### Oxbow Calcining LLC



# MATERIAL SAFETY DATA SHEET

SECTION I

– IDENTIFICATION

EMERGENCY PHONE

281

– 775

- 4741 PRODUCT NAME

Calcined Petroleum Coke CAS NO.



### 64743

– 05

- 01

COMPANY NAME and ADDRESS

Oxbow Calcining LLC

1450 Lake Robbins Dr.

Suite 320

The Woodlands, TX 77380 TRADE NAME AND SYNONYMS

Calcined Petroleum Coke

CHEMICAL NAME AND SYNONYMS

Calcined Petroleum Coke

QUESTIONS CONCERNING THE MSDS

CAN BE DIRECTED TO:

Corporate Technical Manager

Telephone 281

– 775

- 4741 EFFECTIVE

10/20/10

SUPERSEDES

11/05/07 NFPA Rating

0 Least, 1 Slight, 2 Moderate, 3 High, 4 Extreme

Health: 0 Flammability: 1 Reactivity: 0



### SECTION II

– HEALTH HAZARD DATA

MATERIAL INFORMATION

Calcined petroleum coke is not conside red to be hazardous as defined by OSHA’s Hazard Communication Standard 29 CFR

1910.1200. Calcined petroleum coke is considered to be an inert material.

Calcined Petroleum Coke CAS NO. 64743

– 05

- 01

EXPOSURE LIMITS

OSHA: PEL = 15 mg/m 3 as total d ust; 5 mg/m 3 as respirable fraction

ACGIH: PEL = 10 mg/m 3 as total dust; 3 mg/m 3 as respirable fraction

SYMPTOMS OF OVEREXPOSURE

Route(s) of Entry: Inhalation, skin, and eye contact.

This product is nontoxic. The “nuisance dust” exposure values that are listed apply to any inert substance capable of producing

airborne particulates. Excessive concentrations of calcined petroleum coke may reduce visibility, cause unpleasant deposits in the

eye, ears, and nasal passages, or irritate the skin or mucous membranes by mechanical means. However, normal workplace

exposure has not been determined to cause a significant health effect. Calcined petroleum coke, as with many petroleum produ cts,

may cause minor skin, eye, or lung irritation, but good hygienic pra ctices can minimize these effects.

See Section VIII for additional health data.

Is product listed as Carcinogen or Potential Carcinogen by: NTP? No IARC? No OSHA? No

RECOMMENDED FIRST AID TREATMENT

Inhalation: Remove to fresh air. If bre athing has stopped, administer artificial respiration and supply oxygen. If problems persist,

seek medical attention.

Eye Contact: In case of contact, immediately flush eyes with plenty of water until irritation subsides. If irritation persis ts, seek

med ical attention.

Skin Contact: Normal skin contact is not known to cause a significant health effect. Particles should be periodically washed off of

skin with soap and water.

Ingestion: If swallowed, do not induce vomiting. Immediately give water. Never give anything by mouth to an unconscious

person. If symptoms develop, seek medical attention.

### MSDS

– Calcined Petroleum Coke



## SECTION III

– PHYSICAL DATA

BOILING POINT ( O F)

Solid BULK DENSITY (LB/FT 3 )

50 to 55

MELTING POINT ( o F)

Nonmelting solid VAPOR DENSITY (Air = 1)

Not A pplicable

SOLUBILITY IN WATER

Not Soluble ODOR

None

PERCENT VOLATILE BY VOLUME

0.3 Max APPEARANCE

Dark gray to black



## SECTION IV

– FIRE AND EXPLOSION HAZARD DATA

FLASH POINT (Method used)

No Data Available AUTO IGNITION TEMPERATURE

See Unusual F ire and Explosion Hazards

Section below FLAMMABLE LIMITS % BY VOLUME

LEL UEL

No Data Available No Data Available

EXTINGUISHING MEDIA

Water Fog, Dry Chemical, Foam, or Carbon Dioxide

SPECIAL FIRE FIGHTING PROCEDURES Most reported coke fire s have occurred when produced calcined coke is

inadequately cooled and stored in a manner that allows the movement of air through the coke bed. Coke should be well quenche d

or cooled before it is stored in a pile out of doors or placed in silos or bins. Storage should be arranged to prevent movement of air

through the coke. Should a fire occur, its locations and extent should be determined as quickly as possible. The best proce dure is

to dig out and remove the coke in the heated zone. The hot coke shou ld be drenched with water as it is exposed. Because of the

possibility of steam explosion, great care should be used introducing water into confined storage such as a silo. Whenever

possible, bulk material in silos should be removed and material drenched in an open area. Products of combustion may contain

carbon monoxide, carbon dioxide and sulfur dioxide. Do not enter permitted confined space or enclosed area without proper PP E.

There is no dust explosion hazard from calcined petroleum coke.

UNUSUAL F IRE AND EXPLOSION HAZARDS

May burn if exposed to temperatures greater 1290 o F (700 o C).



## SECTION V

– REACTIVITY DATA

STABILITY HAZARDOUS POLYMERIZATION

Unstable May Occur

Stable X Will Not Occur X

INCOMPATIBILITY (Materials to avoid)

S trong oxidizing acids; other strong oxidants

HAZARDOUS DECOMPOSITIONS PRODUCTS

CO, CO 2 , SO 2

CONDITIONS TO AVOID

Extreme heat and open flames. May burn if exposed to temperatures above 1290 o F (700 o C).

### MSDS

– Calcined Petroleum Coke



## SECTION VI

– SPILL OR LEAK PROCEDURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED

Material is not toxic and can be picked up by sweeping, shoveling, or vacuuming. Provisions should be made to prevent washin g,

draining, or directing material to storm or sanitary sewers.

WASTE DISPOSAL METHOD

All Fe deral, State, and Local regulations regarding health and pollution must be followed for disposal of calcined petroleum coke.



## SECTION VII

– SPECIAL PROTECTION INFORMATION

RESPIRATORY PROTECTION (Specify type)

Select appropriate NIOSH

- approved protection where necessary to maintain exposures below the acceptable limits in the Health

Hazard Section. Proper respiratory selection should be determined by adequately trained personnel and based on the

contaminant(s), the degree of potential exposure and publish ed respirator protection factors.

VENTILATION

Dust should be controlled at point of operation.

PROTECTIVE GLOVES

None

EYE PROTECTION

None required. Recommend using dust goggles in areas of high dust concentrations.

OTHER PROTECTIVE EQUIPMENT

None



## SECTION VIII

– ADDITIONAL HEALTH DATA

Petroleum coke was found to be non

- carcinogenic in mice in chronic skin painting studies with coke dust. Petroleum coke was

found not to be carcinogenic in monkeys and rats in a two

- year inhalation study at concent rations up to 30 mg/m 3 . Chronic

inflammatory changes similar to those produced by non

- specific respiratory irritants were observed in some rats at the highest

exposure level.

Petroleum coke was found not to be mutagenic in a rat in vivo Bone Marrow Cytog enetic test, a mouse Lymphoma assay, and an

Ames Mutagenicity assay.



## SECTION IX

– SHIPPING INFORMATION

DEPARTMENT OF TRANSPORATION (DOT)

Proper Shipping Name : Regulated by water mode only, when temperature exceeds 130 o F, Petroleum coke, calcined.

Haz ard Class : ORM ( other regulated material )

– C

Dot Label(s) : None

DOT Placard : None

INTERNATIONAL MARITIME ORGANIZATION (IMO)

Proper Shipping Name : Petroleum coke, calcined. Not regulated by IMO

Special Information : Must not be loaded in cargo vessels when temperatures exceed 225 o F. (46 CFR 148.04

- 17)

### MSDS

– Calcined Petroleum Coke

The information and recommendations contained herein are, to the best of Oxbow Carbon and Minerals ( OC M ) knowledge and belief,

accurate and reliable as of the date issued. OCM does not warrant or guarantee their accuracy or reliability, and OCM shall not be liable for

any loss or damage arising out of the use thereof.

The information and recommendations a re offered for the user’s consideration and examination, and it is the user’s responsibility to satisfy

itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure

proper health, safety and other necessary information is included on the container.