# Technical **Analysis for Arizona Regional Haze FIPs**  **:**

**Modeling Protocol**  **for Subject -**  **to -** **BART and BART Control Options Analyses**  **Work A ssignment:**  5 - 12 **Contract No:** EP - D - 07 - 102 **Task No :**  5 Version: 3 **Prepared for:** Thomas Webb

Air Planning Office U.S. EPA Region 9 75 Hawthorne Street San Francisco, CA 94105 **Prepared by :**  Uma Shankar , Liz Adams, Mohammad Omary,

Brian Naess , and Sarav Arunachalam Institute for the Environment University of North Carolina at Chapel Hill **Date delivered**  **:** July 16 , 20 1 2

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# Contents **Document Change Record ................................**  **................................ ................................**  **.......... iv**  **1 Introduction**  **................................ ................................**  **................................ ...............................**  **1 2**  **Model Versions ................................**  **................................ ................................**  **.......................... 1**  **3 CALPUFF Modeli** **ng ................................**  **................................ ................................**  **................. 1**  3.1 Meteorological Data ................................ ................................ ................................ ............ 2 3.2 Ozone Data ................................ ................................ ................................ .......................... 2 3.3 Ammonia Inputs ................................ ................................ ................................ .................. 2 3.4 Modeled and Emitted Species ................................ ................................ ............................. 5 3.5 Discrete Receptor Data ................................ ................................ ................................ ....... 5 **4 CALPOST Inputs**  **................................ ................................**  **................................ ......................**  **5** 4.1 Postprocessing of CALPUFF Output ................................ ................................ .................. 5 4.2 Natural Visibility

Conditions ................................ ................................ .............................. 6 4.2.1 IMPROVE Method 6 ................................ ................................ ................................ . 6 4.2.2 IMPROVE Method 8 ................................ ................................ ................................ . 9 **References ................................**  **................................ ................................**  **................................ .....**  **11 Appendix A: BART Subje**  **ct Model Protocol ................................**  **................................ .........**  **A -**  **1 Appendix B:**  **EPA R -**  **9 Guidance on BART Sources and Emissions for**  **Modeling ..............**  **B -**  **1 Appendix C: Natural Background Conditions for IMPROVE Method 6 (received**  **from EPA Region 9) ................................**  **................................ ................................**  **.................. 1**  **Appendix D: Natural Background Conditions for IMPROVE Method 8 (taken from FLAG** **- 2010)**  **................................ ................................**  **................................ ......................**  **1**

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# Document Change Record **Revision Date**  **Remarks** 0.1 March 14, 2012 First (draft) version submitted to EPA 2 .0 June 29, 2012 Ver. 2 submitted to EPA - corrected Appendix B, added this table 3.0 July

16, 2012 Ver. 3 submitted to EPA

– incorporates EPA revisions

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# 1 

# 1 **Introduction** The technical support tasks in Work Assignment (WA) 5 - 12 under EPA Contract Number EP - D 07 - 102 are aimed in part at assisting the EPA Region 9 (Pacific Southwest) Air Division in developing Federal Implementation Plans (FIPs) to establish air quality programs for Arizona pursuant to Clean Air Act (CAA) Section 169A and Regional Haze Rule (RHR) Section 40CFR 51.308. The technical analys is for Arizona’s Regional Haze FIP is focused on performing a Best Avail able Retrofit Technology (BART) analys is and a reasonable progress analysis for potential sources . The CALMET - CALPUFF - CALPOST modeling system will be used to assess the visibility impact of the dispersed pollutant plumes. The purpose of this protocol is to describe the typ es and sources of data to be used in the modeling for this WA , with particular emphasis on the source s of emissions data used and the justification for choosing those data sources . In preparing this protocol, extensive use has been made of the modeling protocol provided in Appendix A , which was followed in previous analys es performed for the Western Regional Partnership (WRAP) of BART - eligible sources in Arizona. Exceptions to procedures and recommendations made in that protocol are noted as required throughout the main body of this document. Further, this protocol reflects our initial approach to modeling, which could be subject to revision as regards additional emission scenarios needed, based upon the findings of the initial analyses. 

# 2 **Model Ve**  **rsions** The WA requires the use of the following EPA - approved versions of the modeling components: (a) CALMET version 5.8, level 070623 (b) CALPUFF version 5.8, level 070623 (c) CALPOST version 6.221 To employ the more recent options to calculate visibility (IMPROVE Method 8) specified in the WA, the CALPOST version used is later than that of the dispersion model. Also note that at the start of this project the specified CALPOST version was not available for download as it had been superseded b y a later version, 6.292. However, v6.292 encapsulates and is compatible with the features of v6.221, and is the version being used in this WA. 

# 3 **CA L**  **PUFF Model ing**  All input settings for the CALPUFF modeling follow the values given in the WRAP Protocol for BART Exemption Screening (WRAP, 2006) as required by the WA with the exceptions per EPA guidance noted in this section . The se default input settings are provided in Table 3 - 3 of WRAP (2006) .

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# 3.1 **Meteorological Data**  CALMET is the meteorological model used to provide meteorological inputs for the CALPUFF modeling. This WA uses readily available CALMET output provided by the EPA from a previous modeling effort by ENSR Corporation, the contractor responsible for BART analys is of the Salt River Pro

ject (SRP)

—

Navajo Generating Station (NGS) Units 1 - 3 near Page , AZ (ENSR, 2009). Thus the analys es to be performed using this protocol are for the same modeling period (2001 - 2003 ) and modeling domain that was used in this previous CALPUFF analys is. The modeling domain is shown as the area within the blue boundary in Figure 1 (ENSR, 2009) ; the WRAP Arizona BART modeling domain is indicated as the area within the red boundary . For reference, the major Class IAreas in Arizona and the six BART sources that are being modeled in this WA are also shown in Figure 2 . The meteorological data for each ye ar of CALPUFF modeling are input hourly, with one input file per month modeled, i .e., the value of NMETDAT is non- zero . The option s to be selected fo r **CALPUFF v5.8** are as follows: METRUN = 0 IRLG = 24 * NDAYS, where NDAYS is the total number of days of meteorological data input The end date and time for the run should be specified in similar format to the beginning date and time. **N.B.:** METRUN = 1 will not work **in this code version** for multiple meteorological input files ; the beginning date and time, end date and time, and number of hours of meteorological data input must be specified . 

# 3.2 **Ozone D** **ata** Background ozone levels in parts per billion (ppb ) are input to CALPUFF as annual files , and have been provided as part of the data downloaded from previous modeling for NGS. 

# 3.3 **Ammonia Inputs** Ammonia will be held at a background value of 1 ppb for all months of the model run per EPA guidance .

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# 3 Figure 1. BART modeling domains for this WA (blue boundary) and WRAP BART Subject

modeling for AZ (red boundary). Taken from ENSR (2009).

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# 4 Figure 2. Map showing Arizona C IA s in relation to Apache, Cholla, and Coronado ; other CIAs

outside Arizona within the 300 -km radius of these sources are Bandelier Wilderness, NM ; Bryc e Canyon, UT ; Capitol Reef National P ark, UT ; Gila Wilderness, NM ; Joshua Tree Wilderness, CA ; Mesa Verde National Park, CO ; San Pedro Parks Wilderness, NM, and Zion National Park, UT .

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# 3.4 **Modeled and Emitted Species**  The choice of modeled and emitted species used for the BART analys is will follow the guidance of the WRAP BART modeling protocol ( given in Appendix A) . Emissions are input for the following species: SO 2 

# , NO x 

# , and particulate matter (PM) ; PM is speciated into ammonium sulfate, ammonium nitrate, elemental carbon, organic mass, soil , and coarse mass if the ty pes of data available allow that speciation . The National Park Service (NPS) provides PM speciation profiles in spreadsheets and charts on the following website for speciation of PM emitted by several types of combustion units: http://www.nature.nps.gov/air/Permits/ect/index.cfm . If the unit being modeled is not identifiab le in these spreadsheets , a minimum speciation of PM emissions from the facilities into fine and coarse PM (labeled PMF and PMC) will be attempted using the AP - 42 emission factor data for the ty pe of boiler used in the source modeled. The guidance on all the emission inputs to be used for the sources modeled in the WA tasks covered by this protocol (Tasks 6, 7 , and 8) is provided b y EPA in the document given in Appendix B. 

# 3.5 **Discrete Receptor Data** NPS has compiled inputs for CALPUFF modeling of receptors dis cretized on a 4 -km grid for each Class I Area and provided the data on their website , along with the software for down loading the data converted from the native latitude - longitude coordinate s ys tem to the Lambert Conformal Conic grid in which the dispersi on modeling tasks for this WA will be performed. The discrete receptor data and conversion program are downloadable from www.nature.nps.gov/ air/maps/receptors/index.cfm . 

# 4 **CA LPOST Inputs**  Inputs to the CALPOST postprocessor are set according to the guidance of the WRAP BART protocol, Section 3.1.3. The following sections provide specifics of how CALPUFF output will be processed to calculate the visibility impacts of the selected BART - eligibl e sources at the relevant CIAs for this WA. They include details on the calculation of the natural background concentrations of speciated PM for two different definitions of natural conditions, and two visibility calculation methods. 

# 4.1 **Postprocessing of CA LPUFF Output**  Visibility analysis is required for selecting 98 th



# -p ercentile visibility days, indicated by the 8 th



# - highest deciview from the annual runs of CALPUFF, as well as the 22 nd



# -highest deciview from all three ye ars of model output. CALPOST will be us ed to calculate the first metric by postprocessing CALPUFF concentration output for each year individually from 2001 through 2003. For calculating the second metric, there is no automation available for concatenating the three annual ozone files to be use d as input to CALPUFF, so a continuous run from 2001 through 2003 is not possible. Therefore, to select the 22 nd



# -highest deciview day using all three ye ars ’ worth of output, first the yearly concentration files from CALPUFF should be concatenated using the APPEND tool distributed with the CALPUFF model , and then CALPOST should be used to postprocess the concatenated file to select the 22 nd



# -highest deciview day .

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# 6 

# 4.2 **Natural Visibility Conditions**  CALPOST v6.221 includes several methods of calculating natural background visibility. This WA requires use of the IMPROVE Method 6, which considers the visibility impacts of PM species aggregated over the whole particle size range, and the IMPROVE Method 8 (submode 5 ), which considers the different visibility impacts of small and large particles , in order to compare the results . The input requirements for the two methods are different, and detailed in the following sections . **4.2.1 IMPROVE**  **Method 6** Using Method 6, there are three ways to calculate the natural background visibility based on (a) annual average natural conditions, (b) 20% best visibility days , and (c) 20% worst visibility days. The WRAP BART analys is for the Western region used all three methods according to the WRAP BART protocol . However, the requirements of the WA call for only the first two methods , which are described in the following subsections . **4.2.1.1 An**  **nual A**

**verage Background Concentrations** 

# To calculate the annual average background extinction , the annual average concentrations for SO 4 

# , NO 3 

# , EC, OC, Soil (labeled PMF in CALPOST) , and Coarse Mass (labeled PMC in CALPOST) are derived using two types of information from tables given in Guidance for Estimating Natural Visibility Conditions under the Regional Haze Rule (EPA, 2003): the dry constituent concentrations for the average Western aerosol provided in Table 2 - 1 of this document (“Average Natural Levels of Aerosol Components”) ; and the monthly f(RH) tabulated for each CIA , provided in Table A- 3 , averaged over the year . The annual average f(RH) for each CIA is input into the IMPROVE equation along with the dry constituent concentrations: β ext 

# = 3 × f(RH) × [Ammonium Sulfate] + 3 × f(RH) × [Ammonium Nitrate] + 0.6 × [Coarse Mass] + 4 × [Organic Carbon] + 1 × [Soil] (1) + 10 × [Elemental Carbon] + β ray 

# where β ext 

# = extinction coefficient (Mm- 1 

# ) multiplier preceding f(RH) = extinction efficiency for species named within the brackets f(RH) = relative humidity adjustment (annual average ; unitless) β ray 

# = Rayleigh extinction coefficient (= 10 Mm- 1 

# ) [species ] = average dry constituent concentration of species named within the brackets for a

Western aerosol , from EPA (2003), Table 2 - 1 . **4.2.1.2 Background Concentrations for 20% Best Visibility**  **Days** 

# To derive the background concentrations of the individual components of PM from the extinction coefficient , we would follow the procedure described in the draft CALPUFF BART modeling protocol for Montana (MDEQ, 2006; available at http://www.epa.gov/region8/air/pdf/MontanaBARTProtocol0906.pdf ) . Values for extinction

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# 7 (Mm - 1 

# ) for the 20% best visibility days for each CIA are available in Appendix B of EPA (2003 ) , following the prescription of Ames and Malm (2002 ) . This approach estimates the 10 th



# -percentile haze index (HI) in deciviews (dv) , corresponding to the mean of the 20% best visibility values (denoted HIb20%

# ) , from the annual average haze index, HIann - av 

# , as follows: HIb 20% 

# = HIann - av 

# – 1.28 × sd (2) where sd, the standard deviation of the HI distribution, has a recommended value of 2 dv for the West . From the value of HIb 20% 

# derived using Equation (2 ) , the corresponding extinction coefficient for the 20% best visibility days , β ext-b 20 % 

# , can be calculated as β ext-b 20 % 

# = 10 exp (HIb 20%

# /10) (3) The Montana BART modeling protocol modifies the IMPROVE E quation (1) (Section 4.2.1.1) for the 20% best visibility days extinction coefficient by introduc ing a scaling factor, X , for all the PM constituents : β ext-b 20 % 

# = 3 × f(RH) × [Ammonium Sulfate] × X

+ 3 × f(RH ) × [Ammonium Nitrate] × X (4 ) + 0.6 × [Coarse Mass] × X + 4 × [Organic Carbon] × X + 1 × [Soil] × X + 10 × [Elemental Carbon] × X + β ray 

# To derive X

, β ext-b 20 % 

# can be obtained using Equation s 2 and 3 , or it can be calculated from the HIb20% 

# values tabulated in Appendix B of EPA (2003) for each CIA . The value for X can then be determined from Equation 4 and applied to each of the PM constituent annual average background concentrations at each CIA to obtain the corresponding background concentration s on the 20% best visibility

days. The average Western aerosol constituent background concentrations needed to estimate the reference extinction (Mm - 1 

# ) are provided in Table 1 below for the CIAs of interest for the Arizona sources being modeled in this WA, along with the extinction efficiency by constituent taken from EPA (2003). For each Arizona CIA affected b y the BART - eligible sources in Arizona , Table 2 gives its annual f(RH) and its extinction coefficients for reference conditions and for 20% best visibility conditions as calculated using Equations 2 and 3 above . Table 3 shows the background PM concentration s calculated using the Table 2 values of β ext-b 20% 

# for the same CIAs. A co mplete list of the 156 CIAs in North America along with their background extinctions and concentrations for the 20% best visibility days calculated using the above method is provided in Appendix C of this protocol for reference .

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# 8 **Table 1.** Average Western aerosol constituent background concentrations

and extinction efficiencies **(NH 4** 

# ) **2** 

# SO **4** 

# NH **4**

# NO **3** 

# OC **LAC Soil**  **CM** Conc entration ( g/m 3 

# ) 0.12 0.10 0.47 0.02 0.50 3.00 Extinction E ff

iciency (m2

# /g) a 

# 3.00 3.00 4.00 10.00 1.00 0.60 a 

## Taken from EPA (2003)



# Table 2. Annual f(RH), and extinction coefficients for annual average (reference) background conditions and 20 % best visibility background conditions , at the 20 C IA s of interest **Class I Area Annual** 

**f(RH)** β **ext -** **Ref**



# (Mm**- 1**  

# ) β **ext -** b **20 %** 



# (Mm**- 1**  

# ) Bandelier 1. 9 15. 62 12. 09 0 Bryc e Canyon 1.8 15. 5 8 12. 0 54 Capitol Reef 1.9 15.63 12. 10 6 Chiricahua NM 1. 7 15. 4 7 11. 9 68 Chiricahua Wilderness 1. 7 15. 45 11. 96 3 Galiuro 1.6 15. 4 0 11. 9 45 Gila 1. 8 15. 5 1 12. 0 09 Grand Canyon 1. 8 15. 51 12. 0 35 Joshua Tree 2.1 15. 7 2 12. 1 66 Mazatzal 1.6 15.44 11. 9 75 Mesa Verde 1.9 15. 7 3 12. 176 Mount Baldy 1.7 15. 5 1 12. 0 15 Petrified Forest 1. 8 15. 5 4 12. 0 28 Pine Mountain 1. 7 15. 4 7 11. 97 6 Saguaro 1. 5 15. 35 11. 8 74 San Pedro Parks 1.9 15. 63 12. 106 Sierra Ancha 1.6 15. 4 6 11. 9 81 Superstition 1.6 15. 4 0 11. 9 37 Sycamore Canyon 2.1 15. 5 3 12. 0 54 Zion 1. 8 15. 5 6 12. 0 45

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# 9 **Table 3**  **.** Site - specific background concentrations of PM constituents

for 20% b est visibility days **Class I Area (NH**  **4**

# ) **2** 

# SO **4**



# ( **μ g/m** **3** 

# ) **NH 4** 

# NO **3**



# ( **μ g/m** **3** 

# ) **OC**

**( μ**  **g/m 3**  

# ) **EC**

**( μ**  **g/m 3**  

# ) **Soil**

**( μ**  **g/m 3**  

# ) **CM**

**( μ**  **g/m 3**  

# ) Bandelier 0.045 0.037 0.175 0.007 0.186 1.117 Bryc e Canyon 0.044 0.037 0.173 0.007 0.184 1.106 Capitol Reef 0.045 0.037 0.176 0.007 0.187 1.121 Chiricahua NM 0.043 0.036 0.169 0.007 0.180 1.082 Chiricahua W 0.043 0.036 0.169 0.007 0.180 1.079 Galiuro 0.043 0.036 0.167 0.007 0.178 1.069 Gila 0.044 0.036 0.171 0.007 0.182 1.093 Grand Canyon 0.044 0.036 0.171 0.007 0.182 1.093 Joshua Tree 0.045 0.038 0.178 0.008 0.189 1.136 Mazatzal 0.043 0.036 0.169 0.007 0.180 1.081 Mesa Verde 0.046 0.038 0.179 0.008 0.190 1.140 Mount Baldy 0.044 0.036 0.171 0.007 0.182 1.093 Petrified Forest 0.044 0.037 0.172 0.007 0.183 1.100 Pine Mountain 0.043 0.036 0.169 0.007 0.180 1.082 Saguaro 0.042 0.035 0.165 0.007 0.175 1.052 San Pedro Parks 0. 04 5 0. 03 7 0. 1 76 0. 00 7 0. 1 87 1. 1 21 Sierra Ancha 0.043 0.036 0.170 0.007 0.181 1.084 Superstition 0.043 0.036 0.167 0.007 0.178 1.069 Sycamore Canyon 0.044 0.037 0.172 0.007 0.183 1.096 Zion 0.044 0.037 0.173 0.007 0.184 1.103 **4.2.2 IMPROVE**  **Method 8** Under IMPROVE Method 8 (submode 5), the extinction coefficient , β ext 

# , is calculated as follows: β ext 

# = 2.2 × f

S

# (RH) × [Small Sulfate] + 4.8 × f L 

# (RH) × [Large Sulfate] + 2.4 × f

S

# (RH) × [Small Nitrate] + 5.1 × f L 

# (RH) × [Large Nitrate] + 2.8 × [Small Organic Mass] + 6.1 × [Large Organic Mass] + 10 × [Elemental Carbon] + 1 × [Fine Soil] + 0.6 × [Coarse Mass] + 1.7 × f

SS

# (RH) × [Sea Salt] + β Ray 

# ( s ite specific) + 0.33 × [NO 2 

# (ppb)] {or as: 0.1755 × [NO 2 

# (μg/m 3 

# )]} where the subscripts S, L, and SS represent small particles, large particles , and sea salt , respectively, and a site - specific value of β Ray 

# replaces the constant value of 10 Mm - 1 

# in Eq. 1 . All inputs needed for calculating β ext 

# for each CIA using the method above are provided in the FLAG - 2010 report (FLM, 2010) and are given in Appendix D of this protocol . Figure 5 of that report provides the relationship to be used between total background concentrations of sulfate,

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# 10 nitrate , and organic mass and their corresponding concentrations in the small and large size fractions to calculate the size - specific inputs for these species in CALPOST. Total PM constituent concentrations and Rayleigh scattering coefficients for the 20% best visibility days and annual average natural conditions for each CIA are provided in FLM (2010) Tables 5 and 6 , respectively, while the monthly f(RH) adjustment factors for large - and small -mode sulfate, nitrate , and sea salt can be found in Tables 7 through 9 of th at report. These inputs are used in CALPOST to cal culate the extinction coefficient , β ext 

# .

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# 11 

# References Ames, R., and W. Malm, 2002: Recommendations for Natural Condition Deciview Variability : An Examination of IMPROVE Data Frequency Distributions, Proceedings of “Regional Haze and Global Radiation Balance - Aerosol Measurements and Models: Closure Reconciliation and Evaluation,” October 2 - 5, 2002, Bend, O R . ENSR, 2009: Revised BART Analysis for the Navajo Generating Station Units 1 - 3 , ENSR Corporation, Document No. 05830 - 012 - 300, January 2009, Salt River Project

– Navajo Generating Station, Tempe, AZ. EPA, 2003: Guidance for Estimating Natural Visibility Conditions under the Regional Haze Rule , Report # EPA- 454/B - 03 - 005, U.S. Environmental Protection Agency, Office of Air Quality Planning and Standards, Emissions, Monitoring and Analys is Division, Air Quality Trends Analys is Group, Research Triangle Park, NC. FLM (U.S. Forest Service, National Park Service, and U.S. Fish and Wildlife Service) , 2010: Federal Land Managers’ Air Quality Related Values Wo rking Group Phase I Report

– Revised (2010) , Natural Resources Report NPS/NRPC/NRR 2010/232, National Park Service, Denver, C O . MDEQ (Montana Department of Environmental Quality), 2006: Draft CALPUFF BART Modeling Protocol For Federal Mandatory Class I Areas, Montana Department of Environmental Quality, Air Resources Management Bureau, Helena, MT.

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# Ap **pendix A**  **: BA**  **RT Subject Model**  **Protocol**

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# Ap **pendix B :**  **Direction from EP** 

**A R** **egion 9 on**  **Emissions Inputs for Ap**  **ache, Cholla and Coronado**

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# 1 **BA RT Sources and Their Emissions Inputs**  There are a total of **3 facilities**  that will be analyzed through CALPUFF visibility modeling as part of the Tasks 8 WA as follows: **Task 8:** Perform a full five - factor BART analys is for **NOx controls** with emissions inputs as follows: (a) **Apache Generating Station (AEPCO), Units 1 -** **3 (control s evaluated for**  **2 & 3)** : All units will use ADEQ BART limits on emission factors for SO 2 

# and PM, multiplied by the maximum daily- average heat inputs (BTU/hr) from CAMD/CEMS (2008 - 2010) to calculate the respective emission rates for these pollutants. Unit 1 (not eligible for BART) will use the ADEQ BART limits also on NO x 

# , multiplied by the maximum daily- average heat input (BTU/hr) from CAMD/CEMS (2008 - 2010) to calculate the NOx emission rate. PM Speciation for this unit should use NPS spreadsheet data for “Gas - Fired Combustion Turbine Example” (see http://www.nature.nps.gov/air/Permits/ect/docs/gasCT/EdRevConsensusGasCTexample.xls ). For Units 2 and 3, the NOx baseline values will be taken as the CAMD/CEMS (2008 - 2010) maximum daily- average NOx emiss ion rates. The stack parameters provided by the facility (Table B - 2) should be used in place of the WRAP stack parameters, due to erroneous WRAP modeling inputs for exit velocity and exit temperature . PM speciation should use the NPS spreadsheet data for “PC Dry Bottom FGD and ESP Example” (see http://www.nature.nps.gov/air/Permits/ect/docs/coalBoiler/2006FinalDryBottomPC_FGD_ESPp mSpec iationProfile.xls ). Heating value, and percent coal ash and sulfur content needed as inputs to the spreadsheet are provided in Table B - 1. (b) **Cholla Power Plant, Units 1 -** **4** : Unit 1 is not BART - eligible, and will use actual maximum daily average emissions from CAMD/CEMS (2008 - 2010) for SO 2 

# and NO x 

# for all runs. For PM, this unit has a baghouse similar to the BART - eligible units 2 - 4, and thus the ADEQ BART limit of 0.015 lb/mmBTU should be used for the PM emission factor; this should be multiplied by the maximum daily- average heat input (BTU/hr) from CAMD/CEMS (2008 - 2010) to calculate the filterable PM emission rate. Speciation of PM emissions should be done using the NPS spreadsheets for “PC Dry Bottom FF and FGD Example” (see http://www.nature.nps.gov/air/Permits/ect/docs/coalBoiler/2006FinalDryBottomPC_FGD_FFpm SpeciationProfile.xls ) . For Units 2 - 4, the NO x 

# baseline values will be the actual CAMD/CEMS (2008 - 2010) maximum daily- average NO x 

# emission rates ; SO 2 

# and PM emissions should be based on ADEQ BART limits on emission factors multiplied by the maximum daily- average heat inputs (BTU/hr) from CAMD/CEMS (2008 - 2010) . Speciation of PM for Units 2 and 3 should be as in Unit 1 , but for Unit 4 it should use NPS spreadsheet data for “PC Dry Bottom Wet Scrubber Example” (see http://www.nature.nps.gov/air/Permits/ect/docs/coalBoiler/2006FinalDryBottomPCScrubberPmS peciationProfile.xls ). Heating value, and percent coal ash and sulfur content needed as inputs to the spreadsheets are provided in Table B - 1. Updated stack parameters provided by the facility (Table B - 2) should be used. (c) **SRP Coronado Units 1 and 2 (controls evaluated for**  **1)** : 2008 will be the highest emission ye ar for this plant. ENSR/AECOM, the contractor who previously performed the BART analysis on this plant, al so had different stack parameters before and after NO x 

# burner installation. The

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# parameters appropriate to the plant conditions in 2008 should be used. Unit 1 will use ADEQ BART limits on emission factors for SO 2 

# and PM, multiplied by the maximum daily- average heat input (BTU/hr) from CAMD/CEMS (2008 - 2010) to calculate the respective emission rates for these pollutants. For Unit 1, the NOx baseline value will be the CAMD/CEMS 2008 maximum daily- average NOx emission rate. Unit 2 is also eligible for BART , but a Consent Decree (CD) applies to it, thus the emissions will held at the following values: 0.08 lb/mmBTU for SO 2 

# and NO x 

# , and 0.03 lb/mmBTU for filterable PM , multiplied by the maximum dailyaverage heat input (BTU/hr) from CAMD/CEMS 2008 to calculate the respective emission rate s . ENSR calculated PM speciation for this plant, and these data should be used to speciate the PM emissions above.

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 July 16 , 2012 

# Table B **- 1.**  Summary

of BART Sources, Emissions and Related Parameters for CALPUFF Emission Inputs

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 July 16 , 2012

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 July 16 , 2012 

# Table B **- 2.**  Stack Parameters for all BART Sources

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 July 16 , 2012 

# Ap **pendix C :**  **Natural Background Conditions for IMPROVE**  **Method 6 ( receiv** **ed from EP**  **A Region 9)** 

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 July 16 , 2012 **Natural conce ntrations for be**  **st and wor** **st 20% of day s,**  **Fr om**  **T able**  **2-1** Am mo nium

su lfate Am mo nium

nitrate Org anic

ca rbon Elem ental

ca rbon Soil Coars e Mass **scale d from** 

**annual conce ntrations B20 and W**  **20 e xtinction**  West c onc . 0.12 0.1 0.47 0.02 0.5 3 Eas t c onc . 0.23 0.1 1.4 0.02 0.5 3 bext c alc ulated asa c hec k, us ing table A-2, "rec om mended" f( RH) at IMPROVE site dry ext. eff. 3 3 4 10 1 0.6 

### Best**2 0%**  **d ays**  **concent ra** **ti ons**  FromBes t & W

ors t dv ch ec k Sc aled fromannual by (b_B20 - 10) / (b_Ann - 10) abbr Clas s I Area West / Eas t An nl A

vg (Mm- 1) Bes t Day

s (Mm-1 ) Wo rs t Days

(Mm- 1) An nl avg b

from c onc (Bes t-10) /

(A vg- 10) Am mo nium

su lfate Am mo nium

nitrate Org anic

ca rbon Elem ental

ca rbon Soil Coars e Mass ac ad Ac adia N P Eas t 21.4 14.5790431 31.42441357 21.4495 0.40167045 0.092 0.040 0.562 0.008 0.201 1.205 agti Ag ua Tibia W ilder nes s West 15.86 12.2752506 20.48279147 15.8815 0.38826803 0.047 0.039 0.182 0.008 0.194 1.165 alla Al pine Lake W ildernes s West 16.99 13.152148 21.94600444 16.789 0.45095108 0.054 0.045 0.212 0.009 0.225 1.353 anac An ac onda-Pintler W ildernes s West 16.03 12.4110238 20.70934594 16.074 0.39983811 0.048 0.040 0.188 0.008 0.200 1.200 anad An se l A

dam s Wi ldernes s West 15.78 12.2140276 20.38063312 15.777 0.38304975 0.046 0.038 0.180 0.008 0.192 1.149 arc h Arch es N P West 15.58 12.0562729 20.11739961 15.568 0.36850768 0.044 0.037 0.173 0.007 0.184 1.106 badl Badlands N P West 16.06 12.4358707 20.75080608 16.063 0.40195886 0.048 0.040 0.189 0.008 0.201 1.206 band Bandelier NM West 15.62 12.092496 20.17784243 15.6065 0.37233024 0.045 0.037 0.175 0.007 0.186 1.117 bes e Bering Sea bibe Big Bend N P West 15.48 11.9841518 19.99705661 15.568 0.3620715 0.043 0.036 0.170 0.007 0.181 1.086 blc a Blac k C anyon of the G unnis on NM West 15.68 12.1409628 20.25871544 15.6835 0.37693008 0.045 0.038 0.177 0.008 0.188 1.131 bom a Bob Mars hall W ilder nes s West 16.17 12.5107102 20.87568518 16.2775 0.40692224 0.049 0.041 0.191 0.008 0.203 1.221 bos q Bos que del A

pac he West 15.54 12.0321844 20.07720502 15.535 0.36682029 0.044 0.037 0.172 0.007 0.183 1.100 bow a Boundary Waters Canoe A rea Eas t 20.89 14.2333114 30.6792059 20.99575 0.38873383 0.089 0.039 0.544 0.008 0.194 1.166 bret Breton Eas t 21.57 14.6961432 31.67681715 21.9115 0.40588965 0.093 0.041 0.568 0.008 0.203 1.218 brid Bridger W ildernes s West 15.71 12.1652691 20.29927341 15.744 0.37920649 0.046 0.038 0.178 0.008 0.190 1.138 brig Brigantine Eas t 21.05 14.3332941 30.89471374 21.1195 0.39215332 0.090 0.039 0.549 0.008 0.196 1.176 brc a Bryc e C anyon NP West 15.58 12.0562729 20.11739961 15.568 0.36850768 0.044 0.037 0.173 0.007 0.184 1.106 ca mo Cabinet Mountains W ildernes s West 16.27 12.5985924 21.02232762 16.3435 0.41444855 0.050 0.041 0.195 0.008 0.207 1.243 ca cr Caney C reek W ildernes s Eas t 21.14 14.4051401 31.04957414 21.433 0.39543448 0.091 0.040 0.554 0.008 0.198 1.186 ca ny Canyonlands N P West 15.6 12.0804095 20.15767467 15.546 0.3715017 0.045 0.037 0.175 0.007 0.186 1.115 ca pe Cape Rom ain Eas t 21.22 14.4484204 31.14286273 21.47425 0.39647241 0.091 0.040 0.555 0.008 0.198 1.189 ca re Capitol Reef N P West 15.63 12.1045945 20.19803037 15.6285 0.37381785 0.045 0.037 0.176 0.007 0.187 1.121 ca ri Caribou W ildernes s West 16.05 12.423441 20.73006564 16.1345 0.40056876 0.048 0.040 0.188 0.008 0.200 1.202 cave Carls bad Caverns N P West 15.61 12.092496 20.17784243 15.6065 0.37299394 0.045 0.037 0.175 0.007 0.186 1.119 ch as Chas sa howitz ka Eas t 21.46 14.6082304 31.48732529 21.796 0.40211434 0.092 0.040 0.563 0.008 0.201 1.206 ch ir Chiric ahua NM West 15.47 11.9721736 19.97706954 15.4965 0.36054363 0.043 0.036 0.169 0.007 0.180 1.082 ch ir Chiric ahua W ildernes s West 15.45 11.9602074 19.95710246 15.4855 0.35967109 0.043 0.036 0.169 0.007 0.180 1.079 co hu Cohutta W ildernes s Eas t 21.39 14.5644713 31.39300486 21.60625 0.40074375 0.092 0.040 0.561 0.008 0.200 1.202 crla Crater Lake N P West 16.74 12.956338 21.619271 16.767 0.43862582 0.053 0.044 0.206 0.009 0.219 1.316 crmo Craters of the Moon NM West 15.8 12.2262477 20.40102395 15.8155 0.38383581 0.046 0.038 0.180 0.008 0.192 1.152 cu ca Cuc am onga W ilder nes s West 15.85 12.2752506 20.48279147 15.8485 0.38893173 0.047 0.039 0.183 0.008 0.194 1.167 dena Denali Pres erve NP West 16.27 12.5860001 21.0013158 16.041 0.41244021 0.049 0.041 0.194 0.008 0.206 1.237 des o Des olation W ildernes s West 15.8 12.2262477 20.40102395 15.8045 0.38383581 0.046 0.038 0.180 0.008 0.192 1.152 dipe Diam ond Peak W ilder nes s West 16.84 13.0343098 21.74937656 16.7945 0.44361254 0.053 0.044 0.208 0.009 0.222 1.331 dos o Dolly Sods W ildernes s Eas t 21.13 14.3907421 31.01854009 21.268 0.39449615 0.091 0.039 0.552 0.008 0.197 1.183 dola Dom e Land W ilder nes s West 15.7 12.1531099 20.27898429 15.7 0.37773857 0.045 0.038 0.178 0.008 0.189 1.133

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 July 16 , 2012 **Best 2**  **0% d**  **ays concent**  **ra ti**  **ons** FromBes t & W

ors t dv ch ec k Sc aled fromannual by (b_B20 - 10) / (b_Ann - 10) abbr Clas s I Area West / Eas t An nl A

vg (Mm- 1) Bes t Day

s (Mm-1 ) Wo rs t Days

(Mm- 1) An nl avg b

from c onc (Bes t-10) /

(A vg- 10) Am mo nium

su lfate Am mo nium

nitrate Org anic

ca rbon Elem ental

ca rbon Soil Coars e Mass eac a Eagle C ap W ilder nes s West 16.12 12.4857138 20.83397553 16.03 0.40616238 0.049 0.041 0.191 0.008 0.203 1.218 eane Eagles N es t W ildernes s West 15.72 12.1652691 20.29927341 15.7165 0.37854354 0.045 0.038 0.178 0.008 0.189 1.136 em ig Em igrant W ildernes s West 15.81 12.2384801 20.42143517 15.8155 0.38528056 0.046 0.039 0.181 0.008 0.193 1.156 ever Everglades N P Eas t 20.77 14.1481673 30.49568179 20.74 0.38515945 0.089 0.039 0.539 0.008 0.193 1.155 fitz Fitz patric k W ildernes s West 15.73 12.1774404 20.31958284 15.7275 0.38000705 0.046 0.038 0.179 0.008 0.190 1.140 flto Flat Tops W ilder nes s West 15.7 12.1531099 20.27898429 15.7 0.37773857 0.045 0.038 0.178 0.008 0.189 1.133 gali Ga liuro W ildernes s West 15.4 11.9243806 19.89732087 15.4195 0.35636678 0.043 0.036 0.167 0.007 0.178 1.069 gam o Gates of the M

ountains W ildernes s West 15.93 12.3367806 20.58546189 15.964 0.39406081 0.047 0.039 0.185 0.008 0.197 1.182 gem o Ge ar hart Mountain W ilder nes s West 16.33 12.6364449 21.0854893 16.349 0.41649999 0.050 0.042 0.196 0.008 0.208 1.249 gila Gi la W ilder nes s West 15.51 12.0081441 20.03709074 15.535 0.36445446 0.044 0.036 0.171 0.007 0.182 1.093 glac Gl ac ier N P West 16.48 12.7634433 21.29740199 16.591 0.4264573 0.051 0.043 0.200 0.009 0.213 1.279 glpe Gl ac ier Peak W ildernes s West 16.88 13.0734714 21.81472265 16.756 0.44672549 0.054 0.045 0.210 0.009 0.223 1.340 goro Goat Roc ks W ildernes s West 16.93 13.0996445 21.85839576 16.8 0.44727915 0.054 0.045 0.210 0.009 0.224 1.342 grc a Grand C anyon NP West 15.51 12.0081441 20.03709074 15.546 0.36445446 0.044 0.036 0.171 0.007 0.182 1.093 grte Grand Teton NP West 15.74 12.1774404 20.31958284 15.7495 0.37934502 0.046 0.038 0.178 0.008 0.190 1.138 grgu Great Gulf W ildernes s Eas t 21.1 14.3763586 30.98753705 21.202 0.39426654 0.091 0.039 0.552 0.008 0.197 1.183 grs a Great Sand D unes N M West 15.74 12.1896239 20.33991259 15.777 0.38146759 0.046 0.038 0.179 0.008 0.191 1.144 grs m Great Sm oky Mountains N P Eas t 21.39 14.5644713 31.39300486 21.52375 0.40074375 0.092 0.040 0.561 0.008 0.200 1.202 gum o Gu adalupe Mountains N P West 15.64 12.1045945 20.19803037 15.612 0.37315506 0.045 0.037 0.175 0.007 0.187 1.119 hale Ha leakala N P West 16.02 12.398619 20.68864694 16.052 0.39844169 0.048 0.040 0.187 0.008 0.199 1.195 havo Hawa ii V

olc anoes N P West 16.33 12.6490877 21.10658534 16.448 0.41849726 0.050 0.042 0.197 0.008 0.209 1.255 hec a He lls Cany

on W ildernes s West 16.09 12.4607673 20.79234922 16.052 0.40406688 0.048 0.040 0.190 0.008 0.202 1.212 herc He rc ules -G lades W ildernes s Eas t 21.03 14.318968 30.86383447 21.202 0.39156555 0.090 0.039 0.548 0.008 0.196 1.175 hoov Hoover W ildernes s West 15.78 12.2140276 20.38063312 15.7825 0.38304975 0.046 0.038 0.180 0.008 0.192 1.149 is ro Is le R oyale N P Eas t 20.91 14.2475519 30.70990045 20.971 0.38932648 0.090 0.039 0.545 0.008 0.195 1.168 jari Jam es River Fac e W ilder nes s Eas t 20.96 14.2760755 30.77138172 21.11125 0.39015287 0.090 0.039 0.546 0.008 0.195 1.170 jarb Jar bidge W ildernes s West 15.75 12.1896239 20.33991259 15.777 0.38080416 0.046 0.038 0.179 0.008 0.190 1.142 jom u John Muir W ildernes s West 15.8 12.2384801 20.42143517 15.777 0.38594484 0.046 0.039 0.181 0.008 0.193 1.158 jotr Jos hua Tree N M West 15.72 12.1652691 20.29927341 15.7385 0.37854354 0.045 0.038 0.178 0.008 0.189 1.136 joyc Joyc e-Kilm er-Slic kroc k Wi ldernes s Eas t 21.4 14.5790431 31.42441357 21.57325 0.40167045 0.092 0.040 0.562 0.008 0.201 1.205 kais Kais er W ildernes s West 15.8 12.2262477 20.40102395 15.799 0.38383581 0.046 0.038 0.180 0.008 0.192 1.152 kalm Kalm iops is W ilder nes s West 16.74 12.956338 21.619271 16.8275 0.43862582 0.053 0.044 0.206 0.009 0.219 1.316 kic a Kings Canyon N P West 15.79 12.2262477 20.40102395 15.7825 0.38449874 0.046 0.038 0.181 0.008 0.192 1.153 laga La Gar ita W ildernes s West 15.69 12.1409628 20.25871544 15.6835 0.37626763 0.045 0.038 0.177 0.008 0.188 1.129 lavo Las se n V

olc anicN P West 16.08 12.4483128 20.77156726 16.162 0.40268302 0.048 0.040 0.189 0.008 0.201 1.208 labe Lava B eds N M West 16.37 12.6744112 21.14884075 16.316 0.41984477 0.050 0.042 0.197 0.008 0.210 1.260 ligo Linville Gorge W ildernes s Eas t 21.36 14.5499141 31.36162755 21.60625 0.40052061 0.092 0.040 0.561 0.008 0.200 1.202 los t Los twood West 16.11 12.4732343 20.81315197 16.151 0.40478467 0.049 0.040 0.190 0.008 0.202 1.214 lybr Lye B rook W ildernes s Eas t 20.99 14.2903587 30.80216849 21.06175 0.39038751 0.090 0.039 0.547 0.008 0.195 1.171 ma ca Ma mmoth Cave N P Eas t 21.58 14.6961432 31.67681715 21.42475 0.40553914 0.093 0.041 0.568 0.008 0.203 1.217 ma mo Ma rb le Mountain W ildernes s West 16.65 12.891718 21.51144444 16.7505 0.43484482 0.052 0.043 0.204 0.009 0.217 1.305 ma be Ma roon Bells -Snowm as s Wi lder nes s West 15.7 12.1531099 20.27898429 15.7165 0.37773857 0.045 0.038 0.178 0.008 0.189 1.133 maza Mazatz al W ildernes s West 15.44 11.9602074 19.95710246 15.4525 0.36033225 0.043 0.036 0.169 0.007 0.180 1.081

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 July 16 , 2012 **Best 2**  **0% d**  **ays concent**  **ra ti**  **ons** FromBes t & W

ors t dv ch ec k Sc aled fromannual by (b_B20 - 10) / (b_Ann - 10) abbr Clas s I Area West / Eas t An nl A

vg (Mm- 1) Bes t Day

s (Mm-1 ) Wo rs t Days

(Mm- 1) An nl avg b

from c onc (Bes t-10) /

(A vg- 10) Am mo nium

su lfate Am mo nium

nitrate Org anic

ca rbon Elem ental

ca rbon Soil Coars e Mass me di Me dic ine Lake West 16.07 12.4358707 20.75080608 16.1125 0.40129665 0.048 0.040 0.189 0.008 0.201 1.204 meve MesaV

erde NP West 15.73 12.1774404 20.31958284 15.623 0.38000705 0.046 0.038 0.179 0.008 0.190 1.140 mi ng Mi ngo Eas t 21.03 14.318968 30.86383447 21.21025 0.39156555 0.090 0.039 0.548 0.008 0.196 1.175 mi mo Mi ssi on Mountains W ilder nes s West 16.21 12.5482987 20.93840627 16.2555 0.41035405 0.049 0.041 0.193 0.008 0.205 1.231 mo ke Mo kelum ne W ildernes s West 15.8 12.2384801 20.42143517 15.8045 0.38594484 0.046 0.039 0.181 0.008 0.193 1.158 moos Moos ehorn Eas t 21.22 14.4484204 31.14286273 21.27625 0.39647241 0.091 0.040 0.555 0.008 0.198 1.189 moad Mo unt A

dam s Wi ldernes s West 16.86 13.0473506 21.77113681 16.844 0.4442202 0.053 0.044 0.209 0.009 0.222 1.333 mo ba Mo unt Baldy W ildernes s West 15.51 12.0081441 20.03709074 15.513 0.36445446 0.044 0.036 0.171 0.007 0.182 1.093 mo ho Mo unt Hood W ildernes s West 16.83 13.0343098 21.74937656 16.7835 0.44426204 0.053 0.044 0.209 0.009 0.222 1.333 mo je Mo unt Jeffers on W ildernes s West 16.91 13.0865514 21.83654829 16.7725 0.44667893 0.054 0.045 0.210 0.009 0.223 1.340 mo ra Mo unt R ainier NP West 17.05 13.204862 22.03396426 16.976 0.45459035 0.055 0.045 0.214 0.009 0.227 1.364 mowa Mo unt W as hington W ildernes s West 17.03 13.1916637 22.01194131 16.7835 0.45400622 0.054 0.045 0.213 0.009 0.227 1.362 mozi Mo unt Zir kel W ildernes s West 15.71 12.1652691 20.29927341 15.7165 0.37920649 0.046 0.038 0.178 0.008 0.190 1.138 mo la Mo untain Lakes W ildernes s West 16.5 12.7762131 21.31871004 16.514 0.42710971 0.051 0.043 0.201 0.009 0.214 1.281 noab No rth Abs aroka W ilder nes s West 15.74 12.1774404 20.31958284 15.755 0.37934502 0.046 0.038 0.178 0.008 0.190 1.138 noc a No rth Cas ca des N P West 16.86 13.0473506 21.77113681 16.7615 0.4442202 0.053 0.044 0.209 0.009 0.222 1.333 okef Ok

efenokee Eas t 21.41 14.5790431 31.42441357 21.631 0.40131841 0.092 0.040 0.562 0.008 0.201 1.204 olym Ol ym picN P West 17.02 13.1784786 21.98994037 16.9925 0.45277474 0.054 0.045 0.213 0.009 0.226 1.358 otc r Otter Creek W ilder nes s Eas t 21.14 14.4051401 31.04957414 21.32575 0.39543448 0.091 0.040 0.554 0.008 0.198 1.186 pas a Pas ayten W ilder nes s West 16.84 13.0343098 21.74937656 16.7615 0.44361254 0.053 0.044 0.208 0.009 0.222 1.331 pec o Pec os W ildernes s West 15.65 12.1167052 20.2182385 15.6395 0.37463808 0.045 0.037 0.176 0.007 0.187 1.124 pefo Petrified Fores t N P West 15.54 12.0321844 20.07720502 15.535 0.36682029 0.044 0.037 0.172 0.007 0.183 1.100 pim o Pine Mountain W ildernes s West 15.47 11.9721736 19.97706954 15.469 0.36054363 0.043 0.036 0.169 0.007 0.180 1.082 pinn Pinnac les N M West 16.12 12.4857138 20.83397553 15.986 0.40616238 0.049 0.041 0.191 0.008 0.203 1.218 pore Point Reyes N S West 16.2 12.5482987 20.93840627 16.2555 0.41101592 0.049 0.041 0.193 0.008 0.206 1.233 prra Pres idential R ange-D ry River W ildernes s Eas t 21.15 14.4051401 31.04957414 21.301 0.39507983 0.091 0.040 0.553 0.008 0.198 1.185 rala RainbowLake W ilder nes s Eas t 20.99 14.3046562 30.83298606 18.1 0.39168846 0.090 0.039 0.548 0.008 0.196 1.175 rawa Rawah W ildernes s West 15.72 12.1652691 20.29927341 15.722 0.37854354 0.045 0.038 0.178 0.008 0.189 1.136 redr Red Roc k Lakes West 15.81 12.2384801 20.42143517 15.8155 0.38528056 0.046 0.039 0.181 0.008 0.193 1.156 redw Redwood N P West 16.9 13.0865514 21.83654829 17.174 0.44732629 0.054 0.045 0.210 0.009 0.224 1.342 rom o Roc ky Mountain N P West 15.67 12.1288279 20.23846685 15.6395 0.37545466 0.045 0.038 0.176 0.008 0.188 1.126 roc a Roos evelt C am pobello I nternational Park Eas t 21.22 14.4484204 31.14286273 21.2845 0.39647241 0.091 0.040 0.555 0.008 0.198 1.189 sagu Saguaro N M West 15.35 11.8767783 19.81789055 15.37 0.35079969 0.042 0.035 0.165 0.007 0.175 1.052 st ma Saint Marks Eas t 21.54 14.6667803 31.61352682 21.8455 0.40440037 0.093 0.040 0.566 0.008 0.202 1.213 sa cr Salt Creek West 15.58 12.0562729 20.11739961 15.5845 0.36850768 0.044 0.037 0.173 0.007 0.184 1.106 saga San Gabriel W ilder nes s West 15.86 12.2752506 20.48279147 15.8705 0.38826803 0.047 0.039 0.182 0.008 0.194 1.165 sago San Gorgonio W ildernes s West 15.74 12.1896239 20.33991259 15.8155 0.38146759 0.046 0.038 0.179 0.008 0.191 1.144 sa ja San Jac into W ilder nes s West 15.78 12.2140276 20.38063312 15.8155 0.38304975 0.046 0.038 0.180 0.008 0.192 1.149 sa pe San Pedro Parks W ildernes s West 15.63 12.1045945 20.19803037 15.612 0.37381785 0.045 0.037 0.176 0.007 0.187 1.121 sa ra San R afael W ilder nes s West 16.03 12.4110238 20.70934594 16.0245 0.39983811 0.048 0.040 0.188 0.008 0.200 1.200 sawt Sawtooth W ilder nes s West 15.82 12.2507247 20.44186682 15.854 0.38672245 0.046 0.039 0.182 0.008 0.193 1.160 sca p Sc apegoat W ildernes s West 16.05 12.423441 20.73006564 16.0905 0.40056876 0.048 0.040 0.188 0.008 0.200 1.202

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 July 16 , 2012 **Best 2**  **0% d**  **ays concent**  **ra ti**  **ons** FromBes t & W

ors t dv ch ec k Sc aled fromannual by (b_B20 - 10) / (b_Ann - 10) abbr Clas s I Area West / Eas t An nl A

vg (Mm- 1) Bes t Day

s (Mm-1 ) Wo rs t Days

(Mm- 1) An nl avg b

from c onc (Bes t-10) /

(A vg- 10) Am mo nium

su lfate Am mo nium

nitrate Org anic

ca rbon Elem ental

ca rbon Soil Coars e Mass se lw Selw ay- Bitterroot W ildernes s West 16.09 12.4607673 20.79234922 16.107 0.40406688 0.048 0.040 0.190 0.008 0.202 1.212 se ne Seney Eas t 21.23 14.462876 31.17402116 21.367 0.39740659 0.091 0.040 0.556 0.008 0.199 1.192 se qu Sequoia NP West 15.79 12.2262477 20.40102395 15.744 0.38449874 0.046 0.038 0.181 0.008 0.192 1.153 sh en Shenandoah NP Eas t 20.98 14.2903587 30.80216849 21.25975 0.39074305 0.090 0.039 0.547 0.008 0.195 1.172 sh ro Shining R oc k Wi ldernes s Eas t 21.4 14.5790431 31.42441357 21.62275 0.40167045 0.092 0.040 0.562 0.008 0.201 1.205 si an Sierra Anc ha W ilder nes s West 15.46 11.9721736 19.97706954 15.4635 0.36120396 0.043 0.036 0.170 0.007 0.181 1.084 si me Sim eonof West 17.21 13.3242421 22.233165 17.1795 0.46105994 0.055 0.046 0.217 0.009 0.231 1.383 si ps Sips ey W ildernes s Eas t 21.28 14.4918307 31.2364316 21.499 0.39821194 0.092 0.040 0.557 0.008 0.199 1.195 sowa South W arner W ildernes s West 16.09 12.4607673 20.79234922 16.074 0.40406688 0.048 0.040 0.190 0.008 0.202 1.212 st mo Strawberry M

ountain W ildernes s West 16.37 12.6744112 21.14884075 16.2445 0.41984477 0.050 0.042 0.197 0.008 0.210 1.260 su pe Supers ti tion W ildernes s West 15.4 11.9243806 19.89732087 15.447 0.35636678 0.043 0.036 0.167 0.007 0.178 1.069 swa n Swanquarter Eas t 20.91 14.2475519 30.70990045 21.06175 0.38932648 0.090 0.039 0.545 0.008 0.195 1.168 syca Syc am ore Canyon W ildernes s West 15.53 12.0201582 20.05713785 15.7385 0.3653089 0.044 0.037 0.172 0.007 0.183 1.096 teto Teton W ilder nes s West 15.74 12.1774404 20.31958284 15.7495 0.37934502 0.046 0.038 0.178 0.008 0.190 1.138 thro Theodore R oos evelt N P West 16.08 12.4483128 20.77156726 16.0685 0.40268302 0.048 0.040 0.189 0.008 0.201 1.208 thla Thous and Lakes W ilder nes s West 16.1 12.4607673 20.79234922 16.162 0.40340448 0.048 0.040 0.190 0.008 0.202 1.210 ths i Three Sis ters W ilder nes s West 17.01 13.1653067 21.96796142 16.7945 0.45154162 0.054 0.045 0.212 0.009 0.226 1.355 tuxe Tuxedni West 16.58 12.8402542 21.42557052 16.591 0.43164957 0.052 0.043 0.203 0.009 0.216 1.295 ulbe ULBend West 15.87 12.287532 20.5032845 15.9035 0.38969881 0.047 0.039 0.183 0.008 0.195 1.169 upbu Up per Buffalo W ilder nes s Eas t 21.04 14.3332941 30.89471374 21.301 0.39250853 0.090 0.039 0.550 0.008 0.196 1.178 vent Ve ntana W ilder nes s West 16.09 12.4607673 20.79234922 16.041 0.40406688 0.048 0.040 0.190 0.008 0.202 1.212 viis Vi rgin Isl ands N P (b) voya Voyageurs N P Eas t 20.64 14.0635324 30.31325553 20.78125 0.38191094 0.088 0.038 0.535 0.008 0.191 1.146 wash Wash akie W ildernes s West 15.73 12.1774404 20.31958284 15.744 0.38000705 0.046 0.038 0.179 0.008 0.190 1.140 we mi We mi nuc he W ildernes s West 15.68 12.1409628 20.25871544 15.645 0.37693008 0.045 0.038 0.177 0.008 0.188 1.131 we el West

Elk W ildernes s West 15.71 12.1531099 20.27898429 15.6945 0.37707703 0.045 0.038 0.177 0.008 0.189 1.131 wh pe Wh eeler

Peak W ilder nes s West 15.7 12.1531099 20.27898429 15.7 0.37773857 0.045 0.038 0.178 0.008 0.189 1.133 wh mo Wh ite Mountain W ilder nes s West 15.56 12.0442226 20.09729227 15.557 0.36766594 0.044 0.037 0.173 0.007 0.184 1.103 wi ch Wi ch ita Mountains Eas t 20.6 14.0354335 30.2526896 20.707 0.38070127 0.088 0.038 0.533 0.008 0.190 1.142 wi ca Wi nd C ave N P West 15.97 12.3614789 20.62667401 15.997 0.3955576 0.047 0.040 0.186 0.008 0.198 1.187 wo lf Wo lf Isl and Eas t 21.33 14.5353715 31.3302816 21.57325 0.40029757 0.092 0.040 0.560 0.008 0.200 1.201 yell Ye llow stone NP West 15.77 12.2140276 20.38063312 15.7935 0.38371362 0.046 0.038 0.180 0.008 0.192 1.151 yobo Yo lla Bolly Middle Eel W ildernes s West 16.25 12.5734204 20.98032498 16.338 0.41174726 0.049 0.041 0.194 0.008 0.206 1.235 yos e Yose mi te N P West 15.81 12.2384801 20.42143517 15.854 0.38528056 0.046 0.039 0.181 0.008 0.193 1.156 zi on Zi on NP West 15.56 12.0442226 20.09729227 15.5625 0.36766594 0.044 0.037 0.173 0.007 0.184 1.103

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 July 16 , 2012 **Natural conce ntrations for be**  **st and wor** **st 20% of day s,**  **From T**  **able 2-1**  Am mo nium

su lfate Am mo nium

nitrate Org anic

ca rbon Elem ental

ca rbon Soil Coars e Mass **scale d from** 

**annual conce ntrations B20 and W**  **20 e xtinction**  West c onc . 0.12 0.1 0.47 0.02 0.5 3 Eas t c onc . 0.23 0.1 1.4 0.02 0.5 3 bex t c alc ulated asa c hec k, us ing table A-2, "rec om mended" f(RH) at IMPROVE site dry ext. eff. 3 3 4 10 1 0.6 

### Wo **rs t 2**  **0% days**  **concent ra** **ti ons**  From Bes t & W

ors t dv check Sc aled fromannual by (b_W 20 - 10) / (b_Ann - 10) abbr Cl as s IA

rea West / Eas t An nl A

vg (Mm- 1) Best

Days (Mm- 1) Wo rs t Days

(Mm- 1) An nl avg b

from c onc (Bes t-10) /

(A vg-10) (W ors t-10) /

(A vg-10) Am mo nium

su lfate Am mo nium

nitrate Org anic

ca rbon Elem ental

ca rbon Soil Coars e Mass ac ad Ac adia NP Eas t 21.4 14.5790431 31.42441357 21.4495 0.40167045 1.87933452 0.432 0.188 2.631 0.038 0.940 5.638 agti Ag ua Tibia W ildernes s West 15.86 12.2752506 20.48279147 15.8815 0.38826803 1.78887226 0.215 0.179 0.841 0.036 0.894 5.367 alla Al pine Lake W ildernes s West 16.99 13.152148 21.94600444 16.789 0.45095108 1.70901351 0.205 0.171 0.803 0.034 0.855 5.127 anac An ac onda-Pintler W ildernes s West 16.03 12.4110238 20.70934594 16.074 0.39983811 1.77601094 0.213 0.178 0.835 0.036 0.888 5.328 anad An se l A

dam s Wi ldernes s West 15.78 12.2140276 20.38063312 15.777 0.38304975 1.79595729 0.216 0.180 0.844 0.036 0.898 5.388 arc h Arch es N P West 15.58 12.0562729 20.11739961 15.568 0.36850768 1.81315405 0.218 0.181 0.852 0.036 0.907 5.439 badl Badlands N P West 16.06 12.4358707 20.75080608 16.063 0.40195886 1.77406041 0.213 0.177 0.834 0.035 0.887 5.322 band Bandelier N M West 15.62 12.092496 20.17784243 15.6065 0.37233024 1.81100399 0.217 0.181 0.851 0.036 0.906 5.433 bes e Bering Sea bibe Big Bend N P West 15.48 11.9841518 19.99705661 15.568 0.3620715 1.8242804 0.219 0.182 0.857 0.036 0.912 5.473 blc a Blac k C anyon of the Gunnis on N M West 15.68 12.1409628 20.25871544 15.6835 0.37693008 1.80611187 0.217 0.181 0.849 0.036 0.903 5.418 bom a Bob M

ars hall W ildernes s West 16.17 12.5107102 20.87568518 16.2775 0.40692224 1.76267183 0.212 0.176 0.828 0.035 0.881 5.288 bos q Bos que del A

pac he West 15.54 12.0321844 20.07720502 15.535 0.36682029 1.81899008 0.218 0.182 0.855 0.036 0.909 5.457 bowa Boundary W aters Canoe A rea Eas t 20.89 14.2333114 30.6792059 20.99575 0.38873383 1.89891698 0.437 0.190 2.658 0.038 0.949 5.697 bret Breton Eas t 21.57 14.6961432 31.67681715 21.9115 0.40588965 1.87353649 0.431 0.187 2.623 0.037 0.937 5.621 brid Bridger W ildernes s West 15.71 12.1652691 20.29927341 15.744 0.37920649 1.80372564 0.216 0.180 0.848 0.036 0.902 5.411 brig Brigantine Eas t 21.05 14.3332941 30.89471374 21.1195 0.39215332 1.89092432 0.435 0.189 2.647 0.038 0.945 5.673 brc a Bryce

Canyon N P West 15.58 12.0562729 20.11739961 15.568 0.36850768 1.81315405 0.218 0.181 0.852 0.036 0.907 5.439 ca mo Ca binet Mountains W ildernes s West 16.27 12.5985924 21.02232762 16.3435 0.41444855 1.75794699 0.211 0.176 0.826 0.035 0.879 5.274 ca cr Ca ney C reek W ildernes s Eas t 21.14 14.4051401 31.04957414 21.433 0.39543448 1.88954885 0.435 0.189 2.645 0.038 0.945 5.669 ca ny Ca nyonlands N P West 15.6 12.0804095 20.15767467 15.546 0.3715017 1.81387048 0.218 0.181 0.853 0.036 0.907 5.442 ca pe Ca pe Rom ain Eas t 21.22 14.4484204 31.14286273 21.47425 0.39647241 1.88439062 0.433 0.188 2.638 0.038 0.942 5.653 ca re Ca pitol Reef N P West 15.63 12.1045945 20.19803037 15.6285 0.37381785 1.81137307 0.217 0.181 0.851 0.036 0.906 5.434 ca ri Ca ribou W ildernes s West 16.05 12.423441 20.73006564 16.1345 0.40056876 1.77356457 0.213 0.177 0.834 0.035 0.887 5.321 cave Ca rls bad C averns N P West 15.61 12.092496 20.17784243 15.6065 0.37299394 1.81423216 0.218 0.181 0.853 0.036 0.907 5.443 ch as Ch as sa how itz ka Eas t 21.46 14.6082304 31.48732529 21.796 0.40211434 1.87498475 0.431 0.187 2.625 0.037 0.937 5.625 ch ir Ch iricahua N M West 15.47 11.9721736 19.97706954 15.4965 0.36054363 1.82396153 0.219 0.182 0.857 0.036 0.912 5.472 ch ir Ch iricahua W ildernes s West 15.45 11.9602074 19.95710246 15.4855 0.35967109 1.82699128 0.219 0.183 0.859 0.037 0.913 5.481 co hu Co hutta W ildernes s Eas t 21.39 14.5644713 31.39300486 21.60625 0.40074375 1.87822694 0.432 0.188 2.630 0.038 0.939 5.635 crla Crater Lake N P West 16.74 12.956338 21.619271 16.767 0.43862582 1.72392745 0.207 0.172 0.810 0.034 0.862 5.172 crmo Craters of the M

oon N M West 15.8 12.2262477 20.40102395 15.8155 0.38383581 1.79327999 0.215 0.179 0.843 0.036 0.897 5.380 cu ca Cu ca mo nga W ildernes s West 15.85 12.2752506 20.48279147 15.8485 0.38893173 1.79193017 0.215 0.179 0.842 0.036 0.896 5.376 dena De nali Pres erve N P West 16.27 12.5860001 21.0013158 16.041 0.41244021 1.75459582 0.211 0.175 0.825 0.035 0.877 5.264 des o De so lation W ildernes s West 15.8 12.2262477 20.40102395 15.8045 0.38383581 1.79327999 0.215 0.179 0.843 0.036 0.897 5.380 dipe Di am ond Peak W ildernes s West 16.84 13.0343098 21.74937656 16.7945 0.44361254 1.71774511 0.206 0.172 0.807 0.034 0.859 5.153 dos o Do lly Sods W ildernes s Eas t 21.13 14.3907421 31.01854009 21.268 0.39449615 1.88845823 0.434 0.189 2.644 0.038 0.944 5.665 dola Do meLand W ildernes s West 15.7 12.1531099 20.27898429 15.7 0.37773857 1.80333058 0.216 0.180 0.848 0.036 0.902 5.410

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 July 16 , 2012 **Wo rs** **t 2 0%**  **d ays**  **concent ra** **ti ons**  From Bes t & W

ors t dv ch ec k Sc aled fromannual by (b_W 20 - 10) / (b_Ann - 10) abbr Cl as s IA

rea West / East An nl A

vg (Mm- 1) Bes t Days

(Mm- 1) Wo rst Days

(Mm- 1) An nl avg b

from c onc (Bes t-10) /

(A vg-10) (W ors t-10) /

(A vg-10) Am mo nium

su lfate Am mo nium

nitrate Org anic

ca rbon Elem ental

ca rbon Soil Coars e Mass eac a Eagle C ap W ildernes s West 16.12 12.4857138 20.83397553 16.03 0.40616238 1.77025744 0.212 0.177 0.832 0.035 0.885 5.311 eane Eagles N es t W ildernes s West 15.72 12.1652691 20.29927341 15.7165 0.37854354 1.80057228 0.216 0.180 0.846 0.036 0.900 5.402 em ig Em igrant W ildernes s West 15.81 12.2384801 20.42143517 15.8155 0.38528056 1.79370657 0.215 0.179 0.843 0.036 0.897 5.381 ever Everglades N P East 20.77 14.1481673 30.49568179 20.74 0.38515945 1.90303452 0.438 0.190 2.664 0.038 0.952 5.709 fitz Fitz patric k W ildernes s West 15.73 12.1774404 20.31958284 15.7275 0.38000705 1.80097432 0.216 0.180 0.846 0.036 0.900 5.403 flto Flat Tops W ildernes s West 15.7 12.1531099 20.27898429 15.7 0.37773857 1.80333058 0.216 0.180 0.848 0.036 0.902 5.410 gali Galiuro W ildernes s West 15.4 11.9243806 19.89732087 15.4195 0.35636678 1.8328372 0.220 0.183 0.861 0.037 0.916 5.499 gam o Gates of the Mountains W ildernes s West 15.93 12.3367806 20.58546189 15.964 0.39406081 1.78506946 0.214 0.179 0.839 0.036 0.893 5.355 gem o Gearhart Mountain W ildernes s West 16.33 12.6364449 21.0854893 16.349 0.41649999 1.75126213 0.210 0.175 0.823 0.035 0.876 5.254 gila Gila W ildernes s West 15.51 12.0081441 20.03709074 15.535 0.36445446 1.82161356 0.219 0.182 0.856 0.036 0.911 5.465 glac Glac ierN P West 16.48 12.7634433 21.29740199 16.591 0.4264573 1.74342623 0.209 0.174 0.819 0.035 0.872 5.230 glpe Glac ierPeak W ildernes s West 16.88 13.0734714 21.81472265 16.756 0.44672549 1.7172562 0.206 0.172 0.807 0.034 0.859 5.152 goro Goat R oc ks W ildernes s West 16.93 13.0996445 21.85839576 16.8 0.44727915 1.71116822 0.205 0.171 0.804 0.034 0.856 5.134 grc a Grand Canyon N P West 15.51 12.0081441 20.03709074 15.546 0.36445446 1.82161356 0.219 0.182 0.856 0.036 0.911 5.465 grte Grand Teton N P West 15.74 12.1774404 20.31958284 15.7495 0.37934502 1.79783673 0.216 0.180 0.845 0.036 0.899 5.394 grgu Great Gulf W ildernes s East 21.1 14.3763586 30.98753705 21.202 0.39426654 1.8907691 0.435 0.189 2.647 0.038 0.945 5.672 grs a Great S and Dunes N M West 15.74 12.1896239 20.33991259 15.777 0.38146759 1.8013785 0.216 0.180 0.847 0.036 0.901 5.404 grs m Great S mo ky Mountains N P East 21.39 14.5644713 31.39300486 21.52375 0.40074375 1.87822694 0.432 0.188 2.630 0.038 0.939 5.635 gum o Guadalupe Mountains N P West 15.64 12.1045945 20.19803037 15.612 0.37315506 1.80816141 0.217 0.181 0.850 0.036 0.904 5.424 hale Haleakala NP West 16.02 12.398619 20.68864694 16.052 0.39844169 1.77552275 0.213 0.178 0.834 0.036 0.888 5.327 havo Haw aii V

olc anoes N P West 16.33 12.6490877 21.10658534 16.448 0.41849726 1.75459484 0.211 0.175 0.825 0.035 0.877 5.264 hec a Hells C anyon W ildernes s West 16.09 12.4607673 20.79234922 16.052 0.40406688 1.77214273 0.213 0.177 0.833 0.035 0.886 5.316 herc Hercu les -G lades W ildernes s East 21.03 14.318968 30.86383447 21.202 0.39156555 1.89155344 0.435 0.189 2.648 0.038 0.946 5.675 hoov Hoover

W ildernes s West 15.78 12.2140276 20.38063312 15.7825 0.38304975 1.79595729 0.216 0.180 0.844 0.036 0.898 5.388 is ro Is le Royale N P East 20.91 14.2475519 30.70990045 20.971 0.38932648 1.89824935 0.437 0.190 2.658 0.038 0.949 5.695 jari Jam es River Fac e W ildernes s East 20.96 14.2760755 30.77138172 21.11125 0.39015287 1.89519906 0.436 0.190 2.653 0.038 0.948 5.686 jarb Jarbidge W ildernes s West 15.75 12.1896239 20.33991259 15.777 0.38080416 1.79824567 0.216 0.180 0.845 0.036 0.899 5.395 jom u John M uir W ildernes s West 15.8 12.2384801 20.42143517 15.777 0.38594484 1.79679917 0.216 0.180 0.844 0.036 0.898 5.390 jotr Jos hua Tree N M West 15.72 12.1652691 20.29927341 15.7385 0.37854354 1.80057228 0.216 0.180 0.846 0.036 0.900 5.402 joyc Joyc e- Kilm er-Slic kroc k W ildernes s East 21.4 14.5790431 31.42441357 21.57325 0.40167045 1.87933452 0.432 0.188 2.631 0.038 0.940 5.638 kais Kais erW ildernes s West 15.8 12.2262477 20.40102395 15.799 0.38383581 1.79327999 0.215 0.179 0.843 0.036 0.897 5.380 kalm Kalm iops is W ildernes s West 16.74 12.956338 21.619271 16.8275 0.43862582 1.72392745 0.207 0.172 0.810 0.034 0.862 5.172 kic a Kings C anyon NP West 15.79 12.2262477 20.40102395 15.7825 0.38449874 1.79637719 0.216 0.180 0.844 0.036 0.898 5.389 laga La Gar ita W ildernes s West 15.69 12.1409628 20.25871544 15.6835 0.37626763 1.80293769 0.216 0.180 0.847 0.036 0.901 5.409 lavo Las se n V

olc anicN P West 16.08 12.4483128 20.77156726 16.162 0.40268302 1.77163935 0.213 0.177 0.833 0.035 0.886 5.315 labe Lava B eds N M West 16.37 12.6744112 21.14884075 16.316 0.41984477 1.75021048 0.210 0.175 0.823 0.035 0.875 5.251 ligo Linville Gorge W ildernes s East 21.36 14.5499141 31.36162755 21.60625 0.40052061 1.88042496 0.432 0.188 2.633 0.038 0.940 5.641 los t Los twood West 16.11 12.4732343 20.81315197 16.151 0.40478467 1.76974664 0.212 0.177 0.832 0.035 0.885 5.309 lybr Lye Brook W ildernes s East 20.99 14.2903587 30.80216849 21.06175 0.39038751 1.89282698 0.435 0.189 2.650 0.038 0.946 5.678 ma ca Ma mmoth Cave N P East 21.58 14.6961432 31.67681715 21.42475 0.40553914 1.87191858 0.431 0.187 2.621 0.037 0.936 5.616 ma mo Ma rble Mountain W ildernes s West 16.65 12.891718 21.51144444 16.7505 0.43484482 1.73104428 0.208 0.173 0.814 0.035 0.866 5.193 ma be Ma roon Bells -Snowm as s Wi ldernes s West 15.7 12.1531099 20.27898429 15.7165 0.37773857 1.80333058 0.216 0.180 0.848 0.036 0.902 5.410 maza Mazatz al W ildernes s West 15.44 11.9602074 19.95710246 15.4525 0.36033225 1.83034972 0.220 0.183 0.860 0.037 0.915 5.491

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 July 16 , 2012 **Wo rs** **t 2 0%**  **d ays**  **concent ra** **ti ons**  From Bes t & W

ors t dv ch ec k Sc aled fromannual by (b_W 20 - 10) / (b_Ann - 10) abbr Cl as s IA

rea West / East An nl A

vg (Mm- 1) Bes t Days

(Mm- 1) Wo rst Days

(Mm- 1) An nl avg b

from c onc (Bes t-10) /

(A vg-10) (W ors t-10) /

(A vg-10) Am mo nium

su lfate Am mo nium

nitrate Org anic

ca rbon Elem ental

ca rbon Soil Coars e Mass me di Me dic ine Lake West 16.07 12.4358707 20.75080608 16.1125 0.40129665 1.77113774 0.213 0.177 0.832 0.035 0.886 5.313 meve MesaV

erde N P West 15.73 12.1774404 20.31958284 15.623 0.38000705 1.80097432 0.216 0.180 0.846 0.036 0.900 5.403 mi ng Mi ngo East 21.03 14.318968 30.86383447 21.21025 0.39156555 1.89155344 0.435 0.189 2.648 0.038 0.946 5.675 mi mo Mi ssi on Mountains W ildernes s West 16.21 12.5482987 20.93840627 16.2555 0.41035405 1.76141808 0.211 0.176 0.828 0.035 0.881 5.284 mo ke Mo kelum ne W ildernes s West 15.8 12.2384801 20.42143517 15.8045 0.38594484 1.79679917 0.216 0.180 0.844 0.036 0.898 5.390 moos Moos ehorn East 21.22 14.4484204 31.14286273 21.27625 0.39647241 1.88439062 0.433 0.188 2.638 0.038 0.942 5.653 moad Mo unt A

dam s Wi ldernes s West 16.86 13.0473506 21.77113681 16.844 0.4442202 1.71590916 0.206 0.172 0.806 0.034 0.858 5.148 mo ba Mo unt Baldy W ildernes s West 15.51 12.0081441 20.03709074 15.513 0.36445446 1.82161356 0.219 0.182 0.856 0.036 0.911 5.465 mo ho Mo unt H ood W ildernes s West 16.83 13.0343098 21.74937656 16.7835 0.44426204 1.72026011 0.206 0.172 0.809 0.034 0.860 5.161 mo je Mo unt Jeffers on W ildernes s West 16.91 13.0865514 21.83654829 16.7725 0.44667893 1.71295923 0.206 0.171 0.805 0.034 0.856 5.139 mo ra Mo unt Rainier N P West 17.05 13.204862 22.03396426 16.976 0.45459035 1.70694529 0.205 0.171 0.802 0.034 0.853 5.121 mowa Mo unt W as hington W ildernes s West 17.03 13.1916637 22.01194131 16.7835 0.45400622 1.70866875 0.205 0.171 0.803 0.034 0.854 5.126 mozi Mo unt Zirkel W ildernes s West 15.71 12.1652691 20.29927341 15.7165 0.37920649 1.80372564 0.216 0.180 0.848 0.036 0.902 5.411 mo la Mo untain Lakes W ildernes s West 16.5 12.7762131 21.31871004 16.514 0.42710971 1.74134001 0.209 0.174 0.818 0.035 0.871 5.224 noab North Abs aroka W ildernes s West 15.74 12.1774404 20.31958284 15.755 0.37934502 1.79783673 0.216 0.180 0.845 0.036 0.899 5.394 noc a North C as ca des N P West 16.86 13.0473506 21.77113681 16.7615 0.4442202 1.71590916 0.206 0.172 0.806 0.034 0.858 5.148 okef Okefenokee East 21.41 14.5790431 31.42441357 21.631 0.40131841 1.87768743 0.432 0.188 2.629 0.038 0.939 5.633 olym Ol ym picN P West 17.02 13.1784786 21.98994037 16.9925 0.45277474 1.70796871 0.205 0.171 0.803 0.034 0.854 5.124 otc r Otter C reek W ildernes s East 21.14 14.4051401 31.04957414 21.32575 0.39543448 1.88954885 0.435 0.189 2.645 0.038 0.945 5.669 pas a Pas ayten W ildernes s West 16.84 13.0343098 21.74937656 16.7615 0.44361254 1.71774511 0.206 0.172 0.807 0.034 0.859 5.153 pec o Pec os W ildernes s West 15.65 12.1167052 20.2182385 15.6395 0.37463808 1.80853779 0.217 0.181 0.850 0.036 0.904 5.426 pefo Petrified Fores t N P West 15.54 12.0321844 20.07720502 15.535 0.36682029 1.81899008 0.218 0.182 0.855 0.036 0.909 5.457 pim o Pine Mountain W ildernes s West 15.47 11.9721736 19.97706954 15.469 0.36054363 1.82396153 0.219 0.182 0.857 0.036 0.912 5.472 pinn Pinnac les N M West 16.12 12.4857138 20.83397553 15.986 0.40616238 1.77025744 0.212 0.177 0.832 0.035 0.885 5.311 pore Point R eyes N S West 16.2 12.5482987 20.93840627 16.2555 0.41101592 1.76425908 0.212 0.176 0.829 0.035 0.882 5.293 prra Pres idential Range-Dry River W ilder nes s East 21.15 14.4051401 31.04957414 21.301 0.39507983 1.88785418 0.434 0.189 2.643 0.038 0.944 5.664 rala Ra inbow Lake W ildernes s East 20.99 14.3046562 30.83298606 18.1 0.39168846 1.89563113 0.436 0.190 2.654 0.038 0.948 5.687 rawa Rawa h W ildernes s West 15.72 12.1652691 20.29927341 15.722 0.37854354 1.80057228 0.216 0.180 0.846 0.036 0.900 5.402 redr Re d R oc k Lakes West 15.81 12.2384801 20.42143517 15.8155 0.38528056 1.79370657 0.215 0.179 0.843 0.036 0.897 5.381 redw Re dw ood N P West 16.9 13.0865514 21.83654829 17.174 0.44732629 1.71544178 0.206 0.172 0.806 0.034 0.858 5.146 rom o Ro ck

y Mo untain N P West 15.67 12.1288279 20.23846685 15.6395 0.37545466 1.80572608 0.217 0.181 0.849 0.036 0.903 5.417 roc a Roos evelt Cam pobello I nternational P ark East 21.22 14.4484204 31.14286273 21.2845 0.39647241 1.88439062 0.433 0.188 2.638 0.038 0.942 5.653 sa gu Saguaro N M West 15.35 11.8767783 19.81789055 15.37 0.35079969 1.83511973 0.220 0.184 0.863 0.037 0.918 5.505 st ma Saint Marks East 21.54 14.6667803 31.61352682 21.8455 0.40440037 1.8729226 0.431 0.187 2.622 0.037 0.936 5.619 sa cr Salt Creek West 15.58 12.0562729 20.11739961 15.5845 0.36850768 1.81315405 0.218 0.181 0.852 0.036 0.907 5.439 sa ga San Gabriel W ildernes s West 15.86 12.2752506 20.48279147 15.8705 0.38826803 1.78887226 0.215 0.179 0.841 0.036 0.894 5.367 sa go San Gorgonio W ildernes s West 15.74 12.1896239 20.33991259 15.8155 0.38146759 1.8013785 0.216 0.180 0.847 0.036 0.901 5.404 sa ja San Jac into W ildernes s West 15.78 12.2140276 20.38063312 15.8155 0.38304975 1.79595729 0.216 0.180 0.844 0.036 0.898 5.388 sa pe San Pedro Parks W ildernes s West 15.63 12.1045945 20.19803037 15.612 0.37381785 1.81137307 0.217 0.181 0.851 0.036 0.906 5.434 sa ra San Rafael W ildernes s West 16.03 12.4110238 20.70934594 16.0245 0.39983811 1.77601094 0.213 0.178 0.835 0.036 0.888 5.328 sawt Sawtooth W ildernes s West 15.82 12.2507247 20.44186682 15.854 0.38672245 1.79413519 0.215 0.179 0.843 0.036 0.897 5.382 sca p Sc apegoat W ildernes s West 16.05 12.423441 20.73006564 16.0905 0.40056876 1.77356457 0.213 0.177 0.834 0.035 0.887 5.321

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 July 16 , 2012 **Wo rs** **t 2 0%**  **d ays**  **concent ra** **ti ons**  From Bes t & W

ors t dv ch ec k Sc aled fromannual by (b_W 20 - 10) / (b_Ann - 10) abbr Cl as s IA

rea West / East An nl A

vg (Mm- 1) Bes t Days

(Mm- 1) Wo rst Days

(Mm- 1) An nl avg b

from c onc (Bes t-10) /

(A vg-10) (W ors t-10) /

(A vg-10) Am mo nium

su lfate Am mo nium

nitrate Org anic

ca rbon Elem ental

ca rbon Soil Coars e Mass se lw Selway-Bitterroot W ildernes s West 16.09 12.4607673 20.79234922 16.107 0.40406688 1.77214273 0.213 0.177 0.833 0.035 0.886 5.316 se ne Seney East 21.23 14.462876 31.17402116 21.367 0.39740659 1.88548719 0.434 0.189 2.640 0.038 0.943 5.656 se qu Sequoia N P West 15.79 12.2262477 20.40102395 15.744 0.38449874 1.79637719 0.216 0.180 0.844 0.036 0.898 5.389 sh en Shenandoah N P East 20.98 14.2903587 30.80216849 21.25975 0.39074305 1.89455086 0.436 0.189 2.652 0.038 0.947 5.684 sh ro Shining Roc k W ildernes s East 21.4 14.5790431 31.42441357 21.62275 0.40167045 1.87933452 0.432 0.188 2.631 0.038 0.940 5.638 si an Sierra A

nc ha W ildernes s West 15.46 11.9721736 19.97706954 15.4635 0.36120396 1.82730211 0.219 0.183 0.859 0.037 0.914 5.482 si me Sim eonof West 17.21 13.3242421 22.233165 17.1795 0.46105994 1.69669417 0.204 0.170 0.797 0.034 0.848 5.090 si ps Sips ey W ildernes s East 21.28 14.4918307 31.2364316 21.499 0.39821194 1.88266238 0.433 0.188 2.636 0.038 0.941 5.648 sowa South W arner W ildernes s West 16.09 12.4607673 20.79234922 16.074 0.40406688 1.77214273 0.213 0.177 0.833 0.035 0.886 5.316 st mo Strawberry Mountain W ildernes s West 16.37 12.6744112 21.14884075 16.2445 0.41984477 1.75021048 0.210 0.175 0.823 0.035 0.875 5.251 su pe Supers tition W ildernes s West 15.4 11.9243806 19.89732087 15.447 0.35636678 1.8328372 0.220 0.183 0.861 0.037 0.916 5.499 swa n Swanquarter East 20.91 14.2475519 30.70990045 21.06175 0.38932648 1.89824935 0.437 0.190 2.658 0.038 0.949 5.695 syca Syc am ore Canyon W ildernes s West 15.53 12.0201582 20.05713785 15.7385 0.3653089 1.81865061 0.218 0.182 0.855 0.036 0.909 5.456 teto Teton W ildernes s West 15.74 12.1774404 20.31958284 15.7495 0.37934502 1.79783673 0.216 0.180 0.845 0.036 0.899 5.394 thro Theodore Roos evelt N P West 16.08 12.4483128 20.77156726 16.0685 0.40268302 1.77163935 0.213 0.177 0.833 0.035 0.886 5.315 thla Thous and Lakes W ildernes s West 16.1 12.4607673 20.79234922 16.162 0.40340448 1.76923758 0.212 0.177 0.832 0.035 0.885 5.308 ths i Three Sis ters W ildernes s West 17.01 13.1653067 21.96796142 16.7945 0.45154162 1.70726982 0.205 0.171 0.802 0.034 0.854 5.122 tuxe Tuxedni West 16.58 12.8402542 21.42557052 16.591 0.43164957 1.73640889 0.208 0.174 0.816 0.035 0.868 5.209 ulbe UL Bend West 15.87 12.287532 20.5032845 15.9035 0.38969881 1.78931593 0.215 0.179 0.841 0.036 0.895 5.368 upbu Upper Buffalo W ildernes s East 21.04 14.3332941 30.89471374 21.301 0.39250853 1.89263711 0.435 0.189 2.650 0.038 0.946 5.678 vent Ve ntana W ildernes s West 16.09 12.4607673 20.79234922 16.041 0.40406688 1.77214273 0.213 0.177 0.833 0.035 0.886 5.316 viis Vi rgin I sl ands N P (b) voya Voyageurs N P East 20.64 14.0635324 30.31325553 20.78125 0.38191094 1.90914056 0.439 0.191 2.673 0.038 0.955 5.727 wash Wash akie W ildernes s West 15.73 12.1774404 20.31958284 15.744 0.38000705 1.80097432 0.216 0.180 0.846 0.036 0.900 5.403 we mi We mi nuc he W ildernes s West 15.68 12.1409628 20.25871544 15.645 0.37693008 1.80611187 0.217 0.181 0.849 0.036 0.903 5.418 we el West

Elk W ildernes s West 15.71 12.1531099 20.27898429 15.6945 0.37707703 1.80017238 0.216 0.180 0.846 0.036 0.900 5.401 wh pe Wh eeler Peak W ildernes s West 15.7 12.1531099 20.27898429 15.7 0.37773857 1.80333058 0.216 0.180 0.848 0.036 0.902 5.410 wh mo Wh ite Mountain W ildernes s West 15.56 12.0442226 20.09729227 15.557 0.36766594 1.81605976 0.218 0.182 0.854 0.036 0.908 5.448 wi ch Wi ch ita Mountains East 20.6 14.0354335 30.2526896 20.707 0.38070127 1.91063109 0.439 0.191 2.675 0.038 0.955 5.732 wi ca Wi nd C ave NP West 15.97 12.3614789 20.62667401 15.997 0.3955576 1.7800124 0.214 0.178 0.837 0.036 0.890 5.340 wo lf Wo lf Isl and East 21.33 14.5353715 31.3302816 21.57325 0.40029757 1.88263739 0.433 0.188 2.636 0.038 0.941 5.648 yell Ye llow stone N P West 15.77 12.2140276 20.38063312 15.7935 0.38371362 1.79906986 0.216 0.180 0.846 0.036 0.900 5.397 yobo Yo lla B olly Middle Eel W ildernes s West 16.25 12.5734204 20.98032498 16.338 0.41174726 1.756852 0.211 0.176 0.826 0.035 0.878 5.271 yos e Yose mi te N P West 15.81 12.2384801 20.42143517 15.854 0.38528056 1.79370657 0.215 0.179 0.843 0.036 0.897 5.381 zi on Zi on N P West 15.56 12.0442226 20.09729227 15.5625 0.36766594 1.81605976 0.218 0.182 0.854 0.036 0.908 5.448

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 

# Ap **pendix D :** 

**Natural Background Conditions for**  **IMPROVE Method 8**  **(taken from FLA G**  **- 2010)** 

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 **Table 5. 20% Best Natural Conditions**  **– Concentrations and Ray**  **leigh Scattering By Class I Area**  **a** 

### Class I Area **(NH 4**  

### ) **2** 

### SO **4** 

### μg/m3 **NH 4**  

### NO **3**



### μg/m3 **OM**

**μg/m 3**  

### EC **μg/m 3**  

### Soil **μg/m 3**  

### CM **μg/m 3**  

### Sea

**Salt μg/m**  **3** 

### Ra **y******

**leigh Mm**  **- 1**  

### Ty**pe** Acadia NP 0.09 0.03 0.68 0.01 0.10 0.94 0.03 12 B20% Agua Tibia W ilderness 0.03 0.04 0.26 0.01 0.26 1.20 0.04 11 B20% Alpine Lakes W ilderness 0.04 0.03 0.15 0.01 0.05 0.30 0.02 11 B20% Anaconda Pintler W ilderness 0.04 0.03 0.12 0.01 0.07 0.31 0.00 10 B20% Ansel Adams W ilderness 0.02 0.01 0.12 0.01 0.07 0.44 0.01 9 B20% Arches NP 0.07 0.06 0.23 0.01 0.14 0.89 0.01 9 B20% Badlands NP 0.05 0.05 0.23 0.01 0.22 0.99 0.00 11 B20% Bandelier NM 0.07 0.06 0.31 0.01 0.16 0.91 0.00 9 B20% Bering Sea W ilderness - - - - - - - - B20% Big Bend NP 0.05 0.04 0.24 0.01 0.11 0.80 0.00 10 B20% Black Canyon of the Gunnison NP 0.06 0.04 0.24 0.01 0.13 0.88 0.00 9 B20% Bob Marshall Wi lderness 0.05 0.04 0.19 0.01 0.08 0.37 0.00 10 B20% Bosque del Apache Wi lderness 0.08 0.06 0.30 0.01 0.15 0.97 0.02 10 B20% Boundary W aters Canoe Area Wi lderness 0.11 0.02 0.50 0.01 0.13 0.86 0.01 11 B20% Breton Wi lderness 0.14 0.05 0.73 0.01 0.27 2.26 0.07 11 B20% Bridger Wi lderness 0.05 0.04 0.14 0.01 0.07 0.33 0.00 9 B20% Brigantine Wi lderness 0.12 0.04 0.86 0.01 0.24 1.73 0.04 12 B20% Bryce Canyon NP 0.04 0.05 0.18 0.01 0.10 0.60 0.00 9 B20% Cabinet Mountains W ilderness 0.05 0.05 0.13 0.01 0.09 0.42 0.01 10 B20% Caney Creek Wi lderness 0.07 0.06 0.68 0.01 0.14 1.51 0.02 11 B20% Canyonlands NP 0.07 0.06 0.23 0.01 0.14 0.89 0.01 9 B20% Cape Romain W ilderness 0.14 0.06 0.88 0.01 0.24 1.99 0.04 12 B20% Capitol Reef NP 0.06 0.07 0.26 0.01 0.15 0.79 0.01 9 B20% Caribou Wi lderness 0.03 0.02 0.12 0.01 0.08 0.24 0.01 10 B20% Carlsbad Caverns NP 0.06 0.05 0.26 0.01 0.12 0.82 0.00 9 B20% Chassahowitzka W ilderness 0.14 0.08 1.02 0.01 0.28 2.46 0.02 11 B20% Chiricahua NM 0.06 0.05 0.27 0.01 0.13 0.81 0.00 10 B20% Chiricahua W ilderness 0.06 0.05 0.27 0.01 0.13 0.81 0.00 10 B20% Cohutta Wi lderness 0.09 0.08 0.69 0.01 0.15 1.06 0.01 11 B20% Crater Lake NP 0.02 0.02 0.08 0.01 0.07 0.23 0.01 9 B20% Craters of the Moon NM 0.06 0.05 0.19 0.01 0.12 0.69 0.01 10 B20% Cucamonga W ilderness 0.03 0.03 0.15 0.01 0.14 0.67 0.01 9 B20% Denali NP 0.04 0.02 0.08 0.01 0.05 0.31 0.01 11 B20% Desolation W ilderness 0.04 0.03 0.15 0.01 0.09 0.51 0.01 9 B20% Diamond Peak W ilderness 0.02 0.02 0.08 0.01 0.07 0.23 0.01 9 B20% Dolly Sods W ilderness 0.10 0.05 0.80 0.01 0.17 0.96 0.01 10 B20% Dome Land Wi lderness 0.03 0.02 0.18 0.01 0.08 0.43 0.01 10 B20% Eagle Cap W ilderness 0.05 0.02 0.17 0.01 0.10 0.50 0.01 10 B20%

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 Eagles Nest W ilderness 0.04 0.03 0.14 0.01 0.08 0.36 0.00 8 B20% Emigrant W ilderness 0.03 0.02 0.10 0.00 0.08 0.50 0.01 10 B20% Everglades NP 0.16 0.07 0.77 0.01 0.16 1.86 0.12 11 B20% Fitzpatrick Wi lderness 0.05 0.04 0.14 0.01 0.07 0.33 0.00 9 B20% Flat Tops W ilderness 0.04 0.03 0.14 0.01 0.08 0.36 0.00 8 B20% Galiuro Wi lderness 0.06 0.05 0.27 0.01 0.13 0.81 0.00 10 B20% Gates of the Mountains Wi lderness 0.04 0.04 0.13 0.01 0.07 0.49 0.00 9 B20% Gearhart Mountain W ilderness 0.02 0.02 0.08 0.01 0.07 0.23 0.01 9 B20% Gila W ilderness 0.06 0.04 0.22 0.01 0.09 0.45 0.00 9 B20% Glacier NP 0.05 0.03 0.17 0.01 0.11 0.57 0.00 11 B20% Glacier Peak W ilderness 0.02 0.03 0.09 0.00 0.04 0.28 0.01 11 B20% Goat Rocks Wi lderness 0.02 0.01 0.06 0.00 0.04 0.21 0.01 10 B20% Grand Canyon NP 0.04 0.03 0.12 0.01 0.10 0.59 0.00 9 B20% Grand Teton NP 0.06 0.05 0.17 0.01 0.08 0.33 0.00 9 B20% Great Gulf W ilderness 0.09 0.04 0.56 0.01 0.10 1.05 0.02 11 B20% Great Sand Dunes NP & Pres 0.06 0.05 0.29 0.01 0.15 0.90 0.00 9 B20% Great Smoky Mountains NP 0.09 0.06 0.78 0.01 0.16 1.47 0.01 11 B20% Guadalupe Mountains NP 0.06 0.05 0.26 0.01 0.12 0.82 0.00 9 B20% Haleakala NP 0.05 0.04 0.24 0.01 0.11 1.59 0.13 10 B20% Hawaii Volcanoes NP 0.03 0.04 0.27 0.01 0.06 0.64 0.11 10 B20% Hells Canyon W ilderness 0.06 0.02 0.19 0.01 0.14 0.81 0.01 11 B20% Hercules - Glades W ilderness 0.09 0.06 0.78 0.01 0.16 1.86 0.02 11 B20% Hoover Wi lderness 0.03 0.02 0.08 0.01 0.06 0.55 0.00 9 B20% Isle Royale NP 0.10 0.02 0.34 0.01 0.09 0.79 0.01 12 B20% James River Face W ilderness 0.11 0.06 0.71 0.01 0.20 1.39 0.01 11 B20% Jarbidge Wi lderness 0.05 0.03 0.14 0.01 0.05 0.33 0.00 10 B20% John Muir W ilderness 0.02 0.01 0.12 0.01 0.07 0.44 0.01 9 B20% Joshua Tree NP 0.04 0.02 0.20 0.01 0.17 0.94 0.02 10 B20% Joyce Kilmer- Slickrock Wi lderness 0.09 0.06 0.78 0.01 0.16 1.47 0.01 11 B20% Kaiser W ilderness 0.02 0.01 0.12 0.01 0.07 0.44 0.01 9 B20% Kalmiopsis W ilderness 0.03 0.02 0.31 0.01 0.05 0.99 0.04 12 B20% Kings Canyon 0.03 0.03 0.18 0.01 0.08 0.73 0.02 11 B20% La Garita W ilderness 0.06 0.04 0.24 0.01 0.13 0.88 0.00 9 B20% Lassen Volcanic NP 0.03 0.02 0.12 0.01 0.08 0.24 0.01 10 B20% Lava Beds NM 0.03 0.03 0.14 0.01 0.06 0.46 0.00 10 B20% Linville Gorge W ilderness 0.08 0.06 0.67 0.01 0.14 1.04 0.01 11 B20% Lostwood W ilderness 0.06 0.04 0.23 0.01 0.22 1.05 0.01 11 B20% Lye Brook Wi lderness 0.05 0.03 0.36 0.01 0.09 0.63 0.01 11 B20% Mammoth Cave NP 0.11 0.08 0.86 0.01 0.24 1.54 0.01 11 B20% Marble Mountain Wi lderness 0.03 0.02 0.12 0.01 0.06 0.36 0.01 10 B20% Maroon Bells - Snowmass Wi lderness 0.04 0.03 0.14 0.01 0.08 0.36 0.00 8 B20%

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 Ma zatzal W ilderness 0.06 0.05 0.30 0.01 0.14 0.80 0.00 10 B20% Medicine Lake W ilderness 0.06 0.05 0.24 0.01 0.20 1.13 0.00 11 B20% Mesa Verde NP 0.06 0.05 0.24 0.01 0.17 0.67 0.00 9 B20% Mingo W ilderness 0.12 0.04 0.88 0.01 0.21 1.49 0.01 12 B20% Mission Mountains W ilderness 0.05 0.04 0.19 0.01 0.08 0.37 0.00 10 B20% Mokelumne Wi lderness 0.04 0.03 0.15 0.01 0.09 0.51 0.01 9 B20% Moosehorn W ilderness 0.11 0.04 0.76 0.01 0.12 1.25 0.02 12 B20% Mount Adams Wi lderness 0.02 0.01 0.06 0.00 0.04 0.21 0.01 10 B20% Mount Baldy W ilderness 0.05 0.04 0.19 0.01 0.11 0.53 0.00 9 B20% Mount Hood W ilderness 0.02 0.02 0.06 0.00 0.05 0.15 0.01 10 B20% Mount Jefferson Wi lderness 0.02 0.02 0.08 0.00 0.03 0.31 0.01 11 B20% Mount Rainier NP 0.03 0.02 0.18 0.01 0.06 0.83 0.02 11 B20% Mount W ashington W ilderness 0.02 0.02 0.08 0.00 0.03 0.31 0.01 11 B20% Mount Zirkel W ilderness 0.06 0.04 0.16 0.01 0.09 0.60 0.00 8 B20% Mountain Lakes W ilderness 0.02 0.02 0.08 0.01 0.07 0.23 0.01 9 B20% North Absaroka W ilderness 0.05 0.04 0.16 0.00 0.11 0.82 0.00 9 B20% North Cascades NP 0.02 0.03 0.09 0.00 0.04 0.28 0.01 11 B20% Okefenokee W ilderness 0.13 0.07 0.92 0.01 0.22 1.69 0.03 11 B20% Olympic NP 0.04 0.03 0.23 0.01 0.03 0.50 0.04 11 B20% Otter Creek W ilderness 0.10 0.05 0.80 0.01 0.17 0.96 0.01 10 B20% Pasayten Wi lderness 0.04 0.03 0.07 0.00 0.07 0.24 0.01 10 B20% Pecos W ilderness 0.04 0.03 0.16 0.01 0.08 0.67 0.00 8 B20% Petrified Forest NP 0.06 0.06 0.28 0.01 0.15 0.75 0.00 9 B20% Pine Mountain W ilderness 0.06 0.05 0.30 0.01 0.14 0.80 0.00 10 B20% Pinnacles NM 0.06 0.04 0.31 0.01 0.16 1.50 0.06 11 B20% Point Reyes NS 0.12 0.04 0.33 0.01 0.13 1.08 0.25 12 B20% Presidential Range - Dry River Wi lderness 0.09 0.04 0.56 0.01 0.10 1.05 0.02 11 B20% Rawah W ilderness 0.06 0.04 0.16 0.01 0.09 0.60 0.00 8 B20% Red Rock Lakes W ilderness 0.06 0.05 0.17 0.01 0.08 0.33 0.00 9 B20% Redwood NP 0.05 0.03 0.28 0.01 0.06 1.02 0.10 11 B20% Rocky Mountain NP 0.04 0.02 0.15 0.01 0.09 0.68 0.00 9 B20% Roosevelt Campobello International Park 0.11 0.04 0.76 0.01 0.12 1.25 0.02 12 B20% Saguaro NP 0.07 0.05 0.32 0.01 0.22 1.15 0.03 10 B20% Saint Marks W ilderness 0.14 0.06 0.81 0.01 0.24 2.17 0.04 11 B20% Salt Creek W ilderness 0.05 0.06 0.31 0.01 0.17 1.00 0.02 10 B20% San Gabriel W ilderness 0.03 0.03 0.15 0.01 0.14 0.67 0.01 9 B20% San Gorgonio Wi lderness 0.03 0.02 0.15 0.01 0.10 0.62 0.02 10 B20% San Jacinto W ilderness 0.03 0.02 0.15 0.01 0.10 0.62 0.02 10 B20% San Pedro Parks W ilderness 0.05 0.04 0.14 0.01 0.09 0.34 0.01 8 B20% San Rafael W ilderness 0.03 0.04 0.22 0.01 0.11 0.79 0.02 10 B20% Sawtooth W ilderness 0.05 0.04 0.23 0.01 0.10 0.37 0.00 10 B20% Scapegoat W ilderness 0.05 0.04 0.19 0.01 0.08 0.37 0.00 10 B20%

## EMAQ LOE (EPA Contract EP-D- 07- 102) WA 5 - 12 : Task 5 Modeling Protocol for AZ BART Analyses

UNC -EMAQ (5 - 12) - 008.v3 Selway- Bitterroot Wi lderness 0.04 0.03 0.12 0.01 0.07 0.31 0.00 10 B20% Seney W ilderness 0.08 0.01 0.38 0.01 0.09 0.80 0.01 12 B20% Sequoia NP 0.03 0.03 0.18 0.01 0.08 0.73 0.02 11 B20% Shenandoah NP 0.08 0.07 0.56 0.01 0.14 1.20 0.01 10 B20% Shining Rock W ilderness 0.05 0.05 0.51 0.01 0.13 0.56 0.01 10 B20% Sierra Ancha W ilderness 0.06 0.05 0.33 0.02 0.14 0.73 0.01 10 B20% Simeonof W ilderness 0.06 0.05 0.25 0.02 0.04 1.18 0.25 12 B20% Sipsey W ilderness 0.11 0.10 0.81 0.01 0.25 1.66 0.01 11 B20% South Wa rner Wi lderness 0.03 0.03 0.14 0.01 0.06 0.46 0.00 10 B20% Strawberry Mountain Wi lderness 0.05 0.02 0.17 0.01 0.10 0.50 0.01 10 B20% Superstition W ilderness 0.07 0.05 0.31 0.01 0.16 0.84 0.00 10 B20% Swanquarter W ilderness 0.12 0.06 0.65 0.01 0.23 2.38 0.05 12 B20% Sycamore Canyon W ilderness 0.06 0.05 0.28 0.01 0.12 0.62 0.00 9 B20% Teton Wi lderness 0.06 0.05 0.17 0.01 0.08 0.33 0.00 9 B20% Theodore Roosevelt NP 0.07 0.04 0.26 0.01 0.21 1.20 0.01 11 B20% Thousand Lakes W ilderness 0.03 0.02 0.12 0.01 0.08 0.24 0.01 10 B20% Three Sisters W ilderness 0.02 0.02 0.08 0.00 0.03 0.31 0.01 11 B20% Tu xedni W ilderness 0.03 0.04 0.09 0.01 0.03 0.52 0.05 12 B20% UL Bend W ilderness 0.05 0.03 0.18 0.01 0.15 0.93 0.01 11 B20% Upper Buffalo W ilderness 0.08 0.06 0.68 0.01 0.16 1.33 0.01 11 B20% Ventana W ilderness 0.06 0.04 0.31 0.01 0.16 1.50 0.06 11 B20% Virgin Islands NP 0.18 0.07 0.21 0.01 0.12 1.53 0.26 11 B20% Voyageurs NP 0.12 0.02 0.56 0.01 0.10 0.86 0.01 12 B20% Wa shakie W ilderness 0.05 0.04 0.16 0.00 0.11 0.82 0.00 9 B20% We minuche W ilderness 0.06 0.04 0.24 0.01 0.13 0.88 0.00 9 B20% We st Elk W ilderness 0.04 0.03 0.14 0.01 0.08 0.36 0.00 8 B20% Wh eeler Peak W ilderness 0.04 0.03 0.16 0.01 0.08 0.67 0.00 8 B20% Wh ite Mountain W ilderness 0.05 0.03 0.24 0.01 0.08 0.67 0.01 9 B20% Wi chita Mountains Wi lderness 0.03 0.04 0.28 0.01 0.15 1.52 0.01 11 B20% Wi nd Cave NP 0.05 0.04 0.20 0.01 0.19 1.05 0.00 10 B20% Wo lf Island W ilderness 0.13 0.07 0.92 0.01 0.22 1.69 0.03 11 B20% Yellowstone NP 0.06 0.05 0.17 0.01 0.08 0.33 0.00 9 B20% Yolla Bolly- Middle Eel Wi lderness 0.03 0.02 0.12 0.01 0.06 0.36 0.01 10 B20% Yosemite NP 0.03 0.02 0.10 0.00 0.08 0.50 0.01 10 B20% Zion NP 0.05 0.06 0.28 0.01 0.10 0.60 0.01 10 B20% a 

### Taken from FLM (20 10 )