 Normal 

## 0.626117 no TXDibollTem ple-Inland PB-44 1700-1800 1.428673017 0.895101775 

## 0.626527 no VAPhilipMorr isPark500 B3 10/18/2009 1:00:00 AM 2.015327281 1.263080889 Normal 

## 0.626737 no WABoeingR enton BOIL04 10/08/09 17:00 1.081217263 0.677639248 normal 

## 0.626737 no

ARDomtarIn dustries PB1 8/15/2009 12:00:00 PM 9.710597167 6.089194995 Normal 

## 0.627067 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier

ARDomtarIn dustries PB1 8/17/2009 10:00:00 AM 4.455361958 2.794691979 Normal 10:04 - 10:49 calibration 10:04 - 10:49 calibration 

## 0.627265 no WABoeingR enton BOIL04 09/19/09 13:00 44.35697452 27.84955414 normal 

## 0.627851 no ARDomtarIn dustries PB1 8/12/2009 4:00:00 PM 15.68553653 9.852898467 Normal 

## 0.628152 no TXDibollTem ple-Inland PB-44 0600-0700 4.128405257 2.594892081 

## 0.628546 no ARDomtarIn dustries PB1 8/24/2009 7:00:00 PM 2.278782437 1.432658125 Normal 

## 0.628695 no WABoeingR enton BOIL04 09/19/09 07:00 42.20845011 26.53910828 normal 

## 0.628763 no TXDibollTem ple-Inland PB-44 0900-1000 2.285366354 1.437161549 

## 0.628854 no TXDibollTem ple-Inland PB-44 1300-1400 1.75374177 1.103107386 

## 0.629002 no TXDibollTem ple-Inland PB-44 0100-0200 4.492229773 2.826267083 

## 0.629146 no TXDibollTem ple-Inland PB-44 1500-1600 3.357717462 2.11252624 

## 0.629155 no VAPhilipMorr isPark500 B3 10/17/2009 3:00:00 AM 2.447183127 1.543765531 Normal 

## 0.630834 no ARDomtarIn dustries PB1 8/19/2009 2:00:00 PM 83.81470806 52.87404625 Normal 

## 0.630844 no ARDomtarIn dustries PB1 8/18/2009 9:00:00 AM 4.871830742 3.07468055 Normal 

## 0.631114 no WABoeingR enton BOIL04 09/21/09 00:00 33.52583936 21.16122639 normal 

## 0.631192 no

ARDomtarIn dustries PB1 8/27/2009 10:00:00 PM 1.894298734 1.196103887 Normal 

## 0.631423 no TXDibollTem ple-Inland PB-44 1000-1100 2.991 1.888762404 

## 0.631482 no TXDibollTem ple-Inland PB-44 1700-1800 5.201028057 3.284363143 

## 0.631483 no TXDibollTem ple-Inland PB-44 1500-1600 1.694455485 1.070110655 

## 0.631537 no ARDomtarIn dustries PB1 8/21/2009 9:00:00 AM 28.64425838 18.09307495 Normal 

## 0.631648 no

ARDomtarIn dustries PB1 8/16/2009 12:00:00 PM 7.147924459 4.517303758 Normal 

## 0.631974 no ARDomtarIn dustries PB1 8/16/2009 2:00:00 PM 7.451168813 4.714988361 Normal 

## 0.632785 no WABoeingR enton BOIL04 09/19/09 02:00 41.90137276 26.52215417 normal 

## 0.632966 no ARDomtarIn dustries PB1 8/21/2009 6:00:00 PM 21.72665242 13.75633325 Normal 

## 0.633155 no

ARDomtarIn dustries PB1 8/20/2009 11:00:00 AM 17.18487458 10.88591776 Normal 

## 0.633459 no ARDomtarIn dustries PB1 8/25/2009 3:00:00 PM 2.125382658 1.346707594 Normal 

## 0.633631 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier

ARDomtarIn dustries PB1 9/2/2009 10:00:00 AM 1.586179041 1.006369716 Normal 10:05 - 10:55 calibration 10:05 - 10:55 calibration 

## 0.634462 no ARDomtarIn dustries PB1 8/17/2009 8:00:00 AM 4.090521214 2.597789429 Normal 

## 0.635075 no TXDibollTem ple-Inland PB-44 1800-1900 1.496184654 0.950595329 

## 0.635346 no WABoeingR enton BOIL04 08/22/09 15:00 1.267995822 0.806217744 normal 

## 0.635821 no ARDomtarIn dustries PB1 8/27/2009 2:00:00 AM 1.455772267 0.926588372 Normal 

## 0.636493 no ARDomtarIn dustries PB1 8/25/2009 2:00:00 PM 2.100870377 1.338064574 Normal 

## 0.63691 no ARDomtarIn dustries PB1 8/18/2009 7:00:00 PM 4.541464749 2.893586683 Normal 

## 0.637148 no VAPhilipMorr isPark500 B3 10/16/2009 2:00:00 PM 3.572245573 2.277130848 Normal 

## 0.637451 no ARDomtarIn dustries PB1 8/23/2009 7:00:00 AM 34.05360101 21.72487111 Normal 

## 0.637961 no ARDomtarIn dustries PB1 8/13/2009 2:00:00 PM 6.043615907 3.855852166 Normal 

## 0.638004 no WABoeingR enton BOIL04 08/18/09 02:00 3.598885073 2.296175641 normal 

## 0.638024 no WABoeingR enton BOIL04 08/15/09 06:00 1.206933236 0.770183419 normal 

## 0.638133 no

ARDomtarIn dustries PB1 8/24/2009 10:00:00 AM 3.705157792 2.365925976 Normal 10:10 - 10 :53 calibration 10:10 - 10 :53 calibration 

## 0.638549 no TXDibollTem ple-Inland PB-44 2000-2100 4.13564613 2.643859746 

## 0.639286 no ARDomtarIn dustries PB1 8/21/2009 7:00:00 AM 41.56327441 26.57756812 Normal 

## 0.639448 no ARDomtarIn dustries PB1 8/27/2009 1:00:00 PM 1.629441286 1.044774042 Normal 

## 0.641185 no ARDomtarIn dustries PB1 8/18/2009 5:00:00 AM 5.817565487 3.730939289 Normal 

## 0.641323 no WABoeingR enton BOIL04 08/10/09 18:00 0.898615046 0.576932096 normal 

## 0.642024 no ARDomtarIn dustries PB1 8/16/2009 7:00:00 PM 10.64412883 6.834267849 Normal 

## 0.642069 no ARDomtarIn dustries PB1 8/16/2009 9:00:00 AM 19.9046459 12.78592392 Normal 

## 0.642359 no TXDibollTem ple-Inland PB-44 2100-2200 2.423786848 1.557876749 

## 0.642745 no ARDomtarIn dustries PB1 8/16/2009 7:00:00 AM 11.89339536 7.647678848 Normal 

## 0.643019 no WABoeingR enton BOIL04 09/19/09 15:00 32.48681845 20.89976355 normal 

## 0.643331 no

ARDomtarIn dustries PB1 8/21/2009 10:00:00 AM 26.81548307 17.2597338 Normal 10:10 - 10:59 calibration 10:10 - 10:59 calibration 

## 0.643648 no

ARDomtarIn dustries PB1 8/17/2009 11:00:00 AM 8.251566527 5.315147951 Normal 

## 0.644138 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
ARDomtarIn dustries PB1 8/31/2009 3.859487762 2.487375146 Normal 

## 0.644483 no

ARDomtarIn dustries PB1 8/18/2009 12:00:00 PM 4.153759966 2.678444721 Normal 

## 0.644824 no ARDomtarIn dustries PB1 9/4/2009 6:00:00 PM 4.232490356 2.730409173 Normal 

## 0.645107 no ARDomtarIn dustries PB1 8/16/2009 6:00:00 PM 6.995319778 4.515154368 Normal 

## 0.645454 no TXDibollTem ple-Inland PB-44 0400-0500 2.804756987 1.810648842 

## 0.645564 no
WVDuPont Washington Works P05 9/23/2009 12:00:24 PM 0.362021219 0.233877372 

## 0.646032 no ARDomtarIn dustries PB1 8/19/2009 5:00:00 AM 19.00001592 12.28549576 Normal 

## 0.646604 no ARDomtarIn dustries PB1 8/21/2009 6:00:00 AM 34.03249844 22.01626702 Normal 

## 0.646919 no

ARDomtarIn dustries PB1 8/31/2009 12:00:00 PM 4.258780476 2.755290781 Normal 

## 0.646967 no

ARDomtarIn dustries PB1 8/21/2009 11:00:00 AM 23.55859753 15.24253084 Normal 

## 0.647005 no TXDibollTem ple-Inland PB-44 0900-1000 3.432652217 2.221428547 

## 0.647146 no TXDibollTem ple-Inland PB-44 0300-0400 2.612369005 1.690586734 

## 0.647147 no

ARDomtarIn dustries PB1 8/15/2009 11:00:00 AM 13.09739412 8.478793695 Normal 

## 0.647365 no ARDomtarIn dustries PB1 8/24/2009 9:00:00 PM 2.096330483 1.357474783 Normal 

## 0.647548 no ARDomtarIn dustries PB1 8/18/2009 3:00:00 AM 3.969357237 2.572314686 Normal 

## 0.648043 no ARDomtarIn dustries PB1 8/19/2009 9:00:00 AM 18.62592772 12.07254993 Normal 

## 0.648158 no WABoeingR enton BOIL04 09/19/09 09:00 35.45517192 22.99929103 normal 

## 0.648686 no

ARDomtarIn dustries PB1 8/14/2009 12:00:00 PM 4.735608524 3.072196823 Normal 

## 0.648744 no ARDomtarIn dustries PB1 8/21/2009 8:00:00 PM 24.47616491 15.89533325 Normal 

## 0.649421 no VAPhilipMorr isPark500 B3 11/2/2009 7:00:00 PM 0.383876037 0.249500173 Normal 

## 0.64995 no

VAPhilipMorr isPark500 B3 11/2/2009 11:00:00 PM 0.383876037 0.249500173 Normal 

## 0.64995 no VAPhilipMorr isPark500 B3 11/2/2009 7:00:00 AM 0.42405482 0.275614367 Normal 

## 0.64995 no VAPhilipMorr isPark500 B3 10/31/2009 4:00:00 AM 0.912817904 0.59328586 Normal 

## 0.64995 no VAPhilipMorr isPark500 B3 10/18/2009 9:00:00 AM 1.741274907 1.131741364 Normal 

## 0.64995 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier

VAPhilipMorr isPark500 B3 10/18/2009 10:00:00 AM 2.15927923 1.40342321 Normal 

## 0.64995 no VAPhilipMorr isPark500 B3 11/2/2009 4:00:00 PM 0.381169634 0.247741146 Normal 

## 0.64995 no VAPhilipMorr isPark500 B3 11/2/2009 5:00:00 PM 0.381169634 0.247741146 Normal 

## 0.64995 no VAPhilipMorr isPark500 B3 11/2/2009 6:00:00 PM 0.381169634 0.247741146 Normal 

## 0.64995 no VAPhilipMorr isPark500 B3 11/2/2009 8:00:00 PM 0.381169634 0.247741146 Normal 

## 0.64995 no VAPhilipMorr isPark500 B3 11/2/2009 3:00:00 PM 0.39800664 0.258684356 Normal 

## 0.64995 no

VAPhilipMorr isPark500 B3 10/31/2009 10:00:00 PM 0.429124821 0.278909613 Normal 

## 0.64995 no

VAPhilipMorr isPark500 B3 10/31/2009 11:00:00 PM 0.429124821 0.278909613 Normal 

## 0.64995 no VAPhilipMorr isPark500 B3 11/1/2009 4:00:00 AM 0.879274865 0.571484566 Normal 

## 0.64995 no VAPhilipMorr isPark500 B3 10/31/2009 3:00:00 AM 0.890178571 0.578571429 Normal 

## 0.64995 no VAPhilipMorr isPark500 B3 10/18/2009 2.142238117 1.392347342 Normal 

## 0.64995 no VAPhilipMorr isPark500 B3 11/2/2009 5:00:00 AM 0.427421404 0.277802477 Normal 

## 0.64995 no VAPhilipMorr isPark500 B3 10/31/2009 2:00:00 PM 0.436076462 0.283427831 Normal 

## 0.64995 no ARDomtarIn dustries PB1 8/21/2009 7:00:00 PM 20.70720274 13.47516895 Normal 

## 0.650748 no ARDomtarIn dustries PB1 9/1/2009 2:00:00 AM 4.019120242 2.615521399 Normal 

## 0.65077 no ARDomtarIn dustries PB1 8/21/2009 1:00:00 AM 26.90278254 17.51121476 Normal 

## 0.650907 no TXDibollTem ple-Inland PB-44 1600-1700 2.529206797 1.646961191 

## 0.651177 no TXDibollTem ple-Inland PB-44 2000-2100 2.691517458 1.752800374 

## 0.651231 no WABoeingR enton BOIL04 08/26/09 23:00 5.352277385 3.489382776 normal 

## 0.651944 no TXDibollTem ple-Inland PB-44 0700-0800 5.316326236 3.467809848 

## 0.652294 no TXDibollTem ple-Inland PB-44 1200-1300 1.749247061 1.141245381 

## 0.652421 no TXDibollTem ple-Inland PB-44 1100-1200 1.857228188 1.21169454 

## 0.652421 no ARDomtarIn dustries PB1 8/20/2009 7:00:00 AM 20.22492596 13.19593607 Normal 

## 0.652459 no ARDomtarIn dustries PB1 8/16/2009 4:00:00 AM 6.267489234 4.091944779 Normal 

## 0.652884 no ARDomtarIn dustries PB1 8/14/2009 7:00:00 AM 10.55228299 6.889424732 Normal 

## 0.652885 no ARDomtarIn dustries PB1 8/21/2009 1:00:00 PM 26.50258309 17.32088494 Normal 

## 0.653555 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 0600-0700 4.077816971 2.665168501 

## 0.653577 no TXDibollTem ple-Inland PB-44 1400-1500 2.351947317 1.537921317 

## 0.653893 no TXDibollTem ple-Inland PB-44 1500-1600 1.508801364 0.987260757 

## 0.654334 no ARDomtarIn dustries PB1 8/30/2009 2:00:00 AM 5.295391242 3.465130566 Normal 

## 0.654367 no WABoeingR enton BOIL04 10/05/09 17:00 0.802928414 0.525437607 normal 

## 0.654402 no TXDibollTem ple-Inland PB-44 0400-0500 3.325123912 2.176721155 

## 0.654629 no TXDibollTem ple-Inland PB-44 0200-0300 9.111305819 5.98194682 

## 0.656541 no TXDibollTem ple-Inland PB-44 0100-0200 2.817213336 1.850299483 

## 0.656784 no TXDibollTem ple-Inland PB-44 2200-2300 4.621189254 3.036484097 

## 0.657078 no ARDomtarIn dustries PB1 8/12/2009 6:00:00 PM 20.75440891 13.63752607 Normal 

## 0.657091 no TXDibollTem ple-Inland PB-44 0600-0700 2.372358365 1.559678943 

## 0.657438 no ARDomtarIn dustries PB1 8/16/2009 5:00:00 PM 7.318239416 4.813104644 Normal 

## 0.657686 no TXDibollTem ple-Inland PB-44 0500-0600 3.117262271 2.053072532 

## 0.658614 no ARDomtarIn dustries PB1 8/18/2009 8:00:00 AM 5.622467941 3.70605324 Normal 

## 0.659151 no TXDibollTem ple-Inland PB-44 1500-1600 3.019763009 1.993090301 

## 0.660015 no TXDibollTem ple-Inland PB-44 1900-2000 4.607156924 3.041411461 

## 0.660149 no ARDomtarIn dustries PB1 8/19/2009 6:00:00 AM 14.7090741 9.712520032 Normal 

## 0.660308 no ARDomtarIn dustries PB1 8/15/2009 2:00:00 PM 9.459916437 6.251238551 Normal 

## 0.660813 no ARDomtarIn dustries PB1 8/14/2009 9:00:00 AM 7.125117609 4.711521779 Normal 

## 0.661255 no ARDomtarIn dustries PB1 8/20/2009 1:00:00 PM 17.83371984 11.80395076 Normal 

## 0.661889 no WABoeingR enton BOIL04 09/19/09 12:00 33.20850587 21.99188901 normal 

## 0.662237 no TXDibollTem ple-Inland PB-44 0400-0500 2.609852583 1.728429965 

## 0.662271 no ARDomtarIn dustries PB1 8/21/2009 5:00:00 PM 24.17801844 16.01333094 Normal 

## 0.662309 no ARDomtarIn dustries PB1 8/16/2009 1:00:00 AM 5.602809013 3.712772975 Normal 

## 0.662663 no ARDomtarIn dustries PB1 8/14/2009 6:00:00 AM 10.71216355 7.098638261 Normal 

## 0.662671 no

ARDomtarIn dustries PB1 8/17/2009 12:00:00 PM 6.222265307 4.125662638 Normal 

## 0.663048 no ARDomtarIn dustries PB1 8/17/2009 1:00:00 AM 24.73079799 16.40634177 Normal 

## 0.663397 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/18/09 14:00 0.760797493 0.505229786 normal 

## 0.664079 no TXDibollTem ple-Inland PB-44 1900-2000 2.420506565 1.607462547 

## 0.664102 no

ARDomtarIn dustries PB1 8/20/2009 12:00:00 PM 21.07730478 14.00463251 Normal 

## 0.664441 no

ARDomtarIn dustries PB1 8/29/2009 11:00:00 AM 4.684854776 3.114805951 Normal 

## 0.664867 no TXDibollTem ple-Inland PB-44 1500-1600 2.17649341 1.447409775 

## 0.665019 no ARDomtarIn dustries PB1 8/26/2009 2:00:00 AM 1.955790763 1.301693164 Normal 

## 0.665558 no

ARDomtarIn dustries PB1 8/20/2009 11:00:00 PM 19.71486265 13.13385204 Normal 

## 0.66619 no ARDomtarIn dustries PB1 8/30/2009 7:00:00 AM 5.679011327 3.78617591 Normal 

## 0.666696 no ARDomtarIn dustries PB1 8/16/2009 8:00:00 PM 21.80153646 14.5359468 Normal 

## 0.66674 no TXDibollTem ple-Inland PB-44 2200-2300 3.065748461 2.044194916 

## 0.666785 no

ARDomtarIn dustries PB1 8/16/2009 11:00:00 PM 17.45848875 11.64540015 Normal 

## 0.667034 no ARDomtarIn dustries PB1 8/18/2009 7:00:00 AM 5.886989516 3.930001877 Normal 

## 0.667574 no ARDomtarIn dustries PB1 8/25/2009 9:00:00 PM 1.802075667 1.203204549 Normal 

## 0.667677 no ARDomtarIn dustries PB1 8/20/2009 3:00:00 AM 21.47224877 14.33732534 Normal 

## 0.667714 no TXDibollTem ple-Inland PB-44 1600-1700 1.356922279 0.906428275 

## 0.668003 no ARDomtarIn dustries PB1 8/14/2009 5:00:00 AM 10.2478211 6.852049799 Normal 

## 0.668635 no WABoeingR enton BOIL04 09/21/09 01:00 23.90201573 15.99041559 normal 

## 0.668999 no ARDomtarIn dustries PB1 8/31/2009 2:00:00 PM 3.853231831 2.579037324 Normal 

## 0.669318 no ARDomtarIn dustries PB1 8/19/2009 8:00:00 AM 26.41498204 17.68246415 Normal 

## 0.66941 no TXDibollTem ple-Inland PB-44 1500-1600 2.1142459 1.415554223 

## 0.669531 no ARDomtarIn dustries PB1 8/16/2009 8:00:00 AM 15.1331822 10.13483556 Normal 

## 0.669709 no TXDibollTem ple-Inland PB-44 1500-1600 2.406573379 1.612934161 

## 0.67022 no ARDomtarIn dustries PB1 8/30/2009 2:00:00 PM 3.631827951 2.434425905 Normal 

## 0.670303 no ARDomtarIn dustries PB1 8/16/2009 3:00:00 AM 5.799617746 3.888521644 Normal 

## 0.670479 no TXDibollTem ple-Inland PB-44 2300-2400 2.83791971 1.903947406 

## 0.670895 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 2300-2400 2.256915534 1.514469829 

## 0.671035 no ARDomtarIn dustries PB1 8/16/2009 9:00:00 PM 23.96051272 16.08087804 Normal 

## 0.671141 no ARDomtarIn dustries PB1 8/16/2009 6.444844377 4.328446718 Normal 

## 0.671614 no ARDomtarIn dustries PB1 8/20/2009 6:00:00 AM 15.26474484 10.2528237 Normal 

## 0.671667 no TXDibollTem ple-Inland PB-44 0200-0300 2.815172911 1.89114065 

## 0.671767 no ARDomtarIn dustries PB1 8/18/2009 6:00:00 AM 5.984977065 4.021454039 Normal 

## 0.671925 no ARDomtarIn dustries PB1 8/17/2009 3:00:00 AM 38.75912017 26.07027764 Normal 

## 0.672623 no

ARDomtarIn dustries PB1 8/19/2009 12:00:00 PM 15.23146472 10.24802876 Normal 

## 0.67282 no TXDibollTem ple-Inland PB-44 1700-1800 2.946105445 1.982461473 

## 0.672909 no ARDomtarIn dustries PB1 8/30/2009 1:00:00 AM 7.18000727 4.831553745 Normal 

## 0.672918 no TXDibollTem ple-Inland PB-44 1600-1700 3.068885257 2.066678936 

## 0.67343 no ARDomtarIn dustries PB1 8/13/2009 1:00:00 PM 30.67791195 20.66118418 Normal 

## 0.673487 no ARDomtarIn dustries PB1 8/21/2009 4:00:00 PM 22.98357842 15.49081843 Normal 

## 0.673995 no TXDibollTem ple-Inland PB-44 0700-0800 2.565701733 1.730676397 

## 0.674543 no ARDomtarIn dustries PB1 8/21/2009 2:00:00 PM 25.4062541 17.13920164 Normal 

## 0.674606 no TXDibollTem ple-Inland PB-44 0900-1000 2.200675715 1.48469535 

## 0.674654 no VAPhilipMorr isPark500 B3 10/18/2009 7:00:00 AM 1.856606368 1.253112608 Normal 

## 0.674948 no VAPhilipMorr isPark500 B3 10/18/2009 8:00:00 AM 1.871375332 1.263080889 Normal 

## 0.674948 no WABoeingR enton BOIL04 08/19/09 16:00 0.85844965 0.579408807 normal 

## 0.674948 no

ARDomtarIn dustries PB1 8/16/2009 10:00:00 PM 16.98785957 11.46744373 Normal 

## 0.675038 no ARDomtarIn dustries PB1 8/29/2009 5:00:00 AM 1.883935393 1.271911183 Normal 

## 0.675135 no ARDomtarIn dustries PB1 8/17/2009 2:00:00 AM 34.75675473 23.49500343 Normal 

## 0.675984 no TXDibollTem ple-Inland PB-44 0600-0700 2.865551733 1.938544312 

## 0.676499 no TXDibollTem ple-Inland PB-44 2200-2300 2.722599371 1.841838089 

## 0.6765 no ARDomtarIn dustries PB1 8/21/2009 23.34091635 15.79041852 Normal 

## 0.676512 no ARDomtarIn dustries PB1 8/30/2009 6:00:00 AM 7.370894027 4.986553999 Normal 

## 0.67652 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
ARDomtarIn dustries PB1 8/17/2009 4:00:00 AM 35.44852727 23.9841852 Normal 

## 0.676592 no
WVDuPont Washington Works P05 9/22/2009 2:00:04 PM 0.601919297 0.407253757 

## 0.676592 no

ARDomtarIn dustries PB1 8/19/2009 11:00:00 PM 5.132415387 3.47342315 Normal 

## 0.676762 no TXDibollTem ple-Inland PB-44 2302-2402 2.223822182 1.50604936 

## 0.677235 no ARDomtarIn dustries PB1 8/17/2009 33.26325197 22.55390125 Normal 

## 0.678043 no ARDomtarIn dustries PB1 8/14/2009 4:00:00 AM 15.78341905 10.7042016 Normal 

## 0.678193 no TXDibollTem ple-Inland PB-44 2002-2102 2.009069713 1.363214294 

## 0.67853 no TXDibollTem ple-Inland PB-44 1800-1900 4.728202967 3.210196867 

## 0.678947 no ARDomtarIn dustries PB1 8/13/2009 8:00:00 AM 100.2106003 68.03941017 Normal 

## 0.678964 no TXDibollTem ple-Inland PB-44 1802-1902 1.625760759 1.103883583 

## 0.678995 no ARDomtarIn dustries PB1 8/19/2009 1:00:00 PM 9.335755938 6.340297415 Normal 

## 0.679141 no TXDibollTem ple-Inland PB-44 0300-0400 7.45247617 5.06542268 

## 0.679697 no TXDibollTem ple-Inland PB-44 0700-0800 3.115701346 2.118432636 

## 0.679922 no TXDibollTem ple-Inland PB-44 1200-1300 2.844514196 1.934050992 

## 0.679923 no WABoeingR enton BOIL04 09/19/09 11:00 30.33966995 20.63668052 normal 

## 0.680188 no ARDomtarIn dustries PB1 8/18/2009 3:00:00 PM 4.028771294 2.741801776 Normal 

## 0.680555 no ARDomtarIn dustries PB1 8/20/2009 2:00:00 AM 22.17129065 15.09763821 Normal 

## 0.680954 no ARDomtarIn dustries PB1 8/21/2009 3:00:00 AM 25.21215418 17.18895244 Normal 

## 0.681772 no ARDomtarIn dustries PB1 8/18/2009 4:00:00 AM 4.01073458 2.734913762 Normal 

## 0.681898 no ARDomtarIn dustries PB1 8/20/2009 4:00:00 AM 20.54295799 14.00844039 Normal 

## 0.68191 no VAPhilipMorr isPark500 B3 10/1/2009 1:00:00 PM 2.618644086 1.787086696 Normal 

## 0.682447 no ARDomtarIn dustries PB1 8/18/2009 1:00:00 PM 3.52966303 2.409223082 Normal 

## 0.682565 no TXDibollTem ple-Inland PB-44 1400-1500 2.885913144 1.969900436 

## 0.682592 no ARDomtarIn dustries PB1 8/19/2009 3:00:00 PM 97.61423277 66.67146171 Normal 

## 0.68301 no

ARDomtarIn dustries PB1 8/21/2009 11:00:00 PM 22.5393482 15.39856308 Normal 

## 0.683186 no TXDibollTem ple-Inland PB-44 1600-1700 1.976858937 1.351778494 

## 0.683801 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/16/09 08:00 1.883140648 1.288365243 normal 

## 0.684158 no TXDibollTem ple-Inland PB-44 1315-1415 1.299130157 0.889111305 

## 0.68439 no TXDibollTem ple-Inland PB-44 0400-0500 3.228746154 2.211717828 

## 0.685008 no ARDomtarIn dustries PB1 8/22/2009 2:00:00 AM 17.38769304 11.91097919 Normal 

## 0.685024 no TXDibollTem ple-Inland PB-44 0500-0600 3.215325 2.202594658 

## 0.68503 no ARDomtarIn dustries PB1 8/24/2009 2:00:00 PM 4.418048835 3.02685571 Normal 

## 0.685111 no WABoeingR enton BOIL04 09/19/09 14:00 28.89267717 19.81207395 normal 

## 0.685713 no TXDibollTem ple-Inland PB-44 1800-1900 2.456266144 1.685077658 

## 0.686032 no ARDomtarIn dustries PB1 8/12/2009 2:00:00 PM 13.91813426 9.549997928 Normal 

## 0.686155 no ARDomtarIn dustries PB1 8/20/2009 5:00:00 AM 13.44754783 9.228532585 Normal 

## 0.686261 no

ARDomtarIn dustries PB1 8/12/2009 11:00:00 AM 27.06652504 18.57887953 Normal 

## 0.686415 no ARDomtarIn dustries PB1 8/15/2009 5:00:00 AM 7.706453379 5.290862519 Normal 

## 0.68655 no ARDomtarIn dustries PB1 8/19/2009 7:00:00 AM 14.57352425 10.00690116 Normal 

## 0.686649 no ARDomtarIn dustries PB1 8/22/2009 30.51475827 20.96418125 Normal 

## 0.687018 no ARDomtarIn dustries PB1 8/29/2009 6:00:00 AM 2.66702318 1.83234877 Normal 

## 0.687039 no WABoeingR enton BOIL04 08/12/09 04:00 1.526057751 1.048946531 normal 

## 0.687357 no

ARDomtarIn dustries PB1 8/13/2009 12:00:00 PM 11.50091641 7.911006955 Normal 

## 0.687859 no ARDomtarIn dustries PB1 8/25/2009 1:00:00 PM 2.50961922 1.72755534 Normal 

## 0.688373 no ARDomtarIn dustries PB1 8/23/2009 8:00:00 AM 21.79289062 15.00358079 Normal 

## 0.688462 no ARDomtarIn dustries PB1 8/15/2009 4:00:00 AM 5.818229231 4.007344375 Normal 

## 0.688757 no ARDomtarIn dustries PB1 8/21/2009 2:00:00 AM 26.98156156 18.5867674 Normal 

## 0.688869 no

ARDomtarIn dustries PB1 8/21/2009 12:00:00 PM 23.83679135 16.42257516 Normal 

## 0.688959 no TXDibollTem ple-Inland PB-44 2300-2400 2.961636989 2.041636666 

## 0.689361 no TXDibollTem ple-Inland PB-44 1500-1600 2.68649432 1.852141701 

## 0.689427 no ARDomtarIn dustries PB1 8/29/2009 8:00:00 PM 4.815966911 3.322041699 Normal 

## 0.689797 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier

ARDomtarIn dustries PB1 8/15/2009 11:00:00 PM 6.220805387 4.291207343 Normal 

## 0.689815 no TXDibollTem ple-Inland PB-44 2000-2100 4.657692134 3.213259222 

## 0.689882 no TXDibollTem ple-Inland PB-44 0900-1000 2.443157967 1.687059296 

## 0.690524 no WABoeingR enton BOIL04 08/11/09 20:00 1.051395093 0.726063713 normal 

## 0.690572 no WABoeingR enton BOIL04 08/19/09 08:00 0.340552155 0.235621939 normal 

## 0.691882 no ARDomtarIn dustries PB1 8/15/2009 1:00:00 PM 7.413425858 5.129229795 Normal 

## 0.691884 no ARDomtarIn dustries PB1 8/22/2009 1:00:00 AM 23.14871752 16.01870462 Normal 

## 0.691991 no

ARDomtarIn dustries PB1 8/30/2009 10:00:00 PM 3.626338714 2.510655321 Normal 

## 0.692339 no TXDibollTem ple-Inland PB-44 2000-2100 1.803340869 1.248883146 

## 0.692539 no ARDomtarIn dustries PB1 8/14/2009 3:00:00 AM 20.19476243 13.98772377 Normal 

## 0.692641 no TXDibollTem ple-Inland PB-44 1800-1900 3.056790627 2.117731141 

## 0.692796 no TXDibollTem ple-Inland PB-44 0100-0200 2.383021731 1.651342583 

## 0.692962 no ARDomtarIn dustries PB1 8/21/2009 3:00:00 PM 22.75756875 15.77056005 Normal 

## 0.692981 no TXDibollTem ple-Inland PB-44 1600-1700 2.856216156 1.979493106 

## 0.693047 no ARDomtarIn dustries PB1 8/19/2009 1:00:00 AM 4.114714469 2.851726114 Normal 

## 0.693056 no ARDomtarIn dustries PB1 8/13/2009 9:00:00 AM 25.60146934 17.75326465 Normal 

## 0.693447 no ARDomtarIn dustries PB1 8/30/2009 5:00:00 AM 9.263683457 6.424822594 Normal 

## 0.693549 no ARDomtarIn dustries PB1 8/21/2009 5:00:00 AM 25.40079076 17.61756702 Normal 

## 0.693583 no

ARDomtarIn dustries PB1 8/24/2009 11:00:00 PM 2.326088386 1.613450723 Normal 

## 0.693633 no TXDibollTem ple-Inland PB-44 1500-1600 2.151964651 1.492809926 

## 0.693696 no WABoeingR enton BOIL04 08/10/09 20:00 0.646564485 0.448724963 normal 

## 0.694014 no WABoeingR enton BOIL04 08/26/09 21:00 4.025434597 2.794070462 normal 

## 0.694104 no ARDomtarIn dustries PB1 8/20/2009 6:00:00 PM 23.24093204 16.13304928 Normal 

## 0.694165 no ARDomtarIn dustries PB1 8/17/2009 5:00:00 AM 8.990883118 6.249061019 Normal 

## 0.695044 no ARDomtarIn dustries PB1 8/30/2009 6.22823849 4.329440955 Normal 

## 0.695131 no ARDomtarIn dustries PB1 8/15/2009 3:00:00 AM 5.903452913 4.103887399 Normal 

## 0.695167 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 09/20/09 09:00 25.26605105 17.57249202 normal 

## 0.695498 no ARDomtarIn dustries PB1 8/23/2009 6:00:00 AM 18.88875617 13.13879815 Normal 

## 0.695588 no TXDibollTem ple-Inland PB-44 1600-1700 2.270809289 1.579948168 

## 0.695764 no TXDibollTem ple-Inland PB-44 1600-1700 2.1142459 1.471216684 

## 0.695859 no TXDibollTem ple-Inland PB-44 2102-2202 2.09483038 1.457784326 

## 0.695896 no VAPhilipMorr isPark500 B3 10/18/2009 2:00:00 AM 2.015327281 1.40342321 Normal 

## 0.696375 no VAPhilipMorr isPark500 B3 10/18/2009 4:00:00 AM 2.015327281 1.40342321 Normal 

## 0.696375 no VAPhilipMorr isPark500 B3 10/18/2009 6:00:00 AM 2.015327281 1.40342321 Normal 

## 0.696375 no VAPhilipMorr isPark500 B3 10/18/2009 5:00:00 AM 2.031487392 1.414676705 Normal 

## 0.696375 no WABoeingR enton BOIL04 09/26/09 19:00 0.683305935 0.47583706 normal 

## 0.696375 no

VAPhilipMorr isPark500 B3 10/30/2009 11:00:00 PM 1.038541667 0.723214286 Normal 

## 0.696375 no VAPhilipMorr isPark500 B3 10/31/2009 1.038541667 0.723214286 Normal 

## 0.696375 no VAPhilipMorr isPark500 B3 11/1/2009 2:00:00 PM 1.047199066 0.729243081 Normal 

## 0.696375 no VAPhilipMorr isPark500 B3 10/18/2009 3:00:00 AM 1.999422243 1.392347342 Normal 

## 0.696375 no VAPhilipMorr isPark500 B3 10/31/2009 1:00:00 AM 1.030026238 0.717284356 Normal 

## 0.696375 no VAPhilipMorr isPark500 B3 10/31/2009 2:00:00 AM 1.030026238 0.717284356 Normal 

## 0.696375 no ARDomtarIn dustries PB1 9/2/2009 7:00:00 AM 2.540016035 1.769070257 Normal 

## 0.69648 no TXDibollTem ple-Inland PB-44 1902-2002 1.919817883 1.337491383 

## 0.696676 no ARDomtarIn dustries PB1 9/1/2009 3:00:00 AM 3.735539085 2.602508002 Normal 

## 0.696689 no ARDomtarIn dustries PB1 8/30/2009 3:00:00 PM 4.048518981 2.82222347 Normal 

## 0.6971 no ARDomtarIn dustries PB1 8/14/2009 8:00:00 AM 5.082452662 3.544597836 Normal 

## 0.697419 no ARDomtarIn dustries PB1 9/2/2009 5:00:00 AM 2.245902886 1.566533026 Normal 

## 0.697507 no ARDomtarIn dustries PB1 8/22/2009 4:00:00 AM 19.5867508 13.66267718 Normal 

## 0.697547 no TXDibollTem ple-Inland PB-44 2000-2100 2.584126708 1.802585976 

## 0.697561 no ARDomtarIn dustries PB1 8/19/2009 4:00:00 PM 39.69383738 27.69106675 Normal 

## 0.697616 no ARDomtarIn dustries PB1 8/12/2009 9:00:00 PM 26.95565353 18.81945535 Normal 

## 0.698164 no TXDibollTem ple-Inland PB-44 10/15/2009 0000-0100 3.294760287 2.300600917 

## 0.69826 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 09/19/09 03:00 29.80774962 20.82071437 normal 

## 0.6985 no TXDibollTem ple-Inland PB-44 0200-0300 2.546752188 1.778910247 

## 0.698502 no TXDibollTem ple-Inland PB-44 1900-2000 2.280703673 1.59422623 

## 0.699006 no TXDibollTem ple-Inland PB-44 1400-1500 2.629462521 1.838704215 

## 0.69927 no WABoeingR enton BOIL04 08/25/09 16:00 2.611569446 1.826304802 normal 

## 0.699313 no ARDomtarIn dustries PB1 8/13/2009 4:00:00 AM 7.285526711 5.096947471 Normal 

## 0.699599 no TXDibollTem ple-Inland PB-44 1900-2000 4.337752793 3.035390943 

## 0.699761 no ARDomtarIn dustries PB1 8/18/2009 2:00:00 PM 3.883485446 2.717667404 Normal 

## 0.699801 no ARDomtarIn dustries PB1 8/17/2009 1:00:00 PM 6.002837648 4.202602004 Normal 

## 0.700103 no

ARDomtarIn dustries PB1 8/13/2009 11:00:00 AM 13.04653938 9.13447984 Normal 

## 0.700146 no VAPhilipMorr isPark500 B3 10/16/2009 1:00:00 PM 4.396609936 3.080824089 Normal 

## 0.700727 no ARDomtarIn dustries PB1 8/19/2009 4:00:00 AM 14.92565437 10.46149573 Normal 

## 0.700907 no TXDibollTem ple-Inland PB-44 0402-0502 2.17386832 1.523812339 

## 0.700968 no TXDibollTem ple-Inland PB-44 2300-2400 2.142934714 1.502594105 

## 0.701185 no WABoeingR enton BOIL04 08/10/09 21:00 0.624647044 0.438041036 normal 

## 0.701262 no WABoeingR enton BOIL04 10/06/09 20:00 1.797230093 1.260703468 normal 

## 0.70147 no ARDomtarIn dustries PB1 8/20/2009 1:00:00 AM 8.039952504 5.640518292 Normal 

## 0.701561 no TXDibollTem ple-Inland PB-44 1100-1200 2.322352713 1.632773829 

## 0.703069 no TXDibollTem ple-Inland PB-44 2100-2200 2.268979715 1.596547162 

## 0.703641 no ARDomtarIn dustries PB1 8/20/2009 2:00:00 PM 17.03257536 11.98794919 Normal 

## 0.703825 no WABoeingR enton BOIL04 09/20/09 08:00 24.02195442 16.91128484 normal 

## 0.703993 no ARDomtarIn dustries PB1 8/16/2009 2:00:00 AM 6.159029701 4.33731799 Normal 

## 0.704221 no ARDomtarIn dustries PB1 8/30/2009 8:00:00 AM 6.593973141 4.645130645 Normal 

## 0.704451 no ARDomtarIn dustries PB1 8/13/2009 7:00:00 PM 21.83136671 15.38124931 Normal 

## 0.704548 no TXDibollTem ple-Inland PB-44 1300-1400 2.125609386 1.498130933 

## 0.704801 no

ARDomtarIn dustries PB1 8/18/2009 11:00:00 PM 3.873528896 2.733188816 Normal 

## 0.705607 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 10/01/09 0002-0102 2.266261506 1.599663879 

## 0.70586 no TXDibollTem ple-Inland PB-44 1700-1800 3.965094684 2.799746979 

## 0.706098 no ARDomtarIn dustries PB1 8/21/2009 9:00:00 PM 23.97387195 16.93941138 Normal 

## 0.706578 no TXDibollTem ple-Inland PB-44 1900-2000 2.556726511 1.806606129 

## 0.706609 no TXDibollTem ple-Inland PB-44 2202-2302 2.094503921 1.480379446 

## 0.706792 no ARDomtarIn dustries PB1 8/20/2009 5.299593359 3.745892463 Normal 

## 0.706826 no TXDibollTem ple-Inland PB-44 1600-1700 2.558504137 1.81012824 

## 0.707495 no WABoeingR enton BOIL04 09/26/09 14:00 0.671647954 0.475262586 normal 

## 0.707607 no TXDibollTem ple-Inland PB-44 0500-0600 2.641329998 1.869160897 

## 0.707659 no ARDomtarIn dustries PB1 8/14/2009 1:00:00 PM 5.559323533 3.941695075 Normal 

## 0.709024 no TXDibollTem ple-Inland PB-44 0400-0500 2.429034761 1.72231173 

## 0.709052 no TXDibollTem ple-Inland PB-44 1000-1100 3.491370801 2.476064348 

## 0.709195 no ARDomtarIn dustries PB1 9/2/2009 6:00:00 AM 2.417865072 1.715731946 Normal 

## 0.709606 no TXDibollTem ple-Inland PB-44 1900-2000 3.482918074 2.472098961 

## 0.709778 no ARDomtarIn dustries PB1 8/19/2009 5:00:00 PM 24.63395296 17.48566954 Normal 

## 0.70982 no TXDibollTem ple-Inland PB-44 2000-2100 2.382110413 1.691608032 

## 0.71013 no ARDomtarIn dustries PB1 8/29/2009 3:00:00 PM 4.37361392 3.108369386 Normal 

## 0.71071 no TXDibollTem ple-Inland PB-44 0200-0300 2.61683635 1.860532676 

## 0.710985 no
WVDuPont Washington Works P05 10/5/2009 4:00:48 PM 0.807699643 0.574292575 

## 0.711022 no TXDibollTem ple-Inland PB-44 1800-1900 4.300611362 3.058582234 

## 0.711197 no

ARDomtarIn dustries PB1 8/12/2009 11:00:00 PM 17.16181247 12.20543403 Normal 

## 0.711197 no

ARDomtarIn dustries PB1 8/13/2009 10:00:00 AM 12.0619829 8.582265461 Normal 10:11 - 10:57 calibration 10:11 - 10:57 calibration 

## 0.711514 no TXDibollTem ple-Inland PB-44 0302-0402 2.293415867 1.631956279 

## 0.711583 no

ARDomtarIn dustries PB1 8/23/2009 10:00:00 AM 28.08370901 19.9916362 Normal 10:11 - 10:59 calibration 10:11 - 10:59 calibration 

## 0.711859 no ARDomtarIn dustries PB1 8/27/2009 1:00:00 AM 1.699120282 1.20995179 Normal 

## 0.712105 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
ARDomtarIn dustries PB1 8/20/2009 9:00:00 PM 22.87376431 16.29346389 Normal 

## 0.712321 no VAPhilipMorr isPark500 B3 10/2/2009 9:00:00 AM 3.26259652 2.324420667 Normal 

## 0.712445 no TXDibollTem ple-Inland PB-44 1700-1800 2.457255421 1.750914858 

## 0.712549 no ARDomtarIn dustries PB1 8/14/2009 2:00:00 AM 14.62848969 10.42628114 Normal 

## 0.712738 no TXDibollTem ple-Inland PB-44 2200-2300 3.39675248 2.421307203 

## 0.71283 no TXDibollTem ple-Inland PB-44 2000-2100 5.355215584 3.817704271 

## 0.712895 no

ARDomtarIn dustries PB1 9/2/2009 11:00:00 AM 2.031822426 1.449021138 Normal 

## 0.713163 no TXDibollTem ple-Inland PB-44 0300-0400 2.88359214 2.05790232 

## 0.713659 no ARDomtarIn dustries PB1 8/15/2009 2:00:00 AM 7.586747268 5.415915855 Normal 

## 0.713865 no ARDomtarIn dustries PB1 9/2/2009 8:00:00 AM 2.519443088 1.799244322 Normal 

## 0.714144 no

ARDomtarIn dustries PB1 8/13/2009 10:00:00 PM 13.56532166 9.694433827 Normal 

## 0.714648 no ARDomtarIn dustries PB1 8/19/2009 4.186617317 2.992924633 Normal 

## 0.714879 no WABoeingR enton BOIL04 09/19/09 16:00 22.51438008 16.09928647 normal 

## 0.715067 no TXDibollTem ple-Inland PB-44 2300-2400 2.829508799 2.023307374 

## 0.715074 no ARDomtarIn dustries PB1 8/22/2009 6:00:00 AM 14.56900843 10.42095811 Normal 

## 0.715283 no ARDomtarIn dustries PB1 8/12/2009 1:00:00 PM 12.74750313 9.119815392 Normal 

## 0.71542 no

ARDomtarIn dustries PB1 8/21/2009 10:00:00 PM 30.8334412 22.06398363 Normal 

## 0.715586 no TXDibollTem ple-Inland PB-44 1700-1800 2.959019138 2.117574429 

## 0.715634 no WABoeingR enton BOIL04 08/18/09 03:00 2.770055127 1.982579934 normal 

## 0.715719 no TXDibollTem ple-Inland PB-44 2000-2100 5.626969918 4.027346701 

## 0.715722 no TXDibollTem ple-Inland PB-44 1200-1300 1.768553826 1.265843835 

## 0.715751 no TXDibollTem ple-Inland PB-44 1900-2000 4.274389738 3.060074467 

## 0.715909 no ARDomtarIn dustries PB1 8/21/2009 4:00:00 AM 20.68380973 14.808636 Normal 

## 0.715953 no ARDomtarIn dustries PB1 8/13/2009 8:00:00 PM 26.33750716 18.85968814 Normal 

## 0.716077 no

ARDomtarIn dustries PB1 8/12/2009 12:00:00 PM 19.31674086 13.84629828 Normal 

## 0.716803 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 0602-0702 2.01038834 1.442061845 

## 0.717305 no TXDibollTem ple-Inland PB-44 1600-1702 1.301910103 0.933870996 

## 0.717308 no

ARDomtarIn dustries PB1 8/26/2009 11:00:00 PM 2.2129258 1.587874398 Normal 

## 0.717545 no TXDibollTem ple-Inland PB-44 0500-0600 2.917298924 2.094457829 

## 0.717944 no ARDomtarIn dustries PB1 8/23/2009 9:00:00 AM 22.53579251 16.18093587 Normal 

## 0.718011 no ARDomtarIn dustries PB1 8/20/2009 3:00:00 PM 15.43721567 11.0850499 Normal 

## 0.718073 no WABoeingR enton BOIL04 09/19/09 06:00 26.7876051 19.23568257 normal 

## 0.718081 no TXDibollTem ple-Inland PB-44 1700-1800 3.525275013 2.531627208 

## 0.718136 no ARDomtarIn dustries PB1 8/18/2009 4:00:00 PM 5.001181525 3.592139621 Normal 

## 0.718258 no TXDibollTem ple-Inland PB-44 0202-0302 2.199610127 1.580313432 

## 0.718452 no ARDomtarIn dustries PB1 8/13/2009 9.908768414 7.120672209 Normal 

## 0.718623 no TXDibollTem ple-Inland PB-44 1400-1500 3.907151351 2.809156516 

## 0.718978 no ARDomtarIn dustries PB1 8/30/2009 4:00:00 PM 4.651748595 3.347788203 Normal 

## 0.719684 no ARDomtarIn dustries PB1 8/27/2009 1.781722344 1.282470498 Normal 

## 0.719793 no ARDomtarIn dustries PB1 8/19/2009 6:00:00 PM 21.66446186 15.59837899 Normal 

## 0.719998 no ARDomtarIn dustries PB1 8/19/2009 3:00:00 AM 6.585979821 4.745431636 Normal 

## 0.720535 no ARDomtarIn dustries PB1 8/20/2009 7:00:00 PM 23.93593274 17.25283539 Normal 

## 0.720792 no ARDomtarIn dustries PB1 8/29/2009 2:00:00 PM 4.568996221 3.293692057 Normal 

## 0.720879 no TXDibollTem ple-Inland PB-44 1700-1800 2.030581478 1.464069609 

## 0.72101 no

ARDomtarIn dustries PB1 8/20/2009 10:00:00 PM 22.05619229 15.90401316 Normal 

## 0.721068 no TXDibollTem ple-Inland PB-44 2100-2200 2.061306611 1.488185756 

## 0.721962 no

ARDomtarIn dustries PB1 8/25/2009 10:00:00 PM 2.105921131 1.520583854 Normal 

## 0.722052 no

VAPhilipMorr isPark500 B3 10/16/2009 12:00:00 PM 3.796107545 2.741421697 Normal 

## 0.722166 no VAPhilipMorr isPark500 B3 10/2/2009 7:00:00 AM 3.435732205 2.4811707 Normal 

## 0.722166 no TXDibollTem ple-Inland PB-44 1400-1500 3.936020288 2.844649799 

## 0.722722 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/10/09 22:00 0.635605765 0.459408891 normal 

## 0.722789 no ARDomtarIn dustries PB1 8/13/2009 6:00:00 AM 22.06025548 15.94804888 Normal 

## 0.722931 no ARDomtarIn dustries PB1 8/22/2009 5:00:00 AM 21.03805918 15.20965223 Normal 

## 0.722959 no TXDibollTem ple-Inland PB-44 1800-1900 2.715688281 1.963364637 

## 0.722971 no TXDibollTem ple-Inland PB-44 1200-1300 4.96818 3.592076209 

## 0.723017 no TXDibollTem ple-Inland PB-44 0102-0202 2.255544685 1.630831382 

## 0.723032 no TXDibollTem ple-Inland PB-44 2000-2100 2.468296575 1.785136164 

## 0.723226 no VAPhilipMorr isPark500 B3 10/2/2009 3:00:00 AM 3.944729569 2.853346305 Normal 

## 0.723331 no VAPhilipMorr isPark500 B3 10/2/2009 4:00:00 AM 3.944729569 2.853346305 Normal 

## 0.723331 no

VAPhilipMorr isPark500 B3 10/1/2009 10:00:00 PM 3.97266466 2.87355263 Normal 

## 0.723331 no ARDomtarIn dustries PB1 9/2/2009 4:00:00 AM 2.616471385 1.892704484 Normal 

## 0.723381 no TXDibollTem ple-Inland PB-44 1100-1200 3.063345869 2.217251441 

## 0.723801 no TXDibollTem ple-Inland PB-44 0900-1000 2.946046467 2.132643495 

## 0.7239 no TXDibollTem ple-Inland PB-44 1100-1200 3.240014858 2.345693237 

## 0.723976 no TXDibollTem ple-Inland PB-44 0802-0902 1.724344168 1.249225561 

## 0.724464 no

ARDomtarIn dustries PB1 8/20/2009 10:00:00 AM 5.690744065 4.124292299 Normal 10:06 - 10:59 calibration 10:06 - 10:59 calibration 

## 0.724737 no ARDomtarIn dustries PB1 8/15/2009 6:00:00 AM 6.037148403 4.376056692 Normal 

## 0.724855 no ARDomtarIn dustries PB1 8/20/2009 8:00:00 PM 20.99846665 15.22588314 Normal 

## 0.725095 no TXDibollTem ple-Inland PB-44 0600-0700 5.222318689 3.790321967 

## 0.725793 no ARDomtarIn dustries PB1 8/12/2009 5:00:00 PM 12.97626059 9.418764211 Normal 

## 0.725846 no TXDibollTem ple-Inland PB-44 1700-1800 2.627159912 1.90724068 

## 0.725971 no TXDibollTem ple-Inland PB-44 1300-1400 2.745697952 1.993862901 

## 0.726177 no ARDomtarIn dustries PB1 8/20/2009 4:00:00 PM 20.48231144 14.87940319 Normal 

## 0.726451 no

ARDomtarIn dustries PB1 8/19/2009 10:00:00 PM 3.593980575 2.610978152 Normal 

## 0.726486 no WABoeingR enton BOIL04 08/27/09 04:00 4.487597212 3.262582539 normal 

## 0.727022 no ARDomtarIn dustries PB1 8/17/2009 2:00:00 PM 5.24286996 3.812719258 Normal 

## 0.72722 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 0700-0800 2.317837542 1.686284624 

## 0.727525 no ARDomtarIn dustries PB1 8/22/2009 7:00:00 AM 13.41906065 9.76578033 Normal 

## 0.727754 no TXDibollTem ple-Inland PB-44 2100-2200 2.692921635 1.959982195 

## 0.727827 no ARDomtarIn dustries PB1 8/22/2009 3:00:00 AM 19.38016238 14.11066352 Normal 

## 0.728098 no TXDibollTem ple-Inland PB-44 1700-1800 2.540082351 1.85036571 

## 0.728467 no ARDomtarIn dustries PB1 8/15/2009 8:00:00 AM 7.915008647 5.767155962 Normal 

## 0.728635 no ARDomtarIn dustries PB1 8/30/2009 5:00:00 PM 2.592972936 1.889345184 Normal 

## 0.728641 no TXDibollTem ple-Inland PB-44 2200-2300 2.228119389 1.623534705 

## 0.728657 no TXDibollTem ple-Inland PB-44 0502-0602 2.18256808 1.590558392 

## 0.728755 no TXDibollTem ple-Inland PB-44 1700-1800 2.782699275 2.02823075 

## 0.728872 no ARDomtarIn dustries PB1 8/14/2009 1:00:00 AM 12.89282728 9.398982746 Normal 

## 0.729009 no TXDibollTem ple-Inland PB-44 1000-1100 2.362397213 1.722685487 

## 0.729211 no TXDibollTem ple-Inland PB-44 0500-0600 2.569483083 1.876016902 

## 0.730115 no WABoeingR enton BOIL04 09/19/09 01:00 25.54088701 18.64967265 normal 

## 0.730189 no TXDibollTem ple-Inland PB-44 1200-1300 2.923347305 2.135078262 

## 0.730354 no ARDomtarIn dustries PB1 8/23/2009 8:00:00 PM 20.02732138 14.63193765 Normal 

## 0.730599 no

ARDomtarIn dustries PB1 8/29/2009 11:00:00 PM 6.778002993 4.95277744 Normal 

## 0.730713 no WABoeingR enton BOIL04 08/23/09 08:00 0.088100147 0.064418262 normal 

## 0.731194 no VAPhilipMorr isPark500 B3 11/1/2009 0.572166428 0.418364419 Normal 

## 0.731194 no

VAPhilipMorr isPark500 B3 10/31/2009 12:00:00 PM 0.576763619 0.421725856 Normal 

## 0.731194 no VAPhilipMorr isPark500 B3 10/2/2009 6:00:00 AM 3.538099731 2.587035811 Normal 

## 0.731194 no

VAPhilipMorr isPark500 B3 11/2/2009 11:00:00 AM 0.572848586 0.418863209 Normal 

## 0.731194 no TXDibollTem ple-Inland PB-44 2200-2300 2.300778074 1.682318361 

## 0.731195 no TXDibollTem ple-Inland PB-44 2000-2100 53.31928174 38.99145677 

## 0.731282 no ARDomtarIn dustries PB1 8/12/2009 8:00:00 PM 44.37787305 32.45396902 Normal 

## 0.73131 no ARDomtarIn dustries PB1 8/15/2009 7.232285807 5.289733752 Normal 

## 0.731406 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier

ARDomtarIn dustries PB1 8/14/2009 10:00:00 AM 9.738092406 7.123063251 Normal 10:05 - 10:52 calibration 10:05 - 10:52 calibration 

## 0.731464 no ARDomtarIn dustries PB1 8/22/2009 1:00:00 PM 100.4400879 73.51851644 Normal 

## 0.731964 no TXDibollTem ple-Inland PB-44 1800-1900 2.550617515 1.86809336 

## 0.732408 no TXDibollTem ple-Inland PB-44 1300-1400 3.223946902 2.362458276 

## 0.732784 no ARDomtarIn dustries PB1 8/13/2009 5:00:00 AM 115.961673 85.01471558 Normal 

## 0.733128 no TXDibollTem ple-Inland PB-44 2000-2100 2.252186851 1.651145842 

## 0.73313 no ARDomtarIn dustries PB1 8/12/2009 3:00:00 PM 10.4143334 7.635761382 Normal 

## 0.733197 no ARDomtarIn dustries PB1 8/23/2009 4:00:00 PM 31.03134006 22.76313521 Normal 

## 0.733553 no WABoeingR enton BOIL04 08/26/09 17:00 4.022982456 2.952236842 normal 

## 0.733843 no ARDomtarIn dustries PB1 8/31/2009 9:00:00 PM 3.732840049 2.740598672 Normal 

## 0.734186 no TXDibollTem ple-Inland PB-44 1900-2000 2.514451786 1.846209723 

## 0.734239 no TXDibollTem ple-Inland PB-44 0900-1000 2.761331625 2.027699612 

## 0.734319 no TXDibollTem ple-Inland PB-44 1400-1500 2.447162638 1.797398266 

## 0.734483 no TXDibollTem ple-Inland PB-44 1100-1200 2.452936843 1.801645246 

## 0.734485 no

ARDomtarIn dustries PB1 8/29/2009 12:00:00 PM 4.954991961 3.639865505 Normal 

## 0.734586 no TXDibollTem ple-Inland PB-44 1300-1400 2.643498396 1.941901285 

## 0.734595 no ARDomtarIn dustries PB1 8/13/2009 9:00:00 PM 15.72872695 11.55501554 Normal 

## 0.734644 no TXDibollTem ple-Inland PB-44 1600-1700 2.117408899 1.555862358 

## 0.734795 no ARDomtarIn dustries PB1 8/13/2009 7:00:00 AM 12.06281477 8.86779692 Normal 

## 0.735135 no
WVDuPont Washington Works P05 9/23/2009 1:00:25 PM 0.308071028 0.226511849 

## 0.735259 no ARDomtarIn dustries PB1 8/20/2009 5:00:00 PM 23.11955508 16.99899474 Normal 

## 0.735265 no TXDibollTem ple-Inland PB-44 0702-0802 2.478437714 1.8235158 

## 0.735752 no TXDibollTem ple-Inland PB-44 2100-2200 2.554638385 1.880795142 

## 0.736228 no TXDibollTem ple-Inland PB-44 1400-1500 3.131114152 2.305282203 

## 0.73625 no ARDomtarIn dustries PB1 8/17/2009 3:00:00 PM 4.120351023 3.034772334 Normal 

## 0.736532 no TXDibollTem ple-Inland PB-44 1800-1900 2.455497962 1.809399973 

## 0.736877 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
ARDomtarIn dustries PB1 8/23/2009 3:00:00 PM 80.02312942 58.99619298 Normal 

## 0.737239 no WABoeingR enton BOIL04 08/18/09 06:00 2.201358477 1.622965947 normal 

## 0.737257 no ARDomtarIn dustries PB1 8/22/2009 8:00:00 PM 34.67575415 25.57654145 Normal 

## 0.737591 no ARDomtarIn dustries PB1 8/23/2009 5:00:00 PM 37.10191047 27.36726625 Normal 

## 0.737624 no TXDibollTem ple-Inland PB-44 0400-0500 2.335751743 1.723973079 

## 0.738081 no ARDomtarIn dustries PB1 8/15/2009 9:00:00 AM 7.343223337 5.419959985 Normal 

## 0.73809 no ARDomtarIn dustries PB1 8/13/2009 1:00:00 AM 10.69888342 7.89701231 Normal 

## 0.738116 no TXDibollTem ple-Inland PB-44 1900-2000 2.267388008 1.674150149 

## 0.738361 no

ARDomtarIn dustries PB1 8/15/2009 10:00:00 AM 7.206460303 5.322830536 Normal 10:06 - 10:55 calibration 10:06 - 10:55 calibration 

## 0.738619 no

ARDomtarIn dustries PB1 8/13/2009 11:00:00 PM 13.2849244 9.813321578 Normal 

## 0.738681 no TXDibollTem ple-Inland PB-44 1500-1600 3.065228869 2.264371006 

## 0.738728 no TXDibollTem ple-Inland PB-44 0800-0900 3.22132439 2.380079041 

## 0.738851 no TXDibollTem ple-Inland PB-44 1000-1100 2.333578475 1.724416303 

## 0.738958 no ARDomtarIn dustries PB1 8/14/2009 12.49680752 9.237203513 Normal 

## 0.739165 no ARDomtarIn dustries PB1 8/23/2009 3:00:00 AM 18.15767865 13.42529287 Normal 

## 0.739373 no TXDibollTem ple-Inland PB-44 10/16/2009 0000-0100 3.369191717 2.4918493 

## 0.739599 no ARDomtarIn dustries PB1 8/30/2009 9:00:00 PM 2.763381423 2.043993381 Normal 

## 0.739671 no ARDomtarIn dustries PB1 8/23/2009 6:00:00 PM 53.92637836 39.90181641 Normal 

## 0.739931 no TXDibollTem ple-Inland PB-44 1600-1700 3.005372919 2.224039311 

## 0.740021 no TXDibollTem ple-Inland PB-44 1400-1500 2.158649666 1.598013175 

## 0.740284 no TXDibollTem ple-Inland PB-44 1300-1400 2.950560348 2.185687694 

## 0.74077 no

ARDomtarIn dustries PB1 8/14/2009 11:00:00 PM 5.767316501 4.272811096 Normal 

## 0.740866 no TXDibollTem ple-Inland PB-44 2100-2200 2.458906768 1.822466986 

## 0.74117 no TXDibollTem ple-Inland PB-44 1300-1400 2.303654717 1.707465544 

## 0.741199 no TXDibollTem ple-Inland PB-44 1300-1400 2.440298137 1.808962703 

## 0.741288 no ARDomtarIn dustries PB1 8/19/2009 2:00:00 AM 5.062100895 3.752550109 Normal 

## 0.741303 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 1200-1300 3.037398654 2.251723822 

## 0.741333 no ARDomtarIn dustries PB1 9/1/2009 2.783075162 2.065379121 Normal 

## 0.742121 no ARDomtarIn dustries PB1 8/22/2009 9:00:00 AM 15.48769761 11.50210928 Normal 

## 0.742661 no TXDibollTem ple-Inland PB-44 1100-1200 3.35571657 2.49245247 

## 0.742748 no TXDibollTem ple-Inland PB-44 0300-0400 5.519512719 4.101717621 

## 0.74313 no TXDibollTem ple-Inland PB-44 1400-1500 2.591732479 1.927405639 

## 0.743675 no ARDomtarIn dustries PB1 8/19/2009 9:00:00 PM 4.228758337 3.145628438 Normal 

## 0.743866 no TXDibollTem ple-Inland PB-44 1100-1200 4.03623261 3.002908683 

## 0.743988 no
WVDuPont Washington Works P05 10/20/2009 9:00:04 AM 0.558387479 0.415508167 

## 0.744122 no ARDomtarIn dustries PB1 8/14/2009 7:00:00 PM 6.267720948 4.665196011 Normal 

## 0.744321 no WABoeingR enton BOIL04 08/11/09 21:00 0.974136375 0.725620883 normal 

## 0.744886 no VAPhilipMorr isPark500 B3 10/1/2009 8:00:00 AM 13.7344516 10.23945545 Normal 

## 0.745531 no TXDibollTem ple-Inland PB-44 0400-0500 2.265500122 1.689604683 

## 0.745798 no TXDibollTem ple-Inland PB-44 2200-2300 3.004988894 2.243126874 

## 0.746468 no TXDibollTem ple-Inland PB-44 0300-0400 2.483062279 1.854845446 

## 0.746999 no WABoeingR enton BOIL04 08/15/09 14:00 0.842792144 0.629582825 normal 

## 0.74702 no TXDibollTem ple-Inland PB-44 0100-0200 2.181577108 1.630260903 

## 0.747285 no TXDibollTem ple-Inland PB-44 1200-1300 2.394071911 1.789457439 

## 0.747454 no

ARDomtarIn dustries PB1 8/22/2009 11:00:00 AM 21.43548324 16.03074186 Normal 

## 0.74786 no TXDibollTem ple-Inland PB-44 1000-1100 2.517376863 1.882672541 

## 0.747871 no TXDibollTem ple-Inland PB-44 0800-0900 2.892729274 2.164369171 

## 0.74821 no ARDomtarIn dustries PB1 8/18/2009 3.300694356 2.470095157 Normal 

## 0.748356 no

ARDomtarIn dustries PB1 8/31/2009 11:00:00 AM 3.798303843 2.843056076 Normal 

## 0.748507 no ARDomtarIn dustries PB1 8/13/2009 2:00:00 AM 7.504505577 5.618913562 Normal 

## 0.748739 no TXDibollTem ple-Inland PB-44 1500-1600 2.239141002 1.676849319 

## 0.748881 no ARDomtarIn dustries PB1 8/19/2009 8:00:00 PM 4.172114707 3.126602325 Normal 

## 0.749405 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
ARDomtarIn dustries PB1 8/23/2009 2:00:00 PM 19.71699874 14.77978283 Normal 

## 0.749596 no WABoeingR enton BOIL04 10/10/09 02:00 0.573002579 0.429718777 normal 

## 0.749942 no TXDibollTem ple-Inland PB-44 1500-1600 3.441417444 2.580959513 

## 0.74997 no TXDibollTem ple-Inland PB-44 0500-0600 2.335398936 1.75205993 

## 0.750219 no

ARDomtarIn dustries PB1 8/22/2009 10:00:00 AM 16.31089481 12.24209414 Normal 10:08 - 10:59 calibration 10:08 - 10:59 calibration 

## 0.750547 no ARDomtarIn dustries PB1 8/31/2009 2:00:00 AM 3.007164689 2.257366363 Normal 

## 0.750663 no ARDomtarIn dustries PB1 8/30/2009 7:00:00 PM 2.581945959 1.938806475 Normal 

## 0.750909 no TXDibollTem ple-Inland PB-44 0300-0400 2.286160808 1.716918044 

## 0.751005 no TXDibollTem ple-Inland PB-44 0500-0600 2.399396465 1.801961954 

## 0.751006 no TXDibollTem ple-Inland PB-44 1300-1400 3.249103697 2.440144707 

## 0.751021 no TXDibollTem ple-Inland PB-44 1200-1300 2.253863006 1.69275993 

## 0.751048 no TXDibollTem ple-Inland PB-44 10/09/2009 0000-0100 2.31939041 1.743009127 

## 0.751494 no TXDibollTem ple-Inland PB-44 1900-2000 2.024569082 1.521571766 

## 0.751553 no TXDibollTem ple-Inland PB-44 0600-0700 3.293814026 2.475493314 

## 0.751558 no ARDomtarIn dustries PB1 8/13/2009 3:00:00 PM 5.08249807 3.823091477 Normal 

## 0.752207 no TXDibollTem ple-Inland PB-44 0700-0800 2.815661152 2.118299506 

## 0.752328 no TXDibollTem ple-Inland PB-44 0500-0600 2.931158263 2.205839564 

## 0.752549 no TXDibollTem ple-Inland PB-44 2200-2300 2.371093001 1.784839087 

## 0.75275 no ARDomtarIn dustries PB1 8/13/2009 3:00:00 AM 6.626004215 4.995026285 Normal 

## 0.753852 no TXDibollTem ple-Inland PB-44 1800-1900 2.741585389 2.068535524 

## 0.754503 no ARDomtarIn dustries PB1 8/14/2009 9:00:00 PM 5.704438204 4.305952992 Normal 

## 0.754843 no ARDomtarIn dustries PB1 8/23/2009 7:00:00 PM 56.93253212 42.97785193 Normal 

## 0.754891 no ARDomtarIn dustries PB1 8/15/2009 1:00:00 AM 8.312290956 6.275376458 Normal 

## 0.754951 no ARDomtarIn dustries PB1 8/15/2009 7:00:00 AM 6.275216117 4.738403656 Normal 

## 0.755098 no TXDibollTem ple-Inland PB-44 1500-1600 2.233890642 1.687264205 

## 0.755303 no TXDibollTem ple-Inland PB-44 2200-2300 2.9091894 2.197522839 

## 0.755373 no TXDibollTem ple-Inland PB-44 1200-1300 2.675445088 2.021020248 

## 0.755396 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
ARDomtarIn dustries PB1 8/29/2009 9:00:00 AM 3.142919626 2.375385958 Normal 

## 0.75579 no WABoeingR enton BOIL04 09/18/09 23:00 23.36059591 17.66462623 normal 

## 0.756172 no TXDibollTem ple-Inland PB-44 1800-1900 2.288170761 1.730292644 

## 0.75619 no VAPhilipMorr isPark500 B3 10/1/2009 7:00:00 AM 14.62628451 11.06112852 Normal 

## 0.75625 no ARDomtarIn dustries PB1 8/24/2009 9:00:00 AM 3.389855211 2.56374344 Normal 

## 0.756299 no TXDibollTem ple-Inland PB-44 2000-2100 2.249908771 1.7020386 

## 0.756492 no TXDibollTem ple-Inland PB-44 1700-1800 1.933585958 1.463987891 

## 0.757136 no TXDibollTem ple-Inland PB-44 1100-1200 3.041022863 2.304323224 

## 0.757746 no VAPhilipMorr isPark500 B3 10/2/2009 8:00:00 AM 3.435732205 2.605229235 Normal 

## 0.758275 no TXDibollTem ple-Inland PB-44 2200-2300 2.72335197 2.065294068 

## 0.758365 no TXDibollTem ple-Inland PB-44 2200-2300 2.715694547 2.060226431 

## 0.758637 no ARDomtarIn dustries PB1 8/30/2009 8:00:00 PM 3.266316534 2.477985597 Normal 

## 0.758648 no TXDibollTem ple-Inland PB-44 1400-1500 3.234583021 2.454124907 

## 0.758714 no TXDibollTem ple-Inland PB-44 2200-2300 3.003480677 2.279404239 

## 0.758921 no TXDibollTem ple-Inland PB-44 1400-1500 2.235154214 1.696342704 

## 0.758938 no ARDomtarIn dustries PB1 8/17/2009 4:00:00 PM 4.266581249 3.239552924 Normal 

## 0.759285 no WABoeingR enton BOIL04 09/20/09 23:00 17.99213368 13.66683337 normal 

## 0.7596 no TXDibollTem ple-Inland PB-44 2200-2300 2.558274943 1.94347242 

## 0.759681 no

ARDomtarIn dustries PB1 8/12/2009 10:00:00 PM 8.711712225 6.618872694 Normal 

## 0.759767 no TXDibollTem ple-Inland PB-44 0400-0500 2.870668606 2.181544349 

## 0.759943 no WABoeingR enton BOIL04 09/19/09 00:00 22.97332824 17.45896272 normal 

## 0.759967 no ARDomtarIn dustries PB1 8/17/2009 5:00:00 PM 4.748230794 3.610056396 Normal 

## 0.760295 no TXDibollTem ple-Inland PB-44 1500-1600 2.233890642 1.699529131 

## 0.760793 no ARDomtarIn dustries PB1 8/13/2009 4:00:00 PM 5.391714733 4.102038033 Normal 

## 0.760804 no WABoeingR enton BOIL04 09/20/09 13:00 18.89275581 14.38211259 normal 

## 0.76125 no WABoeingR enton BOIL04 09/20/09 11:00 18.97808573 14.45258857 normal 

## 0.761541 no TXDibollTem ple-Inland PB-44 0200-0300 2.877247357 2.191416743 

## 0.761637 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 1300-1400 2.823947987 2.151971363 

## 0.762044 no ARDomtarIn dustries PB1 8/14/2009 8:00:00 PM 6.008179518 4.579636378 Normal 

## 0.762234 no TXDibollTem ple-Inland PB-44 2300-2400 2.84143575 2.166224021 

## 0.76237 no TXDibollTem ple-Inland PB-44 0200-0300 2.845424751 2.169367627 

## 0.762406 no TXDibollTem ple-Inland PB-44 1600-1700 2.79132695 2.129612429 

## 0.762939 no ARDomtarIn dustries PB1 8/26/2009 2.839089409 2.166516166 Normal 

## 0.763102 no TXDibollTem ple-Inland PB-44 1200-1300 3.475318881 2.653148468 

## 0.763426 no TXDibollTem ple-Inland PB-44 1400-1500 2.955472044 2.257172412 

## 0.763727 no VAPhilipMorr isPark500 B3 10/1/2009 6:00:00 AM 15.89654826 12.14703305 Normal 

## 0.76413 no TXDibollTem ple-Inland PB-44 1500-1600 2.949747662 2.254702483 

## 0.764371 no TXDibollTem ple-Inland PB-44 0100-0200 2.69740269 2.062025774 

## 0.764449 no ARDomtarIn dustries PB1 8/19/2009 7:00:00 PM 4.895176802 3.742375116 Normal 

## 0.764503 no TXDibollTem ple-Inland PB-44 0600-0700 3.575393723 2.734439856 

## 0.764794 no TXDibollTem ple-Inland PB-44 1900-2000 2.80250001 2.1434344 

## 0.764829 no ARDomtarIn dustries PB1 8/30/2009 9:00:00 AM 6.235404562 4.769140545 Normal 

## 0.764849 no TXDibollTem ple-Inland PB-44 0100-0200 2.588158864 1.979671582 

## 0.764896 no

ARDomtarIn dustries PB1 8/30/2009 11:00:00 PM 3.394122386 2.596613829 Normal 

## 0.765032 no ARDomtarIn dustries PB1 8/23/2009 5:00:00 AM 15.790948 12.08745762 Normal 

## 0.765468 no TXDibollTem ple-Inland PB-44 0900-1000 3.144466191 2.407567269 

## 0.765652 no TXDibollTem ple-Inland PB-44 1400-1500 2.649810602 2.029288654 

## 0.765824 no TXDibollTem ple-Inland PB-44 0400-0500 6.587498575 5.045661457 

## 0.765945 no TXDibollTem ple-Inland PB-44 0600-0700 2.706110353 2.072759751 

## 0.765955 no VAPhilipMorr isPark500 B3 10/1/2009 8:00:00 PM 3.588213241 2.748615559 Normal 

## 0.766012 no VAPhilipMorr isPark500 B3 10/2/2009 5:00:00 AM 3.538099731 2.710227993 Normal 

## 0.766012 no VAPhilipMorr isPark500 B3 10/1/2009 9:00:00 PM 3.562981546 2.72928777 Normal 

## 0.766012 no VAPhilipMorr isPark500 B3 10/1/2009 7:00:00 PM 3.613804848 2.768219046 Normal 

## 0.766012 no TXDibollTem ple-Inland PB-44 0700-0800 3.186114108 2.440763403 

## 0.766063 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier

ARDomtarIn dustries PB1 8/22/2009 12:00:00 PM 21.42296644 16.41368042 Normal 

## 0.766172 no TXDibollTem ple-Inland PB-44 0800-0900 3.530816633 2.705608004 

## 0.766284 no TXDibollTem ple-Inland PB-44 0800-0900 7.636648579 5.854898127 

## 0.766684 no TXDibollTem ple-Inland PB-44 1700-1800 2.866005 2.19746338 

## 0.766734 no TXDibollTem ple-Inland PB-44 2300-2400 2.563746941 1.965919523 

## 0.766815 no TXDibollTem ple-Inland PB-44 0800-0900 2.222560479 1.705033923 

## 0.767148 no VAPhilipMorr isPark500 B3 10/1/2009 9:00:00 AM 16.20828577 12.43424998 Normal 

## 0.767154 no ARDomtarIn dustries PB1 8/13/2009 5:00:00 PM 5.315756582 4.080565819 Normal 

## 0.767636 no TXDibollTem ple-Inland PB-44 10/29/2009 0000-0100 2.570510587 1.974129238 

## 0.767991 no TXDibollTem ple-Inland PB-44 1600-1700 2.876477516 2.209747337 

## 0.768213 no TXDibollTem ple-Inland PB-44 2100-2200 2.950417269 2.267015905 

## 0.768371 no TXDibollTem ple-Inland PB-44 1700-1800 3.89387935 2.992623929 

## 0.768546 no TXDibollTem ple-Inland PB-44 1000-1100 2.260143233 1.737052846 

## 0.768559 no ARDomtarIn dustries PB1 8/17/2009 9:00:00 PM 2.999174206 2.305909675 Normal 

## 0.768848 no TXDibollTem ple-Inland PB-44 1400-1500 2.49910845 1.92249573 

## 0.769273 no ARDomtarIn dustries PB1 8/17/2009 8:00:00 PM 3.62651695 2.790362489 Normal 

## 0.769433 no TXDibollTem ple-Inland PB-44 1900-2000 5.162944185 3.974969624 

## 0.769904 no ARDomtarIn dustries PB1 8/13/2009 6:00:00 PM 5.070048359 3.903782794 Normal 

## 0.76997 no

ARDomtarIn dustries PB1 8/14/2009 10:00:00 PM 5.382621728 4.146918043 Normal 

## 0.770427 no TXDibollTem ple-Inland PB-44 1800-1900 3.147113959 2.424634208 

## 0.770431 no TXDibollTem ple-Inland PB-44 1900-2000 2.41435731 1.860102628 

## 0.770434 no TXDibollTem ple-Inland PB-44 2000-2100 2.940024953 2.265158027 

## 0.770455 no ARDomtarIn dustries PB1 8/22/2009 9:00:00 PM 33.35577102 25.70503309 Normal 

## 0.770632 no ARDomtarIn dustries PB1 8/23/2009 4:00:00 AM 20.16611166 15.54373522 Normal 

## 0.770785 no TXDibollTem ple-Inland PB-44 2300-2400 2.777101793 2.140917131 

## 0.770918 no TXDibollTem ple-Inland PB-44 0600-0700 2.546752188 1.96416653 

## 0.771244 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier

ARDomtarIn dustries PB1 8/29/2009 10:00:00 PM 5.595828791 4.315987781 Normal 

## 0.771287 no TXDibollTem ple-Inland PB-44 0100-0200 2.847731583 2.197195569 

## 0.77156 no TXDibollTem ple-Inland PB-44 2200-2300 2.855055193 2.203000401 

## 0.771614 no VAPhilipMorr isPark500 B3 10/1/2009 4:00:00 PM 3.11980008 2.407909891 Normal 

## 0.771815 no

VAPhilipMorr isPark500 B3 10/2/2009 10:00:00 AM 3.038643396 2.345271909 Normal 

## 0.771815 no

ARDomtarIn dustries PB1 8/17/2009 11:00:00 PM 3.748819946 2.893606079 Normal 

## 0.771871 no TXDibollTem ple-Inland PB-44 1500-1600 2.499615703 1.929396992 

## 0.771877 no

ARDomtarIn dustries PB1 8/22/2009 11:00:00 PM 31.93334172 24.64921547 Normal 

## 0.771896 no TXDibollTem ple-Inland PB-44 2100-2200 4.033981347 3.113981831 

## 0.771938 no TXDibollTem ple-Inland PB-44 11/01/2009 0000-0100 2.728242925 2.106638589 

## 0.772159 no WABoeingR enton BOIL04 08/16/09 12:00 1.110900956 0.857857318 normal 

## 0.772218 no TXDibollTem ple-Inland PB-44 2000-2100 2.821565617 2.179064633 

## 0.772289 no TXDibollTem ple-Inland PB-44 2000-2100 5.359336946 4.139122192 

## 0.77232 no TXDibollTem ple-Inland PB-44 2100-2200 2.767968767 2.138298276 

## 0.772515 no TXDibollTem ple-Inland PB-44 1600-1700 3.575750487 2.764004492 

## 0.772986 no

ARDomtarIn dustries PB1 8/22/2009 10:00:00 PM 36.8064935 28.45215398 Normal 

## 0.77302 no TXDibollTem ple-Inland PB-44 1600-1700 2.303654717 1.780885971 

## 0.77307 no ARDomtarIn dustries PB1 8/22/2009 8:00:00 AM 13.21181454 10.2146695 Normal 

## 0.773147 no

VAPhilipMorr isPark500 B3 10/1/2009 11:00:00 PM 3.690230887 2.853346305 Normal 

## 0.773216 no VAPhilipMorr isPark500 B3 10/2/2009 2:00:00 AM 3.690230887 2.853346305 Normal 

## 0.773216 no ARDomtarIn dustries PB1 8/18/2009 1:00:00 AM 3.631765955 2.808756423 Normal 

## 0.773386 no ARDomtarIn dustries PB1 8/23/2009 1:00:00 PM 17.92425358 13.86350226 Normal 

## 0.773449 no WABoeingR enton BOIL04 08/11/09 17:00 1.329251959 1.028168462 normal 

## 0.773494 no TXDibollTem ple-Inland PB-44 0400-0500 3.061787451 2.36877148 

## 0.773656 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 0400-0500 4.444590446 3.438951887 

## 0.773739 no

ARDomtarIn dustries PB1 8/17/2009 10:00:00 PM 3.764423885 2.912918952 Normal 

## 0.773802 no TXDibollTem ple-Inland PB-44 2300-2400 2.558274943 1.980182633 

## 0.77403 no

ARDomtarIn dustries PB1 8/23/2009 11:00:00 AM 19.94174441 15.44983976 Normal 

## 0.774749 no TXDibollTem ple-Inland PB-44 1800-1900 1.85036774 1.433654438 

## 0.774794 no ARDomtarIn dustries PB1 8/22/2009 3:00:00 PM 18.42247476 14.27433922 Normal 

## 0.774833 no TXDibollTem ple-Inland PB-44 2300-2400 2.88366331 2.23460803 

## 0.77492 no TXDibollTem ple-Inland PB-44 0300-0400 2.925536604 2.267334786 

## 0.775015 no TXDibollTem ple-Inland PB-44 1200-1300 2.889272558 2.239369811 

## 0.775064 no TXDibollTem ple-Inland PB-44 0700-0800 2.563977681 1.987332464 

## 0.775097 no TXDibollTem ple-Inland PB-44 0100-0200 3.352812146 2.599726655 

## 0.775387 no TXDibollTem ple-Inland PB-44 2300-2400 2.371093001 1.838592699 

## 0.77542 no TXDibollTem ple-Inland PB-44 1200-1300 2.854503268 2.216112892 

## 0.776357 no ARDomtarIn dustries PB1 8/23/2009 9:00:00 PM 22.48194382 17.45801572 Normal 

## 0.776535 no WABoeingR enton BOIL04 09/26/09 15:00 0.639534912 0.49668519 normal 

## 0.776635 no TXDibollTem ple-Inland PB-44 2300-2400 5.140274251 3.992168184 

## 0.776645 no TXDibollTem ple-Inland PB-44 11/03/2009 0000-0100 3.484706777 2.706440281 

## 0.776662 no ARDomtarIn dustries PB1 8/24/2009 8:00:00 PM 2.725591731 2.118023996 Normal 

## 0.777088 no ARDomtarIn dustries PB1 8/14/2009 6:00:00 PM 7.781321338 6.049069953 Normal 

## 0.777383 no WABoeingR enton BOIL04 08/18/09 05:00 1.732535745 1.346997434 normal 

## 0.777472 no ARDomtarIn dustries PB1 8/17/2009 7:00:00 PM 3.701770367 2.87822262 Normal 

## 0.777526 no TXDibollTem ple-Inland PB-44 0300-0400 2.77464645 2.157643872 

## 0.777628 no ARDomtarIn dustries PB1 8/22/2009 7:00:00 PM 21.53763427 16.74934696 Normal 

## 0.777678 no TXDibollTem ple-Inland PB-44 0400-0500 6.217324759 4.835337431 

## 0.77772 no TXDibollTem ple-Inland PB-44 0100-0200 2.282986665 1.775934717 

## 0.7779 no TXDibollTem ple-Inland PB-44 1900-2000 2.763895492 2.150530312 

## 0.778079 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 2000-2100 4.061319182 3.160222937 

## 0.778127 no TXDibollTem ple-Inland PB-44 1000-1100 3.540912905 2.756638217 

## 0.778511 no TXDibollTem ple-Inland PB-44 0500-0600 2.856854045 2.224446399 

## 0.778635 no TXDibollTem ple-Inland PB-44 09/30/2009 0000-0100 2.597058008 2.023219126 

## 0.779043 no TXDibollTem ple-Inland PB-44 0900-1000 2.239759409 1.745869392 

## 0.77949 no TXDibollTem ple-Inland PB-44 0600-0700 4.135952975 3.224192952 

## 0.779553 no VAPhilipMorr isPark500 B3 10/1/2009 3:00:00 PM 3.24979175 2.534641991 Normal 

## 0.77994 no VAPhilipMorr isPark500 B3 10/1/2009 5:00:00 PM 3.24979175 2.534641991 Normal 

## 0.77994 no WABoeingR enton BOIL04 08/23/09 07:00 0.110192804 0.085943755 normal 

## 0.77994 no

CATesoro S-974 Furance 55 9/18/2009 0.118019203 0.092047876 None 12:58-13:30 12:58-13:30 

## 0.77994 no VAPhilipMorr isPark500 B3 11/1/2009 2:00:00 AM 0.726794103 0.566855662 Normal 

## 0.77994 no TXDibollTem ple-Inland PB-44 0500-0600 3.45993293 2.702062385 

## 0.780958 no TXDibollTem ple-Inland PB-44 1000-1100 2.778637624 2.170542171 

## 0.781153 no TXDibollTem ple-Inland PB-44 1000-1100 3.150016068 2.461630002 

## 0.781466 no TXDibollTem ple-Inland PB-44 1300-1400 2.476255125 1.935265334 

## 0.781529 no TXDibollTem ple-Inland PB-44 10/28/2009 0000-0100 2.353379358 1.839899494 

## 0.781812 no WABoeingR enton BOIL04 08/11/09 18:00 1.052679946 0.823165098 normal 

## 0.781971 no ARDomtarIn dustries PB1 8/17/2009 6:00:00 PM 4.078906976 3.189850629 Normal 

## 0.782036 no TXDibollTem ple-Inland PB-44 0800-0900 3.221031941 2.520133469 

## 0.782399 no TXDibollTem ple-Inland PB-44 1400-1500 3.318549331 2.596620225 

## 0.782456 no TXDibollTem ple-Inland PB-44 2100-2200 2.862631149 2.240777135 

## 0.782768 no TXDibollTem ple-Inland PB-44 0200-0300 2.430065257 1.903055591 

## 0.783129 no TXDibollTem ple-Inland PB-44 0900-1000 3.54858745 2.779412932 

## 0.783245 no ARDomtarIn dustries PB1 8/23/2009 22.8589602 17.90537926 Normal 

## 0.783298 no TXDibollTem ple-Inland PB-44 1200-1300 2.771531838 2.171129265 

## 0.783368 no TXDibollTem ple-Inland PB-44 0500-0600 3.616545044 2.833288169 

## 0.783424 no TXDibollTem ple-Inland PB-44 1500-1600 2.800641455 2.195900639 

## 0.784071 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
WVDuPont Washington Works P05 10/5/2009 2:00:46 PM 0.328551931 0.257619587 

## 0.784106 no TXDibollTem ple-Inland PB-44 0900-1000 2.726531565 2.139071707 

## 0.784539 no TXDibollTem ple-Inland PB-44 1000-1100 3.131869875 2.457943851 

## 0.784817 no TXDibollTem ple-Inland PB-44 0800-0900 2.851910808 2.239020926 

## 0.785095 no TXDibollTem ple-Inland PB-44 0900-1000 3.350511107 2.630948034 

## 0.785238 no TXDibollTem ple-Inland PB-44 0900-1000 2.814973056 2.210648482 

## 0.785318 no TXDibollTem ple-Inland PB-44 2300-2400 2.931004178 2.301774235 

## 0.785319 no ARDomtarIn dustries PB1 8/29/2009 9:00:00 PM 4.154327983 3.264347509 Normal 

## 0.78577 no TXDibollTem ple-Inland PB-44 10/27/2009 0000-0100 3.723099582 2.927888624 

## 0.786412 no
WVDuPont Washington Works P05 9/25/2009 11:00:07 AM 0.141798357 0.111531423 

## 0.786549 no TXDibollTem ple-Inland PB-44 0600-0700 3.191657268 2.510480605 

## 0.786576 no TXDibollTem ple-Inland PB-44 1400-1500 2.677520323 2.106927822 

## 0.786895 no WABoeingR enton BOIL04 09/20/09 12:00 17.37015867 13.6751763 normal 

## 0.78728 no TXDibollTem ple-Inland PB-44 0100-0200 2.595103469 2.04540645 

## 0.788179 no TXDibollTem ple-Inland PB-44 0300-0400 3.080793146 2.430642984 

## 0.788967 no TXDibollTem ple-Inland PB-44 1000-1100 2.270541152 1.791617134 

## 0.789071 no TXDibollTem ple-Inland PB-44 1100-1200 2.280900528 1.80127874 

## 0.789723 no TXDibollTem ple-Inland PB-44 11/02/2009 0000-0100 2.454512019 1.939057583 

## 0.789997 no ARDomtarIn dustries PB1 8/14/2009 5:00:00 PM 7.084481012 5.604682074 Normal 

## 0.791121 no WABoeingR enton BOIL04 08/11/09 23:00 0.929787882 0.735842984 normal 

## 0.79141 no TXDibollTem ple-Inland PB-44 2000-2100 2.579470446 2.041920989 

## 0.791605 no TXDibollTem ple-Inland PB-44 1900-2000 3.403217074 2.694175714 

## 0.791656 no WABoeingR enton BOIL04 09/20/09 10:00 17.1661077 13.60547473 normal 

## 0.792578 no ARDomtarIn dustries PB1 8/22/2009 2:00:00 PM 16.66387132 13.21024434 Normal 

## 0.792748 no TXDibollTem ple-Inland PB-44 10/30/2009 0000-0100 3.254773702 2.583564266 

## 0.793777 no VAPhilipMorr isPark500 B3 10/1/2009 6:00:00 PM 3.50977509 2.78810619 Normal 

## 0.794383 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier

ARDomtarIn dustries PB1 8/23/2009 12:00:00 PM 21.48198848 17.06806739 Normal 

## 0.794529 no TXDibollTem ple-Inland PB-44 2300-2400 5.153346767 4.098001482 

## 0.795212 no TXDibollTem ple-Inland PB-44 1700-1800 2.603130007 2.070386551 

## 0.795345 no TXDibollTem ple-Inland PB-44 0700-0800 3.631462051 2.888678319 

## 0.795459 no TXDibollTem ple-Inland PB-44 1300-1400 2.843765341 2.263214103 

## 0.795851 no TXDibollTem ple-Inland PB-44 0600-0700 2.512547256 1.999933337 

## 0.795978 no ARDomtarIn dustries PB1 8/30/2009 6:00:00 PM 2.248309298 1.789903723 Normal 

## 0.796111 no TXDibollTem ple-Inland PB-44 1700-1800 2.563186479 2.040602911 

## 0.79612 no TXDibollTem ple-Inland PB-44 2100-2200 2.954044656 2.352573475 

## 0.796391 no TXDibollTem ple-Inland PB-44 1300-1400 2.421237997 1.928252836 

## 0.796391 no TXDibollTem ple-Inland PB-44 1800-1900 3.434476013 2.735600412 

## 0.796512 no TXDibollTem ple-Inland PB-44 2000-2100 3.165080043 2.522496103 

## 0.796977 no WABoeingR enton BOIL04 08/17/09 21:00 1.620900769 1.291966313 normal 

## 0.797067 no TXDibollTem ple-Inland PB-44 0300-0400 2.237292908 1.785063498 

## 0.797868 no ARDomtarIn dustries PB1 8/14/2009 3:00:00 PM 8.860616485 7.07045332 Normal 

## 0.797964 no TXDibollTem ple-Inland PB-44 2200-2300 2.66006161 2.124628199 

## 0.798714 no TXDibollTem ple-Inland PB-44 1800-1900 2.728353444 2.179518028 

## 0.79884 no TXDibollTem ple-Inland PB-44 1600-1700 2.843940238 2.272614501 

## 0.799108 no TXDibollTem ple-Inland PB-44 0600-0700 2.527801565 2.020205229 

## 0.799195 no TXDibollTem ple-Inland PB-44 0500-0600 3.261579771 2.608179831 

## 0.799668 no TXDibollTem ple-Inland PB-44 0900-1000 3.334663657 2.666787216 

## 0.799717 no WABoeingR enton BOIL04 08/11/09 22:00 0.919409612 0.736291778 normal 

## 0.800831 no VAPhilipMorr isPark500 B3 10/2/2009 1:00:00 AM 3.513565484 2.813772387 Normal 

## 0.800831 no VAPhilipMorr isPark500 B3 10/2/2009 3.588213241 2.87355263 Normal 

## 0.800831 no TXDibollTem ple-Inland PB-44 1700-1800 4.586698115 3.673326428 

## 0.800865 no TXDibollTem ple-Inland PB-44 2300-2400 2.304575039 1.846503785 

## 0.801234 no ARDomtarIn dustries PB1 9/1/2009 4:00:00 AM 3.389745463 2.716681984 Normal 

## 0.801441 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 0100-0200 3.390335461 2.717305922 

## 0.801486 no TXDibollTem ple-Inland PB-44 0100-0200 3.127237647 2.510924402 

## 0.802921 no TXDibollTem ple-Inland PB-44 1600-1700 2.983017516 2.395634767 

## 0.803091 no TXDibollTem ple-Inland PB-44 0300-0400 3.494747368 2.808879516 

## 0.803743 no TXDibollTem ple-Inland PB-44 0400-0500 3.014597372 2.423122556 

## 0.803796 no ARDomtarIn dustries PB1 8/14/2009 4:00:00 PM 7.624589491 6.129303434 Normal 

## 0.803886 no TXDibollTem ple-Inland PB-44 0200-0300 4.629353298 3.721808771 

## 0.803959 no TXDibollTem ple-Inland PB-44 0500-0600 3.58688194 2.884415707 

## 0.804157 no TXDibollTem ple-Inland PB-44 0200-0300 2.530920007 2.035621476 

## 0.804301 no TXDibollTem ple-Inland PB-44 1900-2000 2.533275576 2.038148448 

## 0.804551 no TXDibollTem ple-Inland PB-44 0200-0300 3.168752038 2.549630081 

## 0.804616 no TXDibollTem ple-Inland PB-44 0600-0700 3.304592337 2.660283739 

## 0.805026 no TXDibollTem ple-Inland PB-44 0400-0500 3.331278326 2.682462118 

## 0.805235 no TXDibollTem ple-Inland PB-44 2200-2300 3.326621462 2.679054407 

## 0.805338 no

VAPhilipMorr isPark500 B3 10/2/2009 11:00:00 AM 2.871681628 2.312773813 Normal 

## 0.805373 no VAPhilipMorr isPark500 B3 10/1/2009 2:00:00 PM 2.98980841 2.407909891 Normal 

## 0.805373 no TXDibollTem ple-Inland PB-44 2100-2200 4.271152444 3.440186746 

## 0.805447 no WABoeingR enton BOIL04 09/19/09 08:00 19.16760086 15.43887183 normal 

## 0.805467 no TXDibollTem ple-Inland PB-44 0300-0400 3.139869884 2.529228479 

## 0.80552 no WABoeingR enton BOIL04 09/20/09 14:00 15.96863033 12.86561259 normal 

## 0.80568 no TXDibollTem ple-Inland PB-44 2300-2400 2.979902466 2.40197097 

## 0.806057 no ARDomtarIn dustries PB1 8/14/2009 2:00:00 PM 8.646211077 6.972249221 Normal 

## 0.806394 no TXDibollTem ple-Inland PB-44 0100-0200 3.078186821 2.482285425 

## 0.806412 no TXDibollTem ple-Inland PB-44 0300-0400 3.074424538 2.47953807 

## 0.806505 no TXDibollTem ple-Inland PB-44 0600-0700 4.32256932 3.490204457 

## 0.807437 no

ARDomtarIn dustries PB1 8/25/2009 11:00:00 PM 2.306354139 1.862372365 Normal 

## 0.807496 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/26/09 16:00 4.035273127 3.260589026 normal 

## 0.808022 no TXDibollTem ple-Inland PB-44 0800-0900 2.947915438 2.382530644 

## 0.808209 no TXDibollTem ple-Inland PB-44 1200-1300 3.655373938 2.957916151 

## 0.809197 no WABoeingR enton BOIL04 08/10/09 19:00 1.231890169 0.997259132 normal 

## 0.809536 no TXDibollTem ple-Inland PB-44 0100-0200 2.92296104 2.368359888 

## 0.810261 no TXDibollTem ple-Inland PB-44 2100-2200 3.326150651 2.697835141 

## 0.811098 no TXDibollTem ple-Inland PB-44 2100-2200 3.200917401 2.597033148 

## 0.81134 no TXDibollTem ple-Inland PB-44 1300-1400 3.434828181 2.787948629 

## 0.81167 no TXDibollTem ple-Inland PB-44 0300-0400 3.85691396 3.132441228 

## 0.812163 no WABoeingR enton BOIL04 08/11/09 19:00 0.9856829 0.800805566 normal 

## 0.812437 no

VAPhilipMorr isPark500 B3 11/1/2009 10:00:00 AM 0.868635044 0.70571152 Normal 

## 0.812437 no VAPhilipMorr isPark500 B3 11/1/2009 5:00:00 AM 0.872152924 0.708569577 Normal 

## 0.812437 no

VAPhilipMorr isPark500 B3 9/21/2009 10:00:00 AM 1.548773506 1.258281384 Normal 

## 0.812437 no VAPhilipMorr isPark500 B3 10/5/2009 2:00:00 AM 2.338266431 1.899694894 Normal 

## 0.812437 no VAPhilipMorr isPark500 B3 10/6/2009 3:00:00 AM 2.338266431 1.899694894 Normal 

## 0.812437 no VAPhilipMorr isPark500 B3 10/31/2009 5:00:00 AM 3.551319261 2.885224274 Normal 

## 0.812437 no

ARDomtarIn dustries PB1 8/26/2009 11:00:00 AM 3.357089403 2.728535459 Normal 

## 0.812768 no
WVDuPont Washington Works P05 9/22/2009 5:00:07 PM 0.43631606 0.354719772 

## 0.812988 no TXDibollTem ple-Inland PB-44 0700-0800 3.589602757 2.918521276 

## 0.813049 no TXDibollTem ple-Inland PB-44 2300-2400 3.365977463 2.736713429 

## 0.813052 no
WVDuPont Washington Works P05 9/23/2009 9:00:21 AM 0.314691535 0.25589957 

## 0.813176 no TXDibollTem ple-Inland PB-44 0800-0900 3.105139692 2.526499246 

## 0.813651 no TXDibollTem ple-Inland PB-44 0100-0200 3.609528625 2.937968164 

## 0.813948 no TXDibollTem ple-Inland PB-44 2000-2100 2.30317881 1.87476398 

## 0.81399 no TXDibollTem ple-Inland PB-44 10/24/2009 0000-0100 4.34173795 3.535368996 

## 0.814275 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 9/17/2009 3:00:00 PM 7.98639832 6.509721583 Normal 

## 0.815101 no ARDomtarIn dustries PB1 8/23/2009 1:00:00 AM 13.70457182 11.17699403 Normal 

## 0.815567 no TXDibollTem ple-Inland PB-44 1600-1700 2.452639993 2.00071516 

## 0.815739 no TXDibollTem ple-Inland PB-44 1600-1700 3.815890971 3.115909118 

## 0.816561 no TXDibollTem ple-Inland PB-44 0800-0900 3.086102387 2.520291066 

## 0.816658 no ARDomtarIn dustries PB1 8/22/2009 6:00:00 PM 18.06538725 14.75605595 Normal 

## 0.816814 no TXDibollTem ple-Inland PB-44 1800-1900 4.400941379 3.596161789 

## 0.817135 no TXDibollTem ple-Inland PB-44 0500-0600 3.298570841 2.696882245 

## 0.817591 no TXDibollTem ple-Inland PB-44 2100-2200 2.756615342 2.25491107 

## 0.818 no TXDibollTem ple-Inland PB-44 1700-1800 2.96429698 2.424874136 

## 0.818027 no TXDibollTem ple-Inland PB-44 10/26/2009 0000-0100 2.913925265 2.384892032 

## 0.818447 no TXDibollTem ple-Inland PB-44 10/25/2009 0000-0100 3.469962757 2.840609724 

## 0.818628 no ARDomtarIn dustries PB1 8/23/2009 2:00:00 AM 12.45182721 10.19390439 Normal 

## 0.818667 no TXDibollTem ple-Inland PB-44 0200-0300 3.430701167 2.808922928 

## 0.818761 no

ARDomtarIn dustries PB1 8/23/2009 10:00:00 PM 11.63965565 9.539623752 Normal 

## 0.81958 no TXDibollTem ple-Inland PB-44 0400-0500 3.615259566 2.965381195 

## 0.82024 no TXDibollTem ple-Inland PB-44 0700-0800 4.967693397 4.075697139 

## 0.820441 no TXDibollTem ple-Inland PB-44 0800-0900 6.35845019 5.219962464 

## 0.820949 no TXDibollTem ple-Inland PB-44 2100-2200 4.07162527 3.343332006 

## 0.82113 no TXDibollTem ple-Inland PB-44 0600-0700 3.612429148 2.966585422 

## 0.821216 no

ARDomtarIn dustries PB1 8/30/2009 10:00:00 AM 7.649658154 6.285002727 Normal 10:01 - 10:59 calibration 10:01 - 10:59 calibration 

## 0.821606 no

CATesoro S-974 Furance 55 8/28/2009 1.84615295 1.516863354 None 10:18-1048 10:18-1048 

## 0.821635 no WABoeingR enton BOIL04 09/20/09 22:00 14.71517383 12.09339576 normal 

## 0.821832 no ARDomtarIn dustries PB1 8/26/2009 1:00:00 AM 3.6757017 3.022245604 Normal 

## 0.822223 no VAPhilipMorr isPark500 B3 10/3/2009 8:00:00 AM 4.051524528 3.332754818 Normal 

## 0.822593 no TXDibollTem ple-Inland PB-44 1600-1700 3.263852449 2.685510823 

## 0.822804 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 1800-1900 2.533275576 2.084805758 

## 0.822968 no WABoeingR enton BOIL04 09/20/09 07:00 15.45831019 12.72361497 normal 

## 0.823092 no TXDibollTem ple-Inland PB-44 0200-0300 3.6527175 3.008123079 

## 0.82353 no TXDibollTem ple-Inland PB-44 2000-2100 2.774110614 2.286475913 

## 0.824219 no VAPhilipMorr isPark500 B3 10/4/2009 4:00:00 AM 3.320155065 2.738916593 Normal 

## 0.824936 no TXDibollTem ple-Inland PB-44 10/14/2009 0000-0100 8.048790525 6.640214904 

## 0.824995 no TXDibollTem ple-Inland PB-44 0900-1000 2.660954447 2.196735297 

## 0.825544 no TXDibollTem ple-Inland PB-44 0800-0900 3.404570633 2.812011209 

## 0.825952 no TXDibollTem ple-Inland PB-44 1400-1500 3.861989933 3.190306005 

## 0.826078 no TXDibollTem ple-Inland PB-44 2000-2100 3.349969755 2.769423878 

## 0.826701 no TXDibollTem ple-Inland PB-44 1800-1900 3.207805254 2.65298339 

## 0.82704 no TXDibollTem ple-Inland PB-44 1300-1400 58.36586645 48.27445866 

## 0.827101 no TXDibollTem ple-Inland PB-44 1200-1300 3.605520569 2.982372552 

## 0.827168 no TXDibollTem ple-Inland PB-44 0600-0700 3.493273703 2.89160264 

## 0.827763 no TXDibollTem ple-Inland PB-44 2100-2200 5.167352974 4.281625036 

## 0.828592 no TXDibollTem ple-Inland PB-44 1900-2000 3.216971872 2.666356785 

## 0.828841 no TXDibollTem ple-Inland PB-44 0800-0900 3.751287126 3.109730659 

## 0.828977 no TXDibollTem ple-Inland PB-44 0700-0800 4.097714443 3.398829807 

## 0.829445 no TXDibollTem ple-Inland PB-44 2300-2400 4.134836925 3.429826726 

## 0.829495 no TXDibollTem ple-Inland PB-44 1100-1200 2.996353703 2.485928875 

## 0.829651 no TXDibollTem ple-Inland PB-44 1900-2000 5.051456449 4.195409008 

## 0.830535 no TXDibollTem ple-Inland PB-44 1100-1200 12.06867288 10.02672467 

## 0.830806 no WABoeingR enton BOIL04 08/15/09 09:00 0.966728697 0.803256611 normal 

## 0.830902 no TXDibollTem ple-Inland PB-44 2200-2300 7.312679562 6.07950516 

## 0.831365 no WABoeingR enton BOIL04 09/20/09 15:00 14.24501691 11.84699405 normal 

## 0.831659 no TXDibollTem ple-Inland PB-44 1000-1100 3.968036921 3.3019425 

## 0.832135 no TXDibollTem ple-Inland PB-44 0500-0600 4.487966612 3.736704517 

## 0.832605 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 0200-0300 2.981680169 2.482967834 

## 0.832741 no WABoeingR enton BOIL04 09/20/09 20:00 14.08044885 11.72824563 normal 

## 0.832945 no TXDibollTem ple-Inland PB-44 0300-0400 3.484171168 2.90533964 

## 0.833868 no TXDibollTem ple-Inland PB-44 0300-0400 3.46709892 2.894058153 

## 0.83472 no TXDibollTem ple-Inland PB-44 1500-1600 3.682230015 3.075113554 

## 0.835123 no WABoeingR enton BOIL04 09/18/09 19:00 17.77051484 14.84109331 normal 

## 0.835153 no VAPhilipMorr isPark500 B3 10/31/2009 7:00:00 AM 1.064954222 0.889928789 Normal 

## 0.83565 no VAPhilipMorr isPark500 B3 10/31/2009 9:00:00 AM 1.025820676 0.85722685 Normal 

## 0.83565 no VAPhilipMorr isPark500 B3 10/5/2009 8:00:00 PM 3.637303337 3.03951183 Normal 

## 0.83565 no

CATesoro S-974 Furance 55 9/15/2009 0.082234878 0.06871956 None 08:25-08:51 08:25-08:51 

## 0.83565 no WABoeingR enton BOIL04 09/20/09 19:00 13.89591361 11.61211752 normal 

## 0.83565 no TXDibollTem ple-Inland PB-44 2200-2300 10.85248862 9.071593515 

## 0.8359 no TXDibollTem ple-Inland PB-44 2200-2300 4.140189188 3.462236916 

## 0.836251 no WABoeingR enton BOIL04 09/19/09 17:00 14.65215381 12.27771509 normal 

## 0.837946 no TXDibollTem ple-Inland PB-44 0300-0400 6.852149286 5.743242803 

## 0.838167 no TXDibollTem ple-Inland PB-44 2300-2400 6.46266971 5.417348884 

## 0.838252 no TXDibollTem ple-Inland PB-44 0700-0800 3.668615951 3.077371787 

## 0.838837 no WABoeingR enton BOIL04 09/20/09 17:00 13.71922269 11.51697479 normal 

## 0.839477 no ARDomtarIn dustries PB1 8/24/2009 4:00:00 AM 6.242766863 5.245168755 Normal 

## 0.840199 no ARDomtarIn dustries PB1 8/24/2009 3:00:00 AM 7.829521201 6.57894146 Normal 

## 0.840274 no WABoeingR enton BOIL04 09/20/09 21:00 13.86774625 11.65305816 normal 

## 0.840299 no TXDibollTem ple-Inland PB-44 0200-0300 3.701410535 3.110857901 

## 0.840452 no VAPhilipMorr isPark500 B3 10/5/2009 9:00:00 PM 3.740574605 3.143774873 Normal 

## 0.840452 no TXDibollTem ple-Inland PB-44 1700-1800 3.293907888 2.769142276 

## 0.840686 no WABoeingR enton BOIL04 09/20/09 16:00 13.77888151 11.58857742 normal 

## 0.841039 no ARDomtarIn dustries PB1 8/24/2009 7:00:00 AM 3.602605676 3.032347585 Normal 

## 0.84171 no VAPhilipMorr isPark500 B3 10/6/2009 4:00:00 AM 2.837677287 2.389268903 Normal 

## 0.84198 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 10/5/2009 3:00:00 AM 2.878374861 2.423535467 Normal 

## 0.84198 no

VAPhilipMorr isPark500 B3 10/4/2009 10:00:00 PM 1.992505621 1.677650853 Normal 

## 0.84198 no ARDomtarIn dustries PB1 8/24/2009 6:00:00 AM 3.619350819 3.048470988 Normal 

## 0.84227 no WABoeingR enton BOIL04 09/20/09 18:00 13.74573849 11.60198645 normal 

## 0.844042 no
WVDuPont Washington Works P05 9/22/2009 4:00:06 PM 0.436317422 0.368659776 

## 0.844935 no VAPhilipMorr isPark500 B3 10/2/2009 7:00:00 PM 3.798304245 3.209319455 Normal 

## 0.844935 no TXDibollTem ple-Inland PB-44 0700-0800 4.561355309 3.854205809 

## 0.844969 no
WVDuPont Washington Works P05 9/23/2009 3:00:27 PM 0.288884715 0.244645668 

## 0.846863 no TXDibollTem ple-Inland PB-44 0500-0600 4.713037552 3.992977506 

## 0.84722 no VAPhilipMorr isPark500 B3 10/3/2009 6:00:00 AM 3.924914387 3.332754818 Normal 

## 0.849128 no TXDibollTem ple-Inland PB-44 0700-0800 5.835691286 4.970173472 

## 0.851685 no TXDibollTem ple-Inland PB-44 1700-1800 5.153736317 4.390910207 

## 0.851986 no WABoeingR enton BOIL04 08/26/09 18:00 3.397203224 2.895344406 normal 

## 0.852273 no VAPhilipMorr isPark500 B3 10/5/2009 3:00:00 PM 3.117688574 2.659572851 Normal 

## 0.853059 no VAPhilipMorr isPark500 B3 10/6/2009 1:00:00 AM 3.117688574 2.659572851 Normal 

## 0.853059 no VAPhilipMorr isPark500 B3 10/3/2009 7:00:00 AM 4.023259398 3.432078353 Normal 

## 0.853059 no VAPhilipMorr isPark500 B3 10/5/2009 1:00:00 AM 2.093363535 1.785762976 Normal 

## 0.853059 no VAPhilipMorr isPark500 B3 10/2/2009 2:00:00 PM 3.038643396 2.592142636 Normal 

## 0.853059 no VAPhilipMorr isPark500 B3 10/6/2009 5:00:00 AM 3.07391677 2.622232912 Normal 

## 0.853059 no

VAPhilipMorr isPark500 B3 10/2/2009 12:00:00 PM 3.081949617 2.629085406 Normal 

## 0.853059 no VAPhilipMorr isPark500 B3 10/4/2009 8:00:00 PM 3.140045303 2.678644464 Normal 

## 0.853059 no TXDibollTem ple-Inland PB-44 2100-2200 3.76733636 3.227539529 

## 0.856717 no TXDibollTem ple-Inland PB-44 1900-2000 4.320089977 3.702986362 

## 0.857155 no ARDomtarIn dustries PB1 8/24/2009 8:00:00 AM 4.012310859 3.440429559 Normal 

## 0.857468 no VAPhilipMorr isPark500 B3 10/5/2009 5:00:00 PM 3.270880524 2.806198962 Normal 

## 0.857934 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 10/3/2009 6:00:00 PM 3.148025616 2.700797584 Normal 

## 0.857934 no VAPhilipMorr isPark500 B3 10/4/2009 3:00:00 AM 3.192456793 2.738916593 Normal 

## 0.857934 no

ARDomtarIn dustries PB1 8/29/2009 10:00:00 AM 4.632928818 3.98019284 Normal 10:07 - 10:59 calibration 10:07 - 10:59 calibration 

## 0.859109 no WABoeingR enton BOIL04 09/26/09 20:00 0.641472192 0.551188659 normal 

## 0.859256 no TXDibollTem ple-Inland PB-44 2100-2200 7.926571928 6.811488056 

## 0.859323 no ARDomtarIn dustries PB1 8/24/2009 1:00:00 AM 7.376079658 6.34217179 Normal 

## 0.85983 no VAPhilipMorr isPark500 B3 10/4/2009 9:00:00 AM 3.367686533 2.904405529 Normal 

## 0.862433 no VAPhilipMorr isPark500 B3 10/6/2009 8:00:00 AM 3.377495955 2.912865503 Normal 

## 0.862433 no

VAPhilipMorr isPark500 B3 10/3/2009 10:00:00 PM 3.320155065 2.863412801 Normal 

## 0.862433 no VAPhilipMorr isPark500 B3 10/4/2009 2:00:00 PM 3.353618611 2.892272883 Normal 

## 0.862433 no VAPhilipMorr isPark500 B3 10/4/2009 6:00:00 PM 3.353618611 2.892272883 Normal 

## 0.862433 no VAPhilipMorr isPark500 B3 10/5/2009 1:00:00 PM 3.401715745 2.93375346 Normal 

## 0.862433 no TXDibollTem ple-Inland PB-44 0400-0500 4.246290452 3.663745216 

## 0.862811 no WABoeingR enton BOIL04 09/19/09 20:00 13.9119557 12.00685674 normal 

## 0.86306 no WABoeingR enton BOIL04 09/20/09 06:00 13.84429778 11.96781415 normal 

## 0.864458 no TXDibollTem ple-Inland PB-44 0500-0600 7.316325329 6.326569883 

## 0.86472 no TXDibollTem ple-Inland PB-44 1100-1200 7.587098567 6.563238485 

## 0.865052 no WABoeingR enton BOIL04 09/19/09 19:00 13.56724295 11.73810678 normal 

## 0.86518 no WABoeingR enton BOIL04 08/17/09 04:00 1.176174201 1.018081588 normal 

## 0.865587 no

VAPhilipMorr isPark500 B3 10/3/2009 11:00:00 AM 3.472358979 3.009145594 Normal 

## 0.8666 no

CATesoro S-974 Furance 55 9/21/2009 0.215409443 0.18667378 None 14:51-15:10 14:51-15:10 

## 0.8666 no VAPhilipMorr isPark500 B3 10/6/2009 3.482603943 3.018023878 Normal 

## 0.8666 no VAPhilipMorr isPark500 B3 10/5/2009 6:00:00 PM 3.507399646 3.03951183 Normal 

## 0.8666 no TXDibollTem ple-Inland PB-44 2100-2200 6.699189259 5.812873296 

## 0.867698 no WABoeingR enton BOIL04 08/22/09 11:00 1.003370607 0.870715163 normal 

## 0.86779 no ARDomtarIn dustries PB1 8/24/2009 5:00:00 AM 6.082260769 5.288208131 Normal 

## 0.869448 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/23/09 01:00 0.407213296 0.35408316 normal 

## 0.869528 no

VAPhilipMorr isPark500 B3 10/5/2009 10:00:00 PM 3.637303337 3.166158156 Normal 

## 0.870469 no VAPhilipMorr isPark500 B3 10/6/2009 9:00:00 AM 3.637303337 3.166158156 Normal 

## 0.870469 no VAPhilipMorr isPark500 B3 10/4/2009 7:00:00 PM 2.535916245 2.207435333 Normal 

## 0.870469 no

VAPhilipMorr isPark500 B3 10/4/2009 11:00:00 AM 3.586236232 3.121705847 Normal 

## 0.870469 no VAPhilipMorr isPark500 B3 10/5/2009 5:00:00 AM 3.663386187 3.188862457 Normal 

## 0.870469 no

VAPhilipMorr isPark500 B3 10/5/2009 12:00:00 PM 3.663386187 3.188862457 Normal 

## 0.870469 no VAPhilipMorr isPark500 B3 10/2/2009 8:00:00 PM 3.545083962 3.085884091 Normal 

## 0.870469 no VAPhilipMorr isPark500 B3 10/2/2009 9:00:00 PM 3.545083962 3.085884091 Normal 

## 0.870469 no ARDomtarIn dustries PB1 8/24/2009 2:00:00 AM 7.827950937 6.832055422 Normal 

## 0.872777 no

ARDomtarIn dustries PB1 8/23/2009 11:00:00 PM 5.778723251 5.045539277 Normal 

## 0.873124 no WABoeingR enton BOIL04 08/18/09 08:00 1.374035281 1.200264609 normal 

## 0.873533 no TXDibollTem ple-Inland PB-44 0900-1000 7.242421511 6.32893339 

## 0.87387 no VAPhilipMorr isPark500 B3 10/3/2009 2:00:00 AM 3.64607883 3.1869299 Normal 

## 0.87407 no WABoeingR enton BOIL04 08/15/09 08:00 0.635994134 0.555903703 normal 

## 0.87407 no

VAPhilipMorr isPark500 B3 10/2/2009 10:00:00 PM 3.671694104 3.209319455 Normal 

## 0.87407 no VAPhilipMorr isPark500 B3 10/3/2009 1:00:00 AM 3.671694104 3.209319455 Normal 

## 0.87407 no WABoeingR enton BOIL04 08/13/09 19:00 1.832344094 1.604548789 normal 

## 0.875681 no WABoeingR enton BOIL04 08/22/09 06:00 0.329768467 0.289349504 normal 

## 0.877432 no VAPhilipMorr isPark500 B3 10/2/2009 6:00:00 PM 3.771805686 3.309504126 Normal 

## 0.877432 no VAPhilipMorr isPark500 B3 10/3/2009 3.771805686 3.309504126 Normal 

## 0.877432 no VAPhilipMorr isPark500 B3 10/3/2009 5:00:00 AM 3.771805686 3.309504126 Normal 

## 0.877432 no VAPhilipMorr isPark500 B3 10/3/2009 9:00:00 AM 3.825180484 3.356336898 Normal 

## 0.877432 no VAPhilipMorr isPark500 B3 10/4/2009 6:00:00 AM 3.830948152 3.361397636 Normal 

## 0.877432 no VAPhilipMorr isPark500 B3 10/5/2009 6:00:00 AM 3.925056629 3.443971453 Normal 

## 0.877432 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier

VAPhilipMorr isPark500 B3 10/5/2009 11:00:00 AM 3.925056629 3.443971453 Normal 

## 0.877432 no VAPhilipMorr isPark500 B3 10/3/2009 3:00:00 AM 3.798304245 3.332754818 Normal 

## 0.877432 no VAPhilipMorr isPark500 B3 10/3/2009 4:00:00 AM 3.798304245 3.332754818 Normal 

## 0.877432 no WABoeingR enton BOIL04 08/16/09 05:00 0.78045204 0.685865491 normal 

## 0.878805 no

ARDomtarIn dustries PB1 8/24/2009 11:00:00 AM 8.121198493 7.141572476 Normal 

## 0.879374 no

CATesoro S-974 Furance 55 8/27/2009 1.566009377 1.378624642 None 14:07-14:45 14:07-14:45 

## 0.880343 no

VAPhilipMorr isPark500 B3 10/2/2009 11:00:00 PM 3.897532542 3.432078353 Normal 

## 0.880577 no VAPhilipMorr isPark500 B3 10/3/2009 9:00:00 PM 3.930907444 3.461467531 Normal 

## 0.880577 no ARDomtarIn dustries PB1 8/24/2009 8.722371552 7.681262072 Normal 

## 0.880639 no VAPhilipMorr isPark500 B3 10/5/2009 2.727977502 2.406280198 Normal 

## 0.882075 no VAPhilipMorr isPark500 B3 10/3/2009 2:00:00 PM 2.662872785 2.348852968 Normal 

## 0.882075 no VAPhilipMorr isPark500 B3 10/4/2009 5:00:00 AM 4.115388419 3.636050926 Normal 

## 0.883526 no VAPhilipMorr isPark500 B3 10/5/2009 8:00:00 AM 4.186727071 3.69908045 Normal 

## 0.883526 no VAPhilipMorr isPark500 B3 10/4/2009 5:00:00 PM 4.156918099 3.672743461 Normal 

## 0.883526 no VAPhilipMorr isPark500 B3 10/5/2009 9:00:00 AM 4.156918099 3.672743461 Normal 

## 0.883526 no WABoeingR enton BOIL04 09/20/09 05:00 13.08431131 11.57793394 normal 

## 0.884871 no VAPhilipMorr isPark500 B3 10/4/2009 2:00:00 AM 2.809361978 2.489924175 Normal 

## 0.886295 no VAPhilipMorr isPark500 B3 10/4/2009 9:00:00 PM 2.837677287 2.515019898 Normal 

## 0.886295 no VAPhilipMorr isPark500 B3 10/6/2009 2:00:00 AM 2.837677287 2.515019898 Normal 

## 0.886295 no VAPhilipMorr isPark500 B3 10/3/2009 7:00:00 PM 2.770262542 2.455270531 Normal 

## 0.886295 no VAPhilipMorr isPark500 B3 10/2/2009 1:00:00 PM 2.891717693 2.574058765 Normal 

## 0.890149 no VAPhilipMorr isPark500 B3 10/3/2009 5:00:00 PM 2.896183567 2.578034057 Normal 

## 0.890149 no VAPhilipMorr isPark500 B3 10/2/2009 3:00:00 PM 3.017444549 2.696632992 Normal 

## 0.893681 no

VAPhilipMorr isPark500 B3 10/4/2009 11:00:00 PM 3.095647949 2.766521888 Normal 

## 0.893681 no VAPhilipMorr isPark500 B3 10/5/2009 4:00:00 AM 3.140045303 2.806198962 Normal 

## 0.893681 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 2000-2100 8.105866838 7.244245433 

## 0.893704 no WABoeingR enton BOIL04 08/17/09 16:00 1.614876347 1.4458619 normal 

## 0.895339 no WABoeingR enton BOIL04 08/13/09 20:00 1.352050717 1.210981257 normal 

## 0.895663 no

VAPhilipMorr isPark500 B3 10/3/2009 11:00:00 PM 3.170086648 2.843348329 Normal 

## 0.896931 no VAPhilipMorr isPark500 B3 10/6/2009 7:00:00 AM 3.201996636 2.87196938 Normal 

## 0.896931 no VAPhilipMorr isPark500 B3 10/5/2009 2:00:00 PM 3.247592265 2.912865503 Normal 

## 0.896931 no VAPhilipMorr isPark500 B3 10/5/2009 4:00:00 PM 3.247592265 2.912865503 Normal 

## 0.896931 no

VAPhilipMorr isPark500 B3 10/3/2009 12:00:00 PM 3.192456793 2.863412801 Normal 

## 0.896931 no

VAPhilipMorr isPark500 B3 10/4/2009 12:00:00 PM 3.22463328 2.892272883 Normal 

## 0.896931 no

VAPhilipMorr isPark500 B3 10/4/2009 10:00:00 AM 3.306862614 2.975946727 Normal 

## 0.899931 no

VAPhilipMorr isPark500 B3 10/3/2009 10:00:00 AM 3.34375309 3.009145594 Normal 

## 0.899931 no

VAPhilipMorr isPark500 B3 10/5/2009 11:00:00 PM 3.353618611 3.018023878 Normal 

## 0.899931 no VAPhilipMorr isPark500 B3 10/6/2009 6:00:00 AM 3.353618611 3.018023878 Normal 

## 0.899931 no VAPhilipMorr isPark500 B3 10/4/2009 3:00:00 PM 3.377495955 3.03951183 Normal 

## 0.899931 no

CATesoro S-974 Furance 55 9/20/2009 0.154236414 0.138802063 None 08:31-09:10 08:31-09:10 

## 0.899931 no

CATesoro S-974 Furance 55 9/22/2009 0.155056493 0.139540077 None 08:35-09:02 08:35-09:02 

## 0.899931 no VAPhilipMorr isPark500 B3 10/2/2009 4:00:00 PM 3.418473821 3.085884091 Normal 

## 0.902708 no

VAPhilipMorr isPark500 B3 10/6/2009 10:00:00 AM 3.545262382 3.200337155 Normal 

## 0.902708 no

CATesoro S-974 Furance 55 9/2/2009 1.286409312 1.162104432 None 14:28-15:42 14:28-15:42 

## 0.903371 no WABoeingR enton BOIL04 09/20/09 03:00 12.53147631 11.33506098 normal 

## 0.904527 no VAPhilipMorr isPark500 B3 10/2/2009 5:00:00 PM 3.520351974 3.1869299 Normal 

## 0.905287 no VAPhilipMorr isPark500 B3 10/4/2009 8:00:00 AM 3.600964867 3.259907727 Normal 

## 0.905287 no VAPhilipMorr isPark500 B3 10/5/2009 7:00:00 AM 3.663386187 3.316416955 Normal 

## 0.905287 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier

VAPhilipMorr isPark500 B3 10/5/2009 10:00:00 AM 3.663386187 3.316416955 Normal 

## 0.905287 no

VAPhilipMorr isPark500 B3 10/6/2009 11:00:00 AM 3.676568396 3.328350641 Normal 

## 0.905287 no
WVDuPont Washington Works P05 9/24/2009 6:00:40 AM 0.634199034 0.575261835 

## 0.907068 no WABoeingR enton BOIL04 08/26/09 04:00 2.109226249 1.917105779 normal 

## 0.908914 no
WVDuPont Washington Works P05 9/23/2009 11:00:23 AM 0.294209913 0.267510915 

## 0.909252 no VAPhilipMorr isPark500 B3 10/5/2009 7:00:00 PM 3.897110718 3.546097135 Normal 

## 0.90993 no VAPhilipMorr isPark500 B3 10/3/2009 8:00:00 PM 3.804103978 3.461467531 Normal 

## 0.90993 no VAPhilipMorr isPark500 B3 10/4/2009 4:00:00 PM 3.869559936 3.521027858 Normal 

## 0.90993 no WABoeingR enton BOIL04 09/20/09 04:00 12.35519537 11.26760412 normal 

## 0.911973 no VAPhilipMorr isPark500 B3 10/4/2009 7:00:00 AM 4.115388419 3.761431993 Normal 

## 0.913992 no VAPhilipMorr isPark500 B3 9/17/2009 2:00:00 PM 18.85313702 17.23161595 Normal 

## 0.913992 no

CATesoro S-974 Furance 55 9/3/2009 1.210820123 1.11169396 None 15:45-16:08 15:45-16:08 

## 0.918133 no VAPhilipMorr isPark500 B3 10/4/2009 2.282462387 2.101605287 Normal 

## 0.920762 no

CATesoro S-974 Furance 55 8/29/2009 1.665045755 1.534346721 None 12:49-13:18 12:49-13:18 

## 0.921504 no TXDibollTem ple-Inland PB-44 1000-1100 10.59253363 9.765497734 

## 0.921923 no WABoeingR enton BOIL04 08/15/09 07:00 0.615190989 0.567634672 normal 

## 0.922697 no WABoeingR enton BOIL04 08/25/09 19:00 1.481236244 1.369214967 normal 

## 0.924373 no WABoeingR enton BOIL04 08/25/09 17:00 1.705893536 1.577279529 normal 

## 0.924606 no WABoeingR enton BOIL04 08/22/09 16:00 0.650536987 0.601975915 normal 

## 0.925352 no WABoeingR enton BOIL04 08/26/09 22:00 3.024606742 2.799189057 normal 

## 0.925472 no VAPhilipMorr isPark500 B3 10/3/2009 1:00:00 PM 2.789676251 2.596100649 Normal 

## 0.93061 no WABoeingR enton BOIL04 09/19/09 23:00 11.85470134 11.04514406 normal 

## 0.93171 no WABoeingR enton BOIL04 08/25/09 18:00 1.736780595 1.618213892 normal 

## 0.931732 no VAPhilipMorr isPark500 B3 10/3/2009 3:00:00 PM 2.916479716 2.719724489 Normal 

## 0.932537 no VAPhilipMorr isPark500 B3 10/4/2009 1:00:00 PM 3.117688574 2.912865503 Normal 

## 0.934303 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier
TXDibollTem ple-Inland PB-44 1100-1200 15.36984221 14.36339692 

## 0.934518 no WABoeingR enton BOIL04 08/25/09 21:00 1.434716221 1.34535335 normal 

## 0.937714 no TXDibollTem ple-Inland PB-44 0200-0300 15.69414493 14.74321237 

## 0.939408 no

CATesoro S-974 Furance 55 8/25/2009 1.925786941 1.809224766 None 10:45-11:02 daily calibrations 10:45-11:02 daily calibrations 

## 0.939473 no WABoeingR enton BOIL04 09/19/09 22:00 11.48435716 10.79035043 normal 

## 0.939569 no VAPhilipMorr isPark500 B3 9/19/2009 3:00:00 AM 3.714791804 3.492298184 Normal 

## 0.940106 no WABoeingR enton BOIL04 09/19/09 05:00 13.43105776 12.64239023 normal 

## 0.94128 no WABoeingR enton BOIL04 09/20/09 00:00 11.38381303 10.72058824 normal 

## 0.94174 no WABoeingR enton BOIL04 09/20/09 02:00 11.62408979 10.95417748 normal 

## 0.942369 no

CATesoro S-974 Furance 55 9/1/2009 1.112403758 1.050262299 None 09:54-10:16 09:54-10:16 

## 0.944138 no WABoeingR enton BOIL04 09/18/09 21:00 13.5685138 12.83617834 normal 

## 0.946027 no WABoeingR enton BOIL04 09/19/09 04:00 13.19435038 12.48395403 normal 

## 0.946159 no

CATesoro S-974 Furance 55 9/8/2009 0.794988444 0.752588598 None 13:57-14:45 13:57-14:45 

## 0.946666 no WABoeingR enton BOIL04 08/25/09 22:00 1.623873808 1.540366838 normal 

## 0.948575 no WABoeingR enton BOIL04 09/20/09 01:00 11.30003151 10.75121849 normal 

## 0.951433 no WABoeingR enton BOIL04 08/16/09 04:00 0.943025785 0.897998289 normal 

## 0.952252 no WABoeingR enton BOIL04 09/19/09 18:00 11.10753241 10.58382343 normal 

## 0.952851 no WABoeingR enton BOIL04 08/14/09 18:00 0.988094947 0.941911171 normal 

## 0.95326 no WABoeingR enton BOIL04 09/18/09 20:00 13.40975584 12.82585987 normal 

## 0.956457 no TXDibollTem ple-Inland PB-44 0700-0800 5.175675932 4.95519539 

## 0.957401 no

CATesoro S-974 Furance 55 9/7/2009 0.659269142 0.631461717 None 09:00-09:33 09:00-09:33 

## 0.957821 no

CATesoro S-974 Furance 55 9/4/2009 0.698149809 0.669107214 None 13:40-14:06 13:40-14:06 

## 0.958401 no WABoeingR enton BOIL04 08/25/09 23:00 1.300275083 1.246184453 normal 

## 0.958401 no WABoeingR enton BOIL04 08/18/09 04:00 1.427248256 1.370052612 normal 

## 0.959926 no WABoeingR enton BOIL04 08/16/09 01:00 0.723275525 0.6944553 normal 

## 0.960153 no WABoeingR enton BOIL04 09/18/09 22:00 12.97987769 12.48979419 normal 

## 0.962243 no

CATesoro S-974 Furance 55 8/31/2009 0.954574468 0.91928905 None 13:44-14:13 13:44-14:13 

## 0.963035 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/13/09 17:00 0.933772037 0.899647405 normal 

## 0.963455 no WABoeingR enton BOIL04 09/19/09 21:00 10.77011198 10.38780357 normal 

## 0.964503 no WABoeingR enton BOIL04 09/18/09 18:00 13.2666462 12.82034483 normal 

## 0.966359 no WABoeingR enton BOIL04 08/15/09 17:00 0.624265837 0.60861223 normal 

## 0.974925 no WABoeingR enton BOIL04 08/17/09 19:00 1.359711597 1.325616522 normal 

## 0.974925 no

CATesoro S-974 Furance 55 9/16/2009 0.14389416 0.140285982 None 13:42-14:07 13:42-14:07 

## 0.974925 no

CATesoro S-974 Furance 55 9/23/2009 0.178200715 0.173732292 None 14:08-14:56 14:08-14:56 

## 0.974925 no WABoeingR enton BOIL04 08/22/09 05:00 0.021971107 0.021420176 normal 

## 0.974925 no WABoeingR enton BOIL04 08/22/09 22:00 0.032896248 0.032071367 normal 

## 0.974925 no WABoeingR enton BOIL04 08/22/09 20:00 0.04383488 0.042735711 normal 

## 0.974925 no WABoeingR enton BOIL04 08/20/09 04:00 0.109654161 0.106904558 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/20/2009 1:00:00 PM 0.131886448 0.128579366 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/19/09 23:00 0.175339521 0.170942843 normal 

## 0.974925 no WABoeingR enton BOIL04 08/21/09 21:00 0.17598431 0.171571464 normal 

## 0.974925 no WABoeingR enton BOIL04 08/23/09 09:00 0.17598431 0.171571464 normal 

## 0.974925 no WABoeingR enton BOIL04 08/19/09 14:00 0.252822492 0.246482911 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 9:00:00 AM 0.267538485 0.260829897 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 12:00 0.470937386 0.459128524 normal 

## 0.974925 no WABoeingR enton BOIL04 08/14/09 19:00 0.503179325 0.49056199 normal 

## 0.974925 no WABoeingR enton BOIL04 08/14/09 21:00 0.514745514 0.501838155 normal 

## 0.974925 no WABoeingR enton BOIL04 08/14/09 23:00 0.515374557 0.502451424 normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 18:00 0.634830446 0.61891193 normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 11/1/2009 12:00:00 PM 0.741815476 0.723214286 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/16/09 02:00 0.746560626 0.72784045 normal 

## 0.974925 no WABoeingR enton BOIL04 08/16/09 16:00 0.831846792 0.810988046 normal 

## 0.974925 no WABoeingR enton BOIL04 08/16/09 17:00 0.832862726 0.811978505 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/19/2009 5:00:00 PM 0.919906707 0.896839839 Normal 

## 0.974925 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 10/3/2009 4:00:00 PM 2.014736395 1.964216425 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 2:00:00 AM 2.140307879 2.086639176 Normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 9/17/2009 10:00:00 PM 2.39053342 2.330590255 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 2.39053342 2.330590255 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 1:00:00 AM 2.39053342 2.330590255 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/19/2009 6:00:00 AM 2.788000382 2.718090643 Normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 9/19/2009 11:00:00 AM 3.199503179 3.119274915 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/19/2009 2:00:00 AM 3.582120668 3.492298184 Normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 9/19/2009 12:00:00 PM 3.970714158 3.871147604 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 4:00:00 PM 4.280615759 4.173278353 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 5:00:00 PM 4.648259428 4.531703274 Normal 

## 0.974925 no TXDibollTem ple-Inland PB-44 1900-2000 2.833279063 2.762233952 

## 0.974925 no TXDibollTem ple-Inland PB-44 1000-1100 3.586679246 3.496742454 

## 0.974925 no

CATesoro S-974 Furance 55 9/5/2009 0.726463829 0.708247584 None 04:42-13:59, 14:00-14:35 04:42-13:59, 14:00-14:35 

## 0.974925 no

CATesoro S-974 Furance 55 8/26/2009 1.334494604 1.30103185 None 08:33-09:09 08:33-09:09 

## 0.974925 no

CATesoro S-974 Furance 55 9/19/2009 0.13190298 0.128595483 None 12:08-12:26 12:08-12:26 

## 0.974925 no

CATesoro S-974 Furance 55 8/30/2009 0.39812345 0.388140415 None 13:11-13:30 13:11-13:30 

## 0.974925 no

CATesoro S-974 Furance 55 9/13/2009 0.011566125 0.011276102 None 14:04-14:53 14:04-14:53 

## 0.974925 no WABoeingR enton BOIL04 08/19/09 19:00 0.010952032 0.010677408 normal 

## 0.974925 no WABoeingR enton BOIL04 08/22/09 18:00 0.03287616 0.032051783 normal 

## 0.974925 no WABoeingR enton BOIL04 08/23/09 00:00 0.06575232 0.064103566 normal 

## 0.974925 no WABoeingR enton BOIL04 08/22/09 04:00 0.076945976 0.075016538 normal 

## 0.974925 no WABoeingR enton BOIL04 08/23/09 04:00 0.076945976 0.075016538 normal 

## 0.974925 no WABoeingR enton BOIL04 08/19/09 04:00 0.087776963 0.085575935 normal 

## 0.974925 no WABoeingR enton BOIL04 08/19/09 22:00 0.098688745 0.096214102 normal 

## 0.974925 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 9/19/2009 8:00:00 AM 0.132761923 0.129432888 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/20/2009 9:00:00 AM 0.133408961 0.130063701 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/20/2009 2:00:00 AM 0.134282022 0.13091487 Normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 11/3/2009 11:00:00 AM 0.261487621 0.25493076 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/20/09 05:00 0.307031651 0.299332763 normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 13:00 0.307219369 0.299515774 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/19/2009 7:00:00 AM 0.398285769 0.388298663 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 11/1/2009 1:00:00 AM 0.432572714 0.421725856 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 10/31/2009 8:00:00 PM 0.439637433 0.428613425 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 02:00 0.482773294 0.470667645 normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 00:00 0.503486216 0.490861186 normal 

## 0.974925 no WABoeingR enton BOIL04 08/14/09 22:00 0.526018564 0.51282853 normal 

## 0.974925 no WABoeingR enton BOIL04 08/16/09 13:00 0.536977284 0.523512457 normal 

## 0.974925 no WABoeingR enton BOIL04 08/14/09 20:00 0.547601611 0.533870377 normal 

## 0.974925 no WABoeingR enton BOIL04 08/19/09 17:00 0.549950968 0.536160824 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 10/31/2009 3:00:00 PM 0.572166428 0.557819225 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 16:00 0.602729604 0.587616023 normal 

## 0.974925 no WABoeingR enton BOIL04 09/27/09 19:00 0.604097139 0.588949267 normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 21:00 0.613313804 0.597934822 normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 20:00 0.635217869 0.619289637 normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 22:00 0.635217869 0.619289637 normal 

## 0.974925 no WABoeingR enton BOIL04 08/16/09 19:00 0.733338619 0.714949988 normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 11/1/2009 11:00:00 AM 0.735733027 0.717284356 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/16/09 20:00 0.777594288 0.758095936 normal 

## 0.974925 no WABoeingR enton BOIL04 08/16/09 14:00 0.854780166 0.833346361 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 10/31/2009 8:00:00 AM 0.890178571 0.867857143 Normal 

## 0.974925 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 11/1/2009 1:00:00 PM 0.890178571 0.867857143 Normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 9/20/2009 10:00:00 AM 0.923205136 0.900055559 Normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 9/19/2009 10:00:00 AM 1.074256177 1.047318961 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/17/09 20:00 1.225879483 1.195140278 normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 9/18/2009 11:00:00 PM 1.335390069 1.301904862 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/19/2009 1.856760358 1.810201673 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 8:00:00 AM 2.006538637 1.956224228 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/21/2009 6:00:00 AM 2.316277069 2.258195898 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/26/09 20:00 2.547230377 2.483358001 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 10/4/2009 1:00:00 AM 2.553965435 2.489924175 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/26/09 19:00 2.618898212 2.553228749 normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 9/20/2009 11:00:00 AM 2.657096028 2.590468745 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 5:00:00 AM 2.942923334 2.869128868 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 6:00:00 AM 2.942923334 2.869128868 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/17/2009 8:00:00 PM 3.534963191 3.446323191 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/17/2009 7:00:00 PM 3.560198884 3.470926093 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 3:00:00 PM 3.611769547 3.52120361 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/17/2009 6:00:00 PM 4.219494973 4.113690184 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/21/2009 5:00:00 AM 5.589641809 5.44948028 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/21/2009 4:00:00 AM 6.939406829 6.765399637 Normal 

## 0.974925 no

CATesoro S-974 Furance 55 9/14/2009 0.081277174 0.07923913 None 14:14-14:35 14:14-14:35 

## 0.974925 no

CATesoro S-974 Furance 55 9/17/2009 0.142184075 0.138618777 None 18:35-18:59 18:35-18:59 

## 0.974925 no WABoeingR enton BOIL04 08/23/09 03:00 0.021957665 0.021407072 normal 

## 0.974925 no WABoeingR enton BOIL04 08/21/09 19:00 0.032976847 0.032149945 normal 

## 0.974925 no WABoeingR enton BOIL04 08/23/09 02:00 0.032997058 0.032169649 normal 

## 0.974925 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/23/09 05:00 0.099112666 0.096627393 normal 

## 0.974925 no WABoeingR enton BOIL04 08/23/09 06:00 0.132231364 0.128915633 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/20/2009 4:00:00 AM 0.132452091 0.129130825 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/19/09 21:00 0.142463361 0.13889106 normal 

## 0.974925 no WABoeingR enton BOIL04 08/22/09 17:00 0.242126824 0.23605544 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 11/2/2009 9:00:00 PM 0.254113089 0.247741146 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/19/2009 6:00:00 PM 0.262830488 0.256239954 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 11/3/2009 2:00:00 PM 0.263398525 0.256793747 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 11/3/2009 3:00:00 PM 0.263398525 0.256793747 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 11/3/2009 4:00:00 PM 0.263398525 0.256793747 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/21/2009 2:00:00 AM 0.265260105 0.258608648 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 11/2/2009 6:00:00 AM 0.284947602 0.277802477 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/19/09 13:00 0.285275128 0.27812179 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 8:00:00 PM 0.400617021 0.390571459 Normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 9/18/2009 10:00:00 PM 0.400617021 0.390571459 Normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 9/18/2009 10:00:00 AM 0.401307727 0.391244846 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 05:00 0.449856933 0.438576669 normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 11:00 0.482478309 0.470380056 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/20/2009 7:00:00 AM 0.529808363 0.516523299 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 03:00 0.537305389 0.523832335 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 10/31/2009 4:00:00 PM 0.567641942 0.553408192 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 10/31/2009 5:00:00 PM 0.567641942 0.553408192 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 10/31/2009 6:00:00 PM 0.567641942 0.553408192 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 10/31/2009 7:00:00 PM 0.567641942 0.553408192 Normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 10/31/2009 11:00:00 AM 0.576763619 0.562301141 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 04:00 0.581878135 0.56728741 normal 

## 0.974925 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/15/09 19:00 0.591049036 0.576228348 normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 10:00 0.593583241 0.578699008 normal 

## 0.974925 no WABoeingR enton BOIL04 08/16/09 00:00 0.625028718 0.609355982 normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 15:00 0.635605765 0.619667807 normal 

## 0.974925 no WABoeingR enton BOIL04 08/16/09 21:00 0.723717463 0.705570084 normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 10/31/2009 10:00:00 AM 0.726794103 0.708569577 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/16/09 23:00 0.745192965 0.726507084 normal 

## 0.974925 no WABoeingR enton BOIL04 08/16/09 22:00 0.767579127 0.748331908 normal 

## 0.974925 no WABoeingR enton BOIL04 08/12/09 19:00 0.810945286 0.79061065 normal 

## 0.974925 no WABoeingR enton BOIL04 08/12/09 20:00 0.819901316 0.799342105 normal 

## 0.974925 no WABoeingR enton BOIL04 08/16/09 15:00 0.853217116 0.831822504 normal 

## 0.974925 no WABoeingR enton BOIL04 08/13/09 18:00 0.975922033 0.951450568 normal 

## 0.974925 no WABoeingR enton BOIL04 08/17/09 23:00 1.304884517 1.272164243 normal 

## 0.974925 no WABoeingR enton BOIL04 08/17/09 17:00 1.315046409 1.282071324 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 10/31/2009 6:00:00 AM 1.404958246 1.369728601 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/19/2009 4:00:00 PM 1.576982927 1.537439724 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 7:00:00 PM 1.602468083 1.562285834 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/20/2009 6:00:00 AM 1.85432927 1.807831545 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 7:00:00 AM 1.872769395 1.825809279 Normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 9/20/2009 12:00:00 PM 1.94987505 1.900981493 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/19/2009 1:00:00 AM 2.254637578 2.198102032 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/17/2009 4:00:00 PM 2.618491252 2.552831993 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/19/2009 3:00:00 PM 2.759720122 2.690519517 Normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 9/17/2009 11:00:00 PM 2.788955657 2.719021964 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 6:00:00 PM 2.788955657 2.719021964 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 3:00:00 AM 2.809154092 2.738713919 Normal 

## 0.974925 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier VAPhilipMorr isPark500 B3 9/18/2009 2:00:00 PM 3.320185306 3.23693091 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/19/2009 5:00:00 AM 3.475603897 3.388452345 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/19/2009 4:00:00 AM 3.821320164 3.725499698 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/21/2009 3:00:00 AM 4.320762742 4.212418642 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/19/2009 1:00:00 PM 4.468118293 4.356079218 Normal 

## 0.974925 no TXDibollTem ple-Inland PB-44 0800-0900 4.16284458 4.058460312 

## 0.974925 no TXDibollTem ple-Inland PB-44 0900-1000 4.695807328 4.5780589 

## 0.974925 no

CATesoro S-974 Furance 55 9/11/2009 0.012128954 0.011824818 None 14:10-15:16 14:10-15:16 

## 0.974925 no WABoeingR enton BOIL04 08/22/09 19:00 0.065712193 0.064064445 normal 

## 0.974925 no WABoeingR enton BOIL04 08/21/09 20:00 0.06591332 0.064260529 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/21/2009 7:00:00 AM 0.12999167 0.1267321 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 11/3/2009 1:00:00 PM 0.13266888 0.129342178 Normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 11/3/2009 12:00:00 PM 0.26533776 0.258684356 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 01:00 0.516005139 0.503066194 normal 

## 0.974925 no WABoeingR enton BOIL04 08/16/09 03:00 0.59213247 0.577284614 normal 

## 0.974925 no WABoeingR enton BOIL04 08/15/09 23:00 0.690399365 0.673087445 normal 

## 0.974925 no WABoeingR enton BOIL04 08/16/09 18:00 0.83032753 0.809506879 normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 9/18/2009 11:00:00 AM 1.337692425 1.304149485 Normal 

## 0.974925 no WABoeingR enton BOIL04 08/25/09 20:00 1.367335121 1.333048885 normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/20/2009 5:00:00 AM 2.384137633 2.324354844 Normal 

## 0.974925 no

VAPhilipMorr isPark500 B3 9/18/2009 12:00:00 PM 2.541615607 2.477884022 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 4:00:00 AM 2.675384849 2.60829897 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/18/2009 1:00:00 PM 2.675384849 2.60829897 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/17/2009 9:00:00 PM 3.032762012 2.95671482 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/19/2009 2:00:00 PM 4.336703049 4.227959241 Normal 

## 0.974925 no VAPhilipMorr isPark500 B3 9/17/2009 1:00:00 PM 5.142509499 5.013559912 Normal 

## 0.974925 no

# Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC (ppm@3%O2) CombUnit_O p_Indicator THC_Op_Ind icator CO_Op_Indi cator 

## TNMOC TO THC Ratio Outlier WABoeingR enton BOIL04 08/23/09 10:00 0.131988232 0.128678598 normal 

## 0.974925 no

CATesoro S-974 Furance 55 9/6/2009 0.845962805 0.836048043 None 09:44-10:13 09:44-10:13 

## 0.98828 no

CATesoro S-974 Furance 55 9/9/2009 0.606520213 0.602682959 None 10:50-11:44 10:50-11:44 

## 0.993673 no

# Appendix D-4: Development of Average VOC Content in THC

1st Quartile 3rd Quartile IQR 1.5 IqR Test for Low Test for High Outliers

0.313908332 0.76605016 0.45214183 0.67821274 0.1010117 1.28559514

Number of Ratios 2509

Sum of Ratios 1440.09171

Average of Ratio Data that are not outliers: 57% Sample Statistics of TNMOC to THC Averages

### Appendix D-5a: Fuel IQR Analysis for Hg From Heavy Liquid Fuels

FacilityID Fuel Pollutant Fuel Concentration

(lb/MMBtu) Outlier?

OKIPValliant No. 6 Residual oil Mercury (Hg) 1.13E-07 yes Fuel Category 1st Quartile 3rd Quartile IQR 1.5 * IQR Low Outlier Cutoff High Outlier Cutoff MEVersoPap erAndroscog gin No. 6 Residual oil Mercury (Hg) 1.51E-07 yes Heavy Liquid 3.50E-07 1.65E-06 1.30E-06 1.94E-06 3.50E-07 1.65E-06 MEVersoPap erAndroscog gin No. 6 Residual oil Mercury (Hg) 1.89E-07 yes

MEVersoPap erAndroscog gin No. 6 Residual oil Mercury (Hg) 2.22E-07 yes Average Including Outliers (lb/MMBtu) Average Excluding Outliers (lb/MMBtu)

MEVersoPap erAndroscog gin UsedPetroleumbased Oils (on-spec) Mercury (Hg) 2.23E-07 yes 5.42E-06 1.04E-06

MEVersoPap erAndroscog gin UsedPetroleumbased Oils (on-spec) Mercury (Hg) 2.44E-07 yes

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 2.70E-07 yes

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 2.71E-07 yes

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 2.71E-07 yes

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 2.71E-07 yes

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 2.71E-07 yes

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 2.71E-07 yes

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 2.72E-07 yes

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 2.72E-07 yes NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 2.74E-07 yes NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 2.74E-07 yes NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 2.75E-07 yes

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 3.24E-07 yes

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 3.27E-07 yes

MEVersoPap erAndroscog gin UsedPetroleumbased Oils (on-spec) Mercury (Hg) 3.58E-07 no

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 3.80E-07 no

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 3.80E-07 no

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 4.86E-07 no

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 6.52E-07 no NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 7.39E-07 no NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 7.65E-07 no

Page 217 of 233

### Appendix D-5a: Fuel IQR Analysis for Hg From Heavy Liquid Fuels

FacilityID Fuel Pollutant Fuel Concentration

(lb/MMBtu) Outlier?

MESDWarre nSomerset No. 6 Residual oil Mercury (Hg) 8.12E-07 no NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 8.13E-07 no NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 8.67E-07 no NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 8.67E-07 no NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 8.67E-07 no NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 8.67E-07 no NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 9.68E-07 no

MESDWarre nSomerset UsedPetroleumbased Oils (on-spec) and No. 6 Residual oil Mercury (Hg) 1.08E-06 no

MESDWarre nSomerset UsedPetroleumbased Oils (on-spec) and No. 6 Residual oil Mercury (Hg) 1.08E-06 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Mercury (Hg) 1.09E-06 no

MESDWarre nSomerset UsedPetroleumbased Oils (on-spec) and No. 6 Residual oil Mercury (Hg) 1.09E-06 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Mercury (Hg) 1.09E-06 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Mercury (Hg) 1.09E-06 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Mercury (Hg) 1.09E-06 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Mercury (Hg) 1.09E-06 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Mercury (Hg) 1.09E-06 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Mercury (Hg) 1.09E-06 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Mercury (Hg) 1.10E-06 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Mercury (Hg) 1.10E-06 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Mercury (Hg) 1.11E-06 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Mercury (Hg) 1.11E-06 no

Page 218 of 233

### Appendix D-5a: Fuel IQR Analysis for Hg From Heavy Liquid Fuels

FacilityID Fuel Pollutant Fuel Concentration

(lb/MMBtu) Outlier?

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Mercury (Hg) 1.11E-06 no NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 1.20E-06 no NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 1.22E-06 no NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 1.29E-06 no NYConEd59t hStStationNe wYork No. 6 Residual oil Mercury (Hg) 1.54E-06 no NYConEd59t hStStationNe wYork No. 6 Residual oil Mercury (Hg) 1.54E-06 no NYConEd59t hStStationNe wYork No. 6 Residual oil Mercury (Hg) 1.54E-06 no NYConEd59t hStStationNe wYork No. 6 Residual oil Mercury (Hg) 1.54E-06 no NYConEd59t hStStationNe wYork No. 6 Residual oil Mercury (Hg) 1.64E-06 no NYConEd59t hStStationNe wYork No. 6 Residual oil Mercury (Hg) 1.65E-06 no NYConEd59t hStStationNe wYork No. 6 Residual oil Mercury (Hg) 1.65E-06 yes NYConEd59t hStStationNe wYork No. 6 Residual oil Mercury (Hg) 1.70E-06 yes NYConEd59t hStStationNe wYork No. 6 Residual oil Mercury (Hg) 1.70E-06 yes NYConEd59t hStStationNe wYork No. 6 Residual oil Mercury (Hg) 1.70E-06 yes NYConEd59t hStStationNe wYork No. 6 Residual oil Mercury (Hg) 1.75E-06 yes NYConEd59t hStStationNe wYork No. 6 Residual oil Mercury (Hg) 1.75E-06 yes NCInvistaHw y421 No. 6 Residual oil Mercury (Hg) 1.82E-06 yes MEFPLEner gyWyman No. 6 Residual oil Mercury (Hg) 2.01E-05 yes MEFPLEner gyWyman No. 6 Residual oil Mercury (Hg) 2.16E-05 yes MEFPLEner gyWyman No. 6 Residual oil Mercury (Hg) 2.22E-05 yes MEFPLEner gyWyman No. 6 Residual oil Mercury (Hg) 2.32E-05 yes MEFPLEner gyWyman No. 6 Residual oil Mercury (Hg) 2.35E-05 yes MEFPLEner gyWyman No. 6 Residual oil Mercury (Hg) 2.51E-05 yes MEFPLEner gyWyman No. 6 Residual oil Mercury (Hg) 2.66E-05 yes MEFPLEner gyWyman No. 6 Residual oil Mercury (Hg) 2.67E-05 yes MEFPLEner gyWyman No. 6 Residual oil Mercury (Hg) 3.54E-05 yes MEFPLEner gyWyman No. 6 Residual oil Mercury (Hg) 4.07E-05 yes MEFPLEner gyWyman No. 6 Residual oil Mercury (Hg) 4.13E-05 yes MEFPLEner gyWyman No. 6 Residual oil Mercury (Hg) 4.89E-05 yes

Page 219 of 233

### Appendix D-5b: Fuel IQR Analysis for Hg From Light Liquid Fuels

FacilityID Fuel Pollutant Fuel Concentration

(lb/MMBtu) Outlier?

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 2.55E-07 yes Fuel Category 1st Quartile 3rd Quartile IQR 1.5 * IQR Low Outlier Cutoff High Outlier Cutoff

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 2.56E-07 yes Light Liquid 3.41E-07 5.21E-06 4.87E-06 7.30E-06 3.41E-07 5.21E-06

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 2.56E-07 yes

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 2.56E-07 yes Average Including Outliers (lb/MMBtu) Average Excluding Outliers (lb/MMBtu)

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 2.56E-07 yes 1.23E-05 2.53E-06

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 2.56E-07 yes

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 2.56E-07 yes

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 2.56E-07 yes

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 2.57E-07 yes

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 2.57E-07 yes

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 3.07E-07 yes

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 3.07E-07 yes

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 3.10E-07 yes CTElectric Boat No. 4 Fuel oil Mercury (Hg) 4.36E-07 no

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 4.60E-07 no

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 4.62E-07 no

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 6.14E-07 no

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 1.01E-06 no

MESDWarre nSomerset No. 2 Distillate Mercury (Hg) 1.03E-06 no TNMilanArm yAmmunition Plant No. 2 Distillate Mercury (Hg) 2.09E-06 no TNMilanArm yAmmunition Plant No. 2 Distillate Mercury (Hg) 2.09E-06 no TNMilanArm yAmmunition Plant No. 2 Distillate Mercury (Hg) 2.10E-06 no TNMilanArm yAmmunition Plant No. 2 Distillate Mercury (Hg) 2.10E-06 no TNMilanArm yAmmunition Plant No. 2 Distillate Mercury (Hg) 2.13E-06 no TNMilanArm yAmmunition Plant No. 2 Distillate Mercury (Hg) 2.15E-06 no TNMilanArm yAmmunition Plant No. 2 Distillate Mercury (Hg) 2.16E-06 no

Page 220 of 233

### Appendix D-5b: Fuel IQR Analysis for Hg From Light Liquid Fuels

FacilityID Fuel Pollutant Fuel Concentration

(lb/MMBtu) Outlier? TNMilanArm yAmmunition Plant No. 2 Distillate Mercury (Hg) 2.16E-06 no TNMilanArm yAmmunition Plant No. 2 Distillate Mercury (Hg) 2.17E-06 no TNMilanArm yAmmunition Plant No. 2 Distillate Mercury (Hg) 2.19E-06 no TNMilanArm yAmmunition Plant No. 2 Distillate Mercury (Hg) 2.23E-06 no TNMilanArm yAmmunition Plant No. 2 Distillate Mercury (Hg) 2.25E-06 no SC3VGeorg etown No. 2 Distillate Mercury (Hg) 5.10E-06 no TNInvistaCh attanooga No. 2 Distillate Mercury (Hg) 5.14E-06 no TNInvistaCh attanooga No. 2 Distillate Mercury (Hg) 5.16E-06 no TNInvistaCh attanooga No. 2 Distillate Mercury (Hg) 5.17E-06 no NCMCASCh erryPoint No. 2 Distillate Mercury (Hg) 5.19E-06 no NCMCASCh erryPoint No. 2 Distillate Mercury (Hg) 5.20E-06 no NCCampLej euneMCB Jet Fuel Mercury (Hg) 5.21E-06 yes NCMCASCh erryPoint No. 2 Distillate Mercury (Hg) 5.22E-06 yes SCGPChem Russellville Diesel fuel Mercury (Hg) 4.06E-05 yes SCGPChem Russellville Diesel fuel Mercury (Hg) 4.57E-05 yes SCGPChem Russellville Diesel fuel Mercury (Hg) 4.59E-05 yes SCGPChem Russellville Diesel fuel Mercury (Hg) 5.08E-05 yes SCGPChem Russellville Diesel fuel Mercury (Hg) 5.08E-05 yes SCGPChem Russellville Diesel fuel Mercury (Hg) 5.08E-05 yes SCGPChem Russellville Diesel fuel Mercury (Hg) 5.08E-05 yes SCGPChem Russellville Diesel fuel Mercury (Hg) 5.08E-05 yes SCGPChem Russellville Diesel fuel Mercury (Hg) 5.08E-05 yes SCGPChem Russellville Diesel fuel Mercury (Hg) 5.10E-05 yes SCGPChem Russellville Diesel fuel Mercury (Hg) 5.10E-05 yes

Page 221 of 233

### Appendix D-5c: Fuel IQR Analysis for HCl From Heavy Liquid Fuels

FacilityID Fuel Pollutant Fuel Concentration

(lb/MMBtu) Outlier?

MEVersoPap

er No. 6 Residual oil Hydrogen Chloride (HCl) 8.25E-05 yes Fuel Category 1st Quartile 3rd Quartile IQR 1.5 * IQR Low Outlier Cutoff High Outlier Cutoff

MEVersoPap

er No. 6 Residual oil Hydrogen Chloride (HCl) 8.29E-05 yes Heavy Liquid 2.23E-03 1.67E-02 1.45E-02 2.18E-02 2.18E-03 1.71E-02

MEVersoPap

er No. 6 Residual oil Hydrogen Chloride (HCl) 8.29E-05 yes

MEVersoPap

er No. 6 Residual oil Hydrogen Chloride (HCl) 8.29E-05 yes Average Including Outliers (lb/MMBtu) Average Excluding Outliers (lb/MMBtu)

MEVersoPap

er No. 6 Residual oil Hydrogen Chloride (HCl) 8.34E-05 yes 7.98E-03 7.67E-03

MEVersoPap

er No. 6 Residual oil Hydrogen Chloride (HCl) 8.34E-05 yes

MEVersoPap

er No. 6 Residual oil Hydrogen Chloride (HCl) 8.34E-05 yes

MEVersoPap

er No. 6 Residual oil Hydrogen Chloride (HCl) 8.38E-05 yes

MEVersoPap

er No. 6 Residual oil Hydrogen Chloride (HCl) 8.38E-05 yes

MEVersoPap

er No. 6 Residual oil Hydrogen Chloride (HCl) 8.38E-05 yes

OKIPValliant No. 6 Residual oil Hydrogen Chloride (HCl) 2.90E-04 yes MEVersoPap erAndroscog gin No. 6 Residual oil Hydrogen Chloride (HCl) 8.89E-04 yes MEVersoPap erAndroscog gin No. 6 Residual oil Hydrogen Chloride (HCl) 1.06E-03 yes

MESDWarre nSomerset UsedPetroleumbased Oils (on-spec) and No. 6 Residual oil Hydrogen Chloride (HCl) 1.12E-03 yes MEVersoPap erAndroscog gin No. 6 Residual oil Hydrogen Chloride (HCl) 1.16E-03 yes

MEFPLEner gyWyman No. 6 Residual oil Hydrogen Chloride (HCl) 2.02E-03 yes

MESDWarre nSomerset UsedPetroleumbased Oils (on-spec) and No. 6 Residual oil Hydrogen Chloride (HCl) 2.22E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 2.23E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 2.23E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 2.23E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 2.23E-03 no

MESDWarre nSomerset UsedPetroleumbased Oils (on-spec) and No. 6 Residual oil Hydrogen Chloride (HCl) 2.23E-03 no

MEFPLEner gyWyman No. 6 Residual oil Hydrogen Chloride (HCl) 2.35E-03 no

Page 222 of 233

### Appendix D-5c: Fuel IQR Analysis for HCl From Heavy Liquid Fuels

FacilityID Fuel Pollutant Fuel Concentration

(lb/MMBtu) Outlier?

MEFPLEner gyWyman No. 6 Residual oil Hydrogen Chloride (HCl) 2.40E-03 no

MEFPLEner gyWyman No. 6 Residual oil Hydrogen Chloride (HCl) 2.40E-03 no

MEFPLEner gyWyman No. 6 Residual oil Hydrogen Chloride (HCl) 2.42E-03 no

MEFPLEner gyWyman No. 6 Residual oil Hydrogen Chloride (HCl) 2.62E-03 no

MEFPLEner gyWyman No. 6 Residual oil Hydrogen Chloride (HCl) 2.80E-03 no

ALGPBrewto nMill No. 6 Residual oil Hydrogen Chloride (HCl) 2.92E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 3.37E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 3.38E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 3.38E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 3.38E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 3.39E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 3.39E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 3.39E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 3.39E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 3.40E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 3.40E-03 no

MEFPLEner gyWyman No. 6 Residual oil Hydrogen Chloride (HCl) 3.41E-03 no

NCInvistaHw y421 No. 6 Residual oil Hydrogen Chloride (HCl) 3.41E-03 no

ALGPBrewto nMill No. 6 Residual oil Hydrogen Chloride (HCl) 3.48E-03 no

MEFPLEner gyWyman No. 6 Residual oil Hydrogen Chloride (HCl) 4.03E-03 no

ALGPBrewto nMill No. 6 Residual oil Hydrogen Chloride (HCl) 4.11E-03 no

MEFPLEner gyWyman No. 6 Residual oil Hydrogen Chloride (HCl) 5.39E-03 no

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 5.55E-03 no

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 5.55E-03 no

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 5.56E-03 no

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 5.58E-03 no

Page 223 of 233

### Appendix D-5c: Fuel IQR Analysis for HCl From Heavy Liquid Fuels

FacilityID Fuel Pollutant Fuel Concentration

(lb/MMBtu) Outlier?

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 5.58E-03 no

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 5.58E-03 no

MEFPLEner gyWyman No. 6 Residual oil Hydrogen Chloride (HCl) 5.72E-03 no

MEFPLEner gyWyman No. 6 Residual oil Hydrogen Chloride (HCl) 7.30E-03 no

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 1.11E-02 no

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 1.11E-02 no

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 1.12E-02 no

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 1.67E-02 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Hydrogen Chloride (HCl) 1.67E-02 no

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 1.67E-02 no

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 1.68E-02 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Hydrogen Chloride (HCl) 1.68E-02 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Hydrogen Chloride (HCl) 1.68E-02 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Hydrogen Chloride (HCl) 1.68E-02 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Hydrogen Chloride (HCl) 1.68E-02 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Hydrogen Chloride (HCl) 1.69E-02 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Hydrogen Chloride (HCl) 1.69E-02 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Hydrogen Chloride (HCl) 1.69E-02 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Hydrogen Chloride (HCl) 1.69E-02 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Hydrogen Chloride (HCl) 1.70E-02 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Hydrogen Chloride (HCl) 1.71E-02 no

VANewportN ewsShipbuild ingDryDock No. 6 Residual oil Hydrogen Chloride (HCl) 1.71E-02 no

Page 224 of 233

### Appendix D-5c: Fuel IQR Analysis for HCl From Heavy Liquid Fuels

FacilityID Fuel Pollutant Fuel Concentration

(lb/MMBtu) Outlier?

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 2.23E-02 yes

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 2.23E-02 yes

MESDWarre nSomerset No. 6 Residual oil Hydrogen Chloride (HCl) 2.79E-02 yes

MEVersoPap erAndroscog gin UsedPetroleumbased Oils (on-spec) Hydrogen Chloride (HCl) 3.73E-02 yes

MEVersoPap erAndroscog gin UsedPetroleumbased Oils (on-spec) Hydrogen Chloride (HCl) 3.73E-02 yes

MEVersoPap erAndroscog gin UsedPetroleumbased Oils (on-spec) Hydrogen Chloride (HCl) 3.84E-02 yes

Page 225 of 233

### Appendix D-5d: Fuel IQR Analysis for HCl From Light Liquid Fuels

FacilityID Fuel Pollutant Fuel Concentration

(lb/MMBtu) Outlier?

TNInvistaCh attanooga No. 2 Distillate Hydrogen Chloride (HCl) 5.34E-07 yes Fuel Category 1st Quartile 3rd Quartile IQR 1.5 * IQR Low Outlier Cutoff High Outlier Cutoff

TNInvistaCh attanooga No. 2 Distillate Hydrogen Chloride (HCl) 5.35E-07 yes Light Liquid 1.04E-03 5.27E-03 4.22E-03 6.33E-03 1.04E-03 5.30E-03

TNInvistaCh attanooga No. 2 Distillate Hydrogen Chloride (HCl) 5.37E-07 yes

CTElectric Boat No. 4 Fuel oil Hydrogen Chloride (HCl) 5.60E-07 yes Average Including Outliers (lb/MMBtu) Average Excluding Outliers (lb/MMBtu)

NCCampLej euneMCB No. 2 Distillate Hydrogen Chloride (HCl) 2.65E-04 yes 4.09E-03 2.89E-03

NCCampLej euneMCB No. 2 Distillate Hydrogen Chloride (HCl) 2.65E-04 yes

NCCampLej euneMCB No. 2 Distillate Hydrogen Chloride (HCl) 2.65E-04 yes

NCCampLej euneMCB No. 2 Distillate Hydrogen Chloride (HCl) 2.65E-04 yes

NCCampLej euneMCB No. 2 Distillate Hydrogen Chloride (HCl) 2.65E-04 yes

NCCampLej euneMCB No. 2 Distillate Hydrogen Chloride (HCl) 2.65E-04 yes

SCGPChem Russellville Diesel fuel Hydrogen Chloride (HCl) 9.91E-04 yes

SCGPChem Russellville Diesel fuel Hydrogen Chloride (HCl) 9.97E-04 yes

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 1.04E-03 no

SCGPChem Russellville Diesel fuel Hydrogen Chloride (HCl) 1.04E-03 no

SCGPChem Russellville Diesel fuel Hydrogen Chloride (HCl) 1.04E-03 no

SCGPChem Russellville Diesel fuel Hydrogen Chloride (HCl) 1.04E-03 no

SCGPChem Russellville Diesel fuel Hydrogen Chloride (HCl) 1.04E-03 no

SCGPChem Russellville Diesel fuel Hydrogen Chloride (HCl) 1.05E-03 no

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 1.06E-03 no TNMilanArm yAmmunition Plant No. 2 Distillate Hydrogen Chloride (HCl) 1.13E-03 no

NCMCASCh erryPoint No. 2 Distillate Hydrogen Chloride (HCl) 1.18E-03 no TNMilanArm yAmmunition Plant No. 2 Distillate Hydrogen Chloride (HCl) 1.21E-03 no TNMilanArm yAmmunition Plant No. 2 Distillate Hydrogen Chloride (HCl) 1.22E-03 no TNMilanArm yAmmunition Plant No. 2 Distillate Hydrogen Chloride (HCl) 1.26E-03 no

NCMCASCh erryPoint No. 2 Distillate Hydrogen Chloride (HCl) 1.29E-03 no TNMilanArm yAmmunition Plant No. 2 Distillate Hydrogen Chloride (HCl) 1.57E-03 no

Page 226 of 233

### Appendix D-5d: Fuel IQR Analysis for HCl From Light Liquid Fuels

FacilityID Fuel Pollutant Fuel Concentration

(lb/MMBtu) Outlier? TNMilanArm yAmmunition Plant No. 2 Distillate Hydrogen Chloride (HCl) 1.57E-03 no

SCGPChem Russellville Diesel fuel Hydrogen Chloride (HCl) 2.09E-03 no

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 2.12E-03 no

MINeenahPa perMI No. 2 Distillate Hydrogen Chloride (HCl) 2.15E-03 no TNMilanArm yAmmunition Plant No. 2 Distillate Hydrogen Chloride (HCl) 2.63E-03 no

ALGPBrewto nMill No. 2 Distillate Hydrogen Chloride (HCl) 2.67E-03 no

ALGPBrewto nMill No. 2 Distillate Hydrogen Chloride (HCl) 2.98E-03 no

MINeenahPa perMI No. 2 Distillate Hydrogen Chloride (HCl) 3.33E-03 no

TNInvistaCh attanooga No. 2 Distillate Hydrogen Chloride (HCl) 3.45E-03 no

TNInvistaCh attanooga No. 2 Distillate Hydrogen Chloride (HCl) 3.60E-03 no

NCMCASCh erryPoint No. 2 Distillate Hydrogen Chloride (HCl) 3.68E-03 no

ALGPBrewto nMill No. 2 Distillate Hydrogen Chloride (HCl) 3.95E-03 no

MINeenahPa perMI No. 2 Distillate Hydrogen Chloride (HCl) 4.08E-03 no

SCGPChem Russellville Diesel fuel Hydrogen Chloride (HCl) 4.88E-03 no

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 5.25E-03 no

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 5.26E-03 no

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 5.26E-03 no

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 5.26E-03 no

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 5.27E-03 no

SCGPChem Russellville Diesel fuel Hydrogen Chloride (HCl) 5.27E-03 no

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 5.27E-03 no

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 5.29E-03 no

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 5.29E-03 no

SCGPChem Russellville Diesel fuel Hydrogen Chloride (HCl) 5.43E-03 yes

SC3VGeorg etown No. 2 Distillate Hydrogen Chloride (HCl) 6.45E-03 yes

TNInvistaCh attanooga No. 2 Distillate Hydrogen Chloride (HCl) 8.50E-03 yes

Page 227 of 233

### Appendix D-5d: Fuel IQR Analysis for HCl From Light Liquid Fuels

FacilityID Fuel Pollutant Fuel Concentration

(lb/MMBtu) Outlier?

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 1.05E-02 yes

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 1.05E-02 yes

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 1.05E-02 yes

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 1.06E-02 yes

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 2.10E-02 yes

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 2.11E-02 yes

MESDWarre nSomerset No. 2 Distillate Hydrogen Chloride (HCl) 2.63E-02 yes

Page 228 of 233Appendix E-1: Area Source Baseline Emission Factors for Organic HAP and CO for Existing UnitsFuel Category Combustor Design NOx Control?Total # of Unitsin SubcategoryTHC(ppm @3% asPropane)THC # ofDataPointsTotalMassDioxins/Furans(ng/dscm@ 7% O2)TotalMassDioxins/Furans #of DataPointsCO (ppm@ 3% O2)CO # ofDataPointsFormaldehyde (ppm @ 3%O2)Formaldehyde# of DataPointsNOx (ppm@ 3% O2)NOx # ofDataPointsCoal Stoker/Sloped Grate/Other Yes 3,710 3.55 14 0.443 10 179.8 5 0.081 4 187.0 11Biomass Stoker/Sloped Grate/Other Yes 10,958 18.32 - 1.08 - 365.85 - 0.18 - 121.93 -Heavy Liquid - Yes 2,137 2.96 11 0.293 7 15.1 13 0.019 4 179.1 9Light Liquid - Yes 165,866 2.90 14 0.277 5 24.3 48 0.467 3 31.0 17Appendix E-2: Area Source Baseline Emission Factors for Fuel-Based HAP and SO2 for Existing UnitsFuel CategoryNon-Hg MetalsControlCategoryTotal # ofUnits in SubCategoryAs(lb/MMBtu)As # ofDataPointsBe(lb/MMBtu)Be # ofDataPointsCd(lb/MMBtu)Cd # ofDataPointsCo(lb/MMBtu)Co # ofDataPointsCoal 5 3,710 2.48E-04 13 8.38E-06 11 4.48E-06 13 1.06E-05 -Biomass 5 10,958 1.20E-05 - 1.61E-05 - 6.54E-06 - 2.11E-06 -Heavy Liquid 6 2,137 4.54E-05 54 2.18E-05 51 2.46E-05 56 1.06E-04 23Light Liquid 6 165,866 1.71E-04 120 5.71E-05 121 2.57E-05 212 2.09E-05 58Appendix E-2:Fuel CategoryCoalBiomassHeavy LiquidLight LiquidCr(lb/MMBtu)Cr # ofDataPointsNi(lb/MMBtu)Ni # ofDataPointsMn(lb/MMBtu)Mn # ofDataPointsPb(lb/MMBtu)Pb # ofDataPointsSb(lb/MMBtu)Sb # ofDataPointsSe(lb/MMBtu)Se # ofDataPoints5.07E-05 13 1.07E-04 13 3.80E-04 11 1.81E-04 13 3.36E-05 - 1.16E-04 111.92E-05 - 3.05E-05 - 3.07E-03 - 7.93E-05 - 3.06E-06 - 1.80E-05 -5.18E-05 55 2.41E-03 55 5.72E-03 53 8.68E-05 56 8.86E-05 23 6.10E-05 482.64E-04 213 2.35E-04 123 1.60E-02 123 3.21E-04 212 1.37E-04 59 2.08E-04 121Appendix E-2:Fuel CategoryCoalBiomassHeavy LiquidLight LiquidHg ControlCategoryTotal # ofUnits in SubCategoryHg(lb/MMBtu)Hg # ofDataPointsPM FilterableControlCategoryTotal # ofUnits in SubCategoryPMFilterable(lb/MMBtu)PM # ofDataPoints6 3,710 3.14E-05 147 5 3,710 2.23E-01 346 10,958 1.17E-06 - 5 10,958 2.84E-01 -6 2,137 9.67E-07 61 6 2,137 7.67E-02 376 165,866 2.51E-06 228 6 165,866 2.05E-02 28Appendix E-2:Fuel CategoryCoalBiomassHeavy LiquidLight LiquidInorganicControlCategoryTotal # ofUnits in SubCategoryHCl(lb/MMBtu)HCl # ofDataPointsHF(lb/MMBtu)HF # ofDataPointsCl2(lb/MMBtu)Cl2 # ofDataPointsSO2 (ppm@ 3% O2)SO2 # ofDataPoints5 3,710 1.12E-01 263 3.01E-03 33 3.26E-03 185 765.0 865 10,958 7.24E-03 - 2.02E-04 - 2.79E-03 - 65.0 -5 2,137 6.90E-03 59 1.68E-04 9 6.36E-04 6 181.3 165 165,866 2.86E-03 225 2.69E-04 5 3.39E-03 4 80.4 11