P. 1 

# RCRA Box 1883 Prepped by Ollie Stewart



### Document

Number: 

# 86 ) ll-B-24 8 Docket Number: 

# A-90-1 9

Printed 12/3/200810:42:16

AM Sheet 86 of 171

## MEMORANDU M P. 2 

## A-90-1 9 ll-B-24 8

TO : FROM : DATE : Proces s Vent s Docke t A-90-1 9 WandaFloy

d Januar y 199 2 SUBJECT : HO N NESHAP : Industr y Characteristics /

Propyr-CEIoride Attache di s aproduct-proces s summar y (PPS ) fo

r th e productio n o

f Propy l Chlorid e vi a hydrohalogenatio n of

n-propy l alcohol . Thi s PP S wa s develope da s par t of th e Industria l Profil e projec t

i n support

o f th e Hazardou s Organi c NESHA P(HON ) regulatory effort . Informatio n i n thi s PP S i s use da s abasi s for emission s an dcos t

impac t estimate s fo

r th e HO Nprogram . Liste dbelo w ar e th e ke

y reference s use di n developin g th e attache dPPS . EP A 600/2-77-023f

. Industria l Proces s Profile s fo r Environmenta l Us e Chapte r 6 : Th e Industria l Organi c Chemical s Industry . February 1977 . p . 6-656 . 

# Tri e Correspondin g guit yAssarsns s "ocmnsi ti s Docketten A-90-1 9 ll-B-25 2P. 3

Preparer : Oate : Reviewer : /~\eLol,'

6- it+. Aic/ l o bo<A<

PfOduct-PrOC m C0<f

t ADMINISTRATIV E NOTE S 

### 5 Ho $*£

/T

### UO Hour s spen t o n thi s PP S p. p Nan , e ?

r °^ll cUorJ*

\A*

JyitoU I % *'«&•*

*-t *- pr* / > t <,(U* ( Incomplet e Item s (part s o f for myo u canno t complete ) 

### (line * an ddescription ) Dat e Cleare d Initial s

Chemical s missin g CA S number s

Plan t wit hCit v

bu t no Count v

(plan t name , dty , state )P. 4

•Ale/ / Afa/W - Preparer : Date : 6

- iv-io Reviewer : PRODUCT-PROCES

S SUMMAR

Y(PPS ) 

### Chemica l nm, prcp 7 

### LclbrJf Alternativ e Chemica l j-ti/ora fr*P*'.t
Rare n fmw Yr 0>rV •£

, vv^jtw^^-XStoAwW-KSx^'lfeXW^ W CHEMICA L SPECIFI C INFORMATIO N 1. 0 U.S . Productio n Re f # . , P

g # . , Re

fYea r (indicat e th e sam

e referenc e Informatio n fo r an y answer s belo wfro m a differen t reference ) i;i ; ^lipffmilP^r^WBfltrft*g | million s o f k o o r million s o f gallon s 

# tx^m&mwtm 1. 3 V X,wT " i 1.5 * 1. 7 Produc

t Pric e ^ 0 

# ddfv

S/K o o r S/gallon

1. 8 Comment sP. 5



### 2. 0 Chealca l End-Us e Re f # , p g # ' R e 

### f Yea r US * Percen t



## no cT-oT

03. 0 U.S . Producer s Re f # . , P g # . , Re f Yea r WM million s Q f K

g UL—millions o f gallon s 3. 2 Naae , Location , an dCapacit y

Proces s Use d (us e P- P # )

Tota l Capacit y 3P. 7

PRODUCT-PROCES S SPECIFI C INFORMATIO N 4. 0 Potentia l Product-Processe s (P-P )

Nam e Re fI 

## IL. . P

g # 6 

## '

s6s Commerciall y % Nat' l YUbl e (Y/n ) Capacit y p. p J ^ r 6p}Lci/t/rJf/jm JfJfokJmjtwJ;,,. • / n-f>n./> f

l/*lt*U f_ p- p 2 ; P- P 3 P- P 4 P- P 5 ^ P- P 6 

## h>7 

## &* x 

## "^

4. 1 Documentatio n o f P-P s Exclude d

P- P no t Commerciall yViabl e Reason sP. 8

47 3 

## mm*} Q X <, *— <- J Re f I i < . , Pg # i--r< f r A1 r Oxidatio nReactio n Oxidatio nReactio n Alkylatio nReactio n Carbonylatio nReactio n Halogenatio nReactio n Condensatio nReactio n Dehydrogenatio nReactio n Dehydrohalogenatio nReactio n Esterificatio nReactio n Hydrogenatio nReactio n (fflycFohalogenationKeactTgn ^ Hydroformylatio nReactio n Hydrolysi s Reactio n Nitratio nReactio n Oxyacetylatlo nReactio n Oxyhalogenat1o nReactio n Sulfonatio nReactio n Catalyti c Reformatio n Hydrodlmerizatlo nReactio n Generi c Reactio n
4. 4 Explai nhow

yo uselecte dth e reactio ntyp e inlin e 4.3 . \€c%«u 

# »4 I s 

## M*J -ir-~ ct



## y ~ . c r*+ 

### f*rio(P. 9

i* 

# 1*1$?-l-^& 4. 5 Writte nDescriptio n I n th e lef t margin , indicat e reference s and pag e number s throughou t writte n description . 

# XcAU / , — ^ h^ dU 

# < **J



# - 2 

# ' " ci/J . cl'l.t"

tr «"£•»••P.1 0

5. 0 Proces s Flo

w Diagra m (attac ha t en

do f package ) 5. 1 Flo w Olagra m Reference : Re f # , P g # 5. 2 Comment s o n Flo

w Diagra m 

### ^ da~ha

9jF*~nm Componen t TYP M Distillatio nColuan s Absorber s Stripper s Reactor s Condenser s Vaporizer s Other s Re f I n|l|||||Jjyj^« M / ctf > a> 1 

### o O . P g *P.1 1

6. 0 Chemica l Dat a 6. 1 Balance dChemica l Reaction s « * * 2- 5 6-

SY > Re f# ___ , Pg # 

### Q 14 cHi<^h a H

+ 14cl 2*'/a - . .J.C^C^c/ i-

HiC* ^ ^ 3

6. 2 Chemica l Tre e 1$ c<-^>t Re f# - P g #

^



### _py 0 

### p] La 

### (- C 

### °L° L H-U 

## x ,;, / 

## cl h** c.fJ.ptP.1 2

6. 4 Stoichioaetry

Re f # z $ . p g# __£l££ / Sho w calculation s an

dassumption s an

dthensummariz e I

ntabl e o

nnex t page . 

## £ H^oti - f /^c / * S 7 c

### ^H_cL+ *z O


## 7^- 5 + ' *P.1 3



### 6. 4 Stoichioaetr y

Conversio nFactor s a ) 

### b 

# ) z^&mf«^

f 

# ^Mw<m c ) twmm-fitm?;m tm d ) Cdft^UHKF&tSfc W Q H e ) COn^Bfo

n Facto rfo ^ Co-PrwJu

f f ) Conversio

n Facto rComment s 

# ,oP.1 4

6.4. 1 Produc t 6.4. 2 Ra w MateriaHs l 

## # 1 -A-Pnp^L

o # 2 ^?_oxo cl>L*r,'(_ # 3 # 4 # 5 5,4, 3 Co-Product s # i # 2 # 3 # 4 # 5 6.,4, 4 BY-Product s 

## # i ^«Uv n # 3 # 4 # 5 6.4. 5 Intermediate s #1 # 2 

## I

Colo L acrj S^oSfS 0.76 o-Hl

711ZIZS o.22> 

# JP.1 5

7. 0 Proces s Ven t EmissionSource s 7. 1 Ar t ther e proces s ven t emissions ! 7. 2 Ai r Oxidatio nve* t emissions ! _ A / (Y/N ) (Y/N ) Re f # a s <>-J

v-.-z-tl

. , Pg #

7. 3 Comment s Re f # . , P g #



## y (Y/N ) Re f I «- . x-/ 1

., Pg # 7. 5 Comment s Re f # . , P g IP.1 6


# j.T^'Lm^w^wim. 7.8 imm^^rmsF$m§ 7. 9 Comment

s 

## •H i y



## (VN ) ( sg g H o

a r 4M Re

f I 5 S.u^.zJ Re f # _. P

a 1

. P a #P.1 7

8. 0 Transfe r Emissio nSource s 

## ar.r ~ mFm^z/m±\m®witzs^ 8* 2 WhiroaterUI s m tra»sT*rr«d J Re f#



### J i (Y/N

) — . P g # .

8.2. 1 Produc t

### propyl

^hloy;c\t 8.2. 2 Co-Product s 

## 5^*5* 5

8. 3 Comment

s Ref I . , Pg #P.1 8

9. 0 Storag e Emissio n Source s Re f # , P

g I 

## 9. rmrttmmun swrM^ V (Y/N ) 9. 2 Hha

tmaterial s ar e stored * Storag e Servic e 

## H H cai i T 

## yp e 9.2. 1 Produc t, 9.2. 2 Co-Product s



### 9,2. 3 Ra wMaterial s 1*2/ro <-L(or,c 

### UoloL

<-\c*'J

• *• • • " • - 9. 4 Comments 'P.1 9



## ts <r>-s6s 10.0 . Wastewate r Emissio n Source s Re f # , P g # 

# io. r i s xmmim fhmm Y

(Y/N ) 10. 2 Describ e wastewate r
Strea mEquipmen t Componen t Numbe r Producin g Wastewate r Comment s o n flo w # 1 vy*%U

t*/ W Ao>ww

tte 'e*cf;*«

^ ^:sf. C°U*<" 

### # 2 ' # 3 

### a- 2_^ 4 ~.k+<h, P" I" ** '* »'V'"'

10. 3 Strea a Compositio n Re f # , P g # (provid e onl yI f readil yavailable ) Strea m# 1 cy[Q 

### jjfa Stea a # 2 Organic s Organic s

HAP s HAP s

Wate r Wate r Othe r Othe rStrea m# 3

Organic s .

HAP s

Wate r Othe r P.2 0

10. 4 Comment s Re f # . , Pg #P.2 1

; EPA-600/2-77-023 f Februar y 197 7

INDUSTRIA L PROCES S PROFILE S FORENVIRONMENTA L US E CHAPTE R6 TH E INDUSTRIAL ORGANI C CHEMICAL S INDUSTRY



### b y Raimon dLiepin s andFores t Mixo n Researc hTriangl e Institut e Researc hTriangl e Park , N.C . 2770 9 Charle s Huda kandTerr y B . Parson s Radia nCorporatio n Austin , Texa s 7876 6

Contrac t No . 68-02-131 9
Projec t Office r Alfre dB . Crai g Metal s andInorgani c Chemical s Branc h Industria l Environmenta l Researc hLaborator y

Cincinnati , Ohi o 4526 8 INDUSTRIA L ENVIRONMENTA L RESEARC H LABORATOR Y OFFIC E O F RESEARC H AN DDEVELOPMEN T U.S . ENVIRONMENTA L PROTECTIO N AGENC Y CINCINNATI , OHI O 4526 8 

## RADIA N LIBRAR Y DURHAM , N.C .P.2 2



# 1 

# T i

T |milSTRlA

L ORGANI C CHEMICAL S PROCES S NO . 23 0 n-Propy l Chlorid e (fro m n-propy l alcohol ) ZnCl . CH 3 CH 2 CH 2 O H + HC I =-*• CH 3 CH 2 CH 2 C 1 + H 2 0
1 . Functio n- n-Propy l chlorid e i s produce d b y heatin g n-propy l alcoho l i nconcentrate d hydrochlori c acid . Zin c chlorid e catalyze s the re action . 2 . Inpu t Material s n-Propy l alcoho l Hydrochlori c aci d (cone. ) 3 . Operatin g Parameter s Temperature : no t give n Pressure : no t give n Catalyst : ZnCl 2 4 . Utilitie s - No t give n 5 . Wast e Stream s - Water-spen t catalyst , propy l chloride , an d tar s ma y b e presen t i nth e separato r wast e effluents . 6 . EPA

Sourc e Classificatio nCod e - Non e 7 . Referenc e Chemica l Technology , Barne s an d Nobl e Books , New York , N.Y. , Vol . 4 (1972) , p . 192 , 270 .

6-56 5