# II-D-121

Matt, Attached please find the responses to the questions on the ICR. Thanks, Warren 

### Responses to Sanford Plant ICR Questions IL,

~ 

## 6~ 98

1) The Sanford facility is permitted to use contaminated soil, however, no contaminated soil was utilized in 1996. There is no percentage or total amount of contaminated soil identified within the current air quality permit. The permit specifies facility wide emission limitations. Please keep in mind as noted in the cover letter Cherokee Sanford intends to phase out the use of contaminated soiLs in our process over the next few years and does not expect to use contaminated soil.s by the time this NESHAP is in effect. 2) The typical operating range for the sawdust dryers at the Sanford facility would be approximately the same as the other plants. The temperature identified in the ICR was 150 °F and 160 °F for EP-M3-1 and EP-A2-1 & 2 respectively. 3) The stack test was conducted at the Moncure facility which is substantially identical to the Sanford, Lee County & Beltsville facilities. I will mail you a copy of the test report.. _ _ .^
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# CHEROKEE BRICK Bricklayer, North Carolina

January 12, 1995

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~ FLUORIDE TESTING RBSULTS CHEROKEE BRICK Bricklayer, North Carolina

Prepared for: t11an McConnell Hunton and Williams One Hanover Square Favetteville Street Mall Raleigh, North Carolina 27602

Prepared by: Hartman Kelly International, Ltd.

Suite 300B 1910 Sedwick Road Durham, North Carolina 27713

January 12, 1995 

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### January 12,1995


## TABI.E OF CONTENTS 

## Eap 1.0 INTRODUCTION . . . . : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 

## 2.0 RESULTS ....................................................1 3.0 SUMMARY OF METHODS AND SAMPLING LOCATIONS . . . . . . . . . . . 2

FIGURE

1. EPA Method 26A Sampling Train . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4



## TABLE 1. Summary of Fluoride Emissions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 APPENDICES APPENDIX A Field Data Sheets APPENDIX B Summary Calculation Sheets APPENDIX C Laboratory Results

ii e-21

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I Hartman, Kelly International, Ltd. 

### January 12,1995


### 1 1.0 INTRODUCTION


# ~ Hartman, Kelly Intemational, Ltd., (HKi) performed stack testing on December 1,

1994 for fluoride at Cherokee Brick's Bricklayer, North Carolina facility. This report 

# ~ presents the results of that testing and the associated background material used.

The fluoride tests were conducted using U.S. Environmental Protection Agency 

# ~ (EPA) Method 26A on the East Stack of the cyclone exhaust on the brick kiln. This

method encompasses EPA Methods 1 through 4 for flows and moisture. The impinger solutions were recovered and analyzed at Triangle Laboratories by ion 

# ~ chromatography.


# ~ The kiln was operated at maximum throughput during the entire testing period. The

average total fluoride emissions were 1.96 pounds per hour (lb/hr). This total was calculated by measuring the concentration in the East Stack of the cyclone exhaust 

# ~ and applying that concentration to the measured flow rate in both the East and West

Stacks.


# ~ Section 2 of this report contains the discussion of results and a summary of results.

Section 3 is a description of the sampling and analytical methods. The Field data and 

# ~ laboratory data are contained in the appendices. 

# I I I I I I I 0 ` J
~Hartman, Kelly International, Ltd. 

### January 12,1995


### 2.0 RESULTS


# ~ Fluoride emission testing conducted on December 1, 1994, is summarized in Table 1.

The emission rate averaged 1.961b/hr with a range of 1.78 to 2.061b/hr. Each nin 

# ~ total was obtained from summing the results of both the East and West Stacks. The

East Stack was measured simultaneously for flow and concentration. The West Stack was measured for flow before or after each test run at the East Stack. The analvtical 

# ~ results for the East Stack were applied to the West Stack flow rate to achieve the

mass emission rate for the West Stack.


# ~ The samples were withdrawn isokinetically over a 1-hour period. The isokinetics

ranged from 98 to 103% during the test period. There were three 1-hour tests 

# ~ conducted on the East Stack, interspersed with three flow rate measurements on the

West Stack. As can be seen from Table 1, the flow rates on the West Stack are higher than the East Stack by approximately 25%. The reason for the difference is 

# ~ not known since the fans are the same size. There was a loss of power in the kiln

between Runs 1 and 2. Testing was not performed during the outage, but was 

# ~ resumed when power was restored.

Table 1. Summary of Fluoride Emissions
Run 1 East' Run 1

West b Run 2

East Run 2

West Run 3

East Run 3

West Stack Velocity, fpm 3240 4325 3465 4280 3434 4303 Volumetric Flow Rate, dscfm 11780 14814 11776 14505 11853 14834 Fluoride Concentration, ppm 26.2 26.2 26.5 26.5 22.6 22.6 Fluoride Emissions, Ib/hr 0.91 1.14 0.92 1.14 0.79 0.99

Total, lb/hr 2.05 2.06 1.78 Average, lb/hr 1.96 'This stack was sampled with the fluoride sampling train. 

# ~ "This stack was measured for flow and the concentration of the East Stack was applied to the flow rate

to yield the emission number.


# ~ There were no known problems encountered during this test series. The sampling

conformed to EPA specifications and the analyses were within the analytical range specified in the method. 

# ~ 

# I I I I 1-

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# I

N Hartman, Kelly International, Ltd. January 12,1995



# ~ 3.0 SUMMARY OF METHODS AND SAMPLING LOCATIONS


# ~ The fluoride emissions were determined according to EPA Method 26A at the outlet

for the wood dust dryer cyclone. Both stacks were sampled after the fans and prior to 

# ~ exhaust into the air. Both stacks had the same diameter (29" ID) and both sampling

locations were approximately 9 feet above the fan exhaust and approximately 40 feet tothe air discharge. Twent.y-four sampling points were used in order to maximize 

# ~ accuracy of the flow readings.



# ~ The sample was withdrawn isokinetically through a calibrated nozzle into the

impingers for collection and was then determined volumetrically with a calibrated dry gas meter. Figure 1 presents a schematic drawing of the sampling train. After one 

# ~ hour of sampling, the sample was recovered in the field using procedures in

Method 26A. The collected sample was transported to Triangle Laboratories in Research Triangle Park, North Carolina for analysis by ion chromatography.


# ~ r rmed b calibratin the chromato a h with standards and

The analysis was pe fo y g gr p 

# ~ blanks prior to and after the sample injections. The results are contained in

Appendix C. All of the samples fell in the range of calibrations. As a quality control check, blanks were run as well as duplicate injections of the samples.


# ~ Flows were determined by a Type S pitot tube which was measured in accordance

with EPA Method 2. The molecular weight was determined by obtaining oxygen, 

# ~ carbon dioxide, and nitrogen by balance with an ORSAT-type apparatus. Moisture

was determined gravimetrically by measuring the moisture trapped in the dryers and 

# ~ silica gel during the testing. 

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# ~ FIELD DATA SHEETS 

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# ~ SUMMARY CALCULATION SHEETS 

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### Facility: CHEROKEE 

# ~ Date: 12/01 /94 Location: EAST STACK Run Number: 1 Sample Type: FLTotal Sampling Time (min) 60.0 Corrected Barometric Pressure (in Hg) 30.09 Absolute Stack Pressure (in H20) 30.07 Stack Static Pressure (in H20) -0.30 Average Stack Temperature (°F) 180.38 Stack Area (sq in) 660.52 Actual Meter Votume (cu ft) 29.507 Average Meter Pressure (in H20) 0.92 Average Meter Temperature (°F) 68.65 Moisture Collected (g) 70.00 Carbon Dioxide Concentration (%V) 3.5 Oxygen Concentration (%V) 16.5 Nitrogen Concentration (%V) 80.0 Dry Gas Meter Factor 1.0050 Nozzle Diameter (in) 0.190 Pitot Constant 0.84 Average Sampling Rate (dscfm) 0.497 Standard Metered Volume (dscf) 29.841 Standard Metered Volume (dscm) 0.845 Stack Moisture (%V) 9.96 Mole Fraction Dry Stack Gas 0.900 Dry Molecular Weight 29.22 Wet Molecular Weight 28.10 Stack Gas Velocity (fpm) 3442.37 Stack Gas Velocity (mpm) 1049.23 Volumetric Flow Rate (acfm) 15789.96 Volumetric Flow Rate (acmm) 447.17 Volumetric Flow Rate (dscfm) 11780.07 Volumetric Flow Rate (dscmm) 333.61 Percent Isokinetic 98.36 Percent Excess Air 355.91 Floride Concentration (g/dscm) 0.02 Floride Emissions (kg/hr) 0.41 Floride Concentration (ppmv) 26.20 Floride Emissions (Ib/hr) 0.91 

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### Facility: CHEROKEE 

# ~ Date: 12/01 /94 Location: EAST STACK Run Number: 2

, Sample Type: FL-

_ Total Sampling Time (min) 72.0 

# ~ Corrected Barometric Pressure (in Hg) 30.09 Absolute Stack Pressure (in H20) 30.07 Stack Static Pressure (in H20) -0.27 

# ~ Average Stack Temperature (°F) 180.21 Stack Area (sq in) 660.52 

# M Actual Meter Volume (cu ft) 37.427 Average Meter Pressure (in H20) 0.92 Average Meter Temperature (°F) 69.94 Moisture Collected (g) 95.00 

# ~ Carbon Dioxide Concentration (%V) 3.0 Oxygen Concentration (%V) 16.5 

# ~ Nitrogen Concentration (%V) 80.5 Dry Gas Meter Factor 1.0050 Nozzle Diameter (in) 0.190 

# ~ Pitot Constant 0.84 Average Sampling Rate (dscfm) 0.525 Standard Metered Volume (dscfl 37.768 

# ~ Standard Metered Volume (dscm) 1.070 Stack Moisture (%V) 10.60 Mole Fraction Dry Stack Gas 0.894 

# ~ Dry Molecular Weight 29.14 Wet Molecular Weight 27.96 Stack Gas Velocity (fpm) 3464.85 

# ~ Stack Gas Velocity (mpm) 1056.09 Volumetric Flow Rate (acfm) 15893.06 Volumetric Flow Rate (acmm) 450.09 

# ~ Volumetric Flow Rate (dscfm) 11776.16 Volumetric Flow Rate (dscmm) 333.50 Percent Isokinetic 103.77 

# ~ Percent Excess Air 346.05 Floride Concentration (g/dscm) 0.02 Floride Emissions (kg/hr) 0.42 

# ~ Floride Concentration (ppmv) 26.50 Floride Emissions (Ib/hr) 0.92



# 0

### Facility:

Date: Location: Run Number: Sample Type: 

## CHEROKEE

12/01 /94 EAST STACK 3

### FLTotai Sampting Time (min) 72,0 Corrected Barometric Pressure (in Hg) 30.09 Absolute Stack Pressure (in H20) 30.06
- Stack Static Pressure (in H20)

. -0.45 Average Stack Temperature (°F) 180.79 Stack Area (sq in) 660.52 Actual Meter Volume (cu ft) 37.228 Average Meter Pressure (in H20) 0.92 Average Meter Temperature (°F) 68.21 Moisture Collected (g) 80.00 Carbon Dioxide Concentration (%V) 3.0 i Oxygen Concentration (%V) 16.5 

# ~ Nitrogen Concentration (%V) 80.5 Dry Gas Meter Factor 1.0050 Nozzle Diameter (in) 0.190 

# ~ Pitot Constant 0.84 Average Sampling Rate (dscfm) 0.524 Standard Metered Volume (dscfl 37.709 

# ~ Standard Metered Volume (dscm) 1.068 Stack Moisture (%V) 9.09 Mole Fraction Dry Stack Gas 0.909 

# ~ Dry Molecular Weight 29.14 Wet Molecular Weight 28.13 Stack Gas Velocity (fpm) 3434.49 

# ~ Stack Gas Velocity (mpm) 1046.83 Volumetric Flow Rate (acfm) 15753.83 Volumetric Flow Rate (acmm) 446.15 

# ~ Volumetric Flow Rate (dscfm) 11853.98 Volumetric Flow Rate (dscmm) 335.70 

# ~ Percent Isokinetic Percent Excess Air 102.93 346.05 Floride Concentration (g/dscm) 0.02 

# ~ Floride Emissions (kg/hr) 0.36 Floride Concentration (ppmv) 22.60 Floride Emissions (Ib/hr) 0.79 

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### Facility: CHEROKEE Date: 12/01 /94 Location: WEST STACK Run Number: 1 Sample Type: FLTotal Sampling Time (min) 

# ~ Corrected Barometric Pressure (in Hg) 30.09 Absolute Stack Pressure (in H20) 30.07 Stack Static Pressure (in H20) -0-30 

# ~ Average Stack Temperature (°F) 179.79 Stack Area (sq in) 660.52 Actual Meter Volume (cu ft) 29.507 

# ~ Average Meter Pressure (in H20) 1.15 Average Meter Temperature (°F) 68.65 

# ~ Moisture Collected (g) 70.00 Carbon Dioxide Concentration (%V) 3.5 Oxygen Concentration (%V) 16.5 

# ~ Nitrogen Concentration (%V) 80.0 Dry Gas Meter Factor 1.0050 Nozzle Diameter (in) 

# ~ Pitot Constant 0.84 Average Sampling Rate (dscfm) 0.497 Standard Metered Volume (dscf) 29.841


# ~ Standard Metered Volume (dscm) 0.845

. Stack Moisture (%V) 9.96 Mole Fraction Dry Stack Gas 0.900 

# ~ Dry Molecular Weight 29.22 Wet Molecular Weight 28.10 Stack Gas Velocity (fpm) 4325.03 

# ~ Stack Gas Velocity (mpm) 1318.27 Volumetric Flow Rate (acfm) 19838.66 Volumetric Flow Rate (acmm) 561.83 

# ~ Volumetric Flow Rate (dscfm) 14814.09 Volumetric Flow Rate (dscmm) 419.54 Percent Isokinetic 

# ~ Percent Excess Air 355.91 Floride Concentration (g/dscm) 0.02 Floride Emissions (kg/hr) 0.52 

# ~ Floride Concentration (ppmv) 26.20


# ~ Floride Emissions (Ib/hr)
-------------- ------------ -------- --------- --------- -------------- ---- --------- --------- 1.14
--------- ----------

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### Facility: Date: Location: Run Number: Sample Type: 

## CHEROKEE

12/01 /94 WEST STACK 2FLTotal Sampling Time (min) 

# ~ Corrected Barometric Pressure (in Hg) 30.09 Absolute Stack Pressure (in H20) 30.07 Stack Static Pressure (in H20)

_ -0.27 

# ~ Average Stack Temperature (°F) 182.13 Stack Area (sq in) 660.52 Actual Meter Volume (cu ft) 37.427 

# ~ Average Meter Pressure (in H20) 1.14 Average Meter Temperature (°F) 69.94 Moisture Collected (g) 95.00 

# ~ Carbon Dioxide Concentration (%V) 3.0 Oxygen Concentration (%V) 16.5 Nitrogen Concentration (%V) 80.5 

# ~ Dry Gas Meter Factor 1.0050 Nozzle Diameter (in) 

# ~ Pitot Constant 0.84 Average Sampling Rate (dscfm) 0.525 Standard Metered Volume (dscfl 37.768 

# ~ Standard Metered Volume (dscm) 1.070 Stack Moisture (%V) 10.60 Mole Fraction Dry Stack Gas 0.894 ' Dry Molecular Weight 29.14 Wet Molecular Weight 27.96 Stack Gas Velocity (fpm) 

# ~ Stack Gas Velocity (mpm) 4280.54 1304.71 Volumetric Flow Rate (acfm) 19634.60 Volumetric Flow Rate (acmm) 556.05 

# ~ Volumetric Flow Rate (dscfm) 14505.06 Volumetric Flow Rate (dscmm) 410.78 Percent Isokinetic 

# ~ Percent Excess Air 346.05 Floride Concentration (g/dscm) 0.02 Floride Emissions (kg/hr) 0.52 ' Floride Concentration (ppmv) 26.50 Floride Emissions (Ib/hr) 1.14



# 1

### Facility: CHEROKEE Date: 12/01 /94 Location: WEST STACK Run Number: 3 Sample Type: FLTotal Sampling Time (min) Corrected Barometric Pressure (in Hg) 30.09 Absolute Stack Pressure (in H20) 30.06 Stack Static Pressure (in H20)

. -0.45 Average Stack Temperature (°F) 181.54 Stack Area (sq in) 660.52 Actual Meter Volume (cu ft) 37.228 Average Meter Pressure (in H20) 1.15 Average Meter Temperature (°F) 68.21 Moisture Collected (g) - 80.00 Carbon Dioxide Concentration (%V) 3.0 Oxygen Concentration (%V) 16.5 Nitro,gen Concentration (%V) 80.5 Dry Gas Meter Factor 1.0050 Nozzle Diameter (in) Pitot Constant 0.84 Average Sampling Rate (dscfm) 0.524 Standard Metered Volume (dscfl 37.709 Standard Metered Volume (dscm) 1.068 Stack Moisture (%V) 9.09 Mole Fraction Dry Stack Gas 0.909 Dry Molecular Weight 29.14 Wet Molecular Weight 28.13 Stack Gas Velocity (fpm) 4303.03 Stack Gas Velocity (mpm) 1311.56 Volumetric Flow Rate (acfm) 19737.74 Volumetric Flow Rate (acmm) 558.97 Volumetric Flow Rate (dscfm) 14834.31 Volumetric Flow Rate (dscmm) 420.11 Percent Isokinetic Percent Excess Air 346.05 Floride Concentration (g/dscm) 0.02 Floride Emissions (kg/hr) 0.45 Floride Concentration (ppmv) 22.60 Floride Emissions (Ib/hr) 0.99

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# A LABORATORY RESULTS 

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# i 0 Data Reprocessed On 12/06/1994 09:00:42 Sample Name: 1 Date: 12/05/1994 20:11 44 Data File : C:\DX\DATA\30704F\92148011.D17 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 17 Detector:PED-Cond. Analyst : Column: Calibration Volume Dilution Points Rate Start Stop Area Reject
-------------------------------------------------------------------- External 1 1 3600 5Hz 0.00 6.93 1000 ********************** Component Report: A11 Components Pk. Ret Component Concentration Height Area Bl. %Delta Num Time Name Code
----------------------------------------------------------------------------- 1 1.47 FLUORIDE 0.000 31471721 417396257 1 0.00 0 0.00 CHLORIDE 0.000 0 0 0 0.00 0 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 0 0.00 SULFATE 0.000 0 0 0 0.00
------------------------------------ Totals 0.000 31471721 417396257 File: 92148011.D17 Samp/e: 1

0 1 2 3 4 5 6 Minutes



# PW I --1 11:z-

# 1 40 

# 1 30 

# I us 20 

# 1 10 

# i 0 

### Data Repr.ocessed On 12/06/1994 09:03:10 Sample Name: 1 N r Date: 12/05/1994 20:25:29 w Data File : C:\DX\DATA\30704F\92148011.D18 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 18 Detector:PED-Cond. Analyst
. Column: Calibration Volume Dilution Points Rate Start Stop Area Reject
-------------------------------------------------------------------- External 1 1 3600 5Hz 0.00 6.57 1000 ********************** Component Report: A11 Components Pk. Ret Component Concentration Height Area B1. %Delta Num Time Name Code
----------------------------------------------------------------------------- 1 1.47 FLUORIDE 0.000 33898814 429597167 1 0.00 0 0.00 CHLORIDE 0.000 0 0 0 0.00 0 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 0 0.00 SULFATE 0.000 0 0 0 0.00
------------------------------------ Totals 0.000 33898814 429597167 File: 92148011.D18 Samp/e: 1



# 23 Minutes



# 1 -0r_0 1 2 3 4 5 6 Minutes 

# 1 w 

# I 30 

# I uS 20 

# 1 10 

# 1 ° I I Data Reprocessed On 12/06/1994 09:04:26 

# ~ Sample Name: 2 Date: 12/05/1994 20:39:15 Data File : C:\DX\DATA\30704F\92148021.D19 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 19 Detector:PED-Cond. 

### ~ 

### Analyst =-----

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### ~ 

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### -=



# ~ Calibration Volume Dilution Points Rate Start Stop Area Reject

-------------------------------------------------------------------- 

### External 1 1 3600 5Hz 0.00 6.80 1000 ********************** Component Report: A11 Components ********************** Pk. Ret Component Concentration Height Area B1. %Delta



# ~ Num Time Name Code

1 1.47 FLUORIDE , ----------------------------------------------------------------------------- 0.000 30963917 393850585 1 0.00 0 0.00 CHLORIDE 0.000 0 0 0 0.00 0 

# ~ 0.00 BROMIDE 0.000 0 0 0 0.00

0 0.00 NITRATE 0.000 0 0 0 0.00 0 0.00 SULFATE 0.000


### -------------- ----------- 0 0 

### ----------- 0 0:00 

# ~ Totals 0.000 30963917 393850585


### I File: 92948021.D19 Samp/e: 2



## 24

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# 1 10 

# 1 ° I Minutes 

### Data Reprocessed On 12/06/1994 09:06:27 

# ~ Sample Name: 2 Date: 12/05/1994 20:53:01 Data File : C:\DX\DATA\30704F\92148021.D20 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 20 Detector:PED-Cond. 

# ~ =- Analyst ==------ 

# - -- --- ---c olwnn

____________ 

# ___ __



# ~ Calibration Volume Dilution Points Rate

- Start

--- Stop Area Reject

------------------------------------------- ------------- External 1 1 3600 5Hz 0.00 6.39 1000



# Component Report: A11 Components ********************** Pk. Ret Component Concentration Height Area B1. %Delta



# ~ Num Time Name

----------------------------------------------------------------------------- 

# Code
1 1.47 FLUORIDE 0.000 31256746 405088472 1 0.00 

# ~ 0

0 0.00 0.00 CHLORIDE BROMIDE 0.000 0.000 0 0 0

0 0 0 0.00 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 0 0.00 SULFATE 0.000 0 0 0 0.00 

# ~ -------------- ----------- Totals 0.000 ----------- 31256746 405088472



# ~ File: 92148021.D20 Samp/e: 2



# I I 25 -, a0 1 - 2 3 4 5 6 

# I uS 20

40

~

' 10 

# i ° Data.Reprocessed On 12/06/1994 09:07:48 Sample Name: 3 Date: 12/05/1994 21:06:46 Data File : C:\DX\DATA\30704F\92148031.D21 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 21 Detector:PED-Cond. 

## Analyst
. Column: 

# I Calibration Volume Dilution Points Rate Start Stop Area Reject External 1 1 3600 5Hz 0.00 6.57 1000 

## ( ********************** Component Report: A11 Components *********************** Pk. Ret Component Concentration Height Area B1. $Delta 

# I Num Time Name

- 

## Code 1 1.47 FLUORIDE ----------------------------------------------------------------- 

### 0.000 28381722 370167550 1 --------- 

### 0.00 0 0.00 CHLORIDE 0.000 0 0 0 0.00 0 0.00 

# ~ BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 0 0.00 SULFATE 0.000
-------------- 

### 0

----------- 

### 0 0 0:00 

# ~ Totals 0.000 28381722 ----------- 370167550


### I File: 92148031.D21 

## Sample: 3

Minutes

1 26 e1% r-n

# 1 w 

# 1 30 

# I uS 20


# ~ 10



# ~ 0 

# ~ Data Reprocessed On 12/06/1994 09:11:41 Sample Name: 3 Date: 12/05/1994 21:20:31 

# ~ Data File : C:\DX\DATA\30704F\92148031.D22 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 22 Detector:PED-Cond. 

# ~ Analyst : Column:



# ' Calibration

--------------------------------------------------------------------



### Volume Dilution Points Rate Start Stop Area Reject External 1 1 3600 5Hz 0.00 6.80 1000 

### Component Report: A11 Components Pk. Ret Component Concentration Height Area B1. %Delta



# ~ Num Time Name
----------------------------------------------------------------------------- 

### Code 1 1.47 FLUORIDE 0.000 28228969 367316049 1 0.00 0 0.00 CHLORIDE 0.000 0 0 0 0.00 

# ~ 0 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 0 0.00 SULFATE 0.000 0 0 0 0.00 

# ~ --------- --- -- ---------------------- Totals 0.000 28228969 367316049


### I File: 92948031.D22 Sample: 3



# ~

~ 0 1 2 3 4 5 6 Minutes


# I I
0 

# 27

# ~ ~ 

# _r w 0 

# ~ v 

## A T r C ~ O ~ 

# v m

~

~ 

# i 1 i I

~ -~ ,180

160 140 120 100
us 

### 80 60 40 20 0 -20 0 2 4 6 8 

### 10 12



### Data Reprocessed On 12/06/1994 10:40:11 Sample Name: STD 100.0 PPM Date: 12/05/1994 19:02:52 Data File : C:\DX\DATA\30704F\STD10001.D12 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 12 Detector:PED-Cond. Analyst
. Column: 3libration Volume Dilution Points Rate Start Stop Area Reject
------------------------------------------------------------------- xternal 1 1 3600 5Hz 0.00 12.00 1000 ********************* Component Report: A11 Components *********************** Pk. 

### Ret Component Concentration Height Area B1. %Delta Num Time Name
---------------------------------------------------------------------------- Code 1 1.43 FLUORIDE 0.000 102554617 973235053 1 0.00 2 2.33 CHLORIDE 0.000 119602937 978557491 1-0.71 0 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 3.10.30 SULFATE 0.000 22479602
------------------------------------ 559206713 

### 1-0.29 Totals 0.000 244637156 2510999257 

## File: STD10001.D12 Sample: STD 100.0 PPM

Minutes90

80 70 60 50 uS 40 30 20 10 0 0 2 4 6 8 10 12



### Data Reprocessed On 12/06/1994 10:25:39 Sample Name: STD 30.0 PPM Date: 12/05/1994 18:35 18 ' 

### Data File : C:\DX\DATA\30704F\STD03001.D10 Method : C:\DX\METHOD\7ANION.met 

### ACI Address: 1 System: 1 Inject$: 10 Detector:PED-Cond. Analyst
. Column:
Calibration Volume Dilution Points Rate Start Stop Area Reject External -------------------------------------------------------------------- 1 1 3600 5Hz 0.00 12.00 1000 ********************** Component Report: A11 Components *********************** Pk. Ret Component Concentration Height Area B1. %Delta Num Time Name
----------------------------------------------------------------------------- Code 1 1.42 FLUORIDE 0.000 36622684 266239467 1 0.00 2 2.27 CHLORIDE 0.000 43297647 266513565 1-3.55 0 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 3 10.47 SULFATE 0.000
------------------------------------ 6277965 154854816 1 1:32 Totals 0.000 86198295 687607848 

### File: STD03001.D1 0 

## Sample: STD 30.0 PPM

Minutes



# 8

### Data Reprocessed On 12/06/1994 10:07:31 Sample Name: STD 10.0 PPM Date: 12/05/1994 18:07:45 Data File : C:\DX\DATA\30704F\STDOl001.D08 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 8 Detector:PED-Cond. Analyst
. Column: Calibration Volume Dilution Points Rate Start Stop Area Reject
-------------------------------------------------------------------- External 1 1 3600 5Hz 0.00 12.00 1000 ********************** Component Report: A11 Components *********************** Pk. Ret Component Concentration Height Area B1. %Delta Num Time Name Code 1 1.40 FLUORIDE ----------------------------------------------------------------------------- 0.000 9668466 79630351 1 0.00 2 2.25 CHLORIDE 0.000 13756779 75218587 1-4.26 0 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 3 10.53 SULFATE 0.000 2134718 52907034 1 1:97 Totals 0.000 ------------------------------------

25559962 207755973 

### File: STD01001.D08 Sample: STD 10.0 PPM

CHLORIDE / 2.25

2 4 6 8 10 12 Minutes uS 18 16 14 12 10' 8 6 4 2 0 .2 0

### Data Reprocessed On 12/06/1994 09:55:06 Sample Name: STD 3.0 PPM Date: 12/05/1994 17:40:13 Data File : C:\DX\DATA\30704F\STD00301.D06 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 6 Detector:PED-Cond. 

### Analyst : Column:
Calibration 

# ~ Volume


# ______________________________ Dilution

- Points

- Rate

-- Start

--- Stop Area



# ______________

Reject External 1 1 3600 5Hz 0.00 12.00 1000 

# I ********************** Component Report: A11 Components *********************** Pk. Ret Component Concentration Height Area B1. %Delta



# ~ Num Time Name
----------------------------------------------------------------------------- 

### Code 1 1.40 FLUORIDE 0.000 2188236 20472716 1 0.00 2 2.25 CHLORIDE 0.000 3668883 20965534 1-4.26 ' 0 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 3 10.58 SULFATE 0.000 920008 24519245 1 2:45 Totals 0.000 6777127 65957494 

### File: STD00301.D06 

## Samp/e: STD 3.0 PPM



# I I 9.0

8.0 7.0 

### 6.0 5.0 CHLORIDE / 2.25 uS 4.0 1 3.0 FLUORIDE / 1. 0 2.0 I ~ 1.0 0.0 -1.0 0 2 4 6 Minutes SULFATE / 10.58

~ 

# ~

8 10 12

# ■ 10 :?<

### Data Reprocessed On 12/06/1994 09:14:13



# __---____-----_=---____________________ ~ Sample Name: STD 1.0 PPM Date: 12/05/1994 17:12:42 Data File : C:\DX\DATA\30704F\STDO0101.D04 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 4 Detector:PED-Cond. 

# ~ 

# -- Analyst ==--------_

— 

# --

- 

# == Column _________________---____________=____—_

~ Calibration Volume D1lution Points Rate Start Stop Area Reject

-------------------------------------------------------------------- 

### External 1 1 3600 5Hz 0.00 12.00 1000 

# I ********************** Component Report: A11 Components Pk. Ret Component Concentration Height Area B1. %Delta 

# ~ Num Time
---- ------- 

### Name

----- ------------------------------------------------------------- 

### Code 1 1.42 FLUORIDE 0.000 597491 4826444 1 0.00 2 2.25 CHLORIDE 0.000 1213151 6773985 1-4.26 

# ~ 0 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00

_ 3 10.58 SULFATE 0.000 656186 17791547 1 2:45 Totals 0.000 2466828 29391975 

### I File: STD00101.D04 Sample: STD 1.0 PPM 

# a
3.0 ' 2.0 

# ~ uS 1.0


# ~ 0.0


# ~ -1.0 CHLORIDE / 2.25 1 FLUORIDE / 1 1 SULFATE / 10.58 1



### 0 2 4 6 8 10 12 Minutes



# 11 ?/ -

### File: STD1000l.D42 

## Sample: STD 100.0 PPM

180 160 140 CHLORIDE / 2.33 120 100 80 60 40 20 0 -20 0 2 4 6 8 10 12 Minutes 

### Data Reprocessed On 12/06/1994 10:43:36 

# I Sampie Name: STD 100.0 PPM Date: 12/06/1994 01:55:52 Data File : C:\DX\DATA\30704F\STD10001.D42 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 42 Detector:PED-Cond. 

# I w Analyst_

~ 

# _ Column:_ =

~ 

### Calibration Volume Dilution Points Rate Start Stop Area Reject External 1 1 - 3600 5Hz 0.00 12.00 1000 

### Component Report: A11 Components Pk. Ret Component Concentration Height Area B1. %Delta 

# I Num Time Name Code 1 1.43 FLUORIDE ----------------------------------------------------------------------------- 

### 0.000 106306214 985906646 1 0.00 2 2.33 CHLORIDE 0.000 121908984 1001519667 1-0.71 0 

# ~ 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 3 10.27 SULFATE 0.000
-------------- ----------- 22668878 567476070 1-0.61

----------- ' Totals 0.000 250884076 2554902384


# I 

# I I us I 

# I I I

19 2 -T

# ~ Minutes 

### Data_Reprocessed On 12/06/1994 10:36:37 

# ~ Sample Name: STD 30.0 PPM Date: 12/06/1994 01:28:17 Data File : C:\DX\DATA\30704F\STD03001.D40 Method : C.\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 40 Detector•PED-Cond. 

## ~ _Analyst 

## ~ Y :



# _ Column:
Calibration 

## ~ Volume Dilution Points Rate Start Sto P Area Reject External 1 1 3600 5Hz 0.00 12.00 1000 

## ********************** Component Report: All Components *********************** Pk. Ret Component Concentration Height Area B1. $Delta



# ~ Num Time Name Code 1 1.42 FLUORIDE ----------------------------------------------------------------------------- 0.000 38259577 272864010 1 0.00 2 2.27 CHLORIDE 0.000 44091172 271195040 1-3.55 

# ~ 0 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 3 10.43 SULFATE 0.000 6191573 148379265 1 1:00 

# ~ ------------------------------------ Totals 0.000 88542322 692438315


### I File: STD03001.D40 Sample: STD 30.0 PPM



# ~ 90

80 

# ~ 70

60 

# ~ 50

uS 40 

# ~ 30

20 

# ~ 10



# 0

1 13 ?d

# ~

~

~

~

~

~

~

~ us File: STD01009.D38 Samp/e: STD 10.0 PPM

18 16 14 12 10 8 6 4 2 0 -2 0 2 4 6 8 10 12 Minutes 

### Data'Reprocessed On 12/06/1994 10:21:29 

# ~ Sample Name: STD 10.0 PPM Date: 12/06/1994 01:00:44 Data File : C:\DX\DATA\30704F\STDO1001.D38 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 38 Detector:PED-Cond. 

# I Analyst

---- 

# =___ -- Column _=-- ~~ 

# f Calibration Volume Dilution Points Rate Start Stop Area Reject External 1 1 -------------------------------------------------------------------- 3600 5Hz 0.00 12.00 1000 

# Component Report: A11 Components Pk.

~ 

# Num Ret

Time

---- ------- 

# Component

Name

----- ------------------------------------------------------



# Concentration Height Area H1. Code %Delta

------- 1 1.40 FLUORIDE 0.000 10117145 80090068 1 0.00 2 2.25 CHLORIDE 0.000 13814148 76490029 1-4.26 ' 0 0.00 BROMIDE 0.000 0 0 0 0.00

0 0.00 NITRATE 0.000 0 0 0 0.00

_ 3 10.52 SULFATE 0.000 2030733 51277234 1 1:81 

### Totals 0.000 25962026 207857331

m

### Data Reprocessed On 12/06/1994 10:56:15 Sample Name: STD 3.0 PPM Date: 12/06/1994 00:33:13

~ 

### Data File : C:\DX\DATA\30704F\STD00301.D36 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 36 Detector:PED-Cond. 

### Analyst : Column: Calibration Volume Dilution Points Rate Start Stop Area Reject

-------------------------------------------------------------------- 

### External 1 1 3600 5Hz 0.00. 12.00 1000 ********************** Component Report: A11 Components ********************** Pk. Ret Component Concentration Height Area B1. %Delta Num Time Name
----------------------------------------------------------------------------- 

### Code 1 1.40 FLUORIDE 0.000 2380345 21472171 1 0.00 2 2.23 CHLORIDE 0.000 3411424 20962105 1-4.96 0 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 3 10.55 SULFATE 0.000 730323

------------------------------------ 

### 19228545 1 2:13 Totals 0.000 6522093 61662821 

### File: STD00301.D36 Samp/e: STD 3.0 PPM

4.0 3.0 2.0 uS 1.0 0.0 -1.0 -2.0 0 2 4 6 8 10 12 Minutes

1 S J 1 ._

### Data Reprocessed On 12/06/1994 09:51:43 Sample Name: STD 1.0 PPM Date: 12/06/1994 00:05:43 Data File : C:\DX\DATA\30704F\STDO0101.D34 Method : C:\DX\METHOD\7ANION.met 

### ACI Address: 1 System: 1 Injecti: 34 

### Detector:PED-Cond. Analyst : Column:
Calibration Volume Dilution Points Rate Start Stop Area Reject External -------------------------------------------------------------------- 1 1 3600 5Hz 0.00 12.00 1000 ********************** Component Report: A11 Components *********************** Pk. Ret Component Concentration Height Area B1. $Delta Num Time Name
----------------------------------------------------------------------------- Code 1 1.40 FLUORIDE 0.000 631325 4970085 1 0.00 2 2.23 CHLORIDE 0.000 1078446 6791602 1-4.96 0 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 3 10.57 SULFATE 0.000 391123
------------------------------------ 10395843 1 2.29 Totals 0.000 2100894 22157530 

### F11e: STD00101.D34 Samp/e: STD 1.0 PPM 4.0

3.0

2.0 uS 1.0

0.0

-1.0 0 2 4 6 8 10 12 Minutes



# 16 Z//

### Data.Reprocessed On 12/06/1994 11:13:42 Sample Name: H2OBLANK Date: 12/05/1994 19:16:38 ~ Data File : C:\DX\DATA\30704F\H2OBLK11.D13 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 13 Detector:PED-Cond. Analyst : Column:
Calibration Volume Dilution Points Rate Start Stop Area Reject External 1 1 -------------------------------------------------------------------- 3600 5Hz 0.00 12.00 1000 ********************** Component Report: A11 Components *********************** Pk. Num Ret Time Component Name Concentration Height Area B1. Code %Delta
0 0.00 FLUORIDE ----------------------------------------------------------------------------- 0.000 0 0 0 0.00 0 0.00 CHLORIDE 0.000 0 0 0 0.00 0 

# I 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 0 0.00 SULFATE 0.000 0 0 0 0.00 Totals 0.000 0 0 

## File: H2OBLK11.D13 - Samp1e: H2OBLANK

40

:1-E


### uS 20
10

ES


### 0 2 - 4 6 8 10 12 Minutes



# 17 I .1_

### Data Reprocessed On 12/06/1994 11:14:21 Sample Name: H20 BLANK Date: 12/05/1994 19:30:25 Data File : C:\DX\DATA\30704F\H2OBLK11.D14 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 14 Detector:PED-Cond. Analyst : Column:
Calibration Volume Dilution Points Rate Start Stop Area Reject External 1 1 -------------------------------------------------------------------- 3600 5Hz 0.00 12.00 1000 ********************** Component Report: A11 Components *********************** Pk. Ret Component 

### Concentration Height Area Bl. $Delta Num Time Name Code 0 0.00 FLUORIDE ----------------------------------------------------------------------------- 0.000 0 0 0 0.00 0 0.00 CHLORIDE 0.000 0 0 0 0.00 0 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 0 0.00 SULFATE 0.000
------------------------------------ 0 0 0 0:00 Totals 0.000 0 0 

## File: H2OBLK11.D14 Samp/e: H20 BLANK



# W- 0 1 0
30
uS 20
10
0


### 0 2 - 4 6 8 10 12 Minutes

1_1 ^--%

### Data Reprocessed On 12/06/1994 11:07:20 Sample Name: QC Date: 12/05/1994 19:44:12 ~- Data File : C:\DX\DATA\30704F\QC000001.D15 

### Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 15 Detector:PED-Cond. Analyst : Column: 

# -_

- - 

# __--___------------------

--- ~ 

# ____--_---------

~ 

# ---_---_ ---_----__ Calibration Volume Dilution Poi.nts Rate Start Stop Area Reject External 1 

# -------------------------------------------------------------------- 1 3600 5Hz 0.00 12.00 1000 ********************** Component Report: All Components ********************** Pk. Ret Component Concentration Height Area B1. %Delta Num Time Name 

# ----------------------------------------------------------------------------- Code 1 1.40 FLUORIDE 0.000 10255385 74735117 1 0.00 2 2.27 CHLORIDE 0.000 30865532 168156307 1-3.55 0 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 3 10.47 SULFATE 0.000



# ------------------------------------

6390129 159439805 1 1:32 

# Totals 0.000 47511046 402331230

File: QC000001.D95 

## Samp/e: QC

0 

# 1 Minutes



# 19 u,,

~ 

# ) 

# 40 30 uS 20 10 0

### Data Reprocessed On 12/06/1994 11:09:39 Sample Name: QC Date: 12/05/1994 19:57:59 Data File : C:\DX\DATA\30704F\QC000001.D16 Method : C:\DX\METHOD\7ANION.met ACI Address: 1 System: 1 Inject#: 16 Detector:PED-Cond. Analyst : Column: Calibration Volume Dilution Points Rate Start Stop Area Reject
-------------------------------------------------------------------- External 1 1 3600 5Hz 0.00 12.00 1000 ********************** Component Report: A11 Components Pk. Ret Component Concentration Height Area Bl. %Delta Num Time Name
----------------------------------------------------------------------------- Code 1 1.40 FLUORIDE 0.000 10373392 75012529 1 0.00 2 2.27 CHLORIDE 0.000 31012470 163440320 1-3.55 0 0.00 BROMIDE 0.000 0 0 0 0.00 0 0.00 NITRATE 0.000 0 0 0 0.00 3 10.45 SULFATE 0.000 6519625
------------------------------------ 169724835 1 1:16 Totals 0.000 47905487 408177684 

### File: QC000001.D16 Samp/e: QC

40

30

uS 20
10

0


### 0 2 4 6 8 10 12 Minutes



# 20

, ,r -

# I1--D-122

June 2, 1998 

# PA N Y

# ■■ i®.i 

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# ■■■■■■■ > ~ 

# ■■■■ / " ~~~.u~~~" \

# ■■■■■■ ~

# ■■■■■■ \ i■■■■■ 701 N. MAIN STREET LEXINGTON, NORTH CAROLINA 27292 PHONE 338-248-8541 TOLL FREE 800-672-6181 

# A$G

- O-JO

Mr. Brian Schrager Midwest Research Institute 5520 Dillard Road Suite 100 Cary, NC 27511-9232 Re: Cleveland County Plant (Grover, N.C.) Title V application Dear Brian: Enclosed is the Title V application that Pine Hall Brick Company filed with NCDHNR regarding the above facility. At the time I completed the ICR form I did not have this document in my possession. I trust you will find it helpful in your research for this type kiln and material at the Cleveland County Plant (Grover, N.C.). Respectfully submitted,
CUNNINGHAM BRICK COMPANY, INC.

Richard W. Cunningham 

# ~ Secretary RWC/jh Enc.: Report



# ~

### 4 

# State of North Carolina

Department of Environment, • 

# Health and Ncitural Resources Mooresville Regional Office James B. Hunt, Jr., Governor 

# e~~

IDEHNR
DIVISION OF AIR QUALITY September 9, 1997 

### Mr. Harold B. Newman Pine Hall Brick Co., Inc. P.O. Box 836 

### Madison, North Carolina 27025-0836 

# SEP 1
Subject: Title V Application

Acknowledgment of Receipt Pine HaD Brick Co., Inc. Grover, North Carolina Cleveland County Site No. 03/23/0011 . 5 

### Air Permit No. 06156R04 Dear Mr. Newman: Your initial Title V permit application was received by 

### this office on August 27, 1997. 

### Your application has been assiped the tracking number 2300115.97B. 

### Please refer to this tracldng number 

### regarding any questions you have or -

- ditional information submitted. Your application will be reviewed for completeness within 60 

### of the received date, at which time you wul receive a letter veritiing completeness of your a i
- ation or a letter indicating the application was considered incomplete and will idendfy any deficie This letter will also indicate the review engineer who will review your application. Any qu;. ;n 

### regarding your application should be directed to this individual. Sincerely,

Michael S. 

### Landis Regional Supervisor

cc: 

### Jeff Twisdale , Regional Files
GADEM\.AQ\WPDATA\PERS0NAL\K b/B\PERM1797N;'1NEHAL..TV1



# ~

~ 4 FAX 7CV , I.W -6C40 Moore!

~ Alle, North Carolina 28115 4FC An Equal C-.
- )Pr)rtunit

~ i ) ';'

~ , ", T .: - . - icft/eAc';.

- )n F-:.,plc , ,'er 919 North Main Strecit,

- )ice 704, 1, 5.'- 1699 50 0 , 1 6 recycied/ 1 0 1 , 1

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# P 

# m .

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# B r~ 

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August 25,1997

Mr. Michael S. Landis 

## DEHNR Division of Air Quality 919 North Main Street Mooresville, N. C. 28115 Reply To: PINE HALL BRICK CO., INC. Lindsay Bridge Road Post Oifce Box 836 Madison, North Carolina 27025-0836 Telephone 910-548-6007 Fax 910-548-1837

~~

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### Subject: Title V Permit Ap.plication Pine Hall Brick Co., Inc. Cleveland County, N. C. Air Permit No. 6156R04 Facility ID No. 03/23/00115
Dear Mr. Landis, In accordance with 15A NCAC 2Q.0501 and 15A NCAC instructions, enclosed are four (4) copies of the Title V permit application for the subject facility.

~ 

### Pine Hall Brick of Cleveland County, N. C. forecasts that it will exceed the 10 ton annual

emission level for hydrogen fluoride during the fourth quarter of 1997. If you have any questions related to the application , please contact Mr. Lewis Slaughter of Trigon at ( 910 )-668-0093 or me at ( 910)-548-6007.
You s truly,



### Harold B. Newman 

## RECsIA0

.:, ~

. 

# (JAUG w x 9 1997

, ~ Tal. (910) 721-7300 Fa.r. (910) 725-3946 2701 Shorefair Drive. P.O. Box 11044 Winston-Salem. NC 27116-1044

## Prepared For:

Pine Hall Brick, Inc. Post Office Box 749 Highway 29 South Kin.as Mountain, NC 28086

Prepared By: Trigon En;ineerino , Consultants, Inc. Post Office Box 18846 Greensboro, NC 27419

August 11, 1997

- i ~

:.~

s~ 

## Title V Applica

-

=on Pine 13all Bric

~ 

## .., lnc. Yir.gs Mountain, '_

~ 

## torth Carolina Tri

~ 

## on Jab No. 153-97-062 I" .22014 :


### TAB 1 - GEr'ERAL INFORMATION

Form Al Area Map Site Plan 

## Layout Flow Sheet

TAB 2- ES-1: NATURAL GAS FIRED DRYER/SILN

Forms B 1 Forms D3-1 Forms D3-2 Forms D3-3 Forms E4 TSP Forms E4 SO Z Forms E4 HCL Forms E4 HF Calculations

TAB 3- ES-2: ROCK FACING

Forms B 1 Forms C2 Forms D3-1 Forms D3-2 Forms D3-3 Forms E4 TSP Calculations

s 

### TAB 4- INSIGNIFICANT FUGITIYE SOURCES

~



### FS-1, FS-2, FS-3 with Calculations
TAB 5 - SiJNEWARY INFORMATION =`

Forms D4 :.~ 

### Forms D5 Forms E1 HF Forms E2 Forms E3 Forms E5 Forms E6

TAB 6- CALEiNDAR YEAR (CY) 1996 MATERIALS USAGE A

~ 

### YD ENIISSION FACTOR APPLICATIONS `~

### SECTION A FACILITY (General Information) 

# '. E M

REVISED: 04/15/94 AI R Q UA UTY SE C TION - APPLIC : "A FOR AIR PERMIT TO CONSTRUCTIOPERATE' -'' 

### I FACILITY NAME: a^ Hall Brick ComvarrV, Irc. MAILING ADDRESS: 634 Lindr Brid e Road, Boz 836 SITE ADDRESS: U.S. CITY: Madfson Cm': Grover COUNTY: Cleveland STATE 1VC ZIP CODE: 27025 7JP CODE: 38086 CONTACT PERSON: Harold B. Newman I T 1 TLE: ATana er, Technical Services TELEPHONE: 910

- 548

- 6007 FAX 910

- 548

- 1837 OWNER OF FACIUTY: SAAE MAILING ADDRESS: CITY: STATE: ZIP CODE: CONTACT PERSON: Hu hJ. DowdleJr. T1TLE: VicePresidetrt, Operah'ons TELEPHONE: 910-548-6007 FAX 910-548-1837 DESCRIBE TYPE OF OPERATION: BrickMamrfacturin SIC CODE(S): 145 DESCRIPTION OF PRIMARY SIC GROUP: Brfck & Structural CZay Tile FAC/UTY UTM EAST: OR LATITUDE: 35 0 10 58 " COORD/NATES UTM NORTH: LONGITUDE: 81 ° ?S 18 " HAVE YOU INCLUDED ( ) CONSISTENCY DETERMINATION( SOURCE REDUCTION & RECYCLING FORM 03,3 AND ( ) APPLICATION FEE? FAC/UTY rS: (,/ ) T1TLE V FACILRY ( ) NON-TITLE V ( ) SYNTHETIC MINOR IF TITLE VlNDICATE APPLlCABILlTY:

~ 1 2 3 4 5. (C(RCLE ALL THAT ARE APPUCABLE) 4PPLICAT/ON /S BEING MADE FOR (CHECK ALL THAT APPLY) NOTE (7
- 10 IND/CATES APPUCABIUTY TO TITLE V FACIL/TIES ONLY?: ( ) NEW FACILITY ( j ) INITIAL TITLE V PERMIT (TV) ( ) RENEWAL (rV) ( ) MODIFICATION ( ) NEW FACILITY (TV) ( ) PSD (TV) ( ) EXISTING EMISSION SOURCE(S) ( ) MINOR MODIFICATION (TV) ( ) NON-ATTAINMENT (TV) ( ) SIGNIFICANT MODIFICATION (TV) ( ) 112(g) (TV) IF APPL/CAT/0N /S BEING MADE FOR ANY OF THE FOLLOWING, FORM A2 MUST BE ATTACHED TO TH/S FORM: ( ) ADMINISTRATIVE AMENDMENT ( ) CHANGE OF OWNERSHIP ( ) RELOCATION (WfTHIN FACIL(TY) (TV) ( ) ADMINISTRATIVE AMENDMENT (TV) ( ) CHANGE OF OWNERSHIP (TV) ( ) LIKE-FOR-I.IKE REPLACEMENT ( ) RENEWAL ( ) RELOCATION (WITHIN FACILITY) ( ) L1KE-FOR-UKE REPLACEMENT (TV) ( ) 502(b)(10) NOTIFICATION (TV) HAVE YOU INCLUDED: FLOW CHART(S) ( ) ROOF DIAGRAM PLANT LAYOUT (,/ ) PLOT PLAN, (,./) AREA DIAGRAM CURRE:IVT/PREVIOUS PERMIT NO: 06156 EJPIRATION/DISCONTINUED DATE: Augw t 31, 1997 ,+ DO YOU CLAIM CONFIDENTIALITY OF DATA ( ) YES NO (SEE INSTRUCTIONS) SIGNATURE OF RESPONSIBLE PERSON OR COMPANY: TITLE: YicePresfderrt, Operadons 6 DATE: 

# x (TYPED) HughJ. DowdleJr. DEPAarMeNT Use ONLY: RECEIVED: ASSIGNED TO: PREMISE NUMBER: APPLICATION NUMBER: RETURNED: COMPLETE: REVIEWDATE:
PERMIT NUMBER: DATE ISSUED:
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### 162 tnm cu. ft/yr 1,030 Btu/cu. ft 18,447 cu. ft/hr



# ..._ Potential NG usage : Heatin; value : NOTES: FACTOR #1 - AP-42, SUPPLEMENT F(7/93). SEC 1.3 FACTOR /r- - EPA 450/2-90-011 

### ASSUMPTIONS: - TSP, PM10, AND POM ARE AFFECTED BY CONTROL 

### 'atural Gas Combustion: Criteria and Toffie Air Poliutant Emissions f o 

### ~ ^ 

### ~ ' a ' I Ceatral Office Version 

### NAME OF FACII.ITY : Pinc Hall (Kiln Max) APP 018638 

### CITY: ICinSs Moutrain Review Engineer W. w111eu COUNTY: Cleveland Boiler Input Data BoILER TYPE > 

### 21 3 1- LARGE BOII.ER > 100 mmBtu/hr 2- SMALL BOILER 10 - 100 mm.Btu 2 3 - COMMERCIAL. < 10 mmBm/hr ACTUAL NG BtJRiYED : 162 mm cu. ft/yr .0503 PM Allowable FOR POTENTIAL : 0.51 lb/mmBtu EN'I'ER BOQ-ER SIZE : 19 mmBrii/ht 9.6 Ib/hr 0 max. iaput HOURS OF OPERATION : 8,760 hr/yr .0516 S02 Allowable I EiNTER o CONTROL EFF. : 0 0 44 lb/hr (2 tnax. inpu[ 

### ACTUAL CRITERIA EiMIISSIONS Factor Emission Races P011utaIIt (lb poll.11E6 cu. ft burned (lb/yr) (lb/hr) (tpy) PM 13.7 2,219 0.25 1.11 M-10 13.7 2,219 0.25 1.11 SOx 0.6 97 0.01 0.05 NOx 140.0 22,680 2.58 11.34 VOCs 2.8 451 0.05 0.23 CO 35.0 5.670 0.645631068 2.835 

### ACTUAL TOXIC EMISSIONS ~ 

### Factor Emission Rates P011utant (Ib poll./1E12 Btu) (lb/yr) - (lb/hr) (tpy) 

### FORMALDEHYDE 220.3 36.8 4.20E-03 0.018

- HEAT CONTENT OF NG 1030 Btu/cu.ft 

### VOCS = TOC*(1-%METHANE) Disclaimer This spreadsheet is for your use only and should be used with caution. DEHNR does not guarantee the accuracy of the information contained. This is a draft spreadsheet and is continually revised and updated. It is your responsibility to be aware of the most current

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# , .,

### 'atural Gas CombLLstion: Criteria and Toxic Air Pollutant Emissions Ci ` fc AGta Ceaaal OPfice Version 

### NAME OF FACILITY: CITY: 

### COUNTY: Boiler Input Data BOILER TYPE > 1- LARGE BOILER > 100 mmBcu/hr 2- SMALL BOII..ER 10 - 100 mmBtu 3 - COMMERCIAI. < 10 mmBtu/hr ACTUAL NG BURNED :
FOR POTENTIAL : ENTER BOILER SIZE : HOURS OF OPERATION : ENTER c CONTROL EFF. : Piae Hall Brick Kings Mountaia Cleveland

2



### 96 Imm cu. ft/yr

19 mmBtu/hr 7,224 hr/yr 0 % APP 018638



### Review Engineer W. willecs

.0503 PM Allowable I

0.51 Ib/mmBtu 9.6 Ib/hr (5 max. i.nput .0516 S02 Allowable I

44 Ib/hr (D max. iapuc 2 3



### ACTIJAL CRITERIA EiNIISSIONS Factor Emission Rates P011utant (lb po11.11E6 cu. ft buined Qb/yr) (lb/hr) (tpy) PM 13.7 - 1,315 0.25 0.66 M-10 13.7 1,315 0.25 0.66 SOx 0.6 58 0.01 0.03 NOx 140.0 13,440 2.58 6.72 VOCs 2.8 267 0.05 0.13 CO 35.0 3.360 0.645631068 1.68

~ 

### ACTLJAL TOXIC E1VIISSIONS Factor Emission Rates P011utant (lb poll./1E12 Btu) (lb/yr) - (lb/hr) (tpy) 

### FORMALDEHYDE 220.3 21.8 3.02E-03 0.011 POtential NG usage : 133 mm cu. ft/yr 18,447 cu. ft/hr Heating value : 1,030 Btu/cu. ft - , 

### NOTES: FACTOR #1 - AP-42, SUPPLEMENT F(7/93). SEC 1.3 FACTOR !!2 - EPA 450/2-90-011 

### ASSUMPTIONS: - TSP. PM10, AND POM ARE AFFECTED BY CONTROL - HEAT CONTE:`!'I' OF NG 1030 Btu/cu.ft 

### VOCS = TOC*(1-

~ 

### '

aMETHANE)

Disclaimer This spreadsheet is for your use only and should be used with caution. DEHNR does not guarantee the accuracy of the information contained. This is a dratt spreadsheet and is continually revised and updated. It is your responsibility to be aware of the most current

### PINE HALL BRICK COMPANY, INC. TITLE V APPLICATION GROVER, NC

PROCESS AREA: ROCK FACING (ES-2) Fired brick are subjected to one of five chipping machines that remove pieces from the face of the brick to create the appearance of the irregularities of natural rock. Each rock-facing machine is equipped with a vacuum duct to remove dust resulting from the chipping. The dust is conveyed to a bagfilter.,The bagfilter is installed outside the building and has 770 sq. ft. of filter area.



## 4:r s

~ ~~

### SECTION' B EMISSION SOURC`:": ;t

~ 

### ENERAL) REVISED: C -W1SIe4 AIR QUALIT'l :: TION 

# F 6 7 1

r --- - - MISSION SOURCE DESCRIPTION: Brick Rock-Facing 0 eration - EMISSION SOURCE ID NO: gS-? CONTROL DEVICE ID NO: RF-3BH-1 

# I EMISSION POINT ID NO(S): gp-Z
INDICATE WHETHER THIS SOURCE IS SUBJECT TO ( ) NSPS OR ( ) NESHAP REGULATIONS. ALTERNATIVE OPERATING SCENARIO (AOS) NO:
DESCRIBE PROCESS: Fired brick enter machines that chip away pieces causing irregularities fn the surface that simulate natural rockc

OPERATION DATE: June 1989 SEASONAL VAR/ATION ('/) JAN-MAR: ?S APR.JUN: ZS JUL-SEP: ZS OCT-DEC: ?S PROCESS .tifilTERldLSEN7ERLWGPROCESS-CO?V77MI0US MAX DESIGN CAPACITY (UNIT/HR) REQUESTED CAPACITY LIMITATION (UNIT/HR) TYPE UNITS t,f o d u l nr R ric k TOAIS > >

M4TERNL4ENTERINGPROCESS-BA11rHOPERATION MAX DESIGN CAPACITy (UNIT/HR) REQUESTED CAPACITY LIMITATION (UNfT/BATCH) TYPE UNITS

MAXIMUM DESIGN CAPACITY (BATCHES/YR): MAXIMUM DESIGN CAPACITY (BATCHESMR):
FUEL USED: TOTAL MAXIMUM FIRING RATE (MILLION BTU/HR): MAX CAPACITY HOURLY FUEL USE: MAX CAPACITY ANNUAL FUEL USE:
DESCRIBE ANY MONITORING DEVICES, GAUGES, OR TEST PORTS:
.;t : r
.. •: ~

INDICATE ALL REQUESTED STATE AND FEDERALLY ENFORCEABLE PERMIT LIMITS (e.g., hours of operation, material input rates, emission rates, etc.) AND DESCRIBE HOW THESE LIMITS ARE MONITORED AND WITH WHAT FREQUENCY.

COMMENTS: Input is limited by the capacity ojthe plant k

- iIn capacfty. ~~

### PINE HALL BRICK COMPANY, INC. TITLE V APPLICATION GROVER, NC

PROCESS AREA: NATURAL GAS FIRED-TUNNEL KILN (ES-1) Wet, formed and stacked brick on kiln cars continuously pass from pre-dry area to dryer then through the kiln. Natural g as is the , fuel source for the heat necessary to fire the brick. The combustion gases (and heat) flow counter to the product bricks through the kiln and are emitted from a stack at the kiln. The gases contain both the products of N.G. combustion and the airborne of the firing process. ' This process is the capacity controlling of the facility. Production in CY96 was 22,208,370 standard brick equivalents. The theoretical maximum capacity is 40,000,000 SBE. Consequently, potential is determined based on a ratio of 40,000,000/22,208,370 or 1.ti80/1.

L.

/ ~

# F B 1 SECTION B EMISSION SOURCE (GENERAL) REVISED: 04/15184 AIR QUALITY SECTION
' vIISSION SOURCE DESCRIPTION: Tunnel Kiln 

# I EMISSION SOURCE ID N0: ES-1 CONTROL DEVICE ID NO: NA EMISSION POINT ID NO(S): EP-1
INDICATE WHETHER THIS SOURCE IS SUBJECT TO ( ) NSPS OR ( ) NESHAP REGULATIONS. ALTERNATIVE OPERATING SCENARIO (AOS) NO:
DESCRIBE PROCESS: Brick Kiln fired with iVG/LPG. . The hot gasses, including the products of combustion and products of the firing process flow counter to the brick flow and are emitted at the kiln stack

OPERATION DATE: August 1988 SEASONAL VARlATION (%) JAN-MAR: 25 APR.JUN: 25 JUL-SEP: 25 OCT-DEC: zj tL4TERL4LSENTERL'vGPROCESS-CONTINUOUS PROCESS MAX DESIGN CAPACITY (UNITIHR) REQUESTED CAPACITY LIMITATION (UNIT/HR) TYPE UNITS
Vfoditlar Rricks TOV

,tiIATERlALSEN7ERINGPROCESS-BATCHOPERATION MAX DESIGN CAPACITY (UNIT/HR) REQUESTED CAPACITY LIMITATION (UNIT/BATCH) TYPE UNITS

MAXIMUM DESIGN CAPACITY (BATCHESJYR): MAXIMUM DESIGN CAPffiClTY (BATCHES/HR): FUEL USED: Natural Gas /Pro ne TOTAL MAXIMUM FIRING RATE (MILLION BTU/HR): 19.0 MAX CAPACITY HOURLY FUEL USE: 18.-JS mcj MAX CAPACITY ANNUAL FUEL USE 162 mmcf
DESCRIBE ANY MONITORING OEVICES, GAUGES, OR TEST PORTS:

T -

INDICATE ALL REQUESTED STATE AND FEDERALLY ENFORCEABLE PERMIT LIMITS (e.g., hours of operation, material input rates, emission rates, etc.) AND DESCRIBE HOW THESE LIMITS ARE MON(TORED AND WITH WHAT FREQUENCY.

I COMMENTS: 

## ~, ~

### SECTION C CONTROL DEVICE (FABRIC FILTER) 

# L C2 —/ 

### ISED: 04/151 , '94 AIR OUALTTY SECTIOIY )N'I'ROL DEVICE ID ;VO: RF-3BH-1 CON'iROLS EMISSIONS FROM WHICH EMISSION SOURCE iD u0(S): ES-2 EMISSION POIM m NO(S): EP-2 POS1770Nlrl SERIE'S OF CONTROLS NO. 1 OF 1 UNI IS MANUFACiURFR Mikrocul MODEL NO: 64S 8-20 ALTER^tATIVE OPERATING SCENARIO (AOS) N0: DESCRIBE CON'iROL SYSTEA: Dust laden air is conveyed from picJaup point through the bagf" tlter by fan that pulls a vacuum on the system

TSP POLLUTANT(S) COLLECTED: CORRESPONDIIYG EFFICIENCY: 

### 99 % o % q 2 EFFICIENCY DETERtitINATION CODE: BEFORE CONTROL ENtISSION RATE (LB/HR): 200 AI-'tER CONTROL E-MISSION RATE (LB/HR): 

### 0.2 PRESSURE DROP (IN. H20): MIN

~ 

### _ MA?(? WARNING AL,AR:1d? YES 

### _,L NO INLET TEMPERATURE (F): MIN MAX OUTLET TEMPERATURE (F): MIN MAX INLET aII2 FLOW R.aTE (ACFIV): 3500 'R TO CLOTH RATIO: 4.5 FILTER SURFACE AREA (FI"_): 770 FIL.TER .ML4?C. OPER.aTING TEMP. (F): 150 i,TER 14ATERL-XL: Polvester DESCRIBE CLEaNIIYG PROCEDURF.S: TIIvIE BETWEEN CLEA.^lING: lScPr ( ) MECHAMCAI. ( ) REVERSE FLOW ( ) SIMPLE BAG COLLAPSE CLEAMNG TIhIE: SONIC AIIt PULSE ( ) RIIvGED BAG COLL.aPSE ( ) OTHF FR:
DESCRIBE MAIIVTENANCE PROCEDURES: Monthly: Clzeck bags for connectiorts or leakr. Check fan belts and lubricate bearings

DESCRIBE MOISTURE BLINDQYG, CFiEMICAL RESISTIVTIY, AND/OR SPECIAL OPERATNG COND[TIONS:

DESCRIBE A1YY MONTI'ORIIYG DEVICES, GAUGES, TEST PORTS, ETC:

SHOW BY DIAGRau`I THE RELATIONSHIP OF THE CONTROL DEVICE TO ITS EMISSION SOURCE(S):



## ~~

### SECTiON D rD3- 1 

### SPECIFIC EMISSION SOURCE (EMISSION INFORMATION)

(•see note in instrudions conceming state air to)dcs regulations) ~~o~ Da~s~s,a AIR QUALITY SECTION ,I EMISSION SOURCE DESCRIPTION: Tunnel Kiln EMISSION SOURCE ID NO: ES-1 

# I IS THIS SOURCE A FUGITIVE SOURCE? ( ) YES NO ALTERNATIVE OPERATING SCENARIO (AOS) NO:

POLLUTANT EMISSION FACTOR TYPE EMISSION RATE IN LBS/HR EMISSION RATE IN POTENTIAL ACTUAL POTENTIAL ACTUAL TSP 5 0.25 0.25 2219 1315 P.W-10 5 0.25 0.25 2219 1315 SOx 5 0.01 0.01 97 58 NOx 5 2..i8 2.58 22,680 13,440 VOC 5 0.05 0.05 451 367 CO 5 0.65 0.65 5670 3360 HYDROGE.V CHLORIDE 5 1.57 1.06 13,678 7,649 HYDROGE.V FLL'ORIDE 5 6.36 4.28 55,726 30,959 FORtiL4LDEHIDE 5 4.2E-03 3.0E-03 36.8 21.8

t , f -

~ COMMENTS:

### SECTION D SPECIFIC EII

~ 

### IISSION SOURCE (EMIISSION INFORil

~ 

### 1ATION) D3-1

('see aota in imnvctioas coaceraiag stace air coxics regulatioas)

AIIZ QUALITY SECTION cFn• naii S

~ oa EMISSION SOURCE DESCRIPTION: BricaE Roc,t Facing Opemtion + EMISSION SOURCE ID NO: SS-2 

# I IS THIS SOURCE A FUGITNE SOURCE? ( ) YES (11) NO AI.TERNATNE OPERATIIVG SCENARIO (AOS) N0:

~ EMISSION ~ SSION RATE IN EMISSION RATE IN FACTOR LBS/HR 

### I POLLUTANT TYPE POTENTIAL ACTUAL POTENTIAL ACTUAL

TSP 2 0.22 0.20 

## 1968 236 

# I PMIO 2 0.011 0.01 98.4 11.8



## I

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## ~ 

# f

### SECTION D D 

### ~ ? SPECIFIC EMISSION SOURCE (REGULATORY ANALYSIS) AIR C2UALITY SECTION /I SED: 04115154 EMISSION SOURCE DESCRIPTION: Tunnel Kiln EMISSION SOURCE ID NO: ES-1 ALTERNATIVE OPERATING SCENARIO (AOS) NO:

REGULATED POLLUTANT EMISSION AND OPERATING LIMITS APPLICABLE REGULATION TSP 0. 25 LB/HR <17.9 LB/Mt 1 SA NC4C 2D . 0515 PM-10 NONE NONE SOx 5E-04 < 2.3 LBS S02&lM07T! INPUT 1 SA NC9C 2D . 0516 NOx NONE NONE 

### VOC NONE NONE CO NONE NONE HCL 1. 57 LB/HR > 0.18 LB/HR 1 SA NC4C 2H . 0600 HF 6.36 LB/RR > 0. 63 LB/DAY, 0.064 LB/ffit 1 SA NCAC 2H . 0600 FORNL4LDEHYDE 4.2E-03 LB/HR < 0. 04 LB/HR 1 SA NC4C 2H . 0600

~ . : . 

## r

...

COMMENTS:

~ ~/

### SECTION D D3-2 SPECIFIC EMISSION SOURCE (REGULATORY ANALYSIS) AIR QUALITY SECTION 'ISED: W 5/94 EMISSION SOURCE DESCRIPTION: BrrckRock-FacingOperrrtron EMISSION SOURCE ID NO: ES-2 ALTERNATIVE OPERATING SCENARIO (AOS) NO:

EMISSION AND OPERATING UMITS APPUCABLE REGULATION REGULATED POLLUTANT TSp 0.1? L&WHR < 4. 0 LBS/FIIZ I5A,VC4C lD . 0513

~ c Y

z .r

COMMENTS:

, 

## ~ ~

### SECTION D D3-3



### SPECIFIC EMISSION SOURCE (REDUCTION AND RECYCLING ACTIVITIES) AIR QUALITY SECTION REVISED: 0411 S194 :MISSION SOURCE DESCRIPTION: Tunnel Kiln EMISSION SOURCE ID NO: ES-1 

# I -m REGULATED 

### POLLUTANT ONGOING SOURCE 

### REDUCTION ACTIVITIES (ENTER CODES) QTY. EMITTED



### BEFORE REDUCTION (LBS/YR) QTY. EMITTED 

### AFTER REDUCTION (LBS/YR) PLANNED SOURCE



### REDUCTION ACTIVITIES (ENTER CODES) 

### TSP NONE NA NA NONE AW-10 NONE NA NA NONE SOx NONE NA fVA NONE 

### NOx NONE NA NA NONE vOC NONE iVA NA NONE CO NONE NA 

### ,V,4 NONE HCL NONE N.4 NA ,VONE HF NONE NA ,VA ,VONE



### ., . ~

~ 

### r.
COMMENTS:

1W

### SECTION D D3-3

SPECIFIC EvIISSION SOURCE (REDUCTION Al

~ 

### 1D RECYCLING ACTIVITIES) AIR QUALTTY SECTION sVISED: 04J15194 EMI SION S UR E DESCRIPTI N: SriaE Roc,t FadnQ Oaaation E1

~ IISSION SOURCE ID N0: ES-z REGULATED ONGOING SOURCE QTY. EMIZTED QTY. EMPPTED PLANNED SOURCE POLLUTANT REDUCTION BEFORE REDUCTION AFrER REDUCTION REDUCTION ACTMTIES (I.BS/YR) (LBS/YR) ACTIVITIES (ENTER CODES) (ENTER CODES)
TSP NONE NA NA NA



# I

® ®
COMMENTS:

~ •~

### SECTION D 

# a EIVIISSION POINT ' FVIS ED: 04115194 

### AIlt QUALITY SECTION

EMISSIOIY POINT ID NO. LIST,ILL QYFORMATION A.SSOCIATHD WiTH F.ACH EMISSION POINT

EM HEIGHT (F'17 I E Q (FTj 

## ~ I T 

## ~ I (FI' SE



## ~ I ~ ACFM 

## ~ I 

## ~ DQtECiTON 

## ~ RAIIY CAP? (Y OR ,^t)

e

COMIIrIENTS:



## ,~~~

### SECTION D FACiLITY EMlSSIONS SUMMARY 

# 0
AaR auaLITY SECTION

, ISED: W594 

### TOTAL FROM SPEC/F!C EM1SS10N SOURCE 

### SUMMARIES

POLLUTANT ANNUAL EMISSIONS IN LBS/YR CAS NO. ACTUAL POTENTIAL I 

## PM

S02 1566 58 4781 97 

### I NOx 13,440 22.680



## CO 3360 5670 

# I VOC 267 451



## LEAD 0 0 I RYDROGEY CHLORIDE 7647010 7649 13,768

RYDROGEN FL UORIDE 7664393 30,959 

### .SS, 726 I FORVIALDEHYDE 50000 21.8 36.8



### I

I

I

I
, 

## I -

TOTAL FACIUTY FiRING RATE FOR FOSSiL AND WOOD-FIRED BURNERS: MILLION BTU/HR 

# F TOTAL REACTIVE VOC's FROM THE FACIL1lY: 0 LBSIDAY or 96 Total Control or OTHER (specify)
'MMENTS:

~ /

## SECTION E 

# E l TITLE V INFORM. .. . ,ON
JISED: 04/15/94 AIIt QUALITY SECTION 

# II I AND ALL SUBSEQUENT E" FORM D (E2 THROUGH E6 

# ~ E V YOU NILTST COMPLETE THIS FORM II
INDICATE HERE IF YOUR FACILITY IS MAJOR FOR TITLE.V BY ( ) CATEGORY OR (V ) EMISSION LEVEL.

IF MAJOR CATEGORY, INDICATE THE CATEGORY:

IF MAJOR EMISSION LEVEL, COMPLETE THE FOLLOWIIVG:
POLLUTANT(S) FOR WHICH THE FACII.ITY IS MAJOR EMISSIOfY RATE (SPECIFY UNiTS) 

### HYDROGEN FL UORIDE I S. S TONS/YEAR

AR& YOU SUB.fECT TO ANY CURRENT MAXIMUM ACHIEVABLE CONTROL TECHNOLOGY STANDARDS (MACTs) OR FUTURE MACTs. IF SO, SPECIFY: NnNF.

LIST ANY ADDITIONAL REGULATIONS WHICH ARE REQUESTED TO BE INCLUDED IN THE PERMIT SHIELD AND PROVIDE AN fiXPLANATION FOR THE REQUESTED SHIELD: ' REGULATION EXPLANATION

:y

/~,~~

### SECTION E TiTLE V INSIGNIFICANT ACTIVITIES SUMMARY E2 REVtSED: oa/15G4 AIR G2UALITY SECTION INSIGNIFICANT ACTIVITIES PER TITLE 15A NCAC 20.0507(b) DESCRIPTiON OF EMISSiON SOURCE UNITS 8ASIS FOR EXEMPTiON (REF. 15A NCAC 21.0507 (b) 1 FS-1: Grtndfng & Screenfng BLilding < S TONS !SA NCAC 2Q .0102(b)(2)(E)(i) REGULATED POL UTANTS 2

. FS 2: Storage & Blending Building <S TONS 1SA NC4C 2Q .0102 (b)(2)(E)rz) REGULATED POL UTANTS 3 FS 3: Lkvnp Truck Pit <S TONS 15A NCf1C 20 .0102 (b)(2)(E)(i) REGUL4TED POL UT.lVT'S 4, Propane Storage Tank: one 30,000gat.' Exernpted I54 :YC4C20.0102 (b)(1)(D)

7.



### 8.

REQUEST FOR INSIGNIFiCANT ACTIVITIES PER TI T LE 15A NCAC 20 .05E78 aa DESCRIPTION OF EMISSION SOURCE UNITS BASI;fiOR EXEMPTION (SEE INSTRUCTIONS) 1.

2.



### 3. ' 

### ~

### SECTION E EMISSION SOURCE (INITIAL/RENEWAL TITLE V FAC1L1TY) E3 REVISED: 04115/94 AIR QUALITY SECTION aMISSION EMISSION CONTROL CONTROL EMISSION SOURCE SOURCE DEVICE DEVICE POINT ID N0. ID NO. DESCRIPTION ID NO. DESCRIPTION or "FUGITIVE"

_7 _7 _7

### SECTION E COMPLIANCE PLAN (METHOD OF COMPLIAlvCE) Q V 7SED: 04/15/94 

### EMISSION SOURCE ID N0. 

### F-7- 1 REGULATED POLLUT 

### arrr 'rcp APPLICABLE REGUI.ATION 1 sa nrr'a r 7n ns 7 s ALTIItNATIVE OPERATION SCENARIO (AOS) NO:



### ~ MONITORING REQUIltEMBNTS IS ENHANCED MONITORING APPLICABLE? ( ) YES (-J) NO IS ENHANCED MONITORING PROTOCOL ATTACHED? ( )YES ( ~ ) NO MONITORING DEVICE TYPE: MONITORING LOCATION: OTHER MONITOItING METHODS (DESCRIBE IN DETAIL): NONF_'

GENERALLY DESCRIBE THE FREQUENCY AND DURATION OF MONITORING AND HOW THE DATA WILL BE RECORDED (i.e., every 15 minutes, 1 minute instantaneoas readi.nss raken to produce an hourly avera;e): NONE

TEST METHODS

REFERENCE TEST METHOD DESCRII'TTON: NnNF_

REFERENCE TEST METHOD CITATION: NnNE

RECORDKEEPING DATA (PARAMETER) BEING RECORDED: FREQUENCY OF RECORDKEEPING (HOW OFTEN IS DATA RECORDED): N d

.~ '

REPORTING REQUIREMENTS GENERALLY DESCRIBE WFiAT IS REPORTED:

FREQUEIYCY: ( ) MONTHI.Y ( ) QUARTERLY ( ) ONCE EVFRY 6

I 1 nlVF PFR YFAR !I/ 1 OTI4F12 (DESCRBE) A c ncrrnWmvrn nv nreiirf'

~ ,I

### SECTION E C OMPLIANCE PLAN (NIETHOD OF C OMPLIANCE) El

' 7SED: 04/15/94 EMISSION SOURCE M N0. F'.T- I REGULATED POLLUTANT Su/fiir ninriilo APPLICABLE REGUI.ATION 1 sA NCa r- 9n ns 7K AL,TERNATIVE OPERATION SCENARIO (AOS) NO: MONITORING IS ENHANCED MONITORING APPLICABLE? ( ) YES N) NO IS ENHANCED MONITORING PROTOCOL ATTACFiED? ( )YES N) NO MONPTORING DEVICE TYPE: MONITORING LOCATION: 0'I'HER MONITORING METHODS (DESCRIBE IN DETAIL): NQNE'

GENERALLY DESCRIBE THE FREQUENCY AIVD DUR4TION OF MONITORING AiND HOW THE DATA WILL BE RECORDED (i.e., every 15 mimues, 1 minuce insranraneous readings raken co produce an hourly avera,e): NA

TEST METHODS

REFERENCE TEST METHOD DESCRIP'I'ION: NnNF_

REFERENCE TEST METHOD CITATION: NA
RECORDKEEPING RE DATA (PARAMETER) BEING RECORDED:

. ., FREQUENCY OF RECORDKEEPING (HOW OFTEN IS DATA RECORDED): NA

~

..

~ ."•

REPORTING GENER.ALLY DESCRIBE WHAT IS REPORTED:

FREQUENCY: ( ) MON'TEII..Y ( ) QUARTEtLY ( ) ONCE E`IIItY 6

( ) ONE PER YEAR (

~ / ) OTI-IER (DESCRIBE) ASnFTFAL

~ S
~ rn nv e ~n~ in'

### SECTION E COMPLLAiNCE PLAN (METHOD OF COMPLIANCE) E4

' ILSED: 04l15/94 EMISSION SOURCE ID N0. F.S 1 REGULATED POLLUT Aty'i' RynRnr:E Av r747 nRmc APPLICABLE REGUI.ATIOty I SA N!'A!' 2FT 06()/) ALTEBNATIVE OPERATION SCENARlO (AOS) NO: MONTTORING IS ENHANCED MONITORING APPLICABLE? ( )YES (4) NO IS ENHANCED MONITORING PROTOCOL ATTACHED? ( )YES (4) NO MONITORING DEVICE TYPE: MONITORING LOCATION: OTHER MONITOR]NG METHODS (DESCRIBE IN DETAII.): NQNF

GENERALLY DESCRIBE THE FREQUENCY AND DURATION OF MONITORING AND HOW THE DATA WII.L BE RECOR.DED (i.e., every 15 minutes, 1 minuce insransnneous readings raken co produce an hourly average): NA



### TEST METHODS

REFERENCE TEST METHOD DESCRIPTION: NONE



### sl REFERENCE TEST METHOD CITATION: N,9

RECORDKEEPING DATA (PA.RAMETER) BEING RECORDED: FREQUENCY OF RECORDKEEPING (HOW OFTEN IS DATA RECORDED)
: NA ._

..., ~

REPORTING GENERAI..LY DESCRIBE WHAT IS REPORTED:

FREQUENCY: ( ) MON'I'HII.Y ( ) QUARTfRLY ( ) ONCE EVERY 6

~ i nwlL' DGD VFSR ( ~ ~ (}TF{TM (pESCRME)

~ C fiC7TDR/f
~ 1 2 't+ Dy DGD;/lT ; I /

### SECTION E COMPLIANCE PLAlY (METHOD OF COMPLIANCE) E ~ , W LSED: 04/15/94 EMISSION SOURCE ID N0. REGUT ATED POLLUTAN'T' Rvnrrnr_FN ff rrnnmE APPLICABLE REGULATION i s,a Nra r 7rf n,snn ALTIItNATIVE OPERATION SCENARIO (AOS) NO: MONITORING IS ENHANCED MONITORING APPLICABLE? ( ) YES NO IS ENHANCED MONITORIlVG PROTOCOL ATTACHED? ( )YES ( ~ ) NO MONITORING DEVICE TYPE: MONITORING LOCATION: OTHER MONITORING METHODS (DESCRIBE IN DETAII.,): NONF

GE.YERALLY DESCRIBE THE FREQUENCY AND DURATION OF MONITORING AND HOW THE DATA WILL BE RECORDED (i.e., every 15 minuces, 1 minute insranra.neous readings taken to produce an hourly average): NA

TEST METHODS

REFERENCE TEST METHOD DESCR.IPTION: NONF'

REFERENCE TEST METHOD CITATION: NA
RECORDKEEPING REQUIItEMENTS DATA (PA,RAMETER) BEING RECORDED: NnNF FREQUENCY OF RECORDKEEPING (HOW OFTEN IS DATA RECORDED): N A

REPORTING REQUIIZEMENTS GENERALLY DESCRIBfi WHAT IS REPORTED:

FREQUENCY: ( ) MONTHLY ( ) QUAR'IZRI.Y ( ) ONCE EVERY 6

~ 1 nNF PER YEAR ) OTHER (DESCRIBE) 4S nFTF"'^"'z'^ OV DGDUrP

### SECTION E COMPLIANCE PLAN (METHOD OF COMPLIANCE) E4 --ViSED: Oan s/sa EMISSION SOURCE ID NO. E'S-? REGULATED POLLUTANT TSP APPUCABLE REGULATION

_ 15,4 ur..4C 20 _ osls ALTERNATIVE OPERATION SCENARIO (AOS) NO: ( MONITORING REQUIREMENTS IS ENHANCED MONITORING APPUCABLE? ( ) YES (J) NO IS ENHANCED MONITORING PROTOCOL ATTACHED? . ( ) YES (,/ ) NO MONITORING DEVICE TYPE: MONITORING LOCATION:. OTHER MONITORING METHODS (DESCRIBE IN DETAIL): NONE



### GENERALLY DESCRIBE THE FREQUEIVCY AND DURATION OF MONITORING AND HOW THE DATA WILL BE RECORDED (i.e., every 15 minutes, 1 minute instantaneous readings taken to produce an hourfy average): ?yO

~~ F.

TEST METHODS

REFERENCE TEST METHOD DESCRIPTION: NON

- F

REFERENCE TEST METHOD ClTAT10N: rIONF.
RECORDKEEPING REQUIREMENTS DATA (PARAMETER) BEING RECORDED:

.., FREQUENCY OF RECORDKEEPING (HOW OFTEN IS DATA RECORDED): NA

4.~

~ .
REPORTING REQUIREMENTS GENERALLY DESCRIBE WHAT IS REPORTED:

FREQUENCY: ( ) MONTHLY ( ) QUARTERLY ( ) ONCE EVERY 6 MONTHS

( ) ONE PER YEAR OTHER (DESCRIBE) 'S ^=D 1 fZVEDBYP RL/R - -

### SECTION E T1TLE V COMPLIANCE CERT1FiCAT10N /IsED: 04115FJ4 In accordance wfth the provisions of Titte 15A NCAC 2Q .0520 the responsible company offlcial of:

(COMPANY NAME) 

## PjN , HAT , BgICK CO3. IN . (COMPANY ADDRESS) 

### 634 f



## JND EY BRID(rE T)., 836 (CITrr, NC) 

## M4DISOM 1VC 27025 (COUNTY) 

## ROCKINGHAM (PERMIT NUMBER) 

### 06156

certifies that 1. for applicable requirements with which tfie facility is in compiiance, the facility shall continue to comply with such requirements;

2. for applicable requirements that will become effective during the permit term, the facility shall comply with such requirements;

3. for applicable requirements for which the facility is not in compliance at the time of permit issuance, a narrative description of how the equipment wiil achieve compliance with the applicable requirements has been submitted to the North Carolina Division of Environmental Management; and

4. the facility shall fulfill applicable enhanced monitoring requirements and submit a compliance certification as required by the EPA and 40 CFR Part 64. ,

Schedule for Submission of Compliance Certitication During the Term of The Permit: Frequency of Submittal As detererrned by nenxit Beginning / /

~ y The undersigned certifies under the penalty of lawthat all inforrnation and statements provided ii ~ ,the application, based on information and belief formed after reasonable inquiry, are true, accurate, and complete.

~ date Signature of responsible company official 

### H]igh J. Dowdle Jr. Vice President, Onerationa Name, Title of responsible official (Type or print) [ 

# E

]

6.s.er.a rv 2 1we.a G. riaen Enew.rvv ca.rs.iR rt.

### SECTION E TITLE V COMPLIANCE SCHEDULE -VISED: W5194 

## COMPLIANCF STATUS WITH RFSPECT TO ALL APPLlCABLE REQUIREMENTS: W ill each emission source at your facility be in compliancE with all appiicable requirements at the time of permit issuance and comply with these requirements? (
~ 

### ) YES () NO (if no compiete a through f below for each 

### requirement for which compliance is not achieved.) WII your facility be in compliance with all applicable requirements taidng effeci during the term of the permit and meet such requirements on a timely basis? (4) YES () NO (if no complete a through f below for each requirement for wiiicti compliance is not achieved.)

a. Identify emission source ID No. , 

### b. Identify applicable requirement for which compliance is not achieved:

c. Narrative description of how compliance wiil be achieved with this applicable requirements:

d. Detailed Schedule of Compiiance: 

# Ste s Date Exoected: 

# -_

>~

e. Frequency for submittal of progress reports (6 month minimum)

f. Starting date for submittal of progress reports



# ~ 

# L

Ei.qoi.e iaw. vvve.a w Trydr 6v+' ~ ^v co

~ frm M 

# F

### I 14 : 20 Kr1G h1 I NERALS, I NC. P. 02



## ~ Z oFCc 

## ~

Narth Cueiina Department af Natural Resources and Comfnvnity Da+elaprnent

Emironmentsl Manaiement Camrnhslon AIR PEILNIIT APPLICATION' pate 1 o! 1 GENERAL INFaRMATiGN /NSTR UCTIONS ON I.I CX •To construct 3nd ooertle Air Emisrion Sourcrs snd Controi Derices in iecordance with N. C. Gensral Sa tutas Chaptar 143, Artida 21. PLEASE TYPE OR PRINT. ATTACH APPROPRIATE E.MiSS10N SOURCE AND CONTROL DEYICE FORMS FOR lrACH SOURCE LISTED IN ITEM 6 BELOW. 1. Faciiity'Nartme (Comoany, Estiblishment, Town. Etc.): S1C Code Oate FdR DEHA U5E dNLY Kings Mountain 8r1ck (Div, of KMG MineraTs; Inc.) 06/26 89 DATE iEC=ivED: 2. Sitc Location (St./Rd.JHwy.): Citq Zip Code Counry Hwy. 29 South a*. SR2238 Grover 28073 C1eveland UTM Narth UTM East UTM Zone
3. MaitinjAddress (P, 0. Box(St.;Rd.JHwy.): 

## P. O. Box 129 ii tr State Z8086 e (704) 739 

## ~ 3616 de 

### ings Mountai n K.C.

4. ~~ rnticanl'Tethnica! Contact: Title Phone with Area Code PER ~I~ IIT NUMBER: Gene Stone Plant Superintenden ~ (704) 937-7431 

### DATEISSUED : 5. De

~ erintiun nf nreratian cenducced at above faeiiiiy: 

## Structural clay brick manufacturing faciTity, brick kiTn with Combination naturaT

. _gas/rueT oi1 b

~ 

### rners artd associa` ~~ 

### raw

~ 

### nater

~ 

### aT, for,rtina conv2vfna and 

## packaging process equipment Lisi each EMISSICN SpURC= and CONTROL DEVIC: for which apvlication is made. Asaignan ID NUMBER toe3eh ernission sour-a and controt dcvice whicil uniqucfy identifies that soun:n. At:ach aovroprizte emission sourca and controf device forr,ts for ur.fi. EMiSStON SOURCE 10 NO. CONTROL DEVICE ID NO. 

### Brick ROCkfaCe Equipment RF-3 Baahouse RF-3-3H-1

USE 5EPaRATE 514Ee_T(5) IF NEEDED

.~ `.` ~ J

.. 7. Mazimum racitity ooeration: ~ Hours/Day 

### 7 Days/Weck

~. • ~ _.Weeks/Year 8. Nimc and address oF cn;;necring iirm tl,at prepared appiieation or ptans: 

## n/a

_ y Signa rc ur ibfc rson or c pany ofrici ~K~~ Date 

### 06/26/89 Signcr's Namc (TYPE OR PRINT) Tille Phone wittl Arra Code Oavid H. Lancast2r P1ant Engineer (704) 739-36I6 JRM AQ-ZZ

KIIIA

### 0-94 FR I I 4: 21 Kr1G M l NERALS, I NC. F. 03


# ~ at~~~

GENERAL DATA FOR PiiOCESSES OR FU1:L BURNING SOURCES



## ~ • page t of 3 NOTE: 00 N O T U SE T HIS FORM FOR INCtNERATORS, USE FORM "F". PLEASE TYPE OR PR1NT. ATTACF{ TO THE GENERAL INFORMnT10N FORM "A". IF APPLICABLE, ATTACH AIR POLLUTION CONTROL DEVICE FORM "C'. USE SEPARATE FORM FOR EACJi SOURCE. 1, Emissinn Source snd ID NQ. (FROM GF.NERAL INFORMATiON FORM "A", ITE4t 6j: 

## Brick Rocicfacing equipment RF-3 Z. Oc3criptPon of Process or Fuef Burnins Source Includ;n6Air Contral Deyice: 

## Fugit_ive_d us 

## t /particu 

## T ate collection from finfshed brick 

### face texturirt 

## g operation

t - (; 3. Perrnit App(ication is mide for (G4ECK ONE ONLY): Mori ~'~'-~I - I (p (5(Q

~ 0() Ncw Source () Exist;n= Source () MadircatPon - Lsst Pcrmit No. C omr+ , cnce Consiryctia nD a 1c _ ~ ~ , 19

~ - Opention Dete 1. A1,tzimum Sottrce Oocrition: S Flovrs/Day 5 D2y3/SVeefc 50 _We:lcs/Yeu S. Air Conuminant.3 Maximum Actuil Emissions Emission Lmittcd: BeforeControl AfterControf Estimite Control (Ib/hr) I (Ib/hr) 

# I Method' 

# I Deyica'• Con trol Emcieney 96 Particuritcs .......... _... _3 - O.L 4 dacnt7uSe Stjirur Dioxida Nitrt,sen Dia:iJc....... --•-- ~ - C.irl»n Munosidc . . . . . . .. _—

_ Hydrvcarbuns (VOC). . . . . _ . . _ Lcad....
~

....... . Otltcr ( Othrr { ) • - -- - — - - I --- 'REFEK 70 4ACK OF GENCRAL 1NFORMATION FORK "A" FOR EMlSS10N ESTIMATION CODE ••ATTACN AIR CONTiiOL DEVICE FORM I.C. 6. T yrc of Sourcc: CNCCK ONE

~ (X ) A GcNCRAL PROCESS - Source not covered by B and C befow. (Camplete items 7, 8, 13 tttrough 22)

D Ge.NERAL PROCE"sS WITh (N-PROCESS FUEL - Sourcr where proQucts of combustfon canvet trt3teriiis heated. (Complete Items 7, S, 9, 13, 14 2 18 througs ZZ) . () C 1=l;EL FlURN1NG 50URC` (boilers, etc.) - Source witere productt ot combtrstfon uo for IJte primuy purpose of produt:ing heat or pow et by i ndirect h ea t t r ansfer. (Complete items9 through 22) 7. Pruccss Operation: (X ) Continuous () Batdt - Norma! 8uch Tints No. Batehet per Diy S. Proccss Namc 

## er?c x Rocxracing equipment Materi,als Enterin; Protess': (include In-process Solid Fuels) 

## A. ._ crusnea ort 

## B. ._.. ~ Max. Re;uested Input Rates (tb/hr) , :'Purnit Input Deiigrt ) Actu a i, • ° Rates (Ib/6r)

c 

## . ......- - - --- -- — o 

## . . .. _ . _- --• --- E. F. • _. _._._.. ----- G. . . - • ---• - ._ ...r. - — TOTAL WEIGHT ENTERING PROCESS J NUT L1ST ANY VOLATILC HYDROCARBONS, USE HYI]ROCARBON EMISSION SOURCES FORM "E"



## ~~~

### Y-20-94 Fn I 14 : 21 KMG ff IiERRLS, [NC, F. 04 

## C~0 

# 0

DATA FOR PROCESSEa ' OR FUEL HURNING SOURCES — corrtlnued ' page 3 Or 3 20. Stack'ar Ern+ission Point Qat;: Heiglsc Abo.e Ground (fs.)I Inside Area (so, ft) I Gas Tempeatzue (De=. F} I Direcsfort or Exit (uR, dovm or harizonta!)

volueretrie FToW Rate Veioeiry (rtajiea) An santpllen pores arasTabiat Is raln ap or ttttter otntruetton orer (/4CFM) ( ) No ( ) Yes stuic? ( ) No ( ) Yes, (specdlS )
!s sciffoldint avaifable for source ttst;ns? 

# ~ Stacfc ID (Vo. — Soureas wiLti 3 common () No () Yes stacfc MsTf hm ttse nm+e srscit rmrnber. 21. Indleste rnonitorinf and recording instniments installed on srieic: () Opacily Monitor () 502 Moniter () NOs 4lonicor () Other 7.2 Attach or sketels a tfow dJagtam ot the proeess or fud burssing rourrr. 1ncJude air eontrvl deviee(s), (SES JNSTRIJCTJCNS ON BACK OF TNtS PAGE):

~ 

## rn i ss+o ~ 

## Souac ~ 

## R F-3

~ ' ~ utcDt• ~c ~ E i.J F}L ~.L~~ ~ F1Ch
~ lEY 

# J= ,R
- cr 1 CLAlA
- TT-1 0I.tSi Col.l.Lc.T1v3 AIaC.T 7 •—

' 

# t y 1pb- -.x"lper—

I DltSi 

### 'b ►s7n5*L. at•] s 

### d14t.t4.r

~ 

### NE Lj C

~ 

### otLtc-'te• 4 J )

~ .'r cartv E.YoQ 

# .::_,.. =y S•

~ commcnb:



# //d

### I41G MINERRLS, INC. P. 04

( 

## ~ ~ -oF


## ~~ .

)R PROCE5SE5 OR FUEL BUANIIYG 50URCE5 —conrinued

' pa5e 3 of 3 

# ~ 20. Slacfc'ar Emissia,! Paine Data: Ne+ghc Abo.e Ground (ft.)I (nside Area (so, ft) I Gu Tetnperiturn (De=. F) I Direetion of E

~ tit (up, dmvn or horizontal)

Volumetric F1ow Rate (ACFM) Velocitr (ttfset.) Ara sztttpilnt ports s aiTsMe? 1s rafn ap or other obstruction awer ( ) No ( ) Yes 

# I seaelcl ( ) No ( ) Yes, (sQecify) is sciPfold;ns avaifable for source trsting? Stick !D No. — Saurcea with s comrrlon ( ) No ( ) Yes stack enli hare the s=me suck rnumbet. 21. Indicale monitorinj 3nd recordinB instrumertts installed on stack: () Opacily Monitor () S02 Monit.or () NOx Monitor () Other 27— Attacfi or tketcft a flow diagrarr of the process or fud buming source. Indude a'u cantrvl derice(s). (SEr iNSTit1JCTi0lVS ON BACK OF TNiS PAGE):

~



### = ! SStetJ SoutZc ~ 

### R F-3 ~ X~~~. a ,~ `,: ~ : t.,i i 

### ~ LL— 

### ~ t EIKO A US'r

~ T1CutJ4-T ~. ~ ~ uS`C' Co1..tf

~ cnv.1 n

~ ac.T 7

s ~ 1111 ~t~ft~NE ~~ CoLL
~ ulea L~ L-T GoNdE`(c ~ . 

### "Wus' b ls7esk.. ata

'3. Commcnts:



## ~~

### Y-20-94 FRI 14:21 KMG MINERALS, INC. P.05

AIR POLLUTION CONTROL DEVICE pag 

### e 1 af 3 LEASE TYPE QR PmNT. ATTACJi Tp GEfVERAIy IIVFORMATIGIV Fi7RJy1 "A". 51JrYt.T GESiGN pATA y SPEGiFICATICNS, AlVO AvAILABLE :NGINEERING DRAwtNGS. - 1. Air Controt Device and 10 Na. (FROM GENERAL INFaRMAT1ON FOItM "A", ITEM 6) 

### Baghous2 

## RF-3-BH-1 • Z, if ti+cre are scYcral de.ices 1n series. Jist each unit in series startin` at the emission saures. (Z) _ (3) TOTALUNITS Ol1e 3. (ndicate Ernission Sourct and 10 No, that Control Device(s) is instal(ed on: 

### Brick Rockface Eguipment RF-3 4. Narrativc Descri0tion of Control Oeiicc(s): 

### Baghous e- `abri c fi 1 ter 

## _.._- -- - •-• ._. 

# M ikropul 

# _ Mi 

# k rooulsaire 64S-$-20 Mar.ufacturcr Model Name Mode! Number , , S. Estimated Cost of Controt Device 

# ~ Period of Time Control Oevice is Estimated co be Adequate: 

## s.2Q.,004--.- •---- 15 Yurs 6. Permit Apvlic»tion is madc ror (C:-tECC ONE ONLY): Q() Ncw Source () Esistin; 4otu

. ca () Modifiation — Last Perrrsit No. Commence Construction Oate ~~ 

### eu`A'Z`{ ( ,1937 

### I Operation Datr 

### j'044r-44 L ,19 

### VL 7. Emission Parsmcten: PART. SOZ NO, t CO VOC LEAD OTHER OTHER PoilUtant(s) COntrolled 9 ) ( ) ( ) ( ) ( ) ( ) Etnis.ion Rate 9erore Control (Ibfltr) _ 3 Emissiort Rate Aftcr Control (Ib(hr) • Remaval Eff;cieney Percent N

_ Particle S;.-c Distribution of Particulatss Enterint Control Devics (: Miaon): 1•lo 10 10•25 

### aQ ' 25-5o 

### ZQ 90-100 

### Z 5 Over 100 , E. Gas Conditiorts at Controi De+ice; 1 3 50Q WTE,ZMEDiATE LOCATIONS 35T O Q LFT Fiow Rate (ACFibt a ..__._ Tcmperature (Deg. F) a _XM5? 

### ent amb

~ 

### „ i 

### ent Vcinciry (ft.Jset.) a 

### Du pressun: Orop (in. H=0) a Maiscure ( e) aG _1 9. Describc Ultirnatc Oisposil of Caitected Matcrials: 

## _. Oispcsal on-site at f 

## a cility solid inarganic inert land f111 area

10. Stack or Ert+issiott Paint Data: FteiRi,t Above inside Area Dirertion oi Exit Are thert obstruetrons av"a stacScT Grnund (rt.) (sa. ft.) (up, down, or harizontal) (() No () Yes; (sped6f 

### 25 1.1 _ uo Is sc3frofJing av:ilibte fur sourccs tcsting? Are sampling poru availabtel ( ) No (X) Yes ( ) No (X) Yes 11. Comrricnls:



### //-
~ 

### zI 1 >IF: cs+T t Posidon In Series # of Uni ts ~ *•+ "MULTiCYCLONE" • y No. of Canes I Prruure Drop (irt. H20) t ~
13. Erriciency (!'e) Volumetric Flow

Rate (ACFM) ,r ~

i' 

### "PY-20-94 FRI 14: MINEnALS, INC. P.06

( 

### 6 cP

~ 

### )

12. Efr icicncy 

### SUPPLEME.YTAL DATA FOR AIR CONTAOL DEyICES

~~ ~~ HFL , pste 2 of 3 ••• LYCLONE (MECANICAL SEPA4TOR5) •+• Vofumetric Fiovr Pn:ssure Orop (in. H20) Baffles or Lou.ars (sperify) Position In Series Rate (ACFiN) # of Unitt Cycfone Dimensiona (indhes) Crdone Body Diameter Cydont Body Height (f't.) Crdone Cone Hei¢st (ft) Tnlet Outlet 

# I (indtes) Wet 9vrnI No, of Nozxles 

# I Liquid Used (speciiy) 

# ~ Ftow Rats (GPM) 

# I Makeup Ra(e (GPM) 

# ~ % Resirwlated ( ) No ( ) Yes A process flow diagram must be attacited if cydone is routed to artother cydone or other equipntettt, show sketch of :ntire system. RCCCtE aticIISn •T C}+ECX lPPRCriZATE tT,.TLZT CCt1r:91J7.LT:0rt B:LCj+ SKETC?t OTHEA cCNf IGURAT2tTN



## ~ Q!f OiAGRA14 ZIVLET _ I 

## ~ AT RZGHT OOof IECIIT 1

Lc+uvers inict Dir..cnsion of (ndividua! Outfet Dimension of individuil Ind'triduil Cydone Intet Tempentute ( ) No ( ) Yes I Cycione (inches) Cyclone (inc.ties) 

# I Diameter (inc.4es) (Oel. F)

14. •+• "FiLTRATiON" (BAGHOUSE) •** 0 Eflicier.cy (%) voiumetric Fiow Filter5urfaee Air-to-FiiterArea Ratio

Rate (ACFM) Ara (sq. ft) (ft.lmin.)



### _ 

## 99 3570 770 

# 1 4.5 acfm/sq. ft, TYPE OF FiLTEit FtLTER MATERIAL ' Q( } Fabric Fiitcr (BAGHOUSE) () FiberOass () Nyfon ( ) Pacicrd Bed ( ) Mat Fiiter ( ) Nomex ( ) Teflon ( ) Pznel Fiiter ( ) Wod ( ) Oacron ( } Other _ ( ) Cotton ( ) Orfon a) Oth e r 

### Da 1 Yes ter No. of ComDartmcntl Time Between CIeanint Iniet Temperaturie 

### one (

~ 

### '2Q sec onds (De

lmbient Pressure Drop (in. H30)
BAG CLF.ANING ( ) Mecfunial ( ) Sonie () Reverse Flow 0( ) Air Pulse ( ) Simpie 8as ( ) Rlnqed Bit Co((apse Caii3pse ( ) Gther Positton 1n Setia # 

### I af
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## ~

### TRIGON ENGINEERING CONSULTANTS, INC.

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### PINE HALL BRICK COMPANY, INC. i°a T LE V APPLICATION GROVER, NC
PROCESS AREA: GRINDING ROOM (FS-1) Ball Clay and Black One (MNO2) are delivered into the grinder building by covered truck from off-site. Grog is transported by enclosed conveyor from storage to the grinder building. The above materials are handled inside the grinder building by front end loader. Material is fed to a scaIper followed by four screens. Material passing through the screens is suitable for further processing. Oversize (tailings) are conveyed to a hammermill and rescreened until correctly sized. The maximum grinding capacity is 100TPH. The CY96 average rate was 22.4 TPH. In 1992 an EPA supervised test was performed on a similar (but lar g er) vented operation at the Pine Hall Madison, NC facility. Emission Factors resulting from that test are used here. Note, however, that the Grover, NC Materials handling and preparation operations are all done in enclosed buildings tfiat have no hoods or exhausts; therefore no emission points. Emissions from the buildings (if any) occur from opening of access doors. A conservative engineering judgment is that no more than five (5) percent of the computed particulates are emitted to atmosphere as fu g itives.

~



## 6'

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### PINE HALL BRICK COMPANY, INC. TITLE V APPLICATION GROVER, NC
PROCESS AREA: RAW MATERIAL STORAGE & BLENDING (FS-2) Granular materials include kaolin clay, sand, marble dust, shale, ball ciay, ore and grog are delivered to the interior of the building. The materials are then weighed in formula proportions onto a conveyor and transported to the pug mill operation in the forming, cutting and stacking area. The operation capacity is limited to the capacity of the pug mill and kiln operation of 65,600 ton/yr. 

### No calculations are necessary to show insignificance for the following: 1. Refer to calculation's of maximum potential theoretical TSP for arinding room. 2. Emission factors are the same. 3. The maximum theoretical through put at grinding is 876,000 TPY with 516 lb/yr TSP. 4. Storage & blending (FS-2) capacity is limited to 65,600 TPY.

s

, V t:b. .4•



# ~~

### PINE HALL BRICK COMPANY, INC. TITLE V APPLICATION GROVER, NC
PROCESS AREA: TRUCK DUMP PIT (FS-3) TO CONVEY KAOLIN TO BLENDING

BUILDING Emissions are insignificant fiigitives by the same rationai as blending building (FS-?).

: y •

•~ ~r s

"~ 

# zs 

### Table 1 Product Tonnages Pine Hall Brick Grover, North CaroIina CY 96 Materials Usage Product Brick No. Produced Tons Produced White (@ 3.28 lbs./SBE) 14,790,152 24,256 Light Gray 2,215,626 3,634 Dark Gray 2,438,460 3,999 Pink 

## 2.764,132 4.533 Total 22,208,370 36,422

~.~ 

### .-, -

. 

### ~~

### Table II Raw Materials by Product CY96 Pine Hall Brick Grover, North Carolina Raw Material 

### ' Total Tons Kaolin Clay %

tons 

### 70

25,484 

### Ball Clay %

tons 

### 13

4,723 

### Black (M n 0 2) %

tons 

### 6.3

2,272 

### P.H. Shale %

tons 

### 5.5

2,017 

### Grog* %

tons 

### 1.8

651 Sand* %



### tons 2



### `728 

### Marble Dust %

tons 

### 1.4

547 % 100 

### Total tons 36,422 *NOTE: Fractions may vary slightly as available grog varies. es ~ eY.s 

### .:

~ 

### .:

1-IzTRIGON EIYGINEERING CONSULTANTS• INC. TRIGON eYGINEFRING CONSULTANTS. INC.

Subjwt 7 Subject Date s a ll.M y Setup 3y
wwk C oMp ,,,,d 13, Work Cmputed By Ch•eked By Ofeked gy •ob Ne I' 73 1 0 -i Z- Pig. No of —ftiM Job NCL Page No Qt

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7 ------ - 42. ::Ll cz- .3772o5= A14 7 - Z
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## ,-i3

### EMISSION FACTOR SOURCES PINE HALL BRICK , INC GROVER, NC

1. TSP=3.38x10" 5 lb/ton, PM10 = 1.6x10" 5 1b/ton: Spreadsheet for stone quarry/gMnite crushing 

### NCDHNR January 1 1997. Vozzo and Pendola. P.3 truck drop---. See appendix. 2. TSP=4.63x10" 6 'tons1ton, PM10=2.19x10 -6 tons/ton: Spreadsheet for stone quarrY/g ranite crushing NCDEHNR January 1 1997. Vozzo and Pendola. P.3 Conveyor drop to pile. See appendix. 3. TSP=0.0117 lbs/ton, PM10=0.0011 lbs/ton: Based on EPA test at Pine Hall Brick in Madison, NC of October 26 through November 7, 1992. See appendix. 4. TSP=0.03 lb/ton, PM10=0.0015 lb/ton: derived from permit application of June 26, 1989 that was based on bag filter test of ldlarch 3, 1989. See appendix 5. Criteria pollutants calculated usin g NCDEHNR central office spreadsheet for natural gas. HCL=0.21 lb/ton, HF=0.85 lb/ton were NCDEHNR mandated.

a

~ x



# '7VFACILITY NAME page 3 o15

FACILITY ID '/_!. 0. - UM1 Conveyor Transfer Points • : w.t Emis Fdr - dry and wet AGTUAL Emis wf wet Inv POTNL Emis - Title V POTNL Emis Amount sopna (Ibslton materiaQ suprsn (TP`f) use wet supm (TPY) (tons per year) Conveyor Transfer Pts o[ Hate 179Em1 ISE E= I;:E P= LSE PmIQ ISE EM1Q Actual Totat - AII Conveyors' : 0.00294 0.001400 0.000 0.000 ERR ERR ERR ERR Dry Irrv. Potential Total (ratio up) : F.RR 0.00010 0.000048 ERR ERR Wat T-5 Potential Total (ratio up) : ERR 'toy corr,eyar ystsfer ponn erouqipus totaMa fram indv. cariveyor trop portnx TiOra v potl is CassA m tatrad wpracty of pYnt at a760 nrs
Other Operations : wet EPA Factors • ACTUAL Emis wl wet Inv POTNL Emis - TiOe V POTNL Emis Amount su;;pres. (Ibslton matrl procd) suprsn (TP`() use wet supm (TPY) (tons per year) (a) Wet Driliing °: ar$attt L71F.tIls1 ISP a]A Lcia E= ISQ E= 129 2u1t] Actual Processed (TPI) 0.5 0.00017 0.00008 0.000 0.000 ERR ERR 0.000 0.000 Rated Capacity (TP-Hr)

- vw1 at6V is sss<rr+W to tw '.ar e+d 7rNors mne+aY6 Atld ro eat<e r:oneoL

. (b) BtasUng - n/a for 1993 Inventory (c) Load In - Load Out : Particulate Emissions from Pft bnd Crusher Feeder Drop Operatlons : (use Truak unloading : fragmented stone: estimate TSP to be 2.114 x PfN-10)

must documeeC fPA Factors • ACTUAL Erns %d ww st-0m Itn PpTNL Erns

- .I v , *t sqm T

- 3 POTENTIAL Ems Ama,t wetsupp pbsiton matrl proed) (TPr) (TPV) (mnspe•ye.r) S!2!A ^J1 P!S fX EMe1 m e= LM 2MI

- Q zM Emia m E= (1) Truck Loading in Pit Actual Tons from pit 

# r_ ~ 0.0000338 0.000016 0.000 0.000 ERR ERR 0.000 0.000 Potential Tons from pit T-5 Potential Tons from pit 0 

### ~ (2) Truck Drop to Crusher/Grizzly Feed + Actual Tons to Feeder O 0.0000338 0.000016 0.000 0.000 ERR ERR 0.000 0.000 Potential Tons to Feeder T-5 Potential Tons to Feeder 0 )oen Storag_e and Haul Roads (see notes) (A) aggregate handling (load in out of piles, acttvity) and storage piles (wind erosion). (1) Load In - Load Out : Particulate Emissfons from Storage Drop Operations : E (tonstton) _ ( (k(0.0032) ((U/5)"1.3) I ((mJ2)"1.4) ) I 2000 Portion (9'o as decimao of total production Default narameters : 

### ~ to washed stone pile : 1.1 : matetiat moisture content (96) (Tab 111.3-1)-m -aeNCreqirasweterspray.useririrange (TfTLE V GtLC aSSUME NO STONE W0.SHED) 0.74 : TSP particle size multiplier (430 um)■ k(Tab.11.2.3-2j (0 3 ao 1.1) 0.35 : PfW.10 particle siZS multiplier (<10 um) a k 7.5 : mean wind speed (mph) a U(Tab 112.3-3) LIM P64 ] 4 TonslDrop Ton : 4.63E-06 2.19E-0i
mastataowxat• TonslOropTon ACTU

~ iLEtASvwuwtstpm MPOTtv1.ErAS-vdretssprn T ~ POTENTtALEers M+ant wet Stpp (per equadon) a x wn seon. (TPr) a x we stone (TP1 ) (tw r>•r y.r}

~ sea aatr; C7!<Fmrs 7

~ SP P

~ e14 ISE 2m14 7

~ P E

~ 7 Q ISP )*6a14 Cor Drop to Pile

ns to Pile ~ 4.63E-06 2.19E-06 0.000 0.000 ERR ERR O.00Q '' 0.000 ons to Pile T. to Pile 0 (2) Drop to Truck from Pile Actual Tons to Pile 4.63E-06 2.19E-06 0.000 0.000 ERR ERR 0.000 0.000 Potential Tons to Pila T-5 Potential Tons to Pile 0 (11) Wind Etosion Factor : E (tonstton) _ (0.0714 'k ' (sl1.5) • (D/90) • (drZ35) • (w415) ) / 2000 Portion (96 as decimaQ of totalroduction DefauR trarameters
- to w ashed stone pile : 1.6 : silf content %= s[Tab 112.3-11 (TITLE V CALC ASsUME No STONE wA.9r+ED) 0.74 : TSP particle size multiplier (<30 um) = k[fab.112.3-2( 0.35 : PM-10 particle size mu@iplier (<10 um) = k 30 : storage pile duration■ D 245 : dry days per year = d(Fg 112.1-1) 22 : time wind (%)
~ 12 mph a w / M PM:14. T....<m..,,. T- e oaaa1aa 6.79E-06

# aUGUST 1993 .:

~ c, •

~ .. ~ ri



# F1NAL TEST REPORT MAIN REPORT FO R 

# USEPA TEST PROGRAM CONDUCTED AT 

# PINE HALL BRICK PLANT MADISOIV, NORTH CAROLINA

USEPA CONTRACT NO. 68-D2-0029 

# EMS WORK ASSIGNMENT 6

~ ~



# ETS CONTRACT N4. 92-655 o'~ 

## 5 ~"~ -

~

### r
TASI.L 3 . 4-1-2 z

RIIN NQH3 ~ IIA2': S?.NZL,ING DATa SII24%RY OP' MET'30D 201: TOTAL FZL't""?Ja= PARTICDI.AT°. AND P.si. ta : GRI.*JDIRG—SQREII'lZNG BGILDIaTG
DI-4tZ01—itl Dl-4001—R3 AV'ERAGE 

### 10/27/92 10/28/92 10/28/92

lietered Voluate - cf 62.641 51.108 52.638 55.462 Total Tsst Time - mia 240 180 I80 200 i Isckiset:a 98.8 98.4 98.2 98.5
aiS _ PAP

- A2J

- %

- ""'ZRS 

### Gas Temperatur8 - oF 72 61 69 67 Ozygea -% 20.9 20.9 20.9 20.9 Cartoa Dioxide -• 0.0 0.0 0.0 0.0 Hoistu: e 1.0 1.0 1.0 1.0
GAS FLOWRAT3 

### Ve3ocity - ft/sec 31.13 33.64 34.87 33.21 Ac':sal Volume - acft : 23471 26163 27119 25585 Staadard Volume - dsc:!:= 22709 25891 26414 25005
TOT?iI. PII,T ✓

'RABZc PARTIC'JI,AT? ZdISSIONS 

### Coaceat=atioa - gr/dscf 0.01166 0.00777 0.01284 0.01076 r3ass Rate - Ib/hr 2.270 1.724 2.907 2.300 '
TOTAL P

~ 1 

### BMISSIONS Caaca.at=atioa - gr/dsc: 0.00094 0.00077 0.00072 0.00081 Mass Ra.te - Ib/hr 0.183 0.171 0.163 0.172

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### 5c--eeniag buildiag.

See Aapeadix P.3.1 for detailed field sampliag iaformatica. A duct sire of 48.0 iaches was u.eed ia calculatiag flowrat8s. This iafor.aatioa was gathered from ETS, Inc. files pert a9*+in 

### g to the duc= workt



### ~~

### FACII.TIY ID NO. 2300115 PERMIT NO. 6156R3

S OLZtCE ID NO. 2 A BAG FILTER ( ID NO. 2; 770 F"I'2 CLOTH AREA) INSTALLED ON ROCICF ACING OPERATION. E:1

~ 

### IISSION SOURCE REFfiREiNCE: BAG HOUSE TEST : 3-1-89 - 99 % EFFICIE<VCY P.4RTICULATES : 0.2 # / HR PM10 .=5% BRICK ROCKFACED 1996 : 4 1 800,000 

## MAXZWUM PRODUCTION RATE: 11,088 BRICK / HR NORMAL PRODUCTION RATE 1996: 4 2 000 BRICK / HR HOLRS OPERATED: 4,800,000 BRICK / 4 7 000 BRICK / HR = 1200 HRS EvIIS SIONS : 1996

_ 'FSP: 1200 HRS ( 0.2 #/ HR )/ 2000 r'r/ TON = 0.12 TONS PM 10 : 0.12 TONS ( 0.05 )= 0.006 TONS


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## Stafie of Nortfi Carolina Deparfiment of Environment, Hec7ith and Natural Resourcas Mooresville Regional Officn Jomes B. Hunt, Jr., Govemor Jonathcn B. Hawes, SecretQry 

# 0EHHNFZ DIVISION OF AIR QUALTTY June 17, 1997 Mr. Harold Newmaa Pine Hall Brick Company, Inc. Post Office Box 836 lbtadison, North Caroiina 27025-0836 Subject HF E mLsioTM+



### Factor Grover, Nortfi Caroljna CIeveland Coumty 031Zi/00115 

### Air Permit No. 06156iZ03 Dear i1&. Newtnan: Ia response to your lette; dated Tune 11, 1997, concemin.g the F-znisssion Faztor for HF emissions from the abave fac+lity, a;cacls test or a$uorine coatent test oa the clay aQtd/or shale at th.is pIarrt must be performed aad resuIts submitted withia 60 days of receipt of this Ietter. If Piae HaI1 Brick Coaipaay, Inc. decides to permna a stack test, a pratocol shaIl be submitted to the Division of Air Qualitp. Once the testing protocol has beea agnroved, it is mzquested that tlie Compauy advise this Office of the test dste so tfrat a member of the ofn

- ce sta$'may observe the test Please be advised that in order tn avoid a vioMoa of North Caroliaa Administradve Code Title 15A 2Q .0501, Pine HaII Bsick Compauy, Inc. must submit a?itle V applicarioa to this office before the faciIity exceeds the TitIe V thresholds of I00 tons per year of PM10, CO 3 NOx, S02 or VOC; 10 toas per year of eacfi individuaI hazardous air pollutaat ('m t}zi.s case, W; or 26 tons per year of all bazardous air pollutauts combmed The toas per yesr liaut tvok effect December 15, 1996; tberefore; Piae HaIl Bricic Company, Ine: shouId submit a Trtle V application before the facility exceects the T' rtle V tiueshoId limits for the 12 moath period beghliag December I5, 1996. Tbis testing should be completed as soon a.s poss

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### ble to easure the fadIiry does aot exc

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### d this Iimit If you have suy quesbons with reference to this matter, please do not hesztate to: contact iNfs. Denise Humphries or me at (704) 663-1699.

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# c i i PINE HALL 3RIC:C CO.. INC. Lincsav 8nc;s ?oaa Pcst ^'Sce aox 936 :tac:son. Norm Carotina Z7 OZ-C836 :aiecror.e =:x d

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### Mr. Nfichael S. Landis DEI-LN1R Division of Air Quality 919 North Main Street Mooresville , N. C. 28115 Subject: HF Emissions Pine Hail Brick Co. Inc. C1eveIand County, North Carolina Air Permit No. 06156R03 Faciiiry ID No. 2300115 Dear. Nlr. Landis, June 11, 1997

The DEH

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### i R me:no dated April 30, 1997 states that if data is not available on the actual HF emissions from a particular brick plant, a factor of 0.85 ton of &red product must be used in preparation of the 1996 Emissiori Inventory. This raises a major concern for the Cleveland County facility. A comparison of the inventory reported for 1993 with the current report due by June 30, 1997 utilirin; the 0. 85 r'r/ ton of hred product is shown below. Please be advised that the number used in the 1993 inventory was based on an EPA sanctioned test performed at a similar brick faciliry in Madison, N. C.. This test work was under USEPA Contract No. -1 

### 68-D2-0029 dated Au;ust 1993. Please note this 1993 inventory was submitted and 

## approved. 1993 1996 Tons of Product 42,272 39,975 

## Produced -

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### HF Emission 0.216 0.85 Factor : # / Ton HF Emission 4.6 Tons 17 Tons 

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### As you can see the utilization of the mandated HF factor of 0.35 4 per fired ton zreatly

effects the status of this plant as far as being a Title V faciIity. Even thou

- gh our production has decreased some 5% in 1996 the HF emission will be increased by 269 %. We will have to report the his ,,h factor in the 1996 inventory even though we question the accuracy of this number. Please advice us as to what steps we need to take to get an accurate number that wiil be acceptable to the state. Thank you for your valued guidance and assistance in this matter.

Sincerely,

Harold B. Newman Nia.nager of Technical Services Ceramic Engineer CC: Denise F. Humphries

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### May. 29, 1997



## Mr. Pete Ciesiak Executive Director 9rick Association of the Carolinas P. O. 8ox 13290 

### Greensboro, NC 27415-3290 

## Re: Hydrogen Chioride Reporting Requirements For OEHNR Dear Pete: In response to the Pcaduction Committee meeting in Sanford yesterday, I have reviewed Ilterature informatfon and Center data pertinent to hydrogen chioride emissions in brfc a ~ 

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## cturing. The purpose of this letter is to expiain the origin of the emissions a d to prov
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## e our memoers with an altemative to using the draft AP
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## 2 errtission factor of 0.21 ib.! on as required by DEHNR in. the absence of other data. The fact t4t# re are chicride emissions in firing has been known for some years. De Jonge s s that "chlorides are reieased in flring of sedimentary clay from the sea bed" (Ziegelindustrie, 10/86). In the ki(n draft, the gasecus chloride species undergoes hydroiysis formirrg HCI. Soiid fueis can contribute to chiorfde .emissions, and the emisaion facter for the fuel should be added to that for the raw materfal. Arnison presented data on British brick kilns where the practice is to add carban to the
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## bod}r, and emission factors may be estimated as simiiar to the Belden number (Ceramic Industry; 3I92). Unfonunately, there was no cfiioride data in .the Triangte test. It is clear that fired bric,ic contain chloride since we are familiar with

- some cases of effforescence related to chloride and water leaching of fired brick can remove chioride. So nat all chtoride is released 'on firing. It is further ciear that a masa batance should reveal the site specific amount of chioride reieased on firing. The oniy way to do this is to obtain a partial chemicai analysis for ch(oride of both' dried and fired products and perform- the mass balance calculation. The data for the dried'product must be converted to a"fired weight basis" by dividing the chloride number in the dried brfck by the factor (1 - fractional foss on ignition). Any credibie laboratory doing traditional wet chemistry can do this. I use Spectrochemical Labs in Piitsburgh (contact Tom Futton at 412-371-Z345).



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## Mr. Pete Cieslak Page 2
The emissiort faetor in the draft AP-42 documerct camo from the EPA test at 

## Belden. There is no HCL data in the test reports for Pine Hall or General Shale. The Belden numlber of 0.18 lb.lton was apparently rounded upward to 0.21 Iblton for EPA's own reasons. In a draft EPA test report, an analysis ot the Louisville bricic showed mone ctrlorida in the fired bricic than the dried brick. t beiieve that it is possible that some North Carolina plants toward the Central or Westem part of the state cauld find an emission factor on the order - of 0.1 fblton. Whether it is worth looking into or whether It is cheaper to pay an emissions levy is up to your individual members. 

## I hope that this information is helpful, and we remain avaiiabfe to assist as necessary. , 

## 'th bestregard ,- i

, .

, 

## Denis A. Brosnan; Ph.D, PE Professor and Diractor 

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