August 22nd, 2011 

Ms. Sharon Leitch 

EPA New England, Region 1 

5 Post Office Square 

Suite 100 (OSRR07-1) 

Boston, MA 02109-3912 

Reference: Quality Assurance Project Plan (QAPP) For IBM Essex Junction, VT Industrial 

Wastewater Sludge De-Listing (approved on 01/27/2011) 

Subject: Submission of Analytical Results as Outlined in the above referenced QAPP 

Dear Ms. Leitch: 

The IBM Corporation, Essex Junction, VT semiconductor manufacturing facility 

(VTD002084705) is providing the analytical results required by the approved Quality Assurance 

Project Plan For IBM Essex Junction, VT Industrial Wastewater Sludge De-Listing. These 

analytical results are being provided to EPA Region 1, so the evaluation phase of the federal 

delisting process for IBM’s F006 Industrial Wastewater Treatment (IWTP) sludge can be 

completed. 

As you indicated in your note to Candice Callahan, of my staff, on March 8th, 2011, when an 

analytical result of less than the detection limit was reported, half of the detection limit was used 

in our calculations. The minimum, average, and maximum values reported in Attachment A are 

calculated based on this assumption, when applicable. 

If you have any questions concerning this information, please contact one of the following 

members of my staff: 

Candice Callahan by telephone at 769-0579 or electronically at ccallaha@us.ibm.com 

David Kost by telephone at 769-2761 or electronically at dlkost@us.ibm.com

Sincerely, 

Tim Baechle 

Manager of Energy, Environmental, and Chemical Programs 
Attachments: 

Attachment A: Summary of Analytical Results 

Attachment B: Annual Sludge Disposal Volumes (2003 through 2010) 

Attachment C: Summary of Detection Limits for Each Parameter for Each Sample Set 

Attachment D: Analytical Laboratory Reports and Laboratory QC Reports for Each 

Sample Set 
ATTACHMENT A 
Summary of Analytical Results - TCLP Volatiles and TCLP Semi-Volatiles

Method Paramater 6/8/11 Result (ug/l) 6/14/11 Result (ug/l)

6/14/11 

Duplicate 

Sample 

Result (ug/l)

6/21/11 Result 

(ug/l)

6/28/11 Result 

(ug/l)

Minimum 

(ug/l)

TCLP VOLATILES

EPA 8260B Vinyl chloride, TCLP < 20 < 20 < 20 < 20 < 20 10 EPA 8260B 1,1-Dichloroethene, TCLP < 10 < 10 < 10 < 10 < 10 5 EPA 8260B 2-Butanone, TCLP < 100 < 100 < 100 < 100 < 100 50 EPA 8260B Chloroform, TCLP < 10 < 10 < 10 < 10 < 10 5 EPA 8260B Carbon tetrachloride, TCLP < 10 < 10 < 10 < 10 < 10 5 EPA 8260B Benzene, TCLP < 10 < 10 < 10 < 10 < 10 5 EPA 8260B 1,2-Dichloroethane, TCLP < 10 < 10 < 10 < 10 < 10 5 EPA 8260B Trichloroethene, TCLP < 10 < 10 < 10 < 10 < 10 5 EPA 8260B Tetrachloroethene, TCLP < 10 < 10 < 10 < 10 < 10 5 EPA 8260B Chlorobenzene, TCLP < 10 < 10 < 10 < 10 < 10 5 EPA 8260B 1,4-Dichlorobenzene, TCLP < 10 < 10 < 10 < 10 < 10 5 

TCLP SEMI-VOLATILES

EPA 8270C Pyridine, TCLP < 100 < 100 < 100 < 100 < 100 50 EPA 8270C Hexachloroethane, TCLP < 50 < 50 < 50 < 50 < 50 25 EPA 8270C Nitrobenzene, TCLP < 50 < 50 < 50 < 50 < 50 25 EPA 8270C Hexachlorobutadiene, TCLP < 50 < 50 < 50 < 50 < 50 25 EPA 8270C 2,4-Dinitrotoluene, TCLP < 50 < 50 < 50 < 50 < 50 25 EPA 8270C Hexachlorobenzene, TCLP < 50 < 50 < 50 < 50 < 50 25 EPA 8270C Cresols, Total TCLP < 100 < 100 < 100 < 100 < 100 50 EPA 8270C 2,4,5-Trichlorophenol, TCLP < 100 < 100 < 100 < 100 < 100 50 EPA 8270C 2,4,6-Trichlorophenol, TCLP < 100 < 100 < 100 < 100 < 100 50 EPA 8270C Pentachlorophenol, TCLP < 200 < 200 < 200 < 200 < 200 100 

** All values below detection limits are calculated at 1/2 of detection limit
Summary of Analytical Results - Total Volatiles and Total Semi-Volatiles

Method Paramater 6/8/11 Result (ug/Kg,Dry) 6/14/11 Result (ug/Kg,Dry)

6/14/11 

Duplicate 

Sample 

Result 

(ug/Kg,Dry)

6/21/11 Result 

(ug/Kg,Dry)

6/28/11 Result 

(ug/Kg,Dry)

Minimum (ug/Kg,Dr

 VOLATILES

EPA 8260B Vinyl chloride < 188 < 120 < 126 < 134 < 108 54.0 EPA 8260B 1,1-Dichloroethene < 94 < 60 < 63 < 67 < 54 27.0 EPA 8260B 2-Butanone < 940 < 600 < 630 < 670 < 540 270.0 EPA 8260B Chloroform < 94 144 155 < 67 < 54 27.0 EPA 8260B Carbon tetrachloride < 94 < 60 < 63 < 67 < 54 27.0 EPA 8260B Benzene < 94 < 60 < 63 < 67 < 54 27.0 EPA 8260B 1,2-Dichloroethane < 94 < 60 < 63 < 67 < 54 27.0 EPA 8260B Trichloroethene < 94 < 60 < 63 < 67 < 54 27.0 EPA 8260B Tetrachloroethene < 94 < 60 < 63 < 67 < 54 27.0 EPA 8260B Chlorobenzene < 94 < 60 < 63 < 67 < 54 27.0 EPA 8260B 1,4-Dichlorobenzene < 94 < 60 < 63 < 67 < 54 27.0 

 SEMI-VOLATILES

EPA 8270C Pyridine < 1050 < 770 < 800 < 830 < 840 385.0 EPA 8270C Hexachloroethane < 525 < 385 < 400 < 415 < 420 192.5 EPA 8270C Nitrobenzene < 525 < 385 < 400 < 415 < 420 192.5 EPA 8270C Hexachlorobutadiene < 525 < 385 < 400 < 415 < 420 192.5 EPA 8270C 2,4-Dinitrotoluene < 525 < 385 < 400 < 415 < 420 192.5 EPA 8270C Hexachlorobenzene < 525 < 385 < 400 < 415 < 420 192.5 EPA 8270C Cresols, Total < 1050 < 770 < 800 < 830 < 840 385.0 EPA 8270C 2,4,5-Trichlorophenol < 1050 < 770 < 800 < 830 < 840 385.0 EPA 8270C 2,4,6-Trichlorophenol < 1050 < 770 < 800 < 830 < 840 385.0 EPA 8270C Pentachlorophenol < 2100 < 1540 < 1600 < 1660 < 1680 770.0 

** All values below detection limits are calculated at 1/2 of detection limit
Summary of Analytical Results - TCLP Metals

Method Paramater 6/8/11 Result (mg/l) 6/14/11 Result (mg/l)

6/14/11 

Duplicate 

Sample 

Result (mg/l)

6/21/11 

Result (mg/l)

6/28/11 

Result (mg/l)

Minimum *

(mg/l)

EPA 6010B Arsenic, Total TCLP < 0.2 < 0.2 < 0.2 < 0.2 < 0.2 0.1 EPA 6010B Barium, Total TCLP < 0.2 < 0.2 < 0.2 < 0.2 < 0.2 0.1 EPA 6010B Cadmium, Total TCLP < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 0.01 EPA 6010B Chromium, Total TCLP < 0.05 < 0.05 < 0.05 < 0.05 < 0.05 0.025 EPA 6010B Lead, Total TCLP < 0.2 < 0.2 < 0.2 < 0.2 < 0.2 0.1 EPA 7470 Mercury, Total TCLP < 0.01 < 0.01 < 0.01 < 0.01 < 0.01 0.005 EPA 6010B Nickel, Total TCLP 0.11 < 0.10 < 0.10 < 0.10 < 0.10 0.05 SM19 3113B Selenium, Total TCLP < 0.02 < 0.02 < 0.02 < 0.02 < 0.02 0.01 EPA 6010B Silver, Total TCLP < 0.2 < 0.2 < 0.2 < 0.2 < 0.2 0.1 ** All values below detection limits are calculated at 1/2 of detection limit
Summary of Analytical Results - Total Metals and Percent Solids

Method Paramater 6/8/11 Result (mg/Kg, dry) 6/14/11 Result (mg/Kg, dry)

6/14/11 

Duplicate 

Sample 

Result 

(mg/Kg, dry)

6/21/11 

Result 

(mg/Kg, dry)

6/28/11 

Result 

(mg/Kg, dry)

Min

(mg

SM18 2540G Solids, Total (%) 31.4 42.6 41.4 39.0 39.8 EPA 7196A Chromium, Hexavalent (mg/Kg) < 10 < 10 < 10 < 10 < 10 EPA 9012A Cyanide, Total < 4 < 4 < 4 < 3 < 3 SM 4500-CN G Cyanide, Total Amenable < 4 < 4 < 4 < 3 < 3 EPA 6010B Aluminum, Total 8,400 9,800 13,000 14,000 15,000 8EPA 6010B Arsenic, Total < 13 < 4.7 6.8 7.5 < 9.0 EPA 6010B Barium, Total 39 27 36 34 36 EPA 6010B Cadmium, Total < 1.30 < 0.47 < 0.57 < 0.51 < 0.90 0EPA 6010B Chromium, Total 290 180 240 280 240 EPA 6010B Copper, Total 680 670 830 1,200 960 EPA 6010B Iron, Total 7,400 7,900 10,000 9,100 9,800 7EPA 6010B Lead, Total < 13.0 < 4.7 < 5.7 5.6 < 9.0 EPA 7471A Mercury, Total < 0.062 < 0.093 < 0.082 0.067 < 0.056 0EPA 6010B Nickel, Total 36 24 31 49 38 EPA 7010 Selenium, Total < 3.2 < 1.2 < 1.2 < 1.3 < 2.2 EPA 6010B Silver, Total < 13.0 < 4.7 < 5.7 < 5.1 < 9.0 EPA 6010B Zinc, Total 780 530 680 930 810 ICP-OES Platinum, Total (ug/g) < 5.0 < 5.0 < 5.0 < 5.0 < 5.0 ICP-OES Tin, Total (ug/g) < 5.0 < 5.0 < 5.0 < 5.0 5.0 ** All values below detection limits are calculated at 1/2 of detection limit
ATTACHMENT B 
Annual Sludge Disposal Volumes (2003 through 2010)

Year Sludge Shipped (tons) Estimated Sludge 

Volume (cubic yards)

2010 2344.34 2700

2009 2387.89 2750

2008 2379.33 2750

2007 2652.68 3050

2006 2732.60 3150

2005 2555.40 2950

2004 2539.48 2900

2003 2354.00 2700

Minimum 2344.34 2700

Average 2493.22 2869

Maximum 2732.60 3150
ATTACHMENT C 
Summary of Detection Limits for Each Parameter for Each Sample Set - TCLP Volatiles and TCLP Semi-V

Method Paramater

6/8/11 

Analytical 

Detection 

Limit (ug/l)

6/14/11 

Analytical 

Detection 

Limit (ug/l)

6/14/11 

Duplicate 

Sample 

Analytical 

Detection 

Limit (u

g/l)

6/21/11 

Analytical 

Detection 

Limit (ug/l)

TCLP VOLATILES

EPA 8260B Vinyl chloride, TCLP 20 20 20 20 EPA 8260B 1,1-Dichloroethene, TCLP 10 10 10 10 EPA 8260B 2-Butanone, TCLP 100 100 100 100 EPA 8260B Chloroform, TCLP 10 10 10 10 EPA 8260B Carbon tetrachloride, TCLP 10 10 10 10 EPA 8260B Benzene, TCLP 10 10 10 10 EPA 8260B 1,2-Dichloroethane, TCLP 10 10 10 10 EPA 8260B Trichloroethene, TCLP 10 10 10 10 EPA 8260B Tetrachloroethene, TCLP 10 10 10 10 EPA 8260B Chlorobenzene, TCLP 10 10 10 10 EPA 8260B 1,4-Dichlorobenzene, TCLP 10 10 10 10 

TCLP SEMI-VOLATILES

EPA 8270C Pyridine, TCLP 100 100 100 100 EPA 8270C Hexachloroethane, TCLP 50 50 50 50 EPA 8270C Nitrobenzene, TCLP 50 50 50 50 EPA 8270C Hexachlorobutadiene, TCLP 50 50 50 50 EPA 8270C 2,4-Dinitrotoluene, TCLP 50 50 50 50 EPA 8270C Hexachlorobenzene, TCLP 50 50 50 50 EPA 8270C Cresols, Total TCLP 100 100 100 100 EPA 8270C 2,4,5-Trichlorophenol, TCLP 100 100 100 100 EPA 8270C 2,4,6-Trichlorophenol, TCLP 100 100 100 100 EPA 8270C Pentachlorophenol, TCLP 200 200 200 200 
Summary of Detection Limits for Each Parameter for Each Sample Set - Total Volatiles and Total Semi-V

Method Paramater

6/8/11 

Analytical 

Detection 

Limit 

(ug/Kg,Dry)

6/14/11 

Analytical 

Detection 

Limit 

(ug/Kg,Dry)

6/14/11 

Duplicate 

Sample 

Analytical 

Detection 

Limit 

(u

g/Kg,Dry)

6/21/11 

Analytical 

Detection 

Limit 

(ug/Kg,Dry)

(

 VOLATILES

EPA 8260B Vinyl chloride 188 120 126 134 EPA 8260B 1,1-Dichloroethene 94 60 63 67 EPA 8260B 2-Butanone 940 600 630 670 EPA 8260B Chloroform 94 60 63 67 EPA 8260B Carbon tetrachloride 94 60 63 67 EPA 8260B Benzene 94 60 63 67 EPA 8260B 1,2-Dichloroethane 94 60 63 67 EPA 8260B Trichloroethene 94 60 63 67 EPA 8260B Tetrachloroethene 94 60 63 67 EPA 8260B Chlorobenzene 94 60 63 67 EPA 8260B 1,4-Dichlorobenzene 94 60 63 67 

 SEMI-VOLATILES

EPA 8270C Pyridine 1050 770 800 830 EPA 8270C Hexachloroethane 525 385 400 415 EPA 8270C Nitrobenzene 525 385 400 415 EPA 8270C Hexachlorobutadiene 525 385 400 415 EPA 8270C 2,4-Dinitrotoluene 525 385 400 415 EPA 8270C Hexachlorobenzene 525 385 400 415 EPA 8270C Cresols, Total 1050 770 800 830 EPA 8270C 2,4,5-Trichlorophenol 1050 770 800 830 EPA 8270C 2,4,6-Trichlorophenol 1050 770 800 830 EPA 8270C Pentachlorophenol 2100 1540 1600 1660 
Summary of Detection Limits for Each Parameter for Each Sample Set - TCLP Metals

Method Paramater

6/8/11 

Analytical 

Detection 

Limit (mg/l)

6/14/11 

Analytical 

Detection 

Limit (mg/l)

6/14/11 

Duplicate 

Sample 

Analytical 

Detection 

Limit (m

g/l)

6/21/11 

Analytical 

Detection 

Limit (mg/l)

6/28

Anal

Dete

Limit 

EPA 6010B Arsenic, Total TCLP 0.2 0.2 0.2 0.2 0EPA 6010B Barium, Total TCLP 0.2 0.2 0.2 0.2 0EPA 6010B Cadmium, Total TCLP 0.02 0.02 0.02 0.02 0.EPA 6010B Chromium, Total TCLP 0.05 0.05 0.05 0.05 0.EPA 6010B Lead, Total TCLP 0.2 0.2 0.2 0.2 0EPA 7470 Mercury, Total TCLP 0.01 0.01 0.01 0.01 0.EPA 6010B Nickel, Total TCLP 0.1 0.10 0.10 0.10 0.SM19 3113B Selenium, Total TCLP 0.02 0.02 0.02 0.02 0.EPA 6010B Silver, Total TCLP 0.2 0.2 0.2 0.2 0
Summary of Detection Limits for Each Parameter for Each Sample Set - Total Metals and Percent So

Method Paramater

6/8/11 

Analytical 

Detection 

Limit 

(mg/Kg, dry)

6/14/11 

Analytical 

Detection 

Limit 

(mg/Kg, dry)

6/14/11 

Duplicate 

Sample 

Analytical 

Detection 

Limit 

(mg/Kg, dry)

6/21/11 

Analytical 

Detection 

Limit 

(mg/Kg, dry)

(

SM18 2540G Solids, Total (%) N/A N/A N/A N/A EPA 7196A Chromium, Hexavalent (mg/Kg) 10 10 10 10 EPA 9012A Cyanide, Total 4 4 4 3 SM 4500-CN G Cyanide, Total Amenable 4 4 4 3 EPA 6010B Aluminum, Total 13 4.7 5.7 5.1 EPA 6010B Arsenic, Total 13 4.7 5.7 5.1 EPA 6010B Barium, Total 13 4.7 5.7 5.1 EPA 6010B Cadmium, Total 1.30 0.47 0.57 0.51 EPA 6010B Chromium, Total 3.3 1.2 1.4 1.3 EPA 6010B Copper, Total 13 4.7 5.7 5.1 EPA 6010B Iron, Total 13 4.7 5.7 5.1 EPA 6010B Lead, Total 13.0 4.7 5.7 5.1 EPA 7471A Mercury, Total 0.062 0.093 0.082 0.067 EPA 6010B Nickel, Total 3.3 1.2 1.4 1.3 EPA 7010 Selenium, Total 3.2 1.2 1.2 1.3 EPA 6010B Silver, Total 13.0 4.7 5.7 5.1 EPA 6010B Zinc, Total 13 4.7 5.7 5.1 ICP-OES Platinum, Total (ug/g) 5.0 5.0 5.0 5.0 ICP-OES Tin, Total (ug/g) 5.0 5.0 5.0 5.0 
ATTACHMENT D 
Laboratory Report

PROJECT: Sludge Analysis

DATE RECEIVED:

WORK ORDER:

DATE REPORTED:

100290

IBM

Mail Stop 966A

Essex Jct, VT 05452

Atten: Dave Kost SAMPLER:

August 08, 2011

1106-07565

Roland Luxenburg

June 08, 2011

Enclosed please find the results of the analyses performed for the samples referenced on the 

attached chain of custody. All required method quality control elements including 

instrument calibration were performed in accordance with method requirements and 

determined to be acceptable unless otherwise noted. 

The column labeled Lab/Tech in the accompanying report denotes the laboratory facility 

where the testing was performed and the technician who conducted the assay. A "W" designates 

the Williston, VT lab under NELAC certification ELAP 11263; "R" designates the Lebanon, NH 

facility under certification NH 2037 and “N” the Plattsburgh, NY lab under certification ELAP 

11892. “Sub” indicates the testing was performed by a subcontracted laboratory. The 

accreditation status of the subcontracted lab is referenced in the corresponding NELAC and Qual 

fields. 

The NELAC column also denotes the accreditation status of each laboratory for each 

reported parameter. “A” indicates the referenced laboratory is NELAC accredited for the 

parameter reported. “N” indicates the laboratory is not accredited. “U” indicates that NELAC 

does not offer accreditation for that parameter in that specific matrix. Test results denoted with an 

“A” meet all National Environmental Laboratory Accreditation Program requirements except 

where denoted by pertinent data qualifiers. Test results are representative of the samples as they 

were received at the laboratory 

Endyne, Inc. warrants, to the best of its knowledge and belief, the accuracy of the analytical 

test results contained in this report, but makes no other warranty, expressed or implied, especially 

no warranties of merchantability or fitness for a particular purpose. 

Page 1 of 4

Reviewed by:

Harry B. Locker, Ph.D.

Laboratory Director

 ELAP 11263

160 James Brown Dr., Williston, VT 05495

Ph 802-879-4333 Fax 802-879-7103

www.endynelabs.com

NH2037

56 Etna Road, Lebanon, NH 03766 

Ph 603-678-4891 Fax 603-678-4893
Laboratory Report

IBM

Page 2 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-07565

06/08/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 1 Composite Time: 7:00 Date Sampled:6/8/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

TCLP Extract-VOA ZHE EPA 1311 Completed 6/16/11 MMW W A

TCLP Extract-SVOA/Metals EPA 1311 Completed 6/15/11 MMW W A

Cyanide, Total EPA 9012A < 4 mg/Kg, dry 6/20/11 CAL N A

Cyanide, Total Amenable SM 4500-CN G < 4 mg/kg, dry 6/20/11 CAL N U

Solids, Total SM18 2540G 31.4 % 6/10/11 JSS W U

Aluminum, Total EPA 6010B 8,400 mg/Kg, dry 7/29/11 ETK W A

Arsenic, Total TCLP EPA 6010B < 0.20 mg/L 7/5/11 ETK W A

Arsenic, Total EPA 6010B < 13 mg/Kg, dry 7/29/11 ETK W A

Barium, Total TCLP EPA 6010B < 0.20 mg/L 7/5/11 ETK W A

Barium, Total EPA 6010B 39 mg/Kg, dry 7/29/11 ETK W A

Cadmium, Total TCLP EPA 6010B < 0.020 mg/L 7/5/11 ETK W A

Cadmium, Total EPA 6010B < 1.3 mg/Kg, dry 7/29/11 ETK W A

Chromium, Hexavalent EPA 7196A < 10 mg/Kg 7/5/11 MMW W N

Chromium, Total TCLP EPA 6010B < 0.050 mg/L 7/5/11 ETK W A

Chromium, Total EPA 6010B 290 mg/Kg, dry 7/29/11 ETK W A

Copper, Total EPA 6010B 680 mg/Kg, dry 7/29/11 ETK W A

Iron, Total EPA 6010B 7,400 mg/Kg, dry 7/29/11 ETK W A

Lead, Total TCLP EPA 6010B < 0.20 mg/L 7/5/11 ETK W A

Lead, Total EPA 6010B < 13 mg/Kg, dry 7/29/11 ETK W A

Mercury, Total TCLP EPA 7470 < 0.010 mg/L 6/21/11 CM W A

Mercury, Total EPA 7471A < 0.062 mg/Kg, dry 6/13/11 CM W A

Nickel, Total TCLP EPA 6010B 0.11 mg/L 7/5/11 ETK W A QA+

Nickel, Total EPA 6010B 36 mg/Kg, dry 7/29/11 ETK W A

Platinum, Total ICP-OES < 5 ug/g 6/21/11 SUB SW U SBV

Selenium, Total TCLP EPA 7010 < 0.020 mg/L 6/24/11 MMW W A

Selenium, Total EPA 7010 < 3.2 mg/Kg, dry 6/15/11 MMW W A

Silver, Total TCLP EPA 6010B < 0.20 mg/L 7/5/11 ETK W A QASilver, Total EPA 6010B < 13 mg/Kg, dry 7/29/11 ETK W A

Tin ICP-OES < 5 ug/g 6/21/11 SUB SW U SBV

Zinc, Total EPA 6010B 780 mg/Kg, dry 7/29/11 ETK W A

VOC Custom List

TCLP VOLATILES

Vinyl chloride EPA 8260B < 188 ug/Kg, Dry 6/22/11 MGT W A

Vinyl chloride, TCLP EPA 8260B < 20.0 ug/L 6/22/11 MGT W A

1,1-Dichloroethene EPA 8260B < 94.0 ug/Kg, Dry 6/22/11 MGT W A

1,1-Dichloroethene, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

2-Butanone, TCLP EPA 8260B < 100 ug/L 6/22/11 MGT W A

2-Butanone EPA 8260B < 940 ug/Kg, Dry 6/22/11 MGT W A

Chloroform, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

Chloroform EPA 8260B < 94.0 ug/Kg, Dry 6/22/11 MGT W A

Carbon tetrachloride EPA 8260B < 94.0 ug/Kg, Dry 6/22/11 MGT W A
Laboratory Report

IBM

Page 3 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-07565

06/08/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 1 Composite Time: 7:00 Date Sampled:6/8/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

Carbon tetrachloride, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

Benzene EPA 8260B < 94.0 ug/Kg, Dry 6/22/11 MGT W A

Benzene, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

1,2-Dichloroethane, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

1,2-Dichloroethane EPA 8260B < 94.0 ug/Kg, Dry 6/22/11 MGT W A

Trichloroethene EPA 8260B < 94.0 ug/Kg, Dry 6/22/11 MGT W A

Trichloroethene, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

Tetrachloroethene EPA 8260B < 94.0 ug/Kg, Dry 6/22/11 MGT W A

Tetrachloroethene, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

Chlorobenzene EPA 8260B < 94.0 ug/Kg, Dry 6/22/11 MGT W A

Chlorobenzene, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

1,4-Dichlorobenzene EPA 8260B < 94.0 ug/Kg, Dry 6/22/11 MGT W A

1,4-Dichlorobenzene, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

Surr. 1 (Dibromofluoromethane) EPA 8260B 96 % 6/22/11 MGT W A

Surr. 1 (Dibromofluoromethane) EPA 8260B 101 % 6/22/11 MGT W A

Surr. 2 (Toluene d8) EPA 8260B 97 % 6/22/11 MGT W A

Surr. 2 (Toluene d8) EPA 8260B 100 % 6/22/11 MGT W A

Surr. 3 (4-Bromofluorobenzene) EPA 8260B 100 % 6/22/11 MGT W A

Surr. 3 (4-Bromofluorobenzene) EPA 8260B 95 % 6/22/11 MGT W A

TCLP SEMI-VOLATILES

Liq/Liq Solvent Extraction EPA 3510C Completed 6/20/11 RBF W A

Pyridine, TCLP EPA 8270C < 100 ug/L 6/27/11 EEP W A

Hexachloroethane, TCLP EPA 8270C < 50.0 ug/L 6/27/11 EEP W A

Nitrobenzene, TCLP EPA 8270C < 50.0 ug/L 6/27/11 EEP W A

Hexachlorobutadiene, TCLP EPA 8270C < 50.0 ug/L 6/27/11 EEP W A

2,4-Dinitrotoluene, TCLP EPA 8270C < 50.0 ug/L 6/27/11 EEP W A

Hexachlorobenzene, TCLP EPA 8270C < 50.0 ug/L 6/27/11 EEP W A

Cresols, Total TCLP EPA 8270C < 100 ug/L 6/27/11 EEP W U

2,4,5-Trichlorophenol, TCLP EPA 8270C < 100 ug/L 6/27/11 EEP W A

2,4,6-Trichlorophenol, TCLP EPA 8270C < 100 ug/L 6/27/11 EEP W A

Pentachlorophenol, TCLP EPA 8270C < 200 ug/L 6/27/11 EEP W A

B/N Surr.1 Nitrobenzene-d5 EPA 8270C 67 % 6/27/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 66 % 6/27/11 EEP W A

B/N Surr.3 Terphenyl-d14 EPA 8270C 87 % 6/27/11 EEP W A

Acid Surr.1 2-Fluorophenol EPA 8270C 26 % 6/27/11 EEP W A

Acid Surr.2 Phenol-d8 EPA 8270C 21 % 6/27/11 EEP W A

Acid Surr.3 Tribromophenol EPA 8270C 77 % 6/27/11 EEP W A

Ultrasonic Extraction EPA 3550B Completed 6/21/11 RBF W A

Pyridine EPA 8270C < 1,050 ug/Kg, dry 6/28/11 EEP W A

Hexachloroethane EPA 8270C < 525 ug/Kg, dry 6/28/11 EEP W A

Nitrobenzene EPA 8270C < 525 ug/Kg, dry 6/28/11 EEP W A
Laboratory Report

IBM

Page 4 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-07565

06/08/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 1 Composite Time: 7:00 Date Sampled:6/8/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

Hexachlorobutadiene EPA 8270C < 525 ug/Kg, dry 6/28/11 EEP W A

2,4-Dinitrotoluene EPA 8270C < 525 ug/Kg, dry 6/28/11 EEP W A

Hexachlorobenzene EPA 8270C < 525 ug/Kg, dry 6/28/11 EEP W A

Cresols, Total EPA 8270C < 1,050 ug/Kg, dry 6/28/11 EEP W U

2,4,5-Trichlorophenol EPA 8270C < 1,050 ug/Kg, dry 6/28/11 EEP W A

2,4,6-Trichlorophenol EPA 8270C < 1,050 ug/Kg, dry 6/28/11 EEP W A

Pentachlorophenol EPA 8270C < 2,100 ug/Kg, dry 6/28/11 EEP W A

B/N Surr.1 Nitrobenzene-d5 EPA 8270C 56 % 6/28/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 64 % 6/28/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 64 % 6/28/11 EEP W A

Acid Surr.1 2-Fluorophenol EPA 8270C 5 % 6/28/11 EEP W A QSAcid Surr.2 Phenol-d8 EPA 8270C 26 % 6/28/11 EEP W A QSAcid Surr.3 Tribromophenol EPA 8270C ND % 6/28/11 EEP W A QSReport Summary of Qualifiers and Notes

SBV: Analysis performed by subcontracted laboratory, VHG Labs. The complete subcontracted report has been appended

to this report.

QS-: Indicates surrogate recovery was below laboratory acceptance limits, attributed to sample matrix interference.

QA-: QA/QC associated with this analysis did not meet laboratory acceptance limits indicating the results may be

biased low.

QA+: QA/QC associated with this analysis did not meet laboratory acceptance limits indicating the results may be

biased high.

IEC: The IEC QC checked failed low for this analyte.This analyte may be biased low.
 276 Abby Road, Manchester, NH 03103 (603) 622-7660 www.vhglabs.com

 Page 1 of 1 

 

 Endyne, Inc DATE: 6/22/2011 

Attn: Mark Westover 

160 James Brown Dr JOB NO: SO1114814 

Williston, VT 05495 

 PO NO: 06171105 

SAMPLE TYPE: Sludge 

 SAMPLE I.D.: 1106-07565 001 

 DATE RECEIVED: 6/14/2011

 METHOD: Quantitative determination of elements by ICP-OES 

 RESULTS: Concentration in μg/g (ppm). 

 

Sample I.D. Sn Pt 

1106-07565 001 <5 <5 

 

 

 

 

We certify the above analysis to be the result obtained on the samples, as received, based upon the analytical chemistry expertise and 

standard methods utilized by VHG Labs. VHG Labs, Inc. waives all responsibility for any damages resulting from the usage and/or 

implementation of the products/data described herein. This report may not be reproduced, except in full, without written approval from 

VHG Labs. 

 

 Approved By: ________________________________ 

 Julie M. MacIntosh, A/S Manager 

 Analytical Services Division
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07565

Project: Sludge Analysis Date Received: June 8, 2011

Report Date: August 8, 2011 Analysis Date: June 20, 2011

Q-List: 52242

Result as Final Value

Run Sequence Identification (ug/L) Target % Recovery mg/Kg dry

Calibration Verification: 150.002 150 100%

Independent Laboratory Fortified Blank: 59.573 63.7 93.5%

Laboratory Reagent Blank -1.937 < 10 Pass

1106-07565-001 Total -1.487 < 4

Duplicate of Sample Above: -1.9 Pass

1106-07856-001 Total -1.353 < 4

Matrix Spike of Sample Above: 82.257 80 103%

1106-07857-001 Total -1.292 < 4

Continuing Calibration Check 145.889 150 97.3%

1106-07565-001 Amenable -1.353 < 4

Duplicate of Sample Above: -1.353 Pass

1106-07856-001 Amenable 1.09 < 4

Matrix Spike of Sample Above: 0.40 < 10 Pass

1106-07857-001 Amenable -0.32 < 4

Matrix Spike of Sample Above: 2.57 < 10 Pass

QC 757-022 Amenable 62.86 63.7 98.7%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

Cyanide, Total and Amenable. EPA 9012A. Sludge.

 20%

70%-130%

80%-120%

13%-199%

Analytical Run Log

1 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07565

Project: Sludge Analysis Sample Date: June 8, 2011

Report Date: August 8, 2011 Analysis Date: July 5, 2011

Receive Date: June 8, 2011 Q-List: 52814

Result as Reported

Run Sequence Identification mg/L Target % Recovery mg/Kg

Calibration Verification: 0.093 0.1 93.0%

Independent Laboratory Fortified Blank: 0.2 0.2 100% 20.02

Laboratory Reagent Blank 0.002 < 10

1106-07565-001 0.029 *** < 10

Duplicate of Sample Above: 0.031 *** 8.8%

1106-07856-001 0.033 *** < 10

Matrix Spike of Sample Above: 0.148 *** 0.233 63.6% * 22.9

1106-07857-001 0.051 *** < 10

1106-08356-001 0.011 *** < 10

1106-08833-001 0.014 *** < 10

Insoluble Matrix Spike of Sample Above: 1.023 0.935 109%** 5770

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 * Matrix Spike for sample 1106-07856 failed low. Results qualified on Final Report

 ** Matrix Spike used as passing closing QA result

 -Calibration Verification acceptance limits

 -Laboratory Fortified Blank (QC) control lim

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Dev

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

Hexavalent Chromium EPA3060A/7196A

20%

75%-125%

80%-120%

80%-120%

Analytical Run Log

 *** Analyst did not measure absobence of sample prior to addition of Diphenyl Carbazide. This resulted in an 

artificially high absorbance.

2 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07565

Project: Sludge Analysis Sample Date: June 8, 2011

Report Date: August 8, 2011 Analysis Date: June 13, 2011

Receive Date: June 8, 2011 Q-List: 51832

Result as Adjusted for

Run Sequence Identification ug/L Target % Recovery Mass Digested mg/Kg

Calibration Verification: 1.96 2 98.0%

Independent Laboratory Fortified Blank: 2.081 2 104% 0.52

Laboratory Reagent Blank 0.002 < 0.050

1106-07565-001 0.189 < 0.062

Duplicate of Sample Above: 0.193 PASS < 0.061

Matrix Spike of Sample Above: 3.02 3 101%

Continuing Calibration Check 1.998 2 99.9%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 0.20ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7471A Mercury-Soil

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

3 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07565

Project: Sludge Analysis Sample Date: June 8, 2011

Report Date: August 8, 2011 Analysis Date: June 21, 2011

Receive Date June 8, 2011 Q-List: 52105

Result as Adjusted for dilution

Run Sequence Identification ug/L Target % Recovery mg/L

Calibration Verification: 2.012 2 101%

Independent Laboratory Fortified Blank: 1.96 2 98.0%

Laboratory Reagent Blank -0.013

1106-07565-001 -0.009 < 0.010

Duplicate of Sample Above: -0.011 PASS

1106-07856-001 -0.006 < 0.010

Matrix Spike of Sample Above: 2.019 2 101%

1106-07857-001 -0.003 < 0.010

Continuing Calibration Check 2.08 2 104%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 1.0ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7470 Mercury-TCLP

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

4 of 18
Laboratory Quality Data Report ENDYNE INC. 160 James Brown Drive

EPA 6010B- ICP Metals Soil Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Client: IBM Work Order: 1106-07565

Project: Sludge Date Received:Report Date: Analysis Date:

Q-List #: 53,665

Int. Chk. CCVA CCVR LFB LRB Duplicate LFM CCVA CCVR

Instrument Instrument Instrument Reported

Parameter PQL (% Rec) (% Rec) (% Rec) (% Rec) (mg/L) RPD (%) (% Rec) mg/L mg/Kg (% Rec) (% Rec)Aluminum-Axial 0.020 NA 97.8 99.2 0.0184 1.9 NP NA NA 103Aluminum-Radial 4.0 96.6 99.5 NA 0.261 1.7 NP 13.0339 8400 93.6

Arsenic 0.020 NA 95.7 98.2 -0.0007 ND 73.2 0.0105 < 13 98.1

Barium 0.020 85.2 98.9 99.1 -0.0017 0.0 NP 0.0607 39.3 97.7Cadmium 0.002 105 98 99.4 0.0002 0.5 64.2 ** 0.0008 < 1.3 98.8

Chromium 0.005 112 99.4 102 -0.0012 3.6 71.6 0.4519 290 107Copper 0.020 88.2 98 104 -0.0002 2.0 NP 1.0478 680 97.6Iron-Axial 0.020 NA 99.6 108 0.038 * ND NP NA NA 99.5

Iron-Radial 4.0 95.7 100 NA 0.1057 0.7 NP 11.4628 7400 93.9

Lead 0.020 111 94.8 101 0.0004 9.0 NP 0.0105 < 13 96.3Nickel 0.005 108 101 98.8 -0.0002 7.3 60.7 ** 0.0555 36 101

Silver 0.020 96.4 100 101 0.0005 ND 83.3 -0.0042 < 13 99.8Zinc 0.020 101 95.2 100 0.002 0.6 NP 1.2111 780 97Notes: * Blank contamination at levels affecting quantitation. Axial line not used for sample quantitation. ** Recovery was not within method acceptance limits. Report was qualified. LRB, LFB, Duplicate & LFM were from digestion batch. Associated QA were not analyzed on the same day as the project sample. -NA: Not Available. Sample not assessed for this element. - ND: Not Determined. Sample did not have analyte within calibration range. - NP: Not Practical, Spike concentration too low relative to Sample concentration -Bold Font indicates value outside laboratory acceptance limits -Interference Check (Int. Chk.) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits.  -Calibration Verification (CCVA) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Calibration Verification High Concentration (CCVR) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Laboratory Fortified Blank (TMLFB) acceptance limits are noted: Values were determined to be within method acceptance limits -Laboratory Reagent Blank (TMLRB) was free of contaminant affecting analytical results. Values as mg/L digested soil blank. -Duplicate relative percent difference (RPD) acceptance criteria is < 20%. Values were within method acceptance limits unless noted.  -Matrix Spike (MS) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits unless noted. 

QC Report Page 1 of 1

August 8, 2011

1106-07565-001

June 8, 2011July 29, 2011
Laboratory Quality Data Report ENDYNE INC. 160 James Brown Drive

EPA 6010B- ICP Metals TCLP Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Client: IBM Work Order: 1106-07565

Project: Sludge Analysis Date Received:Report Date: Analysis Date:

Q-List #: 52,931

Int. Chk. CCVA LFB LRB 

Instrument Reported LFM Instrument Reported Duplicate Instrume

Parameter (% Rec) (% Rec) (% Rec) (mg/L) mg/L mg/L % Recovery mg/L mg/L % RPD mg/L Arsenic NA 97.3 99.4 -0.0013 -0.0055 < 0.20 99.6 -0.0104 < 0.20 ND -0.0098 

Barium 95.2 95.9 98.9 -0.0019 0.0127 < 0.20 94.4 0.0171 < 0.20 ND 0.0197 Cadmium 101 98.5 101 0.0001 0.0001 < 0.020 95.4 0.0003 < 0.020 ND 0.0003 

Chromium 103 97.1 99.8 -0.0015 -0.0026 < 0.050 93.8 -0.0021 < 0.050 ND -0.0007 

Lead 110 98.8 102 0.0007 -0.0005 < 0.20 93.4 0.0002 < 0.20 ND -0.0006 Silver 91.1 98.5 82.9 * 0.0006 -0.0002 < 0.20 71.8 0.0005 < 0.20 ND 0.0007 

Nickel 94.3 97.1 99.5 0.0004 0.0108 0.11 90.2 0.0030 < 0.10 ND 0.0031 Notes: * Silver LFB was not within method Acceptance Limits. Report qualified. ** Closing CCVA failed high, No samples had reportable values. Data not Qualified *** Closing CCVA failed high, Samples with reportable values were qualified. -TCLP samples are digested at a 1:10 dilution -NA: Not Available. Sample not assessed for this element. - ND: Not Determined. Sample did not have analyte above reporting limit. -Bold Font indicates value outside laboratory acceptance limits -Interference Check (Int. Chk.) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits.  -Calibration Verification (CCVA) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Calibration Verification High Concentration (CCVR) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Laboratory Fortified Blank (TMLFB) acceptance limits: 85 - 115%. Values were determined to be within method acceptance limits -Laboratory Reagent Blank (TMLRB) was free of contaminant affecting analytical results. Values as mg/L digested -Duplicate relative percent difference (RPD) acceptance criteria is < 20%. Values were within method acceptance limits unless noted.  -Matrix Spike (MS) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits unless noted. 

QC Report Page 1 of 1

June 8, 2011July 5, 2011

1106

August 8, 2011

1106-07565-001 1106-07856-001
7/12/11

VHG JOB # SO1114814 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.2 0 0 0 1.01 0.102

Instr result 10.1 0.000 0.004 <5 0.004 <5 0.987 0.1

% Recovery 99.0 97.7 98.0

Sn Theoretical 10 0 0 0 0.999 0.100

Instr result 9.99 0.000 0.017 <5 0.019 <5 0.992 0.119

% Recovery 99.9 99.3 119.0

VHG JOB # SO1114844 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.2 0.000 0.000 0.000 1.01 0.102

Instr result 10.1 0.000 -0.009 <5 -0.009 <5 0.976 0.086

% Recovery 99.0 96.6 84.3

Sn Theoretical 10.2 0.000 0.000 0.000 0.999 0.1

Instr result 10.3 0.000 0.008 <5 0.008 <5 0.982 0.113

% Recovery 101.0 98.3 113.0

VHG JOB # SO1114844 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.3 0.000 0.000 0.000 1.01 0.102

Instr result 10.3 0.000 -0.009 <5 -0.009 <5 0.976 0.086

% Recovery 100.0 96.6 84.3

Sn Theoretical 10.2 0.000 0.000 0.000 0.999 0.1

Instr result 10.3 0.000 0.008 <5 0.008 <5 0.982 0.113

% Recovery 101.0 98.3 113.0

VHG JOB # SO1115051 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.0 0.000 0.000 0.000 1.000 0.099

Instr result 9.74 0.005 0.000 <5 0.000 <5 0.976 0.089

% Recovery 97.4 97.6 89.9

Sn Theoretical 10.9 0.000 0.000 0.000 1.074 0.108

Instr result 10.7 0.008 0.005 <5 0.005 <5 1.058 0.119

% Recovery 98.2 98.5 110.2

VHG JOB # SO1115291 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10 0.000 0.000 0.000 1.000 0.099

Instr result 9.98 -0.006 -0.007 <5 -0.007 <5 0.974 0.091

% Recovery 99.8 97.4 91.9

Sn Theoretical 10.9 0.000 0.000 0.000 1.074 0.108

Instr result 10.9 0.004 0.012 6.4 0.012 4.3 1.043 0.120

% Recovery 100.0 97.1 111.1

Sample ID:1106-07857 001 Duplicate composite 

#2,bottle 005-Solids

Date Analyzed:7/8/11

Sample ID:1106-08833 001 Sample 4,bottle #5-

solid

Date Analyzed: 6/21/11

Date Analyzed: 6/29/11 Sample ID:1106-08356 001, Sample#3,bottle#5

Date Analyzed: 6/21/11

Sample ID:1106-07565 001-Sludge Sampler, 

bottle 005

Quality Report-VHG Labs

Date Analyzed: 6/21/11

Sample ID:1106-07856 001Sample 2 

Composite,bottle #5-Solids

7 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07565

Project: Sludge Analysis Sample Date: June 8, 2011

Report Date: August 8, 2011 Analysis Date: June 15, 2011

Receive Date: June 8, 2011 Q-List: 52021

Result as Adjusted for

Run Sequence Identification ug/L Target % Recovery Mass Digested mg/Kg

Calibration Verification: 10.28 10 102.8%

Independent Laboratory Fortified Blank: 20.12 20 100.6% 50.0

Laboratory Reagent Blank -0.122 < 2.5

1106-07565-001 -0.708 < 3.24

Non-project Sample 1.83 < 5.62

Duplicate of Sample Above: 1.09 PASS

Continuing Calibration Check 9.48 10 94.8%

Non-project Sample 5.14 4.36

Matrix Spike of Sample Above: 12.93 20 46.2% *

Continuing Calibration Check 9.81 10 98.1%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 * Matrix Spike was not within Limits. Report for this sample was qualified

 -Instrument quantitation limit is 2.0ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limit

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviat

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7010-Selenium Soil

20%

75%-125%

90%-110%

85%-115%

Analytical Run Log

8 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07565

Project: Sludge Analysis Sample Date: June 8, 2011

Report Date: August 8, 2011 Analysis Date: June 24, 2011

Receive Date June 8, 2011 Q-List: 52389

Result as Adjusted for dilution

Run Sequence Identification ug/L Target % Recovery mg/L

Calibration Verification: 10.25 10 102.5%

Independent Laboratory Fortified Blank: 21.04 20 105.2%

Laboratory Reagent Blank 0.259

1106-07565-001 -0.2468 < 0.020

Matrix Spike of Sample Above: 10.096 10 101.9%

1106-07856-001 -0.0917 < 0.020

Duplicate of Sample Above: -0.4179 PASS

1106-07857-001 -0.4191 < 0.020

Continuing Calibration Check 9.13 10 91.3%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 2.0ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7010-Selenium TCLP

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

9 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07565

Project: Sludge Analysis Sample Date: June 8, 2011

Report Date: August 8, 2011 Analysis Date: June 10, 2011

Receive Date: June 8, 2011 Q-List: 51889

Result as

Run Sequence Identification (%) Target % Recovery

Laboratory Fortified Blank: 100 100 100.0%

Laboratory Reagent Blank < 0.01

Non Project Sample 0.0352

Duplicate of Sample Above: 0.0365 3.6% % RSD

1106-07565-001 31.4

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

Total Solids - SM18 2540G.

10%

Not Applicable

Not Applicable

99%-101%

Analytical Run Log

10 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-07565

Project: Sludge Analysis Date Received: June 8, 2011

Report Date: July 27, 2011 Analysis Date: June 22, 2011

QC Report - Method 8260B, Soil

Associated Samples: 001

File: 06221102.d 06221105.d 06221106.d

Standard: Calibration Cal. Ver. Laboratory LFB Laboratory

Verification Acceptance Fortified Blank Acceptance Reagent Blank

Parameter Units: Recovery (%) Range (%) Recovery (%) Range (%) (ug/L)

Vinyl chloride 87 75 - 125 75 70 - 130 < 2.0

1,1-Dichloroethene 97 75 - 125 101 70 - 130 < 1.0

2-Butanone 76 75 - 125 99 70 - 130 < 10.0

Chloroform 99 75 - 125 102 70 - 130 < 1.0

Carbon tetrachloride 105 75 - 125 103 70 - 130 < 1.0

Benzene 109 75 - 125 97 70 - 130 < 1.0

1,2-Dichloroethane 102 75 - 125 99 70 - 130 < 1.0

Trichloroethene 105 75 - 125 106 70 - 130 < 1.0

Tetrachloroethene 100 75 - 125 93 70 - 130 < 1.0

Chlorobenzene 101 75 - 125 100 70 - 130 < 1.0

1,4-Dichlorobenzene 99 75 - 125 97 70 - 130 < 1.0

Surrogate Recovery (%)

Dibromofluoromethane S1 99 75 - 125 99 70 - 130 100

Toluene-d8 S2 101 75 - 125 99 70 - 130 99

4-Bromofluorobenzene S3 99 75 - 125 98 70 - 130 96

8260B Run Log 6/22/11

(Files Relevant to WO 1106-07565)

Sample Standard.Prep.

File Sample Number Site ID Dilution (%) Date Notes

06221101.d 25ng 8260 BFB Instrument Tune Check 6/2/11

06221102.d 20ug/L 8260B Cal Std Calibration Verification 6/17/11

06221105.d 10ug/L LFB Lab Fortified Blank (QC-Soil Matrix) 6/19/11

06221106.d LRB Lab Reagent Blank (Soil Martix) 6/19/11

06221107.d 1106-07565-001 Sludge Sampler 250uL of 19.1053g/15ml Multiplier = *93.70207

06221108.d 1106-07856-001 Sample 2 Composite 250uL of 21.0811g/15ml Multiplier = *60.35389

06221109.d 1106-07857-001 Duplicate Composite 250uL of 20.7748g/15ml Multiplier = *63.18979

06221121.d MS-07851-002 Well 2 210' - Lab Matrix Spike 100

06221122.d MSD-07851-002 Well 2 210' - Lab MS Duplicate 100

Notes:

 -Calibration Verification (CV) acceptance limits are noted. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB/QC) control limits are noted. Values were determined to be within laboratory acceptance limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Matrix Spike and MS Duplicates were performed at the appropriate frequency for the analytical batch. Analyses were performed

 on samples under a separate work order.

1106-07565 8260 Soil Page 1 of 1

11 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-07565

Project: Sludge Analysis Date Received: June 8, 2011

Report Date: July 27, 2011 Analysis Date: June 22, 2011

QC Report - Method 8260B, Water (TCLP)

Associated Samples: 001

File: 06221102.d 06221103.d 06221104.d

Standard: Calibration Cal. Ver. Laboratory LFB Laboratory

Verification Acceptance Fortified Blank Acceptance Reagent Blank

Parameter Units: Recovery (%) Range (%) Recovery (%) Range (%) (ug/L)

Vinyl chloride 87 75 - 125 103 70 - 130 < 2.0

1,1-Dichloroethene 97 75 - 125 115 70 - 130 < 1.0

2-Butanone 76 75 - 125 79 70 - 130 < 10.0

Chloroform 99 75 - 125 108 70 - 130 < 1.0

Carbon tetrachloride 105 75 - 125 117 70 - 130 < 1.0

Benzene 109 75 - 125 118 70 - 130 < 1.0

1,2-Dichloroethane 102 75 - 125 115 70 - 130 < 1.0

Trichloroethene 105 75 - 125 107 70 - 130 < 1.0

Tetrachloroethene 100 75 - 125 102 70 - 130 < 1.0

Chlorobenzene 101 75 - 125 102 70 - 130 < 1.0

1,4-Dichlorobenzene 99 75 - 125 97 70 - 130 < 1.0

Surrogate Recovery (%)

Dibromofluoromethane S1 99 75 - 125 104 70 - 130 99

Toluene-d8 S2 101 75 - 125 102 70 - 130 99

4-Bromofluorobenzene S3 99 75 - 125 99 70 - 130 98

8260B Run Log 6/22/11

(Files Relevant to WO 1106-07565)

Sample Standard.Prep.

File Sample Number Site ID Dilution (%) Date Notes

06221101.d 25ng 8260 BFB Instrument Tune Check 6/2/11

06221102.d 20ug/L 8260B Cal Std Calibration Verification 6/17/11

06221103.d 10ug/L LFB Lab Fortified Blank (QC-Water Matrix) 6/20/11

06221104.d LRB Lab Reagent Blank (Water Martix) 6/2/11

06221114.d 1106-07565-001 Sludge Sampler 10

06221117.d 1106-07856-001 Sample 2 Composite 10

06221121.d MS-07851-002 Well 2 210' - Lab Matrix Spike 100

06221122.d MSD-07851-002 Well 2 210' - Lab MS Duplicate 100

Notes:

 -Calibration Verification (CV) acceptance limits are noted. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB/QC) control limits are noted. Values were determined to be within laboratory acceptance limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Matrix Spike and MS Duplicates were performed at the appropriate frequency for the analytical batch. Analyses were performed

 on samples under a separate work order.

1106-07565 8260 Water Page 1 of 1

12 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-07565

Project: Sludge Analysis Date Received: June 8, 2011

Report Date: July 27, 2011 Analysis Date: June 28, 2011

QC Report - Method 8270C, Soil

Associated Samples: 001

File: 06271118.d 06271129.d 06271131.d 06271135.d

Standard: Calibration Laboratory LFB Laboratory Sample 001

Verification Fortified Blank Acceptance Reagent Blank Duplicate

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) RPD (%)

N-Nitrosodimethylamine 103.9 < 10 ND

Pyridine 101.9 < 10 ND

Aniline 102.1 < 10 ND

Phenol 100.1 49.5 25.7 - 97.3 < 5 ND

2-Chorophenol 97.8 54.0 29.7 - 96.2 < 5 ND

bis(2-chloroethyl) Ether 95.7 < 5 ND

1,3-Dichlorobenzene 97.0 < 2 ND

1,4-Dichlorobenzene 96.6 52.6 31.1 - 77.7 < 2 ND

1,2-Dichlorobenzene 95.7 < 2 ND

Benzyl Alcohol 109.9 < 20 ND

2-Methylphenol 100.0 < 5 ND

bis(2-chloroisopropyl)ether 95.1 < 10 ND

N-Nitrosodi-n-propylamine 95.1 59.3 45.8 - 85.1 < 10 ND

3&4-Methylphenol 99.8 < 5 ND

Hexachloroethane 94.9 < 5 ND

Nitrobenzene 98.7 < 5 ND

N-Nitrosopiperidine 99.9 < 10 ND

Isophorone 98.1 < 2 ND

2-Nitrophenol 102.3 < 10 ND

2,4-Dimethylphenol 98.9 < 5 ND

bis(2-chloroethoxy)Methane 96.6 < 5 ND

2,4-Dichlorophenol 102.1 < 5 ND

1,2,4-Trichlorobenzene 96.5 54.2 37.5 - 86.4 < 2 ND

Naphthalene 96.5 < 1 ND

4-Chloroaniline 98.5 < 5 ND

2,6-Dichlorophenol 97.0 < 5 ND

Hexachlorobutadiene 97.7 < 5 ND

N-Nitrosodi-n-butylamine 115.7 < 5 ND

4-Chloro-3-methylphenol 104.8 66.4 48.3 - 108.0 < 10 ND

2-Methylnaphthalene 97.5 < 1 ND

1-Methylnaphthalene 97.2 < 1 ND

Hexachlorocyclopentadiene 104.8 < 20 ND

2,4,6-Trichlorophenol 102.2 < 10 ND

2,4,5-Trichlorophenol 103.0 < 10 ND

2-Chloronaphthalene 89.1 < 2 ND

1-Chloronaphthalene 99.9 < 2 ND

2-Nitroaniline 105.4 < 20 ND

Dimethylphthalate 96.7 < 5 ND

2,6-Dinitrotoluene 102.9 < 5 ND

Acenaphthylene 97.1 < 1 ND

3-Nitroaniline 103.2 < 5 ND

1106-07565 8270 Soil Page 1 of 3

13 of 18
QC Report - Method 8270C, Soil

Associated Samples: 001

File: 06271118.d 06271129.d 06271131.d 06271135.d

Standard: Calibration Laboratory LFB Laboratory Sample 001

Verification Fortified Blank Acceptance Reagent Blank Duplicate

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) RPD (%)

Acenaphthene 94.4 62.2 49.0 - 95.3 < 1 ND

2,4-Dinitrophenol 118.1 < 20 ND

Dibenzofuran 97.1 < 2 ND

4-Nitrophenol 106.0 74.7 30.3 - 98.0 < 10 ND

2,4-Dinitrotoluene 104.1 70.7 47.8 - 104.9 < 5 ND

1-Naphthylamine 107.9 < 10 ND

2-Naphthylamine 93.9 < 10 ND

Fluorene 97.0 < 1 ND

Diethylphthalate 96.1 < 5 ND

4-Chlorophenylphenylether 94.5 < 2 ND

4-Nitroaniline 97.6 < 20 ND

2-Methyl-4,6-dinitrophenol 112.8 < 20 ND

N-Nitrosodiphenylamine 99.5 < 5 ND

Azobenzene 98.1 < 5 ND

4-Bromophenylphenylether 95.3 < 2 ND

Hexachlorobenzene 93.9 < 5 ND

Pentachlorophenol 114.1 69.5 32.4 - 120.0 < 20 ND

Phenanthrene 96.4 < 1 ND

Anthracene 97.6 < 1 ND

Carbazole 100.4 < 10 ND

Di-n-butylphthalate 99.6 < 10 ND

Fluoranthene 102.7 < 1 ND

Benzidine 115.1 < 10 ND

Pyrene 101.1 76.8 58.2 - 108.6 < 1 ND

Benzylbutylphthalate 105.3 < 5 ND

Benzo(a)anthracene 97.3 < 1 ND

Chrysene 97.8 < 1 ND

3,3'-Dichlorobenzidine 102.9 < 5 ND

bis(2-ethylhexyl)phthalate 105.3 < 5 ND

Di-n-octylphthalate 106.0 < 10 ND

Benzo(b)fluoranthene 100.4 < 1 ND

Benzo(k)fluoranthene 96.9 < 1 ND

Benzo(a)pyrene 101.6 < 1 ND

Indeno[1,2,3-cd]pyrene 105.7 < 1 ND

Dibenz(a,h)anthracene 105.5 < 1 ND

Benzo(g,h,i)perylene 99.5 < 1 ND

Surrogate Recoveries (%) LFB/LRB/Sample

CV Result LFB Result Acceptance LRB Result Duplicate

Acid Surrogates Recovery (%) Recovery (%) Recovery (%) Recovery (%) Recovery (%)

2-Fluorophenol (E.S.) 97.3 41.9 15.2 - 70.1 52.6 1.3

Phenol-d5 (E.S.) 99.7 55.8 29.9 - 78.3 70.3 18.9

2,4,6-Tribromophenol (E.S.) 101.4 68.9 47.6 - 106.3 80.8 0.0

B/N Surrogates

Nitrobenzene-d5 (E.S.) 97.7 56.6 17.8 - 107.4 71.6 58.3

2-Fluorobiphenyl (E.S.) 95.3 59.8 29.3 - 111.9 71.3 65.0

Terphenyl-d14 (E.S.) 100.2 81.6 48.9 - 125.7 92.7 87.9

1106-07565 8270 Soil Page 2 of 3

14 of 18
8270C Run Log 6/27/11 - 6/28/11

(Files Relevant to WO 1106-07565)

Sample Final Prep/Extraction

File Sample Number Site ID Volume Volume Date

06271102.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

06271103.d 80ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271104.d 70ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271105.d 60ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271106.d 50ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271107.d 40ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271108.d 30ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271109.d 20ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271110.d 15ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271111.d 10ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271112.d 5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271113.d 2ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271114.d 1ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271115.d 0.5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271117.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

06271118.d 50ug 8270C Cal Std 12/21/10 Calibration Verification 4.0ml 6/6/11

06271129.d LFB Lab Fortified Blank (QC) 30.21g 4.0ml 6/21/11

06271131.d LRB Lab Reagent Blank 30.03g 4.0ml 6/21/11

06271132.d 1106-07565-001 Sludge Sampler 30.43g 4.0ml 6/21/11

06271133.d 1106-07856-001 Sample 2 Comp 30.57g 4.0ml 6/21/11

06271134.d 1106-07857-001 Duplicate 30.04g 4.0ml 6/21/11

06271135.d Dup-07565-001 Lab Duplicate - Sludge Sampler 30.23g 4.0ml 6/21/11

06271136.d MS-07857-001 Lab Matrix Spike - Duplicate 30.36g 4.0ml 6/21/11

Notes:

 -Bold Font indicates value outside laboratory acceptance limits

 -ND indicates Not Detected

 -Calibration Verification (CV) acceptance limits: 80 - 120%. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB) control limits are noted. Values were determined to be within laboratory control limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate relative percent difference (RPD) acceptance criteria is < 30%. No compounds were observed in the sample for RPD determination.

 -Matrix Spikes were performed at the appropriate frequency for the extraction batch. Analyses were performed on samples under a separate

 work order.

 -Nonconforming QC Elements: Acid extractable surrogate recoveries were out of range in the duplicated analysis.

1106-07565 8270 Soil Page 3 of 3

15 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-07565

Project: Sludge Analysis Date Received: June 8, 2011

Report Date: July 27, 2011 Analysis Date: June 27, 2011

QC Report - Method 8270C, Water

Associated Samples: 001

File: 06271118.d 06271120.d 06271121.d 06271125.d

Standard: Calibration Laboratory LFB Laboratory Sample 001

Verification Fortified Blank Acceptance Reagent Blank Duplicate

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) RPD (%)

N-Nitrosodimethylamine 103.9 < 10 ND

Pyridine 101.9 < 10 ND

Aniline 102.1 < 10 ND

Phenol 100.1 21.8 13.9 - 36.0 < 5 ND

2-Chorophenol 97.8 53.6 38.9 - 87.4 < 5 ND

bis(2-chloroethyl) Ether 95.7 < 5 ND

1,3-Dichlorobenzene 97.0 < 2 ND

1,4-Dichlorobenzene 96.6 37.7 23.2 - 73.2 < 2 ND

1,2-Dichlorobenzene 95.7 < 2 ND

Benzyl Alcohol 109.9 < 20 ND

2-Methylphenol 100.0 < 5 ND

bis(2-chloroisopropyl)ether 95.1 < 10 ND

N-Nitrosodi-n-propylamine 95.1 56.0 44.7 - 87.3 < 10 ND

3&4-Methylphenol 99.8 < 5 ND

Hexachloroethane 94.9 < 5 ND

Nitrobenzene 98.7 < 5 ND

N-Nitrosopiperidine 99.9 < 10 ND

Isophorone 98.1 < 2 ND

2-Nitrophenol 102.3 < 10 ND

2,4-Dimethylphenol 98.9 < 5 ND

bis(2-chloroethoxy)Methane 96.6 < 5 ND

2,4-Dichlorophenol 102.1 < 5 ND

1,2,4-Trichlorobenzene 96.5 41.9 30.3 - 81.8 < 2 ND

Naphthalene 96.5 < 1 ND

4-Chloroaniline 98.5 < 5 ND

2,6-Dichlorophenol 97.0 < 5 ND

Hexachlorobutadiene 97.7 < 5 ND

N-Nitrosodi-n-butylamine 115.7 < 5 ND

4-Chloro-3-methylphenol 104.8 63.1 45.0 - 115.3 < 10 ND

2-Methylnaphthalene 97.5 < 1 ND

1-Methylnaphthalene 97.2 < 1 ND

Hexachlorocyclopentadiene 104.8 < 20 ND

2,4,6-Trichlorophenol 102.2 < 10 ND

2,4,5-Trichlorophenol 103.0 < 10 ND

2-Chloronaphthalene 89.1 < 2 ND

1-Chloronaphthalene 99.9 < 2 ND

2-Nitroaniline 105.4 < 20 ND

Dimethylphthalate 96.7 < 5 ND

2,6-Dinitrotoluene 102.9 < 5 ND

Acenaphthylene 97.1 < 1 ND

3-Nitroaniline 103.2 < 5 ND

1106-07565 8270 Water Page 1 of 3

16 of 18
QC Report - Method 8270C, Water

Associated Samples: 001

File: 06271118.d 06271120.d 06271121.d 06271125.d

Standard: Calibration Laboratory LFB Laboratory Sample 001

Verification Fortified Blank Acceptance Reagent Blank Duplicate

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) RPD (%)

Acenaphthene 94.4 59.7 45.3 - 98.4 < 1 ND

2,4-Dinitrophenol 118.1 < 20 ND

Dibenzofuran 97.1 < 2 ND

4-Nitrophenol 106.0 34.2 13.7 - 59.3 < 10 ND

2,4-Dinitrotoluene 104.1 65.5 46.2 - 101.1 < 5 ND

1-Naphthylamine 107.9 < 10 ND

2-Naphthylamine 93.9 < 10 ND

Fluorene 97.0 < 1 ND

Diethylphthalate 96.1 < 5 ND

4-Chlorophenylphenylether 94.5 < 2 ND

4-Nitroaniline 97.6 < 20 ND

2-Methyl-4,6-dinitrophenol 112.8 < 20 ND

N-Nitrosodiphenylamine 99.5 < 5 ND

Azobenzene 98.1 < 5 ND

4-Bromophenylphenylether 95.3 < 2 ND

Hexachlorobenzene 93.9 < 5 ND

Pentachlorophenol 114.1 70.3 42.1 - 135.5 < 20 ND

Phenanthrene 96.4 < 1 ND

Anthracene 97.6 < 1 ND

Carbazole 100.4 < 10 ND

Di-n-butylphthalate 99.6 < 10 ND

Fluoranthene 102.7 < 1 ND

Benzidine 115.1 < 10 ND

Pyrene 101.1 78.1 61.8 - 121.9 < 1 ND

Benzylbutylphthalate 105.3 < 5 ND

Benzo(a)anthracene 97.3 < 1 ND

Chrysene 97.8 < 1 ND

3,3'-Dichlorobenzidine 102.9 < 5 ND

bis(2-ethylhexyl)phthalate 105.3 < 5 ND

Di-n-octylphthalate 106.0 < 10 ND

Benzo(b)fluoranthene 100.4 < 1 ND

Benzo(k)fluoranthene 96.9 < 1 ND

Benzo(a)pyrene 101.6 < 1 ND

Indeno[1,2,3-cd]pyrene 105.7 < 1 ND

Dibenz(a,h)anthracene 105.5 < 1 ND

Benzo(g,h,i)perylene 99.5 < 1 ND

Surrogate Recoveries (%) LFB/LRB/Sample

CV Result LFB Result Acceptance LRB Result Duplicate

Acid Surrogates Recovery (%) Recovery (%) Recovery (%) Recovery (%) Recovery (%)

2-Fluorophenol (E.S.) 97.3 32.3 16.2 - 49.9 32.2 28.4

Phenol-d5 (E.S.) 99.7 26.3 11.1 - 42.3 26.7 22.7

2,4,6-Tribromophenol (E.S.) 101.4 73.9 44.6 - 123.6 85.1 81.3

B/N Surrogates

Nitrobenzene-d5 (E.S.) 97.7 64.4 34.3 - 106.9 70.0 67.8

2-Fluorobiphenyl (E.S.) 95.3 67.0 30.7 - 102.3 72.3 67.6

Terphenyl-d14 (E.S.) 100.2 88.4 55.0 - 133.1 96.3 98.4

1106-07565 8270 Water Page 2 of 3

17 of 18
8270C Run Log 6/27/11 - 6/28/11

(Files Relevant to WO 1106-07565)

Sample Final Prep/Extraction

File Sample Number Site ID Volume Volume Date

06271102.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

06271103.d 80ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271104.d 70ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271105.d 60ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271106.d 50ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271107.d 40ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271108.d 30ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271109.d 20ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271110.d 15ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271111.d 10ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271112.d 5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271113.d 2ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271114.d 1ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271115.d 0.5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271117.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

06271118.d 50ug 8270C Cal Std 12/21/10 Calibration Verification 4.0ml 6/6/11

06271120.d LFB Lab Fortified Blank (QC) 0.10L 4.0ml 6/20/11

06271121.d LRB Lab Reagent Blank 0.10L 4.0ml 6/20/11

06271122.d 1106-07565-001 Sludge Sampler 0.10L 4.0ml 6/20/11

06271123.d 1106-07856-001 Sample 2 Comp 0.10L 4.0ml 6/20/11

06271124.d 1106-07857-001 Duplicate 0.10L 4.0ml 6/20/11

06271125.d Dup-07565-001 Lab Duplicate Sludge Sampler 0.10L 4.0ml 6/20/11

06271126.d MS-07856-001 Lab Matrix SpikeSample 2 Comp 0.10L 4.0ml 6/20/11

Notes:

 -ND indicates Not Detected

 -Calibration Verification (CV) acceptance limits: 80 - 120%. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB) control limits are noted. Values were determined to be within laboratory control limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate relative percent difference (RPD) acceptance criteria is < 30%. No compounds were observed in the sample for RPD determination.

 -Matrix Spikes were performed at the appropriate frequency for the extraction batch. Analyses were performed on samples under a separate

 work order.

1106-07565 8270 Water Page 3 of 3

18 of 18

Laboratory Report

PROJECT: Sludge Analysis

DATE RECEIVED:

WORK ORDER:

DATE REPORTED:

100290

IBM

Mail Stop 966A

Essex Jct, VT 05452

Atten: Dave Kost SAMPLER:

August 08, 2011

1106-07856

Roland

June 14, 2011

Enclosed please find the results of the analyses performed for the samples referenced on the 

attached chain of custody. All required method quality control elements including 

instrument calibration were performed in accordance with method requirements and 

determined to be acceptable unless otherwise noted. 

The column labeled Lab/Tech in the accompanying report denotes the laboratory facility 

where the testing was performed and the technician who conducted the assay. A "W" designates 

the Williston, VT lab under NELAC certification ELAP 11263; "R" designates the Lebanon, NH 

facility under certification NH 2037 and “N” the Plattsburgh, NY lab under certification ELAP 

11892. “Sub” indicates the testing was performed by a subcontracted laboratory. The 

accreditation status of the subcontracted lab is referenced in the corresponding NELAC and Qual 

fields. 

The NELAC column also denotes the accreditation status of each laboratory for each 

reported parameter. “A” indicates the referenced laboratory is NELAC accredited for the 

parameter reported. “N” indicates the laboratory is not accredited. “U” indicates that NELAC 

does not offer accreditation for that parameter in that specific matrix. Test results denoted with an 

“A” meet all National Environmental Laboratory Accreditation Program requirements except 

where denoted by pertinent data qualifiers. Test results are representative of the samples as they 

were received at the laboratory 

Endyne, Inc. warrants, to the best of its knowledge and belief, the accuracy of the analytical 

test results contained in this report, but makes no other warranty, expressed or implied, especially 

no warranties of merchantability or fitness for a particular purpose. 

Page 1 of 4

Reviewed by:

Harry B. Locker, Ph.D.

Laboratory Director

 ELAP 11263

160 James Brown Dr., Williston, VT 05495

Ph 802-879-4333 Fax 802-879-7103

www.endynelabs.com

NH2037

56 Etna Road, Lebanon, NH 03766 

Ph 603-678-4891 Fax 603-678-4893
Laboratory Report

IBM

Page 2 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-07856

06/14/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 2 Composite Time: 6:30 Date Sampled:6/14/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

TCLP Extract-VOA ZHE EPA 1311 Completed 6/21/11 MMW W A

TCLP Extract-SVOA/Metals EPA 1311 Completed 6/15/11 MMW W A

Cyanide, Total EPA 9012A < 4 mg/Kg, dry 6/20/11 CAL N A

Cyanide, Total Amenable SM 4500-CN G < 4 mg/kg, dry 6/20/11 CAL N U

Solids, Total SM18 2540G 42.6 % 6/15/11 JSS W U

Aluminum, Total EPA 6010B 9,800 mg/Kg, dry 7/5/11 ETK W A

Arsenic, Total TCLP EPA 6010B < 0.20 mg/L 7/5/11 ETK W A

Arsenic, Total EPA 6010B < 4.7 mg/Kg, dry 7/5/11 ETK W A

Barium, Total TCLP EPA 6010B < 0.20 mg/L 7/5/11 ETK W A

Barium, Total EPA 6010B 27 mg/Kg, dry 7/5/11 ETK W A

Cadmium, Total TCLP EPA 6010B < 0.020 mg/L 7/5/11 ETK W A

Cadmium, Total EPA 6010B < 0.47 mg/Kg, dry 7/5/11 ETK W A

Chromium, Hexavalent EPA 7196A < 10 mg/Kg 7/5/11 MMW W N MChromium, Total TCLP EPA 6010B < 0.050 mg/L 7/5/11 ETK W A

Chromium, Total EPA 6010B 180 mg/Kg, dry 7/5/11 ETK W A

Copper, Total EPA 6010B 670 mg/Kg, dry 7/5/11 ETK W A

Iron, Total EPA 6010B 7,900 mg/Kg, dry 7/5/11 ETK W A

Lead, Total TCLP EPA 6010B < 0.20 mg/L 7/5/11 ETK W A

Lead, Total EPA 6010B < 4.7 mg/Kg, dry 7/5/11 ETK W A

Mercury, Total TCLP EPA 7470 < 0.010 mg/L 6/21/11 CM W A

Mercury, Total EPA 7471A < 0.093 mg/Kg, dry 6/20/11 CM W A

Nickel, Total TCLP EPA 6010B < 0.10 mg/L 7/5/11 ETK W A

Nickel, Total EPA 6010B 24 mg/Kg, dry 7/5/11 ETK W A

Platinum, Total ICP-OES < 5 ug/g 6/21/11 SUB SW U SBV

Selenium, Total TCLP EPA 7010 < 0.020 mg/L 6/24/11 MMW W A

Selenium, Total EPA 7010 < 1.2 mg/Kg, dry 6/29/11 MMW W A

Silver, Total TCLP EPA 6010B < 0.20 mg/L 7/5/11 ETK W A QASilver, Total EPA 6010B < 4.7 mg/Kg, dry 7/5/11 ETK W A

Tin ICP-OES < 5 ug/g 6/21/11 SUB SW U SBV

Zinc, Total EPA 6010B 530 mg/Kg, dry 7/5/11 ETK W A

VOC Custom List

TCLP VOLATILES

Vinyl chloride, TCLP EPA 8260B < 20.0 ug/L 6/22/11 MGT W A

Vinyl chloride EPA 8260B < 120 ug/Kg, Dry 6/22/11 MGT W A

1,1-Dichloroethene EPA 8260B < 60.0 ug/Kg, Dry 6/22/11 MGT W A

1,1-Dichloroethene, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

2-Butanone EPA 8260B < 600 ug/Kg, Dry 6/22/11 MGT W A

2-Butanone, TCLP EPA 8260B < 100 ug/L 6/22/11 MGT W A

Chloroform, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

Chloroform EPA 8260B 144 ug/Kg, Dry 6/22/11 MGT W A

Carbon tetrachloride, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A
Laboratory Report

IBM

Page 3 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-07856

06/14/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 2 Composite Time: 6:30 Date Sampled:6/14/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

Carbon tetrachloride EPA 8260B < 60.0 ug/Kg, Dry 6/22/11 MGT W A

Benzene, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

Benzene EPA 8260B < 60.0 ug/Kg, Dry 6/22/11 MGT W A

1,2-Dichloroethane, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

1,2-Dichloroethane EPA 8260B < 60.0 ug/Kg, Dry 6/22/11 MGT W A

Trichloroethene, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

Trichloroethene EPA 8260B < 60.0 ug/Kg, Dry 6/22/11 MGT W A

Tetrachloroethene EPA 8260B < 60.0 ug/Kg, Dry 6/22/11 MGT W A

Tetrachloroethene, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

Chlorobenzene, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

Chlorobenzene EPA 8260B < 60.0 ug/Kg, Dry 6/22/11 MGT W A

1,4-Dichlorobenzene, TCLP EPA 8260B < 10.0 ug/L 6/22/11 MGT W A

1,4-Dichlorobenzene EPA 8260B < 60.0 ug/Kg, Dry 6/22/11 MGT W A

Surr. 1 (Dibromofluoromethane) EPA 8260B 101 % 6/22/11 MGT W A

Surr. 1 (Dibromofluoromethane) EPA 8260B 73 % 6/22/11 MGT W A

Surr. 2 (Toluene d8) EPA 8260B 96 % 6/22/11 MGT W A

Surr. 2 (Toluene d8) EPA 8260B 100 % 6/22/11 MGT W A

Surr. 3 (4-Bromofluorobenzene) EPA 8260B 101 % 6/22/11 MGT W A

Surr. 3 (4-Bromofluorobenzene) EPA 8260B 97 % 6/22/11 MGT W A

TCLP SEMI-VOLATILES

Liq/Liq Solvent Extraction EPA 3510C Completed 6/20/11 RBF W A

Pyridine, TCLP EPA 8270C < 100 ug/L 6/27/11 EEP W A

Hexachloroethane, TCLP EPA 8270C < 50.0 ug/L 6/27/11 EEP W A

Nitrobenzene, TCLP EPA 8270C < 50.0 ug/L 6/27/11 EEP W A

Hexachlorobutadiene, TCLP EPA 8270C < 50.0 ug/L 6/27/11 EEP W A

2,4-Dinitrotoluene, TCLP EPA 8270C < 50.0 ug/L 6/27/11 EEP W A

Hexachlorobenzene, TCLP EPA 8270C < 50.0 ug/L 6/27/11 EEP W A

Cresols, Total TCLP EPA 8270C < 100 ug/L 6/27/11 EEP W U

2,4,5-Trichlorophenol, TCLP EPA 8270C < 100 ug/L 6/27/11 EEP W A

2,4,6-Trichlorophenol, TCLP EPA 8270C < 100 ug/L 6/27/11 EEP W A

Pentachlorophenol, TCLP EPA 8270C < 200 ug/L 6/27/11 EEP W A

B/N Surr.1 Nitrobenzene-d5 EPA 8270C 72 % 6/27/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 74 % 6/27/11 EEP W A

B/N Surr.3 Terphenyl-d14 EPA 8270C 95 % 6/27/11 EEP W A

Acid Surr.1 2-Fluorophenol EPA 8270C 36 % 6/27/11 EEP W A

Acid Surr.2 Phenol-d8 EPA 8270C 30 % 6/27/11 EEP W A

Acid Surr.3 Tribromophenol EPA 8270C 88 % 6/27/11 EEP W A

Ultrasonic Extraction EPA 3550B Completed 6/21/11 RBF W A

Pyridine EPA 8270C < 770 ug/Kg, dry 6/28/11 EEP W A

Hexachloroethane EPA 8270C < 385 ug/Kg, dry 6/28/11 EEP W A

Nitrobenzene EPA 8270C < 385 ug/Kg, dry 6/28/11 EEP W A
Laboratory Report

IBM

Page 4 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-07856

06/14/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 2 Composite Time: 6:30 Date Sampled:6/14/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

Hexachlorobutadiene EPA 8270C < 385 ug/Kg, dry 6/28/11 EEP W A

2,4-Dinitrotoluene EPA 8270C < 385 ug/Kg, dry 6/28/11 EEP W A

Hexachlorobenzene EPA 8270C < 385 ug/Kg, dry 6/28/11 EEP W A

Cresols, Total EPA 8270C < 770 ug/Kg, dry 6/28/11 EEP W U

2,4,5-Trichlorophenol EPA 8270C < 770 ug/Kg, dry 6/28/11 EEP W A

2,4,6-Trichlorophenol EPA 8270C < 770 ug/Kg, dry 6/28/11 EEP W A

Pentachlorophenol EPA 8270C < 1,540 ug/Kg, dry 6/28/11 EEP W A

B/N Surr.1 Nitrobenzene-d5 EPA 8270C 50 % 6/28/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 58 % 6/28/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 58 % 6/28/11 EEP W A

Acid Surr.1 2-Fluorophenol EPA 8270C 3 % 6/28/11 EEP W A QSAcid Surr.2 Phenol-d8 EPA 8270C 19 % 6/28/11 EEP W A QSAcid Surr.3 Tribromophenol EPA 8270C ND % 6/28/11 EEP W A QSReport Summary of Qualifiers and Notes

Samples were received at the laboratory with a temperature of 15.2 degrees Celsius. Samples must be received in a

cooler with sufficient ice to attain a temperature of 6 degrees Celsius or below. Samples must not be frozen.

SBV: Analysis performed by subcontracted laboratory, VHG Labs. The complete subcontracted report has been appended

to this report.

QS-: Indicates surrogate recovery was below laboratory acceptance limits, attributed to sample matrix interference.

M - : The laboratory fortified matrix (LFM) analysis indicates a potential negative bias in the reported

value.

QA-: QA/QC associated with this analysis did not meet laboratory acceptance limits indicating the results may be

biased low.
 276 Abby Road, Manchester, NH 03103 (603) 622-7660 www.vhglabs.com

 Page 1 of 1 

 

 Endyne, Inc DATE: 6/22/2011 

Attn: Mark Westover 

160 James Brown Dr JOB NO: SO1114844 

Williston, VT 05495 

 PO NO: 06171105 

SAMPLE TYPE: Sludge 

 SAMPLE I.D.: As noted below. 

 DATE RECEIVED: 6/17/2011

 METHOD: Quantitative determination of elements by ICP-OES 

 RESULTS: Concentration in μg/g (ppm). 

 

Sample I.D. Sn Pt 

1106-07856 001 <5 <5 

1106-07857 001 <5 <5 

 

 

 

 

We certify the above analysis to be the result obtained on the samples, as received, based upon the analytical chemistry expertise and 

standard methods utilized by VHG Labs. VHG Labs, Inc. waives all responsibility for any damages resulting from the usage and/or 

implementation of the products/data described herein. This report may not be reproduced, except in full, without written approval from 

VHG Labs. 

 

 Approved By: ________________________________ 

 Julie M. MacIntosh, A/S Manager 

 Analytical Services Division
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07856

Project: Sludge Analysis Date Received: June 14, 2011

Report Date: August 8, 2011 Analysis Date: June 20, 2011

Q-List: 52242

Result as Final Value

Run Sequence Identification (ug/L) Target % Recovery mg/Kg dry

Calibration Verification: 150.002 150 100%

Independent Laboratory Fortified Blank: 59.573 63.7 93.5%

Laboratory Reagent Blank -1.937 < 10 Pass

1106-07565-001 Total -1.487 < 4

Duplicate of Sample Above: -1.9 Pass

1106-07856-001 Total -1.353 < 4

Matrix Spike of Sample Above: 82.257 80 103%

1106-07857-001 Total -1.292 < 4

Continuing Calibration Check 145.889 150 97.3%

1106-07565-001 Amenable -1.353 < 4

Duplicate of Sample Above: -1.353 Pass

1106-07856-001 Amena 1.09 < 4

Matrix Spike of Sample Above: 0.40 < 10 Pass

1106-07857-001 Amenable -0.32 < 4

Matrix Spike of Sample Above: 2.57 < 10 Pass

QC 757-022 Amenable 62.86 63.7 98.7%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation 

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

Cyanide, Total and Amenable. EPA 9012A. Sludge.

 20%

70%-130%

80%-120%

13%-199%

Analytical Run Log

1 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07856

Project: Sludge Analysis Sample Date: June 14, 2011

Report Date: August 8, 2011 Analysis Date: July 5, 2011

Receive Date: June 14, 2011 Q-List: 52814

Result as Reported

Run Sequence Identification mg/L Target % Recovery mg/Kg

Calibration Verification: 0.093 0.1 93.0%

Independent Laboratory Fortified Blank: 0.2 0.2 100% 20.02

Laboratory Reagent Blank 0.002 < 10

1106-07565-001 0.029 *** < 10

Duplicate of Sample Above: 0.031 *** 8.8%

1106-07856-001 0.033 *** < 10

Matrix Spike of Sample Above: 0.148 *** 0.233 63.6% * 22.9

1106-07857-001 0.051 *** < 10

1106-08356-001 0.011 *** < 10

1106-08833-001 0.014 *** < 10

Insoluble Matrix Spike of Sample Above: 1.023 0.935 109%** 5770

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 * Matrix Spike for sample 1106-07856 failed low. Results qualified on Final Report

 ** Matrix Spike used as passing closing QA result

 -Calibration Verification acceptance limits

 -Laboratory Fortified Blank (QC) control lim

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Dev

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

Hexavalent Chromium EPA3060A/7196A

20%

75%-125%

80%-120%

80%-120%

Analytical Run Log

 *** Analyst did not measure absobence of sample prior to addition of Diphenyl Carbazide. This resulted in an 

artificially high absorbance.

2 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07856

Project: Sludge Analysis Sample Date: June 14, 2011

Report Date: August 8, 2011 Analysis Date: June 20, 2011

Receive Date: June 14, 2011 Q-List: 52106

Result as Adjusted for

Run Sequence Identification ug/L Target % Recovery Mass Digested mg/Kg

Calibration Verification: 1.997 2 99.9%

Independent Laboratory Fortified Blank: 1.985 2 99.3% 0.496

Laboratory Reagent Blank -0.020 < 0.050

1106-07856-001 0.146 < 0.093

Duplicate of Sample Above: 0.15 PASS < 0.079

1106-07857-001 0.154 < 0.082

Matrix Spike of Sample Above: 3.056 3 102%

Continuing Calibration Check 1.998 2 99.9%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 0.20ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7471A Mercury-Soil

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

3 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07856

Project: Sludge Analysis Sample Date: June 14, 2011

Report Date: August 8, 2011 Analysis Date: June 21, 2011

Receive Date June 14, 2011 Q-List: 52105

Result as Adjusted for dilution

Run Sequence Identification ug/L Target % Recovery mg/L

Calibration Verification: 2.012 2 101%

Independent Laboratory Fortified Blank: 1.96 2 98.0%

Laboratory Reagent Blank -0.013

1106-07565-001 -0.009 < 0.010

Duplicate of Sample Above: -0.011 PASS

1106-07856-001 -0.006 < 0.010

Matrix Spike of Sample Above: 2.019 2 101%

1106-07857-001 -0.003 < 0.010

Continuing Calibration Check 2.08 2 104%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 1.0ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7470 Mercury-TCLP

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

4 of 18
Laboratory Quality Data Report ENDYNE INC. 160 James Brown Drive

EPA 6010B- ICP Metals Soil Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-710

Client: IBM Work Order: 1106-07856

Project: Sludge Date Received:Report Date: Analysis Date:

Q-List #: 53,655

Int. Chk. CCVA CCVR LRB LFB Duplicate 

Instrument Instrument Instrument Reported 07856-001 Instrument Reported 

Parameter PQL (% Rec) (% Rec) (% Rec) (mg/L) (% Rec) mg/L mg/Kg RPD (%) mg/L mg/Kg Aluminum-Axial 0.020 NA 97.6 0.0234 * 101 ND ND ND ND ND Aluminum-Radial 4.0 99.6 100 0.0973 ND 41.8063 9800 3.5 43.616 13000 

Arsenic 0.020 NA 99.4 0.0009 99.1 0.0106 < 4.7 ND 0.0238 6.8 

Barium 0.020 95.2 97.4 -0.0016 98.8 0.1163 27 3.5 0.1259 36 Cadmium 0.002 101 100 0.0004 100 0.0016 < 0.47 ND 0.0015 < 0.57 Chromium 0.005 103 99.1 -0.0005 99.9 0.7654 180 2.4 0.8252 240 

Copper 0.020 92.2 1.05 0.0006 103 2.8659 670 4.7 2.8795 830 

Iron-Axial 0.020 NA 103 0.0650 * 110 ND ND ND ND ND 

Iron-Radial 4.0 99.5 101 0.1324 ND 33.4643 7900 1.8 35.9537 10000 

Lead 0.020 110 101 -0.0002 102 0.011 < 4.7 ND 0.0118 < 5.7 

Nickel 0.005 94.3 99.4 0.0003 101 0.1034 24 4.6 0.108 31 Silver 0.020 91.1 101 0.0027 101 -0.0153 < 4.7 ND -0.0167 < 5.7 

Zinc 0.020 100 102 0.0045 99.9 2.262 530 4.4 2.3581 680 Notes: * Blank contamination at levels affecting quantitation. Axial line not used for sample quantitation. ** Recovery was not within method acceptance limits. Report was qualified. LRB, LFB, Duplicate & LFM were from digestion batch. Associated QA were not analyzed on the same day as the project sample. -NA: Not Available. Sample not assessed for this element. - ND: Not Determined. Sample did not have analyte within calibration range. -OR: Out-of-range. Spike concentration too low relative to sample concentration. -Bold Font indicates value outside laboratory acceptance limits -Interference Check (Int. Chk.) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits.  -Calibration Verification (CCVA) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Calibration Verification High Concentration (CCVR) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Laboratory Fortified Blank (TMLFB) acceptance limits are noted: Values were determined to be within method acceptance limits -Laboratory Reagent Blank (TMLRB) was free of contaminant affecting analytical results. Values as mg/L digested soil blank. -Duplicate relative percent difference (RPD) acceptance criteria is < 20%. Values were within method acceptance limits unless noted.  -Matrix Spike (MS) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits unless noted. 

QC Report Page 1 of 1

1106-07857-001

August 8, 2011

1106-07856-001

June 14, 2011July 5, 2011
Laboratory Quality Data Report ENDYNE INC. 160 James Brown Drive

EPA 6010B- ICP Metals TCLP Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Client: IBM Work Order: 1106-07856

Project: Sludge Analysis Date Received:Report Date: Analysis Date:

Q-List #: 52,677

Int. Chk. CCVA LFB LRB 

Instrument Reported LFM Instrument Reported Duplicate Instrume

Parameter (% Rec) (% Rec) (% Rec) (mg/L) mg/L mg/L % Recovery mg/L mg/L % RPD mg/L Arsenic NA 97.3 99.4 -0.0013 -0.0055 < 0.20 99.6 -0.0104 < 0.20 ND -0.0098 

Barium 95.2 95.9 98.9 -0.0019 0.0127 < 0.20 94.4 0.0171 < 0.20 ND 0.0197 Cadmium 101 98.5 101 0.0001 0.0001 < 0.020 95.4 0.0003 < 0.020 ND 0.0003 

Chromium 103 97.1 99.8 -0.0015 -0.0026 < 0.050 93.8 -0.0021 < 0.050 ND -0.0007 

Lead 110 98.8 102 0.0007 -0.0005 < 0.20 93.4 0.0002 < 0.20 ND -0.0006 Silver 91.1 98.5 82.9 * 0.0006 -0.0002 < 0.20 71.8 0.0005 < 0.20 ND 0.0007 

Nickel 94.3 97.1 99.5 0.0004 0.0108 0.11 90.2 0.0030 < 0.010 ND 0.0031 

Notes: * Silver LFB was not within method Acceptance Limits. Report qualified. ** Closing CCVA failed high, No samples had reportable values. Data not Qualified *** Closing CCVA failed high, Samples with reportable values were qualified. -TCLP samples are digested at a 1:10 dilution -NA: Not Available. Sample not assessed for this element. - ND: Not Determined. Sample did not have analyte above reporting limit. -Bold Font indicates value outside laboratory acceptance limits -Interference Check (Int. Chk.) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits.  -Calibration Verification (CCVA) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Calibration Verification High Concentration (CCVR) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Laboratory Fortified Blank (TMLFB) acceptance limits: 85 - 115%. Values were determined to be within method acceptance limits -Laboratory Reagent Blank (TMLRB) was free of contaminant affecting analytical results. Values as mg/L digested -Duplicate relative percent difference (RPD) acceptance criteria is < 20%. Values were within method acceptance limits unless noted.  -Matrix Spike (MS) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits unless noted. 

QC Report Page 1 of 1

June 14, 2011July 5, 2011

1106

August 8, 2011

1106-07565-001 1106-07856-001
7/12/11

VHG JOB # SO1114814 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.2 0 0 0 1.01 0.102

Instr result 10.1 0.000 0.004 <5 0.004 <5 0.987 0.1

% Recovery 99.0 97.7 98.0

Sn Theoretical 10 0 0 0 0.999 0.100

Instr result 9.99 0.000 0.017 <5 0.019 <5 0.992 0.119

% Recovery 99.9 99.3 119.0

VHG JOB # SO1114844 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.2 0.000 0.000 0.000 1.01 0.102

Instr result 10.1 0.000 -0.009 <5 -0.009 <5 0.976 0.086

% Recovery 99.0 96.6 84.3

Sn Theoretical 10.2 0.000 0.000 0.000 0.999 0.1

Instr result 10.3 0.000 0.008 <5 0.008 <5 0.982 0.113

% Recovery 101.0 98.3 113.0

VHG JOB # SO1114844 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.3 0.000 0.000 0.000 1.01 0.102

Instr result 10.3 0.000 -0.009 <5 -0.009 <5 0.976 0.086

% Recovery 100.0 96.6 84.3

Sn Theoretical 10.2 0.000 0.000 0.000 0.999 0.1

Instr result 10.3 0.000 0.008 <5 0.008 <5 0.982 0.113

% Recovery 101.0 98.3 113.0

VHG JOB # SO1115051 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.0 0.000 0.000 0.000 1.000 0.099

Instr result 9.74 0.005 0.000 <5 0.000 <5 0.976 0.089

% Recovery 97.4 97.6 89.9

Sn Theoretical 10.9 0.000 0.000 0.000 1.074 0.108

Instr result 10.7 0.008 0.005 <5 0.005 <5 1.058 0.119

% Recovery 98.2 98.5 110.2

VHG JOB # SO1115291 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10 0.000 0.000 0.000 1.000 0.099

Instr result 9.98 -0.006 -0.007 <5 -0.007 <5 0.974 0.091

% Recovery 99.8 97.4 91.9

Sn Theoretical 10.9 0.000 0.000 0.000 1.074 0.108

Instr result 10.9 0.004 0.012 6.4 0.012 4.3 1.043 0.120

% Recovery 100.0 97.1 111.1

Sample ID:1106-07857 001 Duplicate composite 

#2,bottle 005-Solids

Date Analyzed:7/8/11

Sample ID:1106-08833 001 Sample 4,bottle #5-

solid

Date Analyzed: 6/21/11

Date Analyzed: 6/29/11 Sample ID:1106-08356 001, Sample#3,bottle#5

Date Analyzed: 6/21/11

Sample ID:1106-07565 001-Sludge Sampler, 

bottle 005

Quality Report-VHG Labs

Date Analyzed: 6/21/11

Sample ID:1106-07856 001Sample 2 

Composite,bottle #5-Solids

7 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07856

Project: Sludge Analysis Sample Date: June 14, 2011

Report Date: August 8, 2011 Analysis Date: June 29, 2011

Receive Date: June 14, 2011 Q-List: 52679

Result as Adjusted for

Run Sequence Identification ug/L Target % Recovery Mass Digested mg/Kg

Calibration Verification: 10.09 10 100.9%

Independent Laboratory Fortified Blank: 21.9 20 109.5% 50.0

Laboratory Reagent Blank 0.283 < 2.5

1106-07856-001 -0.435 < 1.17

Duplicate of Sample Above: -0.858 PASS

1106-07857-001 -1.024 < 1.20

Matrix Spike of Sample Above: 16.35 20 81.8%

Continuing Calibration Check 10.03 10 100.3%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument quantitation limit is 2.0ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limit

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviat

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7010-Selenium Soil

20%

75%-125%

90%-110%

85%-115%

Analytical Run Log

8 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07856

Project: Sludge Analysis Sample Date: June 14, 2011

Report Date: August 8, 2011 Analysis Date: June 24, 2011

Receive Date: June 14, 2011 Q-List: 52389

Result as Adjusted for dilution

Run Sequence Identification ug/L Target % Recovery mg/L

Calibration Verification: 10.25 10 103%

Independent Laboratory Fortified Blank: 21.04 20 105%

Laboratory Reagent Blank 0.259

1106-07565-001 -0.2468 < 0.020

Matrix Spike of Sample Above: 10.096 10 102%

1106-07856-001 -0.0917 < 0.020

Duplicate of Sample Above: -0.4179 PASS

1106-07857-001 -0.4191 < 0.020

Continuing Calibration Check 9.13 10 91.3%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 2.0ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7010-Selenium TCLP

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

9 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07856

Project: Sludge Analysis Sample Date: June 14, 2011

Report Date: August 8, 2011 Analysis Date: June 15, 2011

Receive Date: June 14, 2011 Q-List: 52064

Result as

Run Sequence Identification (%) Target % Recovery

Laboratory Fortified Blank: 100 100 100.0%

Laboratory Reagent Blank < 0.01

Non Project Sample 0.221

Duplicate of Sample Above: 0.238 7.4% % RSD

1106-07856-001 42.6

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

Total Solids - SM18 2540G.

10%

Not Applicable

Not Applicable

99%-101%

Analytical Run Log

10 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-07856

Project: WW-Sludge Analysis Date Received: June 14, 2011

Report Date: July 27, 2011 Analysis Date: June 22, 2011

QC Report - Method 8260B, Soil

Associated Samples: 001

File: 06221102.d 06221105.d 06221106.d

Standard: Calibration Cal. Ver. Laboratory LFB Laboratory

Verification Acceptance Fortified Blank Acceptance Reagent Blank

Parameter Units: Recovery (%) Range (%) Recovery (%) Range (%) (ug/L)

Vinyl chloride 87 75 - 125 75 70 - 130 < 2.0

1,1-Dichloroethene 97 75 - 125 101 70 - 130 < 1.0

2-Butanone 76 75 - 125 99 70 - 130 < 10.0

Chloroform 99 75 - 125 102 70 - 130 < 1.0

Carbon tetrachloride 105 75 - 125 103 70 - 130 < 1.0

Benzene 109 75 - 125 97 70 - 130 < 1.0

1,2-Dichloroethane 102 75 - 125 99 70 - 130 < 1.0

Trichloroethene 105 75 - 125 106 70 - 130 < 1.0

Tetrachloroethene 100 75 - 125 93 70 - 130 < 1.0

Chlorobenzene 101 75 - 125 100 70 - 130 < 1.0

1,4-Dichlorobenzene 99 75 - 125 97 70 - 130 < 1.0

Surrogate Recovery (%)

Dibromofluoromethane S1 99 75 - 125 99 70 - 130 100

Toluene-d8 S2 101 75 - 125 99 70 - 130 99

4-Bromofluorobenzene S3 99 75 - 125 98 70 - 130 96

8260B Run Log 6/22/11

(Files Relevant to WO 1106-07856)

Sample Standard.Prep.

File Sample Number Site ID Dilution (%) Date Notes

06221101.d 25ng 8260 BFB Instrument Tune Check 6/2/11

06221102.d 20ug/L 8260B Cal Std Calibration Verification 6/17/11

06221105.d 10ug/L LFB Lab Fortified Blank (QC-Soil Matrix) 6/19/11

06221106.d LRB Lab Reagent Blank (Soil Martix) 6/19/11

06221107.d 1106-07565-001 Sludge Sampler 250uL of 19.1053g/15ml Multiplier = *93.70207

06221108.d 1106-07856-001 Sample 2 Composite 250uL of 21.0811g/15ml Multiplier = *60.35389

06221109.d 1106-07857-001 Duplicate Composite 250uL of 20.7748g/15ml Multiplier = *63.18979

06221121.d MS-07851-002 Well 2 210' - Lab Matrix Spike 100

06221122.d MSD-07851-002 Well 2 210' - Lab MS Duplicate 100

Notes:

 -Calibration Verification (CV) acceptance limits are noted. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB/QC) control limits are noted. Values were determined to be within laboratory acceptance limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Matrix Spike and MS Duplicates were performed at the appropriate frequency for the analytical batch. Analyses were performed

 on samples under a separate work order.

1106-07856 8260 Soil Page 1 of 1

11 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-07856

Project: WW-Sludge Analysis Date Received: June 14, 2011

Report Date: July 27, 2011 Analysis Date: June 22, 2011

QC Report - Method 8260B, Water (TCLP)

Associated Samples: 001

File: 06221102.d 06221103.d 06221104.d

Standard: Calibration Cal. Ver. Laboratory LFB Laboratory

Verification Acceptance Fortified Blank Acceptance Reagent Blank

Parameter Units: Recovery (%) Range (%) Recovery (%) Range (%) (ug/L)

Vinyl chloride 87 75 - 125 103 70 - 130 < 2.0

1,1-Dichloroethene 97 75 - 125 115 70 - 130 < 1.0

2-Butanone 76 75 - 125 79 70 - 130 < 10.0

Chloroform 99 75 - 125 108 70 - 130 < 1.0

Carbon tetrachloride 105 75 - 125 117 70 - 130 < 1.0

Benzene 109 75 - 125 118 70 - 130 < 1.0

1,2-Dichloroethane 102 75 - 125 115 70 - 130 < 1.0

Trichloroethene 105 75 - 125 107 70 - 130 < 1.0

Tetrachloroethene 100 75 - 125 102 70 - 130 < 1.0

Chlorobenzene 101 75 - 125 102 70 - 130 < 1.0

1,4-Dichlorobenzene 99 75 - 125 97 70 - 130 < 1.0

Surrogate Recovery (%)

Dibromofluoromethane S1 99 75 - 125 104 70 - 130 99

Toluene-d8 S2 101 75 - 125 102 70 - 130 99

4-Bromofluorobenzene S3 99 75 - 125 99 70 - 130 98

8260B Run Log 6/22/11

(Files Relevant to WO 1106-07856)

Sample Standard.Prep.

File Sample Number Site ID Dilution (%) Date Notes

06221101.d 25ng 8260 BFB Instrument Tune Check 6/2/11

06221102.d 20ug/L 8260B Cal Std Calibration Verification 6/17/11

06221103.d 10ug/L LFB Lab Fortified Blank (QC-Water Matrix) 6/20/11

06221104.d LRB Lab Reagent Blank (Water Martix) 6/2/11

06221114.d 1106-07565-001 Sludge Sampler 10

06221117.d 1106-07856-001 Sample 2 Composite 10

06221121.d MS-07851-002 Well 2 210' - Lab Matrix Spike 100

06221122.d MSD-07851-002 Well 2 210' - Lab MS Duplicate 100

Notes:

 -Calibration Verification (CV) acceptance limits are noted. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB/QC) control limits are noted. Values were determined to be within laboratory acceptance limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Matrix Spike and MS Duplicates were performed at the appropriate frequency for the analytical batch. Analyses were performed

 on samples under a separate work order.

1106-07856 8260 Water Page 1 of 1

12 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-07856

Project: WW-Sludge Analysis Date Received: June 14, 2011

Report Date: July 27, 2011 Analysis Date: June 28, 2011

QC Report - Method 8270C, Soil

Associated Samples: 001

File: 06271118.d 06271129.d 06271131.d

Standard: Calibration Laboratory LFB Laboratory

Verification Fortified Blank Acceptance Reagent Blank

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug)

N-Nitrosodimethylamine 103.9 < 10

Pyridine 101.9 < 10

Aniline 102.1 < 10

Phenol 100.1 49.5 25.7 - 97.3 < 5

2-Chorophenol 97.8 54.0 29.7 - 96.2 < 5

bis(2-chloroethyl) Ether 95.7 < 5

1,3-Dichlorobenzene 97.0 < 2

1,4-Dichlorobenzene 96.6 52.6 31.1 - 77.7 < 2

1,2-Dichlorobenzene 95.7 < 2

Benzyl Alcohol 109.9 < 20

2-Methylphenol 100.0 < 5

bis(2-chloroisopropyl)ether 95.1 < 10

N-Nitrosodi-n-propylamine 95.1 59.3 45.8 - 85.1 < 10

3&4-Methylphenol 99.8 < 5

Hexachloroethane 94.9 < 5

Nitrobenzene 98.7 < 5

N-Nitrosopiperidine 99.9 < 10

Isophorone 98.1 < 2

2-Nitrophenol 102.3 < 10

2,4-Dimethylphenol 98.9 < 5

bis(2-chloroethoxy)Methane 96.6 < 5

2,4-Dichlorophenol 102.1 < 5

1,2,4-Trichlorobenzene 96.5 54.2 37.5 - 86.4 < 2

Naphthalene 96.5 < 1

4-Chloroaniline 98.5 < 5

2,6-Dichlorophenol 97.0 < 5

Hexachlorobutadiene 97.7 < 5

N-Nitrosodi-n-butylamine 115.7 < 5

4-Chloro-3-methylphenol 104.8 66.4 48.3 - 108.0 < 10

2-Methylnaphthalene 97.5 < 1

1-Methylnaphthalene 97.2 < 1

Hexachlorocyclopentadiene 104.8 < 20

2,4,6-Trichlorophenol 102.2 < 10

2,4,5-Trichlorophenol 103.0 < 10

2-Chloronaphthalene 89.1 < 2

1-Chloronaphthalene 99.9 < 2

2-Nitroaniline 105.4 < 20

Dimethylphthalate 96.7 < 5

2,6-Dinitrotoluene 102.9 < 5

Acenaphthylene 97.1 < 1

3-Nitroaniline 103.2 < 5

1106-07856 8270 Soil Page 1 of 3

13 of 18
QC Report - Method 8270C, Soil

Associated Samples: 001

File: 06271118.d 06271129.d 06271131.d

Standard: Calibration Laboratory LFB Laboratory

Verification Fortified Blank Acceptance Reagent Blank

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug)

Acenaphthene 94.4 62.2 49.0 - 95.3 < 1

2,4-Dinitrophenol 118.1 < 20

Dibenzofuran 97.1 < 2

4-Nitrophenol 106.0 74.7 30.3 - 98.0 < 10

2,4-Dinitrotoluene 104.1 70.7 47.8 - 104.9 < 5

1-Naphthylamine 107.9 < 10

2-Naphthylamine 93.9 < 10

Fluorene 97.0 < 1

Diethylphthalate 96.1 < 5

4-Chlorophenylphenylether 94.5 < 2

4-Nitroaniline 97.6 < 20

2-Methyl-4,6-dinitrophenol 112.8 < 20

N-Nitrosodiphenylamine 99.5 < 5

Azobenzene 98.1 < 5

4-Bromophenylphenylether 95.3 < 2

Hexachlorobenzene 93.9 < 5

Pentachlorophenol 114.1 69.5 32.4 - 120.0 < 20

Phenanthrene 96.4 < 1

Anthracene 97.6 < 1

Carbazole 100.4 < 10

Di-n-butylphthalate 99.6 < 10

Fluoranthene 102.7 < 1

Benzidine 115.1 < 10

Pyrene 101.1 76.8 58.2 - 108.6 < 1

Benzylbutylphthalate 105.3 < 5

Benzo(a)anthracene 97.3 < 1

Chrysene 97.8 < 1

3,3'-Dichlorobenzidine 102.9 < 5

bis(2-ethylhexyl)phthalate 105.3 < 5

Di-n-octylphthalate 106.0 < 10

Benzo(b)fluoranthene 100.4 < 1

Benzo(k)fluoranthene 96.9 < 1

Benzo(a)pyrene 101.6 < 1

Indeno[1,2,3-cd]pyrene 105.7 < 1

Dibenz(a,h)anthracene 105.5 < 1

Benzo(g,h,i)perylene 99.5 < 1

Surrogate Recoveries (%) LFB/LRB/Sample

CV Result LFB Result Acceptance LRB Result

Acid Surrogates Recovery (%) Recovery (%) Recovery (%) Recovery (%)

2-Fluorophenol (E.S.) 97.3 41.9 15.2 - 70.1 52.6

Phenol-d5 (E.S.) 99.7 55.8 29.9 - 78.3 70.3

2,4,6-Tribromophenol (E.S.) 101.4 68.9 47.6 - 106.3 80.8

B/N Surrogates

Nitrobenzene-d5 (E.S.) 97.7 56.6 17.8 - 107.4 71.6

2-Fluorobiphenyl (E.S.) 95.3 59.8 29.3 - 111.9 71.3

Terphenyl-d14 (E.S.) 100.2 81.6 48.9 - 125.7 92.7

1106-07856 8270 Soil Page 2 of 3

14 of 18
8270C Run Log 6/27/11 - 6/28/11

(Files Relevant to WO 1106-07856)

Sample Final Prep/Extraction

File Sample Number Site ID Volume Volume Date

06271102.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

06271103.d 80ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271104.d 70ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271105.d 60ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271106.d 50ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271107.d 40ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271108.d 30ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271109.d 20ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271110.d 15ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271111.d 10ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271112.d 5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271113.d 2ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271114.d 1ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271115.d 0.5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271117.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

06271118.d 50ug 8270C Cal Std 12/21/10 Calibration Verification 4.0ml 6/6/11

06271129.d LFB Lab Fortified Blank (QC) 30.21g 4.0ml 6/21/11

06271131.d LRB Lab Reagent Blank 30.03g 4.0ml 6/21/11

06271132.d 1106-07565-001 Sludge Sampler 30.43g 4.0ml 6/21/11

06271133.d 1106-07856-001 Sample 2 Comp 30.57g 4.0ml 6/21/11

06271134.d 1106-07857-001 Duplicate 30.04g 4.0ml 6/21/11

06271135.d Dup-07565-001 Lab Duplicate - Sludge Sampler 30.23g 4.0ml 6/21/11

06271136.d MS-07857-001 Lab Matrix Spike - Duplicate 30.36g 4.0ml 6/21/11

Notes:

 -Calibration Verification (CV) acceptance limits: 80 - 120%. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB) control limits are noted. Values were determined to be within laboratory control limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicates were performed at the appropriate frequency for the extraction batch. Analyses were performed on samples under a separate

 work order.

 -Matrix Spikes were performed at the appropriate frequency for the extraction batch. Analyses were performed on samples under a separate

 work order.

1106-07856 8270 Soil Page 3 of 3

15 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-07856

Project: WW-Sludge Analysis Date Received: June 14, 2011

Report Date: July 27, 2011 Analysis Date: June 27, 2011

QC Report - Method 8270C, Water

Associated Samples: 001

File: 06271118.d 06271120.d 06271121.d 06271126.d

Standard: Calibration Laboratory LFB Laboratory Sample 001 LFM

Verification Fortified Blank Acceptance Reagent Blank Matrix Spike Acceptance Limit

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) Recovery (%) Recovery (%)

N-Nitrosodimethylamine 103.9 < 10

Pyridine 101.9 < 10

Aniline 102.1 < 10

Phenol 100.1 21.8 13.9 - 36.0 < 5 21.6 11.5 - 35.6

2-Chorophenol 97.8 53.6 38.9 - 87.4 < 5 53.3 28.2 - 85.4

bis(2-chloroethyl) Ether 95.7 < 5

1,3-Dichlorobenzene 97.0 < 2

1,4-Dichlorobenzene 96.6 37.7 23.2 - 73.2 < 2 37.0 17.7 - 77.6

1,2-Dichlorobenzene 95.7 < 2

Benzyl Alcohol 109.9 < 20

2-Methylphenol 100.0 < 5

bis(2-chloroisopropyl)ether 95.1 < 10

N-Nitrosodi-n-propylamine 95.1 56.0 44.7 - 87.3 < 10 59.5 32.3 - 87.9

3&4-Methylphenol 99.8 < 5

Hexachloroethane 94.9 < 5

Nitrobenzene 98.7 < 5

N-Nitrosopiperidine 99.9 < 10

Isophorone 98.1 < 2

2-Nitrophenol 102.3 < 10

2,4-Dimethylphenol 98.9 < 5

bis(2-chloroethoxy)Methane 96.6 < 5

2,4-Dichlorophenol 102.1 < 5

1,2,4-Trichlorobenzene 96.5 41.9 30.3 - 81.8 < 2 42.0 21.9 - 87.2

Naphthalene 96.5 < 1

4-Chloroaniline 98.5 < 5

2,6-Dichlorophenol 97.0 < 5

Hexachlorobutadiene 97.7 < 5

N-Nitrosodi-n-butylamine 115.7 < 5

4-Chloro-3-methylphenol 104.8 63.1 45.0 - 115.3 < 10 66.4 43.5 - 106.8

2-Methylnaphthalene 97.5 < 1

1-Methylnaphthalene 97.2 < 1

Hexachlorocyclopentadiene 104.8 < 20

2,4,6-Trichlorophenol 102.2 < 10

2,4,5-Trichlorophenol 103.0 < 10

2-Chloronaphthalene 89.1 < 2

1-Chloronaphthalene 99.9 < 2

2-Nitroaniline 105.4 < 20

Dimethylphthalate 96.7 < 5

2,6-Dinitrotoluene 102.9 < 5

Acenaphthylene 97.1 < 1

3-Nitroaniline 103.2 < 5

1106-07856 8270 Water Page 1 of 3

16 of 18
QC Report - Method 8270C, Water

Associated Samples: 001

File: 06271118.d 06271120.d 06271121.d 06271126.d

Standard: Calibration Laboratory LFB Laboratory Sample 001 LFM

Verification Fortified Blank Acceptance Reagent Blank Matrix Spike Acceptance Limit

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) RPD (%) Recovery (%)

Acenaphthene 94.4 59.7 45.3 - 98.4 < 1 56.3 32.5 - 103.4

2,4-Dinitrophenol 118.1 < 20

Dibenzofuran 97.1 < 2

4-Nitrophenol 106.0 34.2 13.7 - 59.3 < 10 38.8 11.8 - 60.9

2,4-Dinitrotoluene 104.1 65.5 46.2 - 101.1 < 5 70.6 31.1 - 98.5

1-Naphthylamine 107.9 < 10

2-Naphthylamine 93.9 < 10

Fluorene 97.0 < 1

Diethylphthalate 96.1 < 5

4-Chlorophenylphenylether 94.5 < 2

4-Nitroaniline 97.6 < 20

2-Methyl-4,6-dinitrophenol 112.8 < 20

N-Nitrosodiphenylamine 99.5 < 5

Azobenzene 98.1 < 5

4-Bromophenylphenylether 95.3 < 2

Hexachlorobenzene 93.9 < 5

Pentachlorophenol 114.1 70.3 42.1 - 135.5 < 20 83.9 27.3 - 127.5

Phenanthrene 96.4 < 1

Anthracene 97.6 < 1

Carbazole 100.4 < 10

Di-n-butylphthalate 99.6 < 10

Fluoranthene 102.7 < 1

Benzidine 115.1 < 10

Pyrene 101.1 78.1 61.8 - 121.9 < 1 79.4 45.0 - 127.5

Benzylbutylphthalate 105.3 < 5

Benzo(a)anthracene 97.3 < 1

Chrysene 97.8 < 1

3,3'-Dichlorobenzidine 102.9 < 5

bis(2-ethylhexyl)phthalate 105.3 < 5

Di-n-octylphthalate 106.0 < 10

Benzo(b)fluoranthene 100.4 < 1

Benzo(k)fluoranthene 96.9 < 1

Benzo(a)pyrene 101.6 < 1

Indeno[1,2,3-cd]pyrene 105.7 < 1

Dibenz(a,h)anthracene 105.5 < 1

Benzo(g,h,i)perylene 99.5 < 1

Surrogate Recoveries (%) LFB/LRB/Sample LFM

CV Result LFB Result Acceptance LRB Result Matrix Spike Acceptance Limit

Acid Surrogates Recovery (%) Recovery (%) Recovery (%) Recovery (%) Recovery (%) Recovery (%)

2-Fluorophenol (E.S.) 97.3 32.3 16.2 - 49.9 32.2 29.9 16.2 - 49.9

Phenol-d5 (E.S.) 99.7 26.3 11.1 - 42.3 26.7 24.7 11.1 - 42.3

2,4,6-Tribromophenol (E.S.) 101.4 73.9 44.6 - 123.6 85.1 81.1 44.6 - 123.6

B/N Surrogates

Nitrobenzene-d5 (E.S.) 97.7 64.4 34.3 - 106.9 70.0 63.9 34.3 - 106.9

2-Fluorobiphenyl (E.S.) 95.3 67.0 30.7 - 102.3 72.3 66.5 30.7 - 102.3

Terphenyl-d14 (E.S.) 100.2 88.4 55.0 - 133.1 96.3 88.7 55.0 - 133.1

1106-07856 8270 Water Page 2 of 3

17 of 18
8270C Run Log 6/27/11 - 6/28/11

(Files Relevant to WO 1106-07856)

Sample Final Prep/Extraction

File Sample Number Site ID Volume Volume Date

06271102.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

06271103.d 80ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271104.d 70ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271105.d 60ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271106.d 50ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271107.d 40ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271108.d 30ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271109.d 20ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271110.d 15ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271111.d 10ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271112.d 5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271113.d 2ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271114.d 1ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271115.d 0.5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271117.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

06271118.d 50ug 8270C Cal Std 12/21/10 Calibration Verification 4.0ml 6/6/11

06271120.d LFB Lab Fortified Blank (QC) 0.10L 4.0ml 6/20/11

06271121.d LRB Lab Reagent Blank 0.10L 4.0ml 6/20/11

06271122.d 1106-07565-001 Sludge Sampler 0.10L 4.0ml 6/20/11

06271123.d 1106-07856-001 Sample 2 Comp 0.10L 4.0ml 6/20/11

06271124.d 1106-07857-001 Duplicate 0.10L 4.0ml 6/20/11

06271125.d Dup-07565-001 Lab Duplicate Sludge Sampler 0.10L 4.0ml 6/20/11

06271126.d MS-07856-001 Lab Matrix SpikeSample 2 Comp 0.10L 4.0ml 6/20/11

Notes:

 -Calibration Verification (CV) acceptance limits: 80 - 120%. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB) control limits are noted. Values were determined to be within laboratory control limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicates were performed at the appropriate frequency for the extraction batch. Analyses were performed on samples under a separate

 work order.

 -Matrix Spikes (LFM) control limits are noted. Values were determined to be within laboratory control limits.

1106-07856 8270 Water Page 3 of 3

18 of 18

Laboratory Report

PROJECT: Sludge Analysis

DATE RECEIVED:

WORK ORDER:

DATE REPORTED:

100290

IBM

Mail Stop 966A

Essex Jct, VT 05452

Atten: Dave Kost SAMPLER:

August 08, 2011

1106-07857

Roland

June 14, 2011

Enclosed please find the results of the analyses performed for the samples referenced on the 

attached chain of custody. All required method quality control elements including 

instrument calibration were performed in accordance with method requirements and 

determined to be acceptable unless otherwise noted. 

The column labeled Lab/Tech in the accompanying report denotes the laboratory facility 

where the testing was performed and the technician who conducted the assay. A "W" designates 

the Williston, VT lab under NELAC certification ELAP 11263; "R" designates the Lebanon, NH 

facility under certification NH 2037 and “N” the Plattsburgh, NY lab under certification ELAP 

11892. “Sub” indicates the testing was performed by a subcontracted laboratory. The 

accreditation status of the subcontracted lab is referenced in the corresponding NELAC and Qual 

fields. 

The NELAC column also denotes the accreditation status of each laboratory for each 

reported parameter. “A” indicates the referenced laboratory is NELAC accredited for the 

parameter reported. “N” indicates the laboratory is not accredited. “U” indicates that NELAC 

does not offer accreditation for that parameter in that specific matrix. Test results denoted with an 

“A” meet all National Environmental Laboratory Accreditation Program requirements except 

where denoted by pertinent data qualifiers. Test results are representative of the samples as they 

were received at the laboratory 

Endyne, Inc. warrants, to the best of its knowledge and belief, the accuracy of the analytical 

test results contained in this report, but makes no other warranty, expressed or implied, especially 

no warranties of merchantability or fitness for a particular purpose. 

Page 1 of 4

Reviewed by:

Harry B. Locker, Ph.D.

Laboratory Director

 ELAP 11263

160 James Brown Dr., Williston, VT 05495

Ph 802-879-4333 Fax 802-879-7103

www.endynelabs.com

NH2037

56 Etna Road, Lebanon, NH 03766 

Ph 603-678-4891 Fax 603-678-4893
Laboratory Report

IBM

Page 2 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-07857

06/14/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 2 Duplicate Time: 6:30 Date Sampled:6/14/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

TCLP Extract-VOA ZHE EPA 1311 Completed 6/23/11 MMW W A

TCLP Extract-SVOA/Metals EPA 1311 Completed 6/15/11 MMW W A

Cyanide, Total EPA 9012A < 4 mg/Kg, dry 6/20/11 CAL N A

Cyanide, Total Amenable SM 4500-CN G < 4 mg/kg, dry 6/20/11 CAL N U

Solids, Total SM18 2540G 41.4 % 6/15/11 JSS W U

Aluminum, Total EPA 6010B 13,000 mg/Kg, dry 7/5/11 ETK W A

Arsenic, Total TCLP EPA 6010B < 0.20 mg/L 7/5/11 ETK W A

Arsenic, Total EPA 6010B 6.8 mg/Kg, dry 7/5/11 ETK W A

Barium, Total TCLP EPA 6010B < 0.20 mg/L 7/5/11 ETK W A

Barium, Total EPA 6010B 36 mg/Kg, dry 7/5/11 ETK W A MCadmium, Total TCLP EPA 6010B < 0.020 mg/L 7/5/11 ETK W A

Cadmium, Total EPA 6010B < 0.57 mg/Kg, dry 7/5/11 ETK W A

Chromium, Hexavalent EPA 7196A < 10 mg/Kg 7/5/11 MMW W N

Chromium, Total TCLP EPA 6010B < 0.050 mg/L 7/5/11 ETK W A

Chromium, Total EPA 6010B 240 mg/Kg, dry 7/5/11 ETK W A

Copper, Total EPA 6010B 830 mg/Kg, dry 7/5/11 ETK W A

Iron, Total EPA 6010B 10,000 mg/Kg, dry 7/5/11 ETK W A

Lead, Total TCLP EPA 6010B < 0.20 mg/L 7/5/11 ETK W A

Lead, Total EPA 6010B < 5.7 mg/Kg, dry 7/5/11 ETK W A

Mercury, Total TCLP EPA 7470 < 0.010 mg/L 6/21/11 CM W A

Mercury, Total EPA 7471A < 0.082 mg/Kg, dry 6/20/11 CM W A

Nickel, Total TCLP EPA 6010B < 0.10 mg/L 7/5/11 ETK W A

Nickel, Total EPA 6010B 31 mg/Kg, dry 7/5/11 ETK W A MPlatinum, Total ICP-OES < 5 ug/g 6/21/11 SUB SW U SBV

Selenium, Total TCLP EPA 7010 < 0.020 mg/L 6/24/11 MMW W A

Selenium, Total EPA 7010 < 1.2 mg/Kg, dry 6/29/11 MMW W A

Silver, Total TCLP EPA 6010B < 0.20 mg/L 7/5/11 ETK W A QASilver, Total EPA 6010B < 5.7 mg/Kg, dry 7/5/11 ETK W A

Tin ICP-OES < 5 ug/g 6/21/11 SUB SW U SBV

Zinc, Total EPA 6010B 680 mg/Kg, dry 7/5/11 ETK W A

VOC Custom List

TCLP VOLATILES

Vinyl chloride, TCLP EPA 8260B < 20.0 ug/L 7/1/11 MGT W A

Vinyl chloride EPA 8260B < 126 ug/Kg, Dry 6/22/11 MGT W A

1,1-Dichloroethene EPA 8260B < 63.0 ug/Kg, Dry 6/22/11 MGT W A

1,1-Dichloroethene, TCLP EPA 8260B < 10.0 ug/L 7/1/11 MGT W A

2-Butanone EPA 8260B < 630 ug/Kg, Dry 6/22/11 MGT W A

2-Butanone, TCLP EPA 8260B < 100 ug/L 7/1/11 MGT W A

Chloroform, TCLP EPA 8260B < 10.0 ug/L 7/1/11 MGT W A

Chloroform EPA 8260B 155 ug/Kg, Dry 6/22/11 MGT W A

Carbon tetrachloride, TCLP EPA 8260B < 10.0 ug/L 7/1/11 MGT W A
Laboratory Report

IBM

Page 3 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-07857

06/14/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 2 Duplicate Time: 6:30 Date Sampled:6/14/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

Carbon tetrachloride EPA 8260B < 63.0 ug/Kg, Dry 6/22/11 MGT W A

Benzene, TCLP EPA 8260B < 10.0 ug/L 7/1/11 MGT W A

Benzene EPA 8260B < 63.0 ug/Kg, Dry 6/22/11 MGT W A

1,2-Dichloroethane, TCLP EPA 8260B < 10.0 ug/L 7/1/11 MGT W A

1,2-Dichloroethane EPA 8260B < 63.0 ug/Kg, Dry 6/22/11 MGT W A

Trichloroethene, TCLP EPA 8260B < 10.0 ug/L 7/1/11 MGT W A

Trichloroethene EPA 8260B < 63.0 ug/Kg, Dry 6/22/11 MGT W A

Tetrachloroethene EPA 8260B < 63.0 ug/Kg, Dry 6/22/11 MGT W A

Tetrachloroethene, TCLP EPA 8260B < 10.0 ug/L 7/1/11 MGT W A

Chlorobenzene, TCLP EPA 8260B < 10.0 ug/L 7/1/11 MGT W A

Chlorobenzene EPA 8260B < 63.0 ug/Kg, Dry 6/22/11 MGT W A

1,4-Dichlorobenzene, TCLP EPA 8260B < 10.0 ug/L 7/1/11 MGT W A

1,4-Dichlorobenzene EPA 8260B < 63.0 ug/Kg, Dry 6/22/11 MGT W A

Surr. 1 (Dibromofluoromethane) EPA 8260B 108 % 7/1/11 MGT W A

Surr. 1 (Dibromofluoromethane) EPA 8260B 30 % 6/22/11 MGT W A QSSurr. 2 (Toluene d8) EPA 8260B 99 % 6/22/11 MGT W A

Surr. 2 (Toluene d8) EPA 8260B 101 % 7/1/11 MGT W A

Surr. 3 (4-Bromofluorobenzene) EPA 8260B 112 % 6/22/11 MGT W A

Surr. 3 (4-Bromofluorobenzene) EPA 8260B 100 % 7/1/11 MGT W A

TCLP SEMI-VOLATILES

Liq/Liq Solvent Extraction EPA 3510C Completed 6/20/11 RBF W A

Pyridine, TCLP EPA 8270C < 100 ug/L 6/28/11 EEP W A

Hexachloroethane, TCLP EPA 8270C < 50.0 ug/L 6/28/11 EEP W A

Nitrobenzene, TCLP EPA 8270C < 50.0 ug/L 6/28/11 EEP W A

Hexachlorobutadiene, TCLP EPA 8270C < 50.0 ug/L 6/28/11 EEP W A

2,4-Dinitrotoluene, TCLP EPA 8270C < 50.0 ug/L 6/28/11 EEP W A

Hexachlorobenzene, TCLP EPA 8270C < 50.0 ug/L 6/28/11 EEP W A

Cresols, Total TCLP EPA 8270C < 100 ug/L 6/28/11 EEP W U

2,4,5-Trichlorophenol, TCLP EPA 8270C < 100 ug/L 6/28/11 EEP W A

2,4,6-Trichlorophenol, TCLP EPA 8270C < 100 ug/L 6/28/11 EEP W A

Pentachlorophenol, TCLP EPA 8270C < 200 ug/L 6/28/11 EEP W A

B/N Surr.1 Nitrobenzene-d5 EPA 8270C 60 % 6/28/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 62 % 6/28/11 EEP W A

B/N Surr.3 Terphenyl-d14 EPA 8270C 82 % 6/28/11 EEP W A

Acid Surr.1 2-Fluorophenol EPA 8270C 27 % 6/28/11 EEP W A

Acid Surr.2 Phenol-d8 EPA 8270C 23 % 6/28/11 EEP W A

Acid Surr.3 Tribromophenol EPA 8270C 75 % 6/28/11 EEP W A

Ultrasonic Extraction EPA 3550B Completed 6/21/11 RBF W A

Pyridine EPA 8270C < 800 ug/Kg, dry 6/28/11 EEP W A

Hexachloroethane EPA 8270C < 400 ug/Kg, dry 6/28/11 EEP W A

Nitrobenzene EPA 8270C < 400 ug/Kg, dry 6/28/11 EEP W A
Laboratory Report

IBM

Page 4 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-07857

06/14/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 2 Duplicate Time: 6:30 Date Sampled:6/14/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

Hexachlorobutadiene EPA 8270C < 400 ug/Kg, dry 6/28/11 EEP W A

2,4-Dinitrotoluene EPA 8270C < 400 ug/Kg, dry 6/28/11 EEP W A

Hexachlorobenzene EPA 8270C < 400 ug/Kg, dry 6/28/11 EEP W A

Cresols, Total EPA 8270C < 800 ug/Kg, dry 6/28/11 EEP W U

2,4,5-Trichlorophenol EPA 8270C < 800 ug/Kg, dry 6/28/11 EEP W A

2,4,6-Trichlorophenol EPA 8270C < 800 ug/Kg, dry 6/28/11 EEP W A

Pentachlorophenol EPA 8270C < 1,600 ug/Kg, dry 6/28/11 EEP W A

B/N Surr.1 Nitrobenzene-d5 EPA 8270C 61 % 6/28/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 65 % 6/28/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 65 % 6/28/11 EEP W A

Acid Surr.1 2-Fluorophenol EPA 8270C ND % 6/28/11 EEP W A QSAcid Surr.2 Phenol-d8 EPA 8270C 14 % 6/28/11 EEP W A QSAcid Surr.3 Tribromophenol EPA 8270C ND % 6/28/11 EEP W A QSReport Summary of Qualifiers and Notes

Samples were received at the laboratory with a temperature of 15.2 degrees Celsius. Samples must be received in a

cooler with sufficient ice to attain a temperature of 6 degrees Celsius or below. Samples must not be frozen.

SBV: Analysis performed by subcontracted laboratory, VHG Labs. The complete subcontracted report has been appended

to this report.

QS-: Indicates surrogate recovery was below laboratory acceptance limits, attributed to sample matrix interference.

Method 8270C: Soil Analysis: The laboratory fortified matrix (LFM) analysis indicates a potential negative bias in

all acid extractable reported values.

QA-: QA/QC associated with this analysis did not meet laboratory acceptance limits indicating the results may be

biased low.

M - : The laboratory fortified matrix (LFM) analysis indicates a potential negative bias in the reported

value.
 276 Abby Road, Manchester, NH 03103 (603) 622-7660 www.vhglabs.com

 Page 1 of 1 

 

 Endyne, Inc DATE: 6/22/2011 

Attn: Mark Westover 

160 James Brown Dr JOB NO: SO1114844 

Williston, VT 05495 

 PO NO: 06171105 

SAMPLE TYPE: Sludge 

 SAMPLE I.D.: As noted below. 

 DATE RECEIVED: 6/17/2011

 METHOD: Quantitative determination of elements by ICP-OES 

 RESULTS: Concentration in μg/g (ppm). 

 

Sample I.D. Sn Pt 

1106-07856 001 <5 <5 

1106-07857 001 <5 <5 

 

 

 

 

We certify the above analysis to be the result obtained on the samples, as received, based upon the analytical chemistry expertise and 

standard methods utilized by VHG Labs. VHG Labs, Inc. waives all responsibility for any damages resulting from the usage and/or 

implementation of the products/data described herein. This report may not be reproduced, except in full, without written approval from 

VHG Labs. 

 

 Approved By: ________________________________ 

 Julie M. MacIntosh, A/S Manager 

 Analytical Services Division
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07857

Project: Sludge Analysis Date Received: June 14, 2011

Report Date: August 8, 2011 Analysis Date: June 20, 2011

Q-List: 52242

Result as Final Value

Run Sequence Identification (ug/L) Target % Recovery mg/Kg dry

Calibration Verification: 150.002 150 100%

Independent Laboratory Fortified Blank: 59.573 63.7 93.5%

Laboratory Reagent Blank -1.937 < 10 Pass

1106-07565-001 Total -1.487 < 4

Duplicate of Sample Above: -1.9 Pass

1106-07856-001 Total -1.353 < 4

Matrix Spike of Sample Above: 82.257 80 103%

1106-07857-001 Total -1.292 < 4

Continuing Calibration Check 145.889 150 97.3%

1106-07565-001 Amenable -1.353 < 4

Duplicate of Sample Above: -1.353 Pass

1106-07856-001 Amenable 1.09 < 4

Matrix Spike of Sample Above: 0.40 < 10 Pass

1106-07857-001 Amenable -0.32 < 4

Matrix Spike of Sample Above: 2.57 < 10 Pass

QC 757-022 Amenable 62.86 63.7 98.7%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation 

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

Cyanide, Total and Amenable. EPA 9012A. Sludge.

 20%

70%-130%

80%-120%

13%-199%

Analytical Run Log

1 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07857

Project: Sludge Analysis Sample Date: June 14, 2011

Report Date: August 8, 2011 Analysis Date: July 5, 2011

Receive Date: June 14, 2011 Q-List: 52814

Result as Reported

Run Sequence Identification mg/L Target % Recovery mg/Kg

Calibration Verification: 0.093 0.1 93.0%

Independent Laboratory Fortified Blank: 0.2 0.2 100% 20.02

Laboratory Reagent Blank 0.002 < 10

1106-07565-001 0.029 *** < 10

Duplicate of Sample Above: 0.031 *** 8.8% RSD

1106-07856-001 0.033 *** < 10

Matrix Spike of Sample Above: 0.148 *** 0.233 63.6% * 22.9

1106-07857-001 0.051 *** < 10

1106-08356-001 0.011 *** < 10

1106-08833-001 0.014 *** < 10

Insoluble Matrix Spike of Sample Above: 1.023 0.935 109%** 5770

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 * Matrix Spike for sample 1106-07856 failed low. Results qualified on Final Report

 ** Matrix Spike used as passing closing QA result

 -Calibration Verification acceptance limits

 -Laboratory Fortified Blank (QC) control lim

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Dev

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

Hexavalent Chromium EPA3060A/7196A

20%

75%-125%

80%-120%

80%-120%

Analytical Run Log

 *** Analyst did not measure absobence of sample prior to addition of Diphenyl Carbazide. This resulted in an 

artificially high absorbance.

2 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07857

Project: Sludge Analysis Sample Date: June 14, 2011

Report Date: August 8, 2011 Analysis Date: June 20, 2011

Receive Date: June 14, 2011 Q-List: 52106

Result as Adjusted for

Run Sequence Identification ug/L Target % Recovery Mass Digested mg/Kg

Calibration Verification: 1.997 2 99.9%

Independent Laboratory Fortified Blank: 1.985 2 99.3% 0.496

Laboratory Reagent Blank -0.020 < 0.050

1106-07856-001 0.146 < 0.093

Duplicate of Sample Above: 0.15 PASS < 0.079

1106-07857-001 0.154 < 0.082

Matrix Spike of Sample Above: 3.056 3 102%

Continuing Calibration Check 1.998 2 99.9%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 0.20ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7471A Mercury-Soil

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

3 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07857

Project: Sludge Analysis Sample Date: June 14, 2011

Report Date: August 8, 2011 Analysis Date: June 21, 2011

Receive Date: June 14, 2011 Q-List: 52105

Result as Adjusted for dilution

Run Sequence Identification ug/L Target % Recovery mg/L

Calibration Verification: 2.012 2 101%

Independent Laboratory Fortified Blank: 1.96 2 98.0%

Laboratory Reagent Blank -0.013

1106-07565-001 -0.009 < 0.010

Duplicate of Sample Above: -0.011 PASS

1106-07856-001 -0.006 < 0.010

Matrix Spike of Sample Above: 2.019 2 101%

1106-07857-001 -0.003 < 0.010

Continuing Calibration Check 2.08 2 104%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 1.0ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7470 Mercury-TCLP

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

4 of 18
Laboratory Quality Data Report ENDYNE INC. 160 James Brown Drive

EPA 6010B- ICP Metals Soil Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Client: IBM Work Order: 1106-07857

Project: Sludge Date Received:Report Date: Analysis Date:

Q-List #: 53,655

Int. Chk. CCVA CCVR LRB LFB Duplicate 

Instrument Instrument Instrument Reported 07856-001 Instrument Reported 

Parameter PQL (% Rec) (% Rec) (% Rec) (mg/L) (% Rec) mg/L mg/Kg RPD (%) mg/L mg/Kg Aluminum-Axial 0.020 NA 97.6 0.0234 * 101 ND ND ND ND ND Aluminum-Radial 4.0 99.6 100 0.0973 ND 41.8063 9800 3.5 43.616 13000 Arsenic 0.020 NA 99.4 0.0009 99.1 0.0106 < 4.7 ND 0.0238 6.8 

Barium 0.020 95.2 97.4 -0.0016 98.8 0.1163 27 3.5 0.1259 36 

Cadmium 0.002 101 100 0.0004 100 0.0016 < 0.47 ND 0.0015 < 0.57 Chromium 0.005 103 99.1 -0.0005 99.9 0.7654 180 2.4 0.8252 240 Copper 0.020 92.2 1.05 0.0006 103 2.8659 670 4.7 2.8795 830 Iron-Axial 0.020 NA 103 0.0650 * 110 ND ND ND ND ND Iron-Radial 4.0 99.5 101 0.1324 ND 33.4643 7900 1.8 35.9537 10000 

Lead 0.020 110 101 -0.0002 102 0.011 < 4.7 ND 0.0118 < 5.7 Nickel 0.005 94.3 99.4 0.0003 101 0.1034 24 4.6 0.108 31 

Silver 0.020 91.1 101 0.0027 101 -0.0153 < 4.7 ND -0.0167 < 5.7 

Zinc 0.020 100 102 0.0045 99.9 2.262 530 4.4 2.3581 680 Notes: * Blank contamination at levels affecting quantitation. Axial line not used for sample quantitation. ** Recovery was not within method acceptance limits. Report was qualified. LRB, LFB, Duplicate & LFM were from digestion batch. Associated QA were not analyzed on the same day as the project sample. -NA: Not Available. Sample not assessed for this element. - ND: Not Determined. Sample did not have analyte within calibration range. -OR: Out-of-range. Spike concentration too low relative to sample concentration. -Bold Font indicates value outside laboratory acceptance limits -Interference Check (Int. Chk.) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits.  -Calibration Verification (CCVA) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Calibration Verification High Concentration (CCVR) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Laboratory Fortified Blank (TMLFB) acceptance limits are noted: Values were determined to be within method acceptance limits -Laboratory Reagent Blank (TMLRB) was free of contaminant affecting analytical results. Values as mg/L digested soil blank. -Duplicate relative percent difference (RPD) acceptance criteria is < 20%. Values were within method acceptance limits unless noted.  -Matrix Spike (MS) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits unless noted. 

QC Report Page 1 of 1

1106-07857-001

August 8, 2011

1106-07856-001

June 14, 2011July 5, 2011
Laboratory Quality Data Report ENDYNE INC. 160 James Brown Drive

EPA 6010B- ICP Metals TCLP Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Client: IBM Work Order: 1106-07857

Project: Sludge Analysis Date Received:Report Date: Analysis Date:

Q-List #: 52,677

Int. Chk. CCVA LFB LRB 

Instrument Reported LFM Instrument Reported Duplicate Instrume

Parameter (% Rec) (% Rec) (% Rec) (mg/L) mg/L mg/L % Recovery mg/L mg/L % RPD mg/L Arsenic NA 97.3 99.4 -0.0013 -0.0055 < 0.20 99.6 -0.0104 < 0.20 ND -0.0098 

Barium 95.2 95.9 98.9 -0.0019 0.0127 < 0.20 94.4 0.0171 < 0.20 ND 0.0197 Cadmium 101 98.5 101 0.0001 0.0001 < 0.020 95.4 0.0003 < 0.020 ND 0.0003 

Chromium 103 97.1 99.8 -0.0015 -0.0026 < 0.050 93.8 -0.0021 < 0.050 ND -0.0007 

Lead 110 98.8 102 0.0007 -0.0005 < 0.20 93.4 0.0002 < 0.20 ND -0.0006 Silver 91.1 98.5 82.9 * 0.0006 -0.0002 < 0.20 71.8 0.0005 < 0.20 ND 0.0007 

Nickel 94.3 97.1 99.5 0.0004 0.0108 0.11 90.2 0.0030 < 0.010 ND 0.0031 

Notes: * Silver LFB was not within method Acceptance Limits. Report qualified. ** Closing CCVA failed high, No samples had reportable values. Data not Qualified *** Closing CCVA failed high, Samples with reportable values were qualified. -TCLP samples are digested at a 1:10 dilution -NA: Not Available. Sample not assessed for this element. - ND: Not Determined. Sample did not have analyte above reporting limit. -Bold Font indicates value outside laboratory acceptance limits -Interference Check (Int. Chk.) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits.  -Calibration Verification (CCVA) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Calibration Verification High Concentration (CCVR) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Laboratory Fortified Blank (TMLFB) acceptance limits: 85 - 115%. Values were determined to be within method acceptance limits -Laboratory Reagent Blank (TMLRB) was free of contaminant affecting analytical results. Values as mg/L digested -Duplicate relative percent difference (RPD) acceptance criteria is < 20%. Values were within method acceptance limits unless noted.  -Matrix Spike (MS) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits unless noted. 

QC Report Page 1 of 1

June 14, 2011July 5, 2011

1106

August 8, 2011

1106-07565-001 1106-07856-001
7/12/11

VHG JOB # SO1114814 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.2 0 0 0 1.01 0.102

Instr result 10.1 0.000 0.004 <5 0.004 <5 0.987 0.1

% Recovery 99.0 97.7 98.0

Sn Theoretical 10 0 0 0 0.999 0.100

Instr result 9.99 0.000 0.017 <5 0.019 <5 0.992 0.119

% Recovery 99.9 99.3 119.0

VHG JOB # SO1114844 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.2 0.000 0.000 0.000 1.01 0.102

Instr result 10.1 0.000 -0.009 <5 -0.009 <5 0.976 0.086

% Recovery 99.0 96.6 84.3

Sn Theoretical 10.2 0.000 0.000 0.000 0.999 0.1

Instr result 10.3 0.000 0.008 <5 0.008 <5 0.982 0.113

% Recovery 101.0 98.3 113.0

VHG JOB # SO1114844 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.3 0.000 0.000 0.000 1.01 0.102

Instr result 10.3 0.000 -0.009 <5 -0.009 <5 0.976 0.086

% Recovery 100.0 96.6 84.3

Sn Theoretical 10.2 0.000 0.000 0.000 0.999 0.1

Instr result 10.3 0.000 0.008 <5 0.008 <5 0.982 0.113

% Recovery 101.0 98.3 113.0

VHG JOB # SO1115051 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.0 0.000 0.000 0.000 1.000 0.099

Instr result 9.74 0.005 0.000 <5 0.000 <5 0.976 0.089

% Recovery 97.4 97.6 89.9

Sn Theoretical 10.9 0.000 0.000 0.000 1.074 0.108

Instr result 10.7 0.008 0.005 <5 0.005 <5 1.058 0.119

% Recovery 98.2 98.5 110.2

VHG JOB # SO1115291 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10 0.000 0.000 0.000 1.000 0.099

Instr result 9.98 -0.006 -0.007 <5 -0.007 <5 0.974 0.091

% Recovery 99.8 97.4 91.9

Sn Theoretical 10.9 0.000 0.000 0.000 1.074 0.108

Instr result 10.9 0.004 0.012 6.4 0.012 4.3 1.043 0.120

% Recovery 100.0 97.1 111.1

Sample ID:1106-07857 001 Duplicate composite 

#2,bottle 005-Solids

Date Analyzed:7/8/11

Sample ID:1106-08833 001 Sample 4,bottle #5-

solid

Date Analyzed: 6/21/11

Date Analyzed: 6/29/11 Sample ID:1106-08356 001, Sample#3,bottle#5

Date Analyzed: 6/21/11

Sample ID:1106-07565 001-Sludge Sampler, 

bottle 005

Quality Report-VHG Labs

Date Analyzed: 6/21/11

Sample ID:1106-07856 001Sample 2 

Composite,bottle #5-Solids

7 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07857

Project: Sludge Analysis Sample Date: June 14, 2011

Report Date: August 8, 2011 Analysis Date: June 29, 2011

Receive Date: June 14, 2011 Q-List: 52679

Result as Adjusted for

Run Sequence Identification ug/L Target % Recovery Mass Digested mg/Kg

Calibration Verification: 10.09 10 100.9%

Independent Laboratory Fortified Blank: 21.9 20 109.5% 50.0

Laboratory Reagent Blank 0.283 < 2.5

1106-07856-001 -0.435 < 1.17

Duplicate of Sample Above: -0.858 PASS

1106-07857-001 -1.024 < 1.20

Matrix Spike of Sample Above: 16.35 20 81.8%

Continuing Calibration Check 10.03 10 100.3%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument quantitation limit is 2.0ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviati

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7010-Selenium Soil

20%

75%-125%

90%-110%

85%-115%

Analytical Run Log

8 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07857

Project: Sludge Analysis Sample Date: June 14, 2011

Report Date: August 8, 2011 Analysis Date: June 24, 2011

Receive Date June 14, 2011 Q-List: 52389

Result as Adjusted for dilution

Run Sequence Identification ug/L Target % Recovery mg/L

Calibration Verification: 10.25 10 103%

Independent Laboratory Fortified Blank: 21.04 20 105%

Laboratory Reagent Blank 0.259

1106-07565-001 -0.2468 < 0.020

Matrix Spike of Sample Above: 10.096 10 102%

1106-07856-001 -0.0917 < 0.020

Duplicate of Sample Above: -0.4179 PASS

1106-07857-001 -0.4191 < 0.020

Continuing Calibration Check 9.13 10 91.3%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 2.0ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7010-Selenium TCLP

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

9 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-07857

Project: Sludge Analysis Sample Date: June 14, 2011

Report Date: August 8, 2011 Analysis Date: June 15, 2011

Receive Date: June 14, 2011 Q-List: 52064

Result as

Run Sequence Identification (%) Target % Recovery

Laboratory Fortified Blank: 100 100 100.0%

Laboratory Reagent Blank < 0.01

Non Project Sample 0.221

Duplicate of Sample Above: 0.238 7.4% % RSD

1106-07857-001 41.4

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

Total Solids - SM18 2540G.

10%

Not Applicable

Not Applicable

99%-101%

Analytical Run Log

10 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-07857

Project: WW-Sludge Analysis Date Received: June 14, 2011

Report Date: July 27, 2011 Analysis Date: June 22, 2011

QC Report - Method 8260B, Soil

Associated Samples: 001

File: 06221102.d 06221105.d 06221106.d

Standard: Calibration Cal. Ver. Laboratory LFB Laboratory

Verification Acceptance Fortified Blank Acceptance Reagent Blank

Parameter Units: Recovery (%) Range (%) Recovery (%) Range (%) (ug/L)

Vinyl chloride 87 75 - 125 75 70 - 130 < 2.0

1,1-Dichloroethene 97 75 - 125 101 70 - 130 < 1.0

2-Butanone 76 75 - 125 99 70 - 130 < 10.0

Chloroform 99 75 - 125 102 70 - 130 < 1.0

Carbon tetrachloride 105 75 - 125 103 70 - 130 < 1.0

Benzene 109 75 - 125 97 70 - 130 < 1.0

1,2-Dichloroethane 102 75 - 125 99 70 - 130 < 1.0

Trichloroethene 105 75 - 125 106 70 - 130 < 1.0

Tetrachloroethene 100 75 - 125 93 70 - 130 < 1.0

Chlorobenzene 101 75 - 125 100 70 - 130 < 1.0

1,4-Dichlorobenzene 99 75 - 125 97 70 - 130 < 1.0

Surrogate Recovery (%)

Dibromofluoromethane S1 99 75 - 125 99 70 - 130 100

Toluene-d8 S2 101 75 - 125 99 70 - 130 99

4-Bromofluorobenzene S3 99 75 - 125 98 70 - 130 96

8260B Run Log 6/22/11

(Files Relevant to WO 1106-07857)

Sample Standard.Prep.

File Sample Number Site ID Dilution (%) Date Notes

06221101.d 25ng 8260 BFB Instrument Tune Check 6/2/11

06221102.d 20ug/L 8260B Cal Std Calibration Verification 6/17/11

06221105.d 10ug/L LFB Lab Fortified Blank (QC-Soil Matrix) 6/19/11

06221106.d LRB Lab Reagent Blank (Soil Martix) 6/19/11

06221107.d 1106-07565-001 Sludge Sampler 250uL of 19.1053g/15ml Multiplier = *93.70207

06221108.d 1106-07856-001 Sample 2 Composite 250uL of 21.0811g/15ml Multiplier = *60.35389

06221109.d 1106-07857-001 Duplicate Composite 250uL of 20.7748g/15ml Multiplier = *63.18979

06221121.d MS-07851-002 Well 2 210' - Lab Matrix Spike 100

06221122.d MSD-07851-002 Well 2 210' - Lab MS Duplicate 100

Notes:

 -Calibration Verification (CV) acceptance limits are noted. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB/QC) control limits are noted. Values were determined to be within laboratory acceptance limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Matrix Spike and MS Duplicates were performed at the appropriate frequency for the analytical batch. Analyses were performed

 on samples under a separate work order.

1106-07857 8260 Soil Page 1 of 1

11 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-07857

Project: WW-Sludge Analysis Date Received: June 14, 2011

Report Date: July 27, 2011 Analysis Date: July 1, 2011

QC Report - Method 8260B, Water (TCLP)

Associated Samples: 001

File: 06301114.d 06301115.d 06301116.d

Standard: Calibration Cal. Ver. Laboratory LFB Laboratory

Verification Acceptance Fortified Blank Acceptance Reagent Blank

Parameter Units: Recovery (%) Range (%) Recovery (%) Range (%) (ug/L)

Vinyl chloride 104 75 - 125 104 70 - 130 < 2.0

1,1-Dichloroethene 110 75 - 125 117 70 - 130 < 1.0

2-Butanone 112 75 - 125 98 70 - 130 < 10.0

Chloroform 105 75 - 125 106 70 - 130 < 1.0

Carbon tetrachloride 100 75 - 125 101 70 - 130 < 1.0

Benzene 104 75 - 125 103 70 - 130 < 1.0

1,2-Dichloroethane 107 75 - 125 108 70 - 130 < 1.0

Trichloroethene 109 75 - 125 107 70 - 130 < 1.0

Tetrachloroethene 110 75 - 125 106 70 - 130 < 1.0

Chlorobenzene 107 75 - 125 107 70 - 130 < 1.0

1,4-Dichlorobenzene 110 75 - 125 106 70 - 130 < 1.0

Surrogate Recovery (%)

Dibromofluoromethane S1 97 75 - 125 98 70 - 130 101

Toluene-d8 S2 100 75 - 125 99 70 - 130 101

4-Bromofluorobenzene S3 103 75 - 125 102 70 - 130 98

8260B Run Log 6/30/11 - 7/1/11

(Files Relevant to WO 1106-07857)

Sample Standard.Prep.

File Sample Number Site ID Dilution (%) Date Notes

06301113.d 25ng 8260 BFB Instrument Tune Check 6/27/11

06301114.d 20ug/L 8260B Cal Std Calibration Verification 6/27/11

06301115.d 10ug/L LFB Lab Fortified Blank (QC-Water Matrix) 6/20/11

06301116.d LRB Lab Reagent Blank (Water Martix) 6/27/11

06301134.d 1106-07857-001 Duplicate Composite 10

06301139.d MS-08327-006 MW 103S - Lab Matrix Spike 100

06301140.d MSD-08327-006 MW 103S - Lab MS Duplicate 100

Notes:

 -Calibration Verification (CV) acceptance limits are noted. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB/QC) control limits are noted. Values were determined to be within laboratory acceptance limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Matrix Spike and MS Duplicates were performed at the appropriate frequency for the analytical batch. Analyses were performed

 on samples under a separate work order.

1106-07857 8260 Water Page 1 of 1

12 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-07857

Project: WW-Sludge Analysis Date Received: June 14, 2011

Report Date: July 27, 2011 Analysis Date: June 28, 2011

QC Report - Method 8270C, Soil

Associated Samples: 001

File: 06271118.d 06271129.d 06271131.d 06271136.d

Standard: Calibration Laboratory LFB Laboratory Sample 001 LFM

Verification Fortified Blank Acceptance Reagent Blank Matrix Spike Acceptance Limit

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) Recovery (%) Recovery (%)

N-Nitrosodimethylamine 103.9 < 10

Pyridine 101.9 < 10

Aniline 102.1 < 10

Phenol 100.1 49.5 25.7 - 97.3 < 5 11.6 31.4 - 91.9

2-Chorophenol 97.8 54.0 29.7 - 96.2 < 5 5.1 30.1 - 94.1

bis(2-chloroethyl) Ether 95.7 < 5

1,3-Dichlorobenzene 97.0 < 2

1,4-Dichlorobenzene 96.6 52.6 31.1 - 77.7 < 2 40.9 25.7 - 80.3

1,2-Dichlorobenzene 95.7 < 2

Benzyl Alcohol 109.9 < 20

2-Methylphenol 100.0 < 5

bis(2-chloroisopropyl)ether 95.1 < 10

N-Nitrosodi-n-propylamine 95.1 59.3 45.8 - 85.1 < 10 48.9 31.5 - 86.9

3&4-Methylphenol 99.8 < 5

Hexachloroethane 94.9 < 5

Nitrobenzene 98.7 < 5

N-Nitrosopiperidine 99.9 < 10

Isophorone 98.1 < 2

2-Nitrophenol 102.3 < 10

2,4-Dimethylphenol 98.9 < 5

bis(2-chloroethoxy)Methane 96.6 < 5

2,4-Dichlorophenol 102.1 < 5

1,2,4-Trichlorobenzene 96.5 54.2 37.5 - 86.4 < 2 42.6 32.2 - 89.5

Naphthalene 96.5 < 1

4-Chloroaniline 98.5 < 5

2,6-Dichlorophenol 97.0 < 5

Hexachlorobutadiene 97.7 < 5

N-Nitrosodi-n-butylamine 115.7 < 5

4-Chloro-3-methylphenol 104.8 66.4 48.3 - 108.0 < 10 33.0 40.7 - 110.6

2-Methylnaphthalene 97.5 < 1

1-Methylnaphthalene 97.2 < 1

Hexachlorocyclopentadiene 104.8 < 20

2,4,6-Trichlorophenol 102.2 < 10

2,4,5-Trichlorophenol 103.0 < 10

2-Chloronaphthalene 89.1 < 2

1-Chloronaphthalene 99.9 < 2

2-Nitroaniline 105.4 < 20

Dimethylphthalate 96.7 < 5

2,6-Dinitrotoluene 102.9 < 5

Acenaphthylene 97.1 < 1

3-Nitroaniline 103.2 < 5

1106-07857 8270 Soil Page 1 of 3

13 of 18
QC Report - Method 8270C, Soil

Associated Samples: 001

File: 06271118.d 06271129.d 06271131.d 06271136.d

Standard: Calibration Laboratory LFB Laboratory Sample 001 LFM

Verification Fortified Blank Acceptance Reagent Blank Matrix Spike Acceptance Limit

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) RPD (%) Recovery (%)

Acenaphthene 94.4 62.2 49.0 - 95.3 < 1 53.2 41.7 - 98.8

2,4-Dinitrophenol 118.1 < 20

Dibenzofuran 97.1 < 2

4-Nitrophenol 106.0 74.7 30.3 - 98.0 < 10 0.3 24.9 - 101.3

2,4-Dinitrotoluene 104.1 70.7 47.8 - 104.9 < 5 52.5 35.6 - 101.4

1-Naphthylamine 107.9 < 10

2-Naphthylamine 93.9 < 10

Fluorene 97.0 < 1

Diethylphthalate 96.1 < 5

4-Chlorophenylphenylether 94.5 < 2

4-Nitroaniline 97.6 < 20

2-Methyl-4,6-dinitrophenol 112.8 < 20

N-Nitrosodiphenylamine 99.5 < 5

Azobenzene 98.1 < 5

4-Bromophenylphenylether 95.3 < 2

Hexachlorobenzene 93.9 < 5

Pentachlorophenol 114.1 69.5 32.4 - 120.0 < 20 0.0 41.3 - 118.5

Phenanthrene 96.4 < 1

Anthracene 97.6 < 1

Carbazole 100.4 < 10

Di-n-butylphthalate 99.6 < 10

Fluoranthene 102.7 < 1

Benzidine 115.1 < 10

Pyrene 101.1 76.8 58.2 - 108.6 < 1 71.4 49.5 - 112.8

Benzylbutylphthalate 105.3 < 5

Benzo(a)anthracene 97.3 < 1

Chrysene 97.8 < 1

3,3'-Dichlorobenzidine 102.9 < 5

bis(2-ethylhexyl)phthalate 105.3 < 5

Di-n-octylphthalate 106.0 < 10

Benzo(b)fluoranthene 100.4 < 1

Benzo(k)fluoranthene 96.9 < 1

Benzo(a)pyrene 101.6 < 1

Indeno[1,2,3-cd]pyrene 105.7 < 1

Dibenz(a,h)anthracene 105.5 < 1

Benzo(g,h,i)perylene 99.5 < 1

Surrogate Recoveries (%) LFB/LRB/Sample LFM

CV Result LFB Result Acceptance LRB Result Matrix Spike Acceptance Limit

Acid Surrogates Recovery (%) Recovery (%) Recovery (%) Recovery (%) Recovery (%) Recovery (%)

2-Fluorophenol (E.S.) 97.3 41.9 15.2 - 70.1 52.6 0.3 15.2 - 70.1

Phenol-d5 (E.S.) 99.7 55.8 29.9 - 78.3 70.3 13.6 29.9 - 78.3

2,4,6-Tribromophenol (E.S.) 101.4 68.9 47.6 - 106.3 80.8 0.0 47.6 - 106.3

B/N Surrogates

Nitrobenzene-d5 (E.S.) 97.7 56.6 17.8 - 107.4 71.6 52.5 17.8 - 107.4

2-Fluorobiphenyl (E.S.) 95.3 59.8 29.3 - 111.9 71.3 57.9 29.3 - 111.9

Terphenyl-d14 (E.S.) 100.2 81.6 48.9 - 125.7 92.7 84.4 48.9 - 125.7

1106-07857 8270 Soil Page 2 of 3

14 of 18
8270C Run Log 6/27/11 - 6/28/11

(Files Relevant to WO 1106-07857)

Sample Final Prep/Extraction

File Sample Number Site ID Volume Volume Date

06271102.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

06271103.d 80ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271104.d 70ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271105.d 60ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271106.d 50ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271107.d 40ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271108.d 30ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271109.d 20ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271110.d 15ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271111.d 10ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271112.d 5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271113.d 2ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271114.d 1ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271115.d 0.5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271117.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

06271118.d 50ug 8270C Cal Std 12/21/10 Calibration Verification 4.0ml 6/6/11

06271129.d LFB Lab Fortified Blank (QC) 30.21g 4.0ml 6/21/11

06271131.d LRB Lab Reagent Blank 30.03g 4.0ml 6/21/11

06271132.d 1106-07565-001 Sludge Sampler 30.43g 4.0ml 6/21/11

06271133.d 1106-07856-001 Sample 2 Comp 30.57g 4.0ml 6/21/11

06271134.d 1106-07857-001 Duplicate 30.04g 4.0ml 6/21/11

06271135.d Dup-07565-001 Lab Duplicate - Sludge Sampler 30.23g 4.0ml 6/21/11

06271136.d MS-07857-001 Lab Matrix Spike - Duplicate 30.36g 4.0ml 6/21/11

Notes:

 -Bold Font indicates value outside laboratory acceptance limits

 -Calibration Verification (CV) acceptance limits: 80 - 120%. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB) control limits are noted. Values were determined to be within laboratory control limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicates were performed at the appropriate frequency for the extraction batch. Analyses were performed on samples under a separate

 work order.

 -Matrix Spikes (LFM) control limits are noted. Values were determined to be within laboratory control limits unless noted.

 -Nonconforming QC Elements: Acid extractable compound and surrogate recoveries were out of range in the matrix spike analysis.

 Data was qualified in the work order conclusion.

1106-07857 8270 Soil Page 3 of 3

15 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-07857

Project: WW-Sludge Analysis Date Received: June 14, 2011

Report Date: July 27, 2011 Analysis Date: June 28, 2011

QC Report - Method 8270C, Water

Associated Samples: 001

File: 06271118.d 06271120.d 06271121.d

Standard: Calibration Laboratory LFB Laboratory

Verification Fortified Blank Acceptance Reagent Blank

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug)

N-Nitrosodimethylamine 103.9 < 10

Pyridine 101.9 < 10

Aniline 102.1 < 10

Phenol 100.1 21.8 13.9 - 36.0 < 5

2-Chorophenol 97.8 53.6 38.9 - 87.4 < 5

bis(2-chloroethyl) Ether 95.7 < 5

1,3-Dichlorobenzene 97.0 < 2

1,4-Dichlorobenzene 96.6 37.7 23.2 - 73.2 < 2

1,2-Dichlorobenzene 95.7 < 2

Benzyl Alcohol 109.9 < 20

2-Methylphenol 100.0 < 5

bis(2-chloroisopropyl)ether 95.1 < 10

N-Nitrosodi-n-propylamine 95.1 56.0 44.7 - 87.3 < 10

3&4-Methylphenol 99.8 < 5

Hexachloroethane 94.9 < 5

Nitrobenzene 98.7 < 5

N-Nitrosopiperidine 99.9 < 10

Isophorone 98.1 < 2

2-Nitrophenol 102.3 < 10

2,4-Dimethylphenol 98.9 < 5

bis(2-chloroethoxy)Methane 96.6 < 5

2,4-Dichlorophenol 102.1 < 5

1,2,4-Trichlorobenzene 96.5 41.9 30.3 - 81.8 < 2

Naphthalene 96.5 < 1

4-Chloroaniline 98.5 < 5

2,6-Dichlorophenol 97.0 < 5

Hexachlorobutadiene 97.7 < 5

N-Nitrosodi-n-butylamine 115.7 < 5

4-Chloro-3-methylphenol 104.8 63.1 45.0 - 115.3 < 10

2-Methylnaphthalene 97.5 < 1

1-Methylnaphthalene 97.2 < 1

Hexachlorocyclopentadiene 104.8 < 20

2,4,6-Trichlorophenol 102.2 < 10

2,4,5-Trichlorophenol 103.0 < 10

2-Chloronaphthalene 89.1 < 2

1-Chloronaphthalene 99.9 < 2

2-Nitroaniline 105.4 < 20

Dimethylphthalate 96.7 < 5

2,6-Dinitrotoluene 102.9 < 5

Acenaphthylene 97.1 < 1

3-Nitroaniline 103.2 < 5

1106-07857 8270 Water Page 1 of 3

16 of 18
QC Report - Method 8270C, Water

Associated Samples: 001

File: 06271118.d 06271120.d 06271121.d

Standard: Calibration Laboratory LFB Laboratory

Verification Fortified Blank Acceptance Reagent Blank

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug)

Acenaphthene 94.4 59.7 45.3 - 98.4 < 1

2,4-Dinitrophenol 118.1 < 20

Dibenzofuran 97.1 < 2

4-Nitrophenol 106.0 34.2 13.7 - 59.3 < 10

2,4-Dinitrotoluene 104.1 65.5 46.2 - 101.1 < 5

1-Naphthylamine 107.9 < 10

2-Naphthylamine 93.9 < 10

Fluorene 97.0 < 1

Diethylphthalate 96.1 < 5

4-Chlorophenylphenylether 94.5 < 2

4-Nitroaniline 97.6 < 20

2-Methyl-4,6-dinitrophenol 112.8 < 20

N-Nitrosodiphenylamine 99.5 < 5

Azobenzene 98.1 < 5

4-Bromophenylphenylether 95.3 < 2

Hexachlorobenzene 93.9 < 5

Pentachlorophenol 114.1 70.3 42.1 - 135.5 < 20

Phenanthrene 96.4 < 1

Anthracene 97.6 < 1

Carbazole 100.4 < 10

Di-n-butylphthalate 99.6 < 10

Fluoranthene 102.7 < 1

Benzidine 115.1 < 10

Pyrene 101.1 78.1 61.8 - 121.9 < 1

Benzylbutylphthalate 105.3 < 5

Benzo(a)anthracene 97.3 < 1

Chrysene 97.8 < 1

3,3'-Dichlorobenzidine 102.9 < 5

bis(2-ethylhexyl)phthalate 105.3 < 5

Di-n-octylphthalate 106.0 < 10

Benzo(b)fluoranthene 100.4 < 1

Benzo(k)fluoranthene 96.9 < 1

Benzo(a)pyrene 101.6 < 1

Indeno[1,2,3-cd]pyrene 105.7 < 1

Dibenz(a,h)anthracene 105.5 < 1

Benzo(g,h,i)perylene 99.5 < 1

Surrogate Recoveries (%) LFB/LRB/Sample

CV Result LFB Result Acceptance LRB Result

Acid Surrogates Recovery (%) Recovery (%) Recovery (%) Recovery (%)

2-Fluorophenol (E.S.) 97.3 32.3 16.2 - 49.9 32.2

Phenol-d5 (E.S.) 99.7 26.3 11.1 - 42.3 26.7

2,4,6-Tribromophenol (E.S.) 101.4 73.9 44.6 - 123.6 85.1

B/N Surrogates

Nitrobenzene-d5 (E.S.) 97.7 64.4 34.3 - 106.9 70.0

2-Fluorobiphenyl (E.S.) 95.3 67.0 30.7 - 102.3 72.3

Terphenyl-d14 (E.S.) 100.2 88.4 55.0 - 133.1 96.3

1106-07857 8270 Water Page 2 of 3

17 of 18
8270C Run Log 6/27/11 - 6/28/11

(Files Relevant to WO 1106-07857)

Sample Final Prep/Extraction

File Sample Number Site ID Volume Volume Date

06271102.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

06271103.d 80ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271104.d 70ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271105.d 60ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271106.d 50ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271107.d 40ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271108.d 30ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271109.d 20ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271110.d 15ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271111.d 10ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271112.d 5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271113.d 2ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271114.d 1ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271115.d 0.5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

06271117.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

06271118.d 50ug 8270C Cal Std 12/21/10 Calibration Verification 4.0ml 6/6/11

06271120.d LFB Lab Fortified Blank (QC) 0.10L 4.0ml 6/20/11

06271121.d LRB Lab Reagent Blank 0.10L 4.0ml 6/20/11

06271122.d 1106-07565-001 Sludge Sampler 0.10L 4.0ml 6/20/11

06271123.d 1106-07856-001 Sample 2 Comp 0.10L 4.0ml 6/20/11

06271124.d 1106-07857-001 Duplicate 0.10L 4.0ml 6/20/11

06271125.d Dup-07565-001 Lab Duplicate Sludge Sampler 0.10L 4.0ml 6/20/11

06271126.d MS-07856-001 Lab Matrix SpikeSample 2 Comp 0.10L 4.0ml 6/20/11

Notes:

 -Calibration Verification (CV) acceptance limits: 80 - 120%. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB) control limits are noted. Values were determined to be within laboratory control limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicates were performed at the appropriate frequency for the extraction batch. Analyses were performed on samples under a separate

 work order.

 -Matrix Spikes were performed at the appropriate frequency for the extraction batch. Analyses were performed on samples under a separate

 work order.

1106-07857 8270 Water Page 3 of 3

18 of 18

Laboratory Report

PROJECT: Sludge Analysis

DATE RECEIVED:

WORK ORDER:

DATE REPORTED:

100290

IBM

Mail Stop 966A

Essex Jct, VT 05452

Atten: Dave Kost SAMPLER:

August 08, 2011

1106-08356

Not Indicated

June 22, 2011

Enclosed please find the results of the analyses performed for the samples referenced on the 

attached chain of custody. All required method quality control elements including 

instrument calibration were performed in accordance with method requirements and 

determined to be acceptable unless otherwise noted. 

The column labeled Lab/Tech in the accompanying report denotes the laboratory facility 

where the testing was performed and the technician who conducted the assay. A "W" designates 

the Williston, VT lab under NELAC certification ELAP 11263; "R" designates the Lebanon, NH 

facility under certification NH 2037 and “N” the Plattsburgh, NY lab under certification ELAP 

11892. “Sub” indicates the testing was performed by a subcontracted laboratory. The 

accreditation status of the subcontracted lab is referenced in the corresponding NELAC and Qual 

fields. 

The NELAC column also denotes the accreditation status of each laboratory for each 

reported parameter. “A” indicates the referenced laboratory is NELAC accredited for the 

parameter reported. “N” indicates the laboratory is not accredited. “U” indicates that NELAC 

does not offer accreditation for that parameter in that specific matrix. Test results denoted with an 

“A” meet all National Environmental Laboratory Accreditation Program requirements except 

where denoted by pertinent data qualifiers. Test results are representative of the samples as they 

were received at the laboratory 

Endyne, Inc. warrants, to the best of its knowledge and belief, the accuracy of the analytical 

test results contained in this report, but makes no other warranty, expressed or implied, especially 

no warranties of merchantability or fitness for a particular purpose. 

Page 1 of 4

Reviewed by:

Harry B. Locker, Ph.D.

Laboratory Director

 ELAP 11263

160 James Brown Dr., Williston, VT 05495

Ph 802-879-4333 Fax 802-879-7103

www.endynelabs.com

NH2037

56 Etna Road, Lebanon, NH 03766 

Ph 603-678-4891 Fax 603-678-4893
Laboratory Report

IBM

Page 2 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-08356

06/22/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 3 Composite Time: 6:15 Date Sampled:6/21/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

TCLP Extract-VOA ZHE EPA 1311 Completed 7/8/11 MMW W AE

TCLP Extract-SVOA/Metals EPA 1311 Completed 6/29/11 MMW W A

Cyanide, Total EPA 9012A < 3 mg/Kg, dry 7/1/11 CAL N A

Cyanide, Total Amenable SM 4500-CN G < 3 mg/kg, dry 7/1/11 CAL N U

Solids, Total SM18 2540G 39.0 % 6/27/11 JSS W U

Aluminum, Total EPA 6010B 14,000 mg/Kg, dry 7/29/11 ETK W A

Arsenic, Total TCLP EPA 6010B < 0.20 mg/L 7/12/11 RJL W A

Arsenic, Total EPA 6010B 7.5 mg/Kg, dry 7/29/11 ETK W A

Barium, Total TCLP EPA 6010B < 0.20 mg/L 7/12/11 RJL W A

Barium, Total EPA 6010B 34 mg/Kg, dry 7/29/11 ETK W A

Cadmium, Total TCLP EPA 6010B < 0.020 mg/L 7/12/11 RJL W A

Cadmium, Total EPA 6010B < 0.51 mg/Kg, dry 7/29/11 ETK W A

Chromium, Hexavalent EPA 7196A < 10 mg/Kg 7/5/11 MMW W N

Chromium, Total TCLP EPA 6010B < 0.050 mg/L 7/12/11 RJL W A

Chromium, Total EPA 6010B 280 mg/Kg, dry 7/29/11 ETK W A

Copper, Total EPA 6010B 1,200 mg/Kg, dry 7/29/11 ETK W A

Iron, Total EPA 6010B 9,100 mg/Kg, dry 7/29/11 ETK W A

Lead, Total TCLP EPA 6010B < 0.20 mg/L 7/12/11 RJL W A

Lead, Total EPA 6010B 5.6 mg/Kg, dry 7/29/11 ETK W A

Mercury, Total TCLP EPA 7470 < 0.010 mg/L 7/6/11 CM W A

Mercury, Total EPA 7471A 0.067 mg/Kg, dry 6/28/11 CM W A

Nickel, Total TCLP EPA 6010B < 0.10 mg/L 7/12/11 RJL W A

Nickel, Total EPA 6010B 49 mg/Kg, dry 7/29/11 ETK W A

Platinum, Total ICP-OES < 5 ug/g 6/29/11 SUB SW U SBV

Selenium, Total TCLP EPA 7010 < 0.020 mg/L 7/8/11 MMW W A

Selenium, Total EPA 7010 < 1.3 mg/Kg, dry 6/29/11 MMW W A

Silver, Total TCLP EPA 6010B < 0.20 mg/L 7/12/11 RJL W A QASilver, Total EPA 6010B < 5.1 mg/Kg, dry 7/29/11 ETK W A

Tin ICP-OES < 5 ug/g 6/29/11 SUB SW U SBV

Zinc, Total EPA 6010B 930 mg/Kg, dry 7/29/11 ETK W A

VOC Custom List

TCLP VOLATILES

Vinyl chloride EPA 8260B < 134 ug/Kg, Dry 7/1/11 MGT W A

Vinyl chloride, TCLP EPA 8260B < 20.0 ug/L 7/13/11 MGT W A

1,1-Dichloroethene EPA 8260B < 67.0 ug/Kg, Dry 7/1/11 MGT W A

1,1-Dichloroethene, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

2-Butanone, TCLP EPA 8260B < 100 ug/L 7/13/11 MGT W A

2-Butanone EPA 8260B < 670 ug/Kg, Dry 7/1/11 MGT W A

Chloroform EPA 8260B < 67.0 ug/Kg, Dry 7/1/11 MGT W A

Chloroform, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

Carbon tetrachloride, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A
Laboratory Report

IBM

Page 3 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-08356

06/22/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 3 Composite Time: 6:15 Date Sampled:6/21/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

Carbon tetrachloride EPA 8260B < 67.0 ug/Kg, Dry 7/1/11 MGT W A

Benzene, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

Benzene EPA 8260B < 67.0 ug/Kg, Dry 7/1/11 MGT W A

1,2-Dichloroethane EPA 8260B < 67.0 ug/Kg, Dry 7/1/11 MGT W A

1,2-Dichloroethane, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

Trichloroethene, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

Trichloroethene EPA 8260B < 67.0 ug/Kg, Dry 7/1/11 MGT W A

Tetrachloroethene EPA 8260B < 67.0 ug/Kg, Dry 7/1/11 MGT W A

Tetrachloroethene, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

Chlorobenzene, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

Chlorobenzene EPA 8260B < 67.0 ug/Kg, Dry 7/1/11 MGT W A

1,4-Dichlorobenzene, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

1,4-Dichlorobenzene EPA 8260B < 67.0 ug/Kg, Dry 7/1/11 MGT W A

Surr. 1 (Dibromofluoromethane) EPA 8260B 79 % 7/1/11 MGT W A

Surr. 1 (Dibromofluoromethane) EPA 8260B 106 % 7/13/11 MGT W A

Surr. 2 (Toluene d8) EPA 8260B 99 % 7/13/11 MGT W A

Surr. 2 (Toluene d8) EPA 8260B 99 % 7/1/11 MGT W A

Surr. 3 (4-Bromofluorobenzene) EPA 8260B 98 % 7/13/11 MGT W A

Surr. 3 (4-Bromofluorobenzene) EPA 8260B 104 % 7/1/11 MGT W A

TCLP SEMI-VOLATILES

Liq/Liq Solvent Extraction EPA 3510C Completed 7/1/11 MDP W A

Pyridine, TCLP EPA 8270C < 100 ug/L 7/8/11 EEP W A

Hexachloroethane, TCLP EPA 8270C < 50.0 ug/L 7/8/11 EEP W A

Nitrobenzene, TCLP EPA 8270C < 50.0 ug/L 7/8/11 EEP W A

Hexachlorobutadiene, TCLP EPA 8270C < 50.0 ug/L 7/8/11 EEP W A

2,4-Dinitrotoluene, TCLP EPA 8270C < 50.0 ug/L 7/8/11 EEP W A

Hexachlorobenzene, TCLP EPA 8270C < 50.0 ug/L 7/8/11 EEP W A

Cresols, Total TCLP EPA 8270C < 100 ug/L 7/8/11 EEP W U

2,4,5-Trichlorophenol, TCLP EPA 8270C < 100 ug/L 7/8/11 EEP W A

2,4,6-Trichlorophenol, TCLP EPA 8270C < 100 ug/L 7/8/11 EEP W A

Pentachlorophenol, TCLP EPA 8270C < 200 ug/L 7/8/11 EEP W A

B/N Surr.1 Nitrobenzene-d5 EPA 8270C 61 % 7/8/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 67 % 7/8/11 EEP W A

B/N Surr.3 Terphenyl-d14 EPA 8270C 94 % 7/8/11 EEP W A

Acid Surr.1 2-Fluorophenol EPA 8270C 29 % 7/8/11 EEP W A

Acid Surr.2 Phenol-d8 EPA 8270C 24 % 7/8/11 EEP W A

Acid Surr.3 Tribromophenol EPA 8270C 81 % 7/8/11 EEP W A

Ultrasonic Extraction EPA 3550B Completed 6/30/11 MDP W A

Pyridine EPA 8270C < 830 ug/Kg, dry 7/9/11 EEP W A

Hexachloroethane EPA 8270C < 415 ug/Kg, dry 7/9/11 EEP W A

Nitrobenzene EPA 8270C < 415 ug/Kg, dry 7/9/11 EEP W A
Laboratory Report

IBM

Page 4 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-08356

06/22/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 3 Composite Time: 6:15 Date Sampled:6/21/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

Hexachlorobutadiene EPA 8270C < 415 ug/Kg, dry 7/9/11 EEP W A

2,4-Dinitrotoluene EPA 8270C < 415 ug/Kg, dry 7/9/11 EEP W A

Hexachlorobenzene EPA 8270C < 415 ug/Kg, dry 7/9/11 EEP W A

Cresols, Total EPA 8270C < 830 ug/Kg, dry 7/9/11 EEP W U

2,4,5-Trichlorophenol EPA 8270C < 830 ug/Kg, dry 7/9/11 EEP W A

2,4,6-Trichlorophenol EPA 8270C < 830 ug/Kg, dry 7/9/11 EEP W A

Pentachlorophenol EPA 8270C < 1,660 ug/Kg, dry 7/9/11 EEP W A

B/N Surr.1 Nitrobenzene-d5 EPA 8270C 50 % 7/9/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 55 % 7/9/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 55 % 7/9/11 EEP W A

Acid Surr.1 2-Fluorophenol EPA 8270C ND % 7/9/11 EEP W A QSAcid Surr.2 Phenol-d8 EPA 8270C 12 % 7/9/11 EEP W A QSAcid Surr.3 Tribromophenol EPA 8270C ND % 7/9/11 EEP W A QSReport Summary of Qualifiers and Notes

SBV: Analysis performed by subcontracted laboratory, VHG Labs. The complete subcontracted report has been appended

to this report.

E: Sample was TCLP extracted past method specified holding time.

QS-: Indicates surrogate recovery was below laboratory acceptance limits.

QA-: QA/QC associated with this analysis did not meet laboratory acceptance limits indicating the results may be

biased low.
 276 Abby Road, Manchester, NH 03103 (603) 622-7660 www.vhglabs.com

 Page 1 of 1 

 

 Endyne, Inc DATE: 7/1/2011 

Attn: Mark Westover 

160 James Brown Dr JOB NO: SO1115051 

Williston, VT 05495 

 PO NO: Mark Westover 

SAMPLE TYPE: Sludge 

 SAMPLE I.D.: 1106-08356 001 Sample 3 Bottle #005 

 DATE RECEIVED: 6/24/2011

 METHOD: Quantitative determination of elements by ICP-OES 

 RESULTS: Concentration in μg/g (ppm). 

 

Sample I.D. Sn Pt 

1106-08356 001 Sample 3 

Bottle #005 

<5 <5 

 

 

 

 

 

We certify the above analysis to be the result obtained on the samples, as received, based upon the analytical chemistry expertise and 

standard methods utilized by VHG Labs. VHG Labs, Inc. waives all responsibility for any damages resulting from the usage and/or 

implementation of the products/data described herein. This report may not be reproduced, except in full, without written approval from 

VHG Labs. 

 

 Approved By: ________________________________ 

 Julie M. MacIntosh, A/S Manager 

 Analytical Services Division
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

SM20 4500-CN G. Amenable Cyanide Soil

Client: IBM Work Order: 1106-08356

Project: Sludge Analysis Date Received: June 22, 2011

Report Date: August 8, 2011 Analysis Date: June 30, 2011

Q-List: 52596

Result as

Run Sequence Identification ug/L * Target % Recovery Final Value mg/Kg

Calibration Verification: 145.896 150 97.3%

Independent Laboratory Fortified Blank: 64.998 63.7 102%

Laboratory Reagent Blank -3.147 < 10

1106-08356-001 Amenable -0.22 < 3

Duplicate of Sample Above -0.331 Pass

1106-08833-001 Amenable 0.867 < 3

Matrix Spike of Sample Above 0.965 < 10 Pass

Lab Fortified Blank Amenable 6.734 < 10 Pass

1106-08356-001 Total -0.524 < 3

Duplicate of Sample Above -0.631 Pass

1106-08833-001 Total -1.531 < 3

Matrix Spike of Sample Above 70.056 80 88%

Continuing Calibration Check 153.332 150 102%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 Matrix Spike of Amenable Cyanide should have no analyte recovery.

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 9012A Total Cyanide Soil

 20%

70%-130%

80%-120%

13%-199%

Analytical Run Log

1 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-08356

Project: Sludge Analysis Sample Date: June 21, 2011

Report Date: August 8, 2011 Analysis Date: July 5, 2011

Receive Date: June 22, 2011 Q-List: 52814

Result as Reported

Run Sequence Identification mg/L Target % Recovery mg/Kg

Calibration Verification: 0.093 0.1 93.0%

Independent Laboratory Fortified Blank: 0.2 0.2 100% 20.02

Laboratory Reagent Blank 0.002 < 10

1106-07565-001 0.029 *** < 10

Duplicate of Sample Above: 0.031 *** 8.8% RSD

1106-07856-001 0.033 *** < 10

Matrix Spike of Sample Above: 0.148 *** 0.233 63.6% * 22.9

1106-07857-001 0.051 *** < 10

1106-08356-001 0.011 *** < 10

1106-08833-001 0.014 *** < 10

Insoluble Matrix Spike of Sample Above: 1.023 0.935 109%** 5770

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 * Matrix Spike for sample 1106-07856 failed low. Results qualified on Final Report

 ** Matrix Spike used as passing closing QA result

 -Calibration Verification acceptance limits

 -Laboratory Fortified Blank (QC) control lim

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Dev

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

Hexavalent Chromium EPA3060A/7196A

20%

75%-125%

80%-120%

80%-120%

Analytical Run Log

 *** Analyst did not measure absobence of sample prior to addition of Diphenyl Carbazide. This resulted in an 

artificially high absorbance.

2 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-08356

Project: Sludge Analysis Sample Date: June 21, 2011

Report Date: August 8, 2011 Analysis Date: June 28, 2011

Receive Date: June 22, 2011 Q-List: 52436

Result as Adjusted for

Run Sequence Identification ug/L Target % Recovery Mass Digested mg/Kg

Calibration Verification: 2.037 2 102%

Independent Laboratory Fortified Blank: 2.100 2 105% 0.525

Laboratory Reagent Blank 0.000 < 0.050

1106-08356-001 0.244 0.067

Duplicate of Sample Above: 0.229 5.8% RSD 0.071

Matrix Spike of Sample Above: 3.073 3 94.0% 0.863

Continuing Calibration Check 2.071 2 104%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 0.20ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7471A Mercury-Soil

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

3 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-08356

Project: Sludge Analysis Sample Date: June 21, 2011

Report Date: August 8, 2011 Analysis Date: July 6, 2011

Receive Date: June 22, 2011 Q-List: 52640

Result as Adjusted for dilution

Run Sequence Identification ug/L Target % Recovery mg/L

Calibration Verification: 2.019 2 101%

Independent Laboratory Fortified Blank: 2.014 2 101%

Laboratory Reagent Blank -0.014

1106-08356-001 0.005 < 0.010

Non-Project Sample -0.014 < 0.010

Matrix Spike of Sample Above: 2.064 2 104%

Continuing Calibration Check 2.021 2 101%

1106-8833-001 0.002 < 0.010

Non-Project Sample 0.007 < 0.010

Duplicate of Sample Above: 0.004 PASS

Continuing Calibration Check 2.047 2 102%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 1.0ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7470 Mercury-TCLP

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

4 of 18
Laboratory Quality Data Report ENDYNE INC. 160 James Brown Drive

EPA 6010B- ICP Metals Soil Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Client: IBM Work Order: 1106-08356

Project: Sludge Date Received:Report Date: Analysis Date:

Q-List #: 53,665

Int. Chk. CCVA CCVR LFB LRB Duplicate LFM CCVA CCV

Instrument Instrument 07856-001 07857-001 Instrument Reported

Parameter PQL (% Rec) (% Rec) (% Rec) (% Rec) (mg/L) RPD (%) (% Rec) mg/L mg/Kg (% Rec) (% RAluminum-Axial 0.020 NA 97.8 101 0.0234 * ND ND ND ND 103

Aluminum-Radial 4.0 96.6 99.5 ND 0.0973 3.5 OR 55.4246 14000 93.

Arsenic 0.020 NA 95.7 99.1 0.0009 ND 80.1 0.0294 7.5 98.1

Barium 0.020 85.2 98.9 98.8 -0.0016 3.5 44.1 ** 0.1337 34 97.7

Cadmium 0.002 105 98 100 0.0004 ND 98 0.0014 < 0.51 98.8

Chromium 0.005 112 99.4 99.9 -0.0005 2.4 OR 1.0884 280 107

Copper 0.020 88.2 98 103 0.0006 4.7 OR 4.5913 1200 97.6

Iron-Axial 0.020 NA 99.6 110 0.0650 * ND ND ND ND 99.5Iron-Radial 4.0 95.7 100 ND 0.1324 1.8 OR 35.6467 9100 93.Lead 0.020 111 94.8 102 -0.0002 ND 89.4 0.0219 5.6 96.3Nickel 0.005 108 101 101 0.0003 4.6 46.4 ** 0.1902 49 101

Silver 0.020 96.4 100 101 0.0027 ND 75.7 -0.228 < 5.1 99.8Zinc 0.020 101 95.2 99.9 0.0045 4.4 OR 3.6539 930 97Notes: * Blank contamination at levels affecting quantitation. Axial line not used for sample quantitation. ** Recovery was not within method acceptance limits. Report was qualified. LRB, LFB, Duplicate & LFM were from digestion batch. Associated QA were not analyzed on the same day as the project sample. -NA: Not Available. Sample not assessed for this element. - ND: Not Determined. Sample did not have analyte within calibration range. -OR: Out-of-range. Spike concentration too low relative to sample concentration. -Bold Font indicates value outside laboratory acceptance limits -Interference Check (Int. Chk.) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits.  -Calibration Verification (CCVA) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Calibration Verification High Concentration (CCVR) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Laboratory Fortified Blank (TMLFB) acceptance limits are noted: Values were determined to be within method acceptance limits -Laboratory Reagent Blank (TMLRB) was free of contaminant affecting analytical results. Values as mg/L digested soil blank. -Duplicate relative percent difference (RPD) acceptance criteria is < 20%. Values were within method acceptance limits unless noted.  -Matrix Spike (MS) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits unless noted. 

QC Report Page 1 of 1

August 8, 2011

1106-08356-001

June 22, 2011July 29, 2011
Laboratory Quality Data Report ENDYNE INC. 160 James Brown Drive

EPA 6010B- ICP Metals TCLP Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Client: IBM Work Order: 1106-08356

Project: Sludge Analysis Date Received:Report Date: Analysis Date:

Q-List #: 52,913

Int. Chk. CCVA LFB LRB 

Instrument Reported Duplicate Instrument Reported LFM Instrument 

Parameter (% Rec) (% Rec) (% Rec) (mg/L) mg/L mg/L % RPD mg/L mg/L % Recovery mg/L Arsenic NA 98.2 95.1 -0.0085 -0.0101 < 0.20 ND -0.0103 < 0.20 104 -0.0105 Barium 85.2 99.5 98.1 -0.0036 0.0164 < 0.20 ND 0.102 < 0.20 92.4 0.0064 Cadmium 94.4 101 98.7 -0.0001 -0.0003 < 0.020 ND -0.003 < 0.020 103 0.0001 

Chromium 91.8 102 101 -0.0004 -0.0017 < 0.050 ND -0.003 < 0.050 98.8 -0.0031 Lead 102 99.4 97.9 -0.0022 -0.0037 < 0.20 ND -0.0026 < 0.20 100 -0.0038 Silver 90.4 101 68.1 * -0.0004 0.0005 < 0.20 ND 0.0004 < 0.20 99 -0.0029 

Nickel 96.7 98.6 96.4 -0.0012 0.0019 < 0.10 ND NA NA NA 0.0026 

Notes: * Silver LFB was not within method Acceptance Limits. Report qualified. -TCLP samples are digested at a 1:10 dilution -NA: Not Available. Sample not assessed for this element. - ND: Not Determined. Sample did not have analyte above reporting limit. -Bold Font indicates value outside laboratory acceptance limits -Interference Check (Int. Chk.) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits.  -Calibration Verification (CCVA) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Calibration Verification High Concentration (CCVR) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Laboratory Fortified Blank (TMLFB) acceptance limits: 85 - 115%. Values were determined to be within method acceptance limits -Laboratory Reagent Blank (TMLRB) was free of contaminant affecting analytical results. Values as mg/L digested -Duplicate relative percent difference (RPD) acceptance criteria is < 20%. Values were within method acceptance limits unless noted.  -Matrix Spike (MS) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits unless noted. 

QC Report Page 1 of 1

June 22, 2011July 12, 2011

1106-08

August 8, 2011

1106-08356-001 Non-project Sample
7/12/11

VHG JOB # SO1114814 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.2 0 0 0 1.01 0.102

Instr result 10.1 0.000 0.004 <5 0.004 <5 0.987 0.1

% Recovery 99.0 97.7 98.0

Sn Theoretical 10 0 0 0 0.999 0.100

Instr result 9.99 0.000 0.017 <5 0.019 <5 0.992 0.119

% Recovery 99.9 99.3 119.0

VHG JOB # SO1114844 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.2 0.000 0.000 0.000 1.01 0.102

Instr result 10.1 0.000 -0.009 <5 -0.009 <5 0.976 0.086

% Recovery 99.0 96.6 84.3

Sn Theoretical 10.2 0.000 0.000 0.000 0.999 0.1

Instr result 10.3 0.000 0.008 <5 0.008 <5 0.982 0.113

% Recovery 101.0 98.3 113.0

VHG JOB # SO1114844 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.3 0.000 0.000 0.000 1.01 0.102

Instr result 10.3 0.000 -0.009 <5 -0.009 <5 0.976 0.086

% Recovery 100.0 96.6 84.3

Sn Theoretical 10.2 0.000 0.000 0.000 0.999 0.1

Instr result 10.3 0.000 0.008 <5 0.008 <5 0.982 0.113

% Recovery 101.0 98.3 113.0

VHG JOB # SO1115051 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.0 0.000 0.000 0.000 1.000 0.099

Instr result 9.74 0.005 0.000 <5 0.000 <5 0.976 0.089

% Recovery 97.4 97.6 89.9

Sn Theoretical 10.9 0.000 0.000 0.000 1.074 0.108

Instr result 10.7 0.008 0.005 <5 0.005 <5 1.058 0.119

% Recovery 98.2 98.5 110.2

VHG JOB # SO1115291 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10 0.000 0.000 0.000 1.000 0.099

Instr result 9.98 -0.006 -0.007 <5 -0.007 <5 0.974 0.091

% Recovery 99.8 97.4 91.9

Sn Theoretical 10.9 0.000 0.000 0.000 1.074 0.108

Instr result 10.9 0.004 0.012 6.4 0.012 4.3 1.043 0.120

% Recovery 100.0 97.1 111.1

Sample ID:1106-07857 001 Duplicate composite 

#2,bottle 005-Solids

Date Analyzed:7/8/11

Sample ID:1106-08833 001 Sample 4,bottle #5-

solid

Date Analyzed: 6/21/11

Date Analyzed: 6/29/11 Sample ID:1106-08356 001, Sample#3,bottle#5

Date Analyzed: 6/21/11

Sample ID:1106-07565 001-Sludge Sampler, 

bottle 005

Quality Report-VHG Labs

Date Analyzed: 6/21/11

Sample ID:1106-07856 001Sample 2 

Composite,bottle #5-Solids

7 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-08356

Project: Sludge Analysis Sample Date: June 21, 2011

Report Date: August 8, 2011 Analysis Date: June 29, 2011

Receive Date: June 22 2011 Q-List: 52679

Result as Adjusted for

Run Sequence Identification ug/L Target % Recovery Mass Digested mg/Kg

Calibration Verification: 10.09 10 100.9%

Independent Laboratory Fortified Blank: 21.9 20 109.5% 50.0

Laboratory Reagent Blank 0.283 < 2.5

1106-07856-001 -0.435 < 1.17

Duplicate of Sample Above: -0.858 PASS

1106-07857-001 -1.024 < 1.20

Matrix Spike of Sample Above: 16.35 20 81.8%

Continuing Calibration Check 10.03 10 100.3%

1106-08356-001 -1.027 < 1.28

Continuing Calibration Check 9.54 10 95.4%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument quantitation limit is 2.0ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviatio

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7010-Selenium Soil

20%

75%-125%

90%-110%

85%-115%

Analytical Run Log

8 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-08356

Project: Sludge Analysis Sample Date: June 21, 2011

Report Date: August 8, 2011 Analysis Date: July 8, 2011

Receive Date June 22, 2011 Q-List: 52869

Result as Adjusted for dilution

Run Sequence Identification ug/L Target % Recovery mg/L

Calibration Verification: 10.17 10 102%

Independent Laboratory Fortified Blank: 19.646 20 98.2%

Laboratory Reagent Blank 0.115

1106-08356-001 -0.2118 < 0.020

Duplicate of Sample Above: -0.3718 PASS

Non-project Sample -0.4459 < 0.020

Matrix Spike of Sample Above: 10.84 10 108%

1106-08833-001 -0.5294 < 0.020

Continuing Calibration Check 9.69 10 96.9%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 2.0ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7010-Selenium TCLP

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

9 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-08356

Project: Sludge Analysis Sample Date: June 21, 2011

Report Date: August 8, 2011 Analysis Date: June 27, 2011

Receive Date: June 22, 2011 Q-List: 52451

Result as

Run Sequence Identification (%) Target % Recovery

Laboratory Fortified Blank: 100 100 100.0%

Laboratory Reagent Blank < 0.01

1106-08356-001 39.0

Duplicate of Sample Above: 39.9 2.3% % RSD

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

Total Solids - SM18 2540G.

10%

Not Applicable

Not Applicable

99%-101%

Analytical Run Log

10 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-08356

Project: Sludge Analysis Date Received: June 22, 2011

Report Date: July 27, 2011 Analysis Date: July 1, 2011

 

QC Report - Method 8260B, Soil

Associated Samples: 001

File: 07011114.d 07011119.d 07011118.d

Standard: Calibration Cal. Ver. Laboratory LFB Laboratory

Verification Acceptance Fortified Blank Acceptance Reagent Blank

Parameter Units: Recovery (%) Range (%) Recovery (%) Range (%) (ug/L)

Vinyl chloride 98 75 - 125 92 70 - 130 < 2.0

1,1-Dichloroethene 98 75 - 125 103 70 - 130 < 1.0

2-Butanone 123 75 - 125 129 70 - 130 < 10.0

Chloroform 95 75 - 125 99 70 - 130 < 1.0

Carbon tetrachloride 97 75 - 125 98 70 - 130 < 1.0

Benzene 103 75 - 125 95 70 - 130 < 1.0

1,2-Dichloroethane 105 75 - 125 106 70 - 130 < 1.0

Trichloroethene 100 75 - 125 96 70 - 130 < 1.0

Tetrachloroethene 99 75 - 125 95 70 - 130 < 1.0

Chlorobenzene 98 75 - 125 97 70 - 130 < 1.0

1,4-Dichlorobenzene 97 75 - 125 99 70 - 130 < 1.0

Surrogate Recovery (%)

Dibromofluoromethane S1 99 75 - 125 102 70 - 130 102

Toluene-d8 S2 103 75 - 125 102 70 - 130 105

4-Bromofluorobenzene S3 111 75 - 125 105 70 - 130 96

8260B Run Log 7/1/11

(Files Relevant to WO 1106-08356)

Sample Standard.Prep.

File Sample Number Site ID Dilution (%) Date Notes

07011113.d 25ng 8260 BFB Instrument Tune Check 6/27/11

07011114.d 20ug/L 8260B Cal Std Calibration Verification 6/27/11

07011117.d 10ug/L LFB Lab Fortified Blank (QC-Soil Matrix) 6/23/11 out of range, remade and reran

07011118.d LRB Lab Reagent Blank (Soil Martix) 6/27/11

07011119.d 10ug/L LFB Lab Fortified Blank (QC-Soil Matrix) 7/1/11

07011124.d 1106-08356-001 Sample 3 250uL of 21.4815g/15ml Multiplier = *67.09104

07011125.d 1106-08833-001 Sample 4 250uL of 21.1926g/10ml Multiplier = *53.96296

07011133.d MS-08616-006 MW11-06 - Lab Matrix Spike 250uL of 11.8781g/10ml Multiplier = *31.52127

07011134.d MSD-08616-006 MW11-06 - Lab MS Duplicate 250uL of 11.8781g/10ml Multiplier = *31.52127

Notes:

 -Calibration Verification (CV) acceptance limits are noted. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB/QC) control limits are noted. Values were determined to be within laboratory acceptance limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Matrix Spike and MS Duplicates were performed at the appropriate frequency for the analytical batch. Analyses were performed

 on samples under a separate work order.

1106-08356 8260 Soil Page 1 of 1

11 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-08356

Project: Sludge Analysis Date Received: June 22, 2011

Report Date: July 27, 2011 Analysis Date: July 13, 2011

QC Report - Method 8260B, Water (TCLP)

Associated Samples: 001

File: 07131113.d 07131123.d 07131122.d 07131126.d

Standard: Calibration Cal. Ver. Laboratory LFB Laboratory TCLP Method TCLP MS

Verification Acceptance Fortified Blank Acceptance Reagent Blank Spike Acceptance

Parameter Units: Recovery (%) Range (%) Recovery (%) Range (%) (ug/L) Range (%) Range (%)

Vinyl chloride 99 75 - 125 95 70 - 130 < 2.0 102 70 - 130

1,1-Dichloroethene 98 75 - 125 102 70 - 130 < 1.0 108 70 - 130

2-Butanone 94 75 - 125 83 70 - 130 < 10.0 96 70 - 130

Chloroform 98 75 - 125 98 70 - 130 < 1.0 108 70 - 130

Carbon tetrachloride 99 75 - 125 93 70 - 130 < 1.0 99 70 - 130

Benzene 99 75 - 125 96 70 - 130 < 1.0 103 70 - 130

1,2-Dichloroethane 99 75 - 125 91 70 - 130 < 1.0 102 70 - 130

Trichloroethene 97 75 - 125 97 70 - 130 < 1.0 124 70 - 130

Tetrachloroethene 98 75 - 125 91 70 - 130 < 1.0 92 70 - 130

Chlorobenzene 98 75 - 125 89 70 - 130 < 1.0 94 70 - 130

1,4-Dichlorobenzene 95 75 - 125 90 70 - 130 < 1.0 94 70 - 130

Surrogate Recovery (%)

Dibromofluoromethane S1 100 75 - 125 103 70 - 130 103 105 70 - 130

Toluene-d8 S2 98 75 - 125 104 70 - 130 98 106 70 - 130

4-Bromofluorobenzene S3 104 75 - 125 97 70 - 130 100 102 70 - 130

8260B Run Log 7/13/11 - 7/14/11

(Files Relevant to WO 1106-08356)

Sample Standard.Prep.

File Sample Number Site ID Dilution (%) Date Notes

07131107.d 25ng 8260 BFB Instrument Tune Check 6/27/11

07131108.d 0.5ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131109.d 1ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131110.d 2ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131111.d 5ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131112.d 10ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131113.d 20ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131114.d 50ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131115.d 100ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131116.d 150ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131122.d LRB Lab Reagent Blank (Water Martix) 6/27/11

07131123.d 10ug/L LFB Lab Fortified Blank (QC-Water Matrix) 7/7/11

07131125.d 1106-08356-001 Sample 3 10

07131126.d MS-08356-001 TCLP Extraction MS Sample 3 10 Extraction method QC Sample

07131127.d 1106-08833-001 Sample 4 10

07131128.d MS-09424-001 O/W Sep. - Lab Matrix Spike 100

07131129.d MSD-09424-001 O/W Sep. - Lab MS Duplicate 100

Notes:

 -Calibration Verification - The initial calibration analysis performed with data set meets CV requirement. Noted recoveries were determined by 

 reprocessing 20ug/L calibration standard through the initial calibration. Acceptance range is noted. Values were within laboratory acceptance limits.

 -Laboratory Fortified Blank (LFB/QC) control limits are noted. Values were determined to be within laboratory acceptance limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -(Method 1311) TCLP Extraction Matrix Spike control limits are noted. Values were determined to be within control limits.

 -(Method 8260B) Matrix Spike and MS Duplicates were performed at the appropriate frequency for the analytical batch. Analyses were 

 performed on samples under a separate work order.

1106-08356 8260 Water 12 of 18Page 1 of 1
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-08356

Project: Sludge Analysis Date Received: June 22, 2011

Report Date: July 27, 2011 Analysis Date: July 9, 2011

QC Report - Method 8270C, Soil

Associated Samples: 001

File: 07081118.d 07081125.d 07081126.d 07081129.d

Standard: Calibration Laboratory LFB Laboratory Sample 001

Verification Fortified Blank Acceptance Reagent Blank Duplicate

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) RPD (%)

N-Nitrosodimethylamine 95.3 < 10 ND

Pyridine 101.9 < 10 ND

Aniline 99.0 < 10 ND

Phenol 98.7 52.5 25.7 - 97.3 < 5 ND

2-Chorophenol 98.5 53.0 29.7 - 96.2 < 5 ND

bis(2-chloroethyl) Ether 97.2 < 5 ND

1,3-Dichlorobenzene 98.5 < 2 ND

1,4-Dichlorobenzene 98.1 52.5 31.1 - 77.7 < 2 ND

1,2-Dichlorobenzene 98.5 < 2 ND

Benzyl Alcohol 103.8 < 20 ND

2-Methylphenol 99.9 < 5 ND

bis(2-chloroisopropyl)ether 98.5 < 10 ND

N-Nitrosodi-n-propylamine 97.2 62.3 45.8 - 85.1 < 10 ND

3&4-Methylphenol 99.0 < 5 ND

Hexachloroethane 101.0 < 5 ND

Nitrobenzene 98.8 < 5 ND

N-Nitrosopiperidine 98.9 < 10 ND

Isophorone 98.9 < 2 ND

2-Nitrophenol 99.6 < 10 ND

2,4-Dimethylphenol 106.5 < 5 ND

bis(2-chloroethoxy)Methane 98.5 < 5 ND

2,4-Dichlorophenol 93.0 < 5 ND

1,2,4-Trichlorobenzene 98.3 56.2 37.5 - 86.4 < 2 ND

Naphthalene 97.9 < 1 ND

4-Chloroaniline 98.0 < 5 ND

2,6-Dichlorophenol 99.4 < 5 ND

Hexachlorobutadiene 98.4 < 5 ND

N-Nitrosodi-n-butylamine 96.3 < 5 ND

4-Chloro-3-methylphenol 98.5 76.4 48.3 - 108.0 < 10 ND

2-Methylnaphthalene 97.3 < 1 ND

1-Methylnaphthalene 96.3 < 1 ND

Hexachlorocyclopentadiene 100.4 < 20 ND

2,4,6-Trichlorophenol 102.8 < 10 ND

2,4,5-Trichlorophenol 102.8 < 10 ND

2-Chloronaphthalene 96.6 < 2 ND

1-Chloronaphthalene 98.6 < 2 ND

2-Nitroaniline 98.1 < 20 ND

Dimethylphthalate 98.7 < 5 ND

2,6-Dinitrotoluene 99.7 < 5 ND

Acenaphthylene 100.6 < 1 ND

3-Nitroaniline 99.4 < 5 ND

1106-08356 8270 Soil Page 1 of 3

13 of 18
QC Report - Method 8270C, Soil

Associated Samples: 001

File: 07081118.d 07081125.d 07081126.d 07081129.d

Standard: Calibration Laboratory LFB Laboratory Sample 001

Verification Fortified Blank Acceptance Reagent Blank Duplicate

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) RPD (%)

Acenaphthene 99.3 69.4 49.0 - 95.3 < 1 ND

2,4-Dinitrophenol 83.5 < 20 ND

Dibenzofuran 98.6 < 2 ND

4-Nitrophenol 98.7 90.9 30.3 - 98.0 < 10 ND

2,4-Dinitrotoluene 101.2 78.4 47.8 - 104.9 < 5 ND

1-Naphthylamine 103.6 < 10 ND

2-Naphthylamine 95.9 < 10 ND

Fluorene 99.9 < 1 ND

Diethylphthalate 99.5 < 5 ND

4-Chlorophenylphenylether 98.4 < 2 ND

4-Nitroaniline 98.9 < 20 ND

2-Methyl-4,6-dinitrophenol 96.1 < 20 ND

N-Nitrosodiphenylamine 102.0 < 5 ND

Azobenzene 103.2 < 5 ND

4-Bromophenylphenylether 100.1 < 2 ND

Hexachlorobenzene 97.5 < 5 ND

Pentachlorophenol 105.6 80.8 32.4 - 120.0 < 20 ND

Phenanthrene 98.8 < 1 ND

Anthracene 100.4 < 1 ND

Carbazole 96.5 < 10 ND

Di-n-butylphthalate 103.8 < 10 ND

Fluoranthene 102.2 < 1 ND

Benzidine 95.3 < 10 ND

Pyrene 101.5 88.5 58.2 - 108.6 < 1 ND

Benzylbutylphthalate 101.6 < 5 ND

Benzo(a)anthracene 96.5 < 1 ND

Chrysene 97.0 < 1 ND

3,3'-Dichlorobenzidine 101.1 < 5 ND

bis(2-ethylhexyl)phthalate 98.0 < 5 ND

Di-n-octylphthalate 88.7 < 10 ND

Benzo(b)fluoranthene 97.0 < 1 ND

Benzo(k)fluoranthene 105.8 < 1 ND

Benzo(a)pyrene 97.2 < 1 ND

Indeno[1,2,3-cd]pyrene 93.6 < 1 ND

Dibenz(a,h)anthracene 94.6 < 1 ND

Benzo(g,h,i)perylene 106.2 < 1 ND

Surrogate Recoveries (%) LFB/LRB/Sample

CV Result LFB Result Acceptance LRB Result Duplicate

Acid Surrogates Recovery (%) Recovery (%) Recovery (%) Recovery (%) Recovery (%)

2-Fluorophenol (E.S.) 102.3 49.6 15.2 - 70.1 47.4 1.2

Phenol-d5 (E.S.) 100.6 69.0 29.9 - 78.3 56.6 10.8

2,4,6-Tribromophenol (E.S.) 102.0 92.9 47.6 - 106.3 67.9 0.0

B/N Surrogates

Nitrobenzene-d5 (E.S.) 99.4 62.6 17.8 - 107.4 57.3 52.9

2-Fluorobiphenyl (E.S.) 100.2 74.6 29.3 - 111.9 62.5 59.1

Terphenyl-d14 (E.S.) 101.4 101.5 48.9 - 125.7 93.1 86.0

1106-08356 8270 Soil Page 2 of 3

14 of 18
8270C Run Log 7/8/11 - 7/9/11

(Files Relevant to WO 1106-08356)

Sample Final Prep/Extraction

File Sample Number Site ID Volume Volume Date

07081101.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

07081102.d 80ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081103.d 70ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081104.d 60ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081105.d 50ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081106.d 40ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081107.d 30ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081108.d 20ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081109.d 15ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081110.d 10ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081111.d 5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081112.d 2ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081113.d 1ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081114.d 0.5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081116.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

07081118.d 40ug 8270C Cal Std 12/21/10 Calibration Verification 4.0ml 6/6/11

07081125.d LFB Lab Fortified Blank (QC) 30.23g 4.0ml 6/30/11

07081126.d LRB Lab Reagent Blank 30.04g 4.0ml 6/30/11

07081127.d 1106-08356-001 Sample 3 30.89g 4.0ml 6/30/11

07081128.d 1106-08833-001 Sample 4 29.98g 4.0ml 6/30/11

07081129.d Dup-08356-001 Lab Duplicate - Sample 3 29.64g 4.0ml 6/30/11

07081130.d MS-08833-001 Lab Matrix Spike - Sample 4 30.09g 4.0ml 6/30/11

Notes:

 -Bold Font indicates value outside laboratory acceptance limits

 -ND indicates Not Detected

 -Calibration Verification (CV) acceptance limits: 80 - 120%. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB) control limits are noted. Values were determined to be within laboratory control limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate relative percent difference (RPD) acceptance criteria is < 30%. No compounds were observed in the sample for RPD determination.

 -Matrix Spikes were performed at the appropriate frequency for the extraction batch. Analyses were performed on samples under a separate

 work order.

 -Nonconforming QC Elements: Acid extractable surrogate recoveries were out of range in the duplicated analysis.

1106-08356 8270 Soil Page 3 of 3

15 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-08356

Project: Sludge Analysis Date Received: June 22, 2011

Report Date: July 27, 2011 Analysis Date: July 8, 2011

QC Report - Method 8270C, Water

Associated Samples: 001

File: 07081118.d 07081119.d 07081120.d 07081123.d

Standard: Calibration Laboratory LFB Laboratory Sample 001

Verification Fortified Blank Acceptance Reagent Blank Duplicate

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) RPD (%)

N-Nitrosodimethylamine 95.3 < 10 ND

Pyridine 101.9 < 10 ND

Aniline 99.0 < 10 ND

Phenol 98.7 22.6 13.9 - 36.0 < 5 ND

2-Chorophenol 98.5 52.0 38.9 - 87.4 < 5 ND

bis(2-chloroethyl) Ether 97.2 < 5 ND

1,3-Dichlorobenzene 98.5 < 2 ND

1,4-Dichlorobenzene 98.1 32.2 23.2 - 73.2 < 2 ND

1,2-Dichlorobenzene 98.5 < 2 ND

Benzyl Alcohol 103.8 < 20 ND

2-Methylphenol 99.9 < 5 ND

bis(2-chloroisopropyl)ether 98.5 < 10 ND

N-Nitrosodi-n-propylamine 97.2 65.8 44.7 - 87.3 < 10 ND

3&4-Methylphenol 99.0 < 5 ND

Hexachloroethane 101.0 < 5 ND

Nitrobenzene 98.8 < 5 ND

N-Nitrosopiperidine 98.9 < 10 ND

Isophorone 98.9 < 2 ND

2-Nitrophenol 99.6 < 10 ND

2,4-Dimethylphenol 106.5 < 5 ND

bis(2-chloroethoxy)Methane 98.5 < 5 ND

2,4-Dichlorophenol 93.0 < 5 ND

1,2,4-Trichlorobenzene 98.3 35.6 30.3 - 81.8 < 2 ND

Naphthalene 97.9 < 1 ND

4-Chloroaniline 98.0 < 5 ND

2,6-Dichlorophenol 99.4 < 5 ND

Hexachlorobutadiene 98.4 < 5 ND

N-Nitrosodi-n-butylamine 96.3 < 5 ND

4-Chloro-3-methylphenol 98.5 77.7 45.0 - 115.3 < 10 ND

2-Methylnaphthalene 97.3 < 1 ND

1-Methylnaphthalene 96.3 < 1 ND

Hexachlorocyclopentadiene 100.4 < 20 ND

2,4,6-Trichlorophenol 102.8 < 10 ND

2,4,5-Trichlorophenol 102.8 < 10 ND

2-Chloronaphthalene 96.6 < 2 ND

1-Chloronaphthalene 98.6 < 2 ND

2-Nitroaniline 98.1 < 20 ND

Dimethylphthalate 98.7 < 5 ND

2,6-Dinitrotoluene 99.7 < 5 ND

Acenaphthylene 100.6 < 1 ND

3-Nitroaniline 99.4 < 5 ND

1106-08356 8270 Water Page 1 of 3

16 of 18
QC Report - Method 8270C, Water

Associated Samples: 001

File: 07081118.d 07081119.d 07081120.d 07081123.d

Standard: Calibration Laboratory LFB Laboratory Sample 001

Verification Fortified Blank Acceptance Reagent Blank Duplicate

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) RPD (%)

Acenaphthene 99.3 66.0 45.3 - 98.4 < 1 ND

2,4-Dinitrophenol 83.5 < 20 ND

Dibenzofuran 98.6 < 2 ND

4-Nitrophenol 98.7 48.2 13.7 - 59.3 < 10 ND

2,4-Dinitrotoluene 101.2 75.3 46.2 - 101.1 < 5 ND

1-Naphthylamine 103.6 < 10 ND

2-Naphthylamine 95.9 < 10 ND

Fluorene 99.9 < 1 ND

Diethylphthalate 99.5 < 5 ND

4-Chlorophenylphenylether 98.4 < 2 ND

4-Nitroaniline 98.9 < 20 ND

2-Methyl-4,6-dinitrophenol 96.1 < 20 ND

N-Nitrosodiphenylamine 102.0 < 5 ND

Azobenzene 103.2 < 5 ND

4-Bromophenylphenylether 100.1 < 2 ND

Hexachlorobenzene 97.5 < 5 ND

Pentachlorophenol 105.6 81.0 42.1 - 135.5 < 20 ND

Phenanthrene 98.8 < 1 ND

Anthracene 100.4 < 1 ND

Carbazole 96.5 < 10 ND

Di-n-butylphthalate 103.8 < 10 ND

Fluoranthene 102.2 < 1 ND

Benzidine 95.3 < 10 ND

Pyrene 101.5 94.2 61.8 - 121.9 < 1 ND

Benzylbutylphthalate 101.6 < 5 ND

Benzo(a)anthracene 96.5 < 1 ND

Chrysene 97.0 < 1 ND

3,3'-Dichlorobenzidine 101.1 < 5 ND

bis(2-ethylhexyl)phthalate 98.0 < 5 ND

Di-n-octylphthalate 88.7 < 10 ND

Benzo(b)fluoranthene 97.0 < 1 ND

Benzo(k)fluoranthene 105.8 < 1 ND

Benzo(a)pyrene 97.2 < 1 ND

Indeno[1,2,3-cd]pyrene 93.6 < 1 ND

Dibenz(a,h)anthracene 94.6 < 1 ND

Benzo(g,h,i)perylene 106.2 < 1 ND

Surrogate Recoveries (%) LFB/LRB/Sample

CV Result LFB Result Acceptance LRB Result Duplicate

Acid Surrogates Recovery (%) Recovery (%) Recovery (%) Recovery (%) Recovery (%)

2-Fluorophenol (E.S.) 102.3 31.5 16.2 - 49.9 26.7 24.7

Phenol-d5 (E.S.) 100.6 19.8 11.1 - 42.3 21.3 19.9

2,4,6-Tribromophenol (E.S.) 102.0 85.2 44.6 - 123.6 74.2 72.5

B/N Surrogates

Nitrobenzene-d5 (E.S.) 99.4 66.5 34.3 - 106.9 57.0 55.5

2-Fluorobiphenyl (E.S.) 100.2 63.1 30.7 - 102.3 60.2 60.3

Terphenyl-d14 (E.S.) 101.4 99.9 55.0 - 133.1 82.9 96.0

1106-08356 8270 Water Page 2 of 3

17 of 18
8270C Run Log 7/8/11 - 7/9/11

(Files Relevant to WO 1106-08356)

Sample Final Prep/Extraction

File Sample Number Site ID Volume Volume Date

07081101.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

07081102.d 80ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081103.d 70ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081104.d 60ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081105.d 50ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081106.d 40ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081107.d 30ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081108.d 20ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081109.d 15ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081110.d 10ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081111.d 5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081112.d 2ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081113.d 1ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081114.d 0.5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081116.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

07081118.d 40ug 8270C Cal Std 12/21/10 Calibration Verification 4.0ml 6/6/11

07081119.d LFB Lab Fortified Blank (QC) 0.10L 4.0ml 7/1/11

07081120.d LRB Lab Reagent Blank 0.10L 4.0ml 7/1/11

07081121.d 1106-08356-001 Sample 3 0.10L 4.0ml 7/1/11

07081122.d 1106-08833-001 Sample 4 0.10L 4.0ml 7/1/11

07081123.d Dup-08356-001 Lab Duplicate - Sample 3 0.10L 4.0ml 7/1/11

07081124.d MS-08833-001 Lab Matrix Spike - Sample 4 0.10L 4.0ml 7/1/11

Notes:

 -ND indicates Not Detected

 -Calibration Verification (CV) acceptance limits: 80 - 120%. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB) control limits are noted. Values were determined to be within laboratory control limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate relative percent difference (RPD) acceptance criteria is < 30%. No compounds were observed in the sample for RPD determination.

 -Matrix Spikes were performed at the appropriate frequency for the extraction batch. Analyses were performed on samples under a separate

 work order.

1106-08356 8270 Water Page 3 of 3

18 of 18

Laboratory Report

PROJECT: Sludge Analysis

DATE RECEIVED:

WORK ORDER:

DATE REPORTED:

100290

IBM

Mail Stop 966A

Essex Jct, VT 05452

Atten: Dave Kost SAMPLER:

August 08, 2011

1106-08833

Russ Fortin

June 29, 2011

Enclosed please find the results of the analyses performed for the samples referenced on the 

attached chain of custody. All required method quality control elements including 

instrument calibration were performed in accordance with method requirements and 

determined to be acceptable unless otherwise noted. 

The column labeled Lab/Tech in the accompanying report denotes the laboratory facility 

where the testing was performed and the technician who conducted the assay. A "W" designates 

the Williston, VT lab under NELAC certification ELAP 11263; "R" designates the Lebanon, NH 

facility under certification NH 2037 and “N” the Plattsburgh, NY lab under certification ELAP 

11892. “Sub” indicates the testing was performed by a subcontracted laboratory. The 

accreditation status of the subcontracted lab is referenced in the corresponding NELAC and Qual 

fields. 

The NELAC column also denotes the accreditation status of each laboratory for each 

reported parameter. “A” indicates the referenced laboratory is NELAC accredited for the 

parameter reported. “N” indicates the laboratory is not accredited. “U” indicates that NELAC 

does not offer accreditation for that parameter in that specific matrix. Test results denoted with an 

“A” meet all National Environmental Laboratory Accreditation Program requirements except 

where denoted by pertinent data qualifiers. Test results are representative of the samples as they 

were received at the laboratory 

Endyne, Inc. warrants, to the best of its knowledge and belief, the accuracy of the analytical 

test results contained in this report, but makes no other warranty, expressed or implied, especially 

no warranties of merchantability or fitness for a particular purpose. 

Page 1 of 4

Reviewed by:

Harry B. Locker, Ph.D.

Laboratory Director

 ELAP 11263

160 James Brown Dr., Williston, VT 05495

Ph 802-879-4333 Fax 802-879-7103

www.endynelabs.com

NH2037

56 Etna Road, Lebanon, NH 03766 

Ph 603-678-4891 Fax 603-678-4893
Laboratory Report

IBM

Page 2 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-08833

06/29/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 4 Composite Time: 6:20 Date Sampled:6/28/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

TCLP Extract-VOA ZHE EPA 1311 Completed 7/8/11 MMW W A

TCLP Extract-SVOA/Metals EPA 1311 Completed 6/29/11 MMW W A

Cyanide, Total EPA 9012A < 3 mg/Kg, dry 7/1/11 CAL N A

Cyanide, Total Amenable SM 4500-CN G < 3 mg/kg, dry 7/1/11 CAL N U

Solids, Total SM18 2540G 39.8 % 16:25 6/29/11 JSS W U

Aluminum, Total EPA 6010B 15,000 mg/Kg, dry 7/29/11 ETK W A

Arsenic, Total TCLP EPA 6010B < 0.20 mg/L 7/12/11 RJL W A

Arsenic, Total EPA 6010B < 9.0 mg/Kg, dry 7/29/11 ETK W A

Barium, Total TCLP EPA 6010B < 0.20 mg/L 7/12/11 RJL W A

Barium, Total EPA 6010B 36 mg/Kg, dry 7/29/11 ETK W A

Cadmium, Total TCLP EPA 6010B < 0.020 mg/L 7/12/11 RJL W A

Cadmium, Total EPA 6010B < 0.90 mg/Kg, dry 7/29/11 ETK W A

Chromium, Hexavalent EPA 7196A < 10 mg/Kg 7/5/11 MMW W N

Chromium, Total TCLP EPA 6010B < 0.050 mg/L 7/12/11 RJL W A

Chromium, Total EPA 6010B 240 mg/Kg, dry 7/29/11 ETK W A

Copper, Total EPA 6010B 960 mg/Kg, dry 7/29/11 ETK W A

Iron, Total EPA 6010B 9,800 mg/Kg, dry 7/29/11 ETK W A

Lead, Total TCLP EPA 6010B < 0.20 mg/L 7/12/11 RJL W A

Lead, Total EPA 6010B < 9.0 mg/Kg, dry 7/29/11 ETK W A

Mercury, Total TCLP EPA 7470 < 0.010 mg/L 7/6/11 CM W A

Mercury, Total EPA 7471A < 0.056 mg/Kg, dry 7/13/11 CM W A

Nickel, Total TCLP EPA 6010B < 0.10 mg/L 7/12/11 RJL W A

Nickel, Total EPA 6010B 38 mg/Kg, dry 7/29/11 ETK W A

Platinum, Total ICP-OES < 5 ug/g 7/8/11 SUB SW U SBV

Selenium, Total TCLP EPA 7010 < 0.020 mg/L 7/8/11 MMW W A

Selenium, Total EPA 7010 < 2.2 mg/Kg, dry 7/8/11 MMW W A

Silver, Total TCLP EPA 6010B < 0.20 mg/L 7/12/11 RJL W A QASilver, Total EPA 6010B < 9.0 mg/Kg, dry 7/29/11 ETK W A

Tin ICP-OES <= 5 ug/g 7/8/11 SUB SW U SBV

Zinc, Total EPA 6010B 810 mg/Kg, dry 7/29/11 ETK W A

VOC Custom List

TCLP VOLATILES

Vinyl chloride EPA 8260B < 108 ug/Kg, Dry 7/1/11 MGT W A

Vinyl chloride, TCLP EPA 8260B < 20.0 ug/L 7/13/11 MGT W A

1,1-Dichloroethene EPA 8260B < 54.0 ug/Kg, Dry 7/1/11 MGT W A

1,1-Dichloroethene, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

2-Butanone, TCLP EPA 8260B < 100 ug/L 7/13/11 MGT W A

2-Butanone EPA 8260B < 540 ug/Kg, Dry 7/1/11 MGT W A

Chloroform EPA 8260B < 54.0 ug/Kg, Dry 7/1/11 MGT W A

Chloroform, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

Carbon tetrachloride, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A
Laboratory Report

IBM

Page 3 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-08833

06/29/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 4 Composite Time: 6:20 Date Sampled:6/28/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

Carbon tetrachloride EPA 8260B < 54.0 ug/Kg, Dry 7/1/11 MGT W A

Benzene, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

Benzene EPA 8260B < 54.0 ug/Kg, Dry 7/1/11 MGT W A

1,2-Dichloroethane EPA 8260B < 54.0 ug/Kg, Dry 7/1/11 MGT W A

1,2-Dichloroethane, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

Trichloroethene, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

Trichloroethene EPA 8260B < 54.0 ug/Kg, Dry 7/1/11 MGT W A

Tetrachloroethene EPA 8260B < 54.0 ug/Kg, Dry 7/1/11 MGT W A

Tetrachloroethene, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

Chlorobenzene, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

Chlorobenzene EPA 8260B < 54.0 ug/Kg, Dry 7/1/11 MGT W A

1,4-Dichlorobenzene, TCLP EPA 8260B < 10.0 ug/L 7/13/11 MGT W A

1,4-Dichlorobenzene EPA 8260B < 54.0 ug/Kg, Dry 7/1/11 MGT W A

Surr. 1 (Dibromofluoromethane) EPA 8260B 92 % 7/1/11 MGT W A

Surr. 1 (Dibromofluoromethane) EPA 8260B 107 % 7/14/11 MGT W A

Surr. 2 (Toluene d8) EPA 8260B 100 % 7/14/11 MGT W A

Surr. 2 (Toluene d8) EPA 8260B 101 % 7/1/11 MGT W A

Surr. 3 (4-Bromofluorobenzene) EPA 8260B 98 % 7/14/11 MGT W A

Surr. 3 (4-Bromofluorobenzene) EPA 8260B 109 % 7/1/11 MGT W A

TCLP SEMI-VOLATILES

Liq/Liq Solvent Extraction EPA 3510C Completed 7/1/11 MDP W A

Pyridine, TCLP EPA 8270C < 100 ug/L 7/8/11 EEP W A

Hexachloroethane, TCLP EPA 8270C < 50.0 ug/L 7/8/11 EEP W A

Nitrobenzene, TCLP EPA 8270C < 50.0 ug/L 7/8/11 EEP W A

Hexachlorobutadiene, TCLP EPA 8270C < 50.0 ug/L 7/8/11 EEP W A

2,4-Dinitrotoluene, TCLP EPA 8270C < 50.0 ug/L 7/8/11 EEP W A

Hexachlorobenzene, TCLP EPA 8270C < 50.0 ug/L 7/8/11 EEP W A

Cresols, Total TCLP EPA 8270C < 100 ug/L 7/8/11 EEP W U

2,4,5-Trichlorophenol, TCLP EPA 8270C < 100 ug/L 7/8/11 EEP W A

2,4,6-Trichlorophenol, TCLP EPA 8270C < 100 ug/L 7/8/11 EEP W A

Pentachlorophenol, TCLP EPA 8270C < 200 ug/L 7/8/11 EEP W A

B/N Surr.1 Nitrobenzene-d5 EPA 8270C 68 % 7/8/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 73 % 7/8/11 EEP W A

B/N Surr.3 Terphenyl-d14 EPA 8270C 100 % 7/8/11 EEP W A

Acid Surr.1 2-Fluorophenol EPA 8270C 30 % 7/8/11 EEP W A

Acid Surr.2 Phenol-d8 EPA 8270C 24 % 7/8/11 EEP W A

Acid Surr.3 Tribromophenol EPA 8270C 84 % 7/8/11 EEP W A

Ultrasonic Extraction EPA 3550B Completed 6/30/11 MDP W A

Pyridine EPA 8270C < 840 ug/Kg, dry 7/9/11 EEP W A

Hexachloroethane EPA 8270C < 420 ug/Kg, dry 7/9/11 EEP W A

Nitrobenzene EPA 8270C < 420 ug/Kg, dry 7/9/11 EEP W A
Laboratory Report

IBM

Page 4 of 4

CLIENT:

PROJECT: Sludge Analysis

WORK ORDER:

DATE RECEIVED

1106-08833

06/29/2011

DATE REPORTED: 08/08/2011

001 Site: Sample 4 Composite Time: 6:20 Date Sampled:6/28/11

Parameter Result Units Method Analysis Date/Time Lab/Tech NELAC Qual.

Hexachlorobutadiene EPA 8270C < 420 ug/Kg, dry 7/9/11 EEP W A

2,4-Dinitrotoluene EPA 8270C < 420 ug/Kg, dry 7/9/11 EEP W A

Hexachlorobenzene EPA 8270C < 420 ug/Kg, dry 7/9/11 EEP W A

Cresols, Total EPA 8270C < 840 ug/Kg, dry 7/9/11 EEP W U

2,4,5-Trichlorophenol EPA 8270C < 840 ug/Kg, dry 7/9/11 EEP W A

2,4,6-Trichlorophenol EPA 8270C < 840 ug/Kg, dry 7/9/11 EEP W A

Pentachlorophenol EPA 8270C < 1,680 ug/Kg, dry 7/9/11 EEP W A

B/N Surr.1 Nitrobenzene-d5 EPA 8270C 50 % 7/9/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 58 % 7/9/11 EEP W A

B/N Surr.2 2-Fluorobiphenyl EPA 8270C 58 % 7/9/11 EEP W A

Acid Surr.1 2-Fluorophenol EPA 8270C ND % 7/9/11 EEP W A QSAcid Surr.2 Phenol-d8 EPA 8270C 11 % 7/9/11 EEP W A QSAcid Surr.3 Tribromophenol EPA 8270C ND % 7/9/11 EEP W A QSReport Summary of Qualifiers and Notes

SBVG: Analysis performed by subcontracted laboratory, VHG Labs. The complete subcontracted report has been appended

to this report.

QA-: The TMLFBTT (Digested Blank) associated with this analysis did not meet laboratory acceptance limits indicating

the results may be biased low.

QS-: Indicates surrogate recovery was below laboratory acceptance limits.

Method 8270C: Soil Analysis: The laboratory fortified matrix (LFM) analysis indicates a potential negative bias in

all acid extractable reported values.
 276 Abby Road, Manchester, NH 03103 (603) 622-7660 www.vhglabs.com

 Page 1 of 1 

 Endyne, Inc DATE: 7/11/11 

Attn: Mark Westover 

160 James Brown Dr JOB NO: SO1115291 

Williston, VT 05495 

 PO NO: Mark Westover 

SAMPLE TYPE: Sludge 

 SAMPLE I.D.: 1106-08833 001 Sample 4, Bottle #005 

 DATE RECEIVED: 7/1/2011

 METHOD: Quantitative determination of elements by ICP-OES 

 RESULTS: Concentration in ug/g(ppm). 

Sample I.D. Sn Pt 

1106-08833 001 Sample 4 

Bottle #005 ≤ 5 <5 

 

 

 

 

 

We certify the above analysis to be the result obtained on the samples, as received, based upon the analytical chemistry expertise and 

standard methods utilized by VHG Labs. VHG Labs, Inc. waives all responsibility for any damages resulting from the usage and/or 

implementation of the products/data described herein. This report may not be reproduced, except in full, without written approval from 

VHG Labs. 

 

 Approved By: ________________________________ 

 Julie M. MacIntosh, A/S Manager 

 Analytical Services Division

PDF created with pdfFactory trial version www.pdffactory.com
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

SM20 4500-CN G. Amenable Cyanide Soil

Client: IBM Work Order: 1106-08833

Project: Sludge Analysis Date Received: June 29, 2011

Report Date: August 8, 2011 Analysis Date: June 30, 2011

Q-List: 52596

Result as

Run Sequence Identification ug/L * Target % Recovery Final Value mg/Kg

Calibration Verification: 145.896 150 97.3%

Independent Laboratory Fortified Blank: 64.998 63.7 102%

Laboratory Reagent Blank -3.147 < 10

1106-08356-001 Amenable -0.22 < 3

Duplicate of Sample Above -0.331 Pass

1106-08833-001 Amenable 0.867 < 3

Matrix Spike of Sample Above 0.965 < 10 Pass

Lab Fortified Blank Amenable 6.734 < 10 Pass

1106-08356-001 Total -0.524 < 3

Duplicate of Sample Above -0.631 Pass

1106-08833-001 Total -1.531 < 3

Matrix Spike of Sample Above 70.056 80 88%

Continuing Calibration Check 153.332 150 102%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 Matrix Spike of Amenable Cyanide should have no analyte recovery.

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 9012A Total Cyanide Soil

 20%

70%-130%

80%-120%

13%-199%

Analytical Run Log

1 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-08833

Project: Sludge Analysis Sample Date: June 28, 2011

Report Date: August 8, 2011 Analysis Date: July 5, 2011

Receive Date: June 29, 2011 Q-List: 52814

Result as Reported

Run Sequence Identification mg/L Target % Recovery mg/Kg

Calibration Verification: 0.093 0.1 93.0%

Independent Laboratory Fortified Blank: 0.2 0.2 100% 20.02

Laboratory Reagent Blank 0.002 < 10

1106-07565-001 0.029 *** < 10

Duplicate of Sample Above: 0.031 *** 8.8% RSD

1106-07856-001 0.033 *** < 10

Matrix Spike of Sample Above: 0.148 *** 0.233 63.6% * 22.9

1106-07857-001 0.051 *** < 10

1106-08356-001 0.011 *** < 10

1106-08833-001 0.014 *** < 10

Insoluble Matrix Spike of Sample Above: 1.023 0.935 109%** 5770

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 * Matrix Spike for sample 1106-07856 failed low. Results qualified on Final Report

 ** Matrix Spike used as passing closing QA result

 -Calibration Verification acceptance limits

 -Laboratory Fortified Blank (QC) control lim

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Dev

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

Hexavalent Chromium EPA3060A/7196A

20%

75%-125%

80%-120%

80%-120%

Analytical Run Log

 *** Analyst did not measure absobence of sample prior to addition of Diphenyl Carbazide. This resulted in an 

artificially high absorbance.

2 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-08833

Project: Sludge Analysis Sample Date: June 28, 2011

Report Date: August 8, 2011 Analysis Date: July 13, 2011

Receive Date: June 29, 2011 Q-List: 52959

Result as Adjusted for

Run Sequence Identification ug/L Target % Recovery Mass Digested mg/Kg

Calibration Verification: 2.045 2 102%

Independent Laboratory Fortified Blank: 2.087 2 104% 0.522

Laboratory Reagent Blank 0.021 < 0.050

1106-08833-001 0.189 < 0.056

Duplicate of Sample Above: 0.181 PASS

Matrix Spike of Sample Above: 3.066 3 102% 0.846

Continuing Calibration Check 2.066 2 103%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 0.20ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7471A Mercury-Soil

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

3 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-08833

Project: Sludge Analysis Sample Date: June 28, 2011

Report Date: August 8, 2011 Analysis Date: July 6, 2011

Receive Date: June 29, 2011 Q-List: 52640

Result as Adjusted for dilution

Run Sequence Identification ug/L Target % Recovery mg/L

Calibration Verification: 2.019 2 101%

Independent Laboratory Fortified Blank: 2.014 2 101%

Laboratory Reagent Blank -0.014

1106-08356-001 0.005 < 0.010

Non-Project Sample -0.014

Matrix Spike of Sample Above: 2.064 2 104%

Continuing Calibration Check 2.021 2 101%

1106-8833-001 0.002 < 0.010

Non-Project Sample 0.007

Duplicate of Sample Above: 0.004 PASS

Continuing Calibration Check 2.047 2 102%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 1.0ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7470 Mercury-TCLP

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

4 of 18
Laboratory Quality Data Report ENDYNE INC. 160 James Brown Drive

EPA 6010B- ICP Metals Soil Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Client: IBM Work Order: 1106-08833

Project: Sludge Date Received:Report Date: Analysis Date:

Q-List #: 53,665

Int. Chk. CCVA CCVR LFB LRB Duplicate LFM CCVA CCVR

Instrument Instrument Reported

Parameter (% Rec) (% Rec) (% Rec) (% Rec) (mg/L) RPD (%) (% Rec) mg/L mg/Kg (% Rec) (% Rec)Aluminum-Axial NA 97.8 102 0.0249 * ND ND NA NA 103

Aluminum-Radial 96.6 99.5 ND 0.4999 13.5 OR 33.7744 15000 93.6

Arsenic NA 95.7 100 -0.0063 ND 103 0.0064 < 9.0 98.1Barium 85.2 98.9 99.9 -0.0068 ND 92.7 0.08 36 97.7

Cadmium 105 98 103 0.0004 ND 101 0.001 < 0.90 98.8Chromium 112 99.4 108 0.004 ND 97.8 0.5441 240 107

Copper 88.2 98 102 0.0053 10.2 95.3 2.1426 960 97.6Iron-Axial NA 99.6 115 0.0782 * ND 101 NA NA 99.5

Iron-Radial 95.7 100 ND 0.546 ND ND 21.7475 9800 93.9

Lead 111 94.8 102 0.0049 ND 99.7 0.014 < 9.0 96.3Nickel 108 101 107 0.0002 ND 97.4 0.0844 38 101Silver 96.4 100 106 0.0017 ND 99.4 -0.0094 < 9.0 99.8

Zinc 101 95.2 99.5 0.0142 13 101 1.8137 810 97Notes: * Blank contamination at levels affecting quantitation. Axial line not used for sample quantitation. LRB, LFB, Duplicate & LFM were from digestion batch. Associated QA were not analyzed on the same day as the project sample. -NA: Not Available. Sample not assessed for this element. - ND: Not Determined. Sample did not have analyte within calibration range. -OR: Out-of-range. Spike concentration too low relative to sample concentration. -Bold Font indicates value outside laboratory acceptance limits -Interference Check (Int. Chk.) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits.  -Calibration Verification (CCVA) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Calibration Verification High Concentration (CCVR) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Laboratory Fortified Blank (TMLFB) acceptance limits are noted: Values were determined to be within method acceptance limits -Laboratory Reagent Blank (TMLRB) was free of contaminant affecting analytical results. Values as mg/L digested soil blank. -Duplicate relative percent difference (RPD) acceptance criteria is < 20%. Values were within method acceptance limits unless noted.  -Matrix Spike (MS) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits unless noted. 

QC Report Page 1 of 1

August 8, 2011

1106-08833-001

June 29, 2011July 29, 2011
Laboratory Quality Data Report ENDYNE INC. 160 James Brown Drive

EPA 6010B- ICP Metals TCLP Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Client: IBM Work Order: 1106-08833

Project: Sludge Analysis Date Received:Report Date: Analysis Date:

Q-List #: 52,913

Int. Chk. CCVA LFB LRB 

Instrument Reported Duplicate Instrument Reported LFM Instrume

Parameter (% Rec) (% Rec) (% Rec) (mg/L) mg/L mg/L % RPD mg/L mg/L % Recovery mg/L Arsenic NA 98.2 95.1 -0.0085 -0.0101 < 0.20 ND -0.0103 < 0.20 104 -0.0105 

Barium 85.2 99.5 98.1 -0.0036 0.0164 < 0.20 ND 0.102 < 0.20 92.4 0.0064 Cadmium 94.4 101 98.7 -0.0001 -0.0003 < 0.020 ND -0.003 < 0.020 103 0.0001 Chromium 91.8 102 101 -0.0004 -0.0017 < 0.050 ND -0.003 < 0.050 98.8 -0.0031 Lead 102 99.4 97.9 -0.0022 -0.0037 < 0.20 ND -0.0026 < 0.20 100 -0.0038 Silver 90.4 101 68.1 * -0.0004 0.0005 < 0.20 ND 0.0004 < 0.20 99 -0.0029 

Nickel 96.7 98.6 96.4 -0.0012 0.0019 < 0.10 ND ND ND ND 0.0026 

Notes: * Silver LFB was not within method Acceptance Limits. Report qualified. -TCLP samples are digested at a 1:10 dilution -NA: Not Available. Sample not assessed for this element. - ND: Not Determined. Sample did not have analyte above reporting limit. -Bold Font indicates value outside laboratory acceptance limits -Interference Check (Int. Chk.) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits.  -Calibration Verification (CCVA) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Calibration Verification High Concentration (CCVR) acceptance limits: 90 - 110%. Values were determined to be within method acceptance limits.  -Laboratory Fortified Blank (TMLFB) acceptance limits: 85 - 115%. Values were determined to be within method acceptance limits -Laboratory Reagent Blank (TMLRB) was free of contaminant affecting analytical results. Values as mg/L digested -Duplicate relative percent difference (RPD) acceptance criteria is < 20%. Values were within method acceptance limits unless noted.  -Matrix Spike (MS) acceptance limits: 70 - 130%. Values were determined to be within method acceptance limits unless noted. 

QC Report Page 1 of 1

June 29, 2011July 12, 2011

1106

August 8, 2011

1106-08356-001 Non-project Sample
7/12/11

VHG JOB # SO1114814 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.2 0 0 0 1.01 0.102

Instr result 10.1 0.000 0.004 <5 0.004 <5 0.987 0.1

% Recovery 99.0 97.7 98.0

Sn Theoretical 10 0 0 0 0.999 0.100

Instr result 9.99 0.000 0.017 <5 0.019 <5 0.992 0.119

% Recovery 99.9 99.3 119.0

VHG JOB # SO1114844 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.2 0.000 0.000 0.000 1.01 0.102

Instr result 10.1 0.000 -0.009 <5 -0.009 <5 0.976 0.086

% Recovery 99.0 96.6 84.3

Sn Theoretical 10.2 0.000 0.000 0.000 0.999 0.1

Instr result 10.3 0.000 0.008 <5 0.008 <5 0.982 0.113

% Recovery 101.0 98.3 113.0

VHG JOB # SO1114844 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.3 0.000 0.000 0.000 1.01 0.102

Instr result 10.3 0.000 -0.009 <5 -0.009 <5 0.976 0.086

% Recovery 100.0 96.6 84.3

Sn Theoretical 10.2 0.000 0.000 0.000 0.999 0.1

Instr result 10.3 0.000 0.008 <5 0.008 <5 0.982 0.113

% Recovery 101.0 98.3 113.0

VHG JOB # SO1115051 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10.0 0.000 0.000 0.000 1.000 0.099

Instr result 9.74 0.005 0.000 <5 0.000 <5 0.976 0.089

% Recovery 97.4 97.6 89.9

Sn Theoretical 10.9 0.000 0.000 0.000 1.074 0.108

Instr result 10.7 0.008 0.005 <5 0.005 <5 1.058 0.119

% Recovery 98.2 98.5 110.2

VHG JOB # SO1115291 Units:ug/g

Line Check Instrument Blank Rgt Blank#1

sample Resultsprep#1 Rgt Blank#2sample Resultsprep#2 QC ControlDetection limit 

control

Pt Theoretical 10 0.000 0.000 0.000 1.000 0.099

Instr result 9.98 -0.006 -0.007 <5 -0.007 <5 0.974 0.091

% Recovery 99.8 97.4 91.9

Sn Theoretical 10.9 0.000 0.000 0.000 1.074 0.108

Instr result 10.9 0.004 0.012 6.4 0.012 4.3 1.043 0.120

% Recovery 100.0 97.1 111.1

Sample ID:1106-07857 001 Duplicate composite 

#2,bottle 005-Solids

Date Analyzed:7/8/11

Sample ID:1106-08833 001 Sample 4,bottle #5-

solid

Date Analyzed: 6/21/11

Date Analyzed: 6/29/11 Sample ID:1106-08356 001, Sample#3,bottle#5

Date Analyzed: 6/21/11

Sample ID:1106-07565 001-Sludge Sampler, 

bottle 005

Quality Report-VHG Labs

Date Analyzed: 6/21/11

Sample ID:1106-07856 001Sample 2 

Composite,bottle #5-Solids

7 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-08833

Project: Sludge Analysis Sample Date: June 28, 2011

Report Date: August 8, 2011 Analysis Date: July 8, 2011

Receive Date: June 29 2011 Q-List: 52869

Result as Adjusted for

Run Sequence Identification ug/L Target % Recovery Mass Digested mg/Kg

Calibration Verification: 10.17 10 101.7%

Independent Laboratory Fortified Blank: 21.52 20 107.6% 50.0

Laboratory Reagent Blank -0.416 < 2.5

1106-08833-001 -0.485 < 2.24

Duplicate of Sample Above: -0.686 PASS

Matrix Spike of Sample Above: 7.089 8 88.6%

Continuing Calibration Check 9.61 10 96.1%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument quantitation limit is 2.0ug/L

 -Digestion Batch Dup and LFM did not require Selenium Analysis. Duplicate and Matrix Spike performed post-digestion.

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviatio

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7010-Selenium Soil

20%

75%-125%

90%-110%

85%-115%

Analytical Run Log

8 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-08833

Project: Sludge Analysis Sample Date: June 28, 2011

Report Date: August 8, 2011 Analysis Date: July 8, 2011

Receive Date June 29, 2011 Q-List: 52869

Result as Adjusted for dilution

Run Sequence Identification ug/L Target % Recovery mg/L

Calibration Verification: 10.17 10 102%

Independent Laboratory Fortified Blank: 19.646 20 98.2%

Laboratory Reagent Blank 0.115

1106-08356-001 -0.2118 < 0.020

Duplicate of Sample Above: -0.3718 PASS

Non-project Sample -0.4459 < 0.020

Matrix Spike of Sample Above: 10.84 10 108%

1106-08833-001 -0.5294 < 0.020

Continuing Calibration Check 9.69 10 96.9%

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Instrument Quantitation Limit is 2.0ug/L

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation Limits:

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

EPA 7010-Selenium TCLP

20%

85%-115%

90%-110%

90%-110%

Analytical Run Log

9 of 18
 ENDYNE, INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

(802) 879-4333 

Client: IBM Work Order: 1106-08833

Project: Sludge Analysis Sample Date: June 28, 2011

Report Date: August 8, 2011 Analysis Date: June 29, 2011

Receive Date: June 29, 2011 Q-List: 52564

Result as

Run Sequence Identification (%) Target % Recovery

Laboratory Fortified Blank: 100 100 100.0%

Laboratory Reagent Blank < 0.01

1106-08833-001 39.8

Duplicate of Sample Above: 41.3 3.7% % RSD

Notes:

 All Method associated Quality Control was within acceptance limits unless otherwise noted.

 -Calibration Verification acceptance limits: 

 -Laboratory Fortified Blank (QC) control limits:

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicate Percent Relative Standard Deviation

 -Matrix Spike Acceptance Limits:

QC Report Page 1 of 1

QC Data Interpretation Report

Total Solids - SM18 2540G.

10%

Not Applicable

Not Applicable

99%-101%

Analytical Run Log

10 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-08833

Project: Sludge Analysis Date Received: June 29, 2011

Report Date: July 27, 2011 Analysis Date: July 1, 2011

 

QC Report - Method 8260B, Soil

Associated Samples: 001

File: 07011114.d 07011119.d 07011118.d

Standard: Calibration Cal. Ver. Laboratory LFB Laboratory

Verification Acceptance Fortified Blank Acceptance Reagent Blank

Parameter Units: Recovery (%) Range (%) Recovery (%) Range (%) (ug/L)

Vinyl chloride 98 75 - 125 92 70 - 130 < 2.0

1,1-Dichloroethene 98 75 - 125 103 70 - 130 < 1.0

2-Butanone 123 75 - 125 129 70 - 130 < 10.0

Chloroform 95 75 - 125 99 70 - 130 < 1.0

Carbon tetrachloride 97 75 - 125 98 70 - 130 < 1.0

Benzene 103 75 - 125 95 70 - 130 < 1.0

1,2-Dichloroethane 105 75 - 125 106 70 - 130 < 1.0

Trichloroethene 100 75 - 125 96 70 - 130 < 1.0

Tetrachloroethene 99 75 - 125 95 70 - 130 < 1.0

Chlorobenzene 98 75 - 125 97 70 - 130 < 1.0

1,4-Dichlorobenzene 97 75 - 125 99 70 - 130 < 1.0

Surrogate Recovery (%)

Dibromofluoromethane S1 99 75 - 125 102 70 - 130 102

Toluene-d8 S2 103 75 - 125 102 70 - 130 105

4-Bromofluorobenzene S3 111 75 - 125 105 70 - 130 96

8260B Run Log 7/1/11

(Files Relevant to WO 1106-08833)

Sample Standard.Prep.

File Sample Number Site ID Dilution (%) Date Notes

07011113.d 25ng 8260 BFB Instrument Tune Check 6/27/11

07011114.d 20ug/L 8260B Cal Std Calibration Verification 6/27/11

07011117.d 10ug/L LFB Lab Fortified Blank (QC-Soil Matrix) 6/23/11 out of range, remade and reran

07011118.d LRB Lab Reagent Blank (Soil Martix) 6/27/11

07011119.d 10ug/L LFB Lab Fortified Blank (QC-Soil Matrix) 7/1/11

07011124.d 1106-08356-001 Sample 3 250uL of 21.4815g/15ml Multiplier = *67.09104

07011125.d 1106-08833-001 Sample 4 250uL of 21.1926g/10ml Multiplier = *53.96296

07011133.d MS-08616-006 MW11-06 - Lab Matrix Spike 250uL of 11.8781g/10ml Multiplier = *31.52127

07011134.d MSD-08616-006 MW11-06 - Lab MS Duplicate 250uL of 11.8781g/10ml Multiplier = *31.52127

Notes:

 -Calibration Verification (CV) acceptance limits are noted. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB/QC) control limits are noted. Values were determined to be within laboratory acceptance limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Matrix Spike and MS Duplicates were performed at the appropriate frequency for the analytical batch. Analyses were performed

 on samples under a separate work order.

1106-08833 8260 Soil Page 1 of 1

11 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-08833

Project: Sludge Analysis Date Received: June 29, 2011

Report Date: July 27, 2011 Analysis Date: July 14, 2011

QC Report - Method 8260B, Water (TCLP)

Associated Samples: 001

File: 07131113.d 07131123.d 07131122.d

Standard: Calibration Cal. Ver. Laboratory LFB Laboratory

Verification Acceptance Fortified Blank Acceptance Reagent Blank

Parameter Units: Recovery (%) Range (%) Recovery (%) Range (%) (ug/L)

Vinyl chloride 99 75 - 125 95 70 - 130 < 2.0

1,1-Dichloroethene 98 75 - 125 102 70 - 130 < 1.0

2-Butanone 94 75 - 125 83 70 - 130 < 10.0

Chloroform 98 75 - 125 98 70 - 130 < 1.0

Carbon tetrachloride 99 75 - 125 93 70 - 130 < 1.0

Benzene 99 75 - 125 96 70 - 130 < 1.0

1,2-Dichloroethane 99 75 - 125 91 70 - 130 < 1.0

Trichloroethene 97 75 - 125 97 70 - 130 < 1.0

Tetrachloroethene 98 75 - 125 91 70 - 130 < 1.0

Chlorobenzene 98 75 - 125 89 70 - 130 < 1.0

1,4-Dichlorobenzene 95 75 - 125 90 70 - 130 < 1.0

Surrogate Recovery (%)

Dibromofluoromethane S1 100 75 - 125 103 70 - 130 103

Toluene-d8 S2 98 75 - 125 104 70 - 130 98

4-Bromofluorobenzene S3 104 75 - 125 97 70 - 130 100

8260B Run Log 7/13/11 - 7/14/11

(Files Relevant to WO 1106-08833)

Sample Standard.Prep.

File Sample Number Site ID Dilution (%) Date Notes

07131107.d 25ng 8260 BFB Instrument Tune Check 6/27/11

07131108.d 0.5ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131109.d 1ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131110.d 2ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131111.d 5ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131112.d 10ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131113.d 20ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131114.d 50ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131115.d 100ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131116.d 150ug/L 8260B Cal Std Initial Calibration Standard 7/11/11

07131122.d LRB Lab Reagent Blank (Water Martix) 6/27/11

07131123.d 10ug/L LFB Lab Fortified Blank (QC-Water Matrix) 7/7/11

07131125.d 1106-08356-001 Sample 3 10

07131126.d MS-08356-001 TCLP Extraction MS Sample 3 10 Extraction method QC Sample

07131127.d 1106-08833-001 Sample 4 10

07131128.d MS-09424-001 O/W Sep. - Lab Matrix Spike 100

07131129.d MSD-09424-001 O/W Sep. - Lab MS Duplicate 100

Notes:

 -Calibration Verification - The initial calibration analysis performed with data set meets CV requirement. Noted recoveries were determined by 

 reprocessing 20ug/L calibration standard through the initial calibration. Acceptance range is noted. Values were within laboratory acceptance limits.

 -Laboratory Fortified Blank (LFB/QC) control limits are noted. Values were determined to be within laboratory acceptance limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Matrix Spike and MS Duplicates were performed at the appropriate frequency for the analytical batch. Analyses were 

 performed on samples under a separate work order.

1106-08833 8260 Water Page 1 of 1

12 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-08833

Project: Sludge Analysis Date Received: June 29, 2011

Report Date: July 27, 2011 Analysis Date: July 9, 2011

QC Report - Method 8270C, Soil

Associated Samples: 001

File: 07081118.d 07081125.d 07081126.d 07081130.d

Standard: Calibration Laboratory LFB Laboratory Sample 001 LFM

Verification Fortified Blank Acceptance Reagent Blank Matrix Spike Acceptance Limit

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) Recovery (%) Recovery (%)

N-Nitrosodimethylamine 95.3 < 10

Pyridine 101.9 < 10

Aniline 99.0 < 10

Phenol 98.7 52.5 25.7 - 97.3 < 5 15.5 31.4 - 91.9

2-Chorophenol 98.5 53.0 29.7 - 96.2 < 5 5.5 30.1 - 94.1

bis(2-chloroethyl) Ether 97.2 < 5

1,3-Dichlorobenzene 98.5 < 2

1,4-Dichlorobenzene 98.1 52.5 31.1 - 77.7 < 2 49.4 25.7 - 80.3

1,2-Dichlorobenzene 98.5 < 2

Benzyl Alcohol 103.8 < 20

2-Methylphenol 99.9 < 5

bis(2-chloroisopropyl)ether 98.5 < 10

N-Nitrosodi-n-propylamine 97.2 62.3 45.8 - 85.1 < 10 59.3 31.5 - 86.9

3&4-Methylphenol 99.0 < 5

Hexachloroethane 101.0 < 5

Nitrobenzene 98.8 < 5

N-Nitrosopiperidine 98.9 < 10

Isophorone 98.9 < 2

2-Nitrophenol 99.6 < 10

2,4-Dimethylphenol 106.5 < 5

bis(2-chloroethoxy)Methane 98.5 < 5

2,4-Dichlorophenol 93.0 < 5

1,2,4-Trichlorobenzene 98.3 56.2 37.5 - 86.4 < 2 53.6 32.2 - 89.5

Naphthalene 97.9 < 1

4-Chloroaniline 98.0 < 5

2,6-Dichlorophenol 99.4 < 5

Hexachlorobutadiene 98.4 < 5

N-Nitrosodi-n-butylamine 96.3 < 5

4-Chloro-3-methylphenol 98.5 76.4 48.3 - 108.0 < 10 42.7 40.7 - 110.6

2-Methylnaphthalene 97.3 < 1

1-Methylnaphthalene 96.3 < 1

Hexachlorocyclopentadiene 100.4 < 20

2,4,6-Trichlorophenol 102.8 < 10

2,4,5-Trichlorophenol 102.8 < 10

2-Chloronaphthalene 96.6 < 2

1-Chloronaphthalene 98.6 < 2

2-Nitroaniline 98.1 < 20

Dimethylphthalate 98.7 < 5

2,6-Dinitrotoluene 99.7 < 5

Acenaphthylene 100.6 < 1

3-Nitroaniline 99.4 < 5

1106-08833 8270 Soil Page 1 of 3

13 of 18
QC Report - Method 8270C, Soil

Associated Samples: 001

File: 07081118.d 07081125.d 07081126.d 07081130.d

Standard: Calibration Laboratory LFB Laboratory Sample 001 LFM

Verification Fortified Blank Acceptance Reagent Blank Matrix Spike Acceptance Limit

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) RPD (%) Recovery (%)

Acenaphthene 99.3 69.4 49.0 - 95.3 < 1 68.3 41.7 - 98.8

2,4-Dinitrophenol 83.5 < 20

Dibenzofuran 98.6 < 2

4-Nitrophenol 98.7 90.9 30.3 - 98.0 < 10 11.6 24.9 - 101.3

2,4-Dinitrotoluene 101.2 78.4 47.8 - 104.9 < 5 60.1 35.6 - 101.4

1-Naphthylamine 103.6 < 10

2-Naphthylamine 95.9 < 10

Fluorene 99.9 < 1

Diethylphthalate 99.5 < 5

4-Chlorophenylphenylether 98.4 < 2

4-Nitroaniline 98.9 < 20

2-Methyl-4,6-dinitrophenol 96.1 < 20

N-Nitrosodiphenylamine 102.0 < 5

Azobenzene 103.2 < 5

4-Bromophenylphenylether 100.1 < 2

Hexachlorobenzene 97.5 < 5

Pentachlorophenol 105.6 80.8 32.4 - 120.0 < 20 0.0 41.3 - 118.5

Phenanthrene 98.8 < 1

Anthracene 100.4 < 1

Carbazole 96.5 < 10

Di-n-butylphthalate 103.8 < 10

Fluoranthene 102.2 < 1

Benzidine 95.3 < 10

Pyrene 101.5 88.5 58.2 - 108.6 < 1 85.5 49.5 - 112.8

Benzylbutylphthalate 101.6 < 5

Benzo(a)anthracene 96.5 < 1

Chrysene 97.0 < 1

3,3'-Dichlorobenzidine 101.1 < 5

bis(2-ethylhexyl)phthalate 98.0 < 5

Di-n-octylphthalate 88.7 < 10

Benzo(b)fluoranthene 97.0 < 1

Benzo(k)fluoranthene 105.8 < 1

Benzo(a)pyrene 97.2 < 1

Indeno[1,2,3-cd]pyrene 93.6 < 1

Dibenz(a,h)anthracene 94.6 < 1

Benzo(g,h,i)perylene 106.2 < 1

Surrogate Recoveries (%) LFB/LRB/Sample LFM

CV Result LFB Result Acceptance LRB Result Matrix Spike Acceptance Limit

Acid Surrogates Recovery (%) Recovery (%) Recovery (%) Recovery (%) Recovery (%) Recovery (%)

2-Fluorophenol (E.S.) 102.3 49.6 15.2 - 70.1 47.4 1.7 15.2 - 70.1

Phenol-d5 (E.S.) 100.6 69.0 29.9 - 78.3 56.6 15.0 29.9 - 78.3

2,4,6-Tribromophenol (E.S.) 102.0 92.9 47.6 - 106.3 67.9 0.5 47.6 - 106.3

B/N Surrogates

Nitrobenzene-d5 (E.S.) 99.4 62.6 17.8 - 107.4 57.3 55.0 17.8 - 107.4

2-Fluorobiphenyl (E.S.) 100.2 74.6 29.3 - 111.9 62.5 58.6 29.3 - 111.9

Terphenyl-d14 (E.S.) 101.4 101.5 48.9 - 125.7 93.1 81.1 48.9 - 125.7

1106-08833 8270 Soil Page 2 of 3

14 of 18
8270C Run Log 7/8/11 - 7/9/11

(Files Relevant to WO 1106-08833)

Sample Final Prep/Extraction

File Sample Number Site ID Volume Volume Date

07081101.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

07081102.d 80ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081103.d 70ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081104.d 60ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081105.d 50ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081106.d 40ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081107.d 30ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081108.d 20ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081109.d 15ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081110.d 10ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081111.d 5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081112.d 2ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081113.d 1ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081114.d 0.5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081116.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

07081118.d 40ug 8270C Cal Std 12/21/10 Calibration Verification 4.0ml 6/6/11

07081125.d LFB Lab Fortified Blank (QC) 30.23g 4.0ml 6/30/11

07081126.d LRB Lab Reagent Blank 30.04g 4.0ml 6/30/11

07081127.d 1106-08356-001 Sample 3 30.89g 4.0ml 6/30/11

07081128.d 1106-08833-001 Sample 4 29.98g 4.0ml 6/30/11

07081129.d Dup-08356-001 Lab Duplicate - Sample 3 29.64g 4.0ml 6/30/11

07081130.d MS-08833-001 Lab Matrix Spike - Sample 4 30.09g 4.0ml 6/30/11

Notes:

 -Bold Font indicates value outside laboratory acceptance limits

 -Calibration Verification (CV) acceptance limits: 80 - 120%. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB) control limits are noted. Values were determined to be within laboratory control limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicates were performed at the appropriate frequency for the extraction batch. Analyses were performed on samples under a separate

 work order.

 -Matrix Spikes (LFM) control limits are noted. Values were determined to be within laboratory control limits unless noted.

 -Nonconforming QC Elements: Acid extractable compound and surrogate recoveries were out of range in the matrix spike analysis.

 Data was qualified in the work order conclusion.

1106-08833 8270 Soil Page 3 of 3

15 of 18
ENDYNE INC. 160 James Brown Drive

Laboratory Services Williston, VT 05495

 (802) 879-4333 FAX 879-7103

Laboratory Report

Client: IBM Work Order: 1106-08833

Project: Sludge Analysis Date Received: June 29, 2011

Report Date: July 27, 2011 Analysis Date: July 8, 2011

QC Report - Method 8270C, Water

Associated Samples: 001

File: 07081118.d 07081119.d 07081120.d 07081124.d

Standard: Calibration Laboratory LFB Laboratory Sample 001 LFM

Verification Fortified Blank Acceptance Reagent Blank Matrix Spike Acceptance Limit

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) Recovery (%) Recovery (%)

N-Nitrosodimethylamine 95.3 < 10

Pyridine 101.9 < 10

Aniline 99.0 < 10

Phenol 98.7 22.6 13.9 - 36.0 < 5 24.3 11.5 - 35.6

2-Chorophenol 98.5 52.0 38.9 - 87.4 < 5 56.8 28.2 - 85.4

bis(2-chloroethyl) Ether 97.2 < 5

1,3-Dichlorobenzene 98.5 < 2

1,4-Dichlorobenzene 98.1 32.2 23.2 - 73.2 < 2 30.1 17.7 - 77.6

1,2-Dichlorobenzene 98.5 < 2

Benzyl Alcohol 103.8 < 20

2-Methylphenol 99.9 < 5

bis(2-chloroisopropyl)ether 98.5 < 10

N-Nitrosodi-n-propylamine 97.2 65.8 44.7 - 87.3 < 10 63.4 32.3 - 87.9

3&4-Methylphenol 99.0 < 5

Hexachloroethane 101.0 < 5

Nitrobenzene 98.8 < 5

N-Nitrosopiperidine 98.9 < 10

Isophorone 98.9 < 2

2-Nitrophenol 99.6 < 10

2,4-Dimethylphenol 106.5 < 5

bis(2-chloroethoxy)Methane 98.5 < 5

2,4-Dichlorophenol 93.0 < 5

1,2,4-Trichlorobenzene 98.3 35.6 30.3 - 81.8 < 2 35.1 21.9 - 87.2

Naphthalene 97.9 < 1

4-Chloroaniline 98.0 < 5

2,6-Dichlorophenol 99.4 < 5

Hexachlorobutadiene 98.4 < 5

N-Nitrosodi-n-butylamine 96.3 < 5

4-Chloro-3-methylphenol 98.5 77.7 45.0 - 115.3 < 10 85.8 43.5 - 106.8

2-Methylnaphthalene 97.3 < 1

1-Methylnaphthalene 96.3 < 1

Hexachlorocyclopentadiene 100.4 < 20

2,4,6-Trichlorophenol 102.8 < 10

2,4,5-Trichlorophenol 102.8 < 10

2-Chloronaphthalene 96.6 < 2

1-Chloronaphthalene 98.6 < 2

2-Nitroaniline 98.1 < 20

Dimethylphthalate 98.7 < 5

2,6-Dinitrotoluene 99.7 < 5

Acenaphthylene 100.6 < 1

3-Nitroaniline 99.4 < 5

1106-08833 8270 Water Page 1 of 3

16 of 18
QC Report - Method 8270C, Water

Associated Samples: 001

File: 07081118.d 07081119.d 07081120.d 07081124.d

Standard: Calibration Laboratory LFB Laboratory Sample 001 LFM

Verification Fortified Blank Acceptance Reagent Blank Matrix Spike Acceptance Limit

Parameter Units: Recovery (%) Recovery (%) Range (%) (ug) RPD (%) Recovery (%)

Acenaphthene 99.3 66.0 45.3 - 98.4 < 1 59.8 32.5 - 103.4

2,4-Dinitrophenol 83.5 < 20

Dibenzofuran 98.6 < 2

4-Nitrophenol 98.7 48.2 13.7 - 59.3 < 10 57.5 11.8 - 60.9

2,4-Dinitrotoluene 101.2 75.3 46.2 - 101.1 < 5 79.9 31.1 - 98.5

1-Naphthylamine 103.6 < 10

2-Naphthylamine 95.9 < 10

Fluorene 99.9 < 1

Diethylphthalate 99.5 < 5

4-Chlorophenylphenylether 98.4 < 2

4-Nitroaniline 98.9 < 20

2-Methyl-4,6-dinitrophenol 96.1 < 20

N-Nitrosodiphenylamine 102.0 < 5

Azobenzene 103.2 < 5

4-Bromophenylphenylether 100.1 < 2

Hexachlorobenzene 97.5 < 5

Pentachlorophenol 105.6 81.0 42.1 - 135.5 < 20 79.4 27.3 - 127.5

Phenanthrene 98.8 < 1

Anthracene 100.4 < 1

Carbazole 96.5 < 10

Di-n-butylphthalate 103.8 < 10

Fluoranthene 102.2 < 1

Benzidine 95.3 < 10

Pyrene 101.5 94.2 61.8 - 121.9 < 1 92.2 45.0 - 127.5

Benzylbutylphthalate 101.6 < 5

Benzo(a)anthracene 96.5 < 1

Chrysene 97.0 < 1

3,3'-Dichlorobenzidine 101.1 < 5

bis(2-ethylhexyl)phthalate 98.0 < 5

Di-n-octylphthalate 88.7 < 10

Benzo(b)fluoranthene 97.0 < 1

Benzo(k)fluoranthene 105.8 < 1

Benzo(a)pyrene 97.2 < 1

Indeno[1,2,3-cd]pyrene 93.6 < 1

Dibenz(a,h)anthracene 94.6 < 1

Benzo(g,h,i)perylene 106.2 < 1

Surrogate Recoveries (%) LFB/LRB/Sample LFM

CV Result LFB Result Acceptance LRB Result Matrix Spike Acceptance Limit

Acid Surrogates Recovery (%) Recovery (%) Recovery (%) Recovery (%) Recovery (%) Recovery (%)

2-Fluorophenol (E.S.) 102.3 31.5 16.2 - 49.9 26.7 29.8 16.2 - 49.9

Phenol-d5 (E.S.) 100.6 19.8 11.1 - 42.3 21.3 22.3 11.1 - 42.3

2,4,6-Tribromophenol (E.S.) 102.0 85.2 44.6 - 123.6 74.2 85.2 44.6 - 123.6

B/N Surrogates

Nitrobenzene-d5 (E.S.) 99.4 66.5 34.3 - 106.9 57.0 66.5 34.3 - 106.9

2-Fluorobiphenyl (E.S.) 100.2 63.1 30.7 - 102.3 60.2 72.3 30.7 - 102.3

Terphenyl-d14 (E.S.) 101.4 99.9 55.0 - 133.1 82.9 95.6 55.0 - 133.1

1106-08833 8270 Water Page 2 of 3

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8270C Run Log 7/8/11 - 7/9/11

(Files Relevant to WO 1106-08833)

Sample Final Prep/Extraction

File Sample Number Site ID Volume Volume Date

07081101.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

07081102.d 80ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081103.d 70ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081104.d 60ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081105.d 50ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081106.d 40ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081107.d 30ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081108.d 20ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081109.d 15ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081110.d 10ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081111.d 5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081112.d 2ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081113.d 1ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081114.d 0.5ug 8270C Calibration Std Initial Calibration Standard 4.0ml 6/6/11

07081116.d 25ppm 8270C DFTPP Instrument Performance check 4.0ml 11/28/10

07081118.d 40ug 8270C Cal Std 12/21/10 Calibration Verification 4.0ml 6/6/11

07081119.d LFB Lab Fortified Blank (QC) 0.10L 4.0ml 7/1/11

07081120.d LRB Lab Reagent Blank 0.10L 4.0ml 7/1/11

07081121.d 1106-08356-001 Sample 3 0.10L 4.0ml 7/1/11

07081122.d 1106-08833-001 Sample 4 0.10L 4.0ml 7/1/11

07081123.d Dup-08356-001 Lab Duplicate - Sample 3 0.10L 4.0ml 7/1/11

07081124.d MS-08833-001 Lab Matrix Spike - Sample 4 0.10L 4.0ml 7/1/11

Notes:

 -Calibration Verification (CV) acceptance limits: 80 - 120%. Values were determined to be within method acceptance limits.

 -Laboratory Fortified Blank (LFB) control limits are noted. Values were determined to be within laboratory control limits.

 -Laboratory Reagent Blank (LRB) was free of contaminant affecting analytical results.

 -Duplicates were performed at the appropriate frequency for the extraction batch. Analyses were performed on samples under a separate

 work order.

 -Matrix Spikes (LFM) control limits are noted. Values were determined to be within laboratory control limits.

1106-08833 8270 Water Page 3 of 3

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