### 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 

# Order Summary Report

Analytical Laboratory

Order Number: J11010101 Project Name: WWTS - Biweekly

Lab Contact: Jason C Perkins


### Date: 2/14/2011 Customer Address: 3195 Pine Hall Rd Customer Name(s): Bill Kennedy, Melonie Martin, Wayne Chapman, Tom Johnson

Mailcode: Belews Steam Station Belews Creek, NC 28012

Phone: 980-875-5348
Report Authorized By: (Signature)



### Program Comments: FGD - Biweekly (1/17)
Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with an "X" or "1" indicate a deviation from the method quali ty system or quality control requirement. All results ar e reported on a dry weight basis unless otherwise noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimatio n of the uncertainty of measurement for the re sults in the report is available upon requ est. This report shall not be reproduced, ex cept in full, without the written consent of the Analytical Laborator y. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Labor atory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laborator y Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification: The Analytical Laboratory holds the following State Certificati ons : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laborator y for definitive information about the certification status of specific methods.

## Sample ID's & Descriptions:
Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2011000396 BELEWS 17-Jan-11 1:05 AM ILLEGIBLE FGD Purge Eff 2011000397 BELEWS 17-Jan-11 1:09 AM ILLEGIBLE EQ TANK EFF. 2011000398 BELEWS 17-Jan-11 1:13 AM ILLEGIBLE BIOREACTOR 1 INF. 2011000399 BELEWS 17-Jan-11 1:17 AM ILLEGIBLE BIOREACTOR 2 INF. 2011000400 BELEWS 17-Jan-11 1:20 AM ILLEGIBLE BIOREACTOR 2 EFF. 2011000401 BELEWS 17-Jan-11 Trip Blank 2011000402 BELEWS 17-Jan-11 FILTER BLANK 7 Total Samples

### COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. The Vendor Laboratories have been qualified by the Analytical Laboratory Yes No 

# Technical Validation Review Checklist:

Yes No

Yes No



## Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Test Case Narratives Analytical Laboratory QC Report Chain of Custody

Reviewed By: 

### Jenny A Herman Date: 

### 2/14/2011 Yes

Electronic Data Deliverable (EDD) Sent Separately

# Certificate of Laboratory Analysis This re p ort shall not be re p roduced, exce p t in full. 

## Order # J11010101

2011000396 Collection Date: 17-Jan-11 1:05 AM 

### Site: FGD Purge Eff Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 235 ug/L EPA 245.1 20-Jan-11 14:45 5 TLINN
TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 160 mg/L EPA 200.7 21-Jan-11 10:23 0.05 DJSULL1 Barium (Ba) 1.82 mg/L EPA 200.7 21-Jan-11 10:23 0.05 DJSULL1 Beryllium (Be) < 0.05 mg/L EPA 200.7 21-Jan-11 10:23 0.05 DJSULL1 Boron (B) 179 mg/L EPA 200.7 21-Jan-11 10:23 0.5 DJSULL1 Calcium (Ca) 4090 mg/L EPA 200.7 21-Jan-11 10:23 0.1 DJSULL1 Cobalt (Co) 0.181 mg/L EPA 200.7 21-Jan-11 10:23 0.05 DJSULL1 Iron (Fe) 116 mg/L EPA 200.7 21-Jan-11 10:23 0.1 DJSULL1 Magnesium (Mg) 687 mg/L EPA 200.7 21-Jan-11 10:23 0.05 DJSULL1 Manganese (Mn) 6.42 mg/L EPA 200.7 21-Jan-11 10:23 0.05 DJSULL1 Molybdenum (Mo) 0.102 mg/L EPA 200.7 21-Jan-11 10:23 0.05 DJSULL1 Sodium (Na) 43.3 mg/L EPA 200.7 21-Jan-11 10:23 0.5 DJSULL1 Tin (Sn) < 0.5 mg/L EPA 200.7 21-Jan-11 10:23 0.5 DJSULL1 Titanium (Ti) 5.30 mg/L EPA 200.7 21-Jan-11 10:23 0.05 DJSULL1
DISSOLVED METALS BY ICP-MS Selenium (Se) 204 ug/L EPA 200.8 03-Feb-11 13:36 10 KRICHAR
TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 100 ug/L EPA 200.8 09-Feb-11 11:48 100 KRICHAR Arsenic (As) 423 ug/L EPA 200.8 09-Feb-11 11:48 100 KRICHAR Cadmium (Cd) < 100 ug/L EPA 200.8 09-Feb-11 11:48 100 KRICHAR Chromium (Cr) 351 ug/L EPA 200.8 09-Feb-11 11:48 100 KRICHAR Copper (Cu) 264 ug/L EPA 200.8 09-Feb-11 11:48 100 KRICHAR Lead (Pb) 391 ug/L EPA 200.8 09-Feb-11 11:48 100 KRICHAR Nickel (Ni) 278 ug/L EPA 200.8 09-Feb-11 11:48 100 KRICHAR Selenium (Se) 9300 ug/L EPA 200.8 09-Feb-11 11:48 1000 KRICHAR Silver (Ag) < 100 ug/L EPA 200.8 09-Feb-11 11:48 100 KRICHAR Thallium (Tl) < 100 ug/L EPA 200.8 09-Feb-11 11:48 100 KRICHAR Vanadium (V) 586 ug/L EPA 200.8 09-Feb-11 11:48 100 KRICHAR Zinc (Zn) 494 ug/L EPA 200.8 09-Feb-11 11:48 200 KRICHAR
SELENIUM SPECIATION Vendor Parameter Complete V_AS&C
TOTAL DISSOLVED SOLIDS Vendor Parameter Complete V_PRISM

# Certificate of Laboratory Analysis This re p ort shall not be re p roduced, exce p t in full. 

## Order # J11010101

2011000397 Collection Date: 17-Jan-11 1:09 AM 

### Site: EQ TANK EFF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 179 ug/L EPA 245.1 20-Jan-11 14:48 2.5 TLINN
TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 156 mg/L EPA 200.7 21-Jan-11 10:27 0.05 DJSULL1 Barium (Ba) 1.75 mg/L EPA 200.7 21-Jan-11 10:27 0.05 DJSULL1 Beryllium (Be) < 0.05 mg/L EPA 200.7 21-Jan-11 10:27 0.05 DJSULL1 Boron (B) 190 mg/L EPA 200.7 21-Jan-11 10:27 0.5 DJSULL1 Calcium (Ca) 4100 mg/L EPA 200.7 21-Jan-11 10:27 0.1 DJSULL1 Cobalt (Co) 0.178 mg/L EPA 200.7 21-Jan-11 10:27 0.05 DJSULL1 Iron (Fe) 109 mg/L EPA 200.7 21-Jan-11 10:27 0.1 DJSULL1 Magnesium (Mg) 709 mg/L EPA 200.7 21-Jan-11 10:27 0.05 DJSULL1 Manganese (Mn) 6.52 mg/L EPA 200.7 21-Jan-11 10:27 0.05 DJSULL1 Molybdenum (Mo) 0.077 mg/L EPA 200.7 21-Jan-11 10:27 0.05 DJSULL1 Sodium (Na) 45.1 mg/L EPA 200.7 21-Jan-11 10:27 0.5 DJSULL1 Tin (Sn) < 0.5 mg/L EPA 200.7 21-Jan-11 10:27 0.5 DJSULL1 Titanium (Ti) 5.10 mg/L EPA 200.7 21-Jan-11 10:27 0.05 DJSULL1
DISSOLVED METALS BY ICP-MS Selenium (Se) 145 ug/L EPA 200.8 03-Feb-11 13:40 10 KRICHAR
TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 100 ug/L EPA 200.8 09-Feb-11 11:43 100 KRICHAR Arsenic (As) 326 ug/L EPA 200.8 09-Feb-11 11:43 100 KRICHAR Cadmium (Cd) < 100 ug/L EPA 200.8 09-Feb-11 11:43 100 KRICHAR Chromium (Cr) 278 ug/L EPA 200.8 09-Feb-11 11:43 100 KRICHAR Copper (Cu) 321 ug/L EPA 200.8 09-Feb-11 11:43 100 KRICHAR Lead (Pb) 305 ug/L EPA 200.8 09-Feb-11 11:43 100 KRICHAR Nickel (Ni) 345 ug/L EPA 200.8 09-Feb-11 11:43 100 KRICHAR Selenium (Se) 7930 ug/L EPA 200.8 09-Feb-11 11:43 1000 KRICHAR Silver (Ag) < 100 ug/L EPA 200.8 09-Feb-11 11:43 100 KRICHAR Thallium (Tl) < 100 ug/L EPA 200.8 09-Feb-11 11:43 100 KRICHAR Vanadium (V) 468 ug/L EPA 200.8 09-Feb-11 11:43 100 KRICHAR Zinc (Zn) 614 ug/L EPA 200.8 09-Feb-11 11:43 200 KRICHAR 

### 2011000398 Collection Date: 17-Jan-11 1:13 AM 

### Site: BIOREACTOR 1 INF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 1.25 mg/L EPA 200.7 21-Jan-11 10:31 0.05 DJSULL1 Barium (Ba) 0.432 mg/L EPA 200.7 21-Jan-11 10:31 0.05 DJSULL1 Beryllium (Be) < 0.05 mg/L EPA 200.7 21-Jan-11 10:31 0.05 DJSULL1

# Certificate of Laboratory Analysis This re p ort shall not be re p roduced, exce p t in full. 

## Order # J11010101

2011000398 Collection Date: 17-Jan-11 1:13 AM 

### Site: BIOREACTOR 1 INF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst TOTAL RECOVERABLE METALS BY ICP Boron (B) 184 mg/L EPA 200.7 21-Jan-11 10:31 0.5 DJSULL1 Calcium (Ca) 3700 mg/L EPA 200.7 21-Jan-11 10:31 0.1 DJSULL1 Cobalt (Co) < 0.05 mg/L EPA 200.7 21-Jan-11 10:31 0.05 DJSULL1 Iron (Fe) < 0.1 mg/L EPA 200.7 21-Jan-11 10:31 0.1 DJSULL1 Magnesium (Mg) 663 mg/L EPA 200.7 21-Jan-11 10:31 0.05 DJSULL1 Manganese (Mn) 2.70 mg/L EPA 200.7 21-Jan-11 10:31 0.05 DJSULL1 Molybdenum (Mo) < 0.05 mg/L EPA 200.7 21-Jan-11 10:31 0.05 DJSULL1 Sodium (Na) 42.9 mg/L EPA 200.7 21-Jan-11 10:31 0.5 DJSULL1 Tin (Sn) < 0.5 mg/L EPA 200.7 21-Jan-11 10:31 0.5 DJSULL1 Titanium (Ti) < 0.05 mg/L EPA 200.7 21-Jan-11 10:31 0.05 DJSULL1
DISSOLVED METALS BY ICP-MS Selenium (Se) 85.6 ug/L EPA 200.8 03-Feb-11 13:43 10 KRICHAR
TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 100 ug/L EPA 200.8 09-Feb-11 11:28 100 KRICHAR Arsenic (As) < 100 ug/L EPA 200.8 09-Feb-11 11:28 100 KRICHAR Cadmium (Cd) < 100 ug/L EPA 200.8 09-Feb-11 11:28 100 KRICHAR Chromium (Cr) < 100 ug/L EPA 200.8 09-Feb-11 11:28 100 KRICHAR Copper (Cu) < 100 ug/L EPA 200.8 09-Feb-11 11:28 100 KRICHAR Lead (Pb) < 100 ug/L EPA 200.8 09-Feb-11 11:28 100 KRICHAR Nickel (Ni) < 100 ug/L EPA 200.8 09-Feb-11 11:28 100 KRICHAR Selenium (Se) < 100 ug/L EPA 200.8 09-Feb-11 11:28 100 KRICHAR Silver (Ag) < 100 ug/L EPA 200.8 09-Feb-11 11:28 100 KRICHAR Thallium (Tl) < 100 ug/L EPA 200.8 09-Feb-11 11:28 100 KRICHAR Vanadium (V) < 100 ug/L EPA 200.8 09-Feb-11 11:28 100 KRICHAR Zinc (Zn) < 200 ug/L EPA 200.8 09-Feb-11 11:28 200 KRICHAR
SELENIUM SPECIATION Vendor Parameter Complete V_AS&C 

### 2011000399 Collection Date: 17-Jan-11 1:17 AM 

### Site: BIOREACTOR 2 INF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 1.29 mg/L EPA 200.7 21-Jan-11 10:35 0.05 DJSULL1 Barium (Ba) 0.459 mg/L EPA 200.7 21-Jan-11 10:35 0.05 DJSULL1 Beryllium (Be) < 0.05 mg/L EPA 200.7 21-Jan-11 10:35 0.05 DJSULL1 Boron (B) 184 mg/L EPA 200.7 21-Jan-11 10:35 0.5 DJSULL1 Calcium (Ca) 3780 mg/L EPA 200.7 21-Jan-11 10:35 0.1 DJSULL1 Cobalt (Co) < 0.05 mg/L EPA 200.7 21-Jan-11 10:35 0.05 DJSULL1

# Certificate of Laboratory Analysis This re p ort shall not be re p roduced, exce p t in full. 

## Order # J11010101

2011000399 Collection Date: 17-Jan-11 1:17 AM 

### Site: BIOREACTOR 2 INF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst TOTAL RECOVERABLE METALS BY ICP Iron (Fe) 0.385 mg/L EPA 200.7 21-Jan-11 10:35 0.1 DJSULL1 Magnesium (Mg) 693 mg/L EPA 200.7 21-Jan-11 10:35 0.05 DJSULL1 Manganese (Mn) 2.82 mg/L EPA 200.7 21-Jan-11 10:35 0.05 DJSULL1 Molybdenum (Mo) < 0.05 mg/L EPA 200.7 21-Jan-11 10:35 0.05 DJSULL1 Sodium (Na) 44.2 mg/L EPA 200.7 21-Jan-11 10:35 0.5 DJSULL1 Tin (Sn) < 0.5 mg/L EPA 200.7 21-Jan-11 10:35 0.5 DJSULL1 Titanium (Ti) < 0.05 mg/L EPA 200.7 21-Jan-11 10:35 0.05 DJSULL1
TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 100 ug/L EPA 200.8 09-Feb-11 11:22 100 KRICHAR Arsenic (As) < 100 ug/L EPA 200.8 09-Feb-11 11:22 100 KRICHAR Cadmium (Cd) < 100 ug/L EPA 200.8 09-Feb-11 11:22 100 KRICHAR Chromium (Cr) < 100 ug/L EPA 200.8 09-Feb-11 11:22 100 KRICHAR Copper (Cu) < 100 ug/L EPA 200.8 09-Feb-11 11:22 100 KRICHAR Lead (Pb) < 100 ug/L EPA 200.8 09-Feb-11 11:22 100 KRICHAR Nickel (Ni) < 100 ug/L EPA 200.8 09-Feb-11 11:22 100 KRICHAR Selenium (Se) < 100 ug/L EPA 200.8 09-Feb-11 11:22 100 KRICHAR Silver (Ag) < 100 ug/L EPA 200.8 09-Feb-11 11:22 100 KRICHAR Thallium (Tl) < 100 ug/L EPA 200.8 09-Feb-11 11:22 100 KRICHAR Vanadium (V) < 100 ug/L EPA 200.8 09-Feb-11 11:22 100 KRICHAR Zinc (Zn) < 200 ug/L EPA 200.8 09-Feb-11 11:22 200 KRICHAR 

### 2011000400 Collection Date: 17-Jan-11 1:20 AM 

### Site: BIOREACTOR 2 EFF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 1 ug/L EPA 245.1 20-Jan-11 14:50 1 TLINN
TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 1.29 mg/L EPA 200.7 21-Jan-11 10:39 0.05 DJSULL1 Barium (Ba) 0.436 mg/L EPA 200.7 21-Jan-11 10:39 0.05 DJSULL1 Beryllium (Be) < 0.05 mg/L EPA 200.7 21-Jan-11 10:39 0.05 DJSULL1 Boron (B) 173 mg/L EPA 200.7 21-Jan-11 10:39 0.5 DJSULL1 Calcium (Ca) 3720 mg/L EPA 200.7 21-Jan-11 10:39 0.1 DJSULL1 Cobalt (Co) < 0.05 mg/L EPA 200.7 21-Jan-11 10:39 0.05 DJSULL1 Iron (Fe) 0.141 mg/L EPA 200.7 21-Jan-11 10:39 0.1 DJSULL1 Magnesium (Mg) 693 mg/L EPA 200.7 21-Jan-11 10:39 0.05 DJSULL1 Manganese (Mn) 2.63 mg/L EPA 200.7 21-Jan-11 10:39 0.05 DJSULL1 Molybdenum (Mo) < 0.05 mg/L EPA 200.7 21-Jan-11 10:39 0.05 DJSULL1 Sodium (Na) 43.9 mg/L EPA 200.7 21-Jan-11 10:39 0.5 DJSULL1

# Certificate of Laboratory Analysis This re p ort shall not be re p roduced, exce p t in full. 

## Order # J11010101

2011000400 Collection Date: 17-Jan-11 1:20 AM 

### Site: BIOREACTOR 2 EFF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst TOTAL RECOVERABLE METALS BY ICP Tin (Sn) < 0.5 mg/L EPA 200.7 21-Jan-11 10:39 0.5 DJSULL1 Titanium (Ti) < 0.05 mg/L EPA 200.7 21-Jan-11 10:39 0.05 DJSULL1
TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 25 ug/L EPA 200.8 09-Feb-11 11:17 25 KRICHAR Arsenic (As) < 25 ug/L EPA 200.8 09-Feb-11 11:17 25 KRICHAR Cadmium (Cd) < 25 ug/L EPA 200.8 09-Feb-11 11:17 25 KRICHAR Chromium (Cr) < 25 ug/L EPA 200.8 09-Feb-11 11:17 25 KRICHAR Copper (Cu) < 25 ug/L EPA 200.8 09-Feb-11 11:17 25 KRICHAR Lead (Pb) < 25 ug/L EPA 200.8 09-Feb-11 11:17 25 KRICHAR Nickel (Ni) < 25 ug/L EPA 200.8 09-Feb-11 11:17 25 KRICHAR Selenium (Se) < 25 ug/L EPA 200.8 09-Feb-11 11:17 25 KRICHAR Silver (Ag) < 25 ug/L EPA 200.8 09-Feb-11 11:17 25 KRICHAR Thallium (Tl) < 25 ug/L EPA 200.8 09-Feb-11 11:17 25 KRICHAR Vanadium (V) < 25 ug/L EPA 200.8 09-Feb-11 11:17 25 KRICHAR Zinc (Zn) < 50 ug/L EPA 200.8 09-Feb-11 11:17 50 KRICHAR
SELENIUM SPECIATION Vendor Parameter Complete V_AS&C 

### 2011000401 Collection Date: 17-Jan-11 

### Site: Trip Blank Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) < 0.005 mg/L EPA 200.7 21-Jan-11 10:03 0.005 DJSULL1 Barium (Ba) < 0.005 mg/L EPA 200.7 21-Jan-11 10:03 0.005 DJSULL1 Beryllium (Be) < 0.005 mg/L EPA 200.7 21-Jan-11 10:03 0.005 DJSULL1 Boron (B) < 0.05 mg/L EPA 200.7 21-Jan-11 10:03 0.05 DJSULL1 Calcium (Ca) 0.019 mg/L EPA 200.7 21-Jan-11 10:03 1 0.01 DJSULL1 Cobalt (Co) < 0.005 mg/L EPA 200.7 21-Jan-11 10:03 0.005 DJSULL1 Iron (Fe) < 0.01 mg/L EPA 200.7 21-Jan-11 10:03 0.01 DJSULL1 Magnesium (Mg) < 0.005 mg/L EPA 200.7 21-Jan-11 10:03 0.005 DJSULL1 Manganese (Mn) < 0.005 mg/L EPA 200.7 21-Jan-11 10:03 0.005 DJSULL1 Molybdenum (Mo) < 0.005 mg/L EPA 200.7 21-Jan-11 10:03 0.005 DJSULL1 Sodium (Na) < 0.05 mg/L EPA 200.7 21-Jan-11 10:03 0.05 DJSULL1 Tin (Sn) < 0.05 mg/L EPA 200.7 21-Jan-11 10:03 0.05 DJSULL1 Titanium (Ti) < 0.005 mg/L EPA 200.7 21-Jan-11 10:03 0.005 DJSULL1
TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L EPA 200.8 09-Feb-11 11:12 1 KRICHAR Arsenic (As) < 1 ug/L EPA 200.8 09-Feb-11 11:12 1 KRICHAR

# Certificate of Laboratory Analysis This re p ort shall not be re p roduced, exce p t in full. 

## Order # J11010101

2011000401 Collection Date: 17-Jan-11 

### Site: Trip Blank Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst TOTAL RECOVERABLE METALS BY ICP-MS Cadmium (Cd) < 1 ug/L EPA 200.8 09-Feb-11 11:12 1 KRICHAR Chromium (Cr) < 1 ug/L EPA 200.8 09-Feb-11 11:12 1 KRICHAR Copper (Cu) < 1 ug/L EPA 200.8 09-Feb-11 11:12 1 KRICHAR Lead (Pb) < 1 ug/L EPA 200.8 09-Feb-11 11:12 1 KRICHAR Nickel (Ni) < 1 ug/L EPA 200.8 09-Feb-11 11:12 1 KRICHAR Selenium (Se) < 1 ug/L EPA 200.8 09-Feb-11 11:12 1 KRICHAR Silver (Ag) < 1 ug/L EPA 200.8 09-Feb-11 11:12 1 KRICHAR Thallium (Tl) < 1 ug/L EPA 200.8 09-Feb-11 11:12 1 KRICHAR Vanadium (V) < 1 ug/L EPA 200.8 09-Feb-11 11:12 1 KRICHAR Zinc (Zn) < 2 ug/L EPA 200.8 09-Feb-11 11:12 2 KRICHAR
SELENIUM SPECIATION Vendor Parameter Complete V_AS&C 

### 2011000402 Collection Date: 17-Jan-11 

### Site: FILTER BLANK Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst DISSOLVED METALS BY ICP-MS Selenium (Se) < 2 ug/L EPA 200.8 03-Feb-11 13:46 2 KRICHAR

# January 28, 2011 Jay Perkins Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078 (704) 875-5245 Project: Belews – FGD WWTS (2010, Bi-Weekly Sampling) (LIMS # J11010101)

Dear Mr. Perkins, Attached is the report associat ed with four (4) aqueous sa mples submitted for selenium speciation analysis on January 20, 2011. Th e samples were received on January 21, 2011 in a sealed cooler at -0.1 o 

# C. Selenium speciation analysis was performed via ion chromatography inductively coupled plasma dynamic reaction cell mass spectrometry (IC-ICP-DRC-MS). Any analytical issues asso ciated with the analysis are addressed in the following report. If you have any questions, please feel fr ee to contact me at your convenience.

Sincerely,

Russell Gerads Vice President Applied Speciation and Consulting, LLC

# Applied Speciation and Consulting, LLC Report prepared for: Jay Perkins Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078

Project: Belews – FGD WWTS (2010, Bi-Weekly Sampling) (LIMS # J11010101)

January 28, 2011

1. Sample Reception Four (4) aqueous samples in 125mL HDPE bottles (provided by Applied Speciation and Consulting) were submitted for selenium speciation analysis on January 20, 2011. The samples were received on January 21, 2011 in a sealed container at -0.1 o 

# C. The samples were received in a lamina r flow clean hood void of trace metals contamination and ultra-violet radiat ion. Upon reception, the samples were designated discrete sample identifiers. An aliquot of each sample was filtered (0.45μm) and these filtrates were stored in a secure, monitored cryofreezer (maintained at a temperature of -80 o 

# C) until selenium speciat ion analysis could be performed via ion chromatography inductive ly coupled plasma dynamic reaction cell mass spectrometry (IC-ICP-DRC-MS).

2. Sample Preparation All sample preparation is performed in laminar flow clean hoods known to be free from trace metals contamination. All a pplied water for dilutions and sample preservatives are monitored for contamina tion to account for any biases associated with the sample results. Selenium Speciation Analysis by IC-ICP-DRC-MS Prior to analysis , an aliquot of each sample was filtered with a syringe filt er (0.45μm) and inject ed directly into a sealed autosampler vial. No further sa mple preparation was performed as any chemical alteration of the samples may shift the equilibrium of the system resulting in changes in speciation ratios.

# 3. Sample Analysis All sample analysis is precluded by a minimum of a five-poi nt calibration curve spanning the entire concentrati on range of interest. Calibration curves are performed at the beginning of each analytical day. All calibration curves, associated with each species of interest, are sta ndardized by linear regression re sulting in a response factor. All sample results are instrument blank corrected to account for any operational biases associated with the analytical platform. Prior to sample analysis, all calibration curves are ve rified using second source standards which are identified as initial calibration verification standards (ICV). Ongoing instrument performance is iden tified by the analysis of continuing calibration verification standards (CCV) and continuing calibration blanks (CCB) at a minimal interval of every ten analytical runs. Selenium Speciation Anal ysis by IC-ICP-DRC-MS All samples for selenium speciation analysis were analyzed by ion chromatography inductively coupled plasma dynamic reaction cell mass spectrometry (IC-ICP-DRC-MS) on January 24, 2010. An aliquot of each sample is injected onto an anion exchange column and mobilized by a basic (pH > 7) gradient. The eluting selenium species are then introduced into a radio frequency (RF) plasma where energy- transfer processes cause desolvation, atomization, and ionization. The ions are extracted from the plasma through a differentially-pumped vacuum interface and travel through a pressurized chamber (DRC) containing a specific reactive gas whic h preferentially reacts with interfering ions of the same target mass to charge ratios (m/z). A solid-state detector detects ions transmitted through the mass analyzer and the resulting current is processed by a data handling system. Retention times for each eluting species are compared to known standards for species identification.
4. Analytical Issues The overall analyses went very well and no analytical issues were encountered. All quality control parameters associated with these samples were within acceptance limits.
The estimated method detection limits (eMDLs) for selen ite, selenate, and selenocyanate are generated from replicate analyses of the lowest standard in the calibration curve. Not all selenium speci es are present in preparation blanks; therefore, eMDL calculations based on preparat ion blanks are artificially biased low. The eMDL for methylseleninic acid and selenomethionine is calculated from the average eMDL of selenite, selenate, and selenocyanate. The calibration does not contain methylseleninic acid or selenomethionine due to impurities in these standards which would bias the results for other selenium species.

# If you have any questions or concerns regarding this report, please feel free to contact me. Sincerely,

Russell Gerads Vice President Applied Speciation and Consulting, LLCSample ResultsSample IDSe(IV) Se(VI) SeCN MeSe(IV) SeMeUnknown SeSpecies (n)FGD Purge Eff94.281.2 ND (<1.5) ND (<2.0) ND (<2.0) 0 (0)BioReactor 1 Inf1.7470.0 ND (<0.36) 0.77 ND (<0.50) 0 (0)BioReactor 2 Eff ND (<0.61) ND (<0.53) ND (<0.36) ND (<0.50) ND (<0.50) 0 (0)Metals Trip BlkND (<0.12) ND (<0.11) ND (<0.073) ND (<0.10) ND (<0.10) 0 (0)All results reflect the applied dilution and are reported in μg/LND = Not detected at the applied dilutionSeCN = SelenocyanateMeSe(IV) = Methylseleninic acidSeMe = SelenomethionineUnknown Se Species = Total concentration of all unknown Se species observed by IC-ICP-MSn = number of unknown Se species observedReport Generated by: Russell GeradsApplied Speciation and Consulting, LLCSelenium Speciation Results for Duke EnergyProject Name: Belews - FGD WWTS (2010, Bi-Weekly Sampling)Contact: Jay PerkinsDate: January 28, 2011LIMS #J11010101Quality Control Summary - Preparation Blank SummaryAnalyte (μg/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL* eMDL 10x eMDL 50x eMDL 200xSe(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.012 0.12 0.61 2.4Se(VI) 0.000 0.000 0.000 0.000 0.000 0.000 0.011 0.11 0.53 2.1SeCN 0.000 0.000 0.000 0.000 0.000 0.000 0.007 0.073 0.36 1.5MeSe(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.010 0.10 0.50 2.0SeMe 0.000 0.000 0.000 0.000 0.000 0.000 0.010 0.10 0.50 2.0eMDL = Estimated Method Detection Limit*Please see narrative regarding eMDL calculationsQuality Control Summary - Certified Reference MaterialsAnalyte (μg/L) CRM True Value Result RecoverySe(IV) ICV 9.57 9.40 98.2Se(VI) ICV 9.48 9.12 96.2SeCN ICV 8.92 8.72 97.8MeSe(IV) ICV 6.47 5.48 84.7SeMe ICV 9.32 8.60 92.3LIMS #J11010101Date: January 28, 2011Report Generated by: Russell GeradsApplied Speciation and Consulting, LLCSelenium Speciation Results for Duke EnergyProject Name: Belews - FGD WWTS (2010, Bi-Weekly Sampling)Contact: Jay PerkinsQuality Control Summary - Matrix DuplicatesAnalyte (μg/L) Sample ID Rep 1 Rep 2 Mean RPDSe(IV) Batch QC 744.5 748.7 746.6 0.6Se(VI) Batch QC 106.5 104.5 105.5 1.9SeCN Batch QC ND (<1.5) ND (<1.5) NC NCMeSe(IV) Batch QC 2.8 2.5 2.6 11.7SeMe Batch QC ND (<2.0) ND (<2.0) NC NCND = Not detected at the applied dilutionNC = Value was not calculated due to one or more concentrations below the eMDLQuality Control Summary - Matrix Spike/ Matrix Spike DuplicateAnalyte (μg/L)Sample ID Spike Conc MS Result Recovery Spike Conc MSD Result Recovery RPDSe(IV)Batch QC 1112 1825 97.0 1112 1871 101.1 2.5Se(VI)Batch QC 1009 1002 88.8 1009 1019 90.6 1.7SeCNBatch QC 915.0 761.0 83.2 915.0 736.9 80.5 3.2LIMS #J11010101Date: January 28, 2011Report Generated by: Russell GeradsApplied Speciation and Consulting, LLCSelenium Speciation Results for Duke EnergyProject Name: Belews - FGD WWTS (2010, Bi-Weekly Sampling)Contact: Jay Perkins

### This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cert No. 37735 

# Case Narrative
01/27/2011

Duke Energy Corporation Jay Perkins 13339 Hagers Ferry Road Huntersville, NC 28078 Project: Belews - FGD WWTS (Bi-Weekly Sampling) Project No.: J11010101 Lab Submittal Date: 01/18/2011 Prism Work Order: 1010336

Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC.



### VP Laboratory Services Reviewed By

Data Qualifiers Key Reference:



### Method Detection Limit MDL Below Reporting Limit BRL

Relative Percent Difference RPD



## * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 1 of 5

# Sample Receipt Summary 01/27/2011 

## Prism Work Order: 1010336 Client Sample ID Matrix Lab Sample ID Date Sampled Date Received 

### 1010336-01 01/17/11 2011000396/FGD Purge EFF 01/18/11 Water
Samples received in good condition at 2.1 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 2 of 5

# Laboratory Report
01/27/2011

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: J11010101 Project: Belews - FGD WWTS (Bi-Weekly Sampling) Duke Energy Corporation

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: 2011000396/FGD Purge E Prism Sample ID: 1010336-01 Prism Work Order: 1010336 Time Collected: 01/17/11 13:05 Time Submitted: 01/18/11 16:00

General Chemistry Parameters 15000 *SM2540 C P1A0365 1 50 1/21/11 14:00 JAB mg/L 8.7 Total Dissolved Solids

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 3 of 5

### 1/27/11 

## Level II QC Report

13339 Hagers Ferry Road Project No: J11010101 Project: Belews - FGD WWTS (Bi-Weekly Sampling) Duke Energy Corporation

Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 1010336 Time Submitted: 1/18/11 4:00:00PM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control



### Batch P1A0365 - NO PREP Blank (P1A0365-BLK1) 

### Prepared & Analyzed: 01/21/11 Total Dissolved Solids mg/L BRL 50 LCS (P1A0365-BS1) 

### Prepared & Analyzed: 01/21/11 Total Dissolved Solids mg/L 980 50 1000 90-110 98 Duplicate (P1A0365-DUP1) 

### Prepared & Analyzed: 01/21/11 Source: 1010336-01 Total Dissolved Solids mg/L 15200 50 14900 20 2



### Sample Extraction Data

NO PREP
Lab Number Batch Date Initial Final P1A0365 1010336-01 01/21/11 50 50 mL mL

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 4 of 5Page 5 of 5