### Project No. 3338
James RiverCogeneration Company Hopewell, Virginia Emission Evaluation Test Program
Unit No.2
Test Date: May 7,2010

### Prepared for:
Ms. Dana L. 

### Rieves Compliance Supervisor James RiverCogeneration Company 912 East Randolph Road Hopewell. Virginia 23860

Date Prepared: June 2010

### Table ofContents

Page
1.0 Introduction.

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 1
2.0 Source Information and Description 2
3.0 Test Results Summary 3
4.0 Test Methodologies " 6 4.1 Cyclonic Flow.

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 6 4.2 Stack Gas Velocity and Volumetric Flow Determination 6 4.3 Moisture Content 7 4.4 Gaseous Emission Sampling System 7 4.4.1 Oxygen and Carbon Dioxide 8 4.5 Toxic Metals 8 4.6 Total Suspended Particulate Matter/ Particulate Matter< 

### 10 Microns 10
5.0 QualityAssurance/Quality Control Procedures 12 5.1 S-Type PitotTubes 12 5.2 DryGas Meters

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 12 5.3 Nozzles

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. 13 5.4 Thermocouples 13 5.5 Labels..................................................... 14 5.6 Chain-of-Custody Documentation 14 5,7 Calibration Gases 14
AppendixA - Field Data Sheets Appendix B - Laboratory Data Appendix C -Emission Calculations Appendix D -Calibration DataJames River Cogeneration Company June 2010 

### 1.0 Introduction Project No. 3338 Revision No. 0



### AirNova, Inc. conducted an emission evaluation test program atthe James RiverCogeneration Companyfacilitylocated in Hopewell,Virginiaon May7,2010. Emissionsamplingwasconducted inorder
to evaluate the status ofone [1] turbine stackoperating atthis site. The specific emission parameters which were determined as part ofthis test program included the following:

• Toxic Metals*

• Total Suspended Particulate Matter [TSP]

• Particulate Matter< 10 Microns [PM-1 0]

* Toxic Metals included: Antimony [Sb], Arsenic [As], Beryllium [Be], Cadmium [Cd), Chromium [Cr], Cobalt [Co), Lead [Pb], Manganese [Mn), Nickel [Ni), Selenium [Se) and Mercury [Hg] AirNova, Inc. was responsible for all on-site sampling, sample analysis and submittal ofthis test reportwhich provides adescription ofthe source andthe sampling location, acomplete summaryofthe
test results and a discussion ofall test methodologies and analytical techniques thatwere employed in
the performance ofthe test program. Any questions pertainingtothe information provided herein may be addressed to: Mr. Lenny D. Katerynczuk Project Manager AirNova, Inc. 5845 Clayton Avenue Pennsauken, NewJersey 08109 Telephone: [856] Telefax: [856] 486-9896 E-mail: lenny@airnova.com

AirNova, Inc. 

### 1James RiverCogeneration Company June 

### 2010 

### 2.0 Source 

### Information and Description Project No. 3338 Revision No. 

### 0



### The James River Cogeneration Company [JRCC) is 100% owned by Cogentrix, Inc. and was constructed in 1987to provide steam to Honeywell and electricityto Dominion Virginia Power. JRCC's
PPAiscurrentlyNOVEC. The33-acretractonwhich JRCC is located is leasedfrom Honeywell. The plant
has six (6) Fosterwheeler boilers rated at 157,500 Ibs/hreach. Steam is supplied to two (2) General
Electric single automatic extraction/condensing turbines rated at 58.5 MWeach.
Each boiler is equipped with aspraydryerabsorberand a bagfilter. The emissions stream from
each setof3 boilers isductedto acommonturbine stack. Theturbine stacks, identified as UnitNO.1 and
Unit No.2, are 116 inches (9.7 feet) in internal diameter [1.0.). Emissions testing for this evaluation
program was conducted on Unit2 stackonly. Four (4) test ports are located on each exhauststackat
900 

### intervals. The ports are located 80feet(8.3ductdiameters) downstreamfrom theentrypointtothe
final stackand 60 feet (6.2 duct diameters) upstream from the atmospheric exhaust point. A total of
twelve (12) traverse points were utilized for all emission determinations [six (6) across each stack
diameterand three (3) pertest port). Thetraverse points were located as follows:
Table 2-1 James River Cogeneration Company Unit No.2 Traverse Point Locations



# -**\§t~cK** I 

# ., J

...**,,~** .... 

# .. 1 4.4 5.1 2 14.6 16.9 3 29.6 34.3

AirNova, Inc. 

### 2James River Cogeneration Company June 2010 

### 3.0 Test Results Summary Project No. 3338 Revision No. 0



### Acompletesummaryofresultsforthe emission evaluationtestprogram conductedattheJames
River Cogeneration Companyfacility for Unit No.2 is provided in tabularformat on the following pages. Sampling was conducted in order to evaluate the status ofthe boiler for particulate matter and toxic
metals emissions. Summarytables are presented as follows:
James River Cogeneration Company Unit No. 2 Emission Evaluation Test Program

SummaryofTest Results Tables

Table No. Description Page No. 3-1 Unit NO.1

-Test Data Summary

-TSP and PM 10 

### 4 3-2 Unit No.1

-Test Data Summary

-Toxic Metals 

### 5

Abbreviations:

AirNova, Inc. 

### TSP = 

### PM 10 = 

### Total Suspended Particulate Matter Particulate Matter

### < 10 Microns

3James RiverCogeneration Company June 2010 

### Table 3-1 James River Cogeneration Company Unit No.2 Test Data Summary'TSP and PM 10 Project No. 3338 Revision No. 0

Run No. 

### 1 

### 2

• v' 

## ""'

. Date 05/07/10 05/07/10 05/07/10 Test Period 0715-0930 0952-1203 1216-1426 StackGas Charactel'istics Temperature [OF] 210 213 216 213 Moisture Content [%] 10.6 10.4 10.3 10.4 MolecularWeight [Ib/lb-mole] 29.1 29.1 29.1 29.1 Velocity [FPS] 50.3 51.0 50.8 50.7 Flow Rate [ACFM] 221,456 224,529 223,514 223,166 Flow Rate [DSCFM] 156,514 158,617 157,157 157,429 Oxygen [%] 5.49 5.65 5.49 5.54 Carbon Dioxide [%] 13.65 13.53 13.63 13.60 Total Suspended Particulate Matter Concentration [gr /DSCF] 1.4e-03 0.001 0.001 0.001 Emission Rate [Ib/hr] 1.85 1.71 1.45 1.67 Emission Rate [lb/MMBtu] 0.002 0.002 0.002 0.002**.~** •...............• ...... Concentration [gr /DSCF] 0.002 0.002 0.002 0.002 Emission Rate [Ib/hr] 2.92 3.32 3.27 3.17 Emission Rate [lb/MMBtu] 0.004 0.004 0.004 0.004


### Standard Conditions: B8°F, 29.92 in. Hg

AirNova, Inc. 

### 4James RiverCogeneration Company June 2010 

### Table 3-2 James River Cogeneration Company Unit No.2 Test Data Summary-Toxic Metals Project No. 3338 Revision No. 0

Run No. 

### 1 

### 2 3 Average Date 05/07/10 05/07/10 05/07/10 Test Period 0715-0930 0952-1203 1216-1426 StackGas Characteristics Temperature [OF] 208 212 215 212 Moisture Content [%] 11.2 10.6 10.5 10.8 Velocity [FPS] 50.5 50.5 51.7 50.9 Flow Rate [ACFM] 222,359 222,304 227,561 224,075 Flow Rate [DSCFM] 156,513 156,839 159,818 157,723 Oxygen [%] 5.49 5.65 5.49 5.5 Carbon Dioxide [%] 13.65 13.53 13.63 13.6 Toxic Metals [Emission Rate Ib/hr)'" • Antimony 6.1 e-05 9.ge-05 1.2e-04 9.3e-05 Arsenic 4.7e-04 5.1 e-04 5.3e-04 5.0e-04 Beryllium 1.0e-05 1.0e-05 1.4e-05 1.1 e-05 Cadmium <2.4e-05 3.8e-05 8.oe-05 4.7e-05 Chromium 1.0e-03 1.1 e-03 1.1 e-03 1.1e-03 Cobalt 7.6e-05 8.0e-05 1.oe-04 8.5e-05 Lead 4.3e-04 5.4e-04 2.4e-03 1.1 e-03 Manganese 4.8e-03 4.ge-04 7.6e-04 2.oe-03 Nickel 5.8e-04 8.3e-04 1.3e-03 9.0e-04 Selenium 7.6e-05 9.4e-05 1.2e-04 9.7e-05 Mercury < 1.2e-04 < 1.2e-04 < 1.2e-04 < 1.2e-04


### Standard Conditions: B8°F, 29.92 in. Hg

'" Concentrations and emission rates in Ib/MMBtu of each toxic metal can be found in the Emission Calculations Appendix.

AirNova, Inc. 

### 5James RiverCogeneration Company June 2010 

### 4.0 Test Methodologies Project No. 3338 Revision No. 0



### The emission evaluation test program was conducted in determination ofthefollowing emission parameters utilizing the specified methodologies.


### Table 4-1 James River Cogeneration Company Unit No.2 Test MethodologySummary

Emission Parameter No.afTest Runs Sampling and Analytical Methodology Traverse Point Location 

## * EPA Reference Method 1 Volumetric Flow Rate 

## * EPA Reference Method 2 Oxygen/Carbon Dioxide 

## * EPA Reference Method 3A Moisture Content 

## * EPA Reference Method 4 Toxic Metals 3 EPA Reference Method 29 Total Suspended Particulate Matter/ 3 EPA Reference Methods 5 and 202 Particulate Matter< 10 Microns



## * These parameters were determined concurrentlywith all other emission parameters.


### 4.1 Cyclonic Flow
The absence of cyclonic flow was demonstrated atthe sampling location according to Section
11.4 of EPA Reference Method 1. An S-type pitotwas connected to a manometer. The pitottube was placed in such a positionthatthe openings ofthe pitottubewere perpendiculartothe stackgasflow. An anglefinderwas placed onthe pitottubewhich was rotated until a reading ofzero (0) was obtained. The 'yaw' anglewasthen recorded. The cyclonicflowtraversewas performed atthetraverse pointlocations specified in Table 2-1.


### 4.2 StackGas Velocity and Volumetric Flow Rate Determination
The determination ofstack gas velocity and volumetric flow rate was performed in accordance
with EPA Reference Method 2. Velocitytraverses across the stack diameter atthe test location were performed using an S-type pitottube andtype-Kthermocouple. The S-type pitottube was connected to

AirNova, Inc. 

### 6James River Cogeneration Company June 2010 Project No. 3338 Revision No. 0



### an inclined vertical manometervia leak-free connections. The type-Kthermocouplewas connected to a digital temperature indicatorfor signal output. These readings were observed and recorded at each
traverse pointfor each test run. Apost-testleakcheckoftheS-type pitottube,the manometer, andthe interconnectingtubingwas performed in accordance with the procedure described in EPA Reference Method 2, "Determination of
StackGas Velocity and Volumetric Flow Rate ( PitotTube]."
4.3 Moisture Content
Moisturecontentdeterminationswere performed in accordancewith EPAReference Method 4, Section 2.0. The determination ofmoisturecontentwas conducted utilizing largecapacityimpingers and by collecting a minimum sample ofvolume of30 dscf.
4.4 Gaseous Emissions Sampling System
An extractive sampling system was used to continuouslydetermine 02 

### and CO2 

### concentrations.
Arepresentativesampleofthefluegaswasextractedthrough aheated (250°F] stainlesssteel probeand
filterassembly, andtransportedviaaheat-tracedTeflonsample linethrough aheatedglassfiberfilterand

aTeflon lined diaphragm sample pumpto acondensation removal trap located in a mobile laboratory. A
heated out-of-stack filter assembly was maintained at a sufficient temperature to prevent water
condensation. Athree-wayvalvewas utilizedto blocksample gasflowand
the measurement system at the outlet of the sampling probe during system calibrations. The
condensation trap was cooled to approximately40°F. The samplewas exhausted from thetrapfree of
moisture and particulate matter. The sample was introduced into a constant-pressure manifold
constructed ofstainless steel and Teflon for metered distribution to the respective analyzers. Outputsignals from all instrumental analyzers were stored on a personal computer (PC) based
data acquisition system (DAS]. All reference method data was reported from the DAS. All continuous analyzers utilizedforthe RMtesting provided alinearresponsetothe DASoverthecalibrated range. This

was verified bythe pre-test calibration results.

AirNova, Inc. 

### 7James RiverCogeneration Company June 2010 Project No. 3338 Revision No. 0 

### Astratificationtestwas performed duringthefirsttestrunfortheemissionsourcetodetermine
the amountoftraverse pointsto be utilized forthe gas probeduring each subsequenttest run. Thetest

was performed in two (2) test ports utilizing twelve (12) traverse points. The gas probe was at each
traverse pointforaminimum periodoftwo (2)timesthe responsetimeofthe reference method sampling system [1 minute). The oxygen analyzerwas utilized to determine stratification in the exhauststack. It

was determined that the oxygen concentration at each traverse pointwas less than 5% ofthe mean oxygen concentrationforalltraverse points, andtherefore, singlepointsamplingwas implementedforthe

source during the test program. The stratification test results can be found in AppendixA ofthis test report. 

### 4.4.1 Carbon Dioxide and Oxygen
Thecarbondioxideandoxygen concentrationsinthestackgasesweredeterminedbyEPA
Reference Method 3A. The sampling system wasthe same as described above. Oxygen concentrations

were determined using a paramagnetic oxygen analyzer operating in a range of 0-22.D3%. A nondispersive infrared analyzerwas utilized to measure carbon dioxide concentrations operating in a range of 0-22.28%. Before and after each sample run, the analyzer was calibrated with NIST traceable
calibration gases. Calibration gaseswere 0-20% [zero gas), 45-55%and 100%ofthe calibration span. each
test run. Outputsignals were stored and processed bya PC based DAS system. 

### 4.5 

### ToxicMetals
Metals in the exhaust gases were determined isokinetically using EPA Reference Method 29 "Methodology for the Determination of Metal Emissions in Exhaust Gases from Hazardous Waste
Incinerator Processes".
Metals sampling occurred during 2-hour sampling events. Triplicate test runS were performed
with each collecting a minimum volume of 60 DSCF. The sampling train consisted of the following components:

AirNova, Inc. 

### 8James River Cogeneration Company June 2010 Project No. 3338 Revision No. 0



### • Glass sample nozzle and probe

• Heated glass fiber filter

• A modified Greenburg Smith impingercontaining 100 ml ofa 5% HNOa/1 0% H2

### 02 

### • A Greenburg-Smith impingercontaining 100 ml 5% HNOa/1 0% H2

### 02 

### • Modified Greenburg-Smith impinger initiallyempty

• Two [2] modified Greenburg-Smith impingers containing 100 ml 4% KMnO.J1 0% H2

### S04 

### solution

• An impingercontaining approximately225 g ofsilica gel desiccant

• Dry gas meter equipped with inletand outletthermocouples The sample was extracted from the exhauststream using avane-type vacuum pump. Isokinetic sampling conditionswere maintained through the use ofatype "S" pitottubeto monitorthe exhaustgas
stream pressure differentials. A type "K" thermocouple was utilized to determine the exhaust gas temperature.
Atthe completion of sampling, the probe liner, nozzle, and front halfofthe filter housing were rinsed and brushed with 100 ml ofa 0.1 N nitric acid reagent and the washings were placed in a glass
ambercontainerretained foranalysis. Thefilterwas removed from thefilterholderand placed in a petri
dish and sealed. The contents of impingers 1 and 2 were measured forvolume increase and placed in

a second glass amber container. Impingers 1 and 2 and the back half ofthe filter housing were then
rinsed with a total of 100 ml 0.1 N nitric acid and the washings were placed in a third glass amber
container. The contents of impinger3 were measured forvolume increase and placed in afourth glass
amber container along with a total of 100 ml 0.1 N nitric acid washings. Impingers 4 and 5 were measured forvolume increase and placed in afifth glass amber container along with atotal of 100 ml
each ofthe fresh permanganate and distilled water rinses of all sample exposed areas forthe two [2] impingers. Impingers 4 and 5 were then rinsed with atotal of 25 ml of 8N Hel which was placed in a sixth glass ambercontainer. The silica gel was recovered from the last impingerand placed in asealed
containerforweight gain determination.
Priorto analysis, the collected frontand backhalfliquid samplevolumeswere reduced. The filter

was acid digested in accordance with the method prior to being combined with the probe rinse for

AirNova, Inc. 9James RiverCogeneration Company June 2010 Project No. 3338 Revision No. 0



## • 1st: 

## • 2 nd: 

## • 3 rd: 

## • 4th: 

### analysis. Antimony, arsenic, beryllium, cadmium, chromium, cobalt, manganese, nickel, lead and selenium

were determined by inductivelycoupled plasma-optical emission mass spectroscopy(ICP-MS). Mercury

was determined by cold vapor atomic absorption spectrophotometry (CVAA).
The spike recoverieswere mostlywithinthe normal range of75%to 125%. Duplicate analyses,
relative percentdifference (RPO) and spike recoverydata can befound in Appendix Bofthistest report. 

### 4.6 Total Suspended Particulate Matter jParticulateMatter

## <10Microns
Totalsuspended particulatematter(TSP)and particulatematter< 10 microns(PM-1 0)emissions

were determined in accordance with EPA Reference Method 5 and EPA Reference Method 202 respectively. Priortosampling,thesampletrainwas leakchecked at 15inches Hgvacuumtoensurethat
all sampletrain componentswere leakfree. During sampling, gas sampleswere isokineticallyextracted
from the exhauststackand passedthrough aglass nozzle, aglass lined probe and aquartzfiberfilter, all
maintained atatemperature of250°Fto preventcondensation on the glass fiberfilter. The gas sample
then passed through an impingertrain consisting offour (4) glass impingers immersed in an ice bath.
The arrangement ofthe impingers was as follows: Greenburg-Smith, containing 100 ml of

### 01 water. Greenburg-Smith containing 100 ml of

### 01 water. Modified Greenburg-Smith containing 100 ml of

### 01 water Modified Greenburg-Smith containing approximately 350 g ofsilica gel forfinal ofthe

The sample gasvolume was measured by passing itthrough a calibrated dry gas meter. An & type pitottube was attached to the sample probeto monitorthe stackgasvelocity in orderto maintain
isokineticsampling conditions. In addition, atype Kthermocouplewas attachedto measurethe exhaust
gastemperature. Following each test run, the EPA 5/202 sampletrainwas leakchecked atthe highest

vacuum recorded during the run. Aftereach run, the probe, nozzle and all connecting glassware ahead ofthe filterwere brushed
and rinsed with acetone. The washings were retained in an amber glass jarwith ateflon lined lid. The

AirNova, Inc. 10James River Cogeneration Company June 2010 

### quartzfiberfilterwas placed in it's original petri dish. Project No. 3338 Revision No. 0



### Condensable PM-10 was determined from the back half analysis of the particulate matter sampling train. No silicone grease was used in the sampling train. All sampling train glassware was cleaned priorto the test consistentwith Section 3.1.3 of Method 202 [soap and tap water. water. and
rinsed using tap water, water. acetone, and finally, MeCI2). Atthe conclusion ofsampling, the pH ofthe impingertrain was measured. Iffound to be> 4.5 pH, the nitrogen purge was not performed.
The glass fiber filters were oven dried for 2 - 3 hours atthe average temperature maintained duringthe corresponding test run, desiccatedfor2 - 3 more hours andthen reanalyzedforafinalweight
determination. Theacetonesampleswereevaporatedatroomtemperatureand pressureintaredTeflon baggies. desiccated for 24 hours and also reanalyzed for a final weight determination. The impinger
contents were subsequently measured forvolume increase and rinsed with distilled waterand retained
inaglasssamplejarwith aTeflon lid. The impingerswerethen rinsedthreetimeswith methylenechloride
and retained in aseparate glass samplejarwith aTeflon lined lid. The PM-1 0 analysiswas conducted as described in Method202 additionallyutilizingTeflon baggiesfortheanalysisofeach liquidsamplefraction.

AirNova, Inc. 11James RiverCogeneration Company June 2010 

### 5.0 QualityAssurance/Quality Control Procedures Project No, 3338 Revision No, 0



### All ofthe source sampling and analytical procedures were performed in accordancewiththe US
EPA's 'Good LaboratoryPractice' guidelines. AirNova, Inc.followedthe requirements ofthe individualtest methodstoensuretheprecisionandaccuracyofthesourcetesting procedures. Inaddition,AirNova, Inc.
followed the procedures provided in the 'Quality Assurance Handbook for Air Pollution Measurement Systems, Volume III, StationarySources'. Sampling equipmentutilized inthetestprogram was calibrated priorto the test performance. The following procedures were utilized.
5.1 S-Type PitotTubes
The S-type pitot tubes were visually inspected to verify dimension requirements, Pitot tubes meeting requirementswere assigned a pitottube coefficientof0,84. Pitottubeswhich did notmeetthe requirements were not utilized.
5.2 DryGas and Orifice Meters
All drygas meters used inthefieldwerecalibrated againstatransferstandarddrygas meterthat
is maintained in AirNova Inc.'s calibration data, The transfer standard gas meter is calibrated annually
and certified against an NISTtraceable Bell-type Proverwhich operates by liquid displacement.
Field dry gas meters and orifice meters are calibrated attwo month intervals atthe following
orifice metersettings:



## • 0,5 in. H2

### O 1.0 in. H2

### O



## • 1.5 in. H2

### O



## • 2.0 in. H2

### O
The initial and final volume readings and temperature readings were recorded forthe dry gas
meterandthe secondarystandardtest meterateach orifice metersetting. Adrygas metercorrection
factor [DGMCF) was calculated for each setting and the average DGMCF recorded,
Allcalibrationdocumentation isstored inadesignatedfiling cabinetforfuture reference, All repair
and maintenancedocumentationforeach meterisstored infilesthatprovideahistoryofeach meterand

AirNova, Inc, 12James RiverCogeneration Company June 

### 2010 

### aid in our preventative maintenance program. 

### 5.3 Nozzles Project No. 3338 Revision No. 

### 0



### Probe nozzles selected for isokinetic sampling were calibrated accordingto section 3.4.2 ofthe "QualityAssurance HandbookforAir Pollution Measurement Systems: Volume 111." The innerdiameter
of each nozzle was measured across three (3) distinct diameters with a micrometer caliper. The
calibrated nozzle diameteristhe average ofthese measurements. Each nozzle is identified uniquelyand
its calibrated diameterchecked priorto use. 

### 5.4 Thermocouples Thermocouples and thermometers utilized in the sampling program were calibrated everytwo
months according to section 3.4.2 ofthe "Quality Assurance for Air Pollution Measurement Systems:
Volume III." The calibration method includes comparing each field thermometer and thermocouple at differenttemperatures to an ASTM certified mercury-in-glass thermometer. The temperatures must
agree within the tolerances mentioned for the type of sampling equipment being calibrated. All the
calibration data is stored in a designated filing cabinetforfuture reference.
1. Stack Gas and Filter Housing Thermocouples and Thermometers Three temperatures are measured and extrapolated over the range of temperatures encountered infield operations. Thethreetemperatures usedfor calibration are: 1. Ice bath 2. Boiling point ofwater 3. Boiling point of cooking oil [or equivalent in solid salt bath)

2. ImpingerThermometers and Thermocouples Two temperatures are required to calibrate: 1. Ice bath 2. Stabilized room temperature

AirNova, Inc. 

### 3. Dry Gas Thermometers Two temperatures are required to calibrate: 1. Stabilized hotwater bath at approximately 104

- 122°F [40

-50°C) 2. Stabilized room temperature

13James River Cogeneration Company June 2010 

### 5.5 Labels Project No. 3338 Revision No. 0



### All samples collected as partofthe sampling program (silica gel desiccantsamples)were affixed
with labels which identifythe following:



## • Project No.



## • Date



## • Type ofsample



## • Run 

### No.



## • Sample location



## • Sample fraction
5.6 Chain-of-Custody Documentation Chain-of-custodydocumentation for all sampleswas implemented atthe completion ofsampling
and sample clean-up andwas documented untilthe sampleswere received bythe laboratoryforanalysis.
5.7 Calibration Gases NISTTraceable Protocol 1 grade 

### [±1%) 

### gas standardswere utilizedforcalibration ofthe O 2 

### and CO2 

### analyzers.

AirNova, Inc. 

### 14

### Appendix A
Field DataRackCal 

### James River Cogen Unit NO.2 Rack Cal Metals/PM-10

05/07110 08:00:49 02 -0.01 

### % R CO2 -0.24 

### % R 05/07/10 08:00:49 02 -0.01 

### % R CO2 0.00 

### % R 05/07/10 08:00:54 02 -0.01 

### % R CO2 -0.12 

### % R 05/07/10 08:00:59 02 0.00 

### % R CO2 -0.12 

### % R 05/07/10 08:01:04 02 0.01 

### % R CO2 -0.24 

### % R 05/07/10 08:01:09 02 0.01 

### % R CO2 -0.24 

### % R 05/07/10 08:01:14 02 0.00 

### % R CO2 0.00 

### % R 05/07/10 08:01 :19 02 0.01 

### % R CO2 -0.12 

### % R 05/07/10 08:01:24 02 13.42 

### % R CO2 -0.12 

### % R 05/07/10 08:01:29 02 12.93 

### % R CO2 0.00 

### % R 05/07/10 08:01:34 02 12.43 

### % 

### R CO2 0.00 

### % R 05/07/10 08:01:39 02 12.34 

### % R CO2 -0.12 

### % R 05/07/10 08:01:44 02 12.27 

### % R CO2 0.00 

### % R 05/07/10 08:01:49 02 12.22 

### % R CO2 0.12 

### % R 05/07/10 08:01:54 02 12.17 

### % R CO2 0.12 

### % R 05/07/10 08:01:59 02 11.80 

### % R CO2 -0.12 

### % R 05/07/10 08:02:04 02 20.29 

### % R CO2 6.59 

### % R 05/07/10 08:02:09 02 20.95 

### % R CO2 11.35 

### % R 05/07/10 08:02:14 02 21.14 

### % R CO2 12.33 

### % R 05/07/10 08:02:19 02 21.23 

### % 

### R CO2 12.21 

### % R 05/07/10 08:02:24 02 21.39 

### % R CO2 12.33 

### % 

### R 05/07/10 08:02:29 02 21.77 

### % R CO2 12.33 

### % R 05/07/10 08:02:34 02 21.79 

### % R CO2 12.21 

### % R 05/07/10 08:02:39 02 21.86 

### % 

### R CO2 12.33 

### % R 05/07/10 08:02:44 02 21.87 

### % R CO2 12.33 

### % R 05/07/10 08:02:49 02 21.89 

### % R CO2 12.33 

### % R 05/07/10 08:02:54 02 13.23 

### % R CO2 12.45 

### % R 05/07/10 08:02:59 02 0.42 

### % R CO2 12.08 

### % R 05/07/10 08:03:04 02 0.13 

### % R CO2 12.08 

### % R 05/07/10 08:03:09 02 0.10 

### % R CO2 13.06 

### % R 05/07/10 08:03:14 02 0.07 

### % R CO2 21.61 

### % R 05/07/10 08:03:19 02 0.06 

### % R CO2 22.34 

### % R 05/07/10 08:03:46 02 0.06 

### % R CO2 22.34 

### % R 05/07/10 08:03:46 02 0.04 

### % R CO2 22.22 

### % 

### R

1

### Pre1Bias 

### James River Cogen Unit NO.2 Pre Run 1 Bias Metals/PM-10

05/07/10 08:07:31 02 0.15 % R 

### CO2 0.00 % R 

### 05/07/10 08:07:34 02 0.15 % R 

### CO2 0.12 % R 

### 05/07/10 08:07:39 02 0.13 % R 

### CO2 0.00 % R 

### 05/07/10 08:07:44 02 0.13 % R 

### CO2 0.00 % R 

### 05/07/10 08:07:49 02 0.12 % R 

### CO2 0.00 % R 

### 05/07/10 08:07:54 02 0.12 % R 

### CO2 -0.12 % R 

### 05/07/10 08:07:59 02 0.12 % R 

### CO2 0.00 % R 

### 05/07/10 08:08:04 02 0.12 % R 

### CO2 -0.12 % R 

### 05/07/10 08:08:09 02 0.12 % R 

### CO2 0.00 % R 

### 05/07/10 08:08:14 02 0.11 % R 

### CO2 0.12 % R 

### 05/07/10 08:08:19 02 0.11 % R 

### CO2 0.12 % R 

### 05/07/10 08:08:24 02 0.13 % R 

### CO2 0.12 % R 

### 05/07/10 08:08:29 02 0.92 % R 

### CO2 1.34 % R 

### 05/07/10 08:08:34 02 1.72 % R 

### CO2 2.32 % R 

### 05/07/10 08:08:39 02 4.68 % R 

### CO2 3.42 % R 

### 05/07/10 08:08:44 02 7.43 % R 

### CO2 4.76 % R 

### 05/07/10 08:08:49 02 9.16 % R 

### CO2 5.74 % R 

### 05/07/10 08:08:54 02 10.33 % R 

### CO2 6.10 % R 

### 05/07110 08:08:59 02 11.06 % R 

### CO2 6.47 % R 

### 05/07/10 08:09:04 02 11.49 % R 

### CO2 6.84 % R 

### 05/07/10 08:09:09 02 11.84 % R 

### CO2 6.84 % R 

### 05/07/10 08:09:14 02 12.05 % R 

### CO2 6.96 % R 

### 05/07/10 08:09:19 02 12.22 % R 

### CO2 7.20 % R 

### 05/07/10 08:09:24 02 12.32 % R 

### CO2 7.08 % R 

### 05/07/10 08:09:29 02 12.38 % R 

### CO2 7.20 % R 

### 05/07/10 08:09:34 02 12.43 % R 

### CO2 7.08 % R 

### 05/07/10 08:09:39 02 12.45 % R 

### CO2 7.32 % R 

### 05/07/10 08:09:44 02 12.46 % R 

### CO2 7.20 % R 

### 05/07/10 08:09:49 02 12.48 % R 

### CO2 7.32 % R 

### 05/07/10 08:09:54 02 12.48 % R 

### CO2 7.45 % R 

### 05/07/10 08:09:59 02 12.49 % R 

### CO2 7.45 % R 

### 05/07/10 08:10:04 02 12.50 % R 

### CO2 7.57 % R 

### 05/07/10 08:10:09 02 12.50 % R 

### CO2 7.32 % R 

### 05/07/10 08:10:14 02 12.51 % R 

### CO2 7.57 % R 

### 05/07/10 08:10:19 02 12.51 % R 

### CO2 7.57 % R 

### 05/07/10 08:10:24 02 12.50 % R 

### CO2 7.20 % R 

### 05/07/10 08:10:29 02 12.48 % R 

### CO2 7.32 % R 

### 05/07/10 08:10:34 02 12.30 % R 

### CO2 7.57 % R 

### 05/07/10 08:10:39 02 13.87 % R 

### CO2 8.06 % R 

### 05/07/10 08:10:44 02 16.47 % R 

### CO2 9.28 % 

### R 05/07/10 08:10:49 02 18.53 % R 

### CO2 10.50 % R 

### 05/07/10 08:10:54 02 19.90 % R 

### CO2 11.11 % R 

### 05/07/10 08:10:59 02 20.67 % R 

### CO2 11.72 % R 

### 05/07/10 08:11 :04 02 21.19 % R 

### CO2 11.84 % R 

### 05/07/10 08:11 :09 02 21.41 % R 

### CO2 11.84 % R 

### 05/07/10 08:11 :14 02 21.62 % R 

### CO2 12.21 % R 

### 05/07/10 08:11:19 02 21.72 % R 

### CO2 12.33 % R 

### 05/07/10 08:11 :24 02 21.79 % R 

### CO2 12.70 % 

### R 05/07/10 08:11 :29 02 21.84 % R 

### CO2 12.45 % 

### R 05/07/10 08:11 :34 02 21.87 % R 

### CO2 12.45 % 

### R 205/07/10 05/07/10 05/07/10 

### 08:11 :39 08:11 :44 08:11 :49 02 21.89 02 21.89 02 20.07 % % % R R R



### 3 C02 12.45 C02 12.45 

### C02 12.21 % % % R R RRun1 

### James River Cogen Unit NO.2 Run NO.1 Metals/PM-10

05/07110 08:13:09 02 5.83 % R CO2 13.55 % R 05/07/10 08:13:19 02 5.77 % R CO2 13.67 % R 05/07/10 08:13:29 02 5.76 % R CO2 13.67 % R 05/07/10 08:13:39 02 5.74 % R CO2 13.67 % R 05/07/10 08:13:49 02 5.71 % R CO2 13.67 % R 05/07/10 08:13:59 02 5.68 % R CO2 13.67 % R 05/07/10 08:14:09 02 5.63 % R CO2 13.55 % R 05/07/10 08:14:19 02 5.59 % R CO2 13.67 % R 05/07/10 08:14:29 02 5.57 % R CO2 13.55 % R 05/07/10 08:14:39 02 5.53 % R CO2 13.79 % R 05/07/10 08:14:49 02 5.52 % R CO2 13.67 % R 05/07/10 08:14:59 02 5.46 % R CO2 13.67 % R 05/07110 08:15:09 02 5.46 % R CO2 13.79 % R 05/07/10 08:15:19 02 5.49 % R CO2 13.67 % R 05/07/10 08:15:29 02 5.54 % R CO2 13.79 % R 05/07/10 08:15:39 02 5.58 % R CO2 13.79 % R 05/07/10 08:15:50 02 5.63 % R CO2 13.55 % R 05/07/10 08:15:59 02 5.66 % R CO2 13.67 % R 05/07/10 08:16:09 02 5.70 % R CO2 13.67 % R 05/07/10 08:16:19 02 5.70 % R CO2 13.79 % R 05/07/10 08:16:29 02 5.66 % R CO2 13.55 % R 05/07/10 08:16:39 02 5.65 % R CO2 13.67 % R 05/07/10 08:16:49 02 5.66 % R CO2 13.79 % R 05/07/10 08:16:59 02 5.70 % R CO2 13.67 % R 05/07/10 08:17:09 02 5.70 % R CO2 13.55 % R 05/07/10 08:17:19 02 5.68 % R CO2 13.31 % R 05/07/10 08:17:29 02 5.68 % R CO2 13.43 % R 05/07/10 08:17:39 02 5.70 % R CO2 13.55 % R 05/07/10 08:17:49 02 5.73 % R CO2 13.43 % R 05/07/10 08:17:59 02 5.71 % R CO2 13.67 % R 05/07/10 08:18:09 02 5.68 % R CO2 13.67 % R 05/07/10 08:18:19 02 5.65 % R CO2 13.67 % R 05/07/10 08:18:29 02 5.66 % R CO2 13.92 % R 05/07/10 08:18:39 02 5.70 % R CO2 13.55 % R 05/07/10 08:18:49 02 5.71 % R CO2 13.55 % R 05/07/10 08:18:59 02 5.71 % R CO2 13.55 % R 05/07/10 08:19:09 02 5.74 % R CO2 13.43 % R 05/07/10 08:19:19 02 5.76 % R CO2 13.79 % R 05/07/10 08:19:29 02 5.77 % R CO2 13.55 % R 05/07/10 08:19:39 02 5.74 % R CO2 13.67 % R 05/07/10 08:19:49 02 5.69 % R CO2 13.31 % R 05/07/10 08:19:59 02 5.64 % R CO2 13.67 % R 05/07/10 08:20:09 02 5.62 % R CO2 13.79 % R 05/07/10 08:20:19 02 5.63 % R CO2 13.67 % R 05/07/10 08:20:29 02 5.62 % R CO2 13.79 % R 05/07/10 08:20:39 02 5.62 % R CO2 13.67 % R 05/07/10 08:20:49 02 5.63 % R CO2 13.55 % R 05/07/10 08:20:59 02 5.65 % R CO2 13.67 % R 05/07/10 08:21:09 02 5.71 % R CO2 13.67 % R 05/07/10 08:21:19 02 5.75 % R CO2 13.43 % R 

### 405/07/10 

### 08:21:29 02 5.76 % R 

### CO2 13.43 % R 05/07/10 

### 08:21:39 02 5.79 % R 

### CO2 13.55 % R 05/07/10 

### 08:21 :49 02 5.82 % R 

### CO2 13.67 % R 05/07/10 

### 08:21:59 02 5.82 % R 

### CO2 13.55 % R 05/07/10 

### 08:22:09 02 5.79 % R 

### CO2 13.67 % R 05/07/10 

### 08:22:19 02 5.76 % R 

### CO2 13.67 % R 05/07/10 

### 08:22:29 02 5.74 % R 

### CO2 13.67 % R 05/07/10 

### 08:22:39 02 5.74 % R 

### CO2 13.55 % R 05/07/10 

### 08:22:49 02 5.73 % R 

### CO2 13.67 % R 05/07/10 

### 08:22:59 02 5.69 % R 

### CO2 13.67 % 

### R 05/07/10 

### 08:23:09 02 5.69 % R 

### CO2 13.67 % R 05/07/10 

### 08:23:19 02 5.69 % R 

### CO2 13.67 % R 05/07/10 

### 08:23:29 02 5.70 % R 

### CO2 13.55 % 

### R 05/07/10 

### 08:23:39 02 5.73 % R 

### CO2 13.67 % 

### R 05/07/10 

### 08:23:49 02 5.69 % R 

### CO2 13.55 % 

### R 05/07/10 

### 08:23:59 02 5.62 % R 

### CO2 13.55 % 

### R 05/07/10 

### 08:24:09 02 5.57 % R 

### CO2 13.55 % 

### R 05/07/10 

### 08:24:19 02 5.55 % R 

### CO2 13.92 % R 05/07/10 

### 08:24:29 02 5.57 % R 

### CO2 13.31 % 

### R 05/07/10 

### 08:24:39 02 5.59 % R 

### CO2 13.67 % 

### R 05/07/10 

### 08:24:49 02 5.59 % R 

### CO2 13.67 % 

### R 05/07110 

### 08:24:59 02 5.57 % R 

### CO2 13.67 % 

### R 05/07/10 

### 08:25:09 02 5.55 % R 

### CO2 13.79 % 

### R 05/07/10 

### 08:25:19 02 5.54 % R 

### CO2 13.67 % R 05/07/10 

### 08:25:29 02 5.53 % R 

### CO2 13.92 % 

### R 05/07/10 

### 08:25:39 02 5.53 % R 

### CO2 13.67 % R 05/07/10 

### 08:25:49 02 5.53 % R 

### CO2 13.67 % 

### R 05/07/10 

### 08:25:59 02 5.53 % R 

### CO2 13.67 % 

### R 05/07/10 

### 08:26:09 02 5.55 % R 

### CO2 13.67 % 

### R 05/07/10 

### 08:26:19 02 5.57 % R 

### CO2 13.79 % R 05/07/10 

### 08:26:29 02 5.57 % R 

### CO2 13.79 % R 05/07/10 

### 08:26:39 02 5.57 % R 

### CO2 13.67 % R 05/07/10 

### 08:26:49 02 5.59 % R 

### CO2 13.55 % R 05/07/10 

### 08:26:59 02 5.63 % R 

### CO2 13.43 % 

### R 05/07/10 

### 08:27:09 02 5.64 % R 

### CO2 13.67 % 

### R 05/07/10 

### 08:27:19 02 5.63 % R 

### CO2 13.55 % R 05/07/10 

### 08:27:29 02 5.65 % R 

### CO2 13.79 % R 05/07/10 

### 08:27:39 02 5.65 % R 

### CO2 13.55 % R 05/07/10 

### 08:27:49 02 5.66 % R 

### CO2 13.31 % R 05/07/10 

### 08:27:59 02 5.69 % R 

### CO2 13.67 % R 05/07/10 

### 08:28:09 02 5.73 % R 

### CO2 13.67 % 

### R 05/07/10 

### 08:28:19 02 5.80 % R 

### CO2 13.43 % R 05/07/10 

### 08:28:29 02 5.90 % R 

### CO2 13.18 % 

### R 05/07/10 

### 08:28:39 02 5.94 % R 

### CO2 13.31 % R 05/07/10 

### 08:28:49 02 5.93 % R 

### CO2 13.43 % R 05/07/10 

### 08:28:59 02 5.90 % R 

### CO2 13.31 % 

### R 05/07/10 

### 08:29:09 02 7.75 % R 

### CO2 13.31 % R 05/07/10 

### 08:29:19 02 5.90 % R 

### CO2 13.31 % R 05/07/10 

### 08:29:29 02 5.91 % R 

### CO2 13.31 % 

### R 05/07/10 

### 08:29:39 02 5.91 % R 

### CO2 13.43 % R 05/07/10 

### 08:29:49 02 5.91 % R 

### CO2 13.43 % R 05/07/10 

### 08:29:59 02 5.92 % R 

### CO2 13.43 % R 05/07/10 

### 08:30:09 02 5.93 % R 

### CO2 13.43 % R 05/07/10 

### 08:30:19 02 5.94 % R 

### CO2 13.31 % 

### R 5

### 05/07/10 08:30:29 02 5.91 % R 

### CO2 13.43 % R 

### 05/07/10 08:30:39 02 5.83 % R 

### CO2 13.18 % R 

### 05/07/10 08:30:49 02 5.75 % R 

### CO2 13.67 % R 

### 05/07/10 08:30:59 02 5.66 % R 

### CO2 13.67 % R 

### 05/07/10 08:31:09 02 5.60 % R 

### CO2 13.79 % R 

### 05/07/10 08:31:19 02 5.57 % R 

### CO2 13.79 % R 

### 05/07/10 08:31 :29 02 5.55 % R 

### CO2 13.67 % R 

### 05/07/10 08:31:39 02 5.59 % R 

### CO2 13.79 % R 

### 05/07/10 08:31:49 02 5.64 % R 

### CO2 13.67 % R 

### 05/07/10 08:31:59 02 5.68 % R 

### CO2 13.67 % R 

### 05/07/10 08:32:09 02 5.70 % R 

### CO2 13.79 % R 

### 05/07/10 08:32:19 02 5.69 % R 

### CO2 13.67 % R 

### 05/07/10 08:32:29 02 5.65 % R 

### CO2 13.79 % R 

### 05/07/10 08:32:39 02 5.62 % R 

### CO2 13.67 % R 

### 05/07/10 08:32:49 02 5.59 % R 

### CO2 13.79 % R 

### 05/07/10 08:32:59 02 5.55 % R 

### CO2 13.43 % R 

### 05/07/10 08:33:09 02 5.52 % R 

### CO2 13.79 % R 

### 05/07/10 08:33:19 02 5.47 % R 

### CO2 13.55 % R 

### 05/07/10 08:33:29 02 5.42 % R 

### CO2 13.79 % R 

### 05/07/10 08:33:39 02 5.41 % R 

### CO2 13.67 % R 

### 05/07/10 08:33:49 02 5.40 % R 

### CO2 13.92 % R 

### 05/07/10 08:33:59 02 5.41 % R 

### CO2 13.79 % R 

### 05/07/10 08:34:09 02 5.41 % R 

### CO2 13.92 % R 

### 05/07/10 08:34:19 02 5.46 % R 

### CO2 13.92 % R 

### 05/07/10 08:34:29 02 5.54 % R 

### CO2 13.92 % R 

### 05/07/10 08:34:39 02 5.62 % R 

### CO2 13.55 % R 

### 05/07/10 08:34:49 02 5.69 % R 

### CO2 13.55 % R 

### 05/07/10 08:34:59 02 5.75 % R 

### CO2 13.67 % R 

### 05/07/10 08:35:09 02 5.76 % R 

### CO2 13.31 % R 

### 05/07/10 08:35:19 02 5.70 % R 

### CO2 13.55 % R 

### 05/07/10 08:35:29 02 5.63 % R 

### CO2 13.67 % R 

### 05/07/10 08:35:39 02 5.58 % R 

### CO2 13.67 % R 

### 05/07/10 08:35:49 02 5.52 % R 

### CO2 13.67 % R 

### 05/07/10 08:35:59 02 5.49 % R 

### CO2 13.67 % R 

### 05/07/10 08:36:09 02 5.49 % R 

### CO2 13.92 % R 

### 05/07/10 08:36:19 02 5.52 % R 

### CO2 13.92 % R 

### 05/07/10 08:36:29 02 5.54 % R 

### CO2 13.55 % R 

### 05/07/10 08:36:39 02 5.57 % R 

### CO2 13.67 % R 

### 05/07/10 08:36:49 02 5.59 % R 

### CO2 13.92 % R 

### 05/07/10 08:36:59 02 5.60 % R 

### CO2 13.79 % R 

### 05/07/10 08:37:09 02 5.57 % R 

### CO2 13.67 % R 

### 05/07/10 08:37:19 02 5.54 % R 

### CO2 13.79 % R 

### 05/07/10 08:37:29 02 5.49 % R 

### CO2 13.79 % R 

### 05/07/10 08:37:39 02 5.47 % R 

### CO2 13.92 % R 

### 05/07/10 08:37:49 02 5.47 % R 

### CO2 14.04 % R 

### 05/07/10 08:37:59 02 5.48 % R 

### CO2 13.79 % R 

### 05/07/10 08:38:09 02 5.48 % R 

### CO2 13.67 % R 

### 05/07/10 08:38:19 02 5.49 % R 

### CO2 13.67 % R 

### 05/07/10 08:38:29 02 5.51 % R 

### CO2 13.55 % R 

### 05/07/10 08:38:39 02 5.52 % R 

### CO2 13.55 % R 

### 05/07/10 08:38:49 02 5.52 % R 

### CO2 13.92 % R 

### 05/07/10 08:38:59 02 5.53 % R 

### CO2 13.67 % R 

### 05/07/10 08:39:09 02 5.55 % R 

### CO2 13.55 % R 

### 05/07/10 08:39:19 02 5.58 % R 

### CO2 13.67 % R 

### 6

### 05/07/10 08:39:29 02 5.62 % R 

### CO2 13.79 % R 

### 05/07/10 08:39:39 02 5.63 % R 

### CO2 13.55 % R 

### 05/07/10 08:39:49 02 5.65 % R 

### CO2 13.55 % R 

### 05/07/10 08:39:59 02 5.69 % R 

### CO2 13.67 % R 

### 05/07/10 08:40:09 02 5.74 % R 

### CO2 13.55 % R 

### 05/07/10 08:40:19 02 5.81 % R 

### CO2 13.55 % R 

### 05/07/10 08:40:29 02 5.86 % R 

### CO2 13.55 % R 

### 05/07/10 08:40:39 02 5.92 % R 

### CO2 13.31 % R 

### 05/07/10 08:40:49 02 5.97 % R 

### CO2 13.43 % R 

### 05/07/10 08:40:59 02 6.01 % R 

### CO2 13.43 % R 

### 05/07/10 08:41:09 02 6.01 % R 

### CO2 13.55 % R 

### 05/07/10 08:41:19 02 5.94 % R 

### CO2 13.31 % R 

### 05/07/10 08:41:29 02 5.87 % R 

### CO2 13.43 % R 

### 05/07/10 08:41:39 02 5.81 % R 

### CO2 13.79 % R 

### 05/07/10 08:41:49 02 5.77 % R 

### CO2 13.31 % R 

### 05/07/10 08:41:59 02 5.77 % R 

### CO2 13.43 % R 

### 05/07/10 08:42:09 02 5.80 % R 

### CO2 13.43 % R 

### 05/07/10 08:42:19 02 5.86 % R 

### CO2 13.55 % R 

### 05/07/10 08:42:29 02 5.94 % R 

### CO2 13.43 % R 

### 05/07/10 08:42:39 02 5.99 % R 

### CO2 13.18 % R 

### 05/07/10 08:42:49 02 5.99 % R 

### CO2 13.31 % R 

### 05/07/10 08:42:59 02 5.96 % R 

### CO2 13.55 % R 

### 05/07/10 08:43:09 02 5.93 % R 

### CO2 13.43 % R 

### 05/07/10 08:43:19 02 5.92 % R 

### CO2 13.55 % R 

### 05/07/10 08:43:29 02 5.86 % R 

### CO2 13.18 % R 

### 05/07/10 08:43:39 02 5.80 % R 

### CO2 13.31 % R 

### 05/07/10 08:43:49 02 5.74 % R 

### CO2 13.55 % R 

### 05/07/10 08:43:59 02 5.70 % R 

### CO2 13.55 % R 

### 05/07/10 08:44:09 02 5.73 % R 

### CO2 13.67 % R 

### 05/07/10 08:44:19 02 5.76 % R 

### CO2 13.55 % R 

### 05/07/10 08:44:29 02 5.80 % R 

### CO2 13.67 % R 

### 05/07/10 08:44:39 02 5.81 % R 

### CO2 13.31 % R 

### 05/07/10 08:44:49 02 5.81 % R 

### CO2 13.43 % R 

### 05/07/10 08:44:59 02 5.83 % R 

### CO2 13.67 % R 

### 05/07/10 08:45:09 02 5.86 % R 

### CO2 13.31 % R 

### 05/07/10 08:45:19 02 5.87 % R 

### CO2 13.55 % R 

### 05/07/10 08:45:29 02 5.83 % R 

### CO2 13.31 % R 

### 05/07/10 08:45:39 02 5.81 % R 

### CO2 13.55 % R 

### 05/07/10 08:45:49 02 5.79 % R 

### CO2 13.67 % R 

### 05/07/10 08:45:59 02 5.76 % R 

### CO2 13.43 % R 

### 05/07/10 08:46:09 02 5.75 % R 

### CO2 13.55 % R 

### 05/07/10 08:46:19 02 5.74 % R 

### CO2 13.31 % R 

### 05/07/10 08:46:29 02 5.75 % R 

### CO2 13.43 % R 

### 05/07/10 08:46:39 02 5.76 % R 

### CO2 13.67 % R 

### 05/07/10 08:46:49 02 5.80 % R 

### CO2 13.43 % R 

### 05/07/10 08:46:59 02 5.79 % R 

### CO2 13.43 % R 

### 05/07/10 08:47:09 02 5.76 % R 

### CO2 13.43 % R 

### 05/07/10 08:47:19 02 5.71 % R 

### CO2 13.55 % R 

### 05/07/10 08:47:29 02 5.71 % R 

### CO2 13.67 % R 

### 05/07/10 08:47:39 02 5.73 % R 

### CO2 13.67 % R 

### 05/07/10 08:47:49 02 5.76 % R 

### CO2 13.67 % R 

### 05/07/10 08:47:59 02 5.80 % R 

### CO2 13.31 % R 

### 05/07/10 08:48:09 02 5.82 % R 

### CO2 13.55 % R 

### 05/07/10 08:48:19 02 5.85 % R 

### CO2 13.92 % R 

### 705/07/10 08:48:29 02 5.87 % 

### R CO2 13.43 % 

### R 05/07/10 08:48:39 02 5.87 % 

### R CO2 13.43 % 

### R 05/07/10 08:48:49 02 5.82 % 

### R CO2 13.55 % 

### R 05/07/10 08:48:59 02 5.77 % 

### R CO2 13.31 % 

### R 05/07/10 08:49:09 02 5.75 % 

### R CO2 13.55 % 

### R 05/07/10 08:49:19 02 5.74 % 

### R CO2 13.67 % 

### R 05/07/10 08:49:29 02 5.69 % 

### R CO2 13.67 % 

### R 05/07/10 08:49:39 02 5.65 % 

### R CO2 13.43 % 

### R 05/07/10 08:49:49 02 5.57 % 

### R CO2 13.55 % 

### R 05/07/10 08:49:59 02 5.49 % 

### R CO2 13.43 % 

### R 05/07/10 08:50:09 02 5.44 % 

### R CO2 13.67 % 

### R 05/07/10 08:50:19 02 5.42 % 

### R CO2 13.92 % 

### R 05/07/10 08:50:29 02 5.41 % 

### R CO2 13.92 % 

### R 05/07/10 08:50:39 02 5.42 % 

### R CO2 13.67 % 

### R 05/07/10 08:50:49 02 5.49 % 

### R CO2 13.67 % 

### R 05/07/10 08:50:59 02 5.57 % 

### R CO2 13.67 % 

### R 05/07/10 08:51:09 02 5.66 % 

### R CO2 13.55 % 

### R 05/07/10 08:51:19 02 5.74 % 

### R CO2 13.43 % 

### R 05/07/10 08:51:29 02 5.74 % 

### R CO2 13.55 % 

### R 05/07/10 08:51:39 02 5.75 % 

### R CO2 13.55 % 

### R 05/07/10 08:51 :49 02 5.79 % 

### R CO2 13.67 % 

### R 05/07/10 08:51:59 02 5.81 % 

### R CO2 13.43 % 

### R 05/07/10 08:52:09 02 5.81 % 

### R CO2 13.43 % 

### R 05/07/10 08:52:19 02 5.81 % 

### R CO2 13.43 % 

### R 05/07/10 08:52:29 02 5.82 % 

### R CO2 13.55 % 

### R 05/07/10 08:52:39 02 5.86 % 

### R CO2 13.43 % 

### R 05/07/10 08:52:49 02 5.86 % 

### R CO2 13.43 % 

### R 05/07/10 08:52:59 02 5.82 % 

### R CO2 13.43 % 

### R 05/07/10 08:53:09 02 5.77 % 

### R CO2 13.43 

### % 

### R 05/07/10 08:53:19 02 5.74 

### % 

### R CO2 13.67 

### % 

### R 05/07/10 08:53:29 02 5.74 

### % 

### R CO2 13.18 

### % 

### R 05/07/10 08:53:39 02 5.76 

### % 

### R CO2 13.43 

### % 

### R 05/07/10 08:53:49 02 5.79 

### % 

### R CO2 13.67 

### % 

### R 05/07/10 08:53:59 02 5.80 

### % 

### R CO2 13.55 

### % 

### R 05/07/10 08:54:09 02 5.80 

### % 

### R CO2 13.92 

### % 

### R 05/07/10 08:54:19 02 5.80 

### % 

### R CO2 13.67 

### % 

### R 05/07/10 08:54:29 02 5.76 

### % 

### R CO2 13.55 

### % 

### R 05/07/10 08:54:39 02 5.71 

### % 

### R CO2 13.55 

### % 

### R 05/07/10 08:54:49 02 5.69 

### % 

### R CO2 13.55 

### % 

### R 05/07/10 08:54:59 02 5.69 

### % 

### R CO2 13.67 % 

### R 05/07/10 08:55:09 02 5.70 % 

### R CO2 13.67 

### % 

### R 05/07/10 08:55:19 02 5.66 

### % 

### R CO2 13.55 

### % 

### R 05/07/10 08:55:29 02 5.62 % 

### R CO2 13.67 % 

### R 05/07/10 08:55:39 02 5.55 % 

### R CO2 13.55 % 

### R 05/07/10 08:55:49 02 5.52 

### % 

### R CO2 13.55 

### % 

### R 05/07/10 08:55:59 02 5.48 % 

### R CO2 13.79 % 

### R 05/07/10 08:56:09 02 5.46 % 

### R CO2 13.79 % 

### R 05/07/10 08:56:19 02 5.46 

### % 

### R CO2 13.79 

### % 

### R 05/07/10 08:56:29 02 5.43 % 

### R CO2 13.92 

### % 

### R 05/07/10 08:56:39 02 5.38 % 

### R CO2 13.92 % 

### R 05/07/10 08:56:49 02 5.35 

### % 

### R CO2 13.79 

### % 

### R 05/07/10 08:56:59 02 5.32 % 

### R CO2 13.79 

### % 

### R 05/07/10 08:57:09 02 5.29 

### % 

### R CO2 13.79 % 

### R 05/07/10 08:57:19 02 5.27 

### % 

### R CO2 13.79 

### % 

### R 805/07/10 

### 08:57:29 02 5.30 % R 

### CO2 13.92 % R 05107/10 

### 08:57:39 02 5.33 % R 

### CO2 13.79 % R 05/07/10 

### 08:57:49 02 5.38 % R 

### CO2 13.92 % R 05/07/10 

### 08:57:59 02 5.44 % R 

### CO2 13.92 % R 05/07/10 

### 08:58:09 02 5.49 % R 

### CO2 13.55 % R 05/07/10 

### 08:58:19 02 5.52 % R 

### CO2 13.67 % R 05/07/10 

### 08:58:29 02 5.52 % R 

### CO2 13.92 % R 05/07/10 

### 08:58:39 02 5.51 % R 

### CO2 13.67 % R 05/07/10 

### 08:58:49 02 5.51 % R 

### CO2 13.67 % R 05/07/10 

### 08:58:59 02 5.53 % R 

### CO2 13.79 % R 05/07/10 

### 08:59:09 02 5.58 % R 

### CO2 13.92 % R 05/07/10 

### 08:59:19 02 5.64 % R 

### CO2 13.67 % R 05/07/10 

### 08:59:29 02 5.71 % R 

### CO2 13.79 % R 05/07/10 

### 08:59:39 02 5.73 % R 

### CO2 13.55 % R 05/07/10 

### 08:59:49 02 5.69 % R 

### CO2 13.55 % R 05/07/10 

### 08:59:59 02 5.63 % R 

### CO2 13.55 % R 05/07/10 

### 09:00:09 02 5.57 % R 

### CO2 13.67 % R 05/07/10 

### 09:00:19 02 5.53 % R 

### CO2 13.79 % R 05/07/10 

### 09:00:29 02 5.53 % R 

### CO2 13.67 % R 05/07/10 

### 09:00:39 02 5.55 % R 

### CO2 13.55 % R 05/07/10 

### 09:00:49 02 5.58 % R 

### CO2 13.55 % R 05/07/10 

### 09:00:59 02 5.59 % R 

### CO2 13.67 % R 05/07/10 

### 09:01:09 02 5.60 % R 

### CO2 13.67 % R 05/07/10 

### 09:01:19 02 5.59 % R 

### CO2 13.92 % R 05/07/10 

### 09:01:29 02 5.60 % R 

### CO2 13.79 % R 05/07/10 

### 09:01:39 02 5.59 % R 

### CO2 13.79 % R 05/07/10 

### 09:01:49 02 5.55 % R 

### CO2 13.92 % R 05/07/10 

### 09:01:59 02 5.53 % R 

### CO2 13.67 % R 05/07/10 

### 09:02:09 02 5.48 % R 

### CO2 13.79 % R 05/07/10 

### 09:02:19 02 5.42 % R 

### CO2 13.92 % R 05/07/10 

### 09:02:29 02 5.33 % R 

### CO2 14.04 % R 05/07/10 

### 09:02:39 02 5.27 % R 

### CO2 14.04 % R 05/07/10 

### 09:02:49 02 5.22 % R 

### CO2 14.04 % R 05/07/10 

### 09:02:59 02 5.20 % R 

### CO2 13.79 % R 05/07/10 

### 09:03:09 02 5.21 % R 

### CO2 14.16 % R 05/07/10 

### 09:03:19 02 5.22 % R 

### CO2 14.04 % R 05/07/10 

### 09:03:29 02 5.22 % R 

### CO2 14.04 % R 05/07/10 

### 09:03:39 02 5.24 % R 

### CO2 13.79 % R 05/07/10 

### 09:03:49 02 5.24 % R 

### CO2 13.92 % R 05/07/10 

### 09:03:59 02 5.26 % R 

### CO2 14.04 % R 05/07/10 

### 09:04:09 02 5.31 % R 

### CO2 13.92 % R 05/07/10 

### 09:04:19 02 5.35 % R 

### CO2 13.79 % R 05/07/10 

### 09:04:29 02 5.38 % R 

### CO2 14.04 % R 05/07/10 

### 09:04:39 02 5.40 % R 

### CO2 13.79 % R 05/07/10 

### 09:04:49 02 5.41 % R 

### CO2 13.92 % R 05/07/10 

### 09:04:59 02 5.46 % R 

### CO2 13.92 % R 05/07/10 

### 09:05:09 02 5.51 % R 

### CO2 13.92 % R 05/07/10 

### 09:05:19 02 5.57 % R 

### CO2 13.79 % R 05/07/10 

### 09:05:29 02 5.59 % R 

### CO2 13.67 % R 05/07/10 

### 09:05:39 02 5.58 % R 

### CO2 13.79 % R 05/07/10 

### 09:05:49 02 5.54 % R 

### CO2 13.67 % R 05/07/10 

### 09:05:59 02 5.47 % R 

### CO2 13.92 % R 05/07/10 

### 09:06:09 02 5.41 % R 

### CO2 13.92 % R 05/07/10 

### 09:06:19 02 5.36 % R 

### CO2 14.04 % R 905/07/10 09:06:29 02 5.32 % R CO2 14.04 % R 05/07/10 09:06:39 02 5.27 % R CO2 13.92 % R 05/07/10 09:06:49 02 5.25 % R CO2 14.04 % R 05/07/10 09:06:59 02 5.24 % R CO2 13.92 % R 05/07/10 09:07:09 02 5.22 % R CO2 13.79 % R 05/07/10 09:07:19 02 5.16 % R CO2 13.92 % R 05/07/10 09:07:29 02 5.07 

### % R CO2 14.04 

### % R 05/07/10 09:07:39 02 4.96 

### % R CO2 14.04 % R 05/07/10 09:07:49 02 4.90 

### % R CO2 14.16 % R 05/07/10 09:07:59 02 4.86 

### % R CO2 14.16 % R 05/07/10 09:08:09 02 4.83 

### % R CO2 14.40 % R 05/07/10 09:08:19 02 4.81 % R CO2 14.16 % R 05/07/10 09:08:29 02 4.77 % R CO2 14.40 % R 05/07/10 09:08:39 02 4.77 % R CO2 14.28 % R 05/07/10 09:08:49 02 4.77 % R CO2 14.28 % R 05/07/10 09:08:59 02 4.81 % R CO2 14.40 % R 05/07/10 09:09:09 02 4.93 % R CO2 14.40 % R 05/07/10 09:09:19 02 5.10 % R CO2 14.16 % R 05/07/10 09:09:29 02 5.29 % R CO2 14.16 % R 05/07/10 09:09:39 02 5.48 % R CO2 13.79 % R 05/07/10 09:09:49 02 5.60 % R CO2 13.79 % R 05/07/10 09:09:59 02 5.64 % R CO2 14.04 % R 05/07/10 09:10:09 02 5.62 

### % R CO2 13.79 % R 05/07/10 09:10:19 02 5.58 % R CO2 13.79 % R 05/07/10 09:10:29 02 5.55 

### % R CO2 13.79 % R 05/07/10 09:10:39 02 5.53 

### % R CO2 13.92 % R 05/07/10 09:10:49 02 5.46 % R CO2 13.79 % R 05/07/10 09:10:59 02 5.36 

### % R CO2 13.92 % R 05/07/10 09:11:09 02 5.25 % R CO2 14.16 % R 05/07/10 09:11:19 02 5.18 

### % R CO2 14.16 % R 05/07/10 09:11 :29 02 5.16 

### % R CO2 13.92 % R 05/07/10 09:11 :39 02 5.18 

### % R CO2 14.04 % R 05/07/10 09:11:49 02 5.20 

### % R CO2 14.16 % R 05/07/10 09:11 :59 02 5.21 

### % R CO2 14.28 % R 05/07/10 09:12:09 02 5.24 

### % R CO2 14.04 % R 05/07/10 09:12:19 02 5.26 

### % R CO2 13.79 % R 05/07/10 09:12:29 02 5.30 

### % R CO2 13.79 % R 05/07/10 09:12:39 02 5.32 

### % R CO2 13.79 % R 05/07/10 09:12:49 02 5.33 

### % R CO2 14.04 % R 05/07/10 09:12:59 02 5.33 % R CO2 13.92 % R 05/07/10 09:13:09 02 5.33 % R CO2 14.04 % R 05/07/10 09:13:19 02 5.35 % R CO2 13.92 % R 05/07/10 09:13:29 02 5.36 % R CO2 13.92 % R 05/07/10 09:13:39 02 5.33 % R CO2 13.79 % R 05/07/10 09:13:49 02 5.32 % R CO2 13.92 % R 05/07/10 09:13:59 02 5.32 % R CO2 13.92 % R 05/07/10 09:14:09 02 5.35 

### % R CO2 13.67 % R 05/07/10 09:14:19 02 5.36 

### % R CO2 13.92 % R 05/07/10 09:14:29 02 5.35 

### % R CO2 14.04 % R 05/07/10 09:14:39 02 5.36 % R CO2 13.92 % R 05/07/10 09:14:49 02 5.41 % R CO2 13.79 % R 05/07/10 09:14:59 02 5.43 % R CO2 13.79 % R 05/07/10 09:15:09 02 5.58 % R CO2 13.67 % R 05/07/10 09:15:19 02 5.51 

### % R CO2 13.67 

### % R 10

### 05/07/10 09:15:29 02 5.51 % R 

### CO2 13.67 % R 

### 05/07/10 09:15:39 02 5.48 % R 

### CO2 13.67 % R 

### 05/07/10 09:15:49 02 5.46 % R 

### CO2 13.67 % R 

### 05/07/10 09:15:59 02 5.47 % R 

### CO2 14.04 % 

### R 05/07/10 09:16:09 02 5.47 % R 

### CO2 13.92 % R 

### 05/07/10 09:16:19 02 5.51 % R 

### CO2 13.79 % R 

### 05/07/10 09:16:29 02 5.53 % R 

### CO2 13.92 % R 

### 05/07/10 09:16:39 02 5.54 % R 

### CO2 13.67 % R 

### 05/07/10 09:16:49 02 5.53 % R 

### CO2 13.67 % R 

### 05/07/10 09:16:59 02 5.53 % R 

### CO2 13.67 % R 

### 05/07/10 09:17:09 02 5.54 % R 

### CO2 13.79 % R 

### 05/07/10 09:17:19 02 5.55 % R 

### CO2 13.67 % R 

### 05/07/10 09:17:29 02 5.55 % R 

### CO2 13.67 % R 

### 05/07/10 09:17:39 02 5.55 % R 

### CO2 13.67 % R 

### 05/07/10 09:17:49 02 5.53 % R 

### CO2 14.04 % R 

### 05/07/10 09:17:59 02 5.52 % R 

### CO2 13.79 % R 

### 05/07/10 09:18:09 02 5.51 % R 

### CO2 13.92 % R 

### 05/07/10 09:18:19 02 5.44 % R 

### CO2 14.04 % R 

### 05/07/10 09:18:29 02 5.37 % R 

### CO2 13.92 % R 

### 05/07/10 09:18:39 02 5.27 % R 

### CO2 13.79 % R 

### 05/07/10 09:18:49 02 5.20 % R 

### CO2 14.40 % R 

### 05/07/10 09:18:59 02 5.15 % R 

### CO2 14.16 % R 

### 05/07/10 09:19:09 02 5.14 % R 

### CO2 13.92 % R 

### 05/07/10 09:19:19 02 5.10 % R 

### CO2 14.28 % R 

### 05/07/10 09:19:29 02 5.00 % R 

### CO2 14.40 % R 

### 05/07/10 09:19:39 02 4.97 % R 

### CO2 14.16 % R 

### 05/07/10 09:19:49 02 4.97 % R 

### CO2 14.16 % R 

### 05/07/10 09:19:59 02 5.00 % R 

### CO2 14.28 % R 

### 05/07/10 09:20:09 02 5.04 % R 

### CO2 14.04 % R 

### 05/07/10 09:20:19 02 5.09 % R 

### CO2 14.28 % R 

### 05/07/10 09:20:29 02 5.13 % R 

### CO2 14.16 % R 

### 05/07/10 09:20:39 02 5.11 % R 

### CO2 14.04 % R 

### 05/07/10 09:20:49 02 5.09 % R 

### CO2 13.92 % R 

### 05/07/10 09:20:59 02 5.04 % R 

### CO2 14.28 % R 

### 05/07/10 09:21:09 02 5.03 % R 

### CO2 14.16 % 

### R 05/07/10 09:21:19 02 5.07 % R 

### CO2 14.04 % R 

### 05/07/10 09:21 :29 02 5.10 % R 

### CO2 14.16 % R 

### 05/07/10 09:21:39 02 5.13 % R 

### CO2 14.16 % R 

### 05/07/10 09:21:49 02 5.10 % R 

### CO2 14.16 % R 

### 05/07/10 09:21:59 02 5.07 % R 

### CO2 14.04 % R 

### 05/07/10 09:22:09 02 5.03 % R 

### CO2 14.16 % R 

### 05/07/10 09:22:19 02 4.99 % R 

### CO2 14.40 % R 

### 05/07/10 09:22:29 02 5.00 % R 

### CO2 14.16 % R 

### 05/07/10 09:22:39 02 5.04 % R 

### CO2 14.28 % R 

### 05/07/10 09:22:49 02 5.10 % R 

### CO2 14.04 % R 

### 05/07/10 09:22:59 02 5.15 % R 

### CO2 14.16 % R 

### 05/07/10 09:23:09 02 5.21 % R 

### CO2 14.16 % R 

### 05/07/10 09:23:19 02 5.25 % R 

### CO2 14.04 % R 

### 05/07/10 09:23:29 02 5.26 % R 

### CO2 14.04 % R 

### 05/07/10 09:23:39 02 5.26 % R 

### CO2 13.92 % R 

### 05/07/10 09:23:49 02 5.24 % R 

### CO2 13.92 % R 

### 05/07/10 09:23:59 02 5.21 % R 

### CO2 13.92 % R 

### 05/07/10 09:24:09 02 5.16 % R 

### CO2 14.16 % R 

### 05/07/10 09:24:19 02 5.13 % R 

### CO2 14.04 % R 

### 11

### 05/07/10 09:24:29 02 5.13 % 

### R 

### CO2 14.16 % 

### R 

### 05/07/10 09:24:39 02 5.18 % 

### R 

### CO2 14.16 % 

### R 

### 05/07/10 09:24:49 02 5.25 % 

### R 

### CO2 14.04 % 

### R 

### 05/07/10 09:24:59 02 5.29 % 

### R 

### CO2 14.04 % 

### R 

### 05/07/10 09:25:09 02 5.26 % 

### R 

### CO2 14.04 % 

### R 

### 05/07/10 09:25:19 02 5.26 % 

### R 

### CO2 14.04 % 

### R 

### 05/07/10 09:25:29 02 5.32 % 

### R 

### CO2 13.92 % 

### R 

### 05/07/10 09:25:39 02 5.40 % 

### R 

### CO2 14.04 % 

### R 

### 05/07/10 09:25:49 02 5.47 % 

### R 

### CO2 13.92 % 

### R 

### 05/07/10 09:25:59 02 5.52 % 

### R 

### CO2 13.92 % 

### R 

### 05/07/10 09:26:09 02 5.51 % 

### R 

### CO2 13.92 % 

### R 

### 05/07/10 09:26:19 02 5.46 % 

### R 

### CO2 14.04 % 

### R 

### 05/07/10 09:26:29 02 5.42 % 

### R 

### CO2 13.79 % 

### R 

### 05/07/10 09:26:39 02 5.42 % 

### R 

### CO2 13.92 % 

### R 

### 05/07/10 09:26:49 02 5.44 % 

### R 

### CO2 14.28 % 

### R 

### 05/07/10 09:26:59 02 5.49 % 

### R 

### CO2 13.79 % 

### R 

### 05/07/10 09:27:09 02 5.53 % 

### R 

### CO2 13.67 % 

### R 

### 05/07/10 09:27:19 02 5.60 % 

### R 

### CO2 13.67 % 

### R 

### 05/07/10 09:27:29 02 5.68 % 

### R 

### CO2 13.55 % 

### R 

### 05/07/10 09:27:39 02 5.70 % 

### R 

### CO2 13.43 % 

### R 

### 05/07/10 09:27:49 02 5.79 % 

### R 

### CO2 13.67 % 

### R 

### 05/07/10 09:27:59 02 5.88 % 

### R 

### CO2 13.31 % 

### R 

### 05/07/10 09:28:09 02 5.93 % 

### R 

### CO2 13.31 % 

### R 

### 05/07/10 09:28:19 02 5.98 % 

### R 

### CO2 13.31 % 

### R 

### 05/07/10 09:28:29 02 6.01 % 

### R 

### CO2 13.31 % 

### R 

### 05/07/10 09:28:39 02 6.01 % 

### R 

### CO2 13.31 % 

### R 

### 05/07/10 09:28:49 02 5.99 % 

### R 

### CO2 13.43 % 

### R 

### 05/07/10 09:28:59 02 5.99 % 

### R 

### CO2 13.18 % 

### R 

### 05/07/10 09:29:09 02 5.96 % 

### R 

### CO2 13.43 % 

### R 

### 05/07/10 09:29:19 02 5.92 % 

### R 

### CO2 13.43 % 

### R 

### 05/07/10 09:29:29 02 5.86 % 

### R 

### CO2 13.55 % 

### R 

### 05/07/10 09:29:39 02 5.82 % 

### R 

### CO2 13.43 % 

### R 

### 05/07/10 09:29:49 02 5.83 % 

### R 

### CO2 13.43 % 

### R 

### 05/07/10 09:29:59 02 5.86 % 

### R 

### CO2 13.55 % 

### R Avg 

### 5.55 13.73



### 12

### Post1 Bias 

### James River Cogen Unit NO.2 Post Run 1 Bias Metals/PM-10

05/07110 

### 09:31:23 02 1.22 % R 

### CO2 1.46 % R 05/07/10 

### 09:31:24 02 1.06 % R 

### CO2 1.34 % R 05/07/10 

### 09:31:29 02 0.71 % R 

### CO2 0.85 % R 05/07/10 

### 09:31:34 02 0.48 % R 

### CO2 0.61 % R 05/07/10 

### 09:31:39 02 0.32 % R 

### CO2 0.24 % R 05/07/10 

### 09:31:44 02 0.22 % R 

### CO2 0.24 % R 05/07/10 

### 09:31:49 02 0.20 % R 

### CO2 0.37 % R 05/07/10 

### 09:31:54 02 0.10 % R 

### CO2 0.24 % R 05/07/10 

### 09:31:59 02 0.07 % R 

### CO2 0.12 % R 05/07/10 

### 09:32:04 02 0.05 % R 

### CO2 0.24 % R 05/07/10 

### 09:32:09 02 0.05 % R 

### CO2 -0.12 % R 05/07/10 

### 09:32:14 02 0.05 % R 

### CO2 0.12 % R 05/07/10 

### 09:32:19 02 0.06 % R 

### CO2 -0.12 % R 05/07/10 

### 09:32:24 02 0.05 % R 

### CO2 0.00 % R 05/07/10 

### 09:32:29 02 0.05 % R 

### CO2 0.00 % R 05/07/10 

### 09:32:34 02 0.05 % R 

### CO2 0.12 % R 05/07/10 

### 09:32:39 02 0.05 % R 

### CO2 0.24 % R 05/07/10 

### 09:32:44 02 0.20 % R 

### CO2 0.49 % R 05/07/10 

### 09:32:49 02 2.56 % R 

### CO2 1.22 % R 05/07/10 

### 09:32:54 02 6.40 % R 

### CO2 3.54 % R 05/07/10 

### 09:32:59 02 8.98 % R 

### CO2 5.49 % R 05/07/10 

### 09:33:04 02 10.56 % R 

### CO2 6.10 % R 05/07/10 

### 09:33:09 02 11.40 % R 

### CO2 6.59 % R 05/07/10 

### 09:33:14 02 11.85 % R 

### CO2 6.96 % R 05/07/10 

### 09:33:19 02 12.10 % R 

### CO2 7.20 % R 05/07/10 

### 09:33:24 02 12.24 % R 

### CO2 7.20 % R 05/07/10 

### 09:33:29 02 12.35 % R 

### CO2 7.08 % R 05/07/10 

### 09:33:34 02 12.41 % R 

### CO2 7.57 % R 05/07/10 

### 09:33:39 02 12.45 % R 

### CO2 7.20 % R 05/07/10 

### 09:33:44 02 12.45 % R 

### CO2 7.32 % R 05/07/10 

### 09:33:49 02 12.48 % R 

### CO2 7.32 % R 05/07/10 

### 09:33:54 02 12.49 % R 

### CO2 7.45 % R 05/07/10 

### 09:33:59 02 12.49 % R 

### CO2 7.45 % R 05/07/10 

### 09:34:04 02 12.49 % R 

### CO2 7.45 % R 05/07/10 

### 09:34:09 02 12.50 % R 

### CO2 7.45 % R 05/07/10 

### 09:34:14 02 12.50 % R 

### CO2 7.45 % R 05/07/10 

### 09:34:19 02 12.50 % R 

### CO2 7.45 % R 05/07/10 

### 09:34:24 02 12.50 % R 

### CO2 7.45 % R 05/07/10 

### 09:34:29 02 13.70 % R 

### CO2 7.81 % R 05/07/10 

### 09:34:34 02 16.59 % R 

### CO2 9.28 % R 05/07/10 

### 09:34:39 02 18.81 % R 

### CO2 10.50 % R 05/07/10 

### 09:34:44 02 20.15 % R 

### CO2 11.11 % R 05/07/10 

### 09:34:49 02 20.96 % R 

### CO2 11.47 % R 05/07/10 

### 09:34:54 02 21.44 % R 

### CO2 11.72 % R 05/07/10 

### 09:34:59 02 21.69 % R 

### CO2 12.08 % R 05/07/10 

### 09:35:04 02 21.84 % R 

### CO2 12.33 % R 05/07/10 

### 09:35:09 02 21.90 % R 

### CO2 12.21 % R 05/07/10 

### 09:35:14 02 21.92 % R 

### CO2 12.21 % R 05/07/10 

### 09:35:19 02 21.98 % R 

### CO2 12.45 % R


### 13Run2 

### James River Cogen Unit NO.2 Run NO.2 Metals/PM-10

05/07/10 09:52:27 02 5.43 % R CO2 13.67 % R 05/07/10 09:52:29 02 5.44 % R CO2 13.67 % R 05/07/10 09:52:39 02 5.46 % R CO2 13.55 % R 05/07/10 09:52:49 02 5.46 % R CO2 13.79 % R 05/07/10 09:52:59 02 5.46 % R CO2 13.92 % R 05/07/10 09:53:09 02 5.46 % R CO2 14.16 % R 05/07/10 09:53:19 02 5.42 % R CO2 13.67 % R 05/07/10 09:53:29 02 5.44 % R CO2 13.79 % R 05/07/10 09:53:39 02 5.52 % R CO2 13.67 % R 05/07/10 09:53:49 02 5.54 % R CO2 13.79 % R 05/07/10 09:53:59 02 5.54 % R CO2 13.67 % R 05/07/10 09:54:09 02 5.58 % R CO2 13.67 % R 05/07/10 09:54:19 02 5.62 % R CO2 13.55 % R 05/07/10 09:54:29 02 5.64 % R CO2 13.43 % R 05/07/10 09:54:39 02 5.66 % R CO2 13.67 % R 05/07/10 09:54:49 02 5.68 % R CO2 13.55 % R 05/07/10 09:54:59 02 5.69 % R CO2 13.67 % R 05/07/10 09:55:09 02 5.73 % R CO2 13.43 % R 05/07/10 09:55:19 02 5.81 % R CO2 13.55 % R 05/07/10 09:55:29 02 5.87 % R CO2 13.43 % R 05/07/10 09:55:39 02 5.90 % R CO2 13.43 % R 05/07/10 09:55:49 02 5.90 % R CO2 13.67 % R 05/07/10 09:55:59 02 5.92 % R CO2 13.31 % R 05/07/10 09:56:09 02 5.97 % R CO2 13.31 % R 05/07/10 09:56:19 02 6.03 % R CO2 13.43 % R 05/07/10 09:56:29 02 6.03 % R CO2 13.31 % R 05/07/10 09:56:39 02 6.03 % R CO2 13.67 % R 05/07/10 09:56:49 02 6.04 % R CO2 13.43 % R 05/07/10 09:56:59 02 6.05 % R CO2 13.43 % R 05/07/10 09:57:09 02 6.10 % R CO2 13.18 % R 05/07/10 09:57:19 02 6.16 % R CO2 13.06 % R 05/07/10 09:57:29 02 6.24 % R CO2 12.94 % 

### R 05/07/10 09:57:39 02 6.35 % R CO2 13.18 % R 05/07/10 09:57:49 02 6.49 % R CO2 12.82 % R 05/07/10 09:57:59 02 6.67 % R CO2 12.57 % R 05/07/10 09:58:09 02 6.81 % R CO2 12.70 % R 05/07/10 09:58:19 02 6.88 % R CO2 12.82 % R 05/07/10 09:58:29 02 6.90 % R CO2 12.70 % R 05/07/10 09:58:39 02 6.84 % R CO2 12.94 % R 05/07/10 09:58:49 02 6.74 % R CO2 12.82 % R 05/07/10 09:58:59 02 6.62 % R CO2 12.82 % R 05/07/10 09:59:09 02 6.52 % R CO2 13.06 % R 05/07/10 09:59:19 02 6.48 % R CO2 13.18 % R 05/07/10 09:59:29 02 6.54 % R CO2 12.82 % R 05/07/10 09:59:39 02 6.64 % R CO2 12.70 % R 05/07/10 09:59:49 02 6.69 % R CO2 12.57 % R 05/07/10 09:59:59 02 6.65 % R CO2 12.82 % R 05/07/10 10:00:09 02 6.53 % R CO2 12.94 % R 05/07/10 10:00:19 02 6.40 % R CO2 13.06 % R 05/07/10 10:00:29 02 6.35 % R CO2 12.70 % R 

### 1405/07/10 

### 10:00:39 02 6.31 % R 

### CO2 12.94 % R 05/07/10 

### 10:00:49 02 6.24 % R 

### CO2 13.06 % R 05/07/10 

### 10:00:59 02 6.14 % R 

### CO2 13.06 % R 05/07/10 

### 10:01 :09 02 6.09 % R 

### CO2 13.06 % R 05/07/10 

### 10:01:19 02 6.10 % R 

### CO2 13.31 % R 05/07/10 

### 10:01 :29 02 6.14 % R 

### CO2 13.18 % R 05/07/10 

### 10:01 :39 02 6.18 % R 

### CO2 13.06 % R 05/07/10 

### 10:01 :49 02 6.20 % R 

### CO2 12.94 % R 05/07/10 

### 10:01 :59 02 6.20 % R 

### CO2 12.82 % R 05/07/10 

### 10:02:09 02 6.18 % R 

### CO2 13.18 % R 05/07/10 

### 10:02:19 02 6.10 % R 

### CO2 13.31 % R 05/07/10 

### 10:02:29 02 5.99 % R 

### CO2 13.18 % R 05/07/10 

### 10:02:39 02 5.91 % R 

### CO2 13.31 % 

### R 05/07/10 

### 10:02:49 02 5.88 % R 

### CO2 13.67 % R 05/07/10 

### 10:02:59 02 5.90 % R 

### CO2 13.18 % R 05/07/10 

### 10:03:09 02 5.90 % R 

### CO2 13.43 % R 05/07/10 

### 10:03:19 02 5.88 % R 

### CO2 13.55 % R 05/07/10 

### 10:03:29 02 5.85 % R 

### CO2 13.31 % R 05/07/10 

### 10:03:39 02 5.82 % R 

### CO2 13.18 % R 05/07/10 

### 10:03:49 02 5.81 % R 

### CO2 13.31 % R 05/07/10 

### 10:03:59 02 5.79 % R 

### CO2 13.18 % R 05/07/10 

### 10:04:09 02 5.75 % R 

### CO2 13.18 % R 05/07/10 

### 10:04:19 02 5.74 % R 

### CO2 13.55 % R 05/07/10 

### 10:04:29 02 5.71 % R 

### CO2 13.43 % R 05/07/10 

### 10:04:39 02 5.69 % R 

### CO2 13.31 % R 05/07/10 

### 10:04:49 02 5.66 % R 

### CO2 13.43 % R 05/07/10 

### 10:04:59 02 5.59 % R 

### CO2 13.18 % R 05/07/10 

### 10:05:09 02 5.55 % R 

### CO2 13.55 % R 05/07/10 

### 10:05:19 02 5.53 % R 

### CO2 13.43 % 

### R 05/07/10 

### 10:05:29 02 5.54 % R 

### CO2 13.43 % R 05/07/10 

### 10:05:39 02 5.55 % R 

### CO2 13.55 % R 05/07/10 

### 10:05:49 02 5.57 % R 

### CO2 13.43 % R 05/07/10 

### 10:05:59 02 5.57 % R 

### CO2 13.55 % R 05/07/10 

### 10:06:09 02 5.59 % R 

### CO2 13.55 % R 05/07/10 

### 10:06:19 02 5.63 % R 

### CO2 13.43 % R 05/07/10 

### 10:06:29 02 5.65 % R 

### CO2 13.31 % R 05/07/10 

### 10:06:39 02 5.68 % R 

### CO2 13.43 % R 05/07/10 

### 10:06:49 02 5.73 % R 

### CO2 13.43 % R 05/07/10 

### 10:06:59 02 5.76 % R 

### CO2 13.31 % R 05/07/10 

### 10:07:09 02 5.77 % R 

### CO2 13.18 % R 05/07/10 

### 10:07:19 02 5.75 % R 

### CO2 13.31 % R 05/07/10 

### 10:07:29 02 5.70 % R 

### CO2 13.43 % R 05/07/10 

### 10:07:39 02 5.64 0% R 

### CO2 13.43 % R 05/07/10 

### 10:07:49 02 5.62 % R 

### CO2 13.43 % R 05/07/10 

### 10:07:59 02 5.63 % R 

### CO2 13.31 % R 05/07/10 

### 10:08:09 02 5.63 % R 

### CO2 13.43 % R 05/07/10 

### 10:08:19 02 5.64 % R 

### CO2 13.55 % R 05/07/10 

### 10:08:29 02 5.65 % R 

### CO2 13.67 % R 05/07/10 

### 10:08:39 02 5.69 % R 

### CO2 13.43 % R 05/07/10 

### 10:08:49 02 5.75 % R 

### CO2 13.31 % R 05/07/10 

### 10:08:59 02 5.82 % R 

### CO2 13.31 % R 05/07/10 

### 10:09:09 02 5.87 % R 

### CO2 13.43 % R 05/07/10 

### 10:09:19 02 5.91 % R 

### CO2 13.43 % R 05/07/10 

### 10:09:29 02 5.92 % R 

### CO2 13.43 % R 

### 1505/07/10 10:09:39 02 5.93 

### % R CO2 13.31 

### % R 05/07/10 10:09:49 02 5.93 

### % R CO2 13.43 

### % R 05/07/10 10:09:59 02 5.92 

### % R CO2 13.55 

### % R 05/07/10 10:10:09 02 5.91 

### % R CO2 13.31 

### % R 05/07/10 10:10:19 02 5.91 

### % R CO2 13.31 

### % R 05/07/10 10:10:29 02 5.92 

### % R CO2 13.55 

### % R 05/07/10 10:10:39 02 5.93 

### % R CO2 13.31 

### % R 05/07/10 10:10:49 02 5.96 

### % R CO2 13.18 

### % R 05/07/10 10:10:59 02 5.96 

### % R CO2 13.55 

### % R 05/07/10 10:11:09 02 5.94 

### % R CO2 13.43 

### % R 05/07/10 10:11:19 02 5.98 

### % R CO2 13.55 

### % R 05/07/10 10:11:29 02 6.04 

### % R CO2 13.31 

### % R 05/07/10 10:11:39 02 6.07 

### % R CO2 13.43 

### % R 05/07/10 10:11:49 02 6.12 

### % R CO2 13.18 

### % R 05/07/10 10:11 :59 02 6.15 

### % R CO2 13.43 

### % R 05/07/10 10:12:09 02 6.18 

### % R CO2 13.31 

### % R 05/07/10 10:12:19 02 6.16 

### % R CO2 13.18 

### % R 05/07/10 10:12:36 02 6.07 

### % R CO2 13.18 

### % R 05/07/10 10:12:49 02 5.98 

### % R CO2 13.31 

### % R 05/07/10 10:13:09 02 5.90 

### % R CO2 13.43 

### % R 05/07/10 10:13:29 02 5.82 

### % R CO2 13.31 

### % R 05/07/10 10:13:49 02 5.87 

### % R CO2 13.55 

### % R 05/07/10 10:14:09 02 6.02 

### % R CO2 13.31 

### % R 05/07/10 10:14:29 02 6.16 

### % R CO2 13.31 

### % R 05/07/10 10:14:49 02 6.13 

### % R CO2 13.18 

### % R 05/07/10 10:15:09 02 5.92 

### % R CO2 13.43 

### % R 05/07/10 10:15:29 02 5.77 

### % R CO2 13.55 

### % R 05/07/10 10:15:49 02 5.80 

### % R CO2 13.18 

### % R 05/07/10 10:16:09 02 5.87 

### % R CO2 13.31 

### % R 05/07/10 10:16:29 02 5.86 

### % R CO2 13.43 

### % R 05/07/10 10:16:49 02 5.80 

### % R CO2 13.31 

### % R 05/07/10 10:17:09 02 5.79 

### % R CO2 13.43 

### % R 05/07/10 10:17:29 02 5.73 

### % R CO2 13.55 

### % R 05/07/10 10:17:49 02 5.71 

### % R CO2 13.18 

### % R 05/07/10 10:18:09 02 5.76 

### % R CO2 13.55 

### % R 05/07/10 10:18:29 02 5.76 

### % R CO2 13.31 

### % R 05/07/10 10:18:49 02 5.75 

### % R CO2 13.18 

### % R 05/07/10 10:19:09 02 5.73 

### % R CO2 13.67 

### % R 05/07/10 10:19:29 02 5.76 

### % R CO2 13.43 

### % R 05/07/10 10:19:49 02 5.80 

### % R CO2 13.43 

### % R 05/07/10 10:20:09 02 5.76 

### % R CO2 13.55 

### % R 05/07/10 10:20:29 02 5.77 

### % R CO2 13.67 

### % R 05/07/10 10:20:49 02 5.65 

### % R CO2 13.55 

### % R 05/07/10 10:21 :09 02 5.49 

### % R CO2 13.79 

### % R 05/07/10 10:21 :29 02 5.44 

### % R CO2 13.79 

### % R 05/07/10 10:21 :49 02 5.53 

### % R CO2 13.67 

### % R 05/07/10 10:22:09 02 5.64 

### % R CO2 13.55 

### % R 05/07/10 10:22:29 02 5.70 

### % R CO2 13.55 

### % R 05/07/10 10:22:49 02 5.74 

### % R CO2 13.67 

### % R 05/07/10 10:23:09 02 5.79 

### % R CO2 13.43 

### % R 05/07/10 10:23:29 02 5.71 

### % R CO2 13.67 

### % R 05/07/10 10:23:49 02 5.66 

### % R CO2 13.55 

### % R 05/07/10 10:24:09 02 5.73 

### % R CO2 13.55 

### % R 05/07/10 10:24:29 02 5.76 

### % R CO2 13.43 

### % R 

### 1605/07/10 

### 10:24:49 02 5.79 % 

### R 

### CO2 13.43 % 

### R 05/07/10 

### 10:25:09 02 5.76 % 

### R 

### CO2 13.43 % 

### R 05/07/10 

### 10:25:29 02 5.77 % 

### R 

### CO2 13.43 % 

### R 05/07/10 

### 10:25:49 02 5.76 % 

### R 

### CO2 13.43 % 

### R 05/07/10 

### 10:26:09 02 5.65 % 

### R 

### CO2 13.67 % 

### R 05/07/10 

### 10:26:29 02 5.57 % 

### R 

### CO2 13.55 % 

### R 05/07/10 

### 10:26:49 02 5.55 % 

### R 

### CO2 13.55 % 

### R 05/07/10 

### 10:27:09 02 5.64 % 

### R 

### CO2 13.67 % 

### R 05/07/10 

### 10:27:29 02 5.75 % 

### R 

### CO2 13.43 % 

### R 05/07/10 

### 10:27:49 02 5.71 % 

### R 

### CO2 13.18 % R 05/07/10 

### 10:28:09 02 5.69 % 

### R 

### CO2 13.55 % R 05/07/10 

### 10:28:29 02 5.68 % 

### R 

### CO2 13.67 % 

### R 05/07/10 

### 10:28:49 02 5.62 % 

### R 

### CO2 13.43 % R 05/07/10 

### 10:29:09 02 5.55 % 

### R 

### CO2 13.79 % R 05/07/10 

### 10:29:29 02 5.53 % 

### R 

### CO2 13.67 % R 05/07/10 

### 10:29:49 02 5.51 % 

### R 

### CO2 13.67 % 

### R 05/07/10 

### 10:30:09 02 5.57 % 

### R 

### CO2 13.67 % R 05/07/10 

### 10:30:29 02 5.71 % 

### R 

### CO2 13.43 % R 05/07/10 

### 10:30:49 02 5.81 % R 

### CO2 13.31 % R 05/07/10 

### 10:31:09 02 5.77 % 

### R 

### CO2 13.43 % R 05/07/10 

### 10:31:29 02 5.68 % 

### R 

### CO2 13.43 % R 05/07/10 

### 10:31:49 02 5.63 % 

### R 

### CO2 13.55 % 

### R 05/07/10 

### 10:32:09 02 5.62 % 

### R 

### CO2 13.43 % 

### R 05/07/10 

### 10:32:29 02 5.53 % 

### R 

### CO2 13.55 % 

### R 05/07/10 

### 10:32:49 02 5.46 % 

### R 

### CO2 13.55 % R 05/07/10 

### 10:33:09 02 5.43 % 

### R 

### CO2 13.55 % 

### R 05/07/10 

### 10:33:29 02 5.47 % 

### R 

### CO2 13.79 % R 05/07/10 

### 10:33:49 02 5.60 % 

### R 

### CO2 13.43 % R 05/07/10 

### 10:34:09 02 5.64 % 

### R 

### CO2 13.43 % R 05/07/10 

### 10:34:29 02 5.57 % 

### R 

### CO2 13.55 % R 05/07/10 

### 10:34:49 02 5.59 % 

### R 

### CO2 13.79 % R 05/07/10 

### 10:35:09 02 5.66 % 

### R 

### CO2 13.43 % R 05/07110 

### 10:35:29 02 5.77 % 

### R 

### CO2 13.31 % 

### R 05/07/10 

### 10:35:49 02 5.85 % R 

### CO2 13.55 % R 05/07/10 

### 10:36:09 02 5.82 % 

### R 

### CO2 13.43 % R 05/07/10 

### 10:36:29 02 5.66 % R 

### CO2 13.67 % R 05/07/10 

### 10:36:49 02 5.48 % R 

### CO2 13.79 % R 05/07/10 

### 10:37:09 02 5.42 % 

### R 

### CO2 13.79 % R 05/07/10 

### 10:37:29 02 5.46 % 

### R 

### CO2 13.67 % 

### R 05/07/10 

### 10:37:49 02 5.51 % 

### R 

### CO2 13.55 % 

### R 05/07/10 

### 10:38:09 02 5.55 % 

### R 

### CO2 13.67 % 

### R 05/07/10 

### 10:38:29 02 5.54 % 

### R 

### CO2 13.67 % 

### R 05/07/10 

### 10:38:49 02 5.58 % 

### R 

### CO2 13.55 % 

### R 05/07/10 

### 10:39:09 02 5.62 % 

### R 

### CO2 13.55 % R 05/07/10 

### 10:39:29 02 5.60 % 

### R 

### CO2 13.55 % R 05/07/10 

### 10:39:49 02 5.65 % R 

### CO2 13.18 % R 05/07/10 

### 10:40:09 02 5.59 % 

### R 

### CO2 13.67 % 

### R 05/07/10 

### 10:40:29 02 5.58 % 

### R 

### CO2 13.43 % 

### R 05/07/10 

### 10:40:49 02 5.63 % 

### R 

### CO2 13.55 % R 05/07/10 

### 10:41 :09 02 5.65 % 

### R 

### CO2 13.55 % 

### R 05/07/10 

### 10:41:29 02 5.70 % 

### R 

### CO2 13.43 % 

### R 05/07/10 

### 10:41 :49 02 5.73 % 

### R 

### CO2 13.67 % 

### R 05/07/10 

### 10:42:09 02 5.68 % 

### R 

### CO2 13.55 % 

### R 05/07/10 

### 10:42:29 02 5.60 % 

### R 

### CO2 13.92 % 

### R 1705/07/10 10:42:49 02 5.55 % 

### R CO2 13.55 % 

### R 05/07/10 10:43:09 02 5.53 % 

### R CO2 13.43 % 

### R 05/07/10 10:43:29 02 5.62 % 

### R CO2 13.55 % 

### R 05/07/10 10:43:49 02 5.70 % 

### R CO2 13.43 % 

### R 05/07/10 10:44:09 02 5.69 % 

### R CO2 13.55 % 

### R 05/07/10 10:44:29 02 5.65 % 

### R CO2 13.31 % 

### R 05/07/10 10:44:49 02 5.64 % 

### R CO2 13.55 % 

### R 05/07/10 10:45:09 02 5.60 % 

### R CO2 13.43 % 

### R 05/07/10 10:45:29 02 5.62 % 

### R CO2 13.55 % 

### R 05/07/10 10:45:49 02 5.62 % 

### R CO2 13.55 % 

### R 05/07/10 10:46:09 02 5.64 % 

### R CO2 13.55 % 

### R 05/07/10 10:46:29 02 5.68 % 

### R CO2 13.31 % 

### R 05/07/10 10:46:49 02 5.65 % 

### R CO2 13.67 % 

### R 05/07/10 10:47:09 02 5.58 % 

### R CO2 13.43 % 

### R 05/07/10 10:47:29 02 5.53 % 

### R CO2 13.67 % 

### R 05/07/10 10:47:49 02 5.53 % 

### R CO2 13.92 % 

### R 05/07/10 10:48:09 02 5.59 % 

### R CO2 13.43 % 

### R 05/07/10 10:48:29 02 5.64 % 

### R CO2 13.67 % 

### R 05/07/10 10:48:49 02 5.71 % 

### R CO2 13.18 % 

### R 05/07/10 10:49:09 02 5.74 % 

### R CO2 13.55 % 

### R 05/07/10 10:49:29 02 5.75 % 

### R CO2 13.31 % 

### R 05/07/10 10:49:49 02 5.76 % 

### R CO2 13.55 % 

### R 05/07/10 10:50:09 02 5.68 % 

### R CO2 13.55 % 

### R 05/07/10 10:50:29 02 5.60 % 

### R CO2 13.67 % 

### R 05/07/10 10:50:49 02 5.58 % 

### R CO2 13.55 % 

### R 05/07/10 10:51:09 02 5.62 % 

### R CO2 13.67 % 

### R 05/07/10 10:51 :29 02 5.75 % 

### R CO2 13.43 % 

### R 05/07/10 10:51:49 02 5.77 % 

### R CO2 13.55 % 

### R 05/07/10 10:52:09 02 5.75 % 

### R CO2 13.43 % 

### R 05/07/10 10:52:29 02 5.69 % 

### R CO2 13.55 % 

### R 05/07/10 10:52:49 02 5.62 % 

### R CO2 13.31 % 

### R 05/07/10 10:53:09 02 5.55 % 

### R CO2 13.55 % 

### R 05/07/10 10:53:29 02 5.57 % 

### R CO2 13.79 % 

### R 05/07/10 10:53:49 02 5.60 % 

### R CO2 13.43 % 

### R 05/07/10 10:54:09 02 5.66 % 

### R CO2 13.79 % 

### R 05/07/10 10:54:29 02 5.70 % 

### R CO2 13.43 % 

### R 05/07/10 10:54:49 02 5.69 % 

### R CO2 13.43 % 

### R 05/07/10 10:55:09 02 5.60 % 

### R CO2 13.43 % 

### R 05/07/10 10:55:29 02 5.53 % 

### R CO2 13.43 % 

### R 05/07/10 10:55:49 02 5.52 % 

### R CO2 13.55 % 

### R 05/07/10 10:56:09 02 5.55 % 

### R CO2 13.55 % 

### R 05/07/10 10:56:29 02 5.63 % 

### R CO2 13.67 % 

### R 05/07/10 10:56:49 02 5.75 % 

### R CO2 13.43 % 

### R 05/07/10 10:57:09 02 5.79 % 

### R CO2 13.55 % 

### R 05/07/10 10:57:29 02 5.74 % 

### R CO2 13.55 % 

### R 05/07/10 10:57:49 02 5.62 % 

### R CO2 13.67 % 

### R 05/07/10 10:58:09 02 5.55 % 

### R CO2 13.67 % 

### R 05/07/10 10:58:29 02 5.55 % 

### R CO2 13.79 % 

### R 05/07/10 10:58:49 02 5.62 % 

### R CO2 13.18 % 

### R 05/07/10 10:59:09 02 5.68 % 

### R CO2 13.55 % 

### R 05/07/10 10:59:29 02 5.70 % 

### R CO2 13.31 % 

### R 05/07/10 10:59:49 02 5.70 % 

### R CO2 13.31 % 

### R 05/07/10 11:00:09 02 5.70 % 

### R CO2 13.43 % 

### R 05/07/10 11:00:29 02 5.70 % 

### R CO2 13.43 % 

### R 

### 18

### 05/07/10 11:00:49 02 5.66 % R 

### CO2 13.67 % R 

### 05/07/10 11:01:09 02 5.66 % R 

### CO2 13.43 % R 

### 05/07/10 11 :01 :29 02 5.58 % R 

### CO2 13.67 % R 

### 05/07/10 11:01:49 02 5.62 % R 

### CO2 13.43 % R 

### 05/07/10 11:02:09 02 5.73 % R 

### CO2 13.43 % R 

### 05/07/10 11:02:29 02 5.82 % R 

### CO2 13.43 % R 

### 05/07/10 11 :02:49 02 5.91 % R 

### CO2 13.18 % R 

### 05/07/10 11:03:09 02 5.88 % R 

### CO2 13.31 % R 

### 05/07/10 11:03:29 02 5.66 % R 

### CO2 13.67 % R 

### 05/07/10 11:03:49 02 5.41 % R 

### CO2 13.92 % R 

### 05/07/10 11:04:09 02 5.26 % R 

### CO2 13.92 % R 

### 05/07/10 11:04:29 02 5.32 % R 

### CO2 13.92 % R 

### 05/07/10 11:04:49 02 5.47 % R 

### CO2 13.79 % R 

### 05/07/10 11 :05:09 02 5.49 % R 

### CO2 13.55 % R 

### 05/07/10 11:05:29 02 5.59 % R 

### CO2 13.55 % R 

### 05/07/10 11 :05:49 02 5.62 % R 

### CO2 13.55 % R 

### 05/07/10 11 :06:09 02 5.55 % R 

### CO2 13.67 % R 

### 05/07/10 11:06:29 02 5.51 % R 

### CO2 13.79 % R 

### 05/07/10 11:06:49 02 5.47 % R 

### CO2 13.55 % R 

### 05/07/10 11:07:09 02 5.49 % R 

### CO2 13.43 % R 

### 05/07/10 11:07:29 02 5.53 % R 

### CO2 13.67 % R 

### 05/07/10 11:07:49 02 5.54 % R 

### CO2 13.79 % R 

### 05/07/10 11:08:09 02 5.53 % R 

### CO2 13.55 % R 

### 05/07/10 11:08:29 02 5.48 % R 

### CO2 13.55 % R 

### 05/07/10 11:08:49 02 5.30 % R 

### CO2 13.67 % R 

### 05/07/10 11:09:09 02 5.19 % R 

### CO2 13.79 % R 

### 05/07/10 11:09:29 02 5.22 % R 

### CO2 13.92 % R 

### 05/07/10 11:09:49 02 5.20 % R 

### CO2 14.04 % R 

### 05/07/10 11:10:09 02 5.19 % R 

### CO2 14.16 % R 

### 05/07/10 11:10:29 02 5.31 % R 

### CO2 13.79 % R 

### 05/07/10 11:10:49 02 5.41 % R 

### CO2 13.55 % R 

### 05/07/10 11:11:09 02 5.48 % R 

### CO2 13.67 % R 

### 05/07/10 11:11:29 02 5.53 % R 

### CO2 13.79 % R 

### 05/07/10 11:11:49 02 5.48 % R 

### CO2 13.92 % R 

### 05/07/10 11:12:09 02 5.43 % R 

### CO2 13.79 % R 

### 05/07/10 11:12:29 02 5.44 % R 

### CO2 13.55 % R 

### 05/07/10 11:12:49 02 5.53 % R 

### CO2 13.43 % R 

### 05/07/10 11:13:09 02 5.48 % R 

### CO2 13.55 % R 

### 05/07/10 11:13:29 02 5.43 % R 

### CO2 13.67 % R 

### 05/07/10 11:13:49 02 5.37 % R 

### CO2 13.67 % R 

### 05/07/10 11:14:09 02 5.30 % R 

### CO2 13.92 % R 

### 05/07/10 11:14:29 02 5.26 % R 

### CO2 14.04 % R 

### 05/07/10 11:14:49 02 5.19 % R 

### CO2 13.92 % R 

### 05/07/10 11:15:09 02 5.20 % R 

### CO2 13.92 % R 

### 05/07/10 11:15:29 02 5.27 % R 

### CO2 13.92 % R 

### 05/07/10 11:15:49 02 5.29 % R 

### CO2 13.92 % R 

### 05/07/10 11:16:09 02 5.24 % R 

### CO2 13.92 % R 

### 05/07/10 11:16:29 02 5.22 % R 

### CO2 13.67 % R 

### 05/07/10 11:16:49 02 5.16 % R 

### CO2 14.04 % R 

### 05/07/10 11:17:09 02 5.08 % R 

### CO2 14.16 % R 

### 05/07/10 11:17:29 02 5.13 % R 

### CO2 14.16 % R 

### 05/07/10 11:17:49 02 5.29 % R 

### CO2 13.92 % R 

### 05/07/10 11:18:09 02 5.31 % R 

### CO2 14.04 % R 

### 05/07/10 11:18:29 02 5.24 % R 

### CO2 14.04 % R 

### 1905/07/10 11:18:49 02 5.31 

### % 

### R CO2 13.92 

### % 

### R 05/07/10 11:19:09 02 5.37 

### % 

### R CO2 14.04 

### % 

### R 05/07/10 11:19:29 02 5.29 

### % 

### R CO2 13.67 

### % 

### R 05/07/10 11:19:49 02 5.27 

### % 

### R CO2 13.79 

### % 

### R 05/07/10 11:20:09 02 5.44 

### % 

### R CO2 13.67 

### % R 05/07/10 11 :20:29 02 5.65 

### % 

### R CO2 13.67 

### % 

### R 05/07/10 11:20:49 02 5.69 

### % 

### R CO2 13.67 

### % 

### R 05/07/10 11:21:09 02 5.66 

### % 

### R CO2 13.43 

### % 

### R 05/07/10 11 :21 :29 02 5.65 

### % R CO2 13.43 

### % 

### R 05/07/10 11 :21 :49 02 5.59 

### % 

### R CO2 13.55 

### % R 05/07/10 11:22:09 02 5.48 

### % 

### R CO2 13.92 

### % R 05/07/10 11:22:29 02 5.38 

### % 

### R CO2 13.92 

### % 

### R 05/07/10 11:22:49 02 5.27 

### % 

### R CO2 13.79 

### % 

### R 05/07/10 11 :23:09 02 5.29 

### % 

### R CO2 13.79 

### % 

### R 05/07/10 11:23:29 02 5.30 

### % 

### R CO2 13.67 

### % 

### R 05/07/10 11:23:49 02 5.32 

### % R CO2 14.04 

### % 

### R 05/07/10 11:24:09 02 5.33 

### % 

### R CO2 13.67 

### % R 05/07/10 11:24:29 02 5.26 

### % 

### R CO2 13.92 

### % 

### R 05/07/10 11:24:49 02 5.20 

### % 

### R CO2 14.04 

### % 

### R 05/07/10 11:25:09 02 5.13 

### % 

### R CO2 14.04 

### % 

### R 05/07/10 11:25:29 02 5.11 % R CO2 14.04 % 

### R 05/07/10 11:25:49 02 5.19 % R CO2 13.79 

### % 

### R 05/07/10 11:26:09 02 5.26 

### % 

### R CO2 13.92 

### % 

### R 05/07/10 11:26:29 02 5.37 

### % 

### R CO2 13.67 

### % 

### R 05/07/10 11:26:49 02 5.43 

### % 

### R CO2 13.79 

### % 

### R 05/07/10 11:27:09 02 5.44 

### % 

### R CO2 13.79 % 

### R 05/07/10 11:27:29 02 5.48 % 

### R CO2 13.67 

### % 

### R 05/07/10 11:27:49 02 5.49 

### % 

### R CO2 13.67 

### % 

### R 05/07/10 11:28:09 02 5.49 

### % 

### R CO2 13.55 

### % 

### R 05/07/10 11:28:29 02 5.55 

### % 

### R CO2 13.67 % R 05/07/10 11 :28:49 02 5.57 

### % 

### R CO2 13.55 

### % 

### R 05/07/10 11:29:09 02 5.49 

### % 

### R CO2 13.67 

### % R 05/07/10 11:29:29 02 5.35 

### % 

### R CO2 13.79 

### % R 05/07/10 11:29:49 02 5.20 % 

### R CO2 13.79 

### % 

### R 05/07/10 11:30:09 02 5.11 % 

### R CO2 13.92 

### % R 05/07/10 11:30:29 02 5.09 % R CO2 14.04 

### % R 05/07/10 11 :30:49 02 5.08 

### % 

### R CO2 14.16 

### % 

### R 05/07/10 11:31:09 02 5.10 

### % 

### R CO2 13.92 

### % R 05/07/10 11 :31 :29 02 5.02 

### % 

### R CO2 14.04 

### % 

### R 05/07/10 11:31:49 02 4.97 % 

### R CO2 14.16 % 

### R 05/07/10 11:32:09 02 4.97 % 

### R CO2 14.53 

### % 

### R 05/07/10 11:32:29 02 4.94 

### % 

### R CO2 14.04 % 

### R 05/07/10 11:32:49 02 4.94 

### % 

### R CO2 14.28 

### % 

### R 05/07/10 11:33:09 02 5.08 

### % 

### R CO2 14.16 

### % 

### R 05/07/10 11:33:29 02 5.21 % 

### R CO2 14.16 

### % 

### R 05/07/10 11:33:49 02 5.41 

### % 

### R CO2 13.67 

### % R 05/07/10 11:34:09 02 5.55 

### % 

### R CO2 13.67 

### % 

### R 05/07/10 11:34:29 02 5.57 

### % 

### R CO2 13.79 % 

### R 05/07/10 11:34:49 02 5.58 

### % 

### R CO2 13.43 

### % 

### R 05/07/10 11:35:09 02 5.49 % 

### R CO2 13.92 

### % 

### R 05/07/10 11:35:29 02 5.32 

### % 

### R CO2 13.92 

### % 

### R 05/07/10 11 :35:49 02 5.29 

### % 

### R CO2 13.92 

### % 

### R 05/07/10 11:36:09 02 5.30 % 

### R CO2 13.67 

### % 

### R 05/07/10 11:36:29 02 5.31 % 

### R CO2 13.79 % 

### R 2005/07/10 

### 11 :36:49 02 5.37 % R 

### CO2 14.04 % R 05/07/10 

### 11 :37:09 02 5.46 % R 

### CO2 13.79 % R 05/07/10 

### 11:37:29 02 5.54 % R 

### CO2 13.79 % R 05/07/10 

### 11:37:49 02 5.58 % R 

### CO2 13.79 % R 05/07/10 

### 11 :38:09 02 5.53 % R 

### CO2 13.79 % R 05107/10 

### 11:38:29 02 5.43 % R 

### CO2 13.67 % R 05/07/10 

### 11:38:49 02 5.35 % R 

### CO2 13.79 % R 05/07/10 

### 11:39:09 02 5.32 % R 

### CO2 13.79 % R 05/07/10 

### 11:39:29 02 5.46 % R 

### CO2 13.55 % R 05/07/10 

### 11:39:49 02 5.62 % R 

### CO2 13.67 % R 05/07/10 

### 11:40:09 02 5.70 % R 

### CO2 13.67 % R 05/07/10 

### 11:40:29 02 5.69 % R 

### CO2 13.55 % R 05/07/10 

### 11:40:49 02 5.60 % R 

### CO2 13.79 % R 05/07/10 

### 11:41:09 02 5.57 % R 

### CO2 13.92 % R 05/07/10 

### 11:41 :29 02 5.55 % R 

### CO2 13.79 % R 05/07/10 

### 11:41:49 02 5.57 % R 

### CO2 13.55 % R 05/07/10 

### 11:42:09 02 5.63 % R 

### CO2 13.67 % R 05/07/10 

### 11:42:29 02 5.74 % R 

### CO2 13.43 % R 05/07/10 

### 11:42:49 02 5.80 % R 

### CO2 13.79 % R 05/07/10 

### 11:43:09 02 5.73 % R 

### CO2 13.43 % 

### R 05/07/10 

### 11:43:29 02 5.58 % R 

### CO2 13.79 % R 05/07/10 

### 11:43:49 02 5.51 % R 

### CO2 13.79 % R 05/07/10 

### 11:44:09 02 5.53 % R 

### CO2 13.67 % R 05/07/10 

### 11:44:29 02 5.57 % R 

### CO2 13.55 % 

### R 05/07/10 

### 11:44:49 02 5.60 % R 

### CO2 13.55 % R 05/07/10 

### 11:45:09 02 5.62 % R 

### CO2 13.43 % R 05/07/10 

### 11:45:29 02 5.52 % R 

### CO2 13.79 % R 05/07/10 

### 11:45:49 02 5.48 % R 

### CO2 14.04 % R 05/07/10 

### 11 :46:09 02 5.51 % R 

### CO2 13.55 % 

### R 05/07/10 

### 11:46:29 02 5.55 % R 

### CO2 13.55 % 

### R 05/07/10 

### 11:46:49 02 5.52 % R 

### CO2 13.67 % R 05/07/10 

### 11:47:09 02 5.44 % R 

### CO2 13.79 % R 05/07/10 

### 11:47:29 02 5.42 % R 

### CO2 13.67 % R 05/07/10 

### 11:47:49 02 5.42 % R 

### CO2 14.16 % 

### R 05/07/10 

### 11:48:09 02 5.48 % R 

### CO2 13.79 % R 05/07/10 

### 11:48:29 02 5.57 % R 

### CO2 13.43 % R 05/07/10 

### 11:48:49 02 5.57 % R 

### CO2 13.55 % R 05/07/10 

### 11:49:09 02 5.54 % R 

### CO2 13.67 % R 05/07/10 

### 11:49:29 02 5.44 % R 

### CO2 13.92 % R 05/07/10 

### 11:49:49 02 5.38 % R 

### CO2 13.79 % R 05/07/10 

### 11:50:09 02 5.48 % R 

### CO2 13.67 % R 05/07/10 

### 11:50:29 02 5.57 % R 

### CO2 13.79 % R 05/07/10 

### 11:50:49 02 5.59 % R 

### CO2 13.79 % R 05/07/10 

### 11:51:09 02 5.51 % R 

### CO2 13.55 % R 05/07/10 

### 11:51:29 02 5.46 % R 

### CO2 13.43 % R 05/07/10 

### 11:51:49 02 5.51 % R 

### CO2 13.55 % R 05/07/10 

### 11:52:09 02 5.51 % R 

### CO2 13.67 % R 05/07110 

### 11:52:29 02 5.60 % R 

### CO2 13.67 % R 05/07/10 

### 11:52:49 02 5.70 % R 

### CO2 13.31 % R 05/07/10 

### 11:53:09 02 5.74 % R 

### CO2 13.67 % R 05/07/10 

### 11:53:29 02 5.79 % R 

### CO2 13.43 % R 05/07/10 

### 11:53:49 02 5.71 % R 

### CO2 13.55 % R 05/07/10 

### 11:54:09 02 5.54 % R 

### CO2 13.79 % R 05/07/10 

### 11 :54:29 02 5.51 % R 

### CO2 13.92 % R 

### 2105/07/10 

### 11:54:49 02 5.58 % 

### R CO2 13.67 % 

### R 05/07/10 

### 11 :55:09 02 5.70 % 

### R CO2 13.55 % 

### R 05/07/10 

### 11:55:29 02 5.75 % 

### R CO2 13.67 % 

### R 05/07/10 

### 11 :55:49 02 5.70 % 

### R CO2 13.55 % 

### R 05/07/10 

### 11 :56:09 02 5.62 % 

### R CO2 13.43 % 

### R 05/07/10 

### 11 :56:29 02 5.46 % 

### R CO2 13.67 % 

### R 05/07/10 

### 11 :56:49 02 5.36 % 

### R CO2 13.92 % 

### R 05/07/10 

### 11:57:09 02 5.41 % 

### R CO2 13.67 % 

### R 05/07/10 

### 11 :57:29 02 5.51 % 

### R CO2 13.67 % 

### R 05/07/10 

### 11 :57:49 02 5.64 % 

### R CO2 13.43 % 

### R 05/07/10 

### 11:58:09 02 5.83 % 

### R CO2 13.43 % 

### R 05/07/10 

### 11:58:29 02 5.97 % 

### R CO2 13.43 % 

### R 05/07/10 

### 11 :58:49 02 5.90 % 

### R CO2 13.31 % 

### R 05/07/10 

### 11:59:09 02 5.86 % 

### R CO2 13.55 % 

### R 05/07/10 

### 11:59:29 02 5.86 % 

### R CO2 13.55 % 

### R 05/07/10 

### 11:59:49 02 5.93 % 

### R CO2 13.55 % 

### R 05/07/10 

### 12:00:09 02 5.99 % 

### R CO2 13.43 % 

### R 05/07/10 

### 12:00:29 02 5.97 % 

### R CO2 13.43 % 

### R 05/07/10 

### 12:00:49 02 5.98 % 

### R CO2 13.18 % 

### R 05/07/10 

### 12:01:09 02 6.05 % 

### R CO2 13.31 % 

### R 05/07/10 

### 12:01 :29 02 6.07 % 

### R CO2 13.18 % 

### R 05/07/10 

### 12:01:39 02 6.08 % 

### R CO2 13.18 % 

### R 05/07/10 

### 12:01:49 02 6.09 % 

### R CO2 13.31 % 

### R 05/07/10 

### 12:01 :59 02 6.10 % 

### R CO2 13.43 % 

### R 05/07/10 

### 12:02:09 02 6.14 % 

### R CO2 13.55 % 

### R 05/07/10 

### 12:02:19 02 6.16 % 

### R CO2 13.43 % 

### R 05/07/10 

### 12:02:29 02 6.16 % 

### R CO2 13.43 % 

### R 05/07/10 

### 12:02:39 02 6.14 % 

### R CO2 13.18 % 

### R 05/07/10 

### 12:02:49 02 6.12 % 

### R CO2 13.31 % 

### R Avg 

### 5.67 13.54



### 22

### Post2Bias 

### James River Cogen Unit NO.2 Post Run 2 Bias Metals/PM-10

05/07/10 12:04:22 02 5.74 % R 

### CO2 13.55 % R 

### 05/07/10 12:04:24 02 5.71 % R 

### CO2 13.55 % R 

### 05/07/10 12:04:29 02 5.69 % R 

### CO2 13.67 % R 

### 05/07/10 12:04:34 02 5.66 % R 

### CO2 13.67 % R 

### 05/07/10 12:04:39 02 5.68 % R 

### CO2 13.55 % R 05/07/10 

### 12:04:44 02 6.71 % R 

### CO2 13.55 % R 

### 05/07/10 12:04:49 02 7.54 % R 

### CO2 12.45 % R 

### 05/07/10 12:04:54 02 6.31 % R 

### CO2 9.40 % R 

### 05/07/10 12:04:59 02 4.50 % R 

### CO2 6.59 % R 

### 05/07/10 12:05:04 02 3.05 % R 

### CO2 4.15 % R 

### 05/07/10 12:05:09 02 2.04 % R 

### CO2 2.56 % R 

### 05/07/10 12:05:14 02 1.37 % R 

### CO2 1.95 % R 

### 05/07/10 12:05:19 02 0.92 % R 

### CO2 1.34 % R 

### 05/07/10 12:05:24 02 0.63 % R 

### CO2 0.98 % R 

### 05/07/10 12:05:29 02 0.46 % R 

### CO2 1.10 % R 

### 05/07/10 12:05:34 02 0.35 % R 

### CO2 0.61 % R 

### 05/07/10 12:05:39 02 0.29 % R 

### CO2 0.61 % R 

### 05/07/10 12:05:44 02 0.24 % R 

### CO2 0.49 % R 

### 05/07/10 12:05:49 02 0.22 % R 

### CO2 0.37 % R 

### 05/07/10 12:05:54 02 0.20 % R 

### CO2 0.49 % R 

### 05/07/10 12:05:59 02 0.17 % R 

### CO2 0.37 % R 

### 05/07/10 12:06:04 02 0.17 % R 

### CO2 0.73 % R 

### 05/07/10 12:06:09 02 0.16 % R 

### CO2 0.12 % R 05/07/10 

### 12:06:14 02 0.16 % R 

### CO2 0.12 % R 

### 05/07/10 12:06:19 02 0.15 % R 

### CO2 0.37 % R 

### 05/07/10 12:06:24 02 0.13 % R 

### CO2 0.24 % R 

### 05/07/10 12:06:29 02 0.13 % R 

### CO2 0.24 % R 05/07/10 

### 12:06:34 02 0.12 % R 

### CO2 0.37 % R 

### 05/07/10 12:06:39 02 0.12 % R 

### CO2 0.12 % R 

### 05/07/10 12:06:44 02 0.12 % R 

### CO2 0.24 % R 

### 05/07/10 12:06:49 02 0.12 % R 

### CO2 0.12 % R 

### 05/07110 12:06:54 02 0.11 % R 

### CO2 0.12 % R 

### 05/07/10 12:06:59 02 0.12 % R 

### CO2 0.00 % R 

### 05/07/10 12:07:04 02 0.11 % R 

### CO2 0.00 % R 

### 05/07110 12:07:09 02 0.11 % R 

### CO2 0.00 % R 

### 05/07/10 12:07:14 02 0.11 % R 

### CO2 0.24 % R 05/07/10 

### 12:07:19 02 0.10 % R 

### CO2 0.00 % R 

### 05/07/10 12:07:24 02 0.10 % R 

### CO2 0.24 % R 

### 05/07/10 12:07:29 02 0.10 % R 

### CO2 0.12 % R 

### 05/07/10 12:07:34 02 0.10 % R 

### CO2 0.12 % R 

### 05/07/10 12:07:39 02 0.10 % R 

### CO2 -0.12 % R 

### 05/07/10 12:07:44 02 0.68 % R 

### CO2 0.00 % R 

### 05/07/10 12:07:49 02 2.95 % R 

### CO2 1.34 % R 

### 05/07/10 12:07:54 02 5.86 % R 

### CO2 2.81 % R 

### 05/07/10 12:07:59 02 8.18 % R 

### CO2 4.27 % R 

### 05/07/10 12:08:04 02 9.78 % R 

### CO2 5.25 % R 

### 05/07/10 12:08:09 02 10.79 % R 

### CO2 5.98 % R 

### 05/07/10 12:08:14 02 11.40 % R 

### CO2 6.47 % R 

### 05/07/10 12:08:19 02 11.77 % R 

### CO2 6.59 % R 

### 05/07/10 12:08:24 02 11.99 % R 

### CO2 7.08 % R 

### 2305/07/10 

### 12:08:29 02 12.12 % R 

### CO2 6.84 % R 05/07/10 

### 12:08:34 02 12.19 % R 

### CO2 6.84 % R 05/07/10 

### 12:08:39 02 12.26 % R 

### CO2 7.08 % R 05/07/10 

### 12:08:44 02 12.29 % R 

### CO2 7.08 % R 05/07/10 

### 12:08:49 02 12.32 % R 

### CO2 7.08 % R 05/07/10 

### 12:08:54 02 12.33 % R 

### CO2 7.45 % R 05/07/10 

### 12:08:59 02 12.34 % R 

### CO2 7.20 % R 05/07/10 

### 12:09:04 02 12.04 % R 

### CO2 7.32 % R 05/07/10 

### 12:09:09 02 11.65 % R 

### CO2 8.06 % R 05/07/10 

### 12:09:14 02 12.29 % R 

### CO2 7.32 % R 05/07/10 

### 12:09:19 02 12.24 % R 

### CO2 6.96 % R 05/07/10 

### 12:09:24 02 12.35 % R 

### CO2 7.20 % R 05/07/10 

### 12:09:29 02 12.37 % R 

### CO2 7.32 % R 05/07/10 

### 12:09:34 02 12.41 % R 

### CO2 7.32 % R 05/07/10 

### 12:09:39 02 12.43 % R 

### CO2 7.20 % R 05/07/10 

### 12:09:44 02 14.38 % R 

### CO2 7.57 % R 05/07/10 

### 12:09:49 02 18.73 % R 

### CO2 9.64 % R 05/07/10 

### 12:09:54 02 20.80 % R 

### CO2 11.11 % R 05/07/10 

### 12:09:59 02 21.48 % R 

### CO2 11.72 % R 05/07/10 

### 12:10:04 02 21.72 % R 

### CO2 11.84 % R 05/07/10 

### 12:10:09 02 21.79 % R 

### CO2 11.84 % R 05/07/10 

### 12:10:14 02 21.81 % R 

### CO2 12.33 % R 05/07/10 

### 12:10:19 02 21.84 % R 

### CO2 12.33 % R 05/07/10 

### 12:10:24 02 21.86 % R 

### CO2 12.21 % R 05/07/10 

### 12:10:29 02 21.86 % R 

### CO2 12.33 % R 05/07/10 

### 12:10:34 02 21.90 % R 

### CO2 12.21 % R 05/07/10 

### 12:10:39 02 21.89 % R 

### CO2 12.21 % R 05/07/10 

### 12:10:44 02 21.90 % R 

### CO2 12.08 % 

### R

24Run3 

### James River Cogen 

### Unit NO.2 

### Run No.3 Metals/PM-10

05/07110 12:16:17 02 5.62 % R CO2 13.55 % R 05/07/10 12:16:19 02 5.63 % R CO2 13.79 % R 05/07/10 12:16:29 02 5.64 % R CO2 13.55 % R 05/07/10 12:16:39 02 5.65 % R CO2 13.79 % R 05/07/10 12:16:49 02 5.62 % R CO2 13.43 % R 05/07/10 12:17:09 02 5.51 % R CO2 13.55 % R 05/07/10 12:17:29 02 5.32 % R CO2 13.55 % R 05/07/10 12:17:49 02 5.20 % R CO2 13.79 % R 05/07/10 12:18:09 02 5.26 % R CO2 13.67 % R 05/07/10 12:18:29 02 5.35 % R CO2 13.92 % R 05/07/10 12:18:49 02 5.43 % R CO2 13.67 % R 05/07/10 12:19:09 02 5.49 % R CO2 13.67 % R 05/07/10 12:19:29 02 5.57 % R CO2 13.67 % R 05/07/10 12:19:49 02 5.55 % R CO2 13.67 % R 05/07/10 12:20:09 02 5.38 % R CO2 13.79 % R 05/07/10 12:20:29 02 5.29 % R CO2 13.79 % R 05/07/10 12:20:49 02 5.31 % R CO2 13.67 % R 05/07/10 12:21:09 02 5.38 % R CO2 13.92 % R 05/07/10 12:21:29 02 5.46 % R CO2 13.67 % R 05/07/10 12:21:49 02 5.48 % R CO2 13.79 % R 05/07/10 12:22:09 02 5.49 % R CO2 13.92 % R 05/07/10 12:22:29 02 5.51 % R CO2 13.67 % R 05/07/10 12:22:49 02 5.53 % R CO2 13.55 % R 05/07/10 12:23:09 02 5.44 % R CO2 13.67 % R 05/07/10 12:23:29 02 5.37 % R CO2 13.67 % R 05/07/10 12:23:49 02 5.29 % R CO2 13.92 % R 05/07/10 12:24:09 02 5.36 % R CO2 13.92 % R 05/07/10 12:24:29 02 5.53 % R CO2 13.55 % R 05/07/10 12:24:49 02 5.64 % R CO2 13.31 % R 05/07/10 12:25:09 02 5.66 % R CO2 13.31 % R 05/07/10 12:25:29 02 5.48 % R CO2 13.92 % R 05/07/10 12:25:49 02 5.24 % R CO2 13.92 % 

### R 05/07/10 12:26:09 02 5.25 % R CO2 13.92 % R 05/07/10 12:26:29 02 5.31 % R CO2 13.92 % R 05/07/10 12:26:49 02 5.35 % R CO2 13.67 % R 05/07/10 12:27:09 02 5.32 % R CO2 14.04 % R 05/07/10 12:27:29 02 5.38 % R CO2 13.67 % R 05/07/10 12:27:49 02 5.46 % R CO2 13.79 % R 05/07/10 12:28:09 02 5.35 % R CO2 13.79 % R 05/07/10 12:28:29 02 5.26 % R CO2 13.79 % R 05/07/10 12:28:49 02 5.18 % R CO2 14.04 % R 05/07/10 12:29:09 02 5.10 % R CO2 14.04 % R 05/07/10 12:29:29 02 5.07 % R CO2 13.92 % R 05/07/10 12:29:49 02 5.04 % R CO2 14.16 % R 05/07/10 12:30:09 02 5.09 % R CO2 14.16 % R 05/07/10 12:30:29 02 5.09 % R CO2 14.04 % R 05/07/10 12:30:49 02 5.16 % R CO2 13.67 % R 05/07/10 12:31:09 02 5.35 % R CO2 13.67 % R 05/07/10 12:31:29 02 5.44 % R CO2 13.79 % R 05/07/10 12:31:49 02 5.54 % R CO2 13.79 % R 25

### 05/07/10 12:32:09 02 5.64 % R 

### CO2 13.31 % R 

### 05/07/10 12:32:29 02 5.71 % R 

### CO2 13.55 % R 

### 05/07/10 12:32:49 02 5.86 % R 

### CO2 13.18 % R 

### 05/07/10 12:33:09 02 5.82 % R 

### CO2 13.31 % R 

### 05/07/10 12:33:29 02 5.81 % R 

### CO2 13.31 % R 

### 05/07/10 12:33:49 02 5.80 % R 

### CO2 13.55 % R 

### 05/07/10 12:34:09 02 5.70 % R 

### CO2 13.67 % R 

### 05/07/10 12:34:29 02 5.57 % R 

### CO2 13.67 % R 

### 05/07/10 12:34:49 02 5.40 % R 

### CO2 13.92 % R 

### 05/07/10 12:35:09 02 5.38 % R 

### CO2 13.92 % R 

### 05/07/10 12:35:29 02 5.48 % R 

### CO2 13.55 % R 

### 05/07/10 12:35:49 02 5.52 % R 

### CO2 13.55 % R 

### 05/07/10 12:36:09 02 5.46 % R 

### CO2 13.55 % R 

### 05/07/10 12:36:29 02 5.30 % R 

### CO2 13.79 % R 

### 05/07/10 12:36:49 02 5.11 % R 

### CO2 13.79 % R 

### 05/07/10 12:37:09 02 5.11 % R 

### CO2 13.67 % R 

### 05/07/10 12:37:29 02 5.16 % R 

### CO2 13.92 % R 

### 05/07/10 12:37:49 02 5.26 % R 

### CO2 13.79 % R 

### 05/07/10 12:38:09 02 5.42 % R 

### CO2 13.92 % R 

### 05/07/10 12:38:29 02 5.58 % R 

### CO2 13.79 % R 

### 05/07/10 12:38:49 02 5.54 % R 

### CO2 13.67 % R 

### 05/07/10 12:39:09 02 5.54 % R 

### CO2 13.79 % R 

### 05/07110 12:39:29 02 5.52 % R 

### CO2 13.67 % R 

### 05/07/10 12:39:49 02 5.52 % R 

### CO2 13.55 % R 

### 05/07/10 12:40:09 02 5.57 % R 

### CO2 13.55 % R 

### 05/07/10 12:40:29 02 5.52 % R 

### CO2 13.55 % R 

### 05/07/10 12:40:49 02 5.44 % R 

### CO2 13.67 % R 

### 05/07/10 12:41:09 02 5.53 % R 

### CO2 13.55 % R 

### 05/07/10 12:41:29 02 5.65 % R 

### CO2 13.67 % R 

### 05/07/10 12:41:49 02 5.75 % R 

### CO2 13.31 % R 

### 05/07/10 12:42:09 02 5.73 % R 

### CO2 13.55 % R 

### 05/07/10 12:42:29 02 5.55 % R 

### CO2 13.67 % R 

### 05/07/10 12:42:49 02 5.38 % R 

### CO2 13.67 % R 

### 05/07/10 12:43:09 02 5.37 % R 

### CO2 13.55 % R 

### 05/07/10 12:43:29 02 5.42 % R 

### CO2 13.67 % R 

### 05/07/10 12:43:49 02 5.41 % R 

### CO2 13.67 % R 

### 05/07/10 12:44:09 02 5.25 % R 

### CO2 13.92 % R 

### 05/07/10 12:44:29 02 5.35 % R 

### CO2 14.04 % R 

### 05/07/10 12:44:49 02 5.48 % R 

### CO2 13.55 % R 

### 05/07/10 12:45:09 02 5.69 % R 

### CO2 13.67 % R 

### 05/07/10 12:45:29 02 5.70 % R 

### CO2 13.43 % R 

### 05/07/10 12:45:49 02 5.74 % R 

### CO2 13.55 % R 

### 05/07/10 12:46:09 02 5.87 % R 

### CO2 13.55 % R 

### 05/07/10 12:46:29 02 5.91 % R 

### CO2 13.31 % R 

### 05/07/10 12:46:49 02 5.83 % R 

### CO2 13.31 % R 

### 05/07/10 12:47:09 02 5.73 % R 

### CO2 13.67 % R 

### 05/07/10 12:47:29 02 5.64 % R 

### CO2 13.55 % R 

### 05/07/10 12:47:49 02 5.60 % R 

### CO2 13.55 % R 

### 05/07/10 12:48:09 02 5.51 % R 

### CO2 13.43 % R 

### 05/07/10 12:48:29 02 5.38 % R 

### CO2 13.67 % R 

### 05/07/10 12:48:49 02 5.41 % R 

### CO2 13.55 % R 

### 05/07/10 12:49:09 02 5.52 % R 

### CO2 13.43 % R 

### 05/07/10 12:49:29 02 5.54 % R 

### CO2 13.55 % R 

### 05/07/10 12:49:49 02 5.46 % R 

### CO2 13.55 % R 

### 2605/07/10 12:50:09 02 5.43 % 

### R CO2 13.67 % 

### R 05/07/10 12:50:29 02 5.37 % 

### R CO2 13.43 % 

### R 05/07/10 12:50:49 02 5.27 % 

### R CO2 13.79 % R 05/07/10 12:51:09 02 5.22 % 

### R CO2 14.04 % R 05/07/10 12:51 :29 02 5.29 % 

### R CO2 13.67 % R 05/07/10 12:51:49 02 5.33 % 

### R CO2 13.79 % R 05/07/10 12:52:09 02 5.30 % 

### R CO2 13.67 % R 05/07/10 12:52:29 02 5.25 % 

### R CO2 13.55 % R 05/07/10 12:52:49 02 5.32 % R CO2 13.92 % R 05/07/10 12:53:09 02 5.41 % 

### R CO2 13.55 % R 05/07/10 12:53:29 02 5.48 % 

### R CO2 13.67 % R 05/07/10 12:53:49 02 5.59 % R CO2 13.43 % R 05/07/10 12:54:09 02 5.69 % 

### R CO2 13.43 % R 05/07/10 12:54:29 02 5.85 % 

### R CO2 13.18 % R 05/07/10 12:54:49 02 6.04 % 

### R CO2 13.31 % R 05/07/10 12:55:09 02 6.05 % 

### R CO2 13.06 % R 05/07/10 12:55:29 02 5.98 % 

### R CO2 13.43 % R 05/07/10 12:55:49 02 5.87 % 

### R CO2 13.43 % R 05/07/10 12:56:09 02 5.73 % 

### R CO2 13.31 % R 05/07/10 12:56:29 02 5.65 % 

### R CO2 13.43 % R 05/07/10 12:56:49 02 5.68 % 

### R CO2 13.43 % R 05/07/10 12:57:09 02 5.69 % 

### R CO2 13.43 % R 05/07/10 12:57:29 02 5.71 % 

### R CO2 13.43 % R 05/07/10 12:57:49 02 5.63 % 

### R CO2 13.55 % R 05/07/10 12:58:09 02 5.53 % 

### R CO2 13.43 % R 05/07/10 12:58:29 02 5.44 % R CO2 13.43 % R 05/07/10 12:58:49 02 5.43 % 

### R CO2 13.55 % R 05/07/10 12:59:09 02 5.49 % 

### R CO2 13.67 % R 05/07/10 12:59:29 02 5.55 % R CO2 13.67 % R 05/07/10 12:59:49 02 5.59 % 

### R CO2 13.67 % R 05/07/10 13:00:09 02 5.44 % 

### R CO2 13.67 % R 05/07/10 13:00:29 02 5.48 % R CO2 13.79 % R 05/07/10 13:00:49 02 5.69 % 

### R CO2 13.31 % R 05/07/10 13:01 :09 02 5.81 % 

### R CO2 13.31 % R 05/07/10 13:01:29 02 5.93 % R CO2 13.43 % R 05/07/10 13:01:49 02 5.96 % 

### R CO2 13.31 % R 05/07/10 13:02:09 02 5.94 % R CO2 13.18 % R 05/07/10 13:02:29 02 5.93 % 

### R CO2 13.18 % R 05/07/10 13:02:49 02 5.91 % 

### R CO2 13.18 % R 05/07/10 13:03:09 02 5.85 % R CO2 13.43 % R 05/07/10 13:03:29 02 5.69 % 

### R CO2 13.55 % R 05/07/10 13:03:49 02 5.64 % R CO2 13.55 % R 05/07/10 13:04:09 02 5.58 % R CO2 13.55 % R 05/07/10 13:04:29 02 5.53 % 

### R CO2 13.67 % R 05/07/10 13:04:49 02 5.58 % R CO2 13.55 % R 05/07/10 13:05:09 02 5.62 % R CO2 13.43 % R 05/07/10 13:05:29 02 5.53 % 

### R CO2 13.43 % R 05/07/10 13:05:49 02 5.43 % R CO2 13.55 % R 05/07/10 13:06:09 02 5.38 % 

### R CO2 13.67 % R 05/07/10 13:06:29 02 5.42 % 

### R CO2 13.55 % R 05/07/10 13:06:49 02 5.41 % 

### R CO2 13.79 % R 05/07/10 13:07:09 02 5.55 % 

### R CO2 13.92 % R 05/07/10 13:07:29 02 5.54 % 

### R CO2 13.55 % R 05/07/10 13:07:49 02 5.48 % 

### R CO2 13.55 % R 

### 2705/07/10 

### 13:08:09 02 5.51 % R 

### CO2 13.67 % R 05/07/10 

### 13:08:29 02 5.54 % R 

### CO2 13.67 % R 05/07/10 

### 13:08:49 02 5.58 % R 

### CO2 13.67 % R 05/07/10 

### 13:09:09 02 5.54 % R 

### CO2 13.67 % R 05/07/10 

### 13:09:29 02 5.52 % R 

### CO2 13.79 % R 05/07/10 

### 13:09:49 02 5.49 % R 

### CO2 13.67 % R 05/07/10 

### 13:10:09 02 5.38 % R 

### CO2 13.67 % R 05/07/10 

### 13:10:29 02 5.49 % R 

### CO2 13.43 % R 05/07/10 

### 13:10:49 02 5.63 % R 

### CO2 13.43 % R 05/07/10 

### 13:11:14 02 5.71 % R 

### CO2 13.79 % R 05/07/10 

### 13:11 :29 02 5.79 % R 

### CO2 13.67 % R 05/07/10 

### 13:11:49 02 5.77 % R 

### CO2 13.43 % R 05/07/10 

### 13:12:09 02 5.75 % R 

### CO2 13.43 % R 05/07/10 

### 13:12:29 02 5.68 % R 

### CO2 13.43 % R 05/07/10 

### 13:12:49 02 5.58 % R 

### CO2 13.43 % R 05/07/10 

### 13:13:09 02 5.60 % R 

### CO2 13.43 % R 05/07/10 

### 13:13:29 02 5.65 % R 

### CO2 13.43 % R 05/07/10 

### 13:13:49 02 5.66 % R 

### CO2 13.18 % R 05/07/10 

### 13:14:09 02 5.64 % R 

### CO2 13.55 % R 05/07/10 

### 13:14:29 02 5.62 % R 

### CO2 13.43 % R 05/07/10 

### 13:14:49 02 5.49 % R 

### CO2 13.67 % R 05/07/10 

### 13:15:09 02 5.44 % R 

### CO2 13.67 % R 05/07/10 

### 13:15:29 02 5.38 % R 

### CO2 13.55 % R 05/07/10 

### 13:15:49 02 5.37 % R 

### CO2 13.67 % R 05/07/10 

### 13:16:09 02 5.59 % R 

### CO2 13.55 % R 05/07/10 

### 13:16:29 02 5.63 % R 

### CO2 13.43 % R 05/07/10 

### 13:16:49 02 5.62 % R 

### CO2 13.55 % R 05/07/10 

### 13:17:09 02 5.47 % R 

### CO2 13.92 % R 05107/10 

### 13:17:29 02 5.47 % R 

### CO2 13.67 % R 05/07/10 

### 13:17:49 02 5.53 % R 

### CO2 13.67 % R 05/07/10 

### 13:18:09 02 5.49 % R 

### CO2 13.55 % R 05/07/10 

### 13:18:29 02 5.60 % R 

### CO2 13.43 % R 05/07/10 

### 13:18:49 02 5.76 % R 

### CO2 13.18 % R 05/07/10 

### 13:19:09 02 5.74 % R 

### CO2 13.43 % R 05/07/10 

### 13:19:29 02 5.70 % R 

### CO2 13.43 % R 05/07/10 

### 13:19:49 02 5.62 % R 

### CO2 13.31 % R 05/07/10 

### 13:20:09 02 5.53 % R 

### CO2 13.55 % R 05/07/10 

### 13:20:29 02 5.49 % R 

### CO2 13.55 % R 05/07/10 

### 13:20:49 02 5.63 % R 

### CO2 13.67 % R 05/07/10 

### 13:21:09 02 5.85 % R 

### CO2 13.43 % R 05/07/10 

### 13:21:29 02 5.97 % R 

### CO2 13.43 % R 05/07/10 

### 13:21:49 02 5.80 % R 

### CO2 13.43 % R 05/07/10 

### 13:22:09 02 5.69 % R 

### CO2 13.55 % R 05/07/10 

### 13:22:29 02 5.69 % R 

### CO2 13.67 % R 05/07/10 

### 13:22:49 02 5.75 % R 

### CO2 13.31 % R 05/07/10 

### 13:23:09 02 5.55 % R 

### CO2 13.55 % R 05/07/10 

### 13:23:29 02 5.32 % R 

### CO2 13.55 % R 05/07/10 

### 13:23:49 02 5.31 % R 

### CO2 13.67 % R 05/07/10 

### 13:24:09 02 5.40 % R 

### CO2 13.55 % R 05/07/10 

### 13:24:29 02 5.43 % R 

### CO2 13.79 % R 05/07/10 

### 13:24:49 02 5.48 % R 

### CO2 13.55 % R 05/07/10 

### 13:25:09 02 5.52 % R 

### CO2 13.31 % R 05/07/10 

### 13:25:29 02 5.49 % R 

### CO2 13.43 % R 05/07/10 

### 13:25:49 02 5.52 % R 

### CO2 13.67 % R 

### 28

### 05/07/10 13:26:09 02 5.58 % 

### R 

### CO2 13.43 % R 

### 05/07/10 13:26:29 02 5.59 % R 

### CO2 13.92 % R 

### 05/07/10 13:26:49 02 5.65 % 

### R 

### CO2 13.67 % R 

### 05/07/10 13:27:09 02 5.70 % R 

### CO2 13.43 % R 

### 05/07/10 13:27:29 02 5.58 % R 

### CO2 13.43 % R 

### 05/07/10 13:27:49 02 5.47 % R 

### CO2 13.67 % R 

### 05/07/10 13:28:09 02 5.32 % R 

### CO2 13.92 % R 

### 05/07/10 13:28:29 02 5.32 % R 

### CO2 13.79 % R 

### 05/07/10 13:28:49 02 5.46 % R 

### CO2 13.67 % R 

### 05/07/10 13:29:09 02 5.57 % R 

### CO2 13.55 % R 

### 05/07/10 13:29:29 02 5.59 % R 

### CO2 13.67 % R 

### 05/07/10 13:29:49 02 5.55 % R 

### CO2 13.55 % R 

### 05/07/10 13:30:09 02 5.54 % R 

### CO2 13.31 % R 

### 05/07/10 13:30:29 02 5.51 % R 

### CO2 13.67 % R 

### 05/07/10 13:30:49 02 5.43 % R 

### CO2 13.92 % R 

### 05/07/10 13:31:09 02 5.44 % R 

### CO2 13.79 % R 

### 05/07/10 13:31:29 02 5.41 % R 

### CO2 13.79 % R 

### 05/07/10 13:31:49 02 5.44 % R 

### CO2 13.79 % R 

### 05/07/10 13:32:09 02 5.54 % R 

### CO2 13.67 % R 

### 05/07/10 13:32:29 02 5.66 % R 

### CO2 13.67 % R 

### 05/07/10 13:32:49 02 5.68 % R 

### CO2 13.55 % R 

### 05/07/10 13:33:09 02 5.48 % R 

### CO2 13.79 % R 

### 05/07/10 13:33:29 02 5.32 % R 

### CO2 13.67 % R 

### 05/07/10 13:33:49 02 5.31 % 

### R 

### CO2 13.67 % R 

### 05/07/10 13:34:09 02 5.35 % R 

### CO2 13.92 % R 

### 05/07/10 13:34:29 02 5.43 % R 

### CO2 13.79 % R 

### 05/07/10 13:34:49 02 5.46 % R 

### CO2 13.55 % R 

### 05/07/10 13:35:09 02 5.52 % 

### R 

### CO2 13.79 % R 

### 05/07/10 13:35:29 02 5.49 % R 

### CO2 13.55 % R 

### 05/07/10 13:35:49 02 5.37 % R 

### CO2 13.79 % R 

### 05/07/10 13:36:09 02 5.31 % R 

### CO2 13.92 % R 

### 05/07/10 13:36:29 02 5.37 % R 

### CO2 13.79 % R 

### 05/07/10 13:36:49 02 5.41 % R 

### CO2 13.67 % R 

### 05/07/10 13:37:09 02 5.42 % R 

### CO2 13.67 % R 

### 05/07/10 13:37:29 02 5.58 % R 

### CO2 13.67 % R 

### 05/07/10 13:37:49 02 5.71 % R 

### CO2 13.18 % R 

### 05/07/10 13:38:09 02 5.68 % R 

### CO2 13.43 % R 

### 05/07/10 13:38:29 02 5.59 % R 

### CO2 13.55 % R 

### 05/07/10 13:38:49 02 5.46 % R 

### CO2 13.67 % R 

### 05/07/10 13:39:09 02 5.33 % R 

### CO2 13.55 % R 

### 05/07/10 13:39:29 02 5.36 % R 

### CO2 13.79 % R 

### 05/07/10 13:39:49 02 5.38 % R 

### CO2 13.92 % R 

### 05/07/10 13:40:09 02 5.42 % R 

### CO2 13.79 % R 

### 05/07/10 13:40:29 02 5.52 % R 

### CO2 13.79 % R 

### 05/07/10 13:40:49 02 5.51 % R 

### CO2 13.79 % R 

### 05/07/10 13:41 :09 02 5.53 % R 

### CO2 13.43 % R 

### 05/07/10 13:41:29 02 5.52 % R 

### CO2 13.67 % R 

### 05/07/10 13:41 :49 02 5.54 % R 

### CO2 13.67 % R 

### 05/07/10 13:42:09 02 5.54 % R 

### CO2 13.67 % R 

### 05/07/10 13:42:29 02 5.57 % R 

### CO2 13.55 % R 

### 05/07/10 13:42:49 02 5.66 % R 

### CO2 13.43 % R 

### 05/07/10 13:43:09 02 5.68 % R 

### CO2 13.43 % R 

### 05/07/10 13:43:29 02 5.66 % R 

### CO2 13.55 % R 

### 05/07/10 13:43:49 02 5.59 % R 

### CO2 13.55 % 

### R 

### 2905/07/10 

### 13:44:09 02 5.44 % R 

### CO2 13.55 % R 05/07/10 

### 13:44:29 02 5.44 % R 

### CO2 13.55 % R 05/07/10 

### 13:44:49 02 5.38 % R 

### CO2 13.79 % R 05/07/10 

### 13:45:09 02 5.36 % R 

### CO2 13.79 % R 05/07/10 

### 13:45:29 02 5.38 % R 

### CO2 13.55 % R 05/07/10 

### 13:45:49 02 5.49 % R 

### CO2 13.67 % R 05/07/10 

### 13:46:09 02 5.66 % R 

### CO2 13.55 % R 05/07/10 

### 13:46:29 02 5.70 % R 

### CO2 13.43 % R 05/07/10 

### 13:46:49 02 5.85 % R 

### CO2 13.18 % R 05/07/10 

### 13:47:09 02 5.86 % R 

### CO2 13.43 % R 05/07/10 

### 13:47:29 02 5.69 % R 

### CO2 13.55 % R 05/07/10 

### 13:47:49 02 5.62 % R 

### CO2 13.55 % R 05/07/10 

### 13:48:09 02 5.58 % R 

### CO2 13.43 % R 05/07/10 

### 13:48:29 02 5.64 % R 

### CO2 13.67 % R 05/07/10 

### 13:48:49 02 5.75 % R 

### CO2 13.31 % R 05/07/10 

### 13:49:09 02 5.64 % R 

### CO2 13.55 % R 05/07/10 

### 13:49:29 02 5.62 % R 

### CO2 13.67 % R 05/07/10 

### 13:49:49 02 5.49 % R 

### CO2 13.43 % R 05/07/10 

### 13:50:09 02 5.32 % R 

### CO2 13.79 % R 05/07/10 

### 13:50:29 02 5.29 % R 

### CO2 13.67 % R 05/07/10 

### 13:50:49 02 5.31 % R 

### CO2 13.92 % R 05/07/10 

### 13:51:09 02 5.42 % R 

### CO2 13.79 % R 05/07/10 

### 13:51 :29 02 5.58 % R 

### CO2 13.67 % R 05/07/10 

### 13:51:49 02 5.73 % R 

### CO2 13.55 % R 05/07/10 

### 13:52:09 02 5.80 % R 

### CO2 13.43 % R 05/07/10 

### 13:52:29 02 5.70 % R 

### CO2 13.43 % R 05/07/10 

### 13:52:49 02 5.58 % R 

### CO2 13.67 % R 05/07/10 

### 13:53:09 02 5.51 % R 

### CO2 13.43 % R 05/07/10 

### 13:53:29 02 5.47 % R 

### CO2 13.67 % R 05/07/10 

### 13:53:49 02 5.43 % R 

### CO2 13.92 % R 05/07/10 

### 13:54:09 02 5.41 % R 

### CO2 13.67 % R 05/07/10 

### 13:54:29 02 5.48 % R 

### CO2 13.55 % R 05/07110 

### 13:54:49 02 5.44 % R 

### CO2 13.79 % R 05/07/10 

### 13:55:09 02 5.35 % R 

### CO2 13.67 % R 05/07/10 

### 13:55:29 02 5.40 % R 

### CO2 13.67 % R 05/07/10 

### 13:55:49 02 5.49 % R 

### CO2 13.55 % R 05/07/10 

### 13:56:09 02 5.51 % R 

### CO2 13.67 % R 05/07/10 

### 13:56:29 02 5.46 % R 

### CO2 13.92 % R 05/07/10 

### 13:56:49 02 5.53 % R 

### CO2 13.43 % R 05/07/10 

### 13:57:09 02 5.62 % R 

### CO2 13.55 % R 05/07/10 

### 13:57:29 02 5.54 % R 

### CO2 13.55 % R 05/07/10 

### 13:57:49 02 5.54 % R 

### CO2 13.67 % R 05/07/10 

### 13:58:09 02 5.54 % R 

### CO2 13.55 % R 05/07/10 

### 13:58:29 02 5.52 % R 

### CO2 13.43 % R 05/07/10 

### 13:58:49 02 5.51 % R 

### CO2 13.79 % R 05/07/10 

### 13:59:09 02 5.48 % R 

### CO2 13.79 % R 05/07/10 

### 13:59:29 02 5.55 % R 

### CO2 13.79 % R 05/07/10 

### 13:59:49 02 5.62 % R 

### CO2 13.67 % R 05/07/10 

### 14:00:09 02 5.57 % R 

### CO2 13.79 % R 05/07/10 

### 14:00:29 02 5.54 % R 

### CO2 13.55 % R 05/07/10 

### 14:00:49 02 5.41 % R 

### CO2 13.55 % R 05/07/10 

### 14:01 :09 02 5.30 % R 

### CO2 13.67 % R 05/07/10 

### 14:01:29 02 5.35 % R 

### CO2 13.67 % R 05/07/10 

### 14:01 :49 02 5.44 % R 

### CO2 13.67 % R 

### 30

### 05/07/10 14:02:09 02 5.58 % R 

### CO2 13.92 % R 

### 05/07/10 14:02:29 02 5.52 % R 

### CO2 13.55 % R 

### 05/07/10 14:02:49 02 5.52 % R 

### CO2 13.79 % R 

### 05/07/10 14:03:09 02 5.48 % R 

### CO2 13.79 % R 

### 05/07/10 14:03:29 02 5.38 % R 

### CO2 13.92 % R 

### 05/07/10 14:03:49 02 5.29 % R 

### CO2 13.92 % R 

### 05/07/10 14:04:09 02 5.25 % R 

### CO2 13.92 % R 

### 05/07/10 14:04:29 02 5.19 % R 

### CO2 14.04 % R 

### 05/07/10 14:04:49 02 5.25 % R 

### CO2 13.67 % R 

### 05/07/10 14:05:09 02 5.29 % R 

### CO2 13.79 % R 

### 05/07/10 14:05:29 02 5.52 % R 

### CO2 13.67 % R 

### 05/07/10 14:05:49 02 5.80 % R 

### CO2 13.43 % R 

### 05/07/10 14:06:09 02 5.74 % R 

### CO2 13.55 % R 

### 05/07/10 14:06:29 02 5.66 % R 

### CO2 13.31 % R 

### 05/07/10 14:06:49 02 5.62 % R 

### CO2 13.43 % R 

### 05/07/10 14:07:09 02 5.54 % R 

### CO2 13.55 % R 

### 05/07/10 14:07:29 02 5.57 % R 

### CO2 13.67 % R 

### 05/07/10 14:07:49 02 5.63 % R 

### CO2 13.67 % R 

### 05/07/10 14:08:09 02 5.68 % R 

### CO2 13.55 % R 

### 05/07/10 14:08:29 02 5.59 % R 

### CO2 13.43 % R 

### 05/07/10 14:08:49 02 5.54 % R 

### CO2 13.67 % R 

### 05/07/10 14:09:09 02 5.54 % R 

### CO2 13.67 % R 

### 05/07/10 14:09:29 02 5.38 % R 

### CO2 13.79 % R 

### 05/07/10 14:09:49 02 5.13 % R 

### CO2 13.79 % R 

### 05/07/10 14:10:09 02 5.00 % R 

### CO2 14.16 % R 

### 05/07/10 14:10:29 02 5.07 % R 

### CO2 14.04 % R 

### 05/07/10 14:10:49 02 5.11 % R 

### CO2 13.92 % R 

### 05/07/10 14:11:09 02 5.29 % R 

### CO2 13.79 % R 

### 05/07/10 14:11:29 02 5.53 % R 

### CO2 13.55 % R 

### 05/07/10 14:11:49 02 5.57 % R 

### CO2 13.55 % R 

### 05/07/10 14:12:09 02 5.47 % R 

### CO2 13.79 % R 

### 05/07/10 14:12:29 02 5.44 % R 

### CO2 13.79 % R 

### 05/07/10 14:12:49 02 5.51 % R 

### CO2 13.55 % R 

### 05/07/10 14:13:09 02 5.58 % R 

### CO2 13.55 % R 

### 05/07/10 14:13:29 02 5.54 % R 

### CO2 13.92 % R 

### 05/07/10 14:13:49 02 5.55 % R 

### CO2 13.79 % R 

### 05/07/10 14:14:09 02 5.58 % R 

### CO2 13.43 % R 

### 05/07/10 14:14:29 02 5.63 % R 

### CO2 13.67 % R 

### 05/07/10 14:14:49 02 5.57 % R 

### CO2 13.55 % R 

### 05/07/10 14:15:09 02 5.48 % R 

### CO2 13.55 % R 

### 05/07/10 14:15:29 02 5.49 % R 

### CO2 13.67 % R 

### 05/07/10 14:15:49 02 5.57 % R 

### CO2 13.67 % R 

### 05/07/10 14:16:09 02 5.65 % R 

### CO2 13.55 % R 

### 05/07/10 14:16:29 02 5.71 % R 

### CO2 13.43 % R 

### 05/07/10 14:16:49 02 5.71 % R 

### CO2 13.55 % R 

### 05/07/10 14:17:09 02 5.63 % R 

### CO2 13.55 % R 

### 05/07/10 14:17:29 02 5.48 % R 

### CO2 13.67 % R 

### 05/07/10 14:17:49 02 5.36 % R 

### CO2 13.79 % R 

### 05/07/10 14:18:09 02 5.32 % R 

### CO2 13.79 % R 

### 05/07/10 14:18:29 02 5.26 % R 

### CO2 14.04 % R 

### 05/07/10 14:18:49 02 5.25 % R 

### CO2 13.67 % R 

### 05/07/10 14:19:09 02 5.24 % R 

### CO2 13.79 % R 

### 05/07/10 14:19:29 02 5.22 % R 

### CO2 13.67 % R 

### 05/07/10 14:19:49 02 5.30 % R 

### CO2 13.92 % R 

### 31

### 05/07/10 14:20:09 02 5.24 % R 

### CO2 13.79 % R 

### 05/07/10 14:20:29 02 5.26 % R 

### CO2 14.04 % R 

### 05/07/10 14:20:49 02 5.51 % R 

### CO2 13.55 % R 

### 05/07/10 14:21 :09 02 5.64 % R 

### CO2 13.55 % R 

### 05/07/10 14:21:29 02 5.59 % R 

### CO2 13.55 % R 

### 05/07/10 14:21 :49 02 5.57 % R 

### CO2 13.43 % R 

### 05/07/10 14:22:09 02 5.51 % R 

### CO2 13.67 % R 

### 05/07/10 14:22:29 02 5.44 % R 

### CO2 13.55 % R 

### 05/07/10 14:22:49 02 5.26 % R 

### CO2 13.92 % R 

### 05/07/10 14:23:09 02 5.20 % R 

### CO2 13.92 % R 

### 05/07/10 14:23:29 02 5.32 % R 

### CO2 13.79 % R 

### 05/07/10 14:23:49 02 5.36 % R 

### CO2 13.67 % R 

### 05/07/10 14:24:09 02 5.38 % R 

### CO2 13.79 % R 

### 05/07/10 14:24:29 02 5.48 % R 

### CO2 13.43 % R 

### 05/07/10 14:24:39 02 5.48 % R 

### CO2 13.55 % R 

### 05/07/10 14:24:49 02 5.44 % R 

### CO2 13.67 % R 

### 05/07/10 14:24:59 02 5.46 % R 

### CO2 13.55 % R 

### 05/07/10 14:25:09 02 5.46 % R 

### CO2 13.55 % R 

### 05/07/10 14:25:19 02 5.47 % R 

### CO2 13.55 % R 

### 05/07/10 14:25:29 02 5.51 % R 

### CO2 13.43 % R 

### 05/07/10 14:25:39 02 5.58 % R 

### CO2 13.67 % R 

### 05/07/10 14:25:49 02 5.64 % R 

### CO2 13.55 % R Avg 

### 5.51 13.63



### 32

### Post3Bias 

### James River Cogen Unit NO.2 Post Run 3 Bias Metals/PM-10

05/07110 

### 14:26:29 02 5.63 % R 

### CO2 13.55 % R 05/07/10 

### 14:26:29 02 5.64 % R 

### CO2 13.67 % R 05/07/10 

### 14:26:34 02 5.68 % R 

### CO2 13.79 % R 05/07/10 

### 14:26:39 02 5.71 % R 

### CO2 13.55 % R 05/07/10 

### 14:26:44 02 5.75 % R 

### CO2 13.67 % R 05/07/10 

### 14:26:49 02 5.77 % R 

### CO2 13.67 % R 05/07/10 

### 14:26:54 02 8.56 % R 

### CO2 13.43 % R 05/07/10 

### 14:26:59 02 10.61 % R 

### CO2 10.62 % R 05/07/10 

### 14:27:04 02 4.65 % R 

### CO2 4.76 % R 05/07/10 

### 14:27:09 02 1.70 % R 

### CO2 1.71 % R 05/07/10 

### 14:27:14 02 0.70 % R 

### CO2 0.98 % R 05/07/10 

### 14:27:19 02 0.37 % R 

### CO2 0.37 % R 05/07/10 

### 14:27:24 02 0.23 % R 

### CO2 0.37 % R 05/07/10 

### 14:27:29 02 0.18 % R 

### CO2 0.12 % R 05/07/10 

### 14:27:34 02 0.15 % R 

### CO2 0.12 % R 05/07/10 

### 14:27:39 02 0.13 % R 

### CO2 0.24 % R 05/07/10 

### 14:27:44 02 0.12 % R 

### CO2 0.12 % R 05/07/10 

### 14:27:49 02 0.12 % R 

### CO2 0.00 % R 05/07/10 

### 14:27:54 02 0.11 % R 

### CO2 0.00 % R 05/07/10 

### 14:27:59 02 0.11 % R 

### CO2 0.24 % R 05/07/10 

### 14:28:04 02 0.10 % R 

### CO2 0.12 % R 05/07/10 

### 14:28:09 02 0.10 % R 

### CO2 0.12 % R 05/07/10 

### 14:28:14 02 0.09 % R 

### CO2 0.12 % R 05/07/10 

### 14:28:19 02 0.09 % R 

### CO2 0.24 % 

### R 05/07/10 

### 14:28:24 02 0.09 % R 

### CO2 0.12 % R 05/07/10 

### 14:28:29 02 0.09 

### % R 

### CO2 0.12 % R 05/07/10 

### 14:28:34 02 0.17 % R 

### CO2 0.12 

### % 

### R 05/07/10 

### 14:28:39 02 4.39 % R 

### CO2 1.22 % R 05/07/10 

### 14:28:44 02 9.52 % R 

### CO2 4.52 % R 05/07/10 

### 14:28:49 02 11.38 % R 

### CO2 6.23 % 

### R 05/07/10 

### 14:28:54 02 12.02 % R 

### CO2 6.84 % R 05/07/10 

### 14:28:59 02 12.23 % R 

### CO2 6.96 % R 05/07/10 

### 14:29:04 02 12.28 % R 

### CO2 6.96 % R 05/07/10 

### 14:29:09 02 12.33 % R 

### CO2 7.32 % R 05/07/10 

### 14:29:14 02 12.35 % R 

### CO2 7.08 % R 05/07/10 

### 14:29:19 02 12.40 % R 

### CO2 7.45 % R 05/07/10 

### 14:29:24 02 12.43 % R 

### CO2 7.32 % R 05/07/10 

### 14:29:29 02 12.43 % R 

### CO2 7.08 % R 05/07/10 

### 14:29:34 02 12.44 % R 

### CO2 7.32 % R 05/07/10 

### 14:29:39 02 12.45 % R 

### CO2 7.45 % R 05/07110 

### 14:29:44 02 12.45 % R 

### CO2 7.32 % R 05/07/10 

### 14:29:49 02 12.45 

### % R 

### CO2 7.45 % R 05/07/10 

### 14:29:54 02 12.46 % R 

### CO2 7.32 % R 05/07/10 

### 14:29:59 02 12.46 % R 

### CO2 7.45 % R 05/07/10 

### 14:30:04 02 12.48 % R 

### CO2 7.32 % R 05/07/10 

### 14:30:09 02 12.62 % R 

### CO2 7.45 % 

### R 05/07/10 

### 14:30:14 02 16.44 % R 

### CO2 8.30 % R 05/07/10 

### 14:30:19 02 19.93 % R 

### CO2 10.50 % R 05/07/10 

### 14:30:24 02 21.25 % R 

### CO2 11.60 % R 05/07/10 

### 14:30:29 02 21.69 % R 

### CO2 11.96 % R 

### 3305/07/10 14:30:34 02 21.84 

### % R CO2 11.96 

### % R 05/07/10 14:30:39 02 21.90 

### % R CO2 11.96 % R 05/07/10 14:30:44 02 21.92 

### % R CO2 12.08 

### % R 05/07/10 14:30:49 02 21.95 

### % R CO2 12.21 % R 05/07/10 14:30:54 02 21.96 

### % R CO2 12.08 % R 05/07/10 14:30:59 02 21.97 

### % R CO2 12.08 % R 05/07/10 14:31 :04 02 21.98 

### % R CO2 11.72 

### % R 05/07/10 14:31:09 02 21.98 

### % R CO2 

### 12.45 % R 05/07/10 14:31 :14 02 22.00 

### % R CO2 12.33 % R



### 34·

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### Appendix B 

### Laboratory Data

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........ :. 3338eval EPAS/wel202 1 of 23 

# irNova, Inc

. 5845 Clayton Avenue, Pennsauken, New Jersey 08109 (856) 486-1500

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.. 

### www.airnova.com



### NELAC & NJ Lab Cert. No. 04011 PA Env. Lab Reg. No. 68-1676


## EPA Method 5 - ParticulateAnalysis Results Summary (Mass Data)

Client: AirNova Project#: Location: Lab Book#: Sample Date:

Date Rec'd: AirNova @ 

### James River

- Hopewell, VA 3338

- Evaluation Unit 2 5-3-54 5/7/2010 5/10/2010

SampleTrain FilterAnalysis

Run# Mass (mg) Tare(g) Total(g) Diff(g) Qual. Eval. 1 4.0 0.3702 0.3742 0.0040 gray 

### 2 4.5 0.3797 0.3842 0.0045 gray 

### 3 3.2 0.3569 0.3601 0.0032 gray



### Acetone RinseAnalysis

Run# Mass (mg) Tare(g) Total(g) Diff(g) Samp.Vol(mLl 1 

### 3.8 3.5766 3.5804 0.0038 200 

### 2 2.7 3.8969 3.8996 0.0027 200 

### 3 

### 2.9 3.7630 3.7659 0.0029 200 Field Blank 

### 3.3051 3.3051 

### <0.0003 200
Gravimetric MDL= 0.3mg

Date Date 

# rkl//o
b?"""

- -/ 

### Secondary Review The analytical results obtained relate onlyto the samples included within this report. This report should not be reproduced except in full, withoutthe written approval ofAirNova, Inc. AirNova, Inc. certifies thatthe test results contained in this r port ret all requirements of NELAq.

.



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### Client: AirNova Project#: Location: 3338eval EPA5/wet202 2 

# irNova, Inc

. 5845 Clayton Avenue, Pennsauken, New Jersey 08109 (856) 486-1500 " FAX 486-9896 6 www.airnova.com

NELAP & NJ Lab Cert. No. 04011 PA Registration 

### # 68-1676


### AirNova 

### @ James River

- Hopewell, VA 3338

- evaluation Unit2 

## EPA Method 202 Condensable Particulate MatterSummary (Mass Data) Lab Book#: EPA202-2-127 Sample Date: 5/7/10 Date Received: 5/10/10 mo

# =Mass oforganic CPM, mg mi 

### = Mass of inorganicCPM, mg mob

# =Org. Blank, mg mib

# =Inorg. Blank, mg (Volume adjusted) mi

# =mr *Vic/ (Vic

- Vb)

- mc mr

# =Mass ofdried samplefrom inorganicfraction, mg mc

# =Mass of NH4+ added to form ammonium sulfate, mg Vie

# = Total volume ofsample impingercontents, mL Vb

# =Volume ofaliquottaken forsulfate analysis, mL Mo

# =mo - mob Mi 

### = mi

- mib
Total milligrams ofCPM

# =Mo 

## + Mi (top of Eq. 202-3, EPA202 Section 7.4

- modified)

Results based on applied NH4+ K=0.3542: 

### Run# Total CPM mg Mo mo* mob Mi mi mib mr me Vic Vb 1 2.7 

### 0.0 0.0 0.0 2.7 2.7 0.0 5.7 3.35 665 40 2 4.9 

### 0.0 0.0 0.0 4.9 4.9 0.0 8.6 4.23 720 40 3 7.7 0.0 0.0 0.0 7.7 7.7 0.0 8.9 1.82 650 40

Results based on calculated maximun NH4+ possible in residue: 

### Run# Total CPM mg Mo mo* mob Mi mi mib mr mc** Vic Vb 

### 1 4.5 0.0 0.0 0.0 4.5 4.5 0.0 5.7 1.56 665 40 

### 2 

## 6.8 0.0 0.0 0.0 6.8 6.8 0.0 8.6 2.35 720 40 3 7.1 

### 0.0 0.0 0.0 7.1 7.1 0.0 8.9 2.43 650 40

The boldfaced results representthe most realistic milligrams without under reporting Total CPM. *Gravimetric MDL= <0.3 mg

** Maximum Ammonium possible due to 27.3% ofdried residue (mr) mc= mrx0.273

The analytical results obtained relate onlyto the samples included within this report. This report should not be reproduced except in full, withoutthe written approval ofAirNova, Inc. AirNova, Inc. certifies thatthe test results contained in this report mel:::tall requirements of NELAC.



### 2. !



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.. 5846 Clayton Avenue. Pennsauken. New Jersey 08108 (858] 488-1600

.. FAX 486-9896 • www.airnova.com



## Notes concerningthecorrectionfortheAmmoniaaddedduringEPA202analysis Duringthe Section7Equation202-2calculation,thetotalmassofinorganicCPM (mi) isobtainedfromthemassofdriedinorganicsample(mr). Afteranalytically obtainingtheamountofsulfatethatisintheinorganicfraction, themassoftheammonia addedtothe sample(me)tofOImammoniumsulfateiscalculatedaccordingtoEquation 202-1. Ifthereismoresulfatepresentthatisnotassociatedwithammonia,theammonia

mass couldbe**~alculated** 

## falselyhigh. 

## Whenthehigherammoniamassis subtracted from thedriedinorganicfraction (mr),thetotalinorganicCPMcouldbebiasedlow. As asecondaryQCcheck, AirNova, Inc. has addedanadditionalcalculationtoits report. Ifthedriedinorganicsamplemass (mr)is 100% ammonium sulfate (NH4)2S04, ,themostammoniumthatcanbepresentis27.3% ofthesamplemass (basedon ammonium'smolefraction). Thisrepresentsthemaximumammoniumthatcanbeinthe driedinorganicsampledueto associationwithsulfate. IfEquation202-1 calculatesanammoniamassthatisgreaterthantheamountthat ispossibleduetotheinorganicmass (mr) being 100% ammoniumsulfate(NH4hS04, thelowerammoniamass (me) is subtractedduringEquation202-2toreduceanylowbias tothetotal inorganicCPM.

AirNova Information Sheet#24 Revision0



### 33338eval EPA5/wet202 4

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-FractionInformationandCalculations

4

### Client: AirNova Project#: 

### Location: AirNova @ James River

- Hopewell, VA 3338

- evaluation Unit 2 3338eval EPA5/wet202 5



## EPA Method 202 Condensable ParticulateAnalysis (Mass Data) Lab Book#: EPA202-2-127 Sample Date: 5/7/10 Date Received: 5/10/10

Back HalfOrganic Fraction

- (volume ofMeCl2 forall samples & blanks is constant) Mass oforganic CPM (mo) Vol.(Vic) Aq. Vol. 

### Run# 

### .(mg} Tare(g) Total(g) Diff(g) :mL) Extracted 

### 1 0.0 * 3.6704 3.6704 0.0000 665 625 2 0.0 * 3.9481 3.9481 0.0000 720 680 3 0.0 * 3.5953 3.5953 0.0000 650 610 Field Blank 

### 0.0 * 3.4563 3.4563 0.0000 400 360

*Gravimetric MDL

### = < 0.3 mg

" ,.,


# ...

'

# .. "

### ::: AirNova. Inc

. 

### 5

### Client: AirNova Project

### #: Location: AirNova @ James River

- Hopewsll, VA 3338

- evaluation Unit2 3338eval EPA5/wet202 6



## EPA Method 202 Condensable ParticulateAnalysis (Mass Data) Lab Book

### #: EPA202-2-127

Back Half Inorganic Fraction

-Aqueous post-extraction Mass of Inorganic CPM (mi)

NH4+ added (mc) mi=(mg) 

### llmli Tare(g) 

## 2.7 Total Vol. Total(g) Net Diff(g) (mL) 

### 665 Vol.(Vb)** Dried inorganic mass (mr) (mL) 

### llmli 40



### 2



### 3 pick up (mL)= 

### 196 Adjusted InorganicVol (Vic)= 

### 469

5.6934 5.6962 0.0028 5.8205 5.8234 0.0029 0.0000 0.0000 0.0000 3.35 0.0000 0.0000 0.0000 5.7 (mr)



### 4.9 720 40 pick up (mL)= 

### 196 Adjusted InorganicVol (Vic)= 

### 524

5.7625 5.7682 0.0057 5.7967 5.7996 0.0029 0.0000 0.0000 0.0000 4.2 0.0000 0.0000 0.0000 8.6 (mr)


## 7.7 650 40 pick up (mL)= 

### 194 Adjusted InorganicVol (Vic)= 

### 456

5.6626 5.6675 0.0049 5.8065 5.8105 0.0040 0.0000 0.0000 0.0000 1.82 0.0000 0.0000 0.0000 8.9 (mr)

Field Blank 

### 5.9884 5.9884 0.0000 400 40 0.0

** Volume taken forsulfate analysis *Gravimetric MDL = < 0.3 mg 

### 500mL equiv.= NA The analytical results obtained relate onlyto the samples included within this report. This reportshould not be reproduced except in full, without thewritten approval ofAirNova, Inc. AirNova, Inc. certifies thatthe test results contained in this report meet all requirements of NELAC.



### 6 (post NH4+ aliquot adjusted)

### Client: AirNova Project#: Location: Test Date: Dates Rec'd: Lab Book#: 3338eval EPA5/wet202 7

NELAC & NJ Lab Cert. No. 04011 PA Registration 

### # 68-1676 

### AirNova 

### @ James River

- Hopewell, VA 3338

- evaluation Unit2 

### 5/7/2010 5/10/2010 EPA8-1-124 

## Sulfate LaboratoryAnalysis Summary

- EPA Method 202 Ammonia Correction (EPA Method 5F Section 16.1.3.4) Standardizations Ba2+ Solution Standardization against Sulfuric acid 5.0 mL (S04)2- used 0.0100 Molar (S04)2- lot

### # G30519

15.20 mL Ba2+ solution at equivalence point Calculated Concentration of Ba2+ solution= 0.0033 Molar= 0.0066 Normal 

### (S04)2- Control Sample against Ba2+ Standard Solution 4.0 mL (S04)2- 0.0104 M (S04)2- lot

## # 120409

12.60 ml Ba2+ Solution at equivalent Calculated Concentration of Ba2+ Standard Solution (Log-3-23)= 0.0033 Molar: 0.0066 Normal = 100 % Recovery Ba2+


### Sulfate SampleAnalysis K=0.3542

Run# Sample Description SampleAliquot Titrant (Ba2+ sol'n) Sulfate Conc.= Total 804 Total NH4+ Vol.= V(ic) Titrated 1st 2nd Average C(S04) Mass = Mass=m(c) (mL) (mL) (mL) (mL) (mL) (mg/ml:.) (mg as 804) (mg as NH4+) 

### 1 665 H2O 

### 10.0 0.45 0.45 

### 0.45 0.0142 9.45 3.35 2 720 H2O 

### 10.0 0.55 0.50 

### 0.53 0.0166 11.94 4.23 4 650 H2O 

### 10.0 0.20 0.30 

### 0.25 0.0079 5.13 1.82 Blank 400 H2O 

### 10.0 

### < 0.05 

### < 0.05 

### < 0.05 

### < 0.0016 

### < 0.63 

### < 0.22

MDL= 0.027 mg as sulfate The analytical results obtained relate onlyto the samples included within this report. This report should not be reproduced except in full, without thewritten approval ofAirNova, Inc.

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### ntainerTypeLegend P=polybottle(HDPE) G=glassw/fluorolid T= trap V= vial D= Petridish 

# ChainOfCustodyDocumentationForm

SampleFractions (indicate

### #ofeach& ContainerType) I

--••.,...- _._. "".",- I "'- 

### I

## ReportResultsTo: ! s 

# AirNova, Inc

. 5845 Clayton Ave, Pennsauken, NJ 08109 856486-1500 Fax: 856486-9896 

## www.airnova.com

FractionTypeLegend W=wash F=front C=catch B=back Q

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# . . . AirNova, Inc. Laboratory CalibrationDocumentsandAnalyticalCertificates

10GENERAL1 

### TISSUQUARTZ is a high purity filter for the sampling and analysis of trace 

### quant.ities of particulates 

### in ambient to high 

### temperature 

### gas Gtreams. It 

### is made 

### from pure silica '(quartz micro fibers), 

### under clean manufacturing rond

### iti

### ons•**NPLTCATI~:** 

### Stack and 

### aerosol sampling and 

### monitoring. 1>.tomic absorption spectrophotometric 

### analysis (1\-;5). 

### Flame emission spectrophotometric 

### analysis (FES). 

### X-ray 

### fluoroescence and spectrographic 

### analysis, Hay be used at up to 

### 2500 degrees F.
ATh.ll.\HLE TYPES: 

### TIS$UQUARTZ 250OQAo-UP

- approx. 

### 0.016" thick (per TN""?I 441). 

### TISSUQUARTZ**250OQ.~T-UP** 

### - 

### type 250OQAO-UP 

### plus Heat Treatment for l::eduction of 

### trace organics cHid 

### imparts higher 

### strength.
1>.

VAII.ABLE SIZES: 

### Packaged 8" 

### :x 10" 25 sheets/J::ox Discs of 37mn; 47nro; 51lml(25 

### discs per }:)a.x) 

### other sizes and 

### shapes also available. MalnicaJ. Test ResuJ.ts of**TI~:** 

### Following is compilation 

### of test 

### reSUlts from independent test labs and EPA and other sources to**se~e** 

### as guide, but 

### not sF€cificatio,'s, on 

### TISSUQUARTZ. Typical reported data on TISSO(>Ji'.RTZ 2500l\l;;o

.... UP [.**250-')5~** 

### Hicrograms/Sg.Inch
tIH 4 + .22 

## .±. .07 CR -:: .06 l'i <: .06 

### S03 .02 + .10 CO 

### <: .01 S';.J 

### -< 

### .12 504 

### .37 

### .07 Cu 

### <: .12 V .12 

### .:!:. ',

# . N03 

### 20 

### Pb <: 

### .025 Zn <: 

### .12 Cl- 

### .12 + 

### .03 

### Hn <: .12 

## Cc <: 

### .05



### - 

### < 1 .25 Be 

## < .01 Ho 

### < .17 As 

### '!'ensiles: 400 

### gpli pH 

### in 6-7 nU1;:W

TISSUQUARTZ h.as a very high 

### efficiency of OV<2r 99.97""'; 'bas(-d**c·:~** the 

### Utieron D.O.P. 

### aerosol 

### t€:st. J\ir Flow resista.'1CB by 

### Gurley de:-1So,'l'.et,er- 

### a!:. 100cc/s:j. 

### Inch

- 3**secon(.1~;** 

### Avg.

Ttl!}**iflfor(nahD"'~ ~fld** **,j~la pre$~r.led**  1$**~ased** on VJ:r,l,]US tes:s Of (\?DC:rl.;O**e"~€:;l·::~l(€:.** anc i.; CO:"I$ioerlS:O ¥:<:t

...'-':12 HO

..•
..**~~vt::~.** no**YlaH~''':)'** I$.**cr.P(S!·:·$.?~** or**Imp~ied** fOf ttle. ff!SultS :!J:le obtdlOed :tQ!71 :t-.e**::O!.;-nd~d** \,:$1: there':::>L Ct It-.at G"')" :;·_,;:.r. lJS"} '-\'11: no:**ir"".~ri.",.)(1** any**:,::.:~nt.** ThiS ,nfcd'"niah(lf1 a:\d!ol**m~~I(!f1~!1** is 1urnishedupv:'\the**~{;njl1tor:** a"'.a:**:."~** tlE:-SO:l**rer~i·./lli';** an::J I.,;;ing i: · ....111**"'.~k=** il:5 -.)

...."1'.**:~$ts** to O€lfsfn-i1n8trj:..! sLIt:.i.t.,.::tr thE-feo! '[Ifhi:;. PM1t::t.:laf**Plj:~;:-I;;t-:**

# C§~0 t6C3S00!W 

## PALLFLEX PRODUCTS COMPANV

• F
125 KennedyD:i..-a,**;:·t1~;"\a** ..r

.. Cc,nt\(:cHcu1 OG2GO (20.3},926·Tl6t

# :'A~solu{e P'>Iji}nna!/ct**,~,-~** ...



### 11Certificate No.: 020213-753-080309 MettlerToledo Service Business UnitLaboratory 1900 Polaris Parkway Columbus, OH 43240 1-80D-MEDLER ISO 9001 : 2000Registered


# Calibration Certificate Customer

Company: Address:

City: Zip/Postal: 

# Device

Manufacturer: SerialNo.: Max Capacity: Model: AIR NOVA INCORPORATE 5845-A CLAYTON AVENU

PENNSAUKEN 08109

MettlerToledo J28261 205 9 1529 AT250 State/Province:

AssetNo.: DepURoom: Readability: NJ

N/A N/A 0.0001 9 10.00001 9

Procedure Statement: The device referenced inthis document has been metrologicallytested in accordance with MEDLERTOLEDOWork InstructionVW0152A. All translations intoother languagesare based on the referenced work instruction, which is in English. This certificate refers to: As Found and As Left

TestDate: Service Technician: 3-Aug-2009 Carlos Toscano NextCal. DueDate: 31-Aug-2010 A Signature: 

# &vL,/k£'&Vl-O
ReferenceWeights

<. '

Form No.:VF0066A Soflware Version:4.0.1.9 

### 12 This is an original document, an electroniccopy is retained by MEDLER TOLEDO 16280500A TraceabilityofTest Equipment:


## WeightSet 1 WeightSetNo.: Calibration Due Class: Allweights usedfor metrologicaltesting aretraceableto national or international standards. Theweightswere calibrated and certified byan accredited calibration

Date ofIssue: 20-Aug-2008**----=~--------** NISTTraceabilityNo. MT5061 

## -..:-:...-_-------

Page 1 of3 

### © MEDLERTOLEDO

### CertificateNo.: 020213-753-080309 

# Measuring Results 

# METTLER TOLEDO

AsFound TestWeight Position Displayed Value Deviation



### C: 

### 1009 Center 

### 0.00009 N/A 

### 1: 1009 LeftFront 

### 0.0001 9 0.0001 9 2: 1009 LeftRear 

### -0.0002 9 -0.00029 3: 1009 RightRear 

### 0.0001 

### 9 0.0001 

### 9 4: 100g RightFront 

### -0.00029 -0.00029 EccentricLoadDeviation: 

### 0.0002g Manufacturer Specifications: 

### 0.00029 Manufacturer SpecificationsRoundedto Resolutionof Eccentric LoadDeviation: 

### 0.0002 SpecificationsMet: 

### YES AsLeft DisplayedValue Deviation 

### O.OOOOg N/A 

### 0.0001 

### 9 0.0001 

### 9 -0.0002 9 -0.0002

### 9 0.0001 

### 9 0.0001 

### 9 -0.0002 9 

### -0.0002 9 

### 0.00029

0.00029

0.0002

YES 

# Sensitivity

AsFound DisplayedValue Without With Deviation Reference Reference Reference

Weight Weight Weight 

### 199.99999 

### O.OOOOOg 200.0003 

### g 0.0004g SensitivityOffset: 

### 0.0004 9 ManufacturerSpecifications: 

## N/A ManufacturerSpecifications RoundedtoResolutionof SensitivityOffset: 

## N/A SpecificationsMet: 

## N/A AsLeft Displayed Value Without With Deviation Reference Reference

Weight Weight 

### O.OOOOOg 200.0001 9 

### 0.00029 SensitivityOffset: 

### 0.0002 9 ManufacturerSpecifications: 

### 0.0003 

### 9 ManufacturerSpecifications RoundedtoResolutionof SensitivityOffset: 

### 0.0003

### 9 SpecificationsMet: 

### YES



### Form No.:VF0066A SoftwareVersion:4.0.1.9 This is an original document, an electroniccopy is

## ret~~ed byMETTLERTOLEDO Page2of3 

### © METTLERTOLEDOCertificate No.: 

### 020213-753-080309**n"llOI~** 11'&'11'\6

- 

# Differential Method

TestWeight 

### 50.000009

AsFound Displayed Value Preload Deviation 

### * Weight Preload Test Weight


### 1 

### Og 0.0000 9 

### 50.0001 9 0.00007 9 2 50

### 9 50.0001 9 100.0001 9 0.00004 9 3 100

### 9 100.00029 150.00029 0.00001 9 4 

### 1509 150.0003 9 200.0003 9 -0.000029 LinearityDeviation: 

### 0.00007 9 ManufacturerSpecifications: 

### 0.0002 9 ManufacturerSpecifications RoundedtoResolutionof LinearityDeviation: 

### 0.000209 SpecificationsMet: 

### YES 

# METTLER TOLED

AsLeft DisplayedValue Deviation 

### * Preload TestWeight


### 0.0000 9 

### 50.0000 9 

### 0.00000 9 

### 50.00009 

### 100.00009 0.00000 9 100.00009 150.0000 9 

### 0.000009 150.0001 9 200.0001 9 0.000009 LinearityDeviation: 

### 0.00000 9 ManufacturerSpecifications: 

### 0.0002 9 ManufacturerSpecifications RoundedtoResolutionof LinearityDeviation: 

### 0.00020 9 SpecificationsMet: 

### YES

16280500A * This Linearity Deviation is zero pointoffsetand sensitivityerrorcompensated. 

# Remarks

None.

Form 

### No.:VF0066A Software Version:4.0.1.9 

## 14 This is an original document, an electronic copy is retamed by METTLER TOLEDO Page 30f3 

### © METTLERTOLEDO

### -------- 

## --- 3338eval EPA5/wet202 15



### 15

--------.---------- ------Since 1903 

### 3338eval EPA5/wet202 16 

# ort Traceable to NIST
ISO 9001 Registered The Instrument described below has been examined and tested in H-B Instrument Company's Calibration Laboratory using controlled constant temperature equipment and NISTTraceable ReferenceThermometers, in accordance with H-B's ISO 9001 Calibration procedures, and NBS Monograph 174,ASTM Method E77, NIST Special Publication 819, and the International Temperature Scale ITS-90. Calibration is traceable to NISTand is in compliance with MIL-STD 45662A andANSIIASOC 09002-1994. For adiscussion ofaccuracy obtainable with such thermometers, see NIST SP 250-23. 

### 14-Sep-04 VWR International
1451 North Raddant Road Batavia IL 60510

Tel: Fax: Reference

### No: 6447997 ReportNo. SerialNo PartNo Distributor Manufacturer Item Range 

### 307695 3V0393 61099-139 VWR International H-B InstrumentCompany/MW Thermometer, Partial Immersion 95/155°C, 0.2°Div., 108mm Imm.

AmbientAirTemperature: N.I.S.T. Standard



### O.OOO°C 100.000°C 110.000° C 130.000°C 150.000°C Instrument Tested 

### 0.060°C 99.940 ° C 109.980°C 129.920° C 149.960 ° C Correction (ITS-90)*



### -0.060 0.060 0.020 0.080 0.040 N.I.S.T. N.I.S.T. Test Emer. Stem** SerialNo. TestNo. Liquid Temperature



### 710015 53394 Ice °T 710015 53394 Oil 55.0° C 710015 53394 Oil 55.0°C 710015 53394 Oil 45.0°C 710015 53394 Oil 40.0° C RelativeHumidity: 

### 31 

### % T

-Total Immersion

This Report ofTest may not be reproduced withoutthe express written permission of H-B Instrument Company•

Design Copyright ©HBI 2004 

## H

-B InstrumentCompany
102West SeventhAvenue, Trappe, PA 19426-0770 USA Telephone 1-600-4-TEST-LAB Fax (610) 489-9100 

### JB e-mailAddress: cal@hbinstrumentcom 

### JB WebsiteAddress: www.hbinslrumentcom

Fonn 0-592 Rev.6 • Observed instrument readings should be increased bypositive numbers or reduced by negative numbers indicated bya minus (-) sign

. •• Emergent Stem Temperature relates to PARTIAL IMMERSION thermometers ONLY (see reverse). The Platinum ResistanceThermometer (PRT) serial numberabove, was calibrated with anAC Bridge at afrequency of90Hz and a constant currentof 1.0 rnA. This procedure is based on the technical information contained In NISTTechnical Note 1265. Comparison points used to calibrate the thermometer range from atemperature of-196.000°C to 420.000°C. The calibration uncertainty ofthe AC Bridge and PRT is estimated notto exceed O.026°C. The Instrument is in good working order and is suitable for calibration. The capillary of the thermometer has been examined under magnification and no discernable capillary irregularities were noted. Strains in the glass revealed byexamination undera polarized lens, if any, were judged to be minimal and ofno' detrimenttothe function ofthe instrument As a general gUideline, certification/calibration of instruments onceyearly is considered acceptable in most manUfacturing and laboratorypractices, but each 0 .• tion must set its own policies. 4.

### 3338eval EPA5/wet202 17

< 

### 0.3 

### Product No. 5693

Lot No. G30519 Release Date 

### 07/28/2008

1 max. 0.3 max. 0.5 max

. <0.5**=~~="~4~"·~~~·~'="~~"·-····~--·** --_.

__**._~-~_.=,,~~~~_.**

# ------.--._._ ..-. <0.2 

# SulfuricAcid, O.02N Volumetric Solution 'BAKER ANALYZED'@



# .**""._-.~~~----. --~~**  

# "**,,-<~~~._~.~~~--_.** 

# _.**~_._. ------.-~**  

# ..-----_i**~~ra~~~, Research~rM~~.~~~~~_e**  • 

# --------=1 USE BEFORE July 31, 2010 

### CountryofOrigin: USA

Forquestions on this Certificate ofAnalysis please contactTechnical Services at 1-800-582-2537or908-859-2151 Mallinckrodt Baker, Inc.•222 Red School Lane' Phillipsburg, NJ 08865' Phone: 908.859.2151 • Fax: 908.859.6905



### 173338eval EPA5/wel202 18 

# ertificateofAnalysis

NSI Solutions, Inc. 

# *7212ACCBlvd. 

# * Raleigh, NC 27617

# * 1-800-234-7837

Mixture Name: Sulfate (S04), 1000 ppm Part Number: IS-015-100, 500 Lot Number: 120409 EXP Date: 12/2011 Solvent: ReagentWater

Compound Number



### W-1387-04 ANALYTE PURITY (%)



### 99.8 CERTIFIED CONCENTRATION (mg/L)



### 1000

PREPARATION: Reported concentration value 

### has been corrected forpurity using purityvalues obtained by NSI analysts. Concentration is certified by IC analysiswith recovery

### of 103.6%. Microbalances calibrated with NISTtraceable weightsto 0.0001 g and/orASTM ClassA volumetricglassware orcalibrated equivalent labware.

STORAGE 

### & HANDLING: Afteropening, store at5°C. Allowto equilibrateto room temperature before use.

Instructionsfor Use: Sample provided in awhole volumeformat. Nodilution is required.



### 18

### 3338eval EPA5!wet202 19

F . (847) 948-1078· Web: alitechWEB.com 

# lid-Phase Hxtraction Products

Alltech Associates, Inc.•2051 Waukegan Rd' Deerfield, IL60015·Tel: (847) 948-8600· ax. 

# Qualit\[Certificate Packing 

## Type:
Lot No.: 

## IC-H 

# 0701000136 PolymerType: FunctionalGroup: CounterIon: Pm"tical SizeRange: MolecularExclusion Limit: 

### ExchangeCapacity: StyreneDivinylbenzel1e SulfonicAcid Hydrogen 

### 75

- 150**~I** 

### 1000Daltons 2.0meq/mL



## CounterIon Selectivity
Relative elution strength for counter ions on SCX:

General Procedure for Ion Exchange Extraction:
1. Condition Pacl<ing bed with 5 - 10 mL ofdeionized waterora lowionicstrength buffer (e.g. 1 mM to 5 mM). Don't letthe packing dry!
2. Applythe sample.
3. Wash the bed with aweak elution solvent (e.g. deionized waterorlow ionicstrength buffer).
4. Wash the bed with a weak elution solvent (e.g. higher ionicstrength bUfferorbufferat a pH that decreases sample ionization). NOTE: Compounds (both ionized and neutral forms) must be soluble in the elution solvent. The polymeric backbone ofthe resin has the potential for non-polar (especiallyaromatic) secondary interactions with the sample, reducing recovery. These interactions can be overcome with the addition ofan organic modifier, liI<e methanol, to the elution solvent. Lot to lotvariation in resin color is cosmeticonlyand does not affect resin performance.



### Approved-

# .£~ 19 SPE QC Technician

- Scott Irwin 1118/2007

### DataSheet 30264U 3338eval EPAS/wet202 20


# IC-H and IC-H Plus Devices

Alltech Associates, Inc.• 2051 Waukegan Road· Deerfield, IL 60015-1899 •Telephone: (847) 948-8600 • Fax: (847) 948-1078 

### Introduction
Maxi-Clean' and Extract-Clean' ICDevices are solid-phase extraction devices usedto eliminatematrixinterferences from samples priorto analysesbyion chromatography. Each deviceconsists ofeitherO.5mL or 1.5mLofpolystyrene-based packing sandwichedbetween polyethylenefrits withinan injection-moldedmedical-grade polypropylene housing (Figure 1). Samples and wash solvents are passedthrough the packing using aluerhub syringe (forMaxi-Cleans') ora vacuummanifold (forExtract-Cleans'). As sample comesin contactwith the packing, specificchemicalinteractions takeplace which selectivelyretain certain components ofthe matrixinthe device whilethe remaining componentspass throughthe device outlet. The chemical characteristics ofthe packing dictate which sample components are retained. Sevenchemistries are currentlyavailable. SuccessfulapplicationofIC devices requires: 1) properconditioning ofthe devicepriorto sample application, 2) application ofthe sample atarate slowenoughto allowthe chemicalinteractiontotake place while the sampleisin the device, and 3) control ofsample sizeto keep within the device's capacity. The following informationprovides general recommendations for the use ofIC-H devices. Thisprocedure maybe modified to accommodate samples with differentcharacteristics. 

## GeneralInformation
Maxi-Clean" and Extract-Clean" IC-H provide areliable method for the adjustment ofpH ofbasic samplespriortothe analysis ofanionsbyion chromatography. Theymay alsobeusefulforremoving cations from samples priorto the analysis ofanions. IC-Hdevices contain either 0.5mL or 1.5mLofsulfonic acid cation exchangeresinin the H' form. The hydroniumcontainedon thepacking reacts with hydroxide from the sampleto form watertherebyreducing pH. Inthis process, cations from the sample are takenupbythe resin to replace the hydronium consumedin the neutralizationreaction. The netresultis removal of hydroxide (and an equivalentamountofsample cations) from the matrix. Polyvalent cations willbepreferentiallyretained over monovalent cationsin acidic samplesproviding amechanismfor removal ofpolyvalentcations. The recovery ofweaklyionizedanions such as nitrite andphosphate couldbepoor aftersamplepretreatmentwithIC-H. The loss ofthese anions maytake place through anumberofdifferentmechanisms, including evolution ofnitrous oxide, oxidation ofnitrite to nitrate, adsorption in the resin or acombination ofeffects. Astudy ofthe recoveryofions ofinterestin each sample matrix shouldbe determined before quantitative results are obtained.

Formoreinformation on the use ofMaxi-Clean" IC cartridges andthe recoveryobtainedwith eachplease see: R. Saari-Nordhaus, J.M. Anderson, Jr. andI.K. Anderson,Am. Lab., August (1990) 18. LK. Anderson, R. Saari-Nordhaus andJ.M. Anderson, Jr., J. of Chromatography, 546 (1991) 61-71. Figure 1 

## Flowrate
The devices haveanumberofflow-dependentparametersthat may affectresults. In general, high flowrates, particularlyin the sample loading step, willdecreasetheperformancewhilelowflowrates will improve the extractionprocess. Lowflowrates allowthe sample to diffuseinto thepacking thus increasing capacityandimproving the efficiency. Therecommended flowrate for sample loading is lmLI minute orless. 

### Sample Mass
Each devicecontains either0.8 or2.0 milliequivalents ofH' (forthe 0.5mL or 1.5mLdevice, respectively), which underideal conditions will remove an equal amount ofhydroxide orpolyvalentcations from the sample. Inpractice, this maximumcapacitymaynotbe realized. The nature ofthe sample (concentration, ionic strength, solvent) and the rate atwhich the sampleis loadedinto the devicewillaffectthe capacity. Wherepossible, adjustsample sizeto use 50% ofless ofthe device's absolute capacity. Larger amounts ofhydroxide orpolyvalent cations mayberemovedby using two ormoreMaxi-Clean" cartridgesin series. Ifthe amount ofhydroxide orpolyvalentcationsin the sample is unknown, atestextraction shouldbe performed to determine the correct sample size.

Page 1 30264U
© Copyright 2000 AI/tech Associates, Inc. Contact yourAI/tech office ordistributorfor current or local prices. 

### 20

## CertificateofAnalysis 3338eval EPA5/wet202 21

Arlington, TX 76012 Pocomoke City, MD 21851 Batesville, IN 47006 http://www.riccachemical.com 1-888-GO-RICCA customerservice@riccachemical.com Phenolphthalein Indicator, 0.5% (wlv) in 50% (v/v) Alcohol, Neutralized
Lot Number: 2911023 Product Number: 5600 Expiration Date: OCT2011 Manufacture Date:11/2/2009 This producthasa slightcolorbecause it has been purposely neutralized to eliminate any acidic blank. Contains: 

## IName CAS# Grade

EthylAlcohol (Ethanol), CH3CH20H Methanol (Methyl Alcohol), CH30H Phenolphthalein, C20H1404 Water, Deionized, H20 64-17-5 67-56-1 77-09-8 7732-18-5 USP NF ACS ACS, AS1MD 1193 (TypeI),EP, USP

/festName Appearance Suitability for Use AssayMethod Clarity, Color, Odor
CharacteristicCheck Specification Clear,verylightpink, alcoholodor Colorless(pH8.0)

-Pink (pH 10.0) Result PassedTest

PassedTest**~pecification** Reference MethodNumber PhenolphthaleinIndicatorSolution(5 gIL) PhenolphthaleinIndicatorSolution PhenolphthaleinIndicatorSolution(5 gIL) PhenolphthaleinIndicatorSolution(5 gIL) PhenolphthaleinIndicatorSolution(5 gIL) PhenolphthaleinIndicatorSolution(5.0gIL) PhenolphthaleinIndicator PhenolphthaleinIndicatorSolution, Alcoholic PhenolphthaleinIndicatorSolution PhenolphthaleinIndicatorSolution Phenolphthaleinsolution,alcoholic,pH8.3 indicator AS1M AS1M AS1M AS1M AS1M AS1M APHA(14thEd) APHA APHA(14thEd) APHA APHA D287M D 3590A D515A D 1067B D 1067C D2187E 407B 5570C 311 B 4500-CI-B 2320B

7500-RaB 2310B APHA APHA PhenolphthaleinIndicatorSolution Phenolphthaleinindicatorsolution, alcoholic, pH8.3 indicator PhenolphthaleinIndicatorSolution(5.0gIL) AS1M D 2187F PhenolphthaleinIndicator Solution EPA 425.1 PhenolphthaleinIndicatorSolution(5.0gIL) AS1M D 2187 G PhenolphthaleinIndicatorSolution(5 gIL) AS1M D 2187H PhenolphthaleinIndicatorSolution(5.0gIL) AS1M D4548 PhenolphthaleinIndicatorSolution(5 gIL) EPA 365.1 PhenolphthaleinIndicatorSolution(5.0gIL) AS1M D 2187 I PhenolphthaleinIndicatorSolution AS1M D 1425 PhenolphthaleinIndicationSolution(5.0gIL) AS1M D 2330 PhenolphthaleinIndicatorSolution(5.0gIL) AS1M D 2187J PhenolphthaleinIndicatorSolution(5.0gIL) AS1M D 2187K Volumetricglassware complieswith ClassAtolerance requirements ofASTM E 288and NISTCircular434; it iscalibrated beforefirst use and recalibrated regularly in accordancewith ASTM E 542and NIST Procedure NBSIR 74-461. Balances are calibrated regularlywith weightscertifiedtraceable tothe NISTnational mass standard. Thermometers and temperature probesare calibrated before first use and recalibrated regularlywith a thermometertraceable to NISTstandards. All products are prepared according to masterdocumentsthat assure manufacture according tovalidated methods. Batch records document rawmaterialtraceability and production and testing history foreach lotmanufactured.

Version: 1



### 21ShelfLife(unopened container):

5600-32 5600-1 5600-16 Recommended Storage: 15°C

- 30°C (59°F

- 86°F)

## ~:';:1L6-**(y-cUfJJ~/T'---')** c;7J<- ( LaNelleOhlhausen QualityAssurance 24 months 24 months 24 months 

### 3338eval EPAS/wet202 22

This Certificate ofAnalysis is designedto complywith ISOGuide 31 "Reference Materials••ContentsofCertificatesand Labels." Todetermine manufacturing site using lotnumber, visitwww.riccachemical.comfAboulUs/lol.pdf.

Version: 1 

## R!{(A 

# (O-r 

# lCJr!fj?'--->**2;f~** 22w w W 0:> <D < 92.. m

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1'0 W m 

### z o 

### o 

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### o

# Air Nova 5845 ClaytonAvenue Pennsauken, NJ 08109

Project 10: 

# 3338

Antimony, Arsenic, Beryllium, Cadmium,

Chromium, Cobalt, Lead, Manganese, Nickel, Selenium and Mercury

EPA Method 29 Analysis

Analytical Report 

# 14503

Element One, Inc. 5022-C Wrightsville Av., Wilmington, NC 28403 910-793-0128 FAX: 910-792-6853 e1Iab@e1Iab.com

24

### Thefollowing dataforAnalytical Report 

## 14503 has been reviewed for completeness, accuracy, adherenceto method protocol, and compliance with qualityassurance guidelines.

Review by: 

# 0c{j'v 

# L**L~L Dap~ne**  Woodman, Chemist May

## 28,2010

Report Reviewed and Finalized By:

# '/JA."L~

yt'0<Y'1"**'~** 

### Ken S"'mith, Laboratory Director May

## 28,2010

elementOne 14503Air Nova M29 Report Page 2 of27 

### 25

# SUMMARY OF RESULTS

elementOne 14503 Air Nova M29 Report Page 3 of27 

### 26

## Summary ofAnalysis
Summaryof Method 29 MercuryAnalysis 

## H

2

## 02 

## Empty AverageTotal Fronthalf IHN03 

## Impinger KMn04 HCI Run Number Catch, IJg IJg I-Ig I-Ig I-Ig I-Ig**~----------------** 

### --------------- ------------- 

## Run 1 #1 <0.5 <0.1 <0.5 <0.2 <0.5 <0.4 #2 <0.1 <0.5 <0.2 <0.5 <0.4 Run2 #1 <0.5 <0.1 <0.5 <0.2 <0.5 <0.4 #2 <0.1 <0.5 <0.2 <0.5 <0.4 Run3 #1 <0.5 <0.1 <0.5 <0.2 <0.5 <0.4 #2 <0.1 <0.5 <0.2 <0.5 <0.4 Blank #1 <0.5 <0.1 <0.5 <0.2 <0.5 <0.4 #2 <0.1 <0.5 <0.2 <0.5 <0.4

elementOne 14503Air Nova M29 Report Page 4 of27 

### 27

## Summary ofAnalysis

Front Half· Summary of Method 29 MetalsAnalysis
Run 1 Run 2 Run 2 Run 3 Blank 14503-1 FH 14503-2 FH 14503-2 FH duo 14503-3 FH 14503-4 FH 

## Element TotallJg TotallJg TotallJg TotallJg TotallJg



## -----.----------- --------------- ------------.-- 

## --------------- --------------- --.-----.------ 

## Antimony 0.254 0.404 0.412 0.509 < 

## 0.1 Arsenic 1.04 1.07 1.12 1.29 < 

## 0.1 Beryllium 0.043 0.041 0.039 0.057 < 

## 0.025 Cadmium < 

## 0.1 0.156 0.156 0.332 < 

## 0.1 Chromium 3.48 4.23 4.32 3.25 0.923 Cobalt 0.317 0.327 0.338 0.422 < 

## 0.1 Lead 1.57 1.90 1.93 9.41 0.307 Manganese 1.24 1.39 1.42 1.67 0.655 Nickel 1.94 3.11 3.20 3.77 0.514 Selenium 0.318 0.386 0.389 0.495 < 

## 0.1

Back Half· Summary of Method 29 Metals Analysis
Run 1 Run 2 Run 2 Run 3 Blank 14503-1 BH 14503-2 BH 14503-2 BH duo 14503-3 BH 14503-4 BH 

## Element TotallJg TotallJg TotallJg TotallJg Total IJg

----------------- --------------- --------------- --------------- 

## --------------- --------------- 

## Antimony < 

## 0.1 < 

## 0.1 < 

## 0.1 < 

## 0.1 < 

## 0.1 Arsenic 0.923 1.04 0.976 0.939 < 

## 0.1 Beryllium < 

## 0.025 < 

## 0.025 < 

## 0.025 < 

## 0.025 < 

## 0.025 Cadmium < 

## 0.1 < 

## 0.1 < 

## 0.1 < 

## 0.1 < 

## 0.1 Chromium 0.840 0.320 0.305 1.24 0.283 Cobalt < 

## 0.1 < 

## 0.1 < 

## 0.1 < 

## 0.1 < 

## 0.1 Lead 0.237 0.321 0.308 0.406 0.681 Manganese 19.0 0.624 0.619 1.51 0.955 Nickel 0.479 0.289 0.283 1.57 0.358 Selenium < 

## 0.1 < 

## 0.1 < 

## 0.1 < 

## 0.1 < 

## 0.1

elementOne 14503 Air Nova M29 Report**Pagi4~** 

### of27

# ANALYTICAL NARRATIVE

elementOne 14503 Air Nova M29 Report Page 6 of27 

### 29

## Element One Analytical Narrative
Client: Air Nova Element One

## #: 14503 Client 10: 

### 3338 Analyst: ESS & KMS Method: M29 Dates Received: 05/14/10 Analytes: Sb, As, Be, Cd, Cr, Co, Pb, Mn, Ni, Se & 

### DatesAnalyzed: 05/19-20/10 

## HQ
SummaryofAnalysis The Method 29 samples were digested, prepared, and analyzed according to Method 29 protocol. Samples were analyzed for mercuryon a PerkinElmer FIMS-100 CVAA mercuryanalyzer. Samples were analyzed for metals using a PerkinElmer ELAN 6100 ICP-MS.

Detection Limits The FIMS-100 CVAA instrument reporting limitfor mercurywas 0.004 IJg per aliquot analyzed. The ICP-MS instrument reporting limits were 0.25IJg/L for beryllium and 1.0IJg/Lforthe othermetals.
Analysis QAlQC Duplicate analyses relative percent difference (RPD), spike sample recovery and second source calibration verification data are summarized in the Quality Control Section. The selenium spike recoveryfor Run 3was outside ofthe ±25% laboratoryguidelines with 218%. The sample was analyzed at afive-fold dilution resulting in a spike recovery of 138% indicating matrix interference. The sample was non-detecttherefore this should have no significant impacton the results. All other 

### QNQCdata was within the criteria ofthe method.

Additional Comments
The reported results have not been corrected forany blankvalues orspike recoveryvalues. There were noticeable amounts of manganese in the back half fraction of Run 3. The archived portion ofthe back halffraction of Run 3 was analyzed and found to have equivalent results for manganese.



### elementOne 14503Air Nova M29 Report Page 7 of27 

### 30

# QUALITY CONTROL SUMMARY

elementOne 14503Air Nova M29 Report Page 8 of27 

### 31

## Summary ofQuality Control Data

Mercury Duplicate Analysis RPD (Method29 QC limits: < %1

### aforRPD) 

### Run Number Front half H2

### 0 2

### /HN03 

### Empty Imp KMn04 HCI

---------------------.--- 

## ------------- ------------- ------------- 

## ------------- ------------- Run 1 NA NA NA NA NA Run 2 NA NA NA NA NA Run 3 NA NA NA NA NA Blank NA NA NA NA NA

Run Number
Run 3 Mercury Spike Recoveries (Method29 QC limits: ±25% forSpike Recoveries) 

### Front half H202/HN04 Empty Imp KMn04 HCI



# ----- ------------- 

## ------------ ------_...

# _--- ----------- #1 101% 99% 100% 93% 94% #2 102% 102% 101% 94% 94%

elementOne 14503 Air Nova M29 Report Page 9 of27 

### 32

## SummaryofQuality Control Data

Metals Duplicate Analysis RPD (Method29 QC limits: < 20% forRPD) 

### Run 2 Run 2 Front Half Back Half 14503-2 FH 14503-2 BH 

### Element RPD RPD



## ------------------ ----------------- ----------------- 

### Antimony 1.8% NA Arsenic 4.4% 6.3% Beryllium 4.7% NA Cadmium 0.2% NA Chromium 2.2% 5.0% Cobalt 3.3% NA Lead 1.4% 4.3% Manganese 2.0% 0.9% Nickel 2.8% 2.2% Selenium 0.9% NA



### Metals Spike Recoveries (Method29 QC limits:±25% forSpike Recoveries)



### Element Antimony Arsenic Beryllium Cadmium Chromium Cobalt Lead Manganese Nickel Selenium Run 3 Front Half 14503-3 FH 

### Recovery 87% 86% 82% 90% 101% 98% 95% 104% 95% 77% *See Analytical Narrative, page 7.



## elemenlOne 14503 Air Nova M29 Report

### Pag~fO of

### 27 

### Run 3 Back Half 14503-3 BH 

### Recovery 96% 117% 88% 89% 98% 98% 100% 99% 99% *218%

## Summary ofQuality Control Data

Second Source Calibration Check Recoveries (Method29 QC limits: ±10% forSecondSource Continuing CheckStandard*) 

### Element .25 ppb 1 ppb 50 ppb 100 ppb* 250 ppb

----------------- ----------------- ----------------- 

### ----------------- ----------------- ----------------- 

### Antimony 105% 102% 100% 98% Arsenic 108% 102% 104% 100% Beryllium 105% 104% 99% 98% 97% Cadmium 109% 99% 102% 99% Chromium 84% 97% 102% 100% Cobalt 109% 100% 102% 100% Lead 112% 106% 106% 99% Manganese 110% 101% 103% 101% Nickel 107% 100% 104% 100% Selenium 99% 102% 103% 99%



### elemenlOne 14503Air Nova M29 Report 

### Page?

# 41 of27

# SAMPLE CUSTODY

elementOne 14503Air Nova M29 Report Page 12 of27 35, 

## . .- 

## . ;';':;;;;::':: Air-Nova. Inc

. 

# ...

# ..

# ...... ':., D. ':: ;

# iii' 5845 Clayton Avenue. Pennsauken, New .Jersey 08109 

# fd# 

# Ii;.!'" '1715 (856) 486-1500 • FAX 486-9896 • www.aimova.com

# ~,rjJOI!£\ pr"JeL't '3328 

# EV4-/lltt+,'{H'1

# ~t 

# xci) 

# I Chain ofCustody/Analysis Request Form

Requestor's Name:

# J~~tJl-( Shipped foranalysisto: Date ofSample Shipment:**5~/'6-JO** 

## cl e e. 

# t- Onc= NumberofPackages: 

# r 0 I l-U-

.... L'J TotaINumberofltemsShipped:'1l1 

## 1/1J

- 7-75 -01<::-0 (in all packages) 

### I

Item # Sample# Item Description (including matrix)

## J r Analysis Requested Comments



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### elementOne 14503Air Nova M29 Report 

### Pa9jJ3 of27

### Paula Smith
From: jackson@airnova.com Sent: Friday, May 14,20108:40AM To: Paula Smith Subject: AirNova Project3338 Evaluation EPA29 with Hg Page 1 of1

These Unit2samplesweretakenon5-7-2010. Itwas not includedonthe

## cae. Analyzefrontandbackseparate.
Joe

AirNova, Inc. 5845 Clayton Avenue Pennsauken,NJ 08109 856-486-1500 Phone: 856-486-1500 Fax: 856-486-9896 www.airnova.com



### 5/14/2010



### elementOne 14503Air Nova M29 Report**Pag~14** 

### of27

# ANALYTICAL DATA

elementOne 14503Air Nova M29 Report Page 15 of27 

### 38

## Analytical Calculations

MetalsElement Results (1-19) =ICP Results (1-I9/L)*Dilution*Final Volume (L)

WhereICP Results= Raw sample concentration (ppb)--ICP-Data Sheet 

### Dilution= Diluted Volume--ICP-MSRun Sheet 

### Aliquot Final Volume=FH=Final Volume (FV)--Sample Submission 

### BH=Received Volume (BV).*Final Volume (FV)--Sample Submission 

### Aliquot (Used) Combined Results=FH+BH


## MercuryMercury Results (1-19) =CVAA Results (1J9) 

## *Final Volume (ml) Aliquot (ml)

WhereCVAA Results= Rawsample reading (I-Ig)--Hg-Data Sheet 

### Aliquot= Sample Aliquot (Alq.)--Hg-Data Sheet 

### Final Volume=Final Volume (FV)*--Sample Submission



### * 

### With the exception ofthe BH fraction where- =Received Volume (BV)--Sample Submission



### elemenfOne 14503Air Nova M29 Report Page 16 of27 

### 39

## Analytical Calculations
Spike RecoverySpike (%) 

# =(Spiked Result (Mg/l)

- Sample Result (Mg/l)) X100 Spike Amount (lJg/l)
WhereSpike Result = Rawsample concentration (ppb)--ICP-Data Sheet 

### Sample Result = Raw sample concentration (ppb)--ICP-Data Sheet 

### Spike Amount--ICP-MSSpike Table



## Duplicate Analysis RPDRPD (%) 

## = (Duplicate Result (Mg/l)

- Sample Result (Jjg/l)) X100 Average (lJg/l)
WhereSample Result and Duplicate Results=Rawsample concentration (ppb)--ICP-Data Sheet Average=(Duplicate

### +Sample Results) 

### 2



### elemenlOne 14503Air Nova M29 Report

### Pag~q7 of27

### elementOne AIR TESTING SAMPLE SUBMISSION FORM Lab ID 14503 

# IFront 

### &Back Separate Analysis 

# I Analysis Due Date 05.24.10

. . ONOC/Report Due Date 05.26.10 

# IClient Air Nova 

# I I Date Rec 05.14.10 I ProJect No 3338 

### ----1 

### I Time Rec 0930 

### i Project 10 

### I Rec by LLB

Reagent**!3lafl~** HN03 Lot: 

## CR:A"5:3 Volume Marked Y / Sam Ie Identification

# ~~;~~~~:~~ 

# ---3: 4
U2:M29-R2 OlJplicate -_..- ••... i •. ' 

# 3**~~:~;~:~~5** ik:

# _~J _§..amples 1-4 Analyses Requested**r~'~** 

### I

Lab 10 Fraction 4 , C-? FH Acetone Blank

;--------- C-8A FH



### -- 0.1N HN03 C-8A A 0.1N HN03 -_. C-8B B 01 H2O 1---- C-9 BH 5% HNO,J10% H.02

, C-10 B 4% KMnO./10%H250.j i C-11 C 8N HCI DI H2O i f C-12 FH Filter



### --------- Runs/ I Fil/Ace (FH) pH<2.0 YIN Lab 10 FillD BVml 

# I**~.D** I 35**~~,,+-'--;-;o~r::-t---+:=-:;o::--~~::='~--+-+-'--=='-+--'-+** .--=._.1-.,---'---'"..,,'-""-"--'--"- M-29 Reagent Blank

Lab Communications

53 Page 1 of 1**5/14/2~:43** PM 5S by Labeled**8y~1 '\~\**  

### 0 FH Prep By/DateS

### -I Dt:P A Prep By/DateS'

- 

## 1'8-1

## 0 f!jS BH Prep By/DateS

## =1£dtl

# I2P" B Prep By/Date

### S-I~' 0

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### 'S 

### -l (0 

# ess PM Prep By/Date 10Verification By/ DateM 

### 5 -1t:Yf0



### elementOne 14503Air N,p.ya M29 Report 

### Page 

## 18 of27

### elementOne Method 29 Microwave Worksheet**'tI'/~I~S~1 1l/5()L--::....{\~**  Lab 10# 

### e**14>b-;·~,** ...

### tJ. Client:
Date Digested: Initials: 

### ---!t'>uV.!-

__ Worksheet Prepared by:

### _\)u.V!!--

_

Element One, Inc. Form 104

- ReVISion 1.0

Auto Sample Lab Sample # offilters Spike PrepVolume Weight In Units Sample 10 Weight (g) digested (ml) Micro I

Loc. Weight Out Micro
J 

## Lt<fI..**ILllJ~'** 

## L...,I**LJNO~** 

# 1 LF. R 1Ll<02 ") 

## LIZ IQS03 

# It.l /1-/,-/1,\- 

## I 

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## 5 

# -J. 

# "' It> 

# -s 1 

# -4 

# -s q -b 

# lD**Iq~2-\** 

## II 

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## --; /'3> }&/5DS-1 

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## 1-1-\..\0., \o-\-.t\

## \'O~O50 

## 1/

# r ·/at.:#=**51D1,O'1~**

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### elementOne 14503Air Npva M29 Report 

### Pag&t9 of27

## Sample/Batch Report

User Name: icp Computer Name: D8D4DWD1 Sample File: C:\elandatajcp\S,ample\x4.sam Report DatelTime: Thursday, May20,201011 :26:11

AfS Loe. Batch 10 Sample 10 Description Sample Type Init. Quant. Prep. Vol. AiiquotVoL Diluted Vol. Soiids Ratio 5 QC Std2 Sample 14 14503·1FH Sample 15 14503·2FH Sample 16 s 14503·2FH Dupiicate of3 17 14503·3FH Sample 18 d 14503·3FH Spike· 1 of5 19 14503-4FH Sample 20 LRB Sample 21 s LRB Spike -1 of8 22 14503·1BH Sample 23 14503-2BH Sample 24 d 14503·2BH Duplicateof 11 25 14503·3BH Sample 26 s 14503·3BH Spike

- 1 of 13 27 14503-4BH Sample 28 Irb g Sample 29 s Irb 9 Spike· 1 of 16 30 14502-1 9 Sample 31 14502-2 9 Sample 32 d 14502-2 9 Dupiicate of 19 33 14502·3 Ig Sample 34 s 14502-3 Ig Spike

- 1 of21 35 x2 14503-3BH Sample 36 x2s 14503·3BH Spike

- 1 of23 37 x20 14502-1 Eng Sample 38 x20 14502-2 Eng Sample 39 x20d 14502-2 Eng Dupiicate of26 40 x50 14502-3 Eng Sample 41 x50s 14502-3 Eng Spike· 1 of28 42 x5 14503-3BH Sample 43 x5s 14503·3BH Spike

- 1 of30

Page 1



### elementOne 14503Air Nova M29 Report Page 4

# 20 of 27

## Dataset Report

User Name: icp Computer Name: D8D4DWD1 Dataset File Path: C:\elandatajcp\DataSet\051910-3\ Report DatelTime: Thursday, May20, 2010 11 :25:57 Autosampler Position: 3

Time 17:39:28Wed 19-May-10 17:42:35Wed 19-May-10 17:45:44Wed 19-May-10 17:48:53Wed 19-May-10 17:52:01 Wed 19-May-10 17:55:10Wed 19-May-10 17:58:18Wed 19-May-10 18:01:26Wed 19-May-10 18:04:35Wed 19-May-10 18:07:43Wed 19-May-10 18:10:52Wed 19oMay-10 18:14:01 Wed 19-May-10 18:17:11 Wed 19-May-10 18:20:22Wed 19-May-10 18:23:32Wed 19-May-10 18:26:41 Wed 19-May-10 18:29:49Wed 19-May-10 18:32:56Wed 19oMay-10 18:36:04Wed 19-May-10 18:39:12Wed 19-May-10 18:42:20Wed 19-May-10 18:45:28Wed 19-May-10 18:48:37 Wed 19-May-10 18:51:47Wed 19-May-10 18:54:55Wed 19-May-10 18:58:03Wed 19-May-l0 19:01:12Wed 19-May-10 19:04:22Wed 19-May-10 19:07:32Wed 19-May-10 19:10:42Wed 19'May-10 19:13:50Wed 19-May-l0 19:16:58 Wed 19-May-10 19:20:06Wed 19-May-10 19:23:14Wed 19-May-10 19:26:23Wed 19-May-10 19:29:31 Wed 19-May-10 19:32:39Wed 19-May-10 19:35:47Wed 19-May-10 19:38:56Wed 19-May-10 19:42:05Wed 19-May-10 19:45:14Wed 19-May-10 19:48:22Wed 19-May-l0 08:23:38 Thu 20-May-l0 Sample ID Blank Standard 1 Standard 2 Standard 3 QCStd 1 QC Std2 QCStd3 QCStd4 QC Std 5 QC Std 6 QC Std7 QC Std 8 QC Std 9 QC Std 10 QC Std2 14503-1FH 14503-2FH 14503-2FH 14503-3FH 14503-3FH 14503-4FH LRB LRB 14503·1BH QC Sid 1 QC Std 4 14503-2BH 14503-2BH 14503-3BH 14503-3BH 14503-4BH Irb Irb 14502-1 14502-2 14502-2 QC Sid 1 QCStd4 14502-3 14502-3 QC Sid 1 QCStd 4 14503-3BH 

### The Dataset Balch ID Read Type Description Inil. Quant Prep. Vol. Aliquot. Vol. Diluted V Blank Standard #1 Standard #2 Standard#3 QCStd#1 QC Std#2 QC Std#3 QCSld#4 QCStd#5 QCStd#6 QC Std#7 QCStd#8 QC Std#9 QC Sid #10 Sample Sample Sample s Duplicate of 17 Sample d Spike - 1 of19 Sample Sample s Spike -1 of22 Sample QC Sid #1 QC Sid #4 Sample d Duplicate of27 Sample s Spike -1 of29 Sample Sample ,g Spike· 1 of32 ,g Sample Ig Sample

_ Ig d Duplicate of35 Eng QC Std#1 QCStd#4 Sample Eng Spike - 1 of39

.Eng QCStd #1 QC Std#4 x2 Sample Page 1



### elementOne 14503 Air Nova M29 

### Report

### PagEil~1 of2708:26:48 Thu 20·May-10 14503-3BH x2s Spike

- 1 of43 08:29:58 Thu 20·May-10 14502-1 x20 Sample ::09 08:33:08 Thu 20·May-10 14502-2 x20 Sample ::n9 08:36:17 Thu 20·May-10 14502-2 x20d Duplicate of46 ::n9 08:39:25 Thu 20-May-10 14502-3 x50 Sample ::n9 08:42:34 Thu 20·May-10 14502·3 x50s Spike

- 1 of48 ::n9 08:45:42 Thu 20·May-10 QCStd 1 QC Std#1 08:48:50Thu 20·May-10 QC Std 4 QC Std#4 09:00:52 Thu 2D-May-10 14503-3BH x5 Sample 09:04:00Thu 20·May·10 14503-3BH x5s Spike

- 1 of52 09:07:08Thu 2D-May-10 QCStd 1 QC Std#1 09:10:16 Thu 20·May-10 QC Std 4 QC Std#4 09:29:37 Thu 20-May-10 Blank Blank 09:31:11 Thu 20·May-10 Standard 1 Standard #1 09:32:47 Thu20·May·10 Standard 2 Standard #2 09:34:23 Thu 20·May-1 0 Standard 3 Standard #3 09:35:59 Thu 20·May-10 QCStd 1 QCStd#1 09:37:35 Thu 20-May-10 QCStd2 QC Std #2 09:39:10 Thu 20-May-10 QC Std 3 QC Std#3 09:40:45 Thu 20·May-10 QC Sid 4 QC Std #4 09:42:21 Thu 20·May-10 QCSld5 QC Std #5 09:43:57 Thu 20-May-10 QCStd 10 QC Std #10 09:45:33 Thu 20-May-10 Irb Sample ::ng 09:47:08 Thu 20-May-10 Irb s Spike

- 1 of66 ::og 09:48:44 Thu 20-May-10 14502·1 Sample Eng 09:50:19Thu 20-May-10 14502·2 Sample Eng 09:51:54 Thu 20-May-10 14502-2 d Duplicate of69 Eng 09:53:30 Thu 20-May-10 14502·3 Sample Eng 09:55:07 Thu 20·May-10 14502-3 s Spike· 1 of71 Eng 09:56:42 Thu 20-May-10 QCSld 1 QC Sid #1 09:58:17 Thu 20·May-10 QC Std 4 QC Std#4**----------~-----** Page 2



## elementOne 14503Air Nova M29 Report Pagel22 of

### 27elementOne Analyst--KMS-- ICP-MS RUN SHEET 5/20/2010 Job Number:

A!S Lac.

# IDilution Sample 10 

# I Client Type Weight (g) 

# IPrepVol (ml) 5 QC Std2 Sample 14 14503-1FH Sample 100 15 14503-2FH Sample 100 16 

### s 14503-2FH Duplicate of3 100 17 14503-3FH Sample 100 18 d 14503-3FH Spike

- 1 of5 100 19 14503-4FH Sample 100 20 LRB Sample 50 21 s LRB Spike

- 1 of8 50 22 14503-18H Sample 50x2 23 14503-28H Sample 50x2 24 d 14503-2BH Duplicate of 11 50x2 25 14503-38H Sample 50x2 26 

### s 14503-38H Spike

- 1 of 13 50x2 27 14503-4BH Sample 50x2 28 Irb Sample 100 29 s Irb Spike - 1 of 16 100 30 14502-1 Sample 100x2 31 14502-2 Sample 100x2 32 d 14502-2 Duplicate of 19 100x2 33 14502-3 Sample 100x2 34 s 14502-3 Spike

- 1 of21 100x2 35 x2 14503-3BH Sample 50x2 36 x2s 14503-38H Spike - 1 of23 50x2 37 x20 14502-1 Sample 100x2 38 x20 14502-2 Sample 100x2 39 x20d 14502-2 Duplicate of26 100x2 40 x50 14502-3 Sample 100x2 41 x50s 14502·3 Spike - 1 of28 100x2 42 x5 14503·3BH Sample 50x2 43 x5s 14503-38H Spike - 1 of30 50x2

Spikes are postat O.02mL of25ppm spikinQ solutions lot 021410-ABCD & F in a final volume of 10mL Submitted forQC by: DatelTime: QC Review By: DatelTime: KMS 5/2011011:31**l).~** 

### .) 

# I=')Wt.\tO \lo(:'f) Re-Test Required: No: 

# I Yes: Comments: 

# /
Resubmitted for QC Date/Time: QCReview: By: 

# , DatelTime: by:



### elementOne 14503Air Nova M29 Report

### Pag~23 of

### 27

### !ill 

# t?ll fU

Wetllctfvll



### --

I 1 25 1 100 'I**.~** 1 25 1 100 

# " 1 25 1 100 1 1 25 1 100 

# " 1 2s 1 100 

### ;1 1 2S 1 100 1 1 2S 1 ;100 1 1 2S 1 100 'I 1 25 ,I 100 " 1 25 1 100 1 1 25 1 100 1 1 25 1 100 1 1 25 1 100 1 1 25 1 100 1 1 25 1 100 1 

## , 25 1 100 1 1 25 1 100 1 1 25 1 100 1 1 25 1 100 1 1 25 1 100 1 1 25 1 100 1 1 25 1 100 1 1 25 1 100 1 1 25 1 100 1

Thursday, May20, 2010 11 :26 AM



### elementOne 14503Air Nova M29 Report

### Pag~~4 of27ICP Standards and QC Standards ValuesTable

ElementorTest Mass Symbol Std.#1 Std.#2 Std.#3 QC#1 QC#2 QC#3 QC#4 QC#6 QC#7 QC#8 QC#9 QC#10 QC#11 ppb ppb ppb A AB .25 LRB LRB+ LRB+**---._---~** ..**~._** 

### ..

## - Lithium 6 U Lilhium 7 Li 1 100 500 0 1 250 100 0 50 100 Beryllium 9 Be 1 100 500 0 1 250 100 0.25 0 50 100 Boron 10 B 1 50 100 0 1 250 100 0 50 100 Boron 11 B 1 50 100 0 1 250 100 0 50 100 Sodium 23 Na 20 1100 5500 0 21 2500 1100 0 718 Magnesium 24 Mg 20 1100 5500 0 21 2500 1100 0 550 Magnesium 25 Mg 20 1100 5500 0 21 2500 1100 0 550 Aluminum 27 AI 1 100 500 0 1 250 100 0 50 100 Phosphorus 31 P 20 1000 5000 0 20 2500 1000 0 200 Potassium 39 K 20 1100 5500 

### a 21 2500 1100 

### a 500 Calcium 44 Ca 50 1100 5500 0 21 2500 1100 0 550 Scandium 45 Titanium 47 Ti 1 100 SOD 0 1 250 100 0 50 100 Titanium 49 Ti 1 100 SOD 0 1 250 100 0 50 100 Vanadium 51 V 1 100 500 0 1 250 100 0 20 0 50 100 Vanadium 51 V 1 100 SOD 

### a 1 250 100 0 20 0 50 100 Chromium 52 Cr 1 100 500 0 1 250 100 10 0 50 100 Chromium 53 Cr 1 100 500 0 1 250 100 10 

### a 50 100 Iron 54 Fe 20 1100 5500 0 21 2500 1100 0 

### a Manganese 55 Mn 1 100 500 0 1 250 100 0 10 0 50 100 Iron 57 Fe 20 1100 5500 0 21 2500 1100 0 0 Cobalt 59 Co 1 100 500 0 1 250 100 0 20 0 50 100 Nickel 60 Ni 1 100 500 0 1 250 100 0 20 0 50 100 Copper 63 Cu 1 100 500 0 1 250 100 0 10 0 50 100 Copper 65 Cu 1 100 500 0 1 250 100 0 10 0 50 100 Zinc 66 Zn 1 100 500 0 1 250 100 0 10 0 50 100 Zinc 67 Zn 1 100 500 0 1 250 100 0 10 0 50 100 Zinc 68 Zn 1 100 500 0 1 250 100 0 10 0 50 100 Germanium 72 Ge 1 100 500 0 1 250 100 0 50 100 Arsenic 75 As 1 100 500 0 1 250 100 0 10 0 50 100 Selenium 77 Se 1 100 500 0 1 250 100 0 10 0 50 100 Selenium 82 Se 1 100 500 0 1 250 100 0 10 0 50 100 Strontium 88 Sr 1 100 500 0 1 250 100 0 0 50 100 Molybdenum 95 Mo 1 100 500 0 1 250 100 0 50 100 Molybdenum 97 Mo 1 100 500 0 1 250 100 0 50 100 Molybdenum 98 Mo 1 100 500 0 1 200 100 0 50 100 Rhodium 103 Silver 107 Ag 1 100 500 0 1 250 100 0 10 0 50 100 Silver 109 Ag 1 100 500 0 1 250 100 0 10 0 50 100 Cadmium 111 Cd 1 100 500 0 1 250 100 0 5 0 50 100 Cadmium 114 Cd 1 100 500 0 1 250 100 0 5 0 50 100 Tin 118 Sn 1 100 500 0 1 250 100 0 0 50 100 Antimony 121 Sb 1 100 500 0 1 250 100 0 0 50 100 Antimony 123 Sb 1 100 500 0 1 250 100 0 50 100 Tellurium 128 Te 1 100 500 0 1 250 100 0 50 100 Cesium 133 Barium 135 Ba 1 100 500 0 1 250 100 0 0 50 100 Barium 137 Ba 1 100 500 0 1 250 100 0 0 50 100 Lanthanum 139 La 1 100 500 0 1 250 100 

### a 50 100 Tantalum 159 Ta 1 100 500 0 1 250 100 0 50 100 Platinum 195 PI 1 100 500 0 1 250 100 0 50 100 Gold 181 Au 1 100 500 0 1 250 100 0 50 100 Thallium 205 TI 1 100 500 0 1 250 100 

### a 0 50 100 Lead 208 Pb 1 100 500 0 1 250 100 0 0 50 100 Bismuth 209 Bi 1 100 500 0 1 250 100 0 50 100 Thorium 232 Th 1 100 500 0 1 250 100 

### a 50 100 Uranium 238 U 1 100 500 

### a 1 250 100 0 50 100 Krypton 83

elementOne



### elementOne 14503Air N£Xa M29 Report Page 25 of27PerkinElmer ELAN 6100 ICP-MS Method 6020 &200.8 Metals Summary Report Sample 10: Blank Sample DaWednesday, May 19, 2010 17:39:28 Sample Description: Concentration Results Analyte Mass Meas. IntemCone. MearReport Unit 

### I> Li 6 77619.9 ppb 1- Be 9 14.7 ppb 1- P 31 7489.8 ppb 1 Sc 45 76237.1 ppb 

### I Cr 52 3847.8 ppb 1 Cr 53 7853.1 ppb 1 Mn 55 615 ppb 1 Co 59 56.3 ppb 1 Ni 60 147.7 ppb 1 Cu 63 257 ppb 

### I Cu 65 248.3 ppb 1 Zn 66 297 ppb 1 Zn 67 1064.7 ppb 1 Zn 68 460.3 ppb 1 As 75 92.9 ppb 

### I Se 77 410.3 ppb 

### I Se 82 -35.8 ppb 

### I> Rh 103 111053.4 ppb 1 Ag 107 209.7 ppb 1 Ag 109 199.3 ppb 

### I Cd 111 -18.2 ppb 

### 1- Cd 114 22.4 ppb 

### 1- Sb 121 45.3 ppb 1 Sb 123 33.3 ppb 1 Ba 135 40.7 ppb 

### I Ba 137 59.3 ppb 

### I> Ho 165 325362.6 ppb 1 TI 205 168.3 ppb 1- Pb 208 697.3 ppb Kr 83 90.3 mg/L Method 6020 &200.8 Metals Summary Report Sample 10: Standard 1 Sample DaWednesday, May 19, 2010 17:42:35 Sample Description: Concentration Results Analyte Mass Meas. IntemCone. MearReport Unit 

### I> Li 6 77979.4 ppb 1- Be 9 531.7 260001 ppb 1- P 31 10731.3 1300020 ppb 1 Sc 45 74910 ppb 1 Cr 52 5473.3 260001 ppb 

### I Cr 53 9201 260001 ppb 

### I Mn 55 4583.5 260001 ppb 

### I Co 59 2914.8 260001 ppb 1 Ni 60 742.7 260001 ppb 1 Cu 63 1561.5 260001 ppb 1 Cu 65 917.4 260001 ppb 1 Zn 66 793.4 260001 ppb 

### I Zn 67 1615.5 260001 ppb 1 Zn 68 928.7 260001 ppb 1 As 75 459.4 260001 ppb 1 Se 77 442 260001 ppb 

### I Se 82 7.1 260001 ppb 

### I> Rh 103 108869.4 ppb 1 Ag 107 2509.7 0.96554 ppb 1 Ag 109 2412 0.95556 ppb 1 Cd 111 708 260001 ppb 

### 1- Cd 114 1720.8 260001 ppb 

### 1- Sb 121 2471 260001 ppb 1 Sb 123 1945.2 260001 ppb 1 Ba 135 694.7 260001 ppb 

### I Ba 137 1227.7 260001 ppb 

### I> Ho 165 321744 ppb 1 TI 205 12052 260001 ppb 1- Pb 208 16783.8 260001 ppb Kr 83 60.5 mg/L

elementOne ICP-Data 1 of20 

### e 14503-Metals 

### 26.1 49PerkinElmer ELAN 6100 ICP-MS

Meas. IntemCone. MearReport Unit 6 76288.5 ppb 9 254959.3 499.96585 ppb 31 680476.3 5000.1568 ppb 45 73107.6 ppb 52 1178899.1 499.9501 ppb 53 147772.4 499.20867 ppb 55 1929646.2 499.49227 ppb 59 1375835.3 499.70943 ppb 60 281236.5 499.67676 ppb 63 648825.6 499.34656 ppb 65 313023.4 499.44831 ppb 66 232713.3 499.65573 ppb 67 39543.6 498.26724 ppb 68 164864.2 499.47534 ppb 75 210326.3 499.70285 ppb 77 18848.2 499.37559 ppb 82 24648.5 499.78962 ppb 103 104025.6 ppb 107 1034619 423.56569 ppb 109 1037055.5 429.47267 ppb 111 348618.4 499.93777 ppb 114 824786.7 499.71891 ppb 121 1197660.3 499.7514 ppb 123 927028.2 499.802 ppb 135 326434 499.78542 ppb 137 576938.8 499.85971 ppb 165 315219.7 ppb 205 5500906.4 498.40762 ppb 208 7534530.6 498.86717 ppb

83 -17644.4 mg/L Method 6020 &200.8 Metals Summary Report Sample 10: Standard 2 Sample DaWednesday, May 19, 2010 17:45:44 Sample Description: Concentration Results Analyte Mass Meas. IntemCone. MearReport Unit Li 6 80451.6 ppb Be 9 53861.4 2599.7521 ppb P 31 149303.2 25987.831 ppb Sc 45 75751.5 ppb Cr 52 252280.5 2599.8299 ppb Cr 53 38593.5 2598.7308 ppb Mn 55 418560.5 2599.7604 ppb Co 59 294583.4 2599.7555 ppb Ni 60 60391.2 2599.75 ppb Cu 63 141681.8 2599.7672 ppb Cu 65 68119.9 2599.7501 ppb Zn 66 50199.3 2599.7464 ppb Zn 67 9907.7 2598.3136 ppb Zn 68 36071.1 2599.6585 ppb As 75 45093.9 2599.7964 ppb Se 77 4428.4 2599.7519 ppb Se 82 5224.2 2599.8008 ppb Rh 103 109738.5 ppb Ag 107 257670 100.00097 ppb Ag 109 254864.1 100.00123 ppb Cd 111 73751.5 2599.7522 ppb Cd 114 176537.4 2599.7576 ppb Sb 121 254141 2599.7554 ppb Sb 123 196335.2 2599.7504 ppb Ba 135 69192.6 2599.7567 ppb Ba 137 121769.4 2599.7534 ppb Ho 165 330087.8 ppb TI 205 1248747.2 2599.756 ppb Pb 208 1671919.3 2599.7528 ppb Kr 83 -3908.1 mg/L Method 6020 &200.8 Metals Summary Report Sample 10: Standard 3 Sample DaWednesday, May 19, 2010 17:48:53 Sample Description: Concentration Results Analyte Mass Li Be P Sc Cr Cr Mn Co Ni Cu Cu Zn Zn Zn As Se Se Rh Ag Ag Cd Cd Sb Sb Ba Ba Ho TI Pb Kr 

### I>I

### I- I I 1 

### I
1 

### I 

### I 1 

### I 

### I I I
1 

### I I> I I I

### II- 

### I I 

### I I> I 1- 

### I>II- I I I 

### I 

### I I 1 

### I I I I 

### I I I 

### I> I 1 

### I

### II- I 

### I 

### I I> I 

### 1-

ICP-Data 2of20 elementOne 

### e 14503-Metals 

### 26.2
50PerkinElmer ELAN 6100 ICP-MS Method 6020 &200.8 Metals Summary Report Sample 10: QC Std 1 Sample DaWednesday, May 19, 2010 17:52:01 Sample Description: Concentration Results Analyte Mass Meas. Intem Cone. MearReport Unit 

### I> Li 6 78414 ppb 1- Be 9 160.7 0.28108 ppb 

### 1- P 31 8013.2 5.91055 ppb 1 Sc 45 74566.1 ppb 1 Cr 52 4622.5 0.3817 ppb 

### I Cr 53 9642.1 7.217 ppb 

### I Mn 55 1962.5 0.34451 ppb 1 Co 59 991.4 0.33106 ppb 1 Ni 60 316.3 0.30176 ppb 

### I Cu 63 742.7 0.37081 ppb 

### I Cu 65 525 0.44369 ppb 1 Zn 66 463.3 0.37109 ppb 1 Zn 67 1809.2 9.90085 ppb 1 Zn 68 762 0.94396 ppb 

### I As 75 243 0.35325 ppb 

### I Se 77 427.3 0.85209 ppb 1 Se 82 -46.1 -0.22996 ppb 

### I> Rh 103 106931.4 ppb 

### I Ag 107 29080.3 11.47182 ppb 

### I Ag 109 28258.6 11.27151 ppb 1 Cd 111 163.8 0.25225 ppb 

### 1- Cd 114 504 0.28457 ppb 1- Sb 121 749.4 0.29103 ppb 

### I Sb 123 530.9 0.26583 ppb 1 Ba 135 224 0.27959 ppb 1 Ba 137 398.3 0.29265 ppb 

### I> Ho 165 320550.8 ppb 

### I TI 205 5151.2 0.4479 ppb 

### 1- Pb 208 5994.5 0.34857 ppb Kr 83 115.5 mg/L Method 6020 & 200.8 Metals Summary Report Sample 10: QC Std 2 Sample DaWednesday, May 19, 2010 17:55:10 Sample Description: Concentration Results Analyte Mass Meas. IntemCone. MearReport Unit 

### I> Li 6 78085 ppb 

### 1- Be 9 560 1.04354 ppb 

### 1- P 31 10824.4 26.86444 ppb 

### I Sc 45 73182.4 ppb 1 Cr 52 5681.1 0.84049 ppb 1 Cr 53 9933.4 8.51432 ppb 

### I Mn 55 4906 1.09765 ppb 

### I Co 59 3115.2 1.09176 ppb 1 Ni 60 752.7 1.0709 ppb 1 Cu 63 1741.2 1.13235 ppb 

### I Cu 65 1024.7 1.2351 ppb 

### I Zn 66 952.4 1.41227 ppb 1 Zn 67 1947.5 11.81949 ppb 1 Zn 68 1063.4 1.86361 ppb 

### I As 75 665.6 1.34362 ppb 

### I Se 77 427.7 0.95077 ppb 1 Se 82 15.5 0.99359 ppb 

### I> Rh 103 105973.1 ppb 

### I Ag 107 9238.4 3.64268 ppb 

### I Ag 109 9015.5 3.59735 ppb 1 Cd 111 753.4 1.08714 ppb 

### 1- Cd 114 1799.9 1.05836 ppb 

### 1- Sb 121 2522.7 1.03068 ppb 1 Sb 123 1994.7 1.05363 ppb 1 Ba 135 751 1.08592 ppb 

### I Ba 137 1272.8 1.04943 ppb 

### I> Ho 165 316239.9 ppb 1 TI 205 13044.4 1.16226 ppb 

### 1- Pb 208 17592.7 1.11673 ppb Kr 83 55.2 mg/L

elementOne ICP-Data 3of20 

### e 14503-Metals 

### 26.3


### 51PerkinElmer ELAN 6100 ICP-MS

Meas. IntemCone. MearReport Unit 6 80956.1 ppb 9 53053.9 98.17611 ppb 31 150052 1022.8359 ppb 45 76644.3 ppb 52 251099.9 101.55228 ppb 53 38691.3 106.56547 ppb 55 411792.2 102.71141 ppb 59 291270.9 102.06691 ppb 60 60439.9 103.46517 ppb 63 141155 104.71331 ppb 65 66649.5 102.31224 ppb 66 49460.6 102.00793 ppb 67 9958.1 111.29188 ppb 68 36184.6 104.77557 ppb 75 45412.9 103.94999 ppb 77 4231 99.98535 ppb 82 5228.3 102.87508 ppb 103 107796.6 ppb 107 263544.7 104.02647 ppb 109 258279.7 103.15859 ppb 111 73343.8 101.5653 ppb 114 176072.9 102.92564 ppb 121 254605.2 101.62419 ppb 123 194347.5 100.24615 ppb 135 68693.1 100.64253 ppb 137 122211.8 101.2842 ppb 165 329392.6 ppb 205 1243173.9 107.82095 ppb 208 1668005.9 105.69371 ppb

83 -3902.3 mglL Method 6020 &200.8 Metals Summary Report Sample ID: QC Std 3 Sample DaWednesday, May 19. 2010 17:58:18 Sample Description: Concentration Results Analyte Mass Meas. Intem Cone. Mear Report Unit Li 6 80876.5 ppb Be 9 130885.3 242.39193 ppb P 31 691723.6 4912.6299 ppb Sc 45 75001.9 ppb Cr 52 612148.9 250.41452 ppb Cr 53 80332.9 250.06205 ppb Mn 55 1006819.2 251.74091 ppb Co 59 711935.5 250.04861 ppb Ni 60 145046.5 249.13604 ppb Cu 63 341097.3 253.88409 ppb Cu 65 164466.9 253.63143 ppb Zn 66 120489.5 249.81615 ppb Zn 67 21697.9 258.40175 ppb Zn 68 86740.5 253.58855 ppb As 75 108825.4 250.09457 ppb Se 77 9849.3 247.1805ppb Se 82 12598.8 247.47428 ppb Rh 103 107596.3 ppb Ag 107 588474.7 232.88058 ppb Ag 109 573072.3 229.53648 ppb Cd 111 177991.7 246.83851 ppb Cd 114 432627.8 253.3983 ppb Sb 121 612393.7 244.77894 ppb Sb 123 475340.2 245.47545 ppb Ba 135 168656.9 247.59609 ppb Ba 137 294865.5 244.85821 ppb Ho 165 329126.8 ppb TI 205 2860003.2 248.3207 ppb Pb 208 3914595.8 248.54112 ppb Kr 83 -9674.5 mglL Method 6020 &200.8 Metals Summary Report Sample 10: QC Std 4 Sample Da Wednesday. May 19. 2010 18:01:26 Sample Description: Concentration Results Analyte Mass Li Be P Sc Cr Cr Mn Co Ni Cu Cu Zn Zn Zn As Se Se Rh Ag Ag Cd Cd Sb Sb Ba Ba Ho TI Pb Kr 

### I>

### II- I 1 

### I I I 

### I I 

### I 1 

### I I 1 

### I
1 

### I> I 1 

### III- I I
1 

### I> I 

### 1-

I>II- I 1 

### I I I I I 

### I
1 

### I
1 

### I
1 

### I 

### I>
1 

### I
1

### I

### I- I 

### I I 

### I> I 

### 1-

ICP-Data 4of20 elementOne 

### e 14503-Metals 

### 26.4


### 52PerkinElmer ELAN 6100 ICP-MS

Meas. Intem Cone. MearReport Unit 6 86586.3 ppb 9 46.7 0.05285 ppb 31 6277006.3 48591.591 ppb 45 75599.7 ppb 52 5385.3 0.86461 ppb 53 10330.5 12.19956 ppb 55 12262 3.1611 ppb 59 3334.3 1.24491 ppb 60 1741.2 2.9914 ppb 63 2628.4 1.93069 ppb 65 3887.5 6.10549 ppb 66 3590 7.44933 ppb 67 2635.7 22.71216 ppb 68 2057.9 5.22174 ppb 75 63.3 -0.03424 ppb 77 709 9.61499 ppb 82 -59.7 -0.59183 ppb 103 99698.3 ppb 107 2383.7 0.93821 ppb 109 2349.3 0.93772 ppb 111 273.3 0.42536 ppb 114 2366.6 1.48319 ppb 121 334.7 0.11403 ppb 123 278.3 0.12493 ppb 135 305.3 0.38224 ppb 137 516.7 0.3746 ppb 165 333017 ppb 205 921 0.06447 ppb 208 9403.9 0.54533 ppb

83 59.5 mg/L Method 6020 &200.8 Metals Summary Report Sample 10: QC Std 5 Sample Da Wednesday, May 19, 2010 18:04:35 Sample Description: Concentration Results Analyte Mass Meas. Intem Cone. MearReport Unit Li 6 78767.4 ppb Be 9 25907.9 49.26169 ppb P 31 36412.2 213.03735 ppb Sc 45 74306.6 ppb Cr 52 120367 48.67046 ppb Cr 53 23580.6 56.08091 ppb Mn 55 198775.7 50.30891 ppb Co 59 140284.8 49.95658 ppb Ni 60 28756.5 49.91557 ppb Cu 63 66985.2 50.39464 ppb Cu 65 32331.5 50.25524 ppb Zn 66 24087.9 50.18378 ppb Zn 67 5820.9 60.94246 ppb Zn 68 17187.2 49.89944 ppb As 75 21921.6 50.88629 ppb Se 77 2248.3 49.20817 ppb Se 82 2524.2 50.787 ppb Rh 103 106091.8 ppb Ag 107 129930.2 52.10344 ppb Ag 109 126558.1 51.30365 ppb Cd 111 35120.4 49.425 ppb Cd 114 84971.5 50.48261 ppb Sb 121 121366 50.42758 ppb Sb 123 94663.3 50.80241 ppb Ba 135 32867.4 50.09577 ppb Ba 137 57916.2 49.95689 ppb Ho 165 316456.9 ppb TI 205 582757.8 52.57646 ppb Pb 208 805007.6 53.076 ppb Kr 83 92.9 mg/L Method 6020 &200.8 Metals Summary Report Sample 10: QC Std 6 Sample DaWednesday, May 19, 201018:07:43 Sample Description: Concentration Results Analyte Mass Li Be P Sc Cr Cr Mn Co Ni Cu Cu Zn Zn Zn As Se Se Rh Ag Ag Cd Cd Sb Sb Ba Ba Ho TI Pb Kr 

### I>II- I I I I I 

### I I 1 

### I I I 1 

### I I 

### I> I I I

### II- I 

### I I I> 1 

### 1-



### I>II- I I 

### I I I I I I 1 

### I I I 

### I I I> I I I

### II- I 

### I I I> I 

### 1-

ICP-Data 5 of20 elementOne
e 14503-Metals 

### 26.5
53PerkinElmer ELAN 6100 ICP-MS

98250.1 ppb 189.7 0.26119 ppb 11700.9 29.44726 ppb 78000.8 ppb

3745.1 -0.04213 ppb 9686.2 6.04345 ppb 2008.9 0.33766 ppb

874.7 0.27844 ppb 414.3 0.44398 ppb

872 0.44311 ppb 564.4 0.47251 ppb 1567.8 2.55849 ppb 2073.6 12.15091 ppb 1446.8 2.7957 ppb

162.8 0.16152 ppb 406.3 -0.10589 ppb 20 1.05773 ppb 111238 ppb 1560.5 0.51876 ppb 1657.2 0.56608 ppb 195.6 0.28752 ppb 521.7 0.28312 ppb 733.7 0.25723 ppb 583.5 0.26632 ppb 231.7 0.25999 ppb

386 0.25128 ppb 349923 ppb 3573.7 0.27691 ppb 6121.8 0.32051 ppb

29.4 mg/L Meas. IntemCone. MearReport Unit 6 9 31 45 52 53 55 59 60 63 65 66 67 68 75 77 82 103 107 109 111 114 121 123 135 137 165 205 208

83 Method 6020 &200.8 Metals Summary Report Sample ID: QC Std 7 Sample DaWednesday, May 19, 2010 18:10:52 Sample Description: Concentration Results Analyte Mass Meas. IntemCone. MearReport Unit Li 6 85721 ppb Be 9 40.7 0.04298 ppb P 31 5869740.3 48998.313 ppb Sc 45 70021.9 ppb Cr 52 26757.7 11.2824 ppb Cr 53 12192.2 22.63672 ppb Mn 55 47222.4 13.60267 ppb Co 59 52326.2 21.36656 ppb Ni 60 11156.9 22.08546 ppb Cu 63 12976.3 11.05525 ppb Cu 65 8474.3 14.84797 ppb Zn 66 6439.9 14.98073 ppb Zn 67 3057.8 31.64546 ppb Zn 68 4095.3 12.69162 ppb As 75 4095.6 10.74938 ppb Se 77 1013.7 20.42977 ppb Se 82 426.6 10.39879 ppb Rh 103 92469.8 ppb Ag 107 21818.5 9.97488 ppb Ag 109 21482.4 9.93155 ppb Cd 111 3325.1 5.38282 ppb Cd 114 9551.7 6.49988 ppb Sb 121 203 0.06696 ppb Sb 123 154.9 0.06665 ppb Ba 135 469 0.66342 ppb Ba 137 803.7 0.65078 ppb Ho 165 312987 ppb TI 205 644.4 0.04398 ppb Pb 208 3648 0.19862 ppb**~7 ~~**  Method 6020 &200.8 Metals Summary Report Sample ID: QC Std 8 Sample DaWednesday, May 19, 201018:14:01 Sample Description: Concentration Results Analyte Mass Li Be P Sc Cr Cr Mn Co Ni Cu Cu Zn Zn Zn As Se Se Rh Ag Ag Cd Cd Sb Sb Ba Ba Ho TI Pb Kr 

### I>II- I I 

### I I I I 

### I I I I I 

### I I I 

### I> I I I

### II- I I 

### I I> I

### II>II- I 

### I I I I 

### I I 

### I I 

### I I I I 

### I I> I 

### I
1

### II- I I 

### I I> I 1-

ICP-Data 6of20 elementOne 

## e 14503-Metals 

### 26.6
54PerkinElmer ELAN 6100 ICP-MS Method 6020 &200.8 Metals Summary Report Sample ID: QC Std 9 Sample DaWednesday, May 19, 2010 18:17:11 Sample Description: Concentration Results Analyte Mass Meas. IntemCone. MearReport Unit 

### I> Li 6 81047.2 ppb 

### 1- Be 9 16.7 0.00271 ppb 

### 1- P 31 15017.7 66.85655 ppb 1 Sc 45 68145.2 ppb 

### I Cr 52 3667.4 0.13415 ppb 

### I Cr 53 2280.3 -17.50397 ppb 

### I Mn 55 8991.4 2.33476 ppb 

### I Co 59 241 0.07415 ppb 

### I Ni 60 816.4 1.3045 ppb 

### I Cu 63 1310.8 0.89238 ppb 

### I Cu 65 777.7 0.95505 ppb 1 Zn 66 4317 9.30333 ppb 1 Zn 67 1387.4 6.24617 ppb 

### I Zn 68 3202.2 9.07309 ppb 

### I As 75 87 0.01362 ppb 

### I Se 77 33.7 -9.42619 ppb 1 Se 82 7.7 0.84467 ppb 

### I> Rh 103 97439.1 ppb 

### I Ag 107 1044.1 0.37666 ppb 

### I Ag 109 981.4 0.35703 ppb 

### I Cd 111 34.8 0.07793 ppb 

### 1- Cd 114 59.8 0.02554 ppb 

### 1- Sb 121 329.3 0.11989 ppb 

### I Sb 123 263 0.12464 ppb 

### I Ba 135 210 0.26367 ppb 

### I Ba 137 380.3 0.28184 ppb 

### I> Ho 165 313330.1 ppb 1 TI 205 609.7 0.04093 ppb 

### 1- Pb 208 14720.3 0.93692 ppb Kr 83 29 mg/L Method 6020 & 200.8 Metals Summary Report Sample 10: QC Std 10 Sample DaWednesday, May 19, 2010 18:20:22 Sample Description: Concentration Results Analyte Mass Meas. Intem Cone. MearReport Unit 

### I> Li 6 81918.7 ppb 

### 1- Be 9 23096.3 42.1817 ppb 

### 1- P 31 11233.9 37.18669 ppb 1 Sc 45 68079.9 ppb 

### I Cr 52 105462.9 46.52554 ppb 

### I Cr 53 13539.8 25.34589 ppb 1 Mn 55 178224.7 49.19369 ppb 1 Co 59 122774.3 47.6789 ppb 

### I Ni 60 26372.6 49.9552 ppb 

### I Cu 63 57691.7 47.3898 ppb 

### I Cu 65 27675.4 46.94808 ppb 1 Zn 66 24445.5 55.62733 ppb 

### I Zn 67 4455.1 48.73497 ppb 

### I Zn 68 17493.5 55.57279 ppb 

### I As 75 17022.3 43.13246 ppb 1 Se 77 1403.1 30.24689 ppb 

### I Se 82 1843.2 40.61013 ppb 

### I> Rh 103 97256.2 ppb 

### I Ag 107 3790.8 1.58463 ppb 

### I Ag 109 3626.1 1.53547 ppb 

### I Cd 111 28891.9 44.35022 ppb 

### 1- Cd 114 69822.2 45.23462 ppb 1- Sb 121 95469.3 40.83553 ppb 

### I Sb 123 74078.7 40.94289 ppb 

### I Ba 135 28451.5 44.68234 ppb 1 Ba 137 49962.5 44.37706 ppb 

### I> Ho 165 307501 ppb 

### I TI 205 526869.9 48.95588 ppb 1- Pb 208 738149.8 50.13942 ppb Kr 83 36.6 mg/L

elementOne ICP-Data 7of20 

### e 14503-Metals 

### 26.7
55PerkinElmer ELAN 6100 ICP-MS

84466.2 ppb 258.3 0.43182 ppb 489159.1 ppb

72363.9 34.76051 ppb 10090.6 16.14218 ppb 41202.3 12.4177 ppb

7460.4 3.17155 ppb 9359.8 19.36213 ppb 3769.1 10.35671 ppb

219 -3.42923 ppb 104.9 3.18325 ppb 88234.6 ppb

426.3 0.73775 ppb 477.4 0.32565 ppb 5876.9 2.50548 ppb 4608.5 2.54074 ppb 306340.4 ppb 231324.1 15.73806 ppb -1039 mg/L Meas. IntemCone. MearReport Unit 6 9 45 52 53 55 59 60 75 77 82 103 111 114 121 123 165 208

83 Method 6020 &200.8 Metals Summary Report Sample 10: QC Std 2 Sample OaWednesday. May 19. 2010 18:23:32 Sample De Air Nova Concentration Results Analyte Mass Meas. IntemCone. MearReport Unit Li 6 83414.7 ppb Be 9 536.3 0.93363 ppb P 31 10029.2 31.88704 ppb Sc 45 67750.6 ppb Cr 52 4934.3 0.83727 ppb Cr 53 8572.4 8.24378 ppb Mn 55 4368.1 1.12434 ppb Co 59 2735.7 1.10209 ppb Ni 60 657 1.0707 ppb Cu 63 1538.8 1.14974 ppb Cu 65 880.7 1.21326 ppb Zn 66 806 1.35451 ppb Zn 67 1429.8 8.00433 ppb Zn 68 793.7 1.41784 ppb As 75 478.5 1.07605 ppb Se 77 405.3 1.94226 ppb Se 82 48.5 1.79227 ppb Rh 103 92332.9 ppb Ag 107 2674.1 1.15386 ppb Ag 109 2443.7 1.06208 ppb Cd 111 680.5 1.12282 ppb Cd 114 1615.5 1.09066 ppb Sb 121 2673.7 1.19441 ppb Sb 123 2102.3 1.21406 ppb Ba 135 624.4 0.97846 ppb Ba 137 1134.7 1.01789 ppb Ho 165 290214.7 ppb TI 205 12199.2 1.18605 ppb Pb 208 16385.4 1.13455 ppb Kr 83 18.5 mg/L Method 6020 &200.8 Metals Summary Report Sample 10: 14503-1FH Sample OaWednesday, May 19, 201018:26:41 Sample De Air Nova Concentration Results Analyte Mass Li Be Sc Cr Cr Mn Co Ni As Se Se Rh Cd Cd Sb Sb Ho Pb Kr 

### I>I

### I- I 

### I I I I 

### I I I I 

### I I I I 

### I I> I 

### I I

### II- I 

### I 1 

### I> I 1-



### I> 

### I- I I 1 

### I 

### I I 1 

### I 

### I I> 1

### I

### I- I I> 1-

ICP-Oata 8of20 elementOne
e 14503-Metals 

### 26.8
56PerkinElmer ELAN 6100 ICP-MS

85802.6 ppb 239.7 0.38998 ppb 295660.7 ppb

89653.7 43.2182 ppb 11290.7 20.956 ppb 47279.4 14.20764 ppb

7983.8 3.38314 ppb 15456.1 32.0111 ppb 4084.3 11.19325 ppb

195.3 -4.19591 ppb 135.3 3.8892 ppb 88683.7 ppb 913 1.56027 ppb 1516.5 1.0627 ppb 9770.9 4.1172 ppb 7564.8 4.11709 ppb 310845.6 ppb 287738.9 19.30081 ppb

-1025.7 mg/L Meas. IntemConc. MearReport Unit 6 9 45 52 53 55 59 60 75 77 82 103 111 114 121 123 165 208

83 Method 6020 &200.8 Metals Summary Report Sample 10: 14503-2FH Sample DaWednesday, May 19, 2010 18:29:49 Sample De AirNova Concentration Results Analyte Mass Meas. Intem Conc. MearReport Unit Li 6 88759.8 ppb Be 9 259 0.40862 ppb Sc 45 301337.5 ppb Cr 52 89538.9 42.26941 ppb Cr 53 11586.7 21.21705 ppb Mn 55 47319 13.92924 ppb Co 59 7883.8 3.27373 ppb Ni 60 15358.6 31.1378 ppb As 75 3993.4 10.7129 ppb Se 77 185.7 -4.6076 ppb Se 82 136.8 3.85604 ppb Rh 103 90498.1 ppb Cd 111 930.8 1.55779 ppb Cd 114 1489.7 1.02363 ppb Sb 121 9830 4.05689 ppb Sb 123 7581.2 4.04253 ppb Ho 165 317252.1 ppb Pb 208 289874.2 19.03191 ppb Kr 83 -1042.7 mg/L Method 6020 &200.8 Metals Summary Report Sample 10: 14503-2FH Sample Da Wednesday, May 19, 2010 18:32:56 Sample DeAir Nova Concentration Results Analyte Mass Li Be Sc Cr Cr Mn Co Ni As Se Se Rh Cd Cd Sb Sb Ho Pb Kr 

### I> I- I I I 

### I I 1 

### I 

### I I I> I

### II- I 

### I> 1-



### I> I- I I I 

### I I I 

### I I I 

### I> I

### II- I I> 

### 1-

ICP-Data 9of20 elementOne 

### e 14503-Metals 

### 26.9

57PerkinElmer ELAN 6100 ICP-MS

Meas. IntemCone. MearReport Unit 6 84052.4 ppb 9 23300.9 41.43401 ppb 45 544814.4 ppb 52 183175.2 82.89479 ppb 53 22140 58.98249 ppb 55 245652.3 68.54901 ppb 59 135446.2 53.2297 ppb 60 44401.5 85.29411 ppb 75 21850.5 56.04514 ppb 77 1597.1 36.30426 ppb 82 1952.9 43.47821 ppb 103 96323.4 ppb 111 31133 48.26354 ppb 114 74131.4 48.55446 ppb 121 125054.9 48.54446 ppb 123 97220.6 48.69662 ppb 165 338706 ppb 208 2298522.1 141.57966 ppb

83 -1558.7 mg/L Method 6020 &200.8 Metals Summary Report Sample ID: 14503-3FH Sample DaWednesday, May 19, 2010 18:36:04 Sample De Air Nova Concentration Results Analyte Mass Meas. IntemCone. MearReport Unit Li 6 82636.6 ppb Be 9 329 0.56679 ppb Sc 45 549235.9 ppb Cr 52 65571.7 32.45267 ppb Cr 53 8518.3 10.72999 ppb Mn 55 53575.4 16.73271 ppb Co 59 9596.7 4.22432 ppb Ni 60 17528.6 37.72623 ppb As 75 4522.7 12.90244 ppb Se 77 221.3 -3.11754 ppb Se 82 173.6 4.95002 ppb Rh 103 85448.6 ppb Cd 111 1885.5 3.31798 ppb Cd 114 3700 2.71388 ppb Sb 121 11967.2 5.11356 ppb Sb 123 9216.2 5.08621 ppb Ho 165 306682.3 ppb Pb 208 1383708.7 94.09952 ppb Kr 83 -1385.3 mg/L Method 6020 &200.8 Metals Summary Report Sample ID: 14503-3FH Sample DaWednesday, May 19, 201018:39:12 Sample DeAir Nova Concentration Results Analyte Mass Li Be Sc Cr Cr Mn Co Ni As Se Se Rh Cd Cd Sb Sb Ho Pb Kr 

### I>

### II 

### I I I 

### I I I 

### I I I> IIII 

### I> 

### 1-

I>II I I 

### I I I I 

### I I 

### I> IIII I> 1-

ICP-Data 10of20 elementOne
e 14503-Metals 

### 26.10
58PerkinElmer ELAN 6100 rCP-MS

86933.6 ppb 15.3 -0.00198 ppb 86735.8 ppb 5489.3 0.53935 ppb 1206.4 -22.34705 ppb 9456,9 2.02223 ppb

153.7 0.0304 ppb 907.4 1.1862 ppb

126 0,0596 ppb 27.7 -9,73234 ppb -16.5 0.37496 ppb 117348.7 ppb 43.3 0.08002 ppb 106.1 0,04455 ppb 41782.3 14,87045 ppb

32308 14.85682 ppb 369103,8 ppb

19478.8 1.05775 ppb 56.6 mg/L Meas. IntemConc, MearReport Unit 6 9 45 52 53 55 59 60 75 77 82 103 111 114 121 123 165 208

83 Method 6020 &200.8 Metals Summary Report Sample ID: 14503-4FH Sample DaWednesday, May 19, 2010 18:42:20 Sample DeAir Nova Concentration Results Analyte Mass Meas. IntemConc, MearReport Unit Li 6 85392,2 ppb Be 9 36 0.03511 ppb Sc 45 283991.7 ppb Cr 52 26069 9.23322 ppb Cr 53 3703,1 -13.37062 ppb Mn 55 26701,2 6.55406 ppb Co 59 434.7 0.13378 ppb Ni 60 3120.9 5.13731 ppb As 75 177.1 0,20055 ppb Se 77 25.7 -9,72088 ppb Se 82 -59,1 -0.49244 ppb Rh 103 107217.7 ppb Cd 111 281.4 0.41498 ppb Cd 114 195.7 0.10128 ppb Sb 121 1494.5 0.54048 ppb Sb 123 1166 0.54654 ppb Ho 165 351903.8 ppb Pb 208 52531.4 3.07363 ppb Kr 83 -5.5 mg/L Method 6020 &200.8 Metals Summary Report Sample ID: LRB Sample DaWednesday, May 19, 2010 18:45:28 Sample DeAir Nova Concentration Results Analyte Mass Li Be Sc Cr Cr Mn Co Ni As Se Se Rh Cd Cd Sb Sb Ho Pb Kr 

### I> I- I 

### I I I I 

### I I I I 

### I> I

### II- I 

### I> 1-



### I> I- I I I I I I 

### I 

### I I 

### I> I

### II- I 

### I> 1-

rCP-Data 11 of20 

### elementOne 

### e 14503-Metals 

### 26.11
59PerkinElmer ELAN 6100 ICP-MS

94555.2 ppb 27.3 0.01488 ppb 88076 ppb 25565.6 8.39971 ppb

4111.3 -12.8148 ppb 806319 190.13537 ppb

879.4 0.27222 ppb 3105.2 4.79345 ppb 4340.2 9.22813 ppb

157.7 -6.51227 ppb -92.1 -0.99804 ppb 114082.2 ppb 165.7 0.24146 ppb 257.4 0.12855 ppb 1311.1 0.45586 ppb 1037.6 0.46724 ppb 363611.5 ppb 42149.3 2.37337 ppb

1044.5 mg/L Meas. IntemCone. MearReport Unit 6 9 45 52 53 55 59 60 75 77 82 103 111 114 121 123 165 208

83 Method 6020 &200.8 Metals Summary Report Sample ID: LRB Sample DaWednesday, May 19, 2010 18:48:37 Sample DeAir Nova Concentration Results Analyte Mass Meas. IntemCone. MearReport Unit Li 6 85984.6 ppb Be 9 24628.7 42.84753 ppb Sc 45 86035.9 ppb Cr 52 132190.7 46.41794 ppb Cr 53 16210.8 23.02156 ppb Mn 55 225176.5 49.55714 ppb Co 59 152131.4 47.08154 ppb Ni 60 31020 46.75278 ppb As 75 21244.8 42.86126 ppb Se 77 1686.8 28.5269 ppb Se 82 2180.2 38.3135 ppb Rh 103 121926.6 ppb Cd 111 35005.7 42.85892 ppb Cd 114 84989.9 43.89314 ppb Sb 121 117599 41.36337ppb Sb 123 91284.6 41.49537 ppb Ho 165 373789.6 ppb Pb 208 890105.6 49.69573 ppb Kr 83 83.2 mg/L Method 6020 &200.8 Metals Summary Report Sample ID: 14503-1BH Sample DaWednesday, May 19, 2010 18:51:47 Sample De Air Nova Concentration Results Analyte Mass Li Be Sc Cr Cr Mn Co Ni As Se Se Rh Cd Cd Sb Sb Ho Pb Kr 

### I> I· I I 

### I I I 

### I I 

### I 

### I I> I

### I### II 

### I> 1-



### I>II 

### I I I I I I 

### I I 

### I> III

### I I> 1-

ICP-Data 12of20 elementOne
e 14503-Metals 

### 26.12


### 60PerkinElmer ELAN 6100 ICP-MS Method 6020 &200.8 Metals Summary Report Sample ID: QC Std 1 Sample DaWednesday, May 19, 2010 18:54:55 Sample Description: Concentration Results Analyte Mass Meas. Intem Cone. MearReport Unit 

### I> Li 6 94736.4 ppb I_ Se 9 19.7 0.00297 ppb 1_ P 31 7807.4 0.38225 ppb 1 Sc 45 86811.5 ppb 1 Cr 52 4176.3 0.07344 ppb 1 Cr 53 8684.8 1.73511 ppb 1 Mn 55 1504.1 0.2033 ppb 1 Co 59 123.7 0.02144 ppb 1 Ni 60 145.3 -0.01197 ppb 1 Cu 63 290 0.01626 ppb 1 Cu 65 956.7 1.01109 ppb 1 Zn 66 604.4 0.57722 ppb 1 Zn 67 1581.8 5.60997 ppb 1 Zn 68 517 0.10952 ppb 1 As 75 82.9 -0.02735 ppb 1 Se 77 331 -2.30881 ppb 1 Se 82 -8.6 0.52309 ppb 

### I> Rh 103 115135.8 ppb 1 Ag 107 676.7 0.17063 ppb 1 Ag 109 680.7 0.17759 ppb 1 Cd 111 6.8 0.03356 ppb 1_ Cd 114 41.5 0.00985 ppb 1_ Sb 121 262.7 0.07755 ppb 1 Sb 123 233.6 0.0926 ppb 1 Sa 135 62 0.0236 ppb 1 Sa 137 91.3 0.01996 ppb 

### I> Ho 165 357951.2 ppb 1 TI 205 521 0.0268 ppb 1_ Pb 208 1098 0.0193 ppb Kr 83 64.8 mg/L Method 6020 &200.8 Metals Summary Report Sample ID: QC Std 4 Sample DaWednesday, May 19, 2010 18:58:03 Sample Description: Concentration Results Analyte Mass Meas. IntemCone. MearReport Unit 

### I> Li 6 91470.3 ppb 1_ Se 9 59260.7 96.90582 ppb 1_ P 31 163228.2 1042.9403 ppb 1 Sc 45 85633.2 ppb 

### I Cr 52 267731.8 101.35181 ppb 

### I Cr 53 40052.5 102.49351 ppb 1 Mn 55 445905.2 104.1485 ppb 

### I Co 59 307385.7 100.87803 ppb 

### I Ni 60 62863.1 100.72798 ppb 1 Cu 63 148006.1 102.75534 ppb 

### I Cu 65 71664 103.02391 ppb 1 Zn 66 53548.4 103.43239 ppb 1 Zn 67 10453 109.24255 ppb 1 Zn 68 38402.4 104.0879 ppb 

### I As 75 48207.4 103.297 ppb 1 Se 77 4550.8 100.86467 ppb 1 Se 82 5619.6 103.56634 ppb 

### I> Rh 103 115129.1 ppb 1 Ag 107 268242.8 99.19686 ppb 1 Ag 109 263201.6 98.40312 ppb 1 Cd 111 78285.1 101.51597 ppb 1_ Cd 114 188991.2 103.4825 ppb 1_ Sb 121 269782.8 99.92111 ppb 1 Sb 123 209243.3 100.08439 ppb 1 Sa 135 74363.7 101.10726 ppb 1 Sa 137 129913.8 99.93294 ppb 

### I> Ho 165 355125.6 ppb 

### I TI 205 1314927.3 105.71979 ppb 1_ Pb 208 1764150 103.71935 ppb Kr 83 -4124.3 mg/L Method 6020 & 200.8 Metals Summary Report

ICP-Data 13of20 

### elemenlOne
e 14503-Metals


### 61 

### 26.13PerkinElmer ELAN 6100 ICP-MS Sample 10: 14503-2BH Sample OaWednesday, May 19, 201019:01:12 Sample De Air Nova Concentration Results Analyte Mass Meas. IntemCone. Mear Report Unit 

### I> Li 6 91551 ppb 

### 1- Be 9 44.3 0.0461 ppb 

### I Sc 45 85249.9 ppb 

### I Cr 52 11381.5 3.20099 ppb 

### I Cr 53 2954.5 -15.88573 ppb 

### I Mn 55 25237.7 6.24293 ppb 

### I Co 59 610 0.19693 ppb 

### I Ni 60 1803.5 2.88819 ppb 

### I As 75 4559.1 10.39798 ppb 

### I Se 77 157.7 -6.2324 ppb 

### I Se 82 -173.9 -2.77005 ppb 

### I> Rh 103 106325.5 ppb 

### I Cd 111 154.9 0.24124 ppb 

### 1- Cd 114 237.7 0.1273 ppb 

### 1- Sb 121 1424.8 0.53725 ppb 

### I Sb 123 1082.1 0.52768 ppb 

### I> Ho 165 338150.3 ppb 

### 1- Pb 208 52699.9 3.21455 ppb Kr 83 1166.3 mg/L Method 6020 & 200.8 Metals Summary Report Sample 10: 14503-2BH Sample OaWednesday, May 19, 2010 19:04:22 Sample De Air Nova Concentration Results Analyte Mass Meas. IntemCone. Mear Report Unit 

### I> Li 6 96449.1 ppb 

### 1- Be 9 18.3 0.0001 ppb 

### I Sc 45 85165.4 ppb 

### I Cr 52 11174.5 3.04617 ppb 

### I Cr 53 2147.3 -18.785 ppb 

### I Mn 55 25425.9 6.18847 ppb 

### I Co 59 868.7 0.28542 ppb 

### I Ni 60 1791.5 2.82673 ppb 

### I As 75 4337.2 9.76293 ppb 

### I Se 77 142.7 -6.66055 ppb 

### I Se 82 -333.7 -5.91395 ppb 

### I> Rh 103 108055.8 ppb 

### I Cd 111 133.9 0.20908 ppb 

### 1- Cd 114 203.7 0.10599 ppb 

### 1- Sb 121 1326.1 0.47621 ppb 

### I Sb 123 1045 0.48624 ppb 

### I> Ho 165 352530.1 ppb 

### 1- Pb 208 52708.8 3.07819 ppb Kr 83 1250 mg/L

ICP-Oata 14 of20 elementOne 

### e 14503-Metals 

### 62 26.14PerkinElmer ELAN 6100 ICP-MS

97413.5 ppb 28467.6 43.7556 ppb 87580.8 ppb 158140.2 61.21907 ppb 19049 36.995 ppb 268936.7 64.76312 ppb

144987 49.10882 ppb 39304.5 64.95785 ppb 39845.2 88.19729 ppb

4128.3 93.65812 ppb 5287.7 100.64429 ppb 111521.4 ppb 33128.8 44.34772 ppb 79397.4 44.86271 ppb 130640.1 48.36126 ppb 100500.1 48.04733 ppb 355134.5 ppb 921264.7 54.14097 ppb

1010.3 mg/L Meas. IntemCone. MearReport Unit 6 9 45 52 53 55 59 60 75 77 82 103 111 114 121 123 165 208

83 Method 6020 &200.8 Metals Summary Report Sample 10: 14503-3BH Sample DaWednesday. May 19. 2010 19:07:32 Sample DeAirNova Concentration Results Analyte Mass Meas. Intem Cone. MearReport Unit Li 6 98051 ppb Be 9 16.3 -0.00338 ppb Sc 45 86875.2 ppb Cr 52 35113 12.37413 ppb Cr 53 4833.6 -10.16634 ppb Mn 55 63440.6 15.12955 ppb Co 59 1057.7 0.33868 ppb Ni 60 9633.8 15.7072 ppb As 75 4776.1 10.39762 ppb Se 77 126.3 -7.22312 ppb Se 82 -488.6 -8.49632 ppb Rh 103 111794.1 ppb Cd 111 213.5 0.30955 ppb Cd 114 407.4 0.21749 ppb Sb 121 837.4 0.28933 ppb Sb 123 665 0.29834 ppb Ho 165 357840.9 ppb Pb 208 70363.8 4.05887 ppb Kr 83 1307.8 mg/L Method 6020 &200.8 Metals Summary Report Sample 10: 14503-3BH Sample DaWednesday. May 19, 2010 19:10:42 Sample DeAirNova Concentration Results Analyte Mass Li Be Sc Cr Cr Mn Co Ni As Se Se Rh Cd Cd Sb Sb Ho Pb Kr 

### I>II I I 

### I I I I I 

### I 

### I> II### II 

### I> 

### 1-

I>II I I 

### I I I I I 

### I I> I

### II

### I I> 1-

ICP-Data 15 of20 elemenlOne
e 14503-Metals 

### 26.15


### 63PerkinElmer ELAN 6100 ICP-MS

85581.3 ppb 18.3 0.0037 ppb 10520.8 16.74125 ppb 104783.2 ppb

5964.3 0.70338 ppb 12486.6 12.97176 ppb

2491 0.4168 ppb

129 0.02203 ppb 197.7 0.06376 ppb 356.7 0.05583 ppb

787 0.7345 ppb 2186.9 3.52571 ppb 2257.6 12.89021 ppb 1843.9 3.61513 ppb

80.4 -0.03914 ppb 623.4 4.43498 ppb -11.6 0.47091 ppb 118227 ppb

917.7 0.24834 ppb 871.7 0.23834 ppb 26.8 0.05712 ppb 51.3 0.01454 ppb 89.3 0.01535 ppb 72.9 0.01816 ppb 85.7 0.05799 ppb 142.3 0.06146 ppb 349493.5 ppb 402 0.01807 ppb 4810.2 0.24334 ppb

60.3 mg/L Meas. IntemCone. MearReport Unit 6 9 31 45 52 53 55 59 60 63 65 66 67 68 75 77 82 103 107 109 111 114 121 123 135 137 165 205 208

83 Method 6020 &200.8 Metals Summary Report Sample 10: 14503-4BH Sample DaWednesday, May 19, 2010 19:13:50 Sample De Air Nova Concentration Results Analyte Mass Meas. IntemCone. MearReport Unit Li 6 93995.3 ppb Be 9 29 0.01799 ppb Sc 45 85941.1 ppb Cr 52 11401.8 2.82616 ppb Cr 53 1962.2 -19.88998 ppb Mn 55 41745.7 9.55483 ppb Co 59 958.4 0.29342 ppb Ni 60 2397.3 3.58245 ppb As 75 184.8 0.19045 ppb Se 77 42.7 -9.36027 ppb Se 82 -6.3 0.57217 ppb Rh 103 115860.2 ppb Cd 111 289.9 0.39785 ppb Cd 114 601.1 0.31446 ppb Sb 121 2748.7 0.98096 ppb Sb 123 2148 0.99223 ppb Ho 165 362005 ppb Pb 208 118741.9 6.81148 ppb Kr 83 -86.5 mg/L Method 6020 &200.8 Metals Summary Report Sample 10: QC Std 1 Sample DaWednesday, May 19, 2010 19:32:39 Sample Description: Concentration Results Analyte Mass Li Be P Sc Cr Cr Mn Co Ni Cu Cu Zn Zn Zn As Se Se Rh Ag Ag Cd Cd Sb Sb Ba Ba Ho TI Pb Kr 

### I> I- I I I 

### I I I I 

### I 1 

### I> I

### II- I 

### I> 1-



### I>II- I I I 

### I I I I 

### I I 

### I I 1 

### I 

### I I> I I I

### II- I 

### I I 

### I> I 1-

ICP-Data 16of20 elementOne 

### e 14503-Metals 

### 26.16
64PerkinElmer ELAN 6100 ICP-MS

73784.5 ppb 32 0.03695 ppb 12321.3 25.30332 ppb 90299.1 ppb

5814.2 0.56037 ppb 13899 15.63905 ppb 1402.1 0.15813 ppb

222 0.04919 ppb 289 0.18827 ppb 342.3 0.03813 ppb 739.7 0.62719 ppb 610.4 0.51136 ppb 2659.4 16.19763 ppb

829.7 0.82549 ppb 178.5 0.15402 ppb

634 4.1307 ppb -4.2 0.60612 ppb 123071.8 ppb

2214.6 0.68772 ppb 2066.9 0.64715 ppb

42.9 0.07652 ppb 94.9 0.03589 ppb 165.7 0.04545 ppb 105.3 0.03479 ppb 71.7 0.04056 ppb 126.3 0.05052 ppb 344180.1 ppb 759.4 0.04859 ppb 1884.4 0.07005 ppb 61 mg/L Meas. IntemCone. MearReport Unit 6 9 31 45 52 53 55 59 60 63 65 66 67 68 75 77 82 103 107 109 111 114 121 123 135 137 165 205 208

83 Method 6020 &200.8 Metals Summary Report Sample ID: QC Std 4 Sample DaWednesday, May 19, 2010 19:35:47 Sample Description: Concentration Results Analyte Mass Meas. IntemCone. MearReport Unit Li 6 82701.9 ppb Be 9 53283.8 96.37607 ppb P 31 177949.8 1071.5858 ppb Sc 45 101631.9 ppb Cr 52 289104 103.07795 ppb Cr 53 46284.7 113.79576 ppb Mn 55 474786.7 104.35924 ppb Co 59 330285.9 102.00845 ppb Ni 60 67967.7 102.53166 ppb Cu 63 157491.3 102.95845 ppb Cu 65 76463.6 103.47032 ppb Zn 66 55960.2 101.71572 ppb Zn 67 11644.1 115.14598 ppb Zn 68 40606.3 103.64479 ppb As 75 51739.3 104.3963 ppb Se 77 5075.8 106.37795 ppb Se 82 6026.1 104.45798 ppb Rh 103 122334.8 ppb Ag 107 281591.9 98.00966 ppb Ag 109 272568.1 95.96102 ppb Cd 111 80422.4 98.12647 ppb Cd 114 194779.8 100.36779 ppb Sb 121 279954.1 103.15315 ppb Sb 123 217871 103.7126 ppb Ba 135 78980.4 106.81462 ppb Ba 137 138228.6 105.79761 ppb Ho 165 356838.4 ppb TI 205 1295140.5 103.64488 ppb Pb 208 1746535 102.16547 ppb Kr 83 -4468.4 mg/L Method 6020 &200.8 Metals Summary Report Sample ID: QC Std 1 Sample DaThursday, May20,201008:45:42 Sample Description: Concentration Results Analyte Mass Li Be P Sc Cr Cr Mn Co Ni Cu Cu Zn Zn Zn As Se Se Rh Ag Ag Cd Cd Sb Sb Ba Ba Ho TI Pb Kr 

### I>II- I I I 

### I I I I 

### I I I I 

### I I I 

### I> I 

### I I

### II- I I I 

### I> I 1-



### I>II- I 

### I I I I I I I I 

### I I I I 

### I I> I I 

### III- I 

### I I I> I 

### 1-

ICP-Data 17of20 elementOne 

## e 14503-Metals 

### 26.17


### 65PerkinElmer ELAN 6100 ICP-MS

ppb -0.00386 ppb ppb 0.84082 ppb 2.09393 ppb 1.49108 ppb 0.04585 ppb 0.71626 ppb 1.87749 ppb -0.65536 ppb

-3.7369 ppb ppb 0.07146 ppb 0.02141 ppb 0.11607 ppb 0.13423 ppb ppb 0.71898 ppb mglL 77761.7 12.7 84246.2

5810.2 8270.4 6602.1

186.7 563.4 906.7 374.7 -226.9 108391.3 34.1 59.3 330.3 288.6 323203.5 11821 453.7 Meas. IntemCone. MearReport Unit 6 9 45 52 53 55 59 60 75 77 82 103 111 114 121 123 165 208

83 Method 6020 &200.8 Metals Summary Report Sample ID: QC Std 4 Sample DaThursday, May20,201008:48:50 Sample Description: Concentration Results Analyte Mass Meas. Intem Cone. MearReport Unit Li 6 74813.7 ppb Be 9 49881 99.97643 ppb P 31 176149.2 1040.9585 ppb Sc 45 91008.7 ppb Cr 52 292205.4 102.40338 ppb Cr 53 47339 114.54243 ppb Mn 55 476226.1 102.83057 ppb Co 59 334364 101.51229 ppb Ni 60 69174.7 102.59352 ppb Cu 63 161545.4 103.79731 ppb Cu 65 78130.1 103.86103 ppb Zn 66 54932.6 98.07071 ppb Zn 67 11662.5 113.22955 ppb Zn 68 40023 100.34484 ppb As 75 51904 102.93013 ppb Se 77 5008 102.75178 ppb Se 82 5710.9 97.34033 ppb Rh 103 124537.3 ppb Ag 107 281225.8 96.21778 ppb Ag 109 274928.5 95.10465 ppb Cd 111 80623.7 96.61231 ppb Cd 114 192923.8 97.66481 ppb Sb 121 282361.3 107.06744 ppb Sb 123 219969.3 107.83314 ppb Ba 135 79817.9 111.13614 ppb Ba 137 139648 109.92489 ppb Ho 165 347170.3 ppb TI 205 1278541.2 105.3474 ppb Pb 208 1699215.3 102.28579 ppb Kr 83 -4450.6 mglL Method 6020 &200.8 Metals Summary Report Sample ID: 14503-3BH Sample DaThursday, May20,201009:00:52 Sample De Air Nova Concentration Results Analyte Mass Li Be Sc Cr Cr Mn Co Ni As Se Se Rh Cd Cd Sb Sb Ho Pb Kr 

### I> I- I I 

### I 1 

### I I 

### I I 

### I I> II

### I- I 

### I> 1- 

### I>II- I 

### I I I 

### I 

### I I 1 

### I I I I 

### I I I> I 

### I I

### II- I 1 

### I I> I 

### 1-

ICP-Data 18of20 

### elementOne
e 14503-Metals 

### 26.18

66PerkinElmer ELAN 6100 ICP-MS

81243.3 ppb 31.3 0.02911 ppb 11646.8 23.2417 ppb 89230.3 ppb

5661.8 0.56191 ppb 10948.6 7.67031 ppb

1245.1 0.13171 ppb 248.7 0.05975 ppb 275.3 0.18162 ppb 327.7 0.03494 ppb 1091.7 1.15154ppb 615.4 0.55528 ppb 2100.9 10.68095 ppb 706 0.55337 ppb 60.9 -0.07816 ppb 484.7 1.01789 ppb -14.7 0.4231 ppb 119628.7 ppb

2475.4 0.8115 ppb

2324 0.76764 ppb 60.8 0.10091 ppb 105.1 0.04309 ppb

168 0.04498 ppb 137.8 0.04938 ppb 83.3 0.05494 ppb 120.3 0.04396 ppb 349264 ppb

807.7 0.05135 ppb 1911.4 0.06939 ppb

80.4 mg/L Meas. IntemCone. MearReport Unit 6 9 31 45 52 53 55 59 60 63 65 66 67 68 75 77 82 103 107 109 111 114 121 123 135 137 165 205 208

83 Method 6020 &200.8 Metals Summary Report Sample ID: 14503-3BH Sample DaThursday, May20, 2010 09:04:00 Sample De AirNova Concentration Results Analyte Mass Meas. Intem Cone. MearReport Unit Li 6 82995 ppb Be 9 25660.6 46.29505 ppb Sc 45 89084.1 ppb Cr 52 132629.6 50.71513 ppb Cr 53 22662.2 48.43425 ppb Mn 55 219040.6 52.28468 ppb Co 59 146609.1 49.29432 ppb Ni 60 31299.2 51.31491 ppb As 75 27488.7 60.32126 ppb Se 77 3038.5 65.69163 ppb Se 82 3444.9 65.32303 ppb Rh 103 112423.8 ppb Cd 111 35386.6 46.97424 ppb Cd 114 86634 48.57609 ppb Sb 121 132238.2 50.89324 ppb Sb 123 102306.6 50.87754 ppb Ho 165 341636.5 ppb Pb 208 853654.8 52.16478 ppb Kr 83 455.1 mg/L Method 6020 &200.8 MetalsSummary Report Sample ID: QC Std 1 Sample DaThursday, May20,201009:07:08 Sample Description: Concentration Results Analyte Mass Li Be P Sc Cr Cr Mn Co Ni Cu Cu Zn Zn Zn As Se Se Rh Ag Ag Cd Cd Sb Sb Ba Ba Ho TI Pb Kr 

### I>

### II- I I I 

### I I 

### I I I 

### I I 

### I 

### I I I 

### I> I 

### I I

### II- I I 

### I I> I 

### 1- I> I- I I 

### I I I I I I 

### I I> I

### II- I 

### I> 

### 1-

ICP-Data 19of20 elementOne
e 14503-Metals 

### 26.19

67PerkinElmer ELAN 6100 ICP-MS

Meas. IntemCone. MearReport Unit 6 79322 ppb 9 52508.6 99.04208 ppb 31 173079.2 1062.2468 ppb 45 89519.6 ppb 52 284897.8 103.547 ppb 53 43961.9 109.23646 ppb 55 464626.2 104.02705 ppb 59 326606.6 102.87012 ppb 60 67546.6 103.90722 ppb 63 156085 104.00869 ppb 65 75796.6 104.44811 ppb 66 54416.2 100.75639 ppb 67 11227.6 113.03448 ppb 68 39805.4 103.58835 ppb 75 51006 104.94573 ppb 77 4809.9 102.38109 ppb 82 5721.6 101.21468 ppb 103 120161.1 ppb 107 276662.8 98.20815 ppb 109 266812.9 95.68106 ppb 111 78901.6 98.01994 ppb 114 190047.5 99.85866 ppb 121 278452.3 105.22629 ppb 123 213964.8 104.48701 ppb 135 77949.8 108.13731 ppb 137 136706.5 107.31814 ppb 165 348025 ppb 205 1267245 104.00064 ppb 208 1717143.6 103.0175 ppb

83 -4363.1 mg/L Method 6020 &200.8 Metals Summary Report Sample 10: QC Std4 Sample Oa Thursday, May20,201009:10:16 Sample Description: Concentration Results Analyte Mass Li Be P Sc Cr Cr Mn Co Ni Cu Cu Zn Zn Zn As Se Se Rh Ag Ag Cd Cd Sb Sb Ba Ba Ho TI Pb Kr 

### I>

### III I 

### I I I 

### I I I 

### I I I I 

### I I 

### I> I I 

### IIII I I 

### I> I 1-

ICP-Oata 20of20 elementOne
e 14503-Metals 

### 26.20


### 68PerkinElmer FIMS-100 CVAA MercuryAnalyzer Sample_1D Date Time Mean_Sig Mean_Rd Mean_Rt Units Alq. Vol. Sig 1 Reading-1 Result-1 Sig 2 Reading-2 Result-2 Calib Blank 5/20/2010 12:49:03 0.0005393**~g** 0.0005393 STD1=.004ug 5/20/2010 12:50:18 0.0009945**~g** 0.0009945 STD2=.04ug 5/20/2010 12:51:34 0.0103547**~g** 0.0103547 STD3=.08ug 5/20/2010 12:52:51 0.0212455**~g** 0.0212455 STD4=.16ug 5/20/2010 12:54:09 0.040403**~g** 0.040403 STD5=.2ug 5/20/2010 12:55:29 0.05327**~g** 0.05327 ReagentBlank 5/20/2010 12:57:17 -0.0000645 -0.000247 -0.000247**~g** -0.0000423 -0.0001619 -0.0001619 -0.0000868 -0.0003321 -0.0003321 0.004ug =DL 5/20/2010 12:58:31 0.0010321 0.0039473 0.0039473**~g** 0.0010321 0.0039473 0.0039473 0.080ug =STD.2 5/20/2010 12:59:48 0.0205794 0.0787071 0.0787071**~g** 0.0205794 0.0787071 0.0787071 0.080ug=QC STD 3 5/20/2010 13:01:08 0.020962 0.0801703 0.0801703**~g** 0.020962 0.0801703 0.0801703 REAGENT BLANK 5/20/2010 13:02:25 -0.0000379 -0.0001451 -0.0001451**~g** -0.0000379 -0.0001451 -0.0001451 0.004ug =DL 5/20/2010 14:08:48 0.0009773 0.0037377 0.0037377**~g** 4 400 0.0009773 0.0037377 0.0037377 0.080ug =STD.2 5/20/2010 14:10:05 0.0201466 0.0770518 0.0770518**~g** 4 400 0.0201466 0.0770518 0.0770518 REAGENT BLANK 5/20/2010 14:11:22 -0.0000508 -0.0001946 -0.0001946**~g** 4 400 -0.0000508 -0.0001946 -0.0001946 14502/503-lrb 5/2012010 14:19:46 6.507E-05 0.0002489 0.0062222**~g** 4 100 7.327E-05 0.0002802 0.0070059 5.688E-05 0.0002175 0.0054386 14502/503-lrbspk 5/2012010 14:21:35 0.0169244 0.0647283 1.6182072**~g** 4 100 0.0169868 0.0649669 1.6241714 0.016862 0.0644897 1.6122429 0.004ug =DL 5/20/2010 14:32:00 0.0010226 0.0039111 0.0039111**~g** 4 100 0.0010226 0.0039111 0.0039111 0.080ug=STD.2 5/20/2010 14:33:17 0.0205434 0.0785695 0.0785695**~g** 4 100 0.0205434 0.0785695 0.0785695 REAGENTBLANK 5/20/2010 14:34:34 -0.0000987 -0.0003776 -0.0003776**~g** 4 100 -0.0000987 -0.0003776 -0.0003776 14503-1a 5/20/2010 14:53:44 9.607E-05 0.0003675 0.0183726**~g** 4 200 8.205E-05 0.0003138 0.0156918 0.0001101 0.0004211 0.0210534 14503-2a 5/20/2010 14:55:31 1.477E-05 5.651E-05 0.0028259**~g** 4 200 1.083E-05 4.144E-05 0.0020721 1.871E-05 7.159E-05 0.0035797 14503-2adup 5/20/2010 14:57:19 0.0001526 0.0005838 0.0291898**~g** 4 200 0.0001449 0.000554 0.0277002 0.0001604 0.0006136 0.0306794 14503-3a 5/20/2010 14:59:07 6.245E-05 0.0002389 0.0119428**~g** 4 200 4.575E-05 0.000175 0.0087494 7.915E-05 0.0003027 0.0151362 14503-3aspk 5/20/2010 15:00:55 0.0209637 0.0801767 4.0088354**~g** 4 200 0.0208632 0.0797927 3.9896339 0.0210641 0.0805607 4.0280368 0.004ug=DL 5/20/2010 15:02:10 0.0009947 0.0038044 0.0038044**~g** 4 200 0.0009947 0.0038044 0.0038044 0.080ug =STD.2 5/20/2010 15:03:27 0.0204693 0.078286 0.078286**~g** 4 200 0.0204693 0.078286 0.078286 REAGENT BLANK 5/20/2010 15:04:43 -0.0000042 -0.0000162 -0.0000162**~g** 4 200 -0.0000042 -0.0000162 -0.0000162 14503-4a 5/20/2010 15:06:30 0.0001449 0.0005541 0.027707**~g** 4 200 0.0001543 0.0005901 0.0295035 0.0001355 0.0005182 0.0259105 14503-1b 5/20/2010 15:08:20 0.000218 0.0008339 0.1042363**~g** 4 500 0.0002123 0.000812 0.101497 0.0002238 0.0008558 0.1069757 14503-2b 5/20/2010 15:10:10 0.0001219 0.0004662 0.0582698**~g** 4 500 0.00013 0.0004971 0.0621368 0.0001138 0.0004352 0.0544028 14503-2bdup 5/20/2010 15:12:01 9.488E-05 0.0003629 0.0453595**~g** 4 500 9.847E-05 0.0003766 0.0470789 9.128E-05 0.0003491 0.0436401 14503-3b 5/20/2010 15:13:49 0.0000628 0.0002402 0.0300233**~g** 4 500 8.445E-05 0.000323 0.0403745 4.114E-05 0.0001574 0.0196721 14503-3bspk 5/20/2010 15:15:33 0.0195932 0.0749354 9.3669217**~g** 4 500 0.0194908 0.0745438 9.3179692 0.0196956 0.075327 9.4158742 14503-4b 5/20/2010 15:17:17 2.465E-05 9.429E-05 0.0117873**~g** 4 500 2.355E-05 0.0000901 0.0112625 2.575E-05 9.849E-05 0.0123121 14503-1c 5/20/2010 15:19:02 0.0001321 0.0005053 0.0505314**~g** 4 400 0.0001174 0.0004491 0.0449105 0.0001468 0.0005615 0.0561523 14503-2c 5/20/2010 15:20:48 0.0002349 0.0008982 0.0898235**~g** 4 400 0.0002368 0.0009058 0.0905828 0.0002329 0.0008906 0.0890642 14503-2cdup 5/20/2010 15:22:34 0.0007937 0.0030355 0.3035483**~g** 4 400 0.0008089 0.0030938 0.3093828 0.0007784 0.0029771 0.2977137 0.004ug =DL 5/20/2010 15:23:48 0.0009942 0.0038023 0.0038023**~g** 4 400 0.0009942 0.0038023 0.0038023 0.080ug =STD.2 5/20/2010 15:25:05 0.0204261 0.0781206 0.0781206**~g** 4 400 0.0204261 0.0781206 0.0781206 REAGENTBLANK 5/20/2010 15:26:22 -0.0000159 -0.0000611 -0.0000611**~g** 4 400 -0.0000159 -0.0000611 -0.0000611 14503-3c 5/20/2010 15:28:08 0.0001928 0.0007373 0.0737255**~g** 4 400 0.0001948 0.0007449 0.0744911 0.0001908 0.0007296 0.0729599 14503-3cspk 5/20/2010 15:29:54 0.0196252 0.0750577 7.5057671**~g** 4 400 0.0195709 0.07485 7.484997 0.0196795 0.0752654 7.5265373 14503-4c 5/20/2010 15:31:41 0.000104 0.0003976 0.0397575**~g** 4 400 8.583E-05 0.0003283 0.032827 0.0001221 0.0004669 0.0466879 14503-1fh 5/20/2010 15:33:29 7.559E-05 0.0002891 0.0072281**~g** 4 100 7.524E-05 0.0002878 0.0071946 7.594E-05 0.0002905 0.0072616 14503-2fh 5/20/2010 15:35:17 0.0001953 0.0007468 0.01867 I-Ig 4 100 0.0001984 0.0007587 0.0189674 0.0001922 0.0007349 0.0183726 14503-2fhdup 5/20/2010 15:37:06 0.0001099 0.0004201 0.0105034 I-Ig 4 100 0.0001087 0.0004158 0.0103959 0.000111 0.0004244 0.0106108 14503-3fh 5/20/2010 15:38:55 0.0002403 0.0009191 0.022978 I-Ig 4 100 0.0002347 0.0008977 0.0224423 0.0002459 0.0009406 0.0235138 14503-3fhspk 5/20/2010 15:40:45 0.0212197 0.0811559 2.0288983**~g** 4 100 0.0211543 0.0809057 2.0226432 0.0212851 0.0814061 2.0351535 14503-4fh 5/20/2010 15:42:35 -0.0000946 -0.000362 -0.0090502 I-Ig 4 100 -0.0000983 -0.0003759 -0.0093992 -0.000091 -0.000348 -0.0087012 14503-1bh 5/20/2010 15:44:22 0.0005958 0.0022785 0.2905075 I-Ig 4 510 0.0006005 0.0022967 0.2928275 0.000591 0.0022603 0.2881875 0.004ug=DL 5/20/2010 15:45:35 0.0010577 0.0040452 0.0040452 I-Ig 4 510 0.0010577 0.0040452 0.0040452 0.080ug=STD.2 5/20/2010 15:46:52 0.0204345 0.078153 0.078153 I-Ig 4 510 0.0204345 0.078153 0.078153 REAGENTBLANK 5/20/2010 15:48:09 -0.0000078 -0.0000298 -0.0000298 I-Ig 4 510 -0.0000078 -0.0000298 -0.0000298 14503-2bh 5/20/2010 15:49:54 0.0001802 0.0006892 0.0861501**~g** 4 500 0.000173 0.0006616 0.0826952 0.0001874 0.0007168 0.0896051 14503-2bhdup 5/20/2010 15:51:39 0.0001695 0.0006484 0.0810535 I-Ig 4 500 0.0001722 0.0006585 0.0823132 0.0001669 0.0006384 0.0797938 14503-3bh 5/20/2010 15:53:24 0.0001923 0.0007354 0.0919217 I-Ig 4 500 0.0001559 0.0005964 0.0745473 0.0002286 0.0008744 0.1092961 14503-3bhspk 5/20/2010 15:55:10 0.0211068 0.0807243 10.09054 I-Ig 4 500 0.020789 0.0795087 9.9385904 0.0214247 0.0819399 10.24249 14503-4bh 5/20/2010 15:56:56 9.07E-06 0.0000347 0.0026894**~g** 4 310 -0.0000262 -0.0001002 -0.0077704 4.436E-05 0.0001697 0.0131493 0.004ug =DL 5/20/2010 15:59:57 0.000966 0.0036944 0.0036944 I-Ig 5 1000 0.000966 0.0036944 0.0036944 0.080ug=QCSTD 3 5/20/2010 16:01:14 0.020007 0.0765177 0.0765177**~g** 5 1000 0.020007 0.0765177 0.0765177 REAGENT BLANK 5/20/2010 16:02:31 5.35E-06 2.048E-05 2.048E-05 I-Ig 5 1000 5.35E-06 2.048E-05 2.048E-05

Hg-Data 1 of1 elementOne


### e**64~03-Hg** 

### 27.1

### Appendix C
Emission Calculations

## James RiverCogeneration Company Hopewell, Virginia Project No. 3338 May 7,2010 Unit No.2 Run No.1 Coal Analysis for F FactorCalculation

FFACTOR CALCULATION

INPUT INPUT INPUT INPUT INPUT INPUT 

### % H= %C= %N= %0= %S= GCV= 

## 5.81 70.18

1.44 12.44 

## 0.89 13572 Hydrogen Content (%) Carbon Content (%) Nitrogen Content (%) Oxygen Content (%) SulfurContent (%) Gross CalorificValue (Btu/lb)

Fd = 10A

### 6 * [(3.64*%H) + (1.53*%C) + (0.57*%S) + (0.14*%N)

- (0.46*%02)] 

### IGCV Fd = 9100 scf/MMBtu



### 1

## James River Cogeneration Company Hopewell, Virginia Project No. 3338 May

## 7,2010 Unit No.2 Run No.2 Coal Analysis for F FactorCalculation

F FACTOR CALCULATION

INPUT INPUT INPUT INPUT INPUT INPUT 

### % H= %C= % N= %0= %S= GCV= 

## 5.83 70.25

1.46 12.14

0.9 

## 13528 Hydrogen Content (%) Carbon Content (%) Nitrogen Content (%) Oxygen Content (%) SulfurContent (%) Gross CalorificValue (Btu/Ib)

Fd = 10A

### 6 * [(3.64*%H) + (1.53*%C) + (0.57*%S) + (0.14*%N)

- (0.46*%02)] / GCV Fd = 9154 scf/MMBtu

2

## James RiverCogeneration Company Hopewell, Virginia Project No. 3338 May 7,2010 Unit No.2 Run No.3 Coal Analysis for F FactorCalculation

F FACTOR CALCULATION

INPUT INPUT INPUT INPUT INPUT INPUT 

### %H= %C= %N= %0= %S= GCV= 

## 5.61 67.92

1.36 14.02 

## 0.85 13409 Hydrogen Content (%) Carbon Content (%) Nitrogen Content (%) Oxygen Content (%) SulfurContent (%) Gross CalorificValue (Btu/lb)

Fd = 101\6 * [(3.64*%H) + (1.53*%C) + (0.57*%S) + (0.14*%N)

- (0.46*%02)] / GCV Fd = 8842 scf/MMBtu



### 3M7E

Client Project No. Test Location Test Date James RiverCogen 

### 3338 Unit2 05/07/10 Metals/PM-10 

### AirNova, Inc. EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment) Page 1

ActualCalibration Gas Value (% 02): AnalyzerCalibration Response (% 02): AnalyzerCalibration Error(% Span): Parameter: InstrumentSpan (% 02): 

### Oxygen 22.03 AnalvzerCalib. Gases Upscale zero low mid high Sys. Cal. Gas 0.00 N/A 12.47 22.03 12.47 0.01 N/A 12.43 21.89 12.47 0.05 0.00 -0.18 -0.64

Zero System Calibration Gas Upscale System Calibration Gas Apparent Init. Sys. Init. Sys. FinalSys. FinalSys. Calib. Init. Sys. Init. Sys. FinalSys. FinalSys. Calib. Actual ll» Stack Calib. Cal. Bias Calib. Cal. Bias Drift Calib. Cal. Bias Calib. Cal. Bias Drift Stack Run Cone. Response (% span) Response (% span) (% span) Response (% span) Response (% span) (% span) Cone.

1 5.55 0.11 0.45 0.05 0.18 -0.27 12.51 0.18 12.50 0.14 -0.05 5.49 2 5.67 0.05 0.18 0.10 0.41 0.23 12.50 0.14 12.34 -0.59 -0.73 5.65 3 5.51 0.10 0.41 0.09 0.36 -0.05 12.34 -0.59 12.45 -0.09 0.50 5.49 4 0.00 0.09 0.36 0.00 -0.05 -0.41 12.45 -0.09 0.00 -56.60 -56.51 -0.09 5 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR 6 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR 7 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR 8 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR 9 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR 10 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR 11 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERR 12 0.00 0.00 -0.05 0.00 -0.05 0.00 0.00 -56.60 0.00 -56.60 0.00 ERRM7E

Client Project No. Test Location Test Date James RiverCogen 

### 3338 Unit2 

### 05/07/10 

### AirNova, Inc. EPA Method 6C Calculations (Cal. Error, Bias Driftand Bias Adjustment) Page 2

ActualCalibration Gas Value (% C02): AnalyzerCalibration Response (% C02): AnalvzerCalibration Error(% Span): Parameter: InstrumentSpan 

### (% C02): 

### Carbon Dioxide 22.28 AnalyzerCalib. Gases Upscale zero low mid high Sys. Cal. Gas 0.00 N/A 12.38 22.28 12.38 0.00 N/A 12.33 22.34 12.38 0.00 0.00 -0.22 0.27

Zero System Calibration Gas Upscale System Calibration Gas Apparent Init. Sys. Init. Sys. FinalSys. FinalSys. Calib. Init. Sys. Init. Sys. FinalSys. FinalSys. Calib. Actual U1 Stack Calib. Cal. Bias Calib. Cal. Bias Drift Calib. Cal. Bias Calib. Cal. Bias Drift Stack Run Cone. Response (% span) Response (% span) (% span) Response (% span) Response (% span) (% span) Cone.

1 13.73 0.00 0.10 0.00 0.00 0.00 12.45 0.31 12.45 0.31 0.00 13.65 2 13.54 0.00 0.00 0.00 0.00 0.00 12.45 0.31 12.33 -0.22 -0.54 13.53 3 13.63 0.00 0.00 0.12 0.54 0.54 12.33 -0.22 12.45 0.31 0.54 13.63 4 0.00 0.12 0.54 0.00 0.00 -0.54 12.45 0.31 0.00 -55.57 -55.88 -0.12 5 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 6 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 7 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 8 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 

### 9 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 10 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 11 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR 12 0.00 0.00 0.00 0.00 0.00 0.00 0.00 -55.57 0.00 -55.57 0.00 ERR

### 3338-EPA5-202-R1 

## AirNova, Inc. EPA Methods 1,2,3A,4,5and 202 (Flows, 02/C02, H20, Total Suspended Particulate and Back Half PM)
Client James RiverCogeneration Company Project No. 3338 Test Location Hopewell, Virginia Emission Source Unit NO.2 Fuel Coal Test Date 05/07/10 Test Run One Time Period 0715-0930 Emission Data Datafrom: INPUT Vlc= 219.7 cc Vol. of H20 collected EPA4 INPUT Vm= 88.534 dcf Dry gas meterreading EPA4 INPUT Pstatic= 0.55 in. H2O Static pressure EPA2 INPUT Pb= 29.98 in. Hg Barometric pressure Ps= 30.02 in. Hg Stack pressure EPA2 Pstd = 29.92 in. Hg EPA Standard pressure dP= 0.800 in. H20 A.5 Average sq.rt delta P EPA2 dH= 1.67 in. H2O Average draft gauge reading EPA4 Tm= 538.7 R Average metertemperature EPA4 Ts= 669.8 R Average stacktemperature EPA2 INPUT Tstd= 527.7 R Standard temperature INPUT y= 1.00 Metercalibration factor INPUT t= 120 min. Duration ofsampling time INPUT Dn= 0.250 in. Nozzle diameter INPUT An= 0.000341 sq. ft. Nozzle area INPUT Os = 9.667 ft. Diameterofstack As= 73.39 sq. ft. Cross sectional area ofstack INPUT Cp= 0.84 Pitottube coefficient EPA2 Kp= 85.49 ft[(lbllbmol)*(inHg»)A.5}/[s*R*inH20] Pitottube constant K1 = 7.637 R/in.Hg constant K2= 0.047070 cU.ftIml constant K3= 0.0026688 in.Hg-cf/ml-R constant Molarvol air= 385.0 scfllb-mol constant @ 

### 68 deg F Fd = 9100 scf/MMBtu Fuel Factor

EPA Method 3A Instrumental Data
INPUT EPA3 INPUT EPA3 [02] [C02] [N2] 5.49 %-dry 13.65 %-dry

80.86 %-dry

6 Oxygen concentration Carbon Dioxide concentration Nitrogen concentration

### Client Project No. James River Cogeneration Com Emission Source 3338 Test Run
Calculations Unit No.2 One Page 2

1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1* Y *Vm * (Pb + dH/13.6)/Tm Vmstd = 87.255 dsef 2.471 dsem 2) Volume ofwatervaporcollected atstandard conditions, Vw(std). Vw(std) = K2 *Vic Vw(std) = 10.341 sef 3) Decimal fraction ofmoisture byvolume in stackgas, Bws.

Bws =Vwstd / (Vmstd+Vwstd) Bws = 0.1060 4) Molecularweightofthe stackgas on awet basis, Ms.

Ms = [«44*%C02) + (32*%02) + (28*%N2)) * (1-Bws)] + (18*Bws) Ms = 29.089 Ib/lbmole 5) Average stackgas velocity, Vs.

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)".5 Vs = 50.289 fps 6) Average actual stackgas volumetricflowratej 

### Qa.
Qa =60 sec/min *Vs *As Qa = 221456.33 efm 6271.64 emm 7) Average stackgas dryvolumetric flowrate, Qstd.
Qstd = Qa * (TstdITs) * (Ps/Pstd) * (1-Bws) Qstd = 156514.21 dsefm Qstd = 4432.48 dsemm

7

### Client Project No. James River Cogeneration Com Emission Source 3338 Test Run
Calculations (cont.) Unit NO.2 One Page 3

8) 

### Particulate MatterAnalytical Data
INPUT A 0.0040 

### 9 Filtersample netwt INPUT B 200 ml Front acetonewash vol. INPUT C 0.0038 

### 9 Frontacetone residue wt. INPUT D 200 ml Acetone blankvol. INPUT E 0.0000 

### 9 Acetone blank residuewt.
9) 

### Particulate sample mass calculations

H 

### I 

### J Front Half: Acetone blankadj. residue wt Adj. Acetone wash part.wt. Front halfsamplewt. 0.0000 

### 9 0.0038 9 0.0078 9 E*(B/D) C-H A+I 10) Total Suspended Particulate Matter Emission Data C[TSP] (grains/dscf) = (Front HalfWt)(g) * (1Nmstd) * 15.43(grains/g) C[TSP] (Ib/dscf) = C[TSP] (grains/dscf) * (1 Ib/7000

### grains) E[TSP] (lb/MMBtu) = C[TSP] (Ib/dscf) 

### * Fd * (20.9/(20.9-02» 

### E[TSP] (Ib/hr) 

### = C[TSP] *Vdscfm * A * (60 min/hr) * (1 Ib 1

### 7000 graim C[TSP] = 1.38E-03 grains/dscf C[TSP] = 1.97E-07 Ib/dscf 

### E[TSP] = 0.0024 Ib/MMBtu E[TSP] = 1.850 Ib/hr 11) Back HalfOrganic Particulate Analysis C[BHOPM] (grains/dscf) = (Organic Mass Wt)(g) * (1Nmstd) * 15.43(grains/g) C[BHOPM] (Ib/dscf) = C[BHOPM] (grains/dscf) * (1 Ib/7000

### grains) E[BHOPM] (Ib/MMBtu) = C[BHOPM] (Ib/dscf) 

### * Fd * (20.9/(20.9-02» 

### E[BHOPM] (Ib/hr) = C[BHOPM] *Vdscfm * A * (60 min/hr) 

### * (1 Ib 17000

### grains) BHOPM Mass = 0.0000 9 C[BHOPM]= O.OOE+OO grains/dscf C[BHOPM]= O.OOE+OO Ib/dscf E[BHOPM]= 0.0000 Ib/MMBtu E[BHOPM]= 0.000 Ib/hr % 

### BHOPM 0.0



### 8

### Client Project No. James River Cogeneration Com Emission Source 3338 Test Run
Calculations (cont.) Unit NO.2 One Page 4

12) Back HalfInorganic Particulate Analysis C[BHIPM] (grains/dscf) = (Inorganic Mass Wt)(g) * (1Nmstd) * 15.43(grains/g) C[BHIPM] (Ib/dscf) = C[BHIPM] (grains/dscf) * (1 Ib/7000 

### grains) E[BHIPM] (Ib/MMBtu) = C[BHIPM] (Ib/dscf) * Fd * (20.9/(20.9-02» 

### E[BHIPM] (Ib/hr) = C[BHIPM] *Vdscfm * A * (60 min/hr) * (1 Ib 

### 17000 grains) BHIPM Mass = 0.0045 9 C[BHIPMj= 7.96E-04 grains/dscf C[BHIPMj= 1.14E-07 Ib/dscf E[BHIPMj= 0.0014 Ib/MMBtu E[BHIPM]= 1.068 Ib/hr % 

### BHIPM 36.6 13) Total Back HalfParticulate Matter C[TBHPMj (grains/dscf) = (C[BHOPMj (grains/dscf) + (C[BHIPM] (grains/dscf) C[TBHPM] (Ib/dscf) = (C[BHOPM] (Ib/dscf) + (C[BHIPMj (Ib/dscf) E[TBHPMj (lb/MMBtu) = (E[BHOPM] (lb/MMBtu» + (E[BHIPM] (lb/MMBtu» E[TBHPMj (Ib/hr) = C[TBHPM] *Vdscfm * A * (60 min/hr) * (1 Ib 1

### 7000 grains) Blank Mass = 0.0000 9 TBHPM Mass = 0.0045 9 C[TBHPMj= 7.96E-04 grains/dscf C[TBHPM]= 1.14E-07 Ib/dscf E[TBHPMj= 0.0014 Ib/MMBtu E[TBHPM]= 1.068 Ib/hr % 

### TBHPM 36.6 14) Total Particulate Matter

### <10 

### Microns Emission Data C[TPM10j (grains/dscf) = (C[TSP] (grains/dscf) + (C[TBHPM] (grains/dscf) C[TPM10] (Ib/dscf) = (C[TSP] (Ib/dscf) + (C[TBHPMj (Ib/dscf) E[TPM10] (lb/MMBtu) = (E[TSP] (Ib/MMBtu» + (E[TBHPM] (lb/MMBtu» E[TPM10] (Ib/hr) = C[TPM10] *Vdscfm * A * (60 min/hr) * (1 Ib 1

### 7000 grains) C[TPM10] = 2.18E-03 grains/dscf C[TPM10j = 3.11 E-07 Ib/dscf E[TPM10] = 0.0038 Ib/MMBtu E[TPM10] = 2.918 Ib/hr 15) Isokinecity, 

### I.

% 

### I = [1 00*Ts*(K3*Vlc+«(Vm*Y)/Tm)*(Pb+(dH/13.6))))] 

### 1(60*t*Ps*Vs*An) % 

### 1= 100.03

9

### 3338-EPA5-202-R2 

### AirNova, Inc. EPA Methods 1,2,3A,4,5and 202 (Flows, 02/C02, H20, Total Suspended Particulate and Back Half PM)
Client James River Cogeneration Company Project No. 3338 Test Location Hopewell, Virginia Emission Source Unit NO.2 Fuel Coal Test Date 05/07/10 Test Run Two Time Period 0952-1203 Emission Data Datafrom: INPUT Vlc= 217.9 cc Vol. of H20 collected EPA4 INPUT Vm= 91.242 dcf Drygas meter reading EPA4 INPUT Pstatic = 0.55 in. H2O Static pressure EPA2 INPUT Pb= 30.02 in. Hg Barometric pressure Ps = 30.06 in. Hg Stack pressure EPA2 Pstd = 29.92 in. Hg EPA Standard pressure dP = 0.810 in. H20 1\.5 Average sq.rt delta P EPA2 dH = 1.76 in. H2O Average draft gauge reading EPA4 Tm= 549.0 R Average metertemperature EPA4 Ts= 672.5 R Average stacktemperature EPA2 INPUT Tstd= 527.7 R Standard temperature INPUT y= 1.00 Metercalibration factor INPUT t= 120 min. Duration ofsampling time INPUT Dn = 0.250 in. Nozzle diameter INPUT An= 0.000341 sq. ft. Nozzle area INPUT Ds= 9.667 ft. Diameterofstack As= 73.39 sq. ft. Cross sectional area ofstack INPUT Cp= 0.84 Pitottube coefficient EPA2 Kp= 85.49 ft[(lb/lbmol)*(inHg)]A.5}/[s*R*inH20] Pitottube constant K1 = 17.637 R/in.Hg constant K2 = 0.047070 cu.ftIml constant K3 = 0.0026688 in.Hg-cf/ml-R constant Molarvol air= 385.0 scf/lb-mol constant @ 68 deg F Fd = 9154 scf/MMBtu Fuel Factor

EPA Method 3A Instrumental Data

INPUT EPA3 INPUT EPA3 [02] [C02]
[N2] 5.65 %-dry 13.53 %-dry

80.82 %-dry



### 10 Oxygen concentration Carbon Dioxide concentration Nitrogen concentration

### Client Project No. James River Cogeneration Com Emission Source 3338 Test Run
Calculations Unit NO.2 Two Page 2

1) Volume ofgas sampled atstandard conditions, Vmstd.
Vmstd =K1 * Y *Vm * (Pb + dH/13.6) /Tm Vmstd = 88.382 dscf 2.503 dscm 2) Volume ofwatervaporcollected atstandard conditions, Vw(std). Vw(std) = K2 *Vic Vw(std) 

### = 10.257 sef 3) Decimal fraction ofmoisture byvolume in stackgas, Bws.

Bws =Vwstd / (Vmstd+Vwstd) Bws = 0.1040 4) Molecularweight ofthe stackgas on awet basis, Ms.

Ms = [«44*%C02) + (32*%02) + (28*%N2)) * (1-Bws) 

## 1+ (18*Bws) Ms = 29.102 Ib/lbmole 5) Average stackgasvelocity, Vs.

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)A.5 Vs = 50.987 fps 6) Average actual stackgasvolumetricflowrate, Qa.
Qa = 60 sec/min *Vs *As Qa = 224528.65 efm 6358.65 emm 7) Average stackgas dryvolumetricflowrate, Qstd.
Qstd =Qa * (TstdlTs) * (Ps/Pstd) * (1-Bws) Qstd = 158617.05 dsefm Qstd = 4492.03 dsemm



### 11

### Client Project No. James River Cogeneration Com Emission Source 3338 Test Run
Calculations (cont.) Unit NO.2 Two Page 3

8) 

### Particulate MatterAnalytical Data
INPUT A 0.0045 

### 9 Filtersample netwt INPUT B 200 ml Frontacetonewash vol. INPUT C 0.0027 

### 9 Frontacetone residue wt. INPUT D 200 ml Acetone blankvol. INPUT E 0.0000 

### 9 Acetone blank residue wt. 9) 

### Particulate sample mass calculations

H I 

### J Front Half: Acetone blankadj. residue wt Adj. Acetone wash part.wt. Front halfsamplewt. 0.0000 

### 9 0.0027 9 0.0072 9 E*(B/D) C-H A+I 10)

### Total Suspended Particulate Matter Emission Data C[TSP] (grains/dscf) = (Front HalfWt)(g) * (1 Nmstd) 

### * 15.43(grains/g) C[TSP] (Ib/dscf) = C[TSP] (grains/dscf) * (1 Ib/7000

### grains) E[TSP] (lb/MMBtu) = C[TSP] (Ib/dscf) * Fd * (20.9/(20.9-02)) 

### E[TSP] (Ib/hr) = C[TSP] *Vdscfm * A * (60 min/hr) * (1 Ib I

### 7000 graim C[TSP] = 1.26E-03 grains/dscf C[TSP] = 1.80E-07 Ib/dscf E[TSP] = 0.0023 Ib/MMBtu E[TSP] = 1.709 Ib/hr 11) Back HalfOrganic Particulate Analysis C[BHOPM] (grains/dscf) = (Organic MassWt)(g) * (1 Nmstd) * 15.43(grains/g) C[BHOPM] (Ib/dscf) = C[BHOPM] (grains/dscf) * (1 Ib/7000

### grains) E[BHOPM] (lb/MMBtu) = C[BHOPM] (Ib/dscf) * Fd * (20.9/(20.9-02)) 

### E[BHOPM] (Ib/hr) = C[BHOPM] *Vdscfm * A * (60 min/hr) * (1 Ib 17000

### grains) BHOPM Mass = 0.0000 9 C[BHOPM]= O.OOE+OO grains/dscf C[BHOPM]= O.OOE+OO Ib/dscf E[BHOPM]= 0.0000 Ib/MMBtu E[BHOPM]= 0.000 Ib/hr 

### % BHOPM 0.0



### 12

### Client Project No. James River Cogeneration Com Emission Source 3338 Test Run
Calculations (cont.) Unit NO.2 Two Page 4

12) Back HalfInorganic Particulate Analysis C[BHIPM] (grains/dscf) = (Inorganic Mass Wt)(g) * (1Nmstd) * 15.43(grains/g) C[BHIPM] (Ib/dscf) = C[BHIPMj (grains/dscf) * (1 Ib/7000

### grains) E[BHIPM] (lb/MMBtu) = C[BHIPM] (Ib/dscf) * Fd * (20.9/(20.9-02)) 

### E[BHIPM] (Ib/hr) = C[BHIPMj *Vdscfm * A * (60 min/hr) * (1 Ib 17000

### grains) BHIPM Mass = 0.0068 9 C[BHIPM]= 1.19E-03 grains/dscf C[BHIPMj= 1.70E-07 Ib/dscf E[BHIPMj= 0.0021 Ib/MMBtu E[BHIPM]= 1.614 Ib/hr % 

### BHIPM 48.6 13) Total Back HalfParticulate Matter C[TBHPM] (grains/dscf) = (C[BHOPMj (grains/dscf)) + (C[BHIPM] (grains/dscf)) C[TBHPM] (Ib/dscf) = (C[BHOPMj (Ib/dscf)) + (C[BHIPMj (Ib/dscf)) E[TBHPM] (lb/MMBtu) = (E[BHOPM] (lb/MMBtu)) + (E[BHIPM] (lb/MMBtu)) E[TBHPM] (Ib/hr) = C[TBHPM] *Vdscfm * A * (60 min/hr) * (1 Ib/7000 grains) Blank Mass = 0.0000 9 TBHPM Mass = 0.0068 9 C[TBHPM]= 1.19E-03 grains/dscf C[TBHPM]= 1.70E-07 Ib/dscf E[TBHPM]= 0.0021 Ib/MMBtu E[TBHPMj= 1.614 Ib/hr 

### % TBHPM 48.6 14) Total Particulate Matter

### < 10 Microns Emission Data C[TPM10] (grains/dscf) = (C[TSP] (grains/dscf)) + (C[TBHPM] (grains/dscf)) C[TPM10] (Ib/dscf) = (C[TSP] (Ib/dscf)) + (C[TBHPMj (Ib/dscf)) E[TPM10] (lb/MMBtu) = (E[TSP] (lb/MMBtu)) + (E[TBHPM] (lb/MMBtu)) E[TPM10] (Ib/hr) = C[TPM1 0] *Vdscfm * A * (60 min/hr) * (1 Ib 17000

### grains) C[TPM10] = 2.44E-03 grains/dscf C[TPM10] = 3.49E-07 Ib/dscf E[TPM10j = 0.0044 Ib/MMBtu E[TPM10j = 3.323 Ib/hr 15) Isokinecity, I.

% 

### 1= [1 00*Ts*(K3*Vlc+«(Vm*Y)/Tm)*(Pb+(dH/13.6))))] I

### (60*t*Ps*Vs*An) % 

### I = 99.98



### 13

### 3338-EPA5-202-R3 

## AirNova, Inc. EPA Methods 1,2,3A,4,5 and 202 (Flows, 02/C02, H20, Total Suspended Particulate and Back Half PM)
Client James RiverCogeneration Company Project No. 3338 Test Location Hopewell, Virginia Emission Source Unit NO.2 Fuel Coal Test Date 05/07/10 Test Run Three Time Period 1216-1426 Emission Data Datafrom: INPUT Vlc= 214.8 cc Vol. of H20 collected EPA4 INPUT Vm= 91.090 dcf Drygas meterreading EPA4 INPUT Pstatic= 0.55 in. H2O Static pressure EPA2 INPUT Pb= 29.98 in. Hg Barometric pressure Ps= 30.02 in. Hg Stackpressure EPA2 Pstd = 29.92 in. Hg EPA Standard pressure dP= 0.804 in. H20 ".5 Average sq.rt delta P EPA2 dH = 1.74 in. H2O Average draft gauge reading EPA4 Tm= 551.5 R Average metertemperature EPA4 Ts = 675.2 R Average stacktemperature EPA2 INPUT Tstd= 527.7 R Standard temperature INPUT y= 1.00 Metercalibration factor INPUT t= 120 min. Duration ofsampling time INPUT On = 0.250 in. Nozzle diameter INPUT An = 0.000341 sq. ft. Nozzle area INPUT Ds= 9.667 ft. Diameterofstack As= 73.39 sq. ft. Cross sectional area ofstack INPUT Cp= 0.84 Pitottube coefficient EPA2 Kp= 85.49 ft[(Ibllbmol)*(inHg)]".5}/[s*R*inH20] Pitottube constant K1 = 17.637 R/in.Hg constant K2 = 0.047070 cU.ftlml constant K3 = 0.0026688 in.Hg-cf/ml-R constant Molarvol air= 385.0 scf/lb-mol constant @ 

### 68 deg F Fd = 8842 scf/MMBtu Fuel Factor

EPA Method 3A Instrumental Data
INPUT EPA3 INPUT EPA3 [02] [C02] [N2] 5.49 %-dry 13.63 %-dry

80.88 %-dry



### 14 Oxygen concentration Carbon Dioxide concentration Nitrogen concentration

### Client Project No. James River Cogeneration Com Emission Source 3338 Test Run
Calculations Unit NO.2 Three Page 2

1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1* Y *Vm * (Pb + dH/13.6)/Tm Vmstd = 87.707 dscf 2.484 dscm 2) Volume ofwatervaporcollected atstandard conditions, Vw(std). Vw(std) = K2 *Vic Vw(std) = 10.111 scf 3) Decimal fraction ofmoisture byvolume in stackgas, Bws.
Bws =Vwstd/ (Vmstd+Vwstd) Bws = 0.1034 4) Molecularweightofthe stackgas on awet basis, Ms.

Ms = [«44*%C02) + (32*%02) + (28*%N2)) * (1-Bws)] + (18*Bws) Ms = 29.119 Ib/lbmole 5) Average stackgas velocity, Vs.

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)".5 Vs = 50.757 fps 6) Average actual stackgasvolumetricflowrate, Qa.
Qa =60 sec/min *Vs *As Qa = 223514.42 cfm 6329.93 cmm 7) Average stackgas dryvolumetricflowrate, Qstd.
Qstd = Qa * (TstdlTs) * (Ps/Pstd) * (1-Bws) Qstd = 157156.72 dscfm Qstd = 4450.68 dscmm



### 15

### Client Project No. James River Cogeneration Com Emission Source 3338 Test Run
Calculations (cont.) Unit No.2 Three Page 3

8) 

### Particulate MatterAnalytical Data

INPUT A 0.0032 

### 9 Filtersample netwt INPUT B 200 ml Front acetone wash vol. INPUT C 0.0029 

### 9 Frontacetone residuewt. INPUT 

### 0 200 ml Acetone blankvol. INPUT E 0.0000 

### 9 Acetone blank residue wt.
9) 

### Particulate sample mass calculations

H 

### I 

### J Front Half: Acetone blankadj. residue wt Adj. Acetone wash part.wt. Front halfsample wt. 0.0000 9 0.0029 

### 9 0.0061 9 E*(B/D) C-H A+ I 10) Total Suspended Particulate Matter Emission Data
C[TSP] (grains/dscf) = (Front HalfWt)(g) * 

### (1Nmstd) * 15.43(grains/g) C[TSP] 

### (Ib/dscf) = C[TSP] 

### (grains/dscf) * (1 

### Ib/7000grains) E[TSP] (lb/MMBtu) = C[TSP] 

### (Ib/dscf) * Fd * 

### (20.9/(20.9-02)) E[TSP] (Ib/hr) = C[TSP] *Vdscfm * A * (60 min/hr) * (1 Ib 

### I7000 graim C[TSP] = 1.07E-03 grains/dscf C[TSP] = 1.53E-07 

### Ib/dscf E[TSP] = 0.0018 Ib/MMBtu E[TSP] = 1.446 Ib/hr 11) Back HalfOrganic Particulate Analysis C[BHOPM] 

### (grains/dscf) = (Organic Mass Wt)(g) * 

### (1Nmstd) * 15.43(grains/g) C[BHOPM] (Ib/dscf) = C[BHOPM] (grains/dscf) * (1 

### Ib/7000grains) E[BHOPM] (Ib/MMBtu) = C[BHOPM] (Ib/dscf) * Fd * 

### (20.9/(20.9-02») E[BHOPM] (Ib/hr) = C[BHOPM] *Vdscfm * A * (60 min/hr) * (1 Ib 

### I7000 grains) BHOPM Mass = 0.0000 9 C[BHOPM]= O.OOE+OO grains/dscf C[BHOPM]= O.OOE+OO Ib/dscf E[BHOPM]= 0.0000 Ib/MMBtu E[BHOPM]= 0.000 Ib/hr 

### % BHOPM 0.0



### 16

### Client Project No. James River Cogeneration Com Emission Source 3338 Test Run
Calculations (cont.) Unit NO.2 Three Page 4

12) Back HalfInorganic Particulate Analysis C[BHIPM] (grains/dscf) = (Inorganic MassWt)(g) * (1Nmstd) 

### * 15.43(grains/g) C[BHIPM] (Ib/dscf) = C[BHIPM] (grains/dscf) * (1 Ib/7000

### grains) E[BHIPM] (lb/MMBtu) = C[BHIPM] (Ib/dscf) * Fd * (20.9/(20.9-02)) 

### E[BHIPM] (Ib/hr) = C[BHIPM] *Vdscfm * A * (60 min/hr) * (1 Ib 17000

### grains) BHIPM Mass = 0.0077 9 C[BHIPM]= 1.35E-03 grains/dscf C[BHIPM]= 1.94E-07 I

### bIdscf E[BHIPM]= 0.0023 Ib/MMBtu E[BHIPM]= 1.825 Ib/hr % 

### BHIPM 55.8 13)Total Back HalfParticulate Matter C[TBHPM] (grains/dscf) = (C[BHOPM] (grains/dscf)) + (C[BHIPM] (grains/dscf)) C[TBHPM] (Ib/dscf) = (C[BHOPM] (Ib/dscf)) + (C[BHIPM] (Ib/dscf)) E[TBHPM] (lb/MMBtu) = (E[BHOPM] (lb/MMBtu)) + (E[BHIPM] (lb/MMBtu)) E[TBHPM] (Ib/hr) = C[TBHPM] *Vdscfm * A * (60 min/hr) * (1 Ib 17000

### grains) Blank Mass = 0.0000 9 TBHPM Mass = 0.0077 9 C[TBHPM]= 1.35E-03 grains/dscf C[TBHPM]= 1.94E-07 Ib/dscf E[TBHPM]= 0.0023 Ib/MMBtu E[TBHPM]= 1.825 Ib/hr % 

### TBHPM 55.8 14) Total Particulate Matter

### < 10 Microns Emission Data C[TPM10] (grains/dscf) = (C[TSP] (grains/dscf)) + (C[TBHPM] (grains/dscf)) C[TPM10] (Ib/dscf) = (C[TSP] (Ib/dscf)) + (C[TBHPM] (Ib/dscf)) E[TPM10] (lb/MMBtu) = (E[TSP] (Ib/MMBtu)) + (E[TBHPM] (lb/MMBtu)) E[TPM10] (Ib/hr) = C[TPM10] *Vdscfm * A * (60 min/hr) * (1 Ib 17000

### grains) C[TPM10] = 2.43E-03 grains/dscf C[TPM10] = 3.47E-07 Ib/dscf E[TPM10] = 0.0042 Ib/MMBtu E[TPM10] = 3.270 Ib/hr 15) Isokinecity, I.



### % I = [1 00*Ts*(K3*Vlc+(((Vm*Y)/Tm)*(Pb+(dH/13.6))))] 

### I(60*t*Ps*Vs*An) % 

### I = 100.13

17

### 3338-Metals-R1

Client Project No. Test location Test Run Test Date TestTime 

### AirNova, inc. EPA Methods 1,2,3A,4, and 29 (Flows, 02/C02, H20, and Metals)


### James River Cogeneration Company 3338 Unit NO.2 One 05/07/10 0715-0930

Emission Data


### INPUT INPUT INPUT INPUT

INPUT INPUT
INPUT INPUT INPUT
INPUT

INPUT Vlc= Vm= Pstatic= Pb = Ps = 

### Pstd = dP

# = dH = 

### Tm= Ts

# = Tstd= On 

### = An 

### = y= 

### t= Os = As

# = Cp 

### = Kp 

### = K1 = K2 

### = K3= Fd = 231.4 cc Vol. ofH20 collected 86.296 dcf Drygas meter reading 0.55 in. H20 Staticpressure 29.98 in. Hg Barometricpressure 30.02 in. Hg Stack pressure 29.92 in. Hg EPAStandard pressure 0.8029 in. H20 ".5 Average sq.rtdelta P

1.730 in. H20 Average draftgauge reading 534.9 R Average metertemperature 668.1 R Average stacktemperature 527.7 R Standard temperature 0.246 in. Nozzle diameter 0.000330 sq. ft. Area ofnozzle orifice 1.01 Metercalibration factor

120 min. Duration ofsampling time 9.67 ft. Diameterofstack 73.3940 sq. ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lb/lbmol)*(inHg)]".5}/[s*R*inH20] Pitottube constant 17.637 Rlin.Hg constant 0.047070 cU.ft/ml constant 0.0026688 in.Hg-cf/ml-R constant 9100 scf/MMBtu Fuel Factor Instrumental Data


### INPUT
INPUT [02] [C02] [N2] 5.49 %-dry

13.65 %-dry

80.86 %-dry



### 18 Oxygen concentration
Carbon Dioxide concentration Nitrogen concentration

### Client Project No. James RiverCogeneration C'Test Location 3338 Test Run
Calculations Unit NO.2 One 

### Page 2

1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1*Y *Vm * (Pb +dH/13.6) /Tm Vmstd = 86.522 dscf 2.450 dsem 2) Volume ofwatervaporcollected atstandard conditions, Vw(std). Vw(std) = K2 *Vic Vw(std) = 10.892 sef 3) Decimal fraction ofmoisture byvolume in stackgas, Bws.

Bws =Vwstd / (Vmstd+Vwstd) Bws = 0.1118 4) Molecularweightofthe stackgas on awet basis, Ms.

Ms = [«44*%C02) + (32*%02) + (28*%N2)) * (1-Bws)] + (18*Bws) Ms = 29.017 Ib/Ibmole 5) Average stackgas velocity, Vs.

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)".5 Vs = 50.494 fps 6) Average actual stackgas volumetricflowrate, Qa.
Qa =60see/min *Vs *As Qa = 222358.86 cfm 6297.20 cmm 7) Average stackgas dryvolumetricflowrate, Qstd.
Qstd = Qa * (TstdlTs) * (Ps/Pstd) * (1-Bws) Qstd = 156512.97 dsefm 4432.45 dsemm



### 19Client Project No. James RiverCogeneration C'Test Location 3338 Test Run
Calculations (cont.) Unit No.2 One Page 3



### 11)Trace metal concentrations and emission rates C[M] = M[M] (ug) 

### 1Vmstd (dscm) C[M](Ib/dscf) = C[M](ug/dscm) * 1e-06g/ug* 2.205e-03Ib/g * 0.02832 dscm/dscf E[M](Ib/hr) = C[M] (ug/dscm) * (2.205E-09) (Ib/ug) * Qstd (dscmm) * 60 (min/hr) E[M](lb/MMBtu) = C[M](Ib/dscf) * Fd * (20.9/20.9-%02) C[M](@ corr. 02) = C[M] (ug/dscm) * [ (20.9-corrected %02) 

### 1(20.9-actual %02) ] Corrected 02 percentage is: 7.0 % Sample Cone. Conc.@corr. 02 Cone. Emission Rate Emission Rate Element Mass (ug) (ug/dscm) (ug/dscm) (IbIdscf) (Ib/hr) (Ib/MMBtu) Antimony 0.254 1.04E-01 9.35E-02 6.47E-12 6.08E-05 7.989E-08 Arsenic 1.963 8.01 E-01 7.23E-01 5.00E-11 4.70E-04 6.174E-07 Beryllium 0.043 1.75E-02 1.58E-02 1.10E-12 1.03E-05 1.352E-08 Cadmium 0.100 4.08E-02 3.68E-02 2.55E-12 2.39E-05 3.145E-08 

### < Chromium 4.320 1.76E+00 1.59E+00 1.10E-10 1.03E-03 1.359E-06

Cobalt 0.317 1.29E-01 1.17E-01 8.08E-12 7.59E-05 9.971E-08 Lead 1.807 7.37E-01 6.65E-01 4.61E-11 4.32E-04 5.684E-07 Manganese 20.240 8.26E+00 7.45E+00 5.16E-10 4.84E-03 6.366E-06 Nickel 2.419 9.87E-01 8.90E-01 6.16E-11 5.79E-04 7.609E-07 Selenium 0.318 1.30E-01 1.17E-01 8.10E-12 7.61E-05 1.000E-07 Mercury 0.500 2.04E-01 1.84E-01 1.27E-11 1.20E-04 1.573E-07 

### < 9) Isokinecity, I.

% 

### 1= [100*Ts*(K3*Vlc+(((Vm*Y)fTm)*(Pb+(dH/13.6»)))] 

### 1(60*t*Ps*Vs*An) % 

### 1= 102.44



### " < " symbol indicates values given arethe quantitative detection limit.

20

### 3338-Metals-R2 

### AirNova, Inc. EPA Methods 1,2,3A,4, and 29 (Flows, 02/C02, H20, and Metals)
Client James RiverCogeneration Company Project No. 3338 Test Location Unit NO.2 Test Run Two Test Date 05/07/10 TestTime 0952-1203

Emission Data
INPUT Vlc= 214.5 cc Vol. of H20 collected INPUT Vm= 85.239 dcf Drygas meter reading INPUT Pstatic= 0.55 in. H2O Staticpressure INPUT Pb = 30.02 in. Hg Barometricpressure Ps = 30.06 in. Hg Stack pressure Pstd = 29.92 in. Hg EPA Standard pressure dP = 0.8019 in. H20 ".5 Average sq.rt delta P dH = 1.716 in. H2O Average draftgauge reading Tm= 537.8 R Average metertemperature Ts = 671.8 R Average stacktemperature INPUT Tstd= 527.7 R Standard temperature INPUT On = 0.246 in. Nozzle diameter An = 0.000330 sq. ft. Area of nozzle orifice INPUT y= 1.01 Metercalibration factor INPUT t= 120 min. Duration ofsampling time INPUT Ds= 9.67 ft. Diameterofstack As= 73.3940 sq. ft. Cross sectional area ofstack INPUT Cp= 0.84 Pitottube coefficient Kp= 85.49 ft[(lbllbmol)*(inHg)]".5}/[s*R*inH20] Pitottube constant K1 = 17.637 R/in.Hg constant K2= 0.047070 cu.ftIml constant K3= 0.0026688 in.Hg-cf/ml-R constant INPUT Fd = 9154 scf/MMBtu Fuel Factor Instrumental Data
INPUT 

### [02] 5.65 %-dry Oxygen concentration
INPUT [CO2] 13.53 %-dry Carbon Dioxide concentration [N2] 80.82 %-dry Nitrogen concentration



### 21

### Client Project No. James RiverCogeneration C'Test Location 3338 Test Run
Calculations Unit NO.2 Two Page 2

1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1*Y *Vm * (Pb + dH/13.6) /Tm Vmstd = 85.109 dsef 2.410 dsem 2) Volume ofwatervaporcollected atstandard conditions, Vw(std). Vw(std) = K2 *Vic Vw(std) = 10.096 sef 3) Decimal fraction ofmoisture byvolume in stackgas, Bws.

Bws =Vwstd / (Vmstd+Vwstd) Bws = 0.1060 4) Molecularweightofthe stackgas on awet basis, Ms.
Ms = [«44*%C02) + (32*%02) + (28*%N2)) * (1-Bws)] + (18*Bws) Ms = 29.077 Ib/lbmole 5) Average stackgas velocity, Vs.
Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)".5 Vs = 50.482 fps 6) Average actual stackgas volumetricflowrate, Qa.
Qa =60 sec/min *Vs *As Qa = 222304.45 cfm 6295.66 emm 7) Average stackgas dryvolumetric flowrate, Qstd.
Qstd = Qa * (TstdlTs) * (Ps/Pstd) * (1-Bws) Qstd = 156838.78 dscfm 4441.67 dsemm



### 22Client Project No. James RiverCogeneration C'Test Location 3338 Test Run

Calculations (cont.) Unit NO.2 Two Page 3



### 11)Trace metal concentrations and emission rates
C[M] = M[M] (ug) 

### 1Vmstd (dscm) C[M](Ib/dscf) = C[M](ug/dscm) * 1e-06g/ug *2.205e-03Ib/g * 0.02832 dscm/dscf E[M](lb/hr) = C[M] (ug/dscm) * (2.205E-09) (Ib/ug) * Qstd (dscmm) * 60 (min/hr) E[M](Ib/MMBtu)

# =C[M](Ib/dscf) * Fd * (20.9/20.9-%02) C[M](@ corr. 02)

# =C[M] (ug/dscm) * [ (20.9-corrected %02) 

### 1(20.9-actual %02) ] Corrected 02 percentage is: 7.0 %
Sample Cone. Conc.@corr. 02 Cone. Emission Rate Emission Rate Element Mass (ug) (ug/dscm) (ug/dscm) (I

### bidscO (Ib/hr) (lb/MMBtu) Antimony 0.404 1.68E-01 1.53E-01 1.05E-11 9.85E-05 1.313E-07 Arsenic 2.110 8.75E-01 7.98E-01 5.47E-11 5.14E-04 6.858E-07 Beryllium 0.041 1.70E-02 1.55E-02 1.06E-12 1.00E-05 1.333E-08 Cadmium 0.156 6.47E-02 5.90E-02 4.04E-12 3.80E-05 5.070E-08 Chromium 4.550 1.89E+00 1.72E+00 1.18E-10 1.11 E-03 1.479E-06

Cobalt 0.327 1.36E-01 1.24E-01 8.47E-12 7.97E-05 1.063E-07 Lead 2.221 9.21 E-01 8.40E-01 5.75E-11 5.41E-04 7.219E-07 Manganese 2.014 8.36E-01 7.62E-01 5.22E-11 4.91E-04 6.546E-07 Nickel 3.399 1.41 E+OO 1.29E+00 8.81E-11 8.29E-04 1.105E-06 Selenium 0.386 1.60E-01 1.46E-01 1.00E-11 9.41E-05 1.255E-07 Mercury 0.500 2.07E-01 1.89E-01 1.30E-11 1.22E-04 1.625E-07 

### < 9) Isokinecity, 

### I.

% 

### 1= [100*Ts*(K3*Vlc+«(Vm*Y)/Tm)*(Pb+(dH/13.6»))] 

### 1(60*t*Ps*Vs*An) % 

### I

# = 100.56

II < II symbol indicates values given are the quantitative detection limit.

233338-Metals-R3

Client Project No. Test Location Test Run Test Date TestTime 

### AirNova, Inc. EPA Methods 1,2,3A,4, and 29 (Flows, 02/C02, H20, and Metals)

James River Cogeneration Company 3338 Unit NO.2 Three 

### 05/07/10 1216-1426

Emission Data

INPUT INPUT INPUT INPUT

INPUT INPUT

INPUT INPUT INPUT

INPUT

INPUT Vlc= Vm= Pstatic= Pb= Ps 

### = Pstd = dP

# = dH = Tm= Ts = Tstd= Dn = An = 

### y= t= Ds = As = Cp = Kp = K1 = K2

# = K3 = Fd = 220.2 cc Vol. of H20 collected 88.730 dcf Drygas meter reading 0.55 in. H20 Static pressure 29.98 in. Hg Barometric pressure 30.02 in. Hg Stack pressure 29.92 in. Hg EPA Standard pressure 0.8189 in. H20 1\.5 Average sq.rt delta P

1.789 in. H20 Average draft gauge reading 540.3 R Average metertemperature 674.5 R Average stacktemperature 527.7 R Standard temperature 0.246 in. Nozzle diameter 0.000330 sq. ft. Area ofnozzle orifice 1.01 Metercalibration factor

120 min. Duration ofsampling time 9.67 ft. Diameterofstack 73.3940 sq. ft. Cross sectional area ofstack 0.84 Pitottube coefficient 85.49 ft[(lb/lbmol)*(inHg)]ll.5}/[s*R*inH20] Pitottube constant 17.637 R/in.Hg constant 0.047070 cu.ftIml constant 0.0026688 in.Hg-cf/ml-R constant 8842 scf/MMBtu Fuel Factor Instrumental Data

INPUT

INPUT [02] [C02]
[N2] 5.49 %-dry

13.63 %-dry

80.88 %-dry



### 24 Oxygen concentration

Carbon Dioxide concentration
Nitrogen concentrationClient Project No. James RiverCogeneration 

### G Test Location 3338 Test Run
Calculations Unit No.2 Three Page 2

1) Volume ofgas sampled atstandard conditions, Vmstd.

Vmstd =K1 *Y *Vm * (Pb + dH/13.6)/Tm Vmstd = 88.090 dscf 2.495 dscm
2) Volume ofwatervaporcollected atstandard conditions, Vw(std). Vw(std) = K2 *Vic Vw(std) = 10.365 scf
3) Decimal fraction ofmoisture byvolume in stackgas, Bws.

Bws =Vwstd / (Vmstd+Vwstd) Bws = 0.1053


### 4) Molecularweightofthe stack gas on awetbasis, Ms.

Ms = [«44*%C02) + (32*%02) + (28*%N2» * (1-Bws)] + (18*Bws) Ms = 29.095 Ib/lbmole
5) Average stack gas velocity, Vs.

Vs = Kp * Cp * (dP) * (Ts/Ps*Ms)l'.5 Vs = 51.676 fps
6) Average actual stackgas volumetric flowrate, Qa.
Qa =60 sec/min *Vs *As Qa = 227560.76 cfm 6444.52 cmm 7) Average stackgas dryvolumetricflowrate, Qstd.
Qstd = Qa * (TstdlTs) * (Ps/Pstd) * (1-Bws) Qstd = 159818.35 dscfm 4526.06 dscmm

25Client Project No. James RiverCogeneration C'Test Location 3338 Test Run
Calculations (cont.) Unit NO.2 Three Page 3

11 )Trace metal concentrations and emission rates C[M] = M[M] (ug) 

### 1Vmstd (dscm) C[M](lb/dscf)

# =C[M](ug/dscm) * 1e-06g/ug* 2.205e-03Ib/g * 0.02832 dscm/dscf E[M](Ib/hr) = C[M] (ug/dscm) * (2.205E-09) (Ib/ug) * Qstd (dscmm) * 60 (min/hr) E[M](Ib/MMBtu) = C[M](Ib/dscf) * Fd * (20.9/20.9-%02) C[M](@ corr. 02)

# =C[M] (ug/dscm) * [ (20.9-corrected %02) 1(20.9-actual %02) ] Corrected 02 percentage is: 7.0 %

Element Antimony Arsenic Beryllium Cadmium Chromium

Cobalt Lead Manganese Nickel Selenium Mercury 9) Isokinecity, 

### I. Sample Mass (ug)

0.509 2.229 0.057 0.332 4.490 0.422 9.816 3.180 5.340 0.495 0.500 Cone. (ug/dscm) 2.04E-01 8.93E-01 2.28E-02 1.33E-01 1.80E+00 1.69E-01 3.93E+00 1.27E+00 2.14E+00 1.98E-01 2.00E-01 Conc.@corr. 02 (ug/dscm) 1.84E-01 8.06E-01 2.06E-02 1.20E-01 1.62E+00 1.53E-01 3.55E+00 1.15E+00 1.93E+00 1.79E-01 1.81 E-01 Cone. (Ib/dscf) 1.27E-11 5.58E-11 1.43E-12 8.31 E-12 1.12E-10 1.06E-11 2.46E-10 7.96E-11 1.34E-10 1.24E-11 1.25E-11 Emission Rate (I

### b/hr) 1.22E-04 5.35E-04 1.37E-05 7.97E-05 1.08E-03 1.01E-04 2.36E-03 7.63E-04 1.28E-03 1.19E-04 1.20E-04 Emission Rate (Ib/MMBtu) 1.528E-07 6.691E-07 1.711E-08 9.966E-08 1.348E-06 1.267E-07 2.947E-06 9.546E-07 1.603E-06 1.486E-07 1.501E-07 

### <

% 

### 1= [100*Ts*(K3*Vlc+«(Vm*Y)/Tm)*(Pb+(dH/13.6))))] 

### 1(60*t*Ps*Vs*An) % 

### 1= 102.14

.. <
.. symbol indicates values given are the quantitative detection limit.



### 26

### Appendix D
Calibration 

### Data

# CERTIFICATEOFANALYSIS 

# Grade ofProduct: EPAProtocol Airgas SpeciallyGases 600 UnionLanding Road Riverton, NJ08077 (856) 829-7878 Fax(856) 829-0571 www.airgas.com Part Number: Cylinder Number: Laboratory: Analysis Date: E03NI80E15A1087 XC032964B ASG

- Riverton

- NJ Aug 24, 2009 Reference Number: CylinderVolume: Cylinder Pressure: Valve Outlet: 82-124188656-1 150 CU.Ft. 2015 PSIG 590 

### Expiration Date: Aug 24, 2012

Certification performed in accordancewith "EPATraceability Protocol (Sept. 1997)" using the assayprocedures listed. Analytical Methodologydoes not require correction for analytical interferences. This cylinderhas a total analytical uncertainly as stated belowwith a confidence level of95%. There are no significant impuritieswhich affect the use ofthis calibration mixture. All concentrations are on avolume/volume basis unless otherwise noted. Do Not Use This Cylinderbelow 150 psig.i.e. 1 Mega Pascal 

### ANALYTICALRESULTS Component Requested Actual Protocol Total Relative Concentration Concentration Method Uncertainty
CARBON DIO>:,")E 7.500 % 7.450 % G1 +/- 1% NiSTTraceaiJ!e OXYGEN 12.50 % 12.47% G1 +/- 1%

### NISTTraceable NITROGEN Balance 

### CALIBRATIONSTANDARDS Type LotiO Cylinder No Concentration Expiration Date NTRM 01119418 CC'I4317 9.72% OXYGEN/NITROGEN Jul05,2010 NTRM 99061109 XC018416B 4.811 % CARBON DIOXIDE/NITROGEN May 15, 2012 

### ANALYTICALEQUIPMENT Instrument/Make/Model Analytical Principle Last MultipointCalibration



## - Aug 24;2009 Siemens UIlramal6E N1-NOS820 NDIR Siemens 5E BN805 Paramagnetic Aug OS, 2009 /;i

Triad Data Available Upon Request Notes:02 CONCENTRATION CORRECTED FOR CO2 INTERFERENCE.

. (1

### ~\ 

## iri L-

-

# CoJ\[JLl,;7<.J.,\t/ QA Approval

Page 1 of82·124188666·1



### 1

#5000

# CERTIFICATEOFANALYSIS 

# GradeofProduct: EPAProtocol AirgasSpeciallvGases 600Union Landing Road Riverton, NJ08077 (856) 829-7878 Fax(856)829-0571 www.airgas.com Part Number: Cylinder Number: Laboratory: Analysis Date: E03NI65E15A1094 CC5693 ASG

- 

### Riverton

- NJ Jun 23, 2008 Reference Number: CylinderVolume: Cylinder Pressure: 

### Valve Outlet: 82-124142222-1 154 Cu.Ft. 2015 PSIG 590 

### Expiration Date: Jun 23, 2011

Certification performedin accordancewith "EPATraceability Protocol (Sept. 1997)" using the assayprocedures listed. Analytical Methodologydoes not require correctionfor analytical interferences. This cylinderhas a total analytical uncertaintyas stated beiowwith a confidence level of95%. There are no significant impurities which affectthe use ofthis calibration mixture. All concentrations areon avolumelvolume basis unless otherwise noted. Do Not Use This Cylinderbelow 150 psig.i.e, 1 Mega Pascal 

### ANALYTICALRESULTS Component Requested AcMlI Protocol Total Rolative

, Concentration Concentration Method Uncertainty CARBON DIOXIDE 12.50 % 12.38 % 81**+/~** 1% NISTTraceable OXYGEN 22.00% 22.03% 81 +/- 1% N/STTraceable NITROGEN Balance 

### CALIBRATIONSTANDARDS Type Lot 10 CylinderNo Concentration Expiration Date
NTRM 03060212 XC024397B 22.60% OXYGEN/NITROGEN JulO1,2011 NTRM 04060437 XC034316B 19.84% CARBON DIOXIDE/NITROGEN May 15, 2012 

### ANALYTICALEQUIPMENT Instrument/Make/Model Analytical Principle Last MultipointCalibration Siemens Ultra

### mat6E N1-NO-0820 NDIR Jun 17,2008 Siemens 5E BN805 Paramagnetic Jun 05, 2008
Triad Data Avai/able Upon Request Notes:02 CONCENTRATION CORRECTED FOR C02 INTERFERENCE.



# C**ct~~/\~J** 

# QIlLOOe--- QA Approval

'Page 1 of82-124142222-1



### 2

#5000600Unionlanding Road Riverton, NJ08077 Airg8sSllecialtvGases 

# CERTIFICATEOFANALYSIS 

# G d 

# d 1(856) 829-7878 

# ra e Pro net: EPAProtoco Fax(856)829-0571 www.airgas.com 

### Part Number: Cylinder Number: Laboratory: Analysis Date: E02NI78E15A0346 XC0186948 ASG

- Riverton

- 

### NJ Apr23, 2007 

### Expiration Date: Apr23,2010 Reference Number: CylinderVolume: Cylinder Pressure: Valve 

### Outlet: 82-124093653-1 158 Cu.Ft. 2015 PSIG 580

Certification performed in accordance with "EPATraceability Protocol (Sept. 1997)" using the assayprocedures listed. Analytical Methodologydoes not require correction for analytical interferences. This cylinderhas a total analytical uncertaintyasstated belowwith a confidence level of95%. There are nosignificant impurities which affectthe use ofthis calibration mixture. All concentrations are on avolume/volume basis unless otherwise noted. Do Not UseThis Cylinderbelow 150 psig.i.e. 1 Mega Pascal 

## ANALYTICALImS'lJIiTS' Component 

# I CARBONDIOXIDE 

# I NITROGEN Requested Concentration 22.00% Balance 

### Actual Concentration 22.28 % Protocol Method G1 

### Total Relative Uncertainity

. . +1-1% NISTTraceable

III 7"1]'.,,·fJ

....**'t~,** Lot ID -01 Cylinder No 

### CALIBRATIONSTANDARDS Concentration Expiration Date

, NTRM 00060309 XC034300B 19.84% CARBONDIOXIDE/NITROGEN May 15, 2008 

# I ANALYTICALEQUIPMENT**~...;;I;,;n.;;s;,;tr",;,u;,;.m;,;.e;,;n;,;.t1;,;.M~a;,;k,;;,;el;,;.M;,;.o;;.d;,;.e;;.;I~~~=** ,..;;.A;,;.n;.;;a;,;;lyt::..;.;.ic;;.;a;,;I",;,P;,;r;,;in;,;c;;.ip:;;,l;,;e=== L_as_t_M_U_It..;iP:..O_i_n_t_C_a_li_b_ra_t_io_n

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... 6""C",O.,./C m O""2""""""",,,,,,,,,,,,,,,,,,,,,,,,",,,,,,,,,,,,,,,,""FT".,'''''R''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''' ''''''''''''''''''''''''''_A..;p''''r..,1,.;2,.,,2''''0''''07''''''''''''''''' 

# .1

Triad Data Available Upon Request 

### Notes:

# ~~~!U:C4,,~j QAApproval

Page 1 of82·124093653·1



### 3"INDUSTRY LEADER IN SPECIALTY GASES" 

## CertificateofAnalysis



# -EPAPROTOCOLGAS

- 

# ** Recertification

# ** N

Customer Date DeliveryReceipt Gas Standard FinalAnalysisDate ExpirationDate AirNova(Pennsauken, NJ) June03, 201'0 DR-29621 22.28% CarbonDioxide/Nitrogen-EPAPROTOCOL May28,2010 May28, 2013 Component BalanceGas CarbonDioxide Nitrogen AnalyticalData: DO 

## NOTUSEBELOW 150psig EPA Protocol, SectionNo. 2.2, ProceslnLeQ-I

.. '**~.'** --------- >-..:::.::: 

## ReportedCop.centrations 

## / CarbonDioxide: 21.7% 

# +/- 0.210/0 

# Nitrogen: Balance
ReferenceStandards: ".

# "------ SRM/GMIS: GMIS' CylinderNumber: CC-115915 Concentration: 19.44% C02/Nitrogen ExpirationDate: December31, 20I I


## CertificationInstrumentation Component: Carbon Dioxide Make/Model: Agilent7890A SerialNumber: CNI0736166 PrincipalofMeasurement: GC-TCD LastCalibration: May 21, 2010

CGA 580 

### 1950psig, 70°F CylinderOutlet: CylinderPressure: 

## CylinderData CylinderSerialNumber: C.k.C--:Q1862.48

.... CylinderVolume: 136Cubic Feet ExpirationDate: June03, 2013 

## AnalyticalUncertaintyandNISTTraceabilityare incompliancewithEPA-600/R-97/121.

Certifiedby: 

## MikeDuncan Original Data: 22.28% C02/Nitrogen(April 23, 2007)

-Airgas: Riverton, NJ 08077

"UNMATCHED EXCELLENCE" 

### 4 2564 PEMBERTON DRIVE ApOPKA, FLORIDA 32703 PHONE (407)-292-2990 FAX (407)-292-3313 WWW.L1QUIDTECHCORP.COM

# AirNova, Inc. PitotThermocouple Calibration data

Date: '11/17/09 Thermocouple 

### 1.0. : ANT5A
Probe Length: 5 Foot
Calibrator KA


### Ambient Temp.(F): 62
Barometric Pressure (" Hg): 30.10
Reference Thermometer: ASTM-2F

Reference Point



### 1 Source

Ice Water Ref. Thermometer Temp.(F)

34 Thermocouple Temp.(F)

33 Temperature 

# Dm. (%)

0.2%

2 Boiling Water 211 212 0.1%



## 3 Very Hot Oil Bath 353 351 0.2%



### 4 AmbientTemp. 62 63 0.2%

Average Temp. Change: 0.2%
Temperature Differencemustbe < 

### 1.5 %



### 5 

### Date: /

# 1/;7**/~**

## Type S Pitot Tube Dimensional Specification Verification Form • .: • 0 • '.. •

... ,,0 00 0

.

• O@@i)eO@le

.

•• <lIlII 

# A- N I

... EI • ell ell • EI

### ---=-..:.:..::..I...::.r-=--==-o==-v=-=a~,~=-n=-=--=c=-=--

# ..
_

.... <lI ell • 4il e
. "oeE)II€i1:@e c '

.° 00 $8 00 '

.. Go 0 • e : ..


## Pitot No. Calibrator Date
Verifythe following criteria and check all that apply
1) Face opening plane perpendicularto the transverse axis ?

__**L-_--~cc** .. 

## 2) Face-opening plane parallel to the logitudinal axis?

__ 3) Are LegsA 

## &B ofequallen·gth and are centerlines coincident?

__

Ifall the above criteria are met, a pitotcoeffecientof0.84 may be assigned to the respective pitottube. Ifone ofthe following criteria above is not met, the pitottube must be calibrated 

## in awind tunnel.



## Recommended Dimensions


## 4) Diameterofpitottubing? 

## (01):::: 

## J 

# 7.5in. PalDt=

__ 

## Pb/Dt= /; -'--- 

## 5) Dimensions of Pa

# =

__ in. 

## 6) Dimensions of Pb

# =

__ L_/

## in. ( 0.1875 < Dt < 0.375) (1.05 <Ot < 1.50) (1.05 < 

## Dt < 

## 1.50)

TRANSVERSE" 

# i

TUBE AXIS '

## .l.~._.**f-O::;f~G~** • Ftl\NES •**(~.**

"4lG!tt.M!(

,oo<rr
...OA< • f

# ·-0~~: I

# :'::~<Hf"''' llJt.(,uU 1;

........

### _--=-_.**~.y_.l~~.** 

# "".

1H:I0{fUl,.::l.( (hI

vI

# AirNova, Inc. PitotThermocouple Calibration data

Date:

.11/17/09 Thermocouple 1.0. : AN-50
Probe Length: 5 Foot
Calibrator KA


### Ambient Temp.(F): 62
Barometric Pressure (" Hg): 30.10
Reference Thermometer: ASTM-2F

Reference Point Source Ref. Thermometer Temp.(F) Thermocouple Temp.(F) Temperature 

# om. (%)



### 1 Ice Water 34 32 0.4%



## 2 Boiling Water 208 209 0.1%



### 3 Very 

### Hot Oil Bath 351 352 0.1%



### 4 Ambient Temp. 62 62 0.0%

Average Temp. Change: 0.2%
Temperature Difference mustbe < 

### 1.5 %

7 Date: fI

## /17/0"/

### Type S Pitot Tube Dimensional Specification Verification Form • o' 0 • • '11 •

.... se@.o. eeeeee
...

# ~':';:;:;;::'~ 

# AirNova, Inc

..

•• <i> '" (it @l 4!l

.... ----------""----------------------
-"GC!B ••••• o '

• 0 " e @l e ••.

• e tI •

• e e e •



### Pitot No. Calibrator Date 

## 11/1'

## j1rf
Verifythe following criteria and checkall thatapply
1) Face opening plane perpendicularto the transverse axis? _,........-_ ..
_

.. 2) Face-opening plane parallel to the logitudinal axis?

__ ----_.- 3) Are LegsA & B ofequal len'gth and are centerlines coincident? /--

Ifall the 

## abovecriteria are met, a pitot coeffecient of0.84 may be assigned to the respective pitottube. Ifone ofthe following criteria 

## above is not met, the pitottube must be calibrated in awind tunnel.

Recommended Dimensions



## 4) Diameterof pitottubing? (Dt) 

## = " ?o ?5in. (0.1875 < Dt < 0.375) 5) Dimensions of Pa 

## = 

# .'5/0 

### in

. 

## .c.'/ 6) Dimensions of Pb

# =**~./** U 

### in. PaiDt

# = 113?- (1.05 < Ot < 1.50) Pb/Dt

## = 

# /IJt, (1.05 < 

### Dt < 

### 1.50)

TRA/tSVERSE,' 

# i

TUBE AXIS •


# .l.r=g._.**~O::;'~G~** • PlAnES •**(~ A~O(f\.A!l;(**  ,o,,<t",""'" ,f

# '-':?~=-.G:: J

# ::~<H'M'" nl"£V:Cl h

......._--"-_.**-.~_.l~~.l** 

# ",,_**~0{t1.AJil(** (101

f

...

# AirNova, Inc. PitotThermocouple Calibrationdata

Date: '11/17/09 Thermocouple 1.0. : AN-5H
Probe Length: 5 Foot
Calibrator KA


### AmbientTemp.(F): 62
Barometric Pressure (" Hg): 30.10
Reference Thermometer: ASTM-2F

Reference Point Source Ref. Thermometer Temp.(F) Thermocouple Temp.(F) Temperature 

### Diff. (%)



### 1 IceWater 33 34 0.2%



## 2 Boiling Water 211 212 0.1%



### 3 Very Hot Oil Bath 342 342 0.0%

4 

### AmbientTemp. 62 62 0.0%
Average Temp. Change: 0.1%
Temperature Difference mustbe < 

### 1.5 %



### Signature:

9 

### Date:

# iL/ 1 

### 7/0 <1

## Type S Pitot Tube Dimensional Specification Verification Form • .: 9 e '" '0 •

•
.. lit " e e «< ••

• • @ e E'9 €!!I ID e G ". oa@@I.0\lfle@<lI. 

# A- N II'

• 0 l) l!il. 

### G • 4!H\' G

# .--:...--:..:...:.:.I..=r--=-=--=O=-="=-a.-:......"..z...,**~i-=n:....::.....;C=·**:....:"'=--

_ ··eo.l!ilOO

.. •·**··Ge@~@@a··**

... C& e @ • e III •

G •
.. •


# . "

# . "


# .
Pitot No. Calibrator Date 

## H(17/(1
Verifythe following criteria and checkall that apply**(,.,..,.----~-** 

## 1) Face opening plane perpendicularto the transverse axis?

_**c'~'** 

### 2) 

## Face-opening plane parallel to the logitudinal axis?

__c_' 

## 3) Are Legs A & 

## B ofequallen"gth and are centerlines coincident?

__ ----_--'

Ifall the above criteria are met, a pitot coeffecient of0.84 may be assigned to the respective pitottube. Ifone ofthe following criteria above is not met, the pitottube must be calibrated in awind tunnel.

Recommended Dimensions


## 4) Diameterofpitottubing? 

## (Ot)

# = .-:5

## 7J-in. (0.1875 < Ot < 0.375) 5) 

## Dimensions of Pa

# = .f;"C(:' 

## in.

/' 

## " 6) Dimensions of Pb

# = I;;'" (/ 

## in. PaiDt

# = jl

# JJ (1.05 < Ot < 1.50) Pb/Ot

# = I, 

# iJ (1.05 < 

## Ot < 

## 1.50)

## rRA~SVERSE" 

# i
WOE AXIS , 

# .l.E9G9-_.**I-O::;f~G**

# -I

. flAKES • (,j'**A$f~'t,..1.tf(**

# 'Q.<n.~OAl ,f

# '-'0~:=E 

# I**:f~<.<,**

# ...",

ltnt:A.tdb --:---'--.**-.;y_.l~~.** 

# . ....

1Ml0{ft.A.4( (hI

## AirNova, Inc. Dry gas meter& orifice Calibration data and calculations
Meter Box#: 

### Checked with Pump #: 

### Date: Calibrator: 

### 5 5 '2/9/10



### KA

delta H = 0.5 in. H2O Pb = 29.97 in. Hg Time = 19.0 min. Std Test Meter Data DryTest Meter Data I\H@i I\Yi
IVw= 487.046 IVd = 623.455 1.623 1.014 FVw= 494.825 FVd = 631.166 TVw= 7.779 TVd 7.711 tw = 58 ltd = 63 Ftd= 60 Avg. td = 61.5

--------------------- 

### delta H = 1.0 in. H2O Pb = 29.97 in. Hg Time = 23.0 min. Std Test MeterData DryTest Meter Data I\H@i I\Yi
IVw= 473.964 IVd = 610.560 1.679 1.019 FVw= 487.046 FVd = 623.455 TVw= 13.082 TVd 12.895 tw = 57 ltd = 62 Ftd= 59 Avg. td = 60.5



## --------------------- delta H = 1.5 in. H2O Pb = 29.97 in. Hg Time = 15.0 min. Std Test Meter Data DryTest Meter Data I\H@i I\Yi
IVw= 463.755 IVd = 600.565 1.754 1.023 FVw= 473.964 FVd = 610.564 TVw= 10.209 TVd 9.999 tw = 55 ltd = 60 Ftd= 56 Avg. td = 58 Pg 1 of2



### 11

### Date: '2/9/10 

## AirNovCl, Inc. Calibration Data MB#: 

### 5

delta H = Pb

# = Time = 2.0 in. H20 29.97 in. Hg

13.0 min.
Std Test Meter Data DryTest Meter Data
IVw= 453.446 IVd = 590.535 FVw= 463.755 FVd = 600.565 TVw= 10,309 TVd 10.030 tw = 54 ltd = 57 Ftd= 53 Avg. td = 55 1.726 1,025

delta 

### H = Pb 

## = Time = 3.0 in. H20 29.97 in. Hg

12.0 min.
Std Test Meter Data DryTest Meter Data
IVw= 441.774 IVd = 579.275 FVw= 453.446 FVd = 590.535 TVw= 11.672 TVd 11.260 tw = 53 ltd = 54 Ftd= 50 Avg. td = 52 1.724 1.027

delta 

### H = Pb

# = Time = 4.0 in. H20 29.97 in. Hg 8.0 min.
Std Test Meter Data DryTest Meter Data
IVw= FVw= TVw= tw

# = 432.758 441.774 9.016 51 IVd = FVd = TVd ltd = Ftd= Avg. td

# = 570.645 579.275 8.630 50 49 49.5 1.707 1.032



### Signature: 

## Avg.J\H@=: 

## 1.70

12 

## Avg. Y =: 1.02

Date:

# 2/7~ Pg. 2 of2

## AirNova, Inc. Calibration data and calculations Meter Box Temperature Sensors

Meter Box#: Date: Calibrator: Ambient Temp. (F): Barometric Pressure ("Hg):

Reference Thermometer:


### Dry Gas MeterThermocouple -INLET 

### 5 '01/05/09 KA 

### 48 30.00 ASTM-2F

Reference Point

AmbientTemp. HotWater(104-122F) Ref. Thermometer Thermocouple Temp. (F) Temp. (F) Diff.


### 48 48 

### 0 N/A N/A 

### 0 Dry Gas MeterThermocouple

- OUTLET

Reference Point

Ambient Temp. HotWater (104-122F) Ref. Thermometer Thermocouple Temp. (F) Temp. (F) Diff.


### 48 48 0 N/A N/A 0
note: tolerance for inlet and outlet 

### = +/- 5.4 F 

### Thermocouple connector/LED readout:

Ref. Thermometer Thermocouple Temp. (F) Temp. (F) Diff.


### 1 Stack 48 48 

### 0 2 Probe 48 48 

### 0 3 Filter 48 48 0 4 Dryer 48 48 0 5Aux 48 48 0
note: tolerance

# =+/- 2 F

13 

## Date:

## AirNova, Inc. Dry gas meter

## & orifice Calibration data and calculations
Meter Box#: Checked with Pump#: Date: Calibrator: 10 10 '2/2/10

KA



### delta H = 0.5 in. H2O Pb = 30.05 in. Hg Time = 19.0 min. Std Test Meter Data DryTest Meter Data I\H@i I\Yi
IVw= 228.386 IVd = 582.395 1.766 0.992 FVw= 235.845 FVd = 589.975 TVw= 7.459 TVd 7.580 tw = 61 ltd = 66 Ftd= 66 Avg. td = 66



## --------------------- delta H = 1.0 in. H2O Pb = 30.05 in. Hg Time = 14.0 min. Std Test Meter Data DryTest Meter Data I\H@i I\Yi
IVw= 220.786 IVd = 574.700 1.847 0.995 FVw= 228.386 FVd = 582.395 TVw= 7.600 TVd 7.695 tw= 61 ltd = 66 Ftd= 66 Avg. td = 66

--------------------- 

### delta H = 1.5 in. H2O Pb 

### = 30.05 in. Hg Time = 11.0 min.
Std Test Meter Data DryTest Meter Data I\H@i I\Yi
IVw= 213.258 IVd = 567.100 1.743 0.996 FVw= 220.786 FVd = 574.700 TVw= 7.528 TVd 7.600 tw = 61 ltd = 66 Ftd= 66 Avg. td = 66 Pg. 1 of2



### 14

### Date: '2/2/10 

## AirNovCi, Inc. Calibration Data MB#: 10

delta H = Pb

# = Time = 2.0 in. H20 30.05 in. Hg

11.0 min.
Std Test Meter Data DryTest Meter Data
IVw= 204.824 IVd= 558.576 FVw= 213.258 FVd = 567.100 TVw= 8.434 TVd 8.524 tw= 61 ltd = 66 Ftd= 66 

### Avg. td = 66 1.852 0.994

delta 

### H = Pb

# = Time = 3.0 in. H20 30.05 in. Hg

10.0 min.
Std Test Meter Data DryTest Meter Data
IVw= 195.491 IVd = 549.210 FVw= 204.824 FVd = 558.576 TVw= 9.333 TVd 9.366 tw = 61 ltd = 65 Ftd= 65 

### Avg. td = 65 1.878 0.997

delta H = Pb

# = Time = 4.0 in. H20 30.05 in. Hg

10.0 min.
Std Test Meter Data DryTest Meter Data
IVw= 184.630 IVd = 538.324 FVw= 195.491 FVd = 549.210 TVw= 10.861 TVd 10.886 tw = 61 ltd = 63 Ftd= 63 

### Avg. td = 63**---------------~-----** 

## Avg.AH@=: 

## 1.82 

# 1/ 

# d 

# aUSignature: 

# /t.. J4IAU/.:L



### 15 1.857 0.992



## Avg. 

# Y=: 0.99

Date:

# .2/2-/10
Pg 2 of2

## AirNova, Inc. Calibration data and calculations Meter Box Temperature Sensors

Meter Box#: Date: Calibrator: Ambient Temp. (F): Barometric Pressure ("Hg):

Reference Thermometer:



### Dry Gas MeterThermocouple

A 

### INLET 

## 10 '2/2/10 KA 

## 73 30.05 ASTM-2F

Reference Point

AmbientTemp. HotWater (104-122F) Ref. Thermometer Thermocouple Temp. (F) Temp. (F) Diff. 

## 73 72 1 101 101 0 Dry Gas MeterThermocouple

A 

### OUTLET

Reference Point

Ambient Temp. HotWater (104-122F) Ref. Thermometer Thermocouple Temp. (F) Temp. (F) Diff. 

## N/A N/A 0 

## N/A N/A 0
note: tolerance for inlet and outlet

# =+/- 5.4 F 

### Thermocouple connector/LED readout:

Ref. Thermometer Temp. (F) Thermocouple Temp. (F) 

### 1 Stack 2 Probe 

### 3 Filter 4 Dryer 5Aux 

## 73 73 73 73 73 74 

## 73 73 73 73 1 

# o 

# o o o
note: tolerance

# =+/- 2 F

16