Dept. of Environmental Protection 

Bureau of Waste Management 

400 Waterfront Drive 

Pittsburgh, PA 15222 

To Whom It May Concern: 

-o 

:X 

-

.. 

0 

N 

Enclosed please find Great Oak Energy, Inc.'s Form 26R, Chemical 

Analysis of Residual Waste Generated, for our Export Fuel #1 Marcellus 

well. 

If you need any additional information or have any questions, 

please feel free to contact Ed Klammer at our office, as indicated on the 

report. 

Sincerely, 

Donna T. Hogue 

Enclosure 

637 ALLEGHENY AVENUE 

P.O. BOX445 

OAKMONT, PA 15139-0445 

PHONE: 412-828-2900 

FAX: 412-828-8942 

(/1~ ---1"""0 

7.l 

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(;) 

,-.. • .7 

·-?" 
each attached sheet as Form 26R, reference the Item number and Identify the date 

prepared. The date on attached sheets needs to match the date noted below. 

General Reference 287.54 

Date Prepared/Revised 02/24/11 

c. Physical Appearance 

- 1 -

EPA ID# 
a. 

b. 

c. 

Solid waste permit nu 

PA0091472 

Facility Name 

Address Line 1 

Address Line 1 

Address City State ZIP 

Municipality 

Title 

Phone 

Name 

Conemaugh Township Indiana 

Email Address 

d. Volume of waste shipped to processing or disposal year. D cu yd D gal D lb D ton (check one) 

a. Solid waste permit number(s) for processing or disposal facility 

b. Facility Name 

Address Line 1 

Address Line 1 Address City State ZIP 

Municipality 

.C. 

Title 

Phone 

Name 

nty 

to processing or disposal facility In the previous year. D cu yd D gal D lb D ton (check one) 

D ton (check one) 

-2 -
Form Submitted: 0 

0 

Date Submitted: 

Form 26R 

Other (specify) 

0 I certify the information required in Section B-2, Chemical Analysis was supplied to the Department for the year 

_and has not changed. 

Form Submitted: 0 Form 26R 

0 Other (specify) 

Date Submitted: 

0 I certify the information required In Section B-3, Process Description and Schematic, was supplied to the Department for the year __ and has not changed. 

Form Submitted: 0 Form 26R 

Date Submitted: 

Name of Responsible Official 

Edward A. Klammer 

Signature 

0 Other (specify) 

Title Vice President 

Date 2/24/11 

-3 -
Item 2. Chemical Analysis Attachments 

a. Two waste streams have been generated by the Export Fuel #1 

and the waste was segregated prior to disposal. The first waste 

stream was used frac fluid. The analysis of the sample drawn by 

McCutcheon Enterprises on May 13, 2010, is included. 

The second waster stream is production brine. A detailed analysis 

of waste drawn on May 27, 2010, is included. 

b. Frac fluid samples were drawn by McCutcheon Enterprises. 

Great Oak Energy, Inc. does not have details of the sampling 

method. 

Brine samples were drawn from the tank battery at the well 

location by Great Oak Energy, Inc. personnel. The samples were 

collected in clean, apparently un-used containers provided by 

Environmental Service Labs (ESL) and according to instructions 

provided by ESL. The samples were delivered to ESL the same 

day as collected. 

c. Environmental Service Laboratories, Inc. (ESL) is accredited by 

the Pennsylvania Department of Environmental Protection. A 

letter indicating their accreditation is included. 

The Report of Analysis in Section B.2.a. indicates the test 

methods employed in the analysis. 
~ame; 

Report of Analysis 

-----·-- · ... . ··-----------·-. 

DEP Cortiticlll.ion Us 32-00382 

SampJeiD#: 

Sample Type; 

SaiQple Soarce: 

Sampler; 

Client Sample lD: 

10 15713 

Waste Water 

Grab 

CLIENT (Client) 

Export Fuel # 1 

Oeta QuB/mers: 0:: The reported value is from dilution. E ,. Estimated value. S ,. Surrogate out of <lOnttollimits. 

R = Sample received out of holding time. H "' Sample analyzed out of holding time. C = Sample received in incorrect container. 

8 = Analyte was detected in both sample and meti\Qd$ blank. x .. user defined data qualifier. 

Page 1 ct3 
Report of Analysis 

··--------·-·· ----· .. ···-----

~ame: 

DEP Certitication lis 32.00382 

____ .. . 

·-----.. . ·----

Sample I'D#: 10 15713 

Sample Type: Waste Water 

Sampkl Souree: Grab 

Sampler: 

CUent Sample lD: 

CLIENT (Client) 

Export Fuel #I 

... . .. 

alta Data 

louauner 

-·- -

I nla 

---- •••• ao••-

ell .... ____ n/a . ·- .. 

gl1 nla 

·--··--

lVI nla 

-·- -

gl1 nla 

.. 

-

I g/1 n/a 

_, -· gil I nla 

... . .. ~ nla 

I n/a 

.. .. .. --

g/1 n/a 

... 

__ 

1 nJa --··r .. .. _ 

~-.. r 1 

::---· ·-iva I g/1 

-

g/1 

__ 

nla 

,,, 

·-

--~---

.. -· 

Data QtiBiifl.ers: D = The reported value is from dUution. E "' Estimated value. S = Sun"Ogate out of control limits. 

R .. Sample received out of holding time. H '" Sample an~ly)!ed out of holding time. C = Sample received In Incorrect containet. 

B = Anatyte was detected In both sample and methods blank. X .. uaer defined data qualifier. 

Page 2 of3 
~lame: 

Great Oak Energy, Inc:. 

Atul: Mr. Ed Klanun~:tr 

Report of Analysis 

---

Sample II»: 

sample Typo: 

637 AlleJ}!eny Avenue I p0 Box 44S 

Oalanont, PA 1Sl39..0445 

Sample Source: 

Sampler: 

»ample Sblrt DJ~~te: S/2712010 Il :30 AM Client Sample ID: 

leccdpt Date: S/2712010 2:23 PM 

leport Date: 6121/20 10 

10 15713 

Waste Water 

Grab 

CLIENT (Client) 

Sxport Fuel #I 

-::~~~iii'::~~; 

Ail !fi: ___ _j ___ -~::;=rtj __ --:~~~~:~-~-~i~J 

0 .. ! • • ·,,.,~·. r,: 

DEP Curtifioadonll~ 32-00382 

·-··--· ,_... . ····----

Data Qualifiers: D =The reported value I& from dilution. E .. Estimated value. S .. Surrogata out of 1;0ntrollimits. 

R = S01mple received out of holding time. H .. S41mple analyzed out of holding time. C • Sample received In Jneorrect container. 

B • Analyte wa$ detected in both sample and methods blank. X = User defined data qualifier. 

Page 3 of3 
. r 

'lame; 

Great Oak Ener&Y, Jno. 

Attn: Mr. nc!Klammer 

Report of Analysis 

-----

SsmpleiD#: 

Sample Type: 

637 All~eny Avenue I PO Box 44:5 

Oalanont, PA 15139..()445 

Sample Soaree: 

Sampler: 

)ample Start Dato: S/27/2010 11:30 AM Client Sample ID: 

lUcoipt Date: . 5/27/2010 2:23PM 

!teportl)ato: · 6/2212010 

10 1S714 

Waste War 

Grab 

CUENT (Client) 

Export Fuel Nl Rads 

E 

... th· ·.vJ·en· e-OAnaly.cloyi_ie __ .. --··--r .. _A A~~laly~ A=is ~::" · .. ·Sam.~ ..• ::: lJnitS. -.. ~--- ... Metb~d·-~-·-·RPL · -~ ~ .. -~tP~i.k 06/o9 nfa <26.600 mglka ~~r .... 3oo_o·M--l--26.60o--t ·: ~~~~~~gical~-.--=== Je~blnalJ 06121 [~~~~~· ·: . ._ __ * --... .: ~ ~""'""-+~-~~ .. f RAD-C'f!?~~ _r·o.oo~~-1 

CumQI.cPtl= Bthyl\1IIe Glycol subcontracted to Metrohm·Peak. ISO# 10001397QM08 Radiologicats done by 

Benchmark Analytical. PADBP Lab ID: 39-00401 

·------ ~ NotDotcc~d 

--~·· ·" ........ . 

Hm!l, DEP Cettitica&ion I#~ 32..00382 ----· . , 

____________ , 

p ,. The reported value i$ from dilution. E e Estimated value. S .. Surrogate out of control limit$. 

R = Sample Atceived out of holding time. H = Sample analyled out of holding time. C "' Sample receivect ln inc:orrect container. 

8 "' Analyte wa& detected in both sample and methods blank. X "' User defined data qualif~er. Page 1 of 1 
COMPANY: Environmental Service Laboratories, Inc 

ADDRESS: ·1803 Philadelphia St 

1018714 

Indiana, PA 15701 

(724) 483-8378 

. (724) 465-4209 

RECEtyED FOR LAB BY: MAK 

TEST REPORT 

DATE: 0610212010 9:45 

PAGE: · 1 of1 

Pat: OAS06012010 

PWSII» 

Page 1 ofl 

.. , E; . to 11'114 

"eAW'LED BY: David A. Stae. 

Lab 10: 1001020S-(101A . GriD 

~ nn. 0812712010 11:30 

.... ~ ... !.!D!ll!l. IU 

Grou~ 

6060 t 1261. ~.00 

. OroH- 2452 :t 828.6 1788.00 

CombinedMIM1Y 8511 

~+Beta) 

Radium, Combined 346.4 

(RI228 + Ra228) 

.UDIII 

pCIIL 

pCUL 

pOIIL 

pCVI. 

.... 

EPAIOO.O 

I!PAtOO.O 

CllcuJdnn 

Oillcutatlon 

Mel. A""""' §tid ,..!and &iiiD1! 

08111110 9;10 06114110 BPS-CV 

oerr 1tto a: 10 oe/14/fO BPS-CV 

06121110 11:~ BPS-CV 

06121110 11:35 BPS-CV 

~E: 

101ST1-4 I.JibiD: 1~C · Gtalb 

~BY: DavfdA Sllles s.mple l'IIM ' '1JISI2712010 1'1~ ' 

. '\ .;; : . ' ' . 

!Ill 811111 .U!mt. lim .. .UJJIII' . Mllllilll . ' Ill. ,.. Start ~ l!nd ~ 

~ 

134.8 :t 3.o7 47'13.00 paiL EPA 903.0 06104110 1":15 08115110 BH-CV 

----~~----·------------------------ SAWU: 10 1i7t4 Ia 10: 1~1D CMb 

SAMPL.al BY: DIIYid ~ Sfflas Simple 111M OSIZ712010 11:30 

· I 

!Ill BIIYil ~ ~ .Lblll 

~ 

210.9 ll: 12.64 33.56 pCi/1. 

---

REMARKS: 

MtlbGsl 

EPAS04.0 

.MQL &IJWS Stilt ADIII!N l!!nd ADI.IliiC 

06116110 9:00 06118110 NI.&-CV 

. ~ ~ ·~ method has been perfotmed under NElAP certification, the .,..~ys~a hal met an of the requirements of 

·the NEI.:AC standard unless olhenNise noted on the Analytical ~ 

* CV Benchmaf1c; Analytlcs. Inc::. Center Valley, PA; $A= ~ Anrdytica, Inc. Seyre, PA 

MANAGER 

.. :•. 't1" --... 

-----·---- DAl"E; __ 611 __ 112_0_1_0 __ 
NAME: Mike Moyer 

OOJ4pANY: Environmental Service Laboratorll$, lno 

AO~SS: 

1803 Philldefphia st. 

. . l~lane, 

PA 1!701 

PAGE: 1 of1 

PHONE: 

F. AX:. 

10 1Ji'f4 ' 

-~1· ··;~ ;'-~ .• . -

(724) 48$8378 (724> 466-4209 

REC~D FOR lAB BY: MAK 

SAttFU!: 10 11714 

~D 

BV: Devld A. stlee 

!.Ill 

._ :~ i'hcnnn 

~tum 

_u,.,_ 

r-,:-' ~.r~~~l· l :<·-. 1 

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! ... .... ~ l ' ·.; ' . 

, .. 

TEST REPORT 

DATE: ~108:46 

La6r ID: 1CJ08G203.0018 

SalrtJllel'lln« 05127120'10 U:30 

Billa 1111111111 

c 0.0825 mgiL - EPA200.8 

< 62.50 I'IJil IllS EPA200.8 

C4z.60pCIIL EPA200.8 

POl: DAS06012010 

PWSII» 

Pap lofl 

Gnlb 

1M 

- ~ ...... - Milt* Ead Mild&.! 08/DSfiO 10:15 08110110 JRA-CV 

30 06103MO 10:15 06110110 JRA-CV 

06103110 10:15 0&'10110 JRA-CV 

DATE: 6/JJIJ(J/0 
ENVIRONMENTAL SERVICE 

LABORATORIES .. INC. SAMPLE REQUEST & CHAIN OF CUSTODY PAG'E OF 

HEAOQUARlERS: 

11103 Phlladelpbla Sl 

Indiana. PA 15701 

(12.4}~63-TEST 

'24) 465-4.209 

SOUTHERlll DMS!ON: 

D 

SampleTyD& 

Sampte ldentlffcatlon ESl# Com,oslte Grab 

Datecmrarr Ttme Clllhtll Date Time 

Cy.po~f Fva/ tt? t?/5'7t ---- ---- .sA1j1C> 1/ ,'J0,41j 

---- ---- ---- ------ ---- ----

---- ---- ---- ---

---- ---- /tJ~ 71-'f 

---- ----

---- ---- ------ ------ ---- ---- ~ --- ---

---- ---- ---- Vi!:. ~7/7 ---- ---- ---- --- ---- ---- TRIP BLANK 11~)57/? ---- ----

---- ---- -:::::::--:::::::- ---- ---- nEI.INDERSI3!iB:I PUROHABER HEREBY loGREm 'ltl PAY SERYICECKARGES ON '-COO'JNTS OIIER:11 W.VB OLD. 

1. 111BS£ SERYICE ato.RGEB VIILLACCRUEA.T l1iJ!. RATE OF 1 1m! PER MOHJK {111% PER ANNUM OR THE ti.AXIWJP.IAU.OWED 11'1' lAW.l 

2. tHe UNDERSIGNED PURa-t•.seR I.GREBI ro PA.Y, IN 1HE £\EMf IDS I.CXXI\Ilff BEOOrli!ll ceiJNQUEKT AND IS TURIED OVERtON« 

lr.TTOfiii;E\' FOR OOlll!CTl:lH. FIEMIONABLE AITORNEV'B f£BI PUliS J.LL CXJURT ANDA.T1END1offi COUECnON CCI BTl. 

P~~. ~It~~. #.1~ £/tJ.1//() fl'. "!.o 

samp~re) r--- Datet Time 

1 7L /71, /~ 5-~7-<.~ \S'-""a 

Ma1rlx II of Contalners 

ww 1 

ww 2 

ww 1 

ww 1 

(2) 1000 ml ww (3) 500mL 

ww 1 

ww 1 

ww 2 

ww 2 

Water 2 

It Relinq-Jlshed ____ By-~nallCil}._ ,, S-d-7-<o 

Dale/lime 

~'~~ ~~~~ 5'k~:;~-:?? Rellnqllll!lled By: {$1g:tatur~)- Dati!ITime Re<l81Ved By~ OateiTime 

Relinquished By: (Signcura} Dalel Time Recefved By: tSJgna:ur .. J Dale~ lime 

PRESERVAT10.r((:Y) N CONTAINERlvY N TEMP :s~c(fY)f NINA 

ContmnerType 

Pnla-1\'· 

Plastic. Lilar 

none 

PlasUc liter 

nooe 

Plastic Liter 

HNO, 

Plastic Liter 

K.zSOc 

Plaslic Liter 

HNOt 

Amber Glass L 

HCI 

Amber Glass l 

H,S04 

Amber VOA Vials 

1101\e 

Amber VOA Vlllls 

KCI 

AmberVOA VIBls 

HCI 

PtoJec:l NOtes: 

Company/Name: 

Address: 

Contact Peraon: 

Phone: 

Fax: 

Form 2SR. Section B. \tern 2.a. "·· • 

Attachment to Great Oak Energy. 

Report dated February 24, 2011 

Production Brine - RWC 802 

Pa_ge 7 of 7 

Analyst& Requested 

-~-~~: SU!rate, AJ~, ,B~Ide 

a~:~,o.·~ ~a-JD:dl~~ surti . 

~~~~~~~~~ess ~N~.~~ra.~ c GroS&=, Grots Be~. Radium 26, Ra~.um ~ j 

Thorium, .. umnium ./ 

o'lt,&G~ 

~olsi P~~olics 

. c~eo~ .) 

( ~ ~~~-*'"-

Senzene, Totu;;;-.:., 

GREAT OAK ENERGY 

637 Allegheny Ave.l PO Box 445 

Oakmont, PA 15139 

Mr. Ed Klamm&r 

412-.828-2900 /412-828-8942 

. (724] 349-5323 

I 

I 

i 

' 

I ' 

' 

I 

I 

I 

l 

I 

I 
Name: 

Sample Date: 

Receipt Date: 

Report Date: 

Sample Site: 

Analyte 

Arsenic-ICP 

Barium-ICP 

Cadmium - ICP 

Chromium - ICP 

Copper-ICP 

Lead-ICP Mercury 

Nickei-ICP 

Selenium-ICP 

Silver-ICP 

Zinc-ICP 

1) Benzene -

37) Ethylbenzcne 

47) Toluene 

58) m+p-Xylene 

60) o-Xylene 

McCutcheon Enterprises, Inc. 

Attn: Mr. Tim Dobrosky 

SampleiD#: Sample Type: 

250 Park Road Sample Source: 

Apollo, PA 15613 Sampler: 

10 13983 

Water 

Grab 

5/13/2010 8:00AM 

5/13/2010 3:14PM 

05117/2010 

Client Sample ID: 

MF (Client) 

Great Oak Energy 

PO 026676-07 

Analyst Date Sample Units Method MDL 

Analyzed Result 

DRM 5/14/2010 ND mgll 200.7/6010 0 

DRM 5/14/2010 734.9 mg!l 200.7/6010 0 

DRM 5/14/2010 ND mg!l 200.7/6010 0 

DRM 5/14/2010 ND mg!l 200.7/6010 0 DRM 5/14/2010 0.50000000 mgll 200.7/6010 0 DRM 5/14/2010 0.90000000 mg!l 200.7/6010 0 DRM 5/14/2010 ND mgll 245.1 0 

DRM 5/14/2010 ND mgll 200.7/6010 0 DRM 5/14/2010 ND mg!l 200.7/6010 0 DRM 5/14/2010 ND mgll 200.7/6010 0 

DRM 5/14/2010 0.75000000 mg/1 200.7/6010 0 

CL 5/13/2010 ND ug/L 624/82608 10 

CL 5!13/2010 ND ug/L 624/8260B 10 CL 5/13/2010 ND ug/L 624/8260B 10 

CL 5/13/2010 ND ug!L 624/8260B 20 

CL 5/1312010 ND ug!L 624/8260B 10 

ND = Not Detected 

DEP Certification #s 32-00382 32-03566 
(

) 

63

S

AX (724) 465

4209 

Great Oak Energy, Inc. 

Mr. Ed Klammer 

P.O. B0x445 

Oakmont, PA 15139-0445 

November 4, 201 0 

Dear Mr. Klammer, -

Environmental Service Laboratories, Inc. (ESL) is accredited in accordance with 

the Pennsylvania Department of Environmental Protection (PADEP) State 

Environmental Laboratory Accreditation Program. State accreditation is based 

upon compliance with Pennsylvania Code, Title 25, Part I, Subpart D, Article VI, 

Chapter 252 "Environmental Laboratory Accreditation" which specifies all state 

mandated Quality ControVQuality Assurance policies and procedures. 

ESL, Inc. is certified to perform all analysis as outlined on the laboratories Scope 

of Accreditation and utilizes methods promulgated through 40 CFR. Our 

laboratory prides itself on the ability to provide our customers with top quality and 

legally defensible data. We value your company as a customer and appreciate 

your business. Thank you for using ESL for all your environmental testing 

requirements. 

Please do not hesitate to contact our laboratory if you have any questions or 

concerns. 

Sincerely, 

Anngela . Cha an 

Director of Operations/Quality Assurance 
Item 3. Process Description & Schematic 

Frac Flow Back 

During the hydraulic fracturing process treated water and sand are pumped into the well under 

pressure. Once the treatment is completed a controlled flow back is used to allow the frac fluid to 

return to the surface. The flow back is monitored for sand returns, chlorides, natural gas, and 

liquid hydrocarbons. 

The flow back begins at the wellhead. The fluid then passes through a choke to an oil, gas, and 

water separator. Flow backwater is directed to a lined pit. In order to reclaim the location the 

water will be transported from the pit to an approved treatment facility for proper disposal. If liquid 

hydrocarbons had returned they would have been directed to steel storage tanks for subsequent 

sales. In the case of natural gas, it is initially directed to a flare stack. Once the volume and 

pressure are sufficient the natural gas is directed to a sales pipeline. 

When the water volume diminishes to less than 20 barrels per day the flow back phase is 

completed and normal production operations begin. 

Flair stack 

Separator 

Sales Meter 

Wellhead 

Lined Pit 

Steel Tank 
SECTION B. WASTE DESCRIPTION 

Item 3. Process Description & Schematic 

Production Brine 

Brine water is generated during the course of normal natural gas production. Normal production 

processes begin when the well begins producing less than 20 barrels of water per day. Although 

the well began the production phase producing approximately 20 barrels per day, the daily 

volume of water diminishes to approximately 2 barrels per day in ten months. 

The production phase begins at the wellhead. Natural gas and the associated production brine 

then flow to a gas and water separator. Natural gas is directed to the sales meter. The 

production water flows to a tank battery of two 210 barrel steel tanks. The tanks are located 

inside a dike. The tanks are monitored daily by telemetry and periodically by the well tender in 

person. When the tanks reach 75% capacity the water is hauled to water treatment facility for 

proper disposal. 

Wellhead 

EB 

Sales Meter 

Separator 

Diked Tank Battery 

2 x 210 barrels