# Effluent Quality Assessment


# FPL Port Everglades Plant

Broward County

NPDES #FL0001538

Sampled December 3, 2007

February 2008

Biology Section
Bureau of Laboratories
Division of Resource Asses sment and Management

Quality Manual No. 870346G
NELAC Certification No. E31780

## 1 FPL Port Everglades Plant, 8100 Eisenhower Rd., Ft. Lauderdale, Broward County, Florida, 33316. NPDES #FL0001538. Effluent samples for this facility were collected on December 3, 2008.



## Introduction Florida Power and Light (FPL) Port Everglades Plant is an electric power generating facility. The facility uses natural gas and oil as fuel and consists of f our generating units (Units 1 through 4) with a total production capacity of 1,254 Mega-watts. The fac ility has a design flow of 800 million gallons per day (MGD). The mean flow from December 2006 through November 2007 was 730 MGD. Wastewater streams at the facility include once-through cooli ng water (OTCW) and low-volume waste streams which include: sluice water, economizer-hopper wash, ai r pre-heater wash, dust-collector wash, equipment wash, boiler-fireside wash, stack-wash and reverse- osmosis water treatment system effluent streams. OTCW is not treated prior to discharge. The low-volu me wastewater treatment system includes: a solids settling basin, precipitation basin, percolation basi n and their overflow areas. The solids settling and precipitation basins are lined with an impermeable liner. The percolation basin has a limestone bottom. The facility also has an equipment-area runoff treatment system that is designed to collect and retain the first inch of rainfall that falls on the plant’s equipm ent area plus minimal flows from the service water rinses in the power-block area. Drainage from areas subject to oil contamination is routed through oil/water separators or oil traps. Storm water runoff in excess of the fi rst inch is routed to the discharge canal. The facility is permitted for surface water disc harge to the Intracoastal Waterway (Class III Marine Waters) through Outfall D-001. The point-of-discharge for Outfall D-001, located approximately at latitude 26o 05’ 01” N, longitude 80o 07’ 26” W, is at a cr oss-section through the discharge canal 182.8 m (600 feet) downstream from the Unit 1 cooling water disc harge structure. Discharge through D-001 includes boiler blowdown, once-through non-contact cooling water, auxiliary equipment cooling water, reverseosmosis reject water, intake-screen wash water, and storm water.

The facility has two land application systems (LAS). LAS R-001, a percolation basin, receives discharge process wastewater, boiler blowdown, treated storm water, reverse osmosis reject water and metal cleaning waste water. LAS R-002, a storm wate r forwarding basin, receives storm water.

The facility has no Administrative Orde rs or Consent Orders. The facility has no mixing zones. A review of DMR data for the past year revealed permit violations during March 2007 for nickel (permit limit ≤ 0.10 mg/L) at ground water monitoring locations NOB-2B (value (0.11 mg/L) and NOB-3A-R (0.16 mg/L); and, for lead (permit limit ≤ 0.015 mg/L) at ground water monitoring location D-1A (value 0.016 mg/L). There were no reported surface water disc harge permit limit violations. (Fac ility information provided by Lisa Gatch of FDEP Southeast District.)



## Methods Samples were collected from the EFF-5 NPDES samp ling point (500 feet downstream from the Unit 1 discharge structure) for Outfall D-001 by Terry Davis (FDEP Southeast District) following DEP-SOP001/01 FS 2400 Wastewater Sampling. All DEP SOPs are available on the web at: http://www.floridadep.org/labs/qa/sops.htm

.

See Appendix A for the completed chain of custody form.

The 96-hour screening toxicity tests and algal growth potential test were performed following internal DEP SOPs TA07_03, TA07_04, and TA08_01 through TA08_09. All internal DEP SOPs are available on the
web at: http://www.floridadep.org/labs/cgi-bin/sop/biosop.asp . The toxicity bioassays were performed in accordance with permit conditions.



## Toxicity Test Results Tests were performed December 4 - 8, 2007.

## 2 Americamysis bahia 96-hour acute screening bioassay – LC 50 

### > 100%, 0% mortality in 100% sample
at 96 hours

Menidia beryllina 96-hour acute screening bioassay – LC 50 

### > 100%, 5% mortality in 100% sample
at 96 hours

The bioassay samples were not acutely toxic to the test organisms.

See Appendix B for bioassay bench sheets. See Appendix C for results of the last 20 standard reference toxicant (SRT) tests and the bench sheets and statisti cal analyses of the SRT tests that correspond to these facility tests. See Appendix D for test organism receipts.



## Algal Growth Potential The effluent Algal Growth Potential (AGP) was less t han the method detection limit of 3 mg dry wt/L of the saltwater species Dunaliella tertiolecta. Raschke and Shultz found that AGP values above 10.0 mg dry weight/L represent a “problem” threshold for marine receiving waters, implying nutrient enrichment (personal communication with Ron Raschke USEPA R egion 4, 1987). Ratios of nitrogen and phosphorus could not be calculated because ortho-phosphate and total phosphorus were not detected in the sample preserved for nutrient analyses. The absence of detec table concentrations of phosphorus suggests that the effluent is phosphorus-limited (Maloney et al. 1974).

See Table 1 for AGP results.



## Chemistry Results

Total residual chlorine and total ammonia were not dete cted in the bioassay sample in the laboratory. The total ammonia concentration in the sample coll ected and preserved for chemical analysis was 0.028 mg/L. Based on the pH, salinity, and temperature of t he effluent as collected, the calculated unionized ammonia concentration was < 0.02 mg/L.

Copper was detected in the effluent at levels that comply with Class III marine water quality criteria (62- 302.530, F.A.C.). Aluminum was detected between the laboratory method detection limits (MDL) and practical quantitation limits (PQL).

See Table 2 for results of analytes detected in t he effluent, and corresponding limits. See Appendix E for a complete list of chemical analyses performed.



## Conclusion The effluent sample collected from the EFF-5 NPDES sampling point for Outfall D-001 for this facility on December 3, 2007, was not acutely toxic to either test species during the 96-hour acute screening bioassays. The effluent AGP result was less than th e "problem” threshold for marine receiving waters. Effluent water quality samples did not exceed any app licable water quality standards or violate any permit
conditions.



## Literature Cited Maloney, T. E., W. E. Miller, and D. T. Specht. 19 74. The Marine Algal Assay Procedure: Bottle Test. National Environmental Research Center Office of Research and Development. U. S. EPA, Corvallis, Oregon. 43 p.

## 3 FPL Port Everglades Plant

Inor g anic Total

Location N:P ratio N:P ratio
Effluent 3.0 AU ND ND

A

- Value reported is the mean of two or more determinations. U - Material was analyzed for but not detected. T he value reported is the minimum detection limit. Table 1. Measured algal growth potential (AGP; mg dry weight/L) of the saltwater species Dunaliella tertiolecta in a sample of effluent from Outfall D-001 of the FPL Port Everglades Plant, collected on December 3, 2007.

AGP (measured)

ND - Not determined. Nutrient ratios could not be calculated because ortho-phosphate and total phosphorus

concentrations were less than their respective method detection limit.

## 4 FPL Port Everglades Plant

NPDES # FL0001538 Class III

Standards Effluent Limits EFF-5 sampling point

None Detected - - -

Aluminum ≤ 1,500 ≤ 1,500 s 26 I

Arsenic ≤ 50 ≤ 50 s 1.5 UJ
Cadmium ≤ 8.8 ≤ 9.3 s 0.06 U Calcium (mg/L) - - 396 A
Chromium-III - - 3 U Copper ≤ 3.7 ≤ 3.7 sd 3.1 AJ

Iron ≤ 300 ≤ 300 s 90 U

Lead ≤ 8.5 ≤ 5.6 s 0.6 U Magnesium (mg/L) - - 1,290 A Mercury ≤ 0.025 ≤ 0.025 s -

Nickel ≤ 8.3 ≤ 8.3 sd 0.75 UJ
Selenium ≤ 71 ≤ 71 s 1.5 UJ
Silver ≤ 2.3 - 0.075 U
Zinc ≤ 86 ≤ 86 s 15 U

Ortho-phosphate - - 0.011 I Total Phosphorus - - 0.02 U

Total Ammonia - - 0.028 J

Un-ionized Ammonia - - ≤ 0.02 c

Nitrate and Nitrite - - 0.064 Total Kjeldahl Nitrogen - - 0.35 Organic Nitrogen - - 0.322 c Total Nitrogen - - 0.414 c

Dissolved Oxygen (mg/L) ≥ 4.0 s ≥ 4.0 se 4.8 pH (SU) 6.5 - 8.5 s 6 - 9 s 7.5 Conductivity (μmhos/cm) - - 48,240 Temperature °C - Report 28.8 Salinity - - 29 c Total Residual Chlorine (mg/L) ≤ 0.01 s ≤ 0.01 s ≤ 0.03 £U Fluoride (mg/L) ≤ 5.0 s ≤ 5.0 s 1.1 Flow (MGD) - ≤ 800 a 730 a Hardness (mg CaCO 3 ) - - 6,301 c

Value exceeds the Class III Water Quality Criteria or permit limits a - Annual average

b - Value is calculated based on hardness

c - Value is calculated d - Limit is greater of concentration in in take cooling water or water quality standard

s - Single sample

A

- Value reported is the mean of two or more determinations I - The reported value is between the l aboratory method detection limit and the l aboratory practical quantitation limit

J - Estimated value U - Material analyzed for but not detected; value reported is the method detection limit £ - Analysis performed in bioassay laboratory e - Permit limit is ≥ concentration in intake cooling water; or, class III marine water quality crit eria if concentration in intake cooling water is > water quality criteria Nutrients (mg/L)

General Physical and Chemical Parameters Table 2. Effluent limits, Class III Criteria for pr edominantly marine waters and chemical data for samples collected from the FPL Port Everglades Plant on December 3, 2007.

Effluent from EFF-5 sampling point

Organic Constituents (μg/L)

Metals (μg/L unless otherwise noted)

## 5 Appendix A. Chain of Custody Form

## 6 Appendix B. Bench Sheets

## 7 Appendix B. (continued)

## 8 Appendix B. (continued)

## 9 Appendix B. (continued)

## 10 Appendix B. (continued)

## 11 Appendix C. SRT Bench Sheet s and Statistical Analysis Florida Department of Environmental Protection
Bureau of Laboratories

Standard Reference Toxicant (SRT) Test Data - 96-hour Acute Toxicity Americamysis bahia (mysid shrimp) - Cadmium Chloride (CdCl 2 

### )

Date LC50 Mean LC50 Std Dev Lower Control Limit Upper Control Limit
03/28/06 39.19

05/02/06 30.56 34.88 6.10 22.67 47.08
06/06/06 42.57 37.44 8.49 20.46 54.42
07/15/06 41.04 38.34 6.54 25.27 51.41
08/01/06 41.44 38.96 4.85 29.26 48.66

09/06/06 41.68 39.41 4.48 30.46 48.37
10/03/06 28.33 37.83 5.85 26.12 49.54
10/31/06 31.68 37.06 5.84 25.38 48.74

11/28/06 32.57 36.56 5.66 25.24 47.89
01/16/07 24.91 35.40 6.49 22.42 48.37
02/13/07 27.31 34.66 6.62 21.41 47.90
03/14/07 27.97 34.10 6.60 20.90 47.31

04/10/07 30.77 33.85 6.39 21.07 46.62
05/08/07 32.52 33.75 6.15 21.46 46.05
05/30/07 38.18 34.05 6.03 21.98 46.11
07/03/07 29.92 33.79 5.92 21.95 45.63

07/31/07 20.10 32.98 6.62 19.74 46.23
09/05/07 31.20 32.89 6.44 20.01 45.76
10/02/07 29.04 32.68 6.32 20.04 45.32

11/06/07 28.93 32.50 6.21 20.08 44.91

CV = 19.10 Lower Confidence Limit = mean - 2 * Std Dev EPA reference 75th quartile CV = 26% Upper Confidence Limit = mean + 2 * Std Dev



### Standard Reference Toxicant Data Americamysis bahia 96 hour LC 50

20 25 30 35 40 45 50 55 6003/28/0605/02/0606/06/0607/15/0608/01/0609/06/0610/03/0610/31/0611/28/0601/16/0702/13/0703/14/0704/10/0705/08/0705/30/0707/03/0707/31/0709/05/0710/02/0711/06/07

Test Dateμg/L CdCl2

LC50 Mean LC50 Lower Control Limit Upper Control Limit

## 12 Appendix C. (continued)
Florida Department of Environmental Protection
Bureau of Laboratories

Standard Reference Toxicant (SRT) Test Data - 96-hour Acute Toxicity Menidia beryllina (inland silverside) - Copper Chloride (CuCl 2 

### )

Date LC50 Mean LC50 Std Dev Lower Control Limit Upper Control Limit
05/31/06 305.64

07/07/06 181.98 243.81 87.44 68.93 418.69

07/15/06 254.77 247.46 62.15 123.16 371.77
08/01/06 210.80 238.30 53.96 130.38 346.21

09/12/06 252.39 241.12 47.15 146.81 335.42

10/03/06 224.51 238.35 42.71 152.92 323.78
10/31/06 202.88 233.28 41.23 150.81 315.75

11/28/06 152.17 223.14 47.75 127.65 318.63

01/16/07 301.29 231.83 51.70 128.42 335.23

02/14/07 279.18 236.56 51.00 134.57 338.55
03/14/07 316.16 243.80 54.00 135.79 351.81

04/10/07 338.35 274.77 58.28 158.21 391.33

05/22/07 265.69 274.17 55.93 162.31 386.03
05/30/07 247.36 272.49 53.76 164.98 380.00

07/03/07 331.66 275.97 73.41 129.15 422.80

07/31/07 359.44 280.61 73.89 132.83 428.39
09/05/07 351.35 284.33 73.62 137.10 431.57

10/02/07 338.91 287.06 72.69 141.69 432.44

11/06/07 419.55 287.50 73.50 140.50 434.51
12/04/07 356.02 284.51 69.07 146.36 422.65

Organism supplier changed July 7, 2006 CV = 24.27 EPA reference 75th quartile CV = 21% Upper warning and control limits are the 75th and 90th percentiles, respectively, of the LC50s. Lower warning and control limits are the 25th and 10th percentiles, respectively, of the LC50s.



## Standard Reference Toxicant Data Menidia beryllina 96-hour LC 50

0 50 100 150 200 250 300 350 400 45005/31/0607/07/0607/15/0608/01/0609/12/0610/03/0610/31/0611/28/0601/16/0702/14/0703/14/0704/10/0705/22/0705/30/0707/03/0707/31/0709/05/0710/02/0711/06/0712/04/07



### Test Dateμg/L CuCl2

LC50 Mean LC50 Lower Control Limit
Upper Control Limit Lower Warning Limit Upper Warning Limit

## 13 Appendix C. (continued)

## 14 Appendix C. (continued)

## 15 Appendix C. (continued)

## 16 Appendix C. (continued)

## 17 Appendix C. (continued)



## A mericam y sis bahia Acute Standard Reference Toxicant Test

DATE: 11-6-07 DURATION : 96 hours TOXICANT : CdCl 2 

## SPECIES: Americamysis bahia

RAW DATA: Concentration Number Mortalities (μg/L) Exposed

.00 20 0
20.00 20 2
30.00 20 11
45.00 20 19
67.00 20 20
100.00 20 20

SPEARMAN-KARBER TRIM: 10.00%

SPEARMAN-KARBER ESTIMATES: LC50: 28.93 μg/L
95% LOWER CONFIDENCE: 25.70
95% UPPER CONFIDENCE: 32.56

-------------------------------------------- ----------------------------------

M enidia ber y llina Acute Standard Reference Toxicant Test

DATE: 12-4-07 DURATION: 96 hours TOXICANT : CuCl 2 

## SPECIES: Menidia beryllina

RAW DATA: Concentration Number Mortalities (μg/L) Exposed

.00 20 0
100.00 20 0
200.00 20 1
300.00 20 4
400.00 20 13
500.00 20 19

SPEARMAN-KARBER TRIM: 5.00%

SPEARMAN-KARBER ESTIMATES: LC50: 356.02 μg/L
95% LOWER CONFIDENCE: 323.74
95% UPPER CONFIDENCE: 391.53

-------------------------------------------- ----------------------------------

## 18 Appendix D. Test Organism Receipts

## 19 Appendix D. (continued)20Appendix E. Chemical Analyses performed on the effluent from the FPL Port Everglades Plant Outfall D-001,sampled on December 3, 2007.DateSampled Field ID Analysis Component Result Remark Units MDL PQL12/3/2007 11:40 Effluent AGP/LN Algal Growth Potential 3 A U mg DryWt/L 3 312/3/2007 11:40 Effluent Chlorophyll/Grain Size/BOD Chlorophyll-a, Corrected 0.55 U ug/L 0.55 1.712/3/2007 11:40 Effluent Chlorophyll/Grain Size/BOD Phaeophytin-a 1.3 ug/L 0.24 0.7112/3/2007 11:40 Effluent Toxicology Bioassay-Acute-Screen-SW-Fish, LC50 100 L LC5012/3/2007 11:40 Effluent Toxicology Bioassay-Acute-Screen-SW-Mysid, LC50 100 L LC5012/3/2007 11:40 Effluent Metals Magnesium 1290 A mg/L 2 812/3/2007 11:40 Effluent Metals Chromium 3 U ug/L 3 1212/3/2007 11:40 Effluent Metals Selenium 1.5 UJ ug/L 1.5 612/3/2007 11:40 Effluent Metals Cadmium 0.06 U ug/L 0.06 0.2412/3/2007 11:40 Effluent Metals Calcium 396 A mg/L 0.22 0.912/3/2007 11:40 Effluent Metals Lead 0.6 U ug/L 0.6 2.412/3/2007 11:40 Effluent Metals Silver 0.075 U ug/L 0.075 0.312/3/2007 11:40 Effluent Metals Copper 3.1 AJ ug/L 0.75 312/3/2007 11:40 Effluent Metals Arsenic 1.5 UJ ug/L 1.5 612/3/2007 11:40 Effluent Metals Aluminum 26 I ug/L 15 6012/3/2007 11:40 Effluent Metals Iron 90 U ug/L 90 36012/3/2007 11:40 Effluent Metals Zinc 15 U ug/L 15 6012/3/2007 11:40 Effluent Metals Nickel 0.75 UJ ug/L 0.75 312/3/2007 11:40 Effluent Nutrients Total-P 0.02 U mg P/L 0.02 0.0612/3/2007 11:40 Effluent Nutrients NO2NO3-N 0.064 mg N/L 0.004 0.0112/3/2007 11:40 Effluent Nutrients O-Phosphate-P 0.011 I mg P/L 0.008 0.0212/3/2007 11:40 Effluent Nutrients Fluoride 1.1 mg F/L 0.1 0.212/3/2007 11:40 Effluent Nutrients Ammonia-N 0.028 J mg N/L 0.01 0.0212/3/2007 11:40 Effluent Nutrients Kjeldahl Nitrogen 0.35 mg N/L 0.08 0.212/3/2007 11:40 Effluent Priority Organic Pollutants 1,2,4-Trichlorobenzene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic PollutantsBis(2-chloroethoxy)methane 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Endosulfan I 3.7 U ug/L 3.7 1512/3/2007 11:40 Effluent Priority Organic Pollutants Endrin 1.4 U ug/L 1.4 5.612/3/2007 11:40 Effluent Priority Organic Pollutants Isophorone 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants N-Nitrosodiphenylamine/ Diphenylamine 2.8 U ug/L 2.8 1112/3/2007 11:40 Effluent Priority Organic Pollutants Phenol 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants 2,4-Dimethylphenol 9.3 U ug/L 9.3 3712/3/2007 11:40 Effluent Priority Organic Pollutants 2-Nitrophenol 0.93 U ug/L 0.93 3.721Appendix E. (continued)DateSampled Field ID Analysis Component Result Remark Units MDL PQL12/3/2007 11:40 Effluent Priority Organic Pollutants Benzidine 93 U ug/L 93 37012/3/2007 11:40 Effluent Priority Organic Pollutants Benzo(a)anthracene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Benzo(g,h,i)perylene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Benzo(k)fluoranthene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Di-n-butyl phthalate 4.7 U ug/L 4.7 1912/3/2007 11:40 Effluent Priority Organic Pollutants Heptachlor epoxide 1.4 U ug/L 1.4 5.612/3/2007 11:40 Effluent Priority Organic Pollutants Hexachlorobenzene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Nitrobenzene 1.9 U ug/L 1.9 7.512/3/2007 11:40 Effluent Priority Organic Pollutants 4-Nitrophenol 14 U ug/L 14 5612/3/2007 11:40 Effluent Priority Organic Pollutants Aldrin 1.4 U ug/L 1.4 5.612/3/2007 11:40 Effluent Priority Organic Pollutants Anthracene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic PollutantsBis(2-chloroethyl)ether 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Bis(2-ethylhexyl)phthalate 14 U ug/L 14 5612/3/2007 11:40 Effluent Priority Organic Pollutants Heptachlor 1.4 U ug/L 1.4 5.612/3/2007 11:40 Effluent Priority Organic Pollutants N-Nitrosodimethylamine 1.9 U ug/L 1.9 7.512/3/2007 11:40 Effluent Priority Organic Pollutants 2,4,6-Trichlorophenol 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants 2-Chlorophenol 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants 4,4'-DDE 1.4 U ug/L 1.4 5.612/3/2007 11:40 Effluent Priority Organic Pollutants 4,4'-DDT 1.4 U ug/L 1.4 5.612/3/2007 11:40 Effluent Priority Organic Pollutants 4-Chlorophenyl phenyl ether 1.9 U ug/L 1.9 7.512/3/2007 11:40 Effluent Priority Organic PollutantsBis(2-chloroisopropyl)ether 2.8 U ug/L 2.8 1112/3/2007 11:40 Effluent Priority Organic Pollutants Butyl benzyl phthalate 4.7 U ug/L 4.7 1912/3/2007 11:40 Effluent Priority Organic Pollutants Endosulfan sulfate 1.4 U ug/L 1.4 5.612/3/2007 11:40 Effluent Priority Organic Pollutants Fluorene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Hexachlorobutadiene 2.8 U ug/L 2.8 1112/3/2007 11:40 Effluent Priority Organic Pollutants Naphthalene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants gamma-BHC 1.4 U ug/L 1.4 5.612/3/2007 11:40 Effluent Priority Organic Pollutants 2-Chloronaphthalene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants 4-Chloro-3-methylphenol 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Fluoranthene 0.93 UJ ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Hexachlorocyclopentadiene 2.8 U ug/L 2.8 1112/3/2007 11:40 Effluent Priority Organic Pollutants Pentachlorophenol 2.8 U ug/L 2.8 1112/3/2007 11:40 Effluent Priority Organic Pollutants alpha-BHC 1.4 U ug/L 1.4 5.612/3/2007 11:40 Effluent Priority Organic Pollutants delta-BHC 1.4 U ug/L 1.4 5.622Appendix E. (continued)DateSampled Field ID Analysis Component Result Remark Units MDL PQL12/3/2007 11:40 Effluent Priority Organic Pollutants 2,4-Dinitrophenol 14 U ug/L 14 5612/3/2007 11:40 Effluent Priority Organic Pollutants 2,4-Dinitrotoluene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants 2,6-Dinitrotoluene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants 2-Methyl-4,6-dinitrophenol 2.8 U ug/L 2.8 1112/3/2007 11:40 Effluent Priority Organic Pollutants 3,3'-Dichlorobenzidine 37 U ug/L 37 15012/3/2007 11:40 Effluent Priority Organic Pollutants 4,4'-DDD 1.4 U ug/L 1.4 5.612/3/2007 11:40 Effluent Priority Organic Pollutants Acenaphthene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Dibenzo(a,h)anthracene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic PollutantsN-Nitrosodi-n-propylamine 1.9 U ug/L 1.9 7.512/3/2007 11:40 Effluent Priority Organic Pollutants Phenanthrene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants beta-BHC 1.4 U ug/L 1.4 5.612/3/2007 11:40 Effluent Priority Organic Pollutants 2,4-Dichlorophenol 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants 4-Bromophenyl phenyl ether 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Chrysene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Di-n-octyl phthalate 0.93 UJ ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Diethyl phthalate 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Hexachloroethane 2.8 U ug/L 2.8 1112/3/2007 11:40 Effluent Priority Organic Pollutants Indeno(1,2,3-cd)pyrene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Pyrene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Acenaphthylene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Benzo(a)pyrene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Benzo(b)fluoranthene 0.93 U ug/L 0.93 3.712/3/2007 11:40 Effluent Priority Organic Pollutants Dieldrin 1.4 U ug/L 1.4 5.612/3/2007 11:40 Effluent Priority Organic Pollutants Dimethyl phthalate 9.3 U ug/L 9.3 3712/3/2007 11:40 Effluent Priority Organic Pollutants Endosulfan II 3.7 U ug/L 3.7 1512/3/2007 11:40 Effluent Priority Organic Pollutants Endrin aldehyde 3.7 U ug/L 3.7 1512/3/2007 11:40 Effluent Field Parameters Sample Depth 0.2 m12/3/2007 11:40 Effluent Field Parameters Temperature 28.82 C12/3/2007 11:40 Effluent Field Parameters Specific Conductance 48240 umhos/cm12/3/2007 11:40 Effluent Field Parameters pH 7.4812/3/2007 12:05 Field Blank Metals Silver 0.025 U ug/L 0.025 0.112/3/2007 12:05 Field Blank Metals Selenium 0.5 U ug/L 0.5 212/3/2007 12:05 Field Blank Metals Magnesium 0.04 U mg/L 0.04 0.1612/3/2007 12:05 Field Blank Metals Arsenic 0.5 U ug/L 0.5 223Appendix E. (continued)DateSampled Field ID Analysis Component Result Remark Units MDL PQL12/3/2007 12:05 Field Blank Metals Copper 0.25 U ug/L 0.25 112/3/2007 12:05 Field Blank Metals Calcium 0.075 U mg/L 0.075 0.312/3/2007 12:05 Field Blank Metals Chromium 1 U ug/L 1 412/3/2007 12:05 Field Blank Metals Nickel 0.25 U ug/L 0.25 112/3/2007 12:05 Field Blank Metals Zinc 5 U ug/L 5 2012/3/2007 12:05 Field Blank Metals Aluminum 5 U ug/L 5 2012/3/2007 12:05 Field Blank Metals Lead 0.2 U ug/L 0.2 0.812/3/2007 12:05 Field Blank Metals Cadmium 0.02 U ug/L 0.02 0.0812/3/2007 12:05 Field Blank Metals Iron 30 U ug/L 30 12012/3/2007 12:05 Field Blank Nutrients Total-P 0.02 U mg P/L 0.02 0.0612/3/2007 12:05 Field Blank Nutrients O-Phosphate-P 0.004 U mg P/L 0.004 0.0112/3/2007 12:05 Field Blank Nutrients Kjeldahl Nitrogen 0.08 U mg N/L 0.08 0.212/3/2007 12:05 Field Blank Nutrients Fluoride 0.05 U mg F/L 0.05 0.112/3/2007 12:05 Field Blank Nutrients NO2NO3-N 0.004 U mg N/L 0.004 0.0112/3/2007 12:05 Field Blank Nutrients Ammonia-N 0.01 U mg N/L 0.01 0.0212/3/2007 12:05 Field Blank Priority Organic Pollutants 2,6-Dinitrotoluene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants 4,4'-DDD 1.4 U ug/L 1.4 5.712/3/2007 12:05 Field Blank Priority Organic Pollutants 4,4'-DDT 1.4 U ug/L 1.4 5.712/3/2007 12:05 Field Blank Priority Organic Pollutants Benzidine 95 U ug/L 95 38012/3/2007 12:05 Field Blank Priority Organic Pollutants Benzo(a)pyrene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Bis(2-chloroethyl)ether 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Chrysene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Endrin aldehyde 3.8 U ug/L 3.8 1512/3/2007 12:05 Field Blank Priority Organic Pollutants Hexachloroethane 2.9 U ug/L 2.9 1112/3/2007 12:05 Field Blank Priority Organic Pollutants 3,3'-Dichlorobenzidine 38 U ug/L 38 15012/3/2007 12:05 Field Blank Priority Organic Pollutants 4-Chloro-3-methylphenol 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Butyl benzyl phthalate 4.8 U ug/L 4.8 1912/3/2007 12:05 Field Blank Priority Organic Pollutants Diethyl phthalate 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Heptachlor epoxide 1.4 U ug/L 1.4 5.712/3/2007 12:05 Field Blank Priority Organic Pollutants Hexachlorobenzene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Indeno(1,2,3-cd)pyrene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Isophorone 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants N-Nitrosodiphenylamine/ Diphenylamine 2.9 U ug/L 2.9 1112/3/2007 12:05 Field Blank Priority Organic Pollutants Naphthalene 0.95 U ug/L 0.95 3.824Appendix E. (continued)DateSampled Field ID Analysis Component Result Remark Units MDL PQL12/3/2007 12:05 Field Blank Priority Organic Pollutants Pentachlorophenol 2.9 U ug/L 2.9 1112/3/2007 12:05 Field Blank Priority Organic Pollutants Phenol 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Pyrene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants beta-BHC 1.4 U ug/L 1.4 5.712/3/2007 12:05 Field Blank Priority Organic Pollutants 4-Chlorophenyl phenyl ether 1.9 U ug/L 1.9 7.612/3/2007 12:05 Field Blank Priority Organic Pollutants 4-Nitrophenol 14 U ug/L 14 5712/3/2007 12:05 Field Blank Priority Organic Pollutants Di-n-octyl phthalate 0.95 UJ ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Dimethyl phthalate 9.5 U ug/L 9.5 3812/3/2007 12:05 Field Blank Priority Organic Pollutants Heptachlor 1.4 U ug/L 1.4 5.712/3/2007 12:05 Field Blank Priority Organic Pollutants N-Nitrosodi-n-propylamine 1.9 U ug/L 1.9 7.612/3/2007 12:05 Field Blank Priority Organic Pollutants Nitrobenzene 1.9 U ug/L 1.9 7.612/3/2007 12:05 Field Blank Priority Organic Pollutants gamma-BHC 1.4 U ug/L 1.4 5.712/3/2007 12:05 Field Blank Priority Organic Pollutants 2,4-Dichlorophenol 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants 2,4-Dimethylphenol 9.5 U ug/L 9.5 3812/3/2007 12:05 Field Blank Priority Organic Pollutants 2-Chlorophenol 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants 2-Nitrophenol 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Acenaphthylene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Aldrin 1.4 U ug/L 1.4 5.712/3/2007 12:05 Field Blank Priority Organic Pollutants Benzo(k)fluoranthene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Bis(2-chloroethoxy)methane 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Bis(2-chloroisopropyl)ether 2.9 U ug/L 2.9 1112/3/2007 12:05 Field Blank Priority Organic Pollutants Fluoranthene 0.95 UJ ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Acenaphthene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Anthracene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Dieldrin 1.4 U ug/L 1.4 5.712/3/2007 12:05 Field Blank Priority Organic Pollutants Hexachlorobutadiene 2.9 U ug/L 2.9 1112/3/2007 12:05 Field Blank Priority Organic Pollutants Hexachlorocyclopentadiene 2.9 U ug/L 2.9 1112/3/2007 12:05 Field Blank Priority Organic Pollutants Phenanthrene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants 1,2,4-Trichlorobenzene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants 2-Chloronaphthalene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants 2-Methyl-4,6-dinitrophenol 2.9 U ug/L 2.9 1112/3/2007 12:05 Field Blank Priority Organic Pollutants 4,4'-DDE 1.4 U ug/L 1.4 5.712/3/2007 12:05 Field Blank Priority Organic Pollutants Benzo(b)fluoranthene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Di-n-butyl phthalate 4.8 U ug/L 4.8 1925Appendix E. (continued)DateSampled Field ID Analysis Component Result Remark Units MDL PQL12/3/2007 12:05 Field Blank Priority Organic Pollutants Endosulfan I 3.8 U ug/L 3.8 1512/3/2007 12:05 Field Blank Priority Organic Pollutants alpha-BHC 1.4 U ug/L 1.4 5.712/3/2007 12:05 Field Blank Priority Organic Pollutants 2,4,6-Trichlorophenol 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants 2,4-Dinitrotoluene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants 4-Bromophenyl phenyl ether 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Benzo(a)anthracene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Endosulfan II 3.8 U ug/L 3.8 1512/3/2007 12:05 Field Blank Priority Organic Pollutants Endrin 1.4 U ug/L 1.4 5.712/3/2007 12:05 Field Blank Priority Organic Pollutants Fluorene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants 2,4-Dinitrophenol 14 U ug/L 14 5712/3/2007 12:05 Field Blank Priority Organic Pollutants Benzo(g,h,i)perylene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Bis(2-ethylhexyl)phthalate 14 U ug/L 14 5712/3/2007 12:05 Field Blank Priority Organic Pollutants Dibenzo(a,h)anthracene 0.95 U ug/L 0.95 3.812/3/2007 12:05 Field Blank Priority Organic Pollutants Endosulfan sulfate 1.4 U ug/L 1.4 5.712/3/2007 12:05 Field Blank Priority Organic Pollutants N-Nitrosodimethylamine 1.9 U ug/L 1.9 7.612/3/2007 12:05 Field Blank Priority Organic Pollutants delta-BHC 1.4 U ug/L 1.4 5.712/3/2007 12:05

## 26 Transaction Code NPDES NUMBER YR/MO/DA Insp Type Inspector Fac Type

1 N 2 5 3 F L 0 0 0 1 5 3 8 11 12 0 7 1 2 0 3 18 B 19 S 20 2

66

Transaction Code NPDES NUMBER YR/MO/DA Insp Type Inspector Fac Type

1 N 2 5 3 F L 0 0 0 1 5 3 8 11 12 0 7 1 2 0 3 18 X 19 S 20 2

66

Transaction Code NPDES NUMBER YR/MO/DA Insp Type Inspector Fac Type

1 N 2 5 3 F L 0 0 0 1 5 3 8 11 12 0 7 1 2 0 3 18 S 19 S 20 2

66 

# Biological Analyses of FPL Port Everglades Plant effluent sampled on December 3, 2007. NPDES #FL0001538.

Fill Out This Section For All Surface Water Discharger Inspections(CEI, CSI, CBI, PAI, XSI-RI Optional)

Remarks Fill Out This Section For All Surface Water Discharger Inspections(CEI, CSI, CBI, PAI, XSI-RI Optional)

Remarks 

# The Bioassay of FPL Port Everglades Plant effluent sampled on December 3, 2007 . NPDES #FL0001538.

Fill Out This Section For All Surface Water Discharger Inspections(CEI, CSI, CBI, PAI, XSI-RI Optional)

Remarks



# The Priority Pollutants Analysis of FPL Port Everglades Plant effluent sampled on December 3, 2007. NPDES #FL0001538.