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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

WASHINGTON, D.C. 20460

OFFICE OF

CHEMICAL SAFETY AND

POLLUTION PREVENTION

Date: 05-JUN-2014

Subject: Sulfentrazone – Acute and Chronic Aggregate Dietary (Food and Drinking 

Water) Exposure and Risk Assessments for the Section 3 Registration Request for 

a New Use on Apples and for the Preliminary Human-Health Risk Assessment for 

Registration Review. 

PC Code: 129081 DP Barcode: D417172

Decision Nos.: 476747, 483232 Registration Nos.: 279-3370, 279-3189, & 279-3220

Petition No.: 3E8202 Regulatory Action: Section 3

Risk Assessment Type: Dietary Case No.: 7231

TXR No.: NA CAS No.: 122836-35-5

MRID No.: NA 40 CFR: §180.498

From: George F. Kramer, Ph.D., Senior Chemist

Risk Assessment Branch 1 (RAB1)

Health Effects Division (HED, 7509P)

Through: Thurston Morton, Senior Chemist

Pete Savoia, Chemist

Dietary Exposure Science Advisory Council (DESAC)

and

Charles W. Smith III, Branch Chief

RAB1/HED (7509P)

To: Laura Nollen/Barbara Madden, RM 05

Registration Division (RD; 7505P)

and

Michael Goodis, RM 53

Pesticide Re-evaluation Division (PRD; 7508P)

Executive Summary

Acute and chronic dietary-exposure and risk assessments were conducted using the Dietary

Exposure Evaluation Model - Food Consumption Intake Database (DEEM-FCID, ver. 3.16) 

which incorporates consumption data from United States Department of Agriculture (USDA) 

National Health and Nutrition Examination Survey, What We Eat in America, 
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(NHANES/WWEIA; 2003-2008). The revised assessment is being conducted in support of a 

new use on apples and the preliminary human-health risk assessment for Registration Review of 

sulfentrazone. This memorandum was reviewed by two peer reviewers of the DESAC, per 

DESAC SOP 2012.1.

Acute Dietary (Food and Drinking Water) Exposure Results and Characterization

The acute analysis assumed tolerance-level residues for all commodities, 100% crop treated 

(%CT), and DEEM (ver. 7.81) default processing factors. The acute analysis also incorporated 

the most recent drinking water estimates provided by the Environmental Fate and Effects 

Division (EFED). The resulting acute food plus water risk estimates are below HED’s level of 

concern [<100% of the acute population-adjusted dose (aPAD)] at the 95th percentile of the 

exposure distribution for the U.S. general population (<1% aPAD). The aPAD is lower for 

females 13 to 49 years old. Although all infants (<1 year old) old had the highest exposure 

estimate (0.026754 mg/kg/day; 1.1% aPAD), the population subgroup with the highest risk 

estimate was females 13 to 49 years old, which utilized 7% of the aPAD (0.009363 mg/kg/day). 

Chronic Dietary (Food and Drinking Water) Exposure Results and Characterization 

The chronic analysis assumed tolerance-level residues, 100% CT, and DEEM (ver. 7.81) default 

processing factors for all commodities. The chronic analysis also incorporated the most recent 

drinking water estimates provided by EFED. The resulting chronic risk estimates are below 

HED’s level of concern for the U.S. general population [<100% of the chronic populationadjusted dose (cPAD)], and all population subgroups. The population subgroup with the greatest 

exposure and risk estimate was children 1-2 years old, which utilized 7% of the cPAD.

Cancer Dietary (Food and Drinking Water) Exposure Results and Characterization

A cancer dietary assessment was not conducted because sulfentrazone is classified as “not likely

to be carcinogenic to humans.”

I. Introduction

Dietary risk assessment incorporates both exposure and toxicity of a given pesticide. For acute 

and chronic assessments, the risk is expressed as a percentage of a maximum acceptable dose 

(i.e., the dose which HED has concluded will result in no unreasonable adverse health effects). 

This dose is referred to as the PAD. The PAD is equivalent to a point-of-departure [POD; e.g., 

no-observable-adverse-effect-level (NOAEL)] divided by the required uncertainty or safety 

factors. For acute and non-cancer chronic exposures, HED is concerned when estimated dietary

risk exceeds 100% of the PAD. References which discuss the acute and chronic risk assessments 

in more detail are available on the EPA/pesticides web site: “Available Information on 

Assessing Exposure from Pesticides, A User’s Guide,” 6/21/2000, web link: 

http://www.epa.gov/fedrgstr/EPA-PEST/2000/July/Day-12/6061.pdf; or see SOP 99.6 (8/20/99). 

The most recent sulfentrazone dietary exposure assessment was conducted by J. Van Alstine for 

the Section 3 registration request for new uses on rhubarb, turnip roots and tops, sunflower 

subgroup 20b, succulent cowpea, succulent lima bean, succulent vegetable soybean, wheat 
Sulfentrazone Dietary Exposure and Risk Assessment D417172

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(spring), citrus fruit group 10-10, low-growing berry group 13-07, tree nut group 14, pistachios, 

and crop group 18 nongrass animal feeds (14-JUN-2012; D389973).

II. Residue Information

Residues of Concern in Plants and Livestock: The HED Metabolism Assessment Review 

Committee (MARC) has determined that the parent compound, sulfentrazone, and the metabolite 

HMS [N-(2,4-dichloro-5-(4-(difluoromethyl)-4,5-dihydro-3-hydroxymethyl-5-oxo-1H-1,2,4-

triazol-yl)phenyl)methanesulfonamide)] are the residues of concern in soybeans, and that 

sulfentrazone and its metabolites HMS and DMS [(N-2,4- dichloro-5-[4-(difluoromethyl)-4,5-

dihydro-5-oxo-1H-1,2,4-triazol-1-yl)phenyl)methanesulfonamide] are the residues of concern in 

rotational crops (Memo, G. Kramer, 14-JUN-1996; D226434). HED has concluded that the 

results of the rotational crop metabolism studies may be translated to support preemergent uses 

on all types of crops. Additionally, sulfentrazone and its metabolites HMS and DMS were 

identified as the residues of concern in meat, milk, poultry, and eggs. The HED MARC

concluded that parent and 3-carboxylic acid sulfentrazone are the residues of concern for the 

drinking-water assessment (Memo, G. Kramer et al., 10-APR-2003; D288713). HED continues 

to consider the given metabolites and degradates to be the residues of concern for risk 

assessment. 

Established/Recommended Tolerances: A tolerance is currently established under 40 CFR 

§180.498(a)(1) for the combined residues of sulfentrazone and its major metabolite, HMS, in/on 

soybean seed at 0.05 ppm. In addition, permanent tolerances are established under 40 CFR 

§180.498(a)(2) for the combined residues of sulfentrazone and its metabolites HMS and DMS 

in/on several food commodities; these established tolerances range from 0.15 ppm (various plant 

commodities) to 0.40 ppm (peanut meal and Brassica, leafy greens, subgroup 5B). Tolerances 

for the combined residues of sulfentrazone and its metabolites HMS and DMS have been 

established under 40 CFR §180.498(c) in connection with regional registrations; these include 

tolerances for residues in/on succulent lima bean, succulent cowpea, and wheat grain at 0.15

ppm. Finally, tolerances are established under 40 CFR §180.498(d) for inadvertent and indirect 

combined residues of sulfentrazone and its metabolites HMS and DMS in/on cereal grain 

(excluding sweet corn) bran, forage, grain, hay, hulls, stover, and straw at 0.1-0.6 ppm as a result 

of the application of sulfentrazone to growing crops.

The proposed uses and the submitted data support the establishment of the following tolerance 

for the combined residues of sulfentrazone and its metabolites HMS and DMS in/on (G. Kramer, 

05-JUN-2014; D415626):

Table 1. Tolerance Summary for Sulfentrazone.

Commodity Recommended 

Tolerance (ppm)

Establish under 40 CFR §180.498(a)(2):

Apple 0.15

Wet apple pomace is the only significant new feedstuff for livestock (ruminants only). As no 

quantifiable residues were found in apples treated at an exaggerated rate (5X) and tolerances are 

established for feed items at higher levels than the recommended tolerance for the combined 

residues of sulfentrazone, DMS, and HMS of 0.15 ppm for apple (e.g., 0.50 ppm for wheat 

forage), the proposed new use on apples is not expected to increase the livestock dietary burdens. 
Sulfentrazone Dietary Exposure and Risk Assessment D417172

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Residues used in the Acute and Chronic Analyses: These analyses employed tolerance-level 

residues for all commodities, 100% CT, and DEEM (ver. 7.81) default processing factors. The 

established tolerance for succulent vegetable soybean is greater than the 40 CFR§180.498(a)(1) 

tolerance for soybean seed; therefore the succulent vegetable soybean tolerance of 0.15 ppm was 

used for soybean seed as a conservative assumption. 

Fish: The USDA Pesticide Data Program (PDP) monitored pesticide residues in catfish in 2008, 

2009, and 2010. In general, pesticide residues would not be expected to be found in fish unless 

the pesticide bio accumulates or has an aquatic use. To determine whether or not residues are 

present in fish, HED now routinely checks PDP monitoring data regardless of the pesticide’s 

uses and physicochemical properties. However, PDP did not analyze catfish samples for 

sulfentrazone. As a result, residues in fish were not included in the assessment.

III. Estimated Drinking Water Concentrations

Drinking water residues provided by EFED (Memo, M. Barrett, 21-MAY-2014; D415627) were 

incorporated directly into the acute and chronic dietary analyses as “water, direct, all sources” 

and “water, indirect, all sources.” The estimated drinking water concentrations (EDWCs) were 

Tier 1 estimates for ground water using the Pesticide Root Zone Model-Ground Water (PRZMGW) model version 1.07 (Screening Concentration In Ground Water) and surface water using 

the Pesticide Root Zone Model/Exposure Analysis Modeling System (PRZM/EXAMS) model. 

The proposed use on apples carries the maximum single and annual application rates for all 

currently registered uses (0.375 lb ai/ A). Previous estimates of sulfentrazone residues in 

drinking water were done separately for parent and the 3-carboxylic acid sulfentrazone 

degradate. Sulfentrazone and 3-carboxylic acid sulfentrazone have a potential to reach both 

surface and ground waters that may be used as drinking water sources. This revised assessment 

has now taken a total toxic residues (TTR) approach to assessing exposure, instead of providing 

values for each compound individually.

For surface water, the highest acute (peak) sulfentrazone value is 37.3 ppb and the 10-year 

average value is 5.3 ppb. For ground water, the highest daily value (peak) sulfentrazone value is 

134 ppb and the post-breakthrough-average value is 98 ppb. EDWCs of 0.134 ppm and 0.098

ppm were used in the acute and chronic analyses, respectively.

Table 2. Estimated Tier 1 Concentrations of Sulfentrazone and 3-Carboxylic Acid Sulfentrazone in 

Drinking Water Due to the Use of Sulfentrazone.

Scenario

Surface Water (ug/L) Groundwater (ug/L)

Acute Chronic Acute Chronic

FL Sugarcane 37.3 3.2 - -

LA Corn 31.3 5.3 - -

Delmarva Sw. corn - - 134 98

IV. DEEM-FCID Program and Consumption Information

Sulfentrazone acute and chronic dietary exposure assessments were conducted using the DEEMFCID, Version 3.16, which incorporates 2003-2008 consumption data from USDA’s 

NHANES/WWEIA. The data are based on the reported consumption of more than 20,000 

individuals over two non-consecutive survey days. Foods “as consumed” (e.g., apple pie) are 
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linked to EPA-defined food commodities (e.g., apples, peeled fruit - cooked; fresh or N/S; baked; 

or wheat flour - cooked; fresh or N/S, baked) using publicly available recipe translation files 

developed jointly by USDA/ARS and EPA. For chronic exposure assessment, consumption data 

are averaged for the entire U.S. population and within population subgroups. However, for acute 

exposure assessment, consumption data are retained as individual consumption events. Based on 

analysis of the 2003-2008 WWEIA consumption data, which took into account dietary patterns 

and survey respondents, HED concluded that it is most appropriate to report risk for the 

following population subgroups: the general U.S. population, all infants (<1 year old), children 

1-2, children 3-5, children 6-12, youth 13-19, adults 20-49, females 13-49, and adults 50-99 

years old.

For a chronic dietary exposure assessment, an estimate of the residue level in each food or foodform (e.g., orange or orange juice) on the food commodity residue list is multiplied by the 

average daily consumption estimate for that food/food form to produce a residue intake estimate. 

The resulting residue intake estimate for each food/food form is summed with the residue intake 

estimates for all other food/food forms on the commodity residue list to arrive at the total 

average estimated exposure. Exposure is expressed in mg/kg body weight/day and as a percent 

of the cPAD. This procedure is performed for each population subgroup.

For an acute exposure assessment, individual one-day food consumption data are used on an 

individual-by-individual basis. The reported consumption amounts of each food item can be 

multiplied by a residue point estimate and summed to obtain a total daily pesticide exposure for a 

deterministic exposure assessment, or “matched” in multiple random pairings with residue values 

and then summed in a probabilistic assessment. The resulting distribution of exposures is 

expressed as a percentage of the aPAD on both a user (i.e., only those who reported eating 

relevant commodities/food forms) and a per-capita (i.e., those who reported eating the relevant 

commodities as well as those who did not) basis. In accordance with HED policy, per capita 

exposure and risk are reported for analyses performed at all levels of refinement. However, for 

deterministic assessments, any significant differences in user vs. per capita exposure and risk are 

specifically identified and noted in the risk assessment.

V. Toxicological Information

The RAB1 toxicologists have reevaluated the sulfentrazone database and updated the endpoints 

as necessary. The toxicological endpoints selected for sulfentrazone are summarized below in 

Table 3.
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Table 3. Summary of Toxicological Doses and Endpoints for Sulfentrazone for Use in Human-Health Risk 

Assessments.

Exposure

Scenario

Point of 

Departure

Uncertainty/

FQPA Safety 

Factors

RfD, PAD, Level 

of Concern for 

Risk Assessment

Study and Toxicological Effects

Acute Dietary

(Females 13-

49)

NOAEL = 

14 

mg/kg/day

UFA = 10X

UFH = 10X

FQPA SF = 

1X

aRfD = aPAD = 

0.14 mg/kg/day

Two-Gen. Reproductive Toxicity Study – Rat.

Offspring Toxicity LOAEL = 33 (M) and 40 (F) 

mg/kg/day based on reduced prenatal viability (fetal & 

litter), reduced litter size, increased no. of stillborn 

pups, reduced pup and litter postnatal survival, and 

decreased pup body weights throughout lactation.

Acute Dietary

(General 

population

including 

infants

and children)

NOAEL = 

250 

mg/kg/day

UFA = 10X

UFH = 10X

FQPA SF = 

1X

aRfD = aPAD = 

2.5 mg/kg/day

Acute-Neurotoxicity Study – Rat.

LOAEL = 750 mg/kg/day based on increased 

incidence of clinical signs and FOB parameters and 

decreased motor activity.

Chronic 

Dietary

(all 

populations)

NOAEL = 

14 

mg/kg/day 

UFA = 10X

UFH = 10X

FQPA SF = 

1X

cRfD = cPAD =

0.14 mg/kg/day

Two-Gen. Reproductive Toxicity Study – Rat.

Offspring Toxicity LOAEL = 33 (M) and 40 (F) 

mg/kg/day based on reduced prenatal viability (fetal & 

litter), reduced litter size, increased no. of stillborn 

pups, reduced pup and litter postnatal survival, and 

decreased pup body weights throughout lactation.

Cancer (oral, 

dermal, 

inhalation)

Classification: Sulfentrazone is classified as “not likely to be carcinogenic to humans.”

NOAEL = no-observed adverse-effect level. LOAEL = lowest-observed adverse-effect level. UF = uncertainty factor. UFA = 

extrapolation from animal to human (interspecies). UFH = potential variation in sensitivity among members of the human 

population (intraspecies). UFL = extrapolation for use of a LOAEL in the absence of a NOAEL. FQPA SF = FQPA Safety 

Factor. PAD = population-adjusted dose (a = acute, c = chronic). RfD = reference dose. MOE = margin of exposure, LOC = 

level of concern.

VI. Results/Discussion

For acute and chronic assessments, HED is concerned when dietary risk exceeds 100% of the 

PAD. The DEEM-FCID analyses estimate the dietary exposure of the U.S. population and 

various population subgroups. The results reported in Table 4 are for the general U.S. 

population, all infants (<1 year old), children 1-2 years old, children 3-5 years old, children 6-12 

years old, youth 13-19 years old, females 13-49 years old, adults 20-49 years old, and adults 50-

99 years old.

The resulting acute food plus water risk estimates are below HED’s level of concern (<100% 

aPAD) at the 95th percentile of the exposure distribution for the general U.S. population (<1% 

aPAD), and all population subgroups. The population subgroup with the greatest acute risk 

estimate was females 13 to 49 years, which utilized 7% of the aPAD. The population with the 

greatest acute exposure estimate was all infants (<1 year old) (0.026754 mg/kg/day; 1.1% 

aPAD). The resulting chronic risk estimates are also below HED’s level of concern for the U.S. 

general population (<100% cPAD), and all population subgroups. The most highly exposed 

population was children 1-2 years old, with a chronic risk estimated that utilized 7% of the 

cPAD. 
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Table 4. Summary of Acute and Chronic Dietary (Food and Drinking Water) Exposure and Risk for 

Sulfentrazone.1

Population Subgroup

95th Percentile cPAD 

(mg/kg/day)

Exposure 

(mg/kg/day) aPAD %cPAD

(mg/kg/day)

Exposure 

(mg/kg/day) %aPAD

General U.S. Population

2.5

0.011114 <1.0

0.14

0.003973 2.8

All Infants (<1 year old) 0.026754 1.1 0.008577 6.1

Children 1-2 years old 0.022692 <1.0 0.009881 7.1

Children 3-5 years old 0.017984 <1.0 0.007889 5.6

Children 6-12 years old 0.011833 <1.0 0.004817 3.4

Youth 13-19 years old 0.008607 <1.0 0.003225 2.3

Adults 20-49 years old 0.009187 <1.0 0.003498 2.5

Adults 50-99 years old 0.008301 <1.0 0.003314 2.4

Females 13-49 years old 0.14 0.009363 6.7 0.003450 2.5

1 The populations with the greatest risk estimates are bolded.

VII. Characterization of Inputs/Outputs

The unrefined acute and chronic analyses assumed tolerance-level residues for all commodities, 

100% CT, and DEEM (ver. 7.81) default processing factors (as necessary). These analyses are 

considered to be conservative and could be refined through the use of anticipated-residue 

estimates (ARs) for all commodities, %CT data for registered commodities, and empirical 

processing factors. In order to provide a comparison for reference, the dietary results for the 

analysis of food exposures (only) are presented in attachments 5 & 6. 

VIII. Conclusions

The acute and chronic dietary exposure and risk estimates for sulfentrazone are below HED’s 

level of concern. For acute food and drinking water exposures, although all infants (<1 year old) 

had the greatest exposure estimate (0.026754 mg/kg/day; 1% aPAD), females 13 to 49 years old

had the greatest risk estimate (0.009363 mg/kg/day; 7% of the aPAD). For food and drinking 

water chronic exposure, the most highly exposed population subgroup was children 1-2 years 

old, with an estimated risk of 7% of the cPAD. The acute and chronic dietary exposure 

assessments support the proposed new use of sulfentrazone.

Attachments

Attachment 1: DEEM-FCID Acute Residue File.

Attachment 2: DEEM-FCID Acute Exposure Estimates for the General Population Including Infants and 

Children. 

Attachment 3: DEEM-FCID Chronic Residue File.

Attachment 4: DEEM-FCID Chronic Exposure Estimates.

Attachment 5: DEEM-FCID Acute Exposure Estimates for the General Population Including Infants and 

Children (food only).

Attachment 6: DEEM-FCID Chronic Exposure Estimates (food only).

cc: G. Kramer (RAB1)

RDI: DESAC (5/15/14)

G.F. Kramer:S10957:PY-S:(703)305-5079:7509P:RAB1
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Attachment 1: DEEM-FCID Acute Residue File.

Filename: C:\Users\gkramer\Documents\Gk\##Sulfentrazone\129081-ACUTE__30 APR 2014.R08

Chemical: Sulfentrazone

RfD(Chronic): .14 mg/kg bw/day NOEL(Chronic): 14 mg/kg bw/day

RfD(Acute): 2.5 mg/kg bw/day NOEL(Acute): 250 mg/kg bw/day

Date created/last modified: 04-30-2014/16:06:50 Program ver. 3.16, 03-08-d

-----------------------------------------------------------------------------------

 EPA Crop Def Res Adj.Factors Comment

 Code Grp Commodity Name (ppm) #1 #2 

---------- ---- ------------------------------- ---------- ------ ------ -------

0101190000 1AB Horseradish 0.200000 1.000 1.000 

0101388000 1AB Turnip, roots 0.150000 1.000 1.000 

0103015000 1CD Arrowroot, flour 0.150000 1.000 1.000 

0103015001 1CD Arrowroot, flour-babyfood 0.150000 1.000 1.000 

0103017000 1CD Artichoke, Jerusalem 0.150000 1.000 1.000 

0103082000 1CD Cassava 0.150000 1.000 1.000 

0103082001 1CD Cassava-babyfood 0.150000 1.000 1.000 

0103139000 1CD Dasheen, corm 0.150000 1.000 1.000 

0103166000 1CD Ginger 0.150000 1.000 1.000 

0103166001 1CD Ginger-babyfood 0.150000 1.000 1.000 

0103167000 1CD Ginger, dried 0.150000 1.000 1.000 

0103296000 1C Potato, chips 0.150000 1.000 1.000 

0103297000 1C Potato, dry (granules/ flakes) 0.150000 6.500 1.000 

0103297001 1C Potato, dry (granules/ flakes)-b 0.150000 6.500 1.000 

0103298000 1C Potato, flour 0.150000 6.500 1.000 

0103298001 1C Potato, flour-babyfood 0.150000 6.500 1.000 

0103299000 1C Potato, tuber, w/peel 0.150000 1.000 1.000 

0103299001 1C Potato, tuber, w/peel-babyfood 0.150000 1.000 1.000 

0103300000 1C Potato, tuber, w/o peel 0.150000 1.000 1.000 

0103300001 1C Potato, tuber, w/o peel-babyfood 0.150000 1.000 1.000 

0103366000 1CD Sweet potato 0.150000 1.000 1.000 

0103366001 1CD Sweet potato-babyfood 0.150000 1.000 1.000 

0103371000 1CD Tanier, corm 0.150000 1.000 1.000 

0103387000 1CD Turmeric 0.150000 1.000 1.000 

0103406000 1CD Yam, true 0.150000 1.000 1.000 

0103407000 1CD Yam bean 0.150000 1.000 1.000 

0402322000 4B Rhubarb 0.150000 1.000 1.000 

0501061000 5A Broccoli 0.200000 1.000 1.000 

0501061001 5A Broccoli-babyfood 0.200000 1.000 1.000 

0501062000 5A Broccoli, Chinese 0.200000 1.000 1.000 

0501064000 5A Brussels sprouts 0.200000 1.000 1.000 

0501069000 5A Cabbage 0.200000 1.000 1.000 1E0631

 Full comment: 1E06311

0501071000 5A Cabbage, Chinese, napa 0.200000 1.000 1.000 1E0631

 Full comment: 1E06311

0501072000 5A Cabbage, Chinese, mustard 0.200000 1.000 1.000 1E0631

 Full comment: 1E06311

0501083000 5A Cauliflower 0.200000 1.000 1.000 

0501196000 5A Kohlrabi 0.200000 1.000 1.000 

0502063000 5B Broccoli raab 0.400000 1.000 1.000 

0502070000 5B Cabbage, Chinese, bok choy 0.400000 1.000 1.000 1E0631

 Full comment: 1E06311

0502117000 5B Collards 0.400000 1.000 1.000 

0502194000 5B Kale 0.400000 1.000 1.000 

0502229000 5B Mustard greens 0.400000 1.000 1.000 

0502318000 5B Rape greens 0.400000 1.000 1.000 

0502389000 5B Turnip, greens 0.600000 1.000 1.000 

0600347000 6 Soybean, seed 0.150000 1.000 1.000 

0600349000 6 Soybean, soy milk 0.150000 1.000 1.000 

0600349001 6 Soybean, soy milk-babyfood or in 0.150000 1.000 1.000 

0600350000 6 Soybean, oil 0.150000 1.000 1.000 

0600350001 6 Soybean, oil-babyfood 0.150000 1.000 1.000 

0601043000 6A Bean, snap, succulent 0.150000 1.000 1.000 

0601043001 6A Bean, snap, succulent-babyfood 0.150000 1.000 1.000 

0601257000 6A Pea, edible podded, succulent 0.150000 1.000 1.000 

0602031000 6B Bean, broad, succulent 0.150000 1.000 1.000 

0602033000 6B Bean, cowpea, succulent 0.150000 1.000 1.000 

0602037000 6B Bean, lima, succulent 0.150000 1.000 1.000 

0602255000 6B Pea, succulent 0.150000 1.000 1.000 

0602255001 6B Pea, succulent-babyfood 0.150000 1.000 1.000 

0602259000 6B Pea, pigeon, succulent 0.150000 1.000 1.000 
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0603030000 6C Bean, black, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603032000 6C Bean, broad, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603034000 6C Bean, cowpea, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603035000 6C Bean, great northern, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603036000 6C Bean, kidney, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603038000 6C Bean, lima, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603039000 6C Bean, mung, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603040000 6C Bean, navy, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603041000 6C Bean, pink, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603042000 6C Bean, pinto, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603098000 6C Chickpea, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603098001 6C Chickpea, seed-babyfood 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603099000 6C Chickpea, flour 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603182000 6C Guar, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603182001 6C Guar, seed-babyfood 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603203000 6C Lentil, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603256000 6C Pea, dry 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603256001 6C Pea, dry-babyfood 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603258000 6C Pea, pigeon, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603348000 6C Soybean, flour 0.150000 1.000 1.000 

0603348001 6C Soybean, flour-babyfood 0.150000 1.000 1.000 

0801374000 8A Tomatillo 0.150000 1.000 1.000 

0801375000 8A Tomato 0.150000 1.000 1.000 

0801375001 8A Tomato-babyfood 0.150000 1.000 1.000 

0801376000 8A Tomato, paste 0.150000 5.400 1.000 

0801376001 8A Tomato, paste-babyfood 0.150000 5.400 1.000 

0801377000 8A Tomato, puree 0.150000 3.300 1.000 

0801377001 8A Tomato, puree-babyfood 0.150000 3.300 1.000 

0801378000 8A Tomato, dried 0.150000 14.300 1.000 

0801378001 8A Tomato, dried-babyfood 0.150000 14.300 1.000 

0801379000 8A Tomato, juice 0.150000 1.500 1.000 

0801380000 8A Tomato, Tree 0.150000 1.000 1.000 

0802148000 8BC Eggplant 0.150000 1.000 1.000 

0802234000 8BC Okra 0.150000 1.000 1.000 

0802270000 8B Pepper, bell 0.150000 1.000 1.000 

0802270001 8B Pepper, bell-babyfood 0.150000 1.000 1.000 

0802271000 8B Pepper, bell, dried 0.150000 1.000 1.000 

0802271001 8B Pepper, bell, dried-babyfood 0.150000 1.000 1.000 

0802272000 8BC Pepper, nonbell 0.150000 1.000 1.000 

0802272001 8BC Pepper, nonbell-babyfood 0.150000 1.000 1.000 

0802273000 8BC Pepper, nonbell, dried 0.150000 1.000 1.000 

0901075000 9A Cantaloupe 0.150000 1.000 1.000 

0901187000 9A Honeydew melon 0.150000 1.000 1.000 

0901399000 9A Watermelon 0.150000 1.000 1.000 

0901400000 9A Watermelon, juice 0.150000 1.000 1.000 

1001106000 10A Citron 0.150000 1.000 1.000 

1001107000 10A Citrus hybrids 0.150000 1.000 1.000 

1001108000 10A Citrus, oil 0.150000 1.000 1.000 

1001240000 10A Orange 0.150000 1.000 1.000 

1001241000 10A Orange, juice 0.150000 1.800 1.000 

1001241001 10A Orange, juice-babyfood 0.150000 1.800 1.000 

1001242000 10A Orange, peel 0.150000 1.000 1.000 

1001369000 10A Tangerine 0.150000 1.000 1.000 
Sulfentrazone Dietary Exposure and Risk Assessment D417172

____________________________________________________________________________________________

Page 10 of 21

1001370000 10A Tangerine, juice 0.150000 2.300 1.000 

1002197000 10B Kumquat 0.150000 1.000 1.000 

1002199000 10B Lemon 0.150000 1.000 1.000 

1002200000 10B Lemon, juice 0.150000 2.000 1.000 

1002200001 10B Lemon, juice-babyfood 0.150000 2.000 1.000 

1002201000 10B Lemon, peel 0.150000 1.000 1.000 

1002206000 10B Lime 0.150000 1.000 1.000 

1002207000 10B Lime, juice 0.150000 2.000 1.000 

1002207001 10B Lime, juice-babyfood 0.150000 2.000 1.000 

1003180000 10C Grapefruit 0.150000 1.000 1.000 

1003181000 10C Grapefruit, juice 0.150000 2.100 1.000 

1003307000 10C Pummelo 0.150000 1.000 1.000 

1100007000 11 Apple, fruit with peel 0.150000 1.000 1.000 

1100008000 11 Apple, peeled fruit 0.150000 1.000 1.000 

1100008001 11 Apple, peeled fruit-babyfood 0.150000 1.000 1.000 

1100009000 11 Apple, dried 0.150000 8.000 1.000 

1100009001 11 Apple, dried-babyfood 0.150000 8.000 1.000 

1100010000 11 Apple, juice 0.150000 1.300 1.000 

1100010001 11 Apple, juice-babyfood 0.150000 1.300 1.000 

1100011000 11 Apple, sauce 0.150000 1.000 1.000 

1100011001 11 Apple, sauce-babyfood 0.150000 1.000 1.000 

1301055000 13A Blackberry 0.150000 1.000 1.000 

1301056000 13A Blackberry, juice 0.150000 1.000 1.000 

1301056001 13A Blackberry, juice-babyfood 0.150000 1.000 1.000 

1301058000 13A Boysenberry 0.150000 1.000 1.000 

1301208000 13A Loganberry 0.150000 1.000 1.000 

1301320000 13A Raspberry 0.150000 1.000 1.000 

1301320001 13A Raspberry-babyfood 0.150000 1.000 1.000 

1301321000 13A Raspberry, juice 0.150000 1.000 1.000 

1301321001 13A Raspberry, juice-babyfood 0.150000 1.000 1.000 

1302057000 13B Blueberry 0.150000 1.000 1.000 

1302057001 13B Blueberry-babyfood 0.150000 1.000 1.000 

1302136000 13B Currant 0.150000 1.000 1.000 

1302137000 13B Currant, dried 0.150000 1.000 1.000 

1302149000 13B Elderberry 0.150000 1.000 1.000 

1302174000 13B Gooseberry 0.150000 1.000 1.000 

1302191000 13B Huckleberry 0.150000 1.000 1.000 

1303227000 13C Mulberry 0.150000 1.000 1.000 

1304175000 13D Grape 0.150000 1.000 1.000 

1304176000 13D Grape, juice 0.150000 1.200 1.000 

1304176001 13D Grape, juice-babyfood 0.150000 1.200 1.000 

1304179000 13D Grape, wine and sherry 0.150000 1.000 1.000 

1304195000 13D Kiwifruit, fuzzy 0.150000 1.000 1.000 

1307130000 13G Cranberry 0.150000 1.000 1.000 

1307130001 13G Cranberry-babyfood 0.150000 1.000 1.000 

1307131000 13G Cranberry, dried 0.150000 1.000 1.000 

1307132000 13G Cranberry, juice 0.150000 1.100 1.000 

1307132001 13G Cranberry, juice-babyfood 0.150000 1.100 1.000 

1307359000 13G Strawberry 0.150000 1.000 1.000 

1307359001 13G Strawberry-babyfood 0.150000 1.000 1.000 

1307360000 13G Strawberry, juice 0.150000 1.000 1.000 

1307360001 13G Strawberry, juice-babyfood 0.150000 1.000 1.000 

1400003000 14 Almond 0.150000 1.000 1.000 

1400003001 14 Almond-babyfood 0.150000 1.000 1.000 

1400004000 14 Almond, oil 0.150000 1.000 1.000 

1400004001 14 Almond, oil-babyfood 0.150000 1.000 1.000 

1400059000 14 Brazil nut 0.150000 1.000 1.000 

1400068000 14 Butternut 0.150000 1.000 1.000 

1400081000 14 Cashew 0.150000 1.000 1.000 

1400092000 14 Chestnut 0.150000 1.000 1.000 

1400155000 14 Hazelnut 0.150000 1.000 1.000 

1400156000 14 Hazelnut, oil 0.150000 1.000 1.000 

1400185000 14 Hickory nut 0.150000 1.000 1.000 

1400213000 14 Macadamia nut 0.150000 1.000 1.000 

1400269000 14 Pecan 0.150000 1.000 1.000 

1400282000 14 Pistachio 0.150000 1.000 1.000 

1400391000 14 Walnut 0.150000 1.000 1.000 

1500025000 15 Barley, pearled barley 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500025001 15 Barley, pearled barley-babyfood 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500026000 15 Barley, flour 0.100000 1.000 1.000 Inadve
Sulfentrazone Dietary Exposure and Risk Assessment D417172

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Page 11 of 21

 Full comment: Inadvertent tol.

1500026001 15 Barley, flour-babyfood 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500027000 15 Barley, bran 0.150000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500065000 15 Buckwheat 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500066000 15 Buckwheat, flour 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500120000 15 Corn, field, flour 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500120001 15 Corn, field, flour-babyfood 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500121000 15 Corn, field, meal 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500121001 15 Corn, field, meal-babyfood 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500122000 15 Corn, field, bran 0.150000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500123000 15 Corn, field, starch 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500123001 15 Corn, field, starch-babyfood 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500124000 15 Corn, field, syrup 0.150000 1.500 1.000 2F0639

 Full comment: 2F06391

1500124001 15 Corn, field, syrup-babyfood 0.150000 1.500 1.000 2F0639

 Full comment: 2F06391

1500125000 15 Corn, field, oil 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500125001 15 Corn, field, oil-babyfood 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500126000 15 Corn, pop 0.100000 1.000 1.000 2F0639

 Full comment: 2F06391

1500226000 15 Millet, grain 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500231000 15 Oat, bran 0.150000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500232000 15 Oat, flour 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500232001 15 Oat, flour-babyfood 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500233000 15 Oat, groats/rolled oats 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500233001 15 Oat, groats/rolled oats-babyfood 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500323000 15 Rice, white 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500323001 15 Rice, white-babyfood 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500324000 15 Rice, brown 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500324001 15 Rice, brown-babyfood 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500325000 15 Rice, flour 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500325001 15 Rice, flour-babyfood 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500326000 15 Rice, bran 0.150000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500326001 15 Rice, bran-babyfood 0.150000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500328000 15 Rye, grain 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500329000 15 Rye, flour 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500344000 15 Sorghum, grain 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500345000 15 Sorghum, syrup 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500381000 15 Triticale, flour 0.150000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500381001 15 Triticale, flour-babyfood 0.150000 1.000 1.000 Inadve
Sulfentrazone Dietary Exposure and Risk Assessment D417172

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Page 12 of 21

 Full comment: Inadvertent tol.

1500401000 15 Wheat, grain 0.150000 1.000 1.000 

1500401001 15 Wheat, grain-babyfood 0.150000 1.000 1.000 

1500402000 15 Wheat, flour 0.150000 1.000 1.000 

1500402001 15 Wheat, flour-babyfood 0.150000 1.000 1.000 

1500403000 15 Wheat, germ 0.150000 1.000 1.000 

1500404000 15 Wheat, bran 0.150000 1.000 1.000 

1500405000 15 Wild rice 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1800002000 18 Alfalfa, seed 0.150000 1.000 1.000 

2001163000 20A Flax seed, oil 0.150000 1.000 1.000 

2002330000 20B Safflower, oil 0.200000 1.000 1.000 

2002330001 20B Safflower, oil-babyfood 0.200000 1.000 1.000 

2002364000 20B Sunflower, seed 0.200000 1.000 1.000 

2002365000 20B Sunflower, oil 0.200000 1.000 1.000 

2002365001 20B Sunflower, oil-babyfood 0.200000 1.000 1.000 

8601000000 86A Water, direct, all sources 0.134000 1.000 1.000 

8602000000 86B Water, indirect, all sources 0.134000 1.000 1.000 

9500019000 O Asparagus 0.150000 1.000 1.000 2E0650

 Full comment: 2E06500

9500177000 O Grape, leaves 0.150000 1.000 1.000 

9500178000 O Grape, raisin 0.150000 4.300 1.000 

9500263000 O Peanut 0.200000 1.000 1.000 0F0611

 Full comment: 0F06116

9500264000 O Peanut, butter 0.200000 1.890 1.000 0F0611

 Full comment: 0F06116

9500265000 O Peanut, oil 0.200000 1.000 1.000 0F0611

 Full comment: 0F06116

9500275000 O Peppermint 0.300000 1.000 1.000 1E0631

 Full comment: 1E06311

9500276000 O Peppermint, oil 0.300000 1.000 1.000 1E0631

 Full comment: 1E06311

9500352000 O Spearmint 0.300000 1.000 1.000 1E0631

 Full comment: 1E06311

9500353000 O Spearmint, oil 0.300000 1.000 1.000 1E0631

 Full comment: 1E06311

9500362000 O Sugarcane, sugar 0.150000 1.000 1.000 

9500362001 O Sugarcane, sugar-babyfood 0.150000 1.000 1.000 

9500363000 O Sugarcane, molasses 0.200000 1.000 1.000 

9500363001 O Sugarcane, molasses-babyfood 0.200000 1.000 1.000 
Sulfentrazone Dietary Exposure and Risk Assessment D417172

____________________________________________________________________________________________

Page 13 of 21

Attachment 2: DEEM-FCID Acute Exposure Estimates for the General Population including Infants 

and Children.

1

US EPA Ver. 3.18, 03-08-d

DEEM-FCID ACUTE Analysis for SULFENTRAZONE NHANES 2003-2008 2-Day

Residue file: 129081-ACUTE__30 APR 2014.R08 Adjustment factor #2 NOT used.

Analysis Date: 04-30-2014/16:13:22 Residue file dated: 04-30-2014/16:06:50

NOEL (Acute) = 250.000000 mg/kg body-wt/day

RAC/FF intake summed over 24 hours

Run Comment: ""

===============================================================================

Summary calculations--per capita:

--- 95th Percentile---- --- 99th Percentile---- ---99.9th Percentile----

Exposure % aRfD MOE Exposure % aRfD MOE Exposure % aRfD MOE 

---------- ------- -------- ---------- ------- -------- ---------- ------- --------

Total US Population:

 0.011114 0.44 22494 0.017876 0.72 13985 0.030344 1.21 8238 

All Infants:

 0.026754 1.07 9344 0.036226 1.45 6901 0.046693 1.87 5354 

Female 13-50:

 0.009350 0.37 26738 0.013001 0.52 19228 0.017681 0.71 14139 

Children 1-2:

 0.022692 0.91 11017 0.034157 1.37 7319 0.054184 2.17 4613 

Children 3-5:

 0.017984 0.72 13901 0.025050 1.00 9980 0.031751 1.27 7873 

Children 6-12:

 0.011833 0.47 21127 0.018540 0.74 13484 0.026966 1.08 9271 

Youth 13-19:

 0.008607 0.34 29046 0.012752 0.51 19604 0.017460 0.70 14318 

Adults 20-49:

 0.009187 0.37 27211 0.013200 0.53 18940 0.018245 0.73 13702 

Adults 50-99:

 0.008301 0.33 30116 0.011532 0.46 21678 0.017442 0.70 14333 

Female 13-49:

 0.009363 0.372 26699 0.013010 0.52 19215 0.017647 0.71 14166 

1 The aPAD for the general population including infants and children = 2.5 mg/kg bw/day. The aPAD for females 13-49 years 

old = 0.14 mg/kg bw/day.

2 This value was calculated by DEEM using an aPAD of 2.5 mg/kg bw/day. The % aPAD reported in Table 4 was adjusted to 

account for the lower aPAD (0.14 mg/kg bw/day) for females 13-49 years old using the following formula: % aPAD = 

(Exposure/aPAD)*100% = (0.009363/0.14)*100% = 6.7%.
Sulfentrazone Dietary Exposure and Risk Assessment D417172

____________________________________________________________________________________________

Page 14 of 21

Attachment 3: DEEM-FCID Chronic Residue File.

Filename: C:\Users\gkramer\Documents\Gk\##Sulfentrazone\129081-CHRON__30 APR 2014.R08

Chemical: Sulfentrazone

RfD(Chronic): .14 mg/kg bw/day NOEL(Chronic): 14 mg/kg bw/day

RfD(Acute): 2.5 mg/kg bw/day NOEL(Acute): 250 mg/kg bw/day

Date created/last modified: 04-30-2014/16:08:32 Program ver. 3.16, 03-08-d

-----------------------------------------------------------------------------------

 EPA Crop Def Res Adj.Factors Comment

 Code Grp Commodity Name (ppm) #1 #2 

---------- ---- ------------------------------- ---------- ------ ------ -------

0101190000 1AB Horseradish 0.200000 1.000 1.000 

0101388000 1AB Turnip, roots 0.150000 1.000 1.000 

0103015000 1CD Arrowroot, flour 0.150000 1.000 1.000 

0103015001 1CD Arrowroot, flour-babyfood 0.150000 1.000 1.000 

0103017000 1CD Artichoke, Jerusalem 0.150000 1.000 1.000 

0103082000 1CD Cassava 0.150000 1.000 1.000 

0103082001 1CD Cassava-babyfood 0.150000 1.000 1.000 

0103139000 1CD Dasheen, corm 0.150000 1.000 1.000 

0103166000 1CD Ginger 0.150000 1.000 1.000 

0103166001 1CD Ginger-babyfood 0.150000 1.000 1.000 

0103167000 1CD Ginger, dried 0.150000 1.000 1.000 

0103296000 1C Potato, chips 0.150000 1.000 1.000 

0103297000 1C Potato, dry (granules/ flakes) 0.150000 6.500 1.000 

0103297001 1C Potato, dry (granules/ flakes)-b 0.150000 6.500 1.000 

0103298000 1C Potato, flour 0.150000 6.500 1.000 

0103298001 1C Potato, flour-babyfood 0.150000 6.500 1.000 

0103299000 1C Potato, tuber, w/peel 0.150000 1.000 1.000 

0103299001 1C Potato, tuber, w/peel-babyfood 0.150000 1.000 1.000 

0103300000 1C Potato, tuber, w/o peel 0.150000 1.000 1.000 

0103300001 1C Potato, tuber, w/o peel-babyfood 0.150000 1.000 1.000 

0103366000 1CD Sweet potato 0.150000 1.000 1.000 

0103366001 1CD Sweet potato-babyfood 0.150000 1.000 1.000 

0103371000 1CD Tanier, corm 0.150000 1.000 1.000 

0103387000 1CD Turmeric 0.150000 1.000 1.000 

0103406000 1CD Yam, true 0.150000 1.000 1.000 

0103407000 1CD Yam bean 0.150000 1.000 1.000 

0402322000 4B Rhubarb 0.150000 1.000 1.000 

0501061000 5A Broccoli 0.200000 1.000 1.000 

0501061001 5A Broccoli-babyfood 0.200000 1.000 1.000 

0501062000 5A Broccoli, Chinese 0.200000 1.000 1.000 

0501064000 5A Brussels sprouts 0.200000 1.000 1.000 

0501069000 5A Cabbage 0.200000 1.000 1.000 1E0631

 Full comment: 1E06311

0501071000 5A Cabbage, Chinese, napa 0.200000 1.000 1.000 1E0631

 Full comment: 1E06311

0501072000 5A Cabbage, Chinese, mustard 0.200000 1.000 1.000 1E0631

 Full comment: 1E06311

0501083000 5A Cauliflower 0.200000 1.000 1.000 

0501196000 5A Kohlrabi 0.200000 1.000 1.000 

0502063000 5B Broccoli raab 0.400000 1.000 1.000 

0502070000 5B Cabbage, Chinese, bok choy 0.400000 1.000 1.000 1E0631

 Full comment: 1E06311

0502117000 5B Collards 0.400000 1.000 1.000 

0502194000 5B Kale 0.400000 1.000 1.000 

0502229000 5B Mustard greens 0.400000 1.000 1.000 

0502318000 5B Rape greens 0.400000 1.000 1.000 

0502389000 5B Turnip, greens 0.600000 1.000 1.000 

0600347000 6 Soybean, seed 0.150000 1.000 1.000 

0600349000 6 Soybean, soy milk 0.150000 1.000 1.000 

0600349001 6 Soybean, soy milk-babyfood or in 0.150000 1.000 1.000 

0600350000 6 Soybean, oil 0.150000 1.000 1.000 

0600350001 6 Soybean, oil-babyfood 0.150000 1.000 1.000 

0601043000 6A Bean, snap, succulent 0.150000 1.000 1.000 

0601043001 6A Bean, snap, succulent-babyfood 0.150000 1.000 1.000 

0601257000 6A Pea, edible podded, succulent 0.150000 1.000 1.000 

0602031000 6B Bean, broad, succulent 0.150000 1.000 1.000 

0602033000 6B Bean, cowpea, succulent 0.150000 1.000 1.000 

0602037000 6B Bean, lima, succulent 0.150000 1.000 1.000 

0602255000 6B Pea, succulent 0.150000 1.000 1.000 

0602255001 6B Pea, succulent-babyfood 0.150000 1.000 1.000 
Sulfentrazone Dietary Exposure and Risk Assessment D417172

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Page 15 of 21

0602259000 6B Pea, pigeon, succulent 0.150000 1.000 1.000 

0603030000 6C Bean, black, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603032000 6C Bean, broad, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603034000 6C Bean, cowpea, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603035000 6C Bean, great northern, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603036000 6C Bean, kidney, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603038000 6C Bean, lima, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603039000 6C Bean, mung, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603040000 6C Bean, navy, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603041000 6C Bean, pink, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603042000 6C Bean, pinto, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603098000 6C Chickpea, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603098001 6C Chickpea, seed-babyfood 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603099000 6C Chickpea, flour 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603182000 6C Guar, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603182001 6C Guar, seed-babyfood 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603203000 6C Lentil, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603256000 6C Pea, dry 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603256001 6C Pea, dry-babyfood 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603258000 6C Pea, pigeon, seed 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

0603348000 6C Soybean, flour 0.150000 1.000 1.000 

0603348001 6C Soybean, flour-babyfood 0.150000 1.000 1.000 

0801374000 8A Tomatillo 0.150000 1.000 1.000 

0801375000 8A Tomato 0.150000 1.000 1.000 

0801375001 8A Tomato-babyfood 0.150000 1.000 1.000 

0801376000 8A Tomato, paste 0.150000 5.400 1.000 

0801376001 8A Tomato, paste-babyfood 0.150000 5.400 1.000 

0801377000 8A Tomato, puree 0.150000 3.300 1.000 

0801377001 8A Tomato, puree-babyfood 0.150000 3.300 1.000 

0801378000 8A Tomato, dried 0.150000 14.300 1.000 

0801378001 8A Tomato, dried-babyfood 0.150000 14.300 1.000 

0801379000 8A Tomato, juice 0.150000 1.500 1.000 

0801380000 8A Tomato, Tree 0.150000 1.000 1.000 

0802148000 8BC Eggplant 0.150000 1.000 1.000 

0802234000 8BC Okra 0.150000 1.000 1.000 

0802270000 8B Pepper, bell 0.150000 1.000 1.000 

0802270001 8B Pepper, bell-babyfood 0.150000 1.000 1.000 

0802271000 8B Pepper, bell, dried 0.150000 1.000 1.000 

0802271001 8B Pepper, bell, dried-babyfood 0.150000 1.000 1.000 

0802272000 8BC Pepper, nonbell 0.150000 1.000 1.000 

0802272001 8BC Pepper, nonbell-babyfood 0.150000 1.000 1.000 

0802273000 8BC Pepper, nonbell, dried 0.150000 1.000 1.000 

0901075000 9A Cantaloupe 0.150000 1.000 1.000 

0901187000 9A Honeydew melon 0.150000 1.000 1.000 

0901399000 9A Watermelon 0.150000 1.000 1.000 

0901400000 9A Watermelon, juice 0.150000 1.000 1.000 

1001106000 10A Citron 0.150000 1.000 1.000 

1001107000 10A Citrus hybrids 0.150000 1.000 1.000 

1001108000 10A Citrus, oil 0.150000 1.000 1.000 

1001240000 10A Orange 0.150000 1.000 1.000 

1001241000 10A Orange, juice 0.150000 1.800 1.000 

1001241001 10A Orange, juice-babyfood 0.150000 1.800 1.000 

1001242000 10A Orange, peel 0.150000 1.000 1.000 
Sulfentrazone Dietary Exposure and Risk Assessment D417172

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Page 16 of 21

1001369000 10A Tangerine 0.150000 1.000 1.000 

1001370000 10A Tangerine, juice 0.150000 2.300 1.000 

1002197000 10B Kumquat 0.150000 1.000 1.000 

1002199000 10B Lemon 0.150000 1.000 1.000 

1002200000 10B Lemon, juice 0.150000 2.000 1.000 

1002200001 10B Lemon, juice-babyfood 0.150000 2.000 1.000 

1002201000 10B Lemon, peel 0.150000 1.000 1.000 

1002206000 10B Lime 0.150000 1.000 1.000 

1002207000 10B Lime, juice 0.150000 2.000 1.000 

1002207001 10B Lime, juice-babyfood 0.150000 2.000 1.000 

1003180000 10C Grapefruit 0.150000 1.000 1.000 

1003181000 10C Grapefruit, juice 0.150000 2.100 1.000 

1003307000 10C Pummelo 0.150000 1.000 1.000 

1100007000 11 Apple, fruit with peel 0.150000 1.000 1.000 

1100008000 11 Apple, peeled fruit 0.150000 1.000 1.000 

1100008001 11 Apple, peeled fruit-babyfood 0.150000 1.000 1.000 

1100009000 11 Apple, dried 0.150000 8.000 1.000 

1100009001 11 Apple, dried-babyfood 0.150000 8.000 1.000 

1100010000 11 Apple, juice 0.150000 1.300 1.000 

1100010001 11 Apple, juice-babyfood 0.150000 1.300 1.000 

1100011000 11 Apple, sauce 0.150000 1.000 1.000 

1100011001 11 Apple, sauce-babyfood 0.150000 1.000 1.000 

1301055000 13A Blackberry 0.150000 1.000 1.000 

1301056000 13A Blackberry, juice 0.150000 1.000 1.000 

1301056001 13A Blackberry, juice-babyfood 0.150000 1.000 1.000 

1301058000 13A Boysenberry 0.150000 1.000 1.000 

1301208000 13A Loganberry 0.150000 1.000 1.000 

1301320000 13A Raspberry 0.150000 1.000 1.000 

1301320001 13A Raspberry-babyfood 0.150000 1.000 1.000 

1301321000 13A Raspberry, juice 0.150000 1.000 1.000 

1301321001 13A Raspberry, juice-babyfood 0.150000 1.000 1.000 

1302057000 13B Blueberry 0.150000 1.000 1.000 

1302057001 13B Blueberry-babyfood 0.150000 1.000 1.000 

1302136000 13B Currant 0.150000 1.000 1.000 

1302137000 13B Currant, dried 0.150000 1.000 1.000 

1302149000 13B Elderberry 0.150000 1.000 1.000 

1302174000 13B Gooseberry 0.150000 1.000 1.000 

1302191000 13B Huckleberry 0.150000 1.000 1.000 

1303227000 13C Mulberry 0.150000 1.000 1.000 

1304175000 13D Grape 0.150000 1.000 1.000 

1304176000 13D Grape, juice 0.150000 1.200 1.000 

1304176001 13D Grape, juice-babyfood 0.150000 1.200 1.000 

1304179000 13D Grape, wine and sherry 0.150000 1.000 1.000 

1304195000 13D Kiwifruit, fuzzy 0.150000 1.000 1.000 

1307130000 13G Cranberry 0.150000 1.000 1.000 

1307130001 13G Cranberry-babyfood 0.150000 1.000 1.000 

1307131000 13G Cranberry, dried 0.150000 1.000 1.000 

1307132000 13G Cranberry, juice 0.150000 1.100 1.000 

1307132001 13G Cranberry, juice-babyfood 0.150000 1.100 1.000 

1307359000 13G Strawberry 0.150000 1.000 1.000 

1307359001 13G Strawberry-babyfood 0.150000 1.000 1.000 

1307360000 13G Strawberry, juice 0.150000 1.000 1.000 

1307360001 13G Strawberry, juice-babyfood 0.150000 1.000 1.000 

1400003000 14 Almond 0.150000 1.000 1.000 

1400003001 14 Almond-babyfood 0.150000 1.000 1.000 

1400004000 14 Almond, oil 0.150000 1.000 1.000 

1400004001 14 Almond, oil-babyfood 0.150000 1.000 1.000 

1400059000 14 Brazil nut 0.150000 1.000 1.000 

1400068000 14 Butternut 0.150000 1.000 1.000 

1400081000 14 Cashew 0.150000 1.000 1.000 

1400092000 14 Chestnut 0.150000 1.000 1.000 

1400155000 14 Hazelnut 0.150000 1.000 1.000 

1400156000 14 Hazelnut, oil 0.150000 1.000 1.000 

1400185000 14 Hickory nut 0.150000 1.000 1.000 

1400213000 14 Macadamia nut 0.150000 1.000 1.000 

1400269000 14 Pecan 0.150000 1.000 1.000 

1400282000 14 Pistachio 0.150000 1.000 1.000 

1400391000 14 Walnut 0.150000 1.000 1.000 

1500025000 15 Barley, pearled barley 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500025001 15 Barley, pearled barley-babyfood 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.
Sulfentrazone Dietary Exposure and Risk Assessment D417172

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Page 17 of 21

1500026000 15 Barley, flour 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500026001 15 Barley, flour-babyfood 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500027000 15 Barley, bran 0.150000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500065000 15 Buckwheat 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500066000 15 Buckwheat, flour 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500120000 15 Corn, field, flour 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500120001 15 Corn, field, flour-babyfood 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500121000 15 Corn, field, meal 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500121001 15 Corn, field, meal-babyfood 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500122000 15 Corn, field, bran 0.150000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500123000 15 Corn, field, starch 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500123001 15 Corn, field, starch-babyfood 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500124000 15 Corn, field, syrup 0.150000 1.500 1.000 2F0639

 Full comment: 2F06391

1500124001 15 Corn, field, syrup-babyfood 0.150000 1.500 1.000 2F0639

 Full comment: 2F06391

1500125000 15 Corn, field, oil 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500125001 15 Corn, field, oil-babyfood 0.150000 1.000 1.000 2F0639

 Full comment: 2F06391

1500126000 15 Corn, pop 0.100000 1.000 1.000 2F0639

 Full comment: 2F06391

1500226000 15 Millet, grain 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500231000 15 Oat, bran 0.150000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500232000 15 Oat, flour 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500232001 15 Oat, flour-babyfood 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500233000 15 Oat, groats/rolled oats 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500233001 15 Oat, groats/rolled oats-babyfood 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500323000 15 Rice, white 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500323001 15 Rice, white-babyfood 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500324000 15 Rice, brown 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500324001 15 Rice, brown-babyfood 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500325000 15 Rice, flour 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500325001 15 Rice, flour-babyfood 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500326000 15 Rice, bran 0.150000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500326001 15 Rice, bran-babyfood 0.150000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500328000 15 Rye, grain 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500329000 15 Rye, flour 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500344000 15 Sorghum, grain 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500345000 15 Sorghum, syrup 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500381000 15 Triticale, flour 0.150000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.
Sulfentrazone Dietary Exposure and Risk Assessment D417172

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Page 18 of 21

1500381001 15 Triticale, flour-babyfood 0.150000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1500401000 15 Wheat, grain 0.150000 1.000 1.000 

1500401001 15 Wheat, grain-babyfood 0.150000 1.000 1.000 

1500402000 15 Wheat, flour 0.150000 1.000 1.000 

1500402001 15 Wheat, flour-babyfood 0.150000 1.000 1.000 

1500403000 15 Wheat, germ 0.150000 1.000 1.000 

1500404000 15 Wheat, bran 0.150000 1.000 1.000 

1500405000 15 Wild rice 0.100000 1.000 1.000 Inadve

 Full comment: Inadvertent tol.

1800002000 18 Alfalfa, seed 0.150000 1.000 1.000 

2001163000 20A Flax seed, oil 0.150000 1.000 1.000 

2002330000 20B Safflower, oil 0.200000 1.000 1.000 

2002330001 20B Safflower, oil-babyfood 0.200000 1.000 1.000 

2002364000 20B Sunflower, seed 0.200000 1.000 1.000 

2002365000 20B Sunflower, oil 0.200000 1.000 1.000 

2002365001 20B Sunflower, oil-babyfood 0.200000 1.000 1.000 

8601000000 86A Water, direct, all sources 0.098000 1.000 1.000 

8602000000 86B Water, indirect, all sources 0.098000 1.000 1.000 

9500019000 O Asparagus 0.150000 1.000 1.000 2E0650

 Full comment: 2E06500

9500177000 O Grape, leaves 0.150000 1.000 1.000 

9500178000 O Grape, raisin 0.150000 4.300 1.000 

9500263000 O Peanut 0.200000 1.000 1.000 0F0611

 Full comment: 0F06116

9500264000 O Peanut, butter 0.200000 1.890 1.000 0F0611

 Full comment: 0F06116

9500265000 O Peanut, oil 0.200000 1.000 1.000 0F0611

 Full comment: 0F06116

9500275000 O Peppermint 0.300000 1.000 1.000 1E0631

 Full comment: 1E06311

9500276000 O Peppermint, oil 0.300000 1.000 1.000 1E0631

 Full comment: 1E06311

9500352000 O Spearmint 0.300000 1.000 1.000 1E0631

 Full comment: 1E06311

9500353000 O Spearmint, oil 0.300000 1.000 1.000 1E0631

 Full comment: 1E06311

9500362000 O Sugarcane, sugar 0.150000 1.000 1.000 

9500362001 O Sugarcane, sugar-babyfood 0.150000 1.000 1.000 

9500363000 O Sugarcane, molasses 0.200000 1.000 1.000 

9500363001 O Sugarcane, molasses-babyfood 0.200000 1.000 1.000 
Sulfentrazone Dietary Exposure and Risk Assessment D417172

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Page 19 of 21

Attachment 4: DEEM-FCID Chronic Exposure Estimates.

US EPA Ver. 3.16, 03-08-d

DEEM-FCID Chronic analysis for SULFENTRAZONE NHANES 2003-2008 2-day

Residue file name: C:\Users\gkramer\Documents\Gk\##Sulfentrazone\129081-CHRON__30 APR 2014.R08

 Adjustment factor #2 used.

Analysis Date 04-30-2014/16:10:09 Residue file dated: 04-30-2014/16:08:32

Reference dose (RfD, Chronic) = .14 mg/kg bw/day

===============================================================================

 Total exposure by population subgroup

-------------------------------------------------------------------------------

 Total Exposure

 -----------------------------------

 Population mg/kg Percent of 

 Subgroup body wt/day Rfd 

-------------------------------------- ------------- ----------------

Total US Population 0.003973 2.8%

Hispanic 0.004244 3.0%

Non-Hisp-White 0.003929 2.8%

Non-Hisp-Black 0.003729 2.7%

Non-Hisp-Other 0.004432 3.2%

Nursing Infants 0.003630 2.6%

Non-Nursing Infants 0.010786 7.7%

Female 13+ PREG 0.003740 2.7%

Children 1-6 0.008381 6.0%

Children 7-12 0.004506 3.2%

Male 13-19 0.003277 2.3%

Female 13-19/NP 0.003174 2.3%

Male 20+ 0.003354 2.4%

Female 20+/NP 0.003470 2.5%

Seniors 55+ 0.003259 2.3%

All Infants 0.008577 6.1%

Female 13-50 0.003453 2.5%

Children 1-2 0.009881 7.1%

Children 3-5 0.007889 5.6%

Children 6-12 0.004817 3.4%

Youth 13-19 0.003225 2.3%

Adults 20-49 0.003498 2.5%

Adults 50-99 0.003314 2.4%

Female 13-49 0.003450 2.5%

-------------------------------------------------------------------------------
Sulfentrazone Dietary Exposure and Risk Assessment D417172

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Page 20 of 21

Attachment 5: DEEM-FCID Acute Exposure Estimates for the General Population Including Infants and 

Children (food only).

US EPA Ver. 3.18, 03-08-d

DEEM-FCID ACUTE Analysis for SULFENTRAZONE NHANES 2003-2008 2-Day

Residue file: 129081-FoodOnly__30 APR 2014.R08 Adjustment factor #2 NOT used.

Analysis Date: 04-30-2014/16:15:03 Residue file dated: 04-30-2014/16:07:51

NOEL (Acute) = 250.000000 mg/kg body-wt/day

RAC/FF intake summed over 24 hours

Run Comment: ""

===============================================================================

Summary calculations--per capita:

--- 95th Percentile---- --- 99th Percentile---- ---99.9th Percentile----

Exposure % aRfD MOE Exposure % aRfD MOE Exposure % aRfD MOE 

---------- ------- -------- ---------- ------- -------- ---------- ------- --------

Total US Population:

 0.005432 0.22 46025 0.010672 0.43 23425 0.018971 0.76 13177 

All Infants:

 0.009800 0.39 25509 0.014950 0.60 16721 0.032712 1.31 7642 

Female 13-50:

 0.003408 0.14 73365 0.004875 0.19 51283 0.008004 0.32 31232 

Children 1-2:

 0.015691 0.63 15932 0.024021 0.96 10407 0.042166 1.69 5928 

Children 3-5:

 0.012220 0.49 20459 0.017456 0.70 14321 0.022857 0.91 10937 

Children 6-12:

 0.006935 0.28 36048 0.010260 0.41 24365 0.017836 0.71 14016 

Youth 13-19:

 0.004205 0.17 59450 0.006122 0.24 40839 0.009279 0.37 26942 

Adults 20-49:

 0.003339 0.13 74882 0.004778 0.19 52321 0.008052 0.32 31049 

Adults 50-99:

 0.002979 0.12 83908 0.004325 0.17 57800 0.007417 0.30 33706 

Female 13-49:

 0.003404 0.14 73439 0.004798 0.19 52107 0.007683 0.31 32538 
Sulfentrazone Dietary Exposure and Risk Assessment D417172

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Page 21 of 21

Attachment 6: DEEM-FCID Chronic Exposure Estimates (food only).

US EPA Ver. 3.16, 03-08-d

DEEM-FCID Chronic analysis for SULFENTRAZONE NHANES 2003-2008 2-day

Residue file name: C:\Users\gkramer\Documents\Gk\##Sulfentrazone\129081-FoodOnly__30 APR 2014.R08

 Adjustment factor #2 used.

Analysis Date 04-30-2014/16:11:30 Residue file dated: 04-30-2014/16:07:51

Reference dose (RfD, Chronic) = .14 mg/kg bw/day

===============================================================================

 Total exposure by population subgroup

-------------------------------------------------------------------------------

 Total Exposure

 -----------------------------------

 Population mg/kg Percent of 

 Subgroup body wt/day Rfd 

-------------------------------------- ------------- ----------------

Total US Population 0.001921 1.4%

Hispanic 0.002285 1.6%

Non-Hisp-White 0.001819 1.3%

Non-Hisp-Black 0.002036 1.5%

Non-Hisp-Other 0.002067 1.5%

Nursing Infants 0.001773 1.3%

Non-Nursing Infants 0.003961 2.8%

Female 13+ PREG 0.001808 1.3%

Children 1-6 0.005753 4.1%

Children 7-12 0.002795 2.0%

Male 13-19 0.001867 1.3%

Female 13-19/NP 0.001594 1.1%

Male 20+ 0.001443 1.0%

Female 20+/NP 0.001314 0.9%

Seniors 55+ 0.001275 0.9%

All Infants 0.003286 2.3%

Female 13-50 0.001410 1.0%

Children 1-2 0.006921 4.9%

Children 3-5 0.005395 3.9%

Children 6-12 0.003018 2.2%

Youth 13-19 0.001729 1.2%

Adults 20-49 0.001451 1.0%

Adults 50-99 0.001290 0.9%

Female 13-49 0.001410 1.0%

-------------------------------------------------------------------------------