# APPENDIX H

Data Quality AssessmentsDQA-09; Isokinetic Sample Collection Revision Date: December 2012 Reviewed: December 2013

Page 1 of 3 

# Data Quality Assessment C ollection of Stack Gas in all Isokinetic Sampling Trains

**Analyte(s) M**  **ethod(s)**
Particulate Matter EPA Method 5 Hydrochloric Acid/Chlorine EPA Method 26A PCDD/PCDF SW-846 Method 0023A Metals EPA Method 29



### Preliminary **M easurements**  Sampling Location

Measurements All ports meet the minimum requirements for distance from

upstream and downstream disturbances.
Cyclonic Flow Check Cyclonic flow demonstrated to be within constraints for

isokinetic sampling.



### Sample Collection Minimum Sample Volume All other runs met QAPP specifications.

See table below. Minimum Sample Duration All runs met QAPP specifications.

See table below. Isokinetic Sampling Rate All trains met method specifications.

See table below.



### Sampling Train **Operation** Probe Temperature See table below.

Filter Temperature All runs met method specifications.

See table below.
Transfer Line Temperature All runs met method specifications.

See table below.
Condenser Exit Temperature See table below.

Impinger Exit Temperature All runs met method specifications.

See table below.



### Leak Checks Sampling Train – Pre Test All runs met method specifications.

See table below. Sampling Train – Port Changes All runs met method specifications.

See table below. Sampling Train – Post Test All runs met method specifications.

See table below.
Pitot Tubes – Pre Test All runs met method specifications.

See table below.
Pitot Tubes – Post Test All runs met method specifications.

See table below.DQA-09; Isokinetic Sample Collection Revision Date: December 2012 Reviewed: December 2013

Page 2 of 3 

### Sampling **D ocumentation**  Documentation of Calibration All calibrations documented appropriately; All calibrations meet

specifications. Correct Calibration Factors Used Yes.

Correct Molecular Weight Used Yes. Spreadsheet links are to corrected values in CEMs

spreadsheet Completed Data Sheets – Sample Collection Yes. See table below.

Completed Data Sheets – Sample Recovery All required information collected on sampling data sheets.

See table below.



### Conclusions and **Comments** These data are acceptable for the intended purpose.DQA-09; Isokinetic Sample Collection Revision Date: December 2012 Reviewed: December 2013

Page 3 of 3 

## Sampling Details

**P articulate**  **Matter EPA Method 5**  **HCl/Cl 2** 



### EPA Method **26A PCDD/PCDF** 

**EPA Method 23 Metals** 

**EPA Method 29**

Sample Volume Target 30 dscf 30 dscf 88 dscf 60 dscf
Achieved Yes Yes Yes Yes Sampling Duration Target 1 hour 1 hour 3 hours 2 hours
Achieved Yes Yes Yes Yes Isokinetic Sampling Rate between 90&110% Yes Yes Yes Yes
Temperatures Within Specification
Probe Yes Yes Yes Yes Filter Yes Yes Yes Yes Heat-Traced Line -- -- Yes -- Condenser Exit -- -- Yes -- Impinger Exit Yes Yes Yes Yes Data Sheets Complete Sample Collection Yes Yes Yes Yes Train Recovery Yes Yes Yes Yes Train Leak Checks

pre Yes Yes Yes Yes port changes Yes Yes Yes Yes Post (at proper vacuum) Yes Yes Yes Yes Pitot Leak Checks

pre Yes Yes Yes Yes post Yes Yes Yes YesDQA-02: PCDD/F in Stack Gas Revision Date: December 2012

Page 1 of 10 

# Data Quality Assessment Analysis of Stack Gas for Polychlorinated Dibenzodioxins and Dibenzofurans

**Parameter** PCDD/PCDF in Stack Gas 

### Sampling Method SW-846 Method 0023A 

### Analytical Method SW-846 Method 8290 

### Laboratory Project Number(s) H3J140408, H3J190407, H3K010401, H3K010402 

### Preparation Batch Number(s) 3289014, 3289015, 3295023, 3295024, 3308029, 3308030 

### Sample Shipping and Receipt All samples received intact and at or below 4°C. QAPP specifies <4°C.



### Holding Time(s) All samples prepared within 13 days of sampling and analyzed within 18

days of preparation. QAPP specifies 30 days until preparation and 45 days from preparation until analysis. See table below.



### Blank Results All target analytes except 2,3,7,8-TCDD were observed in a media check

sample, laboratory blank or field blank. The levels observed in the blank samples are very low, typically near the detection limit. See tables below and in the main body of the report.



### Laboratory Check Sample (LCS) **and Laboratory Check Sample Duplicate (LCSD) Results**  Recovery of all species in LCS between 70 and 120%. Relative percent difference (RPD) for all LCS/LCSD pairs were all below 25%. QAPP specifies the performance of a LCS once with recoveries between 70 and 130%. The QAPP has no specification for the performance of LCSD, or for RPD. The laboratory specification is RPD below 50%. See table below.



### Surrogate and Internal **Standard Spike Results** Recovery of internal standards between 40 and 130% with a pooled relative standard deviation below 25%. Recovery of pre-sampling surrogates between 70 and 115% with a pooled relative standard deviation below 15%. QAPP specifies internal standard recovery of 40-130% for tetra-hexa isomers and 25-130% for hepta and octa isomers, with no specification for pooled RSD. QAPP specifies recovery of surrogates between 70-130% with a pooled RSD below 30%. See tables below.



### Data Quality Objectives These are given in terms of surrogate spikes: Accuracy: 70-130% Recovery. Precisions: <30% pooled RSD. These objectives were met.



### Conclusions and Comments These data are acceptable for the intended purpose. As noted above, many analytes were found in the blank samples. Typically these levels are below the levels observed in the field samples. This indicates a potential positive bias in the field samples, which is conservative relative to the determination of emission rate. No data are qualified based on blank results.DQA-02: PCDD/F in Stack Gas Revision Date: December 2012

Page 2 of 10 

## Holding Time

**S ample**  **Date Extraction** 

**Date Analysis** 

**Date Holding Time (Days)** 

**Sampling to Extraction**  **Extraction to**

**Analysis** VS2-STK-11B-M0023A-PNR/FILT 11-Oct 16-Oct 28-Oct 5 12 VS2-STK-11B-M0023A-CR/XAD 11-Oct 16-Oct 31-Oct 5 15 VS2-STK-13B-M0023A-PNR/FILT 10-Oct 16-Oct 29-Oct 6 13 VS2-STK-13B-M0023A-CR/XAD 10-Oct 16-Oct 31-Oct 6 15 VS2-STK-15B-M0023A-PNR/FILT 30-Oct 4-Nov 20-Nov 5 16 VS2-STK-15B-M0023A-CR/XAD 30-Oct 4-Nov 22-Nov 5 18 VS2-STK-1FB-M0023A-PNR/FILT 8-Oct 16-Oct 28-Oct 8 12 VS2-STK-1FB-M0023A-CR/XAD 8-Oct 16-Oct 29-Oct 8 13 VS2-STK-1FB2-M0023A-PNR/FILT 29-Oct 4-Nov 20-Nov 6 16 VS2-STK-1FB2-M0023A-CR/XAD 29-Oct 4-Nov 20-Nov 6 16 VS3-STK-12B-M0023A-PNR/FILT 16-Oct 22-Oct 1-Nov 6 10 VS3-STK-12B-M0023A-CR/XAD 16-Oct 22-Oct 6-Nov 6 15 VS3-STK-13B-M0023A-PNR/FILT 17-Oct 22-Oct 5-Nov 5 14 VS3-STK-13B-M0023A-CR/XAD 17-Oct 22-Oct 6-Nov 5 15 VS3-STK-14B-M0023A-PNR/FILT 18-Oct 22-Oct 4-Nov 4 13 VS3-STK-14B-M0023A-CR/XAD 18-Oct 22-Oct 6-Nov 4 15 VS3-STK-1FB-M0023A-PNR/FILT 14-Oct 22-Oct 1-Nov 8 10 VS3-STK-1FB-M0023A-CR/XAD 14-Oct 22-Oct 5-Nov 8 14 VS4-STK-11B-M0023A-PNR/FILT 23-Oct 4-Nov 20-Nov 12 16 VS4-STK-11B-M0023A-CR/XAD 23-Oct 4-Nov 22-Nov 12 18 VS4-STK-12B-M0023A-PNR/FILT 24-Oct 4-Nov 20-Nov 11 16 VS4-STK-12B-M0023A-CR/XAD 24-Oct 4-Nov 22-Nov 11 18 VS4-STK-13B-M0023A-PNR/FILT 25-Oct 4-Nov 20-Nov 10 16 VS4-STK-13B-M0023A-CR/XAD 25-Oct 4-Nov 22-Nov 10 18 VS4-STK-1FB-M0023A-PNR/FILT 22-Oct 4-Nov 19-Nov 13 15 VS4-STK-1FB-M0023A-CR/XAD 22-Oct 4-Nov 21-Nov 13 17DQA-02: PCDD/F in Stack Gas Revision Date: December 2012 Page 3 of 10**Blank Results – Media Check Samples and Laboratory Blanks Analytical Result** **( p** **g/sample) A-5037** **MEDIA CHECK** **XAD A-5038** **MEDIA CHECK** **FILTER A-5074** **MEDIA CHECK** **XAD A-5075** **MEDIA CHECK** **FILTER Laboratory** **Blank; Batch** **3289014 Laboratory** **Blank; Batch** **3289015 Laboratory** **Blank; Batch** **3295023 Laboratory** **Blank; Batch** **3295024 Laboratory** **Blank; Batch** **3308029 Laboratory** **Blank; Batch** **3308030 Range of Field Samples** **PNR/Filt CR/XAD**2,3,7,8-TCDD<2.5 <2.4 <3.7 <3.5 <3.4 <2.7 <0.16 <0.24 <4.6 <6.6 ----1,2,3,7,8-PeCDD <1.2 <0.94 <1.4 <1.1 <1.4 <1.3**0.64**<0.11 <1.8 <2.5 0.23 - <2.2 4.8 * - 120 *1,2,3,4,7,8-HxCDD <1.1 <0.8 <1.1 <0.79 <1.2 <0.94 <0.16**0.22 ***<1.4 <2.2 <0.15 - 4.3 2.6 - 2301,2,3,6,7,8-HxCDD <1.1 <0.78 <1 <0.77 <1.1 <0.91 <0.15**0.34 ***<1.3 <2.1 0.22 * - 16 5.1 * - 9901,2,3,7,8,9-HxCDD <1.1 <0.79 <1.1 <0.78 <1.2 <0.93**0.73 * 1.3 ***<1.4 <2.1 0.41 * - 12 * 5.6 - 6501,2,3,4,6,7,8-HpCDD <1.5 <0.82 <1.5 <0.86 <1.3 <1.2**1.9 2.1 * 7.2**<2 1.5 * - 160 29 - 6100OCDD**4.8 2.5 * 3.1**<1**6 3.4 * 6.4 7 * 13**<2.8 5.6 * - 190 28 - 35002,3,7,8-TCDF<1.6 <1.3 <2.5 <2.3 <1.8 <1.9 <0.1**0.2 ***<2.9 <4.3 0.29 - 3.8 * 6.8 * - 781,2,3,7,8-PeCDF <0.98 <0.89 <1.5 <1.1 <1.3 <1.1 0.37**0.55 ***<1.9 <2.9 0.11 * - <2.1 9.1 * - 130 *2,3,4,7,8-PeCDF <1 <0.9 <1.5 <1.1 <1.3 <1.1**0.79 * 0.65**<1.9 <3 <0.11 - 4.7 * 16 - 550 *1,2,3,4,7,8-HxCDF <0.64 <0.46 <0.87 <0.54 <0.86 <0.61**0.68 0.27 * 8.7**<1.4 0.48 * - 5 25 * - 570 *1,2,3,6,7,8-HxCDF <0.57 <0.41 <0.78 <0.48 <0.77 <0.54**0.76 * 0.54 3.5**<1.2 0.22 * - 2.7 * 11 * - 310 *1,2,3,7,8,9-HxCDF <0.69 <0.49 <0.95 <0.58 <0.93 <0.66**1.3 * 1.1 ***<1.2 <1.5 0.56 * - <1.4 0.9 * - 38 *2,3,4,6,7,8-HxCDF <0.6 <0.43 <0.82 <0.5 <0.81 <0.57**<0.14 1.2 3.1 ***<1.3 0.42 * - 8.4 * 11 * - 600 *1,2,3,4,6,7,8-HpCDF <0.84 <0.88 <1.1 <0.59 <1 <0.78**0.87 * 1.2 * 20**<1.9 1.1 * - 17 22 - 7601,2,3,4,7,8,9-HpCDF <1.1 <1.2 <1.4 <0.77 <1.4 <1**1 * 1.7 3.4**<2.5 0.48 * - 5.9 * 3.8 * - 200OCDF<2 <1.6 <2.2 <1.4 <1.9 <1.7**2.7 * 4.5 18**<3.6 3.8 - 12 * 5.7 * - 630 ** - Value reported is Estimated Maximum Possible Concentration (EMPC)DQA-02: PCDD/F in Stack Gas Revision Date: December 2012 Page 4 of 10**Blank Results – Media Check Samples and Laboratory Blanks A** **n alytical Result** **(pg/sample) VS2-STK-1FB** **M0023A PNR/FILT** **VS2-STK-1FB- M0023A-** **CR/XAD VS2-STK-** **1FB2- M0023A-** **PNR/FILT VS2-STK-** **1FB2- M0023A-** **CR/XAD VS3-STK-1FB-** **M0023A- PNR/FILT** **VS3-STK-1FB- M0023A-** **CR/XAD VS4-STK-1FB-** **M0023A- PNR/FILT** **VS4-STK-1FB- M0023A-** **CR/XAD Range of Field Samples** **PNR/Filt CR/XAD**2,3,7,8-TCDD<1.8 <2.2 <3.4 <4.1 <0.16 <0.25 <2.5 <4.5 ----1,2,3,7,8-PeCDD <0.89 <0.99 <1.4 <1.7 <0.12**0.46 ***<0.92 <1.9 0.23 - <2.2 4.8 * - 120 *1,2,3,4,7,8-HxCDD <0.85 <0.89 <1.2 <1.7**0.46**<0.23 <0.66 <1.6 <0.15 - 4.3 2.6 - 2301,2,3,6,7,8-HxCDD <0.82 <0.86 <1.1 <1.7 <0.17 <0.22 <0.64 <1.6 0.22 * - 16 5.1 * - 9901,2,3,7,8,9-HxCDD <0.84 <0.88 <1.1 <1.7**0.47 * 0.54 ***<0.65 <1.6 0.41 * - 12 * 5.6 - 6501,2,3,4,6,7,8-HpCDD <1 <1.1**2.1 * 3.3 * 1.2 * 0.61 * 2.1 ***<1.9 1.5 * - 160 29 - 6100OCDD**6.1 * 4.7 5.7 * 5.6 16 8.3 * 15 10**5.6 * - 190 28 - 35002,3,7,8-TCDF<1.1 <1.6 <2.3 <2.7 <0.12**0.5 ***<1.6 <3 0.29 - 3.8 * 6.8 * - 781,2,3,7,8-PeCDF <0.84 <0.79 <1.4 <1.5**0.24 * 0.33 ***<0.86 <1.7 0.11 * - <2.1 9.1 * - 130 *2,3,4,7,8-PeCDF <0.85 <0.8 <1.4 <1.6 <0.13**0.36 ***<0.87 <1.7 <0.11 - 4.7 * 16 - 550 *1,2,3,4,7,8-HxCDF**2.3**<0.51 <0.8 <1.1**0.84 * 0.47 ***<0.48 <1.1 0.48 * - 5 25 * - 570 *1,2,3,6,7,8-HxCDF**0.56 ***<0.45 <0.71 <0.95 <0.12**0.36 ***<0.42 <1 0.22 * - 2.7 * 11 * - 310 *1,2,3,7,8,9-HxCDF <0.59 <0.55 <0.86 <1.2**0.22 ***<0.18 <0.52 <1.2 0.56 * - <1.4 0.9 * - 38 *2,3,4,6,7,8-HxCDF <0.52 <0.48 <0.75 <1**0.76 * 0.41 ***<0.45 <1.1 0.42 * - 8.4 * 11 * - 600 *1,2,3,4,6,7,8-HpCDF**9.3**<0.75 <1.3 <1.4**1.9 * 0.84 ***<0.65 <1.4 1.1 * - 17 22 - 7601,2,3,4,7,8,9-HpCDF**1.6 ***<0.97 <1.6 <1.8**1.3 * 0.68 ***<0.85 <1.8 0.48 * - 5.9 * 3.8 * - 200OCDF**15**<1.6 <2.8 <2.7**5.6 4.8 1.8 ***<1.9 0.48 * - 5 25 * - 570 ** - Value reported is Estimated Maximum Possible Concentration (EMPC)DQA-02: PCDD/F in Stack Gas Revision Date: December 2012 Page 5 of 10**Laboratory Check Sample (LCS) and Laboratory Check Sample Duplicate (LCSD) Results L** **a boratory Check Sample and Laboratory Check Sample Duplicate** **Batch 3289014 Batch 3289015** **Batch 3295023 LCS** **Recovery (%)** **LCSD Recovery** **(%) Relative** **Percent Difference** **(%) LCS** **Recovery (%)** **LCSD Recovery** **(%) Relative** **Percent Difference** **(%) LCS** **Recovery (%)** **LCSD Recovery** **(%) Relative** **Percent Difference** **(%)**2,3,7,8-TCDD100 104 4.7 9692 4.4 8992 2.81,2,3,7,8-PeCDD9393 0.18 9291 0.99 9897 0.941,2,3,4,7,8-HxCDD9797 0.6 948969095 4.71,2,3,6,7,8-HxCDD8787 0.95 8888 0.03 908731,2,3,7,8,9-HxCDD116 105 9.6 105 97 7.3 8686 0.011,2,3,4,6,7,8-HpCDD9493 0.71 9392 1.2 88913OCDD9092 1.3 8993 3.8 8790 3.22,3,7,8-TCDF9084 6.9 8685 0.92 9192 1.51,2,3,7,8-PeCDF9497 3.1 9393 0.05 9493 1.32,3,4,7,8-PeCDF9192 0.4 8988 0.92 6666 0.891,2,3,4,7,8-HxCDF9899 1.4 97981109 107 2.11,2,3,6,7,8-HxCDF9293 0.72 8793 6.2 101 103 1.61,2,3,7,8,9-HxCDF118 107 10 102 101 0.91 109 107 1.22,3,4,6,7,8-HxCDF113 105 7.4 98 103 5.7 99 98 1.41,2,3,4,6,7,8-HpCDF8690 4.6 8486 1.8 9393 0.591,2,3,4,7,8,9-HpCDF105 94119185696 1004OCDF9389 4.3 9394 0.08 748715DQA-02: PCDD/F in Stack Gas Revision Date: December 2012 Page 6 of 10**Laboratory Check Sample and Laboratory Check Sample Duplicate Batch 3295024** **Batch 3308029 Batch 3308030** **LCS Recovery** **(%) LCSD** **Recovery (%)** **Relative Percent** **Difference (%)** **LCS Recovery** **(%) LCSD** **Recovery (%)** **Relative Percent** **Difference (%)** **LCS Recovery** **(%) LCSD** **Recovery (%)** **Relative Percent** **Difference (%)** 2,3,7,8-TCDD9385 9.1 9899 0.64 9399 5.61,2,3,7,8-PeCDD959329496 2.2 9693 2.91,2,3,4,7,8-HxCDD8378 5.9 98 101 2.4 939851,2,3,6,7,8-HxCDD99 109 9.2 9294 2.1 9393 0.661,2,3,7,8,9-HxCDD8990 1.4 109 138 23 108 108 0.541,2,3,4,6,7,8-HpCDD9084 6.7 9898 0.03 93963OCDD8189 9.6 9495 1.1 9293 1.62,3,7,8-TCDF9589 6.3 9594 0.89 8589 5.61,2,3,7,8-PeCDF9895 3.6 110 107 2.9 97 102 5.12,3,4,7,8-PeCDF857019 101 102 0.88 939421,2,3,4,7,8-HxCDF9286 6.6 104 109 4.3 99 102 3.31,2,3,6,7,8-HxCDF111 117 5.5 105 101 3.4 98 99 0.361,2,3,7,8,9-HxCDF9897 0.67 112 142 24 104 112 7.52,3,4,6,7,8-HxCDF101 1043113 142 23 103 108 4.91,2,3,4,6,7,8-HpCDF8791 4.2 108 102 6.2 9394 0.641,2,3,4,7,8,9-HpCDF8491 7.3 107 137 259899 1.4OCDF7989128787 0.23 7983 4.9DQA-02: PCDD/F in Stack Gas Revision Date: December 2012 Page 7 of 10**Internal Standard Recovery Internal Standard Recovery (%)** 

**13 C-2,3,7,8-TCDD**  **13 C-2,3,7,8-TCDF**  **13 C-2,3,7,8-TCDF**  **1 13**  **C-1,2,3,7,8- P**  **eCDD 13**  **C-1,2,3,7,8- P**  **eCDF 13**  **C-1,2,3,6,7,8- H**  **xCDD 13**  **C-1,2,3,6,7,8- H**  **xCDF 13**  **C-1,2,3,4,6,7,8- H**  **pCDD 13**  **C-1,2,3,4,6,7,8- H**  **pCDF 13**  **C-OCDD**VS2-STK-11B-M0023A-PNR/FILT88 87 -- 93 85 91 81 84 66 51VS2-STK-11B-M0023A-CR/XAD84 85 98 96 89 88 77 88 76 68VS2-STK-13B-M0023A-PNR/FILT89 85 -- 95 88 92 78 80 70 62VS2-STK-13B-M0023A-CR/XAD87 87 101 83 80 86 76 87 74 75VS2-STK-15B-M0023A-PNR/FILT81 77 -- 89 76 83 76 77 69 55VS2-STK-15B-M0023A-CR/XAD80 74 76 90 81 80 72 80 68 65VS3-STK-12B-M0023A-PNR/FILT75 67 -- 89 97 103 96 91 89 78VS3-STK-12B-M0023A-CR/XAD63 56 82 98 119 93 94 75 74 62VS3-STK-13B-M0023A-PNR/FILT68 68 -- 91 105 125 120 97 101 86VS3-STK-13B-M0023A-CR/XAD67 66 85 53 69 92 95 78 78 67VS3-STK-14B-M0023A-PNR/FILT67 61 -- 69 84 105 110 89 87 74VS3-STK-14B-M0023A-CR/XAD67 67 87 63 75 92 96 76 77 66VS4-STK-11B-M0023A-PNR/FILT72 65 -- 85 70 83 76 73 66 49VS4-STK-11B-M0023A-CR/XAD81 76 81 92 81 80 73 90 73 83VS4-STK-12B-M0023A-PNR/FILT80 76 -- 90 76 83 78 83 71 61VS4-STK-12B-M0023A-CR/XAD85 78 80 96 83 81 77 91 73 73VS4-STK-13B-M0023A-PNR/FILT80 75 -- 85 75 78 73 69 62 48VS4-STK-13B-M0023A-CR/XAD79 74 82 88 75 78 69 87 67 69VS2-STK-1FB-M0023A-PNR/FILT82 86 -- 82 77 79 72 76 60 48VS2-STK-1FB-M0023A-CR/XAD87 84 -- 88 82 92 81 86 76 66VS2-STK-1FB2-M0023A-PNR/FILT79 74 -- 89 76 84 78 69 65 461Associated with analysis using the confirmation columnDQA-02: PCDD/F in Stack Gas Revision Date: December 2012 Page 8 of 10**Internal Standard Recovery (%)**

**13 C-2,3,7,8-TCDD**  **13 C-2,3,7,8-TCDF**  **13 C-2,3,7,8-TCDF**  **1 13**  **C-1,2,3,7,8- P**  **eCDD 13**  **C-1,2,3,7,8- P**  **eCDF 13**  **C-1,2,3,6,7,8- H**  **xCDD 13**  **C-1,2,3,6,7,8- H**  **xCDF 13**  **C-1,2,3,4,6,7,8- H**  **pCDD 13**  **C-1,2,3,4,6,7,8- H**  **pCDF 13**  **C-OCDD**VS2-STK-1FB2-M0023A-CR/XAD91 82 -- 100 81 86 73 85 68 68VS3-STK-1FB-M0023A-PNR/FILT67 62 -- 76 87 95 93 85 90 73VS3-STK-1FB-M0023A-CR/XAD61 58 -- 99 110 104 103 79 79 69VS4-STK-1FB-M0023A-PNR/FILT76 74 -- 87 78 80 70 85 71 79VS4-STK-1FB-M0023A-CR/XAD89 85 -- 102 88 96 83 102 82 85A-5037 MEDIA CHECK XAD87 84 -- 86 80 84 72 75 67 51A-5038 MEDIA CHECK FILTER88 89 -- 90 82 88 71 90 69 63A-5074 MEDIA CHECK XAD80 74 -- 87 70 81 64 82 68 65A-5075 MEDIA CHECK FILTER58 53 -- 79 66 78 66 81 71 65Laboratory Blank; Batch 328901489 85 -- 90 80 86 70 88 69 65Laboratory Blank; Batch 328901587 85 -- 92 83 86 71 84 74 69Laboratory Blank; Batch 329502371 69 -- 80 88 97 86 94 92 76Laboratory Blank; Batch 329502462 59 -- 88 107 76 72 73 82 61Laboratory Blank; Batch 330802968 66 -- 77 65 74 62 80 68 74Laboratory Blank; Batch 330803086 82 -- 99 79 89 67 89 74 69LCS; Batch 328901483 89 -- 86 78 74 63 79 62 67LCSD; Batch 328901484 88 -- 92 84 83 71 84 70 65LCS; Batch 328901584 84 -- 84 77 84 73 76 68 56LCSD; Batch 328901587 83 -- 97 87 89 74 78 72 55LCS; Batch 329502361 59 -- 79 91 85 74 88 83 78LCSD; Batch 329502374 69 -- 94 108 100 90 101 98 89LCS; Batch 329502463 57 -- 61 62 80 78 81 89 77LCSD; Batch 329502463 58 -- 107 124 80 79 83 84 73LCS; Batch 330802974 70 -- 90 70 78 60 88 66 82DQA-02: PCDD/F in Stack Gas Revision Date: December 2012 Page 9 of 10**Internal Standard Recovery (%)**

**13 C-2,3,7,8-TCDD**  **13 C-2,3,7,8-TCDF**  **13 C-2,3,7,8-TCDF**  **1 13**  **C-1,2,3,7,8- P**  **eCDD 13**  **C-1,2,3,7,8- P**  **eCDF 13**  **C-1,2,3,6,7,8- H**  **xCDD 13**  **C-1,2,3,6,7,8- H**  **xCDF 13**  **C-1,2,3,4,6,7,8- H**  **pCDD 13**  **C-1,2,3,4,6,7,8- H**  **pCDF 13**  **C-OCDD**LCSD; Batch 330802960 58 -- 74 60 53 43 73 45 69LCS; Batch 330803076 71 -- 83 71 73 62 82 63 63LCSD; Batch 330803075 70 -- 88 70 74 60 78 60 55Pooled RSD for InternalStandard Recovery (%)PNR/FILT10.2 12.1 -- 8.7 13.5 16.0 19.5 10.8 17.6 21.9CR/XAD11.6 13.1 9.8 18.8 17.3 7.0 13.4 7.5 5.1 9.1QAPP Specification Recovery (%) 40-130 40-130 40-130 40-130 40-130 40-130 40-130 25-130 25-130 25-130DQA-02: PCDD/F in Stack Gas Revision Date: December 2012

Page 10 of 10 

## Surrogate Standard Recovery

**Surrogate Standard Recovery 37** **Cl-2,3,7,8-TCDD 13** **C-2,3,4,7,8- PeCDF** **13 C-1,2,3,4,7,8-** **HxCDD 13** **C-1,2,3,4,7,8- HxCDF** **13 C-1,2,3,4,7,8,9-** **HpCDF**

VS2-STK-11B-M0023A-PNR/FILT 89 97 96 95 88 VS2-STK-11B-M0023A-CR/XAD 86 95 97 94 97 VS2-STK-13B-M0023A-PNR/FILT 98 105 106 108 109 VS2-STK-13B-M0023A-CR/XAD 84 94 100 96 102 VS2-STK-15B-M0023A-PNR/FILT 94 103 106 100 105 VS2-STK-15B-M0023A-CR/XAD 92 101 106 106 111 VS3-STK-12B-M0023A-PNR/FILT 85 78 100 97 100 VS3-STK-12B-M0023A-CR/XAD 85 79 78 73 96 VS3-STK-13B-M0023A-PNR/FILT 89 91 71 75 88 VS3-STK-13B-M0023A-CR/XAD 86 80 80 79 88 VS3-STK-14B-M0023A-PNR/FILT 83 77 83 79 87 VS3-STK-14B-M0023A-CR/XAD 90 87 81 79 98 VS4-STK-11B-M0023A-PNR/FILT 88 103 101 94 91 VS4-STK-11B-M0023A-CR/XAD 92 100 107 101 108 VS4-STK-12B-M0023A-PNR/FILT 94 105 107 97 101 VS4-STK-12B-M0023A-CR/XAD 89 101 108 99 112 VS4-STK-13B-M0023A-PNR/FILT 90 99 103 98 99 VS4-STK-13B-M0023A-CR/XAD 92 101 112 102 110 VS2-STK-1FB-M0023A-PNR/FILT 89 96 103 98 95 VS2-STK-1FB-M0023A-CR/XAD 87 98 100 98 96 VS2-STK-1FB2-M0023A-PNR/FILT 92 100 102 99 93 VS2-STK-1FB2-M0023A-CR/XAD 87 97 99 99 110 VS3-STK-1FB-M0023A-PNR/FILT 88 79 105 98 94 VS3-STK-1FB-M0023A-CR/XAD 84 79 73 70 94 VS4-STK-1FB-M0023A-PNR/FILT 90 97 99 97 106 VS4-STK-1FB-M0023A-CR/XAD 90 100 98 99 109 Pooled RSD for Surrogate Recovery (%) PNR/FILT 5.2 11.6 12.6 11.0 8.5 CR/XAD 3.7 9.7 13.9 13.0 8.1

QAPP Specification Recovery (%) 70-130 70-130 70-130 70-130 70-130 RSD (%) 30 30 30 30 30DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 1 of 22 

# Data Quality Assessment A nalysis of Waste Feeds for Physical & Chemical Parameters

Parameter Physical & Chemical Parameters in Waste Feeds 

### Sampling Method Tap Sampling



### Analytical Method Ash Content – ASTM D482

Density – ASTM D1963 Heat of Combustion – ASTM D240 or ASTM D5865 Kinematic Viscosity – ASTM D445 Total Chlorine – Knox WC-0016 Moisture/Water – EPA 160.3 or ASTM D4017



### Laboratory Job ID Number(s) H3J140415, H3J140417, H3J150401, H3J150402, H3J190415, H3J190416, H3J190417, H3J190418, H3K010415, H3K010416, H3K010418, H3K010419, H3K020402, H3K020403, H3K020404, H3K020405, H3K020406



### Batch Numbers 3288017, 3288047, 3289046, 3291011, 3294014, 3294027, 3294063,

3295017, 3295055, 3296018, 3296033, 3296034, 3297012, 3297044, 3297045, 3298024, 3298026, 3298030, 3301015, 3301016, 3302022, 3304034, 3304036, 3304037, 3305056, 3305057, 3305068, 3308013, 3309013, 3309015, 3309044, 3309045, 3309048, 3310040, 3311015, 3311040, 3311042, 3311046, 3311049, 3312052, 3314010, 3314011, 3315023, 3316017, 3316041, 3316044, 3317013, 3318019, 3318020, 3318021, 3318038, 3319020, 3320010, 3321010, 3322015, 3322032, 3322033, 3322037, 3322038, 3323034, 3323036, 3323037, 3323038, 3323063, 3323064, 3323065, 3324028, 3324029, 3325013, 3328011, 3328012, 3328014, 3328015, 3328016, 3328017, 3330010, 3330011, 3330016 

### Sample Shipping and Receipt Samples received intact and at ambient temperature. QAPP has no temperature specification.



### Holding Time(s) All analyses conducted within 29 days of sample collection.

QAPP specifies analysis within 30 days of sample collection. See table below.



### Blank Results All laboratory blank results below or very near the detection limit.

See table below and in main body of report.



### Laboratory Check Sample (LCS) and Laboratory Check Sample Duplicate (LCSD) Results LCS and LCSD were prepared and analyzed for the various analytical methods, as specified in the QAPP. All LCS and LCSD recoveries and relative percent differences met the laboratory and QAPP specifications. See table below. 

### Matrix Spike (MS) and Matrix Spike Duplicate (MSD) Results MS and MSD were performed for analysis of chlorine. MS/MSD recoveries were between 80 and 105% recovery. RPDs were below 5%. See table below.DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 2 of 22 

### Duplicate Analysis Selected samples were analyzed in duplicate. 90 of 96 duplicate analyses met

the QAPP specifications (see table below). The outliers are:

• Ash in VS2-HBW-13B-COMP2B; results of 582 and 646 mg/kg; RPD of 10.4%

• Gross Calorific Value in VS2-LBW-15B-COMP2B; results of 178 and 152 BTU/lb; RPD of 15.8%

• Chlorine in VS3-CS-11A-COMP 1; results of 253 and 325 mg/kg; RPD of 24.9%

• Chlorine in VS4-BS-11A-COMP1; results of 171 and 221 mg/kg; RPD of 25.5%

• Ash in VS4-HBW-12B-COMP2B-DUP; results of 943 and 1050 mg/kg; RPD of 10.7%

• Ash VS4-HBW-13A-COMP1; results of 1,500 and 928 mg/kg; RPD of 47.1% No duplicate analysis was performed for moisture in solid waste streams. This duplicate analysis was specified in the QAPjP. In addition, samples were collected in duplicate. There are no QAPP specifications for the analysis of duplicate samples. Reproducibility for these samples was good. . See table s below



### Quality Assurance Objective The QAPP specifies quality assurance objectives as follows:

• Chlorine

o Precision: 10% RPD for MS/MSD

o Accuracy: 80-120% Recovery of MS/MSD

• Ash

o Precision: 10% RPD for LCS/LCSD

o Accuracy: 90-110% recovery for LCS

• Water in liquid waste feed

o Precision: 10% RPD for results greater than 1%

o Accuracy: 95-105% recovery of LCS

• Water in solid waste feed:

o Precision: 25% RPD for duplicate analysis

• Heating Value

o Precision: 10% RPD for laboratory duplicates

o Accuracy: 98-102% recovery of LCS

• Density

o Precision: 10% RPD for analytical duplicates

o Accuracy: 99-101% recovery for LCS

• Viscosity

o Precision: 10% RPD for analytical duplicates

o Accuracy: 99-101% recovery of LCS Except as discussed above, these objectives were met.DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 3 of 22 

### Conclusions and Comments These data are acceptable for the intended purposes. The outliers for duplicate analysis have a negligible impact on the usability of the data. The chlorine carried in containerized solids and bulk solids is negligible (<1%) compared to the chlorine provided by the spiking material. The ash carried in high BTU waste is negligible (<1%) compared to the ash provided by the bulk or containerized solids. The heat input results in low BTU waste are near the detection limit. Increased uncertainty is expected close to the detection limit. Although duplicate analysis was not performed for water in solid waste streams, this has no impact on the usability of the data. Moisture results are used only to characterize the waste feed materials, and are not used in any demonstration of compliance. No data are qualified or invalidated based on duplicate analysis.DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013 Page 4 of 22Holding TimeSampleDateAnalysis DateHolding Time (DaysAshContentDensityGrossCalorificValueKinematicViscosityPercentMoistureTotalChlorineAshContentDensityGrossCalorificValueKinematicViscosityPercentMoistureTotalChlorineVS2-CS-11A-COMP1 8-Oct 24-Oct -- 17-Oct -- 15-Oct 17-Oct 16 -- 9 -- 7 9VS2-CS-11B-COMP2A 8-Oct 25-Oct -- 17-Oct -- 15-Oct 17-Oct 17 -- 9 -- 7 9VS2-CS-11B-COMP2B 8-Oct 24-Oct -- 17-Oct -- 15-Oct 17-Oct 16 -- 9 -- 7 9VS2-CS-11B-COMP2C 8-Oct 24-Oct -- 17-Oct -- 15-Oct 17-Oct 16 -- 9 -- 7 9VS2-CS-12A-COMP1 9-Oct 24-Oct -- 17-Oct -- 15-Oct 17-Oct 15 -- 8 -- 6 8VS2-CS-13A-COMP1 10-Oct 24-Oct -- 17-Oct -- 15-Oct 17-Oct 14 -- 7 -- 5 7VS2-CS-13B-COMP2A 10-Oct 24-Oct -- 17-Oct -- 15-Oct 17-Oct 14 -- 7 -- 5 7VS2-CS-13B-COMP2B 10-Oct 24-Oct -- 17-Oct -- 15-Oct 17-Oct 14 -- 7 -- 5 7VS2-CS-13B-COMP2C 10-Oct 24-Oct -- 17-Oct -- 15-Oct 17-Oct 14 -- 7 -- 5 7VS2-CS-14B-COMP2A 11-Oct 24-Oct -- 17-Oct -- 15-Oct 17-Oct 13 -- 6 -- 4 6VS2-CS-14B-COMP2B 11-Oct 24-Oct -- 17-Oct -- 15-Oct 17-Oct 13 -- 6 -- 4 6VS2-CS-14B-COMP2C 11-Oct 24-Oct -- 17-Oct -- 15-Oct 17-Oct 13 -- 6 -- 4 6VS2-CS-15B-COMP2A 30-Oct 26-Nov -- 26-Nov -- 4-Nov 26-Nov 27 -- 27 -- 5 27VS2-CS-15B-COMP2B 30-Oct 26-Nov -- 26-Nov -- 4-Nov 26-Nov 27 -- 27 -- 5 27VS2-CS-15B-COMP2C 30-Oct 26-Nov -- 26-Nov -- 4-Nov 26-Nov 27 -- 27 -- 5 27VS2-HBW-11A-COMP1 8-Oct 24-Oct 24-Oct 21-Oct 24-Oct 22-Oct 23-Oct 16 16 13 16 14 15VS2-HBW-11B-COMP2A 8-Oct 24-Oct 24-Oct 21-Oct 24-Oct 22-Oct 23-Oct 16 16 13 16 14 15VS2-HBW-11B-COMP2B 8-Oct 24-Oct 24-Oct 21-Oct 25-Oct 22-Oct 23-Oct 16 16 13 17 14 15VS2-HBW-11B-COMP2C 8-Oct 24-Oct 24-Oct 21-Oct 25-Oct 22-Oct 23-Oct 16 16 13 17 14 15VS2-HBW-12A-COMP1 9-Oct 24-Oct 24-Oct 21-Oct 25-Oct 22-Oct 23-Oct 15 15 12 16 13 14VS2-HBW-13A-COMP1 10-Oct 24-Oct 24-Oct 21-Oct 25-Oct 22-Oct 23-Oct 14 14 11 15 12 13VS2-HBW-13B-COMP2A 10-Oct 24-Oct 24-Oct 21-Oct 25-Oct 22-Oct 23-Oct 14 14 11 15 12 13VS2-HBW-13B-COMP2B 10-Oct 24-Oct 24-Oct 21-Oct 25-Oct 22-Oct 23-Oct 14 14 11 15 12 13VS2-HBW-13B-COMP2BDUPLICATE10-Oct 24-Oct 24-Oct 21-Oct 25-Oct 22-Oct 23-Oct 14 14 11 15 12 13VS2-HBW-13B-COMP2C 10-Oct 24-Oct 24-Oct 21-Oct 25-Oct 22-Oct 23-Oct 14 14 11 15 12 13VS2-HBW-14B-COMP2A 11-Oct 24-Oct 24-Oct 21-Oct -- 22-Oct 23-Oct 13 13 10 -- 11 12VS2-HBW-14B-COMP2B 11-Oct 24-Oct 24-Oct 21-Oct -- 22-Oct 23-Oct 13 13 10 -- 11 12DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013 Page 5 of 22SampleDateAnalysis DateHolding Time (DaysAshContentDensityGrossCalorificValueKinematicViscosityPercentMoistureTotalChlorineAshContentDensityGrossCalorificValueKinematicViscosityPercentMoistureTotalChlorineVS2-HBW-14B-COMP2C 11-Oct 24-Oct 24-Oct 21-Oct -- 22-Oct 23-Oct 13 13 10 -- 11 12VS2-HBW-15B-COMP2A 30-Oct 26-Nov 25-Nov 26-Nov 26-Nov 27-Nov 26-Nov 27 26 27 27 28 27VS2-HBW-15B-COMP2B 30-Oct 27-Nov 25-Nov 26-Nov 26-Nov 27-Nov 26-Nov 28 26 27 27 28 27VS2-HBW-15B-COMP2C 30-Oct 27-Nov 25-Nov 26-Nov 26-Nov 27-Nov 26-Nov 28 26 27 27 28 27VS2-LBW-11A-COMP1 8-Oct 28-Oct 25-Oct 28-Oct 29-Oct 4-Nov 27-Oct 20 17 20 21 27 19VS2-LBW-11B-COMP2A 8-Oct 28-Oct 25-Oct 28-Oct 30-Oct 4-Nov 27-Oct 20 17 20 22 27 19VS2-LBW-11B-COMP2B 8-Oct 28-Oct 25-Oct 28-Oct 30-Oct 4-Nov 27-Oct 20 17 20 22 27 19VS2-LBW-11B-COMP2C 8-Oct 28-Oct 25-Oct 28-Oct 30-Oct 4-Nov 27-Oct 20 17 20 22 27 19VS2-LBW-12A-COMP1 9-Oct 28-Oct 25-Oct 28-Oct 30-Oct 4-Nov 27-Oct 19 16 19 21 26 18VS2-LBW-13A-COMP1 10-Oct 28-Oct 25-Oct 28-Oct 30-Oct 5-Nov 27-Oct 18 15 18 20 26 17VS2-LBW-13B-COMP2A 10-Oct 28-Oct 25-Oct 28-Oct 30-Oct 5-Nov 27-Oct 18 15 18 20 26 17VS2-LBW-13B-COMP2B 10-Oct 28-Oct 25-Oct 28-Oct 30-Oct 5-Nov 27-Oct 18 15 18 20 26 17VS2-LBW-13B-COMP2BDUPLICATE10-Oct 28-Oct 25-Oct 28-Oct 30-Oct 5-Nov 27-Oct 18 15 18 20 26 17VS2-LBW-13B-COMP2C 10-Oct 28-Oct 25-Oct 28-Oct 30-Oct 5-Nov 27-Oct 18 15 18 20 26 17VS2-LBW-15B-COMP2A 30-Oct 26-Nov 25-Nov 26-Nov 26-Nov 27-Nov 26-Nov 27 26 27 27 28 27VS2-LBW-15B-COMP2B 30-Oct 26-Nov 25-Nov 26-Nov 26-Nov 27-Nov 26-Nov 27 26 27 27 28 27VS2-LBW-15B-COMP2C 30-Oct 26-Nov 25-Nov 26-Nov 26-Nov 27-Nov 26-Nov 27 26 27 27 28 27VS2-LWF-11A-COMP1 8-Oct 28-Oct 25-Oct 31-Oct 28-Oct 26-Oct 29-Oct 20 17 23 20 18 21VS2-LWF-11B-COMP2A 8-Oct 28-Oct 25-Oct 31-Oct 28-Oct 26-Oct 29-Oct 20 17 23 20 18 21VS2-LWF-11B-COMP2B 8-Oct 28-Oct 25-Oct 1-Nov 28-Oct 26-Oct 29-Oct 20 17 24 20 18 21VS2-LWF-11B-COMP2C 8-Oct 28-Oct 25-Oct 1-Nov 28-Oct 26-Oct 29-Oct 20 17 24 20 18 21VS2-LWF-12A-COMP1 9-Oct 28-Oct 25-Oct 1-Nov 28-Oct 26-Oct 29-Oct 19 16 23 19 17 20VS2-LWF-13A-COMP1 10-Oct 28-Oct 25-Oct 1-Nov 28-Oct 26-Oct 29-Oct 18 15 22 18 16 19VS2-LWF-13B-COMP2A 10-Oct 28-Oct 25-Oct 1-Nov 28-Oct 26-Oct 29-Oct 18 15 22 18 16 19VS2-LWF-13B-COMP2B 10-Oct 28-Oct 25-Oct 1-Nov 28-Oct 26-Oct 29-Oct 18 15 22 18 16 19VS2-LWF-13B-COMP2BDUPLICATE10-Oct 28-Oct 25-Oct 1-Nov 28-Oct 26-Oct 29-Oct 18 15 22 18 16 19VS2-LWF-13B-COMP2C 10-Oct 28-Oct 25-Oct 1-Nov 28-Oct 26-Oct 29-Oct 18 15 22 18 16 19VS2-LWF-15B-COMP2A 30-Oct 26-Nov 25-Nov 26-Nov 26-Nov 27-Nov 26-Nov 27 26 27 27 28 27DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013 Page 6 of 22SampleDateAnalysis DateHolding Time (DaysAshContentDensityGrossCalorificValueKinematicViscosityPercentMoistureTotalChlorineAshContentDensityGrossCalorificValueKinematicViscosityPercentMoistureTotalChlorineVS2-LWF-15B-COMP2B 30-Oct 26-Nov 25-Nov 26-Nov 26-Nov 27-Nov 26-Nov 27 26 27 27 28 27VS2-LWF-15B-COMP2C 30-Oct 26-Nov 25-Nov 26-Nov 26-Nov 27-Nov 26-Nov 27 26 27 27 28 27VS3-CS-11A-COMP 1 15-Oct 11-Nov -- 9-Nov -- 22-Oct 12-Nov 27 -- 25 -- 7 28VS3-CS-12A-COMP 1 16-Oct 11-Nov -- 9-Nov -- 22-Oct 12-Nov 26 -- 24 -- 6 27VS3-CS-12B-COMP 2A 16-Oct 11-Nov -- 9-Nov -- 22-Oct 12-Nov 26 -- 24 -- 6 27VS3-CS-12B-COMP 2B 16-Oct 11-Nov -- 9-Nov -- 22-Oct 12-Nov 26 -- 24 -- 6 27VS3-CS-12B-COMP 2C 16-Oct 11-Nov -- 9-Nov -- 22-Oct 12-Nov 26 -- 24 -- 6 27VS3-CS-13A-COMP 1 17-Oct 11-Nov -- 9-Nov -- 22-Oct 12-Nov 25 -- 23 -- 5 26VS3-CS-13B-COMP 2A 17-Oct 11-Nov -- 9-Nov -- 22-Oct 12-Nov 25 -- 23 -- 5 26VS3-CS-13B-COMP 2B 17-Oct 11-Nov -- 9-Nov -- 22-Oct 12-Nov 25 -- 23 -- 5 26VS3-CS-13B-COMP 2C 17-Oct 11-Nov -- 9-Nov -- 22-Oct 12-Nov 25 -- 23 -- 5 26VS3-CS-14B-COMP 2A 18-Oct 11-Nov -- 9-Nov -- 22-Oct 12-Nov 24 -- 22 -- 4 25VS3-CS-14B-COMP 2B 18-Oct 11-Nov -- 9-Nov -- 22-Oct 12-Nov 24 -- 22 -- 4 25VS3-CS-14B-COMP 2C 18-Oct 11-Nov -- 9-Nov -- 22-Oct 12-Nov 24 -- 22 -- 4 25VS3-HBW-11A-COMP 1 15-Oct 6-Nov 1-Nov 11-Nov 1-Nov 10-Nov 5-Nov 22 17 27 17 26 21VS3-HBW-12A-COMP 1 16-Oct 6-Nov 1-Nov 11-Nov 1-Nov 10-Nov 5-Nov 21 16 26 16 25 20VS3-HBW-12B-COMP 2A 16-Oct 6-Nov 1-Nov 11-Nov 1-Nov 10-Nov 5-Nov 21 16 26 16 25 20VS3-HBW-12B-COMP 2B 16-Oct 6-Nov 1-Nov 11-Nov 1-Nov 10-Nov 5-Nov 21 16 26 16 25 20VS3-HBW-12B-COMP 2BDUP16-Oct 6-Nov 1-Nov 11-Nov 4-Nov 10-Nov 5-Nov 21 16 26 19 25 20VS3-HBW-12B-COMP 2C 16-Oct 6-Nov 1-Nov 11-Nov 4-Nov 10-Nov 5-Nov 21 16 26 19 25 20VS3-HBW-13A-COMP 1 17-Oct 6-Nov 1-Nov 11-Nov 4-Nov 10-Nov 5-Nov 20 15 25 18 24 19VS3-HBW-13B-COMP 2A 17-Oct 6-Nov 1-Nov 11-Nov 4-Nov 10-Nov 5-Nov 20 15 25 18 24 19VS3-HBW-13B-COMP 2B 17-Oct 6-Nov 1-Nov 11-Nov 4-Nov 10-Nov 5-Nov 20 15 25 18 24 19VS3-HBW-13B-COMP 2C 17-Oct 6-Nov 1-Nov 11-Nov 4-Nov 10-Nov 5-Nov 20 15 25 18 24 19VS3-HBW-14B-COMP 2A 18-Oct 6-Nov 1-Nov 11-Nov 4-Nov 10-Nov 5-Nov 19 14 24 17 23 18VS3-HBW-14B-COMP 2B 18-Oct 6-Nov 1-Nov 11-Nov 4-Nov 10-Nov 5-Nov 19 14 24 17 23 18VS3-HBW-14B-COMP 2C 18-Oct 6-Nov 1-Nov 11-Nov 4-Nov 10-Nov 5-Nov 19 14 24 17 23 18VS3-LBW-11A-COMP 1 15-Oct 6-Nov 6-Nov 11-Nov 13-Nov 8-Nov 5-Nov 22 22 27 29 24 21VS3-LBW-12A-COMP 1 16-Oct 6-Nov 6-Nov 11-Nov 13-Nov 8-Nov 7-Nov 21 21 26 28 23 22DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013 Page 7 of 22SampleDateAnalysis DateHolding Time (DaysAshContentDensityGrossCalorificValueKinematicViscosityPercentMoistureTotalChlorineAshContentDensityGrossCalorificValueKinematicViscosityPercentMoistureTotalChlorineVS3-LBW-12B-COMP 2A 16-Oct 6-Nov 6-Nov 11-Nov 13-Nov 8-Nov 7-Nov 21 21 26 28 23 22VS3-LBW-12B-COMP 2B 16-Oct 6-Nov 6-Nov 11-Nov 13-Nov 8-Nov 7-Nov 21 21 26 28 23 22VS3-LBW-12B-COMP 2BDUP16-Oct 6-Nov 6-Nov 12-Nov 13-Nov 8-Nov 7-Nov 21 21 27 28 23 22VS3-LBW-12B-COMP 2C 16-Oct 6-Nov 6-Nov 11-Nov 13-Nov 8-Nov 7-Nov 21 21 26 28 23 22VS3-LBW-13A-COMP 1 17-Oct 6-Nov 6-Nov 11-Nov 13-Nov 8-Nov 7-Nov 20 20 25 27 22 21VS3-LBW-13B-COMP 2A 17-Oct 6-Nov 6-Nov 11-Nov 13-Nov 8-Nov 7-Nov 20 20 25 27 22 21VS3-LBW-13B-COMP 2B 17-Oct 6-Nov 6-Nov 12-Nov 13-Nov 8-Nov 7-Nov 20 20 26 27 22 21VS3-LBW-13B-COMP 2C 17-Oct 6-Nov 6-Nov 12-Nov 13-Nov 8-Nov 7-Nov 20 20 26 27 22 21VS3-LBW-14B-COMP 2A 18-Oct 6-Nov 6-Nov 12-Nov 13-Nov 8-Nov 7-Nov 19 19 25 26 21 20VS3-LBW-14B-COMP 2B 18-Oct 6-Nov 6-Nov 12-Nov 13-Nov 8-Nov 7-Nov 19 19 25 26 21 20VS3-LBW-14B-COMP 2C 18-Oct 6-Nov 6-Nov 12-Nov 13-Nov 8-Nov 7-Nov 19 19 25 26 21 20VS3-LWF-11A-COMP 1 15-Oct 11-Nov 11-Nov 12-Nov 12-Nov 13-Nov 7-Nov 27 27 28 28 29 23VS3-LWF-12A-COMP 1 16-Oct 11-Nov 11-Nov 12-Nov 12-Nov 13-Nov 7-Nov 26 26 27 27 28 22VS3-LWF-12B-COMP 2A 16-Oct 11-Nov 11-Nov 12-Nov 12-Nov 13-Nov 7-Nov 26 26 27 27 28 22VS3-LWF-12B-COMP 2B 16-Oct 11-Nov 11-Nov 12-Nov 12-Nov 13-Nov 11-Nov 26 26 27 27 28 26VS3-LWF-12B-COMP 2BDUP16-Oct 11-Nov 11-Nov 12-Nov 12-Nov 13-Nov 11-Nov 26 26 27 27 28 26VS3-LWF-12B-COMP 2C 16-Oct 11-Nov 11-Nov 12-Nov 12-Nov 13-Nov 11-Nov 26 26 27 27 28 26VS3-LWF-13A-COMP 1 17-Oct 11-Nov 11-Nov 12-Nov 12-Nov 13-Nov 11-Nov 25 25 26 26 27 25VS3-LWF-13B-COMP 2A 17-Oct 11-Nov 11-Nov 12-Nov 12-Nov 13-Nov 11-Nov 25 25 26 26 27 25VS3-LWF-13B-COMP 2B 17-Oct 11-Nov 11-Nov 12-Nov 12-Nov 13-Nov 11-Nov 25 25 26 26 27 25VS3-LWF-13B-COMP 2C 17-Oct 11-Nov 11-Nov 12-Nov 12-Nov 13-Nov 11-Nov 25 25 26 26 27 25VS3-LWF-14B-COMP 2A 18-Oct 11-Nov 11-Nov 12-Nov 12-Nov 13-Nov 11-Nov 24 24 25 25 26 24VS3-LWF-14B-COMP 2B 18-Oct 11-Nov 11-Nov 12-Nov 12-Nov 13-Nov 11-Nov 24 24 25 25 26 24VS3-LWF-14B-COMP 2C 18-Oct 11-Nov 11-Nov 12-Nov 12-Nov 13-Nov 11-Nov 24 24 25 25 26 24VS4-BS-11A-COMP1 23-Oct 17-Nov -- 21-Nov -- 5-Nov 18-Nov 25 -- 29 -- 13 26VS4-BS-11B-COMP2A 23-Oct 17-Nov -- 21-Nov -- 5-Nov 18-Nov 25 -- 29 -- 13 26VS4-BS-11B-COMP2B 23-Oct 17-Nov -- 21-Nov -- 5-Nov 18-Nov 25 -- 29 -- 13 26VS4-BS-11B-COMP2C 23-Oct 17-Nov -- 21-Nov -- 5-Nov 18-Nov 25 -- 29 -- 13 26DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013 Page 8 of 22SampleDateAnalysis DateHolding Time (DaysAshContentDensityGrossCalorificValueKinematicViscosityPercentMoistureTotalChlorineAshContentDensityGrossCalorificValueKinematicViscosityPercentMoistureTotalChlorineVS4-BS-12A-COMP1 24-Oct 17-Nov -- 21-Nov -- 5-Nov 18-Nov 24 -- 28 -- 12 25VS4-BS-12B-COMP2A 24-Oct 17-Nov -- 21-Nov -- 5-Nov 18-Nov 24 -- 28 -- 12 25VS4-BS-12B-COMP2B 24-Oct 22-Nov -- 21-Nov -- 5-Nov 18-Nov 29 -- 28 -- 12 25VS4-BS-12B-COMP2C 24-Oct 22-Nov -- 21-Nov -- 5-Nov 18-Nov 29 -- 28 -- 12 25VS4-BS-13A-COMP1 25-Oct 22-Nov -- 21-Nov -- 5-Nov 18-Nov 28 -- 27 -- 11 24VS4-BS-13B-COMP2A 25-Oct 22-Nov -- 21-Nov -- 5-Nov 18-Nov 28 -- 27 -- 11 24VS4-BS-13B-COMP2B 25-Oct 22-Nov -- 21-Nov -- 5-Nov 18-Nov 28 -- 27 -- 11 24VS4-BS-13B-COMP2C 25-Oct 22-Nov -- 21-Nov -- 5-Nov 18-Nov 28 -- 27 -- 11 24VS4-BS-14A-COMP1 25-Oct 22-Nov -- 21-Nov -- 5-Nov 18-Nov 28 -- 27 -- 11 24VS4-CS-11A-COMP1 23-Oct 18-Nov -- 20-Nov -- 5-Nov 15-Nov 26 -- 28 -- 13 23VS4-CS-11B-COMP2A 23-Oct 17-Nov -- 20-Nov -- 5-Nov 15-Nov 25 -- 28 -- 13 23VS4-CS-11B-COMP2B 23-Oct 18-Nov -- 20-Nov -- 5-Nov 15-Nov 26 -- 28 -- 13 23VS4-CS-11B-COMP2C 23-Oct 18-Nov -- 20-Nov -- 5-Nov 15-Nov 26 -- 28 -- 13 23VS4-CS-12A-COMP1 24-Oct 17-Nov -- 20-Nov -- 5-Nov 15-Nov 24 -- 27 -- 12 22VS4-CS-12B-COMP2A 24-Oct 17-Nov -- 20-Nov -- 5-Nov 15-Nov 24 -- 27 -- 12 22VS4-CS-12B-COMP2B 24-Oct 18-Nov -- 20-Nov -- 5-Nov 15-Nov 25 -- 27 -- 12 22VS4-CS-12B-COMP2C 24-Oct 17-Nov -- 20-Nov -- 5-Nov 15-Nov 24 -- 27 -- 12 22VS4-CS-13A-COMP1 25-Oct 18-Nov -- 20-Nov -- 5-Nov 15-Nov 24 -- 26 -- 11 21VS4-CS-13B-COMP2A 25-Oct 18-Nov -- 20-Nov -- 5-Nov 15-Nov 24 -- 26 -- 11 21VS4-CS-13B-COMP2B 25-Oct 18-Nov -- 21-Nov -- 5-Nov 15-Nov 24 -- 27 -- 11 21VS4-CS-13B-COMP2C 25-Oct 18-Nov -- 21-Nov -- 5-Nov 15-Nov 24 -- 27 -- 11 21VS4-CS-14A-COMP1 25-Oct 17-Nov -- 21-Nov -- 5-Nov 15-Nov 23 -- 27 -- 11 21VS4-HBW-11A-COMP1 23-Oct 17-Nov 18-Nov 19-Nov 20-Nov 19-Nov 14-Nov 25 26 27 28 27 22VS4-HBW-11B-COMP2A 23-Oct 17-Nov 18-Nov 19-Nov 20-Nov 19-Nov 14-Nov 25 26 27 28 27 22VS4-HBW-11B-COMP2B 23-Oct 17-Nov 18-Nov 19-Nov 20-Nov 19-Nov 14-Nov 25 26 27 28 27 22VS4-HBW-11B-COMP2C 23-Oct 18-Nov 18-Nov 19-Nov 20-Nov 19-Nov 14-Nov 26 26 27 28 27 22VS4-HBW-12A-COMP1 24-Oct 18-Nov 18-Nov 19-Nov 21-Nov 19-Nov 14-Nov 25 25 26 28 26 21VS4-HBW-12B-COMP2A 24-Oct 18-Nov 18-Nov 19-Nov 21-Nov 19-Nov 14-Nov 25 25 26 28 26 21VS4-HBW-12B-COMP2B 24-Oct 18-Nov 18-Nov 19-Nov 21-Nov 19-Nov 14-Nov 25 25 26 28 26 21DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013 Page 9 of 22SampleDateAnalysis DateHolding Time (DaysAshContentDensityGrossCalorificValueKinematicViscosityPercentMoistureTotalChlorineAshContentDensityGrossCalorificValueKinematicViscosityPercentMoistureTotalChlorineVS4-HBW-12B-COMP2BDUP24-Oct 18-Nov 18-Nov 19-Nov 21-Nov 19-Nov 14-Nov 25 25 26 28 26 21VS4-HBW-12B-COMP2C 24-Oct 17-Nov 18-Nov 19-Nov 21-Nov 19-Nov 14-Nov 24 25 26 28 26 21VS4-HBW-13A-COMP1 25-Oct 18-Nov 18-Nov 19-Nov 21-Nov 19-Nov 14-Nov 24 24 25 27 25 20VS4-HBW-13B-COMP2A 25-Oct 18-Nov 18-Nov 19-Nov 21-Nov 19-Nov 14-Nov 24 24 25 27 25 20VS4-HBW-13B-COMP2B 25-Oct 18-Nov 18-Nov 19-Nov 21-Nov 19-Nov 14-Nov 24 24 25 27 25 20VS4-HBW-13B-COMP2C 25-Oct 18-Nov 18-Nov 19-Nov 21-Nov 19-Nov 14-Nov 24 24 25 27 25 20VS4-HBW-14A-COMP1 25-Oct 17-Nov 18-Nov 19-Nov 21-Nov 19-Nov 14-Nov 23 24 25 27 25 20VS4-LBW-11A-COMP1 23-Oct 18-Nov 18-Nov 19-Nov 21-Nov 21-Nov 19-Nov 26 26 27 29 29 27VS4-LBW-11B-COMP2A 23-Oct 17-Nov 18-Nov 19-Nov 21-Nov 21-Nov 19-Nov 25 26 27 29 29 27VS4-LBW-11B-COMP2B 23-Oct 17-Nov 18-Nov 19-Nov 21-Nov 21-Nov 19-Nov 25 26 27 29 29 27VS4-LBW-11B-COMP2C 23-Oct 18-Nov 18-Nov 19-Nov 21-Nov 21-Nov 19-Nov 26 26 27 29 29 27VS4-LBW-12A-COMP1 24-Oct 18-Nov 18-Nov 19-Nov 21-Nov 21-Nov 19-Nov 25 25 26 28 28 26VS4-LBW-12B-COMP2A 24-Oct 18-Nov 19-Nov 20-Nov 22-Nov 21-Nov 19-Nov 25 26 27 29 28 26VS4-LBW-12B-COMP2B 24-Oct 21-Nov 19-Nov 20-Nov 22-Nov 21-Nov 20-Nov 28 26 27 29 28 27VS4-LBW-12B-COMP2BDUP24-Oct 21-Nov 19-Nov 20-Nov 22-Nov 21-Nov 20-Nov 28 26 27 29 28 27VS4-LBW-12B-COMP2C 24-Oct 21-Nov 19-Nov 20-Nov 22-Nov 21-Nov 20-Nov 28 26 27 29 28 27VS4-LBW-13A-COMP1 25-Oct 21-Nov 19-Nov 20-Nov 22-Nov 21-Nov 20-Nov 27 25 26 28 27 26VS4-LBW-13B-COMP2A 25-Oct 21-Nov 19-Nov 20-Nov 22-Nov 21-Nov 20-Nov 27 25 26 28 27 26VS4-LBW-13B-COMP2B 25-Oct 21-Nov 19-Nov 20-Nov 22-Nov 21-Nov 20-Nov 27 25 26 28 27 26VS4-LBW-13B-COMP2C 25-Oct 21-Nov 19-Nov 20-Nov 22-Nov 21-Nov 20-Nov 27 25 26 28 27 26VS4-LBW-14A-COMP1 25-Oct 21-Nov 19-Nov 20-Nov 22-Nov 21-Nov 20-Nov 27 25 26 28 27 26VS4-LWF-11A-COMP1 23-Oct 21-Nov 19-Nov 18-Nov 20-Nov 18-Nov 19-Nov 29 27 26 28 26 27VS4-LWF-11B-COMP2A 23-Oct 21-Nov 19-Nov 18-Nov 20-Nov 18-Nov 19-Nov 29 27 26 28 26 27VS4-LWF-11B-COMP2B 23-Oct 21-Nov 19-Nov 18-Nov 20-Nov 18-Nov 19-Nov 29 27 26 28 26 27VS4-LWF-11B-COMP2C 23-Oct 21-Nov 19-Nov 18-Nov 20-Nov 18-Nov 19-Nov 29 27 26 28 26 27VS4-LWF-12A-COMP1 24-Oct 21-Nov 19-Nov 18-Nov 20-Nov 18-Nov 19-Nov 28 26 25 27 25 26VS4-LWF-12B-COMP2A 24-Oct 21-Nov 19-Nov 18-Nov 20-Nov 18-Nov 19-Nov 28 26 25 27 25 26VS4-LWF-12B-COMP2B 24-Oct 21-Nov 19-Nov 18-Nov 20-Nov 18-Nov 19-Nov 28 26 25 27 25 26DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013 Page 10 of 22SampleDateAnalysis DateHolding Time (DaysAshContentDensityGrossCalorificValueKinematicViscosityPercentMoistureTotalChlorineAshContentDensityGrossCalorificValueKinematicViscosityPercentMoistureTotalChlorineVS4-LWF-12B-COMP2BDUP24-Oct 21-Nov 19-Nov 19-Nov 21-Nov 18-Nov 19-Nov 28 26 26 28 25 26VS4-LWF-12B-COMP2C 24-Oct 21-Nov 19-Nov 18-Nov 20-Nov 18-Nov 19-Nov 28 26 25 27 25 26VS4-LWF-13A-COMP1 25-Oct 21-Nov 19-Nov 19-Nov 21-Nov 18-Nov 19-Nov 27 25 25 27 24 25VS4-LWF-13B-COMP2A 25-Oct 21-Nov 19-Nov 19-Nov 21-Nov 18-Nov 19-Nov 27 25 25 27 24 25VS4-LWF-13B-COMP2B 25-Oct 21-Nov 19-Nov 19-Nov 21-Nov 18-Nov 19-Nov 27 25 25 27 24 25VS4-LWF-13B-COMP2C 25-Oct 21-Nov 19-Nov 19-Nov 21-Nov 18-Nov 19-Nov 27 25 25 27 24 25VS4-LWF-14A-COMP1 25-Oct 21-Nov 19-Nov 19-Nov 21-Nov 18-Nov 19-Nov 27 25 25 27 24 25DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 11 of 22 

## Laboratory Blank Results

A nalytical Result (mg/kg) Ash Content Total Chlorine Laboratory Blank; Batch 3288047 -- <60 Laboratory Blank; Batch 3291011 -- <60 Laboratory Blank; Batch 3294027 <51 -- Laboratory Blank; Batch 3295055 -- <60 Laboratory Blank; Batch 3296018 <51 -- Laboratory Blank; Batch 3297012 -- <60 Laboratory Blank; Batch 3297044 <51 -- Laboratory Blank; Batch 3297045 <51 -- Laboratory Blank; Batch 3304037 <51 -- Laboratory Blank; Batch 3305056 <51 -- Laboratory Blank; Batch 3305068 -- <60 Laboratory Blank; Batch 3309048 -- <60 Laboratory Blank; Batch 3310040 -- <60 Laboratory Blank; Batch 3311015 -- <60 Laboratory Blank; Batch 3311046 <51 -- Laboratory Blank; Batch 3311049 <51 -- Laboratory Blank; Batch 3316041 -- <60 Laboratory Blank; Batch 3316044 -- <60 Laboratory Blank; Batch 3318019 57 -- Laboratory Blank; Batch 3318020 150 -- Laboratory Blank; Batch 3318038 -- <60 Laboratory Blank; Batch 3319020 -- <60 Laboratory Blank; Batch 3320010 -- <60 Laboratory Blank; Batch 3323036 <51 -- Laboratory Blank; Batch 3323037 <51 -- Laboratory Blank; Batch 3323038 <51 -- Laboratory Blank; Batch 3328014 -- <60 Laboratory Blank; Batch 3328015 -- <60 Laboratory Blank; Batch 3328016 90 -- Laboratory Blank; Batch 3328017 <51 --DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 12 of 22 

## Laboratory Check Sample (LCS) and Laboratory Check Sample Duplicate (LCSD) R esults

A sh Content Density Gross

Calorific Value Kinematic Viscosity Percent

Water Total Chlorine

Laboratory (and QAPP) Specifications Recovery (%) 90-110 99-101 98-102 99-101 95-105 80-120 RPD (%) 10 -- 2 5 -- LCS; Batch 3288047 LCS Recovery, % -- -- -- -- -- 101 LCS/LCSD; Batch 3289046 LCS Recovery, % -- -- 100 -- -- -- LCSD Recovery, % -- -- 100 -- -- -- RPD 1 , % -- -- 0.23 -- -- -- LCS; Batch 3291011 LCS Recovery, % -- -- -- -- -- 94
LCS/LCSD; Batch 3294014 LCS Recovery, % -- -- 100 -- -- -- LCSD Recovery, % -- -- 100 -- -- -- RPD, % -- -- 0.06 -- -- --
LCS/LCSD; Batch 3294027 LCS Recovery, % 99 -- -- -- -- -- LCSD Recovery, % 99 -- -- -- -- -- RPD, % 0.3 -- -- -- -- -- LCS/LCSD; Batch 3294063 LCS Recovery, % -- -- -- -- 99 -- LCSD Recovery, % -- -- -- -- 100 -- RPD, % -- -- -- -- 0.97 -- LCS; Batch 3295055 LCS Recovery, % -- -- -- -- -- 92
LCS/LCSD; Batch 3296018 LCS Recovery, % 99 -- -- -- -- -- LCSD Recovery, % 98 -- -- -- -- -- RPD, % 1.1 -- -- -- -- -- LCS; Batch 3296033 LCS Recovery, % -- -- -- 100 -- -- LCS; Batch 3296034 LCS Recovery, % -- 100 -- -- -- -- LCS; Batch 3297012 LCS Recovery, % -- -- -- -- -- 97 LCS/LCSD; Batch 3297044 LCS Recovery, % 97 -- -- -- -- -- LCSD Recovery, % 98 -- -- -- -- -- RPD, % 1.3 -- -- -- -- --
LCS/LCSD; Batch 3297045 LCS Recovery, % 99 -- -- -- -- -- LCSD Recovery, % 98 -- -- -- -- -- RPD, % 0.91 -- -- -- -- -- LCS; Batch 3298024 LCS Recovery, % -- 100 -- -- -- --
LCS/LCSD; Batch 3298026 LCS Recovery, % -- -- 100 -- -- -- LCSD Recovery, % -- -- 100 -- -- -- RPD, % -- -- 0.05 -- -- -- LCS/LCSD; Batch 3298030 LCS Recovery, % -- -- -- -- 99 -- LCSD Recovery, % -- -- -- -- 99 -- RPD, % -- -- -- -- 0.54 -- LCS; Batch 3301015 LCS Recovery, % -- -- -- 100 -- -- LCS; Batch 3301016 LCS Recovery, % -- -- -- 100 -- -- LCS/LCSD; Batch 3302022 LCS Recovery, % -- -- 100 -- -- -- LCSD Recovery, % -- -- 100 -- -- -- RPD, % -- -- 0.01 -- -- -- LCS; Batch 3304034 LCS Recovery, % -- 100 -- -- -- -- LCS; Batch 3304036 LCS Recovery, % -- -- -- 100 -- --

1 RPD – Relative Percent DifferenceDQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 13 of 22 

### Ash Content Density Gross

Calorific Value Kinematic Viscosity Percent

Water Total Chlorine

Laboratory (and QAPP) Specifications Recovery (%) 90-110 99-101 98-102 99-101 95-105 80-120 RPD (%) 10 -- 2 5 --
LCS/LCSD; Batch 3304037 LCS Recovery, % 100 -- -- -- -- -- LCSD Recovery, % 100 -- -- -- -- -- RPD, % 0.22 -- -- -- -- --
LCS/LCSD; Batch 3305056 LCS Recovery, % 101 -- -- -- -- -- LCSD Recovery, % 100 -- -- -- -- -- RPD, % 0.59 -- -- -- -- --
LCS/LCSD; Batch 3305057 LCS Recovery, % -- -- -- -- 98 -- LCSD Recovery, % -- -- -- -- 100 -- RPD, % -- -- -- -- 1.7 -- LCS; Batch 3305068 LCS Recovery, % -- -- -- -- -- 95 LCS; Batch 3309044 LCS Recovery, % -- 100 -- -- -- -- LCS; Batch 3309045 LCS Recovery, % -- -- -- 100 -- -- LCS; Batch 3309048 LCS Recovery, % -- -- -- -- -- 98 LCS; Batch 3310040 LCS Recovery, % -- -- -- -- -- 95 LCS; Batch 3311015 LCS Recovery, % -- -- -- -- -- 95 LCS/LCSD; Batch 3311040 LCS Recovery, % -- -- -- -- 102 -- LCSD Recovery, % -- -- -- -- 100 -- RPD, % -- -- -- -- 1.5 --
LCS/LCSD; Batch 3311042 LCS Recovery, % -- -- 100 -- -- -- LCSD Recovery, % -- -- 100 -- -- -- RPD, % -- -- 0.09 -- -- --
LCS/LCSD; Batch 3311046 LCS Recovery, % 101 -- -- -- -- -- LCSD Recovery, % 100 -- -- -- -- -- RPD, % 1.1 -- -- -- -- --
LCS/LCSD; Batch 3311049 LCS Recovery, % 102 -- -- -- -- -- LCSD Recovery, % 101 -- -- -- -- -- RPD, % 1.1 -- -- -- -- --
LCS/LCSD; Batch 3312052 LCS Recovery, % -- -- -- -- 97 -- LCSD Recovery, % -- -- -- -- 99 -- RPD, % -- -- -- -- 1.3 -- LCS/LCSD; Batch 3314010 LCS Recovery, % -- -- 100 -- -- -- LCSD Recovery, % -- -- 100 -- -- -- RPD, % -- -- 0.04 -- -- --
LCS/LCSD; Batch 3314011 LCS Recovery, % -- -- 100 -- -- -- LCSD Recovery, % -- -- 100 -- -- -- RPD, % -- -- 0.24 -- -- -- LCS; Batch 3315023 LCS Recovery, % -- 100 -- -- -- -- LCS; Batch 3316017 LCS Recovery, % -- -- -- 99 -- -- LCS; Batch 3316041 LCS Recovery, % -- -- -- -- -- 91 LCS; Batch 3316044 LCS Recovery, % -- -- -- -- -- 98 LCS/LCSD; Batch 3317013 LCS Recovery, % -- -- -- -- 98 -- LCSD Recovery, % -- -- -- -- 99 -- RPD, % -- -- -- -- 0.97 --
LCS/LCSD; Batch 3318019 LCS Recovery, % 108 -- -- -- -- -- LCSD Recovery, % 110 -- -- -- -- -- RPD, % 2 -- -- -- -- --DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 14 of 22 

### Ash Content Density Gross

Calorific Value Kinematic Viscosity Percent

Water Total Chlorine

Laboratory (and QAPP) Specifications Recovery (%) 90-110 99-101 98-102 99-101 95-105 80-120 RPD (%) 10 -- 2 5 --
LCS/LCSD; Batch 3318020 LCS Recovery, % 103 -- -- -- -- -- LCSD Recovery, % 105 -- -- -- -- -- RPD, % 2 -- -- -- -- -- LCS; Batch 3318021 LCS Recovery, % -- 100 -- -- -- -- LCS; Batch 3318038 LCS Recovery, % -- -- -- -- -- 96 LCS; Batch 3319020 LCS Recovery, % -- -- -- -- -- 97 LCS; Batch 3320010 LCS Recovery, % -- -- -- -- -- 97 LCS/LCSD; Batch 3321010 LCS Recovery, % -- -- -- -- 101 -- LCSD Recovery, % -- -- -- -- 100 -- RPD, % -- -- -- -- 1.2 --
LCS/LCSD; Batch 3322015 LCS Recovery, % -- -- 100 -- -- -- LCSD Recovery, % -- -- 100 -- -- -- RPD, % -- -- 0.05 -- -- -- LCS; Batch 3322032 LCS Recovery, % -- 100 -- -- -- -- LCS; Batch 3322033 LCS Recovery, % -- 100 -- -- -- -- LCS/LCSD; Batch 3322037 LCS Recovery, % -- -- 100 -- -- -- LCSD Recovery, % -- -- 100 -- -- -- RPD, % -- -- 0.06 -- -- --
LCS/LCSD; Batch 3322038 LCS Recovery, % -- -- -- -- 102 -- LCSD Recovery, % -- -- -- -- 101 -- RPD, % -- -- -- -- 1.1 -- LCS; Batch 3323034 LCS Recovery, % -- -- -- 100 -- -- LCS/LCSD; Batch 3323036 LCS Recovery, % 103 -- -- -- -- -- LCSD Recovery, % 103 -- -- -- -- -- RPD, % 0.12 -- -- -- -- --
LCS/LCSD; Batch 3323037 LCS Recovery, % 103 -- -- -- -- -- LCSD Recovery, % 103 -- -- -- -- -- RPD, % 0.12 -- -- -- -- -- LCS/LCSD; Batch 3323038 LCS Recovery, % 103 -- -- -- -- -- LCSD Recovery, % 101 -- -- -- -- -- RPD, % 1.8 -- -- -- -- -- LCS/LCSD; Batch 3323063 LCS Recovery, % -- -- 99 -- -- -- LCSD Recovery, % -- -- 100 -- -- -- RPD, % -- -- 0.3 -- -- --
LCS/LCSD; Batch 3323064 LCS Recovery, % -- -- 99 -- -- -- LCSD Recovery, % -- -- 100 -- -- -- RPD, % -- -- 0.26 -- -- -- LCS/LCSD; Batch 3323065 LCS Recovery, % -- -- 100 -- -- -- LCSD Recovery, % -- -- 100 -- -- -- RPD, % -- -- 0.12 -- -- -- LCS; Batch 3324028 LCS Recovery, % -- -- -- 100 -- -- LCS; Batch 3324029 LCS Recovery, % -- -- -- 100 -- --
LCS/LCSD; Batch 3325013 LCS Recovery, % -- -- -- -- 101 -- LCSD Recovery, % -- -- -- -- 99 -- RPD, % -- -- -- -- 1.8 -- LCS; Batch 3328011 LCS Recovery, % -- -- -- 99 -- -- LCS; Batch 3328012 LCS Recovery, % -- 100 -- -- -- --DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 15 of 22 

### Ash Content Density Gross

Calorific Value Kinematic Viscosity Percent

Water Total Chlorine

Laboratory (and QAPP) Specifications Recovery (%) 90-110 99-101 98-102 99-101 95-105 80-120 RPD (%) 10 -- 2 5 -- LCS; Batch 3328014 LCS Recovery, % -- -- -- -- -- 95 LCS; Batch 3328015 LCS Recovery, % -- -- -- -- -- 94
LCS/LCSD; Batch 3328016 LCS Recovery, % 107 -- -- -- -- -- LCSD Recovery, % 102 -- -- -- -- -- RPD, % 5.2 -- -- -- -- -- LCS/LCSD; Batch 3328017 LCS Recovery, % 105 -- -- -- -- -- LCSD Recovery, % 110 -- -- -- -- -- RPD, % 4.5 -- -- -- -- -- LCS/LCSD; Batch 3330010 LCS Recovery, % -- -- 100 -- -- -- LCSD Recovery, % -- -- 100 -- -- -- RPD, % -- -- 0.22 -- -- --
LCS/LCSD; Batch 3330011 LCS Recovery, % -- -- 100 -- -- -- LCSD Recovery, % -- -- 100 -- -- -- RPD, % -- -- 0.09 -- -- -- LCS/LCSD; Batch 3330016 LCS Recovery, % -- -- -- -- 101 -- LCSD Recovery, % -- -- -- -- 99 -- RPD, % -- -- -- -- 1.8 -- LCS; Batch 3288047 LCS Recovery, % -- -- -- -- -- 101DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 16 of 22 

## Matrix Spike (MS) and Matrix Spike Duplicate (MSD) Results

To tal Chlorine
Laboratory and QAPP Specification Recovery (%) 80-120 RPD (%) 10

VS2-CS-11B-COMP2B Sample Result (mg/kg) 167 Spike Amount (mg/kg) 9900 MS Result (mg/kg) 9610 MSD Result (mg/kg) 9570 MS Recovery (%) 95 MSD Recovery (%) 95 RPD (%) 1 0.49

VS2-CS-15B-COMP2B Sample Result (mg/kg) 396 Spike Amount (mg/kg) 9930 MS Result (mg/kg) 9250 MSD Result (mg/kg) 9560 MS Recovery (%) 89 MSD Recovery (%) 92 RPD (%) 3.3

VS2-HBW-13B-COMP2B Sample Result (mg/kg) 3210 Spike Amount (mg/kg) 11000 MS Result (mg/kg) 13600 MSD Result (mg/kg) 13800 MS Recovery (%) 95 MSD Recovery (%) 95 RPD (%) 1.5

VS2-HBW-15B-COMP2B Sample Result (mg/kg) 3580 Spike Amount (mg/kg) 9840 MS Result (mg/kg) 12800 MSD Result (mg/kg) 13000 MS Recovery (%) 94 MSD Recovery (%) 94 RPD (%) 1.3

VS2-LBW-13B-COMP2B Sample Result (mg/kg) 364 Spike Amount (mg/kg) 9970 MS Result (mg/kg) 9820 MSD Result (mg/kg) 9710 MS Recovery (%) 95 MSD Recovery (%) 94 RPD (%) 1.2

1 RPD – Relative Percent DifferenceDQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 17 of 22 

### Total Chlorine
Laboratory and QAPP Specification Recovery (%) 80-120 RPD (%) 10

VS2-LBW-15B-COMP2B Sample Result (mg/kg) 357 Spike Amount (mg/kg) 9,850 MS Result (mg/kg) 9,600 MSD Result (mg/kg) 9,800 MS Recovery (%) 94 MSD Recovery (%) 95 RPD (%) 2.1

VS2-LWF-13B-COMP2B Sample Result (mg/kg) 124 Spike Amount (mg/kg) 9,890 MS Result (mg/kg) 10,100 MSD Result (mg/kg) 9,630 MS Recovery (%) 101 MSD Recovery (%) 96 RPD (%) 4.8

VS2-LWF-15B-COMP2B Sample Result (mg/kg) 92.4 Spike Amount (mg/kg) 9,960 MS Result (mg/kg) 9,400 MSD Result (mg/kg) 9,430 MS Recovery (%) 93 MSD Recovery (%) 94 RPD (%) 0.37

VS3-CS-12B-COMP 2B Sample Result (mg/kg) 195 Spike Amount (mg/kg) 9,930 MS Result (mg/kg) 9,540 MSD Result (mg/kg) 9,530 MS Recovery (%) 94 MSD Recovery (%) 93 RPD (%) 0.1

VS3-HBW-12B-COMP 2B Sample Result (mg/kg) 2,720 Spike Amount (mg/kg) 10,000 MS Result (mg/kg) 12,300 MSD Result (mg/kg) 12,400 MS Recovery (%) 96 MSD Recovery (%) 96 RPD (%) 0.4

VS3-LBW-13B-COMP 2B Sample Result (mg/kg) 429 Spike Amount (mg/kg) 9,980 MS Result (mg/kg) 9,750 MSD Result (mg/kg) 9,640 MS Recovery (%) 93 MSD Recovery (%) 93 RPD (%) 1.1DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 18 of 22 

### Total Chlorine
Laboratory and QAPP Specification Recovery (%) 80-120 RPD (%) 10

VS3-LWF-12B-COMP 2B Sample Result (mg/kg) 696 Spike Amount (mg/kg) 9,930 MS Result (mg/kg) 10,000 MSD Result (mg/kg) 9,960 MS Recovery (%) 94 MSD Recovery (%) 95 RPD (%) 0.71

VS4-BS-14A-COMP1 Sample Result (mg/kg) 164 Spike Amount (mg/kg) 9,920 MS Result (mg/kg) 9,110 MSD Result (mg/kg) 8,980 MS Recovery (%) 90 MSD Recovery (%) 88 RPD (%) 1.4

VS4-CS-13B-COMP2A Sample Result (mg/kg) 207 Spike Amount (mg/kg) 9,990 MS Result (mg/kg) 8,520 MSD Result (mg/kg) 8,540 MS Recovery (%) 83 MSD Recovery (%) 83 RPD (%) 0.31

VS4-HBW-13A-COMP1 Sample Result (mg/kg) 1,350 Spike Amount (mg/kg) 9,970 MS Result (mg/kg) 10,800 MSD Result (mg/kg) 10,800 MS Recovery (%) 95 MSD Recovery (%) 95 RPD (%) 0.37

VS4-LBW-12B-COMP2C Sample Result (mg/kg) 422 Spike Amount (mg/kg) 9,950 MS Result (mg/kg) 9,480 MSD Result (mg/kg) 9,580 MS Recovery (%) 91 MSD Recovery (%) 92 RPD (%) 1

VS4-LWF-12B-COMP2A Sample Result (mg/kg) 1,260 Spike Amount (mg/kg) 10,000 MS Result (mg/kg) 10,600 MSD Result (mg/kg) 10,600 MS Recovery (%) 93 MSD Recovery (%) 93 RPD (%) 0.35DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 19 of 22 

## Results for Duplicate Analysis

A sh Content (mg/kg) Density

(g/cm 3 ) Gross Calorific

Value (BTU/lb) Kinematic

Viscosity (cSt) Water

(%) Total

Chlorine (mg/kg) QAPP Specification Relative Percent Difference (%) 10 10 10 10 10 10

VS2-CS-11BCOMP2B Analytical

Result First Analysis 708,000 -- <130 -- -- --

Duplicate Analysis 760,000 -- <130 -- -- --
RPD 1 (%) 7.1 -- NC 2
-- -- --

VS2-CS-13BCOMP2C Analytical

Result First Analysis 637,000 -- -- -- -- --

Duplicate Analysis 645,000 -- -- -- -- -- RPD (%) 1.2 -- -- -- -- --

VS2-CS-14BCOMP2C Analytical

Result First Analysis -- -- -- -- -- 159

Duplicate Analysis -- -- -- -- -- 186 RPD (%) -- -- -- -- -- 15.7

VS2-CS-15BCOMP2A Analytical

Result First Analysis -- -- -- -- -- 346

Duplicate Analysis -- -- -- -- -- 326 RPD (%) -- -- -- -- -- 6.0

VS2-CS-15BCOMP2B Analytical

Result First Analysis 688,000 -- <130 -- -- --

Duplicate Analysis 695,000 -- <130 -- -- -- RPD (%) 1.0 -- NC -- -- --

VS2-HBW-11ACOMP1 Analytical

Result First Analysis 1,350 0.88 -- 1.31 -- --

Duplicate Analysis 1,360 0.88 -- 1.32 -- -- RPD (%) 0.7 0.0 -- 0.8 -- --

VS2-HBW-13BCOMP2B Analytical

Result First Analysis 582 0.869 9,130 1.18 20.2 3,210

Duplicate Analysis 646 0.869 9,170 1.17 20.2 3,260 RPD (%) 10.4 0.0 0.4 0.9 0.0 1.5

VS2-HBW-15BCOMP2B Analytical

Result First Analysis 1,210 0.883 8,630 1.62 28.1 --

Duplicate Analysis 1,140 0.886 8,680 1.63 28 -- RPD (%) 6.0 0.3 0.6 0.6 0.4 --

VS2-LBW-13BCOMP2B Analytical

Result First Analysis 3,180 1 <130 0.932 96.6 --

Duplicate Analysis 3,000 1 <130 0.933 97.7 -- RPD (%) 5.8 0.0 NC 0.1 1.1 --

VS2-LBW-15BCOMP2B Analytical

Result First Analysis 3,100 1 178 0.929 99 --

Duplicate Analysis 3,030 1 152 0.929 98 -- RPD (%) 2.3 0.0 15.8 0.0 1.0 --

VS2-LWF-13BCOMP2B Analytical

Result First Analysis 592 0.997 <130 0.897 98.7 --

Duplicate Analysis 592 1.01 <130 0.9 98.6 -- RPD (%) 0.0 1.3 NC 0.3 0.1 --

VS2-LWF-15BCOMP2B Analytical

Result First Analysis 832 0.998 <130 0.907 101 --

Duplicate Analysis 883 0.995 <130 0.905 101 -- RPD (%) 5.9 0.3 NC 0.2 0.0 --

VS3-CS-11A-COMP 1 Analytical

Result First Analysis -- -- <130 -- -- 253

Duplicate Analysis -- -- <130 -- -- 325 RPD (%) -- -- NC -- -- 24.9

1 RPD – Relative Percent Difference
2 NC – Not Calculated At least one result is below the detection limit.DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 20 of 22 A sh Content (mg/kg) Density

(g/cm 3 ) Gross Calorific

Value (BTU/lb) Kinematic

Viscosity (cSt) Water

(%) Total

Chlorine (mg/kg) QAPP Specification Relative Percent Difference (%) 10 10 10 10 10 10

VS3-CS-12B-COMP 2B Analytical

Result First Analysis 775,000 -- <130 -- -- --

Duplicate Analysis 781,000 -- <130 -- -- -- RPD (%) 0.8 -- NC -- -- --

VS3-CS-14B-COMP 2C Analytical

Result First Analysis 698,000 -- -- -- -- --

Duplicate Analysis 700,000 -- -- -- -- -- RPD (%) 0.3 -- -- -- -- --

VS3-HBW-11ACOMP 1 Analytical

Result First Analysis -- 0.879 -- 1.33 -- --

Duplicate Analysis -- 0.879 -- 1.32 -- -- RPD (%) -- 0.0 -- 0.8 -- --

VS3-HBW-12BCOMP 2B Analytical

Result First Analysis 1,160 0.877 8,700 1.31 24.1 --

Duplicate Analysis 1,090 0.878 8,800 1.3 24.1 -- RPD (%) 6.2 0.1 1.1 0.8 0.0 --

VS3-HBW-14BCOMP 2B Analytical

Result First Analysis -- -- -- -- -- 1,810

Duplicate Analysis -- -- -- -- -- 1,810 RPD (%) -- -- -- -- -- 0.0

VS3-HBW-14BCOMP 2C Analytical

Result First Analysis -- -- 8,560 -- -- --

Duplicate Analysis -- -- 8,550 -- -- -- RPD (%) -- -- 0.1 -- -- --

VS3-LBW-11ACOMP 1 Analytical

Result First Analysis 3,090 -- -- -- -- --

Duplicate Analysis 3,160 -- -- -- -- -- RPD (%) 2.2 -- -- -- -- --

VS3-LBW-12ACOMP 1 Analytical

Result First Analysis -- 1 -- -- -- --

Duplicate Analysis -- 1.01 -- -- -- -- RPD (%) -- 1.0 -- -- -- --

VS3-LBW-12BCOMP 2C Analytical

Result First Analysis -- -- -- -- -- 408

Duplicate Analysis -- -- -- -- -- 432 RPD (%) -- -- -- -- -- 5.7

VS3-LBW-13BCOMP 2B Analytical

Result First Analysis 3,200 1 181 0.933 100 --

Duplicate Analysis 3,160 1 196 0.936 99.7 -- RPD (%) 1.3 0.0 8.0 0.3 0.3 --

VS3-LWF-11ACOMP 1 Analytical

Result First Analysis -- -- -- 0.901 -- --

Duplicate Analysis -- -- -- 0.899 -- -- RPD (%) -- -- -- 0.2 -- --

VS3-LWF-12BCOMP 2B Analytical

Result First Analysis 713 0.999 <130 0.903 98.7 --

Duplicate Analysis 738 1 <130 0.9 98.3 -- RPD (%) 3.4 0.1 NC 0.3 0.4 --

VS3-LWF-13BCOMP 2A Analytical

Result First Analysis -- -- -- -- -- 101

Duplicate Analysis -- -- -- -- -- 107 RPD (%) -- -- -- -- -- 5.8

VS3-LWF-14BCOMP 2C Analytical

Result First Analysis -- 1 -- -- -- --

Duplicate Analysis -- 1 -- -- -- -- RPD (%) -- 0.0 -- -- -- --DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 21 of 22 A sh Content (mg/kg) Density

(g/cm 3 ) Gross Calorific

Value (BTU/lb) Kinematic

Viscosity (cSt) Water

(%) Total

Chlorine (mg/kg) QAPP Specification Relative Percent Difference (%) 10 10 10 10 10 10

VS4-BS-11A-COMP1 Analytical

Result First Analysis -- -- <130 -- -- 171

Duplicate Analysis -- -- <130 -- -- 221 RPD (%) -- -- NC -- -- 25.5

VS4-BS-14A-COMP1 Analytical

Result First Analysis 710,000 -- <130 -- -- --

Duplicate Analysis 758,000 -- <130 -- -- -- RPD (%) 6.5 -- NC -- -- --

VS4-CS-11A-COMP1 Analytical

Result First Analysis 758,000 -- -- -- -- --

Duplicate Analysis 736,000 -- -- -- -- -- RPD (%) 2.9 -- -- -- -- --

VS4-CS-13BCOMP2A Analytical

Result First Analysis 74,9000 -- <130 -- -- 207

Duplicate Analysis 75,9000 -- <130 -- -- 193 RPD (%) 1.3 -- NC -- -- 7.0

VS4-HBW-11BCOMP2A Analytical

Result First Analysis -- -- 8,700 -- -- --

Duplicate Analysis -- -- 8,680 -- -- -- RPD (%) -- -- 0.2 -- -- --

VS4-HBW-11BCOMP2B Analytical

Result First Analysis -- -- -- 1.28 -- --

Duplicate Analysis -- -- -- 1.29 -- -- RPD (%) -- -- -- 0.8 -- --

VS4-HBW-12BCOMP2B-DUP Analytical

Result First Analysis 943 0.876 -- -- -- --

Duplicate Analysis 1050 0.877 -- -- -- -- RPD (%) 10.7 0.1 -- -- -- --

VS4-HBW-13ACOMP1 Analytical

Result First Analysis 1,500 0.877 8,760 1.38 25.2 1,350

Duplicate Analysis 928 0.877 8,820 1.37 25.2 1,360 RPD (%) 47.1 0.0 0.7 0.7 0.0 0.7

VS4-LBW-12BCOMP2C Analytical

Result First Analysis 2,940 1 166 0.929 97.3 --

Duplicate Analysis 3,120 1 171 0.928 98 --
5.9 0.0 3.0 0.1 0.7 --

VS4-LBW-14ACOMP1 Analytical

Result First Analysis -- -- -- -- -- 530

Duplicate Analysis -- -- -- -- -- 493 RPD (%) -- -- -- -- -- 7.2

VS4-LWF-11ACOMP1 Analytical

Result First Analysis -- -- -- -- -- 1,250

Duplicate Analysis -- -- -- -- -- 1,240 RPD (%) -- -- -- -- -- 0.8

VS4-LWF-12BCOMP2A Analytical

Result First Analysis 694 0.879 8760 1.53 26.9 --

Duplicate Analysis 701 0.878 8,770 1.53 27 -- RPD (%) 1.0 0.1 0.1 0.0 0.4 --

VS4-LWF-13BCOMP2A Analytical

Result First Analysis -- 0.877 -- -- -- --

Duplicate Analysis -- 0.878 -- -- -- -- RPD (%) -- 0.1 -- -- -- --

VS4-LWF-14ACOMP1 Analytical

Result First Analysis 743 -- -- 1.52 -- --

Duplicate Analysis 742 -- -- 1.52 -- -- RPD (%) 0.1 -- -- 0.0 -- --DQA-07; Analysis for Physical and Chemical Parameters Revision Date: December 2012 Reviewed: November 2013

Page 22 of 22 

## R esults for Analysis of Duplicate Samples

A sh Content (mg/kg) Density

(g/cm 3 ) Gross Calorific

Value (BTU/lb) Kinematic

Viscosity (cSt) Water

(%) Total

Chlorine (mg/kg) QAPP Specification Relative Percent Difference (%) 10 10 10 10 10 10

VS2-HBW-13BCOMP2B Analytical

Result Sample 582 0.869 9,130 1.18 20.2 3,210

Duplicate 524 0.869 9,130 1.18 20.2 3,240 Relative Percent Difference (%) 10.5 0.0 0.0 0.0 0.0 0.9

VS2-LBW-13BCOMP2B Analytical

Result Sample 3,180 1 <130 0.932 96.6 364

Duplicate 2,980 1 <130 0.931 98.2 362 Relative Percent Difference (%) 6.5 0.0 NC 1 0.1 1.6 0.6

VS2-LWF-13BCOMP2B Analytical

Result Sample 592 0.997 <130 0.897 98.7 124

Duplicate 589 0.998 <130 0.898 98.5 115 Relative Percent Difference (%) 0.5 0.1 NC 0.1 0.2 7.5

VS3-HBW-12BCOMP 2B Analytical

Result Sample 1,160 0.877 8,700 1.31 24.1 2,720

Duplicate 645 0.878 8,770 1.31 24.1 2,370 Relative Percent Difference (%) 57.1 0.1 0.8 0.0 0.0 13.8

VS3-LBW-12BCOMP 2B Analytical

Result Sample 3,700 1 256 0.932 99.8 419

Duplicate 3,260 1.02 <130 0.935 99 443 Relative Percent Difference (%) 12.6 2.0 NC 0.3 0.8 5.6

VS3-LWF-12BCOMP 2B Analytical

Result Sample 713 0.999 <130 0.903 98.7 696

Duplicate 711 0.998 <130 0.898 97.1 612 Relative Percent Difference (%) 0.3 0.1 NC 0.6 1.6 12.8

VS4-HBW-12BCOMP2B Analytical

Result Sample 1,010 0.877 8,760 1.37 24.9 1,360

Duplicate 943 0.876 8,810 1.38 24.8 1,370 Relative Percent Difference (%) 6.9 0.1 0.6 0.7 0.4 0.7

VS4-LBW-12BCOMP2B Analytical

Result Sample 3,260 1 157 0.933 95.8 393

Duplicate 3,420 1 <130 0.931 99.1 465 Relative Percent Difference (%) 4.8 0.0 NC 0.2 3.4 16.8

VS4-LWF-12BCOMP2B Analytical

Result Sample 673 0.878 8,800 1.52 26.7 2,500

Duplicate 650 0.878 8,840 1.52 26.4 1,250 Relative Percent Difference (%) 3.5 0.0 0.5 0.0 1.1 66.7

1 NC – Not Calculated At least one result is below the detection limit.DQA-08; CEMs Operations Revision Date: June 2013

Page 1 of 11 

# Data Quality Assessment S tack Gas Continuous Emission Monitors
**Parameter(s)** Oxygen, Carbon Dioxide, Total Hydrocarbon 

### Method(s) EPA Methods 3A, 25A



### Calibration Gas Spans were set appropriately; gases were of

appropriate and documented quality. Correct values of all calibration gases used in all calculations. See CEM data in appendix. 

### Interference All analyzers used met the interference check criteria.



### Stratification Check Stratification check performed using one analyte (oxygen). Results of stratification check used to determine number of sampling points. See table below.



### Calibration Error All calibration error checks met method specifications.

See tables below.


### System Bias All system bias checks met method specifications.

See tables below.



### Drift All drift checks for oxygen and carbon dioxide met the method specifications. 70 of 72 drift checks for total hydrocarbons met method specifications. The two outliers were both during Unit 2 Run 1B. A drift of 8.0% was seen at 1800, and a drift of 8.3% was observed at 1909. See tables below



### Data Quality Objectives QAPP specifies these for THC only: Precision: Span and zero drift within 3% of span Accuracy: Calibration error within 5% of calibration gas value Except as noted, these specifications were achieved.DQA-08; CEMs Operations Revision Date: June 2013

Page 2 of 11 

### Conclusions and Comments These data are acceptable for the intended purpose. In accordance with EPA Method 25A, the total hydrocarbon analyzer was immediately re-calibrated following each of the drift excursions. The data from the run was then recalculated using both calibration curves and the higher (more conservative) result reported. As the average THC was well below the standard, and that the conservative recalculation approach specified in the method was implemented, any uncertainty in these data has no impact on the conclusion of the report and the demonstration of compliance. No data are flagged or invalidated based on the calibration drift results.



## Stratification Check Results– Oxygen

**Unit and Date Traverse Point Ox**  **ygen Concentration**  **(%) Difference** 

**from Mean (%)**  **% Difference**

**from Mean**

Unit 2 10/8/2013 **1** 6.23 0.16 2.48
**2** 6.29 0.10 1.55
**3** 6.65 0.26 4.03 **Mean Concentration of all Traverse Points** 6.39 Do the concentrations at each traverse point differ from the mean concentration by no more than (a) ±5.0% of the mean or (b) ±0.5 ppm (whichever is less restrictive)? YES **Use 1 point**



### Unit and Date Traverse Point **Oxygen Concentration**  **(%) Difference** 

**from Mean (%)**  **% Difference**

**from Mean**

Unit 3 10/15/2013 **1** 15.47 0 0
**2** 15.37 0.10 0.6
**3** 15.58 0.11 0.7 **Mean Concentration of all Traverse Points** 6.39 Do the concentrations at each traverse point differ from the mean concentration by no more than (a) ±5.0% of the mean or (b) ±0.5 ppm (whichever is less restrictive)? YES **Use 1 point**



### Unit and Date Traverse Point **Oxygen Concentration**  **(%) Difference** 

**from Mean (%)**  **% Difference**

**from Mean**

Unit 4 10/22/2013 **1** 12.16 0.06 0.49
**2** 12.37 0.15 1.20
**3** 12.14 0.09 0.71 **Mean Concentration of all Traverse Points** 12.22 Do the concentrations at each traverse point differ from the mean concentration by no more than (a) ±5.0% of the mean or (b) ±0.5 ppm (whichever is less restrictive)? YES **Use 1 point**DQA-08; CEMs Operations Revision Date: June 2013

Page 3 of 11 

## Calibration Error Test Results – Oxygen – Method 3A

**C ylinder ID**  **Certified**

**Value (%)**  **Time CEM** 

**Response (%)**  **Absolute**

**Difference (%)**  **Calibration Error**

**(% of Span) 2% Limit** 
8 October 2013 Unit 2 Runs 1A and 1B EEP443 0.00 07:40 -0.03 0.03 0.1%

CC189665 22.50 07:42 22.33 0.17 0.7%
CC43355 10.10 07:44 10.01 0.09 0.4%
9 October 2013 Unit 2 Run 2A EEP443 0.00 07:24 -0.04 0.04 0.2%

CC189665 22.50 07:20 22.50 0.00 0.0%
CC43355 10.10 07:22 10.07 0.03 0.1%
10 October 2013 Unit 2 Runs 3A and 3B EEP443 0.00 07:12 -0.04 0.04 0.2%

CC189665 22.50 07:14 22.64 0.14 0.6%
CC43355 10.10 07:16 10.14 0.04 0.2%
11 October 2013 Unit 2 Run 4B EEP443 0.00 07:12 -0.03 0.03 0.1%

CC189665 22.50 07:13 22.46 0.04 0.2%
CC43355 10.10 07:16 10.05 0.05 0.2%
30 October 2013 Unit 2 Run 5B 52-400193157-1A 0 .00 08:30 -0.01 0.01 0.0%

CC189665 22.50 08:32 22.50 0.00 0.0%
CC196768 9.52 08:33 9.54 0.02 0.1%
15 October 2013 Unit 3 Runs 1A and 1B 52-400193157-1A 0 .00 7:43 0.02 0.02 0.1%

cc189665 22.50 7:45 22.54 0.04 0.2%
cc43355 10.10 7:46 10.12 0.02 0.1%
16 October 2013 Unit 3 Runs 2A and 2B 52-400193157-1A 0 .00 8:24 0.03 0.03 0.1%

cc189665 22.50 8:26 22.50 0.00 0.0%
cc43355 10.10 8:27 10.11 0.01 0.0%
17 October 2013 Unit 3 Runs 3A and 3B 52-400193157-1A 0 .00 7:46 0.01 0.01 0.0%

cc189665 22.50 7:47 22.51 0.01 0.0%
cc43355 10.10 7:48 10.10 0.00 0.0%
18 October 2013 Unit 3 Run 4B 52-400193157-1A 0 .00 07:50 0.02 0.02 0.1%

CC189665 22.50 07:52 22.49 0.01 0.0%
CC43355 10.10 07:53 10.09 0.01 0.0%
23 October 2013 Unit 4 Runs 1A and 1B 52-400193157-1A 0 .00 07:54 0.01 0.01 0.0%

CC189665 22.50 07:56 22.57 0.07 0.3%
CC43355 10.10 07:58 10.12 0.02 0.1%
24 October 2013 Unit 4 Runs 2A and 2B 52-400193157-1A 0 .00 07:42 -0.01 0.01 0.0%

CC189665 22.50 07:44 22.55 0.05 0.2%
CC43355 10.10 07:45 10.10 0.00 0.0%
25 October 2013 Unit 4 Runs 3A, 4A, and 3B 52-400193157-1A 0 .00 07:27 -0.02 0.02 0.1%
CC189665 22.50 07:24 22.58 0.08 0.4%
CC43355 10.10 07:25 10.12 0.02 0.1%DQA-08; CEMs Operations Revision Date: June 2013

Page 4 of 11 

## Calibration Error Test Results – Carbon Dioxide – Method 3A

**C ylinder ID**  **Certified**

**Value (%)**  **Time CEM** 

**Response (%)**  **Absolute**

**Difference (%)**  **Calibration Error**

**(% of Span) 2% Limit** 
8 October 2013 Unit 2 Runs 1A and 1B EEP443 0.00 07:40 0.04 0.04 0.2%

CC189665 19.20 07:42 19.23 0.03 0.2%
CC43355 10.00 07:44 10.13 0.13 0.7%
9 October 2013 Unit 2 Run 2A EEP443 0.00 07:24 0.10 0.10 0.5%

CC189665 19.20 07:20 19.08 0.12 0.6%
CC43355 10.00 07:22 10.06 0.06 0.3%
10 October 2013 Unit 2 Runs 3A and 3B EEP443 0.00 07:12 0.04 0.04 0.2%

CC189665 19.20 07:14 19.29 0.09 0.5%
CC43355 10.00 07:16 10.18 0.18 0.9%
11 October 2013 Unit 2 Run 4B EEP443 EEP443 0.00 07:12 0.06 0.06

CC189665 CC189665 19.20 07:13 18.99 0.21
CC43355 CC43355 10.00 07:16 10.03 0.03
30 October 2013 Unit 2 Run 5B 52-400193157-1A 0 .00 08:30 0.01 0.01 0.1%

CC189665 19.20 08:32 19.23 0.03 0.1%
CC196768 9.53 08:33 9.64 0.11 0.6%
15 October 2013 Unit 3 Runs 1A and 1B 52-400193157-1A 0 .00 7:43 0.02 0.02 0.1%

cc189665 19.20 7:45 19.22 0.02 0.1%
cc43355 10.00 7:46 10.10 0.10 0.5%
16 October 2013 Unit 3 Runs 2A and 2B 52-400193157-1A 0 .00 8:24 0.05 0.05 0.2%

cc189665 19.20 8:26 19.22 0.02 0.1%
cc43355 10.00 8:27 10.10 0.10 0.5%
17 October 2013 Unit 3 Runs 3A and 3B 52-400193157-1A 0 .00 7:46 0.04 0.04 0.2%

cc189665 19.20 7:47 19.21 0.01 0.0%
cc43355 10.00 7:48 10.10 0.10 0.5%
18 October 2013 Unit 3 Run 4B 52-400193157-1A 0 .00 07:50 0.01 0.01 0.0%

CC189665 19.20 07:52 19.15 0.05 0.2%
CC43355 10.00 07:53 10.06 0.06 0.3%
23 October 2013 Unit 4 Runs 1A and 1B 52-400193157-1A 0 .00 07:54 0.02 0.02 0.1%

CC189665 19.20 07:56 19.24 0.04 0.2%
CC43355 10.00 07:58 10.11 0.11 0.6%
24 October 2013 Unit 4 Runs 2A and 2B 52-400193157-1A 0 .00 07:42 0.04 0.04 0.2%

CC189665 19.20 07:44 19.22 0.02 0.1%
CC43355 10.00 07:45 10.06 0.06 0.3%
25 October 2013 Unit 4 Runs 3A, 4A, and 3B 52-400193157-1A 0 .00 07:27 0.04 0.04 0.2%
CC189665 19.20 07:24 19.24 0.04 0.2%
CC43355 10.00 07:25 10.05 0.05 0.3%DQA-08; CEMs Operations Revision Date: June 2013

Page 5 of 11 

## System Bias– Oxygen, Method 3A

**Run No. C**  **ylinder**

**Value (%)**  **CEMS Response during Calibration Error Test**  **(%) Time**  **CEMs Response**  **(%) Bias** 

**(% of Span) 5% Limit** 

8 October 2013 Unit 2 Runs 1A and 1B 0.00 -0.03 07:48 -0.02 0.0% 10.10 10.01 07:50 9.91 -0.4% 0.00 -0.03 14:18 -0.05 -0.1% 10.10 10.01 14:21 9.88 -0.6% 9 October 2013 Unit 2; Run 2A 0.00 -0.04 07:33 -0.03 0.1% 10.10 10.07 07:36 10.04 -0.1%

10 October 2013 Unit 2 Runs 3A and 3B 0.00 -0.04 07:33 -0.01 0.1% 10.10 10.14 07:35 9.94 -0.9% 0.00 -0.04 10:25 0.09 0.6% 10.10 10.14 10:27 9.95 -0.9% 0.00 -0.04 11:32 -0.05 -0.1% 10.10 10.14 11:34 9.94 -0.9% 11 October 2013 Unit 2; Run 4B 0.00 -0.03 07:20 0.05 0.3% 10.10 10.05 07:22 9.94 -0.5% 30 October 2013 Unit 2; Run 5B 0.00 -0.01 12:02 0.00 0.0% 9.52 9.54 12:04 9.40 -0.6%

15 October 2013 Unit 3 Runs 1A and 1B 0.00 0.02 12:41 0.05 0.1% 10.10 10.12 12:43 9.98 -0.6% 0.00 0.02 14:32 0.05 0.1% 10.10 10.12 14:34 9.95 -0.8%

16 October 2013 Unit 3 Runs 2A and 2B 0.00 0.03 8:31 0.07 0.2% 10.10 10.11 8:29 10.04 -0.3% 0.00 0.03 13:49 0.12 0.4% 10.10 10.11 13:51 9.98 -0.6%

17 October 2013 Unit 3 Runs 3A and 3B 0.00 0.01 7:51 0.04 0.1% 10.10 10.10 7:50 10.00 -0.4% 0.00 0.01 11:10 0.06 0.2% 10.10 10.10 11:12 9.93 -0.7% 18 October 2013 Unit 3; Run 4B 0.00 0.02 08:27 0.06 0.2% 10.10 10.09 08:24 10.02 -0.3%

23 October 2013 Unit 4 Runs 1A and 1B 0.00 0.01 08:02 0.05 0.2% 10.10 10.12 08:04 10.09 -0.1% 0.00 0.01 10:48 0.02 0.1% 10.10 10.12 10:50 10.08 -0.2%

24 October 2013 Unit 4 Runs 2A and 2B 0.00 -0.01 07:51 0.02 0.2% 10.10 10.10 07:53 10.07 -0.1% 0.00 -0.01 10:43 0.09 0.4% 10.10 10.10 10:44 10.01 -0.4%

25 October 2013 Unit 4 Runs 3A, 4A, and 3B 0.00 -0.02 07:31 0.08 0.5% 10.10 10.12 07:33 9.97 -0.7% 0.00 -0.02 10:43 0.08 0.4% 10.10 10.12 10:44 9.96 -0.7% 0.00 -0.02 11:58 0.05 0.3% 10.10 10.12 11:59 9.96 -0.7%DQA-08; CEMs Operations Revision Date: June 2013

Page 6 of 11 

## System Bias– Carbon Dioxide, Method 3A

**Run No. C**  **ylinder**

**Value (%)**  **CEMS Response during Calibration Error Test**  **(%) Time**  **CEMs Response**  **(%) Bias** 

**(% of Span) 5% Limit** 

8 October 2013 Unit 2 Runs 1A and 1B 0.00 0.04 07:48 0.06 0.1% 10.00 10.13 07:50 10.00 -0.7% 0.00 0.04 14:18 0.09 0.2% 10.00 10.13 14:21 9.99 -0.7% 9 October 2013 Unit 2; Run 2A 0.00 0.10 07:33 0.05 -0.3% 10.00 10.06 07:36 9.99 -0.4%

10 October 2013 Unit 2 Runs 3A and 3B 0.00 0.04 07:33 0.04 0.0% 10.00 10.18 07:35 9.92 -1.3% 0.00 0.04 10:25 0.22 0.9% 10.00 10.18 10:27 9.97 -1.1% 0.00 0.04 11:32 0.09 0.3% 10.00 10.18 11:34 9.95 -1.2% 11 October 2013 Unit 2; Run 4B 0.00 0.06 07:20 0.07 0.1% 10.00 10.03 07:22 9.89 -0.7% 30 October 2013 Unit 2; Run 5B 0.00 0.01 12:02 0.05 0.2% 9.53 9.64 12:04 9.49 -0.8%

15 October 2013 Unit 3 Runs 1A and 1B 0.00 0.02 12:41 0.04 0.1% 10.00 10.10 12:43 9.89 -1.1% 0.00 0.02 14:32 0.04 0.1% 10.00 10.10 14:34 9.87 -1.2%

16 October 2013 Unit 3 Runs 2A and 2B 0.00 0.05 8:31 0.06 0.1% 10.00 10.10 8:29 9.93 -0.9% 0.00 0.05 13:49 0.03 -0.1% 10.00 10.10 13:51 9.88 -1.1%

17 October 2013 Unit 3 Runs 3A and 3B 0.00 0.04 7:51 0.06 0.1% 10.00 10.10 7:50 9.89 -1.1% 0.00 0.04 11:10 0.05 0.0% 10.00 10.10 11:12 9.88 -1.1% 18 October 2013 Unit 3; Run 4B 0.00 0.01 08:27 0.07 0.3% 10.00 10.06 08:24 9.90 -0.9%

23 October 2013 Unit 4 Runs 1A and 1B 0.00 0.02 08:02 0.03 0.1% 10.00 10.11 08:04 10.07 -0.2% 0.00 0.02 10:48 0.05 0.2% 10.00 10.11 10:50 10.09 -0.1%

24 October 2013 Unit 4 Runs 2A and 2B 0.00 0.04 07:51 0.06 0.1% 10.00 10.06 07:53 10.04 -0.1% 0.00 0.04 10:43 0.07 0.2% 10.00 10.06 10:44 10.01 -0.3%

25 October 2013 Unit 4 Runs 3A, 4A, and 3B 0.00 0.04 07:31 0.03 -0.1% 10.00 10.05 07:33 9.81 -1.2% 0.00 0.04 10:43 0.10 0.3% 10.00 10.05 10:44 9.82 -1.2% 0.00 0.04 11:58 0.08 0.2% 10.00 10.05 11:59 9.86 -1.0%DQA-08; CEMs Operations Revision Date: June 2013

Page 7 of 11 

## Drift Tests – Oxygen, Method 3A

**Run No. C**  **ylinder**

**Value (%)**  **Pre Test Post test**  **Drift (% of Span)**  **3% Limit Time**  **CEMs Response**  **(%) Time**  **CEMs**

**Response (%)** 

8 October 2013 Unit 2 Runs 1A and 1B 

### 0.00 07:48

- 0.02 14:18

- 0.05

- 0.1%

10.10 07:50 9.91 14:21 9.88

- 0.1% 0.00 14:18

- 0.05 19:03 0.04 0.4% 10.10 14:21 9.88 19:07 9.85

- 0.1% 9 October 2013 Unit 2; Run 2A 

### 0.00 07:33

- 0.03 10:55 0.00 0.1%

10.10 07:36 10.04 10:57 9.98

- 0.3%

10 October 2013 Unit 2 Runs 3A and 3B 

### 0.00 07:33

- 0.01 10:25 0.09 0.4%

10.10 07:35 9.94 10:27 9.95 0.0% 0.00 10:25 0.09 11:32

- 0.05

- 0.6% 10.10 10:27 9.95 11:34 9.94 0.0% 0.00 11:32

- 0.05 15:43

- 0.01 0.2% 10.10 11:34 9.94 15:45 9.89

- 0.2% 11 October 2013 Unit 2; Run 4B 

### 0.00 07:20 0.05 13:06

- 0.08

- 0.6%

10.10 07:22 9.94 13:08 9.89

- 0.2% 30 October 2013 Unit 2; Run 5B 

### 0.00 12:02 0.00 16:05 0.03 0.2%

9.52 12:04 9.40 16:07 9.37

- 0.2%

15 October 2013 Unit 3 Runs 1A and 1B 

### 0.00 12:41 0.05 14:32 0.05 0.0%

10.10 12:43 9.98 14:34 9.95

- 0.1% 0.00 14:32 0.05 19:38 0.08 0.1% 10.10 14:34 9.95 19:40 9.94

- 0.1%

16 October 2013 Unit 3 Runs 2A and 2B 

### 0.00 8:31 0.07 12:28 0.10 0.1%

10.10 8:29 10.04 12:31 9.96

- 0.4% 0.00 13:49 0.12 17:26 0.08

- 0.2% 10.10 13:51 9.98 17:28 9.97 0.0%

17 October 2013 Unit 3 Runs 3A and 3B 

### 0.00 7:51 0.04 11:10 0.06 0.1%

10.10 7:50 10.00 11:12 9.93

- 0.3% 0.00 11:10 0.06 16:03 0.07 0.0% 10.10 11:12 9.93 16:05 9.90

- 0.1% 18 October 2013 Unit 3; Run 4B 

### 0.00 08:27 0.06 12:54 0.07 0.0%

10.10 08:24 10.02 12:56 9.93

- 0.4%

23 October 2013 Unit 4 Runs 1A and 1B 

### 0.00 08:02 0.05 10:48 0.02

- 0.1%

10.10 08:04 10.09 10:50 10.08

- 0.1% 0.00 10:48 0.02 15:57 0.05 0.1% 10.10 10:50 10.08 15:59 9.90

- 0.8%

24 October 2013 Unit 4 Runs 2A and 2B 

### 0.00 07:51 0.02 10:43 0.09 0.3%

10.10 07:53 10.07 10:44 10.01

- 0.2% 0.00 10:43 0.09 15:53 0.07

- 0.1% 10.10 10:44 10.01 15:55 10.00 0.0%

25 October 2013 Unit 4 Runs 3A, 4A, and 3B 

### 0.00 07:31 0.08 10:43 0.08 0.0%

10.10 07:33 9.97 10:44 9.96 0.0% 0.00 10:43 0.08 11:58 0.05

- 0.1% 10.10 10:44 9.96 11:59 9.96 0.0% 0.00 11:58 0.05 16:54 0.02

- 0.1% 10.10 11:59 9.96 16:56 9.87

- 0.4%DQA-08; CEMs Operations Revision Date: June 2013

Page 8 of 11 

## Drift Tests – Carbon Dioxide, Method 3A

**Run No. C**  **ylinder**

**Value (%)**  **Pre Test Post test**  **Drift (% of Span)**  **3% Limit Time**  **CEMs Response**  **(%) Time**  **CEMs**

**Response (%)** 

8 October 2013 Unit 2 Runs 1A and 1B 0.00 07:48 0.06 14:18 0.09 0.1%

10.00 07:50 10.00 14:21 9.99 -0.1% 0.00 14:18 0.09 19:03 0.11 0.1% 10.00 14:21 9.99 19:07 9.96 -0.2% 9 October 2013 Unit 2; Run 2A 0.00 07:33 0.05 10:55 0.14 0.5%

10.00 07:36 9.99 10:57 9.98 -0.1%

10 October 2013 Unit 2 Runs 3A and 3B 0.00 07:33 0.04 10:25 0.22 0.9%

10.00 07:35 9.92 10:27 9.97 0.2% 0.00 10:25 0.22 11:32 0.09 -0.7% 10.00 10:27 9.97 11:34 9.95 -0.1% 0.00 11:32 0.09 15:43 0.14 0.3% 10.00 11:34 9.95 15:45 9.90 -0.3% 11 October 2013 Unit 2; Run 4B 0.00 07:20 0.07 13:06 0.09 0.1%

10.00 07:22 9.89 13:08 9.89 0.0% 30 October 2013 Unit 2; Run 5B 0.00 12:02 0.05 16:05 0.04 0.0%

9.53 12:04 9.49 16:07 9.43 -0.3%

15 October 2013 Unit 3 Runs 1A and 1B 0.00 12:41 0.04 14:32 0.04 0.0%

10.00 12:43 9.89 14:34 9.87 -0.1% 0.00 14:32 0.04 19:38 0.09 0.2% 10.00 14:34 9.87 19:40 9.86 0.0%

16 October 2013 Unit 3 Runs 2A and 2B 0.00 8:31 0.06 12:28 0.07 0.0%

10.00 8:29 9.93 12:31 9.92 0.0% 0.00 13:49 0.03 17:26 0.08 0.3% 10.00 13:51 9.88 17:28 9.89 0.0%

17 October 2013 Unit 3 Runs 3A and 3B 0.00 7:51 0.06 11:10 0.05 -0.1%

10.00 7:50 9.89 11:12 9.88 0.0% 0.00 11:10 0.05 16:03 0.07 0.1% 10.00 11:12 9.88 16:05 9.85 -0.2% 18 October 2013 Unit 3; Run 4B 0.00 08:27 0.07 12:54 0.07 0.0%

10.00 08:24 9.90 12:56 9.89 -0.1%

23 October 2013 Unit 4 Runs 1A and 1B 0.00 08:02 0.03 10:48 0.05 0.1%

10.00 08:04 10.07 10:50 10.09 0.1% 0.00 10:48 0.05 15:57 0.06 0.0% 10.00 10:50 10.09 15:59 9.92 -0.9%

24 October 2013 Unit 4 Runs 2A and 2B 0.00 07:51 0.06 10:43 0.07 0.1%

10.00 07:53 10.04 10:44 10.01 -0.1% 0.00 10:43 0.07 15:53 0.06 -0.1% 10.00 10:44 10.01 15:55 10.01 0.0%

25 October 2013 Unit 4 Runs 3A, 4A, and 3B 0.00 07:31 0.03 10:43 0.10 0.4% 10.00 07:33 9.81 10:44 9.82 0.1% 0.00 10:43 0.10 11:58 0.08 -0.1% 10.00 10:44 9.82 11:59 9.86 0.2% 0.00 11:58 0.08 16:54 0.04 -0.2% 10.00 11:59 9.86 16:56 9.70 -0.8%DQA-08; CEMs Operations Revision Date: June 2013

Page 9 of 11 

## Calibration Error Tests – Total Hydrocarbon, Method 25A

**C ylinder ID**  **Certified**

**Value (ppm)**  **Time CEM** 

**Response (ppm)**  **Absolute**

**Difference (ppm)**  **Cal Error 1** 



### (% of Span) **5% Limit**

8 October 2013 Unit 2 THC Run 1B EEP443 0.00 15:16

- 0.18 0.18 n/c

CC111534 21.30 15:19 20.98 0.32 1.5% AL899 12.90 15:21 12.41 0.49 3.8% CC250309 7.58 15:23 7.54 0.04 0.5% EEP443 0.00 18:21 0.11 0.11 n/c CC111534 21.30 18:24 21.02 0.28 1.3% AL899 12.90 18:28 12.78 0.12 0.9% CC250309 7.58 18:26 7.92 0.34 4.5%

10 October 2013 Unit 2 Run 3B EEP443 0.00 11:43 0.24 0.24 n/c

AAL4460 21.10 11:37 21.37 0.27 1.3% AL899 12.90 11:39 12.69 0.21 1.6% CC250309 7.58 11:41 7.73 0.15 2.0%

11 October 2013 Unit 2 Run 4B EEP443 0.00 09:13 0.06 0.06 n/c

AAL4460 21.10 09:15 21.00 0.10 0.5% AL899 12.90 09:19 12.50 0.40 3.1% CC250309 7.58 09:17 7.63 0.05 0.7%

30 October 2013 Unit 2 Run 5B 52

- 400193157

- 1A 0.00 12:10 0.03 0.03 n/c

ALM025456 24.70 12:06 24.63 0.07 0.3% ALM028646 14.80 12:07 14.98 0.18 1.2% ALM057529 8.43 12:08 8.55 0.12 1.4%

15 October 2013 Unit 3 Run 1B 52

- 400193157

- 1A 0.00 15:11

- 0.05 0.05 n/c

alm025456 24.70 15:13 24.64 0.06 0.4% alm028646 14.80 15:15 14.92 0.12 2.5% alm057529 8.43 15:17 8.42 0.01 2.2%

16 October 2013 Unit 3 Run 2B 52

- 400193157

- 1A 0.00 13:49

- 0.08 0.08 n/c

alm025456 24.70 13:44 24.79 0.09 0.0 alm028646 14.80 13:45 15.17 0.37 0.0 alm057529 8.43 13:47 8.61 0.18 0.0

17 October 2013 Unit 3 Run 3B 52

- 400193157

- 1A 0.00 12:16

- 0.07 0.07 n/c

alm025456 24.70 12:18 24.93 0.23 0.9% alm028646 14.80 12:19 15.09 0.29 2.0% alm057529 8.43 12:21 8.54 0.11 1.3%

18 October 2013 Unit 3 Run 4B 52

- 400193157

- 1A 0.00 09:25 0.00 0.00 n/c

ALM025456 24.70 09:26 24.86 0.16 0.7% ALM028646 14.80 09:28 15.17 0.37 2.5% ALM057529 8.43 09:30 8.61 0.18 2.1%

23 October 2013 Unit 4 Runs 1B 52

- 400193157

- 1A 0.00 11:38

- 0.05 0.05 n/c

ALM025456 24.70 11:32 24.79 0.09 0.4% ALM028646 14.80 11:36 15.23 0.43 2.9% ALM057529 8.43 11:34 8.60 0.17 2.1%

24 October 2013 Unit 4 Run 2B 52

- 400193157

- 1A 0.00 11:18

- 0.02 0.02 n/c

ALM025456 24.70 11:20 24.64 0.06 0.3% ALM028646 14.80 11:21 14.96 0.16 1.1% ALM057529 8.43 11:24 8.51 0.08 1.0%

25 October 2013 Unit 4 Run 3B 52

- 400193157

- 1A 0.00 11:58 0.00 0.00 n/c

ALM025456 24.70 12:02 24.67 0.03 0.1% ALM028646 14.80 12:04 15.03 0.23 1.5% ALM057529 8.43 12:06 8.54 0.11 1.4%

1 Calibration Error can not be calculated for the zero gases. The specification is in percent of the certified value. These
a re indicated as n/c – not calculated.DQA-08; CEMs Operations Revision Date: June 2013

Page 10 of 11 

## Drift Tests – Total Hydrocarbon, Method 25A

**Run No. C**  **EMs Response from**

**Calibration Error Test (ppm)**  **Time CEMs**  **Response (ppm)**  **Drift**

**(% of Span) 3% Limit** 

8 October 2013 Unit 2 THC Run 1B 

### -0.18 16: 52 -0.14 0.2

12.41 16:48 12.25 -0.7 -0.18 17:58 -0.63 -1.8 12.41 18:00 10.40 **-8.0** 0.11 19:03 1.10 3.9 12.78 19:09 14.86 **8.3**

10 October 2013 Unit 2 Run 3B 

### 0.24 11: 34 0.02 -0.9

12.69 11:36 12.56 -0.5 0.24 13:34 0.02 -0.9 12.69 13:36 12.56 -0.5 0.24 14:44 0.01 -0.9 12.69 14:47 12.55 -0.6 0.24 15:43 -0.02 -1.0 12.69 15:47 12.50 -0.7

11 October 2013 Unit 2 Run 4B 

### 0.06 10: 49 0.09 0.1

12.50 10:52 12.38 -0.5 0.06 11:54 0.07 0.1 12.50 11:57 12.19 -1.3 0.06 13:06 0.07 0.0 12.50 13:10 12.39 -0.4

30 October 2013 Unit 2 Run 5B 

### 0.03 13: 49 0.05 0.1

14.98 13:50 14.99 0.0 0.03 14:56 0.05 0.1 14.98 14:57 15.00 0.1 0.03 16:05 0.06 0.1 14.98 16:09 15.01 0.1

15 October 2013 Unit 3 Run 1B 

### -0.05 16: 04 -0.01 0.1

14.92 16:06 14.89 -0.1 -0.05 17:18 -0.01 0.1 14.92 17:20 14.58 -1.1 -0.05 18:21 0.00 0.2 14.92 18:23 14.69 -0.8 -0.05 19:38 0.00 0.1 14.92 19:42 14.77 -0.5

16 October 2013 Unit 3 Run 2B 

### -0.08 15: 03 0.01 0.3

15.17 15:05 14.95 -0.7 -0.08 16:16 0.03 0.3 15.17 16:17 14.88 -1.0 -0.08 17:26 -0.02 0.2 15.17 17:29 15.25 0.3DQA-08; CEMs Operations Revision Date: June 2013

Page 11 of 11 

### Run No. **CEMs Response from**

**Calibration Error Test (ppm)**  **Time CEMs**  **Response (ppm)**  **Drift**

**(% of Span) 3% Limit** 

17 October 2013 Unit 3 Run 3B 

### -0.07 13: 37 -0.02 0.2

15.09 13:39 14.80 -1.0 -0.07 14:40 -0.05 0.1 15.09 14:42 14.58 -1.7 -0.07 16:03 -0.04 0.1 15.09 16:07 14.96 -0.4

18 October 2013 Unit 3 Run 4B 

### 0.00 10: 39 0.06 0.2

15.17 10:41 14.88 -0.9 0.00 11:58 0.07 0.3 15.17 12:00 14.94 -0.8 0.00 12:54 0.07 0.2 15.17 12:58 14.98 -0.6

23 October 2013 Unit 4 Runs 1B 

### -0.05 13: 39 0.00 0.2

15.23 13:47 14.78 -1.5 -0.05 15:04 -0.02 0.1 15.23 15:12 14.70 -1.8 -0.05 15:57 -0.04 0.0 15.23 16:01 14.80 -1.4

24 October 2013 Unit 4 Run 2B 

### -0.02 12: 13 -0.04 -0.1

14.96 12:15 14.94 -0.1 -0.02 13:38 -0.04 0.0 14.96 13:39 14.90 -0.2 -0.02 14:46 -0.02 0.0 14.96 14:48 14.75 -0.7 -0.02 15:53 -0.02 0.0 14.96 15:56 14.73 -0.8

25 October 2013 Unit 4 Run 3B 

### 0.00 13: 14 -0.01 0.0

15.03 13:16 14.88 -0.5 0.00 14:37 -0.01 0.0 15.03 14:39 14.93 -0.3 0.00 15:45 -0.02 -0.1 15.03 15:47 14.86 -0.6 0.00 16:54 -0.05 -0.2 15.03 16:58 15.00 -0.1DQA-14; Analysis of Metals in Waste Revision Date: December 2012 Reviewed: December 2013

Page 1 of 10 

# Data Quality Assessment Analysis of Waste Feeds for Metals

Parameter Selected Metals in Waste Feeds 

### Sampling Method Tap Sampling 

### Analytical Method ICPES, SW-846 Method 6010B; CVAA, SW-846 Method 7471A



### Work Order Number(s) H3J140415, H3J140417, H3J150401, H3J150402, H3J150403, H3J190414, H3J190415, H3J190416, H3J190417, H3J190418, H3K010415, H3K010416, H3K010418, H3K010419, H3K010420, H3K010424, H3K020402, H3K020403, H3K020404, H3K020405, H3K020406 

### Preparation Batch Number(s) 3294020, 3294021, 3294022, 3294026, 3295019, 3295020, 3295059, 3296030, 3308021, 3308023, 3308024, 3308025, 3310018, 3310020, 3311018 

### Sample Shipping and Receipt Samples received intact and at ambient temperature. QAPP has no temperature specification.



### Holding Time(s) All analyses conducted within 19 days of sample collection.

QAPP specifies 28-day hold time for mercury, 6 months for all other analytes. See table below.



### Blank Results All method blanks below the detection limit.

See table below.



### Laboratory Check Sample (LCS) and Laboratory Check Sample Duplicate (LCSD) Results All recoveries between 90 and 110%. This met the QAPP specification of recovery between 80 and 120%. All RPDs below 5%. There is no QAPP requirement for LCSD or specification for RPD. This met the laboratory specification of RPD below 20%. See table below.



### Matrix Spike (MS) and Matrix Spike Duplicate (MSD) Results QAPP specifications are 75-125% recovery, 0-20% RPD for mercury and 70- 130% recovery, 20% RPD for others. 187 of 204 MS or MSD met the specifications for recovery. 100 of 102 MS/MSD pairs met the specification for RPD. The following samples were outside the specification:

• VS2-CS-11B-COMP2B: Arsenic recovery 67% in MS, arsenic RPD 23%, chromium recovery 149% and 172% in MS/MSD.

• VS2-CS-15B-COMP2B: chromium recovery 150% in MSD

• VS3-CS-12B-COMP 2B: chromium recovery 131 and 145% in MS/MSD

• VS4-BS-13B-COMP2B: chromium recovery 132 and 134% in MS/MSD, lead recovery 208% in MSD

• VS4-CS-13B-COMP2B: chromium recovery 164 and 186% in MS/MSD, lead recovery 406% in MS, lead RPD 49%, mercury recovery 61 and 45% in MS/MSD

• VS4-LBW-12B-COMP2B: cadmium recovery 145% in MSD, mercury recovery 71 and 66% in MS/MSD. See table below.



### Duplicate Results Selected samples were analyzed in duplicate. Duplicate samples were

collected and analyzed. The QAPP presents no specifications for duplicate analysis or analysis of duplicate samples. Good reproducibility was observed. See table below.DQA-14; Analysis of Metals in Waste Revision Date: December 2012 Reviewed: December 2013

Page 2 of 10 

### Conclusions and Comments These data are acceptable for the intended purpose. Metals feed rates are developed as a sum of totals fed to the system as LVM (arsenic, beryllium and chromium) SVM (cadmium and lead) and mercury. The MS/MSD outliers detailed above indicate increased uncertainty in the concentrations of the metals in those streams. The contribution of these streams to the total feed rates of LVM, SVM and mercury are negligible, and the increased uncertainty in these concentrations has no impact on the conclusions of the report. No data are qualified or invalidated based on MS/MSD results.



## Holding Time

S ample Date Analysis Date Holding time

Metals Excluding Mercury – ICPES Mercury –

CVAA Metals

Excluding Mercury – ICPES Mercury –

CVAA

VS2-CR-11B-GRAB1 8-Oct 25-Oct -- 17 -- VS2-CR-11B-GRAB2 8-Oct 25-Oct -- 17 -- VS2-CR-11B-GRAB3 8-Oct 25-Oct -- 17 -- VS2-CR-13B-GRAB1 10-Oct 25-Oct -- 15 -- VS2-CR-13B-GRAB2 10-Oct 25-Oct -- 15 -- VS2-CR-13B-GRAB3 10-Oct 25-Oct -- 15 -- VS2-CR-14B-GRAB1 11-Oct 25-Oct -- 14 -- VS2-CR-14B-GRAB2 11-Oct 25-Oct -- 14 -- VS2-CR-14B-GRAB3 11-Oct 25-Oct -- 14 -- VS2-CR-15B-GRAB1 30-Oct 11-Nov -- 12 -- VS2-CR-15B-GRAB2 30-Oct 11-Nov -- 12 -- VS2-CR-15B-GRAB3 30-Oct 11-Nov -- 12 -- VS2-CS-11B-COMP2B 8-Oct 24-Oct 23-Oct 16 15 VS2-CS-13B-COMP2B 10-Oct 24-Oct 23-Oct 14 13
VS2-CS-14B-COMP2B 11-Oct 24-Oct 23-Oct 13 12
VS2-CS-15B-COMP2B 30-Oct 8-Nov 8-Nov 9 9
VS2-HBW-11B-COMP2B 8-Oct 24-Oct 23-Oct 16 15
VS2-HBW-13B-COMP2B 10-Oct 24-Oct 23-Oct 14 13
VS2-HBW-13B-COMP2B DUPLICATE 10-Oct 24-Oct 23-Oct 14 13
VS2-HBW-14B-COMP2B 11-Oct 24-Oct 23-Oct 13 12
VS2-HBW-15B-COMP2B 30-Oct 8-Nov 8-Nov 9 9
VS2-HG-11B-GRAB1 8-Oct -- 23-Oct -- 15 VS2-HG-11B-GRAB2 8-Oct -- 23-Oct -- 15
VS2-HG-11B-GRAB3 8-Oct -- 23-Oct -- 15
VS2-HG-13B-GRAB1 10-Oct -- 23-Oct -- 13
VS2-HG-13B-GRAB2 10-Oct -- 23-Oct -- 13
VS2-HG-13B-GRAB3 10-Oct -- 23-Oct -- 13
VS2-HG-14B-GRAB2 11-Oct -- 23-Oct -- 12
VS2-HG-14B-GRAB3 11-Oct -- 23-Oct -- 12
VS2-HG-15B-GRAB1 30-Oct -- 8-Nov -- 9
VS2-HG-15B-GRAB2 30-Oct -- 8-Nov -- 9DQA-14; Analysis of Metals in Waste Revision Date: December 2012 Reviewed: December 2013

Page 3 of 10 

### Sample Date Analysis Date Holding time

Metals Excluding Mercury – ICPES Mercury –

CVAA Metals

Excluding Mercury – ICPES Mercury –

CVAA

VS2-HG-15B-GRAB3 30-Oct -- 8-Nov -- 9
VS2-LBW-11B-COMP2B 8-Oct 24-Oct 23-Oct 16 15 VS2-LBW-13B-COMP2B 10-Oct 24-Oct 23-Oct 14 13
VS2-LBW-13B-COMP2B DUPLICATE 10-Oct 24-Oct 23-Oct 14 13
VS2-LBW-15B-COMP2A 30-Oct 8-Nov 8-Nov 9 9
VS2-LBW-15B-COMP2B 30-Oct 8-Nov 8-Nov 9 9
VS2-LBW-15B-COMP2C 30-Oct 8-Nov 8-Nov 9 9
VS2-LWF-11B-COMP2B 8-Oct 24-Oct 23-Oct 16 15 VS2-LWF-13B-COMP2B 10-Oct 24-Oct 23-Oct 14 13
VS2-LWF-13B-COMP2B DUPLICATE 10-Oct 24-Oct 23-Oct 14 13
VS2-LWF-15B-COMP2B 30-Oct 8-Nov 8-Nov 9 9
VS3-CR-12B-GRAB 1 16-Oct 25-Oct -- 9 -- VS3-CR-12B-GRAB 2 16-Oct 25-Oct -- 9 -- VS3-CR-12B-GRAB 3 16-Oct 25-Oct -- 9 -- VS3-CR-13B-GRAB 1 17-Oct 25-Oct -- 8 -- VS3-CR-13B-GRAB 2 17-Oct 25-Oct -- 8 -- VS3-CR-13B-GRAB 3 17-Oct 25-Oct -- 8 -- VS3-CR-14B-GRAB 1 18-Oct 25-Oct -- 7 -- VS3-CR-14B-GRAB 2 18-Oct 25-Oct -- 7 -- VS3-CR-14B-GRAB 3 18-Oct 25-Oct -- 7 -- VS3-CS-12B-COMP 2B 16-Oct 24-Oct 23-Oct 8 7
VS3-CS-13B-COMP 2B 17-Oct 24-Oct 23-Oct 7 6
VS3-CS-14B-COMP 2B 18-Oct 24-Oct 23-Oct 6 5
VS3-HBW-12B-COMP 2B 16-Oct 24-Oct 23-Oct 8 7
VS3-HBW-12B-COMP 2B-DUP 16-Oct 24-Oct 23-Oct 8 7 VS3-HBW-13B-COMP 2B 17-Oct 24-Oct 23-Oct 7 6
VS3-HBW-14B-COMP 2B 18-Oct 24-Oct 23-Oct 6 5 VS3-HG-12B-GRAB 1 16-Oct -- 23-Oct -- 7
VS3-HG-12B-GRAB 2 16-Oct -- 23-Oct -- 7
VS3-HG-12B-GRAB 3 16-Oct -- 23-Oct -- 7 VS3-HG-13B-GRAB 1 17-Oct -- 23-Oct -- 6
VS3-HG-13B-GRAB 2 17-Oct -- 23-Oct -- 6
VS3-HG-13B-GRAB 3 17-Oct -- 23-Oct -- 6
VS3-HG-14B-GRAB 1 18-Oct -- 23-Oct -- 5
VS3-HG-14B-GRAB 2 18-Oct -- 23-Oct -- 5
VS3-HG-14B-GRAB 3 18-Oct -- 23-Oct -- 5 VS3-LBW-12B-COMP 2B 16-Oct 24-Oct 23-Oct 8 7
VS3-LBW-12B-COMP 2B DUP 16-Oct 24-Oct 23-Oct 8 7
VS3-LBW-13B-COMP 2B 17-Oct 24-Oct 23-Oct 7 6
VS3-LBW-14B-COMP 2B 18-Oct 24-Oct 23-Oct 6 5
VS3-LWF-12B-COMP 2B 16-Oct 24-Oct 23-Oct 8 7
VS3-LWF-12B-COMP 2B-DUP 16-Oct 24-Oct 23-Oct 8 7DQA-14; Analysis of Metals in Waste Revision Date: December 2012 Reviewed: December 2013

Page 4 of 10 

### Sample Date Analysis Date Holding time

Metals Excluding Mercury – ICPES Mercury –

CVAA Metals

Excluding Mercury – ICPES Mercury –

CVAA

VS3-LWF-13B-COMP 2B 17-Oct 24-Oct 23-Oct 7 6
VS3-LWF-14B-COMP 2B 18-Oct 24-Oct 23-Oct 6 5 VS4-BS-11B-COMP2B 23-Oct 8-Nov 8-Nov 16 16
VS4-BS-12B-COMP2B 24-Oct 8-Nov 8-Nov 15 15
VS4-BS-13B-COMP2B 25-Oct 8-Nov 8-Nov 14 14 VS4-CR-11B-GRAB1 23-Oct 11-Nov -- 19 -- VS4-CR-11B-GRAB2 23-Oct 11-Nov -- 19 -- VS4-CR-11B-GRAB3 23-Oct 11-Nov -- 19 -- VS4-CR-12B-GRAB1 24-Oct 11-Nov -- 18 -- VS4-CR-12B-GRAB2 24-Oct 11-Nov -- 18 -- VS4-CR-12B-GRAB3 24-Oct 11-Nov -- 18 -- VS4-CR-13B-GRAB1 25-Oct 11-Nov -- 17 -- VS4-CR-13B-GRAB2 25-Oct 11-Nov -- 17 -- VS4-CR-13B-GRAB3 25-Oct 11-Nov -- 17 -- VS4-CR-13B-GRAB4 25-Oct 11-Nov -- 17 -- VS4-CS-11B-COMP2B 23-Oct 8-Nov 8-Nov 16 16
VS4-CS-12B-COMP2B 24-Oct 8-Nov 8-Nov 15 15
VS4-CS-13B-COMP2B 25-Oct 8-Nov 8-Nov 14 14
VS4-HBW-11B-COMP2B 23-Oct 8-Nov 8-Nov 16 16
VS4-HBW-12B-COMP2B 24-Oct 8-Nov 8-Nov 15 15
VS4-HBW-12B-COMP2B-DUP 24-Oct 8-Nov 8-Nov 15 15
VS4-HBW-13B-COMP2B 25-Oct 8-Nov 8-Nov 14 14 VS4-HG-11B-GRAB1 23-Oct -- 8-Nov -- 16
VS4-HG-11B-GRAB2 23-Oct -- 8-Nov -- 16
VS4-HG-11B-GRAB3 23-Oct -- 8-Nov -- 16
VS4-HG-12B-GRAB1 24-Oct -- 8-Nov -- 15
VS4-HG-12B-GRAB2 24-Oct -- 8-Nov -- 15 VS4-HG-12B-GRAB3 24-Oct -- 8-Nov -- 15
VS4-HG-13B-GRAB1 25-Oct -- 8-Nov -- 14
VS4-HG-13B-GRAB2 25-Oct -- 8-Nov -- 14 VS4-HG-13B-GRAB3 25-Oct -- 8-Nov -- 14
VS4-LBW-11B-COMP2B 23-Oct 8-Nov 8-Nov 16 16
VS4-LBW-12B-COMP2B 24-Oct 8-Nov 8-Nov 15 15 VS4-LBW-12B-COMP2B-DUP 24-Oct 8-Nov 8-Nov 15 15
VS4-LBW-13B-COMP2B 25-Oct 8-Nov 8-Nov 14 14
VS4-LWF-11B-COMP2B 23-Oct 8-Nov 8-Nov 16 16
VS4-LWF-12B-COMP2B 24-Oct 8-Nov 8-Nov 15 15
VS4-LWF-12B-COMP2B-DUP 24-Oct 8-Nov 8-Nov 15 15
VS4-LWF-13B-COMP2B 25-Oct 8-Nov 8-Nov 14 14DQA-14; Analysis of Metals in Waste Revision Date: December 2012 Reviewed: December 2013

Page 5 of 10 

## Laboratory Blank Results

A nalytical Result (mg/kg) Arsenic Beryllium Cadmium Chromium Lead Mercury Laboratory Blank; Batch 3294020 -- -- -- -- -- <0.01 Laboratory Blank; Batch 3294021 -- -- -- -- -- <0.01 Laboratory Blank; Batch 3294022 -- -- -- -- -- <0.01 Laboratory Blank; Batch 3294026 -- -- -- -- -- <0.01 Laboratory Blank; Batch 3295019 <0.33 <0.1 <0.079 <0.22 <0.28 -- Laboratory Blank; Batch 3295020 <0.33 <0.1 <0.079 <0.22 <0.28 -- Laboratory Blank; Batch 3295059 <0.33 <0.1 <0.079 <0.22 <0.28 -- Laboratory Blank; Batch 3296030 -- -- -- <0.22 -- -- Laboratory Blank; Batch 3308021 -- -- -- -- -- <0.01 Laboratory Blank; Batch 3308023 -- -- -- -- -- <0.01 Laboratory Blank; Batch 3308024 -- -- -- -- -- <0.01 Laboratory Blank; Batch 3308025 -- -- -- -- -- <0.01 Laboratory Blank; Batch 3310018 <0.33 <0.1 <0.079 <0.22 <0.28 -- Laboratory Blank; Batch 3310020 <0.33 <0.1 <0.079 <0.22 <0.28 -- Laboratory Blank; Batch 3311018 -- -- -- <0.22 -- --


## Laboratory Check Sample (LCS) and Laboratory Check Sample Duplicate (LCSD) Results

Arsenic Beryllium Cadmium Chromium Lead Mercury LCS; Batch 3294020 LCS Recovery, % -- -- -- -- -- 94 LCS; Batch 3294021 LCS Recovery, % -- -- -- -- -- 102 LCS; Batch 3294022 LCS Recovery, % -- -- -- -- -- 100 LCS; Batch 3294026 LCS Recovery, % -- -- -- -- -- 102 LCS; Batch 3295019 LCS Recovery, % 95 104 100 101 99 -- LCS; Batch 3295020 LCS Recovery, % 99 107 103 104 101 -- LCS; Batch 3295059 LCS Recovery, % 95 103 99 99 97 --

LCS/LCSD; Batch 3296030 LCS Recovery, % -- -- -- 102 -- --

LCSD Recovery, % -- -- -- 102 -- -- Relative Percent Difference, % -- -- -- 0.07 -- --
LCS; Batch 3308021 LCS Recovery, % -- -- -- -- -- 100 LCS; Batch 3308023 LCS Recovery, % -- -- -- -- -- 97

LCS/LCSD; Batch 3308023 LCS Recovery, % -- -- -- -- -- 96

LCSD Recovery, % -- -- -- -- -- 1 Relative Percent Difference, % -- -- -- -- -- 96
LCS; Batch 3308025 LCS Recovery, % -- -- -- -- -- 95 LCS; Batch 3310018 LCS Recovery, % 95 103 100 101 100 -- LCS; Batch 3310020 LCS Recovery, % 95 104 100 102 100 --

LCS/LCSD; Batch 3311018 LCS Recovery, % -- -- -- 99 -- --

LCSD Recovery, % -- -- -- 101 -- -- Relative Percent Difference, % -- -- -- 1.6 -- --DQA-14; Analysis of Metals in Waste Revision Date: December 2012 Reviewed: December 2013

Page 6 of 10 

## Matrix Spike (MS) and Matrix Spike Duplicate (MSD) Results

Arsenic Beryllium Cadmium Chromium Lead Mercury

QAPP Specification MS/MSD Recovery (%) 70-130 70-130 70-130 70-130 70-130 75-125 RPD (%) 20 20 20 20 20 20

VS2-CS-11B-COMP2B Sample Result (mg/kg) 8.8 0.48 0.082 12.8 11.6 0.045 Spike Amount (mg/kg) 9.56 4.78 4.78 19.1 9.56 0.161 MS Result (mg/kg) 15.2 5.19 4.33 41.3 19.7 0.192 MSD Result (mg/kg) 19.2 5.35 4.35 44.4 22.2 0.202 MS Recovery (%) 67 99 89 149 85 91 MSD Recovery (%) 113 106 93 172 116 94 RPD (%) 23 3 0.34 7.2 12 4.9

VS2-CS-15B-COMP2B Sample Result (mg/kg) 8.8 0.73 0.084 16.7 13.5 0.016 Spike Amount (mg/kg) 9.77 4.88 4.88 19.5 9.77 0.155 MS Result (mg/kg) 18.5 5.29 4.46 42.1 22.6 0.18 MSD Result (mg/kg) 19 5.27 4.42 45.6 23.3 0.179 MS Recovery (%) 100 93 90 130 93 106 MSD Recovery (%) 106 94 90 150 102 108 RPD (%) 2.4 0.29 0.77 8 2.9 0.74

VS2-HBW-13BCOMP2B Sample Result (mg/kg) 2.8 <0.099 <0.078 <0.22 0.67 0.021 Spike Amount (mg/kg) 9.19 4.6 4.6 18.4 9.19 0.153 MS Result (mg/kg) 11.8 4.74 4.56 18.3 9.4 0.146 MSD Result (mg/kg) 12.5 5.05 4.89 19.5 10 0.145 MS Recovery (%) 98 103 99 100 95 82 MSD Recovery (%) 101 105 101 101 97 79 RPD (%) 6 6.4 6.9 6.1 6.6 0.39

VS2-HBW-15BCOMP2B Sample Result (mg/kg) <0.32 <0.096 <0.076 <0.21 6.7 0.096 Spike Amount (mg/kg) 9.58 4.79 4.79 19.2 9.58 0.16 MS Result (mg/kg) 9.48 5.03 4.87 19.7 15.4 0.252 MSD Result (mg/kg) 9.54 4.98 4.84 19.5 15.3 0.248 MS Recovery (%) 99 105 102 103 90 98 MSD Recovery (%) 99 104 101 102 89 97 RPD (%) 0.61 0.92 0.74 1.2 0.54 1.6

VS2-LBW-13BCOMP2B Sample Result (mg/kg) 3.2 <0.096 9 0.88 1.7 0.042 Spike Amount (mg/kg) 9.86 4.93 4.93 19.7 9.86 0.152 MS Result (mg/kg) 12.8 5.19 14.1 20.9 11.6 0.199 MSD Result (mg/kg) 12.8 5.3 13.7 21.4 11.8 0.194 MS Recovery (%) 97 105 103 101 100 103 MSD Recovery (%) 96 106 95 103 101 98 RPD (%) 0.39 2 2.6 2.2 1.4 2.5

VS2-LBW-15BCOMP2B Sample Result (mg/kg) 2.1 <0.097 7 0.74 1.1 0.052 Spike Amount (mg/kg) 9.92 4.96 4.96 19.8 9.92 0.161 MS Result (mg/kg) 11.7 5.15 12.2 21 11.2 0.197 MSD Result (mg/kg) 11.3 4.94 13 20.1 10.7 0.194 MS Recovery (%) 97 104 106 102 102 90 MSD Recovery (%) 97 104 127 102 101 91 RPD (%) 2.7 4.3 6.1 4.2 4.6 1.2DQA-14; Analysis of Metals in Waste Revision Date: December 2012 Reviewed: December 2013

Page 7 of 10 Arsenic Beryllium Cadmium Chromium Lead Mercury

QAPP Specification MS/MSD Recovery (%) 70-130 70-130 70-130 70-130 70-130 75-125 RPD (%) 20 20 20 20 20 20

VS2-LWF-13BCOMP2B Sample Result (mg/kg) <0.3 <0.092 <0.073 <0.2 <0.26 <0.0086 Spike Amount (mg/kg) 9.73 4.86 4.86 19.5 9.73 0.148 MS Result (mg/kg) 9.36 5.12 4.9 19.8 9.68 0.136 MSD Result (mg/kg) 9.14 4.98 4.78 19.3 9.51 0.138 MS Recovery (%) 96 105 101 102 99 92 MSD Recovery (%) 96 105 100 101 100 93 RPD (%) 2.3 2.7 2.6 2.6 1.8 1.4

VS2-LWF-15BCOMP2B Sample Result (mg/kg) <0.31 <0.093 <0.073 <0.2 <0.26 <0.0099 Spike Amount (mg/kg) 9.47 4.74 4.74 18.9 9.47 0.152 MS Result (mg/kg) 8.95 4.86 4.71 19 9.44 0.145 MSD Result (mg/kg) 9.1 4.97 4.82 19.7 9.75 0.152 MS Recovery (%) 95 103 99 100 100 96 MSD Recovery (%) 95 104 101 103 102 95 RPD (%) 1.7 2.3 2.3 3.5 3.2 4.6

VS3-CS-12B-COMP 2B Sample Result (mg/kg) 7.5 0.58 <0.071 13.6 11.1 0.028 Spike Amount (mg/kg) 9.24 4.62 4.62 18.5 9.24 0.159 MS Result (mg/kg) 14.9 5 4.25 37.8 19.2 0.197 MSD Result (mg/kg) 14.8 5.18 4.43 42.1 19.9 0.199 MS Recovery (%) 80 96 92 131 87 106 MSD Recovery (%) 74 93 90 145 88 103 RPD (%) 0.32 3.6 4 11 3.4 0.93

VS3-HBW-12B-COMP 2B Sample Result (mg/kg) 2.9 <0.095 <0.075 <0.21 1.8 0.027 Spike Amount (mg/kg) 9.65 4.83 4.83 19.3 9.65 0.16 MS Result (mg/kg) 12.4 5 4.9 19.4 11.5 0.183 MSD Result (mg/kg) 12.7 5.24 5.08 20.3 12 0.183 MS Recovery (%) 99 104 101 100 101 97 MSD Recovery (%) 99 105 102 102 103 97 RPD (%) 2.3 4.7 3.7 4.7 3.5 0

VS3-LBW-13B-COMP 2B Sample Result (mg/kg) 3.2 <0.097 9.4 0.87 1.9 0.049 Spike Amount (mg/kg) 9.69 4.84 4.84 19.4 9.69 0.146 MS Result (mg/kg) 12.9 5.18 14.9 21.1 11.9 0.186 MSD Result (mg/kg) 12.6 5.05 14.8 20.4 11.5 0.186 MS Recovery (%) 101 107 114 104 103 93 MSD Recovery (%) 97 104 111 101 99 95 RPD (%) 2.9 2.5 0.98 3.5 3.3 0.4

VS3-LWF-12B-COMP 2B Sample Result (mg/kg) <0.32 <0.098 <0.077 <0.22 <0.27 <0.0088 Spike Amount (mg/kg) 9.71 4.85 4.85 19.4 9.71 0.153 MS Result (mg/kg) 9.3 5.05 4.85 19.5 9.71 0.144 MSD Result (mg/kg) 9.26 4.96 4.79 19.1 9.52 0.133 MS Recovery (%) 96 104 100 101 100 94 MSD Recovery (%) 97 104 101 101 100 91 RPD (%) 0.45 1.8 1.1 2 2 8DQA-14; Analysis of Metals in Waste Revision Date: December 2012 Reviewed: December 2013

Page 8 of 10 Arsenic Beryllium Cadmium Chromium Lead Mercury

QAPP Specification MS/MSD Recovery (%) 70-130 70-130 70-130 70-130 70-130 75-125 RPD (%) 20 20 20 20 20 20

VS4-BS-13B-COMP2B Sample Result (mg/kg) 2.2 0.26 0.3 29.8 26.6 0.077 Spike Amount (mg/kg) 9.26 4.63 4.63 18.5 9.26 0.151 MS Result (mg/kg) 10.8 4.61 4.02 54.2 38 0.236 MSD Result (mg/kg) 10.9 4.74 4.18 54.8 45.9 0.234 MS Recovery (%) 93 94 80 132 124 106 MSD Recovery (%) 94 96 83 134 208 105 RPD (%) 1.1 2.7 3.7 0.94 19 1.2

VS4-CS-13B-COMP2B Sample Result (mg/kg) 2.1 <0.1 0.45 35.1 25.4 0.26 Spike Amount (mg/kg) 9.36 4.68 4.68 18.7 9.36 0.154 MS Result (mg/kg) 11.7 4.66 4.56 65.9 63.3 0.352 MSD Result (mg/kg) 12.2 4.98 4.92 72.2 38.2 0.326 MS Recovery (%) 103 100 88 164 406 61 MSD Recovery (%) 102 100 90 186 129 45 RPD (%) 4.2 6.6 7.5 9.1 49 7.8

VS4-HBW-13BCOMP2B Sample Result (mg/kg) <0.32 <0.097 <0.077 <0.21 <0.27 0.018 Spike Amount (mg/kg) 9.62 4.81 4.81 19.2 9.62 0.162 MS Result (mg/kg) 9.35 4.97 4.86 19.3 9.78 0.172 MSD Result (mg/kg) 9.41 4.95 4.84 19.4 9.76 0.172 MS Recovery (%) 97 103 101 100 102 95 MSD Recovery (%) 99 104 102 102 102 98 RPD (%) 0.64 0.43 0.35 0.46 0.23 0.11

VS4-LBW-12BCOMP2B Sample Result (mg/kg) 4.9 <0.098 12.1 1.2 2.9 0.14 Spike Amount (mg/kg) 9.45 4.73 4.73 18.9 9.45 0.152 MS Result (mg/kg) 15.1 4.87 17.6 20.3 12.8 0.246 MSD Result (mg/kg) 15.7 4.84 18.8 20.2 13 0.24 MS Recovery (%) 108 103 115 101 104 71 MSD Recovery (%) 116 104 145 102 109 66 RPD (%) 3.9 0.56 7 0.56 2.1 2.6

VS4-LWF-12BCOMP2B Sample Result (mg/kg) <0.32 <0.098 <0.077 <0.22 <0.27 0.019 Spike Amount (mg/kg) 9.75 4.87 4.87 19.5 9.75 0.161 MS Result (mg/kg) 9.45 5.01 4.91 19.7 9.91 0.171 MSD Result (mg/kg) 9 4.8 4.66 18.7 9.4 0.178 MS Recovery (%) 97 103 101 101 102 94 MSD Recovery (%) 97 103 100 101 101 96 RPD (%) 4.8 4.3 5.3 5.1 5.3 3.9DQA-14; Analysis of Metals in Waste Revision Date: December 2012 Reviewed: December 2013

Page 9 of 10 

## Results of Duplicate Analysis of Selected Samples

C hromium Mercury Analytical Result (mg/kg) Relative

Percent Difference (%) Analytical Result

(mg/kg) Relative

Percent Difference (%) First Analysis Second

Analysis First Analysis Second

Analysis VS2-CR-13B-GRAB2 174,000 175,000 0.72 -- -- -- VS2-CR-15B-GRAB1 174,000 178,000 1.8 -- -- -- VS2-HG-13B-GRAB2 -- -- -- 2,150 2,270 5.2 VS2-HG-15B-GRAB3 -- -- -- 2,250 2,140 5 VS3-CR-13B-GRAB 2 179,000 176,000 1.7 -- -- -- VS3-HG-14B-GRAB 2 -- -- -- 2,500 2,410 3.6 VS4-CR-12B-GRAB1 173,000 172,000 0.43 -- -- -- VS4-HG-12B-GRAB2 -- -- -- 19,900 19,800 0.88



## Results of Analysis of Duplicate Samples

A rsenic Beryllium Analytical Result (mg/kg) Relative

Percent Difference (%) Analytical Result

(mg/kg) Relative

Percent Difference (%) Sample Duplicate Sample Duplicate

VS2-HBW-13B-COMP2B 2.8 3 6.9 <0.099 <0.097 NC 1
VS2-LBW-13B-COMP2B 3.2 3 6.5 <0.096 <0.095 NC VS2-LWF-13B-COMP2B <0.3 <0.31 NC <0.092 <0.095 NC VS3-HBW-12B-COMP 2B 2.9 3 3.4 <0.095 <0.098 NC

VS3-LBW-12B-COMP 2B 4.8 4 18.2 <0.096 <0.1 NC VS3-LWF-12B-COMP 2B <0.32 <0.32 NC <0.098 <0.096 NC VS4-HBW-12B-COMP2B 0.37 0.39 5.3 <0.093 <0.094 NC VS4-LBW-12B-COMP2B 4.9 4.8 2.1 <0.098 <0.094 NC VS4-LWF-12B-COMP2B <0.32 <0.3 NC <0.098 <0.092 NC VS2-HBW-13B-COMP2B 2.8 3 6.9 <0.099 <0.097 NC VS2-LBW-13B-COMP2B 3.2 3 6.5 <0.096 <0.095 NC VS2-LWF-13B-COMP2B <0.3 <0.31 NC <0.092 <0.095 NC

1 NC: Not Calculated; at least one result is below the detection limit.DQA-14; Analysis of Metals in Waste Revision Date: December 2012 Reviewed: December 2013

Page 10 of 10 Cadmium Chromium Analytical Result (mg/kg) Relative

Percent Difference (%) Analytical Result

(mg/kg) Relative

Percent Difference (%) Sample Duplicate Sample Duplicate

VS2-HBW-13B-COMP2B <0.078 <0.077 NC <0.22 <0.21 NC VS2-LBW-13B-COMP2B 9 8.5 5.7 0.88 0.83 5.8 VS2-LWF-13B-COMP2B <0.073 <0.075 NC <0.2 <0.21 NC VS3-HBW-12B-COMP 2B <0.075 <0.077 NC <0.21 <0.22 NC

VS3-LBW-12B-COMP 2B 15.2 13 15.6 1.3 1.1 16.7 VS3-LWF-12B-COMP 2B <0.077 <0.076 NC <0.22 <0.21 NC VS4-HBW-12B-COMP2B <0.073 <0.074 NC <0.2 <0.21 NC VS4-LBW-12B-COMP2B 12.1 13.1 7.9 1.2 1.2 0.0 VS4-LWF-12B-COMP2B <0.077 <0.073 NC <0.22 <0.2 NC VS2-HBW-13B-COMP2B <0.078 <0.077 NC <0.22 <0.21 NC VS2-LBW-13B-COMP2B 9 8.5 5.7 0.88 0.83 5.8 VS2-LWF-13B-COMP2B <0.073 <0.075 NC <0.2 <0.21 NC Lead Mercury Analytical Result (mg/kg) Relative

Percent Difference (%) Analytical Result

(mg/kg) Relative

Percent Difference (%) Sample Duplicate Sample Duplicate

VS2-HBW-13B-COMP2B 0.67 0.5 29.1 0.021 <0.0095 NC VS2-LBW-13B-COMP2B 1.7 1.6 6.1 0.042 0.045 6.9 VS2-LWF-13B-COMP2B <0.26 <0.27 NC <0.0086 <0.0091 NC VS3-HBW-12B-COMP 2B 1.8 1.9 5.4 0.027 0.028 3.6

VS3-LBW-12B-COMP 2B 3.1 2.8 10.2 0.065 0.083 24.3 VS3-LWF-12B-COMP 2B <0.27 <0.27 NC <0.0088 <0.0092 NC VS4-HBW-12B-COMP2B 0.4 0.41 2.5 0.021 0.021 0.0 VS4-LBW-12B-COMP2B 2.9 3 3.4 0.14 0.13 7.4 VS4-LWF-12B-COMP2B <0.27 <0.26 NC 0.019 0.014 30.3 VS2-HBW-13B-COMP2B 0.67 0.5 29.1 0.021 <0.0095 NC VS2-LBW-13B-COMP2B 1.7 1.6 6.1 0.042 0.045 6.9 VS2-LWF-13B-COMP2B <0.26 <0.27 NC <0.0086 <0.0091 NCDQA-20: Metals Analysis for Stack Gas Revision Date: January 2013

Page 1 of 12 

# Data Quality Assessment A nalysis of Stack Gas for Metals

**Parameter** Selected Metals in Stack Gas 

### Sampling Method EPA Method 29



### Analytical Method ICPES, SW-846 Method 6010B

CVAA, SW846 Method 7470A 

### Laboratory Job ID Number(s) H3J150406, H3J190412, H3K010412, H3K010422


### Preparation Batch Number(s) 3302012, 3302013, 3302049, 3302051, 3302053, 3308026, 3308027, 3308028, 3311021, 3311022, 3311038, 3311039


### Sample Shipping and Receipt Samples received intact and at ambient temperature. QAPP has no specification for temperature.



### Holding Time(s) All samples analyzed within 28 days of sample collection.

QAPP specifies analysis within 28 days for mercury and 180 days for all other analytes. See table below.



### Blank Results 29 of 31 laboratory blank analyses were below the detection limit. The

outliers were for arsenic in batches associated with analysis of PNR/filter samples. Cadmium and mercury were each found in one field blank sample. Chromium was consistently observed in field blanks and media check samples. See tables below and in the main body of the report.



### Laboratory Control Sample (LCS) **and Laboratory Control Sample Duplicate (LCSD) Results**  All recoveries are between 90 and 110%. All relative percent deviations are below 10%. The QAPP specifies LCS recovery between 80 and 120%. The QAPP has no specification for RPD; the laboratory specifications are for RPD below 20%. See tables below.


### Matrix Spike (MS) and Matrix **Spike (MSD) Results Post Digestion Spike (PDS) and**  **Post Digestion Spike Duplicate**

**(PDSD) Results** QAPP specifications are MS/MSD at 70-130% recovery, <20% RPD for

everything except mercury, 75-125% recovery and 20% RPD for mercury. PDS/PDSD are to show recovery between 75 and 125% for metals excluding mercury and 80-120% recovery for mercury. There are no specifications for RPD on PDS/PDSD. . All MS/MSD and PDS/PDSD results met these criteria. Results are summarized in tables below.



### Date Quality Objectives These are given in terms of matrix spike/matrix spike duplicate. Precision: <20% relative percent difference. Accuracy: 75-125% recovery.For stack samples this is applied to the post-digestion spike and postdigestion spike duplicates. These data quality objectives were all met.DQA-20: Metals Analysis for Stack Gas Revision Date: January 2013

Page 2 of 12 

### Conclusions and Comments These data are acceptable for the intended purpose. The blank results for arsenic in the laboratory blanks are near the detection limit, and similar or below the results for the field samples. This may indicate a slight positive bias in the field results. The single positive result for cadmium in one field blank is similar in magnitude to the field results. This may indicate a positive bias or false identification of cadmium in the field samples. The single positive result for mercury in one field blank is near the detection limit, and well below many of the field results. This may indicate a slight positive bias in the field samples. The consistent observation of chromium in field blank and media check samples is at a lower level than the field samples. This may indicate a slight positive bias in the results for the field samples. Any positive bias in these results is conservative in the demonstration of compliance. No results are invalidated or qualified based on blank results.DQA-20: Metals Analysis for Stack Gas Revision Date: January 2013

Page 3 of 12 

## Holding Time

**S ample**  **Date Metals Excluding Mercury** 

**by ICPES Mercury by CVAA** 
**Analysis Date**  **Holding**

**Time (days) Analysis** 

**Date Holding** 

**Time (days)** VS2-STK-11B-M29 PNR/FILT 8-Oct 5-Nov 5-Nov 28 28
VS2-STK-11B-M29 NPI 8-Oct 5-Nov 5-Nov 28 28
VS2-STK-11B-M29 NPI4 8-Oct 5-Nov 5-Nov 28 28
VS2-STK-11B-M29 PERM1 8-Oct 5-Nov 5-Nov 28 28
VS2-STK-11B-M29 PERM2 8-Oct -- 5-Nov -- 28
VS2-STK-11B-M29 HCLRNS 8-Oct -- 5-Nov -- 28 VS2-STK-13B-M29 PNR/FILT 10-Oct 5-Nov 5-Nov 26 26
VS2-STK-13B-M29 NPI 10-Oct 5-Nov 5-Nov 26 26
VS2-STK-13B-M29 EIR 10-Oct -- 5-Nov -- 26
VS2-STK-13B-M29 PERM 10-Oct -- 5-Nov -- 26
VS2-STK-13B-M29 HCLRNS 10-Oct -- 5-Nov -- 26 VS2-STK-15B-M29-PNR/FILT 30-Oct 14-Nov 14-Nov 15 15 VS2-STK-15B-M29-NPI/NPIB 30-Oct 14-Nov 14-Nov 15 15
VS2-STK-15B-M29-EIR 30-Oct -- 14-Nov -- 15
VS2-STK-15B-M29-PERM 30-Oct -- 14-Nov -- 15
VS2-STK-15B-M29-HCLRNS 30-Oct -- 14-Nov -- 15 VS3-STK-12B-M29-PNR/FILT 16-Oct 5-Nov 5-Nov 20 20
VS3-STK-12B-M29-NPI 16-Oct 5-Nov 5-Nov 20 20
VS3-STK-12B-M29-EIR 16-Oct -- 5-Nov -- 20
VS3-STK-12B-M29-PERM 16-Oct -- 5-Nov -- 20
VS3-STK-12B-M29-HCLRNS 16-Oct -- 5-Nov -- 20 VS3-STK-13B-M29-PNR/FILT 17-Oct 5-Nov 5-Nov 19 19
VS3-STK-13B-M29-NPI 17-Oct 5-Nov 5-Nov 19 19
VS3-STK-13B-M29-EIR 17-Oct -- 5-Nov -- 19
VS3-STK-13B-M29-PERM 17-Oct -- 5-Nov -- 19
VS3-STK-13B-M29-HCLRNS 17-Oct -- 5-Nov -- 19 VS3-STK-14B-M29-PNR/FILT 18-Oct 5-Nov 5-Nov 18 18
VS3-STK-14B-M29-NPI 18-Oct 5-Nov 5-Nov 18 18
VS3-STK-14B-M29-EIR 18-Oct -- 5-Nov -- 18
VS3-STK-14B-M29-PERM 18-Oct -- 5-Nov -- 18
VS3-STK-14B-M29-HCLRNS 18-Oct -- 5-Nov -- 18 VS4-STK-11B-M29-PNR/FILT 23-Oct 14-Nov 14-Nov 22 22 VS4-STK-11B-M29-NPI/NPIB 23-Oct 14-Nov 14-Nov 22 22
VS4-STK-11B-M29-EIR 23-Oct -- 14-Nov -- 22
VS4-STK-11B-M29-PERM 23-Oct -- 14-Nov -- 22
VS4-STK-11B-M29-HCLRNS 23-Oct -- 14-Nov -- 22 VS4-STK-12B-M29-PNR/FILT 24-Oct 14-Nov 14-Nov 21 21 VS4-STK-12B-M29-NPI/NPIB 24-Oct 14-Nov 14-Nov 21 21
VS4-STK-12B-M29-EIR 24-Oct -- 14-Nov -- 21DQA-20: Metals Analysis for Stack Gas Revision Date: January 2013

Page 4 of 12 

### Sample **Date Metals Excluding Mercury** 

**by ICPES Mercury by CVAA** 
**Analysis Date**  **Holding**

**Time (days) Analysis** 

**Date Holding** 

**Time (days)**

VS4-STK-12B-M29-PERM 24-Oct -- 14-Nov -- 21
VS4-STK-12B-M29-HCLRNS 24-Oct -- 14-Nov -- 21 VS4-STK-13B-M29-PNR/FILT 25-Oct 14-Nov 14-Nov 20 20 VS4-STK-13B-M29-NPI/NPIB 25-Oct 14-Nov 14-Nov 20 20
VS4-STK-13B-M29-EIR 25-Oct -- 14-Nov -- 20
VS4-STK-13B-M29-PERM 25-Oct -- 14-Nov -- 20
VS4-STK-13B-M29-HCLRNS 25-Oct -- 14-Nov -- 20 VS2-STK-1FB2-M29-PNR/FILT 29-Oct 14-Nov 14-Nov 16 16
VS2-STK-1FB2-M29-NPI 29-Oct 14-Nov 14-Nov 16 16
VS2-STK-1FB2-M29-EIR 29-Oct -- 14-Nov -- 16
VS2-STK-1FB2-M29-PERM 29-Oct -- 14-Nov -- 16
VS2-STK-1FB2-M29-HCLRNS 29-Oct -- 14-Nov -- 16 VS2-STK-1FB-M29 PNR/FILT 8-Oct 5-Nov 5-Nov 28 28
VS2-STK-1FB-M29 NPI 8-Oct 5-Nov 5-Nov 28 28
VS2-STK-1FB-M29 EIR 8-Oct -- 5-Nov -- 28
VS2-STK-1FB-M29 PERM 8-Oct -- 5-Nov -- 28
VS2-STK-1FB-M29 HLCRNS 8-Oct -- 5-Nov -- 28
VS2-STK-1RB-M29 PERM SOLN 11-Oct 14-Nov -- 34 -- VS3-STK-1FB-M29-PNR/FILT 14-Oct 5-Nov 5-Nov 22 22
VS3-STK-1FB-M29-NPI 14-Oct 5-Nov 5-Nov 22 22
VS3-STK-1FB-M29-EIR 14-Oct -- 5-Nov -- 22
VS3-STK-1FB-M29-PERM 14-Oct -- 5-Nov -- 22
VS3-STK-1FB-M29-HCLRNS 14-Oct -- 5-Nov -- 22 VS4-STK-1FB-M29-PNR/FILT 23-Oct 14-Nov 14-Nov 22 22
VS4-STK-1FB-M29-NPI 23-Oct 14-Nov 14-Nov 22 22
VS4-STK-1FB-M29-EIR 23-Oct -- 14-Nov -- 22
VS4-STK-1FB-M29-PERM 23-Oct -- 14-Nov -- 22
VS4-STK-1FB-M29-HCLRNS 23-Oct -- 14-Nov -- 22
VS2-AUDIT-MET-IMP 11-Oct 5-Nov -- 25 -- VS2-AUDIT-MET-FILT 11-Oct 5-Nov -- 25 -- VS2-AUDIT-HG-1 11-Oct -- 5-Nov -- 25DQA-20: Metals Analysis for Stack Gas Revision Date: January 2013

Page 5 of 12 

## Blank Results – Metals Excluding Mercury

**B lank Results (μg/sample)**  **Arsenic Beryllium Cadmium Chromium Lead** VS2-STK-1FB2-M29-PNR/FILT <0.74 <0.015 <0.021 **1.8** <1
VS2-STK-1FB2-M29-NPI <0.25 <0.015 <0.021 **0.18** <0.27 VS2-STK-1FB-M29 PNR/FILT <0.74 <0.015 <0.021 **1.8** <1
VS2-STK-1FB-M29 NPI <0.25 <0.015 <0.021 **0.27** <0.27 VS3-STK-1FB-M29-PNR/FILT <0.74 <0.015 <0.021 **1.7** <1
VS3-STK-1FB-M29-NPI <0.25 <0.015 <0.021 **0.25** <0.27 VS4-STK-1FB-M29-PNR/FILT <0.74 <0.015 **0.24 1.8**  <1
VS4-STK-1FB-M29-NPI <0.25 <0.015 <0.021 **0.26** <0.27
MEDIA CHECK A 5040 <0.74 <0.015 <0.021 **1.3** <1
A-5078 MEDIA CHECK <0.74 <0.015 <0.021 **1.5** <1
A-5060 MEDIA CHECK <0.74 <0.015 <0.021 **1.4** <1 Laboratory Blank; Batch 3302012 **0.55** <0.015 <0.021 <0.32 <0.52 Laboratory Blank; Batch 3302013 <0.25 <0.015 <0.021 <0.14 <0.27 Laboratory Blank; Batch 3311021 **0.53** <0.015 <0.021 <0.32 <0.52 Laboratory Blank; Batch 3311022 <0.25 <0.015 <0.021 <0.14 <0.27

Range of Field Samples Filter <0.37 - 9.1 <0.021 - 0.91 2.3 - 13.7 <0.37 - 9.1
NPI 0.55 - 0.82DQA-20: Metals Analysis for Stack Gas Revision Date: January 2013

Page 6 of 12 

## Blank Results –Mercury

**M ercury**  **(μg/sample)** VS2-STK-1FB2-M29-PNR/FILT <0.08
VS2-STK-1FB2-M29-NPI <0.12
VS2-STK-1FB2-M29-EIR <0.12
VS2-STK-1FB2-M29-PERM <0.012
VS2-STK-1FB2-M29-HCLRNS <0.045 VS2-STK-1FB-M29 PNR/FILT <0.08
VS2-STK-1FB-M29 NPI <0.12
VS2-STK-1FB-M29 EIR <0.12
VS2-STK-1FB-M29 PERM <0.047
VS2-STK-1FB-M29 HLCRNS **0.12** VS3-STK-1FB-M29-PNR/FILT <0.08
VS3-STK-1FB-M29-NPI <0.12
VS3-STK-1FB-M29-EIR <0.11
VS3-STK-1FB-M29-PERM <0.045
VS3-STK-1FB-M29-HCLRNS <0.082 VS4-STK-1FB-M29-PNR/FILT <0.08
VS4-STK-1FB-M29-NPI <0.12
VS4-STK-1FB-M29-EIR <0.11
VS4-STK-1FB-M29-PERM <0.012
VS4-STK-1FB-M29-HCLRNS <0.045
MEDIA CHECK A 5040 <0.08
A-5078 MEDIA CHECK <0.08
A-5060 MEDIA CHECK <0.08 Laboratory Blank; Batch 3302053 <0.006 Laboratory Blank; Batch 3302053 <0.015 Laboratory Blank; Batch 3302049 <0.08 Laboratory Blank; Batch 3302051 <0.12 Laboratory Blank; Batch 3302051 <0.06 Laboratory Blank; Batch 3308026 <0.08 Laboratory Blank; Batch 3308027 <0.12 Laboratory Blank; Batch 3311038 <0.06 Laboratory Blank; Batch 3308028 <0.006 Laboratory Blank; Batch 3311039 <0.015 Laboratory Blank; MW5WM1AD <0.015 Range of Field Samples (HCl Rinse) <0.082 – 17.2DQA-20: Metals Analysis for Stack Gas Revision Date: January 2013

Page 7 of 12 

## Laboratory Control Sample (LCS) and Laboratory Control **S ample Duplicate (LCSD) Results – Metals Excluding** 

**Mercury**
**Arsenic Beryllium Cadmium Chromium Lead**

LCS/LCSD Recovery; Batch 3302012 LCS Recovery (%) 102 105 102 103 104 LCSD Recovery (%) 102 102 100 102 103 Relative Percent Difference (%) 0.5 2.4 1.8 1.1 1.3

LCS/LCSD Recovery; Batch 3302013 LCS Recovery (%) 92 105 99 100 99 LCSD Recovery (%) 93 104 98 100 98 Relative Percent Difference (%) 0.72 1.2 0.46 0.07 1.1

LCS/LCSD Recovery; Batch 3311021 LCS Recovery (%) 102 105 103 104 104 LCSD Recovery (%) 102 103 102 103 103 Relative Percent Difference (%) 0.19 1.9 1.4 0.81 0.78

LCS/LCSD Recovery; Batch 3311022 LCS Recovery (%) 94 108 101 103 105 LCSD Recovery (%) 92 102 97 100 98 Relative Percent Difference (%) 1.9 5.2 4.1 3.4 7.3



## Laboratory Control Sample (LCS) and Laboratory Control **Sample Duplicate (LCSD) Results –Mercury**

LCS/LCSD; Batch 3302049 L CS Recovery (%) 99 LCSD Recovery (%) 96
Relative Percent Difference (%) 2.9
LCS; Batch 3302051 LCS Recovery (%) 98 LCS; Batch 3302053 LCS Recovery (%) 98

LCS/LCSD; Batch 3308026 LCS Recovery (%) 105 LCSD Recovery (%) 106
Relative Percent Difference (%) 1.1
LCS; Batch 3308027 LCS Recovery (%) 95 LCS; Batch 3308028 LCS Recovery (%) 104 LCS; Batch 3311038 LCS Recovery (%) 101 LCS; Batch 3311039 LCS Recovery (%) 97DQA-20: Metals Analysis for Stack Gas Revision Date: January 2013

Page 8 of 12 

## Matrix Spike (MS) and Matrix Spike (MSD) Results

**M ercury** 

VS2-STK-13B-M29 EIR Sample Result (μg/L) 0.57 Spike Amount (μg/sample) 2 MS Result (μg/sample) 2.6 MSD Result (μg/sample) 2.64 MS Recovery (%) 102 MSD Recovery (%) 104 Relative Percent Difference (%) 1.5

VS2-STK-13B-M29 HCLRNS Sample Result (μg/sample) 17.2 Spike Amount (μg/sample) 1.38 MS Result (μg/sample) 19.4 MSD Result (μg/sample) 18.6 MS Recovery (%) N/C 1 MSD Recovery (%) N/C Relative Percent Difference (%) N/C

VS2-STK-13B-M29 NPI Sample Result (μg/sample) 182 Spike Amount (μg/sample) 2 MS Result (μg/sample) 182 MSD Result (μg/sample) 200 MS Recovery (%) N/C MSD Recovery (%) N/C Relative Percent Difference (%) N/C

VS2-STK-13B-M29 PERM Sample Result (μg/sample) 0.5 Spike Amount (μg/sample) 0.81 MS Result (μg/sample) 1.3 MSD Result (μg/sample) 1.19 MS Recovery (%) 100 MSD Recovery (%) 86 Relative Percent Difference (%) 9.1

VS2-STK-15B-M29-EIR Sample Result (μg/sample) <0.15 Spike Amount (μg/sample) 2.5 MS Result (μg/sample) 2.65 MSD Result (μg/sample) 2.62 MS Recovery (%) 106 MSD Recovery (%) 105 Relative Percent Difference (%) 0.94

VS2-STK-15B-M29-HCLRNS Sample Result (μg/sample) 14.3 Spike Amount (μg/sample) 1.35 MS Result (μg/sample) 15.1 MSD Result (μg/sample) 15.1 MS Recovery (%) N/C MSD Recovery (%) N/C Relative Percent Difference (%) N/C

1 N/C – Not Calculated; Spiking level is less than 25% of native level.DQA-20: Metals Analysis for Stack Gas Revision Date: January 2013

Page 9 of 12 

### Mercury

VS2-STK-15B-M29-NPI/NPIB Sample Result (μg/sample) 142 Spike Amount (μg/sample) 2 MS Result (μg/sample) 145 MSD Result (μg/sample) 147 MS Recovery (%) N/C MSD Recovery (%) N/C Relative Percent Difference (%) N/C

VS2-STK-15B-M29-PERM Sample Result (μg/sample) 3.4 Spike Amount (μg/sample) 0.8 MS Result (μg/sample) 4.22 MSD Result (μg/sample) 4.3 MS Recovery (%) 100 MSD Recovery (%) 110 Relative Percent Difference (%) 1.9

VS3-STK-13B-M29-EIR Sample Result (μg/sample) 0.25 Spike Amount (μg/sample) 2 MS Result (μg/sample) 2.3 MSD Result (μg/sample) 2.26 MS Recovery (%) 102 MSD Recovery (%) 100 Relative Percent Difference (%) 1.8

VS3-STK-13B-M29-HCLRNS Sample Result (μg/sample) 2.6 Spike Amount (μg/sample) 1.38 MS Result (μg/sample) 4.04 MSD Result (μg/sample) 3.93 MS Recovery (%) 107 MSD Recovery (%) 99 Relative Percent Difference (%) 2.8

VS3-STK-13B-M29-NPI Sample Result (μg/sample) 52.2 Spike Amount (μg/sample) 2 MS Result (μg/sample) 53.6 MSD Result (μg/sample) 53.6 MS Recovery (%) N/C MSD Recovery (%) N/C Relative Percent Difference (%) N/C

VS3-STK-13B-M29-PERM Sample Result (μg/sample) <0.048 Spike Amount (μg/sample) 0.8 MS Result (μg/sample) 0.848 MSD Result (μg/sample) 0.864 MS Recovery (%) 106 MSD Recovery (%) 108 Relative Percent Difference (%) 1.9

VS4-STK-12B-M29-EIR Sample Result (μg/sample) <0.12 Spike Amount (μg/sample) 1.96 MS Result (μg/sample) 2.02 MSD Result (μg/sample) 1.98 MS Recovery (%) 103 MSD Recovery (%) 101 Relative Percent Difference (%) 2DQA-20: Metals Analysis for Stack Gas Revision Date: January 2013

Page 10 of 12 

### Mercury

VS4-STK-12B-M29-HCLRNS Sample Result (μg/sample) <0.082 Spike Amount (μg/sample) 1.38 MS Result (μg/sample) 1.47 MSD Result (μg/sample) 1.4 MS Recovery (%) 107 MSD Recovery (%) 102 Relative Percent Difference (%) 4.8

VS4-STK-12B-M29-NPI/NPIB Sample Result (μg/sample) 10.4 Spike Amount (μg/sample) 2 MS Result (μg/sample) 12.2 MSD Result (μg/sample) 12.3 MS Recovery (%) 88 MSD Recovery (%) 92 Relative Percent Difference (%) 0.65

VS4-STK-12B-M29-PERM Sample Result (μg/sample) <0.047 Spike Amount (μg/sample) 0.79 MS Result (μg/sample) 0.78 MSD Result (μg/sample) 0.784 MS Recovery (%) 99 MSD Recovery (%) 99 Relative Percent Difference (%) 0.6
QAPP Specification Recovery (%) 75-125 Relative Percent Difference (%) 20DQA-20: Metals Analysis for Stack Gas Revision Date: January 2013

Page 11 of 12 

## Post Digestion Spike (PDS) and Post Digestion Spike Duplicate (PDSD) Results
**Arsenic Beryllium Cadmium Chromium Lead Mercury**

VS2-STK-13BM29 PNR/FILT Sample Result (μg/L) 1.96 0 0 12.6 3.27

Spike Amount (μg/L) 100 50 50 200 100 PDS Result (μg/L) 96.66 50.49 48.22 210.63 98.35 PDSD Result (μg/L) 98.97 52.19 49.74 218.81 106.79 PDS Recovery (%) 94.7 101 96.4 99 95.1 PDSD Recovery (%) 97 104.4 99.5 103.1 103.5 Relative Percent Difference (%) 2.4 3.3 3.1 3.8 8.2

VS2-STK-13BM29 NPI Sample Result (μg/L) 0 0 0 5.54 2.72

Spike Amount (μg/L) 100 50 50 200 100 PDS Result (μg/L) 90.63 50.46 47.92 199.95 96.5 PDSD Result (μg/L) 93.24 50.94 48.93 202.3 97.68 PDS Recovery (%) 90.6 100.9 95.8 97.2 93.8 PDSD Recovery (%) 93.2 101.9 97.9 98.4 95 Relative Percent Difference (%) 2.8 0.9 2.1 1.2 1.2

VS2-STK-15BM29-PNR/FILT Sample Result (μg/L) 3.84 0 0 23.31 0 0

Spike Amount (μg/L) 100 50 50 200 100 1 PDS Result (μg/L) 99.11 50.86 47.16 226.83 95.98 0.97 PDSD Result (μg/L) 100.79 50.72 46.46 222.84 100.51 0.96 PDS Recovery (%) 95.3 101.7 94.3 101.8 96 96.6 PDSD Recovery (%) 97 101.4 29.9 99.8 100.5 95.7 Relative Percent Difference (%) 1.7 0.3 1.5 1.8 4.6 1.0

VS2-STK-15BM29-NPI/NPIB Sample Result (μg/L) 0 0 0.09 8.11 6.61

Spike Amount (μg/L) 100 50 50 200 100 PDS Result (μg/L) 90.55 50.61 49.15 203.87 100.93 PDSD Result (μg/L) 91.8 51.47 49.39 209.66 104.56 PDS Recovery (%) 90.6 101.2 98.1 97.9 94.3 PDSD Recovery (%) 91.8 102.9 98.6 100.8 98 Relative Percent Difference (%) 1.4 1.7 0.5 2.8 3.5

VS3-STK-13BM29-PNR/FILT Sample Result (μg/L) 0 0 0 109.93 201.4 0

Spike Amount (μg/L) 100 50 50 200 100 1 PDS Result (μg/L) 84.82 49.9 47.23 304.97 279.87 1.07 PDSD Result (μg/L) 83.63 50.36 47.45 303.64 284.71 1.07 PDS Recovery (%) 84.8 99.8 94.5 97.5 78.5 107 PDSD Recovery (%) 83.6 100.7 94.9 96.9 83.3 107 Relative Percent Difference (%) 1.4 0.9 0.5 0.4 1.7 0.0

VS3-STK-13BM29-PNR/FILT Sample Result (μg/L) 0 0 0 56.86 97.14

Spike Amount (μg/L) 100 50 50 200 100 PDS Result (μg/L) 90.34 49.66 48.07 249.36 188.42 PDSD Result (μg/L) 92.16 51.4 49.74 254.91 194.95 PDS Recovery (%) 90.3 99.3 96.1 96.3 91.3 PDSD Recovery (%) 92.2 102.1 99.5 99 97.8 Relative Percent Difference (%) 2.0 3.4 3.4 2.2 3.4DQA-20: Metals Analysis for Stack Gas Revision Date: January 2013

Page 12 of 12 

### Arsenic Beryllium Cadmium Chromium Lead Mercury

VS3-STK-13BM29-NPI Sample Result (μg/L) 0 0 0.08 7.92 1.57

Spike Amount (μg/L) 100 50 50 200 100 PDS Result (μg/L) 90.28 51.2 48.78 206.47 100.82 PDSD Result (μg/L) 91.4 51.33 49.47 206.04 99.77 PDS Recovery (%) 90.3 102.4 97.4 99.3 99.3 PDSD Recovery (%) 91.4 102.7 98.8 99.1 98.2 Relative Percent Difference (%) 1.2 0.3 1.4 0.2 1.0

VS4-STK-12BM29-PNR/FILT Sample Result (μg/L) 39.57 0 1.52 41.75 26.82 0

Spike Amount (μg/L) 100 50 50 200 100 1 PDS Result (μg/L) 134.99 52.2 51.49 252.68 122.8 0.97 PDSD Result (μg/L) 134.39 50.28 50.31 241.36 123.87 0.96 PDS Recovery (%) 95.4 104.4 99.9 105.5 96 96.9 PDSD Recovery (%) 94.8 100.6 97.6 99.8 97 96 Relative Percent Difference (%) 0.4 3.7 2.3 4.6 0.9 1.0

VS4-STK-12BM29-NPI/NPIB Sample Result (μg/L) 0 0 0.17 6.65 4.19

Spike Amount (μg/L) 100 50 50 200 100 PDS Result (μg/L) 91.18 51.03 48.79 206.53 102.04 PDSD Result (μg/L) 90.38 50.79 48.31 203.9 102.96 PDS Recovery (%) 91.2 102.1 97.2 99.9 97.9 PDSD Recovery (%) 90.4 101.6 96.3 98.6 98.8 Relative Percent Difference (%) 0.9 0.5 1.0 1.3 0.9DQA-21: Analysis of HCl and Cl 2 in Gas Revision Date: December 2012

Page 1 of 6 

# Data Quality Assessment A nalysis of Stack Gas for Hydrogen Chloride and Chlorine

**Parameter** Hydrogen Chloride and Chlorine in Stack Gas 

### Sampling Method EPA Method 26A 

### Analytical Method Ion Chromatography, EPA Method 26A 

### Laboratory Project ID

**Number(s)** H3J140410, H3J190409, H3K010414, H3K020401 

### Preparation Batch Number(s) 3295039, 3295058, 3301068, 3302015, 3312042, 3312045, 3316053 

### Sample Shipping and Receipt Sample received intact and at ambient temperature. QAPP has no specification for preservation.



### Holding Time(s) All samples prepared and analyzed within 20 days of sample collection.

QAPP specifies analysis within 28 days. See table below.



### Blank Results Nothing detected in laboratory blanks. Hydrogen chloride consistently

detected in field blanks. See table below. 

### Laboratory Check Sample (LCS) **and Laboratory Check Sample (LCSD) Results**  All LCS recoveries are between 95 and 105%. All RPDs are below 5%. The QAPP specifies LCS recovery between 90 and 110%. There are no QAPP specifications for LCSD or for precision. See table below.



### Matrix Spike (MS) and Matrix **Spike Duplicate (MSD) Results** All recoveries are between 85 and 120%: all RPDs are less than 10%. QAPP specifies recovery between 75 and 125%. There are no QAPP specifications for RPD. See table below.



### Duplicate Analyses All samples analyzed in duplicate. RPD for all samples below 5%.

QAPP specifies RPD below 10%. See table below.



### Data Quality Objective These are given as follows:

• Accuracy: matrix spike recovery between 75 and 125%.

• Precision: RPD for duplicate analysis of each sample less than 10%. These objectives were met.



### Conclusions and Comments These data are acceptable for the intended purpose. The levels of hydrogen chloride observed in the field blank samples (approximately 60 μg per sample) are well below the levels observed in the field samples (all greater than 1800 μg per sample). These negligible levels have no impact on the data. No data are qualified or invalidated based on blank results.DQA-21: Analysis of HCl and Cl 2 in Gas Revision Date: December 2012

Page 2 of 6 

## Holding Time

**S ample Date Analysis Date**  **Holding Time (Days)** 
VS2-STK-11B-M26A-ACDIMP 8-Oct 22-Oct 14
VS2-STK-11B-M26A-ALKIMP 8-Oct 21-Oct 13
VS2-STK-13B-M26A-ACDIMP 10-Oct 22-Oct 12
VS2-STK-13B-M26A-ALKIMP 10-Oct 21-Oct 11
VS2-STK-14B-M26A-ACDIMP 11-Oct 22-Oct 11
VS2-STK-14B-M26A-ALKIMP 11-Oct 21-Oct 10
VS2-STK-15B-M26A-ACDIMP 30-Oct 6-Nov 7
VS2-STK-15B-M26A-ALKIMP 30-Oct 7-Nov 8
VS3-STK-12B-M26A-ACDIMP 16-Oct 28-Oct 12
VS3-STK-12B-M26A-ALKIMP 16-Oct 27-Oct 11
VS3-STK-13B-M26A-ACDIMP 17-Oct 28-Oct 11
VS3-STK-13B-M26A-ALKIMP 17-Oct 27-Oct 10
VS3-STK-14B-M26A-ACDIMP 18-Oct 28-Oct 10
VS3-STK-14B-M26A-ALKIMP 18-Oct 27-Oct 9
VS4-STK-11B-M26A-ACDIMP 23-Oct 11-Nov 19
VS4-STK-11B-M26A-ALKIMP 23-Oct 7-Nov 15
VS4-STK-12B-M26A-ACDIMP 24-Oct 11-Nov 18
VS4-STK-12B-M26A-ALKIMP 24-Oct 7-Nov 14
VS4-STK-13B-M26A-ACDIMP 25-Oct 11-Nov 17
VS4-STK-13B-M26A-ALKIMP 25-Oct 7-Nov 13
VS2-STK-1FB-M26A-ACDIMP 8-Oct 22-Oct 14
VS2-STK-1FB-M26A-ALKIMP 8-Oct 21-Oct 13
VS2-STK-1FB2-M26A-ACDIMP 29-Oct 6-Nov 8
VS2-STK-1FB2-M26A-ALKIMP 29-Oct 7-Nov 9
VS3-STK-1FB-M26A-ACDIMP 15-Oct 28-Oct 13
VS3-STK-1FB-M26A-ALKIMP 15-Oct 27-Oct 12
VS4-STK-1FB-M26A-ACDIMP 22-Oct 11-Nov 20
VS4-STK-1FB-M26A-ALKIMP 22-Oct 7-Nov 16DQA-21: Analysis of HCl and Cl 2 in Gas Revision Date: December 2012

Page 3 of 6 

## Blank Results

**A nalytical Result** 

**(μg/sample) Hydrogen**  **Chloride Chlorine** 

VS2-STK-1FB-M26A-ACDIMP **60.4** -- VS2-STK-1FB-M26A-ALKIMP -- <42
VS2-STK-1FB2-M26A-ACDIMP **61.5** -- VS2-STK-1FB2-M26A-ALKIMP -- <42
VS3-STK-1FB-M26A-ACDIMP **58.9** -- VS3-STK-1FB-M26A-ALKIMP -- <42
VS4-STK-1FB-M26A-ACDIMP **65.8** -- VS4-STK-1FB-M26A-ALKIMP -- <42 Laboratory Blank; Batch 3295039 -- <42 Laboratory Blank; Batch 3295058 <43 -- Laboratory Blank; Batch 3301068 -- <42 Laboratory Blank; Batch 3302015 <43 -- Laboratory Blank; Batch 3312042 <43 -- Laboratory Blank; Batch 3312045 -- <42 Laboratory Blank; Batch 3316053 <43 --DQA-21: Analysis of HCl and Cl 2 in Gas Revision Date: December 2012

Page 4 of 6 

## Laboratory Check Sample (LCS) and **L aboratory Check Sample Duplicate (LCSD) Results** 

**H ydrogen**  **Chloride Chlorine** 

LCS/LCSD; Batch 3295039 LCS Recovery (%) -- 102

LCSD Recovery (%) -- 102 Relative Percent Difference (%) -- 0.13

LCS/LCSD; Batch 3295058 LCS Recovery (%) 105 --

LCSD Recovery (%) 104 -- Relative Percent Difference (%) 0.39 --

LCS/LCSD; Batch 3301068 LCS Recovery (%) -- 98

LCSD Recovery (%) -- 98 Relative Percent Difference (%) -- 0.32

LCS/LCSD; Batch 3302015 LCS Recovery (%) 98 --

LCSD Recovery (%) 98 -- Relative Percent Difference (%) 0.07 --

LCS/LCSD; Batch 3312042 LCS Recovery (%) 99 --

LCSD Recovery (%) 98 -- Relative Percent Difference (%) 0.87 --

LCS/LCSD; Batch 3312045 LCS Recovery (%) -- 100

LCSD Recovery (%) -- 100 Relative Percent Difference (%) -- 0.01

LCS/LCSD; Batch 3316053 LCS Recovery (%) 101 --

LCSD Recovery (%) 102 -- Relative Percent Difference (%) 0.92 --DQA-21: Analysis of HCl and Cl 2 in Gas Revision Date: December 2012

Page 5 of 6 

## Matrix Spike (MS) and Matrix Spike Duplicate (MSD) Results

**H ydrogen**  **Chloride Chlorine** 

VS2-STK-13B-M26A-ACDIMP Sample Result (μg/sample) 15,500 -- Spike Amount (μg/sample) 2,310 -- MS Result (μg/sample) 17,700 -- MSD Result (μg/sample) 17,500 -- MS Recovery (%) 94 -- MSD Recovery (%) 85 -- Relative Percent Difference (%) 1.2 --

VS2-STK-13B-M26A-ALKIMP Sample Result (μg/sample) -- <180 Spike Amount (μg/sample) -- 850 MS Result (μg/sample) -- 989 MSD Result (μg/sample) -- 915 MS Recovery (%) -- 116 MSD Recovery (%) -- 108 Relative Percent Difference (%) -- 7.8

VS2-STK-15B-M26A-ACDIMP Sample Result (μg/sample) 21,600 -- Spike Amount (μg/sample) 4,450 -- MS Result (μg/sample) 26,300 -- MSD Result (μg/sample) 26,100 -- MS Recovery (%) 105 -- MSD Recovery (%) 102 -- Relative Percent Difference (%) 0.48 --

VS2-STK-15B-M26A-ALKIMP Sample Result (μg/sample) -- <180 Spike Amount (μg/sample) -- 860 MS Result (μg/sample) -- 948 MSD Result (μg/sample) -- 954 MS Recovery (%) -- 110 MSD Recovery (%) -- 111 Relative Percent Difference (%) -- 0.61

VS3-STK-13B-M26A-ACDIMP Sample Result (μg/sample) 4,720 -- Spike Amount (μg/sample) 1,970 -- MS Result (μg/sample) 6,920 -- MSD Result (μg/sample) 6,970 -- MS Recovery (%) 111 -- MSD Recovery (%) 114 -- Relative Percent Difference (%) 0.82 --

VS3-STK-13B-M26A-ALKIMP Sample Result (μg/sample) -- <120 Spike Amount (μg/sample) -- 550 MS Result (μg/sample) -- 592 MSD Result (μg/sample) -- 642 MS Recovery (%) -- 108 MSD Recovery (%) -- 117 Relative Percent Difference (%) -- 8DQA-21: Analysis of HCl and Cl 2 in Gas Revision Date: December 2012

Page 6 of 6 

### Hydrogen **Chloride Chlorine** 

VS4-STK-12B-M26A-ACDIMP Sample Result (μg/sample) 8,150 -- Spike Amount (μg/sample) 1,890 -- MS Result (μg/sample) 10,100 -- MSD Result (μg/sample) 10,200 -- MS Recovery (%) 103 -- MSD Recovery (%) 106 -- Relative Percent Difference (%) 0.7 --

VS4-STK-12B-M26A-ALKIMP Sample Result (μg/sample) -- <120 Spike Amount (μg/sample) -- 580 MS Result (μg/sample) -- 611 MSD Result (μg/sample) -- 636 MS Recovery (%) -- 105 MSD Recovery (%) -- 110 Relative Percent Difference (%) -- 4
Laboratory Specification Recovery (%) 75-125 75-125 Relative Percent Difference (%) 20 20


## Duplicate Analysis

**A nalytical Result**  **(μg/sample) Relative**  **Percent Difference**  **(%) First Analysis**  **Duplicate**

**Analysis**
VS2-STK-11B-M26A-ACDIMP 36,600 36,300 0.8
VS2-STK-11B-M26A-ALKIMP <160 <160 NC 1

VS2-STK-13B-M26A-ACDIMP 15,500 15,400 0.6
VS2-STK-13B-M26A-ALKIMP <180 <180 NC
VS2-STK-14B-M26A-ACDIMP 15,900 16,200 1.9
VS2-STK-14B-M26A-ALKIMP <190 <190 NC
VS2-STK-15B-M26A-ACDIMP 21,600 21,400 0.9
VS2-STK-15B-M26A-ALKIMP <180 <180 NC
VS3-STK-12B-M26A-ACDIMP 4,740 4,790 1.0
VS3-STK-12B-M26A-ALKIMP <130 <130 NC
VS3-STK-13B-M26A-ACDIMP 4,720 4,900 3.7
VS3-STK-13B-M26A-ALKIMP <120 <120 NC
VS3-STK-14B-M26A-ACDIMP 1,810 1,820 0.6
VS3-STK-14B-M26A-ALKIMP <140 <140 NC
VS4-STK-11B-M26A-ACDIMP 11,100 11,000 0.9
VS4-STK-11B-M26A-ALKIMP <130 <130 NC
VS4-STK-12B-M26A-ACDIMP 8,150 8,050 1.2
VS4-STK-12B-M26A-ALKIMP <120 <120 NC
VS4-STK-13B-M26A-ACDIMP 23,600 23,700 0.4
VS4-STK-13B-M26A-ALKIMP <140 <140 NC

1 NC – Not Calculated. At least one result is below the detection limit.DQA-22: PM Weighing for Stack Gas Revision Date: December 2012

Page 1 of 2 

# Data Quality Assessment A nalysis of Stack Gas for Particulate Matter

Parameter Particulate Loading in Stack Gas 

### Sampling Method EPA Method 5 

### Analytical Method Gravimetric Analysis – EPA Method 5 

### Laboratory ID Number(s) H3J140413, H3J190410, H3K010423 

### Preparation Batch Number(s) 3293010, 3303016, 3312021


### Sample Shipping and Receipt Sample received intact and at ambient temperature. QAPP has no specification for preservation of these samples.



### Holding Time(s) All samples prepared and analyzed within 20 days of sampling.

QAPP specifies analysis within 28 days. See table below.



### Blank Results Field blank PNR sample had observable levels near the detection limit. No

particulate matter detected in media check samples. Field Blank below actual results. See tables below and in main body of report. 

### Results of Multiple Weighings Final weighing stable within < 0.5 mg



### Balance Calibration Performed daily during applicable periods



### Conclusions and Comments These data are acceptable for the intended purpose. The levels of particulate material observed in the PNR samples were very low, and near the detection limit. Levels in the field samples were similar to these results, and may have a positive bias. As a positive bias is conservative relative to the estimation of emissions, no data are qualified or invalidated based on field blank results.DQA-22: PM Weighing for Stack Gas Revision Date: December 2012

Page 2 of 2 

## Holding Time

S ample Date Analysis Date Holding Time (Days)

VS2-STK-11A-M5-FILT 8-Oct 23-Oct 15
VS2-STK-11A-M5-PNR 8-Oct 23-Oct 15
VS2-STK-12A-M5-FILT 9-Oct 23-Oct 14
VS2-STK-12A-M5-PNR 9-Oct 23-Oct 14
VS2-STK-13A-M5-FILT 10-Oct 23-Oct 13
VS2-STK-13A-M5-PNR 10-Oct 23-Oct 13
VS3-STK-11A-M5-FILT 15-Oct 31-Oct 16
VS3-STK-11A-M5-PNR 15-Oct 31-Oct 16
VS3-STK-12A-M5-FILT 16-Oct 31-Oct 15
VS3-STK-12A-M5-PNR 16-Oct 31-Oct 15
VS3-STK-13A-M5-FILT 17-Oct 31-Oct 14
VS3-STK-13A-M5-PNR 17-Oct 31-Oct 14
VS4-STK-11A-M5-FILT 23-Oct 11-Nov 19
VS4-STK-11A-M5-PNR 23-Oct 11-Nov 19
VS4-STK-13A-M5-FILT 25-Oct 11-Nov 17
VS4-STK-13A-M5-PNR 25-Oct 11-Nov 17
VS4-STK-14A-M5-FILT 25-Oct 11-Nov 17
VS4-STK-14A-M5-PNR 25-Oct 11-Nov 17
VS2-STK-1FB-M5-FILT 7-Oct 23-Oct 16
VS2-STK-1FB-M5-PNR 7-Oct 23-Oct 16
VS3-STK-1FB-M5-FILT 14-Oct 31-Oct 17
VS3-STK-1FB-M5-PNR 14-Oct 31-Oct 17
VS4-STK-1FB-M5-FILT 22-Oct 11-Nov 20
VS4-STK-1FB-M5-PNR 22-Oct 11-Nov 20



## Blank Results

Particulates (total) (mg/sample)
VS2

- STK

- 1FB

- M5

- FILT <0.5 VS2

- STK

- 1FB

- M5

- PNR 1.2 VS3

- STK

- 1FB

- M5

- FILT <0.5 VS3

- STK

- 1FB

- M5

- PNR 1.4 VS4

- STK

- 1FB

- M5

- FILT <0.5 VS4

- STK

- 1FB

- M5

- PNR 1.25 A

- 5076 MEDIA CHECK <0.5 A

- 5058 MEDIA CHECK <0.5 A

- 5039 MEDIA CHECK <0.5 Range of Field Samples PNR <0.5

- 1.35

Filter 0.55

– 2.5