2540-PM-BWM0347 Rev.112011 v **e!!'!~~.!!_** COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WASTE MANAGEMENT FORM26R CHEMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT BY THE GENERA TOR typed or legibly printed In the spaces provided.
If additional space Is necessary, Identify each attached sheet as Fonn 26R, reference the item number and identify the date prepared. The date on attached sheets needs to match the date noted below. c. Appearance Company Mailing Solid {EPA Method 9095) Gas (ambient +<•rn,....,..., •• , Zip+4 15701 Color opaque white/orange

. Number of Solid or Uquid Phases of Separation

Ext No Describe each phase of **separation.~~---------------;** -1 -2540.PM-BWM0347 Rev.112011 b. A of the manufacturing and/or uuiiiULIUII as specified In the Instructions,
Is attached. c. If portions of the information
are a confidentiality claim, as described in the instructions,
Is attached. b. Solid waste permit number(s) for PA0091472 Address Line 1 Address Line 1 Address City State ZIP Municipality c. Facility Contact Name Title d. a. Phone Name Address Line 1 Address Line 1 Address City State ZIP Municipality c. Facility Contact Name Title Phone

County Indiana (check one) to processing or disposal facility in the previous year. D cuyd 0 gal

. 0 lb 0 ton number. b.

D gal

0 ton (check one) -2 -

N/A2540.PM-BWM0347 Rev.1/2011 I certify, under penalty of law, that

I have personally examined and am familiar with the Information submitted In this Annual Report and all attached documents and that based upon my Inquiry of those Individuals immediately responsible for obtaining the Information,

I verify that the submitted Information
Is true, accurate and complete to the best of my knowledge.

I understand that the submission of false information herein is made subject to the penalties of 18 PL C.S. §4904, relating to unsworn falsification to authorities, which Include fine and imprisonment Check the following,
If applicable: D

I certify the Information required In Section B-1, General Properties was supplied to the Department for the year __ and has not changed. Form Submitted:
D Form26R D other (specify) --------------- Date Submitted: D

I certify the information required In Section B-2, Chemical Analysis was supplied to the Department for the year __ and has not changed. Form Submitted:

D Form 26R D Other (specify) Date Submitted: D

I certify the Information required in Section 8-3, Process Description and Schematic, was supplied to the Department for the year_ and has not changed. Form Submitted:

D Form 26R D Other (specify) Date Submitted: Name of Responsible Official

Shale Bernhardt Kissel Signature

Date 2-28-11 - 3-February9,2011Form26R:Section81eGENERATORKNOWLEDGEAllForm26RWasteFormshavebeencompiled,andfuturetestinghasbeenscheduled,toobtainsamplesofeachwastestreamonaPADbyPADbasis.Sampleanalyseswillbeconductedevery5yearsforeachwastestreamunlesstheprocessthatgeneratesanyparticularwastestreamissubstantiallyaltered.Attachedanalyticalresultsforthiswastestreamhavebeenobtainedfromasimilarwastestreamproducingwastefromthesamegeologicformationasthis26RReport.Additionally,themudmixtures,chemicalforml)lationsanddrillingprocessutilizedatthiswellPADaresubstantiallythesameasthoseutilizedatthewellwheretheattachedwasteanalyticalsweregenerated.February 8, 2011 Form 26R: Section B2b WASTE SAMPLING METHODS

j. All samples were obtained as grab type samples with a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are composited within the storage production tank or tank battery at each well site where gas production
is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP permitted waste disposal facilities on different schedules determined by individual well characteristics. Grab samples of the composited fluids were obtained at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. Samples were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory.

- Flowback samples were composited to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process at various times and combined into a composite sample for analyses at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites.
In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness of the composite sample and composite grid sample positions were varied to the extent possible. Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned and reused from well to well.I • February 9, 2011 Fonn 26R: Section 83a WASTE GENERATION PROCESS Pit Water "Drill Fluids" Remnant drill fluids are generated
in the well bore during the penetration of the drill stem as it intercepts both ground water and fonnation fluids. These fluids are brought to the surface along with the drill cuttings, pieces of the intercepted rock strata, by the return flow system of the drilling process

. Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. Fluids are currently stored in closed containers to be processed for reuse. Flowback: "Fracing Fluid" Flowback
is produced from all fluids that flow back to surface during the "hydrofracing" process which occurs under pressure and results in the setting of a propant within the fonnation fractures. Production Fluid "Brine" During the production of natural gas, fonnation pressures bring remnant frac fluids, during the initial production phase, and fonnation fluids to the surface along with produced gas.- COUNTYB ote: . Process producing waste: Gas well produced fluids (brines) are typically produced in conjuction with natural gas. These fluids are brought to the surface utilizing either · mechanical or physical lift procedur _ es.

Well I.·D.# . (various) '\\/ -0.- COUNTY A I

I I I I I

....... , ........ I I I I / / /

Well I. D.# (various) \ I .:-o ..... /II' / / / / / Mobile Tank Truck ------Landfill or**Tre.u.+~U\+** 'P\W\t

(.)**~** w :r: 0 (/) z 0**~** 1-**~** 0 a.. (/') z**~** 1-**~illf ~~~-** **~** ....**~ ~**  ill§**il~ ~~** **~** I a i _ lC**~** Cl -**~] ~~** **~ ~~** **~** 15J**~I ~~**  I I**~ ~** **~**GEOCHEMICALTESTINGEnvironmentalandEnergyAnalysisWednesday,February23,2011RICKBONAZZARESOURCEMANAGEMENTSERVICES65FENTONROADINDIANA,PA15701RE:26RAnalysisDearRICKBONAZZA:OrderNo.:01101912·.GeochemicalTestingreceived1sample(s)on1128/2011fortheanalysespresentedinthefollowingreport.TherewerenoproblemswiththeanalysesandallQCdatametNELAC,EPA,andlaboratoryspecificationsexceptwherenotedintheCaseNarrativeorLaboratoryResults.Ifyouhaveanyquestionsregardingthesetestsresults,pleasefeelfreetocall.Sincerely,TimothyW.BergstresserDirectorofTechnicalServices2005NCenter.AveSomersetPA15501814/443-1671814/445-6666FAX:814/445-6729Geochemical Testin!! CLIENT: Project: Lab Order: RESOURCE MANAGEMENT SERVICES 26R Analysis GII01912

Date: 23-Feb-11 CASE NARRATIVE No problems were encountered during analysis of this workorder, except if noted in this report. The ethylene gycol analysis was subcontracted
to Free Col Labs. A copy of the subcontractor's laboratory report is **enclo~ed** with this Analytical Report. The radiological analysis was subcontracted
to Pace Analytical.
A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. Legend:
J - Indicates an estimated value

. U - The analyte was not detected at or above the listed concentration, which is below the laboratory quantitation limit. B - Analyte detected in the associated Method Blank Q- Qualifier QL -Quantitat

i on Limit DF- Dilution Factor R- RPD outside accepted recovery limits E- Value above quantitation range ** -Value exceeds Action Limit H - Method Hold Time Exceeded MCL

- Contaminant Limit

I.D
. 56-00306 PA DEPLaboratoryResultsGeochemicalTestingDate:23-Feb-11::.,•.-..----.·:.:.-:.:::.-::.··.·:.::-:··:·..:·.. -:...-:-·=:-_-::-.":.CLiENT:LabOrder:RESOURCEMANAGEMENTSERVICESGll01912ClientSampleID:EcklesWell8590HFBRMS111/28Project:26RAnalysisLabID:G1101912-001Matrix:AQUEOUSAnalysesResultINORGANICNON-METALSAciditytopH8.2-38INORGANICNON-METALSAlkalinitytopH4.5150PHYSICALTESTSSpecificConductance111000PHBYSM4500H+BLabpH6.52INORGANICNON-METALSTotaldissolvedsolids97500PHYSICALTESTSTotalsuspendedsolids545INDICATORORGANICPARAMETERSBOD5-day1350FinishDatemme212/201118:10REACTIVECYANIDEReactivecyanideINDICATORORGANICPARAMETERSChemicalOxygenDemandINORGANICNON-METALSBromideChlorideSulfateINORGANICNON-METALSMBASINORGANICNON-METALSAmmoniaNitrogen-DistilledINORGANICNON-METALSNitrate-NitriteINDICATORORGANICPARAMETERSPhenolicsREACTIVESULFIDEReactivesulfideINORGANICNON-METALS<0.25580046157100<100<0.2569.10.53<1000.50SampledBy:ClientCollectionDate:1/28/20II1:I0:00PMReceivedDate:1/28/20117:08:50PMQLQUnitsSM·2310B(4A)0mg/LCaC03SM18232085mg/LCaC03EPA120.1SM4500-H+B0suSM2540C100mgllSM2540D25mg/LSM5210B300mgll0mg/LSW846CH.70.25mg/KgHACH800050mgllEPA300.010.0mg/L50mgll100mgllSM5540C0.25Hmg/LasLASEPA350.1.5.00mgllasNEPA353.20.05mgllasNEPA420.1100IJ9/LSW846CH.70.25mg/KgEPA351.2DFDateAnalyzedAnalyst:LNW214120119:44:00AMAnalyst:LNW213/20114:50:00PMAnalyst:LNW2/3120114:50:00PMAnalyst:LNW2/3120114:50:00PMAnalyst:.KLS51131120117:10:00AMAnalyst:KLS51131120117:17:04AM3003000.9955050505500.99Analyst:SAG1128120116:50:00PM1128/20116:50:00PMAnalyst:SAG219/20114:58:00_PMAnalyst:MGV21112011Analyst:CAS1131/20112:51:00PM1/31/20112:51:00PM1/31120112:51:00PM.Analyst:CAS212120112:30:00PMAnalyst:SLY2/101201112:51:01PMAnalyst:SLY2/1/201110:14:21AMAnalyst:KMW2/4120111:05:00PMAnalyst:SLY2/3120112:50:00PMAnalyst:SLYLD.56-00306PADEPLaboratory Results Geochemical Testing

Date: 23-Feb-11 CLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES Gl101912
Client Sample ID: Eckles Well 8590H FB RMS 1/1/28 Project: 26R Analysis Lab ID: Gl101912-001 Matrix: AQUEOUS Analyses INORGANIC NON-METALS Total Kjeldahl Nitrogen INORGANIC METALS Iron, dissolved INORGANIC METALS Mercury TCLP METALS Mercury TCLP METALS Arsenic Barium Cadmium Chromium Lead Selenium Silver INORGANIC METALS Aluminum Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Lithium Magnesium Manganese Molybdenum Nickel Selenium Silver Sodium Strontium Zinc
Result 61.4 10.5 <0.20 <0.0002 <0.020 3190 <0

. 002 < 0 . 010 <0

. 020 <0

. 020 < 0 . 005 < 1 . 0 <0.20 2850 < 0 . 010 2 . 58 <0

. 020 7470 < 0.10 0 . 544 < 0 . 10 46.9 <0.20 60

. 3 638 3.47 < 0.20 < 0.10 < 0.20 < 0 . 050 1510 1350 < 0.10 Sampled By: Client Collection Date: 1/28/2011 1:10:00 PM Received Date: 1/28/2011 7:08:50 PM QL Q EPA 351.2 20

. 0 EPA 200.7 0.05 SM 31128 0.20 EPA 7470 0 . 0002 EPA 6010 0.020 150 0 . 002 0.010 0.020 0.020 0.005 EPA200.7 1 . 0 0.20 5.00 0.010 0.50 0.020 25.0 0.10 0 . 050 0 . 10 0.50 0 . 20 5.00 1 . 0 0 . 10 0 . 20 0.10 0 . 20 0 . 050 100 2.50 0 . 10 Units mgllas N !f!g/L IJQ/1,. mgll mgll mgll mgll mgll mgll mgll mgiL mgiL mgll mgll mgll mgll mg/L mgll mgll mgll mgll mg/L mgll mg/L mgll mg/L mg/L mg/L mgll mg/L mgll mg/l mg/L DF 20 500 1 1 1 1 10 10 500 10 10 10 250 10 10 10 10 10 500 10 10 10 10 10 10 500 250 10 Date Anal _ yzed Analyst: SLY 2/1/2011 2:35:48 PM Analyst: MS 2/1/2011 12
: 26:00 PM Analyst: JEK 2/1/2011 12:53

: 33 PM Analyst: JEK 2/1/201112:49:15 PM Analyst: MS 2/11201112

: 18
: 00 PM 2131201110

: 31

: 00 AM 2/11201112

: 18
: 00 PM 2/11201112:18

: 00 PM 2/1/201112:18

: 00 PM 2/1/2011 12:18

: 00 PM 211/201112

: 18
: 00 PM Analyst: MS 211/201112

: 22

: 00 PM 21112011 12:22

: 00 PM 213/2011 10:35:00 AM 211/2011 12:22:00 PM 211/201112:22

: 00 PM 21112011 12:22:00 PM 213/2011 10:38:00 AM 2/1/201112:22:00 PM 211/2011 12:22

: 00 PM 2/1/2011 12
: 22:00 PM 2/1/2011 12
: 22:00 PM 2/1/2011 12
: 22:00 PM 2/3/2011 7:41

: 00 PM 2/1/2011 12
: 22

: 00 PM 2/112011 12
: 22

: 00 PM 2/1/2011 12
: 22

: 00 PM 2/1/2011 12
: 22

: 00 PM 2/1/2011 12
: 22

: 00 PM 2/1/201112

: 22

: 00 PM 2/3/2011

7 : 41 :00 PM 2/3/2011 10
: 38

: 00 AM 2/1/201112

: 22:00 PM - · - -- · -·- ... ·····-----

. - -· - -·- ------

- · -- - -· -- -· - · · - - · · · · . - - - **-- -;;**  **~~~~ D**  - ... ..

"' **~**

*- "

- u

**~** <

" 1 . 0 . 56.()()306 PA OEP n - - .. **~** ,. ..,.Laboratory Results Geochemical Testing

Date: 23-Feb-11 -- ---- ----- ----------- CLIENT: RESOURCE MANAGEMENT SERVICES Client Sample ID: Eckles Well 8590H FB Lab Order: 01101912

RMS 1/1/28 Project: 26R Analysis Sampled By: Client Lab ID: 01101912-001 Collection Date: 1128/2011 1:10:00 PM Matrix: AQUEOUS Received Date: 1128/2011 7:08

: 50 PM Analyses
Result QL Q Units DF Date Analyzed INORGANIC METALS

EPA 200.7 Analyst: MS Hardness (SM 23408) 18500 10.0 mg!LCaC03

10 2/1/201112:22:00 PM INORGANIC METALS EPA200.8 Analyst: JEK Thorium

<200 200 IJ9IL 200 2/8/2011 3:03

: 00 PM Uranium

<200 200 IJQ/L 200 2/8/2011

3 : 03

: 00 PM TCLP HERBICIDES EPA8151 Analyst

. : NPT 2,4,5-T

< 0.0050

0 . 0050 mg!L 100 21312011 10

: 39:30 PM 2,4-0

<0

. 020

0 . 020 mg!L 100 213/2011 10

: 39

: 30 PM Silvex

<0

. 0050

0 . 0050 mg/L 100 2/3/2011 10:39

: 30 PM Surr: 2,4-Dichlorophenyl acetic acid 74.9 28

. 5-130 %REC 100 2/3/2011 10:39:30 PM TCLP PESTICIDES EPA8081 Analyst: NPT Chlordane

< 0.010 0.010 mg!L

10 2/212011 7:07:46 PM Endrin

<0

. 00050

0 . 00050 mg!L

10 2/212011 7:07:46 PM Lindane <0.00050

0 . 00050 mg!L

10 2/2/2011

7 : 07

: 46 PM Methoxychlor <0.00050

0 . 00050 mg!L

10 2/212011

7 : 07:46 PM Toxaphene

<0

. 020 0.020 mg!L

10 2/212011

7 : 07:46 PM Heptachlor (and its epoxlde)

< 0 . 0010

0 . 0010 mg!L

10 21212011

7 : 07

: 46 PM Surr: Decachlorobiphenyl

96

. 3 5-156 %REC

10 2/212011 7:07

: 46 PM Surr: Tetrachloro-m-xylene

64

. 3 15

. 9-102 %REC

10 2/2/2011 7:07:46 PM SEMI-VOLATILE COMPOUNDS: TCLP EPA8270 Analyst: JB 2-Methylphenol

< 100 100 IJ9/L

10 2/4/2011 6:48:00 AM 2,4-Dinitrotoluene

< 100 100 IJg/L

10 2/4/2011 6:48

: 00 AM Hexachlorobenzene

< 100 100 1J91l

10 2/4/2011 6:48:00 AM Hexachlorobutadiene

< 100 100 IJ91L

10 2/4/2011

6 : 48

: 00 AM Hexachloroethane

< 100 100 IJ9/L

10 2/4/2011

6 : 48

: 00 AM Nitrobenzene

< 100 100 IJ9/L

10 2/4/2011

6 : 48

: 00 AM Pentachlorophenol

< 500 500 IJ9/L

10 2/4/2011

6 : 48:00 AM Pyridine

< 200 200 IJg/L

10 2/4/2011

6 : 48:00

. AM 2,4,5-Trichlorophenol

< 100 100 IJQ/L

10 2/4/2011

6 : 48:00 AM 2,4 ,6- Trichlorophenol

< 100 100 IJ91L

10 2/4/2011 6:48:00 AM 3,4-Methylphenol

< 100 100 IJg/L

10 2/4/2011 6:4.8:00 AM Surr: 2,4,6-Tribromophenol

101 5-137 %REC

10 2/4/2011 6:48

: 00 AM Surr

: 2-Fiuorobiphenyl

49.3 27

. 7-95.1 %REC

10 2/4/2011 6:48

: 00 AM Surr: 2-Fiuorophenol

60

. 4 5-104 %REC

10 2/4/2011

6 : 48

: 00 AM Surr: Nitrobenzene-05

86.7 16-101 %REC

10 2/4/2011

6 : 48

: 00 AM Surr: Phenol-06

51.7 5-106 %REC

10 2/4/2011

6 : 48

: 00 AM Surr

: p-Terphenyl-014

38

. 8 25

. 4-133 %REC

10 2/4/2011

6 : 48

: 00 AM VOLATILE ORGANIC COMPOUNDS EPA8260 Analyst: SJM Benzene

< 1 . 0 1.0 IJQIL 1/31/2011

7 : 02

: 00 PM -------------------·--

· · - ------
- -·- ----- ·-·----

- - - --- ·· --- ·----- -- ---------·--

- -- **~ ~** 

0 <

1 I. D . 56 - 00306 PA DEPLaboratory Results Geochemical Testing

Date: 23-Feb-11 CLIENT: RESOURCE MANAGEMENT SERVICES Client Sample ID: Eckles Weli8590H FB Lab Order: 01101912

RMS 111/28 Project: 26R Analysis Sampled By: Client Lab ID: Gll0l912-00l Collection Date: 1128/2011

1 : 10
: 00 PM Matrix: AQUEOUS Received Date: l/28/2011 7:08:50 PM - - ·-- ·- ·· - - --- -· -· -·
· -- - · - - - ---·-·

- · ----

- ---- Analyses
Result QL Q Units DF Date Analyzed VOLATILE ORGANIC COMPOUNDS

EPA 8260 Analyst: SJM Toluene

1 . 1

1 . 0 **~giL** 1/3112011 7:02

: 00 PM Surr: 1 , 2-Dichloroethane-d4

108 70-130 %REC 113112011

7 : 02:00 PM Surr

: 4-Bromofluorobenzene

102 70-130 %REC

1 1/3112011

7 : 02:00 PM Surr: Toluene-dB

95

. 3 70-130 %REC

1 1/3112011

7 : 02

: 00 PM VOLATILE ORGANIC COMPOUNDS: TCLP EPA 8260 Analyst: JAW Benzene

<50
50 **~**

50 2/3/20114:31

: 00AM Carbon Tetrachloride

<50
50 j.lg/l

50 213120114:31:00AM Chlorobenzene

<50
50 **~giL**

50 213/2011
4 : 31:00 AM 1 , 1-Dichloroethene

<50
50 **~ll**

50 213120114:31:00AM 1 ,2-Dichloroethane

<50
50 IJgll

50 2/312011 4:31:00 AM 1 A-Dichlorobenzene

<50
50 IJg/L

50 2/3120114:31:00AM Trichloromethane

<50
50 **~giL**
50 2/312011
4 : 31

: 00 AM Methyl Ethyl Ketone

< 250 250 jJgll

50 21312011 4:31:00 AM Tetrachloroethene

<50
50 **~giL**

50 21312011
4 : 31:00 AM Trichloroethene

<50
50 **~giL**
50 21312011
4 : 31

: 00 AM \tinyl Chloride

<50
50 **~ll**

50 21312011
4 : 31:00 AM Surr: 1 ,2-Dichloroethane-d4

90

. 7 70-130 %REC

50 21312011 4:31:00 AM Surr

: 4-Bromofluorobenzene

99

. 7 70-130 %REC

50 213120114:31:00AM Surr: Dibromofluoromethane

92.0 70-130 %REC

50 213120114

: 31

: 00AM Surr: Toluene-dB

97.0 70-130 %REC

50 2/312011 4:31:00 AM INDICATOR ORGANIC PARAMETERS
EPA 1664 Analyst: DSZ Oii&Grease

436

!) mg/l

1 . 08 2/112011
8 : 48:00 AM NOTES: J - Unable to obtain a stable weight within specified limits due to sample matrix. Value is estimated. VOLATILE ORGANIC COMPOUNDS EPA8015 Analyst: SUB Ethylene Glycol
<550 550 mgll. 217/2011 RADIOLOGICAL TESTING

EPA 900.0 Analyst: SUB Gross Alpha
7229 +-1675

3 . 00 pCVL 2/10/2011 Gross Beta
1048 +- 748

4 . 00 pCVL 2/10/2011 RADIOLOGICAL PARAMETERS

EPA 903

. 1 Analyst: SUB Radium 226
1638 +- 307

1 . 00 pCVL 2/18/2011 RADIOLOGICAL PARAMETERS

EPA 904.0 Analyst: SUB Radium 228

199 +- 39.2

1 . 00 pCVL

1 2/18/2011 INORGANIC$ NON-METALS

EPA 9040 Analyst: **~LL** Corrosivity Characteristic

6 . 55

1 . 00 su 1/31/2011 FLASH POINT

EPA 1010 Analyst: RLL **~** ..

<" ...

* "

- u

... <

"' 1.0. 56-00306 PA DEP Page 6 of7Laboratory Results Geochemical Testing CLIENT: Lab Order: Project: Lab ID: Matrix: RESOURCE MANAGEMENT SERVICES Gll01912 26R Analysis Gl101912-001 AQUEOUS

Date: 23-Feb-1

I Client Sample ID: Eckles Well 8590H FB RMS 1/l/28 Sampled By: Client Collection Date: l/2812011
I: 10
: 00 PM Received Date: l/28/2011 7:08:50 PM - ----··· ••- ·· ·-----·
·-

-

-

- -

• P•

0

• •••

•
- **~-**

0

· - ....

- .. **-- ---** 

**<** 0. 0.

0 Oo **---**
**·-** -- --- --

- ·-

• --

- -

-

- -- -- ·- -·

-

-

- Analyses FLASH POINT Flashpoint TCLP ZHE EXTRACTION TCLP,ZHE TCLP EXTRACTION Extraction Fluid Used Final pH Initial pH pH with HCI pH with water TCLP, non-volatile TCLP,ZHE Result QL Q EPA 1010 >200 10.0 EPA 1311 RL

1 . 0 EPA 1311 NA

0 3 . 1 1.0 NA 1.0 NA 1.0 NA 1.0 NA

0 NA

0 Units ·F DF Date Analyzed Analyst: RLL 212/2011 Analyst: RLL 113112011 Analyst: RLL 1/31/2011 1/31/2011 1131/2011 1/3112011 113112011 1 1/3112011 1 113112011 .. .. .. --· · **--~**

- . .. -- -·-.
- - - - - --·- ------

·- - - · --

· - - -

.. -- I. D. 56-00306 PA DEP

# ~pennsylvania - OEPAIITM9fT OF fNVIRONMENTAL PROTECTION 

# COMMONWEALTH OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL

PROTECTION 

# BUREAU OF WASTE MANAGEMENT 

# FORM26R CHEMICAL

ANALYSIS

OF RESIDUAL

WASTE ANNUAL REPORT BY THE GENERATOR typed or legibly printed

In the spaces provided.

If additional space 

# is 

# necessary, identify each attached sheet as Form 26R, reference the 

# Item number and identify

the date 

# prepared.



# The date on attached sheets needs 

# to match the date noted below. General Reference 

# Company 

# c. Number 

# of Solid or Uquld Phases 

# of Separation 

# Une2 brineish 

# 1 10# Describe each phase 

# of separation

• .::;liQ:s.:U::::id=---------------- 

# -1 -

I ' I2540-PM-BWM0347Rev.1/2011a.wastepennitnumber(s)forb.c.PA0095273AddressUne1AddressUne1AddressCityStateZIPMunicipalityPhonewasteshippedtoprocessingorai51POlia•0cuydgalprocessesCountyIndianasteve@pabrine.comyear.0lb0ton(checkone)a.Solidwasteprocessingordisposalfacilitybeingutilized.b.c.d.t,lameAddressUne1AddressUne1AddressCityStateZIPMunicipalityTitleCounty(checkone)0ton(checkone)-2-NoN/A2540-PM-BWM0347 Rev.112011 I certify, under penalty of law, that

I have personally examined and am familiar with the lnfonnation submitted In this Annual Report and all attached documents and that based upon my Inquiry of those individuals Immediately responsible for obtaining the lnfonnation,

I verify that the submitted lnfonnation
is true, accurate and complete to the best of my knowledge.

I understand that the submiaalon of false lnfonnation herein Is made subject to the penalties of 18 Pa. C.S. §4904, relating to unsworn falsification to authorities, which Include fine and Imprisonment Check the following,
If applicable: 0

I certify the lnfonnation required In Section B-1, General Properties was supplied to the Department for the year __ and has not changed. Fonn Submitted:

0 Form26R 0 Other (specify) Date Submitted: 0

I certify the lnfonnation required In Section B-2, Chemical Analysis was supplied to the Department for the year __ and has not changed. Fonn Submitted:

0 Form26R 0 Other (specify) Date Submitted: 0

I certify the lnfonnation required In Section **~.** Proceaa Description and Schematic, was supplied to the Department for the year_ and has not changed. Fonn Submitted: Date Submitted: Name of Responsible Official Bernhardt Kissel Signature

0 Form26R 0 Other (specify) Date

1 -3 -February 8, 2011 Form 26R: Section B2b WASTE SAMPLING METHODS

i · All samples were obtained as grab type samples with a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are composited within the storage production tank or tank battery at each well site where gas production
is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP permitted waste disposal facilities on different schedules determined by individual well characteristics. Grab samples of the composited fluids were obtained at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. Samples were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. Flowback samples were composited to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process at various times and combined into a composite sample for analyses at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites.
In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness of the composite sample and composite grid sample positions were varied to the extent possible. Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned and reused from well to well.j . February 9, 2011 Form 26R: Section B3a WASTE GENERATION PROCESS Pit Water "Drill Fluids" Remnant drill fluids are generated
in the well bore during the penetration of the drill stem as it intercepts both ground water and formation fluids. These fluids are brought to the surface along with the drill cuttings, pieces of the intercepted rock strata, by the return flow system of the drilling process. Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. Fluids are currently stored in closed containers to be processed for reuse. Flowback: "Fracing Fluid" Flowback
is produced from all fluids that flow back to surface during the "hydrofracing" process which occurs under pressure and results in the setting of a propant within the formation fractures. Production Fluid "Brine" During the production of natural gas, formation pressures bring remnant frac fluids, during the initial production phase, and formation fluids to the surface along with produced gas.Well I. D.# (various) Well I.D.# . (various) **~b"-** . -W.- /0, /1' COUNTY A I\ I \ / Well I. D.# (various) \ I ::::0/ \ I //I' \ I / \ I // \ I // . . \ I / Well I. D.# (various) \ 1 // \\/ / \ I /

- COUNTYB -0- / ' / **~** ---- . Q "/ **Ofl"'"'~~~~ ~**  Mobile Tank Truck **~r-oc9vc..-\-** tOJ\ Ocu **th~~~** \tlAkS

**~:** ( **J~** S brine (1YP.) ote: . Process producing waste: Gas well produced fluids (brines) are typically produced' in conjuction with natural gas. These fluids are brought to the surface utilizing either mechanical or physical lift procedur _ es.

----- Landfill or **Treu.+~U\+** 'PlGV\t

(.) i w :c () C/') z 0 **~** 1- c:: 0 a.. (/) z **~** 1- **~illf ~~~~l**  .. **~ ~** 

i I **~ ~**  **~~ ~** 

; i -

i **~ ~**  **~** 1 **~~ ~**  **~I** m **~!**

z **~** ... **~** f' ::2 j!; uTESTINGEnvironmentalandEnergyAnalysisFriday,February04,2011RICKBONAZZARESOURCEMANAGEMENTSERVICES65FENTONROADINDIANA,PA15701RE:26RAnalysisDearRICKBONAZZA:OrderNo.:G1012653GeochemicalTestingreceived1sample(s)on12/22/2010fortheanalysespresentedinthefollowingreport.TherewerenoproblemswiththeanalysesandallQCdatametNELAC,EPA,andlaboratoryspecificationsexceptwherenotedintheCaseNarrativeorLaboratoryResults.Ifyouhaveanyquestionsregardingthesetestsresults,pleasefeelfreetocall.Sincerely,TimothyW.BergstresserDirectorofTechnicalServicesPage1of62005NCenterAveSomersetPA15501814/443-1671814/445-6666FAX:814/445-6729Geochemical Testine: CLIENT: Project: Lab Order: RESOURCE MANAGEMENT SERVICES 26R Analysis GI012653

Date: 04-Feb-11 CASE NARRATIVE No problems were encountered during analysis of this workorder, except if noted in this report

. REVISED REPORT (2/4/11): Sample description changed. The ethylene glycol analysis was subcontracted
to Free Col. A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. The radiological analysis was subcontracted
to Pace Analytical.
A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. Legend

: J - Indicates an estimated value. U -The analyte was not detected at or above the listed concentration, which is below the laboratory quantitation limit. 8 - Analyte detected in the associated Method Blank Q -Qualifier QL -Quantitation Limit OF -Dilution Factor R- RPD outside accepted recovery limits E- Value above quantitation range ** -Value exceeds Action Limit H -Method Hold Time Exceeded MCL- Contaminant Limit Page 2 of 6

1.0
. 56-00306 PA DEPLaboratory Results Geochemical Testing

Date: 04-Feb-1

I ----

. **--- ---·~** 

-

-- --·------· -----·-----· CLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES G1012653
Client Sample ID: Flickinger Well 8447H RMS 1112/20 Project: 26R Analysis Lab ID: 01012653-001 Matrix: AQUEOUS Analyses INORGANIC NON-METALS Acidity to pH 8 . 2 INORGANIC NON-METALS Alkalinity to pH 4 . 5 PHYSICAL TESTS SpecifiC Conductance PH BY SM 4500 H+B Lab pH INORGANIC NON-METALS Total dissolved solids PHYSICAL TESTS Total suspended solids INDICATOR ORGANIC PARAMETERS BOD 5-day Result 260 20 73400 5 . 34 48200 45 280 Finish Date/Time 12127/2010 07

: 15 REACTIVE CYANIDE Reactive cyanide

< 0 . 25 INDICATOR ORGANIC PARAMETERS Chemical Oxygen Demand
5700 INORGANIC NON-METALS Bromide

206 Chloride
29000 Sulfate

<50 INORGANIC NON-METALS MBAS

< 0 . 50 INORGANIC NON-METALS Ammonia Nitrogen

- Distilled

40

. 7 INORGANIC NON-METALS Nitrate

- Nitrite

< 0 . 05 INDICATOR ORGANIC PARAMETERS Phenolics

< 100 REACTIVE SULFIDE Reactive sulfide

0 . 91 INORGANIC NON-METALS Sampled By: Client Collection Date: 12/20/2010 10:30

: 00 A Received Date: 12/22/2010

6 : 42:19 AM ·- - -- --

- - · --- --·- ----·-- --- -- ·-·---· --·- -- -- ------- QL Q Units DF Date Analyzed SM 23108(4A) Analyst: LNW 1213112010 12

: 19

: 00 PM 0 SM 18 23208 5 EPA 120.1 SM4500-H+B 0 SM 2540C 100 SM 2540D 5 SM 5210 B 60 0 SW846 CH

. 7 0.25 HACH 8000 200 EPA 300.0 5.0 25 50 SM 5540C 0.50 EPA 350.1 10

. 0 EPA 353.2 0 . 05 EPA420.1 100 SW 846 CH.7 0 . 25 EPA 351.2 Page 3 of6 mgiLCaC03 mg/LCaC03 **~Jmhoslcm** su mg/L mg/L mg/L mg/L mg/Kg mg/L mg/L mg/L mg/L mg/L as LAS mg/L as N mg/L as N **~Jg/L** mg/Kg

5 60 60 Analyst: LNW 12130/2010

8 : 17

: 00 PM Analyst: LNW 12130/2010

8 : 17

: 00 PM Analyst: LNW 12130/2010

8 : 17

: 00 PM Analyst: KLS 1212212010

8 : 15

: 00 AM Analyst: KLS 1212212010

8 : 31

: 52 AM Analyst: MMR 1212212010

6 : 30

: 00 AM 1212212010

6 : 30:00 AM Analyst: SAG 1.01 12129/2010

2 : 42:00 PM Analyst: LCC 20 1/3/2011 Analyst: CAS 25 12129/2010 12

: 46:00 AM 25 12/29/2010 12:46:00AM 25 12129/2010 12

: 46

: 00 AM Analyst: KMW 10 1212212010 10

: 15

: 00AM Analyst: SLY 100 1/4/2011 12

: 22

: 44 PM Analyst: SLY 12/27/2010 12

: 07

: 42 PM Analyst: SAG 12/28/2010 11:56

: 00 AM Analyst: MMR 1 . p1 12129/2010 12

: 45

: 00 PM Analyst: SLY I.D. 56-00306 PA DEPLaboratory Results Geochemical Testing

Date: 04-Feb-11 CLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES 01012653
Client Sample ID: Flickinger Wen 8447H RMS 1112/20 Project: 26R Analysis Lab ID: 01012653-001 Matrix: AQUEOUS Analyses INORGANIC NON-METALS Total Kjeldahl Nitrogen INORGANIC METALS Iron, dissolved INORGANIC METALS Mercury INORGANIC METALS Aluminum Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Lithium Magnesium Manganese Molybdenum Nickel Selenium Silver Sodium Strontium Zinc Hardness (SM 2340B) INORGANIC METALS Thorium Uranium HERBICIDE ANALYSIS 2
, 4
, 5-T 2,4-D Silvex Surr

: 2 , 4 - Dichlorophenyl acetic acid Result 32

. 7 100 < 0
. 20 < 0 . 1 <0

. 02 1170 < 0.001 2.32 < 0
. 002 2980 < 0 . 01 0 . 044 0 . 04 113 <0

. 02 117 212 9.06 < 0 . 02 0.02 < 0 . 02 < 0
. 005 16200 1040 0 . 09 8310 < 50

. 0 < 50

. 0 < 0 . 47 < 1 . 9 < 0.47 57

. 3 Sampled By: Client Collection Date

: 12/20/2010 10:30

: 00 A Received Date: 12/22/2010

6 : 42

: 19 AM QL Q Units EPA 351.2 20

. 0 mg/L as N EPA200.7 0.05 mg/L SM 31128 0 . 20 1J91l EPA 200.7 0.1 mg/L 0.02 mg/L 5.00 mg/L 0 . 001 mgll 0.05 mg/L 0.002 mg/L 1.0 mg/L 0 . 01 mg/L 0 . 005 mg/L 0.01 mg/L 0.05 mgll 0.02 mg/L 10

. 0 mg/L 1 . 0 mg/L 0.01 mg/L 0.02 mg/L 0.01 mg/L 0.02 mgll 0
. 005 mg/L 100 mg/L 5 . 00 mg/L 0
. 01 mg/L 10

. 0 mg/L CaC03 EPA200.8 50

. 0 IJg/L 50

. 0 1Jg/L EPA 8151 0 . 47 IJg/L 1 . 9 IJQ/L 0.47 IJQIL 28

. 5-130 %REC Page 4 of6
DF 20 1 1 500 10 1 1 1 500 10 1 500 500 1 10 50 50 9 . 43 9.43 9.43 9 . 43 Date Analyzed Analyst: SLY 12129/2010

9 : 26

: 05 AM Analyst: MS 12129/2010

2 : 40

: 00 AM Analyst: JEK 12127/2010
11

: 15

: 54 AM Analyst: MS 12128/2010

6 : 54

: 00 PM 12128/2010 6:54:00 PM 12129/20104

: 05:00 PM 12128/2010

6 : 54:00 PM 12128/2010

6 : 54:00 PM 12128/2010

6 : 54

: 00 PM 12/29/20104

: 32:00 PM 12128/2010

6 : 54:00 PM 12128/2010

6 : 54:00 PM 12128/2010 6:54:00 PM 12128/2010

6 : 54

: 00 PM 12128/2010

6 : 54:00 PM 12129/2010

4 : 05:00 PM 12129/2010

4 : 32

: 00 PM 12128/2010 6:54:00 PM 12128/2010 6:54

: 00 PM 12128/2010 6:54:00 PM 12128/2010 6:54:00 PM 12128/2010

6 : 54

: 00 PM 12129/2010 4:05:00 PM 12129/2010

4 : 05

: 00 PM 12/28/2010

6 : 54

: 00 PM 12129/2010

4 : 32:00 PM Analyst: JEK 12/28/2010 5:29:00 PM 12128/2010

5 : 29

: 00 PM Analyst: TEW 12130/2010

3 : 35

: 05 AM 12/30/2010

3 : 35

: 05 AM 12/30/2010

3 : 35:05 AM 12/30/2010

3 : 35

: 05 AM I. D. 56-00306 PA DEPLaboratory Results Geochemical Testing CLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES GIOI2653 Project: 26R Analysis Lab ID: GI012653-00I Matrix: AQUEOUS Analyses
Result QL Q PESTICIDE ANALYSIS EPA8081 Chlordane

<4

. 9 4

. 9 Endrin

< 0 . 24

0 . 24 Gamma BHC (Lindane)

< 0 . 24 0.24 Heptachlor epoxide

<0

. 24 0.24 Methoxychlor

< 0.24

0 . 24 Toxaphene

< 9.7 9.7 Surr: Decachlorobiphenyl

71

. 6 5-156 Surr: Tetrachloro-m-xylene

51

. 6 15.9-102 SEMI-VOLATILE COMPOUNDS

EPA 8270 2,4,5- Trichlorophenol

<9.4 9.4 2,4,6- Trichlorophenol

<9

. 4 9.4 2,4-0initrotoluene

<9.4 9.4 2-Methylphenol

<9

. 4 9

. 4 Hexachlorobenzene

<9.4 9.4 Hexachlorobutadiene

<9.4

9 . 4 Hexachloroethane

<9.4 9.4 Nitrobenzene

<9

. 4 9

. 4 Pentachlorophenol

<47
47 Pyridine

<47
47 3,4-Methylphenol

<9.4 9.4 Surr: 2,4,6- Tribromophenol

103 5-137 Surr: 2-Fiuorobiphenyl

84.7 27.7-95.1 Surr: 2-Fiuorophenol

71

. 4 5-104 Surr: Nitrobenzene-d5 0.0800 16-101

s Surr. Phenol-d6

77.4 5-106 Surr. p-Terphenyl-d14

61

. 8 25.4-133 Date: 04-Feb-11 Client Sample ID: Flickinger We118447H RMS 1112/20 Sampled By: Client Collection Date: 12/20/2010 10:30:00 A Received Date: 12/22/20

I 0 6:42:19 AM Units

D F Date Analyzed Analyst: TEW r.rg/L

4 . 85 1/4/201111

: 14:00 PM r.rg/L 4.85 1/4/201111:14:00 PM !Jg/L

4 . 85 1/4/201111

: 14:00 PM r.rg/L

4 . 85 1/4/2011 11:14:00 PM r.rg/L

4 . 85 1/4/201111

: 14:00 PM r.rgll 4.85 1/4/201111

: 14:00PM %REC

4 . 85 1/4/2011 11

: 14:00 PM %REC 4.85 1/4/201111

: 14:00 PM Analyst: NPT r.rg/L 0.94 12129/2010 4:42:00 PM r.rg/L 0.94 12129/2010

4 : 42:00 PM IJQ/L 0.94 12129/2010 4:42:00 PM r.rg/L 0.94 12129/2010 4:42

: 00 PM r.rg/L

0 . 94 12129/2010 4:42:00 PM r.rg/L

0 . 94 12129/2010 4:42

: 00 PM r.rg/1,. 0.94 12129/2010 4:42:00 PM r.rg/L 0.94 12129/2010 4:42

: 00 PM r.rg/L 0.94 12129/2010 4:42:00 PM !Jg/L 0.94 12129/2010 4:42

: 00 PM r.rg/L 0.94 12129/2010 4:42:00 PM %REC 0.94 12129/2010

4 : 42

: 00 PM %REC 0.94 12129/2010 4:42:00 PM %REC

0 . 94 12129/2010 4:42

: 00 PM %REC 0.94 12/29/2010 4:42:00 PM %REC 0.94 12129/2010

4 : 42

: 00 PM %REC 0.94 12/29/2010 4:42:00 PM VOLA TILE ORGANIC COMPOUNDS

EPA 8260 Analyst: SJM 12/22/2010 5:42:00 PM 12/22/2010

5 : 42:00 PM 12/2212010 5:42:00 PM 1,1-0ichloroethene

< 1 . 0 1,2-0ichloroethane

< 1 . 0 1,4-0ichlorobenzene

< 1 . 0 Benzene

< 1 . 0 Carbon Tetrachloride

< 1 . 0 Chlorobenzene

< 1 . 0 Methyl Ethyl Ketone

< 5.0 Tetrachloroethane

< 1 . 0 Toluene

2.9 Trichloroethane

< 1 . 0 Trichloromethane

< 1.0 Vinyl Chloride

< 1 . 0 1.0 1 . 0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1 . 0 1.0 1.0 Page 5 of6 r.rg/L r.rg/L r.rg/L r.rg/L r.rg/L !Jg/L r.rg/L r.rg/L r.rg/L IJQ/L r.rg/L IJQ/L

1 1212212010 5:42

: 00 PM 1 12/22/2010 5:42

: 00 PM 12122/2010

5 : 42

: 00 PM 12/22/2010 5:42:00 PM 12/2212010 5:42

: 00 PM 12/22/2010 5:42:00 PM 12/2212010 5:42

: 00 PM 12/22/2010 5:42

: 00 PM 1212212010 5:42

: 00 PM 1.0 . 56-00306 PA OEPLaboratory Results Geochemical Testing .. ·----4----·-

- .... ·-- --.
- .... - - **··~--- -·~**  **~** .. -.. ... . - _ ,. _____

• •-•••., •••-·

- ••

• •• ••···

- • • **••• --**  **-~ •••·•** 

**•** •• rCLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES Gl012653 Project: 26R Analysis Lab ID: 01012653-001 Matrix: AQUEOUS Analyses VOLATILE ORGANIC COMPOUNDS Surr: 1 ,2-Dichloroethane-d4 Surr: 4-Bromoftuorobenzene Surr: Toluene-dB INDICATOR ORGANIC PARAMETERS Oil & Grease VOLA TILE ORGANIC COMPOUNDS Result 93.2 99

. 9 99

. 0 <5 Ethylene Glycol

< 500 RADIOLOGICAL TESTING Gross Alpha
2714 +- 893 Gross Beta

733 +- 943 RADIOLOGICAL PARAMETERS Radium 226
2824 +- 555 QL Q EPA 8260 70-130 70-130 70-130 EPA 1664 5 EPA 8015 500 EPA 900.0 3.00 4.00 EPA 903.1 1 . 00 Date: 04-Feb-11
---- - - - .... -·

· - - .. ---·---- --- - --- ----
-· - Client Sample ID: Flickinger Well 8447H RMS 1112/20 Sampled By: Client Collection Date: 12/20/2010 10:30

: 00 A Received Date: 12/22/2010 6:42:19 AM Units DF %REC %REC %REC mg/L

1 . 08 mgll pCi/L pCi/L pCiiL Date Analyzed Analyst: SJM 1212212010

5 : 42

: 00 PM 1212212010 5:42

: 00 PM 1212212010 5:42

: 00 PM Analyst: DSZ 1212312010

1 : 35

: 00 PM Analyst: SUB 1/3/2011 Analyst: SUB 12130/2010 1213012010 Analyst: SUB 1/1212011 RADIOLOGICAL PARAMETERS

EPA 904.0 Analyst: SUB 1/17/2011 · Radium 228

254 +- 80

. 4 1.00 INORGANICS NON-METALS EPA9040 Corrosivity Characteristic

5 . 15

1 . 00 FLASH POINT

EPA 1010 Flashpoint

>200
10

. 0 Page 6 of6 pCi!L su •f Analyst: RLL 12127/2010 Analyst: RLL 1/4/2011 I. D. 56-00306 PA DEP**2~M-BWM0347** Rev. 112011 COMMONWEALTH OF PENNSYLVANIA **DEPARTMENTOFE~RONMENTALPROTECnON** BUREAU OF WASTE MANAGEMENT FORM26R CHEMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT BY THE GENERA TOR fonn must accurately completed. All must be typed or legibly printed the spaces provided.
If additional space Is necessary, Identify each attached sheet as Fonn 26R, reference the Item number and Identify the date prepared. The date on attached sheets needs to match the date noted below. General Reference 287.54 c. Appearance
State PA First Name Ben Company Mailing Address Une - 1 -

EPA Generator2540-PM-BWM0347 Rev.1/2011 a. b. A schematic of the as specified in the Instructions,
Is attached. c. If portions the

are

for a confidentiality claim, as described In the instructions,
is attached. b. Facility Name Address Une 1 Address Une 1 Address City State ZIP Municipality c. Address Line 1 Address Line 1 Address City State ZIP Municipality c. Facility Contact Title Phone d.

to processing or disposal D cuyd D gal D lb -2- (check one) year. ton (check one) 0 ton (check one)

No NIA2540=PM::SWM0347 Rev. 1/2011 I certify, under penalty of law, that

I have personally examined and am familiar with the Information submitted In this Annual Report and all attached documents and that based upon my Inquiry of those lndMduals Immediately responsible for obtaining the Information,

I verify that the submitted Information
is true, accurate and complete to the best of my knowledge.

I understand that the submission of false Information herein is made subject to the penalties of 18 Pa. C.S. §4904, relating to unsworn falsification to authorities, which Include fine and Imprisonment Check the following,
If applicable: 0

I certify the Information required In Section B-1, General Properties was supplied to the Deparbnent for the year _and has not changed. Form Submitted:

0 Fonn26R 0 Other (specify) Date Submitted: 0

I certify the Information required In Section B-2, Chemical Analysis was supplied to the Deparbnent for the year _and has not changed. Form Submitted:

0 Fonn 26R D other (specify) Date Submitted: 0

I certify the Information required In Section **~.** Process Description and Schematic, was supplied to the Deparbnent for the year_ and has not changed. Form Submitted:

0 Fonn 26R Date Submitted: Name of Responsible Official Bernhardt Kissel Signature

0 Other (specify) Date

1 -3 -February 9, 2011 Form 26R: Section B 1 e GENERATOR KNOWLEDGE

i • All Form 26R Waste Forms have been compiled, and future testing has been scheduled, to obtain samples of each waste stream on a PAD by PAD basis. Sample analyses will be conducted every 5 years for each waste stream unless the process that generates any particular waste stream is substantially altered. Attached analytical results for this waste stream have been obtained from a similar waste stream producing waste from the same geologic formation as this 26R Report. Additionally, the mud mixtures, chemical **form~lations** and drilling process utilized at this well PAD are substantially the same as those utilized at the well where the attached waste analyticals were generated.February 8, 2011 Form 26R: Section B2b WASTE SAMPLING METHODS

I• All samples were obtained as grab type samples with a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are composited within the storage production tank or tank battery at each well site where gas production

is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP permitted waste disposal facilities on different schedules determined by individual well characteristics

. Grab samples of the composited fluids were obtained at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. Samples were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. Flowback samples were composited to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process at various times and combined into a composite sample for analyses at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites.
In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness of the composite sample and composite grid sample positions were varied to the extent possible. Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned and reused from well to well.I• February 9, 2011 Form 26R: Section B3a WASTE GENERATION PROCESS Pit Water "Drill Fluids" Remnant drill fluids are generated
in the well bore during the penetration of the drill stem as it intercepts both ground water and formation fluids. These fluids are brought to the surface along with the drill cuttings, pieces of the intercepted rock strata, by the return flow system of the drilling process. Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. Fluids are currently stored in closed containers to be processed for reuse. Flowback: "Fracing Fluid" Flowback
is produCed from all fluids that flow back to surface during the "hydrofracing" process which occurs under pressure and results in the setting of a propant within the formation fractures. Production Fluid "Brine" During the production of natural gas, formation pressures bring remnant frac fluids, during the initial production phase, and formation fluids to the surface along with produced gas.Well I. D.# (various) Well I. - D.# (various) '\/ )J( **~0~ ~~~**  COUNTY A I\ I \ / Well I. D.# (various) \ I ::::(:£/ \ I //I' \ I / \ I // \ I // . . \ I / Well I.D.# (various) \ 1 // '\/ / \ I / -o- / " ,----

- COUNTYB _,.

**~o,--** ( . **~** C( "/ **Fico.>~....\.. ~7**  **~** Mobile Tank Truck **~r-ob/.\x.:ho.l\** Ocu **t\\~~~** \f>AI,..S :• **~** ,

**'J~** S brine (1YP.) ote: Process producing waste: Gas well produced fluids (brines) are typically produced in conjuction wi . th natural gas. These fluids are brought to the surface utilizing either . mechanical or physical lift procedures.

_ :s:::: Road Transport -------Landfill or**Treu.+~(.J\+** '?lGV\t -

(.) **~** w :c (.) (/) z 0 **~** 1- 0:: 0 0.. (/) z **~** 1- **~~ n~**  I t! g

**~~** i i1 **~ i~**  I i **~** z **~ ~** GEOCHEMICAL TESTING Environmental and Energy Analysis Wednesday, February 23, 2011 RICK BONAZZA RESOURCE MANAGEMENT SERVICES 65 FENTON ROAD INDIANA, PA 15701 RE: 26R Analysis Dear RICK BONAZZA: OrderNo.: G1101912 Geochemical Testing received

1 sample(s) on 1/28/2011 for the analyses presented in the following report. There were no problems with the analyses and all QC data met NELAC, EPA, and laboratory specifications except where noted in the Case Narrative or Laboratory Results. If you have any questions regarding these tests results, please feel free to call. Sincerely, Timothy W. Bergstresser Director of Technical Services Paqe 1 of 7
2005 N Center Ave Somerset PA 15501 814/443-1671 814/445-6666 FAX: 814/445-6729 1.0. 56.00306 PA OEPGeochemical Testine: CLIENT: Project: Lab Order: RESOURCE MANAGEMENT SERVICES 26R Analysis Gll01912

Date: 23-Feb-11 CASE NARRATIVE No problems were encountered during analysis of this workorder, except if noted in this report. The ethylene gycol analysis was subcontracted
to Free Col Labs. A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. The radiological analysis was subcontracted
to Pace Analytical.
A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. Legend: NO
- Not Detected at the Quantitation Limit J - Indicates an estimated value. U -The analyte was not detected at or above the listed concentration, which is below the laboratory quantitation limit. 8 - Analyte detected in the associated Method Blank Q - Qualifier QL -Quantitation Limit OF -Dilution Factor R - RPD outside accepted recovery limits E - Value above quantitation range •• -Value exceeds Action Limit H - Method Hold Time Exceeded MCL- Contaminant Limit Page 2 of 7

J . D . 56-00306 PA DEPLaboratory Results Geochemical Testing

Date: 23-Feb-1

I .. - ·--- - - - - - --·--
- - .. -----·· - · . -··· --- ·· ... -- ·- -- ·--- -- - ---- - - · -· -· . CLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES G1101912
Client Sample ID: Eckles Well 8590H FB RMS 1/1/28 Project: 26R Analysis Lab ID: 01101912-001 Matrix: AQUEOUS Analyses Result INORGANIC NON-METALS Acidity to pH 8.2

-38 INORGANIC NON-METALS Alkalinity to pH 4.5

150 PHYSICAL TESTS Specific Conductance 111000 PH BY SM 4500 H+B Lab pH

6 . 52 INORGANIC NON-METALS Total dissolved solids 97500 PHYSICAL TESTS Total suspended solids

545 INDICATOR ORGANIC PARAMETERS BOD 5-day

1350 Finish DateiTime 2/2/2011 18:10 REACTIVE CYANIDE Reactive cyanide INDICATOR ORGANIC PARAMETERS Chemical Oxygen Demand INORGANIC NON-METALS Bromide Chloride Sulfate INORGANIC NON-METALS MBAS INORGANIC NON-METALS Ammonia Nitrogen

- Distilled INORGANIC NON-METALS Nitrate

- Nitrite INDICATOR ORGANIC PARAMETERS Phenolics REACTIVE SULFIDE Reactive sulfide INORGANIC NON-METALS <0.25 5800 461 57100 < 100 < 0.25 69.1 0.53 < 100 0.50 ·--·--··- .... - - ...... - - ---·--·-

··· -·---------- Sampled By: Client Collection Date: 1/28/2011
1: 1 0 : 00 PM Received Date: 1/28/2011 7:08:50 PM QL Q Units SM

· 23108(4A) 0 mgll CaC03 SM 18 23208 5 mg/l CaC03 EPA 120.1 1Jmhos/cm SM4500-H+B 0 su SM 2540 C 100 mgll SM 2540D 25 mg/L SM 5210 B 300 mg/L 0 mg/l SW846 CH.7 0.25 mg/Kg HACH 8000 50 mg/L EPA 300.0 10.0 mg/L 50 mg/L 100 mg!L SM 5540C 0 . 25 H mg/l as LAS EPA 350.1 . 5 . 00 mg/l as N EPA 353.2 0.05 mg/L as N EPA420.1 100 j.lg/l SW846 CH.7 0 . 25 mg/Kg EPA 351.2
DF Date Analyzed Analyst: LNW 2/4/2011

9 : 44:00 AM Analyst: LNW 2/3/2011
4 : 50:00 PM Analyst: LNW 2/3/2011 4:50:00 PM Analyst: LNW 2/3/2011 4:50:00 PM Analyst:

. KLS 5 1/31/20117

: 10

: 00AM Analyst: KLS 5 113112011 7:17

: 04 AM Analyst: SAG 300 1/28/2011 6:50:00 PM 300 0.99 5 50 50 50 5 50 0
. 99 1/28/2011 6:50

: 00 PM Analyst: SAG 2/9/2011 4:58:00 .PM Analyst: MGV 2/1/2011 Analyst: CAS 1/31/20112:51

: 00PM 1/31/2011 2:51

: 00 PM 1/31/2011 2:51:00 PM Analyst: CAS 2/2/2011 2:30

: 00 PM Analyst: SLY 2/10/201112

: 51

: 01 PM Analyst: SLY 2/1/201110:14

: 21 AM Analyst: KMW 2/4/2011 1:05:00 PM Analyst: SLY 2/3/2011 2:50

: 00 PM Analyst: SLY ----·------------ ______ _ __ _ _ .... _ ... ·- ·- **~ ~** 

**~** u

**~** <

"' I.D
. 56-00306 PA DEP Page 3 of 7Laboratory Results Geochemical Testing

Date: 23-Feb-1
1 CLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES Gll01912
Client Sample ID: Eckles Well 8590H FB RMS 1/l/28 Project: 26R Analysis Lab ID: Gl 101912-001 Matrix: AQUEOUS Analyses INORGANIC NON-METALS Total Kjeldahl Nitrogen INORGANIC METALS Iron

, dissolved INORGANIC METALS Mercury TCLPMETALS Mercury TCLP METALS Arsenic Barium Cadmium Chromium Lead Selenium Silver INORGANIC METALS Aluminum Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Lithium Magnesium Manganese Molybdenum Nickel Selenium Silver Sodium Strontium Zinc Result 61

. 4 10.5 <0.20 <0

. 0002 <0

. 020 3190 <0

. 002 < 0.010 <0

. 020 <0

. 020 <0.005 < 1.0 < 0.20 2850 < 0
. 010 2 . 58 <0

. 020 7470 < 0.10 0
. 544 < 0 . 10 46

. 9 < 0.20 60.3 638 3
. 47 < 0.20 < 0
. 10 < 0.20 <0

. 050 1510 1350 < 0.10 Sampled By: Client Collection Date: 1/28/2011

1 : 10
: 00 PM Received Date: 1128/2011

7 : 08:50 PM QL Q Units EPA 351.2 20

. 0 mg/L as N EPA200.7 0.05 !'lg/L SM 31128 0.20 IJg/1,. EPA 7470 0 . 0002 mg/L EPA6010 0 . 020 150 0.002 0.010 0 . 020 0.020 0 . 005 ** EPA200.7 1.0 0.20 5.00 0.010 0.50 0.020 25.0 0.10 0
. 050 0.10 0.50 0.20 5 . 00 1 . 0 0.10 0.20 0 . 10 0.20 0
. 050 100 2.50 0.10

mg/L mgll mg/L mg/L mg/L mgll mgiL mgll mgll mgll mgll mg/L mgiL mgll

· mgll mgll mgll mg/L mgll mgll mgiL mgll mgll mg/L mgll mgll mgll mgll mgll DF 20 500 1 1 10 10 500 10 10 10 250 10 10 10 10 10 500 10 10 10 10 10 10 500 250 10 Date Anal

. yzed Analyst: SLY 21112011

2 : 35

: 48 PM Analyst: MS 21112011 12:26:00 PM Analyst: JEK 21112011 12:53:33 PM Analyst: JEK 2111201112:49

: 15 PM Analyst: MS 21112011 12

: 18

: 00 PM 2131201110:31:00AM 2111201112

: 18

: 00 PM 21112011 12:18

: 00 PM 21112011 12

: 18

: 00 PM 2111201112:18

: 00PM 21112011 12

: 18

: 00 PM Analyst: MS 21112011 12

: 22

: 00 PM 21112011 12:22:00 PM 21312011 10

: 35

: 00 AM 211/2011 12:22

: 00 PM 21112011 12

: 22

: 00 PM 21112011 12:22

: 00 PM 21312011 10

: 38

: 00 AM 2111201112:22

: 00 PM 21112011 12

: 22

: 00 PM 21112011 12:22

: 00 PM 2/1/2011 12

: 22

: 00 PM 211/2011 12:22:00 PM 21312011

7 : 41

: 00 PM 21112011 12:22

: 00 PM 21112011 12

: 22

: 00 PM 211/2011 12:22

: 00 PM 2/1/2011 12

: 22

: 00 PM 2111201112:22

: 00 PM 2111201112:22

: 00 PM 21312011 7:41

: 00 PM 21312011 10

: 38

: 00 AM 2111201112

: 22:00 PM **-- -·--**  **-· --**  **·-~· --**  **------ ----** 

**--** -· - ·· - -- - - - -- - -- - - - - - -
- ----- - - **~---·** I. D . 56-00306 PA DEP Page 4 of 7LaboratoryResultsGeochemicalTestingCLIENT:LabOrder:RESOURCEMANAGEMENTSERVICESGll01912Project:26RAnalysisLabID:Gll01912-001Matrix:AQUEOUSAnalysesINORGANICMETALSHardness(SM2340B)INORGANICMETALSThoriumUraniumTCLPHERBICIDES2,4,5-T2,4-DSilvexSurr:2,4-DichlorophenylaceticacidTCLPPESTICIDESChlordaneEndrinLindaneMethoxychlorToxapheneHeptachlor(anditsepoxide)Surr:DecachlorobiphenylSurr:Tetrachloro-m-xyleneSEMI-VOLATILECOMPOUNDS:TCLP2-Methylphenol2,4-DinitrotolueneHexachlorobenzeneHexachlorobutadieneHexachloroethaneNitrobenzenePentachlorophenolPyridine2,4,5-Trichlorophenol2,4,6-Trichlorophenol3,4-MethylphenolSurr:2,4,6-TribromophenolSurr:2-FiuorobiphenylSurr:2-FiuorophenolSurr:Nitrobenzene-ciSSurr:Phenol-d6Surr:p-Terphenyl-d14VOLATILEORGANICCOMPOUNDSBenzeneResult18500<200<200<0.0050<0.020<0.005074.9<0.010<0.00050<0.00050<0.00050<0.020<0.001096.364.3<100<100<100<100<100<100<500<200<100<100<10010149.360.486.751.738.8<1.0QLQEPA200.710.0EPA200.8.200200EPA81510.00500.0200.005028.5-130EPA80810.0100.000500.000500.000500.0200.00105-15615.9-102EPA82701001001001001001005002001001001005-13727.7-95.15-10416-1015-10625.4-133EPA82601.0Page5of7Date:23-Feb-11ClientSampleID:EcklesWell8590HFBRMS1/l/28SampledBy:ClientCollectionDate:l/28/20111:10:00PMReceivedDate:1/28/20117:08:50PMUnitsmg/LCaC03IJ9/LIJg/Lmg/Lmg/Lmg/L%RECmg/Lmg/Lmg/Lmg/Lmg/Lmg/L%REC%REC1J9ILIJg/L1J9ILIJg/LIJg/LIJg/LIJ9/LIJgllIJ9/LIJ9/LIJ9/L%REC%REC%REC%REC%REC%RECIJg/LDF1020020010010010010010101010101010101010101010101010101010101010101010DateAnalyzedAnalyst:MS211/201112:22:00PMAnalyst:JEK218/20113:03:00PM218/20113:03:00PMAnalyst.:NPT213/201110:39:30PM2131201110:39:30PM213/201110:39:30PM213/201110:39:30PMAnalyst:NPT2/2120117:07:46PM212120117:07:46PM212120117:07:46PM212120117:07:46PM212120117:07:46PM212120117:07:46PM212120117:07:46PM2/2120117:07:46PM.Analyst:JB214120116:48:00AM214/20116:48:00AM214120116:48:00AM214/20116:48:00AM214/20116:48:00AM2/4/20116:48:00AM214/20116:48:00AM2/4/20116:48:00.AM214/20116:48:00AM214/20116:48:00AM2/4/20116:4.8:00AM2/4/20116:48:00AM2/4/20116:48:00AM214/20116:48:00AM2/4/20116:48:00AM214/20116:48:00AM214/20116:48:00AMAnalyst:SJM1/31/20117:02:00PMI.D.56-00306PADEPLaboratory Results Geochemical Testing

Date: 23-Feb-1

I · -- -----

- ---··--··------

- ----·-
-- ------
- ===== --·------ -:-.:.: :.::::::-====- ====--==-....:=::-: == ::- . :;:: CLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES G1101912
Client Sample ID: Eckles Well 8590H FB RMS 1/1128 Project: 26R Analysis Lab ID: G1101912-00I Matrix: AQUEOUS Analyses VOLATILE ORGANIC COMPOUNDS Toluene Surr: 1,2-Dichloroethane-d4 Surr: 4-Sromofluorobenzene Surr: Toluene-ciS Result
1 . 1 10S 102 95.3 VOLA TILE ORGANIC COMPOUNDS: TCLP Benzene

<50 Carbon Tetrachloride

<50 Chlorobenzene

< 50 1 ,1-Dichloroethene

< 50 1,2-Dichloroethane

< 50 1 ,4-Dichlorobenzene

< 50 Trichloromethane

< 50 Methyl Ethyl Ketone

< 250 Tetrachloroethene

< 50 Trichloroethene

< 50 Vinyl Chloride

< 50 Surr: 1,2-Dichloroethane-<14

90.7 Surr: 4-Bromofluorobenzene

99.7 Surr: Dibromofluoromethane

92.0 Surr: Toluene-ciS

97.0 INDICATOR ORGANIC PARAMETERS Oil & Grease

436 NOTES:

QL Q EPA 8260 1 . 0 70-130 70-130 70-130 EPA8260 50 50 50 50 50 50 50 250 50 50 50 70-130 70-130 70-130 70-130 Sampled By: Client Collection Date: 1/28120 II 1 : I 0:00 PM Received Date: 1/2812011 7:08:50 PM Units 1!9/L %REC %REC %REC **~Jg/L** 1!9/L 1!9/L 1!9/L 1!9/L 1!9/L 1!9/L 1!9/L 1!9/L 1!9/L 1!9/L %REC %REC %REC %REC DF Date Analyzed Analyst: SJM 1131/2011

7 : 02

: 00 PM 1/3112011

7 : 02:00 PM 1/3112011 7:02

: 00 PM 1/3112011 7:02:00 PM Analyst: JAW 50 213/2011
4 : 31:00 AM 50 21312011 4:31:00 AM 50 213/2011 4:31:00 AM 50 213/2011
4 : 31:00 AM 50 213/2011 4:31:00 AM 50 21312011 4:31:00 AM 50 21312011
4 : 31 :00 AM 50 21312011
4 : 31:00AM 50 2/312011 4:31 :00 AM 50 213/2011
4 : 31

: 00 AM 50 213/2011
4 : 31 :00 AM 50 21312011
4 : 31:00 AM 50 213/2011 4:31:00 AM 50 21312011
4 : 31:00 AM 50 213/2011 4:31 :00 AM EPA 1664 Analyst: DSZ 5 rng/L 1.0S 211/2011
S : 4S:OO AM J - Unable to obtain a stable weight within specified limits due to sample matrix

. Value is estimated

. VOLA TILE ORGANIC COMPOUNDS Ethylene Glycol

< 550 RADIOLOGICAL TESTING Gross Alpha
7229 +- 1675 Gross Beta

1 04S +- 7 4S RADIOLOGICAL PARAMETERS Radium 226
163S +- 307 RADIOLOGICAL PARAMETERS Radium 228

199 +- 39.2 INORGANICS NON-METALS Corrosivity Characteristic

6.55 FLASHPOINT EPA8015 550 m9/L EPA 900.0 3.00 pCi/L 4.00 pCi/L EPA 903.1 1.00 pCiiL EPA 904.0 1.00 pCi/L EPA 9040 1.00 su EPA 1010 Page 6 of 7 Analyst: SUB 217/2011 Analyst: SUB 2110/2011 2110/2011 Analyst: SUB 2118/2011 Analyst: SUB 2/18/2011 Analyst: RLL 1/31/2011 Analyst: RLL 1.0 . 56-00306 PA DEPLaboratory Results Geochemical Testing

Date: 23-Feb-/

I CLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES G1101912
Client Sample ID: Eckles Well 8590H FB RMS 1/l/28 Project: 26R Analysis Lab ID: 01101912-001 Matrix: AQUEOUS Analyses
Result FLASH POINT Flashpoint

>200 TCLP ZHE EXTRACTION TCLP,ZHE

RL TCLP EXTRACTION Extraction Fluid Used

NA Final pH
.

3.1 Initial pH

NA pH with HCI

NA pH with water

NA TCLP, non-volatile

NA TCLP,ZHE

NA Sampled By: Client Collection Date: 1/28/2011 1:10:00 PM Received Date: 1/28/2011 7:08:50 PM QL Q Units DF Date Analyzed EPA 1010 10.0 OF EPA 1311 1 . 0 EPA 1311 0 1.0 1.0 1.0 1.0 0 0 Page 7 of 7 Analyst: RLL 21212011 Analyst: RLL 1/3112011 Analyst: RLL 1/3112011 1 1/31/2011 1 113112011 113112011 1 1/31/2011 1 1/3112011 113112011
I. D . 56-00306 PA DEP