Project No. 3338

James River Cogeneration Company

Hopewell, Virginia

Emission Evaluation Test Program

Unit No.2

Test Date: May 7,2010
Prepared for:

Ms. Dana L. Rieves

Compliance Supervisor

James River Cogeneration Company

912 East Randolph Road

Hopewell. Virginia 23860

Date Prepared: June 2010
Table of Contents

Page

1.0 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 1

2.0 Source Information and Description 2

3.0 Test Results Summary 3

4.0 Test Methodologies " 6

4.1 Cyclonic Flow. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 6

4.2 Stack Gas Velocity and Volumetric Flow Determination 6

4.3 Moisture Content 7

4.4 Gaseous Emission Sampling System 7

4.4.1 Oxygen and Carbon Dioxide 8

4.5 Toxic Metals 8

4.6 Total Suspended Particulate Matter/

Particulate Matter < 10 Microns 10

5.0 Quality Assurance/Quality Control Procedures 12

5.1 S-Type Pitot Tubes 12

5.2 Dry Gas Meters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 12

5.3 Nozzles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 13

5.4 Thermocouples 13

5.5 Labels..................................................... 14

5.6 Chain-of-Custody Documentation 14

5,7 Calibration Gases 14

Appendix A - Field Data Sheets

Appendix B - Laboratory Data

Appendix C - Emission Calculations

Appendix D - Calibration Data
James River Cogeneration Company

June 2010

1.0 Introduction

Project No. 3338

Revision No. 0

AirNova, Inc. conducted an emission evaluation test program at the James River Cogeneration

Company facility located in Hopewell, Virginia on May 7,2010. Emission sampling was conducted in order

to evaluate the status of one [1] turbine stack operating at this site. The specific emission parameters

which were determined as part of this test program included the following:

• Toxic Metals*

• Total Suspended Particulate Matter [TSP]

• Particulate Matter < 10 Microns [PM-1 0]

* Toxic Metals included: Antimony [Sb], Arsenic [As], Beryllium [Be], Cadmium [Cd),

Chromium [Cr], Cobalt [Co), Lead [Pb], Manganese [Mn), Nickel [Ni), Selenium [Se) and

Mercury [Hg]

AirNova, Inc. was responsible for all on-site sampling, sample analysis and submittal of this test

report which provides a description of the source and the sampling location, a complete summary of the

test results and a discussion of all test methodologies and analytical techniques that were employed in

the performance of the test program. Any questions pertaining to the information provided herein may

be addressed to:

Mr. Lenny D. Katerynczuk

Project Manager

AirNova, Inc.

5845 Clayton Avenue

Pennsauken, New Jersey 08109

Telephone: [856]

Telefax: [856] 486-9896

E-mail: lenny@airnova.com

AirNova, Inc. 1
James River Cogeneration Company

June 2010

2.0 Source Information and Description

Project No. 3338

Revision No. 0

The James River Cogeneration Company [JRCC) is 100% owned by Cogentrix, Inc. and was

constructed in 1987 to provide steam to Honeywell and electricity to Dominion Virginia Power. JRCC's

PPA is currently NOVEC. The 33-acre tract on which JRCC is located is leased from Honeywell. The plant

has six (6) Foster wheeler boilers rated at 157,500 Ibs/hr each. Steam is supplied to two (2) General

Electric single automatic extraction/condensing turbines rated at 58.5 MWeach.

Each boiler is equipped with a spray dryer absorber and a bagfilter. The emissions stream from

each set of 3 boilers is ducted to a common turbine stack. The turbine stacks, identified as Unit NO.1 and

Unit No.2, are 116 inches (9.7 feet) in internal diameter [1.0.). Emissions testing for this evaluation

program was conducted on Unit 2 stack only. Four (4) test ports are located on each exhaust stack at

900 intervals. The ports are located 80 feet (8.3 duct diameters) downstream from the entry point to the

final stack and 60 feet (6.2 duct diameters) upstream from the atmospheric exhaust point. A total of

twelve (12) traverse points were utilized for all emission determinations [six (6) across each stack

diameter and three (3) per test port). The traverse points were located as follows:

Table 2-1

James River Cogeneration Company

Unit No.2

Traverse Point Locations

- \§t~cK I ., J ... ,,~ .... .. 1 4.4 5.1

2 14.6 16.9

3 29.6 34.3

AirNova, Inc. 2
James River Cogeneration Company

June 2010

3.0 Test Results Summary

Project No. 3338

Revision No. 0

A complete summary ofresults forthe emission evaluation test program conducted at the James

River Cogeneration Company facility for Unit No.2 is provided in tabular format on the following pages.

Sampling was conducted in order to evaluate the status of the boiler for particulate matter and toxic

metals emissions. Summary tables are presented as follows:

James River Cogeneration Company

Unit No. 2

Emission Evaluation Test Program

Summary of Test Results Tables

Table No. Description Page No.

3-1 Unit NO.1 - Test Data Summary - TSP and PM 10 4

3-2 Unit No.1 - Test Data Summary - Toxic Metals 5

Abbreviations:

AirNova, Inc.

TSP =

PM 10 =

Total Suspended Particulate Matter

Particulate Matter < 10 Microns

3
James River Cogeneration Company

June 2010

Table 3-1

James River Cogeneration Company

Unit No.2

Test Data Summary' TSP and PM 10

Project No. 3338

Revision No. 0

Run No. 1 2 • v'

""'.

Date 05/07/10 05/07/10 05/07/10

Test Period 0715-0930 0952-1203 1216-1426

Stack Gas Charactel'istics

Temperature [OF] 210 213 216 213

Moisture Content [%] 10.6 10.4 10.3 10.4

Molecular Weight [Ib/lb-mole] 29.1 29.1 29.1 29.1

Velocity [FPS] 50.3 51.0 50.8 50.7

Flow Rate [ACFM] 221,456 224,529 223,514 223,166

Flow Rate [DSCFM] 156,514 158,617 157,157 157,429

Oxygen [%] 5.49 5.65 5.49 5.54

Carbon Dioxide [%] 13.65 13.53 13.63 13.60

Total Suspended Particulate Matter

Concentration [gr/DSCF] 1.4e-03 0.001 0.001 0.001

Emission Rate [Ib/hr] 1.85 1.71 1.45 1.67

Emission Rate [lb/MMBtu] 0.002 0.002 0.002 0.002

.~ •...............• ......

Concentration [gr/DSCF] 0.002 0.002 0.002 0.002

Emission Rate [Ib/hr] 2.92 3.32 3.27 3.17

Emission Rate [lb/MMBtu] 0.004 0.004 0.004 0.004

Standard Conditions: B8°F, 29.92 in. Hg

AirNova, Inc. 4
James River Cogeneration Company

June 2010

Table 3-2

James River Cogeneration Company

Unit No.2

Test Data Summary - Toxic Metals

Project No. 3338

Revision No. 0

Run No. 1 2 3 Average

Date 05/07/10 05/07/10 05/07/10

Test Period 0715-0930 0952-1203 1216-1426

Stack Gas Characteristics

Temperature [OF] 208 212 215 212

Moisture Content [%] 11.2 10.6 10.5 10.8

Velocity [FPS] 50.5 50.5 51.7 50.9

Flow Rate [ACFM] 222,359 222,304 227,561 224,075

Flow Rate [DSCFM] 156,513 156,839 159,818 157,723

Oxygen [%] 5.49 5.65 5.49 5.5

Carbon Dioxide [%] 13.65 13.53 13.63 13.6

Toxic Metals [Emission Rate Ib/hr)'" •

Antimony 6.1 e-05 9.ge-05 1.2e-04 9.3e-05

Arsenic 4.7e-04 5.1 e-04 5.3e-04 5.0e-04

Beryllium 1.0e-05 1.0e-05 1.4e-05 1.1 e-05

Cadmium < 2.4e-05 3.8e-05 8.oe-05 4.7e-05

Chromium 1.0e-03 1.1 e-03 1.1 e-03 1.1e-03

Cobalt 7.6e-05 8.0e-05 1.oe-04 8.5e-05

Lead 4.3e-04 5.4e-04 2.4e-03 1.1 e-03

Manganese 4.8e-03 4.ge-04 7.6e-04 2.oe-03

Nickel 5.8e-04 8.3e-04 1.3e-03 9.0e-04

Selenium 7.6e-05 9.4e-05 1.2e-04 9.7e-05

Mercury < 1.2e-04 < 1.2e-04 < 1.2e-04 < 1.2e-04

Standard Conditions: B8°F, 29.92 in. Hg

'" Concentrations and emission rates in Ib/MMBtu of each toxic metal can be found in the

Emission Calculations Appendix.

AirNova, Inc. 5
James River Cogeneration Company

June 2010

4.0 Test Methodologies

Project No. 3338

Revision No. 0

The emission evaluation test program was conducted in determination of the following emission

parameters utilizing the specified methodologies.

Table 4-1

James River Cogeneration Company

Unit No.2

Test Methodology Summary

Emission Parameter No. afTest Runs Sampling and Analytical Methodology

Traverse Point Location * EPA Reference Method 1

Volumetric Flow Rate * EPA Reference Method 2

Oxygen/Carbon Dioxide * EPA Reference Method 3A

Moisture Content * EPA Reference Method 4

Toxic Metals 3 EPA Reference Method 29

Total Suspended Particulate Matter/ 3 EPA Reference Methods 5 and 202

Particulate Matter < 10 Microns

* These parameters were determined concurrently with all other emission parameters.

4.1 Cyclonic Flow

The absence of cyclonic flow was demonstrated at the sampling location according to Section

11.4 of EPA Reference Method 1. An S-type pitot was connected to a manometer. The pitot tube was

placed in such a position that the openings of the pitot tube were perpendicular to the stack gas flow. An

angle finder was placed on the pitot tube which was rotated until a reading of zero (0) was obtained. The

'yaw' angle was then recorded. The cyclonic flow traverse was performed at the traverse point locations

specified in Table 2-1.

4.2 Stack Gas Velocity and Volumetric Flow Rate Determination

The determination of stack gas velocity and volumetric flow rate was performed in accordance

with EPA Reference Method 2. Velocity traverses across the stack diameter at the test location were

performed using an S-type pitot tube and type-K thermocouple. The S-type pitot tube was connected to

AirNova, Inc. 6
James River Cogeneration Company

June 2010

Project No. 3338

Revision No. 0

an inclined vertical manometer via leak-free connections. The type-K thermocouple was connected to a

digital temperature indicator for signal output. These readings were observed and recorded at each

traverse point for each test run.

A post-test leak check ofthe S-type pitot tube, the manometer, and the interconnecting tubing was

performed in accordance with the procedure described in EPA Reference Method 2, "Determination of

Stack Gas Velocity and Volumetric Flow Rate ( Pitot Tube]."

4.3 Moisture Content

Moisture content determinations were performed in accordance with EPA Reference Method 4,

Section 2.0. The determination of moisture content was conducted utilizing large capacity impingers and

by collecting a minimum sample of volume of 30 dscf.

4.4 Gaseous Emissions Sampling System

An extractive sampling system was used to continuously determine 02 and CO2 concentrations.

A representative sample ofthe flue gas was extracted through a heated (250°F] stainless steel probe and

filter assembly, and transported via a heat-traced Teflon sample line through a heated glass fiber filter and

a Teflon lined diaphragm sample pump to a condensation removal trap located in a mobile laboratory. A

heated out-of-stack filter assembly was maintained at a sufficient temperature to prevent water

condensation. A three-way valve was utilized to block sample gas flow and

the measurement system at the outlet of the sampling probe during system calibrations. The

condensation trap was cooled to approximately 40°F. The sample was exhausted from the trap free of

moisture and particulate matter. The sample was introduced into a constant-pressure manifold

constructed of stainless steel and Teflon for metered distribution to the respective analyzers.

Output signals from all instrumental analyzers were stored on a personal computer (PC) based

data acquisition system (DAS]. All reference method data was reported from the DAS. All continuous

analyzers utilized forthe RM testing provided a linear response to the DAS overthe calibrated range. This

was verified by the pre-test calibration results.

AirNova, Inc. 7
James River Cogeneration Company

June 2010

Project No. 3338

Revision No. 0

A stratification test was performed during the first test run for the emission source to determine

the amount of traverse points to be utilized for the gas probe during each subsequent test run. The test

was performed in two (2) test ports utilizing twelve (12) traverse points. The gas probe was at each

traverse point for a minimum period oftwo (2) times the response time of the reference method sampling

system [1 minute). The oxygen analyzer was utilized to determine stratification in the exhaust stack. It

was determined that the oxygen concentration at each traverse point was less than 5% of the mean

oxygen concentration for all traverse points, and therefore, single point sampling was implemented forthe

source during the test program. The stratification test results can be found in Appendix A of this test

report.

4.4.1 Carbon Dioxide and Oxygen

The carbon dioxide and oxygen concentrations in the stack gases were determined by EPA

Reference Method 3A. The sampling system was the same as described above. Oxygen concentrations

were determined using a paramagnetic oxygen analyzer operating in a range of 0-22.D3%. A nondispersive infrared analyzer was utilized to measure carbon dioxide concentrations operating in a range

of 0-22.28%. Before and after each sample run, the analyzer was calibrated with NIST traceable

calibration gases. Calibration gases were 0-20% [zero gas), 45-55% and 100% of the calibration span.

each

test run. Output signals were stored and processed by a PC based DAS system.

4.5 Toxic Metals

Metals in the exhaust gases were determined isokinetically using EPA Reference Method 29

"Methodology for the Determination of Metal Emissions in Exhaust Gases from Hazardous Waste

Incinerator Processes".

Metals sampling occurred during 2-hour sampling events. Triplicate test runS were performed

with each collecting a minimum volume of 60 DSCF. The sampling train consisted of the following

components:

AirNova, Inc. 8
James River Cogeneration Company

June 2010

Project No. 3338

Revision No. 0

• Glass sample nozzle and probe

• Heated glass fiber filter

• A modified Greenburg Smith impinger containing

100 ml of a 5% HNOa/1 0% H202

• A Greenburg-Smith impinger containing 100 ml 5% HNOa/1 0% H202

• Modified Greenburg-Smith impinger initially empty

• Two [2] modified Greenburg-Smith impingers containing

100 ml 4% KMnO.J1 0% H2S04 solution

• An impinger containing approximately 225 g of silica gel desiccant

• Dry gas meter equipped with inlet and outlet thermocouples

The sample was extracted from the exhaust stream using a vane-type vacuum pump. Isokinetic

sampling conditions were maintained through the use of a type "S" pitot tube to monitor the exhaust gas

stream pressure differentials. A type "K" thermocouple was utilized to determine the exhaust gas

temperature.

At the completion of sampling, the probe liner, nozzle, and front half of the filter housing were

rinsed and brushed with 100 ml of a 0.1 N nitric acid reagent and the washings were placed in a glass

amber container retained for analysis. The filter was removed from the filter holder and placed in a petri

dish and sealed. The contents of impingers 1 and 2 were measured for volume increase and placed in

a second glass amber container. Impingers 1 and 2 and the back half of the filter housing were then

rinsed with a total of 100 ml 0.1 N nitric acid and the washings were placed in a third glass amber

container. The contents of impinger 3 were measured for volume increase and placed in a fourth glass

amber container along with a total of 100 ml 0.1 N nitric acid washings. Impingers 4 and 5 were

measured for volume increase and placed in a fifth glass amber container along with a total of 100 ml

each of the fresh permanganate and distilled water rinses of all sample exposed areas for the two [2]

impingers. Impingers 4 and 5 were then rinsed with a total of 25 ml of 8N Hel which was placed in a

sixth glass amber container. The silica gel was recovered from the last impinger and placed in a sealed

container for weight gain determination.

Prior to analysis, the collected front and back half liquid sample volumes were reduced. The filter

was acid digested in accordance with the method prior to being combined with the probe rinse for

AirNova, Inc. 9
James River Cogeneration Company

June 2010

Project No. 3338

Revision No. 0

• 1st:

• 2 nd:

• 3rd:

• 4th:

analysis. Antimony, arsenic, beryllium, cadmium, chromium, cobalt, manganese, nickel, lead and selenium

were determined by inductively coupled plasma-optical emission mass spectroscopy (ICP-MS). Mercury

was determined by cold vapor atomic absorption spectrophotometry (CVAA).

The spike recoveries were mostly within the normal range of 75% to 125%. Duplicate analyses,

relative percent difference (RPO) and spike recovery data can be found in Appendix B of this test report.

4.6 Total Suspended Particulate MatterjParticulate Matter <10 Microns

Total suspended particulate matter(TSP) and particulate matter< 10 microns (PM-1 0) emissions

were determined in accordance with EPA Reference Method 5 and EPA Reference Method 202

respectively. Priorto sampling, the sample train was leak checked at 15 inches Hg vacuum to ensure that

all sample train components were leak free. During sampling, gas samples were isokinetically extracted

from the exhaust stack and passed through a glass nozzle, a glass lined probe and a quartz fiber filter, all

maintained at a temperature of 250°F to prevent condensation on the glass fiber filter. The gas sample

then passed through an impinger train consisting of four (4) glass impingers immersed in an ice bath.

The arrangement of the impingers was as follows:

Greenburg-Smith, containing 100 ml of 01 water.

Greenburg-Smith containing 100 ml of 01 water.

Modified Greenburg-Smith containing 100 ml of 01 water

Modified Greenburg-Smith containing approximately 350 g of silica gel for final

of the

The sample gas volume was measured by passing it through a calibrated dry gas meter. An &

type pitot tube was attached to the sample probe to monitor the stack gas velocity in order to maintain

isokinetic sampling conditions. In addition, a type K thermocouple was attached to measure the exhaust

gas temperature. Following each test run, the EPA 5/202 sample train was leak checked at the highest

vacuum recorded during the run.

After each run, the probe, nozzle and all connecting glassware ahead of the filter were brushed

and rinsed with acetone. The washings were retained in an amber glass jar with a teflon lined lid. The

AirNova, Inc. 10
James River Cogeneration Company

June 2010

quartz fiber filter was placed in it's original petri dish.

Project No. 3338

Revision No. 0

Condensable PM-10 was determined from the back half analysis of the particulate matter

sampling train. No silicone grease was used in the sampling train. All sampling train glassware was

cleaned prior to the test consistent with Section 3.1.3 of Method 202 [soap and tap water. water. and

rinsed using tap water, water. acetone, and finally, MeCI2). At the conclusion of sampling, the pH of the

impinger train was measured. If found to be> 4.5 pH, the nitrogen purge was not performed.

The glass fiber filters were oven dried for 2 - 3 hours at the average temperature maintained

during the corresponding test run, desiccated for 2 - 3 more hours and then reanalyzed for a final weight

determination. The acetone samples were evaporated at room temperature and pressure in tared Teflon

baggies. desiccated for 24 hours and also reanalyzed for a final weight determination. The impinger

contents were subsequently measured for volume increase and rinsed with distilled water and retained

in a glass sample jar with a Teflon lid. The impingers were then rinsed three times with methylene chloride

and retained in a separate glass sample jar with a Teflon lined lid. The PM-1 0 analysis was conducted as

described in Method 202 additionally utilizing Teflon baggies forthe analysis of each liquid sample fraction.

AirNova, Inc. 11
James River Cogeneration Company

June 2010

5.0 Quality Assurance/Quality Control Procedures

Project No, 3338

Revision No, 0

All of the source sampling and analytical procedures were performed in accordance with the US

EPA's 'Good Laboratory Practice' guidelines. AirNova, Inc. followed the requirements of the individual test

methods to ensure the precision and accuracy ofthe source testing procedures. In addition, AirNova, Inc.

followed the procedures provided in the 'Quality Assurance Handbook for Air Pollution Measurement

Systems, Volume III, Stationary Sources'. Sampling equipment utilized in the test program was calibrated

prior to the test performance. The following procedures were utilized.

5.1 S-Type Pitot Tubes

The S-type pitot tubes were visually inspected to verify dimension requirements, Pitot tubes

meeting requirements were assigned a pitot tube coefficient of 0,84. Pitot tubes which did not meet the

requirements were not utilized.

5.2 Dry Gas and Orifice Meters

All dry gas meters used in the field were calibrated against a transfer standard dry gas meterthat

is maintained in AirNova Inc.'s calibration data, The transfer standard gas meter is calibrated annually

and certified against an NIST traceable Bell-type Prover which operates by liquid displacement.

Field dry gas meters and orifice meters are calibrated at two month intervals at the following

orifice meter settings:

• 0,5 in. H2O

1.0 in. H2O

• 1.5 in. H2O

• 2.0 in. H2O

The initial and final volume readings and temperature readings were recorded for the dry gas

meter and the secondary standard test meter at each orifice meter setting. A dry gas meter correction

factor [DGMCF) was calculated for each setting and the average DGMCF recorded,

All calibration documentation is stored in a designated filing cabinetforfuture reference, All repair

and maintenance documentation for each meter is stored in files that provide a history of each meter and

AirNova, Inc, 12
James River Cogeneration Company

June 2010

aid in our preventative maintenance program.

5.3 Nozzles

Project No. 3338

Revision No. 0

Probe nozzles selected for isokinetic sampling were calibrated according to section 3.4.2 of the

"Quality Assurance Handbook for Air Pollution Measurement Systems: Volume 111." The inner diameter

of each nozzle was measured across three (3) distinct diameters with a micrometer caliper. The

calibrated nozzle diameter is the average of these measurements. Each nozzle is identified uniquely and

its calibrated diameter checked prior to use.

5.4 Thermocouples

Thermocouples and thermometers utilized in the sampling program were calibrated every two

months according to section 3.4.2 of the "Quality Assurance for Air Pollution Measurement Systems:

Volume III." The calibration method includes comparing each field thermometer and thermocouple at

different temperatures to an ASTM certified mercury-in-glass thermometer. The temperatures must

agree within the tolerances mentioned for the type of sampling equipment being calibrated. All the

calibration data is stored in a designated filing cabinet for future reference.

1. Stack Gas and Filter Housing Thermocouples and Thermometers

Three temperatures are measured and extrapolated over the range of

temperatures encountered in field operations. The three temperatures used for

calibration are:

1. Ice bath

2. Boiling point of water

3. Boiling point of cooking oil [or equivalent in solid salt bath)

2. Impinger Thermometers and Thermocouples

Two temperatures are required to calibrate:

1. Ice bath

2. Stabilized room temperature

AirNova, Inc.

3. Dry Gas Thermometers

Two temperatures are required to calibrate:

1. Stabilized hot water bath at approximately 104 - 122°F [40 - 50°C)

2. Stabilized room temperature

13
James River Cogeneration Company

June 2010

5.5 Labels

Project No. 3338

Revision No. 0

All samples collected as part of the sampling program (silica gel desiccant samples) were affixed

with labels which identify the following:

• Project No.

• Date

• Type of sample

• Run No.

• Sample location

• Sample fraction

5.6 Chain-of-Custody Documentation

Chain-of-custody documentation for all samples was implemented at the completion of sampling

and sample clean-up and was documented until the samples were received by the laboratory for analysis.

5.7 Calibration Gases

NISTTraceable Protocol 1 grade [±1 %) gas standards were utilized for calibration of the O2 and

CO2 analyzers.

AirNova, Inc. 14
Appendix A

Field Data
RackCal James River Cogen

Unit NO.2

Rack Cal Metals/PM-10

05/07110 08:00:49 02 -0.01 % R CO2 -0.24 % R

05/07/10 08:00:49 02 -0.01 % R CO2 0.00 % R

05/07/10 08:00:54 02 -0.01 % R CO2 -0.12 % R

05/07/10 08:00:59 02 0.00 % R CO2 -0.12 % R

05/07/10 08:01:04 02 0.01 % R CO2 -0.24 % R

05/07/10 08:01:09 02 0.01 % R CO2 -0.24 % R

05/07/10 08:01:14 02 0.00 % R CO2 0.00 % R

05/07/10 08:01 :19 02 0.01 % R CO2 -0.12 % R

05/07/10 08:01:24 02 13.42 % R CO2 -0.12 % R

05/07/10 08:01:29 02 12.93 % R CO2 0.00 % R

05/07/10 08:01:34 02 12.43 % R CO2 0.00 % R

05/07/10 08:01:39 02 12.34 % R CO2 -0.12 % R

05/07/10 08:01:44 02 12.27 % R CO2 0.00 % R

05/07/10 08:01:49 02 12.22 % R CO2 0.12 % R

05/07/10 08:01:54 02 12.17 % R CO2 0.12 % R

05/07/10 08:01:59 02 11.80 % R CO2 -0.12 % R

05/07/10 08:02:04 02 20.29 % R CO2 6.59 % R

05/07/10 08:02:09 02 20.95 % R CO2 11.35 % R

05/07/10 08:02:14 02 21.14 % R CO2 12.33 % R

05/07/10 08:02:19 02 21.23 % R CO2 12.21 % R

05/07/10 08:02:24 02 21.39 % R CO2 12.33 % R

05/07/10 08:02:29 02 21.77 % R CO2 12.33 % R

05/07/10 08:02:34 02 21.79 % R CO2 12.21 % R

05/07/10 08:02:39 02 21.86 % R CO2 12.33 % R

05/07/10 08:02:44 02 21.87 % R CO2 12.33 % R

05/07/10 08:02:49 02 21.89 % R CO2 12.33 % R

05/07/10 08:02:54 02 13.23 % R CO2 12.45 % R

05/07/10 08:02:59 02 0.42 % R CO2 12.08 % R

05/07/10 08:03:04 02 0.13 % R CO2 12.08 % R

05/07/10 08:03:09 02 0.10 % R CO2 13.06 % R

05/07/10 08:03:14 02 0.07 % R CO2 21.61 % R

05/07/10 08:03:19 02 0.06 % R CO2 22.34 % R

05/07/10 08:03:46 02 0.06 % R CO2 22.34 % R

05/07/10 08:03:46 02 0.04 % R CO2 22.22 % R

1
Pre1 Bias James River Cogen

Unit NO.2

Pre Run1 Bias Metals/PM-10

05/07/10 08:07:31 02 0.15

%R CO2 0.00

%

R

05/07/10 08:07:34 02 0.15

%

R CO2 0.12

%

R

05/07/10 08:07:39 02 0.13

%R CO2 0.00

%

R

05/07/10 08:07:44 02 0.13

%R CO2 0.00

%

R

05/07/10 08:07:49 02 0.12

%

R CO2 0.00

%

R

05/07/10 08:07:54 02 0.12

%R CO2 -0.12

%

R

05/07/10 08:07:59 02 0.12

%R CO2 0.00

%

R

05/07/10 08:08:04 02 0.12

%

R CO2 -0.12

%

R

05/07/10 08:08:09 02 0.12

%R CO2 0.00

%

R

05/07/10 08:08:14 02 0.11

%R CO2 0.12

%

R

05/07/10 08:08:19 02 0.11

%R CO2 0.12

%

R

05/07/10 08:08:24 02 0.13

%

R CO2 0.12

%

R

05/07/10 08:08:29 02 0.92

%R CO2 1.34

%

R

05/07/10 08:08:34 02 1.72

%R CO2 2.32

%

R

05/07/10 08:08:39 02 4.68

%R CO2 3.42

%

R

05/07/10 08:08:44 02 7.43

%R CO2 4.76

%

R

05/07/10 08:08:49 02 9.16

%R CO2 5.74

%

R

05/07/10 08:08:54 02 10.33

%R CO2 6.10

%

R

05/07110 08:08:59 02 11.06

%R CO2 6.47

%

R

05/07/10 08:09:04 02 11.49

%R CO2 6.84

%

R

05/07/10 08:09:09 02 11.84

%R CO2 6.84

%

R

05/07/10 08:09:14 02 12.05

%

R CO2 6.96

%

R

05/07/10 08:09:19 02 12.22

%

R CO2 7.20

%

R

05/07/10 08:09:24 02 12.32

%R CO2 7.08

%

R

05/07/10 08:09:29 02 12.38

%R CO2 7.20

%

R

05/07/10 08:09:34 02 12.43

%R CO2 7.08

%

R

05/07/10 08:09:39 02 12.45

%R CO2 7.32

%

R

05/07/10 08:09:44 02 12.46

%

R CO2 7.20

%

R

05/07/10 08:09:49 02 12.48

%R CO2 7.32

%

R

05/07/10 08:09:54 02 12.48

%R CO2 7.45

%

R

05/07/10 08:09:59 02 12.49

%

R CO2 7.45

%

R

05/07/10 08:10:04 02 12.50

%

R CO2 7.57

%

R

05/07/10 08:10:09 02 12.50

%

R CO2 7.32

%

R

05/07/10 08:10:14 02 12.51

%R CO2 7.57

%

R

05/07/10 08:10:19 02 12.51

%R CO2 7.57

%

R

05/07/10 08:10:24 02 12.50

%R CO2 7.20

%

R

05/07/10 08:10:29 02 12.48

%R CO2 7.32

%

R

05/07/10 08:10:34 02 12.30

%R CO2 7.57

%

R

05/07/10 08:10:39 02 13.87

%R CO2 8.06

%

R

05/07/10 08:10:44 02 16.47

%

R CO2 9.28

%

R

05/07/10 08:10:49 02 18.53

%R CO2 10.50

%

R

05/07/10 08:10:54 02 19.90

%

R CO2 11.11

%

R

05/07/10 08:10:59 02 20.67

%R CO2 11.72

%

R

05/07/10 08:11 :04 02 21.19

%R CO2 11.84

%

R

05/07/10 08:11 :09 02 21.41

%

R CO2 11.84

%

R

05/07/10 08:11 :14 02 21.62

%R CO2 12.21

%

R

05/07/10 08:11:19 02 21.72

%R CO2 12.33

%

R

05/07/10 08:11 :24 02 21.79

%

R CO2 12.70

%

R

05/07/10 08:11 :29 02 21.84

%R CO2 12.45

%

R

05/07/10 08:11 :34 02 21.87

%R CO2 12.45

%

R

2
05/07/10

05/07/10

05/07/10

08:11 :39

08:11 :44

08:11 :49

02 21.89

02 21.89

02 20.07

%

%

%

R

R

R

3

C02 12.45

C02 12.45

C02 12.21

%

%

%

R

R

R
Run1 James River Cogen

Unit NO.2

Run NO.1 Metals/PM-10

05/07110 08:13:09 02 5.83 % R CO2 13.55 % R

05/07/10 08:13:19 02 5.77 % R CO2 13.67 % R

05/07/10 08:13:29 02 5.76 % R CO2 13.67 % R

05/07/10 08:13:39 02 5.74 % R CO2 13.67 % R

05/07/10 08:13:49 02 5.71 % R CO2 13.67 % R

05/07/10 08:13:59 02 5.68 % R CO2 13.67 % R

05/07/10 08:14:09 02 5.63 % R CO2 13.55 % R

05/07/10 08:14:19 02 5.59 % R CO2 13.67 % R

05/07/10 08:14:29 02 5.57 % R CO2 13.55 % R

05/07/10 08:14:39 02 5.53 % R CO2 13.79 % R

05/07/10 08:14:49 02 5.52 % R CO2 13.67 % R

05/07/10 08:14:59 02 5.46 % R CO2 13.67 % R

05/07110 08:15:09 02 5.46 % R CO2 13.79 % R

05/07/10 08:15:19 02 5.49 % R CO2 13.67 % R

05/07/10 08:15:29 02 5.54 % R CO2 13.79 % R

05/07/10 08:15:39 02 5.58 % R CO2 13.79 % R

05/07/10 08:15:50 02 5.63 % R CO2 13.55 % R

05/07/10 08:15:59 02 5.66 % R CO2 13.67 % R

05/07/10 08:16:09 02 5.70 % R CO2 13.67 % R

05/07/10 08:16:19 02 5.70 % R CO2 13.79 % R

05/07/10 08:16:29 02 5.66 % R CO2 13.55 % R

05/07/10 08:16:39 02 5.65 % R CO2 13.67 % R

05/07/10 08:16:49 02 5.66 % R CO2 13.79 % R

05/07/10 08:16:59 02 5.70 % R CO2 13.67 % R

05/07/10 08:17:09 02 5.70 % R CO2 13.55 % R

05/07/10 08:17:19 02 5.68 % R CO2 13.31 % R

05/07/10 08:17:29 02 5.68 % R CO2 13.43 % R

05/07/10 08:17:39 02 5.70 % R CO2 13.55 % R

05/07/10 08:17:49 02 5.73 % R CO2 13.43 % R

05/07/10 08:17:59 02 5.71 % R CO2 13.67 % R

05/07/10 08:18:09 02 5.68 % R CO2 13.67 % R

05/07/10 08:18:19 02 5.65 % R CO2 13.67 % R

05/07/10 08:18:29 02 5.66 % R CO2 13.92 % R

05/07/10 08:18:39 02 5.70 % R CO2 13.55 % R

05/07/10 08:18:49 02 5.71 % R CO2 13.55 % R

05/07/10 08:18:59 02 5.71 % R CO2 13.55 % R

05/07/10 08:19:09 02 5.74 % R CO2 13.43 % R

05/07/10 08:19:19 02 5.76 % R CO2 13.79 % R

05/07/10 08:19:29 02 5.77 % R CO2 13.55 % R

05/07/10 08:19:39 02 5.74 % R CO2 13.67 % R

05/07/10 08:19:49 02 5.69 % R CO2 13.31 % R

05/07/10 08:19:59 02 5.64 % R CO2 13.67 % R

05/07/10 08:20:09 02 5.62 % R CO2 13.79 % R

05/07/10 08:20:19 02 5.63 % R CO2 13.67 % R

05/07/10 08:20:29 02 5.62 % R CO2 13.79 % R

05/07/10 08:20:39 02 5.62 % R CO2 13.67 % R

05/07/10 08:20:49 02 5.63 % R CO2 13.55 % R

05/07/10 08:20:59 02 5.65 % R CO2 13.67 % R

05/07/10 08:21:09 02 5.71 % R CO2 13.67 % R

05/07/10 08:21:19 02 5.75 % R CO2 13.43 % R

4
05/07/10 08:21:29 02 5.76

%R CO2 13.43

%

R

05/07/10 08:21:39 02 5.79

%R CO2 13.55

%

R

05/07/10 08:21 :49 02 5.82

%

R CO2 13.67

%

R

05/07/10 08:21:59 02 5.82

%R CO2 13.55

%

R

05/07/10 08:22:09 02 5.79

%R CO2 13.67

%

R

05/07/10 08:22:19 02 5.76

%

R CO2 13.67

%

R

05/07/10 08:22:29 02 5.74

%

R CO2 13.67

%

R

05/07/10 08:22:39 02 5.74

%

R CO2 13.55

%

R

05/07/10 08:22:49 02 5.73

%R CO2 13.67

%

R

05/07/10 08:22:59 02 5.69

%R CO2 13.67

%

R

05/07/10 08:23:09 02 5.69

%R CO2 13.67

%

R

05/07/10 08:23:19 02 5.69

%R CO2 13.67

%

R

05/07/10 08:23:29 02 5.70

%R CO2 13.55

%

R

05/07/10 08:23:39 02 5.73

%R CO2 13.67

%

R

05/07/10 08:23:49 02 5.69

%

R CO2 13.55

%

R

05/07/10 08:23:59 02 5.62

%R CO2 13.55

%

R

05/07/10 08:24:09 02 5.57

%R CO2 13.55

%

R

05/07/10 08:24:19 02 5.55

%

R CO2 13.92

%

R

05/07/10 08:24:29 02 5.57

%R CO2 13.31

%

R

05/07/10 08:24:39 02 5.59

%

R CO2 13.67

%

R

05/07/10 08:24:49 02 5.59

%R CO2 13.67

%

R

05/07110 08:24:59 02 5.57

%

R CO2 13.67

%

R

05/07/10 08:25:09 02 5.55

%R CO2 13.79

%

R

05/07/10 08:25:19 02 5.54

%R CO2 13.67

%

R

05/07/10 08:25:29 02 5.53

%

R CO2 13.92

%

R

05/07/10 08:25:39 02 5.53

%R CO2 13.67

%

R

05/07/10 08:25:49 02 5.53

%R CO2 13.67

%

R

05/07/10 08:25:59 02 5.53

%R CO2 13.67

%

R

05/07/10 08:26:09 02 5.55

%R CO2 13.67

%

R

05/07/10 08:26:19 02 5.57

%R CO2 13.79

%

R

05/07/10 08:26:29 02 5.57

%R CO2 13.79

%

R

05/07/10 08:26:39 02 5.57

%R CO2 13.67

%

R

05/07/10 08:26:49 02 5.59

%R CO2 13.55

%

R

05/07/10 08:26:59 02 5.63

%R CO2 13.43

%

R

05/07/10 08:27:09 02 5.64

%

R CO2 13.67

%

R

05/07/10 08:27:19 02 5.63

%R CO2 13.55

%

R

05/07/10 08:27:29 02 5.65

%R CO2 13.79

%

R

05/07/10 08:27:39 02 5.65

%R CO2 13.55

%

R

05/07/10 08:27:49 02 5.66

%R CO2 13.31

%

R

05/07/10 08:27:59 02 5.69

%R CO2 13.67

%

R

05/07/10 08:28:09 02 5.73

%

R CO2 13.67

%

R

05/07/10 08:28:19 02 5.80

%R CO2 13.43

%

R

05/07/10 08:28:29 02 5.90

%R CO2 13.18

%

R

05/07/10 08:28:39 02 5.94

%R CO2 13.31

%

R

05/07/10 08:28:49 02 5.93

%

R CO2 13.43

%

R

05/07/10 08:28:59 02 5.90

%R CO2 13.31

%

R

05/07/10 08:29:09 02 7.75

%R CO2 13.31

%

R

05/07/10 08:29:19 02 5.90

%R CO2 13.31

%

R

05/07/10 08:29:29 02 5.91

%R CO2 13.31

%

R

05/07/10 08:29:39 02 5.91

%R CO2 13.43

%

R

05/07/10 08:29:49 02 5.91

%R CO2 13.43

%

R

05/07/10 08:29:59 02 5.92

%

R CO2 13.43

%

R

05/07/10 08:30:09 02 5.93

%R CO2 13.43

%

R

05/07/10 08:30:19 02 5.94

%R CO2 13.31

%

R

5
05/07/10 08:30:29 02 5.91

%

R CO2 13.43

%

R

05/07/10 08:30:39 02 5.83

%

R CO2 13.18

%

R

05/07/10 08:30:49 02 5.75

%

R CO2 13.67

%

R

05/07/10 08:30:59 02 5.66

%

R CO2 13.67

%

R

05/07/10 08:31:09 02 5.60

%

R CO2 13.79

%

R

05/07/10 08:31:19 02 5.57

%

R CO2 13.79

%

R

05/07/10 08:31 :29 02 5.55

%

R CO2 13.67

%

R

05/07/10 08:31:39 02 5.59

%

R CO2 13.79

%

R

05/07/10 08:31:49 02 5.64

%

R CO2 13.67

%

R

05/07/10 08:31:59 02 5.68

%

R CO2 13.67

%

R

05/07/10 08:32:09 02 5.70

%

R CO2 13.79

%

R

05/07/10 08:32:19 02 5.69

%

R CO2 13.67

%

R

05/07/10 08:32:29 02 5.65

%

R CO2 13.79

%

R

05/07/10 08:32:39 02 5.62

%

R CO2 13.67

%

R

05/07/10 08:32:49 02 5.59

%

R CO2 13.79

%

R

05/07/10 08:32:59 02 5.55

%

R CO2 13.43

%

R

05/07/10 08:33:09 02 5.52

%R CO2 13.79

%

R

05/07/10 08:33:19 02 5.47

%

R CO2 13.55

%

R

05/07/10 08:33:29 02 5.42

%

R CO2 13.79

%

R

05/07/10 08:33:39 02 5.41

%

R CO2 13.67

%

R

05/07/10 08:33:49 02 5.40

%R CO2 13.92

%

R

05/07/10 08:33:59 02 5.41

%

R CO2 13.79

%

R

05/07/10 08:34:09 02 5.41

%R CO2 13.92

%

R

05/07/10 08:34:19 02 5.46

%

R CO2 13.92

%

R

05/07/10 08:34:29 02 5.54

%

R CO2 13.92

%

R

05/07/10 08:34:39 02 5.62

%

R CO2 13.55

%

R

05/07/10 08:34:49 02 5.69

%

R CO2 13.55

%

R

05/07/10 08:34:59 02 5.75

%

R CO2 13.67

%

R

05/07/10 08:35:09 02 5.76

%R CO2 13.31

%

R

05/07/10 08:35:19 02 5.70

%

R CO2 13.55

%

R

05/07/10 08:35:29 02 5.63

%

R CO2 13.67

%

R

05/07/10 08:35:39 02 5.58

%

R CO2 13.67

%

R

05/07/10 08:35:49 02 5.52

%

R CO2 13.67

%

R

05/07/10 08:35:59 02 5.49

%

R CO2 13.67

%

R

05/07/10 08:36:09 02 5.49

%

R CO2 13.92

%

R

05/07/10 08:36:19 02 5.52

%

R CO2 13.92

%

R

05/07/10 08:36:29 02 5.54

%

R CO2 13.55

%

R

05/07/10 08:36:39 02 5.57

%R CO2 13.67

%

R

05/07/10 08:36:49 02 5.59

%

R CO2 13.92

%

R

05/07/10 08:36:59 02 5.60

%

R CO2 13.79

%

R

05/07/10 08:37:09 02 5.57

%

R CO2 13.67

%

R

05/07/10 08:37:19 02 5.54

%

R CO2 13.79

%

R

05/07/10 08:37:29 02 5.49

%R CO2 13.79

%

R

05/07/10 08:37:39 02 5.47

%

R CO2 13.92

%

R

05/07/10 08:37:49 02 5.47

%

R CO2 14.04

%

R

05/07/10 08:37:59 02 5.48

%

R CO2 13.79

%

R

05/07/10 08:38:09 02 5.48

%

R CO2 13.67

%

R

05/07/10 08:38:19 02 5.49

%

R CO2 13.67

%

R

05/07/10 08:38:29 02 5.51

%

R CO2 13.55

%

R

05/07/10 08:38:39 02 5.52

%R CO2 13.55

%

R

05/07/10 08:38:49 02 5.52

%

R CO2 13.92

%

R

05/07/10 08:38:59 02 5.53

%

R CO2 13.67

%

R

05/07/10 08:39:09 02 5.55

%

R CO2 13.55

%

R

05/07/10 08:39:19 02 5.58

%

R CO2 13.67

%

R

6
05/07/10 08:39:29 02 5.62

%

R CO2 13.79

%

R

05/07/10 08:39:39 02 5.63

%

R CO2 13.55

%

R

05/07/10 08:39:49 02 5.65

%

R CO2 13.55

%

R

05/07/10 08:39:59 02 5.69

%

R CO2 13.67

%

R

05/07/10 08:40:09 02 5.74

%

R CO2 13.55

%

R

05/07/10 08:40:19 02 5.81

%

R CO2 13.55

%

R

05/07/10 08:40:29 02 5.86

%

R CO2 13.55

%

R

05/07/10 08:40:39 02 5.92

%R CO2 13.31

%

R

05/07/10 08:40:49 02 5.97

%

R CO2 13.43

%

R

05/07/10 08:40:59 02 6.01

%R CO2 13.43

%

R

05/07/10 08:41:09 02 6.01

%

R CO2 13.55

%

R

05/07/10 08:41:19 02 5.94

%

R CO2 13.31

%

R

05/07/10 08:41:29 02 5.87

%R CO2 13.43

%

R

05/07/10 08:41:39 02 5.81

%

R CO2 13.79

%

R

05/07/10 08:41:49 02 5.77

%

R CO2 13.31

%

R

05/07/10 08:41:59 02 5.77

%

R CO2 13.43

%

R

05/07/10 08:42:09 02 5.80

%

R CO2 13.43

%

R

05/07/10 08:42:19 02 5.86

%

R CO2 13.55

%

R

05/07/10 08:42:29 02 5.94

%

R CO2 13.43

%

R

05/07/10 08:42:39 02 5.99

%

R CO2 13.18

%

R

05/07/10 08:42:49 02 5.99

%

R CO2 13.31

%

R

05/07/10 08:42:59 02 5.96

%

R CO2 13.55

%

R

05/07/10 08:43:09 02 5.93

%

R CO2 13.43

%

R

05/07/10 08:43:19 02 5.92

%

R CO2 13.55

%

R

05/07/10 08:43:29 02 5.86

%

R CO2 13.18

%

R

05/07/10 08:43:39 02 5.80

%

R CO2 13.31

%

R

05/07/10 08:43:49 02 5.74

%

R CO2 13.55

%

R

05/07/10 08:43:59 02 5.70

%

R CO2 13.55

%

R

05/07/10 08:44:09 02 5.73

%

R CO2 13.67

%

R

05/07/10 08:44:19 02 5.76

%

R CO2 13.55

%

R

05/07/10 08:44:29 02 5.80

%

R CO2 13.67

%

R

05/07/10 08:44:39 02 5.81

%

R CO2 13.31

%

R

05/07/10 08:44:49 02 5.81

%

R CO2 13.43

%

R

05/07/10 08:44:59 02 5.83

%

R CO2 13.67

%

R

05/07/10 08:45:09 02 5.86

%

R CO2 13.31

%

R

05/07/10 08:45:19 02 5.87

%

R CO2 13.55

%

R

05/07/10 08:45:29 02 5.83

%

R CO2 13.31

%

R

05/07/10 08:45:39 02 5.81

%

R CO2 13.55

%

R

05/07/10 08:45:49 02 5.79

%

R CO2 13.67

%

R

05/07/10 08:45:59 02 5.76

%

R CO2 13.43

%

R

05/07/10 08:46:09 02 5.75

%

R CO2 13.55

%

R

05/07/10 08:46:19 02 5.74

%

R CO2 13.31

%

R

05/07/10 08:46:29 02 5.75

%

R CO2 13.43

%

R

05/07/10 08:46:39 02 5.76

%

R CO2 13.67

%

R

05/07/10 08:46:49 02 5.80

%

R CO2 13.43

%

R

05/07/10 08:46:59 02 5.79

%

R CO2 13.43

%

R

05/07/10 08:47:09 02 5.76

%

R CO2 13.43

%

R

05/07/10 08:47:19 02 5.71

%

R CO2 13.55

%

R

05/07/10 08:47:29 02 5.71

%

R CO2 13.67

%

R

05/07/10 08:47:39 02 5.73

%

R CO2 13.67

%

R

05/07/10 08:47:49 02 5.76

%

R CO2 13.67

%

R

05/07/10 08:47:59 02 5.80

%

R CO2 13.31

%

R

05/07/10 08:48:09 02 5.82

%

R CO2 13.55

%

R

05/07/10 08:48:19 02 5.85

%

R CO2 13.92

%

R

7
05/07/10 08:48:29 02 5.87

%

R CO2 13.43

%

R

05/07/10 08:48:39 02 5.87

%

R CO2 13.43

%

R

05/07/10 08:48:49 02 5.82

%

R CO2 13.55

%

R

05/07/10 08:48:59 02 5.77

%

R CO2 13.31

%

R

05/07/10 08:49:09 02 5.75

%

R CO2 13.55

%

R

05/07/10 08:49:19 02 5.74

%

R CO2 13.67

%

R

05/07/10 08:49:29 02 5.69

%

R CO2 13.67

%

R

05/07/10 08:49:39 02 5.65

%

R CO2 13.43

%

R

05/07/10 08:49:49 02 5.57

%

R CO2 13.55

%

R

05/07/10 08:49:59 02 5.49

%

R CO2 13.43

%

R

05/07/10 08:50:09 02 5.44

%

R CO2 13.67

%

R

05/07/10 08:50:19 02 5.42

%

R CO2 13.92

%

R

05/07/10 08:50:29 02 5.41

%

R CO2 13.92

%

R

05/07/10 08:50:39 02 5.42

%

R CO2 13.67

%

R

05/07/10 08:50:49 02 5.49

%

R CO2 13.67

%

R

05/07/10 08:50:59 02 5.57

%

R CO2 13.67

%

R

05/07/10 08:51:09 02 5.66

%

R CO2 13.55

%

R

05/07/10 08:51:19 02 5.74

%

R CO2 13.43

%

R

05/07/10 08:51:29 02 5.74

%

R CO2 13.55

%

R

05/07/10 08:51:39 02 5.75

%

R CO2 13.55

%

R

05/07/10 08:51 :49 02 5.79

%

R CO2 13.67

%

R

05/07/10 08:51:59 02 5.81

%

R CO2 13.43

%

R

05/07/10 08:52:09 02 5.81

%

R CO2 13.43

%

R

05/07/10 08:52:19 02 5.81

%

R CO2 13.43

%

R

05/07/10 08:52:29 02 5.82

%

R CO2 13.55

%

R

05/07/10 08:52:39 02 5.86

%

R CO2 13.43

%

R

05/07/10 08:52:49 02 5.86

%

R CO2 13.43

%

R

05/07/10 08:52:59 02 5.82

%

R CO2 13.43

%

R

05/07/10 08:53:09 02 5.77

%

R CO2 13.43

%

R

05/07/10 08:53:19 02 5.74

%

R CO2 13.67

%

R

05/07/10 08:53:29 02 5.74

%R CO2 13.18

%

R

05/07/10 08:53:39 02 5.76

%

R CO2 13.43

%

R

05/07/10 08:53:49 02 5.79

%

R CO2 13.67

%

R

05/07/10 08:53:59 02 5.80

%

R CO2 13.55

%

R

05/07/10 08:54:09 02 5.80

%

R CO2 13.92

%

R

05/07/10 08:54:19 02 5.80

%

R CO2 13.67

%

R

05/07/10 08:54:29 02 5.76

%

R CO2 13.55

%

R

05/07/10 08:54:39 02 5.71

%

R CO2 13.55

%

R

05/07/10 08:54:49 02 5.69

%

R CO2 13.55

%

R

05/07/10 08:54:59 02 5.69

%R CO2 13.67

%

R

05/07/10 08:55:09 02 5.70

%

R CO2 13.67

%

R

05/07/10 08:55:19 02 5.66

%

R CO2 13.55

%

R

05/07/10 08:55:29 02 5.62

%

R CO2 13.67

%

R

05/07/10 08:55:39 02 5.55

%

R CO2 13.55

%

R

05/07/10 08:55:49 02 5.52

%

R CO2 13.55

%

R

05/07/10 08:55:59 02 5.48

%

R CO2 13.79

%

R

05/07/10 08:56:09 02 5.46

%

R CO2 13.79

%

R

05/07/10 08:56:19 02 5.46

%

R CO2 13.79

%

R

05/07/10 08:56:29 02 5.43

%

R CO2 13.92

%

R

05/07/10 08:56:39 02 5.38

%

R CO2 13.92

%

R

05/07/10 08:56:49 02 5.35

%

R CO2 13.79

%

R

05/07/10 08:56:59 02 5.32

%

R CO2 13.79

%

R

05/07/10 08:57:09 02 5.29

%R CO2 13.79

%

R

05/07/10 08:57:19 02 5.27

%R CO2 13.79

%

R

8
05/07/10 08:57:29 02 5.30

%R CO2 13.92

%

R

05107/10 08:57:39 02 5.33

%

R CO2 13.79

%

R

05/07/10 08:57:49 02 5.38

%R CO2 13.92

%

R

05/07/10 08:57:59 02 5.44

%R CO2 13.92

%

R

05/07/10 08:58:09 02 5.49

%R CO2 13.55

%

R

05/07/10 08:58:19 02 5.52

%R CO2 13.67

%

R

05/07/10 08:58:29 02 5.52

%R CO2 13.92

%

R

05/07/10 08:58:39 02 5.51

%

R CO2 13.67

%

R

05/07/10 08:58:49 02 5.51

%R CO2 13.67

%

R

05/07/10 08:58:59 02 5.53

%R CO2 13.79

%

R

05/07/10 08:59:09 02 5.58

%R CO2 13.92

%

R

05/07/10 08:59:19 02 5.64

%R CO2 13.67

%

R

05/07/10 08:59:29 02 5.71

%R CO2 13.79

%

R

05/07/10 08:59:39 02 5.73

%R CO2 13.55

%

R

05/07/10 08:59:49 02 5.69

%

R CO2 13.55

%

R

05/07/10 08:59:59 02 5.63

%R CO2 13.55

%

R

05/07/10 09:00:09 02 5.57

%R CO2 13.67

%

R

05/07/10 09:00:19 02 5.53

%R CO2 13.79

%

R

05/07/10 09:00:29 02 5.53

%

R CO2 13.67

%

R

05/07/10 09:00:39 02 5.55

%R CO2 13.55

%

R

05/07/10 09:00:49 02 5.58

%R CO2 13.55

%

R

05/07/10 09:00:59 02 5.59

%R CO2 13.67

%

R

05/07/10 09:01:09 02 5.60

%

R CO2 13.67

%

R

05/07/10 09:01:19 02 5.59

%R CO2 13.92

%

R

05/07/10 09:01:29 02 5.60

%R CO2 13.79

%

R

05/07/10 09:01:39 02 5.59

%R CO2 13.79

%

R

05/07/10 09:01:49 02 5.55

%R CO2 13.92

%

R

05/07/10 09:01:59 02 5.53

%R CO2 13.67

%

R

05/07/10 09:02:09 02 5.48

%

R CO2 13.79

%

R

05/07/10 09:02:19 02 5.42

%R CO2 13.92

%

R

05/07/10 09:02:29 02 5.33

%

R CO2 14.04

%

R

05/07/10 09:02:39 02 5.27

%R CO2 14.04

%

R

05/07/10 09:02:49 02 5.22

%R CO2 14.04

%

R

05/07/10 09:02:59 02 5.20

%R CO2 13.79

%

R

05/07/10 09:03:09 02 5.21

%R CO2 14.16

%

R

05/07/10 09:03:19 02 5.22

%R CO2 14.04

%

R

05/07/10 09:03:29 02 5.22

%

R CO2 14.04

%

R

05/07/10 09:03:39 02 5.24

%R CO2 13.79

%

R

05/07/10 09:03:49 02 5.24

%

R CO2 13.92

%

R

05/07/10 09:03:59 02 5.26

%R CO2 14.04

%

R

05/07/10 09:04:09 02 5.31

%R CO2 13.92

%

R

05/07/10 09:04:19 02 5.35

%R CO2 13.79

%

R

05/07/10 09:04:29 02 5.38

%R CO2 14.04

%

R

05/07/10 09:04:39 02 5.40

%R CO2 13.79

%

R

05/07/10 09:04:49 02 5.41

%

R CO2 13.92

%

R

05/07/10 09:04:59 02 5.46

%R CO2 13.92

%

R

05/07/10 09:05:09 02 5.51

%R CO2 13.92

%

R

05/07/10 09:05:19 02 5.57

%R CO2 13.79

%

R

05/07/10 09:05:29 02 5.59

%R CO2 13.67

%

R

05/07/10 09:05:39 02 5.58

%R CO2 13.79

%

R

05/07/10 09:05:49 02 5.54

%R CO2 13.67

%

R

05/07/10 09:05:59 02 5.47

%R CO2 13.92

%

R

05/07/10 09:06:09 02 5.41

%R CO2 13.92

%

R

05/07/10 09:06:19 02 5.36

%R CO2 14.04

%

R

9
05/07/10 09:06:29 02 5.32

%

R CO2 14.04

%

R

05/07/10 09:06:39 02 5.27

%

R CO2 13.92

%

R

05/07/10 09:06:49 02 5.25

%

R CO2 14.04

%

R

05/07/10 09:06:59 02 5.24

%

R CO2 13.92

%

R

05/07/10 09:07:09 02 5.22

%

R CO2 13.79

%

R

05/07/10 09:07:19 02 5.16

%

R CO2 13.92

%

R

05/07/10 09:07:29 02 5.07

%

R CO2 14.04

%

R

05/07/10 09:07:39 02 4.96

%

R CO2 14.04

%

R

05/07/10 09:07:49 02 4.90

%

R CO2 14.16

%

R

05/07/10 09:07:59 02 4.86

%R CO2 14.16

%

R

05/07/10 09:08:09 02 4.83

%

R CO2 14.40

%

R

05/07/10 09:08:19 02 4.81

%R CO2 14.16

%

R

05/07/10 09:08:29 02 4.77

%

R CO2 14.40

%

R

05/07/10 09:08:39 02 4.77

%

R CO2 14.28

%

R

05/07/10 09:08:49 02 4.77

%

R CO2 14.28

%

R

05/07/10 09:08:59 02 4.81

%R CO2 14.40

%

R

05/07/10 09:09:09 02 4.93

%

R CO2 14.40

%

R

05/07/10 09:09:19 02 5.10

%

R CO2 14.16

%

R

05/07/10 09:09:29 02 5.29

%

R CO2 14.16

%

R

05/07/10 09:09:39 02 5.48

%

R CO2 13.79

%

R

05/07/10 09:09:49 02 5.60

%

R CO2 13.79

%

R

05/07/10 09:09:59 02 5.64

%

R CO2 14.04

%

R

05/07/10 09:10:09 02 5.62

%R CO2 13.79

%

R

05/07/10 09:10:19 02 5.58

%

R CO2 13.79

%

R

05/07/10 09:10:29 02 5.55

%

R CO2 13.79

%

R

05/07/10 09:10:39 02 5.53

%R CO2 13.92

%

R

05/07/10 09:10:49 02 5.46

%

R CO2 13.79

%

R

05/07/10 09:10:59 02 5.36

%

R CO2 13.92

%

R

05/07/10 09:11:09 02 5.25

%

R CO2 14.16

%

R

05/07/10 09:11:19 02 5.18

%R CO2 14.16

%

R

05/07/10 09:11 :29 02 5.16

%

R CO2 13.92

%

R

05/07/10 09:11 :39 02 5.18

%R CO2 14.04

%

R

05/07/10 09:11:49 02 5.20

%R CO2 14.16

%

R

05/07/10 09:11 :59 02 5.21

%

R CO2 14.28

%

R

05/07/10 09:12:09 02 5.24

%R CO2 14.04

%

R

05/07/10 09:12:19 02 5.26

%R CO2 13.79

%

R

05/07/10 09:12:29 02 5.30

%

R CO2 13.79

%

R

05/07/10 09:12:39 02 5.32

%

R CO2 13.79

%

R

05/07/10 09:12:49 02 5.33

%

R CO2 14.04

%

R

05/07/10 09:12:59 02 5.33

%

R CO2 13.92

%

R

05/07/10 09:13:09 02 5.33

%

R CO2 14.04

%

R

05/07/10 09:13:19 02 5.35

%

R CO2 13.92

%

R

05/07/10 09:13:29 02 5.36

%

R CO2 13.92

%

R

05/07/10 09:13:39 02 5.33

%

R CO2 13.79

%

R

05/07/10 09:13:49 02 5.32

%

R CO2 13.92

%

R

05/07/10 09:13:59 02 5.32

%

R CO2 13.92

%

R

05/07/10 09:14:09 02 5.35

%

R CO2 13.67

%

R

05/07/10 09:14:19 02 5.36

%R CO2 13.92

%

R

05/07/10 09:14:29 02 5.35

%R CO2 14.04

%

R

05/07/10 09:14:39 02 5.36

%

R CO2 13.92

%

R

05/07/10 09:14:49 02 5.41

%R CO2 13.79

%

R

05/07/10 09:14:59 02 5.43

%

R CO2 13.79

%

R

05/07/10 09:15:09 02 5.58

%

R CO2 13.67

%

R

05/07/10 09:15:19 02 5.51

%

R CO2 13.67

%

R

10
05/07/10 09:15:29 02 5.51

%R CO2 13.67

%

R

05/07/10 09:15:39 02 5.48

%

R CO2 13.67

%

R

05/07/10 09:15:49 02 5.46

%R CO2 13.67

%

R

05/07/10 09:15:59 02 5.47

%

R CO2 14.04

%

R

05/07/10 09:16:09 02 5.47

%R CO2 13.92

%

R

05/07/10 09:16:19 02 5.51

%R CO2 13.79

%

R

05/07/10 09:16:29 02 5.53

%R CO2 13.92

%

R

05/07/10 09:16:39 02 5.54

%R CO2 13.67

%

R

05/07/10 09:16:49 02 5.53

%R CO2 13.67

%

R

05/07/10 09:16:59 02 5.53

%R CO2 13.67

%

R

05/07/10 09:17:09 02 5.54

%R CO2 13.79

%

R

05/07/10 09:17:19 02 5.55

%

R CO2 13.67

%

R

05/07/10 09:17:29 02 5.55

%

R CO2 13.67

%

R

05/07/10 09:17:39 02 5.55

%

R CO2 13.67

%

R

05/07/10 09:17:49 02 5.53

%R CO2 14.04

%

R

05/07/10 09:17:59 02 5.52

%

R CO2 13.79

%

R

05/07/10 09:18:09 02 5.51

%

R CO2 13.92

%

R

05/07/10 09:18:19 02 5.44

%

R CO2 14.04

%

R

05/07/10 09:18:29 02 5.37

%

R CO2 13.92

%

R

05/07/10 09:18:39 02 5.27

%R CO2 13.79

%

R

05/07/10 09:18:49 02 5.20

%

R CO2 14.40

%

R

05/07/10 09:18:59 02 5.15

%R CO2 14.16

%

R

05/07/10 09:19:09 02 5.14

%

R CO2 13.92

%

R

05/07/10 09:19:19 02 5.10

%

R CO2 14.28

%

R

05/07/10 09:19:29 02 5.00

%

R CO2 14.40

%

R

05/07/10 09:19:39 02 4.97

%

R CO2 14.16

%

R

05/07/10 09:19:49 02 4.97

%

R CO2 14.16

%

R

05/07/10 09:19:59 02 5.00

%

R CO2 14.28

%

R

05/07/10 09:20:09 02 5.04

%R CO2 14.04

%

R

05/07/10 09:20:19 02 5.09

%R CO2 14.28

%

R

05/07/10 09:20:29 02 5.13

%

R CO2 14.16

%

R

05/07/10 09:20:39 02 5.11

%R CO2 14.04

%

R

05/07/10 09:20:49 02 5.09

%R CO2 13.92

%

R

05/07/10 09:20:59 02 5.04

%

R CO2 14.28

%

R

05/07/10 09:21:09 02 5.03

%R CO2 14.16

%

R

05/07/10 09:21:19 02 5.07

%

R CO2 14.04

%

R

05/07/10 09:21 :29 02 5.10

%R CO2 14.16

%

R

05/07/10 09:21:39 02 5.13

%

R CO2 14.16

%

R

05/07/10 09:21:49 02 5.10

%

R CO2 14.16

%

R

05/07/10 09:21:59 02 5.07

%R CO2 14.04

%

R

05/07/10 09:22:09 02 5.03

%

R CO2 14.16

%

R

05/07/10 09:22:19 02 4.99

%

R CO2 14.40

%

R

05/07/10 09:22:29 02 5.00

%

R CO2 14.16

%

R

05/07/10 09:22:39 02 5.04

%

R CO2 14.28

%

R

05/07/10 09:22:49 02 5.10

%

R CO2 14.04

%

R

05/07/10 09:22:59 02 5.15

%R CO2 14.16

%

R

05/07/10 09:23:09 02 5.21

%R CO2 14.16

%

R

05/07/10 09:23:19 02 5.25

%

R CO2 14.04

%

R

05/07/10 09:23:29 02 5.26

%

R CO2 14.04

%

R

05/07/10 09:23:39 02 5.26

%R CO2 13.92

%

R

05/07/10 09:23:49 02 5.24

%R CO2 13.92

%

R

05/07/10 09:23:59 02 5.21

%R CO2 13.92

%

R

05/07/10 09:24:09 02 5.16

%R CO2 14.16

%

R

05/07/10 09:24:19 02 5.13

%R CO2 14.04

%

R

11
05/07/10 09:24:29 02 5.13

%

R CO2 14.16

%

R

05/07/10 09:24:39 02 5.18

%

R CO2 14.16

%

R

05/07/10 09:24:49 02 5.25

%R CO2 14.04

%

R

05/07/10 09:24:59 02 5.29

%

R CO2 14.04

%

R

05/07/10 09:25:09 02 5.26

%

R CO2 14.04

%

R

05/07/10 09:25:19 02 5.26

%

R CO2 14.04

%

R

05/07/10 09:25:29 02 5.32

%

R CO2 13.92

%

R

05/07/10 09:25:39 02 5.40

%

R CO2 14.04

%

R

05/07/10 09:25:49 02 5.47

%R CO2 13.92

%

R

05/07/10 09:25:59 02 5.52

%

R CO2 13.92

%

R

05/07/10 09:26:09 02 5.51

%

R CO2 13.92

%

R

05/07/10 09:26:19 02 5.46

%

R CO2 14.04

%

R

05/07/10 09:26:29 02 5.42

%

R CO2 13.79

%

R

05/07/10 09:26:39 02 5.42

%

R CO2 13.92

%

R

05/07/10 09:26:49 02 5.44

%

R CO2 14.28

%

R

05/07/10 09:26:59 02 5.49

%

R CO2 13.79

%

R

05/07/10 09:27:09 02 5.53

%

R CO2 13.67

%

R

05/07/10 09:27:19 02 5.60

%

R CO2 13.67

%

R

05/07/10 09:27:29 02 5.68

%

R CO2 13.55

%

R

05/07/10 09:27:39 02 5.70

%R CO2 13.43

%

R

05/07/10 09:27:49 02 5.79

%

R CO2 13.67

%

R

05/07/10 09:27:59 02 5.88

%

R CO2 13.31

%

R

05/07/10 09:28:09 02 5.93

%

R CO2 13.31

%

R

05/07/10 09:28:19 02 5.98

%

R CO2 13.31

%

R

05/07/10 09:28:29 02 6.01

%

R CO2 13.31

%

R

05/07/10 09:28:39 02 6.01

%

R CO2 13.31

%

R

05/07/10 09:28:49 02 5.99

%

R CO2 13.43

%

R

05/07/10 09:28:59 02 5.99

%R CO2 13.18

%

R

05/07/10 09:29:09 02 5.96

%

R CO2 13.43

%

R

05/07/10 09:29:19 02 5.92

%

R CO2 13.43

%

R

05/07/10 09:29:29 02 5.86

%

R CO2 13.55

%

R

05/07/10 09:29:39 02 5.82

%

R CO2 13.43

%

R

05/07/10 09:29:49 02 5.83

%

R CO2 13.43

%

R

05/07/10 09:29:59 02 5.86

%

R CO2 13.55

%

R

Avg 5.55 13.73

12
Post1 Bias James River Cogen

Unit NO.2

Post Run1 Bias Metals/PM-10

05/07110 09:31:23 02 1.22

%

R CO2 1.46

%

R

05/07/10 09:31:24 02 1.06

%

R CO2 1.34

%

R

05/07/10 09:31:29 02 0.71

%R CO2 0.85

%

R

05/07/10 09:31:34 02 0.48

%

R CO2 0.61

%

R

05/07/10 09:31:39 02 0.32

%

R CO2 0.24

%

R

05/07/10 09:31:44 02 0.22

%

R CO2 0.24

%

R

05/07/10 09:31:49 02 0.20

%

R CO2 0.37

%

R

05/07/10 09:31:54 02 0.10

%

R CO2 0.24

%

R

05/07/10 09:31:59 02 0.07

%R CO2 0.12

%

R

05/07/10 09:32:04 02 0.05

%

R CO2 0.24

%

R

05/07/10 09:32:09 02 0.05

%

R CO2 -0.12

%

R

05/07/10 09:32:14 02 0.05

%

R CO2 0.12

%

R

05/07/10 09:32:19 02 0.06

%R CO2 -0.12

%

R

05/07/10 09:32:24 02 0.05

%

R CO2 0.00

%

R

05/07/10 09:32:29 02 0.05

%R CO2 0.00

%

R

05/07/10 09:32:34 02 0.05

%R CO2 0.12

%

R

05/07/10 09:32:39 02 0.05

%

R CO2 0.24

%

R

05/07/10 09:32:44 02 0.20

%

R CO2 0.49

%

R

05/07/10 09:32:49 02 2.56

%R CO2 1.22

%

R

05/07/10 09:32:54 02 6.40

%

R CO2 3.54

%

R

05/07/10 09:32:59 02 8.98

%

R CO2 5.49

%

R

05/07/10 09:33:04 02 10.56

%

R CO2 6.10

%

R

05/07/10 09:33:09 02 11.40

%R CO2 6.59

%

R

05/07/10 09:33:14 02 11.85

%

R CO2 6.96

%

R

05/07/10 09:33:19 02 12.10

%R CO2 7.20

%

R

05/07/10 09:33:24 02 12.24

%

R CO2 7.20

%

R

05/07/10 09:33:29 02 12.35

%

R CO2 7.08

%

R

05/07/10 09:33:34 02 12.41

%R CO2 7.57

%

R

05/07/10 09:33:39 02 12.45

%

R CO2 7.20

%

R

05/07/10 09:33:44 02 12.45

%R CO2 7.32

%

R

05/07/10 09:33:49 02 12.48

%R CO2 7.32

%

R

05/07/10 09:33:54 02 12.49

%

R CO2 7.45

%

R

05/07/10 09:33:59 02 12.49

%R CO2 7.45

%

R

05/07/10 09:34:04 02 12.49

%

R CO2 7.45

%

R

05/07/10 09:34:09 02 12.50

%

R CO2 7.45

%

R

05/07/10 09:34:14 02 12.50

%

R CO2 7.45

%

R

05/07/10 09:34:19 02 12.50

%

R CO2 7.45

%

R

05/07/10 09:34:24 02 12.50

%

R CO2 7.45

%

R

05/07/10 09:34:29 02 13.70

%R CO2 7.81

%

R

05/07/10 09:34:34 02 16.59

%R CO2 9.28

%

R

05/07/10 09:34:39 02 18.81

%

R CO2 10.50

%

R

05/07/10 09:34:44 02 20.15

%

R CO2 11.11

%

R

05/07/10 09:34:49 02 20.96

%R CO2 11.47

%

R

05/07/10 09:34:54 02 21.44

%

R CO2 11.72

%

R

05/07/10 09:34:59 02 21.69

%R CO2 12.08

%

R

05/07/10 09:35:04 02 21.84

%

R CO2 12.33

%

R

05/07/10 09:35:09 02 21.90

%

R CO2 12.21

%

R

05/07/10 09:35:14 02 21.92

%R CO2 12.21

%

R

05/07/10 09:35:19 02 21.98

%

R CO2 12.45

%

R

13
Run2 James River Cogen

Unit NO.2

Run NO.2 Metals/PM-10

05/07/10 09:52:27 02 5.43 % R CO2 13.67

%

R

05/07/10 09:52:29 02 5.44

%

R CO2 13.67

%

R

05/07/10 09:52:39 02 5.46

%

R CO2 13.55

%

R

05/07/10 09:52:49 02 5.46 % R CO2 13.79

%

R

05/07/10 09:52:59 02 5.46

%

R CO2 13.92

%

R

05/07/10 09:53:09 02 5.46 % R CO2 14.16

%

R

05/07/10 09:53:19 02 5.42 % R CO2 13.67

%

R

05/07/10 09:53:29 02 5.44 % R CO2 13.79

%

R

05/07/10 09:53:39 02 5.52 % R CO2 13.67

%

R

05/07/10 09:53:49 02 5.54 % R CO2 13.79

%

R

05/07/10 09:53:59 02 5.54

%

R CO2 13.67

%

R

05/07/10 09:54:09 02 5.58 % R CO2 13.67

%

R

05/07/10 09:54:19 02 5.62 % R CO2 13.55

%

R

05/07/10 09:54:29 02 5.64

%

R CO2 13.43

%

R

05/07/10 09:54:39 02 5.66 % R CO2 13.67

%

R

05/07/10 09:54:49 02 5.68 % R CO2 13.55

%

R

05/07/10 09:54:59 02 5.69 % R CO2 13.67

%

R

05/07/10 09:55:09 02 5.73 % R CO2 13.43

%

R

05/07/10 09:55:19 02 5.81

%

R CO2 13.55

%

R

05/07/10 09:55:29 02 5.87

%

R CO2 13.43

%

R

05/07/10 09:55:39 02 5.90

%

R CO2 13.43

%

R

05/07/10 09:55:49 02 5.90 % R CO2 13.67

%

R

05/07/10 09:55:59 02 5.92

%

R CO2 13.31

%

R

05/07/10 09:56:09 02 5.97 % R CO2 13.31

%

R

05/07/10 09:56:19 02 6.03 % R CO2 13.43

%

R

05/07/10 09:56:29 02 6.03

%

R CO2 13.31

%

R

05/07/10 09:56:39 02 6.03 % R CO2 13.67

%

R

05/07/10 09:56:49 02 6.04

%

R CO2 13.43

%

R

05/07/10 09:56:59 02 6.05 % R CO2 13.43

%

R

05/07/10 09:57:09 02 6.10 % R CO2 13.18

%

R

05/07/10 09:57:19 02 6.16 % R CO2 13.06

%

R

05/07/10 09:57:29 02 6.24

%

R CO2 12.94

%

R

05/07/10 09:57:39 02 6.35

%

R CO2 13.18

%

R

05/07/10 09:57:49 02 6.49 % R CO2 12.82

%

R

05/07/10 09:57:59 02 6.67 % R CO2 12.57

%

R

05/07/10 09:58:09 02 6.81

%

R CO2 12.70

%

R

05/07/10 09:58:19 02 6.88 % R CO2 12.82

%

R

05/07/10 09:58:29 02 6.90 % R CO2 12.70

%

R

05/07/10 09:58:39 02 6.84 % R CO2 12.94

%

R

05/07/10 09:58:49 02 6.74 % R CO2 12.82

%

R

05/07/10 09:58:59 02 6.62 % R CO2 12.82

%

R

05/07/10 09:59:09 02 6.52

%

R CO2 13.06

%

R

05/07/10 09:59:19 02 6.48

%

R CO2 13.18

%

R

05/07/10 09:59:29 02 6.54 % R CO2 12.82

%

R

05/07/10 09:59:39 02 6.64 % R CO2 12.70

%

R

05/07/10 09:59:49 02 6.69 % R CO2 12.57

%

R

05/07/10 09:59:59 02 6.65

%

R CO2 12.82

%

R

05/07/10 10:00:09 02 6.53

%

R CO2 12.94

%

R

05/07/10 10:00:19 02 6.40 % R CO2 13.06

%

R

05/07/10 10:00:29 02 6.35 % R CO2 12.70

%

R

14
05/07/10 10:00:39 02 6.31

%

R CO2 12.94

%

R

05/07/10 10:00:49 02 6.24

%R CO2 13.06

%

R

05/07/10 10:00:59 02 6.14

%

R CO2 13.06

%

R

05/07/10 10:01 :09 02 6.09

%R CO2 13.06

%

R

05/07/10 10:01:19 02 6.10

%

R CO2 13.31

%

R

05/07/10 10:01 :29 02 6.14

%

R CO2 13.18

%

R

05/07/10 10:01 :39 02 6.18

%

R CO2 13.06

%

R

05/07/10 10:01 :49 02 6.20

%

R CO2 12.94

%

R

05/07/10 10:01 :59 02 6.20

%

R CO2 12.82

%

R

05/07/10 10:02:09 02 6.18

%

R CO2 13.18

%

R

05/07/10 10:02:19 02 6.10

%R CO2 13.31

%

R

05/07/10 10:02:29 02 5.99

%R CO2 13.18

%

R

05/07/10 10:02:39 02 5.91

%R CO2 13.31

%

R

05/07/10 10:02:49 02 5.88

%

R CO2 13.67

%

R

05/07/10 10:02:59 02 5.90

%

R CO2 13.18

%

R

05/07/10 10:03:09 02 5.90

%R CO2 13.43

%

R

05/07/10 10:03:19 02 5.88

%R CO2 13.55

%

R

05/07/10 10:03:29 02 5.85

%

R CO2 13.31

%

R

05/07/10 10:03:39 02 5.82

%R CO2 13.18

%

R

05/07/10 10:03:49 02 5.81

%

R CO2 13.31

%

R

05/07/10 10:03:59 02 5.79

%R CO2 13.18

%

R

05/07/10 10:04:09 02 5.75

%

R CO2 13.18

%

R

05/07/10 10:04:19 02 5.74

%

R CO2 13.55

%

R

05/07/10 10:04:29 02 5.71

%R CO2 13.43

%

R

05/07/10 10:04:39 02 5.69

%R CO2 13.31

%

R

05/07/10 10:04:49 02 5.66

%R CO2 13.43

%

R

05/07/10 10:04:59 02 5.59

%R CO2 13.18

%

R

05/07/10 10:05:09 02 5.55

%R CO2 13.55

%

R

05/07/10 10:05:19 02 5.53

%

R CO2 13.43

%

R

05/07/10 10:05:29 02 5.54

%R CO2 13.43

%

R

05/07/10 10:05:39 02 5.55

%

R CO2 13.55

%

R

05/07/10 10:05:49 02 5.57

%

R CO2 13.43

%

R

05/07/10 10:05:59 02 5.57

%

R CO2 13.55

%

R

05/07/10 10:06:09 02 5.59

%

R CO2 13.55

%

R

05/07/10 10:06:19 02 5.63

%

R CO2 13.43

%

R

05/07/10 10:06:29 02 5.65

%

R CO2 13.31

%

R

05/07/10 10:06:39 02 5.68

%

R CO2 13.43

%

R

05/07/10 10:06:49 02 5.73

%

R CO2 13.43

%

R

05/07/10 10:06:59 02 5.76

%

R CO2 13.31

%

R

05/07/10 10:07:09 02 5.77

%

R CO2 13.18

%

R

05/07/10 10:07:19 02 5.75

%

R CO2 13.31

%

R

05/07/10 10:07:29 02 5.70

%R CO2 13.43

%

R

05/07/10 10:07:39 02 5.64 0%

R CO2 13.43

%

R

05/07/10 10:07:49 02 5.62

%R CO2 13.43

%

R

05/07/10 10:07:59 02 5.63

%

R CO2 13.31

%

R

05/07/10 10:08:09 02 5.63

%

R CO2 13.43

%

R

05/07/10 10:08:19 02 5.64

%

R CO2 13.55

%

R

05/07/10 10:08:29 02 5.65

%R CO2 13.67

%

R

05/07/10 10:08:39 02 5.69

%

R CO2 13.43

%

R

05/07/10 10:08:49 02 5.75

%R CO2 13.31

%

R

05/07/10 10:08:59 02 5.82

%

R CO2 13.31

%

R

05/07/10 10:09:09 02 5.87

%R CO2 13.43

%

R

05/07/10 10:09:19 02 5.91

%

R CO2 13.43

%

R

05/07/10 10:09:29 02 5.92

%

R CO2 13.43

%

R

15
05/07/10 10:09:39 02 5.93

%R CO2 13.31

%

R

05/07/10 10:09:49 02 5.93

%

R CO2 13.43

%

R

05/07/10 10:09:59 02 5.92

%R CO2 13.55

%

R

05/07/10 10:10:09 02 5.91

%R CO2 13.31

%

R

05/07/10 10:10:19 02 5.91

%R CO2 13.31

%

R

05/07/10 10:10:29 02 5.92

%R CO2 13.55

%

R

05/07/10 10:10:39 02 5.93

%R CO2 13.31

%

R

05/07/10 10:10:49 02 5.96

%R CO2 13.18

%

R

05/07/10 10:10:59 02 5.96

%

R CO2 13.55

%

R

05/07/10 10:11:09 02 5.94

%R CO2 13.43

%

R

05/07/10 10:11:19 02 5.98

%R CO2 13.55

%

R

05/07/10 10:11:29 02 6.04

%R CO2 13.31

%

R

05/07/10 10:11:39 02 6.07

%R CO2 13.43

%

R

05/07/10 10:11:49 02 6.12

%R CO2 13.18

%

R

05/07/10 10:11 :59 02 6.15

%R CO2 13.43

%

R

05/07/10 10:12:09 02 6.18

%R CO2 13.31

%

R

05/07/10 10:12:19 02 6.16

%R CO2 13.18

%

R

05/07/10 10:12:36 02 6.07

%R CO2 13.18

%

R

05/07/10 10:12:49 02 5.98

%R CO2 13.31

%

R

05/07/10 10:13:09 02 5.90

%R CO2 13.43

%

R

05/07/10 10:13:29 02 5.82

%R CO2 13.31

%

R

05/07/10 10:13:49 02 5.87

%

R CO2 13.55

%

R

05/07/10 10:14:09 02 6.02

%R CO2 13.31

%

R

05/07/10 10:14:29 02 6.16

%R CO2 13.31

%

R

05/07/10 10:14:49 02 6.13

%R CO2 13.18

%

R

05/07/10 10:15:09 02 5.92

%R CO2 13.43

%

R

05/07/10 10:15:29 02 5.77

%

R CO2 13.55

%

R

05/07/10 10:15:49 02 5.80

%R CO2 13.18

%

R

05/07/10 10:16:09 02 5.87

%R CO2 13.31

%

R

05/07/10 10:16:29 02 5.86

%R CO2 13.43

%

R

05/07/10 10:16:49 02 5.80

%R CO2 13.31

%

R

05/07/10 10:17:09 02 5.79

%R CO2 13.43

%

R

05/07/10 10:17:29 02 5.73

%R CO2 13.55

%

R

05/07/10 10:17:49 02 5.71

%R CO2 13.18

%

R

05/07/10 10:18:09 02 5.76

%R CO2 13.55

%

R

05/07/10 10:18:29 02 5.76

%R CO2 13.31

%

R

05/07/10 10:18:49 02 5.75

%R CO2 13.18

%

R

05/07/10 10:19:09 02 5.73

%R CO2 13.67

%

R

05/07/10 10:19:29 02 5.76

%R CO2 13.43

%

R

05/07/10 10:19:49 02 5.80

%R CO2 13.43

%

R

05/07/10 10:20:09 02 5.76

%R CO2 13.55

%

R

05/07/10 10:20:29 02 5.77

%R CO2 13.67

%

R

05/07/10 10:20:49 02 5.65

%R CO2 13.55

%

R

05/07/10 10:21 :09 02 5.49

%R CO2 13.79

%

R

05/07/10 10:21 :29 02 5.44

%R CO2 13.79

%

R

05/07/10 10:21 :49 02 5.53

%

R CO2 13.67

%

R

05/07/10 10:22:09 02 5.64

%R CO2 13.55

%

R

05/07/10 10:22:29 02 5.70

%

R CO2 13.55

%

R

05/07/10 10:22:49 02 5.74

%R CO2 13.67

%

R

05/07/10 10:23:09 02 5.79

%R CO2 13.43

%

R

05/07/10 10:23:29 02 5.71

%R CO2 13.67

%

R

05/07/10 10:23:49 02 5.66

%R CO2 13.55

%

R

05/07/10 10:24:09 02 5.73

%R CO2 13.55

%

R

05/07/10 10:24:29 02 5.76

%R CO2 13.43

%

R

16
05/07/10 10:24:49 02 5.79

%R CO2 13.43

%

R

05/07/10 10:25:09 02 5.76

%R CO2 13.43

%

R

05/07/10 10:25:29 02 5.77

%

R CO2 13.43

%

R

05/07/10 10:25:49 02 5.76

%R CO2 13.43

%

R

05/07/10 10:26:09 02 5.65

%

R CO2 13.67

%

R

05/07/10 10:26:29 02 5.57

%R CO2 13.55

%

R

05/07/10 10:26:49 02 5.55

%R CO2 13.55

%

R

05/07/10 10:27:09 02 5.64

%

R CO2 13.67

%

R

05/07/10 10:27:29 02 5.75

%

R CO2 13.43

%

R

05/07/10 10:27:49 02 5.71

%

R CO2 13.18

%

R

05/07/10 10:28:09 02 5.69

%R CO2 13.55

%

R

05/07/10 10:28:29 02 5.68

%R CO2 13.67

%

R

05/07/10 10:28:49 02 5.62

%

R CO2 13.43

%

R

05/07/10 10:29:09 02 5.55

%

R CO2 13.79

%

R

05/07/10 10:29:29 02 5.53

%

R CO2 13.67

%

R

05/07/10 10:29:49 02 5.51

%

R CO2 13.67

%

R

05/07/10 10:30:09 02 5.57

%

R CO2 13.67

%

R

05/07/10 10:30:29 02 5.71

%

R CO2 13.43

%

R

05/07/10 10:30:49 02 5.81

%R CO2 13.31

%

R

05/07/10 10:31:09 02 5.77

%

R CO2 13.43

%

R

05/07/10 10:31:29 02 5.68

%

R CO2 13.43

%

R

05/07/10 10:31:49 02 5.63

%

R CO2 13.55

%

R

05/07/10 10:32:09 02 5.62

%R CO2 13.43

%

R

05/07/10 10:32:29 02 5.53

%R CO2 13.55

%

R

05/07/10 10:32:49 02 5.46

%R CO2 13.55

%

R

05/07/10 10:33:09 02 5.43

%

R CO2 13.55

%

R

05/07/10 10:33:29 02 5.47

%R CO2 13.79

%

R

05/07/10 10:33:49 02 5.60

%R CO2 13.43

%

R

05/07/10 10:34:09 02 5.64

%

R CO2 13.43

%

R

05/07/10 10:34:29 02 5.57

%R CO2 13.55

%

R

05/07/10 10:34:49 02 5.59

%

R CO2 13.79

%

R

05/07/10 10:35:09 02 5.66

%R CO2 13.43

%

R

05/07110 10:35:29 02 5.77

%

R CO2 13.31

%

R

05/07/10 10:35:49 02 5.85

%R CO2 13.55

%

R

05/07/10 10:36:09 02 5.82

%R CO2 13.43

%

R

05/07/10 10:36:29 02 5.66

%

R CO2 13.67

%

R

05/07/10 10:36:49 02 5.48

%

R CO2 13.79

%

R

05/07/10 10:37:09 02 5.42

%

R CO2 13.79

%

R

05/07/10 10:37:29 02 5.46

%R CO2 13.67

%

R

05/07/10 10:37:49 02 5.51

%

R CO2 13.55

%

R

05/07/10 10:38:09 02 5.55

%

R CO2 13.67

%

R

05/07/10 10:38:29 02 5.54

%

R CO2 13.67

%

R

05/07/10 10:38:49 02 5.58

%

R CO2 13.55

%

R

05/07/10 10:39:09 02 5.62

%R CO2 13.55

%

R

05/07/10 10:39:29 02 5.60

%

R CO2 13.55

%

R

05/07/10 10:39:49 02 5.65

%

R CO2 13.18

%

R

05/07/10 10:40:09 02 5.59

%

R CO2 13.67

%

R

05/07/10 10:40:29 02 5.58

%

R CO2 13.43

%

R

05/07/10 10:40:49 02 5.63

%

R CO2 13.55

%

R

05/07/10 10:41 :09 02 5.65

%R CO2 13.55

%

R

05/07/10 10:41:29 02 5.70

%

R CO2 13.43

%

R

05/07/10 10:41 :49 02 5.73

%

R CO2 13.67

%

R

05/07/10 10:42:09 02 5.68

%

R CO2 13.55

%

R

05/07/10 10:42:29 02 5.60

%

R CO2 13.92

%

R

17
05/07/10 10:42:49 02 5.55

%

R CO2 13.55

%

R

05/07/10 10:43:09 02 5.53

%

R CO2 13.43

%

R

05/07/10 10:43:29 02 5.62

%

R CO2 13.55

%

R

05/07/10 10:43:49 02 5.70

%

R CO2 13.43

%

R

05/07/10 10:44:09 02 5.69

%

R CO2 13.55

%

R

05/07/10 10:44:29 02 5.65

%

R CO2 13.31

%

R

05/07/10 10:44:49 02 5.64

%

R CO2 13.55

%

R

05/07/10 10:45:09 02 5.60

%

R CO2 13.43

%

R

05/07/10 10:45:29 02 5.62

%

R CO2 13.55

%

R

05/07/10 10:45:49 02 5.62

%

R CO2 13.55

%

R

05/07/10 10:46:09 02 5.64

%

R CO2 13.55

%

R

05/07/10 10:46:29 02 5.68

%

R CO2 13.31

%

R

05/07/10 10:46:49 02 5.65

%

R CO2 13.67

%

R

05/07/10 10:47:09 02 5.58

%

R CO2 13.43

%

R

05/07/10 10:47:29 02 5.53

%

R CO2 13.67

%

R

05/07/10 10:47:49 02 5.53

%

R CO2 13.92

%

R

05/07/10 10:48:09 02 5.59

%

R CO2 13.43

%

R

05/07/10 10:48:29 02 5.64

%

R CO2 13.67

%

R

05/07/10 10:48:49 02 5.71

%

R CO2 13.18

%

R

05/07/10 10:49:09 02 5.74

%

R CO2 13.55

%

R

05/07/10 10:49:29 02 5.75

%

R CO2 13.31

%

R

05/07/10 10:49:49 02 5.76

%

R CO2 13.55

%

R

05/07/10 10:50:09 02 5.68

%

R CO2 13.55

%

R

05/07/10 10:50:29 02 5.60

%

R CO2 13.67

%

R

05/07/10 10:50:49 02 5.58

%

R CO2 13.55

%

R

05/07/10 10:51:09 02 5.62

%

R CO2 13.67

%

R

05/07/10 10:51 :29 02 5.75

%

R CO2 13.43

%

R

05/07/10 10:51:49 02 5.77

%

R CO2 13.55

%

R

05/07/10 10:52:09 02 5.75

%

R CO2 13.43

%

R

05/07/10 10:52:29 02 5.69

%

R CO2 13.55

%

R

05/07/10 10:52:49 02 5.62

%

R CO2 13.31

%

R

05/07/10 10:53:09 02 5.55

%

R CO2 13.55

%

R

05/07/10 10:53:29 02 5.57

%

R CO2 13.79

%

R

05/07/10 10:53:49 02 5.60

%

R CO2 13.43

%

R

05/07/10 10:54:09 02 5.66

%

R CO2 13.79

%

R

05/07/10 10:54:29 02 5.70

%

R CO2 13.43

%

R

05/07/10 10:54:49 02 5.69

%

R CO2 13.43

%

R

05/07/10 10:55:09 02 5.60

%

R CO2 13.43

%

R

05/07/10 10:55:29 02 5.53

%

R CO2 13.43

%

R

05/07/10 10:55:49 02 5.52

%

R CO2 13.55

%

R

05/07/10 10:56:09 02 5.55

%

R CO2 13.55

%

R

05/07/10 10:56:29 02 5.63

%

R CO2 13.67

%

R

05/07/10 10:56:49 02 5.75

%

R CO2 13.43

%

R

05/07/10 10:57:09 02 5.79

%

R CO2 13.55

%

R

05/07/10 10:57:29 02 5.74

%

R CO2 13.55

%

R

05/07/10 10:57:49 02 5.62

%

R CO2 13.67

%

R

05/07/10 10:58:09 02 5.55

%

R CO2 13.67

%

R

05/07/10 10:58:29 02 5.55

%

R CO2 13.79

%

R

05/07/10 10:58:49 02 5.62

%

R CO2 13.18

%

R

05/07/10 10:59:09 02 5.68

%

R CO2 13.55

%

R

05/07/10 10:59:29 02 5.70

%

R CO2 13.31

%

R

05/07/10 10:59:49 02 5.70

%

R CO2 13.31

%

R

05/07/10 11:00:09 02 5.70

%

R CO2 13.43

%

R

05/07/10 11:00:29 02 5.70

%

R CO2 13.43

%

R

18
05/07/10 11 :00:49 02 5.66

%

R CO2 13.67

%

R

05/07/10 11:01:09 02 5.66

%R CO2 13.43

%

R

05/07/10 11 :01 :29 02 5.58

%R CO2 13.67

%

R

05/07/10 11:01:49 02 5.62

%R CO2 13.43

%

R

05/07/10 11:02:09 02 5.73

%R CO2 13.43

%

R

05/07/10 11:02:29 02 5.82

%

R CO2 13.43

%

R

05/07/10 11 :02:49 02 5.91

%

R CO2 13.18

%

R

05/07/10 11:03:09 02 5.88

%

R CO2 13.31

%

R

05/07/10 11:03:29 02 5.66

%

R CO2 13.67

%

R

05/07/10 11:03:49 02 5.41

%

R CO2 13.92

%

R

05/07/10 11:04:09 02 5.26

%R CO2 13.92

%

R

05/07/10 11:04:29 02 5.32

%

R CO2 13.92

%

R

05/07/10 11:04:49 02 5.47

%R CO2 13.79

%

R

05/07/10 11 :05:09 02 5.49

%

R CO2 13.55

%

R

05/07/10 11:05:29 02 5.59

%

R CO2 13.55

%

R

05/07/10 11 :05:49 02 5.62

%

R CO2 13.55

%

R

05/07/10 11 :06:09 02 5.55

%

R CO2 13.67

%

R

05/07/10 11:06:29 02 5.51

%

R CO2 13.79

%

R

05/07/10 11:06:49 02 5.47

%R CO2 13.55

%

R

05/07/10 11:07:09 02 5.49

%R CO2 13.43

%

R

05/07/10 11:07:29 02 5.53

%

R CO2 13.67

%

R

05/07/10 11:07:49 02 5.54

%R CO2 13.79

%

R

05/07/10 11:08:09 02 5.53

%

R CO2 13.55

%

R

05/07/10 11:08:29 02 5.48

%R CO2 13.55

%

R

05/07/10 11:08:49 02 5.30

%R CO2 13.67

%

R

05/07/10 11:09:09 02 5.19

%R CO2 13.79

%

R

05/07/10 11:09:29 02 5.22

%

R CO2 13.92

%

R

05/07/10 11:09:49 02 5.20

%R CO2 14.04

%

R

05/07/10 11:10:09 02 5.19

%R CO2 14.16

%

R

05/07/10 11:10:29 02 5.31

%R CO2 13.79

%

R

05/07/10 11:10:49 02 5.41

%

R CO2 13.55

%

R

05/07/10 11:11:09 02 5.48

%

R CO2 13.67

%

R

05/07/10 11:11:29 02 5.53

%R CO2 13.79

%

R

05/07/10 11:11:49 02 5.48

%R CO2 13.92

%

R

05/07/10 11 :12:09 02 5.43

%R CO2 13.79

%

R

05/07/10 11:12:29 02 5.44

%

R CO2 13.55

%

R

05/07/10 11:12:49 02 5.53

%

R CO2 13.43

%

R

05/07/10 11:13:09 02 5.48

%

R CO2 13.55

%

R

05/07/10 11:13:29 02 5.43

%

R CO2 13.67

%

R

05/07/10 11:13:49 02 5.37

%

R CO2 13.67

%

R

05/07/10 11:14:09 02 5.30

%

R CO2 13.92

%

R

05/07/10 11:14:29 02 5.26

%R CO2 14.04

%

R

05/07/10 11:14:49 02 5.19

%R CO2 13.92

%

R

05/07/10 11:15:09 02 5.20

%R CO2 13.92

%

R

05/07/10 11:15:29 02 5.27

%R CO2 13.92

%

R

05/07/10 11:15:49 02 5.29

%

R CO2 13.92

%

R

05/07/10 11:16:09 02 5.24

%R CO2 13.92

%

R

05/07/10 11 :16:29 02 5.22

%R CO2 13.67

%

R

05/07/10 11:16:49 02 5.16

%

R CO2 14.04

%

R

05/07/10 11 :17:09 02 5.08

%

R CO2 14.16

%

R

05/07/10 11:17:29 02 5.13

%

R CO2 14.16

%

R

05/07/10 11:17:49 02 5.29

%

R CO2 13.92

%

R

05/07/10 11:18:09 02 5.31

%

R CO2 14.04

%

R

05/07/10 11:18:29 02 5.24

%

R CO2 14.04

%

R

19
05/07/10 11:18:49 02 5.31

%

R CO2 13.92

%

R

05/07/10 11:19:09 02 5.37

%R CO2 14.04

%

R

05/07/10 11:19:29 02 5.29

%R CO2 13.67

%

R

05/07/10 11:19:49 02 5.27

%

R CO2 13.79

%

R

05/07/10 11:20:09 02 5.44

%R CO2 13.67

%

R

05/07/10 11 :20:29 02 5.65

%R CO2 13.67

%

R

05/07/10 11:20:49 02 5.69

%

R CO2 13.67

%

R

05/07/10 11:21:09 02 5.66

%R CO2 13.43

%

R

05/07/10 11 :21 :29 02 5.65

%

R CO2 13.43

%

R

05/07/10 11 :21 :49 02 5.59

%R CO2 13.55

%

R

05/07/10 11:22:09 02 5.48

%R CO2 13.92

%

R

05/07/10 11:22:29 02 5.38

%

R CO2 13.92

%

R

05/07/10 11:22:49 02 5.27

%R CO2 13.79

%

R

05/07/10 11 :23:09 02 5.29

%R CO2 13.79

%

R

05/07/10 11:23:29 02 5.30

%R CO2 13.67

%

R

05/07/10 11:23:49 02 5.32

%R CO2 14.04

%

R

05/07/10 11:24:09 02 5.33

%

R CO2 13.67

%

R

05/07/10 11:24:29 02 5.26

%R CO2 13.92

%

R

05/07/10 11:24:49 02 5.20

%R CO2 14.04

%

R

05/07/10 11:25:09 02 5.13

%

R CO2 14.04

%

R

05/07/10 11:25:29 02 5.11

%R CO2 14.04

%

R

05/07/10 11:25:49 02 5.19

%R CO2 13.79

%

R

05/07/10 11:26:09 02 5.26

%R CO2 13.92

%

R

05/07/10 11:26:29 02 5.37

%

R CO2 13.67

%

R

05/07/10 11:26:49 02 5.43

%R CO2 13.79

%

R

05/07/10 11:27:09 02 5.44

%

R CO2 13.79

%

R

05/07/10 11:27:29 02 5.48

%R CO2 13.67

%

R

05/07/10 11:27:49 02 5.49

%R CO2 13.67

%

R

05/07/10 11:28:09 02 5.49

%

R CO2 13.55

%

R

05/07/10 11:28:29 02 5.55

%R CO2 13.67

%

R

05/07/10 11 :28:49 02 5.57

%R CO2 13.55

%

R

05/07/10 11:29:09 02 5.49

%R CO2 13.67

%

R

05/07/10 11:29:29 02 5.35

%R CO2 13.79

%

R

05/07/10 11:29:49 02 5.20

%R CO2 13.79

%

R

05/07/10 11:30:09 02 5.11

%R CO2 13.92

%

R

05/07/10 11:30:29 02 5.09

%R CO2 14.04

%

R

05/07/10 11 :30:49 02 5.08

%R CO2 14.16

%

R

05/07/10 11:31:09 02 5.10

%

R CO2 13.92

%

R

05/07/10 11 :31 :29 02 5.02

%R CO2 14.04

%

R

05/07/10 11:31:49 02 4.97

%R CO2 14.16

%

R

05/07/10 11:32:09 02 4.97

%R CO2 14.53

%

R

05/07/10 11:32:29 02 4.94

%R CO2 14.04

%

R

05/07/10 11:32:49 02 4.94

%R CO2 14.28

%

R

05/07/10 11:33:09 02 5.08

%R CO2 14.16

%

R

05/07/10 11:33:29 02 5.21

%R CO2 14.16

%

R

05/07/10 11:33:49 02 5.41

%R CO2 13.67

%

R

05/07/10 11:34:09 02 5.55

%R CO2 13.67

%

R

05/07/10 11:34:29 02 5.57

%R CO2 13.79

%

R

05/07/10 11:34:49 02 5.58

%R CO2 13.43

%

R

05/07/10 11:35:09 02 5.49

%R CO2 13.92

%

R

05/07/10 11:35:29 02 5.32

%R CO2 13.92

%

R

05/07/10 11 :35:49 02 5.29

%R CO2 13.92

%

R

05/07/10 11:36:09 02 5.30

%R CO2 13.67

%

R

05/07/10 11:36:29 02 5.31

%R CO2 13.79

%

R

20
05/07/10 11 :36:49 02 5.37

%

R CO2 14.04

%

R

05/07/10 11 :37:09 02 5.46

%

R CO2 13.79

%

R

05/07/10 11:37:29 02 5.54

%

R CO2 13.79

%

R

05/07/10 11 :37:49 02 5.58

%

R CO2 13.79

%

R

05/07/10 11 :38:09 02 5.53

%

R CO2 13.79

%

R

05107/10 11:38:29 02 5.43

%

R CO2 13.67

%

R

05/07/10 11 :38:49 02 5.35

%

R CO2 13.79

%

R

05/07/10 11:39:09 02 5.32

%

R CO2 13.79

%

R

05/07/10 11:39:29 02 5.46

%

R CO2 13.55

%

R

05/07/10 11:39:49 02 5.62

%R CO2 13.67

%

R

05/07/10 11:40:09 02 5.70

%

R CO2 13.67

%

R

05/07/10 11:40:29 02 5.69

%

R CO2 13.55

%

R

05/07/10 11:40:49 02 5.60

%

R CO2 13.79

%

R

05/07/10 11:41 :09 02 5.57

%

R CO2 13.92

%

R

05/07/10 11:41 :29 02 5.55

%

R CO2 13.79

%

R

05/07/10 11:41:49 02 5.57

%

R CO2 13.55

%

R

05/07/10 11:42:09 02 5.63

%R CO2 13.67

%

R

05/07/10 11:42:29 02 5.74

%

R CO2 13.43

%

R

05/07/10 11:42:49 02 5.80

%

R CO2 13.79

%

R

05/07/10 11:43:09 02 5.73

%

R CO2 13.43

%

R

05/07/10 11:43:29 02 5.58

%

R CO2 13.79

%

R

05/07/10 11:43:49 02 5.51

%

R CO2 13.79

%

R

05/07/10 11:44:09 02 5.53

%

R CO2 13.67

%

R

05/07/10 11:44:29 02 5.57

%

R CO2 13.55

%

R

05/07/10 11:44:49 02 5.60

%R CO2 13.55

%

R

05/07/10 11:45:09 02 5.62

%

R CO2 13.43

%

R

05/07/10 11:45:29 02 5.52

%

R CO2 13.79

%

R

05/07/10 11:45:49 02 5.48

%

R CO2 14.04

%

R

05/07/10 11 :46:09 02 5.51

%

R CO2 13.55

%

R

05/07/10 11:46:29 02 5.55

%

R CO2 13.55

%

R

05/07/10 11:46:49 02 5.52

%

R CO2 13.67

%

R

05/07/10 11:47:09 02 5.44

%

R CO2 13.79

%

R

05/07/10 11 :47:29 02 5.42

%

R CO2 13.67

%

R

05/07/10 11 :47:49 02 5.42

%

R CO2 14.16

%

R

05/07/10 11:48:09 02 5.48

%

R CO2 13.79

%

R

05/07/10 11:48:29 02 5.57

%

R CO2 13.43

%

R

05/07/10 11:48:49 02 5.57

%

R CO2 13.55

%

R

05/07/10 11:49:09 02 5.54

%

R CO2 13.67

%

R

05/07/10 11:49:29 02 5.44

%

R CO2 13.92

%

R

05/07/10 11:49:49 02 5.38

%

R CO2 13.79

%

R

05/07/10 11:50:09 02 5.48

%

R CO2 13.67

%

R

05/07/10 11:50:29 02 5.57

%

R CO2 13.79

%

R

05/07/10 11:50:49 02 5.59

%

R CO2 13.79

%

R

05/07/10 11:51:09 02 5.51

%

R CO2 13.55

%

R

05/07/10 11:51:29 02 5.46

%R CO2 13.43

%

R

05/07/10 11:51:49 02 5.51

%R CO2 13.55

%

R

05/07/10 11:52:09 02 5.51

%

R CO2 13.67

%

R

05/07110 11:52:29 02 5.60

%

R CO2 13.67

%

R

05/07/10 11:52:49 02 5.70

%

R CO2 13.31

%

R

05/07/10 11:53:09 02 5.74

%

R CO2 13.67

%

R

05/07/10 11:53:29 02 5.79

%

R CO2 13.43

%

R

05/07/10 11:53:49 02 5.71

%

R CO2 13.55

%

R

05/07/10 11:54:09 02 5.54

%

R CO2 13.79

%

R

05/07/10 11 :54:29 02 5.51

%R CO2 13.92

%

R

21
05/07/10 11:54:49 02 5.58 % R CO2 13.67 % R

05/07/10 11 :55:09 02 5.70 % R CO2 13.55 % R

05/07/10 11:55:29 02 5.75 % R CO2 13.67 % R

05/07/10 11 :55:49 02 5.70 % R CO2 13.55 % R

05/07/10 11 :56:09 02 5.62 % R CO2 13.43 % R

05/07/10 11 :56:29 02 5.46 % R CO2 13.67 % R

05/07/10 11 :56:49 02 5.36 % R CO2 13.92 % R

05/07/10 11:57:09 02 5.41 % R CO2 13.67 % R

05/07/10 11 :57:29 02 5.51 % R CO2 13.67 % R

05/07/10 11 :57:49 02 5.64 % R CO2 13.43 % R

05/07/10 11:58:09 02 5.83 % R CO2 13.43 % R

05/07/10 11:58:29 02 5.97 % R CO2 13.43 % R

05/07/10 11 :58:49 02 5.90 % R CO2 13.31 % R

05/07/10 11:59:09 02 5.86 % R CO2 13.55 % R

05/07/10 11:59:29 02 5.86 % R CO2 13.55 % R

05/07/10 11:59:49 02 5.93 % R CO2 13.55 % R

05/07/10 12:00:09 02 5.99 % R CO2 13.43 % R

05/07/10 12:00:29 02 5.97 % R CO2 13.43 % R

05/07/10 12:00:49 02 5.98 % R CO2 13.18 % R

05/07/10 12:01:09 02 6.05 % R CO2 13.31 % R

05/07/10 12:01 :29 02 6.07 % R CO2 13.18 % R

05/07/10 12:01 :39 02 6.08 % R CO2 13.18 % R

05/07/10 12:01:49 02 6.09 % R CO2 13.31 % R

05/07/10 12:01 :59 02 6.10 % R CO2 13.43 % R

05/07/10 12:02:09 02 6.14 % R CO2 13.55 % R

05/07/10 12:02:19 02 6.16 % R CO2 13.43 % R

05/07/10 12:02:29 02 6.16 % R CO2 13.43 % R

05/07/10 12:02:39 02 6.14 % R CO2 13.18 % R

05/07/10 12:02:49 02 6.12 % R CO2 13.31 % R

Avg 5.67 13.54

22
Post2Bias James River Cogen

Unit NO.2

Post Run2 Bias Metals/PM-10

05/07/10 12:04:22 02 5.74

%R CO2 13.55

%

R

05/07/10 12:04:24 02 5.71

%R CO2 13.55

%

R

05/07/10 12:04:29 02 5.69

%

R CO2 13.67

%

R

05/07/10 12:04:34 02 5.66

%

R CO2 13.67

%

R

05/07/10 12:04:39 02 5.68

%R CO2 13.55

%

R

05/07/10 12:04:44 02 6.71

%R CO2 13.55

%

R

05/07/10 12:04:49 02 7.54

%R CO2 12.45

%

R

05/07/10 12:04:54 02 6.31

%

R CO2 9.40

%

R

05/07/10 12:04:59 02 4.50

%R CO2 6.59

%

R

05/07/10 12:05:04 02 3.05

%

R CO2 4.15

%

R

05/07/10 12:05:09 02 2.04

%R CO2 2.56

%

R

05/07/10 12:05:14 02 1.37

%

R CO2 1.95

%

R

05/07/10 12:05:19 02 0.92

%R CO2 1.34

%

R

05/07/10 12:05:24 02 0.63

%R CO2 0.98

%

R

05/07/10 12:05:29 02 0.46

%R CO2 1.10

%

R

05/07/10 12:05:34 02 0.35

%R CO2 0.61

%

R

05/07/10 12:05:39 02 0.29

%

R CO2 0.61

%

R

05/07/10 12:05:44 02 0.24

%R CO2 0.49

%

R

05/07/10 12:05:49 02 0.22

%

R CO2 0.37

%

R

05/07/10 12:05:54 02 0.20

%

R CO2 0.49

%

R

05/07/10 12:05:59 02 0.17

%

R CO2 0.37

%

R

05/07/10 12:06:04 02 0.17

%R CO2 0.73

%

R

05/07/10 12:06:09 02 0.16

%

R CO2 0.12

%

R

05/07/10 12:06:14 02 0.16

%R CO2 0.12

%

R

05/07/10 12:06:19 02 0.15

%

R CO2 0.37

%

R

05/07/10 12:06:24 02 0.13

%R CO2 0.24

%

R

05/07/10 12:06:29 02 0.13

%

R CO2 0.24

%

R

05/07/10 12:06:34 02 0.12

%R CO2 0.37

%

R

05/07/10 12:06:39 02 0.12

%

R CO2 0.12

%

R

05/07/10 12:06:44 02 0.12

%R CO2 0.24

%

R

05/07/10 12:06:49 02 0.12

%

R CO2 0.12

%

R

05/07110 12:06:54 02 0.11

%R CO2 0.12

%

R

05/07/10 12:06:59 02 0.12

%R CO2 0.00

%

R

05/07/10 12:07:04 02 0.11

%

R CO2 0.00

%

R

05/07110 12:07:09 02 0.11

%

R CO2 0.00

%

R

05/07/10 12:07:14 02 0.11

%R CO2 0.24

%

R

05/07/10 12:07:19 02 0.10

%

R CO2 0.00

%

R

05/07/10 12:07:24 02 0.10

%R CO2 0.24

%

R

05/07/10 12:07:29 02 0.10

%

R CO2 0.12

%

R

05/07/10 12:07:34 02 0.10

%R CO2 0.12

%

R

05/07/10 12:07:39 02 0.10

%

R CO2 -0.12

%

R

05/07/10 12:07:44 02 0.68

%R CO2 0.00

%

R

05/07/10 12:07:49 02 2.95

%R CO2 1.34

%

R

05/07/10 12:07:54 02 5.86

%R CO2 2.81

%

R

05/07/10 12:07:59 02 8.18

%

R CO2 4.27

%

R

05/07/10 12:08:04 02 9.78

%R CO2 5.25

%

R

05/07/10 12:08:09 02 10.79

%

R CO2 5.98

%

R

05/07/10 12:08:14 02 11.40

%

R CO2 6.47

%

R

05/07/10 12:08:19 02 11.77

%

R CO2 6.59

%

R

05/07/10 12:08:24 02 11.99

%R CO2 7.08

%

R

23
05/07/10 12:08:29 02 12.12 % R CO2 6.84 % R

05/07/10 12:08:34 02 12.19 % R CO2 6.84 % R

05/07/10 12:08:39 02 12.26 % R CO2 7.08 % R

05/07/10 12:08:44 02 12.29 % R CO2 7.08 % R

05/07/10 12:08:49 02 12.32 % R CO2 7.08 % R

05/07/10 12:08:54 02 12.33 % R CO2 7.45 % R

05/07/10 12:08:59 02 12.34 % R CO2 7.20 % R

05/07/10 12:09:04 02 12.04 % R CO2 7.32 % R

05/07/10 12:09:09 02 11.65 % R CO2 8.06 % R

05/07/10 12:09:14 02 12.29 % R CO2 7.32 % R

05/07/10 12:09:19 02 12.24 % R CO2 6.96 % R

05/07/10 12:09:24 02 12.35 % R CO2 7.20 % R

05/07/10 12:09:29 02 12.37 % R CO2 7.32 % R

05/07/10 12:09:34 02 12.41 % R CO2 7.32 % R

05/07/10 12:09:39 02 12.43 % R CO2 7.20 % R

05/07/10 12:09:44 02 14.38 % R CO2 7.57 % R

05/07/10 12:09:49 02 18.73 % R CO2 9.64 % R

05/07/10 12:09:54 02 20.80 % R CO2 11.11 % R

05/07/10 12:09:59 02 21.48 % R CO2 11.72 % R

05/07/10 12:10:04 02 21.72 % R CO2 11.84 % R

05/07/10 12:10:09 02 21.79 % R CO2 11.84 % R

05/07/10 12:10:14 02 21.81 % R CO2 12.33 % R

05/07/10 12:10:19 02 21.84 % R CO2 12.33 % R

05/07/10 12:10:24 02 21.86 % R CO2 12.21 % R

05/07/10 12:10:29 02 21.86 % R CO2 12.33 % R

05/07/10 12:10:34 02 21.90 % R CO2 12.21 % R

05/07/10 12:10:39 02 21.89 % R CO2 12.21 % R

05/07/10 12:10:44 02 21.90 % R CO2 12.08 % R

24
Run3 James River Cogen

Unit NO.2

Run No.3 Metals/PM-10

05/07110 12:16:17 02 5.62 % R CO2 13.55

%

R

05/07/10 12:16:19 02 5.63

%

R CO2 13.79

%

R

05/07/10 12:16:29 02 5.64 % R CO2 13.55

%

R

05/07/10 12:16:39 02 5.65 % R CO2 13.79

%

R

05/07/10 12:16:49 02 5.62 % R CO2 13.43

%

R

05/07/10 12:17:09 02 5.51

%

R CO2 13.55

%

R

05/07/10 12:17:29 02 5.32 % R CO2 13.55

%

R

05/07/10 12:17:49 02 5.20

%

R CO2 13.79

%

R

05/07/10 12:18:09 02 5.26

%

R CO2 13.67

%

R

05/07/10 12:18:29 02 5.35 % R CO2 13.92

%

R

05/07/10 12:18:49 02 5.43 % R CO2 13.67

%

R

05/07/10 12:19:09 02 5.49

%

R CO2 13.67

%

R

05/07/10 12:19:29 02 5.57

%

R CO2 13.67

%

R

05/07/10 12:19:49 02 5.55

%

R CO2 13.67

%

R

05/07/10 12:20:09 02 5.38 % R CO2 13.79

%

R

05/07/10 12:20:29 02 5.29 % R CO2 13.79

%

R

05/07/10 12:20:49 02 5.31

%

R CO2 13.67

%

R

05/07/10 12:21:09 02 5.38 % R CO2 13.92

%

R

05/07/10 12:21:29 02 5.46

%

R CO2 13.67

%

R

05/07/10 12:21:49 02 5.48 % R CO2 13.79

%

R

05/07/10 12:22:09 02 5.49

%

R CO2 13.92

%

R

05/07/10 12:22:29 02 5.51 % R CO2 13.67

%

R

05/07/10 12:22:49 02 5.53 % R CO2 13.55

%

R

05/07/10 12:23:09 02 5.44 % R CO2 13.67

%

R

05/07/10 12:23:29 02 5.37

%

R CO2 13.67

%

R

05/07/10 12:23:49 02 5.29

%

R CO2 13.92

%

R

05/07/10 12:24:09 02 5.36 % R CO2 13.92

%

R

05/07/10 12:24:29 02 5.53

%

R CO2 13.55

%

R

05/07/10 12:24:49 02 5.64

%

R CO2 13.31

%

R

05/07/10 12:25:09 02 5.66

%

R CO2 13.31

%

R

05/07/10 12:25:29 02 5.48 % R CO2 13.92

%

R

05/07/10 12:25:49 02 5.24

%

R CO2 13.92

%

R

05/07/10 12:26:09 02 5.25

%

R CO2 13.92

%

R

05/07/10 12:26:29 02 5.31 % R CO2 13.92

%

R

05/07/10 12:26:49 02 5.35

%

R CO2 13.67

%

R

05/07/10 12:27:09 02 5.32 % R CO2 14.04

%

R

05/07/10 12:27:29 02 5.38

%

R CO2 13.67

%

R

05/07/10 12:27:49 02 5.46 % R CO2 13.79

%

R

05/07/10 12:28:09 02 5.35

%

R CO2 13.79

%

R

05/07/10 12:28:29 02 5.26

%

R CO2 13.79

%

R

05/07/10 12:28:49 02 5.18 % R CO2 14.04

%

R

05/07/10 12:29:09 02 5.10 % R CO2 14.04

%

R

05/07/10 12:29:29 02 5.07 % R CO2 13.92

%

R

05/07/10 12:29:49 02 5.04 % R CO2 14.16

%

R

05/07/10 12:30:09 02 5.09 % R CO2 14.16

%

R

05/07/10 12:30:29 02 5.09

%

R CO2 14.04

%

R

05/07/10 12:30:49 02 5.16 % R CO2 13.67

%

R

05/07/10 12:31:09 02 5.35 % R CO2 13.67

%

R

05/07/10 12:31:29 02 5.44 % R CO2 13.79

%

R

05/07/10 12:31:49 02 5.54

%

R CO2 13.79

%

R

25
05/07/10 12:32:09 02 5.64

%

R CO2 13.31

%

R

05/07/10 12:32:29 02 5.71

%

R CO2 13.55

%

R

05/07/10 12:32:49 02 5.86

%

R CO2 13.18

%

R

05/07/10 12:33:09 02 5.82

%

R CO2 13.31

%

R

05/07/10 12:33:29 02 5.81

%

R CO2 13.31

%

R

05/07/10 12:33:49 02 5.80

%

R CO2 13.55

%

R

05/07/10 12:34:09 02 5.70

%

R CO2 13.67

%

R

05/07/10 12:34:29 02 5.57

%

R CO2 13.67

%

R

05/07/10 12:34:49 02 5.40

%

R CO2 13.92

%

R

05/07/10 12:35:09 02 5.38

%

R CO2 13.92

%

R

05/07/10 12:35:29 02 5.48

%

R CO2 13.55

%

R

05/07/10 12:35:49 02 5.52

%

R CO2 13.55

%

R

05/07/10 12:36:09 02 5.46

%

R CO2 13.55

%

R

05/07/10 12:36:29 02 5.30

%

R CO2 13.79

%

R

05/07/10 12:36:49 02 5.11

%

R CO2 13.79

%

R

05/07/10 12:37:09 02 5.11

%

R CO2 13.67

%

R

05/07/10 12:37:29 02 5.16

%

R CO2 13.92

%

R

05/07/10 12:37:49 02 5.26

%

R CO2 13.79

%

R

05/07/10 12:38:09 02 5.42

%

R CO2 13.92

%

R

05/07/10 12:38:29 02 5.58

%

R CO2 13.79

%

R

05/07/10 12:38:49 02 5.54

%

R CO2 13.67

%

R

05/07/10 12:39:09 02 5.54

%

R CO2 13.79

%

R

05/07110 12:39:29 02 5.52

%

R CO2 13.67

%

R

05/07/10 12:39:49 02 5.52

%

R CO2 13.55

%

R

05/07/10 12:40:09 02 5.57

%

R CO2 13.55

%

R

05/07/10 12:40:29 02 5.52

%

R CO2 13.55

%

R

05/07/10 12:40:49 02 5.44

%

R CO2 13.67

%

R

05/07/10 12:41:09 02 5.53

%

R CO2 13.55

%

R

05/07/10 12:41:29 02 5.65

%

R CO2 13.67

%

R

05/07/10 12:41:49 02 5.75

%

R CO2 13.31

%

R

05/07/10 12:42:09 02 5.73

%

R CO2 13.55

%

R

05/07/10 12:42:29 02 5.55

%

R CO2 13.67

%

R

05/07/10 12:42:49 02 5.38

%

R CO2 13.67

%

R

05/07/10 12:43:09 02 5.37

%

R CO2 13.55

%

R

05/07/10 12:43:29 02 5.42

%

R CO2 13.67

%

R

05/07/10 12:43:49 02 5.41

%

R CO2 13.67

%

R

05/07/10 12:44:09 02 5.25

%

R CO2 13.92

%

R

05/07/10 12:44:29 02 5.35

%

R CO2 14.04

%

R

05/07/10 12:44:49 02 5.48

%

R CO2 13.55

%

R

05/07/10 12:45:09 02 5.69

%

R CO2 13.67

%

R

05/07/10 12:45:29 02 5.70

%

R CO2 13.43

%

R

05/07/10 12:45:49 02 5.74

%

R CO2 13.55

%

R

05/07/10 12:46:09 02 5.87

%

R CO2 13.55

%

R

05/07/10 12:46:29 02 5.91

%

R CO2 13.31

%

R

05/07/10 12:46:49 02 5.83

%

R CO2 13.31

%

R

05/07/10 12:47:09 02 5.73

%

R CO2 13.67

%

R

05/07/10 12:47:29 02 5.64

%

R CO2 13.55

%

R

05/07/10 12:47:49 02 5.60

%

R CO2 13.55

%

R

05/07/10 12:48:09 02 5.51

%

R CO2 13.43

%

R

05/07/10 12:48:29 02 5.38

%

R CO2 13.67

%

R

05/07/10 12:48:49 02 5.41

%

R CO2 13.55

%

R

05/07/10 12:49:09 02 5.52

%

R CO2 13.43

%

R

05/07/10 12:49:29 02 5.54

%

R CO2 13.55

%

R

05/07/10 12:49:49 02 5.46

%

R CO2 13.55

%

R

26
05/07/10 12:50:09 02 5.43

%

R CO2 13.67

%

R

05/07/10 12:50:29 02 5.37

%

R CO2 13.43

%

R

05/07/10 12:50:49 02 5.27

%

R CO2 13.79

%

R

05/07/10 12:51:09 02 5.22

%

R CO2 14.04

%

R

05/07/10 12:51 :29 02 5.29

%

R CO2 13.67

%

R

05/07/10 12:51:49 02 5.33

%

R CO2 13.79

%

R

05/07/10 12:52:09 02 5.30

%

R CO2 13.67

%

R

05/07/10 12:52:29 02 5.25

%

R CO2 13.55

%

R

05/07/10 12:52:49 02 5.32

%

R CO2 13.92

%

R

05/07/10 12:53:09 02 5.41

%

R CO2 13.55

%

R

05/07/10 12:53:29 02 5.48

%

R CO2 13.67

%

R

05/07/10 12:53:49 02 5.59

%

R CO2 13.43

%

R

05/07/10 12:54:09 02 5.69

%

R CO2 13.43

%

R

05/07/10 12:54:29 02 5.85

%

R CO2 13.18

%

R

05/07/10 12:54:49 02 6.04

%

R CO2 13.31

%

R

05/07/10 12:55:09 02 6.05

%

R CO2 13.06

%

R

05/07/10 12:55:29 02 5.98

%

R CO2 13.43

%

R

05/07/10 12:55:49 02 5.87

%

R CO2 13.43

%

R

05/07/10 12:56:09 02 5.73

%

R CO2 13.31

%

R

05/07/10 12:56:29 02 5.65

%

R CO2 13.43

%

R

05/07/10 12:56:49 02 5.68

%

R CO2 13.43

%

R

05/07/10 12:57:09 02 5.69

%

R CO2 13.43

%

R

05/07/10 12:57:29 02 5.71

%

R CO2 13.43

%

R

05/07/10 12:57:49 02 5.63

%

R CO2 13.55

%

R

05/07/10 12:58:09 02 5.53

%

R CO2 13.43

%

R

05/07/10 12:58:29 02 5.44 % R CO2 13.43

%

R

05/07/10 12:58:49 02 5.43

%

R CO2 13.55

%

R

05/07/10 12:59:09 02 5.49

%

R CO2 13.67

%

R

05/07/10 12:59:29 02 5.55

%

R CO2 13.67

%

R

05/07/10 12:59:49 02 5.59

%

R CO2 13.67

%

R

05/07/10 13:00:09 02 5.44

%

R CO2 13.67

%

R

05/07/10 13:00:29 02 5.48

%

R CO2 13.79

%

R

05/07/10 13:00:49 02 5.69

%

R CO2 13.31

%

R

05/07/10 13:01 :09 02 5.81

%

R CO2 13.31

%

R

05/07/10 13:01:29 02 5.93

%

R CO2 13.43

%

R

05/07/10 13:01:49 02 5.96

%

R CO2 13.31

%

R

05/07/10 13:02:09 02 5.94

%

R CO2 13.18

%

R

05/07/10 13:02:29 02 5.93

%

R CO2 13.18

%

R

05/07/10 13:02:49 02 5.91

%

R CO2 13.18

%

R

05/07/10 13:03:09 02 5.85

%

R CO2 13.43

%

R

05/07/10 13:03:29 02 5.69

%

R CO2 13.55

%

R

05/07/10 13:03:49 02 5.64

%

R CO2 13.55

%

R

05/07/10 13:04:09 02 5.58

%

R CO2 13.55

%

R

05/07/10 13:04:29 02 5.53

%

R CO2 13.67

%

R

05/07/10 13:04:49 02 5.58

%

R CO2 13.55

%

R

05/07/10 13:05:09 02 5.62

%

R CO2 13.43

%

R

05/07/10 13:05:29 02 5.53

%

R CO2 13.43

%

R

05/07/10 13:05:49 02 5.43

%

R CO2 13.55

%

R

05/07/10 13:06:09 02 5.38

%

R CO2 13.67

%

R

05/07/10 13:06:29 02 5.42

%

R CO2 13.55

%

R

05/07/10 13:06:49 02 5.41

%

R CO2 13.79

%

R

05/07/10 13:07:09 02 5.55

%

R CO2 13.92

%

R

05/07/10 13:07:29 02 5.54

%

R CO2 13.55

%

R

05/07/10 13:07:49 02 5.48

%

R CO2 13.55

%

R

27
05/07/10 13:08:09 02 5.51

%R CO2 13.67

%

R

05/07/10 13:08:29 02 5.54

%

R CO2 13.67

%

R

05/07/10 13:08:49 02 5.58

%

R CO2 13.67

%

R

05/07/10 13:09:09 02 5.54

%

R CO2 13.67

%

R

05/07/10 13:09:29 02 5.52

%

R CO2 13.79

%

R

05/07/10 13:09:49 02 5.49

%

R CO2 13.67

%

R

05/07/10 13:10:09 02 5.38

%

R CO2 13.67

%

R

05/07/10 13:10:29 02 5.49

%

R CO2 13.43

%

R

05/07/10 13:10:49 02 5.63

%

R CO2 13.43

%

R

05/07/10 13:11:14 02 5.71

%

R CO2 13.79

%

R

05/07/10 13:11 :29 02 5.79

%R CO2 13.67

%

R

05/07/10 13:11:49 02 5.77

%

R CO2 13.43

%

R

05/07/10 13:12:09 02 5.75

%R CO2 13.43

%

R

05/07/10 13:12:29 02 5.68

%

R CO2 13.43

%

R

05/07/10 13:12:49 02 5.58

%

R CO2 13.43

%

R

05/07/10 13:13:09 02 5.60

%

R CO2 13.43

%

R

05/07/10 13:13:29 02 5.65

%

R CO2 13.43

%

R

05/07/10 13:13:49 02 5.66

%

R CO2 13.18

%

R

05/07/10 13:14:09 02 5.64

%

R CO2 13.55

%

R

05/07/10 13:14:29 02 5.62

%R CO2 13.43

%

R

05/07/10 13:14:49 02 5.49

%

R CO2 13.67

%

R

05/07/10 13:15:09 02 5.44

%R CO2 13.67

%

R

05/07/10 13:15:29 02 5.38

%

R CO2 13.55

%

R

05/07/10 13:15:49 02 5.37

%

R CO2 13.67

%

R

05/07/10 13:16:09 02 5.59

%

R CO2 13.55

%

R

05/07/10 13:16:29 02 5.63

%

R CO2 13.43

%

R

05/07/10 13:16:49 02 5.62

%

R CO2 13.55

%

R

05/07/10 13:17:09 02 5.47

%

R CO2 13.92

%

R

05107/10 13:17:29 02 5.47

%

R CO2 13.67

%

R

05/07/10 13:17:49 02 5.53

%

R CO2 13.67

%

R

05/07/10 13:18:09 02 5.49

%

R CO2 13.55

%

R

05/07/10 13:18:29 02 5.60

%R CO2 13.43

%

R

05/07/10 13:18:49 02 5.76

%

R CO2 13.18

%

R

05/07/10 13:19:09 02 5.74

%

R CO2 13.43

%

R

05/07/10 13:19:29 02 5.70

%

R CO2 13.43

%

R

05/07/10 13:19:49 02 5.62

%

R CO2 13.31

%

R

05/07/10 13:20:09 02 5.53

%

R CO2 13.55

%

R

05/07/10 13:20:29 02 5.49

%

R CO2 13.55

%

R

05/07/10 13:20:49 02 5.63

%

R CO2 13.67

%

R

05/07/10 13:21:09 02 5.85

%

R CO2 13.43

%

R

05/07/10 13:21:29 02 5.97

%R CO2 13.43

%

R

05/07/10 13:21:49 02 5.80

%

R CO2 13.43

%

R

05/07/10 13:22:09 02 5.69

%

R CO2 13.55

%

R

05/07/10 13:22:29 02 5.69

%

R CO2 13.67

%

R

05/07/10 13:22:49 02 5.75

%

R CO2 13.31

%

R

05/07/10 13:23:09 02 5.55

%

R CO2 13.55

%

R

05/07/10 13:23:29 02 5.32

%

R CO2 13.55

%

R

05/07/10 13:23:49 02 5.31

%

R CO2 13.67

%

R

05/07/10 13:24:09 02 5.40

%

R CO2 13.55

%

R

05/07/10 13:24:29 02 5.43

%R CO2 13.79

%

R

05/07/10 13:24:49 02 5.48

%

R CO2 13.55

%

R

05/07/10 13:25:09 02 5.52

%

R CO2 13.31

%

R

05/07/10 13:25:29 02 5.49

%

R CO2 13.43

%

R

05/07/10 13:25:49 02 5.52

%

R CO2 13.67

%

R

28
05/07/10 13:26:09 02 5.58

%

R CO2 13.43

%

R

05/07/10 13:26:29 02 5.59

%R CO2 13.92

%

R

05/07/10 13:26:49 02 5.65

%

R CO2 13.67

%

R

05/07/10 13:27:09 02 5.70

%R CO2 13.43

%

R

05/07/10 13:27:29 02 5.58

%

R CO2 13.43

%

R

05/07/10 13:27:49 02 5.47

%R CO2 13.67

%

R

05/07/10 13:28:09 02 5.32

%

R CO2 13.92

%

R

05/07/10 13:28:29 02 5.32

%R CO2 13.79

%

R

05/07/10 13:28:49 02 5.46

%

R CO2 13.67

%

R

05/07/10 13:29:09 02 5.57

%

R CO2 13.55

%

R

05/07/10 13:29:29 02 5.59

%

R CO2 13.67

%

R

05/07/10 13:29:49 02 5.55

%

R CO2 13.55

%

R

05/07/10 13:30:09 02 5.54

%

R CO2 13.31

%

R

05/07/10 13:30:29 02 5.51

%

R CO2 13.67

%

R

05/07/10 13:30:49 02 5.43

%R CO2 13.92

%

R

05/07/10 13:31:09 02 5.44

%

R CO2 13.79

%

R

05/07/10 13:31:29 02 5.41

%

R CO2 13.79

%

R

05/07/10 13:31:49 02 5.44

%

R CO2 13.79

%

R

05/07/10 13:32:09 02 5.54

%

R CO2 13.67

%

R

05/07/10 13:32:29 02 5.66

%

R CO2 13.67

%

R

05/07/10 13:32:49 02 5.68

%

R CO2 13.55

%

R

05/07/10 13:33:09 02 5.48

%

R CO2 13.79

%

R

05/07/10 13:33:29 02 5.32

%

R CO2 13.67

%

R

05/07/10 13:33:49 02 5.31

%

R CO2 13.67

%

R

05/07/10 13:34:09 02 5.35

%R CO2 13.92

%

R

05/07/10 13:34:29 02 5.43

%

R CO2 13.79

%

R

05/07/10 13:34:49 02 5.46

%R CO2 13.55

%

R

05/07/10 13:35:09 02 5.52

%

R CO2 13.79

%

R

05/07/10 13:35:29 02 5.49

%

R CO2 13.55

%

R

05/07/10 13:35:49 02 5.37

%

R CO2 13.79

%

R

05/07/10 13:36:09 02 5.31

%

R CO2 13.92

%

R

05/07/10 13:36:29 02 5.37

%

R CO2 13.79

%

R

05/07/10 13:36:49 02 5.41

%

R CO2 13.67

%

R

05/07/10 13:37:09 02 5.42

%

R CO2 13.67

%

R

05/07/10 13:37:29 02 5.58

%

R CO2 13.67

%

R

05/07/10 13:37:49 02 5.71

%

R CO2 13.18

%

R

05/07/10 13:38:09 02 5.68

%

R CO2 13.43

%

R

05/07/10 13:38:29 02 5.59

%

R CO2 13.55

%

R

05/07/10 13:38:49 02 5.46

%

R CO2 13.67

%

R

05/07/10 13:39:09 02 5.33

%

R CO2 13.55

%

R

05/07/10 13:39:29 02 5.36

%

R CO2 13.79

%

R

05/07/10 13:39:49 02 5.38

%

R CO2 13.92

%

R

05/07/10 13:40:09 02 5.42

%

R CO2 13.79

%

R

05/07/10 13:40:29 02 5.52

%

R CO2 13.79

%

R

05/07/10 13:40:49 02 5.51

%

R CO2 13.79

%

R

05/07/10 13:41 :09 02 5.53

%

R CO2 13.43

%

R

05/07/10 13:41:29 02 5.52

%

R CO2 13.67

%

R

05/07/10 13:41 :49 02 5.54

%

R CO2 13.67

%

R

05/07/10 13:42:09 02 5.54

%

R CO2 13.67

%

R

05/07/10 13:42:29 02 5.57

%

R CO2 13.55

%

R

05/07/10 13:42:49 02 5.66

%

R CO2 13.43

%

R

05/07/10 13:43:09 02 5.68

%

R CO2 13.43

%

R

05/07/10 13:43:29 02 5.66

%

R CO2 13.55

%

R

05/07/10 13:43:49 02 5.59

%

R CO2 13.55

%

R

29
05/07/10 13:44:09 02 5.44

%

R CO2 13.55

%

R

05/07/10 13:44:29 02 5.44

%

R CO2 13.55

%

R

05/07/10 13:44:49 02 5.38

%

R CO2 13.79

%

R

05/07/10 13:45:09 02 5.36

%

R CO2 13.79

%

R

05/07/10 13:45:29 02 5.38

%

R CO2 13.55

%

R

05/07/10 13:45:49 02 5.49

%

R CO2 13.67

%

R

05/07/10 13:46:09 02 5.66

%

R CO2 13.55

%

R

05/07/10 13:46:29 02 5.70

%

R CO2 13.43

%

R

05/07/10 13:46:49 02 5.85

%

R CO2 13.18

%

R

05/07/10 13:47:09 02 5.86

%R CO2 13.43

%

R

05/07/10 13:47:29 02 5.69

%

R CO2 13.55

%

R

05/07/10 13:47:49 02 5.62

%

R CO2 13.55

%

R

05/07/10 13:48:09 02 5.58

%

R CO2 13.43

%

R

05/07/10 13:48:29 02 5.64

%

R CO2 13.67

%

R

05/07/10 13:48:49 02 5.75

%

R CO2 13.31

%

R

05/07/10 13:49:09 02 5.64

%

R CO2 13.55

%

R

05/07/10 13:49:29 02 5.62

%

R CO2 13.67

%

R

05/07/10 13:49:49 02 5.49

%

R CO2 13.43

%

R

05/07/10 13:50:09 02 5.32

%

R CO2 13.79

%

R

05/07/10 13:50:29 02 5.29

%

R CO2 13.67

%

R

05/07/10 13:50:49 02 5.31

%

R CO2 13.92

%

R

05/07/10 13:51:09 02 5.42

%

R CO2 13.79

%

R

05/07/10 13:51 :29 02 5.58

%

R CO2 13.67

%

R

05/07/10 13:51:49 02 5.73

%

R CO2 13.55

%

R

05/07/10 13:52:09 02 5.80

%

R CO2 13.43

%

R

05/07/10 13:52:29 02 5.70

%

R CO2 13.43

%

R

05/07/10 13:52:49 02 5.58

%

R CO2 13.67

%

R

05/07/10 13:53:09 02 5.51

%

R CO2 13.43

%

R

05/07/10 13:53:29 02 5.47

%

R CO2 13.67

%

R

05/07/10 13:53:49 02 5.43

%

R CO2 13.92

%

R

05/07/10 13:54:09 02 5.41

%

R CO2 13.67

%

R

05/07/10 13:54:29 02 5.48

%

R CO2 13.55

%

R

05/07110 13:54:49 02 5.44

%

R CO2 13.79

%

R

05/07/10 13:55:09 02 5.35

%

R CO2 13.67

%

R

05/07/10 13:55:29 02 5.40

%

R CO2 13.67

%

R

05/07/10 13:55:49 02 5.49

%

R CO2 13.55

%

R

05/07/10 13:56:09 02 5.51

%

R CO2 13.67

%

R

05/07/10 13:56:29 02 5.46

%

R CO2 13.92

%

R

05/07/10 13:56:49 02 5.53

%

R CO2 13.43

%

R

05/07/10 13:57:09 02 5.62

%

R CO2 13.55

%

R

05/07/10 13:57:29 02 5.54

%

R CO2 13.55

%

R

05/07/10 13:57:49 02 5.54

%

R CO2 13.67

%

R

05/07/10 13:58:09 02 5.54

%

R CO2 13.55

%

R

05/07/10 13:58:29 02 5.52

%

R CO2 13.43

%

R

05/07/10 13:58:49 02 5.51

%

R CO2 13.79

%

R

05/07/10 13:59:09 02 5.48

%

R CO2 13.79

%

R

05/07/10 13:59:29 02 5.55

%

R CO2 13.79

%

R

05/07/10 13:59:49 02 5.62

%

R CO2 13.67

%

R

05/07/10 14:00:09 02 5.57

%

R CO2 13.79

%

R

05/07/10 14:00:29 02 5.54

%

R CO2 13.55

%

R

05/07/10 14:00:49 02 5.41

%

R CO2 13.55

%

R

05/07/10 14:01 :09 02 5.30

%

R CO2 13.67

%

R

05/07/10 14:01 :29 02 5.35

%

R CO2 13.67

%

R

05/07/10 14:01 :49 02 5.44

%

R CO2 13.67

%

R

30
05/07/10 14:02:09 02 5.58

%R CO2 13.92

%

R

05/07/10 14:02:29 02 5.52

%R CO2 13.55

%

R

05/07/10 14:02:49 02 5.52

%R CO2 13.79

%

R

05/07/10 14:03:09 02 5.48

%R CO2 13.79

%

R

05/07/10 14:03:29 02 5.38

%

R CO2 13.92

%

R

05/07/10 14:03:49 02 5.29

%R CO2 13.92

%

R

05/07/10 14:04:09 02 5.25

%R CO2 13.92

%

R

05/07/10 14:04:29 02 5.19

%

R CO2 14.04

%

R

05/07/10 14:04:49 02 5.25

%R CO2 13.67

%

R

05/07/10 14:05:09 02 5.29

%R CO2 13.79

%

R

05/07/10 14:05:29 02 5.52

%R CO2 13.67

%

R

05/07/10 14:05:49 02 5.80

%R CO2 13.43

%

R

05/07/10 14:06:09 02 5.74

%R CO2 13.55

%

R

05/07/10 14:06:29 02 5.66

%

R CO2 13.31

%

R

05/07/10 14:06:49 02 5.62

%R CO2 13.43

%

R

05/07/10 14:07:09 02 5.54

%R CO2 13.55

%

R

05/07/10 14:07:29 02 5.57

%R CO2 13.67

%

R

05/07/10 14:07:49 02 5.63

%R CO2 13.67

%

R

05/07/10 14:08:09 02 5.68

%R CO2 13.55

%

R

05/07/10 14:08:29 02 5.59

%R CO2 13.43

%

R

05/07/10 14:08:49 02 5.54

%R CO2 13.67

%

R

05/07/10 14:09:09 02 5.54

%R CO2 13.67

%

R

05/07/10 14:09:29 02 5.38

%R CO2 13.79

%

R

05/07/10 14:09:49 02 5.13

%R CO2 13.79

%

R

05/07/10 14:10:09 02 5.00

%R CO2 14.16

%

R

05/07/10 14:10:29 02 5.07

%R CO2 14.04

%

R

05/07/10 14:10:49 02 5.11

%R CO2 13.92

%

R

05/07/10 14:11:09 02 5.29

%R CO2 13.79

%

R

05/07/10 14:11 :29 02 5.53

%R CO2 13.55

%

R

05/07/10 14:11:49 02 5.57

%R CO2 13.55

%

R

05/07/10 14:12:09 02 5.47

%R CO2 13.79

%

R

05/07/10 14:12:29 02 5.44

%R CO2 13.79

%

R

05/07/10 14:12:49 02 5.51

%R CO2 13.55

%

R

05/07/10 14:13:09 02 5.58

%R CO2 13.55

%

R

05/07/10 14:13:29 02 5.54

%R CO2 13.92

%

R

05/07/10 14:13:49 02 5.55

%R CO2 13.79

%

R

05/07/10 14:14:09 02 5.58

%R CO2 13.43

%

R

05/07/10 14:14:29 02 5.63

%R CO2 13.67

%

R

05/07/10 14:14:49 02 5.57

%

R CO2 13.55

%

R

05/07/10 14:15:09 02 5.48

%R CO2 13.55

%

R

05/07/10 14:15:29 02 5.49

%R CO2 13.67

%

R

05/07/10 14:15:49 02 5.57

%R CO2 13.67

%

R

05/07/10 14:16:09 02 5.65

%R CO2 13.55

%

R

05/07/10 14:16:29 02 5.71

%R CO2 13.43

%

R

05/07/10 14:16:49 02 5.71

%R CO2 13.55

%

R

05/07/10 14:17:09 02 5.63

%R CO2 13.55

%

R

05/07/10 14:17:29 02 5.48

%R CO2 13.67

%

R

05/07/10 14:17:49 02 5.36

%

R CO2 13.79

%

R

05/07/10 14:18:09 02 5.32

%R CO2 13.79

%

R

05/07/10 14:18:29 02 5.26

%R CO2 14.04

%

R

05/07/10 14:18:49 02 5.25

%R CO2 13.67

%

R

05/07/10 14:19:09 02 5.24

%R CO2 13.79

%

R

05/07/10 14:19:29 02 5.22

%R CO2 13.67

%

R

05/07/10 14:19:49 02 5.30

%R CO2 13.92

%

R

31
05/07/10 14:20:09 02 5.24 % R CO2 13.79 % R

05/07/10 14:20:29 02 5.26 % R CO2 14.04 % R

05/07/10 14:20:49 02 5.51 % R CO2 13.55 % R

05/07/10 14:21 :09 02 5.64 % R CO2 13.55 % R

05/07/10 14:21 :29 02 5.59 % R CO2 13.55 % R

05/07/10 14:21 :49 02 5.57 % R CO2 13.43 % R

05/07/10 14:22:09 02 5.51 % R CO2 13.67 % R

05/07/10 14:22:29 02 5.44 % R CO2 13.55 % R

05/07/10 14:22:49 02 5.26 % R CO2 13.92 % R

05/07/10 14:23:09 02 5.20 % R CO2 13.92 % R

05/07/10 14:23:29 02 5.32 % R CO2 13.79 % R

05/07/10 14:23:49 02 5.36 % R CO2 13.67 % R

05/07/10 14:24:09 02 5.38 % R CO2 13.79 % R

05/07/10 14:24:29 02 5.48 % R CO2 13.43 % R

05/07/10 14:24:39 02 5.48 % R CO2 13.55 % R

05/07/10 14:24:49 02 5.44 % R CO2 13.67 % R

05/07/10 14:24:59 02 5.46 % R CO2 13.55 % R

05/07/10 14:25:09 02 5.46 % R CO2 13.55 % R

05/07/10 14:25:19 02 5.47 % R CO2 13.55 % R

05/07/10 14:25:29 02 5.51 % R CO2 13.43 % R

05/07/10 14:25:39 02 5.58 % R CO2 13.67 % R

05/07/10 14:25:49 02 5.64 % R CO2 13.55 % R

Avg 5.51 13.63

32
Post3Bias James River Cogen

Unit NO.2

Post Run3 Bias Metals/PM-10

05/07110 14:26:29 02 5.63

%R CO2 13.55

%

R

05/07/10 14:26:29 02 5.64

%R CO2 13.67

%

R

05/07/10 14:26:34 02 5.68

%R CO2 13.79

%

R

05/07/10 14:26:39 02 5.71

%R CO2 13.55

%

R

05/07/10 14:26:44 02 5.75

%

R CO2 13.67

%

R

05/07/10 14:26:49 02 5.77

%R CO2 13.67

%

R

05/07/10 14:26:54 02 8.56

%

R CO2 13.43

%

R

05/07/10 14:26:59 02 10.61

%

R CO2 10.62

%

R

05/07/10 14:27:04 02 4.65

%R CO2 4.76

%

R

05/07/10 14:27:09 02 1.70

%

R CO2 1.71

%

R

05/07/10 14:27:14 02 0.70

%

R CO2 0.98

%

R

05/07/10 14:27:19 02 0.37

%R CO2 0.37

%

R

05/07/10 14:27:24 02 0.23

%

R CO2 0.37

%

R

05/07/10 14:27:29 02 0.18

%R CO2 0.12

%

R

05/07/10 14:27:34 02 0.15

%

R CO2 0.12

%

R

05/07/10 14:27:39 02 0.13

%R CO2 0.24

%

R

05/07/10 14:27:44 02 0.12

%R CO2 0.12

%

R

05/07/10 14:27:49 02 0.12

%R CO2 0.00

%

R

05/07/10 14:27:54 02 0.11

%

R CO2 0.00

%

R

05/07/10 14:27:59 02 0.11

%R CO2 0.24

%

R

05/07/10 14:28:04 02 0.10

%R CO2 0.12

%

R

05/07/10 14:28:09 02 0.10

%

R CO2 0.12

%

R

05/07/10 14:28:14 02 0.09

%

R CO2 0.12

%

R

05/07/10 14:28:19 02 0.09

%R CO2 0.24

%

R

05/07/10 14:28:24 02 0.09

%

R CO2 0.12

%

R

05/07/10 14:28:29 02 0.09

%R CO2 0.12

%

R

05/07/10 14:28:34 02 0.17

%

R CO2 0.12

%

R

05/07/10 14:28:39 02 4.39

%

R CO2 1.22

%

R

05/07/10 14:28:44 02 9.52

%R CO2 4.52

%

R

05/07/10 14:28:49 02 11.38

%R CO2 6.23

%

R

05/07/10 14:28:54 02 12.02

%

R CO2 6.84

%

R

05/07/10 14:28:59 02 12.23

%

R CO2 6.96

%

R

05/07/10 14:29:04 02 12.28

%R CO2 6.96

%

R

05/07/10 14:29:09 02 12.33

%

R CO2 7.32

%

R

05/07/10 14:29:14 02 12.35

%

R CO2 7.08

%

R

05/07/10 14:29:19 02 12.40

%R CO2 7.45

%

R

05/07/10 14:29:24 02 12.43

%

R CO2 7.32

%

R

05/07/10 14:29:29 02 12.43

%

R CO2 7.08

%

R

05/07/10 14:29:34 02 12.44

%

R CO2 7.32

%

R

05/07/10 14:29:39 02 12.45

%R CO2 7.45

%

R

05/07110 14:29:44 02 12.45

%R CO2 7.32

%

R

05/07/10 14:29:49 02 12.45

%

R CO2 7.45

%

R

05/07/10 14:29:54 02 12.46

%

R CO2 7.32

%

R

05/07/10 14:29:59 02 12.46

%

R CO2 7.45

%

R

05/07/10 14:30:04 02 12.48

%R CO2 7.32

%

R

05/07/10 14:30:09 02 12.62

%

R CO2 7.45

%

R

05/07/10 14:30:14 02 16.44

%

R CO2 8.30

%

R

05/07/10 14:30:19 02 19.93

%

R CO2 10.50

%

R

05/07/10 14:30:24 02 21.25

%

R CO2 11.60

%

R

05/07/10 14:30:29 02 21.69

%R CO2 11.96

%

R

33
05/07/10 14:30:34 02 21.84 % R CO2 11.96 % R

05/07/10 14:30:39 02 21.90 % R CO2 11.96 % R

05/07/10 14:30:44 02 21.92 % R CO2 12.08 % R

05/07/10 14:30:49 02 21.95 % R CO2 12.21 % R

05/07/10 14:30:54 02 21.96 % R CO2 12.08 % R

05/07/10 14:30:59 02 21.97 % R CO2 12.08 % R

05/07/10 14:31 :04 02 21.98 % R CO2 11.72 % R

05/07/10 14:31:09 02 21.98 % R CO2 12.45 % R

05/07/10 14:31 :14 02 22.00 % R CO2 12.33 % R

34
· .... .......

........

•••• I)' I •• ....•,•.... .• " ••••I'

.........

......

....

AirNova, Inc .

5845 Clayton Avenue, Pennsauken. New Jersey 08109

(856) 486·1500 • FAX 486·9896 • \'1."" almovacom ISDKINETIC SAMPLING DATA SHEET

Project No.----=J....:'>....:'.=-~ ....:\' _

Date S - '"':J - } 0

Facility -:s ".. "- •sR', \I '" < .;; dC' 4 <: ex

Location Uc,~ l\ ':2 5,i..., ... k 6<.,-jh~

Method I SampleType ePA <; /'d-{)?

Run No. Or- '-- Operator[s)::::~:)~J Tn S

P Bar ["Hg) 2 I. '1 V Static Press.["H20) 4 ,'55

Silica Gel Number_-f)(";-'-e.;-13-=--i<:.l-:;;-::;:-----,;;--;;;-::::--_

H2 0 Pickup [mL) -T 11 (;.f-- 23.7-::- 2( '7. 7

Leak Check Pre-Test =0,1)(,)3 @15"Hg Post-Test =,-,,-lO~€ '9-Ig

Probe No. ..':.. f~'· '5 Type 6 j£.s S

Nozzle No. G LI1 ss 1.0. So

Meter Box No.__I1"-- "H@ ) {, (.

Y Factor _-,-,I,--,0,,-,'0"'- _

Pitot Number__~J....:' Cp 0, ~~ '1

Sample Box No. ------------

Assumed Moisture [%) _---:.\.::;:0__=-- ---

Assumed Meter Temp. [OF)_....:(6=:-'1-"-- _

O2 :5. 'S [%) J:'1 '1

CO2 1'3 , 'S [%) /3. f.S~

[Isoklnetlc Data Sheet Single Sided Rev.1 12/08)

Traverse Sample Start Gas Velocity Orifice Preesure Stack Meter Pump Sample Impinger

Point Time Clock Meter Head (in. H20] Temp Temp, Vacuum Box Temp r ~'Q b

Number (min.] Time Reading (in. H20] (OF] (in. H.] Temp (OF] - ft' desired actual Inlet Outlet (OF] J';",....p,

(OF] (OF]

~I (.) o 7i IS ~4W,. 0'\') !J. ':j t1 , "'1\ \ ,,\\ ").\5 ":/1 t '1 H.O ')/f"'l Ci 1",:1.5::3

't., j t) I <) "'.;> \ • eb'dO O. (. i J "5>1) /. '51\ -;;lId '"':j'S ':;1 5. 0 "';;l. ~5 \ 5';( '). 63

7 ....2:."" \1; qsq. 165 O. SL~ j. J-j 0 !'10 '?\\ """;j'"';j --4 -;) bI. D 'd- s \ 5"& ";) qc,

'5 V' 0-=1'1':> '"1' ~, c

l, - - - - - - - - - - @ , ;; (;) () ':J 'S 1 '1'5 Ci

I , '='6 0,":./ 5 i. "L.j \."v-\ ';;}..\O "ill -=i <-( 5. 0 "J.'S""i is ? S'i

. -'/ () i "'1"=\3 . -~ Lj S O. C"":\ \,-.\"3 \,":J] ?,\ 0 ~O ~~ 5 j..j,5 ?Lf"i (, i "d-S"=i

; 'j'D ~U Co, "6 \ , ·~:!O 0, 41..\ I . I", 1.1"1 ';).o~ \ -=i ( 4. e) ?-60 (; 3 ? c ,:,

to ,,"OJ, "). \ '"'1 -:.) . 6S'). - - - - '- - - - - - '.0, t .,' M1.l '1 ':i. CS'Z O.'71i l. "\ I I."', \ "JD~ "63 "'=1"1 S, 0 ') '::' d t'S1 ?6'3

.... -::iO l c,"\'5, 1.-\ (, OS () 6 '\ \ • "':, C''\ 1.""1",- ? ''- "!:,''"). ~o -;,. 0 '?'S>y 6S -;) OS--=:)

:> ~o 0 ) 003. ) (,5 0.'5\ I· ~";). {. '::> YJ ?o~ ~5 ~\ 4, 'S "d--.Lf to 5'5

1cJ l>".l-S (; \O() ~. '). .- - - - - - - - - (':;) I ~\ t- O c, C t,; 10""'1. <;s."=i-1 0:; y d.O'- 7..0<.. '~\o '6 S ~'5 5. 0 ? '-I e'\ (; G ,;>S-:.)

<: i 0';) I ,01 "';j, ~';l.'5 o,-:'-:L J, '<i , I. ~6 ?\~ '5J Y 'I ), :5. 0 'J'S0 61 ? S?

') ;)0 ,L \\:;';).5. (. Lj 0 (), 'S '-i \.1; 0 I. 'i 0 ";;l \ '\ "! (, ,;r~ 5. 0 ? s·z. 5'l5 'd.6-5

\'Z..G.} 0"\ ')() 10)';1. 6';;lb - - - - - - - -- - - -......... If~r,1-;,1)

I~

.JJ
.....

.......

........

.•• 80 ••• ,

""lIfie..·, .........

·.1 •••• • ....... , ...

Inc.

5845 ClaWln Avenue, Pennsauken, New Jersey 08109

(8561 486,1500 • FAX 486,9896 • WlNI almova.com ISOKINETIC SAMPLING DATA SHEET

/,00

Project No.=:"';;S</;,

Date S - ";>. - \0

Facility -S <,,....~., (z.". v<_ r C Q ')V "'--\ <;;', .~

Location u~: \ .~ ? s-\"",H 6L~hJ

Method / SampleType is ('" oS /' -;;l.c:?

Run No.-I'w u Operator[sJ J HJ 1'" 'S

P Bar [UHgJ ? 0 0 ':!-- Static Press.[UH20J +0. n/"

Silica Gel Number.,...--'c')0-.::{,-,J(:.:::3:-,(,,~_--::-_---=-__

H2 0 Pickup [mLJ ±19f;. f- 2-1. ('C.. :J..A7.1

LeakCheck Pre-Test=D,OIP:j @15"Hg Post-Test =0 C/QIJtJ"Hg

Probe NO._---'-A-':;";.:..J_"_,~"$'-- Type._-=~,-",-,'",-,"'=-)=--_

Nozzle No. Ctt\ J' J 1.0. _-,-'c..:J-e:....;:'S...:;<'=-:>__

Meter Box No. y I\H@---,-J..:-. .=.'--,(,'-.· _

Y Factor

Pitot Number__-----"s'-- Cp ~,L:''G'-t1'__ _

Sample Box No., _

Assumed Moisture [%J _-:.I=:O~---------

Assumed Meter Temp. [OFJ--:::_'1.!-("") _

O2 5. S [%) s.c. r

CO2 \ 3, '$ [%) /3. s':g

Traverse Sample Start Gas Velocity Orifice Pressure Stack Meter Pump Sample Impinger f\.,6 Point Time Clock Meter Head (in. HaO) Temp Temp. Vacuum Box Temp

Number [min.) Time Reading [in. H20) ["F) [in.H,) Temp ["F] .-o'

ft3 desired actual Inlet Outlet ["F) ""-Y'o'

[OF) (OF]

I C (19'5<: O"',":l . "6"\0 () ,-:; l I. €j '::( J. 7 7j ").I?. ~6 'is .-/ s. 0 Q6 Lf G''1' ?S?

'- \ " J 01-10, CJoo O. C";( I. G'5 I. 65 t;J.\?, ~"1 8b 1.0 ~60 6 'f '.;I. S 3

;. "- '" ,l uf..j"6. ";)."40 O. SO \ . ..." 3 1'5 ';)..IS ~;j 'S 'ii5 :5. 0 ?4'ii' 6Ci ')S-::t

''S '-' )o:::>""J. () ') 5, O~S - - - - - - -. - - ""]v ,0 ,,-,-,\ O<,S, o6t:, () --1 S <). (,)0 ?,00 ~\J. "(,":'> 'b c: i .) 5. 0 ").. 'S 0 6'3 ?s '7

<. '-]0 I 063 ISO (. "":i"3 \.,') l. '1 ") -;)/'1 '15 -:;t 2f 5 3, 0 ? S::t '5 t :is:;

':> t.~ -1 () -1 I. 060 0 "j --I ,. 'S ") I '5 ';l ";;).\';;1 ''10 '2b 3. 0 '). S e-) l-IC ?-s

(& \0')"'\ ("1":( 'it . \ '\? -. - - - - - - - - \ (, :J 110 v O~ 'g. I <::1 '~ (),-~'5 ').. Go 2.Ue) 'd.\~ C1? 90 '"3.0 I";). 'S \ 6)1 ':J.4t

"- ~lJ I o~f.,. '''';;)' c::> 0 4{) 1."6 -:j ,. '?--.) ').l!-\ <; C> "6 C\ '3, <;) ?5(;, {, 's. ~"'::':

.", <;(Q ~1 ()<\1.\_ () '6 OS '0. 51-\ I. "l'-\ (,t.fl-f d-.'~ "1 !-\ '\() 5.0 oa.S£ G\ ? S Co.

"\0 I\'"'>G 1 () \" o C) Lj - - - - - - - - - - \ '\ v In') 10 \ . OS'1 0.~~ 'do.O<i" '<.0 "'i d. '

<;' "JS c,s 7- () "2...,.---/ (1 I) &ti

<.. \ () l> I \ oel \ \ 0 (\, 7.i ":J I. Cj J I. '7 ':l.\'i '1'i 9) '3. (.) 'J.. y S' 60 d- 61

;, \ \ 0 J; \\"1. :'05 0."50 i."rs I. "5 "'>;, ~\\ "\"5 c\ 'i J.O ';;).'50 6'). 'd Si

\'l.O 1<0\ I';} "1. I'" ~:::l. - - - - - '- - -

1(1/.;'-rv)

';>0 (Isoklnetlc Data Sheet Single Sided Rev.1 12/09J
. ..... .. . •• •••• 4.

.., .,•.... .. . ' ".' ...... .....

AirNovs, Inc .

5845 Clayton Avenue, Pennsauken, New Jersey 08109

{856} 486-1500 • FAX 486-9896 • WM'I almova, com ISOKINETIC SAMPLING DATA SHEET

Type (, I<$~

1.0. .? 51-?

AH@ I. ~L

Cp '0 .. 3 It

Probe No. f.",rv S

Nozzle No. GLi4S.r

Meter Box No.__3---"- _

Y Factor _---'''.:..c."::..::·0'----::- ....,--,- _

Pitot Number__----'S~ _

Sample Box No., _

Assumed Moisture [%J ( 0

Assumed Meter Temp. -[O-F]~='c.-c):---------

O2 5. S [%J 5: LtC)

CO2 13. S [%] (3.(,1

Project NO,----'·Jc.:;J_.z,_'6 _

Date '5 - -I - J 0

Facility ::5"',-,>5, (2,',\)&, Lv<,,,-,,\<: .,(

Location \J,,:-I iJ '::l 5~ -. <-It o,.1! ,,-{

Method / SampleType t: P/l 7 / ·;lto':l.

Run No:-l\.-<",-... Operator(sJ I '" 'S

P Bar (UHgJ 21. 9Y Static Press.[UH20J +0 n-'

Silica Gel Number__.J-f-'---n.!.--'3-"'--"'-?__;;:-c- _

H2 0 Pickup [mLJ +/1lf t"U!.,t.., 2i'1, y

Leak Check Pre·Test =<l.OO {@15"Hg Post-Test = (lc)~@7UHg

Traverse Sample Start Gas Velocity Orifice Pressure Stack Meter Pump Sample lmpinger f, ,~,,:>,,- Point Time Clock Meter Head [in. H2O) Temp Temp. Vacuum Box Temp

Number [min.) Time Reading [in. HaD) [OF) [in. H.) Temp [OF) -- ft3 desired actual Inlet Outlet [OF) Jr-<'''"'F,

[OF) ["F)

;;;> I () I '.).1 \";).I-j • l.1Sl-J () -':J Lf \ . "\ ~b \ - <'\ "'1 '?15 ~'d. "I:> 5.0 ,') 'S 0 (, 5 .') S '-1

<. i () r \:, d.. (,\Q O. tG, '6 I. \ I. '1S \ 'J.l 'S '\\ '13 S. [) ")s ':J. (" 'd-So

:> Z.D IU \40, 3~o o S \ .'"'J f. \ .)(, ?,1"1- ~""':> "'I "'.) 4. () ':14"(, 55 ') "S S

'3 () ld-.'1L It-/":/ . 063 - - - - - - - - - - 3'J I '1 .... \'1..4~ l'i ":) , 06:5> O. ~~I ") J..OU ::2.Vi.~ ?-I i'1 ~11.f '5.0 ";) ~.:' (, cli ".)6'5

<{ '-' \ is?. 1(,5 () , G ;; I -:j'l I. ::; 'd. I -:j '1"5 9L.j 6.0 ';} 'S \ S-=1 'J C';)

.5 c::} 0 I C,)_ ,,\<,'S 0:" '6 \. J'~ Li'J,<;S ~I 'S C') -:l Ci ') 4.5 "J'S S 5-:; ? t "1

bC> \';;\ 16 e,. 5& 3 - - - - - - - - - -

:j£I i. C> \5'2.'5 i(, CJ , 563. (') . -~ <') ') .1.\ ';). \ '\ ')10 "\\ S. "5 \ "\\ .). -S '-I (; "'I ')6 0

"'t. -~O I ,--\ ':\, -:; s () 0, f/3 I."lS ;, '95 ':l14 <'"\ \ '"\\ t.O t),S5 t"'l ",).6" I

'1 ~6 \) 1"':s5,'6'iS O.~~ \.1..\ \ I.Yl ?I~ ." \ '10 $.5 '?-:sC ~5 r;}. 6 'j

Ct 0 \ ",'S \ '\';.. "b <, :, - - -- - - - - - - 1) \ C\O \~56 \"\c. '6-"5 o. '".:Jl.. \. '11.. L"'~ ?ll..\ ci 0 "\ 0 t.O '?Y c,\ .:; .... ? OJ

<- led I 2<)0, ""4l0 (), ':.., J. i '3 I 'T3 ';). 1 "" \ '" , -;':J.O ?SO 5'l 'J.6'()

3- \' u ,\; J.() 9. 1")0 o. 56 I. !.-I c\ i. J1 "', fJ.l "I "1O '2,"'1 -.:t. 0 ";).I-/"ii 51. D5"2

'·z() il-\ ";lG :} \ '5. "5 I'P'l - ....-. ~-.

----- - - ~-

/' .-......

CJ{.O?u)

"-------

oJ [Isoklnetlc Data Sheet Single Sided Rev.1 12/08J
. ..... ., ..... ,:: ;';:::. Ail"Ncl11!8 ., . ' . ..... ... 5845 Clayton Avenue, Pennsauken, Nell Jersey 08109

(856) 486-1500 ' FAX 4869896 ' WNwalmova,com ISOKINETIC SAMPLING DATA SHEET

Project No. :5,55 2! Probe No,,_-,---"AC-.::/lJ,-'-=.5_· Type G/cL.JJ

Date 5 7 -/9 Nozzle No. r:; C4J'l 1.0., :< 5" (;

Facility J"Ctrr>f.'.> (2;....( (' C9~eo to Meter Box No. 7 AH@ I, 'i{(J

Location 5!l3Cf::' Of/Ie E'T V,'V.L lA ';). Y Factor _--,-f-=--.Q-'.-('---------=-r,--

Method I SampleType E 'Pn d. eor Pitot Number__-"'S'--__ Cp Q, 1 9

Run No. Gel) C Operator[s) ("1-J S, (/-I Sample Box No.__----'=-~=------ P Bar ["Hg) Z. ~'. 7Y StaticPress.[''H20) ttl, n..... Assumed Moisture [%) __-')-:;(2;-:;:- _

Silica Gel Number fn2r Assumed Meter Temp. [OF)-,:--~~~5,,--- _

H20 Pickup [mL) -tJ.-1b ·hr:'i-=- :;'~/·i O2 §.t; [%] s.'f~

Leak Check Pre-Test = CLOD b @15"Hg Post-Test =tJ. 00 1@?"Hg CO2 /), 5 [%) 13. (,.r

Traverse Sample Start Gas Velocity Orifice Pressure Stack Meter Pump Sample ImpingeI' fro 6 Point Time Clock Meter Head (in. HaD) Temp Temp. Vacuum Box Temp

Number (min.) Time Reading (in. HaD] (OF) (in. H.) Temp (OF] jR~ ft3 dasired actual Inlet Outlet rF) 9(:, (OF) (OF)

, • 00 07J!S 5tS; :JJI(; ,1<1 ::;ot ;;J,Q'l ;;2 II 1;;] 1(;1 6',0 :2..'5"0 G'iJ :JL/1

.2 10 57.3. -- ~7L) J, cr 7 ren 21 Q 74 7/ s: 0 :2.1f7f S-1 :2j+~

3 2.0 K~ 1< 1'27 J ('Jf /.70 /70 ;201) 76 7/ '3.0 ::(50 f;9 ;;::!f

- 30 b7:~ ,5<Ji:dLf 0 - ---- - -- - -_. -- -- -- --

I 30 07 S·- 1,,,< S'1J $.:J Yc. .7Lf 1,'17 ;, CJ7 ;)09 77 7/ 7.0 ;;<03 57 :25

;), ,,+-0 5·9.5,90Cj (iO I.S~ Iff? ;QO~ 7'3 7/ 5' 0 :<S~S- 5/ Q5

:s 5"'0 I~ (;,03, :23) I~" I 1,3(; /3' .106 51( 7.s t;~o X/ 53 ';;)5:;

(,0 I

bO~ ,71 b f.--- - Q&,;;)."J -- - -- -- -- -- -- I--

I GO ~'2r;, 6()q tet b /"7t:j :::r.O? ~.(?o !~O9 79 73 '5.0 ;;)5 ] 67 Q$Lg'

70 /7.14-Cb 17"3 U:;lf /.CfL/- :LO'1 55~ /3 5..... 0 ~4::< t;C] ~¥-~.

3 55'0 62A. 'j0~ J If C, I, :12 ).2). :20S' 1S( 71- 5~o 9,55 C;O Q"S' :

- 0,0 b~,5b 1(;"31, I 7:~ -_. - - --- -- -~ -- -_. -- -

I q 0 ;lj,'o<J h31. /7's JI I J/is'1 /.1f9 ;)oq 7'1 7Lf ~,O ~53 ~"$ :;) l/~

J. ( Q (l b.S"D, 5 7 ) ,5c; /, 5'') Il;7 ~o9 79 7-::2 s: 0 e-~,,- C75b.. 5~ ,QIJ-rs

'3 110 04-5.6' I Lj. ,if5" 1,20 /':)0 Q...Q~ 1)l 73 If. 0 :;).5Q 5"Y Q~~

i;::w , 65{, J)' Lf d - - - )':;'30 -- --' - -- -- - ----+ .~

(r:rfo.J.7Y :

,;)0 [Isoklnetlc Data Sheet Single SIded Rev,1 12/08)
,"'. ......

ISOKINETIC SAMPLING DATA SHEET

Inc.

5845 Oayrnn Avenue, Pennsauken New Jersey 08109

(8561 48&1500 ' FAX 48&9896 ' W'MV B1movaGom

.::::i:;::~. AirNova, • ,. 8 •• ··- '., ..... -

... ,.-' ....

Project No, 133?S Probe No. AN :f:,- Type G/q>S

Date S""-)?/o Nozzle No. C{==4S J 1.0. ,;9...¥(;

Facility CT~e R~ \,It' r Lose nCo Meter Box No._~Z<-c:- I\H@ ). $0

Location S··Tec}:. 4br!. £ T UMk/ #-Q Y Factor _---')..L.-'_0-'-1 --:::7-,---_

Method I SampleType ellA ,,';1 '1 Pitot Number_~r,-- Cp Q 0 trYRun No.-<fv-o 0 Dperator[sJ /l'LJ"> , T/+ Sample Box No.__--'-=__--=- _

P Bar ["H9J :3 (), " z...- Static Press.n420J +.0.. n/ Assumed Moisture [%J /...-'Oc.".- _

Silica Gel Number I :L(;. Assumed Meter Temp. [OFJ "65'

H20 Pickup [mLJ +t"f?tlc. r-:~ ;L( 'I. r O2 ..;,;-5.5' [%J -S-:-."-r..,-=""------

Leak Check Pre-Test = Q~@15"Hg Post-Test =Q.OOf£"Hg CO2 /3.£ [%J 13,5-.J

Travel'se Sample Start Gas Velocity Orifice Pressure Stack Meter Pump Sample Impinger ~\<l 6f:

Point Time Clock Meter Head [in. HaD} Temp Temp. Vacuum Box Temp

Number [min.} Time Reading [in. H teCVIc 2 0] [OF} [in. H.} Temp [OF}

ft3 desired actual Inlet Outlet rF) Of' ("F) [OF)

} 00 1j ;51< G5.;2,~ ,73 /0;4 /94- :<"1 ,<g 7+ .6',0 ;)53 60 Q!-9

) 0 t~· 0, ;.;{3 \ 64- I. 70 J70 2/0 <iQ )5 5.0 =<:55 SC: ::2 L})?

'?

.) :20 GG 7. :\~:S' .53 1/+6 J.'-!b :2. 1G 10 7.1 5J;) '2.<)1 5.5 .;:)~C

---- 30 M;Q~ G7'f < bY h - - - -- -- - -- -- 1 '30 IO:Jt.j- Ih71f;GCfb ,,70 ;. '6'6 J,<tt 2./.1 'is { 7C- 5~ 0 1.:2~ (; fLf ~<Jjf

If()! I&'$'~, OO;l::- "&-7 1.1«, 1.7~ :lltf 'I!~ 75 .5.0 :26.5 1/-9 :<J)-g

'5 'So b'ffCj, 595 5''-' 1/,4/ J,4 I I" b ;,Q( ( g~ 7~ !J.O ::2.5<i! c"!ro ~5J

- bO /0,:5Lf b9&.QCbt]' -- .----- -- ~. - --, --

l (,.,,0 1'1 ,(). ' 0 (;/i(; / ~<i 5 ·7::2. 192 l Cfd.- h<'I.J 1f1 1et !5:0 ~5L-f .. :;)~2

:J, '70 703·7<t;Cb .6Cf I, fjLf I. gLf ;21~ cg/ /j- -5'.(2 ~53 5<15 :JJ-!->t

'3 <if 0 7/ {,.307 I GO /.(;0 }.~O 1Sl-}3 79 '75 5. Q ;;)~7 bO ::<51

- 00 II :JO 7/$, :;J.!JO --'0 1- -- - -- -- -- --- - I 90 1/ :)3 7/.g. ;;2.5 9 .70 11 gb I.'h& ,>(13 ~I 77 S- O ~S 1 b<6 ;)SC

;00 /.;<3. 1f9cr .<6 I, '3/ ).15 ( ::J..1~ :B'J 77 5', 0 C;Z53 66 Q'I-?

'3 /1 0 1st.e,e,e ,53 1/4-/ I, YI ;),):2 <j)~ 7<Z !f 0 ~5h fb ::21-~

- 1.20 IJ,:031737, 5;;( 7 ________:J - - -- - -- -- ~-

--- Vff. 2-31)

'" .-/ -

.;)';2 (Isoklnetlc Data Sheet Single Sided Rev.1 12/09J
· .... ,II., .

.. """

.;:;~;~;::. AirNoval Inc. ·.1 ••• I"

': ~:::::" 5845 Clayton Avenue, Pennsauken New Jersey 08109 '" ., (856) 486·1500 • FAX 486-9896 • Wlm al1'l1ova.com ISOKINETIC SAMPLING DATA SHEET

Project No. '333' Probe No. A;G ~;-. Type Iq 5" S'

Date 5 - 7- 1 0 Nozzle No. r; LA.;J 1.0.. ,;z ¥ {;

Facility JcftrlC' :? (j?, <.Ie r CO'ieo. Co Meter Box No.__7-<-- AH@ /. e0

Location 1TflCI;:: OU7LEy.... VA/IT *~ Y Factor --IJ,,-,-,,-0--,-1---------:T"-

Method/ SampleType EZA Q. 0; PitotNumber__~£,--__ Cp----"Q.f->-.---,-gL-·7'-'-----_

Run No./h'C" e Dperator(s] (>l::::lS: , I f.! Sample Box No. ----;c--~----

P Bar ( "Hg] Z 2·1Y Static Press.('l-f20J +ci. r J Assumed Moisture (%] t 10

Silica Gel Number f17J& Assumed Meter Temp. (OF] .!L7)--=::5':.------

H20 Pickup (mL] t2-c.J L{ tic". 'Z- -=. l:Z_o. 'Z.- 0 2 !!' 5 (%] <;; '1';

Leak Check Pre-Test =O.co5@15"Hg Post-Test =o.OO'$'Hg CO2 J '3,5 (%] /3. (,?

Traverse Sample Start Gas Velocity Orifice Pressure Stack Meter Pump Sample Impinger ~(O~ Point Time Clock Metel' 1·lead {in. 112 0) Temp Temp. Vacuum Box Temp

Number [min.) Time Reading [in. H20] (Of) {in. H.) Temp ("F) ;e~y

ft' desired actual Inlet Outlet ("F)

[OF) (OF) Of

I ' /

oq I'd. 'I b 751 cg~ 7/ l.olJ jf5;e, ;),,1 if 'g',,:2 7t> '-.9 ~5,-? (;8" )/1

;) 10 7'f5, 'f7.5 .~1 /.'8'1 /.11'1 ;;;{/3 73'3 7 7 h.t? :<S5 0\ -;:)5

<')

::. ~Gl 7~~. 9:J. 7 :55 I. t-f6 I.'-!t, ;':2/3 ~~ 77 ~O ~:<55 c,C( <Q5:

- '30 1.2;'!{; 159.'37 '-- - -. - - - .- - - I JO /2:tr 751. '37 ,71f ;,9 7 r(.77 Q.llf "5'f 7'1 G'.(1 QlfCf c. g ~1f-

.). L(o 7 h 7, -;;z /'is ,7 I l.r.gq /."i5C; :115 1r3 79 (;.0 Q. 'f-?f l.jq ;;;<~

'$ JOjO 7 71./, 15b,t{ J05 ! 73 J.73 ~16 ~;;( 77 5' . Q :::2 G' I :5' 1 :::?!f-i - GO 13; r6 /¥::J. ] 7'+ - - -- -- -- - - -. - I ~o 113,:Zs 7?J;). /74 .75' ::2LJCJ ;),{)(J :;:2, I ("" ?J( 71J {. () :;;<6 J 66 Qlf'~

:2 70 ",' 7'3Cf, ?3Cj .70 I. [5, l~~ 2,/£j '15~ 79 ~.O ~~5:S 57 ~_S

...,

-') ~o 777. ·~O.5 ,~S" /,S'Z; 1.51:) ::<10 '8~ 7'1 Is-. 0 ;;),50 h( :J~" - 00 ." ~53 'i'otf '7.J . '---- "--- --- - ------- !::>. • . """,6 - -- -- - I '10 13 :56 'g04. «~b 1,7 2 00< 12 Q~ QI, ct::? <60 ". 0 :25;) ~i) ;;)9

2. )00 15{/!.ey3.5 , (..,?; I 5b I J. 'iI Q)(, ~'3 'i)J G·O Q5S b;;< ::< 2f (

:) (10 75'/9. '1:J70 53 1140 /,lfb d.,lt[ ~') -go 3'_0 ::<.5-'0 59 ~44' "" ....... 1;;)0 N~)G ~dh, ?;fiLb 0....--- -- ............ - --- - -

(rY.ls V )

\.. / -

I

£.IU (Isoklnetlc Data Sheet Single Sided Rev.1 12/08]
Appendix B

Laboratory Data

...... ".. • • .. • 1II e ....

• , .... IS •• Ill •

... eOO_OGGh

• oe@ ••4!I@oo'

·"Ge@leDGe.··

" •• " 0 e 1Il •• ,

..... ., .... ........ :.

3338eval EPAS/wel 202 1 of 23

irNova, Inc .

5845 Clayton Avenue, Pennsauken, New Jersey 08109

(856) 486-1500 .. FAX 486-9896 .. www.airnova.com

NELAC & NJ Lab Cert. No. 04011

PA Env. Lab Reg. No. 68-1676

EPA Method 5 - Particulate Analysis Results Summary (Mass Data)

Client:

AirNova Project #:

Location:

Lab Book#:

Sample Date:

Date Rec'd:

AirNova @ James River - Hopewell, VA

3338 - Evaluation

Unit 2

5-3-54

5/7/2010

5/10/2010

Sample Train Filter Analysis

Run# Mass (mg) Tare(g) Total(g) Diff(g) Qual. Eval.

1 4.0 0.3702 0.3742 0.0040 gray

2 4.5 0.3797 0.3842 0.0045 gray

3 3.2 0.3569 0.3601 0.0032 gray

Acetone Rinse Analysis

Run# Mass (mg) Tare(g) Total(g) Diff(g) Samp.Vol(mLl

1 3.8 3.5766 3.5804 0.0038 200

2 2.7 3.8969 3.8996 0.0027 200

3 2.9 3.7630 3.7659 0.0029 200

Field Blank 3.3051 3.3051 < 0.0003 200

Gravimetric MDL= 0.3mg

Date

Date

rkl//o

b?""" - -/

Secondary Review

The analytical results obtained relate only to the samples included within this report.

This report should not be reproduced except in full, without the written approval of AirNova, Inc.

AirNova, Inc. certifies that the test results contained in this r port ret all requirements of NELAq. .

. {ttt i , ,<: [f r;' 2DjtlJ

La o.a.torJ ire~. /f;dJ117=/

1
; ...... '.. . • .. e It " ....

•• Q ..... fll •• "

.• ee.eeee ...

.•• ee•• e" .. ' •••• (I e 8··" ' ••• l!iJ ••• D·'

............

'''. '1'1 Q:'

Client:

AirNova Project #:

Location:

3338eval EPA5/wet 202 2

irNova, Inc .

5845 Clayton Avenue, Pennsauken, New Jersey 08109

(856) 486-1500 " FAX 486-9896 6 www.airnova.com

NELAP & NJ Lab Cert. No. 04011

PA Registration # 68-1676

AirNova @ James River - Hopewell, VA

3338 - evaluation

Unit 2

EPA Method 202 Condensable Particulate Matter Summary (Mass Data)

Lab Book #: EPA202-2-127

Sample Date: 5/7/10

Date Received: 5/10/10

mo =Mass of organic CPM, mg

mi = Mass of inorganic CPM, mg

mob =Org. Blank, mg

mib =Inorg. Blank, mg (Volume adjusted)

mi =mr * Vic / (Vic - Vb) - mc

mr =Mass of dried sample from inorganic fraction, mg

mc =Mass of NH4+ added to form ammonium sulfate, mg

Vie =Total volume of sample impinger contents, mL

Vb =Volume of aliquot taken for sulfate analysis, mL

Mo =mo - mob

Mi = mi - mib

Total milligrams of CPM =Mo + Mi

(top of Eq. 202-3, EPA202 Section 7.4 - modified)

Results based on applied NH4+ K=0.3542:

Run# Total CPM mg Mo mo* mob Mi mi mib mr me Vic Vb

1 2.7 0.0 0.0 0.0 2.7 2.7 0.0 5.7 3.35 665 40

2 4.9 0.0 0.0 0.0 4.9 4.9 0.0 8.6 4.23 720 40

3 7.7 0.0 0.0 0.0 7.7 7.7 0.0 8.9 1.82 650 40

Results based on calculated maximun NH4+ possible in residue:

Run# Total CPM mg Mo mo* mob Mi mi mib mr mc** Vic Vb

1 4.5 0.0 0.0 0.0 4.5 4.5 0.0 5.7 1.56 665 40

2 6.8 0.0 0.0 0.0 6.8 6.8 0.0 8.6 2.35 720 40

3 7.1 0.0 0.0 0.0 7.1 7.1 0.0 8.9 2.43 650 40

The boldfaced results represent the most realistic milligrams without under reporting Total CPM.

*Gravimetric MDL = < 0.3 mg

** Maximum Ammonium possible due to 27.3% of dried residue (mr) mc = mr x 0.273

The analytical results obtained relate only to the samples included within this report.

This report should not be reproduced except in full, without the written approval of AirNova, Inc.

AirNova, Inc. certifies that the test results contained in this report mel:::t all requirements of NELAC.

2
. !

... ; .; :. . ~::=:::':t:: . .. e." ....•• _.

••• •••••••• • lit •••••• " e'

- •• " Gil 0- lit .. • ,,-

•• e •• ell III ••

. : :' : .

3338eval EPA5!we1202 3

nc ..

5846 Clayton Avenue. Pennsauken. New Jersey 08108

(858] 488-1600 .. FAX 486-9896 • www.airnova.com

Notes concerning the correction for the Ammonia added during EPA202 analysis

During the Section 7 Equation 202-2 calculation, the total mass ofinorganic CPM

(mi) is obtained from the mass of dried inorganic sample (mr). After analytically

obtaining the amount ofsulfate that is in the inorganic fraction, the mass ofthe ammonia

added to the sample (me) to fOIm ammonium sulfate is calculated according to Equation

202-1.

Ifthere is more sulfate present that is not associated with ammonia, the ammonia

mass could be ~alculated falsely high. When the higher ammonia mass is subtracted

from the dried inorganic fraction (mr), the total inorganic CPM could be biased low.

As a secondary QC check, AirNova, Inc. has added an additional calculation to its

report. Ifthe dried inorganic sample mass (mr) is 100% ammonium sulfate (NH4)2S04,

,the most ammonium that can be present is 27.3% ofthe sample mass (based on

ammonium's mole fraction). This represents the maximum ammonium that can be in the

dried inorganic sample due to association with sulfate.

IfEquation 202-1 calculates an ammonia mass that is greater than the amount that

is possible due to the inorganic mass (mr) being 100% ammonium sulfate (NH4hS04,

the lower ammonia mass (me) is subtracted during Equation 202-2 to reduce any low bias

to the total inorganic CPM.

AirNova Information Sheet #24 Revision 0

3
3338eval EPA5/wet 202 4

•• <ilI •••

.. ~eeeQ~ .

• : ••••• tIl@ ••

d" •• Cit ••••

... .. .... ............ '. * ••••• !II"

•• " lit •• " • •

• • $: .. 4'# • - . .

AirNova, Inc. Laboratory

EPA Method 202 - Fraction Information and Calculations

4
Client:

AirNova Project #:

Location:

AirNova @ James River - Hopewell, VA

3338 - evaluation

Unit 2

3338eval EPA5/wet 202 5

EPA Method 202 Condensable Particulate Analysis (Mass Data)

Lab Book #: EPA202-2-127

Sample Date: 5/7/10

Date Received: 5/10/10

Back Half Organic Fraction - (volume of MeCl2 for all samples & blanks is constant)

Mass of organic CPM (mo) Vol.(Vic) Aq. Vol.

Run# .(mg} Tare(g) Total(g) Diff(g) :mL) Extracted

1 0.0 * 3.6704 3.6704 0.0000 665 625

2 0.0 * 3.9481 3.9481 0.0000 720 680

3 0.0 * 3.5953 3.5953 0.0000 650 610

Field Blank 0.0 * 3.4563 3.4563 0.0000 400 360

*Gravimetric MDL = < 0.3 mg

" ,.,

...

'..

"

::: AirNova. Inc.

5
Client:

AirNova Project #:

Location:

AirNova @ James River - Hopewsll, VA

3338 - evaluation

Unit 2

3338eval EPA5/wet 202 6

EPA Method 202 Condensable Particulate Analysis (Mass Data)

Lab Book #: EPA202-2-127

Back Half Inorganic Fraction - Aqueous post-extraction

Mass of Inorganic CPM (mi)

NH4+ added (mc)

mi=(mg) llmli Tare(g)

2.7

Total

Vol.

Total(g) Net Diff(g) (mL)

665

Vol.(Vb)** Dried inorganic mass (mr)

(mL) llmli

40

2

3

pick up (mL)= 196

Adjusted Inorganic Vol (Vic)= 469

5.6934 5.6962 0.0028

5.8205 5.8234 0.0029

0.0000 0.0000 0.0000

3.35 0.0000 0.0000 0.0000 5.7 (mr)

4.9 720 40

pick up (mL)= 196

Adjusted Inorganic Vol (Vic)= 524

5.7625 5.7682 0.0057

5.7967 5.7996 0.0029

0.0000 0.0000 0.0000

4.2 0.0000 0.0000 0.0000 8.6 (mr)

7.7 650 40

pick up (mL)= 194

Adjusted Inorganic Vol (Vic)= 456

5.6626 5.6675 0.0049

5.8065 5.8105 0.0040

0.0000 0.0000 0.0000

1.82 0.0000 0.0000 0.0000 8.9 (mr)

Field Blank 5.9884 5.9884 0.0000 400 40 0.0

** Volume taken for sulfate analysis

*Gravimetric MDL = < 0.3 mg 500mL equiv.= NA

The analytical results obtained relate only to the samples included within this report.

This report should not be reproduced except in full, without the written approval of AirNova, Inc.

AirNova, Inc. certifies that the test results contained in this report meet all requirements of NELAC.

6

(post NH4+

aliquot adjusted)
Client:

AirNova Project #:

Location:

Test Date:

Dates Rec'd:

Lab Book #:

3338eval EPA5/wet 202 7

NELAC & NJ Lab Cert. No. 04011

PA Registration # 68-1676

AirNova @ James River - Hopewell, VA

3338 - evaluation

Unit 2

5/7/2010

5/10/2010

EPA8-1-124

Sulfate Laboratory Analysis Summary - EPA Method 202 Ammonia Correction

(EPA Method 5F Section 16.1.3.4)

Standardizations

Ba2+ Solution Standardization against Sulfuric acid

5.0 mL (S04)2- used

0.0100 Molar (S04)2- lot # G30519

15.20 mL Ba2+ solution at equivalence point

Calculated Concentration of Ba2+ solution=

0.0033 Molar = 0.0066 Normal

(S04)2- Control Sample against Ba2+ Standard Solution

4.0 mL (S04)2-

0.0104 M (S04)2- lot # 120409

12.60 ml Ba2+ Solution at equivalent

Calculated Concentration of Ba2+ Standard Solution (Log-3-23)=

0.0033 Molar: 0.0066 Normal = 100 % Recovery Ba2+

Sulfate Sample Analysis K=0.3542

Run# Sample Description Sample Aliquot Titrant (Ba2+ sol'n) Sulfate Conc.= Total 804 Total NH4+

Vol.= V(ic) Titrated 1st 2nd Average C(S04) Mass = Mass=m(c)

(mL) (mL) (mL) (mL) (mL) (mg/ml:.) (mg as 804) (mg as NH4+)

1 665 H2O 10.0 0.45 0.45 0.45 0.0142 9.45 3.35

2 720 H2O 10.0 0.55 0.50 0.53 0.0166 11.94 4.23

4 650 H2O 10.0 0.20 0.30 0.25 0.0079 5.13 1.82

Blank 400 H2O 10.0 < 0.05 < 0.05 < 0.05 < 0.0016 < 0.63 < 0.22

MDL= 0.027 mg as sulfate

The analytical results obtained relate only to the samples included within this report.

This report should not be reproduced except in full, without the written approval of AirNova, Inc.

" .. ,

...

-"

'.

::: AirNova. Inc.

7
8

3338eval EPA5/wet 202 8

.. e " .. 'II lit >I

• liII • lit • <@I •• :e8 ••• iIII~ ••

: ., . "..•••.... . 41. "" ••• "" . " .., . • " 4Il l1li Ii • • .

" .. . . .

AirNova, Inc. Laboratory

Chain-of-custody
i

,..,

'"' ..s

1!J

"3

.€

.§

Po<

i3

-5

o

<Q

[

rrJ

Preservation

ntainer Type Legend

P = polybottle (HDPE)

G= glass w/fluorolid

T = trap V = vial

D = Petri dish

Chain OfCustody Documentation Form

Sample Fractions

(indicate # of each & Container Type)

I --••.,...- _._. "".",- I "'- I Report Results To: ! s

AirNova, Inc. 5845 Clayton Ave,

Pennsauken, NJ 08109

856486-1500

Fax: 856486-9896

www.airnova.com

Fraction Type Legend

W = wash F = front

C = catch B = back

Q =quartz T =fluoropolymer Run

#

....... . " . .•• ., • e • It •••

, . ........H.

.............

". « '" ••• " • 'II II •

., : .

Collection IAnalysis

Method

(include additional

requirements)

Test

Set

tj tJ I I .LJ t=t=tttJ I t=1=tj I t= I I I Ii

~I • , • BReceived By (PrintiSignlDatefTime): 1<0

! !!!!!!! , ! I , ! , ! ! , ! !! !!! I~

tes'

I • [

Relinquis7e,d By (prJl1t1~gnlDat;;:ri~e): r::;~:;? L' C i Relinquished By (PrintiSignlDatefTime): • m ,;/"L"/~~, du<?e:.-''''' ""-Y?'"

Received By (printiSignlDatelT'

Chain ofCustody Revision 1 (Jan. 2010)
3338eval EPA5/wel202 10

.~.e·e~

• l!!i • " ••••

'. II .. II • 11II ""

:,: II lIIl ., • ., " " ...

••••••••••• •• 11II lIIl • ., 11II.'

". III III ".,

••• 11II " " e ... " ••• Cit : •

. . .

AirNova, Inc. Laboratory

Calibration Documents and Analytical Certificates

10
GENERAL1

TISSUQUARTZ is a high purity filter for the sampling and analysis of trace

quant.ities of particulates in ambient to high temperature gas Gtreams. It

is made from pure silica '(quartz micro fibers), under clean manufacturing

rondi tions•

NPLTCATI~:

Stack and aerosol sampling and monitoring.

1>.tomic absorption spectrophotometric analysis (1\-;5).

Flame emission spectrophotometric analysis (FES).

X-ray fluoroescence and spectrographic analysis,

Hay be used at up to 2500 degrees F.

ATh.ll.\HLE TYPES:

TIS$UQUARTZ 250OQAo-UP - approx. 0.016" thick (per TN""?I 441).

TISSUQUARTZ 250OQ.~T-UP - type 250OQAO-UP plus Heat Treatment for

l::eduction of trace organics cHid imparts higher strength.

1>.VAII.ABLE SIZES:

Packaged 8" :x 10" 25 sheets/J::ox

Discs of 37mn; 47nro; 51lml(25 discs per }:)a.x)

other sizes and shapes also available.

MalnicaJ. Test ResuJ.ts of TI~:

Following is compilation of test reSUlts from independent test labs and

EPA and other sources to se~e as guide, but not sF€cificatio,'s, on

TISSUQUARTZ.

Typical reported data on TISSO(>Ji'.RTZ 2500l\l;;o....UP [. 250-')5~

Hicrograms/Sg.Inch

tIH 4 + .22 .±. .07 CR -:: .06 l'i <: .06

S03 .02 + .10 CO <: .01 S';.J -< .12

504 .37 .07 Cu <: .12 V .12 .:!:. ',. N03 20 Pb <: .025 Zn <: .12

Cl- .12 + .03 Hn <: .12 Cc <: .05 - Be < .01 Ho < .17 As < 1 .25

'!'ensiles: 400 gpli pH in 6-7 nU1;:W

TISSUQUARTZ h.as a very high efficiency of OV<2r 99.97""'; 'bas(-d c·:~ the

Utieron D.O.P. aerosol t€:st.

J\ir Flow resista.'1CB by Gurley de:-1So,'l'.et,er- a!:. 100cc/s:j. Inch - 3 secon(.1~; Avg.

Ttl!} iflfor(nahD"'~ ~fld ,j~la pre$~r.led 1$ ~ased on VJ:r,l,]US tes:s Of (\?DC:rl.;O e"~€:;l·::~l(€:. anc i.; CO:"I$ioerlS:O ¥:<:t...'-':12 HO..•.. ~~vt::~. no YlaH~''':)' I$. cr.P(S!·:·$.?~

or Imp~ied fOf ttle. ff!SultS :!J:le obtdlOed :tQ!71 :t-.e ::O!.;-nd~d \,:$1: there':::>L Ct It-.at G"')" :;·_,;:.r. lJS"} '-\'11: no: ir"".~ri.",.)(1 any :,::.:~nt. ThiS ,nfcd'"niah(lf1 a:\d!ol m~~I(!f1~!1

is 1urnished upv:'\ the ~{;njl1tor: a"'.a: :."~ tlE:-SO:l rer~i·./lli'; an::J I.,;;ing i: ·....111 "'.~k= il:5 -.)...."1'. :~$ts to O€lfsfn-i1n8 trj:..! sLIt:.i.t.,.::tr thE-feo! '[If hi:;. PM1t::t.:laf Plj:~;:-I;;t-:

C§~0 t6C3S00!W

PALLFLEX PRODUCTS COMPANV

• F

125 Kennedy D:i..-a, ;:·t1~;"\a ..r.. Cc,nt\(:cHcu1 OG2GO (20.3},926·Tl6t

:'A~solu{e P'>Iji}nna!/ct ,~,-~ ...

11
Certificate No.: 020213-753-080309

Mettler Toledo

Service Business Unit Laboratory

1900 Polaris Parkway

Columbus, OH 43240

1-80D-MEDLER

ISO 9001 : 2000 Registered

Calibration Certificate

Customer

Company:

Address:

City:

Zip/Postal:

Device

Manufacturer:

Serial No.:

Max Capacity:

Model:

AIR NOVA INCORPORATE

5845-A CLAYTON AVENU

PENNSAUKEN

08109

Mettler Toledo

J28261

205 9 152 9

AT250

State/Province:

Asset No.:

DepURoom:

Readability:

NJ

N/A

N/A

0.0001 9 10.00001 9

Procedure Statement: The device referenced in this document has been metrologically tested in accordance

with MEDLER TOLEDO Work Instruction VW0152A. All translations into other

languages are based on the referenced work instruction, which is in English.

This certificate refers to: As Found and As Left

Test Date:

Service Technician:

3-Aug-2009

Carlos Toscano

Next Cal. Due Date: 31-Aug-2010 A

Signature: &vL,/k£'&Vl-O

Reference Weights <. '

Form No.:VF0066A

Soflware Version: 4.0.1.9 12

This is an original document, an electronic copy is retained by MEDLER TOLEDO

16280500A

Traceability ofTest

Equipment:

Weight Set 1

Weight Set No.:

Calibration Due

Class:

All weights used for metrological testing are traceable to national or international

standards. The weights were calibrated and certified by an accredited calibration

Date ofIssue: 20-Aug-2008

----=~--------

NIST Traceability No. MT5061

-..:-:...-_-------

Page 1 of3

© MEDLER TOLEDO
Certificate No.: 020213-753-080309

Measuring Results

METTLER TOLEDO

As Found

Test Weight Position Displayed Value Deviation

C: 1009 Center 0.0000 9 N/A

1: 100 9 LeftFront 0.0001 9 0.0001 9

2: 1009 LeftRear -0.0002 9 -0.0002 9

3: 100 9 RightRear 0.0001 9 0.0001 9

4: 100g RightFront -0.0002 9 -0.0002 9

Eccentric Load Deviation: 0.0002g

Manufacturer

Specifications: 0.0002 9

Manufacturer

Specifications Rounded to

Resolution ofEccentric

Load Deviation: 0.0002

Specifications Met: YES

AsLeft

Displayed Value Deviation

O.OOOOg N/A

0.0001 9 0.0001 9

-0.0002 9 -0.0002 9

0.0001 9 0.0001 9

-0.0002 9 -0.0002 9

0.0002 9

0.00029

0.0002

YES

Sensitivity

As Found

Displayed Value

Without With Deviation

Reference Reference Reference

Weight Weight Weight

199.99999 O.OOOOOg 200.0003 g 0.0004g

Sensitivity Offset: 0.0004 9

ManufacturerSpecifications: N/A

ManufacturerSpecifications

Rounded to Resolution of

Sensitivity Offset: N/A

Specifications Met: N/A

As Left

Displayed Value

Without With Deviation

Reference Reference

Weight Weight

O.OOOOOg 200.0001 9 0.00029

Sensitivity Offset: 0.0002 9

ManufacturerSpecifications: 0.0003 9

ManufacturerSpecifications

Rounded to Resolution of

SensitivityOffset: 0.0003 9

Specifications Met: YES

Form No.:VF0066A

Software Version: 4.0.1.9

This is an original document, an electronic copy is ret~~ed by METTLER TOLEDO

Page 2 of3

© METTLER TOLEDO
Certificate No.: 020213-753-080309

n"llOI~ 11'&'11'\6 - Differential Method

Test Weight 50.00000 9

As Found

Displayed Value

Preload Deviation *

Weight Preload Test Weight

1 Og 0.0000 9 50.0001 9 0.00007 9

2 50 9 50.0001 9 100.0001 9 0.00004 9

3 100 9 100.0002 9 150.0002 9 0.00001 9

4 150 9 150.0003 9 200.0003 9 -0.00002 9

Linearity Deviation: 0.00007 9

ManufacturerSpecifications: 0.0002 9

ManufacturerSpecifications

Rounded to Resolution of

Linearity Deviation: 0.00020 9

Specifications Met: YES

METTLER TOLED

As Left

Displayed Value

Deviation *

Preload Test Weight

0.0000 9 50.0000 9 0.00000 9

50.0000 9 100.0000 9 0.00000 9

100.0000 9 150.0000 9 0.00000 9

150.0001 9 200.0001 9 0.00000 9

Linearity Deviation: 0.00000 9

ManufacturerSpecifications: 0.0002 9

ManufacturerSpecifications

Rounded to Resolution of

Linearity Deviation: 0.00020 9

Specifications Met: YES

16280500A

* This Linearity Deviation is zero point offset and sensitivity error compensated.

Remarks

None.

Form No.:VF0066A

Software Version:4.0.1.9 14

This is an original document, an electronic copy is retamed by METTLER TOLEDO

Page 30f3

© METTLER TOLEDO
-------- ---

3338eval EPA5/wet 202 15

15 --------.----------------
Since 1903

3338eval EPA5/wet 202 16

ort

Traceable to NIST

ISO 9001 Registered

The Instrument described below has been examined and tested in H-B Instrument Company's Calibration Laboratory using controlled constant temperature

equipment and NIST Traceable Reference Thermometers, in accordance with H-B's ISO 9001 Calibration procedures, and NBS Monograph 174, ASTM Method

E77, NIST Special Publication 819, and the International Temperature Scale ITS-90. Calibration is traceable to NIST and is in compliance with MIL-STD 45662A

and ANSII ASOC 09002-1994. For a discussion of accuracy obtainable with such thermometers, see NIST SP 250-23.

14-Sep-04

VWR International

1451 North Raddant Road

Batavia IL 60510

Tel: Fax:

Reference No: 6447997

Report No.

Serial No

Part No

Distributor

Manufacturer

Item

Range

307695

3V0393

61099-139

VWR International

H-B Instrument Company/MW

Thermometer, Partial Immersion

95/155°C, 0.2°Div., 108mm Imm.

Ambient Air Temperature:

N.I.S.T.

Standard

O.OOO°C

100.000° C

110.000 ° C

130.000°C

150.000° C

Instrument

Tested

0.060°C

99.940 ° C

109.980°C

129.920 ° C

149.960 ° C

Correction

(ITS-90)*

-0.060

0.060

0.020

0.080

0.040

N.I.S.T. N.I.S.T. Test Emer. Stem**

Serial No. Test No. Liquid Temperature

710015 53394 Ice °T

710015 53394 Oil 55.0° C

710015 53394 Oil 55.0°C

710015 53394 Oil 45.0°C

710015 53394 Oil 40.0° C

Relative Humidity: 31 %

T - Total Immersion

This Report of Test may not be reproduced

without the express written permission

of H-B Instrument Company•

Design Copyright ©HBI 2004

H-B Instrument Company 102 West Seventh Avenue, Trappe, PA 19426-0770 USA

Telephone 1-600-4-TEST-LAB Fax (610) 489-9100 JB e-mail Address: cal@hbinstrumentcom JB Website Address: www.hbinslrumentcom

Fonn 0-592 Rev.6

• Observed instrument readings should be increased by positive numbers or reduced by negative numbers indicated by a minus (-) sign. •• Emergent Stem Temperature relates to PARTIAL IMMERSION thermometers ONLY (see reverse).

The Platinum Resistance Thermometer (PRT) serial number above, was calibrated with an AC Bridge at a frequency of 90Hz and a constant current of 1.0 rnA.

This procedure is based on the technical information contained In NIST Technical Note 1265. Comparison points used to calibrate the thermometer range from

a temperature of -196.000°C to 420.000°C. The calibration uncertainty of the AC Bridge and PRT is estimated not to exceed O.026°C.

The Instrument is in good working order and is suitable for calibration. The capillary of the thermometer has been examined under magnification and no

discernable capillary irregularities were noted. Strains in the glass revealed by examination under a polarized lens, if any, were judged to be minimal and of no'

detriment to the function of the instrument

As a general gUideline, certification/calibration of instruments once yearly is considered acceptable in most manUfacturing and laboratory practices,

but each 0 .• tion must set its own policies.

4.
3338eval EPA5/wet 202 17

< 0.3

Product No. 5693

Lot No. G30519

Release Date 07/28/2008

1 max.

0.3 max.

0.5 max.

<0.5 =~~="~4~"·~~~·~'="~~"·-····~--·--_.__._~-~_.=,,~~~~_.------.--._._..-.

<0.2

Sulfuric Acid, O.02N Volumetric

Solution

'BAKER ANALYZED'@

.""._-.~~~----.--~~ " ,,-<~~~._~.~~~--_._.~_._.------.-~..-----_i ~~ra~~~,Research~rM~~.~~~~~_e • --------=1

USE BEFORE July 31, 2010

Country of Origin: USA

For questions on this Certificate of Analysis please contact Technical Services at 1-800-582-2537 or 908-859-2151

Mallinckrodt Baker, Inc.• 222 Red School Lane' Phillipsburg, NJ 08865' Phone: 908.859.2151 • Fax: 908.859.6905

17
3338eval EPA5/wel202 18

ertificate of Analysis

NSI Solutions, Inc. * 7212ACC Blvd. * Raleigh, NC 27617 * 1-800-234-7837

Mixture Name: Sulfate (S04), 1000 ppm

Part Number: IS-015-100, 500

Lot Number: 120409

EXP Date: 12/2011

Solvent: Reagent Water

Compound

Number

W-1387-04

ANALYTE

PURITY

(%)

99.8

CERTIFIED

CONCENTRATION

(mg/L)

1000

PREPARATION: Reported concentration value has been corrected for purity using purity values

obtained by NSI analysts. Concentration is certified by IC analysis with recovery of 103.6%.

Microbalances calibrated with NIST traceable weights to 0.0001 g and/or ASTM Class A

volumetric glassware or calibrated equivalent labware.

STORAGE & HANDLING: After opening, store at 5°C. Allow to equilibrate to room temperature before use.

Instructions for Use: Sample provided in a whole volume format. No dilution is required.

18
3338eval EPA5!wet 202 19

F . (847) 948-1078· Web: alitechWEB.com

lid-Phase Hxtraction Products

Alltech Associates, Inc.• 2051 Waukegan Rd' Deerfield, IL 60015· Tel: (847) 948-8600· ax.

Qualit\[Certificate

Packing Type:

Lot No.:

IC-H

0701000136

Polymer Type:

Functional Group:

Counter Ion:

Pm"tical Size Range:

Molecular Exclusion Limit:

Exchange Capacity:

Styrene Divinylbenzel1e

Sulfonic Acid

Hydrogen

75 - 150 ~I

1000 Daltons

2.0meq/mL

Counter Ion Selectivity

Relative elution strength for counter ions on SCX:

General Procedure for Ion Exchange Extraction:

1. Condition Pacl<ing bed with 5 - 10 mL of deionized water or a low ionic strength buffer

(e.g. 1 mM to 5 mM). Don't let the packing dry!

2. Apply the sample.

3. Wash the bed with a weak elution solvent (e.g. deionized water or low ionic strength buffer).

4. Wash the bed with a weak elution solvent (e.g. higher ionic strength bUffer or buffer at a pH that

decreases sample ionization).

NOTE: Compounds (both ionized and neutral forms) must be soluble in the elution solvent. The

polymeric backbone of the resin has the potential for non-polar (especially aromatic) secondary

interactions with the sample, reducing recovery. These interactions can be overcome with the addition

of an organic modifier, liI<e methanol, to the elution solvent.

Lot to lot variation in resin color is cosmetic only and does not affect resin performance.

19

Approved- .£~ SPE QC Technician - Scott Irwin

1118/2007
Data Sheet

30264U

3338eval EPAS/wet 202 20

IC-H and IC-H Plus Devices

Alltech Associates, Inc.• 2051 Waukegan Road· Deerfield, IL 60015-1899 • Telephone: (847) 948-8600 • Fax: (847) 948-1078

Introduction

Maxi-Clean' and Extract-Clean' IC Devices are solid-phase extraction

devices used to eliminate matrix interferences from samples prior to

analyses by ion chromatography. Each device consists of either O.5mL

or 1.5mL of polystyrene-based packing sandwiched between

polyethylene frits within an injection-molded medical-grade

polypropylene housing (Figure 1). Samples and wash solvents are

passed through the packing using a luer hub syringe (for Maxi-Cleans')

or a vacuum manifold (for Extract-Cleans'). As sample comes in

contact with the packing, specific chemical interactions take place

which selectively retain certain components of the matrix in the device

while the remaining components pass through the device outlet. The

chemical characteristics of the packing dictate which sample

components are retained. Seven chemistries are currently available.

Successful application of IC devices requires:

1) proper conditioning of the device prior to sample application,

2) application of the sample at a rate slow enough to allow the

chemical interaction to take place while the sample is in the

device, and

3) control of sample size to keep within the device's capacity.

The following information provides general recommendations for

the use of IC-H devices. This procedure may be modified to

accommodate samples with different characteristics.

General Information

Maxi-Clean" and Extract-Clean" IC-H provide a reliable method for the

adjustment of pH of basic samples prior to the analysis of anions by ion

chromatography. They may also be useful for removing cations from

samples prior to the analysis of anions. IC-H devices contain either

0.5mL or 1.5mL of sulfonic acid cation exchange resin in the H' form.

The hydronium contained on the packing reacts with hydroxide from

the sample to form water thereby reducing pH. In this process, cations

from the sample are taken up by the resin to replace the hydronium

consumed in the neutralization reaction. The net result is removal of

hydroxide (and an equivalent amount of sample cations) from the

matrix. Polyvalent cations will be preferentially retained over

monovalent cations in acidic samples providing a mechanism for

removal of polyvalent cations.

The recovery of weakly ionized anions such as nitrite and phosphate

could be poor after sample pretreatment with IC-H. The loss of these

anions may take place through a number of different mechanisms,

including evolution of nitrous oxide, oxidation of nitrite to nitrate,

adsorption in the resin or a combination of effects. A study of the

recovery ofions of interest in each sample matrix should be determined

before quantitative results are obtained.

For more information on the use of Maxi-Clean" IC cartridges and the

recovery obtained with each please see:

R. Saari-Nordhaus, J.M. Anderson, Jr. and I.K. Anderson, Am. Lab.,

August (1990) 18.

LK. Anderson, R. Saari-Nordhaus and J.M. Anderson, Jr., J. of

Chromatography, 546 (1991) 61-71.

Figure 1

Flowrate

The devices have a number of flow-dependent parameters that may

affect results. In general, high flowrates, particularly in the sample

loading step, will decrease the performance while low flowrates will

improve the extraction process. Low flowrates allow the sample to

diffuse into the packing thus increasing capacity and improving the

efficiency. The recommended flowrate for sample loading is lmLI

minute or less.

Sample Mass

Each device contains either 0.8 or 2.0 milliequivalents of H' (for the

0.5mL or 1.5mL device, respectively), which under ideal conditions will

remove an equal amount of hydroxide or polyvalent cations from the

sample. In practice, this maximum capacity may not be realized. The

nature of the sample (concentration, ionic strength, solvent) and the

rate at which the sample is loaded into the device will affect the

capacity. Where possible, adjust sample size to use 50% of less of the

device's absolute capacity. Larger amounts of hydroxide or polyvalent

cations may be removed by using two or more Maxi-Clean" cartridges in

series. If the amount of hydroxide or polyvalent cations in the sample

is unknown, a test extraction should be performed to determine the

correct sample size.

Page 1 30264U

© Copyright 2000 AI/tech Associates, Inc. Contact your AI/tech office or distributor for current or local prices.

20
Certificate ofAnalysis

3338eval EPA5/wet 202 21

Arlington, TX 76012

Pocomoke City, MD 21851

Batesville, IN 47006

http://www.riccachemical.com

1-888-GO-RICCA

customerservice@riccachemical.com

Phenolphthalein Indicator, 0.5% (wlv) in 50% (v/v) Alcohol, Neutralized

Lot Number: 2911023 Product Number: 5600 Expiration Date: OCT 2011 Manufacture Date:11/2/2009

This product has a slight color because it has been purposely neutralized to eliminate any acidic blank.

Contains:

IName CAS# Grade

Ethyl Alcohol (Ethanol), CH3CH20H

Methanol (Methyl Alcohol), CH30H

Phenolphthalein, C20H1404

Water, Deionized, H20

64-17-5

67-56-1

77-09-8

7732-18-5

USP

NF

ACS

ACS, AS1M D 1193 (Type I), EP, USP

/fest Name

Appearance

Suitability for Use

Assay Method

Clarity, Color, Odor

Characteristic Check

Specification

Clear, very light pink,

alcohol odor

Colorless (pH 8.0) - Pink

(pH 10.0)

Result

Passed Test

Passed Test

~pecification Reference Method Number

Phenolphthalein Indicator Solution (5 gIL)

Phenolphthalein Indicator Solution

Phenolphthalein Indicator Solution (5 gIL)

Phenolphthalein Indicator Solution (5 gIL)

Phenolphthalein Indicator Solution (5 gIL)

Phenolphthalein Indicator Solution (5.0 gIL)

Phenolphthalein Indicator

Phenolphthalein Indicator Solution, Alcoholic

Phenolphthalein Indicator Solution

Phenolphthalein Indicator Solution

Phenolphthalein solution, alcoholic, pH 8.3

indicator

AS1M

AS1M

AS1M

AS1M

AS1M

AS1M

APHA (14th Ed)

APHA

APHA (14th Ed)

APHA

APHA

D287M

D 3590 A

D515A

D 1067B

D 1067C

D2187E

407B

5570C

311 B

4500-CI- B

2320B

7500-RaB

2310B

APHA

APHA

Phenolphthalein Indicator Solution

Phenolphthalein indicatorsolution, alcoholic,

pH 8.3 indicator

Phenolphthalein Indicator Solution (5.0 gIL) AS1M D 2187 F

Phenolphthalein Indicator Solution EPA 425.1

Phenolphthalein Indicator Solution (5.0 gIL) AS1M D 2187 G

Phenolphthalein Indicator Solution (5 gIL) AS1M D 2187 H

Phenolphthalein Indicator Solution (5.0 gIL) AS1M D 4548

Phenolphthalein Indicator Solution (5 gIL) EPA 365.1

Phenolphthalein Indicator Solution (5.0 gIL) AS1M D 2187 I

Phenolphthalein Indicator Solution AS1M D 1425

Phenolphthalein Indication Solution (5.0 gIL) AS1M D 2330

Phenolphthalein Indicator Solution (5.0 gIL) AS1M D 2187 J

Phenolphthalein Indicator Solution (5.0 gIL) AS1M D 2187 K

Volumetric glassware complies with Class A tolerance requirements ofASTM E 288 and NIST Circular 434; it is calibrated before first use

and recalibrated regularly in accordance with ASTM E 542 and NIST Procedure NBSIR 74-461. Balances are calibrated regularly with

weights certified traceable to the NIST national mass standard. Thermometers and temperature probes are calibrated before first use and

recalibrated regularly with a thermometer traceable to NIST standards. All products are prepared according to master documents that

assure manufacture according to validated methods. Batch records document raw material traceability and production and testing history

for each lot manufactured.

Version: 1

21
ShelfLife (unopened container):

5600-32

5600-1

5600-16

Recommended Storage: 15°C - 30°C (59°F - 86°F)

~:';:1L6- (y-cUfJJ~/T'---') c;7J<- (

LaNelle Ohlhausen

Quality Assurance

24 months

24 months

24 months

3338eval EPAS/wet 202 22

This Certificate of Analysis is designed to comply with ISO Guide 31 "Reference Materials •• Contents of Certificates and Labels."

To determine manufacturing site using lot number, visitwww.riccachemical.comfAboulUs/lol.pdf.

Version: 1

R!{(A

(O-r lCJr!fj?'--->

2;f~

22
w

w

W

0:>

<D

<

92..

m

:;:

m.

1'0

a

1'0

1'0

W

m

z

o

.,

o

;:0

m

-0

o
Air Nova

5845 Clayton Avenue

Pennsauken, NJ 08109

Project 10: 3338

Antimony, Arsenic, Beryllium, Cadmium,

Chromium, Cobalt, Lead, Manganese,

Nickel, Selenium and Mercury

EPA Method 29 Analysis

Analytical Report

14503

Element One, Inc.

5022-C Wrightsville Av., Wilmington, NC 28403

910-793-0128 FAX: 910-792-6853 e1Iab@e1Iab.com

24
The following data for Analytical Report 14503

has been reviewed for completeness, accuracy,

adherence to method protocol,

and compliance with quality assurance guidelines.

Review by:

0c{j'vL L~L Dap~ne Woodman, Chemist

May 28,2010

Report Reviewed and Finalized By:

'/JA."L~ yt'0<Y'1" '~

Ken S"'mith, Laboratory Director

May 28,2010

elementOne

14503 Air Nova M29 Report

Page 2 of 27

25
SUMMARY OF RESULTS

elementOne

14503 Air Nova M29 Report

Page 3 of 27

26
Summary of Analysis

Summary of Method 29 Mercury Analysis

H20 2 Empty

Average Total Front half IHN03 Impinger KMn04 HCI

Run Number Catch, IJg IJg I-Ig I-Ig I-Ig I-Ig ~---------------- --------------- -------------

Run 1 #1 < 0.5 < 0.1 < 0.5 < 0.2 < 0.5 <0.4

#2 < 0.1 < 0.5 < 0.2 < 0.5 <0.4

Run2 #1 < 0.5 < 0.1 < 0.5 < 0.2 < 0.5 <0.4

#2 < 0.1 < 0.5 < 0.2 < 0.5 <0.4

Run3 #1 < 0.5 < 0.1 < 0.5 < 0.2 < 0.5 <0.4

#2 < 0.1 < 0.5 < 0.2 < 0.5 <0.4

Blank #1 < 0.5 < 0.1 < 0.5 < 0.2 < 0.5 <0.4

#2 < 0.1 < 0.5 < 0.2 < 0.5 <0.4

elementOne

14503 Air Nova M29 Report

Page 4 of 27

27
Summary of Analysis

Front Half· Summary of Method 29 Metals Analysis

Run 1 Run 2 Run 2 Run 3 Blank

14503-1 FH 14503-2 FH 14503-2 FH duo 14503-3 FH 14503-4 FH

Element TotallJg TotallJg TotallJg TotallJg TotallJg -----.----------- --------------- ------------.-- --------------- --------------- --.-----.------

Antimony 0.254 0.404 0.412 0.509 < 0.1

Arsenic 1.04 1.07 1.12 1.29 < 0.1

Beryllium 0.043 0.041 0.039 0.057 < 0.025

Cadmium < 0.1 0.156 0.156 0.332 < 0.1

Chromium 3.48 4.23 4.32 3.25 0.923

Cobalt 0.317 0.327 0.338 0.422 < 0.1

Lead 1.57 1.90 1.93 9.41 0.307

Manganese 1.24 1.39 1.42 1.67 0.655

Nickel 1.94 3.11 3.20 3.77 0.514

Selenium 0.318 0.386 0.389 0.495 < 0.1

Back Half· Summary of Method 29 Metals Analysis

Run 1 Run 2 Run 2 Run 3 Blank

14503-1 BH 14503-2 BH 14503-2 BH duo 14503-3 BH 14503-4 BH

Element TotallJg TotallJg TotallJg TotallJg Total IJg ----------------- --------------- --------------- --------------- --------------- ---------------

Antimony < 0.1 < 0.1 < 0.1 < 0.1 < 0.1

Arsenic 0.923 1.04 0.976 0.939 < 0.1

Beryllium < 0.025 < 0.025 < 0.025 < 0.025 < 0.025

Cadmium < 0.1 < 0.1 < 0.1 < 0.1 < 0.1

Chromium 0.840 0.320 0.305 1.24 0.283

Cobalt < 0.1 < 0.1 < 0.1 < 0.1 < 0.1

Lead 0.237 0.321 0.308 0.406 0.681

Manganese 19.0 0.624 0.619 1.51 0.955

Nickel 0.479 0.289 0.283 1.57 0.358

Selenium < 0.1 < 0.1 < 0.1 < 0.1 < 0.1

elementOne

14503 Air Nova M29 Report

Pagi4~ of 27
ANALYTICAL NARRATIVE

elementOne

14503 Air Nova M29 Report

Page 6 of 27

29
Element One Analytical Narrative

Client: Air Nova Element One #: 14503

Client 10: 3338 Analyst: ESS & KMS

Method: M29 Dates Received: 05/14/10

Analytes: Sb, As, Be, Cd, Cr, Co, Pb, Mn, Ni, Se & Dates Analyzed: 05/19-20/10 HQ

Summary of Analysis

The Method 29 samples were digested, prepared, and analyzed according to

Method 29 protocol. Samples were analyzed for mercury on a PerkinElmer

FIMS-100 CVAA mercury analyzer. Samples were analyzed for metals using a

PerkinElmer ELAN 6100 ICP-MS.

Detection Limits

The FIMS-100 CVAA instrument reporting limit for mercury was 0.004 IJg per

aliquot analyzed. The ICP-MS instrument reporting limits were 0.25IJg/L for

beryllium and 1.0IJg/L for the other metals.

Analysis QAlQC

Duplicate analyses relative percent difference (RPD), spike sample recovery and

second source calibration verification data are summarized in the Quality Control

Section. The selenium spike recovery for Run 3 was outside of the ±25%

laboratory guidelines with 218%. The sample was analyzed at a five-fold dilution

resulting in a spike recovery of 138% indicating matrix interference. The sample

was non-detect therefore this should have no significant impact on the results.

All other QNQC data was within the criteria of the method.

Additional Comments

The reported results have not been corrected for any blank values or spike

recovery values. There were noticeable amounts of manganese in the back half

fraction of Run 3. The archived portion of the back half fraction of Run 3 was

analyzed and found to have equivalent results for manganese.

elementOne

14503 Air Nova M29 Report

Page 7 of 27

30
QUALITY CONTROL SUMMARY

elementOne

14503 Air Nova M29 Report

Page 8 of 27

31
Summary of Quality Control Data

Mercury Duplicate Analysis RPD

(Method 29 QC limits: < %1afor RPD)

Run Number Front half H20 2/HN03 Empty Imp KMn04 HCI ---------------------.--- ------------- ------------- ------------- ------------- -------------

Run 1 NA NA NA NA NA

Run 2 NA NA NA NA NA

Run 3 NA NA NA NA NA

Blank NA NA NA NA NA

Run Number

Run 3

Mercury Spike Recoveries

(Method 29 QC limits: ±25% for Spike Recoveries)

Front half H202/HN04 Empty Imp KMn04 HCI

----- ------------- ------------ ------_..._--- -----------

#1 101% 99% 100% 93% 94%

#2 102% 102% 101% 94% 94%

elementOne

14503 Air Nova M29 Report

Page 9 of 27

32
Summary of Quality Control Data

Metals Duplicate Analysis RPD

(Method 29 QC limits: < 20% for RPD)

Run 2 Run 2

Front Half Back Half

14503-2 FH 14503-2 BH

Element RPD RPD ------------------ ----------------- -----------------

Antimony 1.8% NA

Arsenic 4.4% 6.3%

Beryllium 4.7% NA

Cadmium 0.2% NA

Chromium 2.2% 5.0%

Cobalt 3.3% NA

Lead 1.4% 4.3%

Manganese 2.0% 0.9%

Nickel 2.8% 2.2%

Selenium 0.9% NA

Metals Spike Recoveries

(Method 29 QC limits: ±25% for Spike Recoveries)

Element

Antimony

Arsenic

Beryllium

Cadmium

Chromium

Cobalt

Lead

Manganese

Nickel

Selenium

Run 3

Front Half

14503-3 FH

Recovery

87%

86%

82%

90%

101%

98%

95%

104%

95%

77%

*See Analytical Narrative, page 7.

elemenlOne

14503 Air Nova M29 Report

Pag~fO of 27

Run 3

Back Half

14503-3 BH

Recovery

96%

117%

88%

89%

98%

98%

100%

99%

99%

*218%
Summary of Quality Control Data

Second Source Calibration Check Recoveries

(Method 29 QC limits: ±10% for Second Source Continuing Check Standard*)

Element .25 ppb 1 ppb 50 ppb 100 ppb* 250 ppb ----------------- ----------------- ----------------- ----------------- ----------------- -----------------

Antimony 105% 102% 100% 98%

Arsenic 108% 102% 104% 100%

Beryllium 105% 104% 99% 98% 97%

Cadmium 109% 99% 102% 99%

Chromium 84% 97% 102% 100%

Cobalt 109% 100% 102% 100%

Lead 112% 106% 106% 99%

Manganese 110% 101% 103% 101%

Nickel 107% 100% 104% 100%

Selenium 99% 102% 103% 99%

elemenlOne

14503 Air Nova M29 Report

Page?41 of 27
SAMPLE CUSTODY

elementOne

14503 Air Nova M29 Report

Page 12 of 27

35
, . .- . ;';':;;;;::':: Air-Nova. Inc. ... ........ ':., D. ':: ; iii' 5845 Clayton Avenue. Pennsauken, New .Jersey 08109 fd#Ii;.!'" '1715 (856) 486-1500 • FAX 486-9896 • www.aimova.com

~,rjJOI!£\ pr"JeL't '3328 EV4-/lltt+,'{H'1 ~t xci)

I Chain of Custody/Analysis Request Form

Requestor's Name: J~~tJl-( Shipped for analysis to:

Date of Sample Shipment: 5~/'6-JO cle e. t- Onc=

Number of Packages: r 0 I l-U- .... L'J

TotaINumberofltemsShipped:'1l1 1/1J - 7-75 -01<::-0

(in all packages) I

Item

#

Sample # Item Description (including matrix) J

r

Analysis

Requested

Comments

7 ,3

If} 7- 'f ..... - 9 \

II J

12 ~/allll:: \/ J

03"

I'J "2.. ' I 5"A

\ J

" n I f

(, I' I f

elementOne

14503 Air Nova M29 Report

Pa9jJ3 of 27
Paula Smith

From: jackson@airnova.com

Sent: Friday, May 14,20108:40 AM

To: Paula Smith

Subject: AirNova Project 3338 Evaluation EPA29 with Hg

Page 1 of 1

These Unit 2 samples were taken on 5-7-2010. It was not included on the cae. Analyze front and back separate.

Joe

AirNova, Inc.

5845 Clayton Avenue

Pennsauken, NJ 08109

856-486-1500

Phone: 856-486-1500 Fax: 856-486-9896

www.airnova.com

5/14/2010

elementOne

14503 Air Nova M29 Report

Pag~14 of 27
ANALYTICAL DATA

elementOne

14503 Air Nova M29 Report

Page 15 of 27

38
Analytical Calculations

MetalsElement Results (1-19) =ICP Results (1-I9/L)*Dilution*Final Volume (L)

WhereICP Results= Raw sample concentration (ppb)--ICP-Data Sheet

Dilution= Diluted Volume--ICP-MS Run Sheet

Aliquot

Final Volume=FH=Final Volume (FV)--Sample Submission

BH=Received Volume (BV).*Final Volume (FV)--Sample Submission

Aliquot (Used)

Combined Results=FH+BH

MercuryMercury Results (1-19) =CVAA Results (1J9) *Final Volume (ml)

Aliquot (ml)

WhereCVAA Results= Raw sample reading (I-Ig)--Hg-Data Sheet

Aliquot= Sample Aliquot (Alq.)--Hg-Data Sheet

Final Volume=Final Volume (FV)*--Sample Submission

* With the exception of the BH fraction where-

=Received Volume (BV)--Sample Submission

elemenfOne

14503 Air Nova M29 Report

Page 16 of 27

39
Analytical Calculations

Spike RecoverySpike (%) =(Spiked Result (Mg/l) - Sample Result (Mg/l)) X100

Spike Amount (lJg/l)

WhereSpike Result = Raw sample concentration (ppb)--ICP-Data Sheet

Sample Result = Raw sample concentration (ppb)--ICP-Data Sheet

Spike Amount--ICP-MS Spike Table

Duplicate Analysis RPDRPD (%) = (Duplicate Result (Mg/l) - Sample Result (Jjg/l)) X100

Average (lJg/l)

WhereSample Result and Duplicate Results=Raw sample concentration (ppb)--ICP-Data

Sheet

Average=(Duplicate + Sample Results)

2

elemenlOne

14503 Air Nova M29 Report

Pag~q7 of 27
elementOne AIR TESTING SAMPLE SUBMISSION FORM Lab ID 14503

I

Front & Back Separate Analysis I Analysis Due Date 05.24.10

. . ONOC/Report Due Date 05.26.10

IClient Air Nova I I Date Rec 05.14.10

I ProJect No 3338 ----1 I Time Rec 0930

i Project 10 I Rec by LLB

Reagent !3lafl~

HN03 Lot: CR:A"5:3

Volume Marked Y /

Sam Ie Identification

~~;~~~~:~~ ---3: 4

U2:M29-R2 OlJplicate -_ ..- ••... i •. '

3 ~~:~;~:~~5 ik: _~J _§..amples 1-4 Analyses Requested

r~'~

Lab 10 I Fraction

4 , C-? FH Acetone Blank

;--------- C-8A FH -- 0.1N HN03

C-8A A 0.1N HN03

-_.

C-8B B 01 H2O 1----

C-9 BH 5% HNO,J10% H.02

, C-10 B 4% KMnO./10%H250.j

i C-11 C 8N HCI DI H2O

i f C-12 FH Filter ---------

Runs / I Fil/ Ace (FH)

pH<2.0 YIN

Lab 10 FillD BV ml

I~.D I 35 ~~,,+-'--;-;o~r::-t---+:=-:;o::--~~::='~--+-+-'--=='-+--'-+

.--=._.1-.,---'---'"..,,'-""-"--'--"-

M-29 Reagent Blank

Lab Communications

53 Page 1 of 1

5/14/2~:43 PM

5S by

Labeled 8y~1 '\~\ 0

FH Prep By/DateS -I Dt:P A Prep By/DateS'- 1'8-1 0 f!jS

BH Prep By/DateS=1 £dtlI2P" B Prep By/Date S-I~' 0 6~ BH/FH Prep By/Date$-I'1-\ Ot::-l; C Prep By/Date 'S -l (0 ess

PM Prep By/Date 10 Verification By / DateM 5 -1t:Yf0

elementOne

14503 Air N,p.ya M29 Report

Page 18 of 27
elementOne Method 29 Microwave Worksheet

'tI'/~I~S~1

1l/5()L--::....{\~

Lab 10 # e 14>b-;·~,... tJ.

Client:

Date Digested: Initials: ---!t'>uV.!-__ Worksheet Prepared by: _\)u.V!!-- _

Element One, Inc. Form 104 - ReVISion 1.0

Auto Sample Lab Sample # of filters Spike Prep Volume Weight In Units

Sample 10 Weight (g) digested (ml) Micro I

Loc. Weight Out

Micro

J Lt<fI.. ILllJ~' L...,I LJNO~

1 LF. R 1Ll<02

") LIZ IQS03 It.l /1-/,-/1,\- I IL,,/IAJOJ1,.,1 J.ll

5 -J. "' It> -s

1 -4

-s

q -b

lD Iq~2-\

II .7.

Jl --;

/'3> }&/5DS-1

ILl -:l

/5 -> I~ -q ,I,-

,

1-1-\..\0., \o-\-.t\ \'O~O50

1/r ·/at.:#= 51D1,O'1~

..

elementOne

14503 Air Npva M29 Report

Pag&t9 of 27
Sample/Batch Report

User Name: icp

Computer Name: D8D4DWD1

Sample File: C:\elandatajcp\S,ample\x4.sam

Report DatelTime: Thursday, May 20,201011 :26:11

AfS Loe. Batch 10 Sample 10 Description Sample Type Init. Quant. Prep. Vol. AiiquotVoL Diluted Vol. Soiids Ratio

5 QC Std2 Sample

14 14503·1FH Sample

15 14503·2FH Sample

16 s 14503·2FH Dupiicate of 3

17 14503·3FH Sample

18 d 14503·3FH Spike· 1 of 5

19 14503-4FH Sample

20 LRB Sample

21 s LRB Spike -1 of 8

22 14503·1BH Sample

23 14503-2BH Sample

24 d 14503·2BH Duplicate of 11

25 14503·3BH Sample

26 s 14503·3BH Spike - 1 of 13

27 14503-4BH Sample

28 Irb g Sample

29 s Irb 9 Spike· 1 of 16

30 14502-1 9 Sample

31 14502-2 9 Sample

32 d 14502-2 9 Dupiicate of 19

33 14502·3 Ig Sample

34 s 14502-3 Ig Spike - 1 of 21

35 x2 14503-3BH Sample

36 x2s 14503·3BH Spike - 1 of 23

37 x20 14502-1 Eng Sample

38 x20 14502-2 Eng Sample

39 x20d 14502-2 Eng Dupiicate of 26

40 x50 14502-3 Eng Sample

41 x50s 14502-3 Eng Spike· 1 of 28

42 x5 14503-3BH Sample

43 x5s 14503·3BH Spike - 1 of 30

Page 1

elementOne

14503 Air Nova M29 Report

Page420 of 27
Dataset Report

User Name: icp

Computer Name: D8D4DWD1

Dataset File Path: C:\elandatajcp\DataSet\051910-3\

Report DatelTime: Thursday, May 20, 2010 11 :25:57

Autosampler Position: 3

Time

17:39:28 Wed 19-May-10

17:42:35 Wed 19-May-10

17:45:44 Wed 19-May-10

17:48:53 Wed 19-May-10

17:52:01 Wed 19-May-10

17:55:10 Wed 19-May-10

17:58:18 Wed 19-May-10

18:01:26 Wed 19-May-10

18:04:35 Wed 19-May-10

18:07:43 Wed 19-May-10

18:10:52 Wed 19oMay-10

18:14:01 Wed 19-May-10

18:17:11 Wed 19-May-10

18:20:22 Wed 19-May-10

18:23:32 Wed 19-May-10

18:26:41 Wed 19-May-10

18:29:49 Wed 19-May-10

18:32:56 Wed 19oMay-10

18:36:04 Wed 19-May-10

18:39:12 Wed 19-May-10

18:42:20 Wed 19-May-10

18:45:28 Wed 19-May-10

18:48:37 Wed 19-May-10

18:51:47 Wed 19-May-10

18:54:55 Wed 19-May-10

18:58:03 Wed 19-May-l0

19:01:12 Wed 19-May-10

19:04:22 Wed 19-May-10

19:07:32 Wed 19-May-10

19:10:42 Wed 19'May-10

19:13:50 Wed 19-May-l0

19:16:58 Wed 19-May-10

19:20:06 Wed 19-May-10

19:23:14 Wed 19-May-10

19:26:23 Wed 19-May-10

19:29:31 Wed 19-May-10

19:32:39 Wed 19-May-10

19:35:47 Wed 19-May-10

19:38:56 Wed 19-May-10

19:42:05 Wed 19-May-10

19:45:14 Wed 19-May-10

19:48:22 Wed 19-May-l0

08:23:38 Thu 20-May-l0

Sample ID

Blank

Standard 1

Standard 2

Standard 3

QCStd 1

QC Std2

QCStd3

QCStd4

QC Std 5

QC Std 6

QC Std7

QC Std 8

QC Std 9

QC Std 10

QC Std2

14503-1FH

14503-2FH

14503-2FH

14503-3FH

14503-3FH

14503-4FH

LRB

LRB

14503·1BH

QC Sid 1

QC Std 4

14503-2BH

14503-2BH

14503-3BH

14503-3BH

14503-4BH

Irb

Irb

14502-1

14502-2

14502-2

QC Sid 1

QCStd4

14502-3

14502-3

QC Sid 1

QCStd 4

14503-3BH

The Dataset

Balch ID Read Type Description Inil. Quant Prep. Vol. Aliquot. Vol. Diluted V

Blank

Standard #1

Standard #2

Standard #3

QCStd#1

QC Std#2

QC Std#3

QCSld#4

QCStd#5

QCStd#6

QC Std#7

QCStd#8

QC Std#9

QC Sid #10

Sample

Sample

Sample

s Duplicate of 17

Sample

d Spike - 1 of 19

Sample

Sample

s Spike -1 of22

Sample

QC Sid #1

QC Sid #4

Sample

d Duplicate of 27

Sample

s Spike -1 of 29

Sample

Sample ,g

Spike· 1 of 32 ,g

Sample Ig

Sample _ Ig

d Duplicate of 35 Eng

QC Std#1

QCStd#4

Sample Eng

Spike - 1 of 39 .Eng

QCStd #1

QC Std#4

x2 Sample

Page 1

elementOne

14503 Air Nova M29 Report

PagEil~1 of 27
08:26:48 Thu 20·May-10 14503-3BH x2s Spike - 1 of 43

08:29:58 Thu 20·May-10 14502-1 x20 Sample ::09

08:33:08 Thu 20·May-10 14502-2 x20 Sample ::n9

08:36:17 Thu 20·May-10 14502-2 x20d Duplicate of 46 ::n9

08:39:25 Thu 20-May-10 14502-3 x50 Sample ::n9

08:42:34 Thu 20·May-10 14502·3 x50s Spike - 1 of 48 ::n9

08:45:42 Thu 20·May-10 QCStd 1 QC Std#1

08:48:50 Thu 20·May-10 QC Std 4 QC Std#4

09:00:52 Thu 2D-May-10 14503-3BH x5 Sample

09:04:00 Thu 20·May·10 14503-3BH x5s Spike - 1 of 52

09:07:08 Thu 2D-May-10 QCStd 1 QC Std#1

09:10:16 Thu 20·May-10 QC Std 4 QC Std#4

09:29:37 Thu 20-May-10 Blank Blank

09:31:11 Thu 20·May-10 Standard 1 Standard #1

09:32:47 Thu 20·May·10 Standard 2 Standard #2

09:34:23 Thu 20·May-1 0 Standard 3 Standard #3

09:35:59 Thu 20·May-10 QCStd 1 QCStd#1

09:37:35 Thu 20-May-10 QCStd2 QC Std #2

09:39:10 Thu 20-May-10 QC Std 3 QC Std#3

09:40:45 Thu 20·May-10 QC Sid 4 QC Std #4

09:42:21 Thu 20·May-10 QCSld5 QC Std #5

09:43:57 Thu 20-May-10 QCStd 10 QC Std #10

09:45:33 Thu 20-May-10 Irb Sample ::ng

09:47:08 Thu 20-May-10 Irb s Spike - 1 of 66 ::og

09:48:44 Thu 20-May-10 14502·1 Sample Eng

09:50:19 Thu 20-May-10 14502·2 Sample Eng

09:51:54 Thu 20-May-10 14502-2 d Duplicate of 69 Eng

09:53:30 Thu 20-May-10 14502·3 Sample Eng

09:55:07 Thu 20·May-10 14502-3 s Spike· 1 of 71 Eng

09:56:42 Thu 20-May-10 QCSld 1 QC Sid #1

09:58:17 Thu 20·May-10 QC Std 4 QC Std#4

----------~-----

Page 2

elementOne

14503 Air Nova M29 Report

Pagel22 of 27
elementOne

Analyst--KMS--

ICP-MS RUN SHEET

5/20/2010

Job Number:

A!S Lac. IDilution Sample 10 I Client Type Weight (g) IPrep Vol (ml)

5 QC Std2 Sample

14 14503-1FH Sample 100

15 14503-2FH Sample 100

16 s 14503-2FH Duplicate of 3 100

17 14503-3FH Sample 100

18 d 14503-3FH Spike - 1 of 5 100

19 14503-4FH Sample 100

20 LRB Sample 50

21 s LRB Spike - 1 of 8 50

22 14503-18H Sample 50x2

23 14503-28H Sample 50x2

24 d 14503-2BH Duplicate of 11 50x2

25 14503-38H Sample 50x2

26 s 14503-38H Spike - 1 of 13 50x2

27 14503-4BH Sample 50x2

28 Irb Sample 100

29 s Irb Spike - 1 of 16 100

30 14502-1 Sample 100x2

31 14502-2 Sample 100x2

32 d 14502-2 Duplicate of 19 100x2

33 14502-3 Sample 100x2

34 s 14502-3 Spike - 1 of 21 100x2

35 x2 14503-3BH Sample 50x2

36 x2s 14503-38H Spike - 1 of 23 50x2

37 x20 14502-1 Sample 100x2

38 x20 14502-2 Sample 100x2

39 x20d 14502-2 Duplicate of 26 100x2

40 x50 14502-3 Sample 100x2

41 x50s 14502·3 Spike - 1 of 28 100x2

42 x5 14503·3BH Sample 50x2

43 x5s 14503-38H Spike - 1 of 30 50x2

Spikes are post at O.02mL of 25ppm spikinQ solutions lot 021410-ABCD & F in a final volume of 10mL

Submitted for QC by: DatelTime: QC Review By: DatelTime:

KMS 5/2011011:31 l).~ .) I=')Wt.\tO \lo(:'f)

Re-Test Required: No: I Yes: Comments:

/

Resubmitted for QC Date/Time: QCReview: By: , DatelTime:

by:

elementOne

14503 Air Nova M29 Report

Pag~23 of 27
!ill t?ll fU Wetllctfvll

--

I

1 25 1 100 'I .~

1 25 1 100

1 25 1 100 "

1

1 25 1 100

1 2s 1 100 ";1 1 2S 1 100 1

1 2S 1 ;100 1

1 2S 1 100 'I

1 25 ,I 100 "

1 25 1 100 1

1 25 1 100 1

1 25 1 100 1

1 25 1 100 1

1 25 1 100 1

1 25 1 100 1

, 25 1 100 1

1 25 1 100 1

1 25 1 100 1

1 25 1 100 1

1 25 1 100 1

1 25 1 100 1

1 25 1 100 1

1 25 1 100 1

1 25 1 100 1

Thursday, May 20, 2010 11 :26 AM

elementOne

14503 Air Nova M29 Report

Pag~~4 of 27
ICP Standards and QC Standards Values Table

Element or Test Mass Symbol Std.#1 Std.#2 Std.#3 QC#1 QC #2 QC #3 QC #4 QC#6 QC#7 QC#8 QC#9 QC#10 QC#11

ppb ppb ppb A AB .25 LRB LRB+ LRB+

---._---~ ..~._..- Lithium 6 U

Lilhium 7 Li 1 100 500 0 1 250 100 0 50 100

Beryllium 9 Be 1 100 500 0 1 250 100 0.25 0 50 100

Boron 10 B 1 50 100 0 1 250 100 0 50 100

Boron 11 B 1 50 100 0 1 250 100 0 50 100

Sodium 23 Na 20 1100 5500 0 21 2500 1100 0 718

Magnesium 24 Mg 20 1100 5500 0 21 2500 1100 0 550

Magnesium 25 Mg 20 1100 5500 0 21 2500 1100 0 550

Aluminum 27 AI 1 100 500 0 1 250 100 0 50 100

Phosphorus 31 P 20 1000 5000 0 20 2500 1000 0 200

Potassium 39 K 20 1100 5500 a 21 2500 1100 a 500

Calcium 44 Ca 50 1100 5500 0 21 2500 1100 0 550

Scandium 45

Titanium 47 Ti 1 100 SOD 0 1 250 100 0 50 100

Titanium 49 Ti 1 100 SOD 0 1 250 100 0 50 100

Vanadium 51 V 1 100 500 0 1 250 100 0 20 0 50 100

Vanadium 51 V 1 100 SOD a 1 250 100 0 20 0 50 100

Chromium 52 Cr 1 100 500 0 1 250 100 10 0 50 100

Chromium 53 Cr 1 100 500 0 1 250 100 10 a 50 100

Iron 54 Fe 20 1100 5500 0 21 2500 1100 0 a

Manganese 55 Mn 1 100 500 0 1 250 100 0 10 0 50 100

Iron 57 Fe 20 1100 5500 0 21 2500 1100 0 0

Cobalt 59 Co 1 100 500 0 1 250 100 0 20 0 50 100

Nickel 60 Ni 1 100 500 0 1 250 100 0 20 0 50 100

Copper 63 Cu 1 100 500 0 1 250 100 0 10 0 50 100

Copper 65 Cu 1 100 500 0 1 250 100 0 10 0 50 100

Zinc 66 Zn 1 100 500 0 1 250 100 0 10 0 50 100

Zinc 67 Zn 1 100 500 0 1 250 100 0 10 0 50 100

Zinc 68 Zn 1 100 500 0 1 250 100 0 10 0 50 100

Germanium 72 Ge 1 100 500 0 1 250 100 0 50 100

Arsenic 75 As 1 100 500 0 1 250 100 0 10 0 50 100

Selenium 77 Se 1 100 500 0 1 250 100 0 10 0 50 100

Selenium 82 Se 1 100 500 0 1 250 100 0 10 0 50 100

Strontium 88 Sr 1 100 500 0 1 250 100 0 0 50 100

Molybdenum 95 Mo 1 100 500 0 1 250 100 0 50 100

Molybdenum 97 Mo 1 100 500 0 1 250 100 0 50 100

Molybdenum 98 Mo 1 100 500 0 1 200 100 0 50 100

Rhodium 103

Silver 107 Ag 1 100 500 0 1 250 100 0 10 0 50 100

Silver 109 Ag 1 100 500 0 1 250 100 0 10 0 50 100

Cadmium 111 Cd 1 100 500 0 1 250 100 0 5 0 50 100

Cadmium 114 Cd 1 100 500 0 1 250 100 0 5 0 50 100

Tin 118 Sn 1 100 500 0 1 250 100 0 0 50 100

Antimony 121 Sb 1 100 500 0 1 250 100 0 0 50 100

Antimony 123 Sb 1 100 500 0 1 250 100 0 50 100

Tellurium 128 Te 1 100 500 0 1 250 100 0 50 100

Cesium 133

Barium 135 Ba 1 100 500 0 1 250 100 0 0 50 100

Barium 137 Ba 1 100 500 0 1 250 100 0 0 50 100

Lanthanum 139 La 1 100 500 0 1 250 100 a 50 100

Tantalum 159 Ta 1 100 500 0 1 250 100 0 50 100

Platinum 195 PI 1 100 500 0 1 250 100 0 50 100

Gold 181 Au 1 100 500 0 1 250 100 0 50 100

Thallium 205 TI 1 100 500 0 1 250 100 a 0 50 100

Lead 208 Pb 1 100 500 0 1 250 100 0 0 50 100

Bismuth 209 Bi 1 100 500 0 1 250 100 0 50 100

Thorium 232 Th 1 100 500 0 1 250 100 a 50 100

Uranium 238 U 1 100 500 a 1 250 100 0 50 100

Krypton 83

elementOne

elementOne

14503 Air N£Xa M29 Report

Page 25 of 27
PerkinElmer ELAN 6100 ICP-MS

Method 6020& 200.8 Metals Summary Report

Sample 10: Blank

Sample DaWednesday, May 19, 2010 17:39:28

Sample Description:

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

I> Li

6 77619.9 ppb

1- Be

9 14.7 ppb

1-

P 31 7489.8 ppb

1 Sc 45 76237.1 ppb I Cr 52 3847.8 ppb 1 Cr 53 7853.1 ppb 1 Mn 55 615 ppb 1 Co 59 56.3 ppb 1 Ni 60 147.7 ppb 1 Cu 63 257 ppb I Cu 65 248.3 ppb 1 Zn 66 297 ppb 1 Zn 67 1064.7 ppb 1 Zn 68 460.3 ppb 1 As 75 92.9 ppb I Se 77 410.3 ppb I Se 82 -35.8 ppb

I> Rh 103 111053.4 ppb 1 Ag 107 209.7 ppb 1 Ag 109 199.3 ppb I Cd 111 -18.2 ppb

1- Cd 114 22.4 ppb

1- Sb 121 45.3 ppb 1 Sb 123 33.3 ppb 1 Ba 135 40.7 ppb I Ba 137 59.3 ppb

I> Ho 165 325362.6 ppb 1 TI 205 168.3 ppb

1- Pb 208 697.3 ppb

Kr 83 90.3 mg/L

Method 6020& 200.8 Metals Summary Report

Sample 10: Standard

1

Sample DaWednesday, May 19, 2010 17:42:35

Sample Description:

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

I> Li

6 77979.4 ppb

1- Be

9 531.7 260001 ppb

1-

P 31 10731.3 1300020 ppb

1 Sc 45 74910 ppb 1 Cr 52 5473.3 260001 ppb I Cr 53 9201 260001 ppb I Mn 55 4583.5 260001 ppb I Co 59 2914.8 260001 ppb 1 Ni 60 742.7 260001 ppb 1 Cu 63 1561.5 260001 ppb 1 Cu 65 917.4 260001 ppb 1 Zn 66 793.4 260001 ppb I Zn 67 1615.5 260001 ppb 1 Zn 68 928.7 260001 ppb 1 As 75 459.4 260001 ppb 1 Se 77 442 260001 ppb I Se 82 7.1 260001 ppb

I> Rh 103 108869.4 ppb 1 Ag 107 2509.7 0.96554 ppb 1 Ag 109 2412 0.95556 ppb 1 Cd 111 708 260001 ppb

1- Cd 114 1720.8 260001 ppb

1- Sb 121 2471 260001 ppb 1 Sb 123 1945.2 260001 ppb 1 Ba 135 694.7 260001 ppb I Ba 137 1227.7 260001 ppb

I> Ho 165 321744 ppb 1 TI 205 12052 260001 ppb

1- Pb 208 16783.8 260001 ppb

Kr 83 60.5 mg/L

elementOne

ICP-Data1 of 20

e 14503-Metals 26.1

49
PerkinElmer ELAN 6100 ICP-MS

Meas. Intem Cone. Mear Report Unit

6 76288.5 ppb 9 254959.3 499.96585 ppb

31 680476.3 5000.1568 ppb

45 73107.6 ppb

52 1178899.1 499.9501 ppb

53 147772.4 499.20867 ppb

55 1929646.2 499.49227 ppb

59 1375835.3 499.70943 ppb

60 281236.5 499.67676 ppb

63 648825.6 499.34656 ppb

65 313023.4 499.44831 ppb

66 232713.3 499.65573 ppb

67 39543.6 498.26724 ppb

68 164864.2 499.47534 ppb

75 210326.3 499.70285 ppb

77 18848.2 499.37559 ppb

82 24648.5 499.78962 ppb

103 104025.6 ppb

107 1034619 423.56569 ppb

109 1037055.5 429.47267 ppb

111 348618.4 499.93777 ppb

114 824786.7 499.71891 ppb

121 1197660.3 499.7514 ppb

123 927028.2 499.802 ppb

135 326434 499.78542 ppb

137 576938.8 499.85971 ppb

165 315219.7 ppb

205 5500906.4 498.40762 ppb

208 7534530.6 498.86717 ppb

83 -17644.4 mg/L

Method 6020

& 200.8 Metals Summary Report

Sample 10: Standard

2

Sample DaWednesday, May 19, 2010 17:45:44

Sample Description:

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

Li6 80451.6 ppb

Be9 53861.4 2599.7521 ppb

P 31 149303.2 25987.831 ppb

Sc 45 75751.5 ppb

Cr 52 252280.5 2599.8299 ppb

Cr 53 38593.5 2598.7308 ppb

Mn 55 418560.5 2599.7604 ppb

Co 59 294583.4 2599.7555 ppb

Ni 60 60391.2 2599.75 ppb

Cu 63 141681.8 2599.7672 ppb

Cu 65 68119.9 2599.7501 ppb

Zn 66 50199.3 2599.7464 ppb

Zn 67 9907.7 2598.3136 ppb

Zn 68 36071.1 2599.6585 ppb

As 75 45093.9 2599.7964 ppb

Se 77 4428.4 2599.7519 ppb

Se 82 5224.2 2599.8008 ppb

Rh 103 109738.5 ppb

Ag 107 257670 100.00097 ppb

Ag 109 254864.1 100.00123 ppb

Cd 111 73751.5 2599.7522 ppb

Cd 114 176537.4 2599.7576 ppb

Sb 121 254141 2599.7554 ppb

Sb 123 196335.2 2599.7504 ppb

Ba 135 69192.6 2599.7567 ppb

Ba 137 121769.4 2599.7534 ppb

Ho 165 330087.8 ppb

TI 205 1248747.2 2599.756 ppb

Pb 208 1671919.3 2599.7528 ppb

Kr 83 -3908.1 mg/L

Method 6020

& 200.8 Metals Summary Report

Sample 10: Standard

3

Sample Da Wednesday, May 19, 2010 17:48:53

Sample Description:

Concentration Results

Analyte Mass

Li

BeP

Sc

Cr

Cr

Mn

Co

Ni

Cu

Cu

Zn

Zn

Zn

As

Se

Se

Rh

Ag

Ag

Cd

Cd

Sb

Sb

Ba

Ba

Ho

TI

Pb

Kr

I>

II-II1I1II1IIII1I

I>III

II-III

I>I

1-

I>

II-IIIIII1IIIIIII

I>I1I

II-III

I>I

1-

ICP-Data2 of 20

elementOne e 14503-Metals 26.2

50
PerkinElmer ELAN 6100 ICP-MS

Method 6020& 200.8 Metals Summary Report

Sample 10: QC Std

1

Sample DaWednesday, May 19, 2010 17:52:01

Sample Description:

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

I> Li

6 78414 ppb

1- Be

9 160.7 0.28108 ppb

1-

P 31 8013.2 5.91055 ppb

1 Sc 45 74566.1 ppb 1 Cr 52 4622.5 0.3817 ppb I Cr 53 9642.1 7.217 ppb I Mn 55 1962.5 0.34451 ppb 1 Co 59 991.4 0.33106 ppb 1 Ni 60 316.3 0.30176 ppb I Cu 63 742.7 0.37081 ppb I Cu 65 525 0.44369 ppb 1 Zn 66 463.3 0.37109 ppb 1 Zn 67 1809.2 9.90085 ppb 1 Zn 68 762 0.94396 ppb I As 75 243 0.35325 ppb I Se 77 427.3 0.85209 ppb 1 Se 82 -46.1 -0.22996 ppb

I> Rh 103 106931.4 ppb I Ag 107 29080.3 11.47182 ppb I Ag 109 28258.6 11.27151 ppb 1 Cd 111 163.8 0.25225 ppb

1- Cd 114 504 0.28457 ppb

1- Sb 121 749.4 0.29103 ppb I Sb 123 530.9 0.26583 ppb 1 Ba 135 224 0.27959 ppb 1 Ba 137 398.3 0.29265 ppb

I> Ho 165 320550.8 ppb I TI 205 5151.2 0.4479 ppb

1- Pb 208 5994.5 0.34857 ppb

Kr 83 115.5 mg/L

Method 6020& 200.8 Metals Summary Report

Sample 10: QC Std

2

Sample DaWednesday, May 19, 2010 17:55:10

Sample Description:

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

I> Li

6 78085 ppb

1- Be

9 560 1.04354 ppb

1-

P 31 10824.4 26.86444 ppb

I Sc 45 73182.4 ppb 1 Cr 52 5681.1 0.84049 ppb 1 Cr 53 9933.4 8.51432 ppb I Mn 55 4906 1.09765 ppb I Co 59 3115.2 1.09176 ppb 1 Ni 60 752.7 1.0709 ppb 1 Cu 63 1741.2 1.13235 ppb I Cu 65 1024.7 1.2351 ppb I Zn 66 952.4 1.41227 ppb 1 Zn 67 1947.5 11.81949 ppb 1 Zn 68 1063.4 1.86361 ppb I As 75 665.6 1.34362 ppb I Se 77 427.7 0.95077 ppb 1 Se 82 15.5 0.99359 ppb

I> Rh 103 105973.1 ppb I Ag 107 9238.4 3.64268 ppb I Ag 109 9015.5 3.59735 ppb 1 Cd 111 753.4 1.08714 ppb

1- Cd 114 1799.9 1.05836 ppb

1- Sb 121 2522.7 1.03068 ppb 1 Sb 123 1994.7 1.05363 ppb 1 Ba 135 751 1.08592 ppb I Ba 137 1272.8 1.04943 ppb

I> Ho 165 316239.9 ppb 1 TI 205 13044.4 1.16226 ppb

1- Pb 208 17592.7 1.11673 ppb

Kr 83 55.2 mg/L

elementOne

ICP-Data3 of 20

e 14503-Metals 26.3

51
PerkinElmer ELAN 6100 ICP-MS

Meas. Intem Cone. Mear Report Unit

6 80956.1 ppb 9 53053.9 98.17611 ppb

31 150052 1022.8359 ppb

45 76644.3 ppb

52 251099.9 101.55228 ppb

53 38691.3 106.56547 ppb

55 411792.2 102.71141 ppb

59 291270.9 102.06691 ppb

60 60439.9 103.46517 ppb

63 141155 104.71331 ppb

65 66649.5 102.31224 ppb

66 49460.6 102.00793 ppb

67 9958.1 111.29188 ppb

68 36184.6 104.77557 ppb

75 45412.9 103.94999 ppb

77 4231 99.98535 ppb

82 5228.3 102.87508 ppb

103 107796.6 ppb

107 263544.7 104.02647 ppb

109 258279.7 103.15859 ppb

111 73343.8 101.5653 ppb

114 176072.9 102.92564 ppb

121 254605.2 101.62419 ppb

123 194347.5 100.24615 ppb

135 68693.1 100.64253 ppb

137 122211.8 101.2842 ppb

165 329392.6 ppb

205 1243173.9 107.82095 ppb

208 1668005.9 105.69371 ppb

83 -3902.3 mglL

Method 6020

& 200.8 Metals Summary Report

Sample ID: QC Std

3

Sample DaWednesday, May 19. 2010 17:58:18

Sample Description:

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

Li6 80876.5 ppb

Be9 130885.3 242.39193 ppb

P 31 691723.6 4912.6299 ppb

Sc 45 75001.9 ppb

Cr 52 612148.9 250.41452 ppb

Cr 53 80332.9 250.06205 ppb

Mn 55 1006819.2 251.74091 ppb

Co 59 711935.5 250.04861 ppb

Ni 60 145046.5 249.13604 ppb

Cu 63 341097.3 253.88409 ppb

Cu 65 164466.9 253.63143 ppb

Zn 66 120489.5 249.81615 ppb

Zn 67 21697.9 258.40175 ppb

Zn 68 86740.5 253.58855 ppb

As 75 108825.4 250.09457 ppb

Se 77 9849.3 247.1805ppb

Se 82 12598.8 247.47428 ppb

Rh 103 107596.3 ppb

Ag 107 588474.7 232.88058 ppb

Ag 109 573072.3 229.53648 ppb

Cd 111 177991.7 246.83851 ppb

Cd 114 432627.8 253.3983 ppb

Sb 121 612393.7 244.77894 ppb

Sb 123 475340.2 245.47545 ppb

Ba 135 168656.9 247.59609 ppb

Ba 137 294865.5 244.85821 ppb

Ho 165 329126.8 ppb

TI 205 2860003.2 248.3207 ppb

Pb 208 3914595.8 248.54112 ppb

Kr 83 -9674.5 mglL

Method 6020

& 200.8 Metals Summary Report

Sample 10: QC Std

4

Sample Da Wednesday. May 19. 2010 18:01:26

Sample Description:

Concentration Results

Analyte Mass

Li

BeP

Sc

Cr

Cr

Mn

Co

Ni

Cu

Cu

Zn

Zn

Zn

As

Se

Se

Rh

Ag

Ag

Cd

Cd

Sb

Sb

Ba

Ba

Ho

TI

Pb

Kr

I>

II-I1IIIIII1II1I1

I>I1I

II-II1

I>I

1-

I>

II-I1IIIIII1I1I1I

I>1I1

II-III

I>I

1-

ICP-Data4 of 20

elementOne e 14503-Metals 26.4

52
PerkinElmer ELAN 6100 ICP-MS

Meas. Intem Cone. Mear Report Unit

6 86586.3 ppb 9 46.7 0.05285 ppb

31 6277006.3 48591.591 ppb

45 75599.7 ppb

52 5385.3 0.86461 ppb

53 10330.5 12.19956 ppb

55 12262 3.1611 ppb

59 3334.3 1.24491 ppb

60 1741.2 2.9914 ppb

63 2628.4 1.93069 ppb

65 3887.5 6.10549 ppb

66 3590 7.44933 ppb

67 2635.7 22.71216 ppb

68 2057.9 5.22174 ppb

75 63.3 -0.03424 ppb

77 709 9.61499 ppb

82 -59.7 -0.59183 ppb

103 99698.3 ppb

107 2383.7 0.93821 ppb

109 2349.3 0.93772 ppb

111 273.3 0.42536 ppb

114 2366.6 1.48319 ppb

121 334.7 0.11403 ppb

123 278.3 0.12493 ppb

135 305.3 0.38224 ppb

137 516.7 0.3746 ppb

165 333017 ppb

205 921 0.06447 ppb

208 9403.9 0.54533 ppb

83 59.5 mg/L

Method 6020

& 200.8 Metals Summary Report

Sample 10: QC Std

5

Sample Da Wednesday, May 19, 2010 18:04:35

Sample Description:

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

Li6 78767.4 ppb

Be

9 25907.9 49.26169 ppb

P 31 36412.2 213.03735 ppb

Sc 45 74306.6 ppb

Cr 52 120367 48.67046 ppb

Cr 53 23580.6 56.08091 ppb

Mn 55 198775.7 50.30891 ppb

Co 59 140284.8 49.95658 ppb

Ni 60 28756.5 49.91557 ppb

Cu 63 66985.2 50.39464 ppb

Cu 65 32331.5 50.25524 ppb

Zn 66 24087.9 50.18378 ppb

Zn 67 5820.9 60.94246 ppb

Zn 68 17187.2 49.89944 ppb

As 75 21921.6 50.88629 ppb

Se 77 2248.3 49.20817 ppb

Se 82 2524.2 50.787 ppb

Rh 103 106091.8 ppb

Ag 107 129930.2 52.10344 ppb

Ag 109 126558.1 51.30365 ppb

Cd 111 35120.4 49.425 ppb

Cd 114 84971.5 50.48261 ppb

Sb 121 121366 50.42758 ppb

Sb 123 94663.3 50.80241 ppb

Ba 135 32867.4 50.09577 ppb

Ba 137 57916.2 49.95689 ppb

Ho 165 316456.9 ppb

TI 205 582757.8 52.57646 ppb

Pb 208 805007.6 53.076 ppb

Kr 83 92.9 mg/L

Method 6020

&200.8 Metals Summary Report

Sample 10: QC Std

6

Sample DaWednesday, May 19, 201018:07:43

Sample Description:

Concentration Results

Analyte Mass

Li

BeP

Sc

Cr

Cr

Mn

Co

Ni

Cu

Cu

Zn

Zn

Zn

As

Se

Se

Rh

Ag

Ag

Cd

Cd

Sb

Sb

Ba

Ba

Ho

TI

Pb

Kr

I>

II-IIIIIII1III1II

I>III

II-III

I>1

1-

I>

II-IIIIIIII1IIIII

I>III

II-III

I>I

1-

ICP-Data5 of 20

elementOne e 14503-Metals 26.5

53
PerkinElmer ELAN 6100 ICP-MS

98250.1 ppb

189.7 0.26119 ppb

11700.9 29.44726 ppb

78000.8 ppb

3745.1 -0.04213 ppb

9686.2 6.04345 ppb

2008.9 0.33766 ppb

874.7 0.27844 ppb

414.3 0.44398 ppb

872 0.44311 ppb

564.4 0.47251 ppb

1567.8 2.55849 ppb

2073.6 12.15091 ppb

1446.8 2.7957 ppb

162.8 0.16152 ppb

406.3 -0.10589 ppb

20 1.05773 ppb

111238 ppb

1560.5 0.51876 ppb

1657.2 0.56608 ppb

195.6 0.28752 ppb

521.7 0.28312 ppb

733.7 0.25723 ppb

583.5 0.26632 ppb

231.7 0.25999 ppb

386 0.25128 ppb

349923 ppb

3573.7 0.27691 ppb

6121.8 0.32051 ppb

29.4 mg/L

Meas. Intem Cone. Mear Report Unit

69

31

45

52

53

55

59

60

63

65

66

67

68

75

77

82

103

107

109

111

114

121

123

135

137

165

205

208

83

Method 6020

& 200.8 Metals Summary Report

Sample ID: QC Std

7

Sample DaWednesday, May 19, 2010 18:10:52

Sample Description:

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

Li6 85721 ppb

Be9 40.7 0.04298 ppb

P 31 5869740.3 48998.313 ppb

Sc 45 70021.9 ppb

Cr 52 26757.7 11.2824 ppb

Cr 53 12192.2 22.63672 ppb

Mn 55 47222.4 13.60267 ppb

Co 59 52326.2 21.36656 ppb

Ni 60 11156.9 22.08546 ppb

Cu 63 12976.3 11.05525 ppb

Cu 65 8474.3 14.84797 ppb

Zn 66 6439.9 14.98073 ppb

Zn 67 3057.8 31.64546 ppb

Zn 68 4095.3 12.69162 ppb

As 75 4095.6 10.74938 ppb

Se 77 1013.7 20.42977 ppb

Se 82 426.6 10.39879 ppb

Rh 103 92469.8 ppb

Ag 107 21818.5 9.97488 ppb

Ag 109 21482.4 9.93155 ppb

Cd 111 3325.1 5.38282 ppb

Cd 114 9551.7 6.49988 ppb

Sb 121 203 0.06696 ppb

Sb 123 154.9 0.06665 ppb

Ba 135 469 0.66342 ppb

Ba 137 803.7 0.65078 ppb

Ho 165 312987 ppb

TI 205 644.4 0.04398 ppb

Pb 208 3648 0.19862 ppb

~7 ~~

Method 6020& 200.8 Metals Summary Report

Sample ID: QC Std

8

Sample DaWednesday, May 19, 201018:14:01

Sample Description:

Concentration Results

Analyte Mass

Li

BeP

Sc

Cr

Cr

Mn

Co

Ni

Cu

Cu

Zn

Zn

Zn

As

Se

Se

Rh

Ag

Ag

Cd

Cd

Sb

Sb

Ba

Ba

Ho

TI

Pb

Kr

I>

II-IIIIIIIIIIIIII

I>III

II-III

I>I

II>

II-IIIIIIIIIIIIII

I>II1

II-III

I>I

1-

ICP-Data6 of 20

elementOne e 14503-Metals 26.6

54
PerkinElmer ELAN 6100 ICP-MS

Method 6020& 200.8 Metals Summary Report

Sample ID: QC Std

9

Sample DaWednesday, May 19, 2010 18:17:11

Sample Description:

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

I> Li

6 81047.2 ppb

1- Be

9 16.7 0.00271 ppb

1-

P 31 15017.7 66.85655 ppb

1 Sc 45 68145.2 ppb I Cr 52 3667.4 0.13415 ppb I Cr 53 2280.3 -17.50397 ppb I Mn 55 8991.4 2.33476 ppb I Co 59 241 0.07415 ppb I Ni 60 816.4 1.3045 ppb I Cu 63 1310.8 0.89238 ppb I Cu 65 777.7 0.95505 ppb 1 Zn 66 4317 9.30333 ppb 1 Zn 67 1387.4 6.24617 ppb I Zn 68 3202.2 9.07309 ppb I As 75 87 0.01362 ppb I Se 77 33.7 -9.42619 ppb 1 Se 82 7.7 0.84467 ppb

I> Rh 103 97439.1 ppb I Ag 107 1044.1 0.37666 ppb I Ag 109 981.4 0.35703 ppb I Cd 111 34.8 0.07793 ppb

1- Cd 114 59.8 0.02554 ppb

1- Sb 121 329.3 0.11989 ppb I Sb 123 263 0.12464 ppb I Ba 135 210 0.26367 ppb I Ba 137 380.3 0.28184 ppb

I> Ho 165 313330.1 ppb 1 TI 205 609.7 0.04093 ppb

1- Pb 208 14720.3 0.93692 ppb

Kr 83 29 mg/L

Method 6020& 200.8 Metals Summary Report

Sample 10: QC Std 10

Sample DaWednesday, May 19, 2010 18:20:22

Sample Description:

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

I> Li

6 81918.7 ppb

1- Be

9 23096.3 42.1817 ppb

1-

P 31 11233.9 37.18669 ppb

1 Sc 45 68079.9 ppb I Cr 52 105462.9 46.52554 ppb I Cr 53 13539.8 25.34589 ppb 1 Mn 55 178224.7 49.19369 ppb 1 Co 59 122774.3 47.6789 ppb I Ni 60 26372.6 49.9552 ppb I Cu 63 57691.7 47.3898 ppb I Cu 65 27675.4 46.94808 ppb 1 Zn 66 24445.5 55.62733 ppb I Zn 67 4455.1 48.73497 ppb I Zn 68 17493.5 55.57279 ppb I As 75 17022.3 43.13246 ppb 1 Se 77 1403.1 30.24689 ppb I Se 82 1843.2 40.61013 ppb

I> Rh 103 97256.2 ppb I Ag 107 3790.8 1.58463 ppb I Ag 109 3626.1 1.53547 ppb I Cd 111 28891.9 44.35022 ppb

1- Cd 114 69822.2 45.23462 ppb

1- Sb 121 95469.3 40.83553 ppb I Sb 123 74078.7 40.94289 ppb I Ba 135 28451.5 44.68234 ppb 1 Ba 137 49962.5 44.37706 ppb

I> Ho 165 307501 ppb I TI 205 526869.9 48.95588 ppb

1- Pb 208 738149.8 50.13942 ppb

Kr 83 36.6 mg/L

elementOne

ICP-Data7 of 20

e 14503-Metals 26.7

55
PerkinElmer ELAN 6100 ICP-MS

84466.2 ppb

258.3 0.43182 ppb

489159.1 ppb

72363.9 34.76051 ppb

10090.6 16.14218 ppb

41202.3 12.4177 ppb

7460.4 3.17155 ppb

9359.8 19.36213 ppb

3769.1 10.35671 ppb

219 -3.42923 ppb

104.9 3.18325 ppb

88234.6 ppb

426.3 0.73775 ppb

477.4 0.32565 ppb

5876.9 2.50548 ppb

4608.5 2.54074 ppb

306340.4 ppb

231324.1 15.73806 ppb

-1039 mg/L

Meas. Intem Cone. Mear Report Unit

69

45

52

53

55

59

60

75

77

82

103

111

114

121

123

165

208

83

Method 6020

& 200.8 Metals Summary Report

Sample 10: QC Std

2

Sample OaWednesday. May 19. 2010 18:23:32

Sample De Air Nova

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

Li6 83414.7 ppb

Be9 536.3 0.93363 ppb

P 31 10029.2 31.88704 ppb

Sc 45 67750.6 ppb

Cr 52 4934.3 0.83727 ppb

Cr 53 8572.4 8.24378 ppb

Mn 55 4368.1 1.12434 ppb

Co 59 2735.7 1.10209 ppb

Ni 60 657 1.0707 ppb

Cu 63 1538.8 1.14974 ppb

Cu 65 880.7 1.21326 ppb

Zn 66 806 1.35451 ppb

Zn 67 1429.8 8.00433 ppb

Zn 68 793.7 1.41784 ppb

As 75 478.5 1.07605 ppb

Se 77 405.3 1.94226 ppb

Se 82 48.5 1.79227 ppb

Rh 103 92332.9 ppb

Ag 107 2674.1 1.15386 ppb

Ag 109 2443.7 1.06208 ppb

Cd 111 680.5 1.12282 ppb

Cd 114 1615.5 1.09066 ppb

Sb 121 2673.7 1.19441 ppb

Sb 123 2102.3 1.21406 ppb

Ba 135 624.4 0.97846 ppb

Ba 137 1134.7 1.01789 ppb

Ho 165 290214.7 ppb

TI 205 12199.2 1.18605 ppb

Pb 208 16385.4 1.13455 ppb

Kr 83 18.5 mg/L

Method 6020

&200.8 Metals Summary Report

Sample 10: 14503-1FH

Sample OaWednesday, May 19, 201018:26:41

Sample De Air Nova

Concentration Results

Analyte Mass

Li

Be

Sc

Cr

Cr

Mn

Co

Ni

As

Se

Se

Rh

Cd

Cd

Sb

Sb

Ho

Pb

Kr

I>

II-IIIIIIIIIIIIII

I>III

II-II1

I>I

1-

I>

I-II1III1II

I>1

II-I

I>

1-

ICP-Oata8 of 20

elementOne e 14503-Metals 26.8

56
PerkinElmer ELAN 6100 ICP-MS

85802.6 ppb

239.7 0.38998 ppb

295660.7 ppb

89653.7 43.2182 ppb

11290.7 20.956 ppb

47279.4 14.20764 ppb

7983.8 3.38314 ppb

15456.1 32.0111 ppb

4084.3 11.19325 ppb

195.3 -4.19591 ppb

135.3 3.8892 ppb

88683.7 ppb

913 1.56027 ppb

1516.5 1.0627 ppb

9770.9 4.1172 ppb

7564.8 4.11709 ppb

310845.6 ppb

287738.9 19.30081 ppb

-1025.7 mg/L

Meas. Intem Conc. Mear Report Unit

69

45

52

53

55

59

60

75

77

82

103

111

114

121

123

165

208

83

Method 6020

& 200.8 Metals Summary Report

Sample 10: 14503-2FH

Sample Da Wednesday, May 19, 2010 18:29:49

Sample De Air Nova

Concentration Results

Analyte Mass Meas. Intem Conc. Mear Report Unit

Li6 88759.8 ppb

Be9 259 0.40862 ppb

Sc 45 301337.5 ppb

Cr 52 89538.9 42.26941 ppb

Cr 53 11586.7 21.21705 ppb

Mn 55 47319 13.92924 ppb

Co 59 7883.8 3.27373 ppb

Ni 60 15358.6 31.1378 ppb

As 75 3993.4 10.7129 ppb

Se 77 185.7 -4.6076 ppb

Se 82 136.8 3.85604 ppb

Rh 103 90498.1 ppb

Cd 111 930.8 1.55779 ppb

Cd 114 1489.7 1.02363 ppb

Sb 121 9830 4.05689 ppb

Sb 123 7581.2 4.04253 ppb

Ho 165 317252.1 ppb

Pb 208 289874.2 19.03191 ppb

Kr 83 -1042.7 mg/L

Method 6020& 200.8 Metals Summary Report

Sample 10: 14503-2FH

Sample Da Wednesday, May 19, 2010 18:32:56

Sample De Air Nova

Concentration Results

Analyte Mass

Li

Be

Sc

Cr

Cr

Mn

Co

Ni

As

Se

Se

Rh

Cd

Cd

Sb

Sb

Ho

Pb

Kr

I>

I-IIIII1III

I>I

II-I

I>

1-

I>

I-IIIIIIIII

I>I

II-I

I>

1-

ICP-Data9 of 20

elementOne e 14503-Metals 26.9

57
PerkinElmer ELAN 6100 ICP-MS

Meas. Intem Cone. Mear Report Unit

6 84052.4 ppb

9 23300.9 41.43401 ppb

45 544814.4 ppb

52 183175.2 82.89479 ppb

53 22140 58.98249 ppb

55 245652.3 68.54901 ppb

59 135446.2 53.2297 ppb

60 44401.5 85.29411 ppb

75 21850.5 56.04514 ppb

77 1597.1 36.30426 ppb

82 1952.9 43.47821 ppb

103 96323.4 ppb

111 31133 48.26354 ppb

114 74131.4 48.55446 ppb

121 125054.9 48.54446 ppb

123 97220.6 48.69662 ppb

165 338706 ppb

208 2298522.1 141.57966 ppb

83 -1558.7 mg/L

Method 6020 & 200.8 Metals Summary Report

Sample ID: 14503-3FH

Sample DaWednesday, May 19, 2010 18:36:04

Sample De Air Nova

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

Li 6 82636.6 ppb

Be 9 329 0.56679 ppb

Sc 45 549235.9 ppb

Cr 52 65571.7 32.45267 ppb

Cr 53 8518.3 10.72999 ppb

Mn 55 53575.4 16.73271 ppb

Co 59 9596.7 4.22432 ppb

Ni 60 17528.6 37.72623 ppb

As 75 4522.7 12.90244 ppb

Se 77 221.3 -3.11754 ppb

Se 82 173.6 4.95002 ppb

Rh 103 85448.6 ppb

Cd 111 1885.5 3.31798 ppb

Cd 114 3700 2.71388 ppb

Sb 121 11967.2 5.11356 ppb

Sb 123 9216.2 5.08621 ppb

Ho 165 306682.3 ppb

Pb 208 1383708.7 94.09952 ppb

Kr 83 -1385.3 mg/L

Method 6020 & 200.8 Metals Summary Report

Sample ID: 14503-3FH

Sample DaWednesday, May 19, 201018:39:12

Sample De Air Nova

Concentration Results

Analyte Mass

Li

Be

Sc

Cr

Cr

Mn

Co

Ni

As

Se

Se

Rh

Cd

Cd

Sb

Sb

Ho

Pb

Kr

I>

II

I

I

I

I

I

I

I

I

I>

I

III

I>

1-

I>

II

I

I

I

I

I

I

I

I

I>

I

III

I>

1-

ICP-Data 10 of 20

elementOne

e 14503-Metals 26.10

58
PerkinElmer ELAN 6100 rCP-MS

86933.6 ppb

15.3 -0.00198 ppb

86735.8 ppb

5489.3 0.53935 ppb

1206.4 -22.34705 ppb

9456,9 2.02223 ppb

153.7 0.0304 ppb

907.4 1.1862 ppb

126 0,0596 ppb

27.7 -9,73234 ppb

-16.5 0.37496 ppb

117348.7 ppb

43.3 0.08002 ppb

106.1 0,04455 ppb

41782.3 14,87045 ppb

32308 14.85682 ppb

369103,8 ppb

19478.8 1.05775 ppb

56.6 mg/L

Meas. Intem Conc, Mear Report Unit

69

45

52

53

55

59

60

75

77

82

103

111

114

121

123

165

208

83

Method 6020

& 200.8 Metals Summary Report

Sample ID: 14503-4FH

Sample DaWednesday, May 19, 2010 18:42:20

Sample De Air Nova

Concentration Results

Analyte Mass Meas. Intem Conc, Mear Report Unit

Li6 85392,2 ppb

Be9 36 0.03511 ppb

Sc 45 283991.7 ppb

Cr 52 26069 9.23322 ppb

Cr 53 3703,1 -13.37062 ppb

Mn 55 26701,2 6.55406 ppb

Co 59 434.7 0.13378 ppb

Ni 60 3120.9 5.13731 ppb

As 75 177.1 0,20055 ppb

Se 77 25.7 -9,72088 ppb

Se 82 -59,1 -0.49244 ppb

Rh 103 107217.7 ppb

Cd 111 281.4 0.41498 ppb

Cd 114 195.7 0.10128 ppb

Sb 121 1494.5 0.54048 ppb

Sb 123 1166 0.54654 ppb

Ho 165 351903.8 ppb

Pb 208 52531.4 3.07363 ppb

Kr 83 -5.5 mg/L

Method 6020& 200.8 Metals Summary Report

Sample ID: LRB

Sample DaWednesday, May 19, 2010 18:45:28

Sample De Air Nova

Concentration Results

Analyte Mass

Li

Be

Sc

Cr

Cr

Mn

Co

Ni

As

Se

Se

Rh

Cd

Cd

Sb

Sb

Ho

Pb

Kr

I>

I-IIIIIIIII

I>I

II-I

I>

1-

I>

I-IIIIIIIII

I>I

II-I

I>

1-

rCP-Data 11 of 20

elementOne e 14503-Metals 26.11

59
PerkinElmer ELAN 6100 ICP-MS

94555.2 ppb

27.3 0.01488 ppb

88076 ppb

25565.6 8.39971 ppb

4111.3 -12.8148 ppb

806319 190.13537 ppb

879.4 0.27222 ppb

3105.2 4.79345 ppb

4340.2 9.22813 ppb

157.7 -6.51227 ppb

-92.1 -0.99804 ppb

114082.2 ppb

165.7 0.24146 ppb

257.4 0.12855 ppb

1311.1 0.45586 ppb

1037.6 0.46724 ppb

363611.5 ppb

42149.3 2.37337 ppb

1044.5 mg/L

Meas. Intem Cone. Mear Report Unit

6

9

45

52

53

55

59

60

75

77

82

103

111

114

121

123

165

208

83

Method 6020 & 200.8 Metals Summary Report

Sample ID: LRB

Sample DaWednesday, May 19, 2010 18:48:37

Sample De Air Nova

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

Li 6 85984.6 ppb

Be 9 24628.7 42.84753 ppb

Sc 45 86035.9 ppb

Cr 52 132190.7 46.41794 ppb

Cr 53 16210.8 23.02156 ppb

Mn 55 225176.5 49.55714 ppb

Co 59 152131.4 47.08154 ppb

Ni 60 31020 46.75278 ppb

As 75 21244.8 42.86126 ppb

Se 77 1686.8 28.5269 ppb

Se 82 2180.2 38.3135 ppb

Rh 103 121926.6 ppb

Cd 111 35005.7 42.85892 ppb

Cd 114 84989.9 43.89314 ppb

Sb 121 117599 41.36337ppb

Sb 123 91284.6 41.49537 ppb

Ho 165 373789.6 ppb

Pb 208 890105.6 49.69573 ppb

Kr 83 83.2 mg/L

Method 6020 & 200.8 Metals Summary Report

Sample ID: 14503-1BH

Sample DaWednesday, May 19, 2010 18:51:47

Sample De Air Nova

Concentration Results

Analyte Mass

Li

Be

Sc

Cr

Cr

Mn

Co

Ni

As

Se

Se

Rh

Cd

Cd

Sb

Sb

Ho

Pb

Kr

I>

I·

I

I

I

I

I

I

I

I

I

I>

I

III

I>

1-

I>

II

I

I

I

I

I

I

I

I

I>

I

III

I>

1-

ICP-Data 12 of 20

elementOne

e 14503-Metals 26.12

60
PerkinElmer ELAN 6100 ICP-MS

Method 6020& 200.8 Metals Summary Report

Sample ID: QC Std

1

Sample DaWednesday, May 19, 2010 18:54:55

Sample Description:

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

I> Li6 94736.4 ppb

I_ Se9 19.7 0.00297 ppb

1_P 31 7807.4 0.38225 ppb

1 Sc 45 86811.5 ppb 1 Cr 52 4176.3 0.07344 ppb 1 Cr 53 8684.8 1.73511 ppb 1 Mn 55 1504.1 0.2033 ppb 1 Co 59 123.7 0.02144 ppb 1 Ni 60 145.3 -0.01197 ppb 1 Cu 63 290 0.01626 ppb 1 Cu 65 956.7 1.01109 ppb 1 Zn 66 604.4 0.57722 ppb 1 Zn 67 1581.8 5.60997 ppb 1 Zn 68 517 0.10952 ppb 1 As 75 82.9 -0.02735 ppb 1 Se 77 331 -2.30881 ppb 1 Se 82 -8.6 0.52309 ppb

I> Rh 103 115135.8 ppb 1 Ag 107 676.7 0.17063 ppb 1 Ag 109 680.7 0.17759 ppb 1 Cd 111 6.8 0.03356 ppb

1_ Cd 114 41.5 0.00985 ppb

1_ Sb 121 262.7 0.07755 ppb 1 Sb 123 233.6 0.0926 ppb 1 Sa 135 62 0.0236 ppb 1 Sa 137 91.3 0.01996 ppb

I> Ho 165 357951.2 ppb 1 TI 205 521 0.0268 ppb

1_ Pb 208 1098 0.0193 ppb

Kr 83 64.8 mg/L

Method 6020

& 200.8 Metals Summary Report

Sample ID: QC Std

4

Sample Da Wednesday, May 19, 2010 18:58:03

Sample Description:

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

I> Li6 91470.3 ppb

1_ Se9 59260.7 96.90582 ppb

1_P 31 163228.2 1042.9403 ppb

1 Sc 45 85633.2 ppb I Cr 52 267731.8 101.35181 ppb I Cr 53 40052.5 102.49351 ppb 1 Mn 55 445905.2 104.1485 ppb I Co 59 307385.7 100.87803 ppb I Ni 60 62863.1 100.72798 ppb 1 Cu 63 148006.1 102.75534 ppb I Cu 65 71664 103.02391 ppb 1 Zn 66 53548.4 103.43239 ppb 1 Zn 67 10453 109.24255 ppb 1 Zn 68 38402.4 104.0879 ppb I As 75 48207.4 103.297 ppb 1 Se 77 4550.8 100.86467 ppb 1 Se 82 5619.6 103.56634 ppb

I> Rh 103 115129.1 ppb 1 Ag 107 268242.8 99.19686 ppb 1 Ag 109 263201.6 98.40312 ppb 1 Cd 111 78285.1 101.51597 ppb

1_ Cd 114 188991.2 103.4825 ppb

1_ Sb 121 269782.8 99.92111 ppb 1 Sb 123 209243.3 100.08439 ppb 1 Sa 135 74363.7 101.10726 ppb 1 Sa 137 129913.8 99.93294 ppb

I> Ho 165 355125.6 ppb I TI 205 1314927.3 105.71979 ppb

1_ Pb 208 1764150 103.71935 ppb

Kr 83 -4124.3 mg/L

Method 6020

& 200.8 Metals Summary Report

ICP-Data 13 of 20

elemenlOne e 14503-Metals

61

26.13
PerkinElmer ELAN 6100 ICP-MS

Sample 10: 14503-2BH

Sample OaWednesday, May 19, 201019:01:12

Sample De Air Nova

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

I> Li 6 91551 ppb

1- Be 9 44.3 0.0461 ppb

I Sc 45 85249.9 ppb

I Cr 52 11381.5 3.20099 ppb

I Cr 53 2954.5 -15.88573 ppb

I Mn 55 25237.7 6.24293 ppb

I Co 59 610 0.19693 ppb

I Ni 60 1803.5 2.88819 ppb

I As 75 4559.1 10.39798 ppb

I Se 77 157.7 -6.2324 ppb

I Se 82 -173.9 -2.77005 ppb

I> Rh 103 106325.5 ppb

I Cd 111 154.9 0.24124 ppb

1- Cd 114 237.7 0.1273 ppb

1- Sb 121 1424.8 0.53725 ppb

I Sb 123 1082.1 0.52768 ppb

I> Ho 165 338150.3 ppb

1- Pb 208 52699.9 3.21455 ppb

Kr 83 1166.3 mg/L

Method 6020 & 200.8 Metals Summary Report

Sample 10: 14503-2BH

Sample Oa Wednesday, May 19, 2010 19:04:22

Sample De Air Nova

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

I> Li 6 96449.1 ppb

1- Be 9 18.3 0.0001 ppb

I Sc 45 85165.4 ppb

I Cr 52 11174.5 3.04617 ppb

I Cr 53 2147.3 -18.785 ppb

I Mn 55 25425.9 6.18847 ppb

I Co 59 868.7 0.28542 ppb

I Ni 60 1791.5 2.82673 ppb

I As 75 4337.2 9.76293 ppb

I Se 77 142.7 -6.66055 ppb

I Se 82 -333.7 -5.91395 ppb

I> Rh 103 108055.8 ppb

I Cd 111 133.9 0.20908 ppb

1- Cd 114 203.7 0.10599 ppb

1- Sb 121 1326.1 0.47621 ppb

I Sb 123 1045 0.48624 ppb

I> Ho 165 352530.1 ppb

1- Pb 208 52708.8 3.07819 ppb

Kr 83 1250 mg/L

ICP-Oata 14 of 20

elementOne

e 14503-Metals

62

26.14
PerkinElmer ELAN 6100 ICP-MS

97413.5 ppb

28467.6 43.7556 ppb

87580.8 ppb

158140.2 61.21907 ppb

19049 36.995 ppb

268936.7 64.76312 ppb

144987 49.10882 ppb

39304.5 64.95785 ppb

39845.2 88.19729 ppb

4128.3 93.65812 ppb

5287.7 100.64429 ppb

111521.4 ppb

33128.8 44.34772 ppb

79397.4 44.86271 ppb

130640.1 48.36126 ppb

100500.1 48.04733 ppb

355134.5 ppb

921264.7 54.14097 ppb

1010.3 mg/L

Meas. Intem Cone. Mear Report Unit

6

9

45

52

53

55

59

60

75

77

82

103

111

114

121

123

165

208

83

Method 6020 & 200.8 Metals Summary Report

Sample 10: 14503-3BH

Sample Da Wednesday. May 19. 2010 19:07:32

Sample De Air Nova

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

Li 6 98051 ppb

Be 9 16.3 -0.00338 ppb

Sc 45 86875.2 ppb

Cr 52 35113 12.37413 ppb

Cr 53 4833.6 -10.16634 ppb

Mn 55 63440.6 15.12955 ppb

Co 59 1057.7 0.33868 ppb

Ni 60 9633.8 15.7072 ppb

As 75 4776.1 10.39762 ppb

Se 77 126.3 -7.22312 ppb

Se 82 -488.6 -8.49632 ppb

Rh 103 111794.1 ppb

Cd 111 213.5 0.30955 ppb

Cd 114 407.4 0.21749 ppb

Sb 121 837.4 0.28933 ppb

Sb 123 665 0.29834 ppb

Ho 165 357840.9 ppb

Pb 208 70363.8 4.05887 ppb

Kr 83 1307.8 mg/L

Method 6020 & 200.8 Metals Summary Report

Sample 10: 14503-3BH

Sample DaWednesday. May 19, 2010 19:10:42

Sample De Air Nova

Concentration Results

Analyte Mass

Li

Be

Sc

Cr

Cr

Mn

Co

Ni

As

Se

Se

Rh

Cd

Cd

Sb

Sb

Ho

Pb

Kr

I>

II

I

I

I

I

I

I

I

I

I>

I

III

I>

1-

I>

II

I

I

I

I

I

I

I

I

I>

I

III

I>

1-

ICP-Data 15 of 20

elemenlOne

e 14503-Metals 26.15

63
PerkinElmer ELAN 6100 ICP-MS

85581.3 ppb

18.3 0.0037 ppb

10520.8 16.74125 ppb

104783.2 ppb

5964.3 0.70338 ppb

12486.6 12.97176 ppb

2491 0.4168 ppb

129 0.02203 ppb

197.7 0.06376 ppb

356.7 0.05583 ppb

787 0.7345 ppb

2186.9 3.52571 ppb

2257.6 12.89021 ppb

1843.9 3.61513 ppb

80.4 -0.03914 ppb

623.4 4.43498 ppb

-11.6 0.47091 ppb

118227 ppb

917.7 0.24834 ppb

871.7 0.23834 ppb

26.8 0.05712 ppb

51.3 0.01454 ppb

89.3 0.01535 ppb

72.9 0.01816 ppb

85.7 0.05799 ppb

142.3 0.06146 ppb

349493.5 ppb

402 0.01807 ppb

4810.2 0.24334 ppb

60.3 mg/L

Meas. Intem Cone. Mear Report Unit

69

31

45

52

53

55

59

60

63

65

66

67

68

75

77

82

103

107

109

111

114

121

123

135

137

165

205

208

83

Method 6020

& 200.8 Metals Summary Report

Sample 10: 14503-4BH

Sample DaWednesday, May 19, 2010 19:13:50

Sample De Air Nova

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

Li6 93995.3 ppb

Be9 29 0.01799 ppb

Sc 45 85941.1 ppb

Cr 52 11401.8 2.82616 ppb

Cr 53 1962.2 -19.88998 ppb

Mn 55 41745.7 9.55483 ppb

Co 59 958.4 0.29342 ppb

Ni 60 2397.3 3.58245 ppb

As 75 184.8 0.19045 ppb

Se 77 42.7 -9.36027 ppb

Se 82 -6.3 0.57217 ppb

Rh 103 115860.2 ppb

Cd 111 289.9 0.39785 ppb

Cd 114 601.1 0.31446 ppb

Sb 121 2748.7 0.98096 ppb

Sb 123 2148 0.99223 ppb

Ho 165 362005 ppb

Pb 208 118741.9 6.81148 ppb

Kr 83 -86.5 mg/L

Method 6020

& 200.8 Metals Summary Report

Sample 10: QC Std

1

Sample DaWednesday, May 19, 2010 19:32:39

Sample Description:

Concentration Results

Analyte Mass

Li

BeP

Sc

Cr

Cr

Mn

Co

Ni

Cu

Cu

Zn

Zn

Zn

As

Se

Se

Rh

Ag

Ag

Cd

Cd

Sb

Sb

Ba

Ba

Ho

TI

Pb

Kr

I>

I-IIIIIIII1

I>I

II-I

I>

1-

I>

II-IIIIIIIIIII1II

I>III

II-III

I>I

1-

ICP-Data 16 of 20

elementOne e 14503-Metals 26.16

64
PerkinElmer ELAN 6100 ICP-MS

73784.5 ppb

32 0.03695 ppb

12321.3 25.30332 ppb

90299.1 ppb

5814.2 0.56037 ppb

13899 15.63905 ppb

1402.1 0.15813 ppb

222 0.04919 ppb

289 0.18827 ppb

342.3 0.03813 ppb

739.7 0.62719 ppb

610.4 0.51136 ppb

2659.4 16.19763 ppb

829.7 0.82549 ppb

178.5 0.15402 ppb

634 4.1307 ppb

-4.2 0.60612 ppb

123071.8 ppb

2214.6 0.68772 ppb

2066.9 0.64715 ppb

42.9 0.07652 ppb

94.9 0.03589 ppb

165.7 0.04545 ppb

105.3 0.03479 ppb

71.7 0.04056 ppb

126.3 0.05052 ppb

344180.1 ppb

759.4 0.04859 ppb

1884.4 0.07005 ppb

61 mg/L

Meas. Intem Cone. Mear Report Unit

69

31

45

52

53

55

59

60

63

65

66

67

68

75

77

82

103

107

109

111

114

121

123

135

137

165

205

208

83

Method 6020

& 200.8 Metals Summary Report

Sample ID: QC Std

4

Sample DaWednesday, May 19, 2010 19:35:47

Sample Description:

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

Li6 82701.9 ppb

Be9 53283.8 96.37607 ppb

P 31 177949.8 1071.5858 ppb

Sc 45 101631.9 ppb

Cr 52 289104 103.07795 ppb

Cr 53 46284.7 113.79576 ppb

Mn 55 474786.7 104.35924 ppb

Co 59 330285.9 102.00845 ppb

Ni 60 67967.7 102.53166 ppb

Cu 63 157491.3 102.95845 ppb

Cu 65 76463.6 103.47032 ppb

Zn 66 55960.2 101.71572 ppb

Zn 67 11644.1 115.14598 ppb

Zn 68 40606.3 103.64479 ppb

As 75 51739.3 104.3963 ppb

Se 77 5075.8 106.37795 ppb

Se 82 6026.1 104.45798 ppb

Rh 103 122334.8 ppb

Ag 107 281591.9 98.00966 ppb

Ag 109 272568.1 95.96102 ppb

Cd 111 80422.4 98.12647 ppb

Cd 114 194779.8 100.36779 ppb

Sb 121 279954.1 103.15315 ppb

Sb 123 217871 103.7126 ppb

Ba 135 78980.4 106.81462 ppb

Ba 137 138228.6 105.79761 ppb

Ho 165 356838.4 ppb

TI 205 1295140.5 103.64488 ppb

Pb 208 1746535 102.16547 ppb

Kr 83 -4468.4 mg/L

Method 6020

&200.8 Metals Summary Report

Sample ID: QC Std

1

Sample Da Thursday, May 20,201008:45:42

Sample Description:

Concentration Results

Analyte Mass

Li

BeP

Sc

Cr

Cr

Mn

Co

Ni

Cu

Cu

Zn

Zn

Zn

As

Se

Se

Rh

Ag

Ag

Cd

Cd

Sb

Sb

Ba

Ba

Ho

TI

Pb

Kr

I>

II-IIIIIIIIIIIIII

I>III

II-III

I>I

1-

I>

II-IIIIIIIIIIIIII

I>III

II-III

I>I

1-

ICP-Data 17 of 20

elementOne e 14503-Metals 26.17

65
PerkinElmer ELAN 6100 ICP-MS

ppb

-0.00386 ppb

ppb

0.84082 ppb

2.09393 ppb

1.49108 ppb

0.04585 ppb

0.71626 ppb

1.87749 ppb

-0.65536 ppb

-3.7369 ppb

ppb

0.07146 ppb

0.02141 ppb

0.11607 ppb

0.13423 ppb

ppb

0.71898 ppb

mglL

77761.7

12.7

84246.2

5810.2

8270.4

6602.1

186.7

563.4

906.7

374.7

-226.9

108391.3

34.1

59.3

330.3

288.6

323203.5

11821

453.7

Meas. Intem Cone. Mear Report Unit

69

45

52

53

55

59

60

75

77

82

103

111

114

121

123

165

208

83

Method 6020

& 200.8 Metals Summary Report

Sample ID: QC Std

4

Sample DaThursday, May 20,201008:48:50

Sample Description:

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

Li6 74813.7 ppb

Be9 49881 99.97643 ppb

P 31 176149.2 1040.9585 ppb

Sc 45 91008.7 ppb

Cr 52 292205.4 102.40338 ppb

Cr 53 47339 114.54243 ppb

Mn 55 476226.1 102.83057 ppb

Co 59 334364 101.51229 ppb

Ni 60 69174.7 102.59352 ppb

Cu 63 161545.4 103.79731 ppb

Cu 65 78130.1 103.86103 ppb

Zn 66 54932.6 98.07071 ppb

Zn 67 11662.5 113.22955 ppb

Zn 68 40023 100.34484 ppb

As 75 51904 102.93013 ppb

Se 77 5008 102.75178 ppb

Se 82 5710.9 97.34033 ppb

Rh 103 124537.3 ppb

Ag 107 281225.8 96.21778 ppb

Ag 109 274928.5 95.10465 ppb

Cd 111 80623.7 96.61231 ppb

Cd 114 192923.8 97.66481 ppb

Sb 121 282361.3 107.06744 ppb

Sb 123 219969.3 107.83314 ppb

Ba 135 79817.9 111.13614 ppb

Ba 137 139648 109.92489 ppb

Ho 165 347170.3 ppb

TI 205 1278541.2 105.3474 ppb

Pb 208 1699215.3 102.28579 ppb

Kr 83 -4450.6 mglL

Method 6020

& 200.8 Metals Summary Report

Sample ID: 14503-3BH

Sample DaThursday, May 20,201009:00:52

Sample De Air Nova

Concentration Results

Analyte Mass

Li

Be

Sc

Cr

Cr

Mn

Co

Ni

As

Se

Se

Rh

Cd

Cd

Sb

Sb

Ho

Pb

Kr

I>

I-III1IIIII

I>I

II-I

I>

1-

I>

II-IIIIIII1IIIIII

I>III

II-I1I

I>I

1-

ICP-Data 18 of 20

elementOne e 14503-Metals 26.18

66
PerkinElmer ELAN 6100 ICP-MS

81243.3 ppb

31.3 0.02911 ppb

11646.8 23.2417 ppb

89230.3 ppb

5661.8 0.56191 ppb

10948.6 7.67031 ppb

1245.1 0.13171 ppb

248.7 0.05975 ppb

275.3 0.18162 ppb

327.7 0.03494 ppb

1091.7 1.15154ppb

615.4 0.55528 ppb

2100.9 10.68095 ppb

706 0.55337 ppb

60.9 -0.07816 ppb

484.7 1.01789 ppb

-14.7 0.4231 ppb

119628.7 ppb

2475.4 0.8115 ppb

2324 0.76764 ppb

60.8 0.10091 ppb

105.1 0.04309 ppb

168 0.04498 ppb

137.8 0.04938 ppb

83.3 0.05494 ppb

120.3 0.04396 ppb

349264 ppb

807.7 0.05135 ppb

1911.4 0.06939 ppb

80.4 mg/L

Meas. Intem Cone. Mear Report Unit

69

31

45

52

53

55

59

60

63

65

66

67

68

75

77

82

103

107

109

111

114

121

123

135

137

165

205

208

83

Method 6020& 200.8 Metals Summary Report

Sample ID: 14503-3BH

Sample Da Thursday, May 20, 2010 09:04:00

Sample De Air Nova

Concentration Results

Analyte Mass Meas. Intem Cone. Mear Report Unit

Li6 82995 ppb

Be9 25660.6 46.29505 ppb

Sc 45 89084.1 ppb

Cr 52 132629.6 50.71513 ppb

Cr 53 22662.2 48.43425 ppb

Mn 55 219040.6 52.28468 ppb

Co 59 146609.1 49.29432 ppb

Ni 60 31299.2 51.31491 ppb

As 75 27488.7 60.32126 ppb

Se 77 3038.5 65.69163 ppb

Se 82 3444.9 65.32303 ppb

Rh 103 112423.8 ppb

Cd 111 35386.6 46.97424 ppb

Cd 114 86634 48.57609 ppb

Sb 121 132238.2 50.89324 ppb

Sb 123 102306.6 50.87754 ppb

Ho 165 341636.5 ppb

Pb 208 853654.8 52.16478 ppb

Kr 83 455.1 mg/L

Method 6020

& 200.8 Metals Summary Report

Sample ID: QC Std

1

Sample DaThursday, May 20,201009:07:08

Sample Description:

Concentration Results

Analyte Mass

Li

BeP

Sc

Cr

Cr

Mn

Co

Ni

Cu

Cu

Zn

Zn

Zn

As

Se

Se

Rh

Ag

Ag

Cd

Cd

Sb

Sb

Ba

Ba

Ho

TI

Pb

Kr

I>

II-IIIIIIIIIIIIII

I>III

II-III

I>I

1-

I>

I-IIIIIIIII

I>I

II-I

I>

1-

ICP-Data 19 of 20

elementOne e 14503-Metals 26.19

67
PerkinElmer ELAN 6100 ICP-MS

Meas. Intem Cone. Mear Report Unit

6 79322 ppb

9 52508.6 99.04208 ppb

31 173079.2 1062.2468 ppb

45 89519.6 ppb

52 284897.8 103.547 ppb

53 43961.9 109.23646 ppb

55 464626.2 104.02705 ppb

59 326606.6 102.87012 ppb

60 67546.6 103.90722 ppb

63 156085 104.00869 ppb

65 75796.6 104.44811 ppb

66 54416.2 100.75639 ppb

67 11227.6 113.03448 ppb

68 39805.4 103.58835 ppb

75 51006 104.94573 ppb

77 4809.9 102.38109 ppb

82 5721.6 101.21468 ppb

103 120161.1 ppb

107 276662.8 98.20815 ppb

109 266812.9 95.68106 ppb

111 78901.6 98.01994 ppb

114 190047.5 99.85866 ppb

121 278452.3 105.22629 ppb

123 213964.8 104.48701 ppb

135 77949.8 108.13731 ppb

137 136706.5 107.31814 ppb

165 348025 ppb

205 1267245 104.00064 ppb

208 1717143.6 103.0175 ppb

83 -4363.1 mg/L

Method 6020 & 200.8 Metals Summary Report

Sample 10: QC Std 4

Sample Oa Thursday, May 20,201009:10:16

Sample Description:

Concentration Results

Analyte Mass

Li

Be

P

Sc

Cr

Cr

Mn

Co

Ni

Cu

Cu

Zn

Zn

Zn

As

Se

Se

Rh

Ag

Ag

Cd

Cd

Sb

Sb

Ba

Ba

Ho

TI

Pb

Kr

I>

III

I

I

I

I

I

I

I

I

I

I

I

I

I

I>

I

I

I

III

I

I

I>

I

1-

ICP-Oata 20 of 20

elementOne

e 14503-Metals 26.20

68
PerkinElmer FIMS-100 CVAA Mercury Analyzer

Sample_1D Date Time Mean_Sig Mean_Rd Mean_Rt Units Alq. Vol. Sig 1 Reading-1 Result-1 Sig 2 Reading-2 Result-2

Calib Blank 5/20/2010 12:49:03 0.0005393 ~g 0.0005393

STD1=.004ug 5/20/2010 12:50:18 0.0009945 ~g 0.0009945

STD2=.04ug 5/20/2010 12:51:34 0.0103547 ~g 0.0103547

STD3=.08ug 5/20/2010 12:52:51 0.0212455 ~g 0.0212455

STD4=.16ug 5/20/2010 12:54:09 0.040403 ~g 0.040403

STD5=.2ug 5/20/2010 12:55:29 0.05327 ~g 0.05327

Reagent Blank 5/20/2010 12:57:17 -0.0000645 -0.000247 -0.000247 ~g -0.0000423 -0.0001619 -0.0001619 -0.0000868 -0.0003321 -0.0003321

0.004ug = DL 5/20/2010 12:58:31 0.0010321 0.0039473 0.0039473 ~g 0.0010321 0.0039473 0.0039473

0.080ug = STD.2 5/20/2010 12:59:48 0.0205794 0.0787071 0.0787071 ~g 0.0205794 0.0787071 0.0787071

0.080ug = QC STD 3 5/20/2010 13:01:08 0.020962 0.0801703 0.0801703 ~g 0.020962 0.0801703 0.0801703

REAGENT BLANK 5/20/2010 13:02:25 -0.0000379 -0.0001451 -0.0001451 ~g -0.0000379 -0.0001451 -0.0001451

0.004ug = DL 5/20/2010 14:08:48 0.0009773 0.0037377 0.0037377 ~g 4 400 0.0009773 0.0037377 0.0037377

0.080ug = STD.2 5/20/2010 14:10:05 0.0201466 0.0770518 0.0770518 ~g 4 400 0.0201466 0.0770518 0.0770518

REAGENT BLANK 5/20/2010 14:11:22 -0.0000508 -0.0001946 -0.0001946 ~g 4 400 -0.0000508 -0.0001946 -0.0001946

14502/503-lrb 5/2012010 14:19:46 6.507E-05 0.0002489 0.0062222 ~g 4 100 7.327E-05 0.0002802 0.0070059 5.688E-05 0.0002175 0.0054386

14502/503-lrb spk 5/2012010 14:21:35 0.0169244 0.0647283 1.6182072 ~g 4 100 0.0169868 0.0649669 1.6241714 0.016862 0.0644897 1.6122429

0.004ug = DL 5/20/2010 14:32:00 0.0010226 0.0039111 0.0039111 ~g 4 100 0.0010226 0.0039111 0.0039111

0.080ug = STD.2 5/20/2010 14:33:17 0.0205434 0.0785695 0.0785695 ~g 4 100 0.0205434 0.0785695 0.0785695

REAGENT BLANK 5/20/2010 14:34:34 -0.0000987 -0.0003776 -0.0003776 ~g 4 100 -0.0000987 -0.0003776 -0.0003776

14503-1a 5/20/2010 14:53:44 9.607E-05 0.0003675 0.0183726 ~g 4 200 8.205E-05 0.0003138 0.0156918 0.0001101 0.0004211 0.0210534

14503-2a 5/20/2010 14:55:31 1.477E-05 5.651E-05 0.0028259 ~g 4 200 1.083E-05 4.144E-05 0.0020721 1.871E-05 7.159E-05 0.0035797

14503-2a dup 5/20/2010 14:57:19 0.0001526 0.0005838 0.0291898 ~g 4 200 0.0001449 0.000554 0.0277002 0.0001604 0.0006136 0.0306794

14503-3a 5/20/2010 14:59:07 6.245E-05 0.0002389 0.0119428 ~g 4 200 4.575E-05 0.000175 0.0087494 7.915E-05 0.0003027 0.0151362

14503-3a spk 5/20/2010 15:00:55 0.0209637 0.0801767 4.0088354 ~g 4 200 0.0208632 0.0797927 3.9896339 0.0210641 0.0805607 4.0280368

0.004ug = DL 5/20/2010 15:02:10 0.0009947 0.0038044 0.0038044 ~g 4 200 0.0009947 0.0038044 0.0038044

0.080ug = STD.2 5/20/2010 15:03:27 0.0204693 0.078286 0.078286 ~g 4 200 0.0204693 0.078286 0.078286

REAGENT BLANK 5/20/2010 15:04:43 -0.0000042 -0.0000162 -0.0000162 ~g 4 200 -0.0000042 -0.0000162 -0.0000162

14503-4a 5/20/2010 15:06:30 0.0001449 0.0005541 0.027707 ~g 4 200 0.0001543 0.0005901 0.0295035 0.0001355 0.0005182 0.0259105

14503-1b 5/20/2010 15:08:20 0.000218 0.0008339 0.1042363 ~g 4 500 0.0002123 0.000812 0.101497 0.0002238 0.0008558 0.1069757

14503-2b 5/20/2010 15:10:10 0.0001219 0.0004662 0.0582698 ~g 4 500 0.00013 0.0004971 0.0621368 0.0001138 0.0004352 0.0544028

14503-2b dup 5/20/2010 15:12:01 9.488E-05 0.0003629 0.0453595 ~g 4 500 9.847E-05 0.0003766 0.0470789 9.128E-05 0.0003491 0.0436401

14503-3b 5/20/2010 15:13:49 0.0000628 0.0002402 0.0300233 ~g 4 500 8.445E-05 0.000323 0.0403745 4.114E-05 0.0001574 0.0196721

14503-3b spk 5/20/2010 15:15:33 0.0195932 0.0749354 9.3669217 ~g 4 500 0.0194908 0.0745438 9.3179692 0.0196956 0.075327 9.4158742

14503-4b 5/20/2010 15:17:17 2.465E-05 9.429E-05 0.0117873 ~g 4 500 2.355E-05 0.0000901 0.0112625 2.575E-05 9.849E-05 0.0123121

14503-1c 5/20/2010 15:19:02 0.0001321 0.0005053 0.0505314 ~g 4 400 0.0001174 0.0004491 0.0449105 0.0001468 0.0005615 0.0561523

14503-2c 5/20/2010 15:20:48 0.0002349 0.0008982 0.0898235 ~g 4 400 0.0002368 0.0009058 0.0905828 0.0002329 0.0008906 0.0890642

14503-2c dup 5/20/2010 15:22:34 0.0007937 0.0030355 0.3035483 ~g 4 400 0.0008089 0.0030938 0.3093828 0.0007784 0.0029771 0.2977137

0.004ug = DL 5/20/2010 15:23:48 0.0009942 0.0038023 0.0038023 ~g 4 400 0.0009942 0.0038023 0.0038023

0.080ug = STD.2 5/20/2010 15:25:05 0.0204261 0.0781206 0.0781206 ~g 4 400 0.0204261 0.0781206 0.0781206

REAGENT BLANK 5/20/2010 15:26:22 -0.0000159 -0.0000611 -0.0000611 ~g 4 400 -0.0000159 -0.0000611 -0.0000611

14503-3c 5/20/2010 15:28:08 0.0001928 0.0007373 0.0737255 ~g 4 400 0.0001948 0.0007449 0.0744911 0.0001908 0.0007296 0.0729599

14503-3c spk 5/20/2010 15:29:54 0.0196252 0.0750577 7.5057671 ~g 4 400 0.0195709 0.07485 7.484997 0.0196795 0.0752654 7.5265373

14503-4c 5/20/2010 15:31:41 0.000104 0.0003976 0.0397575 ~g 4 400 8.583E-05 0.0003283 0.032827 0.0001221 0.0004669 0.0466879

14503-1fh 5/20/2010 15:33:29 7.559E-05 0.0002891 0.0072281 ~g 4 100 7.524E-05 0.0002878 0.0071946 7.594E-05 0.0002905 0.0072616

14503-2fh 5/20/2010 15:35:17 0.0001953 0.0007468 0.01867 I-Ig 4 100 0.0001984 0.0007587 0.0189674 0.0001922 0.0007349 0.0183726

14503-2fh dup 5/20/2010 15:37:06 0.0001099 0.0004201 0.0105034 I-Ig 4 100 0.0001087 0.0004158 0.0103959 0.000111 0.0004244 0.0106108

14503-3fh 5/20/2010 15:38:55 0.0002403 0.0009191 0.022978 I-Ig 4 100 0.0002347 0.0008977 0.0224423 0.0002459 0.0009406 0.0235138

14503-3fh spk 5/20/2010 15:40:45 0.0212197 0.0811559 2.0288983 ~g 4 100 0.0211543 0.0809057 2.0226432 0.0212851 0.0814061 2.0351535

14503-4fh 5/20/2010 15:42:35 -0.0000946 -0.000362 -0.0090502 I-Ig 4 100 -0.0000983 -0.0003759 -0.0093992 -0.000091 -0.000348 -0.0087012

14503-1bh 5/20/2010 15:44:22 0.0005958 0.0022785 0.2905075 I-Ig 4 510 0.0006005 0.0022967 0.2928275 0.000591 0.0022603 0.2881875

0.004ug = DL 5/20/2010 15:45:35 0.0010577 0.0040452 0.0040452 I-Ig 4 510 0.0010577 0.0040452 0.0040452

0.080ug = STD.2 5/20/2010 15:46:52 0.0204345 0.078153 0.078153 I-Ig 4 510 0.0204345 0.078153 0.078153

REAGENT BLANK 5/20/2010 15:48:09 -0.0000078 -0.0000298 -0.0000298 I-Ig 4 510 -0.0000078 -0.0000298 -0.0000298

14503-2bh 5/20/2010 15:49:54 0.0001802 0.0006892 0.0861501 ~g 4 500 0.000173 0.0006616 0.0826952 0.0001874 0.0007168 0.0896051

14503-2bh dup 5/20/2010 15:51:39 0.0001695 0.0006484 0.0810535 I-Ig 4 500 0.0001722 0.0006585 0.0823132 0.0001669 0.0006384 0.0797938

14503-3bh 5/20/2010 15:53:24 0.0001923 0.0007354 0.0919217 I-Ig 4 500 0.0001559 0.0005964 0.0745473 0.0002286 0.0008744 0.1092961

14503-3bh spk 5/20/2010 15:55:10 0.0211068 0.0807243 10.09054 I-Ig 4 500 0.020789 0.0795087 9.9385904 0.0214247 0.0819399 10.24249

14503-4bh 5/20/2010 15:56:56 9.07E-06 0.0000347 0.0026894 ~g 4 310 -0.0000262 -0.0001002 -0.0077704 4.436E-05 0.0001697 0.0131493

0.004ug = DL 5/20/2010 15:59:57 0.000966 0.0036944 0.0036944 I-Ig 5 1000 0.000966 0.0036944 0.0036944

0.080ug = QC STD 3 5/20/2010 16:01:14 0.020007 0.0765177 0.0765177 ~g 5 1000 0.020007 0.0765177 0.0765177

REAGENT BLANK 5/20/2010 16:02:31 5.35E-06 2.048E-05 2.048E-05 I-Ig 5 1000 5.35E-06 2.048E-05 2.048E-05

Hg-Data 1 of 1

elementOne

e 64~03-Hg 27.1

Appendix C

Emission Calculations

James River Cogeneration Company

Hopewell, Virginia

Project No. 3338

May 7,2010

Unit No.2

Run No.1

Coal Analysis for F Factor Calculation

F FACTOR CALCULATION

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

% H=

%C=

%N=

%0=

%S=

GCV=

5.81

70.18

1.44

12.44

0.89

13572

Hydrogen Content (%)

Carbon Content (%)

Nitrogen Content (%)

Oxygen Content (%)

Sulfur Content (%)

Gross Calorific Value (Btu/lb)

Fd = 10A6 * [(3.64*%H) + (1.53*%C) + (0.57*%S) + (0.14*%N) - (0.46*%02)] I GCV

Fd = 9100 scf/MMBtu

1
James River Cogeneration Company

Hopewell, Virginia

Project No. 3338

May 7,2010

Unit No.2

Run No.2

Coal Analysis for F Factor Calculation

F FACTOR CALCULATION

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

% H=

%C=

% N=

%0=

%S=

GCV=

5.83

70.25

1.46

12.14

0.9

13528

Hydrogen Content (%)

Carbon Content (%)

Nitrogen Content (%)

Oxygen Content (%)

Sulfur Content (%)

Gross Calorific Value (Btu/Ib)

Fd = 10A6 * [(3.64*%H) + (1.53*%C) + (0.57*%S) + (0.14*%N) - (0.46*%02)] / GCV

Fd = 9154 scf/MMBtu

2
James River Cogeneration Company

Hopewell, Virginia

Project No. 3338

May 7,2010

Unit No.2

Run No.3

Coal Analysis for F Factor Calculation

F FACTOR CALCULATION

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

%H=

%C=

%N=

%0=

%S=

GCV=

5.61

67.92

1.36

14.02

0.85

13409

Hydrogen Content (%)

Carbon Content (%)

Nitrogen Content (%)

Oxygen Content (%)

Sulfur Content (%)

Gross Calorific Value (Btu/lb)

Fd = 101\6 * [(3.64*%H) + (1.53*%C) + (0.57*%S) + (0.14*%N) - (0.46*%02)] / GCV

Fd = 8842 scf/MMBtu

3
M7E

Client

Project No.

Test Location

Test Date

James River Cogen

3338

Unit 2

05/07/10 Metals/PM-10

AirNova, Inc.

EPA Method 6C Calculations

(Cal. Error, Bias Drift and Bias Adjustment)

Page 1

Actual Calibration Gas Value (% 02):

Analyzer Calibration Response (% 02):

Analyzer Calibration Error (% Span):

Parameter:

Instrument Span (% 02):

Oxygen

22.03 Analvzer Calib. Gases Upscale

zero low mid high Sys. Cal. Gas

0.00 N/A 12.47 22.03 12.47

0.01 N/A 12.43 21.89 12.47

0.05 0.00 -0.18 -0.64

Zero System Calibration Gas Upscale System Calibration Gas

Apparent Init. Sys. Init. Sys. Final Sys. Final Sys. Calib. Init. Sys. Init. Sys. Final Sys. Final Sys. Calib. Actual

ll» Stack Calib. Cal. Bias Calib. Cal. Bias Drift Calib. Cal. Bias Calib. Cal. Bias Drift Stack

Run Cone. Response (% span) Response (% span) (% span) Response (% span) Response (% span) (% span) Cone.

1 5.55 0.11 0.45 0.05 0.18 -0.27 12.51 0.18 12.50 0.14 -0.05 5.49

2 5.67 0.05 0.18 0.10 0.41 0.23 12.50 0.14 12.34 -0.59 -0.73 5.65

3 5.51 0.10 0.41 0.09 0.36 -0.05 12.34 -0.59 12.45 -0.09 0.50 5.49

4 0.00 0.09 0.36 0.00 -0.05 -0.41 12.45 -0.09 0.00 -56.60 -56.51 -0.09

5 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR

6 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR

7 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR

8 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR

9 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR

10 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR

11 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR

12 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR
M7E

Client

Project No.

Test Location

Test Date

James River Cogen

3338

Unit 2

05/07/10

AirNova, Inc.

EPA Method 6C Calculations

(Cal. Error, Bias Drift and Bias Adjustment)

Page 2

Actual Calibration Gas Value (% C02):

Analyzer Calibration Response (% C02):

Analvzer Calibration Error (% Span):

Parameter:

Instrument Span (% C02):

Carbon Dioxide

22.28 Analyzer Calib. Gases Upscale

zero low mid high Sys. Cal. Gas

0.00 N/A 12.38 22.28 12.38

0.00 N/A 12.33 22.34 12.38

0.00 0.00 -0.22 0.27

Zero System Calibration Gas Upscale System Calibration Gas

Apparent Init. Sys. Init. Sys. Final Sys. Final Sys. Calib. Init. Sys. Init. Sys. Final Sys. Final Sys. Calib. Actual

U1 Stack Calib. Cal. Bias Calib. Cal. Bias Drift Calib. Cal. Bias Calib. Cal. Bias Drift Stack

Run Cone. Response (% span) Response (% span) (% span) Response (% span) Response (% span) (% span) Cone.

1 13.73 0.00 0.10 0.00 0.00 0.00 12.45 0.31 12.45 0.31 0.00 13.65

2 13.54 0.00 0.00 0.00 0.00 0.00 12.45 0.31 12.33 -0.22 -0.54 13.53

3 13.63 0.00 0.00 0.12 0.54 0.54 12.33 -0.22 12.45 0.31 0.54 13.63

4 0.00 0.12 0.54 0.00 0.00 -0.54 12.45 0.31 0.00 -55.57 -55.88 -0.12

5 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR

6 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR

7 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR

8 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR

9 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR

10 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR

11 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR

12 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR
3338-EPA5-202-R1 AirNova, Inc.

EPA Methods 1,2,3A,4,5 and 202

(Flows, 02/C02, H20, Total Suspended Particulate and Back Half PM)

Client James River Cogeneration Company

Project No. 3338

Test Location Hopewell, Virginia

Emission Source Unit NO.2

Fuel Coal

Test Date 05/07/10

Test Run One

Time Period 0715-0930

Emission Data Data from:

INPUT Vlc= 219.7 cc Vol. of H20 collected EPA 4

INPUT Vm= 88.534 dcf Dry gas meter reading EPA 4

INPUT Pstatic = 0.55 in. H2O Static pressure EPA 2

INPUT Pb= 29.98 in. Hg Barometric pressure

Ps= 30.02 in. Hg Stack pressure EPA 2

Pstd = 29.92 in. Hg EPA Standard pressure

dP= 0.800 in. H20 A.5 Average sq.rt delta P EPA 2

dH= 1.67 in. H2O Average draft gauge reading EPA 4

Tm= 538.7 R Average meter temperature EPA 4

Ts= 669.8 R Average stack temperature EPA 2

INPUT Tstd= 527.7 R Standard temperature

INPUT y= 1.00 Meter calibration factor

INPUT t= 120 min. Duration of sampling time

INPUT Dn= 0.250 in. Nozzle diameter

INPUT An= 0.000341 sq. ft. Nozzle area

INPUT Os = 9.667 ft. Diameter of stack

As= 73.39 sq. ft. Cross sectional area of stack

INPUT Cp= 0.84 Pitot tube coefficient EPA2

Kp= 85.49 ft[(lbllbmol)*(inHg»)A.5}/[s*R*inH20] Pitot tube constant

K1 = 7.637 R/in.Hg constant

K2= 0.047070 cU.ftIml constant

K3= 0.0026688 in.Hg-cf/ml-R constant

Molar vol air= 385.0 scfllb-mol constant @ 68 deg F

Fd = 9100 scf/MMBtu Fuel Factor

EPA Method 3A Instrumental Data

INPUT EPA3

INPUT EPA3

[02]

[C02]

[N2]

5.49 %-dry

13.65 %-dry

80.86 %-dry

6

Oxygen concentration

Carbon Dioxide concentration

Nitrogen concentration
Client

Project No.

James River Cogeneration Com Emission Source

3338 Test Run

Calculations

Unit No.2

One

Page 2

1) Volume of gas sampled at standard conditions, Vmstd.

Vmstd =K1* Y * Vm * (Pb + dH/13.6) / Tm

Vmstd = 87.255 dsef

2.471 dsem

2) Volume of water vapor collected at standard conditions, Vw(std).

Vw(std) = K2 * Vic

Vw(std) = 10.341 sef

3) Decimal fraction of moisture by volume in stack gas, Bws.

Bws = Vwstd / (Vmstd+Vwstd)

Bws = 0.1060

4) Molecular weight of the stack gas on a wet basis, Ms.

Ms = [«44*%C02) + (32*%02) + (28*%N2)) * (1-Bws)] + (18*Bws)

Ms = 29.089 Ib/lbmole

5) Average stack gas velocity, Vs.

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)".5

Vs = 50.289 fps

6) Average actual stack gas volumetric flowratej Qa.

Qa = 60 sec/min * Vs * As

Qa = 221456.33 efm

6271.64 emm

7) Average stack gas dry volumetric flowrate, Qstd.

Qstd = Qa * (TstdITs) * (Ps/Pstd) * (1-Bws)

Qstd = 156514.21 dsefm

Qstd = 4432.48 dsemm

7
Client

Project No.

James River Cogeneration Com Emission Source

3338 Test Run

Calculations (cont.)

Unit NO.2

One

Page 3

8) Particulate Matter Analytical Data

INPUT A 0.0040 9 Filter sample net wt

INPUT B 200 ml Front acetone wash vol.

INPUT C 0.0038 9 Front acetone residue wt.

INPUT D 200 ml Acetone blank vol.

INPUT E 0.0000 9 Acetone blank residue wt.

9) Particulate sample mass calculations

H

I

J

Front Half:

Acetone blank adj. residue wt

Adj. Acetone wash part.wt.

Front half sample wt.

0.0000 9

0.0038 9

0.0078 9

E*(B/D)

C-H

A+I

10) Total Suspended Particulate Matter Emission Data

C[TSP] (grains/dscf) = (Front Half Wt)(g) * (1Nmstd) * 15.43(grains/g)

C[TSP] (Ib/dscf) = C[TSP] (grains/dscf) * (1 Ib/7000 grains)

E[TSP] (lb/MMBtu) = C[TSP] (Ib/dscf) * Fd * (20.9/(20.9-02»

E[TSP] (Ib/hr) = C[TSP] * Vdscfm * A * (60 min/hr) * (1 Ib 17000 graim

C[TSP] = 1.38E-03 grains/dscf

C[TSP] = 1.97E-07 Ib/dscf

E[TSP] = 0.0024 Ib/MMBtu

E[TSP] = 1.850 Ib/hr

11) Back Half Organic Particulate Analysis

C[BHOPM] (grains/dscf) = (Organic Mass Wt)(g) * (1Nmstd) * 15.43(grains/g)

C[BHOPM] (Ib/dscf) = C[BHOPM] (grains/dscf) * (1 Ib/7000 grains)

E[BHOPM] (Ib/MMBtu) = C[BHOPM] (Ib/dscf) * Fd * (20.9/(20.9-02»

E[BHOPM] (Ib/hr) = C[BHOPM] * Vdscfm * A * (60 min/hr) * (1 Ib 17000 grains)

BHOPM Mass = 0.0000 9

C[BHOPM]= O.OOE+OO grains/dscf

C[BHOPM]= O.OOE+OO Ib/dscf

E[BHOPM]= 0.0000 Ib/MMBtu

E[BHOPM]= 0.000 Ib/hr

% BHOPM 0.0

8
Client

Project No.

James River Cogeneration Com Emission Source

3338 Test Run

Calculations (cont.)

Unit NO.2

One

Page 4

12) Back Half Inorganic Particulate Analysis

C[BHIPM] (grains/dscf) = (Inorganic Mass Wt)(g) * (1Nmstd) * 15.43(grains/g)

C[BHIPM] (Ib/dscf) = C[BHIPM] (grains/dscf) * (1 Ib/7000 grains)

E[BHIPM] (Ib/MMBtu) = C[BHIPM] (Ib/dscf) * Fd * (20.9/(20.9-02»

E[BHIPM] (Ib/hr) = C[BHIPM] * Vdscfm * A * (60 min/hr) * (1 Ib 17000 grains)

BHIPM Mass = 0.0045 9

C[BHIPMj= 7.96E-04 grains/dscf

C[BHIPMj= 1.14E-07 Ib/dscf

E[BHIPMj= 0.0014 Ib/MMBtu

E[BHIPM]= 1.068 Ib/hr

% BHIPM 36.6

13) Total Back Half Particulate Matter

C[TBHPMj (grains/dscf) = (C[BHOPMj (grains/dscf) + (C[BHIPM] (grains/dscf)

C[TBHPM] (Ib/dscf) = (C[BHOPM] (Ib/dscf) + (C[BHIPMj (Ib/dscf)

E[TBHPMj (lb/MMBtu) = (E[BHOPM] (lb/MMBtu» + (E[BHIPM] (lb/MMBtu»

E[TBHPMj (Ib/hr) = C[TBHPM] * Vdscfm * A * (60 min/hr) * (1 Ib 17000 grains)

Blank Mass = 0.0000 9

TBHPM Mass = 0.0045 9

C[TBHPMj= 7.96E-04 grains/dscf

C[TBHPM]= 1.14E-07 Ib/dscf

E[TBHPMj= 0.0014 Ib/MMBtu

E[TBHPM]= 1.068 Ib/hr

% TBHPM 36.6

14) Total Particulate Matter < 10 Microns Emission Data

C[TPM10j (grains/dscf) = (C[TSP] (grains/dscf) + (C[TBHPM] (grains/dscf)

C[TPM10] (Ib/dscf) = (C[TSP] (Ib/dscf) + (C[TBHPMj (Ib/dscf)

E[TPM10] (lb/MMBtu) = (E[TSP] (Ib/MMBtu» + (E[TBHPM] (lb/MMBtu»

E[TPM10] (Ib/hr) = C[TPM10] * Vdscfm * A * (60 min/hr) * (1 Ib 17000 grains)

C[TPM10] = 2.18E-03 grains/dscf

C[TPM10j = 3.11 E-07 Ib/dscf

E[TPM10] = 0.0038 Ib/MMBtu

E[TPM10] = 2.918 Ib/hr

15) Isokinecity, I.

% I = [1 00*Ts*(K3*Vlc+«(Vm*Y)/Tm)*(Pb+(dH/13.6))))] 1(60*t*Ps*Vs*An)

% 1= 100.03

9
3338-EPA5-202-R2 AirNova, Inc.

EPA Methods 1,2,3A,4,5 and 202

(Flows, 02/C02, H20, Total Suspended Particulate and Back Half PM)

Client James River Cogeneration Company

Project No. 3338

Test Location Hopewell, Virginia

Emission Source Unit NO.2

Fuel Coal

Test Date 05/07/10

Test Run Two

Time Period 0952-1203

Emission Data Data from:

INPUT Vlc= 217.9 cc Vol. of H20 collected EPA4

INPUT Vm= 91.242 dcf Dry gas meter reading EPA4

INPUT Pstatic = 0.55 in. H2O Static pressure EPA 2

INPUT Pb= 30.02 in. Hg Barometric pressure

Ps = 30.06 in. Hg Stack pressure EPA 2

Pstd = 29.92 in. Hg EPA Standard pressure

dP = 0.810 in. H20 1\.5 Average sq.rt delta P EPA 2

dH = 1.76 in. H2O Average draft gauge reading EPA4

Tm= 549.0 R Average meter temperature EPA 4

Ts= 672.5 R Average stack temperature EPA2

INPUT Tstd= 527.7 R Standard temperature

INPUT y= 1.00 Meter calibration factor

INPUT t= 120 min. Duration of sampling time

INPUT Dn = 0.250 in. Nozzle diameter

INPUT An= 0.000341 sq. ft. Nozzle area

INPUT Ds= 9.667 ft. Diameter of stack

As= 73.39 sq. ft. Cross sectional area of stack

INPUT Cp= 0.84 Pitot tube coefficient EPA2

Kp= 85.49 ft[(lb/lbmol)*(inHg)]A.5}/[s*R*inH20] Pitot tube constant

K1 = 17.637 R/in.Hg constant

K2 = 0.047070 cu.ftIml constant

K3 = 0.0026688 in.Hg-cf/ml-R constant

Molar vol air= 385.0 scf/lb-mol constant @ 68 deg F

Fd = 9154 scf/MMBtu Fuel Factor

EPA Method 3A Instrumental Data

INPUT EPA3

INPUT EPA3

[02]

[C02]

[N2]

5.65 %-dry

13.53 %-dry

80.82 %-dry

10

Oxygen concentration

Carbon Dioxide concentration

Nitrogen concentration
Client

Project No.

James River Cogeneration Com Emission Source

3338 Test Run

Calculations

Unit NO.2

Two

Page 2

1) Volume of gas sampled at standard conditions, Vmstd.

Vmstd =K1 * Y * Vm * (Pb + dH/13.6) / Tm

Vmstd = 88.382 dscf

2.503 dscm

2) Volume of water vapor collected at standard conditions, Vw(std).

Vw(std) = K2 * Vic

Vw(std) = 10.257 sef

3) Decimal fraction of moisture by volume in stack gas, Bws.

Bws = Vwstd / (Vmstd+Vwstd)

Bws = 0.1040

4) Molecular weight of the stack gas on a wet basis, Ms.

Ms = [«44*%C02) + (32*%02) + (28*%N2)) * (1-Bws) 1+ (18*Bws)

Ms = 29.102 Ib/lbmole

5) Average stack gas velocity, Vs.

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)A.5

Vs = 50.987 fps

6) Average actual stack gas volumetric flowrate, Qa.

Qa = 60 sec/min * Vs * As

Qa = 224528.65 efm

6358.65 emm

7) Average stack gas dry volumetric flowrate, Qstd.

Qstd = Qa * (TstdlTs) * (Ps/Pstd) * (1-Bws)

Qstd = 158617.05 dsefm

Qstd = 4492.03 dsemm

11
Client

Project No.

James River Cogeneration Com Emission Source

3338 Test Run

Calculations (cont.)

Unit NO.2

Two

Page 3

8) Particulate Matter Analytical Data

INPUT A 0.0045 9 Filter sample net wt

INPUT B 200 ml Front acetone wash vol.

INPUT C 0.0027 9 Front acetone residue wt.

INPUT D 200 ml Acetone blank vol.

INPUT E 0.0000 9 Acetone blank residue wt.

9) Particulate sample mass calculations

H

I

J

Front Half:

Acetone blank adj. residue wt

Adj. Acetone wash part.wt.

Front half sample wt.

0.0000 9

0.0027 9

0.0072 9

E*(B/D)

C-H

A+I

10) Total Suspended Particulate Matter Emission Data

C[TSP] (grains/dscf) = (Front Half Wt)(g) * (1 Nmstd) * 15.43(grains/g)

C[TSP] (Ib/dscf) = C[TSP] (grains/dscf) * (1 Ib/7000 grains)

E[TSP] (lb/MMBtu) = C[TSP] (Ib/dscf) * Fd * (20.9/(20.9-02))

E[TSP] (Ib/hr) = C[TSP] * Vdscfm * A * (60 min/hr) * (1 Ib I 7000 graim

C[TSP] = 1.26E-03 grains/dscf

C[TSP] = 1.80E-07 Ib/dscf

E[TSP] = 0.0023 Ib/MMBtu

E[TSP] = 1.709 Ib/hr

11) Back Half Organic Particulate Analysis

C[BHOPM] (grains/dscf) = (Organic Mass Wt)(g) * (1 Nmstd) * 15.43(grains/g)

C[BHOPM] (Ib/dscf) = C[BHOPM] (grains/dscf) * (1 Ib/7000 grains)

E[BHOPM] (lb/MMBtu) = C[BHOPM] (Ib/dscf) * Fd * (20.9/(20.9-02))

E[BHOPM] (Ib/hr) = C[BHOPM] * Vdscfm * A * (60 min/hr) * (1 Ib 17000 grains)

BHOPM Mass = 0.0000 9

C[BHOPM]= O.OOE+OO grains/dscf

C[BHOPM]= O.OOE+OO Ib/dscf

E[BHOPM]= 0.0000 Ib/MMBtu

E[BHOPM]= 0.000 Ib/hr

% BHOPM 0.0

12
Client

Project No.

James River Cogeneration Com Emission Source

3338 Test Run

Calculations (cont.)

Unit NO.2

Two

Page 4

12) Back Half Inorganic Particulate Analysis

C[BHIPM] (grains/dscf) = (Inorganic Mass Wt)(g) * (1Nmstd) * 15.43(grains/g)

C[BHIPM] (Ib/dscf) = C[BHIPMj (grains/dscf) * (1 Ib/7000 grains)

E[BHIPM] (lb/MMBtu) = C[BHIPM] (Ib/dscf) * Fd * (20.9/(20.9-02))

E[BHIPM] (Ib/hr) = C[BHIPMj * Vdscfm * A * (60 min/hr) * (1 Ib 17000 grains)

BHIPM Mass = 0.0068 9

C[BHIPM]= 1.19E-03 grains/dscf

C[BHIPMj= 1.70E-07 Ib/dscf

E[BHIPMj= 0.0021 Ib/MMBtu

E[BHIPM]= 1.614 Ib/hr

% BHIPM 48.6

13) Total Back Half Particulate Matter

C[TBHPM] (grains/dscf) = (C[BHOPMj (grains/dscf)) + (C[BHIPM] (grains/dscf))

C[TBHPM] (Ib/dscf) = (C[BHOPMj (Ib/dscf)) + (C[BHIPMj (Ib/dscf))

E[TBHPM] (lb/MMBtu) = (E[BHOPM] (lb/MMBtu)) + (E[BHIPM] (lb/MMBtu))

E[TBHPM] (Ib/hr) = C[TBHPM] * Vdscfm * A * (60 min/hr) * (1 Ib / 7000 grains)

Blank Mass = 0.0000 9

TBHPM Mass = 0.0068 9

C[TBHPM]= 1.19E-03 grains/dscf

C[TBHPM]= 1.70E-07 Ib/dscf

E[TBHPM]= 0.0021 Ib/MMBtu

E[TBHPMj= 1.614 Ib/hr

% TBHPM 48.6

14) Total Particulate Matter < 10 Microns Emission Data

C[TPM10] (grains/dscf) = (C[TSP] (grains/dscf)) + (C[TBHPM] (grains/dscf))

C[TPM10] (Ib/dscf) = (C[TSP] (Ib/dscf)) + (C[TBHPMj (Ib/dscf))

E[TPM10] (lb/MMBtu) = (E[TSP] (lb/MMBtu)) + (E[TBHPM] (lb/MMBtu))

E[TPM10] (Ib/hr) = C[TPM1 0] * Vdscfm * A * (60 min/hr) * (1 Ib 17000 grains)

C[TPM10] = 2.44E-03 grains/dscf

C[TPM10] = 3.49E-07 Ib/dscf

E[TPM10j = 0.0044 Ib/MMBtu

E[TPM10j = 3.323 Ib/hr

15) Isokinecity, I.

% 1= [1 00*Ts*(K3*Vlc+«(Vm*Y)/Tm)*(Pb+(dH/13.6))))] I (60*t*Ps*Vs*An)

% I = 99.98

13
3338-EPA5-202-R3 AirNova, Inc.

EPA Methods 1,2,3A,4,5 and 202

(Flows, 02/C02, H20, Total Suspended Particulate and Back Half PM)

Client James River Cogeneration Company

Project No. 3338

Test Location Hopewell, Virginia

Emission Source Unit NO.2

Fuel Coal

Test Date 05/07/10

Test Run Three

Time Period 1216-1426

Emission Data Data from:

INPUT Vlc= 214.8 cc Vol. of H20 collected EPA4

INPUT Vm= 91.090 dcf Dry gas meter reading EPA 4

INPUT Pstatic = 0.55 in. H2O Static pressure EPA2

INPUT Pb= 29.98 in. Hg Barometric pressure

Ps= 30.02 in. Hg Stack pressure EPA2

Pstd = 29.92 in. Hg EPA Standard pressure

dP= 0.804 in. H20 ".5 Average sq.rt delta P EPA 2

dH = 1.74 in. H2O Average draft gauge reading EPA4

Tm= 551.5 R Average meter temperature EPA4

Ts = 675.2 R Average stack temperature EPA2

INPUT Tstd= 527.7 R Standard temperature

INPUT y= 1.00 Meter calibration factor

INPUT t= 120 min. Duration of sampling time

INPUT On = 0.250 in. Nozzle diameter

INPUT An = 0.000341 sq. ft. Nozzle area

INPUT Ds= 9.667 ft. Diameter of stack

As= 73.39 sq. ft. Cross sectional area of stack

INPUT Cp= 0.84 Pitot tube coefficient EPA2

Kp= 85.49 ft[(Ibllbmol)*(inHg)]".5}/[s*R*inH20] Pitot tube constant

K1 = 17.637 R/in.Hg constant

K2 = 0.047070 cU.ftlml constant

K3 = 0.0026688 in.Hg-cf/ml-R constant

Molar vol air= 385.0 scf/lb-mol constant @ 68 deg F

Fd = 8842 scf/MMBtu Fuel Factor

EPA Method 3A Instrumental Data

INPUT EPA3

INPUT EPA3

[02]

[C02]

[N2]

5.49 %-dry

13.63 %-dry

80.88 %-dry

14

Oxygen concentration

Carbon Dioxide concentration

Nitrogen concentration
Client

Project No.

James River Cogeneration Com Emission Source

3338 Test Run

Calculations

Unit NO.2

Three

Page 2

1) Volume of gas sampled at standard conditions, Vmstd.

Vmstd =K1* Y * Vm * (Pb + dH/13.6) / Tm

Vmstd = 87.707 dscf

2.484 dscm

2) Volume of water vapor collected at standard conditions, Vw(std).

Vw(std) = K2 * Vic

Vw(std) = 10.111 scf

3) Decimal fraction of moisture by volume in stack gas, Bws.

Bws = Vwstd / (Vmstd+Vwstd)

Bws = 0.1034

4) Molecular weight of the stack gas on a wet basis, Ms.

Ms = [«44*%C02) + (32*%02) + (28*%N2)) * (1-Bws)] + (18*Bws)

Ms = 29.119 Ib/lbmole

5) Average stack gas velocity, Vs.

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)".5

Vs = 50.757 fps

6) Average actual stack gas volumetric flowrate, Qa.

Qa = 60 sec/min * Vs * As

Qa = 223514.42 cfm

6329.93 cmm

7) Average stack gas dry volumetric flowrate, Qstd.

Qstd = Qa * (TstdlTs) * (Ps/Pstd) * (1-Bws)

Qstd = 157156.72 dscfm

Qstd = 4450.68 dscmm

15
Client

Project No.

James River Cogeneration Com Emission Source

3338 Test Run

Calculations (cont.)

Unit No.2

Three

Page 3

8) Particulate Matter Analytical Data

INPUT A 0.0032 9 Filter sample net wt

INPUT B 200 ml Front acetone wash vol.

INPUT C 0.0029 9 Front acetone residue wt.

INPUT 0 200 ml Acetone blank vol.

INPUT E 0.0000 9 Acetone blank residue wt.

9) Particulate sample mass calculations

H

I

J

Front Half:

Acetone blank adj. residue wt

Adj. Acetone wash part.wt.

Front half sample wt.

0.0000 9

0.0029 9

0.0061 9

E*(B/D)

C-H

A+ I

10) Total Suspended Particulate Matter Emission Data

C[TSP] (grains/dscf) = (Front Half Wt)(g) * (1Nmstd) * 15.43(grains/g)

C[TSP] (Ib/dscf) = C[TSP] (grains/dscf) * (1 Ib/7000 grains)

E[TSP] (lb/MMBtu) = C[TSP] (Ib/dscf) * Fd * (20.9/(20.9-02))

E[TSP] (Ib/hr) = C[TSP] * Vdscfm * A * (60 min/hr) * (1 Ib I 7000 graim

C[TSP] = 1.07E-03 grains/dscf

C[TSP] = 1.53E-07 Ib/dscf

E[TSP] = 0.0018 Ib/MMBtu

E[TSP] = 1.446 Ib/hr

11) Back Half Organic Particulate Analysis

C[BHOPM] (grains/dscf) = (Organic Mass Wt)(g) * (1Nmstd) * 15.43(grains/g)

C[BHOPM] (Ib/dscf) = C[BHOPM] (grains/dscf) * (1 Ib/7000 grains)

E[BHOPM] (Ib/MMBtu) = C[BHOPM] (Ib/dscf) * Fd * (20.9/(20.9-02»)

E[BHOPM] (Ib/hr) = C[BHOPM] * Vdscfm * A * (60 min/hr) * (1 Ib I 7000 grains)

BHOPM Mass = 0.0000 9

C[BHOPM]= O.OOE+OO grains/dscf

C[BHOPM]= O.OOE+OO Ib/dscf

E[BHOPM]= 0.0000 Ib/MMBtu

E[BHOPM]= 0.000 Ib/hr

% BHOPM 0.0

16
Client

Project No.

James River Cogeneration Com Emission Source

3338 Test Run

Calculations (cont.)

Unit NO.2

Three

Page 4

12) Back Half Inorganic Particulate Analysis

C[BHIPM] (grains/dscf) = (Inorganic Mass Wt)(g) * (1Nmstd) * 15.43(grains/g)

C[BHIPM] (Ib/dscf) = C[BHIPM] (grains/dscf) * (1 Ib/7000 grains)

E[BHIPM] (lb/MMBtu) = C[BHIPM] (Ib/dscf) * Fd * (20.9/(20.9-02))

E[BHIPM] (Ib/hr) = C[BHIPM] * Vdscfm * A * (60 min/hr) * (1 Ib 17000 grains)

BHIPM Mass = 0.0077 9

C[BHIPM]= 1.35E-03 grains/dscf

C[BHIPM]= 1.94E-07 IbIdscf

E[BHIPM]= 0.0023 Ib/MMBtu

E[BHIPM]= 1.825 Ib/hr

% BHIPM 55.8

13) Total Back Half Particulate Matter

C[TBHPM] (grains/dscf) = (C[BHOPM] (grains/dscf)) + (C[BHIPM] (grains/dscf))

C[TBHPM] (Ib/dscf) = (C[BHOPM] (Ib/dscf)) + (C[BHIPM] (Ib/dscf))

E[TBHPM] (lb/MMBtu) = (E[BHOPM] (lb/MMBtu)) + (E[BHIPM] (lb/MMBtu))

E[TBHPM] (Ib/hr) = C[TBHPM] * Vdscfm * A * (60 min/hr) * (1 Ib 17000 grains)

Blank Mass = 0.0000 9

TBHPM Mass = 0.0077 9

C[TBHPM]= 1.35E-03 grains/dscf

C[TBHPM]= 1.94E-07 Ib/dscf

E[TBHPM]= 0.0023 Ib/MMBtu

E[TBHPM]= 1.825 Ib/hr

% TBHPM 55.8

14) Total Particulate Matter < 10 Microns Emission Data

C[TPM10] (grains/dscf) = (C[TSP] (grains/dscf)) + (C[TBHPM] (grains/dscf))

C[TPM10] (Ib/dscf) = (C[TSP] (Ib/dscf)) + (C[TBHPM] (Ib/dscf))

E[TPM10] (lb/MMBtu) = (E[TSP] (Ib/MMBtu)) + (E[TBHPM] (lb/MMBtu))

E[TPM10] (Ib/hr) = C[TPM10] * Vdscfm * A * (60 min/hr) * (1 Ib 17000 grains)

C[TPM10] = 2.43E-03 grains/dscf

C[TPM10] = 3.47E-07 Ib/dscf

E[TPM10] = 0.0042 Ib/MMBtu

E[TPM10] = 3.270 Ib/hr

15) Isokinecity, I.

% I = [1 00*Ts*(K3*Vlc+(((Vm*Y)/Tm)*(Pb+(dH/13.6))))] I (60*t*Ps*Vs*An)

% I = 100.13

17
3338-Metals-R1

Client

Project No.

Test location

Test Run

Test Date

Test Time

AirNova, inc.

EPA Methods 1,2,3A,4, and 29

(Flows, 02/C02, H20, and Metals)

James River Cogeneration Company

3338

Unit NO.2

One

05/07/10

0715-0930

Emission Data

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

Vlc=

Vm=

Pstatic =

Pb =

Ps =

Pstd =

dP = dH =

Tm=

Ts =

Tstd=

On =

An =

y=

t=

Os =

As = Cp =

Kp =

K1 =

K2 =

K3=

Fd =

231.4 cc Vol. of H20 collected

86.296 dcf Dry gas meter reading

0.55 in. H20 Static pressure

29.98 in. Hg Barometric pressure

30.02 in. Hg Stack pressure

29.92 in. Hg EPA Standard pressure

0.8029 in. H20 ".5 Average sq.rt delta P

1.730 in. H20 Average draft gauge reading

534.9 R Average meter temperature

668.1 R Average stack temperature

527.7 R Standard temperature

0.246 in. Nozzle diameter

0.000330 sq. ft. Area of nozzle orifice

1.01 Meter calibration factor

120 min. Duration of sampling time

9.67 ft. Diameter of stack

73.3940 sq. ft. Cross sectional area of stack

0.84 Pitot tube coefficient

85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R*inH20] Pitot tube constant

17.637 Rlin.Hg constant

0.047070 cU.ft/ml constant

0.0026688 in.Hg-cf/ml-R constant

9100 scf/MMBtu Fuel Factor

Instrumental Data

INPUT

INPUT

[02]

[C02]

[N2]

5.49 %-dry

13.65 %-dry

80.86 %-dry

18

Oxygen concentration

Carbon Dioxide concentration

Nitrogen concentration
Client

Project No.

James River Cogeneration C' Test Location

3338 Test Run

Calculations

Unit NO.2

One

Page 2

1) Volume of gas sampled at standard conditions, Vmstd.

Vmstd =K1* Y * Vm * (Pb + dH/13.6) / Tm

Vmstd = 86.522 dscf

2.450 dsem

2) Volume of water vapor collected at standard conditions, Vw(std).

Vw(std) = K2 * Vic

Vw(std) = 10.892 sef

3) Decimal fraction of moisture by volume in stack gas, Bws.

Bws = Vwstd / (Vmstd+Vwstd)

Bws = 0.1118

4) Molecular weight of the stack gas on a wet basis, Ms.

Ms = [«44*%C02) + (32*%02) + (28*%N2)) * (1-Bws)] + (18*Bws)

Ms = 29.017 Ib/ Ibmole

5) Average stack gas velocity, Vs.

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)".5

Vs = 50.494 fps

6) Average actual stack gas volumetric flowrate, Qa.

Qa = 60 see/min * Vs * As

Qa = 222358.86 cfm

6297.20 cmm

7) Average stack gas dry volumetric flowrate, Qstd.

Qstd = Qa * (TstdlTs) * (Ps/Pstd) * (1-Bws)

Qstd = 156512.97 dsefm

4432.45 dsemm

19
Client

Project No.

James River Cogeneration C' Test Location

3338 Test Run

Calculations (cont.)

Unit No.2

One

Page 3

11 )Trace metal concentrations and emission rates

C[M] = M[M] (ug) 1Vmstd (dscm)

C[M](Ib/dscf) = C[M](ug/dscm) * 1e-06g/ug * 2.205e-03Ib/g * 0.02832 dscm/dscf

E[M](Ib/hr) = C[M] (ug/dscm) * (2.205E-09) (Ib/ug) * Qstd (dscmm) * 60 (min/hr)

E[M](lb/MMBtu) = C[M](Ib/dscf) * Fd * (20.9/20.9-%02)

C[M](@ corr. 02) = C[M] (ug/dscm) * [ (20.9-corrected %02) 1(20.9-actual %02) ]

Corrected 02 percentage is: 7.0 %

Sample Cone. Conc.@corr. 02 Cone. Emission Rate Emission Rate

Element Mass (ug) (ug/dscm) (ug/dscm) (IbIdscf) (Ib/hr) (Ib/MMBtu)

Antimony 0.254 1.04E-01 9.35E-02 6.47E-12 6.08E-05 7.989E-08

Arsenic 1.963 8.01 E-01 7.23E-01 5.00E-11 4.70E-04 6.174E-07

Beryllium 0.043 1.75E-02 1.58E-02 1.10E-12 1.03E-05 1.352E-08

Cadmium 0.100 4.08E-02 3.68E-02 2.55E-12 2.39E-05 3.145E-08 <

Chromium 4.320 1.76E+00 1.59E+00 1.10E-10 1.03E-03 1.359E-06

Cobalt 0.317 1.29E-01 1.17E-01 8.08E-12 7.59E-05 9.971E-08

Lead 1.807 7.37E-01 6.65E-01 4.61E-11 4.32E-04 5.684E-07

Manganese 20.240 8.26E+00 7.45E+00 5.16E-10 4.84E-03 6.366E-06

Nickel 2.419 9.87E-01 8.90E-01 6.16E-11 5.79E-04 7.609E-07

Selenium 0.318 1.30E-01 1.17E-01 8.10E-12 7.61E-05 1.000E-07

Mercury 0.500 2.04E-01 1.84E-01 1.27E-11 1.20E-04 1.573E-07 <

9) Isokinecity, I.

% 1= [100*Ts*(K3*Vlc+(((Vm*Y)fTm)*(Pb+(dH/13.6»)))] 1(60*t*Ps*Vs*An)

% 1= 102.44

" < " symbol indicates values given are the quantitative detection limit.

20
3338-Metals-R2 AirNova, Inc.

EPA Methods 1,2,3A,4, and 29

(Flows, 02/C02, H20, and Metals)

Client James River Cogeneration Company

Project No. 3338

Test Location Unit NO.2

Test Run Two

Test Date 05/07/10

Test Time 0952-1203

Emission Data

INPUT Vlc= 214.5 cc Vol. of H20 collected

INPUT Vm= 85.239 dcf Dry gas meter reading

INPUT Pstatic = 0.55 in. H2O Static pressure

INPUT Pb = 30.02 in. Hg Barometric pressure

Ps = 30.06 in. Hg Stack pressure

Pstd = 29.92 in. Hg EPA Standard pressure

dP = 0.8019 in. H20 ".5 Average sq.rt delta P

dH = 1.716 in. H2O Average draft gauge reading

Tm= 537.8 R Average meter temperature

Ts = 671.8 R Average stack temperature

INPUT Tstd= 527.7 R Standard temperature

INPUT On = 0.246 in. Nozzle diameter

An = 0.000330 sq. ft. Area of nozzle orifice

INPUT y= 1.01 Meter calibration factor

INPUT t= 120 min. Duration of sampling time

INPUT Ds= 9.67 ft. Diameter of stack

As= 73.3940 sq. ft. Cross sectional area of stack

INPUT Cp= 0.84 Pitot tube coefficient

Kp= 85.49 ft[(lbllbmol)*(inHg)]".5}/[s*R*inH20] Pitot tube constant

K1 = 17.637 R/in.Hg constant

K2= 0.047070 cu.ftIml constant

K3= 0.0026688 in.Hg-cf/ml-R constant

INPUT Fd = 9154 scf/MMBtu Fuel Factor

Instrumental Data

INPUT [02] 5.65 %-dry Oxygen concentration

INPUT [CO2] 13.53 %-dry Carbon Dioxide concentration

[N2] 80.82 %-dry Nitrogen concentration

21
Client

Project No.

James River Cogeneration C' Test Location

3338 Test Run

Calculations

Unit NO.2

Two

Page 2

1) Volume of gas sampled at standard conditions, Vmstd.

Vmstd =K1* Y * Vm * (Pb + dH/13.6) / Tm

Vmstd = 85.109 dsef

2.410 dsem

2) Volume of water vapor collected at standard conditions, Vw(std).

Vw(std) = K2 * Vic

Vw(std) = 10.096 sef

3) Decimal fraction of moisture by volume in stack gas, Bws.

Bws = Vwstd / (Vmstd+Vwstd)

Bws = 0.1060

4) Molecular weight of the stack gas on a wet basis, Ms.

Ms = [«44*%C02) + (32*%02) + (28*%N2)) * (1-Bws)] + (18*Bws)

Ms = 29.077 Ib/lbmole

5) Average stack gas velocity, Vs.

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)".5

Vs = 50.482 fps

6) Average actual stack gas volumetric flowrate, Qa.

Qa = 60 sec/min * Vs * As

Qa = 222304.45 cfm

6295.66 emm

7) Average stack gas dry volumetric flowrate, Qstd.

Qstd = Qa * (TstdlTs) * (Ps/Pstd) * (1-Bws)

Qstd = 156838.78 dscfm

4441.67 dsemm

22
Client

Project No.

James River Cogeneration C' Test Location

3338 Test Run

Calculations (cont.)

Unit NO.2

Two

Page 3

11 )Trace metal concentrations and emission rates

C[M] = M[M] (ug) 1Vmstd (dscm)

C[M](Ib/dscf) = C[M](ug/dscm) * 1e-06g/ug * 2.205e-03Ib/g * 0.02832 dscm/dscf

E[M](lb/hr) = C[M] (ug/dscm) * (2.205E-09) (Ib/ug) * Qstd (dscmm) * 60 (min/hr)

E[M](Ib/MMBtu) =C[M](Ib/dscf) * Fd * (20.9/20.9-%02)

C[M](@ corr. 02) =C[M] (ug/dscm) * [ (20.9-corrected %02) 1(20.9-actual %02) ]

Corrected 02 percentage is: 7.0 %

Sample Cone. Conc.@corr. 02 Cone. Emission Rate Emission Rate

Element Mass (ug) (ug/dscm) (ug/dscm) (IbidscO (Ib/hr) (lb/MMBtu)

Antimony 0.404 1.68E-01 1.53E-01 1.05E-11 9.85E-05 1.313E-07

Arsenic 2.110 8.75E-01 7.98E-01 5.47E-11 5.14E-04 6.858E-07

Beryllium 0.041 1.70E-02 1.55E-02 1.06E-12 1.00E-05 1.333E-08

Cadmium 0.156 6.47E-02 5.90E-02 4.04E-12 3.80E-05 5.070E-08

Chromium 4.550 1.89E+00 1.72E+00 1.18E-10 1.11 E-03 1.479E-06

Cobalt 0.327 1.36E-01 1.24E-01 8.47E-12 7.97E-05 1.063E-07

Lead 2.221 9.21 E-01 8.40E-01 5.75E-11 5.41E-04 7.219E-07

Manganese 2.014 8.36E-01 7.62E-01 5.22E-11 4.91E-04 6.546E-07

Nickel 3.399 1.41 E+OO 1.29E+00 8.81E-11 8.29E-04 1.105E-06

Selenium 0.386 1.60E-01 1.46E-01 1.00E-11 9.41E-05 1.255E-07

Mercury 0.500 2.07E-01 1.89E-01 1.30E-11 1.22E-04 1.625E-07 <

9) Isokinecity, I.

% 1= [100*Ts*(K3*Vlc+«(Vm*Y)/Tm)*(Pb+(dH/13.6»))] 1(60*t*Ps*Vs*An)

% I = 100.56

II < II symbol indicates values given are the quantitative detection limit.

23
3338-Metals-R3

Client

Project No.

Test Location

Test Run

Test Date

Test Time

AirNova, Inc.

EPA Methods 1,2,3A,4, and 29

(Flows, 02/C02, H20, and Metals)

James River Cogeneration Company

3338

Unit NO.2

Three

05/07/10

1216-1426

Emission Data

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

INPUT

Vlc=

Vm=

Pstatic =

Pb=

Ps =

Pstd =

dP = dH =

Tm=

Ts =

Tstd=

Dn =

An =

y=

t=

Ds =

As =

Cp =

Kp =

K1 =

K2 = K3 =

Fd =

220.2 cc Vol. of H20 collected

88.730 dcf Dry gas meter reading

0.55 in. H20 Static pressure

29.98 in. Hg Barometric pressure

30.02 in. Hg Stack pressure

29.92 in. Hg EPA Standard pressure

0.8189 in. H20 1\.5 Average sq.rt delta P

1.789 in. H20 Average draft gauge reading

540.3 R Average meter temperature

674.5 R Average stack temperature

527.7 R Standard temperature

0.246 in. Nozzle diameter

0.000330 sq. ft. Area of nozzle orifice

1.01 Meter calibration factor

120 min. Duration of sampling time

9.67 ft. Diameter of stack

73.3940 sq. ft. Cross sectional area of stack

0.84 Pitot tube coefficient

85.49 ft[(lb/lbmol)*(inHg)]ll.5}/[s*R*inH20] Pitot tube constant

17.637 R/in.Hg constant

0.047070 cu.ftIml constant

0.0026688 in.Hg-cf/ml-R constant

8842 scf/MMBtu Fuel Factor

Instrumental Data

INPUT

INPUT

[02]

[C02]

[N2]

5.49 %-dry

13.63 %-dry

80.88 %-dry

24

Oxygen concentration

Carbon Dioxide concentration

Nitrogen concentration
Client

Project No.

James River Cogeneration G Test Location

3338 Test Run

Calculations

Unit No.2

Three

Page 2

1) Volume of gas sampled at standard conditions, Vmstd.

Vmstd =K1 * Y * Vm * (Pb + dH/13.6) / Tm

Vmstd = 88.090 dscf

2.495 dscm

2) Volume of water vapor collected at standard conditions, Vw(std).

Vw(std) = K2 * Vic

Vw(std) = 10.365 scf

3) Decimal fraction of moisture by volume in stack gas, Bws.

Bws = Vwstd / (Vmstd+Vwstd)

Bws = 0.1053

4) Molecular weight of the stack gas on a wet basis, Ms.

Ms = [«44*%C02) + (32*%02) + (28*%N2» * (1-Bws)] + (18*Bws)

Ms = 29.095 Ib/lbmole

5) Average stack gas velocity, Vs.

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)l'.5

Vs = 51.676 fps

6) Average actual stack gas volumetric flowrate, Qa.

Qa = 60 sec/min * Vs * As

Qa = 227560.76 cfm

6444.52 cmm

7) Average stack gas dry volumetric flowrate, Qstd.

Qstd = Qa * (TstdlTs) * (Ps/Pstd) * (1-Bws)

Qstd = 159818.35 dscfm

4526.06 dscmm

25
Client

Project No.

James River Cogeneration C' Test Location

3338 Test Run

Calculations (cont.)

Unit NO.2

Three

Page 3

11 )Trace metal concentrations and emission rates

C[M] = M[M] (ug) 1Vmstd (dscm)

C[M](lb/dscf) =C[M](ug/dscm) * 1e-06g/ug * 2.205e-03Ib/g * 0.02832 dscm/dscf

E[M](Ib/hr) = C[M] (ug/dscm) * (2.205E-09) (Ib/ug) * Qstd (dscmm) * 60 (min/hr)

E[M](Ib/MMBtu) = C[M](Ib/dscf) * Fd * (20.9/20.9-%02)

C[M](@ corr. 02) =C[M] (ug/dscm) * [ (20.9-corrected %02) 1(20.9-actual %02) ]

Corrected 02 percentage is: 7.0 %

Element

Antimony

Arsenic

Beryllium

Cadmium

Chromium

Cobalt

Lead

Manganese

Nickel

Selenium

Mercury

9) Isokinecity, I.

Sample

Mass (ug)

0.509

2.229

0.057

0.332

4.490

0.422

9.816

3.180

5.340

0.495

0.500

Cone.

(ug/dscm)

2.04E-01

8.93E-01

2.28E-02

1.33E-01

1.80E+00

1.69E-01

3.93E+00

1.27E+00

2.14E+00

1.98E-01

2.00E-01

Conc.@corr. 02

(ug/dscm)

1.84E-01

8.06E-01

2.06E-02

1.20E-01

1.62E+00

1.53E-01

3.55E+00

1.15E+00

1.93E+00

1.79E-01

1.81 E-01

Cone.

(Ib/dscf)

1.27E-11

5.58E-11

1.43E-12

8.31 E-12

1.12E-10

1.06E-11

2.46E-10

7.96E-11

1.34E-10

1.24E-11

1.25E-11

Emission Rate

(Ib/hr)

1.22E-04

5.35E-04

1.37E-05

7.97E-05

1.08E-03

1.01E-04

2.36E-03

7.63E-04

1.28E-03

1.19E-04

1.20E-04

Emission Rate

(Ib/MMBtu)

1.528E-07

6.691E-07

1.711E-08

9.966E-08

1.348E-06

1.267E-07

2.947E-06

9.546E-07

1.603E-06

1.486E-07

1.501E-07 <

% 1= [100*Ts*(K3*Vlc+«(Vm*Y)/Tm)*(Pb+(dH/13.6))))] 1(60*t*Ps*Vs*An)

% 1= 102.14

.. < .. symbol indicates values given are the quantitative detection limit.

26
Appendix D

Calibration Data

CERTIFICATE OF ANALYSIS

Grade ofProduct: EPA Protocol

Airgas Specially Gases

600 Union Landing Road

Riverton, NJ 08077

(856) 829-7878

Fax (856) 829-0571

www.airgas.com

Part Number:

Cylinder Number:

Laboratory:

Analysis Date:

E03NI80E15A1087

XC032964B

ASG - Riverton - NJ

Aug 24, 2009

Reference Number:

Cylinder Volume:

Cylinder Pressure:

Valve Outlet:

82-124188656-1

150 CU.Ft.

2015 PSIG

590

Expiration Date: Aug 24, 2012

Certification performed in accordance with "EPA Traceability Protocol (Sept. 1997)" using the assay procedures listed. Analytical Methodology does not require correction for

analytical interferences. This cylinder has a total analytical uncertainly as stated below with a confidence level of 95%. There are no significant impurities which affect the use

of this calibration mixture. All concentrations are on a volume/volume basis unless otherwise noted.

Do Not Use This Cylinder below 150 psig.i.e. 1 Mega Pascal

ANALYTICAL RESULTS

Component Requested Actual Protocol Total Relative

Concentration Concentration Method Uncertainty

CARBON DIO>:,")E 7.500 % 7.450 % G1 +/- 1% NiST TraceaiJ!e

OXYGEN 12.50 % 12.47 % G1 +/- 1% NIST Traceable

NITROGEN Balance

CALIBRATION STANDARDS

Type LotiO Cylinder No Concentration Expiration Date

NTRM 01119418 CC'I4317 9.72% OXYGEN/NITROGEN Jul05,2010

NTRM 99061109 XC018416B 4.811 % CARBON DIOXIDE/NITROGEN May 15, 2012

ANALYTICAL EQUIPMENT

Instrument/Make/Model Analytical Principle Last Multipoint Calibration

- Siemens UIlramal6E N1-NOS820 NDIR Aug 24;2009

Siemens 5E BN805 Paramagnetic Aug OS, 2009 /;i

Triad Data Available Upon Request

Notes:02 CONCENTRATION CORRECTED FOR CO2

INTERFERENCE. . (1 ~\ iri

L- -Co J\[JLl,;7<.J.,\t/

QA Approval

Page 1 of 82·124188666·1

1

#5000
CERTIFICATE OF ANALYSIS

Grade ofProduct: EPA Protocol

Airgas Speciallv Gases

600 Union Landing Road

Riverton, NJ 08077

(856) 829-7878

Fax (856) 829-0571

www.airgas.com

Part Number:

Cylinder Number:

Laboratory:

Analysis Date:

E03NI65E15A1094

CC5693

ASG - Riverton - NJ

Jun 23, 2008

Reference Number:

Cylinder Volume:

Cylinder Pressure:

Valve Outlet:

82-124142222-1

154 Cu.Ft.

2015 PSIG

590

Expiration Date: Jun 23, 2011

Certification performed in accordance with "EPA Traceability Protocol (Sept. 1997)" using the assay procedures listed. Analytical Methodology does not require correction for

analytical interferences. This cylinder has a total analytical uncertainty as stated beiow with a confidence level of 95%. There are no significant impurities which affect the use

of this calibration mixture. All concentrations are on a volumelvolume basis unless otherwise noted.

Do Not Use This Cylinder below 150 psig.i.e, 1 Mega Pascal

ANALYTICAL RESULTS

Component Requested AcMlI Protocol Total Rolative

, Concentration Concentration Method Uncertainty

CARBON DIOXIDE 12.50 % 12.38 % 81 +/~ 1% NIST Traceable

OXYGEN 22.00% 22.03% 81 +/- 1% N/ST Traceable

NITROGEN Balance

CALIBRATION STANDARDS

Type Lot 10 Cylinder No Concentration Expiration Date

NTRM 03060212 XC024397B 22.60% OXYGEN/NITROGEN JulO1,2011

NTRM 04060437 XC034316B 19.84% CARBON DIOXIDE/NITROGEN May 15, 2012

ANALYTICAL EQUIPMENT

Instrument/Make/Model Analytical Principle Last Multipoint Calibration

Siemens Ultramat 6E N1-NO-0820 NDIR Jun 17,2008

Siemens 5E BN805 Paramagnetic Jun 05, 2008

Triad Data Avai/able Upon Request

Notes:02 CONCENTRATION CORRECTED FOR C02

INTERFERENCE.

C ct~~/\~J QIlLOOe---

QA Approval

'Page 1 of82-124142222-1

2

#5000
600 Union landing Road

Riverton, NJ 08077

Airg8s Sllecialtv Gases

CERTIFICATE OF ANALYSIS

G d d 1

(856) 829-7878

ra e Pro net: EPA Protoco Fax (856)829-0571

www.airgas.com

Part Number:

Cylinder Number:

Laboratory:

Analysis Date:

E02NI78E15A0346

XC0186948

ASG - Riverton - NJ

Apr 23, 2007

Expiration Date: Apr 23,2010

Reference Number:

Cylinder Volume:

Cylinder Pressure:

Valve Outlet:

82-124093653-1

158 Cu.Ft.

2015 PSIG

580

Certification performed in accordance with "EPA Traceability Protocol (Sept. 1997)" using the assay procedures listed. Analytical Methodology does not require correction for

analytical interferences. This cylinder has a total analytical uncertainty as stated below with a confidence level of 95%. There are no significant impurities which affect the use

of this calibration mixture. All concentrations are on a volume/volume basis unless otherwise noted.

Do Not Use This Cylinder below 150 psig.i.e. 1 Mega Pascal

ANALYTICAL ImS'lJIiTS'

Component

I CARBON DIOXIDE

I NITROGEN

Requested

Concentration

22.00%

Balance

Actual

Concentration

22.28 %

Protocol

Method

G1

Total Relative

Uncertainity . .

+1-1% NISTTraceable

III 7"1]'.,,·fJ -01 ....'t~, Lot ID Cylinder No

CALIBRATION STANDARDS

Concentration Expiration Date

,

NTRM 00060309 XC034300B 19.84% CARBON DIOXIDE/NITROGEN May 15, 2008 I

ANALYTICAL EQUIPMENT

~...;;I;,;n.;;s;,;tr",;,u;,;.m;,;.e;,;n;,;.t1;,;.M~a;,;k,;;,;el;,;.M;,;.o;;.d;,;.e;;.;I~~~= ,..;;.A;,;.n;.;;a;,;;lyt::..;.;.ic;;.;a;,;I",;,P;,;r;,;in;,;c;;.ip:;;,l;,;e=== L_as_t_M_U_It..;iP:..O_i_n_t_C_a_li_b_ra_t_io_n ___

"""",N""ic""o""'e""t""56""0...A""D""U""9""8""00..,4""0...6""C",O.,./CmO""2""""""",,,,,,,,,,,,,,,,,,,,,,,,",,,,,,,,,,,,,,,,""FT".,'''''R''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''' ''''''''''''''''''''''''''_A..;p''''r..,1,.;2,.,,2''''0''''07''''''''''''''''' .1

Triad Data Available Upon Request

Notes:

~~~!U:C4,,~j QAApproval

Page 1 of 82·124093653·1

3
"INDUSTRY LEADER IN SPECIALTY GASES"

Certificate ofAnalysis

- EPA PROTOCOL GAS -

** Recertification **

N

Customer

Date

Delivery Receipt

Gas Standard

Final Analysis Date

Expiration Date

Air Nova (Pennsauken, NJ)

June 03, 201'0

DR-29621

22.28% Carbon Dioxide/Nitrogen-EPA PROTOCOL

May 28,2010

May 28, 2013

Component

Balance Gas

Carbon Dioxide

Nitrogen

Analytical Data: DO NOT USE BELOW 150 psig

EPA Protocol, Section No. 2.2, ProceslnLeQ-I .. ' ~.' --------- >-..:::.:::

Reported Cop.centrations

/ Carbon Dioxide: 21.7% +/- 0.210/0

Nitrogen: Balance

Reference Standards: ".

"------ SRM/GMIS: GMIS'

Cylinder Number: CC-115915

Concentration: 19.44% C02/Nitrogen

Expiration Date: December 31, 20 I I

Certification Instrumentation

Component: Carbon Dioxide

Make/Model: Agilent 7890A

Serial Number: CNI0736166

Principal of Measurement: GC-TCD

Last Calibration: May 21, 2010

CGA 580

1950 psig, 70°F

Cylinder Outlet:

Cylinder Pressure:

Cylinder Data

Cylinder Serial Number: C.k.C--:Q1862.48 ....

Cylinder Volume: 136 Cubic Feet

Expiration Date: June 03, 2013

Analytical Uncertainty and NIST Traceability are in compliance with EPA-600/R-97/121.

Certified by:

Mike Duncan

Original Data: 22.28% C02/Nitrogen (April 23, 2007) - Airgas: Riverton, NJ 08077

"UNMATCHED EXCELLENCE"

4

2564 PEMBERTON DRIVE ApOPKA, FLORIDA 32703 PHONE (407)-292-2990 FAX (407)-292-3313

WWW.L1QUIDTECHCORP.COM
AirNova, Inc.

Pitot Thermocouple

Calibration data

Date: ' 11/17/09

Thermocouple 1.0. : ANT5A

Probe Length: 5 Foot

Calibrator KA

Ambient Temp.(F): 62

Barometric Pressure (" Hg): 30.10

Reference Thermometer: ASTM-2F

Reference

Point

1

Source

Ice Water

Ref. Thermometer

Temp.(F)

34

Thermocouple

Temp.(F)

33

Temperature

Dm. (%)

0.2%

2 Boiling Water 211 212 0.1%

3 Very Hot Oil Bath 353 351 0.2%

4 Ambient Temp. 62 63 0.2%

Average Temp. Change: 0.2%

Temperature Difference must be < 1.5 %

5

Date: / 1/;7/~
Type S Pitot Tube

Dimensional Specification Verification Form

• .: • 0 • '.. •

... ,,0 00 0 .

• O@@i)eO@le .

•• <lIlII A- N I ... EI • ell ell • EI ---=-..:.:..::..I...::.r-=--==-o==-v=-=a~,~=-n=-=--=c=-=--.. _ .... <lI ell • 4il e .

"oeE)II€i1:@ec '

.° 00 $8 00 '

.. Go 0 • e : ..

Pitot No.

Calibrator

Date

Verify the following criteria and check all that apply

1) Face opening plane perpendicular to the transverse axis ? __L-_--~cc..

2) Face-opening plane parallel to the logitudinal axis? __

3) Are Legs A & B of equallen·gth and are centerlines coincident? __

If all the above criteria are met, a pitot coeffecient of 0.84 may be assigned to

the respective pitot tube. If one of the following criteria above is not met, the

pitot tube must be calibrated in a wind tunnel.

Recommended Dimensions

4) Diameter of pitot tubing? (01):::: J 7.5 in.

PalDt= __

Pb/Dt = /; -'---

5) Dimensions of Pa =__in.

6) Dimensions of Pb =__L_/ in.

( 0.1875 < Dt < 0.375)

(1.05 <Ot < 1.50)

(1.05 < Dt < 1.50)

TRANSVERSE" i TUBE AXIS '

.l.~._.

f-O::;f~G~ • Ftl\NES •

(~.

"4lG!tt.M!(

,oo<rr...OA< • f ·-0~~: I:'::~<Hf"''' llJt.(,uU 1; ........_--=-_.~.y_.l~~. "". 1H:I0{fUl,.::l.(

(hI

vI
AirNova, Inc.

Pitot Thermocouple

Calibration data

Date: .11/17/09

Thermocouple 1.0. : AN-50

Probe Length: 5 Foot

Calibrator KA

Ambient Temp.(F): 62

Barometric Pressure (" Hg): 30.10

Reference Thermometer: ASTM-2F

Reference

Point

Source Ref. Thermometer

Temp.(F)

Thermocouple

Temp.(F)

Temperature

om. (%)

1 Ice Water 34 32 0.4%

2 Boiling Water 208 209 0.1%

3 Very Hot Oil Bath 351 352 0.1%

4 Ambient Temp. 62 62 0.0%

Average Temp. Change: 0.2%

Temperature Difference must be < 1.5 %

7

Date: fI /17/0"/
Type S Pitot Tube

Dimensional Specification Verification Form

• o' 0 • • '11 •

.... se@.o.

eeeeee ...

~':';:;:;;::'~ AirNova, Inc.. •• <i> '" (it @l 4!l ....----------""----------------------

-"GC!B ••••• o '

• 0 " e @l e ••. • e tI •

• e e e •

Pitot No.

Calibrator

Date 11/1' j1rf

Verify the following criteria and check all that apply

1) Face opening plane perpendicular to the transverse axis? _,........-_.._..

2) Face-opening plane parallel to the logitudinal axis? __----_.-

3) Are Legs A & B of equal len'gth and are centerlines coincident? /--

If all the above criteria are met, a pitot coeffecient of 0.84 may be assigned to

the respective pitot tube. If one of the following criteria above is not met, the

pitot tube must be calibrated in a wind tunnel.

Recommended Dimensions

4) Diameter of pitot tubing? (Dt) = " ?o ?5in. (0.1875 < Dt < 0.375)

5) Dimensions of Pa = .'5/ 0 in.

.c.'/ 6) Dimensions of Pb = ~./ U in.

PaiDt = 113?- (1.05 < Ot < 1.50)

Pb/Dt = /IJt, (1.05 < Dt < 1.50)

TRA/tSVERSE,' i TUBE AXIS •

.l.r=g._. ~O::;'~G~ • PlAnES •

(~

A~O(f\.A!l;(

,o,,<t",""'" ,f '-':?~=-.G:: J ::~<H'M'" nl"£V:Cl h......._--"-_.-.~_.l~~.l ",,_

~0{t1.AJil(

(101

f...
AirNova, Inc.

Pitot Thermocouple

Calibration data

Date: '11/17/09

Thermocouple 1.0. : AN-5H

Probe Length: 5 Foot

Calibrator KA

Ambient Temp.(F): 62

Barometric Pressure (" Hg): 30.10

Reference Thermometer: ASTM-2F

Reference

Point

Source Ref. Thermometer

Temp.(F)

Thermocouple

Temp.(F)

Temperature

Diff. (%)

1 Ice Water 33 34 0.2%

2 Boiling Water 211 212 0.1%

3 Very Hot Oil Bath 342 342 0.0%

4 Ambient Temp. 62 62 0.0%

Average Temp. Change: 0.1%

Temperature Difference must be < 1.5 %

Signature:

9

Date: iL/1 7/0 <1
Type S Pitot Tube

Dimensional Specification Verification Form

• .: 9 e '" '0 •

• .. lit " e e «< ••

• • @ e E'9 €!!I ID e G ".

oa@@I.0\lfle@<lI. A- N II'

• 0 l) l!il. G • 4!H\' G .--:...--:..:...:.:.I..=r--=-=--=O=-="=-a.-:......"..z...,~i-=n:....::.....;C=·:....:"'=-- _

··eo.l!ilOO .. •· ··Ge@~@@a··

... C& e @ • e III •

G • .. •

. " . " .

Pitot No.

Calibrator

Date H(17/(1

Verify the following criteria and check all that apply

(,.,..,.----~-

1) Face opening plane perpendicular to the transverse axis? _

c'~'

2) Face-opening plane parallel to the logitudinal axis? __c_'

3) Are Legs A & B of equallen"gth and are centerlines coincident? __----_--'

If all the above criteria are met, a pitot coeffecient of 0.84 may be assigned to

the respective pitot tube. If one of the following criteria above is not met, the

pitot tube must be calibrated in a wind tunnel.

Recommended Dimensions

4) Diameter of pitot tubing? (Ot) = .-:5 7J- in. (0.1875 < Ot < 0.375)

5) Dimensions of Pa = .f;"C(:' in.

/' " 6) Dimensions of Pb = I;;'" (/ in.

PaiDt = jlJJ (1.05 < Ot < 1.50)

Pb/Ot = I, iJ (1.05 < Ot < 1.50)

rRA~SVERSE" i WOE AXIS ,

.l.E9G9-_. I-O::;f~G -I . flAKES •

(,j'

A$f~'t,..1.tf(

'Q.<n.~OAl ,f '-'0~:=E I:f~<.<,...", ltnt:A.tdb--:---'--.-.;y_.l~~. ..... 1Ml0{ ft.A.4(

(hI
AirNova, Inc.

Dry gas meter & orifice

Calibration data and calculations

Meter Box #:

Checked with Pump #:

Date:

Calibrator:

5

5

'2/9/10

KA

delta H = 0.5 in. H2O

Pb = 29.97 in. Hg

Time = 19.0 min.

Std Test Meter Data Dry Test Meter Data I\H@i I\Yi

IVw= 487.046 IVd = 623.455 1.623 1.014

FVw= 494.825 FVd = 631.166

TVw= 7.779 TVd 7.711

tw = 58 ltd = 63

Ftd= 60

Avg. td = 61.5

---------------------

delta H = 1.0 in. H2O

Pb = 29.97 in. Hg

Time = 23.0 min.

Std Test Meter Data Dry Test Meter Data I\H@i I\Yi

IVw= 473.964 IVd = 610.560 1.679 1.019

FVw= 487.046 FVd = 623.455

TVw= 13.082 TVd 12.895

tw = 57 ltd = 62

Ftd= 59

Avg. td = 60.5

---------------------

delta H = 1.5 in. H2O

Pb = 29.97 in. Hg

Time = 15.0 min.

Std Test Meter Data Dry Test Meter Data I\H@i I\Yi

IVw= 463.755 IVd = 600.565 1.754 1.023

FVw= 473.964 FVd = 610.564

TVw= 10.209 TVd 9.999

tw = 55 ltd = 60

Ftd= 56

Avg. td = 58 Pg 1 of 2

11
Date: '2/9/10

AirNovCl, Inc.

Calibration Data MB#: 5

delta H =

Pb = Time =

2.0 in. H20

29.97 in. Hg

13.0 min.

Std Test Meter Data Dry Test Meter Data

IVw= 453.446 IVd = 590.535

FVw= 463.755 FVd = 600.565

TVw= 10,309 TVd 10.030

tw = 54 ltd = 57

Ftd= 53

Avg. td = 55

1.726 1,025

delta H =

Pb =

Time =

3.0 in. H20

29.97 in. Hg

12.0 min.

Std Test Meter Data Dry Test Meter Data

IVw= 441.774 IVd = 579.275

FVw= 453.446 FVd = 590.535

TVw= 11.672 TVd 11.260

tw = 53 ltd = 54

Ftd= 50

Avg. td = 52

1.724 1.027

delta H =

Pb = Time =

4.0 in. H20

29.97 in. Hg

8.0 min.

Std Test Meter Data Dry Test Meter Data

IVw=

FVw=

TVw=

tw =

432.758

441.774

9.016

51

IVd =

FVd =

TVd

ltd =

Ftd=

Avg. td =

570.645

579.275

8.630

50

49

49.5

1.707 1.032

Signature:

Avg.J\H@=: 1.70

12

Avg. Y =: 1.02

Date: 2/7~ Pg. 2 of 2
AirNova, Inc.

Calibration data and calculations

Meter Box Temperature Sensors

Meter Box #:

Date:

Calibrator:

Ambient Temp. (F):

Barometric Pressure ("Hg):

Reference Thermometer:

Dry Gas Meter Thermocouple -INLET

5

'01/05/09

KA

48

30.00

ASTM-2F

Reference Point

Ambient Temp.

Hot Water (104-122F)

Ref. Thermometer Thermocouple

Temp. (F) Temp. (F) Diff.

48 48 0

N/A N/A 0

Dry Gas Meter Thermocouple - OUTLET

Reference Point

Ambient Temp.

Hot Water (104-122F)

Ref. Thermometer Thermocouple

Temp. (F) Temp. (F) Diff.

48 48 0

N/A N/A 0

note: tolerance for inlet and outlet = +/- 5.4 F

Thermocouple connector/LED readout:

Ref. Thermometer Thermocouple

Temp. (F) Temp. (F) Diff.

1 Stack 48 48 0

2 Probe 48 48 0

3 Filter 48 48 0

4 Dryer 48 48 0

5Aux 48 48 0

note: tolerance =+/- 2 F

13

Date:
AirNova, Inc.

Dry gas meter & orifice

Calibration data and calculations

Meter Box#:

Checked with Pump #:

Date:

Calibrator:

10

10

'2/2/10

KA

delta H = 0.5 in. H2O

Pb = 30.05 in. Hg

Time = 19.0 min.

Std Test Meter Data Dry Test Meter Data I\H@i I\Yi

IVw= 228.386 IVd = 582.395 1.766 0.992

FVw= 235.845 FVd = 589.975

TVw= 7.459 TVd 7.580

tw = 61 ltd = 66

Ftd= 66

Avg. td = 66

---------------------

delta H = 1.0 in. H2O

Pb = 30.05 in. Hg

Time = 14.0 min.

Std Test Meter Data Dry Test Meter Data I\H@i I\Yi

IVw= 220.786 IVd = 574.700 1.847 0.995

FVw= 228.386 FVd = 582.395

TVw= 7.600 TVd 7.695

tw= 61 ltd = 66

Ftd= 66

Avg. td = 66

---------------------

delta H = 1.5 in. H2O

Pb = 30.05 in. Hg

Time = 11.0 min.

Std Test Meter Data Dry Test Meter Data I\H@i I\Yi

IVw= 213.258 IVd = 567.100 1.743 0.996

FVw= 220.786 FVd = 574.700

TVw= 7.528 TVd 7.600

tw = 61 ltd = 66

Ftd= 66

Avg. td = 66 Pg. 1 of 2

14
Date: '2/2/10

AirNovCi, Inc.

Calibration Data MB#: 10

delta H =

Pb = Time =

2.0 in. H20

30.05 in. Hg

11.0 min.

Std Test Meter Data Dry Test Meter Data

IVw= 204.824 IVd= 558.576

FVw= 213.258 FVd = 567.100

TVw= 8.434 TVd 8.524

tw= 61 ltd = 66

Ftd= 66

Avg. td = 66

1.852 0.994

delta H =

Pb = Time =

3.0 in. H20

30.05 in. Hg

10.0 min.

Std Test Meter Data Dry Test Meter Data

IVw= 195.491 IVd = 549.210

FVw= 204.824 FVd = 558.576

TVw= 9.333 TVd 9.366

tw = 61 ltd = 65

Ftd= 65

Avg. td = 65

1.878 0.997

delta H =

Pb = Time =

4.0 in. H20

30.05 in. Hg

10.0 min.

Std Test Meter Data Dry Test Meter Data

IVw= 184.630 IVd = 538.324

FVw= 195.491 FVd = 549.210

TVw= 10.861 TVd 10.886

tw = 61 ltd = 63

Ftd= 63

Avg. td = 63

---------------~-----

Avg.AH@=: 1.82

Signature: /t..1/

J4IAU/.:L

d aU15

1.857 0.992

Avg. Y =: 0.99

Date: .2/2-/10

Pg 2 of 2
AirNova, Inc.

Calibration data and calculations

Meter Box Temperature Sensors

Meter Box#:

Date:

Calibrator:

Ambient Temp. (F):

Barometric Pressure ("Hg):

Reference Thermometer:

Dry Gas Meter Thermocouple A INLET

10

'2/2/10

KA

73

30.05

ASTM-2F

Reference Point

Ambient Temp.

Hot Water (104-122F)

Ref. Thermometer Thermocouple

Temp. (F) Temp. (F) Diff.

73 72 1

101 101 0

Dry Gas Meter Thermocouple A OUTLET

Reference Point

Ambient Temp.

Hot Water (104-122F)

Ref. Thermometer Thermocouple

Temp. (F) Temp. (F) Diff.

N/A N/A 0

N/A N/A 0

note: tolerance for inlet and outlet =+/- 5.4 F

Thermocouple connector/LED readout:

Ref. Thermometer

Temp. (F)

Thermocouple

Temp. (F)

1 Stack

2 Probe

3 Filter

4 Dryer

5Aux

73

73

73

73

73

74

73

73

73

73

1

o

o

o

o

note: tolerance =+/- 2 F

16