®-BORAL BRICKS, INC. 

500 Northridge Road • Suite 300 

Atlanta, GA 30350 

Telephone 770-645-4500 • Facsiniile 770-645-2888 

www.boralbricks.com 

II--D-105 

April 10, 1998 

Bruce C. Jordan, Director 

Attn: Bill Neuffer 

Emission Standards Division (MD-13) 

U. S. Environmental Protection Agency 

Office of Air Quality Planning and Standards 

Research Triangle Park, North Carolina 27711 

Subject: MACT Infonmation Collection Request Response 

Submittal for Boral Bricks, Inc. 

Dear Sirs: 

Boral Bricks, Inc. is pleased to submit the enclosed completed Structural Clay Products MACT 

Information Collection Requests for its remaining 6 facilities. These 6 ICRs complete Boral's submittal 

which totals 18 facility locations. 

As before, we would like to stress that Boral Bricks is committed to working with EPA to help develop 

an appropriate MACT standard for our industry. To this end, we have chosen to complete Enciosure 2, 

believing that it provides the most focused, industry specific information available. It should be noted 

that in completing the ICRs we have used the best available information for each of our facilities. While 

most of Boral's understanding and subsequent completion of Enclosure 2 was developed from the 

instructions provided by EPA, several items required further clarification and interpretation. Many of 

these items were discussed with Mr. Bill Neuffer through our environmental consultant, Mr. 011ie Fick 

with CH2M HILL. Although these items are highlighted in the completed ICRs, there are several that 

warrant specific mention in this letter. They are as follows: 

Based on a February 25, 1998, telephone conversation between Mr. Fick and Mr. Neuffer, Boral 

understands that details on fugitive emission sources need not be included in the ICR unless there is 

specific test data available to support emission estimates. 

The HAP emission infonmation requested in Table 5 is being submitted through the enclosure of 

source test and mass balance data (Appendix B). As allowed in the Enclosure 2 instructions, Boral 

considers the submission of relevant sections of applicable data to be preferable to providing 

emission estimates. Boral has reviewed all applicable and available data and has excerpted those 

sections relative to HAP and HAP surrogate emissions to include in Appendix B. EPA will note, 

however, that the quality and consistency of the data and supporting documentation varies widely 

among the various plants and states. This is largely because environmental affairs for many Boral 

facilities has been historically managed at the plant level. This has only changed within the last 2 

years. 

BRICKSTUDIO. / 

n~~~sowu srt~cKs 
~VIr. ,Bruce Jordan 

April 10, 1998 

Page 2 

Where appropriate, Boral has used Title V permit application information in completing the ICRs. 

However, Boral believes that the methods used to estimate emissions for penmitting purposes are 

different from those necessary in the development of a MACT standard. Therefore, the emission 

estimates used in the Title V applications are not included in the ICRs except where actual plantspecific data was available. 

Boral is in agreement with the Brick Industry Association in their recommendation not to use the 

AP-42 emission factors to estimate emissions. Once again, we consider these factors to be 

inappropriate for use in the development of a MACT standard. 

We very much appreciate Mr. Neuffer's time and assistance in answering our questions and providing 

further clarification where needed. Boral Bricks looks forward to working with EPA during the 

interpretation of the enclosed ICRs and the future. development of the MACT standard. 

If you have any questions or comments please feel free to contact Mr. David Johnson at (334) 480-2487 

or me at (770) 645-4500. 

Sincerely, 

,&w~ ~~ / 

Edward M. Thebaud 

Vice President - Manufacturing 

cc: Dennis Brown 

David Johnson 

Mary Ann Keon 

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MACT Information Collection Request Response 

from 

Boral Bricks, Inc. 

Table of Contents 

• Information Collection Request 

• 

• Appendix A - MSDS's 

• Appendiz B - Test Data 

1l 
Enclosure 2 

INFORMATION REQUEST FOR BRICK AND 

STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS 

I. Instructions 

Please return the completed information request to: 

Bruce C. Jordan, Director 

Attn: Bill Neuffer 

Emission Standards Division (MD-13) 

U. S. Environmental Protection Agency 

Office of Air Quality Planning and Standards 

Research Triangle Park, North Carolina 27711 

If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at 

(919) 541-5435. 

This information request should be completed for each facility that manufactures brick and 

structural clay products, including facilities that are not major sources. Information is 

requested for all processes at your plant that emit hazardous air pollutants (HAP's), 

including those processes that are not associated with brick and structural clay products 

manufacturing. Sections II through VII request information specific to brick and structural 

clay products manufacturing, and Section VIII requests information on emissions of HAP's 

from other processes located at the facility. Processes that may emit HAP's include those 

processes that use or handle any materials that contain a HAP compound, all processes with 

elevated temperatures, and all other processes in which HAP compounds may be formed. The 

HAP list from Section 112(b) of the Clean Air Act is included as Attachment 1 to this 

information request. Atta.chment 2 provides background information on the requirements of the 

Clean Air Act and explains how the information requested in this questionnaire will be used by 

EPA. Attachment 3 is a list of abbreviations and acronyms used in this information request. 

Several tables are provided throughout the information request for your convenience in 

answering the questions. An example response is given (shaded first column or row) in each 

table. If additional space is needed to respond, please make copies of applicable pages. If 

necessary, please make copies of this information request for additional facilities. No 

additional emission testing or monitoring is required to respond to this request. 

amm-71M.!oi •!1!•F •! 

A. Name of company Boral Bricks- Inc. 

Name of facility Marshall Plant 

Page 1 of 29 

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Facility address: 

No. and street 1902 N. Franklin St. 

City Marshall State TX_ Zip 75670 

Latitude and longitude coordinates of plant: 32 033'35" 94022'05" 

Standard Industrial Classification (SIC) Code(s) of brick and structural clay products 

manufacturing operations 3251 

Dun and Bradstreet No. 00-327-5682 

Total No. of employees for company > 1,500 for facility 36 

(If facility is a foreign subsidiary or if company has foreign subsidiaries, include 

number of employees not based in the U.S.). 

Please complete the following shift information for the facility: 

Shift No. of employees Hours per shift Days per year 

1 34 9 260 

2 1 (kiln operation) 8 365 

3 1 (kiln operation) 8 365 

B. Respondent name Guiomar Obregon 

Respondent title Anal,yst 

Respondent address (if different from above) and telephone number: 

• . • street 500 Northri dge C•,d Suite 300 

City Atlanta State GA_ Zip 30350 

Telephone No. ( 770 ) 6454500 

Name and telephone number of technical contact person (if different from above) 

Name David Johnson Telephone No. (33A) 480-2487 

~ •r~~. •~ •~ ••- ~ • •_• ~~ ..~• ~ •• .• - -.- ~~ •~ _ ... ~ .._ ~ 

A. Please provide copies of relevant parts of all operating permits and permit 

applications for your facility. Relevant parts include the sections that provide 

specific information and data on: processes that emit HAP's; the use of HAPPage 2 of 29 

67 
containing substances; emission levels for HAP and surrogate pollutants (i.e., VOC 

for organic HAP's and PM for metal and other particulate HAP's); emission control 

device design and operation; monitoring and operation and maintenance (O&M) 

procedures for control devices; and generation and releases of other media such as 

wastewater and solid waste that are associated with the operation of air pollution 

controls for brick and structural clay products manufacturing processes. 

If the operating permit or application contains the same information requested 

in any part of this questionnaire, you may respond to the requested information 

by referencing the page or section of the permit/application to avoid 

duplication. If you reference your permit or application, you must supplement your 

response with all of the additional information requested in this questionnaire that is 

not included in the permit or permit application. If you prefer, you may submit the 

requested information from your permit/application on a 3-1/2 inch diskette. 

B. If any source or emission unit at this facility is subject to a New Source Performance 

Standard or other Federal emission standard, please identify the source and 

applicable standard. Examples of applicable NSPS include 40 CFR 60, 

Subpart 000 - Standards of Performance for Nonmetallic Mineral Processing 

Plants, and 40 CFR 60, Subpart UUU- Standards of Performance for Calciners and 

Dryers in Mineral Industries. 

' 1M, = ~ ~ M "t M . 

~~~~~ •~ 

A. Please provide the 1997 production rates and the current production capacity for 

each type of brick and structural clay product manufactured (e.g., structural brick, 

clay sewer pipes, structural clay tile, etc.). Note that production data should be 

provided in units of tons per year (tons/yr). 

Product 1997 production (tons) Production capacity (tons/yr) 

Brick (fired weight) 63,222 66,845 

Page 3 of 29 

7 
B. Please proviciU the type and amount of each raw material and body additive used in 

1997 for m_,~ n}afacturing 4.; r ick and structural clay products at your facility. Examples 

include clays, shale, and a.ny additives that are mixed into the raw material prior to 

forming. Indicate additives by chemical compound, rather than by trade name. If 

the information requested is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than providing the information 

below. 

Raw material/body additive Amount used in 1997 (tons/yr) 

Clays (wet weight) 76,000 

Iron oxide (dry weight) 110 

Manganese (dry weight) 

~ 

35 

C. If available, please provide a copy of the MSDS's for the raw materials and additives 

listed above. 

See Appendix A 

D. If available, please provide chemical analyses, including fluorine, metals, and 

organic content, of the raw materials listed above. 

See Appendix B(Raw material analysis) 

Page 4 of 29 

0 
E. Using Table 1, please provide information on the consumption and HAP 

composition of all glazes and colorants that contain HAP's or HAP precursors and 

that your facility applies to brick and structural clay products. Indicate whether the 

coatings are glazes or colorants. Also indicate the type of product that the coatings 

are applied to and the total weight of coatings used in 1997. If the glazes or 

colorants are formulated at your facility indicate so and provide the production 

capacity. List each ingredient of the glaze or colorant. Beside each ingredient, 

indicate the total amount of the ingredient used in 1997. If the information requested 

in the table is contained in your facility's operating permit or permit application, you 

may reference the applicable sections of the permit (or application) rather than filling 

out the table. 

F. In the space below, please indicate any glazes or colorants used by your facility that 

do not contain HAP's and are substitutes for HAP-containing glazes or colorants 

used by your industry. Indicate which HAP-containing materials the non-HAP 

glazes or colorants replace. Describe any limitations on the use of those substitute 

glazes or colorants. 

G. If your facility colors brick and structural clay products by flashing, please indicate 

the types of substances used to flash the products and the amounts of those 

substances used in 1997. 

H. If available, please provide a copy of the MSDS's for the glazes and colorants used 

by your facility. If your facility prepares its own glaze, please provide any available 

MSDS's for the glaze ingredients. 

See Appendix A 

Page 5 of 29 

0 
TABLE 1. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND COLOR.ANTS 

the table is contained in your facility iperating permit or permit application, you may reference 

the applicable sections of the permit (or application) rather than filling out the table. 

Page 6 of 29 
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A. Please provide a simple process flow diagram for each brick and structural clay 

product manufacturing process line. An example process flow diagram is provided 

in Figure 1. A diagram of the plant layout with all processes and emission points 

clearly labeled is also acceptable. 

Assign a unique identification number (ID No.) for each process that has 

associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. 

Please identify aU emission points, including those that do not emit HAP's. For 

emission points that are vented to an air pollution control device (APCD), assign an 

ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are 

uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof 

vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information 

request for any responses that pertain to any process or emission point. 

Page 7 of 29 

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capacities, and related information for each type of equipment used in brick and 

structural clay product manufacturing. In Table 2A, provide the requested 

information for only those sources that are known or expected to emit HAP's. In 

Table 2B, provide the requested information for all thermal processing, such as 

drying and firing sources. For combustion sources that use different fuels, Table 2B 

should be completed for each type of fuel. For example, if a kiln typically is fired 

with gas, but periodically is fired with oil, one column in Table 2B should be 

completed for the kiln when fired with gas, and another column should be completed 

for the same kiln when fired with oil. Provide the data in the units listed for each 

row. 

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process operating rate for each of the pieces of equipment and HAP emission 

sources listed in Tables 2A and 2B. Use the same HAP emission source types and 

equipment ID numbers you listed in Tables 2A to 2B. 

• Indicate whether you monitor process rate or not. 

• Provide a summary of process rate monitoring procedures that 

describes how process rate is measured for the particular piece of 

equipment. Include where the rate is monitored (i.e., rate of material fed, 

rate of material discharged, or material production rate), the units used to 

measure process rate (e.g., lb/hr or pieces/hr), and how the process data is 

recorded, i.e., manually, automatically (e.g., computer - printout or stored 

to disk, or not at all). If you monitor process rate at both the feed and 

discharge ends of the equipment, indicate so. 

Indicate the type of monitor, equipment, or instrument used to measure 

process operating rate. 

Indicate the monitoring frequency or how often process rate 

measurements are made. 

If instruments are used to measure process throughput, indicate in the 

monitor accuracy column the accuracy of the instrument. The monitor 

accuracy could be listed in terms of a percentage of the throughput 

(f 1 percent), mass per unit time (f21b/hr), number of pieces per unit time 

(f 10 pieces/hr), or other appropriate units. 

• Indicate the frequency that the monitor is calibrated. 

• Provide data in the units listed for each row. 

Page 13 of 29 

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A. Use the process flow diagrams developed for your facility and Table 4 to provide 

the following information for each HAP emission source at your facility. 

' Define HAP emission source type in terms of equipment, such as dryers, 

kilns, etc. As in the process flow diagram, you may group multiple pieces of 

similar equipment. 

' Use the same equipment ID numbers indicated on the process flow 

diagram(s). 

' If the emission source vents inside a building or to outside ambient air without 

first passing through a control device, place a check mark in the uncontrolled 

column. 

' If the emission source vents inside a building or to outside ambient air after 

passing through a fabric filter, dry injection fabric filter, or scrubber, place the . 

APCD ID number(s) in the column corresponding to the APCD type. 

' If the emission source vents through a control device type not listed in 

Table 4, indicate the control device type in the other control column and place 

the APCD ID number in the appropriate cell. 

' In the emission test data column, place a"yes" or "no" in the appropriate cell 

to indicate whether the specific source has been tested for any pollutants, 

including any HAP's, VOC, PM, or opacity. 

Page 15 of 29 

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B. Using Table 5, please provide information on stack parameters and emission 

estimates for each emission point at your facility that is known or expected to emit 

HAP's. Provide information for all APCD's, including those that exhaust inside the 

building. Include data for each inlet and outlet, if available, as indicated in the 

table. If you have more than one inlet to an APCD, provide data for each of the 

inlets. Provide data in the units listed for each row. 

Provide emission estimates for any HAP's or HAP surrogates, such as PM for 

metal HAP's or VOC for organic HAP's. Emission estimates may consist of 

measurements reported in emission test reports or may be calculated using mass 

balances, emission factors, engineering judgement, or other estimation methods. 

Provide the emission estimates as emission factors in units of lb of pollutant 

emitted per ton of product (lb/ton). Provide complete copies of any emission test 

reports or other reports that document measurements of emissions. Test 

reports and other emission measurement documents should include the following 

information: process identification; location of sampling point; stack diameter, 

temperature, and flow rate; test method, including analytical procedures; number 

of test runs; emission concentration, emission rate, percent oxygen, and percent 

moisture for each test run; process operating rate; type of APCD; and APCD 

operating parameters. However, test reports with incomplete documentation may 

still be useful and should also be submitted. 

You do not need to fill out Table 5 for emission points that are covered by an 

emission test report that is included in your submittal. If emission test reports are 

not available, provide calculations that support your emission estimate, 

including the basis for all assumptions in the estimate. Note that emission 

estimates are needed for all HAP's that the facility emits or has the potential to 

emit. (Please refer to the HAP list in Attachment 1.) If the information requested 

in the table is contained in your facility's operating permit, you may reference the 

applicable sections of the permit rather than filling out the table. 

Page 17 of 29 

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191 
C. Using Tables 6A through 61), please provide design and operating data for each 

APCD associated with all dryers, kilns, and any other brick and structural clay products 

manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of 

APCD's. Use Table 6D for other types of APCD's. When using Table 6D, please 

specify the type of control device and 2 to 4 key design or operating parameters for the 

device. Provide data in the units listed for each row. If the information requested in 

Tables 6A through 6D is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the tables. 

Page 20 of 29 

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m 
D. Using Table 7, please provide the following information on current monitoring 

procedures for each of the control devices listed in Tables 6A to 6D: parameters 

monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices 

used (e.g., differential pressure transducer, thermocouple), and recordkeeping 

practices (e.g., manually recorded in log book, continuously recorded by electronic 

data acquisition system). Describe briefly other operation and maintenance (O&M) 

procedures for each control device. If the information requested in the table is 

contained in your facility's operating permit, you may reference the applicable sections 

of the permit rather than filling out the table. 

e -siumfm e C Mm--ro ! - ~ t- i.m wsm- - U ,-ro - Fm 

A. Please describe all pollution prevention practices (i.e., process modifications, such as 

re-use of discarded or rejected materials, or any practice that prevents or reduces the 

amount of air emissions, or the generation and release of solid waste or wastewater 

associated with the operation of air pollution controls). If the information requested 

here is contained in your facility's operating permit, you may reference the applicable 

sections of the permit rather than providing the information below. 

Page 25 of 29 

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kvill • • ! • 1!! • • ! • ! • - ! " ! ~ _! ~ • . ~ _! ! . ~ ._ _ • • ~ , ~ ~ _i . i. 

• - - 

A. Using Table 8, please identify all other processes or operations at this facility that are 

not addressed in Items II through VII above and that are potential sources of HAP 

emissions. Estimate total annual emissions of each HAP emitted by these collocated 

processes. If the information requested in the table is contained in your facility's 

operating permit, you may reference the applicable sections of the permit rather than 

filling out the table. 

Page 28 of 29 

'3Z 
TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCES 

Process/emission source/SIC Code(s) HAP's emitted I Estimated annual emissions, 

tons 

Vehicle Maintenance and Refueling in 

Support of Brick Operations--- Vehicle 

maintenance and refueling in support of 

Boral Brick's manufacturing and sales 

operations take place at this plant but are 

not otherwise identified or reported in 

this ICR because there is no emission 

data. 

No Data I Not Applicable 

SIC 3251 

Quality Control Testing Lab in Support c 

Brick Manufacturing-- A small quality 

control testing laboratory operation takes 

place at this plant but is not otherwise 

identified or reported on this ICR 

because there are no emissions data. 

No Data I Not Applicable 

Page 29 of 29 

2 
/ 

RARSIIAW/FI I.TROL 

NATERIAL SAFETY DATA SIiEET 

CODE : 541-032 

I'1tUUUCT NAME 

L-6570 Yellow Body Stain, 

11-33-84-WP DATE: 09/23/86 

-- SECTION I -- IDENTIFICATION 

SUPPLIER'S NAtlE Harshaw/Filtrol Partnership 

ADDRESS30100 Chagrin Blvd. 

Cleveland, Oltio 44124 

CAS'No. 68186-90-3 

U.N. No.Not applicable 

D.O.T. CLASSIFICATION.Not regulated 

EHfiRGENCY TELEFI(ONE 216/292-9200 

CIEENICAL NAMEChrome Antimony 

Titaoium Buff Rutile; 

C.I. Pigment Brown 24 

FORtiULAC. I. 77310 

---SECTION II -- 1(AZARDOUS INGREDIENTS OF HIXTURES 

Ha terial orCom p nent o

Crystalline quartt 

114808-60-7j** 

Chromium III oxide as Cr 

[ 12018-01-8 1*e 

Antimony oxide as Sb 

112036-21-4 [+* 

Titanium oxide 

113463-67-71*-h 

**See Section V. 

T11RES1fOLD LIHIT VALUE 

ACGIN, 1986-67* OSIIA PEL* 

Proprietary 0.1 mg/m 3 , 0.59 mg/m 3 6 

reapirable reepirable 

Proprietary 0.5 mg/ma i mg/m 3 

Propcietary 0.5 mg/m 3 0.5 mg/m3 

Proprietary 5 mg/m3 0 15 mg/m 3 

reepirable 

*Unless otherwise noted, all values are reported as Time-Weighted Averages (TWA'3)1,' 

and total dust (particiilatea only). 

~~• SECTION III -- PHYSICAL DATA 

BOILING POINT Not applicable HELTING POINTNot appliCable 

SPECIFIC GRAVITY (1120=1) Not available VAPOR PRESSURE Not applicable 

VA'POR DENSITY (Air=1) Not applicable SOLUBILITY IN H 20 (% by Wt.) Insoluble 

~ VOLATILES BY VOLl1ME Not aliplicable E_VAPORATION RA1'E(Dutyl Acetate=l) 

Not applicable ' 

APPEARANCE AND ODOR Fiiie yellow-buff pouder; odorless 

' SECTION IV -- FIRE AND EXPLOSION DATA . 

Not a tire or explosion,hazard. 

SECTION V-- 11EALTII 1LAZARD DATA 

THRESIIOLD LIHIT VALUE (_TLV)/ PERHISSIBLE EXPOSURE LIHIT (P_EL) 

See Section II above. These valuea maynot be applicable ae the 

constituents are homogeneously and ionically interdiffused to form 

a cryatalline matrix of r itile. 

F~ 

3`~ 
EfEfCTS UF 0VF.tif;Xrf)SUnF, 

Eye cantect 

_ 

cniiArn 1ritat inn. 

in eontact c:rusps irrftat-I.nre; ltching And allergic reactions are posqible. 

nIs al!tion rnnnem Irrllnl lt+rs rir the r.•wplratery trnct anol mINy cnuee 

dl.eabling, progressiva prrlmonnry fibrosis due to .the free cluartz silica. 

Symptoms incllide cough, dyspnea, wheezing, and impairment of pulmonary 

functioh. Progression of symptoms can continue efter dust exposure ceasea. 

In es g tionis harmEul. 

Note : AlthouRh indastriAl handling of this product has been good, the 

toxicological properties have not been flllly investigated. 

Chronic : Chromium and certain compounds have been lieted at+ carcinogenic, 

both in'animals and humnns by'the National Toxicology Program (NTP) and the 

International Agency for Research an Cancer (IARC). Some Cr (VZ) compounds 

are identi(ied as lurig ctrrinogens by toxicological studies. F,vidence of 

Cr(III) comporind carclnogenicity in animale and hrAmens ie inconclusive. 

This product contains Cr (II1). 

Chronic : Long ter+rt inhalati.on studfes indicate antimony oxide cauaee 

m+llignant lung tumors in lahoratory rats. 

EltERGENCY AND FIAST AID PROC EDURES 

Eye end Skin cv_nt __.____.._.... ac t: [mmi-riintely Ei.ueh Pyee aith water to remove perticlea. Cell a 

physiciart if irritrtion develops. Wash skin with soap and water. 

Inhalation: Remove tn freah nir. IE breathing is difficult., give oxygen. Cail 

a physician. 

— nATE: 09/23/86 --- SFCTION VI -- REACTIVITY DATA CODF: 54I-032 = 

vDITI0N9 CONTRIBUTING TO INSTABILITY None expected 

AaCOMPATIBILIT4 None exl+ectetl 

IlAZARDOUS DECOLIPOSITION PRODUC rS None expected. ` 

°— -SFCTION VIL -- SPILL OR LEAK PROCF,DURES - - — 

eTEPS TO BE TAKEN IN CASE MATERIAL is RELEASED OR SPILLED 

Contain spillage end scoop up or vacuum. Avoid dusting. Notification of the National ' F • Reaponse Center (800/424-8802) may be reqisired. Refer to EPA. DOT and applicable 

atate nnd local reqltlations tor cur,rent response information. 

It is recomnlended that each user establish a spill prevention rconttol and 

collntermeenure plen (SPCC). Slich plan ahould include procedures applicable to proper 

stor.nRe, control and clearr-up of spills, including reuse or dinposel as nppropriate 

(see wgqte dispos;rl methrir,l, iiclow). 

WASTE DISpOSAI. PIETIIUD Fecler:rl, st:ite anel local di.sposal laws and regulations will 

determine theproper ~waRte riisposal procedure. A7,1 waste materials should be reviewed 

to determine tlle applicah.le haxards (testing may be necessary). Disposal reqrrirrments 

are dPpendent on tlle hnzar.d classifitation and will vary by Iocatiort and the type oE 

disposal selecterl. Some: aastp materials are amenable to recycle/reuse. 

- --" -- SECTiON VIII -- PROTECTIVE EQUIPMENT 

VENTI LATION Ceneral•; local exliauat ventilation es necessary to control dust. 

PERSUNAL E'ROTECTIVE EQtI_IPNENT Cliemical goRgles. _.---- Gl.oves 

A NIOSiI/MSiIA approvcd sespirator as necessary 

Borly protection as necessary to prevent skin contact. 

~./ 

Vn7xQ 7H}Tf)4 al4efii QF—j-A—ttv 

T1,n71 7c-rtT 
~ 

----- --- SEC3'IUtV IX -- SPECIAL PRECAU -tIONS 

Avoid breathing dust . 

Wash thoroughly after hindllnR . 

Avoid contact with eye4, skin and clothing. 

Keep container closed. 

Keep awsy from foocl and feed products. 

Use with adegitate ventitation. 

-- - -- - - ~ ~ ~~~ ~~~----- SFCTION X -- PF.RSONNF.L SANPLING PROCEDURE — ~ , 

For metallic componenta: Refer to N10S11 Manual 4f Analytical Nethods, 3rd Edition, 

Volume 1, lletfioc! 7300. 

Information pcesented lierein It ~ s been compiled from sourcee considered to l)e dependable 

and is eccurate acod reliAble to the beet of our knowledge and belief but is not guaranteed to be eo. Slnce tonditions of use ere beyond our control, we make no warranties, 

expreRsed or implied, except those that may be contained in our written contract of 

eale or acknowledgement. 

DATE; 09/23/H6 CODE: 541-032 

" PRODUCT: L-6570 Ye11oW Body Stain 

! 

fip.,T T4,0717C-nT 1f"T1fQ RN?fflQ O1M'i~ T 
F" - Material Safety Data Sheet 

Substance Identification 

r ntity : MANGANESE DIOXIDE cas #: 1313-13-9 

, rade Names: 13rlckox, GranuSpeck 

.. .. 

. . 

. . . 

Manufaclurer: The Prince Manufacturing Co. Emergency: Chemlrec 

One Prince Plaza 1-800A24-9300 

Quincy, IL 62301 

217-222-8854 

Component.s and Contaminants 

Chgrmlcal Name: V4,g,S 0 SZ§J-IA PEL AGGIfi TLV Percent 

Manganese Compound ( as Mn) 7439-96-5 5 mg/O (C) 5 mg/m' (C) 51-55% Mn 

Iron Oxlde 1309-37-1 -- -- 1-5% FeZO, 

Sllica. Crystalline Quartz (respirable) 14808-60-7 0.1 mglm3 0.1 mglm' (TWA) 1-5% SiOz 

Aluminum Oxlde (non-Gbrous) 

(respirable fraction) 1344-28-1 5 mg/m' 5 mglm~ (TWA) 1-7% AI203 

Barium Oxide 1304-28-5 --- --• 0,2-2% Ba0 

Physicai Data 

8olling Point: NA Speciflc Gravity (Ha0=1): 5.0 

Vapor Pressure (mmlHg): NA Melting Point: 535° C 

Vapor Denstty (Air—fl: NA Evaporatlon Ftate (Butyl Acetate=l): NA 

Solubllity In Water: Insoluble 

Appearance and Odor: black to-brownish black, no odor 

Fire and Explosion Hazard Data 

sh Pointt Not cornbUstlble 

,.ammable Limlts: LEL NA UEL NA 

ctinguishing Medla: Foarn, CO2 , dry chemical or water. 

Qpecial Fire Pighting Procedures: In the event of fire, wear ftll) protective clothing and NIOSH-approved 

seif-contained breathing apparatus with full face piece operated in the 

pressure demand or other positive pressure mode. 

Unusual Fire and explosion hazards: Not combuslible, but substance is a slrong oxidizer and its heal of 

reaction with reducing agents or cornbustibies rnay cause ignition. 

Increases the ftammability of any combustible substance. 

Reactivity Data 

Stabllity: Stable under ordinary conditions of use and storage. T 

Conditions to avoid: Do not heat or grind In the presence of easily oxidizabie subslarices or 

organic matter. 

Incompatlbility (rnaterials to avoid): Easily oxidizable substances, sulfur, suifides, phospliides, 

hydrophosphides, chlorates, peroxides, aluminum powder, rubidium 

acetylide, potassiur'n azide, chiorine triCluoride. Reacts with 

Itydrochloric acid lo form corrosive chlorine gas. 

Hazardous Decomposition or Byproducts: Upon heating it decomposes to form manganese sesquioxide and 

oxygen which facilitates combustion. 

Hazardous Polymerizatfon: Vlfill not occur. 

Health Hazard Data 

Route of f=ntry: INHALATION: May Irritate the respiratory tract. May increase the 

incidence of upper respiratory infections (pneumonia). Prolonged 

exposure to silica dusl may result in siticosis, a ribrotic lung disease. 

SKIN: May cause irritation. 

, INGESTION: May cause abdominal pain and nausea. Manganese 

dioxide dust Is poorl absorbed through lhe gut. 

07 

Manganese Dioxidi, Pop: t 

1zeYiewed Juiy 1996 Unchangcd sincc Julv 1+>, ~ 
Health Hazard Data 

i Hazards (Acute and Chronlc): Chronic exposure and inhalalion of excessive manganese dust may cause 

disorders of the central nervous system. 

inogenicity: NTP: No IARC Monographs: Yes (Silica) 

Signs and Symptoms of Exposure: Early symptoms of manganese loxicity include sluggishriess, sleepiness. 

and weakness in legs. Syrnptoms of silicosis include impaired pulmonary 

function and wheezing. 

Aggravation of Pre-exlsting Conditlons: Persons with Pmpaired respiratory function may be more susceptible to the 

effecl of this substance. 

Emergency and Flrst Aid Procedures: IF INHALED, remove to fresh'air and seek medical altenlion for any 

breathing difficulty, 

IN CASE OF SKIN CONTACT, wash with soap & waler. Seek medical 

altention If red 8 irritated. 

IN CASE OF EYE CONTACT, flush eyes immediately wilh water for at leasl 

15 minutes. Seek medical atlenlibn If irritatfon persists. 

IF INGESTED, induce vomiting irnmedialely by giving two glasses of water 

and sticking ftnger down lhroat. Never give anylhing by nioulh to an 

unconscious person. Call a physician immediately. 

Precautions for Safe Handling and Use 

Material Release or Splll Precautlons: Should a spill occur, ventilate area. Clean-up personnel require respiralory 

proteclion. Recover unconlamEnated material for use. Vacuum or sweep 

remaining malerial, keeping dust to a minimum. Isolate wet material from 

dry and store away from combuslibie materials. • 

Waste Dlsposal Method: Dispose of unreciaimable material In a-RCRA-approved waste facility. 

Handling and Storing Precautions: Manganese dioxide is classifred as an oxidizer and should be stored in a 

dry place away from combUsilibes and sources of high heal. Protect 

conlainers from damage and keep closed when not in use. 

o.l►—c Precautlons: Obserye ood personal hygiene. Wash after handling, 

Control Measures 

Respiralory Protectlon: Use NIOSH approved particulate respirator if dust generalion occurs or is 

anlicipaled. OSHA standard 1910.134 or ANSI Z86.2-1980 specifications 

are recommended. 

Ventilation: A system of local and/or general exhaust is recommended to keep 

employee exposures below the Airborne Exposure Limils. Local e -•:hausl is 

generally preferred because it can control the emissions of the contaminant 

at its source, preventing dispersion of it inlo lhe general work area. Please 

refer to the ACGIH document, "Industrial Ventilalion, A Manual of 

Recommended Practices', most recenl edilion, for delails. 

Protective Gloves: Yes 

Eye Protection: Safety goggles are recommended. 

Other Protective Clothing or Equlpment: Use olher prolective equipment when necessary in order lo avoid 

prolonged exposure lo skin. 

Work and Hygienic Practices: Observe good personal hygiene. Wash after liandling. 

SARA Titte III Section 313 Supplier Notification 

'rhis product contains the following loxic chemicals subJect lo the reporting requiremenls of section 313 of lhe Emergency 

Planning and Communily Rlght-to-Know Act of 1986 and of 40 CFR 372.45: 

Corroonent CAS # % by Weiglit 

Manganese Dioxide 1313-13-9 51-55% Mn 

Barium Oxide 1304-28-5 0.1-1.6% [3a 

T,. nformalion must be Included In all MSDS's thal are copied and dislributed for lhis material. 

~ 

' Mhun6aocsc Uioxid.. t'agc Z 

n ~ , s - L^ ~ ~^ ~ - lirei ~w~ d hJv In ~ R_ Iln~l~~ nurrl cinrr lul ~ ' I ~~ G _ 
APR-el2-1 ~9~ 12:51 BUR(-1L BRiCKS J 334 480 2415 P.02/03 

. ~ 

TEXAS AIR CONTROL BOARD 

LABORATORX 

6330 Nighway 290 Easti 

Austin, Texas 78723 .•t+;j 

ACL Number: 3491 Status: complete Priority: standard 

Property Sampled: Henderson Clay Products, Inc. 

Addres,: P. 0. Hox 1129 Henderson, Texa3 75653' 

City: Marshall County: Harriaon Region: 12 

Sampled by: George F. Daugherty Date Samplea: 4-18-84 

Adjacent Sources: no 

Number ot samples: 7 Number of reference aaMples or blanks: 0 

Analy3i9 ReQuested: total fluorides, total sulfur in weight percent 

Number of 9amp1e3 received: 7 Date ReceYved: 4-27-84 

Number of reference samples or bianks received: 0 

Conditfon: o.k. 

Assigned to: Vince Anselmo As9igned Qy: John Key 

Analyais to be performed: total fluorides d: total.suifur percent 

If transferred between sectiona, Date Tranaferred: 

By: To: 

Date Analysi9 Completed• 07- ~ 03-8Y { !,` 

Analysis Per!'ormed by: Juan J. Rios and Nilliatt White ~ ' _~~~ I',~ 

. . 

Date Reported: ,07-11-8 4 ~

/"^~''~ 

Approved by: Maxine Jenka e~ 

Deacription of Samplea: 5 plastic baga- c wi inside label as fo lows: 

1. white clay from Bell Cutoff Rd, pit 

2; white sand from Bell Cutoff Rd: pit 

3. red clay from Macadonia Rd. pit 

u: iron oxide sand from Macadonia Rd. pit 

S. broken grog (fired brick) 

2 formed bricka 

1. one fir•,ed (t'inished) brick 

2; one green (unt'ired) brick 

Nhy were the samplea taken? 11hat do you hope to learn?: we are trying to learn 

amount of fluoride and sulfur in the materiala in order to estimate pooaible 

emis9ions when brieks are rired in kilns. A190 need to know which raw raaterials 

may have the awst tluoride & sulfur. 

Hou uill the analytical results be used? What act3on is depepdent on these 

resuita?: there•i3 a permit pending for a new brick kiln at this plant.. Would be 

very u9erul to have an idea of possible emis9ions: it' significant, we may 

require stack sampling. 

L~ 
APR-02-1998 12:51 BORAL BRICKS 0 334 480 2415 P.03iO3 

Laboratory Analysis 

Procedure: The sample9 were heated at 105 degree9 centigrade un'til dry. 

Sample9 yere crushed and eieved into 200 Mesh particles. A 

quantity of each sample tnat did not exceed one gram was placed in 

tared nickel crucibles. Ten mL of 5N sodium hydroxide was added. 

The crucibles were placed in an oven at 120 degrees Centigrade 

until the liquid evaporated. The crucibles were tnen placed in 

a£urnace and heated to 600' degrees centigrade and then cooled. 

The crucible content3 were taken into solution by adding 20 mL 

of distilled waCer and warming on a hot plate. 1'hree normal 

hydrochloric acid was added to bring the pH ot' the solution to 8-9. 

The solutiori was transferred to 100 mVpolypropylene volumetric 

flask and diluted to the mark with distilled water. The solution was 

filtered through dry Ulhatman No. 40 paper wnich removed interfering 

cations as insoluble oxides. A£luoride specific ion eleetrode wa9 

used to determine the concentration of.the standard solutions and 

the unknowns. Precision was measured with auplicate samples and the 

recovery ot the procedure was tested using spiked solution. 

Results: Fiuoride Analyeis 

Sample Micrograms fluoride/gram sample 

01 white clay l"rom Bell Cuto£f Road pit 123 

y2 white 9and trom 9e11 Cutort' Road pit' 109 

a3 red clay !'rora Macadonia Road pit 190 

u4 Lron oxide 9and t'rom Macadonia Road pit 226 

#5 Droken grog (rired brick) 22 

fired (finished) brick 16 

green (unfired) brick 274 

Precisiont 9% 

Recoverability: 104x 

MDL: 7 micrograms fluoride/gram sample 

Sulfur Analysie 

Procedure: The samples were pulverized, dried overnight ln a 50 degree 

Centi,grade oven and analyzed i'or sulfur with the LECO 132 Sulfur Determinator. 

The basis ot this.method is combustion at 2500 degree9 Fahrenheit in an 

oxygen atmosphere and measurement o£ the infrared absorption of the sulfur 

oxides produced. A thin layer of vanadium pentoxide was placed on top of 

the samples td premote combustion. 

Sultur Analysis 

Result9: Sample Suirur Content 

D1 white clay From Bell Cutof£ Road p! t 0.1895 

02 white sand from Bell Cutot£ Road pit , n: d. ( none detected) 

03 red clay from Macadonia Road pit 0..233% 

ll++ iron oxide sand from Macadonia Ri :ad pit 0:0115 

M5 broken grog (fired brick) n: d. 

fired (tinished) brick n, d,. 

green (unfired) brick 0.123% 

minimum detection limit is .oiox sul£ur 

precision Is 4% 

~~ 

Tf1TAI P M 
iGPCrla`~ !Z 

A CC,vutuT N0. lf H- 00t $-3 

STACK EMISSIONS SURVEY 

BORAL HENDERSON CLAY PRODUCTS 

MARSHALL BRICK PLANT 

MARSHALL, TEXAS 

JUNE 1986 

~ eCvuKT 90 . 

4''~"-°~~=~' ~ 

FILE NUMBER 8660-607 

Prepared By: 

Western Environmental Services and Testing, Inc. 

P.O. Box 7513 

Beaumont, Texas 77706 

(409) 899-4515 
SUMMARY OF RESULTS 

Kiln Stack 

Fluoride Test Runs 

Run Number 4 6 7 

'Stack Flow Rate - ACFM 12993 13179 13173 

Stack Flow Rate - DSCFM* 7110 7171 7161 

X Water Vapor -% Volume 11.49 11.44 11.69 

x CO Z- X Volume 3.0 2.5 2.5 

% 0 2 - X Volume 16.0 15.8 15.8 

z Excess Air At Sampling Poiat 293 270 270 

Particulates 

Probe,Cqclone & Filter Gatch (Can) 

grains/dscf* ---- 

:A - 

----- ----- 

grains/cf - at Stack Conditions (C at) 

lbs/hr (Caw) ---- ----- ---- 

Total Catch (C ) 

graias/dscf* aa ----- ----- ----- 

graias/cf at Stack Conditions (Cau) 

----- ---° °-- 

Ibs/hr (Cax) ---- ----- ----- 

* 68°F., 29.92 "Hg (20 ° C., 760 mm Hg) 

8660-607 

-4- 

`?" ~ 
SUrIlKARY OF RESULTS 

Kiln Stack 

Fluorides 

Run 4 Run 6 Run 7 

Impinger #1 (mg) 42.63 39.46 38.43 

Impinger #2 (mg) 5.55 7.10 6.75 

Total (mg) 48.18 46.56 45.18 

Total lbs/hr 4.36 4.25 4.06 

8660-607 

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MACT Information Collection Request Response 

from 

Boral Bricks, Inc. 

Table of Contents 

• Information Collection Request 

• Appendiz A - MSDS's 

• Appendiz B - Test Data 

)1S 
Enclosure 2 

INFORMATION REQUEST FOR BRICK AND 

STRUCTURAL CLAY PRODUCTS MANU F':it:TURING OPERATIONS 

I. Instructions 

Please return the completed information request to: 

Bruce C. Jordan, Director 

Attn: Bill Neuffer 

Emission Standards Division (MD-13) 

U. S. Environmental Protection Agency 

Office of Air Quality Planning and Standards 

Research Triangle Park, North Carolina 27711 

If you need ~; tarification of any question or item, please contact Mr. Bill Neuffer of EPA at 

(919) 541-5435. 

This information request should be completed for each facility that manufactures brick and 

structural clay products, including facilities that are not major sources. Information is 

requested for all processes at your plant that emit hazardous air pollutants (HAP's), 

including those processes that are not associated with brick and structural clay 

products manufacturing. Sections II through VII request information specific to brick 

and structural clay products manufacturing, and Section VIII requests information on 

emissions of HAP's from other processes located at the facility. Processes that may emit 

HAP's include those processes that use or handle any materials that contain a HAP 

compound, all processes with elevated temperatures, and all other processes in which HAP 

compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is 

included as Attachment 1 to this information request. Attachment 2 provides background 

information on the requirements of the Cle ~ = Air Act and explains how the information 

requested in this questionnaire will be used EPA. Attachment 3 is a list of abbreviations 

and acronyrns used in this information request. 

Several tables are provided throughout the information request for your convenience in 

answering the questions. An example response is given (shaded first colummm or row) in each 

table. If additional space is needed to respond, please make copies of applicable pages. If 

necessary, please make copies of this information request for additional facilities. No 

additional emission testing or monitoring is required to respond to this request. 

II. General Facility Information 

A. Name of company Boral Bricks, Inc. 

Name of facility Phenix City, Plants 1 and 2 

Page 1 of 30 

Wb 
Facility address: 

No. and street 100 Brickyard Road, Plant 1 

City Phenix City State Alabama Zip 36865 

Latitude and longitude coordinates of plant: Lat M 32°24'3.88" . Long (W) 85°00' 12.88" 

Standard Industrial Classification (SIC) Code(s) of brick and structural clay products 

manufacturing operations 3251 

Dun and Bradstreet No. 00-327-5682 

Total No. of employees for company > 1,500 for facility 74 

(If facility is a foreign subsidiary or if compa.ny has foreign subsidiaries, include 

number of employees not based in the U.S.). 

Please complete the following shift information for the facility: 

Shift No. of employees Hours per shift Days per year 

1 38 (manufacturing, main- 8- 12 359 

tenance, etc ... ) 

1 Kiln Fireman g 365 

2 33 (manufacturing, main- 8- 12 359 

tenance, etc ... ) 

1 Kiln Fireman 8 365 

3 1 Kiln Fireman 8 365 

B. Respondent name Andrew S.R. Wichers 

Respondent title Regional Safety Manager 

Respondent address (if different firom above) and telephone number: 

No. and street P.O. Box 1178 

City Columbus State GA Zip 31902-1178 

Telephone No. (334) 480-2407 

Name and telephone number of technical contact person (if different from above) 

Name David Johnson Telephone No. (334) 480-2487 

Page 2 of 30 

47 
III. Informa.tion on Operating Permits and Applicable Federal Emission Standards 

A. Please provide copies of relevant parts of all operating permits and permit 

applications for your facility. Relevant parts include the sections that provide specific 

information and data on: processes that emit HAP's; the use of HAP- containing 

substances; emission levels for HAP and surrogate pollutants (i.e., VOC for organic 

HAP's and PM for metal and other particulate HAP's); emission control device 

design and operation; monitoring and operation and maintenance (O&M) procedures 

for control devices; and generation and releases of other media such as wastewater 

and solid waste that are associated with the operation of air pollution controls for 

brick and structural clay products manufacturing processes. 

If the operating permit or application contains the same 3- ,. formation requested 

in any part of this questionnaire, you may respond to the requested information 

by referencing the page or section of the permit/application to avoid 

duplication. Ifyou reference your permit or application, you must supplement your 

response with all of the additional information requested in this questionnaire that is 

not included in the permit or permit application. If you prefer, you may submit the 

requested information from your permit/application on a 3-1/2 inch di.skette. 

B. If any source or emission unit at this facility is subject to a New Source Performance 

Standard or other Federal emission standard, please identify the source and applicable 

standard. Examples of applicable NSPS include 40 CFR 60, Subpart 000 - 

Standards of Performance for Nonmetallic Mineral Processing Plants, and 

40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers in 

Mineral Industries. 

40 CFR 60 Subpart 00060.670-60-676 Standards of Performance for non-metallic 

mineral processing_alant => all belt conveyors. 40 CFR 82 Subpart F 82.150-82.166 

Recycling and Emissions Reduction => Refrigerators and Air conditioners. 

IV. Brick and Structural Clav Products Production and Raw Material Consumption 

Information 

A. Please provide the 1996 production rates and the current production capacity for 

each type of brick and structural clay product manufactured (e.g., structural brick, 

clay sewer pipes, structural clay tile, etc.). Note that production data should be 

provided in units of tons per year (tons/yr). 

Product 1996 pre>: +.::.tion (tons) Production capacity (tons/yr) 

Face Brick (fired weight) 10' ~ 7 133,361 

Page 3 of 30 

61? 
B. Please provide the type and amount of each raw material and body additive used in 

1996 for manufacturing brick and structural clay products at your facility. Examples 

include clays, shale, and any additives that are mixed into the raw material prior to 

forming. Indicate additives by chemical compound, rather than by trade name. If the 

information requested is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than providing the information 

below. 

Raw materiaUbody additive Amount used in 1996 (tons/yr) 

Calcium Lignosolfulnate 106 (wet weight) 

Manganese, 325 Mesh 7(Dry Weight) 

Ochre 548 69 (Dry Weight) 

Hallmark Fireclay 1,200 (Wet Weight) 

Kaolin, Eufaula 45 (Wet Weight) 

Rome Shale 13,390 (Wet Weight) 

Clay (mined locally) 109,300 (Wet Weight) 

C. If available, please provide a copy of the MSDS's for the raw materials and additives 

listed above. 

See Appendiz A 

D. If available, please provide chemical analyses, including fluorine, metals, and organic 

content, of the raw materials listed above. 

See Appendiz B 

Page 4 of 30 

~~ 
E. Using Table 1, please provide information on the consumption and HAP 

composition of all glazes and colorants that contain HAP's or HAP precursors and 

that your facility applies to brick and structural clay products. Indicate whether the 

coatings are glazes or colorants. Also indicate the type of product that the coatings 

are applied to and the total weight of coatings used in 1996. If the glazes or 

colorants are formulated at your facility indicate so and provide the production 

capacity. List each ingredient of the glaze or colorant. Beside each ingredient, 

indicate the total amount of the ingredient used in 1996. If the information requested 

in the table is contained in your facility's operating permit or permit application, you 

may reference the applicable sections of the permit (or application) rather than filling 

out the table. 

F. In the space below, please indicate any glazes or colorants used by your facility that 

do not contain HAP's and are substitutes for HAP-containing glazes or colorants 

used by your industry. Indicate which HAP-containing materials the non-HAP glazes 

or colorants replace. Describe any limitations on the use of those substitute glazes or 

colorants. 

NONE 

G. If your facility colors brick and structural clay products by flashing, please indicate 

the types of substances used to flash the products and the amounts of those 

substances used in 1996. 

Substance Amount used in 1996 Units Mecify) 

Natural Gas Unknown — Not Measured Not applicable 

Propane Gas (,backup fuel) Unknown — Not Measured Not applicable 

H. If available, please provide a copy of the MSDS's for the glazes and colorants used by 

your facility. If your facility prepares its own glaze, please provide any available 

MSDS's for the glaze ingredients. 

See Appendiz A 

Page 5 of 30 

wo 
I Type (e.g., glaze, colorant) 

Type of product glazed or 

colored 

1996 consumption (tons/yr) 

I Produced at facility? (yes/no) 

I Production capacity (tons/yr) 

Total usage (weight) of each 

ingredient (that is a HAP, 

contains a HAP, or is a HAP 

precursor) in 1996 

Coatings/Coiorants 

Brick 

957 

No 

N/A 

I Tota11996 

Ingredient usage, tons 

Gleason ball clay 8.55 

Green chromium 0.44 

oxide 

Ochre 548 dark 68.88 

Manganese 6.89 

Zinc oxide 7.30 

TABLE 1. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND COLORANTS 

Page 6 of 30 

J1 
V. Description of Brick and Structural Clay Product Manufacturing Processes 

A. Please provide a simple process flow diagram for each brick and structural clay 

product nianufacturing process line. An example process flow diagram is provided in 

Figure 1. A diagram of the plant layout with all processes and emission points clearly 

labeled is also acceptable. 

Assign a unique identification number (ID No.) for each process that has 

associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. 

Please identify all emission points, including those that do not emit HAP's. For 

emission points that are vented to an air poflution control device (APCD), assign an 

ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are 

uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof 

vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information 

request for any responses that pertain to any process or emission point. 

Page 7 of 30 

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B. Using Tables 2A and 213, please provide current production rates, production 

capacities, and related information for each type of equipment used in brick and 

structural clay product manufacturing. In Table 2A, provide the requested 

information for only those sources that are known or expected to emit HAP's. In 

Table 213, provide the requested information for all thermal processing, such as drying 

and firing sources. For combustion sources that use different fuels, Table 2B should 

be completed for each type of fuel. For example, if a kiln typically is fired with gas, 

but periodically is fired with oil, one column in Table 2B should be completed for the 

kiln when fired with gas, and another column should be completed for the same kiln 

when fired with oil. Provide the data in the units listed for each row. 

Page 10 of 30 

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NOTE 1 

Except as otherwise indicated, Boral Bricks does not possess process-specific data that would 

allow estimates to be niade of the types or quantities of HAPs contained in the materials or of the 

resulting HAP emissions. Sections 10.5, 11.3 and 11.19.1 of AP42 provide generally available 

information on the pollutants that may be emitted Srom sawdust dryers, clay products processes 

and sand and gravel processes respectively.11w AP42 data are considered indicative of the types 

of I-iAPs that M be emitted from processes at this plant but are not considered indicative of the 

quantities of HAPs emitted. 

NOTE 2 

Fugitive emissions occur at several points throughout this plant. Boral Bricks has no data on 

these emissions, and is not including fugitive sources per Feb. 25, 1998 telephone conversation 

between 011ie Fick (Consultant to Boral Bricks) and Bill Neuffer of the EPA. 

C. Using Table 3, please provide information on procedures used to monitor the 

process operating rate for each of the pieces of equipment and HAP emission 

sources listed in Tables 2A and 2B. Use the same HAP emission source types and 

equipment ID numbers you listed in Tables 2A to 2B. . 

• Indicate whether you monitor process rate or not. 

• Provide a summary of process rate monitoring procedures that 

describes how process rate is measured for the particular piece of 

equipment. Include where the 'rate is monitored (i.e., rate of material fed, 

rate of material discharged, or material production rate), the units used to 

measure process rate (e.g., lb/hr or pieces/hr), and how the process data is 

recorded, i.e., manually, automatically (e.g., computer - printout or stored 

to disk, or not at all). If you monitor process rate at both the feed and 

discharge ends of the equipment, indicate so. 

Indicate the type of monitor, equipment, or instrument used to measure 

process operating rate. 

• Indicate the ::: aitoring frequency or how often process rate 

measurerr.::::; ;, are made. 

• If instruments are used to measure process throughput, indicate in the 

monitor accuracy column the accuracy of the instrument. The monitor 

accuracy could be listed in terms of a percentage of the throughput 

(f 1 percent), mass per unit time (f2 lb/hr), number of pieces per unit time 

(f 10 pieces/hr), or other appropriate units. 

• Indicate th. -quency that the monitor is calibrated. 

• Provide da % the units listed for each row. 

Page 13 of 30 

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VI. Identification of Brick and Structural Clay Product Manufacturing Emission Points 

A. Use the process flow diagrams developed for your facility and Table 4 to provide 

the following information for each HAP emission source at your facility. 

• Define HAP emission source type in terms of equipment, such as dryers, 

kilns, etc. As in the process flow diagram, you may group multiple pieces of 

similar equipment. 

• Use the same equipment ID numbers indicated on the process flow diagram(s). 

• If th,s emission source vents inside a building or to outside ambient air without 

firs: passing through a control device, place a check mark in the uncontrolled 

column. 

• If the emi.ssion source vents inside a building or to outside ambient air after 

passing through a fabric filter, dry injection fabric filter, or scrubber, place the 

APCD ID number(s) in the column corresponding to the APCD type. 

• If the emission source vents through a control device type not listed in Table 4, 

indicate the control device type in the other control column and place the 

APCD ID number in the appropriate cell. 

• In the emission test data column, place a"yes" or "no" in the appropriate cell 

to indicate whether the specific source has been tested for any pollutants, 

including any HAP's, VOC, PM, or opacity. 

Page 15 of 30 

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B. Using Table 5, please provide information on stack parameters and emission 

estimates for each emission point at your facility that is known or expected to emit 

HAP's. Provide information for all APCD's, including those that exhaust inside the 

building. Include data for each inlet and outlet, if available, as indicated in the table. 

If you have more than one inlet to an APCD, provide data for each of the inlets. 

Provide data in the units listed for each row. 

Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal 

HAP's or VOC for organic HAP's. Emission estimates may consist of 

measurements reported in emission test reports or may be calculated using mass 

balances, emission factors, engineering judgement, or other estimation methods. 

Provide the emission estimates as emission factors in units of lb of pollutant emitted 

per ton of product (lb/ton). Provide complete copies of any emission test reports 

or other reports that document measurements of emissions. Test reports and 

other emission measurement documents should include the following information: 

process identification; location of sampling point; stack diameter, temperature, and 

flow rate; test method, including analytical procedures; number of test runs; 

emission concentration, emission rate, percent oxygen, and percent moisture for 

each test run; process operating rate; type of APCD; and APCD operating 

parameters. However, test reports with incomplete documentation may still be 

useful and should also be submitted. 

You do not need to fill out Table 5 for emission points that are covered by an 

emission test report that is included in your submittal. If emission test reports are 

not available, provide calculations that support your emission estimate, 

including the basis for all assumptions in the estimate. Note that emission 

estimates are needed for all HAP's that the facility emits or has the potential to emit. 

(Please refer to the HAP list in Attachment 1.) If the information requested in the 

table is contained in your facility's operating permit, you may reference the 

applicable sections of the permit rather than filling out the table. 

Page 17 of 30 

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C. Using Tables 6A through 61), please provide design and operating data for each APCD 

associated with all dryers, kilns, and any other brick and structural clay products 

manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of 

APCD's. Use Table 6D for other types of APCD's. When using Table 61), please 

specify the type of control device and 2 to 4 key design or operating parameters for the 

device. Provide data in the units listed for each row. If the information requested in 

Tables 6A through 6D is contained in your facility's operating permit, you may reference 

the applicable sections of the permit rather than filling out the tables. 

Page 22 of 30 

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-21 
D. Using Table 7, please provide the following information on current monitoring 

procedures for each of the control devices listed in Tables 6A to 6D: parameters 

monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices 

used (e.g., differential pressure transducer, thermocouple), and recordkeeping 

practices (e.g., manually recorded in log book, continuously recorded by electronic data 

acquisition system). Describe briefly other operation and maintenance (O&M) 

procedures for each control device. If the information requested in the table is contained 

in your facility's operating permit, you may reference the applicable sections of the 

permit rather than filling out the table. 

VII.Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing 

A. Please describe afl pollution prevention practices (i.e., process modifications, such as reuse of discarded or rejected materials, or any practice that prevents or reduces the 

amount of air emissions, or the generation and release of solid waste or wastewater 

associated with the operation of air pollution controls). If the information requested 

here is contained in your facility's operating permit, you may reference the applicable 

sections of the permit rather than providing the information below. 

Pollution Prevention Practices: 

This facilty: 

1 Recycles waste heat from the kiln to heat the dryers and to a lesser de eg_r e, the 

holding rooms. 

2 Recycles floor sweeyings and scrap/waste clay into the brick body: 

3. Recycles green brick into the body. 

4 Recycles off spec brick (grog) into the brick body. 

5. Recycles sand coating into the brick body. 

6. Recycles wash water into the body. 

Page 27 of 30 

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'23 
VIII.Information on Processes Other Than Brick and Structural Clay Products Manufacturing 

Processes 

A. Using Table 8, please identify all other processes or operations at this facility that are 

not addressed in Items II through VII above and that are potential sources of HAP 

emissions. Estimate total annual emissions of each HAP emitted by these collocated 

processes. If the information requested in the table is contained in your facility's 

operating permit, you ma.y reference the applicable sections of the permit rather than 

filling out the table. 

Page 29 of 30 

7V 
TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCES 

Process/enussion source/SIC Code(s) HA.P's emitted Estiniated annual emissions, 

tons 

EXAMPLE: MiningSIC 

trace metals 

(Cr, Mn, Ni 

compou nds) 

0.2 

Concrete block plant (Plant 2): A 

concrete block plant is located on this 

plant site and is owned and operated by 

Boral Bricks. Boral has no emissions 

data on this process. 

SIC 3271 

No Data No Data 

Quality testing lab in support of brick 

nmanufacturing: A small quality control 

testing laboratory operation takes place at 

this plant but is not otherwise identified or 

reported in this ICR because there are no 

emissions data available. 

SIC 3251 

No Data No Data 

SIC 

SIC 

If the information requested in the table is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the table. 

Page 30 of 30 

7~ 
h,Saferlal Safety Dala Sheet 

May b1 used 10 CaMply wit11 

OS}{A's Hazard Cocnrnunk-atlon Standard, 

29 CFFi 1910.1200. Standard musl bo 

consulted lor 3peclflc rtaqultram•nb. 

U.S. Depertment ot Labor 

Occupatlonal Sjif•ty •nd HeaIth Adminittratlon 

(Non-Mandatary Form) 

Form Approv•d 

OM8 No. 1 2 18-0072 

~ 

IOENTTfY (Aa t13od on laDd anC LhQ lVoro: Brank spacsa an nor p.mwtad. r any Ir•m b na arpycaoio. or n 

q 548 1Uchre ln/orm•oan b avsjlaDk, an• 30•cra mus! D• marfc Mto ndKa • T , 

Scctlon 1 

AAanufactut•r's Nam• Em•rq• j I ~o~, 

Saud-hern Color ac Chemical 

,►.6d( • ss (Numoer. Strr t C,1'y. St a th, an0 11P Cod•) T rl a p~«~ • Nw~~r ~r ~a t~ort 

P.O. Box 1507 1404 ) s86-~16(i 

oal. Prrroara ~ 

7 Swisher Drive May 21 1986 

Si9nature o1 Prepuer (apdonaq , 

Cartersville, Georgia 30120 

Stctlon II -- Haz9rdous Ingredlents/ldantity Informatlon , 

Olh•r Llrnils 

Hasardous Compon•Ms (Sp•c iM1c CMmk.sJ Id•ni tty, Common Nam•{31) OSHA PEL ACOIH TLV R•comm•ndW ~1 loona 

M548 Ochre (Fe20I-XH20)Natural Iron Ox3de1 Non Established; lOmg/L None 

Note: Ochre is 'listed as Hazardous because of t'he nuisance dust 

that may be created in handling t e pro uct. 

CASM 1343 - 8 1 - 3 

I 1 . 

Sectlon III — Phyalcal/Chemlcal Characteristics 

f3arnq Pan1 Specdio (3ravity (H30 • 1) 

N/A 3.2-3.6 

Vapor Pr•ssur• (mm Hq.) M•Itlny Point 

N/A ' N/A 

Vapor Oransity (AIR • 1) EvaporaUon Rats 

N A I (8utq1 Ac•tnts • 11 1 N/A 

So+uaH6ty in vYaur 

Insoluble 

Appearance and Odor 

Yellow Powder - No Odor 

Section IV — Fire and Exploslon Hazard Oata 

Flasn Pouu (MUncd Usod) N/A Flammabl• Umits LEL UEL 

• N/A N/A 

. . - N/A 

Sp+ciaJ Fr• Fiqht,ng Proc•dur•fa 

None Required' 

Unutuat Fi• and Expbswn Hazird• 

None 

tR•produc• locally) OSHA 174, $•pL 1S8` 

76 
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3NON (P/oAy ol qeueleNf) AIt11411tdut•o2ul 

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uMoux auoN P?OAr a fton!wo-J I I olam:un I Nqctts 

-- rlea A1 1AIlo*ab — A uo11DoS 

-77 
J 

Material Safety Data Sheet 

Substance Identification 

Identity: IRON CHROMITE CAS #: 1308-38-9 

Trade Names: CHROMOX 

Manufacturer: The Prince Manufacturing Company Emergency: Chemtrec 

One Prince Plaza 1-800-424-9300 

Quincy, IL 62301 

217-222-8854 

Components and Contaminants 

Chemical Name CAS # OSIiA PEL ACGIH TLV Percent 

Chromium Cr" 7440-47-3 0.5 mg/m3 0.5 mg/m3(TWA) 30-45% Cr 

Silica, Crystalline Quartz respirable dust 14808-60-7 0.1 mg/m3 0.1 mg/m3(TWA) 1.2% Si02 

Physical Data 

Boiling Point: NA Specific Gravity (1120 =1): 4.4 

Vapor Pressure (mm/Hg): NA Melting Point: 3350 - 4000° F 

Vapor Density (Air=1): NA Evaporation Rate (Butyl Acetate=l): NA 

Solubility in Water. insoluble 

Appearance and Odor. black powder, no odor. 

Fire and Explosion Hazard Data 

Flash Point: Not combustible 

Flammable Limits: LEL NA UEL NA 

Extinguishing Media: ' Foam, CO2, or dry chemical or water. 

Special F'ire Fighting Procedures: In the event of fire, wear full protective clothing and NIOSH-approved selfcontained breathing apparatus with full face piece operated in the pressure 

demand or other positive pressure mode. 

Unusual F'ire and explosion hazards: Not combustible. 

Reactivity Data 

Stability: Stable under ordinary conditions of use and storage. 

Conditions to avoid: None Known " 

Incompatibility (materials to avoid): None Known. 

Hazardous Decomposition or Byproduds: None Known. 

Hazardous Polymerization: Will not occur. 

Health Hazard Data 

Route of Entry: INHALATION: May cause delayed respiratory disease if dust is inhaled over a 

prolonged period of time. - 

S KIN: No. 

INGESTION: Ingestion of Iron Chromite may cause abdominal pain and 

nausea. 

...._ . 

Iron Chromite, Page 1 

Ap-. :9~-: 

71-)". 
Health Hazards (Acute and Chronic): 

Carcinogenicity: 

Signs and Symptoms of Eaposure: 

Aggravation of Pre-existing Conditions: 

Health Hazard Data (ront.) 

Respiratory disease may result from prolonged overexposure. Can cause eye 

initation. 

NTP: No IARC Monographs: Yes (Silica) 

Excessive inhalation of dust may result in shortness of breath and reduced pulmonary function. Symptoms of silicosis include impaired pulmonary function 

and wheezing. 

Persons with impaired respiratory function may be more susceptible to the effect of this substance. 

Emergency and First Aid Procedures: IF INHALED, remove to fresh air and seek medical attention for any breathing 

difficulty. 

IN CASE OF SRIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. 

IN CASE OF EYE CONTACT, flush eye.s imme:liately with water for at least 

15 minutes. Seek medical attention if irritation persists. 

IF INGESTED, induce vomiting immediately by giving two glasses of water 

and sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. 

Precautions for Safe Haindling and Use 

Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratory 

protection. Recover uncontaminated material for use. Vacuum or sweep 

remaining material, keeping dust to a minimum. 

Waste Disposal Method: Dispose of unreclaimable material in a RCRA=approved waste facility. 

Handling and Storing Precautions: Protect containers from damage and keep closed when not in use. 

Other Precautions: Observe good personal hygiene. Wash after handt'mg. 

Control Measures 

Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or is 

anticipated. OSHA standard 1910.134 or ANSI Z.88.2-1980 specifications are 

' recommended. 

Venti7ation: A system of local and / or general exhaust is recommended to keep employee 

exposures below the Airborne Exposure Limits. Local exhaust is generally 

preferred because it can control the emissions of the cqntaminant at its source, 

preventing dispersion of it into the general work area. Please refer to the 

ACGIH document, "Industrial Ventilation, A Manual of Recommended Prac- 

— tices', most recent edition, for detaiLs. 

Protective Gloves: Yes 

Eye Protecxion: Safety goggles are recommended. 

Other Protedive Clothing or Equipment: Use other protective equipment when necessary in order to avoid prolonged 

exposure to skin. 

Work and Hygienic Practices: Observe good personal hygiene. Wash after handling. 

. . -- - SAR.A Title III Section 313 Supplier Noti6cation 

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency 

Planning and Community Right-to Know Act of 1986 and of 40 CFR 372.45: 

ComRgnent CAS # % b„yWei¢ht 

Iron Chromite 1308-38-9 30 - 35% Cr 

This informatioa must be included in all MSDS's that are copied and distnbuted for this material. - 

Iron Chromite, Page 2 

April 1991 

-7~ 
ividturlal oale(y uata %)neet 

May be used Io comply with 

OSHA's Hazard Communication Standard, 

29 CFR 1910.1200. Staridard must be 

consulted for specific requirements. 

U.S. Department of Labor /~_, 

Occupational Safety and Health Administration ``; 

(Non-Mandatory Form) ', 

Form Approved 

D OM8 No . 1218-0072 CAS# 11115-91-6 

IDENTITY (As Used on Label and List) I Note: Blank spaces are not permitted. 11 any item is not applicable, or no IRON MANGANESE OXIDE BLACK (I320/3 18 inlamatron is availabee, the space must be martced to indica'e mat. 

Section I CHEMICAL FORMULA - Fe2 0 3 Mn20 

Manufacturer's Name Emergency Telephone Number 

404 386-4766 

Address (Number, Street, City, State, and ZIP Code) Telephone Number for Information 

7 Swisher Drive (404) 386-4766 

Cartersville, GA 30120 Date Prepared 

September 21, 1987 

Signature of Preparer (opdonal) 

Section II — Hazardous Ingredients/Identity Information 

Other Limits 

Hazardous Components (Specific Chemical Identity; t.',ommon Name(s)) OSHA PEL ACGIH TLV Recommended (opLCna/) 

HAZARDOUS INGREDIENTS - NO ADDITIONAL INGREDIENTS 

IRON OXIDE FUMES as Fe 5mg/m' 

_ RESPIRABLE DUST 5tng/m3 

MANGANESE COMPOUNDS 5mA/ta3 

(CEILING, AS Mn) 

Section III — Physical/Chemical Characteristics 

Boiling Point Specific Gravity (HZO - 1) 

N/A 4.8-5 

Vapor Pressure (mm Hg.) Meltlng Point 

Vapor Density (A1R - 1) Evaporatieon Rate 

(8utyf Acetate - 1) 

Sotubility in water 

. INSOLUBLE 

Appearance and Odor 

BLACK POWDER - ODORLESS 

Section IV — Fire and Expiosion Hazard Data 

Flash Point Flammable Limita UEL 

N/A N/A N/A I N/A 

Ex6nguishing Media 

WATER DRY CHEMICAL • 

Special Fre Fghting Procedures 

NnNF: 

Unusual Fire and Explooion Hazards 

• NONE 

(Reproduce locally) HAZARDOUS MATERIALS IDENTIFICATION SYSTEMS (HMIS) OSHA 174, Sept. 19B5 

HEALTH 0 FLAMMABILITY 0 REACTIVITY 0 

ti1J 
1 D 

>ection V — Reactivity Data 

tability Unstable Conditions lo Avoid 

NONE 

Slable 

• X 

icompatibility (Materia/s to Avord) 

NONE KNOWN 

azardous Decomposition or Byproducts , 

NnNF uNnLflU 

azardous May Occur Conditions to Avoid 

olymerization NONE 

Will Not Occur 

X 

ection VI — Health Hazard Data 

oute(s) of Entry: Inhalation?YES Skin? NO ingestion? YES 

ealth Hazards (Acute and Chronic) 

ANGA_NESE IG CHEMTCAL.L.Y RF.ATED AS PART OF THIS ST B E PI tKFr1T CRYSTAL , OVER EXPOSURE TO 

'0 MANGANESE IN AN UNREACTED FORM MAY RESULT IN CHRONIC MANGANESE POISONING(MANGANISM) THE 

'ENTRAL NERVOUS SYSTEM IS THE CHIEF SITE OF EFFECT. TO DATE THESE TYPES OF EFFECTS HAVE NOT 

arcinogenicity: NTP? NO IARC Monographs? NO OSHA Regulated? NO 

EEN ASSOCIATED WITH THI$ PRODUCT. 

gns and Symptoms of Exposure 

XCESSTVR FxPOSttRF TO ATRRORNR TN1ST WTT.T. RFqIJT.T TN FFFFCT SIMIT AR TO THAT OF NUISANCE TYPE 

UST THAT IS PARTICULATE MAY REDUCE VISIBILITY AND/OR CAUSE UNPLEASANT DEPOSITS IN THE EYES, 

edical Conditions E~R~AND NOSE . INJURY TO THE SKIN OR MUCOUS MEMBRANES CAN OCCUR BY DIRECT :nerally Aggravated ure ~~A1UT ~+AT Ar•TTA1T nD aV DT/•nDAttQ CYT c f+i L'A cTN/c l ~~~ c`c' ~ nv - emra=Qa ~ sysm eeyxxvu vse as sesvvsevvv vicexiti vaxrrv*+ss~ QF 

DUST. 

nergenry and Frst Aid Procedures 

ICTN r'ntyTer`T — WeCN L1TTtI gnev ANn t,JATER EYE CONTACT — FLUSH WTTN t.ARGE AMOUNTS OF WATER • 

ONSULT PHYSICIAN. INHALATION — REMOVE FROM DUSTY AREA. 

3ction VII — Precautions for Safe Hangling and Use 

ips to Be Taken in Case Material Is Released or Spilled 

ANDLE AS NORMAL SOLID WASTE, SCOOP UP BY SOME MEANS AND PLACE IN A WASTE CONTAINER 

aste Disposal Method 

ASTE MATERIAL CAN BE BURIED IN A APPROVED LANDFILL OR HANDLED AS INERT WASTE IN ACCORDANCE 

ITH FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. 

-cautiona to Be Taken in Handling and Storing 

TORE DRY AT AMBIENT TEMPERATURE AWAY FROM FOOD AND DRINK. 

her PrecautlOn! 

NONE 

!ction VIII — Control Measures 

spiratory Prvtectlon (SpecA'y Type) 

[OSH APPROVED FOR DUSTS, MISTS AND FUtdES. DONOT EXCEED USE LIMITS OF THE RESPIRATOR. 

ntilation 

Mechanicel (GerteraQ 

)tective Gloves Eye Protectlon 

IBBER, CLOTH OR PLASTIC GLOVES SAFETY GLASSES 

ier Protective Clothing or Equipment 

N/A 

rk/Hygienk Practices 

) NOT STORE NEAR FOOD AND DRINK. WASH EXPOSED SKIN FOR HYGIENE PURPOSES. 

Pftf Z • u.eo,ro.: ,rel.491-521/45775 

"M 
MATERIAL SAFETY DATA SHEET 

Section I - Product Identification 

The Georgia Marble Com pany 

1201 Roberts Boulevard, Buildin g 100 

Kennesaw, Georgia 30144-3619 

Emergency Telephone: (770) 421-6508 

Prepared by: Trevor G. Lamond, Technical Director 

Trade Name: 

Ground limestone/ Calcium carbonate 

Production Locations: Marble Hill, Ga, Sylacauga, AI 

Chemical Identity: Product consists of ground limestone (CAS Number: 

1317-65-3), which is a natural peoduct composed of Calcium Carbonate 

(CAS Number 471-34-1) and from 1-3% Magnesium Carbonate (CAS 

Number 546-93-0) together with various other natural ingredients at trace 

levels. 

Section II - Hazardous Inaredients 

~ 

Hazardous Materials Identification System 

Health Hazard 0 

Flammability Hazard 0 

Reactivity Hazard 0 

Personaf Protection E 

Hazardous Inaredients TLV (mg/m ) 

Silica, Quartz 

Calcium Carbonate Dust 

.1 (Respirable Dust) 

10 (Nuisance Dust) 

This product typically contains less than 0.3% crystalline silica. 

In addition, there are also small but detectable amounts of the following 

other naturally occurring chemicals that are known to the State of 

California to cause cancer, birth defects or other reproductive harm. This 

warning is provided in the absence of definitive testing to prove that these 

risks do not exist. These amounts are typical quantities and may vary 

slightly with different lots. 

Pz 
Chemical Name Typical Amount CAS Number 

Arsenic 

Lead 

Less than 1 ppm 

Less than 1 ppm 

7440-38-2 

7439-92-1 

Section III - Physical/Chemical Characteristics 

Appearance and Odor: Fine, White Powder; No Odor 

Boiling Point: N/A Specific Gravity: 2.71 

Vapor Pressure: N/A Evaporation Rate: N/A 

Vapor Density: N/A (Butyl Acetate = 1) 

Solubility in Water: Slight Melting Point: N/A 

Section IV - Fire and Explosion Hazard Data 

Flash Point: N/A 

Flammable Limits: N/A 

Fire Extinguishing Media: N/A 

Special Fire Fighting Procedures: None 

Unusual Fire and Explosion Hazards: None 

Section V - Reactive Data 

This material is stable. 

Incompatibility: May react with acids to liberate carbon dioxide. 

This material will not polymerize. 

Hazardous Decomposition By-Products: None 

Section Vl - Health Hazard Data 

Calcium Carbonate, the main component of limestones and marbles, is 

not on the NTP, IARC, or OSHA lists of carcinogens and there are no 

health effects associated with prolonged exposure to pure calcium 

carbonate. Crystalline silica (sand), a trace component of many limestone 

and marble powders, in its res irable form has been listed by IARC as a 

Type 1 carcinogen and the NTPP has stated that crystalline silica is 

reasonably anticipated to be a carcinogen. Also, prolonged exposure to 

crystalline silica has been found to cause silicosis, a noncancerous lung 

disease. 

Exposure: 

Inhalation: Can be irritating to the respiratory tract. 

e Contact: Mild irritation. Rin Contact: No effect. 

Ingestion: Minimal efFect. 

First Aid: 

J"-"3 
Inhalation: Remove from area of exposure and to fresh air area. 

Eye Contact: Flush eyes with water for 10 minutes. If irritation 

persists, obtain medical attention. 

Skin Contact: Wash from skin with mild soap and water. 

Ingestion: Ingestion should not cause any significant health 

problems. 

Section VII - Spill or Leak Procedure 

Spill or Leak: Respiratory protection should be worn during clean 

up to protect from airborne dust. Measures should 

be taken to reduce airborne dust during clean up. 

Waste Disposal: Shovel up material and dispose of in landfill. 

Comply with applicable federal, state and local 

regulations: 

. Section VIII - Special Protection 

Respiratory Protection: NIOSH/OSHA/MSHA approved dust respirator if 

T.L.V. is exceeded. 

Ventilation: ' Local exhaust: As required for dust to maintain 

airborne dust below the TLV. 

Mechanical: As required for dust. 

Eye Protection: Safety glasses or goggles. 

Special Protection: None required. 

Date Prepared: March 3. 1998 

?6/ 
georgia marbie company 

nw wOvAta+S 1201 roberts boulevard, building 100 • kennesaw, georgia 30144-3619 

" STONE PR00LCn fax: (770)421-6507 (770)421-6500 

MA TERIAL SAFETY DA TA SMEET 

Section I - Product Identification 

The Georgia Marble Compan 

1201 Roberts Boulevard, Building 100 

Kennesaw, Georgia 30144-3619 

,.a Lmergency e ephone: 7 421- 557 

enneth J. Meeks, Safety and Training Manager 

Risk Management 

Chemical Name: Calcium Carbonate 

Chemical Family.• Marb/e; Limestone; DolomitE 

Chemical Fonnula: CaCO3 ; CaCO3 i MgCO3 

CAS Number. 471-34-1 

Trade Name: : 

Section ll - Hazardous Ingredients 

Hazardous Materials ldentification S sy tem 

Health Hazard 0 

Flammability Hazard 0 

Reactivity hlazard 0 

Personal Protection E 

Hazardous /ngredients TLV (1VIg/M ) 

Silica, Quartz 

Calcium Carbonate Dust 

,1 (Respirab/e Dust) 

10 (Nuisance Dust) 

Calcium Carbonate may contain crystalline silica at levels between 0.01 % 

and 1.5% and varies naturally. 

There are a/so small, but detectable amounts, of the following other 

naturally occurring chemica/s that are known to the State of Califomia to 

cause cancer, birth defects or other reproductive hamn. This warning is 

provided in the absence of definitive testing to prove that these risks do 

not exist. These amounts are typical quantities and may vary slightly with 

different jobs. 

Chemical Name Typical Amount CAS Number 

Arsenic Less than 1 ppm 7440-38-2 

Lead Less than 1 ppm 7439-92-1 ?J 
Section lll - Physical/Chemical Characteristics 

Appearance and Odor Fine, White Powder; No Odor 

Boiling Point: 

Vapor Pressure: 

Vapor Density: 

Solubility in Water 

N/A Sp ecific Gravity: 2.71 

N/A Evaporation Rate: N/A 

N/A (Butyl Acetate = 1) 

Slight Me/ting Point: N/A 

Section IV - Fire and Explosion Hazard Data 

Flash Point: N/A 

Flammable Limits: N/A 

Fire Extinguishin g.Media: N/A 

6nusual

p ecial Fire Fight,ng Procedures: None 

 Fire and Explosion Hazards: None 

Section V - Reactive Data 

This material is stable. 

lncompatibility: Reacts with strong acids to liberate carbon dioxide. 

This material will not po/ymerize. 

Hazardous Decomposition By-Products: None 

Section VI - Health Hazard Data 

Calcium Carrbonate is not on the N. T. P., 1.A. R. C., or OSHA lists of 

carcinogens. Cry stalline silica, a trace component of Calcium Carbonate, 

has been listed by IARC as carcinogenic to experimental animals and has 

developed limited evidence for carclnogenicity to humans, however, IARC 

has detennined that the carcinogenicity to humans is neither certain or 

proven. 

Prolonged, repeated inha/ation of crystalline silica can cause silicosis, a 

noncancerous /ung disease. 

Exvosure: 

Inha/ation: Can be irritating to the respiratory tract. 

Eye Contact: Mild inYitation. 

Skin Contact: No effect. 

ingestion: Minima/ effect. 

First Aid: 

Inha/ation: Remove from area of exposure and to fresh air area. 

Eye Contact: Flush eyes with water for 10 minutes. !f initation 

%sists, obtain medical attention. 

Skin Contact: sh from skin with mild soap and water. 

Ingestion: Ingestion should not cause any significant health 

problems. 

•, 
Section Vll - Spil! or Leak Procedures 

Spill or Leak: Respiratory protection should be worn during clean 

up to protect from airborne dust. Measures should 

be taken to reduce airborne dust during clean up. 

Waste Disposal: Shovel up material and dispose of in landfill. 

Comp1y with applicable federal, state and local 

regulations. 

Section Vill - Special Protection 

Respiratory Protection: NIOSH/OSHA/MSHA approved dust respirator if 

T. L. V. is exceeded. 

Ventilation: Local exhaust: As required for dust to maintain 

airborne dust below the TLV. 

Mechanical: As required for dust. 

Eye Protection: Safety glasses or goggles. 

Special Protection: None required. 

Date Prepared:March 4.1998Prepared by Safety Department 

N 
MATERIAL SAFETY DATA SHEET 

tNDUSTRIAS SULFAMEX, S.A. Distributor - North America 

:ampico, Mexico AGROMEX, INC: 

Mobile, Alabama 

FOR HEALTH HAZARD INFORMATION, CALL: -(205) 443-5665 

Date of Revision: •'03/12/90 

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- Product Name: TECMANGAM (R) Soluble Manganese Sulfate 

- Synonym: Manganese Sulfate (81-83.8 ) 

- Formula: Mixture 

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SECTION II. PRODUCT AND COMPONENT HA2ARD DATE 

A. COMPONENTS: 

Approx. _ •_ c 

Percent TLV** CAS Reg.No.. ~. 

*Manganese Sulfate.83.8 5 mg/m3 (as Mn) 7785-87-7`•_:.: 

Magnesium Sulfate 2.0 None 7487-88-9 = 

Calcium Sulfate .5 None - - 7788-18-9 - 

Water 1.0 None 7732-18-5 

- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - i- - - - - - - - 

*Principal hazardous componertt ~ `•- 

**See Section VI-A for additional'information on exposure limit . s. 

PRECAUTIONARY LABEL STATEMENTS: . 

WARNING! MAY BE HARMFUL IF INHALED , 

CAUSES IRRITATION 

Avoid breathing dust. 

Avoid contact with eyes. 

Avoid prolonged.or repeated contact with skin. .... 

Use with adequate ventilation. _ Wash'.thoroughly .after handling. : 

. 

. . . 

. • - 

FIRST_AID ,-_ In case of contact,immediately flush eyes with 

plenty of water for at least 15 _minutes. ,-; Call -;',a physician.;, iWash ' 

skin with soap and plenty of .: water.... ,Wash 'clothing before: reuse. 

In case of irritation of eyes, nose, and throat, -' remove from 

exposure,.treat symptomatically, and call a physician if.symptoms 

persist. ► ° 

~ 

_ MSDS 001:1 . . - .. . . .. • -- 

... :: .. 

~ i 

~~ '03/11/90 

 a• . .. . 

 t•'t. 

. . . . _. 

B.

0- 
Since emptied packages retain product residue, follow label warnings even after ~ 

package is emptied. 

Notice: Manganese Sulfate may discolor ornamental surfaces, rock, tile, masonry, 

etc. Contact with these surfaces should be avoided. If contact'occurs, wash area 

immediately with water. _ 

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SECTION III. PHYSICAL DATA 

'•s <. .- 

- Appearance and Odor: White to cream-colored powder, practically odorless. 

- Boiling Point: Not applicable. 

- Specific gravity (H20 - 1): 0.81 at 20`/20`C 

- Vapor Pressure: Not applicable. 

- Percent Volatile by Volume: Not applicable. 

- Vapor Density (Air a 1): Not applicable. 

- Evaporation Rate: Not applicable. 

- Solubility in Water: Appreciable (approx. 99X). 

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, , . , _ . ' . . . ~ :. .: • . 

SECTION IV. FIRE AND EXPLOSION HAZARD DATA 

- Flash Point: Not applicable (Noncombustible). 

- Flammable Limits: Not applicable. 

- Extinguishing Agent: Use appropriate agent for surrounding fire. 

- Special Fire-Fighting Procedures: None known to Sulfamex. -=-• ~ = -= 

- Unusual Fire and Explosion Hazards: None known to Sulfamex. • - ;'~_~ 

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SECTION V. REACTIVITY DATA - -+ ~ - 

- Stability: Stable. 

- Incompatibility: None known to SulfameY. 

- Hazardous Decomposition Products: Decomposes to oxides of manganese and sulfur. 

, - Hazardous Polymerization: Will not occur. "' . : . : : 7, .t'1:: 

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. , 

._._ . _ . •.. . . . _ .:: . • ~ . • 

SECTION VI. TOXICITY AND HEALTH 

A. EXPOSURE LIMITS i~ a?'• ~ _- ~J . 

• • ' ~5:2wJ ~ L.Z'J.a 

- OSHA Permissible Eaposure Limit (PEL): . Kanganese sulfate (as Ma):.`-"i 

5 mg/m3-C. 

- Threshold Limit Value (TLV) : Pfanganese Sulfate (as Mn):' .=5mg/K3-C, 

ACGIH, 1982. 

- A NIOSH industrial hygiene analytical method-for manganeseis'availa6le:. (1) 

- An industrial hygiene analytical method for Manganese Sulfate'is avsilable 

to health and safety professionals upon request. ~" ~~ :;' =` ~i~ ==r:.''i.I•Ya 

_ , ~ :~ ::: ~tr.y_ ~ =. 

B. EXPOSURE EFFECTS - '— _ ~ ~---

7 4.1 

Inhalation: May be harmful if inhaled. May cause irritation of the nasal 

passages. 

Eyes: Dust may cause irritation. 

Skin: Prolonged or repeated contact may cause irritation. l 

03/12/90 ' 

MSDS: 001:1 
C. SKIN AlVll x~ Yt ricuiauiiv.v 

Safety glasses should be worn in any type of industrial operation. Protective 

gloves should be worn. _:.. 

D. OTHER CONTROL MEASURES 

An eye bath and washing facilities should be available. Wash thoroughly 

after handling. 

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SECTION VIII. SPECIAL STORAGE AND HANDLING PRECAUTIONS 

Since emptied packages retain product residue, follow label warnings evea after 

package is emptied. 

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SECTION IX. SPILL, LEAK, AND DISPOSAL PRACTICES 

Steps to be taken in case material is released or spilled : Collect and contain f:r 

salvage or disposal. 

Waste Disposal Method : Landfill. Observe all federal, state, and local laws 

concerning health and environment. 

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SECTION X. ENVIRONMENTAL EFFECTS DATA 

A. StAM4SARY: This product has not been tested for environmental effects. 

However, some laboratory test data and published data (7,8) are available for 

all of the major components of this product, and these data have been used to 

provide the following estimate of environmental impact:' 

This product has a low biological oxygen demand, and it is expected to cause 

little oxygea depletioa in aquatic systems. It is expected to have a low - 

potential to affect aquatic organisms, secondary waste treatment micro— 

organisms, and the germination and growth of some plants. If diluted with a 

large amount of water, this product released directly or indirectly into the 

environment is not expected to have a significant impact. 

SECTION XI. TRANSPORTATION 

DOT Hazard Classification: Not regulated'-by"DOT 

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SECTION XII. REFERENCES 1 

1. NIOSH Manual of AnalyticalMethods , 2nd Edition, Volume 2. Issued by the -„ 

National Institute for Occupational Safety and Health. Washington, U.S._;~—~ 

Government Printing Office, 1977, Method S5. ` 

• • +"~ 

2. H..C. Hodge and J. H. St4rner, Tabulation of toxicity classes. AmInd: ~". 

Hyg. Assoc. Q. 1949; 10:93-96. ~ - 

MSDS: 001:1 

03/12/90 

• . qa 
C: FIRST AID 

Inhalation : Remove from exposure. Treat symptomatically, and get medi&al 

attentioa if symptoms persist. 

I 

Eyes: Immediately flush with plenty of water for at least 15 minutes and 

get medical attentioa. ' 

Skin: Immediately wash with soap and plenty of water. Wash contaminated 

clothing before reuse. 

D. ANIMAL TOXICITY DATA 

The composition of this product varies from one batch to another; however, 

toxicity data felt to be representative of this variable product are provided 

below: 

Toxicity 

Test Scecies Result (2) Classification (3) 

Acute oral LD50 Rat 1600-3200 mg/kg Slightly To: ~ :,: 

Acute oral LD50 Mouse 800-1600 mg/kg Slightly Tox: 

Dermal LD50 Guinea pig >1000 mg/kg 

Skin irritation Guinea pig Slight 

Eye irritation Rabbit Moderate 

In the 1930's, manganese ore mining and processing operations were studied,.and 

it was determined that chronic overexposure to manganese ore dust produced a 

disease of the nervous system with symptoms similar to Parkinson's diesease: 

tremor, rigidity of facial expression, stooped posture, and stiffness and slowness of movements. (4) Other reported illnesses include pneumonia and metal fume 

fever. (5) Although these effects in humans have occurred from exposure to 

manganese ore, manganese dioxide, and finely divided manganese, a thorough 

search of the world medical lfterature has disclosed no reports of such effects 

occurrinfrom exposure to manganese sulfate, the form of manganese present in 

Tecma Eastman Chemical Products, Inc. reported that no neurotoxicity, 

pulmonary disease, nor metal fume fever have been seen in Eastman employees who 

have worked with Tecmangam for many years, although irritation of the nasal 

mucous membrances, skin irritation, and eye irritatioa have been observed.' (6) 

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SECTION.VII. PERSONAL YROTECTION AND CONTROLS 

A. RESPIRATORY PROTECTION 

.: ~. .. 

An appropriate NIOSH-approved respirator for dust should be worn if needed. 

B. VENTILATION . 

General: Recommend at least 10 air changes per hour for good general room. 

ventilation. 

Local Exhaust: Recommended to control dust. See Section VI-A for 

information on exposure limits. Maintain workroom air concentrations below 

irritating levels. 

MSDS 001:1 

03/12/90 

. q1( 
, 3. R.H. Flinn, cc eu. %o•..4-+y...."..6 ....— 

Public Health Bulletin No. 247 , 1940. 

4. A. xamilton and H.L. Hardy,Industrial Toxicology . Acton, MA, Publishing 

Sciences Group, Inc., 1914, pp 127-130. 

5. Battele's Columbus Laboratories, Wafer Quality Critical Data Book Volume - 

3- Effe_cts of Chemicals on Aquatic Life , Selected data from the literature 

through 1968. Washington, U.S. Environmental Protection Agency, Project 

No. 18050 GWV, Contract No. 68-01 -007, May 1911. 

6. J.E. McKee and H.W. Wolf, Editors. Water Quality Criteria , Publ. No. 3-A 

(Revised). State of California, 1963. 

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The information contained herein is .furnished without warranty of any kind. Users 

should consider these data only as a supplement to other information gathered by 

them and must make independ?nt determinations of suitability and completeness of 

information from all sources .to assure proper use aad disposal of these materials 

and the safety and health of employees and customers. 

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MSDS': 001:1 

03/ 12/90 

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AlRICAN MICROTR.ACE 

. .. MSDS 

~ (',PneralInPormation 

Product Name: - ;Maa=Gto®,'1Mah'*fo ®'AS"-` MoIecular Formula: MnSO4H2O 

Chemical Name: Manganese Sulfate Monohydrrate Molecular Weight• 169.01 

Contact: American MicroTrace Phone: (800) 544-3155 

569 Central Dtive, Suite 201 or: (402) 729-6191 

V'irginia Beach, \/A 23454 Date Lssued: 2/27/91 

Fax Phone No: (804) 463-8156 

For Emergency Assistance Involving Chemicals - Call Chemtrec 

(800) 424-9300 

 ! 

ComponenC Manganese Sulfate Monohydrate CAS NUMBER: 

Permissible Air Concentration: 

Manganese Sulfate Monohydrate 5 mg/m 3Ceiling (ACGII-D (As Mn) Percent: 90 ~/o 7785-87-7 

Ferric Oxide - 5 mg/tn3 1.5°rb 1309-37-1 

Aluminum Sulfate 12 mg/m3 1.5% 1344-28-1 

Silica Dioxide 5 mg/m3 1.00/0 7440-21-3 

c First A3d Measures 

Ingestion: If large amounts are ingested, if victim is consaous, immediately give 2 to 4 glasses of water, and induce 

vomiting by touching finger to back of throac Do not give carbonates. Get nffedical attention 

immediately. t ~ _,.. ,..: t ' i . ~~ ~ 

~ ; Y 

Eye Contact: If eye irritation exists, flush thoroughly with plain water. 

Skin Contact If sidn irritation exists, wash with soap and water. 

D. xazards Information JAN 31 I999- ' 

"Health EfPects" 

Inhalation: May crause irritation of nasal membranes and upper respirat tra 

Ingestion: of large amounts may be harmful. Eyes: Contact may 

Skin: Contact may cause irritatiorL -- -W1 -.— 

Medical Conditions Possibly Aggravated: Respiratory problems could be aggravated by inhalation of dust 

Unusual Chronic ?oadclty: Some manganese compounds are known to cause acute and chronic toxidty which 

primarily involves the central nesvous system, however, there are no known reports 

of such effects from exposure to manganese sulfate. Chronic exposure to silica dust 

may cause silicosis, a fiberotic lung disease. 

"Fire and Explosion Data•• 

Flash Point: N/A , 

Fire and E.eplosion Hazard: Negligible fire and explosion hazard in dust form when exposed to heat of flame 

Flammable Iimit• N/A 

Unusual Fi1e and Explosioa Harards: None 5/15/91 

°r.3 
L Precautions/Procedures 

Fire Exdnguishing Agents Recommended: CDry chemical, carbon dioxide, water spray or foam) as appropriate ! 

for surrounding mateiiaL 

Fire E_Ytingui.shing Agents to Avoid: None 

Spedal Fire Fighting Precautions: Use self contained breathing apparatus 

Eng3neering Controls: Use containment and/or local exhaust ventilat3on to control dust 

Normal Handling: Avoid contact with eyes, skin, and clothing. Avoid breathing dust Maintain good 

housekeeping practices. 

Storage: Keep dry 

Spill or Leak: Collect and contain for salvage or disposal. Vacvum or sweep keeping dust to a minimum. 

Special Precautions/Procedures/IabeLs Instructions: See "Normal Handling" 

Note label signal words'Warnin¢1• 

Personal Hygiene: Wash thoroughly after handling and before eating or smoking. 

;•L- - r •L n - 

Respiratory Protection: Use NIOSH -,MSHA approved dust respirator if irritation exists or in dus ty areas which ----- 

e:cceed mg/m3 

_ - 

Eyes and Face: Glasses, goggles, or face shields are recommended if initation eaists. 

Hands, Arm.s, and Body: Gloves and protective clothing should be used if irritat9on exists. 

Other Clothing a.nd Equipment: None 

~ Phvsical Data 

Description: Light Tan to Pale Gray Material PH: 3.0-5.0 ® 109•6 Solution 

Boiling Point-- N/A ' Vapor Pressvre & Deasity: N/A _ 

Solubility in Water. 50% by weight Melting Point: Decomposes above 450° C. 

• K= n , 

~ . . 

Stability: Stable under normal temperatures and pressures. Polymetiration: Will not occur 

Incompatibllities: None 

Decomposition: Thermal decomposition may release toxic fumes of manganese. Possibly ozides of sulfur. 

L Environmental 

EPA Hazardous Substance: Yes 

DOT Hazard Class: N.O.S. Orm E NA 9188 RQ 

RCRA Status of Unufed Material: Not listed 

J. Rerenccs °e .. -. _ . 

Federal RQ Quantity: 1000 LB/454 KG 

Waste Disposal Method: Landfill or field 

appliccation at agronomic rates 

Permissible concentrat3oa references: "TLV'' -"'Tlueshold Limit Values for Cheniical and Physical - - 

Agents in the Work Environment' 1084-85 (ACGIIO 

Harard Informatlon References: "Merck Index" lOth Edition, 1983. Merck and Company, Inc. 

i_~MK • i_ • tiT.- . •• 

Thi.s chemical may be subject to the reporting requirements of Section 313 of Title III of 49 CFR 372 of the Emergeney 

Plann3ng and Community Right-To-Know Act 

Ibic matertal sa,/'ety sbeet is ofjered solely for your informatton and investigation. It provides no 

warranties ettber express or impltect; and assumes no responsibtlity for tbe accurary or completeness 

of tbe data contatned berein 5/15/91 

eW 
MATERIAL SAFETY DATA SHEET 

ZINOX 

NPCA - EBfIS HAZARD RATL\G 

Health I 

Flammability 0 

Reactivity 0 

Maximum 

Personal Protection E 

SECTION I 

:vtA`'UFACTC:RER 

EMERGENCY TELEPHONE 

CHEMIC4L NAME 

TRADE NAME 

CHEMIC4L F.aMILY 

FORMULA 

CAS NUMBER 

AMERICAN CHEMET CORPORATION 

P.O. Box 1160 

East Helena, MT 59635 

(406) 227-5302 ATTN: W. H. Porter or Dan Brimhall 

Zinc Oxide 

ZINOX 

Zinc Oxide 

Zn0 

1314-13-2 

SECTIO\' II HAZARDOUS INGREDIENTS PEL + TLV 

ZItiC OXIDE °c RESPIRABLE DUST 5 mg/m' 

97.0 0(T)ypical) (94.5% 'v1in.) TOTAL DUST 10 mg/m' 

Exposure is governed by the 8 hour TN4:a established for Zinc Oxide. Zine Oxide is not carcinogenic material as listed by OSHA (39CFR1910) or ACGIH (Appendix 

A. Threshc'.d L imit V_!_es `or Chetnica] S_bstances 1984-!9S5). 

SECTION III PH1'SICAL DAT:4 

Boiling Point (f): Specific Gravity: Vapor Pressure: Percent Volatile by volume (9): 

NA H 0=1 5.6 NA 0% 

N'apor Densiry: Evaporation Rate: Solubiliry in VVater: Melting Point: Appearance and Odor: 

NA NA Less than 1%. 3590`F Fine poader. Cream yellow. No odor. 

SECTION IV FIRE & EXPLOSION IiAZARD DATA ~ 

Flash Point F)ammable Limits 

LEL UEL 

NA NA NA 

Extinguishing Media: NA 

,ecial Fre Fghtin gProcedures: None known 

-ual Fire Fehtins Procedures: None knoa•n. 

' SECTION V . HEALTH HAZARD DATA 

Threshold Limit Value: See Section II 

Signs, Symptoms, and Effects of Overexposure: Nausea, chills, diarrhea. May cause upper respiratory irritation; skin irritation (oxide pox); fever, eye irritation w°ith 

redness, pain and conjunctii•itis; preexisting lung diseases may be aggravated by exposure. Could result in respiratory irritadon; preexisting lung diseases may be aggra- 

%ated by extosure. Could result in respiratory disease if over exposed on a chronic basis. _ 

Primary Routes of Entry: Inhalation and/or ingestion. 

Emergency artd Fm Aid Procedure: Remove to fresh air. Lay patient down. Cover w•ith blanket. If irritated, flush eyes and skin w•ith large volumes of fresh uater 

for 15 minutes. Refer to MD. 

SECI'ION VI REACTIVITY DATA 

Stable x Unstable 

Conditions and Materials to Avoid: Mass build up under reactive conditions such as but not limited to acids. Zinc Oxide may react violently w'ith strong reductants 

such as orgaeic compeu:tds, i.^.cluding ch:o; inated rubber at tempeatures over 4'0°F, (a Flammability toaction with linseed oii uac reported once), and metals including 

but not limited to Mg. 

Hazardous Decomposition Producu: Above melting point (3590°F) zine fumes may result. 

Hazardous Polymerization: wll not ottvr. 

SECTION VII SPILL OR LEAK PROCEDURES 

Steps to be taken in case material is released or spilled. Clean up with vaccum or conventional tools. Avoid dusting. 

Waste Disposal Method: Approved land fill. 

SECTION VIII SPECIAL PROTECTION INFOR.N4ATION 

Respiratory Proteaion: Cartridge q'pe filter or approved dust mask. Refer to Respiratory Protective devices approved by Bureau of Mines Circttlar IC 8436. 

Ventilation: To keep below listed TLV in Seaion II, use general dilut9on type ventilation. 

Protective Gloves: Wear if skin contact is probable and skin is sensitive. . 

Eye Proteaion: Safety glasses or goggles. 

Other Protective Equipment: Lon¢ sleeve shirts if contact is probable and skin is sensitive. 

qECT10N IX SPECIAL PRECAUTIOINS 

:cautions :o be taken in handling and storing: Keep lids tiehtly sealed. Store in cool, dry place. 

.her Preca::ions: Do not take internallv. Avoid prolonged contact u•ith skin. Wash with soap and uater after contact. 

. SECTION X SARA TITLE III 

This produca contains a zinc compound (Zine Oxide) and is subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act cf 1986 and 10 CFR Part 372. 

Date: 5`.arch I, 1989 (Rev. 4) ~~i 
.~ . _ ' 

. . 

'~ i ~ LO 

P.O. Box 1178 

Columbus, GA 31902-1178 

Telephone 334/291-0930 • Facsimile 334/291-3237 

MEMORANDUM 

To: David Ousley, Alabama Department of Environmental Management 

From: Robert Maner, Environmental ManagN , YVaAV--, 

Re: Fluorine Mass Balance 

Date: May 28, 1996 

In our conversation last week, you suggested it might be beneficial to perform a fluorine mass balance on a 

dried and fired brick from Boral plants in Phenix City. I leamed that a fluorine mass balance had been 

performed while these plants operated as Bickerstaff Clay Products. I have summarized the results below. 

Plant/ Product Main Body 

Coastituent 

dried brick 

fluorine content 

fued brick 

fluorine content 

fluorine 

evolved 

•/. 

evolved 

emission factot 

Ob HF / ton ware 

Atlanta, GA Plant Shale 606 ppm 280 ppm 326 pom 53.8 0.69 

Bessemer Buff Bod Shale 679 ppm 339 ppm 340 ppm . 50.1 0.72 

Bessemer Standard Red Shale 603 ppm 166 ppm 437 ppm 72.5 0.92 

Phenix City Plant 1 Alluvial Clay 454ppm 84 ppm 370 ppm 81.5 0.78 

Phenix Ci Plant 3 Alluvial Cla 348 pM 1 56 R2m 292 22M 84.9 0.61 

1) A bufi body brick describes a Gghter color bricJc as a result of lowet iron conteat in raw materials. 'I1te raw materiai may alao 

have a higher alumina content and higher mahaing temperatute. 

2) The emission factor is developed using the following formula: 

= fluorine evolved (ppm) x 2000 QbJton) x 20 Ib HF 

1,000,000 x 19 Ib F 

= 292 Faets-gueaae 2000 Ib 20 Ib HF 

1,000,000 ton 19 l" 

0.61 Ib HF / ton fired ware 

These mass batance results were produced by Clemson University using a pyrohydrolysis test and are 

relatively consistent with mass balance results for other Boral plants. 

The Phenix City Plant 3 stack test that I referenced in the earlier emissions inventory for the Phenix City 

plants was also conducted by Clemson University. An emission factor of 0.451b HF / ton of fired ware is 

produced by dividing the average emission rate by the production rate during the test. This is 74% of the 

emission factor produced from mass balance data for tthe same plant. This is consistent with experience that 

shows actual stack emissions to be approximately 65% of predicted maximum emissions using the mass 

balance technique ("Monitoring for Hydrogen Fluoride Emissions in the Ceramic Manufacturing," Ceramfc 

Induslry Magazfne, 143 (1) p. 3840 (1994). 

The emission factor derived from the stack test at Plant 3 appears to be the most conservative emission 

factor (produces the lowest estimated emissions) based on the compilation of all data. The potentdal 

production of each plant coupled with this emission factor produces potential emissions of hydrogen 

fluoride in excess of ten tons per year. Based on this estimate, I will continue to assume that our 

manufacturing sites are Title V major sources. If you have any questions, please call me at 334-480-2487. 

01- 
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EPA iVIACT Information Collection 

Request Response 

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MA.CT Information Collection Request Response 

from - 

Boral Bricks, Inc. 

Table of Contents 

• Information Collection Request 

• Appendiz A - MSDS's 

• Appendi.g B - Test Data 

Ik 
Enclosure 2 

INFORMATION REQUEST FOR BRICK AND 

STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS 

I. Instructions 

Please return the completed information request to: 

Bruce C. Jordan, Director 

Attn: Bill Neuffer 

Emission Standards Division (MD-13) 

U. S. Environmental Protection Agency 

Office of Air Quality Planning and Standards 

Research Triangle Park, North Carolina 27711 

If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at 

(919) 541-5435. 

This information request should be completed for each facility that manufactures brick and 

structural clay products, including facilities that are not major sources. Information is 

requested for all processes at your plant that emit hazardous air pollutants (HAP's), 

including those processes that are not associated with brick and structural clay 

products manufacturing. Sections II through VII request information specific to brick 

and structural clay products manufacturing, and Section VIII requests information on 

emissions of HAP's from other processes located at the facility. Processes that may enut 

HAP's include those processes that use or handle any materials that contain a HAP 

compound, all processes with elevated temperatures, and all other processes in which HAP 

compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is 

included as Attachment 1 to this information request. Attachment 2 provides background 

information on the requirements of the Clean Air Act and explains how the information 

requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations 

and acronyms used in thi.s information request. 

Several tables are provided throughout the information request for your convenience in 

answering the questions. An example response is given (shaded first column or row) in each 

table. If additional space is needed to respond, please niake copies of applicable pages. If 

necessary, please make copies of this information request for additional facilities. No 

additional emission testing or monitoring is required to respond to this request. 

II. General Facility Information 

A. Name of company Boral Bricks, Inc. 

Name of facilityPhenix City. Plant 3 

Page 1 of 24 

W 
Facility address: 

No. and street 100 Brickyard Road, Plant 3 

City Phenix City State AL Zip 36869 

Latitude and longitude coordinates of plant: Lat: 32124'03.88" N Long: 85° 00' 12.88" W 

Standard Industrial Classification (SIC) Code(s) of brick and structural clay products 

manufacturing operations 3251 

Dun and Bradstreet No. 00-327-5682 

Total No. of employees for company > 1,500 for facility 33 

(If facility is a foreign subsidiary or if company has foreign subsidiaries, include 

number of employees not based in the U.S.). 

Please complete the following shift information for the facility: 

Shift No. of employees Hours per shift Days per year 

1 26 8- 12 359 days - 25 employees 

365 days - 1 employee 

2 6 8- 10 359 days - 5 employees 

365 days - 1 employee 

3 1 8 365 

B. Respondent name Andrew S.R. Wichers 

Respondent title Regional Safety Manager 

Respondent address (if different from above) and telephone number: 

No. and street P.O. Box 1178 

City Columbus State GA Zip 3 1 902-1 1 78 

Telephone No. (334) 480-2407 

Name and telephone number of technical contact person (if different from above) 

Name David Johnson Telephone No. ( 334 ) 480-2487 

Page 2 of 24 

let 
I1I. Information on Operating Permits and Applicable Federal Emission Standards 

A. Please provide copies of relevant parts of all operating permits and permit 

appGcations for your facility. Relevant parts include the sections that provide specific 

information and data on: processes that emit HAP's; the use of HAP- containing 

substances; emission levels for HAP and surrogate pollutants (i.e., VOC for organic 

HA.P's and PM for metal and other particulate HAP's); emission control device 

design and operation; monitoring and operation and maintenance (O&M) procedures 

for control devices; and generation and releases of other niedia such as wastewater 

and solid waste that are associated with the operation of air pollution controls for 

brick and structural clay products manufacturing processes. 

If the operating permit or application contains the same information requested 

in any part of this questionnaire, you may respond to the requested information 

by referencing the page or section of the permit/appGcation to avoid 

duplication. If you reference your permit or application, you must supplement your 

response with all of the additional information requested in this questionnaire that is 

not included in the permit or permit application. If you prefer, you may submit the 

requested information from your permit/application on a 3-1/2 inch diskette. 

B. If any source or emission unit at this facility is subject to a New Source Performance 

Standard or other Federal emission standard, please identify the source and applicable 

standard. Exa.mples of applicable NSPS include 40 CFR 60, Subpart 000 - 

Standards of Performance for Nonmetallic Mineral Processing Plants, and 

40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers in 

Mineral Industries. 

No NSPS ayylicability determination has been made for this facility at this time. 

IV. Brick and Structural Clay Products Production and Raw Material Consmption 

Information 

A. Please provide the 1996 production rates and the current production capacity for 

each type of brick and structural clay product manufactured (e.g., structural brick, 

clay sewer pipes, structural clay tile, etc.). Note that production data should be 

provided in units of tons per year (tons/yr). 

Product 1996 production (tons) Production capacity (tons/yr) 

Brick (Fired Weight) 122,491 135,289 

Page 3 of 24 

/D( 
B. Please provide the type and amount of each raw material and body additive used in 

1996 for manufacturing brick and structural clay products at your facility. Examples 

include clays, shale, and any additives that are mixed into the raw material prior to 

forming. Indicate additives by chemical compound, rather than by trade nanze. If the 

information requested is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than providing the informa.tion 

below. 

Raw materiaVbody additive Amount used in 1996 (tons/yr) 

Lignosol (Additive A) (wet weight) 198 

Rome Shale (wet weight) 11,475 

Hallmark Fire Clay (wet weight) 894 

Kaolin-Eufaula (wet weight) 227 

Clay (mined locally) (wet weight) 128,000 

C. If available, please provide a copy of the MSDS's for the raw materials and additives 

listed above. 

See Appendiz A 

D. If available, please provide chemical analyses, including fluorine, metals, and organic 

content, of the raw materials listed above. 

See Appendia B 

Page 4 of 24 

lD z 
E. vsing Table 1, please provide information on the consumption and HAP 

composition of all glazes and colorants that contain HAP's or HAP precursors and 

that your facility applies to brick and structural clay products. Indicate whether the 

coatings are glazes or colorants. Also indicate the type of product that the coatings 

are applied to and the total weight of coatings used in 1996. If the glazes or 

colorants are formulated at your facility indicate so and provide the production 

capacity. List each ingredient of the glaze or colorant. Beside each ingredient, 

indicate the total amount of the ingredient used in 1996. If the information requested 

in the table is contained in your facility's operating permit or permit application, you 

may reference the applicable sections of the permit (or application) rather than filling 

out the table. 

F. In the space below, piease indicate any glazes or colorants used by your facilit:, hat 

do not contain HAP's and are substitutes for HAP-containing glazes or colorai;r.:; 

used by your industry. Indicate which HAP-conta ining materials the non-HAP glazes 

or colorants replace. Describe any limitations on the use of those substitute glazes or 

colorants. 

G. If your facility colors brick and structural clay products by flashing, please indicate 

the types of substances used to flash the products and the amounts of those 

substances used in 1996. 

Substance Amount used in 1996 Units specifyl 

Natural Gas Unknown - Not Measured Not Applicable 

Propane Gas back-uy fuell Unknown - Not Measured Not Applicable 

H. If available, please provide a copy of the MSDS's for the glazes and colorants used by 

your facility. If your facility prepares its own glaze, please provide any available 

MSDS's for the glaze ingredients. 

See Appendiz A 

Page 5 o f 24 

/D3 
Type of product glazed or 

colored 

1996 consumption (tons/yr) 

I Produced at facility? (yes/no) 

I Production capacity (tons/yr) 

Total usage (weight) of each 

ingredient (that is a HAP, 

contains a HAP, or is a HAP 

precursor) in 1996 

Brick 

179 

kme 

Not Applicable 

Ingredient 

Total 1996 

usage, tons 

Iron Chronute 

Green Chromium 

Oxide 

Zinc Oxide 

Manganese 325 

Mesh 

Liniestone GA 

Dolomitic 

Manganese 

Sulphate 

OA ~ 

24.12 

0.90 

1.75 

:1Zix? 

88.23 

TABLE 1. CONSLTMPTION AND HAP COMPOSITION OF GLAZES AND COi.nRANTS 

I Type (e.g., glaze, colorant) EXAMPLE: ColorantlCoatings 

Glaze 

Page 6 of 24 

/'~ el 
If additional space is required, please make copies of this page. If the information requested in 

the table is contained in your facility's operating permit or permit application, you may reference 

the applicable sections of the perrnit (or application) rather than filling out the table. 

Page 7 of 24 

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D. Using Table 7, please provide the following information on cunent monitoring 

procedures for each of the control devices listed in Tables 6A to 61): parameters 

monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices 

used (e.g., differential pressure transducer, thermocouple), and recordkeeping 

practices (e.g., manually recorded in log book, continuously recorded by electronic data 

acquisition system). Describe briefly other operation and maintenance (O&M 

procedures for each control device. If the information requested in the table i.s contained 

in your facility's operating permit, you may reference the applicable sections of the 

permit rather than filling out the table. 

VII. Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing 

A. Please describe all pollution prevention practices (i.e., process modifications, such as reuse of discarded or rejected materials, or any practice that prevents or reduces the 

amount of air emissions, or the generation and release of solid waste or wastewater 

associated with the operation of air pollution controls). If the information requested 

here is contained in your facility's operating permit, you may reference the applicable 

sections of the permit rather than providing the information below. 

This facility: 1) reuses waste heat from the kiln to heat the dryers (and to a lesser 

degLee the holdin rooms)• 2) recycles floor sweepings and scrap/waste clay back into 

the brick body; 3) rec cyy les areen brick back into the brick body; and 4) recycles off-spec 

brick Qrog) back into the brick body. 

Page 22 of 24 

120 
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/z/ 
TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOURCES I Process/emission source/SIC Code(s) I HAP's eniitted I Estimated annual emissions, I 

tons 

Not Applicable 

SIC 

SIC 

SIC 

SIC 

If the information requested in the table i.s contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the table. 

Page 24 of 24 

/ZZ 
ivtdterlal oale(y vata Jneet 

May be used to comply with 

OSHA's Hazard Communication Standard, 

29 CFR 1910.1200. Staridard must be 

consulted for specific requirements. 

IDENTITY (As Used on Label and LJst) 

IRON MANGANESE OXIDE BLACK #320/318 

U.S. Department of Labor 

Occupational Safety and Health Administration 

(Non-Mandatory Form ) 

Form Approved 

D OMB No. 1218 -0072 CAS# 11115-91-6 

Notc: 8/ank spaces are not permltted tl any item is not applicable, or no 

infovmation is evailabte, the space must be marked to indica'e that. 

Section I CHEMICAL FORtiULA - Fe2 0 3 Mn2 0 3 

Manufaclurer's Name Emergency Telephone Number 

404 3336-4766 

Address (Number, Street, City. State, and I!P Code) Telephone Number for Information 

7 Swisher Drive (404) 386-4766 

Cartersville, GA 30120 Date Prepared 

September 21, 1987 

Signature of Preparer (optlonal) 

Section 11 — Hazardous Ingredients/identity Informatlon 

Other Limits 

Hazardous Components (SpeciBc Chemical Identity; Common Name(s)) OSHA PEL ACGIH TLV Recommended % (optional) 

HAZARDOUS INGREDIENTS - NO ADDITIONAL INGREDIENTS 

IRON OXIDE FUM.ES as Fe 5mg/m' 

RESPIRABLE DUST 5mg/m3 

MANGANESE COMPOUNDS 5mq/m3 

(CEILING r AS Mn) 

Section III — Physical/Chemit:al Characteristics 

Boieng Point Specific Gravily (H20 - 1) 

N/A 4,8-5 

Vapor Pressure (mm Hg.) Meltfng Poitnt 

Vapor Density (AIR - 1) Evaporation Rate 

(Butyl Acetate - 1) 

Sdubility in water 

.INSOLUBLE 

Appearance and Odor 

BLACK POWDER - ODORLESS 

SectionIV — Fire and Explosion Hazard Data 

Flash Poir>; 

N/A N/A N/A ( N/A 

Extinguishing Media 

WATER DRY CHEMICAL • 

Special Fre FtghUng Prooedures 

Nt1NF 

Unusual Fre and Explosqn Hazard.l 

NONE 

(Reproduce locally) . HAZARDOUS MATERIALS IDENTIFICATION SYSTEMS (HMIS) OSHA 174, Sept. 1985 

HEALTH 0 FLAMMABILITY 0 REACTIVITY 0 

/z3 
, D 

;ection V — Reactivity Data 

lability Unstable Conditions to Avoid 

NONE 

Stable 

X 

)compatibility (Materials to Avold) 

NONE KNOWN 

azardous Decomposition or Byproducts • 

~ ection VI — Health Hazard Data 

oute(s) of Entry: Inhalation?YES Sk1n? NO Ingestion? YES 

ealth Hazards (Acute and Chronic) 

'AN ,AN .S . IS CHEMTCALLYREATED AS PART OF THIS ST AT.R PTGMENT CRY TAt OVER EXPOSURE TO 

'0 MANGANESE IN AN UNREACTED FORM MAY RESULT IN CHRONIC MANGANESE POISONING(MANGANISM) THE 

:ENTRAL NERVOUS SYSTEM IS THE CHIEF SITE OF EFFECT. TO DATE THESE TYPES OF EFFECTS HAVE NOT 

arcinogenicity: NTP? NO IARC Monographs? NO OSHA Regulated? NO 

EEN ASSOCIATED WITH THIS PRODUCT. 

gns and Symptoms of Ezposure 

X('F.SSTVR EXPOSttRF TO AIRAO N. D 1ST WITI RF.S T.T IN FFFVCT SIMTIAR TO THAT OF NUISANCE TYPE 

UST THAT IS PARTICULATE MAY REDUCE VISIBILITY AND/OR CAUSE UNPLEASANT DEPOSITS IN THE EYES, 

edical Conditions E~IR~ AND NOSE. INJURY TO THE SKIN OR MUCOUS I~ E MBRANES CAN OCCUR BY DIRECT 

~neralty Aggravated y t"pos

- -- 

ure94.rVAl~iT/+AT A/•TTAN !

sClim iiyiiyi, y!

~ D DY DTnA ■ ai iei00ltVtlO yie'DAt1Q Q PTIy n7 L`A1yT1*

~

~ ATL'!`CCQADV r.AD DCA~,~ QI+ ,i yaa:a z ' a--pia-~eear 

DUST. 

nergency and Frst A1d Procedures 

KTULCf]NTACT — LteCld tJTTH SneD eNn GIATFR EYE CONTACT — FLUSH WITH LARGE AMOUNTS OF WATER • 

ONSULT PHYSICIAN. INHALATION — REMOVE FROM DUSTY AREA. 

ection VII — Precautlons for Safe Hangling and Use 

eps to Be Taken In Case Material Is Released or Spilled 

ANDLE AS NORMAL SOLID WASTE, SCOOP UP BY SOIME MEANS AND PLACE IN A WASTE CONTAINER 

aste Disposal Method 

ASTE MATERIAL CAN BE BURIED IN A APPROVED LANDFILL OR HANDLED AS INERT WASTE IN ACCORDANCE 

ITH FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGUL 

to Be Taken in Handlfng and 

TO DRINK 

her Precautions 

NONE _. 

ection VIII — Control Measunrs 

-spiratory Protectlon (Speclly Type) 

IOSH APPROVED FOR DUSTS, MISTS AND FUMES. DO NOT EXCEED USE LIMITS OF THE RESPIRATOR. 

ntilation I Local 

Mechanicel (Generaq 

:)tective Gloves Eye Protection 

JBBER, CLOTH OR PLASTIC GLOVES I SAFETY GLASSES 

ier Protective Ctothing or Equipment 

N/A 

)rk/Hygienic Pr8ctice3 

) NOT STORE NEAR FOOD AND DRINK. WASH EXPOSED SKIN FOR HYGIENE PURPOSES . 

Pe" Z • u.earo: , ose_a91-s29/AS17S 
Material Safety Data Sheet 

Substance Identification 

Identity. IRON CHROMITE 

Trade Names: CHROMOX 

Manufacturer: The Prince Manufacturing Company 

One Prince Plaza 

Quincy, IL 62301 

217-222-8854 

CAS #: 1308-38-9 

Emergenry: Chemtrec 

1-800-424-9300 

Components and Contaminants 

Chemical Name CAS# OSHA PEL ACGIH TLV Percent 

Chromium Cr+3 7440-47-3 OS mg/m3 OS mg/m3(TWA) 30-45% Cr 

Silica, Crystalline Quartz respirable dust 14808-60-7 0.1 mg/m3 0.1 mg/m3('I'WA) 1.2% Si02 

Physical Data 

Boili.ng Point: NA Specific Gravity (H=O =1): 4.4 

Vapor Pressure (mm/Hg): NA Melting Point: 3350 - 4000° F 

Vapor Density (Air=1): NA Evaporation Rate (Butyl Acetate =1): NA 

Solubility in Water. insoluble 

Appearance and Odor black powder, no odor. 

Fire and Explosion Hazard Data 

Flash Point: Not combustible 

Flammable Limits: LEL NA UEL NA 

Extinguishing Media: ' Foam, COV or dry chemical or water. 

Special F'ire Fighting Procedures: In the event of fire, wear full protective clothing and NIOSH-approved selfcontained breathing apparatus with full face piece operated in the pressure 

demand or other positive pressure mode. 

Unusual F'ire and explosion hazards: Not combustible. 

Reactivity Data 

Stabilit}+: Stable under ordinary conditions of use and storage. 

Conditions to avoid: None Known ". 

Incompatibility (materials to avoid): None Known. 

Hazardous Decomposition or Byproducts: None Known. 

Hazardous Polymerization: Will not occur. 

Health Hazard Data 

Route of Entry: INHALATION: May cause delayed respiratory disease if dust is inhaled over a 

prolonged period of time. 

SKIN: No. 

INGESTION: Ingestion of Iron Chromite may cause abdominal pain and 

nausea. 

_..._ . 

Iron Chromite, Page 1 

April 1991 

/'!2Jr 
Health Hazard Data (rottt.) 

Health Hazards (Acute and Chronic): Respiratory disease may result from prolonged overexposure. Can cause eye 

irritation. 

Carcinogenicity. NTP: No IARC Monographs: Yes (Silica) 

Signs and Symptoms of Ezposure: Excessive inhalation of dust may result in shortness of breath and reduced pulmonary function. Symptoms of silicosis include impaired pulmonary function 

and wheezing. 

Aggravation of Pre-existing Conditions: Persons with impaired respiratory function may be more susceptible to the effect of this substance. 

Emergency and First Aid Procedures: IF INHALED, remove to fresh, air and seek medical attention for any breathing 

difficulty. 

IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. 

IN CASE OF EYE CONTACT, flush eyes imme:liately with water for at least 

15 minutes. Seek medical attention if irritation persists. 

IF INGESTED, induce vomiting immediately by gi-ving two glasse: " water 

and sticking finger down throat. Never give anything by mouth to ::: ~ :aconscious person. Call a physician immediately. 

Precautions for Safe Handling and Use 

Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratory 

protection. Recover uncontaminated material for use. Vacuum or sweep 

remaining material, keeping dust to a minimum. 

Waste Disposal Method: Dispose of unreclaimable material in a RCRA=approved waste facility. - Handling and Storing Precautions: Protect containers from damage and keep closed when not in use. 

Other Precautions: - Observe good personal hygiene. Wash after haadling. 

Control Measures 

Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or is 

anticipated. OSHA standard 1910.134 or ANSI Z88.2-1980 speeifications are 

' recommended. ' 

Ventilation: A system of local and / or general exhaust is recommended to keep employee 

exposures below the Airborne Exposure Limits. Local exhaust is generally 

preferred because it can control the emissions of the cpntaminant at its source, 

preventing dispersion of it into the general work area. Please refer to the 

ACGIH document, "Industrial Ventilation, A Manual of Recommended Prac- 

— tices', most recent edition, for detaiLs. 

Protective Gloves: Yes 

Eye Protection: Safety goggles are recommended. . 

Other Protective Clothing or Equipment: Use other protective equipment when necessary in order to avoid prolonged 

exposure to skin. 

Work and Hygienic Practices: Observe good personal hygiene. Wash after handling. 

- SARA Title III Section 313 Supplier Notification 

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency 

Plaaning and Community R3ght-to Know Act of 1986 and of 40 CFR 372.45: 

Component CAS # % by Weii}ht 

Iron Chromite 1.308-38-9 30 - 35% Cr 

This information must be included in all h: 's that are copied and distributed for this m,ttriaL — 

iron Chromite, Page 2 

April 1991 

f ~~ 
Material Safety Data Sheet 

May ba ussd lo oomply wilh 

OSIIA'rt Flazard Communkallon Slandald, 

29 CFfi 1910.1200. Standard musl bo 

consulted lor specHlc rraqulrKnents. 

U.S. Department of Labor 

Occupstlonal Saf•ty and Health Adminittratlon 

INon-Mandatory Form) 

Form Approvod 

OM8 No. 1218-0072 

IOEPITTTY (Aa Uad on LibM and LktQ I Noro: Bran# ~.csa an nor p. ~rrvrtrr.0. 1' any A'•m ia nor wpkcao+a. or 

q 5481 Ochre hhartn•aon lt av&,laD)v, cn• sp&C• musf be mark•d to nd;ca'•c 

Sectlan I 

1.1LnUfac1ur44'3 Nam• Em•(q•I 

Saj fiern Color ac Chemical ~(Y+ ~+~b 

,►Gdrau (Numos•. SvwoC C)y, Stan, an0 ZIP Cod•) T•I• or~ • N w~o~. ~r i~,~ at~at 

P.O. Box 15 0 7 t4o4) j86- ~/66 

Oala Praparad , 

7 Swisher Drive May 21 1986 

Cartersville, Georgia 30120 

Si4nalur• 01 Pr•puK (qodanaq L!~,k 

Se•ction 11 -- Huarilous Ingredlentslldentlty Inlormatlon , 

Other Limits 

Huardou>t Compon•M1 (Sp•c iBc Cn•m"Id•ntlty; Common Nun•(st) OSHA PEL ACO1H TlV Rrrcomm•nd•d K loo! 

M548 Ochre (Fe?0-1-XH2O)Natural Iron Oxider Non Established; lOmg/L None 

Note: Ochre is • listed as Hazardous because of t•he nuisance dust 

that may be created in handling t e pro uct. 

CASt4 1343 -8 1 - 3 

1 ( . 

Sec(lon III — Physlcal/Chemical Characterisllcs 

Bai,ng PaM Sp•cifiC dravity (H=O . I) 

N/A 3.2-3.E 

Vapor Prossurra (mrn Hq.) M41lln9 PoirM 

N/A • N/A 

Vapor Oansity (AIA • 1) Evaporatbn Ftale 

N A I (8utyl /ketate • 11 N/A 

Sduafity in Water 

Insoluble 

App•atancta and Oda 

Yellow Powder - No Odor 

Sectlon IV -- Fire end Exploslon Hazard Data 

Ftash Paru (M•Ihod Us•d) N/A Flammablra Umils LEL UEL 

• N/A N/A 

Esunquisfwnq MWita N/A r-- -- - — - - — — - — - - : 

Sp+c,aJ Fra FiqhbnQ Procedu(t+s 

None Required ' 

Unusua! Fr• and Explosan Hazsrdlt 

No ne 

IF•producfa locally) OSHA 174, 3apl Ig 

/,;2 7 
ttcs+ittt-llr-rw ~ o~e~~ • t •Bed 

3NON ie ~p ~ e1d 

Q32iIn63a 3NON lvewdtnb3 )o 5un4tq0 •AIt>•tad i614j0 

TINOI•LdO ~~~d ~~ 3 'I~fNOI•LdO Aqo •nruep,d 

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"''~ R 

3NON R~ I 'IfINOI,LdO I 

. S sneVY3 Rm1 UontiTIV•A 

631MJ°JnS ,LnB 'IKNOI,LdO SI .Lsna 3JNVSInN L103 03A0Mdd'd aO,Lh2iIdS3M 

(odtl Ar>@'dS) uo"totd kotendsrd 

cainseoyy I0Jlu03-- IIIA u0 11 3 ;S 

- - tuo!1n~~~~ teV10 

',LSna 3AISS33X3 3,LH3210 lIJIHM SNOI,I,vn,LIS QIOAY 

8uvo1S Pvt 6utIDvtH w veM*1 19 ol euo!intm,d 

TII3aNV'I a3A02iddV NY NI 7t1SOdSIa 31SYt•1 aI'IOS 7HW2iON 

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Q3td I na32s< 3 NON 

sa,npow)d D!Y Icn~ pue Aouv6nw: 

1 . 

' NMONX 3NON •intod:3 Aq paleAsIGBr Anviouso 

tuol11Pu0D R*"YI 

~ ssoj 9a64slotu oa anp oulciaeLlo xo SSaUAlp 

mtntod:3 ;o twotduiRg pve tu8±S 

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MojjeMB lou op paqaosqe aq jouue, 's-lH9 'I OW •Oi AU-zsnp aauesinN 

Luonsebul lu!lS 009e1*Wl :A+ni3 lo It?etnoti 

NleCI pJMH 411 89 11 — M uOIlaaS 

~ x 9*0OpNrM 

NMON:{ 3NOPi UOPTIuM140d 

D!onr ol 1UGTIIDuoO troa0 Aeyr I tnoP,ersH 

• ttonpaW8 jo uofl!sadwaoo tnopt*reH 

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{OJaAY o! eleuolriY) Rllliqlledwoou) 

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uMOUx t3uoN v,oAr a won!au00 I I t,lan:un Nr•c+,s 

s1s0 MIAIlOsoy — A uo11DaS 

/;-V 
MATERIAL SAFETY DATA SHEET 

Section I - Product Identification 

The Georgia Marble Company 

1201 Roberts Boulevard, Building 100 

Kennesaw, Georgia 30144-3619 

Emergency Telephone: (770) 421-6508 

Prepared by: Trevor G. Lamond, Technical Director 

Trade Name: 

Ground limestone/ Calcium carbonate 

Production Locations: Marble Hill, Ga, Sylacauga, AI 

Chemical Identity: Product consists of ground limestone (CAS Number: 

1317-65-3), which is a natural ptoduct composed of Calcium Carbonate 

(CAS Number471-34-1) and from 1-3% Magnesium Carbonate (CAS 

Number 546-93-0) together with various other natural ingredients at trace 

levels. 

Section II - Hazardous Ingredients 

Hazardous Materials Identification System 

Health Hazard 0 

Flammability Hazard 0 

Reactivity Hazard 0 

Personaf Protection E 

Hazardous Ingredients TLV (mg/m; ) 

Silica, Quartz .1 (Respirable Dust) 

Calcium Carbonate Dust 10 (Nuisance Dust) 

This product typically contains less than 0.3% crystalline silica. : 

In addition, there are also small but detectable amounts of the following 

other naturally occurring chemicals that are known to the State of 

California to cause cancer, birth defects or other reproductive harm. This 

warning is provided in the absence of definitive testing to prove that these 

risks do not exist. These amounts are typical quantities and may vary 

slightly with different lots. 

/p-f 
Chemical Name 

Arsenic 

Lead 

Typical Amount 

Less than 1 ppm 

Less than 1 ppm 

CAS Number 

7440-38-2 

7439-92-1 

Section III - Physical/Chemical Characteristics 

Appearance and Odor: Fine, White Powder; No Odor 

Boiling Point: N/A Specific Gravity: 2.71 

Vapor Pressure: N/A Evaporation Rate: N/A 

Vapor DensIter: N/A (Butyl Acetate = 1) 

Solubility in Slight Melting Point: N/A 

Section IV - Fire and Explosion Hazard Data 

Flash Point: N/A 

Flammable Limits: N/A 

Fire Extinguishing Media: N/A 

Special Fire Fighting Procedures: None 

Unusual Fire and Explosion Hazards: None 

ection V - Reactive Data 

This material is stable. 

Incompatibility: May react with acids to liberate carbon dioxide. 

This material will not polymerize. 

Hazardous Decomposition By-Products: None 

Section-Vl - Health Hazard Data 

Calcium Carbonate, the main component of limestones and marbles, is 

not on the NTP, IARC, or OSHA lists of carcinogens and there are no 

health effects associated with prolonged exposure to pure calcium 

carbonate. Crystalline silica (sand), a trace component of many limestone 

and marble powders, in its res irable form has been listed by IARC as a 

Type 1 carcinogen and the NTpP has stated that crystalline silica is 

reasonably anticipated to be a carcinogen. Also, prolonged exposure to 

crystalline silica has been found to cause silicosis, a noncancerous lung 

disease. 

Exposure: 

Inhalation: Can be irritating to the respiratory tract. 

R

e Contact: Mild irritation. 

in Contact: No effect. 

Ingestion: Minimal effect. 

First Aid: 

130 
Inhalation: Remove from area of exposure and to fresh air area. 

Eye Contact: Flush eyes with water for 10 minutes. If irritation 

persists, obtain medical attention. 

Skin Contact: Wash from skin with mild soap and water. 

Ingestion: Ingestion should not cause any significant health 

problems. 

Section VII - Snill or Leak Procedures 

Spill or Leak: Respiratory protection should be worn during clean 

up to protect from airborne dust. Measures should 

be taken to reduce airborne dust during clean up. 

Waste Disposal: Shovel up material and dispose of in landfill. 

Comply with applicable federal, state and local 

regulations. 

Section VIII - Special Protection 

Respiratory Protection: NIOSH/OSHA/MSHA approved dust respirator if 

T.L.V. is exceeded. 

Ventilation: Local exhaust: As required for dust to maintain 

airborne dust below the TLV. 

Mechanical: As required for dust. 

Eye Protection: Safety glasses or goggles. 

Special Protection: None required. 

Date Prepared: March 3. 1998 

131 
C georgia marble c«T,pany 

TNE NROVATOpS 1201 rober[s boulevard, building 100 • kennesaw, georgia 30144-3619 

N STOME °A00UCTS fax: (770)421-6507 (770) 421-6500 

MATERIAL SAFETYDATA SHEET 

Section I - Product Identification 

The Georgia Marble Company 

1201 Roberts Boulevard, Building 100 

Kennesaw, Georgia 30144-3619 

Emergency Telephone: (770) 421-6557 

lCenneth J. Meeks, Safety and Training Manager 

Risk Management 

Chemical Name: Calcium Carbonate 

Chemical Family: Marble; Limestone; Dolomite 

Chemical Formula: CaCO3 ; CaCO3 ; MgCO3 

CAS Number. 471-34-1 

Trade Name: 

Section 11- Hazardous Ingredients 

Hazardous Materials Identification System 

Health Hazard 0 

Flammabili~ty Hazard 0 

Reactivity Hazard 0 

Persona/ Protection E 

Hazardous Ingredients TLV (Mg/M 1 

Silica, Quartz 

Calcium Carbonate Dust 

.1 (Respirab/e Dust) 

10 (Nuisance Dust) 

Calcium Carbonate may contain crystalline silica at leve/s between 0.01 % 

and 1.5% and varies naturally. 

There are a/so small, but detectab/e amounts, of the following other 

naturally occuning chemica/s that are known to the State of Califomia to 

cause cancer, birth defects or other reproductive harm. This waming is 

provided in the absence of definitive testing to prove that these risks do 

not exist. These amounts are typical quantities and may vary slightly with 

different jobs. 

Chemical Name Typical Amount CAS Number 

Arsenic Less than 1 ppm 7440-38-2 

Lead Less than 1 ppm 7439-92-1 l 3 z 
Section 11l - Physical/Chemical Characteristics 

Appearance and Odor. Fine, White Powder; No Odor 

Boiling Point: N/A Sp ecific Gravity: 2.71 

Vapor Pressure: N/A Evaporation Rate: N/A 

Vapor Density: N/A (Butyl Acetate = ZA 

Solubility in Water.~ Slight Melting Point: 

Section IV - Fire and Explosion Hazard Data 

Flash Point: N/A 

Flammable Limits: N/A 

Fire Extinguishing. Media: N/A 

Special Fire Fight/ng Procedures: None 

unusual Fire and Explosion Hazards: None 

Section V - Reactive Data 

This material is stable. 

Incompatibility: Reacts with strong acids to liberate carbon dioxide. 

This matenal will not polymerize. 

Hazardous Decomposition By-Products: None 

Section VI - Hea/th Hazard Data 

Calcium Carbonate is not on the N. T. P., I.A. R. C., or OSHA lists of 

carcinogens. Cry stalline silica, a trace component of Calcium Carbonate, 

has been listed by IARC as carcinogenic to experimental animals and has 

developed limited evidence for carclnogenicity to humans, however, lARC 

has determined that the carcinogenicity to humans is neither certain or 

proven. 

Prolonged, repeated inhalation of crystalline silica can cause silicosis, a 

noncancerous lung disease. 

Exposure: 

Inhalation: Can be irritating to the respiratory tract. 

Eye Contact: Mild irritation. 

Skin Contact: No effect. 

Ingestion: Minima/ effect. 

First Aid: 

Inhalation: Remove from area of exposure and to fresh air area. 

Eye Contact: Flush eyes with water for 10 minutes. If irritation 

%sists, obtain medical attention. 

Skin Contact: sh from skin with mild soap and water. 

Ingestion: Ingestion should not cause any significant health 

problems. 

133 
Section Vll - Spill_or Leak Procedures 

Spill or Leak: Respiratory protection should be wom during clean 

up to protect from airborne dust. Measures should 

be taken to reduce airborne dust during clean up. 

Waste Disposal: Shovel up material and dispose of in landfill. 

Comp1y wlth applicable federal, state and local 

regulation s. 

Section Vlll - Special Protection 

Respiratory Protection: N10SH/OSHA/MSHA approved dust respirator if 

T.L. V. is exceeded. 

Ventilation: Local exhaust: As required for dust to maintain 

airborne dust below the TLV. 

Mechanical: As required for dust. 

E'ye Protection: Safety g/asses or goggles. 

Special Protection: None required. 

Date Prepared: March 4.1998 Prepared by Safety Department 

/3V 
MATERIAL SAFETY DATA SHEET 

?NDUSTRIAS SULFAMEX, S.A. Distributor - North America 

•ampico, Mexico AGROMEX, INC: 

Mobile, Alabama 

FOR HEALTH HAZARD INFORMATION, CALL: -(205) 443-5665 . 

Date of Revision: •'03/12/90 

assssa :aaasasaasaaassamaaoaaaaaaaa sa=saza=ssassassassasaasaasssasasmaaa ssasa ~ = 

- Product Name: TECMANGAM (R) Soluble Manganese Sulfate 

- Synonym: Manganese Sulfate (81-83.8 ) 

- Formula: Mixture r ~ 

t 

E

a 

SCTION II. PRODUCT AND COMPONENT HA2ARD DATE 

A. COMPONENTS: 

Approx. 

Percent TLV** CAS Reg.No. ~ 

*Manganese Sulfate 83.8 5 mg/m3 (as Mn) : 7785-87-7 

Magnesium Sulfate •2.0 None . ; 7487-88-9 = 

Calcium Sulfate 65 None - 7788-18-9 - 

Water 1.0 None 7732-18-5 

*Principal hazardous component 

**See Section VI-A for additional information on expoeure limits. 

B. PRECAUTIONARY LABEL STATEMENTS: ._ ; , . . . . . .- _ . ' _ , •_.. 

. WARNING! MAY BE HARMFUL IF INHALED j 

CAUSES IRRITATION ;• 

' Avoid breathing dust. 

Avoid contact with eyes. 

Avoid prolonged or repeated contact with skin. ... 

Use with adequate ventilation. w 

Wash',thoroughly .after handling. ~ 

. .. . . .. . . . 

FIRST AID ~,_ In case of contact, immediately flush eyes with 

plenty o£ water for at least 15 minutes. •:_Ca11 •;',a ,physician.;, -Wash ' 

skin with soap and plenty of . : 'water.. - ,Wash ~ clothing before:reuse. 

In case of irritation of eyes, nose, and throat, remove from 

exposure,,treat symptomatically, and call a physician if.symptoms 

persist. r ,: 4 

_ _. .. 

ir1SDS . 001:1 - 

, 

- 03/11/90 

, ~ . . . 

.. ,. 

• _ /35 
•'1 . 

Since emptied packages retain product residue, follow label warnings even after ~ 

package is emptied. 

Notice: Manganese Sulfate may discolor ornamental surfaces, rock, tile, masonry, 

etc. Contact with these surfaces should be avoided. If contact occurs, wash area 

immediately with water. _ 

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 •'. ► . 

SECTION III. PHYSICAL DATA - - -'=• - "="r ~ • y.J . 

- Appearance and Odor: White to cream-colored powder, practically odorless. 

- Boiling Point: Not applicable. 

- Specific gravity (H20 = 1): 0.81 at 20 ° /20`C 

- Vapor Pressure: Not applicable. 

- Percent Volatile by Volume: Not applicable. 

- Vapor Density (Air - 1): Not applicable. 

- Evaporation Rate: Not applicable. 

- Solubility ia Water: Appreciable (approx. 99X). 

=- !lssiisaasaaaisiiisasasssassssisasssasissiassaiizaaasasaaasssas:sssasassisssssliss 

, ' • ' . . . ' . .: . , SECTION IV. FIRE AND EXPLOSION HAZARD DATA 

- Flash Poiat: Not applicable (Noncombustible). 

- Flammable Limits: Not applicable. 

- Extinguishing Agent: Use appropriate agent for surrounding fire. 

- Special Fire-Fighting Procedures: None known to Sulfamex. :-• '= - 

- Unusual Fire and Explosion Hazards: None known to Sulfamex.' ....•'_ .- . ~~_~ 

JSECTION V. REACTIVITY DATA .- ':~ • 

- Stability: Stable. 

- Incompatibility: None known to Sulfamea. 

- Hazardous Decomposition Products: Decomposes to oxides of manganese and sulfur. 

, - Hazardous Polymerizatioa: Will not occur. "- . : . : : -.t' ~ ` ~ `"'. _ : . • 

assasasasssssssasszaassiasaaszasss ~is=msssssssslssassasssssassalslasssssssaslislss! 

. . - - - • . . _ :.': . - ~ 'j . . 

SECTION VI. TOXICITY AND HEALTH 

A. EXPOSURE LIMITS 

. • . . ~ . -.. :`,z:. ~ a"c.:•~ .. 

- OSHA Permissible Eaposure Limit (PEL): . Manganese sulfate (as "lin):.`• -'t6~.~

,

`. 

5 mg/m3-C. - _ . • _ ._ . _ .. - ... > : ._ : T i : ~...:ri: r x . ~~ . 

- Threshold Limit Value (TLV): Manganese Sulfate (as'Mn):' ~ 5mg/M3-C, 

ACGIH, 1982. 

- A NIOSfl industrial hygiene analytical method_for.manga'nese • is'available:, (1) 

- An industrial hygiene analytical method for Manganese Sulfate is available 

r, :+. i . ?.~ .:.3- ~ii~ S :r:. i`a ~'.'i.2 to health aad safety professionals upon request. ... -. .. 

B. EXPOSURE EFFECTS _ 

Inhalation: May be harmful if inhaled. May cause irritation'of the nasal 

passages. 

Eyes: Dust may cause irritation. 

Skin: Prolonged or repeated contact may cause irritation. e 

03/12/90 - 

MSDS: 001:1 

. !3~ 
C. SKIN A1dD 9;Ya rtcvicvllv v 

Safety glasses should be worn in any type of industrial operatioa. Protective 

gloves should be worn. _... 

D. OTHER CONTROL MEASURES 

An eye bath and washing facilities should be available. Wash thoroughly 

after handling. 

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SECTION VIII. SPECIA.L STORAGE AND HANDLING PRECAUTIONS 

Since emptied packages retain product residue, follow label warniags even after 

package is emptied. 

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SECTION IX. SPILL, LEAK, AND DISPOSAL PRACTICES 

Steps to be taken in case material is released or spilled: Collect and contain f:r 

salvage or disposal. 

Waste Disposal Method: Landfill. Observe all federal, state, and local laws 

concerning health and environment. 

assaasaasaasamasasxa=ssassssszaas=smassaa=so=ss=asa==ss:saoass=sssssisaasss:sisosszs 

SECTION X. ENVIRONMENTAL EFFECTS DATA 

A. SUIrMARY: This product has not beea tested for eavironmeatal effects. 

However, some laboratory test data aad published data (7,8) are available for 

all of the major compoaents of this product, and these data have been used to 

provide the followiag estimate of environmeatal impact:" 

This product has a low biological oxygen demand, and it is expected to cause 

little oxygen depletioa in aquatic systems. It is expected to have a low - 

potential to affect aquatic organisms, secondary waste treatment micro— 

organisms, and the germination and growth of some plants. If diluted with a 

large amount of water, this product released directly or indirectly into the 

environment is not expected to have a significant impact. a 

SECTION XI. TRANSPORTATION 

DOT Hazard Classification: Not regulated'-by"DOT 

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SECTION XII. REFERENCES 

1. NIOSH Manual of AnalyticalMethods , 2nd Edition, Volume 2. Issued by the r: 

National Institute for Occupatioa.al Safety and Health. Washiagton, U.S. r ~ 

Government Printing Office, 1971, Method S5. =. 

2. H..C. Hodge and J. H. St4rner, Tabulation of toxicity classes. Am_Ind: ~". 

Hyg. Assoc. Q. 1949; 10:93-96. rMSDS: 001:1 

03/12/90 

' 137 
C: FIRST AID 

Inhalation: Remove from exposure. Treat symptomatically, and get medic'al 

attention if symptoms persist. 

I 

Eyes : Immediately flush with plenty of water for at least 15 minutes and 

get medical attention. ' 

Skin : Immediately wash with soap and plenty of water. Wash contaminated 

clothing before reuse. 

D. ANIMAI. TOXICI,TY DATA 

The compdsition of this product varies from one batch to another; however, 

toxicity data felt to be representative of this variable product are provided 

below: 

Toxicity 

Test Species Result 2) Classification (3) 

Acute oral LDgO Rat 1600-3200 mg/kg Slightly Toxic 

Acute oral LD50 Mouse 800-1600 mg/kg Slightly Toxic 

Dermal LD50 Guinea pig >1000 mg/kg 

Skin irritation Guinea pig Slight 

Eye irritation Rabbit Moderate 

In the 1930's, manganese ore mining and processing operations were studied,.and 

it was determined that chronic overexposure to manganese ore dust produced a 

disease of the nervous system with symptoms similar to Parkinson's diesease: 

' tremor, rigidity of facial expression, stooped posture, and stiffness and slowness of movements. (4) Other reported illnesses include pneumonia and metal fume 

fever. (5) Although these effects in humans have occurred from exposure to 

manganese ore, manganese dioxide, and finely divided manganese, a thorough 

search of the world medical lfterature has disclosed no reports of such effects 

occurrinFrom exposure to manganese sulfate, the form of manganese present in 

Tecmangam-r Eastman Chemical Products, Inc. reported that no neurotoxicity, 

pulmonary disease, nor metal fume fever have been seen in Eastman employees who 

have worked with Tecmangam for many years, although irritation of the nasal 

mucous membrances, skin irritation, and eye irritation have been observed. (6) 

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SECTION.VII. PERSONAL 1'ROTECTION AND CONTROLS 

A. BTSPIRATORY PROTECTION 

An appropriate NIOSH-approved respirator for dust should be worn if needed. 

B. VENTILATION 

General: Recommend at least 10 air changes per hour for good general room 

ventilation. 

Local Exhaust: Recommended to control dust. See Section VI-A for - 

information on exposure limits. Maintain workroom air concentrations below 

irritating levels. 

MSDS 001:1 

03/12/90 

• ~ lJ~~ 
3. R.H. Flinn, cc A~L . 

Public Health Bulletin No. 247 , 1940. 

4. A. Hamilton and H.L. Hardy,Industrial Toxicology . Acton, MA, Publishing 

Sciences Group, Inc., 1914, pp 127-130. 

5. Battele's Columbus Laboratories, Wafer Quality Critical Data Book Volume - 

_3 - Effects of Chemicals on Aquatic Life , Selected data from the literature 

through 1968. Washington, U.S. Environmeatal Protectioa Agency, Project 

No. 18050 GWY, Contract No. 68-01-007, May 1971. 

6. J.E. McKee and H.W. Wolf, Editors.Water Quality Criteria , Publ. No. 3-A 

(Revised). State of California, 1963. 

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The information contained herein is furnished without warranty of any kind. Users 

should consider these data only as a supplement to other information gathered by 

them and must make independ?nt determinations of suitability and completeness of 

information from all sources ,to assure proper use and disposal of these materials 

aad the safety and health of employees and customers. 

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MSDS : "001 : 1 

03/12/90 

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AlriERICAN MICROTRACE 

MSDS 

Product Name:':Maa=Gfo®`Man=Gro'® AS"~ 

Chemical Name: Manganese Sulfate Monohydrate 

Contact American MicroTrace 

569 Central Drive, Suite 201 

Virginla Beach, VA 23454 

Fax Phone No: (804) 463-8156 

Molecular Formula: MnSO4H2O 

Molecular Weight: 169.01 

Phone: (800) 544-3155 

or: (402) 729-6191 

Date Issued 2/27/91 

For Emergency Assistance Involving Chemicals - Call Chemtrec 

(800) 424-9300 

i.s IC IT. 

Component.• Manganese Sulfate Monohydrate CAS NUMBER 

PermLssible Air Concentration: 

Manganese Sulfate Monohydrate 5 mg/m 3Ceiling (ACGIH) (As Mn) Percent.• 90'/0 7785-87-7 

Ferric Oxide - 5 mg/1113 1.5% 1309-37-1 

Aluminum Sulfate 12 mg/m3 1.5% 1344-28-1 

Silica Dioxide 5 mg/m3 1.00/0 7440-21-3 

G First Aid Measures 

Ingestion: If large amounts are ingested, if victim is conscious, immediately give 2 to 4 glasses of water, and induce 

vomiting by touching finger to back of throat Do not give carbonates. - Get rffedica.l attention 

immediately. 

~ rt ••~~; ~ ,c~. 

Eye Contact• If eye irritation exists, flush thoroughly with plain water. 

Skin Contact.• If sldn irritation e•ai.sts, wash with soap and water. 

D. xarards Tnformation J~ 3~ 

""'Health Effects" _ . ... . 

Inhalation: May cause irritation of nasal membtanes and upper respiratory tra 

Ingestion: of large amounts may be harmfiil. Eyes: Contact maySkin: Contact may ccause imtation. -- -+r'` 

Mediccal Conditions Possibly Aggravated: Respiratory problems could be ag,gravated by inhalation of dust 

Unusval Chronic Tox.idty: Some manganese compounds are known to cause acute and chronic toaiary which 

primarily invobes the central nervous system, however, there are no known reports 

of such effects from exposure to manganese sulfate. Chronic exposure to silica dust 

may cause silicosis, a fibero[ic lung disease. 

"Fire and Explosion Data•• 

Flash Point: N/A , 

Fire and Explosion Harard: Negligible fue and explosion hazard in dust form when exposed to heat of tlame 

Flammable Iimit N/A 

Unusual Fire and Explosion Haaards: None 5/15/91 

i1-11e) 
~ precrautions/Procedures 

Fire Extingui.shing Agents Recommended: CDry chemical, carbon dioxide, water spray or foam) as appropriate ~ 

for surrounding materiaL . 

Fire Estingu.ishing Agents to Avoid: None 

Spec3al Fire Fighting Precautions: Use self conta:.-.-~ d breathing appamtus 

Englaeering Controls: Use containment and/or loc-al exhaust ventilation to control dust 

Normal HandlIag: Avoid contact with eyes, sidn, and clothing. Avoid breathing dust. Ma3ntain good 

housekeeping practices. 

Storage: Keep dty 

SpLll or Leak: Collect and contain for salvage or disposal. Vacuum or sweep keeping dust to a minimum. 

Special Precautions/Procedures/Labels Instructions: See "Normal Handling" 

Note label signal words'Warning!' 

Personal Hygiene: Wash thoroughly after handling and before eating or smoking. 

E )Personal Protedive EqWpment 

Respiratory Protec.:on: Use NIOSH-,MSHA approved dust respirator if irritation exists or in dusry areas which --- -- 

ezceed mg/m3.. - 

Eyes and Face: Glasses, goggles, or face shields are recommended if irritation exists. 

Ha.nds, Arms, and Body: Gloves and protective clothing should be used if ircitation exists. 

Other Clothing and EquipmenL• None 

fr. Physical Data 

Descript3on: Light Tan to Pale Gray hlaterial 

Boiling Point• N/A ' 

Solubility in Water: 50a/a by weight 

•:~W• ~ ~..: 

PHs 3.0-5.0 ® 100/o Solution 

Vapor Pressure & Density: N/A _ 

Melting Poinh Decomposes above 450° C. 

Stability: Stable under normal temperatures and pressures. Polymeriration: Will not occur 

Incompatibilities: None 

Decomposition: Thennal decomposition may release toxic fumes of manganese. Possibly o:ades of sulfiu 

I Environmental 

EPA Fiazardous Substance: Yes Federal RQ Quantity: 1000 LB/454 KG 

DOT Hazard Class: N.O.S. Orm E NA 9188 RQ Waste Disposal Method: LandPill or field 

RCRA Status of Unused MaterIaL• Not listed application at agronomic rates 

Refzrences-... _ . 

--.~.., 

PearmLssiblle eoncentratioa references: "'I'LV" -"Threshold Limit Values for Chemicral and Physical --. -_ 

Agents in the Work Environment' 1084-85 GACG" 

Harard Information References: "Merck Index" 10th Edition, 1983. Merck and Company, Inc. 

& AdditionalInformation 

This chemical may be subject to the reporting requ'uements of Section 313 of Tide III of 49 CFR 372 of the Emergeney 

Planning and Communiry Right-To-Know Act 

Tbis matertal safety sbeet is o,(jered solely foryour informatton and investigattort It provldes no 

warranties ettber express or impliecl; and assumes no responsibllity for the accurary or completeness 

of tbe data contained beretn, 5/15/91 

`~t! 
INIATERIAL SAFETY DATA SHEET 

ZINOX 

NPCA - FLNi1S HAZARD RA7Z\G 

Health I 

Flammabiliry p 

Reactivity 0 

Maximum 

Personal Protection E 

-)ECTION I 

MANL'FACTL'RER 

EMERGENCY TELEPHONE 

CHE'v1ICAL NAME 

TRADE NAME 

CHE1IICAL F.aMILY 

FORM U LA 

CAS NUMBER 

AMERICAN CHE:vSET CORPORATION 

P.O. Box 1160 

East Helena, MT 59635 

(406) 227-5302 ATTN: W. H. Porter or Dan Brimhall 

Zinc Oxide 

ZINOX 

Zinc Oxide 

Zn0 

1314-13-2 

SECTION II ELkZARDOUS INGREDIENTS PEL + TLV 

ZI`C OXIDE 17C RESPIR.ABLE DUST 5 mg/m' 

97.090 (Typical) (94.5% Min.) TOTAL DUST 10 mg/m3 

Exposure is governed by the 8 hour TWA established for Zine Oxide. Zinc Oxide is not carcinogenic material as listed by OSHA (29CFRI910) or ACGIH (Appendix 

A. Threshold L imit V_!aes ,`or Che:nical Substances 1984-1985). 

SECTION III PHl'SICAL DATA 

Boiling Point (f): Specific Gravity: Vapor Pressure: Percent Volatile by volume (90): 

NA H;0=1 5.6 NA p% 

Vapor Density: Evaporation Rate: Solubiliry in Water: hielting Point: Appearance and Odor: 

NA NA Less than 1 k. 3590 °F Fine powder. Cream yellow. No odor. 

SECTION IV FIRE & E.XPLOSION HAZARD DATA 

Flash Point Flammable Limits 

LEL UEL 

NA NA NA 

Extinguishing Media: NA 

'+ecial Fre Fahting Procedures: None known 

aal Fre Fi¢htins Procedures: None know'n. 

aECTION V HEALTH HAZARD DAT.s► 

Threshold Limit Value: See Section tI 

Signs, Symptoms, and Effects of Overexposure: Nausea, chills, diarrhea. May cause upper respiratory irritation; skin irritation (oxide pox); fever, eye irritation With 

redness, pain and conjunctivitis; preexisting lung diseases may be aggravated by exposure. Could result in respiratory irritation; preexisting lung diseases ntay be aggra- 

%ated by exposure. Could result in respiratory disease if over exposed on a chronic basis. _ 

Primary Routes of Entry: Inhalation and/or ingestion. 

Emergency and Frst Aid Procedure: Remove to fresh air. Lay patient down. Cover With blanket. If irritated, flush eyes and skin with large volumes of fresh water 

for 15 minutes. Refer to MD. 

SECTION VI REACTIVITY DATA 

Stable X Unstable 

Conditions and Materials to Avoid: Mass build up under reactive conditions such as but not limited to acids. Zinc Oxide may react violently a'ith strong reductaats 

such as orgar.ic compounds, including chlo:inated rt:bber at temperatures over 420°F, (a Flammability rr.action w•ith linseed oii was reported once), and ntetals includirtg 

but not limited to Mg. 

Hazardous Decomposition Products: Above melting point (3590°F) zinc fumes may result. 

Hazardous Polvnurization: Will not occur. 

SEC'rION VII SPILL OR LEAK PROCEDURES 

Steps to be taken in case material is released or spilled. Clean up w'ith vaccum or conventional tools. Avoid dusting. 

Waste Disposal Method: Approved land fill. 

SECTION VIII SPECIAL PROTECTION INFOR:'1TATION 

Respitatory Protection: Cartridge type filter or approved dust mask. Refer to Respiratory Protective devices approved by Bureau of Mines Circular IC 8436. 

Ventilation: To keep below listed TLV in Section 11, use general dilution type ventilation. 

Protective Gloves: Wear if skin contact is probable and skin is sensiave. 

Eye Protection: Safety glasses or goggles. 

Other Protective Equipment: Long sleeve shirts if contact is probable and skin is sensitive. 

SECTION IX SPECIAL PRECAUTIOi\S 

.autions to be taken in handling and storing: Keep lids tightly sealed. Store in cool, dry place. 

ier Precautions: Do not take internally. Avoid prolon¢ed contact w•ith skin. R'ash with soap and water after contact. 

SECTION X SARA TITLE III 

This product contains a zinc compound (Zinc Oxide) and is subject to the reporting requirements of Section 313 of 'I itle III of the Superfund Amendments and Reauthoriration Act o f1986 and 40 CFR Part 372. 

Date: IMarch I, 1989 (Rev. 4) 

~ FY ~' 
1

. . . . . • ~ . 

P.O. Box 1178 

Columbus, GA 31902-1178 

Telephone 3341291-0930 - Facsimile 3341291-3237 

ul u 1' • 1iT 

To: David Ousley, Alabama Department of Environmental Management 

From: Robert Maner, Environmental Managn 

Re: Fluorine Mass Balance 

Date: May 28, 1996 

In our conversation last week, you suggested it might be beneficial to perfotm a fluorine mass balance on a 

dried and fired brick from Boral plants in Phenix City. I learned that a fluorine mass balance had been 

performed while these plants operated as Bickerstaff Clay Products. I have summarized the results below. 

Plant/ Product Main Body 

Constituent 

dried bricJc 

fluorine content 

fired brick 

tluorine content 

fluorine 

evolved 

'/• 

evolved 

emission faaor 

Ob Fff / ton ware 

Atlanta, GA Plant Sbale 606 ppm 280 ppm 326 opm 53.8 0.69 

Bessemer Buff Bod Shale 679 ppm 339 ppm 340 pom . 50.1 0.72 

Bessemer Standard Red Shale 603 ppm 166 ppm 437 ppm 72.5 0.92 

Phenix City Plant I Alluvial Clay 454ppm 84 ppm 370 ppm 81.5 0.78 

Pheaix City Plant 3 Alluvial CI 348 po 56 22m 292 m 

1 

84.9 0.61 

1) A buff body brick desaibes a lighter color brick as a result of lower iron centent in raw materials. The raw material may aLso 

have a higher alumina content and higher matucing tempesariue. 

2) The emission factor is developed using the following formula: 

= fluorine evolved (ppm) x 2000 pb/ton) x 20 Ib HF 

1,000,000 x 19 Ib F 

= 292 paFts gaeFiAe 2000 Ib 20 Ib HF 

1,000,000 ton 19 I~ F 

0.61 lb HF / ton fired ware 

These mass balance results were produced by Clemson University using a pyrohydrolysis test and are 

relatively consistent with mass balance results for other Boral plants. 

The Phenix City Plant 3 stack test that I referenced in the earlier emissions inventory for the Phenix City 

plants was also conducted by Clemson University. An emission factor of 0.45 lb HF / ton of fired ware is 

produced by dividing the average emission rate by the production rate during the test. This is 74% of the 

emission factor produced from mass balance data for the same plant. This is consistent with experience that 

shows actual stack emissions to be approximately 65% of predicted maximum emissions using the mass 

balance technique ("Monitoring for Hydrogen Fluoride Emissions in the Ceramic Manufacturing," Ceramic 

Industry Magazine, 143 (1) p. 38-40 (1994). 

The emission factor derived from the stack test at Plant 3 appears to be the most conservative emission 

factor (produces the lowest estimated emissions) based on the compilation of all data. The potential 

production of each plant coupled with this emission factor produces potential emissions of hydrogen 

fluoride in excess of ten tons per year. Based on this estimate, I will continue to assume that our 

manufacturing sites are Title V major sources. If you have any questions, please call me at 334-480-2487. 

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MACT Information Collection Request Response 

from 

Boral Bricks, Inc. 

Table of Contents 

• Information Collection Request 

• Appendiz A - MSDS's 

J ~~ 
Enclosure 2 

INFORMATION REQUEST FOR BRICK AND 

STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS 

Instroctionc 

Please return the completed information request to: 

Bruce C. Jordan, Director 

Attn: Bill Neuffer 

Emission Standards Division (MD-13) 

U. S. Environmental Protection Agency 

Office of Air Quality Planning and Standards 

Research Triangle Park, North Carolina 27711 

If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at 

(919) 541-5435. 

This information request should be completed for each facility that manufactures brick and 

structural clay products, including facilities that are not major sources. Information is 

requested for all processes at your plant that emit hazardous air pollutants (HAP's), 

including those processes that are not associated with brick and structural clay 

products manufacturing. Sections II through VII request information specific to brick 

and structural clay products manufacturing, and Section VIII requests information on 

emissions of HAP's from other processes located at the facility. Processes that may emit 

HAP's include those processes that use or handle any materials that contain a HAP 

compound, all processes with elevated temperatures, and all other processes in which HAP 

compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is 

included as Attachment 1 to this information request. Attachment 2 provides background 

information on the requirements of the Clean Air Act and explains how the information 

requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations 

and acronyms used in this information request. 

Several tables are provided throughout the information request for your convenience in 

answering the questions. An example response is given (shaded first column or row) in each 

table. If additional space is needed to respond, please make copies of applicable pages. If 

necessary, please make copies of this inforniation request for additional facilities. No 

additional emission testing or monitoring is required to respond to this request. 

II. General Facility Information 

A. Name of company Bora:, .' ~ qks, Inc. 

Nanie of facility Phen~_ City. Plant 4 

Page 1 of 31 

iLA, 
Facility address: 

No. and street 100 Brickyard Road, Plant 4 

City Phenix City StateAlabamaZip36865 

Latitude and longitude coordinates of plant: Lat (N) 32° 23' 46", Long (W) 85 000'29" 

Standard Industrial Classification (SIC) Code(s) of brick and structural clay products 

manufacturing operations 3251 

Dun and Bradstreet No. 00-327-5682 

Total No. of employees for company> 1,500 for facility101 

(If facility is a foreign subsidiary or if company has foreign subsidiaries, include 

number of employees not based in the U.S.). 

Please complete the following shift information for the facility: 

Shift No. of employees Hours per shift Days per year 

1 89 

1 

8- 12 

8 

359 

365 

2 5 

3 

8 —12 

8 

359 

365 

3 3 8 365 

B. Respondent name Andrew Wichers 

Respondent titleRe,gional SafM Manager 

Respondent address (if different from above) and telephone number: 

No. and street100 Brickyard Road 

CityPhenix Ci ,t~ StateAL Zip36865 

Telephone No.(334) 480-2407 

Name and telephone number of technical contact person (if different from above) 

NameDavid JohnsonPhone No.(334) 480-2487 

Page 2 of 31 

/`/7 
III. Information on Onerating Permits and Applicable Federal Emission Standards 

A. Please provide copies of relevant parts of all operating permits and permit 

applications for your facility. Relevant parts include the sections that provide specific 

information and data on: processes that emit HAP's; the use of HAP- containing 

substances; emission levels for HAP and surrogate pollutants (i.e., VOC for organic 

HAP's and PM for metal and other particulate HAP's); emission control device 

design and operation; monitoring and operation and maintenance (O&M) procedures 

for control devices; and generation and releases of other media such as wastewater 

and solid waste that are associated with the operation of air pollution controls for 

brick and structural clay products manufacturing processes. 

If the operating permit or application contains the same information requested 

in any part of this questionnaire, you may respond to the requested information 

by referencing the page or section of the permit/application to avoid 

duplication. If you reference your permit or application, you must supplement your 

response with all of the additional information requested in this questionnaire that is 

not included in the permit or permit application. If you prefer, you may submit the 

requested information from your permit/application on a 3-1/2 inch diskette. 

B. If any source or emission unit at this facility is subject to a New Source Performance 

Standard or other Federal emission standard, please identify the source a.nd applicable 

standard. Examples of applicable NSPS include 40 CFR 60, Subpart 000 - 

Standards of Performance for Nonmetallic Mineral Processing Plants, and 

40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers in 

Mineral lndustries. 

No NSPS applicability determination has been made for this facility at this time 

IV. Brick and Structural Cla,y Products Production and Raw Material Consumption 

Information 

A. Please provide the 1996 production rates and the current production capacity for 

each type of brick and structural clay product manufactured (e.g., structural brick, 

clay sewer pipes, structural clay tile, etc.). Note that production data should be 

provided in units of tons per year (tons/yr). 

Product 1996 prodt, ~ : -:on (tons) Production capacity (tons/yr) 

Bricks (Fired Weight) 199,464 228,601 

Page 3 of 31 

/ C/P 
B. Please provide the type and amount of each raw material and body additive used in 

1996 for manufacturing brick and structural clay products at your facility. Examples 

include clays, shale, and any additives that are mixed into the raw material prior to 

forming. Indicate additives by chemical compound, rather than by trade name. If the 

information requested is contained in your facilit}rs operating permit, you may 

reference the applicable sections of the permit rather than providing the information 

below. 

Raw niateriaUbody additive Amount used in 1996 (tons/yr) 

Lignosol (wet weight) 260 

Manganese Sulphate (dry weight) 0.15 

Manganese 325 Mesh (dry weight) 2.58 

MRC Grog 48 Mesh (dry weight) 10.80 

Ochre 548 Dark (dry weight) 25.03 

Redart Clay (dry weight) 23.13 

Hallmark Fire Clay (wet weight) 3,750 

Mary Lee Grace Chapel Clay (wet weight) 1,000 

Rome Shale (wet weight) 27,200 

Clay (local mines) (wet weight) 197,000 

C. If available, please provide a copy of the MSDS's for the raw materials and additives 

listed above. 

See Appendia A 

D. If available, please provide chemical analyses, including fluorine, metals, and organic 

content, of the raw materials listed above. 

Not Available 

Page 4 of 31 

ld~ 
E. Using Table 1, please provide information on the consumption and HA.P composition 

of all glazes and colorants that contain HAP's or HAP precursors and that your facility 

applies to brick and structural clay products. Indicate whether the coatings are glazes 

or colorants. Also indicate the type of product that the coatings are applied to and the 

total weight of coatings used in 1996. If the glazes or colorants are formulated at your 

facility indicate so and provide the production capacity. List each ingredient of the 

glaze or colorant. Beside each ingredient, indicate the total amount of the ingredient 

used in 1996. If the informa.tion requested in the table is contained in your facility's 

operating permit or permit application, you may reference the applicable sections of 

the permit (or application) rather than filling out the table. 

F. In the space below, please indicate any glazes or colorants used by your facility that 

do not contain HAP's and are substitutes for HAP-containing glazes or colorants 

used by your industry. Indicate which HAP-containing materials the non-HAP glazes 

or colorants replace. Describe any limitations on the use of those substitute glazes or 

colorants. 

None 

G. If your facility colors brick and structural clay products by flashing, please indicate 

the types of substances used to flash the products and the amounts of those 

substances used in 1996. 

Substance Amount used in 1996 Units (specify) 

Natural Gas Unknown — Not Measured Not Applicable 

Propane (back-up fuel) Unknown — Not Measured Not Applicable 

H. If available, please provide a copy of the MSDS's for the glazes and colorants used by 

your facility. If your facility prepares its own glaze, please provide any available 

MSDS's for the glaze ingredients. 

See Appendix A 

Page 5 of 31 

/S-Z) 
TABLE 1. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND COr.nuaNTR 

I Type (e.g., glaze, colorant) EXAMPLE: Colorant/Coatings 

Glaze - 

I

Type of product glazed or 

colored 

Stractural tile Brick 

1,982 1996 consumption (tons/yr) 

I Produced at facility? (yes/no) 

I Production capacity (tons/yr) 

Total usage (weight) of each 

ingredient (that is a HAP, 

contains a HAP, or is a HAP 

precursor) in 1996 

1,140 

r": 

_., ' 

.. _ - -: -_ -- . _ 

Totat 1996 

Ingredient : `: ` us~ge, toas: 

, • -_- ._..._ . _ _ . Cr203 _.. 0.?.3 

Coa 0.18 

_ . MQo, _ 

- _.. .-_ ----- - -- _ ;:=_. _::_ _ . :., ~ - .: ~; ------------_- - ,. - ,. - - --- -- 

No 

Not Applicable 

Total 1996 

Ingredient usage, tons 

Iron Chromite 1.75 

Limestone 34.73 

Manganese 0.15 

Sulphate 

Manganese 325 2.58 

Ochre 548 25.03 

Zinc Oxide 4.55 

If additional space is required, please make copies of this page. If the information requested in 

the table is contained in your facility's operating permit or permit application, you may reference 

the applicable sections of the permit (or application) rather than filling out the table. 

Page 6 of 31 

1 ~-f 
V. Description of Brick and Structural Clay Product Manufacturing Processes 

A. Please provide a simple process flow diagram for each brick and structural clay 

product manufacturing process line. An example process flow diagram is provided in 

Figure 1. A diagram of the plant layout with all processes and emission points clearly 

labeled is also acceptable. 

Assign a unique identification number (ID No.) for each process that has 

associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. 

Please identify all emission points, including those that do not emit HAP's. For 

emission points that are vented to an air pollution control device (APCD), assign an 

ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are 

uncontrolled, assign an ID No. to the uncontrofled stack (e.g., S-1) or building roof 

vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information 

request for any responses that pertain to any process or emission point. 

Page 7 of 31 

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B. Using Tables 2A and 2B, please provide current production rates, production 

capacities, and related information for each type of equipment used in brick and 

structural clay product manufacturing. In Table 2A, provide the requested 

information for only those sources that are known or expected to emit HAP's. In 

Table 213, provide the requested information for all thermal processing, such as drying 

and firing sources. For combustion sources that use di$'erent fuels, Table 2B should 

be completed for each type of fuel. For example, if a kiln typically is fired with gas, 

but periodically is fired with oil, one column in Table 2B should be completed for the 

kiln when fired with gas, and another column should be completed for the same kiln 

when fired with oil. Provide the data in the units listed for each row. 

Page 10 of 31 

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C. Using Table 3, please provide information on procedures used to monitor the 

process operating rate for each of the pieces of equipnzent and HAP emission 

sources listed in Tables 2A and 2B. Use the same HAP emission source types and 

equipment ID numbers you listed in Tables 2A to 2B. 

Indicate whether you monitor process rate or not. 

Provide a summary of process rate monitoring procedures that 

descn'bes how process rate is measured for the particular piece of 

equipment. Include where the rate is monitored (i.e., rate of material fed, 

rate of material discharged, or niaterial production rate), the units used to 

measure process rate (e.g., lb/hr or pieceslhr), and how the process data is 

recorded, i.e., manually, automatically (e.g., conYputer - printout or stored 

to disk, or not at all). If you monitor process rate at both the feed and 

discharge ends of the equipment, indicate so. 

Indicate the type of monitor, equipment, or instrument used to measure 

process operating rate. 

• Indicate the monitoring frequency or how often process rate 

measurements are made. 

• If instruments are used to measure process throughput, indicate in the 

monitor accuracy cohunn the accuracy of the instrument. The monitor 

accuracy could be listed in terms of a percentage of the throughput 

(t 1 percent), mass per unit time (t2lb(hr), number of pieces per unit time 

(f 10 pieces/hr), or other appropriate units. 

• Indicate the frequency that the monitor is cahbrated. 

• Provide data in the units listed for each row. 

Page 14 of 31 

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VI. Identification of Brick and Structural Clay Product Manufacturing Emission Points 

A. Use the process flow diagrams developed for your facility and Table 4 to provide 

the foflowing information for each HAP emission source at your facility. 

• Define HAP emission souree type in terms of equipment, such as dryers, 

kilns, etc. As in the process flow diagram, you may group multiple pieces of 

similar equipment. 

• Use the same equipment ID numbers indicated on the process flow diagram(s). 

• If the emission source vents inside a building or to outside ambient air without 

first passing through a control device, place a check mark in the uncontrolled 

column. 

• If the emission source vents inside a building or to outside ambient air after 

passing through a fabric filter, dry injection fabric filter, or scrubber, place the 

APCD ID number(s) in the column corresponding to the APCD type. 

• If the emission source vents through a control device type not listed in Table 4, 

indicate the control device type in the other control column and place the 

APCD ID number in the appropriate cefl. 

• In the emission test data column, place a"yes" or "no" in the appropriate cell 

to indicate whether the specific source has been tested for any pollutants, 

including any HAP's, VOC, PM, or opacity. 

Page 16 of 31 

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B. Using Table 5, please provide information on stack parameters and emission 

estimates for each emission point at your facility that is known or expected to emit 

HAP's. Provide information for all APCD's, including those that exhaust inside the 

building. Include data for each inlet and outlet, if available, as indicated in the table. 

If you have more than one inlet to an APCD, provide data for each of the inlets. 

Provide data in the units listed for each row. 

Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal 

HAP's or VOC for organic HAP's. Emission estimates may consist of 

measurements reported in emission test reports or may be calculated using mass 

balances, emission fa.ctors, engineering judgement, or other estimation methods. 

Provide the emission estimates as emission factors in units of lb of poflutant emitted 

per ton of product (lb/ton). Provide complete copies of any emission test reports 

or other reports that document measurements of emissions. Test reports and 

other emission measurement documents should include the following information: 

process identification; location of sampling point; stack diameter, temperature, and 

flow rate; test method, including analytical procedures; number of test runs; 

emission concentration, emission rate, percent oxygen, and percent moisture for 

each test nm; process operating rate; type of APCD; and APCD operating 

parameters. However, test reports with incomplete documentation may still be 

useful and should also be submitted. 

You do not need to fill out Table 5 for emission points that are covered by an 

emission test report that is included in your submittal. If emission test reports are 

not available, provide calculations that support your emission estimate, 

including the basis for all assumptions in the estimate. Note that emission 

estiniates are needed for all HAP's that the facility emits or has the potential to emit. 

(Please refer to the HAP list in Attachment 1.) If the information requested in the 

table is contained in your facility's operating permit, you may reference the 

applicable sections of the permit rather than filling out the table. 

Page 18 of 31 

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C. Using Tables 6A through 61), please provide design and operating data for each APCD 

associated with all dryers, kilns, and any other brick and structural clay products 

manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of 

APCD's. Use Table 6D for other types of APCD's. When using Table 6D, please 

specify the type of control device and 2 to 4 key design or operating parameters for the 

device. Provide data in the units listed for each row. If the information requested in 

Tables 6A through 6D is contained in your facility's operating permit, you niay reference 

the applicable sections of the permit rather than filling out the tables. 

Page 23 of 31 

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D. Using Table 7, please provide the following information on current nionitoring 

procedures for each of the control devices listed in Tables 6A to 61): parameters 

monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices 

used (e.g., differential pressure transducer, thermocouple), and recordkeeping 

practices (e.g., manually recorded in log book, continuously recorded by electronic data 

acquisition system). Describe briefly other operation and maintenance (O&M) 

procedures for each control device. If the information requested in the table is contained 

in your facility's operating permit, you may reference the applicable sections of the 

permit rather than filling out the table. 

VII. Pollution Prevention Practices for Brick and Structural Clay Products Manufacturing 

A. Please describe all pollution prevention practices (i.e., process modifications, such as reuse of discarded or rejected materials, or any practice that prevents or reduces the 

amount of air emissions, or the generation and release of solid waste or wastewater 

associated with the operation of air pollution controls). If the information requested 

here is contained in your facility's operating permit, you may reference the applicable 

sections of the pernzit rather than providing the information below. 

This facility: 1) reuses waste heat from the kiln to heat the dryers (and to a lesser 

degree, the holdin r g ooms), 2 recycles floor sweepings and scrap/waste clay back into 

the brick body: 3) recycles green brick back into the brick body; and 4) recycles off-sQec 

brick grog) back into the brick body. 

Page 28 of 31 

173 
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VIII. Information on Processes Other Than Brick and Structural Clay Products 

Manufacturing Processes 

A. Using Table 8, please identify all other processes or operations at this facility that are 

not addressed in Itenms II through VII above and that are potential sources of HAP 

emissions. Estimate total annual emissions of each HAP emitted by these collocated 

processes. If the information requested in the table is contained in your facility's 

operating permit, you may reference the applicable sections of the permit rather than 

filling out the table. 

Page 30 of 31 

125, 
TABLE 8. ESTIMATED ANNUAL HAP EIvIISSIONS FROM OTHER SOURCES 

Process/emission source/SIC Code(s) HAP's emitted Estiniated annual emissions , 

tons 

e me#a~ _ _: .-.:...._ v= .. 

~ 

Not Applicable 

SIC 

ISIC 

ISIC 

SIC 

If the infonnation requested in the table is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the table. 

Page 31 of 31 

1710 
Material Safety Data Sheet 

Substance Identification 

Identity: IRON CHROMITE CAS #: L308-38-9 

Trade Names: CHROMOX 

Manufacturer: 'Ibe Prince Manufacturing Company Emergency: Chemtrec 

One Prince Plaza 1-800-424-9300 

Quincy, IL 62301 

217-222-8854 

Components and Contaminants 

Chemical Name CAS # OSHA PEL ACGIH TLV Percent 

Chromium Cr+' 7440-47-3 0.5 mg/m3 0.5 mg/m3(TWA) 30-45% Cr 

Silica, Crystalline Quartz respirable dust 14808-60-7 0.1 mg/m3 0.1 mg/m3(TWA) 1.2% Si02 

Physical Data 

Boiliag Point: NA Specific Gravity (H=0=1): 4.4 

Vapor Pressure (mm/Hg): NA Melting Point: 3350 - 4000° F 

Vapor Density (Air =1): NA Evaporation Rate (Butyl Acetate =1): NA 

Solubility in Water. insoluble 

Appearance and Odor: black powder, no odor. !~ 

Fire and Explosion Hazard Data 

F7ash Point: Not combustible 

Flammable Limits: LEL NA UEL NA 

Extinguishing Media: ` Foam, COZ, or dry chemical or water. 

Specia.l F'ire )~ighting Procedures: In the event of fire, wear full protective clothing and NIOSH-approved selfcontained breathing apparatus with full face piece operated in the pressure 

demand or other positive pressure mode. 

Unusual F'ire and explosion hazards: Not combustible. 

Reactivity Data 

Stability: Stable under ordinary conditions of use and storage. 

Conditions to avoid: None Known ' 

Incompatibility (materials to avoid): None Known. 

Hazardous Decomposition or Byproducts: None Known. 

Hazardous Polymerizatioa Will not occur. 

Health Hazard Data 

Route of Entry: INHALATION: May cause delayed respiratory disease : if dust is inhaled over a 

prolonged period of ttme. 

S KIN: No. 

INGESTION: Ingestion of Iron Chromite may cause abdominal pain and 

nausea. 

...._ . 

Iron Chromite, Page 1 

A^=l 1991 

/7 ~ 
Health Hazard Data (ront.) 

Health Hazards (Acute and Chronic): Respiratory disease may result from prolonged overexposure. Can cause eye 

irritation. 

Carcinogenicity: NTP: No IARC Monographs: Yes (Silica) 

Signs and Symptoms of Exposure: Excessive inhalation of dust may result in shortness of breath and reduced pulmonary function. Symptoms of silicosis include impaired pulmonary function 

and wheezing. 

Aggravation of Pre-existing Conditions: Persons with impaired respiratory function may be more susceptible to the effect of this substance. 

Emergency and F'irst Aid Procedures: IF INHALED, remove to fresh air and seek medical attention for any breathing 

difficulty. 

IN CA.SEOF SKIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. 

IN CASE OF EYE CONTACT, flush eyes immP~ iately with water for at least 

15 minutes. Seek medical attendon if irritation persists. 

IF INGESTED, induce vomiting immediately by giving two glasses of water 

and sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. 

Precautions for Safe Handling and Use 

Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratory 

protection. Recover uncontaminated material for use. Vacuum or sweep 

remaining material, keeping dust to a minimum. 

Waste Disposal Method: Dispose of unreclaimable material in a RCRA=approved waste faci7ity. 

Handling and Storing Precautions: Protect containers from damage and keep closed when not in use. 

Other Precautions: Observe good personal hygiene. Wash after handfing. 

Control Measures 

Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or is 

anticipated. OSHA standard 1910.134 or ANSI Z,88.2-1980 specifications are 

recommended. 

Venti'Iation: A system of local and / or general exhaust is recommended to keep employee 

exposures below the Airborne Exposure Limits. Local exhaust is generally 

preferred because it can control the emissions of the contaminant at its source, 

preventing dispersion of it into the general work aiea. Please refer to the 

ACGIH document, "Industrial Ventilation, A Manual of Recommended Prac- 

~ tices', most recent edition, for detaiLs. 

Protedive Gloves: Yes 

Eye Protection: Safety goggles are recommended. 

Other Protedive Clothing or Equipment: Use other protective equipment when necessary in order to avoid prolonged 

exposure to skin. 

Work and Hygienic Practices: Observe good personal hygiene. Wash after handling. 

-- - SARA Title III Section 313 Supplier Notification 

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency 

Planning and Community Right-to Know Act of 1986 and of 40 CFR 372.45: 

Compgnent CAS # % by Weight 

Iron Chromite 1308-38-9 30 - 35% Cr 

This information must be included in all MSDS's that are copied and distributed for this material. — 

Iron Ctiomite, Page 2 

April 1991 

/ ?,P 
tiSalerlal Safety Data Sheet 

Mlay tH used lo comply wilh 

OSIIA's tivard Communlcalbn SlttnOard, 

29 CFH 19 10. 1 Slandard musi till 

con3ulled lor speci(!c rrrqulrementa. 

U.S. Depariment of Labor 

Occupotlonal Safety and Health Adminittrtatlon 

(Non-Mandatory Form) 

Form Approv•d 

OM8 No. 1718-0077 

IOEHTTT7 (Ai Uad a^ L" and UsiJ hbro: At&',t spxsi r+n nor pamvrriPd r any rr•m 4 no( acpMcao+a. or 

M 5481 Ochre h/arrn.00n b a vrLr,.b.r, an• sp•cQ mus t b• mark•d to ndici•rr o 

Sestlon 1 

Mu,ulactufw'1 Nam• Em•(q• 

~_hern Color ac Chemical ~+U ~ ! 

AdCr a s.f (NurnDar. S'trr t, Ca'y. 57 a m an0 I1P C.od•) T• I• w~o~ • N ~,r~~c~. ~r a t,on 

P.O. Box 15 0 7 t404 ) j8b- ~+~ 

Oata Prtpurrd , 

7 Swisher Drive may 21 1986 

SiQnalur• or Prrrpu•r (optianaQ . 

Cartersville, Georgia 30120 1 ~ . /~" 

Sectlon II -- Haiardoua Ingredlents/ldenllty Informatlon 

01h•r Limits 

Huudous Component• (Sp•cihc Ct14rnlco! Id•ntHy,Common Nam•(s)) OSHA PEL ACOIH TLV Rocommand•d 4 (oo 

M548 Ochre (Fe7O-4-XH20)Natural Iron Oxider Non Established; lOmg/L None 

Note: Ochre is • listed as liazardous because of t -he nuisance dust 

that may be created in handling t e pro uct. 

CASN 1343- 8 1- 3 

t l . 

Sectlon III — Phyalcal/Chemlca) Characteristics 

8alinq PaM Sp•ciAC Oraviry (H =O . I) 

N/A 3.2-3.E 

Vapor Prrtssur• (mm Hq.) M•Illny Poirr 

N/A ' N/A 

Vapor Ortnsity (A A • 1) Evaporatlon Rala 

N A (eutyl Ae.tat. . 1) N/A 

9oluoitity n Watu 

Insoluble 

App•uanc• and Odar 

Yellow Powder - No Odor 

Secllon IV — Fire and Exploalon Hazard Data 

Flasln Poani (MaIhod Us•d) N/A Flammablra Umits LEL UEL 

N/A I N/A 

Erunquisttinq 6A•dia 

N/A 

Sp•cial Fwrt Fi9hunQ Procedur•t 

None Required • 

UnutuaJ Fita tlnd Expbsion Hu1ro• 

None 

(R•ptoduc• locally) OSHA 111, $•pl. 1i. 

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NMON:{ 3N014 U"nurt++~d 

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• tf~x+Dn,ditB io vop!sodwoor0 rno0,rrrH 

3NON (P/oAy ol rlrurlr Y) ll1llqtltdwo2ul 

urtoux auoN Pfo^V ol ruoft!PUOO I I rlcmsun I N-"tS 

sl*a ~IIMtOtod — A uoilDoS 

m 
ividtertal Jafety uata ,,)neet 

May be used to comply with 

OSHA's Hazard Communication Standard, 

29 CFR 1910.1200. Staridard must be 

consulted for specific requirements. D 

IDENTITY (As Used on Label and List) 

I RON MANGANESE OXIDE BLACK #320/318 

U.S. Department of Labor /~_` 

Occupational Safety and Health Administrat i on ``';j„ 

(Non-Mandatory Form) 

Form Approved 

OM8 No. 1218-0072 CAS# 1 1 11 5-41 -4 

Noto: Blank spaces are not permifted. d any item is not app/icab/e, or no 

inlormation is available,the space must be marked to indica 'ethat. 

Section 1 CHEMICAL FORMULA - Fe2 0 3 Mn2 0 3 

Manufacturer's Name Emergency Telephone Number 

404 386-4766 

Address (Number, Street• City, State, and Z/P ~Code) 

Drive 

Telephone Number for Information 

7 Swisher (404) 386-4766 

Cartersville, GA 30120 Date Prepared 

September 21, 1987 

Signature of Preparer (optiona/) 

Section 11 — Hazardous Ingredients/ldentity Information 

Other Limits 

Hazardous Components (Specific Chemical Identity; Comrnon Name(s)) OSHA PEL ACGIH TLV Recommended %(optional) 

HAZARDOUS INGREDIENTS - NO ADDITIONAL INGREDIENTS 

IRON OXIDE FUMES as Fe 5mg/m' 

RESPIRABLE DUST 5mg/tn3 

MANGANESE COMPOUNDS 5taq/m3 

(CEILING, AS Mn) 

Section 111 — Physical/Chemical Characteristics 

Boifing Point SpecifiC Gravity (H20 - 1) 

N/A 4.8-5 

Vapor Pressure (mm Hg.) Meftiny Poirtt 

Vapor Density (A1R - 1) Evaporation Rate 

(BuM Acetete - 1) 

Saubility in water 

INSOLUBLE 

Appearance end Odor 

BLACK POWDER - ODORLESS 

Section IV — Fire and Explosion Hazerd Data 

Flash Point (Method LEL' I UEL 

N/A N/A I N/A I N/A 

Extinguishirg Media 

WATER DRY CHEMICAL • 

Special Fre FighUng Procedures 

Nl)NF 

Unusual Fre and Ezplosion Hazarda 

. NONE 

(Reproduce localty) HAZARDOUS MATERIALS IDENTIFICATION SYSTEMS (HMIS) OSHA 174, Sept. 1985 

HEALTH 0 FI.A?QtABILITY 0 REACTIVITY 0 

~~~ 
, D 

;ection V — Reactivity Data 

tability I Unstable I I Conditions to Avoid 

I IXI 

icompatibility (Mateiials 10 Avoid) 

NONE KNOWN 

azardous Oecomposition or Byproducts • 

ection VI — Health Hazard Data 

oute(s) of Entry: Inhalation?YES Skin? NO Ingestion? YES 

ealth Hazards (Acute and Chnonic) 

fANGANESE IS C EMICALLY R_F.ATED AS P RT OF THIS ST BLE PIGMFNT CRYSTAL OVER EXPOSURE TO 

'4 MANGANESE IN AN UNREACTED FORM MAY RESULT IN CHRONIC MANGANESE POISONING(MANGANISM) T HE 

;ENTRAL NERVOUS SYSTEM IS THE CHIEF SITE OF EFFECT. TO DATE THESE TYPES OF EFFECTS HAVE NOT 

arcinogenicity: NTP? NO WRC Monographs? NO OSHA Regulated? NO 

EEN ASSOCIATED WITH THIS PRODUCT. 

gns and Symptoms of Exposure 

XCESSIVE EXPOSIIRE TO AIRRORNE DU4T WILL RESUL.T IN EFFECT SIMILAR TO T1iAT OF NUISANCE TYPE 

UST THAT IS PARTICULATE MAY REDUCE VISIBILITY AND/OR CAUSE UNPLEASANT DEPOSITS IN THE EYE S, 

edical Conditions EAR~S __AND NOSE . INJURY TO THE SKIN OR MUCOUS MEMBRANES CAN OCCUR BY DIRECT :neralty Aggravate~6y t"pvsure ~y.nVAfyT/~ AT AnTTAL7 AD 4V DT/`/1DAiTQ QVT~I* l~~AN TAir TE'('G'CCADV Or+ cmv:aa svem srorrv: ~ oce as cesvtrssvw-vcr 

DUST. 

nergency and Frst Aid Procedures 

gTU CONTACT _liAqH WTTu SppP ANn rJpTPg EYE CONTACT — FLUSH WITH LARGE AMOUNTS OF WATER • 

ONSULT PHYSICIAN. INHALATION — REMOVE FROM DUSTY AREA. 

ection VII — Precautlons for Safe Hano11ng and Use 

3ps to Be Taken in Case Material Is Released or Spilled 

ANDLE AS NORMAL SOLID WASTE, SCOOP UP BY SOME MEANS AND PLACE IN A WASTE CONTAINER. 

aste Oisposal Method 

ASTE MATERIAL CAN BE BURIED IN A APPROVED LANDFILL OR HANDLED AS INERT WASTE IN ACCORDANCE 

ITH FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. 

-cautions to Be Taken in HandGng and Storing 

TORE DRY AT AMBIENT TEMPERATURE AWAY FROM FOOD AND DRINK. 

her Precautiorts 

NONE _. 

-iction VIII — Control Measums 

spiratory Protection (Speclfy Type) 

IO_SH_ APPROVED FOR DUSTS, MISTS AND _FUt-tES. _DO NOT EXCEED USE LIMITS OF THE RESPIRATOR. 

ntitation 

X 

Mechanical ChL 7 

nective Gloves Eye Protection 

IBBER, CLOTH OR PLASTIC GLOVES SAFETY GLASSES 

)er Protective Ctothing or Equipment 

N/A 

;rWHygienic Practices 

) NOT STORE NEAR FOOD AND DRINK. WASH EXPOSED SKIN FOR HYGIENE PURPOSES. 

Pop Z • U.DO.tO.: toe!-491-52 9/45 7 73 

l f2-- 
MATER/AL SAFETY DATA SHEET 

Section I - Product Identification 

The Georgia Marble Com pany' 

1201 Roberts Boulevard, Buildin g 100 

Kennesaw, Georgia 30144-3619 

Emergency Telephone: (770) 421-6508 

Prepared by: Trevor G. Lamond, Technical Director 

Trade Name: 

Ground limestone/ Calcium carbonate 

Production Locations: Marble Hill, Ga, Sylacauga, AI 

Chemical Identity: Product consists of ground limestone (CAS Number: 

1317-65-3), which is a natural peoduct composed of Calcium Carbonate 

(CAS Number 471-34-1) and from 1-3% Magnesium Carbonate (CAS 

Number 546-93-0) together with various other natural ingredients at trace 

levels. 

Section II - Hazardous Inaredients 

Hazardous Materials Identification System 

Health Hazard 0 

Flammability Hazard 0 

Reactivity Hazard 0 

Personaf Protection E 

Hazardous In,aredients TLV (mg/m' ) 

Silica, Quartz 

Calcium Carbonate Dust 

.1 (Respirable Dust) 

10 (Nuisance Dust) 

This product typically contains less than 0.3% crystalline silica. : 

In addition, there are also small but detectable amounts of the following 

other naturally occurring chemicals that are known to the State of 

California to cause cancer, birth defects or other reproductive harm. This 

warning is provided in the absence of definitive testing to prove that these 

risks do not exist. These amounts are typical quantities and may vary 

slightly with different lots. 

l8~~ 
Chemical Name 

Arsenic 

Lead 

Typical Amount 

Less than 1 ppm 

Less than 1 ppm 

CAS Number 

7440-38-2 

7439-92-1 

Section III - Physical/Chemical Characteristics 

Appearance and Odor: Fine, White Powder; No Odor 

Boiling Point: N/A Specific Gravity: 2.71 

Vapor Pressure: N/A Evaporation Rate: N/A 

Vapor DensIter: N/A (Butyl Acetate = 1) 

Solubility in Slight Melting Point: N/A 

Section IV - Fire and Explosion Hazard Data 

Flash Point: N/A 

Flammable Limits: N/A 

Fire Extinguishing Media: N/A 

Special Fire Fighting Procedures: None 

Unusual Fire and Explosion Hazards: None 

Section V - Reactive Data 

This material is stable. 

Incompatibility: May react with acids to liberate carbon dioxide. 

This material will not polymerize. 

Hazardous Decomposition By-Products: None 

Section-Vl - Health Hazard Data 

Calcium Carbonate, the main component of limestones and marbles, is 

not on the NTP, IARC, or OSHA lists of carcinogens and there are no 

health effects associated with prolonged exposure to pure calcium 

carbonate. Crystalline silica (sand), a trace component of many limestone 

and marble powders, in its respirable form has been listed by IARC as a 

Type 1 carcinogen and the NTP has stated that crystalline silica is 

reasonably anticipated to be a carcinogen. Also, prolonged exposure to 

crystalline silica has been found to cause silicosis, a noncancerous lung 

disease. 

Exposure: 

Inhalation: Can be irritating to the respiratory tract. 

R

e Contact: Mild irritation. 

in Contact: No effect. 

Ingestion: Minimal effect. 

First Aid: 

i lw 
Inhalation: Remove from area of exposure and to fresh air area. 

Eye Contact: Flush eyes with water for 10 minutes. If irritation 

persists, obtain medical attention. 

Skin Contact: Wash from skin with mild soap and water. 

Ingestion: Ingestion should not cause any significant health 

problems. 

Section VII - Spill or Leak Procedures 

Spill or Leak: Respiratory protection should be worn during clean 

up to protect from airborne dust. Measures should 

be taken to reduce airborne dust during clean up. 

Waste Disposal: Shovel up material and dispose of in landfill. 

Comply with applicable federal, state and local 

regulations. 

Section VIII - Special Protection 

Respiratory Protection: NIOSH/OSHA/MSHA approved dust respirator if 

T.L.V. is exceeded. 

Ventilation: Local exhaust: As required for dust to maintain 

airborne dust below the TLV. 

Mechanical: As required for dust. 

Eye Protection: Safety glasses or goggles. 

Special Protection: None required. 

Date Prepared: March 3. 1998 

~~~/ 
C georgia marble company 

nK MNOVATaa 1201 rober[s boulevard, building 100 • kennesaw, georgia 30144-3619 

" STONE °A00LLn fax:770 421-6507 [ ) (770)421-6500 

1VIATERIAL SAFETYDATA SHEET 

Section I - Product Identification 

The Georgia Marble Company 

1201 Roberts Boulevard, Buildin g 100 

Kennesaw, Georgia 30144-3619 

Emergency Telephone: (770) 421-6557 

Kenneth J. Meeks, Safety and Training Manager 

Risk Management 

Chemical Name: Calcium Carbonate 

Chemical Family: Marble; Limestone; Dolomite 

Chemical Formula: CaCO3 ; CaCO3 ; MgCO3 

CAS Number. 471-34-1 

Trarla A/amzSection Il - Hazardous Ingredients 

Hazardous Materials ldentification System 

Health Hazard 0 

Flammability Hazard 0 

Reactivity Hazard 0 

Persona/ Protection E 

Hazardous /ngredients TLV (My/M ) 

Silica, Quartz 

Calcium Canbonate Dust 

.1 (Respirab/e Dust) 

10 (Nursance Dust) 

Calcium Carbonate may contain crystalline silica at levels between 0.01 % 

and 1.5% and varies naturally. 

There are a/so sma11, but detectab/e amounts, of the followin g othernaturally occurring chemica/s that are known to the State of Califomia to 

cause cancer, birth defects or other reproductive harm. This waming is 

provided in the absence of definitive testing to prove that these risks do 

not exist. These amounts are typical quantities and may vary slightly with 

different jobs. 

Chemical Name Taical Amount CAS Number 

Arsenic Less than 1 ppm 7440-38-2 

Lead Less than lppm 7439-92-1 ~~ 
Section Ill - Physical/Chemical Characteristics 

Appearance and Odor. Fine, White Powder; No Odor 

Boiling Point: N/A S ecifc Gravity: 2.71 

Vapor Pressure: N/A EPaporation Rate: N/A 

Vapor Density:~ N/A (Butyl Acetate = 1) 

Solubility in Water. Slight Meltmg Point: N/A 

Section !V -Fire and Explosion Hazard Data 

Flash Point: N/A 

Flammable Limits: N/A 

Fire Extinguishing Media: N/A 

Special Fire Fighting Procedures: None 

lJnusual Fire and Explosion Hazards: None 

Section V - Reactive Data 

This material is stable. 

Incompatibility: Reacts with strong acids to liberate canbon dioxide. 

This material will not polymerize. 

Hazardous Decomposition By-Products: None 

Section V! -Health Hazard Data 

Calcium Carbonate is not on the N. T. P., I.A. R. C., or OSHA lists of 

carcinogens. Crystalline silica, a trace component of Calcium Carbonate, 

has been listed by IARC as carcinogenic to experimental animals and has 

developed limited evidence for carcrnogenicity to humans, however, /ARC 

has determined that the carcinogenicity to humans is neither certain or 

proven. 

Prolonged, repeated inhalation of crystalline silica can cause silicosis, a 

noncancerous lung disease. 

Exposure: 

Inhalation: Can be irritating to the respiratory tract. 

Eye Contact: Mild irritation. 

Skin Contact: No effect. 

Ingestion: Minimal effect. 

First Aid: 

Inha/ation: Remove from area of exposure and to fresh air area. 

Eye Contact: Flush eyes with water for 10 minutes. If irritation 

Mrssihstfsr'

obtain medical attention. 

Skin Contact: om skin with mild soap and water. 

Ingestion: Ingestion should not cause any significant health 

problems. 

%CX2 
Section Vil - Spill or Leak Procedures 

Spill or Leak: Respiratory protection should be worn during clean 

up to protect from airborne dust. Measures should 

be taken to reduce airborne dust during clean up. 

Waste Disposal: Shovel up material and disp ose of in landfill. 

Comp1y with applicable federal, state and local 

regulation s. 

Section Vlll - Special Protection 

Respiratory Protection: NIOSH/OSHA/MSHA approved dust respirator if 

T. L. V. is exceeded. 

Ventilation: Local exhaust: As required for dust to maintain 

airborne dust below the TLV. 

Mechanical: As required for dust. 

Eye Protection: Safety glasses or goggles. 

Special Protection: None required. 

Date Prepared: March 4.1998 Prepared by Safety Department 

/ft 
MATERIAL SAFETY DATA SHEET 

TNDUSTRIAS SULFAMEX, S.A. Distributor - North America 

ampico, Mexico AGROMEX, INC: 

Mobile, Alabama 

FOR HEALTH HAZARD INFORMATION, CALL: -(205) 443-5665. 

Date of Revision: ••03/12/90 

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- Product Name: TECMANGAM (R) Soluble Manqanese Sulfate 

- Synonym: Manqanese Sulfate (81-83.8 ) 

- Formula: Mixture 

a s a s x a=¢ s s s a a a a a a a a c a= a a a e= 3 

SECTION II. PRODUCT AND COMPONENT HAZARD DATE 

A. COMPONENTS: 

Approx. 

Percent TLV** CAS Req.No.. ~ 

*Manqanese Sulfate . 83.8 5 mq/m3 (as Mn) 7785-87-7 

Maqnesium Sulfate .2.0 None ; 7487-88-9 

Calcium Sulfate .5 None - 7788-18-9 

Water 1.0 None 

---------------------- - ---------------------- --- 

7732-18-5 

-- ---- 

*Principal hazardous component 

**See Section VI-A for additional information on exposure limits. 

PRECAUTIONARY LABEL STATEMENTS: 

WARNING! MAY BE HARMFUL IF INHALED 

CAUSES IRRITATION 

Avoid breathing dust. . ~ • . 

Avoid contact with eyes. 

Avoid prolonqed or repeated contact with skin. - Use with adequate ventilation. _ Wash•,thorouqhly .after handlinq. 

. .. . . .. . . 

FIRST AID:..: In case of contact,.immediately flush eyes with 

plenty 61water for at least 15 minutes. ,;: Call .:',a ,physician., : _Wash 

skin with soap and plenty of .: water. ,Wash ~ clothinq before:reuse. 

In case of irritation of eyes, nose, and "throat, remove from 

exposure,.treat symptomatically, and call a physician if.symptoms 

persist. 

. . _ _... MSDS 001:1 . 

'03/lt/90 

. ,;. . . ~ . .. . 

,. 

- ,.. 

• . !~f' 

B.
Since emptied packages retain product residue, follow label warnings even after 

package is.emptied. 

Notice: Manganese Sulfate may discolor ornamental surfaces, rock, tile, masonry, 

etc. Contact with these surfaces should be avoided. If contact occurs, wash area 

immediately with water. 

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SECTION III . PHYSICAL DATA - = • - ,' :±~?., - 

- Appearance and Odor: White to cream-colored powder, practically odorless. ~ 

- Boiling Point: Not applicable. 

- Specific gravity (H20 = 1): 0.87 at 20`/20`C 

- Vapor Pressure: Not applicable. 

- Percent Volatile by Volume: Not applicable. 

- Vapor Density (Air - 1): Not applicable. 

- Evaporation Rate: Not applicable. 

- Solubility in Water: Appreciable (approx. 99X). 

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' • • • •. 

SECTION IV. FIRE AND EXPLOSION HAZARD DATA 

- Flash Point: Not applicable (Noncombustible). 

- Flammable Limits: Not applicable. 

- Extinguishing Agent: Use appropriate agent for surrounding fire. 

- Special Fire-Fighting Procedures: None known to Sulfamex. ==-• ~ : -' 

- Unusual Fire and Explosion Hazards: None known to Sulfamex.'. 

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- . J . • 

SECTION V. REACTIVITY DATA 

- Stability: Stable. 

- Incompatibility: None known to Sulfamez. 

- Hazardous Decomposition Products: Decomposes to oxides of manganese and sulfur. 

, - Hazardous Polymerization: Will not occur. - 

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. 

- - - 

. . ' . . ~ - ..': . j . • 

SECTION VI. TOXICITY AND HEALTH 

A. EXPOSURE LIMITS 

it:. J C.^ J 

- OSHA Permissible Exposure Limit (PEL):. Manganese sulfate (asIa): 

5 mg/m3-C. 

- Threshold Limit Value (TLV): Manganese Sulfate (as'Mn):--=5mg/K3-6, ~ = 

ACGIH, 1982. ;::.._.... ;;r.~~ 

- A NIOSH industrial hygiene analytical method_for manganeseis'available: .(1) 

- An industrial hygiene analytical method for Manganese Sulfate is available 

to health and safety professionals upon request. ' 7 ~~ ' = ~i~= ~ '''• 1 •Y z 

= 

B. EXPOSURE EFFECTS 

Inhalation : May be harmful if inhaled. May cause irritation of the nasal 

passages. 

Eyes : Dust may cause irritation. 

Skin:Prolonged or repeated contact may cause irritation. 

03/12/90 • 

MSDS: 001:1 

r 

... . IC10- 
C. SKIN AND EYa rnUlc.t.,.lva 

Safety'glasses should be worn in any type of industrial operation. Protective 

gloves should be worn. _.-.. 

D. OTHER CONTROL MEASURES 

An eye bath and washing facilities should be available. Wash thoroughly 

after handling. 

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SECTION VIII. SPECIAL STORAGE AND HANDLING PRECAUTIONS 

Since emptied packages retain product residue, follow label warnings even after 

package is emptied. 

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SECTION IX. SPILL, LEAK, AND DISPOSAL PRACTICES 

Steps to be takea in case material is released or spilled : Collect and contain f:r 

salvage or disposal. 

Waste Disposal Method : Landfill. Observe all federal, state, and local laws 

concerning health and environment. 

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SECTION X. ENVIRONMENTAL EFFECTS DATA 

A. SUP4iARY: This product has not been tested for environmental effects. 

However, some laboratory test data and published data (7,8) are available for 

all of the major.components of tFiis product, and these data have been used to 

provide the following estimate of environmental impact: 

This product has a low biological oxygen demand, and it is expected to cause 

little oxygen depletion in aquatic systems. It is expected to have a low - 

potential to affect aquatic organisms, secondary waste treatment microorganisms, and the germination and growth of some plants. If diluted with a 

large amount of water, this product released directly or indirectly into the 

environment is not expected to have a significant impact. 

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SECTION %I. TRANSPORTATION - - - - 

DOT Hazard Classification: Not regulated".by-DaT 

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SECTION BII. REFERENCES , 

1. NIOSH Manual of AnalyticalMethods , 2nd Edition, Volume 2. Issued by the: 

National Institute for Occupational Safety and Health. Washington, U.S. ;~;~ 

Government Printing Office, 1977, Method S5. 

2. H..C. Hodge and J. H. St4rner, Tabulation of toxicity classes. Am_. Ind: Y

" 

Hyg. Assoc. Q. 1949; 10:93-96. ~ - 

MSDS: 001:1 

03/12/90 

' /~~ 
C: FIRST AID 

Inhalation: Remove from exposure. Treat symptomatically, and get medieal 

attention if symptoms persist. 

I 

Eyes : Immediately flush with plenty of water for at least 15 minutes aad 

get medical attention. ' 

Skia : Immediately wash with soap and plenty of water. Wash contaminated 

clothing before reuse. 

D. ANIMAL TOXICITY DATA 

The composition of this product varies f rom oae batch to another; however, 

toxicity data felt to be representative of this variable product are provided 

below: 

Toxicity 

Teat Species Result (2) Clasaification (3) 

Acute oral LD50 Rat 1600-3200 mg/kg Slightly Toxic 

Acute oral LD50 Mouse 800-1600 mg/kg Slightly Toxic 

Dermal LD50 Guinea pig >1000 mg/kg 

Skin irritation Guinea pig Slight 

Eye irritation Rabbit Moderate 

In the 1930's, manganese ore mining and processing operatioas were studied,.and 

it was determined that chronic overexposure to manganese ore dust produced a 

disease of the nervous system with symptoms similar to Parkinson's diesease: 

' tremor, rigidity of facial expression, stooped posture, and stiffaess and slowness of movements. (4) Other reported illnesses include pneumonia and metal fume 

f ever. (5) Although these effects in humans have occurred from exposure to 

manganese ore, manganese dioxide, and finely divided manganese, a thorough 

search of the world medical lfterature has disclosed no reports of such effects 

occurring,-from exposure to manganese sulf ate, the form of manganese present in 

Tec Eastman Chemical Products, Inc. reported that no neurotoxicity, 

pulmonary disease, nor metal fume fever have been seen in Eastman employees who 

have worked with Tecmangam for many years, although irritation of the nasal 

mucous membrances, skin irritation, and eye irritatioa have been observed. (6) 

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SECTION.VII. PERSONAL rROTECTION AND CONTROLS 

A. R.ESPIRATORY PROTECTION 

An appropriate NIOSH-approved respirator for dust should be worn if needed. 

B. VENTILATION ' 

General: Recommend at least 10 air changes per hour for good general room 

ventilation. 

Local Exhaust: Recommended to control dust. See Section VI-A for 

information on exposure limits. Maintain workroom air conceatrations below 

irritating levels. 

MSDS 001:1 

03/12/90 

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. 
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~ 

C. 

Public Health Bulletin No. 247 , 1940. 

.4. A. Hamiltoa aad H.L. Hardy,Industrial Toxicology . Acton, MA, Publishing 

Sciences Group, Inc., 1974, pp 127-130. 

5. Battele's Columbus Laboratories, Wafer Quality Critical Data Book Volume - 

3- Effects of Chemicals on Aquatic Life , Selected data from the literature 

through 1968. Washingtoa, U.S. Eavironmental Protection Agency, Project 

No. 18050 GWV, Contract No. 68 -01 -007, May 1971. 

6. J.E. 14cKee and H.W. uolf, Editors. Water Quality Criteria , Publ. No. 3-A 

(Revised). State of California, 1963. 

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The information coatained herein is furnished without warranty of any kind. Users 

should consider these data only as a supplemeat to other information gathered by 

them and must make independent determinations of suitability and completeness of 

information from all sources .to assure proper use and disposal of these materials 

and the safety and health of employees and customers. 

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.-__ ~ _ .- ...__.-. _:•. ~~ .:a= ~ xc• ~ :..-= z.a ~ _.:_s aa. ~ . _ • ~ ' - . .. . . 

[' 

J 

1~ - ~ I -~ .. •.:• 1 :..9 

- ♦ 
~7 

AMERICAN MICROTRACE 

MSDS. 

~ Generallnformation 

Product Na.me:':14ian=Gro®, 1 'LM2h=Gro'®'t1S"' ~ Molecular Formula: MnSO41-12O 

Chemical Name: hianganese Sulfate Monohydrate Molecular WeighL• 169.01 

ContacL• Ametican tifiaoTrace Phone: (800) 544-3155 

569 Central Drive, Suite 201 or: (402) 729-6191 

Virginia Beach, \/A 23454 Date Lssued: 2/27/91 

Fax Phone No: (804) 463-8156 

For Emergency Assistance Involving Chemicals - Ca11 Chemtrec 

(800) 424-9300 

s. ~ ~. s~• ~ "~ 

ComponenG Manganese Sulfate Monohydrate CAS NUMBER 

Permissible Air Concentration: 

Manganese Sulfate Monohydrate 5 mg/m3Ceiling (ACGII-i) (~As Mn) Percent: 90% 7785-87-7 

FerYic Oxide - 5 mg/m3 1.5% 1309-37-1 

Aluminum Sulfate 12 mg/m3 1.50/o 1344-28-1 

Silica Dioxide 5 mg/m3 1.00/0 7440-21-3 

G First Aid Measures 

Ingestion: If large amounts are ingested, if victim is conscious, immediately give 2 to 4 glasses of water, and induce 

vomiting by touching finger to back of throat. Do not give carl,)onates. Get iffedical attention 

immediately. ~ ~ l • f\ ``~ ~~ ~ 

Eye Contact If eye irritation eaists, flush thoroughly with plain water. V'Kn 17 

Skin ContacL• If skin irritation eaists, wash with soap and water. 

D. Harards Information JA ~,' 3 ~ 19~ ' 

'THealth Effects" H~ ` 

Inhalallon: May cause irritation of nasal membtanes and upper respiratory tra ' ~~ ~ w 

Ingestion: of large amounts may be harmful. Eyes: Contact may~~atatio 

Sk9n: Contact may crause irritation. -- +r "" 

Mediral Conditions Possibly Aggravated: Respiratory problems could be aggravated by inhalation of dust 

Unusual Chronic Toa.idty: Some manganese compounds are known to cause acvte and chronic toxiciry which 

primarily involves the central nervous system, however, there are no known reports 

of such effects from eaposure to manganese sulfate. Chronic exposure to silica dust 

may cause silicosis, a fiberotic lung disease. 

"Fire and Eaplosion Data•• 

Flash Point: N/A , 

Fire and Exxplosion Harard: Negligible fire and explosion hazard in dust form when exposed to heat of flame 

Flammable I3mit N/A 

Unusual Fire and Explosion Hazards: None 5/15/91 

~~~ 
E. 

F4re Extinguishing Agents Recommended: (Dry chemical, crarbon dioxide, water spray or foarn) as appropriate 

for surrounding materiaL 

Fire Estingu.ishing Agents to Avoid: None 

Spedal Fire Fighting Precautions: Use self contained breathing apparatus 

Engineering Controls: Use containment and/or local exhaust ventilation to control dust 

Nor-mal Handling: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Maintain good 

. housekeeping practices. 

Storage: Keep dry 

Spill or I,eak: Collect and contain for salvage or disposal. Vacvum or sweep keeping dust to a minimum. 

Spedal Precautions/Procedures/Iabels Instruct3ons: See "Normal Handling" 

Note label signal words •Waming!' 

Personal Hygieae: Wash thoroughly after handling and before eating or smoking. 

w 

fTf.1~Li~-~'~ /_ /! ~'~. .~l~ l'• / // • 

Respiratory Protection: Use NIOSH ,MSHA approved dust res_pirator if irritation exists or in dusty areas which --- -J - 

e:rceed mg/m3. ~ ~ 

Eyes and Face: Glasses, goggles, or face shields are recommended if irrftation exists. 

Ha.nds, Arms, and Body: Gloves and protective clothfng should be used if ircitation exists. 

Other Clothing and Equipment: None 

~ Physical Data 

Description: L;ght Tan to Pale Gray hlaterial 

Boiling Point: N/A ' 

Solubility in Water: 50% by weight 

: ' ~ Y • ~ ~.~ 

PIL- 3.0-5.0 ® 109'o Solution 

Yapor Pressure & Density: N/A _ 

Melting Poi;nt Decomposes above 450° C. 

Stabllity: Stable under normal temperatures and pressures. Polymeriration: WIll not occur 

Inco mpati'biliti es: Iv'one 

Decomposition: Thermal decomposition may release toxic fumes of manganese. Possibly ozides of sulfur. 

I Environmental 

EPA Harardous Substance: Yes Feder'al RQ Quantity: 1000 LB/454 KG 

DOT Ha7ard Cla.ss: N.O.S. Orm E NA 9188 RQ Waste Disposal Method: Landfill or field 

RCRA Status of Unused MateriaL• Not listed applicration at agronomic rates 

J. 

Permi.ssible concentradoa references: "TI.V' -"Threshold Limit Values for Cheniical and Physical -- -. - 

Agents in the Work Environment' 1084-85 (ACGIIA 

Harard Information References: "Merck Index" lOth Edition, 1983. Merck and Company, Inc. 

& Additionallnformation 

This chemical may be subject to the reporting requirements of Section 313 of Title III of 49 CFR 372 of the Emergency 

Planning and Community Right-To-Know Act 

Thts rnatertal safety sbeet is o,,(fered solelyforyour infornratton and tnvestigation. It provfdes no 

warranties eitber express or impiteci; and assumes no respottsibility for the accurary or completeness 

of tbe data corrtatned berein. 5/15/91 

l ~.~ 
SECTION I 

MANUFACTURER 

EMERGENCY TELEPHONE 

CHEMICAL NAME 

TRADE NAME 

CHE1vIIC4L F.Ah4ILY 

FORMULA 

C4S NU?v1BER 

NPCA - FLMIS HAZARD RATL\G 

Health I 

MATERIAL SAFETY DATA SHEET Flat"tnability o 

Reactivity 0 

ZINOX Maximum 

Personal Protection E 

AMERICAN CHE'vIET CORPORATION 

P.O. Box 1160 

East Helena, MT 59635 

(406) 227-5302 ATTN: W. H. Porter or Dan Brimhall 

Zinc Oxide 

ZINOX 

Zinc Oxide 

Zn0 

1314-13-2 

SECTION II fiXZARDOUS INGREDIE.\TS PEL + TLV 

ZINC OXIDE c RESPIRABLE DUST 5 mg/m3 

97.0 ro(Tj•pical) (94.5% Min.) TOTAL DUST 10 mg/m' 

Exposure is _rnerned by the 8 hour TI~A established for Zinc Oxide. Zinc Oxide is not carcinogenic material as listed by OSHA (29CFR1910) or ACGIH (Appendiz 

A. Threshold Limit u_!ues ,°or Chemical Substances 1984-1985). 

SECTION III PHI'SICAL DATA 

Boiling Point (f): Specific Gravity: Vapor Pressure: Percent Volatile by volume (90): 

NA H:0=1 5.6 NA Oq 

Vapor Density: Evaporation Rate: Solubiliry in Water: Melting Point: Appearance and Odor: 

NA NA Less than 1%. 3590`F Fine powder. Cream yellow No odor. 

SECTION IV FIRE & EXPLOSION HAZARD DATA ~ 

Flash Point Flammable Limits 

LEL UEL 

NA NA NA 

Extinguishing Media: NA 

ecial Fre Fghting Procedures: None known. 

ual Fre Fahtin¢ Procedures: None knoun. 

SECTION V HEaLTH HAZARD DATA 

Threshold Limit Value: See Section II 

Signs, Symptoms, and Effecu of Overexposure: Nausea, chills, diarrhea. May cause upper respiratory irritation; skin irritation (oxide pox); fever, eye irritation v%ith 

redness, pain and conjunctivitis; preexisdng lung diseases may be aggra%ated by exposure. Could result in respiratory irritation; preexisting lung diseases may be aggravated by exposure. Could result in respiratory disease if over ezposed on a chronic basis. _ 

Primary Routes of Entry: Inhalation and/or ingestion. 

Emergency and Frst Aid Prcredure: Remave to fresh air. Lay patient down. Cover with blanket. If irritated, }]ush eyes and skin with large volumes of fresh water 

for 15 minutes. Refer to !v[D. 

SECTION VI REACTIVITY DATA 

Stable X Unstable 

Conditions and Materials to Avoid: Mass build up under reactive conditions such as but not limited to acids. Zinc Oxide may react violently with strong reductartts 

such as organic cempounds, i.^.cluding chlorinated ruaber at temperatures over 4'0°F, (a Flammabiliry rcaccion u•ith linseed oii %ac reported once), and metals including 

but not limited to Mg. 

Hazardous Decomposition Pr+oduar: Above melting point (3590°F) zinc fumes may result. 

Hazardous Polymerization: Will not occur. 

SECTION VII SPILL OR LEAK PROCEDL'RES 

Steps to be taken in case material is released or spilled. Clean up with vaccum or conventional tools. Avoid dusting. 

Waste Disposal Method: Approved land fill. 

SECTION VIII SPECIAL PROTECTION L1'FORIVIATIOIV 

Respiratory Protection: Canridge type filter or approved dust mask. Refer to Respiratory Protective devices approved by Bureau of Mines Circutar IC 8436. 

Ventilation: To keep below listed TLV in Section II, ase general dilution type ventilation. 

Proteaive Gloves: Wear if skin contact is probable and skin is sensitive. . 

Eye Protection: Safety glasses or goggles. 

Other Protective Equipment: Long sleeve shirts if contact is probable and skin is sensitive. 

SECTION IX SPECIAL PRECAUTIOTS 

=autions to be taken in handling and storing: Keep lids tishtly sealed. Store in cool, dry place. 

.her Precautions: Do not take internallv. Avoid prolonaed contact with skin. A'ash with soap and Water after contact. 

SECTION X SARA TITLE III 

This product contains a zinc compound (Zinc Oxide) and is subject to the reporting requirements of Section 3 L3 of Title lI1 of the Superfund Amendments and Reautho-ization Act of 1986 and 40 CFR Part M. 

Date: tifarch 1, 1989 (Rev. 4) ~ 

ll~ 
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, 

.~ ,._~ ~.,: . ~- _ , . _ -- ~ ~ 

-.._~ -a- -~•.ti:-., : ~~—' . 

9 

EPA MACT Information Collection 

Request Response 

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~ 
MACT Information Collection Request Response 

from 

Boral Bricks, Inc. 

Table of Contents 

• Information Collection Request 

• Appendiz A - MSDS's 

/ 9y 
Enclosure 2 

INFORMATION REQUEST FOR BRICK AND 

STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS 

Instructions 

Please return the completed informa.tion request to: 

Bruce C. Jordan, Director 

Attn: Bill Neuffer 

Emission Standards Division (MD-13) 

U. S. Environmental Protection Agency 

Office of'Air Quality Planning and Standards 

Research _i"angle Park, North Carolina 27711 

If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at 

(919) 541-5435. 

Thi.s information request should be completed for each facility that manufactures brick and 

structural clay products, including facilities that are not major sources. Information is 

requested for all processes at your plant that emit hazardous air pollutants (HAP's), 

including those processes that are not associated with brick and structural clay 

products manufacturing. Sections II through VII request information specific to brick 

and structural clay products manufacturing, and Section VIII requests information on 

emissions of HAP's from other processes located at the facility. Processes that may emit 

HAP's include those processes that use or handle any ma.terials that contain a HAP 

compound, all processes with elevated temperatures, and all other processes in which HAP 

compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is 

included as Attachment 1 to this information request. Attachment 2 provides background 

information on the requirements of the Clean Air Act and explains how the information 

requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations 

and acronyms used in this information request. 

Several tables are provided throughout the information request for your convenience in 

answering the questions. An example response is given (shaded first column or row) in each 

table. If additional space is needed to respond, please make copies of applicable pages. If 

necessary, please make copies of this informa.tion request for additional facilities. No 

additional emission testing or monitoring is required to respond to this request. 

II.General Facility Information 

A. Name of company Bora1 Bricks Inc. 

Name of facility Muskog_ee Plant 

Page 1 of 28 

~~S 
Enclosure 2 

Facility address: 

No. and street 3101 West 53`dStreet South 

City Muskogee State Oklahoma Zip74401 

Latitude and longitude coordinates of plant: Lat 35°40'53" N, Long 95°24'35" W 

Standard Industrial Classification (SIC) Code(s) of brick and structural clay products 

manufacturing operations 3 

Dun and Bradstreet No. 00-327-5682 

Total No. of employees for company >1,500 for facility 4 

(If facility is a foreign subsidiary or if company has foreign subsidiaries, include 

number of employees not based in the U.S.). 

Please complete the following shift information for the facility: 

Shift No. of employees Hours per shift Days per year 

1 41 (Admin, Maintenance, 8-12 360 

Manufacturing, Mining) 

1 Kiln Fireman g 365 

2 —3 amtenance persomel 8 360 

1 Kiln Fireman 8 365 

3 1 Kiln Fireman 8 365 

B. Respondent name Andrew S.R. Wichers 

Respondent title Regional Safety Manager 

Respondent address (if different from above) and telephone number: 

No. and street P.O. Box 1178 

City Columbus State GA Zip 3 1 902-1 1 78 

Telephone No. (334) 480-2407 

Name and telephone number of technical contact person (if different from above) 

Name David Johnson Telephone No. (334) 480-2487 

Page 2 of 28 

~~ 
Enclosure 2 

III. Information on Operating Permits and Apnlicable Federal Emission Standards 

A. Please provide copies of relevant parts of all operating permits and permit applications for 

your facility. Relevant parts include the sections that provide specific information and data 

on: processes that emit HAP's; the use of HAP- containing substances; emission levels for 

HAP and surrogate pollutants (i.e., VOC for organic HAP's and PM for metal and other 

particulate HAP's); emission control device design and operation; monitoring and operation 

and maintenance (O&M) procedures for control devices; and generation and releases of other 

media such as wastewafer and solid waste that are associated with the operation of air 

pollution controls for brick and structural clay products manufacturing processes. 

If the operating permit or application contains the same information requested in any 

part of this questionnaire, you may respond to the requested information by referencing 

the page or section of the permit/application to avoid duplication. If you reference your 

permit or application, you must supplement your response with all of the additional 

information requested in this questionnaire that is not included in the permit or permit 

application. If you prefer, you may submit the requested information from your 

permit/application on a 3-1/2 inch diskette. 

B. If any source or emission unit at this facility is subject to a New Source Performance 

Standard or other Federal emission standard, please identify the source and applicable 

standard. Examples of applicable NSPS include 40 CFR 60, Subpart 000 - 

Standards of Performance for Nonmetallic Mineral Processing Plants, and 

40 CFR 60, Subpart UUU - Standards of Performance for Calciners and Dryers in 

Mineral Industries. 

Based on the Title V Permit application, the followina sources are subject to NSPS: All belt 

conveyors 40 CFR 60 Subpart 00060.670-676 Standards of Performance for non-metallic 

mineral Qrocessing plant• Refrigerators and Air conditioners 40 CFR 82 Subpart F 82.150- 

82.166 Recycling_& Emissions Reduction. 

IV. Brick and Structural Ck Products Production and Raw Material Consumntion 

Informa.tion 

A. Please provide the 1996 production rates and the current production capacity for 

each type of brick and structural clay product manufactured (e.g., structural brick, 

clay sewer pipes, structural clay tile, etc.). Note that production data should be 

provided in units of tons per year (tons/yr). 

Product 1996 production (tons) Production capacity (tons/yr) 

Brick (fired weight) 127,743 138,621 

Page 3 of 28 

020 tl 
Enclosure 2 

B. Please provide the type and amount of each raw material and body additive used in 1996 for 

manufacturing brick and structural clay products at your facility. Examples include clays, 

shale, and any additives that are mixed into the raw material prior to forming. Indicate 

additives by chemical compound, rather than by trade name. If the information requested is 

contained in your facility's operating permit, you may reference the applicable sections of the 

permit rather than providing the information below. 

Raw materiaUbody additive Amount used in 1996 (tons/yr) 

Barium Carbonate (dry weight) 33.85 

P+K Fire Clay (wet weight) 18,393 

Blue Shale Clay (wet weight) 78,007 

Yellow Shale Clay (wet weight) 49,736 

Porter Fire Clay (wet weight) 13,343 

C. If available, please provide a copy of the MSDS's for the raw materials and additives listed 

above. See Appendiz A 

D. If available, please provide chemical analyses, including fluorine, metals, and organic content, 

of the raw materials listed above. 

Not Available 

Page 4 of 28 

,--)dZ 
Enclosure 2 

E. Using Table 1, please provide information on the consumption and HAP 

composition of all glazes and colorants that contain HAP's or HAP precursors a.nd 

that your facility applies to brick and structural clay products. Indicate whether the 

coatings are glazes or colorants. Also indicate the type of product that the coatings 

are applied to and the total weight of coatings used in 1996. If the glazes or 

colorants are formulated at your facility indicate so and provide the production 

capacity. List each ingredient of the glaze or colorant. Beside each ingredient, 

indicate the total amount of the ingredient used in 1996. If the information requested 

in the table is contained in your facility's operating permit or permit application, you 

niay reference the applicable sections of the permit (or application) rather than filling 

out the table. 

F. In the space below, please indicate any glazes or colorants used by your facility that 

do not contain HAP's and are substitutes for HAP-containing glazes or colorants 

used by your industry. Indicate which HAP-containing materials the non-HAP glazes 

or colorants replace. Describe a.ny limitations on the use of those substitute glazes or 

colorants. 

NONE 

G. If your facility colors brick and structural clay products by flashing, please indicate 

the types of substances used to flash the products and the amounts of those 

substances used in 1996. 

Substance Amount used in 1996 Units (specify) 

Natural Gas Unknown Not Applicable 

H. If available, please provide a copy of the MSDS's for the glazes and colorants used by 

your facility. If your facility prepares its own glaze, please provide any available 

MSDS's for the glaze ingredients. See Appendiz A 

Page 5 of 28 

a1~3 
Enclosure 2 

TABLE 1. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND 

COLORANTS 

Type (e.g., glaze, colorant) EXAMPM Coatings/Colorants 

Glaze . 

Type of product glazed or Stractural tile Brick 

colored 

1996 consumption (tons/yr) 1,140` 349 

Produced at facili ~ t3' (Y es/no ) 

;. 

Yes No 

Production capacity (tons/yr) 

, 

N/A 

Total usage (weight) of each Totat 1996- Tota11996 

ingredient (that is a HAP, :.; In gredzent " usage,;.tens=' Ingredient usage, tons 

contains a HAP, or is a HAP ;- 

P recursor in 1996 ) = _ _ 

6s1l' cl~~`:: = : . ..... 

-: -; 

63~= _ Manganese 8.78 

:: Cr~o~ a.2~ :: Soda Ash 30.93 

vEl~ `:: > ; ; . = ... ... .. '' ' ' _13~ f~ ;;°- ;- _;-. S Yn thetic Red 0.25 

...... ....... ..... .: 

.. .. - Iron xi e 

Nt~~ - >' :' - ... . ' ` O.00r :;';: .. 

If additional space is required, please make copies of this page. If the information requested in 

the table is contained in your facility's operating permit or permit application, you ma.y reference 

the applicable sections of the permit (or application) rather than filling out the table. 

Page 6 of 28 

';2 C</"," 
Enclosure 2 

V. Description of Brick and Structural Clay Product Mqnufacturipg P,Locesses 

A. Please provide a siniple process flow diagrarn for each brick and structural clay 

product manufacturing process line, An example process $ow diagram is provided in 

Figure 1. A diagram of the plant layout with all processes atxi emission points clearly 

labeled is also acceptable. 

Assign a unique identification numbex (ID No.) for each proeess that has 

associated emissions (e.g., TK-1 for tugnel kiln no. l) asd each emiasion point. 

Please identify ~11 eruission points, including those that do not emit HAP's. For 

emission points that are vented to an air polllrtion control device (APCD), assign an 

ID No. to the APCI] (e.g., BH-1 for baghouse no. 1). For emission points that are 

uncontrolled, assign an ID No. to the uneorrtrolled stack (e.g., S-1) or building roof 

vent (e.g., RV-1). Use these same ID Plos. throaghout the rest of the infarmation 

request for any responses that pertain to uny process or emission point. 

Page 7 of 28 

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Enclosure 2 

B. Using Tabiea 2A and 2B, please provide cwtrent production rates, production capacities, 

and related information for each type of equipment used in brick and struetural elay product 

manu.facturing. Tn Table 2A, provide the requested 'mforcmation for only those sources t.hat are 

known or expected to emit HAP's. In Table ?B, provide the requested informa.tion for all thermal 

processing, such as drying and firing sources. For combustion sour+ces that use different fuels, 

Table 2B should be completed for each type of fuel. For example, if a kfln typically is fuvd with 

gas, but periodicatly is fired with oil, one eolumn in Tabte 2B should be completed for the kilts 

when fired wi#h gas, an,d another cokgrxi shoukt be completed for the same kiln when fred with 

oil. Prsovide the data in tln~ writs listed for each row. 

Pap 9 of 28 

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The following notes are used in Tables 2A and 2B: 

NOTE 1 

Except as otherwise indicated, Boral Bricks does not possess process-specific data that would 

allow estimates to be made of the types or quantities of HAPs contained in the materials or of the 

resulting HAP emissions. Sections 10.5, 11.3 and 11.19.1 of AP-42 provide generally available 

information on the pollutants that may be emitted from sawdust dryers, clay products processes 

and sand a.nd gravel processes respectively. The AP-42 data are considered indicative of the types 

of HAPs that MU be emitted from processes at this plant but are not considered indicative of the 

quantities of HAPs emitted. 

NOTE 2 

Fugitive emissions occur at several points throughout this plant. Boral Bricks has no data on 

these emissions, and is not including fugitive sources per Feb. 25, 1998 telephone conversation 

between 011ie Fick (Consultant to Boral Bricks) and Bill Neuffer of the EPA. 

Page 12 of 28 

o~ ~~ 
C. Using Table 3, please provide information on procedures used to monitor the process 

operating rate for each of the pieces of equipment and HAP emission sources listed in Tables 2A 

and 2B. Use the same HAP emission source types a.nd equipment ID numbers you listed in Tables 

2A to 2B. 

Indicate whether you monitor process rate or not. 

Provide a summary of process rate monitoring procedures that 

describes how process rate is measured for the particular piece of 

equipment. Include where the rate is monitored (i.e., rate of material fed, 

rate of material discharged, or material production rate), the units used to 

measure process rate (e.g., lb/hr or pieces/hr), and how the process data is 

recorded, i.e., manually, automatically (e.g., computer - printout or stored 

to disk, or not at all). If you monitor process rate at both the feed and 

discharge ends of the equipment, indicate so. 

Indicate the type of monitor, equipment, or instrument used to measure 

process operating rate. 

Indicate the monitoring frequency or how often process rate 

measurements are made. 

If instruments are used to measure process throughput, indicate in the 

monitor accuracy column the accuracy of the instrument. The monitor 

accuracy could be listed in terms of a percentage of the throughput 

(f 1 percent), mass per unit time (±21b/hr), number of pieces per unit time 

(t 10 pieces/hr), or other appropriate units. 

Indicate the frequency that the monitor is calibrated. 

Provide data in the units listed for each row. 

Page 13 of 28 

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VI. Identification of Brkk azd Struclura4 Clay Pxoducl N. .tKturin Er~' ion Points 

A. Use the process flow diagrams developed for your f$cility artd Table 4 to provide 

the following information for each HAP emission source at yottr facility. 

Define HAP emisston stiarce type in terms of equipsnent, such as dryers, 

kiMs, etc. As in the process flow diagram, you may group multiple pieces of 

similar equipment. 

Use the same equipment ID numbers :=wated on the process flow diagram(s). 

If th~: ~~urce vents imside a 

frrst ugh a control device, 

cohunn. 

Agor to outside ambient air without 

e a check mazk in the uncontrolled 

If tle emissiari ~,)uree vents inside a 1-. 1 or to outside atnbient air after 

passing through a fabric $her, dry in?t. fabric filter, or scruk ~ber, place the 

APCD Ifa nwnbe,r(s) in the cohum t° i .)onding to the APCD type. 

If the em ission source vents throuY: .=ytrol device type not listed in Table 4, 

indicate the control device type in other control cokimn and p*e the 

APCD ID number iQ the wropriate celL 

In the emission test data cohnm, place a"yes" or "no" m the appropriate cell 

to indicate whether the specific se -,. -T has been tested f,or any pollutants, 

uuchiding any HAP's, VOC, PM, c i:city. 

Page 15 of 28 

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B. Using Table 5, please provide informa.tion on stack parameters and emission 

estimates for each emission point at your facility that is known or expected to emit 

HAP's. Provide information for all APCD's, including those that exhaust inside the 

building. Include data for each inlet and outlet, if available, as indicated in the table. 

If you have more tha.n one inlet to an APCD, provide data for each of the inlets. 

Provide data in the units listed for each row. 

Provide emission estima.tes for any HAP's or HAP surrogates, such as PM for metal 

HAP's or VOC for organic HAP's. Emi.ssion estimates may consist of 

measurements reported in emission test reports or may be calculated using mass 

balances, emission factors, engineering judgement, or other estimation methods. 

Provide the emission estima.tes as emission factors in units of lb of pollutant emitted 

per ton of product (lb/ton). Provide complete copies of any emission test reports 

or other reports that document measurements of emissions. Test reports and 

other emission measurement documents should include the following information: 

process identification; location of sampling point; stack diameter, temperature, and 

flow rate; test method, including analytical procedures; number of test runs; 

emission concentration, emission rate, percent oxygen, and percent moisture for 

each test run; process operating rate; type of APCD; and APCD operating 

parameters. However, test reports with incomplete documentation may still be 

useful and should also be submitted. 

You do not need to fill out Table 5 for emission points that are covered by an 

emission test report that is included in your submittal. If emission test reports are 

not available, provide calculations that support your emission estimate, 

including the basis for all assumptions in the estimate. Note that eniission 

estimates are needed for all HAP's that the facility emits or has the potential to emit. 

(Please refer to the HAP list in Attachment 1.) If the information requested in the 

table is contained in your facility's operating permit, you may reference the 

applicable sections of the permit rather than filling out the table. 

Page 17 of 28 

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C. Using Tabtes 6A #hrough 6D, please pravide design and operating data for each APCD 

associated with atl dryers, kins, and any other brick and structural clay products 

manu£acturing source that may emit HAP's. Use Tables 6A to 6C for speciflc types of 

APCD's. Use Tabie 6D for other iypes of APCD's. When using Table 61), pkase 

specify the type of controi device and 2 to 4 key design or operating parameters for tlte 

device. Provide data in the wtits listed for each row. Yf the information requested in 

Tables 6A through 6D is contained in your facility's operating permit, you my reference 

the applicable sections ofthe perinit rather than Ming out the ta.bles. 

Page 20 of 28 

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D. Using Table 7, please provide the foflowing information on current monitoring 

procedures for each of the control devices listed in Tables 6A to 61): parameters 

monitored (e.g., baghouse pressure drop), monitoring frsquency, monitoting devices 

used (e.g., differential pressure trausducer, thermocouple), and necordkeeping 

practices (e.g., nianually recorded in log book, continuously recorded by electronie d$ta 

acquisition system). Describe briefly other operation and maiurtenance (O&IV) 

procedures for each control device. If the information requested in the table is cotrtained 

in your facility's operating permit, you may referenee the applicable sections of tbe 

permit rather than filling out the table. 

VII. Pollution Prevention Pragtices for Brick and Structural Clay Products Manufacturing 

A. Please describe all pollution prevention practices (i.e., process rnodifications, such as reuse of discarded or rejected materials, or any practice that prevents or reduves the 

amount of air emissions, or the generation and release of solid waste or wastewater 

associated with the operation of air pollution controls). If the infortnation rec}uested 

here is contained in your facili#y's operating permit, you may reference the applicable 

sections of the permit rather than providing the ittfprmation below. 

This fac' I) recycles waste heat from the kiln to heat the d=s and to a ksset 

degree, xhe holding room; 2) recycles floor swgepings and sarap/wastB clay into the 

brick body: 3) recycies green bricic into the brick bodY: 4) r ~ecYeles waste slurry into the 

brick body: 5) receySIQ offspec brick (,grog) into the brick body; 6) reeycles sand 

coating into the briock body 7) recy,cles wash w.ater into the brick body 

Page 25 of 28 

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VIII.Information on Processes Ot 4:: Than Brick and Structural Clay Products Manufacturing 

Processes 

A. Using Table 8, please ide:;tify all other processes or operations at this facility that are 

not addressed in Items II through VII above and that are potential sources of HAP 

emissions. Estimate total annual emissions of each HAP emitted by these collocated 

processes. If the information requested in the table is contained in your facility's 

operating permit, you may reference the applicable sections of the permit rather than 

filling out the table. 

Mining in support of brick manufacturinQ (Brick SIC Code: 3251) See Table 8 

Page 27 of 28 
TABLE 8. ESTIMATED ANNUAL HAP EMISSIONS FROM OTHER SOi TRC'F IR 

Process/emission source/SIC Code(s) HAP's emitted Estimated annual emissions, 

tons 

EXAMPLEc: Mining 

SIC 

trace metals 

(Cr, Mn; Ni 

conEpounds). 

_ 0.2 

Mining in Support of Brick Manufacturing: 

Some of the raw materials used by this plant 

are obtained from an adjacent mine that is 

owned by Boral Bricks. All material is 

transported to the facility for processing. No 

mine data are reported in this ICR because 

Boral Bricks has no emissions data. 

SIC 3251 

No data No data 

SIC 

SIC 

If the information requested in the table is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the table. 

Page 28 of 28 

m 
iviaterialbatety ata ~5hee 

Substance Identification 

Identity: MANGANESE DIOXIDE . CAS #: 1313-13-9 

Trade Names: - ~'Brickox, GranuSpeck , 

Manufacturer: The Prince Manufacturing Company Emergenry: Chemtrec 

One Prince Plaza 1-800-424-9300 

Quincy, IL 62.'i01 

217-2?2-8854 

Components and Contaminants 

Chemical Name CAS # OSHA PBL ACGIH TLV P rc n 

Manganese Compound (as Mn) 7439-96-5 5 mg/m3(C) 5 mg/m3(C) 51-55% Mn 

Iron Oxide 1309-37-1 --- --- 1-5% Fe2O3 

Silica, Crystalline Quartz (respirable) 14508-60-7 0.1 mg/m3 0.1 mg/m3(TWA) 1-5% Si0 = 

Aluminum Oxide (non-fibrous) 

(respirable fractioh) 1344-28-1 5 mg/m3 15 mg/m3(TWA) 1-7% Al203 

Barium Oxide 1304-28-5 -- --- 0.2-2% Ba0 

Physical Data 

Boiling Point: NA Specific Gravity (H=O =1): 5.0 

Vapor Pressure (mm/Hg): NA Melting Point: (Decomposes) 535° C 

Vapor Density (Air=1): NA Evaporation Rate (Butyl Acetate =1): NA 

Solubility in Water: insoluble 

Appearance and Odor: black to browaish black, no odor 

Fire and Explosion Hazard Data 

Flash Point: Not combustible 

Flammable Limits: LEL NA UEL NA 

Extinguishing Media: Foam, CO2, or dry chemical. 

Special Fire Fighting Procedures: In the event of fire, wear full protective clothing and MOSH-approved selfcontained breathing apparatus with full face piece operated in the pressure 

demand or other positive pressure mode. 

Unusual Fire and explosion hazards: Not combustible, but substance is a strong oxidizer and its heat of reaction with 

reducing agents or combustibles may cause ignition. Increases the flammability of any combustible substance. 

Reactivity Data 

Stability: Stable under ordinary conditions of use aad storage. 

Conditions to avoid: Do not heat or grind in the presence of easily oxidizable substances or organic 

matter. 

Incompatibility (materials to avoid): Easily oxidizable substances, sulfur, sulfides, phosphides, hydrophospliides, 

chlorates, peroxides, aluminum powder, rubidium acetylide, potassium a7ide, 

chlorine tritluoride. Reacts with hydrochloric acid to form corrosive chlorine 

gas. 

Hazardous Decomposition or Byproducts: Upon heating it decomposes to form manganese sesquioxide and oxygen which 

facilitates combustion. 

Hazardous Polymerization: Will not occur. 

Manganese Dio)dde, Page : 

Reviewed October 1994 Unchanged since July 1991 

~Z'~Z~7 
~ Health Hazard Data 

Route of Entry: INHALATION: May irritate the respiratory tract. May increase the incidL:nc;: 

of upper respiratory infections (pneumonia). Prolonged exposure to silica du,t 

may result in silicosis, a fibrotic lung disease. 

SKIN: May cause irritation. 

1NGESTION: May cause abdominal pain and nausea. Manganese dioxid;2 

dust is poorly absorbed through the gut. ' 

Hcalth Hazards (Acute and Chronic): Chronic exposure and inhalation of excessive manganese dust may cause disorders of the central nervous system. 

Carcinogenicity: NTP: No IARC Monographs: Yes (Siliea) 

Signs and Symptoms of Exposure: Early symptoms of manganese toxicity include sluggishness, sleepiness, and 

weakness in legs. Symptoms of silicosis include impaired pulmonary function 

and wheezing. 

Aggravation of Pre-existing Conditions: Persons with impaired respiratory function may be more susceptible to the effect of this substance. 

Emergency and First Aid Procedures: IF INHALED, remove to fresh air and seek medical attention for any breathin_ 

difficulty. - 

IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical attention if red & irritated. 

IN CASE OF EYE CONTACT, flush eyes immediately with water for at least 

15 minutes. Seek medical attention if irritation persists. 

IF INGESTED, induce vomiting immediately by giving two glasses of water 

and sticking finger down throat. Never give anything by mouth to an unconscious person. Call a physician immediately. 

Precautions for Safe Handling and Use 

Material Release or Spill Precautions: Should a spill occur, ventilate area. Clean-up personnel require respirator} 

protection. Recover uncontaminated material for use. Vacuum or sweep 

remaining material, keeping dust to a minimum. Isolate wet material from drv 

and store away from combustible materials. 

Waste Disposal Method: Dispose of unreclaimable material in a RCRA-approved waste facility. 

Handling and Storing Precautions: Manganese dioxide is classified as an oxidizer and should be stored in a dr ., 

place away from combustibles and sources of high heat. Protect containers 

from damage and keep closed when not in use. 

Other Precautions: Observe good personal hygiene. Wash after handling. 

Control Measures 

Respiratory Protection: Use NIOSH approved particulate respirator if dust generation occurs or is 

anticipated. USBM approved schedule 21B respirator or equal is recommended. 

Ventilation: A system of local and / or general exhaust is recommended to keep employee 

exposures below the Airborne Exposure Limits. Local exhaust is generally 

preferred because it can control the emissions of the contaminant at its 

source, preventing dispersion of it into the general work area. Please refer to 

the ACGIH document, "Indust-rial Ventilation, A Manual of Recommended 

Practices", most recent edition, for details. 

Protective Gloves: Yes 

Eye Protection: Safety goggles are recommended. 

Other Protective Clothing or Equipment: Use other protective equipment when necessary in order to avoid prolonged 

exposure to skin. 

Work and Hygienic Practices: Observe good personal hygiene. Wash after handling. 

SARA Title III Section 313 Supplier Notification 

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emereency 

Planning and Community Right-to Know Act of 1986 and of 40 CFR 372.45: 

Component CAS # % by Weieht 

Manganese Dioxide 1313-13-9 51- 55% Mn 

Barium Oxide 1304-28-5 0.1-1.8% Ba 

This information must be included in all MSDS's that are copied and distributed for this material. 

Manganese Dioxide, Page 2 

Reviewed October 1994 Unchanged since Jul,v 1991 

mi 
~ 'da-_RIaL 3A=°_77 DaTA SODI ONATE + m c 

m DA VERSION 

PRINTED FOR ............... 

497 -19 -8 

EFFECTIVE: 02/03/94 

DELTA DISTRIBUTORS 

ATTN: WAYNE WRIGHT 

10319 E. 54TH ST. 

TULSA OK 74146 

NTED: 09/07/94 

COPY, 

~ 

PRODUCTNAME .............: 

SYNONYMS.................: 

INFORMATION PROVIDED BY..: 

11. CHEMICAL PRODUCT/COMPANY IDENTIFICATION 

SOD I UM,,,,~ ARBONA-TE:.~-„ANHYIIQ. 

ti![,'Y- .. ~;~.. ..,c. ~._ .r .:• 

50DA SH,_SOIIII~M: ~.CiARBON~ ^ NH. DROUS"1 

FMC-`WYOM I GN CORPORAT I ON ,- 

1735 MARKET STREET ~ 

PHILADELPHIA, PA 19103 ~ 

(800) 253-7632 

(800) 424-9300 

(303) 595-9048 CALL COLLECT' 

(307) 875-2580 CALL COLLECT . 

2. COMPOSITION/INFORMATION ON INGREDIENTS 

97-19-8 SODIUM CARBONATE 99.8% :. 

EMERGENCY PHONE NUMBERS 

CHEMTREC..............: 

MEDICAL...............: 

PLANT/OTHER ........... : 

CAS # AND COMPONENTS ..... : 

. HAZARD IDENTIFICATION 

EMERGENCY OVERVIEW ....... : 

HEALTHEFFECTS ........ ...: 

WHITE GRANULAR SOLID. PRODUCT IS 

NON-COMBUSTIBLE. REACTS WITH ACIDS TO RELEASE 

CARBON DIOXIDE AND HEAT. IRRITATING TO THE 

EYES. CONTINUOUS CONTACT MAY IRRITATE SKIN. 

DIRECT CONTACT WITH THE PRODUCT CAUSES 

IRRITATION OF THE EYES AND CONTINUOUS CONTACT 

MAY CAUSE SKIN IRRITATION (RED, DRY, CRACKED 

SKIN) . 

EXCESSIVE LEVELS OF AIRBORNE DUST MAY IRRITATE 

THE MUCOUS MEMBRANES AND UPPER RESPIRATORY 

TRACT. 

--------"---------------- 14. FIRST AID MEASURES 

EYES ............. ........: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 

15 MINUTES, LIFTING THE UPPER AND LOWER LIDS 

OCCASIONALLY. SEE A MEDICAL DOCTOR IMMEDIATELY. 

SKIN .....................: WASH WITH PLENTY OF WATER FOR 15 MINUTES. IF 

IRRITATION OCCURS AND PERSISTS, OBTAIN 

MEDICAL ATTENTION. 

INHALATION ...............: REMOVE FROM EXPOSURE. IF DISCOMFORT OCCURS 

AND PERSISTS, OBTAIN MEDICAL ATTENTION. 

INGESTION ................: RINSE MOUTH WITH WATER. DILUTE BY GIVING 1 OR 2 

GLASSES OF WATER. DO NOT INDUCE VOMITING. NEVER 

GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. 

SEE A MEDICAL DOCTOR IMMEDIATELY. 

NOTES TO PHYSICIAN ....... : WHILE INTERNAL TOXICITY IS LOW, IRRITANT 

EFFECTS OF HIGH CONCENTRATIONS MAY PRODUCE 

(CONTINUED) PAGE 01 ~-SI 
"'-=--' JAT" SOD I UM CARBONATE 

497 -19 -8 

U.S./CANADA VERSION EFFECTIVE: 02/03/94 PRINTED: 09/07/94 

4. FIRST AID MEASURES ------------- 

ORNEAL OPACITIES AND VESICULAR SKIN 

EACTIONS IN HUMANS WITH ABRADED SKIN ONLY. 

REATMENT IS SYMPTOMATIC AND SUPPORTIVE. 

-------------------- 15. FIRE FIGHTING MEASURES 

EXTINGUISHING MEDIA ...... : 

SPECIAL FIREFIGHTING ..... : 

PROCEDURES 

DEGREE OF FIRE AND ....... : 

EXPLOSION HAZARD 

HAZARDOUS DECOMPOSITION..: 

PRODUCTS 

'WATER, WATER,FOG, CARBON DIOXIDE (CO2), 

RY CHEMICAL. 

WEAR FULL PROTECTIVE CLOTHING AND SELF 

CONTAINED BREATHING APPARATUS. 

NOT APPLICABLE. 

EATED TO DECOMPOSITION, IT EMITS FUMES OF 

SODIUM OXIDE. 

~6. ACCIDENTAL RELEASE MEASURES 

PROCEDURE FOR RELEASE....: WEEP UP AND RECYCLE INTO PROCESS IF 

OR SPILL CONTAMINATION DOES NOT PRESENT A PROBLEM. USE 

PPROPRIATE PROTECTIVE EQUIPMENT IF DUST IS 

GENERATED DR CONTACT WITH EYES OR SKIN IS 

XPECTED. FLUSH RESIDUES AND LIQUID TD HOLDING 

REA FOR NEUTRALIZATION BEFORE DISCHARGE. 

HANDLING AND STORAGE _----------__----__---- 

HANDLING ................. SE AIR CONVEYING/MECHANICAL SYSTEMS FOR BULK 

RANSFER TO STORAGE. FDR MANUAL HANDLING OF BULK 

RANSFER USE MECHANICAL VENTILATION TO REMOVE 

IRBORNE DUST FROM RAILCAR, SHIP OR TRUCK. USE 

PPROVED RESPIRATORY PROTECTION WHEN VENTILATION 

YSTEMS ARE NOT AVAILABLE. SELECTION OF 

ESPIRATORS IS BASED ON THE DUST CLOUD 

ENERATED. 

VENTILATION ..............: RDVIDE GENERAL MECHANICAL AND/OR LOCAL EXHAUST 

ENTILATION TO PREVENT RELEASE OF AIRBORNE DUST 

INTO THE WORK ENVIRONMENT. APPROVED RESPIRATDRY 

RDTECTION SHOULD BE USED WHEN AIRBORNE DUST 

IS EXPECTED TO BE RELEASED. 

STORAGE ..................: TORE IN A COOL DRY AREA, AWAY FROM ACIDS. 

18. EXPOSURE CONTROLS/PERSONAL PROTECTION ====== 

CONTROL MEASURES.........: INIMIZE EYE AND SKIN CONTACT BY USING 

PPROPRIATE PROTECTIVE EQUIPMENT. USE LOCAL OR 

ENERAL ROOM VENTILATION TO CONTROL AIRBORNE 

UST THAT MAY BE GENERATED INTO THE WORK 

NVIRONMENT. 

RECOMMENDED PERSONAL 

(CONTINUED) PAGE 02 
USE APPROVED DUST RESPIRATORS FOR LOW LEVELS OF 

AIRBORNE DUST. HIGH CONCENTRATIONS MAY REQUIRE 

AIR SUPPLIED SYSTEMS. 

USE CUP TYPE. CHEMICAL GOGGLES. 

USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT. 

ARM PROTECTORS AND APRONS. IF CLOTHING BECOMES 

CONTAMINATED REMOVE AND LAUNDER BEFORE REUSE. 

INDUSTRIAL SAFETY SHOES. 

. PHYSICAL AND CHEMICAL PROPERTIES 

1 DEGREES C(13b4 DEGREES F) 

COMPOSES 

T APPLICABLE 

T APPLICABLE 

ITE. SOLID GRANULAR 

DORLESS 

.509 

3.2 MAXIMUM. 

DT APPLICABLE 

DT APPLICABLE 

NOT APPLICABLE 

11.4 

NOT APPLICABLE 

DENSE GRADES,0.86-1.121 

NOT APPLICABLE 

ONCOMBUSTIBLE 

OT APPLICABLE 

OT APPLICABLE 

OT APPLICABLE 

OT APPLICABLE 

OT APPLICABLE 

OT AVAILABLE 

LIGHT GRADES.0.70-0.90 

SODIUM CARBONATE 

497 —19 —8 

EFFECTIVE: 02/03/94 PRINTED: 09/07/9 

. EXPOSURE CONTROLS/PERSONAL PROTECTION ====== 

PROTECTIVE EQUIPMENT 

RESPIRATORY........: 

EYES ...............: 

GLOVES .............: 

SPECIAL CLOTHING...: 

AND EQUIPMENT 

FOOTWEAR ...........: 

MELTING/FREEZING POINT...: 

BOILING POINT .... ........s 

VAPOR PRESSURE ........... : 

VAPOR DENSITY (AIR=1) .... : 

ROOM TEMPERATURE ......... : 

APPEARANCE AND STATE 

ODOR .....................: 

SPECIFIC GRAVITY (H2O=1).: 

SOLUBILITY IN H20 y BY WT: 

% VOLATILES ..............: 

EVAPORATION RATE.........: 

(BUTYL ACETATE=1) 

PH(AS IS) ...............a 

PH (lY. SOLUTION).........: 

ODOR THRESHOLD .......... .: 

DENSITY (G/ML)...........: 

PARTITIDN COEFFICIENT....: 

N—OCTANOL/WATER 

FLASH POINT ..............: 

AUTOIGNITION TEMPERATURE.s 

FLAMMABLE LIMITS UPPER..: 

(AIR) LOWER..: 

EXPLOSIVE PROPERTIES.....: 

OXIDIZING PROPERTIES.....: 

SOLUBILITY ...............: 

— FAT SOLUBILITY 

(SOLVENT — OIL) 

-------------------------- --------------------- ~ 10. STABILITY AND REACTIVITY 

STABILITY................a STABLE 

HAZARDOUS POLYMERIZATION.: WILL NOT OCCUR 

CONDITIONS TO AVOID ...... : CONTACT WITH ACIDS EXCEPT UNDER CONTROLLED 

CONDITIONS. 

MATERIALS TO AVOID ....... : ALUMINUM POWDER. ACIDS, FLUORINE, MOLTEN 

LITHIUM. 

MAJOR CONTAMINANTS THAT..: 

(CONTINUED) PAGE 03 
,.. _. ,. _ 3.4=_ 77 :;.. 7 .. SODIUM CARBONATE ~ 

—19 — 

U.S./CANADA VERS EFFECTIVE: 02/03/94 PRI NTED: 09/07/94 

----------- 10. STABILITY AND REACTIVITY 

CONTRIBUTE TO INSTABILITY NONE 

INCOMPATIBILITY...........: REACTS WITH ACIDS WITH RELEASE OF LARGE VOLUMES 

OF CARBON DIOXIDE GAS AND HEAT. 

HAZARDOUS DECOMPOSITION..: NONE 

PRODUCTS 

SENSITIVITY TO MECH......: INONE 

IMPACT 

SENSITIVITY TO STATIC .... s NONE 

DISCHARGE 

111. TOXICOLOGICAL INFORMATION -- ------ 

EYECONTACT ..............: 

SKIN CONTACT .............: 

SKIN ABSORPTION........... 

INHALATION...............: 

INGESTION................: 

ACUTE EFFECTS FROM ....... : 

OVEREXPOSURE 

CHRONIC EFFECTS FROM.....: 

OVEREXPOSURE 

(EFFECTS CONSIDERED 

INCLUDE: 

SENSITIVITIES, 

CARCINOGENICITY, 

TERATOGENICITY. 

MUTAGENICITY. 

SYNERGISTIC . 

PRODUCTS. AND ANY 

MEDICAL CONDITIONS 

GENERALLY RECOGNIZED 

AS BEING AGGRAVATED 

BY EXPOSURE.) 

3EVERE IRRITANT (RABBIT) 

rOXICOLOGY 23:281-291 (1982) 

VON—IRRITATING TO INTACT SKIN. MINOR IRRITATION 

MAY OCCUR ON ABRADED SKIN. 

VON—SENSITIZING (GUINEA PIG) 

rOXICOL. APPL. PHARMACOL. 31:481-490 (1975) 

VO DATA AVAILABLE. 

_C50 = 2.3 MG/L (RAT,2 HR.) ENVIRON 

3ES 31:138 (1983). 

_D50 = 4090 MGlKG (RAT) (RTECS 1985-6). 

MAY CAUSE SEVERE IRRITATION OF THE EYES. 

[NCLUDING CORNEAL OPACITIES. DUSTS AND MISTS 

4RE IRRITATING TO THE SKIN. MUCOUS MEMBRANES 

4ND UPPER RESPIRATORY TRACT. 

MAY CAUSE INFLAMMATION OF THE MUCOUS MEMBRANES 

IN THE RESPIRATORY TRACT AND OF THE SKIN. 

ECOLOGICAL INFORMATION 

ENVIRONMENTAL FATE ....... : BIODEGRADABILITY DOES NOT APPLY TO INORGANIC 

UBSTANCES. NO OTHER DATA AVAILABLE. 

ENVIRONMENTAL EFFECTS .... : 96 HR. LC50 (DAPHNIA MAGNA) a 265-565 MG/L. 

6 HR. LC50 (BLUEGILL SUNFISH) = 300-320 MG/L. 

( CONT I NUED ) PAGE 04A3• 
SODIUM CARBONATE 

497 -19 -8 

NA DA VERSION PRINT : 09/07/94 

DISPOSAL CONSIDERATIONS =___-----_-_-_--_-- 

WASTE DISPOSAL METHOD .... : SALVAGE AS MUCH MATERIAL AS POSSIBLE AND RETURN 

TO PROCESS IF CONTAMINATION DOES NOT PRESENT A 

PROBLEM. DISPOSE IN AN APPROVED LANDFILL IN 

ACCORDANCE WITH ACCEPTED GOVERNMENTAL 

REGULATIONS. 

--------------- ------------"--------=====114. TRANSPORT INFORMATION 

DOT PROPER SHIPPING NAME.: 

IATA .....................: 

IMDG ....... ................ 

DOT CLASSIFICATION.......: 

DOT LABELS ...............: 

DOT MARKING ..............: 

DOT PLACARD ..............: 

UN NUMBER ................: 

HAZARDOUS SUBSTANCE/RQ ... : 

49 STCC NUMBER ........... : 

PRECAUTIONS TO BE TAKEN..: 

IN TRANSPORTATION 

OTHER SHIPPING...........: 

INFORMATION 

SODIUM CARBONATE 

NOT APPLICABLE 

NOT APPLICABLE 

NON HAZARDOUS 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

BWEEP UP, RETURN TO CONTAINER AND MARK AS WASTE 

FOR DISPOSAL. 

50DIUM CARBONATE IS GENERALY REGARDED AS SAFE, 

(GRAS) WHEN USED WITH CURRENT GOOD 

INANUFACTURING PRACTICES. 

-------------- -------------------------- "----------- I15. REGULATORY INFORMATION 

OSHA 

EXPOSURE LIMITS 

SUBSTANCE(S) ........... : 

OSHA PEL—TWA .......... : 

STEL .... ... ... ...s 

CEILING. ..... ....s 

SKIN DESIGNATION.: 

ACGIH TLV—TWA .......... : 

STEL ..... . ....... : 

CEILING...... .... : 

SKIN DESIGNATION.: 

TARGET ORGAN EFFECTS ..... : 

CARCINOGENIC POTENTIAL ... : 

REGULATED BY OSHA ...... : 

LISTED ON NTP REPORT ... : 

IARC GROUP 1, 2A, 2B...: 

U.S. EPA REQUIREMENTS 

RELEASE REPORTING 

CERCLA (40 CFR 302) 

LISTED SUBSTANCE(S)....: 

RQ ............... 

CATEGORY.........: 

RCRA WASTE NO....: 

SODIUM CARBONATE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

EYE 

NO 

NO 

NO 

NOT LISTED 

NOT APPLICABLE 

NOT APPLICABLE 

NOT APPLICABLE 

o!~, 33 

(CONTINUED) PAGE 05 
SODIUM CARBONATE Pil I= 

497 —19 — 

.S./CANADA V EFFECTIVE: 02/03/9 PRINTED : 09/07/9 

-------------------------= 115. REGULATORY INFORMATION =____-----_--_------ 

UNLISTED SUBSTANCE(S)..: 

RQ ............... 

CHARACTERISTIC...s 

RCRA WASTE NO .... : 

SARA TITLE III SEC 313 

(40 CFR 372) ........... : 

LISTED TOXIC CHEMICAL..; 

INVENTORY REPORTING 

SARA TITLE III SEC 311/312 

(40 CFR 370) 

SUBSTANCE(S)...........a 

HAZARD CATEGORY ........ : 

PLANNING THRESHOLD ..... a 

EMERGENCY PLANNING 

SARA TITLE III SEC 302-303 

(40 CFR 355) 

LISTED SUBSTANCE(S)....: 

a .....................• 

PLANNING THRESHOLD.....: 

U.S. TSCA STATUS.........: 

CANADA 

INGREDIENT DISCLOSURE LIST 

SUBSTANCE(S) ........... : 

CONTROLLED PRODUCT ....... : 

H AZARD SYMBOLS ........... : 

CLASS & DIVISION ....... : 

PRODUCT IDENTIFICATION N0: 

DOMESTIC SUBSTANCE LIST..: 

CEPA PRIORITY LIST ....... : 

CARCINOGENICITY 

ACGIH APPENDIX A ....... : 

A1 — CONFIRMED HUMAN...a 

A1 — SUSPECTED HUMAN...: 

IARC GROUP 1 OR 2 ........ : 

LABEL LANGUAGE (US/CANADA) 

HEALTH.................: 

PHYSICAL...............: 

HANDLING AND STORAGE...: 

FIRST AID ..............: 

STATE REGULATIONS ........ : 

OT APPLICABLE 

OT APPLICABLE 

OT APPLICABLE 

OT APPLICABLE 

T LISTED 

SODIUM CARBONATE 

IMMEDIATE (ACUTE) HEALTH HAZARD (IRRITANT) 

10,000 POUNDS 

OT APPLICABLE 

OT APPLICABLE 

OT APPLICABLE 

ISTED 

ODIUM CARBONATE 

ES 

OXIC 

LASS D. DIVISION 21 SUBDIVISION B. 

OT APPLICABLE 

ISTED 

OT LISTED 

T LISTED 

T LISTED 

T LISTED 

UST MAY CAUSE SEVERE IRRITATION OF EYES AND 

LIGHT IRRITATION OF NOSE AND THROAT. REPEATED 

ONTACT MAY CAUSE REDNESS AND DRYs CRACKED SKIN. 

OT APPLICABLE 

0 NOT STORE CLOSE TO ACIDS. WEAR EYE 

ROTECTION AND APPROVED DUST RESPIRATOR WHEN 

XCESSIVE DUST IS PRESENT. 

N CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH 

ATER FOR AT LEAST iS MINUTES. IF IRRITATION 

ERSISTS. OBTAIN MEDICAL ATTENTION. FLUSH SKIN 

ITH WATER. 

ALIFORNIA PROPOSITION 65: SAFE WATER AND TOXIC 

NFORCEMENT ACT OF 1986, THE FOLLOWING CHEMICALS 

AVE BEEN DETECTED. 

(CONTINUED) PAGE O6~ 
 +4ATEA1AL .> SODIUM CARBONATE 

497 -19 - 

-- --------------=115. REGULATORY INFORMATION 

ARSENIC,PPM AS AS203 = 0.03 

TOTAL CHROMIUM,PPM CR = 0.03 

LEAD,PPM PB ..... ..... _ <1 

CADMIUM,PPM CD....... _ <0.1 

ALL OTHER LISTED CHEMICALS ARE NOT DETECTED OR 

NOT SUSPECTED TO BE PRESENT. , 

16. OTHER INFORMATION 

PRODUCT USES .............: GLASS MANUFACTURE, DETERGENT MANUFACTURE, SODIUM 

CHEMICALS AND CARBONATE CHEMICALS MANUFACTURE, 

PULP AND PAPER, BRINE TREATMENT, WATER HARDNESS 

REMOVAL, PH ADJUSTMENT IN WATER OR WASTE WATER, 

FLUE GAS DESULFURIZATION, COAL TREATMENT, ION 

EXCHANGE RESIN REGENERATION. 

NFPA 704 

HEALTH..............: 

FLAMMABILITY ........ : 

REACTIVITY.......... : 

SPECIAL HAZARD ...... : 

(DEGREE OF HAZARD 

0 = NO HAZARD 

4 = SEVERE HAZARD) 

as=sos=asss=sasss=a=ssss=scsa=as=sc==ssaoao==s 

THE CONTENTS AND FORMAT OF THIS MSDS ARE IN 

ACCORDANCE WITH OSHA HAZARD COMMUNICATION AND 

CANADA'S WORKPLACE HAZARDOUS MATERIAL 

INFORMATION SYSTEM (WHMIS). 

~J 7 

PAGE 07 
03/06/98 08:23 17217 222 8854 PRINCE Lab Q 002 

Material Safety Data Sheet 

Substance Identification 

Merifih/: SYNiHET1C RED IRON OXiDE Cas #: 1309-37-1 

Trade Names: '17'56 e ~ F 6 ~ 

Manufacturer: The Prince Manufacturing Co. Emergency: Chemtrec 

One Prince Plaza 1-800-424-9300 

Quincy, IL 62301 

217-222-8854 

Components and Contaminants 

Chemical Name: CAg:R Q3HA PEL ACGIH TLV Percerrt 

Iron Oxide 1309-37-1 -- — 80-95% Fe203 

Par6cle.s not otherwise Regulated _ 

Total 15 mg/m' 15 mg1m3 (TWA) 

Respirable Fraction 5 mg/m' 5 m4/m3 (i'WA) 

Physical Data 

Boiting Point NA speciFc Gravity (H20-'): 4.8-5.3 

Vapor Pg ure (mm/Hg): NA Melting Poiint: > 1700° C 

Vapor Density (Air=1): NA Evaporation RatU (But)ti Aaetate-l): NA 

Solubitity in Water. insoluble 

Appearance and Odor: red to reddish-brown powder, no odor. 

Fire and Explosion Hazard Data 

Fiash Point: Not combustible 

Fiammable Limits: LEL NA UEL NA 

ExHnguishing Media: Foam, CO2, dry chemicaf or water. 

Speclal Fire Fighting Procedunes: In the event of 6re, wear fuN pmtec6ve clothing and NIOSH-appnoved 

self-contained bnaathing apparatus with full face piece operabed in the 

pressur+e demand or other posi6ve fxessure mode. 

Unusuai Fire and expiosion hazards: Not combustible. 

Reactivity Data 

Stability: Stable under ordinary conditions of use and storage. 

Conditbns to avoid: None Knawn. 

lncompatfbility (maberlals to avoid): Aluminum, Ethylene Oxide, Hydrazine, Caidum Hypoctdorite, 

Perlormic Acid, 13romine PentaRouride. 

Hazardous Decomposidon or Byproducts: None Known. 

Hazardous Poflm~erizaUon: Wili not occur. 

Health Hazard Data 

Route of Entry: MiHALATION: May cause irrittation of mucous membrane if dust is 

inhaled over a prolonged period of time. 

SK1N: No. 

INGESTI!ON: Ingestion of mineral compounds may cause abdominal 

pain and nausea. 

Synthetic Red Iron Oxide, Page 1 

Revbwad J* 1996 Unahartged since June 1991 

PW-06-1998 08:34 217 222 8E354 95% P' 02 

~ 3~~ 
03/06/98 08:23 '0217 222 8854 PRINCE Lab Q 003 

Health Hazard Data (cont.) 

Heatth Hazards (Acute and Chronic): Can cause eye irritation. Injury to skin may occur by direct mechanical 

action. 

Carcinogenicity: NTP: No IARC Monographs: No 

Signs and Symptoms of Exposure: Excessive inhalation of dust may result in shortness of breath and reduced 

pulmonary function. Iron oxide fum has been linked to siderosis which is 

considered to be a benign pneumoconiosis that exhibits no adverse health 

effects. To the best of our knowledge, this condition has not been observed 

after prolonged exposure to iron oxide pigments. 

Aggravation of Pre-existing Conditions: None Known. 

Emergency and First Aid Procedures: IF INHALED, remove to fresh air and seek medical attention for any 

breathing difflcully. 

IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical 

attention if ned S irritated. 

IN CASE OF EYE CONTACT, flush eyes immediately with water for at least 

15 minutes. Seek medical attention if irritation pensists. 

IF INGESTED, induce vomiting immediately by giving two glasses of water 

and sticking finger down thnoat Never give anything by mouth to an 

unconscious person. Call a physician immediately. 

Precautions for 3afe Handting and Use 

Material Release or Splll Precautions: Should a spill occur, ventilate area. Clean-up personnel require respiratary 

protection. Recwer uncontaminated material for use. Vacuum or sweep 

remaining material, keeping dust to a minimum. 

Waste Disposai Method: Dispose of unredaimable material in a RCRArapproved waste facitity. 

Handling and Storing Precautions: Protect containers from damage and keep closed when not in use. 

Other Pnmautions: Observe good personal hygiene. Wash after handling. 

Contro! Nleasures . 

Respiratory Protection: Use NIOSH approved pardculate respirator if dust generation occurs or is 

anticipated. OSHA standard 1910.134 or ANSt Z88.2-1980 specifications 

are recommended. 

Ventilation: A system of kwal and/or general exhaust is recommended to keep 

employee exposures below the Airbome Exposure Limits. Local exhaust is 

generalgr preferr+ed because R can control the emissions of the contaminant 

at its source, preventing dispersion of it into the general work area. Please 

refer to the ACGIH document, "Industr'ra! Ventilation, A Manual of 

Recommended Practices", most recent edition, for details. 

Protective Gloves: Yes 

Eye Pr+otection: Safety goggles are recommended. 

Other Protective Clothing or Equipment: Use other protective equipment when necessary in order to avoid 

probnged exposurre to skin. 

Work and Hygienic Praatices: Observe good personal hygiene. Wash after handling. 

SARA Title Ili Section 313 Supplier Notiflcation 

This product does 1g# contain chemicals subject to the reporting re 

and Community Right to-Know Act of 1966 and of 40 CFR 372.45: 

This information must be included in all MSDS's that are copied and distribubed far this material. 

syntlmtic Red Iron Oxdd0. Page 2 

Reviewed July 1996 Unchanged since June 1991 

MAR-06-1998 08:34 217 222 8854 95% P.03 

,~z 37 
03/06/98 08:24 '0217 222 8854 PRINCE Lab 9 004 

Material Safety Data Sheet 

Subatance Identification 

)dentity: MANGANESE OXIDE CAS #: 1317-35-7 

Trade Names: Brickox, Trimanganese Tetraoxide 

Manufacturer. The Prince Manufacturing Co. Emergency: Chemtnrc 

One Prince Plaza 1-800-424-9300 

Qufncy, IL 62301 

217-222-8854 

Components and Contaminants 

chemlcsI Name: GAS a' o5F1A PEL ACGIH TLV Pen:en 

Manganese Compound ( as Mn) 7439-96-5 5 mg/m3 (C) 5 mg/m3 (C) 68-70% Mn 

Iron Oxide 1309-37-1 — -- 2-4% Fe103 

Silica, Crystalline Quartz (respirable) 14808-60-7 0.1 mg/m' 0.1 mg/m3 ('TWA) 0.5-1 % SiOZ 

Aluminum Oxide (nonfibrous) 

(respirable fraction) 1344-28-1 5 mg/m' 5 mg/m3 (TWA) 1-2% AI20, 

Magnesium Oxide (respirabie) 1309-484 5 mg/m3 5 mg/m' (TWA) 1-2% Mg0 

Physicai Data 

Boiling Point: NA Specific Gravity (1420=1): 4.8 

Vapor Pressure (mnft): NA Melting Point: 1564° C 

Vapor Density (Air-1): NA Evaporstton Rate (Butyl Acetateal): NA 

Soiubility in Water. insoluble 

Appearance and Odor. brvHm tD broamish bladc. no odor 

Fire and Explosion Hazard Data 

Flash Point: Not combustibfe 

Flammable Llmits: LEL NA UEL NA 

Extinguishing Media: tJse exdnguishing media appropriate for surrounding fire. 

Special Fire Fighting Procedures: In the event of fine, wem fuN protiective dothing and NIOSH-approved 

self-contained breathing apparatus with full face piece oper°ated in the 

pressure demand or other positive pressure mode. 

Unusual Fire and explosion hazards: Not combustible, but substance is an oxidizer and its heat of n:action 

with reducing agents or combustibles may cause ignition. Increases 

the flammabiliiy of any combusU'bie substance. 

Reactivity Data 

Stabiiity: Stabie under ordinary conditions of use and storage. 

Conditlons to avoid: Do not heat or grind in the presence of easiiy oxdizab(e substances or 

organic matter. 

Incompadbility (materlals Eo avold): Easily oxid'¢able substances, suiiur, sulfides, phosphides, 

hydrophosphides, chlorates, peroxides, aluminum powder, rubidium 

acetyNde, potassium azide, chlorine trifluoride. Reads with 

hydrochloric add to forTn corrosive chlorine gas. 

Hazardous Decomposltbn or Byproducb: None icnamrn. 

Hazardous Polymerization: Will not occur. 

Health Hazard Data 

Route of Entry: INHALATION: May irritate the respiratory tracf. May increase the 

incidence of upper respiratory infeclions (pneumonia). Prolonged 

exposure to silica dust may resutt in silicosis, a fibrotic lung disease. 

SKIN: May cause irritation. 

INGESTION: May cause abdominal pain and nauses. Manganese 

dioxide dust is poorly absorbed thnwgh the gut. 

Mangama Oxide. >ap I 

september 1997 

MAf2-06-1998 08:35 217 222 8854 94% P.04 

~ 
03i06i98 08:25 0217 222 8854 PRINCE Lab Q005 

Health Haiard Data 

Healtlt Hazards (Acute and Chronic): Chronic exposure and inhalation of excessive manganese dust may cause 

disorders of the central nervous system. 

Carcinogenicity: 

Signs and Symptoms of Exposure: 

Aggravation of Pre-existing Conditilons: 

Emergency and Fin:t Aid Procedures: 

NTP: No IARC Monographs: Yes (Siiica) 

Earty symptoms of manganese toxicity include sluggishness, sleepiness, 

and weakness in legs. Symptoms of silicosis inciude impaired pulmonary 

function and wheezing. 

Persons with impaired respiratory function may be more susceptibie to the 

etfect of this substance. 

IF INHALED, remove to fresh air and seek medical attention for any 

breathing diffecutty. 

IN CASE OF SKIN CONTACT, wash with soap & water. Seek medical 

attention if red & inftated. 

iN CASE OF EYE CONTACT, flush eyes immediately with water for at least 

15 minutes. Seek medipl attention if irritation persists. 

IF INGESTED, induce vomiting immediately by giving two glasses of water 

and sticking 5nger down throat Never give anything by mouth to an 

unconscious person. Cali a physician immediately. 

Precautions for Safe Handling and Use 

iNaterial Release or Should a spill occur, ventilate area. Clean-up personnel nequire respiratory 

protection. Recover uncontaminated materiai fw use. Vacuum or sweep 

nemaining material, keeping dust to a minimum. Isolate wet traterial frorn 

dry and store away from combustibte msterials. 

Waste Disposal Method: Dispose of unreclaimable material in a RCRA-approved wasbe facility. 

Handling and Storing Precaudons: Manganese dioxide is dassified as an oxidizer and shouid be stored in a 

dry place away from combusitibes and sources of high heat. Protect 

containets ftom damage and keep cbsed when not in use. 

Other Precautions: Observe good personal hygiene. Wash after handling. 

Control Measures 

Respiratory Protection: Use NJOSH appraved padticulate respirator if dust generation occuss or is 

ant+cipated. OSl-!A standard 1910.134 or ANSI 288.2-1980 specifications 

are recommended. 

Yendlation: A system of kxcal and/or general exhaust is necommended to keep 

employee exposunrs below the Airbome Exposure Limits. Locai exhaust is 

generaAy preferred because k can control the emissions of the contaminant 

at its source, preventing dispension of it into the general work area. Please 

refer to the ACGIH document, "Industrial Ven6(atm, A Manual of 

Recommended Practices", most recent edition, for details. 

Protecthre Gloves: Yes 

Eye Protection: Safety goggles are recommended. 

Other Protectin e Clothing or Equipnrertt: Use other protective equipment when necessary in order to avoid 

prolonged exposure to skin_ 

Work and Hysienic Practices: Obserye good personal hygiene. Wash after hand6ng. 

SARA Title III Section 313 Supplier Notification 

This producx contains the foUowing toxic dhemkmis subject to the ne ~iporting requirements of section 313 of the Emergency 

Planning and Community Right-to-Know Act of 1986 and of 40 CFR 372.45: 

Comoonent CAS # 96 bv Weiaht 

Manganese Oxide 1317-35-7 68-70% Mn 

This information must be included in all MSDS's that ar+e copied and distributed for this material. 

Maogause dxide, Page 2 

Scptsmbcr 1997 

MAl2-06-1998 08:36 217 222 8854 92% P. 05 

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EPA iVIACT Information Collection 

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MACT Information Collection Request Response 

from 

Boral Brick,s, Inc. 

Table of Contents 

• Information 'Collection Request 

• Appendix A - MSDS's 

• Appendix B - Test Data 

aq( 
Enclosure 2 

INFORMATION REQUEST FOR BRICK AND 

STRUCTURAL CLAY PRODUCTS MANUFACTURING OPERATIONS 

I. Instructions 

Please return the completed information request to: 

Bruce C. Jordan, Director 

Attn: Bill Neuffer 

Emission Standards Division (MD-13) 

U. S. Environmental Protection Agency 

Office of Air Quality Planning and Standards 

Research Triangle Park, North Carolina 27711 

If you need clarification of any question or item, please contact Mr. Bill Neuffer of EPA at 

(919) 541-5435. 

This information request should be completed for each facility that manufactures brick and 

structural clay products, including facilities that are not major sources. Information is 

requested for all processes at your plant that emit hazardous air pollutants (HAP's), 

including those processes that are not associated with brick and structural clay 

products manufacturing. Sections II through VII request information specific to brick 

and structural clay products manufacturing, and Section VIII requests information on 

emissions of HAP's from other processes located at the facility. Processes that may emit 

HAP's include those processes that use or handle any materials that contain a HAP 

compound, all processes with elevated temperatures, and all other processes in which HAP 

compounds may be formed. The HAP list from Section 112(b) of the Clean Air Act is 

included as Attachment 1 to this information request. Attachment 2 provides background 

information on the requirements of the Clean Air Act and explains how the information 

requested in this questionnaire will be used by EPA. Attachment 3 is a list of abbreviations 

and acronyms used in this information request. 

Several tables are provided throughout the information request for your convenience in 

answering the questions. An example response is given (shaded first column or row) in 

each table. If additional space is needed to respond, please make copies of applicable 

pages. If necessary, please make copies of this information request for additional facilities. 

No additional emission testing or monitoring is required to respond to this request. 

To M- . I W-M Wil ro_e M10, riT W 

A. Name of company Boral Bricks. Inc 

Name of facility Augusta Plants 3& 5 

Page 1 of 39 

c~V-2-- 
Facility address: 

No. and street 1630 Athern Road 

City Augusta State GA Zip 30901 

Latitude and longitude coordinates of plant: Lat. 33° 27' 17" Long. 81° 57' 32" 

Standard Industrial Classification (SIC) Code(s) of brick and structural clay products 

manufacturing operations 3251 

Dun and Bradstreet No. 003275682 

Total No. of employees for company >1,500 for facility 225 

(If facility is a foreign subsidiary or if company has foreign subsidiaries, include 

number of employees not based in the U.S.). 

Please complete the following shift information for the facility: 

Shift No. of employees Hours per shift Days per year 

1 186 10 252 

2 10 10 252 

3 5 10 252 

B. Respondent name Guiomar Obregon 

Respondent title Analyst 

Respondent address (if different from above) and telephone number: 

No. and street 500 Northridge Road, Suite 300 

City Atlanta State GA Zip 30350 

Telephone No. (770) 645-4500 

Name and telephone number of technical contact person (if different from above) 

Name David Johnson Telephone No. (334) 480-2487 

III. Information on Operating Permits and Applicable Federal Emission Standards 

A. Please provide copies of relevant parts of all operating permits and permit 

applications for your facility. Relevant parts include the sections that provide specific 

information and data on: processes that emit HAP's; the use of HAP- containing 

Page 2 of 39 

,P,43 
specific information and data on: processes that emit HAP's; the use of HAPcontaining substances; emission levels for HAP and surrogate pollutants (i.e., VOC 

for organic HAP's and PM for metal and other particulate HAP's); emission control 

device design and operation; monitoring and operation and maintenance (O&M) 

procedures for control devices; and generation and releases of other media such as 

wastewater and solid waste that are associated with the operation of air pollution 

controls for brick and structural clay products manufacturing processes. 

If the operating permit or application contains the same information requested 

in any part of this questionnaire, you may respond to the requested information 

by referencing the page or section of the permit/application to avoid 

duplication. If you reference your permit or application, you must supplement your 

response with all of the additional information requested in this questionnaire that is 

not included in the permit or permit application. If you prefer, you may submit the 

requested information from your pennit/application on a 3-1/2 inch diskette. 

B. If any source or emission unit at this facility is subject to a New Source Performance 

Standard or other Federal emission standard, please identify the source and 

applicable standard. Examples of applicable NSPS include 40 CFR 60, 

Subpart 000 - Standards of Performance for Nonmetallic Mfneral Processing 

Plants, and 40 CFR 60, Subpart UUU - Standards of Performance for Calciners and 

Dryers fn Mineral lndustries. 

:i ,.T• u_ t.., ' .•. ' •• •r@ .oT- ;. 5. v,•• ~ ro ~ • •• 

Inforination 

A. Please provide the 1996 production rates and the current production capacity for 

each type of brick and structural clay product manufactured (e.g., structural brick, 

clay sewer pipes, structural clay tile, etc.). Note that production data should be 

provided in units of tons per year (tons/yr). 

Product 1996 production (tons) Production capacity (tons/yr) 

Brick (fired weight) 315,600 tons 340,900 ton/yr 

Page 3 of 39 

;~ `t`Z 
Li 

B. Please provide the type and amount of each raw material and body additive used in 

1996 for manufacturing brick and structural clay products at your facility. Examples 

include clays, shale, and any additives that are mixed into the raw material prior to 

forming. Indicate additives by chemical compound, rather than by trade name. If 

the information requested is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than providing the information 

below. 

Raw material/body additive Amount used in 1996 (tons/yr) 

Cordova clay (wet weight) 9,700 

Albion Kaolin (wet weight) 13,300 

Bond Kaolin (wet weight) 9,600 

Shale (wet weight) 19,100 

Merry clay (wet weight) 354,300 

Sawdust (as received) 10,000 

Manganese ND 

Marble dust ND 

Fines ND 

C. If available, please provide a copy of the MSDS's for the raw materials and additives 

listed above. 

See Appendix A. 

D. If available, please provide chemical analyses, including fluorine, metals, and organic 

content, of the raw materials listed above. 

Not available. 

Page 4 of 39 

a~~ 
E. Using Table 1, please provide information on the consumption and HAP 

composition of all glazes and colorants that contain HAP's or HAP precursors and 

that your facility applies to brick and structural clay products. Indicate whether the 

coatings are glazes or colorants. Also indicate the type of product that the coatings 

are applied to and the total weight of coatings used in 1996. If the glazes or 

colorants are formulated at your facility indicate so and provide the production 

capacity. List each ingredient of the glaze or colorant. Beside each ingredient, 

indicate the total amount of the ingredient used in 1996. If the information requested 

in the table is contained in your facility's operating permit or permit application, you 

may reference the applicable sections of the permit (or application) rather than filling 

out the table. 

F. In the space below, please indicate any glazes or colorants used by your facility that 

do not contain HAP's and are substitutes for HAP-containing glazes or colorants 

used by your industry. Indicate which HAP-containing materials the non-HAP 

glazes or colorants replace. Describe any limitations on the use of those substitute 

glazes or colorants. 

None 

G. If your facility colors brick and structural clay products by flashing, please indicate 

the types of substances used to flash the products and the amounts of those 

substances used in 1996. 

Substance Amount used in 1996 Units (snecifvl 

Natural Gas Unknown - Not Measured Not Applicable 

Sawdust Unknown - Not Measured Not Applicable 

H. If available, please provide a copy of the MSDS's for the glazes and colorants used by 

your facility. If your facility prepares its own glaze, please provide any available 

MSDS's for the glaze imr-pdients. 

See Appendix A. 

Page 5 of 39 

,~2 q6 
TABLE 1. CONSUMPTION AND HAP COMPOSITION OF GLAZES AND COLORANTS 

Page 6 of 39 

otq7 
If additional space is required, please make copies of this page. If the information requested in 

the table is contained in your facility's ope ~ ;Fing permit or permit application, you may reference 

the applicable sections of the permit (or ap} `:. -:ation) rather than filling out the table. 

Page 7 of 39 

-z ~~ 
A. Please provide a simple process flow diagram for each brick and structural clay 

product manufacturing process line. An example process flow diagram is provided 

in Figure 1. A diagram of the plant layout with all processes and emission points 

clearly labeled is also acceptable. 

Assign a unique identification number (ID No.) for each process that has 

associated emissions (e.g., TK-1 for tunnel kiln no. 1) and each emission point. 

Please identify aU emission points, including those that do not emit HAP's. For 

emission points that are vented to an air pollution control device (APCD), assign an 

ID No. to the APCD (e.g., BH-1 for baghouse no. 1). For emission points that are 

uncontrolled, assign an ID No. to the uncontrolled stack (e.g., S-1) or building roof 

vent (e.g., RV-1). Use these same ID Nos. throughout the rest of the information 

request for any responses that pertain to any process or emission point. 

Page 8 of 39 

a~F 
Add Mix Clay Process - 

~ i ) 

Clay Storage Clay Unloading p Apron Feeder 0 Clay Crusher Clay Storage Clay Unloading Clay Feeder 

Bays (14) Bins (4) ~ 

q~ 

iI 

3 . 

Primary Side Raw Material Receiving 

, 

Clay Storage Clay Unloading Clay Clay 

Feeders (3) Crushers (6) 

Clay Grinder 

Clay Cage Mill 

Clay Shaker ~ 

Screens (8) 

Processed Clay Clay Loading Storage Bays(20) 

Clay 

Feeders (12) 

Plant 1, Shapes 

O 0 Pug Mill Feeders (2) Pug Mills (2) IFExtruders (2) Texturing (2) Shapes Hand-Set 

on Carts 

To Plant 3 or 5 

for Drying and 

Firing 

Plants 3& 5, Sand Preparation 

Rotary Coating To Sand Coating and 

Sand Storage Hoppers (3) Flow Bin Mixers (2) Bins (2) Texturing Plants 1, 3, 

(RM-1, RM-2) and 5 

Ground Base Bag Mix 

Caly Additives s 3 

~ Hopper Screening Hopper Fluid Bed Dryer 

Page 9 of 39 

---- ------- -- --- _. .~-- 

Boral Bricks Augusta Plants Process Flow Diagaram 

Plant 1, Clay Preparation and Shaping Process and 

Plants 3& 5, Sand Preparation Process 
Truck wfth Dry 

Processed 

Sawdust 

Fro m Processed 

Clay Storage or 

Shap(ng 

Process 

I Brick 

Ifor 

ent 

Boral Bricks Augusta Plants Process Flow Diagaram 

Page 10 of 39 Plant 3 

.~.~ ~ 
From Processed 

Clay Storage or 

Shaping 

Process 

Packaged Brick 

to Yard tor 

Shfpment 

(7 `; 

Truck wlth Dry 

Sawdust 

~ 

~ 

Page 11 of 39 

Boral Bricks Augusta Plants Process Flow Diagaram 

Plant 5 

-) , 2— 
B. Using Tables 2A and 2B, please provide current production rates, production 

capacities, and related information for each type of equipment used in brick and 

structural clay product manufacturing. In Table 2A, provide the requested 

information for only those sources that are known or expected to emit HAP's. In 

Table 213, provide the requested information for all thermal processing, such as 

drying and firing sources. For combustion sources that use difPerent fuels, Table 2B 

should be completed for each type of fuel. For example, if a kiln typically is fired 

with gas, but periodically is fired with oil, one column in Table 2B should be 

completed for the kiln when fired with gas, and another column should be completed 

for the same kiln when fired with oil. Provide the data in the units listed for each 

row. 

Page 12 of 39 

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The following notes are used in Tables 2A and 2B: 

NOTE 1 

Fugitive emissions occur at several points throughout this plant. Boral Bricks has no data on 

these emissions, and is not including fugitive sources per Feb. 25, 1998 telephone conversation 

between 011ie Fick (Consultant to Boral Bricks) and Bill Neuffer of the EPA. 

NOTE 2 

Except as otherwise indicated, Boral Bricks does not possess process-specific data that would 

allow estimates to be made of the types or quantities of HAPs contained in the materials or of the 

resulting HAP emissions. Sections 10.5, 11.3 and 11.19.1 of AP-42 provide generally available 

information on the pollutants that may be emitted from sawdust dryers, clay products processes 

and sand and gravel processes respectively. The AP-42 data are considered indicative of the types 

of HAPs thatmavbe emitted from processes at this plant but are not considered indicative of the 

quantities of HAPs emitted. 

Page 14 of 39 

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C. Using Table 3, please provide information on procedures used to monitor the 

process operating rate for each of the pieces of equipment and HAP emission 

sources listed in Tables 2A and 2B. Use the same HAP emission source types and 

equipment ID numbers you listed in Tables 2A to 2B. 

• Indicate whether you monitor process rate or not. 

• Provide a summary of process rate monitoring procedures that 

describes how process rate is measured for the particular piece of 

equipment. Include where the rate is monitored (i.e., rate of material fed, 

rate of material discharged, or material production rate), the units used to 

measure process rate (e.g., lb/hr or pieces/hr), and how the process data is 

recorded, i.e., manually, automatically (e.g., computer - printout or stored 

to disk, or not at all). If you monitor process rate at both the feed and 

discharge ends of the equipment, indicate so. 

• Indicate the type of monitor, equipment, or instrument used to measure 

process operating rate. 

Indicate the monitoring frequency or how offten process rate 

measurements are made. 

If instruments are used to measure process throughput, indicate in the 

monitor accuracy column the accuracy of the instrument. The monitor 

accuracy could be listed in terms of a percentage of the throughput 

(~ 1 percent), mass per unit time (t21b/hr), number of pieces per unit time 

(f 10 pieces/hr), or other appropriate units. 

• Indicate the frequency that the monitor is calibrated. 

• Provide data in the units listed for each row. 

Page 18 of 39 

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A. Use the process flow diagrams developed for your facility and Table 4 to provide 

the following information for each HAP emission source at your facility. 

• Define HAP emission source type in terms of equipment, such as dryers, 

kilns, ete. As in the process flow diagram, you may group multiple pieces of 

similar equipment. 

• Use the same equipment ID numbers indicated on the process flow 

diagram(s). 

• If the emission source vents inside a building or to outside ambient air without 

first passing through a control device, place a check mark in the uncontrolled 

column. 

• If the emission source vents inside a building or to outside ambient air after 

passing through a fabric filter, dry injection fabric filter, or scrubber, place the 

APCD ID number(s) in the column corresponding to the APCD type. 

• If the emission source vents through a control device type not listed in 

Table 4, indicate the control device type in the other control column and place 

the APCD ID number in the appropriate cell. 

• In the emission test data column, place a"yes" or "rio" in the appropriate cell 

to indicate whether the specific source has been tested for any pollutants, 

including any HA.P's, VOC, PM, or opacity. 

Page 22 of 39 

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B. Using Table 5, please provide information on stack parameters and emission estimates 

for each emission point at your facility that is known or expected to emit HAP's. 

Provide information for all APCD's, including those that exhaust inside the building. 

Include data for each inlet and outlet, if available, as indicated in the table. If you have 

more than one inlet to an APCD, provide data for each of the inlets. Provide data in the 

units listed for each row. 

Provide emission estimates for any HAP's or HAP surrogates, such as PM for metal 

HAP's or VOC for organic HAP's. Emission estimates may consist of ineasurements 

reported in emission test reports or may be calculated using mass balances, emission 

factors, engineering judgement, or other estimation methods. Provide the emission 

estimates as emission factors in units of lb of pollutant emitted per ton of product 

(lb/ton). Provide complete copies of any emission test reports or other reports that 

document measurements of emissions. Test reports and other emission 

measurement documents should include the following information: process 

identification; location of sampling point; stack diameter, temperature, and flow rate; 

test method, including analytical procedures; number of test runs; emission 

concentration, emission rate, percent oxygen, and percent moisture for each test run; 

process operating rate; type of APCD; and APCD operating parameters. However, test 

reports with incomplete documentation may still be useful and should also be 

submitted. 

You do not need to fill out Table 5 for emission points that are covered by an emission 

test report that is included in your submittal. If emission test reports are not 

available, provide calculations that support your emission estimate, including the 

basis for all assumptions in the estimate. Note that emission estimates are needed 

for all HAP's that the facility emits or has the potential to emit. (Please refer to the 

HAP list in Attachment 1.) If the information requested in the table is contained in 

your facility's operating permit, you may reference the applicable sections of the 

permit rather than filling out the table. 

Page 24 of 39 
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C. Using Tables 6A through 6D, please provide design and operating data for each 

APCD associated with all dryers, kilns, and any other brick and structural clay products 

manufacturing source that may emit HAP's. Use Tables 6A to 6C for specific types of 

APCD's. Use Table 6D for other types of APCD's. When using Table 61), please 

specify the type of control device and 2 to 4 key design or operating parameters for the 

device. Provide data in the units listed for each row. If the information requested in 

Tables 6A through 6D is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the tables. 

Page 31 of 39 

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D. Using Table 7, please provide the following information on current monitoring 

procedures for each of the control devices listed in Tables 6A to 61): parameters 

monitored (e.g., baghouse pressure drop), monitoring frequency, monitoring devices 

used (e.g., differential pressure transducer, thermocouple), and recordkeeping 

practices (e.g., manually recorded in log book, continuously recorded by electronic 

data acquisition system). Describe briefly other operation and maintenance (O&M) 

procedures for each control device. If the information requested in the table is 

contained in your facility's operating permit, you may reference the applicable sections 

of the permit rather than filling out the table. 

PIM906Mo 1 ' - M, e INUMM . : IM. 

A. Please describe all pollution prevention practices (i.e., process modifications, such as 

re-use of discarded or rejected materials, or any practice that prevents or reduces the 

amount of air emissions, or the generation and release of solid waste or wastewater 

associated with the operation of air pollution controls). If the information requested 

here is contained in your facility's operating permit, you may reference the applicable 

sections of the permit rather than providing the infonmation below. 

Page 36 of 39 

,;~ --;27 
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• ' 

A. Using Table 8, please identify all other processes or operations at this facility that are 

not addressed in Items II through VII above and that are potential sources of HAP 

emissions. Estimate total annual emissions of each HAP emitted by these collocated 

processes. If the information requested in the table is contained in your facility's 

operating permit, you may reference the applicable sections of the permit rather than 

filling out the table. 

Page 38 of 39 

~-~~ 
TABLE 8. ESTIMATED ANNiJAL HAP EMiSSInNS FRnM nTkF.R ~ nr rRCFc 

Process/emission source/SIC Code(s) HAP's emitted Estimated annual emissions, 

tons 

EXAMPLE: Mining 

SIC 

trace metals 

(Cr, Mn, Ni 

compoands). 

0.2 

Quality testing lab in support of brick 

manufacturing: A small quality control 

testing laboratory operation takes place 

at this plant but is not otherwise 

identified or reported in this ICR because 

there are no emissions data available. 

SIC 3251 

No Data No Data 

SIC 

SIC 

SIC 

If the information requested in the table is contained in your facility's operating permit, you may 

reference the applicable sections of the permit rather than filling out the table. 

Page 39 of 39 

~~~ 
APPENDIX A 

MATERIAL SAFETY DATA SHEETS 
-Pa-ge 1 OF 2 

MATERIAL SAFEIY DM SHEEr 

sEcrioN I iDan-EFiCATION OF PRODUCT 

ManaLfactLm-er f s Name: Merry Brothers Brick Emergency Telephcne Number 

A Division Of Boral Bricks INC. 404-722-6831 

Address (Number,Street, Cityp State, zip Code) C.A.S. No. 

P.O. Box 1957 (13) 

Augusta, GA. 30913 1332-58-7 

Chemical Name, Identity Merry Clay 

Chemical, Family, Pynonyrs, EIC. 

HYdrous aLluminun silicate-Silica 

S=ON II KUMUAL OR CCM¢'ONFN11 -t 

Formula 

Al203 2Si02 2H20 

T'rade Name 

Ver 

C. A. S. No. H.M..I.S. 

Clay/ Shale 50 - 75 11332-58-7 Health Hazard o 

Free Silica (Quartz) Si02 25 - 50 14808-60-7 Flarmrability Hazar o 

Reactivity Hazard 0 

Personal Protection t I 

SECrION III PHYSICAL DM 

Appearance and Odor: Tan Powder when anourd, Enthy Odor, Especially When Wet. 

Boi-ling Point(F): N. A. Specific Gravity (Water--1): 2.6. 

Vapor - Pressure (m Hg) N. A. Percent Volatile (By Volume): N.A. 

q. 

 N 

. .7apor Density' - EvaporationPate (Drtyl acetate=1 

Solubi1ity In . Water: . Insoiub1fi' - Evaporation Rate '(Ethyl6thei, A,= 

SECMON IV EXPLOSION.DATA 

FLish Point (Specify MeUlod) Flanimable Limits Ladex. 

..(Degrees"FWwer6_it);. on P e N 

FliW Ectirquishin-g Milia' lq ~ 'T -i 3. P", A 

1%C Uvi- "(X?, 

%"M;Re~i L 1 1Msa E:e 7 ,5t- ty at"a__qWj ._&_zrge,,to ,resporjsibl&q- 

-sut 16' • ;,e llt,at~jthgi Rdjr:eE_;X.F:TAlth6_x i the =-oir'4i::rar-110w]"~~ 44,-- V~ '- .. -1-'~..'e V.,.-10 F. u 

ooqtAixied ,~ , veibddhic WilOr-i from-: so i~to: - b&li'Viiid e ito' ;j5e' -,, reiliib1:o,!3. r 

ax-L 3 an ye kihd,-e--xp c _a.p a 
Paaae 2 of 2 

3, 

:17 

SECrION V HEALTH HkZAM DATA 

lffweshold Limit Value (TLV): 1.0 mg/M3 (ACGIH & OSHA) 

pend_ssable EVosure Limit - Tvtal Dist: , 3.0 mg/M3 (ACGIH) 

Permissable Exposure Limit - Re•pirable Dust: 1. 0 mg/M3 (OSHA) 

Route of Ehtry: Lmgs (Breathing) 

Effects of Overexposure: Prolonged Irihalation May Cause Lung Injury (SIMCOSIS) in 

scme cases. 

EYrergerlicy and Fu-st Aid Procedures: Wash dust fron skin with soap and water. 

Flush cut eyes with generous a=unts of water. 

SECrION VI REACrVM DAMN 

Stability: Unstable 140 Conditions to Avoid: N.A. 

Stable YES 

IncaTpatability (Material to Avoid): None 

Hazardous Decarposition Products: None 

Hazardous Polymerization Will not oocur. 

SECnON VII SPILL OR LEAK PFCCEDURES 

Steps to be, taken in case Material •is Released or SpiUad: Sweep up or VacLm and 

rexLse. : If Contamimted,"". in suitable. contairex 

Waste Disposal Mett-10d: MaY bs disPOsed Of in an aRx'Oved Ianiifill Fli6ility.--. in. 

)ordance with Applicable Federal,, State and Local Regulationd.. -~ 

....SECrION vii SPECIAL PRO INFOEVA0N T1 

Respiratory Prot on; ify;;Ype • ?ve dVcb 5r , 

1.4 

on.. 5-YeSD :. 

4j 4. Lz~ 

tt" WA Hm 

Gloves y-q Pii~~ aon:: -.0 ~ 

N'M - 

f-3. I ot I •- I x sp EC iW PRE c Auri oN s 

i7incJ:*,, 
f"N 

ot - 

In. 

Material Safe'QData SheeL 

7 

-Substance Identification • 

bW &DIOMDEr~;• CAS #: 1313-13-9 

TradeNamm Brickor, GranuSpcA' 

tr Manufacturer. • ThePrlj~6-Nlanuracturin CompAny 9 ti~er en 9 cr. Che' M CC

Oue Prince' P" 1-806-4 -24 -9300 

OuLncy, 

217-=-n% 

'Components and Contaminants 

Chemical Na-me CAS # OSHAP ACGrK TLV P;rcen 

MangaDese Compound (as W) 7439-96-5 5 m-,Jml (c) 5 mglml (c) 51-55% Ma 

Iron Oxide 1309-37-1 — 1-5% 

Fe, 

0

SiUca, CrystaMne Quartz (respirable) 14WS-60-7. 3 0 o ~ IM3 0. 1 mg/m3 (IWA) 1-5% si 2 Aluminwn Oxide (non-fibrous) 

M3 (respinble fractioa) 1344-28-1 15 mg/m'('I'A) 14% AIsO, 

Barium Oxide 1304-28-5 02-2% BaO 

Physical Data 

BoWng Point NA Spedfic Gravity ~I.O = 1): 5.0 

Vapor Prewwc (mm/Hg): NA Melting Point (Decomfos c") 53Y C""'.- 

Vapor Density (Air = 1): NA Evaporation Rate (Bury 

A e 

Acetate %;1): NA 

SolubMty in Water. 

Appearance and Odw. black to brownish black, no odor 

Fire and Explosion Hazard Data 

Flash Point: Not conibuttible 

Flammable Llmitsi* LEL NA 

ir 

EA:tingiishiag Media. Foarm, CO., or dry chemicaL 

Special Fire F4hting Procedur= In the eveat of fire, wtu full protective clqthing and NIOSH-approved seLfcontained breathing apparatus with fuU fice piece operated in the pressure 

demand or other positive pressure mode. 

Unusual Fire and explosion hazards. Not combust•bte, but substance is a strong oxidizer and its heat of reiction wU 

reducing agents or combusti'bles may cause ipitioiL Increase-s the flammabWq of any combustllc substance. 

Reactivity Data. 

Stabilit)r Stable under ordinary concfidons of use and storage. .1 

Conditions to avoidL Do not heat or grind in the presence of easily oxidizable substa&es or organic 

IncompatlbWq (materials to avoid): 

matter. 

EasUy oxidizable substances, sulfur, sulrid'ei, 'phosphides, hydrophosphides' 

J:;:: chlorates, peroxides, aluminurn powder, rubidlum'acetyii4e, potassium azide, 

chlorine trifluoride. Reacts with hy4roc!49ric acid to form coftosive chlorine 

gaL 

Han dous Decomposition or Byproducts: Upoa beating it decomposes to'form imangan' " cs-esquioxide and oWa which 

facxlitates combustion. .7 -; Ltj 

HazardousPolymerization:. vrlu not occur. 

Manp , = Dicr! ' , pa;t I 
Health Hazard Data 

Route of Entry: iNNA1aTION: May irritate the respiratory tracL May cxrcase the incddence 

of upper respiratory infectioas (pneumonia). Prolonged aposure to u7ica dust" 

_. __.. may result in silicosis, a fibrodc lung distase. _._-, ... ,.... 

~ SKIN: May cause irritation. _... _ 

INGESTION: May cause abdominal pain and nausea. 'sfanganese dioxide 

dust is poorly absorbed through the gut. 

Health I-iaaatds (Acute and Chronic): Chronic exposure and inhalation of excessive manganese dn_st may cause d'u- . 

-- - - --- - - - - . - --- orders of the central nervous system. - - 

Carc3nogenidty: NTP: No IA.RC Monographs: Yes (30ica) 

Signs and Symptoms of Exposure: Early symptoms of manganese toxicity include slugg~shncss, aleepincsa, aad, ::: .. • 

- weakness ia legs. Symptoms of silicosi.s incl de impaired palmonary funcdoa ._--. -. . 

and wheea.ng. . 1~ . . 

Aggravation of Pre-existing Conditiou.s: Persons with impaired respiratory function may be more susceptible to the effect of this subscance. 

Emergenry and First Aid Procedures: IF LNHALED, remove to fresh air and seek medical attencioa for any breathing 

difficulty. , 

_ IN CASE OF SKIN COi`ITACT, wash with soap & water. Seek medical atten- 

~ tion if red & irritated. 

LY CASE OF EYE CONTACT, flush eyes immediately ocich water for at least 

15 minutes. Seek medical attention if imtation persists. 

IF INGESTED, induce vomiting immediately by giving tsro glasses of water 

and sticking finger down throat. Never give anything bp moath to an uncon- 

. sdous person. Call a physicdaa immediately. 

_ Precautions for Safe Handling and Use 

Material Release or Spill Precantions: Should a spill occur, venti7ate area. Clean-up personnel require respiratory 

protection. Recover uncontaminated material for use. Vacuum or sweep 

•... -, remaining material, keeping dust to a minimum.• Isolate vtt material from dr' 

^ ; , .;,: : , : : • , 

~Waste Disposal Method: 

and store aaray fiom combusti'ble materials. t 

Dispose of unreclaimable material in a RCRA-approved aaste faciIity. ;~.r:;; 

radling and Storing Precaution.s: Manganese dioadde is dassified as an oAdizer and shoald be stored in a dry 

~ _- ------ ----- `- - 

place away from combustibles and sources of high heat. Protect containers 

from damage and keep closed w6en not in use. - 

Other Precautions: -- -- --- - Observe good personal hygiene. Wash aher handling. - ~=- 

: 

A

- 

- Control Measures : 

Respiratory Protedion: ::,: . Use NIOSH approved particulate respirator if dust gmsation occurs or is 

_ ,,.,, .;; ;;:.::,;;;, •, .,,; ;:,,; anticipated. USBM approved schedule 21B respiratot or equal is recommended. 

,VentY'lation: A system of locai and / or general exizaust ia recommendad to keep employee 

.; ;,;;.; :: ;; ,1t;t,.;: ~ ;.i .• ; exposures below the Airborne Exposure Limita. Local ezbaust is generally 

preferred because it can control tbe emissions of the contaminant at its 

source, preventing dispersion of it into the general work area. Please refer to 

the ACGIH document,'Industrial Ventilation, A Manaal of Recomniended 

Pradices', most recent edition, for detat7s. _. • - 

Protective Gloves: .. . - .. . Yes _d~ Z 

Eye Proteciion: wi:, Safety goggles are recommended. 

Other Protedive Clothing or Equipment: Use other protective equipment whea necessary ia order to avoid prolonged 

: c:••,.L~. ,:':r ~ ~ ::;~ ~ ,. :.; X:`M;t:.. exposure to skin. 

_Work and Hygienic Practices: Observe good persoaal hygiene. Wash after handling. 

~;f "i "C ' • • • • 

SARA Title III Section 313 Supplier Notification 

This product'contains the fonowing toxie chemicals subject to the reporting requirements of section 313 of the Emergency 

Plaaning and Community Right-to Know Act of 1986 and of 40 CFR 372.45: = e ~ 

CAS # 7gby Weight . 

Mangaaese Dioxide 1313-13-9 51- 55% Ma 

'aslum Oadde 1344-•23-5 0.1- 1.8% Ba ' 

_his inforaation must be included in 3!1 titSDS's tbat are coricd ar.d dis.ribu:cd for th's m3terial. 

N(l=;:_cc Diocde. Page 2 

July 1991. 

,~~ • 
The T1111beI'llll',Il, Yiie 

Materiai Safety Data Slieet 

TRADE NAME Wood Dust 

SYNONYMS None 

CAS. NO. None 

DESCRIPTION 

Particles generated by any manual or mechanical cutting or 

abrasion process performed on wood. 

PHYSICAL DATA 

Boiling Point ........................ Not Applicable 

Specific Gravity ..................... Variable (Dependent 

on wood species and 

moisture content.) 

Vapor Density ........................ Not Applicable 

% Volatiles by Vol ................... Not Applicable 

Melting Point ........................ Not Applicable 

Vapor Pressure ....................... Not Applicable 

Solubility in Water (% By Wt.)....... Insoluble 

pH................................... Not Applicable 

Appearance and.Odor .................. Light to dark 

colored granular 

solid. Color and 

odor are dependent 

on the wood species 

and time since dust 

was generated. 

FIRE AND EXPLOSION DATA 

Flash Point .......................... Not Applicable 

Autoignition Temperature ............. Variable (typically 

400 - 500• F) 

Explosive Limits in Air .............. 40 grams/m' (LEL) 

Extinguishing Media .................. Water, CO„ Sand 

Special Fire Fighting Procedures..... Use water to wet 

down wood dust to 

reduce the 

likelihood of 

ignition or 

dispersion of dust 

into the air. 

Remove burned or-wet - 

- - dust to open area 

after extinguished. 
Inhalation.............................. May cause nasal 

dryness, irritation 

and obstruction. 

Coughing, wheezing 

and sneezing; 

sinusitis and 

prolonged colds 

have also been 

reported. 

Chronic Effects ......................... Wood dust, depending 

• on species, may 

cause dermatitis on 

prolonged, 

repetitive contact; 

may cause 

respiratory 

sensitization 

and/or irritation. 

Prolonged exposure 

' to wood dust has 

been reported by 

some observers to 

be associated with 

nasal cancer. Wood 

dust is not listed 

as a carcinogen by 

IARC, NTP, ACGIH or 

OSHA. 

REACTIVITY DATA 

Conditions Contributing ................. Stable under normal 

to Instability conditions. 

Incompatibility.......................... Avoid contact with 

oxidizing agents 

and drying oils. 

Avoid open flame. . 

Product may ignite 

at temperatures in 

excess of 400°F. 

Hazardous Decomposition ................. Thermal oxidative 

Products degradation of 

wood produces 

irritating and 

toxic fumes . and 

gases, including 

CO, aldehydes and 

organic acids. 

Conditions Contributing to ...........::. Not Applicable 

Polymerization 

~ 7 
Unusual Fire and Explosion Hazard....... Wood dust is a. 

strong to severe 

explosion hazard 

if a dust "cloud" 

contacts an 

ignition source. 

HEALTH EFFECTB INFORMATION 

Exposure Limit .......................... ACGIH TLVM: 

TWA - 5.0 mg/m s ; 

STEL(15 min.) - 10 

mg/m3 (softwood); 

TWA - 1.0 mg/ms 

(certain hardwoods 

such as beech and 

oak) 

1 See footnote below concerning OSHA PEL: 

OSHA PELs for wood dust TWA - 5.0 mg/m3 ; 

STEL (15 min.) 

- 10 mg/m3 (all 

soft and 

hard woods, except 

Western red 

cedar) ; 

Western red cedar: 

TWA - 2.5 mg/m3 . 

Skin and Eye Contact ..................... Wood dust can cause' 

eye irritation. 

Various species of 

wood dust can 

elicit allergic 

contact dermatitis 

in sensitized 

individuals. 

Ingestion ............................... Not Applicable 

Skin Absorption ......................... Not K,nown to Occur 

1 Although OSHA's Air,-,^ontaminants Rule, including OSHAts 

wood dust PELs, was struck down in AFL-CIO v: OSHA, 965 F. 2d 962 

(i1th.Cir. 1992), a number of states have incorpor.ated those 

provisions in their state plans. Additiomally, OSHA has 

announced that it nay cite companies under the OSH Act general 

duty clause ur.der aopropriate circumstances for non-compliance 

with these levels. 
PRECADTIONB AND BAFE HANDLING 

Avoid eye contact. 

Avoid repeated or prolonged contact with skin. Careful 

bathing and clean clothes are indicated after exposure. 

Avoid prolonged or repeated breathing of wood dust in the air. 

Avoid contact with oxidizing agents and drying oils. 

Avoid open flame. ' 

GENERALLY APPLICABLE CONTROL MEASUREB 

Ventilation: Provide adequate general and local exhaust 

ventilation to maintain healthful working 

conditions. 

Wear goggles or safety glasses. Other protective equipment such 

as gloves and approved dust respirators may be needed depending 

upon dust conditions. 

EMERGENCY AND FIRST AID PROCEDIIRES 

Eyes........ Flush with water to remove dust particles. If 

irritation persistis, get medical attention. 

Skin........ If a rash or persistent irritation or dermatitis 

occur, get medical advice where applicable 

before returning to work where wood dust is 

present. 

Inhalation.. Remove to fresh air. If persistent irritation, 

severe coughing, or breathing difficulties 

occur,.get medical advice before returning to 

work where wood dust is present. 

Ingestion... Not applicable 

BPILL~[,LEAR CLEAN IIP PROCEDIIREB_ 

Sweep or vacuum spills for recovery or disposal; avoid 

creating dust conditions. Provide good ventilation where dust 

conditions may occur. Place recovered wood dust in a' 

container for proper disposal. 

IMPORTANT : The information and data contained herein are 

believed to be accurate and' ~5i`ave been compiled from sources 

believed to be reliable. It is offered for your consideration, 

investigation and verification. AF&PA makes no warranty of any 

kind, express or implied, concerning the accuracy or completeness 

of the infornation and data herein. AF&PA will not be liable for 

claims relating to any party's use of or reliance on information 

and data contained herein regardless of whether it is claimed 

that the infornation and data are inaccurate, incomplete or 

otrerwise misleading. 

~~f 
Wood Dust IIacacd Labc:l 

Caution! 

Wood Dust 

(For all Untreated Wood and Untreated Wood Products) 

Sawing, sanding or machining wood products can produce wood dust 

that can cause a flammable or explosive hazard. 

Wood dust may cause lung, upper respiratory tract, eye and skin 

irritation. some Wood species may cause dermatitis and/or 

respiratory aller.gic effects. 

* Avoid dust contact with ignition source. 

* Sweep or vacuum dust for recovery or disposal. 

* Avoid prolonged or repeated breathing or wood dust in air. 

* Avoid dust contact with eyes and skin. 

* First Aid: In case of contact, flush eyes and skin with water. 

If.irritation persists, call a physician. 

For additional information, see the Wood Dust Material Safty Data 

Sheet. 

THE TIlVLBERMEN, INC. 

P. O. BOX 107 

CAMAX GA 30807 

(706) 465-3506 

~J~ 
.._.. . .... .. 

S 

MATERIAL SAFETY DATA SHEET 

Page: 1 

Date Prepared: October 18, 1993 

PRODUCT NAME 

OCHRE 

1. CHEMICAL PRODUCT AND COMPANY-=IDENTIFICATION 

Product Identifier: Ochre 

CAS No.: 1343-81-3 

General Use: Pigmenting Agent 

Product Description: Natural Iron Oxide, N548 Ochre, #404 Ochre, /808 Ochre 

MANUFAC'TURER: NEW RIVERSIDE OCHRE COMPANY, INC. 

P. O. Box 460 

Cartersville, Georgia 30120 

Contact: Mary Nell Miller (404) 382-4568 

2. COMPOSPTION/INFORMATION ON INGREDIEN'TS 

- 

~~.. .._.. _ - 

Ocl~reis go

.

ethite, a naturally occurring inorganic iron oxide. Componoats preseat at levels greater than 

196 are: 

Wt. % CAS Registry ,i! 

HFe01 52-63 1310-14-1 

Si0= 20-29 14808-60-7 

Ma0= 1. 54.0 1313-13-9 

3. HAZARDS IDENTIFICATION 

EMERGENCY OVERVIEW: 

... Poses little or no immediate bazard. Not absorbed by the body. 

OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200): 

EXPOSURE LIMITS 8 Hrs. TWA 

OSHA-PEL ' ACGIH TLV 

RESPIRABLE DUST TOTAL DUST 

(TABLE 2) (1991-1992) 

SiO; 0.1 mg/m' 0.1 mglm3 

,~7- 7l 
Page: 2 

Date Prepared: October 18, 1993 

POTENTIAL HEAI.TI-i EFFECTS: 

IIv'HALATION: lahalation of the dust may cause mechanical irritation to the respiratory tract. Excessive 

exposure above the TLV can give mild pulmonary irritation. Long term over-exposure to silica causes 

silicosis. 'Riis product is considered a carcinogen by IARC because it contains crystalline silica at levels 

greater than 0.196. 

EYE CONTACT: Will result in no specific effects other than general particulate irritation in the eye. 

SKIN CONTACT: Not absorbed by the body. Skin contact may cause mechanical irritation due to 

abrasion. 

INGESTION: Not absorbed by the body. 

CHRONIC: See INHALATION above. " 

4. FIRST AID MEASURES 

INHALATION: Remove victim from the area where TLV has been exceeded. If victim not breathing, 

give artificiai respiration. Call a physician. Remediate work area as described in Section S. 

EYE CONTACI': Flush eyes with large amounts of water until irritation subsides. If irritation persists, 

get medical attention. 

. J 

SIQN CONTACT: Wash with soap and water. Get medical attention if irritation develops. 

IIr'GESTION: If conscious, give large quantities of water to induce vomiting. Get medical attention. 

S. FIRE FIGHTING MEASURP,S 

FLASHPOINT: Non-flammable. 

EX'I'IIdGUISHING MBDIA: As appropriate for sursounding combustibles. Product does not bum or 

support combustion. Not a fire or explosion haurd. 

FIRE FIGHTING EQUIPMENT: Respiratory and eye protection roquired for fire fighting personnel. 

6. ACCIDENTAL RELEASE MEASURES 

GENERAL: Refer to local, state, or federal regulations for specific disposal information. Pursvant to 40 

CFR Part 261 of the Resources Conservation and Recovery Act (RCRA) regulations currently in effect, 

discarded iron oxide would not be classified as a hazardous waste. 

LAND SPILL: Vacuum or scoop up spilled material for recovery or disposal, avoid dusting conditions 

and use good ventilation. Wetting the spill area with water spray may help to keep airbom dust levels 

down. 

WATER SPILL: Product is inert and stable. Decomposition and polymerization will not accur. ` 

~~J" Z 
Page: 3 

Date Prepared: October 18, 1993 

7. HANDLING AND STORAGE 

STORAGE TEMPERATURE: Ambient STORAGE PRESSURE: Atmospheric 

GENERAL: Mainta; i packaging intact until ready for use. See Section S. 

8. EXPOSURE CONTROL/PERSONAL PROTECTION 

ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering 

controls to control airbom levels below recommended exposure limits. Provide mechanicai ventilation of 

conflned spaces. 

PERSONAL PROTECTION: 

Eye Protection: Safety glasses or dust tight goggles. 

Skin Protection: Rubber, cloth, or plastic gloves if appropriate for job conditions. 

Respirator: If exposure limits are excerded and appropriate NIOSH dust respirator should 

be used. 

9. PHYSICAL AND CHEMICAL PROPERTIES 

Specific Gravity (Absolute): 3.5 

Solubility in Water: <0.556 

PH/10% Solution: 8.5 

Average Particle Diameter (Microns): 2 

Bulk Density - Loose/Lbs. Cu. Ft.: 55 

Odor: None 

Appearance: Solid Yellowish/Brown Powder 

10. STABILITY AND REACTIVITY 

GENERAL: 'Iliis product is stable and hazardous polymerization will not occur. 

INCOMPA'IEBLE MATERIALS AND CONDTTIONS TO AVOID: None 

HAZARDOUS DECOMPOSITION: None 

11. REGULATORY INFORMATION 

DISPOSAL: Natural iron oxides are not harardous wastes per 40 CFR 261.24 or 261.3. However, the 

user should consult with the state environment regulatory agency before disposing of this material. 

SPILL REPORTING: Natuaal iron oxides are not CERCLA hazardous substances, per 40 CFR 301.4. 

These are not on the list of harardous substances under the Clean Water Act (40 CFR 116 and 40 CFR 

117), nor are they included on the list of Extremely Hazardous Substances under SARA, 40 CFR 355 

~ Appendix A. Thus, there are no Federal reporting requirements in the event of release of these materials. 

~~~ 
Page: 4 

, Date Prepared: October 18, 1993 

SARA REPORTING: Natural iron oxides are not subject to the reporting requirements of Section 304 of 

SARA, since they are not Extremely Hzzardous Substances. In addition, these iron oxides are not subject 

to the reporting requirements of Section 313 of SARA. However, due to the presence of up to S 96 silica - 

quartz, natural iron oxides are regulated as mixtures under the reporting requirements of Sections 311 and 

312 of SARA. 

12. MANUFACTURERS CONTACT REPRESENTATIYE 

Mary Nell Miller 

(404) 3824568 

-'Ihis information is furnished without wananty, expressed or implied, except that it is accurate to the best knowledge 

of New Riverside Ochre Company. lnc. and New Riverside Ochre Company, lnc. assumes no legal responsibility 

for use or reliance upon the information presented. 

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Material Safety Data Sheet 

AMERICAN MINERALS PRODUCT: 

901 EAST EIGHTH AVENUE, P.O.BOX 1569 

KING OF PRUSSIA, PA 19406 MSDS: AMCHROMITE 

Phone: Health & Safety Info 215/337-1100 Date: 1/4/90 

Revision: 12/92 

HEALTH HAZARD 2 - Moderate 

FLAHMABILITY HAZARD 0 - Minimal 

REACTIVITY HAZARD 0 - Minimal 

PERSONAL PROTECTION B- Glasses & Gloves 

National Paint 

and Coatings 

Association 

Hazardous Material 

Identification 

System 

SECTION I. MATERIAL IDENTIFICATION 

Chemical Name: Chromite 

Common Names: Chrome Ore, Chromite, Chromite Ore, Iron Chromite, Iron Chromite Ore 

Description: Chromite is a mineral composed of a natural oxide of ferrous iron and 

chromium, with varying amounts of magnesium and aluminum substituting for the iron and 

chromium respectively. It has the general formula of (Fe,Hg)O•(Cr,Fe,Al) 203 . 

CASf: 1308-31-2 

Distributor: American Minerals Phone: 215/337-1100 

SECTION II. INGREDIENTS AND HAZARDS 

Ingredient Name: CAS Numbers Percent: Exposure Limits: 

Chrome Ore 1308-31-2 100 For Chromium (III) Compounds 

as /Cr/ ACGIH TLV:TWA is 

0.5mg/m3 . This would equate 

to a chrome ore dust exposure 

of 1.62mg/m3for a chrome ore 

containing 45% Cr203 . OSHA 

Typical Chemical Analysis, Wt.t PEL:TWA for Chromium (III) 

Si02 1-5 Compounds Final PEL 0.5mg/m 3 . 

Fe0 15-25 FOR ORE PROCESSING - ACGIH 

A1 03 10-20 TLV:TWA - 0.05mg/m . For ore 

Mg~ 10-20 processing, chrome ore is 

Ca0 0-1 listed as a Human Carcinogen. 

Cr203 35-45 

The oxides shown in the "Typical Chemical Analysis• do not exist as free, uncombined 

oxides, but exist in complex mineralogical combinations. 

I SECTION III. PHYSICAL DATA I 

Appearance and Odor: Chrome ore is'usually bl•ack, but does show some variation from 

iron-black to brownish black with some brown streaks. Various grades can vary from 

large pieces down to fine powders. Chrome ore is odorless. 

Apparent Density: 4.3 - 4.5 g/cc. (37 lbs/gal) 

Water Solubility (t): O, Insoluble in Water 

Melting Point: >3400°F 

% volatile by volume: 0 

_ Page 1 --- MSDS continues on page 2 --- Page 1 

3or 
Material Safety Data Sheet 

A1IERICAN MINERALS PRODUCT: CHROHE ORE 

901 EAST EIGHTH AVENUE, P.O.BOX 1569 

KING OF PRUSSIA, PA 19406 MSDS: AHCHROHITE 

Phone: Health & Safety Info 215/337-1100 Date: 2/14/92 

Revision: 12/92 

I SECTION IV. FIRE AND EXPLOSION DATA I 

Extinguishing Media: Chrome ore is not combustible. Use extinguishing media appropriate 

to combustibles in the surrounding area. 

Unusual fire or explosion hazards: None 

Hazardous decomposition Products: None 

I SECTION V. REACTIVITY DATA I 

Stability: Chrome ore is an inert and stable mineral. Hazardous polymerization will not 

occur. 

Chemical incompatibilities: Chrome ore can react at high temperature with molten 

alkalies and alkali vapors forming water soluble chromium salts. 

Storage: Chrome ore is stable under all normal conditions of storage. 

I SECTION VI. HEALTH HAZARD INFORMATION I 

Summary of risks: Exposure to chrome ore presents a low order of risk. The primary 

health hazard is the excessive inhalation of dust generated during handling operations. 

health hazards such as: hexavalent chromium compounds produce a corrosive action on any 

skin and mucous membranes they contactp chromite salts are human and experimental 

carcinogens of the lungs, nasal cavity and paranasal sinus, and are also experimental 

carcinogens of the stomach and larynx; the hexavalent (VI) chromium compounds are more 

toxic than the trivalent (III) compounds. Eczematous dermatitis has been reported for 

some trivalent chromium compounds. A competent industrial hygienist should be consulted 

for evaluation of potential health hazards associated with specific chemical processes 

involving the use of chrome ore. 

Nedical conditions which may be aggravated by contact: The excessive inhalation of 

mineral dust may aggravate pr.e-existir.g chronic lung'conditions such as, but not 

limited to, bronchitis, emphysema, and asthma. 

Target organs: Upper Respiratory System 

Primary entry route: Inhalation 

Acute Effects: The excessive inhalation of mineral dust can cause a transitory upper 

respiratory irritation. 

Chronic Effects: The chromitl:n in chrome ore i.g in the trivalent (III) form. Trivalent 

Chrome oxide (Cr203 ) is repvrted tb have a low order of toxicity. The IARC - Cancer 

Review: Animal - Inadequate Evidence. Chrome ore is listed as a human carcinogen in ore 

processing. 

Page 2--- HEaI.TH HAZARD INFORMATION continues on page 3 --- Page 2 

3~'~z 
Naterial Safety Data Sheet 

AMERICAN HINERALS PRODUCT: CHROME ORE 

901 EAST EIGHTH AVENUE, P.O.BOX 1569 

KING OF PRUSSIA, PA 19406 MSDS: AMCHROt•tITE 

Phone: Health & Safety Info 215/337-1100 Date: 2/14/92 

Revision: 12/92 

I HEALTH HAZARD INFORHATION continued from page 2 1 

Signs & symptoms of overexposure: 

Eye contact: Physical Irritation 

Skin contact: Possible irritation from repeated or prolonged contact to 

individuals sensitive to mineral dust. 

inhalation: Upper respiratory irritation. 

First aid: 

Eye contact: Flush eyes, including under the eyelids, with large amounts of 

water. If irritation persists, seek medical attention. 

Skin contact: Wash with mild soap and water. 

Inhalation: Remove to fresh air. 

Ingestion: No data available. 

SECTION VII. SPILL, LEAK AND DISPOSAL PROCEDURES 

Spill / Leak procedures: 

Chrome ore is unreactive and insoluble in water and acids. Reuse all spilled 

material whenever possible. Thoroughly cleanup spilled material and place into a 

suitable container, being careful to avoid creating dusty conditions. If conditions 

warrant clean-up personnel should wear approved respiratory protection, gloves, and 

goggles to prevent irritation from contact and/or inhalation. 

Waste management / Disposal: 

Chrome ore is not biodegradable, and does not exhibit any characteristics of a 

hazardous waste. It is insoluble by EPA's SW-846 TCLP methodology. It is suitable 

for landfill disposal. However, used debris containing chromium must be evaluated 

for the Characteristic of Toxicity to determine the method of disposal. Follow all 

local, state and federal regulations for proper disposal. 

I SECTION VIII. SPECIAL PROTECTION INFORMATION I 

Personal protective equipment: The use of safety glasses, gloves, and long sleeve 

clothing is recommended. 

Workplace Considerations= 

Ventilation: 

Provide adequate general ventilation and local ventilation in both sufficient volume 

and air flow patterns to keep air contaminant concentration levels below allowable 

limits. 

Page 3--- MSDS continues on page 4 --- Page 3 

jU•j 
Material Safety Data Sheet 

AMERICAN MINERALS PRODUCT: CHROME ORE 

901 EAST EIGHTH AVENUE, P.O.BOX 1569 

KING OF PRUSSIA, PA 19406 MSDS: AMCHROMITE 

Phone: Health & Safety Info 215/337-1100 Date: 2/14/92 

Revision: 12/92 

I SECTION IX. REGULATORY INFOR.MATION I 

SARA TITLE III INFORMATIONi 

The product is 100% chrome ore CAS11308-31-2, which is composed of up to 42s Chromium 

and reportable under SARA TITLE III Section 313. Chrome ore is included because of 

definition given in 40 CFR Ch.l Part 372.65 on chromium compounds. Chrome ore is not 

listed under SARA TITLE III Sections 302 and 304. 

TSCA INVENTORY: 

Chrome ore is listed on the chemical Substance Inventory of the Toxic Substances 

Control Act (TSCA). 

DOT Class: Not Regulated 

SECTION X. REFERENCES 

Sax, N. Irving: Dangerous Properties of Industrial Materials, Seventh Edition, Van 

Nostrand Reinhold Co., Inc., 1989. 

Kirk, R. and Othmer, D., Encvclopedia of Chemical TechnoloQY, Third Edition, WileyInterscience, New York, NY 1980. 

Clansky, K.B., Suscect Chemicals Sourcebook, 1992-2 Edition, Roytech Publications, 

Bethesda, Maryland. 

Sax, N.Irving and Lewis,R.J. Hawlev's Condensed Chemical Dictionarv, Eleventh Ed., Van 

Nostrand Reinhold Co.,Inc., NY 

I SECTION XI. ACRONYMS/DEFINITIONS USED IN THIS MSDS I 

ACGIH: 

CASif: 

IARC3 

mg/m : 

NFPA: 

OSHA: 

PEL: 

SARA: 

Title III: 

Section 302: 

Section 304: 

. Section 313: 

TC Rule: 

TCLP: 

TLV: 

TSCA: 

TWA: 

American Conference of Governmental Industrial Hygienists 

CAS Registration Number is an assigned number to identify a 

material. CAS stands for Chemical Abstract Service. 

International Agency for Research on Cancer 

Milligrams per cubic meter 

National Fire Protection Association 

Occupational Safety and Health Administration 

Permissible Exposure Limit (OSHA) 

Superfund Amendments and Reauthorization Act 

Emergency Planning and Ccmmu:iity Right to Kr.ow Act 

Extremely Hazardous , Substances ~ 

Emergency Release 

Toxic Chemicals - Reporting 

Toxicity Characteristic Rule 

Toxicity Characteristic Leaching Procedure 

Threshold Limit Value (ACGIH) 

Toxic Substances Control Act 

Time Weighted Average = 8 hours 

Prepared/revised by: A.G.Nighswander, December 9, 1992 

Although reasonable care has been taken in the preparation of the information contained 

herein, American Minerals extends no warranties, makes no representation and assumes 

no responsibility as to the accuracy or suitability of such information for application 

to purchaser's intended purposes or for consequences.of its use. 

` Page 4 --- End of MSDS --- Page 4 

3~ ~ 
I 

s 

. ~ 

.I 

., 

i 

--~ 

I 

~.uuv- ruX,l TO 82-14247241369 P.02 

_ •s . 

; • - ` . 

ftIl1 IXkRWa OaCp11" 

, 

BsCtion Y ~ produot,Iftttification 

Ths Godrqia Xarblo Comisany 

1201 Robsrts $oulevArd 

Huildirbg loo - 

Xemdsaw. GeOrqia 30144-3619 

FSdSryarncy Taiophono: (404) 421-6557 ~ 3tannath .J. Maake 

Rf sk D4ansq.r ~ 

Chomiatil Name: CalciWa Cdrbonata 

Chamiaal Familys 2ssrblat Limtstonot Dolamit• 

G9 Numbers 471-34-1 

Trade Name t Plus 5 A r-a/ sBectiors 11 - Has<ardous Znoradiant,s 

~.~.~.. 

ggsardous Matorials

__ 

Idantifiaation ey st em. 

Haalth Hasard 0 

!'lasmaability xazarQ 0 

Raactivitiy Hazard o 

Pernonal Frotaction s 

Hazard_.. Inci.dilats TLV L,x•qL: 

6ilioa, Quarts 

calcium CArborato Dust 

.1 (Rospirabls Dust) 

30 (Nuisanc• Du*t) 

Calaium Caxiborvate may cantain crystallina silica at lwe3.e 

bstwson 0,01% arld i.M anQ varies natvrally. 

7*ha" ara algo small but datactabl• amounts of ths follovis7q 

othar naturally occurrinq aheastioals thaC are knawn to tha 

etata of Caiifornia to cauoa aatioer, birth dafsats or otbar , rteproduativo harm. Rhis warni.nq is pxroviaed in the absonca 

of definitivs tvsting to provo that theao ri.sks do tsot 

oxist. Thoso amounta aro typical 4uantitiss and may vary 

r aliqhtly With differant lots. 

Ciiamir,al xame TYOieai Amount.' Ca$ Numbar 

llraenia Lesa then lppm 7440-38-1 

Lsad - Lises thaxt ippm 7439-92-1 

~ 

3~~ 
^ JLN-0'7- i 99 i i 1 1 36 FRah1 GA MARgLE - CORP tW TO 82-14847241369 P.03 

-

a .. 

saation ZZI - 

~aranca ar ~d odor: 

soilinc Points K/~1 

Vapox Pressurss N/A 

Vapor Densitys N/A 

solubility in 14ater: 

phyAica]JChemical charactQriatics 

Fins, 4Ih.l.te Fowdsr s No Odor 

Specitic aravity: 2.71 

I'Vaporation Ratet N/A 

sIiqht rsalttin4 Point: s ~lN/a 

~ 

gaGtion i~V -Fire and Sxplosion Na$a -rd DatA 

Flash Points N/l► 

llammabia Limits: it/A 

Firs Exti.nqvishirig Xedia: N/A , 

spaciai Firs Fi9htinq Frocsdursas Nona 

unugual Fira and bcploeion Hazardss Norie 

sootl.on _9 - RaaotiYa Data 

- 

Thia material is stable. 

Thi ~s~matiriiitwill~ot polyim~iriso „g ac ~'ds to libarats carbon dioxide. 

Muardous Deacartposition Sy-Produ.atat Hons 

_ 

SActian VI - 8salth llaaard Datta 

Calcium Carbonata is riot ott ths N. T. P. , Io A. R. C. , or OM 

liats of aarairoqans. CrYtitaliina sil icaa tracs caupo nant 

cara 

CaloiumtCax'kvna►ts

imettital animals 

listod 

 ha~ d

ia~ti aa 

limit~ oevidance st~ caroinoqQnicity to humana, howsvs~r, wc has dat.srmised that ths caroirncgenioity to humans is 

naither cartaitt or provar:. 

Pmlonqed rspsatod it>hAlation of ox~ystal-line siiica oan 

vausm sillposis, a norlaancerma lurjq diasaso. 

ESCDOsure: 

Inhalation: 

b'y~ tbntaat ~ 

• gk.in Coritact: 

Zt~asticnt 

Can bs 3.rritatinq to 

Kild irritatian. 

!Io af taat. 

xinimal .ffact. 

ths x'aspiratory tract. 

Firat Aid 

Z a at on: Remov lkom aroa ot exDosurs and to tresh air area. 

bys Contaot: llush eyss with wataz tor lo minutas. rt irritation 

persista, obtain medical attantion. 

ekin Contact: Waah fr= skin with mild aoap and wata.r. 

SnQeatioon: Inqastion ahould not caua• any sicmificant health 

problema. 

,36 b 
_ _. .....w.. .,..~ ~.~ iu tfd-14e47241369

. ..P.Oa .. 

Sa`n y2Z - Apiil or Leak Progeduras, 

spiil or Laa}c: Respiratory protoction should bi rrorn durinq claan up 

to protect lrom airborne flust. Measurss should be 

taks.n to rraduc.e airborr» dust durinq ciaan up. 

Wast• Dispos.al: Shovel up matecial and dispo~~ 'o~

a lxai

f ili.comply 

with applicable ledaral , st.a ~ requlatitons. 

ssction V'IYI - S,mial Prot,rction 

R.rupiratory Protections X208H/o$xAA4M approvad duet t"pirator i! 

T.L.V. i. 4xo..4eQ. 

Yentilation: Lxal axhduott ~ Ar requirad !or dust to maintain 

airbwne duat beloa tha TLV. 

Mc.hanicalt As raquired for dust. 

Eya protection t Salety qlassotr or qvqqlsa. 

6pecial Prbtectiont None t•equired. 

Dete Frepaxadt ~7une 7.- ].991_ Fnperid by Safaty Dapartment 

~ . 

I 

.~ v~ 
~ . . 

f ~ l c ni . ~.;~ a~ ~., . c .a ..... 1 .-., •, . 

. . ~ . . 

. 

 ` • ` ~ 

HATBRIAL SAFBTY DATA SllB{T l~u~ 

Ceraei Color t Cben cal 1lfg. Co. 

13tD ~ Greet i 11t11 ~v e aue 

Ney BrigIlton, PA 15066 

(112) 846-4000 DATB: D10o. 3 1 1991 

• SSC"tIOM I • IDBHTIPICATI01 

PQODOCT: 1513 C861fICAL NAKE: NBTAL OLIDt 

BORNOLA: Co Al204 CAS 10: 66166•86-I 

. SBCTION II • HAZARDOOS IIiGRBDIE9TS OF MIITORYS 

ABDI81iT }XT . PBL- jyY-Ji~,18 `

Cobalt 40 t .1 kg/Mj 1 ngjK3 

Cobalt Alu in a te B1uQ Spin 1 an • inor y ani i ent, is a reaction prodact of bi Il tenper tpre • ca I ieation in 

~n~eidig ~u~ed ( tol forada ci~ystaY~ ineemarii~ g~f~~SQiaelvaryiag aaountb are beocgen ~ cusly an~ ionicat ~ y 

nlefa oterYis noted, allvalnes.are r ported as Tiee-NeigLted Alerages TRa o ani total dust- particulates onlyg. 

SBCTION III - PHiSICAL DATA 

go113nq Point; N t ap v icable Speclfic G;avity ~92 0=1 ; 9 t applicable 

xeltin point: got a Oa~ l 

Va or ~ressure- 11ot ~~pf icable va r• essit ZAi ~ 1 : Aot ap li able " l

v ~o r~t}pn ~ate ~Bn~~ l ltet t~ =l~ : Not applicable ilo i ity Yater: nsolab~ e , 

APPBARIIkB ?.ND ODOY - inert odorless blue porder 

SBCTIOIt 5 - FIRs 1lltD 11PLOSI01 BAZAYD DA1l 

Hot a fire or explosioa Aaiatd. 

HMIS HAEAAD CLASSIPICDTIOY 

HealtIl: 1 Flaneable: 0 1 Reactivity: 0 

SBC?IOH 1 - RBACTI9I2I DATA ; 

—- ~ . 

STABILITY: Generall coesidered stable ' POLIlM1EATI0b: tot eipected to occur AvOID: lone expectei AVOID: Not applicable 

~Naterials to A•roi ~il Bcze ex D ?cted 

_ BA:As?OuS ~ SCOy: SITIG;i OR BY P30!'JCTS t~ Cce ekYecced 

-?aP 
 Page 2 

S6CTION YI - R6ALT9 RAtARD DATA 

10uTE5 OF BNTRY: 

Byes? YBS Skin? TBS Inbalation? TBS Ingestion? THS 

BPF3CTS OF 07816IPOSURg: •811 CONTACT na Canse irrltation StIti CONTACT ~ol op ed or.repe ted conta0t sa ~ cause irritation. 

IBBAI,ATIOH cagses l ~ rrta t ion p~ the res irato y ract. ~S o toes inslade ouah dy s nea, vbeetin g , aod 

lo alrnent.of p uloonary tunctio . Prog ~ e S slon,o 6ya po~ ~ n cpntinu e a~ tef dust ~ x Go ure ceases. 

• : IN~ BSTIQN 1 harsful. llo t e- A~ tbou b indastrla h3n ~~ ing o ~ thls product has bezn gao~ , the toxlcological 

properties g ave not been fully inves~ igated. 

CAt~ INO~ENIC IARC? HO OSHA? NO 

1513 • CAS 68186-86-1 E I. 17346 is not listed as a carcinogen in the NAP, IARC, or OSRA listings. 

B!43RGSHCY AND FIRST AID PROC$DUR ~ :; 

B yB ~1 D$XIH,CONTACT: Iaaediate ~ , flush eyes vith plenty of yater for at least 1S ainutes. Call a plysican. 

Flusd skla ~ ith 9ater. 

IN9A!~ ATION: R e moae to,flesb air. lf.breathin 4 is difficult, 9 ive oxy ep. Call a phy e i s an. 

INGBSTION: Induce voalting. Ner:r glve aaytning by noutb to 3a uncon ~ clars person. Cait a physiciaa. 

SBMOH YII - PR3CADTIOHS FOR SAFB BaNDLIHG AND DSE 

N

BPS,TO B$ TAAEII I CASB NATERIA5 IS RBL3ASBD OA SPjLLBD 

nt ala s 111 dge aa scoo ,u p or ~ a cuui. Avoid dustin . Aotification of t h¢ Bational Res onse Center 

00-124- ~ 8 Q 2) oa be req~ ir2d. ?eier to BPA, DOT andyappllcable state and local regulatl obas for current 

:es Donse lnfornat~ oa. 

It ls rec4 mtad ~ d tbat ea~ h user :gtablisl a s ~ill preveaticn, control ~nd counters~ asu;e lapt ~ sPtc l . such 

g

lan shoul ~ :ac ude rpce u ~ es a~~ ica ~ le to q o ~et to a~ e, control an clean-up o spillg, lac uding reuse 

r dis osa as ap roB riate see lste isposa Y tbo~, ~e o~r~. 

YA TB $ 1SPOSAL M& 9pD F eral state da 1 al d i osal,law3 and r ean ldtion rill 4 ete i e tb p o er,raste disposal roc dare. A~ vasEe aaterla s °s~oold ~~ r QleYed t 4 d tenl ne t~e. 1rCab~e ~asBr s ~t~ stln~ nay .be ne es arY~ . ~ ~

Is sal re ulremeat are de en de~ ~ t pn tbe ~ aiaTd c 1 assi ~~~ati n and ril~ vary by .ocatioa an ~ t~e type of 

is~osal segected. ~Soee vas ~ e Qaterials are aoenable to recyc ~ elreuse. 

SBCTI09 YIII - SPBCIAL PROT8CTI08 IBFORXATIOB 

t3SPIRA;ORY PRO?BCTI ~H A NIOSRL_OSHa approve respirator as necessary 

vBlirl TO 6enerocal xhaust ventilation as necessary to control any air contaainants to vitbin their TLYS, in the 

nse ol fbrs pro ~act. 

tOTICT IYB 100 IPMBNT beaical oq les as peeded to prevent irritation. 

~pber orgne~ rene loves. 

R~ ~~~IgcN tzgRAs l ~Belessary to prevent skin contact. 

rol breat5in . ~st. roi~ .cont ct ~it~ e es skin and clotbing. 

se - vith a~equate ve~tilatioa. 

SBCTI01 II - SPBCIAL PRBCAOTIONS i GOY8Rg118ltT RHGOLA1I09s 

aandiing, ship ia and storing reca t ~ ons: ~n ~ccordance wrt$ $oo~ ind~ strial ~~ actice ha ~dle ritA car~ ~nd,a9oid nnasc9ssar gerspon$1 contact. Wasb tbor aghly a ter han ing aab be ore eating, rinkin or osin tob lc o ro acts. 

For iadustrial use only. 

SBCTIOH 313 SOPPLIBA HOTIFICATIOY . 

Tbis p roduct contai0s the tollorip 9 to;ic chenicals sub 1' ct t Q tb repot tinq re~u irenents of Section 313 of 

tbe e4ergency Planning and Coeeuni[y Right-to-Inor Act 0 ~ 1986 an~ of 30 CFI< 37i: 

PBR CBNT BY 

CAS; CHBNICAL HAHB 96IG9T 

1?07•96-6 Cobalt Oxide !6 t 

_ tbis i ~ for:atic,~ aust be incleded in all NSDS's that are copied atd distributed for t9is aatetial. 

:t: 

3?)S 
Potymeri=ation 

. .-, MATERIAL S 

' 

AFETY 

PATA'SHEET-.'.'' 

191 0. 

 e 

DA1 E PfIEP AR ED 12 / 8 6 

EMERGENCY HAZAf1D f1AT ING 

rwt 

4 - Ex1PEME 

7 - FaGH 1 

2 - AAOOEAAtE M•Lr ~ •r•crM1 

1 • SLIGIIT 

O - INSIGNIFICANT 

s.tc ✓ c •!Aro 

13TH STREET S 11TH AVBNUE, NEN BRICHTON, PA 15066 412-846'-4000 ✓ 

SECTION I- PROOUCTION INFORMATION: SINGLE SUBSTANCE 0 MIXTURE O 

Chem+ca+ Neme 3 CAS No. COBALT ( I I) CARBONATE, BAS IC .. CAS 12 6 0 2- 2 3- 2] 

Trade Name & Synonyms Sphaerocobaltite, cobalt spar 

Chemicat Insoluble cobalt com ounds lOnemicet C H Co O H 0• 2CoC0 .3Co(OH) .li Family P lformute 2 6 5 12 ' 2' 3 2 

SECTION 11 - HAZARDOUS INGREDIENTS AND/OR CHARACTERISTICS 

~ Cobalt Carbonate, Basic - CAS 1112 6 02-2 3- 2J - 83-84$ 

~ Water of Crystallization - CAS 117732 - 18 - 5J - 16 - 17$ 

SECTION III - PHYSICAL DATA 

Mellin9 Poinl( •F) NA Speclrc Gravity (H20 -1) gm/cc @ 25°C 4.13 

Boitiny Point ( • F) Decomposes NA Percent Volatlte by Volume (•~.) NA 

9utk Density (LBSIPer CuiFt.) NDA PH Slightly 

alkal ine 

i+i(y in water Insoluble 

Appearance and Odor AIMOSt purp is , pink pow er; tdo no . irritanE~— 

It has no odor. 

SECTION IV - REACTIVITY DATA 

Stabitity [Unstabte IConditlons to Avoid 

lable X I NA - - 

lncompatability (Materiais to Avrd

e

)acts with acids, releasinq CO 2 . 

HaZardous Decomposition Products Toxic fumes and metal . oxides may be present during decanposition. 

SECTION V;= FIRE ANO EXPLOSION HAZARD DATA 

Flash Point (Method Used) pA Flemmeble Llmlts NA LeL NA Uel NA 

Eatinfluishiny Media CO,; dry chemical preferred. 

Spectal Fire F19htiny Procedures Avoid flushing with water to sewer or stream. 

Wlien large quantities are involved, wear self-contained 

_ breathing apparatus. 

Ur,usual Fire and Exptosion Hazerds 

During decomposition, may emit toxic fumes and metal oxi ~ es. 
'EC ! ION VI - HEALTH HAZARD DATA ' 

=posuretumits 3 t 11L`GIH 3 

LV: G. i m/m (Cobalt metal fume TwA: 0.1 /m (Cobalt metal Cetting: NDA 

"t ot overelposure and uSt IIT~uS 

N ausea and vomiting if swallowed. Possible dermatitis, conjunctivitis, 

bronchitis. 

hronic' May cause polycythemia. 

+edlcal Conditlons a99ravaled by exposurra 

Pre-existing allergies, respiratoyy disQase. 

'mer9ency flrst Aid Procedures ee pFiysician ~or eye, skin, nose or tl)roat irritation. 

_ y e Flush with copious amounts of water (und er l-ids)--for--1S--minutes 

;kin 

Wash thoroughly with water and soap. 

nhalation 

Remove to fresh air, Aid in hrpa hina i f. , Pce ssar_y-and_ca ll-ph-y."c-ian.— 

ngestion 

Give two glasses water and induce vcmiting. Call physician. 

)THER HEALTH INFORMATION: 

1S T E0: OCarcinogen OTeralogen Otilutagen Q+pther Su spect carcinogen, hematotoxin . 

>ECTION VII - SPECIAL PROTECTION INFORMATION - PRODUCTION AND/OR MAINTENANCE OPERATIONS 

lespiratory Prolectlon (Specily Type) N IOSEi-approved f or toXic dus ts . 

entitation local Exhaust Speciat 

Suction Non e 

Mechanical (General) Other 

Fan None 

-i 0 ve Gloves . iEye ProtecGon -- 

ubbg~ o~i_th impEZVious_>roating Face mask or gog g les 

)tn otecliv e Eq ui ent .:'requenfTy laundered work clothes. 

;ECTION VIII - SPILL OR LEAK PROCEDURES 

;IepstobeTakenlnCaseMalerialisReleasedorSpilled Wearing protective gear, sweep up for recycle 

ar~ ispa ~al. D~>~at -flu~}i-tb-sewe c~or-sEream;-foxic fo -planEs-and ~isFi.-- 

yaste Disposal Method 

Recycle or send to facility approved by local, state, and federal 

authorities for toxic metals disposal. 

;ECTION IX - SPECIAL PRECAUTIONS 

•recnuttons to be taken in Handling and Slorin9 

Keep tightly closed in cool and dry area. 

, 

, 

)ther Precautions! 

Avoid breathing and use adequate ventilation. Maintain clean work area. 

Shower with soap after work sliift. 

;ECTION X - TRANSPORTATION DATA: 

~ c•Shi ~ pingName RO t4az,1d t;l.iss 10 g(^9CFt7 112-101) 

r'0B11LT C11RBO ~ lATE rll~ N11 _. N11 

abc 

pQciA1 Inlormation 

tlone 

NA - NOT AprtiCAeLE NOA • NO OAIA AVAILAfILE LESS flIAn ~ . 6~ Of ~ F. Irinrl 

fulremenl NONE (not regulated by DOT) 
Ceramics 

40 

CY 71 ~ TnwOKE N ~ VEER: 

..- nintory %l(.1rmation: KAO) 648-8165 QWsextays Q50on-5:00pa 

Knv ~ qnncy Telephone Number: (610) 643-S!85 (24 •4 - z-) 

3 N7 Ki, q Roan, lo•t Cwster, PA 1910) 

WD syqQNynoi 

p Czain Pin:< 

41 ~ : OAVE AND SYNTSY18. 

!A0162 

?"T OF "REPARATION: 

"ARED BY: 

.16y Oster, Environmental, HeAfWa6d Sil Q.tekki ician 

7- 00yers s-ould use •5is infoymitfo'n onjyjas,> Aupplemant to other 

information get"erat by them, adogghould qgFe,fhdependent judgements a - • 

of this iniormation to.An=•Ukje':~pr.Opei-Use and protect the healt:-, 

A*! SAVIty cl employee•. This information is lurnished without warranty, and 

zov use as Ana prcduct not in conlarmance with this Material Safety Data 

3-lem, cr in combination with •ny other prcduct or process, is the 

onsponstaility of the user. 

--------------------- ----------------------- 

i:-113 - -:ODUC7 !2 FORMED BY HIGH TEMPERATURE CALCINATION. THEREFORE, IT MAY No-i -

':'I -t A~,Y OF THE PROPERTIES OF THE FOLLOWING SETAL CO•POUNDS LISTED. 

,:-- WT% CAS-4 ACGIH TLV OSHA PEL 

Alumirum 85-95 -------- 10 mq1m3 (b) 5 mg/m3 (a) 

Wnganegq 6•i0 -------- 5 mg/m3 (C) 5 mg/M3 

:1 later lo 29 CFR 1910.1013 (Arsenic Stordard), 29 CFR 1910-1025 (Lead 

Svnn6aed) and 29 OFR 1910.1027 (Cadmium Standard) for more information. 

(CO Cailing Limit Value 

veoo••nb•e Oac•io^: 

. .. ... ... .... .... .... ... ..... 

............................ 

tm fv zzov rn • FAY fo rm gzmpngr, 
.. ... .... .. 

:70XSCN NATTHEY CERAMICS INC. 

-- - -- --------------- ------------------------------------------------------------ 

- - - ....... - - - - - ....... - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - ----- 

W 700,19WASAWS . .... . . .. ...- 

D7AG177 (AIR • 10. 

-3 .:7KT VCLATTLE 1Y VOLUME Mn 

~ 10 toolicadiQ 7. 0 711TY 1N ~ ATER: 

. —7nole 

OPOIANANCE AND ODOR: 

2-mon pctder, no cdor 

------------------------------- 

------------------------------------------ 

§,Pg±g ................... 

--------------- 

-~ 

39 POIMT (METHOD USED): 

it applicable `40 

AA7:X001SW7NS MEWA: a 400 oto 10. 

Antsrial will not burn, however, SAO& m&y We" I

"us-Od to cool down metal 

containers. % 

Tn=A! 71RE FIGHTING 

fighters shculd wear Self -ConGARIBMthing Apparatus. Use watar 

s7jay to ccul metal containers. Use . , . w~niii~ approaching advanced or 

mAssive fires. Run off from •ire control may cause environmental pollution. 

LQ ~ SWAL F:RE AND EXPLOSION HAZARDS: 

7cxic fumes way be evolved during a firs. 

----------------------------------------------------------------------------------------- 

------------------------- 

----------------------------- 

ROUT".-E- S OF EX•OSURE: 

i n X.o Eyes: Nio Inhalation: Yes Ingestion: Yes 

74?GET ORGAN(S) EFFECTS: 

Aluminum-Not available 

ma nganese-Respi ra tory system, Central Nervous System, blood, kidneys 

CARCINOGENWITY STATUS: 

74e foij•wing con7•und(s) ire listed as carcinogens by NTP, !ARC, 

CSVA cr a!!: 

Vone 

77-=S I. OVEREXPOSURE: 

7tto 7c ~ :.ntty: •mis comoound is low in acute toxicity with an LD50 of 

-V n . . " _ ' .;n 2,W mg/Kq oral rat. 

Conic vn ~

±City: Long term exposure to Csdojua compounds may rusult 0 -: 

~ nd increased risk of cincer of the lung and prostate. 

staidard 29 cFR 19W.1027 !or more information. 

c onjnun ~ s any cAuse lunq cAniar. voloc to 1 23Q 

1: 12 
Cefamics • 

. . ... ........ .... ... ... .... 

. .. .. ... 

77A 

lco&162 

004SON NATTHEY CERAMICS INC. 

. . . . .... .... .... .... . .. ... ........... ......... 

—.5wAgnA ..................... 

707-IM AND FIRS7 •ATZ PRCG7DjRzS% 

FIVSK with plenty of water for 15 Minutes. Zf irritation qsrv!SIE ~ 

a ohysician. . 

An case 0~ con tect, wash skin with soap ort water. Alcove 

~7~ 70ns? 710thing and S~'Ces. AaW or clean properly toicre rEnse'. 

AIAV004 Ro-ove to Tres> air. Gi-e actilicial -aspiralion A! nzt 

-St ~ vnq. TV nreathing is difficolt, give oxygon. ContacL a whysician 

:30tion: oi"a milk or watar. Do not indoce vemiling i! verson •is 

Contact a ph•ztcian inmediately. 

77AT: ~ 17y (choose one): jUNSTABLVI : .* 

(x)STABL- 

-1nPA71SZLITY (MATERIALS TO A01DOW.'I 

Acidic conditions and acids 

14AWRDOGS DECOMPOS171ON PRODUCTS i 

- at applicable 

PAZARDOUS POLYMERIZATION (choosdo )TAYO-QW, 

;_( Y ) . WII~LANOT C 'CC' R Ur 

----------------------------------- --------------------------------- 

------------------- --------------------- 

?7a•5 TO BE TAKEN 1N CASE MATERIAL 1S RELEASED OR SPILLED: 

iTVACUAte area. Use appropriate personal protective equipment during clean 

•9z Use a wet moo or vacu"m cleaner equiped with a HEPA filter. Prevent 

*ntry into waterways. If reportable quantity is exceeded, contact the 

Notional Response Center. 

NASTE DIEPOSAL METHOD: 

allow all Federal, State and Local regulations for removal and disposal. 

------------------------------------------------------------------------------ 

------------------- 

RES0 7RATORY PROTECTION (SPECIFY TYPE): 

A XZ0SH/MShA approved respirator with HEPA filter represents the minimum 

7

.4021 of oratection. See OSHA 29 CFR 1910.134 for respirator fit, selectioi -i 

%nt "se, 

LWAL !AKAUST: At souvne of gvno ~,~ Ior to ramove dust from breAthir , :7 

zGne.. 

~ =%TCAL VWHAAI ~ w Accup ~ nhlw for 
' 

Ceramicl 

----'- ... ... ' ......... ' ....... --' ' '' '- 

. 

MATTHEY CERAMICS INC. 

- - '-_----'-----_---------_-------- --- '------------- .... .... ....... --_ -'- 

--... ........ .... ... _'--_-_-------_--------_-_'-'--'_ 

' 7>0ver ar& eye jath. Dispcsable csveralls to nrc,54t 

'^ 

--- ... ............... ..................................... ... ... --------------------------------------------------- 

' -' ---'-------- ------------------------- 

75 BE TAKEN 1N KANDLING AHD STORINW. 

-,.`nlej, closed containers. Prevent noisturs inside ccntaisyrs, -- '- ~ Oj7C%TION% 

'ov eat, trink or smoke while using this material. Use i ~ acccrdance witi-I 

~ ^'-,O 'ntustnial hygiene standards. 

~ --- --------------------------------------------------------------------------- 

/ ' `- -- ~~ ^ ' ' 

r7L ~-172RY ' 

-~ 

~ 

SAa'zs: Cooponents on `^ n. 

~ ;l? 7ttla 71I Section 313 Re 

Manga:ese Compounds 

--_'_-_--_---____--------___-_ ~= ----_-_--_-_----__----_ 

--------_--_-_---_- ~~~tig~_~I_ ..................... 

|11247-TO-KNOW INFORMATION: 

~ cSMQ:ent 

'2~1''Pigoent Red 231 68186-99-2 

' 

!"`ilfo'niw Proposition 65: 

~~~~~ z oateriaI does not contain any ingredients that are known to the State 

~ ol,California to cause cancer or reproductive toxicity. 

PrPoge§ ---------------------------- 

REFERENCES: 

PA ~ "!ays California Code of Regulations. 

~

73 6& Pocket Guide to Chemical Harards. 

2 0 ~0 1 1910.1000, Z-tables 

~-77 ~ T.'/ Yen Waicial Substances and PhysicaI Agents. 

~ .' 

' 

K ~Z ' 
APPENDIX B 

Source Test Data 

3/46 
ENGINEERING EMISSION TESTING 

FOR 

BORAL BRICKS, INC. 

AUGUSTA, GEORGIA 

SEPTEMBER 10-11,1991 

Submitted By: 

AIR SYSTEMS TESTING, INC. 

P.O. Box 6278 

Marietta, GA 30065 

(404) 426-0447 

BRUCE LAWRIE 

317 
E.P.A. TEST PROCEDURES 

The testing procedures followed were according to Methods 1, 2, 5, 7, 8, 9, and 

13; for location of sampling points; measuring of stack gas velocity and 

volumetric flow rate; determination of particulate concentrations; determination of 

NOX concentrations; determination of SO: emission concentrations; 

determination of opacity emissions; and determination of fluoride emission 

concentrations. These methods can be found in the Code of Federal 

Regulations, Title 40, Parts 53-60, revised as of July 1, 1990. 

Method 1, determination of number and location of sampling points, was used to 

calculate the location of the twelve points used on each traverse. 

EPA Method 2 was used to calculate the stack gas velocity and volumetric flow 

rate. The S-type pitot tube on the pitot-probe assembly was fabricated according 

to design criteria in Method 2 that allows a pitot coefficient of 0.84 to be used in 

the calculations. Stack gas temperatures used in the velocity calculations were 

obtained with a type "K" thermocouple and digital thermometer. Leak checks 

were performed on the pitot-manometer assembly after each test and showed 

no leak. 

Method 5, Determination of Particulate Emission Concentrations, was used to 

determine particulate emissions. The sampling train consisted of a calibrated 

nozzle, union, heated glass liner, glass fiber filter and filter holder, four 

impingers, umbilical cord, pump, and control console. Impinger outlet and dry 

gas meter temperatures were monitored throughout the test with type "K" 

thermocouples. The dry gas meter in the control console was calibrated against 

a Rockwell S-415 test meter that had been standardized with a Rockwell #1464 

Bell Prover. 

4 

3 ~~ 
SUMMARY OF TEST RESULTS 

TK-2 - Fluorides 

Test #2 Test #4 

Volume C Meter (Vm): 26.547 26.035 

Sqrt Deita P: 0.388 0.360 

Sampling Time (min): 45 45 

Barometric Pressure (Pb): 30.05 30.05 

Delta H (H): 1.13 0.99 

Volume in Impingers (mis): 9.5 10.0 

Stack Pressure (Ps): 30.05 30.05 

Stack Temperature (Ts): 668 662 

Meter Coefficient (Y): 1.007 1.007 

Pitot Coefficient (Cp): 0.84 0.84 

Meter Temperature (Tm): 563 570 

Area Stack (As): 7.47 7.47 

Area Nozzle (An): 0.000524 0.000524 

Percent CO2 (96): 0.0 0.0 

Percent 02 (96): 21.0 21.0 

Percent N2 (96): 79.0 79.0 

Milligrams Fluoride: 3.3 3.8 

Average 

Molecular Weight Dry (Md): 28.84 28.84 28.84 

Volume Water (Vwstd): 0.45 0.47 0.46 

Volume Gas Sampled (Vmstd): 25.239 24.440 24.840 

Wet Fraction (Bws): 0.017 0.019 0.018 

Molecular Weight Wet (Ms): 28.65 28.64 28.64 

Volume Gas Sampled (Vma): 32.357 31.098 31.727 

Stack Gas Velocity, (Vs): 24.54 22.68 23.61 

Volumetric Flowrate (Qs): 8,580 7,987 8,284 

Volumetric Flowrate (Qa): 11,000 10,163 10,582 

Grainloading, gr/dscf: 0.002 0.002 0.002 

Fluoride Emission Rate, #/Hour: 0.15 0.16 0.16 

Percent Isokinetic Sampling: 93.2 97.0 95.1 

3i9 
SUMMARY OF TEST RESULTS 

TK-2 - Particulates 

Test #1 Test #3 

Volume 0 Meter (Vm): 25.505 25.384 

Sqrt Delta P: 0.365 0.346 

Sampling Time (min): 45 45 

Barometric Pressure (Pb): 30.05 30.05 

Delta H (H): 1.00 0.90 

Volume in Impingers (mis): 8.5 10.0 

Stack Pressure (Ps): 30.05 30.05 

Stack Temperature (Ts): 673 673 

Meter Coefficient (Y): 1.007 1.007 

Pitot Coefficient (Cp): 0.84 0.84 

Meter Temperature (Tm): 553 570 

Area Stack (As): 7.47 7.47 

Area Nozzle (An): 0.000524 0.000524 

Percent CO2 (96): 0.0 0.0 

Percent 02 (96): 21.0 21.0 

Percent N2 (96): 79.0 79.0 

Milligrams: 11.2 20.0 

Average 

Molecular Weight Dry (Md): 28.84 28.84 28.84 

Volume Water (Vwstd): 0.40 0.47 0.44 

Volume Gas Sampled (Vmstd): 24.679 23.824 24.252 

Wet Fraction (Bws): 0.016 0.019 0.018 

Molecular Weight Wet (Ms): 28.67 28.63 28.65 

Volume Gas Sampled (Vma): 31.829 30.832 31.330 

Stack Gas Velocity, (Vs): 23.17 21.98 22.57 

Volumetric Flowrate (Qs): 8,051 7,611 7,831 

Volumetric Flowrate (Qa): 10,384 9,850 10,117 

Grainloading, gr/dscf: 0.007 0.013 0.010 

Emission Rate, #/Hour: 0.48 0.85 0.66 

Percent Isokinetic Sampling: 97.2 99.2 98.2 

:3ZC3 
SUMMARY OF TEST RESULTS 

Plant #5 - Fluorides 

Test #7 Test #8 

Volume 0 Meter (Vm): 38.259 38.199 

Sqrt Delta P: 0.701 0.669 

Sampling Time (min): 45 45 

Barometric Pressure (Pb): 30.05 30.05 

Delta H (H): 2.58 2.38 

Volume in Impingers (mis): 41.0 43.0 

Stack Pressure (Ps): 30.05 30.05 

Stack Temperature (Ts): 910 910 

Meter Coefficient (Y): 1.022 1.022 

Pitot Coefficient (Cp): 0.84 0.84 

Meter Temperature (Tm): 578 573 

Area Stack (As): 28.27 28.27 

Area Nozzle (An): 0.000475 0.000475 

Percent CO2 (96): 2.0 2.0 

Percent 02 M: 18.0 18.0 

Percent N2 M: 80.0 80.0 

Milligrams Fluoride: 43.0 45.0 

Average 

Molecular Weight Dry (Md): 29.04 29.04 29.04 

Volume Water (Vwstd): 1.93 2.02 1.98 

Volume Gas Sampled (Vmstd): 36.086 36.326 36.206 

Wet Fraction (Bws): 0.051 0.053 0.052 

Molecular Weight Wet (Ms): 28.48 28.46 28.47 

Volume Gas Sampled (Vma): 65.235 65.809 65.522 

Stack Gas Velocity, (Vs): 51.91 49.56 50.73 

Volumetric Flowrate (Qs): 48,705 46,401 47,553 

Volumetric Flowrate (Qa): 88,048 84,062 86,055 

Grainloading, gr/dscf: 0.018 0.019 0.019 

Fluoride Emission Rate, #/Hour: 7.68 7.60 7.64 

Percent Isokinetic Sampling: 98.1 103.6 100.8 

3 z/ 
SUMMARY OF TEST RESULTS 

Plant #5 - Particulates 

Test #5 Test #6 

Volume C Meter (Vm): 39.736 39.437 

Sqrt Delta P: 0.700 0.699 

Sampling Time (min): 45 45 

Barometric Pressure (Pb): 30.05 30.05 

Delta H (H): 2.54 2.55 

Volume in Impingers (mis): 37.0 35.0 

Stack Pressure (Ps): 30.05 30.05 

Stack Temperature (Ts): 919 917 

Meter Coefficient (Y): 1.022 1.022 

Pitot Coefficient (Cp): 0.84 0.84 

Meter Temperature (Tm): 578 575 

Area Stack (As): 28.27 28.27 

Area Nozzle (An): 0.000475 0.000475 

Percent CO2 (%): 2.0 2.0 

Percent 02 (%): 18.0 18.0 

Percent N2 (%): 80.0 80.0 

Milligrams: 38.9 29.7 

Average 

Molecular Weight Dry (Md): 29.04 29.04 29.04 

Volume Water (Vwstd): 1.74 1.65 1.69 

Volume Gas Sampled (Vmstd): 37.475 37.388 37.431 

Wet Fraction (Bws): 0.044 0.042 0.043 

Molecular Weight Wet (Ms): 28.55 28.57 28.56 

Volume Gas Sampled (Vma): 67.962 67.501 67.732 

Stack Gas Velocity, (Vs): 52.03 51.87 51.95 

Volumetric Flowrate (G?s): 48,661 48,736 48,698 

Volumetric Flowrate (G?a): 88,248 87,988 88,118 

Grainloading, gr/dscf: 0.016 0.012 0.014 

Emission Rate, #/Hour: 6.68 5.12 5.90 

Percent Isokinetic Sampling: 101.9 101.5 101.7 

322 
SAMPLING PROCEDURES 

The sampling locations for the testing were on a specially constructed platforms 

on the exhaust stacks. A wooden platform was used on each of the test ports to 

support the filter/impinger box while the probe traversed the stack. 

Prior to each test, the sampling train was assembled for testing. An 80°k 

isopropanol solution was placed in impinger one, and a 396 hydrogen peroxide 

solution in impingers two and three. 200.0 grams (g) of silica gel was placed in 

impinger number 4. The probe was secured in the sampling box, the filter holder 

assembly was installed, and the system was ready for pre-test leak checks. 

After each test, leak checks were performed on each sampling train and each 

side of the pitot tubes. In each of the test repetitions, all leak checks were within 

the allowable limitations. Next, the train was disassembled. The filter holder was 

removed and sealed to prevent loss of particulate matter. The probe and nozz(e 

were cleaned with reagent grade acetone, with all sample exposed surfaces 

brushed and rinsed at least six times to insure all particulate matter was 

removed. This rinse was saved in a 500 ml polyethylene bottle. Next, the 

contents of impingers two and three were measured with a graduated cylinder, 

and saved for further analysis. The silica gel was returned to its container and 

sealed. 

6 sZ3 
Method 8, Determination of Sulfur Dioxide Emissions from Stationary Sources, 

was used to determine S02 concentrations. The particulate test train was 

modified by replacing the distilled water normally used in the first two impingers 

with a 80°6 isopropanol solution in impinger one, and a 396 hydrogen peroxide 

solution in impingers two and three. 

Method 13B, Determination of Fluoride Emission Concentrations, was used to 

determine fluoride emissions. The sampling train consisted of a calibrated 

nozzle, union, probe with 316 stainless steel liner heated with 50 feet of 0.4 

ohms per foot of nichrome wire, three impingers, Whatman number one filter and 

filter holder, silica gel impinger, umbilical cord, pump, and control console. 

~ Impinger outlet and dry gas meter temperatures were monitored throughout the 

test with type "K" thermocouples. The dry gas meter in the control console was 

~ calibrated against a Rockwell S-415 test meter that had been standardized with 

a Rockwell #1464 Bell Prover. 

5 32 ~ 
/~ t2 1 °i 94 

~ ST" AC, r, T6rS i 

FAX ANb FACTS ~umr 5 

FROM CLEMSON 

THE CERAMIC CENTER 

CLEMSON UNIVERSlTY, P. 0. BOX 340908 

CLEMSOfV, SC 29634-0908 

TEL: 803-656-1094 FAX: 803-656-1095 

DATE 

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BORAL BRICK PLANT #5 - FLUORIDES 

, r 

•yJ 

'..;olume @ Meter (Vm): 

' I Sqrt Delta P: 

'timpling Tlme (min): 

Barometric Pressure (Pbar): 

Avg Delta H: 

Volume in impingers (mis): 

Stack Pressure (Ps): 

Stack Temperature (Ts): 

Meter Coefficient (Y): 

Pitot Coefficient (Cp); 

Meter Temperature (Tm): 

Area Stack (As): 

Area Nozzle (An): 

Percent CO2 (%): 

Percent 02 (%): 

Percent N2 (%); 

Fluoride (mg): 

Test #4 Test #5 

41.364 40.379 

0.784 0,775 

60 60 

30.10 30.10 

1.55 1.50 

62.0 57.7 

30.15 30.14 

880 889 

0.9874 0.9874 

0.84 0.84 

554 558 

28.27 28.27 

0.000334 0.000334 

2.0 2.0 

18.0 18,0 

80.0 80.0 

85.8 75.9 

Test #6 

40.692 ft^3 

0.770 

60 min 

30.10 inHg 

1.46 

64.1 mis 

30.13 inHg 

883 R 

0.9874 

0.84 

545 R 

28,27 ft^2 

0.000334 ft^2 

2.0 % 

18.0 % 

80.0 % 

82.1 mg 

Molecular Weight Dry (Md): 

Volume Water (Vwstd): 

lume Gas Measured (Vmstd): 

Wet Fraction (Bws): 

Molecular Weight Wet (Ms): 

Volume Gas Sampled (Vma): 

Stack Gas Velocity (Vs): 

Volumetric Flowrate (Qs): , 

Volumetric Flowrate (Qa): 

Total HF (mg): 

HF Concentration (cs): 

HF Emissions rate (pmr): 

Percent Isokinetic Sampling: 

29.04 29.04 29.04 

2.92 2.71 3.02 

39.32 38.10 39.32 

0.0691 0.0665 0.0712 

28.3 28.3 28,3 

68.7 68.3 67,7 

57.2 56.8 56.3 

58216 57260 57151 

97054 96441 95595 

90.35 79.92. 86.45 

2.30 2.10 2.20 

17.69 15.89 16.62 

101.7 100.0 103.9 

Average 

29.04 lblibmol 

2.88 scf 

38.91 scf 

0.0689 

28.3 lb/lbmol. 

68.2 ft^3 

56.8 - ftls 

57542 scfm 

96363 scfm 

85.57 mg 

2.20 mg/dscf 

16.73 lb/h 

101.9 % 

3,2? 2 
BORAL BRICK PLANT #5 - CHLORIDES 

~ 

/olume @ Meter (Vm): 

Q Sqrt Delta P: 

Sainpling Time (min): 

Barometric Pressure (Pbar): 

Avg Delta H: 

Volume in impingers (mis): 

Stack Pressure (Ps): 

Stack Temperature (Ts): 

Meter Coefficient (Y): 

Pitot Coefficient (Cp): 

Meter Temperature (Tm): 

Area Stack (As): 

Area Nozzle (An): 

Percent CO2 (%): 

Percent 02 (%): 

Percent N2 (%): 

Chloride (mg): 

Molecular Weight Dry (Md): 

Volume Water (Vwstd): 

N" ime Gas Measured (Vrnstd): 

V1ret Fraction (Bws): 

Molecular Weight Wet (Ms): 

Volume Gas Sampled (Vma): 

Stack Gas Velocity (Vs): 

Volumetric Flowrate (Qs): . 

Volumetric Flowrate (Qa): 

Total HCI (mg): 

HCI Concentration (cs): 

HCI Emissions rate (pmr): 

Percent Isokinetic Sampling: 

Test #4 Test #5 Test #6 

41.364 40.379 40.692 ft^3 

0,784 0.775 0.770 ' 

60 60 60 min 

30.10 30.10 30.10 inHg 

1.55 1.50 . 1.46 

62.0 57.7 64.9 mis 

30.15 30.14 30.13 inHg 

880 889 883 R 

0,9874 0.9874 0.9874 

0.84 0.84 0.84 

554 558 545 R 

28.27 28.27 28.27 ft^2 

0.000334 0.000334 0.000334 ft^2 

2.0 2.0 2.0 % 

18.0 18.0 18.0 % 

80.0 80.0 80.0 % 

42.9 38.1 40.4 mg. 

, 

Average 

29.04 29.04 29.04 29.041b/lbmol 

2.92 2.71 3.02 2.88 scf 

39.32 38.10 39.32 38.91 scf 

0.0691 0,0665 0,0712 0.0689 

28.3 28.3 28.3 28.31bltbmol 

68.7 68.3 67.7 68.2 ft"3 

57.2 5618 56.3 56.8 ft/s 

58216 57260 57151 57542 scfm 

97054 96441 95595 96363 scfm 

44:10 39.17 41.53 41.60 mg 

1.12 1.03 1.06 1.07 mg/dscf 

8.64 7.79 7.99 8.141b/h 

101.7 100.0 103.9 10 9.9 % 

.3~'