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# OAR Box 1878 Prepped by Charmelle Mathews



### Document

Number: 

# 129 ) ll-E-1 3 Docket Number: 

# A-90-1 9

Printed 11/28/20081:21:26

PM Sheet 129of 145P. 2 

## A-90-1 9 ll-E-1 3

* 1 =00' l * UNITE D STATE S ENVIRONMENTA L PROTECTI O Offic e o f Ai rQualit yPlannin g an d Standard s Researc h Triangl e Park , Nort h Carolin a 2771 1

0 1 MA R 199 0 

## J E 0 WE DEC I 8 199

2 EPAAIRDOCKE 1 MEMORANDU M SUBJEC T
FROM :
TO ; Meetin g wit hChemica l Manufacturer s Associatio n(CMA ) t o

Discus s Hazardou s Organi c NESHA P Rober t E . Rosensteel , Chie f Chemica l Manufacturin g Sectio n(MD-13 ) Susa nR . Wyatt , Chie f Chemical s an

dPetroleu

m Branc h(MD-13 ) 1 . A meetin g wa s conducte donJanuar y 30 , 1990 , i

nth e tent hfloo r conferenc e roo m betwee nrepresentative s o f CM A an dEPA t o discus s variou s ai r toxic s activities . Attendee s a t th e meetin g were : 

### Of t Davi dGustafso n- DO

W Roge r Ma i on e - Unio nCarbid e BobTrautne r - Shel l Bria nTarant o - Exxo n Dorothy Bower s - Merc k Erni e Rosenber g - Occidenta l Kare nFidle r - CM

A Richar dSigma nr CM

A
RADIA N COR P Rees e Howi e Shery l Hatkln s

2 . Topic s Discusse di nMeeting : Davi dMarkword t - CP B

Gil l Woo d- EM

B Darry l VonLehmde n- AREAL A l Weh e - SD B Laur a Butle r - SD B JosephKnol l - AREA L Roge r Shigehar a - EMB Kelvi nMarti n- CP B Randy McDonal d- CP B K. C Hustved t - CP B Rodne y Midget t - AREA L To m Walto n- SD B Bo bRosenstee l - CP B Debbi e Stackhous e - SD B Bo bKellam

- PAB

Afte r brie f introduction s o f thos e i nattendance , anagend a wa s distribute da s a guid e fo r discussio ndurin g th e meetin g (Attachmen t I) .P. 3

: " v

3 ; Ai r Toxic s Implementation : Bo b Kella mo f th e Pollutan t Assessmen t Branc hprovide d an overvie wo f th e authorit ycontaine d in propose d legislatio n befor e Congres s (H.R.3030/S.1490 ) and discusse d implementatio n activitie s fo r whic hES Q o f OAQP S ha s th e lea d (Attachmen t 2) . 4 . Hazardou s Organi c NESHA P Overview : Th e nex t topi c o f discussio n wa s th e genera l technica l approac ht o th e rul e makin g an

d discussio n o f th e individua l regulation s lea d byth e EP Aan d Radia n representative s identifie d in th e agend a (Attachmen t 3) . Ther e wa s genera l discussio n concernin g detail s o f th e technica l analysis , and EP Arepresentative s identifie d som e potentia l area s fo r industr yinput , e.g . characteristic s o f productio n o r use r processe s o f on e o r mor e o f th e organic s o n th e lis t o f 191 , baselin e level s o f control , distributio n o f tank s bysize , and informatio n o n distributio n o f transfe r operations
. ACMArepresentativ e aske d fo r EP At o provid e a lis t o f processe s wher e technica l input s wer e no t availabl e in th e literature , and th e industr ywoul d tr yt o provid e dat a t o fil l thos e gaps . 5 . Th e propose d progra mfo r developin g emissio n measuremen t method s fo r organi c pollutant s o n th e lis t o f 19 1 wa s discusse d bya representativ e fro m AREA L (Attachmen t 4) . Ther e wa s a reques t fro mth e AREA L representative s fo r furthe r interactio n wit hindustr yin identifyin g and providin g site s fo r method s developmen t testin g and possibl e join t cooperatio n i n developin g methods . 6 . Th e draf t questionnaire s fo r transfe r emission s and wastewate r wer e distribute d t o th e attendee s (Attachment s 5 and 6) , and th e industr y representative s agree d t o provid e comment s byFebruar y16 , 1990 . 7 . Th e CMAresponde d wit hspecifi c proposal s fo r follow-u p activitie s i n a lette r t o m e date d Februar y1 , 199 0 (Attachmen t 7) .

cc : Glen n Rives , Radia n Debbi e Stackhouse , (MD-13 )P. 4

Attachmen t I

Agend a CM A an dEPA Meetin g t o Discus s Hazardou s Organi c NESHA P (HON )

Januar y 30 , 199 0

I . Introductio n- BobRosenstee l II . Titl e II I Implementatio n- BobKellam III . HON Technica l Approac h A . Overvie w

- Debbi e Stackhous e B . Proces s Vent s - Bo bRosenstee l C . Equipmen t Leak s - Dav e Markword t D . Transfe r Operation s - Dav e Markword t E . Storag e - Randy

McDonal d F . Wastewate r - K.C . Hustved t G . Industr y

Profil e - Rees e Houl e IV . Sampling/Analytica l Method s Program - Jo e Knol l V . Discussio no f Draf t Questionnaire s A . Transfe r Operation s - Dav e Markword t B . Wastewate r - K.C . Hustved t

# AI R TOXIC S IMPLEMENTATIO N PLANNIN G

p i o zr B a 

# Informatio n Briefin g fo r CM A

January 30, 1990

u

# PURPOS E

Describe

Activities

Necessary

to Implement

Title III Identify Major Implementation

Issues Discuss Coordination

Plans

b >

# H.R . 3030/S . 149 0 Titl e II I - Ai r Toxic s 

# i

Alternative

Compliance 

# i 

# I

Exemptio n fro m MAC Tupo n domondrntio n o

fvokmtsf y 90 % omissio n foductio n 

# I 1
Exemptio n from MAC T upo n damonttratio n o

f •—•-•*- •* * 

# J Lis t ol19 1 Hazardou s 

# I 1 Petition s to"" !

PuUW i Majo r Source Categor

y UaHnF W naWMr t 12{imOn-tfi

EP A rankin g o f

Raoutotory Aoand a 

# I

Maximu m Achievabl e Contro l ToohnotoQ

y (MACT ) 

# I I P r omiaaato standard * to protec t adequatel y agains t "unreasonabl e mm * oonaldarin g coat , technical leatNfty . an d haattt-basa d

Stale s Issu e Oparalin g Parmt a EPARifhw

^ i

# QinnipD<®inni(©o1tSQ."ttoo o ^otowo'tt O

Specified

Actions Procedural

Requirements Coordination

with Other Titles

c o

# Specified

Actions:

Publis h Source Categor y Lis t Mee t Regulator

y Timetables Issu e Negligibl e Ris k

Guidance Issu e Voluntar

y Reductio n Guidance Conduc t Utilit y Stea m Generato r Hazar d Study Promulgat

e Acciden t Preventio n Regulation s an d Pollutan t Lis t Conduc t Great Lakes Study *

* added in Lent-Dingell

substitute

C O

# Procedural

Requirements:
Procedure s fo r addition/deletio n o fpollutant s (includin g petitions ) Syste m fo r rankin g sourc e categorie s Criteri a fo r establishin g lesse r quantit y fo r majo r source cut-off s Rational e fo r designatio n o fare a sourc e categorie s Procedure s fo r withdrawa l o fsource categorie s Healt h benchmark

s fo r liste d pollutants Criteri a an d scop e o

funreasonabl e residua l ris k determinatio n Researc h o n prevention , measurement , an d contro l o femission s an d evaluatio n o

fhealt h an d ecologica l ris k Mechanis m fo r assistanc e t o smal l source s (Clearinghouse )

* added in Lent-Dingell

substitute

O

# Coordination

with Other Titles: Titl e I-Ozone , PM1 0
• Co-Contro l • Rankin g byToxi cFractio n • Lea d Titl e I I - Mobil e Source s • Stud yo

f Ai rToxic s fro m Mobil e Source s Titl e I V - Permit s • Negligibl e Risk , Voluntar yReductio n Guidanc e • Trainin g of Permittin g Authoritie s • Permi t Dat a Bas e Titl e VI I - Miscellaneou s • Ai rPollutan t Releas e Investigatio n Boar d

### SCRS MACT Negligible Risk Guidance Voluntary Reduction Guidance Petitions

to Add/Delete Utility Study Great Lakes Study Accidental Release Regulations lf/0 9 EhadmM f 

# Implementatio n Timelin e Enactment* ! Ei-d0imli2 Ehadmen M &iatf/ne/i M Enactment s



### Title il Study Title IV Permits Pro p )s e Gui d we e Peti t Filo d

Pro p ps e Miniinu m Eler r Pu b is h



## "1 5 

## ~ Prop o Cate g Mie s (ind. ben hmarks) Pro p as e > e 1 0 Promu l jat e 1 0 p r0 p 0S e



### Gui d mc e Prom t Igat e Guid a ic e 

### ons

ent s Cate g Drie s (ind. bei tchmarks) Pror r ulgat e Gui d mc e

Gran t o r Den y



### an d Complet e Toxics Stud y Pro r mlgat e Min i nu m Element s 

### 25 Vo (ind. be -dvnaiks)

(ind. ben

-nmarks)

Repc r t t o Con j res s

Pro ; os e Pror r ulgat e Reguf i ition s Regu l ttion s 

### Us t and Pro m jlgat e 25>/ «

Ext e na J Re>r i

List Report : o



### e w Congr e ss

# Immediate

Priorities:
Complet e Source Categor

y Rankin g Decid e o n Are a Sources , Lesse r Quantit y Criteri a Identif y an d Procee d wit h Regulatio n Developmen t fo r Initia l Categorie s Develo p Negligibl e Ris k Guidance an d Healt h Benchmark s fo r Firs t Standard s Develo p Voluntar

y Reductio n Guidance Establis h Petitio n Response Procedures Develo p Trackin g Syste m fo r Activities

T I C O

# Near

Term:

Select Additiona l Categorie s fo r Regulatio n Developmen t Develo p Healt h Benchmark s fo r Remainin g Pollutant s

T I

# At Enactment:
Initiat e Utilit y Study Begi n Developmen t o

fAccidenta l Releas e Regulation s an d Lis t Begi n Plannin g Great Lakes Stud y Initiat e Developmen t o

fResearc h Objectives Establis h Assistance Mechanis m fo r Smal l Sources

T IDRAF T AGEND A February 7 , 199 0
8:0 0 - 8:4 5 Welcom e andOverview o f Titl e II I - Plenar y

Sessio n
8:45-9:1 5 SESSIO N

I : Sourc e Category

Identificatio nandRankin g 8:45-9:1 5
9:15-10:3 0 Spli t int o DiscussionGroup s 10:30-10:4 5 Coffe e Brea k 10:45-11:3 0 Report s fro m DiscussionGroup s 9:15-10:3 0 10:30-10:4 5 10:45-11:3 0 SESSION

II : PetitionProces s an dCriteri a fo r Additions/Deletion s Spli t int o Discussio nGroup s Coffe e Brea k Report s fro a DiscussionGroup s
11:30-1:0 0 LUNC H
1:00-1:3 0 SESSIO N

III : Developmen t o f MACT standard s an d Initia l Sourc e Categor y

Selectio n 1:30-3:4 5 Discussio nandSugar y 1:00-1:3 0 SESSIO N IV : Negligibl e Ris kGuidanc e
1:30-3:0 0 Spli t int o DiscussionGroup s 3:00-3:4 5 Report s fro a Discussio nGroup s
4:00-5:0 0 SlBMAR i - Plenary SessionDRAF T AGEND A

Februar y8 , 199 0 8:00-8:1 5 Brie f Statu s Repor t - Plenar ySessio n 8:15-8:3 0 SESSIO NV : Unreaeoaabl e Ris k Determinatio n
8:30-9:3 0 Spli t int o DiSCUSSiO DGroup s 9:30-9:4 5 Coffe e Brea k 9:45-10:0 0 Report s fro a Discussio n Group s 10:00-10:1 5 SESSIO NV (Cont) : Researc hNeed s 10:15-11:1 5 Spli t int o Discussio n Group s 11:15-11:3 0 Report s fro a Discussio n Group s 8:15-8:4 5 SESSIO NVI : 90 * Voluntar yReductio n Guideline s 8:45-10:1 5 Spli t int o Discussio n Group s 10:15-10:3 0 Coffe e Brea k 10:30-11:3 0 Report s fro n Discussio n Group s

11:30-1:0 0 LUNC H
1:00-1:1 5 SESSIO NVII : Coordinatio n wit hOthe r Titles , Office s 1:00-1:4 0 SESSIO NVII I A : Accidenta l Releas e Regulation s Discussio n an d Suaur y 1:15-2:1 5 Discussio n & Sumar y 1:40-2:1 5 B : Grea t Lake s Stud y Discussio n an d Suaur y
2:15-3:1 5 Spli t int o Constituen t Group s (Regiona l Offices , STAPPA/ALAPCO ,

Progra mOffices , ORD , Enforcement ) t o Identif yIssue s Specifi c t o th e Group s 3:15-4:0 0 Report s fro a Constituen t Group s 4:00-5:0 0 SUMMAR Y

T JP.1 8

Attachmen t .3

Hazardou s Organi c NESHAP Projec t Overvie w Coverage :

- Productio n o f organi c hazardou s ai r pollutant s (HAP's) .

- Us e o f organi c HAP' s i n SOCM I industry
. Sourc e Category : Coul d b e define d a s chemica l productio n uni t (e.g . butadien e productio n i s a sourc e category) . Emissio n Sources :

- Continuou s proces s vent s • Ai r oxidatio n vent s • Distillatio n vent s • Reacto r vent s

- Storag e tank s

- Pumps , valves , flange s (i.e. , equipment )

- Transfe r equipmen t (i.e. , loadin g racks )

- Wastewate r handling equipmen t Othe r Coverage : Coul d potentiall yinclud e storag e an d equipmen t leak s associate d wit h pesticides , pharmaceuticals , styrene-butadien e rubbe r production , an d others . Standards : Pla n t o develo p generi c standard s fo r eac h emissio n sourc e t o broadl ycove r al l o r mos t sourc e categories
. 

### Sasi s Fo r Standards :

Woul d rel yo n existing dat a base s an d control s fro

m previou s NSP S sources .

• Proces s vent s - 98 % contro l b yincineratio n o r flaring
. Coul d potentiall yhav e a cutof f base d o n emissions , cost-effectiveness , o r othe r ven t strea m characteristic
.

• Storag e tank s - 95 % contro l wit h fixe d roo f contro l vente d t o vapo r recover yo r destructio n device s o r us e o f equivalen t controls . Coul d hav e cutoff s base d o n tank size , chemica l vapo r pressure , o r othe r criteria
.

• Equipmen t leak s - Curren t approac h i s abou t 6 0 t o 70 % control . EPAi s negotiating a ne wapproac h tha t mayachiev e 95 % control .

- Sectio n 11 4 informatio n collectio n effor t i s neede d o n transfe r an

d wastewater . Existing informatio n suc h a s benzen e NESHAP , industria l wastewate r CT G woul d als o b e used .P.1 9

Projec t Schedules : Schedule s ar e groupe d consisten t wit h th e time neede d t o complet e dat a gathering an d analysis
. Emissio n Source s 1 . Ai r Oxidatio n vent s 2 . Distillatio n vent s 3 . Reacto r vent s 4 . Storag e 5 . Equipmen t leak s 6 . Transfe r 7 . Wastewate r Proposa l 6/9 1
8/9 1 10/9 1 Promulgatio n 6/9 2
8/9 2 10/9 2P.2 0

j

. '

EQUIPMEN T LEAK S
TECHNICA L BASI S FORTH E STANDARD :

. Regulator yNegotiatio n Committe e
APPROACH : Develo p mode l plant s base d o n in-hous e dat a

Profil e wil l b e provide d vi a anothe r tas k Develo p emissio n impact s allocat e mode l plant s hazard s associate d wit hchemica l Updat e cost s fro mNSP S and Us e Reg/Ne gP.2 1

PROCES S VENT S SCOPE :

. Separat e regulation s wil l b e develope d fo r reacto r processes ,

distillatio n processes , and ai r oxidatio n processes . Onl ycontinuou s produc t processe s wil l b e include d i n thi s effor t TECHNOLOG YBASI S O F STANDARDS :

. Combustio n contro l device s (therma l incinerators , flares ) APPROACH : Us e existin g dat a base s fo r ven t strea mcharacteristic s - ai r

oxidation , distillation ; reacto r processe s an d 11 4 dat a collecte d fo r sourc e assessments . Identif yproduct/processe s fo r eac hSOCM I chemica l o n th e HA P lis t a s ai r oxidation , o r reactor s o r distillation
. Develo p mode l plant s fo r eac hproces s typ e includin g numbe r o f vents , and ven t strea mcharacteristics
. Identif yHA P t o tota l VO C rati o fo r mode l streams . Calculat e baselin e emissions , potentia l emissio n reductions , contro l costs , and cos t effectivenes s fo r mode l ven t streams . Extrapolat e mode l ven t strea m emission s an d cost s fo r developmen t o f nationa l impacts
. AREA S WHER E CM

A CA N CONTRIBUTE : Existin g leve l o f contro l Characteristic s o f production/use r processe sP.2 2

STORAG E TANK S SCOPE : Tan k service s covered :

• Ra wmateria l storag e Intermediat e produc t storag e Produc t storag e • Tan k typ e covered :

• Fixed-roo f tank s • Floating-roo f tank s Open-top tank s TECHNICAL BASI S FO

RTH E STANDARD : Subpar t K b and demonstrate d technolog ymor e effectiv e tha n control s require d j ySubpar t Kb . APPROACH : Develo p industr yprofil e wit hrespec t t o storag e tan k types , tan k

size s and controls , fro m readil yavailabl e information
. Th e bul k o f thi s informatio n wil l com e fro m Sourc e Assessment/Sourc e Categor yInvestigations
. Extrapolat e th e impact s o f control s o n th e mode l processe s t o develo p nationa l impacts
. AREA S WHER E CM

A CA N CONTRIBUTE : Distributio n o f tan k type s and size s i n servic e Existin g leve l o f contro lP.2 3

TRANSFE R OPERATION S (Tan k Trucks , Railcars , Marin e Vessels )
TECHNICAL BASI S OF STANDARD :

Combustio n devic e capabl e o f 98 % reductio n o f VO C APPROACH : CA

Aamendment/Marin e Vesse l Contro l Arm yCorp s o f Engineer s dat a bas e fo r industr yprofil e Nationa l Researc hCounci l Stud yfo r cost s

. Tan k Trucks/Rai l car s

Sectio n 11 4 Reques t fo r Dat a Develo p model s fo r loadin g operation s Benzen e transfe r regulatio n provide s cos t basi s Industr yprofil e provide d vi a separat e tas k Develo p nationa l impact s AREA S WHER E CM

A CA N CONTRIBUTE :

• Revie wdraf t 11 4 Questionnair e

. Provid e industr yprofil e dat a

. Existin g contro l requirement s (b yState )P.2 4

WASTEWATE R
TECHNICAL BASI S O F STANDAR D Collec t certai n wastewate r stream s a t th e poin t o f generatio n and transfe r throug hclose d pipin g and controlle d storag e tank s t o a treatmen t devic e (likel ystea mstripper)
. Alternative s o f controllin g th e wastewate r syste mwoul d likel yb e allowed . GENERAL APPROAC H Existin g information - gathere d throug hSectio n 11 4 questionnaire s t o suppor t th e developmen t o f th e CT G fo r industria l wastewater s and throug hSectio n 30 8 questionnaire s t o suppor t Effluen t Guideline s develope d wil l b e used . Additiona l informatio n gatherin g t o fil l dat a gap s wil l b e conducte d throug hSectio n 11 4 questionnaires
. Mode l plan t analysi s wil l b e use d t o estimat e impact s suc ha s baselin e emissions , potentia l emissio n reductions , contro l costs , and cos t effectivenes s o f control . Th e mode l plan t impact s wil l b e extrapolate d t o develo p nationa l impacts
. AREA S WHER E CM

A CA N CONTRIBUTE : Numbe r and volum e o f continuou s and batc hstream s pe r produc t process . Organi c loadin g i n stream s (i.e
. percen t o f saturation )P.2 5

INDUSTRIAL PROFIL E TAS K PURPOSE : Characteriz e the SOCM I Industry a s i t relate s t o th e organi c HAP s liste dinth e CA

A (eithe r produce do r used ) an dth e source s t o be regulated . Thi s includes : Identif y th e SOCM I produc t processe s wher e a HA P i s produce do r use da s a reactan t (numbe r o f facilitie s an dquantitie s processed) . Identif y th e type s o f emissio nsource s likel y t o be presen t i

n eac hproduc t proces s (i.e. , reacto r vents , distillatio nvents , fixe droo f storage , etc.) . Develo pchemica l trees , s o tha t th e cos t impact s onvariou s chemica l product s ca nb e evaluated . Develo pth e conceptua l framewor kfo r evaluatin g th e cost s an d environmenta l impact s o f candidat e regulator y option s
APPROACH : Workin g fro

m th e lis t o f -35 0 SOCM I chemical s in4 0 CF R6 0 VV , identif y th e majo r productio nroute s fo r eac hchemical , th e raw material s an

d th e products . Identif y th e organi c chemical s reacte do r produce di n eac hproces s tha t ar e HAP s (base do nCA A bill) . Develo pinformatio nonth e numbe r o f plant s tha t us e eac hprocess , th e quantit y o f eac hHA P use dan

dth e quantit y

o f eac hHA P produced . I n mos t cases , proces s stochiometr y wil l b e use dt o estimat e us e a s a facto r o f production . Also , develo pinformatio nonth e geographica l distributio no f plants . Develo pchemica l us e tree s fo r al l o f th e HAP s produce do r use di n SOCMI . Revie w Stat e regulation s t o determin e th e require dbaselin e leve l o f contro l fo r variou s geographica l regions , fo r eac hemissio nsourc e type . Assig na representativ e se t o f mode l source s (i.e. , proces s vents , storag e tanks , equipmen t components ) t o eac hproduc t process . Base donmode l sourc e assignments , Stat e regulations , numbe r o f plants , an dgeographica l distribution ; estimat e baselin e emissions . Fo r eac hregulator y

option , comput e nationa l impact s (emissio n reductio nan

dcosts ) fo r eac hproduc t proces s base do nmode l assignments , an

dthe nsu

m fo r al l produc t processes .P.2 6

AREA S WHER E CM

A CA N CONTRIBUTE : Fillin g informatio ngaps : description s o f SOCM I processe s fo r whic h ther e i s no informatio ni npubli c sources , includin g th e numbe r o f facilitie s an

dcapacities . Assignmen t o f representativ e model s t o produc t processe s fo r whic h ther e i s n o emission s dat a available . Identificatio no f produc t processe s whic hd o no t hav e certai nemissio n sourc e types . Fo r example , ther e ma y no t be raw

materia l storag e tank s o r loadin g operation s du e t o captiv e use . Assis t indefinin g baselin e contro l levels . Sinc e muc ho f th e curren t emission s dat a i s fo r VOC , th e HA P portio no f tota l VO C wil l nee dt o b e estimated . CM A coul dprovid e assistanc e i s estimatin g th e HAP:V0 C ratio s fo r specifi c produc t processes . I nth e cas e o f wastewater , assistanc e inestimatin g th e rati o o f HAP s t o priorit y pollutant s coul dreduc e Informatio ngatherin g requirement s significantly .

# NEE D FO R MEASUREMEN TMETHOD S

CONDUC TINDUSTRIA L SURVEY S DETERMIN E CONTRO L DEVIC E EFFICIENC Y US E I N TH E STANDAR D SETTIN G PROCES S VALIDAT E "NEGLIGIBL E RISK " CLAIM S DETERMIN E I F MAC TDEVICE S AR E WORKIN G DEVELO P PERFORMANC E STANDARD S FO R CEM S VALIDAT E "RECOR D KEEPING " STANDARD S o -T a a

# SCREENIN G METHOD S MEASURE S A COMMO N PROPERT Y DOE S NO TGIV E COMPOUN D SPECIFI C INFORMATIO N USEFU L T O DEMONSTRAT E OPERATIO N O F MAC T USEFU L WHE N ONL YA SINGL E POLLUTAN TI S EMITTE D USEFU L WHE N AL L EMISSION S AR E REGULATE D USEFU L WHE N EMISSION S AR E FA R BELO W STANDAR D

o o

# EXAMPLE S O F SCREENIN G METHOD S TOTA L HYDROCARBO N ANALYZE R (THC ) A N INSTRUMENTA L METHO D US E A FLAM E IONIZATIO N DETECTO R RESPONS E VARIE S WIT H COMPOUND S USEFU L FO R ON-LIN E MEASUREMENT S
TOTA L ORGANI C CHLORIN E METHO D (TOCL ) A MANUA L METHO D ORGANI C CMP D COMBUSTED , CHLORID E MEASURE D FO R SCREENIN G CHLORINATE D SOLVENT S

# GENERI C METHOD S FUNCTIONA L GROU P ANALYSI S COMMO N SAMPLIN G AN D ANALYTICA L METHO D YIELD S COMPOUN D SPECIFI C INFORMATIO N SAMPL E QUANTIFIE S MOR E THA N ON E POLLUTAN T SAVE S TIM E AN D COS TI N DEVELOPMEN T

C O

# EXAMPLE S O F GENERI C METHOD S

CHLORINATE D HYDROCARBON S BROMINATE D HYDROCARBON S ALDEHYDE S AN D KETONE S ISOCYANATE S ARY L AMINE S HYDRAZINE S VOS TMETHO D MODIFIE D METHO D 5 (Semi-VOST )

T I C O

# METHOD S DEPEN

D O N TH E LEVE

L OF TH E STANDAR D
DIFFEREN TTECHNIQUE S AR E NEEDE D FO R DIFFEREN TLEVEL S EXAMPLE : BENZEN E
I N TH E 1-10 0 PP M RANGE : Tedla rBa g Sampling , GC-FI D Measuremen t Sampl e Stabilit yBetter , Detectio n Limit s No t Proble m Bot h Developmen t an d Us e Les s Costl y I N TH E PP B RANGE : TH E VOS TMETHO D MUS TB E USED

. Absorbe rTub e Collection , GC/M S Measuremen t Bot h Developmen t an d Us e Mor e Expensiv e

# POLLUTANT-SPECIFI C METHOD S SOM E POLLUTANT S HAV E UNIQU E PROPERTIE S SOM E AR E HIGHL YREACTIV E SOM E MA YOCCU R I N UNIQU E MATRICE S
EXAMPLES : DIAZOMETHAN E ETHYLENEIMIN E PHOSGEN E PHOSPHEN E

## SCHEDUL E
f-9 1 SCREENIN

GMETHO D FO

RCHLORINATE D ORGANIC S COMPLETED . GENERI C METHO D FO

RCHLORINATE D ORGANIC S INITIATED . METHOD S FO

RFIFTEE

N POLLUTANT S COMPLETED , BYBOT H GENERI C AND POLLUTAN T SPECIFI C PROCEDURES . DESIG N AN D ACQUIR E THC CEM S AN D BEGI N FIEL D TESTS . DEVELO P METHO D SPECIFI C QUALIT YASSURANC E GUIDANCE , AUDI T MATERIAL S AN D PROCEDURES .

## SCHEDUL E
-9 2 GENERI C METHOD FO RCHLORINATE D AN

D BROMINATE D ORGANIC S COMPLETED . GENERI C METHOD FO

RALDEHYDE S AN

D KETONE S COMPLETED . 

# Tbrh METHOD S FO

RTWENTY-FIVE POLLUTANT S COMPLETE D B YBOT H GENERI C AN

D POLLUTANT SPECIFI C PROCEDURES . FIELD TES T TH E TH C SYSTE M O N MAC T APPLICATIO

N DURIN GSTANDARD S SETTIN G PHASE . DEVELO P METHOD SPECIFI C QUALIT YASSURANC E GUIDELINE S AUDI T MATERIAL S AN D PROCEDURES .

## SCHEDUL E
r-9 3 GENERI C METHO D FO RISOCYANATE S COMPLETED . METHOD S FO

RTWENTY-FIV

E POLLUTANT S COMPLETE D BYBOTH GENERI C AN D POLLUTANT SPECIFI C PROCEDURES . CONDUC T PROGRA

M O F SPECIFI C TOXI C ORGANI C CEM S FO RTHOS E COMPOUND S REQUIRED . REPORT O

N AUDI T RESULTS .

## SCHEDUL E
?Y-9 4 GENERI C METHO D FO RARY L AMINE S COMPLETED . METHOD S FO

RTWENTY-FIVE POLLUTANT S COMPLETE D BYBOT H GENERI C AND POLLUTANT SPECIFI C PROCEDURES . ?T-9 5 METHOD S FO

RTE N SPECIFI C POLLUTANT S COMPLETED .

T I C O ^ 1 J

## SCHEDUL E

FY-9 6 METHOD S FO

RTE N SPECIFI C POLLUTANT S COMPLETE D

FY-9 7 METHOD S FO

RTE N SPECIFI C POLLUTANT S COMPLETE DP.3 9

Attachmen t 5

ATTACHMEN T TRANSFE REMISSION S Thi s informatio nreques t i s directe dtowar deac hloadin g rac ka t a plan t tha t load s a "SOCMI/HAP" . Fo r thos e rack s tha t ar e use dt o transfe r SOCMI/HA P chemicals , pleas e provid e th e followin g informatio no nTable s 1 though5 fo r al l product s loaded . Th e informatio nshoul dinclud e dat a onnonSOCMI/HA P material s loade da t th e rack . Thi s informatio nshoul db e fo r th e calenda r yea r 198 8 an

dwil l b e use dt o estimat e loadin g emissions . Th e material s transferre dshoul dinclud e an y ra w materials , feedstocks , products , wastes , an dintermediate s fo r th e entir e facilit y tha t loadint o tan ktrucks , railcars , an

dmarin e vessels .TABL E 1 . MATERIAL TRANSFER *

Hateria l Rack/Dock *

Designatio n Quantit y

Transferred 6 (Sa O Percen t o f

Tota l Productio n Tranaferre d Coapositio n o f Product 1 1 (Vol . Xo r Ut . X ) (Circl e you r Choice ) Transfe r Vehicl e Breakdown *

Tan kMarin e Loadin g Truc kRaitca r Vesse l Teaperature * (X ) (X ) (X ) (°F )

r o

'Coaplet e Tabl a 1 for eac hMateria l containin g a NAP chemical .

^Provid e uniqu e identifie r for eac hrac ko r dock . 'Provid e tha tota l quantit y transferre dcontainin g th e subjec t HAP cheaica l an dan y othe r chea t cat s i f a Mixture . Provid e a coaplet e coapositio no f th e produc t transferred . "Provid e the percen t breakdow nb y transfe r vehicl e for eachcheaical . Provid e th e Materia l teaperatur e durin g loading .

vch/09 8 T ITABL E 2 . TRANSFE RVEHICL E SPECIFICATIONS * P.4 1

Transfe r Vehicl e Loading "

Techniqu e Rate d

Capacit y Rang e (Gallons ) Number '

inFlee t Numbe r I

n Flee t Fitte d Wit hEmissions . Control s
Tan kTruc k Rai l ca r Marin e Vesse l
'Identif y transfe r vehicl e specification s fo r you r carrie r fleet . "Splas hloading , submerge dloading , o r bottom filling . 'Numbe r o f transfe r vehicle s inyou r carrie r fleet .

vch/09 8P.4 2

TABL E 3 . TAN

KTRUC KLOADINGRAC KOPERATIO N

Rac k Designation * Numbe r Truck s Loade d Simultaneousl y Maximu m Loadin g ,Fo r Al l Arms " Emissio n

Controls 5

'Correlat e t o Tabl e 1 . "Provid e maximu

m tota l loadin g rat e fo r al l arm s loadin g simultaneousl y i n GPM . c Identif y th e emissio ncontro l devic e an dcomplet e Tabl e 6 i f appropriate .

vch/09 8P.4 3



### TABL E 4 . RAILCA

RLOADIN GRACKOPERATION

Rac k Designation * Numbe r Car s Loade d Simultaneousl y Maximu m Loadin g Fo r Al l Arms b 

### Emissio n

Controls '

•Correlat e t o Tabl e 1 . "Provid e maximu

m tota l loadin g rat e fo r al l arm s loadin g simultaneousl y in GPM . 'Identif y th e emissio ncontro l devic e an dcomplet e Tabl e 6 i f appropriate .

vch/09 8 

# JP.4 4

TABL E 5 . MARIN E VESSEL S LOADIN GDOC KOPERATIO N

Doc k Designation * Numbe r Vessel s Loade d Simultaneousl y Maximu m Loadin g Fo r Al l Arms * Emissio n

Controls '

'Correlat e t o Tabl e 1 . "Provid e maximu

m tota l loadin g rat e fo r al l arm s loadin g simultaneousl y in GPM . 'Identif y th e emissio ncontro l devic e an dcomplet e Tabl e 6 i f appropriate .

vch/09 8 

# JP.4 5

TABL E 6 . EMISSION

CONTRO L DEVICE S

Contro l VO C Rack/Doc kContro l Oevlc e Destructio n Designation * Devic e Desig nCapacit y Efficienc y

*I f a singl e contro l devic e 1 s use dfo r mor e tha n1 rack/dock , 11s t al l applicabl e rack/doc kdesignation .

vch/09 8P.4 6

Attachmen t 6


### ENCLOSUR E 1
IDENTIFICATION

O F PLAN T LOCATION S ANDSPECIFI C PROCES S UNIT S (WHER E POSSIBLE ) FO

RWHIC HINFORMATION

I S REQUESTE D

nja.02 9 1- 1P.4 7

ENCLOSUR E 2 WASTEWATE R HAZARDOU S ORGANI C NESHA P QUESTIONNAIR E
Th e purpos e o f thi s questionnair e i s t o gathe r informatio n o n potentia l ai r emission s fro m

th e collection , treatment , an d handlin g o f industria l wastewater . Th e informatio n requeste d i s fo r eac hproces s uni t specifie d i n Enclosur e 1 . Fo r eac ho f thes e proces s units , informatio n shoul d b e reporte d fo r al l hazardou s ai r pollutant s liste d i n Enclosur e 3 and fo r tota l organi c compounds . Th e compound s liste d i n Enclosur e 3 ar e th e organi c compound s i n th e lis t o f 19 1 hazardou s ai r pollutants . Th e informatio n requeste d i s fo r th e 198 9 calenda r year . Enclosur e 3 , whic hpresent s o f th e 19 1 potentiall yhazardou s ai r pollutant s (HAPs) , include s onl yth e organi c compound s i n th e lis t o f 191 . Throughou t thi s questionnaire , informatio n i s requeste d fo r al l o f thes e HAP s use d o r produce d i n specifi c proces s unit s withi n you r facility
. T o facilitat e completin g thi s questionnaire , you r response s ma yb e keye d t o "HA P codes. " I f yo u wis ht o avoi d repeatedl ylistin g eac hpollutan t throughou t th e questionnaire , complet e Tabl e 1 fo r al l applicabl e HAPs . Th e questionnair e i s designe d t o gathe r informatio n o n wastewate r stream s a t th e poin t o f proces s generatio n (suc ha s a wate r was hcolumn o r a decanter) , prio r t o exposur e t o ambien t ai r an d prio r t o mixin g wit h additiona l wastewate r streams . Thes e stream s ma yb e continuou s o r intermitten t (batc hstreams , leaks , an d spills)
. Informatio n i s als o requeste d fo r an

yoperation s (suc ha s stea mstripping , o r carbo n adsorption ) utilize d a t th e facilit yt o remov e o r recove r organi c compound s fro m wastewate r stream s o r t o trea t thes e stream s befor e dischargin g th e wastewate r fro mth e process . Th e questionnair e I s divide d int o th e followin g thre e sections ; (A ) Compan yan

dProces s Information , (B ) Proces s Wastewate r Strea mData , and (C ) Informatio n o n Recovery/Remova l Operations
. Sectio n A , Tabl e 2 i n Sectio n B , and th e applicabl e table s i n Sectio n C shoul d b e reproduce d and complete d fo r eac hproces s uni t liste d 1 n Enclosur e 1 . Samplin g dat a i s requeste d i n Sectio n B . Pleas e provid e thes e dat a i f available , however , additiona l samplin g i s no t required.

- I f th e informatio n i s no t available , pleas e provid e a bes t estimat e o f th e requeste d pollutan t loadin g and concentratio n data .
nja.02 9 2- 1P.4 8

TABL E 1 . HAZAROOUS AI RPOLLUTAN T CODE S

HA P Cod e Chemica l A Chemica l B Chemica l C Chemica l D Chemica l E Chemica l F Chemica l G Chemica l H Chemica l I Chemica l J CA S Numbe r Chemica l Nam e

nja.02 9 2- 2P.4 9

Sectio nC 1 s designe dt o obtai ndetaile dinformatio no neac hoperatio n utilize dt o recove r o r remov e organi c compound s fro m proces s wastewate r stream s generate dinth e proces s uni t o r t o trea t wastewate r stream s prio r t o discharg e fro

m th e facility . Complet e flnly. th e table s tha t ar e applicabl e t o thi s proces s unit . Th e followin g Section s ar e t o b e complete dfo r eac hproces s uni t a t th e facilit y liste dinEnclosur e 1 . Pleas e mak e a separat e coo v o f thes e section s fo r eac happlicabl e proces s unit .

nja.02 9 2- 3«

SECTIO N- A COMPAN Y AN D PROCES S INFORMATIO N
I . COMPAN Y INFORMATIO N Pleas e provid e th e followin g compan yinformation
. A . Wha t i s th e primar y4-digi t Standar d Industria l Classificatio n (SIC ) cod e fo r thi s facility ?

B . Wha t i s th e secondar y4-digi t SI C cod e fo r thi s facility ?

II . GENERA L PROCES S INFORMATIO N Provid e th e followin g informatio n fo r eac hproces s uni t Identifie d i n Enclosur e 1 tha t generate s wastewate r stream s containin g anyo f th e compound s liste d i n Enclosur e 3 . A . Proces s I D
B . Proces s Name
C . Proces s Descriptio n

nja.02 9 2- 4 P.5 0P.5 1

D . Provid e a proces s bloc kflo w diagram identifyin g al l proces s strea m (e.g., . inputs/feedstocks , intermediat e products , products , byproducts ) an

dwastewate r streams . Provid e a descriptio no f th e wastewate r stream s (e.g. , was htowe r sou r water , decante r drawoff , etc. ) an dsho w an y operation s utilize dt o trea t o r remove/recove r organi c compound s fro

m thes e wastewate r streams . Eac hwastewate r strea m shoul dbe identifie db y a nidentificatio nnumbe r fo r us e i n Tabl e 2 presente di

nSectio nC . Operation s utilize dt o trea t o r remove/recove r organi c compound s fro m thes e wastewate r stream s shoul db e assigne didentificatio nnumber s a s well .

Product(s )

F . Typ e o f Proces s - batch , continuous , semi-continuou s (circl e one )

G . Nomina l Productio nCapacit y (DesignCapacity ) (pounds/year )

H . Capacit y

Utilizatio nfo r th e 198 9 Calenda r Yea r ( % o f desig ncapacity ) (lis t fo r eac hproduct )

nja.02 9 2- 5P.5 2

I . Wha t wer e th e mai nCHEMICA L INPUTS/FEEDSTOCK S use db y th e proces s in198 9 an

dhow muc hwa s use do f eac hinput/feedstock ? Identif y b y chemica l name o r HA P cod e i f appropriate . Chemica l Inputs/Feedstock s Quantit y Use din198 9 pound s o r - ton s pound s o r ton s pound s o r ton s

, pound s o r ton s

Wha t wa s th e principa l chemica l produc t (b y weight ) tha t thi s proces s uni t produce din1989 ? Identif y b y chemica l name o r HA P cod e i f appropriate .

How muc ho f th e principa l chemica l produc t di dthi s proces s uni t produc e in1989 ?

L . Wha t i s th e mai nENDUS E o f thi s principa l chemica l product ?

M . Di dth e proces s uni t produc e an y othe r chemica l product s in1989 ? Ye s No (I f No , ski pt o questio nP )

nja.02 9 2- 6P.5 3

N . Wha t othe r chemical s di dthi s proces s uni t produc e in198 9 an dho w muc hdi di t produc e o f eac ho f thes e othe r chemica l products ? Identif y b y chemica l name o r HA P cod e i f appropriate . Othe r Chemica l Product s Quantit y Produce din198 9 oound s o r pound s o r pound s o r pound s o r ton s

ton s ton s ton s

0 . Wha t wer e th e mai nENDUSE S o f thes e othe r chemica l product s in1989 ? Othe r Chemica l Product s En dUs e o f Chemica l Product s

P . Wha t wa s th e tota l valu e (1989$ ) o f eac hindividua l chemica l produc t produce db

y thi s proces s uni t in1989 ?

Q . Lis t below

an y HAP s tha t occu r inwaste s (othe r tha nwastewater ) o r Intermediat e material s tha t wer e produce dinthi s proces s i n198 9 an dth e quantit y

produce do f each . Identif y b y chemica l name o r HA P cod e i f appropriate . D o no t includ e an y waste s tha t ar e permitte d unde r th e Resourc e Conservatio nan dRecover y

Ac t (RCRA ) o r tha t ar e manage dinRCRA-permitte dunits . A nexampl e o f a wast e tha t shoul d b e reporte dwoul db e a wast e tha t 1 s recycle dan dreuse dinth e productio nprocess' .

nja.02 9 2- 7P.5 4

Wastes/Intermediat e Materia l Quantit y Produce di

n198 9

" pound s o r ton s pound s o r ton s

_pound s o r ion s pound s o r ton s

R . Fo r eac hwast e o r intermediat e materia l Identifie di n4 above , indicat e th e destinatio no f tha t materia l (e.g. , recycle dwithi nth e productio nunit , use di nanothe r productio nunit , sol da s intermediate , etc. ) Waste/Intermediat e Materia l Destinatio n

nja.02 9 2- 8P.5 5

SECTION - B PROCES S WASTEWATE RSTREA M DAT A
Fo r eac hproces s wastewate r strea m show n1 nth e flow

shee t diagram , provid e the informatio nrequeste di nTabl e 2 . Th e tabl e request s informatio n o nproces s wastewate r flo w data , an

dproces s wastewate r pollutan t concentratio ndata . Th e proces s wastewate r flo w question s ar e designe dt o obtai nflow characteristic s o f eac hproces s wastewate r strea m show ninth e diagram requeste dinSectio nA . Th e informatio nrequeste dshoul db e complete dfo r al l wastewate r streams . Fo r intermitten t wastewate r streams , pleas e provid e bes t estimate s o f frequency , duration , an dflo w rat e durin g flow

periods . I f the informatio no

nthe wastewate r stream s provide dI s base do nactua l samplin g data , provid e samplin g period , frequency , an dmethod . Tabl e 2 als o request s individua l HA P an dtota l organi c compound concentratio ndat a fo r eac hindividua l proces s wastewate r strea m a t th e poin t o f generatio n(prio r t o mixin g wit hothe r wastewaters) . I f th e wastewate r strea m wa s sampled , pleas e provid e th e measure dconcentration s o f eac hHA P detected , an

dth e tota l organi c compoundconcentratio ninTabl e 2 . In addition , pleas e indicat e th e analytica l metho dutilize dt o quantif y eac h pollutan t concentration . I f samplin g wa s no t conducted , pleas e provid e a bes t estimat e o f th e requeste dconcentration s base donoperationa l consideration s (e.g. , equilibriu m solubility , etc.) .

nja.02 9 2- 9TABL E 2 . PROCES S WASTEWATE RSTREA M DAT A Oraenl c Concentratio n Waatawatar * Waatawajar flo w pat . Annua l ^.^. 4 t „ lm t Strea a 1 0 Flo w Rata " Unlt a litl i fo r Eatlaate c Caaapound " Average Kanae " Eatlaate * Controla *

*Uae atraa a IdantlfIcatIo nprovlda

dl nth a procaaa flo

w dlagraa . I f contlnuoua . rapor t flo w durln a nom a I oparatlon . I f noncon t lnuoua , provld a frequenc

y o f flo w (nuaba r pa r day) , durationo f flo w (hr) . an

d flo w rat a (gal/hr) . c I f flo w cat * aaaaureaan t dat a ar a avaliabla , provld a aaaplln

a period , aaaplln

a anthod , an

dfraquancy . I f flo w rat a l a baaa do na naatlaata , provld

a baal s for aatlaata . "Provld a Individua l concantratlon a fo r al l HAP s llata

dl nEncloaura 3 whic

har a praaant Inth

a waatawatar atraaa , an dprovld

a a tota l orsani c concant ra

t Ion . 'Provld a th a ranea o f concant ra t lon a aapacta

dfo r th a compoun

dt nthat waatawatar atraaa . 'Indicat e concentrationan dwhether concentratio nwaa aMaaurad(a) , or eatlaeted , (a) . I f aeasured , rapor t aatho d (a.». . EP

A aetho d601 . 625 , ate) , 'identify

operation * utilise dto recover/r«aoy

« organi c compound * froa th a waatawatar atraaa . Uaa th e operatio

nIdentificatio

nnuabar provlda

dl nth a procaaa flo

w dlagra a an

dcoaplet e appropriat e tablaa I nSectio

nC fo r th e operation .P.57
_

SECTIO N - C INFORMATION

O N ORGANI C RECOVERY/REMOVA L OPERATION S
Fo r eac hoperatio nutilize dt o recover/remov e organi c compound s fro m wastewate r stream s generate db y processe s tha t produc e o r proces s a s a reactant an

y o f th e HAP s inTabl e 1 , provid e th e followin g dat a concernin g th e specifi c operation s inth e appropriat e tables . Table s ar e provide dfo r seve n operation s commonl y

use dt o recover/remov e organic s fro m wastewate r o r t o trea t wastewate r prio r t o discharg e t o a wastewate r treatmen t facility . I f a n operatio ni s bein g utilize dothe r tha non e o f th e seve nliste doperations , pleas e attac ha shee t detailin g simila r desig ndata . Informatio ni s requestedfo r eac hoperatio nonth e majo r piec e o f equipmen t (I.e. , th e strippe r column , th e carbo nadsorber , etc.) . In addition , fo r steam

strippers , a breakdow no f th e majo r system

component s a s wel l a s utilit y

usag e i s requested . Complet e onl y th e table s tha t ar e utilize dinyou r process .

nja.029 2-1 1P.5 8

TABL E 3 . AI R STRIPPIN G - COLUMNDESIGN

Ai r Strippin g Column ID * Column Operatin g Variable s Pressur e Dro p (psig ) Temperatur e (°F ) Air/Fee d Rati o (scf mair/l b feed ) Column Dimensions : Diamete r (ft ) Heigh t (ft ) Internals : Tray s (no. , type ) Packin g (type ) Desig n Efficiency , % (Specif yb

ychemical )

Strippe d Organic s Destination " Ai r Emissio n Contro l Devic e Specify 8 Efficiency , X (Specif y b y chemical )

*Us e th e sam

e identificatio ntha t wa s usedi nth e flo

w diagram . "Proces s recycle , incinerator , etc . 'Carbo n adsorber , condenser , etc .

nja.02 9 2-1 2P.5 9

« . »

TABL E 4 . ADSORPTIO N- ADSORBE R DESIGN

Adsorbe r ID *
Liqui d o r Ga s phas e (specify ) Typ e o f Adsorbent " Adsorptio n Column Dimensions : Height , (ft) c Diameter , (ft) e Syste mVariables : Contac t time , (m1n) e Syste mconfiguration " Adsorben t Regeneration * Adsorben t Capacity , (l b solute/l b adsorbent ) Desig n Efficiency , % (Specif yb

ychemical )

Adsorbe d Organic s Destination 1
•Us e th e sam e identificatio n tha t wa s use d i n th e flo wdiagram
. "Activate d Carbo n (GAC.PAC) , Io n Exchang e Resin , Othe r (describe)
. 'Specif yunit s 1 f differen t fro mth e unit s listed
. Parallel , Series, Movin g bed , Upflow-expande d bed , Othe r (specify)
. •Thermal , Chealcal , Othe r (specify)
. 'Incinerator , Recycl e t o Process , etc .

nja.02 9 2-1 3P.6 0

TABL E 5 . DISTILLATIO N

- COLUM N DESIG N
Distillatio nID *

Colum nOperatio nMode " Colum nOperatin g Variable s Pressur e (psig) c Temperatur e (°F) C Steam/Fee dRatio * Colum nDimensions : Diamete r (ft) c Heigh t (ft) c Internals : Tray s (no. , type ) Packin g (type ) Desig nEfficiency , % (Specif y b y chemcial )

Distille dOrganic s Destination * I s condense r vente dt o th e atmosphere ? Condense r Temperatur e (°F), C Condense r Pressur e (psig) °
•Us e th e saa t Identificatio nnumbe r tha t wa s use dinth e flow diagram . "Batc ho r continuous . 'Specif y unit s i f no t th e same a s requested . Specif y units . 'Incineration , proces s recycle , etc .

nja.029 2-1 4P.6 1

' * . 

### TABL E 6 . STEAMSTRIPPING- STRIPPE R AN D AUXILIAR Y EQUIPMEN T DESIGN

Stea mStrippin g ID *

Column Operatin g Variable s Pressur e Dro p (psig) b 

### Temperatur e (°F) b 

### Steam/Fee d Ratio * Stea mTemperatur e (°F) b 

### Stea mPressur e (pslg) " Column Dimensions : Diamete r (ft) " Heigh t (ft) b 

### Internals : Tray s (number , type ) Packin g (type ) Desig n Efficiency , % (Specif yb ychemical )

Strippe d Organic s Destination 1 1


### •Us e th e sam e Identificatio n tha t wa s use d i n th e flo wdiagram
. "Includ e unit s I f no t sane a s requested . 'Specif yunits . Recycl e t o Process , Incineration , etc .

nja.02 9 2-1 5P.6 2

TABL E 6 . STEA

M STRIPPING- AUXILIAR YEQUIPMEN T OESIGN (continued )

Steam Strippe r ID * System Tank s Lis t an dspecif y

type, " Volum e (gal) 6 Hold-u ptime (min) c
Hea t exchanger s Lis t an dspecif y

surfac e area , ft 2 ) ' Pump s Lis t an dspecif y

h p Condenser s Lis t an dspecif y

typ e Othe r system

component s Lis t an dspecif y

Utilit y Usag e Steam (psig , lb/yr) ° Electricit y

(kw-hr/yr) « Wate r (gal/yr) e Proces s ai r (ft 3 /yr) a Othe r (specify )
•Us e th e I.D . use di nth e flow diagram . "Feedtank, treate dwastewate r surg e tank, etc . 'Specif y unit s i f differen t fro m th e unit s listed .

nja.02 9 2-1 6P.6 3

' \
.

TABL E 7 . SOLVEN T EXTRACTION - EXTRACTO RDESIG N
Solven t Extractio nID *
Operatio nMode " Extractin g Solven t Use d Vesse l Description 0 Vesse l Dimension s Diamete r (ft) d Heigh t (ft) 4 So l vent:Fee dRatio * Desig nEfficiency , % (Specif y b y chemical )

Extracte dOrganic s Destination '
•Us e th e same identificatio ntha t wa s use dinth e flow diagram . "Batc ho r continuous . 'Mixing-settlin g vessels , spray tower , packe dtower , etc . d Specif y unit s i f no t sam e a s requested . 'Specif y units . 'Distillatio ncolumn , Incinerator , etc .

nja.029 2-1 7P.6 4

J i\ i t *

-

TABL E 8 . CHEMICA L OXIDATIO N- OXIDIZE R DESIGN
Chemica l Oxidatio n ID *

Oxidizin g Agent " Oxidant:Fee d Ratio * Reactio n Vesse l Description 4 Vesse l Dimensions : Heigh t (ft) * Diamete r (ft) * Require d Contac t Tim e (min.) ' Desig n Efficiency , % (Specif yb

ychemical )

'Us e th e sam e Identificatio n tha t wa s use d i n th e flo wdiagram
. "Hydroge n peroxide , ozone , potassium permanganate , etc . 'Specif yunits
. "Ope n to p tank , close d vessel , etc . 'Includ e unit s i f no t sam e a s requested .

nja.02 9 2-1 8P.6 5

» V i • r

TABL E 9 . BIOLOGICA L TREATMEN T - TREATMEN T BASI NDESIGN

Biologica l Treatmen t ID *

Treatmen t Basin/Tan k Descriptio n Treatmen t Basi n Diamete r (ft) c Treatmen t Basi n Dept h(ft) 0 Minimu mFreeboar d (ft) * Aerator s (type ) Numbe r Powe r (hp) ° Volum e (gal ) Retentio n tim e (hrs) ' Desig n Efficiency , X (Specif yb

ychemical )

'Us e th e sam e identificatio n tha t wa s use d i n th e flo w diagram
. "Ope n to p tank , holdin g basin , surfac e impoundmen t (lined , unlined) , covere d tank , etc . 'Includ e unit s i f no t san e a s requested .

njt.02 9 2-1 9P.6 6



### TABL E 10 . OIL/WATE R SEPARATO R DESIGN Oi l Wate r Separato r ID * Separato r Lengt h(ft) " Separato r Widt h(ft) " Volum e (gal) " Retentio n tim e (hr) b 

### Influen t Compositio n Oi l Fractio n (weigh t %) " Tota l Organi c Compound s (specif yb ychemical ) Desig n Efficienc y(X ) Oi l Fractio n Tota l Organi c Compound s (specif yb ychemical ) Remove d Organic s Destination 0 

### Utilit yUsag e Electricit y(kw-hr/yr) " Othe r (specify ) Ai r Emissio n Controls * 'Us e th e sam

e Identificatio n tha t wa s use d i n th e flo w diagram
. "Includ e unit s 1 f no t sam e a s requested . 'Recycl e t o process , Incineration , etc . 'Describ e anycontrol s i n plac e t o reduc e ai r emission s fro mth e oil-layer
.

nja.02 9 2-2 0P.6 7

ENCLOSUR E 3 HAZARDOU S AI RPOLLUTANT S
CA S NUMBE R CHEMICAL

NAME 7507 0 Acetaldehyd e 6035 5 Acetamid e 7505 8 AcetonitrU e 9886 2 Acetophenon e 5396 3 2-Acetylaminofluorin e 10702 8 Acrolei n 7906 1 Aery 1 amid e 7910 7 Acryli c ad d 10713 1 Acrylonitril e 10705 1 Ally l chlorid e 9267 1 4-Aminobipheny l 6253 3 Anilin e 9004 0 o-Anisidin e 7143 2 Benzen e (Including benzen e fro m gasoline ) 9287 5 Benzidin e 9807 7 Benzotrichlorid e 10044 7 Benzy l chlorid e 9252 4 Bipheny l 11781 7 B1s(2-ethylhexy1)phtha1at e (DEHP ) 54288 1 B1s(chloromethyl)ethe r 7525 2 Bromoform 10699 0 1,3-Butadien e 10560 2 Caprolactam 13306 2 Capta n 6325 2 Carbary l 7515 0 Carbo ndisulfid e 5623 5 Carbo ntetrachlorid e 16358 1 Carbony l sulfid e 12080 9 Catecho l 13390 4 Chloranbe n 5774 9 Chlordan t 7911 8 Chloroaceti c ad d 53227 4 2-Chloroacetophenon e 10890 7 Chlorobenzen e 51015 6 Chlorobenzllat e 6766 3 Chloroform 10730 2 Chloromethy l methy l ethe r 12699 8 Chloropren e 31977 3 Cresols/Cresyll c aci d(Isomer s an dmixture ) 9548 7 Cresols/Cresyll c aci d(Isomer s an dmixture ) 10839 4 Cresols/Cresyl1 c aci d(Isomer s an dmixture ) 10644 5 Cresols/Cresyl1 c aci d{ isomers an

dmixture ) 9882 8 Cumen e

nja.02 9 3- 1P.6 8

ENCLOSUR E 3 (Continued )
CA S NUMBE R 9475 7 354704 4 33488 3 13264 9 9612 8 8474 2 10646 7 9194 1 11144 4 54275 6 6273 7 11142 2 12169 7 6467 5 11990 4 6011 7 11993 7 7944 7 6812 2 5714 7 13111 3 7778 1 53452 1 5128 5 12114 2 12391 1 12266 7 10689 8 10688 7 14088 5 10041 4 5179 6 7500 3 10693 4 10706 2 10721 1 15156 4 7521 8 9645 7 7534 3 5000 0 7644 8 11874 1 8768 3 7747 4 CHEMICAL NAME 2,4-D , salt s an

dester s DD E Diazomethan e Dibenzofuran s l,2-01bromo-3-chloropropan e Dlbutylphthalat e 1,4-D1ch1orobenzene(p ) 3,3-D1ch1orobenziden e Dichloroethy l ethe r (b1s(2-chloroethyl)ether ) l,3-D1chloropropen e Dichlorvo s Diethanolamin e N,N-D1ethy l anilin e (N,N-Dimethylan1l1ne ) Diethy l sulfat e 3,3'-D1methoxybenz1din e Dimethy l aminoazobenzen e 3,3'-Dimethy l benzidin e Dimethy l carbamoy l chlorid e Dimethy l formamid e 1,1-Dimethy l hydrazin e Dimethy l phthalat e Dimethy l sulfat e 4,6-D1n1tro-o-cresol , an dsalt s 2,4-D1n1tropheno 1 2,4-01n1trotoluen e 1,4-Dioxan e (l,4-D1ethyleneoxide ) 1,2-D1phenylhydrazin e Epichlorohydri n(l-Ch1oro-2,3-epoxypropane ) 1,2-Epoxybutan e Ethy l acrylat e Ethy l benzen e Ethy l carbamat e (Urethane ) Ethy l chlorid e (Chloroethane ) Ethylen e dlbromid e (Dibromoethane ) Ethylen e dichlorid e (1,2-Dichloroethane ) Ethylen e glyco l Ethylen e 1m1n e (Aziridine ) Ethylen e oxid e Ethylen e thioure a EthylIden e dichlorid e (l,2-D1ch1oroethane ) Formaldehyd e Heptachlo r Hexachlorobenzen e Hexachlorobutadien e Hexachlorocyclopentadien e

nja.02 9 3- 2P.6 9

ENCLOSUR E 3 (Continued )
CA S NUMBE R
6772 1 82206 0 68031 9 11054 3 30201 2 12331 9 7859 1 5889 9 10831 6 6756 1 7243 5 7483 9 7487 3 7155 6 7893 3 6034 4 7488 4 10810 1 62483 9 8062 6 163404 4 10114 4 7509 2 10168 8 10177 9 9120 3 9895 3 9293 3 10002 7 7946 9 68493 5 6275 9 5989 2 56382 : 8268 % 8786 5 10895 2 10650 3 7544 5 8544 9 133636 3 112071 4 5757 8 12338 6 CHEMICAL

NAME Hexachloroethan e Hexamethylene-1,6-d i isocyanat e Hexamethy1phosphoram i d e Hexan e Hydrazin e Hydroquinon e Isophoron e Lindan e (al l isomers ) Malei c anhydrid e Methano l Methoxychlo r Methy l bromid e (Bromomethane ) Methy l chlorid e (Chloromethane ) Methy l chloroform

(1,1,1-Trichioroethane ) Methy l ethy l keton e (2-Butanone ) Methy l hydrazin e Methy l Iodid e (Iodomethane ) Methy l isobuty l keton e (Hexone ) Methy l 1socyanat e Methy l methacrylat e Methy l ter t buty l ethe r 4,4-Methylen e b1s(2-chloroaniline ) Methylen e chlorid e (01chloromethane ) Methylen e dipheny l diisocyanat e (MDI ) 4,4'-Methylenedlanilin e Naphthalen e Nitrobenzen e 4-Nitroblpheny l 4-Nitropheno l 2-N1tropropan e N-N1troso-N-»ethylure a N-Nitrosodimethy l amin e N-N1trosonorphol1n e Parathlo n Pentachloronltrobenzen e (Quintobenzene ) Pentachloropheno l Pheno l p-Phenylenedlamin e Phosgen e Phthali c anhydrid e Polychlorinate dbiphenyl s (Aroclors ) 1,3-Propan e sulton e beta-Proplolacton e Propionaldehyd e

nja.02 9 3- 3P.7 0

CA S NUMBE R ENCLOSUR E 3 (Continued )

CHEMICAL NAME 11426 1 Propoxu r (Baygon ) 7887 5 Propylen e dichlorid e (l,2-D1ch1oropropane ) 7556 9 Propylen e oxid e 7555 8 l,2-Propylenim1n e (2-Methy l azlridine ) 9125 5 Quinolin e 10651 4 Quinon e 10042 5 Styren e 9609 3 Styren e oxid e 174601 6 2,3,7,8-Tetrachlorodibenzo-p-diox1 n 7934 5 1,1,2,2-Tetrachloroethan e 12718 4 Tetrachloroethylen e (Perchloroethylene ) 755045 0 Titaniu

m tetrachlorid e 10888 3 Toluen e 9580 7 2,4-Toluen e diamin e 58484 9 2,4-Toluen e diisocyanat e 9553 4 o-Toluidin e 800135 2 Toxaphen e (chlorinate dcamphene ) 12082 1 1,2,4-Trichlorobenzen e 7900 5 1,1,2-Trlchloroethan e 7901 6 Trichloroethylen e 9595 4 2,4,5-Trlchloropheno l 8806 2 2,4,6-Trichloropheno l 12144 8 Triethy l amin e 158209 8 Trlflurall n 54084 1 2,2,4-Trimethylpentan e 10805 4 Viny l acetat e 59360 2 Viny l bromid e 7501 4 Viny l chlorid e 7535 4 Vinyliden e chlorid e (1,1dichloroethylene ) 133020 7 Xylene s (Isomer s an dmixture ) 9547 6 Xylene s (Isomer s an dmixture ) 10838 3 Xylene s (Isomer s an dmixture ) 10642 3 Xylene s (Isomer s an dmixture ) 0 Glyco l ethers * 0 Polycyll c organi c matter " an ddi - ether s o f ethylen e glycol , diethylen e glycol , 'Include s mon o an dtriethylen e glyco l R-(OCH2CH2 ) -OR ' wher e n• R- R * 1 , 2 , o r 3 alky l o r aryl group s • R , H , o r group s which , whe nremoved , yiel dglyco l ether s wit hth e structure : R-(0CH2CH) B -0 H Polymer s ar e exclude dfro m th e glyco l category . "Include s organi c compound s wit hmor e thanon e benzen e ring , an dwhic hhav e a boilin g poin t greate r tha no r equa l t o 100'C .

nja.02 9 3- 4P.7 1

Attachmen t 7

CHEMICA L MANUFACTURER S ASSOCIATIO N Februar y

1 , 199 0

Mr . Rober t Rosensteel , Chie f Chemica l Manufacturin g Sectio n Chemical s an

dPetroleu

m Branc h Offic e o f Ai r Qualit y Plannin g an

dStandard s MD-1 3 U.S . Environmenta l Protectio nAgenc y Researc hTriangl e Park , N C 2771 1 ^,

_. r . n „ 1- . . Onbehal f o f Kare nFidler , mysel f an dthe CM

A membe r companies , I woul dlike t o thank yo uan dthe othe r OAQP S staf f for takin g th e tim e t o discus s EPA' s plan s for implementing Titl e II I o f the Clea nAi r Ac t amendments . Th e discussio nwa s mos t informativ e for u s an dwe .hop

e tha t we were abl e t o giv e yo usom e ide a o f wha t area s we were concerne d wit han

dho w we ma y

abl e t o provid e yo uwit hadditiona l informatio nfor you r regulator y

developmen t efforts . I hav e liste dbelo w som e o f the topic s the groupagree dwere area s for follo

w up :
o Holdin g a join t worksho pt o discus s specifi c implementatio n topic s i nmor e detail ;
o Holdin g a meetin g t o discus s ho w cos t wil l b e factore dint o standar ddevelopment ;
o Possibl e join t funding o f researc hactivities ;
o Availabilit y

o f plan t site s for EPA researc hactivities ;
o CM

A comment s ondraf t questionnaire s o nwastewate r an d *-.ri7if»fr.

r opars t f ?r.n ;
o Fillin g industry profil e gap s o nselecte dchemica l productio n processes . I naddition , CM

A suggest s tha t we hav e furthe r discussion s o nthe feasibilit y

o f providin g informatio nt o EP A o nthe following :
o Existin g level s o f contro l inth e chemica l industry ;
o Characterizatio no f mode l plant s for selecte dchemica l productio nprocesses ;
o Estimatin g HAP:VO C ratio s for selecte dchemica l productio n processes .

250 1 M Street

. NW

. Washington

. D C 2003 7 202-887-110 0 Tele x8961 7 (CM AWSH )P.7 2

2/ :

Wit hregar dt o th e questionnaires , CMAanticipate s submittin g comment s t o EP Ath e wee k o f Februar y12-16 . Kare n o r I wil l cal l yo u i n th e nex t fe wday s abou t th e bes t foru mfo r presentin g ou r comment s t o EPA . I f yo u hav e an

yquestions , pleas e giv e u s a call . Onc e again , than k yo u fo r th e opportunit yt o mee t wit h you , an d w e loo k forwar d t o workin g wit h yo u i n th e future . Sincerely ,

Richar d G . Sigma n Associat e Director , Ai r Program s
cc : Michae l Shapir o Stanle yMeibur g Bo b Kellat n