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# OAR Box 

# 1413 Prepped by Ollie Stewart



### Document

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# 37 ) 11-1-3 7 Docket Number: 

# A-94-5 2

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### NORT H DAKOT A STAT EDEPARTMEN

T O FHEALT

H AN D CONSOLIDATE

D LABORATORIES ENVIRONMENTA L HEALT H SECTIO N 

### Augus t 9 , 199 3
John Jambois , Presiden t Tecto n Product s 440 1 15t h Avenu e N W P.O . Bo x 271 2 Fargo , ND 58108-271 2 Re : Ai r Pollutio n Contro l Permi t t o Operat e Dea r Mr . Jambois : 120 0 Missour i Avenu e P.O . Bo x552 0 Bismarck , Nort h Dakot a 58502-552 0 Fa x#701-221-520 0



### Th e Departmen t issue d a Permi t t o Construc t o n Septembe r 9 , 1991 , t o Tecto n Product s fo r a windo wan d doo r lineal s plan t locate d i n Fargo , Nort h Dakota . O n Jul y15 , 1993 , th e facilit ywa s inspecte d b yDepartmen t personnel . Als o o n Jul y15 , 1993 , a complianc e tes t wa s conducte d a t th e facility . Th e tes t repor t fo r th e complianc e tes t whic h wa s receive d byth e Departmen t o n Augus t 5 , 1993 , indicate s complianc e wit h th e applicabl e requirements . Base d o n ou r revie wo f th e permi t application , th e Ai r Qualit y Effect s Analysis , th e Permi t t o Construct , th e result s o f th e inspection , and th e result s o f th e complianc e test , th e Departmen t hereb yissue s a Permi t t o Operat e fo r th e source . Th e Department' s issuanc e o f th e permi t i s contingen t upo n complianc e wit h applicabl e section s o f th e Nort h Dakot a Ai r Pollutio n Contro l Rule s a s wel l a s th e attache d conditions . Pleas e revie weac h conditio n carefull yand not e th e restriction s place d o n th e source . I f yo u hav e anyquestions , fee l fre e t o contac t thi s Department . Sincerely , 

# £.flfo£, Gar yD . Helblin g & Environmenta l Enginee r Ai r Qualit yManagemen t Branc h Div . o f Environmenta l Engineerin g GDHrgs h Ene : xc/enc : EPA , Denve r xc : Bil l Delmore , Lega l Counse l Pau l Govig , ED C Communit yHealt h Center , Farg o

Environmenta l Healt h Sectio n an d Enforcemen t 701-221-515 0 Environmenta l Engineerin g 701-221-518 8 Municipa l Facilities 701-221-521 0 

## 2 L Wast e Managemen t 701-221-516 6 Wate r Qualit y 701-221-521 0 

# S LP. 4



### •NORTH-DAKOTA
. STAT EDEPARTMEN T O FHEALT H AN D CONSOLIDATE D LABORATORIE S ENVIRONMENTA L HEALT H SECTIO N

AI R POLLUTIO NCONTRO L PERMI T T O OPERAT E 120 0 Missour i Avenu e P.O . Bo x552 0 Bismarck , Nort h Dakot a 58502-552 0 Fa x#701-221-520 0

Pursuan t t o Chapte r 23-2 5 o f th e Nort h Dakot a Centur yCode , an d th e Ai r Pollutio n Contro l Rule s o f th e Stat e o f Nort h Dakota , an d i n relianc e o n statement s an d representation s heretofor e mad e b yth e owne r designate d below , a Permi t t o Operat e i s hereb yissue d authorizin g suc h owne r t o operat e th e sourc e unit(s ) a t th e locatio n designate d below . Thi s Permi t t o Operat e i s subjec t t o al l applicabl e rule s an d order s no wo r hereafte r i n effec t o f th e Nort h Dakot a Stat e Departmen t o f Healt h an d Consolidate d Laboratorie s an d t o an ycondition s specifie d below : 1 . Owner :
A . Nam e Tecto n Product s
B . Addres s 440 1 15t h Avenu e N W P.O . Bo x 271 2 Fargo , N D 58108-271 2 2 . Permi t Numbe r M9300 1 3 . Installatio n Windo wan d Doo r Lineal s Plan t 4 . Installatio n Locatio n 440 1 15t h Avenu e N W Fargo , Nort h Dakot a Cas s Count y 5 . Expiratio n Date : Augus t ••'• 2 OV * 199 6 6 . Sourc e Unit(s) : Awindo wan d doo r lineal s plan t consistin g o f th e followin g equipment : 1 . Fiv e pultrusio n machines , Pulsta r Model s 80 4 an d 1606 . 2 . Mixin g roo m an d resi n bul k tan k roo m(4-6,000-gallo n storag e tanks) . Resi n consist s o f unsaturate d polyeste r resi n wit h styren e an d methy l methacrylate . 3 . On e matslitter , Pulsta r Mode l 782 4 4 . Fiv e cut-of f saws . 5 . Too l an d di e room . 6 . On e pain t booth .

Environmenta l Healt h Sectio n an d Enforcement 701-221-515 0 Environmenta l Engineerin g 701-221-518 8 Municipa l Facilities 701-221-521 0 

# 3 Wast e Managemen t 701-221-516 6 Wate r Quality . 701-221-521 0 

# 3P. 5 

### Page 2 o f 4 Permi t No . M9300 1 Th e facility

wil l utiliz e th

e followin

g ai r pollutioncontro l equipment :

v• • • • ..-•-.• • • ... . £ 

### 1 . ..Therma

l oxidize r fo

r th e contro l or volatil e organi c compounds . The exhaus t fo

r th e catalyti c oxidize r wil l be ventedt o the outside air . 2 . Cartridg e filte r collectio nfo r th e contro l o f particulat e matte r (fiberglass) . The exhaus t fo r th e cartridg e filte r collection wil l be vente

dbac k int o th

e building . CONDITION S 7 . A . EmissionLimits : Emissio nlimit s fro

m th e operationo f the majo r sourc e unit(s ) identifiedi nIte m 6 o f thi s Permi t t o Operat e (hereafte r referredt o a s "permit" ) ar e a s follows : Source * Ai r Emission Uni t Contaminan t Limi t •Therma l Oxidize r Styrene 0.528*lb/h r Methy l Methacrylat e 0.10 2 lb/h r Odor s 2 Odo r Concentration Unit s •Th e therma l oxidize r mus t als o contro l volatil e organi c compoun d emission s b

y at leas t 95 M B . Fugitiv

e Emissions : Al l reasonabl e precaution s shal l be takenb y the owner/operato r t o prevent and/o r minimiz e fugitiv e emission s t o th e outside ai r fro m th e operatio

no f the sourc e unit(s ) identifie

dunde r Ite

m 6 . C . EmissionInventor y Reports : Emissio

ninventor

y report s including , bu t not limite

dt o proces s informatio nregarding th

e amoun t an

d type s of ai r contaminant s emitte dshal l b e submittedt o the Department , upo

nrequest , o

nform s suppliedb

y th e Department . D . Sourc e Operations : The owner/operator shal l operat e the sourc e unit(s ) describedinIte m 6 of thi s permi t i naccordanc e wit h statements , representations , procedure s an dsupportin

g dat a containedinthe initia l application , an dan y supplementa l informatio

nor renewa l applications ) submittedthereafter . E . Alterations , Modification s o r Changes : An

y alteration , rebuilding , repairing , expansion , chang e i nth e metho do f operation , o r chang e o f locatio

no f th

e sourc e whic

hresult s i nthe emissiono f a n additiona l type or greate r amount o f ai r contaminant s o r whic h result s ina

nincreas e inth

e ambien t concentrationo f an y ai r contaminant , mus t b e reviewe

dan dapprovedb

y the Departmen t prio r t o the star t o f suchalteration , rebuilding , repairing , expansion , chang e inth

e metho do f operation , or chang e o f location .

*

### Paq e 3 o f 4 Permi t No . M9300 1 1 1 i nn nua v

anhhorli o fh o P. 6



# v F . Nuisanc e o r Danger : Thi s permi t s

maintenanc e o f a nuisanc e o r a dange r t o publi c healt h o r safety . G . Malfunctio n Notification : Th e owner/operato r shal l notif yth e Departmen t o f an ymalfunctio n whic h ca n b e expecte d t o las t longe r tha n twenty-fou r hour s an d ca n caus e th e emissio n o f ai r • (* ff 

### contaminant s i n violatio n o f applicabl e rule s an d regulations . / H . "^Storag e Tank s Requirement : Th e proposedthree-wa yballvalv e fo r •a • flVentinq-emissions fro mth e storage- m 

### tanks , 

### *"'-t ; 

### o' , 

### "' , 

### the w 

### ox'i'd*izer*-->S'hal*l ii 

### 'b

e A-fr""*-', installed-b ySeptembe r 15 , 1993 . ii/>yrii . Permi t Renewa l an d Invalidation : Thi s permi t shal l b e effectiv e

fro mth e dat e o f it s issuanc e unti l th e dat e specifie d i n Ite m5 unles s soone r suspended , revoke d o r surrendered . Applicatio n fo r renewa l o f thi s permi t shal l b e submitte d sixt yday s prio r t o suc h expiratio n date . Th e Departmen t shal l approv e o r disapprov e th e renewa l o f th e permi t withi n sixt yday s o f receip t o f th e renewa l application . J . Ne wSourc e Performanc e Standards : Th e owner/operato r mus t compl y wit h al l requirement s outline d i n 4 0 CF R Par t 60 , Subpar t V W - Standard s o f Performanc e fo r Polymeri c Coating s o f Supportin g Substrate s Facilities . K . Chang e o f Ownership : Thi s permi t ma yno t b e transferre d an d i s t o b e returne d t o th e Departmen t upo n th e destructio n o r chang e o f ownershi p o f th e sourc e unit(s) , o r upo n expiration , suspensio n o r revocatio n o f thi s permit . L . Righ t o f Entry : An ydul yauthorize d officer , employe e o r agen t o f th e Nort h Dakot a Stat e Departmen t o f Healt h an d Consolidate d Laboratorie s ma yente r an d inspec t an yproperty , premis e o r plac e a t whic h th e sourc e liste d i n Ite m3 o f thi s permi t i s locate d a t an ytim e fo r th e purpos e o f ascertainin g th e stat e o f complianc e wit h th e Nort h Dakot a Ai r Pollutio n Contro l Rules . Th e Departmen t ma yconduc t test s an d tak e sample s o f ai r contaminants , fuel , processin g material , an d othe r material s whic h affec t o r ma yaffec t emission s o f ai r contaminant s fro man ysource . Th e Departmen t shal l hav e th e righ t t o acces s an d cop yan yrecord s require d b yth e Department' s rule s an d t o inspec t monitorin g equipmen t locate d o n th e premises . M . Othe r Regulations : Th e owner/operato r o f th e sourc e unit(s ) describe d i n Ite m6 o f thi s permi t shal l compl ywit h al l Stat e an d Federa l environmenta l law s an d rules . I n addition , th e owner/operato r shal l compl ywit h al l loca l burning , fire , zoning , an d othe r applicabl e ordinances , codes , rule s an d regulations . N . Permi t Issuance : Thi s permi t i s issue d i n relianc e upo n th e accurac yan d completenes s o f th e informatio n se t fort h i n th e application . Th e condition s o f thi s permi t herei n become , upo n th e effectiv e dat e o f thi s permit , enforceabl e b yth e Departmen t pursuan t t o an yremedie s i t no whas , o r ma yi n th e futur e have , unde r th e Nort h Dakot a Ai r Pollutio n Contro l Law , NDC C Chapte r 23

-_P 7 

### Pag e _4
_ Permi t No . _o f 4

M9300 1 25 . Eac h an

d everyconditio n o f thi s permi t i s a materia l par t thereof , an

d i s no t severable . FO R TH E NORT H DAKOTASTAT E DEPARTMEN

T O F HEALT H AN D CONSOLIDATE D LABORATORIE S

Dat e 

## J> 

# my ry. Dana K . Mount , Directo r Divisio n o f Environmenta l Engineering



# G 

# io

### P. 8

AI R QUALIT Y EFFECT S ANALYSI S

O F MARVI NWINDOW S WINDO W AN

D DOO R LINEAL S PLAN T FARGO , NORT H DAKOT

A CAS S COUNT Y

FOR

AI R POLLUTIONCONTRO L PERMI T T O CONSTRUC T

AUGUS T 199 1

Divisio n o f Environmenta l Engineerin g Nort h Dakot a Stat e Departmen t o f Healt h an d Consolidate d Laboratorie s 120 0 Missour i Avenue , Room30 4

Bo x 552 0 Bismarck , ND 58502-552 0



# * 1-

### Tabl e o f Content s P. 9



### Lis t o f Table s P'S'".'?? Lis t o f -Eigu^es-. 7 

### ^.^ ^ Par t 1 Propose d Projec t 1. 1 Projec t Descriptio n 1. 2 Applicabl e Ai r Pollutio n Contro l Rule s 1. 3 Executiv e Summaryan d Recommendation s . . Par t 2 Cohtro l TechnologyRevie w 2. 1 Finding s 2. 2 Allowabl e Emission s 2. 3 Expecte d Emission s Par t 3 Analysi s o f Impac t o n Ai r Qualit y... . 3. 1 Overvie w 3. 2 Ambien t Ai r Qualit yAnalysi s 3. 3 Summar y. Appendi x APermi t Applicatio n an d Supplementa l Informatio n Appendi x B Propose d Permi t t o Construc t Appendi x C Propose d Permi t t o Operat e Appendi x D Polic yfo r th e Contro l o f Hazardou s Ai r

Pollutan t Emission s i n Nort h Dakot a (Ai r Toxic s Policy ) Pag e i i ii i 1 1 4 7 1 0 1 0 1 2 1 5 1 7 1 7 1 8 2 1



# t

### P.1 0

Lis t o f Figure s
Pag e Figur e 1- 1 Plan t Locatio n 2 Figur e 2- 1 Proces s Flo wDiagram1 1

i i 

# °\P-1 1



### Lis t o f Table s
Pag e Tabl e 2- 1 Expecte d Emission s 1 6 Tabl e 3- 1 Maximu

mPredicte d Concentration s 2 4

ii i 

# 0P.1 2



### Par t 1 : PROPOSE D PROJEC T
1. 1 PROJEC T DESCRIPTION

A n applicatio n fo r a Permi t t o Construc t fo r a windo wan d doo r lineal s plan t t o b e locate d i n Fargo , Nort h Dakot a wa s felled wit h th e Departmen t o n July#l ^ 1991 : 

### r ; 

### b yMarvin > 

### Window s . Acopyo f th e applicatio n i s include d i n Appendi x A .
Th e doo r and windo wproduct s ar e produce d b ya proces s calle d pultrusion , wher e fiberglas s reinforcin g materia l i s pulle d throug h a resi n bath , i s saturate d an d enter s a heate d di e wher e th e polyeste r i s cure d int o a hardene d linea l shap e whic h i s the n cu t t o lengt h b

ya cut-of f saw . Th e plan t wil l b e locate d i n th e N W 1/ 4 o f Sectio n 34 , Townshi p 140N , Rang e 49W , o f Cas s County , Nort h Dakota . Mor e specifically , 15t h Avenu e an d 44t h Stree t NW , Fargo , Nort h Dakota .
Th e locatio n o f th e plan t i s shown i n Figur e 1-1 . Th e plan t wil l operat e 2 4 hour s pe r day/;rS^dayS;:.-per;.week , 5 0 weeks , pe r year .
Ai r contaminant s emitte d t o th e atmospher e wil l consis t o f volatil e organi c compound s emission s (styrene , methy l methacrylat e an d a smal l amoun t o f acetone) .
Th e facilit ywil l consis t basicall yo f th e followin g proces s equipment :P.1 3

Ra d tin t mdiutt t n m m «rh«t » onl y Undmaf h buiUtnf t ar « whom* t(f«ISH»> N '•••(M l •• ! latlftl f i.HII|llln l I'lX H .W-ti.l l filatlll^frfldl s l.h* - 1 ' '•" . " « l'<iMtl> ' '"" ' ' ' '' " ''* * " *' ' *' ' *" " "& " , t - " ' •»*'• THI S •*•* * COMfLIC l WIT H NATIONA L M* » ACCU*AC V STANOARO * FO R SAI C B YU S GCOlOGlCA t SU»VCY . OCNVCR . COiORAO O 9099%. O R RC«TO N VIRGINI A 77W

ANI > SIAI C WAIC R COMMISSION . lUSMAHCHNONI H llAKOI A "ktfeO I 0 A IOUII M IWM.IH«W« - lUfOCMAIHtl C MA*** AM I SVMBOl * i t AVAtAM l O N Mlt)Uft 1P. M

1
. PUl c tTru#!IiSln ^ 

### an d 5 tota l withi n 2 years) t

2 . Mixin g rooman d resi n bul k tank roo m(4-6,00 0 gallo n storag e tanks) . Resi n consist s o f styren e an d methy l methacrylate .
3 . On e matslitter , Pulsa r Mode l 7824 .
4 . Cut-of f saw s ( 2 initiall yand 5 tota l withi n 2 years) .
5 . Too l an

d di e room .
Th e facilit ywil l utiliz e th e following ai r pollutio n contro l equipment : '

1 . Catalyti c oxidize r fo r th e contro l o f volatil e organi c compounds . Th e exhaus t fromth e catalyti c oxidize r wil l b e vente d t o th e outsid e air .
2 . Bagfilte r fo r th e contro l o f particulat e matte r (fiberglass) . Th e exhaus t fo r th e bagfilte r wil l b e vente d bac k int o th e building .


# 13P.1 5



### 1. 2 APPLICABL E AI R POLLUTIONCONTRO L RULE S

1.2. 1 4 0 CF R Par t 60 ; Subpar t VWtfe E Standard s o f Performanc e fo r Polymeri c Coatin g o f Supportin g Substrates-Facilities ,
Th e federa l standar d applie s t o an yfacilit ywhic h conduct s coatin g operation s and an

yon-sit e coatin g mi x preparatio n equipmen t use d t o prepar e coating s fo r th e polymeri c coating o f supportin g substrate s and whic h begin s construction , modification , o r reconstructio n afte r Apri l 30 , 1987 . Th e process , whic h wil l b e conducte d at , th e propose d Marvi n Window s facility , i s subjec t t o thi s subpart .
1.2. 2 Chapte r 33-15-1 2 - Standard s o f Performanc e fo r Ne w Stationar ySource s
Thi s chapte r wil l appl yt o th e propose d facilit ya t suc h tim e a s 4 0 CF R Par t 60 , Subpar t V W i s incorporate d int o th e Nort h Dakot a Ai r Pollutio n Contro l Rules .
1.2. 3 Chapte r 33-15-0 2 - Ambien t Ai r Oualit vStandard s
Th e facilit ywil l no t emi t an ycriteri a pollutant s whic h ar e subjec t t o a specifi c ambien t ai r qualit ystandar d a s outline d i n thi s chapter . However , thi s chapte r ha s a sectio n tha t state s th e ambien t ai r shal l no t contai n othe r ai r contaminant s i n concentration s tha t woul d b e injuriou s t o huma n healt h o r well

being o r unreasonabl yinterfer e wit h th e enjoymen t o f propert ytha t \ M

### P.1 6

woul d injur e plan t o r anima l life . Th e Departmen t ma yestablish , o n a case-by-cas e basi s specifi c limit s o f concentratio n fo r thes e contaminants .

T o satisf ythi s sectio n o f Chapte r 33-15-02 , the Departmen t utilize d th e Polic yfo r th e Contro l o f Hazardou s Ai r Pollutan t Emission s i n Nort h Dakot a (Ai r Toxic s Policy) . Thi s polic yserve s a s a mechanis mt o evaluat e emission s o f hazardou s substance s from a give n sourc e and determin e wha t contro l measures , i f any , ar e appropriate . Acopyo f th e Ai r Toxic s Polic yi s include d a s Appendi x D .
Th e substance s whic h wil l b e evaluate d i n accordanc e wit h thi s polic yar e styren e and methy l methacrylat e (se e Par t 3) . Asmal l amoun t o f aceton e wil l b e use d (les s tha n 20 0 gal//ir ) fo r cleanup purposes . Aceton e emission s wil l b e minima l and , therefore , no t b e evaluate d wit h th e Ai r Toxic s Policy .
1.2. 4 Chapte r 33-15-0 3 - Restrictio n o f Emissio n o f Visibl e Ai r Contaminant s
Al l emissio n point s vente d t o th e outsid e ai r a t th e facilit yar e require d t o hav e an opacit yles s tha n o r equa l t o twent ypercen t (20% ) . 

# 1 5P.1 7



### 1.2. 5 Chapte r 33-15-0 7 - Contro l o f Organi c Compound s Emission s
Th e emission s o f organi c compound s gase s an d vapor s i s restricted , excep t froma n emergenc yvapo r blowdow n syste mo r emergenc yrelie f system , unles s thes e gase s an d vapor s ar e burne d b ya flare , o r a n equall yeffectiv e contro l devic e a s approve d b yth e Department .
1.2. 6 Chapte r 33-15-1 4 - Designate d Ai r Contaminan t Sources . Permi t t o Construct . Permi t t o Operat e
Thi s chapte r state s tha t certai n sourc e categorie s ar e designate d a s ai r contaminan t source s an d ar e require d t o obtai n a n Ai r Pollutio n Contro l Permi t t o Construc t an d Operat e fromth e Department . Surfac e coatin g operations , whic h th e Marvi n Windo w facilit ywil l conduct , i s on e o f th e sourc e categorie s liste d a s a n ai r contaminan t source . Therefore , Marvi n Window s i s require d t o obtai n a n Ai r Pollutio n Contro l Permi t t o Construc t and Operat e fo r th e facility .
1.2. 7 Chapte r 33-15-1 6 - Restrictio n o f Odorou s Ai r Contaminant s
Emission s o f objectionabl e odorou s substance s ar e restricte d t o tw o odo r concentratio n unit s outsid e th e propert yboundary .



# ioP.1 8



### 1. 3 EXECUTIVE SUMMARY AND RECOMMENDATION S
Marvi n Window s ha s applie d t o th e Nort h Dakot a Stat e Departmen t o f Healt h an

d Consolidate d Laboratorie s fo r a windo wan d doo r lineal s plan t t o b e locate d i n Fargo , Nort h Dakota .
Th^^lan ^ * b e a majo r source^*:E.;ofjfsEiany^sregulated;;:;-al r contaminant . Volatil e organi c compound s (VOC ) wil l b e emitted . A s a resul t o f th e amoun t o f VO C use d an d emitted , th e plan t i s subjec t t o 4 0 CF R Par t 60 , Subpar t V W - Standards;,of:,-Performanc e for-Polymeri c Coatin g o f Supportin g Substrate s Facilities . Specifi c emissio n rate s o f volatil e organi c compound s wer e evaluate d a s outline d i n th e Polic yfo r th e Contro l o f Hazardou s Ai r Pollutan t Emission s i n Nort h Dakot a (Ai r Toxic s Policy ) and th e Nort h Dakot a Ai r Pollutio n Contro l Rules .
Th e Departmen t ha s determine d fromit s revie wo f th e applicatio n tha t th e technologypropose d t o contro l emission s fromth e plant , a catalyti c oxidize r fo r VOC s and a baghous e fo r particulates , i s acceptabl e and th e emissio n rate s wil l compl ywit h th e emissio n rat e reductio n standard s specifie d i n 4 0 CF R Par t 6 0 Subpar t VW , th e Ai r Toxic s Policy , an d th e Nort h Dakot a Ai r Pollutio n Contro l Ruies .
Th e Departmen t conducte d ai r qualit ydispersio n modelin g o f th e styren e and methy l methacrylat e emission s fro mth e propose d plan t t o predic t th e impac t o n ai r quality . Bot h styren e an d methy l methacrylat e ar e classifie d b yth e Stat e o f Nort h Dakot a a s Grou p



# 1 >P.1 9



### 3 hazardou s ai r pollutants , i.e. , substance s whic h ar e no t carcinogeni c o r fo r whic h ther e i s insufficien t dat a t o establis h evidenc e o f carcinogenicity , bu t whic h nevertheles s caus e advers e healt h effect s a t high enoug h concentrations . Eac h Group 3 HA P i s associate d wit h a Maximu mAcceptabl e Ambien t Leve l (MAAL ) fo r 8

- hou r and/o r 1-hou r averagin g periods . Amaximu mground-leve l concentratio n les s tha n it s correspondin g MAAL require s n o furthe r revie wb

yth e Department , wherea s a maximu mground-leve l concentratio n whic h exceed s it s correspondin g MAA L require s furthe r revie wb

yth e Departmen t t o determin e i f emissio n control s o r ambien t monitorin g ar e necessary . I n addition , th e effect s o f multipl e Group 3 substance s emitte d fro mth e sam e sourc e ar e assume d t o b e additive . Therefore , fo r eac h Group 3 pollutant , th e rati o o f it s maximu mconcentratio n t o it s MAAL i s computed , and th e su mo f thi s rati o fo r al l pollutant s mus t b e les s tha n 1.0 . Th e result s o f th e dispersio n modelin g wer e compare d t o th e maximum acceptabl e ambien t level s (MAAL ) a s outline d i n th e Polic yfo r th e Contro l o f Hazardou s Ai r Pollutan t Emission s i n Nort h Dakot a (Ai r Toxic s Policy) . Thi s compariso n indicate d tha t th e impac t fromth e emission s i s wel l belo wth e MAAL s outline d i n th e Ai r Toxic s Polic y and th e su

m o f th e rati o i s les s tha n 1.0 .
Th e Departmen t o f Healt h and Consolidate d Laboratorie s find s th e Permi t t o Construc t applicatio n t o b e complet e and hereb yprovides , fo r publi c comment , a n assessmen t an d preliminar ydeterminatio n concernin g th e Marvi n Windows ' propose d plant . I n vie wo f th e result s o f th e evaluation , th e preliminarydeterminatio n o f th e Departmen t i s tha t a Permi t t o Construc t b e grante d fo r 8 

# I SP.2 0



### constructio n o f th e Marvi n Windows ' windo wan d doo r lineal s plan t provide d i t i s constructe d i n accordanc e wit h statements , representations , and informatio n containe d i n th e applicatio n an d supportin g documents .
Th e propose d Permi t t o Construc t i s include d a s Appendi x B . Th e propose d Permi t t o Operat e i s include d a s Appendi x C .



# °iP.2 1



### Par t 2 : CONTROL TECHNOLOG YREVIE W

2. 1 FINDING S i 

### Th e primar

y ai r contaminant s emittedwil l b e volatil e organi c compound s consistin g of styrene an

dmethy l methacrylate . i 

### Th e source s o f thes e ai r contaminant s fro m th e plan t wil l be th e resi nstation , di e station , bul k storag e tank , an dhig hdispersion mixe r (see Figur e 2-1) . The ai r contaminant s fro m thes e source s ar e vented t o a centra l contro l devic e (catalyti c oxidizer ) wit ha minimu m contro l efficienc

y o f 95% . The exhaus t fro m the catalyti c oxidize r wil l be vente dt o th e ambien t air . Due t o utilizationo f thi s contro l device , th e emission s fro

m th e facility

wil l compl y wit hthe applicabl e Stat e rule s an dpolicie s as wel l a s the Federa l rules .

A smal l amoun t o f aceton e wil l b

e use d(les s tha

n20 0 gal/yr ) for cleanu ppurposes . Th

e acetone emission s wil l be collecte dan dals o ventedt o the catalyti c oxidizer . Aceton e emission s wil l be minimal .
The source s o f particulat e emission s (fiberglass ) wil l be the sa w statio nan d matslitte r whichar e ventedt o a commo nbaghous e (see Figur e 2-1) . The exhaus t fro m the baghous e wil l be vente d bac k int o th

e building . Therefore , ther e wil l be n o particulat e emission s (fiberglass ) ventedt o the ambient air .


### 1 0 

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i- 1 i fIHROU S ROVIN G SUIIO N EXHAUS T (ID S I ) (ventp*. ' t c<ii.'.bieni ; EXHAUS T ( I D M 7 > " • (vente dbac k

int o building )
BAGHOUS E 

# I FIBERGLAS S PARIICUIAIE S (MISSIO N JSOCE H

A t SIAIIO M (vente dbac k int o building )

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### S^ >P.2 3

rp" 

### 2.2 ' ALLOWABL E EMISSION S

2.2. 1 4 0 CF R Par t 60 . Subpar t V W

Th e standar d fo r volatil e organi c compound s (VOC ) a s outline d i n 4 0 CF R Par t 60 , Subpar t W V - Standard s o f Performanc e fo r Polymeri c Coatin g o f Supporting Substrate s Facilitie s i s a s follows :

1 . Reduc e VO C emissiori s t o atmospher e fro mth e coatin g operatio n by^jfci ^ reduction " standard) ; o r
2 . Install , operate , an d maintai n a tpjtal enclosur e around th e coatin g operatio n an d ven t th e capture d VO C emission s fromth e tota l enclosur e t o a contro l devic e tha t i s a t leas t £ 0 percen t efficien t (alternativ e standard) . &



### /At>]y°. 3 . Fo r th e on-sit e coatin g mi x preparatio n equipment , ven t th e I ',•/„.- . VO C emission s t o a 95 % efficien t contro l device . Marvi n Window s ha s electe d t o instal l a catalyti c oxidize r tha t i s 9 5 percen t efficient ; therefore , th e facilit ywil l compl ywit h th e standard s outline d i n Subpar t VW .
2.2. 2 Odo r Chapte r 33-15-1 6 o f th e Nort h Dakot a Ai r Pollutio n Contro l Rules , Restrictio n o f Odorou s Ai r Contaminant s state s n o perso n ma y 

### C7\C KP.2 4



### discharg e int o th e ambien t ai r an yobjectionabl e odorou s ai r contaminan t whic h i s i n exces s o f tw o odo r concentratio n unit s outsid e th e propert yboundary .
Th e Handboo k o f Environmenta l Dat a o n Organi c Chemicals , Second Edition , indicate s th e odor wthreshol d ..^of*-..methy l -methacrylat e i s approximatel y0.3 0 mg/m ? an d th e odo r ^threshol d of w

### styren e is

approximatel y0.2 6 mg/m 3


### .
Th e facilit ywil l hav e a contro l devic e (catalyti c oxidizer ) fo r th e contro l o f volatil e organi c compound s wit h a n efficienc yo f 95% . Base d o n ai r qualit ydispersio n modeling , th e 1-hou r and 8

- hou r ambien t concentratio n fromth e facilit yi s expecte d t o b e 0.002 6 mg/m 3 

### an d 0.001 8 mg/m 3 

### , respectively , fo r methy l methacrylat e an d th e 1-hou r an

d 8-hour ambien t concentratio n from-th e facility , fo r styrerile , i s expecte d t o b e 0.1 3 mg/m 3 

### and 0.09 4 mg/m 3 

### , respectively . Thes e concentration s ar e al l belo wth e odo r detectabilit ylimi t mentione d previousl yfo r eac h pollutant .
Give n th e expecte d contro l efficienc yan d th e expecte d ambien t concentrations , th e facilit yshoul d compl ywit h th e odo r standard . Th e Departmen t wil l conduc t a n inspectio n o f th e facilit yan d conduc t odo r measurements , i f necessary , t o determin e complianc e wit h th e odo r standard .



### 1 3 

# 9 3P.2 5



### 2.2. 3 Visibl e Emission s Chapte r 33-15-0 3 o f th e Nort h Dakot a Ai r Pollutio n Contro l Rules , Restrictio n o f Visibl e Emissio n o f Visibl e Ai r Contaminant s require s opacit yt o les s than o r equa l t o twent ypercen t (20%) .
Th e emission s whic h wil l b e emitte d fro mth e facilit yar e a vapo r rathe r tha n particulat e matter ; therefore , th e opacit ywil l b e negligible , i f any .
2.2. 4 Contro l o f Organi c Compound s Chapte r 33-15-0 7 o f th e Nort h Dakot a Ai r Pollutio n Contro l Rules , Contro l o f Organi c Compound s Emission s state s tha t organi c compound s gase s i s restricted , excep t froma n emergenc yvapo r blowdown syste mo r emergenc yrelie f system , unles s thes e gase s and vapor s ar e burne d b ya flar e o r a n equall yeffectiv e contro l devic e a s approve d b

yth e Department .

Acatalyti c oxidize r wil l b e use d a t th e facilit ywit h a contro l efficienc yo f 95%. Th e Departmen t consider s thi s contro l device , whic h i s a n incinerator , a s equall yeffectiv e a s a flare , and therefore , th e facilit ywil l compl ywit h thi s rule .


# a4
1 4P.2 6



### 2. 3 EXPECTE D EMISSION S

2.3. 1 Stvren e and Methv l Methacrylat e
Expecte d emission s fo r styren e an d methy l methacrylat e wer e calculate d usin g EPAAP-42 , Compilatio n o f Ai r Pollutan t Emissio n Factors , Sectio n 4.12 , Polyeste r Resi n Plastic s Produc t Fabrication , Tabl e 4.12-2 .
Th e emissio n facto r outline d i n EP AAP-4 2 incorporate s plan t productio n rat e t o calculat e th e expecte d emissions . A s allowe d b y Sectio n 33-15-01-1 6 o f th e Nort h Dakot a Ai r Pollutio n Contro l Rules , Marvi n Window s ha s requeste d tha t informatio n o n productio n fee d stream s a t th e facilit yb e treate d confidential . Th e Departmen t ha s accepte d thi s informatio n a s confidential ; therefore , th e actua l calculation s o f th e expecte d emission s wil l no t b e shown i n thi s analysis . Th e Departmen t ha s calculate d th e expecte d emission s usin g a n EP AAP-4 2 emissio n facto r o f 5.5% . Th e result s o f th e expecte d emission s calculation s ar e summarize d i n Tabl e 2-1 .

1 5 

# 3£

### P.2 7

Tabl e 2- 1 Expecte d Emission s Ai r Contaminan t Styren e Methy l Methacrylat e Lb/h r 0.52 8 0.10 2 Ton/v r

1.5 8 0.3 1 Hour s ODeration/v r 6,00 0 6,00 0

1 6 

# ac ?P.2 8



### Par t 3 : ANALYSI S O F IMPAC T O NAI R QUALIT Y
3. 1 Overvie w
Th e Departmen t ha s conducte d a dispersio n modelin g analysi s t o evaluat e th e impac t o n ambien t ai r qualit yo f ai r pollutant s emitte d b

yth e propose d Marvi n Window s windo wand doo r lineal s plan t i n Fargo . Th e manufacturin g proces s wil l produc e significan t emission s o f styren e and methy l methacrylat e vente d t o th e ambien t air . Bot h pollutant s ar e regulate d a s hazardou s ai r pollutant s (HAPs ) b

yth e State' s Polic yfo r th e Contro l o f Hazardou s Ai r Pollutan t Emission s i n Nort h Dakota . Th e purpos e o f th e modelin g analysi s wa s t o determin e whethe r HA P emission s fro mth e propose d Marvi n Window s plan t wil l compl ywit h Nort h Dakota' s HAP contro l policy .

Bot h styren e an

d methy l methacrylat e ar e classifie d byth e Stat e o f Nort h Dakot a a s Group 3 hazardou s ai r pollutants , i.e. , substance s whic h ar e no t carcinogeni c o r fo r whic h ther e i s insufficien t dat a t o establis h evidenc e o f carcinogenicity , bu t whic h nevertheles s caus e advers e healt h effect s a t high enough concentrations . Eac h Group 3 HA P i s associate d wit h a Maximu mAcceptabl e Ambien t Leve l (MAAL ) fo r 8-hour and/o r 1-hou r averagin g periods . Amaximu m ground-leve l concentratio n les s tha n it s correspondin g MAA L require s n o furthe r revie wb yth e Department , wherea s a maximu m ground-leve l concentratio n whic h exceed s it s correspondin g MAA L require s furthe r revie wb yth e Departmen t t o determin e i f emissio n control s o r ambien t monitorin g ar e necessary . I n addition , th e 1 7 

# a TP.2 9



### effect s o f multipl e Grou p 3 substance s emitte d fro mth e sam e sourc e ar e assume d t o b e additive . Therefore , fo r eac h Group 3 pollutant , th e rati o o f it s maximu mconcentratio n t o it s MAAL i s computed , an d th e su mo f thi s rati o fo r al l pollutant s mus t b e les s tha n 1.0 . Styren e an d methy l methacrylat e wil l b e emitte d a t severa l differen t step s i n th e manufacturin g process . A t eac h step , th e pollutan t emission s wil l b e collecte d int o a n overhea d hoo d and vente d into ! a commo n catalyti c oxidize r t o contro l th e HA P emissions . Th e catalyti c oxidize r incinerate s th e pollutan t emissions , reducin g th e emission s by95% . Afte r exitin g th e catalyti c oxidizer , th e resultant , controlle d HA P emission s from al l source s combine d wil l b e vente d t o th e ambien t ai r throug h a singl e stack .
3. 2 Procedur e

Fo r modelin g problem s involving singl e sources , EPArecommend s th e us e o f screenin g model s tha t includ e a simplifie d treatmen t o f meteorologyand ar e faste r t o us e relativ e t o mor e refine d models . Th e purpos e o f a screening mode l i s t o provid e a conservativ e estimat e o f ai r qualit yimpac t fro ma simple , singl e sourc e usin g a minimumamoun t o f resource s an d time .
Becaus e th e Marvi n Window s HA P emission s essentiall yconstitut e a single-sourc e modelin g application , th e EPA-approve d screenin g mode l SCREE Nwa s utilized . SCREE Ncalculate s concentration s a t man ydownwin d distance s fo r a wid e variet yo f possibl eP.3 0



### meteorologica l condition s (e.g. , wind spee d an d atmospheri c stabilit yclass ) and determine s th e worst-cas e concentration s unde r worst-cas e condition s a t an ydownwind distance . SCREE N incorporate s th e sam e mathematica l algorithm s a s i n othe r Gaussian

plum e models . Som e o f th e specia l feature s o f other , mor e refine d dispersio n model s ar e als o availabl e i n SCREEN , including treatmen t o f elevate d terrai n and buildin g downwas h effects .
Buildin g downwas h effects , th e resul t o f usin g a stac k lowe r tha n Goo d Engineerin g Practic e (GEP ) height , tend t o increas e ground

leve l concentration s froma n elevate d sourc e becaus e th e turbulen t flo waround a buildin g mor e rapidl ytransport s th e stac k emission s t o th e ground . Sinc e Marvi n Windows ' stac k wil l b e les s tha n GE P heigh t wit h respec t t o th e proces s building , th e stac k wil l potentiall yb e affecte d b ybuildin g downwas h effects .
Th e SCREE Nmode l require s inpu t o f certai n sourc e dat a an d user selectio n o f certai n technica l options . Sourc e dat a require d b y SCREE Ninclud e pollutan t emissio n rate , stac k height , stac k diameter , stac k ga s exi t temperature , an d stac k ga s exi t velocity . T o accoun t fo r th e effect s o f buildin g downwash , th e dimension s o f th e buildin g adjacen t t o th e stac k mus t b e inpu t t o SCREEN . Sourc e an d buildin g dat a utilize d fo r th e Marvi n Window s analysi s ar e a s follows : *.,„• : ~ , _.-. • .. . . Mf

••*' : •'.•

• "' ' J'

•sr- S*gK ' sfe. » sfe r .vv'^k.i

- i ? > • ute- ' *•••• -' Sf ' , #- vf»

, s ? JEE#'| ' •# " <*' ; '* "

O, O Q 7 

### Styren e emissio n rat e = 0.6 7 g/sec ! Methy l methacrylat e emissio n rat e = 0.01 3 g/se c Stac k heigh t vv..a^,<,.,,..:= ; 

### .J ; 

### P,.6.7 . m? 

### 1 9 

# 3f lP.3 1

=

= S

=

=

=

= 

### 422' K 10.0 6 m/se c 0.6 6 m 7.0 1 m 77.7 2 m 53.3 4 m 

# "" 1 f f IS ; 

# 1 1; 

# I l |Exi t temperatur e £ ' t 

### I Exi t velocit y t Stack diamete r I Buildin g heigh t jBuilding lengt h I Buildin g widt h

Sourc e inpu t dat a wer e obtaine d fro m Marvi n Windows ' permi t application . Building dimension s wer e obtaine d from plan s provide d b yMarvi n Windows . Th e pollutan t emissio n rate s reflec t th e 95 % reductio n i n emission s accomplishe d b yth e catalyti c oxidizer . Becaus e th e horizonta l cros s sectio n o f th e buildin g deviate s slightl yfrom

a rectangula r shape , th e maximu mbuildin g lengt h an d widt h wer e use d i n th e modelin g analysis .
Sinc e acces s t o th e buildin g wil l no t b e restricte d b ya fenc e surroundin g th e plant , receptor s (location s a t whic h th e mode l calculate s pollutan t concentrations ) wer e include d o n Marvi n Windows ' propert yu p t o th e plan t building . Th e SCREE Nmode l calculate s concentration s a t downwind receptor s space d ever y10 0 meter s apar t fromth e stac k ou t t o a t leas t 100 0 meter s and wit h a large r spacin g beyond 100 0 meters . Becaus e th e terrai n nea r th e plan t i s relativel yflat , characteristi c o f th e Re d Rive r Valley , fla t terrai n wa s assume d i n th e modelin g analysis . Th e maximum concentratio n wa s interpolate d betwee n th e tw o receptor s wit h th e highes t concentrations .



### 2 0P.3 2



### Technica l option s inpu t wer e basicall yth e same a s thos e normall y applie d i n a mor e refine d modelin g analysi s (e.g. , gradua l plum e rise , stack-ti p downwash , buoyancy-induce d dispersion) , consisten t wit h EP Aguidance . An ambien t temperatur e o f 293" K (default ) wa s assume d (ambien t temperatur e i s th e onl ymeteorologica l variabl e tha t need s t o b e specifie d fo r SCREEN) . SCREE Nca n b e operate d i n eithe r rura l o r urba n mode . Becaus e th e propose d Marvi n Window s sit e wa s a borderlin e rural/urba n location , a s define d b yEP Afo r modelin g purposes , SCREE Nwa s execute d bot h i n rura l and urba n mode , and th e highe r o f th e tw o maximu mconcentration s wa s selecte d (rura l mod e produce d th e highe r concentrations) . Eight-hou r averag e concentration s wer e estimate d b ymultiplyin g th e modele d maximu m1-hour concentration s b y0.7 , a standar d averaging-perio d adjustmen t factor . Becaus e styren e an d methy l methacrylat e ar e no t natura l occurrin g and ther e ar e n o nearb ysources , backgroun d concentration s o f zer o wer e assumed .
3. 3 Result s
Result s o f th e ai r qualit ymodelin g analysi s fo r th e Marvi n Window s windo wan

d doo r lineal s plan t i n Farg o ar e summarize d i n Tabl e 3-1 . Result s ar e presente d fo r bot h styren e an d methy l methacrylate . Th e applicabl e MaximumAcceptabl e Ambien t Leve l (MAAL ) i s provide d fo r eac h averagin g perio d fo r compariso n wit h th e predicte d maximu m concentrations .
Tabl e 3- 1 show s tha t th e maximu mpredicte d styren e concentration s ar e wel l belo wth e MAAL s fo r styrene . Th e extremel ysmal l maximu m 

## 2 1 " 9 

## |



# 3 IP.3 3



### predicte d 8-hour methy l methacrylat e concentratio n i s fa r belo wth e 8-hou r MAA L fo r methy l methacrylat e an d i s actuall yles s tha n 1/100 0 o f th e 8-hour MAAL . Th e maximu m1-hour and 8-hour styren e concentration s ar e 3.1 % and 4.4 % o f thei r respectiv e MAALs . Th e maximum8-hou r methy l methacrylat e concentratio n i s 0.04 % o f it s 8

- hou r MAAL .
Thes e concentration s expresse d a s percentage s o f thei r respectiv e MAAL s ca n b e use d t o addres s th e additiv e effect s o f styren e and methy l methacrylate , bot h Group 3 hazardou s ai r pollutant s (HAPs) . Th e su mo f th e maximu

m8-hour styren e and methy l methacrylat e concentration s expresse d a s percentage s o f thei r MAAL s i s
4.4 % + 0.04 % = 4.44 % = 0.0444 ,
whic h i s les s tha n 1.0 , a s require d b yth e Department' s HA P policy . Th e additiv e effec t o f methy l methacrylat e i s ver ymino r becaus e o f it s smal l concentratio n relativ e t o it s MAAL .
Base d o n th e abov e results , th e styren e an d methy l methacrylat e emission s fromth e propose d Marvi n Window s plan t wil l compl ywit h th e Department' s HA P polic yan d requir e n o furthe r revie wb yth e Departmen t a s Grou p 3 HAPs .
Maximumconcentration s ar e predicte d t o occu r a t a distanc e o f 2 1 meter s fromth e stack , ver yclos e t o th e plan t building . Thi s woul d plac e th e maximu m concentration s nea r th e northeas t corne r o f th e building , sinc e th e stac k i s locate d ver yclos e t o th e 2 2 

# 3 aP.3 4



### northeas t corne r o f th e building . Th e s&£ong^bu4'ld4ng*»downwas h effect s ar e responsibl e fo r th e maximumconcentration s occurrin g s o clos e t o th e building . Maximu mconcentration s wil l occu r unde r condition s o f stron g wind s and neutra l atmospheri c stability , typica l o f a cloudy , wind ydayo r night . Unde r suc h meteorologica l conditions , th e stron g wind s inhibi t plum e ris e an d bend th e plum e ove r t o a relativel ylowheigh t abov e th e ground , producin g hig h ground-leve l concentrations .



# 3 3

### P.3 5

Tabl e 3- 1 Maximu mPredicte d Concentration s

(mg/m 3 

### )

Pollutan t Styren e 1-hour 8-hour Methy l methacrylat e 1-hour 8-hou r Predicte d Concentration * 0.1 3 0.09 4 0.002 6 0.001 8 MAA L 4.2 6 2.1 3

__—_ 

### 4. 1

* Abackground concentratio n o f zer o wa s assumed .

2 4 

# 3 4P.3 6



### Marvi nWindows Windo w an dDoo r Lineal s Plant

Permi t Applicatio

nan d Supplementa l Informatio n Appendi xA

Divisiono f Environmenta l Engineerin g Nort hDakot a Stat e Departmen t o f Healt h an dConsolidatedLaboratorie s 120 0 Missour i Avenue , Roo m 3 4 Bo x552 0 Bismarck , N

D 58502-552 0 

# 3 5P.3 7

. xPERMI T APPLICATIO N FO RAI RCONTAMINAN T SOURCE S • I NORT H DAKOT A STAT E DEPARTMEN

Tq f •CALT

O - AI R POLLUTIO N CONTRO L PR SFN 851 6 (A P IOO-I ) 5/8 5 Fl IT YIDENTIFICATIO N Nt*-* o f Fir m -v

Institutio n MARVI N WINDOW

S Owne r o r Officia l t o Contac t o n Ai r Pollutio n Matter s CHARLE S VANASS E Applicatio n Bein g Mad e B y (Name) :

_JOH N JAMBOI S Tlt. e •PRODUCT DEVELOP . Mailin g Addres s (Stree t & No. ) 804 3 24T H AVE
. SOUT H Plan t Locatio n (Stree t & No. ) 15T H AVE
. AN D 44T H ST

. NW
_ Lega l Descriptio n o t Plan t Sit e

{ ; . Sectio n ATTACHE D Twp . Rge . Lan d Are a a t Plan t Sit e

61.9 4 Acre s (or ) 2,698.106. 4 Sq . Ft . Titl e CO O - TECTO

N PROD

I Cit y MINNEAPOLI S Cit y FARG O Latitud e (Neares t Second ) 46 ° 53 ' 32 "
_

. MS L Elevatio n a t Plan t 894.0 0 USG S Longitud e (Neares t Secon e 96 ° 51 * 28 " Numbe r Employee s a t Loca l 4 5 WITHI N 2.YEAR S

_ GENERA L NATUR E O F BUSINESS : DESCRIB E NATURE O

F BUSINESS STANDARD INDUSTRIA L CLAS S IFICATIO N NUMBE

A PULTRUSION ; A PROCES S PRCOUCING WINDO W AN D DOO RLINEAL S DURIN G WHIC H A THERMOSE

T POLYESTERRESI N MATRI X I S REINFORCE

D WIT H MISCELLANEOU S

PIASTIC S 308 9 FIBERGIAS S MA

T AN D ROVING . SOURC E IDENTIFICATIO N AN D CATEGOR YO F EAC H SOURC E INCLUDE D O N THI S PERMI TAPPLICATION : / g n you r Identificatio n Numbe r (1,2 , 3 , etc. ) t o eac h Sourc e o r Permi t Unit . Lis t I D Numbe r an d Identif y devic e below , the n chec k

appropriat e categor y I n th e box t o righ t o f liste d devic e YOU R I O N O



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KTAN KROO M PUISTA R782 4 - MATSLITTE R CUT-OF F SAW

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SH 85) 6 I F APPLICATIO N I S FO R APERMI TTO CONSTRUCT , PROVID E TH E FOLLOWIN G OATA : .Sam e o f Installe ro rContrecto r MalIIn g Addres s Phon e Nippe r Star t Oote/Construc t ComoletEcr t Oat f SEP T 15 , 199 1 MA Y 15 , 199 2 ES TIMATE D Sf417 ;
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### (STO
s /bbo - ;iooo t COS T •950 , O F 00 0 EQUIPMEN TO R MODIFICATIO N (FO R PERMI TT O CONSTRUC T

BASIC EQUIPMEN T AI R POLLUTIO N CONTRO L EQUIPMEN TEXISTIN G •* $ O F CUTE O F APP. . NE WAI R POLLUTIO N CCNTH XEQUIPMEN TT O 3 E INSTALLE D MODIFICATIO N T

O EXISTIN G AI R POLLUTIO N CONTRO L EQUIPMEN T ONLY ) :

ICATIO N

IDENTIFICATIO N

O F AI RCONTAMINANT S (Chec kal l whic har e emltTe dI nmeasurabl e quer. t I • I _s int o

atmospher e fro m

an y operatio na t thi s facility. ) ACID S ALKALIE S ARSENI C " ASBESTOS L
_ BERYLLIU M F
_ CADMIU M && . VISIBL E EMISSION S CARBON MONOXIO E CH.ORIN E CO*POUND S OUST S FLUORIN E COWOUND S FLYAS H HYDROCARBONS 

### _ff l £ j HYDROGE N SULFID E LEA D MERCUR Y NITROGE N CC+POUNOS ODOR S ORGANI C CO^fOUNO S OTHE R (SPECIFY ) ' I PA I P.<\RTICULVfI S PESTICIDE S .ADIOISOTOPE S SILIC A SMOK E j SULFU RC>POUNt> S Lis t Specifi c Compound s FIBERGLASS , FIBERGLAS S AN D CURE D RESIN , STYKENE , ACETONE , METHYL METHACRYLAT E I Ha s Sourc e Testin g Bee nDon e 1 A t > Fac t Ility?f~lYE S JQ^N O Lates t Dat e Whe na Testin g Progra m wa s Completed : I f Progra m i s Continuous , Giv e Approximat e Testin g Frequency ;
INDICAT E WIT H "X " WHIC H O F TH E FOLLOWIN G FORM S AR E ATTACHE D AN D MADE PAR TO F TH E APPLICATIO N

X X

• AP IO I FUE L BURNIN G EQUIPMEN TUSE D FO R INDIREC THEATIN G (SF N 8518 ) A P 10 2 MANUFACTURIN G O R PROCESSIN G EQUIPiMEN T(SF N 8520 ) AP 10 3 INCINERATOR S (SF N 8522 ) AP 10 4 GRAIN , FEE D AN D FERTILIZE R OPERATION S (SF N 8524 ) A P 10 5 ASPHALTCONCRETE PLANT S (SF N 8526 ) AP 10 6 CONCRET E BATC H PLANT S AN D CEMENTHANDLIN G EQUIPMEN T(SF N 8527 ) X X

X X A P 10 5 ROCK , GRAVE L AN D 3AND . PLANTS (SF N 8530 ) A P 10 9 GA

S CLEANIN G EQUIPMEN T(SF N 8532 ) A P 11 0 CONPLIANC E SCHEDUL E (SF N 8534 ) A P H I AI R POL'.-TIC N EMERGENC Y EPISOD E ?•_.».: : :Z7'.i

zzoa A P 11 2 VOLATIL E ORGANI C CC*FOUND S STORAG E TAN K(Sr N 8535 ) AP 11 3 INTERNA L COMBUSTIO N ENGIN E SOURCE S (SF N 3SS>; ) OTHE RATTACHMENT S AR E A S FOLLOW S AN D AR E A PAR T O F THI S APPLICATION :

X X ( (AP11 7 APPLICATIO N FO RHA PSOURCE

S

Th e undersigne dapplican t I s full y awar e tha t statement s mad e I nthi s applicatio nandth e attache dexhibit s an dstate ment s constitut e th e applicatio nfor Permlt(s ) t o Construc t and/o r Operat e Ai r Contaminan t source s fro m th e Nort h Dak - Stat e Departmen t o f Healt handcertifie s tha t th e Informatio nI nthi s applicatio nI s true , correc t an dcomplet e t o tn e bes t o f hi s knowledg e andbelief . Further , th e undersigne dagree s t o compl y wit hth e provision s o f Chapte r 23 - o f th e Nort hDakot a Centur y Cod e andal l rule s an dregulation s o f th e Department , o r revision s thereof . H e als o under stand s th e permi t I s non-transferabl e and . I f grante da permit , h e wil l promptl y notif y th e Departmen t upo nsal e o r lega l transfe r o f th e permitte destablishment . Signe d 

# -O X c u*JiL_ 37

1



# -
-_

_.—,_.— _P.3 9

LEGAL DESCRIPTIO N Industria l Subdivisio nNo . 3 Lot s 1 , 2 , 3 , 4 , 5 ; Bloc k1 4 Lot s 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 ; Bloc k1 5 Lo t 1 , Bloc k1 7 Repla t o f Industria l Subdivisio nNo . 3 Lo t 9 ; Bloc k1 5 Lo t 2 ; Bloc k1 7
andadjacen t stree t right-of-wa y o f 16t hAvenu e Northwes t and44t hStree t Northwest , i nth e Cit y o f Fargo , Count y

o f Cass , Nort hDakota .

^P.4 0

EMISSIO N POINT S (Lis teecr. poin tseparately , numbe reac h an d locat e o n attache d flow-char t lumbe r 1 Stac kMelcT t(Ft. )

•^q-^Rp- r i n E T PK/P Pvonv (miniimp l Stac k Dia . (rt . a t Top ) ? F Y 7TT- T Ga ^ VoT^ACTM )

/10,75 4 /Exi tTem p 300 " L
. Ca s velocit y (

ba s y i

AI RCONTAMINANT

S EMITTE D - KNOW N G RSUITE D TM, + 46 0 = ^5 ^ = 1 " « 75 ° ° ^ X *• « = ",75 , us e san e Identificatio n n-jnbe ra s abov e PCB. Nunbe r Pollutan t

frTYRFW R MFTTHVT

. MPTTTArPVT.aTP ArPTOJ P Amoun t Pounds/H r ^ 5 -i n fii 1 1 .a*
. 1.27-2.0 4 Ton s A r



## _£ai _JL L Basi s o f Estimat e

- 31.? 2 SE

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. R P Pan^ar-HPTi

AR E AN YVOLATIL E ORGANI C COMPOUND S STORE D O

N PREMISE S N

O
_ x
_YE S - Lis t Belo w Se e Rule s 33-15 . Sectio n 33-15-01-O A fo rclasse s o f compound s covered ) Materia l Store d AROPOT , fl $52 2 Siz e Tan k(Gallons ) -______0 - -?: TANK

S vapo r Contro l Dev i

,GA3_A__YTIG

- OXIDIZE RO R 

# 5 AFjnpnr , 0 ano n -£000 . ? TANKS ' TZvPRn wancn-op ^
AR E AN YORGANI C SOLVENT S USE D O

R PRODUCED

? CIN O (Non e o r les s tha n 5 0 gallon s pe r year ) B Ye s - Identif y belo w Principa l Us e Gal/Y rConsulte d LESS,THANl2 ^ Gal/Y rProduce d grMPPM T RTTT. KTaNTrv r7fEftwiip ; *M » ATFirnrff : MOID . MIX ROOM^RESTN BAT H W ^1^Tras*THANv22 0

I S THER E AN

YEMISSIO N

CONTRO L EQUIFWEN T O N THI S UNI T O RPROCESS ? D N O G 3 Ye s - attac hFor m AP 10 ? (S> 4 8532 ) Doe s th e inpu t materia l o r produc t fro

m thi s proces s contai nfinel y divide dmateria l whic h coul dbecome airborne ? D N O D Ye s Describ e storag e method s use d

Storag e Pile s Typ e o f

Materia l Particl e Siz e (Averag e

Diamete r o r Scree nSiz e Pil e Siz e Averag e Ton s Pil e vette d

(Yes o rNO ) Pit s Cov e (Ye s o r N
Describ e an

y fugitiv e dus t problem : 

# ..siJ L ^ Signatur e o f

Ap i Attac h additiona l sheet s i f neede d t o explai n an y answe Us e separat e form fo reac h proces s tha temit s contamln eP.4 1

PERMIT0F*»LICATI0 N - CA S CLEANIN G EQUIPMEN T STAT E DEPARTMEN

TO F HEALT H - Ai r Pollutio n Contro l Progra m SF N 853 2 (A P 109 ) 10/6 5 NOTE : Bea d Instruction s Befor e Startin g r e
APPLICANT Name o f rirm/Organlzatio n MARVI N WINDOW S Perso n Submittin g Applicatio n JOH N JAMBOI S Plan t Locatio n 1/ 4 1/

4 Sourc e I.D. # (For m A P 100 ) Titl e CO O - TECTO

N PRODUCT

S Sectio n niP RG E Applicatio n Qat e

Phon e NO . (61 2 ) . 854-146 4 EXT . 1 4 Coun t un. y CAS S EOUI^EN T Typ e O Cyclon e D Multiclon e

_D Bagfilte r Q Othe

r(Describe ) CARTRIDG E FILTE

RCOLLECTIO

N Electrostati c D Precipitato r D we t Scrubbe r Nam e o f Manufacture r TORI T DIVISIO N DONALDSO N CO . Mode l NO . 4DF48 , 2 DFG, ET C Oat e installe d Applicatio n D Boile r D Kil n ffi Othe r (Specify ) IPollutant s Removed Desig n Efficienc y FTRERTCTAS S Q Q QQ % 1 b M1UUU N Operatin g Efficienc y | caf^ f Describ e Metho d use d t o Determin e Operatin g Efficiency : ASHRA E TES TRP-5 3

GA S CONDITIONS Ga s volum e (SCF

M *__9°F. , 14. 7 psia ) Ga s Temperatur e (*T. ) Ga s Pressur e (In

. HJ3) Ga s velocit y(ft/sec ) Pollutan t Concentratio n (Specif yPollutan t an d Uni t o f Concentration ) Pressur e Dro p Throu^ i Ga s Cleanin g Devic e Pollutan t

( i n H.0 ) Uni t o f Concentrat e I.H.E T 10° P 1 ? T N •^nn-ann n PP M

- OUTLE T 7n° p 0 T N 3snn-4nn n FP V

ttac h sketc h o f ga s cleanin g eguipmen t an d proces s equipmen t arrangement .

Dat e Signatur e o f Applican t


# MD .P.4 2

PERMI TAPPLICATIO N FO R HAZARDOU S AI R POLLUTAN T(HAP ) SOURCE S HEALT H AN D CONSOLIDATE D LABORATORIE S Environmenta l Engineerin g Sf N 832 9 (11/90 ) AP-li T S b J N A-APPLICAN TINFORMATIO N Nam e 0 * fitm

o f Institutio n MARVI N WINDOW

S Nam e ofApplican t JOH N JAMBOI S Mailin g Addres s (stree t & n o 804 3 24T H AV E SOr " Titl e CC O TECTO N PRODUCT S fr&NEAPOLIS Standar d industria l Classificatio n N o ..MTSC

. PIASTIC S 308 9 Phon e Numbe r 612-854-1464-EX T 1 4 

## m *«$* &
FACILIT YINFORMATIO N Wh o t o Contac t o n Ai r Pollutio n Matter s . :HARLE S VANASS E Mailin g Addres s (stree t & n o ) 804 3 24T H AV E SOUT H fitint y Addres s (stree t & n o ) 1 5 T H AV E an d 44T H ST

. N W Titl e PRODUC TDEVELOPMEN T MINNEAPOLI S City an d Count y FARG O CAS S Lega l Descriptio n o fPlan t Sit e ____, „__ .

1/ 4 i/4.5^,n ATrA CHE_? wp A P 10 0 Rge
. Lan d Are a a t Plan t Sit e 61.9 4 AerM(0f ) 2,698,106. 4 S q . . Latitud e (neares t second ) 46 ° 53 ' 32 " MSLE 

## W:w t n 

## B§b s Stat e M N Stat e N D Phon e Numbe r 612-854-146 4 

### *$§&% Zi p Cod e 5810 2 Longitud e (neares t second ) 96 ° 51 ' 28 " N 

### a? b 

### WfTMT , 

### tf&& a t 

### ' o n

Oescnb eNatur

eo f Bus.^goces ^ ; ^ pwCESS PRODUCING WINDO W AN D DOO RLINEAL S DURIN G WHIC H A THERMOSE

T POLYEESTE

RRESI N MATRI

X I S REINFORCED WITH FIBERGLAS S MA T AN D ROVING .

SECTIONS-STAC KDAT A insid e Diamete r ?E T ?TN insid e Are a 530. 9 S q in . Heigh t Abov e Grad e

3 7 ft . Ar e Emissio n Contro l Device s i n Place ?

i f s o Complet e A P 10 9 YE S Ga s Temperatur e a t Exi t 30 0 Gas velocit y a t Exi t 3 3 Gas Vol u ft/se c I\5,75 4 SCf n Bast s o fEstimat e (attac h separat e shee t i f necessary) SE E PAG E 2 A P10 2

Neares t Residence s o r Buildin g

PHOENIX GROU

PBUHDIN G Oistanc e (ft. ) 46 0 Directio n SOUT H Ne»"»s t Propert y Lin e 4 5 T H STREE T N

W SE E SIT E PLA

N Distanc e ( ^1 8 Dir e 

### TSfcT



# q iP.4 3
•>*=\.83- 9
SECTIO N C •EMISSIO N STREA M DATA Sourc e i D » For m AP-10 0 Flo wRate (scfm ) 10,75 4 ACE M Strea m Temperatur e (°F ) 300 ° F Moistur e Conten t (**-b

> AMBIEN T Pressure (i n Hg ) 0 H G 1 I N W

C Hea t Conten t (Btu/scfm ) 18,60 0 BTU/L B Mea n Particl e Diamete r (um ) N A Drif t velocit y (ft/sec ) Particulat e Concentratio n (gr/dscf ) Halogen s o r Metai s Present ' NON E Organi c Conten t (ppmv ) LES S THA N 100PP M O . Conten t (% ) 18 % ATMOSPHER E
SECTIO N O •POLLUTAN TSPECIFI C OAT A (Complet e On e Bo

xfo r Eac h Pollutan t i n Emissio n Stream ) Pollutan t Emitte d STYREN E /Pfoposed-ETf-nsiTorTRatetlb/hr A V 6.5-10.6 4 _JL ^ 5 MACHINE S SourcFCTassificatio n (proces s point , process fugitive , are a fugitive ) PROCES S POIN T Concentratio n i n emissio n Strea m (ppmv ) 6 2 PP M Solubilit y I N WATE R .03 2 @ 77 ° F Chemica l Abstrac t Services (CAS ) Numbe r 100-42- 5 Emissio n Sourc e (describe ) EVAPORATIO N FRO M RESI N SYSTE M Pollutan t Clas

s an d For m (organic/inorgani c •particulate/vapor ) CLAS S 3 ORGANIC/VAPOF T Vapo r Pressur

e (in . H g @ °F) 4. 5 Wi @ 68 y F Molecula r Weigh t (Ib/lb-mole ) 10 4 Absorptiv e Propertie s '0 0 LB S CARBO N ADSORBS 3 4 LB S STYREN E

Pollutan t Emitte d METTHY L METH ACRYLAT E Propose d Emissio n Rat e (lb/hr ) "- > Qj..27-2..0 4 5 MACHPES- ^ Sourc e Classificatio n (proces s point , process fugitive , are a fugitive ) PROCES S POIN T Concentratio n i n emissio n Strea m (ppmv ) LES S THA N 10PP M Solubilit y MODERATEL

YSOLUBL E I N WATE R 1.5 % Chemica l Abstrac t Services (CAS ) Numbe r 80-62- 6 Emissio n Sourc e (describe ) . . EVAPORATIO N FRO M RESI N SYSTE M Pollutan t Clas

s an d For m (organic/inorgani c - particulate/vapor ) CLAS S 3 ORGANIcTVAPOi r Vapo r Pressur

e (in . H a @°F ) 2 9 m < § 68 * F Molecula r Weigh t (Ib/lb-mole ) 100.1 3 Absorptiv e Propertie s POLYMERIZE S AN D GENERATE S HEA TWHE N ADSORBE D I N CARBO N 

# / m r

Dat e I Signatur e o f Applican t


# L J ^P.4 4

GENERA L PERHi TAPPLICATIO N - VOL»TIL E ORGANI C COMPOUND S 5 T 0«AG E TANK Stat e Departmen t o f Healt h - Ai r Pollutio n Contro l Progra m SF N 853 5 (A P 112 ) 11/8 5

Nam e o fFir m o r Organizatio n .•lARVEE N WINDOW S Perso n Submittin g Applicatio n JOH N JAMBOI S Tit i 

## to o - TECTO N PRODUCT

S ApplIcatio n Dot *

Plan t Locatio n 16T H AVE . AN

D 44T H ST . NW

. FARGO , N

D Sourc e 1 0 (A P 100 )

TAN KDAT

A CAPACITY : Barrel s Ga l Ion s 6,00 0 DIMENSION : D

l amete r 10-F T * Heigh t KTF T Lengt h widt h SHAPE : g^eyTlndrice l •Spherica l Q Other , Specif y MATERIAL S OF CONSTRUCTION : (I.e. , steel )

3/1 6 STAINLES S STEE L CONSTRUCTION : •Rivete d &Welde d •Other , Specif y COLOR : CONDITION : JQtGoo d CJFai r Q Poo r STATUS : QNe wConstructio n Q Alteratio n Q Existing , Giv e Dat e Constructe d TYP E O F TANK : Q;Fixe d Roof

•Externa l Floatin g

_ J Interna l Floatin g •Variabl e Vapo r Spac e
•Pressur e (lo wo r high ) D Other , Spec i f y TYP E O F ROOF : •Pa n •Doubl e Dec k •Pontoo n •Other , Specif y TYP E O F SEAL : •Meta l li e Sho e Sea l ___Prlmar y Sea l Onl y ___wit h Sho e Mounte d Secondar y Sea l Wit h Ri m Mounte d Sea l • liqui dMounte d Re s 1 1 len t Sea l Primar y Sea l Onl y Wit hWeathe r Shiel d Wit hRi m

Mounte d Sea l • Vapo r Mounte d Re s 1 1 len t Sea l Primar y Sea l Onl y Wit hWeathe r Shiel d wit hRi m

Mounte d Sea l VAPO R 0ISPOSA L

•Atmospher e •Vapo r Recover y Utl t • Flar e ©Other , Specif y CARBO N ADSORBTION O

RCATALYTI C OXIDIZE R NAME AL L LIQUIDS , VAPORS , GASES , O R MIXTURE S O F SUCH MATERIAL S T O B E STORE D I N TH E TANK . GIV E DENSIT

Y(LBS/GAL ) O

R •A.P.I . UNSATURATE

D POLYESTERRESIN , STYRENE , METHY L MErHACRYLAT

E A AROPO

L Q800 0 8.80 7 LBS/GA L - TAN K# 1 B AROPO

L Q652 2 9.40 7 LBS/GA L - TAN K# 2

^ 

## Vl- }P.4 5

Maximu m Fillin g Rat e (oarrei s pe r hcj r o r gallon s De r hour ) Averag e Outag e (Averag e distanc e fro m to p of tan k shel l t o liqui d surfac e (ft ) Averag e Throughpu t (Barrel s pe r da y o r gallon s p« r

dsy > Averag e Throughput SE E SPREADSHEET Tan kTurnovers PerYea r SE E SPREADSHEET I F MATERIAL STORE

D I S A SOLUTION , SUPPL YTH E FOLLOWIN

G INFORMATION Nam e of Solven t STYREN

E Nam e o f Materia l Dissolve d POLYESTERRESI N Concentratio n > > Materia l dissolve d C l b y weight ' o r$ b

y volume o rlbs/gal ) AROPO L Q80Q 0 47 % (WEIGHT ) AROPO

L Q652 2 67 % (WEIGHT ) \F MATERIA L STORE

D I S A GA

S O R LIQUIFIE D GA

S WHIC H I S NO TA PETROLEU

M PROOUCT

, SUPPL YTHE FOLLOWIN

G INFORMATIO N Identit y th e Materia l Pressur e a t Whic h Materia l i s Store d (lb s pe r squar e Inc h gag e a t *F )
TA W EMISSION S •'•b l lutan t Maximu m Pound s Pe r Hou r Ton s Por Yea r Basi s an d Calculation s fo r Quantitie s (Attac h

separat e shee t I t needed )

Ar e th e standard s o f perfonnanc e fo r ne wstationar y sources ; petroleu m liqui d storag e vessels , 4 0 CF R Par t 60 , Subpart s Kan d Xa (Apri l 4 , 198 0 Federa l Register ) bein g adhere d to , where applicable ? _LJQ
_ I fNo , Explai n DOES NOT APPL Y

' D6t

e

SEf O YOI F APPLICATIO N TO : Nort h Dakot a Stat e Departmen t o f Healt h 0 1 visio n o t Environmenta l Engineerin g 120 0 Missour i Avenue , Roo m 30 4 Bo x #552 0 Bismarck , >C

58502-552 0 PHONE (701)224-234 8 

# L mP.4 6

TAN K CLEANIN

G Twic e a yea r tan

k cleaning i s recommended . On e t o thre e day s i s th e tim e estimate d fo r the procedure . Styren e i s th e mos t likel ysolven t t o b e used , sinc e i t i s presen t i n th e polyeste r resi n allowing th e resultin g solutio n t o be catalyze d and dispose d o f a s a non-hazordou s soli d waste . W e ar e currentl y considerin g installing fou r tanks . Thi s wil l facilitat e coordinatin g deliveries , plus , tan k cleanin g ca n b e don e withou t stopping production .



## IP.4 7



### Densitie s o f Resi n Component s Aropo l Q652 2 Averag e specifi c gravit y Densit y
Aropo l Q800 0 Averag e specifi c gravit y Densit y = 1.1 3
= 1.127 2 grams/cubi c cr o = 0.0 4 0 7 lbs/cubi c inc h
= 9.40 7 lbs/gallo n

= 1.05 8
= 1.055 4 grams/cubi c c m = 0.038 1 lbs/cubi c inc h
= 8.807 0 lbs/gallo n Mixe d formulatio n (70 % Q652 2 and 30 % Q800 0 Densit y= ' 9.22 7 lbs/gallo n

Conversio n factor s used : grams/cubi c cm . = specifi c gravit y(.9975 ) lbs/cubi c inc h = grams/cubi c c m(1/453.6)(2.54*3 ) lbs/gallo n = lbs/cubi c inc h (1/.0254*3)(1/264.172 )



# i\ioP.4 8

PERHI TAF^-VICATIO N - GA S CLEANIN G EQUI^EN T STAT E DEPARTMEN

T O f HEALT H - Ai rPollutio n Contro l Progra m ST N 853 2 (A

P109 ) 10/8 5 NOTE : Rea d Instructlo Befor e Startin g
APPLICAN T Nam e o f firm/organizatio n MARVI N WTNTrw s Perso n SuDmlttin g Applicatio n

JOH N JAMBOI S Plan t Locatio n 1/ A 1/ A Sourc e I.D. I (For m A P 100 ) Titl e CO O TECTO N PRODUCT S Sectio n r* p RC E Applicatio n Dat e JUL Y8 , 199 1 Phon e NO

. (612 ) -854-146 4 EXT
. 1 4 County CAS S EOUlfEN T Typ e Electrostati c D Cyclone Q Multiclon e Q Bagfilte r0 Precipitato rD *e tscrub . Q Othe r(Describe ) CATALYTI C OXIDIZE

R Nam * of Manufacture r awmTT . .ENVTRrNMFM-AT . .qYSTFfl g Mode l NO . 7 5 750 0 SCF M ' * Oat

e Installe d Applicatio n D Boile rD Kil n Q Other(Soeclfy ) PULTRUSIO N Pollutant s Remove

d Desig n Efficienc y j Operatin g Efficienc y QTVOTNE Q Q X q R* METHY L METHACRYLAT

E 9 9 X 9 5 X X X Describ e Metho

d use d t o Determin e Operatin g Efficiency : TYPICALL

Y EP A METHO

D 2 5 PP

M OU T PP M I N

CA S C0NOI T I0N S IN L S T OUTIE T Ca s volin e (SCT H 68°r. , 1A. 7 psia ) 750 0 SO M 7bU0 Ur' M Ga s Temperatur

e (T. ) 70 ° F ?QQ ° F Ca s Pressure (in . HJD ) 

### ta B J 2 TT . Ca s velocit y (ft/sec ) Pollutan tConcentratio n (Specif y Pollutan tan

d uni to f Concentration ) Pollutan t

STYREN E Pressur e Dro

p Throug h Ca s Cleanin g Devic e (if i MFTHYT . MFTHftTRYTATF

; I n H.J ) uni to f Concentrate 3 3 FFS LB/H R LB/H R 10.6 4 LB/HR

2.0 4 LB/HR 3 3 fPf t .53 2 LB/HR .10 2 Lti/HK 63,81 3 LB S STYRENE/Y R5 MACHINE

S = 10.6 4 LB/

F 6,00 0 HR

S attac h sketc h o f

ga s cleanin g equipmentan d proces s equipmentarrangement . 

# 9 : Ml 12,27 6 LB S METHY L METHACRYLAT

E = 2.0 4 LB/H

R Signatur e d f

Applican t
SE E SPREA D SHEE T FO RYEA R5 FIGURE

S FO R1 4 MACHINE

S 

# nP.4 9



# CITY OF FARGO PUBLIC

WORKS ENGINEERING 30 6 Fourt hStreet Nort h Fargo , Nort

hDakot a5810 2 Phone : (701 ) 241-154 5 FAX : (701 ) 241-810 1 Jun e 21 , 199 1



## MEMORANDU M
TO : Mauric e Anderson , Communit y Developmen t

Specialis t FROM : Mark

H
. Bittner , civi

l Enginee r

" } 1 ")&J2_

j/
. &.~tC^^ SUBJECT : Marvi nWindow s Sit e Followin g i s informatio nyou requeste drelativ e t o cente r o f Lo t 3 , Bloc k15 , Industria

l Par k Sub
. No
. 3
. Th e exac t

locatio no

f reference dpoin t

i s 24 0 fee t

eas t o f th e cente rof 44t hStree t an d80 0 fee t

nort ho f th e cente r

o f 15t hAvenu e North
. Latitud e Longitud e Elevatio n 46<>53'32 "

96°51*28 " 894.0 0 USG S Fo r compariso npurposes , th e elevatio no f to p o f curb directl y southo n15t hAvenu e Northi s 897.02
. I f you hav e any questions , pleas e call
.

MHB/av l CC : Rober t

C Welto n Attachmen t 

# 4 $P.5 0

Repla t o f Industria l Sub . No . 3 ; Lo t 2 , Bloc k17 ; andLo t 9 , Bloc k1 5 503,553. 6 squar e fee t platte dlot s Industria l Sub . No . 3 ; Lo t 1 , Bloc k17 ; Bloc k14 ; andLot s 1-8 , Bloc k1 5 1,971,525. 6 squar e fee t platte dlot s 223,027. 1 squar e fee t platte droadwa y 2,698,106. 4 squar e fee t tota l 61.9 4 Acre s



# •UP.5 1



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building * •' •mow n l(i-, i .•"'•" * (n-Ml i •• •|NH|il f > .*M|»lr-" l tji.il i • . <i.i l 1 J...| l 4 ii,.|J > - l I ,-.,:. )•• ' •.1 . ' l" > '' . II.* - .ill.J....,!..* . , H

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# PROJECTBOUNDARIE S



# 5 0.- —: -*c- ^



### 1 . FOO D SERVIC E O F AMERIC A 2 . . HOENI XGROU P 3 . SPECIA L RESOURC E MANAGEMEN T 4 . NABISC O 5 . FARG O ASSEMBL

YCO . 

# BUILDIN G LOCATION S 6 . McARTHU

RCOMPAN

Y 7 . J.B. PRODUCT S 8 . TAP P REPAI R SERVIC E 9 . OP P CONSTRUCTIO N 10 . SANITATIO N PRODUCTION S 

# 5 3P.5 5



# PLATTE D PROPERTIE S

### EXHAUS T (ID#I ) EXHAUS T (ID#7- )

FIBROU S ROVIN G STATIO N STYREN E EMISSIO N 50 0 CF M 3 4 PP M 

# A
LIOUI D ENTR Y FINISHE D

PRODUC T EXI T

FIBROU S MA T STATIO H RESI N

STATIO N 

# I STATIO N PULLE R STATIO N BAGHOUS E 

# I

iti n *< • com m
STYREN E

EMISSIO N 200 0 CF M 77PP M FIBERGLAS S PARTICULATE S EMISSIO N 350CF M

iA W STA T IO I

# -6— 

# A

BAGHOUS E 

# A FIBERGLAS S PARTICULATE S 50 0 CF M
UNCU T
CU T

MA T SLITTIN GARE AP.5 8

ESTIMATE D 'UNCONTROLLE D EMISSIONS 5 PULTRUDER S YEA

R 2

DT V BY DI V B Y
I
DI V BY 63,81 3 TOTA L STYREN

E EMISSION/Y

R 600 0 HOUR S O F PRODUCTION/Y R LBS/H R EMISSIO

N LBS/MI NEMISSIO

N LB S T O GRAM S SECOND S GRAMS/SE C EMISSIO

N 1 HR MAAL (N

D MAAL 4.26 ) 2.4 4 8 HOU

R MAAL (N

D MAAL 2.13 ) 

### X

X X 10.6 4 6 0 .17 7 453. 6 80.2 9 6 0 1.3 4 2. 6 3.4 8

. 7

THI S PERMI T I S INTENDE D T O APPLY T O 5 PULTRUDERS . 2 WIL L B E INSTALLE D AND OPERATIN G I NYEA

R 1 . 3 MOR E AR E PROJECTE D PO R YEA R 2 . TH E FOLLOWIN

G FIGURE S AR E ESTIMATE S O F RESI NUS E AND STYREN E EMISSIONS INYEA

R 2 . * SE E PAG E 4.12- 8 U S EPAAP-4 2 SUPPLEMEN T B SEPT . 198 8



# 5P.59 .

ESTIMATE D REDUCTIONI NSTYREN E EMISSION S USING 95 % EFFICIENT CATALYTI C OXIDIZE R (750 0 CFM ) 5 MACHINE S YEAR 2

63,81 3 L B STYREN E EMISSICN/YR DI V B Y 6,00 0 10.6 4 LB/H R X .0 5 95 % EFFICIENT OXIDATION

. .5 3 LB/HR T O ATMOSPHER E DI V B Y 6 0 .008 8 LB/MI N X 453. 6 4.0 2 GRAMS/MI N DI V B Y 6 0

.06 7 GRAMS/SB C X 2. 6 .174 2 1HOU

R MAA L (N

D MAA L 4.26 ) X . 7 .121 8 8HOU

R MAA L (N

D MAA L 2.13 )



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# ioOP.6 2

PROPOSE D WAST E STREA M MANAGEMEN T PLAN S FO RTECTON , INC . FARGO , NORT H DAKOT A I . Bul kStorag e Tank s Tecto n wil l hav e 2^*600 0 gallohSbulksstorage tanks fo runcure d resi n tha

tcontain s 40%

» sjpfnlf * Thes e tank

s wil l require cleanin g approximately twic e pe ryear . Th e cleanin g agen twil l b e th e solven ti n th e resin ; styrene ; v 1 . SR M ca n provid e cleanin g service s fo rth e tank s an d manag e th e disposal o f th e contents , whic h wil l b e catalyzed . Cleanin g with styren e i n aclose d spac e wil l require leve l A protectiv e clothin g (self-containin g breathing apparatus) , which SR

M i s trained t o us e an

d owns . SR

M als o ha s aCertified Industria l Hygienis t(CIH ) o n staf f fo rhealt

h an d safet y oversigh to f

thi s project . 2 . I twoul d b e possibl e t o reduc e exposur e level s i n th e cleanin g operation s o f thes e tank

s an d thus reduc e th e ris kleve l an d expense s i n cleaning . SR M woul d b e please d t o offe rengineerin g suggestion s fo rth e constructio n o f thes e tanks to make the

m easil y and mos tcos teffectivel y cleaned . Potentia l idea s are : a tleas ton e 2 4 inc h manway tha ti s easil y removable ; preferabl y another manway elsewher e o n th e tan kfo rventilatio n exhaust ; ahar d plumbe d purg e o n th e tan

kfo rexhaust ; etc . SRM can als o provid e th e ai rquality expertis e i n th e even tscrubbers ar e neede d o n the exhaus tt o mee tai rqualit y standards .
n . Mol d Releas e Solvents , Mol d Cleanup , Mixin g Roo m Cleanup SRM hold s agreements wit h approximatel y 2 0 disposal facilitie s whic h offe ravariet y o f wast e managementmethods . Iti s ou rpolic y to offer ' companie s achoic e o f facilitie s an

d waste managementoption s whic h wil l bes tsui tthei rneeds . Waste s from th e abov e operations , fo rexample , may b e managed b y fue l blending , grindin g and fuel blendin g o rdirectincineration . Som e o f th e paints may b e suitabl e for landfil l disposa l dependin g upo n thei rchemica l analysi s an d regulator y status . m . Spen tAceton e Solven t Ther e are anumbero f method s o f

managin g aceton e wastes . I f th e recover y valu e o f th e solven ti s high enough , redistillatio n and reus e i s usuall y th e bes tchoice . SR M ca n provid e recyclin g service s off-sit e eithe ra s drummed wast e o ri n bul ktankers o f wast e and can retur

n th e productfo rreuse . W e wil l provid e pricin g fo ranumber o f options , includin g on-sit e distillatio n usin g amobil e solven tstil l SR M own s an d operate s o ra

n in-plantstil l operate d b y Tecton . SR M can tha

n manag e th e stil l bottoms . Othe roption s i f th e quality ofth e aceton e i s no thig h enoug h fo rrecyclin g includ e fuel blendin g an d direc tincineration . 

# r.?•? ! :o : ' - - 4SH_HI ^ -IMEHMM L EHl' 3 T O •? ? 15-1I50Q 7 _•—_ • 3 9e' 6 P
. 1 0
.

TABL E 4.12-2 . EMISSIO

N FACTOR

S FO RUNCONTROLLE

D POLYESTE

RRESI N PRODUC T FABRICATIO

N PROCESSES * (10 0 x mas s o f

VO C emitted/mas s o f

monome rInput )

•

^ ( '!> ' *JiO Proces s

Han dlayu p Spra y layu p Continuou s laminatio n Pultruslon

d Filamen t winding * Marbl e castin

g Closedoolding

g Res l



### NV S 5-1 0 9-1 3 4 - 7 

# (TTT ?
5 - J O 1 - 3 1 - 3 

### n VS

b

- 7 3 - 9 1 - 5 1 - 5 2 - 7 1 - 2 1 - 2 Eo i sio

n Facto r Rating 

### C B B 

# ©
D B D Ce l Coa t



### NV S 2 6 - 3 5 2 6 - 3 5 

### c c c f c VS

b 8-2 5 • 8-2 5 

### c c

- r.
c 

# 1 Esission

Facto r Rating 

### 0 B

_

—

—

• —

— •Referenc e 9 . Range s represen tth e variabilit y o f processe s an i sensiti vlt y o f ealsslon s t o proces s paraneters . Singl e valu e factor s shoul d b e selecte d wit h caution . NV S • nonvapor-suppresse d resin . V S • vapor-tup * presse d rerln . bFactor s ar e 30-70 * o f thos e fo rnonvapor-suppresse d resins . CGe l coa ti% no tnormall y use d i n thi s process . dp'M n factor s fo rth e continuou s laclns.io n proces s ar e assuc.- 7 ' . e o apply . \i factor s fo rth e han d layu p p

r' • ar e assume d t o apply .

.• r s unavailable . However , whe n part s ar e subsequentl y spraye d
• it - 1 coat , hand an d spra y layu p ^ . . coa tfactor s ar e a s sue." , t capply , «•?•»-. . .actor s fo rmarbl e casting , asemiclose d process , ar e assume d t o /••pply . TABL E 4.12-3 . TYPICA L RESI N STYRENE PERCENTAGE S

Resi nApplication
Han d layu p Spra y layu p Continuou s laminatio n Filaaent winding Marbl e castin

g Close dmoldin

g Ce l coa t •i nStyr> e Content * (wgt . 

### 4 3 4 3 4 0 4 0 3 2 •5. ' 

### 3 5 •"Ma y var y b y a t leas , _r

5 percentas i point *
• 8 EMISSIO N FACTOR ? 

# fa
9/8 8

_P.6 4

: : _L-a3-159 1 35:0 8 =£C M ASHLAND CHEM : CS L EH& S S612=5<:DC23—2B56 6 

# s Rorvn an d Haa s Conpan y

Independenc e Mal l Wes t Philadelphia , P

A H10 5 HEALTH EMERGENC Y SPIL L EMERGENC

Y CHEMTRE C : 215-512-300 0 : 215-592-300 0 : 100-424-930 0 

# MATERIA L SAFET

Y DATASHEE T PRODUC TIDENTIFICATIO N METHY L METHACRYLAT E - 5 0 pp m MEH Q Produc t cod e Ke y MSD S dat e Supersede s 6528 1 905516- 7 09/12/9 0 05/25/8 9 Roh m an d Haa s Hazard Ratin g Toxicit y 2 Fir e 3 Reactivit y 2 Specia l Scal e 4«IXTRSM e J'WIC M -.•MOO-KAT E •USIICW T •J.INSICNUICAN T

COMPONEN TINFORMATIO N No . 1 Methy l methacrylat e 2 Othe r este r adduct s 3 MEH Q CA S RE G NO . AMT.(% ) 80-62- 6 99. 8 MI N No t Require d 0.2 0 MA X 150-76- 5 0.00 5 

# EMERGENC

YRESPONS E INFORMATIO N FIRS TAI D PROCEDURE S Inhalatio n

Ey e Contac t

Ski n Contac t

Ingestio n Mov e subjec t t o fres h air . Giv e artificia l respiratio n i fbreathin g ha s stopped . Ge t promp t medica l attention .

Flus h eye s wit h a larg e amoun t o f wate r fo r a t leas t 1 5 minutes . Consul t a physicia n i f irritatio n persists .

Remov e an d was h contaminate d clothin g thoroughly . Was h ski n thoroughl y wit h soa p an d water . Se e a physician .

I f swallowed , giv e 2 glasse s o fwate r t o drink . Neve r giv e anythin g b y mout h t o a n unconsciou s person . Se e a physician .

# > PAG E 1 o f9P.6 5

JL : L-03-135 1 0S:3 9 '--SC M fiSHLPND CHEMICH L EH& 3 T O 56125546323--28S6 S P.22

Roh m an d Haa s Compan y Independenc e Mal l wes t Philadelphia . P

A 1910 S PRODUCT : METHYL METHACRYLAT E - S O pp m MEH Q KEY : 905516- 7 DATE : 09/12/9 0

FIR E FIGHTIN G INFORMATIO N Unusua l Hazard s
Extinguishin g Agent

s Vapor s ca n trave l t o a source o f ignitio n and flas h back . Heat ca n cause polymerization . Heate d container

s ca n explode .
Use th e followin g extinguishin g medi a whe n fightin g fire s involvin g thi s material :

- pola r solven t (alcohol ) foa m - carbo n dioxid e - dr y chemica l - wate r spra y Persona l Protectiv e Equipmen t Wea r self-containe d breathin g apparatu s (pressure-deman d MSHA/NIOS H ap prove d o r equivalent

) and ful l protectiv e gear . Specia l Procedures EXPLOSIO N HAZARD . Figh t advance d fire s fro m a protecte d locatio n Us e wate r spra

y t o coo l container

s expose d t o fire . SPIL L O R LEAKHANDLIN G INFORMATIO N " ' Persona l Protectio n

Procedure s Appropriate protective equipmen t mus t be wor n whe n handlin g a spil l o fthi s material . Se

e th e PERSONA

L PROTECTIO

N MEASURE

S Sectio n fo r recommendations . I fexpose d t o materia l durin g clean-u p operations , see th e FIRS TAI O PROCEDURE

S Sectio n fo r action s to follow .
Kee p spectators away. Eliminat e al l ignitio n sources . Contai n spill s immediatel y wit h iner

t material s (e.g . sand , earth) . Transfe r liquid s an d soli d dikin g materia l t o separate suitabl e container s fo r recovery o r disposal . Contaminate d monome r ma y be unstable . Add inhibito r to preven t polymerization . Se e WASTE DISPOSA L Sectio n fo r informatio n regardin g th e disposa l ofcontaine d spills . NOTE : Spill s o n porou s surface s ea n contaminat e groundwater . CAUTION : Keep spill s an d cleanin g runoffout ofmunicipa l sewer s an d ope n bodie s o fwater . 

# (A
PAG E 2 o f9P.6 6

JLL-33-1SS 1 35=3 S 

# s FRO M ftSHL.SND CHEniCfl L EH&5 T G 96129346823—2556 6 P.2 4

Reh m an d Haa s Compan y Xnd«p«neene « Mal l Wes t Philadelphia . P

A 1910 5 PRODUCT : METHY L METHACRYLAT E - 5 0 pp m MEHQ KEY : 90SS16- 7 DATE : 09/12/9 0 

# HAZAR D INFORMATIO N HEALT H EFFECT

S FRO M OVEREXPOSUR E Primar y Routes o fExposur

e Inhalatio n Ski n Contact Inhalatio n Inhalatio n o fvapo r o r mis t ca n cause th e following :

- irritatio n o fnose and throa t Repeate d o r prolonge d exposur e ca n caus

e th e following :

- headach e - nause

a - drowsiness - unconsciousness Ey e Contact Material , as supplied , ea n caus e th e following :

- sligh t irritatio n Ski n Contact Materia l ca n cause th e following :

- moderate ski n irritatio n - ski n sensitizatio n Ingestio n Materia l i s possibl y harmfu l i f swallowed . Delaye d Effect s Prolonge d o r repeate d exposur e ca n caus

e th e following :

- allergi c ski n reactio n - kidne y damage - live r damage FIR E AN D EXPLOSIV E PROPERTIES '

Flas h Poin t 10°C/50° F Setaflas h Closed Cu p Auto-ignitio n temperatur e 435°C/815° F Lowe r explosive limi t 2.1 % Uppe r explosive limit 12.5% REACTIVIT

YINFORMATIO N Instabilit y Thi s materia l i s considere d stabl e unde r specifie d condition s o fstorage , shipmen t and/o r use . Se e STORAG E AN O HANDLING INFORMATIO N Sectio n fo r specifie d CONTINUE D PAG E 3 o f9 / .£ -

^'.Wm- « --> + Qmt»>,mm<J-%r-4 * • _ • ^ - - -*----- -P.6 7

;LL-33-lSS l 39=1 3 F^.Cr, SSHLhN D CHE-llCn L EH&

3 3612S546E23—2SS66
Roh m and Haa

s Compan y PRODUCT : METHYL METHACRYLAT E - S O pp m Independenc

e Mal l Wes

t M . u n Philadelphia . P

A 1910 S men u KEY : 905516- 7 DAT E 09/12/9 0 CONTINUATIO N conditions . However , thi s materia l can underg o hazardou s polymerization . See Hazardou s Polymerizatio n fo r condition s to avoid . Hazardou s Decompositio n Products There ar

e n o know n hazardou s decompositio n product s fo r thi s material . Hazardou s Polymerizatio n Excessiv e aging , hea t contaminatio n wit h polymerizatio n eatalysts , oxygen-fre e atmosphere , inhibito r depletio n o r ultraviole t ligh t (sunlight

) ma y cause polymerization . A n uncontrolle d polymerizatio n ma y produc e a rapi d releas e o fenerg y wit h th e potentia l fo r an explosio n o f unvented closed containers . Incompatibilit

y Avoi d contact wit h th e following :

- acid s - base

s •oxidizin g agent

s - reducin g agent

s - U V ligh t

r »'VIRONMENTA L IMPACT Environmenta l Toxicit y Rainbo wtrou t (Salm o gairdneri) , 9 6 Hou r LC50 : 8 0 mg/l (Slightl y toxic ) Daphni a magna, LC50 : 7 0 mg/ l (Slightly toxic) Rainbo wtrou t (Salm o gairdneri) . LC50 : 17 0 mg/ I (Practicall y non-toxic ) 

## ACCIDEN TPREVENTIO N INFORMATIO N COMPONENTEXPOSUR E INFORMATIO N Componen

t Informatio n N o CA S RE G NO . AMT.(%

) 1 Methy l methacrylate 80-62- 6 99. 8 MI N 2 Other, este r adducts No t Required 0.2 0 MA X 3 MEH Q 150-76- 5 0.00 5 Exposur e Limi t Informatio n \ Component ; ROH M AN D HAA S OSH

A ACGI H No . Units TWA STE L TW A STE L TL V STE L pp m Q>0j ) (7S) 10 0 Non e 10 0 Non e •i ar ^ j ^ a a a a 3 mg/m 3 5 Non e 5 Non e 5 Non e

, CONTINUED ,P.6 8 .A
. -33-1=9 1 39=1 3 • =~.C M PSHLHN C C.-Er.iCA L Er-& 3 rt.i=--cc<i o 5—-c c
Roh m an d Haa s Company Independenc e Mal l wes t Philadelphia , P

A 1910 5 PRODUCT : METHY L METHACRYLAT E - 5 0 pp m MEH Q KEY : 905516- 7 DATE : 09/12/9 0 CONTINUATIO N
a Not Require d NOTE : Contac t Roh m an d Haa

s Compan

y fo r ai r monitorin g metho d PERSONAL PROTECTIO N MEASURES Respirator

y Protectio n

Ey e Protectio n

Hand Protectio n

Othe r Protectio n A respirato r protectio n progra m meetin g OSH A 1910.13 4 an d ANS I Z88. 2 re quirement

s mus t be followe d wheneve r workplac e condition s warran t a respirator' s use . Non e require d i fairborn e concentration s ar e maintained belo w th e TWA/TLV s liste d i n th e COMPONEN TEXPOSUR

E INFORMATIO N Section . Fo r airborn e concentration s u p t o 1 0 times th e TWA/TLV s liste d i n th e COMPONEN T EXPOSUR E INFORMATION Sectio n wea r a MSHA/NIOS H approve d (o r equivalent ) half-mask , air-purifyin g respirator . Air-purifyin g respirator s shoul d b e equippe d wit h organi c vapo r cartridge s an d dus t and rriis

t filters . Fo r airborn e concen tration s u p t o 10 0 time s th e TWA/TLV s liste d i n th e COMPONEN TEXPOSUR

E INFORMATIO N Sectio n wea r a MSHA/NIOS H approve d (o r equivalent) full facepiec e airlin e respirato r i n th e positive pressur e mod e wit h emergenc y escap e provisions .
Us e chemica l splas h goggle s (ANS I 237. 1 o r approve d equivalent) . Ey e protectio n wor n mus

t b e compatibl e wit h respirator y protectio n syste m employed .
Th e glove(s) liste d belowma y provid e protectio n agains t permeation . Glove s o fothe r chemicall y resistan t material s ma y no t provid e adequate protection :

- Buty l rubbe r Rinse an d remov

e gloves immediatel y afte r use . Was h hand s wit h soa p and water . Glove s shoul d be removed an d replace d immediatel y i fther e i s any indicatio n o fdegradatio n o r chemica l breakthrough . NOTE : Materia l i s a possibl e ski n sensitizer .
Us e chemicall y resistan t apro n o r othe r imperviou s clothin g t o avoi d prolonged o r repeate d ski n contact .

PAG E 5 o f 9 

# (Pr_^_^_

_P.6 9

JUL-33-13S 1 39=1 1 FRC M PSHLAN D CHE"ICS L c~i& 5 T

G 36125546323—2556 6 ~.2~
Roh m an d Haa

s Compan

y PRODUCT : METHY L METHACRYLAT E - 5 0 pp m Independenc e Mal l Wes t MRU « Philadelphia . P

A 1910 S IY1EHQ KEY : 905516- 7 DATE : 09/12/9 0

FACILIT YCONTRO L MEASURE S Ventilatio n Us e loca l exhaus t ventilatio n wit h a minimu m captur e velocit y o f10 0 ft/min . (3 0 m/min. ) a t th e poin t o fvapo r evolution . Refe r t o th e curren t editio n o fIndustria l Ventilation : A Manua l o fRecommende d Practic e publishe d by th e America n Conferenc e o fGovernmenta l Industria l Hygienist s fo r informatio n o n th e design , installation , use . an d maintenanc e o f exhaus t systems . Othe r Protectiv e Equipmen t Facilitie s storin g o r utilizin g thi s materia l shoul d b e equippe d wit h a n eyewas h facilit y an d a safet y shower . STORAG E AN D HANDLIN G INFORMATIO N Storag e Condition s

Handlin g Procedure s

Othe r Stor e ou t o fdirec t sunligh t i n a coo l place . Avoi d temperatur e extreme s durin g storage ; ambien t temperatur e preferred . Materia l ca n burn ; limi t indoo r storag e t o approve d area s equippe d wit h automati c sprinklers . Tota l absenc e o foxyge n wil l inactivat e th e inhibitor . D o no t stor e unde r oxygen-fre e environmen t Leav e ai r spac e ove r liqui d surfac e i n al l container s introducin g ai r periodicall y i fstore d mor e tha n 6 months . Us e monome r withi n 1 year . Conduc t a stabilit y tes t o n materia l store d i n bul k ever y month ; drum s an d pail s ever y 3 month s usin g tes t metho d TM-1011 A availabl e fro m Roh m an d Haa s Company .

Thi s materia l i s a potentia l ski n sensitizer . Se e th e PERSONAL PROTECTIO N MEASURES Sectio n prio r t o handling .

CONTAINER S HAZARDOU S WHE N EMPTY . Sinc e emptie d container s retai n produc t residu e (vapor s and/o r liquid ) follo wal l MSD S an d labe l warning s eve n afte r containe r i s emptied . 

## SUPPLEMENTA L INFORMATIO N TYPICA L PHYSICA L PROPERTIE S "

Appearanc e Clea r Colo r Colorles s Stat e Liqui d Odo r Characteristi c Fruit y odo r Viscosit y 0.5 3 CP S Specifi c Gravit y (Wate r » 1 ) * .. . 0.9 4 CONTINUE D PAG E 6 o f9 

# MLP.7 0

;UL-33-135 1 35 = ?C M ASHLAN D CHEMICA L t.-'& S 56123546323—2S56 6 ,25
Roh m andHaa s Compan

y Independenc e Mal l wes t Philadelphia , P

A 1910 5 PRODUCT : METHY L METHACRYLAT E - 5 0 pp m MEHQ KEY : 90S516- 7 DAT E 09/12/9 0 CONTINUATIO N

Vapo r Densit

y (Ai r = 1 ) 3. 5 Vapo r Pressure 2 9 m m Hg @2Q*Ct68'\* Meltin g poin t -48°C/-54° F Boilin g poin t 101°C/214° F Solubilit y i n wate r 1.5 % Moderatel y solubl e Percen t Volatilit y 10 0 Evaporatio n rat e (BA

e B 1 ) ... . > 1 

### iy\ftl€tiJlA<T

_bJ^-KlH' X yQQjm TOXICIT YINFORMATIO N Acute Dat a

Sensitizatio n Data Epidemiology Dat

a Derma l LD5 0 - rabbi t >500 0 mg/k g Ora l LDS

O - rat : >500 0 mg/k g Inhalatio n LC5 0 - ra t 709 4 pp m fo r 4. 0 h r Ski n Irritatio n - rabbit : moderate irritatio n Ey e Irritatio n - rabbi t slight irritatio n
Sensitizatio n - human : Allergi c response observe d

I n a retrospective stud y of th e effect s ofexposur e t o ethy l acrylat e an d methy l methacrylate o n worker s hire d i n on e plant betwee n 193 3 an d 1945 , a higherthan-expecte d incidenc e ofcolorecta l cance r mortalit y wa s observed . A stud y o n worker s hire d afte r 194 5 i n th e sam e plant , an d a study o n worker s hired afte r 194 2 i n a secon d plant , di d no t sho wa n increase d ris k

o fcolorecta l cance r mortality . WASTE DISPOSA L Procedure Afte r th e additio n ofexcess inhibitor , incinerat e liqui d an d contaminate d dikin g materia l i n accordance wit h local , state , and federa l regulations . 

## REGULATOR

YINFORMATIO N WORKPLAC E CLASSIFICATION S Thi s product i s considere d hazardou s under th e OSHA Hazar d Communicatio n Standar d (29CF R 1910.1200) . Thi s produc

t i s a 'controlle d product ' under th e Canadia n Workplac e Hazardou s Material s Informatio n Syste m (WHMIS) .

PAG E 7 of9 

# tf lP.71
_

JUL-33-1SS 1 0S = 1 2 FRC M ASHLAN D CHEMICA L EHg 5 T Q .36125546323—2656 6 F.2 S

Roh m an d Haa s Company PRODUCT : METHY L METHACRYLAT E - 5 0 pp m Independenc e Mal l Ves t Meur \ Philadelphia . P

A 1910 5 ivifcn u 

# ygW-l* KEY: 905516- 7 DATE : 09/12/9 0

TRANSPORTATIO N CLASSIFICATION S

Prope r shippin g nam

e METHY L METHACRYLATE , INHIBITE D U S DO THazard Class FLAMMABL E LIQUI D Identificatio n number U N 124 7 DOTshippin g labe l Flammabl e Liqui d EMERGENC

YPLANNIN G & COMMUNIT YRIGHT-TO-KNOW(SAR A TITL E 3 ) Sectio n 311/31 2 Categorization s (4QCFR 370 ) Thi s product i s a hazardou s chemica l unde r 29CF R 1910.1200 , an d i s categorize d a s an immediat

e and delaye

d health , an d flammabilit y an d reactivity physica l hazard . Sectio n 31 3 Informatio n (4QCF R 372 ) Thi s product contain s a chemica l whic h i s liste d i n Sectio n 31 3 above d e minimi s concentrations . Th e followin g liste d chemical s ar e present : (Quantit y presen t i s foun d elsewhere o n thi s MSDS. )

- Methy l methacrylate (80-62-6 ) CERCL A INFORMATIO N (40CF R 302.4 )

Thi s materia l ha

s a componen

t o r component

s wit h a reportabl e quantit y unde r / the . Comprehensiv e Environmenta l Response , Compensation , an d Liabilit y Ae t (CERCLA ) an d th e Superfun d Amendment s an d Reauthorizatio n Act (SARA ) Titl e II I Sectio n 304 . The components . CA S numbers , an d reportabl e quantitie s ar e liste d below . Spill s o fa componen t i n exces s o f it s reportabl e quantit y mus t be:reporte d t o th e Nationa l Respons e Cente r (1-800-424-8802 ) an d t o th e appropriate stat e an d loca l emergenc y response organizations . Methy l methacrylate (80-62-6 ) lOOOIbs. RCR A INFORMATIO N Whe n thi s produc t become

s a waste , i t i s classifie d as a hazardou s wast e unde r criteri a o fthe

* Resourc

e Conservatio n and Recover y Act , Category : U-16 2 (4 0 CF R 261) . CHEMICA L CONTRO L LA WSTATU S Al l component

s o fthi s produc

t ar e liste d o r ar e exclude d fro m listin g o n th e U.S . Toxi c Substance

s Contro l Ac

t (TSCA ) Chemica l Substane

e Inventory .

PAG E 8 of9 

# TOP.7 2

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— & 3 rb.i-=:UEa23—2o56 6 -.1 2 

# 0 Roh

m an d Haa

s Compan

y Independenc e Mal i Ves t Philadelphia . P

A 19105 PRODUCT : METHY L METHACRYLAT E - 5 0 pp m MEH Q KEY : 905516- 7 DATE : 09/12/9 0

ABBREVIATIONS : ACGI H = America n Conferenc e o f Governmenta l Industria l Hygienist s OSH A " Occupationa l Safet y an d Healt h Administratio n TL V •Threshol d Limi t Valu e PE L •Permissibl e Exposur e Limi t TW A - Tim e Weighte d Averag e STE L « Short-Ter m Exposur e Limi t BA e s Buty l acetat e I Ba r denote s a revisio n fro m previou s MSD S i n thi s area .

Th e informatio n eonttint d he r ti n i t base d e n dat a considere d accurate . However , n e warrant y I s espresso * e r Implie d regardin g th « accurac y o f thes * dat e e r th e result s t e b e obtaine d fro m th e us * thereof , •.ohm an d Haa s Compan y assume s n e responsibilit y fo r ptrsong l injury o r propert y damag e t o »*nd**S . user s o r thir d partie s ceust d fry th e material . Suc h venaee s o r user s sssum * * H risk s associate d wit h th e us * o < th e material .

PAG E 9 o f9 

# I IP.7 3

• ! • 

# Dow U.S.A. Material Safety Data Sheet Emergenc y S17 636-4400

Produc t Code : 8135 2 Product Name : STYREN E MONOME R Effectiv e Date : 10/17/9 0 Dat e Printed : 07/03/9 1 Page : 1

MSDS-.00025 8
1 . INGREDIENTS : (

% w/w . unles s otherwis e noted ) Styrene , minimu m (Inhibitor : p-t-butylcatecho l 5 5 PP m » max. ) CAS # 000100-142- 5 99-6 % CAS # 027213-78- 1 Thi s documen t i s prepare d pursuan t t o th e OSH AHazar d Communicatio n Standar d (2 9 CF R 1910.1200) . I n addition , othe r substance s no t 'Hazardous ' pe r thi s OSH AStandar d ma yb e listed . Wher e proprietar yingredien t shows , th e identit yma yb e mad e availabl e a s provide d i n thi s standard .

2 . PHYSICA

L DATA : BOILIN G POINT : 293F , l^ C VAP . PRESS : U.S

mmH g @ 20 C VAP :
. DENSITY : 3. 6 SOL . I NWATER : 0.03 2 @ 25 C SP . GRAVITY : .903 1 * @ 25/25 C APPEARANCE : Colorles s liquid , 00OR : Swee t odor .
3 . FIR E AN D EXPLOSION

HAZAR D DATA : FLAS H POINT : 88F ; 31 C METHO D USEO : Ta g Close d Cu p FLAMMABL E LIMIT S LFL : 1. 1 Vol . % UFL : 6. 1 Vol . % EXTINGUISHIN G MEDIA : Wate r fog , foam , alcoho l foam , carbo n dioxide , dr ychemical . (Continue d o n pag e 2 ) (R ) Indicate s a Trademar k o f Th e Do wChemica l Compan y

^P.7 4



### D o w Chemica l U.S.A. * Midland , M l 4867 4 Emergency Phone : 517-636-440 0 Produc t Code : 8135 2 Page : 2 Product Name : STYREN E MONOME R Effectiv e Date : 10/17/9 0 Dat e Printed : 07/03/9 1 MSDS:00025 8

3 . FIR E AN D EXPLOSIO

N HAZAR D DATA : (CONTINUED ) FIR E 6 EXPLOSIO NHAZARDS : Materia l autoignite s a t 9 1 UF , l*90C i n air . Polymerizatio n wil l tak e plac e unde r fir e conditions . I f polymerizatio n occur s i n a close d container , ther e i s a possibilit yi t wil l explode . Coo l storag e container s wit h water , i f expose d t o fire . FIRE-FIGHTIN G EQUIPMENT : Wea r positive-pressure , self-containe d breathin g apparatus ; wea r goggle s i f ey e protectio n i s no t provide d b

yth e breathin g apparatus . 4 . REACTIVIT

YDATA : STABILITY : (CONDITION S T O AVOID ) Polymerize s easily . Stor e belo w90F , 32C . Maintai n inhibito r an d dissolve d oxyge n level . INCOMPATIBILITY : (SPECIFI C MATERIAL S T O AVOID ) Acid , caustic , oxidizin g material , metalli c halide s (salts) . HAZARDOU S DECOMPOSITIO NPRODUCTS : Non e known . HAZARDOU S POLYMERIZATION : Avoi d heat , metalli c (halide ) salt s - suc h a s ferri c an d aluminu mchlorides , unintende d contac t wit h peroxides , an d depletio n o f inhibito r an d oxygen . (Se e sectio n 9 fo r additiona l information. )

5 . ENVIRONMENTA L AN D DISPOSAL INFORMATION : ACTIO NT O TAK E FO R SPILLS/LEAKS : Smal l spil l o r lea k - absor b wit h suitabl e agent , suc h a s san d o r vermiculite ; was h are a wit h soa p an d water . Larg e spil l - contai n wit h dikes , pump wate r int o area , recove r styren e t o b e burne d o r purifie d fo r reuse . Som e absorbents , suc h a s Zorb-all , ma yinitiat e polymerization . (Continue d o n pag e 3 ) ' (R ) Indicate s a Trademar k o f Th e Do wChemica l • Compan y

* A n Operatin g Uni t o f Th e Do wChemica l Compan y 

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Do w Chemica l U.S.A. * Midland . M l 4867 4 Emergenc y Phone : 517-636-440 0 Product Code : 8135 2 Page : 3 Product Name : STYREN E MONOME R Effectiv e Date : 10/17/9 0 Dat e Printed : 07/03/9 1 MSDS:00025 8

5 . ENVIRONMENTA L AN D DISPOSA L INFORMATION : (CONTINUED )

DISPOSA L METHOD : Incinerat e i n properl ydesigne d furnace . Compl ywit h federal , state , an d loca l regulations . Cal l Th e Do wChemica l Compan yfo r additiona l help .
6 . HEALT H HAZAR D DATA : « EYE : Ma ycaus e moderat e irritatio n wit h cornea l injury . Vapor s ma yirritat e eyes . Vapor s ma ycaus e lachrymatio n (tears) . SKI NCONTACT : Prolonge d o r repeate d exposur e ma ycaus e ski n irritation , eve n a burn . Repeate d contac t ma ycaus e dryin g o r flak i n g o f sk i n . SKI NABSORPTION : Asingl e prolonge d exposur e i s no t likel yt o result i n th e materia l bein g absorbe d throug h ski n i n harmfu l amounts . Th e derma l LD5 0 ha s no t bee n determined . Repeate d ski n exposur e ma yresul t i n absorptio n o f harmfu l amounts . INGESTION : Singl e dos e ora l toxicit yi s low . Th e ora l LD5 0 fo r rat s i s 500 0 mg/kg . Smal l amount s swallowe d incidenta l t o norma l handlin g operation s ar e not likel yt o caus e injury ; swallowin g amount s large r tha n tha t ma ycaus e injury . I f aspirate d (liqui d enter s th e lung) , ma yb e rapidl yabsorbe d throug h th e lung s and resul t i n injur yt o othe r bod ysystems . Ingestio n ma ycaus e irritatio n o f th e mouth , throat , an d gastrointestina l tract . INHALATION : Excessiv e vapo r concentration s ar e attainabl e an d coul d b e hazardou s o n singl e exposure . Sign s an d symptom s o f excessiv e exposur e ma yb e anestheti c o r narcoti c effect s an d irritatio n t o uppe r respirator ytract . SYSTEMI C (OTHE R TARGE T ORGAN ) EFFECTS : Repeate d excessiv e 1 (Continue d o n pag e ->) (R ) Indicate s a Trademar k o f Th e Do wChemica l Compan y

* An Operatin g Uni t o f Th e Do wChemica l Compan y 

# 1* 4

### D o w Chemica l U.S.A. * Midland . M l 4867 4 Emergency Phone : 517-636-440 0 Produc t Code : 8135 2 Page : k Product Name : STYREN E MONOME R Effectiv e Date : 10/17/9 0 Dat e Printed : 07/03/9 1 MSDS:00025 8

6 . HEALT H HAZAR DDATA : (CONTINUED )

exposure s t o hig hamount s maycaus e centra l nervou s system , liver , kidne yeffect s an d respirator yo r ey e irritation . Repeate d excessiv e exposure s t o smalle r amount s ma ycaus e centra l nervou s syste meffect s an d respirator yo r ey e irritation . Styren e i s reporte d t o hav e cause d hearin g los s i n laborator yanimal s upo n exposur e t o hig hconcentration s (sixtee n time s th e TL V an d higher) ; however , th e relevanc e o f thi s t o human s i s unknown . CARCINOGENICITY : Fo r hazar d communicatio n purpose s unde r OSH A Standar d 2 9 CF R Par t 1910.1200 , thi s chemica l i s liste d a s a potentia l carcinoge n b yIARC . Neithe r th e dat a fro mvariou s long-ter manima l studie s no r fro m epidemiolog yo f worker s expose d t o styren e provid e a n adequat e basi s t o conclud e tha t styren e i s carcinogenic . TERATOLOG Y (BIRT H DEFECTS) : Birt hdefect s ar e unlikely . Eve n exposure s havin g a n advers e effec t o n th e mothe r shoul d hav e n o effec t o n th e fetus . REPRODUCTIV E EFFECTS : I n anima l studies , styren e monome r ha s bee n show n no t t o interfer e wit hreproduction . MUTAGENICIT Y (EFFECT S O NGENETI C MATERIAL) : Result s o f i n vitr o ('tes t tube' ) mutagenicit ytest s hav e bee n inconclusive . Result s o f mutagenicit ytest s i n animal s hav e bee n inconclusive . 7 . FIRS T AID : EYES ; : Flus heye s wit hplent yo f water . SKIN : Was hof f i n flowin g wate r o r shower . INGESTION : D o no t induc e vomiting . Cal l a physicia n and/o r (Continue d o n pag e 5 ) (R ) Indicate s a Trademar k o f Th e Do wChemica l Compan y
* An Operatin g Uni t o f Th e Do wChemica l Compan y
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Do w Chemica l U.S.A. * Midland . M l 4867 4 Emergenc y Phone : 517-636-440 0 Produc t Code : 8135 2 Page : 5 Product Name : STYREN E MONOME R Effectiv e Date : 10/17/9 0 Dat e Printed : 07/03/9 1 MSDS:O0O25 8

7 . FIRS T AID : (CONTINUED )

transpor t t o emergenc yfacilit yimmediately . INHALATION : I f inhaled , remov e t o fres h air . I f no t breathing , resuscitate . I f breathin g i s difficult , oxyge n shoul d b e administere d b

yqualifie d personnel . Cal l a physicia n o r transpor t t o a medica l facility . NOT E T O PHYSICIAN : Becaus e rapi d absorptio n ma yoccu r throug h lung s i f aspirate d an d caus e systemi c effects , th e decisio n o f whethe r t o induc e vomitin g o r no t shoul d b e mad e b ya physician . I f lavag e i s performed , sugges t endotrachea l and/o r esophagea l control . Dange r fro mlun g aspiratio n mus t b e weighe d agains t toxicit ywhe n considerin g emptyin g th e stomach . I f bur n i s present , trea t a s an ytherma l burn , afte r decontamination . N o specifi c antidote . Supportiv e care . Treatmen t base d o n judgmen t o f th e physicia n i n respons e t o reaction s o f th e patient . Repeate d excessiv e exposur e ma y aggravat e preexistin g live r an d kidne ydisease .
8 . HANDLIN GPRECAUTIONS : EXPOSUR E GUIDELIN E (S) : Styrene , monomer : ACGI H TL V an d OSH APE L ar e 5 0 pp m

TWA , 10 0 pp mSTEL . VENTILATION : Contro l airborn e concentration s belo wth e exposur e guidel i ne . RESPIRATOR Y PROTECTION : Atmospheri c level s shoul d b e maintaine d belo wth e exposur e guideline . Whe n respirator yprotectio n i s require d fo r certai n operations , us e a n approve d air-purifyin g respirator . SKI NPROTECTION : Us e protectiv e clothin g imperviou s t o thi s material . Selectio n o f specifi c item s suc h a s gloves , boots , (Continue d o n pag e 6 ) (R ) Indicate s a Trademar k o f Th e Do wChemica l Compan y

* A n Operatin g Uni t o f Th e Do wChemica l Compan y 

# U

### D o w Chemica l U.S.A. * Midland . M l 4867 4 Emergency Phone : 517-636-440 0 Product Code : 8135 2 Page : 6 

### Product Name : STYREN E MONOME R Effectiv e Date : 10/17/9 0 Dat e Printed : 07/03/9 1 MSDS:00025 8

8 . HANDLIN GPRECAUTIONS : (CONTINUED )

apron , o r full-bod ysui t wil l depen d o n operation . EY E PROTECTION : Us e chemica l goggles . I f vapo r exposur e cause s ey e discomfort , us e a full-fac e respirator .
9 . ADDITIONA

L INFORMATION : SPECIA L PRECAUTION S T O B E TAKE NI NHANDLIN G AN D STORAGE : Practic e car e an d cautio n t o avoi d explosiv e conditions . Equipmen t shoul d b e grounde d durin g transfer , an d non-sparkin g pump s shoul d b e used . Hazardou s polymerizatio n ca n occu r unde r certai n conditions , includin g increase d temperature , lowinhibito r concentration , an d lowoxyge n concentration . T o minimiz e thi s possibility , stor e i n a coo l plac e awa yfro mdirec t sunligh t an d maintai n prope r concentration s o f TB C inhibito r and oxygen . Monito r an d contro l inhibito r leve l a t > 5 pp man d th e dissolve d oxyge n leve l a t a minimu mo f 1 5 ppm . Th e monome r shoul d b e aerate d onc e a wee k fo r abou t 3 0 minutes . Stor e belo w90F , 32C ; idea l storag e temperatur e i s 78F , 26 C o r lower . Avoi d ski n an d ey e contact . Avoi d breathin g vapors . Refe r t o bulleti n 115-608 , "Th e Oo wFamil yo f Qfyropi/

- "^""r 1 1 , MSD S STATUS : Revise d sectio n 3 . 6 , 7 an d 8 .

Fo r informatio n regardin g state/provincia l an d federa l regulation s se e (R ) Indicate s a Trademar k o f Th e Do wChemica l Compan y

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### D o w Chemica l U.S.A. * Midland , M l 4867 4 Emergenc y Phone : 517-636-440 0 Produc t Code : 8135 2 Page : R- l Product Name : STYREN E MONOME R Effectiv e Date : 10/17/9 0 Dat e Printed : 07/03/9 1 MS0S:OOO25 8



### REGULATOR YINFORMATION : (No t mean t t o be all-inclusive—selected regulation s represented. ) NOTICE : Th e informatio n herei n i s presente d i n goo d fait h an d believe d t o b e accurat e a s th e effectiv e dat e show n above . However , n o warranty, ! expres s o r implied , i s given . Regulator yrequirement s ar e subjec t t o chang e an d ma ydiffe r fro mon e locatio n t o another ; i t i s th e buyer' s responsibilit yt o ensur e tha t it s activitie s compl ywit h federal , stat e o r provincial , an d loca l laws . Th e followin g specifi c informatio n i s mad e fo r th e purpos e o f complyin g wit h numberou s federal , stat e o r provincial , and loca l law s an d regulations . Se e MS D Shee t fo r healt h an d safet yinformation . 

### U.S . REGULATION S

SAR A31 3 INFORMATION : Thi s product contain s th e followin g substance s subjec t t o th e reportin g requirement s o f Sectio n 31 3 o f Titl e I I I o f th e Superfun d Amendment s an d Reauthorizatio n Ac t o f 198 6 an d U O CF R Part 372: ' CHEMICA L NAM E CA S NUMBE R CONCENTRATIO N STYREN E 000100-I.2- 5 9 9 *

SAR AHAZAR D CATEGORY : Thi s produc t ha s bee n reviewe d accordin g t o th e EP A"Hazar d Categories " promulgate d unde r Section s 31 1 an d 31 2 o f th e Superfun d Amendmen t and Reauthorizatio n Ac t o f 198 6 (SAR ATitl e III ) an d i s considered , unde r applicabl e definitions , t o mee t th e followin g categories : A n immediat e healt h hazar d Adelaye d healt h hazar d Afir e hazar d Areactiv e hazar d (Continue d o n pag e R-2 ) (R ) Indicate s a Trademar k o f Th e Oo wChemical-Compan y

* A n Operatin g Uni t o f Th e Do wChemica l Compan y 

# ytP.8 0

i 250in i pe

r\<N U a i ates ttemperatur

e 0 1 55' C (I30T) . as •Jetem-une

d b y jpecm e testmethod 26 1 21 . I f i i is asoli d wast

e tha i exhibits the characteristi cof cor rosivity . bu

tis no tliste d a s ahazardou s wast e in subpar

tD . the n i l has the EP

A hazardous wast

e numberof

D 002 .
Reactivit y The reactivit

y characteristi cidentifie s wast e which unde r routine condition s present s ahazar d becaus e o f

instabilit y o rex treme reactivity , an

d the tendenc

y to explode . A materia l is con sidered reactive i

f arepresentative sampl e ofth e wast e ha s an y o f th e followin g propenies : I . Composition / Liqui d

2 . 3 . 4 . 5 .
6 . I f i ti s normally unstable an d readily undergoe s violen tchang e withoutdetonating . I f i treact s violentl y wit

h water. I f i tforms potentially explosiv e mixture s wit h water. if . when mixed wit

h water, i tgenerate s toxi cgases , vapor s o r fume s in aquantit

y sufficientto presen tadangert o huma n healt h o renvironment . I f i ti s acynaide - o rsulfide-bearin g waste , which , when ex pose d to p

H condition s betwee n 2 an d 12.5 . can generat e toxi c gases , vapor

s o rfumes in aquantit y sufficientto present dangert o huma

n healt h o renvironment . I f i ti s capabl e o f

detonatio n o rexplosiv e reactio n whe n sub jecte d 1 0 aj'.ron g initiating sourc e o rif

heale d underconfine ment . If ii i s readily capabl e of

detonatio n o rexplosiv e decomposi tio n o rreaction a

tstandar d temperature o rpressure . I f i ti s aforbidde

n explosiv e a s defined i n 4 9 Cod e o f Federa l Regulation s 173.51 , o raClas s A explosiv e a s defined in 4 9 Cod e o f Federa l Regulation s 173.53 , o raClas s B explosiv e a s defined in 4 9 Cod e o f

Federa l Regulation s 173.88. If i ti s asoli d wast

e tha texhibits th e characteristi co f reactivity, bu ti s notliste d a s ahazardous wast e in subpa n D , then i

tha s th e EP A Hazardous Wast

e numbero f

D 003 .
Toxicit y Th e toxicit

y characteristi cidentifie s waste whic h ma y release toxi cmaterials in sufficien tamount s to pos e asubstantia

l hazar d to huma n healt h o rthe environment . 1 . I f the extractfro

m arepresentative sampl e o f waste contain s an y o f the contaminant

s liste d in Table I o f

4 0 Cod e o f

Federa l Regulation s 261.2 1 a

taconcentratio n equal to o rgreate rtha n th e respective value give n in tha ttable . Wher e th e waste con tains les s tha

n O. S percen tfilterabl e solids , th e wast e itsel f afte r filtering i s considere d to b e th e extractfo rth e purpos e o f this section. (Determine d usin g specifi ctes tmethod s describe d i n Appendi x II. ) 2 . I f i ti s asoli d wast

e tha texhibits th e characteristi co f extractio n procedure toxicity , bu

ti s notliste d a s ahazardou s waste in sub pa n D , has the EP

A Hazardou s Wast

e numberspecifie d i n Table I o f

4 0 Cod e o f

Federa l Regulation s 261.2 1 whic h cor responds to the toxi ccontaminantcausin g itto b e hazardous .
TH E PULTRUSIO

N PROCESSIN

G FACILIT

Y Hazardou s Wtst e Classificatio

n Th e followin g pultrusio n mix fonnulatio n wa s use d a s atypica l sampl e submitted fo

rwast e characterizatio n analysis . I n i u liqui d sttt e i twa s determined to b e ahazardou s waste base d upo n it s ignitability . 2 /SESSIO N 12-

A Unsaturated polyeste rRe s Siyren e i n (in styrene ) Polyviny l Acetate Copolyme r PigmentComponents Inorgani cFille r Magnesiu m Carbonat

e Alcoho l Phosphat

e

p H Density 1 . Corrosivity 2 . Reactivity-Sulfid e

Cyanid e 3 . Flas h Point 4 . EPToxicity (mg/L ) Arseni c Silve r Barium Cadmiu m Chromium Mercury Lead Seleniu m NA = Non-Applicabl e Wast e Analysi s Result s N A 1.04 g/ml < 1 mm/year <0. 1 mg/k g <0. 1 mg/k g 75* F (24* Q <0.0 5 <0.0 2 <1. 0 <0.0 I <0.2 7 <0.00 1 <0.0 2 <0.0 5 58-W *

15-20 % 2-4 % 0.50-0.77 % 16.32-24.32 % 130-0.32 % 0.05-1.0 % EP A Standar

d (Max . Allowable )

>6.3 5 mm/yea r 50 0 mg/k g 2S 0 mg/k g < 140 # F (60*C ) 5. 0 5. 0 100. 0 1. 0 5. 0 0.0 2 S. O 1.0
Th e precedin g pultrusio n mix fonnulatio n afte rsolidificatio n wa s use d a s atypical sampl e submitte d forwast

e characterizatio n analysi s an

d in its soli d sut e was evaluated a s non-hazardous , a s i t di d no texcee d establishe d limit s forth e fourbasi ccriteri adefined .

Composition/Soli d Unsaturated polyeste rResi n (i n styrene ) Styren e Polyviny l Acetate Copolyme r PigmentComponents Inorgani cFille r Magnesiu m Carbonat

e Alcoho l Phosphat

e Bi s (4- 4 Butylcyclohexyl ) Peroxydicarbonate ±Butyl Perbenzoate

p H Density 1 . Corrosivity 2 . Reactivity-Sulfid e

Cyanid e 3 . Flas h Point 4 . E PToxicit y (mg/L ) Arseni c Silve r Barium Cadmiu m Chromiu m Mercury Lead Seleneu m Wast e Analysi s Resul u N A 1.0 4 g/m l 1 mm/yea r 0. 1 mg/k g 0. 1 mg/k g 230° F (110 # C ) 0.0 5 0.0 2 I. O 0.0 1 0.0 7 0.00 1 0.0 6 O.O S 73-83 %

0.5 % 2-4 % 0.50-0.77 % 16.32-24.32 % 0.30-0.32 % 0.05 % 0.40-0.80 % 0.20-0.40 % EP A Standar

d (Max . Allowable )

6.3 S mm/yea r 50 0 mg/k g 25 0 mg/k g 140 # F (60 # C ) 5. 0 5. 0 100. 0 1. 0 5. 0 0.2 0 S. O 1.0 N A = Non-Applicabl e Th e cos to f

th e wast e characterizatio n analysi s b y a n indepen den tla b i s approximately $11000 0 and wil l tak e 4- 6 weeks . Q 

# y] K 3P.8 1

< \ Th e materia

l in u s soh d <SJI

C I S mw-ha/jrdou s an

d ca n b e dis pose d o f withoutregulations . Th e materia l i n it s liquid stale i s a hazardous wast

e an d i s regulated underRCRA . an d mustb e sent o afederally approved hazardous wast e managemen

tfacilit y transported solel y by EP A authorized transporters . I n orde rto d o so . yo u mus tnotif y the Environmenta

l Protection Agency o ryour authorized Stat

e Agency of

youractivitie s an

d apply fo

raU.S . EP A identificatio n number. Yo u ca n satisf y thes e requirements b

y filling For

m 8700-1 2 'Notificatio n o f Hazardou

s Wast e Activity, " submittin g on e notificatio n for m pe rsic e o rlocation . Al

l informa tio n you submiti

n the notificatio n ca

n be released to the public . RCR A requires a

n EP A identificatio n numbe

ran d ahazardous wast e manifes ti o accompany the wast e to it s fina l destination . Th e manifes ti s atrackin g documentdesigne d to recor d the movement o f hazardous waste fro

m th e generator' s premises to the authorized off-site treatment , storage , o rdisposal facility . On-site wast e man agemen tdoe s notrequir e amanifest . A

tthis time , the En vironmental Protectio n Agency allow s wast e treatmen

twithout penni tbu

tdoe s cautio n the policy ma y b e changed . Thi s allow s smal l companie s t

o trea thazardous waste , t

o reacton-sit e unuse d thermosettin g plasti crcsi n int o iner tsoli d wastes , withoutapermit a s lon g as th e waste i s treate d withi n 18

0 days an d the volum e o f accumulate d waste doe s no texcee d 600 0 k

g (13,20 0 lbs. ) a

tan y on e time .
EMISSIO N CONTROLS Understanding ho wt

o determin e i

f yourwast

e i s hazardous an

d ho wto dispos e o f

i ti s a n importa m firs tstep , i f you ar e amanufac ture ro f fiberglas s reinforced plasti ccomposite profiles , you als o have to compl y with yourState' s regulation s o n plan toperations . Al l permits an

d regulations referred to in the followin g discus sio n wil l be in regard to anewpultrusio n facilit y in Ohio . Th e Ohi o Environmenta

l Protectio n Agenc

y requires a

n applicatio n for penni tto install forall newo rmodified source s o f pollutio n unde r th e provision s o f

OA C Rule 3745-31 . Th e significantinformatio n required o n thi s permiti s adescrip tio n o f th e producto rservic e to b e produced an d adescriptio n o f th e sourc e o rfacility . Als o includ e alis tnamin g all material s and chemical s and quantitie s tha twil l b e used o rproduced b y th e sourc e o rfacility. Forall airpollutio n source s you ar e required t o provid e actua

l (i f measured ) o restimate d emission s statin g th e amoun to f eac h aircontaminantfro m eac h sourc e in pounds pe r hou ran d tons pe ryeara

tmaximum an

d averag e conditions . Fo rexample , the source s o f emissio n wil l be : Sourc e Maximum * 1 . Pultrusio n Machin e (mono meremission s a

tresi n bat

h and di e exit ) Mi x Room (monomer ) 2 . Dus tCollectio n Cu tof f saw s Ma tSlittin g Fibe rcollectio n HX ) CFM . 20 0 PP

M = .3 3 lbs/hr * o r1.38 tons/y r 10 0 CFM . 20 & PP

M = 3 3 lbs/hr * o r1.38 tons/y r 35 0 CFM = .05 6 lbs/h ro r .2 3 tons/yr * 50 0 CFM = .1 4 Ibs/h ro r .5 8 tons/yr *
"Averag e t o b e determine

d base d o n leve l o f operatio n afte rareasonabl

e perio d o f time. 'Lbs/h rbase d o n 2 4 hour s pe rday . 348 day s pe ryea roperation. 'Ous tcollection estimate

d o n a n averag e produc tweigh to f materia l dis place d b y th e thickness of

th e anting blade

. 'Ma ttlining estiinate

d o n a n avenge amoun

to f sli twidth s pe rrol l o f materia l displace d b y th e thicknes s o f th e slinin g blade. The applican tmus tsui ctha i h e wil l U M ihe bestavailable tech nology , o rtechnology tha ti s recognize d as acceptabl e throughou t the pultrusio n industr

y an d considere d standar

d an d cos teffective t o control emissions . Thi s can b e accomplishe d b y th e us e of resin s wuh lowlevel s o f

styrene nwnomer . exposur e o f a s littl e styrene monome ro rstyrenate

d resin to th e atmosphere a s possible , the us e o f smalle ran

d deepercontainers , keepin g containers of thi s materia l covered (ora

s close d a s possible ) an d finall y collectin g dust(fiberglas s particulates ) whic h i s exhausted int o ahig h effi ciency collecto rsystem . An Appendix (Appendix A . Proces s Data) fo reac h ai rcontami nan tsourc e mus

taccompan

y th e application . The significantinfor mation require

d i n the Appendi x i s aproces s flo w diagra m showin g entr

y an d exi tpoints o f

al l ra wmaterials , intennediate products , by-products , an d finished products . Emissio n dat a shoul d be included whethe riti s actua l o rtheoreticall y determin ed . Figure I i s aflow diagra m o f apultrusio n machine lin e show ing all information tha

ti s required . Dat

awa s collecte d wit

h atoxi c ga s detecto ra

tthe liquid entry and finished produc texi tpoints (Exhaus tI) . Wit

h a n exhaus tductvelocity seta t8 5 CFM a

tbo t points , the highes treadin g achieve d wa s IO

O PP M directly overth

< liqui d entr

y an d 2 5 PP M a tth e finishe d productexi t(se e Tabl e I ) Figure 1 show s dustcollectio n o f fiberglass particulates (Exhaus i 2 ) a tthe sa wstation , whic h wa s estimate d base d o n a n avtrag t produc tweigh to f

materia l displace d by th e cuttin g blade thic k ness . Figur

e 2 is aflow diagram o f

ami x roo m showin g al

l infor matio n tha

ti s required , alon g with dal acollecte d using the um e ga s detecto rwit

h the same exhaus tduc

tvelocity . I2

S PP M directl y ove rthe mixe rwas the highes treading achieve d (se e Table 2) . Figure 3 show s the dustcollectio n o f fiberglass particulates (Exhaus t2 ) a

tth e ma tslitter , whic h wa s estimate d based o n a n average amoun

to f slitwidth s pe rroll o f

materia l displace d b

y th e slittin g blad e thickness . Th e final approva l o f th e "Permit

s t o In stall * normally wil l tak

e 3- 4 month s atacos to f $150 0 fo reac h sourc e o f emission . Fo

rexample , atwo-machin e operatio n wit h mixin g an

d slittin g capabilit

y woul d hav e si x emissio n source s base d o n th e flow chart

s described . When you hav

e receive d final approva

l o f th e penni tto install , you mustnotif

y the appropriat

e distric toffic e of

the EP A o rlocal ai ragency , in writing , o f th e construaio n starting date , the con structio n completio n date , and th e dat e th e facilitie s wil l b e place d in operation . They wil l the n sen d a n applicatio n forapenni tto operate . Thi s permi

tcove rshee trequires information similarto the permi tto install . I

f n o change s have occurred , the previously complete d Appendix A (Proces s Data) ca n b e attache d to the ap plication . Th e final approva l o f th e "Permit

s t o Operate * normally wil l tak e 2- 3 week s a

ta n additional cos to f

$15.00 fo reac h sourc e o f emission .
CONCLUSION

S Th e disposal o f

soli d and hazardou s waste has bee n agrav e con cer n notonl y to the Federa l Government , bu

tals o th e public . Dis posal o f material s ha

s becom e increasingl y more difficultbecaus e o f th e continuin g technologica l advance s in developmento f raw material s an

d methods o f

manufacturing , and th e potentia l lon g ter m change s in raw material s thatare discarded . Disposal o f soli d and hazardou s waste in o rom o lan d withou tcareful planning and managementcan presen tadange rto huma

n healt h an d th e en vironment . Th e objective s o f

the Regulatory Program s are t o promot e the protectio n o f

healt h an d th e environmen tand t o develo p wast e managementplan s (RCRA ) whic h wil l promote improve d wast e managementtechnique s and environmentall y saf e disposal o f

non recoverabl e residues. Othe rwast e managementsystem s such as Subtitl e C o f

th e Cod e o f

Federal Regulation s enforce s a"cradl e to grave " contro l approach .

K A 

# ^ D SESSION I2-A/ 3 (P.8 2

Tli e icmforce d plastic s industry h.i s becom e a foca l poin t f.i r Federa l an d Sute agencie s concernin g styren e an d paniculat e emission s insid e a facilit y a s wel l a s transferrin g these emission s outsid e th e facility . Al l o fth e regulation s an d requirements ir e tim e consumin g an d costly , bu t the y d o slowdow n th e chai n o f events o fcontaminatin g th e environment . Hopefully , th e rein force d plastic s industr y wil l continu e t o tak e a constructive rol e i n reachin g solution s t o problem s an d minimizin g th e need fo r ex cessive regulatio n i n th e future . RKFERENCK S 1 . Code o

fFedera l Regulations Titl e « 0 ftiru 190-399 . Subchapte r I Soli d U-aMo . Paf u 26 a 261 . 262 {Revised a s o fJul y I . 1985) . 2 . "Environmenta l Protectio n Agenc y Hazardou s Wisi e Propose d Guide line s an d Regulations in d Propose d o n Identificatio n in d Listing. " Federal Refiner. Par

t I V (Decembe r 18. 1978) .

. V Th e Resourc

e Cooservitio n an d Recover y Act . Publi c La

w94-580 . 94t h Congres

s (Ociobe r 21 . 1976) . BIOGRAPHIE S Kennet h J . Elia s Mr . Kennet h J . Elia s i s th e Directo r o fManufacturin g fo r Pultrusio n Technology . Inc . an d Viapu l Corporation . H e received a n associates degree i n Electro-Chemica l Technolog y fro m Cleve lan d Institut e o fTechnolog y i n 1969 . Afte r spendin g seve n yea n a t Fireston e Tir e an d Rubbe r Compan y i n plasti c processin g re search . Mr . Elia s joine d a divisio n o fMonogra m Industrie s an d spen t si xyea n a

s a proces s enginee r i n th e pultrude d product s group . I n 1982 , Ke n Elia s joine d Pultrusio n Technology . Inc . I n 1986 . Ke n Elias . Jef

fMartin , an d Jo

e Sumera k

forme d Viapu l Corpora ' tion . a pultrusio n manufacturin g developmen t entity .

Daw n K . Wilkin s Mrs . Daw n K . Watkin s i s a 1967 graduat e o f Miam i Universit y o fOhi o wher e sh e obtaine d a Bachelo r o f Scienc e Degre e i n Ap plie d Science . Sh e has spen t te n years i n a supervisory positio n i n th e graphic s an d graphic s managemen t functio n wit h a great dea l o fcustome r servic e responsibility. l n earl y 1986 , Mn . Watkin s cam e t o Pultrusio n Technology , Inc . a s Sale s Servic e Administrator . I n thi s role, sh e function s external l y i n a custome r servic e rol e whil e internall y sh e i s responsibl e fo r th e establishmen t an d integratio n o fsystem s t o penni t a smoot h in teractio n betwee n department s at Pultrusio n Technology , Inc . TABI E 1 . Appendi xA o f"Permi t l o Operoie. " EMISSIO N DATA * Exhaus t 1 - Machin e Emissio n Tes t No .

I 1 2 3 4 5 6 7 8 Resi nStation / Liqui d Entr y 3 5 PP M 10 0 PP M 9 5 PP M 3 0 PP M 3 5 PP M 5 0 PP M 3 0 PP M 5 0 PP M Exhaus t 1 Finishe dProduc t Exi t 1 5 PP M 5 PP M 2 5 PP M 8 PP M 1 5 PP M "* 2 0 PP M 1 0 PP M 1 5 PP M Mi xRoo

m Emissio n 

# f\J .

Tes t No . 1 2 3

- 4 5 6 Hig hDispersio nMixe r 4 0 PP M 3 5 PP M 8 0 PP M 8 5 PP M 12 5 PP M 9 5 PP M 

# # 0 A

* Duc t velocit y

se t a t 8 5 CFM , PP M reading s wit htoxi c ga s detecto r I8014-400 A 4/SESSIO

N 12- A % K'P.8 3



### Marvi nWindows Windo w an dDoor Lineal s Plan t

ProposedPermi t t o Construc t

Appendi xB

Divisionof Environmenta l Engineerin g Nort hDakot a Stat e Departmen t o f Healt h an dConsolidatedLaboratorie s 120 0 Missour i Avenue , Roo m 30 4 Bo x552 0 Bismarck , N

D 58502-552 0 

# yxP.8 4



### (Proposed ) AI RPOLLUTIO

N CONTROL PERMI T T O CONSTRUC T

Pursuan t t o the Ai r Pollutio nContro l Rule s of th e Stat e o f Nort h Dakot a (Articl e 33-1 5 o f th e Nort hDakot a Administrativ e Code) , the Nort hDakot a Stat e Departmen t of Healt han dConsolidated Laboratorie s hereb y grant s a Permi t t o Construc t fo r th e followin

g facility :

I . Genera l information : i i 

### A . Source : 1 . Name : Marvi nWindows 2 . Location : 15t hAvenue & 44thStree t N W Fargo , Nort hDakot a 5810 2 3 . Sourc e Type : Windo w an dDoo r Lineal s Plan t 4 . Equipmen t at th e Facility :

a . Fiv

e pultrusionmachines , Pulsa r Model s 80 5 an d1606 .
b . Mixin

g roo m an dresi nbul k tan

k roo m (4-6,000 - gallo nstorag e tanks) . Resi nconsist s o f

, styrene an

dmethy l methacrylate .

c . One matslitter , Pulsa r Mode l 7824 .


## O 

# Hi

### P.8 5

d . Fiv e cut-of f saws .

e . Too l an

d di e room .
Th e facilit ywil l utiliz e th e followin g ai r pollutio n contro l equipment :

1 . Catalyti c oxidize r fo r th e contro l o r volatil e organi c compounds . Th e exhaus t fo r th e catalyti c oxidize r wil l b e vente d t o th e outsid e air .
2. Bagfilte r fo r th e contro l o f particulat e matte r (fiberglass) . Th e exhaus t fo r th e bagfilte r wil l b e vente d bac k int o th e building .

B . Owner/Operato r (Permi t Applicant) :
1 . Name : Marvi n Window s 2 . Address : 80 4 3 24t h Avenu e Sout h

Minneapolis , M

N5542 5 3 . Applicatio n Date : Jul y8 , 199 1
Thi s Permi t t o Construc t i s subjec t t o al l applicabl e rules , regulations , an

d order s no wo r hereafte r i n effec t o f th e Nort h Dakot a Stat e Departmen t o f Healt h an d Consolidate d Laboratorie s and t o th e condition s specifie d below : 

# yP.8 6



### II . Permi t Conditions :

A . Specia l Conditions :

1 . Emissio n Limits : Th e emission s o f ai r contaminant s fro mth e sourc e uni t shal l no t excee d th e following rates :

Sourc e Uni t Contaminan t •Emissio n Rat e Catalyti c Oxidize r Styren e Methy l Methacrylat e Odor s 0.52 8 lb/h r 0.10 2 lb/h r 2 odo r concentratio n unit s
*Th e catalyti c oxidize r mus t als o contro l volatil e organi c compoun d emission s fro mth e sourc e uni t b ya t leas t 95% .
2 . Performanc e Testing : Following completio n o f constructio n an

d withi n 6 0 day s afte r achievin g th e maximu m productio n rat e a t whic h th e facilit ywil l b e operated , bu t no t late r tha n 18 0 day s afte r initia l start-u

p o f th e facility , th e owne r o r operato r shal l conduc t performanc e test s o f th e catalyti c oxidize r a s specifie d b ythi s Department . Additiona l requirement s ar e a s follows :



# 4 5P.8 7



### a . Tes t method s an d procedure s use d shal l b e thos e se t fort h i n th e Nort h Dakot a Ai r Pollutio n Contro l Rules , 4 0 CF R Par t 60 , Subpar t V W - Standard s o f Performanc e fo r Polymeri c Coatin g o f Supportin g Substrate s Facilities , o r equivalen t method s approve d b y th e Departmen t an d th e U.S . Environmenta l Protectio n Agency . Performanc e tes t guideline s shal l b e obtaine d fromthi s Departmen t prio r t o developin g testin g procedure s t o ensur e the ywil l compl ywit h th e specifie d requirements .
b . Th e Departmen t shal l b e notifie d 3 0 day s prio r t o th e dat e o f th e test s t o allo wfo r a pretes t meetin g wit h th e Departmen t an d t o affor d th e Departmen t th e opportunit yt o hav e a n observe r present . Th e tes t result s shal l b e submitte d t o th e Departmen t fo r revie wand approval .

c . Saf e sampling platform s shal l b e provided . Utilitie s fo r samplin g an d testin g equipmen t shal l b e provided . Plan s and specification s showin g th e siz e an d locatio n o f th e ports , platform s an

d utilitie s shal l b e submitte d t o th e Departmen t fo r revie wand approval .



# UP.8 8



### 3 . Th e facilit ymus t compl ywit h al l applicabl e provision s outline d i n 4 0 CF R Par t 60 , Subpar t V W

- Standard s o f Performanc e fo r Polymeri c Coatin g o f Supportin g Substrate s Facilities .

B . Genera l Conditions :

1 . Thi s permi t shal l i n n o wa ypermi t o r authoriz e th e maintenanc e o f a publi c nuisanc e o r dange r t o publi c healt h o r safety .
2 . Th e owner/operato r identifie d i n ItemI.B . o f thi s permi t shal l compl ywit h al l Stat e and Federa l environmenta l law s an d rules . I n addition , th e owner/operato r shal l compl ywit h al l loca l building , fire , zoning , an d othe r applicabl e ordinances , codes , rule s an d regulations .
3 . Constructio n o f th e abov e describe d facilit yshal l b e i n accordanc e wit h informatio n provide d i n th e permi t applicatio n a s wel l a s an yplans , specification s and supportin g dat a submitte d t o th e Department . Th e Departmen t shal l b e notifie d te n day s i n advanc e o f an ysignifican t deviation s from th e specification s furnished . Th e issuanc e o f thi s Permi t t o Construc t ma yb e suspende d o r revoke d i f th e Departmen t determine s tha t a significan t 

# 43 -P.8 9



### deviatio n fro

mth e plan s an d specification s furnishe d ha s bee n o r i s t o b e made .
4 . Al l reasonabl e precaution s shal l b e take n b yth e owne r t o preven t and/o r minimiz e fugitiv e emission s durin g th e constructio n period .
5 . Withi n thirt yday s afte r completio n o f construction , thi s Departmen t mus t b e notifie d o f th e dat e o f completio n o f constructio n and th e actua l o r propose d dat e o f startup .
6 . An ydul yauthorize d officer , employe e o r agen t o f th e Nort h Dakot a Stat e Departmen t o f Healt h and Consolidate d Laboratorie s ma yente r an d inspec t any property , premis e o r plac e a t whic h th e sourc e liste d i n ItemI.A . o f thi s permi t i s o r wil l b e locate d a t an

ytim e fo r th e purpos e o f ascertainin g th e stat e o f complianc e wit h th e Nort h Dakot a Ai r Pollutio n Contro l Rule s an d th e condition s o f thi s permit .
7 . Anyviolatio n o f a conditio n issue d a s par t o f thi s approva l t o construc t a s wel l a s anyconstructio n whic h proceed s i n varianc e wit h anyinformatio n submitte d i n th e application , i s regarde d a s a violatio n o f constructio n authorit yand i s subjec t 

# 1%

### t o enforcemen t action .
8 . Thi s Permi t t o Construc t shal l becom e invali d i f constructio n i s no t commence d withi n eightee n month s afte r receip t o f suc h permit , i f constructio n i s discontinue d fo r a perio d o f eightee n month s o r more ; o r i f constructio n i s no t complete d withi n a reasonabl e time .
9 . Thi s Permi t t o Construc t i s issue d i n relianc e upo n th e accurac yand completenes s o f th e informatio n se t fort h i n th e application . Notwithstandin g th e tentativ e natur e o f thi s information , th e condition s o f thi s permi t herei n become , upo n th e effectiv e dat e o f thi s permit , enforceabl e b yth e Departmen t pursuan t t o an yremedie s i t no wha s o r ma yi n th e futur e have , unde r th e Nort h Dakot a Ai r Pollutio n Contro l Law , NDC C Chapte r 23-25 . Eac h and everyconditio n o f thi s permi t i s a materia l par t thereof , an

d i s no t severable .

FOR TH E NORT H DAKOTASTAT E DEPARTMENT O F HEALT H AN D CONSOLIDATE D LABORATORIE S

Dat e By _ Dan a K . Mount , Directo r Divisio n o f Environmenta l Engineerin g 

# a 

# T |P.9 1



### Marvi nWindows Windo w an dDoo r Lineal s Plan t

ProposedPermi t t o Operat e

Appendi xC

Divisiono f Environmenta l Engineerin g Nort hDakot a Stat e Departmen t o f Healt h an dConsolidatedLaboratorie s 120 0 Missour i Avenue , Roo m 30 4 Bo x552 0 Bismarck , N

D 58502-552 0 

# °1 DP.9 2



### (Proposed ) AI R POLLUTIO NCONTRO L PERMI T T O OPERAT E

Pursuan t t o Chapte r 23-2 5 o f th e Nort h Dakot a Centur yCode , an d th e Ai r Pollutio n Control ; Rule s o f th e Stat e o f Nort h Dakota , an d i n relianc e o n statement s and representation s heretofor e mad e b yth e owne r designate d below , a Permi t t o Operat e i s hereb yissue d authorizin g suc h owne r t o operat e th e sourc e unit(s ) a t th e locatio n designate d below . Thi s Permi t t o Operat e i s subjec t t o al l applicabl e rule s an d order s nowo r hereafte r i n effec t o f th e Nort h Dakot a Stat e Departmen t o f Healt h and Consolidate d Laboratorie s an d t o an ycondition s specifie d below : 1 . Owner :
A . Nam e Marvi n Window s B . Addres s 804 3 24t h Avenu e S Minneapolis , M

N5542 5 2 . Permi t Numbe r

3 . Installatio n Windo w& Doo r Lineal s Plan t 4 . Installatio n Locatio n 15t h Avenu e & 44t h Stree t N W Fargo , Nort h Dakot a 5810 2 Cas s Count y 5 . Expiratio n Date : 6 . Sourc e Unit(s) : Awindo wand doo r lineal s plan t consistin g o f th e followin g proces s equipment : 1 ) Fiv e pultrusio n machines , Pulsa r Model s 80 4 and 1606 . 2 ) Mixin g roo man d resi n bul k tank room(4-6,000-gallo n storag e tanks) . Resi n consist s o f styren e an d methy l methacrylate . 3 ) On e matslitter , Pulsa r Mode l 7824 . 4 ) Fiv e cut-of f saws . 5 ) Too l and di e room . Th e facilit ywil l utiliz e th e followin g ai r pollutio n contro l equipment : 1 ) Catalyti c oxidize r fo r th e contro l o f volatil e organi c compounds . Th e exhaus t fo r th e catalyti c oxidize r wil l b e vente d t o th e outsid e air . 

# q i

### 2 ) Bagfilte r fo r th e contro l o f particulat e matte r (fiberglass) . Th e

exhaus t fo r th e bagfilte r wil l b e vente d bac k int o th e building .
CONDITION S 7 . A . Emissio n Limits : Emissio n limit s fromth e operatio n o f th e majo r

sourc e unit(s ) identifie d i n Item6 o f thi s Permi t t o Operat e (hereafte r referre d t o a s "permit" ) ar e a s follows : Source * Ai r **Emissio n Uni t Contaminan t Limi t Catalyti c Styren e 0.52 8 lb/h r Oxidize r Methy l Methacrylat e 0.10 2 lb/h r •Mino r sourc e unit s no t liste d ar e subjec t t o th e applicabl e emissio n limit s specifie d i n th e Nort h Dakot a Ai r Pollutio n Contro l Rules . ••Th e catalyti c oxidize r mus t als o contro l volatil e organi c compound emission s fro mth e sourc e uni t b ya t leas t 95% . B . Fugitiv e Emissions : Al l reasonabl e precaution s shal l b e take n b y th e owner/operato r t o preven t and/o r minimiz e fugitiv e emission s t o th e outsid e ai r fromth e operatio n o f th e sourc e unit(s ) identifie d unde r Item

6 . C . Emissio n InventoryReports : Emissio n inventoryreport s including , bu t no t limited.t o proces s informatio n regardin g th e amoun t and typ e o f volatil e organi c compound s use d an d ai r contaminant s emitted , shal l b e submitte d t o th e Department , upo n request , o n form s supplie d b

yth e Department . D . Sourc e Operations : Th e owner/operato r shal l operat e th e sourc e unit(s ) describe d i n Item6 o f thi s permi t i n accordanc e wit h statements , representations , procedure s an d supportin g dat a containe d i n th e initia l application , an d an ysupplementa l informatio n o r renewa l application(s ) submitte d thereafter . E . Alterations , Modification s o r Changes : An yalteration , rebuilding , repairing , expansion , chang e i n th e metho d o f operation , o r chang e o f locatio n o f th e sourc e whic h result s i n th e emissio n o f a n additiona l typ e o r greate r amoun t o f ai r contaminant s o r whic h result s i n a n increas e i n th e ambien t concentratio n o f anyai r contaminant , mus t b e reviewe d and approve d b yth e Departmen t prio r t o th e star t o f suc h alteration , rebuilding , repairing , expansion , chang e i n th e metho d o f operation , o r chang e o f location . F . Nuisanc e o r Danger : Thi s permi t shal l i n n o wa yauthoriz e th e maintenanc e o f a nuisanc e o r a dange r t o publi c healt h o r safety .

^

### G . Malfunctio n Notification : Th e owner/operato r shal l notif yth e

Departmen t o f an

ymalfunctio n whic h ca n b e expecte d t o las t longe r tha n twenty-fou r hour s an d can caus e th e emissio n o f ai r contaminant s i n violatio n o f applicabl e rule s and regulations . H . Permi t Renewa l and Invalidation : Thi s permi t shal l b e effectiv e fromth e dat e o f it s issuanc e unti l th e dat e specifie d i n Item5 unles s soone r suspended , revoke d o r surrendered . Applicatio n fo r renewa l o f thi s permi t shal l b e submitte d sixt yday s prio r t o suc h expiratio n date . Th e Departmen t shal l approv e o r disapprov e th e renewa l o f th e permi t withi n sixt yday s o f receip t o f th e renewa l application . I . Ne wSourc e Performanc e Standards : Th e facilit yshal l compl ywit h th e requirement s o f 4 0 CF R Par t 60 , Subpar t V W - Standard s o f Performanc e fo r Polymeri c Coating o f Supportin g Substrate s Facilities . J . Odo r Restriction : Thi s permi t shal l i n n o wa yauthoriz e th e discharg e o f an

yobjectionabl e odorou s ai r contaminan t whic h i s i n exces s o f tw o odo r concentratio n unit s outsid e th e propert y boundary . K . Chang e o f Ownership : Thi s permi t mayno t b e transferre d and i s t o b e returne d t o th e Departmen t upo n th e destructio n o r chang e o f ownershi p o f th e sourc e unit(s) , o r upo n expiration , suspensio n o r revocatio n o f thi s permit . L . Righ t o f Entry : Anydul yauthorize d officer , employe e o r agen t o f th e Nort h Dakot a Stat e Departmen t o f Healt h an d Consolidate d Laboratorie s ma yente r and inspec t an yproperty , premis e o r plac e a t whic h th e sourc e liste d i n Ite m6 o f thi s permi t i s locate d a t an ytim e fo r th e purpos e o f ascertainin g th e stat e o f complianc e wit h th e Nort h Dakot a Ai r Pollutio n Contro l Rules . Th e Departmen t ma yconduc t test s and tak e sample s o f ai r contaminants , fuel , processin g material , and othe r material s whic h affec t o r mayaffec t emission s o f ai r contaminant s fro man ysource . Th e Departmen t shal l hav e th e righ t t o acces s an d copyan

yrecord s require d byth e Department' s rule s and t o inspec t monitorin g equipmen t locate d o n th e premises . M . Othe r Regulations : Th e owner/operato r o f th e sourc e unit(s ) describe d i n Item6 o f thi s permi t shal l compl ywit h al l Stat e and Federa l environmenta l law s an d rules . I n addition , th e owner/operato r shal l compl ywit h al l loca l burning , fire , zoning , and othe r applicabl e ordinances , codes , rule s and regulations . N . Permi t Issuance : Thi s permi t i s issue d i n relianc e upo n th e accurac yan

d completenes s o f th e informatio n se t fort h i n th e application . Th e condition s o f thi s permi t herei n become , upo n th e effectiv e dat e o f thi s permit , enforceabl e b yth e Departmen t pursuan t t o an

yremedie s i t nowhas , o r ma yi n th e futur e have , unde r th e Nort h Dakot a Ai r Pollutio n Contro l Law , NDC C Chapte r 23

- 

# VrP.9 5

25 . Eac h an d ever yconditio n o f thi s permi t i s a materia l par t thereof , an d i s no t severable . FO R TH E NORT H DAKOT ASTAT E DEPARTMEN T O F HEALT H AN D CONSOLIDATE D LABORATORIE S

Dat e , By . Dan a K . Mount , Directo r Divisio n o f Environmenta l Engineerin g



# °tA

### P.9 6

Marvi n Window s Windo wand Doo r Lineal s Plan t

Departmen t Polic yfo r th e Contro l o f Hazardou s Ai r Pollutan t Emission s

i n Nort h Dakot a (Ai r Toxic s Policy ) Appendi x D

Divisio n o f Environmenta l Engineering Nort h Dakot a Stat e Departmen t o f Healt h an d Consolidate d Laboratorie s 120 0 Missour i Avenue , Room30 4

Bo x 552 0 Bismarck , N

D 58502-552 0 

# q^ >P.9 7



### POLICYFO

RTH E CONTROL O F HAZARDOU S AI RPOLLUTANT EMISSION S I N NORT H DAKOT

A (Ai r Toxic s Policy )
PURPOS E Thi s documen t establishe s th e polic y t o be usedb

y th e Nort hDakot a Stat e Departmen t o f Healt han dConsolidatedLaboratories , Divisio n o f Environmenta l Engineering , fo r th e evaluatio

no f permi t application s fro

m source s emittin

g Hazardou s Ai r Pollutant s (HAP's ) int o .th

e ambien t air . Thi s polic y documen t i s effectiv e unti l modifiedb

y th e Departmen t or forma l rule s ar e promulgated . APPLICABILIT Y Thi s documen t i s applicabl e to al l ne w or modifiedai r contaminan t sources , a s designate din33-15-14-0 1 o f the Nort hDakot a Ai r PollutionContro l Rules , require dt o submi t a

napplicationfo r Permi t t o Construc t unde r Sectio n0 2 o f Chapte r 33-15-14 . Thi s includes : (1 ) al l source s designateda s Ai r Contaminan t Sources ; (2 ) an y categor

y o f source s subjec t t o a stat e o r federa l New Sourc e Performanc e Standard(NSPS) ; (3 ) an y sourc e subjec t t o revie w unde r stat e o r federa l Preventiono f Significan t Deteriorationo f Ai r Quality (PSD ) Rules ; (4 ) an y sourc e whos e emission s impac t significantl y stat e o r federa l Ambien t Ai r Qualit y Standard s (AAQS) ; an d(5 ) an

y sourc e subjec t t o Nationa l Emissio n Standard s for Hazardou s Ai r Pollutant s (NESHAP) . Certain , additiona l source s o f HAP' s wil l be considere dfo r emissioncontro l b y th e Departmen t o

na case-by-cas e basi s o r a s deeme dappropriate . Thes e ma y include "nontraditional " source s suc ha s ai r stripper s for th e remova l o f organi c contaminant s fro m groundwater , ethylen e oxide sterilizers , o r an y existing o r new sourc e wher e ther e i s reaso nt o believ

e tha t HAP' s being emitte d pos e a significan t ris k t o huma no r environmenta l health . Source s affectedb y thi s documen t ar e requiredt o complet e anAi r PollutionPermi t Application(A P 100 ) i f a napplicatio nha s no t bee nsubmitted , a HAP Permi t Application(AP-117) , and an y additiona l informationneede db y th e Departmen t t o evaluat e th e potentia l humano r environmenta l ris k fro m HAP's . AUTHORIT Y Th e Departmen t ha s authorit y to contro l HA

P emission s unde r Chapte r 33-15-02-04 , subsection3 o f th e Nort hDakot a Ai r PollutionContro l Rule s whic hstates , "Th e ambient ai r shal l no t contai nai r contaminant s i nconcentration s tha t woul db e injuriou s t o huma n healt ho r well-being o r unreasonabl y interfer e wit hthe enjoymen t o f propert y

o r tha t woul dinjur e plan t o r anima l life . Th e Departmen t ma

y establish , o

na case-by-cas e basis , specifi c limit s o f concentrationfor thes e contaminants. " 

## C\ %P.9 8



### b y variou s local , stat e an dfedera l rules . Particulat e matte r les s than1 0 micron s i ndiamete r (P M ) , sulfu

r dioxide , nitrogen dioxide , carbonmonoxide , an dlea demission s ar e regulate db y placing emission s limit s o ndesignatedai r contaminan t sources . Th e Federa l NSP S progra m regulates , inadditio nt o th

e previousl y mentione dpollutants , the emissionrate s o f fluoride , sulfuri c aci d mist , hydrogensulfide , reduce dsulfu r compounds , an

dvolatil e organic s fro

m selec t sources . Som e effor t ha s beenmad e t o contro l HAP' s o nthe federa l an

dstat e level s throug hthe NESHA

P program . However , promulgationo f ne w NESHAP' s b

y EP A ha s beenslow , requiring 4- 5 years . Presentl y fou r pollutants , asbestos , beryllium , mercury , an dviny l chloride are designate dNESHAP' s unde r the stat e regulation s wit hthree additiona l pollutants , benzene , radionuclides , an darsenic , regulate dat the federa l leve l for certai nfacilities . Also , th e NESHA P progra

m ha s concentrated o npollutant s posin g a nationa l healthrisk , no t a loca l healt h risk . Smal l populationcenter s ar e oftenoverlookedi nth e federa l process . Increase dloca l an dnationa l concer nabou t the releas e o f hazardous/toxi c substances , the relativ e slownes s o f NESHA P promulgationa t th e federa l level , an dincreasedencouragemen t a t th e federa l level , ar e the primar y impetuse s fo r a policy documen t delineating the Department' s policy wit hrespec t t o the contro l o f routin e release s o f HAP's . APPROAC H Th e approac husedb y the Departmen t t o evaluat e permi t application s fo r source s releasin g HAP' s int o th

e ambient ai r i s based upo n classificationo f th e HA P int o on

e of th

e thre e categorie s (discussed below) , wher e eac hcategor y represent s the presen t certaint y

o f a substanc e being a huma ncarcinogen . Substance s ar e classifie d a s know nhumancarcinogens , suspectedo r reasonabl y anticipate dhumancarcinogens , an da s noncarcinogen s o r substance s lacking sufficien t dat a t o determin e carcinogenicity . I t i s the Department' s positio ntha t the classificationo f a substanc e a s a know no r suspected huma ncarcinoge nwil l b e basedo ndetermination s mad e b y either : (1 ) the Internationa l Agency fo r Researc hon Cance r (IARC) ; (2 ) the Nationa l Toxicolog y Progra

m (NTP) ; or (3 ) th e America nConferenc e o f Governmenta l Industria l Hygienist s (ACGIH) . Thes e agencie s ar e recognizedexpert s i nth e discipline s o f toxicolog

y an d carcinogenesis . Othe r substance s no t classified a s a know

no r suspectedhumancarcinogenb y one o f thes e agencie s wil l b e regulate d b y using adjustment s t o the Threshol d Limi t Value-Tim

e WeightedAverag e (TLV-TWA) , th e Threshol dLimi t Value Shor t Ter

m Exposur e Limi t (TLV-STEL) , or th e Threshol dLimi t Value Ceiling (TLV-C) , a s publishe db y th e ACGI H (1990) . Additiona l pollutant s no t listed i nth e ACGI H handbook whic hpos e a significan t healt hrisk , eithe r directl y or indirectly , wil l be evaluate do

na case-by-cas e basis . 

# QP.9 9



### th e lis t o f Group 3 substances . Thes e substance s hav e beenremoved basedo nthe Department' s determinationtha t th e ambient standard for PM

1 0 

### adequatel y

addresse s emission s o f thes e substances . The ACGI H (1990 ) define s th e TLV-TW

A a s th e time-weightedaverag e concentrationfo r a norma l 8-hou r workday

an da 40-hour wor k week , t o whic hnearl y

al l worker s ma

y be repeatedl y

exposed , day

afte r day , withou t advers e effect . The TLV-STE L i s th e concentrationt o whichworker s canb e expose

dt o continuousl y

for a shor t perio do f tim e withou t sufferin g from : (1 ) irritation ; (2 ) chroni c o r irreversibl e tissue damage ; or (3 ) narcosi s o f sufficien t degre e t o increas e the likelihoodo f accidenta l injury , impai r self-rescu e o r materiall y

reduc e wor k efficiency , an dprovidedtha t the dail y TLV TW A i s no t exceeded . Th e TLV- C i s the concentratio ntha t shoul d no t be exceede ddurin g an y par t o f th

e workin

g exposure . Eight hour an d1-hou

r Maximu

m Acceptabl e Ambien t Level s (MAAL ) fo r the pollutant s specified i nAppendi x3 ar e establishedfro m the TLV-TW

A an dTLV-STEL/TLV-C , respectivel y o f th e ACGIH . I t mus t be stresse d tha t the MAA

L for a substanc e i s no t anambient standard . Rather , th e MAA L wil l be usedb

y th e Departmen t a s a mechanism t o furthe r evaluat e the needfor contro l o f pollutan t emission s fro m source s whos e modele d concentration s exceedeithe r th e 8-hour o r 1-hour MAAL . Also , onl y

certai nsubstance s i nAppendi x3 hav e a 1-hour MAAL . Thes e substance s hav e bee nrecognizedb y the ACGI H a s havin g acut e effect s a s wel l a s chroni c effect s an d hav e a nappropriat e TLV-STE L o r TLV-C . Therefore , the Departmen t believe s an additiona l shorte r averagin g periodi s warrante dfo r thes e substances . Computation , o f bot hth e 8-hou r an d1-hou

r MAAL' s ar e base do nthe applicationo f certai ncorrectio nfactor s t o th

e TLV-TW

A an dTLV STEL/TLV-C , respectively . Eight-hour MAAL' s ar e calculate db y firs t extrapolating th e dos e incurred durin g a 40-hour wor k wee k t o an"equivalent " continuou s weekl y dos e b y dividin

g the TLV-TW

A b y 4. 2 (168/4 0 hours) . The TLV-TW A i s thenadjustedb y dividin g b

y a factor o f 1.7 5 representin g th e averag e lun

g ventilationvolum e o f 1 0 cubi c meters/2 4 hour s for a 6-year ol dchil dweighin g 2 0 k g comparedt o the averag e ventilationvolum e o f 2 0 cubi c meters/2 4 hour s fo r anadul t weighin g 7 0 k g (Commonwealtho f Massachusett s 1985) . Thi s i s don e t o protec t children , who m fo r variou s reason s suc ha s differing ventilation , absorption , an dexcretionrates , an d immatur e immune systems , ma y be mor e susceptibl e t o the effect s o f thes e pollutants . Finally , th e TLV-TW

A i s divide db

y a safet y factor o f 1 0 t o protec t additiona l portion s o f the expose d populationan

dprovid e additiona l safety . Therefore , the preliminar

y 8-hou r MAA L i s givenb

y equation1 . (1 ) Preliminary

MAAL

e 

### . heu r 

### » TLV-TW

A / (4. 2 X1 0 x1.75 ) However , t o simplif y calculatio

no f the MAA

L an dconsiderin g tha t divisor s fro

m 1 0 t o 30 0 are presentl y use db

y a numbe r o f state s depending o

nthe toxicit y

o f the substanc e being emitted , th e safety facto r wa s adjustedt o 13.6 , resulting i na diviso r o f 100 . 

# 0 

# it f

### _e x

condition s modele dwit hPTDI S wer e th e sam e condition s use

di nth e curren t EP

A versiono f the PTPL Uscreenin

g modal . A

nassumed mixing heigh t o f 500 0 meter s wa s use dinth

e mode l t o simulat e unlimited vertica l mixing . Plum e ris e wa s no t simulate di nth

e screenin

g procedure ; therefore , ambient temperatur e datu m wa s no t required(i.e. , th e PTDI S optio

nt o specif y

releas e height wa s used) . Othe r simplifyin

g assumption s made i nproducin g Tabl e 1 wer e tha t terrai nor building-induce d plum e downwas heffect s wer e no t a factor . Fo r the greate r releas e heights , th e presenc e o f eithe r o f thes e factor s hav e a potentia l t o increas e ground-leve l concentrations . For th e lowe r releas e heights , downwas heffect s may instea ddecreas e ground-leve l concentrations . Fo r mos t type s o f sources , th e potentia l fo r increasedconcentration s du e t o thes e effect s i s expectedt o be mor e tha noffse t b

y the fac t tha t plum e ris e wa s no t considere di nthi s analysis . I nfact , a revie w o f man y source s modele dpreviousl y b y th e Departmen t indicate dtha t the concentration s liste di nTabl e 1 woul dbe conservative fo r eac h o f th e source s modeled , whic hincludedsevera l wit helevate d terrai nor plum

e downwas hsituations . Base do

nthe Department' s previou s modeling experience , i t i s expecte dtha t Tabl e 1 wil l produc e appropriat e concentratio n estimate s for al l type s o f source s excep t for thos e whic hmee t al l o f the followin

g criteria : 1 ) n o plum e rise , 2 ) stac k height greate r tha n1 0 meters , an

d 3 ) possibilit y

o f building-inducedplum e downwas ho r terrai n effects . Fo r an y source s whic hmee t the abov e criteria , a source-specifi c dispersionmodeling analysi s shoul dbe conducted . Finally , th

e Departmen t usedanassumedemissio nrat e o f 1. 0 g/se c t o produc e the estimatedconcentration s i nTabl e 1 . Therefore , t o estimat e the maximu m 1-hour , ground-leve l concentratio nfro m a source , the pollutan t emissionrat e i ng/se c mus t be multiplie d b y the appropriat e valu e i nTabl e 1 . Calculation s T o obtai nanestimat e o f th e maximu

m 1-hou

r off-propert y concentrationusing Tabl e 1 , for comparisont o the 8-hou r an d 1 - hour MAAL , perfor

m the following procedure : 1 ) determin e the releas e (stack ) heigh t o f the pollutan t fro m th e sourc e i nmeter s (m) . Ignor e an y plum e rise . 2 ) selec t th

e ro w i nTabl e 1 havin

g a releas e heigh t neares t to , bu t les s thano r equa l to , the actua l releas e height .



# nP. 2



### carcinogen . Also , i nn o cas e shal l a sourc e whic hi s emittin g a Grou p1 substanc e tha t i s als o regulated unde r NSP S an dNESHA P be allowedt o obtai na varianc e to LAE Rwhichi s les s stringen t than th e requirement s o f NSP S or NESHAP . Facilitie s emittin g mor e tha

none HA

P wil l b

e givenspecia l considerationb

y th e Department , becaus e o f th e possibilit y

o f synergis

m betweenpollutants . Fo r example , wher e tw o o r mor e carcinogeni c ris k assessment s ar e required , risk s fro m the individua l pollutant s wil l be assumedt o b e additiv

e an dthe combinedmaximu

m individua l lifetim e ris k fro

m al l carcinogeni c HAP' 8 mus t be les s tha n1 xIO' 6 

### . Similarly , th e effect s o f multipl e Grou

p 3 substance s emitte dfro m a sourc e ar e assumedt o b e additive , i f th

e availabl e toxicit y dat a ar e insufficien t t o determin e otherwise . The releas e o f multipl e Grou p3 HAP' s int o the ambien t ai r wil l be evaluatedaccordin g t o equation4 ; MC . MC . MC , M C (4 ) + + -i - + .. . + - — < - 1 MAAL , MAAL , MAAL , MAA L wher e MC X 

### , MC. , MC n

### ar e th e modeledambient concentration s fo r HAP' s 1 , 2 , ... , nan

d MAAL 1 # 

### MAAL. , MAAL . ar e the Maximu m Acceptabl e Ambien t Level s for HAP' s 1 , 2 , ... , n . A su m o f les s than1 wil l be considere dacceptable , wherea s a su m greate r thanon e wil l trigge r furthe r revie w b y th e Department . Whe nclassifying substance s a s Grou p1 , Grou

p2 , o r Group3 , the Departmen t wil l us e the mos t restrictiv e classificationwher e list s fro m the ACGIH , IARC , o r NT P do no t agree . Fo r example , benzen e i s classifie d a s a know nhuma ncarcinoge nb

y NT P an

da Group 1 substanc e b

y the Department , althoug hclassifieda s a suspecte d humancarcinoge nb y ACGIH . A s ne

w informatio

nbecome s availabl e throug hthe NTP , ACGIH , or IARC , the compositio no f Group1 , Group 2 , o r Grou

p 3 ma y change . Thes e list s wil l be periodicall y reviewedb

y the Department . The Departmen t wil l als o conside r alternative classification s for a specifi c Grou p1 , Grou p2 , o r Grou p3 substanc e an

danalternativ

e MAA L fo r a Group3 substance , providedthe affected sourc e or person(s ) candemonstrat e t o th e satisfactiono f th e Departmen t b

y presentin

g scientifi c dat a tha t reclassificationor analternativ e MAA L i s mor e scientificall y valid . Ris k assessment s shoul db e conductedaccordin g t o the document , "Guideline s fo r Carcinogeni c Ris k Assessment " publishe di nthe Federa l Registe r (Septembe r 24 , 1986 : 33992-34003) . Th e carcinogeni c uni t ris k factor s providedi nAppendi xD o f thi s documen t ar e t o b e used whencalculating the maximu m individua l lifetim e ris k o f developing cancer . .Th e uni t ris k factor s give ni n Appendi xD ar e fro m 4 0 CFRPar t 260 ; Februar y 21 , 1991 . Also , "Guideline s for Exposur e Assessment " (Federa l Register , Septembe r 24 , 1986 : 34042-34054 ) shoul dbe closel y followedwhe nperformin g the exposur e assessment . The Departmen t acknowledge s th e proble m o f exposur e fro

m multipl e environmenta l pathways , bu t wil l presentl y

conside r onl y

exposur e throug

hth e air . An

y question s 

# 10 0P. 3



### DOCUMENTATIO

N AmericanConferenc e o f Governmenta l Industria l Hygienists . 1990 . Threshol d Limi t Value s an dBiologica l Exposur e Indice s fo r 1990 - 1991 . ISB

N 0-936712-86-4 . Code o f Federa l Regulations . Septembe r 24 , 1986 . Guideline s for Carcinogeni c Ris k Assessment , p p33992-34003 . Code o f Federa l Regulations . Septembe r 24 , 1986 . Guideline s fo r Exposur e Assessment , p p34042-34054 . Commonwealt ho f Massachusetts . 1985 . Th e Chemica l Healt hEffect s Assessmen t Methodolog y an dThe Metho

dt o Deriv

e Acceptabl e Ambien t Levels . Departmen t o f Environmenta l Quality Engineering . Internationa l Agency for Researc ho

nCancer . 1982 . Chemicals , Industria l Processe s an dIndustrie s Associatedwit hCance r i n Humans . IAR

C Monographs . Supplemen t 4 . Nationa l Toxicolog y Program . 1982 . ThirdAnnua l Repor t on Carcinogens . U.S . Departmen t o f Healt han dHuma nServices . Nationa l Toxicolog y Program . 1985 . Fourt hAnnua l Repor t on Carcinogens . U.S . Departmen t o f Healthan dHuma nServices . U.S . EPA . 1979 . Guidanc e for Lowes t Achievabl e Emission s Rate s fro m 1 8 Majo r Stationar y Source s o f Particulates , Nitroge nDioxide , Sulfur Dioxide , or Volatil e Organi c Compounds . EPA-450/3-79-024 . U.S . EPA . 1985 . The Ai r Toxic s Proble m inth e UnitedStates xA n Analysi s o f Cance r Risk s fo r SelectedPollutants . Offic e o f Ai r an dRadiation , an

d Offic e o f Policy , Plannin g an dEvaluation . 10 0 pp . Stat e o f Nort hDakota . Decembe r 17 , 1990 . Guidelin e for Ai r Qualit y Modeling Analyses . Divisiono f Environmenta l Engineering . Code o f Federa l Regulations . Februar y 21 , 1991 . Appendi xV , Ris k Specifi c Doses , pp . 7232-7233 .



### 1 1 

# to i•EA- I



### Appendi xA . Grou

p 1 hazardou s ai r pollutant s know nt o caus e cance r i nhuman s whic hrequir e LAER . 4-Aminodipheny l Arseni c an

dinorgani c compound s Asbesto s Auramin e Benzene Benzidine Bis(chloromethyl)ethe r (BCME ) an dtechnica l grade chloromethy l methy l ethe r (CMME ) Chromiu m (VI) , wate r insolubl e compounds , an dzin c chromate s Cok e ove nemission s 2-Naphthylamine Nickel , inorgani c nicke l compound s (includin g nicke l carbonyl ) 4-Nitrodipheny 1 Thoriu m dioxid e Viny l chlorid e Manufactur e o f Pharmaceuticals : Azathioprine , N,N-bis(2-chloroethyl)-2-naphthylamin e (chlornaphazine) , 1,4-Butanedio l dimethylsulfonat e (myleran) , Chlorambucil , Conjugatedestrogens , Cyclophosphamide , Diethylstilbestro l (DES) , Melphalan , Mustar dGas , N,N-Bi s (2 - chloroethyl)-2naphthylamine , Phenacetin , Treosulphan , certai n chemotherapeutic s



### 1 2 

# [09 s•££- *

Appendi xB . Grou p2 hazardou s ai r pollutant s suspecte do f causin g cance r i nhuman s whic hrequir e BACT . 2-Acetylaminofluoren e Acrylamid e Acrylonitril e Aflatoxin a 2-Aminoanthraquinon e 1-Amino-2-methylanthraquinon e o-Anisidin e an do-anisidin e hydrochlorid e Antimon y

trioxid e Benzotrichlorid e Beryllium

an dberylliu

m compound s 1,3-Butadien e Cadmiu m an dcadmium

compound s Carbo ntetrachlorid e Chlorofor m 4-Chloro-o-phenylenediamin e Chrysen e p-Cresidin e Cupferro n Cycasi n> 2,4-Diaminoanisol e sulfat e 2,4-Diaminotoiuen e Di(2-ethylhexyl)phthalat e l,2-Dibromo-3-chloropropan e (DBCP ) (pesticide ) 1,2-Dibromoethan e (EDB ) 3,3'-Dichlorobenzidin e 1,2-Dichloroethan e (EDC ) Diepoxybutan e 1,1-Dimethylhydrazin e Diethy l sulfat e Dimethy l sulfat e 3,3-Dimethyoxybenzidin e (o-dianisidine ) 4-Dimethylamihoazobenzen e 3,3'-Dimethylbenzidin e Dimethylcarbamoy l chlorid e 1,4-Dioxan e Direc t blac k 3 8 Direc t blu e 6 , Epichlorohydri n Ethy l acrylat e Ethylen e dibromid e Ethylen e oxid e Ethylen e thioure a Formaldehyd e Hexachlorobenzen e (HCB ) Hexachlorobutadien e Hexamethylphosphoramid e Hydrazin e an dhydrazin e sulfat e Hydrazobenzen e Lea dacetat e an dlea dphosphat e Lea d chromat e Lindan e an dothe r hexachlorocyclohexan e isomer s 4,4'-Methylen e bis(2-chloroaniline ) (MOCA ) 1 3 

# lo 3P. 6



### Manufactur e o f Pharmaceuticals : Adriamycin , l-(2-Chloroethyl)-3-cyclohexvl-l-nitro« rt 

### „,— . (CCNU) , Dacarbazine , EthinylesJadiol/lro nSxtra ncSJl S Mestranol , Metronidazole , Norethisterone , Estrogen s an d progestin s (not conjugated) , Estrone , Phenazopyridine hydrochloride , Phenytoi nan dsodiu m sal t o f phenvtoi n Propylthiouraci l Reserpine , Seleniu m sulfidS , Streptozotocin , Tris(1-azindmyl)phosphin e sulfide , uracil , Nitrogenmustard



### 1 5P. 7



### Appendi xC . Group3 hazardou s ai r pollutant s whic har e noncarcinogeni c o r hav e insufficien t dat a fo r classificationwit h respec t t o carcinogenicit y an dthei r MAAL(s ) ("e" denote s MAA L basedo nTLV-Ceiling) .

Acetaldehyd e Aceti c aci d Aceti c anhydrid e Aceton e Acetonitril e Acetylen e tetrabromid e Acetylsalicyli c aci d(aspirin ) Acrolei n Acryli c aci d Aldri n Ally l alcoho l Ally l chlorid e Ally l glycidy l ethe r Ally l propy l disulfid e Aluminu m Meta l dus t Pyr o powder s Welding fume s Solubl e salt s Alkyl s 2-Aminopyridine Amitrol e Ammoni a Ammoniu m chlorid e fume s Ammoniu m perfluorooctanoat e Ammoniu m sulfamat e n-Amyl acetat e sec-Amy l acetat e Anilin e an

d homologue s A nisidine (o- , p - isomers ) Antimon y & compounds , a s S b Antimon y trioxide , a s S b ANT U Arsenic , solubl e compound s a s A s Arsin e Asphal t (petroleum ) fume s Atrazin e Azinphos-methy l Barium , solubl e compounds , a s B a Bariu m sulfat e Benomy l Benzoy l peroxid e Benzy l chlorid e Bipheny l Bismut htellurid e Se-doped MAA L 8-hou r 1. 8 .2 5 17. 8 .6 7 .1 4 .0 5 .002 3 .05 9 .002 5 .04 8 .0 3 .2 3 .1 2

. 1 .0 5 .0 5 .0 2 .0 2 .0 2 .00 2 .1 7

. 1 .00 1

. 1 5.3 2 6.6 5 .07 6 .00 5 .00 5 .00 5 .00 3 .00 2 .001 6 .0 5 .0 5 .00 2 .00 5

. 1

. 1 .0 5 .05 2 .01 3

. 1 .0 5 Ima/m 3



### ) 1-hou r 2. 7 .3 7 .2 1 23.8 0 1.0 1 .00 6 .09 5 .0 6 .4 7 .1 8

.2 4

. 2



### 1 6 

# 0 6P. 8



### Chlorine Chlorine dioxid e Chlorine trifluorid e (c ) Chloroacetaldehyd e (c ) Chloroacetone alpha-Chloroacetophenone Chloroacety l chlorid e Chlorobenzene o-Chlorobenzylidene malononitril e (c ) Chlorobromomethane Chlorodifluoromethane Chlorodipheny l (42 % chlorine ) Chlorodipheny l (54 % chlorine ) 1-Chloro-1-nitropropane Chloropentafluoroethan e Chloropicri n beta-Chloroprene o-Clorostyrene o-Chlorotoluene Chlorpyrifo s Chromiu m Meta l Chromiu m (II ) compound s a s Cr Chromiu m (III ) compound s a s C r Chromiu m (VI ) wate r solubl e compound s a s C r Chromy l chorid e Clopido l Cobal t metal , dus t an d fume , a s C o Cobal t carbonyl , a s C o Cobal t hydrocarbonyl , a s C o Coppe r Fum e Dust s & mists , a s C u Cottondust , ra

w Cresol , al l isomer s Crotonaldehyde Crufomat e Cumen e Cyanamide Cyanides , (inorganics ) a s C N Cyanoge n Cyanoge nchlorid e (C ) Cyclohexan e Cyclohexano l Cyclohexanon e Cyclohexen e Cyclohexylamin e Cyclonit e Cyclopentadien e Cyclopentan e : Cyhexati n 2,4- D DD T Decaborane Demeton Diacetone alcoho l .01 5 .002 8

.003 2 .002 3 3.4 5 10. 6 35. 4 

### .0 1 .00 5 

### .1 0 63. 2 .006 7 

### .3 6 2.8 3 2.5 9 .00 2 .00 5 .00 5 .00 5 .000 5 .001 6



### . 1 .000 5 .00 1 .00 1 .00 2 

### .0 1 .00 2 

### .2 2 .05 7 

### .0 5 2.4 6 

### .0 2 .0 5 .2 1 10. 3 2.0 6 

### 1. 0 10.1 0 

### .4 1 .01 5 2.0 3 17. 2 

### .0 5 .1 0 .0 1 .002 5 .001 1 2.3 8 .02 9

008 3 003 8 03 2 03 8
003 9

4.2 5

.007 5



### .007 5
1 8 

# lO kP. 9



### Diviny l benzen e Emer y Endosulfan Endri n Enflurane Epichlorohydri n EPN Ethanolamin e Ethion 2-Ethoxyethano l (EGEE ) 2-Ethoxyethy l acetat e (EGEEA ) Ethy l acetat e Ethy l alcoho l Ethylamin e Ethy l amy l keton e Ethy l benzen e Ethy l bromid e Ethy l buty l keton e Ethy l chlorid e Ethylen e chlorohydri n(c ) Ethylenediamin e Ethylen e dichlorid e Ethylen e glyco l vapo r (c ) Ethylen e glyco l dinitrat e Ethylenimin e Ethy l ethe r Ethy l format e Ethyliden e norbornen e (c ) Ethy l mercaptan N-Ethylmorpholin e Ethy l silicat e Fenamipho s Fensulfothion Fenthion Ferba m Ferrovanadiu

m dus t Fibrou s glas s dus t Fluorides , a s F Fluorin e Fonofo s Formamid e Formi c Aci d Furfura l Furfury l alcoho l Gasolin e Germaniu

m tetrahydrid e Glutaraldehyd e (c ) Glyceri nmis t Glycido l Graphite , natura l (respirabl e dust ) Graphite , syntheti c Hafniu m Halothan e Heptachlo r Heptane , n 

### .5 3

. 1 .00 1 .00 1 5.6 6 .07 6 .00 5 .07 5 .00 4 

### .1 8 .2 7 14. 4 18. 8 

### .1 8 1.3 1 4.3 4 8.9 1 2.3 4 26. 4 

### .2 5

. 4 .003 1 .008 8 12. 1 3.0 3 .01 3 

### .2 4 .8 5 .00 1 .00 1 .00 2



### . 1 .0 1

. 1 .02 5 .01 6 .00 1 

### .1 8 .09 4 .07 9



### . 4 8. 9 .006 3



### . 1 .7 6 .02 5



### . 1 .00 5 4.0 4 .00 5 16. 4 

### .15

5.4 3 11. 1 .03 3 1.2 7 15. 2 

### .2 5

.0 3 .03 1



### . 6 14. 8 .00 8

20. 5 2 0 

# 10 ^P.1 0



### Mercur y Alky l compound s Al l forms excep t alky l Vapo r Ary l an d inorgani c compound s Mesity l oxid e Methacryli c aci d Methomy l Methoxyclo r 2-Methoxyethano l 2-Methoxyethy l acetat e (EGMEA ) 4-Methoxypheno l Methy l acetat e Methy l acetylen e Methy l acetylene-propadiene mixtur e (MAPP ) Methy l aerylat e Methylacrylonitril e Methyla l Methy l alcoho l Methylamin e Methy l n-amy l ketone N-Methy l anilin e Methy l bromid e Methy l n-buty l ketone Methy l chlorid e Methy l chlorofor

m Methy l 2-cyanoacrylat e Methylcyclohexan e Methylcyclohexano l o-Methylcyclohexanone Methylcyclopentadieny l manganes e tricarbonyl , a s M n Methy l demeton Methylen e bispheny l isocyanat e (MDI ) Methylen e bi s (4-cyclohexylisocyanate ) Methy l ethy l keton e (MEK ) Methy l ethy l keton e peroxid e (c ) Methy l format e Methy l isoamy l ketone Methy l isobuty l carbino l Methy l isobuty l ketone Methy l isocyanat e Methy l isopropy l ketone Methy l mercapta n Methy l methacrylat e Methy l parathio n Methy l propy l ketone Methy l silicat e alpha-Methy l styrene Metribuzi n Mevinpho s Mica , respirabl e dus t Minera l woo l fibe r .000 1 .000 5 .00 1



### . 6

. 7 .02 5



### . 1 .1 6 .2 4 .0 5 6.0 6 16. 4 16. 4 

### .3 5 .02 7 31. 1 2.6 2 

### .1 3 2.3 3 .02 2 

### .1 9

. 2 1.0 3 19. 1 .09 1 16. 1 2.3 4 2.2 9 .00 2 .00 5 .0005 1 .0005 4 

### 5. 9 2.4 6 2.3 4 1.0 4 2.0 5 .0004 7 7.0 5 .009 8 

### 4. 1 .00 2 7.0 5 

### .0 6 2.4 2 

### .0 5 .0009 2 

### .0 3

. 1 .000 3



### 1. 0

7.5 7 20. 5

3.2 8

2.0 7 24. 6 

### .1 8 3.4 4

8.8 5 .01 5 3.6 8 1.6 7 3.0 7

8.8 1 4.8 3 .002 7

2 2 

# 10$P.1 1



### Phosphori c aci d Phosphoru s (yellow ) Phosphoru s oxychlorid e Phosphoru s pentachlorid e Phosphoru s pentasulfid e Phosphoru s trichlorid e Phthali c anhydrid e m-Phthalodinitril e Piclora m Picri c aci d Pindone Plperazine dihydrochlorid e Platinu m Meta l Solubl e salts , a s P t Potassiu

m hydroxid e (c ) Propargy l alcoho l Propioni c aci d Propoxur n-Propy l acetat e n-Propy l alcoho l Propylene dichlorid e Propy l glycol : dinitrat e Propylene glyco l monomethy l ethe r Propylene oxid e n-Propy l nitrat e Pyrethru

m Pyridin e Quinon e Resorcino l Rhodiu m Meta l Insolubl e compounds , a s R h Solubl e compounds , a s R h Ronne l Rosi ncor e solde r pyrolysi s products , a s formaldehyd e Rotenone (commercial ) Roug e Rubbe r solven t (Naphtha ) Seleniu m an d compounds , a s S e Seleniu m hexafluoride , a s S e Seson e Silica-amorphou s Diatomaceou s eart h(uncalcined ) Precipitate dsilic a Silic a ge l Silica-crystallin e Cristobalite , respirabl e dus t Quartz , respirabl e dus t Silic a (fused) , respirabl e dus t Tridymlte , respirabl e dus t Tripoli , o f containe drespirabl e dus t Silicon Siliconcarbid e 

### .0 1 .00 1 .006 3 .008 5 

### .0 1 .01 1 .06 1 

### .0 5

. 1 .00 1 .00 1 

### .0 5 .0 1 .0000 2 .02 3



### . 3 .00 5 8.3 5 4.9 2 3.4 7 .003 4 3.6 9 

### .4 8 1.0 7 

### .0 5 .1 6 .004 4 

### .4 5 .0 1 .0 1 .000 1



### . 1 .00 1 

### .0 5

. 1 15. 9 .00 2 .001 6



### . 1

. 1

. 1

. 1 .000 5 .00 1 .00 1 .000 5 .00 1



### . 1

. 1 .0 3

.0 3 .0 2

.0 2

10. 4 6.1 4 5.0 8 5.5 3 1.7 2



### . 9

2 4 

# \D C 

# \P.1 2



### Ti n Meta l Oxid e & inorgani c compounds , excep t SnH 4 

### , a s S n Organi c compounds , a s S n Titaniu m dioxid e Toluen e Toluene-2,4-diisocyanat e (TDI ) m-Toluidin e ] 

### Tributy l phosphat e Trichloroaceti c aci d 1,2,4-Trichlorobenzene (c ) 1,1,2-Trichloroethane Trichloroethylen e Trichloroflouromethan e (c ) Trlchloronaphthalen e 1,2,3-Trichloropropane 1,1,2-Trichloro-1,2, 2 trifluoroethane Triethylamin e Tr i fluorobromomethane Trimelllti c anhydride Trimethylamin e Trimethy l benzen e Trimethy l phosphit e 2,4,6-Trinitrotoluen e (TNT ) Triorthocresy l phosphat e Tripheny l amine Tripheny l phosphat e Tungsten , a s W Insolubl e compound s Solubl e compound s Turpentin e Uraniu m (natural ) Solubl e & Insoluble , a s U n-Valeraldehyd e Vanadium , a s V.0 S 

### , respirabl e dus t an dfum e Vegetabl e oil , mist s Viny l acetat e Vinyliden e chlorid e Viny l toluen e V M & P Naphtha Warfari n Weldin g fume s (not otherwis e classified ) Wooddus t (certai nhar dwood s a s beec h& oak ) Sof t Woo d Xylen e m-Xylen e a,a'-diamine (c ) Yttriu m Zinc chlorid e fum

e Zin c oxid e fum e dus t Zirconiu

m compounds , a s Z r 

### .0 2 .0 2 .00 1

. 1 3.7 7 .0003 6 .08 8 .02 2 .06 7 .5 5 2.6 9 .0 5

. 6 76. 7 .4 1 60. 9 .0003 9 .2 4 1.2 3

. 1 .00 5 .00 1 .0 5 .0 3 .0 5 .0 1 5.5 6 .00 2 1.7 6 .000 5

. 1 .3 5

. 2 2.4 2 13. 7 .00 1 .0 5 .0 1 .0 5 4.3 4 .0 1 .0 1 .0 5

. 1 .0 5 5.6 5

.001 4

.3 7 10. 7 56. 2 95. 9 .6 2 .3 6

. 1 .0 3 .00 6

.7 0 .7 9 4.8 3

. 1 6.5 1 .00 1 .0 2

. 1

. 1 

# 1\ 0 2 6P.1 3



### Appendi xD . Uni t ris k factor s for carcinogeni c constituents . Constituen t Acrylamid e Acrylonitril e Aldri n Aniline Arseni c Benz(a)anthracen e Benzene Benzidine Benzo(a)pyrene Berylliu

m Bis(2-chloroethyl)ethe r Bis(chloromethyl)ethe r Bis(2-ethylexyl)phthalat e 1,3-butadiene Cadmiu m Carbo nTetrachlorid e Chlordane Chlorofor

m Chloromethan e Chromiu m V I 

### DD T Dibenz(a,h)anthracen e 1,2-dibromo-3-chloropropane 1,2-dibromoethane 1,1-dichloroethane 1,2-dichloroethane 1,1-dichloroethylene 1,3-dichloropropene Dieldri n Diethylstilbestro l Dimethylnitrosamin e 2,4-dinitrotoluene 1,2-diphenylhydrazine 1,4-dioxan

e Epichlorohydri n Ethylene Oxid e Ethylene Dibromid e Formaldehyde Heptachlo r Heptachlo r Epoxid e Hexachlorobenzen e Hexachlorobutadien e Alpha-hexachloro-cyclohexan e Beta-hexachloro-cyclohexan e Gamma-hexachloro-cyclohexan e Hexachlorocyclohexane , Technica l Hexachlorodibenzo-p-dioxi n(1, 2 mixture ) Hexachloroethane Hydrazine Hydrazine Sulfat e Uni t Ris k Facto r LmVi/c n 1. 3 E-0 3 6. 8 E-0 5 4. 9 E-0 3 7. 4 E-0 6 4. 3 E-0 3 8. 9 E-0 4 8. 3 E-0 6 6. 7 E-0 2 3. 3 E-0 3 2. 4 E-0 3 3. 3 E-0 4 6. 2 E-0 2 2. 4 E-0 7 2. 8 E-0 4 1. 8 E-0 3 1. 5 E-0 5 3. 7 E-0 4 2. 3 E-0 5 3. 6 E-0 6 1. 2 E-0 2 9. 7 E-0 5 1. 4 E-0 2 6. 3 E-0 3 2. 2 E-0 4 2. 6 E-0 5 2. 6 E-0 5 5. 0 E-0 5 3. 5 E-0 1 4. 6 E-0 3 1. 4 E-0 1 1. 4 E-0 2 8. 8 E-0 5 2. 2 E-0 4 1. 4 E-0 6 1. 2 E-0 6 1. 0 E-0 4 2. 2 E-0 4 1. 3 E-0 5 1. 3 E-0 3 2. 6 E-0 3 4. 9 E-0 4 2. 0 E-0 5 1. 8 E-0 3 5. 3 E-0 4 3. 8 E-0 4 5. 1 B-0 4 1. 3 E+0 0 4. 0 E-0 6 2. 9 E-0 3 2. 9 B-0 3 

### 2 7 

# W

\TABL E 1 .

Maximu m 1-hou r Ground-Leve l Centerlin e Concentration s (ag/m^ )

Downwin d Distanc e (meters ) p Releas e Ht . (• ) 1 5 1 0 2 0 3 0 5 0 10 0 20 0 - 1 0

30 0 .8 2
•'neg . neg . neg . neg . neg . neg . 2 0 21 0 8. 6 •1 5 neg . neg . neg . neg . neg . 3 0 12 0 1 0 1. 3 neg . neg . neg . neg . neg . H

O 7 7 9. 2 2.2 .02 8 neg . neg . neg . neg . - 5 0 5 1 8. 4 2. 1 .1 4 .00 1 3 neg . neg . neg . 7 5

21 1 1 2. 5 .4 9 .05 4 neg . neg . neg . 10 0 16 9. 4 2. 0 .6 1 .1 7 .002 8 neg . neg . 15 0 8. 0 6. 1 2. 6 .6 4 .2 9 .05 0 neg . neg . 20 0 4. 9 4. 0 2. 4 .5 3 .2 9 .1 0 .001 3 neg . 30 0 2. 5 2. 1 1. 7 .5 9 .2 5 .1 1 .02 0 neg . 40 0 1. 5 1. 3 1. 1 .6 0 .2 1 .1 1 .03 6 .001 9 50 0

1. 0 .9 3 .8 3 .5 3 .2 5 .09 3 .03 4 .008 7 75 0

.5 3 .4 8 .4 4 .3 5 .2 4 .06 9 .03 1 .01 1 100 0 .3 4 .3 2 .2 8 .2 4 .1 9 .08 7 .02 5 .007 1 200 0

.1 2 .1 1 .1 0 .09 2 .08 3 .06 0 .01 4 .006 6 500 0 .03 2 .03 2 .03 1 .02 7 .02 3 .02 1 .008 1 .001 9



# y 'Emissio n rat e o f1. 0 grams/se c wa s used . Terrain , Halte d vertica l mixing , an d structurally Induce d downwas h effect s no t accounte d for . 2 Plum e ris e I s no t take n Int o accoun t (releas e ht . •plum e ht. ) ^Negligibl e I s define d a s les s tha n 0.00 1 allllgrams/m 3