CALIFORNIA AIR RESOURCES BOARD



### SIP COMPLETENESS CHECKLIST (Electronic Format)

*** TO BE COMPLETED BY DI STRICT AND RETURNED TO ARB ***

All rules submitted to the EPA as State Implementation Plan (SIP) revisions must be suppor ted by certain information and documentation for the rule packages to be deemed complete for review by the EPA. Rules will not be evaluated for approvability by the EPA unless the submittal packages are comple te. To assist you in determining that all necessary materials are included in rules packages sent to the ARB fo r submittal to the EPA, please fill out the following form and include it with the rule package you send ARB. See the ARB's Guidelines on the Impl ementation of the 40 CFR 51, Appendix V , for a more detailed explanation than is provi ded here. Adopted rules and rule amendments should be checked against U.S. EPA's Guidance Document for Correcting Common VOC & Other Rule Deficiencies (Little Blue Book, August 21, 2001) to ensure that they contain no elements which will result in disapproval by EPA.

District: Sacramento Metropolit an Air Quality Management District

Rule No: 454

Rule Title: Degreasing Operations

Date Adopted or Amended: Amended on May 23, 2002 and September 25, 2008

ADMINISTRATIVE MATERIALS

Note: All documents should be in electronic format. Items that have signatures, initials, or stamps may be scanned.

Not Attached Attached N/A

COMPLETE COPY OF THE RULE: Provide an unmarked copy of the entire rule as adopted or amended by your District Board.

UNDERLINE AND STRIKEOUT COPY OF THE RULE : If an amended rule,

provide a complete copy of the ru le indicating in underline and strikeout format all language which has been added, deleted, or changed since the rule was last adopted or amended.

COMPLETE COPY OF THE REFERENCED RULE(S): For any rule which

includes language specifically referencing another rule, a copy of that other rule must also be submitted, unless it has already been submitted to EPA as part of a previous SIP submittal.

PUBLIC NOTICE EVIDENCE: Include a copy of the local newspaper clipping

certification(s), stating t he date of publication, whic h must be at least 30 days before the hearing. As an alternative, include a copy of the actual published notice of the public hearing as it appeared in the local newspaper(s). In this case, however, enough of the newspaper page must be included to show the date of publication. The notice must s pecifically identify by title and number each rule adopted or amended.

RESOLUTION/MINUTE ORDER: Provide the Board Clerk certified resolution

or minute order. This document must include certification that the hearing was held in accordance with the informati on in the public notice. It must also list the rules that were adopted or am ended, the date of the public hearing, and a statement of compliance with California Health and Safety Code Sections 40725-40728 (Administr ative Procedures Act).

PUBLIC COMMENTS AND RESPONSES: Submit copies of written public

comments made during the notice period and at the public hearing. Also submit any written responses prepared by the District staff or presented to the District Board at the public hearing. A summary of the public comments and responses is adequate. If there were no comments made during the notice period or at the hearing, please indicate N/A to the left.5/1/2002 CALIFORNIA AIR RESOURCES BOARD



### SIP COMPLETENESS CHECKLIST (Electronic Format)

TECHNICAL MATERIALS

Not Attached Attached N/A

RULE EVALUATION FORM: See instructions for completing the Rule Evaluation Form and the accompanying sample form.

NON-EPA TEST METHODS: Attach all test methods that are referenced in

your rule that do not appear in 40 CFR 51, 60, 61, 63, or have not been previously submitted to EPA. EPA me thods used in other media such as SW846 for solid waste are not autom atically approved for air pollution applications. Submittal of test me thods that are not EPA-approved should include the information and follow the procedure described in Region 9’s “Test Method Review & Evaluation Process.”

MODELING SUPPORT: Provide if appropriate. In general, modeling support

is not required for VOC and NOx rules to determine their impacts on ozone levels. Modeling is required where a ru le is a relaxation that affects large sources (> 100 TPY) in an attainment area for SO2, directly emitted PM10, CO, or NOx (for NO2 purposes). In cases where EPA is concerned with the impact on air quality of rule revisions which relax limits or cause a shift in emission patterns in a nonattainment area, a reference back to the approved SIP will be sufficient provided the appr oved SIP accounts for the relaxation and provided the approved SIP used the current EPA modeling guidelines. If current EPA modeling guidelines were not used, then new modeling may be required.

ECONOMIC AND TECHNICAL JUSTIFICATION FOR DEVIATIONS FROM

EPA POLICIES : The District staff report or other information included with the submittal should discuss all potential relaxations or deviations from RACT, RACM, BACT, BACM, enforceability, atta inment, RFP, or other relevant EPA requirements. This includes, for exampl e, demonstrating that exemptions or emission limits less stringent than the presumptive RACT (e.g., a CTG) meet EPA’s 5 percent policy, and demonstrating that all source categories exempted from a RACM/BACM rule are de minimus according to EPA’s RACM/BACM policy.

ADDITIONAL MATERIALS : Provide District staff reports and any other

supporting information concerning developm ent of the rule or rule changes. This information should explain the basis for all limits and thresholds contained in the rule.CALIFORNIA AIR RESOURCES BOARD



### APCD/AQMD RULE EVALUATION FORM -- Page 1 (Electronic Format)

I. GENERAL INFORMATION

District: Sacramento Metropolit an Air Quality Management District

Rule No(s): 454 Date adopted/Amended/Rescinded: Amended September 25, 2008

Rule Title(s): Degreasing Operations

Date Submitted to ARB: May 18, 2009

If an Amended Rule, Date Last Amended (or Adopted): Amended May 23, 2002

Is the Rule Intended to be Sent to the U.S. EPA as a SIP Revision? Yes No ( If No, do not complete remainder of form)

District Contact: Kevin J. Williams Phone Number: (916) 874-4851 E-mail Address: kjwilliams@airquality.org

Narrative Summary of New Rule or Rule Changes: New Rule Amended Rule

The adopted amendments will require all degreasing operations use solvents that contai n no more than 25 g/l of VOCs in Section 302.3. The adopted amendments also added an exemption for the degreasing of high-voltage

microwave vacuums tubes in Section 110.8.

Pollutant(s) Regulated by the Rule (Check): ROG (NOx) SO2 (CO) PM TAC (name):

II. EFFECT ON EMISSIONS

Complete this section ONLY for rules that, when implemented, w ill result in quantifiable changes in emissions. Attach referenc e(s) for emission factor(s)

and other information. Attach calculation sheet showi ng how the emission information provided below was determined

.

Net Effect on Emissions: Increase Decrease N/A

Emission Reduction Commitment in SIP for this Source Ca tegory: The 1994 SIP included a commitment to reduce VOC emissions from surface preparation and cleanup solvents by 2.9 tpd from the Sacramento district. Surface preparation and cleanup solvents are included in multiple rules. Prior to amendment of this rule, the district had reduced emissions from this category by 2.5 tpd. This rule amendment reduces emissions from this category by 60 tons per year (0.16 tpd). Together with the 2008 amendm ents to eight other prohibitory rules with surface preparation and cleanup requirements, the total emission reducti on from this category is now 3 tpd, which satisfies

the SIP commitment.

Inventory Year Used to Calcul ate Changes in Emissions: 2010 Area Affected: Sacramento County

Future Year Control Profile Estimate (Provide information on as many years as possible) : N/ACALIFORNIA AIR RESOURCES BOARD



### APCD/AQMD RULE EVALUATION FORM -- Page 2 (Electronic Format)

Baseline Inventory in the SIP for the Control M easure: 5.6 tpd for t he Sacramento district.

Emissions Reduction Commitment in the SIP for the Cont rol Measure: 2.9 tpd fo r the Sacramento district.

Revised Baseline Inventory (if any): N/A

Revised Emission Reduction Estimate (if developed): N/A

Note that the district’s input to the Rule Evaluation Form will not be used as input to the ARB’s emission forecasting and planning.

III. SOURCES/ATTAINMENT STATUS

District is: Attainment Nonattainment Split

Approximate Total Number of Small (<100 T PY) Sources Affected by this Amendment: 1800

Percent in Nonattainment Area: 100 %

Number of Large (> 100 TPY) Sources Controlled: 0 Percent in Nonattainment Area: N/A %

Name(s) and Location(s) (city and county) of Large (> 100 TPY) Sources Controlled by Rule (Attach additional sheets as

necessary) : N/A

IV. EMISSION REDUCTION TECHNOLOGY

Does the Rule Include Emission Limits that are Continuous? Yes No

If Yes, Those Limits are in Section(s) 302 of the Rule.

Other Methods in the Rule for Achieving Emission Reducti ons are: work practice standards in Sections 301-308.

V. OTHER REQUIREMENTS

The Rule Contains:

Emission Limits in Section(s): 302 Work Practice Standar ds in Section(s): 301-308 Recordkeeping Requirements in Section(s): 501 Reporting Requirements in Section(s): N/ACALIFORNIA AIR RESOURCES BOARD



### APCD/AQMD RULE EVALUATION FORM -- Page 3 (Electronic Format)

5/1/2002 3

VI. IMPACT ON AIR QUALITY PLAN

No Impact Impacts RFP Impacts attainment

Discussion: Reduces emissions and makes progress toward reasonable further progress and attainment.SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

May 23, 2002 XX-XX-08 454-1 RULE 454 DEGREASING OPERATIONS Adopted 6-5-79 (Amended 7-23-81, 11-29-83, 2-23-93, 9-5-96, 4-3-97, 5-23-02 , XX-XX-08 )

INDEX

100 GENERAL
101 PURPOSE

102 APPLICABILITY

103 SEVERABILITY

110 EXEMPTIONS

200 DEFINITIONS
201 AIRTIGHT/AIRLESS CLEANING SYSTEM

202 CIRCUMFERENTIAL TROUGH

203 CLOSED CONTAINER

204 CONVEYORIZED DEGREASER

205 DEGREASER

206 EXEMPT COMPOUND

207 FREEBOARD HEIGHT

208 FREEBOARD RATIO

209 KEY SYSTEM OPERATING PARAMETER:

210 LEAK
211 LIP EXHAUST SYSTEM

212 LOW VOLATILITY SOLVENT

213 MAKEUP SOLVENT

214 NESHAP

215 NON-VAPOR DEGREASER

216 OPEN-TOP VAPOR DEGREASER

217 OSHA

218 REFRIGERATED FREEBOARD CHILLER

219 REMOTE RESERVOIR DEGREASER

220 SOLVENT

221 SOLVENT DEGREASING

222 STATIONARY SOURCE

223 SUPERHEATED VAPOR ZONE 224 VOLATILE ORGANIC COMPOUND (VOC)

225 VOLATILE SOLVENT

226 WATER SEPARATOR

22 6 7 WIPE CLEANING

22 7 8 WORKLOAD

300 STANDARDS
301 GENERAL EQUIPMENT REQUIREMENTS 302 NON-VAPOR DEGREASERS; EQUIPMENT REQUIREMENTS

303 VAPOR DEGREASERS; EQUIPMENT REQUIREMENTS AIRTIGHT/AIRLESS CLEANING
SYSTEM REQUIREMENTS

304 AIRTIGHT/AIRLESS CLEANING SYSTEM VAPOR DEGREASERS; EQUIPMENT
REQUIREMENTS

305 REMOTE RESERVOIR DEGREASER 306 VAPOR DEGREASERS; SAFETY SWITCHES

307 CONVEYORIZED DEGREASERS
308 GENERAL OPERATING REQUIREMENTS

309 LIP EXHAUST SYSTEM
310 EMISSIONS CONTROL EQUIPMENTSACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

454-2 May 23, 2002 XX-XX-08 400 ADMINISTRATIVE REQUIREMENTS
401 CALCULATION FOR DETERMINATION OF VOC CONTENT OF MATERIAL INCLUDING

WATER AND EXEMPT COMPOUNDS

402 CALCULATION FOR DETERMINING PERCENT CONTROL EFFICIENCY AND VOC MASS

EMISSION RATE

403 OPERATION AND MAINTENANCE PLAN

500 MONITORING AND RECORDS
501 USAGE RECORDS

502 TEST METHODSSACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

May 23, 2002 XX-XX-08 454-3 100 GENERAL

101 PURPOSE: To limit the emission of volatile organic compounds from degreasers.

102 APPLICABILITY: This rule applies to solvent degreasing operations.

103 SEVERABILITY : If a court of competent jurisdiction issues an order that any provision of this rule is invalid, it is the intent of the Board of Directors of the District that other provisions of this rule remain in full force and effect, to the extent allowed by law.

110 EXEMPTIONS: 110.1 The provisions of this rule do not apply to wipe cleaning.

110.2 Prior to May 22, 2003, the provisions of Section 302 of this rule do not apply to

non

- vapor degreasers which have an air

- solvent interface area less than or equal to

1.0 m 2 , or to remote reservoir degreasers using a low

- volatility solvent spray which is drained into the remote reservoir concurrently with the degreasing operation.

110. 3 2 On or after May 22, 2003 Prior to (one year after date of adoption), the provisions of this rule shall not apply to non-vapor degreasers which use s solvents that contain 50 grams per liter or less VOCs including water and exempt compounds. 110.3 Effective (one year after date of adoption), the provisions of this rule shall not apply to degreasers which use solvents that contain 25 grams per liter or less VOCs including water and exempt compounds, as determined by Sections 502.5 and

502.6. 110.4 The provisions of Section 308.7 of this rule do not apply to open-top vapor degreasers where solvent flow complies with Section 308.10.b. and liquid solvent does not splash above the air-vapor interface.

110.5 The provisions of this rule shall not apply to solvent degreasing operations using exempt compounds mixed with volatile organ ic compounds provided that the mixture does not contain more than 5% volatile organic compounds by weight.

110. 6 5 Prior to (one year after date of adoption), T t he provisions of this rule shall not apply to solvent degreasing operations that are subject to the NESHAP requirements of 40 CFR Part 63 Subpart T- Halogenated Solvents Emissions from Solvent Cleaning.

110.7 Until May 22, 2004, t he 50 grams per liter VOC limit in Section 302.2 does not apply

to a non

- vapor degreaser or a remote reservoir degreaser t hat uses a solvent that complies with the VOC limit specified for t he cleaning activity list ed in Section 301 of

Rule 466

– SOLVENT CLEANING. Any non

- vapor degreaser exempt under this section shall comply with other requirements of this rule.

110. 8 6 The provisions of this rule shall not apply to products subject to the Air Resources Board Consumer Products Regulations as se t forth at Subchapter 8.5, Article 2, Section 94507-94517 of Title 17 of the California Code of Regulations.

110. 9 7 T he 50 grams per lit er VOC limit in Section 302.2 The VOC content limits in Sections

302.2 and 302.3 do es not apply to degreasing of tools, equipment and machinery, regulated under Rule 456, AEROSPACE ASSEMBLY AND COMPONENT COATING OPERATIONS, and aerospace products using solvents that comply with the surface preparation and cleanup VOC limits in Section 304. 5 6 of Rule 456,
AEROSPACE ASSEMBLY AND COMPONENT COATING OPERATIONS

. 110.8 The provisions of this rule shall not apply to degreasing of high-voltage microwave

vacuum tubes.

200 DEFINITIONS

201 AIRTIGHT/AIRLESS CLEANING SYSTEM: A sealed cleaning system that has no open air/vapor or air/solvent interface, and is des igned and automatically operated to minimize the discharge or leakage of solvent vapor emissi ons to the atmosphere during all cleaning and vacuum drying operations. The system consis ts of devices to c ondense and re cover solvent and solvent vapor, and control devices to remove solvent vapors from all gas streams that vent to the atmosphere.SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

454-4 May 23, 2002 XX-XX-08 202 CIRCUMFERENTIAL TROUGH: A receptacle located below the primary condenser that conveys condensed solvent and atmospheric moisture to a water separator.

203 CLOSED CONTAINER: A container which has a nonabsorbent cover where the cover meets with the main body of the container without any visible gaps between the cover and the main body of the container.

204 CONVEYORIZED DEGREASER: Any continually loaded, conveyorized degreaser, using solvent that is maintained either above or below the initial boiling point temperature of the

solvent.

205 DEGREASER: A tank, tray, drum, or other container in which objects to be cleaned are exposed to a degreasing solvent or degreasing solvent vapor.

206 EXEMPT COMPOUND: For the purposes of this rule, “exempt compound” has the same meaning as in Rule 101—GENERAL PROVISIONS AND DEFINITIONS.

207 FREEBOARD HEIGHT: 207.1 For non-vapor degreasers, freeboard height means the distance from the top of the solvent to the top of the tank. 207.2 For vapor degreasers, freeboard height means the distance from the solvent vapor-air interface to the top of the degreaser.

208 FREEBOARD RATIO: The freeboard height divided by the sm aller of the inside length or the inside width of the degreaser's evaporative surface area.

209 KEY SYSTEM OPERATING PARAMETER: 209.1 A variable that is critical to the operation of an emission control system and that

ensures: a. Operation of the system within the system manufacturer’s specifications,

and b. Compliance with the overall system efficiency standard required by Section

306. 209.2 Such variables may include, but are not limited to: a. Hours of operation, b. Temperature, c. Flow rate, and

d. Pressure.

210 LEAK: A leak is: 210.1 The dripping of liquid volatile organic compounds in excess of three drops per minute; or 210.2 The appearance of a visible mist.

211 LIP EXHAUST SYSTEM: A system which collects solvent vapors escaping from the top of a degreaser and directs them away from operating personnel.

212 LOW VOLATILITY SOLVENT: Any solvent with an initial boiling point which is greater than

248 o F (120 o C).

213 MAKEUP SOLVENT: The solvent added to the degreaser to replace solvent lost through evaporation or other means.

214 NESHAP: National Emission Standards for Hazardous Air Pollutants.SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

May 23, 2002 XX-XX-08 454-5 215 NON-VAPOR DEGREASER: Any degreaser , including a remote reservoir degreaser, using solvent which, if heated, is maintained below the initial boiling point temperature of the

solvent.

216 OPEN-TOP VAPOR DEGREASER: Any batch-loaded degreaser using solvent which is maintained above the initial boiling point temperature of the solvent. Degreasing occurs through the condensation of the resultant solvent vapor onto the surface of the workload.

217 OSHA: Occupational Safety and Health Administration.

218 REFRIGERATED FREEBOARD CHILLER: A secondary cooling coil mounted above the primary condenser which provides a chilled air blanket above the solvent vapor-air interface

to cause the condensation of additional solvent vapor, thereby increasing vapor control efficiency.

219 REMOTE RESERVOIR DEGREASER: A non-vapor degreaser with a tank which is completely enclosed except for a solvent return opening no larger than 15.50 square inches (100 square centimeters) which allows used solvent to drain into it from a separate solvent sink or work area and which is not accessible for soaking workloads.

220 SOLVENT: Any liquid containing a volatile organic compound or combination of volatile organic compounds, which is used to perform solvent degreasing.

221 SOLVENT DEGREASING: The removal of contaminants with solvents from parts, products, tools, machinery, and equipment, including the subsequent drying of the items.

222 STATIONARY SOURCE: Any building, structure, facility, or emissions unit which emits or may emit any affected pollutant directly or as a fugitive emission. 222.1 Building, structure, facility, or emissions unit includes all pollutant emitting activities

which: a. Belong to the same industrial grouping, and b. Are located on one property, or two or more contiguous properties, and c. Are under the same or common ownership, operation, or control, or which are owned or operated by entities which are under common control. 222.2 Pollutant emitting activities shall be considered as part of the same industrial grouping if: a. They belong to the same two-digit Standard Industrial Classification (SIC) code, or b. They are part of a common production process, which includes industrial processes, manufacturing processes and any connected processes involving a common material.

223 SUPERHEATED VAPOR ZONE: A region located within the vapor zone of a degreaser whereby solvent vapors are heated above the solvent's boiling point.

224 VOLATILE ORGANIC COMPOUND (VOC): For the purposes of this rule, “volatile organic compound” has the same meaning as in Rule 101—GENERAL PROVISIONS AND

DEFINITIONS.

225 VOLATILE SOLVENT: Any solvent which is not defined as a low volatility solvent pursuant to
Section 212.

226 WATER SEPARATOR: A device that isolates water from an organic solvent or a mixture of organic solvents by a variety of means including, but not limited to, extraction, evaporation, distillation, drying, adsorption, and filtration.SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

454-6 May 23, 2002 XX-XX-08 22 6 7 WIPE CLEANING: A method of cleaning which utilizes a material such as a rag wetted with a solvent, coupled with a physical rubbing process to remove contaminants from metal

surfaces.

22 7 8 WORKLOAD: The objects put in a degreaser for the purpose of removing oil, grease, soil, coating, dirt or other undesirable matter from the surface of the objects.

300 STANDARDS

301 GENERAL EQUIPMENT REQUIREMENTS: Any person who uses a degreaser or a remote reservoir degreaser shall utilize the following equipment: 301.1 An apparatus or cover which prevents the solvent from evaporating when not processing work in the degreaser. a. For non-vapor degreasers using volatile solvent, or solvent that is agitated, the cover shall be designed so that it can be opened and closed easily with

one hand. b. For open-top vapor degreasers, the cover shall be designed such that it can be opened and closed easily without disturbing the vapor zone. c. For conveyorized degreasers, a cover shall be provided for closing off the

entrance and exit when not in use. 301.2 A facility for draining cleaned parts so that the drained solvent is returned to the

container. 301.3 A permanent, conspicuous label which summarizes operating requirements contained in Sections 306 through 308 of this rule. 301.4 Use only solvent containers free of all liquid leaks. Auxiliary equipment such as pumps, pipelines, or flanges, shall not have any liquid leaks, visible tears, or cracks.

302 NON-VAPOR DEGREASERS; EQUIPMENT REQUIREMENTS: In addition to the applicable requirements in Section 301, a pers on operating a non-vapor degreaser shall also comply with the following requirements:

302.1 A person shall only operate non-vapor degreasers , including remote reservoir degreasers ( except as noted in Section 110.2)

, using one of the following control

devices: a. Non-vapor degreasers shall operate with a freeboard ratio equal to or greater than 0.75 if using solvents which are: i. Agitated, or

ii. Heated above 122 o F (50 o C), or

iii. Volatile. b. Non-vapor degreasers using only low volatility solvents which are not agitated shall operate with a freeboard height of at least 6 inches. c. A water cover may be used as an acceptable alternative to Sections a and

d b if the solvent is insoluble in water and has a specific gravity greater than

1.

302.2 On or after May 22, 2003 Prior to (one year after date of adoption)

, a person owning or operating a non-vapor degreaser shall use solvents with a VOC content of 50 grams per liter or less including water and exempt compounds, or use an airtight/airless cleaning system. The airtigh t/airless cleaning system shall comply with the requirements in Section 303.302.3 Effective (one year after date of adoption), a person owning or operating a nonvapor degreaser shall use a solvent with a VOC content of 25 grams per liter or less including water and exempt compounds, or use an airtight/airless cleaning system. The airtight/airless cleaning system shall comply with the requirements in Section

303.

303 AIRTIGHT/AIRLESS CLEAN ING SYSTEM REQUIREMENTS : In lieu of complying with the applicable requirements in Sections 302, 304, or 307, a person may use an airtight/airless cleaning system that complies with the following requirements:SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

May 23, 2002 XX-XX-08 454-7 303.1 The airtight/airless cleaning system shall be operated in accordance with the manufacturer's specifications and operated with a door or other pressure sealing apparatus that is in place during all cleaning and drying cycles; 303.2 The airtight/airless cleaning system shall not have a vapor leak of more than 50 parts per million measured as methane at the outlet of the airtight/airless cleaning system as indicated by a portable analyzer pursuant to Section 502.7; 303.3 All waste solvent shall be stored in properly identified and closed containers; 303.4 All associated pressure relief devices shall not allow liquid solvents to drain out; and 303.5 Spills during solvent transfer shall be wiped up immediately and the used wipe rags

shall be stored in closed containers.

304 VAPOR DEGREASERS; EQUIPMENT REQUIREMENTS: In addition to the applicable requirements in Section 301, a person shall operat e ing the a vapor degreaser shall also comply with the following requirements:

304.1 Until May 22, 2003, a person shall operate vapor degreasers using one or a combination of the following control devices:

a. A freeboard ratio greater than or equal to 0.75; or

b. A refrigerated freeboard chiller for which the chilled air blanket temperature ( o F) at the coldest point on the vertical axis in the center of the air

- vapor interface shall be no greater than 30% of the initial boiling point ( o F) of the fresh solvent used, or 41 o F.

c. A carbon adsorptio n system which ventilates the air

- vapor interface at a

minimum rate of 15 m 3 /min/m 2 , but not greater than 20 m 3 /min/m 2 , unless necessary to meet Federal and State OSHA requirements, with a solvent vapor concentration exiting the exhaust duct of the carbon adsorber of less than 25 ppm solvent averaged over one complete adsorption cycle, and an overall capture and control efficiency of 85 percent.

304. 2 1 Effective May 22, 2003, a A person shall not operate a vapor degreaser unless the vapor degreaser shall be is equipped with: a. An automated parts handling system; b. Circumferential primary condensing coils; c. A circumferential trough; d. A water separator; e. A freeboard ratio of at least 1.0; f. A superheated vapor zone; and g. A refrigerated freeboard chiller for which the chilled air blanket temperature ( o F) at the coldest point on the vertical axis in the center of the air-vapor interface shall be no greater than 30% of the initial boiling point ( o F) of the fresh solvent used, or 41 o F.

304. 3 2 In lieu of complying with the requirements in Section 304. 2 1 , a carbon adsorption system which ventilates the air-vapor interface at a minimum rate of 15 m 3 /min/m 2

, but not greater than 20 m 3 /min/m 2 , unless necessary to meet Federal and State OSHA requirements, with a solvent vapor concentration exiting the exhaust duct of the carbon adsorber of less than 25 ppm solvent averaged over one complete adsorption cycle, and an overall capture collection and control efficiency of 85 percent. 304.3 Effective (one year after date of adopt ion), a person owning or operating a vapor degreaser shall use a solvent with a VOC content of 25 grams per liter or less including water and exempt compounds, or use an airtight/airless cleaning system. The airtight/airless cleaning system shall comply with the requirements in Section

303.

305 REMOTE RESERVOIR DEGREASER: On or after May 22, 2003, a In addition to the applicable requirements in Sections 301 and 302, a person owning or operating a remote reservoir degreaser shall comply with the following requirements: 305.1 Prevent solvent vapors from escaping from the solvent container by using such devices as a cover or a valve when the remote reservoir is not being used, cleaned, or repaired;SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

454-8 May 23, 2002 XX-XX-08 305.2 Direct solvent flow in to prevent liquid solvent from splashing outside of the remote reservoir degreaser; 305.3 Use only solvent containers free of all liquid leaks. Auxiliary equipment such as pumps, pipelines, or flanges, shall not have any liquid leaks, visible tears, or cracks.

306 VAPOR DEGREASERS; SAFETY SWITCHES: If a vapor degreaser is used, then the following equipment shall be utilized. 306.1 A device which shuts off the sump heater if the condenser coolant stops circulating or becomes warmer than specified; 306.2 For spray degreasers, a device which prevents spray pump operation unless the solvent vapor level is at the designed operating level; and 306.3 A manual rest device which shuts off the sump heater if the solvent vapor level rises above the designed operating level.

307 CONVEYORIZED DEGREASERS: In addition to the requirements of Sections 302 and 304, a person shall not operate a conveyorized degreaser unless it is equipped with both of the following control devices: 307.1 Either a drying tunnel or other means such as a rotating basket, sufficient to prevent cleaned parts from carrying out solvent liquid or vapor, and 307.2 Minimized opening: entrances and exits s hould silhouette workloads so that the average clearance between parts and the edge of the degreaser opening is either less than 4 inches (10 cm) or less than 10 percent of the width of the opening.

308 GENERAL OPERATING REQUIREMENTS: Any person who uses a degreaser must conform to the following operating requirements: 308.1 Operate and maintain the degreaser and emission control equipment in proper working order. 308.2 Do not allow any solvent to leak from any portion of the degreaser. 308.3 Do not store or dispose of any solvent from the degreaser, including waste solvent, in a manner that causes or allows any volatile organic compounds emissions. 308.4 If distillation recovery of waste solvent is performed, solvent residues shall not contain more than 10 percent solvent by volume after distillation. 308.5 Do not remove or open any device designed to cover the solvent unless processing work in the degreaser or performing maintenance on the degreaser. 308.6 Drain cleaned parts after cleaning until dr ipping ceases (non-vapor degreaser only). 308.7 If using a solvent flow, use only a continuous , fluid stream (not a fine, atomized, or shower type spray) at a pressure which does not cause liquid solvent to splash outside of the degreaser. 308.8 Perform solvent agitation, where nece ssary, by means other than air agitation. 308.9 Do not degrease porous or absorbent materials such as cloth, leather, wood, or rope. 308.10 For vapor degreasers: a. Workloads shall not occupy more than half of the degreaser's evaporative surface area, and b. Solvent spray shall be kept at least 4 inches below the air-vapor interface. c. When starting the degreaser, the cooling system shall be turned on before, or simultaneously with, the sump heater. d. When shutting down the degreaser, the sump heater shall be turned off before, or simultaneously with, the cooling system. e. The degreaser shall be covered whenever the cooling system is off. 308.11 Minimize solvent carryout by the following measures, as applicable: a. Rack workload to facilitate drainage; b. Move workload in and out of the degreaser at less than 3.3 m/min (11 ft/min); c. Degrease the workload in the vapor zone until condensation ceases; d. Allow workload to dry within the degreaser until visually dry; e. For manual operation, tip out any pools of solvent remaining on the workload before removing it from the degreaser. 308.12. All waste solvent shall be stored in properly identified and closed containers;SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

May 23, 2002 XX-XX-08 454-9 308.13 All associated pressure relief devices shall not allow liquid solvents to drain out; and 308.14 Spills during solvent transfer shall be wiped up immediately and the used wipe rags

shall be stored in closed containers.

309 LIP EXHAUST SYSTEM: A lip exhaust system shall not be used on any degreaser, unless it

is vented to an emission s control system, pursuant to Section 310 equipment provided the emissions control equipment satisfies the requirements specified below . The lip exhaust shall be turned off when the degreaser is covered. 309.1 The emissions control equipment is approved by the Air Pollution Control Officer pursuant to Rule 201 – GENERAL PERMIT REQUIREMENTS, and 309.2 The emissions control equipment is designed and operated with an overall collection and control device efficiency (the collecti on efficiency multiplied by the control efficiency) of at least 85 percent on a mass basis, as determined pursuant to Sections 402, 502.2 and 502.3. 309.3 The emission collection system shall have a ventilation rate not greater than 20 cubic meters per minute per square meter over the total area of the degreaser's evaporative surface area, unless the rate must be changed to meet Federal and State OSHA requirements.

310 EMISSIONS CONTROL EQUIPMENT: Prior to (one year after date of adoption), A a s an alternative to complying with the applicable requi rements of Sections 302, 304, or 307 of this rule, a person may use emissions control equi pment, subject to the approval of the Air Pollution Control Officer, provided the emissions control equipment satisfies the following requirements: 310.1 The emissions control equipment is approved by the Air Pollution Control Officer pursuant to Rule 201 – GENERAL PERMIT REQUIREMENTS, and 310.2 The emissions control equipment is designed and operated with an overall collection and control device efficiency (the collecti on efficiency multiplied by the control efficiency) of at least 85 percent on a mass basis, as determined pursuant to Sections 402, 502.2 and 502.3. 310.3 The emission collection system shall have a ventilation rate not greater than 20 cubic meters per minute per square meter over the total area of the degreaser's evaporative surface area, unless the rate must be changed to meet Federal and State OSHA requirements.

400 ADMINISTRATIVE REQUIREMENTS

401 CALCULATION FOR DETERMINATION OF VOC CONTENT OF MATERIAL INCLUDING

WATER A B N D EXEMPT COMPOUNDS: The volume of solvent is defined as the volume of the original solvent, plus any VOC-containing material added to the original solvent. The weight of VOC per volume of solvent shall be calculated by the following equation:


# ( ) ( )

S ec W V 

### V W W W

− −

Where: W

v = weight of all volatile organic compounds.

W

w = weight of water.

W
ec = weight of exempt compounds

V S = volume of solvent.

402 CALCULATION FOR DETERMINING PERCENT CONTROL EFFICIENCY AND VOC

MASS EMISSION RATE: The VOC mass emission rate shall be calculated both upstream

and downstream of the emissions control equipment based on the VOC mass concentration and volumetric flowrate, pursuant to Sections 502.3, 502.4 and the following equations:

402.1 VOC Mass Emission Rate:SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

454-10 May 23, 2002 XX-XX-08 

### ) ( ) 60 ( * ) ( * ) ( downstream and upstream calculated hr m C Q M =

Where: M = VOC mass emission rate (upstream/downstream), in lb/hr. Q = the volumetric flowrate at the inlet (upstream) or exhaust stack outlet (downstream), in standard cubic feet per minute as determined by Section 502.3. C = the VOC mass concentration at the inlet (upstream) or outlet (downstream), in pounds per standard cubic feet, as determined pursuant to Section 502.3.

402.2 The percent control efficiency is calculated as follows:



### 100 * % ⎟ ⎟ ⎠ ⎞ ⎜ ⎜ ⎝ ⎛

−

=

u d u 

### M M M CE

Where: CE = control efficiency.

M
u = the upstream VOC mass emission rate, in lb/hr.

M d = the downstream VOC mass emission rate, in lb/hr.

403 OPERATION AND MAINTENANCE PLAN: Any person using an approved emission control device pursuant to Section s 309 and 310 must submit an Operat ion and Maintenance plan for the emissions control equipment to the Air Pollution Control Officer for approval. The plan shall specify operation and maintenance procedur es that demonstrate continuous operation and compliance of the emissions control equipm ent during periods of emissions-producing operations. The plan shall specify key system operating parameters such as temperatures, pressures, and flow rates, necessary to determine compliance with this rule and shall describe in detail procedures to maintain the approved control device. The plan shall specify which records must be kept to document t hese operations and maint enance procedures. The records shall comply with the requirements of Section 501. The plan shall be implemented upon approval by the Air Pollution Control Officer.

500 MONITORING AND RECORDS

501 RECORDKEEPING: In addition to any existing permit conditions issued pursuant to Rule 201, GENERAL PERMIT REQUIREMENTS any person subject to this rule shall comply with the following requirements:

501.1 List of Materials: A list shall be maintained of all solvents currently used and/or stored at the site. The list shall include the following information: a. Cleaning material type by name/code/manufacturer. b. The actual VOC content of cleaning material listed in Section 302, as applied including water and exempt compounds. c. The actual mixing ratio for the cleaning material as applied.

501.2 Usage Records: Any person using cleaning materials regulated by this rule shall update and maintain the records as required by this rule as follows:

a. Monthly: 1. Records of total applied volume in gallons for each cleaning

material used. 2. Record of solvent cleaning activity associated with each solvent

used.

501.3 Emissions Control Equipment: Any person using an emission control system pursuant to this rule shall maintain such records on a daily basis, of key system operating parameters for emission control equipment, including, but not limited to: a. Hours of operation; b. Routine and non-routine maintenance; and c. The records required by Section 403 as part of the Operation and

Maintenance Plan.SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

May 23, 2002 XX-XX-08 454-11 d. Records of test reports conducted pursuant to Section 502.

501. 5 4 Duration of Records: a. Prior to (two years after date of adoption), R r ecords shall be maintained onsite for a continuous three-year peri od and made available for review by the Air Pollution Control Officer upon request.b. Effective (two years after date of adoption), records shall be maintained onsite for a continuous five-year period and made available for review by the Air Pollution Control Officer upon request.

502 TEST METHODS

502.1 DETERMINATION OF BOILING POINT: The initial boiling point of solvents shall be
determined in accordance with ASTM D 1078-0 1 5

. 502.2 DETERMINATION OF CONTROL EFFICIENCY: Control efficiency of control equipment shall be determined in accordance with United States Environmental Protection Agency Method 18, 25, or 25A (whichever is applicable).

502.3 DETERMINATION OF COLLECTION EFFICIENCY: Efficiency of the collection system shall be determined in accordance with the United St ates Environmental Protection Agency's Guidelines for Determining Capture Efficiency, January 9,

1995 . Individual capture efficiency test runs subject to United States Environmental Protection Agency techni cal guidelines shall be determined by: Collection efficiency shall be determined in accordance with the U.S. EPA technical guideline document, “Guidelines for Determining Capture Efficiency,” dated January 9, 1995. Individual capture e fficiency test runs subject to U.S. EPA technical guidelines shall be determined by: a. Applicable United States Environmental Protection Agency U.S. EPA Methods 204, 204A, 204B, 204C, 204D, 204E, and/or 204F; or b. Any other method approved by United States Environmental Protection Agency U.S. EPA , the California Air Resources Board, and the Air Pollution

Control Officer.

502.4 DETERMINATION OF VOLUMETRIC FLOWRATE: Volumetric flowrate shall be determined in accordance with United States Environmental Protection Agency Methods 2, 2A, or 2C, or 2D (whichever is applicable).

502.5 DETERMINATION OF VOC CONTENT: VOC content of solvents shall be determined in accordance with United States Environmental Protection Agency

Method 24 and Sections 402 and 502.6 of this rule.

502.6 DETERMINATION OF COMPOUNDS EXEMPT FROM VOC DEFINITION: Compounds exempted from the VOC definition, as in Section 206 of this rule, shall

be determined in accordance with ASTM D 4457- 91 02 (2008) or California Air Resources Board Method 432. If any of the perfluorocarbons or volatile cyclic and linear methyl siloxanes are being claim ed as exempt compounds, the person making the claim must state in advance which compounds are present, and the United States Environmental Protection Agency approved test method used to make the determination of these compounds.

502.7 DETERMINATION OF VOC LEAKS: Vapor VOC leaks shall be determined in accordance with United States Environmental Protection Agency test Method 21.

502.8 MULTIPLE TEST METHODS: When more than one test method or set of test methods is specified for any testing, a vi olation of any requirement of this rule established by any one of the specified test methods or set of test methods shall

constitute a violation of this rule.SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

September 25, 2008 454-1 RULE 454 DEGREASING OPERATIONS Adopted 6-5-79 (Amended 7-23-81, 11-29-83, 2-23-93, 9-5-96, 4-3-97, 5-23-02, 9-25-08)

INDEX

100 GENERAL
101 PURPOSE

102 APPLICABILITY

103 SEVERABILITY

110 EXEMPTIONS

200 DEFINITIONS
201 AIRTIGHT/AIRLESS CLEANING SYSTEM

202 CIRCUMFERENTIAL TROUGH

203 CLOSED CONTAINER

204 CONVEYORIZED DEGREASER

205 DEGREASER

206 EXEMPT COMPOUND

207 FREEBOARD HEIGHT

208 FREEBOARD RATIO

209 KEY SYSTEM OPERATING PARAMETER:

210 LEAK
211 LIP EXHAUST SYSTEM

212 LOW VOLATILITY SOLVENT

213 MAKEUP SOLVENT

214 NESHAP

215 NON-VAPOR DEGREASER

216 OPEN-TOP VAPOR DEGREASER

217 OSHA

218 REFRIGERATED FREEBOARD CHILLER

219 REMOTE RESERVOIR DEGREASER

220 SOLVENT

221 SOLVENT DEGREASING

222 STATIONARY SOURCE

223 SUPERHEATED VAPOR ZONE 224 VOLATILE ORGANIC COMPOUND (VOC)

225 VOLATILE SOLVENT

226 WATER SEPARATOR

227 WIPE CLEANING

228 WORKLOAD

300 STANDARDS
301 GENERAL EQUIPMENT REQUIREMENTS 302 NON-VAPOR DEGREASERS; EQUIPMENT REQUIREMENTS
303 AIRTIGHT/AIRLESS CLEANING SYSTEM REQUIREMENTS 304 VAPOR DEGREASERS; EQUIPMENT REQUIREMENTS

305 REMOTE RESERVOIR DEGREASER 306 VAPOR DEGREASERS; SAFETY SWITCHES

307 CONVEYORIZED DEGREASERS
308 GENERAL OPERATING REQUIREMENTS

309 LIP EXHAUST SYSTEM
310 EMISSIONS CONTROL EQUIPMENTSACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

454-2 September 25, 2008 400 ADMINISTRATIVE REQUIREMENTS
401 CALCULATION FOR DETERMINATION OF VOC CONTENT OF MATERIAL INCLUDING

WATER AND EXEMPT COMPOUNDS

402 CALCULATION FOR DETERMINING PERCENT CONTROL EFFICIENCY AND VOC MASS

EMISSION RATE

403 OPERATION AND MAINTENANCE PLAN

500 MONITORING AND RECORDS
501 USAGE RECORDS

502 TEST METHODSSACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

September 25, 2008 454-3 100 GENERAL

101 PURPOSE: To limit the emission of volatile organic compounds from degreasers.

102 APPLICABILITY: This rule applies to solvent degreasing operations.

103 SEVERABILITY : If a court of competent jurisdiction issues an order that any provision of this rule is invalid, it is the intent of the Board of Directors of the District that other provisions of this rule remain in full force and effect, to the extent allowed by law.

110 EXEMPTIONS: 110.1 The provisions of this rule do not apply to wipe cleaning. 110.2 Prior to September 25, 2009, the provisions of this rule shall not apply to non-vapor degreasers which use solvents that contain 50 grams per liter or less VOCs including water and exempt compounds. 110.3 Effective September 25, 2009, the provis ions of this rule shall not apply to degreasers which use solvents that contain 25 grams per liter or less VOCs including water and exempt compounds, as determined by Sections 502.5 and 502.6. 110.4 The provisions of Section 308.7 of this rule do not apply to open-top vapor degreasers where solvent flow complies with Section 308.10.b. and liquid solvent does not splash above the air-vapor interface. 110.5 Prior to September 25, 2009, the provisions of this rule shall not apply to solvent degreasing operations that are subject to the NESHAP requirements of 40 CFR Part 63 Subpart T- Halogenated Solvents Emissions from Solvent Cleaning. 110.6 The provisions of this rule shall not apply to products subject to the Air Resources Board Consumer Products Regulations as se t forth at Subchapter 8.5, Article 2, Section 94507-94517 of Title 17 of the California Code of Regulations. 110.7 The VOC content limits in Sections 302.2 and 302.3 do not apply to degreasing of tools, equipment and machinery, regulated under Rule 456, AEROSPACE

ASSEMBLY AND COMPONENT COATING O PERATIONS, and aerospace products using solvents that comply with the surface preparation and cleanup VOC limits in Section 304.7 of Rule 456, AEROSPACE ASSEMBLY AND COMPONENT

COATING OPERATIONS

. 110.8 The provisions of this rule shall not apply to degreasing of high-voltage microwave

vacuum tubes.

200 DEFINITIONS

201 AIRTIGHT/AIRLESS CLEANING SYSTEM: A sealed cleaning system that has no open air/vapor or air/solvent interface, and is des igned and automatically operated to minimize the discharge or leakage of solvent vapor emissi ons to the atmosphere during all cleaning and vacuum drying operations. The system consis ts of devices to c ondense and re cover solvent and solvent vapor, and control devices to remove solvent vapors from all gas streams that vent to the atmosphere.

202 CIRCUMFERENTIAL TROUGH: A receptacle located below the primary condenser that conveys condensed solvent and atmospheric moisture to a water separator.

203 CLOSED CONTAINER: A container which has a nonabsorbent cover where the cover meets with the main body of the container without any visible gaps between the cover and the main body of the container.

204 CONVEYORIZED DEGREASER: Any continually loaded, conveyorized degreaser, using solvent that is maintained either above or below the initial boiling point temperature of the

solvent.SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

454-4 September 25, 2008 205 DEGREASER: A tank, tray, drum, or other container in which objects to be cleaned are exposed to a degreasing solvent or degreasing solvent vapor.

206 EXEMPT COMPOUND: For the purposes of this rule, “exempt compound” has the same meaning as in Rule 101—GENERAL PROVISIONS AND DEFINITIONS.

207 FREEBOARD HEIGHT: 207.1 For non-vapor degreasers, freeboard height means the distance from the top of the solvent to the top of the tank. 207.2 For vapor degreasers, freeboard height means the distance from the solvent vapor-air interface to the top of the degreaser.

208 FREEBOARD RATIO: The freeboard height divided by the sm aller of the inside length or the inside width of the degreaser's evaporative surface area.

209 KEY SYSTEM OPERATING PARAMETER: 209.1 A variable that is critical to the operation of an emission control system and that

ensures: a. Operation of the system within the system manufacturer’s specifications,

and b. Compliance with the overall system efficiency standard required by Section

306. 209.2 Such variables may include, but are not limited to: a. Hours of operation, b. Temperature, c. Flow rate, and

d. Pressure.

210 LEAK: A leak is: 210.1 The dripping of liquid volatile organic compounds in excess of three drops per minute; or 210.2 The appearance of a visible mist.

211 LIP EXHAUST SYSTEM: A system which collects solvent vapors escaping from the top of a degreaser and directs them away from operating personnel.

212 LOW VOLATILITY SOLVENT: Any solvent with an initial boiling point which is greater than

248 o F (120 o C).

213 MAKEUP SOLVENT: The solvent added to the degreaser to replace solvent lost through evaporation or other means.

214 NESHAP: National Emission Standards for Hazardous Air Pollutants.

215 NON-VAPOR DEGREASER: Any degreaser, including a remote reservoir degreaser, using solvent which, if heated, is maintained below the initial boiling point temperature of the

solvent.

216 OPEN-TOP VAPOR DEGREASER: Any batch-loaded degreaser using solvent which is maintained above the initial boiling point temperature of the solvent. Degreasing occurs through the condensation of the resultant solvent vapor onto the surface of the workload.

217 OSHA: Occupational Safety and Health Administration.

218 REFRIGERATED FREEBOARD CHILLER: A secondary cooling coil mounted above the primary condenser which provides a chilled air blanket above the solvent vapor-air interface

to cause the condensation of additional solvent vapor, thereby increasing vapor control efficiency.SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

September 25, 2008 454-5 219 REMOTE RESERVOIR DEGREASER: A non-vapor degreaser with a tank which is completely enclosed except for a solvent return opening no larger than 15.50 square inches (100 square centimeters) which allows used solvent to drain into it from a separate solvent sink or work area and which is not accessible for soaking workloads.

220 SOLVENT: Any liquid containing a volatile organic compound or combination of volatile organic compounds, which is used to perform solvent degreasing.

221 SOLVENT DEGREASING: The removal of contaminants with solvents from parts, products, tools, machinery, and equipment, including the subsequent drying of the items.

222 STATIONARY SOURCE: Any building, structure, facility, or emissions unit which emits or may emit any affected pollutant directly or as a fugitive emission. 222.1 Building, structure, facility, or emissions unit includes all pollutant emitting activities

which: a. Belong to the same industrial grouping, and b. Are located on one property, or two or more contiguous properties, and c. Are under the same or common ownership, operation, or control, or which are owned or operated by entities which are under common control. 222.2 Pollutant emitting activities shall be considered as part of the same industrial grouping if: a. They belong to the same two-digit Standard Industrial Classification (SIC) code, or b. They are part of a common production process, which includes industrial processes, manufacturing processes and any connected processes involving a common material.

223 SUPERHEATED VAPOR ZONE: A region located within the vapor zone of a degreaser whereby solvent vapors are heated above the solvent's boiling point.

224 VOLATILE ORGANIC COMPOUND (VOC): For the purposes of this rule, “volatile organic compound” has the same meaning as in Rule 101—GENERAL PROVISIONS AND

DEFINITIONS.

225 VOLATILE SOLVENT: Any solvent which is not defined as a low volatility solvent pursuant to
Section 212.

226 WATER SEPARATOR: A device that isolates water from an organic solvent or a mixture of organic solvents by a variety of means including, but not limited to, extraction, evaporation, distillation, drying, adsorption, and filtration.

227 WIPE CLEANING: A method of cleaning which utilizes a material such as a rag wetted with a solvent, coupled with a physical rubbing process to remove contaminants from metal

surfaces.

228 WORKLOAD: The objects put in a degreaser for the purpose of removing oil, grease, soil, coating, dirt or other undesirable matter from the surface of the objects.

300 STANDARDS

301 GENERAL EQUIPMENT REQUIREMENTS: Any person who uses a degreaser shall utilize the following equipment: 301.1 An apparatus or cover which prevents the solvent from evaporating when not processing work in the degreaser. a. For non-vapor degreasers using volatile solvent, or solvent that is agitated, the cover shall be designed so that it can be opened and closed easily with

one hand.SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

454-6 September 25, 2008 b. For open-top vapor degreasers, the cover shall be designed such that it can be opened and closed easily without disturbing the vapor zone. c. For conveyorized degreasers, a cover shall be provided for closing off the

entrance and exit when not in use. 301.2 A facility for draining cleaned parts so that the drained solvent is returned to the

container. 301.3 A permanent, conspicuous label which summarizes operating requirements contained in Sections 306 through 308 of this rule. 301.4 Use only solvent containers free of all liquid leaks. Auxiliary equipment such as pumps, pipelines, or flanges, shall not have any liquid leaks, visible tears, or cracks.

302 NON-VAPOR DEGREASERS; EQUIPMENT REQUIREMENTS: In addition to the applicable requirements in Section 301, a pers on operating a non-vapor degreaser shall also comply with the following requirements:

302.1 A person shall only operate non-vapor degreasers using one of the following control

devices: a. Non-vapor degreasers shall operate with a freeboard ratio equal to or greater than 0.75 if using solvents which are: 1. Agitated, or

2. Heated above 122 o F (50 o C), or

3. Volatile. b. Non-vapor degreasers using only low volatility solvents which are not agitated shall operate with a freeboard height of at least 6 inches. c. A water cover may be used as an acceptable alternative to Sections a and b if the solvent is insoluble in water and has a specific gravity greater than 1. 302.2 Prior to September 25, 2009

, a person owning or operating a non-vapor degreaser shall use solvents with a VOC content of 50 grams per liter or less including water and exempt compounds, or use an airtight/airless cleaning system. The airtight/airless cleaning system shall comp ly with the requirements in Section 303. 302.3 Effective September 25, 2009, a person owning or operating a non- vapor degreaser shall use a solvent with a VOC content of 25 grams per liter or less including water and exempt compounds, or use an airtight/airless cleaning system. The airtight/airless cleaning system shall comp ly with the requirements in Section 303.

303 AIRTIGHT/AIRLESS CLEANING SYSTEM REQUIREMENTS : In lieu of complying with the applicable requirements in Sections 302, 304, or 307, a person may use an airtight/airless cleaning system that complies with the following requirements: 303.1 The airtight/airless cleaning system shall be operated in accordance with the manufacturer's specifications and operated with a door or other pressure sealing apparatus that is in place during all cleaning and drying cycles; 303.2 The airtight/airless cleaning system shall not have a vapor leak of more than 50 parts per million measured as methane at the outlet of the airtight/airless cleaning system as indicated by a portable analyzer pursuant to Section 502.7; 303.3 All waste solvent shall be stored in properly identified and closed containers; 303.4 All associated pressure relief devices shall not allow liquid solvents to drain out; and 303.5 Spills during solvent transfer shall be wiped up immediately and the used wipe rags

shall be stored in closed containers.

304 VAPOR DEGREASERS; EQUIPMENT REQUIREMENTS: In addition to the applicable requirements in Section 301, a person operating a vapor degreaser shall also comply with the following requirements: 304.1 A person shall not operate a vapor degreaser unless the vapor degreaser is equipped with: a. An automated parts handling system; b. Circumferential primary condensing coils; c. A circumferential trough; d. A water separator; e. A freeboard ratio of at least 1.0;SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

September 25, 2008 454-7 f. A superheated vapor zone; and g. A refrigerated freeboard chiller for which the chilled air blanket temperature ( o F) at the coldest point on the vertical axis in the center of the air-vapor interface shall be no greater than 30% of the initial boiling point ( o F) of the fresh solvent used, or 41 o F. 304.2 In lieu of complying with the requirements in Section 304.1, a carbon adsorption system which ventilates the air-vapor interface at a minimum rate of 15 m 3 /min/m 2

, but not greater than 20 m 3 /min/m 2 , unless necessary to meet Federal and State OSHA requirements, with a solvent vapor concentration exiting the exhaust duct of the carbon adsorber of less than 25 ppm solvent averaged over one complete adsorption cycle, and an overall collection and control efficiency of 85 percent. 304.3 Effective September 25, 2009, a person owning or operating a vapor degreaser shall use a solvent with a VOC content of 25 grams per liter or less including water and exempt compounds, or use an airtight/airless cleaning system. The airtight/airless cleaning system shall comply with the requirements in Section 303.

305 REMOTE RESERVOIR DEGREASER: In addition to the applicable requirements in Sections 301 and 302, a person owning or operating a remote reservoir degreaser shall comply with the following requirements: 305.1 Prevent solvent vapors from escaping from the solvent container by using such devices as a cover or a valve when the remote reservoir is not being used, cleaned, or repaired; 305.2 Direct solvent flow in to prevent liquid solvent from splashing outside of the remote reservoir degreaser; 305.3 Use only solvent containers free of all liquid leaks. Auxiliary equipment such as pumps, pipelines, or flanges, shall not have any liquid leaks, visible tears, or cracks.

306 VAPOR DEGREASERS; SAFETY SWITCHES: If a vapor degreaser is used, then the following equipment shall be utilized. 306.1 A device which shuts off the sump heater if the condenser coolant stops circulating or becomes warmer than specified; 306.2 For spray degreasers, a device which prevents spray pump operation unless the solvent vapor level is at the designed operating level; and 306.3 A manual rest device which shuts off the sump heater if the solvent vapor level rises above the designed operating level.

307 CONVEYORIZED DEGREASERS: In addition to the requirements of Sections 302 and 304, a person shall not operate a conveyorized degreaser unless it is equipped with both of the following control devices: 307.1 Either a drying tunnel or other means such as a rotating basket, sufficient to prevent cleaned parts from carrying out solvent liquid or vapor, and 307.2 Minimized opening: entrances and exits s hould silhouette workloads so that the average clearance between parts and the edge of the degreaser opening is either less than 4 inches (10 cm) or less than 10 percent of the width of the opening.

308 GENERAL OPERATING REQUIREMENTS: Any person who uses a degreaser must conform to the following operating requirements: 308.1 Operate and maintain the degreaser and emission control equipment in proper working order. 308.2 Do not allow any solvent to leak from any portion of the degreaser. 308.3 Do not store or dispose of any solvent from the degreaser, including waste solvent, in a manner that causes or allows any volatile organic compounds emissions. 308.4 If distillation recovery of waste solvent is performed, solvent residues shall not contain more than 10 percent solvent by volume after distillation. 308.5 Do not remove or open any device designed to cover the solvent unless processing work in the degreaser or performing maintenance on the degreaser. 308.6 Drain cleaned parts after cleaning until dr ipping ceases (non-vapor degreaser only).SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

454-8 September 25, 2008 308.7 If using a solvent flow, use only a continuous , fluid stream (not a fine, atomized, or shower type spray) at a pressure which does not cause liquid solvent to splash outside of the degreaser. 308.8 Perform solvent agitation, where nece ssary, by means other than air agitation. 308.9 Do not degrease porous or absorbent materials such as cloth, leather, wood, or rope. 308.10 For vapor degreasers: a. Workloads shall not occupy more than half of the degreaser's evaporative surface area, and b. Solvent spray shall be kept at least 4 inches below the air-vapor interface. c. When starting the degreaser, the cooling system shall be turned on before, or simultaneously with, the sump heater. d. When shutting down the degreaser, the sump heater shall be turned off before, or simultaneously with, the cooling system. e. The degreaser shall be covered whenever the cooling system is off. 308.11 Minimize solvent carryout by the following measures, as applicable: a. Rack workload to facilitate drainage; b. Move workload in and out of the degreaser at less than 3.3 m/min (11 ft/min); c. Degrease the workload in the vapor zone until condensation ceases; d. Allow workload to dry within the degreaser until visually dry; e. For manual operation, tip out any pools of solvent remaining on the workload before removing it from the degreaser. 308.12 All waste solvent shall be stored in properly identified and closed containers; 308.13 All associated pressure relief devices shall not allow liquid solvents to drain out; and 308.14 Spills during solvent transfer shall be wiped up immediately and the used wipe rags

shall be stored in closed containers.

309 LIP EXHAUST SYSTEM: A lip exhaust system shall not be used on any degreaser, unless it is vented to emissions control equipment provi ded the emissions control equipment satisfies the requirements specified below. The lip exhaust shall be turned off when the degreaser is

covered. 309.1 The emissions control equipment is approved by the Air Pollution Control Officer pursuant to Rule 201 – GENERAL PERMIT REQUIREMENTS, and 309.2 The emissions control equipment is designed and operated with an overall collection and control device efficiency (the collecti on efficiency multiplied by the control efficiency) of at least 85 percent on a mass basis, as determined pursuant to Sections 402, 502.2 and 502.3. 309.3 The emission collection system shall have a ventilation rate not greater than 20 cubic meters per minute per square meter over the total area of the degreaser's evaporative surface area, unless the rate must be changed to meet Federal and State OSHA requirements.

310 EMISSIONS CONTROL EQUIPMENT: Prior to September 25, 2009, as an alternative to complying with the applicable requirements of Sections 302, 304, or 307 of this rule, a person may use emissions control equipment, subject to the approval of the Air Pollution Control Officer, provided the emissions control equipment satisfies the following requirements: 310.1 The emissions control equipment is approved by the Air Pollution Control Officer pursuant to Rule 201 – GENERAL PERMIT REQUIREMENTS, and 310.2 The emissions control equipment is designed and operated with an overall collection and control device efficiency (the collecti on efficiency multiplied by the control efficiency) of at least 85 percent on a mass basis, as determined pursuant to Sections 402, 502.2 and 502.3. 310.3 The emission collection system shall have a ventilation rate not greater than 20 cubic meters per minute per square meter over the total area of the degreaser's evaporative surface area, unless the rate must be changed to meet Federal and State OSHA requirements.SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

September 25, 2008 454-9 400 ADMINISTRATIVE REQUIREMENTS

401 CALCULATION FOR DETERMINATION OF VOC CONTENT OF MATERIAL INCLUDING

WATER AND EXEMPT COMPOUNDS: The volume of solvent is defined as the volume of the original solvent, plus any VOC-containing material added to the original solvent. The weight of VOC per volume of solvent shall be calculated by the following equation:


# ( ) ( )

S ec W V 

### V W W W

− −

Where: W

v = weight of all volatile organic compounds.

W

w = weight of water.

W
ec = weight of exempt compounds

V S = volume of solvent.

402 CALCULATION FOR DETERMINING PERCENT CONTROL EFFICIENCY AND VOC

MASS EMISSION RATE: The VOC mass emission rate shall be calculated both upstream

and downstream of the emissions control equipment based on the VOC mass concentration and volumetric flowrate, pursuant to Sections 502.3, 502.4 and the following equations:

402.1 VOC Mass Emission Rate:



### ) ( ) 60 ( * ) ( * ) ( downstream and upstream calculated hr m C Q M =

Where: M = VOC mass emission rate (upstream/downstream), in lb/hr. Q = the volumetric flowrate at the inlet (upstream) or exhaust stack outlet (downstream), in standard cubic feet per minute as determined by Section 502.4. C = the VOC mass concentration at the inlet (upstream) or outlet (downstream), in pounds per standard cubic feet, as determined pursuant to Section 502.4.

402.2 The percent control efficiency is calculated as follows:



### 100 * % ⎟ ⎟ ⎠ ⎞ ⎜ ⎜ ⎝ ⎛

−

=

u d u 

### M M M CE

Where: CE = control efficiency.

M
u = the upstream VOC mass emission rate, in lb/hr.

M d = the downstream VOC mass emission rate, in lb/hr.

403 OPERATION AND MAINTENANCE PLAN: Any person using an approved emission control device pursuant to Sections 309 and 310 must submit an Operation and Maintenance plan for the emissions control equipment to the Air Pollution Control Officer for approval. The plan shall specify operation and maintenance procedur es that demonstrate continuous operation and compliance of the emissions control equipm ent during periods of emissions-producing operations. The plan shall specify key system operating parameters such as temperatures, pressures, and flow rates, necessary to determine compliance with this rule and shall describe in detail procedures to maintain the approved control device. The plan shall specify which records must be kept to document t hese operations and maint enance procedures. The records shall comply with the requirements of Section 501. The plan shall be implemented upon approval by the Air Pollution Control Officer.SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

454-10 September 25, 2008 500 MONITORING AND RECORDS

501 RECORDKEEPING: In addition to any existing permit conditions issued pursuant to Rule 201, GENERAL PERMIT REQUIREMENTS any person subject to this rule shall comply with the following requirements:

501.1 List of Materials: A list shall be maintained of all solvents currently used and/or stored at the site. The list shall include the following information: a. Cleaning material type by name/code/manufacturer. b. The actual VOC content of cleaning material listed in Section 302, as applied including water and exempt compounds. c. The actual mixing ratio for the cleaning material as applied.

501.2 Usage Records: Any person using cleaning materials regulated by this rule shall update and maintain the records as required by this rule as follows:

a. Monthly: 1. Records of total applied volume in gallons for each cleaning

material used. 2. Record of solvent cleaning activity associated with each solvent

used.

501.3 Emissions Control Equipment: Any person using an emission control system pursuant to this rule shall maintain such records on a daily basis, of key system operating parameters for emission control equipment, including, but not limited to: a. Hours of operation; b. Routine and non-routine maintenance; and c. The records required by Section 403 as part of the Operation and

Maintenance Plan. d. Records of test reports conducted pursuant to Section 502.

501.4 Duration of Records: a. Prior to September 25, 2010, records shall be maintained on-site for a continuous three-year period and made available for review by the Air Pollution Control Officer upon request. b. Effective September 25, 2010, records shall be maintained on-site for a continuous five-year period and made av ailable for review by the Air Pollution Control Officer upon request.

502 TEST METHODS

502.1 DETERMINATION OF BOILING POINT: The initial boiling point of solvents shall be
determined in accordance with ASTM D 1078-05.

502.2 DETERMINATION OF CONTROL EFFICIENCY: Control efficiency of control equipment shall be determined in accordance with United States Environmental Protection Agency Method 18, 25, or 25A (whichever is applicable).

502.3 DETERMINATION OF COLLECTION EFFICIENCY: Collection efficiency shall be determined in accordance with the U.S. EPA technical guideline document, “Guidelines for Determining Capture Effi ciency,” dated January 9, 1995. Individual capture efficiency test runs subject to U.S. EPA technical guidelines shall be determined by: a. Applicable U.S. EPA Methods 204, 204A, 204B, 204C, 204D, 204E, and/or 204F; or b. Any other method approved by U.S. EPA, the California Air Resources Board, and the Air Pollution Control Officer.

502.4 DETERMINATION OF VOLUMETRIC FLOWRATE: Volumetric flowrate shall be determined in accordance with United States Environmental Protection Agency Methods 2, 2A, or 2C, or 2D (whichever is applicable).

502.5 DETERMINATION OF VOC CONTENT: VOC content of solvents shall be determined in accordance with United States Environmental Protection Agency

Method 24 and Sections 401 and 502.6 of this rule.

502.6 DETERMINATION OF COMPOUNDS EXEMPT FROM VOC DEFINITION: Compounds exempted from the VOC definition, as in Section 206 of this rule, shall be determined in accordance with ASTM D 4457-02 (2008) or California AirSACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

September 25, 2008 454-11 Resources Board Method 432. If any of the perfluorocarbons or volatile cyclic and linear methyl siloxanes are being claim ed as exempt compounds, the person making the claim must state in advance which compounds are present, and the United States Environmental Protection Agency approved test method used to make the determination of these compounds.

502.7 DETERMINATION OF VOC LEAKS: Vapor VOC leaks shall be determined in accordance with United States Environmental Protection Agency test Method 21.

502.8 MULTIPLE TEST METHODS: When more than one test method or set of test methods is specified for any testing, a vi olation of any requirement of this rule established by any one of the specified test methods or set of test methods shall

constitute a violation of this rule.SACRAMENTO METROPOLITAN AQMD RULES AND REGULATIONS

454-12 September 25, 2008 

### This Page Intentionally Left Blank

### SACRAMENTO METROPOLITAN
AIR QUALITY MANAGEMENT DISTRICT

STAFF REPORT

RULE 450 – GRAPHIC ARTS OPERATIONS

RULE 451 – SURFACE COATING OF MISCEL LANEOUS METAL PARTS AND PRODUCTS

RULE 452 – CAN COATING

RULE 454 – DEGREASING OPERATIONS

RULE 456 – AEROSPACE ASSEMBLY AND COMPONENT COATING OPERATIONS

RULE 463 – WOOD PRODUCTS COATINGS

RULE 464 – ORGANIC CHEMICAL MA NUFACTURING OPERATIONS

RULE 465 – POLYESTER RESIN OPERATIONS

RULE 466 – SOLVENT CLEANING

August 25, 2008

Prepared by: Jimmy Cheng Assistant Air Quality Engineer

Reviewed by: Kevin J. Williams, Ph.D. Program Coordinator

Aleta Kennard Program Supervisor

Approved by: Brigette Tollstrup Division Manager

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 2

BACKGROUND

Ground level ozone is a secondary pollutant formed from photochemical reactions of nitrogen oxides (NOx) and volatile organic compounds (VOCs) in the presence of sunlight. Ozone is a strong irritant that adversely affects human health and damages crops and other environmental resources. As documented by the U.S. Environmental Protection Agency (EPA) in the most recent Criteria Document for ozone (U.S. EPA 2006), both short-term and long-term exposur e to ozone can irritate and damage the human respiratory system, resulting in:

• decreased lung function;

• development and aggravation of asthma;

• increased risk of cardiovascular problems such as heart attacks and strokes;

• increased hospitalizations and emergency room visits; and

• premature deaths.

The District is currently designated as a nonattainment area for both the state and federal ozone standards. Since VOCs are a precursor to ozone, one of the strategies to control ozone pollution is to reduce VOC emi ssions from existing stationary sources.

The primary purpose of this rule project is to amend the solvent cleaning limits and requirements specified in Rule 450, Graphic Arts Operations; Rule 451, Surface Coating of Miscellaneous Metal Parts and Products; Rule 452, Can Coating; Rule 454, Degreasing Operations; Rule 456, Aerospace Assembly and Component Coating Operations; Rule 463, Wood Products Coatings; Rule 464, Organic Chemical Manufacturing Operations; Rule 465, Polyester Resin Operations; and Rule 466, Solvent Cleaning. In the 2003 Triennial Report, the District committed to adopt more stringent solvent cleaning standards to satisfy state plan requirements for “all feasible measures.” These amendments will fulfill that state plan co mmitment, and will also achieve emission reductions that will help the District attain the federal 8-hour ozone standard. These rules were originally adopted to meet f ederal Reasonably Available Control Technology (RACT) requirements, state Best Available Retrofit Control Technology (BARCT) requirements, and to meet 1994 State Implementation Plan requirements.

Solvent cleaning is an essential part of any manufacturing operation or service operation (e.g., automotive repair, graphic arts printing) and is not limited just to application equipment, but also includes manufactured or serviced parts or equipment. The cleaning process generally involves surfac e preparation such as wipe cleaning or degreasing to remove grease and other contaminants prior to assembling. Currently, most of the cleaning is done using cleanup materials containing VOCs or materialscontaining inorganic or exempt compounds (e.g., halogenated solvents, and nonhalogenated solvents.) Some of the halogenated solvents have been regulated by EPA under 40 CFR Part 463, Subpart T – National Emission Standards for Halogenated Solvent Cleaning.

Staff is also proposing to amend Rules 450 and 451 to conform to recent ControlTechnique Guideline documents (CTGs) promulgated by EPA. The two graphic artsrelated CTGs, dated September 2006, address emissions from offset lithographic and letterpress printing and flexible package printing. The September 2007 CTG for metal

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 3

furniture coatings address emissions from such coating operations.

BACKGROUND FOR EACH RULE

The proposed changes will lower the VOC content limits for cleaning solvents to feasible limits that have been implemented in the South Coast Air Quality Management District (SCAQMD). Additionally, the proposed change s will lower the VOC limits for fountain solutions and include control device requirements specified in the 2006 CTGs for graphic arts operations, and lower the VOC limits and increase the emissions control equipment efficiency requirement for metal furniture coatings to be consistent with the 2007 CTG for metal furniture coatings.

Rule 450- Graphic Arts Operations

Adopted on July 23, 1981 and last amended on March 23, 2000, Rule 450 regulates VOC emissions from graphic arts operations , which include cleaning activities for gravure, screen printing, flexographic, lithographic, and various other coating and laminating operations. This rule is being proposed for amendment in order to require that general cleaning and application equipment cleaning operations use cleanup materials with lower VOC content than previously allowed. The proposed amendments

will:

• Lower the solvent VOC limits for several cleaning categories to as low as 25 grams per liter (g/l); and

• Eliminate the current VOC composite vapor pressure limits and all references to vapor pressure limits.

• For sources that emit more than 450 pounds of VOC per month, lower the VOC

limits for fountain solutions.

• For sources that emit 25 tons of VOC or more per year, require control equipment for lithographic, letterpress, and flexible package printing operations,

in conformance with the 2006 CTGs.

Rule 451- Surface Coating of Miscellaneous Metal Parts and Products

Rule 451 was adopted on June 19, 1979 and was last amended on October 2, 1997. This rule applies to coating, coating removal (stripping), surface preparation, and cleanup operations for miscellaneous metal parts and products. The proposed amendment will lower the VOC limit for surface preparation and cleanup materials to 25 g/l, lower the VOC limits for metal furniture coatings to as low as 275 g/l, and increase the emissions control equipment efficiency requirement to 90%.

Rule 452- Can Coating

Rule 452 was adopted on June 19, 1979 and last amended on September 5, 1996. Can coating operations include surface preparation and cleanup. The proposed

amendments will:

• Lower the VOC limit for cleaning to 25 g/l.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 4

• Reduce the VOC content limits for two piece and three piece interior body sprays and end sealing compounds.

• Specify acceptable application methods.

• Increase emissions control equipment efficiency requirement to 90%.

Rule 454- Degreasing Operations

Adopted on June 5, 1979 and last amended on May 23, 2002, Rule 454 regulates VOC emissions from solvent degreasing operations. As defined in this rule, degreasing operations include vapor and non-vapor (cold) degreasing. This rule is being proposed for amendment in order to require that all degreasing operations use solvents that contain no more than 25 g/l of VOCs. This rule currently allows the use of airtight/airless cleaning system or emissions control equipment as alternatives to complying with the VOC limit. Staff proposes to retain the option to use an airtight/airless cleaning system. Staff also proposes to add an exemption for the degreasing of high-voltage microwave

vacuum tubes.

Rule 456- Aerospace Assembly and Component Coating Operations

Rule 456 was adopted on February 23, 1993 and was last amended on July 23, 1998. This rule limits VOC emissions from aerospace assembly and coating operations, which include coating removal (stripping), surface preparation and cleaning, and application equipment cleanup material. The proposed amendments to this rule will lower the solvent VOC limit for cleaning application equipment to 25 g/l.

Rule 463- Wood Products Coatings

Rule 463 was adopted on September 5, 1996 and was last amended on July 23, 1998. This rule regulates VOC emissions from wood coating operations, including strippers used on wood products and surface preparation and cleanup materials. The proposed amendments will reduce the VOC limit for surface preparation and cleanup materials to 25 g/l and will lower the low usage exemption to 55 gallons per year. Additionally, Staff proposes to restrict the use of the emissions averaging provisions to a maximum of 20 gallons per year of historical reproduction coatings.

Rule 464- Organic Chemical Manufacturing Operations

Rule 464 was adopted on July 23, 1998 and has never been amended. This rule limits VOC emissions from organic chemical plants. Cleanup activities, which include maintenance solvent cleaning and in-line solvent cleaning of process units and piping, are regulated under this rule.

The solvent cleaning requirements for Rule 464 are found under the cleanup and storage requirements section. The proposed amendments will reduce the VOC limit for maintenance cleaning solvent to 25 g/l.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 5

Rule 465- Polyester Resin Operations

Rule 465 was adopted on February 6, 1997 and was last amended on June 4, 1998. The rule regulates emissions from polyester resin operations. Polyester resin operations include but are not limited to bathtub, shower, and sink manufacturers, spa and boat manufacturers, and tomato bin manufacturers, and include cleaning materials. The proposed amendments will reduce the VOC limit for cleaning materials to 25 g/l. Additionally, Staff proposes to increase the emissions control equipment efficiency requirement to 90%.

Rule 466- Solvent Cleaning

Prior to the adoption of Rule 466 on May 23, 2002, there were still cleaning activities such as the cleaning of electrical and electronic components, medical devices and pharmaceuticals, and architectural coating application equipment, that were not regulated by the industry-specific solvent cleaning rules (Rules 450, 451, etc.). Rule 466 was implemented to capture these solvent clea ning activities. This rule has not been amended since adoption. The proposed amendments will:

• Lower the solvent VOC limits for several cleaning categories to as low as 25 g/l,

and

• Add a new VOC standard of 200 grams per liter for the sterilization of food product manufacturing and processing equipment.

• Add an exemption for the cleaning of high-voltage microwave vacuum tubes.

LEGAL MANDATES

Attainment Demonstration Plan: The District is designated as a nonattainment area for the federal 8-hour ozone standard (69 FR 23858, April 30, 2004). U.S. EPA’s Phase 2 Rule (70 FR 71611, Nov. 29, 2005) to implement the 8-hour ozone standard requires the District to submit an attainment demonstration plan into the state implementation plan.

The proposed amendments will achieve reducti ons in VOC emissions that will be necessary to help the Sacramento area attain the federal 8-hour ozone standard. These rules will be included in the attainment demonstration plan.

Reasonably Available Control Technology (RACT); Clean Air Act (CAA) section 172 (c)(1) specifies that state implementation plans (SIPs) for nonattainment areas must include “reasonably available control measures” (RACM), including “reasonably available control technology” (RACT), for sources of emissions. Section 182 (b)(2) specifically provides that for nonattainment areas classified as “moderate” or worse, states must revise their SIPs to include RACT for sources of VOC emissions covered by a CTG document issued after November 15, 1990 and prior to the area’s date of

attainment. EPA defines RACT as “the lowe st emission limitation that a particular source is capable of meeting by the application of control technology that is reasonably available considering technological and economic feasibility.” 44 FR 53761 (Sept. 17,

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 6

1979). In developing CTGs, EPA evaluates, among other things, the sources of VOC emissions and the available control appr oaches for addressing these emissions, including the costs of such approaches. Based on available information and data, EPA provides the recommendations for RACT.

The details of the 2006 CTGs pertaining to graphic arts operations and the 2007 CTG for metal furniture coatings are summarized below.

CTG for Offset Lithographic Printing and Letterpress Printing (EPA-453/R-06-002)

Applicability This CTG, promulgated by EPA in September 2006, provides control recommendations for reducing VOC emissions stemming from the use of fountain solutions, cleaning materials, and inks in offset lithographic printing and cleaning materials and inks in letterpress printing. The requirements for fountain solutions do not apply to offset lithographic printing operations with less than or equal to 15 pounds per day of actual VOC emissions. The requirements for control equipment do not apply to presses with potential to emit less than 25 tons of VOC per year, prior to controls.

Recommended Control Options The CTG specifies three methods to reduce VOC emissions from offset lithographic printing and letterpress printing. These options are add-on controls; process modifications or work practices; and material reformulation or substitution. Specific CTG requirements are detailed below.

A. Heatset web offset lithographic and heatset letterpress inks and dryers add-on control requirements:

• The recommended level of control for VOC emi ssions from heatset dryers is 90 percent control efficiency for a control device whose first installation date was prior to the effective date of a State RACT rule, which was issued after the date of this CTG.

• The recommended level of control for VOC emi ssions from heatset dryers is 95 percent control efficiency for a control device whose first installation date was on or after the effective date of the State RACT rule, which was issued after the date of this CTG.

• To accommodate situations where the inlet VOC concentration is so low that a 90 or 95 percent efficiency may not be achievable, it is recommended that an alternative requirement be specified for the control device outlet concentration to be no more than 20 ppmv as hexane on a dry basis.

B. Fountain Solution VOC content limits: • Heatset Web Offset Lithographic Printing: 1.6% alcohol by weight (or 3% if chilled) • Sheet-fed Offset Lithographic Printing: 5% alcohol by weight (or 8.5% if chilled) • Coldset Web Offset Lithographic Printing: 5% percent alcohol substitute by weight and

no alcohol in the fountain solution

C. Cleaning materials VOC limits: The following recommendations apply to blanket washing, roller washing, plate cleaners, metering roller cleaners, impression cylinder cleaners, rubber rejuvenators, and other cleaners used for cleaning a press, press parts, or to remove dried ink from areas

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 7

around a press. • Use cleaning materials with a VOC composite vapor pressure less than 10mm Hg at 20 degrees C or cleaning materials containing less than 70 weight % VOC.

D. Work Practices • Keep cleaning materials and used shop towels in closed containers.

CTG for Offset Flexible Package Printing (EPA-453/R-06-003)

Applicability This CTG, promulgated by EPA in September 2006, provides control recommendations for reducing VOC emissions from inks, coatings, adhesives and cleaning materials used in flexible package printing. The requirements for control equipment do not apply to presses with potential to emit less than 25 tons of VOC per year, prior to controls.

Recommended Control Options The two options for reducing VOC emissions from inks, coatings, and adhesives used in the flexible package printing industry are adding/improving add-on controls, and material

reformulation or substitution.

Recommendations for controlling VOC emissions from inks, coatings, adhesives and cleaning materials used in flexible package printing operations are as follows:

A. Coatings, inks and adhesives used on flexible packaging printing presses The recommended control levels in the final CTG include the following: • 65% overall control for a press that was first installed prior to March 14, 1995 and that is controlled by an add-on air pollution control device whose first installation date was prior to the effective date of the State RACT rule. • 70% overall control for a press that was first installed prior to March 14, 1995 and that is controlled by an add-on air pollution contro l device whose first installation date was on

or after the effective date of the State RACT rule. • 75% overall control for a press that was first installed on or after March 14, 1995 and that is controlled by an add-on air pollution co ntrol device whose first installation date was prior to the effective date of the State RACT rule. • 80% overall control for a press that was first installed on or after March 14, 1995 and that is controlled by an add-on air pollution co ntrol device whose first installation date

was on or after the effective date of the State RACT rule.

B. Cleaning Materials Work Practices at Flexible Package Printing Presses Keep cleaning materials and used shop towels in closed containers, and conveying cleaning materials from one location to another in closed containers or pipes.

The proposed amendments will meet RACT r equirements and achieve reductions in VOC emissions that will be necessary to hel p the Sacramento area attain the federal 8- hour ozone standard. These rules will be included in the attainment demonstration plan.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 8

CTG for Metal Furniture Coatings (EPA-453/R-07-005)

Applicability This CTG, promulgated by EPA in September 2007, provides control recommendations for reducing VOC emissions stemming from the use of surface coatings on metal furniture. The requirements for metal furniture do not apply to each metal furniture surface coating unit at a facility where the total actual VOC emissions from all such operations, including related cleaning activities, are less than 15 pounds per day (equivalent to 3 tons per 12-month rolling period) before consideration of controls.

Recommended Control Options The CTG specifies three methods to reduce VOC emissions from metal furniture coatings. These options are lower VOC limits, add-on controls, work practices, or application methods. Various exemptions are also recommended. Specific CTG requirements are detailed below.

A. Metal furniture coatings VOC content limits:

VOC CONTENT: Grams/Liter (Lbs/Gal) excluding water and exempt compounds

COATING TYPE AIR DRIED BAKED General, One-Component 275 (2.3) 275 (2.3) General, Multi-Component 340 (2.8) 275 (2.3) Extreme High Gloss 340 (2.8) 360 (3.0) Extreme Performance 420 (3.5) 360 (3.0) Heat Resistant 420 (3.5) 360 (3.0) Metallic 420 (3.5) 420 (3.5) Pretreatment Coatings 420 (3.5) 420 (3.5) Solar Absorbent 420 (3.5) 360 (3.0)



### B. Add-on control requirements: The CTG recommends an overall control efficiency of 90% for metal furniture coating operations.

C. Work Practices • store all VOC-containing materials and used shop towels in closed containers • ensure that mixing and storage containers used for VOC-containing materials are kept closed at all times except when depositing or removing these materials • minimize spills of VOC-containing materials • convey VOC-containing materials from one location to another in closed containers or pipes • minimize VOC emission from cleaning of storage, mixing, and conveying equipment

D. Application Methods The following application methods are recommended:

• Electrostatic application

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 9

• HVLP spray

• Flow coat

• Roller coat

• Dip coat, including electrodeposition

• Other coating application methods capable of achieving a transfer efficiency equivalent or better than that achieved by HVLP spraying

Recommended exemptions The CTG recommends the following types of coatings and coating operations be exempt

from our recommended VOC content limits:

• Stencil coatings

• Safety-indicating coatings

• Solid-film lubricants

• Electric-insulating and thermal-conducting coatings

• Touch-up and repair coatings

• Coating application utilizing hand-held aerosol cans

State Mandates:

Serious Nonattainment Plan Requirements : The District is designated as a serious nonattainment area for the state ozone standard. The California Clean Air Act requires areas with this designation to adopt control measures required in sections 40913, 40914,

and 40919 of the California HSC:

• HSC Section 40913 requires districts to develop a plan to achieve California’s ambient air quality standards by the earliest practicable date.

• HSC Section 40914(b)(2) requires every nonattainment district which cannot achieve a reduction of 5% or more per year in district wide emissions to include in their state attainment plans “every feasible measure” to reduce the emissions of nonattainment pollutants and their precursors. SCAQMD Rule 1171, which regulates emissions from solvent cleaning, qualifies as a “feasible measure.” The District’s 2003 Triennial Plan update included a commitment to achieve VOC emission reductions of 0.37 tons per day by implementing more stringent, feasible controls on solvent cleaning. The proposed amendments will achieve VOC emission reductions of 0.54 tons per day and will satisfy the state plan

commitment.

• HSC Section 40919(a)(3) requires districts with serious nonattainment for ozone to adopt BARCT for all existing permitted sources. Staff has found that the proposed amendments will meet the BARCT requirement.

Transport Mitigation Emission Control Requirements : Title 17, Section 70600 of the California Code of Regulations requires that districts within the areas of origin of transported air pollutants, as identified in section 70500(c), include sufficient emission control measures (including “all feasible measures” and BARCT) in their attainment plans for ozone to mitigate the impact of pollution sources within their jurisdictions on

ozone concentrations in downwind areas commensurate with the level of contribution. An upwind district shall comply with the transport mitigation planning and implementation requirements set forth in this section regar dless of its attainment status, unless the

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 10

upwind district complies with the requirements of section 70601.

The proposed amendments are based on all feasible control measures and BARCT requirements, and therefore comply with the state mandates.

SUMMARY OF REQUIREMENTS

The proposed rules will set more stringent VOC content limits, and in some cases eliminate vapor pressure limits. Several VOC limits in SCAQMD Rule 1171 for graphic arts-related cleaning categories have not yet been implemented. Staff considered these VOC limits with future effective dates in the proposed rules, as discussed below in the summary for Rule 450.

The requirements for each proposed rule are as follows.

Rule 450

Rule 450 includes cleaning and storage requirements for graphic arts operations. Solvent cleaning in a graphic arts operation falls under two categories: general cleaning (which includes maintenance, repair, and wipe cleaning) and application equipment cleaning (which includes such activities as cleaning for lithographic and letter press printing and screen printing). The rule currently allows compliance by meeting a VOC composite vapor pressure limit in lieu of achi eving the VOC content lim it. Alternatively, air pollution control equipment may be used if neither limit can be attained.

The VOC limits for lithographic printing (other than newsprint substrates), screen printing, and UV/electron beam ink equipm ent cleaning in SCAQMD Rule 1171 recently became effective, on January 1, 2008. SCAQ MD technology assessments completed in August 2006 provide evidence to support the im plementation of these VOC limits. The San Joaquin Valley Unified Air Pollution Control District (SJVUAPCD) also used these limits, effective January 1, 2010, when they amended their graphic arts rule (Rule 4607) on September 20, 2007. Therefore, Staff proposes to lower the VOC limits in Rule 450 for the above cleaning categories to the January 1, 2008 limits in SCAQMD Rule 1171, but with a future effective date of January 1, 2011.

Staff proposes to add exemptions for two cleaning categories: cleaning of metering rollers and printing plates (for newsprint as well as other substrates) and stripping of cured inks, cured coatings, and cured adhesives. In the proposed exemption for metering rollers and printing plates, specific presses are not subject to the monthly usage limit for materials used to clean metering rollers and printing plates specified in Section 302.2, provided that they comply with the eventual VOC limit of 100 g/l (effective 1/1/2011) for these components. The proposed exemption for the stripping of cured materials is for clarification purposes only, since the current definition of solvent cleaning already implies that stripping of such cured materials is exempt.

Currently, Rule 450 allows cleaning solvents to comply with vapor pressure limits instead of VOC content limits. Staff is proposing to remove the solvent vapor pressure limits

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 11

from Rule 450. This change is consistent with SCAQMD Rule 1171, which contains solvent VOC limits that are less than or equal to the current Rule 450 VOC limits and does not allow the use of low vapor pressure solvents in lieu of meeting the VOC content limits. Staff considers the SCAQMD VOC content limits to constitute a more stringent feasible measure than the current Rule 450 VOC content/vapor pressure limits.

Adoption of the SCAQMD limits will result in greater and more quantifiable reductions from solvent cleaning in graphic arts operations . While low vapor pressure solvents may evaporate at a slower rate, all of the solvent eventually evaporates. Setting a lower VOC limit will reduce further what is eventually emitted to the air than setting a low vapor pressure limit. EPA’s CTG for Offset Lithographic Printing and Letterpress Printing (2006) states that the use of low vapor pressure cleaning materials (vapor pressure less than 10 mm Hg at 20 °C) results in an emission reduction comparable to using materials with 30% VOC by weight (approximately 240 g/l of VOC), considerably higher than the proposed VOC limits in Rule 450.

Staff proposes to reduce the allowable VOC content of fountain solutions to those specified in the 2006 CTG for Offset Lithographic Printing and Letterpress Printing (see table following #8). In order to incorporate the CTG requirements, it is necessary to establish separate categories for heatset web, coldset web, sheet fed, and all other lithographic presses.

The new requirements for emissions control equipment also address the 2006 CTG recommendations. Effective one year after the date of adoption, the minimum overall control system efficiency of 67% will be increased to various levels, depending upon the specific process involved and the date on which the press and emissions control equipment were first installed. Unless exempted in Section 110 as described below, sources must use emissions control equipment, and the equipment must achieve at least an overall efficiency of one of the following, whichever is applicable:

Heatset Web Offset Lithographic Printing and Heatset Web Letterpress Printing:

• 90% overall efficiency if permit application is deemed complete prior to (date of adoption)

• 95% overall efficiency if permit application is deemed complete after (date of adoption).

Flexible Package Printing Inks, Coatings, and Adhesives:

• 70% overall efficiency for a press that was first installed prior to March 14, 1995.

• 80% overall efficiency for a press that was first installed on or after March 14, 1995.

To be consistent with the 2006 CTG recommendations, a new section was also added to provide an alternative to compliance with the overall system efficiency requirements for heatset web offset lithographic and heatset web letterpress printing. In lieu of complying with those overall efficiency requirements, sources are required to use emissions control equipment with mass outlet concentration no greater than 20 ppmv as hexane on a dry basis. For all other printing operations in cluding exempted operations, the emissions control equipment (with a required 67% efficiency, consistent with the current requirement) is optional if the a ssociated VOC limits are achieved.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 12

The new exemptions in Section 110 of the proposed rule are also based on the 2006

CTG recommendations. Fountain solutions are ex empt from the revised VOC limits if the offset lithographic operations do not exceed 15 pounds of VOC per day (in which case the current VOC limits for fountain solutions will remain in effect). A heatset web offset lithographic press is exempt from th e control equipment requirements if 1) the potential to emit from the dryer is less than 25 tons of VOC per year, or 2) the press is used for book printing, or 3) if the press has a maximum web width of 22 inches or less. Inks, coatings, and adhesives used for flexible package printing are exempt from the control equipment requirements if the potential to emit from the dryer is less than 25 tons of VOC per year. Section 110 also clarifies that if actual emissions from control equipment are at least 25 tons per year of VOC per rolling 12-month period, then that unit must comply with Section 303.1 and cannot use the exemptions in this section. This is a “once in, always in” requirement.

The proposed amendments for this rule are listed below. For a detailed list of all changes to Rule 450, please refer to Appendix B.

1. Lower the solvent VOC limits for several cleaning categories (see below).

Proposed Limits Current Limits (The specified limits remain in effect until limits are replaced by limits listed in subsequent columns.) Effective (one year

after date of

adoption) Effective
1/1/2011 Material Type

VOC Content g/l (lb/gal) Including Water

and Exempt Compounds VOC Composite

Partial

Pressure

Millimeters of Mercury at 20

o C (68 o F) VOC

Content g/l (lb/gal) Including

Water and

Exempt Compounds VOC

Content g/l (lb/gal) Including

Water and

Exempt Compounds

General (e.g., main tenance, repair, solvent, wipe) Cleaning 72 (0.60) 25 (0.21)

Application Equipment Cleaning

General (not specifically listed below)

Lithographic and Letter Press Printing

Newsprint substrates

Blanket and Roller Washes Metering Rollers/Printing Plates Other On-Press Components Removable Press Components

Substrates other than newsprint

Blanket and Roller Washes Metering Rollers/Printing Plates Other On-Press Components Removable Press Components

Screen Printing 100 (0.83)

300 (2.5) 300 (2.5) 100 (0.83) 100 (0.83)

300 (2.5) 300 (2.5) 100 (0.83) 100 (0.83)

300 (2.5) AND

OR

OR

AND

AND

OR

OR

AND

AND

OR 3

10

25

3

3

10

25

3

3

10 25 (0.21)

100 (0.83) 100 (0.83) 100 (0.83) 25 (0.21)

25 (0.21) 100 (0.83) 100 (0.83) 100 (0.83)

100 (0.83)

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 13

Proposed Limits Current Limits (The specified limits remain in effect until limits are replaced by limits listed in subsequent columns.) Effective (one year

after date of

adoption) Effective
1/1/2011 Material Type

VOC Content g/l (lb/gal) Including Water

and Exempt Compounds VOC Composite

Partial

Pressure

Millimeters of Mercury at 20

o C (68 o F) VOC
Content g/l (lb/gal) Including

Water and

Exempt Compounds VOC
Content g/l (lb/gal) Including

Water and

Exempt Compounds

Flexographic Printing

Specialty Flexographic Printing

Ultraviolet/Electron Beam Inks (Except Screen Printing) 100 (0.83)

810 (6.8)

800 (6.7) AND

AND

AND 3

21

33 25 (0.21)

100 (0.83)

650 (5.4) 100 (0.83)



### 2. Add a new VOC limit of 100 g/l specifically for blanket and roller washes used on newsprint equipment (shown in the table above). 3. Add a new VOC limit of 25 g/l specifica lly for removable press components (shown in the table above). 4. Add definitions of “potential to emit,” “electron beam ink,” “newsprint,” “other on-press component”, “removable press component,” “stripping,” and “cured coating, cured ink, or cured adhesive,” using the same definitions as the ones in the SCAQMD

rules. 5. Replace the term “other cleaning” with “metering rollers/printing plates,” consistent with previous definition. 6. Add a new VOC limit of 100 g/l specifically for metering rollers and printing plates used in newsprint operations (shown in the table above). 7. Eliminate the current VOC composite vapor pressure limits. 8. Add new categories for fountain solutions and lower the VOC limits, as shown in the following table.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 14

VOC Content Limits

Including water and exempt compounds MATERIAL TYPE

Current Limits (g/l)

(The specified

limits remain in

effect until limits are replaced by

limits listed in the subsequent column.) Effective (One Year

After Date

Of Adoption)
(% by weight)

Heatset Web Offset Lithography Fountain Solutions Containing Alcohol 1. Chilled Using Refrigerated Chiller

2. Non-Chilled Fountain Solutions Containing No Alcohol 1. Chilled Using Refrigerated Chiller

2. Non-Chilled

Coldset Web Offset Lithography Fountain Solutions Containing Alcohol 1. Chilled Using Refrigerated Chiller

2. Non-Chilled Fountain Solutions Containing No Alcohol 1. Chilled Using Refrigerated Chiller

2. Non-Chilled

Sheet-fed Offset Lithography with maximum sheet size greater than 11 X 17 inches or total solution reservoir greater than 1 gallon Fountain Solutions Containing Alcohol 1. Chilled Using Refrigerated Chiller

2. Non-Chilled Fountain Solutions Containing No Alcohol 1. Chilled Using Refrigerated Chiller

2. Non-Chilled

All Other Presses (includes offset lithographic presses exempt pursuant to Section 110.9) 1. Chilled Using Refrigerated Chiller

2. Non-Chilled 100

80

100

80

100

80

100

80

100

80

100

80

100

80 3

1.6

5

5

(*See below) (*See below)

5

5

8.5

5

5

5

10

8



### * Effective one year after date of adoption, fountain so lutions containing alcohol shall not be used in coldset web offset lithography printing operations.



### 9. Add a requirement for mandatory emissions control equipment for heatset web offset lithographic printing, heatset web letterpress printing, and flexible package printing inks, coatings, and adhesives. Increase the required overall control efficiency to the following levels:

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 15

Overall Control Efficiency Process Description Current Proposed Heatset Web Offset Lithographic Printing and Heatset Web Letterpress Printing Permit application complete prior to date of adoption 67% 90%

Permit application complete after date of adoption 67% 95%

Flexible Package Printing Inks, Coatings,

and Adhesives Press was first installed prior to 3/14/95 67% 70%

Press was first installed on or after 3/14/95 67% 80%

10. Add exemptions (as described above) for VOC content of fountain solutions and for control equipment for heatset web offset lithographic printing, heatset web letterpress printing, and flexible package printing inks, coatings, and adhesives. 11. Update the recordkeeping section to include new usage record requirements for materials used for printing on newsprint. 12. Add calculation method for determining overall emissions control equipment system efficiency. 13. Update the test methods to specify the most current test methods.

Rule 451

Rule 451 limits VOC emissions from the app lication of coating, coating removers (strippers), surface preparation material, and cleanup material to miscellaneous metal parts and products in a shop environment. Similar to Rule 450, Rule 451 also provides the option of using an emission control system in lieu of complying with the specified

VOC emissions limits.

Currently, Sections 110.2 and 110.3 of Rule 451 provide low-usage exemptions for aluminum coatings applied to window frames and door frames, as well as for pretreatment wash primers, that exceed the VOC limits in the rule, provided that the usage of such materials is less than 200 gallons per calendar year. Section 401 requires facilities utilizing the low-usage exemptions to submit annual reports showing the usage of these materials. Staff reviewed the recent annual reports and found that no facility used such materials in an amount greater than 55 gallons per calendar year. Therefore, Staff is proposing to eliminate the low-usage exemptions in Sections 110.2 and 110.3. The usage of these materials will be subject to the general low-usage exemption of 55 gallons per calendar year as specified in Section 110.1. The 55 gallon/year exemption level is consistent with the EPA Region IX “Little Bluebook” ( Guidance Document for Correcting Common VOC & Other Rule Deficiencies , April 1, 1991, revised August 21, 2001).

Staff also proposes to revise the current rule language such that electrostatic spray guns are subject to the proposed VOC requirement for cleanup of metal parts/products coating application equipment. This proposal is consistent with the June 30, 2005

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 16

sunset of an exemption for electrostatic coating application equipment cleaning in SCAQMD Rule 1171. Also, the use of enclosed gun cleaners will no longer remain as a compliance option for the application equipment cleanup requirements under the proposed rule, consistent with SCAQMD Rule 1171.

In the current rule, Section 304.4 allows spray gun nozzles to be soaked in solventbased materials in a tightly covered container not exceeding 5 gallons in size. Staff proposes to eliminate this section to be consistent with SCAQMD Rule 1171, which currently does not contain such a provision.

Staff proposes to reduce the allowable VOC content of metal furniture coatings (which is defined in the proposed rule) to those specified in the 2007 CTG for Metal Furniture Coatings (see table following #2). Under the current rule, metal furniture coating operations are subject to the coating VOC limits specified in Section 301. The proposed rule establishes separate VOC limits for metal furniture coating operations at sources emitting at least 3 tons of VOC emissions per 12-month rolling period prior to controls. As stated in the new exemption for metal furniture coatings, sources that emit less than 3 tons per 12-month rolling period prior to controls are not subject to the metal furniture coatings requirements, but are subject to the requirements for miscellaneous metal parts and products coatings in Section 301 In order to incorporate the CTG requirements, it is necessary to establish two new coating categories (which are subject to the “all other coatings” category under the current rule), for general multi-component coatings and all other coatings.

The new requirement for emissions control equipment also addresses the 2007 CTG recommendations. Effective on the rule adoption date, the minimum overall control system efficiency of 85% will be increased to 90%.

The proposed rule also includes the following amendments:

1. Lower both of the solvent VOC limits in the surface preparation/cleanup/storage requirements from 72 g/l to 25 g/l. 2. Lower the VOC limits for metal furniture coatings at large sources (3 tons of VOC or more per 12-month rolling period) as shown in the following table, and add an exemption from this section for sources with emissions of less than 3 tons per 12- month rolling period.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 17

VOC CONTENT: Grams/Liter (Lbs/Gal) less water and exempt compounds CURRENT LIMITS EFFECTIVE (ONE YEAR AFTER DATE OF ADOPTION)

COATING
CATEGORY AIR DRIED BAKED AIR DRIED BAKED

General, MultiComponent 340 (2.8) 275 (2.3) 340 (2.8) 275 (2.3)

Extreme High

Gloss 420 (3.5) 360 (3.0) 340 (2.8) 360 (3.0)

Extreme

Performance 420 (3.5) 420 (3.5) 420 (3.5) 360 (3.0)

Heat Resistant 420 (3.5) 360 (3.0) 420 (3.5) 360 (3.0) Metallic/Iridescent 420 (3.5) 420 (3.5) 420 (3.5) 420 (3.5)

Pretreatment

Wash Primer 420 (3.5) 420 (3.5) 420 (3.5) 420 (3.5)

Solar Absorbent 420 (3.5) 360 (3.0) 420 (3.5) 360 (3.0)

All Other Coatings 340 (2.8) 275 (2.3) 275 (2.3) 275 (2.3)



### 3. Add definitions for “electrostatic spray,” “metal furniture,” and “multi-component coating.”

4. Increase the overall emissions contro l equipment efficiency from 85% to 90%. 5. Add an exemption for metal furniture coatings. 6. Add additional work practice requirements for disposal of cloth, paper, or sponges used for coating application; minimizing spillage of VOC-containing materials; and conveyance of VOC-containing materials using closed containers or pipes, to be consistent with the 2007 CTG for Metal Furniture Coatings and the 2008 Draft CTG for Miscellaneous Metal and Plastic Parts Coatings (dated July 3, 2008). 7. Revise the duration of records requirement from three to five years to be consistent with other District rules, and 8. Update the test methods to specify the most current test methods.

Rule 452

Rule 452 limits VOC emissions from can coating operations, which include coatings applied or intended for application onto the surfaces of metal cans or metal sheets, strips, rolls, and coils intended for can construction. The option of using of an emission control system instead of meeting the specifi ed VOC emissions limits is available in this rule. The following amendments are proposed:

1. Add applicability and severability sections to the rule. 2. Lower the solvent VOC limits for cleanup of container assembly equipment from 200 g/l to 25 g/l. 3. Lower the VOC limits for three piece can interior body spray and two piece can interior body spray to be consistent with the more stringent, feasible limits in BAAQMD Rule 8-11, SJVAPCD Rule 4604. 4. Separate the end sealing compound category into “end sealing compound for food/beverage cans” and “end sealing compound for non-food containers,” and

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 18

establish VOC limits that are lower than the current VOC limit for end sealing compound. The proposed VOC limits for the two subcategories are consistent with the more stringent, feasible limits in SCAQMD Rule 1125. 5. Add a definition of “dip coat,” “electrostatic spray,” “flow coat,” “food/beverage can,” ”“hand application equipment,” “high-volume low-pressure application equipment,” “low-volume low-pressure application equipment,” and “roll coater.” 6. Add section for application equipment requirements, consistent with the requirements in the other current District coating rules, with an additional option to use emissions control equipment that achi eves an overall system efficiency of at least 85.5%. This requirement is consistent with current permit conditions and

ensures that the emissions control equipment achieves an emission reduction equivalent to the use of HVLP. 7. Add equations for calculation of overall sy stem efficiency, of VOC content of cleanup material, and of percent control efficiency and VOC mass emission rate. 8. Increase the required emissions control equipment efficiency from 85.5% to 90%, except when emissions control equipment is used as an application method as given under the application equipment requirements in new Section 304. 9. Revise the duration of records requirement from two to five years to be consistent with other District rules, and 10. Update the test methods to specify the most current test methods.

Rule 454

Vapor and non-vapor degreasing operations are regulated under Rule 454. The proposed rule implements more stringent VOC limits for both types of degreasers. However, sources are still allowed to use an airtight/airless cleaning system in lieu of complying with the limits on VOC content.

Section 110.5 in the current rule exempt s solvent degreasing operations using exempt compounds mixed with VOCs not exceeding 5% in weight. Staff proposes to eliminate this exemption because it duplicates the exemption in Section 110.3, which is being proposed to sunset one year after the adoption date of these amendments. Under the proposed amendments, all degreasers using solv ents containing 25 g/l or less of VOCs will be exempt from the rule.

Staff is proposing to add an exemption for degreasing high-voltage microwave vacuum tubes, at the request of a facility within the District that manufactures these devices. Staff has reviewed detailed technical information submitted by this facility and concurs that the use of low-VOC solvents is technically infeasible for this application. The facility conducted testing of various low-VOC solvents and blends over the past three years and has been unable to find a suitable alternative to using 100% isopropyl alcohol for the cleaning of components during the manufacture and repair of high-voltage microwave vacuum tubes. The high-vacuum, high-voltage operation of the devices requires an ultra-low level of contamination by organic residues and moisture. Alternative low-VOC solvents were demonstrated to result in unacceptably high failure rates of these devices, which are the principal components of electronic radar-jamming devices. Some of these devices are used in aerospace applications, which are exempt under Rule 456. Staff researched the location of competitors for this source and identified SCAQMD and

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 19

BAAQMD. Staff reviewed the rules for these districts and contacted SCAQMD staff to discuss the compliance status of these facilities. It was determined that the cleaning of these devices with high VOC solvents is allowed under the existing rules for aerospace assembly operations.

The additional proposed changes to Rule 454 are presented below.

1. Lower the solvent VOC limits for non-vapor degreasing operations from 50 g/l to 25 g/l. 2. Add a new VOC limit of 25 g/l for vapor degreasing operations. 3. Add a definition of “water separator.” 4. Add an exemption for degreasing of high-voltage microwave vacuum tubes. 5. Revise the duration of records requirement from three to five years to be consistent with other District rules, and 6. Update the test methods to specify the most current test methods.

Rule 456

The proposed changes to this rule, which limit s solvent VOC emissions from aerospace assembly and coating operations, primarily in volve the implementation of more stringent VOC limits. The use of an emission control system will remain as an alternative to compliance with the specified VOC standards. However, the proposed rule will remove the option of using an enclosed gun cleaner in lieu of complying with the specified VOC limit for the cleaning of spray guns. This proposed change is consistent with the SCAQMD solvent cleaning rules, which currently do not allow the use of enclosed gun cleaners as a compliance method.

Currently, Section 110 of Rule 456 provides a low-usage exemption for materials such as coatings, adhesives, maskants, and strippers that exceed the VOC limits in the rule, provided that the usage of such materials is less than 200 gallons per calendar year. Staff is proposing to lower the exemption level to 55 gallons per calendar year. The 55 gallon/year exemption level is consistent with the EPA Region IX “Little Bluebook” ( Guidance Document for Correcting Common VOC & Other Rule Deficiencies , April 1, 1991, revised August 21, 2001). Section 401 requires facilities utilizing the low-usage exemption to submit annual reports showing the usage of these materials. Staff reviewed the recent annual reports and found that no facility used such materials in an amount greater than 55 gallons per calendar year.

Staff also proposes to revise the current rule language such that electrostatic spray guns are subject to the proposed VOC requirement for the cleaning of spray guns. This inclusion of electrostatic spray guns follows from the June 30, 2005 sunset of an exemption for electrostatic coating application equipment cleaning in SCAQMD Rule

1171.

In the current rule, Section 304.4 allows spray gun nozzles to be soaked in solventbased materials in a tightly covered container not exceeding 5 gallons in size. Staff proposes to eliminate this section to be consistent with SCAQMD Rule 1171, which currently does not contain such a provision.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 20

The following changes are also proposed:

1. Lower the solvent VOC limits for the cleaning of spray guns used in coating operations from 200 g/l to 25 g/l. 2. Add a sunset date for the option of using an enclosed gun cleaner in lieu of complying with the 25 g/l VOC limit for the cleaning of spray guns used in coating operations. 3. Revise the low usage exemption to lower usage limit from 200 gallons to 55 gallons to be consistent with other District rules and with EPA Region IX “Little Bluebook.” 4. Add a definition of “electrostatic spray.” 5. Revise the duration of records requirement from three to five years to be consistent with other District rules, and 6. Update the test methods to specify the most current test methods.

Rule 463

Rule 463 regulates VOC emissions from coatings, strippers, and surface preparation and cleanup materials used in wood products coating operations. The proposed rule lowers the VOC limit for surface preparation and cleanup. The current VOC limit for strippers is equivalent to the limit specified by SCAQMD, and therefore remains the

same.

In the current rule, Section 308.1 allows spray gun nozzles to be soaked in solventbased materials in a tightly covered container not exceeding 5 gallons in size. Staff proposes to eliminate this section to be consistent with SCAQMD Rule 1171, which currently does not contain such a provision.

Staff is proposing to limit the applicability of the emissions averaging provisions in Section 306 to a maximum of 20 gallons per year of noncompliant, refinishing coatings applied to historical reproductions of antique wood products. Only one facility in the District currently uses Section 306, Emissions Averaging Provisions, to comply with Rule 463. This change is being proposed to addr ess requirements in the EPA Region IX “Little Bluebook” ( Guidance Document for Correcting Common VOC & Other Rule

Deficiencies , April 1, 1991, revised August 21, 2001) and RACT requirements for major

sources.

The proposed changes to this rule are indicated below.

1. Add a severability section to this rule. 2. Remove the exemption pertaining to stencil coatings used in compliance with U.S. Military Specifications. (Staff determined that the facility that used this exemption is no longer in operation.) 3. Lower the solvent VOC limit for surface preparation or cleanup from 200 g/l to 25 g/l. 4. Revise the equation for determining compliance with emissions limits for coatings. 5. Limit the applicability of Section 306, as described previously. 6. Add definition of “historical reproduction coating.” 7. Revise the duration of records requirement from three to five years to be consistent

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 21

with other District rules, and 8. Update the test methods to specify the most current test methods.

Rule 464

Rule 464 limits VOC emissions from organic chemical plants. These are the proposed changes to Rule 464:

1. Lower the solvent VOC limit for maint enance solvent cleaning from 50 g/l to 25 g/l,

and 2. Update the test methods to specify the most current test methods.

Rule 465

Rule 465 regulates emissions of VOCs from polyester resin operations, which include bathtub, shower, and sink manufacturers and spa and boat manufacturers. The proposed changes to Rule 465 are listed below.

1. Lower the solvent VOC limit for cleaning materials from 204 g/l to 25 g/l, 2. Increase the overall emissions control efficiency requirements from 85% to 90% to be consistent with the more stringent, feasible requirements in SCAQMD Rule 1162. 3. Revise the duration of records requirement from three to five years to be consistent with other District rules, and 4. Update the test methods to specify the most current test methods.

Rule 466

Rule 466 regulates emissions from solvent cleaning activities, which include repair and maintenance cleaning, architectural coating application equipment cleaning, cleaning during manufacturing, and surface preparation. The proposed amendments require general cleaning to be performed with materials that contain less than 25 grams per liter VOCs as applied. The proposed changes also involve lowering other VOC content limits, with various limits specified for each type of cleaning activity. For some cleaning activities, such as medical devices/pharmaceuticals and platelets, the VOC limits will remain unchanged. The proposed rule still allows the use of air pollution control equipment as an alternative to complying wi th the VOC limits proposed by the rule, although emission control systems must ensur e that emissions are no greater than would have resulted from compliance with the applicable VOC limits. The rule also specifies cleaning method requirements, general equipment requirements, operating requirements, storage and disposal requirements, and recordkeeping requirements.

Staff is proposing to add an exemption for the cleaning of high-voltage microwave vacuum tubes, at the request of a facility within the District that manufactures these

devices. Staff has reviewed detailed technical information submitted by this facility and concurs that the use of low-VOC solvents is technically infeasible for this application. The facility conducted testing of various low-VOC solvents and blends over the past three years and has been unable to find a suitable alternative to using 100% isopropyl alcohol for the cleaning of components during the manufacture and repair of high-

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 22

voltage microwave vacuum tubes. The high-vacuum, high-voltage operation of the devices requires an ultra-low level of contamination by organic residues and moisture.

Alternative low-VOC solvents were demonstrat ed to result in unacceptably high failure rates of these devices, which are the principal components of electronic radar-jamming

devices. Some of these devices are used in aerospace applications, which are exempt under Rule 456. Staff researched the location of competitors for this source and
identified SCAQMD and BAAQMD. Staff reviewed the rules for these districts and contacted SCAQMD staff to discuss the compliance status of these facilities. It was determined that the cleaning of these devices with high VOC solvents is allowed under the existing rules for aerospace assembly operations.

The current exemption in Section 110.2(g) for electrostatic coating application equipment cleaning is being proposed for removal, consistent with the June 30, 2005 sunset of an exemption for this cleaning category in SCAQMD Rule 1171.

Staff also proposes to add a specific exemption from the solvent cleaning requirements for the stripping of cured inks, cured coatings, and cured adhesives. Since the current definition of solvent cleaning already implies that the stripping of such cured materials is exempt, this new exemption is fo r clarification purposes only.

In the current rule, Section 302.8 allows spray gun nozzles to be soaked in solventbased materials in a tightly covered container not exceeding 5 gallons in size. Staff proposes to eliminate this section to be consistent with SCAQMD Rule 1171, which currently does not contain such a provision.

The additional proposed changes are specified below.

1. Lower the solvent VOC limits for seve ral cleaning categories, as shown in the following table.

VOC Content g/l (lb/gal)

Solvent Cleaning Activity Prior to (one year after

date of adoption) Effective (one year after

date of adoption) General (wipe cleaning, maintenanc e cleaning) 50 (0.42) 25 (0.21) Product Cleaning During Manufacturing Process or Surface Preparation for Coating, Adhesive, Sealant s, or Ink Application

General Electrical Apparatus Components and Electronic Components

Medical Devices and Pharmaceuticals

Platelets 50 (0.42) 500 (4.2) 800 (6.7) 800 (6.7) 25 (0.21) 100 (0.83) 800 (6.7) 800 (6.7) Repair and Maintenance Cleaning

General Electrical Apparatus Components and Electronic Components

Medical Devices and Pharmaceuticals

General Work Surfaces Tools, Equipment, and Machinery

Platelets 50 (0.42) 900 (7.5)

600 (5.0) 800 (6.7) 800 (6.7) 25 (0.21) 100 (0.83)

600 (5.0) 800 (6.7) 800 (6.7)

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 23

VOC Content g/l (lb/gal)

Solvent Cleaning Activity Prior to (one year after

date of adoption) Effective (one year after

date of adoption) Architectural Coating Application Equipment

Water based Coatings

Enclosed Gun Cleaner

No Enclosed Gun Cleaner

Solvent based Coatings

Enclosed Gun Cleaner No Enclosed Gun Cleaner, cleaning at jobsite No Enclosed Gun Cleaner, cleaning not at jobsite No limit 50 (0.42)

No limit 300 (2.5) 50 (0.42) 25 (0.21) 25 (0.21)

25 (0.21) 25 (0.21) 25 (0.21)

Sterilization of food manufa cturing and processing equipment No limit 200 (1.68)



### 2. Revise the duration of records requirement from three to five years to be consistent with other District rules, 3. Add a new VOC limit of 200 g/l for the sterilization of food product manufacturing and processing equipment (shown in the table above). 4. Add definitions of “general work surface,” “jobsite,” “pharmaceutical product,” “solvent based coating,” “water based coating,” “sterilization,” “food manufacturing and processing operation,” “stripping,” and “cured coating, cured ink, or cured adhesive,” using the same definitions as those in the SCAQMD rules, and 5. Update the test methods to specify the most current test methods. 6. Remove the exemption for the cleaning of electrostatic application equipment. 7. Add an exemption for the cleaning of high-voltage microwave vacuum tubes.

EMISSIONS IMPACT

In most cases, emissions reductions for individual cleaning categories were calculated by multiplying the percentage reduction for that category by its corresponding emissions inventory. Percentage reductions were comput ed by comparing the current VOC limit to the proposed limit. (For example, the lowe ring of a VOC limit from 100 g/l to 25 g/l represents a 75% reduction.) Because more specific information is not available, these emissions calculations assume that all sources performing the specific cleaning activity use products matching the current VOC limit, and will replace them with products matching the proposed VOC limit.

A different approach was used to calculate emission reductions for categories for which all affected sources could be identified. In these cases, more precise emissions reductions were computed by comparing the actual VOC content of the current products to the proposed VOC limits. The amounts of solvent products currently used by affected facilities were obtained though telephone inquiries and annual emission inventory surveys of these facilities. Usage amounts are not expected to change when switching from the current product to a compliant, low VOC product. Staff also assumed that current annual solvent usage amounts are representative of usage levels in 2010 (the year for which the emission reductions were estimated).

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 24

Staff expects that compliance with the lower VOC limits will be achieved, in many cases, by using acetone (an exempt compound), or by using mixtures of acetone and other exempt compounds. The assumption that the VO C content of replacement materials will

match the VOC limits leads to conservative estimates of the emission reductions.

The total emission of VOC from all solvent cleaning operations, in the absence of the proposed amendments, is projected to be 498 tons per year in 2010. The allocation of this inventory to specific activities covered by individual rules in presented in Appendix

C.

Rule 450

As shown in Appendix C, the estimated 2010 emissions inventory for solvent cleaning activities associated with Rule 450 is 80.82 tons per year of VOC. The proposed amendments to the rule are expected to result in an overall VOC emission reduction of 55.16 tons per year. The VOC emission reductions were estimated based on the following information: 1. Estimated 2010 emissions inventory for Rule 450 in Appendix C, and 2. The 2004 SCAQMD emissions inventory (from the 4/19/05 staff report for SCAQMD Rule 1171) to estimate the % of each graphic arts related cleaning activity, as shown in the following table. (The 2004 SCAQMD emissions inventory represents the last inventory prior to implementation of reduced VOC limits in 2005 and 2006 for Rule 1171.) Graphic arts-related cleaning processes within Sacramento County are expected to be similar to the SCAQMD. These percentages were applied to the 2010 emissions inventory to approximate the annual emissions for each cleaning activity. Except for newsprint and UV/electron beam inks, emissions reductions were calculated by using the current-to- proposed VOC limit comparison described in the beginning of the Emissions Impact section.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 25

Cleaning Activity % of Rule

450 inventory 2010

Emissions Inventory (Tons/year) Current

VOC limit (g/l) Proposed
VOC limit (g/l) % VOC

Emissions

Reduction 2010 VOC

Emissions

Reduction (Tons/year) Repair &

Maintenance Cleaning (i) General* 0.00% 0.00 72 25 65.28% 0 Ink Application Equipment Cleaning

(i) General 0.96% 0.78 100 25 75.00% 0.58 (ii) Flexographic or
Gravure 5.02% 4.05 100 25 75.00% 3.04 (iii) Litho/Letterpress (1) Roller

Wash-Blanket Wash & Metering Rollers & Printing Plates (a) Newsprint 2.70%** 2.18** 300 100 83.49%** 1.82** (b) Other

Substrates 67.33% 54.41 300 100 66.67% 36.28 (2) Removable Press Components 0.58% 0.47 100 25 75.00% 0.35 (iv) Screen Printing 20.45% 16.53 300 100 66.67% 11.02 (vi) UV/Electron

Beam Ink 0.85%** 0.69** 800 100 82.60%** 0.57** (vii) Specialty Flexographic 2.12% 1.72 810 100 87.65% 1.50

TOTAL 100.00% 80.82 68.25% 55.16 * Based on annual District survey data of permitted source s, general repair and maintenance cleaning solvent emissions are minimal. ** For these categories, all sources were readily identified using the District permit database and other permit records. Annual emission inventor y surveys, telephone surveys, and annual permit inspection reports provided the annual so lvent usage amounts and VOC contents of current products necessary to compute more precise VOC emission inventories and reductions for each facility identified. Note that the VOC content of current products may exceed current limits if products comply with the low vapor pressure option.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 26

No emissions reductions will result from the amendments proposed to address the 2006 CTGs for graphic arts. According to District permitting records, all sources are already in compliance with the proposed VOC limits for fountain solutions. Of the 22 sources that conduct sheet-fed offset lithographic printing operations, six will be exempt (their emissions are below 15 lbs/day) and the rest currently use fountain solutions achieving the proposed VOC limits. Of the six sources that conduct coldset web offset lithographic printing operations, three will be exempt (their emissions are below 15 lbs/day) and the other three currently use fountain solutions containing less than 5% alcohol substitute. All four facilities conducting heatset web o ffset lithographic printing operations are using fountain solutions compliant with the proposed VOC limits. The graphic arts facilities that use presses exceeding the 25 tons/year potential to emit level already use emissions control equipment that achieve t he proposed overall system efficiency levels.

Each amendment will result in the following VOC emission reductions, calculated for

2010:

Requirement VOCs Reduced Tons/year General Repair and Maintenance Cleaning 0

Application Equipment Cleaning 1. General (not specifically listed) 0.58 2. Lithographic & Letter Press Printing, Blanket & Roller Washes Metering Rollers and Printing Plates, Newsprint 1.82

3. Lithographic & Letter Press Printing, Blanket & Roller Washes Metering Rollers and Printing Plates (Except Newsprint) 36.28

4. Lithographic & Letter Press Printing, Removable Press Components 0.35

5. Screen Printing 11.02 6. Flexographic Printing 3.04 7. Specialty Flexographic Printing 1.50 8. Ultraviolet Inks (Except Screen Printing) 0.57

2006 CTG requirements for fountain solutions and control equipment 0

Total 55.16

Rule 451

Staff identified 61 permitted metal parts/products coating operations in the District permit database. The estimated VOC emissions inventory for solvent cleaning activities associated with Rule 451 in 2010 is 11.09 tons per year, 7.15 tons per year of which are

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 27

attributed to application equipment cleaning and 3.94 tons per year to surface preparation/cleanup (see Appendix C). The anticipated emission reduction for 2010 for surface preparation, product cleaning, and application equipment cleanup is a combined 163 pounds per year. This reduction is rela tively small because only five facilities currently use noncompliant material, according to annual facility inspection reports. Annual emissions inventory survey data showed that four of these facilities have small annual usage totals for these products, while one facility reported high usage of a product only slightly exceeding 25 g/l. The other facilities already meet the proposed standards, either by using the low usage exemption, exempt compounds (such as acetone), or soap and water.

No emissions reductions will result from the amendments proposed to address the 2007 CTG for metal furniture coatings. According to District permitting records, only one source currently conducts metal furniture coating operations. However, this facility only conducts powder coating operations, and its total annual emissions from such coating operations fall well below the applicability threshold of 3 tons of VOC per 12-month rolling period. Based on permitting records, Staff also determined that none of the existing facilities subject to Rule 451 use emissions control equipment.

Rule 452

The estimated 2010 VOC emissions inventory for solvent cleaning associated with Rule 452 is 13.31 tons per year for application equipment cleaning, as shown in Appendix C. There is currently only one can coating operation, Silgan Can Company. No emissions reductions will result from the proposed rule because Silgan does not use VOC containing solvents for cleaning, already m eets the proposed lower VOC limits for can coating, and uses emissions control equipment to comply with the application equipment requirements in Section 304, which specifies the same overall control efficiency (85.5%) required under the current rule. Information contained in the annual emission inventory survey indicates that only exem pt compounds are used for cleaning.

Rule 454

As shown in Appendix C, the estimated 2010 VOC emissions inventory for solvent cleaning associated with Rule 454 is 101.97 tons per year. The proposed amendments to the rule are expected to result in an overall VOC emission reduction of 50.99 tons per year, calculated for 2010.

Each amendment will result in the following VOC emission reductions:

Requirement VOCs Reduced Tons/year Non-vapor degreasing 50.29 Vapor degreasing 0.7

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 28

Rule 456

The estimated 2010 VOC emissions inventory fo r solvent cleaning activities associated with Rule 456 is 14.32 tons per year, 9.03 tons per year of which are attributed to application equipment cleaning and 5.29 tons per year to surface preparation/cleanup. There are currently two facilities that c onduct aerospace application equipment cleanup using noncompliant material. These facilities use high VOC materials in enclosed gun cleaners, which can no longer be used for compliance with the proposed VOC limits. Assuming that enclosed gun cleaners result in VOC emissions equivalent to the current VOC limit (200 g/l) for application equipment cleanup, the proposed requirements are expected to result in an overall emission reduction of 17 pounds per year. This reduction is based on the usage rates for the only two facilities that use noncompliant

material.

Rule 463

Despite no current requirement to use low VOC products for surface preparation/cleanup, all permitted sources already voluntarily perform surface preparation or cleanup activities using acetone or water. Because of the widespread, voluntary use of acetone for this cleaning activity, Staff has no reason to expect that unpermitted sources use VOC containing solvents. However, the current inventory for this category still assumes that wood coating sources use VOC-containing solvents. As given in Appendix C, the estimated 2010 VOC emissions inventory for solvent cleaning associated with this rule is 24.75 tons per year, consisting of 22.33 tons per year from application equipment cleaning and 2.42 tons per year from surface preparation/cleanup. Emission reductions were estimated by applying an 87% reduction (the VOC limits are lowered from 200 g/l to 25 g/l) to both the surface preparation and cleanup inventories. The adoption of the new requirements will result in an inventory reduction of 21.4 tons per year of VOC for this rule.

Rule 464

None of the three facilities currently regul ated by Rule 464 currently use solvent-based materials for maintenance cleaning in or ganic chemical manufac turing operations. Water-based detergent solutions are used for this purpose. No emissions reductions will result from the proposed rule.

Rule 465:

The five permitted sources in Sacramento County that conduct polyester resin operations use acetone in their cleaning activities. However, the inventory for this category still assumes that polyester resin operations use VOC-containing solvents. As computed in Appendix C, the estimated 2010 VOC emissions inventory for solvent cleaning activities associated with this rule is 1.97 tons per year, consisting of 1.44 tons per year from application equipment cleaning and 0.52 tons per year from surface preparation/cleanup. Emission reductions were estimated by applying an 87% reduction (the VOC limits are lowered from 204 g/l to 25 g/l) to both the surface preparation and cleanup inventories. The adoption of the new requirements will result in an inventory

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 29

reduction of 1.72 tons per year of VOC for this category.

Rule 466

The estimated 2010 VOC emissions inventory fo r solvent cleaning activities associated with Rule 466 is 141.91 tons per year, as shown in Appendix C. The proposed amendments to the rule are expected to result in an overall VOC emission reduction of 66.24 tons per year (see below). The VOC emissions inventory and reductions were estimated based on the following information:

1. Architectural coating equipment cleaning category: The 2010 CARB Ozone SIP Planning Inventory, Version 1.06, Sacramento NAA (Rf#980), November 16, 2006, was used (www.arb.ca.gov/app/emsi nv/o3sip/fcemssumcat_o3v106.php). The inventory for this category is 82.82 tons per year. This inventory consists of both cleaning for water-based coatings and cleaning for solvent-based coatings A composite emissions reduction percentage of 57.1% was calculated based upon the assumption that 83% of architectural solvent usage is attributed to the water-based coatings subcategory (refer to the CARB report entitled “New Method for Estimating Emissions from Thinning and Cleanup Solvents,” March 9, 2006), and the remaining 17% of the usage is attributed to solvent-based coating cleaning. The emissions reduction is an estimated 47.34 tons per year.

2. All other solvent cleaning categories in Rule 466: The 2004 SCAQMD emissions inventory (see previous discussion for Rule 450) was used to establish the percentage breakdown for each solvent cleaning activity related to Rule 466. These cleaning processes within Sacramento County are expected to be similar to the SCAQMD. The percentage breakdown is shown in the table below. These percentages were applied to the remaining 2010 emissions inventory (see Appendix C) of 141.91-82.82 = 59.09 tons per year to approximate the annual emissions for each cleaning category. The current-to-proposed VOC limit comparison was then used to estimate the emissions reductions shown in the following table. The total emissions reduction for these solvent cleaning categories is 17.16 tons per year.

Cleaning Activity % of Rule 466 inventory (excluding

architectural coating equipment cleaning) 2010

Emissions Inventory (Tons/year) Current

VOC

limit (g/l) Proposed
VOC limit (g/l) % VOC

Emissions

Reduction 2010 VOC

Emissions

Reduction (Tons/year) (A) Product Cleaning & Surface Preparation

(i) General 10.77% 6.36 50 25 50.00% 3.18 (ii)

Electrical/Electronic Apparatus & Components
20.05% 11.85 500 100 80.00% 9.48

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 30

Cleaning Activity % of Rule 466 inventory (excluding

architectural coating equipment cleaning) 2010

Emissions Inventory (Tons/year) Current

VOC

limit (g/l) Proposed
VOC limit (g/l) % VOC

Emissions

Reduction 2010 VOC

Emissions

Reduction (Tons/year) (iii) Medical Devices

&Pharmaceuticals 29.09% 17.19 800 800 0.00% 0.00 (B) Repair &

Maintenance

(i) General 8.25% 4.88 50 25 50.00% 2.44 (ii)

Electrical/Electronic Apparatus & Components
3.93% 2.32 900 100 88.89% 2.06 (iii) Medical Devices &

Pharmaceuticals

(A) Tools, Machinery & Equipment 15.72% 9.29 800 800 0.00% 0.00 (B) General Work

Surfaces 12.19% 7.20 600 600 0.00% 0.00

TOTAL 100.00% 59.09 29.04% 17.16



### 3. Methods #1 and #2 above were not used to calculate the emission reductions for food equipment sterilization. These emission reductions are based on annual emission inventory surveys, telephone surveys, and permit records. These reductions were calculated using the same methods as described above for readily identifiable sources. The estimated emission reduction is 1.74 tons per year.

The table below summarizes the VOC emission reductions:

Requirement VOCs Reduced Tons/year Product Cleaning During Manufacturing Process or Surface Prep aration for Coating, Adhesive, Sealants, or Ink Application

1. General 3.18 2. Electrical Apparatus Components and Electronic Components 9.48

3. Medical Devices and Pharmaceuticals 0 (no change in VOC limit) 4. Platelets 0 (no change in VOC limit) Repair and Maintenance Cleaning

1. General 2.44 2. Electrical Apparatus Components and Electronic Components 2.06

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 31

Requirement VOCs Reduced Tons/year

3. Medical Devices and PharmaceuticalsGeneral Work Surfaces 0 (no change in VOC limit)

4. Medical Devices and PharmaceuticalsTools, Equipment, and Machinery 0 (no change in VOC limit)

5. Platelets 0 (no change in VOC limit) Architectural Coating Application Equipment 1. Water-based Coatings 2. Solvent-based Coatings 47.34 (combined) Sterilization of food product manufacturing and processing equipment 1.74

Total 66.24



### Total Emission Reduction for All Rules:

The total reduction in VOC emissions from the amendment of all nine rules is 195.64 tons per year, calculated for 2010. The tabl e below summarizes the emission reductions

for each rule.

Rule VOCs Reduced Tons/year

450 55.16

451 0.081

452 0

454 50.99

456 0.008

463 21.44

464 0

465 1.72

466 66.24

Total 195.64

COST IMPACT

Section 40703 of the California Health and Safety Code requires that districts consider and make public findings relating to the cost effectiveness of implementing an emission

control measure.

Cost to Businesses:

The majority of the proposed solvent cleaning limits are not expected to result in additional costs to the industry because compliant products, which have been readily available for some time, do not cost more than the materials currently used, with exceptions noted in the following sections. SCAQMD has released several technology

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 32

assessments in 2003 and 2006 demonstrating that, for many cleaning applications, current cleaning products can be diluted with water or blended with other compliant products to form a compliant cleaning material that is also equally effective. These technology assessments are availa ble at http://www.aqmd.gov/rules/support.html#r1171.

A technology assessment 1 

### performed by SCAQMD concluded that compliant products for the cleaning of application equipment are readily available in the market and do not result in additional costs to industry. SCAQMD has published a list of “Clean Air Solvents,” defined as solvents with VOC concentrations not greater than 25 g/l, that comply with both SCAQMD Rules 1122- Solvent Degreasers and 1171- Solvent Cleaning Operations. Businesses looking for information on compliant products will find further information at the SCAQMD Clean Air Solvent Certification Program at http://www.aqmd.gov/rules/cas/index.html.

The cost information presented below is prim arily based on SCAQMD cost estimates, which are applicable because industry processes in SCAQMD are similar to those in SMAQMD. Staff expects that sources in SMAQMD can readily replace their current products with the compliant products because they are currently available in SCAQMD.

The following sections provide additional cost information for each proposed rule.

Rule 450

General Wipe Cleaning : There will be no additional costs for this category. Low VOC cleaners are detergent-based and cost more per gallon than solvent-based cleaners, but can be diluted with water, resulting in a lower total cost.

Application Equipment Cleaning - Roller and Blanket Washes, Metering Rollers and Printing Plates, and Other On-Press Components: Based on the March 2006 SCAQMD technology assessment for lithographic printing, the cost of compliant material is approximately $16 per gallon, while the approximate average cost of the current cleaning products is $6.60 per gallon.

Application Equipment Cleaning – Removable Press Components: According to the 9/27/99 staff report for SCAQMD Rule 1171, the proposed requirements will result in increased costs if handwiping is performed, but no additional costs if remote reservoir cleaners are used (see the 8/15/96 staff report for SCAQMD Rule 1171 for cost effectiveness analysis for remote reservoir cleaners). SCAQMD estimates that 75% of the emissions from this category are from handwipe operations and the remaining 25% are from using remote reservoir cleaners. SCAQMD states that current handwiping materials can be blended with acetone, a mixture of acetone, MeAc, and PCBTF, or a mixture of MeAc and PCBTF to achieve the proposed 25 g/l limit, for an average cost of $19 per gallon. The approximate average cost of the current cleaning products is $9 per gallon.

1 “Assessment, Development and Demonstration of Lo w-VOC Cleaning Systems for South Coast Air Quality Management District Rule 1171,” SCAQMD, August 2003.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 33

Application Equipment Cleaning – Screen Printing: Based on the May 2006 SCAQMD technology assessment for screen printing, the cost of a typical compliant material is approximately $10.90 per gallon, while the typical cost of the current cleaning products is approximately $13 per gallon. Most screen printing operations are expected to reduce costs by switching to the lower VOC cleaning materials.

Application Equipment Cleanup – Flexographic Printing: The proposed requirements applicable to flexographic printing are not expected to result in an increase in cost to affected businesses, according to SCAQMD’s industry sources (1999 staff report for SCAQMD Rule 1171).

Application Equipment Cleanup – Specialty Flexographic Printing: The proposed requirements applicable to specialty flexographic printing are expected to result in cost savings for affected businesses, according to the 9/27/99 staff report for SCAQMD Rule 1171. SCAQMD states that the 100 g/l limit can be met by blending VOC materials currently used (IPA) with water. The estimated cost of this mixture is $1 per gallon, whereas the cost of IPA is approximately $6 per gallon.

Application Equipment Cleanup – Ultraviolet/Electron Beam Inks: The 650 g/l VOC limit was implemented by SCAQMD in July 2006. According to the June 2006 SCAQMD Rule 1171 staff report, SCAQMD expects no additional compliance costs associated with this new VOC limit. SCAQMD also states that compliant products are readily available and their costs are comparable to that of existing high-VOC solvents.

The eventual VOC limit of 100 g/l (effective 1/ 1/2010) is expected to result in cost savings for the one permitted source that performs application equipment cleanup of UV/electron beam inks. This facility uses a UV wash costing $6 per gallon, according to a recent telephone survey. The 9/27/99 staff report for SCAQMD Rule 1171 estimates that a compliant product (a blend of IPA, the current VOC material, with water) costs $1 per gallon.

Fountain Solutions and Control Equipment: As described earlier, no graphic arts facilities will be affected by the proposed changes for fountain solutions and control equipment because they either will be exempt or already use solvents or control equipment achieving the proposed, CTG-recommended requirements. Therefore, no additional compliance costs will be incurred.

Rule 451

Application Equipment Cleanup: The proposed requirements are expected to result in cost savings for affected businesses. According to the November 2003 staff report for SCAQMD Rule 1171, the average cost of compliant material (consisting of such products as acetone, a mixture of acetone and PCBTF, and a mixture of acetone and sulfonic acid) is $11 per gallon. The average cost of currently used material is $14.16 per gallon.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 34

Product Cleaning or Surface Preparation: SCAQMD stated in the 1999 staff report for Rule 1171 that reducing the VOC limit from 70 g/l to 25 g/l would not result in increased cost due to minimal material substitution necessary to lower the VOC content. For the same reason, Staff believes that lowering this VOC limit from 72 g/l to 25 g/l will not

increase costs.

SCAQMD has found that cleaning products m eeting the 25 g/l VOC limit are comparable to those complying with the 50 g/l limit (as well as those complying with the previous limit of 70 g/l) in terms of average price. Staff therefore believes that lowering the limit from 72 g/l will not lead to additional compliance costs.

Metal Furniture Coatings and Control Equipment: District permitting records indicate that only one facility in Sacramento County conducts metal furniture coating operations. However, this facility only conducts powder coating operations, and its total annual emissions from such coating operations fall well below the applicability threshold of 3 tons of VOC per 12-month rolling period. Based on permitting records, staff also determined that none of the existing facilities subject to Rule 451 use emissions control equipment. Therefore, the proposed CTG-recommended amendments will not lead to additional compliance costs.

Rule 452

The only source affected by this proposed rule is already in compliance with the proposed rule. As a result, no additional compliance costs are incurred.

Rule 454

In the previous amendment of Rule 454, Staff found that almost all of the regulated facilities were using solvent type parts cleaners, which are usually leased. With the eventual adoption of the amendment, the affected sources were essentially required to replace these degreasers with new units that are designed to be used with aqueous cleaners since almost all of the low VOC cleaners are aqueous. Those same sources, which have since installed aqueous cleaning equipment, do not need to replace their cleaning systems again because the new rule requires them only to switch to another aqueous material with lower VOC content. There will be no additional compliance costs associated with Rule 454 because no cleaning system replacement is necessary and the cost of compliant materials is comparable to the current aqueous products used.

Rule 456

Compliance costs are expected to decrease for the two sources that currently perform spray gun cleaning using noncompliant materials. The average cost of the noncompliant material is $23.40 per gallon, while the average cost of compliant material, as given in the November 2003 staff report for SCAQMD Rule 1171, is $11 per gallon. Examples of compliant materials include acetone, an acetone/PCBTF blend, and an acetone/ sulfonic

acid blend.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 35

Rule 463

The proposed amendments are not expected to result in a change in cost for affected businesses because they are already using exempt compounds. Acetone, an exempt compound, is currently used in surface preparation operations.

Rule 464

Facilities currently regulated by Rule 464 use water-based detergent solutions for maintenance cleaning in organic chemical manufacturing operations. Because these materials already comply with the proposed limits, there will be no additional costs.

Rule 465

There will be no additional compliance costs associated with the proposed amendments. Acetone is the cleaning product used in polyester resin operations.

Rule 466

General Product Cleaning/ Surface Preparation, General Repair/Maintenance Cleaning, Cleaning of Architectural Coating Application for Solvent-based coatings (for cleaning not performed at jobsite) and Water-based coatings, and Spray gun cleaning: There is no expected cost increase for these categories because sources are already using aqueous cleaners or acetone to meet the current 50 g/l VOC limit. The proposed rule will require some sources to switch from one aqueous cleaning solvent to another comparably-priced material that meets the new VOC limit.

Product Cleaning/ Surface Preparation- Electrical Apparatus and Electronic Components: The proposed requirements applicable to cleaning of electrical components are expected to result in either cost savings or increases for affected businesses, depending on the compliant product a particular source chooses. The following table summarizes the approximate cost of current cleaning products and their potential replacements. The cost data is based on the 9/27/99 staff report for SCAQMD

Rule 1171.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 36

*Note: Exempt solvent blend is a mixture of acetone, methyl acetate, and parachlorobenzotrifluoride. Estimated cost of this mixture is $23 per gallon, according to the 9/27/99 staff report for SCAQMD Rule 1171.

Repair/Maintenance Cleaning- Electrical Apparatus and Electronic Components:

The proposed requirements applicable to repair/maintenance cleaning of electrical components are expected to result in either cost savings or increases for affected businesses, depending on the compliant product a particular source chooses. The table below summarizes the approximate cost of current cleaning products and their potential replacements. The cost data is based on the 9/27/99 staff report for SCAQMD Rule

1171.

Category Cost of Current Material (900 g/l) Cost of Compliant Material (100 g/l)

Printed circuit boards $6 per gallon (IPA) $1 per gallon (mixture

of deionized water and IPA)

Other electrical and electronic components $6 per gallon (IPA) $3 per gallon (mixture

of current material with acetone)

Or $21 per gallon (mixture

of current material with exempt solvent blend) *Exempt solvent blend is a mixture of acetone, methyl acetate, and parachlorobenzotrifluoride. Estimated cost of this mixture is $23 per gallon, according to the 9/27/99 staff report for SCAQMD Rule 1171. Category Cost of Current Material (500 g/l) Cost of Compliant Material (100 g/l)

Printed circuit boards $3 per gallon (mixture of deionized water and IPA) $1 per gallon (mixture

of deionized water and IPA)

Other electrical and electronic components $5 per gallon (mixture of

current material with acetone)

Or $14 per gallon (mixture of

current material with exempt solvent blend*) $3 per gallon (mixture

of current material with acetone)

Or $21 per gallon (mixture

of current material with exempt solvent blend*)

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 37

Architectural Coating Application Equipment- Solvent based Coatings (for cleaning performed at jobsite):

Sources that perform this type of cleaning at the jobsite currently use a mixture of thinner, acetone and other exempt solvents to meet the 300 g/l limit. There will be an increase in compliance cost. The cost data shown in the table below was taken from the 5/23/02 staff report for Rules 454 and 466 and the 9/27/99 staff report for SCAQMD Rule

1171.

Cost of Current Material (300 g/l) Cost of Compliant Material (25 g/l)

$7 per gallon (mixture of thinner, acetone and other exempt solvents) $19 per gallon (mixture of current

material with acetone and other exempt solvents)

Sterilization of food product manufacturing and processing equipment:

The proposed requirements applicable to food manufacturing/processing equipment sterilization are expected to result in cost savings for affected businesses. Staff identified one source that currently conducts this sterilization process. This facility will be able to meet the 200 g/l VOC limit by diluting their current VOC product (IPA) with water. This compliance method has been proven to be sufficient for accomplishing the FDA-required sterilization for sources subject to a similar VOC standard in SCAQMD. (Please refer to the 8/23/00 staff report for SCAQMD Rule 1131 for supporting documentation.) The cost data of the current non-compliant material is based on a price quote from an online vendor for a 500 gallon drum of sterilizing product. Diluting with water will lower the IPA usage at this facility to 35% of the current usage.

Category Cost of Current Material (571 g/l) Cost of Compliant Material (200 g/l)

Sterilization of food product manufacturing and processing equipment 

### $13.61 per gallon (IPA) $4.76 per gallon (mixture of water and IPA)

Overall Rule Cost Effectiveness:

The cost effectiveness estimates for the rule amendments are shown in the following table. The rule-by-rule cost data in the preceding “Cost Impact” section was used to calculate the overall compliance cost and the corresponding cost effectiveness for each rule. The sum of all compliance costs divided by the sum of all emission reductions (from the preceding “Emissions Impact” section) yields the overall cost effectiveness for the particular rule.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 38

Rule Cost Effectiveness 450 $3.70 per lb of VOC reduced 451 Cost savings 456 Cost savings 466 $3.70 per lb of VOC reduced

In year 2007 dollars, previously adopted Distri ct rules have cost effectiveness figures for VOC reductions ranging from $1.06 per pound of VOC reduced (for the 8/21/1990 adoption of Rule 452) to as much as $18.05 per pound of VOC reduced (for the 12/17/1991 adoption of Rule 449, Transfer of Gasoline into Vehicle Fuel Tanks).

Cost to the District:

The proposed amendments are not expected to result in additional costs to the District. Sources affected by the rule amendments ar e already subject to requirements under the existing rules.

SOCIOECONOMIC IMPACT

CHSC Section 40728.5 requires a district to perform an assessment of the socioeconomic impacts before adopting, amending, or repealing a rule that will significantly affect air quality or emission limitations. The District Board is required to actively consider the socioeconomic impacts of the proposal and make a good faith effort to minimize adverse socioeconomic impacts.

CHSC Section 40728.5 defines “socioeconomic impact” to mean the following:

1. The type of industry or business, including small business, affected by the proposed rule or rule amendments. 2. The impact of the proposed rule or rule amendments on employment and the economy of the region. 3. The range of probable costs, including costs to industry or business, including

small business. 4. The availability and cost-effectiveness of alternatives to the proposed rule or rule

amendments. 5. The emission reduction potential of the rule or regulation. 6. The necessity of adopting, amending, or repealing the rule or regulation to attain

state and federal ambient air standards.

Type of industry or business, including small business, affected by the rule

amendments:

Rule 450 applies to all graphic arts operations, including small businesses. According to the Sacramento County business directory, t here are over 260 graphic arts operations in the District. All of these graphic arts operations are currently subject to the solvent cleaning limits in Rule 450 and will be affected by the proposed rule amendments.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 39

There are 61 permitted metal parts and products coating operations that are currently subject to the requirements of Rule 451. Five of these operations will be affected by the new solvent cleaning limits in the proposed ru le. All other operations already employ exempt compounds, water, or low-VOC material for surface preparation and/or equipment cleaning. As described earlier, none of the current sources subject to Rule 451 will be affected by the proposed CTG-recommended changes.

There is only one can coating process operating within the District. This source

manufactures steel and aluminum container s used for food products like soup, meat, vegetables, and coffee. The proposed changes to Rule 452 will not affect this source because exempt compounds are already being used to clean container assembly equipment.

Rule 454 will affect all degreasing operations. The majority of degreasers in the District are parts cleaners, but only two parts cleaners ar e required to obtain air district permits because most parts cleaners are smaller than our 100 gallon exemption. All parts cleaners, however, are subject to Rule 454. Parts cleaners are widely used by automotive repair shops. According to the Bureau of Automotive Repair, there are over 1900 automotive repair operations in the county. In addition to the two permitted parts cleaners, there are three other permitted degreasing operations in the District.

Rule 456 will affect two aerospace coating operations. All other facilities are in compliance with the proposed VOC limits for spray gun cleaning, the only cleaning activity with a reduced VOC limit.

All wood products operations exceeding 55 gallons a year in coating and stripper usage are subject to the new requirements in Rule 463. Many of the wood products operations are conducted by small businesses that produce wood household furniture, kitchen cabinets, television cabinets, office furniture, and store fixtures. All permitted businesses are already in compliance with the proposed VOC content limits in this rule. Because of the widespread use of acetone, businesses that are exempt from permit requirements because of low usage are also expected to be in compliance with the proposed limits.

Organic chemical manufacturing operations with uncontrolled VOC emissions exceeding 15 pounds per day are required to comply with the requirements of the Rule 464. As mentioned earlier, none of the three facili ties currently regulated by Rule 464 use solvent-based materials for maintenance cleaning, and are, therefore, already in compliance with the proposed rule.

Rule 465 will affect businesses that use polyester resins in their manufacturing process, which include tub, shower, and sink manufacturers and tomato bin manufacturers. There are currently seven facilities regulated by the rule. These sources and others with resin usage exceeding 20 gallons per month are subject to the new requirements. As previously stated, products currently used by these sources comply with the proposed

rule.

Rule 466 was introduced in 2002 to address previously unregulated cleaning operations,

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 40

such as wipe cleaning and cleaning of medical devices and pharmaceuticals, electrical apparatus components and electronic components, and architectural application equipment. The proposed rule will continue to regulate these operations and other solvent cleaning operations not already addr essed by the industry specific solvent cleaning rules.

Impact of rule amendments on employment and the economy in the District:

Amendments for two of the rules – Rule 450 and Rule 466 – will result in additional costs to businesses to comply with the new requirements. The increase in annual costs for the entire graphic arts industry is estimated to be $408,000 per year, or about $1,550 per year for each graphic arts operation. A socioeconomic impact analysis was performed by SJVUAPCD when they adopted nearly ident ical solvent cleaning requirements for graphic arts operations on September 20, 2007, and they concluded that compliance costs for the printing industry, as a percentage of net profits, were well below the level at which significant economic or employment im pacts would occur. Printing operations in Sacramento County are similar to those in SJVUAPCD, and Staff expects that the proposed amendments to Rule 450 will not si gnificantly impact employment or the economy in the District.

The amendments to Rule 466 are estimated to increase annual costs by a total of $489,000 per year, or about $130 per year for each affected business. These cost increases are relatively minor and are not expected to result in significant effects on employment or the economy in the District.

Range of Probable Costs of Rule Amendments: This is discussed under the "COST

IMPACT" section above.

Availability and Cost-Effectiveness of Alternatives to Rules:

The most fundamental alternative to the proposed rules is to not amend them. However, the District is required by Section 40914(b)(2) of the Health and Safety Code to include in its state attainment plan “all feasible measures” to reduce ozone precursors. The proposed standards have been demonstrated as feasible in the SCAQMD, and consequently, the District committed to them in the 2003 Triennial Report. This evaluation confirms that the proposed changes provide substantive, cost effective emission benefits. Many of them provide cost savings. If the proposed rules are not adopted, the District will not fulfill this state plan commitment. Furthermore, the VOC emissions reductions will not be achieved, which could require the District to implement

less cost effective measures for other sources in order to attain the federal 8-hour ozone

standard.

Emission Reduction Potential: The proposed amendments to the rules will achieve an emission reduction of at least 195.64 tons per year of VOCs in 2010 (See discussion under Emissions Impact).

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 41

Necessity of Adopting, Amending, or Repealing the Rules of Regulation to Attain
State and Federal Ambient Air Standards:

The proposed amendments to the solvent cleaning rules are necessary to comply with all feasible measures requirements and prov ide additional VOC emission reductions that contribute to the attainment of both the state and federal ozone standards, in Sacramento County and downwind areas.

INCREMENTAL COST EFFECTIVENESS ANALYSIS

Pursuant to Health and Safety Code Section 40920.6(a)(3), the District is required to perform incremental cost effectiveness analysis prior to adopting requirements for Best Available Retrofit Control Technology (BARCT) or a “feasible measure” requirement pursuant to HSC Section 40914. The District is required to identify one or more potential control options that achieve the emission reduction objective for the regulation. Staff evaluated the cost effectiveness of using alternative control options such as the use of air pollution control equipment, where feasible. Staff did not perform a cost effectiveness analysis where the use of air pollution control equipment is not feasible (e.g., wipe cleaning for equipment and machinery.) No other options could meet the

emission reduction commitments for these rules.

The incremental cost effectiveness analysis performed for this rule is based on the Discounted Cash Flow cost analysis method to compute the present value of the proposed rule’s costs over a 10-year period (the assumed equipment lifetime), using a 7.0% interest rate (based on a U.S. Treasury Security maturing in 10 years plus two percent.) The incremental cost effectiveness analysis was performed for the following:

1. Compliant materials (proposed control option); 2. Air pollution control equipment; and 3. Compliant materials and air pollution control equipment.

The incremental cost effectiveness was performed for the following control options:

1. Use of compliant materials vs. air pollution control equipment 2. Use of control equipment vs. air pollution control equipment and compliant

material. 3. Use of compliant materials vs. air pollution control equipment and compliant

material.

The following equation was used to calculate the incremental cost:



### ⎟ ⎟ ⎠ ⎞ ⎜ ⎜ ⎝ ⎛

− −

=

1 2 1 2 

### ) / ($ /

option option opetion option



### TER TER PV

PV

ton E IC

Where: IC = Incremental Cost ($) E = Emission reduction (tons)

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 42

PV option 2 

### = Present value of control costs for option 2 ($/yr)

PV option 1 

### = Present value of control costs for option 1 ($/yr)

TER option2 

### = Total emission reduction for option 2 over a 10-year period (tons)

TER option1 

### = Total emission reduction for option 1 over a 10-year period (tons)

Rule 450

As discussed earlier, cost increases are expected for the cleaning of blanket and roller washes, metering rollers and printing plates, other on-press components, and removable press components.

As stated earlier, incremental cost effectiveness analysis was performed for compliant materials only, air pollution control (APC) equipment only, and both compliant materials and APC equipment. This analysis assumes typi cal press room dimensions of 40’ W x 60’ L x 20’ H and 6 air changes occur per hour, thus requiring a blower with a flow rate with an airflow capacity of least 5,000 cubic feet per minute (CFM) The cost of APC equipment is based on actual cost data taken from the EPA Air Pollution Control Cost Manual, Sixth Edition. The costs of using a Calgon Carbon Corporation’s High Flow Ventsorb System carbon adsorption system with a flow rate of 6,000 CFM— to accommodate the typical printing facility airflow rate of 5,000 CFM— was used for these calculations. The High Flow Ventsorb System represents the lowest priced carbon adsorption system (according to the EPA cost manual) with sufficient airflow capacity. This cost analysis also accounted for all capital costs and annual costs of using a carbon adsorption system. Capital costs include installation costs, equipment costs, and labor costs, and annual costs include carbon replacement costs, electricity costs, labor costs, property taxes, insurance, overhead, and adminis trative costs. The tables listing the cost effectiveness and incremental costs of these control options are shown below.

Present Value Annualized Total Emission Cost
Control Option of Cost Cost Reduction Effectiveness
$ $/yr Tons/year $/ton $/lb
Compliant Material $2,867,214 $408,226 55.16 $7,400 $3.70
APC Equipment $39,068,293 $5, 562,446 53.74 $103,502 $51.75
Compliant & APC $33,336,134 $4,746,315 72.22 $65,719 $32.86

IC/E IC/E Incremental Comparisons ($/ton) ($/lb)
Compliant material vs. add on control equipment -$2,551,170 -$1,275
Compliant material vs. add on control equipment and compliant material $178,599 $89.30

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 43

Based on the above analysis, it is not cost effective to require the use of APC equipment instead of compliant material because APC equipment costs more and reduces less VOCs. Also, the incremental cost effectiveness of using both compliant material and APC equipment vs. only compliant material also significantly exceeds $18.05/lb.

Rules 451, 452, 454, 456, 463, 464, and 465

Compliance costs are expected to decrease for sources regulated by Rules 451 and 456. Sources regulated by Rules 452, 463, 464, and 465 are already in compliance with the VOC limits proposed. No incremental co st effectiveness analysis is necessary for

these rules.

Emission reductions will result from the proposed changes to Rule 454. However, incremental cost effectiveness analysis is not needed for these rules because there are no added compliance costs for this rule.

Rule 466

As stated earlier, incremental cost effectiveness analysis was performed for compliant materials only, air pollution control (APC) equipment only, and both compliant materials and APC equipment. Staff assumes the room dimensions and airflow requirements for a printing facility and a non-printing facility to be the same, since the 7/19/02 SCAQMD staff report for Rule 1171 states that the airflow requirement for a non-printing facility is approximately 5,000 CFM. Therefore, equipment, installation, and annual costs are assumed to be similar as well, and the costs computed for Rule 450 can be used here (only the annual emission reductions differ from that of Rule 450). The tables listing the cost effectiveness and incremental costs of these control options are shown below.

Present Value Annualized Total

Emission Cost
Control Option of Cost Cost Reduction Effectiveness
$ $/yr Tons/year $/ton $/lb
Compliant Material $3,437,559 $489,431 66.23 $7,390 $3.70
APC Equipment $405,861,794 $57,785,588 121.33 $476,255 $238.13
Compliant & APC $396,024,905 $56,385,037 130.94 $430,630 $215.32

IC/E IC/E Incremental Comparisons ($/ton) ($/lb)
Compliant material vs. add on control equipment $730,276 $365 Compliant material vs. add on control equipment and compliant material $606,699 $303



### Based on the above analysis, the cost effectiveness of using APC equipment or using

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 44

both APC equipment and compliant material significantly exceeds the most expensive control measure ever required by the District, $18.05 per pound.

OTHER FACTORS:

Technological Feasibility: The VOC limits proposed in the solvent cleaning rules are based on requirements adopted and implem ented by SCAQMD. Therefore, the proposed VOC limits are technologically feasible.

Enforceability: Reporting requirements and testing procedures have been included in the rules to increase enforceability, as required by EPA.

Public Acceptability: Similar requirements are cu rrently implemented in SCAQMD. The rules have a future compliance timeline to allow time for affected businesses to identify and purchase the appropriate complaint materials. Therefore, Staff expects these rules and other associated costs to be acceptable to the public.

PUBLIC COMMENTS

Staff held a public workshop to discuss the proposed amendments on April 28, 2008. A public notice was mailed to interested parties including all permitted stationary sources, printing and automotive repair shops identified through the yellow pages, and all persons who have requested to receive rulemaking notices. The notice was posted on the District website, and the draft rules and staff report were made available for public

review at that time.

Staff received several comments and questions at the workshop, as well as written comments from industry and CARB. All comments and responses are included in Appendix D.

ENVIRONMENTAL REVIEW AND COMPLIANCE

Staff finds that the proposed rules are exempt from the California Environmental Quality Act as an action by a regulatory agency for protection of the environment (Class 8 Categorical Exemption, Section 15308 State CEQA Guidelines) and because it can be seen with certainty that there is no possibi lity that the activity in question may have a significant adverse effect on the envir onment (Section 15061(b)(3), State CEQA Guidelines).

California Public Resources Code (Section 21159) requires an environmental analysis of the reasonably foreseeable methods of compliance. Compliance is expected to be achieved by the replacement of current cleaning solvents with compliant products. Compliant products may contain higher levels of exempt compounds, but these exempt compounds are generally less toxic than the VO C solvents they replace. The proposed

rules will not increase emissions and will not cause any other significant adverse effects on the environment; therefore Staff has conclu ded that no environmental impacts will be

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 45

caused by compliance with the proposed rules.

FINDINGS

The California Health and Safety Code, Division 26, Air Resources, require local Districts to comply with a rule adoption protocol as set forth in Section 40727 of the Code. This section has been revised through legislative mandate to contain six findings that the District must make when developing, amending, or repealing a rule. These findings, effective January 1, 1992, and their definitions are listed in the table below.

Rule 450

FINDING FINDING DETERMINATION

Authority: The District must find that a provision of law or of a state or federal regulation permits or requires the District to adopt, amend, or repeal the rule. The District is authorized to adopt rules and regulations by California Health and Safety Code, Sections 40001, 40702, 40716, 41010 and 41013. (CHSC Section 40727(b)(2))

Necessity: The District must find that the rulemaking demonstrates that a need exists for the rule, or for its amendment or repeal. Proposed amendments to Rule 450 are necessary in order to meet the Federal Clean Air Act Reasonably Available Control Technology requirements (Sections 182(b)(2) and 172(c)(1) (42 U.S.C. 7502 of the Federal Clean Air Act Amendments of 1990), 1994 Sacramento Area Regional Ozone Attainment Plan (CHSC Section 40913), the state’s

Best Available Retrofit Cont rol Technology requirements (CHSC Section 40919(a)(3)), an d “all feasible measures” requirement (CHSC Section 40914) for reducing volatile organic compound emissions from graphic arts operations. (CHSC Section 40727(b)(1)) Clarity: The District must find that the rule is written or displayed so that its meaning can be easily understo od by the persons directly affected by it. Staff has reviewed the proposed rule amendments and determined that they can be easily understood by the affected industry. In addition, the record contains no evidence that the persons dire ctly affected by the rule can not understand it. (CHSC Section 40727(b)(3)) Consistency: The rule is in harmony with, and not in conflict with or contradictory to, existing statutes, court decisions, or state or federal regulations. The proposed rule amendments do not conflict with and are not contradictory to, existing st atutes, court decisions, or state or federal regulations. (CHSC Section 40727(b)(4))

Non-Duplication: The District must find that either: 1) The rule does not impose the same requirements as an existing state or federal regulation; or 2) that the duplicative requirements are necessary or proper to execute the powers and duties granted to, and imposed upon the District. The proposed rule amendments do not duplicate any state laws or regulations, regarding the attainment and

maintenance of state and f ederal air quality standards. (CHSC Section 40727(b)(5))

Reference: The District must refer to any statute, court decision, or other provision of law that the District implements, interprets, or makes specific by adopting, amending or repealing the rule. CHSC Sections 40913, 40914 and 40919(a)(3), 41010; Sections 182(b)(2) and 172(c)(1) of the Federal Clean Air Act Amendments of 1990. (CHSC Section 40727(b)(6))

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 46

FINDING FINDING DETERMINATION Additional Informational Requirements (CHSC Section 40727.2): In complying with CHSC Section 40727.2, the District must identify all federal requirements and District rules that apply to the same equipment or source type as the proposed

rule or amendments. The discussion attached (Appendix A) contains a comparison of other requirements that apply to graphic arts operations. (CHSC Section 40727.2)



### Rule 451

FINDING FINDING DETERMINATION

Authority: The District must find that a provision of law or of a state or federal regulation permits or requires the District to adopt, amend, or repeal the rule. The District is authorized to adopt rules and regulations by California Health and Safety Code, Sections 40001, 40702, 40716, 41010 and 41013. (CHSC Section 40727(b)(2))

Necessity: The District must find that the rulemaking demonstrates that a need exists for the rule, or for its amendment or repeal. Proposed amendments to Rule 451 are necessary in order to meet the Federal Clean Air Act Reasonably Available Control Technology requirements (Sections 182(b)(2) and 172(c)(1) (42 U.S.C. 7502 of the Federal Clean Air Act Amendments of 1990), 1994 Sacramento Area Regional Ozone Attainment Plan (CHSC Section 40913), the state’s

Best Available Retrofit Cont rol Technology requirements (CHSC Section 40919(a)(3)), an d “all feasible measures” requirement (CHSC Section 40914) for reducing volatile organic compound emissions from surface coating of miscellaneous metal parts a nd products. (CHSC Section 40727(b)(1)) Clarity: The District must find that the rule is written or displayed so that its meaning can be easily understo od by the persons directly affected by it. Staff has reviewed the proposed rule amendments and determined that they can be easily understood by the affected industry. In addition, the record contains no evidence that the persons dire ctly affected by the rule can not understand it. (CHSC Section 40727(b)(3)) Consistency: The rule is in harmony with, and not in conflict with or contradictory to, existing statutes, court decisions, or state or federal regulations. The proposed rule amendments do not conflict with and are not contradictory to, existing st atutes, court decisions, or state or federal regulations. (CHSC Section 40727(b)(4))

Non-Duplication: The District must find that either: 1) The rule does not impose the same requirements as an existing state or federal regulation; or 2) that the duplicative requirements are necessary or proper to execute the powers and duties granted to, and imposed upon the District. The proposed rule amendments do not duplicate any state laws or regulations, regarding the attainment and

maintenance of state and f ederal air quality standards. (CHSC Section 40727(b)(5))

Reference: The District must refer to any statute, court decision, or other provision of law that the District implements, interprets, or makes specific by adopting, amending or repealing the rule. CHSC Sections 40913, 40914 and 40919(a)(3), 41010; Sections 182(b)(2) and 172(c)(1) of the Federal Clean Air Act Amendments of 1990. (CHSC Section 40727(b)(6))

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 47

FINDING FINDING DETERMINATION Additional Informational Requirements (CHSC Section 40727.2): In complying with CHSC Section 40727.2, the District must identify all federal requirements and District rules that apply to the same equipment or source type as the proposed

rule or amendments. The discussion attached (Appendix A) contains a comparison of other requirements that apply to surface coating of miscellaneous meta l parts and products. (CHSC Section 40727.2)



### Rule 452

FINDING FINDING DETERMINATION

Authority: The District must find that a provision of law or of a state or federal regulation permits or requires the District to adopt, amend, or repeal the rule. The District is authorized to adopt rules and regulations by California Health and Safety Code, Sections 40001, 40702, 40716, 41010 and 41013. (CHSC Section 40727(b)(2))

Necessity: The District must find that the rulemaking demonstrates that a need exists for the rule, or for its amendment or repeal. Proposed amendments to Rule 452 are necessary in order to meet the Federal Clean Air Act Reasonably Available Control Technology requirements (Sections 182(b)(2) and 172(c)(1) (42 U.S.C. 7502 of the Federal Clean Air Act Amendments of 1990), 1994 Sacramento Area Regional Ozone Attainment Plan (CHSC Section 40913), the state’s

Best Available Retrofit Cont rol Technology requirements (CHSC Section 40919(a)(3)), an d “all feasible measures” requirement (CHSC Section 40914) for reducing volatile organic compound emissions from can coating operations. (CHSC Section 40727(b)(1)) Clarity: The District must find that the rule is written or displayed so that its meaning can be easily understo od by the persons directly affected by it. Staff has reviewed the proposed rule amendments and determined that they can be easily understood by the affected industry. In addition, the record contains no evidence that the persons dire ctly affected by the rule can not understand it. (CHSC Section 40727(b)(3)) Consistency: The rule is in harmony with, and not in conflict with or contradictory to, existing statutes, court decisions, or state or federal regulations. The proposed rule amendments do not conflict with and are not contradictory to, existing st atutes, court decisions, or state or federal regulations. (CHSC Section 40727(b)(4))

Non-Duplication: The District must find that either: 1) The rule does not impose the same requirements as an existing state or federal regulation; or 2) that the duplicative requirements are necessary or proper to execute the powers and duties granted to, and imposed upon the District. The proposed rule amendments do not duplicate any state laws or regulations, regarding the attainment and

maintenance of state and f ederal air quality standards. (CHSC Section 40727(b)(5))

Reference: The District must refer to any statute, court decision, or other provision of law that the District implements, interprets, or makes specific by adopting, amending or repealing the rule. CHSC Sections 40913, 40914 and 40919(a)(3), 41010; Sections 182(b)(2) and 172(c)(1) of the Federal Clean Air Act Amendments of 1990. (CHSC Section 40727(b)(6))

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 48

FINDING FINDING DETERMINATION Additional Informational Requirements (CHSC Section 40727.2): In complying with CHSC Section 40727.2, the District must identify all federal requirements and District rules that apply to the same equipment or source type as the proposed

rule or amendments. The discussion attached (Appendix A) contains a comparison of other requirements that apply to can coating operations. (CHSC Section 40727.2)



### Rule 454

FINDING FINDING DETERMINATION

Authority: The District must find that a provision of law or of a state or federal regulation permits or requires the District to adopt, amend, or repeal the rule. The District is authorized to adopt rules and regulations by California Health and Safety Code, Sections 40001, 40702, 40716, 41010 and 41013. (CHSC Section 40727(b)(2))

Necessity: The District must find that the rulemaking demonstrates that a need exists for the rule, or for its amendment or repeal. Proposed amendments to Rule 454 are necessary in order to meet the Federal Clean Air Act Reasonably Available Control Technology requirements (Sections 182(b)(2) and 172(c)(1) (42 U.S.C. 7502 of the Federal Clean Air Act Amendments of 1990), 1994 Sacramento Area Regional Ozone Attainment Plan (CHSC Section 40913), the state’s

Best Available Retrofit Cont rol Technology requirements (CHSC Section 40919(a)(3)), an d “all feasible measures” requirement (CHSC Section 40914) for reducing volatile organic compound emissions from solvent cleaning operations. (CHSC Section 40727(b)(1)) Clarity: The District must find that the rule is written or displayed so that its meaning can be easily understo od by the persons directly affected by it. Staff has reviewed the proposed rule amendments and determined that they can be easily understood by the affected industry. In addition, the record contains no evidence that the persons dire ctly affected by the rule can not understand it. (CHSC Section 40727(b)(3)) Consistency: The rule is in harmony with, and not in conflict with or contradictory to, existing statutes, court decisions, or state or federal regulations. The proposed rule amendments do not conflict with and are not contradictory to, existing st atutes, court decisions, or state or federal regulations. (CHSC Section 40727(b)(4))

Non-Duplication: The District must find that either: 1) The rule does not impose the same requirements as an existing state or federal regulation; or 2) that the duplicative requirements are necessary or proper to execute the powers and duties granted to, and imposed upon the District. The proposed rule amendments do not duplicate any state laws or regulations, regarding the attainment and

maintenance of state and f ederal air quality standards. (CHSC Section 40727(b)(5))

Reference: The District must refer to any statute, court decision, or other provision of law that the District implements, interprets, or makes specific by adopting, amending or repealing the rule. CHSC Sections 40913, 40914 and 40919(a)(3), 41010; Sections 182(b)(2) and 172(c)(1) of the Federal Clean Air Act Amendments of 1990. (CHSC Section 40727(b)(6))

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 49

FINDING FINDING DETERMINATION Additional Informational Requirements (CHSC Section 40727.2): In complying with CHSC Section 40727.2, the District must identify all federal requirements and District rules that apply to the same equipment or source type as the proposed

rule or amendments. The discussion attached (Appendix A) contains a comparison of other requirements that apply to degreasing operations. (CHSC Section 40727.2)



### Rule 456

FINDING FINDING DETERMINATION

Authority: The District must find that a provision of law or of a state or federal regulation permits or requires the District to adopt, amend, or repeal the rule. The District is authorized to adopt rules and regulations by California Health and Safety Code, Sections 40001, 40702, 40716, 41010 and 41013. (CHSC Section 40727(b)(2))

Necessity: The District must find that the rulemaking demonstrates that a need exists for the rule, or for its amendment or repeal. Proposed amendments to Rule 456 are necessary in order to meet the Federal Clean Air Act Reasonably Available Control Technology requirements (Sections 182(b)(2) and 172(c)(1) (42 U.S.C. 7502 of the Federal Clean Air Act Amendments of 1990), 1994 Sacramento Area Regional Ozone Attainment Plan (CHSC Section 40913), the state’s

Best Available Retrofit Cont rol Technology requirements (CHSC Section 40919(a)(3)), an d “all feasible measures” requirement (CHSC Section 40914) for reducing volatile organic compound emissions from aerospace assembly and component coating operations. (CHSC Section 40727(b)(1)) Clarity: The District must find that the rule is written or displayed so that its meaning can be easily understo od by the persons directly affected by it. Staff has reviewed the proposed rule amendments and determined that they can be easily understood by the affected industry. In addition, the record contains no evidence that the persons dire ctly affected by the rule can not understand it. (CHSC Section 40727(b)(3)) Consistency: The rule is in harmony with, and not in conflict with or contradictory to, existing statutes, court decisions, or state or federal regulations. The proposed rule amendments do not conflict with and are not contradictory to, existing st atutes, court decisions, or state or federal regulations. (CHSC Section 40727(b)(4))

Non-Duplication: The District must find that either: 1) The rule does not impose the same requirements as an existing state or federal regulation; or 2) that the duplicative requirements are necessary or proper to execute the powers and duties granted to, and imposed upon the District. The proposed rule amendments do not duplicate any state laws or regulations, regarding the attainment and

maintenance of state and f ederal air quality standards. (CHSC Section 40727(b)(5))

Reference: The District must refer to any statute, court decision, or other provision of law that the District implements, interprets, or makes specific by adopting, amending or repealing the rule. CHSC Sections 40913, 40914 and 40919(a)(3), 41010; Sections 182(b)(2) and 172(c)(1) of the Federal Clean Air Act Amendments of 1990. (CHSC Section 40727(b)(6))

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 50

FINDING FINDING DETERMINATION Additional Informational Requirements (CHSC Section 40727.2): In complying with CHSC Section 40727.2, the District must identify all federal requirements and District rules that apply to the same equipment or source type as the proposed

rule or amendments. The discussion attached (Appendix A) contains a comparison of other requirements that apply to aerospace assembly and component coating operations. (CHSC Section 40727.2)



### Rule 463

FINDING FINDING DETERMINATION

Authority: The District must find that a provision of law or of a state or federal regulation permits or requires the District to adopt, amend, or repeal the rule. The District is authorized to adopt rules and regulations by California Health and Safety Code, Sections 40001, 40702, 40716, 41010 and 41013. (CHSC Section 40727(b)(2))

Necessity: The District must find that the rulemaking demonstrates that a need exists for the rule, or for its amendment or repeal. Proposed amendments to Rule 463 are necessary in order to meet the Federal Clean Air Act Reasonably Available Control Technology requirements (Sections 182(b)(2) and 172(c)(1) (42 U.S.C. 7502 of the Federal Clean Air Act Amendments of 1990), 1994 Sacramento Area Regional Ozone Attainment Plan (CHSC Section 40913), the state’s

Best Available Retrofit Cont rol Technology requirements (CHSC Section 40919(a)(3)), an d “all feasible measures” requirement (CHSC Section 40914) for reducing volatile organic compound emissions from wood products coating operations. (CHSC Section 40727(b)(1)) Clarity: The District must find that the rule is written or displayed so that its meaning can be easily understo od by the persons directly affected by it. Staff has reviewed the proposed rule amendments and determined that they can be easily understood by the affected industry. In addition, the record contains no evidence that the persons dire ctly affected by the rule can not understand it. (CHSC Section 40727(b)(3)) Consistency: The rule is in harmony with, and not in conflict with or contradictory to, existing statutes, court decisions, or state or federal regulations. The proposed rule amendments do not conflict with and are not contradictory to, existing st atutes, court decisions, or state or federal regulations. (CHSC Section 40727(b)(4))

Non-Duplication: The District must find that either: 1) The rule does not impose the same requirements as an existing state or federal regulation; or 2) that the duplicative requirements are necessary or proper to execute the powers and duties granted to, and imposed upon the District. The proposed rule amendments do not duplicate any state laws or regulations, regarding the attainment and

maintenance of state and f ederal air quality standards. (CHSC Section 40727(b)(5))

Reference: The District must refer to any statute, court decision, or other provision of law that the District implements, interprets, or makes specific by adopting, amending or repealing the rule. CHSC Sections 40913, 40914 and 40919(a)(3), 41010; Sections 182(b)(2) and 172(c)(1) of the Federal Clean Air Act Amendments of 1990. (CHSC Section 40727(b)(6))

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 51

FINDING FINDING DETERMINATION Additional Informational Requirements (CHSC Section 40727.2): In complying with CHSC Section 40727.2, the District must identify all federal requirements and District rules that apply to the same equipment or source type as the proposed

rule or amendments. The discussion attached (Appendix A) contains a comparison of other requirements that apply to wood products coating operations. (CHSC Section 40727.2)



### Rule 464

FINDING FINDING DETERMINATION

Authority: The District must find that a provision of law or of a state or federal regulation permits or requires the District to adopt, amend, or repeal the rule. The District is authorized to adopt rules and regulations by California Health and Safety Code, Sections 40001, 40702, 40716, 41010 and 41013. (CHSC Section 40727(b)(2))

Necessity: The District must find that the rulemaking demonstrates that a need exists for the rule, or for its amendment or repeal. Proposed amendments to Rule 464 are necessary in order to meet the Federal Clean Air Act Reasonably Available Control Technology requirements (Sections 182(b)(2) and 172(c)(1) (42 U.S.C. 7502 of the Federal Clean Air Act Amendments of 1990), 1994 Sacramento Area Regional Ozone Attainment Plan (CHSC Section 40913), the state’s

Best Available Retrofit Cont rol Technology requirements (CHSC Section 40919(a)(3)), an d “all feasible measures” requirement (CHSC Section 40914) for reducing volatile organic compound emissions from organic chemical manufacturing operations. (CHSC Section 40727(b)(1)) Clarity: The District must find that the rule is written or displayed so that its meaning can be easily understo od by the persons directly affected by it. Staff has reviewed the proposed rule amendments and determined that they can be easily understood by the affected industry. In addition, the record contains no evidence that the persons dire ctly affected by the rule can not understand it. (CHSC Section 40727(b)(3)) Consistency: The rule is in harmony with, and not in conflict with or contradictory to, existing statutes, court decisions, or state or federal regulations. The proposed rule amendments do not conflict with and are not contradictory to, existing st atutes, court decisions, or state or federal regulations. (CHSC Section 40727(b)(4))

Non-Duplication: The District must find that either: 1) The rule does not impose the same requirements as an existing state or federal regulation; or 2) that the duplicative requirements are necessary or proper to execute the powers and duties granted to, and imposed upon the District. The proposed rule amendments do not duplicate any state laws or regulations, regarding the attainment and

maintenance of state and f ederal air quality standards. (CHSC Section 40727(b)(5))

Reference: The District must refer to any statute, court decision, or other provision of law that the District implements, interprets, or makes specific by adopting, amending or repealing the rule. CHSC Sections 40913, 40914 and 40919(a)(3), 41010; Sections 182(b)(2) and 172(c)(1) of the Federal Clean Air Act Amendments of 1990. (CHSC Section 40727(b)(6))

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 52

FINDING FINDING DETERMINATION Additional Informational Requirements (CHSC Section 40727.2): In complying with CHSC Section 40727.2, the District must identify all federal requirements and District rules that apply to the same equipment or source type as the proposed

rule or amendments. The discussion attached (Appendix A) contains a comparison of other requirements that apply to organic chemical manufacturing operations. (CHSC Section 40727.2)



### Rule 465

FINDING FINDING DETERMINATION

Authority: The District must find that a provision of law or of a state or federal regulation permits or requires the District to adopt, amend, or repeal the rule. The District is authorized to adopt rules and regulations by California Health and Safety Code, Sections 40001, 40702, 40716, 41010 and 41013. (CHSC Section 40727(b)(2))

Necessity: The District must find that the rulemaking demonstrates that a need exists for the rule, or for its amendment or repeal. Proposed amendments to Rule 465 are necessary in order to meet the Federal Clean Air Act Reasonably Available Control Technology requirements (Sections 182(b)(2) and 172(c)(1) (42 U.S.C. 7502 of the Federal Clean Air Act Amendments of 1990), 1994 Sacramento Area Regional Ozone Attainment Plan (CHSC Section 40913), the state’s

Best Available Retrofit Cont rol Technology requirements (CHSC Section 40919(a)(3)), an d “all feasible measures” requirement (CHSC Section 40914) for reducing volatile organic compound emissions from polyester resin operations. (CHSC Section 40727(b)(1)) Clarity: The District must find that the rule is written or displayed so that its meaning can be easily understo od by the persons directly affected by it. Staff has reviewed the proposed rule amendments and determined that they can be easily understood by the affected industry. In addition, the record contains no evidence that the persons dire ctly affected by the rule can not understand it. (CHSC Section 40727(b)(3)) Consistency: The rule is in harmony with, and not in conflict with or contradictory to, existing statutes, court decisions, or state or federal regulations. The proposed rule amendments do not conflict with and are not contradictory to, existing st atutes, court decisions, or state or federal regulations. (CHSC Section 40727(b)(4))

Non-Duplication: The District must find that either: 1) The rule does not impose the same requirements as an existing state or federal regulation; or 2) that the duplicative requirements are necessary or proper to execute the powers and duties granted to, and imposed upon the District. The proposed rule amendments do not duplicate any state laws or regulations, regarding the attainment and

maintenance of state and f ederal air quality standards. (CHSC Section 40727(b)(5))

Reference: The District must refer to any statute, court decision, or other provision of law that the District implements, interprets, or makes specific by adopting, amending or repealing the rule. CHSC Sections 40913, 40914 and 40919(a)(3), 41010; Sections 182(b)(2) and 172(c)(1) of the Federal Clean Air Act Amendments of 1990. (CHSC Section 40727(b)(6))

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 53

FINDING FINDING DETERMINATION Additional Informational Requirements (CHSC Section 40727.2): In complying with CHSC Section 40727.2, the District must identify all federal requirements and District rules that apply to the same equipment or source type as the proposed

rule or amendments. The discussion attached (Appendix A) contains a comparison of other requirements that apply to polyester resin operations. (CHSC Section 40727.2)



### Rule 466

FINDING FINDING DETERMINATION

Authority: The District must find that a provision of law or of a state or federal regulation permits or requires the District to adopt, amend, or repeal the rule. The District is authorized to adopt rules and regulations by California Health and Safety Code, Sections 40001, 40702, 40716, 41010, and 41013. (CHSC Section 40727(b)(2))

Necessity: The District must find that the rulemaking demonstrates that a need exists for the rule, or for its amendment or repeal. It is necessary to adopt proposed Rule 466 in order to meet the Federal Clean Air Act Reasonably Available Control Technology requirements (Secti ons 182(b)(2) and 172(c)(1) (42 U.S.C. 7502 of the Federal Clean Air Act Amendments of 1990), 1994 Sacramento Area Regional Ozone Attainment Plan (CHSC Secti on 40913), the state’s Best Available Retrofit Control Technology requirements (CHSC Section 40919(a)(3)), and “all feasible measures” requirement (CHSC Section 40914) for reducing volatile organic compound emissions from solvent cleaning operations. (CHSC Section 40727(b)(1)) Clarity: The District must find that the rule is written or displayed so that its meaning can be easily understood by the persons directly affected by it. Staff has reviewed the rule and determined that it can be easily understood by the affected industry. In addition, the record contains no evidence that the persons directly affected by the rule can not understand it. (CHSC Section 40727(b)(3)) Consistency: The rule is in harmony with, and not in conflict with or contradictory to, existing statutes, court decisions, or state or federal regulations. The proposed rule does not conflict with and are not contradictory to, existing statut es, court decisions, or state or federal regulations. (CHSC Section 40727(b)(4))

Non-Duplication: The District must find that either: 1) The rule does not impose the same requirements as an existing state or federal regulation; or 2) that the duplicative requirements are necessary or proper to execute the powers and duties granted to, and imposed upon the District. The proposed rule does not dupl icate any state laws or regulations, regarding the attainment and maintenance of state and federal air quality standards. (CHSC Section 40727(b)(5))

Reference: The District must refer to any statute, court decision, or other provision of law that the District implements, interprets, or makes specific by adopting, amending or repealing the rule. CHSC Sections 40913, 40914 and 40919(a)(3), 41010; Sections 182(b)(2) and 172(c) (1) of the Federal Clean Air Act Amendments of 1990. (CHSC Section 40727(b)(6))

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 54

FINDING FINDING DETERMINATION Additional Informational Requirements (CHSC Section 40727.2): In complying with CHSC Section 40727.2, the District must identify all federal requirements and District rules that apply to the same equipment or source type as the proposed rule or amendments. The discussion attached (Appendix A) contains a comparison of other requirements that apply to solvent cleaning operations. (CHSC Section 40727.2)



### REFERENCES

1. South Coast Air Quality Management Distri ct, “Clean Air Solvent (CAS) Certification Program.” http://www.aqmd.gov/rules/cas/index.html

.

2. Institute for Research and Technical Assistance, “Assessment, Development, and Demonstration of Low-VOC Cleaning System s for South Coast Air Quality Management District Rule 1171.” August 2003.

3. South Coast Air Quality Management Dist rict, “Technology Assessment to Determine the Relationship of Solvent Vapor Pressure and VOC Mass Emissions.” April 10, 2002.

4. Air Resources Board, “New Method for Estimating Emissions from Thinning and Cleanup Solvents.” March 9, 2006.

5. Bay Area Air Quality Management District, “BACT/TBACT Workbook – Guidelines for Best Available Control Technology.” http://www.baaqmd.gov/pmt/bactworkbook/

6. South Coast Air Quality Management District, “Rule 1130, Graphic Arts Operations,” October 8, 1999.

7. South Coast Air Quality Management District, “Rule 1107, Coating of Metal Parts and Products,” January 6, 2006.

8. South Coast Air Quality Management District, “Rule 1125, Metal Container, Closure and Coil Coating Operations,” January 13, 1995.

9. South Coast Air Quality Management Distri ct, “Rule 1122, Solvent Degreasers,” October 1, 2004.

10. South Coast Air Quality Management District, “Rule 1124, Aerospace Assembly and Component Manufacturing Operations,” September 21, 2001.

11. South Coast Air Quality Management District, “Rule 1136, Wood Products Coatings,” June 14, 1996.

12. South Coast Air Quality Management District , “Rule 1162, Polyester Resin Operations,” July 8, 2005

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 55

13. South Coast Air Quality Management District, “Rule 1171, Solvent Cleaning Operations,” May 6, 2005.

14. South Coast Air Quality Management District, “Rule 1171, Solvent Cleaning Operations,” July 7, 2006.

15. South Coast Air Quality Management District, “Staff Report for Proposed Amended Rule 1122- Solvent Degreasers,” September 21, 2004.

16. South Coast Air Quality Management Distri ct, “Final Report for Technology Assessment for 2006 VOC Limit for Vapor Degreasers Under Rule 1122- Solvent Degreasers,” October 12, 2005.

17. South Coast Air Quality Management District, “Staff Report for Proposed Rule 1131- Food Product Manufacturing and Processing Operations,” August 23, 2000.

18. South Coast Air Quality Management District, “Rule 1131- Food Product Manufacturing and Processing Operations,” June 6, 2003.

19. South Coast Air Quality Management District, “Staff Report for Proposed Amended Rule 1171- Solvent Cleaning Operations,” September 27, 1999.

20. South Coast Air Quality Management District, “Staff Report for Proposed Amended Rule 1171- Solvent Cleaning Operations,” July 19, 2002.

21. South Coast Air Quality Management District, “Staff Report for Proposed Amended Rule 1171- Solvent Cleaning Operations,” November 2003.

22. South Coast Air Quality Management District, “Staff Report for Proposed Amended Rule 1171- Solvent Cleaning Operations,” April 19, 2005.

23. South Coast Air Quality Management District, “Staff Report for Proposed Amended Rule 1171- Solvent Cleaning Operations,” June 2006.

24. CARB Ozone SIP Planning Inventory, Version 1.06, Sacramento NAA (Rf#980), November 16, 2006.

25. EPA Air Pollution Control Cost Manual, Sixth Edition, January 2002.

26. Printing Industries Association/Graphic Arts Technical Foundation, “Assessment, Development, and Demonstration of Low-VOC Solvents for Cleaning of Lithographic Printing Ink Application Equipment,” March 2006.

27. University of Tennessee Center for Clean Products and Clean Technologies, “Compatibility Testing of Low-VOC Alternative Cleaning Solvents for Lithographic Printing Application,” April 2006.

### Staff Report Rules 450, 451, 452, 454, 456, 463, 464, 465, 466 August 25, 2008, Page 56

28. Institute for Research and Technical Assistance, “Assessment, Development, and Demonstration of Low-VOC Materials for Cleaning Ultraviolet and Electron Beam Curable Coatings and Adhesives,” May 2006.

29. Institute for Research and Technical Assistance, “Low-VOC, Low-Toxicity Clean up Solvents for Screen Printing: Safer Alternatives,” May 2006.

30. Institute for Research and Technical Assistance, “Assessment, Development, and Demonstration of Low-VOC Materials for Cleaning of Lithographic Printing Ink Application Equipment,” May 2006.

31. San Joaquin Valley Unified Air Pollution Control District, “Final Draft Staff Report for Rules 4603, 4604, 4605, 4606, 4607, 4612, 4653, 4661, 4662, 4663, and 4684,” August

2007.

32. United States Environmental Protection Agency, “Control Techniques Guidelines for Flexible Package Printing,” September 2006.

33. United States Environmental Protection Agency, “Control Techniques Guidelines for Offset Lithographic Printing and Letterpress Printing,” September 2006.

34. United States Environmental Protection Agency, “Control Techniques Guidelines for Metal Furniture Coatings,” September 2007.

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 57

Appendix A Rule Consistency Analysis

Proposed Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 will limit the VOC emissions from solvent cleaning activities. There are E PA standards such as Best Available Control Technology (BACT) and Lowest Achievable Emi ssion Rate (LAER) that apply to solvent cleaning. There are also National Emission Standards for regulating the emissions of Hazardous air pollutants from solvent cleaning operations. This regulation is 40 CFR Part 63 Subpart T – Halogenated Solvent Emissions from Solvent Cleaning. Proposed Rule 454 now prohibits the use of solvents regulated under 40 CFR Part 63 Subpart T in degreasing operations unless an airless/airtight cleaning system is used. The rule consistency matrices for the proposed rules are listed in the following tables A-1 through A-9.

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 58

Appendix A-1 40727.2 Matrix for Proposed Amendments to Rule 450, Graphic Arts Operations

Elements of Comparison Specific

Provisions Proposed Rule 450 BACT/LAER (*)

Exemptions Sixty pounds per month for actual VOC emissions or 175 pounds per month for potential emissions.

Gravure printing; business and personal printers; prepress operations; aerosol adhesives for screen printing; aerosol adhesives other than screen printing; stripping of cured inks, coatings, and adhesives; lithographic and letter press printing- metering rollers and printing plates

Fountain solutions for lower VOC if total offset lithographic printing operations emit less than or equal to 450 pounds per month of VOC

Heatset web offset lithographic printing presses or heatset web letterpress printing presses with potential to emit less than 25 tons per year of VOC prior to controls

Heatset web offset lithographic printing presses used for book printing or presses with maximum

web width of 22 inches or less

Flexible package printing presses with potential to emit less than 25 tons per year of VOC prior to

controls 10 pounds of VOCs per day. (Rule 202, NEW SOURCE REVIEW)

Averaging

Provisions For air pollution control equipment,

meet the control and collectionefficiency specified in the rule or lbsVOC/gal or grams of VOC/liter as applied. Compliance with

control/collection is done using source test methods specified below and the corresponding averaging period (typically average of three 40-minute runs.)

Units % Control or lbs-VOC/gal or grams of VOC/liter as applied. % Control or lbs-VOC/gal or grams of VOC/liter as applied.

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 59

Elements of Comparison Specific

Provisions Proposed Rule 450 BACT/LAER (*)

Emission

Reductions Meet the VOC limit s specified in Section 300 or install air pollution control equipment with overall control efficiency of 67%

Mandatory control equipment for heatset web offset lithographic printing, heatset web letterpress printing, and flexible package printing with overall control efficiencies ranging from 67% to 95%, depending on specific process and date of control equipment installation (see Sections 303 and 304 of the rule)` If cost effective, capture and

vent VOC to afterburner or carbon adsorption system

with ≥ 98.5% destruction/recovery device efficiency; or VOC outlet ≤ 10 ppmv. (*) Emission Limits

Compliance

alternatives Air Pollution Control Equipment Air Pollution Control Equipment

Operating

Parameters

Work Practice Requirements Closed Containers; Proper disposal of spent solvents. Closed containers, proper disposal of spent solvents.

Recordkeeping Records of VOC emissions and

usage Records of emissions and operating parameters. Records vary depending on the control technology. Monitoring/

Records

Frequency Daily and/or monthly. Records are to be kept for five years. Daily, monthly, and/or quarterly.

Test Methods Applicable test methods are specified under Section 502 of the

rule. Applicable EPA Methods 2, 2C, 18, 25, 25A, 204, 204A, 204B, 204C, 204D, 204E,

204F or ARB Method 432. Monitoring/ Testing

Frequency No testing frequency specified in the

rule. Frequency can be annual if air pollution control equipment is selected.

(*) BACT trigger level is based on District's Rule 202 – NEW SOURCE REVIEW. BACT limits are based on similar requirements adopted by other districts as BACT that are det ermined to be cost effective and technologically feasible. (**) Based on BACT adopted by the Bay Area Air Quality Managem ent District, BACT/TBACT Work book – Guidelines for Best Available Control Technology

.

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 60

Appendix A-2 40727.2 Matrix for Proposed Amendments to Rule 451, Surface Coating of Miscellaneous

Metal Parts and Products

Elements of Comparison Specific

Provisions Proposed Rule 451 BACT/LAER

Exemptions Usage less than 55 gal/yr

Coating of prefabricated architectural components or structures not coated in a shop environment; motor vehicles; aircraft or aerospace vehicles, components, and tooling; cans, coils, or magnetic wire; adhesives; magnetic data storage discs; safety-indicating coatings; stencil coatings; conformal coatings; hand lettering

Aerosol containers less than or equal

to 1 liter

Touch-up coating and repair coating operations; application of coatings producing a textured finish

Metal furniture for lower VOC if less than 3 tons per year from such operations a) touch-up coatings b) stencil coatings c) aerosol coating products d) emission limits not applicable if using approved emissions control system, operating

under an alternative emission control plan, or using less than twelve pounds per day for educational purposes at a training center.

Averaging

Provisions For air pollution control equipment,

meet the control and collectionefficiency specified in the rule or lbsVOC/gal or grams of VOC/liter as applied. For emission control equipment,

must reduce emissions to level that is equivalent or lower than limit specified in rule.

Units % Control or lbs-VOC/gal or grams of VOC/liter as applied. 1. Grams per liter less water and exempt compounds, or; 2. Pounds per gallon less water and exempt compounds.

Emission

Reductions Meet the emission limits specified in Section 300, or install emissions control equipment specified in Section 305 with overall system efficiency of ≥ 90%. Lower solvent content, higher transfer efficiency than required by applicable rules, and control equipment with overall capture/destruction efficiency of ≥
90% Emission Limits

Compliance

alternatives Air Pollution Control Equipment Air Pollution Control Equipment

Operating

Parameters

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 61

Elements of Comparison Specific

Provisions Proposed Rule 451 BACT/LAER

Work Practice Requirements Closed containers for disposal of

materials used for surface preparation, cleanup and coating removal; closed containers; cleanup to take place in an enclosed system; minimizing spills, conveyance of VOC materials using closed containers or pipes. Closed containers for disposal of

materials used for surface preparation, cleanup and coating removal; closed containers; cleanup to take place in an enclosed system.

Recordkeeping Recordkeeping of usage; recordkeeping for air pollution control equipment if used. Daily records of operations for most recent two years; method application and substrate type; amount of coating used including exempt amounts; VOC content of each coating; amount of surface prep and cleanup material used; vapor pressure of solvents, where applicable. Monitoring/

Records

Frequency Daily and/or monthly for coating usages. Records kept for a continuous five-year period. Daily records of coating usages

Test Methods Applicable test methods are specified

under Section 502 of the rule. Applicable EPA Methods 2 or 2C, 18, 24, 25, 25A, 204, 204A, 204B, 204C, 024D, 204E, 204F, ASTM D 4457-85 or ARB method 432, ASTM Standard D2832, ASTM D 4457-85, SCAQMD 318, and Sections 221, and 404 of the Rule. Monitoring/ Testing

Frequency No frequency specified in the rule

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 62

Appendix A-3 40727.2 Matrix for Proposed Amendments to Rule 452, Can Coating

Elements of Comparison Specific

Provisions Proposed Rule 452 BACT/LAER

Exemptions None a) touch-up coatings b) stencil coatings c) aerosol coating products d) emission limits not applicable if using approved emissions control system, operating

under an alternative emission control plan, or using less than twelve pounds per day for educational purposes at a training center. Averaging

Provisions For air pollution control equipment,

meet the control and collectionefficiency specified in the rule or lbsVOC/gal or grams of VOC/liter as applied. For emission control equipment,

must reduce emissions to level that is equivalent or lower than limit specified in rule.

Units % Control or lbs-VOC/gal or grams of VOC/liter as applied. 1. Grams per liter less water and exempt compounds, or; 2. Pounds per gallon less water and exempt compounds.

Emission

Reductions Meet the emission limits specified in Section 300, or install emissions control equipment specified in Section 302 with overall system efficiency of ≥ 90%. Lower solvent content, higher transfer efficiency than required by applicable rules, and control equipment with overall capture/destruction efficiency of ≥
90% Emission Limits

Compliance

alternatives Air Pollution Control Equipment Air Pollution Control Equipment

Operating

Parameters

Work Practice Requirements Closed containers for disposal of materials used for cleanup; closed containers; cleanup to take place in an enclosed system. Closed containers for disposal of

materials used for surface preparation, cleanup and coating removal; closed containers; cleanup to take place in an enclosed system. Recordkeeping Recordkeeping of usage; recordkeeping for air pollution control equipment if used. Daily records of operations for most recent two years; method application and substrate type; amount of coating used including exempt amounts; VOC content of each coating; amount of surface prep and cleanup material used; vapor pressure of solvents, where applicable. Monitoring/

Records

Frequency Daily and/or monthly for coating usages. Records kept for a continuous five-year period. Daily records of coating usages

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 63

Elements of Comparison Specific

Provisions Proposed Rule 452 BACT/LAER

Test Methods Applicable test methods are specified

under Section 501 of the rule. Applicable EPA Methods 2 or 2C, 18, 24, 25, 25A, 204, 204A, 204B, 204C, 024D, 204E, 204F, ASTM D 4457-85 or ARB method 432, ASTM Standard D2832, ASTM D 4457-85, SCAQMD 318, and Sections 221, and 404 of the Rule. Monitoring/ Testing

Frequency No frequency specified in the rule

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 64

Appendix A-4 40727.2 Matrix for Proposed Amendments to Rule 454, Solvent Degreasing

Elements of Comparison Specific

Provisions Proposed Rule 454 BACT/LAER

Exemptions Cleaning operations using cleanup materials containing less than 25 grams per liter VOCs; Cleanup operations specifically regulated under other prohibitory rules; open-top vapordegreasers; degreasing of highvoltage microwave vacuum tubes 10 lbs-VOC/day

Averaging

Provisions None None

Units Lbs-VOC/gal or grams of VOC/liter Lbs-VOC/gal or grams of VOC/liter

Emissions

Reduction Meet the VOC limits in Section 300 or use an airtight airless cleaning system Typical BACT for cold solvent cleaning tanks is using low volatility solvents, drain cover, and a freeboard height at least 6 inches. Other BACT used by SJVUAPCD is the use of Safety Kleen

Premium Solvent – California and a degreaser cover.

Use of air pollution control equipment

such as an afterburner with 99% destruction efficiency. Emissions

Limits

Compliance

Alternatives Use an airtight airless cleaning system Reduce VOC emissions by add on air pollution control equipment and meet certain control and collection efficiency (generally >95%).

Operating

Parameters Operating parameters for air pollution control equipment are specified in

Section 404 of the rule. Specific operating parameters will be specified in the permit to operate and will vary depending on the control technology selected.

Work Practice Requirements Operating requirements for degreasers; Storage and disposal requirements for solvents. Operating requirement s for degreasers; Storage and disposal requirements for

solvents.

Recordkeeping Recordkeeping of usage; recordkeeping for air pollution control equipment if used. Recordkeeping of usage and recordkeeping for air pollution control equipment. Monitoring/

Records

Frequency Daily for exemptions and monthly for sources subject to the rule. Records are to be kept for five years. Daily records for air pollution control equipment; Monthly records for solvent

usage.

Test Methods Applicable test methods are specified

under Section 502 of the rule. Applicable test methods are the same

as those listed in Rule 454. Monitoring/ Testing

Frequency No testing frequency is specified in the

rule. Initial testing to verify system control efficiency; Annual testing thereafter.

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 65

Appendix A-5 40727.2 Matrix for Proposed Amendments to Rule 456, Aerospace Assembly and Component Coating Operations

Elements of Comparison Specific

Provisions Proposed Rule

456 Aerospace
Control Technology

Guideline BACT/LAER Aerospace
NESHAP

Exemptions Less than 55 gal/yr, aerosol

containers <1 liter, surface prep/clean for space vehicles

and adhesive bonding; coatings applied via templates, stencil, stamp, or hand lettering; touch-up and repair coating operations and

use of detail guns; application of coatings containing fillers adversely affecting

atomization with HVLP spray guns; hand held spray containers

less than or equal to 8

ounces and total facility usage

less than or equal to 10 gal/yr Less than 200 gal/yr, aerosol containers, space vehicles, cleanup of R & D, lab testing,

rework operations Certain waterreduciblecoatings, handheld spray application,

essential use cleaning

solvents

Averaging

Provisions

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 66

Elements of Comparison Specific

Provisions Proposed Rule

456 Aerospace
Control Technology

Guideline BACT/LAER Aerospace

NESHAP

Units grams of VOC/liter (g/l) grams of VOC/liter (g/l)

Surface prep and cleanup Cleaning/surface prep: VOC

content limit of 200 g/l; spray gun cleaning:

VOC content limit of 25 g/l 80% aqueous

solvent or VOC with vapor pressure less than or equal to

45 millimeters of mercury (mm Hg) at 20° C, or enclosed gun

cleaner Use of solvents

less than 45 mm Hg at 20° C, or enclosed gun

cleaner

Stripping VOC content limit of 300 g/l HAP strippers limited to 26 gal commercial, 50 gal military per

year Emissions

Limits

Compliance

Alternatives 85% overall system efficiency. VOC emissions capture and

control equipment efficiency of at least 81% by weight Carbon absorber,incineration, Hitransfer efficiency equipment to

HVLP or electrostatic, spray booth vented to dry particle filter,

waterwash hiefficiency particulate filter, stage II or III, particulate filter, capture and
control of 81%

Operating

Parameters

Work Practice Requirements All containers

closed when not

in use. VOC

content available

for all materials. All containers

closed when not

in use. Label all

materials for

VOC content. Use of closed containers, other housekeeping

measures

Monitoring/

Records Recordkeeping List of materials

with VOC
contents, as applied, method of application, usage amounts, monitoring VOC content as applied, coating

usage, aqueousand semiaqueous handwipe cleaning

solvents- list Continuous monitoring for pressure drop at filter unit. Name,

vapor pressure, and

documentation

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 67

Elements of Comparison Specific

Provisions Proposed Rule

456 Aerospace
Control Technology

Guideline BACT/LAER Aerospace

NESHAP

parameters for

control equipment materials with water contents,

vapor pressurecompliant handwipe cleaning

solvents- list cleaning

solvents and

vapor pressures or, for blended solvents, VOC composite vapor

pressures,exempt handwipe cleaning

processes, monitoring parameters for

control equipment for all HAP,

solvents.

Records of leaks from gun

cleaners. VOC

content of each VOC coating. Name, volume,

and HAP content

of all chemical strippers. Name,type of nonchemical equipment.

Frequency Monthly for all;daily for noncompliant;

records are to be kept for five

years On annual basis Monthly for noncompliant,

semi-annual for compliant coatings.

Test Methods Applicable test

methods are specified under

Section 502 of

the rule. VOC content:

EPA Method 24

Control Equipment: EPA method 18, 25,

and/or 25A Filtration Efficiency; Method 139,

HAP and VOC

content: Method

24

Carbon Absorption:

Method 18

Gas Analysis:

Method 3 Monitoring/ Testing

Frequency As needed As needed As needed

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 68

Appendix A-6 40727.2 Matrix for Proposed Amendments to Rule 463, Wood Products Coatings

Elements of Comparison Specific

Provisions Proposed Rule 463 BACT/LAER

Exemptions Usage less than 55 gal/yr; woodproducts coatings sold in nonrefillable aerosol containers; coating operations for the purpose of manufacturing a finished wood panel

for attachment to inside walls of buildings; coating of architectural components or structures not coated in a shop environment a) touch-up coatings b) stencil coatings c) aerosol coating products d) emission limits not applicable if using approved emissions control system, operating

under an alternative emission control plan, or using less than twelve pounds per day for educational purposes at a training center. Averaging

Provisions Rolling 30-day averaging for a maximum of 20 gallons per year of historical reproduction coatings For emission control equipment,

must reduce emissions to level that is equivalent or lower than limit specified in rule.

Units % Control or lbs-VOC/gal or grams of VOC/liter as applied. 3. Grams per liter less water and exempt compounds, or; 4. Pounds per gallon less water and exempt compounds.

Emission

Reductions Meet the emission limits specified in Sections 300, or install emissions control equipment specified in

Section 305 Lower solvent content, higher transfer efficiency than required by applicable rules, and control equipment with overall capture/destruction efficiency of ≥
90% Emission Limits

Compliance

alternatives Air Pollution Control Equipment with equivalent or greater emission

reduction than would result from compliance with VOC limits Air Pollution Control Equipment

Operating

Parameters

Work Practice Requirements Closed containers for disposal of

materials used for surface preparation, cleanup and coating removal; closed containers; cleanup to take place in an enclosed system. Closed containers for disposal of

materials used for surface preparation, cleanup and coating removal; closed containers; cleanup to take place in an enclosed system. Recordkeeping Recordkeeping of usage; recordkeeping for air pollution control equipment if used. Daily records of operations for most recent two years; method application and substrate type; amount of coating used including exempt amounts; VOC content of each coating; amount of surface prep and cleanup material used; vapor pressure of solvents, where applicable. Monitoring/

Records

Frequency Daily and/or monthly for coating usages. Records kept for a continuous five-year period. Daily records of coating usages

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 69

Elements of Comparison Specific

Provisions Proposed Rule 463 BACT/LAER

Test Methods Applicable test methods are specified

under Section 503 of the rule. Applicable EPA Methods 2 or 2C, 18, 24, 25, 25A, 204, 204A, 204B, 204C, 024D, 204E, 204F, ASTM D 4457-85 or ARB method 432, ASTM Standard D2832, ASTM D 4457-85, SCAQMD 318, and Sections 221, and 404 of the Rule. Monitoring/ Testing

Frequency No frequency specified in the rule

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 70

Appendix A-7

40727.2 Matrix for Proposed Amendments to Rule 464, Organic Chemical Manufacturing Operations

Elements of Comparison Specific

Provisions Proposed Rule 464 BACT/LAER

Exemptions Equipment or operations with VOC emissions less than or equal to 15 pounds per day; laboratory equipment solvent cleaning; solvent cleaning regulated by FDA with less than or equal to 15 pounds per day

of VOC emissions

Averaging

Provisions

Units

Emissions

Reduction 90% control efficiency for VOC emissions exceeding 15 pounds per day Double bed type carbon adsorber (estimated control efficiency of 97%) Emissions Limits

Compliance

Alternatives 90% overall control efficiency.

Operating

Parameters

Work Practice Requirements

Recordkeeping Daily recordkeeping is required for exempt equipment or operations emitting 15 pounds or less of VOCs per day. Daily recordkeeping is also required for cleanup solvent usage. Records are also required for

source test results. Monitoring/Records

Frequency Daily or annual (see above); records are to be kept for five years

Test Methods Applicable test methods are specified under Section 502 of the

rule. Monitoring/Testing

Frequency Initial/annual as required by the

APCO

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 71

Appendix A-8 40727.2 Matrix for Proposed Amendments to Rule 465, Polyester Resin Operations

Elements of Comparison Specific

Provisions Proposed Rule 465 BACT/LAER

Exemptions Polyester resin material usage less than 20 gallons per month 10 lbs-VOC/day

Averaging

Provisions None

Units Lbs-VOC/gal or grams of VOC/liter Lbs-VOC/gal or grams of VOC/liter

Emissions

Reduction Meet the VOC limits in Sections 301 and 303 or install air pollution control equipment If cost effective, vent to an afterburner ( ≥ 0.3 sec. retention time at ≥ 1400 o F) or an activated carbon adsorption system ( ≥ 6 ppm at outlet) (*) Emissions Limits

Compliance

Alternatives 90% overall efficiency Reduce VOC emissions by add on air pollution control equipment and meet certain control and collection efficiency (generally >95%).

Operating

Parameters Operating parameters for air pollution control equipment are specified in Section 405 of the rule. Store solvents in closed containers; Use of rags to clean parts and use of a rag washing machine with solvent reclamation system; Use of enclosed cleaning system.

Work Practice Requirements Application equipment requirements; Storage and disposal requirements; surface preparation and cleanup requirements. Application equipment requirements; Storage and disposal requirements; surface preparation and cleanup requirements.

Recordkeeping Recordkeeping of usage; recordkeeping for air pollution control equipment if installed. Recordkeeping of usage and recordkeeping for air pollution control equipment. Monitoring/Records

Frequency Daily for exemptions and monthly for sources subject to the rule. Records are to be kept for five

years. Daily records for air pollution control equipment; Monthly records for solvent

usage.

Test Methods Applicable test methods are specified under Section 502 of the

rule. Applicable test methods are the same as

those listed in Rule 465. Monitoring/Testing

Frequency No testing frequency is specified in the rule. However, source testing Will be required for initial compliance verification if air pollution control equipment is installed Testing frequency thereafter will be specified based on

need. Initial testing to verify system control efficiency; Annual testing thereafter.

(*) Based on BACT adopted by the Bay Area Air Quality Managem ent District, BACT/TBACT Work book – Guidelines for Best Available Control Technology

.

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 72

Appendix A-9 40727.2 Matrix for Proposed Amendments to Rule 466, Solvent Cleaning

Elements of Comparison Specific

Provisions Proposed Rule 466 BACT/LAER

Exemptions Cleaning operations using cleanup materials containing less than 25 grams per liter VOCs; Cleanup operations specifically regulated under other prohibitory rules; Other exemptions specific to District are specified in Section 110 of the rule. 10 lbs-VOC/day

Averaging

Provisions None None

Units Lbs-VOC/gal or grams of VOC/liter Lbs-VOC/gal or grams of VOC/liter

Emissions

Reduction Meet the VOC limits in Section 300 or install air pollution control equipment Use of solvents for general cleanup with VOC limit less than 50 grams per liter; Use of air pollution control device such as after burner, carbon adsorption system; use of exempt solvent such as acetone. Emissions Limits

Compliance

Alternatives 95% control efficiency and 90% collection efficiency, and emissions must not be greater than would have resulted from compliance with applicable VOC limits Reduce VOC emissions by add on air pollution control equipment and meet certain control and collection efficiency (generally >95%).

Operating

Parameters Operating parameters for air pollution control equipment are specified in Section 405 of the rule. Store solvents in closed containers; Use of rags to clean parts and use of a rag washing machine with solvent reclamation system; Use of enclosed cleaning system.

Work Practice Requirements Application equipment requirements; Storage and disposal requirements; surface preparation and cleanup requirements. Application equipment requirements; Storage and disposal requirements; surface preparation and cleanup requirements.

Recordkeeping Recordkeeping of usage; recordkeeping for air pollution control equipment if installed. Recordkeeping of usage and recordkeeping for air pollution control equipment. Monitoring/Records

Frequency Daily for exemptions and monthly for sources subject to the rule. Records are to be kept for five

years. Daily records for air pollution control equipment; Monthly records for solvent

usage.

Monitoring/Testing Test Methods Applicable test methods are specified under Section 502 of the

rule. Applicable test methods are the same as

those listed in Rule 466.

### Appendix A Rule Consistency Matrices Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 73

Elements of Comparison Specific

Provisions Proposed Rule 466 BACT/LAER

Frequency No testing frequency is specified in the rule. However, source testing Will be required for initial compliance verification if air pollution control equipment is installed Testing frequency thereafter will be specified based on

need. Initial testing to verify system control efficiency; Annual testing thereafter.

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 74

Appendix B

Summary of Changes

Rule 450, Graphic Arts Operations

Existing
Section

Number New
Section

Number Proposed Change

101-102 Same Updated references to renumbered sections. 110.1 Same Removed paragraph (a) that is no longer applicable because it has expired. 110.2 NA Removed this section because it has expired.

110.3-

110.6 110.2-

110.5 Sections renumbered.

110.7 110.6 For clarification, revised the language to specify that this exemption is applicable to aerosol adhesives used by graphic arts operations “other than screen printing.” Consistent with original intent of this section as documented in the staff report for the 3/23/00 amendment of Rule 450.

Added requirement that aerosol adhesiv es that are exempt from Rule 450 under this section shall comply with the limits of Rule 460, Adhesives and Sealants (consistent with new section number 110.5). NA 110.7 Added an exemption for materials used to strip cured inks, cured coatings, or cured adhesives, consistent with SCAQMD Rule 1171. This exemption was already implied in the definition of Solvent Cleaning, but this new

section has been added for clarification. NA 110.8 Added an exemption from the requirements of Sections 302.2, 501.3(b)(2), and 501.3(b)(5) for presses that use solvents containing 100 g/l VOC or less to clean metering rollers and printing plates. The reason for this exemption is that it is not necessary to restrict the usage of such solvents to 15% of the usage of blanket and roller washes if such solvents meet VOC limits as stringent as those for blanket and roller washes. NA 110.9 Added an exemption from the future requirements of Section 301.2 for fountain solutions used in an offset lithographic printing operation with actual emissions less than or equal to 450 pounds of VOC per month. This exemption fulfills the recommendations specified in the 2006 EPA Control Techniques Guidelines for Lithographic and Letterpress Printing. NA 110.10 Added an exemption from the requirements of Section 303.1 for heatset web offset lithographic presses and heatset web letterpress presses with potential to emit from the dryer less than 25 tons of VOC per year, prior to controls. This exemption fulfills the recommendations specified in the 2006 EPA Control Techniques Guidelines for Lithographic and Letterpress Printing.

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 75

Existing
Section

Number New
Section

Number Proposed Change

Added an exemption from the requirements of Section 303.1 for heatset web offset lithographic presses and heatset web letterpress presses used for book printing and for presses with maximum web width of 22 inches or less. This exemption fulfills the recommendations specified in the 2006 EPA Control Techniques Guidelines for Lithographic and Letterpress Printing.

Added rule language clarifying that if actual emissions prior to control equipment are at least 25 tons per year of VOC per rolling 12-month period, then that unit must comply with Section 303.1 and cannot use the exemptions in this section. This is a “once in, always in” requirement. NA 110.11 Added an exemption from the requirements of Section 303.2 for inks, coatings, and adhesives used in a flexible package printing press with potential to emit from the dryer less than 25 tons of VOC per year, prior to controls. This exemption fulfills the recommendations specified in the 2006 EPA Control Techniques Guidelines for Lithographic and Letterpress Printing.

Added rule language clarifying that if actual emissions prior to control equipment are at least 25 tons per year of VOC per rolling 12-month period, then that unit must comply with Section 303.1 and cannot use the exemption in this section. This is a “once in, always in” requirement. NA 210 For clarification, added a definition for cured ink, cured coating, or cured
adhesive. This definition is consistent with SCAQMD Rule 1171.

210 211 Section renumbered.

NA 212 Added a definition for “electron beam ink.” This definition is the same as
the definition used in SCAQMD Rule 1171.

211-217 213-219 Sections renumbered. 218 220 Corrected grammatical error.

219-226 221-228 Sections renumbered. 227 NA Removed the definition for “Lithographic and Letter Press Printing, Other Cleaning.” For clarification, references in the rule to “Other Cleaning” have been replaced with “cleaning of metering rollers and printing plates,”

consistent with this former definition.

228-231 229-232 Sections renumbered. 232 233 Clarified that metering rollers transfer and meter fountain solution, not just

water. NA 234 Added a definition for “Newsprint.” This definition is the same as the
definition used in SCAQMD Rule 1171.

233-236 235-238 Sections renumbered. NA 239 Added a definition for “Other On-Press Component.” This definition is the

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 76

Existing
Section

Number New
Section

Number Proposed Change

same as the definition of “On-Press Component” used in SCAQMD Rule 1171, but excludes blankets, rollers, metering rollers, and printing plates,

which have different current limits.

237 240 Sections renumbered.

NA 241 Added a definition for “Potential to Emit.” This definition is the same as the

definition used in Rule 202 – NEW SOURCE REVIEW.

238-242 242-246 Sections renumbered. NA 247 Added a definition for “Removable Press Component.” This definition is
the same as the definition used in SCAQMD Rule 1171.

243-248 248-253 Sections renumbered. NA 254 For clarification, defined “Stripping” as the removal of cured inks, cured coatings, or cured adhesives, consistent with SCAQMD Rule 1171.

249-259 255-265 Sections renumbered. 301 Same Removed from the tables the limits that have expired. 301.2 Same Revised the table to include more subcategories for chilled and non-chilled fountain solutions, and include more stringent VOC limits. The future limits fulfill the recommendations specified in the 2006 EPA Control Techniques Guidelines for Lithographic and Letterpress Printing. NA 301.4 Added a section prohibiting the use of fountain solutions containing alcohol on coldest web offset lithographic presses, consistent with the recommendations specified in the 2006 EPA Control Techniques Guidelines for Lithographic and Letterpress Printing. 302.1 Same Revised the text to clarify that composite partial vapor pressure standards will no longer be in effect after new, more stringent VOC content limits take

effect.

Revised the table to include more stringent VOC limits for cleaning
materials. The future limits are consistent with SCAQMD Rule 1171. Most new limits will take effect one year after the date of adoption; however, the new limits for the following categories have been delayed until 1/1/2011 to allow sufficient time for successful implementation in
SCAQMD first:

• Blanket and roller washes, cleaning of metering rollers and printing plates, and cleaning of other on-press components used in lithographic and letter press printing on substrates other than newsprint;

• Screen printing; and

• Ultraviolet/electron beam inks (inter im limit to take effect one year after date of adoption; final limit to take effect 1/1/2011).

Divided Lithographic and Letter Press Printing into two substrate groups (Newsprint, and Substrates other than Newsprint) to allow for different

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 77

Existing
Section

Number New
Section

Number Proposed Change

effective dates, consistent with SCAQMD Rule 1171.

Eliminated Lithographic and Letter Press Printing, Other Cleaning, and replaced with Metering Rollers and Printing Plates, consistent with former

definition.

Added new categories for Other On-Press Components and Removable Press Components, previously in cluded under General cleaning, for clarification. These categories will ultimately be subject to different limits. 302.2 Same Updated text to reflect the elimination of the definition of “Other Cleaning”, and replaced with “Cleaning of Metering Rollers and Printing Plates,” consistent with previous definition. Added a sunset date for this section so that it expires on 1/1/2011. After that date, the limits for cleaning metering rollers and printing plates will be at least as stringent as the limits for Blanket and Roller Washes; therefore, restricting the monthly usage of these cleaning materials to 15% will no longer be necessary. Added reference to exemption of Section 110.8. NA 303 Added requirements for mandatory control equipment for heatset web offset lithographic printing, heatset web letterpress printing, and flexible package printing. The revised emissions control equipment requirements are specified in new Sections 303.1—303.3 and are effective on the date of adoption.

Added a section providing an alternative to compliance with the overall system efficiency requirements specified in Section 303.1. In lieu of complying with the overall efficiency requirements, sources are required to use emissions control equipment with mass outlet concentration no greater than 20 ppmv as hexane on a dry basis.

The above requirements fulfill the recommendations specified in the 2006 EPA Control Techniques Guidelines. 303 304 Updated to reflect renumbered section, and clarified that this section applies to alternative control equipment. The current rule specifies separate efficiency level requirements for the control device and emission collection. The proposed rule specifies a combined overall system efficiency requirement rather than separate capture and control efficiency requirements. 402.4 Same Revised so that sellers will not be required to display composite partial pressure after 1/1/2011, because after this date, there will no longer be any standards for composite partial pressure in effect. 403 Same Updated ASTM method numbers to the most current versions.

407 406 Removed the reference to deleted section 110.2.

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 78

Existing
Section

Number New
Section

Number Proposed Change

NA 408 Added section specifying calculation method for determining overall system efficiency of emissions control equipment, consistent with the method

stated in other District rules. 501.1 Same Removed the reference to deleted section 110.2. Updated references to

renumbered sections. 501.3 Same Updated references to renumbered sections. Added a requirement to paragraph (b)(1) to differentiate between materials used for printing on newsprint and materials used for printing on other substrates until 1/1/2011 (when the standards will be the same for all substrates). Clarified that presses exempt pursuant to Section 110.8 will not be required to maintain separate usage records for materials used for printing on newsprint and non-newsprint substrates.

Updated text in paragraph (b)(4) to replace “Lithographic and Letter Press Printing, Other Cleaning” with “metering rollers and printing plates,” consistent with former definition. Added a sunset date for this paragraph so that it expires on 1/1/2011. Added reference to exemption of Section

110.8. 502 Same Updated ASTM method numbers to the most current, EPA-approved versions. Updated references to renumbered sections. Corrected typographical errors. NA 502.9 To clarify enforceability, added paragraph stating that where multiple test methods are specified, a violation established by any one of the test

methods constitutes a violation of the rule.

Rule 451, Surface Coating of Miscellaneous Metal Parts and Products

Existing
Section

Number New
Section

Number Proposed Change

110.1 110 Section renumbered, and updated to reflect new paragraphs added to

section 305. 110.2 NA Section deleted. The 200 gallon/year exemption for aluminum coatings on window and door frames is no longer necessary. Records indicate that the general 55 gallon/year exemption is sufficient for applicable District sources, and is consistent with the EPA Region IX “Little Bluebook.” 110.3 NA Section deleted. The 200 gallon/year exemption for pretreatment wash primer is no longer necessary. Records indicate that the general 55 gallon/year exemption is sufficient fo r applicable District sources, and is consistent with the EPA Region IX “Little Bluebook.” 111 Same Moved the exemptions in Sections 111.6, 111.7, 111.8, and 111.10 into the

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 79

Existing
Section

Number New
Section

Number Proposed Change

new Section 112. Clarified that the conformal coatings are regulated under Rule 456- Aerospace Assembly and Component Coating Operations.

Removed rule language requiring operations and coatings exempted under the remaining exemptions in this section to comply with Section 501. The remaining exemptions pertain to operations and coatings subject to other District rules. Therefore, Section 501 in the other District rules should apply to such operations and coatings, rather than Section 501 under Rule

451. NA 112 Moved the exemptions in Sections 111.6, 111.7, 111.8, and 111.10 into this new section in order to require these operations and coatings to comply with the storage, disposal, and recordkeeping requirements.

Clarified that only coatings applied exclusively by hand lettering are exempt.

112-113 113-114 Sections renumbered. NA 115 Added an exemption for coatings on metal furniture. Such coating operations emitting less than 3 tons of VOC per 12-month rolling period are subject to the requirements of Section 301 (pertaining to miscellaneous metal parts and products coatings) rather than Section 302 (pertaining to metal furniture coatings). This exemption is consistent with the recommendations in the 2007 EPA Control Techniques Guidelines. NA 216 Added a definition for “electrostatic spray.” This definition is the same as the definition used in Shasta County AQMD Rule 3:13- Polyester Resin Operations.

216-227 217-228 Sections renumbered.

NA 229 Added a definition for “metal furniture.” This definition is consistent with the definition specified in the 2007 CTG for Metal Furniture Coatings.

228-229 230-231 Sections renumbered. NA 232 Added a definition for “multi-component coating.” This definition is consistent with the definition used in SCAQMD Rule 1107- Coating of

Metal Parts and Products. 230 233 Updated to reflect the new paragraphs added to section 305.

231 234 Section renumbered.

232-246 235-249 Sections renumbered. 301 Same Removed the expired VOC limits from the table. Clarified that the VOC content limits apply to materials “as applied.” NA 302 Established separate VOC limits for metal furniture coating operations emitting greater than or equal to 3 tons of VOC per 12-month rolling period from such operations, to be consistent with the recommendations specified in the 2007 CTG for Metal Furniture Coatings. Metal furniture coating operations emitting less than 3 tons of VOC per 12-month rolling period

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 80

Existing
Section

Number New
Section

Number Proposed Change

remain subject to Section 301. 302 303 Removed the past effective date. 303.9 304.8 Section renumbered to correct previous error in numbering.

304 305 Added a sunset date for the current standard for solvents used in the cleanup of application equipment in miscellaneous metal parts and products coating operations, and lowered the VOC limit to 25 g/l. Added a sunset date for the provision that allows application equipment to be cleaned in an enclosed gun cleaner in lieu of complying with the VOC limit. Added a sunset date for the exception for electrostatic spray guns. Changes are consistent with SCAQMD Rule 1171- Solvent Cleaning Operations, in (c)(1)(B)(i).

Added a sunset date for the provision that allows the soaking of spray gun nozzles in solvents without a limit on VOC content. After the sunset date, spray gun nozzles are subject to the same requirements as other application equipment, consistent with SCAQMD Rule 1171.

Added a sunset date for the current standard for solvents used in product cleaning or surface preparation, and lowered the VOC limit to 25 g/l. This limit is consistent with SCAQMD Rule 1171- Solvent Cleaning Operations, in (c)(1)(A)(i).

Added additional work practice requirements for use of closed containers for disposal of cloth, paper or sponges used for coating application; minimizing spillage of VOC-containing materials; and for conveyance of VOC-containing materials using closed containers or pipes. These requirements are be consistent with the 2007 CTG for Metal Furniture Coatings and the 2008 EPA Draft CTG for Miscellaneous Metal and Plastic Parts Coatings (dated July 3. 2008). 305 306 Updated to reflect the new paragraphs added to section 305. Increased the required overall emissions control efficiency from 85% to 90%,

consistent with the recommendations in the 2007 CTG for Metal Furniture Coatings 401 Same Removed the past effective date and updated to reflect new paragraphs

added to section 305. 405 Same Corrected previous typographical error in equation for calculating control efficiency. 406 Same Corrected previous typographical errors in text and in equation for calculating overall system efficiency. 407 Same Updated to reflect the new paragraphs added to section 305. 501 Same Updated to include the new exemption Section 112. As discussed earlier, several exemptions in Section 111 in the current rule have been moved

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 81

Existing
Section

Number New
Section

Number Proposed Change

into new Section 112 in order to require such operations and coatings to comply with the rule requirements for storage, disposal, and recordkeeping (this section). 501.1 Same Corrected typographical error and updated to reflect the new paragraphs

added to section 305. 501.3 Same Updated to reflect the new paragraphs added to section 305. 501.5 Same Added a sunset date for the current requirement for duration of records. Revised the requirement for duration of records to five years. This is

consistent with other District rules. 502 Same Updated ASTM method numbers to the most current versions. 502.3 Same Updated to incorporate most recent U.S. EPA guidelines on determining capture efficiency. NA 502.7 To clarify enforceability, added paragraph stating that where multiple test methods are specified, a violation established by any one of the test

methods constitutes a violation of the rule.

Rule 452, Can Coating

Existing
Section

Number New
Section

Number Proposed Change

NA 102 Added an applicability section to this rule, consistent with other District

rules. NA 103 Added a severability section to this rule, consistent with other District rules. NA 203 Added a definition for “dip coat.” This definition is the same as the

definition used in other District rules. NA 204 Added a definition for “electrostatic spray.” This definition is the same as the definition used in Shasta County AQMD Rule 3:13- Polyester Resin Operations.

203-205 205-207 Sections renumbered.

NA 208 Added a definition for “flow coat.” This definition is the same as the

definition used in other District rules. NA 209 Added a definition for “food/beverage can.” This definition is the same as the definition used in SCAQMD Rule 1125- Metal Container, Closure, and Coil Coating Operations. NA 210 Added a definition for “hand application equipment.” This definition is the

same as the definition used in other District rules. NA 211 Added a definition for “high-volume low-pressure application equipment.”

This definition is the same as the definition used in other District rules.

206-207 212-213 Sections renumbered. NA 214 Added a definition for “low-volume low-pressure application equipment.”

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 82

Existing
Section

Number New
Section

Number Proposed Change

This definition is the same as the definition used in other District rules.

208 215 Section renumbered.

NA 216 Added a definition for “roll coater.” This definition is the same as the

definition used in other District rules.

209-211 217-219 Sections renumbered. 301 Same Lowered VOC limits for three piece can interior body spray and two piece can interior body spray to be consistent with the limits in BAAQMD Rule 8-

11 and SJVAPCD Rule 4604.

Separated the end sealing compound category into “end sealing compound for food/beverage cans” and “end sealing compound for non-food containers,” and established VOC limits that are lower than the current VOC limit for end sealing compound. The proposed VOC limits for the two subcategories are consistent with the more stringent, feasible limits in
SCAQMD Rule 1125. 302 Same Increased emissions control efficiency requirement to be consistent with the requirements in BAAQMD Rule 8-11 and SJVAPCD Rule 4604. Added an equation for the calculation of the allowable daily emissions from emissions control equipment and from compliance with the VOC limits. 303 Same Added a sunset date to the current VOC limit for cleanup of container assembly equipment, and removed the expired effective date. Revised the VOC limit for the cleanup of container assembly equipment to 25 g/l. This is now consistent with SCAQMD Rule 1171- Solvent Cleaning Operations, in (c)(1)(B)(i). NA 304 Added a section for application equipment requirements. These requirements are the same as the requirements in other District coating rules, with an additional option to use an add-on control device with an overall system efficiency of 85.5% (equivalent to 90% capture efficiency and 95% control efficiency). NA 403 Added a section for the calculation of VOC content of cleanup material,

consistent with other District rules. NA 404 Added a section for the calculation of percent control efficiency and VOC mass emission rate, consistent with other District rules. Specified EPA Method 25A as an allowed method of determining VOC mass

concentration to be consistent with other District rules. NA 405 Added a section for calculation for determining overall system efficiency.

This calculation is the same as the calculation in other District rules. 501.1 Same Added a reference to new section 403, which specifies the procedure for calculating VOC content of cleanup material. 501.2 Same Added a reference to new section 404, which specifies the procedure for calculating the percent control efficiency. 501.3 Same Revised the test methods for determining capture efficiency to be

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 83

Existing
Section

Number New
Section

Number Proposed Change

consistent with other District rules. Specified EPA Method 25A as an allowed method of determining control efficiency and emission rates from

control devices to be consistent with other District rules. 501.4 Same Updated ASTM method number to the most current version.

NA 501.5 To clarify enforceability, added paragraph stating that where multiple test methods are specified, a violation established by any one of the test

methods constitutes a violation of the rule. 504 Same Added a sunset date for the current requirement for duration of records. Revised the requirement for duration of records to five years. This is

consistent with other District rules.

Rule 454, Degreasing Operations

Existing
Section

Number New
Section

Number Proposed Change

110.2 NA Removed this section because it has since expired. 110.3 110.2 Added a sunset date for the current exemption.

NA 110.3 Revised the exemption to 25 grams per liter or less VOCs for solvents used in degreasers. This is consistent with SCAQMD Rule 1122, Solvent Degreasers, in (d). 110.5 NA Removed this section because it duplicated the exemption in previous section 110.3, which is being sunset. 110.6 110.5 Added a sunset date for the current exemption, which will make degreasers that are subject to the NESHAP also subject to the requirements of this rule, including VOC content limits. The NESHAP does not regulate VOC

content. 110.7 NA Removed this section because it has since expired.

110.8 110.6 Section renumbered. 110.9 110.7 Updated to reflect the new paragraph added to section 302 and renumbering of Rule 456. NA 110.8 Added an exemption for the degreas ing of high-voltage microwave vacuum tubes because compliance with the degreasing VOC limit is not technologically feasible. 215 Same Clarified the definition of non-vapor degreaser to emphasize that the definition includes remote reservoir degreasers. NA 226 Added a definition for “water separator.” This definition is the same as the
definition used in SCAQMD Rule 1122.

226-227 227-228 Sections renumbered. 301 Same Deleted text that was unnecessary because the term “degreaser” already includes “remote reservoir degreaser.”

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 84

Existing
Section

Number New
Section

Number Proposed Change

302 Same Clarified to emphasize that non-vapor degreasers are also subject to the requirements of Section 301.

302.1 Same Removed the reference to Section 110.2 because this section has since expired. Removed “including remote reservoir degreasers” because the definition of “non-vapor degreasers” already includes remote reservoir degreasers.

Corrected the typographical error to now read “b” instead of “d.”

302.2 Same Added a sunset date for the current VOC limit for solvents used in nonvapor degreasers. NA 302.3 Revised the VOC limit for solvents used in non-vapor degreasers. Solvents used in non-vapor degreasers must have a VOC content of 25 g/l or less. This is consistent with SCAQMD Rule 1122, Solvent Degreasers, in (d). 303 Same Corrected typographical error. 304 Same Corrected grammatical error. 304.1 NA Removed this section because it has since expired. 304.2 304.1 Removed the effective date, which has passed. Corrected grammatical

error. 304.3 304.2 Updated to reflect renumbered section.

NA 304.3 Added a new VOC limit for vapor degreasing operations. Solvents used in vapor degreasers must have a VOC content of 25 g/l or less. This is consistent with SCAQMD Rule 1122, Solvent Degreasers, in (e)(3). 305 Same Removed the effective date, which has passed. Clarified to emphasize that remote reservoir degreasers are also subject to the requirements of

Sections 301 and 302. 309 Same Added emissions control equipment requirements to the requirements for lip exhaust system. After the sunset date for Section 310, emissions control equipment will no longer be allowed as an alternative to Sections 302, 304, and 307 (see discussion of Section 310 below), but will still be allowed for venting emissions from a lip exhaust system. 310 Same Added a sunset date for the provision allowing the use of emissions control equipment in lieu of compliance with the equipment requirements for degreasing operations. After the sunset date, the use of an emission control device as specified in this section would no longer ensure emission reductions that are equivalent to compliance with the other sections of the rule, which will require the use of solvents containing no more than 25 g/l VOC or the use of an airtight/airless system. Change is consistent with SCAQMD Rule 1122, Solvent Degreasers. 401 Same Corrected typographical error. 501.5 501.4 Corrected the typographical error to now read 501.4 instead of 501.5. Added a sunset date for the current requirement for duration of records.

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 85

Existing
Section

Number New
Section

Number Proposed Change

Revised the requirement for duration of records to five years. This is

consistent with other District rules. 502 Same Updated ASTM method numbers to the most current versions. 502.3 Same Reworded to be consistent with other District rules. No change in meaning.

NA 502.8 To clarify enforceability, added paragraph stating that where multiple test methods are specified, a violation established by any one of the test

methods constitutes a violation of the rule.

Rule 456, Aerospace Assembly and Component Coating Operations

Existing
Section

Number New
Section

Number Proposed Change

110 Same Effective 1/1/09, the low usage exemption will be lowered from 200 gallons per year to 55 gallons per year. Records indicate that the 55 gallons per year exemption is sufficient for applicable District sources, and is consistent with the EPA Region IX “Little Bluebook.” 113 Same Updated to reflect renumbering of Section 304.5 to 304.6. NA 219 Added a definition for “electrostatic spray.” This definition is the same as the definition used in Shasta County AQMD Rule 3:13- Polyester Resin Operations.

219-232 220-233 Sections renumbered. NA 234 Defined Material as any coating, coating remover, or solvent.

233-234 235-236 Sections renumbered. 235 237 Revised to clarify that non-compliant materials include adhesives, maskants, and strippers as well as coatings.

236-262 238-264 Sections renumbered. 301 Same Removed the past effective date. Clarified that the VOC limits are as applied. 302 Same Removed the past effective date. 304 Same Added a sunset date for current standard for cleaning of spray guns used in coating operations. Added a VOC limit of 25 g/l for cleaning of application equipment, effective one year after adoption date. This proposed provision applies to all application equipment, not just spray guns. An enclosed gun cleaner may still be used in lieu of complying with the 25 g/l limit, until two years after adoption date, when the VOC limit is applicable regardless of whether an enclosed gun cleaner is used. (This extension was added in response to a comment from an aerospace coating source, to allow sufficient time to test and requalify substitute solvents.) Eventual requirements (VOC limit without enclosed gun cleaner option) are consistent with SCAQMD Rule 1171- Solvent Cleaning Operations, in

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 86

Existing
Section

Number New
Section

Number Proposed Change

(c)(1)(C).

Added a sunset date for the provision that allows the soaking of spray gun nozzles in solvents without a limit on VOC content. After the sunset date, spray gun nozzles are subject to the same requirements as other application equipment, consistent with SCAQMD Rule 1171.

Removed the past effective date. 401 Same Removed the past effective date and clarified that non-compliant materials include adhesives, maskants, and strippers as well as coatings. 406 Same Updated ASTM test method numbers to the most current versions.

407 Same Corrected the typographical error in the equation for percent control efficiency. 408 Same Corrected the typographical error in the equation for overall system efficiency 501.5 Same Added a sunset date for the current requirement for duration of records. Revised the requirement for duration of records to five years. This is

consistent with other District rules. 502 Same Updated ASTM method numbers to the most current versions. 502.5 Same Updated to incorporate most recent U.S. EPA guidelines on determining capture efficiency. NA 502.8 To clarify enforceability, added paragraph stating that where multiple test methods are specified, a violation established by any one of the test

methods constitutes a violation of the rule.

Rule 463, Wood Products Coatings

Existing
Section

Number New
Section

Number Proposed Change

NA 103 Added a severability section to this rule, consistent with other District rules. 110.4 Same Clarified that coating of architectural components or structures not coated in a shop environment is subject to Rule 442- Architectural Coatings. 110.5 NA Removed exemption pertaining to stencil coatings used to comply with U.S. Military Specifications. The facility that used this exemption is no longer in operation. 210 Same Replaced the term “self sealing” with “combined sealer/topcoat” to clarify that conversion varnish is not subject to the VOC limit for sealers when used as a combined sealer/topcoat system. Removed the past effective

date.

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 87

Existing
Section

Number New
Section

Number Proposed Change

NA 220 Added a definition for “historical reproduction coating.” This definition limits the applicability of the emissions averaging provision specified in Section 306.1 to a wood coating facility in Sacramento County. This facility, the only source in Sacramento County curr ently using the emissions averaging provision in the current Rule 463, will be allowed to continue to use the provision for the restoration of antiq ue wood products to a historically

accurate finish.

220-222 221-223 Sections renumbered. NA 224 Added a definition for “major stationary source of VOC.” This definition was extracted from Rule 207, TITLE V – FEDERAL OPERATING PERMIT

PROGRAM.

223-242 225-244 Sections renumbered. 301 Same Removed the past effective date. 302 Same Clarified that the VOC limits are as applied. 302.2 Same Revised the language to clarify that “VOC limits expressed in grams per

liter shall be used” if emissions averaging is used to achieve rule compliance for low-solids stains, toners, and washcoats.

Clarified that the VOC limit for conversion varnish is applicable “when used as a combined sealer/topcoat system.” Previously, this information could be found only in Section 210.

Removed the expired VOC limits and the past effective date for the current

VOC limits.

Corrected typographical error to include correct units for low-solid stains, toners, and washcoats. 302.3 NA Removed this section because it shouldn’t have applied after 7/1/05, but

was never sunset. 303.2 Same Revised the rule language to clarify that “VOC limits expressed in grams per liter shall be used” if emissions averaging is used to achieve rule compliance for low-solids stains, toners, and washcoats.

Removed the past effective date for the current VOC limits.

Corrected typographical errors, including correct units for low-solid stains, toners, and washcoats. 304 Same Removed the past effective date. 306 Same Revised the emissions averaging provision to limit its applicability to historical reproduction coatings only and not for a major stationary source, and to limit the usage of these coatings to 20 gallons per year per facility. These changes are proposed to ad dress EPA comments concerning the

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 88

Existing
Section

Number New
Section

Number Proposed Change

approvability of the averaging provision.

Removed the section that is no longer applicable because it has since expired. Revised the equation for determining compliance with emissions limits for coatings for consistency with the expiration of the 0.9 multiplier.

Added paragraph 306.2 to specify that if a stationary source does not satisfy the requirement to demonstrate compliance with the averaging provision at any time during a rolling 30-day period, the stationary source has exceeded the allowable emissions on every day of the rolling 30-day period. 308 Same Added a sunset date for the provision that allows the soaking of spray gun nozzles in solvents without a limit on VOC content. After the sunset date, spray gun nozzles are subject to the same requirements as other application equipment, consistent with SCAQMD Rule 1171.

Removed the past effective dates. Added a sunset date for the surface preparation/cleanup requirement that spray equipment must be disassembled and cleaned in an enclosed gun cleaner. After the sunset date, the rule no longer requires spray equipment cleanup to be performed using an enclosed gun cleaner, but still requires compliance with the proposed VOC limit for surface preparation and cleanup, consistent with
SCAQMD Rule 1171.

Added a sunset date for current VOC limit for surface preparation and cleanup with a VOC material. Added a new VOC limit for surface preparation and cleanup with a VOC material. This new limit is consistent with SCAQMD Rule 1171- Solvent Cleaning Operations, in (c)(1)(A)(i). 401 Same Removed the past effective date. 407 NA Removed this section because it has since expired. 501.1 Same Inserted missing label for paragraph c.

502 Same Added a sunset date for the current requirement for duration of records. Revised the requirement for duration of records to five years. This is

consistent with other District rules. 503 Same Updated ASTM method numbers to the most current versions. 503.4 Same Reworded to be consistent with other District rules. No change in meaning.

NA 503.8 To clarify enforceability, added paragraph stating that where multiple test methods are specified, a violation established by any one of the test

methods constitutes a violation of the rule.

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 89

Rule 464, Organic Chemical Manufacturing Operations

Existing
Section

Number New
Section

Number Proposed Change

110-113 Same Updated to reflect section 400 renumbering. 115 Same Updated to reflect new paragraph added to section 308. 301-304 Same Updated to reflect section 400 renumbering. 305 Same Updated to reflect section 400 renumbering, and removed past effective

dates. 306-307 Same Updated to reflect section 400 renumbering. 308 Same Added sunset date for current VOC limit for maintenance solvent cleaning. Lowered the VOC limit for maintenance solvent cleaning to 25 g/l. This new limit is consistent with SCAQMD Rule 1171- Solvent Cleaning Operations, in (c)(1)(B)(i). 401 NA Deleted section because the compliance date has passed. 402-413 401-412 Sections renumbered, and text updated to reflect renumbered sections. 407 406 Updated ASTM method numbers to the most current versions. 501.1 Same Updated to reflect section 400 renumbering. 501.3 Same Updated to reflect section 400 renumbering.

501.4-

501.7 Same Added rule language to require sources to keep records of the VOC content of materials used. Sources already keep these records, but the added rule language clarifies this requirement. 502.2 Same Changed “capture efficiency” to “collection efficiency” to maintain consistency with other sections of this rule. Reworded to be consistent with other District rules. No change in meaning. 502.4 Same Updated ASTM method number to the most current version.

NA 502.6 To clarify enforceability, added paragraph stating that where multiple test methods are specified, a violation established by any one of the test

methods constitutes a violation of the rule.

Rule 465, Polyester Resin Operations

Existing
Section

Number New
Section

Number Proposed Change

104 Same Added a sunset date for the current exemption for cleaning materials. This is consistent with SCAQMD Rule 1171- Solvent Cleaning Operations, which does not contain such an exemption. 301 Same Increased overall control efficiency requirements to 90%, consistent with the requirements in SCAQMD Rule 1162. 303 Same Added a sunset date for the current VOC limit for cleaning materials.

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 90

Existing
Section

Number New
Section

Number Proposed Change

Lowered the VOC limit for cleaning materials to 25 g/l. Eliminated the provision currently allowing the use of an enclosed gun cleaner In lieu of compliance with the VOC content limit for cleaning materials. This new limit is consistent with SCAQMD Rule 1171-Solvent Cleaning Operations, in (c)(1)(E). 404 Same Corrected previous typographical error in equation for calculating overall system efficiency. 501.2c Same Replaced “non-compliant coatings” with “non-compliant materials” for consistency with Section 215. 501.4 Same Added a sunset date for the current requirement for duration of records. Revised the requirement for duration of records to five years. This is

consistent with other District rules. 502.4 Same Updated ASTM method number to the most current version. 502.5 Same Updated to incorporate most recent U.S. EPA guidelines on determining capture efficiency. NA 502.7 To clarify enforceability, added paragraph stating that where multiple test methods are specified, a violation established by any one of the test

methods constitutes a violation of the rule.

Rule 466, Solvent Cleaning Operations

Existing
Section

Number New
Section

Number Proposed Change

102 Same Clarified that the requirements of proposed Rule 466 apply to sterilization of food manufacturing and processing equipment 110.2 Same Added a sunset date for current exemption for solvent cleaning. Lowered the VOC limit in the exemption to 25 g/l. This new limit is consistent with SCAQMD Rule 1171- Solvent Cleaning Operations, in (h)(1).

Added an exemption for the cleaning of high-voltage microwave vacuum tubes because, similar to other exempt applications, compliance with the solvent VOC limit is not technologically feasible.

Added a sunset date for the exemption for electrostatic coating application equipment, consistent with SCAQMD Rule 1171. 110.4 Same Corrected typographical error. Cleaning of nozzle tips of automated spray equipment systems is not subject to the entire Section 302, not only 302.2. NA 110.5 Added an exemption for materials used to strip cured inks, cured coatings, or cured adhesives, consistent with SCAQMD Rule 1171. This exemption was already implied in the definition of Solvent Cleaning, but this new

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 91

Existing
Section

Number New
Section

Number Proposed Change

section has been added for clarification. NA 209 For clarification, added a definition for cured ink, cured coating, or cured
adhesive. This definition is consistent with SCAQMD Rule 1171.

209-213 210-214 Sections renumbered. NA 215 Added a definition for food product manufacturing and processing operation. This definition is the same as the definition in SCAQMD Rule 1131- Food Product Manufacturing and Processing Operations. NA 216 Added a definition for general work surface. This definition is the same as the definition in SCAQMD Rule 1171- Solvent Cleaning Operations.

214-216 217-219 Sections renumbered. 217 220 Revised the definition of janitorial cleaning. This definition is the same as the definition in SCAQMD Rule 1171- Solvent Cleaning Operations. NA 221 Added a definition for jobsite to clarify the applicability of the VOC limits in

the table in Section 301.1.

218-219 222-223 Sections renumbered. 220 224 Revised the definition of maintenance cleaning. This definition is the same as the definition in SCAQMD Rule 1171- Solvent Cleaning Operations.

221-226 225-230 Sections renumbered. NA 231 Added a definition for pharmaceutical product. This definition is the same as the definition in SCAQMD Rule 1171- Solvent Cleaning Operations.

227-235 232-240 Sections renumbered. NA 241 Added a definition for solvent based coating to clarify the applicability of the

VOC limits in the table in Section 301.1. 236 242 Added a provision that effective one year after date of adoption, solvent cleaning operations will include the sterilization of food manufacturing and processing equipment.

237 243 Section renumbered.

NA 244 Added a definition for sterilization. This definition is the same as the definition in SCAQMD Rule 1131- Food Product Manufacturing and Processing Operations.

238-239 245-246 Sections renumbered. NA 247 For clarification, defined “stripping” as the removal of cured inks, cured coatings, or cured adhesives.

240-241 248-249 Sections renumbered. NA 250 Added a definition for water based coating to clarify the applicability of the

VOC limits in the table in Section 301.1.

242 251 Section renumbered. 301 Same Replaced “per Section 502.1” with “pursuant to Section 502.1” for consistency with other rule language.

Added sunset dates for current VOC standards for solvent cleaning activities. Lowered the VOC limits for solvent cleaning activities. These

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 92

Existing
Section

Number New
Section

Number Proposed Change

new limits are consistent with SCAQMD Rule 1171- Solvent Cleaning Operations, in (c)(1).

Added a sunset date for the current standards for architectural coating application equipment cleaning using solvent based coatings without an enclosed gun cleaner. Lowered the VOC limit to 25 g/l for this category. This new VOC limit applies regardless of whether an enclosed gun cleaner is used, and is consistent with SCAQMD Rule 1171.

Added a new VOC standard for sterilization of food product manufacturing and processing equipment. This new limit is consistent with SCAQMD Rule 1131- Food Product Manufacturing and Processing Operations. 302 Same Deleted sections that specified devices and methods used to clean architectural coating application equipment. These requirements have

been added to the table in Section 301.1.

Added a sunset date for the provision that allows the soaking of spray gun nozzles in solvents without a limit on VOC content. After the sunset date, spray gun nozzles are subject to the same requirements as other application equipment, consistent with SCAQMD Rule 1171. 304 Same Deleted reference to Section 302, from which the architectural application equipment cleaning requirements have been moved to Section 301. Clarified that all of the following paragraphs apply. 304.2 Same Updated to reflect section renumbering.

NA 304.3 Added a provision requiring emissi ons from use of an emissions control equipment to be less than or equal to the emissions resulting from compliance with all applicable VOC limits. This is more stringent than SCAQMD Rule 1171, which does not contain such a provision. Added an equation for the calculation of the allowable quarterly emissions from emissions control equipment and from compliance with the VOC limits. 401 NA Deleted section because the compliance date has passed.

402-405 401-404 Sections renumbered.

501.2 Same Updated to reflect section renumbering. 501.4 Same Updated to reflect section renumbering. 501.5 Same Added a sunset date for the current requirement for duration of records. Revised the requirement for duration of records to five years. This is

consistent with other District rules. 502.1 Same Updated to reflect section renumbering. 502.2 Same Updated ASTM method number to the most current version. Updated to reflect section renumbering. 502.4 Same Updated to incorporate most recent U.S. EPA guidelines on determining capture efficiency.

### Appendix B Summary of Changes Rules 450, 451, 452, 454, 456, 463, 464, 465, and 466 August 25, 2008, Page 93

Existing
Section

Number New
Section

Number Proposed Change

NA 502.6 To clarify enforceability, added paragraph stating that where multiple test methods are specified, a violation established by any one of the test

methods constitutes a violation of the rule.Appendix CAllocation of the 2010 District Solvent Cleaning Emissions Inventory to Specific District RulesAugust 25, 2008, Page 94Appendix C- Allocation of the 2010 District Solvent CleaningEmissions Inventory to Specific District RulesVOC Emissions by EIC code2010 Non-Coating, VOC TPY2010 Coating - Application Equipment Cleaning - VOC TPY2010 Coating - Surf Prep/Cleanup - VOC TPYEIC2010OzoneSIP(v1.06RF980,11/16/06))TPYPrinting(Rule450)Degreasing(Rule454)Other(Rule466)Misc.MetalParts(Rule451)CanCoating(Rule452)AeroSpace(Rule456)AutoRefinishing(Rule459)Adhesives&Sealants(Rule 460)WoodProducts(Rule463)PolyesterResin(Rule465)Misc.MetalParts(Rule451)CanCoating(Rule452)AeroSpace(Rule456)AutoRefinishing(Rule459)Adhesives&Sealants(Rule 460)WoodProducts(Rule463)PolyesterResin(Rule465)COLD CLEANING230-240-8300-0000Coatings – Thinning andCleanup Solvents(Unspecified)116.10 92.2 22.3 1.4220-204-0500-0000Cold Cleaning –Petroleum Naphtha190.46 64.94 69.91 7.15 13.31 9.03 8.71 3.63 0.00 4.88 4.37 1.81 2.24 0.48220-204-3022-0000Cold Cleaning –Alcohols (Unspecified)4.67 4.67 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-204-3083-0000Cold Cleaning –Chlorofluorocarbons(Unspecified)1.06 1.06 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-204-3162-0000Cold Cleaning –Fluorocarbons(Unspecified)0.00220-204-3176-0000Cold Cleaning – GlycolEthers (Unspecified)0.29 0.29 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-204-3202-0000Cold Cleaning –Isopropanol0.37 0.37 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-204-3204-0000Cold Cleaning –Ketones (Unspecified)0.18 0.18 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00Appendix CAllocation of the 2010 District Solvent Cleaning Emissions Inventory to Specific District RulesAugust 25, 2008, Page 95VOC Emissions by EIC code2010 Non-Coating, VOC TPY2010 Coating - Application Equipment Cleaning - VOC TPY2010 Coating - Surf Prep/Cleanup - VOC TPYEIC2010OzoneSIP(v1.06RF980,11/16/06))TPYPrinting(Rule450)Degreasing(Rule454)Other(Rule466)Misc.MetalParts(Rule451)CanCoating(Rule452)AeroSpace(Rule456)AutoRefinishing(Rule459)Adhesives&Sealants(Rule 460)WoodProducts(Rule463)PolyesterResin(Rule465)Misc.MetalParts(Rule451)CanCoating(Rule452)AeroSpace(Rule456)AutoRefinishing(Rule459)Adhesives&Sealants(Rule 460)WoodProducts(Rule463)PolyesterResin(Rule465)220-204-3246-0000Cold Cleaning –Methylene Chloride(Dichloromethane)0.00220-204-3333-0000Cold Cleaning –Terpenes (Unspecified)2.41 2.41 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-204-3339-0000Cold Cleaning –Toluene/Xylene0.15 0.15 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-204-3344-0000Cold Cleaning – 1,1,1,-Trichloroethane (TCA)0.00220-204-8104-0000Cold Cleaning –Degreasing Solvents –Pure (Unspecified)0.07 0.07 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-204-8106-0000Cold Cleaning –Degreasing Solvents –Blends (Unspecified)21.46 21.46 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-206-3083-0000**Vapor DegreasingChlorofluorocarbons(Unspecified)0.55 0.55220-206-3107-0000**Vapor DegreasingDichlorofluoroethane(HCFC-141B)0.04 0.04Appendix CAllocation of the 2010 District Solvent Cleaning Emissions Inventory to Specific District RulesAugust 25, 2008, Page 96VOC Emissions by EIC code2010 Non-Coating, VOC TPY2010 Coating - Application Equipment Cleaning - VOC TPY2010 Coating - Surf Prep/Cleanup - VOC TPYEIC2010OzoneSIP(v1.06RF980,11/16/06))TPYPrinting(Rule450)Degreasing(Rule454)Other(Rule466)Misc.MetalParts(Rule451)CanCoating(Rule452)AeroSpace(Rule456)AutoRefinishing(Rule459)Adhesives&Sealants(Rule 460)WoodProducts(Rule463)PolyesterResin(Rule465)Misc.MetalParts(Rule451)CanCoating(Rule452)AeroSpace(Rule456)AutoRefinishing(Rule459)Adhesives&Sealants(Rule 460)WoodProducts(Rule463)PolyesterResin(Rule465)220-206-3300-0000**Vapor DegreasingPerchloroethylene0.00220-206-3301-0000**Vapor DegreasingPerfluorocarbons(Unspecified)0.15 0.15220-206-3344-0000**Vapor Degreasing1,1,1,- Trichloroethane(TCA)0.00220-206-3346-0000**Vapor DegreasingTrichloroethylene (TCE)0.66 0.66WIPE CLEANING220-208-0500-0000Handwiping – PetroleumNaphtha24.71 24.71 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-208-3022-0000Handwiping – Alcohols(Unspecified)11.17 11.17 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-208-3083-0000Handwiping –Chlorofluorocarbons(Unspecified)0.15 0.15 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-208-3176-0000Handwiping – GlycolEthers (Unspecified)2.34 2.34 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00Appendix CAllocation of the 2010 District Solvent Cleaning Emissions Inventory to Specific District RulesAugust 25, 2008, Page 97VOC Emissions by EIC code2010 Non-Coating, VOC TPY2010 Coating - Application Equipment Cleaning - VOC TPY2010 Coating - Surf Prep/Cleanup - VOC TPYEIC2010OzoneSIP(v1.06RF980,11/16/06))TPYPrinting(Rule450)Degreasing(Rule454)Other(Rule466)Misc.MetalParts(Rule451)CanCoating(Rule452)AeroSpace(Rule456)AutoRefinishing(Rule459)Adhesives&Sealants(Rule 460)WoodProducts(Rule463)PolyesterResin(Rule465)Misc.MetalParts(Rule451)CanCoating(Rule452)AeroSpace(Rule456)AutoRefinishing(Rule459)Adhesives&Sealants(Rule 460)WoodProducts(Rule463)PolyesterResin(Rule465)220-208-3204-0000Handwiping – Ketones(Unspecified)8.47 8.47 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-208-3246-0000Handwiping – MethyleneChloride(Dichloromethane)0.00220-208-3333-0000Handwiping – Terpenes(Unspecified)0.07 0.07 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-208-3339-0000Handwiping –Toluene/Xylene2.19 2.19 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-208-3344-0000Handwiping – 1,1,1,-Trichloroethane (TCA)0.00220-208-3346-0000Handwiping –Trichloroethylene (TCE)0.22 0.22 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-208-8104-0000Handwiping –Degreasing SolventsPure (Unspecified)1.61 1.61 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00220-208-8106-0000Handwiping –Degreasing Solvents –Blends (Unspecified)5.15 5.15 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00230-216-8350-0000Coatings – PreparationSolvents (Unspecified)1.10 1.10Appendix CAllocation of the 2010 District Solvent Cleaning Emissions Inventory to Specific District RulesAugust 25, 2008, Page 98VOC Emissions by EIC code2010 Non-Coating, VOC TPY2010 Coating - Application Equipment Cleaning - VOC TPY2010 Coating - Surf Prep/Cleanup - VOC TPYEIC2010OzoneSIP(v1.06RF980,11/16/06))TPYPrinting(Rule450)Degreasing(Rule454)Other(Rule466)Misc.MetalParts(Rule451)CanCoating(Rule452)AeroSpace(Rule456)AutoRefinishing(Rule459)Adhesives&Sealants(Rule 460)WoodProducts(Rule463)PolyesterResin(Rule465)Misc.MetalParts(Rule451)CanCoating(Rule452)AeroSpace(Rule456)AutoRefinishing(Rule459)Adhesives&Sealants(Rule 460)WoodProducts(Rule463)PolyesterResin(Rule465)230-240-3008-0000Coatings – Acetone0.00230-240-3128-0000Coatings – Ethyl Alcohol0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00230-240-3232-0000Coatings – Methyl EthylKetone (MEK)0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00230-240-8302-0000Coatings – ThinningSolvents (Unspecified)0.22 0.00 0.00 0.00 0.00 0.05 0.00 0.06 0.05 0.02 0.03 0.01230-240-8350-0000Coatings – CleanupSolvents (Unspecified)1.24 0.00 0.00 0.00 0.00 0.26 0.00 0.35 0.31 0.13 0.16 0.03240-240-3202-0000Printing – Thinning andCleanup Solvents –Isopropanol15.00 15.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00240-240-3314-0000Printing – Thinning andCleanup Solvents – NPropanol1.10 1.10240-240-8302-0000Printing – ThinningSolvents (Unspecified)0.88 0.88 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00299-995-8000-0000Coatings – OtherSolvents (Unspecified)0.84 0.84Appendix CAllocation of the 2010 District Solvent Cleaning Emissions Inventory to Specific District RulesAugust 25, 2008, Page 99VOC Emissions by EIC code2010 Non-Coating, VOC TPY2010 Coating - Application Equipment Cleaning - VOC TPY2010 Coating - Surf Prep/Cleanup - VOC TPYEIC2010OzoneSIP(v1.06RF980,11/16/06))TPYPrinting(Rule450)Degreasing(Rule454)Other(Rule466)Misc.MetalParts(Rule451)CanCoating(Rule452)AeroSpace(Rule456)AutoRefinishing(Rule459)Adhesives&Sealants(Rule 460)WoodProducts(Rule463)PolyesterResin(Rule465)Misc.MetalParts(Rule451)CanCoating(Rule452)AeroSpace(Rule456)AutoRefinishing(Rule459)Adhesives&Sealants(Rule 460)WoodProducts(Rule463)PolyesterResin(Rule465)520-522-8300-0000**Architectural CoatingsThinning andCleanup SolventsCoatings (Unspecified)82.82 82.82Total TPY497.77 80.82 101.97 141.9 7.15 13.31 9.03 92.23 8.71 22.33 1.44 3.94 0.00 5.29 4.74 1.96 2.42 0.52TotalTPD1.36 0.22 0.28 0.38 0.02 0.04 0.02 0.25 0.02 0.060.00 0.01 0.00 0.01 0.01 0.01 0.01 0.00Total VOC Emissions by District RuleRule 450-GraphicArtsRule451-Misc.MetalPartsRule 452-CanCoatingRule 454-DegreasingRule 456-AerospaceRule 459-AutoRefinishingRule 460-Adhesives& SealantsRule 463-WoodProductsRule 465-PolyesterResinRule 466-SolventCleaningTotalTotal TPY (Application Equipment Cleaning)80.82 7.15 13.31 9.0392.23 8.71 22.33 1.44235.01Total TPY (Surface Preparation/Cleanup) 3.94 5.29 4.74 1.96 2.42 0.5218.88Total TPY (Other)101.97 141.91243.88TOTAL TPY80.82 11.09 13.31 101.9714.32 96.97 10.67 24.751.97 141.91 497.77

### Appendix D

Public Comments August 25, 2008, Page 

### 100

APPENDIX D
PUBLIC COMMENTS

Public Workshop Comments (April 28, 2008)

Participants: Kathy Adams Al Batakji Larry Battenberg

Frederick Carr Steve Cerniglit

Bill Coleman George Contos

Richard Crowe Bob Dipper Don Eggleston Nancy Fletcher Randy Harvey Beth Barker Hidalgo Vern Howlett

Ted Huff

James Iwamoto Rodger Mannka

Kevin Peterson David Ratajczak

Jill Reed

Chelsea Sand Randy Thompson Raymond Vigil

Jim Williams Kevin Willy

Comment #1: Is the 15% monthly usage limit for metering roller/printing plate cleaning in Rule 450 (Section 302.2) going away? What is the purpose of this 15% usage limit? Acetone is hazardous and extremely flammable, so why is it an exempt solvent? Also, it is not feasible to use non-acetone solvents because they leave residue.

Response: The 15% usage limit is proposed to sunset when the VOC content of blanket/roller washes and metering rollers/printing plates are all required to meet a limit of 100 g/l. This usag e limit was originally designed to limit the usage of metering roller/printing plate cleaning because the rule allows for higher vapor pressure limits than for blanket and roller washes. Acetone is an exempt compound because the U.S. EPA determined that acetone has negligible reactivity for forming ground-level ozone.

Sources in the South Coast AQMD are currently using non-acetone cleaning products to comply with the 100 g/l limit. Staff is proposing to extend by one year the effective dates for all categories in Rule 450 that have 1/1/2010 effective dates in the version of proposed Rule 450 presented at the 4/28/08 Public Workshop. The new effective date for these categories is 1/1/2011. Staff believes that extending the effective dates for these categories will allow sufficient time for industry to convert to the lower VOC cleaning products and find suitable replacement

solvents.

Comment #2: It is currently not feasible to require low VOC solvents to be used on automatic washing systems for ink rollers. Manufacturers of automatic washing systems are not recommending the use of low VOC solvents, because of potential problems with the seals.

Response: Sources in the South Coast AQMD are currently using low-VOC solvents in automatic washing systems. St aff believes the delayed effective date of 1/1/2011 for non-newsprint cleaning provides enough time to find

### Appendix D

Public Comments August 25, 2008, Page 

### 101

suitable materials.

Comment #3: We plan on requesting exemptions for the use of higher VOC cleaning materials for our products because we find that soaking and degreasing is more effective than wipe cleaning. We will submit written comments regarding this.

Response: Staff will review the written comments once we receive them. (See response to Comment #1 from Teledyne MEC).

Comment #4: Will the VOC limit for gun cleaning drop to 25 g/l?

Response: Yes, Staff proposes to lower the VOC limit for application equipment cleaning, which includes gun cleaning, to 25 g/l in Rules 451, 456, 463 and 466. The option of using enclosed gun cleaners with solvents containing greater than 25 g/l VOC will no longer be allowed in the proposed rules. Solvents used in enclosed gun cleaners must comply with the 25 g/l limit as well.

Comment #5: Solvents containing 25 g/l or less VOCs are not capable of cleaning guns effectively. The use of polyurethane in particular destroys the guns, thereby requiring the guns to be replaced frequently.

Response: Based on the successful implementation of the 25 g/l limit for application equipment cleaning in other air districts, Staff believes compliant, effective solvents for gun cleaning are readily available. Staff believes that spray guns do not require specialized cleaning processes or products.

Comment #6: When will these rules be adopted?

Response: These amendments are tentatively scheduled for consideration at the September 25, 2008 Board meeting.

Comment #7: Regarding Rule 450, we use the same material to clean removable press components that we use to clean blankets and rollers. Why is a 25 g/l VOC limit proposed for removable press components?

Response: The 25 g/l VOC limit for cleaning removable press components has been
demonstrated to be feasible in the South Coast AQMD.

Comment #8: We use the same presses and cleaning materials for printing on both newsprint and non-newsprint substrates. The separate recordkeeping requirements proposed in Rule 450, Section 501.3 are unnecessary.

Response: See response to Comment #3 from the Office of State Publishing.

Comment #9: Regarding Rule 451, Section 110, Staff is proposing to delete the 200 gal/yr low usage exemptions for alum inum coatings and pretreatment wash primers. A 55 gal/yr exemption is not enough for my business.

### Appendix D

Public Comments August 25, 2008, Page 

### 102

Response: In follow-up discussions with the commenter, Staff learned that this business will use powder coatings and will be able to comply with the rule as proposed.

Comment #10: Regarding Rule 466, cleaning of high voltage electrical equipment is also critical. Why isn’t this cleaning application exempt?

Response: See response to Comment #1 from SMUD.

Letter from Alex Krichevsky, California Air Resources Board (April 24, 2008)

Comment #1: We recommend that the District lower the exemption level in Section 110.1 of Rule 450, from 60 pounds of VOC per month to 200 pounds per rolling 12-month period, since Ventura County Air Pollution Control District (VCAPCD) Rule 74.19 currently contains the latter exemption

level.

Response: The VCAPCD Rule 74.19 exemption specifies 200 pounds per rolling 12- month period, but the exemption does not include VOC emissions from aerosol products, cold cleaners, and vapor degreasers in this determination. Also the VCAPCD rule includes an exemption for circuit board printing and specifies VOC limits for cleaning materials and printing adhesives that are higher than those specified in proposed Rule 450. Collectively, the exemptions and proposed VOC limits in proposed Rule 450 will deliver greater emission reductions than that achieved by implementing the recommended VCAPCD exemption level and limits. Therefore, this change to the exemption level is not recommended.

Comment #2: We recommend that the District revise the VOC limits in Rule 450 for “Extreme Performance Ink/Coating” for screen printing from 800 g/l to 400 g/l and the VOC limit for “Sign Ink/Coating” from 500 g/l to 400 g/l, because other air districts in California (Bay Area and San Joaquin Valley) have implemented the 400 g/l limit in their respective rules.

Response: SJVUAPCD Rule 4607 includes an exemption for facilities that emit less than 400 pounds of VOC per calendar month, which is less stringent than the exemption level in proposed Rule 450. Also, proposed Rule 450 includes several VOC limits for solvent cleaning that are lower than those in SJVUAPCD Rule 4607. The 2002 emissions inventory for screen printing inks and coatings is only 0.07 tons per day of VOC. The two categories mentioned above only affect a portion of the screen printing inventory, and, therefore, Staff is not proposing to lower these limits.

Comment #3: We recommend that the District withhold the proposed amendment of the VOC limit for cleaning of ultraviolet/electron beam inks (from 800 g/l to 100 g/l on 1/1/2010) until after the VOC limit for this category becomes effective in South Coast AQMD Rule 1171 on 1/1/2009. The proposed

VOC limit for ultraviolet inks is a technology forcing limit.

Response: Staff is proposing to extend by one year the effective dates for all categories in Rule 450 that have 1/1/2010 effective dates in the version of

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proposed Rule 450 presented at the 4/28/08 Public Workshop. The new effective date for these categories is 1/1/2011. Staff believes that extending the effective dates for these categories will allow sufficient time for industry to convert to the lower VOC cleaning products.

Comment #4: We recommend that the combined collection and control efficiency for an emission control system in Rule 450 (Section 303) be raised from 67% to 85%, consistent with the current requirement in San Diego County APCD

Rule 67-16.

Response: Staff now proposes to increase the overall emissions control system efficiencies to at least 90% for several types of printing processes to conform to two recent Control Techniques Requirements (CTGs) promulgated by EPA in September 2006.

Comment #5: We recommend that the District revise Section 502.3 in Rule 450 to specify the latest ASTM method, ASTM Test Method D 4457-02(2008).

Response: Staff has revised the rule language to specify this updated ASTM method.

Comment #6: We recommend that the District revise Section 502.7 in Rule 450 to specify the latest ASTM method, ASTM Test Method D 2879-97(2007).

Response: Staff has revised the rule language to specify this updated ASTM method.

Comment #7: We recommend that the District revise the rule language in Rule 454 (Section 310) to reflect the sunset date of the emissions control equipment requirement.

Response: To address this potential loophole, Staff has added the emissions control equipment requirements to the lip exhaust system requirements (Section 309), which still provide the option of using emissions control equipment.

Comment #8: We recommend that the low usage exemption in Section 110 of Rule 463 be lowered from 55 gallons per year to 20 gallons per year, consistent with the exemption level adopted by other air districts in California (Bay Area, El Dorado County, San Joaquin Valley, and Santa Barbara County) in their respective rules.

Response: Unlike Rule 463, the rules at other air districts that contain this 20 gallon/year exemption do not establis h VOC limits for refinishing of wood products. Staff is proposing to maintain the current exemption level with the existing and proposed VOC limits for refinishing and repairing, which will collectively deliver greater VOC reductions than the requirements in

other districts.

Comment #9: We recommend that VOC limit for “High-Solid Stain” in Rule 463 be lowered from 350 g/l to 240 g/l and the VOC limit for “Sealer” from 275 g/l to 240 g/l, consistent with the VOC limits adopted by other air districts in California (El Dorado County, San Joaquin Valley, Santa Barbara County, and Ventura County).

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Response: Staff determined that, as potential all-feasible measures, lowering the VOC limits for high-solid stains and sealers to the most stringent limits in the San Joaquin and Ventura County rules would reduce VOC emissions by less than 0.02 tons per day. Therefore, Staff is not proposing to lower

these limits.

Comment #10: We recommend that VOC limit for strippers in Rule 463 be lowered from 350 g/l to 200 g/l, consistent with the VOC limit in SDAPCD Rule 67-11.

Response: SDAPCD Rule 67-11 includes an exemption for sources with coating usage levels below 500 gallons per year, while Rule 463 exempts sources with coating usage levels less than 55 gallons per year. The District exemption is more stringent than the SDAPCD exemption, and therefore Staff is not proposing to lower the VOC limit for strippers.

Comment #11: We recommend that the District revise Section 503.3 in Rule 463 to specify the latest ASTM method, ASTM Test Method D 4457-02(2008).

Response: Staff has revised the rule language to specify this updated ASTM method.

Comment #12: We recommend that the District revise Section 503.7 in Rule 463 to specify the latest ASTM method, ASTM Test Method D 5403-93(2007).

Response: Staff has revised the rule language to specify this updated ASTM method.

Comment #13: We recommend that the District revise the combined collection and control efficiency for an emission cont rol system in Rule 465 (Section 301.2) from 85% to 90%, consistent with the current requirement in
SCAQMD Rule 1162.

Response: Staff now proposes to increase the control efficiency requirement for Rule

465 from 85% to 90%.

Comment #14: We recommend that the District revise Section 502.2 in Rule 466 to specify the latest ASTM method, ASTM Test Method D 4457-02(2008).

Response: Staff has revised the rule language to specify this updated ASTM method.

Letter from Don Eggleston, Office of State Publishing (April 25, 2008)

Comment #1: Compliance dates by substrate in Rule 450 (Section 302.1) are not appropriate for printers who use both newsprint and non-newsprint in their products from the same presses. At OSP, the same cleanup solvents are used on these presses regardless of substrate. Printers who use the same materials regardless of substrate should be allowed the maximum compliance period which is until 1/1/2010.

Response: South Coast AQMD successfully impl emented a similar two-tier structure for establishing effective dates for newsprint and non-newsprint substrates. The VOC limit for newsprint substrates became effective on

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7/1/2006, earlier than the effective date of 1/1/2008 for the VOC limit for non-newsprint substrates. Staff therefore believes compliance dates by substrates, as it relates to newsprint and non-newsprint, is reasonable.

Comment #2: For Rule 450 (Section 302.1), the proposed 25 g/l VOC limit for the cleaning of “Removable Press Components” is unreasonable because in most cases, the contamination is the same material removed from ink rollers and blankets, and blanket and roller washes are often used to clean such components. VOC limits for “Removable Press Components”

should match those of “Blanket and Roller Washes.”

Response: The 25 g/l VOC limit for the cleaning of “Removable Press Components” has already been demonstrated to be feasible in SCAQMD. Sources must utilize cleaning products other than blanket and roller washes to clean removable press components. Components that can be readily detached from the printing press do not necessitate specialized cleaning processes and higher VOC limits.

Comment #3: Printers such as OSP use the same fountain solutions, same solvents, same adhesives, and essentially the same inks on presses that run both newsprint and other substrates. Therefore, the list of materials used for newsprint would be identical to the list of materials for other substrates. The requirement in Rule 450 (Section 501.3) for separate usage records to be kept for newsprint and non-newsprint substrates serves no practical purpose in this case, and should be dropped.

Response: Staff has revised the recordkeeping requirement in Rule 450 for newsprint and non-newsprint substrates. The revised rule language does notrequire a source to keep separate usage records for newsprint and nonnewsprint substrates provided that t he source can already comply with the 1/1/2011 requirements for newsprint substrates.

Letter from Ted Huff, SMUD (May 5, 2008)

Comment #1: We request that an exemption be added to Section 110.2c in Rule 466 to include high voltage gloves, hot sticks, rubber blankets, line hoses, mechanical jumpers, insulator covers, and high-voltage test equipment leads. This equipment is used by personnel on energized circuits to perform testing, switching, equipment repairs, protection of personnel and other related functions to equipment and apparatus that cannot be practically de-energized. This high voltage equipment (hot sticks, gloves, rubber blankets, line hoses, mechanical jumpers, insulator covers and high voltage test equipment leads) represents in some cases, the individual's only protection from injury or death from electrocution while working on energized circuits or equipment. The products currently used for cleaning of this high voltage equipment provides the necessary level of cleaning to ensure that the equipment remains safe for use on live or energized circuits. The concern is that lower VOC-content products may not clean the surface as thoroughly and leave a residue allowing tracking

and flashover of the device.

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Response: Staff has determined that compliant products (aerosol products) are readily available and have been successfully used by electrical utilities in
SCAQMD. These aerosol cleaners are exempt from Rule 450 when used in quantities of 160 fluid ounces or less per day. CARB’s Consumer Products Regulations allow up to 45% VOC by weight for these electrical cleaners, which is lower that the current Rule 450 limit of 900 g/l but higher than the proposed limit of 100 g/l that will take effect one year after the date of adoption.

Letter from Daniel B. Pourreau, Lyondell Chemical Company (May 5, 2008)

Comment #1: We request that an exemption for tertiary-butyl acetate (TBAC) be added to all nine of the solvent cleaning rules. TBAC is a much better degreaser than acetone, produces less ozone than acetone, is safer to use than acetone, and was exempted from the federal VOC definition in November 2004 because of its negligible photochemical reactivity.

Response: Compliant products that do not contain TBAC are readily available. In order to exempt TBAC, Rule 101—General Provisions and Definitions, which lists all exempt compounds, would need to be revised to include TBAC. However, Rule 101 is not being proposed for amendment at this time. Staff will consider the request for the exemption of TBAC when Rule 101 is proposed for amendment.

Letter from G.M. Bonetto, Ph.D., Printing Industries of California (PIC) (May 7, 2008)

Comment #1: The District justifies its currently proposed VOC limits and corresponding implementation schedule by citing simila r amendments already in effect in
SCAQMD Rule 1171 and SCAQMD Technology Assessments that provide the supporting evidence. However, the results acquired in these technology assessments (specifically the report entitled “Assessment, Development, and Demonstration of Low-VOC Solvents for Cleaning of Lithographic Ink Application Equipment” by the Institute for Research and Technology Assistance”) are inconclusive and incomplete. Solvent formulations found to be successful during Institute for Research and Technology Assistance’s (IRTA) experiments do not work over the long term and cause a number of problems over time, including buildup and absorption of solvent residue on the rollers and reduction of the ink’s tack (which is detrimental because the level of ink tack governs the sharpness of the dot pattern). These problems have been substantiated in PIC’s independent studies, which were conducted by a well-known technical expert on lithographic printing. Additional problems and issues from the use of low-VOC solvents given in IRTA’s report include reduction of overall worker productivity and in extreme cases, fire hazards and destruction of the printing press.

Response: These studies did not evaluate all of the materials currently available on the market. There are other products available on the market, and there is at least one source in Sacramento County already using cleaning materials that comply with these limits.

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SCAQMD Rule 1171, adopted in 1999, set a date of July 1, 2005 for compliance with the 100 g/l limits. This date was extended twice, and the limits finally took effect on January 1, 2008. SCAQMD’s June 2006 staff report, which addressed the extension of the deadline for the final time, noted that field testing of compliant materials had been completed and that the additional 18 months (until 1/1/2008) would be necessary for additional testing and to give the industry time to transition to the new cleaning materials. Sources and their suppliers in SMAQMD are now working in earnest to make this transition. As was noted by Mr. Bonetto during discussions, there are other promising materials being developed,

such as surfactant-based cleaners.

Comment #2: PIC recommends that the District revise the definition of “Other On-Press Components” in Rule 450 to exclude dampening rollers, fountains, impression cylinders, and plates. The definition of “Removable Press Components” excludes these items.

Response: Staff intended to exclude dampening rollers, fountains, impression cylinders, and plates from the definition of “Removable Press Components” in order for these items to be subject to the requirements for “Other On-Press Components.” Staff has revised the definition of “Other On-Press Components” to explic itly state that these items are

included.

Comment #3 PIC recommends that the District reduce the VOC limits for in Rule 450 for the non-newsprint cleaning of blankets, rollers, metering rollers/printing plates, and other on-press components in two steps; first to less than 500 g/l one year after the effective date, and then to 100 g/l one year after the first date. This would give printers time to adjust to working with these low-VOC solvents. No other district attempted to move from the current limit to less than 100 g/l. It is hard to get these low-VOC solvents to work. The stepping down allows printers to become familiar with how lower solvent work and prepares them for less than 100 g/l limit. In doing so, SMAQMD would have extended the Effective Date of the 100 g/l by only six months to around July 2010. Please seriously consider this request.

Response: Staff has delayed the effective date for these categories to January 1, 2011, giving sources additional time as requested to address issues that printers in SCAQMD currently encounter in their transition to the use of

low-VOC solvents.

Staff did not include an additional interim limit in the rule as requested. It has been determined that many sources (including the largest printing establishments) are already using solvents containing less than 500 g/l of VOC. Establishing an interim limit of 500 g/l without a vapor pressure option, thereby replacing the current limit 300 g/l with a vapor pressure option, for the above categories could constitute a relaxation of the current requirements. Since many sources are already phasing to lower VOC products with the current limits in place, staff did not include this PIC proposed limit.

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Comment #4: PIC requests the removal of Section 302.2 in Rule 450, which specifies a 15% usage limit for solvents used for cleaning metering rollers and printing plates. No other air district in the nation has this standard. It is also more difficult to find an effective low-VOC solvent for metering rollers/printing plates than for rollers/blankets, and because of this, printers will have no incentive to use lower VOC solvents because it will exceed the usage percentage for metering rollers/printing plates. PIC suggests establishing the same VOC limit for metering rollers/printing plates as for On-Press Components. It follows that Section 501.3(b)(4) (in which sources are required to keep monthly records showing the percentage of materials used for cleaning metering rollers/printing plates according to Section 302.2) should also be removed if the District grants PIC’s request for the removal of Section 302.2.

Response: We agree with many of the issues raised and have made the following change. Section 302.2 now has a proposed sunset date of January 1, 2011, when the non-newsprint VOC limits for blanket/roller washes, metering rollers/printing plates, and other on-press components become effective. The VOC limits for all three of these categories will be 100 g/l. To avoid relaxing the 15% usage limit, Section 302.2 will remain in effect

until the 1/1/11 effective date for the three VOC limits mentioned above.

Under the proposed Rule 450, printers that use the same solvent for both metering rollers/printing plates and blankets/rollers and meet the 100 g/l limit for both materials are exempt from the 15% requirement.

Comment #5: Sources should not be required to retain their records for more than 2 years, as required in the proposed Rule 450 (Section 501.5). It is unreasonable for and especially burdensom e on small businesses, which are now being asked to retain records for 5 years, equivalent to the EPA requirements for Title V sources. Ninety percent of all printing companies in SMAQMD have fewer than 15 employees.

Response: The proposed requirement for sources to retain records for 5 years is intended to be a means of standardizing the record retention requirements for all of the solvent cleaning rules. Several rules, such as Rule 450, already currently require record s to be kept for at least 5 years. The proposed rules are expected to be SIP-approved by EPA, rendering them federally enforceable rules. Requiring records to be kept for 5 years ensures consistency with federal statute of limitations of 5 years for acting upon a rule violation.

Comment #6: Since the District is proposing to delete the vapor pressure requirement in Rule 450 on 1/1/2010, Section 502.7 should also be deleted.

Response: Section 502.7 specifies the method of determining vapor pressure.

Section 502.7 must remain in Rule 450 at least until 1/1/2011. The majority, but not all, of the vapor pressure requirements will be removedon 1/1/2010. Vapor pressure will remain a compliance option for nonnewsprint substrates and for screen printing until 1/1/2011.

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Comment #7: The District should reconsider its decision to remove the vapor pressure compliance option. PIC and SCAQMD had agreed in discussions during the 10/8/1999 amendments to SCAQMD Rule 1171 that a study should be conducted to ascertain the relationship between vapor pressure and VOC mass emission rates. SCAQMD produced an inadequate study, however, since the study addressed how vapor pressure affects total mass emissions rather than emission rates as agreed upon during the discussions. SCAQMD based its decision to remove vapor pressure on its conclusion that lower vapor pressure do not lead to lower mass emissions, but acknowledges that lower vapor pressure does lead to lower mass emission rates. PIC agrees with the latter conclusion, and disagrees with SCAQMD’s decision to remove vapor pressure based on

total mass emissions.

It is also baffling that SCAQMD did not follow the solvent cleaning requirements set by EPA, which rec ognizes and supports the use of low vapor pressure cleaning solvents in several EPA documents. The EPA document entitled “Technical Support Document (TSD) for Title V Permitting of Printing Facilities (January 2005)” encourages the use of low vapor pressure products as a means of reducing emissions at a particular source.

Response: South Coast’s studies focused on total mass emissions while PIC focuses on the mass emission rates. While low vapor pressure solvents may evaporate at a slower rate, the SCAQ MD study showed that all of the solvent eventually evaporates. Si nce solvent eventually evaporates, setting a lower VOC limit will reduce furt her what is eventually emitted to the air than setting a low vapor pressure limit.

In addition, even if we agreed with PIC’s focus on emission rates, low vapor pressure limits do not reduce emissions equivalent to the low-VOC limits being proposed. EPA’s document, Control Techniques Guidelines for Offset Lithographic Printing and Letterpress Printing (2006) recommends the use of low vapor pressure cleaning materials (specified in the CTG as having a vapor pressure of less than 10 mm Hg at 20 °C),

and that the use of such materials results in an emission reduction comparable to using materials with 30% VOC by weight (or approximately 240 g/l of VOC). However, the proposed limits in Rule 450 of 25 g/l VOC for general cleaning and 100 g/l for blanket and roller washes, metering rollers, printing plates, and other on-press components are lower than CTG limits and, therefore, will lead to greater emission reductions than low vapor pressure solvents. Furthermore, stand-alone VOC limits (without vapor pressure as a compliance option) have already been demonstrated to be feasible in SCAQMD, and some sources in Sacramento County are already using cleaning materials that comply with

these limits.

Comment #8: PIC believes that looking at just VOC content may likely result in higher consumption of materials and consequently, the creation of greater waste

streams.

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Response: Some of the compliant cleaning options, such as the impregnated cloth cleaning systems already in use at some Sacramento County sources, consume much less cleaning material than the previous cleaning techniques. Nevertheless, sources subject to Rule 450 are also required to comply with applicable state and federal regulations concerning the proper handling and disposal of hazardous waste.

Letter from Al Batakji, Teledyne MEC (January 31, 2007)

Comment #1: Teledyne MEC requests an exemption in Rules 454 and 466 for high voltage microwave tubes or rule language stating that alternative compliance in Rule 107 may be applied to high voltage microwave tubes. (Teledyne had previously been granted a variance to allow Alternative Compliance pursuant to Rule 107.) Our small scale operation manufactures high voltage microwave tubes, which are the principal components of electronic radar jamming dev ices that are used primarily in military aircraft and vessels to protectively disable incoming missile guidance systems. The use of 100% anhydrous isopropyl alcohol (IPA) has proven for decades to be the most effective cleaning and degreasing solvent for such complicated and expensive assemblies ($15,000 each) in that it produces the least number of rejected assemblies or those that fail during use. In contrast, the use of an IPA/acetone blend has demonstrated in testing to result in twice the number of device rejects,

due to increased residue retention on critical surfaces of the assemblies. Teledyne MEC has undergone extensive efforts to identify comparable alternatives to IPA, but no such solvent or blend has been found that cleans as effectively. To support the fact that 100% anhydrous IPA removes residue and other potential contaminants more effectively than alternatives, we have included reports from our own investigations, from component vendors, and from our mass spectrometry study of vacuum tube surfaces when exposed to different solvents. The airtight/airless cleaning system allowed in Rule 454 is not an option either because it would be impractical and infeasible to employ such a system to capture emissions from such operations, which involve hand manipulation of very small parts during cleaning and assembly. We estimate that such an exemption would lead to an increase of only 25 pounds of VOC emissions per operating day.

Response: Staff has reviewed the technical information submitted by Teledyne pertaining to the cleaning of high voltage microwave tubes. Staff also reviewed rules in other districts where such devices are produced, and determined that the cleaning of such devices with high VOC solvents is allowed under existing rules for aerospace assembly operations. Staff acknowledges that these types of assemblies require high VOC products to clean them effectively and has proposed exemptions in Rule 454 and

456.

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Letter from Chelsea Sand, Aerojet (May 19, 2008)

Comment #1: Aerojet requests a minimum delay of 2 years from rule adoption in the proposed effective date for Section 304.4 of Rule 456, which will reduce the VOC limit for application equipment cleanup from 200 g/l to 25 g/l and eliminate the enclosed gun cleaner compliance option. Aerojet is also requesting the retention of the enclosed gun cleaner compliance option, which is a critical compliance tool currently for Aerojet and achieves the same reductions as the reduced VOC limit. Aerojet is concerned about the proposed requirement for a number of reasons. These changes will cause Aerojet to place a heavier reliance on exempt solvents, particularly acetone, or an acetone-based material, which will have negative health and safety impacts (such as fire hazards) and will be restricted based on Environmental Health and Safety risks. There are no known commercially available products that achieve 25 g/l and can effectively cleaning aerospace coatings. A very limited number of substitute, compliant solvents are available that thoroughly clean multi-part epoxies and polyurethane containing materials. There is not enough time given by SMAQMD to test and requalify substitute solvents by the proposed effective date of this rule change. (This research process can potentially last a minimum of 36 months without any guarantee of successfully finding an alternative product.) Based on preliminary discussions with our suppliers, suitable replacements may not even exist. Aerojet would incur additional costs associated with the work to requalify and incorporate the replacement solvents, costs related to reduced productivity and throughput from diverting resources to this research of solvents, as well as the high costs of the replacement solvents themselves. If acetone is used, additional costs would come from controlling hazards in both explosive and inert operating areas and replacing damaged equipment as the result of applying acetone. Aerojet’s strict standards on health and safety rule out the use of all other SMAQMD exempt compounds. The aerospace facilities in SCAQMD, which were used as the basis for the compliance costs associated with achieving the 25 g/l limit in SCAQMD Rule 1171, are much smaller than the Aerojet campus in Sacramento and have far fewer spray booths. Therefore, it is inappropriate to assume that the same compliance costs in SCAQMD (which were based on the cost of acetone) could be applied to our facility. A delay in the rule effective date will allow Aerojet adequate time to conduct the necessary research for alternative products. Retention of the enclosed gun cleaner option will allow Aerojet to use this option to effectively clean spray guns and long booms/wands (also currently a SMAQMD approved technique).

Response: Staff now proposes to retain the enclosed gun cleaner option until the proposed sunset date of two years from rule adoption. Delaying the sunset date for the enclosed gun cleaner option will allow Aerojet and other affected sources to continue to use this option while giving sufficient time for a suitable, low-VOC alternative solvent to be found and successfully implemented.

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Letter from Andrew Steckel, EPA Region 9 (August 18, 2008)

Rule 450

Comment #1: Potential Approvability Issue: The 2006 CTG for Offset Lithographic Printing and Letterpress Printing recommends a 1.6 percent alcohol by weight fountain solution for heatset web offset lithographic printing, a 5 percent alcohol by weight for sheet-fed offset lithographic printing, and 5 percent alcohol substitute or less and no alcohol in the fountain solution for coldset web offset lithographic printing. For heatset web and sheet-fed printing, the CTG provides different approaches for achieving the recommended level of control. The 100 g/L VOC limit for chilled fountain solutions and 80 g/L limit for non-chilled fountain solutions in Section 301.2 are not as stringent as the CTG recommendations. Please include requirements that are as stringent as the CTG recommendations.

Response: Staff has revised proposed Rule 450 to conform to all of the recommendations in the 2006 CTG for Offset Lithographic Printing and Letterpress Printing. Refer to the Summary of Requirements section of this staff report for further details.

Comment #2: Potential Approvability Issue: The 2006 CTG for Offset Lithographic Printing and Letterpress Printing recommends a control device with an overall control efficiency of 90% or 95% for heatset web offset lithographic printing depending on the first installation date of the control device, and also recommends that the dryer be operated at negative pressure. While Section 303.2.a requires a control device efficiency of at least 95%, Section 303.2.b requires an emission collection efficiency of at least 70%. The 70% emission collection efficiency requirement is not as stringent as requiring the dryer to operate at negative pressure. Please include requirements that are as stringent as the CTG recommendations.

Please note that the CTG does not recommend that heatset web sources be allowed to use graphic art printing materials (inks and varnishes) with a certain VOC content instead of using an add-on control device. Please change rule requirements to allow heatset web sources to comply only by using control technology that has an overall capture and control efficiency that's equivalent to CTG recommendations or demonstrate that compliance with the VOC content limits is equally as stringent.

Response: See response to EPA comment #1. Staff has revised proposed Rule 450

to conform to the recommendations in the 2006 CTG for Offset Lithographic Printing and Letterpress Printing, including requirements for overall system efficiency (which combines capture and control). The proposed rule is now as stringent as the CTG recommendations. Refer to the Summary of Requirements section of this staff report for further

details.

Comment #3: Potential Approvability Issue: The 2006 CTG for Flexible Package Printing, depending on first installation date of the press and add-on control device, recommends an overall capture and control efficiency of up to 80%. Section 303.2 requires an overall capture and control

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efficiency of only 67%. As an alternative to meeting the applicable capture and control efficiency, the CTG recommends that materials be used that meet the following limits: .8 kg VOC/kg solids applied or .16 kg VOC/kg materials applied. Please include requirements that are as stringent as

the CTG recommendations.

Response: Staff has revised proposed Rule 450 to conform to the recommendations in the 2006 CTG for Flexible Package Printing. Staff is not proposing to include the following less stringent overall system efficiencies specified below because these requirements would not apply to any existing or

future sources.

• 65% overall control for a press that was first installed prior to March 14,

1995 and that is controlled by an add-on air pollution control device whose first installation date was prior to the effective date of the State

RACT rule. • 75% overall control for a press that was first installed on or after March

14, 1995 and that is controlled by an add-on air pollution control device whose first installation date was prior to the effective date of the State

RACT rule.

The option to use the low VOC materials in lieu of emissions control equipment was not included in the proposed rule. Staff determined that this compliance option is not necessary for any existing District sources and that it is unlikely that any future sources would need this compliance option. Refer to the Summary of Requirements section of this staff report

for further details.

Comment #4: Recommendation: Section 110.1 exempts any graphic art operation that has actual emissions of less than or equal to 60 pounds per calendar month. As noted in CARB's April 24 comments, VCAPCD Rule 74.19 contains a current exemption limit of 200 pounds per rolling 12-month period. The SJVUAPCD is currently workshopping their Rule 4607 and also intends to lower their exemption to graphic arts operations which emit less than 200 pounds per 12 rolling consecutive calendar months. Please consider making Rule 450 limits as stringent.

Response: See response to CARB comment #1. The VCAPCD Rule 74.19 exemption specifies 200 pounds per rolling 12-month period, but the exemption does not include VOC emissions from aerosol products, cold cleaners, and vapor degreasers in this determination. Also the VCAPCD rule includes an exemption for circuit board printing and specifies VOC limits for cleaning materials and printing adhesives that are higher than those specified in proposed Rule 450. Collectively, the exemptions and proposed VOC limits in proposed Rule 450 will deliver greater emission reductions than that achieved by implementing the recommended VCAPCD exemption level and limits. Therefore, this change to the exemption level is not recommended.

Comment #5: Recommendation: The VOC limit for “Extreme Performance Ink/Coating” for screen printing is currently 800 g/L. SJVUAPCD Rule 4607 and

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BAAQMD Rule 8-20 both limit the VOC content for this category to 400 g/L. Please consider making Rule 450 limits as stringent.

Response: See response to CARB comment #2. SJVUAPCD Rule 4607 includes an exemption for facilities that emit less than 400 pounds of VOC per calendar month, which is less stringent than the exemption level in proposed Rule 450. Also, proposed Rule 450 includes several VOC limits for solvent cleaning that are lower than those in SJVUAPCD Rule 4607. The 2002 emissions inventory for screen printing inks and coatings is only 0.07 tons per day of VOC. Staff has determined that lowering the VOC limits for the above categories will have minimal impact on overall emissions, and is not proposing to lower these limits.

Comment #6: Recommendation: The VOC limit for “Sign Ink/Coating” for screen printing is currently 500 g/L. Both SJVUAPCD Rule 4607 and BAAQMD Rule 8- 20 limit the VOC content for this category to 400 g/L. Please consider making Rule 450 limits as stringent.

Response: See response to CARB comment #2. SJVUAPCD Rule 4607 includes an exemption for facilities that emit less than 400 pounds of VOC per calendar month, which is less stringent than the exemption level in proposed Rule 450. Also, proposed Rule 450 includes several VOC limits for solvent cleaning that are lower than those in SJVUAPCD Rule 4607. The 2002 emissions inventory for screen printing inks and coatings is only 0.07 tons per day of VOC. Staff has determined that lowering the VOC limits for the above categories will have minimal impact on overall emissions, and is not proposing to lower these limits.

Rule 451

Comment #7: Potential Approvability Issue: Section 111.9 exempts conformal coatings. This exemption is not recommended in applicable CTGs. Please demonstrate that Rule 451 meets RACT even though this exemption is not recommended in applicable CTGs.

Response: The exemption for conformal coatings was adopted in the 2/23/93 amendment of Rule 451, in response to comment letters from industry submitted in the previous year. A letter from a process engineer with a paints and depaints company requested this exemption in order to clarify that such coatings are not categorized under electrical insulating coatings, which are subject to rule requirements. In her letter, the engineer stated that conformal coatings are applied to circuit boards, which usually contain very closely spaced circuits, and that moisture, corrosion, or fungi/bacteria can cause a short circuit and eventually result in catastrophic failure of the associated equipment. The District staff report for the 2/23/93 amendments states that this exemption was added for clarity because coating of printed circuit boards is regulated under a separate rule (referring to Rule 456, which was amended on the same date and includes a VOC limit for aerospace conformal coatings). A 10/7/93 District letter to EPA explains that, at the time, survey results indicated that no non-aerospace operations in Sacramento County

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applied conformal coatings. That is still the case today. Therefore, in response to this comment, Staff is proposing to limit the conformal coating exemption to those coatings regulated by Rule 456.

Comment #8: Potential Approvability Issue: We understand that Rule 451 includes coating emission limits for metal furniture operations. Please ensure that Rule 451 requirements are as stringent as the recommendations in the 2007 Metal Furniture Coatings CTG. Certain limits in the VOC content table in Section 301 are less stringent than the recommend emission limits for various coating categories in the 2007 Metal Furniture Coatings CTG (e.g., the VOC table in the rule has a 3.5 lb/gal air dried limit for extreme high gloss coatings whereas the CTG recommends a 2.8 lb/gal air dried limit for the same category). Moreover, the CTG recommends an overall capture and control efficiency of 90% whereas Section 305 only requires an overall capture and control efficiency of 85%. The CTG also recommends work practice standards for both coating and cleaning activities, whereas the rule only contains work practice standards for surface preparation and clean-up in Section 304.

Response: Staff has revised proposed Rule 451 to conform to all of the recommendations in the 2007 CTG for Metal Furniture Coatings. Refer to the Summary of Requirements section of this staff report for further

details.

Comment #9: Recommendation: SCAQMD Rule 1107 has lower limits for the extreme high gloss, extreme performance, pre-fabricated architectural component, and general one-component coating categories. Please consider making Rule 451 limits as stringent as Rule 1107 for these categories.

Response: See response to EPA comment #8. Staff has revised proposed Rule 451

to conform to the recommendations in the 2007 CTG for Metal Furniture Coatings, including lowering the VOC limits for high-gloss, extreme performance, and general one-component coatings applied to metal

furniture.

The projected 2018 inventory for other metal parts and products coatings is only 0.09 tons per day of VOC. Rule 451 contains two categories, camouflage coatings and electrical insulating coatings, with limits that are more stringent than SCAQMD Rule 1107. In addition, SCAQMD Rule 1107 contains more specialty coating categories, with higher VOC limits than are allowed under the “All Other Coatings” category of Rule 451. For these reasons, Staff determined that, as potential all-feasible measures, lowering the VOC limits for the coatings applied to other miscellaneous metal parts and products will have an insignificant impact on overall emissions. Therefore, Staff is not proposing to lower these

VOC limits at this time.

Rule 452

Comment #10: Potential Approvability Issue: Unlike similar rules in other areas, Rule 452

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does not require sources to use specific coating application methods (see, for example, Section (c)(4) of South Coast Air Quality Management District (SCAQMD) Rule 1125 and Section 5.6.2 of San Joaquin Valley Air Pollution Control District (SJVUAPCD) Rule 4604). Please add provisions to Rule 452 that specify appropriate coating application

methods.

Response: Staff has added a new section that provides a list of approved coating application methods. This added section is the same as Section 303 in Rules 451 and 456, and includes an additional option to an air pollution control device with an overall control efficiency of at least 85.5%. Definitions for each method (roll coater, dip coat, electrostatic spray, flow coat, HVLP and LVLP application equipment, and hand application equipment) have also been added.

Comment #11: Potential Approvability Issue: We noticed that there were several other California rules that had more stringent requirements than Rule 452. Please explain why each of the following more stringent requirements are not feasible in Sacramento or change Rule 452 to be equally as stringent:

• The VOC limit for end sealing compound is 440 g/L. BAAQMD Rule 8-11 and SJVUAPCD Rule 4604 have a 60 g/L limit for drum, pail and lid end sealing compounds, and a 20 g/L limit for end sealing compounds in all other categories.

• SCAQMD Rule 1125 has a 20 g/L limit for end sealing compounds for food/beverage cans and a 0 limit for end sealing compounds

for non-food containers.

• The VOC limit for three piece can interior body spray is 510.
BAAQMD Rule 8-11 and SJVUAPCD Rule 4604 both have a 360 g/L limit for this category.

• The VOC limit for two piece can interior body spray is 440.
BAAQMD Rule 8-11 and SJVUAPCD Rule 4604 both have a 420 g/L limit for this category.

• Section 302.1 requires an overall 85% capture and control efficiency for add-on control devices. BAAQMD Rule 8-11 and SJVUAPCD Rule 4604 both require an overall 90% capture and control efficiency.

Response: Staff has revised proposed Rule 452 to include all of the recommended changes. Refer to the Summary of Requirements section of this staff report for further details.

Comment #12: Recommendation: Section 302 allows sources to comply with the use of an add-on control device only if emissions do not exceed the level which would be achieved from the equivalent use of compliant coatings. However, Rule 452 does specify how to calculate whether the control device is achieving emission reductions that would be equivalent to using compliant coatings. We recommend adding a section that's similar to

SJVUAPCD Rule 4604 Section 5.2.9.

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Response: Staff has added a new section that provides an equation for calculating emissions equivalency. This added section is the same as Section 304.3 in the proposed Rule 466.

Rule 454

Comment #13: Recommendation: Section 304.1 gives sources the option of complying with rule requirements by operating a vapor degreaser with a water separator. We recommend adding a definition for water separator. See SCAQMD Rule 1122 Section (b)(40) for potential draft rule language.

Response: Staff has added a definition for “water separator,” consistent with the one
in SCAQMD Rule 1122.

Comment #14: Recommendation: Rule 454 requires that airtight/airless cleaning systems not have a vapor leak of more than 50 parts per million measured as methane at the outlet of the airtight/airless cleaning system. SCAQMD Rule 1122 section (f)(4) requires that airless/air-tight equipment be maintained in a vapor-tight, leak-free condition and states that any leak is a violation. Please consider whether a similar provision would strengthen

Rule 454.

Response: SCAQMD Rule 1122 does not define w hat constitutes a vapor-tight, leakfree condition. Staff therefore considers Rule 454 to be as stringent as SCAQMD Rule 1122 in regards to requiring leak-free airtight/airless cleaning systems.

Rule 456

Comment #15: Recommendation: Section 302 limits the VOC content of strippers to 300 g/L of VOC per liter of material. Section B.6 of Imperial Rule 425 limits the VOC content of strippers to 200 g/L. Please consider inserting this lower

limit into Rule 456.

Response: Imperial County APCD Rule 425 exempts stationary source using less than 3 gallons per day of aerospace coatings, which is equivalent to 1,095 gallons per year. Proposed Rule 456 exempts sources using less than 55 gallons per year of aerospace materials, including coatings and strippers. Because District sources use less coating volume than Imperial County’s exemption level, the combination of the exemption level and VOC limits in proposed Rule 456 is more stringent and will lead to greater

emission reductions.

Comment #16: Recommendation: The current limit for adhesives is 600 g/L. SJVUAPCD Rule 4605 has three different categories for adhesives - non-structural adhesives with a 250 g/L limit, structural autoclavable adhesives with a 50 g/L limit, and structural nonautoclavable adhesives with a 850 g/L limit. Please consider whether including a category for non-structural

adhesives or structural autoclavable adhesives would allow the District to

obtain additional emission reductions.

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Response: SJVUAPCD Rule 4605 exempts aerospac e coating operations using less than 4 gallons per day of aerospace materials, which is equivalent to 1,460 gallons per year. Proposed Rule 456 exempts sources using less than 55 gallons per year of aerospace materials. Because District sources use less coating volume than San Joaquin’s exemption level, the combination of the exemption level and VOC limits in proposed Rule 456 is more stringent and will lead to greater emission reductions.

Comment #17: Recommendation: The current limit for adhesive bonding agents is 780 g/L. SJVUAPCD Rule 4605 has six different categories for adhesive bonding primer, three with a 250 g/L limit, and three with a 805 g/L limit. Please consider if including additional categories that have a 250 g/L limit

would allow the District to obtain additional emission reductions.

Response: See response to EPA comment #16. SJVUAPCD Rule 4605 exempts aerospace coating operations using less than 4 gallons per day of aerospace materials, which is equivalent to 1,460 gallons per year. Proposed Rule 456 exempts sources using less than 55 gallons per year of aerospace materials. . Because District sources use less coating volume than San Joaquin’s exemption level, the combination of the exemption level and VOC limits in proposed Rule 456 is more stringent and will lead to greater emission reductions.

Rule 463

Comment #18: Potential Approvability Issue: Section 306 provides for a rolling 30 day averaging period for compliance with the rule's emission limits. From conversations with the District, we understand that only one very small source that refinishes antiques is currently utilizing this averaging provision. We are aware of no other areas that have SIP approved rules with such an extensive compliance period for wood coatings. Though we recognize that rules in other areas that have daily or no averaging provisions might be less stringent than Rule 463 in some other respects, we recommend the District remove this provision. However, if the District significantly narrows the scope of the provision (e.g., to very small sources refinishing antiques), we believe that the District can utilize our 1% Screening Analysis (see December 2002 Memo from Andrew Steckel) to demonstrate that the averaging provision does not cause the rule to deviate from RACT or affect attainment of the eight hour ozone

standard.

Response: The only wood coating facility that currently uses this emissions averaging provision performs restorations of historical antique wood products. Based on the EPA recommendations above, Staff proposes to limit the applicability of this emissi ons averaging provision to this wood facility, and limit the total annual usage of such coating products to 20 gallons per year. Using the 1% screening analysis, Staff was able to show that the emissions benefits from removing the averaging provision (and thus having this facility subject to the VOC limits in this rule) represent only 0.04% of baseline emissions, which is much less than 1%. Refer to the Summary of Requirements section of this staff report for

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further details.

Comment #19: Potential Approvability Issue: Please demonstrate that Rule 463 meets RACT though the exemption for military stencil coatings in Section 110.5 is not in the 1996 Wood Furniture Manufacturing CTG.

Response: Staff proposes to remove Section 110.5 in proposed Rule 463. The military facility that used this exemption is no longer in operation.

Comment #20: Recommendation: Section 110.4 exempts the coating of architectural components or structures, not coated in a shop environment. We recommend that the District add rule language to Section 110.4 to clarify that the exempted wood products are still subject to the requirements in the District's architectural coatings rule.

Response: Staff has added rule language clarifying that such components and structures are subject to Rule 442.

Comment #21: Recommendation: The VOC limit for strippers is 350 g/l. San Diego County Air Pollution Control District (SDAPCD) Rule 67-11 Section (d)(5)(i) has a limit of 200 g/l for strippers. We recommend that the district

include this lower limit in the rule.

Response: See response to CARB comment #10. SDAPCD Rule 67-11 includes an exemption for sources with coating usage levels below 500 gallons per year, while Rule 463 exempts sources with coating usage levels less than 55 gallons per year. The District exemption is more stringent than the SDAPCD exemption, and therefore Staff is not proposing to lower the VOC limit for strippers.

Comment #22: Recommendation: Section 306 provides for a rolling 30 day averaging period for compliance with the rule's emission limits. Please confirm that District policy interprets any violation of the averaging period as a violation of each day of the averaged period. EPA recommends inserting language similar to the following to clarify this in the rule: “Any rolling 30- day averaged value which exceeds the applicable emission limit shall constitute a violation of the rule for each day of the averaged period.”

Response: Staff now proposes to insert rule language in Rule 463 as requested.

Comment #23: Sources using less than 55 gallons per year of wood product coatings and/or strippers are exempt from th e requirements of this rule. BAAQMD Rule 8-32, SJVUAPCD Rule 4606, and Santa Barbara County Air Pollution Control District (SBAPCD) Rule 351 limit this exemption to 20 gallons per year. Please consider making Rule 463 as stringent.

Response: See response to CARB comment #8. Unlike Rule 463, the rules at other air districts that contain this 20 gallon/year exemption do not establish VOC limits for refinishing of wood products. Staff is proposing to maintain the current exemption level with the existing and proposed VOC limits for refinishing and repairing, which will collectively deliver greater VOC

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reductions than the requirements in other districts.

Comment #24: The VOC limit for “High-Solid Stain” in Section 302.2 is 350 g/l. SJVUAPCD Rule 4606, SBAPCD Rule 351, and VCAPCD Rule 74-30 all have a limit of 240 g/l for this category. Please consider making Rule 463 as stringent.

Response: See response to CARB comment #9. Staff determined that, as potential all-feasible measures, lowering the VOC limits for high-solid stains and sealers to the most stringent limits in the San Joaquin and Ventura County rules would reduce VOC emissions by less than 0.02 tons per day. Therefore, Staff is not proposing to lower these limits.

Comment #25: Recommendation: The VOC limit for “Sealer” in Section 302.2 is 275 g/l. VCAPCD Rule 74-30 has a limit of 240 g/l for this category. Please consider making Rule 463 as stringent.

Response: See response to CARB comment #9. Staff determined that, as potential all-feasible measures, lowering the VOC limits for high-solid stains and sealers to the most stringent limits in the San Joaquin and Ventura County rules would reduce VOC emissions by less than 0.02 tons per day. Therefore, Staff is not proposing to lower these limits.

Rule 464

Comment #26: Recommendation: While the recordkeeping provisions in Section 501.4 through Section 501.7 require sources to keep daily records on-site of the types and amounts of organic compounds used for continuous processes as well as information about each production batch for batch processes, they do not specifically require sources to record the VOC content of the materials used. We recommend adding a recordkeeping requirement specifically for the VOC content of materials used.

Response: Staff has added recordkeeping requirements for the VOC content of materials used in the proposed Rule 464.

Rule 465

Comment #27: Potential Approvability Issue: We noticed several other California rules have more stringent requirements than Rule 465. Please explain why having the following more stringent requirements is not feasible or change Rule 465 to be equally as stringent:

• Section 301.1.a.1 requires that general resins have a monomer content of no more than 35%. Ventura County Air Pollution Control District (VCAPCD) Rule 74.14 and SCAQMD Rule 1162have replaced the general purpose resin category with four subcategories: marble resins (10% monomer content or 32% as supplied, no fillers), solid surface resins (17% monomer content), tub/shower resins (24% monomer content or 35% as supplied, no

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fillers), and lamination resins (31% monomer content or 35% as supplied, no fillers).

• Section 301.1.a.2 requires that pigmented gel coats have a

monomer content of no more than 45%. VCAPCD Rule 74.14 and SCAQMD Rule 1162 have replaced the limit for pigmented gel coats with lower limits in three sub-categories: white and off white (30% monomer content), non-white (37% monomer content), and primer (28% monomer content).

• Section 301.1.a.3 requires that specialty resins and clear gel coats

have a monomer content of no more than 50%. Rule 74.14 and SCAQMD Rule 1162 have replaced the limit for clear gel coats with two sub-categories that have lower limits: marble resins (40% monomer content) and other resins (44% monomer content). Rule 465 defines specialty resins as "any...resin used to make product for exposure to one or more of the following extreme environmental conditions: acute or chronic exposure to corrosive agents, caustic agents, acidic agents, or flame." Both Rule 74.14
and SCAQMD Rule 1162 also have 38% monomer content limit for fire retardant resin, 48% monomer content limit for corrosion resistant resin, and 40% monomer content limit for high strength

resin.

• Section 301.2 requires that emission control systems have an overall 85% control efficiency. Rule 74.14 and SCAQMD Rule 1162 both require an overall capture and control efficiency of 90%.

Response: EPA identified this as a potential approvability issue based on the fact that there is a polyester resin operation within the District that will become a major source of VOC if the District “bumps up” to a classification of severe nonattainment, as expected. Section 182(b)(2) of the federal Clean Air Act requires RACT for all major sources of VOC and all source categories for which EPA has promulgated a CTG. In recent discussions with the source, however, Staff has learned that the source is in the process of submitting an application to modify the permit to limit the potential-to-emit to less than 25 tons per year. In light of this development and because polyester resin operations is not a CTG category, Staff believes that this should no longer be considered a RACT/approvability issue. As potential all-feasible measures, Staff determined that lowering the VOC limits to those contained in the South Coast and Ventura County rules will only reduce VOC emissions by 0.1 tons per day. Therefore, Staff is not proposing to lower these limits. However, Staff is proposing to increase the required overall capture and control efficiency to 90%.

Rule 466

Comment #28: Potential Approvability Issue: The VOC standards table in Section 301 allows for different limits for the solvent cleaning of architectural coating

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application equipment for water based coatings and solvent based coatings. Until one year after rule adoption, for water based coatings, cleaning without an enclosed gun cleaner has a 50 g/L limit, whereas for solvent based coatings, cleaning without an enclosed gun cleaner can have a limit up to 300 g/L.

In order to ensure that these limits are enforceable, please define water based coating and solvent based coating. Also, under solvent based coatings, cleaning architectural coating equipment without an enclosed gun cleaner at the jobsite has a 300 g/L limit whereas cleaning architectural coating equipment without an enclosed gun cleaner not at the jobsite has a 50 g/L limit. In order to ensure that these limits are enforceable, please define job-site in the rule.

Response: Staff has added definitions for “water based coating,” “solvent based coating,” and “jobsite.”

Comment #29: Recommendation: Section 110.4 exempts the cleaning of the nozzle tips of automated spray equipment from the requirements of Section 302.2. Section 302.2 is one of many options that sources can pick from in order to be in compliance with the rule's requirements for cleaning devices and

methods. Please ensure that the reference in Section 110.4 to Section

302.2 is correct.

Response: The reference to Section 302.2 is incorrect. Section 110.4 was intended to exempt such cleaning from the requirements in Section 302 as a whole, not only the one option indicated in the current Rule 466. Staff has corrected this typographical error.

Comment #30: Recommendation: The District is widening the applicability of the rule by including VOC content limits for the sterilization of food manufacturing and processing equipment. We recommend clarifying this in Section 102, Applicability.

Response: Staff has added this clarification to the Applicability section of proposed

Rule 466.

Comment #31: Recommendation: To further clarify the applicability of the VOC limits in table 301.1, we recommend adding a definition for pharmaceutical product and general work surfaces. Potential draft language can be found
in SCAQMD Rule 1171.

Response: Staff has added definitions for these terms, consistent with those specified in SCAQMD Rule 1171.

Letter from Don Eggleston, Office of State Publishing (August 20, 2008)

Comment #1: OSP requests the removal of Section 302.2 in Rule 450, which specifies a 15% usage limit for solvents used for cleaning metering rollers and printing plates. OSP has been using new lower-VOC blanket wash for the last two months and discovered that smaller quantities of this wash

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are needed to do the job when compared to washes previously used. This transition has already made a substantial impact on reduction of VOC emissions and waste generation at OSP. Unfortunately, this situation creates solvent usage ratios that exceed the 15% limit because our plate cleaner and metering roller cleaner usage is relatively the same

from month to month.

Response: Section 302.2 now has a proposed sunset date of January 1, 2011, when the non-newsprint VOC limits for blanket/roller washes, metering rollers/printing plates, and other on-press components become effective. The VOC limits for all three of these categories will be 100 g/l. To ensure equivalency with the 15% usage limit, Section 302.2 must remain in effect

until the 1/1/11 effective date for the three VOC limits mentioned above.

Section 110.8 of proposed Rule 450 provides an exemption from the 15% usage limit for presses that use materials for cleaning metering rollers and printing plates containing 100 g/l of VOC or less.

### Larry Greene

AIR POLLUTION CONTROL OFFICER

777 12 th Street, 3 rd Floor * Sacramento, CA 95814-1908

916/874-4800 * 916/874-4899 fax www.airquality.org 

### May 18, 2009

Mr. Michael Guzzetta Stationary Source Division

California Air Resources Board

PO Box 2815 Sacramento, CA 95812

Subject: State Implementation Plan Revision, SMAQMD Rule 454

Dear Mr. Guzzetta:

Enclosed is the information necessary for submittal of Rule 454, Degreasing Operations, for revision to the State Implementation Plan. Rule 454 was amended by the District’s Board of Directors on May 23, 2002, and recently amended again on September 25, 2008. Please also

forward the information for this submittal to U.S. EPA.

If you have any comments or questions, please contact me at (916) 874-4851.

Sincerely,

Kevin J. Williams, Ph.D. Program Coordinator (sent via e-mail)

Attachments:

1. SIP Checklist Rule 454 2. 2002 Amendments, Underline/Strikeout Version

3. 2008 Final Version of Rule 454
4. 2008 Underline/Strikeout Version of Rule 454

5. Public Notice Evidence

6. Resolution
7. Public Comments

8. Rule Evaluation Form

9. Board Memo


### 10. Staff Report (includes responses to comments)