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Results and Discussion

Based on the 11 narrow standards of PMMA, MMA and 1-Phenylhexane, a 4th order calibration curve 

and one equation were generated by the software. Figure 1 shows the calibration curve, and the raw 

data and the calibration equation were also listed. Sample chromatogram and the results are shown in 

Figure 2 & Figure 3. Table 2 lists slice data for Amix 1000 product and Table 3 lists slice data for 

PolyethyleneAmine E100 product.

Log Mol Wt

2.00

2.50

3.00

3.50

4.00

4.50

5.00

5.50

6.00

Retention Time

12.50 13.00 13.50 14.00 14.50 15.00 15.50 16.00 16.50 17.00 17.50 18.00 18.50 19.00 19.50

Retention Time Mol Wt Log Mol Wt

12.49 1916000 6.28

13.11 625500 5.80

14.26 138600 5.14

15.00 52550 4.72

15.55 27600 4.44

16.30 10290 4.01

16.90 5000 3.70

17.41 2810 3.45

18.49 645 2.81

19.28 162 2.21

19.86 100 2.00

Calibration Method: System 3_Plgel_THFN_102814_PMMA

y = 0.00150696x4- 0.10100046x3 + 2.51549408x2- 28.14848748x + 125.55486179

R2 = 0.99932510

Figure 1. The calibration curve of the standards, the raw data and the calibration equation.
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TS-DL13Y4 GPC Data.doc 

3 MV

0.00

20.00

40.00

60.00

80.00

100.00

120.00

140.00

160.00

180.00

200.00

220.00

240.00

260.00

Minutes

11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00 19.00 20.00 21.00

Label Sample Name Mn Mw MP Mz Mz+1 Polydispersity Mz/Mw Mz+1/Mw

U10271429 33264R38(01) PolyethyleneAmine 

E100 391 668 812 999 1324 1.71 1.50 1.98

Figure 2. The GPC chromatogram of TS-DL13Y4 PolyethyleneAmine E 100 & Fatty acids product 

and the average molecular weight. 

 Table 2. Slice Data for TS-DL13Y4 (FA & PolyethyleneAmine E100 product)

Slice 

No.

Slice 

MW Slice Log MW Slice EV Slice Area Cumulative %

1 4238 3.63 17.05 0 0

2 4146 3.62 17.07 88 0

3 4055 3.61 17.08 205 0

4 3966 3.60 17.10 326 0

5 3879 3.59 17.12 466 0

6 3793 3.58 17.13 634 0

7 3710 3.57 17.15 835 0

8 3628 3.56 17.17 1049 0

9 3548 3.55 17.18 1297 0

10 3469 3.54 17.20 1577 0

11 3392 3.53 17.22 1904 0

12 3317 3.52 17.23 2288 0

13 3244 3.51 17.25 2718 0

14 3172 3.50 17.27 3204 0

15 3101 3.49 17.28 3761 0

16 3032 3.48 17.30 4387 0

17 2964 3.47 17.32 5103 0

18 2898 3.46 17.33 5917 0

19 2833 3.45 17.35 6829 0

Slice 

No.

Slice 

MW Slice Log MW Slice EV Slice Area Cumulative %

20 2770 3.44 17.37 7858 0
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21 2708 3.43 17.38 9019 0

22 2647 3.42 17.40 10319 0

23 2588 3.41 17.42 11765 0

24 2530 3.40 17.43 13370 0

25 2473 3.39 17.45 15148 0

26 2417 3.38 17.47 17118 1

27 2363 3.37 17.48 19271 1

28 2309 3.36 17.50 21625 1

29 2257 3.35 17.52 24194 1

30 2206 3.34 17.53 26998 1

31 2156 3.33 17.55 30035 1

32 2107 3.32 17.57 33302 1

33 2060 3.31 17.58 36816 1

34 2013 3.30 17.60 40575 2

35 1967 3.29 17.62 44595 2

36 1922 3.28 17.63 48868 2

37 1879 3.27 17.65 53412 2

38 1836 3.26 17.67 58219 2

39 1794 3.25 17.68 63307 3

40 1753 3.24 17.70 68666 3

41 1713 3.23 17.72 74310 3

42 1674 3.22 17.73 80231 4

43 1636 3.21 17.75 86437 4

44 1598 3.20 17.77 92924 4

45 1562 3.19 17.78 99674 5

46 1526 3.18 17.80 106680 5

47 1491 3.17 17.82 113926 6

48 1457 3.16 17.83 121387 6

49 1423 3.15 17.85 129030 7

50 1391 3.14 17.87 136828 8

51 1359 3.13 17.88 144724 8

52 1327 3.12 17.90 152676 9

53 1297 3.11 17.92 160637 9

54 1267 3.10 17.93 168566 10

55 1238 3.09 17.95 176392 11

56 1209 3.08 17.97 184063 12

57 1181 3.07 17.98 191529 13

58 1154 3.06 18.00 198723 13

59 1127 3.05 18.02 205598 14

60 1101 3.04 18.03 212090 15

61 1076 3.03 18.05 218156 16

62 1051 3.02 18.07 223740 17

63 1027 3.01 18.08 228790 18

64 1003 3.00 18.10 233283 19

65 980 2.99 18.12 237186 20

66 957 2.98 18.13 240481 21

67 935 2.97 18.15 243181 22

Slice 

No.

Slice 

MW Slice Log MW Slice EV Slice Area Cumulative %

68 913 2.96 18.17 245315 23

69 892 2.95 18.18 246906 24
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70 871 2.94 18.20 248020 25

71 851 2.93 18.22 248712 27

72 831 2.92 18.23 249053 28

73 812 2.91 18.25 249109 29

74 793 2.90 18.27 248954 30

75 775 2.89 18.28 248644 31

76 757 2.88 18.30 248241 32

77 739 2.87 18.32 247796 33

78 722 2.86 18.33 247323 34

79 705 2.85 18.35 246854 35

80 689 2.84 18.37 246399 36

81 673 2.83 18.38 245968 37

82 657 2.82 18.40 245532 38

83 642 2.81 18.42 245087 39

84 627 2.80 18.43 244609 40

85 613 2.79 18.45 244098 41

86 598 2.78 18.47 243518 43

87 585 2.77 18.48 242876 44

88 571 2.76 18.50 242126 45

89 558 2.75 18.52 241274 46

90 545 2.74 18.53 240300 47

91 532 2.73 18.55 239199 48

92 520 2.72 18.57 237977 49

93 508 2.71 18.58 236591 50

94 496 2.70 18.60 235050 51

95 485 2.69 18.62 233346 52

96 473 2.68 18.63 231450 53

97 462 2.67 18.65 229361 54

98 452 2.65 18.67 227072 55

99 441 2.64 18.68 224572 56

100 431 2.63 18.70 221856 57

101 421 2.62 18.72 218926 58

102 411 2.61 18.73 215780 59

103 402 2.60 18.75 212442 59

104 393 2.59 18.77 208930 60

105 384 2.58 18.78 205269 61

106 375 2.57 18.80 201459 62

107 366 2.56 18.82 197540 63

108 358 2.55 18.83 193542 64

109 350 2.54 18.85 189474 65

110 342 2.53 18.87 185382 65

111 334 2.52 18.88 181267 66

112 326 2.51 18.90 177171 67

113 319 2.50 18.92 173098 68

114 311 2.49 18.93 169082 68

115 304 2.48 18.95 165130 69

Slice 

No.

Slice 

MW Slice Log MW Slice EV Slice Area Cumulative %

116 297 2.47 18.97 161268 70

117 291 2.46 18.98 157481 71

118 284 2.45 19.00 153792 71
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119 278 2.44 19.02 150187 72

120 271 2.43 19.03 146685 72

121 265 2.42 19.05 143291 73

122 259 2.41 19.07 139995 74

123 253 2.40 19.08 136788 74

124 248 2.39 19.10 133670 75

125 242 2.38 19.12 130636 75

126 237 2.37 19.13 127678 76

127 231 2.36 19.15 124803 77

128 226 2.35 19.17 121994 77

129 221 2.34 19.18 119255 78

130 216 2.33 19.20 116573 78

131 211 2.33 19.22 113951 79

132 207 2.32 19.23 111376 79

133 202 2.31 19.25 108871 80

134 198 2.30 19.27 106418 80

135 193 2.29 19.28 104002 80

136 189 2.28 19.30 101651 81

137 185 2.27 19.32 99348 81

138 181 2.26 19.33 97091 82

139 177 2.25 19.35 94877 82

140 173 2.24 19.37 92713 83

141 169 2.23 19.38 90597 83

142 165 2.22 19.40 88532 83

143 162 2.21 19.42 86514 84

144 158 2.20 19.43 84534 84

145 155 2.19 19.45 82600 84

146 152 2.18 19.47 80713 85

147 148 2.17 19.48 78868 85

148 145 2.16 19.50 77061 85

149 142 2.15 19.52 75296 86

150 139 2.14 19.53 73587 86

151 136 2.13 19.55 71920 86

152 133 2.12 19.57 70281 87

153 130 2.12 19.58 68694 87

154 128 2.11 19.60 67153 87

155 125 2.10 19.62 65655 88

156 122 2.09 19.63 64180 88

157 120 2.08 19.65 62738 88

158 117 2.07 19.67 61347 88

159 115 2.06 19.68 59993 89

160 112 2.05 19.70 58673 89

161 110 2.04 19.72 57385 89

162 108 2.03 19.73 56125 89

163 106 2.02 19.75 54899 90

Slice 

No.

Slice 

MW Slice Log MW Slice EV Slice Area Cumulative %

164 103 2.01 19.77 53690 90

165 101 2.01 19.78 52515 90

166 99 2.00 19.80 51372 90

167 97 1.99 19.82 50244 90
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168 95 1.98 19.83 49138 91

169 93 1.97 19.85 48057 91