### Revision date : 2012/10/16 Page : 1 / 11

Version : 2

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## 1. Product and Company Identification

2. Hazards Identification

Emergency overview

CAUTION:

May cause severe irritation to eyes.

Inhalation may cause respiratory irritation.

Ingestion may result in severe irritaton or burns of the mouth, esophagus and stomach.

State of matter : liquid

Colour : black

Odour : sulfur

- like, strong

Potential health effects

Primary routes of exposure :

Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry for

gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases.

Acute toxicity :

Harmful by inhalation, in contact with skin and if swallowed.

Irritation / corrosion :

Irritating to eyes, respiratory system and skin.



## 3. Composition / Information on Ingredients

CAS Number Content ( W/W ) Chemical name

142

- 82

- 5 >= 1.0

- <= 20.0 % heptane

102

- 69

- 2 >= 0.0

- <= 20.0 % tripropylamine

142

- 84

- 7 >= 0.0

- <= 15.0 % dipropylamine

37143

- 54

- 7 >= 0.0

- <= 15.0 % 1

- methoxy

- 2

- propanamine

7704

- 34

- 9 >= 1.0

- <= 25.0 % sulfur

7732

- 18

- 5 >= 5.0

- <= 25.0 % Water>= 1.0

- <= 40.0 % Proprietary ingredient of



## 4. First

- Aid Measures

General advice :

First aid providers should wear personal protective equipment to prevent exposure. Remove contaminated

clothing. Move person to fresh air. If person is not breathing, call 911 or ambulance, then give artificial

respiration, preferably mouth

- to

- mouth if possible. Call a poison control center or physician for treatment advice.

Have the product container or label with you when calling a poison control center or doctor or going for

treatment.

If inhaled :

Remove the affected individual into fresh air and keep the person calm.

If on skin :

Rinse skin immediately with plenty of water for 15

- 20 minutes.

If in eyes :

Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present,

after first 5 minutes, then continue rinsing.

If swallowed :

Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Do not

induce vomiting. Have person sip a glass of water if able to swallow.

Note to physician

Treatment : Aspiration of this product during induced emesis can r esult in lung injury. If

evacuation of stomach contents is considered necessary, use method least

likely to cause aspiration, such as gastric lavage after endotracheal intubation.



## 5. Fire

- Fighting Measures

Flash point : 100

- 140 °F

Autoignition : No data available.

Lower explosion limit : not determined

Upper explosion limit : not determined

Self

- ignition temperature : not determined

Suitable extinguishing media :

water spray, dry powder, carbon dioxide, foam

Hazards during fire -fighting:

No particular hazards known.

Protective equipment for fire

- fighting :

Firefighters should be equipped with self

- contained breathing apparatus and turn

- out gear.



## 6. Accidental release measures

Personal precautions :

Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions.

Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable personal

protective clothing and equipment.

Environmental precautions :

Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater. Contain

contaminated water/firefighting water.Cleanup :

Dike spillage. Pick up with suitable absorbent material. Place into suitable containers for reuse or di sposal in a

licensed facility. Spilled substance/product should be recovered and applied according to label rates whenever

possible. If application of spilled substance/product is not possible, then spills should be contained, solidified,

and placed in sui table containers for disposal. After decontamination, spill area can be washed with water.

Collect wash water for approved disposal.



## 7. Handling and Storage

Handling

General advice :

Ensure adequate ventilation. Provide good ventilation of working area (local exhaust ventilation if necessary).

Keep away from sources of ignition

- No smoking. Keep container tightly sealed. Protect contents from the

effects of light. Protect against heat. Protect from air. Avoid aerosol formation. Avoid dust formation. Pro vide

means for controlling leaks and spills. Follow label warnings even after container is emptied. Avoid all direct

contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid inhalation of

dusts/mists/vapours. Wear suitable personal protective clothing and equipment.

Protection against fire and explosion :

The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid all

sources of ignition: heat, sparks, open flame. Sources of ignition should be kept well clear. Avoid extreme heat.

Keep away from oxidizable substances. Electrical equipment should conform to national electric code. Ground

all transfer equipment properly to prevent electrostatic discharge. Electrostatic discharge may cause ignition.

Storage

General advice :

Protect containers from physical damage. Protect against contamination. The authority permits and storage

regulations must be observed.

Storage incompatibility :

General advice : Segregate from incompatible substances. Segregate from foods and animal feeds. Segregate

from textiles and similar materials.

Temperature tolerance

Protect from temperatures above: 40 °C

Changes in the properties of the product may occur if substance/product is stored above indicated temperature

for extended periods of time.



## 8. Exposure Controls and Personal Protection

Components with occupational exposure limits

heptane OSHA PEL 500 ppm 2,000 mg/m3 ;

ACGIH TWA value 400 ppm ; STEL value 500 ppm ;

Advice on system design :

Whenever possible, engineering controls should be used to minimize the need for personal protective

equipment.

Personal protective equipment

Respiratory protection :

Wear respiratory protection if ventilation is inadequate. Wear a NIOSH

- certified (or equivalent) organic

vapour/particulate respirator. For situations where the airborne concentrations may exceed the level for which

an air purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or

Health (IDL H), use NIOSH

- certified full facepiece pressure demand self

- contained breathing apparatus (SCBA)

or a full facepiece pressure demand supplied

- air respirator (SAR) with escape provisions.Hand protection :

Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment of the

workplace hazards.

Eye protection : Safety glasses with side

- shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing

hazard exists.

Body protection :

Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron,

protective boots, chemical

- protection suit.

General safety and hygiene measures :

Wear long sleeved work shirt and long work pants in addition to other stated pe rsonal protective equipment.

Work place should be equipped with a shower and an eye wash. Handle in accordance with good industrial

hygiene and safety practice. Personal protective equipment should be decontaminated prior to reuse. Gloves

must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off

immediately all contaminated clothing. Store work clothing separately. Hands and/or face should be washed

before breaks and at the end of the shift. No eating, drinking, smoking or tobacco use at the place of work. Keep

away from food, drink and animal feeding stuffs.



## 9. Physical and Chemical Properties

Form : liquid

Odour : sulfur

- like, strong

Colour : black

pH value : approx. 4

- 8

Information on: heptane

Boiling point : 98 °C ( 1,013 hPa ) ( other ) Literature data.

---------------------------------- Vapour pressure : 30 mmHg ( 20 °C )

Density : approx. 0.93

- 1.1

g/cm3 ( 20 °C )

Vapour density : not determined

Partitioning coefficient n

octanol/water (log Pow) : not applicable

Viscosity, dynamic : not determined

Solubility in water : ( 20 °C ) not determined



## 10. Stability and Reactivity

Conditions to avoid :

Avoid contact with air.

Substances to avoid :

strong acids, strong bases, strong oxidizing agents

Hazardous reactions :

The product is chemically stable.

Decomposition products : No hazardous decomposition products if stored and handled as prescribed/indicated., Prolonged thermal

loading can result in products of degradation being given off.

Thermal decomposition :

Possible thermal decomposition products :

carbon monoxide

, carbon dioxide

, Sulphur dioxide

, nitrogen dioxide

, nitrogen oxide

, hydrogen sulphide

If product is heated above decomposition temperature, toxic vapours will be re leased.

Corrosion to metals :

No data available.Oxidizing properties :

Not an oxidizer.



## 11. Toxicological information

Acute toxicity

Oral :

Information on: heptane

Type of value : LD50

Species : mouse (

male/female )

Value : > 4,420 mg/kg ( Test )

Information on: tripropylamine

Type of value : LD50

Species : rat ( male/female )

Value : > 200

- < 2,000 mg/kg ( Test )

Information on: dipropylamine

Type of value : LD50

Species : rat ( male/female )

Value : 495 mg/kg ( Test )

Information on: sulfur

Type of value : LD50

Species : rat ( male/female )

Value : > 2,200 mg/kg ( OECD Guideline 401 )

----------------------------------

Inhalation :

Information on: heptane

Type of value : LC50

Species : rat

Value : approx. 62 mg/l

Exposure time : 4 h

Species : rat

Value : ( IRT )

Exposure time : 3 min

Mortality within the stated exposition time as shown in animal studies.

Information on: tripropylamine

Type of value : LC50

Species : rat

Value : 1.5 mg/l (

other )

Exposure time : 4 h

Literature data.

Species : rat

Value : ( IRT )

Exposure time : 3 min

No Mortality within the stated exposition time as shown in animal studies, however, deaths occurred after longer

exposure.

Information on: dipropylamineType of value : LC50

Species : rat

Value : 4.4 mg/l (

other )

Exposure time : 4 h

Information on: 1- methoxy-2- propanamine

Type of value : LC50

Species : rat ( male/female )

Value : 13.1

- 14.3 mg/l ( OECD Guideline 403 )

Exposure time : 4 h

Information on: sulfur

Type of value : LC50

Species : rat ( male/female )

Value : > 5.4 mg/l ( OECD Guideline 403 )

Exposure time : 4 h

----------------------------------

Dermal :

Information on: heptane

Type of value : LD50

Species : rabbit

Value : > 3,400 mg/kg

Literature data.

Information on: tripropylamine

Type of value : LD50

Species : rabbit

Value : 433 mg/kg (

other )

Information on: 1- methoxy -2- propanamine

Type of value : LD50

Species : rabbit (

male/female )

Value : approx. 3,000 mg/kg

Information on: sulfur

Type of value : LD50

Species : rat ( male/female )

Value : > 2,000 mg/kg ( OECD Guideline 402 )

----------------------------------

Irritation / corrosion :

Skin:

Information on: heptane

Species : rabbit

Result : Irritant.

Method : Test

Information on: tripropylamine

Species : rabbit

Result : Corrosive.

Method : Test

Information on: dipropylamine

Species : rabbitResult : Corrosive.

Method : Draize test

Information on: 1- methoxy-2- propanamine

Species : rabbit

Result : Corrosive.

Information on: sulfur

Species : rabbit

Result : non -irritant

Method : OECD Guideline 404

The European Union (EU) has classified this substance with 'Irritating to skin' (R38).

----------------------------------

Eye :

Information on: heptane

Species : rabbit

Result : non -irritant

Method : Test

Information on: tripropylamine

Result : Risk of serious damage to eyes.

As the product corrodes the skin, it can be expected to have a similar effect on the eyes also.

Information on: dipropylamine

Species : rabbit

Result : Risk of serious damage to eyes.

Method : Test

Information on: 1- methoxy-2- propanamine

Species : rabbit

Result : Risk of serious damage to eyes.

Method : Test

Information on: sulfur

Species : rabbit

Result : non -irritant

Method : OECD Guideline 405

----------------------------------

Sensitization:

Information on: 1- methoxy-2- propanamine

Guinea pig maximization test

Species : guinea pig

Result : Non

- sensitizing.

Method : OECD Guideline 406

Information on: sulfur

Guinea pig maximization test

Species : guinea pig

Result : Non

- sensitizing.

Method : OECD Guideline 406

----------------------------------

Genetic toxicityInformation on: heptane

No mutagenic effect was found in various tests with bacteria and mammalian cell culture.

Information on: tripropylamine

The substance was not mutagenic in bacteria.

Information on: dipropylamine

The substance was not mutagenic in bacteria.

Information on: 1- methoxy-2- propanamine

The substance was not mutagenic in bacteria. The substance was not mutagenic in mammalian cell culture.

Information on: sulfur

The substance was not mutagenic in bacteria.

----------------------------------

Carcinogenicity

Information on: dipropylamine

Under certain conditions the substance can form nitrosamines. Nitrosamines are carcinogenic in animal studies.

----------------------------------



## 12. Ecological Information

Fish

Information on: heptane

Acute:

DIN 38412 Part 15 static

Leuciscus idus / LC50 (

96 h ): 220

- 270 mg/l

Information on: tripropylamine

Acute:

DIN 38412 Part 15 static

Leuciscus idus / LC50 (

96 h ): 38.3 mg/l

The details of the toxic effect relate to the nominal concentration. The product will cause changes in the pH

value of the test system. The result refers to an unneutralized sample. After neutralization, it is no longer toxic.

Information on: dipropylamine

Acute:

OECD Guideline 203 semistatic

Oryzias latipes / LC50 (

96 h ): 27 mg/l

The product has not been tested. The statement has been derived from substances/products of a similar

structure or composition.

Fish test acute Salmo gairdneri, syn. O. mykiss / LC50 (

96 h ): 37 mg/l

The statement of the toxic effect relates to the analytically determined concentration. The study was carried out

in hard water. The product has not been tested. The statement has been derived from substances/products of a

similar structure or composition. Literature data.

Fish test acute static

Salmo gairdneri, syn. O. mykiss / LC50 (

96 h ): 182 mg/l

The study was carried out in hard water. The product has not been tested. The statement has been derived

from substances/products of a similar structure or composition. The statement of the toxic effect relates to the

analytically determined concentration. Literature data.

Information on: 1- methoxy-2- propanamine

Acute:

DIN 38412 Part 15 static

Leuciscus idus melanotus / LC50 (

96 h ): > 46

- < 100 mg/l

The details of the toxic effect relate to the nominal concentration.

Information on: sulfur

Acute:

Orientating study staticOncorhynchus mykiss / LC50 (

96 h ): > 5,000 mg/l

Nominal concentration.

----------------------------------

Aquatic invertebrates

Information on: heptane

Acute:

other

Gammarus sp. / EC50 (

48 h ): 0.2 mg/l

Literature data.

Daphnia test acute static

Daphnia magna / LC50 (

96 h ): 82.5 mg/l

Literature data.

Information on: tripropylamine

Acute:

DIN 38412 Part 11 static

Daphnia magna / EC50 (

48 h ): 99 mg/l

The details of the toxic effect relate to the nominal concentration. The product will cause changes in the pH

value of the test system. The result refers to an unneutralized sample. After neutralization a reduction in harmful

effect can be observed.

Information on: dipropylamine

Acute:

Directive 79/831/EEC static

Daphnia magna / EC50 (

48 h ): 73.34 mg/l

The details of the toxic effect relate to the nominal concentration.

Information on: 1- methoxy-2- propanamine

Acute:

Directive 79/831/EEC static

Daphnia magna / EC50 (

48 h ): 101.5 mg/l

The details of the toxic effect relate to the nominal concentration.

Information on: sulfur

Acute:

OECD Guideline 202, part 1 static

Daphnia magna / EC50 (

48 h ): > 1,000 mg/l

Nominal concentration.

----------------------------------

Aquatic plants

Information on: heptane

Toxicity to aquatic plants :

static

algae / EC50 (

8 h ): 1.5 mg/l

Literature data.

Information on: tripropylamine

Toxicity to aquatic plants :

DIN 38412 Part 9 static

green algae / EC50 ( 72 h ): 22.4 mg/l

The details of the toxic effect relate to the nominal concentration. The product will cause changes in the pH

value of the test system. The result refers to an unneutralized sample. After neutralization a reduction in harmful

effect can be observed.

Information on: dipropylamine

Toxicity to aquatic plants :

DIN 38412 Part 9 static

green algae / EC50 ( 72 h ): 11.8 mg/l

The details of the toxic effect relate to the nominal concentration.

Information on: 1- methoxy-2- propanamineToxicity to aquatic plants :

DIN 38412 Part 9 static

green algae / EC50 ( 72 h ): 34.6 mg/l

After neutralization a reduction in harmful effect can be observed. The details of the toxic effect relate to the

nominal concentration.

----------------------------------



## 13. Disposal considerations

Container disposal :

No special precautions necessary.

RCRA : D001



## 14. Transport Information

Reference Bill of Lading



## 15. Regulatory Information

Federal Regulations

Registration status :

Chemical TSCA, US blocked / not listed



### 40 CFR: 721.4133, 40 CFR: 721.4128

OSHA hazard category : Chronic target organ effects reported ; ACGIH TLV established ; Flammable

Liquid

EPCRA 311/312 (Hazard categories) : Acute ; Chronic ; Fire ; Sudden release of pressure

CERCLA RQ CAS Number Chemical name

5000 LBS 142

- 84

- 7 dipropylamine

100 LBS 142

- 82

- 5 heptane

State regulations

State RTK CAS Number Chemical name

MA, NJ, PA 142

- 82

- 5 heptane

MA, NJ, PA 102

- 69

- 2 tripropylamine

MA, NJ, PA 142

- 84

- 7 dipropylamine

MA, NJ, PA 7704

- 34

- 9 sulfur



## 16. Other Information

We support worldwide Responsible Care® initiatives. We value the health and safety of our employees,

customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible

Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible

fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our

products, and minimizing the impact of our operations on society and the environment during production,

storage, transport, use and disposal of our products.I MPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN

ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOUR

GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE

RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR

PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR

IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY O R FITNESS FOR A PARTICULAR

PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION

SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT

INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SH ALL THE

DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR

TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT

THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY

HEREUNDER ARE G IVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE

DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING

GIVEN AND ACCEPTED AT YOUR RISK.

END OF DATA SHEET