# [



# ] REPORT [



# ] 

# . . Determination
of Auto-Ignition Temperature (Liquids and Gases and Low Melting Point Solids) Study Director: Test Facility:



# [



# ] Sponsor:



# [

] 1 Study Number: 

# 41301965 Study 

# Completion Date:

23 July 2013 Page
1 of 11

# l studyNumber: 41301965



# Rep ort

Page2 

# CONTENTS CONTENTS ...............................................................................

. .....................

. ..............................

2 STUDY DIRECTOR STATEMENT OF GLP COMPLIANCE ....................................................



# 3 QUALITY ASSURANCE STATEMENT ......................................................................................



# 4 SUMMARY .......

. ..........................

.. .......................................

. . . ...........................

. ..........................



# S GENERAL INFORMATION .........................................................................

.. ..............................



# 6 Schedule .................................................................................................................................

6 

# Deviations from Study Plan ...................................................................................................



# 6 Archiving ...............................................................................................................................



# 6 1 INTRODUCTION 

# AND PURPOSE ......................

.. .............................................................

7 

# 1.1 Guidelines



# I Regulations ..........................................................................................

7 2 TEST ITEM ..............................................................................................................

.. ...... ....
. 8 

# 3 TEST ................. ..... .................. ....... ....................................................................................

... 

# 9 3.1 Auto-Ignition Temperature (Liquids and Gases and 

# Low Melting Point Solids) ......................................................................................................................

9 

# 3.1.1 Test System ...............................................................................................

9 3.1.2 Principle ofthe Test ................................................

..... ..............................



# 9 3 .1.3 Perfonnance of the Te st. .............
... ............................................................



# 9 3.1.4 Data Handling ............................................................................................



# 9 3.1.5 Result

s ........................................................................

.. ...........................



# 10 3.1.6 Conclusion ...............................................................................................



# 10 APPENDIX ......................................................................

........ .....................................................

11 Appendix

1 Monitoring Authority Statement of GLP Compliance ...... ..... ...............................

11IStudyNumber:41301965ReportPage3STUDYDIRECTORSTATEMENTOFGLPCOMPLIANCE[]1StudyNwnber:41301965StudyTitle:[1:DeterminationofAuto-IgnitionTemperature (LiquidsandGasesandLowMeltingPointSolids)ThisstudywasperformedincompliancewithUKGLPstandards(Schedule1,GoodLaboratoryPracticeRegulations1999(SI1999/3106asamendedbySI2004/0994)).TheseRegulationsareinaccordancewithGLPstandardspublishedasOECDPrinciplesonGoodLaboratoryPractice(revised1997,ENV/MC/CHEM(98)17);andareinaccordancewith,andimplement,therequirementsofDirectives2004/9/ECand2004/10/EC.TheseprinciplesarecompatiblewithGoodLaboratoryPracticeregulationsspecifiedbyregulatoryauthoritiesthroughouttheEuropeanCommunity,theUnitedStates(EPAandFDA),andJapan(MHLW,MAFFandMETI).Thisreportfullyandaccuratelyreflectstheproceduresusedanddatagenerated.Therewerenocircumstancesconsideredtohaveaffectedtheintegrityofthestudyorthevalidityofthedata.StudyDirector:[]Date:23JULZ013

# I Study Number

: 41301965 Report

Pa ge4 

# QUALITY ASSURANCE STATEMENT 1 Study Nwnber: 

# 41301965 Study Title: 

# [ 1

: Determination
of Auto-Ignition Temperature (Liqui ds and Gases and Low Melting Point Solids) The general facilities and activities are inspected
at least once a year and the results are reported to the relevant responsible person and management. Study-related procedures conducted
at the test facility were audited and inspected. The details of these audits and inspections are given below. Reported
to the relevant Dates and Types ofQA Inspections
Study Director and Test Facility Management Date of Inspect ion Type of Inspection Phase Inspected Report Date 31 May 2013 Study P lan Verification

N / A

31 May2013 02 April20 13 Process

- based Auto-Ignition Temperature
02 April 20 13 (Liquids and Gases) 10 July 2013 Report Audit N/A

10 July2013 

# This statement confirms that this final report reflects the raw data and the procedures followed. Quality Assurance:

[



# ] 

# [ ·········
"



# ] Date

:


# i 4 JUL 2013

# I Study 

# Number

: 41301965 Report

PageS 

# SUMMARY The auto ignition temperature of [

1 has been determined
to be 474 ± 

# 5 °C, using
a procedure designed to be compatible with 

# Method Al5 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) 

# No 440 /2 008 of30 May 2008.

# l Study Number: 41301965 Report 

# GENERAL INFORMATION S chedule Expe rim e n ta l Start in g Da t e: Experimental Comp

l etion D ate: 

# Deviation

s from Stud y Plan
21 Jun e 20 1 3 26 June 20 1 3 There were no deviations (unplanned changes) from the study plan. 

# A rchi v in g

Page6 

# Unless instructed otherwise by the S p onsor, the Study P l an, all raw data (paper and e l ec t ro ni c) and the final report will be retained in the

[

] archives for fifteen years after which instructions will be sought as to further retention or disposal. Further retention or return of the data wi ll be chargeable to the Sponsor. No data wi ll be discarded without co n tacting the Sponsor to obtain their written consent.1 study Number

: 41301965 Report

Page7 

## 1 INTRODUCTION AND PURPOSE The purpo

s e of this study

i s to evaluate the auto-ignition temperature of the test item. 

### 1.1 Guidelines

I 

### Regulations The test method described
is designed to be compatible 

### with the procedures indicated by the following internationally accepted guidelines and recommendations: • Commission Regulation (EC) No 440/2008 (as amended) of 30 May 2008, Part A : Methods for the determination
of physico-chemical properties.

# I Study Number

: 4 1 301965 Report

P ageS 

# 2 TESTITEM Information supplied by the sponsor: Identification: De scri ption:
Green solid block
• Batch

:

[ 

# Ex piry

I 

# Retest Date:

Not Specified Storage Co ndition s:

R oom te mper ature in 

# the dark • Sa mpl e was melted with penn ission of the s pon sor on 08/05113,

p ost melting the sam pl e was an ambe
r liqui d. Sponsor confirmed sam p l e was okay for testing post melt.lstu dyNumber: 41301965 Report

Page9 

## 3 TEST 3.1 Auto-Ignition Temperature (Liquids and Gases and Low Melting Point Solids) 3.1.1 Test System The determination was carried out using
a procedure

1 designed to be compatible with Method Al5 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of30 May 2008. Instrument:
Carbo lite flask heater 

### 3.1.2 Principle of the Test The auto -i gnition temperature

i s the lowest temperature

at which the test item will ignite when mixed with air under the conditions defined in the test method. 

### 3.1.3 Performance
of the Test The test fl ask was heated in a flask heater. Aliquots of test item (tested as r eceived) were injected into the flask using
a syringe and the flask observed for signs of ignition over a 300 second period. This procedure was repeated, varying the samp

l e size, as necessary, until the lowest temperature

at which ignition, if any, occurred within 300 seconds of insertion, was determined. 

### 3.1.4 Data Handling The auto-ignition temperature

is the lowest temperature that will result in the ignition of the test item injected into the test flask. The room temperature and atmospheric pressure is recorded for each day of the test. 1 Based on, Anon (1987), Electrical Apparatus for Explosive Gas Atmospheres

. Part 4 : Method of Test for Ignition Temperature. JEC Publications 79-4, Pl-19.I Study Number: 41301965 Report 3.1.5 Results Results of the auto-ignition temperature determination are shown in the following table. Table 3.1 Test Test Volume Ignition Delay Temperature COC) (IlL)

(s) 200 (clean flask)
70 >300 250 (clean flask)
70 >300 300 (clean flask)
70 >300 350

70 >300 400

70 >300 450 (clean flask)
70 >300 500 (clean flask)
70

3 490

70

4 480

70

6 470 (clean flask)
70 >300 476

70

11 472

70 >300 474 (clean flask)
70 >300 474 (clean flask) 200

6 470 200 >300 472 (clean flask) 200 >300 472 (clean flask) 400 >300 472 (clean flask) 600 >300 472 (clean flask) 800

>3 00 472 (clean flask) 1000 >300 Room temperature:

19 °C to 20 °C Atmospheric pressure: 101.1 kPa to 103.0 kPa 3.1.6 Conclusion Observations No ignition, grey fumes emitted. No ignition, grey fumes emitted. No ignition, grey fumes emitted. No ignition

, grey fumes emitted. No ignition, grey fumes emitted. No ignition, grey fumes emitted. Orange flame, grey fumes emitted. Orange flame, grey fumes em itted. Orange flame, grey fumes emitted. No ignition, grey fumes emitted. Orange flame, grey fumes emitted. No ignition, grey fumes emitted. No ignition, grey fumes emitted. Orange flame, grey fumes emitted. No ignition, grey fumes emitted. No ignition, grey fumes emitted. No ignition, grey fumes emitted. No ignition

, grey fumes emitted. No ignition, grey fumes emitted. No ignition, grey fumes emitted. The tes t item has been determined
to have an auto-ignition temperature of 474 ± 5 °C. Page 101 Study Number: 41301965 Report 

## APPENDIX Appendix

1 Monitoring Authority Statement of GLP Compliance 

# i 

# nli) Department **~** ofHeafth THE DEPARTMENT OF HEALTH OF THE GOVERNMENT OF THE UNITED KINGDOM GOOD LABORATORY PRACTICE STATEMENT OF COMPLIANCE IN ACCORDANCE WITH DIRECTIVE 2004/9/EC TEST FACIUTY

TEST TYPE(S) 

# [



# ] DATE OF INSPECTION 10 July 2012 **Anal~lcaVCIInlcal** Chemistry Environmental Tox icity Environmental Fate Mutagenicity P hys/Chem. Tests Toxicology An inspection for compliance with the Principles of Good Laboratory Practice was carried out at the above test facility as part of the UK Good Laboratory Practice Compliance Monitoring Programme

. Th

i s statement confirms that, on the date of issue, the UK Good Laboratory Practice Monitoring Authority were satisfied that the above test facility was operating
in compliance with the OECD Principles of Good Laboratory Practice. This statement constitutes

a Good Laboratory Practice Instrument (as defined In the UK Good Laboratory Practice Regulations 1999)

. 

## p::?~~ '30 

## f, f,z... Dr. AndrewJ

. Grey

• Head, UK GLP Monitoring Authority

• • Page 11