.v, Fwd: FW: Submittal of Requested NMP Data 

Terri Zick to: Christopher Lambesis 09/30/2010 03:56 PM 

From: Terri Zick <tzick@cticompanies.com> 

To: Christopher Lambesis/R5/USEPA/US@EPA 

,,,, .. „,„„ ,„,.,„,,,„,-„,,,„,,_________,,,,.._,...,.,_,...-,s.,,„...,..,..--.„--..„,„.„.,,„,.,..,„.,,,,_.,..„„„.,.„._,,,,,,,,,.,,...„„,.„,.,,,______ 

Chris 

Attached please find the information you requested. I will be in all day 

tomorrow if there are questions 

Thank you 

Hi Terri, 

Below and attached relate to the quantitation of the unknown peak Chris had 

asked about. 

Gary 

Original Message 

From: Rick Wilburn [mailto:wilburnr@trimatrixlabs.com] 

Sent: Thursday, September 30, 2010 9:09 AM 

To: woodgl@trimatrixlabs.com 

Subject: RE: FW: Submittal of Requested NMP Data 

Attached is quantitation of unknown peak at retention time of 7.825 from 

sample 1003151-03. The peak was not found in any of the other samples. 

Rick 

Original Message 

From: Gary Wood [mailto:woodgl@trimatrixlabs.com] 

Sent: Tuesday, September 28, 2010 5:00 PM 

To: Rick Wilburn 

Subject: FW: FW: Submittal of Requested NMP Data 

Hi Rick - Is this something you or Jodi can do in short order? 

Gary 

Original Message 

From: Lambesis.Christopher@epamail.epa.gov 

[mailto:Lambesis.Christopher@epamail.epa.gov] 

Sent: Tuesday, September 28, 2010 4:50 PM 

To: Terri Zick 

Cc: Kathy Wilson; Ramaly.Todd@epamail.epa.gov 

Subject: Re: FW: Submittal of Requested NMP Data 

Terri, 

Thank you for submitting the additional information. As you know, we 

are are trying to determine a conservative analytical concentration of 

NMP in the waste samples. I feel we have exhausted our review of the 

NMP analysis and at this point we will require one last calculation 

submittal from the laboratory. We found that there is evidence that the 

chromatographic peak just before the first internal standard may be a 
derivative of the NMP analyte. Can you have the laboratory integrate 

this peak (approximately retention time 7.825 min.) for all four of the 

composite samples. Please submit these calculations in the same format 

as the last submission. 

It looks like this may double the concentration of NMP in the samples 

but that these results will still be well below the DRAS limits. 

Please let me know if you have any questions. 

-Chris 

Christopher Lambesis 

Environmental Scientist 

U.S EPA Region 5 

Land and Chemicals Division 

(312) 886-3583 

From: Terri Zick <tzick@cticompanies.com > 

To: Christopher Lambesis/R5/USEPA/US@EPA, Todd 

Ramaly/R5/USEPA/US@EPA 

Cc: Kathy Wilson <kathywilson@owossographic.com > 

Date: 09/24/2010 12:42 PM 

Subject: FW: Submittal of Requested NMP Data 

GentlemenAre there any questions regarding this last data submittal? I will 

available all day if questions arise. We will do whatever we can to 

assist in reaching your goal of a 9/30/10 completion date. 

be 

Thanks 

Terri Zick 

313-300-7401 cell 

tzick@cticompanies.com 

CTI and Associates, Inc. 

51331 W. Pontiac Trail, Wixom, MI 48393 

248.486.5100 Phone I 248.486.5050 Fax 

Original Message 

From: Terri Zick 

Sent: Thursday, September 23, 2010 11:12 AM 

To: 'Lambesis.Christopher@epamail.epa.gov '; 
'Ramaly.Todd@epamail.epa.gov' 

Cc: 'Kathy Wilson' 

Subject: FW: Submittal of Requested NMP Data 

GentlemenI am hopeful that this satisfies your remaining need for back-up 

documentation for the delisting. Please let me know as soon as possible 

if there are other needs prior to publication. 

Thank you 

Terri Zick 

313-300-7401 cell 

tzick@cticompanies.com 

CTI and Associates, Inc. 

51331 W. Pontiac Trail, Wixom, MI 48393 

248.486.5100 Phone 1 248.486.5050 Fax 

Original Message 

From: Rick Wilburn [mailto:wilburnr@trimatrixlabs.com] 

Sent: Thursday, September 23, 2010 10:49 AM 

To: Lambesis.Christopher@epamail.epa.gov 

Cc: Ramaly.Todd@epamail.epa.gov ; Terri Zick; 'Gary Wood' 

Subject: RE: Requested NMP Data 

Chris, 

Here are the requested spectra and areas for sample 1003151-03. 

Rick 

Original Message 

From: Lambesis.Christopher@epamail.epa.gov 

[mailto:Lambesis.Christopher@epamail.epa.gov] 

Sent: Wednesday, September 22, 2010 3:03 PM 

To: wilburnr@trimatrixlabs.com 

Cc: Ramaly.Todd@epamail.epa.gov ; tzick@cticompanies.com ; Gary Wood 

Subject: Re: Requested NMP Data 

Rick, 

Thanks for this data. One last request, can you send me the same 

chromatogram and ion abundance scans for sample 1003151-03, peaks at RT 

7.82 and RT 8.42 minutes? Thanks. 

-Chris 

Christopher Lambesis 

Environmental Scientist 

U.S EPA Region 5 

Land and Chemicals Division 

(312) 886-3583 
From: "Rick Wilburn" <wilburnr@trimatrixlabs.com> 

To: <tzick@cticompanies.com>, 

<Lambesis.Christopher@epamail.epa.gov>, <Ramaly.Todd@epamail.epa.gov > 

Cc: "Gary Wood" <woodgl@trimatrixlabs.com> 

Date: 09/22/2010 12:46 PM 

Subject: Requested NMP Data 

Attached please find the requested NMP data. 

Rick 

Rick D. Wilburn 

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[attachment "NMP TICS 4.PDF" deleted by Christopher 

Lambesis/R5/USEPA/US] 

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[attachment "NMP TICS 5.PDF" deleted by Christopher 

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The information contained in this electronic message is privileged and/or 

confidential information intended only for the use of the individual or 

entity named above. If the reader of this message is not the intended 

recipient, or the employee or agent responsible to deliver it to the 

intended recipient, you are hereby notified that any dissemination, 

distribution or copying of the communication is neither allowed nor 

intended. If you have received this communication in error, please 

immediately notify us by return e-mail or by calling 800-CTI-TODAY and 

delete the message. Thank You! 

The information contained in this electronic message is privileged and/or 

confidential information intended only for the use of the individual or entity 

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the employee or agent responsible to deliver it to the intended recipient, you 

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TIC Calculation 

Example 

Sample Peak Area Internal S tan dard Concentration Final Extract Volume 

x = ug / = (mg / kg) g 

Internal S tan dard Peak Area x Re sponse Factor Initial Sample Volume 

Sample #1003151-03 (peak at 7.825) 

2361636 5 ug/mL 

x = 57u 

1542096 1 29.8 g 

NMP TICS 6.doc 
File :C: \Documents and Settings\analystsv\Desktop\0317 10\1003151-0 

3.D 

Operator : JLB 

Instrument : 308 

Acquired : 17 Mar 2010 16:00 using AcqMethod 0308 10BNA.M 

Sample Name: 1003151-03 

Misc Info : 

Abundance TIC: 1003151-03.D\data.ms 

1000000 

900000 7.825 

800000 \ \ 

\ 'ti 

700000 

1 \ 600000. 

I \ 

/ \ 1 

500000• I 

\ I \ 

1 I \ 

/ 1 \ 400000. 

1 J 

I 

/ 

30000a '-\\-1 

200000. I 

\ 

100000 I I 

Time--> 7.75 7.80 7.85 7.90 7.95 8.00 8.05 8.10 8.15 8.20 8.25 8.30 8.35 8.40 8.45 8.50 8.55 8.60 8.65 8.70 

Abundance 

7 

Scan 853 (7.825 min): 1003151-03.D\data.ms 

220000 

200000 

180000 

160000 

140000 71 

120000 

100000 

80000 42 

60000 

40000 

52 

20000 

62 82 

1 112 207 236 281 

m z--> 40 50 60 . 70 . 80 _90 100 110 120 130 140 150 160 170 1.80, 190..200 210 . 220 230 . 240 250 260 270 280 
File :C:\Documents and Settings\analystsv\Desktop\031710\1003151-0 

• • • 3 . D 

Operator : JLB 

Instrument : 30 8 

Acquired : 17 Mar 2010 16:00 using AcqMethod 0308 10BNA.M 

Sample Name : 1003151-03 

Misc Info : 

Abundance TIC: 1003151-03.D\data.ms 

5e+07. 

4.5e+07• 

4e+07 

3.5e+07 

8.432 

3e+07 

/1\ 2.5e+07• 

2e+07 I 

1.5e+07 1 

I 

1e+07 

5000000 

7.825 

Time-> 7.10 7.20 7.30 7.40 7.50 7.60 7.70 7.80 7.90 8.00 8.10 8.20 8.30 8.40 8.50 8.60 8.70 8.80 8.90 9.00 9.10 9.20 

 WM 

Scan 957 (8.432 min): 1003151-03.D\data.ms 

■ 41 

4500000• 

4000000• 

3500000• 

3000000 

2500000 

55 86 

2000000 

1500000 69 

1000000. 100 

500000. 129 

114 

0 Pi'l 1 ,_ 1 . . 11 . . ,, .140, r , 1,5s 1,7o, 182 , i lp i 207, i221 . ‘ 2,37 i i2p , , 2,7o ,2s1 , Fs6, , , , , , , , , i p,,18 , , , 

, , 11,01 m z--> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360