# (, (

# c (

:

# 4 Toxicological properties 4.1 Acute toxicity 

# 4.1.1 4.1.5 4

. 1.6 Oral exposure Oral LD 50 

# in rats ranged from 0.77 to 2.83 g/kg bw Transitory liver damage

is seen after sublethal doses given
to animals. Intake may cause corrosion

in mouth and oesophagus. 

# Skin irritation Liquid DEA applied

to rabbit skin under semiocclusion

for 24 hours on
1 0 consecutive days caused only minor irritation. Skin may denature upon repeated application. Clinical testing
of cosmetics containing DEA showed mild skin irritation

in humans, when the concentration
was 5 % and above. 

# Eye irritation Liquid DEA dropped into rabbit eye (0.2 ml) and rinsed out after 15 seconds caused moderate

to severe conjunctival irritation and corneal injury. Impairment

of vision may occur on prolonged contact. 

# 4. 1. 7 

# Skin sensitisation No data found

. 

# 4. 1. 8 Respiratory sensitisation No data found. 4.3 Other effects 

# 4. 3. 1 Mutagenic effect
in bacteria

(5) (6) (6) 

# (5) (5) (5) DEA was not mutagenic

in four strains
of S. 

# typhimurium

or in mouse

(7) lymphoma cells (L5178Y) with or without metabolic activation. DEA did not induce sister chromatid exchanges

or chromosomal aberrations

in cultured CHO cells with or without metabolic activation. Nor did DEA induce cytogenetic changes (micronuclei)

in mice exposed dermally

to 80 - 1 ,250 mg DEA/kg bw for 13 weeks. 4.4 Other relevant toxicological information 

# 4 . 4. 1 Reproduction toxicity No data were available

on reproductive
and developmental effects

in

(8) humans. Dansk Toksikologi Center, 07-12-2001

Page 2/4 42472/khc/Toxprofil Diethanolamine.docInafeedingstudywithrats,pupsreducedbodyweightgainandpostimplantationandpostnatalmortalitieswereincreasedatdosesthatcausedmaternaltoxicityseenasreducedbodyweightgain,increasedkidneyweightandreducedfeedandwaterintake.NOAELsformaternalanddevelopmentaltoxicitywere50mg/kgbw/dayandLOAEL'swere125mg/kgbw/dayinthisstudy.4.4.2CarcinogenicityFourstudiesonworkersusingmetalworkingfluidsshowedsmallexcessesofcancerinthestomach,oesophagusandlarynx.NocorrelationcouldbespecificallyrelatedtoDEAexposure,butonlytosolubleoilsandsyntheticfluids.IARCconcludedthatthereisinadequateevidenceinhumansforthecarcinogenicityofDEA.MicewereexposedtoDEAbyskinapplication.Inbothfemalesandmalesatreatment-relatedincreaseinlivertumourswasseen.Inastudyusingtransgenicmice(Tg.AC)notreatment-relatedincreaseinskintumourswereseen.InratsexposedtoDEAbyskinapplicationnotreatment-relatedincreasedtumourincidencewereseen,neitherinfemalesnorinmales.IARCconcludedthatthereislimitedevidenceinexperimentalanimalsforthecarcinogenicityofDEA.IARC'soverallevaluationisthatDEAisnotclassifiableastoitscarcinogenicitytohumans(group3).DEAmaynitrosatedtoN-nitrosodiethanolamine,whichisaknownanimalcarcinogen.4.4.3NeurotoxicityNodatafound.4.4.4OtherorgantoxicityRatsfedwith170mg/kgbw/dayfor90daysshoweddegenerationofrenaltubulesandfattydegenerationoftheliver.A90-dayfeedingstudyshoweda"no-ill-effect"levelof20mg/kgbw/day5Ecotoxicologicalproperties5.2Degradation5.2.1BioticdegradationManytestswithvaryingresultfromreadilybiodegradabletonotbiodegradablearereported.However,mostofthetestspointtoDEAasreadilybiodegradable.TheBIOWINQSARmodelsestimateDEAtobiodegradefast.DanskToksikologiCenter,07-12-200142472/khc/ToxprofilDiethanolamine.docPage3/4(9)(8)(8)(8)(5)(5)(5)(3)(10)

### 4 Toxicological properties 4.1 Acute toxicity 

### 4. 1. 1 Oral exposure The oral LDso
is 541 0 mg/kg

in rats.

(2) The oral LDso
is 2700 mg/kg

in mice.

(4) 

### 4.1.5 Skin irritation Tetrahydrophthalic anhydride

is slightly irritating

to the rabbit skin (500

(2) mg/24 hour- mild). Skin irritating test performed

in according

to the OECD guideline
no. 404 (3) resulted

in an irritation index
at 0

. 6/8 indicating that tetrahydrophthalic anhydride

is not irritating. 

### 4. 1. 6 Eye irritation In an eye-irritating
test according

to OECD guideline 405

it was found

(3) that there

is a risk for irreversible effects. No score was calculated since only one animal was used
in the test and the test was stopped after one hour due to the severe effects. 

### 4. 1. 

### 7 Skin sensitisation In a guinea pig maximisation
test according

to OECD guideline
no. 406,
(3) there were 17/20 animals that showed positive response

. 

### 4. 1. 8 Respiratory sensitisation No data found. 4.3 Other effects 

### 4. 3. 

### 1 Mutagenic effect
in bacteria One negative Ames test was found using Salmonella typhimurium TA98,
(3) TA 1 00, TA 1535, TA 1537 and TA 1538 with and without metabolic activation

at a concentration

on 1 000 Jlg/plate. 4.4 Other relevant toxicological information 

### 4. 4.

1 Reproduction toxicity No data found. 

### 4. 4. 2 Carcinogenicity No data found. Dansk Toksikologi Center, 07-12-2001 42472/apjffoxprofil THPA

. doc

Page

2/3

# ..



# .. ( (4Toxicologicalproperties4.1Acutetoxicity4.1.1OralexposureTheoralLDsorangedfrom1.9to5.6g/kginratsand1.25g/kginmice.TheoralLD50inrabbitswas5.6g/kg.Poisonedmiceexperiencedirritationofthegastrointestinalmucosa,accompaniedwithhyperemiaandhemorrhageandsometimeswithperforationsofthestomach.4.1.2InhalationexposureIrritanttolungsandairpassages.Inhalationcancauselungedemaandasthma.NodeathsoracuteadversereactionswereobservedwhenratsinhaledrespirableTMAdustat7400mg/m3for4hours.4.1.5SkinirritationIrritanttotheskin.4.1.6Eyeirritation100mgTMApowderappliedtorabbiteyesresultedincornealcorrosivelesionsandchemicalburnsoftheconjunctivathatdidnotreverseafter7days.DraizetestinrabbitsshowedTMAasbeingseverelyirritating.4.1.7SkinsensitisationMaybeapowerfullallergen.TopicalexposuretoTMAmayleadtotypeIVhypersensitivityreactionsresultingincontactdermatitisinhumans.Dermalsensitisationreactionsareobserved.DanskToksikologiCenter,07-12-200142472/apjfroxprofilTMA.docPage2/5(5)(7)((8)(4)(5)(3)(5)(9)(10)(3)(8)(11)(7)(4.1.8RespiratorysensitisationProlongedorrepeatedexposurecancauseasthmaticreaction.(4)Re-exposurebyinhalationmayleadtoacell-mediatedimmuneresponse(11)inthelungs,whichplaysaroleinthepathologyseeninconjunctionwithtypesIIandIllpulmonarydisease.LevelsofserumlgEcanbemeasuredinexposedworkersandare(11)predictiveoftheoccurrenceoftypeIpulmonaryreactions.Inastudy,ratswereexposedtoasingle,6-hour,gradedinhalationof(5)TMA(rangingfrom0to135J.lg/m3)andheldfor3weekswithoutfurtherexposure,theanimalswerechallengedwithasingle6-hourexposureat500J.lg/m3ofTMA.Therewerenodeathsandnoclinicalsignsoftoxicity.Aconcentration-relatedincreaseinthenumbersofhemorrhagicfociinthelungswasrecorded.Undertheconditionsofthestudy,anoobserved-adverse-effectlevel(NOAEL)forsensitisationwas1.6J.lglm3,andthelowest-observed-adverselevel(LOAEL)was7.7J.lg/m3.4.3Othereffects4.3.1MutageniceffectinbacteriaTMAwasnegativeinaSalmonellamutagenicityassay.(7)4.4Otherrelevanttoxicologicalinformation4.4.1ReproductiontoxicityPregnantratsandguineapigswereexposedbyinhalationforonehour,(7)sixtimesduringorganogenesistotheconcentrationof0.5mgTMA/m3.Thisdidnotresultinteratogenicfindingsbutlunghemorrhagewasfoundtodevelop.4.4.2CarcinogenicityNodatafound4.4.3NeurotoxicityRepeatedexposureshowedmoderatecumulativepropertiesofTMAand(7)centralnervoussystemactivitywasaffected.4.4.4OtherorgantoxicitySprague-DawleyratswereexposedtoTMAat0,2,15or50J.lglm3,6(5)hours/day,5days/weekfor6.5or13weeks.Therepeatedexposureresultedinaconcentration-relatedincreaseinfocalpulmonaryhemorrhage,microscopicalveoarhemorrhage,pulmonaryedema,andlobularbronchopneumonia.DanskToksikologiCenter,07-12-200142472/apjfToxprofilTMA.docPage3/5Bank (HSDB). CHEMBANK

on CD-ROM, updated August 2001. 10

. European chemical Bureau (ECB). International uniform chemical information Database (IUCLID)

on CO-rom

. lspra

: ECB; 2001. 11

. Klaassen CD, Amdur MO, Oculi

J, editors

. Casarett and Oculi's toxicology

: The basic science

of poisons.

5 ed. New York

: McGrawHill; 1996. Dansk Toksikologi Center, 07-12-2001 42472/apjfToxprofil TMA.doc

Page 5/5

# .



# .. ( (

# 4.1.5 Skin irritation No data found. 

# 4.1.6
Eye irritation No data found. 

# 4

. 1.7 Skin sensitisation No data found. 

# 4.1.8 Respiratory sensitisation No data found. 4.3 Other effects 

# 4.3.1 Mutagenic effect
in bacteria No data found. 4.4 Other relevant toxicological information 

# 4.4. 1 Reproduction
toxicity No data found. 

# 4.4.2 Carcinogenicity No data found. 

# 4. 4. 3 Neurotoxicity No data found. 

# 4.4.4 Other organ toxicity No data found. 

# 5 Ecotoxicological properties 5.2 Degradation 

# 5.2.1 

# 6 Biotic degradation 4-Ciyclohexene-1,2-dicarboxylic

acid
is expected

to be reaily biodegradable. 

# Summary It is not possible

to prepare

a summary

of this toxicological profile
of 4- cyclohexene-1,2-dicarboxylic

acid due to lack of data. Dansk Toksikologl Center, 07-12-2001 42472/apj/Toxprofil THPAcid.doc

Page

2/3



# ( (1)(

7 Reference List 1. EPISuite [computer program].

v. 3.1 0. U.S. Environmental Protection Agency; 2001. Dansk Toksikologi Center, 07-12-2001 42472/apjfToxprofil THPAcld.doc

Page 3/3.... **--~**


# -·


# . ( (4.1.1OralexposureTheoralLDsois2,500mg/kginmice.Poisonedmiceexperienceirritation(3)ofthegastrointestinalmucosa,accompaniedwithhyperemiaandhemor(4)rhage,andsometimeswithperforations.4.1.5SkinirritationNodatafound.4.1.6EyeirritationNodatafound.4.1.7SkinsensitisationNodatafound.4.1.8RespiratorysensitisationNodatafound.4.3Othereffects4.3.1MutageniceffectinbacteriaNodatafound.4.4Otherrelevanttoxicologicalinformation4.4.1ReproductiontoxicityNodatafound.4.4.2CarcinogenicityNodatafound.4.4.3NeurotoxicityNodatafound.4.4.4OtherorgantoxicityNodatafound.5Ecotoxicologicalproperties5.2Degradation5.2.1BioticdegradationTrimelliticacidisexpectedtobereadilybiodegradable.DanskToksikologiCenter,07-12-200142472/apj/ToxprofilTMAcid.doc(2)Page2/3

### , 

# .....

. ( 

# (0ccC'J

# c~ 

# (Soil Adsorption Coefficient (PCKOCWIN v1.66): Koc

10 Log Koc: 1.000 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 4.306E-005

C)

[ HYDRO WIN v1. 67] L/mol-sec Kb Half-Life

at pH 8: 510.026 years Kb Half-Life

at pH 7: 5100.257 years BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 0.500 (BCF



### = 3.162) log Kow used: -3.08 (estimated) Volatilization
from Water: Henry LC: 4.45E-020 atm-m3/mole (estimated

by Half-Life from Model River: 2.11E+016 hours Half-Life from Model Lake

: 2.302E+017 hours Group SAR Method) (8.793E+014 days) (9.593E+015 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.75 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) Air 8.09e-009
0.756 Water 42.8

208 Soil 57.1

208 Sediment 0.0638

832 Persistence Time: 266 hr (kg/hr) 1000 1000 1000 0



# ( 

# c (

# Koc 12.47 Log Koc: 1.096 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 2.718E-001 Kb Half-Life

at pH 8: 29.511 days Kb Half-Life

at pH 7: 295.109 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 

# 0.500 (BCF

= 

# 3.162) log Kow used: -0.24 (estimated) Volatilization
from Water:

C)

[ HYDRO WIN v1

. 67] L/mol-sec Henry LC: 1.25£-024 atm-m3/mole (estimated

by Group SAR Method) Half-Life from Model River: 8.076E+020 hours (3.365E+019 days) Half-Life from Model Lake

: 8.B1E+021 hours (3.671E+020 days) Removal

In Wastewater Treatment Total removal: Total biodegradation: Total sludge adsorption: Total to Air: Level III Fugacity Model: (recommended maximum 99%): 1.85 percent 0.09 percent 1.76 percent 0.00 percent Mass Amount Half-Life Emissions (percent)

(hr) (kg/hr) Air 2.84e-013
2.81
1000 Water 45.1

360
1000 Soil 54.8

360
1000 Sediment 0.0755 1.44e+003

0 Persistence Time: 421 hr



# ( ( 

# c (

# Koc Log Koc: 12.47 1. 

# 096 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 4.200E-001

C)

[ HYDROWIN
v1. 67] L/mol-sec Kb Half-Life

at pH 8: 19.098 days Kb Half-Life

at pH 7: 190.978 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 

# 0.500 (BCF

= 

# 3.162) log Kow used: -0.24 (estimated) Volatilization
from Water: Henry LC: 1.25E-024 atm-m3/mole (estimated

by Half-Life from Model River: 8.076E+020 hours Half-Life from Model Lake

: 8.81E+021 hours Group SAR Method) (3.365E+019 days) (3.671E+020 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 1.85 percent

99%)

: Total biodegradation:

0.09 percent Total sludge adsorption:

1.76 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) Air 2.84e-013

2.81 Water 45.1

360 Soil 54.8

360 Sediment 0.0755 1.44e+003 Persistence Time: 421 hr (kg/hr) 1000 1000 1000 0



# ( (

# Koc Log Koc: 12.47 1. 

# 096 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 2.282E+OOO

C)

[ HYDROWIN

v1

. 67] L/mol-sec Kb Half-Life

at pH 8: 3.515 days Kb Half-Life

at pH 7: 35.155 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF



# = 0.500 (BCF



# = 3.162) log Kow used: -0.58 (estimated) Volatilization
from Water: Henry LC: 1.25E-024 atm-m3/mole (estimated

by Half-Life from Model River: 8.076E+020 hours Half-Life from Model Lake

: 8.81E+021 hours Group SAR Method) (3.365E+019 days) (3.671E+020 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1. 7 6 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions Air Water Soil Sediment (percent)

(hr) 2.84e-013

2.81 45.2

360 54.7

360 0.0755 1.44e+003 Persistence Time: 421 hr (kg/hr) 1000 1000 1000 0



# ( 

# c (Soil Adsorption Coefficient (PCKOCWIN vl.66): Koc

10 Log Koc: 1.000 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg C)

[ HYDROWIN v1.67] Rate constants
can NOT be estimated
for this structure! BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 0.500 (BCF



### = 3.162) log Kow used: -0.79 (estimated) Volatilization
from Water: Henry LC: 1.51E-018 atm-m3/mole (estimated

by Half-Life from Model River: 6.219E+014 hours Half-Life from Model Lake

: 6.785E+015 hours Bond SAR Method) (2.591E+013 days) (2.827E+014 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.76 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions Air Water Soil Sediment (percent)

(hr) 7.18e-008
0.884 42.7

208 57.2

208 0.0638

832 Persistence Time: 266 hr (kg/hr) 1000 1000 1000 0



# ( 

# (_Log Koc:

1. 000 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg C)

[ HYDROWIN v1.67] Rate constants can NOT be estimated
for this structure! BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 0.500 (BCF

= 3.162) log Kow used: -1.39 (estimated) Volatilization
from Water: Henry LC: 1.02E-023 atm-m3/mole (estimated

by Bond SAR Method) Half-Life from Model River: 9.897E+019 hours (4.124E+018 days) Half-Life from Model Lake

: 1.08E+021 hours (4.498E+019 days) Removal

In Wastewater Treatment Total removal: Total biodegradation: Total sludge adsorption: Total to Air: Level III Fugacity Model: (recommended maximum 99%): 1.85 percent 0.09 percent 1.75 percent 0.00 percent Mass Amount Half-Life Emissions Air Water Soil Sediment (percent)

(hr) 3.56e-010

7.56 45.3

360 54.6

360 0.0755 1.44e+003 Persistence Time: 421 hr (kg/hr) 1000 1000 1000 0



# ( 

# c (

# Log Koc:
1. 

# 000 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg C)

[ HYDROWIN v1.67] Rate constants
can NOT be estimated
for this structure! BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


# = 0.500 (BCF

= 

# 3.162) log Kow used: -1.39 (estimated) Volatilization
from Water: Henry LC: 1.02E-023 atm-m3/mole (estimated

by Bond SAR Method) Half-Life from Model River: 9.897E+019 hours (4.124E+018 days) Half-Life from Model Lake

: 1.08E+021 hours (4.498E+019 days) Removal

In Wastewater Treatment Total removal: Total biodegradation: Total sludge adsorption: Total to Air: Level III Fugacity Model: (recommended maximum 99%): 1.85 percent 0.09 percent 1.75 percent 0.00 percent Mass Amount Half-Life Emissions (percent)

(hr) (kg/hr) Air 3.56e-010
7.57
1000 Water 45.3

360
1000 Soil 54.6

360
1000 Sediment 0.0755 1.44e+003

0 Persistence Time: 421 hr



# (

# Log Koc:

1. 

# 000 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg C)

[ HYDROWIN v1.67] Rate constants
can NOT be estimated
for this structure! BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


# = 0.500 (BCF



# = 3.162) log Kow used: -1.73 (estimated) Volatilization
from Water: Henry LC: 1.02E-023 atm-m3/mole (estimated

by Half-Life from Model River: 9.897E+019 hours Half-Life from Model Lake

: 1.08E+021 hours Bond SAR Method) (4.124E+018 days) (4.498E+019 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%)

: 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1. 

# 7 5 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) Air 3.56e-010
7.56 Water 45.3

360 Soil 54.6

360 Sediment 0.0755 1.44e+003 Persistence Time: 421 hr (kg/hr) 1000 1000 1000 0



# c (

# ( 

# (

)

# .

. ( (

# Soil Adsorption Coefficient (PCKOCWIN v1.66): Koc 2535 Log Koc: 3.404 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 8.613E-005

C)

[ HYDRO WIN v1. 67] L/mol-sec Kb Half-Life

at pH 8: 255.013 years Kb Half-Life

at pH 7: 2550.128 years BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


# = 0.500 (BCF



# = 3.162) log Kow used: -1.42 (estimated) Volatilization
from Water: Henry LC: 5.73E-025 atm-m3/mole (estimated

by Half-Life from Model River: 2.068E+021 hours Half-Life from Model Lake

: 2.256E+022 hours Group SAR Method) (8.615E+019 days) (9.398E+020 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1. 85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.75 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions Air Water Soil Sediment (percent)

(hr) 1.85e-013 0.438 42.8

208 57.2

208 0.0638

832 Persistence Time: 266 hr (kg/hr) 1000 1000 1000 0



# ( 

# c (Koc Log Koc: 6.184E+004 4.791 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 5.437E-001

C)

[ HYDROWIN
vl. 67] L/mol-sec Kb Half-Life

at pH 8: 14.755 days Kb Half-Life

at pH 7: 147.554 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 0.500 (BCF

= 3.162) log Kow used: 1.64 (estimated) Volatilization
from Water: Henry LC: 4.55E-034 atm-m3/mole (estimated

by Half-Life from Model River: 2.847E+030 hours Half-Life from Model Lake

: 3.105E+031 hours Group SAR Method) (1.186E+029 days) (1.294E+030 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 2.02 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.93 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) (kg/hr) Air 1.04e-018

2.84
1000 Water 36.1

360
1000 Soil 63.8

360
1000 Sediment 0.0822 1.44e+003

0 Persistence Time: 438 hr



# (_

# Koc 6.184E+004 LogKoc: 4.791 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total Kb for pH>

8 at 25 deg C : 8.401E-001

C)

[ HYDRO WIN v1

. 67] L/mol-sec Kb Half-Life

at pH 8: 9.549 days Kb Half-Life

at pH 7: 95.489 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


# = 0.500 (BCF



# = 3.162) log Kow used: 1.64 (estimated) Volatilization
from Water: Henry LC: 4.55E-034 atm-m3/mole (estimated

by Half-Life from Model River: 2.847E+030 hours Half-Life from Model Lake

: 3.105E+031 hours Group SAR Method) (1.186E+029 days) (1.294E+030 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 2.02 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.93 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) Air 1.04e-018

2.84 Water 36.1

360 Soil 63.8

360 Sediment 0.0822 1.44e+003 Persistence Time: 438 hr (kg/hr) 1000 1000 1000 0



# c 

# c (Koc Log Koc: 6.184E+004 4.791 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 6.919E-001

C)

[ HYDROWIN
v1. 67] L/mol-sec Kb Half-Life

at pH 8: 11.594 days Kb Half-Life

at pH 7: 115.945 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 0.500 (BCF

= 3.162) log Kow used: 1.64 (estimated) Volatilization
from Water: Henry LC: 4.55E-034 atm-m3/mole (estimated

by Half-Life from Model River: 2.847E+030 hours Half-Life from Model Lake

: 3.105E+031 hours Group SAR Method) (1.186E+029 days) (1.294E+030 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 2.02 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.93 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions Air Water Soil Sediment (percent)

(hr) 1.04e-018

2.84 36.1

360 63.8

360 0.0822 1.44e+003 Persistence Time: 438 hr (kg/hr) 1000 1000 1000 0



# ( 

# ( (

# Koc 6.184E+004 Log Koc

:
4

. 7 91 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 2.702E+OOO

C)

[ HYDRO 

# WIN v1. 67] L/mol-sec Kb Half-Life

at pH 8: 2.969 days Kb Half-Life

at pH 7: 29.689 days BCF Estimate from Log Kow (BCPdiN v2.15): Log BCF


# = 0.500 (BCF



# = 3.162) log Kow used: 1.30 (estimated) Volatilization
from Water: Henry LC: 4.55E-034 atm-m3/mole (estimated

by Half-Life from Model River: 2.847E+030 hours Half-Life from Model Lake

: 3.105E+031 hours Group SAR Method) (1.186E+029 days) (1.294E+030 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.93 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.83 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) Air 1.06e-018

2.84 Water 39.5

360 Soil 60.5

360 Sediment 0.077 1.44e+003 Persistence Time: 431 hr (kg/hr) 1000 1000 1000 0



# ( 

# c (

# Koc Log Koc: 6.184E+004 4.791 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total Kb for pH>

8 at 25 deg
C

: 2.554E+OOO Kb Half-Life

at pH 8:

3

. . 141 days Kb Half-Life

at pH 7: 31.413 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 

# 0.500 (BCF

= 

# 3.162) log Kow used: 1.30 (estimated) Volatilization
from Water:

C)

[ HYDROWIN
v1. 67] L/mol-sec Henry LC: 4.55E-034 atm-m3/mole (estimated

by Group SAR Method) Half-Life from Model River: 2.847E+030 hours (1.186E+029 days) Half-Life from Model Lake

: 3.105E+031 hours (1.294E+030 days) Removal
In Wastewater Treatment Total removal: Total biodegradation: Total sludge adsorption: Total to Air: Level III Fugacity Model: (recommended maximum 99%): 1.93 percent 0.09 percent 1.83 percent 0.00 percent Mass Amount Half-Life Emissions (percent)

(hr) (kg/hr) Air 1.06e-018

2.84
1000 Water 39.5

360
1000 Soil 60.5

360
1000 Sediment 0.077 1.44e+003

0 Persistence Time: 431 hr



# ( 

# ( (

# Koc Log Koc: 6.184E+004 4.791 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 4.564E+OOO

C)

[ HYDROWIN
vl. 67] L/mol-sec Kb Half-Life

at pH 8: 1.758 days Kb 

# Half-Life

at pH 7: 17.577 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 

# 0.500 (BCF



# = 3.162) log Kow used: 0.96 (estimated) Volatilization
from Water: Henry LC: 4.55E-034 atm-m3/mole (estimated

by Half-Life from Model River: 2.847E+030 hours Half-Life from Model Lake

: 3.105E+031 hours Group SAR Method) (1.186E+029 days) (1.294E+030 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.88 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.79 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions Air Water Soil Sediment (percent)

(hr) 1.07e-018

2.84 42.1

360 57.9

360 0.0756 1.44e+003 Persistence Time: 427 hr (kg/hr) 1000 1000 1000 0



# ( ( 

# ( (

# Soil Adsorption Coefficient (PCKOCWIN vl.66): Koc 1.252E+004 Log Koc: 4.098 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 2.719E-001

C)

[ HYDROWIN
v1. 67] L/mol-sec Kb Half-Life

at pH 8: 29.506 days Kb Half-Life

at pH 7: 295.062 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 

# 0.500 (BCF



# = 3.162) log Kow used: -1.20 (estimated) Volatilization
from Water: Henry LC: 1.62E-029 atm-m3/mole (estimated

by Half-Life from Model River: 7.662E+025 hours Half-Life from Model Lake

: 8.358E+026 hours Group.SAR Method) (3.192E+024 days) (3.483E+025 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.75 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions Air Water Soil Sediment (percent)

(hr) 1.04e-015 0.759 45.3

360 54.6

360 0.0755 1.44e+003 Persistence Time: 421 hr (kg/hr) 1000 1000 1000 0Soil Adsorption Coefficient (PCKOCWIN v1.66): Koc 1.252E+004 Log Koc: 4.098 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 4.201E-001

C)

[ HYDROWIN
v1. 67] L/mol-sec Kb Half-Life

at pH 8: 19.096 days Kb Half-Life

at pH 7: 190.958 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


### = 0.500 (BCF



### = 3.162) log Kow used: -1.20 (estimated) Volatilization
from Water: Henry LC: 1.62E-029 atm-rn3/mole (estimated

by Half-Life from Model River: 7.662E+025 hours Half-Life from Model Lake

: 8.358E+026 hours Group SAR Method) (3.192E+024 days) (3.483E+025 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.75 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) Air 1.04e-015 0.759 Water 45.3

360 Soil 54.6

360 Sediment 0.0755 1.44e+003 Persistence Time: 421 hr

( kg/hr) 1000 1000 1000 0



# ( (

# Soil Adsorption Coefficient (PCKOCWIN v1.66): Koc 1.252E+004 Log Koc: 4.098 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 2.282E+OOO

C)

[ HYDROWIN
vl. 67] L/mol-sec Kb Half-Life

at pH 8: 3.515 days Kb Half-Life

at pH 7: 35.154 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


# = 0.500 (BCF



# = 3.162) log Kow used: -1.54 (estimated) Volatilization
from Water: Henry LC: 1.62E-029 atm-m3/mole (estimated

by Half-Life from Model River: 7.662E+025 hours Half-Life from Model Lake

: 8.358E+026 hours Group SAR Method) (3.192E+024 days) (3.483E+025 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.75 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) Air 1.04e-015 0.759 Water 45.3

360 Soil 54.6

360 Sediment 0.0755 1.44e+003 Persistence Time: 421 hr (kg/hr) 1000 1000 1000 0



# ( 

# cSoil Adsorption Coefficient (PCKOCWIN v1.66): Koc

10 Log Koc:

1. 000 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total Kb for pH>

8 at 25 deg C : 8.613E-005

C)

[ HYDROWIN v1. 67] L/mol-sec Kb Half-Life

at pH 8: 255.013 years Kb Half-Life

at pH 7: 2550.128 years BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 0.500 (BCF



### = 3.162) log Kow used: -0.67 (estimated) Volatilization
from Water: Henry LC: 1.41E-019 atm-m3/mole (estimated

by Half-Life from Model River: 7.706E+015 hours Half-Life from Model Lake

: 8.407E+016 hours Bond SAR Method) (3.211E+014 days) (3.503E+015 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 1.85 percent

99%)

: Total biodegradation:

0.09 percent Total sludge adsorption:

1.76 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) Air 3.55e-009

0.6 Water 45.2

360 Soil 54.7

360 Sediment 0.0755 1.44e+003 Persistence Time: 421 hr (kg/hr) 1000 1000 1000 0



# cKoc

10 Log Koc:
1. 000 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 6.919E-001

C)

[ HYDROWIN
v1. 67] L/mol-sec Kb Half-Life

at pH 8: 11.594 days Kb Half-Life

at pH 7: 115.945 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF



### = 0.500 (BCF



### = 3.162) log Kow used: -1.02 (estimated) Volatilization
from Water: Henry LC: 9.54E-025 atm-m3/mole (estimated

by Half-Life from Model River: 1.203E+021 hours Half-Life from Model Lake

: 1.313E+022 hours Bond SAR Method) (5.013E+019 days) (5.469E+020 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.75 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions Air Water Soil Sediment (percent)

(hr) 3.04e-011

1.42 45.3

360 54.6

360 0.0755 1.44e+003 Persistence Time: 421 hr (kg/hr) 1000 1000 1000 0



# ( 

# c ( 

# (Koc

10 Log Koc:

1. 000 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total **~n** for pH>

8 at 25 deg C : 3.495E-001

C)

[ HYDROWIN
v1. 67] L/mol-sec Kb Half-Life

at pH 8: 22.955 days Kb Half-Life

at pH 7: 229.54

7 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


### = 0.500 (BCF



### = 3.162) log Kow used: -1.37 (estimated) Volatilization
from Water: Henry LC: 9.54E-025 atm-m3/mole (estimated

by Half-Life from Model River: 1.203E+021 hours Half-Life from Model Lake

: 1.313E+022 hours Bond SAR Method) (5.013E+019 days) (5.469E+020 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.75 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions Air Water Soil Sediment (percent)

(hr) 3.04e-011

1.42 45.3

360 54.6

360 0.0755 1.44e+003 Persistence Time: 421 hr (kg/hr) 1000 1000 1000 0



# ( 

# c ( (Koc

10 Log Koc: 1.000 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 4.909E-001

C)

[ HYDROWIN
v1. 67] L/mol-sec Kb Half-Life

at pH 8: 16.341 days Kb Half-Life

at pH 7: 163.415 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 0.500 (BCF

= 3.162) log Kow used: -1.37 (estimated) Volatilization
from Water: Henry LC: 9.54E-025 atm-m3/mole (estimated

by Half-Life from Model River: 1.203E+021 hours Half-Life from Model Lake

: 1.313E+022 hours Bond SAR Method) (5.013E+019 days) (5.469E+020 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.75 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions Air Water Soil Sediment (percent)

(hr) 3.04e-011

1.42 45.3

360 54.6

360 0.0755 1.44e+003 Persistence Time: 421 hr (kg/hr) 1000 1000 1000 0



# ( 

# c (

# Soil Adsorption Coefficient (PCKOCWIN v1.66): Koc 42.97 Log Koc:
1. 633 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg C)

[ HYDROWIN v1.67] Rate constants
can NOT be estimated
for this structure! BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


# = 0.500 (BCF



# = 3.162) log Kow used: -3.31 (estimated) Volatilization
from Water: Henry LC: 5.55E-019 atm-m3/mole (estimated

by Half-Life from Model River: 1.958E+015 hours Half-Life from Model Lake

: 2.136E+016 hours Bond SAR Method) (8.157E+013 days) (8.899E+014 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.75 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) Air 0.000494
0.778 Water 45.4

360 Soil 54.5

360 Sediment 0.0756 1.44e+003 Persistence Time: 420 hr (kg/hr) 1000 1000 1000 0



# c c (

# Log Koc: 1.000 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg C)

[ HYDROWIN vl.67] Rate constants
can NOT be estimated
for this structure! BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 

# 0.500 (BCF


# = 3.162) log Kow used: -4.14 (estimated) Volatilization
from Water: Henry LC: 3.75E-024 atm-m3/mole (estimated

by Bond SAR Method) Half-Life from Model River: 3.061E+020 hours (1.275E+Ol9 days) Half-Life from Model Lake

: 3.339E+021 hours (1.391E+020 days) Removal
In Wastewater Treatment Total removal: Total biodegradation: Total sludge adsorption: Total to Air: Level III Fugacity Model: (recommended maximum 99%): 1.85 percent 0.09 percent 1. 

# 7 5 percent 0.00 percent Mass Amount Half-Life Emissions (percent)

(hr) (kg/hr) Air 6.88e-006

3.87
1000 Water 45.3

360
1000 Soil 54.6

360
1000 Sediment 0.0755

1. 

# 4 4e+003

0 Persistence Time: 421 hr



# c (_ (LogKoc:1.000AqueousBase/Acid-CatalyzedHydrolysis(25degC)[HYDROWINv1.67]RateconstantscanNOTbeestimatedforthisstructure!BCFEstimatefromLogKow(BCFWINv2.15):LogBCF=0.500(BCF=3.162)logKowused:-4.49(estimated)VolatilizationfromWater:HenryLC:3.75E-024atm-m3/mole(estimatedbyBondSARMethod)Half-LifefromModelRiver:3.061E+020hours(1.275E+019days)Half-LifefromModelLake:3.339E+021hours(1.391E+020days)RemovalInWastewaterTreatmentTotalremoval:Totalbiodegradation:Totalsludgeadsorption:TotaltoAir:LevelIIIFugacityModel:(recommendedmaximum99%):1.85percent0.09percent1.75percent0.00percentMassAmountHalf-LifeEmissions(percent)(hr)(kg/hr)Air6.88e-0063.861000Water45.33601000Soil54.63601000Sediment0.07551.44e+0030PersistenceTime:421hr\c(ccLog Koc: 1.000 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg C)

[ HYDROWIN v1.67] Rate constants can NOT be estimated
for this structure! BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


### = 0.500 (BCF



### = 3.162) log Kow used: -4.49 (estimated) Volatilization
from Water: Henry LC: 3.75E-024 atm-m3/mole (estimated

by Bond SAR Method) Half-Life from Model River: 3.061E+020 hours (1.275E+019 days) Half-Life from Model Lake

: 3.339E+021 hours (1.391E+020 days) Removal

In Wastewater Treatment Total removal: Total biodegradation: Total sludge adsorption: Total to Air: Level III Fugacity Model: (recommended maximum 99%): 1.85 percent 0.09 percent 1.75 percent 0.00 percent Mass Amount Half-Life Emissions Air Water Soil Sediment (percent)

(hr) 6.88e-006

3.87 45.3

360 54.6

360 0.0755 1.44e+003 Persistence Time: 421 hr (kg/hr) 1000 1000 1000 0



# ( 

# c (

# Soil Adsorption Coefficient (PCKOCWIN v1.66): Koc 14.55 Log Koc: 1.163 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 4.306E-005 Kb Half-Life

at pH 8: 510.026 years Kb Half-Life

at pH 7: 5100.257 years BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


# = 0.500 (BCF



# = 3.162) log Kow used: -1.99 (estimated) Volatilization
from Water:

C)

[ HYDRO WIN v1

. 67] L/mol-sec Henry LC: 7.04E-021 atm-m3/mole (estimated

by Bond SAR Method) Half-Life from Model River: 1.543E+017 hours (6.431E+015 days) Half-Life from Model Lake

: 1.684E+018 hours (7.015E+016 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.75 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) (kg/hr) Air 1.06e-007
0.683
1000 Water 45.3

360
1000 Soil 54.6

360
1000 Sediment 0.0755 1.44e+003

0 Persistence Time: 421 hr



# (Koc

10 Log Koc:

1 . 0 0 0 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 4.200E-001

C)

[ HYDRO WIN v1. 67] L/mol-sec Kb Half-Life

at pH 8: 19.098 days Kb Half-Life

at pH 7: 190.978 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF



### = 0.500 (BCF



### = 3.162) log Kow used: -2.58 (estimated) Volatilization
from Water: Henry LC: 4.75E-026 atm-m3/mole (estimated

by Half-Life from Model River: 2.417E+022 hours Half-Life from Model Lake

: 2.636E+023 hours Bond SAR Method) (1.007E+021 days) (1.098E+022 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.75 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) Air 1.3e-009

2.07 Water 45.3

360 Soil 54.6

360 Sediment 0.0755 1.44e+003 Persistence Time: 421 hr (kg/hr) 1000 1000 1000 0



# ( 

# c (Koc10LogKoc:1.000AqueousBase/Acid-CatalyzedHydrolysis(25degTotalKbforpH>8at25degC :2.718E-001KbHalf-LifeatpH8:29.511daysKbHalf-LifeatpH7:295.109daysBCFEstimatefromLogKow(BCFWINv2.15):LogBCF=0.500(BCF=3.162)logKowused:-2.58(estimated)VolatilizationfromWater:C)[HYDROWINvl.67]L/mol-secHenryLC:4.75E-026atm-m3/mole(estimatedbyBondSARMethod)Half-LifefromModelRiver:2.417E+022hours(1.007E+021days)Half-LifefromModelLake:2.636E+023hours(1.098E+022days)RemovalInWastewaterTreatmentTotalremoval:Totalbiodegradation:Totalsludgeadsorption:TotaltoAir:LevelIIIFugacityModel:(recommendedmaximum99%):1.85percent0.09percent1.75percent0.00percentMassAmountHalf-LifeEmissionsAirWaterSoilSediment(percent)(hr)1.3e-0092.0745.336054.63600.07551.44e+003PersistenceTime:421hr(kg/hr)1000100010000(cc(Koc

10 Log Koc: 1.000 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 1.550E+OOO

C)

[ HYDROWIN
vl. 67] L/mol-sec Kb Half-Life

at pH 8: 5.176 days Kb Half-Life

at pH 7: 51.759 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


### = 0.500 (BCF



### = 3.162) log Kow used: -2.93 (estimated) Volatilization
from Water: Henry LC: 4.75E-026 atm-m3/mole (estimated

by Half-Life from Model River: 2.417E+022 hours Half-Life from Model Lake

: 2.636E+023 hours Bond SAR Method) (1.007E+021 days) (1.098E+022 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.75 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) Air 1.3e-009

2.07 Water 45.3

360 Soil 54.6

360 Sediment 0.0755 1.44e+003 Persistence Time: 421 hr (kg/hr) 1000 1000 1000 0



# c 

# c (

# Koc



# 10 Log Koc:

1. 

# 000 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg
C

: 2.282E+OOO

C)

[ HYDROWIN
v1. 67] L/mol-sec Kb Half-Life

at pH 8: 3.515 days Kb Half-Life

at pH 7: 35.155 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


# = 0.500 (BCF



# = 3.162) log Kow used: -2.93 (estimated) Volatilization
from Water: Henry LC: 4.75E-026 atrn-m3/mole (estimated

by Half-Life from Model River: 2.417E+022 hours Half-Life from Model Lake

: 2.636E+023 hours Bond SAR Method) (1.007E+021 days) (1.098E+022 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1. 8 5 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.75 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) (kg/hr) Air

1. 

# 3e-009
2.07
1000 Water 45.3

360
1000 Soil 54.6

360
1000 Sediment 0.0755 1.44e+003

0 Persistence Time: 421 hr



# ( 

# c c (

# Koc Log Koc:
10 1.000 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 2.853E-001

C)

[ HYDROWIN

v1

. 67] L/mol-sec Kb Half-Life

at pH 8: 28.118 days Kb Half-Life

at pH 7: 281.179 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


# = 0.500 (BCF



# = 3.162) log Kow used: -2.93 (estimated) Volatilization
from Water: Henry LC: 4.75E-026 atm-m3/mole (estimated

by Half-Life from Model River: 2.417E+022 hours Half-Life from Model Lake

: 2.636E+023 hours Bond SAR Method) (1.007E+021 days) (1.098E+022 days) Removal
In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.75 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions Air Water Soil Sediment (percent)

(hr) 1.3e-009

2.07 45.3

360 54.6

360 0.0755 1.44e+003 Persistence Time: 421 hr (kg/hr) 1000 1000 1000 0



# ( 

# c ( (Koc10LogKoc:1.000AqueousBase/Acid-CatalyzedHydrolysis(25degTotalKbforpH>8at25degC:2.718E-001KbHalf-LifeatpH8:29.511daysKbHalf-LifeatpH7:295.109daysBCFEstimatefromLogKow(BCFWINv2.15):LogBCF=0.500(BCF=3.162)logKowused:-2.93(estimated)VolatilizationfromWater:C)[HYDROWINv1.6"7]L/mol-secHenryLC:4.75E-026atm-m3/mole(estimatedbyBondSARMethod)Half-LifefromModelRiver:2.417E+022hours(1.007E+021days)Half-LifefromModelLake:2.636E+023hours(1.098E+022days)RemovalInWastewaterTreatmentTotalremoval:Totalbiodegradation:Totalsludgeadsorption:TotaltoAir:LevelIIIFugacityModel:(recommendedmaximum99%):1.85percent0.09percent1.75percent0.00percentMassAmountHalf-LifeEmissionsAirWaterSoilSediment(percent)(hr)1.3e-0092.0745.336054.63600.07551.44e+003PersistenceTime:421hr(kg/hr)1000100010000(cSoilAdsorptionCoefficient(PCKOCWINvl.66):Koc226.6LogKoc:2.355AqueousBase/Acid-CatalyzedHydrolysis(25degTotalKbforpH>8at25degC :4.306E-005KbHalf-LifeatpH8:510.026yearsKbHalf-LifeatpH7:5100.257yearsBCFEstimatefromLogKow(BCFWINv2.15):LogBCF=0.500(BCF=3.162)logKowused:0.46(estimated)VolatilizationfromWater:C)[HYDROWINv1.67]L/mol-secHenryLC:1.17E-024atm-m3/mole(estimatedbyBondSARMethod)Half-LifefromModelRiver:1.013E+021hours(4.219E+019days)Half-LifefromModelLake:1.105E+022hours(4.603E+020days)RemovalInWastewaterTreatmentTotalremoval:Totalbiodegradation:Totalsludgeadsorption:TotaltoAir:LevelIIIFugacityModel:(recommendedmaximum99%):1.86percent0.09percent1.77percent0.00percentMassAmountHalf-LifeEmissions(percent)(hr)Air1.18e-0090.478Water41.9208Soil58208Sediment0.0639832PersistenceTime:267hr(kg/hr)1000100010000((Log Koc: 3.354 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 4.200E-001

C)

[ HYDROWIN
v1. 67] L/mol-sec Kb Half-Life

at pH 8: 19.098 days Kb Half-Life

at pH 7: 190.978 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


### = 0.500 (BCF



### = 3.162) log Kow used: 0.08 (estimated) Volatilization
from Water: Henry LC: 5.32E-035 atm-m3/mole (estimated

by Half-Life from Model River: 2.435E+031 hours Half-Life from Model Lake

: 2.656E+032 hours Bond SAR Method) (1.014E+030 days) (1.107E+031 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.76 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) Air 3.6e-014

7.84 Water 49.1

900 Soil 50.8

900 Sediment 0.0916 3.6e+003 Persistence Time: 793 hr (kg/hr) 1000 1000 1000 0



# (

# Log Koc: 3.354 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 2.718E-001

C)

[ HYDROWIN v1. 67] L/mol-sec Kb Half-Life

at pH 8: 29.511 days Kb Half-Life

at pH 7: 295.109 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF



# = 0.500 (BCF



# = 3.162) log Kow used: 0.08 (estimated) Volatilization
from Water: Henry LC: 5.32E-035 atm-m3/mole (estimated

by Half-Life from Model River: 2.435E+031 hours Half-Life from Model Lake

: 2.656E+032 hours Bond 

# SAR Method) (1.014E+030 days) (1.107E+031 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.76 percent Total to Air:

0.00 percent Level III 

# Fugacity Model: Mass Amount Half-Life Emissions Air Water Soil Sediment (percent)

(hr) 3.6e-014

7.84 49.1

900 50.8

900 0.0916 3.6e+003 Persistence Time: 793 hr (kg/hr) 1000 1000 1000 0



# c (Log Koc: 3.354 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 2.718E-001 Kb Half-Life

at pH 8: 29.511 days Kb Half-Life

at pH 7: 295.109 days BCF Estimate from Log Kow **(BC~&IN** v2.15): Log BCF



### = 0.500 (BCF



### = 3.162) log Kow used: 0.08 (estimated) Volatilization
from Water:

C)

[ HYDROWIN
v1. 67] L/mol-sec Henry LC: 5.32E-035 atm-m3/mole (estimated

by Bond SAR Method) Half-Life from Model River:

2. 435E+031 hours

( 1. 014E+030 days) Half-Life from Model Lake

: 2.656E+032 hours (1.107E+031 days) Removal

In Wastewater Treatment Total removal: Total biodegradation: Total sludge adsorption: Total to Air: Level III Fugacity Model: (recommended maximum 99%): 1.85 percent 0.09 percent 1.76 percent 0.00 percent Mass Amount Half-Life Emissions (percent)

(hr) Air 3.6e-014
7.85 Water 49.1

900 Soil 50.8

900 Sediment 0.0916 3.6e+003 Persistence Time: 793 hr (kg/hr) 1000 1000 1000 0



# cLog Koc: 3.354 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 4.200E-001

C)

[ HYDROWIN
vl. 67] L/mol-sec Kb Half-Life

at pH 8: 19.098 days Kb Half-Life

at pH 7: 190.978 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


### = 0.500 (BCF



### = 3.162) log Kow used: 0.08 (estimated) Volatilization
from Water: Henry LC: 5.32E-035 atm-m3/mole (estimated

by Half-Life from Model River: 2.435E+031 hours Half-Life from Model Lake

: 2.656E+032 hours Bond SAR Method) (1.014E+030 days) (1.107E+031 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.76 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) Air 3.6e-014

7.85 Water 49.1

900 Soil 50.8

900 Sediment 0.0916 3.6e+003 Persistence Time: 793 hr (kg/hr) 1000 1000 1000 0

# Log Koc: 3.354 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 4.200E-001 Kb Half-Life

at pH 8: 19.098 days Kb Half-Life

at pH 7: 190.978 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF



# = 0.500 (BCF



# = 3.162) log Kow used: -0.26 (estimated) Volatilization
from Water:

C)

[ HYDROWIN
vl. 67] L/mol-sec Henry LC: 5.32E-035 atm-m3/mole (estimated

by Bond SAR Method) Half-Life from Model River: 2.435E+031 hours (l.Ol4E+030 days) Half-Life from Model Lake

: 2.656E+032 hours (l.l07E+031 days) Removal

In Wastewater Treatment Total removal: Total biodegradation: Total sludge adsorption: Total to Air: Level III Fugacity Model: (recommended maximum 99%): 1.85 percent 0.09 percent 1.76 percent 0.00 percent Mass Amount Half-Life Emissions (percent)

(hr) (kg/hr) Air 3.62e-014

7.84
1000 Water 49.5

900
1000 Soil 50.4

900
1000 Sediment 0.0917 3.6e+003

0 Persistence Time: 791 hr



# ( 

# c c (

# Log Koc: 3.354 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 2.718E-001

C)

[ HYDROWIN
v1. 67] L/mol-sec Kb Half-Life

at pH 8: 29.511 days Kb Half-Life

at pH 7: 295.109 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 

# 0.500 (BCF

= 

# 3.162) log Kow used: -0.26 (estimated) Volatilization
from Water: Henry LC: 5.32E-035 atm-m3/mole (estimated

by Half-Life from Model River: 2.435E+031 hours Half-Life from Model Lake

: 2.656E+032 hours Bond SAR Method) (1.014E+030 days) (1.107E+031 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.76 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) (kg/hr) Air 3.62e-014

7.84
1000 Water 49.5

900
1000 Soil 50.4

900
1000 Sediment 0.0917 3.6e+003

0 Persistence Time:

7 91 hr



# ( 

# ( 

# c (Log Koc: 3.354 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total Kb for pH>

8 at 25 deg C : 2.282E+OOO

C)

[ HYDROWIN
vl. 67] L/mol-sec Kb Half-Life

at pH 8: 3.515 days Kb Half-Life

at pH 7: 35.155 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


## = 0.500 (BCF

= 3.162) log Kow used: -0.60 (estimated) Volatilization
from Water: Henry LC: 5.32E-035 atm-m3/mole (estimated

by Half-Life from Model River: 2.435E+031 hours Half-Life from Model Lake

: 2.656E+032 hours Bond SAR Method) (1.014E+030 days) (1.107E+031 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.76 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass **~mount** Half-Life Emissions 

### Air Water Soil Sediment (percent)

(hr) 3.62e-014

7.84 49.7

900 50.2

900 0.0918 3.6e+003 Persistence Time: 790 hr (kg/hr) 1000 1000 1000 0



# c c (Log Koc: 3.354 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 2.282E+OOO Kb Half-Life

at pH 8: 3.515 days Kb Half-Life

at pH 7: 35.155 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


### = 0.500 (BCF



### = 3.162) log Kow used: -0.26 (estimated) Volatilization
from Water:

C)

[ HYDROWIN
v1. 67] L/mol-sec Henry LC: 5.32E-035 atm-m3/mole (estimated

by Bond SAR Method) Half-Life from Model River: 2.435E+031 hours (1.014E+030 days) Half-Life from Model Lake

: 2.656E+032 hours (1.107E+031 days) Removal
In Wastewater Treatment Total removal: Total biodegradation: Total sludge adsorption: Total to Air: Level III Fugacity Model: (recommended maximum 99%): 1.85 percent 0.09 percent 1.76 percent 0.00 percent Mass Amount Half-Life Emissions (percent)

(hr) (kg/hr) Air 3.62e-014

7.85
1000 Water 49.5

900
1000 Soil 50.4

900
1000 Sediment 0.0917 3.6e+003

0 Persistence Time: 791 hr



# (Log Koc: 3.354 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 2.282E+OOO

C)

[ HYDROWIN
vl. 67] L/mol-sec Kb Half-Life

at pH 8: 3.515 days Kb Half-Life

at pH 7: 35.155 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


### = 0.500 (BCF



### = 3.162) log Kow used: -0.26 (estimated) Volatilization
from Water: Henry LC: 5.32E-035 atm-m3/mole (estimated

by Half-Life from Model River: 2.435E+031 hours Half-Life from Model Lake

: 2.656E+032 hours Bond SAR Method) (1.014E+030 days) (1.107E+031 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.85 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.76 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) Air 3.62e-014

7.84 Water 49.5

900 Soil 50.4

900 Sediment 0.0917 3.6e+003 Persistence Time: 791 hr (kg/hr) 1000 1000 1000 0



# ( (Soil Adsorption Coefficient (PCKOCWIN v1.66): Koc 457.1 Log Koc: 2.660 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 4.306E-005 Kb Half-Life

at pH 8: 510.026 years Kb Half-Life

at pH 7: 5100.257 years BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF



### = 0.500 (BCF



### = 3.162) log Kow used: 0.44 (estimated) Volatilization
from Water:

C)

[ HYDROWIN
v1. 67] L/mol-sec Henry LC: 7.89E-030 atm-m3/mole (estimated

by Bond SAR Method) Half-Life from Model River: 1.573E+026 hours (6.555E+024 days) Half-Life from Model Lake

: 1.716E+027 hours (7.151E+025 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.86 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.77 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) (kg/hr) Air 6.48e-012 0.915
1000 Water 44.2

360
1000 Soil 55.7

360
1000 Sediment 0.0754 1.44e+003

0 Persistence Time: 423 hr



# (SoilAdsorptionCoefficient(PCKOCWINv1.66):Koc457.1LogKoc:2.660AqueousBase/Acid-CatalyzedHydrolysis(25degTotalKbforpH>8at25degC :4.306E-005C)[HYDROWINvl.67]L/mol-secKbHalf-LifeatpH8:510.026yearsKbHalf-LifeatpH7:5100.257yearsBCFEstimatefromLogKow(BCFWINv2.15):LogBCF=0.500(BCF=3.162)logKowused:0.10(estimated)VolatilizationfromWater:HenryLC:7.89E-030atm-m3/mole(estimatedbyHalf-LifefromModelRiver:1.573E+026hoursHalf-LifefromModelLake:1.716E+027hoursBondSARMethod)(6.555E+024days)(7.151E+025days)RemovalInWastewaterTreatmentTotalremoval:(recommendedmaximum99%):1.85percentTotalbiodegradation:0.09percentTotalsludgeadsorption:1.76percentTotaltoAir:0.00percentLevelIIIFugacityModel:MassAmountHalf-LifeEmissionsAirWaterSoilSediment(percent)(hr)6.5e-0120.91544.836055.13600.07551.44e+003PersistenceTime:422hr(kg/hr)1000100010000c(

# Soil Adsorption Coefficient (PCKOCWIN vl.66): Koc 1119 Log Koc: 3.049 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total Kb for pH>

8 at 25 deg C : 4.200E-001

C)

[ HYDROWIN vl. 67] L/mol-sec Kb Half-Life

at pH 8: 19.098 days Kb Half-Life

at pH 7: 190.978 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF

= 

# 0.500 (BCF

= 

# 3.162) log Kow used: 0.68 (estimated) Volatilization
from Water: Henry LC: 7.89E-030 atm-m3/mole (estimated

by Half-Life from Model River: 1.573E+026 hours Half-Life from Model Lake

: 1.716E+027 hours Bond SAR Method) (6.555E+024 days) (7.151E+025 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1 . 8 7 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.77 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions Air Water Soil Sediment (percent)

(hr) 6.46e-012 0.888 43.5

360 56.5

360 0.0754 1.44e+003 Persistence Time: 424 hr (kg/hr) 1000 1000 1000 0



# c (_Soil Adsorption Coefficient (PCKOCWIN v1.66): Koc 1119 Log Koc: 3.049 Aqueous Base/Acid-Catalyzed Hydrolysis

(25 deg Total
Kb for pH>

8 at 25 deg C : 2.282E+OOO

C)

[ HYDROWIN
v1. 67] L/mol-sec Kb Half-Life

at pH 8: 3.515 days Kb Half-Life

at pH 7: 35.155 days BCF Estimate from Log Kow (BCFWIN v2.15): Log BCF


### = 0.500 (BCF



### = 3.162) log Kow used: 0.34 (estimated) Volatilization
from Water: Henry LC: 7.89E-030 atm-m3/mole (estimated

by Half-Life from Model River: 1.573E+026 hours Half-Life from Model Lake

: 1.716E+027 hours Bond SAR Method) (6.555E+024 days) (7.151E+025 days) Removal

In Wastewater Treatment Total removal: (recommended maximum 99%): 1.86 percent Total biodegradation:

0.09 percent Total sludge adsorption:

1.76 percent Total to Air:

0.00 percent Level III Fugacity Model: Mass Amount Half-Life Emissions (percent)

(hr) (kg/hr) Air 6.49e-012
0.888
1000 Water 44.4

360
1000 Soil 55.5

360
1000 Sediment 0.0754

1. 44e+003

0 Persistence Time: 422 hr



# (SoilAdsorptionCoefficient(PCKOCWINvl.66):Koc1119LogKoc:3.049AqueousBase/Acid-CatalyzedHydrolysis(25degTotalKbforpH>8at25degC:2.718E-001C)[HYDROWINv1.67]L/mol-secKbHalf-LifeatpH8:29.511daysKbHalf-LifeatpH7:295.109daysBCFEstimatefromLogKow(BCFWINv2.15):LogBCF=0.500(BCF=3.162)logKowused:0.68(estimated)VolatilizationfromWater:HenryLC:7.89E-030atm-m3/mole(estimatedbyHalf-LifefromModelRiver:1.573E+026hoursHalf-LifefromModelLake:1.716E+027hoursBondSARMethod)(6.555E+024days)(7.151E+025days)RemovalInWastewaterTreatmentTotalremoval:(recommendedmaximum99%):1.87percentTotalbiodegradation:0.09percentTotalsludgeadsorption:1.77percentTotaltoAir:0.00percentLevelIIIFugacityModel:MassAmountHalf-LifeEmissions(percent)(hr)(kg/hr)Air6.46e-0120.8881000Water43.53601000Soil56.53601000Sediment0.07541.44e+0030PersistenceTime:424hr(cc