each attached sheet as Fonn 26R, reference the item number and identify the date 

prepared. The date on attached sheets needs to match the date noted below. 

c. Appearance 

Company Mailing 

Solid {EPA Method 9095) 

Gas (ambient +<•rn,....,..., •• , 

Zip+4 

15701 

Color opaque white/orange . 

Number of Solid or Uquid Phases of Separation 

Ext 

No 

Describe each phase of separation.~~---------------; 

-1 -
b. 

Solid waste permit number(s) for 

PA0091472 

Address Line 1 

Address Line 1 

Address City State ZIP 

Municipality 

c. Facility Contact Name 

Title 

d. 

a. 

Phone 

Name 

Address Line 1 

Address Line 1 

Address City State ZIP 

Municipality 

c. Facility Contact Name 

Title 

Phone 

County Indiana 

(check one) 

to processing or disposal facility in the previous year. D cuyd 0 gal .0 lb 0 ton 

number. 

b. 

D gal 0 ton (check one) 

-2 -
Form Submitted: D Form26R 

D other (specify) ---------------

Date Submitted: 

D I certify the information required In Section B-2, Chemical Analysis was supplied to the Department for the year 

__ and has not changed. 

Form Submitted: D Form 26R 

D Other (specify) 

Date Submitted: 

D I certify the Information required in Section 8-3, Process Description and Schematic, was supplied to the Department for the year_ and has not changed. 

Form Submitted: D Form 26R 

D Other (specify) 

Date Submitted: 

Name of Responsible Official Shale 

Bernhardt Kissel 

Signature Date 2-28-11 

- 3-
Form 26R: Section 81 e 

GENERATOR KNOWLEDGE 

All Form 26R Waste Forms have been compiled, and future testing has been 

scheduled, to obtain samples of each waste stream on a PAD by PAD basis. Sample 

analyses will be conducted every 5 years for each waste stream unless the process that 

generates any particular waste stream is substantially altered. 

Attached analytical results for this waste stream have been obtained from a similar 

waste stream producing waste from the same geologic formation as this 26R Report. 

Additionally, the mud mixtures, chemical forml)lations and drilling process utilized at this 

well PAD are substantially the same as those utilized at the well where the attached 

waste analyticals were generated. 
Brine fluids are composited within the storage production tank or tank battery at each 

well site where gas production is occurring. Each automatic or manual ejection of 

formation fluids is deposited into the tank(s) and added to the previously ejected and 

stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP 

permitted waste disposal facilities on different schedules determined by individual well 

characteristics. Grab samples of the composited fluids were obtained at the 

represented well pads directly from the storage tank drain ports. All drain ports had 

small "built in" containment and storage "buckets" capable of retaining small amounts of 

lost fluids. 

Samples were obtained with bottle sets prepared at the laboratory which contained 

appropriate preservatives, as necessary, depending on the specific test run requested. 

All chain of custody and handling/holding time requirements were met. In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot 

portions at the laboratory. -

Flowback samples were composited to the extent possible during the flowback process 

primarily during times where safety issues did not override sample collection 

requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers 

and smaller aliquot portions at the laboratory or on the well location upon completion of 

the composite sampling process. Samples were distributed into bottle sets prepared at 

the laboratory which contained appropriate preservatives, as necessary, depending on 

the specific test run requested. All chain of custody and handling/holding time 

requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and 

combined into a composite sample for analyses at the laboratory. On several wells, 

cuttings from the vertical portion of the well bore were segregated from cuttings from 

the target Marcellus Formation and separate testing was completed on both sample 

composites. In some earlier cases during the utilization of open pits, composite 

samples were obtained from inactive drill pits. Safety concerns usually limited the 

randomness of the composite sample and composite grid sample positions were varied 

to the extent possible. 

Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned 

and reused from well to well. 
Fonn 26R: Section 83a 

WASTE GENERATION PROCESS 

Pit Water "Drill Fluids" 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and fonnation fluids. These fluids are brought to 

the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are 

mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

Flowback: "Fracing Fluid" 

Flowback is produced from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the 

fonnation fractures. 

Production Fluid "Brine" 

During the production of natural gas, fonnation pressures bring remnant frac fluids, 

during the initial production phase, and fonnation fluids to the surface along with 

produced gas. 
- COUNTYB 

ote: . Process producing waste: Gas well produced 

fluids (brines) are typically produced in 

conjuction with natural gas. These fluids 

are brought to the surface utilizing either 

· mechanical or physical lift procedur_es. 

Well I.·D.#.(various) 

'\\/ 

-0.- COUNTY A 

I 

I 

I 

I 

I 

I 

....... , ........ 

I 

I 

I 

I 

/ 

/ 

/ 

Well I. D.# (various) 

\ I .:-o ..... /II' 

/ 

/ 

/ 

/ 

/ 

Mobile Tank Truck 

------Landfill orTre.u.+~U\+ 'P\W\t 

(.) 

w 

~ :r: 

0 

(/) 

z 

0 

~ 1-

~ 

0 

a.. 

(/') 

z 

~ 1-

~illf 

~~~- .... ~ ~ ~ 

ill§ il~ 

~~ ~ 

I

a i _ lC ~ Cl -

~] ~~ 

~ ~~ ~ 15J 

~I ~~ 

I 

I ~ 

~ 

~ 
RICK BONAZZA RESOURCE MANAGEMENT SERVICES 

65 FENTON ROAD 

INDIANA, P A 15701 

RE: 26R Analysis 

Dear RICK BONAZZA: OrderNo.: 01101912·. 

Geochemical Testing received 1 sample(s) on 1128/2011 for the analyses presented in the 

following report. 

There were no problems with the analyses and all QC data met NELAC, EPA, and laboratory 

specifications except where noted in the Case Narrative or Laboratory Results. 

If you have any questions regarding these tests results, please feel free to call. 

Sincerely, 

Timothy W. Bergstresser 

Director of Technical Services 
No problems were encountered during analysis of this workorder, except if noted in this report. 

The ethylene gycol analysis was subcontracted to Free Col Labs. A copy of the subcontractor's laboratory report is enclo~ed with this Analytical Report. 

The radiological analysis was subcontracted to Pace Analytical. A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. 

Legend: 

J - Indicates an estimated value. 

U - The analyte was not detected at or above the listed 

concentration, which is below the laboratory quantitation limit. 

B - Analyte detected in the associated Method Blank 

Q- Qualifier QL -Quantitation Limit DF- Dilution Factor 

R- RPD outside accepted recovery limits 

E- Value above quantitation range 

** -Value exceeds Action Limit 

H - Method Hold Time Exceeded 

MCL - Contaminant Limit 

I.D. 56-00306 PA DEP 
Matrix: AQUEOUS 

Analyses Result 

INORGANIC NON-METALS 

Acidity to pH 8.2 -38 

INORGANIC NON-METALS 

Alkalinity to pH 4.5 150 

PHYSICAL TESTS 

Specific Conductance 111000 

PH BY SM 4500 H+B 

Lab pH 6.52 

INORGANIC NON-METALS 

Total dissolved solids 97500 

PHYSICAL TESTS 

Total suspended solids 545 

INDICATOR ORGANIC PARAMETERS 

BOD 5-day 1350 

Finish Datemme 212/2011 18:10 

REACTIVE CYANIDE 

Reactive cyanide 

INDICATOR ORGANIC PARAMETERS 

Chemical Oxygen Demand 

INORGANIC NON-METALS 

Bromide 

Chloride 

Sulfate 

INORGANIC NON-METALS 

MBAS 

INORGANIC NON-METALS 

Ammonia Nitrogen - Distilled 

INORGANIC NON-METALS 

Nitrate - Nitrite 

INDICATOR ORGANIC PARAMETERS 

Phenolics 

REACTIVE SULFIDE 

Reactive sulfide 

INORGANIC NON-METALS 

< 0.25 

5800 

461 

57100 

< 100 

< 0.25 

69.1 

0.53 

< 100 

0.50 

Received Date: 1/28/2011 7:08:50 PM 

QL Q Units 

SM·2310B(4A) 

0 mg/LCaC03 

SM 18 23208 

5 mg/LCaC03 

EPA 120.1 

SM4500-H+B 

0 su 

SM2540C 

100 mgll 

SM 2540D 

25 mg/L 

SM 5210 B 

300 mgll 

0 mg/L 

SW846 CH.7 

0.25 mg/Kg 

HACH 8000 

50 mgll 

EPA300.0 

10.0 mg/L 

50 mgll 

100 mgll 

SM 5540C 

0.25 H mg/L as LAS 

EPA 350.1 

. 5.00 mgll as N 

EPA 353.2 

0.05 mgll as N 

EPA 420.1 

100 IJ9/L 

SW 846 CH.7 

0.25 mg/Kg 

EPA 351.2 

DF Date Analyzed 

Analyst: LNW 

21412011 9:44:00 AM 

Analyst: LNW 

213/2011 4:50:00 PM 

Analyst: LNW 

2/312011 4:50:00 PM 

Analyst: LNW 

2/312011 4:50:00 PM 

Analyst: . KLS 

5 113112011 7:10:00 AM 

Analyst: KLS 

5 113112011 7:17:04 AM 

300 

300 

0.99 

5 

50 

50 

50 

5 

50 

0.99 

Analyst: SAG 

112812011 6:50:00 PM 

1128/2011 6:50:00 PM 

Analyst: SAG 

219/2011 4:58:00 _PM 

Analyst: MGV 

21112011 

Analyst: CAS 

1131/2011 2:51:00 PM 

1/31/2011 2:51:00 PM 

1/31120112:51:00PM . 

Analyst: CAS 

21212011 2:30:00 PM 

Analyst: SLY 

2/1012011 12:51:01 PM 

Analyst: SLY 

2/1/2011 10:14:21 AM 

Analyst: KMW 

2/412011 1:05:00 PM 

Analyst: SLY 

2/312011 2:50:00 PM 

Analyst: SLY 

LD. 56-00306 PA DEP 
Matrix: AQUEOUS 

Analyses 

INORGANIC NON-METALS 

Total Kjeldahl Nitrogen 

INORGANIC METALS 

Iron, dissolved 

INORGANIC METALS 

Mercury 

TCLP METALS 

Mercury 

TCLP METALS 

Arsenic 

Barium 

Cadmium 

Chromium 

Lead 

Selenium 

Silver 

INORGANIC METALS 

Aluminum 

Arsenic 

Barium 

Beryllium 

Boron 

Cadmium 

Calcium 

Chromium 

Cobalt 

Copper 

Iron 

Lead 

Lithium 

Magnesium 

Manganese 

Molybdenum 

Nickel 

Selenium 

Silver 

Sodium 

Strontium 

Zinc 

Result 

61.4 

10.5 

<0.20 

<0.0002 

<0.020 

3190 

<0.002 

< 0.010 

<0.020 

<0.020 

< 0.005 

< 1.0 

<0.20 

2850 

< 0.010 

2.58 

<0.020 

7470 

< 0.10 

0.544 

< 0.10 

46.9 

<0.20 

60.3 

638 

3.47 

< 0.20 

< 0.10 

< 0.20 

< 0.050 

1510 

1350 

< 0.10 

Received Date: 1/28/2011 7:08:50 PM 

QL Q 

EPA 351.2 

20.0 

EPA 200.7 

0.05 

SM 31128 

0.20 

EPA 7470 

0.0002 

EPA 6010 

0.020 

150 

0.002 

0.010 

0.020 

0.020 

0.005 

EPA200.7 

1.0 

0.20 

5.00 

0.010 

0.50 

0.020 

25.0 

0.10 

0.050 

0.10 

0.50 

0.20 

5.00 

1.0 

0.10 

0.20 

0.10 

0.20 

0.050 

100 

2.50 

0.10 

Units 

mgllas N 

!f!g/L 

IJQ/1,. 

mgll 

mgll 

mgll 

mgll 

mgll 

mgll 

mgll 

mgiL 

mgiL 

mgll 

mgll 

mgll 

mgll 

mg/L 

mgll 

mgll 

mgll 

mgll 

mg/L 

mgll 

mg/L 

mgll 

mg/L 

mg/L 

mg/L 

mgll 

mg/L 

mgll 

mg/l 

mg/L 

DF 

20 

500 

1 

1 

1 

1 

10 

10 

500 

10 

10 

10 

250 

10 

10 

10 

10 

10 

500 

10 

10 

10 

10 

10 

10 

500 

250 

10 

Date Anal_yzed 

Analyst: SLY 

2/1/2011 2:35:48 PM 

Analyst: MS 

2/1/2011 12:26:00 PM 

Analyst: JEK 

2/1/2011 12:53:33 PM 

Analyst: JEK 

2/1/201112:49:15 PM 

Analyst: MS 

2/11201112:18:00 PM 

2131201110:31 :00 AM 

2/11201112:18:00 PM 

2/11201112:18:00 PM 

2/1/201112:18:00 PM 

2/1/2011 12:18:00 PM 

211/201112:18:00 PM 

Analyst: MS 

211/201112:22:00 PM 

21112011 12:22:00 PM 

213/2011 10:35:00 AM 

211/2011 12:22:00 PM 

211/201112:22:00 PM 

21112011 12:22:00 PM 

213/2011 10:38:00 AM 

2/1/201112:22:00 PM 

211/2011 12:22:00 PM 

2/1/2011 12:22:00 PM 

2/1/2011 12:22:00 PM 

2/1/2011 12:22:00 PM 

2/3/2011 7:41 :00 PM 

2/1/2011 12:22:00 PM 

2/112011 12:22:00 PM 

2/1/2011 12:22:00 PM 

2/1/2011 12:22:00 PM 

2/1/2011 12:22:00 PM 

2/1/201112:22:00 PM 

2/3/2011 7:41 :00 PM 

2/3/2011 10:38:00 AM 

2/1/201112:22:00 PM 

-·--- ·-·-

... 

·····-----

. - -· --·------- -·----·---·-· ·- -···· . ----- -;; 

~~~~ D -... 

.. "' ~ *-

u " -~ < " 

1.0 . 56.()()306 PA OEP 

n - - .. ~ ,. ..,. 
Matrix: AQUEOUS Received Date: 1128/2011 7:08:50 PM 

Analyses Result QL Q Units DF Date Analyzed 

INORGANIC METALS EPA 200.7 Analyst: MS 

Hardness (SM 23408) 18500 10.0 mg!LCaC03 10 2/1/201112:22:00 PM 

INORGANIC METALS EPA200.8 Analyst: JEK 

Thorium <200 200 IJ9IL 200 2/8/2011 3:03:00 PM 

Uranium <200 200 IJQ/L 200 2/8/2011 3:03:00 PM 

TCLP HERBICIDES EPA8151 Analyst.: NPT 

2,4,5-T < 0.0050 0.0050 mg!L 100 21312011 10:39:30 PM 

2,4-0 <0.020 0.020 mg!L 100 213/2011 10:39:30 PM 

Silvex <0.0050 0.0050 mg/L 100 2/3/2011 10:39:30 PM 

Surr: 2,4-Dichlorophenyl acetic acid 74.9 28.5-130 %REC 100 2/3/2011 10:39:30 PM 

TCLP PESTICIDES EPA8081 Analyst: NPT 

Chlordane < 0.010 0.010 mg!L 10 2/212011 7:07:46 PM 

Endrin <0.00050 0.00050 mg!L 10 2/212011 7:07:46 PM 

Lindane <0.00050 0.00050 mg!L 10 2/2/2011 7:07:46 PM 

Methoxychlor <0.00050 0.00050 mg!L 10 2/212011 7:07:46 PM 

Toxaphene <0.020 0.020 mg!L 10 2/212011 7:07:46 PM 

Heptachlor (and its epoxlde) < 0.0010 0.0010 mg!L 10 21212011 7:07:46 PM 

Surr: Decachlorobiphenyl 96.3 5-156 %REC 10 2/212011 7:07:46 PM 

Surr: Tetrachloro-m-xylene 64.3 15.9-102 %REC 10 2/2/2011 7:07:46 PM 

SEMI-VOLATILE COMPOUNDS: TCLP EPA8270 Analyst: JB 

2-Methylphenol < 100 100 IJ9/L 10 2/4/2011 6:48:00 AM 

2,4-Dinitrotoluene < 100 100 IJg/L 10 2/4/2011 6:48:00 AM 

Hexachlorobenzene < 100 100 1J91l 10 2/4/2011 6:48:00 AM 

Hexachlorobutadiene < 100 100 IJ91L 10 2/4/2011 6:48:00 AM 

Hexachloroethane < 100 100 IJ9/L 10 2/4/2011 6:48:00 AM 

Nitrobenzene < 100 100 IJ9/L 10 2/4/2011 6:48:00 AM 

Pentachlorophenol < 500 500 IJ9/L 10 2/4/2011 6:48:00 AM 

Pyridine < 200 200 IJg/L 10 2/4/2011 6:48:00.AM 

2,4,5-Trichlorophenol < 100 100 IJQ/L 10 2/4/2011 6:48:00 AM 

2,4 ,6-Trichlorophenol < 100 100 IJ91L 10 2/4/2011 6:48:00 AM 

3,4-Methylphenol < 100 100 IJg/L 10 2/4/2011 6:4.8:00 AM 

Surr: 2,4,6-Tribromophenol 101 5-137 %REC 10 2/4/2011 6:48:00 AM 

Surr: 2-Fiuorobiphenyl 49.3 27.7-95.1 %REC 10 2/4/2011 6:48:00 AM 

Surr: 2-Fiuorophenol 60.4 5-104 %REC 10 2/4/2011 6:48:00 AM 

Surr: Nitrobenzene-05 86.7 16-101 %REC 10 2/4/2011 6:48:00 AM 

Surr: Phenol-06 51.7 5-106 %REC 10 2/4/2011 6:48:00 AM 

Surr: p-Terphenyl-014 38.8 25.4-133 %REC 10 2/4/2011 6:48:00 AM 

VOLATILE ORGANIC COMPOUNDS EPA8260 Analyst: SJM 

Benzene < 1.0 1.0 IJQIL 1/31/2011 7:02:00 PM 

-------------------·--··- ------- -·------ ·-·------ ----·· ---·----------------·-----

< 

0 ~ ~ 1 

I. D. 56-00306 PA DEP 
AQUEOUS Received Date: l/28/2011 7:08:50 PM 

- - ·--·-··- -----·-·-··---·- - - ---·-·-· ---------

Analyses Result QL Q Units DF Date Analyzed 

VOLATILE ORGANIC COMPOUNDS EPA 8260 Analyst: SJM Toluene 1.1 1.0 

~giL 

1/3112011 7:02:00 PM 

Surr: 1 ,2-Dichloroethane-d4 108 70-130 %REC 113112011 7:02:00 PM 

Surr: 4-Bromofluorobenzene 102 70-130 %REC 1 1/3112011 7:02:00 PM 

Surr: Toluene-dB 95.3 70-130 %REC 1 1/3112011 7:02:00 PM 

VOLATILE ORGANIC COMPOUNDS: TCLP EPA 8260 Analyst: JAW Benzene <50 50 

~ 

50 2/3/20114:31:00AM 

Carbon Tetrachloride <50 50 j.lg/l 50 213120114:31:00AM Chlorobenzene <50 50 

~giL 50 213/2011 4:31:00 AM 

1 , 1-Dichloroethene <50 50 

~ll 

50 213120114:31:00AM 

1 ,2-Dichloroethane <50 50 IJgll 50 2/312011 4:31:00 AM 1 A-Dichlorobenzene <50 50 IJg/L 50 2/3120114:31:00AM Trichloromethane <50 50 

~giL 

50 2/312011 4:31 :00 AM 

Methyl Ethyl Ketone < 250 250 jJgll 50 21312011 4:31:00 AM Tetrachloroethene <50 50 

~giL 50 21312011 4:31:00 AM 

Trichloroethene <50 50 

~giL 50 21312011 4:31 :00 AM 

\tinyl Chloride <50 50 

~ll 

50 21312011 4:31:00 AM 

Surr: 1 ,2-Dichloroethane-d4 90.7 70-130 %REC 50 21312011 4:31:00 AM 

Surr: 4-Bromofluorobenzene 99.7 70-130 %REC 50 213120114:31:00AM 

Surr: Dibromofluoromethane 92.0 70-130 %REC 50 213120114:31 :00AM 

Surr: Toluene-dB 97.0 70-130 %REC 50 2/312011 4:31:00 AM 

INDICATOR ORGANIC PARAMETERS EPA 1664 Analyst: DSZ Oii&Grease 436 !) mg/l 1.08 2/112011 8:48:00 AM 

NOTES: 

J - Unable to obtain a stable weight within specified limits due to sample matrix. Value is estimated. 

VOLATILE ORGANIC COMPOUNDS EPA8015 Analyst: SUB Ethylene Glycol <550 550 mgll. 217/2011 

RADIOLOGICAL TESTING EPA 900.0 Analyst: SUB Gross Alpha 7229 +-1675 3.00 pCVL 2/10/2011 

Gross Beta 1048 +- 748 4.00 pCVL 2/10/2011 

RADIOLOGICAL PARAMETERS EPA 903.1 Analyst: SUB Radium 226 1638 +- 307 1.00 pCVL 2/18/2011 

RADIOLOGICAL PARAMETERS EPA 904.0 Analyst: SUB Radium 228 199 +- 39.2 1.00 pCVL 1 2/18/2011 

INORGANIC$ NON-METALS EPA 9040 Analyst: ~LL Corrosivity Characteristic 6.55 1.00 su 1/31/2011 

FLASH POINT EPA 1010 Analyst: RLL 

.. 

~ 

<" 

... * 

u " -... 

< "' 

1.0. 56-00306 PA DEP 

Page 6 of7 
Matrix: 

AQUEOUS 

Received Date: l/28/2011 7:08:50 PM 

- ----···••- ···-----··-- - - - • P• 0 • •••• - ~- 0 · - .... - .. -- --- < 0. 0. 0 Oo --- ·- ----- --- ·-• --- - - -

----·--·- - -

Analyses 

FLASH POINT 

Flashpoint 

TCLP ZHE EXTRACTION 

TCLP,ZHE 

TCLP EXTRACTION 

Extraction Fluid Used 

Final pH 

Initial pH 

pH with HCI 

pH with water 

TCLP, non-volatile 

TCLP,ZHE 

Result QL Q 

EPA 1010 

>200 10.0 

EPA 1311 

RL 1.0 

EPA 1311 

NA 0 

3.1 1.0 

NA 1.0 

NA 1.0 

NA 1.0 

NA 0 

NA 0 

Units 

·F 

DF Date Analyzed 

Analyst: RLL 

212/2011 

Analyst: RLL 

113112011 

Analyst: RLL 

1/31/2011 

1/31/2011 

1131/2011 

1/3112011 

113112011 

1 1/3112011 

1 113112011 

.. .. .. 

--· · --~ - ... ---·-. - - --- --·- ------·- - -· -- ·- -- .. --

I. D. 56-00306 PA DEP 
prepared. The date on attache

General Reference 

Company 

c. Number of Solid or Uquld Phases of Separation 

Une2 

brineish 

1 

10# 

Describe each phase of separation • .::;liQ:s.:U::::id=----------------

-1 -
a. waste pennit number(s) for 

b. 

c. 

PA0095273 

Address Une 1 Address Une 1 

Address City State ZIP 

Municipality 

Phone 

waste shipped to processing or ai51POlia• 0 cuyd gal 

County Indiana 

steve@pabrine.com 

year. 0 lb 0 ton (check one) 

a. Solid waste processing or disposal facility being utilized. 

b. 

c. 

d. 

t,lame 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

Title 

County 

(check one) 

0 ton (check one) 

-2-
Fonn Submitted: 0 Form26R 

0 Other (specify) 

Date Submitted: 

0 I certify the lnfonnation required In Section B-2, Chemical Analysis was supplied to the Department for the year 

__ and has not changed. 

Fonn Submitted: 0 Form26R 

0 Other (specify) 

Date Submitted: 

0 I certify the lnfonnation required In Section ~. Proceaa Description and Schematic, was supplied to the Department 

for the year_ and has not changed. 

Fonn Submitted: 

Date Submitted: 

Name of Responsible Official 

Bernhardt Kissel 

Signature 

0 Form26R 

0 Other (specify) 

Date 1 

-3 -
Brine fluids are composited within the storage production tank or tank battery at each well site where gas production is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP permitted waste disposal facilities on different schedules determined by individual well characteristics. Grab samples of the composited fluids were obtained at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. 

Samples were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. 

Flowback samples were composited to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and combined into a composite sample for analyses at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites. In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness of the composite sample and composite grid sample positions were varied to the extent possible. 

Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned and reused from well to well. 
Form 26R: Section B3a 

WASTE GENERATION PROCESS 

Pit Water "Drill Fluids" 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and formation fluids. These fluids are brought to 

the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are 

mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

Flowback: "Fracing Fluid" 

Flowback is produced from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the 

formation fractures. 

Production Fluid "Brine" 

During the production of natural gas, formation pressures bring remnant frac fluids, 

during the initial production phase, and formation fluids to the surface along with 

produced gas. 
Well I. D.# (various) Well I.D.#.(various) 

~b"- . -W.- /0, /1' 

COUNTY A 

I\ I 

\ / Well I. D.# (various) 

\ I ::::0/ 

\ I //I' 

\ I / \ I // 

\ I // 

. . \ I / 

Well I. D.# (various) \ 1 // 

\\/ / \ I / 

- COUNTYB 

-0- / ' 

Q / ~ ---- . 

"/ Ofl"'"'~~~~ ~ Mobile Tank Truck 

~r-oc9vc..-\- tOJ\ Ocu th~~~ \tlAkS ~: ( 

J~ S brine (1YP.) 

ote: . Process producing waste: Gas well produced 

fluids (brines) are typically produced' in 

conjuction with natural gas. These fluids 

are brought to the surface utilizing either 

mechanical or physical lift procedur_es. 

----- Landfill or 

Treu.+~U\+ 'PlGV\t 

(.) 

i 

w 

:c 

() 

C/') 

z 

0 

~ 1-

c:: 

0 

a.. 

(/) 

z 

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~~~~l .. ~ ~ 

i I ~ ~ 

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; i - i ~ ~ 

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m ~! z ~ ... 

~ f' 

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u 
RICK BONAZZA 

RESOURCE MANAGEMENT SERVICES 

65 FENTON ROAD 

INDIANA, PA 15701 

RE: 26R Analysis 

Dear RICK BONAZZA: 

OrderNo.: G1012653 

Geochemical Testing received 1 sample(s) on 12/22/2010 for the analyses presented in the 

following report. 

There were no problems with the analyses and all QC data met NELAC, EPA, and laboratory 

specifications except where noted in the Case Narrative or Laboratory Results. 

If you have any questions regarding these tests results, please feel free to call. 

Sincerely, 

Timothy W. Bergstresser 

Director of Technical Services 

Page 1 of 6 
REVISED REPORT (2/4/11): Sample description changed. 

The ethylene glycol analysis was subcontracted to Free Col. A copy of the subcontractor's laboratory 

report is enclosed with this Analytical Report. 

The radiological analysis was subcontracted to Pace Analytical. A copy of the subcontractor's 

laboratory report is enclosed with this Analytical Report. 

Legend: 

J - Indicates an estimated value. 

U -The analyte was not detected at or above the listed 

concentration, which is below the laboratory quantitation limit. 

8 - Analyte detected in the associated Method Blank 

Q -Qualifier QL -Quantitation Limit OF -Dilution Factor 

R- RPD outside accepted recovery limits 

E- Value above quantitation range 

** -Value exceeds Action Limit 

H -Method Hold Time Exceeded 

MCL- Contaminant Limit 

Page 2 of 6 

1.0. 56-00306 PA DEP 
Analyses 

INORGANIC NON-METALS 

Acidity to pH 8.2 

INORGANIC NON-METALS 

Alkalinity to pH 4.5 

PHYSICAL TESTS 

SpecifiC Conductance 

PH BY SM 4500 H+B 

Lab pH 

INORGANIC NON-METALS 

Total dissolved solids 

PHYSICAL TESTS 

Total suspended solids 

INDICATOR ORGANIC PARAMETERS 

BOD 5-day 

Result 

260 

20 

73400 

5.34 

48200 

45 

280 

Finish Date/Time 12127/2010 07:15 

REACTIVE CYANIDE 

Reactive cyanide < 0.25 

INDICATOR ORGANIC PARAMETERS 

Chemical Oxygen Demand 5700 

INORGANIC NON-METALS 

Bromide 206 

Chloride 29000 

Sulfate <50 

INORGANIC NON-METALS 

MBAS < 0.50 

INORGANIC NON-METALS 

Ammonia Nitrogen - Distilled 40.7 

INORGANIC NON-METALS 

Nitrate - Nitrite < 0.05 

INDICATOR ORGANIC PARAMETERS 

Phenolics < 100 

REACTIVE SULFIDE 

Reactive sulfide 0.91 

INORGANIC NON-METALS 

·-- ----- -·-----·-----·-------·-·---· --·- -----------

QL Q Units DF Date Analyzed 

SM 23108(4A) Analyst: LNW 

0 1213112010 12:19:00 PM 

SM 18 23208 

5 

EPA 120.1 

SM4500-H+B 

0 

SM 2540C 

100 

SM 2540D 

5 

SM 5210 B 

60 

0 

SW846 CH.7 

0.25 

HACH 8000 

200 

EPA 300.0 

5.0 

25 

50 

SM 5540C 

0.50 

EPA 350.1 

10.0 

EPA 353.2 

0.05 

EPA420.1 

100 

SW 846 CH.7 

0.25 

EPA 351.2 

Page 3 of6 

mgiLCaC03 

mg/LCaC03 

~Jmhoslcm 

su 

mg/L 

mg/L 

mg/L 

mg/L 

mg/Kg 

mg/L 

mg/L 

mg/L 

mg/L 

mg/L as LAS 

mg/L as N 

mg/L as N 

~Jg/L 

mg/Kg 

5 

60 

60 

Analyst: LNW 

12130/2010 8:17:00 PM 

Analyst: LNW 

12130/2010 8:17:00 PM 

Analyst: LNW 

12130/2010 8:17:00 PM 

Analyst: KLS 

1212212010 8:15:00 AM 

Analyst: KLS 

1212212010 8:31 :52 AM 

Analyst: MMR 

1212212010 6:30:00 AM 

1212212010 6:30:00 AM 

Analyst: SAG 

1.01 12129/2010 2:42:00 PM 

Analyst: LCC 

20 1/3/2011 

Analyst: CAS 

25 12129/2010 12:46:00 AM 

25 12/29/2010 12:46:00AM 

25 12129/2010 12:46:00 AM 

Analyst: KMW 

10 1212212010 10:15:00AM 

Analyst: SLY 

100 1/4/2011 12:22:44 PM 

Analyst: SLY 

12/27/2010 12:07:42 PM 

Analyst: SAG 

12/28/2010 11:56:00 AM 

Analyst: MMR 

1.p1 12129/2010 12:45:00 PM 

Analyst: SLY 

I.D. 56-00306 PA DEP 
Analyses 

INORGANIC NON-METALS 

Total Kjeldahl Nitrogen 

INORGANIC METALS 

Iron, dissolved 

INORGANIC METALS 

Mercury 

INORGANIC METALS 

Aluminum 

Arsenic 

Barium 

Beryllium 

Boron 

Cadmium 

Calcium 

Chromium 

Cobalt 

Copper 

Iron 

Lead 

Lithium 

Magnesium 

Manganese 

Molybdenum 

Nickel 

Selenium 

Silver 

Sodium 

Strontium 

Zinc 

Hardness (SM 2340B) 

INORGANIC METALS 

Thorium 

Uranium 

HERBICIDE ANALYSIS 

2,4,5-T 

2,4-D 

Silvex 

Surr: 2,4-Dichlorophenyl acetic acid 

Result 

32.7 

100 

< 0.20 

< 0.1 

<0.02 

1170 

< 0.001 

2.32 

< 0.002 

2980 

< 0.01 

0.044 

0.04 

113 

<0.02 

117 

212 

9.06 

< 0.02 

0.02 

< 0.02 

< 0.005 

16200 

1040 

0.09 

8310 

< 50.0 

< 50.0 

< 0.47 

< 1.9 

< 0.47 

57.3 

QL Q Units 

EPA 351.2 

20.0 mg/L as N 

EPA200.7 

0.05 mg/L 

SM 31128 

0.20 1J91l 

EPA 200.7 

0.1 mg/L 

0.02 mg/L 

5.00 mg/L 

0.001 mgll 

0.05 mg/L 

0.002 mg/L 

1.0 mg/L 

0.01 mg/L 

0.005 mg/L 

0.01 mg/L 

0.05 mgll 

0.02 mg/L 

10.0 mg/L 

1.0 mg/L 

0.01 mg/L 

0.02 mg/L 

0.01 mg/L 

0.02 mgll 

0.005 mg/L 

100 mg/L 

5.00 mg/L 

0.01 mg/L 

10.0 mg/L CaC03 

EPA200.8 

50.0 IJg/L 

50.0 1Jg/L 

EPA 8151 

0.47 IJg/L 

1.9 IJQ/L 

0.47 IJQIL 

28.5-130 %REC 

Page 4 of6 

DF 

20 

1 

1 

500 

10 

1 

1 

1 

500 

10 

1 

500 

500 

1 

10 

50 

50 

9.43 

9.43 

9.43 

9.43 

Date Analyzed 

Analyst: SLY 

12129/2010 9:26:05 AM 

Analyst: MS 

12129/2010 2:40:00 AM 

Analyst: JEK 

12127/2010 11:15:54 AM 

Analyst: MS 

12128/2010 6:54:00 PM 

12128/2010 6:54:00 PM 

12129/20104:05:00 PM 

12128/2010 6:54:00 PM 

12128/2010 6:54:00 PM 

12128/2010 6:54:00 PM 

12/29/20104:32:00 PM 

12128/2010 6:54:00 PM 

12128/2010 6:54:00 PM 

12128/2010 6:54:00 PM 

12128/2010 6:54:00 PM 

12128/2010 6:54:00 PM 

12129/2010 4:05:00 PM 

12129/2010 4:32:00 PM 

12128/2010 6:54:00 PM 

12128/2010 6:54:00 PM 

12128/2010 6:54:00 PM 

12128/2010 6:54:00 PM 

12128/2010 6:54:00 PM 

12129/2010 4:05:00 PM 

12129/2010 4:05:00 PM 

12/28/2010 6:54:00 PM 

12129/2010 4:32:00 PM 

Analyst: JEK 

12/28/2010 5:29:00 PM 

12128/2010 5:29:00 PM 

Analyst: TEW 

12130/2010 3:35:05 AM 

12/30/2010 3:35:05 AM 

12/30/2010 3:35:05 AM 

12/30/2010 3:35:05 AM 

I. D. 56-00306 PA DEP 
Analyses Result QL Q 

PESTICIDE ANALYSIS EPA8081 

Chlordane <4.9 4.9 

Endrin < 0.24 0.24 

Gamma BHC (Lindane) < 0.24 0.24 

Heptachlor epoxide <0.24 0.24 

Methoxychlor < 0.24 0.24 

Toxaphene < 9.7 9.7 

Surr: Decachlorobiphenyl 71 .6 5-156 

Surr: Tetrachloro-m-xylene 51 .6 15.9-102 

SEMI-VOLATILE COMPOUNDS EPA 8270 

2,4,5-Trichlorophenol <9.4 9.4 

2,4,6-Trichlorophenol <9.4 9.4 

2,4-0initrotoluene <9.4 9.4 

2-Methylphenol <9.4 9.4 

Hexachlorobenzene <9.4 9.4 

Hexachlorobutadiene <9.4 9.4 

Hexachloroethane <9.4 9.4 

Nitrobenzene <9.4 9.4 

Pentachlorophenol <47 47 

Pyridine <47 47 

3,4-Methylphenol <9.4 9.4 

Surr: 2,4,6-Tribromophenol 103 5-137 

Surr: 2-Fiuorobiphenyl 84.7 27.7-95.1 

Surr: 2-Fiuorophenol 71 .4 5-104 

Surr: Nitrobenzene-d5 0.0800 16-101 s 

Surr. Phenol-d6 77.4 5-106 

Surr. p-Terphenyl-d14 61 .8 25.4-133 

Units D F Date Analyzed 

Analyst: TEW 

r.rg/L 4.85 1/4/201111:14:00 PM 

r.rg/L 4.85 1/4/201111:14:00 PM 

!Jg/L 4.85 1/4/201111:14:00 PM 

r.rg/L 4.85 1/4/2011 11:14:00 PM 

r.rg/L 4.85 1/4/201111:14:00 PM 

r.rgll 4.85 1/4/201111:14:00PM 

%REC 4.85 1/4/2011 11 :14:00 PM 

%REC 4.85 1/4/201111:14:00 PM 

Analyst: NPT 

r.rg/L 0.94 12129/2010 4:42:00 PM 

r.rg/L 0.94 12129/2010 4:42:00 PM 

IJQ/L 0.94 12129/2010 4:42:00 PM 

r.rg/L 0.94 12129/2010 4:42:00 PM 

r.rg/L 0.94 12129/2010 4:42:00 PM 

r.rg/L 0.94 12129/2010 4:42:00 PM 

r.rg/1,. 0.94 12129/2010 4:42:00 PM 

r.rg/L 0.94 12129/2010 4:42:00 PM 

r.rg/L 0.94 12129/2010 4:42:00 PM 

!Jg/L 0.94 12129/2010 4:42:00 PM 

r.rg/L 0.94 12129/2010 4:42:00 PM 

%REC 0.94 12129/2010 4:42:00 PM 

%REC 0.94 12129/2010 4:42:00 PM 

%REC 0.94 12129/2010 4:42:00 PM 

%REC 0.94 12/29/2010 4:42:00 PM 

%REC 0.94 12129/2010 4:42:00 PM 

%REC 0.94 12/29/2010 4:42:00 PM 

VOLA TILE ORGANIC COMPOUNDS EPA 8260 Analyst: SJM 

12/22/2010 5:42:00 PM 

12/22/2010 5:42:00 PM 

12/2212010 5:42:00 PM 

1,1-0ichloroethene < 1.0 

1,2-0ichloroethane < 1.0 

1,4-0ichlorobenzene < 1.0 

Benzene < 1.0 

Carbon Tetrachloride < 1.0 

Chlorobenzene < 1.0 

Methyl Ethyl Ketone < 5.0 

Tetrachloroethane < 1.0 

Toluene 2.9 

Trichloroethane < 1.0 

Trichloromethane < 1.0 

Vinyl Chloride < 1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

5.0 

1.0 

1.0 

1.0 

1.0 

1.0 

Page 5 of6 

r.rg/L 

r.rg/L 

r.rg/L 

r.rg/L 

r.rg/L 

!Jg/L 

r.rg/L 

r.rg/L 

r.rg/L 

IJQ/L 

r.rg/L 

IJQ/L 

1 1212212010 5:42:00 PM 

1 12/22/2010 5:42:00 PM 

12122/2010 5:42:00 PM 

12/22/2010 5:42:00 PM 

12/2212010 5:42:00 PM 

12/22/2010 5:42:00 PM 

12/2212010 5:42:00 PM 

12/22/2010 5:42:00 PM 

1212212010 5:42:00 PM 

1.0. 56-00306 PA OEP 
Analyses 

VOLATILE ORGANIC COMPOUNDS 

Surr: 1 ,2-Dichloroethane-d4 

Surr: 4-Bromoftuorobenzene 

Surr: Toluene-dB 

INDICATOR ORGANIC PARAMETERS 

Oil & Grease 

VOLA TILE ORGANIC COMPOUNDS 

Result 

93.2 

99.9 

99.0 

<5 

Ethylene Glycol < 500 

RADIOLOGICAL TESTING 

Gross Alpha 2714 +- 893 

Gross Beta 733 +- 943 

RADIOLOGICAL PARAMETERS 

Radium 226 2824 +- 555 

QL Q 

EPA 8260 

70-130 

70-130 

70-130 

EPA 1664 

5 

EPA 8015 

500 

EPA 900.0 

3.00 

4.00 

EPA 903.1 

1.00 

Units DF 

%REC 

%REC 

%REC 

mg/L 1.08 

mgll 

pCi/L 

pCi/L 

pCiiL 

Date Analyzed 

Analyst: SJM 

1212212010 5:42:00 PM 

1212212010 5:42:00 PM 

1212212010 5:42:00 PM 

Analyst: DSZ 

1212312010 1:35:00 PM 

Analyst: SUB 

1/3/2011 

Analyst: SUB 

12130/2010 

1213012010 

Analyst: SUB 

1/1212011 

RADIOLOGICAL PARAMETERS EPA 904.0 Analyst: SUB 

1/17/2011 · Radium 228 254 +- 80.4 1.00 

INORGANICS NON-METALS EPA9040 

Corrosivity Characteristic 5.15 1.00 

FLASH POINT EPA 1010 

Flashpoint >200 10.0 

Page 6 of6 

pCi!L 

su 

•f 

Analyst: RLL 

12127/2010 

Analyst: RLL 

1/4/2011 

I. D. 56-00306 PA DEP 
atch the date noted below. 

General Reference 287.54 

c. Appearance 

State 

PA 

First Name 

Ben 

Company Mailing Address Une 

- 1 -

EPA Generator 
b. Facility Name 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

c. 

Address Line 1 

Address Line 1 

Address City State ZIP 

Municipality 

c. Facility Contact 

Title 

Phone 

d. to processing or disposal D cuyd D gal D lb 

-2-

(check one) 

year. 

ton (check one) 

0 ton (check one) 
Form Submitted: 0 Fonn26R 

0 Other (specify) 

Date Submitted: 

0 I certify the Information required In Section B-2, Chemical Analysis was supplied to the Deparbnent for the year 

_and has not changed. 

Form Submitted: 0 Fonn 26R 

D other (specify) 

Date Submitted: 

0 I certify the Information required In Section ~. Process Description and Schematic, was supplied to the Deparbnent 

for the year_ and has not changed. 

Form Submitted: 0 Fonn 26R 

Date Submitted: 

Name of Responsible Official 

Bernhardt Kissel 

Signature 

0 Other (specify) 

Date 1 

-3 -
Form 26R: Section B 1 e 

GENERATOR KNOWLEDGE 

All Form 26R Waste Forms have been compiled, and future testing has been scheduled, to obtain samples of each waste stream on a PAD by PAD basis. Sample analyses will be conducted every 5 years for each waste stream unless the process that generates any particular waste stream is substantially altered. 

Attached analytical results for this waste stream have been obtained from a similar 

waste stream producing waste from the same geologic formation as this 26R Report. 

Additionally, the mud mixtures, chemical form~lations and drilling process utilized at this well PAD are substantially the same as those utilized at the well where the attached 

waste analyticals were generated. 
Brine fluids are composited within the storage production tank or tank battery at each well site where gas production is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP permitted waste disposal facilities on different schedules determined by individual well characteristics. Grab samples of the composited fluids were obtained at the 

represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. 

Samples were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. 

Flowback samples were composited to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and combined into a composite sample for analyses at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites. In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness of the composite sample and composite grid sample positions were varied to the extent possible. 

Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned 

and reused from well to well. 
Form 26R: Section B3a 

WASTE GENERATION PROCESS 

Pit Water "Drill Fluids" 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and formation fluids. These fluids are brought to 

the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are 

mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

Flowback: "Fracing Fluid" 

Flowback is produCed from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the 

formation fractures. 

Production Fluid "Brine" 

During the production of natural gas, formation pressures bring remnant frac fluids, 

during the initial production phase, and formation fluids to the surface along with 

produced gas. 
Well I. D.# (various) Well I.-D.# (various) 

'\/ )J( ~0~ ~~~ 

COUNTY A 

I\ I 

\ / Well I. D.# (various) 

\ I ::::(:£/ \ I //I' 

\ I / \ I // 

\ I // 

. . \ I / 

Well I.D.# (various) \ 1 // 

'\/ / \ I / 

-o- / " ,----

- COUNTYB 

C( _,. 

"/ ~o,-- Fico.>~....\.. ~7 ( . ~ 

~ Mobile Tank Truck 

~r-ob/.\x.:ho.l\ Ocu t\\~~~ \f>AI,..S :• ~ 

, 'J~ S brine (1YP.) 

ote: 

Process producing waste: Gas well produced 

fluids (brines) are typically produced in 

conjuction wi.th natural gas. These fluids 

are brought to the surface utilizing either 

. mechanical or physical lift procedures. 

_ :s:::: Road Transport 

-------Landfill orTreu.+~(.J\+ '?lGV\t -

(.) 

~ w 

:c 

(.) 

(/) 

z 

0 

~ 1-

0:: 

0 

0.. 

(/) 

z 

~ 1-

~~ 

n~ 

I

t! g ~~ 

i i1 ~ i~ 

I 

i ~ z 

~ 

~ 
RICK BONAZZA 

RESOURCE MANAGEMENT SERVICES 

65 FENTON ROAD 

INDIANA, PA 15701 

RE: 26R Analysis 

Dear RICK BONAZZA: OrderNo.: G1101912 

Geochemical Testing received 1 sample(s) on 1/28/2011 for the analyses presented in the 

following report. 

There were no problems with the analyses and all QC data met NELAC, EPA, and laboratory 

specifications except where noted in the Case Narrative or Laboratory Results. 

If you have any questions regarding these tests results, please feel free to call. 

Sincerely, 

Timothy W. Bergstresser 

Director of Technical Services 

Paqe 1 of 7 

1.0. 56.00306 PA OEP 
The ethylene gycol analysis was subcontracted to Free Col Labs. A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. 

The radiological analysis was subcontracted to Pace Analytical. A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. 

Legend: NO - Not Detected at the Quantitation Limit 

J - Indicates an estimated value. 

U -The analyte was not detected at or above the listed 

concentration, which is below the laboratory quantitation limit. 

8 - Analyte detected in the associated Method Blank 

Q - Qualifier QL -Quantitation Limit OF -Dilution Factor 

R - RPD outside accepted recovery limits 

E - Value above quantitation range 

•• -Value exceeds Action Limit 

H - Method Hold Time Exceeded 

MCL- Contaminant Limit 

Page 2 of 7 

J.D. 56-00306 PA DEP 
Q

Analyses Result 

INORGANIC NON-METALS 

Acidity to pH 8.2 -38 

INORGANIC NON-METALS 

Alkalinity to pH 4.5 150 

PHYSICAL TESTS 

Specific Conductance 111000 

PH BY SM 4500 H+B 

Lab pH 6.52 

INORGANIC NON-METALS 

Total dissolved solids 97500 

PHYSICAL TESTS 

Total suspended solids 545 

INDICATOR ORGANIC PARAMETERS 

BOD 5-day 1350 

Finish DateiTime 2/2/2011 18:10 

REACTIVE CYANIDE 

Reactive cyanide 

INDICATOR ORGANIC PARAMETERS 

Chemical Oxygen Demand 

INORGANIC NON-METALS 

Bromide 

Chloride 

Sulfate 

INORGANIC NON-METALS 

MBAS 

INORGANIC NON-METALS 

Ammonia Nitrogen - Distilled 

INORGANIC NON-METALS 

Nitrate - Nitrite 

INDICATOR ORGANIC PARAMETERS 

Phenolics 

REACTIVE SULFIDE 

Reactive sulfide 

INORGANIC NON-METALS 

<0.25 

5800 

461 

57100 

< 100 

< 0.25 

69.1 

0.53 

< 100 

0.50 

·--·--··-

.... 

- -

...... 

- ----·--·-···-·----------

ate: 1/28/2011 7:08:50 PM 

QL Q Units 

SM·23108(4A) 

0 mgll CaC03 

SM 18 23208 

5 mg/l CaC03 

EPA 120.1 

1Jmhos/cm 

SM4500-H+B 

0 su 

SM 2540 C 

100 mgll 

SM 2540D 

25 mg/L 

SM 5210 B 

300 mg/L 

0 mg/l 

SW846 CH.7 

0.25 mg/Kg 

HACH 8000 

50 mg/L 

EPA 300.0 

10.0 mg/L 

50 mg/L 

100 mg!L 

SM 5540C 

0.25 H mg/l as LAS 

EPA 350.1 

. 5.00 mg/l as N 

EPA 353.2 

0.05 mg/L as N 

EPA420.1 

100 j.lg/l 

SW846 CH.7 

0.25 mg/Kg 

EPA 351.2 

DF Date Analyzed 

Analyst: LNW 

2/4/2011 9:44:00 AM 

Analyst: LNW 

2/3/2011 4:50:00 PM 

Analyst: LNW 

2/3/2011 4:50:00 PM 

Analyst: LNW 

2/3/2011 4:50:00 PM 

Analyst: . KLS 

5 1/31/20117:10:00AM 

Analyst: KLS 

5 113112011 7:17:04 AM 

Analyst: SAG 

300 1/28/2011 6:50:00 PM 

300 

0.99 

5 

50 

50 

50 

5 

50 

0.99 

1/28/2011 6:50:00 PM 

Analyst: SAG 

2/9/2011 4:58:00 .PM 

Analyst: MGV 

2/1/2011 

Analyst: CAS 

1/31/20112:51:00PM 

1/31/2011 2:51 :00 PM 

1/31/2011 2:51:00 PM 

Analyst: CAS 

2/2/2011 2:30:00 PM 

Analyst: SLY 

2/10/201112:51 :01 PM 

Analyst: SLY 

2/1/201110:14:21 AM 

Analyst: KMW 

2/4/2011 1:05:00 PM 

Analyst: SLY 

2/3/2011 2:50:00 PM 

Analyst: SLY 

----·------------

___________ .... _ ... 

·- ·- ~ ~ ~ u ~ < "' 

I.D. 56-00306 PA DEP 

Page 3 of 7 
Q

Analyses 

INORGANIC NON-METALS 

Total Kjeldahl Nitrogen 

INORGANIC METALS 

Iron, dissolved 

INORGANIC METALS 

Mercury 

TCLPMETALS 

Mercury 

TCLP METALS 

Arsenic 

Barium 

Cadmium 

Chromium 

Lead 

Selenium 

Silver 

INORGANIC METALS 

Aluminum 

Arsenic 

Barium 

Beryllium 

Boron 

Cadmium 

Calcium 

Chromium 

Cobalt 

Copper 

Iron 

Lead 

Lithium 

Magnesium 

Manganese 

Molybdenum 

Nickel 

Selenium 

Silver 

Sodium 

Strontium 

Zinc 

Result 

61 .4 

10.5 

<0.20 

<0.0002 

<0.020 

3190 

<0.002 

< 0.010 

<0.020 

<0.020 

<0.005 

< 1.0 

< 0.20 

2850 

< 0.010 

2.58 

<0.020 

7470 

< 0.10 

0.544 

< 0.10 

46.9 

< 0.20 

60.3 

638 

3.47 

< 0.20 

< 0.10 

< 0.20 

<0.050 

1510 

1350 

< 0.10 

7:08:50 PM 

QL Q Units 

EPA 351.2 

20.0 mg/L as N 

EPA200.7 

0.05 !'lg/L 

SM 31128 

0.20 IJg/1,. 

EPA 7470 

0.0002 mg/L 

EPA6010 

0.020 

150 

0.002 

0.010 

0.020 

0.020 

0.005 

** 

EPA200.7 

1.0 

0.20 

5.00 

0.010 

0.50 

0.020 

25.0 

0.10 

0.050 

0.10 

0.50 

0.20 

5.00 

1.0 

0.10 

0.20 

0.10 

0.20 

0.050 

100 

2.50 

0.10 

mg/L 

mgll 

mg/L 

mg/L 

mg/L 

mgll 

mgiL 

mgll 

mgll 

mgll 

mgll 

mg/L 

mgiL 

mgll · 

mgll 

mgll 

mgll 

mg/L 

mgll 

mgll 

mgiL 

mgll 

mgll 

mg/L 

mgll 

mgll 

mgll 

mgll 

mgll 

DF 

20 

500 

1 

1 

10 

10 

500 

10 

10 

10 

250 

10 

10 

10 

10 

10 

500 

10 

10 

10 

10 

10 

10 

500 

250 

10 

Date Anal.yzed 

Analyst: SLY 

21112011 2:35:48 PM 

Analyst: MS 

21112011 12:26:00 PM 

Analyst: JEK 

21112011 12:53:33 PM 

Analyst: JEK 

2111201112:49:15 PM 

Analyst: MS 

21112011 12:18:00 PM 

2131201110:31:00AM 

2111201112:18:00 PM 

21112011 12:18:00 PM 

21112011 12:18:00 PM 

2111201112:18:00PM 

21112011 12:18:00 PM 

Analyst: MS 

21112011 12:22:00 PM 

21112011 12:22:00 PM 

21312011 10:35:00 AM 

211/2011 12:22:00 PM 

21112011 12:22:00 PM 

21112011 12:22:00 PM 

21312011 10:38:00 AM 

2111201112:22:00 PM 

21112011 12:22:00 PM 

21112011 12:22:00 PM 

2/1/2011 12:22:00 PM 

211/2011 12:22:00 PM 

21312011 7:41 :00 PM 

21112011 12:22:00 PM 

21112011 12:22:00 PM 

211/2011 12:22:00 PM 

2/1/2011 12:22:00 PM 

2111201112:22:00 PM 

2111201112:22:00 PM 

21312011 7:41 :00 PM 

21312011 10:38:00 AM 

2111201112:22:00 PM -- -·-- -· -- ·-~·--------

------ -·-··------ -- ---- - -- - - ------- -

~---· 

I. D. 56-00306 PA DEP 

Page 4 of 7 
Q

Analyses 

INORGANIC METALS 

Hardness (SM 2340B) 

INORGANIC METALS 

Thorium 

Uranium 

TCLP HERBICIDES 

2,4,5-T 2,4-D 

Silvex 

Surr: 2,4-Dichlorophenyl acetic acid 

TCLP PESTICIDES 

Chlordane 

Endrin 

Lindane Methoxychlor 

Toxaphene 

Heptachlor (and its epoxide) 

Surr: Decachlorobiphenyl 

Surr: Tetrachloro-m-xylene 

SEMI-VOLATILE COMPOUNDS: TCLP 

2-Methylphenol 

2,4-Dinitrotoluene 

Hexachlorobenzene Hexachlorobutadiene Hexachloroethane 

Nitrobenzene 

Pentachlorophenol 

Pyridine 

2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 

3,4-Methylphenol 

Surr: 2,4,6-Tribromophenol 

Surr: 2-Fiuorobiphenyl Surr: 2-Fiuorophenol Surr: Nitrobenzene-ciS Surr: Phenol-d6 

Surr: p-Terphenyl-d14 

VOLATILE ORGANIC COMPOUNDS 

Benzene 

Result 

18500 

<200 

< 200 

< 0.0050 

<0.020 

<0.0050 

74.9 

< 0.010 

< 0.00050 

< 0.00050 

<0.00050 

<0.020 

< 0.0010 

96.3 

64.3 

< 100 < 100 

< 100 

< 100 < 100 < 100 < 500 

< 200 < 100 < 100 < 100 

101 

49.3 

60.4 

86.7 51.7 38.8 

< 1.0 

QL Q 

EPA 200.7 

10.0 

EPA 200.8 

. 200 

200 

EPA 8151 

0.0050 

0.020 

0.0050 

28.5-130 

EPA 8081 

0.010 

0.00050 

0.00050 0.00050 

0.020 

0.0010 

5-156 

15.9-102 

EPA 8270 

100 100 100 

100 100 

100 

500 

200 

100 100 100 

5-137 

27.7-95.1 

5-104 

16-101 

5-106 

25.4-133 

EPA 8260 

1.0 

Page 5 of 7 

ece

ved 

ate: 

/

8/

0

7:08:50 

Units 

mg/LCaC03 

IJ9/L IJg/L 

mg/L mg/L mg/L 

%REC 

mg/L mg/L 

mg/L mg/L mg/L mg/L 

%REC 

%REC 

1J9IL 

IJg/L 

1J9IL 

IJg/L IJg/L 

IJg/L IJ9/L 

IJgll 

IJ9/L 

IJ9/L IJ9/L 

%REC %REC 

%REC %REC %REC %REC 

IJg/L 

DF 

10 

200 

200 

100 100 100 

100 

10 

10 10 

10 

10 10 10 10 

10 10 

10 10 

10 10 

10 10 

10 10 

10 

10 10 10 

10 

10 

10 

Date Analyzed 

Analyst: MS 

211/2011 12:22:00 PM 

Analyst: JEK 

218/2011 3:03:00 PM 218/2011 3:03:00 PM 

Analyst.: NPT 

213/2011 10:39:30 PM 

21312011 10:39:30 PM 213/2011 10:39:30 PM 

213/2011 10:39:30 PM 

Analyst: NPT 

2/212011 7:07:46 PM 21212011 7:07:46 PM 

21212011 7:07:46 PM 

21212011 7:07:46 PM 21212011 7:07:46 PM 

21212011 7:07:46 PM 21212011 7:07:46 PM 

2/212011 7:07:46 PM 

.Analyst: JB 

21412011 6:48:00 AM 214/2011 6:48:00 AM 

21412011 6:48:00 AM 

214/2011 6:48:00 AM 214/2011 6:48:00 AM 

2/4/2011 6:48:00 AM 

214/2011 6:48:00 AM 

2/4/2011 6:48:00.AM 

214/2011 6:48:00 AM 

214/2011 6:48:00 AM 

2/4/2011 6:4.8:00 AM 

2/4/2011 6:48:00 AM 

2/4/2011 6:48:00 AM 

214/2011 6:48:00 AM 

2/4/2011 6:48:00 AM 

214/2011 6:48:00 AM 

214/2011 6:48:00 AM 

Analyst: SJM 

1/31/20117:02:00 PM 

I.D. 56-00306 PA DEP 
Q

Analyses 

VOLATILE ORGANIC COMPOUNDS 

Toluene 

Surr: 1,2-Dichloroethane-d4 

Surr: 4-Sromofluorobenzene 

Surr: Toluene-ciS 

Result 

1.1 

10S 

102 

95.3 

VOLA TILE ORGANIC COMPOUNDS: TCLP 

Benzene <50 

Carbon Tetrachloride <50 

Chlorobenzene < 50 

1 ,1-Dichloroethene < 50 

1,2-Dichloroethane < 50 

1 ,4-Dichlorobenzene < 50 

Trichloromethane < 50 

Methyl Ethyl Ketone < 250 

Tetrachloroethene < 50 

Trichloroethene < 50 

Vinyl Chloride < 50 

Surr: 1,2-Dichloroethane-<14 90.7 

Surr: 4-Bromofluorobenzene 99.7 

Surr: Dibromofluoromethane 92.0 

Surr: Toluene-ciS 97.0 

INDICATOR ORGANIC PARAMETERS 

Oil & Grease 436 

NOTES: 

QL Q 

EPA 8260 

1.0 

70-130 

70-130 

70-130 

EPA8260 

50 

50 

50 

50 

50 

50 

50 

250 

50 

50 

50 

70-130 

70-130 

70-130 

70-130 

8

50 PM 

Units 

1!9/L 

%REC 

%REC 

%REC 

~Jg/L 

1!9/L 

1!9/L 

1!9/L 

1!9/L 

1!9/L 

1!9/L 

1!9/L 

1!9/L 

1!9/L 

1!9/L 

%REC 

%REC 

%REC 

%REC 

DF Date Analyzed 

Analyst: SJM 

1131/2011 7:02:00 PM 

1/3112011 7:02:00 PM 

1/3112011 7:02:00 PM 

1/3112011 7:02:00 PM 

Analyst: JAW 

50 213/2011 4:31:00 AM 

50 21312011 4:31:00 AM 

50 213/2011 4:31:00 AM 

50 213/2011 4:31:00 AM 

50 213/2011 4:31:00 AM 

50 21312011 4:31:00 AM 

50 21312011 4:31 :00 AM 

50 21312011 4:31:00AM 

50 2/312011 4:31 :00 AM 

50 213/2011 4:31 :00 AM 

50 213/2011 4:31 :00 AM 

50 21312011 4:31:00 AM 

50 213/2011 4:31:00 AM 

50 21312011 4:31:00 AM 

50 213/2011 4:31 :00 AM 

EPA 1664 Analyst: DSZ 

5 rng/L 1.0S 211/2011 S:4S:OO AM 

J - Unable to obtain a stable weight within specified limits due to sample matrix. Value is estimated. 

VOLA TILE ORGANIC COMPOUNDS 

Ethylene Glycol < 550 

RADIOLOGICAL TESTING 

Gross Alpha 7229 +- 1675 

Gross Beta 1 04S +- 7 4S 

RADIOLOGICAL PARAMETERS 

Radium 226 163S +- 307 

RADIOLOGICAL PARAMETERS 

Radium 228 199 +- 39.2 

INORGANICS NON-METALS 

Corrosivity Characteristic 6.55 

FLASHPOINT 

EPA8015 

550 m9/L 

EPA 900.0 

3.00 pCi/L 

4.00 pCi/L 

EPA 903.1 

1.00 pCiiL 

EPA 904.0 

1.00 pCi/L 

EPA 9040 

1.00 su 

EPA 1010 

Page 6 of 7 

Analyst: SUB 

217/2011 

Analyst: SUB 

2110/2011 

2110/2011 

Analyst: SUB 

2118/2011 

Analyst: SUB 

2/18/2011 

Analyst: RLL 

1/31/2011 

Analyst: RLL 

1.0. 56-00306 PA DEP 
: AQUEOUS 

Analyses Result 

FLASH POINT 

Flashpoint >200 

TCLP ZHE EXTRACTION 

TCLP,ZHE RL 

TCLP EXTRACTION 

Extraction Fluid Used NA 

Final pH. 3.1 

Initial pH NA 

pH with HCI NA 

pH with water NA 

TCLP, non-volatile NA 

TCLP,ZHE NA 

ved Date: 1/28/2011 7:08:50 PM 

QL Q Units DF Date Analyzed 

EPA 1010 

10.0 OF 

EPA 1311 

1.0 

EPA 1311 

0 

1.0 

1.0 

1.0 

1.0 

0 

0 

Page 7 of 7 

Analyst: RLL 

21212011 

Analyst: RLL 

1/3112011 

Analyst: RLL 

1/3112011 

1 1/31/2011 

1 113112011 

113112011 

1 1/31/2011 

1 1/3112011 

113112011 

I. D. 56-00306 PA DEP