Veoli a E S Technica l Solutions , L.L.C . Pag e 13 8 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T Expiratio n Date : DRAF T (ii ) Equippe dwit h abarrie r flui dsyste

mdegassing reservoir

tha t i s routed t o aproces s or

fue l ga s syste mor connected b y aclosed-ven t syste mt o acontro l devic e tha

t complie s with th

e requirement s o f

4 0 C.F.R . §61.242-11 ; or (iii ) Equippe dwit h asyste mtha t purge s th e barrie r flui dint o aproces s strea mwith zero VHA P emission s t o atmosphere . (c) Th e barrie

r flui dshal l no

t b e i n VHA P servic e and , i f th e compresso

r i s covere db y standard s unde r 4 0 C.F.R . Par

t 60 , shal l no

t b e i n VO C service . (d ) The Permitte e shal l equi p eac h barrie r flui dsyste

ma s describe d i n 4 0 C.F.R . § 61.242- 3 (a)-(c ) with asenso r tha t wil l detec

t failur e ofth e sea

l system , barrie

r fluidsystem , o

r both . (e ) The Permittee shal l chec k eac h senso r a s require d i n 4 0 C.F.R . § 61.242

- 3(d ) dail y o r shal l equi

p the senso

r with a n audibl e alar

munles s th

e compresso

r i s locate d withi n th

e boundar

y o f a n unmanned plan

t site . (f ) Th e Permitte e shal l determine , based on desig n consideration s an d operatin g experience , acriterio n tha t indicate s failur e o f

th e sea l system , th e barrie r flui dsystem , or

both . (g ) I f th e senso r indicate s failur e o f

th e sea l system , th

e barrie r fluidsystem , o r bot h based on th

e criterio n determined unde r paragrap h (e)(2 ) o f

4 0 C.F.R . § 61.242-3 , alea

k i s detected . (h ) Whe n alea

k i s detected , th

e Permittee shal l repai

r i t a s soon a s practicable , bu t not late r tha n 1 5 calenda

r day s afte r i t i s detected , except

a s provide di n 4 0 CF.R . § 61.242-10 . (i ) Th e Permittee shal l mak e afirst attemp t a t repai r n o late r tha n 5 calenda

r day s after eac h lea k i s detected . (j ) A compresso

r i s exemp t fro mth e requirements o f

4 0 C.F.R . § 61.242-3(a

) an d (b ) i f it i s equippe d wit h aclosed-ven t syste mt o captur e an d transpor

t leakag e fro mth

e compresso

r driv e shaf

t back t o aproces s or

fue l ga s syste mo r t o acontro l devic e tha

t complie s with th

e requirement s o f 4 0 CF.R . § 61.242-11 , except a s provide d i n 4 0 C.F.R . § 61.242-3(i) . (k ) An y compresso

r tha t i s designated , a

s describe d i n 4 0 C.F.R . § 61.246(e)(2) , fo r

no detectable emissio n a s indicate d b y a

n instrumen

t readin g o f

les s tha n 500 pp mabove backgroun d i s exemp t fro mth e requirements o f

40 CF.R . § 61.242-3(a)-(h) i f th e compressor :Veoli a E S Technica l Solutions , L.L.C . Page 13 9 o f 17 2 Penni tNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T ExpirationDate : DRAF T (i ) I s demonstrated t o b e operating with no detectable emissions , a s indicate db

y a n instrumen

t reading o f

les s tha n 50 0 pp mabove background , a

s measure d b y th e metho d specifie di n 4 0 C.F.R . § 61.245(c) ; an

d I s teste d fo r complianc e with 4

0 C.F.R . § 61.242

- 3(i)(l ) initiall y upo n designation , annually , an d a t othe r time s requested b y th

e Administrator . 4 . Open-ended valve s o r lines : [40 C.F.R . § 61.242-6 ] (a ) Th e Permitte e shal l equip eac h open-ende

d valv e o r lin e wit h acap , blin d flange , plug , or

asecond valve , excep

t a s provide di n 4

0 C.F.R . § 61.242

- 1(c) . (b) Th e cap , blin dflange , plug , o r second valv e shal l sea

l th e open en d a t al l time s except

durin g operation s requirin g proces s flui dflo w throug h th e open-ended valv e o

r line . (c ) Th e Permitte e shal l operat e eac h open-ende

d valv e o r lin e equipped wit

h a second valv e i n amanne

r such tha t th e valv e o n th

e proces s flui den

d i s close dbefore th

e secon d valv e i s closed . (d ) Whe n adoubl e bloc k an d blee d syste

mi s bein g used , th

e blee d valv e o

r lin e ma y remai n open durin g operation s tha t requir e ventin g th

e lin e betwee n th e bloc k valve s bu

t shal l compl y with 4 0 CF.R . § 61.242-6(a ) a t al l othe r times . (e ) Open-ende d valve s o r line s i n a n emergenc

y shutdown syste

mwhic h ar

e designe d t

o ope n automaticall y i n th

e even t o f aproces s upse

t ar e exemp t fro mth e requirement s o f 4 0 C.F.R . § 61.242-6(a) , (b) an d (c) . (f ) Open-ende d valve s o r line s containin g material s whic h woul d autocatalyticall y polymeriz e o r woul dpresen

t a n explosion , seriou s overpressure , o

r othe r safet y hazar d i f capped o r equippe d with adouble bloc k an d blee d syste

ma s specifie di n 4 0 CF.R . § 61.242-6(a ) throug h (c ) ar e exempt fro mth e requirements o f

4 0 CF.R . § 61.242-6(a

) throug h (c) . 5 . Valves : [4 0 C.F.R . §61.242-7 ] (a ) Th e Permitte e shal l monito r eac h valv e monthly t

o detec t leak s b y th

e metho d specifie di n 4 0 CF.R . § 61.245(b ) an d shal l compl y with 4

0 C.F.R . § 61.242-7(b)-(e) , except a s provide di n 4 0 C.F.R . § § 61.242-7(1) , (g) , an d (h) , 61.243- 1 o

r 61.243-2 , an

d 61.242-l(c) . (b) I f a n instrumen

t readin g o f

10,00 0 ppmo r greate r i s measured , alea

k i s detected .Veoli a E S Technica l Solutions , L.L.C . Pag e 14 0 o f 17 2 Permi tNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T ExpirationDate : DRAF T

(c ) Th e Permittee ma

y monitor an y valv e fo r

whic h alea

k i s no t detecte d fo r 2 successiv e month s th

e first mont h o f ever y quarter , beginnin g with th e nex t quarter, unti l alea

k i s detected . (d ) I f alea k i s detected , th

e Permittee shal l monitor th e valv e monthly unti l a lea k i s not detecte d fo r 2 successiv e months . (e ) Whe n alea

k i s detected , th

e Permittee shal l repai

r i t a s soo n a s practicable , bu t n o late r tha n 1 5 calenda

r day s afte r

th e lea k i s detected , except

a s provide di n 4 0 CF.R . § 61.242-10 . (f ) Th e Permittee shal l mak e afirst attemp t a t repair no late r tha n five calenda

r day s after each lea k i s detected . (g ) Firs t

attempt s a t repair include , bu

t ar e no t limite dto , th

e followin g bes

t practice s wher

e practicable : (i ) Tightenin g o f

bonne t bolts ; (ii ) Replacemen

t o f bonne t bolts ; (iii ) Tightenin g o f

packin g glan d nuts ; an

d (iv ) Injectio n o f

lubricant int o lubricate d packing . (h ) An y valv e tha

t i s designated , a

s describe d i n 4 0 C.F.R . § 61.246(e)(2) , fo r n o detectable emissions , a s indicate db y a

n instrumen

t readin g o f

les s tha n 50 0 pp mabove background , i s exemp t fro mth e requirement s o f

4 0 C.F.R . § 61.242-7(a)ifth e valve : (i ) Ha s no externa

l actuating mechanis mi n contact with th e proces s fluid ; (ii ) Is operate

d with emission s les s tha n 50 0 pp mabove background , a s measure d b y th e metho d specifie di n 4 0 CF.R . § 61.245(c) ; an d (iii ) Is teste

d fo r complianc e with 4

0 C.F.R . § 61.242-7(f)(2 ) initiall y upo n designation , annually , an d a t othe r time s requested by th

e Administrator . (i ) An y valv e tha

t i s designated , a

s describe d i n 4 0 C.F.R . § 61.246(f)(1) , a s an unsafe-to-monitor

valv e i s exemp

t fro mth e requirement s o f

4 0 C.F.R . § 61.242-7(a)if :



### VES01760 2Veoli a E S Technica l Solutions , L.L.C . Pag e 14 1 o f 17 2 Permi tNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T Expiratio n Date : DRAF T (i ) The Permittee demonstrate s tha t th e valv e i s unsaf

e t o monitor becaus e monitorin g personne l woul dbe exposed t

o a n immediat

e dange r a s aconsequence o f

complyin g with 4

0 C.F.R . § 61.242-7(a) ; an d (ii ) Th e Permittee has awritten pla n tha t require s monitorin g ofth e valv e a s frequen t a s practicabl e durin g safe-to-monitor times . (j ) An y valv e tha

t i s designated , a

s describe d i n 4 0 C.F.R . § 61.246(f)(2) , a s a difficult-to-monito r

valv e i s exemp

t fro mth e requirements o f

paragrap h (a ) of40C.F.R . § 61.242- 7 if : (i ) The Permittee demonstrate s tha t th e valv e canno

t b e monitore d without elevatin g th

e monitorin g personnel mor e tha n 2 meter s abov e asuppor

t surface ; (ii ) The proces s unit

withi n whic h th

e valv e i s locate d i s a

n existin g proces s unit ; an

d (iii ) Th e Permittee follow s awritte n plan tha t require s monitorin g o f

th e valv e a t least onc e pe r calenda r year . 6 . Alternativ e standards fo r valve s i n VHA P servic e - allowabl e percentage o f valve s leaking : [4

0 C.F.R . § 61.243-1 ] (a ) The Permittee ma

y elec t t o have al l valve s withi n aproces s uni t compl y wit h a n allowabl e percentage o f valve s leakin g o f

equa l t o or les s tha n 2. 0 percent . (b ) The followin g requirements shal l b e me t i f th e Permitte e decide s t

o compl y wit h a n allowabl e percentage o f valve s leaking : (i ) Th e Permittee must

notif y th e Administrato r

tha t i t ha s elected t o hav e al l valve s withi n aproces s uni t to compl y wit h th

e allowabl e percentag e o f valve s leakin g befor

e implementin g thi s alternativ e standard , a

s specifie di n 4

0 C.F.R . § 61.247(d) . (ii ) Th e Permittee conducts aperformanc e test a s specifie di n 4 0 C.F.R . § 61.243-l(c ) initiall y upon designation , annually , an d a t othe r time s requeste d b y th e Administrator . (iii ) I f avalv e lea

k i s detected , th

e Permitte e shal l repai

r i t i n accordanc e wit h 4 0 C.F.R . § 61.242-7(d

) an d (e) . (c ) The Permitte

e shal l conduc t

performanc e tests i n th

e followin g manner :Veoli a E S Technica l Solutions , L.L.C . Page 14 2 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T Expiratio n Date : DRAF T (i ) Th e Permitte e shal l monitor al l valve s i n VHA P servic e withi n th e proces s uni t

withi n 1 wee

k b y th e method s specifie di n 4 0 C.F.R . § 61.245(b) . (ii ) I f a n instrumen

t readin g o f

10,00 0 pp mo r greate r i s measured , alea

k i s detected . (iii ) The Permitte e shal l determin e th e lea k percentag e b y dividing th e numbe r o f valve s i n VHA P servic e fo r whic h leaks ar

e detected b y th e numbe r o f valve s i n VHA P servic e withi n th e proces s unit . (d ) I f th e Permitte e elect s to have al l valve s compl y with thi s alternativ e standard , n o proces s uni t

shal l hav e alea k percentag e greate

r tha n 2. 0 percent . (e ) I f th e Permitte e decide s no longe r t o compl y with 4

0 C.F.R . § 61.243-1 , the Permittee mus t

notif y th e Administrato r

i n writin g tha

t i t wil l follo w th

e wor k practic e standar

d describe d i n 4

0 C.F.R . § 61.242-7(a)-(e) . 7 . Alternativ e standard s fo r valve s i n VHA P service : [4 0 C.F.R . § 61.243-2 ] (a ) The Permittee ma

y elec t fo r al l valve s withi n aproces s uni t t o compl y with on e o f th e alternativ e wor

k practice s specifie di n 4 0 C.F.R . § 61.243

- 2(b)(2) an d (3) . (b ) The Permittee must

notif y th e Administrato r

befor e implementin g on

e o f th e alternativ e wor

k practices , a

s specifie di n 4 0 C.F.R . § 61.247(d) . (c ) Th e Permittee shal l compl y initiall y with th e requirement s fo r

valves , a s describe di n 4 0 C.F.R . § 61.242-7 . (d ) Afte r tw o consecutiv e quarterly lea k detectio n period s with th e percentage o f valve s leakin g equa

l to o r les s tha n 2.0 , th e Permittee ma

y begi n t o skip on e o f th e quarterly lea

k detectio n period s fo r

th e valve s i n VHA P service . (e ) Afte r fiv e consecutiv e quarterly lea k detectio n period s wit

h th e percentage o f valve s leakin g equa

l to o r les s tha n 2.0 , the Permittee ma

y begin t o ski p thre e o f th e quarterly lea

k detectio n period s fo r

th e valve s i n VHA P service . (f ) I f th e percentage o f

valve s leakin g i s greate

r tha n 2.0 , th e Permittee shal l compl y wit

h th e requirement s a

s described i n 4 0 C.F.R . § 61.242-7 , bu t ma y agai n elec t

t o us e 4 0 C.F.R . § 61.243-2 .Veoli a E S Technica l Solutions , L.L.C . Pag e 14 3 o f 17 2 Penni tNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T ExpirationDate : DRAF T (D ) Monitorin

g an d Testin g [4 0 C.F.R . § 71.6(a)(3)(i)(A) ] 1 . Th e Permittee shal l compl y wit h th e followin g tes t

method s andprocedure s requirements o f

4 0 C.F.R . § 61.245 : (a ) Th e Permittee shal l monitor , a s require di n 4 0 C.F.R . § § 61.242 , 61.243 , 61.244 , an

d61.135 , as follows : (i ) Th e Permittee shal l monitor a s require db y Metho d2 1 o f 4 0 C.F.R . Par t 60 , Appendi x A . (ii ) Th e detectio n instrumen

t shal l mee

t th e performanc e criteri ao f Metho d21 . (iii ) The instrumen

t shal l b e calibrate dbefor

e us e on eac

h da y o f its use by th e procedure s specifie di n Metho d21 . (iv ) Calibratio n gase s shal l be : A . Zero ai r

(les s tha n 1 0 ppmo f

hydrocarbo n i n air) ; and B . A mixtur e o f

methan e or n-hexan e an dai r a t aconcentratio n o f approximately , bu

t les s than , 10,000 ppmmethan e or n-hexane . (v ) Th e instrumen

t prob e shal l b e traverse daroun dal l potential lea

k interface s a

s clos e t o th e interfac e a

s possible , a

s describe di n Metho d2 1 o f

4 0 C.F.R . Par

t 60 , Appendi x A . (b ) Whe

n equipmen

t i s teste d fo r

complianc e wit h o

r monitore dfo r

n o detectabl e emissions , th

e Permittee shal l compl y with th e followin g requirements : (i ) Th e Permittee shal l test

equipmen

t a s require db y 4 0 C.F.R . § 61.245(b)(1 ) through (4) . (ii ) Th e backgroun dleve l shal l b e determined , a

s se t fort h i n Metho d2 1 o f 4 0 C.F.R . Par

t 60 , Appendi x A . (iii ) The instrumen

t prob e shal l b

e traverse daroun

dal l potentia

l lea k interface s a

s clos e t o th e interfac e a

s possibl e a

s describe di n Metho d 2 1 o f 4 0 C.F.R . Par

t 60 , Appendi x A . (iv ) The arithmeti c differenc e betwee n th e maximu mconcentratio n indicate db y the instrumen t an dth e backgroun dleve l i s compared wit h 50 0 pp mfo r

determinin g compliance .



### VES01760 5Veoli a E S Technica l Solutions , L.L.C . Page 14 4 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T ExpirationDate : DRAF T

(c) Eac h piec e o f

equipmen

t withi n aproces s uni t

tha t ca n conceivabl y contai n equipmen t i n VHA P servic e i s presumed t o b e i n VHA P servic e unles s th e Permitte e demonstrate s tha t th e piec e o f equipmen

t i s not i n VHA P service . Fo r apiec e o f

equipmen

t t o be considere d not

i n VHA P service , i t

mus t be determine d tha

t th e percen t VHA P conten

t ca n b e reasonably expected neve r t o excee d 1 0 percen

t by weight . Fo r

purpose s o f

determinin g th

e percen t VHA P conten

t ofth e proces s flui dtha

t i s containe d i n or

contact s equipment , th

e Permittee shal l us e procedure s tha t confor mt o th e methods describe di n AST M Metho dD-226 7 (incorporate d b y referenc e a s specifie d in40C.F.R . §61.18) . (d ) Th e Permittee ma

y us e engineerin g judgment rathe r tha n th e procedure s i n 4 0 C.F.R . § 61.245(d)(1 ) t o demonstrat

e tha t th e percen t VHA P conten

t doe s not excee d 1 0 percen

t b y weight , provide dtha t the engineerin g judgmen t demonstrate s tha

t th e VHA P conten

t clearl y doe s not

excee d 1 0 percen t b y weight . Whe n th

e Permitte e an

d th e Administrato r

do no t agre e o n whethe

r apiec e o f

equipmen

t i s no t i n VHA P service , however , th e Permitte e shal l us

e the procedure s i n 4 0 C.F.R . § 61,245(d) ( 1) . (e ) I f th e Permittee determine s tha t apiec e o f

equipmen

t i s i n VHA P service , th e determinatio n ca

n be revise d onl y after

followin g th

e procedure s i n paragraph 4 0 C.F.R . § 61.245(d)(1) . (f ) Sample s used i n determinin g th e percen t VHA P conten

t shal l be representative ofth e proces s flui dtha t i s containe d i n o

r contact s th

e equipmen t o r th e ga s bein g combusted i n th

e flare. 2 . Requirement s o f

4 0 C.F.R . §61.246 : (a ) The Permittee ma

y compl y wit

h th e recordkeepin g requirement s fo r multipl e proces s unit s subjec t t o th e provision s o f

40 C.F.R . Par

t 61 , Subpar t V , i n on e recordkeepin g systemi f th e syste midentifie s eac

h record b y eac h proces s unit . (b ) Whe n eac

h lea k i s detected a

s specifie di n 4 0 C.F.R . § § 61.242-2 , 61.242

- 3 , 61.242-7 , an

d 61.242-8 , th

e followin g requirement s apply : (i ) Th e Permittee shal l attac h aweatherproo f

an dreadil y visibl e identification , marke d with the equipmen t identificatio n number, t

o th e leakin g equipment : (ii ) Th e Permittee ma

y remove th e identificatio n on avalv e after i t ha s monitore dth

e valv e fo r

2 successiv e month s a

s specifie di n 4

0Veoli a E S Technica l Solutions , L.L.C . Pag e 14 5 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T ExpirationDate : DRAF T C.F.R . § 242-7(c ) andno lea k ha s bee n detecteddurin g those 2 months . (iii ) Th e Permittee ma

y remov e th

e identificatio n o n equipment , excep t on avalve , afte

r i t ha s repaire dth

e equipment . (c ) Whe n th

e Permitte

e ha s detectedeac

h lea k a s specifie di n 4 0 C.F.R . § § 61.242-2 , 61.242-3 , 61.242-7 , 61,242-8 , an d61.135 , th

e Permittee shal l recor dth e followin g informatio n i n alo g an dshal l kee

p th e informatio n fo r 2 years i n areadil y accessibl e location : (i ) Th e instrumen

t an doperato r identificatio n numbers an dth e equipmen t identificatio n number ; (ii ) Th e dat

e th e lea k was detecte

dan dthe date s o f

eac h attemp t t o repair th e leak ; (iii ) Repair

methods applie di n eac

h attemp t t o repair th e leak ; (iv ) "Abov e 10,000 " i f

th e maximu minstrumen

t readin g measure

db y th e methods specifie di n 4 0 C.F.R . § 61.245(a ) afte r eac h repai r attemp t i s equa l to o r greate r tha n 10,00 0 ppm ; (v ) "Repai r

delayed " andth

e reason fo r

the dela y i f alea k i s no t repaire d withi n 1 5 calenda

r day s after

discover y o f th e leak ; (vi ) Th e signatur

e ofth e responsibl e officia l whos e decisio n i t was tha t repai r coul dno t

be affecte dwithout

aproces s shutdown ; (vii ) Th e expecte ddat e o f successfu l repair

o f th e lea k i f alea k i s no t repaire dwithi n 1 5 calenda r days ; (viii ) Date s o f

proces s uni t

shutdown s tha

t occu r whil e th e equipmen

t i s unrepaired ; and (ix ) Th e dat e o f successfu l repai

r ofth e leak . (d ) The Permittee shal l recor di n alo g an

dkee p i n areadil y accessibl e locatio n th e followin g informatio n pertainin g t o al l equipmen

t t o whic h astandar

d applies : (i ) A lis t

o f identificatio n number

s fo r equipmen

t (excep t welde d fittings ) subject

to th e requirement s o f

4 0 C.F.R . Par

t 61 , Subpar

t V ;Veoli a E S Technica l Solutions , L.L.C . Pag e 14 6 o f 17 2 Permi tNo. : V-1L-)716300103-2014-1 0 Issuanc e Date : DRAF T Expiratio n Date : DRAF T (ii ) A lis t o f identificatio n numbers fo r equipmen

t tha t th e Permittee elect s t o designat

e fo r no detectable emission s a s indicate db y a

n instrumen t readin g o f

les s tha n 500 pp mabove background ; (iii ) Th e designatio n ofthi s equipmen t fo r no detectable emission s shal l b e signe db y aresponsibl e official ; (iv ) The date s o f

each complianc e test

require di n 4 0 CF.R . § § 61.242

- 2(e) , 61.242-3(i) , 61.242-4 , an d61.242-7(f) ; (v ) The backgroundleve l measureddurin g eac h complianc e test ; an

d (vi ) Th e maximu minstrumen t readin g measureda

t th e equipmen

t durin g eac h complianc e test . (e ) Th e Permittee shal l recor di n alo g an

dkee p i n areadil y accessibl e locatio n th e followin g informatio n pertainin g t o al l valve s subject

t o th e requhements o f

4 0 C.F.R . § 61.242-7(g ) an d(h ) andt o al l pump s subjec t

t o th e requirements o f

4 0 C.F.R . § 61.242-2(g) : (i ) A lis t

o f identificatio n numbers fo r valve s an

dpump s tha

t ar e designateda

s unsaf e to monitor , a

n explanatio n fo r

eac h valv e or pum p statin g wh y th

e valv e o r pum p i s unsaf

e t o monitor , an

dth e pla n fo r monitorin g eac

h valv e o r pump ; and (ii ) A lis t

o f identificatio n number

s fo r valve s tha

t ar e designateda

s difficul t to monitor , a

n explanatio n fo r

eac h valv e stating why th

e valv e i s difficul t

t o monitor , an

dth e planne dschedule fo r

monitorin g eac h valve . (f ) Th e Permittee shal l recor dandkee p i n areadil y accessibl e locatio n th e followin g information : (i ) Desig n criterio n require di n 4 0 C.F.R . § § 61.242-2(d)(5 ) an d61.242

- 3(e)(2) , an

da n explanatio n o f

th e desig n criterion ; an

d (ii ) An y change s t o thi s criterio n an dthe reason s fo r

th e changes . (g) Hour s o f

operation o f

eac h component . (h ) Emission s o f

VOC . (E ) Recordkeepin

g an d Reportin

g [4 0 C.F.R . § 71.6(a)(3)

]Veoli a E S Technica l Solutions , L.L.C . Pag e 14 7 o f 17 2 Permi tNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T ExpirationDate : DRAF T

1 . The Permittee shal l promptl y notify the permittin g authorit y o f deviation s o f

th e affecte dleakin g equipmen t fro mth e permit requirements . Report s shal l describ e th e probable caus e o f

suc h deviations , an

d an y correctiv e action s or

preventiv e measure s taken . [4

0 C.F.R . § 71.6(a)(3)(iii)(B) ] 2 . Requirement s o f

4 0 C.F.R . § 61.247 : (a ) The Permittee shal l submit astatemen

t i n writin g notifyin g th

e Administrato r

tha t i t i s implementin g th

e requirements o f

4 0 C.F.R . § § 61.242 , 61.245 , 61.246 , and 61.247 . (b ) I n th e cas e o f a n existin g sourc e o

r ane w sourc e whic h ha

s a n initia l startu p dat e precedin g th

e effectiv e date , th

e Permitte e shal l submit

th e statemen t t o th e Administrato r

alon g wit

h the informatio n require d unde r 4 0 C.F.R . § 61.1 0 withi n 90 day s ofth e effectiv e date , unles s awaiver o f complianc e i s grante

d unde r 4 0 C.F.R . § 60.11 . I f

awaiver o f complianc e i s granted , th

e Permitte e mus t

submit th e statemen

t o n adat e schedule d b y th e Administrator . (c ) The Permittee must includ e tli e followin g informatio n fo r eac h sourc e i n th e statement : (i ) Equipmen

t identificatio n numbe

r an d proces s unit

identification ; (ii ) Typ e o f

equipmen

t (fo r example , apum

p o r pipelin e valve) ; (iii ) Percen

t by weigh

t VHA P i n th

e flui da t th e equipment ; (iv ) Proces s flui dstat

e a t th e equipmen

t (gas/vapo

r o r liquid) ; and (v ) Metho do f

complianc e with th

e standar d (fo r example , "monthl y lea k detectio n an

d repair " or

"equippe d with dua

l mechanica

l seals") . (d ) The Permittee shal l submit t o th e Administrato r

areport , semiannually startin g 6 month s after

th e initia l repor

t require d i n 40 C.F.R . § 61.247(a) , tha t include s th

e followin g information : (i ) Proces s uni t

identification ; (ii ) Fo r eac h mont h durin g th

e semiannua

l reportin g period : A . Numbe

r o f valve s fo r

whic h leak s wer

e detecte d a s describe d i n 4 0 C.F.R . § § 61.242-7(b ) o r 61.243-2 ;Veoli a E S Technica l Solutions , L.L.C . Page 14 8 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T ExpirationDate : DRAF T B . Numbe r o f valve s fo r

whic h leak s wer

e no t repaire d a

s require d in40C.F.R . § 61.242-7(d) ; C . Numbe

r o f pump s fo r

whic h leak s wer

e detecte d a s describe d i n 4 0 C.F.R . § 61.242-2(b ) an d(d)(6) ; D : Numbe

r o f pump s fo r

whic h leak s wer

e no t repaire das require di n 4 0 C.F.R . § 61.242-2(c ) an d(d)(6) ; E . Number

o f compressors fo r

whic h leaks wer

e detected a

s describe di n 4 0 CF.R . § 61.242-3(f) ; F . Numbe

r o f compressors fo r

whic h leaks wer

e no t repaire da

s require di n 4

0 C.F.R . § 6I.242-3(g);.an d G . Th e fact s tha

t explai n an

y dela y o f repairs and , wher

e appropriate , wh y aproces s uni t shutdown wa

s technicall y infeasible . 2.1 0 INSIGNIFICAN T EMISSIO N UNIT S AN D ACTIVITIE S (A ) Lis to f Insignifican

tEmissio

n Unit s an d Activitie

s [4 0 CF.R . § 71.5(c)(ll) ] Th e followin g ar

e insignifican t

emissio n unit s andactivitie s a t th e facility : 1 . One 2. 5 mmBtu/h

r Tiog aportabl e boiler ; 2 . One horizonta

l 550-gallo n kerosen

e tank ; 3 . Tw o horizonta

l 550-gallo n No . 2 diese l fue l tanks ; 4 . As h handling ; 5 . Handlin g o f

spen t dry scrubbe

r solids ; 6 . Lim e unloadin g andproportioning ; 7 . Gasolin e storage an ddispensing ; 8 . Us e o f

absorben t material ; 9 . Genera

l vehicl e maintenanc e an dservicin g (assumedt

o include diese l fue l handling) ; 10 . Laborator

y (chemica

l an dphysica l analysis) ; 11 . Pipin g an

dstorag e syste mfo r natura l gas ; 12 . Non-halogenated col dcleanin g degreasers ; 13 . Interna l combustio n engine s o f

moto r vehicles ; an d 14 . Storag e an dhandlin g o f

close ddrums .Veoli a E S Technica l Solutions , L.L.C . Pag e 14 9 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T Expiratio n Date : DRAF T (B) Applicabl

e Requirement

s [4 0 C.F.R . § 71.6(a)(1)

] 1 . Fo r eac h particulat

e matte r proces s emissio n unit , the Permittee shal l compl y wit h th e applicabl e particulat

e matte r emissio n limi t

o f 3 5 IA C 212.32 1 o

r 212.32 2 an

d3 5 IA C Par

t 266 . Fo r

example , th

e particulat

e matte r emission s fro maproces s emissio n uni t shal l not excee d0.5 5 pound s pe

r hou r i f th e emissio n unit' s proces s weigh t rat e i s 10 0 pound s pe

r hou r o r less , pursuan

t t o 3 5 IA C 266.110 . [3 5 IA C 212.32 1 or 212.32 2 an

d3 5 IA C Par

t 266 ] 2 . Fo r eac h organi c materia

l emissio n uni t

tha t uses organi c material , e.g. , amixer o r printin g line , th

e Permitte e shal l compl y wit h the applicabl e VO M emissio n limi t o f 3 5 IA C 215.301 , whic h require s tha t organi c materia

l emission s no

t exceed8. 0 pounds pe

r hou r or , i f n o odo r nuisanc e exists , d

o no t qualif y a s photochemicall y reactiv e materia l a s define di n 3 5 IA C 211.4690 . [3 5 IA C 215.301 ] 3 . Fo r eac h ope n burnin g activity , th

e Permitte e shal l compl y wit h 3 5 IA C Par

t 237 , includin g th

e requiremen

t t o obtai n apermit

fo r ope n burnin g i n accordanc e wit h 3 5 IA C 237.201 , i f

necessary . [3 5 IA C Par

t 237 ] (C) Complianc

e wit h Applicable Requirement s [4 0 C.F.R . § 71.6(a)(3)

] 1 . Th e Permittee shal l kee p curren t afile fo r th e affecte dinsignifican t

emissio n units , whic h ma

y contai n estimatedemissions , throughput , inspection , maintenance an

drepair log , andothe

r informatio n necessar

y t o demonstrat

e complianc e with the applicabl e requirement s andclassificatio n o f th e unit s a s insignifican t

emission s units . [4

0 C.F.R . § 71.6(a)(3)(i)(B) ] 2 . The Permittee must

maintai n record s o f

result s o f

an y emission s testin g conducte don th e affecte demissio n units . [4 0 C.F.R . § 71.6(a)(3)(i)(B) ]Veoli a E S Technica l Solutions , L.L.C . Pag e 15 0 o f 17 2 Permi tNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T ExpirationDate : DRAF T 

## 3. 0 FACILITY-WID E PERMI T REQUIREMENT S 3.1 . GENERA L PAR T 7 1 RECORDKEEPIN G (A ) Require

d Record

s [4 0 C.F.R . § 71.6(a)(3)(ii) ] Th e Permittee shal l kee

p record s o f

require dmonitorin g informatio n tha t include the following : 1 . The date , place , an

d tim e o f samplin g o

r measurements ; 2 . The date(s ) analyse s wer e performed ; 3 . Th e compan y o r entit y tha t performe dth

e analyses ; 4 . The analytical technique s or method s used ; 5 . Th e result s o f

suc h analyses ; an

d 6 . Th e operatin g condition s existin g a t th e tim e o f samplin g o

r measurement . (B ) Recor d Retentio

n Schedul

e [4 0 C.F.R . § 71.6(a)(3)(ii) ] Th e Permittee shal l retain record s o f al l require d monitorin g dat aan d suppor t informatio n fo r

aperio do f

a t leas t 5 calenda

r year s fro mthe dat

e o f th e monitorin g sample , measurement, report , or application . Suppor

t informatio n includes , bu t i s no t limite dto , al l calibratio n an d maintenanc e records , al l origina l strip-char t recording s fo r

continuou s monitorin g instrumentation , and copie s o f al l reports requiredb y thi s permit . (C ) Emission

s Calculatio

n Methodolog

y [4 0 C.F.R . § 71.6(a)(3)(i)(B) ] 1 . I f a n applicabl e requiremen

t containe d i n thi s permi t

doe s no t requir e th e us e o f a specifi c methodolog y fo r calculatin g emissions , th e Permitte e must

follo w th e followin g hierarch

y (i n orde r o f preference ) whe

n selectin g th

e appropriat

e methodolog y fo r

calculatin g emissions : (a ) CE M dat

afro mth e stationar

y source ; (b) Performanc e test

dat afro mth e stationar

y source ; (c ) Manufacturer' s emission s performanc e guarantee ; (d ) CE M dat

afro masimilar

stationar y sourc e or

sources ; (e ) Performanc e tes

t dat afro masimila

r stationar y sourc e o

r sources ; (f ) Industry-derive d emissio n factors ;Veoli a E S Technica l Solutions , L.L.C . Pag e 15 1 o f

17 2 Permi tN o : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T ExpirationDate : DRAF T

(g ) Emissio n factor s publishe di n the lates t versio n o f

EPA' s Compilatio n o f Ai r Pollutant Emissio n Factor s (AP-42) , with "A"-rate dAP-4 2 emissio n factor s bein g considere dbefor e th e lowe r rate demissio n factors ; (h ) Engineerin g judgment . 2 . The Permittee must

documen t tha t i t reviewe dth

e hierarch

y i n conditio n 3.1(C)(1) , above , befor

e selectin g th

e emission s calculatio n methodolog y includin g ademonstratio n ofth e selectedemissio n factors ' appropriatenes s fo r th e specifi c emissio n unit s fro mwhic h emission s ar e bein g calculated . 3 . Th e Permittee' s choic e o f emissio n calculatio n methodolog y pursuan t t o conditio n 3.1(C)(1) , above , doe s no t preclude an

y person , suc h a

s EPA , th e publi c andothe

r regulator y agencies , fro musin g othe r credibl e evidenc e to establis h complianc e o

r noncomplianc e wit h applicabl e requirements a s provide d b y th e Act . [4 2 U.S.C . § 7413 ] 3.2 . GENERA L PAR T 7 1 REPORTIN G [4

0 C.F.R . § 71.6(a)(3)(iii) ] (A ) Semi-annua

l Report s 1 . The Permittee shal l submi t t o EP A semi-annua

l report s o f

al l require d monitorin g eac

h si x mont

h reportin g perio dfro mJanuar y 1 to Jun

e 3 0 an dfro m Jul y 1 t o Decembe

r 31 . Al l reports shal l b

e submitte dt

o th e EP A an dshal l b e postmarkedb y th

e 30t h da y followin g th

e endofth e reportin g period . Al l instance s o f

deviation s fro mpermit

requirements must

b e clearl y identifie di n suc h reports . Al l require dreports must be certifie db y aresponsibl e officia l consisten t with conditio n 4.8(A)(1 ) ofthi s permit . [4 0 C.F.R . §71.6(a)(3)(iii)(A) ] 2 . A monitorin g repor

t submitte dpursuan

t t o conditio n 3.2(A)(1 ) mus t includ e th

e following : (a ) Th e compan

y nam e an daddress ; (b ) The beginnin g andendin g date s o f th e reportin g period ; (c ) Th e emission s uni t

o r activity bein g monitored ; (d ) Th e emission s limitatio n or standard , includin g operationa l requirements an dlimitation s (suc h a

s paramete

r ranges) , specifie di n th

e permit fo r whic h complianc e i s bein g monitored ; (e ) Al l instance s o f

deviation s fro mpermit

requirements whethe

r demonstrated by reference dtes t

method , monitoring , o

r through an

y othe r credibl eVeoli a E S Technica l Solutions , L.L.C . Page 15 2 o f 17 2 Peimi tNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T Expiratio n Date : DRAF T

evidence , includin g thos e attributabl e t o upse t condition s as define di n thi s permit , an

dth e dat e on whic h eac h deviatio n occurred ; (f ) Th e tota

l time whe

n monitorin g require db y thi s penni t wa s no t performe d durin g th e reportin g perio dand , a

t th e source' s discretion , eithe r th e tota l duratio n o f

deviation s indicate db y such monitorin g o r th e actua l record s o f deviations ; (g) Al l othe

r monitorin g results , data , or analyse s require dt

o be reportedb y th e applicabl e requirement ; an d (h ) Th e name , title , an

dsignatur e o f th e responsibl e officia l who i s certifyin g t o th e truth , accuracy , andcompletenes s ofth e report . (i ) An y repor

t require db y a

n applicabl e requiremen

t tha t provide s th

e sam e informatio n describe di n condition s 3.2(A)(2)(a ) through (h) , above , shal l satisf y th e requiremen

t unde r conditio n 3.2(A)(1) . [4 0 C.F.R . § 71.6(a)(3)(iii)(A) ]
(B) Deviation

s 1 . "Deviation " mean s an y situatio n i n whic h a

n emission s unit

fail s t o mee t a permi t ter mor condition . A deviatio n i s not alway s aviolation . A deviatio n ca n b e determine db y observatio n o r through revie w o f

dat aobtainedfro man

y testing , monitoring , o

r recor dkeepin g establishedi n accordanc e with 4 0 C.F.R . § 71.6(a)(3)(i ) an

d(ii) . Fo r

asituatio n lastin g mor

e tha n 2 4 hours , eac

h 24-hou r perio di s considere daseparat e deviation . "Deviations " includes , bu t i s no t limite dto , an

y ofth e following : [40 C.F.R . § 71.6(a)(3)(iii)(C) ] (a ) A situatio n whe

n emission s excee da

n emissio n limitatio n o

r standard ; (b) A situatio n wher

e proces s o

r emission s contro l devic e paramete r value s indicat e tha t a n emissio n limitatio n o

r standar dha s no t bee n met ; an d (c ) A situatio n i n whic h observation s o r dat acollecte ddemonstrate s noncomplianc e wit

h a n emissio n limitatio n or

standar do r an y wor k practic e o r operating conditio n require db y th e permit . 2 . The Permittee shal l promptl y repor t t o th e EP A deviation s fro mpermit requirements , includin g thos e attributedt o malfunction , emergency o r othe r upse t conditions , th

e probabl e caus e o f

suc h deviations , andan

y correctiv e action s o r preventiv e measure s taken . "Prompt " i s define da s follows : [40C.F.R.§71.6(a)(3)(iii)(B) ]Veoli a E S Technica l Solutions , L.L.C . Pag e 15 3 o f 17 2 Permi tNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T ExpirationDate : DRAF T

(a ) An y definitio n o f

"prompt " or

specifi c timeframe fo r

reportin g deviation s provide di n a

n underlyin g applicabl e requiremen t (a s identifie di n thi s permit) ; o

r (b ) Wher

e th e underlyin g applicabl e requiremen t doe s no t defin e promp

t o r provide atimeframe fo r

reportin g deviations , report s o f deviation s wil l b

e submittedbase

do n the followin g schedule : (i ) Fo r emission s o f

ahazardou s air

pollutant o r atoxi c ai r pollutant (a s identifie di n a

n applicabl e regulation ) tha t continu e fo r

mor e tha n a n hou r i n exces s o f

permi t requirements , th

e repor t must b e mad e withi n 2 4 hour s o f

th e occurrence . (ii ) Fo r emission s o f

an y regulate dpollutant

excludin g ahazardou s ai r pollutan t o r atoxi c ai

r pollutant tha t continu e fo r

mor e tha n tw o hour s i n exces s o f

permit requirements , th

e repor t must b e mad e withi n 4 8 hours . (iii ) Fo r al l othe r deviation s fro mpermit

requirements , th

e repor t shal l b e submittedwit h th

e semi-annua

l monitorin g repor

t require di n conditio n 3.2(A)(1 ) ofthi s permit . 3 . I f an y ofth e requirements i n conditio n 3.2(B)(1)(a ) through (c) , above , ar

e met , th e Permittee mus

t notif y EP A b y telephone o

r facsimil e basedo n th

e timetabl e listed . A written notice , certifie dconsisten t wit h conditio n 4.8(A) , must b e submittedwithi n 1 0 workin g day s ofth e occurrence . Al l deviation s reported unde r thi s conditio n mus t

als o b e identifie di n th

e semi-annua

l repor t require d unde r conditio n 3.2(A)(1) , above . 3.3 . PERFORMANC E TESTIN G [4 0 C.F.R . § 71.6(a)(3)(i)

] Th e Permittee shal l provide performanc e testin g facilitie s tha t includ e th

e following : (A ) Samplin g port s adequat e fo r th e applicabl e test

methods ; (B ) Saf e samplin g platform(s) ; (C ) Saf e acces s t o samplin g platform(s) ; an d (D ) Utilitie s fo r

samplin g an

dtestin g equipment .Veoli a E S Technica l Solutions , L.L.C . Pag e 15 4 o f 17 2 Permi tNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T ExpirationDate : DRAF T 3.4 . FACILITY-WID E APPLICABL E REQUIREMENT S (A ) Fugitiv e Particulat

e Matte r Restriction

s [3 5 IA C 212.301] Th e Permittee shal l no

t caus e o r allo w th e emissio n o f

fugitiv e particulat

e matte r fro man y process , includin g an

y material handlin g or

storag e activit

y tha t i s visibl e b y a n observe r lookin g generally towar

d th e zenit h a t apoin t beyondth

e propert y lin e o f th e emissio n source . (B ) Ope n Burning Prohibition

s [3 5 IA C 237.102

] 1 . The Permittee shal l not caus e or allo w ope

n burning , except

a s provide di n 3 5 IA C 237 . 2 . Th e Permittee shal l not caus e or allo w ope

n burnin g o f

any refus e i n an

y chambe r o r apparatus , unles s suc h chambe r or apparatu s i s designe d fo r th e purpos e o f

disposin g o f

th e clas s o f refus e bein g burned . (C ) Visible Emission

s [3 5 IA C 212.123(a)

] The Permittee shal l no t

caus e or allo w th e emissio n o f

smok e o r othe r particulat

e matter, wit

h a n opacit y greate r tha n 3 0 percent , into th

e atmospher

e fro man

y emissio n unit

othe r tha n thos e emissio n unit s subjec t t o th e requirements o f

3 5 IA C 212.122 , excep

t a s allowe db y 3 5 IA C 212.123(b ) an d 3 5 IA C 212.124 . (D ) Recyclin

g an d Emission

s Reductio

n [4 0 C.F.R . Par

t82 , Subpar tF ] Th e Permittee shal l compl y with th e standards fo r

recyclin g an

d emission s reductio n o f ozon e depletin g substance s pursuan t to 4 0 C.F.R . Par

t 82 , Subpar

t F , except a s provide dfo r

moto r vehicl e air

conditioner s i n 4 0 C.F.R . Par t 82 , Subpar

t B : 1 . Person s opening appliance s fo r maintenance , service , repair , o r disposa l mus t compl y wit

h th e require d practice s pursuan t t o 4 0 C.F.R . § 82.156 . 2 . Equipmen

t use d durin g th

e maintenance , service , repair , or disposa l o f appliance s mus

t compl y wit h th

e standards fo r

recyclin g an

d recover y equipmen

t pursuan t t o 4 0 C.F.R . § 82.158 . 3 . Person s performin g maintenance , service , repair , o r disposa l o f appliance s must b e certifie db

y a n approve d technicia

n certificatio n progra

mpursuan

t t o 4 0 CF.R . § 82.161 .Veoli a E S Technica l Solutions , L.L.C . Pag e 15 5 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T ExpirationDate : DRAF T (E) Risk Managemen

tPla n (RMP ) [4 0 C.F.R . § 68.215(a)(2)(i ) an d (ii) ] Shouldthi s stationar

y source , a

s define di n 4 0 C.F.R . § 68.3 , becom e subjec t t o th e federa l regulation s fo r

Chemica l Acciden t

Preventio n i n 4

0 CF.R . Par

t 68 , the n th e Permittee shal l submit

th e item s below : 1 . A complianc e schedul e fo r meetin g th

e requirements o f

4 0 C.F.R . Par

t 6 8 b y th e dat e provide di n 4 0 C.F.R . § 68.10(a) ; o r 2 . A certificatio n statemen t tha t th e sourc e i s i n complianc e with al l requirements o f 4 0 C.F.R . Par

t 68 , includin g th

e registratio n an

d submissio n o f

th e RMP , a s par t o f th e annua l complianc e certification . (F) Episod

e Actio n Plan s [3 5 IA C 244

, Subpar tC ] The Permitte

e shal l maintai n a

t th e sourc e an

d hav e o n file with th

e IEP A awritten episod e actio n plan (plan ) fo r

reducin g th

e level s o f

emission s durin g yello w alerts , redalerts , an

d emergencies , consisten t with saf e operatin g procedures . Th e pla n shal l contain th

e informatio n specifie di n 3 5 IA C 244.144 an d i s incorporate d b y referenc e int

o thi s permit . (G ) Annua l Benzen e Wast e Quantit

y Determinatio

n [4 0 C.F.R . § 61.355

] Th e Permittee shal l determin e th e tota l annua l benzen e quantit y fro mfacilit y wast

e b y th e followin g procedure : 1 . Fo r eac h wast e strea msubjec t

t o 4 0 C.F.R . Par

t 61 , Subpar

t FF , havin g aflo w weightedannua

l average wate

r conten t greate r tha n 1 0 percen

t water , on a volum e basi s a s total water , o

r whic h i s mixe dwith wate r o r othe r waste s a t an y tim e an d th e resultin g mixture has a n annua l average wate

r conten t greate r tha n 1 0 percen t a s specifie di n 4 0 C.F.R . § 61.342(a) , th e Permittee shall : (a ) Determine th

e annua l wast e quantit y fo r eac h wast e strea musin g th

e procedure s specifie di n 4 0 CF.R . § 61.355(b) . (b ) Determine th

e flow-weighted annua

l average benzen

e concentratio n fo r eac h wast e strea musin g th e procedure s specifie di n 4 0 CF.R . § 61.355(c) . (c ) Calculate th

e annua l benzen e quantit y fo r eac h wast e strea mb y multiplyin g th e annua l wast e quantit y o f th e wast e strea mtime s th

e flow-weighted annua l average benzen

e concentration . (d ) Total annua

l benzen e quantit y fro mfacilit y wast

e i s calculate db y adding togethe r th e annua l benzen e quantit y fo r eac h wast e strea mgenerate

dVeoli a E S Technica l Solutions , L.L.C . Page 15 6 o f 17 2 Permi tNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T ExpirationDate : DRAF T

durin g the yea

r an d th e annua l benzen e quantit y fo r eac h proces s uni t turnaround wast

e annualize d accordin g t o 4 0 C.F.R . § 61.355(b)(4) . 2 . I f th e total annua

l benzen e quantit y fro mfacilit y wast

e i s equa l to o r greate r tha n 1 0 megagra

mpe r yea r (1 1 ton/yr) , the

n th e Permittee shal l compl y with th e requirements o f

40 C.F.R . § 61.342(c) , (d) , o r (e) . (H ) Genera l Prohibitio

n o n Ai rPollutio

n [3 5 IA C 201.141

] N o person shal l caus e o

r threate n or allo w th e discharg e o

r emissio n o f

an y contaminan

t int o th e environmen

t i n an y Stat e so as , eithe

r alone or i n combinatio n wit h contaminant s fro mothe r sources , t

o caus e o r tend t o caus e ai r

pollutio n i n Illinois , o r

s o a s t o violate th

e provision s o f

3 5 IAC , Subtitl e B , Chapte r I , o r so a s t o preven t th e attainmen

t o r maintenanc e o f

an y applicabl e ambien

t ai r qualit y standard . [3 5 IA C 201.141 ] (I ) Facility-wid

e Testin g [4 0 C.F.R . § 71.6(a)(3)(i)

] 1 . Testin g Require db y 3 5 IA C 201.282 . Every emissio n sourc e an d al l ai r pollutio n contro l equipmen t shal l b e subject t o th e followin g testin g requirement s fo r th e purpos e o f

determinin g th

e natur e an d quantitie s o f

specifie dai

r contaminan

t emission s an

d fo r th e purpos e o f determinin g groun

d leve l and ambien

t ai r concentration s o f

such ai r contaminants : (a ) Testin g b y th

e Per mittee . Th e IEP A ma

y requir e th e Permitte e t

o conduct tests i n accordanc e wit h procedure s adopte d b y th e IEPA , a t such reasonable time s a

s ma y b e specifie dby th

e IEP A an d a

t th e expens e ofth e Permittee . Th e IEP A ma y adop t procedure s detailin g methods o f testin g an dformat s fo r

reportin g result s o f

testing . Suc h procedure s an d formats , an drevision s thereto , shal l not becom e effectiv e unti l file dwit h th e Inde x Divisio n ofth e Offic e o f th e Secretar

y o f Stat e a s Require db y "A n Ac t concernin g administrativ e rules, " approve d Jun e 14 , 1951 , a

s amended . Al l suc h tests shal l be mad

e b y or unde r th e directio n o f

aperso n qualifie db y trainin g and/o

r experienc e i n th

e fieldo f air pollutio n testing . The IEP A shal l have th

e right t o observe al l aspect

s o f suc h tests . (b ) Testin g b y th

e IEPA . Th e IEP A shal l have th e righ t t o conduct such tests a t any tim e a t it s ow n expense . Upo n request ofth e IEPA , th

e Permittee shal l provide , withou t

charge t o th e IEPA , necessar

y hole s i n stack

s o r duct s and othe

r saf e an d prope r testin g facilities , includin g scaffolding , bu t excludin g instrument s and sensin g devices , a s ma y be necessary .Veoli a E S Technica l Solutions , L.L.C . Pag e 15 7 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T ExpirationDate : DRAF T

2 . Determinatio n o f

annua l benzen e wast e quantit y fo r off-sit e waste s [4

0 C.F.R . § 61.355 ] (a ) The determinatio n o f annua l benzen e wast e quantit y fo r th e off-sit e waste s receive db y th

e Permitte e shal l be mad

e b y usin g th

e method s an

d procedure s establishe d i n 4 0 CF.R . § 61.35 5 alon g with th e following : (b) Forth e purpose s ofth e calculatio n require dby 4 0 C.F.R . § 61.355(a) , th e Permitte e shal l determine th e flow-weighte dannua

l average benzen

e concentratio n i n amanne r tha t meet s th e requirement s give n i n 4 0 C.F.R . § 61.355(c)(1 ) usin g eithe r ofth e method s give n i n 4 0 C.F.R . § 61.355(c)(2 ) an

d (c)(3) . (i ) The determinatio n fo r waste s tha

t ar e receive d fro moffsit e shal l be mad e a t th e point wher e th e wast e enter s th e hazardou s wast

e treatment, storage , or

disposa l facility . (ii ) Knowledg e o f

th e waste . Th e Permittee shal l provid e sufficien t informatio n to documen

t the flow-weighte dannua l average benzen

e concentratio n o f

eac h wast e stream . Example s o f

informatio n tha

t coul dconstitut

e knowledg e include materia l balances , record s o f chemical s purchases , o

r previou s test

result s provide dth

e result s ar

e stil l relevan

t t o th e curren t wast e strea mconditions . I f

test dat aar e used , the n th e Permitte e shal l provide documentatio n describin g th e testin g protoco l an

d th e means b y whic h samplin g variabilit y an d analytical variabilit y wer e accounted fo r

i n th e determinatio n o f

th e flow-weighte dannua

l average benzen

e concentratio n fo r

th e wast e stream . Whe n th

e Permitte e an

d th e Administrato r

d o not agre e on determination s o f

th e flow-weighte dannua

l averag e benzen

e concentratio n based o n knowledg e o f th e waste , th

e procedure s unde r 4 0 C.F.R . § 61.355(c)(3 ) shal l b e used . (iii ) Measurement s o f

th e benzen e concentratio n i n th

e wast e strea mi n accordanc e wit h th

e followin g procedures : A . Collec t

aminimu mo f

thre e representative sample s fro meac h wast e stream . Wher

e feasible , sample s shal l be take n fro ma n enclose dpip e prio r

t o th e wast e bein g exposed t

o th e atmosphere . B . For wast e i n enclose d pipes , th

e followin g procedure s shal l be used :Veoli a E S Technica l Solutions , L.L.C . Pag e 15 8 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T Expiratio n Date : DRAF T I . Sample s shal l b e collecte dprio r

to th e wast e bein g expose d t o th e atmospher

e i n orde r t o minimiz e th

e los s o f benzen e prior t o sampling . II . A stati c mixer

shal l be installe d i n th

e proces s lin e o r

i n aby-pas s lin e unles s th

e Permitte e demonstrate s tha t installatio n o f

astati c mixe r

i n th e lin e i s no

t necessar y to accuratel y determin

e the benzen

e concentratio n ofth e wast e stream . IH . Th e Sampling ta

p shal l be locate d withi n tw o pip e diameter s o f

th e stati c mixe r

outlet . IV . Prio r

t o th e initiatio n o f

sampling , sample line s an d coolin g coi l shal l b

e purge d with a

t leas t fou r volume s o f waste . V . Afte r

purging , th

e sample flo w shal l b

e directe d to a sampl e containe

r an d th e ti p o f th e samplin g tube shal l b e kep t belo w th e surfac e ofth e wast

e durin g samplin g t o minimiz e contac

t wit h th e atmosphere . VI . Sample s shal l be collecte da t aflo w rat

e such tha

t th e coolin g coi l i s abl

e t o maintai n awast

e temperatur

e les s tha n 10° C (50°F) . VII . Afte r

filling, th e sampl e containe

r shal l be capped immediatel y (withi n 5 seconds ) t o leav e aminimu m headspac e i n th

e container . VIII . Th e sample container s shal l immediately b e coole dan d maintaine da

t atemperatur

e belo w 10° C (50°F ) fo r transfer to th e laboratory . C . Whe n samplin g fro ma n enclose d pip e i s not

feasible , a minimu mo f

thre e representativ e sample s shal l b e collecte di n a manne r t o minimiz e exposur

e o f th e sample t

o th e atmospher

e an dlos s o f benzen e prio r t o sampling . D . Eac h wast

e sampl e shal l b e analyze dusin g on

e o f th e followin g tes t

methods fo r

determinin g th

e benzen e concentratio n i n awast

e stream : I . Metho d8020 , Aromati c Volatil e Organics , i n "Tes t Method s fo r

Evaluatin g Soli dWaste , Physical/Chemica l



### VES01762 0Veoli a E S Technica l Solutions , L.L.C . Pag e 15 9 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T ExpirationDate : DRAF T Methods, " EP A Publicatio n No . SW-84 6 (incorporatio n b y referenc e a

s specifie di n 4 0 C.F.R . § 61.18) ; II . Metho d8021 , Volatil e Organi c Compound s i n Wate r b y Purg e an dTra p Capillar y Column Ga s Chromatograph y wit h Photoionizatio n andElectrolyti c Conductivity Detectors i n Series , i n "Tes t Method s fo r

Evaluatin g Soli dWaste , Physical/Chemica l Methods, " EP A Publicatio n No . SW-84 6 (incorporatio n b y referenc e a s specifie di n 4 0 C.F.R . § 61.18) ; III . Metho d8240 , Ga s Chromatography/Mas s Spectrometr y fo r Volatil e Organics , i n "Tes t Method s fo r

Evaluatin g Soli dWaste , Physical/Chemica l Methods, " EP A Publicatio n No . SW-84 6 (incorporatio n b y referenc e a s specifie di n 4 0 C.F.R . § 61.18) ; IV . Metho d8260 , Ga s Chromatography/Mas s Spectrometr y fo r Volatil e Organics : Capillar y Colum n Technique , i n "Tes t Method s fo r

Evaluatin g Soli dWaste , Physical/Chemica l Methods, " EP A Publicatio n No . SW

84 6 (incorporatedb y referenc e a s specifie di n 4 0 CF.R . §61.18) ; V . Metho d602 , Purgeabl e Aromatics , a s describe di n 4 0 C.F.R . Par

t 136 , Appendi x A , Tes t

Procedure s fo r Analysi s o f

Organi c Pollutants , fo r

wastewaters fo r whic h thi s i s a

n approve dEP A methods ; o r VI . Metho d624 , Purgeables , a s describe di n 4 0 C.F.R . Par t 136 , Appendi x A , Tes t

Procedure s fo r

Analysi s o f Organi c Pollutants , fo r

wastewaters fo r

whic h thi s i s a

n approvedEP A method . E . Th e Permittee shal l calculat e th e flow-weighte dannua

l averag e benzen e concentratio n b y averagin g th e result s ofth e sample analyse s a

s follows : C = —x 2 (QiXQ ) Qt i = i Where :Veoli a E S Technica l Solutions , L.L.C . Permi tNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T ExpirationDate : DRAF T Pag e 16 0 o f 17 2

(QiXCi ) average benzen

e concentratio n

1 .
2 . Q t = Total annua

l wast e quantit y fo r wast e stream , kg/yr (lb/yr) . n = Numbe

r o f wast e sample s (a

t least 3) . Q i = Annua l wast

e quantit y fo r wast e strea mrepresente

d b y Ci , kg/y r

(lb/yr) . C i = Measure d concentratio n o f benzen e i n wast e sample i , ppmw . :ility-wid e Recordkeepin

g [4 0 .C.F. R§ 71.6(a)(3)(i)(B) ] I f testin g i s require d b y conditio n 3.4(1) , th e Permitte e shal l kee

p record s o f

th e testing , includin g th

e test date , conditions , methodologies , calculations , test results , an

d an y discrepancie s betwee

n th e test results . Reportin g requirement s establishe d by 4 0 C.F.R . Par t 61 , Subpar

t FF : [40 C.F.R . § 61.357 ] I f th e tota l annua l benzen e quantit y fro mfacilit y wast

e i s equa l to o r greate r tha n 1 0 Mg/y r (1 1 ton/yr) , then th

e Permittee shal l submit

to th e Administrato r

th e followin g reports : (a ) Th e Permittee shal l submit annually t

o th e Administrato r

arepor t tha t update s th

e informatio n liste d i n 4 0 C.F.R . § 61.357(a)(1 ) through (a)(3) . I f th e informatio n i n th

e annua l repor t require d b y 4

0 C.F.R . § 61.357(a)(1 ) through (a)(3 ) i s not

change d i n th e followin g year , th

e Permitte e ma

y submit astatemen

t t o tha t effect . (b) Th e Permitte e mus t include th

e followin g informatio n i n th e annua l report : [4 0 C.F.R . § 61.357(a)(1 ) throug h (a)(3) ] (i ) Tota l annua

l benzen e quantit y fro mfacilit y wast

e determine d i n accordanc e wit

h 4 0 C.F.R . § 61.355(a) . (ii ) A tabl e identifyin g eac h wast e strea man d whethe r or no t th e wast e strea mwil l b e controlle dfo r

benzene emission s i n accordanc e with th e requirements o f

4 0 C.F.R . Par

t 61 , Subpar

t FF . (iii ) Fo r eac h wast e strea midentifie da

s not bein g controlle dfo r

benzen e emission s i n accordanc e with th e requirements o f

4 0 C.F.R . Par

t 61 ,Veoli a E S Technica l Solutions , L.L.C . Pag e 16 1 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T ExpirationDate: DRAF T Subpar t FF , th e Permittee shal l ad

d th e followin g informatio n t o th e table : A . Whethe

r o r not th e wate r conten t o f th e wast e strea mi s greate

r tha n 1 0 percent ; B . Whethe

r o r not the wast e strea mi s aproces s wastewate r stream , product

tan k drawdown , or

landfil l leachate ; C . Annua l wast

e quantit y fo r th e wast e stream ; D . Rang e o f

benzen e concentration s fo r

th e wast e stream ; E . Annua l averag e flow-weighte dbenzen e concentratio n fo r

th e wast e stream ; an

d F . Annua l benzen

e quantit y fo r th e wast e stream . (c ) Beginnin g 3 month s after th e dat e tha t th e equipmen

t necessar y t o compl y with 4 0 CF.R . Par

t 61 , Subpar

t FF , ha s bee n certifie di n accordanc e wit h 4 0 CF.R . § 61.357(d)(1) , th e Permittee shal l submit

quarterly t

o th e Administrato r

acertificatio n tha

t al l o f th e require d inspection s have bee n carrie dou

t i n accordanc e with th

e requirement s o f

4 0 C.F.R . Par

t 61 , Subpar t FF . (d ) Beginnin g 3 month s after th e dat e tha t th e equipmen

t necessar y t o compl y with 4 0 CF.R . Par

t 61 , Subpar

t FF , ha s bee n certifie di n accordanc e with 4 0 C.F.R . § 61.357(d)(1) , th e Permittee shal l submit

arepor t quarterly t

o th e Administrato r

tha t includes : (i ) I f atreatmen

t proces s o

r wastewate

r treatmen t syste munit i s monitore di n accordanc e wit h 4 0 CF.R . § 61.354(a)(1) , the n eac h perio do f operatio n durin g whic h th e concentratio n o f

benzen e i n th e monitore dwast

e strea mexitin g th

e uni t i s equa l t o o r greate r tha n 1 0 parts pe r millio n b y weight . (ii ) I f atreatmen

t proces s o

r wastewate

r treatmen t syste muni t i s monitore di n accordanc e wit h 4 0 C.F.R . § 61.354(a)(2) , the n eac h 3

- hou r perio do f operation durin g whic h th e average valu e ofth e monitore dparamete

r i s outside th

e range o f

acceptabl e value s o

r durin g whic h th

e unit i s no t operatin g a

s designed . (iii ) I f atreatmen

t proces s or

wastewate

r treatmen t syste munit i s monitore di n accordanc e wit h 4 0 CF.R . § 61.354(b) , the n eac h perio do f operatio n durin g whic h th e flow-weighte dannua

l averageVeoli a E S Technica l Solutions , L.L.C . Pag e 16 2 o f 17 2 PermitNo. : V-IL-1716300103-2014-10 . Issuance Date : DRAF T ExpirationDate : DRAF T concentration o f benzen e i n th e monitore dwast

e strea mentering th

e unit i s equa l to o r greate r tha n 1 0 ppm

w and/o r th e tota l annua l benzen e quantit y i s equa l t o o r greate r tha n 1. 0 mg/yr . (iv ) Fo r acontro l devic e monitore di n accordanc e with 4 0 C.F.R . § 61.354(c) , eac

h perio do f

operatio n monitore ddurin g whic h an y o f th e condition s establishe db y 4 0 C.F.R . § 61.357(d)(7)(iv ) occur , a s applicabl e t

o th e contro l device . (v ) Fo r acove r andclosed-ven

t syste mmonitore di n accordanc e with 4 0 CF.R . § 61.354(g) , th

e Permitte e shal l submi t

arepor t quarterly to th e Administrato r

tha t identifie s an

y perio di n whic h th

e pressur e i n th e wast e managemen

t uni t i s equa l t o or greate r tha n atmospheri c pressure . 3 . Th e Permitte e shal l submit annuall y t

o th e Administrato r

arepor t tha t summarize s al l inspection s require db y 4 0 CF.R . § § 61.34 2 throug h 61.35 4 durin g whic h detectabl

e emission s ar

e measure do r aproble m(suc

h a s abroken seal , ga p o r othe r problem ) tha t coul dresult

i n benzene emission s i s identified , includin g informatio n abou t th e repair s or

correctiv e actio n taken .Veoli a E S Technica l Solutions , L.L.C . Page 16 3 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T ExpirationDate : DRAF T 

## 4. 0 GENERA L PAR T 7 1 REQUIREMENT S 4.1 . DEFINITION S [4 0 C.F.R . § 71.2

] Term s an d condition s not

otherwis e define di n thi s permi t have th e meaning assigned t

o the mi n 4 0 C.F.R . Par

t 7 1 unles s othe

r regulation s o

r statute s ar

e referenced . 4.2 . ANNUA L FE E PAYMEN T [4 0 C.F.R . § § 71.6(a)(7

) an d 71.9 ] A . Th e Permitte e shal l pa y a n annua l permi t fe e i n accordanc e wit

h th e procedure s outline dbelow . [4

0 CF.R . § 71.9(a) ] B . The Permitte e shal l submi t a n annua l repor t o f it s actua l emission s fo r

th e precedin g calenda r year , afe e calculatio n wor k shee t (base d o n th e report) , an

d ful l paymen

t o f th e annua l fe e eac h year . The Permittee shal l submi t the annua

l repor t an d pa y th e annua l permit fe e eac h yea r o n o r befor e th e anniversar

y dat e (3 month s fro mthe issuanc e o f

thi s permit

) o f it s initia l fe e calculatio n wor k sheet . Th e Permittee shal l submi t th e annua l repor t to : Ai r Permit

s Sectio n (AR-18J

) Ai r an d Radiatio

n Divisio n EP A Regio

n 5 7 7 Wes tJackso n Boulevar

d Chicago , Illinoi

s 6060 4 C Th e fe e paymen

t shal l be i n Unite dState s currenc y an d shal l be pai db y mone

y order , ban

k draft , certifie dcheck , corporat e check , or

electroni c fund s transfe

r payabl e to th

e orde r o f th e U.S . Environmental Protectio n Agency . D . Th e Permittee shal l sen d fee paymen

t an d acomplete d fe e filing formto : U.S . Environmenta

l Protectio

n Agenc y FOI A an d Miscellaneou

s Payments

, Cincinnat

i Financ e Center , P.O . Bo x 979078 , St . Louis , M O 63197-900

0 E . Th e Permittee shal l sen

d a n updated fe e calculatio n workshee t forman d aphotocop y o f eac h fe e paymen

t chec k (o r othe r confirmatio n o f

actua l fe e paid) submitted annuall y b y th

e sam e deadline a

s require d fo r

fe e paymen

t t o th e addres s liste d i n conditio n 4.8(B ) ofthi s permit . (Th e Permitte e shoul d not

e tha t a n annua l emission s report , require d a

t th e sam e time a s th e fe e calculatio n workshee t b y 4 0 C.F.R . § 71.9(h) , ha

s bee n incorporated int

o the fe e calculatio n workshee t forma s a convenience. )



### VES01762 5Veoli a E S Technica l Solutions , L.L.C . Page 16 4 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T ExpirationDate : DRAF T F . Basi s fo r

calculatin g annua

l fee : 1 . Th e annua

l emission s fe e shal l b

e calculate d b y multiplyin g th e tota l ton s o f actua l emission s o f

al l regulated pollutant s (fo r fe e calculation ) emitted fro mth e source , includin g fugitiv e emission s b y th e presumptiv e emission s fe e (i n dollars/ton ) i n effec t

a t th e tim e o f calculation . (a ) "Actua l emissions " means th e actua l rat e o f emission s i n ton s pe

r yea r o f an y "regulate d pollutan

t (fo r fe e calculation) " emitted fro maPar t 7 1 sourc e ove

r th e precedin g calenda

r year . Actua l emission s shal l b e calculate dusin g eac h emission s unit' s actua l operating hours , productio n rates , in-plac e contro l equipment , an d type s o f material s processed , stored , o r combusted durin g th

e precedin g calenda

r year . [4 0 CF.R . § 71.9(c)(6) ] (b ) Actua l emission s shal l b e computed usin g method s required b y th e permit fo r determinin g compliance , suc h a s monitorin g o

r source testin g data . [40 CF.R . § 71.9(h)(3) ] (c ) I f actua l emission s canno

t be determined usin g th

e complianc e methods i n th e permit , th

e Permittee shal l us e othe r federall y recognize dprocedures . [40 C.F.R . § 71.9(e)(2) ] (d ) The ter

m"regulate d pollutant

(fo r fe e calculation) " i s define di n 4 0 C.F.R . §71.2 . (e ) Prio r t o th e star t o f eac h calenda r year , EP A wil l revis e fo r inflatio n rat

e an d mak e availabl e th

e presumptiv e fe e amount . 2 . The Permittee shal l exclude th e followin g emission s fro mth e calculatio n o f

fees : (a ) Th e amoun

t o f actua l emission s o f

eac h regulate d pollutan

t (fo r fe e calculation ) tha

t th e sourc e emits i n exces s o f 4,000 ton s pe

r year ; [40C.F.R.§71.9(c)(5)(I) ] (b ) Actua l emission s o f

an y regulated pollutant

(fo r fe e calculation ) alread

y include di n th

e fe e calculation ; [4

0 C.F.R . § 71.9(c)(5)(ii) ] an d (c ) The quantit

y o f actua l emission s (fo r

fe e calculation ) o f

insignifican t activitie s [define d i n 4 0 C.F.R . § 71.5(c)( l l)(i) ] o r o f insignifican t emission s level s fro memission s unit s identifie di n th e Permittee' s applicatio n [pursuan

t t o 4 0 C.F.R . § 71.5(c)( l l)(ii)] . [4 0 C.F.R . §71.9(c)(5)(iii) ]Veoli a E S Technica l Solutions , L.L.C . Pag e 16 5 o f 17 2 Peimi tNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T ExpirationDate : DRAF T G . Fe e calculatio n worksheets shal l b e certifie da

s t o truth , accuracy , and completenes s b y aresponsibl e officia l i n accordanc e with conditio n 4.8(A) . (Th e Permitte e shoul d not e tha t th e fee calculatio n workshee t incorporate s asectio n t

o hel p mee t thi s responsibility. ) H . Th e Permittee shal l retai n fe e calculatio n worksheet s an d othe r emissions-relate d dat aused t o determin

e fe e paymen

t fo r 5 years followin g submitta l o f fe e payment . Emission-relate ddat

ainclude , fo r

example , emissions-relate d form s provide db y th e EP A an d use d b y th e Permitte e fo r

fe e calculatio n purposes , emissions-relate d spreadsheets , and emissions-relate d data , suc h a s record s o f

emission s monitorin g dat aan d related suppor

t informatio n require d t

o b e kep t i n accordanc e with 4 0 CF.R . § 71.6(a)(3)(h) . [4 0 C.F.R . § 71.9(1) ] I . Failure o f

th e Permittee t

o pa y fee s i n atimel y manne r shal l subject

th e Permitte e t

o assessmen

t o f penaltie s ari dinteres t

i n accordanc e wit h 4

0 C.F.R . § 71.9(1) . J . When notifie db y th

e EP A o f underpaymen

t o f fees , th e Permittee shal l remi t

ful l paymen t withi n 3 0 day s o f

receipt o f notification . [4 0 C.F.R . § 71.9(j)(l ) an d (2) ] K . A Permittee who believe s tha t th e EP A assesse

d fe e i s i aerro

r an d who wishe s t

o challeng e suc

h fe e shal l provid e awritten explanatio n o f th e allege d erro

r to th e EP A alon g with ful l paymen

t ofth e EP A assesse

d fee . [4 0 C.F.R . § 71.9(j)(3) ] 4.3. COMPLIANC E STATEMEN T [4 0 C.F.R . § 71.6(a)(6)

] (A ) Th e Permittee must

compl y wit

h al l condition s o f

thi s Par t 7 1 permit . An y noncomplianc e with thi s permi t constitute s aviolatio n o f th e CA A an

d i s ground s for : [40C.F.R . § 71.6(a)(6)(I) ] 1 . Enforcemen

t action ; 2 . Permi t

termination , revocatio n an d reissuance , or

modification ; o

r 3 . Denial o f

apermit renewa l application . (B ) I t shal l no t be adefens e fo r

aPermittee i n a

n enforcemen

t actio n tha

t i t woul dhav

e bee n necessar

y t o hal t o r reduc e th e permitte d activity i n orde r t o maintai n complianc e wit

h th e condition s ofthi s permit . [4 0 CF.R . § 71.6(a)(6)(h) ] 4.4 . COMPLIANC E CERTIFICATION S [4 0 C.F.R . § 71.6(c)(5)

] The Permittee shal l submit to EP A acertificatio n o f complianc e wit

h al l permi t

terms an d conditions , includin g emissio n limitations , standards , o r wor k practices , eac

h calenda r yea r fo r th e reportin g perio d fro mJanuar y 1 t o Decembe

r 31 , excep

t th e firs t reportin g perio dshal l begi

n o n th e effectiv e dat

e ofthi s permit

and end on Decembe

r 31 . Al lVeoli a E S Technica l Solutions , L.L.C . Pag e 16 6 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T ExpirationDate : DRAF T reports shal l b

e submitte dt

o th e EP A an dshal l be postmarkedb y th e 30 t hda y followin g th e en dofth e reportin g period . Th e complianc e certificatio n shal l b e certifie da

s to truth , accuracy , an

dcompletenes s b y aresponsibl e officia l i n accordanc e with conditio n 4.8(A ) o f thi s permit . The certificatio n shal l include th e following : (A ) Identificatio n o f

eac h permit ter mo r conditio n tha

t i s the basi s o f

the certification ; (B ) Identificatio n ofth e method(s ) o r othe r mean s use d fo r

determinin g th

e complianc e statu s o f eac h ter man dconditio n durin g th

e certificatio n period , an

dwhethe r such methods o

r othe r means provide continuou s or intermitten

t data . I f necessary , th

e Permittee als o shal l identif y an y othe r materia l mformatio n tha

t must be include di n th e certificatio n t

o compl y wit h sectio n 113(c)(2 ) o f the CAA , whic h prohibit s knowingl y makin g afals e certificatio n o r omittin g materia

l information ; (C ) Th e complianc e statu s o f

eac h ter man dconditio n o f

th e permit , includin g whethe r monitorin g dat

ai s continuou s an

dwhethe r tha t dat ao r an y othe r credibl e evidenc e show s th e complianc e i s continuous . Th e certificatio n shal l identif y eac h deviatio n an dtak e it int o accoun t i n th e complianc e certification ; an d (D ) A statemen

t indicatin g th

e complianc e statu s o f

th e sourc e with an

y applicabl e monitorin g andcomplianc e certificatio n requirement s o f th e CAA . 4.5 . SCHEDUL E O F COMPLIANC E [4 0 C.F.R . § § 71.6(c)(3

) an d 71.5(c)(8)(iii)] (A ) Th e Permittee wil l compl y wit h al l requirements o f th e permit . (B ) Fo r applicabl e requirement s tha t wil l becom

e effectiv e durin g th

e permit term , th e Permitte e shal l timel y compl y wit h such requirements . 4.6 . DUT Y T O PROVID E AN D SUPPLEMEN T INFORMATIO N [4 0 C.F.R . § § 71.6(a)(6)(v ) an d 71.5(b) ] (A ) Th e Permittee shal l furnis h t o th e EPA , withi n areasonable time , an y informatio n tha t th e EP A ma

y request i n writin g t

o determine whethe

r caus e exist s fo r modifying , revokin g an

dreissuing , o

r terminatin g thi s permit

or t o determin

e complianc e with thi s permit . Upo n request, th e Permitte e shal l als o furnis h t o EP A copie s o f record s tha

t ar e require dt

o b e kept pursuan t t o th e term s o f

thi s permit , includin g informatio n claime dt o b e confidential . Informatio n claime dt o b e confidentia

l shoul dbe accompanie db y aclai mo f confidentiality accordin g t o th e provision s o f

4 0 C.F.R . Par

t 2 , Subpar

t B . (B ) Th e Permittee , upo n becomin g awar e tha t any relevan

t fact s wer

e omitte do

r incorrect informatio n was submitte di n th e permi t application , shal l promptly submit suc h supplementar

y fact s o r correcte dinformation . The Permittee shal l als o provid eVeoli a E S Technica l Solutions , L.L.C . Pag e 16 7 o f 17 2 Permi tNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T ExpirationDate : DRAF T

additiona l informatio n a

s necessar

y t o addres s an

y requirement s tha

t becom e applicabl e t

o th e facilit y after

thi s permit

i s issued . 4.7 . ENFORCEABILIT Y [4 0 C.F.R . § 71.6(b)

] Al l terms an

d condition s i n thi s permit , includin g an y provision s designated t o limi t th e source' s potentia

l t o emit , ar e enforceabl e b y th

e EP A an d citizen s i n accordanc e wit h the CAA . 4.8 . SUBMISSION S [4

0 CF.R . § § 71.5(d) , 71.

6 an d 71.9 ] (A ) A responsibl e officia l o f th e Permitte e shal l certif

y a s t o the truth , accuracy , and completenes s o f

an y documen

t require d t

o b e submitte d b y thi s permit . Such certification s shal l stat

e tha t base d on informatio n an d belie f forme dafter

reasonable inquiry , th

e statement

s an d informatio n i n th

e documen

t ar e true , accurate , an

d complete . Excep t

a s otherwis e noted , th

e Permittee shal l submit

al l document

s require dto b

e submitted b y thi s permi t to : Ai r Enforcemen

tan d Complianc

e Assuranc

e Branc h (AE-17J

) Ai r an d Radiatio

n Divisio n EP A Regio

n 5 7 7 Wes tJackso n Boulevar

d Chicago, Illinoi

s 6060 4 (B ) Th e Permittee shal l submit permi t applications , application s fo r permi t amendments , and othe r applicabl e permi t

information , whic h include s bu t i s no t limite dt o installatio n o f

contro l equipment , replacemen t o f a n emission s unit , fe e calculatio n worksheets , an

d application s fo r

renewal s an

d permit modifications , to : Ai r Permit

s Sectio n Ai r Program

s Branc h (AR-18J

) EPA Regio

n 5 7 7 Wes tJackso n Boulevar

d Chicago , Illinoi

s 6060 4 4.9 . SEVERABILIT Y CLAUS E [4 0 C.F.R . § 71.6(a)(5)

] Th e provision s o f

thi s permit

ar e severable , an

d i n th e even t o f an y challeng e t

o an y portio n o f thi s permit , o

r i f an y portio n i s hel d invalid , th e remainin g permi

t condition s shal l remain vali dan

d i n force . 4.10 . PERMI T ACTION S [4 0 C.F.R . § 71.6(a)(6)(iii) ] Th e EP A ma

y modify , revoke , reope

n an d reissue thi s permit , o

r terminat e i t fo r cause . The filin g o f

areques t b y th e Permitte e fo r

apenni t modification , revocatio n an dVeoli a E S Technica l Solutions , L.L.C . Page 16 8 o f 17 2 Permi tNo. : V-IL-171630010 3 -2014-1 0 Issuance Date : DRAF T Expiratio n Date : DRAF T reissuance , o

r termination , o

r o f anotificatio n o f

planne dchange s or

anticipate d noncomplianc e doe s not

sta y an y permit condition . 4.11 . ADMINISTRATIV E PERMI T AMENDMENT S [4 0 C.F.R . § 71.7(d)

] Th e Permittee ma

y request th e us e o f administrativ e permi t

amendmen

t procedure s fo r

a permit revisio n i n accordanc e with 4 0 C.F.R . § 71.7(d) . 4.12 . MINO RPERMI T MODIFICATION S [4 0 C.F.R . § 71.7(e)(1)

] Th e Permittee ma

y request th e use o f mino r permi t modificatio n procedure s fo r thos e modification s tha

t mee t th e requirements containe d i n 4 0 C.F.R . § 71.7(e)(1) . 4.13. SIGNIFICAN T PERMI T MODIFICATION S [4 0 C.F.R . § 71.7(e)(3)

] Th e Permittee mus t

request th e us e o f significan t

permi t modificatio n procedure s fo r thos e modification s tha

t mee t th e requirement s containe d i n 4 0 C.F.R . § 71.7(e)(3) . 4.14 . REOPENIN G FO RCAUS E [4 0 C.F.R . § 71.7(f)] Th e EP A shal l reope

n an d revis e th

e permi t prio r t o expiratio n unde

r an y ofth e followin g circumstances : (A ) Additiona l applicabl e requirements unde r the CA A becom

e applicabl e t

o thi s sourc e i f th e remainin g permit

ter mi s 3 o r mor e years . (B ) The EP A determine s tha t th e permit contain s amaterial mistak e or tha t inaccurat e statement s wer e mad e i n establishin g th

e emission s standard s o

r othe r terms o r condition s o f

th e permit . (C ) The EP A determine s tha t th e permit mus t be revise dor

revoke dt

o assur e complianc e with th

e applicabl e requirements . 4.15 . PROPERT Y RIGHT S [4 0 CF.R . § 71.6(a)(6)(iv) ] Thi s permit

doe s no t conve y an y propert y right s o f

an y sort , o r an y exclusiv e privilege . 4.16 . INSPECTIO N AN D ENTR Y [4 0 C.F.R . § 71.6(c)(2)

] Upo n presentation o f

credential s an

d othe r documents a

s ma y be require db y law , th

e Permittee shal l allo w EP A o r a n authorize d representativ e t o perfor mth e followin g a

s authorizedb y th

e CAA :Veoli a E S Technica l Solutions , L.L.C . Pag e 16 9 o f 17 2 Permi tNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T ExpirationDate : DRAF T (A ) Ente r upo n th e Permittee' s premise s wher e th e Par t 7 1 sourc e i s locate d or emissions-relate d activit

y i s conducted , or

wher e record s ar

e kep t unde r th e condition s o f

th e permit ; (B ) Hav e acces s t

o and copy , a

t reasonable times , an

y record s tha

t must b e kept unde r th e condition s o f

th e permit ; (C ) Inspec

t a t reasonable time s any facilities , equipmen t (includin g monitorin g an d ai r pollutio n contro l equipment) , practices , or operation s regulated o

r require d unde

r th e permit ; an

d (D ) Sample o

r monitor a t reasonable time s substance s o r parameters fo r

th e purpos e o f assuring complianc e with th e permi t o r applicabl e requirements . 4.17 . EMERGENC Y PROVISION S [4 0 C.F.R . § 71.6(g)

] (A ) I n additio n t

o an y emergency or

upse t provisio n containe d i n an y applicabl e requirement , th

e Permittee ma

y see k t o establis h tha

t noncomplianc e wit

h a technology-base d emissio n limitatio n unde r thi s permi t

wa s du e t o a n emergency . T o d o so , th e Permittee shal l demonstrat e th e affirmativ e defens e o f

emergency through properl y signed , contemporaneou s operatin g logs , o r othe r relevan t evidenc e that : 1 . A n emergency occurre d an d tha t th e Permittee ca

n identif y th e cause(s ) o f

th e emergency ; 2 . Th e permitte d facilit y wa s a t th e time bein g properl y operated ; 3 . Durin g th

e perio do f

th e emergency th

e Permittee took

al l reasonabl

e step s to minimiz e level s o f

emission s tha

t exceeded th

e emission s standards , o

r othe r requirements i n thi s permit ; an d 4 . The Permittee submitted notic e o f th e emergency to EP A withi n 2 workin g day s o f th e time whe

n emissio n limitation s wer e exceeded du

e to th e emergency . Thi s notic e mus t

contain adescriptio n o f

th e emergency , an

y step s take

n t o mitigat e emissions , an

d correctiv e action s taken . Thi s notic e fulfill s th e requirements o f conditio n 3.2(B ) o f

thi s permit , concernin g prompt notificatio n o f

deviations . (B ) I n an y enforcemen

t proceeding , th

e Permitte e attempting t

o establis h th

e occurrenc e o f a n emergency ha

s th e burden o f

proof. (C ) A n "emergency " mean s an y situatio n arisin g fro msudde n and reasonabl

y unforeseeable event

s beyond th

e contro l o f

th e source , includin g act

s o f God , whic h situatio n require s immediat e correctiv e actio n t

o restor e norma l operation , an

d tha t cause s th e sourc e t o exceed atechnology-base d emissio n limitatio n unde r th e permi tVeoli a E S Technica l Solutions , L.L.C . Pag e 17 0 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuanc e Date : DRAF T ExpirationDate : DRAF T

du e t o unavoidable increase s i n emission s attributabl e t o th e emergency . A n emergenc y shal l not

includ e noncomplianc e t o the exten

t cause d b y improperl y designed equipment , lac k o f preventiv e maintenance , careles s o r imprope r operation , or operato r error . 4.18 . OF F PERMI T CHANGE S [4 0 CF.R . § 71.6

(a )(12) ] Th e Permittee i s allowe dt o mak e certai n change s without apenni t revision , provide dtha

t th e followin g requirements ar e met : (A ) Eac h change i s no t

addressed o

r prohibite d b y thi s permit ; (B ) Eac h change mus

t compl y wit h al l applicabl e requirement s an d ma y no t violate an

y existin g penni t

ter mo r condition ; (C ) Change s unde

r thi s provisio n ma

y no t include change s subject

t o an y requiremen

t o f 4 0 C.F.R . Parts 7

2 through 7 8 o

r modification s unde

r an y provisio n o f

Titl e I o f th e CAA ; (D ) Th e Permittee must

provid e contemporaneou s writte n notic e t o EP A o f each change , excep t fo r change s tha

t qualif y a s insignifican t

activitie s unde

r 4 0 C.F.R . § 71.5(c)( l 1) . Th e writte n notic e must describ e eac

h change , th

e dat e o f th e change , an y change i n emissions , pollutant s emitted , an d an y applicabl e requirement s tha t woul dappl

y a s aresult o f th e change ; (E ) The permit

shiel ddoe s no t

appl y to change s mad

e unde r thi s provision ; an

d (F) The Permittee mus t

kee p arecord describin g al l change s tha t result i n emission s o f an y regulated ai r

pollutant subjec t t o an y applicabl e requiremen

t not otherwis e regulated unde

r thi s permit , and th

e emission s resultin g fro mthos e changes . 4.19 . PERMI T EXPIRATIO N AN D RENEWA L [4 0 C.F.R . § § 71.5 (a

)(l)(iii) , 71.6(a)(ll) , 71.7(b), 71.7(c)(l)(i

) an d (ii) , 71.8(d)

] (A ) Excep t

a s provide di n condition s 4.19(C ) an d (D) , below , thi s permit shal l expir

e fiv e year s fro mth

e effectiv e date . (B ) Expiratio n o f

thi s permit

terminate s th

e Permittee' s righ t

t o operat e unles s th

e Permitte e ha

s submitte d atimel y an

d complet e permi t renewa l applicatio n t

o th e permittin g authorit

y a t leas t 6 calenda

r months , bu

t no t mor e tha n 1 8 calenda

r months , prior

t o th e dat e o f expiratio n ofthi s permit . (C ) I f th e Permittee submit s atimel y an d complet

e permit applicatio n fo r

renewal , consisten t with 4 0 C.F.R . § 71.5(a)(1 ) and (2 ) an d conditio n 4.19(B) , above , bu t th e permittin g authorit

y fail s t o issu e o r den y th e renewa l permit , the

n thi s permit

shal l



### VES01763 2Veoli a E S Technica l Solutions , L.L.C . Pag e 171 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T ExpirationDate : DRAF T

no t expir e unti l th e permittin g authorit

y ha s issue do r deniedarenewa

l permit . An y permi t shiel dgrante

dunde r conditio n 4.2 1 o f

thi s permi t

ma y be extende

ddurin g th

e perio dtha t th e permittin g authorit

y fail s t o ac t o n th e renewa l application . (D ) I f th e Permittee ha

s submitte datimel y an

dcomplet e applicatio n fo r

renewal consisten t with 4 0 C.F.R . § 71.5(a)(1 ) and(2) an dconditio n 4.19(B) , above , th e Permittee' s failure t

o have aPar

t 7 1 permit

i s no t aviolatio n o f

Par t 7 1 o r th e CA A unti l th e permittin g authorit

y take s fina l actio n o n th

e permit renewa l application . Thi s protectio n shal l ceas e t o apply if , subsequen

t t o the completenes s determination , th

e Permitte e fail s t

o submit an y additional informatio n identifie da s being neede

dt o proces s th

e applicatio n b y th

e deadlin e specifie di n writin g b y th e permittin g authority . (E ) Renewa

l o f thi s permi

t i s subjec t

t o th e sam e procedura

l requirements tha

t appl y t o initia l permi

t issuance , includin g thos e fo r publi c participatio n an

daffecte dstat

e an d tribal review . (F ) Th e applicatio n fo r

renewa l shal l includ e th

e curren t permit number , descriptio n o f permi t revision s an

doff-permi t

change s tha

t occurre ddurin g th

e permit term , an y applicabl e requirements tha t wer e promulgate dan

dno t incorporate dint

o th e permit durin g th e permit term , an dothe r informatio n require db y th e applicatio n form . 4.20 . OPERATIONA L FLEXIBILIT Y [4 0 C.F.R . § 71.6(a)(13)

] Th e Permitte

e ma y mak e change s withi n th

e permitte dfacilit y without apermi t revision , includin g th

e additio n o f

ane w generato

r o r replacemen

t o f a n existin g generator, provide dth

e followin g condition s are. met : (A ) Th e change s ar

e not modification s unde

r an y provisio n o f

Titl e I o f th e CAA ; (B ) The change s d

o no t excee dth

e emission s allowe dunde r thi s permit

(whethe r expresse dtherei n a

s arat e o f emission s o

r i n term s o f

tota l emissions) ; an d (C ) Th e Permittee notifie s th

e EP A a t least 7 day s i n advanc e ofth e propose dchanges . Th e written notificatio n shal l includ e abrie f descriptio n o f

th e change withi n th

e permitte dfacility , th

e dat e o n whic h th

e change wil l occur , an

y change i n emissions , an dan y permi t ter mo r conditio n tha

t i s n o longe r applicabl e a

s aresult ofth e change . 4.21 . PERMI T SHIEL D [4 0 C.F.R . § 71.6(f)] (A ) Except

a s notedi n condition s 4.21(A)(1 ) an d(2) , below , complianc e wit h th e condition s o f

thi s permi t

shal l b e deeme dcompliance , a

s o f the dat e o f penni t issuance , wit

h an y applicabl e requirements tha t ar e specificall y identifie dan dVeoli a E S Technica l Solutions , L.L.C . Pag e 17 2 o f 17 2 PermitNo. : V-IL-1716300103-2014-1 0 Issuance Date : DRAF T Expiratio n Date : DRAF T

include di n thi s permit

o r tha t ar e specificall y identifie di n thi s permit a s no t applyin g t o th e facility . 1 . Complianc e with thi s permi t shal l not b e deeme

d t o b e complianc e wit

h an y requiremen

t o f 4 0 C.F.R . Par

t 63 , Subpar

t EEE , (includin g th

e appendix an

d an y requiremen

t o f th e General Provision s (40 C.F.R . Par t 63 , Subpar

t A ) identifie d i n Tabl e 1 a

s applicabl e t

o 4 0 C.F.R . Par

t 63 , Subpar

t EEE) . 2 . Th e permit

shiel dshal l no t

apply , an d complianc e with thi s permi t shal l no t be deeme d t o be complianc e with , Part s C an d D o f Titl e I o f th e CAA , o r an y requirements o f

th e Illinoi s SIP , o

r federal o r stat e regulation s tha

t gover n the permittin g o f

majo r modification s t

o source s o f

air emissions . (B ) Nothin g i n thi s permit shal l alte r o r affec t th e following : 1 . Th e liabilit y o f

th e Permitte e fo r

an y violatio n o f

applicabl e requirements prio r t o o r a t th e tim e o f permit issuance ; 2 . Th e ability o f

EP A t o obtai n informatio n unde r Sectio n 11 4 o f

th e CAA ; 3 . Th e applicabl e requirement s ofth e aci drai n program , consisten t with sectio n 408(a ) o f th e CAA ; o r 4 . Th e provision s o f

sectio n 30 3 o f

th e CA A (emergency orders) , includin g th e authorit y ofth e Administrato r

unde r tha t section . 4.22 . CREDIBL E EVIDENC E [6 2 Fed . Reg . 831

4 (Februar

y 24,1997) ; 4

2 U .S .C . § 7413

] Notwithstandin g th

e condition s o f

thi s permit

specifyin g complianc e practice s fo r applicabl e requirements , an y perso n (includin g th

e Permittee ) ma

y als o us e othe

r credibl e evidenc e t

o establis h complianc e or noncomplianc e wit

h applicabl e requirements .

# VES017635-017638.pd f

## Multi-Metal s Continuou s Emission s Monitorin g Syste m (CEMS )
Descriptio n CES ' Xact 64 0 syste m use s reel-to-ree ! (RTR ) filte r tap e samplin g an d nondestructiv e X-ray fluorescenc e (XRF ) analysi s t o monito r stac k meta l emissions . A n isokineti c sub-sampl e o f stac k ga s i s take n fro m th e stillin g chambe r an d draw n throug h a chemicall y reactiv e filter tape . Vapo r phas e metals , includin g mercury (Hg) , ar e deposite d alon g wit h th e particulat e matte r (PM ) o n th e filte r tape . Th e deposi t i s automaticall y advance d an d analyze d b y XR F fo r selecte d metal s as th e nex t sampl e i s bein g collected . Samplin g an d analysi s ar

e performe d continuousl y an d simultaneously , excep t durin g advancemen t ofth e tap e (-2 0 sec ) an d durin g daily-automate d qualit y assuranc e checks . I n 2007 , throug h it

s Clea n Ai r Excellenc e Award , th e EP A recognize d th e Xac t 64 0 CEM S as a n outstandin g achievemen t i n innovativ e clea n ai r technology . Th e EPA als o approve d th e Xac t 64 0 CEM S as a n alternativ e metho d fo r periodi c Metho d 2 9 testin g an d fee d strea m analysis , a

s wel l a s fo r monitorin g emission s durin g plan t operation . Feature s Automati c qualit y assurance , alarms , an d contro l feature s Ga s phas e calibratio n no t require d Identificatio n an d measuremen t of a s man y as 2 3 element s simultaneousl y (refe r t o th e periodi c tabl e o n th e Element s Supporte d pag e ofthi s dat a sheet ) Interna l calibratio n chec k incorporate d wit h every sampl e analyze d • Prove n RTR/XR F technolog y demonstrate d o n th e ocea n floor , Mars , an d i n thousand s o f bet a attenuatio n monitor s Daily , automati c upscale , blank , an d flo wcheck s Recognize d b

y th e EP A a s a n innovativ e clea n ai r technolog y (Clea n Ai r Excellenc e Award , 2007) Sampling , analysis , an d near-real-tim e reportin g (ever y 15,30,6 0 an d 12 0 minutes )Singl e monito r platfor m fo r H g an d HA P metal s monito r complianc e N o P M monito r neede d t o compl y wit h Mercur y & Ai r Toxic s (MATS ) rul e fo r powe r plant s May b e use d t o mee t 4 0 CF R Par t 6 0 an d 6

3 regulation s Measure s tota l elemental , oxidized , an d particulat e mercur y i n pg/dsc m Multi-meta l analysi s reduce s expenses , time , an d resource s Non-destructiv e analysi s allow s fo r sampl e archivin g Sensitive an d reliabl e (ng/m 3 t o ug/m 3 range ) Application s Th e Xac t 64 0 monitorin g syste m ca n simultaneousl y identif y an d measur e multipl e metal s i n flu e ga s t o provid e dat a fo r us e i n th e followin g applications .

• H g CEM S • HA P metal s CEM S Baselinin g a ne wproces s Optimizatio n o f emissio n control s Permittin g Regulatory complianc e Ris k managemen ti



### VES01763 7§• 4 ••••l i

Xac t 64 0 monitorin g system s identif y an d measur e th e 6 3 element s highlighte d i n th e tabl e below . Minimu m detectio n limit s (MDLs ) forth e element s highlighte d i n blu e ca n b e foun d o n th e Performanc e pag e ofthi s dat a sheet.Th e syste m i s capabl e o f measurin g th e element s highlighte d i n dar k gray , bu t MDL s hav e no t bee n developed .

To plac e a n orde r o r fo r mor e informatio n abou t th e Xac t 64 0 continuou s emission s monitorin g system , contac t you r regiona l CE S representativ e o r emai l u s a t info@cooperenvironmental.co m

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VES01763 8

# VES017639-017668.pd f

# Presente d a t A&WMA' s 

# 2014 International

Conference on Thermal Treatment

Technologies (IT3) & Hazardous Waste Combustors Specialty Conferenc e
Baltimore , M D October 13-15 , 201 4

VES01763 9

# Reviewof Monitorin g

Experienc e wit h th e Xact ® Multi-Metal s CEM S Kra g A
. Petterson , Coope rEnvironmenta l Services , LL C Pape r# 2 9

### Baltimor

e 201 4 

# Regulatio n o f Meta l Emission s Fro m Stationar y source s

• HA P Metal s Regulate d Usin g Maximu m Achievabl e Contro l Technolog y (MACT ) Approac h
• Severa l Sourc e Categorie s Hav e Regulate d Meta l Emission s • Portlan d Cemen t
• Hazardou s Wast e Incinerator s • Coa l fire d powe rplant s • Medica l Wast e Incinerator s

VES01764 1

# MAC T Rule s Approache s t o "Measuring "

Meta l Emission s fro m Source s

• Particulat e Matte r(PM ) a s a Surrogat e • Severa l MAC T Rule s eithe rrequir e o rallo w th e us e o f P M a s a surrogat e fo rmetal s (e.g
. EG U Mact , Portlan d Cemen t MACT , Boile rMACT )
• P M ma y b e monitore d usin g • P M CEM S (EGU , Portlan d Cement , Boiler )
• P M CPM S (EGU , Portlan d Cement , Boiler )
• Periodi c Metho d 5 test s (EGU )


# • Perio d Performanc e Test s • Remova l efficienc y fo rmetal s i s determine d wit h Metho d 2 9 testin g (e.g
. Hazardou s Wast e Incinerators , Medica l Wast e Incinerators )

VES01764 2

# EP A Ma y B e Movin g i n th e Directio n of

Requirin g Continuou s Monitorin g fo rMetal s

• EP A i s generall y requirin g mor e sophisticate d CEM S o n source s (e.g
. H g CEMS , P M CEM S an d HC I CEMS )
• Origina l 199 6 HW I MAC T Include d Multi-Meta l CEM S
• 201 3 - EP A attempte d t o Requir e HW I i n greate rSt
. Loui s t o hav e a M M CEM S
• Secondar y Lea d Smelte rMAC T Proposa l i n 201 1 requeste d commen t o n th e us e o f P b CEM S

VES01764 3

# Xac t CEM S Summar y

• Base d o n X-ra y Fluorescenc e (XRF )
• Utilize s Reactiv e Filte r Tap e an d Chemica l Dopan t t o Captur e Vapo rPhas e an d Particulat e Phas e Metal s • Abl e t o Measur e u p t o 2 0 Metal s Simultaneousl y

VES01764 4

# Xac t CEM S Overal l C

IT3/HW C Baltimor e 201 4 Transpor t Lin e

Stillin g Chamber/ Interfac e
Samplin g & Flo w Measuremen t Dopant/Dilutio n

X-ra y Analysi s

Dat aRecorder/Displa y Ai r sampl e intak e Iron i slac k (20 0 lpn> »

I'xlmii M retur n l o stac k

Dopan tailililio n (0. 1 lpm )
Isokineti c sampl e intak e to r XRJ - analysi s i 1 lpm )

VES01764 5

# XAC T SAMPLIN G AN D ANALYSI S

# Revie w o f Som e Stac k Samplin g Experience s wit h th e Xac t

• Metho d 30 1 Validatio n
• Qualit y Assuranc e Dat a Ove r5 year s o f Operatio n a t a Hazardou s Wast e Incinerato r
• Multi-Metal s Measuremen t A t a Coa l Fire d Facilit y
• Mercur y Measuremen t a t Coa l Fire d Powe rPlant s Baltimor e 2014

VES01764 7

# Metho d 30 1 Validatio n

• Metho d 30 1 i s th e Procedur e b y whic h ne w stac k measuremen t method s ar e evaluate d fo raccurac y an d precisio n • A t El i Lilly' s Tippecano e Laboratorie s Hazardou s Wast e Incinerato r • Xac t Evaluate d Usin g a Referenc e Aeroso l o f 5 metal s (As , Cd , Cr , Pb , Hg ) a t thre e concentratio n level s • Referenc e Aeroso l Generate d usin g th e Quantitativ e Aeroso l Generato r(QAG )
• QA G Itsel f wa s Metho d 30 1 Validated , an d P M versio n o f QA G ha s bee n extensivel y validate d wit h EPR I suppor t
• Metho d 29' s Accurac y an d Precisio n isn' t sufficien t (15 % o rmore )

VES01764 8•« * t o r - ^ — o 

### ( 0 U J 

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# o ( 0 

# o 11 1 < 

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# Metho d 30 1 Testin g Res u Its - Linearit y

IT3/HW C Baltimor

e 2014 14 0 12 0 

# I 10 0 O ) 3 . C o

o re X 8 0 6 0 4 0 Z 2 0 y = 0.952x-1.1 0 r = 0.99 5 n =96 0

QA G Referenc e Concentratio n (ug/dscm ) 

# Passe d M30 1 Requirement s fo r slope , intercep t an d correlatio n coefficien t Al l Dat a Include d

VES01765 0

# Metho d 30 1 Testin g Result s Precisio n

• Require d <10 % Relativ e Standar d Deviatio n • Easil y Me t M30 1 Precisio n Requiremen t

VES01765 1

# Metho d 30 1 Xac t Validatio n

t IT3/HWC Baltimor e 2014 

# Goa l Tes t Resul t Pass ? 19 2 Pas s -Ml % Pas s 

### H f J ) 

## 7 % Pns s I Pjs s N D N D I f ij S < rp l 

## N P i 1 (1 

## N D

Al l m c » »!i »emen t resi' ? 

## ^ i i 1 

## 'de d N D : No t

Define d Coope rEnvironmenta l Service s 1 3



### VES01765 2

# Xac t Operatio n a t a Hazardou s Wast e

Incinerato r

• Xac t operate d a s a complianc e instrumen t fo rfiv e plu s year s a t El i Lill y Tippecano e Laboratorie s
• Xac t incorporate d int o El i Lilly' s Alternativ e Monitorin g Pla n
• Evoni k Deguss a purchase d facilit y
• Evoni k successfull y use d th e Xac t t o d o CP T Performanc e Tes t i n 201 0 i n lie u o f usin g Metho d 2 9
• Xac t no t currentl y use d becaus e o f limite d us e ofth e incinerato r
• Xac t mee t initia l an d on-goin g performanc e criteri a

VES01765 3

# Initia l an d On-goin g Performanc e

Criteri a fo rth e Xac t

IT3/HW C Baltimor e 2014 

### Tes t

Categor y Tes t Tes t Requirement s Tes t Criteri a Seve n Da y Stabilit y (Automatic , Daily ) Zer o Drif t Monito rZer o standar d fo r7 consecutiv e day s < 20 % Seve n Da y Stabilit y (Automatic , Daily ) Upscal e Drif t Monito rupscal e standar d fo r7 consecutiv e day s <15 % Seve n Da y Stabilit y (Automatic , Daily ) Flo w Drif t Monito rFlo w drif t fo r7 consecutiv e day s < 20 %

Calibratio n Chec k (Quarterly ) X R F Calibratio n Drif t Chec k a standar d fo reac h complianc e elemen t measure d < 10 % Calibratio n Chec k (Quarterly ) Flo w Calibratio n Drif t Compar e sampl e flo w mete rt o

NIS T Traceabl e mete r < 10 %

Accurac y (Annua! ! y ) Linearit y RAT A (Dynami c Spiking ) 3 concentratio n level s Spik e int o transpor tlin e a s clos e to prob e a s possibl e Slop e = 0.8 0 t o 1.2 0 R> 0 9 0 Intercep t< 20 % o f emissio n lirni t



### VES01765 4

# Xac t Dail y Upscal e Result s fo ra Yea r

250 0 | 200 0 o i 

# f 1 150 0 g £ 100 0 a > o c o o 50 0 

### Xac t Upscal e Marc h 200 6 - Marc h 200 7

• C d • C r

a 

### H g P b

_; was . 0 H 1 1 1 1 Feb-0 6 May -0 6 Aug -0 6 Nov -0 6 Mar -0 7 Dat e



### VES01765 5

# Dail y Flo w QA/Q C Chec k - Percen t Differenc e
10.0 0 i



### VES01765 6

# Thi n Fil m Standard s
Use d t o calibrat e th e Xac t

IT3/HW C 

## Use d t o perfor m XR F audit s o n th e Xac t (Quarterly ) Recommende d b y 1 0 3. 3 fo r calibratio n o f XR F instrument s Gravimetricall y NIS T traceabl e Baltimor e 201 4

VES01765 7

# Xac t Lon g Ter m Q A Dat a -

Quarterl y Audit s

Baltimor e 201 4 Audi t Yea r Quarte r Audi t Dat e Flo wErro r XR F Audi t Erro r Audi t Yea r Quarte r Audi t Dat e Flo wErro r C r A s C d H g P b 200 7 1 3/1/200 7 3.04 % 1,46 % 2.18 % 2.84 % 1,75 % 2.34 % 200 7 2 5/25/200 7 3.13 % 3,32 % 0.13 % 4.23 % 2.60 % 2.96 % 200 7 3 8/29/200 7 0.68 % -3.74 % 2.18 % -4.13 % 2.36 % 2.76 % 200 7 4 12/26/200 7 1.42 % 6.50 % 0.36 % 7.36 % 4.18 % 0.40 % 200 8 1 2/15/200 8 N A 0.22 % 0.11 % 1.20 % -0.99 % 0.87 % 200 8 2 3/17/200 8 1.07 % 1.93 % 0.66 % 1.82 % 2.16 % 2.34 % 200 8 3 5/20/200 8 0.53 % 2.96 % 2.61 % 3.30 % 2.53 % 0.68 % 200 8 4 10/20/200 8 1.37 % 1.77 % 0.72 % 1.48 % 0.56 % 1.06 % 200 9 1 1/7/200 9 2.10 % 0.60 % 2.94 % 1.52 % 3.45 % 0.46 % 200 9 2 5/6/200 9 3.67 % 1.49 % 4.09 % 1.07 % 1.78 % 0.30 % 200 9 3 7/9/200 9 0.84 % 2.00 % 5.43 % 2.78 % 0.72 % 0.22 % 200 9 4 N A N A N A N A N A N A NA 201 0 1 1/12/201 0 N A 1.60 % 5.13 % 0.45 % 0.71 % 2.11 % 201 0 2 4/25/201 0 N A 1.61 % 5.92 % 1.12 % 4.00 % 0.96 % 201 0 3 7/13/201 0 1.68 % -3.47 % -0.92 % -2.82 % -2.42 % -2.11 % 201 0 4 12/10/201 0 ~2ji %

1 W E
. 1-77 % 1.35

% 2.16 % 1.66 % 1.68 % 1.22% . NA - Dat a No t Availabl e



### VES01765 8

# Schemati c o f Dynami c Spikin g fo r

Annua l RAT A

IT3/HW C Baltimor e 201 4

VES01765 9

# Annua l RAT A Result s

Yea r Slop e

C r A

s C d H g P b Averag e 200 6 0.8 3 0.9 0 0.8 5 0.8 2 0.8 5 0.8 5 200 6 (Quarterly ) 0.9 1 0.7 7 0.9 5 0.9 2 0.9 3 0.89 200 7 0.8 4 0.8 2 0.8 8 0.8 4 0.8 1 0.84 200 8 0.9 6 0.7 1 0.9 8 0.9 9 0.9 7 0.9 2 200 9 0.9 6 0.9 9 0.9 9 1.1 0 1.0 0 1.0 1 201 0 0.9 7 1.0 6 1.1 1 1.02 1.0 4 1.0 4 Averag e 0.9 1 0,8 7 0.9

6 0.9

5 0.9

3 0.9

3 

# Passe d Al l Require d Annua l a n Quarterl y Audit s Durin g it s

Operatio n

VES01766 0

# Testin g a t a Coa l Fire d Facilit y

•Coa l Fire d furnac e - EPA' s Multi-Pollutan t Contro l Researc h Facilit y •4 millio n BT U facilit y operatin g wit h ES P an d we t scrubbe r •Spik e a subsampl e o f effluen t wit h th e QA G a t thre e concentratio n level s •Compar e Xac t t o QA G
•Funde d unde r a n EP A SBI R Gran t

VES01766 1

# Xac t Accurac y Result s o n a Coa l Fire d

Sourc e

c o u t J X 

# Xac t vs . QA G fo r Al l Element s 350.0 0 300.0 0 250.0 0 200.0 0 150.0 0 100.0 0 50.0 0 0.0 0 y = 1.1041X - 1.382 9

R 2 =0.991 2 •C r

•A s A C d X H g
» P b

0.0 0 50,0 0 100.0 0 150.0 0 200.0 0 250.0 0 300.0 0 QA G Con e (ng/m ) 

### Excellen t Linearit y Excellen t Correlatio n Coa l Fue l Sourc e ha s n o impac t o n th e Xact' s measuremen t abilit y

VES01766 2

### Baltimor

e 2014 

# Mercur y Measuremen t o n a Coa l Fire d Powe rPlan t - Stud y 1

•58 5 Mwat t Coa l Fire d Powe r Plan t
•Downstrea m o f Electrostati c Precipitato r •Measuremen t o f Stac k Concentration s o f H g •Compariso n wit h Metho d 30 B an d a n on-sit e operatin g Therm o Mercur y Freedo m Uni t
•Xac t wa s installe d an d operatin g withi n 2 day s

VES017663

# H g Measuremen t o n a Coa l Fire d Powe r

Plan t

E u 1/ t

= L u c o u > . 3 u i ~ ( U 2 1 0 9 8 7 6 5 4 3 2 1 0 n • 

## j~

j 

## ? P ®

C 3 D

1 h'.'rm o Q A Perio d • CE S Xac t

• Metho d 30 B A Therm o CM M

0 1 2 3 4 5 6 7 8 9 1 0 1 1 1 2 1 3 RAT A Numbe r

Coope rEnvironmenta l Service s



### VES01766 4

# Mercur

y Measuremen t o n a Coa l Fire d Powe rPlan t - Stud y 2

• 75 0 M W Sourc e burnin g Lignite/PR B Blen d (60/4 0 an d 80/20 ) Equippe d wit h ES P an d We t FG D Control s • Mercur y Contro l Strateg y Testing - Brominate d Powde rActivate d Carbo n an d EM O (separatel y an d i n combination )
• Samplin g don e downstrea m o f a singl e ES P modul e • Sid e b y sid e samplin g wit h speciate d Metho d 30 B a t variou s time s eac h da y • Xac t Measure d Hg , Br , As , Se , an d P b - ga s phas e an d ver y smal l particulat e • Tes t lengt h - abou t 2 week s

VES01766 5

# Mercur

y Measuremen t o n a Coa l Fire d Powe rPlan t - Stud y 2

IT3/HW C Baltimor e 2014 Fua l Condition s Tim e H g Control s Metho d 30 B Hg (^g/dscm ) Xac

t H g (ng/dscm ) Percen t

Differenc e 10/3 /201 2 11:4 5 Baselin e 24.5 7 2

2 5 9 -8.1 % 10/3/201 2 14:4

5 EM O Only 14.8 5 15.3

3 I 3

.2 % 10/3/201 2 16:4

5 EM O Only 1 6 3 0 158 3 -2.9 % 10/5/201 2 12:1 5 EM O & PA C 9.2 5 10.0

9 9.0

% 60 % Lignit e 10/5/201 2 16:1 5 EM O & PA C 115 2 12.7 4 10.6

% 40 % PR B 10/5

/201 2 17:4 5 EM O a PA C 4.0 5 5.8

8 45.2% 10 /6/201 2 10:4

5 Baselin e 240 3 24.5 5 2.2% 10/6/201 2 13 :4

5 EM O & PA C 11.1 4 12.3 4 10,8

% 10/6/201 2 15:4

5 EM O & PA C 5.7 4 38.8 % 10/6/201 2 18 :4

5 EM O & PA C 13.9 2 15.7

2 13,0

% 10/9/201 2 10:1 5 Baselin e 28.1 4 25 .0 7 -10.9 % 10 /9/201 2 12:1 5 PA C Onl y 19.01 19.2 6 1.3

% 10/9/201 2 16:1 5 PA C Onl y 7.0 0 7.3

4 4.9% 10 /10 /201 2 10:3

0 Baselin e 2 3 1 9 23.9

8 3.4

% 80 % Lignit e 2 0 % PR B 10/10/201 2 13 :4 5 EM O Only 187 3 2 0 2 2 8.0

% 80 % Lignit e 2 0 % PR B 10/10/201 2 16:4 5 EM O Onl y 20.1 0 22.1 0 1 0 0 % 80 % Lignit e 2 0 % PR B 10/10/201 2 19 :4 5 EM O Onl y 1 8 6 0 22.1 0 18.8 % 10/10/201 2 9:0

0 Baselin e 21.5 7 18.6

9 -13.4

% 10/11 /20129:0 0 Baselin e 24,0 0 23.5

3 -1.9 % 10/11/201 2 10:4

5 EM O Onl y 20.5 2 18.9

0 -7.9 % 10/11/201 2 11:3

0 EM O Onl y 2 1 3 8 19.5

5 -8

.6 % Averag e Percen t Differenc e Baselin e Condition s -4.8 % Averag e Percen t Differenc e wit h H g Contro l 7.6 % Overal l Averag e Percen t Differenc e 6.0 %



### VES01766 6

# What' s Next ?

• Demonstratio n Stud y wit h Xac t 64 0 o n tw o Secondar y Lea d Smelter s
• Stud y require d b y Sout h Coas t Ai rQualit y Managemen t Distric t
• Instrumen t Installe d o n eac h fo rapproximatel y fou rmonth s
• Arseni c an d lea d ar e ke y HAP s o f interes t
• QA G spikin g an d manua l stac k test s
• Installatio n approximatel y Januar y o f 201 5

VES01766 7

# QUESTIONS ? k r a g p @ co o p e r

e n 

## v i r o n m e n

t 

## a I
. c o m

VES01766 8

# VES017669-017795.pd f