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## UNITED STA **TES ENVIRONMENTA L PROTECTION A**  **GENCY** WA SHINGTON, D.C. 20460 **OFFICE OF CHEMICAL SAFETY AND**  **POLLUTION PREVENTION** 

## Date: 05 - JUN - 2014 **Subject: Sulfentrazone**  **– Acute and Chronic**  **Aggregate Dietary**  **(Food and Drinking**

**Water) Exposure and Risk Assessments**  for the Section 3 Registration Request for a New Use on Apples and for the Preliminary Human - Health Risk Assessment for Registration Review . **PC Code:**  129081 **DP Barcode:** D 4 1 7 1 7 2 **Decision Nos.:** 476747, 483232 **Registration Nos. :**  279 - 3370, 279 - 3189, & 279 - 3220 **Petition No.:** 3E8202 **Regulatory Action:** Section 3 **Risk Assessment Type:** Dietary **Case No.:** 7231 **T XR No.:**  NA **CAS No.:** 122836 - 35 - 5 **MRID No.:** NA **40 CFR:** §180.498 

## From: George F. Kramer, Ph.D., Senior Chemist

R isk A ssessment Branch 1 (RAB1) Health Effects Division (HED, 7509P) **Through:** Thurston Morton, Senior Chemist

Pete Savoia, Chemist Dietary Exposure Science Advisory Council (DESAC) a nd Charles W. Smith III, Branch Chief RAB1/HED (7509P) **To:** Laura Nollen/Barbara Madden, RM 05

Registration Division (RD; 7505P) and Michael Goodis, RM 53 Pesticide Re - evaluation Division (PRD; 7508P) **Executive Summary** Acute and chronic dietary - exposure and risk assessments were conducted using the Dietary Exposure Evaluation Model - Food Consumption Intake Database (DEEM - FCID, ver. 3.16) which incorporates consumption data from United States Department of Agriculture (U SDA) National Health and Nutrition Examination Survey , What We Eat in America,

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## (NHANES/WWEI A; 2003 - 2008). The revised assessment is being conducted in support of a new use on apples and the preliminary human - health risk assessment for Registration Review of sulfentrazone . This memorandum was reviewed by two peer reviewers of the DESAC, per DESAC SOP 2012.1. Acute Dietary

(Food and Drinking Water) Exposure Results and Characterization The acute anal ys is assumed tolerance - level residues for all commodities , 100% crop treated ( % CT) , and DEEM (ver. 7.81) default processing factors . The acute anal ys is also incorporated the most recent drinking water estimates provided by the Environmental Fate and Effects Division ( EFED ) . The resulting acute food plus water risk estimates are below HED ’s level of concern [ <100% of the acute population - adjusted dose (aPAD) ] at the 95 th 

## percentile of the exposure distribution for the U . S . general population ( < 1 % aPAD) . T he aPAD is lower for females 13 to 49 ye ars old . Although all infants (<1 y ear old) old had the highest exposure estimate ( 0.026754 mg/kg/day ; 1 .1 % a PAD), t he population subgroup with the highest risk estimate was females 13 to 49 y ears old , which utilized 7 % of the aPAD ( 0.00 9363 mg/kg/day ) . Chronic Dietary

(Food and Drinking Water) Exposure Results and Characterization The chr onic anal ys is assumed tolerance - level residues , 100% CT , and DEEM (ver. 7.81) default processing factors for all commodities. The chronic anal ys is also incorporated the most recent drinking water estimates provided b y EFED. The resulting chronic risk estimates are below HED’s level of concern for the U.S. general population [<100% of the chronic population adjusted dose (cPAD)] , and all population subgroups . T he population subgroup with the greatest exposure and risk estimate was children 1 - 2 y ears old , which utilized 7 % of the cPAD . Cancer Dietary

(Food and Drinking Water) Exposure Results and Characterization A cancer dietary

assessment was not conducted because sulfentrazone is classified as “not likely to be carcinogenic to humans.” **I. Introduction**  Dietary risk assessment incorporates both exposure and toxicity of a given pesticide. For acute and chronic assessments, the risk is expressed as a percentage of a maximum acceptable dose (i.e., the dose which HED has concluded will result in no unreasonable adverse health effects). This dose is referred to as the PAD. The PAD is equivalent to a point - of - departure [ POD; e.g., no - observable - adverse - effect - level (NOAEL) ] divided by the required uncertainty

or safet y factors. For acute and non - cancer chronic exposures, HED is concerned when estimated dietary risk exceeds 100% of the PAD. Refer ences which discuss the acute and chronic risk assessments in more detail are available on the EPA/pesticides web site: “Available Information on Assessing Exposure from Pesticides, A User’s Guide,” 6/21/2000, web link: http://www.epa.gov/fedrgstr/EPA - PEST/2000/July /Day - 12/6061.pdf

; or see SOP 99.6 (8/20/99). The most recent sulfentrazone dietary exposure assessment was conducted by J. Van Alstine for the Section 3 registration request for new uses on rhubarb, turnip roots and tops, sunflower subgroup 20b, succulent cowpea, succulent lima bean, succulent vegetable soy bean, wheat

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## (spring), citrus fruit group 10 - 10, low - growing berry group 13 - 07, tree nut group 14, pistachios, and crop group 18 nongrass animal feeds ( 14 - JUN - 2012 ; D389973 ) . **II. Residue Information**  Residues of Concern in Plants and Livestock: The HED Metabolism Assessment Review Committee (MARC) has determined that the parent compou nd, sulfentrazone, and the metabolite HMS [ N - (2,4 - dichloro - 5 - (4 - (difluorometh yl ) - 4,5 - dihy dro - 3 - hy drox ym eth yl - 5 - oxo - 1 H - 1,2,4 - triazol - yl )phen yl )methanesulfonamide)] are the residues of concern in so yb eans, and that sulfentrazone and its metabolites HMS and DMS [( N - 2,4 - dichloro - 5 - [4 - (difluoromethy l) - 4,5 - dihy dro - 5 - oxo - 1 H

- 1,2,4 - triazol - 1 - yl )pheny l)methanesulfonamide] are the residues of concern in rotational crops (Memo, G. Kramer, 14 - JUN - 1996; D226434) . HED has concluded that the results of the rotational cr op metabolism studies may be translated to support preemergent uses on all ty pes of crops. Additionally , sulfentrazone and its metabolites HMS and DMS were identified as the residues of concern in meat, milk, poultry , and eggs. The HED MARC concluded tha t parent and 3 - carbox yl ic acid sulfentrazone are the residues of concern for the drinking - water assessment (Memo, G. Kramer et al. , 10 - APR - 2003; D288713) . HED continues to consider the given metabolites and degradates to be the residues of concern for ris k assessment. Established/Recommended Tolerances: A tolerance is currently established under 40 CFR §180.498(a)(1) for the combined residues of sulfentrazone and its major metabolite, HMS, in/on soy bean seed at 0.05 ppm. I n addit ion, permanent tolerances are established under 40 CFR §180.498(a)(2) for the combined residues of sulfentrazone and its metabolites HMS and DMS in/on several food commodities ; these established tolerances range from 0.15 ppm (various plant commodities) to 0.40 ppm (peanut meal and Brassica , leafy greens, subgroup 5B) . Tolerances for the combined residues of sulfentrazone and its metabolites HMS and DMS have been established under 40 CFR §180.498( c ) in connection with regional registrations ; these include tolerances for residues in/on succulent lima bean, succulent cowpea, and wheat grain at 0. 15 ppm. Finally , tolerances are established under 40 CFR §180.498(d) for inadvertent and indirect combined residues of sulfentrazone and its metaboli tes HMS and DMS in/on cereal grain (excluding sweet corn) bran, forage, grain, hay , hulls, stover, and straw at 0.1 - 0.6 ppm as a result of the application of sulfentrazone to growing crops. T he proposed uses and the submitted data support the establishmen t of the following tolerance for the combined residues of sulfentrazone and its metabolites HMS and DMS in/on (G. Kramer, 05 - JUN - 2014 ; D 415626 ) : **Table 1. Tolerance Summary for Sulfentrazone.**

Commodity Recommended Tolerance (ppm) **Establish under 40 CFR §180.498(a)(2):**  Apple 0.15 

## Wet apple pomace is the only significant new feedstuff for livestock (ruminants only ). As no quantifiable residues were found in apples treated at an exaggerated rate (5X) and tolerances are established for feed items at higher levels than the recommended tolerance for the combined residues of sulf

entrazone, DMS, and HMS of 0.15 ppm for apple (e.g., 0.50 ppm for wheat forage), the proposed new use on apples is not expected to increase the livestock dietary burdens.

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## Residues used in the Acute and Chronic Analyses : The se analy s e s employ ed tolerance - level residues for all commodities , 100% CT , and DEEM (ver. 7.81) default processing factors . The establish ed tolerance for succulent vegetable soy bean is greater than the 40 CFR§180.498(a)(1) tolerance for so ybean seed; therefore the succulent vegetable soy bean tolerance of 0.15 ppm was used for so ybean seed as a conservative assumption. Fish: The USDA Pesticide Data Program (PDP) monitored pesticide residues in catfish in 2008, 2009, and 2010. In general, pesticide residues would not be expected to be found in fish unless the pesticide bio accumulates or has an aquatic use. To determine whether or not residues are present in fish, HED now routinely checks PDP monitoring data regardless of the pesticide’s uses and ph ys icochemical properties. Howe ver, PDP did not analy ze catfish samples for sulfentrazone. As a result, residues in fish were not included in the assessment. **I II.**  **Estimated Drinking Water**  **Concentrations** D rinking water residues provided b y EFED (Memo, M. Barrett, 21 - M A Y - 201 4; D415627 ) were incorporated directl y into the acute and chronic dietary analy ses as “water, direct, all sources” and “water, indirect, all sources . ” The estimated drinking water concentrations (EDWCs) were Tier 1 estimates for ground water using the Pesticide Root Zone Model - Ground Water (PRZM GW) m odel version 1.07 (Screening Concentration I n Ground Water) and surface water using the Pesticide Root Zone Model/Exposure Analy sis Modeling Sy stem (PRZM/EXAMS) model . The proposed use on apples carries the maximum single and annual application rates for all currentl y registered uses (0.375 lb ai/ A ). Previous estimates of sulfentrazone residues in drinking water were done separatel y for parent and the 3 - carbox yl ic acid sulfentrazone degra date. Sulfentrazone and 3 - carbox yl ic acid sulfentrazone have a potential to reach both surface and ground waters that may be used as drinking water sources. This revised assessment has now taken a total toxic residues (TTR) approach to assessing exposure , instead of providing values for each compound individually . For surface water, the highest acute (peak) sulfentrazone value is 37.3 ppb and the 10 - y ea r average value is 5. 3 ppb. For ground water, the h ighest dail y value (peak) sulfentrazone value is 134 ppb and the post - breakthrough - average value is 98 ppb. EDWCs of 0. 134 ppm and 0.0 98 ppm were used in the acute and chronic anal ys es, respectivel y. **Table 2. Estimated Tier 1 Concentrations of Sulfentrazone and 3 -**  **Carboxylic Acid Sulfentrazone in**  **Drinking Water Due to the Use of Sulfentrazone**  **.**

Scenario Surface Water (ug/L) Groundwater (ug/L) Ac ute Chronic Ac ute Chronic FL Sugarcane 37.3 3.2 - - LA Corn 31.3 5.3 - - Delmarva Sw. corn - - 134 98 

## IV **. DEEM**  **- FCID Program and Consumption Information**  Sulfentrazone acute and chronic dietary exposure assessments were conducted using the DEEM FCID, Version 3.16, which incorporates 2003 - 2008 consumption data from USDA’s NHANES/WWEI A. The data are based on the reported consumption of more than 20,000 individuals over two non - consecutive survey day s. Foods “as consumed” (e.g., apple pie) are

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## linked to EPA - defined food commodities (e.g., apples, peeled fruit - cooked; fresh or N/S; baked; or wheat flour - cooked ; fresh or N/S, baked) using publicl y available recipe translation files developed jointly

by USDA/ARS and EPA. For chronic exposure assessment, consumption data are averaged for the entire U.S. population and within population subgroups. However, for ac ute exposure assessment, consumption data are retained as individual consumption events. Based on anal ys is of the 2003 - 2008 WWEI A consumption data, which took into account dietary patterns and survey

respondents, HED concluded that it is most appropriate to report risk for the following population subgroups: the general U.S. population, all infants (<1 y ear old), children 1 - 2, children 3 - 5, children 6 - 12, y outh 13 - 19, adults 20 - 49, females 13 - 49, and adults 50 - 99 ye ars old. For a chronic dietary

exposure assessment, an estimate of the residue level in each food or food form (e.g., orange or orange juice) on the food commodity residue list is multiplied by the average dail y consumption estimate for that food/food form to produce a residue intake estimate. The resulting residue intake estimate for each food/food form is summed with the residue intake estimates for all other food/food forms on the commodity residue list to arrive at the total average estimated exposure. Exposure is expressed in mg/kg bod y we ig ht/day and as a percent of the cPAD. This procedure is performed for each population subgroup. For an acute exposure assessment, individual one - day food consumption data are used on an individual - by - individual basis. The reported consumption amounts o f each food item can be multiplied by

a residue point estimate and summed to obtain a total daily pesticide exposure for a deterministic exposure assessment, or “matched” in multiple random pairings with residue values and then summed in a probabilistic as sessment. The resulting distribution of exposures is expressed as a percentage of the aPAD on both a user (i.e., onl y those who reported eating relevant commodities/food forms) and a per - capita (i.e., those who reported eating the relevant commodities as well as those who did not) basis. In accordance with HED policy, per capita exposure and risk are reported for anal ys es performed at all levels of refinement. However, for deterministic assessments, any significant differences in user vs. per capita expo sure and risk are specificall y identified and noted in the risk assessment. **V. Toxicological Information**  The RAB1 toxicologists have reevaluated the sulfentrazone database and updated the endpoints as necessary . The toxicological endpoints selected for sulfentrazone are summarized below in Table 3 .

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Page 6 of 21 **Table 3**  **. Summary of Toxicological Doses and Endpoints for Sulfentrazone for Use in Hum an**  **- Health Risk**  **Assessments.** Exposure Scenario Point of

Departure Uncertainty/

FQPA Safety Factors RfD, PAD, Level

of Concern for Risk Assessment Study and Toxicological Effects Acute Dietary (Females 13 - 49) NOAEL =

14 mg/kg/day UF A 

### = 10X

UF H 

### = 10X FQPA SF = 1X aRfD = aPAD =

0.14 mg/kg/day Two - Gen . Reproductive Toxicity Study

– Rat .

Offspring Toxicity LOAEL = 33 (M) and 40 (F) mg/kg/day based on reduced prenatal viability (fetal & litter), reduced litter size, increased no. of stillborn pups, reduced pup and litter postnatal survival , and decreased pup body weights throughout lactation . Acute Dietary (General population including infants and children) NOAEL =

250 mg/kg/day UF A 

### = 10X

UF H 

### = 10X FQPA SF = 1X aRfD = aPAD =

2.5 mg/kg/day Acute - Neurotoxicity Study

– Rat .

LOAEL = 750 mg/kg/day based on increased incidence of clinical signs and FOB parameters and decre ased motor activity. Chronic Dietary (all populations) NOAEL =

14 mg/kg/day UF A 

### = 10X

UF H 

### = 10X FQPA SF = 1X cRfD = cPAD =

0.14 mg/kg/day Two - Gen . Reproductive Toxicity Study

– Rat .

Offspring Toxicity LOAEL = 33 (M) and 40 (F) mg/kg/day based on reduced prenatal viability (fetal & litter), reduced litter size, increased no. of stillborn pups, reduced pup and litter postnatal survival , and decreased pup body weights throughout lactation . Cancer (oral, dermal, inhalation) **Classification:** S ulfentrazone is classified as “not likely to be carcinogenic to humans.” NOAEL = no - observed adverse - effect level. LOAEL = lowest - observed adverse - effect level. UF = uncertainty factor. UF A 

### = extrapolation from animal to human (interspecies). UF H 

### = potential variation in sensitivity among members of the human population (intraspecies). UF L 

### = extrapolation for use of a LOAEL in the absence of a NOAEL. FQPA SF = FQPA Safety Factor. PAD = population - adjusted dose (a = acute, c = chronic). RfD = r eference dose. MOE = margin of exposure, LOC = level of concern. 

## V **I .**  **Results/Discussion** For acute and chronic assessments, HED is concerned when dietary risk exceeds 100% of the PAD. The DEEM - FCID anal ys es estimate the dietary exposure of the U.S. po pulation and various population subgroups. The results reported in Table 4 are for the general U.S. population, all infants (<1 y ear old), children 1 - 2 y ears old, children 3 - 5 y ears old, children 6 - 12 ye ars old, y outh 13 - 19 y ears old, females 13 - 49 y ears old, adults 20 - 49 y ears old, and adults 50 - 99 y ears old. The resulting acute food plus water risk estimates are below HED ’s level of concern (<100% aPAD) at the 95 th 

## percentile of the exposure distribution for the general U . S . population ( < 1 % aPAD), and all population subgroups . T he population subgroup with the greatest acute risk estimate was females 13 to 49 y ears , which utilize d 7 % of the aPAD. The population with the greatest acute exposure estimate was all infants (<1 y ear old) (0.026754 mg/kg/day ; 1 .1 % a PAD) . The resulting chronic risk estimates are also below HED’s level of concern for the U.S. general population (<100% c PAD), and all population subgroups. The most highly exposed population was children 1 - 2 y ears old , with a chronic risk estimated that utilized 7 % of the cPAD.

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Page 7 of 21 **Table 4**  **. Summary of Acute and Chronic Dietary (Food and Drinking Water)**  **Exposure and Risk for Sulfentrazone.**  **1** 

### Population Subgroup 

### 95 th 

### Percentile cPAD (mg/kg/day) Exposure

(mg/kg/day) %cPAD aPAD (mg/kg/day) Exposure

(mg/kg/day) %aPAD General U.S. Population

2.5 0.011114 <1.0

0.14 0.003973 2.8 **All Infants (<1 year old)** 0.026754 1. 1 0.008577 6.1 **Children 1 -**  **2 years old** 0.022692 <1.0 **0.009881 7.1**  Children 3 - 5 years old 0.017984 <1.0 0.007889 5.6 Children 6 - 12 years old 0.011833 <1.0 0.004817 3.4 Youth 13 - 19 years old 0.008607 <1.0 0.003225 2.3 Adults 20 - 49 years old 0.009187 <1.0 0.003498 2.5 Adults 50 - 99 years old 0.008301 <1.0 0.003314 2.4 **Females 13 -**  **49 years old** 0.14 **0.009363 6.7**  0.003450 2.5 1 

### The population s with the greatest risk estimate s are bolded. 

## VI **I .**  **Characterization of Inputs/Outputs** The unrefined acute and chronic analy ses assumed tolerance - level residues for all commodities , 100% CT , and DEEM (ver. 7.81) default processing factors (as necessary ) . These analy ses are considered to be conservative and could be refined through the use of anticipated - residue estimates (ARs) for all commodities, %CT data for registered commodities, and empirical processing factors. In order to provide a comparison for reference, the dietary results for the anal ys is of food exposures (only ) are presented in attachments 5 & 6. **VII I**  **. Conclusions**  The acute and chronic dietary exposure and risk estimates for sulfentrazone are below HED’s level of concern. For acute food and drinking water exposure s , although all infants (<1 y ear old) had the greatest exposure estimate (0.026754 mg/kg/day ; 1% a PAD) , females 13 to 49 y ears old had the greatest ris k estimate ( 0.009363 mg/kg/day ; 7 % of the aPAD) . For food and drinking water chronic exposure, the most highly exposed population subgroup was children 1 - 2 y ears old , with an estimated risk of 7 % of the cPAD. The acute and chronic dietary exposure assess ments support the proposed new use of sulfentrazone. **Attachments** Attachment 1 : DEEM - FCI D A cute Residue File. Attachment 2: DEEM - FCI D Acute Exposure Estimates for the General Population I ncluding Infants and

Children. Attachment 3 : DEEM - FCI D Chronic Residue File. Attachment 4 : DEEM - FCI D Chronic Exposure Estimates. Attachment 5: DEEM - FCI D Acute Exposure Estimates for the General Population I ncluding Infants and

Children (food only ). Attachment 6: DEEM - FCI D Chronic Exposure Estimates (food only ). cc: G. Kramer (RAB1) RDI: DESAC ( 5 / 15 /14) G.F. Kramer:S10957:PY - S:(703)305 - 5079:7509P:RAB1

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## Attachment **1 :**  **DEEM -**  **FCID A**  **cute R**  **esidue F**  **ile .**  Filename: C: \ Users \ gkramer \ Documents \ Gk \ ##Sulfentrazone \ 129081 - ACUTE__30 APR 2014.R08 Chemical: Sulfentrazone RfD(Chronic): .14 mg/kg bw/day NOEL(Chronic): 14 mg/kg bw/day RfD(Acute): 2.5 mg/kg bw/day NOEL(Acute): 250 mg/kg bw/day Date created/last modified: 04 - 3 0 - 2014/16:06:50 Program ver. 3.16, 03 - 08 - d

----------------------------------------------------------------------------------- EPA Crop Def Res Adj.Factors Comment Code Grp Commodity Name (ppm) #1 #2

---------- ---- ------------------------------- ---------- ------ ------ ------- 0101190000 1AB Horseradish 0.200000 1.000 1.000 0101388000 1AB Turnip, roots 0.150000 1.000 1.000 0103015000 1CD Arrowroot, flour 0.150000 1.000 1.000 0103015001 1CD Arrowroot, flour - babyfood 0.150000 1.000 1.000 0103017000 1CD Artichoke, Jerusalem 0.150000 1.000 1.000 0103082 000 1CD Cassava 0.150000 1.000 1.000 0103082001 1CD Cassava - babyfood 0.150000 1.000 1.000 0103139000 1CD Dasheen, corm 0.150000 1.000 1.000 0103166000 1CD Ginger 0.150000 1.000 1.000 0103166001 1CD Ginger - babyfood 0.150000 1.000 1.000 0103167000 1CD Ginger, dried 0.150000 1.000 1.000 0103296000 1C Potato, chips 0.150000 1.000 1.000 0103297000 1C Potato, dry (granules/ flakes) 0.150000 6.500 1.000 0103297001 1C Potato, dry (granules/ flakes) - b 0.150000 6.500 1.000 0103298000 1C Potato, f lour 0.150000 6.500 1.000 0103298001 1C Potato, flour - babyfood 0.150000 6.500 1.000 0103299000 1C Potato, tuber, w/peel 0.150000 1.000 1.000 0103299001 1C Potato, tuber, w/peel - babyfood 0.150000 1.000 1.000 0103300000 1C Potato, tuber, w/o peel 0.150000 1.000 1.000 0103300001 1C Potato, tuber, w/o peel - babyfood 0.150000 1.000 1.000 0103366000 1CD Sweet potato 0.150000 1.000 1.000 0103366001 1CD Sweet potato - babyfood 0.150000 1.000 1.000 0103371000 1CD Tanier, corm 0.150000 1.000 1.000 0103387000 1CD Turmeric 0.150000 1.000 1.000 0103406000 1CD Yam, tr ue 0.150000 1.000 1.000 0103407000 1CD Yam bean 0.150000 1.000 1.000 0402322000 4B Rhubarb 0.150000 1.000 1.000 0501061000 5A Broccoli 0.200000 1.000 1.000 0501061001 5A Broccoli - babyfood 0.200000 1.000 1.000 0501062000 5A Broccoli, Chinese 0.200000 1.000 1.000 0501064000 5A Brussels sprouts 0.200000 1.000 1.00 0 0501069000 5A Cabbage 0.200000 1.000 1.000 1E0631

Full comment: 1E06311 0501071000 5A Cabbage, Chinese, napa 0.200000 1.000 1.000 1E0631

Full comment: 1E06311 0501072000 5A Ca bbage, Chinese, mustard 0.200000 1.000 1.000 1E0631

Full comment: 1E06311 0501083000 5A Cauliflower 0.200000 1.000 1.000 0501196000 5A Kohlrabi 0.200000 1.000 1.000 050 2063000 5B Broccoli raab 0.400000 1.000 1.000 0502070000 5B Cabbage, Chinese, bok choy 0.400000 1.000 1.000 1E0631

Full comment: 1E06311 0502117000 5B Collards 0.400000 1.000 1.000 0502194000 5B Kale 0.400000 1.000 1.000 0502229000 5B Mustard greens 0.400000 1.000 1.000 0502318000 5B Rape gree ns 0.400000 1.000 1.000 0502389000 5B Turnip, greens 0.600000 1.000 1.000 0600347000 6 Soybean, seed 0.150000 1.000 1.000 0600349000 6 Soybean, soy milk 0.150000 1.000 1.000 0600349001 6 Soybean, soy milk - babyfood or in 0.150000 1.000 1.000 0600350000 6 Soybean, oil 0.150000 1.000 1.000 0600350001 6 Soybean, oil - babyfood 0.150000 1.000 1.000 0601043000 6A Bean, snap, succulent 0.150000 1.000 1.000 0601043001 6A Bean, snap, succulent - babyfood 0.150000 1.000 1.000 0601257000 6A Pea, edible podded, succulent 0.150000 1.000 1.000 0602031000 6B Bean, b road, succulent 0.150000 1.000 1.000 0602033000 6B Bean, cowpea, succulent 0.150000 1.000 1.000 0602037000 6B Bean, lima, succulent 0.150000 1.000 1.000 0602255000 6B Pea, succulent 0.150000 1.000 1.000 0602255001 6B Pea, succulent - babyfood 0.150000 1.000 1.000 0602259000 6B Pea, pigeon, succulent 0.150000 1.000 1.000

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Page 9 of 21 0603030000 6C Bean, black, seed 0.150000 1.000 1.00 0 2F0639

Full comment: 2F06391 0603032000 6C Bean, broad, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603034000 6C Bean, cowpea, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603035000 6C Bean, great northern, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603036000 6C Bean, kidney, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603038000 6C Bean, lima, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603039000 6C Bean, mung, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603040000 6C Bean, navy, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603041000 6C Bean, pink, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603042000 6C Bean, pinto, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603098000 6C Chickpea, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603098001 6C Chickpea, seed - babyfood 0.150000 1.00 0 1.000 2F0639

Full comment: 2F06391 0603099000 6C Chickpea, flour 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603182000 6C Guar, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603182001 6C Guar, seed - babyfood 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603203000 6C Lentil, seed 0.150000 1.000 1.000 2F0639

Full comment: 2 F06391 0603256000 6C Pea, dry 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603256001 6C Pea, dry - babyfood 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603258000 6C Pea, pigeon, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603348000 6C Soybean, flour 0.150000 1.000 1.000 0603348001 6C Soybean, flour - babyfood 0.150000 1.000 1.000 0801374000 8A Tomatillo 0.150000 1.000 1.000 0801375000 8A Tomato 0.150000 1.000 1.000 0801375001 8A Tomato - babyfood 0.150000 1.000 1.000 0801376000 8A Tomato, p aste 0.150000 5.400 1.000 0801376001 8A Tomato, paste - babyfood 0.150000 5.400 1.000 0801377000 8A Tomato, puree 0.150000 3.300 1.000 0801377001 8A Tomato, puree - babyfood 0.150000 3.300 1.000 0801378000 8A Tomato, dried 0.150000 14.300 1.000 0801378001 8A Tomato, dried - babyfood 0.150000 14.300 1.000 0801379000 8A Tomato, juice 0.150000 1.500 1.000 0801380000 8A Tomato, Tree 0.150000 1.000 1.000 0802148000 8BC Eggplant 0.150000 1.000 1.000 0802234000 8BC Okra 0.150000 1.000 1.000 0802270000 8B Pepper, bell 0.150000 1.000 1.000 0802270001 8B Pepper, bell - babyfood 0.150000 1.000 1.000 0802271000 8B Pepper, bell, dried 0.150000 1.000 1.000 0802271001 8B Pepper, bell, dried - babyfood 0.150000 1.000 1.000 0802272000 8BC Pepper, nonbell 0.150000 1.000 1.000 0802272001 8BC Pepper, nonbell - babyfood 0.150000 1.000 1.000 0802273000 8BC Pepper, nonbell, dried 0.150000 1.000 1.00 0 0901075000 9A Cantaloupe 0.150000 1.000 1.000 0901187000 9A Honeydew melon 0.150000 1.000 1.000 0901399000 9A Watermelon 0.150000 1.000 1.000 0901400000 9A Water melon, juice 0.150000 1.000 1.000 1001106000 10A Citron 0.150000 1.000 1.000 1001107000 10A Citrus hybrids 0.150000 1.000 1.000 1001108000 10A Citrus, oil 0.150000 1.000 1.000 1001240000 10A Orange 0.150000 1.000 1.000 1001241000 10A Orange, juice 0.150000 1.800 1.000 1001241001 10A Orange, j uice - babyfood 0.150000 1.800 1.000 1001242000 10A Orange, peel 0.150000 1.000 1.000 1001369000 10A Tangerine 0.150000 1.000 1.000

### Sulfentrazone Dietary Exposure and Risk Assessment D 417172

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Page 10 of 21 1001370000 10A Tangerine, juice 0.150000 2.300 1.000 1002197000 10B Kumquat 0.150000 1.000 1.000 1002199000 10B Lemon 0.150000 1.000 1.000 1002200000 10B Lemon, juice 0.150000 2.000 1.000 1002200001 10B Lemon, juice - babyfood 0.150000 2.000 1.000 1002201000 10B Lemon, peel 0.150000 1.000 1.000 1002206000 10B Lime 0.150000 1.000 1.000 1002207000 10B Lime, j uice 0.150000 2.000 1.000 1002207001 10B Lime, juice - babyfood 0.150000 2.000 1.000 1003180000 10C Grapefruit 0.150000 1.000 1.000 1003181000 10C Grapefruit, juice 0.150000 2.100 1.000 1003307000 10C Pummelo 0.150000 1.000 1.000 1100007000 11 Apple, fruit with peel 0.150000 1.000 1.000 1100008000 11 Apple, peeled fruit 0.150000 1.000 1.00 0 1100008001 11 Apple, peeled fruit - babyfood 0.150000 1.000 1.000 1100009000 11 Apple, dried 0.150000 8.000 1.000 1100009001 11 Apple, dried - babyfood 0.150000 8.000 1.000 1100010000 11 Apple , juice 0.150000 1.300 1.000 1100010001 11 Apple, juice - babyfood 0.150000 1.300 1.000 1100011000 11 Apple, sauce 0.150000 1.000 1.000 1100011001 11 Apple, sauce - babyfood 0.150000 1.000 1.000 1301055000 13A Blackberry 0.150000 1.000 1.000 1301056000 13A Blackberry, juice 0.150000 1.000 1.000 1301056001 13A Blackberry, juice - babyfood 0.150000 1.000 1.000 1301058000 13A Boysenberry 0.150000 1.000 1.000 1301208000 13A Loganberry 0.150000 1.000 1.000 1301320000 13A Raspberry 0.150000 1.000 1.000 1301320001 13A Raspberry - babyfood 0.150000 1.000 1.000 1301321000 13A Raspberry, juice 0.150000 1.000 1.000 1301321001 13A Raspberry, juice - babyfood 0.150000 1.000 1.000 1302057000 13B Blueberry 0.150000 1.000 1.000 1302057001 13B Blueberry - babyfood 0.150000 1.000 1.000 1302136000 13B Currant 0.150000 1.000 1.000 1302137000 13B Currant, dried 0.150000 1.000 1.000 1302149000 13B Elderberry 0.150000 1.000 1.000 1302174000 13B Gooseberry 0.150000 1.000 1.000 1302191000 13B Huckleb erry 0.150000 1.000 1.000 1303227000 13C Mulberry 0.150000 1.000 1.000 1304175000 13D Grape 0.150000 1.000 1.000 1304176000 13D Grape, juice 0.150000 1.200 1.000 1304176001 13D Grape, juice - babyfood 0.150000 1.200 1.000 1304179000 13D Grape, wine and sherry 0.150000 1.000 1.000 1304195000 13D Kiwifruit, fuzzy 0.150000 1.000 1.00 0 1307130000 13G Cranberry 0.150000 1.000 1.000 1307130001 13G Cranberry - babyfood 0.150000 1.000 1.000 1307131000 13G Cranberry, dried 0.150000 1.000 1.000 1307132000 13G Cranb erry, juice 0.150000 1.100 1.000 1307132001 13G Cranberry, juice - babyfood 0.150000 1.100 1.000 1307359000 13G Strawberry 0.150000 1.000 1.000 1307359001 13G Strawberry - babyfood 0.150000 1.000 1.000 1307360000 13G Strawberry, juice 0.150000 1.000 1.000 1307360001 13G Strawberry, juice - babyfood 0.150000 1.000 1.000 1400003000 14 Almond 0.150000 1.000 1.000 1400003001 14 Almond - babyfood 0.150000 1.000 1.000 1400004000 14 Almond, oil 0.150000 1.000 1.000 1400004001 14 Almond, o il - babyfood 0.150000 1.000 1.000 1400059000 14 Brazil nut 0.150000 1.000 1.000 1400068000 14 Butternut 0.150000 1.000 1.000 1400081000 14 Cashew 0.150000 1.000 1.000 1400092000 14 Chestnut 0.150000 1.000 1.000 1400155000 14 Hazelnut 0.150000 1.000 1.000 1400156000 14 Hazelnut, oil 0.150000 1.000 1.000 1400185000 14 Hickory nut 0.150000 1.000 1.000 1400213000 14 Macadamia nut 0.150000 1.000 1.000 1400269000 14 Pecan 0.150000 1.000 1.000 1400282000 14 Pistach io 0.150000 1.000 1.000 1400391000 14 Walnut 0.150000 1.000 1.000 1500025000 15 Barley, pearled barley 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500025001 15 Barley, pearled barley - babyfood 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500026000 15 Barley, flour 0.100000 1.000 1.000 Inadve

### Sulfentrazone Dietary Exposure and Risk Assessment D 417172

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Page 11 of 21 Full comment: Inadvertent tol. 150 0026001 15 Barley, flour - babyfood 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500027000 15 Barley, bran 0.150000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500065 000 15 Buckwheat 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500066000 15 Buckwheat, flour 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500120000 15 Corn, field, flour 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 1500120001 15 Corn, field, flour - babyfood 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 1500121000 15 Corn, field, meal 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 1500121001 15 Corn, field, meal - babyfood 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 1500122000 15 Corn, field, bran 0.15 0000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500123000 15 Corn, field, starch 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 1500123001 15 Corn, field, starch - babyfood 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 1500124000 15 Corn, field, syrup 0.150000 1.500 1.000 2F0639

Full comment: 2F06391 1500124001 15 Corn, field, syrup - babyfood 0.150000 1.500 1.000 2F0639

Full comment: 2F06391 1500125000 15 Corn, field, oil 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 1500125001 15 Corn, field, oil - babyfood 0.150000 1.000 1.000 2F0639

Full comment: 2F0 6391 1500126000 15 Corn, pop 0.100000 1.000 1.000 2F0639

Full comment: 2F06391 1500226000 15 Millet, grain 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 15002310 00 15 Oat, bran 0.150000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500232000 15 Oat, flour 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500232001 15 Oat, flour - babyfood 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500233000 15 Oat, groats/rolled oats 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500233001 15 Oat, groats/rolled oats - babyfood 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500323000 15 Rice, white 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500323001 15 Ric e, white - babyfood 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500324000 15 Rice, brown 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500324001 15 Rice, b rown - babyfood 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500325000 15 Rice, flour 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500325001 15 Rice, flour - babyfood 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500326000 15 Rice, bran 0.150000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500326001 15 Rice, bran - baby food 0.150000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500328000 15 Rye, grain 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500329000 15 Rye, flour 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500344000 15 Sorghum, grain 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500345000 15 Sorghum, syrup 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500381000 15 Triticale, flour 0.150000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500381001 15 Triticale, flour - babyfood 0.150000 1.000 1.000 Inadve

### Sulfentrazone Dietary Exposure and Risk Assessment D 417172

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Page 12 of 21 Full comment: Inadvertent tol. 1500401000 15 Wheat, grain 0.150000 1.000 1.000 1500401001 15 Wheat, grain - babyfood 0.150000 1.000 1.000 1500402000 15 Whe at, flour 0.150000 1.000 1.000 1500402001 15 Wheat, flour - babyfood 0.150000 1.000 1.000 1500403000 15 Wheat, germ 0.150000 1.000 1.000 1500404000 15 Wheat, bran 0.150000 1.000 1.000 1500405000 15 Wild rice 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1800002000 18 Alfalfa, seed 0.150000 1.000 1.000 2001163000 20A Flax seed, oil 0.150000 1.000 1.000 2002330000 20B Safflower, oil 0.200000 1.000 1.000 2002330001 20B Safflower, oil - babyfood 0.200000 1.000 1.000 2002364000 20B Sunflower, seed 0.200000 1.000 1.000 2002365000 20B Sunflower, oil 0.200000 1.000 1.000 2002365001 20B Sunflower, oil - babyfood 0.200000 1.000 1.000 8601000000 86A Water, direct, all sources 0.134000 1.000 1 .000 8602000000 86B Water, indirect, all sources 0.134000 1.000 1.000 9500019000 O Asparagus 0.150000 1.000 1.000 2E0650

Full comment: 2E06500 9500177000 O Grape, leaves 0.15 0000 1.000 1.000 9500178000 O Grape, raisin 0.150000 4.300 1.000 9500263000 O Peanut 0.200000 1.000 1.000 0F0611

Full comment: 0F06116 9500264000 O Peanut, butter 0.200000 1.890 1.000 0F0611

Full comment: 0F06116 9500265000 O Peanut, oil 0.200000 1.000 1.000 0F0611

Full comment: 0F06116 9500275000 O Peppermint 0.300000 1.000 1.000 1E0631

Full comment: 1E06311 9500276000 O Peppermint, oil 0.300000 1.000 1.000 1E0631

Full comment: 1E06311 9500352000 O Spearmint 0.300000 1.000 1.000 1E0631

Full comment: 1E06311 9500353000 O Spearmint, oil 0.300000 1.000 1.000 1E0631

Full comment: 1E06311 9500362000 O Sugarcane, sugar 0.150000 1.000 1.000 9500362001 O Sugarcane, su gar - babyfood 0.150000 1.000 1.000 9500363000 O Sugarcane, molasses 0.200000 1.000 1.000 9500363001 O Sugarcane, molasses - babyfood 0.200000 1.000 1.000

### Sulfentrazone Dietary Exposure and Risk Assessment D 417172

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Page 13 of 21 

## Attachment **2 :**  **DEEM -**  **FCID A**  **cute E**  **xposure E**  **stimates for the General Population including Infants**  **and Children .**  **1** US EPA Ver. 3.18, 03 - 08 - d DEEM - FCID ACUTE Analysis for SULFENTRAZONE NHANES 2003 - 2008 2 - Day Residue file: 129081 - ACUTE__30 APR 2014.R08 Adjustment factor #2 NOT used. Analysis Date: 04 - 30 - 2014/16:13:22 Residue file dated: 04 - 30 - 2014/16:06:50 NOEL (Acute) = 250.000000 mg/kg body - wt/day RAC/FF intake summed over 24 hours Run Comment: ""

===================================== ========================================== Summary calculations -- per capita:

--- 95th Percentile ---- --- 99th Percentile ---- --- 99.9th Percentile ---- Exposure % aRfD MOE Exposure % aRfD MOE Exposure % aRfD MOE

---------- ------- -------- ---------- ------- -------- ---------- ------- -------- Total US Population: 0.011114 0.44 22494 0.017876 0.72 13985 0.030344 1.21 8238 All Infants: 0.026754 1.07 9344 0.036226 1.45 6901 0.046 693 1.87 5354 Female 13 - 50: 0.009350 0.37 26738 0.013001 0.52 19228 0.017681 0.71 14139 Children 1 - 2: 0.022692 0.91 11017 0.034157 1.37 7319 0.054184 2.17 4613 Children 3 - 5: 0.017984 0.72 1 3901 0.025050 1.00 9980 0.031751 1.27 7873 Children 6 - 12: 0.011833 0.47 21127 0.018540 0.74 13484 0.026966 1.08 9271 Youth 13 - 19: 0.008607 0.34 29046 0.012752 0.51 19604 0.017460 0.70 14318 Adults 20 - 49: 0.009187 0.37 27211 0.013200 0.53 18940 0.018245 0.73 13702 Adults 50 - 99: 0.008301 0.33 30116 0.011532 0.46 21678 0.017442 0.70 14333 Female 13 - 49: 0.009363 0.37 2 26699 0.013010 0.52 19215 0.017647 0.71 14166 1 

### The a PAD for the general population including infants and children = 2.5 mg/kg bw/day . The a PAD for f em ales 13 - 49 years old = 0.1 4 mg/kg bw/day. 2 

### This value was calculated by DEEM using an a PAD of 2.5 mg/kg bw/day. The % a PAD reported in Table 4 wa s adjusted to account for the lower a PAD (0.1 4 mg/kg bw/day) for females 13 - 49 years old using the follow ing formula: % aPAD = (Exposure/aPAD)*100% = ( 0.009363 /0.1 4 )*100% = 6.7 % .

### Sulfentrazone Dietary Exposure and Risk Assessment D 417172

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## Attachment **3 :**  **DEEM -**  **FCID C**  **hronic R**  **esidue F**  **ile .**  Filename: C: \ Users \ gkramer \ Documents \ Gk \ ##Sulfentrazone \ 129081 - CHRON__30 APR 2014.R08 Chemical: Sulfentrazone RfD(Chronic): .14 mg/kg bw/day NOEL(Chronic): 14 mg/kg bw/day RfD(Acute): 2.5 mg/kg bw/day NOEL(Acute): 250 mg/kg bw/day Date created/last modified: 04 - 30 - 2014/16:08:32 Program ver. 3.16, 03 - 08 - d

----------------------------------------------------------------------------------- EPA Crop Def Res Adj.Factors Comment Code Grp Commodity Name (ppm) #1 #2

---------- ---- ------------------------------- ---------- ------ ------ ------- 0101190000 1 AB Horseradish 0.200000 1.000 1.000 0101388000 1AB Turnip, roots 0.150000 1.000 1.000 0103015000 1CD Arrowroot, flour 0.150000 1.000 1.000 0103015001 1CD Arrowroot, flour - baby food 0.150000 1.000 1.000 0103017000 1CD Artichoke, Jerusalem 0.150000 1.000 1.000 0103082000 1CD Cassava 0.150000 1.000 1.000 0103082001 1CD Cassava - babyfood 0.150000 1.000 1.000 0103139000 1CD Dasheen, corm 0.150000 1.000 1.000 0103166000 1CD Ginger 0.150000 1.000 1.000 0103166001 1CD Ginger - babyfood 0.150000 1.000 1.000 0103167000 1CD Ginger, dried 0.150000 1.000 1.000 0103296000 1C Potato, chips 0.150000 1.000 1.000 0103297000 1C Potato, dry (granules/ flakes) 0.150000 6.500 1.000 0103297001 1C Potato, dry (granul es/ flakes) - b 0.150000 6.500 1.000 0103298000 1C Potato, flour 0.150000 6.500 1.000 0103298001 1C Potato, flour - babyfood 0.150000 6.500 1.000 0103299000 1C Potato, tuber, w/peel 0.150000 1.000 1.000 0103299001 1C Potato, tuber, w/peel - babyfood 0.150000 1.000 1.000 0103300000 1C Potato, tuber, w/o peel 0.150000 1.000 1.000 0103300001 1C Potato, tuber, w/o peel - babyfood 0.150000 1.000 1.000 01033660 00 1CD Sweet potato 0.150000 1.000 1.000 0103366001 1CD Sweet potato - babyfood 0.150000 1.000 1.000 0103371000 1CD Tanier, corm 0.150000 1.000 1.000 0103387000 1CD Turmeric 0.150000 1.000 1.000 0103406000 1CD Yam, true 0.150000 1.000 1.000 0103407000 1CD Yam bean 0.150000 1.000 1.000 0402322000 4B Rhubarb 0.150000 1.000 1.000 0501061000 5A Broccoli 0.200000 1.000 1.000 0501061001 5A Broccoli - babyfood 0.200000 1.000 1.000 0501062000 5A Broccoli, Chinese 0.200000 1.000 1.000 0501064000 5A Brussels sprouts 0.200000 1.000 1.000 0501069000 5A Cabbage 0.200000 1.000 1.000 1E0631

Full comment: 1E06311 0501071000 5A Cabbage, Chinese, n apa 0.200000 1.000 1.000 1E0631

Full comment: 1E06311 0501072000 5A Cabbage, Chinese, mustard 0.200000 1.000 1.000 1E0631

Full comment: 1E06311 0501083000 5A Cauliflower 0.2000 00 1.000 1.000 0501196000 5A Kohlrabi 0.200000 1.000 1.000 0502063000 5B Broccoli raab 0.400000 1.000 1.000 0502070000 5B Cabbage, Chinese, bok choy 0.400000 1.000 1.000 1E0631

Full comment: 1E06311 0502117000 5B Collards 0.400000 1.000 1.000 0502194000 5B Kale 0.400000 1.000 1.000 0502229000 5B Mustard greens 0.400000 1.000 1.000 0502318000 5B Rape greens 0.400000 1.000 1.000 0502389000 5B Turnip, greens 0.600000 1.000 1.000 0600347000 6 Soybean, seed 0.150000 1.000 1.000 0600349000 6 Soybean, soy milk 0.150000 1.000 1.000 0600349001 6 Soybean, soy milk - babyfood or in 0.150000 1.000 1.000 0600350000 6 Soybean, oil 0.150000 1.000 1.000 0600350001 6 Soybean, oil - babyfood 0.150000 1.000 1.000 0601043000 6A Bean, snap, succulent 0.150000 1.000 1.000 0601043001 6A Bean, snap, succulent - babyfood 0.150000 1.000 1.000 0601257000 6A Pea, edib le podded, succulent 0.150000 1.000 1.000 0602031000 6B Bean, broad, succulent 0.150000 1.000 1.000 0602033000 6B Bean, cowpea, succulent 0.150000 1.000 1.000 0602037000 6B Bean, lima, succulent 0.150000 1.000 1.000 0602255000 6B Pea, succulent 0.150000 1.000 1.000 0602255001 6B Pea, succulent - babyfood 0.150000 1.000 1.000

### Sulfentrazone Dietary Exposure and Risk Assessment D 417172

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Page 15 of 21 0602259000 6B Pea, pigeon, succulent 0.150000 1.000 1.000 0603030000 6C Bean, black, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603032000 6C Bean, broad, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603034000 6C Bean , cowpea, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603035000 6C Bean, great northern, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603036000 6C Bean, kidney, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603038000 6C Bean, lima, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603039000 6C Bean, mung, seed 0.150000 1. 000 1.000 2F0639

Full comment: 2F06391 0603040000 6C Bean, navy, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603041000 6C Bean, pink, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603042000 6C Bean, pinto, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603098000 6C Chickpea, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603098001 6C Chickpea, seed - babyfood 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603099000 6C Chickpea, flour 0.150000 1.000 1.000 2F0639

Full comme nt: 2F06391 0603182000 6C Guar, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603182001 6C Guar, seed - babyfood 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603203000 6C Lentil, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603256000 6C Pea, dry 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603256001 6C Pea, dry - babyfoo d 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603258000 6C Pea, pigeon, seed 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 0603348000 6C Soybean, flour 0.1 50000 1.000 1.000 0603348001 6C Soybean, flour - babyfood 0.150000 1.000 1.000 0801374000 8A Tomatillo 0.150000 1.000 1.000 0801375000 8A Tomato 0.150000 1.000 1.000 08 01375001 8A Tomato - babyfood 0.150000 1.000 1.000 0801376000 8A Tomato, paste 0.150000 5.400 1.000 0801376001 8A Tomato, paste - babyfood 0.150000 5.400 1.000 0801377000 8A Tomato, pur ee 0.150000 3.300 1.000 0801377001 8A Tomato, puree - babyfood 0.150000 3.300 1.000 0801378000 8A Tomato, dried 0.150000 14.300 1.000 0801378001 8A Tomato, dried - babyfood 0.150000 14.300 1.000 0801379000 8A Tomato, juice 0.150000 1.500 1.000 0801380000 8A Tomato, Tree 0.150000 1.000 1.000 0802148000 8BC Eggplant 0.150000 1.000 1.000 0802234000 8BC Okra 0.150000 1.000 1.000 0802270000 8B Pepper, bell 0.150000 1.000 1.000 0802270001 8B Pepper, bell - babyfood 0.150000 1.000 1.000 0802271000 8B Pepper, bell, dried 0.150000 1.000 1.000 0802271001 8B Pepper, bell, dried - babyfood 0.150000 1.000 1.000 0802272000 8BC Pepper, nonbell 0.150000 1.000 1.000 0802272001 8BC Pepper, nonbell - babyfood 0.150000 1.000 1.000 0802273000 8BC Pepper, nonbell, dried 0.150000 1.000 1.000 0901075000 9A Cantaloupe 0.150000 1.000 1.000 0901187000 9A Honeyde w melon 0.150000 1.000 1.000 0901399000 9A Watermelon 0.150000 1.000 1.000 0901400000 9A Watermelon, juice 0.150000 1.000 1.000 1001106000 10A Citron 0.150000 1.000 1.000 1001107000 10A Citrus hybrids 0.150000 1.000 1.000 1001108000 10A Citrus, oil 0.150000 1.000 1.000 1001240000 10A Orange 0.150000 1.000 1.00 0 1001241000 10A Orange, juice 0.150000 1.800 1.000 1001241001 10A Orange, juice - babyfood 0.150000 1.800 1.000 1001242000 10A Orange, peel 0.150000 1.000 1.000

### Sulfentrazone Dietary Exposure and Risk Assessment D 417172

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Page 16 of 21 1001369000 10A Tange rine 0.150000 1.000 1.000 1001370000 10A Tangerine, juice 0.150000 2.300 1.000 1002197000 10B Kumquat 0.150000 1.000 1.000 1002199000 10B Lemon 0.150000 1.000 1.000 1002200000 10B Lemon, juice 0.150000 2.000 1.000 1002200001 10B Lemon, juice - babyfood 0.150000 2.000 1.000 1002201000 10B Lemon, peel 0.150000 1.000 1.000 1002206000 10B Lime 0.150000 1.000 1.000 1002207000 10B Lime, juice 0.150000 2.000 1.000 1002207001 10B Lime, jui ce - babyfood 0.150000 2.000 1.000 1003180000 10C Grapefruit 0.150000 1.000 1.000 1003181000 10C Grapefruit, juice 0.150000 2.100 1.000 1003307000 10C Pummelo 0.150000 1.000 1.000 1100007000 11 Apple, fruit with peel 0.150000 1.000 1.000 1100008000 11 Apple, peeled fruit 0.150000 1.000 1.000 1100008001 11 Apple, peeled fruit - babyfood 0.150000 1.000 1.000 1100009000 11 Apple, dried 0.150000 8.000 1.000 1100009001 11 Apple, dried - babyfood 0.150000 8.000 1.000 1100010000 11 Apple, juice 0.150000 1.300 1.000 1100010001 11 Apple, juice - babyfood 0.150000 1.300 1.000 1100011000 11 Apple, sauce 0.150000 1.000 1.000 1100011001 11 Apple, sauce - babyfood 0.150000 1.000 1.000 1301055000 13A Blackberry 0.150000 1.000 1.000 1301056000 13A Blackberry, juice 0.150000 1.000 1.000 1301056001 13A Blackberry, juice - babyfood 0.150000 1.000 1.000 1301058000 13A Boysenberry 0.150000 1.000 1.00 0 1301208000 13A Loganberry 0.150000 1.000 1.000 1301320000 13A Raspberry 0.150000 1.000 1.000 1301320001 13A Raspberry - babyfood 0.150000 1.000 1.000 1301321000 13A Raspb erry, juice 0.150000 1.000 1.000 1301321001 13A Raspberry, juice - babyfood 0.150000 1.000 1.000 1302057000 13B Blueberry 0.150000 1.000 1.000 1302057001 13B Blueberry - babyfood 0.150000 1.000 1.000 1302136000 13B Currant 0.150000 1.000 1.000 1302137000 13B Currant, dried 0.150000 1.000 1.000 1302149000 13B Elderberry 0.150000 1.000 1.000 1302174000 13B Gooseberry 0.150000 1.000 1.000 1302191000 13B Huckleberry 0.150000 1.000 1.000 1303227000 13C Mulberry 0.150000 1.000 1.000 1304175000 13D Grape 0.150000 1.000 1.000 1304176000 13D Grape, juice 0.150000 1.200 1.000 1304176001 13D Grape, juice - babyfood 0.150000 1.200 1.000 1304179000 13D Grape, wine and sherry 0.150000 1.000 1.000 1304195000 13D Kiwifruit, fuzzy 0.150000 1.000 1.000 1307130000 13G Cranberry 0.150000 1.000 1.000 1307130001 13G Cranberry - babyfood 0.150000 1.000 1.000 1307131000 13G Cranberry, dried 0.150000 1.000 1.000 1307132000 13G Cranberry, juice 0.150000 1.100 1.000 1307132001 13G Cranber ry, juice - babyfood 0.150000 1.100 1.000 1307359000 13G Strawberry 0.150000 1.000 1.000 1307359001 13G Strawberry - babyfood 0.150000 1.000 1.000 1307360000 13G Strawberry, juice 0.150000 1.000 1.000 1307360001 13G Strawberry, juice - babyfood 0.150000 1.000 1.000 1400003000 14 Almond 0.150000 1.000 1.000 1400003001 14 Almond - babyfood 0.150000 1.000 1.00 0 1400004000 14 Almond, oil 0.150000 1.000 1.000 1400004001 14 Almond, oil - babyfood 0.150000 1.000 1.000 1400059000 14 Brazil nut 0.150000 1.000 1.000 1400068000 14 Butte rnut 0.150000 1.000 1.000 1400081000 14 Cashew 0.150000 1.000 1.000 1400092000 14 Chestnut 0.150000 1.000 1.000 1400155000 14 Hazelnut 0.150000 1.000 1.000 1400156000 14 Hazelnut, oil 0.150000 1.000 1.000 1400185000 14 Hickory nut 0.150000 1.000 1.000 1400213000 14 Macadamia nut 0.150000 1.000 1.000 1400269000 14 Pecan 0.150000 1.000 1.000 1400282000 14 Pistachio 0.150000 1.000 1.000 1400391000 14 Walnut 0.150000 1.000 1.000 1500025000 15 Barley, pearled barley 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500025001 15 Barley, pearled barley - babyfood 0.100000 1.000 1.000 In adve

Full comment: Inadvertent tol.

### Sulfentrazone Dietary Exposure and Risk Assessment D 417172

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Page 17 of 21 1500026000 15 Barley, flour 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500026001 15 Barley, flour - babyfood 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500027000 15 Barley, bran 0.150000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500065000 15 Buckwheat 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500066000 15 Buckwheat, flour 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500120000 15 Corn, field, flour 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 1500120001 15 Corn, field, flour - babyfood 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 1500121000 15 Corn, field, meal 0.150000 1.000 1.000 2F0639

Full comment: 2F0 6391 1500121001 15 Corn, field, meal - babyfood 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 1500122000 15 Corn, field, bran 0.150000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 15001230 00 15 Corn, field, starch 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 1500123001 15 Corn, field, starch - babyfood 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 1500124000 15 Corn, field, syrup 0.150000 1.500 1.000 2F0639

Full comment: 2F06391 1500124001 15 Corn, field, syrup - babyfood 0.150000 1.500 1.000 2F0639

Full comment: 2F06391 1500125000 15 Corn, field, oil 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 1500125001 15 Corn, field, oil - babyfood 0.150000 1.000 1.000 2F0639

Full comment: 2F06391 1500126000 15 Corn, pop 0.100000 1.000 1.00 0 2F0639

Full comment: 2F06391 1500226000 15 Millet, grain 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500231000 15 Oat, bran 0.150000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500232000 15 Oat, flour 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500232001 15 Oat, flour - babyfood 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500233000 15 Oat, groats/rolled oats 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500233001 15 Oat, groats/rolled oats - babyfood 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500323000 15 Rice, white 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500323001 15 Rice, white - babyfood 0.100000 1.000 1.000 Inadve

Ful l comment: Inadvertent tol. 1500324000 15 Rice, brown 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500324001 15 Rice, brown - babyfood 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500325000 15 Rice, flour 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500325001 15 Rice, flour - babyfood 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500326000 15 Rice, bran 0.150000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500326001 15 Rice, bran - babyfood 0.150000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500328000 15 Rye, grain 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500329000 15 Rye, flour 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500344000 15 Sorghum, grain 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500345000 15 Sorghum, syrup 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1500381000 15 Triticale, flour 0.150000 1.000 1.000 Inadve

Full comment: Inadvertent tol.

### Sulfentrazone Dietary Exposure and Risk Assessment D 417172

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Page 18 of 21 1500381001 15 Triticale, flour - babyfood 0.150000 1.000 1.000 Inadve

Full com ment: Inadvertent tol. 1500401000 15 Wheat, grain 0.150000 1.000 1.000 1500401001 15 Wheat, grain - babyfood 0.150000 1.000 1.000 1500402000 15 Wheat, flour 0.150000 1.000 1.000 15 00402001 15 Wheat, flour - babyfood 0.150000 1.000 1.000 1500403000 15 Wheat, germ 0.150000 1.000 1.000 1500404000 15 Wheat, bran 0.150000 1.000 1.000 1500405000 15 Wild rice 0.100000 1.000 1.000 Inadve

Full comment: Inadvertent tol. 1800002000 18 Alfalfa, seed 0.150000 1.000 1.000 2001163000 20A Flax seed, oil 0.150000 1.000 1.000 200 2330000 20B Safflower, oil 0.200000 1.000 1.000 2002330001 20B Safflower, oil - babyfood 0.200000 1.000 1.000 2002364000 20B Sunflower, seed 0.200000 1.000 1.000 2002365000 20B Sunflower, o il 0.200000 1.000 1.000 2002365001 20B Sunflower, oil - babyfood 0.200000 1.000 1.000 8601000000 86A Water, direct, all sources 0.098000 1.000 1.000 8602000000 86B Water, indirect, all sources 0. 098000 1.000 1.000 9500019000 O Asparagus 0.150000 1.000 1.000 2E0650

Full comment: 2E06500 9500177000 O Grape, leaves 0.150000 1.000 1.000 9500178000 O Grape, raisin 0.150000 4.300 1.000 9500263000 O Peanut 0.200000 1.000 1.000 0F0611

Full comment: 0F06116 9500264000 O Peanut, butter 0.200000 1.890 1.000 0F0611

Full comment: 0F06116 9500265000 O Peanut, oil 0.200000 1.000 1.000 0F0611

Full comment: 0F06116 9500275000 O Peppermint 0.300000 1.000 1.000 1E0631

Full comment: 1E06311 95002 76000 O Peppermint, oil 0.300000 1.000 1.000 1E0631

Full comment: 1E06311 9500352000 O Spearmint 0.300000 1.000 1.000 1E0631

Full comment: 1E06311 9500353000 O Spearmint, oil 0.300000 1.000 1.000 1E0631

Full comment: 1E06311 9500362000 O Sugarcane, sugar 0.150000 1.000 1.000 9500362001 O Sugarcane, sugar - babyfood 0.150000 1.000 1.000 9500363000 O Sugarcane, molasses 0.200000 1.000 1.000 9500363001 O Sugarcane, molasses - babyfood 0.200000 1.000 1.000

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## Attachment **4 :**  **DEEM -**  **FCID C**  **hronic E**  **xposure E**  **stimates .**  US EPA Ver. 3.16, 03 - 08 - d DEEM - FCID Chronic analysis for SULFENTRAZONE NHANES 2003 - 2008 2 - day Residue file name: C: \ Users \ gkramer \ Documents \ Gk \ ##Sulfentrazone \ 129081 - CHRON__30 APR 2014.R08 Adjustment factor #2 used. Analysis Date 04 - 30 - 2014/16:10:09 Residue file dated: 04 - 30 - 2014/16:08:32 Reference dose (RfD, Chronic) = .14 mg/kg bw/day

=============================================================================== Total exposure by population subgroup

------------------------------------------------------------------------------- Total Exposure

--------------------- -------------- Population mg/kg Percent of Subgroup body wt/day Rfd

-------------------------------------- ------------- ---------------- Total US Population 0.003973 2.8% Hispanic 0.004244 3.0% Non - Hisp - White 0.003929 2.8% Non - Hisp - Black 0.003729 2.7% Non - Hisp - Other 0.004432 3.2% Nursing Infants 0.003630 2.6% Non - Nursing Infants 0.010786 7.7% Female 13+ PREG 0.003740 2.7% Children 1 - 6 0.008381 6.0% Children 7 - 12 0.004506 3.2% Male 13 - 19 0.003277 2.3% Female 13 - 19/NP 0.003174 2.3% Male 20+ 0.003354 2.4% Female 20+/NP 0.003470 2.5% Seniors 55+ 0.003259 2.3% All Infants 0.008577 6.1% Female 13 - 50 0.003453 2.5% Children 1 - 2 0.009881 7.1% Children 3 - 5 0.007889 5.6% Children 6 - 12 0.004817 3.4% Youth 13 - 19 0.003225 2.3% Adults 20 - 49 0.003498 2.5% Adults 50 - 99 0.003314 2.4% Female 13 - 49 0.003450 2.5%

--------------------- ----------------------------------------------------------

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## Attachment 5: DEEM **- FCID Acute Exposure Estimates for the General Population Including Infants and** 

**Children (food only).** US EPA Ver. 3.18, 03 - 08 - d DEEM - FCID ACUTE Analysis for SULFENTRAZONE NHANES 2003 - 2008 2 - Day Residue file: 129081 - FoodOnly__30 APR 2014.R08 Adjustment factor #2 NOT used. Analysis Date: 04 - 30 - 2014/16:15:03 Residue file dated: 04 - 30 - 2014/16:07:51 NOEL (Acu te) = 250.000000 mg/kg body - wt/day RAC/FF intake summed over 24 hours Run Comment: ""

=============================================================================== Summary calculations -- per capita:

--- 95th Percentile ---- --- 99th Percentile ---- --- 99.9th Percentile ---- Exposure % aRfD MOE Exposure % aRfD MOE Exposure % aRfD MOE

---------- ------- -------- ---------- ------- -------- ---------- ------- -------- Total US Population: 0.005432 0.22 46025 0.010672 0.43 23425 0.018971 0.76 13177 All Infants: 0.009800 0.39 25509 0.014950 0.60 16721 0.032712 1.31 7642 Female 13 - 50: 0.003408 0.14 73365 0.004875 0.19 51283 0.008004 0.32 31232 Children 1 - 2: 0.015691 0.63 15932 0.024021 0.96 10407 0.042166 1.69 5928 Children 3 - 5: 0.012220 0.49 20459 0.017456 0.70 14321 0.022857 0.91 10937 Children 6 - 12: 0.006935 0.28 36048 0.010260 0.41 243 65 0.017836 0.71 14016 Youth 13 - 19: 0.004205 0.17 59450 0.006122 0.24 40839 0.009279 0.37 26942 Adults 20 - 49: 0.003339 0.13 74882 0.004778 0.19 52321 0.008052 0.32 31049 Adults 50 - 99: 0.002979 0.12 83908 0.004325 0.17 57800 0.007417 0.30 33706 Female 13 - 49: 0.003404 0.14 73439 0.004798 0.19 52107 0.007683 0.31 32538

### Sulfentrazone Dietary Exposure and Risk Assessment D 417172

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## Attachment 6: DEEM - FCI D Chronic Exposure Estimates (food only ). US EPA Ver. 3.16, 03 - 08 - d DEEM - FCID Chronic analysis for SULFENTRAZONE NHANES 2003 - 2008 2 - day Residue file name: C: \ Users \ gkramer \ Documents \ Gk \ ##Sulfentrazone \ 129081 - FoodOnly__30 APR 2014.R08 Adjustment factor #2 used. Analysis Date 04 - 30 - 2014/16:11:30 Residue file dated: 04 - 30 - 2014/16:07:51 Reference dose (RfD, Chronic) = .14 mg/kg bw/day

================================================= ============================== Total exposure by population subgroup

------------------------------------------------------------------------------- Total Exposure

----------------------------------- Population mg/kg Percent of Subgroup body wt/day Rfd

-------------------------------------- --- ---------- ---------------- Total US Population 0.001921 1.4% Hispanic 0.002285 1.6% Non - Hisp - White 0.001819 1.3% Non - Hisp - Black 0.002036 1.5% Non - Hisp - Other 0.002067 1.5% Nursing Infants 0.001773 1.3% Non - Nursing Infants 0.003961 2.8% Female 13+ PREG 0.001808 1.3% Children 1 - 6 0.005753 4.1% Children 7 - 12 0.002795 2.0% Male 13 - 19 0.001867 1.3% Female 13 - 19/NP 0.001594 1.1% Male 20+ 0.001443 1.0% Female 20+/NP 0.001314 0.9% Seniors 55+ 0.001275 0.9% All Infants 0.003286 2.3% Female 13 - 50 0.001410 1.0% Children 1 - 2 0.006921 4.9% Children 3 - 5 0.005395 3.9% Children 6 - 12 0.003018 2.2% Youth 13 - 19 0.001729 1.2% Adults 20 - 49 0.001451 1.0% Adults 50 - 99 0.001290 0.9% Female 13 - 49 0.001410 1.0%

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