P.1 

OAR Box 1500 

Prepped by Ollie Stewart 

Document Number: 

49) ll-C-75 

Docket Number: 

A-94-52 

Printed 8/5/2008 1:51:28 PM Sheet 49 of 343 
P.2 

..«. A-Bk-SX. 

11-£-75 

Date sent: 

From: 

To: 

Copies to: 

Subject: 

ThU, 06 NOV 1997 08:07:11 -0500 

MADELEINE STRUM <STRUM.MADELEINE@EPAMAIL.EPA.COV> 

robhab@erols.com 

mproctor@rtp.pes.com 

emissions data 

The attached lotus file contains the emissions data we are working with to come up with MACT emission models. 

We would like to use all data available - however, we have been unable to use data in which we would have had 

to make assumptions to split out the resin and gel coat emission factors. 

I will send you the MACT floor data base later today. 
P.3 

Pacific Environmental Services, Inc. 

Project No. N801 - Reinforced Plastic / Composites NESHAP 

Analysis: One Variable (Styrene) Linear Regression for Manual Resin Application - Bucket 

Data Legend 

CFA Phase I, CFA Phas, Lower Bound 

DOW Chemical f 

Run No. 

1'2A 

12B 

4A; 

13 . 

4B 

Q 

1.1A 

iiB 

Data ID 

Assume 

;060596 

092895C 

092695A 

100295A 

10039: 

092995A": 

092695A 

092795C 

0927.95A 

100295B 

09.1995A 

os; 

09209: 

092695B 

092595A 

092895B 

092995C 

0801oe 

052996 

'052996B 

053096B 

060396B 

Monomer 

Content 

(% Styrene) 

Styrene 

Emissions 

% resin wt) 

44.4 

3.40/ 

/o, 

3.6% 

3.6%' 

4.2% 

4.2%: 

4.6%;. 

5.0%: 

5.3%: 

6.2%' 

6.3%:: 

4.9%. 

F\ 7%" 

9% 

o. I. /o: 

8.9% 

8.9% 

4.9 

3.4%; 

9.3%:. 

Styrene 

Emissions 

(% monomer) 

0.0% 

T3I8%S 

9.6%

 : 

10,1% 

io.1%. 

11.7%; 

11:9% 

13.1% 

14.( 

14.7% 

17. 

17.6%; 

11.7%; 

11.5% 

5%: 

14 ' 

21.2% 

21.0%;}' 

11.0%-

LT8;8 

19:6 

^ 
P.4 

Pacific Environmental Services, Inc. 

Project No. N801 - Reinforced Plastic / Composites NESHAP 

Analysis: One Variable (Styrene) Linear Regression for Manual Resin with Vapor Suppression 

Data Legend CFA Phase II,. . CFA Filled. 

Run No, 

Monomer 

Content 

(% Styrene 

NMMA 

I DOW Chemical! 

Suppressant 

Level 

% Resin) 

Lower Bound 

Styrene 

Emissions 

Styrene 

Emissions 

.monomer) 

3 
P.5 

\ ^ 

Pacific Environmental Services, Inc. 

Project No. N801 - Reinforced Plastic / Composites NESHAP 

Analysis: One Variable (Styrene) Linear Regression for Mechanical Resin Application 

CFA Fill 

Data Legend 

v Phase I GFAPhase ll NMMA Lower Boi 

DOW Chemical I 

Run No, 

Assumed 

11-3 

Data ID 

Assumed 

081296B; 

080896A^ 

080896B 

121295A' 

120895A112995A; 

120895B: 

111595B 

112895 A' 

112995B: 

121295B 

120695A 

'0495A 

Monomer 

Content 

% Styrene) 

0 

33.8 

35 

ob 

35.1 

1 (&'1C 

- 11 A2 

3B 

5 

8. 

12-2 

12-1 

Ig female 

Ig female 

Ig male 

/022296A 

120695B 

121495B 

121495B 

120795A 

95B 

111695B 

111695A 

113095A 

112895B 

120595B 

092596B 

092596A 

101796B 

•4Z 

4X _\ 

AO 

42 

42 

42.2 

49 o 

44.4" 

44.4 

44.4 

Styrene 

Emissions 

[% resin wt) 

0.0< 

7.9%. 

8.3%; 

8.4%. 

5.6% 

6.3%; 

6.4% 

6.5%. 

6.6% 

6.7% 

. 6.9%. 

7.2%; 

8.0%. 

8.2°-

18.3% 

9.1%", 

9.4%..: 

10.4:%. 

10.7% 

12.1% 

Q 

13.0%; 

13.9%. 

14.2%. 

15.0% 

16.0%. 

16.5% 

23.0% 

•1: 

13.4%; 

Styrene 

Emissions 

(%

 m on

o

mer ) 

'23.3% : 

24.6%"-

2.5.0% 

16.1% 

18.2% 

18.6% .: 

18,8% -

19.C 

20.6 

•22.9% : 

52.0% 

.21.7% 

.22.4% 

24.8% 

25.4%: 

28;7%-

31.0% 

33.1% 

33.9% 

35.8% 

38.0% 

39.2% 

54.6% 

28:2%. 

'30.2% 

+ 
P.6 

t . 

Pacific Environmental Services, Inc. 

Project No. N801 - Reinforced Plastic / Composites NESHAP 

Analysis: One Variable (Styrene) Linear Regression for Mechanical Resin Application with Vapor Suppression 

Data Legend 

CFA Phase! CFA Phase! Iii CFA Filled NMMA 

DOW Chemical f 

Moaui i i t J 

,::.:i396B. 

081396A 

061396B"'. 

030796A -

082796A 

v 081B96B :• 

Monomer 

Content 

(% Styrene) 

33 R 

4^.4 

44 4 

48.8 

48 8--

Suppressant 

Level 

(% Resin) 

1 :;-

1.5 

Styrene 

Emissions 

(% resin wt) 

Styrene 

Emissions 

(% monomer) 

12.-' 
P.7 

Pacific Environmental Services, Inc. 

Project No. N801 - Reinforced Plastic / Composites NESHAP 

Analysis: One Variable (Styrene) Linear Regression for Mechanical Resin Application with Non-Atomized Application 

Data Legend ^___^__^^__ _ 

CFA Filled _ NMMA Lower Bound 

DOW Chemical HHHH H 

Styrene Styrene 

Emissions Emissions 

r^sin wt) (% monomer) 

0.0% 0.0% 

Run No. 

Assumed 

Data ID 

Assumed 

Monomer 

Content 

(% Sty a-: •. 

0 0 

Control 

Equipment 

Flow Coater 

Flow Coater 

3.7% 

3.7% 

502279 

:02279 

'02279 

44.4-

44.4 

PF-R6! 5.7%' 

10.5% 

10.5% 

15-2 

16-2 

42.2 

42.2 

Flow Coater 

Flow Coater 

Flow Coater 

Flow Coater 

4.5% 

5.9% 

10.6% 

14.0% 

11.4% 

0 
P.8 

Pacific Environmental Services, Inc. 

Project No. N801 - Reinforced Plastic / Composites NESHAP 

Analysis: One Variable (Styrene) Linear Regression for Mechanical Resin Application with Controlled Spraying 

Data Legend 

^FAPhase^FAPhas ^ NMMA I 

DOW Chemical I 

Run No, 

Assumed 

7-1 

4-2 

Data ID 

Assumei 

Monomer Control Styrene Styrene 

Content Equipment Emissions Emissions 

% Styrenjft) Iypfl (% resin wt) (% monomer) 

Cont. St 

35.1 

35.1 

Cont. Spraying 

Cont. Spraying 

5.5% 

5.7% 

15.7% 

16.1% 

Sprayi 

Sprayi 

18.8% 

Cont. Spraying 20.4% 

5-2 

2-1 

9-1 

9-2 

42.2 

42.2 

42.2 

42.2 

Cont. Spraying 

Cont. Spraying 

Cont. Spraying 

Cont. Si 

8.8% 

9.4% 

9.6% 

9.7% 

20.8% 

22.3% 

22.8% 

23.0% 

2 

4 

3 

1 

080196B 

061296A 

061396A 

092596A 

101796A 

080696A 

090496A 

090596A 

090496B 

082996A 

081696A 

. 081596 

44.4 

•44.4 

44.4 

44.4 

44.4-

•44.4 

45.8 

45.8 

45.8 

45.8 

Cont. Spraying 

Cont. Spraying 

Cont. Spraying 

Cont. SprayingCont. Spraying 

Cont. Spraying 

Cont. Spraying 

Cont. Spraying 

Cont. Spraying 

Cont. Spray 

;nt. Sprav 

,.-; Cont. Sprav 

6.1 

9.9% 

; .10.0% 

13.1 

9.2% 

10.2% 

13 8% 

17.0% 

22 33. L' 

22 5% 

24.6% 

29.5% 

17.4% 

20.1% 

18.9% 

21.5% 

11.8% 
P.9 

Pacific Environmental Services, Inc. 

Project No. N801 - Reinforced Plastic / Composites NESHAP 

Analysis: One Variable (Styrene) Linear Regression for Filament Winding 

CFA Filled . NMMA . M 

\DOW Chemical! 

Run No, 

1 

9 

16 

14 

13 

2 

6 

19 

7 

18 

Data ID 

Monomer 

Content 

(% Styrene) 

33 

33 

33 

33 

48 

48 

48 

48 

48 

48 

Styrene 

Emissions 

(% resin wt) 

4.9% 

5.9% 

6.3% 

7.2% 

8.3% 

8.6% 

10.3% 

10.3% 

11.8% 

12.0% 

Styrene 

Emissions 

(% monomer) 

O.l 

14.9% 

17.9% 

19.1% 

21.8% 

17.4% 

17.9% 

21.4% 

21.4% 

24.5% 

24.9% 

7 
P.10 

t > 

Pacific Environmental Services, Inc. 

Project No. N801 - Reinforced Plastic / Composites NESHAP 

Analysis: One Variable (Styrene) Linear Regression for Filament Winding with Vapor Suppression 

Data Legend 

Cf^A Phase CFA Filled NMMA 

I DOW Chemical 

Run No. 

Assumed 

20 

17 

10 

4 

5 

3 

12 

8 

15 

11 

Data ID 

Assumed 

(% Styrene) 

0. 

33 

33 

33 

33 

33 

48 

48 

48 

48 

48 

(% Resin) 

1.5 

1.5 

1.5 

1.5 

1.5 

1.5 

1.5 

1.5 

1.5 

1.5 

1.5 

(% resin wt) ( 

Q,Q°A 

3.7% 

3.7% 

3.9% 

4.8% 

5.4% 

4.0% 

4.6% 

4.9% 

5.0% 

6.6% 

% monomer} 

0i)%_ 

11.2% 

11.2% 

11.8% 

14.4% 

16.5% 

8.4% 

9.6% 

10.3% 

10.3% 

13.8% 

°\ 
n 

p.11 

Pacific Environmental Services, Inc. 

Project No. N801 - Reinforced Plastic / Composites NESHAP 

Analysis: One Variable (Styrene) Linear Regression for Gel Coat Application 

Data Legend 

CFA Phase I NMMA Lower/Bound, 

DOW Chemical I 

Monomer Styrene Styrene 

Content Emissions Emissions 

(% Styrene) (% resin wt) (% monomer) 

0 0.0% 0.0% 

45:8%o 

l.u idyoM 

030596A11B 

101695B101795A10.1895B 

102395B; 40 

24. 

24.8% 

58.C 

62. 

|0 
P.12 

Pacific Environmental Services, Inc. 

Project No. N801 - Reinforced Plastic / Composites NESHAP 

Analysis: One Variable (Styrene) Linear Regression for Gel Coat Application with Controlled Spraying 

Data Legend »TM~TMr«»aiB~^ 

NMMA Lower Bound 

DOW Chemical ••••^ 1 

Control Styrene Styrene 

Equipment Emissions Emissions 

Type (% resin wt) (% monomer)_ 

Cont. Spraying 0.0% 0.0% 

Run No. 

Assumed 

DaJtaJD 

Assumed 

CFA Filled 

Monomer 

Content 

0.0 

Ig female 

!g male 

6-1 

11-1G 

6-2 

6-P 

o r 

37 

37 

37 

37 

Cont. Sprayingy 

Cont.. Spraying; 

Cont. Spraying 

Cont. Spraying 

Cont. Spraying 

Cont. Spraying 

: 

15.7% 

16.1% 

16.7% 

17.4% 

31.0% 

42.3% 

43.4% 

45.2% 

47.0% 

Cont. Spraying 20.1 % 54.2% 

... Spray ii 

t. Sprayir 

Cont. Sprayir .12.7 

H