### PROPOSED AMENDMENTS TO THE HEXAVALENT CHROMIUM

AIRBORNE TOXIC CONTROL MEASURE FOR CHROME PLATING AND

CHROMIC ACID ANODIZING OPERATIONS

Stationary Source Division Air Quality Measures Branch

Release Date: August 11, 2006

To Be Considered by the Board: September 28, 2006

### State of California

AIR RESOURCES BOARD



## STAFF REPORT: INITIAL STATEMENT OF REASONS

FOR PROPOSED RULEMAKING

Public Hearing to Consider

ADOPTION OF THE PROPOSED AMENDMENTS TO THE HEXAVALENT

CHROMIUM AIRBORNE TOXIC CONTROL MEASURE FOR CHROME

PLATING AND CHROMIC ACID ANODIZING OPERATIONS

To be considered by the Air Resources Board on September 28, 2006, at:

California Environmental Protection Agency

Headquarters Building

1001 “I” Street Sacramento, California

Stationary Source Division:

Robert Fletcher, P.E., Chief Robert D. Barham, Ph.D., Assistant Division Chief Janette Brooks, Chief, Air Quality Measures Branch Carla D. Takemoto, Manager, Technical Evaluation Section

This report has been prepared by the staff of the Air Resources Board. Publication does not signify that the contents reflect the views and policies of the Air Resources Board, nor does mention of trade names or commercial products constitute endorsement or recommendation for

use.

## Acknowledgements

Contributing Authors

Shobna Sahni, M.P.H. (Lead)

Carla Takemoto
Reza Mahdavi, Ph.D. Tony Servin, P.E.

Robert Barrera

Legal Counsel

Robert Jenne, Esq., Office of Legal Affairs

_______________________________________________________________________

We are particularly grateful to Mr. Jose Mauro Saldana for his untiring assistance in the preparation of this report.

We also wish to acknowledge the participation and assistance of:

Metal Finishing Association of Southern California Surface Technology Association

We would also like to acknowledge the participation and assistance of air pollution control and air quality management districts. In particular, we would like to thank the individuals at the following districts that participated in the ARB/District Working Group:

Richard Wales, Antelope Valley Air Quality Management District Randy Frazier, Bay Area Air Quality Management District Karla Sanders, Feather River Air Quality Management District

Jose De Guzman and Mark Loutzenhiser, Sacramento Metropolitan Air Quality Management District Archie de la Cruz, Cara Bandera, Dave Byrnes, San Diego County Air Pollution Control District Chay Thao, Martin Keast, John Copp, San Joaquin Valley Air Pollution Control District Shasta County Air Quality Management District Robert Gottschalk, Andrew Lee, Jay Chen, Susan Nakamura, Marco Polo, Thomas Liebel, Joan Niertit, Jill Whynot, Mike Garibay, David Jones, and Sam Vergara, South Coast Air Quality Management District Terri Thomas, Ventura County Air Pollution Control DistrictFor the emissions testing program we want to acknowledge the invaluable

assistance of: Mr. Dominic Nole, Mr. Dan Cunningham, Mr. Dean High, Mr. Paramo Hernandez, Mr. Ray Lucas, Mr. Chad Medico, Mr. John Martin, and Mr. Ralph Hersher

We also acknowledge the assistance of the tested facilities: Sigma Plating, Excello Plating, Van Nuys Plating, Alta Plating, Sherm’s Custom Chrome, Clovis Specialty Plating, Walker Custom Chrome

Numerous ARB staff helped in the emissions testing program and in development of this report. In particular we acknowledge: Alex Barber; Ron Barros; Nicholas Berger; Darryl Burns; Chris Clark; Monique Davis; Steve Eve; Cynthia Garcia; Marline Hicks; Chris Nguyen; Olufemi Olaluwoye; Johnnie Raymond; Don Ridgley; Betsy Ronsse; Peter Samra; Dale Shimp; David Todd, Source Testing Lead; Roxana Walker; Evan Wong; Glen Villa; Zuzana Vonai 

## Table of Contents

Executive Summary ES-1

I . Introduction ................................................................................................................1

A. Overview ....................................................................................................................1

B. Goals of the Proposed Amendments .........................................................................2

C. Regulatory Authority...................................................................................................3

D. Existing State Control Measure..................................................................................5

E. Federal Regulations ...................................................................................................6

F. Current Air District Rules............................................................................................7

G. Barrio Logan, A Case Study of Near Source Impacts ................................................9

H. Hexavalent Chromium Emissions Study and Conclusions.......................................10

II. Need for Further Regulation.....................................................................................13

A. Characteristics, Sources, and Ambient Concentrations of Hexavalent

Chromium and Chromium Compounds....................................................................14

B. Health Impacts .........................................................................................................18

C. Barrio Logan: A Case Study of Near Source Impacts .............................................19

D. Proximity of Facilities to Sensitive Receptors...........................................................20

III. Public Outreach and Data Collection .......................................................................24

A. Public Involvement ...................................................................................................24

B. Data Collection Tools ...............................................................................................25

IV. Chromium Plating and Chromic Acid Anodizing Operations ....................................28

A. Overview ..................................................................................................................28

B. Types of Chromium Operations ...............................................................................29

C. Data Resources .......................................................................................................30

D. Industry Characterization .........................................................................................31ii

V. Emissions.................................................................................................................39

A. Overview ..................................................................................................................39

B. Emission Factor Background ...................................................................................39

C. Emissions Testing Program .....................................................................................40

D. Statewide Hexavalent Chromium Emissions............................................................47

E. Fugitive Emissions ...................................................................................................49

VI. Reducing Hexavalent Chromium Emissions ............................................................52

A. In-tank Controls........................................................................................................52

B. Add-on Air Pollution Control Devices .......................................................................58

C. Alternative Processes...............................................................................................59

VII. Health Risk Assessment ..........................................................................................66

A. Overview ..................................................................................................................66

B. Health Risk Assessment Process ............................................................................66

C. Factors that Affect Health Risk Assessments...........................................................73

D. Cancer Risk Assessment .........................................................................................74

E. Non-Cancer Risk Assessment .................................................................................75

VIII. Proposed Risk Reduction Approach and Benefits....................................................78

A. Best Available Control Technology ..........................................................................78

B. Emissions and Cancer Risk Reduction Benefits ......................................................80

C. Other Aspects of the Staff’s Proposal ......................................................................82

IX. Proposed Amendments and Alternatives .................................................................84

A. Summary of the Existing Airborne Toxic Control Measure.......................................84

B. Summary of the Proposed Amendments..................................................................84

C. Basis for the Proposed Amendments.......................................................................97

D. Alternatives to the Proposed Amendments ..............................................................97

E. Recommendation ...................................................................................................101iii

X. Economic Impacts..................................................................................................103

A. Summary of the Economic Impacts........................................................................103

B. Economic Impact Analysis .....................................................................................104

XI. Environmental Impacts...........................................................................................118

A. Legal Requirements ...............................................................................................118

B. Analysis of Reasonably Foreseeable Environmental Impacts................................119

C. Reasonably Foreseeable Mitigation Measures ......................................................122

D. Reasonably Foreseeable Alternative Means of Compliance..................................123

E. Community Health and Environmental Justice.......................................................123iv 

## List of Tables

Table ES-1. Sixty-three Facilities have Estimated Cancer Risk of Over

10 per Million Exposed People (2005 Baseline) ..............................................8

Table ES-2. Proposed Hexavalent Chromium Emission Limits for Existing

Facilities ........................................................................................................11

Table ES-3. Adoption of Staff’s Proposal Significantly Reduces the Estimated

Cancer Risk from Hexavalent Chromium Emissions .....................................13

Table ES-4. Adoption of Staff’s Proposal Offers the Greatest Reduction in Significant Community Cancer Risk ..............................................................18

Table I-1. Air Districts with Active Chromium Plating and/or Anodizing

Facilities and Corresponding Prohibitive Rule .................................................8

Table II-1. Hexavalent Chromium Mean Concentration in Air Districts with

Chromium Plating and Anodizing Facilities for the Year 2005.......................16

Table IV-1. Description of Hexavalent Chromium Operations..........................................30

Table IV-2. Number of Operations by Plating Type..........................................................32

Table IV-3. Hexavalent Chromium Plating Type and Ampere-hours (2003) ....................33

Table IV-4. Number of Employees at Chromium Plating and Chromic Acid Anodizing Facilities........................................................................................37

Table V-1. Decorative Chromium Plating Emission Factors in Existence Prior to ARB

Testing Program (milligrams/ampere-hour) ...................................................40

Table V-2. Average Hexavalent Chromium Emission Rates and Selected Testing

Parameters for Phase 1.................................................................................41

Table V-3. Average Hexavalent Chromium Emission Rates and Selected Testing Parameters for Phase II....................................................................44

Table V-4. Chemical Fume Suppressants Approved for Use at Specified

Surface Tensions...........................................................................................45

Table V-5. Plating Bath Contaminants, Concentration Levels Where Bath

Clean-up is Recommended, and Hexavalent Chromium Emission

Rates.............................................................................................................47

Table V-6. Summary of Indoor Air Results During Emissions Testing Program..............50v

Table VI-1. Types of Chemical Fume Suppressants Used in California in 2003..............56

Table VI-2. Summary of Chemical Fume Suppressant Mechanism of Control

and Recommended Surface Tension ............................................................57

Table VI-3. Cost Estimate for Conversion to Trivalent Chromium....................................61

Table VII-1. Inhalation Cancer Potency Factors for Common Carcinogens......................67

Table VII-2. Hexavalent Chromium Health Effects Values Used in Non-Cancer

Health Risk Assessment................................................................................68

Table VII-3. Key Parameters for Air Dispersion Modeling and Health Risk

Assessment...................................................................................................70

Table VII-4. Generic Facility Parameters for Air Dispersion Modeling and

Health Risk Assessment................................................................................71

Table VII-5. Key Parameters for Assessing Estimated Cancer and Non-Cancer

Health Impacts for Chromium Plating and Chromic Acid Anodizing Facilities........................................................................................73

Table VII-6. Sixty-three Facilities have Estimated Cancer Risk of Over 10 per Million Exposed People (2005 Baseline) ............................................75

Table VIII-1. Adoption of Staff’s Proposal Significantly Reduces the Estimated

Cancer Risk from Hexavalent Chromium Emissions .....................................81

Table VIII-2. Adoption of Staff’s Proposal Significantly Reduces the Estimated

Cancer Risk from Hexavalent Chromium Emissions for Off-Site Workers.....81

Table IX-1. Definitions Proposed for Modification ............................................................86

Table IX-2. New Definitions Proposed for Addition ..........................................................86

Table IX-3. Proposed Hexavalent Chromium Emission Limits for Existing Facilities .......89

Table IX-4. Chemical Fume Suppressants Approved for Use at Specified Surface

Tensions........................................................................................................94

Table IX-5. Adoption of Staff’s Proposal Offers the Greatest Reduction in Significant

Community Cancer Risk..............................................................................100

Table X-1. Estimated Compliance Costs (Other than Those for Add-On Air

Pollution Control Devices) ...........................................................................106

Table X-2. Costs for HEPA Add-on Air Pollution Control Devices.................................107

Table X-3. Number of Affected Hexavalent Chromium Plating and Chromic Acid

Anodizing Facilities by Air District................................................................114vi

Table XI-1. Distribution of Chromium Plating and Chromic Acid Anodizing

Facilities in the Los Angeles and Orange County Areas..............................124vii 

## List of Figures

Figure ES-1. Location and Type of Operation Performed at Chromium Plating

and Chromic Acid Anodizing Facilities in California (2003) .............................5

Figure ES-2. Throughput (in Ampere-hours) for Chromium Plating and Chromic Acid

Anodizing Facilities in California (2003)...........................................................6

Figure ES-3. Baseline Hexavalent Chromium Emissions are About Four Pounds (2005).........................................................................................7

Figure ES-4. Forty-three Percent of Facilities are Located Near Sensitive Receptors .........9

Figure IV-1. Main Components of an Electroplating Tank.................................................29

Figure IV-2. Distribution of Chromium Operations by District (2003).................................31

Figure IV-3. Distribution of Hexavalent Chromium Operations by Type (2003).................32

Figure IV-4. Throughput (in Ampere-hours) for Chromium Plating and Chromic Acid

Anodizing Facilities in California (2003).........................................................33

Figure IV-5. Distribution of Emission Controls by Type of Chromium Operation...............34

Figure IV-6. Distance (in Meters) Between Hexavalent Chromium Facilities and the

Nearest Sensitive Receptor...........................................................................36

Figure IV-7. Gross Annual Revenue for Hexavalent Chromium Plating and Anodizing

Facilities (2003) .............................................................................................37

Figure V-1. Temporary ‘Hood’ for Capturing Hexavalent Chromium Emissions at

Decorative Chromium Plating Facilities.........................................................43

Figure V-2. Statewide Hexavalent Chromium Emissions in 2003 Were 14.4 Pounds......48

Figure VII-1. Percent Concentration of Hexavalent Chromium at Increasing

Distances from the Source ............................................................................72

Figure VIII-1. Comparison of Cancer Risks (MICR) Remaining After Application

of Controls at Various Throughputs...............................................................79viii 

### List of Appendices

Appendix A: Proposed Regulation Order for the Proposed Amendments

to the Chromium Plating ATCM

Appendix B: Chronology of Meetings

Appendix C: Industry Survey Form

Appendix D: Supplier Survey Form

Appendix E: Economic Survey Forms

Appendix F: Results of Emission Testing Program

Appendix G: Results of SDCAPCD Dust Samples Collected from Hexavalent

Chromium Plating Facilities

Appendix H: Air Quality Modeling Parameters and Results

Appendix I: Analysis of Proximity of Chromium Plating and Chromic Acid

Anodizing Facilities in a Southern California CommunityES-1



## Executive Summary

T he Air Resources Board (ARB) staff is proposing amendments to the Hexavalent Chromium Airborne Toxic Control Measure for Chrome Plating and Chromic Acid Anodizing Operations (Chromium Plating ATCM or ATCM). The amendments are proposed as a result of our evaluation of the 226 chromium plating and chromic acid anodizing facilities in California.

In 1986, the Board identified hexavalent chromium as a toxic air contaminant (TAC). Hexavalent chromium was determined to be an extremely potent human carcinogen with no known safe level of exposure. Only dioxin is a more potent carcinogen than hexavalent chromium. Exposure over a lifetime to very low hexavalent chromium concentrations can substantially increase a person’s chance of developing cancer.

Due to its potential cancer risk, ARB has adopted a number of control measures for hexavalent chromium sources, including chromium plating and chromic acid anodizing facilities. The current ATCM reduced emissions of hexavalent chromium by over 90 percent, and in some cases by over 99 percent. Other air district programs have also reduced emissions of hexavalent chromium. As a result, ambient levels of hexavalent chromium are low and have been reduced by about 60 percent since the early 1990s.

Based on community concerns and the potency of hexavalent chromium, the staff has re-evaluated the current Chromium Plating ATCM. We found that people living near many of these facilities are exposed to unacceptable concentrations of hexavalent chromium. Our evaluation showed that 43 percent of chromium plating and chromic acid anodizing operations are located within 100 meters of sensitive receptors and about 30 percent of the facilities have emissions sufficient to produce a potential cancer risk of greater than ten per million exposed people. The data also show that the chromium plating facilities are often located in low income and ethnically diverse communities.

In the evaluation, we also found that reliable add-on air pollution control devices, such as high efficiency particulate arrestor (HEPA) filters, are available. These controls now represent best available control technology (BACT) for intermediate and large sized facilities that can result in higher community risks. BACT for smaller facilities, those with emissions that can relatively easily be controlled to the levels needed to keep community risk low (under one per million), is use of specific chemical fume suppressants. In our proposal, all 226 facilities would be affected; 89 of those facilities would need to meet an emission limit equivalent to that achieved by HEPA filters and another 48 facilities would have to use specific chemical fume suppressants. The other facilities are in substantial compliance. The requirements would be phased-in over time, with facilities close to receptors having to install BACT in two years, versus five years for other facilities.

By requiring BACT for all facilities, remaining cancer risks would be reduced by up to 85 percent in communities close to facilities. We also estimate that adoption of the staff’s proposal will reduce the estimated cancer risk for about 75 percent of facilities to no more than one per million exposed persons, with 92 percent of facilities having estimated cancer risks of less than ten per million exposed persons. The proposal would alsoES-2

isolate new chromium plating or chromic acid anodizing facilities from people and require housekeeping measures to address fugitive emissions.

Staff has determined that costs for some individual businesses are expected to be significant and may adversely impact their profitability. Some smaller volume plating or anodizing businesses may decide to cease chromium plating or anodizing operations rather than make the investments needed to comply. This analysis assumes that affected facilities would install HEPA filters, although there may be less costly equivalent options available, and the facilities cannot recover their costs through increased prices.

This Executive Summary provides an overview of the staff’s proposal, including the basis and rationale, key provisions, and the environmental and economic impacts. The staff report, entitled “Proposed Amendments to the Hexavalent Chromium Airborne Toxic Control Measure For Chrome Plating and Chromic Acid Anodizing Operations,” presents detailed information related to the staff’s proposal, as well as the proposed regulation

order.



### A. Background

1. What is chromium plating and chromic acid anodizing?

Hexavalent chromium plating, or simply chromium plating, is the electrical application of a coating of chromium onto a surface for decoration, corrosion protection, or for durability. An electrical charge is applied to a tank (bath) containing an electrolytic salt (chromium anhydride) solution. The electrical charge causes the chromium metal particles in the bath to fall out of solution and deposit onto objects placed in the plating solution. The most familiar type of chromium plating is the decorative chromium plating process which provides a bright, shiny finish onto objects such as wheels and plumbing fixtures. During chromic acid anodizing, an oxidation layer is generated on the surface of the part. These electrolytic processes cause mists containing hexavalent chromium to be ejected from the plating tank which are eventually emitted into outdoor air.

2. What is hexavalent chromium?

Hexavalent chromium is the cation of a metal salt and does not occur naturally. Generally, hexavalent chromium ions are produced under strong oxidizing conditions from metallic chromium, with the most common ions being chromate ion (CrO 4 -2 ) or dichromate ion (Cr 2 O 7 -2 ). Unlike many pollutants which are gases, hexavalent chromium is a particle.

3. How is hexavalent chromium emitted from the plating/anodizing process?

In the chromium plating process, only about 20 percent of the electrical current applied actually deposits chromium onto the part. The remaining current forms bubbles, hydrogen gas at the cathode and oxygen at the anode, that rise to the surface of the bath. As these bubbles burst, hexavalent chromium is emitted into the air.ES-3

4. Why are we concerned about emissions of hexavalent chromium?

Hexavalent chromium is a known human carcinogen. Prolonged exposure causes lung

cancer. The Board identified hexavalent chromium as a TAC in 1986. A cancer unit risk factor of 0.15 ( μ g/m 3 ) -1 was developed in support of the TAC identification by the Office of Environmental Health Hazard Assessment (OEHHA) and approved by the Scientific Review Panel on TACs. This value means that a person’s chance of developing cancer due to exposure to 1 μg/m 3 of hexavalent chromium over a 70 year lifetime would be 146,000 chances per million people, almost 15 percent. Only one other identified TAC, dioxin, has been determined more likely to cause cancer than hexavalent chromium. When the Board designated hexavalent chromium as a TAC, they further determined that there was no known level of exposure that would be considered safe.

5. What does State law require ARB to do to reduce the public’s exposure to

toxic air contaminants?

Health and Safety Code section 39666 requires ARB to adopt control measures to reduce emissions of TACs. When adopting or amending ATCMs for TACs, if no safe threshold exposure level is identified, the ATCM is to reduce emissions to the lowest level achievable through the application of BACT or a more effective control method, in

consideration of health risk and cost.

6. What does the current ATCM require?

Originally adopted in 1988 and amended in 1998, the Chromium Plating ATCM set forth the requirements for reducing hexavalent chromium emissions based on the type of operation. Most hard chromium plating facilities were required to reduce hexavalent chromium emissions by 99 percent or more. This was achieved through installation of add-on air pollution control devices. Decorative chromium plating and chromic acid anodizing facilities were required to reduce uncontrolled emissions by at least 95 percent. However, they were not required to use add-on air pollution control devices. A brief summary of the requirements follows:

• Hard chromium plating facilities are required to install add-on air pollution control devices to meet emission limits ranging from 0.15 milligrams/ampere-hour to 0.006 milligrams/ampere-hour, depending on levels of throughput. An alternative surface tension limit was provided for hard chromium plating facilities with throughput levels of 500,000 ampere-hours or less; and

• Decorative plating and chromic acid anodizing facilities must comply with either an emission limit using add-on air pollution control devices or meet a surface tension limit. Most facilities comply by using chemical fume suppressants to meet the

surface tension limit.

The ATCM was amended in 1998 to establish equivalency with the National Emission Standards for Chromium Emissions from Hard and Decorative Chromium Electroplating and Chromium Anodizing Tanks (Chromium Plating NESHAP) (U.S. EPA, 1995).ES-4

Therefore, chromium plating and chromic acid anodizing facilities are only subject to California’s Chromium Plating ATCM.

7. Why did ARB staff decide to evaluate the existing ATCM?

Due to the carcinogenicity of hexavalent chromium, and in response to community concerns, ARB staff undertook an evaluation of the Chromium Plating ATCM. The staff evaluated if people located near chromium plating or chromic acid anodizing facilities were adequately protected from emissions of hexavalent chromium. Staff also evaluated if technologies were available to reduce hexavalent chromium emissions, if necessary. As part of the evaluation, staff determined that 43 percent of the operations are located within 100 meters of a sensitive receptor, such as a residence or school. By conducting an emissions testing program and air quality modeling, staff determined that these sensitive receptors may be exposed to unacceptable hexavalent chromium concentrations. ARB staff also found that reliable add-on air pollution control devices such as HEPA filters are now available and are used by many facilities to reduce

hexavalent chromium emissions.

Concurrent with the review of the Chromium Plating ATCM, unexpectedly high concentrations of hexavalent chromium were measured during an air monitoring study conducted near chromium plating facilities in San Diego. Through further air monitoring, the source of the high concentrations was determined to be the decorative chromium plating facility.

8. Have other regulatory actions affected the chromium plating and chromic acid anodizing industry?

Yes. In 2003, the South Coast Air Quality Management District (SCAQMD) adopted amendments to Rule 1469, entitled Hexavalent Chromium Emissions from Chromium Plating and Chromic Acid Anodizing Operations (SCAQMD, 2003). The amended rule requires hexavalent chromium facilities located within 25 meters of a sensitive receptor or

within 100 meters of a school to reduce hexavalent chromium emissions so that the residential cancer risk will be no more than ten chances per million people. The rule also requires facilities located greater than 25 meters from a sensitive receptor or greater than

100 meters from a school to reduce emissions such that off-site worker cancer risk would be no more than 25 chances per million people. The amended rule is in full effect. To help meet the requirements, SCAQMD staff conducted a chemical fume suppressant certification program which established a list of products that could be used to meet an emission rate of 0.01 milligrams/ampere-hour.

As mentioned previously, a federal control measure is also in place to control emissions of chromium compounds from chromium plating and chromic acid anodizing facilities (U.S. EPA, 1995). The ARB has achieved equivalency with the Chromium Plating

NESHAP.

The United States Department of Labor Occupational Safety and Health Administration (OSHA) established a Permissible Exposure Limit (PEL) to protect workers fromES-5

hexavalent chromium exposures. OSHA’s time-weighted average PEL is 5 μg/m 3

, measured and reported as Chromium VI and an action level of 2.5 μg/m 3 for the general industry.



### B. The Chromium Plating and Chromic Acid Anodizing Industry in

California

9. What are the results of the industry survey?

ARB staff conducted a survey of chromium plating and chromic acid anodizing facilities for calendar year 2003. Staff collected information on types of operations performed, emission rates, throughput in terms of annual ampere-hours, methods for controlling hexavalent chromium emissions, and economic information. Staff also conducted an emissions testing program to better characterize emissions of hexavalent chromium from decorative chromium plating operations.

Results of our survey showed that there were 228 active facilities, and 12 of these conduct more than one electroplating process. These 228 facilities perform 240 chromium related operations. This means, for example, that some facilities conduct both decorative and hard chromium plating. Ten operations use the trivalent chromium plating process to conduct decorative chromium plating. Of these ten operations, six facilities conduct only trivalent chromium plating. Four trivalent chromium operations are part of a facility that also conducts hexavalent chromium plating. The other 230 operations use the hexavalent chromium process. Of these operations 58 are hard chromium plating, 127 are decorative chromium plating, and 45 are chromic acid anodizing operations. Our survey findings are shown graphically in Figure ES-1 below.

Figure ES-1 . Location and Type of Operation Performed at Chromium Plating and

Chromic Acid Anodizing Facilities in California (2003)

As shown in Chart A of Figure ES-1, ARB staff found that about 75 percent of facilities are located in the SCAQMD. Chart B shows that over half of California’s industry are decorative chromium plating facilities.

Figure ES-2 shows the distribution of the 222 hexavalent chromium plating and chromic acid anodizing facilities based on throughput. The six facilities conducting only trivalent chromium plating are not represented. Throughput is presented in ampere-hours. An Chart A: Facility Location

BAAQMD

9%

SCAQMD

75% SJVAPCD

7% OTHER

9% Chart B: Type of Operation

Anodizing

20%

Hard

25% Decorative

55%ES-6

ampere-hour is a unit of amperes integrated over time. It is an important variable

because it is used to determine the amount of hexavalent chromium emissions from a facility. The ampere-hours are multiplied by an emission rate to calculate emissions.

Figure ES-2 . Throughput (in Ampere-hours) for Chromium Plating and Chromic Acid Anodizing Facilities in California (2003)

48 60

45

34

15 18

0 10 20 30 40 50 60 70Number of Facilities

< 2 0 , 00 0

20 , 000 - 200 , 0 0 0

2 00 , 0 00 - 1 M i l l i on

1 - 5 M i l l i on

5 - 15 M i l l i on

> 15 M i l l i on

As shown in Figure ES-2, about 48 (about 20 percent) of facilities have annual throughput of 20,000 annual ampere-hours or less. Sixty facilities (27 percent) have throughput of between 20,000 to 200,000 annual ampere-hours. Over 50 percent of facilities have annual ampere-hours over 200,000.

10. What are the results from the decorative chromium plating emissions testing program?

The goal of the emissions testing program was to establish an emission rate for chromium plating and chromic acid anodizing tanks controlling hexavalent chromium emissions with chemical fume suppressants. Staff conducted six tests to estimate emissions based on normal facility operations. Averaging the emission rates from these six tests results in a hexavalent chromium emission factor of 0.04 milligrams/ampere-hour. These data are representative of ‘real world’ conditions.

Concurrent with our testing program, the SCAQMD tested the ability of chemical fume suppressants to reduce emissions under carefully controlled conditions. The purpose of this testing was to determine parameters that yielded optimum emission reductions. The
SCAQMD demonstrated that hexavalent emissions can be further reduced if certain chemical fume suppressants are used. In fact, the SCAQMD demonstrated that several chemical fume suppressants could reduce emissions of hexavalent chromium to no more than 0.01 milligrams/ampere-hour. The surface tension at which this emission rate is achieved is at lower surface tension than currently required by the ATCM.ES-7

A seventh test was done to verify the SCAQMD results. The seventh test was conducted using the chemical fume suppressant Fumetrol 140®. The SCAQMD certified this chemical fume suppressant to reduce hexavalent chromium emissions to no more than 0.01 milligrams/ampere-hour when surface tension is maintained below 40 dynes/centimeter. In test seven, ARB was able to duplicate this emission rate. Based on this test result, as well as an evaluation of the SCAQMD source test data from their chemical fume suppressant certification program, ARB staff determined which chemical fume suppressants could be used as the sole control by some facilities to comply with the ATCM. These chemical fume suppressants have been shown to reduce hexavalent chromium emissions to no more than 0.01 milligrams/ampere-hour at specified surface

tensions.

11. What are the emissions of hexavalent chromium from chromium plating and chromic acid anodizing facilities?

Staff developed the emission inventory for chromium plating and chromic acid anodizing facilities by using data from the survey. As explained previously, emissions of hexavalentchromium are determined based on throughput and are quantified in milligrams/amperehour. To develop the emission inventory, staff developed two emission factors for hexavalent chromium plating facilities controlling emissions by using chemical fume suppressants. We estimated emissions for these facilities by using the emission rate of 0.04 milligrams/ampere-hour for facilities outside SCAQMD. We used the emission factor of 0.01 milligrams/ampere-hour for SCAQMD facilities. The SCAQMD facilities are required to use chemical fume suppressants that meet this emission rate. Emissions from facilities with add-on air pollution control devices are based on source test results or regulatory requirements.

Figure ES-3 . Baseline Hexavalent Chromium Emissions are About Four Pounds (2005)

As shown in Figure ES-3, staff estimates that emissions of hexavalent chromium from chromium plating and chromic acid anodizing facilities in 2005 totaled 4.0 pounds, or about 1,800 grams. Facilities without add-on air pollution controls (in tank controls only): 1.6 pounds per year Facilities with add-on air pollution control devices: 2.4 pounds per yearES-8

12. Why is staff concerned about 4.0 pounds per year of emissions?

While the 4.0 pounds (1,800 grams) per year of emissions seems low, even a very small amount of hexavalent chromium can result in a substantial cancer risk. For example, staff found that as little as two grams of annual emissions would yield an estimated cancer risk of ten per million people exposed. As shown in Table ES-1, the maximum individual cancer risk (MICR) was determined for each chromium plating and chromic acid anodizing facility in California based on these 4.0 pounds of emissions. It should be noted that the MICR is calculated using the highest concentration of hexavalent chromium downwind of a facility that is predicted by an air quality model. People may not be living at the MICR point. Table ES-1 reflects implementation of the current ATCM and air district rules, including Rule 1469 for facilities in the South Coast Air Basin.

Table ES-1 . Sixty-three Facilities have Estimated Cancer Risk of Over 10 per Million

Exposed People (2005 Baseline)



### Number of Facilities by Cancer Risk

< 1 per million >1 < 10

per million >10 < 100

per million >100

per million

Baseline 2005 90 67 57 6

As shown in Table ES-1, 90 facilities (about 41 perc ent) have estimated cancer risk less than one per million exposed people. However, Table ES-1 also shows that 57 facilities (about 26 percent) have an estimated cancer risk of over ten per million exposed people. Six facilities (about 3 percent) may have an estimated cancer risk of over 100 per million people exposed.

Based on these results, staff determined that further risk reduction measures are necessary. While Rule 1469 reduced the estimated cancer risk for facilities in the SCAQMD, the rule had no impact on facilities in the rest of the state. We have also

determined that Rule 1469 did not achieve the maximum reduction feasible because BACT was not required for all facilities.

13. Are sensitive receptors located within 100 meters of a chromium plating and chromic acid anodizing facility?

Yes. Near source exposures to chromium plating and chromic acid anodizing facilities are our primary health concern. ARB staff and the air districts worked together to determine the location of chromium plating and chromic acid anodizing facilities, and to determine the distance to the nearest residence, school, hospital, day care center, or similar sensitive receptor location. Figure ES-4 shows the proximity of facilities to sensitive receptors.ES-9

Figure ES-4 . Forty-three Percent of Facilities are Located Near Sensitive Receptors

43

26 27 126

0 20 40 60 80 100 120 140Number of Facilities

<25 >25 <50 >50 <100 >100

Distance to Receptor (meters)

Figure ES-4 shows that 96 chromium plating and chromic acid anodizing facilities are located within 100 meters of a sensitive receptor. This represents 43 percent of the facilities. Forty-three facilities are located within 25 meters of a sensitive receptor.



### C. Staff’s Proposal to Amend the Chromium Plating ATCM

14. How did staff determine the most effective approach to control?

Staff evaluated available add-on air pollution control technologies and alternative processes for hexavalent chromium plating and chromic acid anodizing to determine if

cancer risk could be reduced or eliminated. While alternatives exist for some applications, their use is limited. Thus, we concluded that alternative technologies are not available that enable a phase-out of the hexavalent chromium process at this time. However, our analysis also shows that effective add-on air pollution control devices are readily available. These devices minimize the cancer risk to the extent technology allows.

Staff also conducted modeling analyses to determine how hexavalent chromium is dispersed from chromium plating and chromic acid anodizing facilities. The concentration of hexavalent chromium is highest near the facility, but the impacts of the emissions appear to be localized. We found that at 100 meters from the source hexavalent chromium concentrations are reduced by up to 90 percent.

To develop the proposal, staff conducted the health risk assessment in a manner which is very health protective in estimating cancer risks for a range of reasonably foreseeable exposure scenarios. Staff believes this health protective approach is necessary due to the very high potency and resultant serious health hazards associated with hexavalent chromium emissions. The goal of this proposal is to reduce cancer risk to as low as technology allows. Use of BACT will meet this goal.ES-10

15. What is best available control for (BACT) chromium plating and chromic acid anodizing facilities?

Staff has evaluated various types of add-on air pollution control devices. We also have evaluated the effectiveness of chemical fume suppressants through our emissions testing program. We have determined that BACT for very small facilities is use of specific types of chemical fume suppressants. BACT for intermediate and larger sized facilities is use of add-on air pollution control devices with the final capture device being HEPA filters. Use

of HEPA filters will reduce hexavalent chromium emissions to no more than 0.0015 milligrams/ampere-hour. HEPA filters reduce emissions by over 99.9 percent. Any other combination of control devices that can meet this emission rate would be considered equivalent to BACT. These technologies are already employed by many chromium plating and chromic acid anodizing facilities. These control technologies are

described below.

a. Chemical Fume Suppressants

Surface tension is the force that keeps a fluid together at the air/fluid interface. It is expressed in force per unit of width such as dynes/centimeter. Chemical fume suppressants that contain ‘wetting agents,’ or surfactants, reduce this surface tension. By reducing surface tension in the plating/anodizing bath, gas bubbles become smaller and rise more slowly than larger bubbles. Slower bubbles have reduced kinetic energy such that when the bubbles do burst at the surface the hexavalent chromium is less likely to be emitted into the air, and the droplets fall back onto the surface of the bath (Bayer ® ).

The most common types of surfactants used in chromium electroplating and chromic acid anodizing are fluorinated or perfluorinated compounds or fluorosurfactants (U.S. EPA, 1998). As proposed, the types of chemical fume suppressants that could be used for compliance with the ATCM would contain fluorosurfactants.

b. HEPA (High Efficiency Particulate Arrestor) Filters

HEPA filters are specifically designed for the collection of submicrometer particulate matter at high collection efficiencies. HEPA filters are rated at 99.97 percent effective in capturing particles 0.3 μm in diameter. When used in particulate air pollution control, HEPA filters are best utilized in applications with a low flow rate and low pollutant concentration. Typically, HEPA filters are installed downstream of another control device to lessen loading on the filter, thereby lengthening its life. HEPA filters are considered the most effective control of hexavalent chromium emissions from chromium plating and chromic acid anodizing.

16. What are the goals of the proposed amendments?

The goals of the proposed amendments are to achieve the maximum hexavalent chromium emission reduction from chromium plating and chromic acid anodizing facilities, ensure that new facilities are isolated from sensitive receptors, and reduce fugitive

hexavalent chromium emissions.ES-11

17. How would the proposed amendments achieve these goals?

The proposed amendments would require use of BACT for all facilities. Use of HEPA filters, or other combinations of controls that are as effective as HEPA filters, represent BACT for intermediate and large throughput facilities. BACT for very small facilities is the use of ARB specified chemical fume suppressants. The requirements would be phased in based on throughput and proximity to sensitive receptors. Sensitive receptor locations include residences, schools, daycare centers, hospitals, hospices, retirement or nursing homes, prisons and dormitories.

The proposal would also prevent new hexavalent chromium plating and chromic acid anodizing facilities from operating in areas zoned as residential or mixed use or within 150 meters (~500 feet) of these zones. Any new facility would also be required to install state-of-the-art add-on air pollution control devices prior to beginning operations.

Proposed housekeeping provisions would reduce fugitive emissions of hexavalent chromium from all facilities by establishing housekeeping measures.

18. What would the proposed amendments require for existing hexavalent chromium plating and chromic acid anodizing facilities?

Staff is proposing to amend the Chromium Plating ATCM by phasing in BACT. The timing for application of BACT would be related to throughput and proximity to sensitive receptors. The requirements and timing are shown in Table ES-2 below.

Table ES-2 . Proposed Hexavalent Chromium Emission Limits for Existing Facilities

Tiers of

Annual

Permitted Ampere-Hours Sensitive

Receptor

Distance Emission Limitation Effective Date

Tier 1

≤ 20,000 A ny Use Chemical Fume Suppressant as specified in section 93102.8 [Six Months after Effective Date]

Tier 2 > 20,000 and

≤ 200,000 < 100

Meters 0.0015 milligrams/ampere-hour [Two Years after Effective Date]

Tier 3 > 20,000 and

≤ 200,000 > 100

Meters 0.0015 milligrams/ampere-hour [Five Years after Effective Date]

Tier 4
> 200,000 Any 0.0015 milligrams/ampere-hour [Two Years after Effective Date]

As shown in Table ES-2, very low throughput (less than 20,000 ampere-hours per year) facilities would be required, at a minimum, to reduce hexavalent chromium emissions through use of specified chemical fume suppressants to lower surface tension of the plating or anodizing bath. This represents BACT for these facilities, and would generally ensure that the maximum cancer risk near the facility is under one in a million.ES-12

Intermediate-sized facilities (greater than 20,000 but less than 200,000 ampere-hours per year) would be required to meet an emission limitation of 0.0015 milligrams/ampere-hour. These facilities, however, would have the option to demonstrate compliance without installation of add-on air pollution control devices. This proposal, along with providing additional time to comply for those facilities more than 100 meters from a sensitive receptor, could reduce compliance costs for some small businesses.

The largest facilities (more than 200,000 ampere-hours per year) would be required to comply with the emission limitation of 0.0015 milligrams/ampere-hour within two years using an add-on air pollution control device(s). After application of BACT, facilities with remaining cancer risk over 25 per million exposed people would be required to conduct a site specific analysis of their facility’s risk to determine if further control measures are

necessary.

19. What would the proposed amendments require for any new facility?

The proposal would prevent new chromium plating or chromic acid anodizing facilities from operating in areas zoned residential or mixed use or within 150 meters (~500 feet) of an area zoned residential or mixed use. At this distance, modeling for point sources shows that the hexavalent chromium concentration has dropped off by about 80 percent. New facilities would also be required to conduct a site specific analysis to ensure their emissions do not cause adverse impacts.

20. What is staff proposing to limit fugitive emissions?

Fugitive dust emissions also likely impact people residing near chromium plating and chromic acid anodizing facilities. Therefore, staff is proposing that all facilities implement housekeeping measures to reduce dust emissions.

21. Are other changes proposed?

Yes. Training explaining the Chromium Plating ATCM and the requirements, conducted by ARB staff, would be required for employees responsible for compliance every two years. The training offered by SCAQMD would fulfill this requirement.

The proposal would also prohibit the sale or use of chromium plating or chromic acid anodizing materials unless sold or used by individuals or businesses under air district permit to conduct such operations.

Staff is proposing to require use of specific types of chemical fume suppressants for complying with the surface tension limits. The chemical fume suppressants that could be

used have been shown to reduce hexavalent chromium emissions to more than 0.01 milligrams/ampere-hour at the proposed surface tensions.

To implement the new hexavalent chromium emission reduction requirements, a definition for “sensitive receptor” is proposed. A "sensitive receptor" is proposed to be defined as “any residence including private homes, condominiums, apartments, and living quarters;ES-13

education resources such as preschools and kindergarten through grade twelve (k-12) schools; daycare centers; and health care facilities such as hospitals or retirement and nursing homes. A "Sensitive Receptor" includes individuals housed in long term care hospitals, hospices, prisons, and dormitories or similar live-in housing.”



### D. Health Benefits Resulting from the Proposed Amendments

Adoption of the proposed amendments would significantly reduce both emissions and cancer risk from chromium plating and chromic acid anodizing facilities.

22. How would emissions and cancer risk be reduced if the staff’s proposal were to be adopted?

If the staff’s proposal were to be adopted, an additional 40 percent of facilities would be reducing emissions by over 99 percent. Estimated cancer risk for residents and off-site workers living or working near chromium plating and chromic acid anodizing facilities would be reduced by up to 85 percent depending on the individual facility.

Table ES-3 below shows how excess cancer risk would be reduced beyond the risk reduction achieved by implementation of current ARB and district rules.

Table ES-3 . Adoption of Staff’s Proposal Significantly Reduces the Estimated Cancer

Risk from Hexavalent Chromium Emissions



### Number of Facilities by Cancer Risk

< 1 per million >1 < 10

per million >10 < 100

per million >100

per million Staff Proposal 162 41 17 0

Baseline 90 67 57 6

As shown in Table ES-3, by adopting the staff’s proposal about 162 facilities (74 percent) would have remaining cancer risk of no more than one per million exposed persons. This represents an additional 72 facilities compared to the baseline. Only 17 facilities (about 8 percent) would have estimated cancer risk of over ten per million exposed people. No facilities would have cancer risk exceeding 100 per million exposed people. Under the staff’s proposal each facility with residual cancer risk over 25 per million exposed people would need to do a site specific analysis to determine if further control measures are needed. Total hexavalent chromium emissions from all chromium plating and chromic acid anodizing facilities would decrease, by 55 percent, to 1.8 pounds per year.

Non-cancer health risks were also evaluated. Our analysis found that each facility’s hazard index was well below the level of concern (hazard index = 1). Adoption of the proposal would only lower further the potential for any adverse non-cancer effects to

occur.ES-14



### E. Public Outreach

23. In developing the proposal what actions did staff take to consult with all

stakeholders?

Staff worked with the air districts, industry, the environmental community, and other affected parties through public workshops, meetings, telephone calls, and mail-outs. Major outreach activities included:

• Forming an ARB/Air District Working Group;

• Forming an ARB/Stakeholder Working Group and conducting meetings in Northern and Southern California;

• Conducting site visits to numerous chromium plating and chromic acid anodizing operations;

• Creating a website and maintaining a List-Serve to automatically update interested parties about proposed ATCM developments;

• Conducting surveys of chromium plating and chromic acid anodizing facilities, chemical fume suppressant manufacturers providing chemicals and services to the chromium plating and chromic acid anodizing facilities in California, and conducting an economic survey of the industry;

• Mailing workshop notices and posting workshop materials on ARB’s website;

• Conducting public workshops, with conference call tie-in, in Northern and Southern California; and

• Preparing a fact sheet regarding the development of the proposed ATCM and making it available to the public.



### F. Economic Impacts of the Staff’s Proposal

Staff has evaluated the financial impact on California businesses that would result from adoption of the proposed amendments. Staff conducted a very conservative cost impact assessment. While some businesses may be able to demonstrate compliance without purchasing a HEPA system, it was assumed for the purpose of our economic impact analysis that all facilities required to meet the 0.0015 milligrams/ampere-hour limit would purchase a HEPA filtration system.

24. How many businesses are impacted by the staff’s proposal?

All of the 226 facilities affected by the proposed amendments to the ATCM will have some compliance costs. [Two facilities have closed down since conducting the survey.] Up to 89 facility owners would be required to expend significant capital to meet the requirements. About 60 percent of facilities however, are already in substantial compliance.ES-15

25. What would be an individual facility’s cost to comply?

During the first year, all facilities would have compliance costs. Costs will vary depending on the extent an individual business is already in compliance with the proposed amendments. We estimate that costs in the first year would range from $450 to $217,000, with an average cost of $23,000. In subsequent years, costs would range from near zero to $217,000, with an average cost of $53,000. After the first year, 60 percent of the facilities would have no additional compliance costs.

26. How would the Return on Owner’s Equity be affected?

All of the chromium plating and chromic acid anodizing businesses affected by these proposed amendments are California businesses. Businesses are affected by the proposed amendments to the extent that costs associated with implementation of the regulation may reduce their profitability.

Profitability impacts were estimated by calculating the decline in the return on owner’s equity (ROE). A decline in ROE of 10 percent or more is one indication that the ATCM could result in a significant adverse impact. The proposed amendments to the ATCM are expected to result in an average ROE decline of nine percent.

Staff has determined that costs for some individual businesses are expected to be significant and would adversely impact their profitability. For the 89 businesses that would likely need to install or upgrade add-on air pollution control devices, the estimated decline in profitability ranges from 3 to 41 percent. Twenty-eight of these are small businesses. The average estimated compliance cost for these businesses is about $53,000. Some smaller volume plating or anodizing businesses may decide to cease chromium plating or anodizing operations rather than make the investments needed to comply.

27. Is there any assistance available to help small businesses secure the necessary capital to comply?

The Governor, in 2005, signed legislation (Assembly Bill 721, Nunez) to establish a loan guarantee program for decorative chromium plating operations to purchase pollution control equipment. The program is administered by the Business, Transportation, and Housing Agency. The program will provide loan guarantees of up to $100,000 to owners of decorative chromium plating small businesses that are not able to qualify for a conventional loan. The loan guarantee program is now in effect. In July 2006, the Governor signed into law amendments to the loan guarantee program. The loan guarantee program is now available for all metal plating facilities.

28. Are manufacturers of chromium plating and chromic acid anodizing suppliers adversely impacted by the proposed amendments?

We do not expect manufacturers of chromium plating and chromic acid anodizing materials to incur any costs. However, the staff’s proposal to prohibit sales of chromiumES-16

plating kits to non-permitted facilities may result in lost revenue for these businesses. The proposed amendments would potentially impact the chemical manufacturers in a positive way through increased sale of chemical fume suppressants. Add-on air pollution control device manufacturers, as well as the metal fabricating industry would also benefit from the proposed amendments as controls and ductwork for ventilation systems is purchased.

29. Would consumers be impacted by the proposal?

The potential impact of the proposed amendments to the ATCM on consumers depends upon the extent to which affected businesses are able to pass on the increased cost to consumers in terms of higher prices for their goods and services. If all costs are passed onto the consumers, we expect the cost per ampere-hour to increase from near zero to about $2.20 per ampere-hour. These costs are estimated based on facilities that would have to install add-on air pollution control devices. The lower end of this cost would represent a large throughput facility, while the upper end cost would represent a small throughput facility.

To put these costs into perspective, consider that chromium plating an automobile bumper (a decorative chromium application) requires 50 ampere-hours to chromium plate. This would mean the increased cost to plate a bumper would increase from near zero to about $110. If re-plating a bumper costs $400 at present time, the cost of the bumper would increase from about $400 to as much as $510.

30. Are there any costs to public agencies?

Yes. The air districts, as a result of the proposed amendments, would incur costs for reviewing initial compliance status reports; reviewing or revising permit modifications for facilities adding or upgrading to HEPA, or an equivalent level of control; reviewing source test protocols and results; and reviewing site specific analyses, if necessary. We estimate the new costs to air districts resulting from the proposed amendments to the ATCM to be approximately $685,000. However, air districts can recover these costs through fees charged to the facilities.

31. What are the total costs of the proposed amendments to the Chromium Plating ATCM?

Total capital costs for purchase of add-on air pollution control devices are estimated at $9.6 million. Total recurring costs are estimated at $3.6 million. An additional $1.0 million in costs is estimated for reports, source testing, permit fees, and site specific analyses. In total costs are estimated to be $14.2 million.ES-17



### G. Evaluation of Alternatives

32. What alternatives to the proposed amendments to the Chromium Plating

ATCM did staff consider?

Staff considered four alternatives to the proposed amendments. The alternatives were evaluated in terms of applicability, risk reduction, enforceability, and cost.

a. Require decorative chromium plating facilities to use the trivalent chromium plating process

One alternative to the staff’s proposal would be to require the use of the trivalent chromium plating process for all decorative chromium plating facilities. Requiring all decorative chromium facilities to use the trivalent chromium process would eliminate the remaining cancer risk from the hexavalent chromium emissions from decorative chromium plating facilities. Staff has evaluated the trivalent chromium process and has determined that it is not a universal replacement for all decorative chromium plating applications. Therefore, staff has determined this is not a technologically feasible

alternative.

b. Require HEPA filtration systems, or an equivalent add-on air pollution control device, for all facilities

Another alternative would be to require installation of HEPA filtration systems, or an equivalent add-on air pollution control device for all facilities. Staff determined that this alternative would result in no appreciable additional benefit because the very small facilities would have estimated cancer risk of no more than one per million exposed people after implementation of the proposal. This option would add additional equipment costs of over $4.0 million. As a result staff chose not to pursue this alternative.

c. Adopt the provisions of SCAQMD Rule 1469 statewide

A third alternative considered was to adopt the provisions of SCAQMD Rule 1469 statewide. In 2003, the SCAQMD amended its Rule 1469, Control of Hexavalent Chromium Emissions from Chrome Plating and Chromic Acid Anodizing Operations (Rule 1469). The rule requires hexavalent chromium facilities located within 25 meters of a sensitive receptor or within 100 meters of a school to reduce hexavalent chromium emissions such that the residential cancer risk will be no more than ten chances per million people. The rule also requires facilities located greater than 25 meters from a sensitive receptor or 100 meters from a school to reduce emissions such that off-site worker cancer risk would be no more than 25 chances per million people. The amended

rule is in full effect.

Staff has evaluated this alternative and has found it does not provide the level of protection that would be achieved through adoption of the staff’s proposal. Such an approach would not ensure that BACT is applied at all facilities. ARB staff has determined that BACT for very small facilities ( ≤ 20,000 ampere-hour throughput) is useES-18

of specific types of chemical fume suppressants. BACT for intermediate and larger facilities is use of add-on air pollution control devices with the final capture device being HEPA filters, or any other combination of controls that are as effective as HEPA filters.

d. Require no further control

Alternative 4 would be to require no additional control. Staff does not believe the status

quo is protective of public health especially considering that 43 percent of operations are located within 100 meters of a sensitive receptor. Our goal is to achieve the maximum feasible health protection—especially when people are living, learning, working, or playing near chromium plating and chromic acid anodizing facilities. Thus, staff did not choose

this alternative.

e. Summary

Table ES-4 compares alternatives three and four with the staff’s proposal. Alternatives one and two are not presented. Alternative one is not technologically feasible. Alternative two essentially offers no benefit beyond the staff’s proposal.

Table ES-4 . Adoption of Staff’s Proposal Offers the Greatest Reduction in Significant

Community Cancer Risk



### Number of Facilities by Cancer Risk

< 1 per million >1 < 10

per million >10 < 100

per million >100

per million Staff Proposal 162 41 17 0

Rule 1469

Statewide 98 67 53 2

Baseline 90 67 57 6

Table ES-4 shows that the staff’s proposal offers the best health protection. As shown, adopting the provisions of SCAQMD Rule 1469 statewide would result in 98 facilities (about 45 percent) with remaining cancer risk of no more than one per million exposed persons. This represents an additional 8 facilities compared to the baseline. Adoption of the staff’s proposal would reduce the estimated cancer risk for 162 facilities (about 74 percent) to no more than one per million exposed persons.

Table ES-4 also shows that if the provisions of Rule 1469 were to be adopted statewide, 53 facilities (about 24 percent) would continue to have estimated cancer risk of over ten per million exposed people, and two facilities would have estimated cancer risk of over 100 per million exposed people. If the staff’s proposal were adopted, 17 facilities (about 8 percent) would have estimated cancer risk of over ten per million exposed people and no facilities would have cancer risk exceeding 100 per million exposed people. Under the staff’s proposal each facility with residual cancer risk over 25 per million would need to do a site specific analysis to determine if further control measures are needed.ES-19

f. Conclusion

We evaluated each of the alternatives and concluded that the alternatives did not meet the objective of Health and Safety Code section 39666 to reduce emissions to the lowest level achievable in consideration of cost, health risk, and environmental impacts. Staff believes the proposed amendments represent the best balance between costs and

cancer risk.



### H. Environmental Impacts

33. What are the expected environmental benefits if the proposed amendments are adopted?

The primary benefit from the proposed amendments is a large reduction in excess cancer risk from emissions of hexavalent chromium. We estimate that an additional 40 percent of facilities would be controlling emissions by over 99 percent and cancer risk would be reduced by up to 85 percent for individual facilities. Almost 75 percent of facilities would have cancer risk of less than one per million people exposed. Ninety-two percent of facilities would have cancer risk of less than ten per million people exposed. The proposal will also have a direct benefit for low income and ethnically diverse communities that may be heavily impacted by hexavalent chromium emissions from chromium plating and chromic acid anodizing operations.

34. Are there any significant adverse environmental impacts that would result from adopting the proposed amendments?

No. We evaluated the potential impacts on air quality, water and wastewater, and

hazardous waste. We also evaluated the effect on the environment of the use of chemical fume suppressants.

Air Quality . The proposed amendments to the ATCM would result in a negligible improvement in air quality in terms of the weight of the emissions. While the proposed amendments reduce emissions of hexavalent chromium by about 55 percent, the actual reduction in mass is about 2.2 pounds per year. Remaining emissions are estimated to be 1.8 pounds per year.

It is also anticipated that there will be a temporary increase in emissions of criteria pollutants due to construction related activity involved in the installation of new add-on air pollution controls and the possible dismantling of current controls.

Water and Wastewater . Many of the add-on air pollution control devices required by the proposed amendments require periodic water washdown to clean and maintain the integrity of the system. Implementation of housekeeping measures would likely require fresh water usage as well. The increased water usage is difficult to quantify. However, we do not expect the increased use to be significant. We expect the amount of wastewater to also increase due to the proposed amendments related to housekeeping and equipment maintenance. Compliance with State Water Resources Control BoardES-20

regulations would prevent this hexavalent chromium from being discharged to lakes, rivers, bays, or oceans.

Hazardous waste . The proposed amendments would require an additional

89 facilities to begin using add-on air pollution control devices with the final collection mechanism likely to be HEPA filters. These filters, as well as pre-filters designed to increase the useful life of HEPA filters, are considered hazardous waste to be disposed of in Class A landfills. HEPA filters are usually replaced at least annually, but replacement schedules depend upon the individual operation. Pre-filters are replaced more often. Assuming a typical filter volume of 4 cubic feet each, the resulting volume of hazardous waste generated is 2.9 cubic feet per day. We do not consider this to be a significant

increase in the amount of hazardous waste to be landfilled.

In California, all hazardous waste must be disposed of at a facility that is registered with the Department of Toxic Substances Control (DTSC). Chromium plating and chromic acid anodizing facility wastes are classified as hazardous waste because they contain

hexavalent chromium.

Use of Bioaccumulative Compounds . The fluorosurfactants used as active ingredients in chemical fume suppressants are often referred to as perfluorooctyl sulfonates (PFOS). While these products are highly effective at reducing hexavalent chromium emissions by reducing plating bath surface tension the compounds have been shown to be persistent, bioaccumulative, and toxic to mammals. Studies indicate that PFOS may have potential developmental, reproductive, and systemic toxicity (U.S. EPA, 2006). These compounds are being evaluated for addition to a Significant New Use Rule for perfluoroalkyl sulfonates (PFAS). Based on the staff’s proposal we estimate a maximum increased use of chemical fume suppressants of about three gallons per year.

We expect these impacts to be minimal and believe that the significant reduction in cancer risk overrides any small adverse impact that would result from adoption of the staff’s proposal.

35. Are any reasonably foreseeable mitigation measures necessary?

No. The California Environmental Quality Act requires an agency to identify and adopt feasible mitigation measures that would minimize any significant adverse environmental impacts described in the environmental analysis. The ARB staff has concluded that no significant adverse environmental impacts should occur from adoption of and compliance with the proposed amendments to the ATCM. Because no significant adverse impacts have been identified, no specific mitigation measures would be necessary.

36. Are there any reasonably foreseeable alternative means of compliance with the proposed amendments to the airborne toxic control measure?

Alternatives to the proposed amendments to the Chromium Plating ATCM are discussed in question 32. The ARB staff has concluded that the proposed amendments to the ATCM provide the most effective and least burdensome approach to reducing the public’sES-21

exposure to hexavalent chromium emitted from chromium plating and chromic acid anodizing facilities.

37. How does the staff’s proposal relate to ARB’s community health and environmental justice programs?

Environmental Justice is defined as the fair treatment of people of all races, cultures, and incomes with respect to the development, adoption, implementation, and enforcement of environmental laws, regulations, and policies. The ARB is committed to integrating environmental justice into all of our activities. The proposed amendments to the ATCM are consistent with our policies to reduce health risks from toxic air pollutants in all communities, including those with low-income and ethnically diverse populations, regardless of location. Potential health risks from hexavalent chromium emissions from chromium plating and chromic acid anodizing operations can affect both urban and rural communities. Therefore, reducing hexavalent chromium emissions from chromium plating and chromic acid anodizing operations will provide air quality benefits to urban and rural communities in the State, including low-income areas and ethnically diverse

communities.

We have identified several communities that may be heavily impacted by hexavalent chromium emissions from chromium plating and chromic acid anodizing operations. The residents in these communities would realize a large portion of the benefits of the proposal.

To further address environmental justice and the public’s concern regarding exposure to hexavalent chromium emissions, the proposed amendments to the ATCM would specify that any new facility would not be able to operate in any area zoned as residential or mixed use, or within 150 meters of a residential or mixed use zone.



### I. Recommendation

We recommend that the Board adopt the proposed amendments to the Chromium Plating ATCM. Staff has determined that the proposed amendments are necessary to reduce cancer risk from hexavalent chromium emissions from chromium plating and chromic acid anodizing facilities. If adopted, about 75 percent of facilities would have estimated cancer risk of no more than one per million exposed people. Ninety-two percent of facilities would have estimated cancer risk of no more than ten per million exposed people. Staff also believes the proposal represents a balance between health risk and cost. The proposed amendments are contained in Appendix A.

Within six months of the amendments becoming legally effective, the air districts would be required to implement and enforce the proposed amendments to the ATCM or adopt an equally effective measure.ES-22

REFERENCES

Bayer ®. Product information Bayowet® FT 248 and FT 248R.

SCAQMD, 2003. South Coast Air Quality Management District. Rule 1469: “Hexavalent Chromium Emissions from Chrome Plating and Chromic Acid Anodizing Operations”

. Amended May 2, 2003

U.S. EPA, 1995. U.S. Environmental Protection Agency. 40 CFR Part 63 Subpart N:

“National Emission Standards for Chromium Emissions From Hard and Decorative Chromium Electroplating and Chromium Anodizing Tanks” . 1995.

U.S. EPA, 1998. U.S. Environmental Protection Agency. EPA/625/R-98/002: “Capsule Report Hard Chrome Fume Suppressants and Control Technologies”. 1998.

U.S. EPA, 2006. U.S. Environmental Protection Agency. 40 CFR Part 721: “Perfluoroalkyl Sulfonates; Proposed Significant New Use Rule.” 2006.Chapter I Page 1



## I. Introduction

H exavalent chromium plating, or simply chromium plating, is the electrical application of a coating of chromium onto a surface for decoration, corrosion protection, or for durability. An electrical charge is applied to a tank (bath) containing an electrolytic salt (chromium anhydride) solution. The electrical charge causes the chromium metal particles in the bath to fall out of solution and deposit onto objects placed into the plating solution. During chromic acid anodizing, an oxidation layer is generated on the surface of the part. These electrolytic processes cause mists containing hexavalent chromium to be ejected from the plating tank which are eventually dispersed into outdoor ambient air.

Hexavalent chromium is a potent known human carcinogen. Consequently, the California Air Resources Board (ARB or Board) has regulated the hexavalent chromium emissions from chromium plating and chromic acid anodizing facilities since 1988. The existing control measure, the Hexavalent Chromium Airborne Toxic Control Measure for Chrome Plating and Chromic Acid Anodizing Operations (ATCM or Chromium Plating ATCM), is found in title 17, California Code of Regulations, section 93102.

ARB staff has determined that despite significant reductions, people living near chromium plating and chromic acid anodizing facilities are still exposed to unnecessarily high concentrations of hexavalent chromium. Therefore, this Initial Statement of Reasons sets forth the staff’s proposal to amend the ATCM (contained in Appendix A) and the rationale for the proposal.



### A. Overview

In 1986, based on a recommendation by the Scientific Review Panel (SRP) on Toxic Air Contaminants (TACs), the Board identified hexavalent chromium as a TAC (ARB, 1985). Hexavalent chromium was determined to be a potent human carcinogen with no known safe level of exposure. Subsequent to that finding, the Board adopted measures to control hexavalent chromium emissions, including an ATCM to reduce hexavalent chromium emissions from chromium plating and chromic acid anodizing operations. This ATCM reduced hexavalent chromium emissions from chromium plating and anodizing facilities by well over 90 percent.

While an over 90 percent reduction is significant, because of the potent carcinogenicity ofhexavalent chromium, even minute amounts are cause for concern, particularly for nearsource receptors. Hexavalent chromium emissions of as little as two grams per year can result in an estimated cancer risk of ten per million people exposed. Because of the potential for near-source unacceptable residual health risks, staff undertook an evaluation of the chromium plating and chromic acid anodizing industry and the existing ATCM to ensure that it continues to provide the maximum feasible health protection. These amendments are being proposed as a result of that evaluation. ARB staff hasChapter I Page 2

reviewed control technologies, emissions, population exposures, and remaining health risks, and has found that further control is feasible and warranted. This Initial Statement of Reasons (ISOR or Staff Report) sets forth the staff’s proposal to amend the Chromium Plating ATCM and outlines the need and rationale for the proposal. This staff report for the proposed amendments includes:

• Background regulatory information and authority;

• Goals of the regulation and public outreach;

• Chromium plating and chromic acid anodizing industry characterization;

• Findings from the Industry Survey, Chemical Manufacturers Survey, Economic Survey, and Receptor Proximity Survey;

• Emission factor development and the decorative chromium plating emissions testing

program;

• Potential exposure and risk from chromium plating and chromic acid anodizing operations;

• Availability and technological feasibility of potential control devices;

• Description of the proposed amendments;

• Economic impacts of the proposed amendments; and

• Environmental impacts of the proposed amendments.



### B. Goals of the Proposed Amendments

The goal of the proposed amendments to the Chromium Plating ATCM is to minimize the public’s exposure to hexavalent chromium emissions from chromium plating and chromic acid anodizing facilities. The amendments are designed to achieve the maximum hexavalent chromium emission reductions by using the most reliable controls available. The amendments are also designed to isolate people from new facilities. If adopted, the amendments would set more stringent requirements for all intermediate and large hexavalent chromium plating and chromic acid anodizing facilities by requiring best available add-on air pollution control technology (BACT). We have determined that BACT for very small facilities is the use of specific types of chemical fume suppressants. The requirements would be phased in based on throughput and proximity to sensitive receptors. Sensitive receptor locations include residences, schools, daycare centers, hospitals, hospices, retirement or nursing homes, prisons, and dormitories.

The proposal would also prevent new chromium plating and chromic acid anodizing facilities from operating in areas zoned as residential or mixed use or within 150 meters(~500 feet) of these zones. Any new facility would also be required to install state-of-theart add-on air pollution control devices prior to beginning operations.

Proposed housekeeping provisions would also reduce fugitive emissions of hexavalent chromium from all facilities by establishing housekeeping measures. Personnel at plating operations would also be required to undergo ARB-sponsored training to ensure that parameter monitoring and recordkeeping are done properly. The amendments would also prevent sale of chromium plating chemicals and equipment to any individual that was not the owner or operator of a permitted facility.Chapter I Page 3

The existing ATCM requirements are different based on the type of operation (decorative plating and anodizing or hard chromium plating). Under this proposal, all facilities using the hexavalent chromium process regardless of type of operation would be subject to the same control requirements. The proposed amendments are contained in Appendix A. Adoption of the staff’s proposal would result in reducing cancer risk by up to 85 percent

for individual facilities.

If adopted by the Board, the amended control measure would be implemented and enforced by the air pollution control and air quality management districts (air districts). The air districts may implement the proposed amendments to the ATCM, as adopted by the Board, or adopt an alternative rule at least as stringent as the ARB's ATCM.



### C. Regulatory Authority

Legislation enacted in the 1980’s delegated to ARB the authority and responsibility to identify and control toxic air contaminants. This section outlines the statutory authority to control toxic substances and includes a description of the processes that have been developed to fulfill the requirements of State law.

The ARB's statewide air toxics program was established in the early 1980's. Assembly Bill (AB) 1807 (Tanner, Chapter 1047, statutes 1983), The Toxic Air Contaminant Identification and Control Act, created California's Toxic Air Contaminant Identification and Control Program (Air Toxics Program) to reduce the public's exposure to air toxics. This law is codified in Health and Safety Code sections 39650 through 39675. AB 2588 (Connelly, Chapter 1252, statutes of 1987), Air Toxics "Hot Spots" Information and
Assessment Act, supplements the Air Toxics Program by requiring a statewide air toxics inventory, notification of people exposed to a significant health risk, and facility plans to

reduce these risks.

1. Identification and Control of Toxic Air Contaminants

The Air Toxics Program established a two step process to identify and then control air toxics to protect the health of Californians.

In the first step, a substance is formally identified as a TAC based on reviews by the ARB and the Office of Environmental Health Hazard Assessment (OEHHA). The agencies evaluate the health impacts of, and exposure to, substances, and identify as TACs those substances that pose the greatest health threat. The ARB's evaluation is made available to the public and is formally reviewed by the SRP on TACs established under Health and Safety Code section 39670. Following the ARB's evaluation and the SRP's review, the Board, at a public hearing, may formally identify a TAC.Chapter I Page 4

In the second step, risk reduction, the ARB reviews the emission sources of a TAC to determine what regulatory actions are available and necessary to maximize health protection. Health and Safety Code sections 39658, 39665, 39666, and 39667 require ARB, with the participation of the air districts, and in consultation with affected sources and interested parties, to prepare a report on the need and appropriate degree of regulation for a TAC. In situations where no safe threshold level is found for a particular TAC, the control measures are to be designed to reduce emissions to the lowest level achievable through application of BACT or a more effective control method in consideration of health risk to the public and cost.

2. The “Hot Spots” Program

Under the AB 2588 program, stationary sources are required to report the types and quantities of certain substances that their facilities routinely release into the air. The goals of the "Hot Spots" Act are to collect emission data, identify facilities having localized impacts, determine health risks, and notify nearby residents of significant risks. In September 1992, the "Hot Spots" Act was amended by SB 1731 to address the reduction of significant risks. The bill requires that owners of significant-risk facilities reduce their risks below the level of significance as determined by air districts. Chromium plating and anodizing operations are subject to the “Hot Spots” program, and, as described below, are also subject to a technology-based ATCM to minimize emissions of hexavalent

chromium.

3. Identification and Control of Hexavalent Chromium

In 1986, ARB identified hexavalent chromium as a TAC after peer review by the SRP. Hexavalent chromium was determined to be a potent known human carcinogen with a

cancer unit risk factor of 1.5 X 10 -1 microgram per cubic meter (μg/m 3 ) of air. This potency factor means that exposure to 1 μg/m 3 of hexavalent chromium over a lifetime would potentially result in 146,000 excess cancer cases per million exposed people. The Board also found that the available scientific evidence did not support a hexavalent chromium threshold exposure level below which significant adverse health effects would not be expected (title 17, California Code of Regulations, section 93000). Also, at this time, the Board did not find sufficient evidence to identify trivalent chromium as a TAC (ARB, 1985).

To reduce the risk from hexavalent chromium, the Board has adopted four ATCMs:

• 1988 - Hexavalent Chromium Airborne Toxic Control Measure for Chrome Plating and Chromic Acid Anodizing Operations (ARB, 1988) ;

• 1989 - Airborne Toxic Control Measure for Hexavalent Chromium For Cooling

Towers (ARB, 1989);

• 2001 - Airborne Toxic Control Measure for Emissions of Hexavalent Chromium and Cadmium From Motor Vehicle and Mobile Equipment Coatings (ARB, 2001);

• 2005 – Airborne Toxic Control Measure to Reduce Emissions of Hexavalent Chromium and Nickel From Thermal Spraying (ARB, 2005).Chapter I Page 5

This report describes staff’s proposal to further reduce the public’s exposure to hexavalent chromium from chromium plating and chromic acid anodizing facilities. To better understand the proposal it is important to first understand the requirements of the

current ATCM.



### D. Existing State Control Measure

The State’s existing Chromium Plating ATCM was originally adopted in 1988 and amended in 1998. The regulation is set forth in title 17, CCR, section 93102. The ATCM adopted in 1988 set technology-based standards that focused primarily on hard chromium plating facilities and set limits based on BACT at that time. Implementation of this regulation resulted in hexavalent chromium emission reductions of over 90 percent. A brief summary of the requirements for the existing ATCM follows:

• Hard chromium plating facilities are required to install add-on air pollution control devices to meet emission limits ranging from 0.15 milligrams/ampere-hour (mg/amp-hr) to 0.006 milligrams/ampere-hour, depending on levels of throughput. An alternative surface tension limit was provided for hard chromium plating facilities with throughput levels of 500,000 ampere-hours or less; and

• Decorative plating and anodizing facilities must comply with either an emission limit using add-on air pollution controls or meet a surface tension limit. Most facilities comply by meeting the surface tension limit.

The ATCM also has recordkeeping requirements and operation and maintenance requirements. However, the existing ATCM does not take into account proximity of existing chromium plating and chromic acid anodizing facilities to people.

The ATCM was amended in 1998 to establish equivalency with the National Emission Standards for Chromium Emissions from Hard and Decorative Chromium Electroplating and Chromium Anodizing Tanks (Chromium Plating NESHAP) (U.S. EPA, 1995). The federal Chromium Plating NESHAP included control requirements for trivalent chromium operations because it is a hazardous air pollutant (HAP). Therefore, the focus of ARB's 1998 amendments was to include provisions for controlling emissions from trivalent chromium plating facilities (ARB, 1998). Also, prior to these amendments, chromic acid anodizing facilities were required to comply with the same provisions as hard chromium plating facilities. These amendments provided that chromic acid anodizing facilities could comply with the surface tension limit alone rather than the previous emission rate limit. Other conforming changes included:

• Parameter Monitoring requirements;

• Inspection and Maintenance requirements;

• Operation and Maintenance Plan requirements;

• Recordkeeping requirements; and

• Reporting requirements.Chapter I Page 6



### E. Federal Regulations

Because the ARB has achieved equivalency with the Chromium Plating NESHAP for chromium plating and chromic acid anodizing facilities, California’s facilities are only required to comply with the State’s ATCM (Approval of section 112 (l) Authority of Hazardous Air Pollutants; Chromium Emissions from Hard and Decorative Chromium Electroplating and Chromium Anodizing Tanks; State of California; Approved December 16, 1998, Volume 63, number 241, Page 69251-69256) (U.S. EPA, 1998a). However, a description of United States Environmental Protection Agency’s (U.S. EPA) Chromium Plating NESHAP, as well as the Occupational Safety and Health Administration’s (OSHA) permissible exposure level for hexavalent chromium is useful to understand how chromium plating facilities and chromic acid anodizing facilities are regulated.

1. Chromium Plating NESHAP

The 1990 federal Clean Air Act Amendments established a list of Hazardous Air Pollutants (HAPs) and directed the U.S. EPA to set standards for all major sources of air toxics. “Chromium Compounds,” including hexavalent chromium and trivalent chromium are listed as HAPs. [In 1992, California AB 2728 (Tanner, Chapter 1161, statutes of 1992) specified that ARB must, by regulation, identify as TACs the 189 substances identified by the federal government as HAPs.]

For certain designated source categories, U.S. EPA has developed specific regulations referred to as the National Emission Standards for Hazardous Air Pollutants (NESHAPs). In January 1995, the U.S. EPA promulgated, in 40 Code of Federal Regulations (CFR) Part 63, Subpart N, the Chromium Plating NESHAP. Concentration standards were established for hard chromium plating facilities. These limits could be met by the addition of forced ventilation systems, but add-on air pollution control devices were not necessarily needed. Surface tension limits were established for decorative chromium plating facilities and chromic acid anodizing facilities (U.S. EPA, 1995).

On July 19, 2004, the U.S. EPA amended the Chromium Plating NESHAP. The changes

are summarized below.

• Allowed the use of chemical fume suppressants to control chromium emissions from hard chromium plating facilities as an alternative to the existing concentration emission limit;

• Provided an alternative standard to the existing concentration emission limit for hard chromium plating tanks equipped with enclosed hoods;

• Modified surface tension parameter testing to accommodate the differences in measurement between the use of a stalagmometer and the tensiometer (stalagmometer requirement: < 45 dynes/centimeter; tensiometer requirement: < 35 dynes/centimeter);

• Expanded the definition of “chromium electroplating and anodizing” to include all of the ancillary hardware associated with the plating process. This includes suchChapter I Page 7

items as the tank, “add-on” control equipment, rectifier, process tanks, ductwork, etc.; and

• Amended the pressure drop for composite mesh pads to ±2 inches of water column instead of ±1 inch of water column (U.S. EPA, 2004).

2. Federal OSHA Worker Exposure Limits

Under the U.S. Department of Labor, OSHA published a Permissible Exposure Limit (PEL) to protect workers from hexavalent chromium exposures. The exposures to hexavalent chromium are addressed in specific standards for maritime, construction, and general industries.

OSHA's PEL for chromic acid and chromates is found in 29 CFR 1910.1000, Table Z-2.On February 28, 2006, OSHA changed the hexavalent chromium rule by setting a timeweighted average PEL of 5 μg/m 3 , measured and reported as Chromium VI, and an action level of half the PEL for the general industry. OSHA also adopted other ancillary provisions for employee protection such as preferred methods for controlling exposure, respiratory protection, protective work clothing and equipment, establishing hygiene areas and practices, medical surveillance, hazard communication, and recordkeeping (OSHA, 2006). More information can be found at the following webpage: http://www.osha.gov/SLTC/hexavalentchromium/standard s.html

.



### F. Current Air District Rules

As required by State law, air districts are required to adopt, implement, and enforce rules that are equivalent to any State adopted ATCM, or may elect to adopt a rule that is more stringent. The air districts also are required to gather from facilities emissions information required by the “Hot Spots” Act. Some air districts also have adopted rules or policies that require existing facilities to reduce health risks below an air district specified level of significance. New facilities generally are not allowed to operate unless the potential health risk posed by the facility’s emissions is below the air district’s level of significance.

Chromium plating and chromic acid anodizing facilities operate under permits issued by each air district. Table I-1 lists air districts that have active chromium plating and/or chromic acid anodizing facilities and the rule with which facilities in that air district must comply.Chapter I Page 8

Table I-1 . Air Districts with Active Chromium Plating and/or Chromic Acid Anodizing Facilities and Corresponding Prohibitive Rule

District Rule

Bay Area Air Quality Management District (BAAQMD) Rule 11.8 Feather River Air Quality Management District (FRAQMD) Rule 11.2
South Coast Air Quality Management District (SCAQMD) Rule 1469
Sacramento Metropolitan Air Quality Management District (SMAQMD) Rule 904

San Diego County Air Pollution Control District (SDCAPCD) Rule 1201

San Joaquin Valley Air Pollution Control District (SJVAPCD) Rule 7011

Shasta County Air Quality Management District Rule 3:11
Ventura County Air Pollution Control District (VCAPCD) Chromium Plating

ATCM

Of particular interest for this rulemaking is the May 2003 amendments to Rule 1469 adopted by the South Coast Air Quality Management District (SCAQMD), Hexavalent Chromium Emissions from Chrome Plating and Chromic Acid Anodizing Operations (SCAQMD, 2003). These changes were designed to further reduce health risk by specifying lower emission rates for all facilities, and establishing more stringent requirements for facilities located near sensitive receptors than were in place at the time. The goal was to specify emission rates to reduce the potential cancer risk from all facilities below the air district’s level of significance, a potential cancer risk of no more than 25 per million persons. However, more stringent requirements were specified for facilities located within 25 meters of a sensitive receptor, or 100 meters of an existing school. In these instances, potential cancer risks were to be reduced below ten per million persons. A summary of the changes is provided below:

• Set more stringent mass emission limits with increasing ampere-hours and distance to receptor;

• Established a fume suppressant certification program and an emission rate of 0.01 milligrams/ampere-hour for certified fume suppressants;

• Added housekeeping practices for all facilities;

• Prohibited the air sparging of chromium plating or anodizing tanks, unless in use;

• Prohibited removal of existing add-on air pollution control equipment, unless replaced with air pollution control techniques meeting higher control efficiencies;

• Provided optional emission limits for small facilities;

• Added alternative compliance options for all facilities; and

• Established an operator training requirement.

As part of the “Hot Spots” program, air districts have developed rules or policies designed to further reduce health risks from sources of toxic air pollutants. These rules are triggered at air district specified levels of significance and apply to both new and existingChapter I Page 9

facilities. These rules establish the health risk levels that trigger the need for installation of BACT for Toxics (T-BACT). Generally, new facilities are subject to the more stringent requirements. All of these rules and policies have been useful in our evaluation of measures that are feasible to further reduce health risk from chromium plating and chromic acid anodizing operations. A synopsis of some of these rules is provided below.

SCAQMD Rule 1401, New Source Review of Toxic Air Contaminants applies to air permits for new, relocated, or modified sources that emit TACs. If the potential increase in cancer risk from a modification does not exceed one case per one million persons, T-BACT controls are not required to obtain an air permit. If the potential increase in cancer risk is between 1 and 10 per million persons, T-BACT controls are required to obtain an air permit. In addition, the cancer burden must not exceed 0.5 cases (SCAQMD, 1990).

SCAQMD Rule 1402, Control of Toxic Air Contaminants from Existing Sources, specifies an action risk level of 25 excess cases per million persons for cancer risk, a cancer burden of 0.5, or a total acute or chronic hazard index of 3.0 for any target organ system at any receptor location. [An acute or chronic hazard index is the ratio of the estimated level of exposure over a specified period of time to its acute or chronic reference exposure level.] Existing facilities that exceed the action risk level must develop risk reduction plans and implement measures to reduce risks to below the action level. The amendments to Rule 1469 were designed as an alternative for chromium plating and chromic acid anodizing facilities to meet the requirements of Rule 1402 (SCAQMD, 1994).

San Diego County Air Pollution Control District (SDCAPCD) Rules 1200, Toxic Air Contaminants – New Source Review, and 1210, Toxic Air Contaminant Public Health Risks – Public Notification and Risk Reduction, specify that if the potential increase in cancer risk does not exceed one per million persons, T-BACT controls are not required to obtain an air permit. If the potential increase in cancer risk is between 1 and 10 per million persons, T-BACT controls are generally required to obtain an air permit. If the potential increased cancer risk is greater than 10 but no more than 100 per million persons, it may still be possible to get an air permit if a facility can meet specific conditions (SDCAPCD, 1996).

The Bay Area Air Quality Management District (BAAQMD) does not have a specific rule for toxics permitting. However, BAAQMD’s permitting policy is generally consistent with the SCAQMD and SDCAPCD toxics new source review rules. All permit applications for new or modified sources are screened for emissions of TACs and sources that may present significant health risks are required to install T-BACT to minimize TAC emissions (BAAQMD, 2005).



### G. Barrio Logan, A Case Study of Near Source Impacts

In May of 2001, ARB, with cooperation of the SDCAPCD, began monitoring around two chromium plating facilities in the Barrio Logan neighborhood of San Diego. A residence

was located between these facilities and numerous residences were in the area. Local concern about possible exposures to hexavalent chromium emissions from theseChapter I Page 10

facilities, as well as, the Children’s Environmental Health Protection Act [Senate Bill 25, Escutia 1999 (SB 25)] prompted the study. SB 25 required ARB to evaluate the air that children are exposed to in places where they live and play and to determine if current regulations adequately protect them. One facility was a hard chromium plating operation with emissions controlled by a HEPA filter system. The other facility was a decorative plating operation with emissions controlled by using a chemical fume suppressant to reduce the surface tension of the plating bath.

In January 2002, unexpectedly high levels of hexavalent chromium were found at a number of monitoring sites. More intensive monitoring pinpointed the source of the elevated levels of hexavalent chromium to be from the decorative chromium plating facility. Through this study, we also found that fugitive dust emissions from the facility contributed to community hexavalent chromium exposures. For more detailed information, please refer to the Barrio Logan Report, “A Compilation of Air Quality Studies in Barrio Logan, November 2004” (ARB, 2004). The report can be found at the following address: http://www.arb.ca.gov/ch/programs/bl_11_04.pdf



### H. Hexavalent Chromium Emissions Study and Conclusions

The results of air monitoring for hexavalent chromium in Barrio Logan indicated that emissions from decorative chromium plating facilities may be underestimated. To investigate this theory, we undertook a hexavalent chromium emissions testing program at decorative chromium plating facilities in various parts of the State to evaluate the emission factor for facilities using only in-tank controls. As a result of this testing, the emission factor for chemical fume suppressant controlled facilities (those complying with

the surface tension limit 1 ) has been revised and is used in this report to assess emissions of, and exposure to, hexavalent chromium from these facilities.

Through our evaluation, we have found that there are remaining significant public health risks associated with hexavalent chromium emissions from chromium plating and chromic acid anodizing facilities, especially when facilities are located near homes or schools. In assessing existing, readily available, control technologies for chromium plating and chromic acid anodizing facilities, staff believes further control is feasible and necessary to protect the health of California’s residents, by reducing exposure to hexavalent chromium.

1 Chemicals are added to the plating bath that reduce surface tension. Surface tension reductions also reduce

hexavalent chromium emissions.Chapter I Page 11



### REFERENCES

ARB, 1985. Air Resources Board . “ Staff Report: Initial Statement of Reasons for Proposed Rulemaking – Public Hearing to Consider the Adoption of a Regulatory Amendment Identifying Hexavalent Chromium as a Toxic Air Contaminant”. 1985.

ARB, 1988. Air Resources Board. “Final Regulation Order – Hexavalent Chromium Airborne Toxic Control Measure (ATCM) for Chrome Plating and Chromic Acid Anodizing Operations”. 1988.

ARB, 1989. Air Resources Board

. “Final Regulation Order – Chromate Treated Cooling

Towers”. 1989.

ARB, 1998. Air Resources Board. “Staff Report – Proposed Amendments to the Hexavalent Chromium Control Measure For Decorative and Hard Chrome Plating and Chromic Acid Anodizing Facilities”. 1998.

ARB, 2001. Air Resources Board. “Final Regulation Order - Airborne Toxic Control

Measure for Emissions of Hexavalent Chromium and Cadmium From Motor Vehicle and Mobile Equipment Coatings”. 2001.

ARB, 2004. Air Resources Board. “Barrio Logan Report: A Compilation of Air Quality Studies in Barrio Logan”. 2004.

ARB, 2005. Air Resources Board. “Final Regulation Order - Airborne Toxic

Control Measure to Reduce Emissions of Hexavalent Chromium and Nickel from Thermal Spraying”. 2005.

BAAQMD, 2005. Bay Area Air Quality Management District. Regulation 2 Permits Rule

5: “New Source Review of Toxic Air Contaminants”. 2005.

OSHA, 2006. Occupational Safety and Health Administration. 29 CFR Parts 1910, 1915, 1917, 1918, and 1926, “Occupational Exposure to Hexavalent Chromium; Final Rule”

. 2006

SCAQMD, 1990. South Coast Air Quality Management District. Rule 1401: “New

Source Review of Toxic Air Contaminants”. 1990

SCAQMD, 1994. South Coast Air Quality Management District. Rule 1402: “Control of Toxic Air Contaminants from Existing Sources”. 1994

SCAQMD, 2003. South Coast Air Quality Management District. Rule 1469: “Hexavalent Chromium Emissions from Chrome Plating and Chromic Acid Anodizing Operations”

. Amended May 2, 2003Chapter I Page 12

SDCAPCD, 1996. San Diego Air Pollution Control District: Rule 1200: “Toxic Air

Contaminants – New Source Review” . Revised June 12, 1996

U.S. EPA, 1995. U.S. Environmental Protection Agency. 40 CFR Part 63 Subpart N:

“National Emission Standards for Chromium Emissions From Hard and Decorative Chromium Electroplating and Chromium Anodizing Tanks” . 1995.

U.S. EPA, 1998a. U.S. Environmental Protection Agency. 40 CFR Part 63: “Approval of Section 112(I) Authority for Hazardous Air Pollutants; Chromium Emissions from Hard and Decorative Chromium Electroplating and Chromium Anodizing Tanks; State of

California” . 1998.

U.S. EPA, 2004. U.S. Environmental Protection Agency. 40 CFR Part 63: “National

Emission Standards for Chromium Emissions From Hard and Decorative Chromium Electroplating and Chromium Anodizing Tanks”. 2004.Chapter II Page 13



## II. Need for Further Regulation

I n 1986, the Board identified hexavalent chromium as a Toxic Air Contaminant (TAC). Hexavalent chromium was determined to be an extremely potent human carcinogen with no known safe level of exposure. The Board found that exposure over a lifetime to very low ambient hexavalent chromium concentrations could substantially increase a person’s chance of developing cancer from exposure to the hexavalent chromium emissions. Based on this finding, in 1988 the Board adopted a very stringent ATCM which resulted in reducing hexavalent chromium emissions from chromium plating and chromic acid anodizing facilities by well over 90 percent. While an over 90 percent reduction is significant, even minute amounts are cause for concern, particularly for near-source receptors because of the potent carcinogenicity of hexavalent chromium.

Ambient levels of hexavalent chromium measured from our air toxics monitoring network are routinely low, with many measurements below the level of detection. Thus, the general public’s exposure to ambient hexavalent chromium concentrations is not considered significant. However, near-source exposures can be significant. In 2002, SCAQMD conducted limited ambient air sampling around several chromium plating and chromic acid anodizing facilities. Based on this monitoring, estimated cancer risks from five facilities ranged from 20 to 55 per million people exposed. Four facilities had cancer risks of less than ten per million exposed people. One facility had an estimated cancer risk of 450 per million exposed people (SCAQMD, 2003a). [SCAQMD worked with the facility with cancer risk of 450 per million exposed people to reduce the risk.] Although these data were collected prior to implementation of Rule 1469, the results demonstrate

that measurable and elevated concentrations of hexavalent chromium are found near these sources. Due to implementation of SCAQMD Rule 1469, these estimated cancer

risks from the facilities tested could be lower.

Information from our Barrio Logan study reinforce findings that hexavalent chromium emissions from chromium plating and chromic acid anodizing operations are measurable, but highly localized. The Barrio Logan study, also showed that dust containing hexavalent chromium can contribute to ambient, near-source concentrations. This result was confirmed by follow-up sampling conducted by the SDCAPCD. These fugitive emissions can not be quantified for all facilities, but could increase the cancer risk beyond what is calculated based on emissions from the plating operation alone.

Our modeling analyses also indicate that near-source concentrations are, in many cases, significant. Hexavalent chromium emissions of as little as two grams per year can result in an estimated cancer risk of ten per million people exposed. Thus, staff has found that emissions from some facilities still result in unacceptable health risks to near-by receptors. Based on our evaluation of chromium plating and chromic acid anodizing facilities, we found that it is common to find sensitive receptors near these facilities. In fact, we found that 43 percent of facilities are located within 100 meters of a sensitive receptor. For all of these reasons, staff has determined that, despite the fact that significant emissions reductions have been achieved, there is a need to further reduce emissions, if technologically feasible.Chapter II Page 14

This Chapter contains a general summary of the physical and chemical characteristics of hexavalent chromium and chromium compounds. Emissions and sources of hexavalent chromium, as well as health effects from exposure to hexavalent chromium are also provided. For ease of the reader, we have summarized some of the information from earlier reports, and have updated information where appropriate. For further information, the reader is referred to the following documents:

• Staff Report: Initial Statement of Reasons for Proposed Rulemaking – Identification of Hexavalent Chromium as a Toxic Air Contaminant (ARB,1985);

• Proposed Hexavalent Chromium Control Plan (ARB, 1988a);

• Initial Statement of Reasons for Proposed Rulemaking – Proposed Airborne Toxic Control Measure for Emissions of Hexavalent Chromium from Chrome Plating and Chromic Acid Anodizing Operations (ARB, 1988b);

• Proposed Hexavalent Chromium Control Measure for Cooling Towers (ARB, 1989a);

• Toxic Air Contaminant Identification List Summaries (ARB, 1997);

• Airborne Toxic Control Measure for Emissions of Hexavalent Chromium and Cadmium from Motor Vehicle and Mobile Equipment Coatings: Initial Statement of Reasons for Proposed Rulemaking Executive Summary/Staff Report (ARB, 2001a); and

• Airborne Toxic Control Measure to Reduce Emissions of Hexavalent Chromium and Nickel from Thermal Spraying Initial Statement of Reasons for Proposed Rulemaking (ARB, 2004a).

In support of the need for further regulation, this Chapter also contains a synopsis of our Barrio Logan study findings and results from our survey to determine proximity of sensitive receptors to hexavalent chromium plating and chromic acid anodizing facilities.



### A. Characteristics, Sources, and Ambient Concentrations of Hexavalent Chromium and Chromium Compounds

The chromium compounds of interest for this staff report are the TACs hexavalent

chromium and trivalent chromium. Because hexavalent chromium is a TAC and has been identified as a human carcinogen with no known safe exposure level (ARB, 1985), the focus of the staff’s proposal is to further reduce hexavalent chromium emissions from chromium plating and chromic acid anodizing facilities.

Trivalent chromium has been identified as a TAC by virtue of it being a hazardous air pollutant (HAP). By comparison to hexavalent chromium, it poses lesser health hazards. It is not a human carcinogen. Health hazards associated with use of trivalent chromium are presented to put these hazards in perspective to the health hazards associated with use of hexavalent chromium. Due to the comparatively lower toxicity impact, staff believes trivalent chromium plating (for decorative plating) to be a safer alternative to

hexavalent chromium plating. In fact, the trivalent chromium chemistry is already successfully in use at several California decorative chromium plating facilities. However,Chapter II Page 15

although improvements in the process have been made, use of trivalent chromium is not available for all applications.

1. Chemistry

Trivalent chromium occurs naturally in the mineral chromite (chrome ore). It is from chromite that chromium metal and other chromium compounds are formed. Of the
various chromium oxidation states, trivalent chromium is the most stable. Hexavalent chromium is the cation of a metal salt and does not occur naturally. Generally, hexavalent chromium ions are produced under strong oxidizing conditions from metallic chromium, with the most common ions being chromate ion (CrO 4 -2 ) or dichromate ion (Cr 2 O 7 -2 ). Hexavalent chromium ions are strong oxidizing agents and are readily reduced to trivalent chromium in acid or by organic matter (ARB, 1997).

2. Sources and Emissions

Chromium plating, chromic acid anodizing, thermal spraying, and firebrick lining of glass furnaces are all stationary sources of hexavalent chromium in California. In California, stationary sources are estimated to emit about 1,000 pounds per year of hexavalent chromium. Approximately 0.13 tons/year are emitted by gasoline vehicles and 0.83 tons/year by other mobile sources such as trains and ships (ARB, 2006a). Chapter V describes the emissions of hexavalent chromium in California from chromium plating and chromic acid anodizing facilities.

Based on staff’s survey of the chromium plating and chromic acid anodizing industry it appears data used to compile the 2006 Almanac emission inventory overestimated the hexavalent chromium emissions contributed by chromium plating and chromic acid anodizing facilities. In the 2006 Almanac, emissions from chromium plating and chromic acid anodizing facilities were estimated to be about 30 pounds. Since publication of the 2006 Almanac, updated emission inventory information has resulted in a revision of the earlier estimate of 30 pounds to about 4.5 pounds. We estimate, based on our survey, that in 2005 emissions from chromium plating and chromic acid anodizing facilities were about four pounds. These data are provided in Chapter V. Information from the survey, along with updated emissions estimates from local air districts and other sources, will be

used as the basis for emissions estimates in future Almanacs. Emission inventories are dynamic and are ‘snapshots’ in time. This reduction in hexavalent chromium plating and chromic acid anodizing facility emissions, that will be reflected in the next Almanac, will not appreciably reduce the total statewide stationary source estimated emissions.

3. Ambient Concentrations

Chromium compounds and hexavalent chromium are routinely monitored as part of the statewide ARB air toxics network. This monitoring meets U.S. EPA’s standards for ambient monitoring. It does not reflect near source exposures which may be significant. Trivalent chromium compounds are not specifically monitored, but are accounted for as a fraction of total chromium. The monitoring results indicate that hexavalent chromiumChapter II Page 16

concentrations have declined in recent years. The statewide mean concentration of hexavalent chromium has decreased from 0.27 nanograms per cubic meter (ng/m 3 ) in 1992 to 0.091 ng/m 3 in 2005. For hexavalent chromium ambient monitoring, the limit of detection has also decreased from 0.2 ng/m 3 in 1992 to 0.06 ng/m 3 in 2002. Therefore, the mean concentrations for 2002 and later are based on more precise measurements of ambient concentrations (ARB, 2006a).

Table II-1 shows the hexavalent chromium mean concentration at various monitoring sites in air districts with chromium plating and anodizing facilities (ARB, 2006b).

Table II-1

. Hexavalent Chromium Mean Concentration in Air Districts with Chromium Plating and Anodizing Facilities for the Year 2005

District ARB’s Air Toxics Network Monitoring Site Mean Concentration (ng/m 3 ) South Coast Air Quality Management District Azusa-803 Loren Ave. 0.08

Burbank – W. Palm Ave. 0.113 North Long Beach 0.10 San Diego County Air

Pollution Control District Chula Vista 0.038

El Cajon-Redwood

Avenue 0.048

Ventura County Air

Pollution Control District Simi Valley-Cochran

Street 0.05

Bay Area Air Quality Management District Fremont-Chapel Way 0.05

San Francisco-Arkansas

Street 0.11

San Joaquin Valley Air

Pollution Control District Fresno-1st Street 0.063

Stockton-Hazelton Street 0.12

Sacramento Metropolitan Air Quality Management District Roseville-N Sunrise Blvd 0.058

As shown in Table II-1, mean concentrations range from 0.038 to 0.12 ng/m 3 in 2005. These values would yield a range of estimated cancer risk of about 6 per million to 18 per million people exposed.

The mean concentrations may be overestimated. This is because prior to 2002 monitoring results below the limit of detection are assumed to be one-half the limit of detection or 0.1 ng/m 3 (ARB, 2006a). Our ambient monitoring data show that the percentage of measurements that were below the detection limits increased steadily over the years, reaching a peak of over 96 percent in 1999. Starting in 2002, analysis was performed on composite samples representative of one quarter. This lowered the detection limit to 0.06 ng/m 3 . Even with this lowering of the detection limit, the percentage of measurements below the detection limit has been steady at around 28 percent.Chapter II Page 17

Therefore, we conclude that ambient concentrations of hexavalent chromium are low and are not a general public health concern. From these ambient data we are also able to infer that the emissions from chromium plating and chromic acid anodizing facilities are a near source-concern. As further support, in the SCAQMD ambient monitoring mentioned earlier, concentrations measured downwind of 10 chromium plating and chromic acid anodizing facilities ranged from 0.03 ng/m 3 to 2.99 ng/m 3 , with an average of 0.44 ng/m 3
(SCAQMD, 2003a).

4. Indoor Sources and Concentrations

The extent of exposure to airborne hexavalent chromium in the indoor environment, other than in the workplace, is not known. There are no direct consumer uses of chromium that could lead to indoor emissions of hexavalent chromium compounds. During the emissions testing program conducted by the ARB, staff placed ambient air monitors inside the plating shops that were being source tested. Indoor levels of hexavalent chromium detected in the chromium plating facilities tested without forced ventilation systems in place ranged from four to 2,350 ng/m 3 . These data are qualitative and the numbers should not be used as indoor air concentration numbers. However, the numbers clearly indicate that hexavalent chromium is emitted from plating tanks, and is present as an airborne particle. These data are presented in Chapter V.

Environmental Tobacco Smoke is known to contain hexavalent chromium in the particulate matter components (ARB, 2005a) The Board identified environmental tobacco smoke as a TAC in January 2006.

5. Atmospheric Persistence

Atmospheric reactions of chromium compounds were characterized in field reaction studies and laboratory chamber tests. These results demonstrated an average experimental half-life of 13 hours (ARB, 1997). Based on this, one would expect there to be minimal amounts of hexavalent chromium in the dust found in and around the plating facilities. However, during ARB’s Barrio Logan study and later during a SDCAPCD study, indoor dust was collected at plating shops to determine if hexavalent chromium was present. Results of dust sample analyses indicated that hexavalent chromium was indeed present in the dust samples. Hexavalent chromium concentrations in samples collected near the plating tank ranged from 407 to 89,800 milligrams per kilogram. These results are summarized in Appendix G.

6. Particle Size of Hexavalent Chromium

The potential of hexavalent chromium to become airborne and disperse into ambient air is dependent on particle size. If the particles are large, they would likely not become airborne, or if they would become airborne they would rapidly deposit. Our indoor air data collected during the emissions testing program demonstrate that hexavalent chromium is present in ambient air inside the facilities. Our modeling analyses in Chapter VII are based on hexavalent chromium particles being small enough to behave as a gas such that they are emitted into ambient air. To verify this, we consulted the U.S. EPA’s AP 42Chapter II Page 18

document and found that generally hexavalent chromium particles are eight micrometers or smaller in diameter. Particles of this size are thought to behave as a gas (U.S. EPA, 1996). Thus, we conclude that the modeling analyses accurately predict how hexavalent chromium is dispersed into the outside ambient air.



### B. Health Impacts

Health Impacts of hexavalent chromium have been well documented. The ARB and U.S. EPA have identified hexavalent chromium as a TAC and HAP respectively. It is widely recognized as a potent human carcinogen with no known level of safe exposure. When hexavalent chromium was identified as a TAC, OEHHA developed a cancer potency value of 0.15 ( μ g/m 3 ) -1 that was approved by the SRP on TACs. This value means that a person’s chance of developing cancer due to exposure to 1 μg/m 3 of hexavalent chromium over a 70 year lifetime would be 146,000 chances per million people, almost 15 percent (ARB, 1985). Only one other identified TAC, dioxin, has been determined more likely to cause cancer than hexavalent chromium.

Unlike hexavalent chromium, trivalent chromium is not considered to be a human carcinogen (U.S. EPA, 2000). Results from a study published in 2000 documented that hexavalent chromium caused an increased incidence of lung cancer in a group of 2,357 workers at a chromate production plant. Cumulative hexavalent chromium exposure was associated with an increased lung cancer risk, while cumulative trivalent exposure was not (AJIM, 2000). The U.S. EPA published another report that distinguishes the health impacts of the two oxidation states of chromium. In that report, hexavalent chromium is described as a “Group A known human carcinogen,” while trivalent chromium “is much less toxic and is recognized as an essential element in the human diet.” Trivalent chromium is “a Group D Carcinogen, not classifiable as to carcinogenicity in humans” (U.S. EPA, 2000).

Trivalent chromium is also markedly less potent in causing other toxic effects. While some adverse effects on the lung, kidney, and reproductive system have been reported in animal studies, and in studies of humans occupationally exposed to trivalent chromium compounds, the doses required to produce these effects are high. These doses were generally at least ten times higher than those for corresponding effects of hexavalent chromium (ATSDR, 2000). Some of this difference is apparently due to the poor absorption of trivalent chromium from the lung or digestive system, and its much reduced ability (compared to hexavalent chromium) to move from extracellular body fluids into cells of potentially sensitive tissues.

While the chemistry and toxicology of hexavalent chromium and trivalent chromium are markedly different, trivalent chromium is not without toxic effects and still should be handled appropriately.Chapter II Page 19



### C. Barrio Logan: A Case Study of Near Source Impacts

1. Background

Findings from an air monitoring study conducted by ARB in the Barrio Logan communityin San Diego provide one important basis for our proposal. Barrio Logan is a residentialcommercial area with single-family homes and apartments located in close proximity to light industrial facilities, including two chromium plating businesses. Many of the families living near the chromium plating shops include children and the elderly. In addition to the plating shops, there are approximately twelve single family residences, a cabinet shop, a neighborhood youth center, and a community swimming pool.

In May 2001, the ARB began monitoring around the two chromium plating facilities. One facility was a hard chromium plating facility with add-on air pollution control devices, including a HEPA filter and forced ventilation system. The other facility was a decorative chromium plating shop with in-tank controls (chemical fume suppressant) and no forced ventilation system. The chromium plating facilities were close to multiple residences and a community youth center and the community was concerned about hexavalent chromium emissions from these facilities. Thus, the ARB staff designed a receptor-oriented sampling study focusing on airborne hexavalent chromium concentrations.

The monitoring study also allowed us to evaluate the effectiveness of the existing Chromium Plating ATCM in providing public health protection, especially in community settings where residences and sensitive receptors are in close proximity to emission

sources.

2. Air Monitoring

Air monitoring to determine hexavalent chromium ambient air concentrations began in May 2001 and continued periodically until May of 2002. Analysis of air samples, collected during monitoring from December 3 through December 17, 2001, found some unusually high hexavalent chromium levels (nine samples had results greater than 3.0 ng/m 3 ) in the immediate vicinity of the plating shops and residences. The average of all 24-hour ambient samples was 0.98 ng/m 3 (ARB, 2003). To put this in perspective, the statewide annual average hexavalent chromium concentration in 2005 is 0.091 ng/m 3 . The highest

24-hour ambient hexavalent chromium value recorded in ARB’s statewide toxics network was 22 ng/m 3 measured on February 20, 1995, in Burbank in the South Coast Air Basin. The next highest values statewide were 9.9 ng/m 3 in 1991 and 3.0 ng/m 3 in 1992.

Further sampling was conducted to identify the source or sources of the emissions and the specific activities leading to the high concentrations of hexavalent chromium found in December 2001. Follow-on sampling began on February 5 and ran daily through May 24, 2002, to identify the source of the emissions and to address the public health

concern associated with the ambient hexavalent chromium levels. In addition to air monitoring, we also conducted compliance inspections, dust and soil sampling, a source test, indoor air sampling at the plating shops, extensive area walks and inspections, and air dispersion modeling.Chapter II Page 20

3. Summary of Results and Findings

Analysis of samples implicated the decorative chromium plating operation as the source of the high ambient hexavalent chromium measurements. The data also showed that it was not only emissions from the daily plating process that were the cause of the high ambient hexavalent chromium readings. We also found that fugitive hexavalent chromium laden dust, that had accumulated within the shop was escaping through building openings and contributing to elevated outdoor hexavalent chromium concentrations (ARB, 2004).

This study was important to the evaluation of the Chromium Plating ATCM because

results indicated that:

• Hexavalent chromium emissions from decorative chromium plating facilities may be underestimated;

• Poor ‘housekeeping’ practices may lead to fugitive hexavalent chromium emissions;

• Hexavalent chromium emissions from chromium plating create a local impact, a “Hot Spot,” but the hexavalent chromium concentration drops off quickly; and

• Emissions from the HEPA controlled hard chromium plating facility were effectively reduced and not contributing to elevated levels of hexavalent chromium in the neighborhood.



### D. Proximity of Facilities to Sensitive Receptors

As part of our evaluation, we collected data to determine proximity of sensitive receptors to all chromium plating and chromic acid anodizing shops. We learned from the Barrio Logan study that the receptors nearest volume emission sources (source without add-on air pollution control) are most affected.

ARB staff worked with the air districts to obtain receptor information for all chromium plating and chromic acid anodizing facilities. In instances when data were not available, ARB staff visited facilities and determined the distance to the nearest sensitive receptor. We are proposing to define sensitive receptor as a residence including private homes, condominiums, apartments, and living quarters; education resources such as preschools and kindergarten through twelve (K-12) schools; daycare centers; and health care facilities such as hospitals or retirement and nursing homes. A sensitive receptor would include long term care hospitals, hospices, prisons, and dormitories or similar live-in housing.

Out of 222 hexavalent chromium plating and chromic acid anodizing facilities, 19 percent are located within 25 meters of a sensitive receptor. We also found that 96 facilities (43 percent) are located within 100 meters of a sensitive receptor. Air quality modeling results, found in Chapter VII, indicate that receptors located within 100 meters of aChapter II Page 21

chromium plating operation (volume source) may be exposed to significant levels of hexavalent chromium. The detailed data on proximity of sensitive receptors to chromium plating and chromic acid anodizing facilities are summarized in Chapter IV.

These data point to the need to further control hexavalent chromium emissions to protect near-source receptors, especially sensitive receptors such as children and the elderly.Chapter II Page 22



### REFERENCES

AJIM, 2000. American Journal of Industrial Medicine. HJ Gibb, PSJ Lees, PF Pinsky & BC Rooney. Lung Cancer Among Workers in Chromium Chemical Production. 38:115-

126. 2000.

ARB, 1985. Air Resources Board . “ Staff Report: Initial Statement of Reasons for Proposed Rulemaking – Public Hearing to Consider the Adoption of a Regulatory Amendment Identifying Hexavalent Chromium as a Toxic Air Contaminant”. 1985.

ARB, 1988a. Air Resources Board

. “Technical Support Document to Proposed

Hexavalent Chromium Control Plan” . 1988.

ARB, 1988b. Air Resources Board. “Staff Report: Initial Statement of Reasons for Proposed Rulemaking – Proposed Airborne Toxic Control Measure for Emissions of Hexavalent Chromium from Chrome Plating and Chromic Acid Anodizing Operations”.

1988.

ARB, 1989a. Air Resources Board

. “Proposed Hexavalent Chromium Control Measure For Cooling Towers”. 1989.

ARB, 1997. Air Resources Board

. “Toxic Air Contaminant Identification List – Summaries – Chromium and Compounds Hexavalent Chromium ” . 1997.

ARB, 2001a. Air Resources Board. “Airborne Toxic Control Measure For Emissions Of Hexavalent Chromium And Cadmium From Motor Vehicle And Mobile Equipment Coatings: Initial Statement Of Reasons For Proposed Rulemaking. Executive Summary/Staff Report ”. 2001.

ARB, 2003. Air Resources Board. “Ambient Monitoring for Hexavalent Chromium and Metals in Barrio Logan: May 2001 through May 2002”. 2003.

ARB, 2004a. Air Resources Board. “Staff Report: Initial Statement of Reasons for Proposed Rulemaking – Airborne Toxic Control Measure to Reduce Emissions of Hexavalent Chromium and Nickel from Thermal Spraying” . 2004.

ARB, 2004. Air Resources Board. “Barrio Logan Report: A Compilation of Air Quality Studies in Barrio Logan”. 2004.

ARB, 2005a. Air Resources Board. “Proposed Identification of Environmental Tobacco Smoke as a Toxic Air Contaminant: Executive Summary”. 2005.

ARB, 2006a. Air Resources Board. “The California Almanac of Emissions And Air Quality” . 2006 Edition.Chapter II Page 23

ARB, 2006b. Air Resources Board. Annual Statewide Toxics Summary-Hexavalent Chromium. 2006. (http://www.arb.ca.gov/adam/toxics/statepages/cr6state.html)

ATSDR, 2000. Agency for Toxic Substances and Disease Registry. “Toxicological

Profile for Chromium” . 2000.

SCAQMD, 2003a. South Coast Air Quality Management District. “Draft Staff Report - Proposed Amended Rule 1469-- Hexavalent Chromium Emissions from Chrome Plating and Chromic Acid Anodizing Operations and Proposed Rule 1426- Emissions from Metal Finishing Operations.” 2003

U.S. EPA, 1996. U.S. Environmental Protection Agency. “Emission Factor Documentation for AP-42 Section 12.20 – Electroplating – Final Report”. 1996.

U.S. EPA, 2000. U.S. Environmental Protection Agency, Office of Air Quality Planning and Standards, Research Triangle Park, NC. 453/R-99-007: “National Air Toxics Program: The Integrated Urban Strategy, Report to Congress”. 2000.Chapter III Page 24



## III. Public Outreach and Data Collection

P ublic participation is a key ingredient of ARB's regulatory process. Reliable data are also necessary to provide a sound basis for regulatory action. This Chapter summarizes our efforts to inform and involve all stakeholders in the regulatory process. We also

summarize our data collection efforts.



### A. Public Involvement

The full benefits of public participation are realized when all stakeholders are involved and informed, particularly those directly affected by a regulation. In addition, public outreach to low-income and ethnically diverse communities is an important tool for fulfilling ARB’s goal to provide equal environmental protection to all Californians. Thus, throughout the development of the proposed amendments to the ATCM, staff worked with the affected industry and public organizations to offer opportunities to: 1) become informed about the proposed changes to the ATCM and the public process; 2) provide pertinent information for ARB staff consideration; and 3) discuss comments and concerns.

Staff has used Internet web page http://www.arb.ca.gov/toxics/chrome/chrome.htm and electronic and mail-out notices to alert and invite organizations and individuals to workgroup meetings, public workshops, and to the public hearing at which these proposed changes to the ATCM will be considered. In addition, outreach efforts have included personal contacts via telephone, electronic mail, U.S. mail, surveys, facility visits, and meetings. The following stakeholders have been involved in the process:

• Chromium plating and chromic acid anodizing facility owners and operators;

• Metal finishing industry associations;

• Chemical suppliers;

• Control equipment manufacturers;

• Representatives from federal agencies, including the U.S. EPA and OSHA;

• Representatives from State agencies, including the Department of Toxic Substance Control (DTSC), the Water Resources Control Board, and the Business, Transportation, and Housing Agency;

• Representatives from California Air Pollution Control and Air Quality Management Districts;

• Environmental and community groups; and

• Representatives from pollution prevention and public health advocate organizations.

Stakeholders were initially made aware of ARB’s intention to evaluate the current ATCM in January 2002 when stakeholder workgroups meetings were held in Diamond Bar, Fresno, and San Francisco, California. Over the course of the evaluation of the industry, the emissions testing program, and regulatory concept development, stakeholders were given the opportunity to participate and comment. A summary of outreach activities is

shown below:Chapter III Page 25

• Forming a District Workgroup and conducting meetings and conference calls;

• Forming a Stakeholder Workgroup and conducting meetings throughout the state;

• Creating the Hexavalent Chromium mailing list, activity website and maintaining a List-Serve to update interested parties;

• Conducting site visits in various districts to familiarize ARB staff with chromium plating and chromic acid anodizing processes and to select facilities for the emissions testing program;

• Preparing and disseminating a fact sheet on chromium plating and chromic acid anodizing operations for community outreach meetings;

• Participating in the SCAQMD negotiated rulemaking process;

• Conducting surveys on industry throughput levels and economics by mail, facsimile and telephone;

• Conducting a survey of chemical fume suppressant manufacturers;

• Developing a compliance assistance compact disk;

• Mailing workshop notices and posting workgroup materials on ARB’s website; and

• Conducting public workshops in various locations within the State.

Staff held numerous meetings with affected industry and the public. A chronology of meetings is compiled in Appendix B of this report. In addition as specified in Health and Safety Code 39665(c), relevant comments on the ATCM received by ARB on the proposed amendments to the ATCM have been included in the administrative record. They are listed as a reference at the end of this Chapter (ATCM comments) and are available from ARB staff upon request for public review and comment.



### B. Data Collection Tools

ARB staff gathered information by conducting surveys of air districts, chromium plating and chromic acid anodizing operations, and chemical fume suppressant manufacturers. A brief summary of the types of information collected is summarized below.

1. Air District Survey

Chromium plating and chromic acid anodizing operations are located in eight air districts. Because air districts implement the ATCM, ARB staff worked with them throughout the evaluation process to gather information on chromium plating and chromic acid anodizing facilities. To characterize the industry, ARB staff requested permit information, ongoing compliance reports, source test results, and available risk assessment information for active chromium plating and chromic acid anodizing operations. These data were used to form an initial mailing list and preliminary emission estimates. To gather more information, ARB staff conducted facility surveys and a receptor survey.Chapter III Page 26

2. Chromium Plating and Chromic Acid Anodizing Facility Survey

The first step in evaluating the existing ATCM was to characterize the facilities in California. A letter dated April 12, 2004, was sent to each facility informing them of ARB's effort to re-evaluate the Chromium Plating ATCM and included a brief questionnaire related to calendar year 2003. The list of questions included type of operation, annual throughput in ampere-hours, type of in-tank and add-on controls, manual or hoist lines, grinding and polishing operations, and questions on storage of chemicals. To collect the information on the questionnaire, ARB staff contacted all facilities by telephone. The results of the survey were used to characterize the industry (see Chapter IV) and assess technological feasibility (see Chapter VI). The survey is included as Appendix C to this
report.

3. Chemical Fume Suppressant Manufacturers Survey

The ARB staff also conducted a survey of chemical fume suppressant manufacturers to gather information on chemical fume suppressants and recommendations on optimum tank conditions for efficient plating. The survey requested information on fume suppressant formulations, the primary mechanism of reducing hexavalent chromium emissions, and recommended surface tension. We also collected information on recommended tank contaminant levels to determine when bath clean-up was recommended, such that decorative chromium plating baths would operate most efficiently. The survey information is summarized in Chapter IV. The survey is included as Appendix D to this report.

4. Economic Questionnaire

The ARB is required by law to assess the economic impact of regulations on the affected industry. To assist with this requirement, ARB staff contacted the facilities by mail in February 2005. The letter included a brief economic questionnaire to collect financial information for calendar year 2003. Businesses were then contacted by telephone to complete the questionnaire. These data are summarized in Chapter IV. The questionnaire is included as Appendix E to this report.Chapter III Page 27



### REFERENCES

ATCM Comments. Comment letters received by ARB on the proposed amendments to the Chromium Plating ATCM.Chapter IV Page 28



## IV. Chromium Plating and Chromic Acid Anodizing

O perations

A RB has regulated chromium plating and chromic acid anodizing facilities since 1988. In this Chapter, we provide a brief summary describing the processes. A detailed review of the source category can be found in the original staff report (ARB, 1988b). As part of our evaluation of the effectiveness of the existing ATCM, staff conducted two facility surveys. This Chapter also summarizes the results of these surveys by providing an overview of chromium plating and chromic acid anodizing facilities in California in 2003. One goal of the proposed amendments is to further reduce hexavalent chromium emissions and exposure; therefore, this Chapter primarily describes information on hexavalent chromium plating and chromic acid anodizing operations.



### A. Overview

Electroplating is a chemical or electrochemical process of surface treatment. A metallic layer is deposited onto a base material. In the chromium plating process, an electrical charge is applied to a plating bath containing an electrolytic salt (chromium anhydride) solution. The electrical charge causes the chromium metal in the bath to fall out of solution and deposit onto various objects (usually metallic) placed into the plating bath. In an anodizing process, an oxide film is formed on the surface of the part.

The hexavalent chromium plating process is only about 20 percent efficient. This inefficiency leads to excess generation of hydrogen and oxygen bubbles as electrical current is applied to the plating bath. The bubbles rise through the tank and burst at the surface, leading to emissions of hexavalent chromium. Facilities using trivalent chromium baths emit trivalent chromium in the process. Once emitted from the facility, hexavalent chromium can be inhaled and entrained in the lungs. In a similar manner hexavalent chromium mist is generated during chromic acid anodizing. Thus, hexavalent chromium emissions have the potential to adversely impact public health on a statewide basis, as well as at the local community level. A schematic diagram of a plating tank is shown in Figure IV-1.Chapter IV Page 29

Figure IV-1 . Main Components of an Electroplating Tank

From OHCOW, 1997

As shown in Figure IV-1, the part to be plated becomes the cathode in the circuit. In chromic acid anodizing, the part to be oxidized serves as the anode in the circuit.



### B. Types of Chromium Operations

As mentioned above, facilities use either trivalent or hexavalent chromium baths. However, the trivalent chromium plating process is only available for decorative chromium plating applications. Facilities using hexavalent chromium baths can be divided into three types. These include hard chromium (or functional chromium) plating operations, decorative chromium plating operations, and chromic acid anodizing operations. Decorative plating includes black chromium plating which is selected both for its functional and decorative properties. It has a dull dark gray, or black finish when polished. It has numerous applications and can be used in military, aerospace, automotive or other applications. It is a semi hard, non-reflective, abrasion resistant, heat and corrosion resistant coating.

The same hexavalent chromium bath chemistry can be used for both hard and decorative chromium plating. Table IV-1 provides a summary of the three processes. Source: Burgess WA Recognitions of Health Hazards in Industry – A

Review of Materials &
Processes, 2 nd edition John Wiley & Sons Inc., 1995 (CATHODE)Chapter IV Page 30

Table IV-1 . Description of Hexavalent Chromium Operations

HARD CHROMIUM

PLATING DECORATIVE

CHROMIUM

PLATING CHROMIC ACID

ANODIZING

Type of layer Thick layer (2.5 μm –

760 μm) Thin layer

0.003 μm-2.5 μm Electrochemical

conversion

Properties provided Corrosion protection,

wear resistance, lubricity and oil retention among other properties A decorative and protective finish Corrosion and

abrasion resistant surface by forming an oxide coating

Type of parts Engine parts,

industrial machinery,

and tools Bath fixtures, faucets, automotive bumpers and wheels, furniture
components, motorcycle parts Architectural applications, landing gears, giftware and novelties,

automotive trim and bumpers

Plating duration Hours or days Seconds or minutes <1 – 5 minutes

Substrate Typically plated on

steel Typically plated on

Nickel Aluminum

The most familiar type of chromium plating is decorative chromium plating which provides a bright, and shiny finish on objects such as faucets and wheels. Generally, the base material has been nickel-plated prior to plating the chromium.



### C. Data Resources

To characterize the industry, ARB staff contacted all air districts with active chromium plating and chromic acid anodizing facilities. These operations are under permits to operate issued by air districts and must comply with applicable district rules or the Chromium Plating ATCM. Together with the air districts and utilizing other data sources, a list of 355 potential operations was developed. A letter was sent to these 355 facilities informing them of ARB’s intent to review the ATCM, and requesting them to provide basic information about their business. Each facility was contacted by telephone to complete the questionnaire. From this survey, 222 active hexavalent chromium plating and chromic acid anodizing facilities and ten trivalent chromium plating operations were identified. Of the ten trivalent chromium operations, six facilities only plate using the trivalent chromium process, while the other four operations are part of a business that also conducts hexavalent chromium plating. ARB staff also conducted an economic survey to gather employee and economic information. Data on proximity of plating shops to receptors was also gathered with the assistance of the air districts. A summary of the data collected from our surveys is provided in the following sections.Chapter IV Page 31



### D. Industry Characterization

The following sections provide information collected from our calendar year 2003 industry survey. Note that a distinction is made between number of facilities and number of operations. This is necessary because some facilities perform multiple operations. For example, one facility may conduct chromic acid anodizing as well as hard chromium plating.

1. Location and Number of Plating and Anodizing Facilities

ARB staff determined that in 2003 there were 228 combined trivalent and hexavalent chromium plating and chromic acid anodizing facilities in California. Several of these facilities perform multiple operations using hexavalent chromium (230 operations) and trivalent chromium (10 operations). Four hexavalent chromium plating facilities also conduct trivalent chromium plating. There are six facilities that only conduct trivalent chromium plating. Most of this Chapter will focus on the 222 hexavalent chromium plating and chromic acid anodizing facilities. The facility list was verified by air districts. Therefore, we believe that the industry is fully represented. Information collected included: facility location; type of operation; total throughput; add-on air pollution control equipment; in-tank controls; source test information; type of plating line; and grinding and polishing activity information. In the following graphs, note the distinction between facility and operation as we characterize the industry.

Out of 240 operations, the majority are in located in the SCAQMD. Figure IV-2 below depicts the plating and anodizing operations by air district. Other air districts include Shasta, Sacramento, Ventura, and Feather River.

Figure IV-2 . Distribution of Chromium Operations by District (2003)

BAAQMD

9%

SCAQMD

75% SJVAPCD

7% OTHER

9%Chapter IV Page 32

Out of 240 operations, 230 are hexavalent chromium plating or anodizing operations and ten are trivalent chromium plating operations. Table IV-2 below summarizes all active facilities by operation type. Note that there were 228 active chromium plating and chromic acid anodizing facilities in California in 2003 and twelve of them perform multiple operations.

Table IV-2

. Number of Operations by Plating Type

Hexavalent Chromium Baths Hard (Functional) Chromium Plating 58 Decorative Chromium Plating 127 Chromic Acid Anodizing 45

Trivalent Chromium Baths Trivalent Chromium Plating 10

TOTAL 240

Figure IV-3 below shows that of the 222 active hexavalent chromium facilities, 55 percent of them perform decorative chromium plating, 25 percent perform hard (functional) chromium plating, and 20 percent conduct chromic acid anodizing.

Figure IV-3 . Distribution of Hexavalent Chromium Operations by Type (2003)

Emissions of hexavalent chromium from plating and anodizing operations depend on total throughput in ampere-hours. An ampere-hour is a unit of amperes integrated over time. It is an important variable because it determines the amount of hexavalent chromium emissions from a facility. The ampere-hours are multiplied by the emission rate (milligrams/ampere-hour) to calculate emissions. This is discussed later in Chapter V on emissions. Table IV-3 provides a summary of throughput ranges and averages by plating type. Data were not available for two operations, therefore, the numbers in Tables IV-2 and IV-3 differ slightly. Hard

25%

Anodizing

20% Decorative

55%Chapter IV Page 33

Table IV-3 . Hexavalent Chromium Plating Type and Ampere-hours (2003) Hard Decorative Anodizing



### Number of operations 57 126 45



### Range of Amperehours 1,200 –
79,000,000 120 –

82,900,000 260 – 2,000,000

Average (Mean) Amperehours 12,500 1,700,000 150,000

Median Ampere-hours 2,900,000 95,000 43,000 *Unknown throughput information for 2 plating or anodizing operations

Although the ranges appear similar for hard and decorative plating, generally amperehours from hard chromium plating operations are much higher than those from decorative chromium plating. This can be seen by comparing the mean and median ampere-hours shown in Table IV-3. The higher throughput levels, in ampere-hours, that are shown for hard chromium plating are related to the length of time required to build the thick chromium layer typical of hard chromium plating.

In terms of throughput, many chromium plating and chromic acid anodizing facilities are small operations. Figure IV-4 shows the level of throughput, in ampere-hours for the various operations.

Figure IV-4 . Throughput (in Ampere-hours) for Chromium Plating and Chromic Acid Anodizing Facilities in California (2003)

48 60

45

34

15 18

0 10 20 30 40 50 60 70Number of Facilities

< 2 0 , 00 0

20 , 000 - 200 , 0 0 0

2 00 , 0 00 - 1 M i l l i on

1 - 5 M i l l i on

5 - 15 M i l l i on

> 15 M i l l i onChapter IV Page 34

As shown in Figure IV-4, 48 (about 20 percent) facilities have annual throughput of 20,000 annual ampere-hours or less. Sixty facilities (27 percent) have throughput of between 20,000 to 200,000 annual ampere-hours. Over 50 percent of facilities have annual ampere-hours over 200,000.

2. Control Equipment

All chromium plating and chromic acid anodizing facilities already use a variety of controls to comply with the existing ATCM. Emissions control can be achieved through using add-on air pollution controls, such as filter systems, or in-tank controls, primarily chemical fume suppressants that reduce surface tension. The staff collected information on the types of emission controls in use based on visits to many plating and anodizing operations, and through the survey. The following section provides information on controls currently being used by the chromium plating and chromic acid anodizing industry. A description of these control types is provided in Chapter VI.

To comply with the existing ATCM, hard chromium plating facilities must use add-on airpollution control devices to meet emission limitations expressed in milligrams/amperehour (an alternative to meet a surface tension limit is provided for hard chromium plating facilities with less than 500,000 ampere-hours). Decorative plating and chromic acid anodizing facilities have the option of complying with an emission limit expressed in milligrams/dry standard cubic meter of air (mg/dscm) or meeting a surface tension requirement using a chemical fume suppressant with a wetting agent. Most have chosen the latter means of complying. Many facilities use a combination of controls to reduce emissions. Figure IV-5 shows distribution of current control options in use at the

hexavalent chromium facilities in California.

Figure IV-5 . Distribution of Emission Controls by Type of Chromium Operation

* Note no information about 2 operations that have shut down since 2003 10 4 6 38 34

21

9 88

18

0 10 20 30 40 50 60 70 80 90 100Number of Operations

A dd-On Only A dd-On + In tank

C o ntro ls In tank co ntro ls Only Hard Decorative AnodizingChapter IV Page 35

As shown in Figure IV-5, in 2003, there are 113 operations controlling hexavalent chromium emissions with add-on air pollution control devices. Of facilities with add-on air pollution controls, 69 operations (14 chromic acid anodizing, 26 decorative chromium, and 29 hard chromium plating facilities), or 61 percent, had HEPA filters as their final control. Our survey also gathered source test emission rate information for facilities. Out of 113 operations with add-on air pollution control device(s), source test information was available for 71 (63 percent) of the operations.

Figure IV-5 also shows that the majority of operations used chemical fume suppressants as the sole source of emission control. As shown, 88 operations, or almost 70 percent of decorative chromium plating operations used chemical fume suppressants to control hexavalent chromium emissions. Note also that there are several hard chromium plating facilities using chemical fume suppressants. These are operations with throughput below 500,000 ampere-hours per year.

3. Housekeeping

Because of information gleaned from our Barrio Logan study, we also gathered information on grinding and polishing operations within facilities, and whether the plating line was automatic or manual. We are interested in this information because operations with grinding and polishing activities generate dust, which could act as a sink for hexavalent chromium mist being emitted from the plating or anodizing tank. Once disturbed by activities of the workers or ventilation within the operation, the dust can be re-entrained leading to fugitive emissions of hexavalent chromium.

Through the survey, we found 145 facilities that performed grinding polishing or buffing

on site and 72 that did not. No information was available for five facilities.

The manner in which parts are processed, particularly for decorative plating, also could lead to hexavalent chromium emissions as droplets of liquid from the plating tank may fall to the floor surrounding the tank. Again, this could lead to dust and fugitive emissions of hexavalent chromium. Automatic lines generally have tanks set up in a row but manual lines may not. We found that were 186 facilities with manual lines, 30 with automatic lines, and 3 facilities that had both manual and automatic lines. No information was

available for 4 facilities.

4. Sensitive Receptor Distances

As we found in Barrio Logan, the impacts of hexavalent chromium emissions are highly localized. While ambient hexavalent chromium emissions may be low, emissions of hexavalent chromium from plating and anodizing could pose significant exposures to receptors living near the source. Therefore, to assess potential adverse impacts to near source receptors, with assistance from the air districts, ARB staff determined the distances to the nearest sensitive receptors for all facilities. Figure IV-6 provides distances, in meters, from the source to the nearest sensitive receptor for all hexavalent chromium facilities by type of operation. The receptors include: any residence including private homes, condominiums, apartments, and living quarters; education resources suchChapter IV Page 36

as preschools and kindergarten through grade twelve (K-12) schools; daycare centers; and health care facilities such as hospitals, retirement and nursing homes, long term care hospitals, hospices, prisons, and dormitories or similar live-in housing.

Figure IV-6 . Distance (in Meters) Between Hexavalent Chromium Facilities and the Nearest Sensitive Receptor

43

26 27 126

0 20 40 60 80 100 120 140Number of Facilities

<25 >25 <50 >50 <100 >100

Distance to Receptor (meters)

As shown in Figure IV-6, and as stated previously, 96 hexavalent chromium facilities are located within 100 meters of a sensitive receptor. This represents 43 percent of the facilities. Of these, 76 are decorative chromium plating and chromic acid anodizing facilities that generally control emissions with chemical fume suppressants. Figure IV-6 also shows that 43 of these facilities are located within 25 meters of a sensitive receptor.

5. Economic Survey

To characterize the industry financially, ARB staff contacted active facilities in February 2005 to obtain economic information. These data for the 2003 calendar year are summarized here and will be used to determine the economic impacts of the proposed amendments on chromium plating and chromic acid anodizing facilities. The financial information obtained is shown in Figure IV-7.Chapter IV Page 37

Figure IV-7 . Gross Annual Revenue for Hexavalent Chromium Plating and Anodizing Facilities (2003)

As shown in Figure IV-7, out of 222 hexavalent chromium facilities, we found that one third had gross annual revenue of less than $1,000,000, while another third had revenues between $1,000,000 to $5,000,000. About 20 percent have annual revenue over $5,000,000. No information was received from 14 percent of the facilities.

Table IV-4 provides data on the number of people employed by various plating and anodizing businesses.

Table IV-4 . Number of Employees at Chromium Plating and Chromic Acid

Anodizing Facilities

Employee Number Range Number of

Facilities

1 – 10 60

11 – 25 46

26 – 100 61

>101 24

No information 31

As shown in Table IV-4, 25 percent (60 facilities) employ ten or fewer people. Seventyfive percent of facilities have less than 100 employees. < $1,000,000

33% No Information

14%

$1,000,000 -
$5,000,000

34% $5,000,000 -
$10,000,000

7% > $10,000,000

12%Chapter IV Page 38



### REFERENCES

ARB, 1988b. Air Resources Board. “Staff Report; Initial Statement of Reasons for Proposed Rulemaking – Proposed Airborne Toxic Control Measure for Emissions of Hexavalent Chromium from Chrome Plating and Chromic Acid Anodizing Operations”

. 1988.

OHCOW, 1997. Occupational Health Clinics for Ontario Workers Inc. “Electroplating – A Focus on Chrome Plating”. 1997Chapter V Page 39



## V. Emissions

T his Chapter presents a summary of our decorative chromium plating emissions testing program to investigate and, if needed, improve the emission factor for chemical fume suppressant controlled decorative plating facilities. Based on the emission factor developed through the testing program, this Chapter also includes 2003 estimated statewide emissions of hexavalent chromium from chromium plating and chromic acid anodizing facilities in California. As background, information on existing hexavalent

chromium emission factors is also included.



### A. Overview

One goal of characterizing the industry and estimating hexavalent chromium emissions was to assess the potential for significant near-source residual cancer risk resulting from chromium plating and chromic acid anodizing. The remaining risk, if any, would be from facilities already complying with the Chromium Plating ATCM and air districts rules. During our evaluation, it became clear that a better understanding of emissions occurring from decorative chromium plating was necessary. To comply with the ATCM, most decorative chromium plating facilities have used chemical fume suppressants to reduce the bath surface tension. Reducing the surface tension reduces misting and, therefore, hexavalent chromium emissions. However, the overall effectiveness of chemical fume suppressants to reduce emissions was not well quantified. Therefore, ARB staff undertook an emissions testing program to quantify hexavalent chromium emissions from decorative chromium plating facilities using chemical fume suppressants.



### B. Emission Factor Background

ARB staff, in 1988, established for hexavalent chromium plating and chromic acid anodizing operations uncontrolled and controlled hexavalent chromium emission factors (ARB, 1988b). These factors were based on source tests available at the time. For hard chromium plating and chromic acid anodizing facilities, an uncontrolled emission factor of 5.2 milligrams/ampere-hour was established. Based on available data, an uncontrolled emission factor of 0.5 milligrams/ampere-hour was established for decorative chromium plating facilities. ‘Controlled’ emission factors were then developed based on efficiencies reported for various control methods. For example, at the time, chemical fume suppressants were thought to be 95 percent effective. Therefore, the controlled hexavalent chromium emission factor was believed to be 0.025 milligrams/ampere-hour, based on uncontrolled decorative chromium emissions of 0.5 milligrams/ampere-hour. Likewise, an emission factor of 0.006 milligrams/ampere-hour for hard chromium plating facilities was based on 99.8 percent control from an uncontrolled hard chromium plating emission factor of 5.2 milligrams/ampere-hour.

Controlled emissions for hard chromium plating operations have since been measured directly through source testing emissions downstream of add-on air pollution control devices. However, quantifying controlled emissions from decorative plating operations has been more difficult because most facilities do not have add-on air pollution control devices. To better assess residual health risk from decorative chromium plating facilities,Chapter V Page 40

improved information on emissions from tanks controlled with chemical fume suppressants was necessary. To that end, ARB undertook an emissions testing program.

In other developments, the SCAQMD also tested effectiveness of chemical fume suppressants to control hexavalent chromium emissions. (SCAQMD, 2004) From their testing, a list of chemical fume suppressant products was developed that under specified conditions, would result in emissions of no more than 0.01 milligrams/ampere-hour. The list of SCAQMD certified chemical fume suppressants can be found on the air district website at: http://www.aqmd.gov/prdas/chrome%20plating/chromeplating.htm

A summary of controlled and uncontrolled emission factors for decorative plating tanks that existed prior to our testing program is provided in Table V-1 below.

Table V-1 . Decorative Chromium Plating Emission Factors in Existence Prior to ARB Testing Program (milligrams/ampere-hour)

ARB

(1988) U.S. EPA

(1996) SCAQMD

(2003)

Uncontrolled 0.5 2.14 4.4

Controlled with foam or foam plus

scrubber 0.025

-- --

Controlled with chemical fume
suppressants 0.025 0.008

--

Controlled with certified chemical fume
suppressants -- -- 0.01

Controlled with HEPA filter 0.0015

In reviewing the data in Table V-1, it becomes clear that residual cancer risk would vary widely based on the emission factor chosen.



### C. Emissions Testing Program

1. Overview

During our Barrio Logan study unexpectedly high concentrations of hexavalent chromium were measured outside a decorative chromium plating facility in San Diego (refer to Chapter II). These concentrations were higher than would have been predicted based on ARB’s decorative chromium plating emission factor. In light of these findings, we conducted an emissions testing program at decorative chromium plating businesses to gather emissions information. The testing was conducted in two phases in consultation with the chromium plating industry and the air districts. Each test consists of three test runs. These individual runs are averaged to determine an emission rate. A summary ofChapter V Page 41

both phases and testing result summary tables are provided in the sections below. Appendix F contains further data on each test conducted.

2. Phase I

During Phase I of the testing program, ARB staff conducted four source tests at three decorative chromium plating facilities. These facilities had forced ventilation systems and were using a variety of controls which included chemical fume suppressants. All of these tests measured emissions after in-tank controls (chemical fume suppressants) alone. These in-tank control test results ranged from 0.0017 to 0.810 milligrams/ampere-hour, with an average of 0.21 milligrams/ampere-hour. After evaluating these data, staff determined that the presence of forced ventilation systems may have led to higher emission rates than would be representative of the overall decorative chromium plating industry. Table V-2 presents results of the Phase 1 testing.

Table V-2 . Average Hexavalent Chromium Emission Rates and Selected Testing

Parameters for Phase 1

Test Number 1 2* 2* 3 4

Date 1/2003 1/2003 1/2003 3/2003 4/2003

Mean Hexavalent Chromium

Emission Rate (milligrams/ampere-hour) 0.19 0.28 0.003 0.003 0.159

SurfaceTension* (dynes/centimeter) 35.5 38.5 38.5 33.2 32.7

Chemical Fume Suppressant CR

1700® CR

1700® CR

1700® Fumetrol

140® Dis Mist NP®

Other Controls None None Composite

Mesh Pad Polyballs None

Chromic Acid Concentration (ounce/gallon) 33.8 33.2 33.2 44.7 21.4

* Same test, emissions collected before and after the composite mesh pad.

These data were not used to develop an emission factor. However, we did find that, even though emissions off the tank varied widely, emissions after an add-on air pollution control device were consistently low. In one test we measured hexavalent chromium emissions before and after an add-on air pollution control device, a composite mesh pad system. The samples collected before the composite mesh pad system would be representative of a tank controlled with chemical fume suppressants. In this test, although the emission rate results collected before the composite mesh pad system varied for each of three test runs (0.0017 to 0.810 milligrams/ampere-hour), the emission rates measured after the composite mesh pad were consistent. Emission results rangedfrom 0.002 to 0.003 milligrams ampere-hour with an average of 0.003 milligrams/amperehour. These results provide evidence that add-on air pollution control devices provide aChapter V Page 42

consistent level of control regardless of operating parameters. In another test, use of polyballs and chemical fume suppressant yielded an emission rate of0.003 milligrams/ampere-hour. This test result indicates that polyballs combined with intank controls provides emission reduction benefits over that achieved with chemical fume suppressants alone.

From these tests, we also evaluated differences in surface tension readings based on two types of instruments: a stalagmometer and a tensiometer. There was a difference observed between measurements with the two instruments. While all stalagmometer surface tension readings were higher than the tensiometer readings, no uniform difference was seen ( i.e. they did not consistently vary by the same amount of dynes/centimeter). In developing the proposed amendments to the Chromium Plating NESHAP, U.S. EPA determined that measurements between the two instruments varied consistently by ten dynes/centimeter. Our testing did not confirm this.

We also learned that the emission rates from decorative chromium plating tanks were similar to those of hard chromium plating facilities with similar controls. We believe this indicates that uncontrolled emissions from decorative plating facilities were underestimated during the development of the original ATCM. This finding supports the proposal to have similar emission limits for all plating types.

3. Phase II

During Phase II of the testing program, ARB staff measured hexavalent chromium emissions at facilities with open tanks ( i.e. , they do not have forced ventilation systems). These facilities all reduced hexavalent chromium emissions using chemical fume suppressants as the sole control source. These facilities are more representative of the decorative plating industry. Seven source tests were conducted at three facilities. To facilitate testing, ARB staff designed a temporary hood to capture emissions. The temporary hood set-up is shown in Figure V-1.Chapter V Page 43

Figure V-1 . Temporary ‘Hood’ for Capturing Hexavalent Chromium Emissions at

Decorative Chromium Plating Facilities

T he results of the first six tests were used to assess existing hexavalent chromium emissions from various decorative chromium plating tanks without forced ventilation. These tanks were all controlled with various chemical fume suppressants. The mean emission rate from these tests is representative of emissions existing prior to implementation of Rule 1469 in the SCAQMD. Table V-3 provides results for each of the

first six tests. TEMPORARY

HOOD DUCTChapter V Page 44

Table V-3 . Average Hexavalent Chromium Emission Rates and Selected Testing

Parameters for Phase II

Test Number 1 2 3 4 5 6

Date 1/2004 2/2004 5/2004 10/2004 5/2005 6/2005

Mean Hexavalent Chromium

Emission Rate (milligrams/ampere-hour) 0.009 0.004 0.050 0.050 0.052 0.065

SurfaceTension* (dynes/centimeter) 39.9 29.5 36.8 42 30.1 31.5

Chemical Fume Suppressant Protab

1000® Clepo

Mist® Protab

1000® Chrome

Foam® Chrome

Foam® Chrome

Foam®

Chromic Acid Concentration (ounce/gallon) 36 34.7 33.4 30.2 25 28.2

* Surface tension was determined using a stalagmometer

For consistency, several variables remained as constant as practicable for the six tests shown in Table V-3. [The seventh test was done to verify the results of the SCAQMD fume suppressant certification program. The results of this test will be discussed separately.] The plating tanks were of similar size, the ampere-hours per test were consistent, and the same number and types of parts were plated each time. More details on each of these six tests are included in Appendix F. In addition to evaluating the effectiveness of different chemical fume suppressants to control hexavalent chromium emissions, we also monitored several other parameters to determine the effect, if any, on hexavalent chromium emissions. A brief description of our findings is provided below.

a. Hexavalent Chromium Emission Factor for Chemical Fume Suppressant Controlled Plating Tanks Derived from the Emissions Testing Program

Using the results from the six tests shown in Table V-3, a hexavalent chromium emission factor was developed to quantify the emissions from chromium plating and chromic acid anodizing operations using chemical fume suppressants as the sole source of control. These data are representative of ‘real world’ conditions. The emission rates from six tests ranged from 0.004 to 0.065 milligrams/ampere-hour, with an average of 0.04 milligrams/ampere-hour. For establishing the 2003 statewide hexavalent chromium emissions, this average emission rate, 0.04 milligrams/ampere-hour, was used.

b. Assessing Chemical Fume Suppressants to be Used for Compliance with

the ATCM

Concurrent with our testing program, the SCAQMD tested chemical fume suppressants under controlled conditions. The purpose of this testing was to determine parameters that yielded optimum emission reductions. The SCAQMD demonstrated that hexavalent emissions can be further reduced if certain chemical fume suppressants are used. In fact, the SCAQMD demonstrated that several chemical fume suppressants could reduce emissions of hexavalent chromium to no more than 0.01 milligrams/ampere-hourChapter V Page 45

(SCAQMD, 2004a). The surface tension at which this emission rate is achieved is at lower surface tension than currently required in the ATCM.

Our first six tests were used to estimate emissions based on how facilities normally operate using chemical fume suppressants. Test seven was designed to verify the SCAQMD results. The seventh test was conducted using the chemical fume suppressant, Fumetrol 140®. This chemical fume suppressant was certified by the
SCAQMD to reduce hexavalent chromium emissions to no more than 0.01 milligrams/ampere-hour when surface tension is maintained below 40 dynes/centimeter.

The results of the this test yielded an average emission rate of 0.009 milligrams/amperehour. This emission rate was achieved when surface tension was maintained at 35 dynes/centimeter, just below the level of SCAQMD certification. ARB was able to confirm results of the SCAQMD fume suppressant certification program. Based on this test result, as well as an evaluation of the SCAQMD source test data from their chemical fume suppressant certification program, ARB staff determined the chemical fume suppressants that would reduce emissions of hexavalent chromium to no more than 0.01 milligrams/ampere-hour at specified surface tensions. (SCAQMD, 2004a) Table V-4 lists these chemical fume suppressants with the surface tension at which the emission rate of 0.01 milligrams/ampere-hour is achievable.

Table V-4 . Chemical Fume Suppressants Approved for Use at Specified Surface

Tensions

Chemical Fume Suppressant and

Manufacturer Stalagmometer Measured Surface Tension (dynes/cm) Tensiometer Measured

Surface Tension (dynes/cm)

Benchbrite CR 1800®

Benchmark Products <40 <35 Clepo Chrome®

MacDermid <40 <35

Fumetrol 140®

Atotech U.S.A. <40 <35

Note that Table V-4 does not list all chemical fume suppressants certified by the SCAQMD. The chemical fume suppressants that employ a foaming mechanism for reducing emissions are not included on this list. This foaming component is critical to the effectiveness of the chemical fume suppressant. Most of the chromium plating facilities that will use these chemical fume suppressants as sole source of control are decorative chromium plating facilities. Many of these facilities do not operate in a manner that would allow the foam blanket to form and be maintained on the surface of the plating bath. In instances when the foam blanket is not maintained, emissions are likely higher than 0.01 milligrams/ampere-hour.

Through the emissions testing program and data obtained in the SCAQMD certification program, staff has developed two emission factors for hexavalent chromium plating tanks using chemical fume suppressants. The emission factor of 0.04 milligrams/ampere-hourChapter V Page 46

is developed for all tanks using chemical fume suppressants prior to 2005. The second emission rate of 0.01 milligrams/ampere-hour for chemical fume suppressant controlled facilities is used to evaluate the SCAQMD facilities in the 2005 baseline year, while the emission rate of 0.04 milligrams/ampere-hour is used for facilities in other parts of the State. Finally, to determine the benefits of adoption of the ARB staff’s proposal, estimated cancer risk and emissions from facilities using chemical fume suppressants asthe sole control will be calculated based on an emission factor of 0.01 milligrams/amperehour.

c. Effect of Surface Tension on Emission Rate

The requirement in the ATCM for controlling hexavalent chromium emissions with chemical fume suppressants specifies that surface tension is to be maintained below 45 dynes/centimeter. Hexavalent chromium emissions are lowered as surface tension is reduced. Therefore, part of our testing program was to determine if reducing surface tension further resulted in decreased emission rates. For tests one and two, we

evaluated the effect of reduced surface tension on emissions. The emission rates presented in Table V-3 are the averages of three test runs. As shown, the mean emission rate for test one, run at a surface tension of ~ 40 dynes/centimeter, was 0.009 milligrams/ampere-hour, while for test two, run at a surface tension of ~ 30 dynes/centimeter, the mean was 0.004 milligrams/ampere-hour. While the average emission rate for test two is lower, as determined by the statistical t-Test, at a significance

level where α =0.05, the means, and therefore the emission rates, are not different.

Interestingly, the emission rates for tests five and six, conducted at the same facility with the same chemical fume suppressant and at similar surface tensions, are higher—not lower—than the emission rate calculated for test four at the same facility conducted at a higher surface tension. We believe this indicates that other factors and practices at individual operations also affect the rate of hexavalent chromium emissions.

We also evaluated emission rates with the type of chemical fume suppressant used. The chemical fume suppressants used in tests one through six all contain fluorinated surfactants as the active ingredients (further information on chemical fume suppressant chemistry is included in Chapter VI). Because of this, one would expect, if all other
variables are similar, that emission rates would be similar. However, emission rates ranged from 0.004 to 0.065 milligrams/ampere-hour, with an average of 0.04 milligrams/ampere-hour. Recall that ARB's historical emission factor for hexavalentchromium emissions from decorative chromium plating tanks is 0.025 milligrams/amperehour.

d. Effect of Tank Contaminants on Emission Rate

Tests four, five, and six were conducted at the same facility and were designed to

evaluate the effect of bath contaminant levels on hexavalent chromium emissions. Generally, as the level of metallic contaminants builds in the plating bath, the bath becomes less efficient, and more current is necessary to overcome the resistance caused by the contaminants. Increasing the current, in turn, produces more bubbling which couldChapter V Page 47

lead to an emissions increase. Table V-5 contains information obtained from our survey of chemical suppliers, as well as contaminant levels present in the plating bath for tests four, five, and six. We have also included the hexavalent chromium emission rates obtained from each test to allow for easy comparison.

Table V-5 . Plating Bath Contaminants, Concentration Levels Where Bath Clean-up is Recommended, and Hexavalent Chromium Emission Rates

Manufacturer

Recommended

Action Level* Test 4 Test 5 Test 6

Metallic

Contaminants (milligrams/Liter) 5000–7000 mg/L 15,000 mg/L 60 mg/L 700 mg/L

Trivalent

Chromium 0.5–1 oz/gal 0.64 oz/gal < 0.1 oz/gal 0.2 oz/gal

Chloride 50 mg/L 130 mg/L 14 mg/L 20 mg/L

Mean Hexavalent

Chromium

Emission Rate 0.050 mg/amp-hr 0.052

mg/amp-hr 0.065

mg/amp-hr * Average from 5 suppliers of chemicals to the plating industry.

The data in Table V-5 summarize information on common contaminants. The largest concentrations of metallic contaminants are typically nickel, copper, and lead. Trivalent chromium and chloride are also common contaminants that reduce bath efficiency. Note that despite heavy contaminant levels in test four the emission rate was lower than the emission rates in the two subsequent tests. If contaminants play a role in increasing emissions, we would have expected test five, conducted with a freshly prepared plating bath with essentially no contaminants (same tank, old solution disposed of) to yield the

lowest emission rate. While we did not find a correlation with contaminant levels and emission rates, we nevertheless recommend that bath contaminants be minimized by conducting routine maintenance.



### D. Statewide Hexavalent Chromium Emissions

The emission factor of 0.04 milligrams/ampere-hour was used to estimate 2003 hexavalent chromium emissions and estimated cancer risk for facilities using chemical fume suppressants as sole control. This would reflect emissions prior to implementation
of Rule 1469 in the SCAQMD.Chapter V Page 48

Statewide emissions of hexavalent chromium were calculated based on information from the 2003 survey of chromium plating and anodizing operations. To calculate emissions, the following equation was used:

Emission Rate (milligrams/ampere-hour) X Throughput (ampere-hours/year) =

Annual Facility Hexavalent Chromium Emissions

Emission rates were assigned as follows:

Volume (fume suppressant) Tank Emission Rate: 0.04 milligrams/ampere-hour

Point Source Emission Rate:

• Available emission rates from source tests

When source data were not available, emission rates were assigned based on type of controls corresponding to emission rates in the current ATCM as follows:

• HEPA or Mist Eliminator combination– 0.006 milligrams/amperehour

• Scrubber – 0.15 milligrams/ampere-hour

Figure V-2 shows the estimated statewide hexavalent chromium emissions in 2003.

Figure V-2 . Statewide Hexavalent Chromium Emissions in 2003 Were

14.4 Pounds

As shown in Figure V-2, statewide emissions of hexavalent chromium from chromium plating and chromic acid anodizing operations totaled 14.4 pounds in 2003. Facilities with in tank controls emitting 4.7 pounds per year, are primarily decorative plating and chromic acid anodizing operations. Facilities with add-on air pollution controls, emitting 9.7 pounds per year, generally are hard chromium plating operations. However, for health risk reasons, a number of decorative chromium plating and chromic acid anodizing facilities are also controlled with add-on air pollution control devices. While this amount of hexavalent chromium emissions seems small on a statewide basis, the emissions are Facilities with add- on air pollution controls: 9.7 pounds Facilities with in-tank controls only: 4.7 poundsChapter V Page 49

highly localized and the cancer potency of hexavalent chromium make these emissions a public health concern for sensitive receptors, especially those located in close proximity to plating and anodizing operations. It is also important to note that the emissions of hexavalent chromium shown in Figure V-2 do not include fugitive emissions of hexavalent chromium, which we have learned can be a significant part of a facility’s overall impact.



### E. Fugitive Emissions

In addition to hexavalent chromium emissions from the tank, chromium plating and chromic acid anodizing facilities also have fugitive emissions of hexavalent chromium, primarily dust. Dust accumulating in facilities from other operations such as grinding and polishing of parts prior to plating, and/or from poor housekeeping practices, provides a surface on which particles of hexavalent chromium from the plating operation may adhere. The hexavalent chromium may come directly from the plating process as mist is ejected from the bath. Other sources of hexavalent chromium may include droplets of chromic acid dripping onto other surfaces as plated parts are transferred to rinse tanks. This hexavalent chromium laden dust has the potential to become re-entrained due to air currents and activity in the plating or anodizing facilities.

Our Barrio Logan study confirmed that emissions of hexavalent chromium from a decorative plating shop were not only from the actual plating process, but from hexavalent chromium dust which became re-entrained. A study done by SDCAPCD also measured significant hexavalent chromium levels in dust of chromium plating and chromic acid anodizing facilities. This would indicate that the residence time might be longer for hexavalent chromium than was originally thought. During the emissions testing program, ARB staff also collected indoor air samples to qualitatively measure hexavalent chromium emissions. These studies are discussed individually and have prompted ARB to propose housekeeping requirements for hexavalent chromium plating and chromic acid anodizing

facilities to minimize dust.

1. Barrio Logan Fugitive Emissions – Indoor Air Results

During the Barrio Logan study, indoor air samples were collected at two plating facilities. The first facility, a hard chromium plating facility had add-on air pollution control devices, including a HEPA filtration system. The second facility was a decorative chromium plating facility with no add-on air pollution control device or forced ventilation system. Indoor samples from the hard chromium plating facility averaged a hexavalent chromium concentration of 42.5 ng/m 3 , while the average at the decorative plating facility was 393.4 ng/m 3 . Continued indoor air sampling at the decorative plating facility yielded results as high as 2,315 ng/m 3 . To put these numbers in perspective, the statewide annual average of ambient hexavalent chromium levels was 0.091 ng/m 3 in 2005. Key conclusions of this study are:

• High hexavalent chromium indoor air readings corresponded with high throughput (ampere-hour) at the decorative chromium plating facility;

• High levels of hexavalent chromium seen at ambient sites within the study area were consistent with high indoor levels at the decorative chromium plating facility,Chapter V Page 50

indicating that the indoor hexavalent chromium emissions were emitted to the outdoors;

• Dust generated by clean up and construction activities was shown to contain high levels of hexavalent chromium (1200 mg/kg or higher), which exited the building;

and

• The hard chromium plating facility, with add-on air pollution control devices, had low indoor concentrations of hexavalent chromium compared to those at the decorative chromium plating facility (ARB, 2003).

As a follow-up to the Barrio Logan study, SDCAPCD staff took additional samples at 10 other plating facilities in their district. These results are summarized in Appendix G. These data confirm that hexavalent chromium is in the dust at chromium plating and chromic acid anodizing facilities. This dust can become re-entrained in the indoor air and affect not only the workers at the facility, but also the receptors living near the facility

when the dust is blown outside.

2. ARB - Indoor Air Samples During Source Testing

As we began the emissions testing program, we qualitatively measured indoor levels of hexavalent chromium during each test. Samples were taken during the source test and, for Phase II, samples were taken during the source test with the temporary hood in place. Background samples were also taken without the temporary hood for comparison. These

results are summarized in Table V-6.

Table V-6 . Summary of Indoor Air Results During Emissions Testing Program

Test Number Samples Range Indoor Air Concentration (ng/m3) Average Indoor Air Concentration (ng/m3) Facility 1 5 131* – 391* 262* Facility 2 3 106 – 220 174 Facility 3 3 2.2 – 5.6 4 Facility 4 6 9.3 - 70 25 Facility 4 (background) 4 3.9 - 79 45 Facility 5 3 39 - 67 57 Facility 5 (background) 3 100 – 210 143 Facility 6 9 150-2350 976 Facility 6 (background) 4 120-460 248

*Total chromium numbers

Facilities four through six are those facilities that were tested by placing a temporary hood over the plating tank. While only qualitative, these data support that hexavalent chromium is being emitted from the plating tank during the electrolytic process. The data also indicate the presence of hexavalent chromium laden fugitive dust.Chapter V Page 51



### REFERENCES

ARB, 1988b. Air Resources Board. “Staff Report: Initial Statement of Reasons for Proposed Rulemaking – Proposed Airborne Toxic Control Measure for Emissions of Hexavalent Chromium from Chrome Plating and Chromic Acid Anodizing Operations”.

1988.

ARB, 2003. Air Resources Board. “Ambient Monitoring for Hexavalent Chromium and Metals in Barrio Logan: May 2001 through May 2002”. 2003.

SCAQMD, 2003a. South Coast Air Quality Management District. “Draft Staff Report - Proposed Amended Rule 1469-- Hexavalent Chromium Emissions from Chrome Plating and Chromic Acid Anodizing Operations and Proposed Rule 1426- Emissions from Metal Finishing Operations.” 2003

SCAQMD, 2004. South Coast Air Quality Management District. Certified List of Fume Suppressants for Facilities Performing Chrome Plating and Chromic Acid Anodizing Operations. 2004 (http://www.aqmd.gov/prdas/ChromePlating/ChromePlating.htm)

SCAQMD, 2004a. South Coast Air Quality Management District. “Hexavalent and Total Chromium Emissions from a Decorative Chrome Plating Tank Controlled by Various Mist Suppressants”. 2004

U.S. EPA, 1996. U.S. Environmental Protection Agency. “Emission Factor Documentation for AP-42 Section 12.20 – Electroplating – Final Report”. 1996.Chapter VI Page 52



## VI. Reducing Hexavalent Chromium Emissions

N o new technologies or technology transfers would be required for facilities to comply with the proposed amendments to the Chromium Plating ATCM. Hard chromium plating facilities, for the most part, have used add-on air pollution control devices such as scrubbers, composite mesh pads, and HEPA filters. Decorative chromium plating and chromic acid anodizing facilities have mostly used in-tank controls, such as chemical fume suppressants and polyballs. These same technologies, or combinations of technologies, would allow facilities to comply with the proposed amendments. Generally, the proposed amendments would require wider use of add-on air pollution control devices. This Chapter describes the types of methods used to control hexavalent

chromium emissions.



### A. In-tank Controls

In-tank controls are the most widely used method of reducing hexavalent chromium emissions. In-tank controls include chemical fume suppressants which are added directly to the plating bath solution and mechanical fume suppressants which float on top of the plating bath. Each is described below, along with information on their effectiveness at reducing emissions and the number of facilities using them, based on our industry survey.

1. Mechanical Fume Suppressants

Mechanical fume suppressants are added to a plating bath’s surface to form a physical barrier. These plastic balls (similar in appearance to ping-pong balls), called polyballs, act as a barrier to prevent mist from escaping the tank during plating. ARB’s “Senate Bill (SB) 1731 Risk Reduction Audits and Plans Guidelines for Chrome Electroplating Facilities” assigns for polyballs a 70 percent emission reduction efficiency (ARB, 1997a).

To achieve this level of emission reduction requires complete coverage of the plating bath. Our survey results indicate that polyballs are used by about 60 facilities. Of these facilities, about 40 use them in combination with a chemical fume suppressant. One test in our emissions testing program evaluated the effectiveness of polyballs in conjunction with fume suppressants to reduce emissions. This test yielded an emission rate of 0.004 milligrams/ampere-hour. However, we cannot measure the efficiency of this

combination because we did not test the uncontrolled emissions from the bath.

Polyballs can be a source of fugitive emissions if they are ejected from the tank when parts are removed and the solution on the polyballs dries on the floor of the facility. Plated parts must be removed from the tank carefully to avoid pulling polyballs out of the tank along with the plated part. Polyballs may be a partial control option for facilities where there is concern with ‘pitting.’Chapter VI Page 53

2. Chemical Fume Suppressants

In the chromium plating process, only about 20 percent of the electrical current applied actually deposits chromium onto the part. The remaining current forms bubbles, hydrogen gas at the cathode and oxygen at the anode, that rise to the surface of the bath. As these bubbles burst, hexavalent chromium is emitted into the air. These bubbles can be reduced by adding chemical fume suppressants directly into the plating bath to reduce emissions. Emissions are controlled by reducing surface tension of the bath, by forming a physical foam blanket across the tank surface during plating, or by using a combination of foam blanket and reduced surface tension. The most used type of chemical fume suppressant in California’s plating industry are chemicals that reduce surface tension.

a. Chemical Fume Suppressants Containing a Wetting Agent

Surface tension is the force that keeps a fluid together at the air/fluid interface. It is expressed in force per unit of width such as dynes/centimeter (dynes/cm). Chemical fume suppressants that contain ‘wetting agents,’ or surfactants, reduce this surface tension. By reducing surface tension, gas bubbles become smaller and rise more slowly than larger bubbles. Slower rising bubbles have reduced kinetic energy such that when the bubbles do burst at the surface the hexavalent chromium is less likely to be emitted into the air, and the droplets fall back onto the surface of the bath (Bayer ® ).

The most common types of surfactants used in chromium electroplating and anodizing are fluorinated or perfluorinated compounds or, collectively, fluorosurfactants. The active ingredients are compounds such as organic fluorosulfonate and tetraethylammonium perfluoroctyl sulfonate. The fluorosurfactant-based fume suppressant products used today represent an improvement over the previous hydrocarbon-based products. Fluorosurfactants are more hydrophobic than hydrocarbon surfactants and they are more surface active than hydrocarbon surfactants. Fluorinated sulfonate surfactants are effective in highly acidic solutions because they are resistant to hydrolysis by strong acids (U.S. EPA 1998). Fluorocarbon chains are also ‘stiffer’ than hydrocarbon chains so they are able to pack more closely. For these and other reasons, fluorosurfactants are able to reduce surface tension to levels that cannot be reached with hydrocarbon surfactants (JPCB, 1999).

These products are highly effective at reducing hexavalent chromium emissions by reducing plating bath surface tension. However, the compounds have been shown to bioaccumulate (see further discussion in Chapter XI). The fluorosurfactants used as active ingredients in chemical fume suppressants are often referred to as perfluorooctyl sulfonates (PFOS). On March 10, 2006, U.S. EPA published at 40 CFR Part 721.9582, a proposal to add certain PFOS into their Significant New Use Rule for perfluoroalkyl sulfonates (PFAS)(U.S. EPA, 2006). The PFOS proposed for addition include the PFOS commonly used in chemical fume suppressants. More information can be found on the following website: http://www.epa.gov/opptintr/pfoa/index.htm.

The notice for the amended Significant New Use Rule indicated that comments were being accepted to determine if these PFOS were in current use, such that a potentialChapter VI Page 54

exception could be included. As of this writing, it is unclear as to what U.S. EPA’s final action will be. However, it is clear that the PFOS used to control hexavalent chromium emissions from chromium plating and chromic acid anodizing have been in use since the early 1990’s (P&SF, 2000). Should the U.S. EPA act to include the PFOS in the Significant New Use Rule without providing an exception for their use in electroplating, the manufacturer or importer would have to seek approval from U.S. EPA to allow their use in electroplating. ARB staff will continue to follow developments here, and would potentially have to propose regulatory changes depending on the final rule.

To put the magnitude of surface tension reduction required to suppress hexavalent chromium emissions into perspective, consider that the surface tension of water is about 72 dynes/centimeter. The current ATCM requirement is to reduce surface tension below 45 dynes/centimeter. Data suggest that lowering the surface tension below 45 dynes/centimeter reduces emissions further. In fact, product literature from a

manufacturer of the fluorinated surfactants indicates that maximum emission reduction is achieved at 30 dynes/centimeter (Bayer ®). Our testing results did not statistically confirm that reducing surface tension to this level reduced emissions further. Balancing cost, staff is proposing that surface tension be maintained below 40 dynes/centimeter.

Another advantage of chemical fume suppressants containing fluorinated surfactants is that once a certain concentration is added to the tank, surface tension reduces rapidly (Kissa, 1994). Thus, a consistent level of emission reduction is provided. This is further justification for requiring facilities to use the chemical fume suppressants that rapidly

reduce surface tension.

Earlier generation chemical fume suppressants were thought to cause pitting. Pitting is development of small holes or imperfections during plating. This was of particular concern in hard chromium plating applications due to the length of time necessary to build the desired chromium thickness. Earlier generation chemical fume suppressants, although perfluorinated, contained salts. These salts, when mixed with the fluoride ions in the plating bath, became suspended and caused roughness, porosity or cracking of the chromium plate leading to pits. The chemical fume suppressants in use today no longer contain these salts. Thus, chemical fume suppressants used today containing fluorosurfactants are no longer a source of ‘pitting,’ and are accepted for use even in hard chromium plating applications. However, if the plating bath contains other contaminants that may cause pitting, such as chloride, the chemical fume suppressant will accentuate the pit (P&SF, 2000 and Jones, 2006).

The main loss of fluorinated chemical fume suppressants is through dragout of solution because fluorinated surfactants are highly stable (U.S. EPA, 1993). Studies have shown that the carbon-fluorine (C-F) chemical bond can remain stable when exposed to acids, alkali, oxidation, and reduction at relatively high temperatures (Kissa, 1994). Therefore, it is not expected that the surface tension of a bath will increase after a few days of use, due to chemical breakdown, for these types of surfactants.

However, surface tension will increase as chemical fume suppressant is lost to drag out as parts are removed from the tank. The quantity of chemical lost will depend onChapter VI Page 55

workload and shop-specific parameters. Dragout can be minimized if electroplated parts are sprayed off over the tank, or drip trays are installed to return the surfactant to the tank along with the excess chromic acid.

b. Foam Blanket Chemical Fume Suppressants

Foam blanket chemical fume suppressants generate a layer of foam on the surface of the bath when current is applied. The foam blanket is formed by agitation from the hydrogen and oxygen gas bubbles generated during plating. The blanket reduces hexavalent chromium emissions by physically entrapping the mist in the foam.

There are some issues with use of foaming chemical fume suppressants. For example,foam blankets need time to form after the current is applied and may also need time to reform after parts are removed, or makeup chemical fume suppressant is added to the bath. For shops that use their tanks intermittently, a consistent level of emission reduction is not achieved. Under the staff’s proposal, chemical fume suppressants that rely on building a foam blanket for emission control could no longer be used.

Foam blankets also can entrap hydrogen gas, which may result in explosions if a spark is generated. This is more of a concern in hard chromium plating than in decorative chromium plating, because of the higher current densities and longer plating times associated with hard chromium electroplating operations. A foam blanket can also reduce the evaporative cooling of a bath, resulting in the need for increased cooling by other means (U.S. EPA, 1993).

c. Measuring Surface Tension

Because hexavalent chromium emissions are reduced only at lowered surface tensions, accurate measurement of the bath’s surface tension is a critical compliance step. Surface tension has traditionally been measured either using a stalagmometer or a tensiometer. A du Nouy tensiometer is an instrument that measures surface tension by increasing force to a platinum-iridium ring in contact with the surface of the liquid. The tensiometer pulls on the ring and measures the force it takes to break the ring from the surface.

The stalagmometer is an instrument used to measure surface tension by determining the mass of a drop of liquid by weighing, a known number of drops or by counting the number of drops obtained from a known volume of liquid. Measuring surface tension with a stalagmometer is sometimes referred to as the ‘drop weight’ method. A stalagmometer is similar to a pipette (CDPHE 1999). Measuring surface tension with the stalagmometer is the most often used method, mostly because of cost considerations.

U.S. EPA's research found that measurements of surface tension with a tensiometer were approximately 20 percent lower than those obtained with a stalagmometer (U.S. EPA, 2002). Results of surface tension measurements from our emissions testing program also confirm that the tensiometer routinely gives lower surface tension readings than the stalagmometer. However, we did not see a consistent difference.Chapter VI Page 56

In 2004, U.S. EPA amended the Chromium Plating NESHAP. One of the changes establishes different surface tension standards, depending upon the type of measurement device used. If a facility uses a stalagmometer to measure surface tension, the surface tension should not exceed 45 dynes/centimeter. If a tensiometer is used, the surface tension limit is 35 dynes/centimeter (U.S. EPA, 2004).

Generally, the tensiometer is considered to provide the truer measure of surface tension. However, tensiometers can cost thousands of dollars, while stalagmometers only cost hundreds of dollars (Hensley, 1997).

Staff is proposing to incorporate the Chromium Plating NESHAP’s revised surface tension requirements into the ATCM. For measuring surface tension the ATCM has referenced an U.S. EPA method, Method 306-B, contained in Appendix A of 40 Code of Federal Regulations, part 63. This Method 306-B requires use of ASTM Method D 1331-89,

Standard Test Methods for Surface and Interfacial Tension of Solutions of Surface Active Agents, when surface tension is measured with a tensiometer. When measurements are taken with a stalagmometer, Method 306-B requires operators to use the instructions that came with the measuring device. For standardization, staff is proposing to include, as Appendix 8 to the ATCM, a standardized procedure for measuring surface tension with a stalagmometer. This method or a method approved by the permitting agency must be used to measure surface tension with a stalagmometer.

d. Fume Suppressants Used in California

As part of our survey of the chromium plating and chromic acid anodizing industry in California, ARB collected information on the types of fume suppressants used. The data

are summarized in Table VI-1 below.

Table VI-1 . Types of Chemical Fume Suppressants Used in California in 2003

Fume Suppressant Name Numbers Using

Fumetrol 140 ® 108

Fumetrol 140 ® + Dis Mist ® 16

Zero Mist ® 10

Dis Mist NP ® 23

Protab 1000 ® or Mactec Spray

Stop ® 5

Fumetrol 101 ® 5

Benchbrite ® 4

Chrome Foam 4 Clepo Chrome Mist Control ® 5

Foam Lok ® , Harshaw MSP ®

, EconoChrome ® 3Chapter VI Page 57

Of the 230 hexavalent chromium operations, 190 reported use of fume suppressant either as the sole control, or with other control devices. Table VI-1 shows the types of chemical fume suppressants reported as used by 183 operations for calendar year 2003. The other operations did not name the type of chemical fume suppressant used.

After the survey was conducted, SCAQMD amended their chromium plating and anodizing rule. They introduced the chemical fume suppressant certification program. The list of certified chemical fume suppressants can be found on their web site at: http://www.aqmd.gov/prdas/chromeplating/chromeplatin g.htm

Because the type of chemical fume suppressant used is critical to the chemical’s ability to reduce and maintain lower surface tension, ARB staff also conducted a survey of chemical fume suppressant manufacturers to gather information on product formulation, mechanism of action, and the surface tension to be achieved for maximum effectiveness. The results of the survey are shown in Table VI-2, below.

Table VI-2 . Summary of Chemical Fume Suppressant Mechanism of Control and

Recommended Surface Tension

Chemical Fume Suppressant Primary Mechanism and Surface Tension

Atotech USA

Dis Mist NP ® Foam 1-2 inches

Fumetrol 140 ® Surface Tension Reducer (30 dynes/cm with a tensiometer)

Benchmark

Benchbrite CR-1800 ® Surface Tension Reducer (40 dynes/cm)

Chemithon-Micel

Chrome Foam ® Surface Tension Reducer (20-30 dynes/cm)

MacDermid Proquel 1299 ® Surface Tension Reducer (40 dynes/cm) Macuplex STR ® Surface Tension Reducer (40 dynes/cm) Clepo Cr Mist Control ® Surface Tension Reducer (40 dynes/cm)

Enthone ®

Zero-Mist ® Surface Tension Reducer (30 dynes/cm)

(Source: Chemical Manufacturer Survey)

As shown in Table VI-2, almost all chemical fume suppressants used in California’s chrome plating industry control hexavalent chromium emissions by reducing bath surface tension. It should also be noted that most manufacturers recommend operating baths at 40 dynes/centimeter or below for maximum effectiveness. The current ATCM requires surface tension to be maintained below 45 dynes/centimeter. The survey also indicates that the products that reduce surface tension all use fluorosurfactants as the active ingredient.Chapter VI Page 58



### B. Add-on Air Pollution Control Devices

When the Chromium Plating ATCM was first adopted in 1998, hard chromium plating and chromic acid anodizing facilities were required to use add-on air pollution control devices to comply with hexavalent chromium emission limits (except for smaller operations). A number of decorative chromium plating facilities also use add-on air pollution control devices to comply with air district health risk rules. From our survey, 113 facilities reported using add-on air pollution control devices. Most facilities have either a one stage system consisting of composite mesh pad, mist eliminator or scrubber; or a two stage system which has a HEPA filter after the first stage. A brief description of the types of add-on air pollution control devices currently in use follows.

1. High Efficiency Particulate Arrestor (HEPA) Filter

High Efficiency Particulate Arrestor (HEPA) filters are specifically designed for the collection of submicrometer particulate matter at high collection efficiencies. First developed in the 1940’s for the Manhattan Project to control radioactive contaminants, HEPA filters are rated at 99.97 percent effective in capturing particles 0.3 μm in diameter. Particles of 0.3 μm in diameter represent the most penetrating particle size, meaning that the 99.97 percent efficiency is the worst efficiency. Smaller or larger particles are trapped with higher efficiency (HHS, 2000). When used in particulate air pollution control, HEPA filters are best utilized in applications with a low flow rate and low pollutant concentration. Typically HEPA filters are installed downstream of another control device to lessen loading on the filter, thereby lengthening its life. These products do require maintenance. The filters should be replaced at least annually and disposed of as hazardous waste. For all but very small facilities, HEPA filters are considered the most effective control of hexavalent chromium emissions. They represent BACT and can reduce hexavalent chromium emissions to no more than 0.0015 milligrams/ampere-hour. About one-third of facilities are already using HEPA filters to reduce emissions.

2. Composite Mesh Pad or Dry Scrubber

A Composite Mesh Pad (CMP) system typically consists of several layers of more than one monofilament diameter and/or interlocked fibers densely packed between twosupporting grids. Most systems do exist in two or three stages to ensure collection of reentrainment caused by washdown. A 3 stage system will remove small particles from one to 3 μm at about 99 percent efficiency. Each stage can capably remove particles at this size but it will take at least 3 stages to reach this efficiency. Filters must be changed every one to six years and need to be disposed of as hazardous waste (CDPHE, 1999 and U.S. EPA, 1998).

3. Wet Scrubber

A wet scrubber is similar to a CMP system, or Dry Scrubber, except that before the first stage of filtration, there is a water washdown of the influent mist in order to increase the size of the particles in the mist. In this system, a packing media is used to coalesce theseChapter VI Page 59

larger particles and allow them to drip off into a reservoir at the bottom of the scrubber. This “packing” can best be described as a big bag of polypropylene “whiffle” balls.

4. Fiber-bed Mist Eliminator

A Fiber Bed Mist Eliminator (FBME) removes contaminants from a gas stream through the mechanisms of inertial impaction, direct interception, and Brownian diffusion. A FBME consists of one or more fiber beds and each bed consists of a hollow cylinder formed from two concentric screens designed for horizontal, concurrent gas liquid flow through the fiber bed. It is typically installed downstream from another control device to prevent plugging (CDPHE, 1999). The filter should last four to six years and needs to be disposed of as hazardous waste. According to our survey, this control technology is not widely used today in California.

5. Enclosed Tank Covers

For hard chromium plating and chromic acid anodizing facilities, devices are available to totally enclose the plating tank. These containers, sometimes referred to as Merlin hoods, form a sealed system to capture the hexavalent chromium emissions within the enclosed area. Gasses resulting from plating are vented through a semi-permeable membrane which allows the hydrogen and oxygen to exit, but, due to its size, the hexavalent chromium does not pass through. Two facilities reported using this technology. This technology would not be feasible for decorative chromium plating due to the short periods of time that plating actually occurs.



### C. Alternative Processes

Numerous processes are available, that in some cases, could be used as a replacement for some hexavalent chromium plating and chromic acid anodizing operations. Some of these processes are briefly described below.

1. Trivalent Chromium for Decorative Chromium

Decorative chromium consists of coatings typically 0.003 to 2.5 μm to provide a bright surface with wear and tarnish resistance when plated over a nickel layer. It is used for plating, for example, automotive trim/bumpers, bath fixtures and small appliances. An option staff considered for this proposal is to phase out hexavalent chromium for decorative chromium plating facilities and replace it with the trivalent chromium process. This option would eliminate cancer risk from decorative chromium plating facilities because trivalent chromium is not considered a carcinogen; however, it is still a toxic compound.

Trivalent chromium baths are currently commercially available for decorative chromium plating. In 2003, there were 10 active trivalent chromium operations in California. Of these, six are stand alone trivalent chromium operations and four perform both hexavalent and trivalent chromium plating for decorative applications. The double cellChapter VI Page 60

process developed in the 1970’s is improved and has been changed to a single cell process, which is easier to maintain. There are many benefits to using a trivalent chromium process as well as potential issues. These are presented in the following paragraphs. We also provide an example of costs associated with converting from the hexavalent chromium decorative plating process to the trivalent chromium process.

a. Benefits and Issues

The greatest benefit to using a trivalent chromium process is reduction in health risk. Trivalent chromium is not a carcinogen like hexavalent chromium. However, it has toxic effects. As such, it is a U.S. EPA HAP and is a TAC. In the Chromium Plating NESHAP and ATCM, emissions from trivalent chromium baths are regulated because of this designation. The health effects associated with trivalent chromium are summarized in Chapter II.

In addition to the reduction in toxicity, the trivalent chromium process also has other environmental advantages for the plating facility. The total chromium concentration in a trivalent chromium bath is significantly less than that of a hexavalent chromium bath. This leads to less wastewater and sludge, decreasing the hazardous waste cost for the facility. The misting and odor is greatly reduced compared to a hexavalent chromium bath, thereby protecting the worker. Trivalent chromium also has better throwing power 2
reducing the number of rejects as well as buffing and polishing of parts (P&SF, 2003a).

In addition to benefits, there are some potential issues with the trivalent chromium process. The first issue is the color. The newer baths produce a deposit much closer in color to the hexavalent chromium deposit. If a standard trivalent chromium plated part is placed more than a few inches away from a hexavalent chromium plated part, most consumers would not be able to distinguish between the two deposits. If it placed adjacent, manufacturers and consumers might prefer the hexavalent chromium deposit. (P&SF, 2003a). To keep the color consistent, the trivalent bath requires careful monitoring (Mikhael, 2006).

The second issue is thickness and corrosion resistance. Trivalent chromium can be plated thick enough for decorative purposes. Adhesion and cohesion are as good as hexavalent chromium deposits up to at least 1.4 μm ( P&SF, 2003a)

. However, some industry representatives believe that for automotive applications, the trivalent deposit is not thick enough to meet the step test requirements (Leehy, 2006). The manufacturers are working on acceptance of a trivalent finish for the automotive industry and have successfully changed the requirements for one company (MacDermid, 2006). Corrosion protection is also an issue for automotive applications. Hexavalent chromium ions themselves offer some corrosion resistance for the plated substrate by “chromating” thepart. To achieve the same affect for parts plated with trivalent chromium, posttreatments/dips after plating can be used to produce an equivalent short-term corrosion resistance (P&SF, 2003a). Also, trivalent chromium coatings are often deposited over nickel layers. The subsequent coating is said to exhibit corrosion resistance comparable

2 Throwing power is the ability to deposit chromium into the intricate recesses of a particular part.Chapter VI Page 61

to hexavalent chromium when using ASTM B117 salt spray test or the CASS test [1] (AF, 2000). However, some industry representatives still believe the trivalent plated deposit is “too soft” (Lucas, 2006) and will scratch easily. For the end user corrosion resistance is reduced and there is no “self healing” benefit (AF, 2001.)

Cost is another factor to consider when switching from hexavalent to trivalent chromium. Most of the equipment used for hexavalent chromium plating can be re-used when converting to trivalent chromium. A new synthetic tank lining, graphite anodes, and titanium or teflon spaghetti coils should be added for heating and cooling.

One major manufacturer estimated the costs associated with converting to trivalent chromium plating. The costs are shown below in Table VI-3.

Table VI-3. Cost Estimate for Conversion to Trivalent Chromium Operating Cost: Cost Cost for 800

Gallon Tank Operating cost (1,000,000 amp-hr) $0.023/amp-hr $23,000

Equipment/Chemicals:

Bath make- up

$11/gallon $8,800 Graphite anode cost $2.50/gallon $2,000 Ion exchange system $6,000 to $10,000 $10,000 Filter (for carbon) $5,000 to $10,000 $10,000

Air lines $500 $500 Heating/cooling coil (titanium) $2,000 $2,000 Amp-hour meter/feeder $1,200 $1,200

Tank Liner $2,000 to $5,000 $5,000 Conversion to flowing rinse from

Hexavalent pre-dip $2,000 $2,000

Additional Rinse Tanks varies varies

Subtotal $41,500 Hazardous Waste Disposal: **

Chromic Acid Disposal $4.35/gallon $3,480

Total $67,980

Source: Atotech **Cost estimate from Filter Recycling Services

Table VI-3 provides an estimate of the initial costs to convert from the hexavalent chromium process to the trivalent chromium process for a decorative plating facility with an 800 gallon plating tank and operating 1,000,000 ampere-hours per year. Of course, conversion costs would vary depending on an individual operation. A facility converting would have one-time equipment and chemical cost of about $41,500 and a chromic acid disposal cost (in this example, about $3,500). A facility would also have recurring operating costs of $23,000 plus additional chemical costs which would vary depending on the operation. A facility may have to install additional rinse tanks. This could lead to additional costs to accommodate this tank(s) within an existing plating line (Atotech,Chapter VI Page 62

2006). These costs should only be viewed as an example. An individual facility’s conversion costs will also vary based on type of parts plated (substrate and configuration), ambient temperatures, bath loading, and racking.

Staff has evaluated information from manufacturers of the trivalent chromium process, relevant literature, information from facility operators currently using the trivalent chromium process, and operators that feel they are unable to use the trivalent chromium process. We believe that the trivalent chromium process holds promise for the future. However, at this time, the trivalent chromium process is not feasible to replace all hexavalent decorative chromium plating applications.

2. Trivalent Chromium for Hard Chrome Plating

Trivalent chromium baths have not been used for hard chromium plating. There is difficulty in plating thick chromium coatings with the appropriate properties. Hard chromium coatings are typically 1.3 to 760 μm and provide functional properties such as hardness, corrosion resistance, wear resistance, and low coefficient of friction. Example applications include strut and shock absorber rods, hydraulic cylinders, crankshafts, and

industrial rolls.

There has been some recent research funded by the U.S. EPA on developing a process for hard trivalent chromium plating. The project is ongoing and a company is working on a trivalent chromium process for hard chromium plating (P&SF, 2003). This process is not commercially available.

3. Other Alternatives

A number of other alternative processes exist for some chromium plating and chromic acid anodizing applications. Some of the alternative processes include:

• Type II Sulfuric Acid Anodizing – often referred to as “regular,” “architectural,” or “sulfuric” anodizing. Sulfuric anodize is formed by using an electrolytic solution of sulfuric acid at room temperature. The process produces a fairly clear coating and is normally used for decorative purposes and provides some corrosion protection (IHC, 2006).

• Electroless Nickel Phosphorous – an auto-catalytic process that deposits a layer of nickel alloyed with the reducing agent, phosphorous. The deposit thickness is uniform and free of edge buildup because no current is used. Deposits are generally semi-bright. The properties include excellent wear, good corrosion resistance in many environmental, good lubricity, and improved hardness on many substrates (PMPC, 2006).

• Nickel-Tungsten Electroplating – an electrodeposited alloy of nickel and tungsten. The plated deposit exhibits physical and chemical properties similar to chromium and electroless nickel. The process is simple to control and can be operated inChapter VI Page 63

equipment similar to that used for hard chromium plating. A bright or dull finish is produced depending on the substrate (Enthone, 2006).

• Tin-Cobalt Alloy or Tin-Nickel Alloy – Tin-Cobalt al loy is usually plated over bright nickel and provides a finish with the appearance of chromium. It is durable and wear resistant (Seachrome, 2006). Tin-Nickel deposits can be used as an etch resist. It’s most common use is a replacement for hexavalent chromium in decorative applications (RPC, 2006).Chapter VI Page 64



### REFERENCES

AF, 2000. Automotive Finishing. BA Graves. Alternatives to Hexavalent Chromium and Chromium Plating. Winter 2000:

AF, 2001. Automotive Finishing. PC Wynn, CV Bishop. Replacing Hexavalent Chromium Plating. Spring, 2001:

ARB, 1997a. Air Resources Board

. “Senate Bill (SB) 1731 Risk Reduction Audits and Plans Guidelines for Chrome Electroplating Facilities” . 1997

Atotech, 2006. Paul Cartwright. Email to ARB staff regarding cost comparisons between trivalent and hexavalent chromium electroplating systems. 2006.

Bayer ®. Product information Bayowet® FT 248 and FT 248R

CDPHE, 1999. Colorado Department of Public Health and Environment. Chromium Maximum Achievable Control Technology (MACT) guidance. Updated April 21, 1999. (http://www.cdphe.state.co.us/ap/chromium/html/index.html)

Enthone, 2006. Cookson Electronics: Enthone. ENLOY® Ni-500. 2006. (http://www.enthone.com/functional/index.aspx?Detail=../uc/enloy-ni-500.ascx)

Hensley, 1997. JE Hensley and D York. “Report on Observed Differences in Dynes/Centimeter Readings of Various Chromium MACT Method 306B Surface Tension Measuring Devices”. presented at the 18 th AESF/EPA Pollution Prevention & Control

Conference. 1997.

HHS, 2000. U.S. Department of Health and Human Services. “Primary Containment for Biohazards: Selection, Installation and Use of Biological Safety Cabinets”. 2000

IHC, 2006. IHC, Inc. Sulfuric Anodizing. 2006. (http://www.ihccorp.com/IHCSulf_Anod.htm)

Jones, 2006. Jones, A.R., Email Communication dated April 17, 2006.

JPCB, 1999. Journal of Physical Chemistry B. K Wang, G Karlsson and M Almgren. Aggregation Behavior of Cationic Fluorosurfactants in Water and Salt Solutions. A CryoTEM Survey. 103, 9237-9246. 1999

Kissa E, 1994. “Fluorinated Surfactants” . Chapter 4, Marcel Dekker, Inc. 1994

Leehy, 2006. Air Resources Board staff telephone conversation with David Leehy,

Grover Products. 2006.

Lucas, 2006. Ray Lucas. Email to ARB staff regarding feasibility of trivalent as an alternative to hexavalent chromium plating. 2006Chapter VI Page 65

MacDermid, 2006. Air Resources Board staff telephone conversation with Ken Kraemer

of MacDermid. 2006

Mikhael, 2006. Air Resources Board staff telephone conversation with Fiyador Mikhael, Bronzeway Plating. 2006

P&SF, 2000. Plating and Surface Finishing. TD Ferguson, M Zellen, D Brennan and J Lutz. Use of Fume Suppressants in Hard Chromium Baths—Quality Testing. February

2000:67-72.

P&SF, 2003a. Plating & Surface Finishing. DL Snyder. Distinguishing Trivalent Chromium Deposits by Color. November 2003:34-39

P&SF, 2003b. Plating and Surface Finishing. RP Renz, JJ Fortman, EJ Taylor and ME Inman. Electrically Mediated Process for Functional Trivalent Chromium to Replace Hexavalent Chromium: Scale-up for Manufacturing Insertion. June 2003:52-58

PMPC, 2006. Precious Metals Plating Company, Inc. Electroless Nickel. 2006. (http://www.pmplating.com/electroless%20nickel.htm)

RPC, 2006. Reliable Plating Corporation. Tin/Nickel Plating. 2006. (http://www.reliableplating.com/tinnickel.html)

Seachrome, 2006. Seaboard Metal Finishing. Seachrome. 2006. (http://www.seaboardmetalfin.com/schrome.htm)

U.S. EPA, 1993. U.S. Environmental Protection Agency. EPA/453/R-93-030a: “Chromium Emissions from Chromium Electroplating and Chromic Acid Anodizing Operations - Background Information for Proposed Standards” . 1993.

U.S. EPA, 1998. U.S. Environmental Protection Agency. EPA/625/R-98/002: “Capsule Report Hard Chrome Fume Suppressants and Control Technologies”. 1998.

U.S. EPA, 2002. U.S. Environmental Protection Agency. “National Emission Standards for Chromium Emissions From Hard and Decorative Chromium Electroplating and Chromium Anodizing Tanks”. 2002.

U.S. EPA, 2004. U.S. Environmental Protection Agency. 40 CFR Part 63: “National

Emission Standards for Chromium Emissions From Hard and Decorative Chromium Electroplating and Chromium Anodizing Tanks”. 2004.

U.S. EPA, 2006. U.S. Environmental Protection Agency. 40 CFR Part 721: “Perfluoroalkyl Sulfonates; Proposed Significant New Use Rule.” 2006.Chapter VII Page 66



## VII. Health Risk Assessment

T his Chapter presents an overview of the health risk assessment (HRA) process that forms the basis for the proposed amendments to the Chromium Plating ATCM. The air quality modeling necessary to conduct the HRA is also summarized. Current cancer and non-cancer health impacts from exposure to hexavalent chromium from chromium plating and chromic acid anodizing operations is also included.



### A. Overview

A health risk assessment (HRA) is an evaluation or report that a risk assessor (e.g., ARB, district, consultant, or facility operator) develops to describe the potential a person or population may have of developing adverse health effects from exposure to a facility’s emissions. Some health effects that are evaluated include cancer, developmental effects,and respiratory illness. For hexavalent chromium, we evaluated the cancer and noncancer health impacts and found that the cancer health impacts were far more significant than any non-cancer impacts. Therefore, the following sections focus on the cancer risk assessment. Section E contains a discussion of non-cancer health impacts.

Exposure to TACs can occur through pathways that include inhalation, skin exposure, and the ingestion of soil, water, crops, fish, meat, milk, and eggs. OEHHA has determined that hexavalent chromium is carcinogenic by the inhalation route only (OEHHA, 2003) and does not recommend using a mulitpathway methodology. The methods used in this risk assessment are consistent with the Tier 1 analysis described in the OEHHA Air Toxics “Hot Spots” Program Risk Assessment Guidelines, the Air Toxics Hot Spots Program Guidance Manual for Preparation of Health Risk Assessments (OEHHA, 2003).



### B. Health Risk Assessment Process

The following sections describe the steps in the HRA process and the resulting health risk estimates for chromium plating and chromic acid anodizing facilities .

1. Hazard Identification

Step one for the risk assessor is to determine whether a hazard exists. If so, the assessor identifies the pollutant(s) and the type of effect, such as cancer or respiratory effects. In this case, we have determined that hexavalent chromium is emitted from chromium plating and chromic acid anodizing facilities. In 1986, the Board formally

identified hexavalent chromium as a TAC.

The Board determined that hexavalent chromium exposure causes cancer and there was no safe level of exposure where adverse health effects would not occur. When the Board identified hexavalent chromium as a TAC, a unit risk factor of 1.5 X 10 -1 μg/m 3 was established in support of the identification. This means that a lifetime exposure toChapter VII Page 67

one μg/m 3 of hexavalent chromium would increase an exposed person’s chance of developing cancer by about 15 percent. Exposure to hexavalent chromium is known to cause lung and nasal cancers, respiratory irritation, severe nasal and skin ulcerations and lesions, perforation in the nasal septum, liver and kidney failure and birth defects (ARB, 1985). Hexavalent chromium is also classified as a human carcinogen by the International Agency for Research on Cancer (IARC, 1997).

2. Dose-Response Assessment

The second step of risk assessment is for the risk assessor to characterize the relationship between a person’s exposure to a pollutant and the incidence or occurrence of an adverse health effect. This step of the HRA is performed by OEHHA. OEHHA supplies these dose-response relationships in the form of cancer potency factors (CPF) and reference exposure levels (RELs.) A CPF is used when estimating potential cancer risks and RELs are used to assess potential non-cancer health impacts (OEHHA, 1999; OEHHA, 2002; OEHHA, 2003).

Cancer potency factors are the upper bound probability of developing cancer, assuming continuous lifetime exposure to a substance at a dose of one milligram per kilogram of body weight. To compare the potency of hexavalent chromium with other carcinogens, Table VII-1 lists cancer potency factors for various TACs.

Table VII-1 . Inhalation Cancer Potency Factors for Common Carcinogens and Their Relative Potency to Hexavalent Chromium

Compound (in descending order) Cancer Potency Factor (mg/kg-day) -1 Relative Potency

to Hexavalent

Chromium

Dioxin 1.3 X 10 +5 250

Hexavalent Chromium 5.1 X 10 +2 1

Cadmium 1.5 X 10 +1 .029 Arsenic (inorganic) 1.2 X 10 +1 .024

Diesel Exhaust 1.1 X 10 .0022

Nickel 9.1 X 10 -1 .0018

Benzene 1.0 X 10 -1 .0002 Ethylene Dichloride 7.2 X 10 -2 .00014

Lead 4.2 X 10 -2 .000082 Formaldehyde 2.1 X 10 -2 .000041 Perchloroethylene 2.1 X 10 -2 .000041

Chloroform 1.9 X 10 -2 .000037 Acetaldehyde 1.0 X 10 -2 .000020 Trichloroethylene 7.0 X 10 -3 .000014 Methylene Chloride 3.5 X 10 -2 .000069
(OEHHA, 2003)

As shown in Table VII-1, only one other chemical, dioxin, has a higher potential to cause

cancer than does hexavalent chromium.Chapter VII Page 68

An REL is used as an indicator of potential non-cancer adverse health effects, and is

defined as a concentration level at or below which no adverse health effects are expected. RELs are designed to protect the most sensitive persons in the population by including safety factors in their development, and can be created for both acute and chronic exposures. An acute exposure is defined as one or a series of short-term exposures generally lasting less than 24 hours. Chronic exposure is defined as long-term exposure usually lasting from one year to a lifetime. Table VII-2 contains non-cancer RELs and toxicological endpoints for hexavalent chromium.

Table VII-2 . Hexavalent Chromium Health Effects Values Used in Non-Cancer

Health Risk Assessment

Non-Cancer Reference Exposure Levels (RELs) Toxicological Endpoints

Chronic – Inhalation 0.20 (μg/m 3 ) Respiratory system

Chronic – Oral 0.02 (mg/kg-day) Hematologic

*OEHHA 2003

As shown in Table VII-2, only non-cancer chronic RELs have been determined for hexavalent chromium. There is no non-cancer acute REL. Non-cancer impacts linked to hexavalent chromium exposure include respiratory irritation, severe nasal and skin ulcerations and lesions, perforation in the nasal septum, liver and kidney failure and birth defects (ARB, 1985).

3. Exposure Assessment

In an exposure assessment, step 3, the risk assessor estimates the extent of public exposure by determining people who will likely to be exposed, how exposure will occur (e.g., inhalation and ingestion), and the magnitude of exposure. For chromium plating and chromic acid anodizing facilities, the receptors (people) that are likely to be exposed are residents and off-site workers located near the facility. For this assessment, we focused on residential and off-site worker exposures.

Although on-site workers could be impacted by the emissions, they are not the focus of this HRA because the OSHA has jurisdiction over on-site workers. To protect worker safety, OSHA has established a PEL for hexavalent chromium of 5 μg/m 3 . The PEL is the maximum, eight hour, time-weighted average concentration for occupational exposure. Because the proposed amendments to the ATCM will require the installation of ventilation systems and add-on air pollution control devices for many additional chromium plating and chromic acid anodizing facilities, on site-worker exposure to hexavalent chromium at

the affected facilities would be reduced as well.

Hexavalent chromium is considered to be carcinogenic only when exposure occurs by the inhalation route (OEHHA, 2003.) Therefore, residential and off-site worker locations were evaluated via the inhalation pathway only.Chapter VII Page 69

One of the most reliable and cost-effective tools used by ARB staff to evaluate public exposures to a pollutant is to conduct air dispersion modeling simulations. The following sections summarize the air dispersion modeling conducted to evaluate the health impacts from exposure to hexavalent chromium. Further detail on the modeling simulations and the input parameters is contained in Appendix H of this report.

a. Air Dispersion Modeling

To assess the magnitude of exposure, ARB staff used a computerized air dispersion model to estimate downwind ground-level concentrations of hexavalent chromium at near source locations after it is emitted from a chromium plating or chromic acid anodizing facility. The downwind concentration is a function of the quantity of emissions, release parameters at the source, and appropriate meteorological conditions. ARB used the U.S. EPA’s Industrial Source Complex Short Term (Version 02035) air dispersion model (ISCST3 model). The ISCST3 model estimates concentrations at specific locations around each facility, directly caused by each facility’s emissions. The modeling inputs

used are summarized below.

b. Emission Estimates

Modeled concentrations are based on unit emission rates and can be adjusted to reflect any emission rate scenario. Therefore, emissions of hexavalent chromium from chromium plating and chromic acid anodizing facilities for this modeling analysis were based on an unit emission rate of one gram per second. The mass emission estimates in the model are then scaled down to reflect emissions from each chromium plating and chromic acid anodizing facility. Thus, the modeling simulation does not “grow” an individual facility’s emissions. By scaling the modeled concentrations we are able to determine how each facility’s emissions are dispersed into ambient air and the resulting concentrations at various distances from the facility. For this analysis staff assumed an operating schedule of 9 hours per day, 7 days per week, 52 weeks per year.

c. Meteorological Data

Four sets of meteorological data representing various locations in California were used for this HRA. The data selected are representative of where the majority of chromium plating and chromic acid anodizing facilities are located. The four locations, and the years the meteorological data represented are Los Angeles area – Pasadena (1981), San Francisco Bay area – Oakland (1960-64), San Diego area –Inland (1967-71), Central Valley – Fresno (1985-89).

d. Physical Description of the Source and Emission Release

Parameters

Six generic chromium plating and chromic acid anodizing facilities were modeled. These generic facilities were created from survey information, source test reports, and information obtained during site visits from ARB or district staff. Therefore, they are representative of the facilities in California. The modeling simulation predicted airborneChapter VII Page 70

concentrations of hexavalent chromium for potential receptor distances that ranged from 20 to 1,000 meters (66 – 3,280 feet) from the chromium plating and chromic acid anodizing facilities. The assumptions used for modeling emissions from generic facilities

are shown in Table VII-3 and Table VII-4.

Table VII-3 . Key Parameters for Air Dispersion Modeling and Health Risk

Assessment

Air Dispersion Model: U.S. EPA, Industrial Source Complex Short Term (ISCST3), Version 02035

Source Type: Volume and Point

Dispersion Setting: Urban

Receptor Height: 1.2 meters

Meteorological Data: Los Angeles area - Pasadena San Francisco Bay area - Oakland San Diego area - Miramar Naval Air Station Central Valley - Fresno

Receptor’s Hypothetical Exposure

Time: 70 years, 365 days/year

Adult Daily Breathing Rates: 393 liters/kg body weight-day (high-end) 302 liters/kg body weight-day (80th percentile) 271 liters/kg body weight-day (mean)

Adult Body Weight: 70 kg

Cancer Inhalation Potency Factors: Hexavalent Chromium – 510 (mg/kg-day) -1

Non-Cancer Acute RELs –

Inhalation: Hexavalent Chromium – not established

Non-Cancer Chronic RELs –

Inhalation: Hexavalent Chromium – 0.20 ug/m 3

Non-Cancer Chronic RELs - Oral: Hexavalent Chromium – 0.02 mg/kg-dayChapter VII Page 71

Table VII-4 . Generic Facility Parameters for Air Dispersion Modeling and Health

Risk Assessment

Stack Information (Point Sources):

Stack Diameters 0.32, 0.66, and 0.92 meters

Stack Heights 9.1, 9.1, and 12.8 meters

Stack Temperatures 24 degrees Celsius

Stack Exhaust Velocities 10.4, 12.2, and 8.5 meters/second

Volume Source Parameters : Release Height 2.5 meters (ground level)

Lateral Dimension 2.3, 4.0, and 7.0 meters

Vertical Dimension 2.3 meters

Point sources are facilities that already use add-on air pollution control devices with forced ventilation systems to collect hexavalent chromium emissions. Exhaust air containing any uncollected hexavalent chromium is then vented through a stack. Table VII-4 shows the various stack parameters used in the modeling. Note that emissions are modeled from the stack, and the stack is assumed to be in the center of the building. A typical point source would be a hard chromium plating facility.

Volume sources are facilities that use only in-tank controls ( i.e. chemical fume suppressants) to reduce hexavalent chromium emissions. Table VII-4 also shows the release parameters of the facilities that were used in the modeling. In this case, the source of emissions (the tank) is assumed to be in the center of the building and the emissions are modeled from that point. A typical volume source would be a decorative chromium plating facility.

e. Pollutant Specific Health Effects Values

Dose-response or pollutant-specific health values are developed to characterize the relationship between a person’s exposure to a pollutant and the incidence or occurrence of an adverse health effect. A CPF is used when estimating potential cancer risks and a REL is used to assess potential non-cancer health impacts. For ease of the reader, the current OEHHA-adopted health effects values for hexavalent chromium are repeated inTable VII-3. Note that the cancer inhalation potency factor is 510 (milligrams/kilogramday) -1

.

Through computerized modeling simulations and using the inputs listed in Tables VII-3 and VII-4, ARB staff can estimate how concentrations of hexavalent chromium are dispersed and diluted into ambient air. These data are then used to determine health impacts from chromium plating and chromic acid anodizing facilities.

Figure VII-1 depicts how concentrations of hexavalent chromium are reduced as they are dispersed from the facility. The meteorological data used are from Pasadena.Chapter VII Page 72

Figure VII-1 . Percent of Maximum Predicted Concentration of Hexavalent Chromium at

Increasing Distances from the Source *

0 20 40 60 80 100 120

20 30 40 50 100 200 500 1000

Distance from Facility in MetersPercent of Concentration volume source point source

* Concentrations using Pasadena meteorological data set and small facility.

Figure VII-1 shows that concentrations of hexavalent chromium decrease rapidly as they are dispersed from a facility. For volume sources (facilities without add-on air pollution control devices), at 100 meters the concentration is reduced to 9 percent of the concentration at 20 meters. For point sources (facilities with add-on air pollution control devices), at 100 meters the concentration is reduced to about 30 percent of the concentration at 30 meters. Note also that at 150 meters the concentration from the point source has been reduced to about 20 percent of the initial concentration.

Because of the model’s resolution, for volume sources a receptor is placed at 20 meters from the edge of the building. This is assumed to be the point of highest concentration, or as depicted in Figure VII-1,100 percent. While it is true that the concentration of hexavalent chromium would be higher at ten meters from the edge of the building, the model has not been validated to provide an accurate concentration at a distance less than 20 meters. For the modeled emissions from a small point source, the maximum concentration of hexavalent chromium is 30 meters from the edge of the building. This distance is the point of highest concentration, or 100 percent. Although not shown, a larger point source with a higher stack would have the highest concentration of

hexavalent chromium at a distance of 50 meters from the source.

These data indicate that emissions from chromium plating and chromic acid anodizing facilities are localized and cancer risk is highest for near-source receptors.Chapter VII Page 73

4. Risk Characterization

To characterize the health risk, the risk assessor combines information derived from the previous steps. Modeled pollutant concentrations from the exposure assessment are combined with the CPFs (for cancer risk) and RELs (for non cancer effects) derived from the dose-response assessment. Risk characterization integrates this information to quantify the potential cancer risk and non-cancer health effects.

For our assessment, Table VII-5 displays the parameters used to calculate both cancer and non-cancer health impacts.

Table VII-5 . Key Parameters for Assessing Estimated Cancer and Non-Cancer Health Impacts for Chromium Plating and Chromic Acid Anodizing Facilities

Point Source Volume Source
Exposure Residential Residential Breathing Rate 80 th percentile (302 l/kg) 80 th percentile (302 l/kg) Meteorological data set Pasadena Pasadena Operating Schedule 9 hrs/day, 7 days/week 9 hrs/day, 7 days/week

Facility Size Small (< 5,000,000 ampere/hrs) Medium (> 5,000,000

< 50,000,000 ampere/hrs) Large (>50,000,000 ampere/hrs) Small (3,000 ft 2 )

Maximum Individual Cancer Risk (MICR)

Distance 30 meters for small, 40 meter for medium, 50 meters for large 20 meters

Release Height 9.1 meters (stack height) for

small and medium 12.8 meters for large 2.5 meters (ground level)

Baseline emissions (2005) of hexavalent chromium for assessing cancer and non-cancerimpacts from each facility were calculated by multiplying reported throughput (in amperehours) by the facility’s emission rate. For volume source facilities in the SCAQMD, we used the emission rate for their certified chemical fume suppressants of 0.01 milligrams/ampere-hour. All other volume sources in the State were assigned a chemical fume suppressant emission rate of 0.04 milligrams/ampere-hour. This is consistent with results from our emissions testing program. For point sources, when source test data were available, the reported emission rate was used. For other point source facilities, emission rates were assigned based on regulatory requirements.

Based on these assumptions, statewide baseline hexavalent chromium emissions for 2005 were estimated to be four pounds per year.



### C. Factors that Affect Health Risk Assessments

The results of an HRA include an evaluation of potential adverse health impacts from exposure to a TAC. It is a complex process that requires the analysis of many variables to simulate real-world situations. For our purposes, we conducted health risk assessmentChapter VII Page 74

analyses in a manner which is very health protective in estimating cancer risks for a range of reasonably foreseeable exposure scenarios. A recent study, funded by ARB, indicted that the model employed in this analysis may actually under-predict near-source concentrations (UCR, 2003). Staff believe this health protective approach is necessary due to the very high potency and resultant serious health hazards associated with exposure to hexavalent chromium emissions. There are a variety of factors that can affect the results of the HRA for chromium plating and chromic acid anodizing facilities.

These include:

• Toxicity of hexavalent chromium;

• Emission rate of hexavalent chromium from the facility in milligrams/ampere-hour;

• Source release characteristics (e.g., height of stack, stack configuration, flow rate, and building dimensions);

• Facility operating schedule (duration of exposure);

• Local meteorological conditions;

• Distance to the receptor;

• Duration of exposure; and

• Inhalation rate of the receptor.

A combination of these factors will determine the potential health impacts. Due to the variability of these factors, the potential health impacts can also vary. For example, if the inhalation rate of the receptor were to increase (we have assumed the 80th percentile breathing rate), and all other factors were held constant, the resulting potential health impacts would also increase. The estimated cancer risks presented are representative of the maximum individual cancer risk (MICR). This implies calculation of a cancer risk where the concentration of hexavalent chromium is at its maximum upon being emitted from a facility. There may or may not be a receptor at this location.



### D. Cancer Risk Assessment

While the 4.0 pounds (1,800 grams) per year of emissions seems low, even a very small amount of hexavalent chromium can result in a substantial cancer risk. For example, staff found that as little as two grams of annual emissions would yield an estimated cancer risk of ten per million people exposed. As shown in Table VII-6, the maximum individual cancer risk (MICR) was determined for each chromium plating and chromic acid anodizing facility in California based on these 4.0 pounds of emissions. It should be noted that the MICR is calculated using the highest concentration of hexavalent chromium downwind of a facility that is predicted by an air quality model. People may not be living at the MICR point. Table VII-6 reflects implementation of the current ATCM and air district rules, including Rule 1469 for facilities in the South Coast Air Basin.Chapter VII Page 75

Table VII-6 . Sixty-three Facilities have Estimated Cancer Risk of Over 10 per

Million Exposed People (2005 Baseline)



### Number of Facilities by Cancer Risk

< 1 per million >1 < 10

per million >10 < 100

per million >100

per million

Baseline 2005 90 67 57 6

As shown in Table VII-6, 90 facilities (about 41 percent) have estimated cancer risk less than one per million exposed people. However, Table VII-6 also shows that 57 facilities (about 26 percent) have an estimated cancer risk of over ten per million exposed people. Six facilities (about 3 percent) may have an estimated cancer risk of over 100 per million people exposed.

Implementation of Rule 1469 in the South Coast Air Basin provided an improvement in cancer risk reduction for facilities located there. In 2003, we estimate that 30 percent of facilities had estimated cancer risk of less than one per million exposed people. Overall, about 55 percent of facilities had estimated cancer risks below ten per million exposed people. Eleven percent of facilities had estimated cancer risk of over 100 per million people exposed. These data are not shown graphically.

Based on these results staff has determined that while Rule 1469 reductions provided risk reduction benefits in the SCAQMD it had no impact in reducing cancer risk in other areas

of the State. We also believe Rule 1469 did not achieve the maximum reduction feasible because BACT was not required for all facilities. The staff’s proposal to reduce the cancer risk from chromium plating and chromic acid anodizing facilities is described in Chapter VIII.



### E. Non-Cancer Risk Assessment

Non-cancer impacts linked to hexavalent chromium exposure include respiratory irritation, severe nasal and skin ulcerations and lesions, perforation in the nasal septum, liver and kidney failure, and birth defects (ARB, 1985). We performed a non-cancer risk assessment to evaluate potential non-cancer health impacts based on 2005 emissions. This year reflects implementation of Rule 1469 in the South Coast Air Basin. The assessment included potential impacts from long-term (chronic) exposures. Potential chronic and acute health impacts are expressed in terms of a hazard quotient (for a single substance.) Typically, a hazard quotient or hazard index that is greater than 1.0 is considered to be unacceptable. The parameters that were used to model emissions and estimate cancer risk are contained in Tables VII-3, VII-4, and VII-5.

The analysis indicated that no facility’s hazard index exceeded 1.0 for either worker or residential exposure scenarios. In fact, no facility’s hazard index exceeded 0.01. Therefore, staff has concluded that no additional measures would be necessary to reduce potential chronic non-cancer impacts related to long-term exposure to hexavalent chromium from chromium plating and chromic acid anodizing facilities.Chapter VII Page 76

We also analyzed the throughput threshold, in ampere-hours, that could result in a hazardindex of 1.0. If we evaluate the hazard index for a generic facility and assume amperehours of 100,000,000 (higher than any facility’s throughput in the State) and use the assumed emission rate of 0.0015 milligrams/ampere-hour (HEPA level of control), ampere-hours would have to increase 100-fold to reach a hazard index of 1.0.Chapter VII Page 77

REFERENCES

ARB, 1985. Air Resources Board . “ Staff Report: Initial Statement of Reasons for Proposed Rulemaking – Identification of Hexavalent Chromium as a Toxic Air

Contaminant”. 1985.

IARC, 1997. World Health Organization – International Agency for Research on Cancer. Volume 49: “Chromium, Nickel and Welding, Summary of Data Reported and Evaluation”.

1997.

OEHHA, 1999. Office of Environmental Health Hazard Assessment. “Air Toxics Hot Spots Program Risk Assessment Guidelines, Part I, The Determination of Acute Reference Exposure Levels for Airborne Toxicants” . 1999.

OEHHA, 2002. Office of Environmental Health Hazard Assessment. “Air Toxics Hot Spots Program Risk Assessment Guidelines, Part II, Technical Support Document for Describing Available Cancer Potency Factors ”. 2002.

OEHHA, 2003. Office of Environmental Health Hazard Assessment. “Air Toxics Hot Spots Program Risk Assessment Guidelines, The Air Toxics Hot Spots Program Guidance Manual for Preparation of Health Risk Assessments ”. 2003.

UCR, 2003. Department of Mechanical Engineering, University of California, Riverside. “Draft Final Report: Validation of Concentrations Estimated from Air Dispersion Modeling for Source-Receptor Distances of less than 100 Meters". 2003.Chapter VIII Page 78



## VIII. Proposed Risk Reduction Approach and Benefits

D espite significant reductions in hexavalent chromium emissions, the cancer risks for some chromium plating and chromic acid anodizing facilities is still unacceptably high. This is largely due to the potent carcinogenicity of hexavalent chromium. As little as two grams of annual emissions can elevate the estimated cancer risk to ten per million exposed people. The location of many of the facilities also indicates that some low income and ethnically diverse communities in the State are disproportionately impacted by the emissions. This is of special concern given that 43 percent of facilities are located within100 meters of people. These factors compel staff to evaluate emission reduction

scenarios that minimize or eliminate the cancer risks.

As described in Chapter VI, staff has evaluated various alternative processes for hexavalent chromium plating and chromic acid anodizing to determine if cancer risk could be eliminated. While alternatives exist for some applications, their use is limited. Thus, we conclude that alternative technologies are not available to require a phase-out of the hexavalent chromium process at this time. However, our analysis also shows that effective emission reduction alternatives are readily available and these approaches minimize the cancer risk to the extent technology allows.



### A. Best Available Control Technology

Staff has evaluated BACT for chromium plating and chromic acid anodizing facilities. We also have evaluated the effectiveness of chemical fume suppressants through our emissions testing program. We have determined that add-on air pollution control devices with the final capture device being high efficiency particulate arrestor (HEPA) filters represents BACT for larger facilities, while use of chemical fume suppressants represents BACT for very small facilities. As described in Chapter VI, HEPA filters are rated at 99.97 percent efficient for collecting particles of 0.3 micrometers in diameter. Use of BACT for larger facilities would reduce hexavalent chromium emissions to no more than 0.0015 milligrams/ampere-hour. There is ample evidence to demonstrate that this is an effective method to reduce cancer risk. HEPA filter technology is already used in over 30 percent of the facilities to reduce hexavalent chromium emissions. In fact, we are aware that facilities currently using various combinations of controls, including HEPA filters, have emission rates lower than 0.0015 milligrams/ampere-hour.

By establishing this level of control, staff has found that emissions, and therefore cancer risk, can be minimized. This level of control is 85 percent more effective than the emission reductions achieved through use of chemical fume suppressants that have been shown to reduce emissions to no more than 0.01 milligrams/ampere-hour. Figure VIII-1 shows graphically the effectiveness of HEPA filters compared to chemical fume suppressants.Chapter VIII Page 79

Figure VIII-1 . Comparison of Cancer Risks (MICR) Remaining After Application of

Controls at Various Throughputs *

1 0.03 10 1 210

10 25

0 20 40 60 80 100 120 140 160 180 200MICR*

20,000 200,000 4,000,000 10,100,000

Ampere-hours 0.01 mg/amp-hr** 0.0015 mg/amp-hr***

* Results are for the inhalation pathway and calculated for a residential receptor with a 70-year exposure duration, 80th percentile daily breathing rate and Pasadena meteorological data set ** Emission rate of a chemical fume suppressant (emission rate 0.01 mg/amp-hr) modeled using a small

volume source *** Emission rate of a HEPA filtering system, (emission rate of 0.0015 mg/amp-hr) modeled using a small point source

Figure VIII-1 shows various throughputs and compares the estimated MICRs resulting if emissions are reduced using chemical fume suppressants and by using HEPA filters or equivalent controls. Note that a facility using a chemical fume suppressant with throughput of 20,000 ampere-hours per year would pose a cancer risk of no more than one per million exposed people. This is based on the maximum exposed individual, which for volume sources is at 20 meters. At this risk level, chemical fume suppressants represent BACT.

A facility using a chemical fume suppressant and operating 200,000 ampere-hours per year poses a cancer risk of ten per million exposed people. However, when BACT for intermediate and larger-sized facilities is used, estimated cancer risk is reduced to less than one per million exposed persons. HEPA filters or equivalent controls meeting the 0.0015 milligrams/ampere-hour limit represents BACT.

Figure VIII-1 also shows that a facility with throughput of 4.0 million ampere-hours would have an estimated cancer risk of 200 per million exposed persons if emissions were controlled with chemical fume suppressants alone. However, if BACT is used, cancer risk would be reduced to ten per million exposed people.

Finally, Figure VIII-1 shows that once a facility’s throughput exceeds 10.0 million amperehours, even after application of BACT, estimated cancer risk is greater than 25 per million exposed persons. This indicates that other risk reduction measures may be necessary for some facilities.Chapter VIII Page 80



### B. Emissions and Cancer Risk Reduction Benefits

Staff is proposing to amend the Chromium Plating ATCM by phasing in BACT. The timing for the application of BACT would be related to throughput and proximity to sensitive receptors. BACT for very small facilities would be defined as use of chemical fume suppressants.

The proposed amendments to the Chromium Plating ATCM are found in Appendix A to this report and are described in plain English in Chapter IX. As described below, staff estimates that by adopting this proposal estimated cancer risk from hexavalent chromium emissions could be reduced by up to 85 percent.

Very low throughput (less than 20,000 ampere-hours per year) facilities would be allowed to reduce hexavalent chromium emissions through use of specified chemical fume suppressants to lower surface tension of the plating or anodizing bath. This has been determined to be BACT for these facilities. Using specified chemical fume suppressants

to lower surface tension reduces hexavalent chromium emissions to 0.01 milligrams/ampere-hour. Remaining cancer risk for these facilities would be no more than one per million exposed people.

Application of BACT for all other facilities would require use of control technologies rated at 99.97 percent efficient for collecting particles of 0.3 micrometers in diameter. This is the control efficiency achieved through installation of a HEPA filter add-on air pollution control device. The emission limitation equivalent to this level of control would be 0.0015 milligrams/ampere-hour.

Intermediate-sized facilities (greater than 20,000 but less than 200,000 ampere-hours per year) would have five years to comply with the emission limitation if the facility is located more than 100 meters from a sensitive receptor. This would allow some small businesses more time to secure the necessary capital to purchase the needed equipment. To provide earlier protection for sensitive receptors, other intermediate-sized facilities located at or within 100 meters of a sensitive receptor would be required to meet the emission limitation in two years.

Industry representatives have indicated that combinations of in-tank controls such as chemical fume suppressants and polyballs may, in some cases, be able to reduceemissions to no more than 0.0015 milligrams/ampere-hour. Therefore, all intermediatesized facilities would be given the option to demonstrate compliance with the emission limitation without installation of add-on air pollution control devices. This proposal could reduce compliance costs for some small businesses. However, performance testingwould be required to demonstrate compliance. After full implementation, all intermediatesized facilities would have remaining cancer risk of no more than two per million exposed people.Chapter VIII Page 81

The largest facilities (more than 200,000 ampere-hours per year) would be required to comply with the emission limitation of 0.0015 milligrams/ampere-hour within two years using an add-on air pollution control device(s). Remaining cancer risk for these facilities would range from ten to no more than 61 per million exposed people. However, facilities with remaining cancer risk over 25 per million exposed people, would be required to conduct a refined assessment of their facility’s risk to determine if further risk reduction measures would be necessary.

Table VIII-1 below shows how excess cancer risk would be reduced beyond the risk reduction achieved by implementation of the current ATCM and air district rules.

Table VIII-1 . Adoption of Staff’s Proposal Significantly Reduces the Estimated Cancer

Risk from Hexavalent Chromium Emissions



### Number of Facilities by Cancer Risk

< 1 per million >1 < 10

per million >10 < 100

per million >100

per million Staff Proposal 162 41 17 0

Baseline 90 67 57 6

As shown in Table VIII-1, by adopting the staff’s proposal about 162 facilities (74 percent) would have remaining cancer risk of no more than one per million exposed persons. This represents an additional 72 facilities compared to the baseline. Only 17 facilities (about 8 percent) would have estimated cancer risk of over ten per million exposed people. No facilities would have cancer risk exceeding 100 per million exposed people. Under the staff’s proposal each facility with residual cancer risk over 25 per million exposed people would need to do a site specific analysis to determine if further control measures are needed. Total hexavalent chromium emissions from all chromium plating and chromic acid anodizing facilities would decrease, by 55 percent, to 1.8 pounds per year.

Off-site worker cancer risks were also evaluated. Table VIII-2 shows the remaining cancer risk for exposed off-site workers if the staff’s proposal were to be adopted.

Table VIII-2 . Adoption of Staff’s Proposal Significantly Reduces the Estimated Cancer

Risk from Hexavalent Chromium Emissions for Off-Site Workers



### Number of Facilities by Cancer Risk

< 1 per million >1 < 10

per million >10 < 100

per million >100

per million Staff Proposal 203 14 3 0

Baseline 113 70 36 1Chapter VIII Page 82

In addition to reducing cancer risk for everyone living near hexavalent chromium and chromic acid anodizing facilities, as shown in Table VIII-2, the proposal would also provide health benefits for off-site workers. As shown, 92 percent or 203 facilities would have cancer risk of no more than one per million exposed off-site workers. This is an additional 90 facilities compared to the 2005 baseline.

These estimates of cancer risk remaining after implementation of the staff’s proposal could be either higher or lower. Factors such as meteorology and release characteristics of a facility could change the outcome. Additionally, the cancer risk estimates are based on a fixed distance, and a facility may or may not have a receptor at that location. If a receptor were located less than 20 meters from a facility, their cancer risk could be higher. If a receptor were located more than 20 meters from a facility, their cancer risk could be lower. Twenty meters is the minimum air dispersion modeling distance used by the ARB in the Air Toxics Program.



### C. Other Aspects of the Staff’s Proposal

Another goal of the amendments is to ensure that new facilities are isolated from sensitive receptors. As discussed previously, we have learned that emissions of hexavalent chromium have the greatest impact on people living near chromium plating and chromic acid anodizing facilities. Our data show that 43 percent of the chromium plating and chromic acid anodizing facilities are located within 100 meters of a sensitive receptor. To prevent future situations such as this, staff is proposing that any new chromium plating or chromic acid anodizing facility not be allowed to operate in an area zoned residential or

mixed use or within 150 meters of an area zoned residential or mixed use. At this distance, 150 meters, (~500 feet), modeling for point sources shows that the hexavalent chromium concentration has dropped off by about 80 percent.

Nevertheless, staff is also proposing that facilities would have to conduct a site specific health risk assessment to ensure that public exposure to emissions from the new source, will be below the air districts’ levels of significance contained in health risk rules and policies. This proposal provides a margin of safety and accounts for situations where receptors may move in closer to a facility.

While they cannot be quantified because of variation from facility to facility, fugitive dust emissions also likely impact people residing near chromium plating and chromic acid anodizing facilities. Information on fugitive dust emissions is contained in Chapter V. Therefore, staff is proposing that all facilities would need to implement housekeeping measures to reduce dust emissions. We have found that fugitive emissions related to poor housekeeping can be an additional source of hexavalent chromium emissions.

Training explaining the Chromium Plating ATCM and the requirements, conducted by ARB staff, would be required every two years for employees responsible for compliance at chromium plating and chromic acid anodizing facilities. An exception to this requirement would be personnel that had attended the SCAQMD’s training class for

Rule 1469.Chapter VIII Page 83

The proposal would also prohibit the sale or use of chromium plating or chromic acid anodizing materials unless sold or used by individuals or businesses under air district permit to conduct such operations.

All of these proposals, as well as the provisions necessary to implement them, are described further in Chapter IX.Chapter IX Page 84



## IX. Proposed Amendments and Alternatives

S taff is proposing to amend the Chromium Plating ATCM (title 17, California Code of Regulations, section 93102). As described below, the amended ATCM will now be contained in sections 93102 through 93102.16. The amendments are being proposed to further reduce the public's exposure to emissions of hexavalent chromium. If adopted, the staff’s proposal would reduce the estimated cancer risk by up to 85 percent. This Chapter is provided to describe, in “plain English,” the changes being proposed. The rationale for the proposal is also described. The text of the proposed amendments to the ATCM can be found in Appendix A to this staff report. This Chapter also discusses alternative emission reduction approaches that were evaluated.



### A. Summary of the Existing Airborne Toxic Control Measure

Chromium plating and chromic acid anodizing facilities have been regulated to control hexavalent chromium emissions since 1988 when the ATCM was first adopted. The regulation established different limits based on facility throughput and type of operation. Hard chromium plating and chromic acid anodizing facilities, except for small hard chromium plating facilities, were required to control hexavalent chromium emissions by meeting emission limitations using add-on air pollution control devices. The stringency of the limits depended on throughput, with the highest volume facilities meeting the most restrictive limit. Decorative chromium plating facilities, on the other hand, were required to control hexavalent chromium emissions, but to a lesser extent than hard chromium plating facilities. Most decorative chromium plating facilities chose to comply by using chemical fume suppressants.

The regulation was amended in 1998 to incorporate changes necessary for equivalency with the federal Chromium Plating NESHAP. This included changing the requirements for chromic acid anodizing facilities to harmonize them with the requirements for decorative chromium plating facilities, and requiring control of emissions from trivalent chromium plating facilities.



### B. Summary of the Proposed Amendments

The staff is proposing a complete renumbering of the Chromium Plating ATCM. Rather than having alphabetized subsections to section 93102, staff is proposing to number sections consecutively in order to make the regulation easier to read. For example, previous subsection (a) would be renumbered to section 93102.1. This convention would be followed throughout the ATCM.

Section 93102 would set forth the organization of the regulation and clarify where requirements pertaining to a specific facility could be found. The reorganized ATCM would be contained in sections 93102 through 93102.16.Chapter IX Page 85

1. Section 93102.1--Applicability

Applicability requirements were previously contained in subsection (a). We are proposing a modification to the Applicability section. Originally the regulation’s applicability was to “each chromium electroplating or chromic acid anodizing tank at a facility.” Staff is proposing that the regulation applies to any owner or operator of a facility performing hard chromium electroplating, decorative chromium electroplating, or chromic acid anodizing. We are proposing this change to clarify that the requirements apply facility-wide. Ultimately, compliance responsibility is placed upon the owner or operator, therefore, this change would provide clarification.

Other changes are proposed to section 93102.1. We are also proposing to extend the applicability of the ATCM to manufacturers or distributors of chromium plating or chromic acid anodizing kits. This is necessary to implement other provisions of the proposal.

Staff is proposing a provision that would allow the ATCM to remain in effect if an individual part of the ATCM is found to be invalid. This severability provision is contained in many ARB regulations and is designed to insure that the control of hexavalent chromium emissions will continue even if a particular provision of the ATCM is held to be invalid by a court.

2. Section 93102.2--Exemptions

Exemptions were previously contained in subsection (a). We are not proposing any new exemptions within the ATCM. The proposal would move the existing exemptions to their own section. Generally, the exemptions exclude process tanks where chromium plating or chromic acid anodizing does not occur. The exemptions also clarify that the provisions for inspection and maintenance do not apply during breakdown conditions.

3. Section 93102.3--Definitions

Definitions were previously contained in subsection (b). Staff is proposing to modify a number of definitions, and is also proposing several new definitions necessary to implement other proposals in the regulation. The modified definitions are intended to further clarify the existing definitions. The proposed amended definitions are shown in

Table IX-1 below.Chapter IX Page 86

Table IX-1 . Definitions Proposed for Modification

Base metal Modification Chromic acid anodizing Foam blanket Chromium electroplating or chromic acid anodizing tank Hard chromium electroplating or industrial chromium electroplating Composite mesh-pad system High Efficiency Particulate Arrestor (HEPA) filter Decorative chromium electroplating Mechanical fume suppressant

Emission limitation Packed-bed scrubber

Facility Stalagmometer

Fiber-bed mist eliminator Tensiometer

One definition proposed for amendment, “Modification,” warrants a further explanation. The definition for “Modification” is intended to describe changes to a facility that would trigger additional requirements. Presently, a facility is not considered “Modified” if throughput increases, as long as the maximum design capacity of the equipment is not exceeded. One amendment proposed by staff would define a modification as a change in throughput that would cause a facility to be subject to a different emission limitation. We are also proposing that changes to a permit unit or addition of a permit unit that does not

increase hexavalent chromium emissions would not be considered a modification. These changes are necessary to implement the emission limit requirements in section 93102.4.

Several new definitions are proposed to implement other proposals in the Chromium Plating ATCM. Other definitions are proposed to further clarify the ATCM. The proposed

new definitions to be added are shown in Table IX-2.

Table IX-2 . New Definitions Proposed for Addition Annual Permitted Ampere-hour Modified Facility Dragout New Facility Enclosed storage area Owner or Operator

Enclosed hexavalent chromium electroplating tank Permitting Agency

Existing Facility Person

Fugitive dust Sensitive receptor

Initial start-up Tank

Most of these proposed new definitions are necessary to implement housekeeping requirements and other measures designed to reduce emissions of hexavalent chromium laden fugitive dust. Other proposed definitions are designed to clarify what constitutes an existing, new or modified facility, and others define those responsible for compliance or oversight.

One new definition proposed, “Sensitive receptor,” warrants further explanation. A sensitive receptor is proposed to be defined as “any residence including private homes, condominiums, apartments, and living quarters; education resources such as preschoolsChapter IX Page 87

and kindergarten through grade twelve (K-12) schools; daycare centers; and health care facilities such as hospitals or retirement and nursing homes. A sensitive receptor includes long term care hospitals, hospices, prisons, and dormitories or similar live-in housing.” This is the same definition used in the ATCM to Reduce Emissions of Hexavalent Chromium and Nickel from Thermal Spraying (title 17, CCR, section 93102.5), which was adopted by the Board in 2005. The definition is necessary to implement the proposed hexavalent chromium emission limit requirements in subsection 93102.4. As will be explained below, the requirements to control hexavalent chromium emissions will be phased in on different dates depending on a facility’s distance to a sensitive receptor. Data show that sensitive receptors located in close proximity to hexavalent chromium plating or chromic anodizing facilities are at greater risk of exposure to elevated levels of hexavalent chromium. Note that as proposed, a residence would beconsidered a sensitive receptor. This is because children, the elderly, and other healthcompromised individuals are often located in residences.

4. Section 93102.4--Emission Limits

Emission limitations for hexavalent chromium were previously contained in subsection (c) and would now be contained in section 93102.4. A number of organizational changes are proposed including renaming the section to “Requirements for Existing, Modified, and New Hexavalent Chromium Plating and Chromic Acid Anodizing Facilities.” Other organizational changes are necessary to clarify that the existing limits would remain in effect until the proposed new limits would become effective. The section would be divided into requirements that continue to apply until the new requirements

become effective.

a. Proposed subsection (a), Existing Hexavalent Chromium Limits

In section 93102.4, clarifying language is proposed to help the owner or operator to understand when the existing limits would no longer be effective and when compliance with the newly proposed limits would be required. As proposed, subsection 93102.4(a) would contain the current limits for existing hexavalent chromium facilities, and the limits for new or modified facilities up until the effective date of the new limits. Subsection (a)(1) applies to hard chromium plating facilities while subsection (a)(2) applies to decorative chromium plating and chromic acid anodizing facilities. Language is also proposed to specifically list all of the sections that contain other requirements that must be complied with, in addition to the limits set forth in section 93102.4.

b. Proposed subsection (b), New Hexavalent Chromium Limits

Proposed subsection (b) would contain the proposed new requirements for existing

hexavalent chromium facilities to reduce emissions. Rather than continued bifurcation of requirements, staff is proposing that all facilities using the hexavalent chromium process, whether they perform decorative plating, hard plating, or chromic acid anodizing, would be subject to the same requirements. Based on emissions testing results, staff believes

that uncontrolled emissions from these sources are similar and that each source of

hexavalent chromium emissions should be controlled in the same manner and to theChapter IX Page 88

same degree. Also, based on our analysis of health risks in Chapter VIII, staff is also proposing that limits be phased in based on throughput, cancer risk, and proximity to sensitive receptors.

The proposed amendments to the ATCM would require best available control technology (BACT) to further reduce the public’s exposure to hexavalent chromium from chromium plating and chromic acid anodizing facilities. BACT would apply to all facilities over time. For very small facilities BACT is use of specific chemical fume suppressants. BACT for all other facilities is a HEPA filtration system, or equivalent control. The requirements that would apply to each class of facility are specified in Table 93102.4, and are described

below.

Very low throughput (< 20,000 ampere-hours per year) facilities would be allowed to reduce hexavalent chromium emissions through use of specified chemical fume suppressants to lower surface tension of the plating or anodizing bath. This represents BACT for these facilities. Using specified chemical fume suppressants to lower surface tension reduces hexavalent chromium emissions to 0.01 milligrams/ampere-hour. Alternatively, these facilities may choose to comply by installing add-on air pollution control devices. Staff estimates that using specified chemical fume suppressants would result in a remaining cancer risk of no more than one per million people exposed. The chemical fume suppressants to be used for compliance are displayed in Table 93102.8 of

section 93102.8.

Application of BACT for all other facilities would require use of control technologies rated at 99.97 percent efficient for collecting particles of 0.3 micrometers in diameter. This is the control efficiency achieved through installation of a HEPA filter add-on air pollution control device. The emission limitation equivalent to this level of control would be 0.0015 milligrams/ampere-hour. Staff is also proposing that intermediate-sized facilities be allowed to control emissions with devices other than HEPA filters, as long as a performance test demonstrates hexavalent chromium emissions to be no more than 0.0015 milligrams/ampere-hour. The timing for requiring compliance would be based on annual ampere-hours, health risk, and proximity to sensitive receptors.

Intermediate-sized facilities (> 20,000 and < 200,000 ampere-hours per year) would have five years to comply with the emission limitation if the facility is located more than100 meters from a sensitive receptor. To protect sensitive receptors, other intermediatesized facilities located at or within 100 meters of a sensitive receptor would be required to meet the emission limitation in two years. All intermediate-sized facilities would be given the option to demonstrate compliance with the emission limitation without installation of add-on air pollution control devices. These proposals are designed to potentially reduce compliance costs for smaller businesses. Staff estimates that meeting the emission limit of 0.0015 milligrams/ampere-hour would result in a remaining cancer risk of no more than one per million people exposed.

The largest facilities (> 200,000 ampere-hours per year) would be required to comply with the emission limitation of 0.0015 milligrams/ampere-hour within two years using an add-on air pollution control device(s). After meeting the emission rate, we estimate thatChapter IX Page 89

85 percent of larger facilities would have a remaining cancer risk of less than 10 per million people exposed. Less than one percent of facilities would have cancer risk of more than 25 per million people exposed. Those facilities with cancer risk of over 25 per million would be required to conduct an additional risk analysis, based on the individual facility’s specific conditions and parameters to determine if further risk reduction would be required. Staff estimates that about 15 grams of emissions from a small point source would result in a cancer risk of over 25 per million people exposed. This site specific analysis could lead to measures to further reduce cancer risk.

Table IX-3 summarizes the requirements for compliance with the emission limitations. In the regulation, this table is labeled “Table 93102.4” and is set forth in section 93102.4.

Table IX-3 . Proposed Hexavalent Chromium Emission Limits for Existing Facilities

Tiers of

Annual

Permitted Ampere-Hours Sensitive

Receptor

Distance 1 Emission Limitation Effective Date

Tier 1
< 20,000 Any Use Chemical Fume Suppressant as specified in section 93102.8 2 [Six Months after Effective Date]

Tier 2 > 20,000 and
< 200,000 < 100

Meters 0.0015 milligrams/ampere-hour 3 [Two Years after Effective Date]

Tier 3 > 20,000 and
< 200,000 > 100

Meters 0.0015 milligrams/ampere-hour 3 [Five Years after Effective Date]

Tier 4
> 200,000 Any 0.0015 milligrams/ampere-hour 4, 5 [Two Years after Effective Date]

1 Distance shall be evaluated by the permitting agency.

2 Alternatively, [Two Years after Effective Date] facility shall comply with the requirement for facilities with > 20,000 and < 200,000 annual permitted ampere-hours.

3 Emission limit compliance can be demonstrated without add-on air pollution control device.

4 Measured after add-on air pollution control device.

5 When actual annual emissions exceed 15 grams, a site specific analysis must be conducted in accordance with the permitting agency’s procedures.

In proposed subsection 93102.4(b)(2), language is provided to explicitly indicate that facilities within Tier 2 or Tier 3 can demonstrate compliance without using an add-on air pollution control device. However, at a minimum, these facilities would have to use the chemical fume suppressants specified in section 93102.8. This subsection would also specify that facilities in Tier 4 would be required to use an add-on air pollution control device to demonstrate compliance.Chapter IX Page 90 c. Proposed subsection (c), Modified Facilities

As mentioned above in the ‘Definitions’ section, staff is proposing to change the definition of ‘Modification’ to include increases in throughput (measured as ampere-hours) that would result in the facility moving to a different tier of control. To protect public health, a facility wishing to modify operations would be required to control hexavalent chromium emissions by installing an add-on air pollution control device to reduce hexavalent chromium emissions to a rate of no more than 0.0015 milligrams/ampere-hour.

To evaluate if a facility continues to pose an unacceptable health risk after installation of state-of-the-art add-on air pollution control devices, an additional requirement is proposed. Facilities whose emissions exceed 15 grams per year would need to conduct a site specific analysis to determine if further risk reduction measures are necessary. Staff estimates that about 15 grams of emissions from a small point source would result in a cancer risk of over 25 per million people exposed.

d. Proposed subsection (d), New Facilities

As explained in Chapter I, chromium plating and chromic acid anodizing operations can create “Hot Spots,” with emissions that have a maximum impact near-source. Our data also show that 43 percent of existing facilities are located near people, which has led to unacceptable exposures to hexavalent chromium emissions. To avoid future situations where residential units or sensitive receptors are located in very close proximity to a chromium plating or chromic acid anodizing facility, staff is proposing that a new facility cannot operate in an area zoned for residential or mixed use. In addition, the facility also could not operate within 150 meters from the boundary of any area zoned as residential or mixed use. Modeling results indicate that at this distance the concentration of the hexavalent chromium emissions has been reduced to about 20 percent of the original

near source concentration.

However, staff is proposing to include provisions that the new facility would be deemed to meet this requirement as long as the facility met the separation requirement when the authority to construct was issued by the permitting agency (and substantial use of the authority to construct takes place within one year after it is issued), or met the requirement before any land use zoning changes occur.

Even with this separation requirement, staff is proposing that any new facility would be required to control hexavalent chromium emissions by installing a HEPA add-on air pollution control device and demonstrate that the hexavalent chromium emission rate after the HEPA add-on air pollution control device is no more than 0.0015 milligrams/ampere-hour. Under the proposal, all new facilities would be required to conduct a site-specific analysis to determine if further risk reduction measures are

necessary.Chapter IX Page 91 e. Proposed subsection (e), Notification Requirements for New and

Modified Sources

The requirements of proposed subsection 93102.4(e) have been moved from former subsection (j). Minor modifications to the language were also made to improve clarity. These requirements, relating to new and modified facilities, specify other requirements that must be met prior to a facility undergoing modification or prior to a new facility beginning operation.

5. Proposed Section 93102.5--Additional Requirements

Within new section 93102.5, requirements are proposed that apply to all hexavalent chromium plating and chromic acid anodizing facilities ( i.e. , all existing, modified, and new facilities).

Staff is proposing, in subsection (a), that any facility with an add-on air pollution control device(s) could not remove the device, unless it is replaced with an add-on air pollution control device(s) meeting an emission rate of 0.0015 milligrams/ampere-hour. Requiring that the add-on air pollution control device remain in place provides an extra margin of safety.

ARB staff recognizes that the ATCM has many requirements that may be difficult to understand or carry out correctly without training. Staff also knows that following the requirements are necessary to control hexavalent chromium emissions effectively. Therefore, in subsection (b), we are proposing that every two years personnel designated by the owner or operator as responsible for environmental compliance must attend an ARB training class explaining how to comply. An exception to this requirement would be personnel that had attended the SCAQMD’s training class for Rule 1469, which is also required every two years.

Fugitive emissions, essentially dust containing hexavalent chromium, can be an important contributor a facility’s overall emission impact. While these emissions are difficult to quantify, we nevertheless believe measures are necessary to minimize these fugitive emissions. We are therefore proposing housekeeping measures in subsection (c) to reduce the mechanisms by which hexavalent chromium may be accidentally splashed or spilled, and are also proposing housekeeping measures to reduce dust that may become

re-entrained into the ambient air.

To limit the generation of hexavalent chromium dust, staff’s proposal includes:

• Storing chemicals such as chromic acid in closed containers in enclosed storage

areas;

• Transporting chemicals to the plating or anodizing bath in closed containers;

• Cleaning up or containing liquid or solid spills that may contain hexavalent chromium within an hour of the spill occurring;

• Minimizing dragout by: - For automated lines: requiring drip trays between tanks;Chapter IX Page 92

- For manual lines: requiring that dragout be minimized. When parts are sprayed off over the tank with fresh water, a splash guard would be required to ensure water from the part rinsing is returned to the tank;

• Cleaning of surfaces, such as floors, walkways around tanks, and storage areas that potentially are contaminated with hexavalent chromium at least once every seven days;

• Installing a barrier, such as plastic strip curtains, to separate buffing and grinding areas from the plating tank area; and

• Requiring that all waste/dust from housekeeping practices be disposed of properly

as hazardous waste.

6. Proposed Section 93102.6--Requirements for Trivalent Chromium Baths and Enclosed Hexavalent Chromium Electroplating Facilities

The requirements for trivalent chromium plating facilities were previously contained in subsection (c). Proposed new section 93102.6 would specify the requirements for facilities electroplating with the trivalent chromium process and for facilities employing an enclosure around the plating tank to control hexavalent chromium emissions.

Generally, the requirements for facilities plating with trivalent chromium would be unchanged (subsection (a)). However, even though trivalent chromium is not considered a carcinogen, its use is not without some health impacts. Therefore, we are proposing that the separation requirements (in section 93102.4(d)(1)) for new hexavalent chromium facilities also apply to new trivalent chromium plating facilities.

Like the provision for new hexavalent chromium plating or chromic acid anodizing facilities, no new trivalent chromium facility could operate if it were located within an area zoned residential or mixed use, or if it were to be located within 150 meters from the boundary of any area zoned residential or mixed use.

Subsection 93102.6(a) also specifies which requirements of the ATCM an owner or operator of a trivalent chromium plating facility does not need to comply with.

The requirements in subsection (b) relating to enclosed hexavalent chromium tanks are being proposed to incorporate changes to the federal Chromium Plating NESHAP. As described by U.S. EPA, ventilation rates for enclosed tanks are considerably lower than ventilation rates for conventional ventilated facilities. Because of this, some facilities with enclosed tanks had difficulty meeting the chromium emission concentration limit specified in the Chromium Plating NESHAP, even when emissions from those tanks are well controlled. To rectify the situation, U.S. EPA adopted a separate alternative mass emission rate limit for chromium electroplating tanks equipped with enclosing hoods (U.S. EPA, 2004). We are proposing to add these provisions to the Chromium Plating ATCM.

Alternatively, these facilities may opt to comply with an emission rate of 0.0015 milligrams per dry standard cubic meter of air as measured after the add-on air pollution control device, or use a specified chemical fume suppressant.Chapter IX Page 93

New enclosed hexavalent chromium plating facilities would also be subject to the separation requirements described above for new trivalent chromium plating facilities.

7. Proposed Section 93102.7--Performance Testing and Test Methods

Performance testing and test methods were previously contained in subsection (d). Many of the proposed new regulatory requirements require facilities to determine the actual hexavalent chromium emission rate after the add-on air pollution control device(s). In this subsection, we are specifying the facilities that would have to conduct a performance (source) test to demonstrate compliance. As proposed, the following types of facilities

would need to conduct a source test:

• Existing facilities demonstrating compliance with the 0.0015 milligrams/amperehour hexavalent chromium emission limitation;

• Facilities that undergo modification;

• Any new facility; and

• Trivalent chromium plating facilities meeting the emission rate in subsection 93102.6(a)(1).

All of these types of facilities would have to conduct the performance test within 60 days of initial start-up using an approved test method.

Facilities would be able to use an existing source test if it was conducted after January 1, 2000, and the test demonstrated an emission rate of 0.0015 milligrams/ampere-hour, or less. The test would need to have been approved by the permitting agency using an approved test method. The test results would also need to be representative of the air pollution control device(s) currently in use.

Minor modifications are proposed to subsections (c) and (d). One modification to the Approved Test Methods in subsection (c) would clarify that any performance test must include three test runs. Under another proposal, to measure surface tension with a tensiometer continued use of U.S. EPA Method 306-B would be required. When measuring surface tension with a stalagmometer, the method in new proposed Appendix 8, or a method approved by the permitting agency would need to be used. Identifying a specific procedure will provide more accurate and uniform results. In subsection (d), clarifying language is proposed to identify that the pre-test protocol is to be submitted to the permitting agency.

8. Proposed Section 93102.8--Chemical Fume Suppressants Used for Compliance

Results of our emissions testing program, along with results from the SCAQMD certification program, demonstrated that certain chemical fume suppressants were more efficient than others at reducing hexavalent chromium emissions. To ensure maximum reduction of hexavalent chromium from facilities using chemical fume suppressants, staff is proposing to specify the types of chemical fume suppressants that could be used to reduce surface tension. The chemical fume suppressants that could be used are listedChapter IX Page 94

below in Table IX-4, along with the surface tension at which they must be used. Based on our emissions testing program and analysis of results from the SCAQMD Fume Suppressant Certification Program (SCAQMD, 2004), staff has determined that the chemical fume suppressants listed in Table IX-4 are most efficient for preventing emissions of hexavalent chromium. In the regulation, Table IX-4 is labeled “Table 93102.8” and is set forth in section 93102.8(a).

Table IX-4 . Chemical Fume Suppressants Approved for Use at Specified Surface Tensions

Chemical Fume Suppressant and

Manufacturer Stalagmometer

Measured

Surface Tension (dynes/centimeter) Tensiometer

Measured Surface

Tension (dynes/centimeter)

Benchbrite CR 1800®

Benchmark Products < 40 < 35 Clepo Chrome®

MacDermid < 40 < 35

Fumetrol 140®

Atotech U.S.A. < 40 < 35

Staff is also proposing that additional chemical fume suppressants may be used upon approval by the ARB Executive Officer, if specified criteria are met. A provision to revoke use of a specified chemical fume suppressant, if it is found to no longer meet an emission rate of 0.01 milligrams/ampere-hour or less, is also proposed. This provision is necessary to protect public health.

9. Proposed Section 93102.9--Parameter Monitoring

Parameter monitoring requirements were previously contained in subsection (e). Minor changes are proposed to section 93102.9, Parameter Monitoring, to clarify existing provisions.

10. Proposed Section 93102.10--Inspection and Maintenance Requirements

Inspection and maintenance requirements were previously contained in subsection (f). Changes are proposed to section 93102.10, Inspection and Maintenance Requirements, to consolidate the requirements where appropriate. A new provision is proposed for facilities that have custom designed add-on air pollution control devices. The owner or operator of such a facility would be required to develop operation and maintenance requirements for review and approval by the permitting agency.Chapter IX Page 95

11. Proposed section 93102.11--Operation and Maintenance Plan Requirements

Operation and maintenance plan requirements were previously contained in subsection (g). Minor modifications are proposed to section 93102.11. The proposed changes are necessary to update citations for other subsections which have been reorganized.

12. Proposed section 93102.12--Recordkeeping

Recordkeeping requirements were previously contained in subsection (h). Minor modifications are proposed to section 93102.12, Recordkeeping. Most of the modifications clarify the provisions or update citations within the ATCM. Also, as proposed, section 93102.12, would be modified to specify additional records that must be kept. Facilities would be required to maintain monthly records of total ampere-hour usage per calendar year to verify compliance with the emission limit that corresponds to the ampere-hour thresholds. In addition, facilities would be required to keep records documenting that the proposed housekeeping requirements are met.

13. Proposed section 93102.13--Reporting

Reporting requirements were previously contained in subsection (i). Minor changes are proposed to subsections (a) through (d) of section 93102.13, Reporting. These changes would clarify the information to be reported or specify when reports are to be submitted to the permitting agency. The staff is proposing to modify subsection (e) to identify the information that must be submitted to the permitting agency for existing facilities using trivalent chromium and for new facilities using the trivalent chromium process.

14. Proposed section 93102.14--Procedure for Establishing Alternative Requirements

Procedures for establishing alternative requirements were previously contained in subsection (k). Minor modifications are proposed in subsections (a) through (e) of section 93102.14, Procedure for Establishing Alternative Requirements. In subsection (f), we are proposing that waivers obtained from U.S. EPA for alternative compliance with the emission limits will no longer be valid after the date of the requirements in section 93102.4(b) become effective for a particular facility. This modification is necessary to ensure all facilities meet the new requirements. We are also proposing that ARB would have to concur on any waivers associated with alternatives to compliance with section 93102.4, Requirements for Existing, Modified, and New Hexavalent Chromium Plating and Chromic Acid Anodizing Facilities.

15. Proposed section 93102.15--Requirements Related to Chromium Plating or Chromic Acid Anodizing Kits

Staff is proposing requirements related to chromium plating kits. We are aware that these kits are currently offered for sale over the Internet. Because no restrictions exist on whoChapter IX Page 96

may buy these kits, they may be sold or supplied to a person that is not trained or aware of the hazards associated with chromium plating or chromic acid anodizing. These kits

also could be a source of uncontrolled hexavalent chromium emissions. This could lead to unacceptable exposures for the individual performing the chromium plating or chromic acid anodizing, or for near-by sensitive receptors.

Because of these hazards, staff is proposing that these chromium plating or chromic acid anodizing kits could not be sold, supplied, offered for sale, or manufactured for sale in California. However, this provision would not apply if the kit was sold to the owner or operator of a permitted chromium plating or chromic acid anodizing facility.

These kits also could not be used unless the kit is used at a permitted chromium plating or chromic acid anodizing facility that is in full compliance with the ATCM.

We are also proposing that for the purposes of these provisions a “chromium electroplating or chromic acid anodizing kit” means chemicals and associated equipment for conducting chromium electroplating or chromic acid anodizing, including, but not limited to, internal and external tank components.

16. Proposed section 93102.16--Appendices

Staff is proposing that the Appendices to the Chromium Plating ATCM be contained within a new section, 93102.16. There are eight appendices. Most of these have been part of the Chromium Plating ATCM since 1998. Only the Appendices proposed for modification or addition are described. Appendix 1, Content of Performance Test Reports, is proposed for modification to indicate that test results must be provided in milligrams/ampere-hour.

Appendices 2 and 3, Content of Initial Compliance Status Reports, and Content of Ongoing Compliance Status Reports, respectively, are being modified to ensure that the permitting agency has all of the necessary information to ensure facilities are complying with all of the newly proposed provisions and requirements.

We are proposing to add a requirement to Appendix 4, Notification of Construction Reports, to ensure that any new facility is complying with the provisions for new facilities in section 93102.4(d), such as the separation requirements.

We are proposing to add Appendix 7, Alternative Requirements for Enclosed Hexavalent Chromium Electroplating Facilities- Mass Emission Rate Calculation Procedure. The calculation method shown in the appendix is used to demonstrate compliance with the alternative emission limit for enclosed tanks specified in subsection 93102.6(b)(1)(C).

We are also proposing to add Appendix 8, Surface Tension Procedure for a Stalagmometer. This appendix outlines a method to be followed to ensure accurate and consistent measurement of surface tension with a stalagmometer.Chapter IX Page 97

17. When the Proposed Amendments Become Legally Effective

In addition, we would like to clarify that the proposed amendments to the ATCM do not impose retroactive requirements on chromium plating and anodizing facilities. California law is clear that the proposed amendments to the ATCM cannot become legally effective until it is adopted by the ARB and is approved by the Office of Administrative Law. Until then, chromium plating and chromic acid anodizing facilities are not required to comply with any requirement specified in the amended ATCM, unless an air district independently imposes the same or similar requirement pursuant to its own local rules or permitting authority.



### C. Basis for the Proposed Amendments

The proposed amendments to the Chromium Plating ATCM are based on our reevaluation of BACT for reducing hexavalent chromium emissions from chromium plating and chromic acid anodizing facilities, in consideration of health risk and cost. In reevaluating BACT, we analyzed information from ARB’s 2003 chromium plating and chromic acid anodizing facility survey, available source test data, and data from the emissions testing program.

As a basis for the proposal, staff conducted the HRA to determine estimated cancer risks in a manner which is very health protective in estimating cancer risks for a range of reasonably foreseeable exposure scenarios. Staff believes this health protective approach is necessary due to the very high potency and resultant serious health hazards associated with exposure to hexavalent chromium emissions.

Based on the information collected, the health protective analyses conducted, and discussions with air districts, industry, and control equipment manufacturers, we determined that reliable control devices are readily available and widely used. Further, the application of BACT, as proposed by staff, will result in potential cancer risk levels being reduced to no more than one per one million people for 162 facilities (about 75 percent). An additional 41 facilities (about 20 percent), would have estimated cancer risk of no more than ten per million exposed people. Moreover, only six facilities would have a remaining cancer risk greater than 25 per million exposed people. Staff’s proposal to require a site specific analysis, for review by the air districts, could result in further cancer risk reduction from these facilities. Overall 92 percent of the facilities would have cancer risk of no more than ten per million exposed people. In addition, the proposed

amendments would ensure that the chronic hazard indices for all facilities would not

exceed one.



### D. Alternatives to the Proposed Amendments

California Government Code section 11346.2 requires the ARB to consider and evaluate reasonable alternatives to the proposed amendments to the ATCM and to provide reasons for rejecting these alternatives. Staff considered the following alternatives to the proposed amendments to the ATCM:Chapter IX Page 98

1. Alternative 1: Require Decorative Chromium Plating Facilities to Use the Trivalent Chromium Plating Process

One alternative to the staff’s proposal would be to require the use of the trivalent chromium plating process for all decorative chromium plating facilities. The process is already in use successfully in ten businesses (six facilities only conduct trivalent chromium plating and four facilities conduct both trivalent and hexavalent chromium plating) in California. Requiring all decorative chromium facilities to use the trivalent chromium process would eliminate the remaining cancer risk from the hexavalent chromium emissions from decorative chromium plating facilities. In fact, the switch to the trivalent chromium process could be more cost effective than the staff’s proposal, which would require installation of BACT (HEPA add-on air pollution control device). As estimated, installation and annual operating costs for a HEPA system are estimated at about $89,000 and $33,500 respectively. Our cost estimate for converting to trivalent chromium includes a one-time cost of about $41,500 and ongoing costs of $23,000. Under the staff’s proposal, there will be residual cancer risk. However, 162 facilities would have estimated cancer risks of one or less per million exposed people after adoption of the staff’s proposal. Overall, 92 percent of facilities would have cancer risk of less than ten per million exposed people.

Staff has evaluated the trivalent chromium process and has determined that it is not a universal replacement for all decorative chromium plating applications. Also, use of the trivalent chromium process would create business competitiveness issues between California businesses and those in other States, and between California businesses and those off-shore. Therefore, staff has determined this is not a technologically feasible

alternative.

Nevertheless, businesses may make the decision to convert to the trivalent chromium process, if it is a viable option for their application.

2. Alternative 2: Require HEPA, or the Equivalent, Add-On

Air Pollution Control Device for All Facilities

Another alternative would be to require installation of HEPA, or equivalent, add-on air pollution control devices for all facilities. This technology is the most effective option. Implementation of this proposal would reduce the remaining cancer risk from about 48 facilities that presently have throughput below 20,000 annual ampere-hours. Staff chose not to pursue this alternative. The staff’s proposal represents a balance between health risk and cost. For these facilities, chemical fume suppressants represent BACT. Adoption of the staff’s proposal will result in these facilities having estimated cancer risks below one per million people. This alternative would result in no appreciable additional benefit and would add additional equipment costs of over $4.0 million. Individual businesses would have annual costs of about $46,000. About half of these facilities are small businesses with annual revenue of less than $1,000,000.Chapter IX Page 99

3. Alternative 3: Adopt the Provisions of Rule 1469 Statewide

Industry representatives have asked staff to evaluate the adoption of SCAQMD Rule 1469 statewide. Rule 1469, Control of Hexavalent Chromium Emissions from Chrome Plating and Chromic Acid Anodizing Operations, is now in full effect in the SCAQMD. Rule 1469 requires hexavalent chromium facilities located within 25 meters from a sensitive receptor or within 100 meters from a school to reduce

hexavalent chromium emissions such that the residential cancer risk will be no more than ten chances per million people. The rule also requires facilities located greater than 25 meters from a sensitive receptor or 100 meters from a school to reduce emissions such that off-site worker cancer risk would be no more than 25 chances per million people.

Staff has evaluated this alternative and has found it does not provide the level of protection that would be achieved through adoption of the staff’s proposal. This is because BACT is not required for all facilities. By using off-site worker scenarios to calculate cancer risk, rather than residential, the risk to people and children living near the facility is underestimated by one-third. This means that estimated cancer risk for residents is 33 per million people exposed, rather than 25 per million people exposed.

ARB could not use this scenario because it does not follow standard risk assessment methodologies developed by OEHHA and employed by ARB.

If Rule 1469 were implemented statewide, 75 percent of facilities would have estimated cancer risk of less than ten per million exposed people. This offers very little benefit over the baseline in which 71 percent of facilities were found to have estimated cancer risk of ten per million exposed people. The staff’s proposal would result in 92 percent of facilities having estimated cancer risk of less than ten per million exposed people. In addition, if Rule 1469 were adopted statewide, eight percent of facilities would have cancer risk of over 25 per million exposed people. Two facilities’ risk would exceed 100 per million exposed people. This is not health protective given the availability of BACT. If the staff’s proposal were adopted, no facilities would have cancer risks over 100 per million exposed people. A comparison of the benefits of adopting Rule 1469 statewide and the benefits of the staff’s proposal as shown in Figure IX-1.

Adoption of Rule 1469 statewide would, however, result in cost savings over the staff’s proposal. Equipment costs would be about $600,000 because only seven additional facilities would need to install add-on air pollution control devices.

4. Alternative 4: Require No Further Control

Alternative 4 would be to require no additional control beyond what the existing ATCM, in combination with implementation of Rule 1469 in the SCAQMD, has achieved. This would be equivalent to the 2005 baseline cancer risk. This would result in allowing the maximum incremental cancer risks from some facilities to exceed 100 per million people and for 29 percent of facilities to have cancer risk in excess of ten per million people. Only 41 percent of facilities would have estimated cancer risk below one per million exposed people. Requiring no further control would, of course, result in cost savingsChapter IX Page 100

because the staff’s proposal is estimated to cost $14.2 million dollars. Of this amount, about $9.6 million would be related to purchasing HEPA filtering add-on air pollution

control devices.

Staff does not believe the status quo is protective of public health especially considering that 43 percent of facilities are located within 100 meters of a sensitive receptor. Our goal is to achieve the maximum feasible health protection using the most effective controls. This is especially important when people are living, learning, working, or playing near chromium plating and chromic acid anodizing facilities. Thus, staff did not choose

Alternative 4.

5. Summary

Table IX-5 compares alternatives three and four with the staff’s proposal. Alternatives one and two are not presented. Alternative one is not technologically feasible. Alternative two essentially offers no benefit beyond the staff’s proposal.

Table IX-5 . Adoption of Staff’s Proposal Offers the Greatest Reduction in Significant

Community Cancer Risk



### Number of Facilities by Cancer Risk

< 1 per million >1 < 10

per million >10 < 100

per million >100

per million Staff Proposal 162 41 17 0

Rule 1469

Statewide 98 67 53 2

Baseline 90 67 57 6

Table IX-5 shows that the staff’s proposal offers the best health protection. As shown, adopting the provisions of SCAQMD Rule 1469 statewide would result in 98 facilities (about 45 percent) with remaining cancer risk of no more than one per million exposed persons. This represents an additional 8 facilities compared to the baseline. Adoption of the staff’s proposal would reduce the estimated cancer risk for 162 facilities (about 74 percent) to no more than one per million exposed persons.

6. Conclusion

We evaluated each of the alternatives and determined that the alternatives did not meet the objective of Health and Safety Code section 39666 to reduce emissions to the lowest level achievable through the application of BACT, or a more effective control method, in consideration of cost, health risk, and environmental impacts.Chapter IX Page 101



### E. Recommendation

Based on the forgoing, staff recommends that the Board adopt the proposed amendments to the Chromium Plating ATCM (Appendix A). Requiring BACT for all facilities provides the greatest reductions in significant community cancer risk. The staff’s proposal, compared to the 2005 baseline, would result in up to an 85 percent reduction in estimated cancer risk for individual facilities. Staff predicts the proposal would reduce 162 facilities’ (about 74 percent) cancer risk to no more than one per million exposed people, and reduce cancer risk to no more than ten per million for over 92 percent of facilities. The proposal would also directly benefit low income and ethnically diverse communities that have been disproportionately impacted by emissions from chromium plating and chromic acid anodizing facilities.Chapter IX Page 102

REFERENCES:

SCAQMD, 2004. South Coast Air Quality Management District. Certified List of Fume Suppressants for Facilities Performing Chrome Plating and Chromic Acid Anodizing Operations. 2004 ( http://www.aqmd.gov/prdas/ChromePlating/ChromePlatin g.htm )

U.S. EPA, 2004. U.S. Environmental Protection Agency. 40 CFR Part 63: “National

Emission Standards for Chromium Emissions From Hard and Decorative Chromium Electroplating and Chromium Anodizing Tanks” . 2004.Chapter X Page 103



## X. Economic Impacts

A RB staff has evaluated the estimated costs and economic impacts associated with implementation of the proposed amendments to the Chromium Plating ATCM. This Chapter summarizes the results of our findings. The expected first year estimated costs, capital costs and annual recurring costs that would be expended to comply with the proposed amendments are described. Staff has conducted a conservative analysis of potential costs to be incurred. We have estimated that all facilities needing to demonstrate compliance with the 0.0015 milligrams/ampere-hour limit would install a HEPA add-on air pollution control device. This may not be the case. Some facilities may be able to demonstrate compliance with alternative, cheaper methods. The costs and associated economic impacts are given for private companies and California governmental agencies.



### A. Summary of the Economic Impacts

The proposed amendments to the Chromium Plating ATCM are not expected to have a significant adverse impact on the profitability of most owners or operators of chromium plating and chromic acid anodizing facilities in California. However, staff has determined that costs for some individual businesses are expected to be significant and would adversely impact their profitability. The effect of compliance costs on profitability impacts were estimated by calculating the decline in the return on owner’s equity (ROE). A decline in ROE of 10 percent or more indicates a significant adverse impact. The proposed amendments to the ATCM are expected to result in an average ROE decline of nine percent which is not considered to be a significant impact on the profitability of most affected businesses. However, the ROE for some individual businesses exceeds ten percent. We estimate that businesses’ profitability impacts range from less than one percent to 41 percent.

When considering the entire industry, we expect the proposed amendments to have no significant impact on employment; business creation, elimination or expansion; or business competitiveness in California. However, some individual businesses, including small businesses, could be significantly impacted, which could result in business closures and lost jobs. We expect no significant adverse fiscal impacts on any local or State agencies.

Of the 226 facilities affected by the proposed amendments to the ATCM, up to 89 facility owners would be required to expend significant capital to meet the requirements. Some of these operators may have difficulty securing the required capital to finance the cost of the add-on air pollution control devices that would be required for compliance with the proposed amendments to the ATCM. However, in 2005, the Governor signed legislation to establish a loan guarantee program for decorative chromium plating operations to purchase pollution control equipment. The program is administered by the Business, Transportation, and Housing Agency. The program provides loan guarantees of up to $100,000 to owners of decorative chromium plating small businesses that may not be able to qualify for a conventional loan. In July of thisChapter X Page 104

year, the Governor signed into law amendments to the loan guarantee program. The loan guarantee program is now available for all metal plating facilities.

During the first year, all facilities would have compliance costs. Costs would vary depending on the extent an individual business was already in compliance with the proposed amendments. About 40 percent of facilities are already controlled with HEPA filtration systems, or equivalent; they would incur no capital costs. Another 20 percent of facilities would use chemical fume suppressants as sole control. Therefore, these facilities compliance costs will be low, as well. Compliance costs for trivalent chromium plating facilities would also be low. The proposed amendments would only require these facilities to file an initial compliance status report.

We estimate that costs in the first year would range from $450 to $217,000 with an average cost of $23,000. Median cost would be $8,500. In subsequent years, costs would range from essentially no cost to $217,000 with an average cost of $53,000. Median cost in subsequent years would be $46,000. After the first year, 60 percent of the facilities would have no additional compliance costs. Costs for all facilities include completion of an initial compliance status report. Other costs incurred by some, but not all facilities, include permit fees, performance testing, site specific analyses, housekeeping costs, capital equipment costs (amortized), and ongoing (recurring) costs. The assumptions from which these costs are estimated as described below.



### B. Economic Impact Analysis

1. Legal Requirements

Section 11346.3 of the Government Code requires State agencies to assess the potential for adverse economic impacts on California business enterprises and individuals when proposing to adopt or amend any administrative regulation. The assessment must include a consideration of the impact of the proposed regulation on California's jobs, business expansion, elimination or creation, and the ability of California businesses to compete with businesses in other states.

In addition, State agencies are required to estimate the cost or savings to any State or local agency and school district in accordance with instructions adopted by the Department of Finance. The estimate shall include any non-discretionary cost or savings to local agencies and the cost or savings in federal funding to the State.

Health and Safety Code section 57005 requires the ARB to perform an economic impact analysis of submitted alternatives to a proposed regulation before adopting any major regulation. The proposed amendments to the Chromium Plating ATCM are considered to be a “major regulation”, because the estimated cost to California business enterprises exceeds $10 million in the first year.Chapter X Page 105

2. Affected Businesses

Any business conducting chromium plating, chromic acid anodizing, or business selling chromium plating kits to non-permitted facilities would be affected by the proposed amendments to the ATCM. Also potentially affected are businesses that are customers of chromium plating or chromic acid anodizing facilities, such as the aerospace and automotive industries. The focus of this analysis, however, will be chromium plating and chromic acid anodizing facilities because these businesses would be most affected by the proposed amendments to the ATCM.

The affected businesses generally fall under a Standard Industrial Classification (SIC) code of 34, Fabricated Metal Industry, and more specifically, SIC 3471, Plating and Polishing, or North American Industry Classification System (NAICS) 332813.

3. Potential Impacts on Profitability for Affected Businesses

The approach used in evaluating the potential economic impact of the proposed

amendments to the ATCM on California businesses is as follows:

• All affected facilities are identified from responses to the ARB's 2003 Chromium Plating and Anodizing Facility Survey.

• Financial data and net profit data are obtained for a typical business engaged in plating and polishing businesses from Dun’s Financial Profile; SIC 3471 Industry Profiles (D&B, 2005) and Dun and Bradstreet Business Information Report. (D&B, 2006)

• The annual cost of compliance is estimated for the businesses that are affected by the proposed amendments to the ATCM.

• The annual cost of compliance for each business is adjusted for both federal and state taxes. It is assumed affected businesses are subject to federal and State tax rates of 35 percent and 9.3 percent, respectively.

• These adjusted costs are subtracted from net profit data and the results are used to

recalculate the ROE.

• The resulting ROE is then compared with the ROE before the subtraction of the adjusted costs to determine the impact on the profitability of the businesses. A reduction of more than 10 percent in profitability is considered to indicate a potential for significant adverse economic impacts. This threshold is consistent with the thresholds used by the U.S. EPA and ARB in previous regulations.

• Affected businesses absorb the costs of the proposed amendments to the ATCM instead of increasing the prices of their products or lowering their costs of doing business through cost-cutting measures.

All of the chromium plating and chromic acid anodizing businesses affected by these proposed amendments are California businesses. These businesses are affected to the extent that implementation of the proposed amendments reduces their profitability. Using ROE to measure profitability, we estimate the decline in ROE for most affectedChapter X Page 106

businesses would be less than ten percent based on 2002-2004 financial data. This is based on an average compliance cost for all facilities of $23,000. This does not represent a noticeable decline in the profitability of most affected businesses.

However, for the 89 businesses that would likely need to install or upgrade add-on air pollution control devices, the estimated decline in profitability ranges from 3 to 41 percent. The average estimated compliance costs for these facilities is $53,000.

Of the 89 facilities, 28 small businesses may need to install add-on air pollution control devices. This could result in a potential significant adverse cost impact. These businesses’ profitability could decline by 33 percent in order to comply with the proposed amendments. Some marginal businesses would likely face a difficult business decision as to whether to continue operating the chromium plating portion of their operation. However, this cost analysis is based on the assumption that these small businesses would have to install add-on air pollution control devices. Some of these businesses may be able to demonstrate compliance without the use of an add-on air pollution control device. Others may decide to cease chromium plating, but retain other aspects of their operations and remain viable. In these instances, the ROE estimated here would be much lower. Some of these businesses may also qualify for a loan guarantees of up to $100,000 to purchase pollution control equipment.

The remaining 137 businesses would have average compliance costs of about $4,000. The decline in profitability for these businesses is not considered to be significant. The change in ROE ranges from less than one percent to nine percent.

4. Assumptions for Facility Cost Estimates

Seventy-five percent of the facilities are located in the SCAQMD. These facilities have already complied with Rule 1469 and are familiar with how the air district estimated costs for compliance with that rule. To allow for a comparison ARB staff generally used the SCAQMD’s cost methodology, except that costs were grown from 2003 to 2006 dollars at a rate of 5 percent (factor of 1.158). Using this factor provides for a ‘worst case’ cost estimate because the inflation rate has been about three percent over this period of time (CPI, 2006). The costs estimated for each compliance requirement are summarized below in Tables X-1 and X-2. In addition, chemical fume suppressant cost was estimated at $185/gallon at a use rate of 1.98x10 -6 gallons/ampere-hour.

Table X-1 . Estimated Compliance Costs (Other than Those for Add-On Air Pollution Control Devices)**

Initial Compliance

Plan Drip Trays Plastic Strip

Curtains Permit fee * Source

Test Site

Specific Analysis $450 2@ $350 $1,138 $700/$2,232 $7,335 $11,500

* Permit fee of $2,232 for initial HEPA permit (cost estimate from ARB’s Thermal Spraying Report).

** Costs are rounded.Chapter X Page 107

Table X-2 displays the cost estimates used to estimate costs associated with hexavalent chromium add-on air pollution control devices.

Table X-2 . Costs for HEPA Add-on Air Pollution Control Devices

System size Based on

Fan Size Freight Equipment Installation Recurring

Small (5,000 Cubic Feet per Minute (CFM)) $1,580 $33,047 $54,129 $33,513

Medium (10,000 CFM) $2,328 $48,705 $79,313 $39,850

Large (20,000 CFM) $3,843 $80,396 $129,882 $57,570

For consistency, ARB staff calculated the cost of add-on air pollution controls as per the SCAQMD method. It was assumed that each tank at a facility is 36 square feet and is ventilated at 150 CFM per square foot. One tank, would require 5,400 CFM to be properly ventilated. The number of tanks at a facility was then multiplied by 5,400 to arrive at the total amount of ventilation required (SCAQMD, 2003a and SCAQMD, 2003b).

For example: 6 tanks @ 36 square feet X 5,400 CFM = 32,400 total CFM

In this example, it is assumed the facility would need to purchase one 5,000 CFM system @ $88,756, one 10,000, system @ $130,346, and one 20,000 CFM system @ $214,121. The total cost would be $433,223. In like fashion, recurring costs would be $130,933.

When actual tank numbers were known, this information was used to estimate cost. When this information was not available, staff estimated the number of tanks needing ventilation based on facilities with similar ampere-hours where the number of tanks was known. The size of the system does not necessarily relate to throughput. An intermediate-sized facility (no more than 200,000 ampere-hours) may have multiple tanks requiring ventilation, such that a larger system 10,000 CFM system is needed. Other very large throughput facilities may only have one tank requiring ventilation. In this case, the larger facility would have cheaper compliance costs as only a 5,000 CFM system may be needed. However, staff has estimated that of the 89 facilities required to install HEPA systems, 80 out of 89 would be 5,000 CFM systems.

We annualized non-recurring fixed costs using the Capital Recovery Method. Using this method, we multiplied the non-recurring fixed costs by the Capital Recovery Factor (CRF) to convert these costs into equal annual payments over a ten year project horizon at a discount rate of five percent. The Capital Recovery Method for annualizing fixed costs is recommended by the California Environmental Protection Agency (Cal/EPA) (Cal/EPA, 1996), and is consistent with the methodology used in previous cost analyses for ARB regulations (ARB, 2000).Chapter X Page 108

The CRF is calculated as follows:

CRF i i

i n

n = +

+ − ( )

( ) 1

1 1
where, CRF = Capital Recovery Factor i = discount interest rate (assumed to be 5 percent) n = project horizon or useful life of equipment

All costs of the add-on air pollution control devices were annualized over 10 years. These values are based on a conservative estimate of the expected lifetime of the equipment. The total annualized cost was obtained by adding the annual recurring costs to the annualized fixed costs derived by the Capital Recovery Method.

Capital costs include the cost of the add-on air pollution control device, installation, freight, source test, and instrumentation.

Recurring costs include replacement filters, disposal of filters as hazardous waste, electrical usage, labor, property tax, insurance, and reporting costs.

5. Potential Economic Impacts for Individual Chromium Plating and Anodizing Facilities

From our industry survey we have identified 226 chromium plating and chromic acid anodizing facilities in California. Of these businesses, two are federal government facilities, the U.S. Naval Aviation Depot, in the SDCAPCD, and the United States Mint in
the BAAQMD.

We estimate that 71 of the affected businesses are small businesses with gross annual revenue of less than $1.0 million (U.S. EPA, 1995a). Of these, 28 businesses would likely incur costs associated with purchase and operation of add-on air pollution control

devices.

In terms of estimating compliance costs, facilities can be divided into 4 groups: trivalent chromium plating facilities; hexavalent chromium plating and chromic acid anodizing facilities with throughput of less than or equal to 20,000 annual ampere-hours; hexavalent chromium plating and chromic acid anodizing facilities with throughput of more than 20,000 but less than or equal to 200,000 annual ampere-hours; and hexavalent chromium plating and chromic acid anodizing facilities with throughput of more than 200,000 annual ampere-hours. There are also hexavalent chromium plating and chromic acid anodizing facilities with throughput of more than 20,000 that are already in substantial compliance with the proposal. Costs for these facilities will be estimated separately from those needing to expend significant capital to comply.Chapter X Page 109

a. Trivalent Chromium Plating Facilities

Six facilities conduct only trivalent chromium plating. These facilities would incur costs associated with submitting an initial compliance status report. This cost has been estimated at $450 per facility. Beyond this one-time cost, compliance with the proposed

amendments would result in no additional cost for these facilities.

b. Hexavalent Chromium Plating and Chromic Acid Anodizing Facilitieswith Throughput of Less Than or Equal to 20,000 Annual AmpereHours

Forty-eight facilities have been identified with throughput of less than or equal to 20,000 annual ampere-hours. Under the proposed amendments these facilities would be allowed to control hexavalent chromium emissions by reducing surface tension of the plating/anodizing bath by using specified chemical fume suppressants. Compliance costs for these facilities are estimated to average about $2,000. The costs were estimated as

described below.

Based on 2003 calendar year data, only ten of these 48 facilities were not using the specified chemical fume suppressants. Costs for these ten facilities to begin using specified chemical fume suppressants would result in no significant cost increase. All 48 of these facilities however, would need to complete an initial compliance status report estimated to cost $450. It is also assumed that these facilities would have permit renewal fees of $700. For facilities with buffing, grinding or polishing operations we estimated costs associated with purchase of plastic strip curtains at $1,100. Costs for purchase of drip trays for facilities with automated lines were estimated to cost $700. Thus, costs for these facilities range from $1,150 to $2,600, with average compliance costs of $2,000. After the first year, 38 of these facilities would have no additional compliance costs beyond housekeeping and recordkeeping. Ten facilities would have annual recurring costs, but they are near zero.

c. Hexavalent Chromium Plating and Chromic Acid Anodizing Facilities with Throughput of More Than 20,000 but Less Than or Equal to 200,000 Annual Ampere-Hours

Sixty facilities have been identified with more than 20,000 but less than or equal to 200,000 annual ampere-hours. Of these, 45 facilities would need to take actions to demonstrate compliance with the emission limit of 0.0015 milligrams/ampere-hour; the other 15 facilities are already in substantial compliance. Generally, to meet the 0.0015 milligrams/ampere-hour limit requires use of a HEPA add-on air pollution control device. However, the requirement would be phased in based on throughput and proximity to sensitive receptors. [The other 15 facilities’ costs are estimated as described in part e., below.] Total capital costs for these facilities are estimated to be about $4.0 million. Total annualized costs (amortized plus recurring costs) are estimated to be $2.1 million. The costs were estimated as described below.Chapter X Page 110

Twenty-eight of these facilities are located within 100 meters of a sensitive receptor and would be required to demonstrate compliance within two years. The other 17 facilities would have five years to demonstrate compliance with the emission limit because they do not have sensitive receptors located within 100 meters. Some of these 45 facilities may be able to demonstrate compliance with the emission limit without installation of a HEPA add-on air pollution control device. However, most are expected to need to install a HEPA add-on air pollution control device to meet the 0.0015 milligrams/ampere-hour limit. Costs were estimated based on installation of a HEPA add-on air pollution control device

for all of these facilities.

All of these facilities would need to complete an initial compliance status report estimated to cost $450. It is also assumed that these facilities would have permit fees associated with installation a HEPA add-on air pollution control device. This cost is estimated to be $2,200. Ongoing permit renewal fees are estimated at $700. For facilities with buffing, grinding or polishing operations we estimated costs associated with purchase of plastic strip curtains at $1,100. Costs for purchase of drip trays for facilities with automated lines were estimated to cost $700. Performance tests would be required of all facilities, which is included in the cost of purchasing and installing a HEPA add-on air pollution control

device.

The cost to purchase an add-on air pollution control device is estimated to be $89,000 in initial capital costs (including installation, source testing, and freight). For these facilities, we amortized the costs of purchasing the add-on air pollution control devices over ten years. We also amortized the costs for permit fees, and purchase of plastic strip curtains and/or drip trays when required. Total costs to be amortized are estimated to be $92,000. This equates to an annualized capital cost of about $12,000 (in 2006 dollars) over the life of the equipment.

Annual recurring costs associated with equipment maintenance and ongoing permit fee renewals are estimated at $34,000. Combining these annual costs with amortized costs results in an annual cost of about $46,000 for purchase, installation, reports, fees, analyses, and maintenance of the equipment.

d. Hexavalent Chromium Plating and Chromic Acid Anodizing Facilities with Throughput of More Than 200,000 Annual Ampere-Hours

One hundred twelve facilities have been identified with more than 200,000 annual ampere-hours. Of these, 44 facilities would need to take actions to demonstrate compliance with the emission limit of 0.0015 milligrams/ampere-hour, as measured after an add-on air pollution control device. Generally, this requires use of a HEPA add-on air pollution control device. Costs were estimated for these facilities based on installation of a HEPA add-on air pollution control device. These facilities would be required to demonstrate compliance within two years. [The other 68 facilities’ costs are estimated as described in part e., below.] Total capital costs for 44 facilities are estimated to be $5.6 million. Total annualized costs (amortized plus recurring costs) are estimated to be $2.7

million. The costs were estimated as described below.Chapter X Page 111

All of these facilities would need to complete an initial compliance status report estimated to cost $450. It is also assumed that these facilities would have permit fees associated with installation a HEPA add-on air pollution control device. This cost is estimated to be $2,200. Ongoing permit renewal fees are estimated at $700. For facilities with buffing, grinding or polishing operations we estimated costs associated with purchase of plastic strip curtains at $1,100. Costs for purchase of drip trays for facilities with automated lines were estimated to cost $700. Performance tests would be required of all facilities, which is included in the cost of purchasing and installing a HEPA add-on air pollution control device. After meeting the 0.0015 milligrams/ampere-hour limits, one facility would be required to conduct an additional assessment to determine if further risk reduction was needed. Cost for site specific analysis is estimated to cost $11,500.

The costs to purchase add-on air pollution control devices are estimated to range from $89,000 to about $500,000 in initial capital costs (including installation, source testing, and freight). Average capital cost is about $130,000. For these facilities, we amortized the costs of purchasing the add-on air pollution control devices over ten years. We also amortized the costs for permit fees, and purchase of plastic strip curtains and/or drip trays when required. Total costs to be amortized range from about $90,000 to $500,000. This equates to an annualized capital cost of about $12,000 to $68,000 (in 2006 dollars) over the life of the equipment.

Annual recurring costs associated with equipment maintenance and ongoing permit fee renewals are estimated to range from $34,000 to $150,000, with an average of about $43,000. Combining these annual costs with amortized costs results in an annual cost of about $46,000 to $217,000 for purchase, installation, reports, fees, analyses, and maintenance of the equipment. The mean cost would be about $61,000.

e. Hexavalent Chromium Plating and Chromic Acid Anodizing Facilities with Throughput of More Than 20,000 Annual Ampere-Hours Already in Substantial Compliance with the Proposal

Eighty-three facilities have been identified with throughput of more than 20,000 annual ampere-hours that already meet the emission limit. These facilities would incur compliance costs in the first year only. The average compliance cost for these facilities is about $5,500. The costs for these facilities were estimated as described below.

All of these facilities would need to complete an initial compliance status report estimated to cost $450. It is also assumed that these facilities would have permit renewal fees of $700. For facilities with buffing, grinding or polishing operations we estimated costs associated with purchase of plastic strip curtains at $1,100. Costs for purchase of drip trays for facilities with automated lines were estimated to cost $700. Performance tests would be required of 31 facilities with an estimated cost of $7,500 each. Based on 2003 data, five facilities would be required to conduct an additional assessment to determine if further risk reduction was needed. Cost for this site specific analysis is estimated to cost $11,500. Thus, costs for these facilities range from $1,150 to $21,000, with averageChapter X Page 112

compliance costs of about $5,000. Beyond the first year, these facilities would have no additional compliance costs beyond housekeeping and recordkeeping.

6. Potential Impact on Manufacturers and Suppliers of Chromium Plating and Chromic Acid Anodizing Equipment and Chemicals

We do not expect manufacturers of chromium plating and chromic acid anodizing materials to incur any costs. However, the staff’s proposal to prohibit sales of chromium plating kits to non-permitted facilities may result in lost revenue for these businesses. The proposed amendments would potentially impact the chemical manufacturers in a positive way through increased sale of chemical fume suppressants. Add-on air pollution control device manufacturers, as well as the metal fabricating industry, would also benefit from the proposed amendments as controls and ductwork for ventilation systems are purchased.

7. Potential Impact on Consumers

The potential impact of the proposed amendments to the ATCM on consumers depends upon the extent to which affected businesses are able to pass on the increased cost to consumers in terms of higher prices for their goods and services. If all costs are passed onto the consumers, we expect the cost per ampere-hour to increase by between $0.01 to $2.21 per ampere-hour. These costs are estimated based on facilities that would have to install add-on air pollution control devices. The lower end of this cost would represent a large facility, while the upper end cost would represent a small facility.

To put these costs into perspective consider that chromium plating an automobile bumper (a decorative chromium application) requires 10 to 12 ampere-hours (Walker, 2006). Using the cost per ampere-hour above, this would mean the increased cost of a bumper would be between $0.12 to $26.52. A larger automobile bumper would require 50 ampere-hours to chromium plate (Walker, 2006). This would mean the increased cost to plate a larger bumper would be under a dollar to as much as $110 more. One current cost estimate to re-plate a bumper is $400. Because the majority of plating is done at larger facilities we anticipate the net impact on consumers to be negligible to minor.

8. Potential Impact on Employment

Of the 226 affected businesses, 86 percent responded to our survey and provided calendar year 2003 employee data. Fifty percent reported employing 25 or fewer people. Another 30 percent reported employing between 26 to 100 people. Four businesses reported employing 1,000 or more employees. Generally, facilities with large numbers of employees have a chromium plating or anodizing process as part of the overall facility’s operation. It is likely only a small number of these employees would be dedicated to conducting plating or anodizing. An example of this situation would be an aerospace company. About 25 facilities that would have substantial compliance costs employ ten or fewer people.Chapter X Page 113

We expect the proposed amendments to the ATCM to adversely impact some employees.

9. Potential Impact on Business Creation, Elimination or Expansion

The proposed amendments to the ATCM would have an impact on the status of some California businesses. The compliance costs of the proposed amendments to the ATCM are expected to be significant for marginal chromium plating and chromic acid anodizing facilities as shown by the estimated impacts on the profitability of some affected businesses. The businesses subject to control requirements are expected to pass the compliance costs on to their customers, or make a business decision as to whether or not to continue operations.

10. Potential Impact on Business Competitiveness

The proposed amendments to the ATCM will not have a significant, statewide adverse impact on the ability of California businesses to compete with businesses in other states, although the competitiveness of some individual business would be adversely impacted. No other state controls emissions of hexavalent chromium from chromium plating and chromic acid anodizing businesses as stringently as does California. Most other states’ requirements are limited to those of the federal Chromium Plating NESHAP, which is less stringent than the existing ATCM. Therefore, the existing ATCM creates a competitive disadvantage for some California businesses because they generally do not have compliance costs as high as out-of-state businesses.

The proposed amendments would make this existing competitive disadvantage worse for some individual businesses (i.e., those chromium plating and chromic acid anodizing businesses that would have to spend significant amounts of money to comply with the amended ATCM). However, approximately 60 percent of the existing businesses are in substantial compliance with the requirements that would be established by the proposed amendments, and would have to spend very little additional money to comply. The proposed amendments would not have a significant adverse impact on the existing competitive position of these businesses. In addition, many chromium plating and chromic acid anodizing businesses in California compete only with other California businesses. The competitive position of these businesses would also not be significantly impacted by the proposed amendments.

11. Costs to Public Agencies

Health and Safety Code section 39666 requires that, once the Board adopts the proposed amendments, the air districts implement and enforce the ATCM or adopt an equally effective or more stringent regulation. Because the air districts will have primary responsibility for implementing and enforcing the proposed amendments to the ATCM, we evaluated the potential cost to the air districts. We also evaluated the potential cost toChapter X Page 114

local and State agencies. This section provides the conclusions we reached and the

basis for those conclusions.

The chromium plating and anodizing facilities affected by the proposed amendments to the ATCM are located in eight air districts, as shown in Table X-3.

Table X-3 . Number of Affected Hexavalent Chromium Plating and Chromic Acid

Anodizing Facilities by Air District

Location # Affected

Facilities # Facilities

Installing or Upgrading

Controls Percent

of

Facilities Bay Area AQMD 18 12 8
Feather River AQMD 1 0 <1

Sacramento Metro AQMD 5 3 <1
South Coast AQMD 173 60 76 San Diego APCD 9 2 4 San Joaquin Valley APCD 17 12 8 Shasta County APCD 2 0 <1 Ventura County APCD 1 0 <1

Total 226 89

New costs the air districts would incur as a result of the proposed amendments would be reviewing initial compliance status reports; reviewing permit modifications for facilities adding or upgrading to HEPA, or an equivalent level of control; reviewing source test protocols and results; and reviewing site specific analyses, if necessary. The air districts already review ongoing compliance status reports and permit renewals. Facilities are also regularly inspected. Therefore, we do not expect any additional costs to be incurred for performing these functions. We estimate the new costs to air districts resulting from the proposed amendments to the ATCM to be approximately $685,000.

However, air districts can recover these costs through fees charged to the facilities. The costs to the air districts can be recovered under the fee provisions authorized by Health and Safety Code sections 42311 and 40510. Therefore, the proposed amendments to the ATCM would impose no costs on the air districts that would require the State to reimburse them pursuant to Section 6 of Article XIIIB of the California Constitution and Part 7 (commencing with section 17500), division 4, title 2 of the Government Code. We are also aware that some air districts may assess costs differently than how costs were estimated for this rulemaking. However, any additional costs are also recoverable from

fees assessed on facilities within their air district.

The proposed amendments to the Chromium Plating ATCM would not affect any State agency or program other than ARB. Although the air districts will have primary responsibility for enforcing the proposed amendments to the ATCM, the ARB may, at the request of an air district, provide assistance in the form of technical expertise, legal support, or other enforcement support. We estimate that providing assistance to airChapter X Page 115

districts as they adopt the proposed amendments to the ATCM would require about onequarter person year or $25,000 over the next three fiscal years. Review and approval of chemical fume suppressants data to affirm the chemicals meet the 0.01 milligram/ampere-hour limit would require about two person months each, or $17,000. We expect the number of reviews to be small. These costs are absorbable within the existing ARB budget.

We also anticipate no fiscal effect on federal funding of State programs.

12. Total Cost of the Proposed Amendments to the Airborne Toxic

Control Measure

Based on information provided in the ARB’s 2003 Chromium Plating and Chromic Acid Anodizing Facility Survey, and applying similar compliance costs to those estimated for compliance with SCAQMD Rule 1469 (2003 dollars grown to 2006 dollars at a rate of 5 percent per year), we estimated the total cost of compliance with the proposed amendments to the ATCM. Total capital costs for purchase of add-on air pollution control devices are estimated at $9.6 million. Total recurring costs are estimated at $3.6 million. An additional $1.0 million in costs are estimated for reports, source testing, permit fees, and site specific analyses. In total, costs are estimated to be $14.2 million.

During the first year, all facilities would have compliance costs. Costs would vary depending on the extent an individual business was already in compliance with the proposed amendments. We estimate that costs in the first year would range from $450 to about $217,000 with an average cost of about $23,000. In subsequent years, costs would range from near zero to $217,000, with an average cost of $53,000. Nine facilities would have ongoing costs over $50,000. After the first year, 60 percent of the facilities would have no additional compliance costs.Chapter X Page 116

REFERENCES

ARB, 2000. Air Resources Board. “Staff Report: Initial Statement of Reasons for Proposed Amendments to the Vapor Recovery Certification and Test Procedures for Gasoline Loading and Motor Vehicle Gasoline Refueling at Service Stations.” 2000.

Cal/EPA, 1996. California Environmental Protection Agency. Memorandum from Peter M. Rooney, Undersecretary, to Cal/EPA Executive Officers and Directors. “Economic Analysis Requirements for the Adoption of Administrative Regulations.” Appendix C (“Cal/EPA Guidelines for Evaluation Alternatives to Proposed Major Regulations”). 1996.

CPI, 2006. InflationData.com. Current Consumer Price Index. 2006 (http://www.inflationdata.com/inflation/consumer_price_index/currentCPI.asp)

D&B, 2005. Dun and Bradstreet. Duns Financial Profile - Industry Profile; SIC 3471.

2005

D&B, 2006. Dun and Bradstreet. D&B’s Business Information Report – Various

Businesses. 2006

SCAQMD, 2003b. South Coast Air Quality Management District. “Draft Socioeconomic Assessment for Proposed Amendments to Rule 1469-Hexavalent Chromium Emissions from Chrome Plating and Chromic Acid Anodizing Operations and Proposed Rule 1426- Emissions from Metal Finishing Operations”. 2003

SCAQMD, 2003a. South Coast Air Quality Management District. “Draft Staff Report for Proposed Amended Rule 1469-- Hexavalent Chromium Emissions from Chrome Plating and Chromic Acid Anodizing Operations and Proposed Rule 1426- Emissions from Metal Finishing Operations.” 2003

U.S. EPA, 1995a. U.S. Environmental Protection Agency, “EPA Office of Compliance Sector Notebook Project – Profile of the Fabricated Metal Products Industry”. 1995

Walker, 2006. Air Resources Board staff telephone conversation with Howard Walker,

Walker’s Custom Chrome. 2006Chapter XI Page 118



## XI. Environmental Impacts

The main goal of these proposed amendments is to reduce the public’s exposure to hexavalent chromium by achieving the maximum reduction in emissions. This is done by proposing a phase-in of HEPA filters, or equivalent for the intermediate and large size facilities, and use of chemical fume suppressants for very small facilities. The proposed amendments are especially designed to reduce exposures when chromium plating and chromic acid anodizing facilities are located near where children and people live, learn, work, and play. The proposal is also designed to have direct benefit for low income and non-white communities that have been disproportionately impacted by hexavalent chromium emissions from chromium plating and chromic acid anodizing operations. A further goal is to isolate people from any new chromium plating or chromic acid anodizing facility.

The primary benefit from the proposed amendments is a large reduction in excess cancer

risk from emissions of hexavalent chromium. We estimate cancer risk would be reduced by up to 85 percent. Almost 75 percent of facilities would have cancer risk of less than one per million people exposed. About 92 percent of facilities would have cancer risk of less than ten per million people exposed.

While the reduction in cancer risk is substantial, the overall air quality benefit, in terms of mass, is negligible. Moreover, reducing the cancer risk through adoption of the proposed amendments may have an affect on other environmental factors. As described below, while there may be some potential adverse impacts, ARB staff has determined that they are not significant.

The legal requirements imposed on ARB to assess environmental impacts and our overall evaluation of the environmental impacts of the proposal are summarized below. We evaluated the potential impacts that the proposed amendments to the ATCM may have on air quality, wastewater treatment, and hazardous waste disposal.



### A. Legal Requirements

The California Environmental Quality Act (CEQA) and ARB policy require an analysis to determine the potential environmental impacts of proposed regulations. ARB’s program for adopting regulations has been certified by the Secretary of Resources, pursuant to Public Resources Code section 21080.5. Consequently, the CEQA environmental analysis requirements may be included in the ISOR for this rulemaking. In the ISOR, the ARB must include a functionally equivalent document, rather than adhering to the format described in CEQA of an Initial Study, a Negative Declaration, and an Environmental Impact Report. In addition, staff will respond in the Final Statement of Reasons for the proposed amendments to the ATCM to all significant environmental issues raised by the public during the 45-day public review period or at the Board hearing.Chapter XI Page 119

Public Resources Code section 21159 requires that the environmental impact analysis conducted by ARB include the following:

• An analysis of reasonably foreseeable environmental impacts of the methods of compliance;

• An analysis of reasonably foreseeable feasible mitigation measures; and

• An analysis of reasonably foreseeable alternative means of compliance with the proposed amendments to the ATCM.

Compliance with the proposed amendments to the Chromium Plating ATCM is expected to directly affect air quality and potentially affect other environmental media as well. Our analysis of the reasonably foreseeable environmental impacts of the methods of compliance is presented below.



### B. Analysis of Reasonably Foreseeable Environmental Impacts

The proposed amendments reduce the public’s exposure to hexavalent chromium emissions from chromium plating and chromic acid anodizing facilities. The methods used to reduce the public’s exposure, however, will impact the environment. Our analysis of how the environment would be impacted follows.

1. Potential Air Quality Impacts

As previously discussed, hexavalent chromium is found in the particulate emissions from chromium plating and chromic acid anodizing facilities. However, the small reduction in hexavalent chromium emissions achieved from this proposal would have a negligible effect on ambient particulate levels. While the proposed amendments reduce emissions of hexavalent chromium by about 55 percent, the actual reduction in mass is about 2.2 pounds per year. Remaining emissions are estimated to be 1.8 pounds per year. However, by reducing 2.2 pounds per year of hexavalent chromium, near source cancer risk impacts would be reduced by up to about 85 percent. These reductions will occur in eight air districts, with the greatest benefits occurring in the SCAQMD.

The proposed amendments to the Chromium Plating ATCM are based on our reevaluation of BACT for reducing hexavalent chromium emissions from chromium plating and chromic acid anodizing facilities, in consideration of health risk and cost. The staff’s proposal would phase-in BACT over time. The timing for application of BACT would be related to throughput and proximity to sensitive receptors.

By requiring BACT for all facilities, remaining cancer risks would be reduced by up to 85 percent. We also estimate that adoption of the staff’s proposal will reduce the estimated cancer risk for 92 percent of facilities to less than or equal to ten per million exposed persons. The proposal would also isolate any new chromium plating or chromic acid anodizing facility from residential or mixed use zones by not allowing new facilities to operate in these areas. The new facility also could not operate within 150 meters of an

area so zoned.Chapter XI Page 120

Additional indirect air quality impacts will result from the implementation of the proposed amendment to the ATCM. It is anticipated that there will be a temporary increase in emissions of criteria pollutants due to construction related activity involved in the installation of new add-on air pollution controls and the possible dismantling of current controls. Staff finds that this short-term impact will not be significant.

2. Potential Water and Wastewater Impacts

Many of the add-on air pollution control devices required by the proposed amendments require periodic water washdown to clean and maintain the integrity of the system. Implementation of housekeeping measures would likely require fresh water usage as well.

This will increase the amount of freshwater used at these facilities. The increased water usage is difficult to quantify, however, we do not expect the increased use to be significant. A total of 89 facilities may increase water usage by installing add-on air pollution control devices. All of this freshwater becomes hazardous wastewater. However, water used to washdown control devices is often returned to the plating tank to reduce generation of hazardous waste.

The State Water Resources Control Board (SWRCB) regulates wastewater in California. It is illegal to dispose into the sewer system, wastewater containing hazardous substances such as hexavalent chromium. Chromium plating and chromic acid anodizing facilities are subject to these regulations. While we expect the amount of wastewater to increase due to the proposed amendments related to housekeeping and equipment maintenance, by compliance with SWRCB regulations, we do not expect this hexavalent chromium to be discharged to lakes, rivers, bays, or oceans.

Some facilities ‘treat’ their wastewater on site to precipitate the chromium from the water. This sludge, is also hazardous waste, but may be reused in the manufacture of stainless steel, thus further reducing the hazardous waste stream.

3. Potential Hazardous Waste Impacts

Hazardous waste is regulated in California by federal and State laws. In California, all hazardous waste must be disposed of at a facility that is registered with the Department of Toxic Substances Control (DTSC). Chromium plating and chromic acid anodizing facility wastes are classified as hazardous waste because they contain hexavalent

chromium.

The proposed amendments, through housekeeping measures and disposal of HEPA filters and other pre-filters from the add-on air pollution control devices that capture hexavalent chromium, would increase the hazardous waste stream.

The use of HEPA systems is already in wide use in the chromium plating and chromic acid anodizing industry in California. These filters, as well as pre-filters designed to increase the useful life of HEPA filters, are considered hazardous waste to be disposed of in Class A landfills. The proposed amendments would require an additional 89 facilities toChapter XI Page 121

begin using add-on air pollution control devices with the final collection mechanism likely to be HEPA filters. HEPA filters are usually replaced at least annually, but replacement schedules depend upon the individual operation. Pre-filters are replaced more often.

We have estimated the impact of the incremental increase in the disposal of used filters due to the implementation of the proposed ATCM as follows: For our analysis, we assumed that each of the 89 affected facilities will be disposing of three filters per year, or 89 x 3 = 267 filters per year. Assuming a typical filter volume of 4 cubic feet each, the resulting volume of hazardous waste generated will be 1,068 cubic feet per year (SCAQMD, 2003c). This corresponds to 2.9 cubic feet per day. We do not consider this to be a significant increase in the amount of hazardous waste to be landfilled. Moreover, staff has determined that the expected reduction in cancer risk from the proposed

amendments overrides this increase in hazardous waste.

4. Potential Effect on the Environment due to Use of Persistent and Bioaccumulative Perfluorooctyl Sulfonates (PFOS)

One of the hexavalent chromium control technologies in use today employs the use of chemical fume suppressants. The most common types of surfactants used in chromium electroplating and chromic acid anodizing are fluorinated or perfluorinated compounds, or simply, fluorosurfactants (U.S. EPA, 1998).

The fluorosurfactants used as active ingredients in chemical fume suppressants are often referred to as perfluorooctyl sulfonates (PFOS). While these products are highly effective at reducing hexavalent chromium emissions by reducing plating bath surface tension the compounds have been shown to be persistent, bioaccumulative, and toxic to mammals (U.S. EPA, 2006).

Studies indicate that PFOS may have potential developmental, reproductive, and systemic toxicity. PFOS compounds have been shown to be readily absorbed orally and distribute primarily to the serum and liver. Epidemiologic studies have also shown a link between exposure and the incidence of bladder cancer. PFOS compounds have also been shown to exhibit moderate toxicity in fish, aquatic plants, invertebrates, amphibians and birds (U.S. EPA, 2006).

For these reasons, on March 10, 2006, U.S. EPA published at 40 CFR Part 721.9582, a proposal to add certain PFOS into their Significant New Use Rule for perfluoroalkyl sulfonates (PFAS). The PFOS proposed for addition include the PFOS commonly used in chemical fume suppressants.

Our survey of the industry for calendar year 2003 indicated that 190 operations were using chemical fume suppressants as a mechanism to control hexavalent chromium emissions. Almost all of these facilities are using a chemical fume suppressant using PFOS as the active ingredient. We estimate that annually, over 800 gallons of chemical fume suppressant are currently used. The staff’s proposal does not require use of chemical fume suppressants except for very small operations. It is also possible thatChapter XI Page 122

some facilities would cease to use chemical fume suppressants as a result of the staff’s proposal. However, when applications allow use of chemical fume suppressants, we expect facilities to continue using them to aid in emission reduction and to lengthen the

useful life of HEPA filters.

The proposed amendments would require an additional ten facilities with throughput below 20,000 ampere-hours to either begin using chemical fume suppressants or increase use of chemical fume suppressant to reduce surface tension to below 40 dynes/centimeter. In total, we estimate the initial amount of chemical fume suppressant required to be 0.15 gallons. This is based on total ampere-hours (77,000)

and the estimated use of 1.98 X 10 -6 gallons of chemical fume suppressant per amperehour (SCAQMD, 2003b). Up to eight additional intermediate-sized facilities may begin using chemical fume suppressants if they choose to demonstrate compliance without use of an add-on air pollution control device. At most, the additional amount of chemical fume suppressant used would be three gallons. The chemical fume suppressant is usually supplied at concentrations of 5 to 10 percent PFOS. Typically, in plating/anodizing operations the concentration of PFOS in the plating/anodizing bath is 100 ppm (Atotech, 2006a).

Staff believes this estimate of additional chemical fume suppressant use to be negligible, and expect no significant impact to result from the staff’s proposal.

The PFOS chemicals are not present on the finished plated part. Chemical fume suppressants are also known to break down in the plating/anodizing bath (Atotech, 2006a), although the major loss of fume suppressant is due to dragout. Dragout can be reduced by part rinsing over the tank. It has been estimated that about ten percent of the chemical fume suppressant is discharged with wastewater (Atotech, 2006a). Thus, the potential of the general public’s exposure to PFOS compounds in the environment from plating and anodizing activities is low.

Staff is not aware of any product other than PFOS that would be as effective at reducing hexavalent chromium while not damaging the plated part. To eliminate the potential of PFOS from chromium plating and chromic acid anodizing activities would require use of add-on air pollution control devices for all facilities, which we have concluded is not appropriate due to costs. Therefore, staff believes that the benefit from the reduction in excess cancers through the use of chemical fume suppressants containing PFOS outweighs the potential adverse impact to the environment due to use of PFOS.



### C. Reasonably Foreseeable Mitigation Measures

The California Environmental Quality Act requires an agency to identify and adopt feasible mitigation measures that would minimize any significant adverse environmental impacts described in the environmental analysis. The ARB staff has concluded that no significant adverse environmental impacts should occur from adoption of and compliance with the proposed amendments to the ATCM. Because no significant adverse impacts have been identified, no specific mitigation measures would be necessary.Chapter XI Page 123



### D. Reasonably Foreseeable Alternative Means of Compliance

Alternatives to the proposed amendments to the Chromium Plating ATCM are discussed in Chapter IX of this report. ARB staff has concluded that the proposed amendments to the ATCM provide the most effective and least burdensome approach to reducing the public’s exposure to hexavalent chromium emitted from chromium plating and chromic acid anodizing facilities.



### E. Community Health and Environmental Justice

Environmental Justice is defined as the fair treatment of people of all races, cultures, and incomes with respect to the development, adoption, implementation, and enforcement of environmental laws, regulations, and policies. The ARB is committed to integrating environmental justice into all of our activities. ARB’s “Policies and Actions for Environmental Justice,” (Policies) establish our framework for incorporating Environmental Justice into the ARB’s programs, consistent with the directive of California state law (ARB, 2001b). These Policies apply to all communities in California. However, environmental justice issues have been raised specifically in the context of low-income

areas and non-white communities.

The Policies are intended to promote the fair treatment of all Californians and cover the full spectrum of the ARB’s activities. Underlying these Policies is a recognition that the agency needs to engage community members in a meaningful way as it carries out its activities. People should have the best possible information about the air they breathe and what is being done to reduce unhealthful air pollution in their communities. The ARB recognizes its obligation to work closely with all communities, environmental and public health organizations, industry, business owners, other agencies, and all other interested parties to successfully implement these Policies.

During the development of the proposed amendments, ARB staff proactively identified and contacted chromium plating and chromic acid anodizing facility owners, environmental organizations, and other parties interested in chromium plating and chromic acid anodizing. These individuals participated by providing data, reviewing draft regulations, and attending public meetings in which staff directly addressed their

concerns.

Staff has found, through modeling analyses, that the health risks from hexavalent chromium emissions from chromium plating and chromic acid anodizing operations tend to be localized, and have the greatest impact on near-source receptors. For these reasons, staff has proposed amendments to reduce exposures to people and children by requiring highly effective controls, and phasing in these controls most quickly at larger facilities and those located nearer to sensitive receptors. Only very small operations (less than 20,000 ampere-hours) would not be required to meet an emission rate of 0.0015 milligrams/ampere-hour. BACT for these facilities is specific chemical fume suppressantsChapter XI Page 124

capable of reducing emissions to 0.01 milligrams/ampere-hour. However, these small facilities would pose a cancer risk of no more than one per million exposed people. Allother facilities would need to demonstrate compliance with the 0.0015 milligram/amperehour limit.

For facilities when application of BACT does not reduce cancer risk to below 25 per million exposed people, staff has proposed additional measures to require facilities to conduct a site specific analysis of emissions and health risk. The air districts will use this information to determine if further reductions are necessary. We estimate cancer risk would be reduced by up to 85 percent if the staff’s proposal were adopted.

The proposed amendments to the ATCM are consistent with our Policies to reduce health risks from toxic air pollutants in all communities, including those with low-income and non-white populations, regardless of location. Potential health risks from hexavalent chromium emissions from chromium plating and chromic acid anodizing operations can affect both urban and rural communities. Therefore, reducing hexavalent chromium emissions from chromium plating and chromic acid anodizing operations will provide air quality benefits to urban and rural communities in the State, including low-income areas

and non-white communities.

We have identified several communities that may be disproportionately impacted from hexavalent chromium emissions from chromium plating and chromic acid anodizing operations. As an example, Appendix I, Chart 1 depicts chromium plating and chromic acid anodizing facilities in the Los Angeles/Orange County area. About 160 facilities aredepicted on this Chart. The area shown within the box is magnified in Chart 2. Twentyfour facilities are located within this small area. This is almost 15 percent of all facilities represented in Chart 1. In Chart 2 we have identified those areas where over 30 percent of the residents have incomes below the poverty level (hatched areas). Six facilities are

located within this area. Table XI-1 shows the number of facilities located in non-white areas and in areas with a high poverty rate.

Table XI-1 . Distribution of Chromium Plating and Chromic Acid Anodizing Facilities in the Los Angeles and Orange County Areas

Location Total

Number of

Facilities 30 to 100%

Below Poverty Over 90%

Non-white* Combined 30 to 100%

Below Poverty and

Over 90% Non-white Los Angeles and Orange Counties 160 38 80 38 Compton Area 24 6 20 6

* Non-white is defined as the sum of all other races that are not included in the “white-alone” one race category in the 2000 census data prepared by the U.S. Census Bureau.

Table XI-1 shows that half of the facilities in the Los Angeles and Orange County areas are located in areas where over 90 percent of the population is non-white. In our analysis of 2000 U.S. census data, we created the category percent non-white to serve as measure of ethnic diversity on a census tract. The percent non-white value is calculatedChapter XI Page 125

from the sum of all other races that are not included in the “white-alone” one-race category in the 2000 census data prepared by the U.S. Census Bureau. Of these, 38 facilities (almost 25 percent) are located in areas where the poverty level is 30 percent or more. Similarly for the Compton area, 20 facilities (about 80 percent of the facilities shown in Chart 2) are located in non-white areas, with six of these facilities located in areas where the poverty level exceeds 30 percent. Staff believes this concentration of plating/anodizing operations in low-income and non-white communities has created disproportionate impacts from hexavalent chromium emissions from chromium plating and chromic acid anodizing facilities. Because the proposed amendments to the ATCM would greatly reduce these emissions in residential areas, these communities would realize a major portion of the benefits from the proposal.

To further address environmental justice and the public’s concern about developing cancer from exposure to hexavalent chromium emissions at all locations, including currently heavily impacted communities, the proposed amendments to the ATCM establish criteria for the operation of new chromium plating and anodizing facilities. Staff is proposing that any new facility would not be able to operate in any area zoned as residential or mixed use, or within 150 meters of a residential or mixed use zone. Also, new chromium plating and chromic acid anodizing facilities would be required to install add-on air pollution control devices that provide the maximum hexavalent chromium reduction and undergo a site-specific analysis to ensure adequate protection of public health. These criteria will help ensure that new chromium plating and chromic acid anodizing facilities are not operated in areas where people live.

We believe these criteria are necessary to protect people from exposures to hexavalent chromium, an extremely potent, known human carcinogen. While we believe these precautions are necessary in this case, similar requirements may not be appropriate for sources of other TACs. Each TAC should be evaluated on a case by case basis to determine the appropriate methods to protect public health and reduce exposure.Chapter XI Page 126

REFERENCES

ARB, 2001b. Air Resources Board. “Policies and Actions for Environmental Justice”.

2001

Atotech, 2006a. Atotech USA Inc, GW Walker. Draft Letter to US EPA regarding proposed amendments to the Significant New Use Rule (SNUR) for perfluoroalkyl sulfonates (Docket ID: EPA-HQ-OPPT-2005-0015). 2006.

SCAQMD, 2003b. South Coast Air Quality Management District. “Draft Socioeconomic Assessment for Proposed Amendments to Rule 1469-Hexavalent Chromium Emissions from Chrome Plating and Chromic Acid Anodizing Operations and Proposed Rule 1426- Emissions from Metal Finishing Operations”. 2003

SCAQMD, 2003c. South Coast Air Quality Management District, “Final Environmental Assessment: Proposed Rule 1426 – Emissions from Metal Finishing Operations; and, Proposed Amended Rule 1469 – Hexavalent Chromium Emissions from Chrome Plating and Chromic Acid Anodizing Operations.” 2003

U.S. EPA, 1998. U.S. Environmental Protection Agency. EPA/625/R-98/002: “Capsule Report Hard Chrome Fume Suppressants and Control Technologies”. 1998.

U.S. EPA, 2006. U.S. Environmental Protection Agency. 40 CFR Part 721: “Perfluoroalkyl Sulfonates; Proposed Significant New Use Rule.” 2006.

## Appendix A

Proposed Regulation Order for the Proposed Amendments to the Chromium Plating ATCM1

H exavalent Chromium Airborne Toxic Control Measure (ATCM) for Chrome

Plating and Chromic Acid Anodizing Operations

[Note: The proposed amendments are shown in strikeout to indicate proposed

deletions and underline to indicate proposed additions. New quotation marks have been added to the definitions in section 93102.3; these quotation marks have not been underlined to make the regulations easier to read. In addition, explanatory notes are included after or before some provisions of the regulations. They are not part of the regulations; they are included for clarity and are shown in

brackets and italics: [Note......]

Amend title 17, California Code of Regulations, Section 93102, to read as follows; the amendments include a reorganization of section 93102 so that its provisions are now contained in sections 93102-93102.16:

Section 93102. Hexavalent Chromium

Airborne Toxic Control Measure for

Chrome Chromium

Plating and Chromic Acid Anodizing Operations

Facilities

.

The Airborne Toxic Control Measure for Chromium Plating and Chromic Acid Anodizing Facilities (ATCM) is contained in sections 93102 through 93102.16. The ATCM is organized as

follows:

Sections 93102 through 93102.3 specify the applicability of the ATCM, exemptions, and definitions. Section 93102.4 sets forth requirements that differ depending on whether a facility is an existing facility, a modified facility, or a new facility. Section 93102.5 sets forth various new requirements that apply to all facilities beginning [Effective Date] (i.e., all existing, modified, and new facilities). Section 93102.6 contains special provisions that apply only to enclosed hexavalent chromium electroplating facilities and facilities that perform electroplating using a trivalent chromium bath. Sections 93102.7 through 93102.14 contain additional requirements that apply to all facilities. Most of the requirements in sections 93102.7 through 93102.14 have

been in effect since 1998. Section 93102.15 sets forth requirements that apply to the manufacture, sale, supply, offer for sale, and use of chromium plating and chromic acid anodizing kits in California. There are eight appendices to the ATCM; these appendices are contained in section 93102.6.2

93102.1 (a ) Applicability.

(a) This regulation shall apply to:

(1) The owner or operator of each chromium electroplating or

chromic acid anodizing tank at facilities any facility performing hard chromium electroplating, decorative chromium electroplating, or chromic acid anodizing.

(2) Any person who sells, supplies, offers for sale, uses, or

manufactures for sale in California a chromium plating or chromic acid anodizing kit.

(b) (5) Title V Permits.

The owner or operator of a major source subject to the requirements

of this section is required to obtain a title V permit (See 42 U.S.C. 7401, et seq.) from the permitting authority of the district in which the major source is located.

(c) Severability.

Each part of this ATCM shall be deemed severable, and in the event that any part of this ATCM is held to be invalid, the remainder of this

ATCM shall continue in full force and effect.

93102.2 (2) Exemptions.

(a) This regulation shall not apply to process tanks associated with a

chromium electroplating or chromic acid anodizing process, but in which neither chromium electroplating nor chromic acid anodizing is taking place. Examples of such tanks include, but are not limited to, rinse tanks, etching tanks, electro stripping tanks and cleaning tanks. Tanks that contain a chromium solution, but in which no electrolytic process occurs, are not subject to this regulation. An example of such a tank is a chromium conversion coating tank where no electrical current is applied.

( 3) The requirements of subsections (e ) ) , (f ), and (g) do not apply to decorative chromium electroplating tanks using a trivalent chromium bath with a wetting agent.

(b) (4) The requirements of subsections 93102.4 (c) and (g) 93102.11 do

not apply during periods of equipment breakdown, provided the provisions of the permitting agency's breakdown rule are met (see Appendix 6).3

93102.3 (b) Definitions.

(a) For the purposes of this regulation, the following definitions shall

apply:

(1) “Add-on air pollution control device” means equipment installed in the ventilation system of chromium electroplating and anodizing tanks for the purposes of collecting and containing chromium emissions from the tank(s).

(2) “Air pollution control technique” means any method, such as an add-on air pollution control device, mechanical fume
suppressant or a chemical fume suppressant, that is used to reduce chromium emissions from chromium electroplating and chromic acid anodizing tanks.

(3) “Ampere-hours ” means the integral of electrical current applied to a plating tank (amperes) over a period of time (hours).

(4) “Annual Permitted Ampere-hour” means the maximum allowable chromium plating or anodizing rectifier production in ampere-hours, on an annual basis as specified in the permitting agency's Permit to Operate for the facility.

(5) (4) “Area source” means any stationary source of hazardous air pollutants that is not a major source as defined in this part.

(6) ( 5 ) “Base material ” metal means the metal or metal alloy, or plastic that comprises the workpiece.

(7) (6) “Bath component” means the trade or brand name of each component(s) in trivalent chromium plating baths. For trivalent chromium baths, the bath composition is proprietary in most cases. Therefore, the trade or brand name for each component(s) can be used; however, the chemical name of the wetting agent contained in that component must be

identified.

(8) (7) “Breakdown” means an unforeseeable impairment of an air pollution control equipment or related operating equipment which causes a violation of any emission limitation or restriction prescribed by a permitting agency's rule or by State law and which: is not the result of neglect or disregard of any air pollution control law, rule, or regulation; is not intentional or the result of negligence, or improper maintenance; is not a4 recurrent breakdown of the same equipment; and, does not constitute a nuisance pursuant to section 41700 of the California Health and Safety Code, with the burden of proving the criteria of this section placed upon the person seeking to come under the provisions of this law.

(9) (8) “Chemical fume suppressant” means any chemical agent that reduces or suppresses fumes or mists at the surface of an electroplating or anodizing bath; another term for fume suppressant is mist suppressant.

(10) (9) “Chromic acid” means the common name for chromium anhydride (CrO3).

(11) (10) “Chromic acid anodizing” means the electrolytic process by which an oxide layer is produced on the surface of a base

metal material for functional purposes (e.g., corrosion resistance or electrical insulation) using a chromic acid solution. In chromic acid anodizing, the part to be anodized acts as the anode in the electrical circuit, and the chromic acid solution, with a concentration typically ranging from 50 to 100 grams per liter (g/L), serves as the electrolyte.

(12) (11) “Chromium electroplating or chromic acid anodizing tank”

means the receptacle or container in which hard or decorative chromium electroplating or chromic acid anodizing occurs.

, along with the following accompanying internal and external tank components needed for chromium electroplating or chromic acid anodizing. These tank components include, but are not limited to, rectifiers fitted with controls to allow for voltage adjustments, heat exchanger equipment, and circulation pumps.

(13) (12) “Composite mesh-pad system” means an add-on air pollution control device typically consisting of several mesh-pad stages to remove particles . The purpose of the first stage is to remove large particles. Smaller particles are removed in the

secon d stage, which consists of the composite mesh pad. A final stage may remove any reentrained particles not collected by the composite mesh pad.

(14) (1 3 ) “Decorative chromium electroplating” means the process by which a thin layer of chromium (typically 0.003 to

2.5 microns meters ) is electrodeposited on a base metal, plastic, or undercoating material to provide a bright surface with wear and tarnish resistance. In this process, the part(s) serves as the cathode in the electrolytic cell and the solution5 serves as the electrolyte. Typical current density applied during this process ranges from 540 to 2,400 Amperes per square meter (A/m 2 ) for total plating times ranging between

0.5 to 5 minutes.

(15) “Dragout” means fluid containing hexavalent chromium that

adheres to parts when they are removed from a tank.

(16) (14) “Electroplating or anodizing bath” means the electrolytic solution used as the conducting medium in which the flow of current is accompanied by movement of metal ions for the purpose of electroplating metal out of the solution onto a workpiece or for oxidizing the base material.

(17) (15 ) “Emission limitation” means, for the purposes of this section trivalent chromium plating, the concentration of total chromium allowed to be emitted expressed in milligrams per dry standard cubic meter (mg/dscm), . For hexavalent chromium plating or anodizing, or

the allowable surface tension expressed in dynes per centimeter (dynes/cm) for decorative chromium electroplating and chromic acid anodizing tanks ; or and the milligrams of hexavalent chromium per ampere-hour (mg/amp-hr) of electrical charge applied to the chromium electroplating or anodizing tank, or the concentration of chromium allowed to be emitted expressed in milligrams per dry standard cubic meter (mg/dscm). for hard chromium electroplating tanks.

(18) “Enclosed storage area” means any space or structure used to contain material that prevents its contents from being emitted into the atmosphere. This includes cabinets, closets or sheds designated for storage.

(19) “Enclosed hexavalent chromium electroplating tank” means a

hard, decorative or chromic acid anodizing tank using a hexavalent chromium solution that is equipped with an enclosing hood and ventilated at half the rate or less that of an ventilated open surface tank of the same surface area

.

(20) "Existing Facility" means a facility that is in operation before

[Effective Date].

(21) (16) “Facility” means the major or area source at which chromium electroplating or chromic acid anodizing is performed. and/or any source or group of sources or other contaminant-emitting activities which are located on one or more contiguous6 properties within the District, in actual physical contact or separated solely by a public roadway or other public right-of way, and are owned or operated by the same person (or by persons under common control), or an outer continental shelf (OCS) source as determined in 40 CFR Section 55.2.

(22) (17) “Fiber-bed mist eliminator” means an add-on air pollution

control device that removes contaminants particles from a gas stream through the mechanisms of inertial impaction and Brownian diffusion. These devices are typically installed

downs tream of another control device, which serves to prevent plugging, and consist of one or more fiber beds. Each bed consists of a hollow cylinder formed from two concentric screens; the fiber between the screens may be fabricated from glass, ceramic, plasti c, or metal.

(23) (18) “Foam blanket” means the type of chemical fume suppressant that generates a layer of foam across the surface of a solution when current is applied to that solution. A foam blanket does not lower surface tension of a liquid.

(24) (1 9 ) “Fresh water” means water, such as tap water, that has not been previously used in a process operation or, if the water has been recycled from a process operation, it has been treated and meets the effluent guidelines for chromium

wastewater.

(25) “Fugitive dust” means any solid particulate matter that may contain hexavalent chromium that has the potential to become airborne by natural or man-made activities. “Fugitive dust” does not include particulate matter emitted from an exhaust

stack.

(26) (20 ) “Hard chromium electroplating or industrial chromium

electroplating”

means a process by which a thick layer of chromium (typically greater than 1.0 micrometers ns ) is electrodeposited on a base material to provide a surface with functional properties such as wear resistance, a low coefficient of friction, hardness, and corrosion resistance. In this process, the part serves as the cathode in the electrolytic cell and the solution serves as the electrolyte. The H h ard chromium electroplating process is performed at current densities typically ranging from 1,600 to 6,500 A/m 2 for total plating times ranging from 20 minutes to 36 hours depending upon the desired plate thickness.7

(27) (21 ) “Hexavalent chromium” means the form of chromium in a

valence state of +6.

(28) ( 22 ) “High Efficiency Particulate Air Arrestor (HEPA) filter”

means filter(s) rated at 99.97 percent or more efficient in collecting particle sizes 0.3 micrometers ns or larger.

(29) "Initial Startup" means the first time a new facility begins

production or the first time a modified chromium plating or anodizing tank begins operating at a modified facility. If such production or operation occurs prior to [Effective date], the date of "Initial Startup" is [Effective date]. "Initial Startup" does not include operation solely for testing of equipment or subsequent startup of permit units following malfunction or

shutdown.

(30) ( 23 ) “Large, hard chromium electroplating facility” means a facility that performs hard chromium electroplating and emits greater than or equal to 10 pounds per year (lbs/yr) controlled

emissions of hexavalent chromium.

(31) ( 24 ) “Leak” means the release of chromium emissions from any

opening in the emission collection system prior to exiting the

emission control device.

(32) (25 ) “Major source” means any stationary source or group of stationary sources located within a contiguous area and under common control that emits or has the potential to emit considering controls, in the aggregate, 10 tons per year or more of any hazardous air pollutant or 25 tons per year or more of any combination of hazardous air pollutants.

(33) ( 26 ) “Maximum cumulative potential rectifier capacity” means the summation of the total installed rectifier capacity associated with the hard chromium electroplating tanks at a facility, expressed in amperes, multiplied by the maximum potential operating schedule of 8,400 hours per year and 0.7, which assumes that electrodes are energized 70 percent of the total operating time. The maximum potential operating schedule is based on operating 24 hours per day, 7 days per week, 50 weeks per year.

(34) ( 27 ) “Mechanical fume suppressant” means any device, including but not limited to polyballs, that reduces fumes or mist at the surfaces of an electroplating or anodizing bath by direct8 contact with the surface of the bath. Polyballs are the most

common ly used mechanical fume suppressant.

(35) (28 ) “Medium, hard chromium electroplating facility” means a facility that performs hard chromium electroplating and emits greater than 2 pounds per year (lbs/yr) controlled emissions but less than 10 pounds per year (lbs/yr) controlled emissions

of hexavalent chromium.

(36) (29 ) “Modification” means either:

(A) any physical change in, change in method of operation of,

or addition to an existing permit unit that requires an application for a permit to construct and/or operate and

results in an increase in hexavalent chromium emissions

. Routine maintenance and/or repair shall not be considered a physical change. A change in the method of operation of equipment, unless previously limited by an enforceable permit condition, shall not include:

1. an increase in the production rate, unless such increases

will cause the maximum design capacity of the equipment to be exceeded; or

1. 2

. an increase in the hours of operation; or

2. 3. a change in ownership of a facility source ; or

3. an increase in the annual ampere-hours, unless such

increase will cause a facility to move from a lower tier to a higher tier in Table 93102.4 of section 93102.4.

(B) The the addition of any new chromium plating or anodizing

tank permit unit at an existing facility source which

increases hexavalent chromium emissions ; or

(C) the fixed capital cost of the replacement of components

exceeding 50 percent of the fixed capital cost that would be required to construct a comparable new facility source

.

(37) "Modified Facility" means any facility which has undergone a

modification.

(38) "New Facility" means any facility that begins initial operations

on or after [Effective Date]. "New Facility" does not include9 the installation of a new chromium plating or anodizing tank at an existing facility or the modification of an existing facility.

(39) ( 30 ) “Operating parameter value” means a minimum or maximum value established for a control device or process parameter which, if achieved by itself or in combination with one or more other operating parameter values, determines that an owner or operator is in continual compliance with the applicable

emission limitation or standard.

(40) “Owner or Operator” means a person who is the owner or the

operator of a facility performing hard chromium electroplating, decorative chromium electroplating, or chromic acid anodizing.

(41) (31 ) “Packed-bed scrubber” means an add-on air pollution control device consisting of a single or double packed-bed that contains packing media on which the chromic acid droplets impinge. The packed

- bed section of the scrubber is followed by a mist eliminator to remove any water entrained from the packed

- bed sec tion.

(42) “Permitting Agency” means the local air pollution control or air quality management district.

(43) "Person" shall have the same meaning as defined in Health

and Safety Code section 39047.

(44) ( 32 ) “Responsible official” means one of the following:

(A) For a corporation: A president, secretary, treasurer, or vice

president of the corporation in charge of a principal business function, or any other person who performs similar policy or decision-making functions for the corporation, or a duly authorized representative of such person if the representative is responsible for the overall operation of one or more manufacturing, production, or operating facilities and either:

1. The facilities employ more than 250 persons or have

gross annual sales or expenditures exceeding $25 million (in second quarter 1980 dollars); or

2. The delegation of authority to such representative is

approved in advance by the Administrator.10

(B) For a partnership or sole proprietorship: a general partner

or the proprietor, respectively.

(C) For a municipality, state, Federal, or other public agency:

either a principal executive officer or ranking elected official. For the purposes of this part, a principal executive officer of a Federal agency includes the chief executive officer having responsibility for the overall operations of a principal geographic unit of the agency (e.g., a Regional Administrator of the U.S. EPA).

(D) For sources (as defined in this part) applying for or subject

to a title V permit: "responsible official" shall have the same meaning as defined in 40 CFR Part 70 or federal title V regulations in this chapter (42 U.S.C. 7401, et seq.), whichever is applicable.

(45) ( 33 ) “Small, hard chromium electroplating facility” means a facility that performs hard chromium electroplating and emits less than or equal to 2 pounds per year (lbs/yr) controlled

emissions of hexavalent chromium.

(46) “Sensitive receptor” means any residence including private homes, condominiums, apartments, and living quarters; education resources such as preschools and kindergarten through grade twelve (k-12) schools; daycare centers; and health care facilities such as hospitals or retirement and nursing homes. A sensitive receptor includes long term care hospitals, hospices, prisons, and dormitories or similar live-in housing.

(47) ( 34 ) “Source” means any chromium electroplating or chromic acid anodizing operation and any equipment or materials associated with the selected associated air pollution control technique.

(48) ( 35 ) “Stalagmometer” means a device used to measure the surface

tension of a solution. an instrument used to measure the surface tension of a solution by determining the mass of a drop of liquid by weighing a known number of drops or by counting the number of drops obtained from a given volume of liquid.

(49) ( 36 ) “Surface tension” means the property, due to molecular forces, that exists in the surface film of all liquids and tends to prevent liquid from spreading.11

(50) “Tank” means the structure or receptacle containing the

electroplating or anodizing bath.

(51) ( 37 ) “Tank operation” means the time in which current and/or voltage is being applied to a chromium electroplating tank or a chromic acid anodizing tank.

(52) (38 ) “Tensiometer” means a device used to measure the surface

tension of a solution. an instrument used to measure the surface tension of a solution by determining the amount of force needed to pull a ring from the liquid surface. The amount of force is proportional to the surface tension.

(53) ( 39 ) “Trivalent chromium” means the form of chromium in a

valence state of +3.

(54) ( 40 ) “Trivalent chromium process” means the process used for

electrodeposition of a thin layer of chromium onto a base material using a trivalent chromium solution instead of a

chromic acid solution.

(55) ( 41 ) “Weekly” means at least once every seven calendar days.

(56) ( 42 ) “Wetting agent” means the type of chemical fume suppressant that reduces the surface tension of a liquid.

93102.4 (c) Standards Requirements for Existing, Modified, and New

Hexavalent Chromium Plating and Chromic Acid Anodizing

Facilities

.

This section 93102.4 sets forth requirements that apply to all

hexavalent chromium hard and decorative chromium electroplating and chromic acid anodizing facilities, except for facilities subject to section 93102.6 (i.e., facilities that perform electroplating using a trivalent chromium bath and are enclosed hexavalent chromium electroplating facilities). The requirements differ depending on whether a facility is an existing facility, a modified facility or a new facility. Additional requirements that apply to all facilities ( i.e. , all existing, modified, and new facilities) are contained in section 93102.5 and sections 93102.7 through 93102.14

.

Subsection (a) contains the requirements to reduce hexavalent chromium emissions that were in effect before [Effective Date]. The limits in subsection (a) shall remain in effect for a facility12 until the limits in subsection (b) become effective. Once the limits in subsection (b) become effective for an individual facility the limits in subsection (a) no longer apply.

The limits in subsection (b) are phased in depending on the amount of annual permitted ampere-hours and the distance to the nearest sensitive receptor. Depending on the facility, limits in subsection (b) become effective on [Six Months after Effective Date], [Two Years after Effective Date], or [Five Years after Effective Date].

(a) (1) Requirements that Apply to Existing Hexavalent Chromium

Electroplating and Chromic Acid Anodizing Facilities.

An existing facility is a facility that is in operation before [Effective

Date].

In addition to the limits specified in this subsection (a) all facilities ( i.e. , all existing, modified, and new facilities) must comply with the applicable provisions contained in section 93102.5 and sections 93102.7 through 93102.14.

(1) Limits that Apply to Existing Hard Chromium Electroplating

Facilities Until the Limits in subsection (b) Become Effective. Hard Chrome Electroplating Operations

.

During tank operation, each owner or operator of an existing, modified, or new source facility shall control hexavalent chromium emissions discharged to the atmosphere from that facility source by reducing the hexavalent chromium emissions from the add-on air pollution control device(s) serving the electroplating tank(s) as identified below.13

(A) Limits that Apply Until the Limits in subsection (b) Become

Effective for Existing Operations (on or before 12/16/93) Hard Chromium Electroplating Facilities that Began Operations on or before December 16, 1993.

Requirement

< 60 million amp-hrs 2 > 60 million amp-hrs 2 Facility Size Controlled

emissions 1
(lbs/yr) Option 1 Option 2 3

Large > 10 lbs/yr < 0.006 mg/amp-hr < 0.006

mg/amp-hr < 0.006

mg/amp-hr Medium < 10 lbs/yr but

> 2 lbs/yr < 0.03

mg/amp-hr < 0.006

mg/amp-hr < 0.03

mg/amp-hr

and 0.015 mg/dscm

Small < 2 lbs/yr < 0.15 mg/amp-hr < 0.03

mg/amp-hr < 0.15

mg/amp-hr

and 0.015 mg/dscm

(B) New and/or Modified Operations (after 12/16/93) Limits

that Apply Until the Limits in subsection (b) Become Effective for Existing Hard Chromium Electroplating Facilities that Began Operations after December 16, 1993, and Before [Effective Date].

Requirement Facility Size Controlled

Emissions 1 (lbs /yr) < 60 million amphrs 2 > 60 million amphrs 2

Large > 10 lbs/yr < 0.006 mg/amphr < 0.006 mg/amphr Medium/ Small < 10 lbs/yr < 0.03 mg/amp-hr < 0.006 mg/amphr

1 combined hexavalent or total chrome chromium emissions from hard chrome

chromium plating operations.

2 maximum cumulative potential rectifier capacity or usage limit.

3 “Option 2” is an alternative emission limitation for small and medium facilities that elect to demonstrate compliance with both a mg/amp-hr and a mg/dscm requirement.

(C) Special Provisions that Apply for some Hard Chromium

Electroplating Facilities Using Less than or Equal to 500,000 Ampere-hours per Year Until the Limits in subsection (b) Become Effective. Very small operations using less than or equal to 500,000 ampere

- hours per

year.14 The permitting agency may approve, on a case-by-case basis, alternative standards for small hard chrome plating operations chromium electroplating facilities using less than or equal to 500,000 ampere-hours per year. The operation must have been constructed on or before December 16, 1993. At a minimum, the source facility must use a chemical fume suppressant containing a wetting agent to lower the surface tension of the plating bath to at least 45 dynes per centimeter (dynes/cm) (3.1x10 -3 pound-force per foot [lbF/ft]). The permitting agency may require additional emission reduction techniques as necessary to reduce the public health impact of emissions from the operation. The owner or operator must comply with the applicable monitoring [subsection ( e )

93102.9 ], recordkeeping [subsection (h) 93102.12 ], and reporting [subsection (i) 93102.13 ] requirements. The owner or operator must submit a plan to the permitting agency describing the alternative technique and identifying appropriate monitoring, recordkeeping, and reporting requirements. The permitting agency, with U.S. EPA concurrence, shall approve this plan if equivalent results are obtained. Upon approval, the requirements identified in the plan shall be the applicable requirements under this regulation.

(2) Requirements that Apply to Existing Hexavalent Decorative

Chrome ium

Electroplating and Chromic Acid Anodizing Facilities Until the Limits in subsection (b) Become Effective.

During tank operation, each owner or operator of an existing

, modified, or new source decorative hexavalent chromium electroplating or chromic acid anodizing facility shall control hexavalent chromium emissions discharged to the atmosphere by meeting either of the requirements identified below.

Method of compliance Requirement

1. add-on air pollution control equipment, or chemical fume suppressants, or mechanical fume suppressants (i.e. polyballs) 0.01 milligrams per dry standard cubic meter of air (mg/dscm) (4.4x10 -6 gr/dscf)

2. chemical fume suppressants containing a wetting agent 45 dynes per centimeter (dynes/cm) (3.1x10 -3 pound-force per foot [lbF/ft])15

(b) Limits that Apply to All Existing Hexavalent Hard and Decorative

Chromium Electroplating and Chromic Acid Anodizing Facilities After [Effective Date].

(1) During tank(s) operation, each owner or operator of an

existing hexavalent chromium facility shall control hexavalent chromium emissions discharged to the atmosphere by meeting the requirements identified below.

[ Table 93102.4 is a newly proposed table. It is not shown in underline for clarity ]

Table 93102.4: Hexavalent Chromium Emission Limits for Existing

Facilities

Tiers of

Annual

Permitted Ampere-Hours Sensitive

Receptor

Distance 1 Emission Limitation Effective Date

Tier 1

< 20,000 Any Use Chemical Fume Suppressant as specified in section 93102.8 2 [Six Months after Effective Date]

Tier 2 > 20,000 and

< 200,000 < 100

Meters 0.0015 milligrams/ampere-hour 3 [Two Years after Effective Date]

Tier 3 > 20,000 and

< 200,000 > 100

Meters 0.0015 milligrams/ampere-hour 3 [Five Years after Effective Date]

Tier 4
> 200,000 Any 0.0015 milligrams/ampere-hour 4, 5 [Two Years after Effective Date]

1 Distance shall be evaluated by the permitting agency.

2 Alternatively, [Two Years after Effective Date] facility shall comply with the requirement for facilities with > 20,000 and < 200,000 annual permitted ampere-hours.

3 Emission limit compliance may be demonstrated without using add-on air pollution control device(s). If an add-on air pollution control device has been installed, the emission limitation shall be measured after the add-on air pollution control device.

4 Measured after add-on air pollution control device(s).

5 When actual annual emissions exceed 15 grams a site specific analysis must be conducted in accordance with the permitting agency’s procedures.

(2) Demonstrating Compliance with the Emission Limitation in

Table 93102.4

(A) Facilities complying with Tier 2 or Tier 3 requirements in

Table 93102.4 may demonstrate compliance with the emission limitation of 0.0015 milligrams/ampere-hour without the use of an add-on air pollution control device(s). At a minimum, if the facility is demonstrating compliance16 with the Tier 2 or Tier 3 requirements in Table 93102.4 without an add-on air pollution control device(s), the facility must use a chemical fume suppressant as specified in

section 93102.8.

(B) Facilities complying with Tier 4 requirements in Table 93102.4 must use an add-on air pollution control

device(s) to control hexavalent chromium emissions and demonstrate compliance with the emission limitation of 0.0015 milligrams/ampere-hour as measured after the add-on air pollution control device.

(c) Requirements for Modified Hexavalent Chromium Electroplating or

Chromic Acid Anodizing Facilities.

(1) During tank operation, each owner or operator of a

modified facility shall upon initial start-up control hexavalent chromium emissions discharged to the atmosphere from that facility by reducing the hexavalent chromium emissions from the electroplating or anodizing tank(s) by:

(A) Using an add-on air pollution device(s) to control

hexavalent chromium emissions, and

(B) Meeting an emission limit of 0.0015 milligrams per

ampere-hour or less as measured after add-on controls.

(2) Prior to initial start-up of a modified facility, with actual annual

emissions of hexavalent chromium exceeding 15 grams per year, the owner or operator shall conduct a site specific analysis in accordance with the permitting agency’s procedures.

(d) Requirements for New Hexavalent Chromium Electroplating and

Chromic Acid Anodizing Facilities Beginning [Effective Date].

(1) No person shall operate a new facility unless it is located

outside of an area that is zoned for residential or mixed use

and is located at least 150 meters from the boundary of any

area that is zoned for residential or mixed use as determined by the permitting agency.

(A) A new facility shall be deemed to meet the requirements

specified in this subsection (d)(1) if one of the following criteria is met, even if the facility does not meet the17 requirement at the time of initial startup (e.g., because of a zoning change that occurs after the authority to construct is issued):

1. The requirements specified in this subsection (d)(1) are

met at the time it is issued an authority to construct by the permitting agency, and substantial use of the authority to construct takes place within one year after it is issued; or

2. The requirements specified in this subsection (d)(1) are

met at the time it is issued an authority to construct by the permitting agency, and substantial use of the authority to construct takes place before any zoning change occurs that affects the operation’s ability to meet the requirement at the time of initial startup.

(2) During tank operation, each owner or operator of a new facility

shall control hexavalent chromium emissions discharged to the atmosphere from that facility by reducing the hexavalent chromium emissions from the electroplating or anodizing tank(s) by installing a HEPA add-on air pollution control

device. The measured emission rate of hexavalent chromium shall be no more than 0.0015 milligrams per ampere-hour as measured after the HEPA add-on air pollution control device.

(3) Prior to initial start-up each new facility shall conduct a site

specific analysis in accordance with the permitting agency’s procedures.

(4) Prior to initial startup, each new facility shall demonstrate to

the permitting agency that the new facility meets the requirements specified in this subsection (d).18

( 3) Decorative Chromium Electroplating Tanks Using a Trivalent Chromium

Bath.

[Note: This subsection has been modified and moved to section 93102.6 of this regulation]

During tank operation, each owner or operator of an existing, modified, or new source shall control chromium emissions discharged to the atmosphere by meeting either of the requirements identified below.

Method of compliance Requirement

a dd

- on air pollution control equipment, or chemical fume suppressants, or mechanical fume suppressants (i.e. polyballs) < 0.01 mg/dscm (4.4x10 - 6 g r/dscf)

c hemical fume suppressants containing a wetting agent use wetting agent as bath ingredient and comply with recordkeeping and reporting provisions of subsections ( h )(9) and ( i )(5).

(e) Notification Requirements for New and Modified Facilities.

[Note: This subsection has been moved from section 93102.13 (j) to this

section 93102.4 (c) . It has also been modified.]

(1) Notification of Construction Reports.

(A) No person may construct or modify a facility, such that it becomes a facility subject to this section 93102, without submitting a notification of construction or modification to the permitting agency and receiving approval in advance to construct or modify the facility

.

(B) The contents of the Notification of Construction Report shall include the information contained in Appendix 4.

(2) Alternative Notification Requirements: Instead of complying with the requirements in subpart paragraph (e)(1)(A) of this subsection, a facility may fulfill these requirements by complying with the permitting agency's “New Source Review” requirements, provided similar information is obtained.19

93102.5 Requirements that Apply to Existing, Modified, and New

Hexavalent Chromium Plating or Chromic Acid Anodizing Facilities Beginning [Effective Date].

Each owner or operator of a hexavalent chromium plating or chromic acid anodizing facility shall comply with the following requirements on or after the dates specified below:

(a) Removal of Add-on Pollution Control Device(s). No add-on air

pollution control device(s) installed before [Effective Date] shall be removed or rendered inoperable unless it is replaced by an add-on air pollution control device(s) meeting an emission rate of 0.0015 mg/amp-hr or less as measured after the add-on air pollution

control device.

(b) Environmental Compliance Training. No later than [Two Years After

Effective Date] and within every two years thereafter, the owner or operator of a facility, or personnel designated by the owner or operator that are responsible for maintaining environmental compliance, shall complete an Air Resources Board (ARB) Compliance Assistance Training Course.

(1) On or after [Two Years After the Effective Date] environmental

compliance and recordkeeping required by this section 93102 shall be conducted only by persons who completed an ARB Compliance Assistance Training Course.

(2) In the event that all persons who have completed the ARB

training class are no longer associated with a facility, the owner or operator may be responsible for environmental compliance and recordkeeping required by this section for a period of time not to exceed two years. The owner or operator shall ensure that as soon as practicable, but not longer than two years, personnel complete the training specified in subsection 91302.5(b).

(3) Environmental compliance training conducted by the South

Coast Air Quality Management District pursuant to Rule 1469 shall fulfill the requirements of this subpart.

(4) Nothing in this subsection 91302.5(b) shall absolve an owner

or operator from complying with this section 93102.20

(c) Housekeeping Requirements. Effective [Six Months After Effective

Date], housekeeping practices shall be implemented to reduce potential fugitive emissions of hexavalent chromium. At a minimum, the following practices shall be implemented:

(1) Chromic acid powder or flakes, or other substances that may

contain hexavalent chromium, shall be stored in a closed container in an enclosed storage area;

(2) Chromic acid powder or flakes shall be transported from an

enclosed storage area to the electroplating or anodizing bath(s) in a closed container;

(3) Any liquid or solid material that may contain hexavalent

chromium that is spilled shall be cleaned up or contained within one hour after being spilled.

(4) (D) Dragout from the tank(s) shall be minimized by implementing

the following practices:

(A) Facilities with automated lines. Drip trays shall be installed

between tanks so that the liquid does not fall through the space between tanks. Trays shall be placed such that the liquid is returned to the tank(s).

(B) Facilities without automated lines.

1. Each electroplated or anodized part must be handled so

that excess chromic acid is not dripped outside the electroplating tank.

2. Each facility spraying down parts over the electroplating

or anodizing tank(s) to remove excess chromic acid shall have a splash guard installed around the tank to minimize overspray and to ensure that any hexavalent chromium laden liquid is returned to the electroplating or anodizing tank.

(5) Surfaces within the enclosed storage area, open floor area,

walkways around the electroplating or anodizing tank(s), or any surface potentially contaminated with hexavalent chromium, that accumulates or potentially accumulates dust shall be HEPA vacuumed, hand wiped with a damp cloth, or wet mopped, or shall be maintained with the use of non-toxic chemical dust suppressants at least once every seven days.21

(6) Buffing, grinding, or polishing areas within a facility shall be

separated from the facility by installing a physical barrier. The barrier may take the form of plastic strip curtains.

(7) Chromium or chromium-containing wastes generated from

housekeeping activities shall be stored, disposed of, recovered, or recycled using practices that do not lead to fugitive dust and in accordance with hazardous waste requirements.

93102.6 Special Provisions that Apply Only to Facilities that Perform

Electroplating Using a Trivalent Chromium Bath and Enclosed Hexavalent Chromium Electroplating Facilities.

(a) Provisions that Apply to All Facilities that Perform Electroplating

Using a Trivalent Chromium Bath.

(1) During tank operation, each owner or operator of an existing,

modified, or new facility shall control chromium emissions discharged to the atmosphere by meeting either of the requirements identified below.

[Note: This is an existing table that has been moved from section (c)(3) of the existing regulation. It has not been underlined in order to make it easier to read.]

Method of compliance Requirement add-on air pollution control equipment, or chemical fume suppressants, or mechanical fume suppressants (i.e. polyballs) < 0.01 mg/dscm (4.4x10 -6 gr/dscf)

chemical fume suppressants containing a wetting agent use wetting agent as bath ingredient and comply with recordkeeping and reporting provisions of sub sections (h ) (9) 93102.12 (i) and (i)(5) 93102.13 (e)

.

(2) New facilities that perform electroplating using a trivalent

chromium bath must comply with the requirements specified in section 93102.4 (d)(1)

.

(3) An owner or operator that performs electroplating using a

trivalent chromium bath and complying through use of a chemical fume suppressant containing a wetting agent shall not be required to comply with the requirements of sections 93102.4 (except for section 93102.4(d)(1)), 93102.7, 93102.8,22 93102.9 (b) through (f), 93102.10, 93102.11, 93102.12 (a) through (f), and 93102.12 (h).

(b) (2) Requirements for Enclosed Hexavalent Chromium Electroplating

Tanks.

(1) The owner or operator of a hexavalent chromium

electroplating facility with enclosed hexavalent chromium plating tank(s) shall control hexavalent chromium emissions from the electroplating tank(s) by:

(A) Achieving a hexavalent chromium emission limitation of

0.015 mg/dscm as measured after the add-on air pollution control device(s); or

(B) Using a chemical fume suppressant specified in section

93102.8, and maintaining the surface tension of the plating bath solution at a value specified in section 93102.8; or

(C) Not allowing the mass rate of the total chromium to exceed

the maximum allowable mass emission rate determined by using the calculation procedure specified in Appendix 7.

(2) The owner or operator of a facility with enclosed hexavalent

chromium plating tank(s) must also comply with all requirements of this ATCM except for the requirements set forth in section 93102.4(b) and (c).

93102.7 (d) Performance Test Requirements and Test Methods.

(a) (1) Performance test requirements

.

Any source subject to the emission standards in subsection (c)(1)(A) or (B), or any source electing to comply with the mg/dscm emission standard in subsections (c)(2) or (c)(3) shall conduct a performance test to demonstrate compli ance with the applicable emission

standards within 180 days after initial startup.

(1) The following facilities must conduct a performance test to

demonstrate compliance with the hexavalent chromium emission rate as specified in section 93102.4:

(A) Existing facilities demonstrating compliance with the

0.0015 milligrams per ampere-hour emission limitation specified in Table 93102.4.23

(B) Facilities that undergo a modification after [Effective Date].

(C) New facilities.

(D) Trivalent chromium plating facilities meeting the emission

rate specified in section 93102.6 (a)(1)

.

(2) Facilities must conduct the performance test required by this

section 93102.7 no later than 60 days after initial start-up.

(3) The performance test must be conducted using one of the

approved test methods specified in subsection 93102.7(c). The hexavalent chromium emission rate shall be multiplied by the facility annual permitted ampere-hour usage to determine the annual emissions of hexavalent chromium for the facility.

(b) (2) Use of existing previously conducted

performance test.

A performance test conducted prior to July 24, 1997 may be used to demonstrate compliance provided the existing source test is approved by the permitting agency and the U.S. EPA.

A performance test conducted after January 1, 2000 may be used to satisfy the requirements of this section 93102.7 so long as all of the following criteria are met:

(1) The add-on air pollution control device tested demonstrated a

hexavalent chromium emission rate of 0.0015 mg/amp-hr or less for hexavalent chromium plating or chromic acid anodizing facilities, or 0.01mg/dscm or less for trivalent chromium plating facilities, and

(2) The performance test was approved by the permitting agency,

and

(3) The test is representative of the add-on air pollution control

device currently in use as of [Effective Date], and

(4) The performance test was conducted using one of the

approved test methods specified in subsection 93102.7(c).

(c) (3) Approved test methods.

(1) (A) Emissions testing for hexavalent and total chromium shall

be conducted with a minimum of three test runs in accordance with one of the following test methods:24

(A) 1. California Air Resources Board CARB Test Method 425,

last amended July 28, 1997, (section 94135, Title 17, California Code of Regulations (CCR); or

(B) 2

. U.S. EPA Method 306, (40 CFR 63 Appendix A) with a

minimum of three test runs with hexavalent chromium option (Method 306, Section 2.2.3) ; or

(C) 3

. South Coast Air Quality Management District

Method 205.1, for results reported as total chromium

.

(2) ( B ) Smoke Test to Verify the Seal Integrity of Covers Designed to

Reduce Chromium Emissions from Electroplating and Anodizing Tanks (See Appendix 5).

(3) (C ) Surface tension using a tensiometer shall be measured in accordance with U.S. EPA Method 306B (40 CFR 63 Appendix A). Surface tension using a stalagmometer shall be measured using the procedure set forth in Appendix 8, or an alternative procedure approved by the permitting agency.

(d) ( 4 ) Pre-Test protocol. Facilities S ources subject to the provisions of

sub section (d) (1), above, 93102.7 (a) must submit a pre-test protocol to the permitting agency at least 60 days prior to conducting a performance test. The pre-test protocol shall include the performance test criteria of the end user and all assumptions, required data, and calculated targets for testing the source target chromium concentration, the preliminary chromium analytical data, and the planned sampling parameters. In addition, the pre-test protocol shall include information on equipment, logistics, personnel, and other resources necessary for an efficient and coordinated test.

(e) ( 5 ) Test all emission points. Each emission point subject to the

requirements of this regulation must be tested unless a waiver is granted by U.S. EPA and approved by the permitting agency.25

93102.8 Chemical Fume Suppressants.

Chemical fume suppressants used to comply with sections 93102.4 and 93102.6 shall meet the criteria specified in this section 93102.8.

(a) One or more of the chemical fume suppressants listed in

Table 93102.8 shall be used to reduce the surface tension of the electroplating or anodizing bath(s) below the surface tension value listed in Table 93102.8. The surface tension value may be measured using either a stalagmometer or a tensiometer.

[Table 93102.8 is a new table. For clarity it is not shown in underline/strikeout ]

Table 93102.8: Chemical Fume Suppressants Approved for Use at

Specified Surface Tensions

Chemical Fume Suppressant and

Manufacturer Stalagmometer

Measured

Surface Tension (dynes/centimeter) Tensiometer

Measured Surface

Tension (dynes/centimeter)

Benchbrite CR 1800®

Benchmark Products < 40 < 35

Clepo Chrome®

MacDermid < 40 < 35

Fumetrol 140®

Atotech U.S.A. < 40 < 35

(b) Alternative chemical fume suppressants. Chemical fume

suppressants not listed in Table 93102.8 may be used upon approval by the Executive Officer. The Executive Officer shall approve the use of an alternative chemical fume suppressant if the following criteria

are met:

(1) The chemical fume suppressant has been performance tested

in a hexavalent chromium electroplating or anodizing bath and

demonstrated to reduce the hexavalent chromium emissions below 0.01 milligrams per ampere hour; and

(2) In the performance testing, the hexavalent chromium emission

rate of 0.01 milligrams per ampere-hour was achieved under

conditions in which the surface tension did not exceed 45 dynes/cm, as measured by a stalagmometer or 35 dynes/cm, as measured by a tensiometer.

(c) A chemical fume suppressant that is listed in subsection 93102.8(a)

or that has been approved under subsection 93102.8(b) may no26 longer be used if the Executive Officer determines that the chemical fume suppressant is no longer able to reduce the hexavalent chromium emission rate below 0.01 milligrams per ampere-hour

under conditions in which the surface tension does not exceed 45 dynes/cm, as measured by a stalagmometer or 35 dynes/cm, as measured by a tensiometer.

93102.9 (e) Parameter Monitoring Requirements

.

(a) (1) Ampere-hours. Each electroplating or anodizing tank or group of

electroplating or anodizing tanks shall have installed a continuous recording, non resettable, ampere-hour meter that operates on the electrical power lines connected to the tank or group of tanks. A separate meter shall be hard-wired for each rectifier.

(b) (2) Pressure drop. The owner or operator shall continuously monitor the

pressure drop across an add-on control device such as a compositemesh-pad (CMP), packed-bed scrubber (PBS), a CMP/PBS, fiberbed mist eliminator, and a High Efficiency Particulate Air Arrestor (HEPA) filter with a mechanical gauge. The gauge shall be located so that it can be easily visible and in clear sight of the operation or maintenance personnel. The pressure drop shall be maintained

within ± 1 +2 inches of water of the value established during the performance test to demonstrate compliance with the emission limitation for CMP, PBS, a CMP/PBS, and a fiber-bed mist eliminator. The pressure drop shall be maintained within - 1⁄2 times to +2 times the inches of water of the value established during the performance test to demonstrate compliance with the emission limitation for HEPA

filters.

(c) (3) Inlet velocity pressure. The owner or operator shall continuously

monitor the inlet velocity pressure of a packed-bed scrubber with a mechanical gauge. The gauge shall be located so that it can be easily visible and in clear sight of the operation or maintenance personnel. The inlet velocity pressure shall be maintained within

+ 10 percent of the value established during the performance test to

demonstrate compliance with the emission limitation.

(d) (4) Surface tension. The owner or operator shall measure and monitor

the surface tension of the chrom e electro plating or chromic acid anodizing tank bath(s) that contains a wetting agent with either a stalagmometer using the procedure in Appendix 8 of this section 93102 or a procedure approved by the permitting agency, or with a tensiometer using U.S. EPA Method 306B (40 CFR part 63, Appendix A) . The surface tension shall be maintained at or below the value required by sub section (c)(2) 93102.8. Surface tension27 shall be measured daily for 20 operating days, and weekly thereafter as long as there is no violation of the surface tension requirement. If a violation occurs, the measurement frequency shall return to daily for 20 operating days, and weekly thereafter.

(e) (5) Foam blanket thickness. The owner or operator shall monitor the

foam blanket thickness across the surface of the chrom e electro plating or chromic acid anodizing bath tank . The foam blanket thickness shall be maintained consistent with the requirements established during the performance test to demonstrate compliance

with the emission limitation. Foam thickness shall be measured hourly for 15 operating days, and daily thereafter as long as there is no violation of the foam thickness requirement. If a violation occurs, the measurement frequency shall return to hourly for 15 operating days, and daily thereafter.

(f) (6) Polyballs or similar m M echanical fume suppressants. The owner or operator shall visually inspect the chrom e electro plating or chromic

acid anodizing tank

bath for coverage comparable to the coverage during the performance test daily.

91302.10 (f) Inspection and Maintenance Requirements.

(a) (1) Hard and decorative chrom e Hexavalent chromium electroplating,

and chromic acid anodizing operati ons facilities using add

- on air pollution control equipment shall comply with the applicable inspection and maintenance requirements listed in

Table 93102.10 (f )(1)

.

Table 93102.10 (f )(1) -- Summary of Inspection and Maintenance Requirements for Sourc es Using Add

- on Air Pollution Control Devices

Control Technique/Equipment Inspection and Maintenance Requirements Frequency

Composite mesh-pad (CMP) system.

, Packed-bed scrubber (PBS), or PBS/CMP 1. Visually inspect device to ensure that there is proper drainage, no unusual chromic acid buildup on the pads, and / or packed beds and no

evidence of chemical attack that affects the structural integrity of the device. 1. 1/quarter.28 2. Visually inspect back portion of the mesh pad closest to the fan to ensure there is no breakthrough of chromic acid mist and/or back portion of the

chevron mist eliminator to ensure it is dry and there is no breakthrough of

chromic acid mist

. 2. 1/quarter.

3. Visually inspect ductwork from tank

to the control device to ensure there

are no leaks. 3. 1/quarter.

4. Perform washdown of the composite

mesh

- pads in accordance with

manufacturer's recommendations and/or add fresh makeup water to the packed bed when it is needed

. 4. Per

manufacturer.

P acked

- bed scrubber (PBS) 1. Visually inspect device to ensure there is proper drainage, no unusual chromic acid buildup on the packed

beds, and no evidence of chemical

attack that affects the structural integrity of the device. 1. 1/quarter.

2. Visually inspect back portion of the

chevron blade mist eliminator to ensure that it is dry and there is no breakthrough of chromic acid mist. 2. 1/quarter.

3. Same as number 3 above for CMP
system. 3. 1/quarter.

4. Add fresh makeup water to the packed

- bed A 4. Whenever makeup is

needed. PBS/CMP system 1. Same as for CMP system 1. 1/quarter. 2. Same as for CMP system 2. 1/quarter. 3. Same as for CMP system 3. 1/quarter. 4. Same as for CMP system 4. Per

manufacturer.

Fiber-bed mist

eliminator A B 1. Visuall y inspect fiber

- bed unit and prefiltering device to ensure there is proper drainage, no unusual chromic acid buildup in the units, and no

evidence of chemical attack that affects the structural integrity of the devices.

Same as number 1 for CMP/PBS. 1. 1/quarter.

2. Visually inspect ductwork from tank

or tanks to the control device to ensure

there are no leaks. Same as number 3

for CMP/PBS. 2. 1/quarter.29 3. Perform washdown of fiber elements

in accordance with manufacturer's

recommendations . Same as number 4

for CMP/PBS. 3. Per

manufacturer.

High Efficiency

Particulate Air

Arrestor (HEPA) filter 1. Look for changes in the pressure drop.

2. Replace HEPA filter. 1. 1/week.

2. Per

manufacturer's specifications or permitting agency's requirement.

Chromium Tank

Covers [facilities complying

with subsection 93102.6(b) 1. Drain the air-inlet (purge air) valves at the end of each day that the tank is in operation. 1. 1/day.

2. Visually inspect access door seals and membranes for integrity. 2. 1/week.

3. Drain the evacuation unit directly into the plating tank or into the rinse tanks (for recycle into the plating tank). 3. 1/week.

4. Visually inspect membranes for perforations using a light source that adequately illuminates the membrane (e.g., Grainger model No. 6X971 Fluorescent Hand Lamp). 4. 1/month.

5. Visually inspect all clamps for proper operation; replace as needed. 5. 1/month.

6. Clean or replace filters on

evacuation unit. 6. 1/month.

7. Visually inspect piping to, piping from, and body of evacuation unit to

ensure there are no leaks and no

evidence of chemical attack. 7. 1/quarter.

8. Replace access door seals, membrane evacuation unit filter, and purge air inlet check valves in

accordance with the manufacturer's

recommendations. 8. Per

manufacturer.30

Pitot tube Backflush with water, or remove from

the duct and rinse with fresh water. Replace in the duct and rotate 180 degrees to ensure that the same zero reading is obtained. Check pitot tube ends for damage. Replace pitot tube if cracked or fatigued. 1/quarter.

Ampere-hour meter Install and maintain per manufacturer's specifications. Per

manufacturer. Stalagmometer/

Tensiometer Calibrate and maintain per manufacturer’s specifications. Per

manufacturer.

A Horizontal packed

- bed scru bbers without continuous recirculation must add

make

- up water to the top of the packed

- bed.

A B Inspection and maintenance requirements for the control device installed upstream of the fiber-bed mist eliminator to prevent plugging do not apply as long as the inspection and maintenance requirements for the fiber-bed unit are

followed.

(2) Hard and decorative chrome electroplating, and chromic acid anodizing operations using chemical fume suppressants (i.e. wetting agent, foam) or mechanical fume suppressa nts (i.e. polyballs) shall comply with the applicable inspection and maintenance requirements in Table (f)(2).

Note: Table (f)(2) is proposed for deletion

Table (f)(2)

-- Summary of Inspection and Maintenance Requirements for Sources Using Chemical or Me chanical Fume Suppressants

Equipment Inspection and

Maintenance Requirement for Monitoring Equipment Frequency

Ampere

- hour meter

Install and maintain per

manufacturer's specifications Per manufacturer

Stalagmometer/

Tensiometer Calibrate and maintain

pe r manufacturer’s specifications Per manufacturer

(b) Add-on air pollution control device(s) that is custom designed for a

specific operation shall develop operating and maintenance requirements. The requirements shall be submitted to the permitting agency for review and approval. The requirements and frequency of inspection must be sufficient to ensure compliance.31

93102.11 (g) Operation and Maintenance Plan (O & M plan)

Requirements.

(a) (1) Prepare the O & M plan. The owner or operator subject to the

inspection and maintenance requirements of subsections 93102.10(a) and (b) (f)(1) shall prepare an operation and maintenance plan. For major sources, the plan shall be incorporated by reference into the source's title V permit. The plan shall incorporate the inspection and maintenance requirements for that device or monitoring equipment, as identified in Table 93102.10 (f)(1) or subsection 93102.10 (b) of this section and include the following

elements:

(1) (A) A standardized checklist to document the operation and

maintenance of the facility source , the add-on air pollution control device, and the process and control system monitoring equipment; and

(2) (B) Procedures to be followed to ensure that equipment is

properly maintained. [To satisfy the inspection and

maintenances requirements of this subsection, the owner or operator may use applicable standard operating procedure (SOP) manuals, Occupational Safety and Health Administration (OSHA) plans, or other existing plans, provided the alternative plans meet the requirements of this subsection.]

(b) (2) Retain the O & M plan. The owner or operator shall keep the written

operation and maintenance plan on record after it is developed to be made available for inspection, upon request, during normal working

hours.

(c) (3) Changes to the O & M plan. Any changes made by the owner or

operator should be documented in an addendum to the plan. In addition, the owner or operator shall keep previous (i.e., superseded) versions of the operation and maintenance plan on record to be made available for inspection, upon request, during normal working hours, for a period of 5 years after each revision to the plan.

(d) (4) Revisions to the O & M plan to address breakdowns. The operation

and maintenance plan shall be revised as necessary to minimize

breakdowns.

93102.12 (h) Recordkeeping Requirements.32

(a) (1) Inspection records for sources using add

- on control air pollution

control devices . The owner or operator shall maintain inspection records to document that the inspection and maintenance requirements of sub section (f) 93102.10 and Table (f) (1) 93102.10

, and the provisions of the operation and maintenance plan required by

sub section (g) 93102.11 have been met. The record can take the form of a checklist and shall identify:

(1) (A) the device inspected,

(2) (B ) the date and time of inspection,

(3) (C ) a brief description of the working condition of the device during

the inspection,

(4) ( D ) maintenance activities performed on the components of the air

pollution control system (i.e. duct work replacement, filter pad replacement, fan replacement, etc), and

(5) ( E ) actions taken to correct deficiencies found during the

inspection.

(2) Inspection records for sources using chemical fume suppressants (i.e. wetting agent , foam) or mechanical fume suppressants (i.e. polyballs). The owner or operator shall maintain inspection records to document that the inspection and maintenance requirement of subsection (f)(2) and Table (f)(2) have been met. The record can take the form of a checklist.

(b) (3) Performance test records. The owner or operator shall maintain test

reports documenting the conditions and results of all performance

tests.

(c) (4 ) Monitoring data records. The owner or operator shall maintain

records of monitoring data required by sub section 93102.9 (e) that are used to demonstrate compliance with the standard including the

date and time the data are collected.

(1) (A) Cumulative rectifier usage records. Record the actual

cumulative rectifier usage expended during each month of the reporting period, and the total usage expended to date.

(2) ( B ) Pressure drop. The owner or operator shall record the

pressure drop once a week.

(3) ( C ) Inlet Velocity Pressure. The owner or operator shall record

the inlet velocity pressure weekly.33

(4) ( D ) Surface tension. The owner or operator shall record the

surface tension daily for 20 operating days, and weekly thereafter as long as there is no violation of the surface tension requirement. If the surface tension exceeds 45 dyn es/cm levels specified in section 93102.8 , the owner or operator shall again record the surface tension daily for 20 operating days, and weekly thereafter.

(5) (E ) Foam thickness. The owner or operator shall record the foam

thickness hourly for 15 operating days, and daily thereafter as long as there is no violation of the foam thickness requirement. If a violation occurs, the measurement frequency shall return to hourly for 15 operating days, and daily thereafter.

(d) (5) Breakdown records . The owner or operator shall maintain records of

the occurrence, duration, and cause (if known) and action taken on

each breakdown.

(e) (6) Records of excesses. The owner or operator shall maintain records

of exceedances of: the emission limitations in sub section 93102.4 (c)

, the monitoring parameter values established under sub section (e)

93102.9 , or any site-specific operating parameters established for alternative equipment. The records shall include the date of the occurrence, the duration, cause (if known), and, where possible, the magnitude of any excess emissions.

(f) (7) Records demonstrating facility size . Facility size for determining the

applicable emission limitation in subsection 93102.4 (a) is determined by the maximum cumulative potential rectifier capacity. However, a facility with a maximum cumulative potential rectifier capacity of 60 million amp-hr/yr or more may, at the option of the owner or operator, be considered small or medium if the actual cumulative rectifier usage is less than 60 million amp-hr/yr as demonstrated by using either of the following procedures:

(1) (A) Annual actual cumulative rectifier capacity. Show by records

that the facility's previous annual actual cumulative rectifier capacity was less than 60 million amp-hr/yr, by using nonresettable ampere-hour meters and keeping monthly records of actual ampere-hour capacity for each 12-month rolling period following the compliance date. The actual cumulative rectifier capacity for the previous 12-month rolling period shall be tabulated monthly by adding the capacity for the current month to the capacities for the previous 11 months;

or34

(2) (B) Maximum cumulative potential rectifier usage limit. By

accepting a limit on the maximum cumulative potential rectifier usage of a hard chromium electroplating facility through a title V permit condition or a permitting agency operating permit condition and by maintaining monthly records in accordance

with subsection 93102.12(c)(1) (h) (4) (A) to demonstrate that

the limit has not been exceeded.

(g) Records of annual ampere-hour use. Facilities shall maintain

monthly records of total ampere-hour use per calendar year. The record shall be submitted to the permitting agency as part of their Initial and Ongoing Compliance Status Reports as specified in Appendix 2 and 3.

(h) (8) Records of chemical fume suppressant additions. For facilities

sources using chemical fume suppressants to comply with the standards or requirements , the owner or operator shall maintain records of the date, time, approximate volume, and product

identification of the chemical fume suppressants that are is added to the electroplating or anodizing bath.

(i) (9 ) Records of trivalent chromium process bath components. For

facilities sources complying with subsection 93102.6(a) (c)(3) using

the trivalent chromium e baths process , the owner or operator shall maintain records of the bath components purchased, with the wetting agent clearly identified as a bath constituent contained in one of the
components.

(j) (10 ) New/modified source review information. The owner or operator

shall maintain records supporting the notifications and reports required by the permitting agency's new source review provisions and/or subsection 93102.4(e) (j)

.

(k) Housekeeping records. The owner or operator shall maintain records

demonstrating compliance with housekeeping requirements, as required by section 93102.5, including the dates on which specific activities were completed, and records showing that chromium or chromium-containing wastes have been stored, disposed of, recovered, or recycled using practices that do not lead to fugitive dust

emissions.

(l) (11 ) Records retention. All records shall be maintained for five years, at

least two years on site.35

93102.13 ( i) Reporting Requirements.

(a) (1) Performance test documentation.

(1) (A) Notification of performance test.

(A) 1. The owner or operator of a facility source shall notify the permitting agency of his or her intention to conduct a performance test at least 60 calendar days before the performance test is scheduled.

(B) 2 . The provisions in subsection 93102.13(a)(1)(A) (i )(1)(A)1.

,

above, do not apply if the performance test was conducted prior to July 24, 1997, was used to demonstrate compliance with 93102.4(a) or 93102.6(a), and was approved by the permitting agency and the U.S. EPA.

(2) (B) Reports of performance test results. The owner or

operator shall report performance test results to the permitting agency. Reports of performance test results shall be submitted no later than 90 days following the completion of the required performance test, and shall be submitted as part of the notification of compliance status required by subpart (b) paragraph (2) of this subsection.

(3) (C) The content of performance test reports shall contain the

information is identified in Appendix 1.

(b) (2) Initial compliance status report. An initial compliance status report is

required each time that a facility source becomes subject to the requirements of this section. The owner or operator shall submit to the permitting agency an initial compliance status report, signed by the responsible official who shall certify its accuracy, attesting to whether the facility source has complied with this rule.

(1) (A) Initial compliance status report due date.

1

. For sources required to conduct a performance test, the initial compliance status report shall be submitted to the permitting agency no later than 90 calendar days following comple tion of the compliance demonstration.

2. For sources that are not required to complete a performance

test, the initial compliance status report shall be submitted to the permitting agency no later than 30 days after the effective36 date of this rule for existing facilities sources , or at start-up for

new facilities sources

.

(2) (B) The content of the initial compliance status report shall contain

the information is identified in Appendix 2.

(c) (3) Ongoing compliance status reports. The owner or operator shall

submit a summary report to the permitting agency to document the ongoing compliance status.

(1) (A) Frequency of o O ngoing compliance status reports

.

1. The report shall be submitted to the permitting agency on or before February 1 annually for major all facilities sources and shall include information for the preceding calendar year (January 1 through December 31)

.

2. The report shall be prepared annually and made available to the permitting agency upon request for area sour ces.

(2) (B) The content of ongoing compliance status reports shall include

the information is identified in Appendix 3.

(d) (4) Reports of breakdowns. The owner or operator shall report

breakdowns as required by the permitting agency's breakdown rule.

(e) (5) Reports associated with the trivalent chromium process baths using a wetting agent

.

(1) Facilities currently using the trivalent chromium process

.

(A) Owners or operators electroplating with the trivalent

chromium process baths using a wetting agent are not subject to subsections (a), (b), and (c) paragraphs (1) through (3) of this subsection 93102.13 , but must instead

shall submit to the permitting agency the following

information reports:

(A) Sources currently using trivale nt chromium. N n o later

than 30 days after the effective date of this rule: , the

owner or operator shall submit a notification of compliance

status that contains:

1. The name and address of each facility source subject to

this paragraph;37 2. A statement that a trivalent chromium process that

incorporates a wetting agent will be used to comply with these requirements; and

3. The list of bath components that comprise the trivalent

chromium bath, with the wetting agent clearly identified.

(B) An owner or operator electroplating with the trivalent

chromium process and complying with the emission limitation option in subsection 93102.6 (a) shall submit the information contained in subsections (a), (b), and (c) of this section 93102.13. The report shall be submitted in

accordance with the schedules identified in those paragraphs.

(2) (B) Facilities sources changing to the trivalent chromium e

process . Within 30 days of a change to the trivalent chromium electroplating process, the owner or operator shall submit to the permitting agency a report that includes:

(A) Facilities electroplating with the trivalent chromium process

using a wetting agent shall submit the following

information:

1. The name and address of each facility subject to this

paragraph; and

2. A statement that a trivalent chromium process that

incorporates a wetting agent will be used to comply with these requirements; and

3. The list of bath components that comprise the trivalent

chromium bath, with the wetting agent clearly identified;

and

4. 1. A description of the manner in which the process has

been changed. and the emission limitation, if any, now applicable to the source; and

(B) Facilities electroplating with the trivalent chromium process

and complying with the emission limitation option in 93102.6 (a) shall submit the information contained in subsections (a), (b), and (c) of this subsection 93102.13. The report shall be submitted in accordance with the schedules identified in those paragraphs.38 2. The notification and reporting requirements of paragraphs (1),

(2), and (3) of this subsection, if the source complies with the emission limitation option, or paragraph (5) of this subsection, if

the source uses a wettin g agent to comply. The report shall be

submitted in accordance with the schedules identified in those paragraphs.

(f) (6) Adjustments to the timeline for submittal and format of reports. A

permitting agency may adjust the timeline for submittal of periodic reports, allow consolidation of multiple reports into a single report, establish a common schedule for submittal or reports, or accept reports prepared to comply with other State or local requirements. Prior to allowing an adjustment, the permitting agency must find that the adjustment will provide the same information and will not alter the overall frequency of reporting.

(j) New and Modified Sources.

[Note: this subsection has been moved to section 93102.4 and has been modified.]

(1) Notif ication of Construction Reports. After the effective date of this rule no person may construct or modify a source, such that it becomes a source subject to this section, without submitting a notification of construction or modification to the permitting a gency and receiving approval in advance to construct or modify the source. The contents of the Notification of Construction Report is contained in Appendix 4.

(2) New Source Review Rules. In lieu of complying with the requirements in paragraph (j)(1) of this subsection, a facility may fulfill these requirements by complying with the permitting agency's new source review rule or policy, provided similar information is obtained.

93102.14 (k ) Procedure for Establishing Alternative Requirements.

(a) (1) Request Approval of an Alternative Requirement . Any person may request approval of an alternative requirement. The person seeking such approval shall submit the proposed alternative requirement to the permitting agency for approval. The request must include the proposed alternative requirement, the reason for requesting the alternative requirement, and information demonstrating that the criteria for approval identified in Table 93102.14 (k)(1) is are met.

(b) (2) Approval of an Alternative Requirement. A permitting agency may

approve an alternative requirement if it determines that application of the alternative requirement meets the criteria for approval identified in39 Table 93102.14 (k)(1) , and the permitting agency has received concurrence by the ARB and U.S. EPA where concurrence is required.

(c) (3) Concurrence for an Alternative Requirement. For those requirements

identified in Table 93102.14 (k)(1) as requiring concurrence by the

U.S. EPA and ARB , the permitting agency shall submit the alternative requirement to the concurring agency prior to final action by the permitting agency.

(d) ( 4 ) Reports of Approved Alternative Requirements to U.S. EPA . The

permitting agency shall provide the U.S. EPA and ARB with copies of all approved alternative requirements. The information shall be provided at a mutually agreed upon frequency.

(e) ( 5 ) Approval Criteria. Nothing in this section prohibits the permitting

agency from establishing approval criteria more stringent than that required in Table 93102.14 (k)(1)

.

(f) ( 6 ) Alternatives Approved by U.S. EPA. Waivers obtained from U.S.

EPA prior to the effective date [Effective Date] of this regulation shall remain in effect until the effective dates of the requirements in subsection 93102.4(b) become effective.

Table 93102.14 (k)(1) -- Requirements for Approval of Alternatives

Subsection Requirement Criteria for Approval Approving

Agency Concurring

Agency (4) (1)

(a)

93102.1 a A pplicability equivalent type and

size of facility

source regulated District U. S. EPA

(c)

93102.4 s tandards

Limits and requirements equivalent emission

reductions District U. S. EPA,

ARB

(d ) (1) 93102.7(a) p P erformance

test requirements equivalent means

of determining compliance District U. S. EPA

( d) (2) 93102.7(b) u U se of

previously

conducted existing performance

source tests O o verall existing

tests provide a

similar level of compliance

assurance District U. S. EPA

(d) (3) 93102.7(c) a A lternative

test method provides a similar

level of accuracy and precision District U. S. EPA

ARB (d ) (4) 93102.7(d) a A mendments

to the pre-test equivalent means

of determining District U. S. EPA40 protocol compliance (d) (5) 93102.7(e) t T est all

emission points equivalent means

of determining compliance District U. S. EPA

(e)

93102.9 p P arameter

monitoring equivalent means

of determining and assuring compliance District U. S. EPA

(f)

93102.10 i I nspection

maintenance requirements equivalent means

of assuring compliance District U. S. EPA

(g)

93102.11 o O peration and

maintenance plans equivalent means

of assuring compliance District U. S. EPA

( h) (1)( 10) 93102.12 (a) through (f) and (h) through (j) r R ecordkeeping equivalent means

of assuring compliance District U. S. EPA

(h) (11) 93102.12(l) r R etention of

records assure historical

records available for up to 5 years District U. S. EPA

(i)

93102.13 r R eporting equivalent means of assuring compliance District U. S. EPA

1. combined hexavalent or total chrome emissions from hard chrome plating operations

2. maximum cumulative potential rectifier capacity or usage li mit

3. "Option 2" is an alternative emission limitation for small and medium facilities that elect to demonstrate compliance with both a mg/amp

- hr and a mg/dscm requirement

4. 1. U.S. EPA or the implementing agency in accordance with any delegation of authority to approve alternatives from the U.S. EPA.

93102.15 Requirements Relating to Chromium Plating Kits.

(a) Except as provided in subsection (b), no person shall sell, supply,

offer for sale, or manufacture for sale in California, any chromium plating or chromic acid anodizing kit.

(b) The provisions of subsection (a) do not apply to any person that sells,

supplies, offers for sale, or manufactures for sale in California a chromium plating or chromic acid anodizing kit to the owner or operator of a permitted facility at which chromium plating or chromic acid anodizing is performed.

(c) No person shall use a chromium plating or chromic acid anodizing kit

to perform chromium electroplating or chromic acid anodizing unless41 these activities are performed at a permitted facility that complies with the requirements of this ATCM.

(d) For the purposes of this section, “chromium electroplating or chromic

acid anodizing kit” means chemicals and associated equipment for conducting chromium electroplating or chromic acid anodizing including, but not limited to, internal and external tank components.

93102.16 This section 93102.16 contains Appendices 1 through 8 to the

ATCM for Chromium Plating and Chromic Acid Anodizing Facilities.42

Appendix 1 - Content of Performance Test Reports

Performance test reports required by section 93102.13 shall contain the following

information:

1. A brief process description; 2. Sampling location description(s); 3. A description of sampling and analytical procedures and any modifications to standard procedures; 4. Test results in mg/amp-hr ; 5. Quality assurance procedures and results; 6. Records of operating conditions during the test, preparation of standards, and calibration procedures; 7. Original data for field sampling and field and laboratory analyses; 8. Documentation of calculations; and 9. Any other information required by the test method.

Note: Test reports consistent with the provisions of California Air Resources

Board ARB Method 425 will fulfill the above performance test report content requirement.43

Appendix 2 - Content of Initial Compliance Status Reports

Initial compliance status reports required by subsection 93102.13(b) shall contain the following information:

1. The applicable emission limitation and the methods that were used to

de termine compliance with this limitation;

2. If a performance test is required, the test report documenting the results of the performance test, which contains the elements listed in Appendix 1;

3. The type and quantity of hazardous air pollutants emitted by th e source reported in mg/dscm or mg/hr for decorative and anodizing operations. (If the owner or operator is subject to the construction and modification provisions of subsection (j) and had previously submitted emission estimates, the owner or operator sha ll state that this report corrects or verifies the previous estimate.) For sources not required to conduct a performance test, the surface tension measurement may fulfill this requirement;

4. For each monitored parameter for which a compliant value is to be established under subsection (e) the specific operating parameter value, or range of values, that corresponds to compliance with the applicable emission limit;

5. The methods that will be used to determine continuous compliance, including a description of mo nitoring and reporting requirements, if methods differ from those identified in this section;

6. A description of the air pollution control technique for each emission point;

7. A statement that the owner or operator has completed and has on file the operation and maintenance plan as required by subsection (g);

1. Company Information: Facility name, address, owner/operator name, telephone number, the measured distance from the edge of the facility that is nearest to the sensitive receptor to the property boundary of the sensitive receptor that is within 150 meters;

2. The applicable requirements from section 93102.4 and the methods that were used to determine compliance. A description of the air pollution control technique for each emission point;

3. If a facility is using add-on controls to comply provide the following:

a) Description of add-on controls and a performance test report documenting the results of the performance test, which contains the elements listed in Appendix 1;44

b) The actual hexavalent chromium emissions of the facility in pounds peryear calculated by multiplying the emission rate with the actual amperehours for the preceding calendar year.

c) For monitored parameters 93102.9 (b) and (c), the specific operating parameter value, or range of values, that corresponds to compliance with the applicable emission limit;

d) A statement that the owner or operator has completed and has on file the operation and maintenance plan as required by subdivision (j);

4. If a facility is using in-tank controls to comply, provide the following:

a) Description of in-tank controls including name of in tank controls, name of chemical fume suppressant, surface tension of the electroplating or anodizing bath;

b) For monitored parameters 93102.9 (d), (e), and (f) the specific operating parameter value where applicable, or range of values, that corresponds to compliance;

5. The actual cumulative ampere-hour usage expended during the preceding calendar year.

6. 8. If the owner or operator is determining facility size based on actual cumulative rectifier usage, records to support that the facility is small or medium. For existing facilities sources , records from any 12-month period preceding the compliance date shall be used or a description of how operations will change to meet a small or medium designation shall be provided. For new facilities sources , records of projected rectifier usage for the first 12-month period of tank operation shall be used;

7. A statement that the owner or operator, or personnel designated by the owner or operator, has completed Environmental Compliance Training pursuant to 93102.5 (b).

8. 9. A statement by the owner or operator as to whether the facilities source has complied with the provisions of this sections 93102 through 93102.16.45

Appendix 3 - Content of Ongoing Compliance Status Reports

Ongoing compliance status reports required by section 93102.13(c) shall contain the following information:

1. The company name and address of the source ; 1. Company Information: facility name, address, owner/operator name, telephone number, the measured distance from the edge of the facility that is nearest to the sensitive receptor to the property boundary of the sensitive receptor that is within 150 meters

2. An identif ication of the operating parameter that is monitored for compliance determination, as required by subsection (e);

3. 2. The relevant emission limitation requirements for the facility source

, and the operating parameter value, or range of values, that correspond to compliance with this emission limitation as specified in the notification of initial compliance status required by Appendix 2;

4. The beginning and ending dates of the reporting period;

5. A description of the type of process performed in the source;

6. 3 . The actual cumulative rectifier ampere-hour

usage expended during the reporting period, on a month-by-month basis, for the reporting period January 1 through December 31; if the source is a hard chromium electroplating tank ; 4. The actual hexavalent chromium emissions of the facility during the reporting period in pounds per year calculated by multiplying the emission rate with the actual ampere-hour usage for the reporting period;

7. 5. A summary of any excess emissions or exceeded monitoring parameters as identified in the records required by subsection (h)(6) 93102.12(e) ; 8. 6. A certification by a responsible official that the inspection and maintenance requirements in sub section 93102.10 (f) were followed in accordance with the operation and maintenance plan for the facility

source ; 9. 7. If the operation and maintenance plan required by sub section

93102.11 (g) was not followed, an explanation of the reasons for not following the provisions, an assessment of whether any excess emissions and/or monitoring parameter excesses are believed to have occurred, and a copy of the record(s) required by subsection 93102.12(a) (h)(1) documenting that the operation and maintenance plan was not followed;

10. 8. A description of any changes in monitoring, processes, or controls since the last reporting period;

9. A statement that the owner or operator, or personnel designated by the owner or operator, has, within the last 2 years, completed Environmental Compliance Training pursuant to 93102.5(b)46

11. 10. The name, title, and signature of the responsible official who is certifying the accuracy of the report; and

12. 11. The date of the report.

Appendix 4 - Notification of Construction Reports

Notification of Construction Reports required by subsection 93102.4(e) shall contain the following information:

1. A. The owner or operator's name, title, and address;

2. B

. The address (i.e., physical location) or proposed address of the

facility source if different from the owner's or operator's;

3. C. A notification of intention to construct a new facility source and

certification that all of the criteria specified in subsection 93102.4 (d) are met.

4. A notification of intention to or make any physical or operational changes to a facility source that may meet or has been determined to meet the criteria for a modification;

5. D

. The expected commencement and completion dates of the

construction or modification;

6. E

. The anticipated date of (initial) startup of the facility source ;
7. F

. The type of process operation to be performed (hard or decorative

chromium electroplating, or chromic acid anodizing);

8. G

. A description of the air pollution control technique to be used to

control emissions, such as preliminary design drawings and design capacity if an add-on air pollution control device is used; and

9. H

. An estimate of emissions from the facility source based on

engineering calculations and vendor information on control device efficiency, expressed in units consistent with the emission limits of this subpart. Calculations of emission estimates should be in sufficient detail to permit assessment of the validity of the

calculations.

Note: A facility can fulfill these report content requirements by complying with the permitting agency's new source review rule or policy, provided similar information is obtained.47

Appendix 5 - Smoke Test for Chromium Tank Covers

SMOKE TEST TO VERIFY THE SEAL INTEGRITY OF COVERS DESIGNED

TO REDUCE CHROMIUM EMISSIONS FROM ELECTROPLATING AND

ANODIZING TANKS

1. Applicability and Principle

2. 1.1 Applicability. This alternative method is applicable to all hard chromium

electroplating and anodizing operations where a chromium tank cover is used on the tank for reducing chromium emissions.

3. 1.2 Principle. During chromium electroplating or anodizing operations,

bubbles of hydrogen and oxygen gas generated during the process rise to the surface of the tank liquid and burst. Upon bursting, tiny droplets of chromic acid (chromium mist) become entrained in the air above the tank. Because the chromium tank cover completely encloses the air above the tank, the chromium mist either falls back into the solution because of gravity or collects on the inside walls of the chromium tank cover and runs back into the solution. A semi-permeable membrane allows passage of the hydrogen and oxygen out of the chromium tank cover. A lit smoke device is placed inside the chromium tank cover to detect leaks at the membrane, joints, or seals.

3. 2. Apparatus

4. 2.1 Smoke device. Adequate to generate 500 to 1000 ft 3 of smoke/20 ft 2 of

tank surface area (e.g., Model #1A=15 SECONDS from Superior Signal, New York).

5. 2.2 Small container. To hold the smoke device.

6. 3. Procedure

Place the small container on a stable and flat area at center of the chromium tank cover (you can use a board and place it on the buss bars). Place the smoke device inside the container. After lighting the smoke device, quickly close the access door to avoid smoke from escaping. Let smoke device completely burn; entire space under the

chromium tank cover will now be filled with the smoke. Observe for leaks of smoke from each seal, joint, and membrane of the chromium tank cover. Record these observations including the locations and a qualitative assessment of any leaks of smoke.

When all seals, joints, and membranes have been observed, evacuate

the unit to remove the smoke from the chromium tank cover.48

Appendix 6 - Air Pollution Control or Air Quality Management District

Breakdown Rules.

DISTRICT RULE # RULE NAME
Amador 516 Upset and Breakdown Conditions
Antelope 430 Breakdown Provisions
Bay Area 1 General Provisions and Definitions
Butte 275 Reporting Procedures for Excess Emissions
Calaveras 516 Upset and Breakdown Conditions
Colusa 1.13 Equipment Breakdown
El Dorado 516 Upset and Breakdown Conditions

Feather

River 9.6 Equipment Breakdown

Glenn 95.2 Malfunction of Equipment

Great Basin 403 Breakdown
Imperial 111 Equipment Breakdown
Kern 111 Equipment Breakdown
Lake Chapter

III, Article

II Malfunction

Lassen 2:15 Equipment Breakdown
Mariposa 516 Upset and Breakdown Conditions

Mendocino R1-5-540 Equipment Breakdown
Modoc 2.12 Equipment Breakdown
Mojave 430 Breakdown Provisions
Monterey Bay 214 Breakdown Condition

North Coast 3-4-540 Breakdown and Violation Reporting

North Coast 1-5-540 Equipment Breakdown

Northern

Sierra 516 Upset and Breakdown Conditions

Northern

Sonoma 1-5-540 Equipment Breakdown

Placer 404 Upset Conditions Breakdown. Scheduled

Maintenance

Sacramento 602 Breakdown Conditions: Emergency Variance
San Diego 98 Breakdown Conditions: Emergency Variance

San Joaquin 110 Equipment Breakdown

San Luis Obispo 107 Breakdown or Upset Conditions and Emergency Variances49

Santa

Barbara 505 Breakdown Conditions

Santa

Barbara 506 Emergency Variances for Breakdowns

Shasta 3:10 Excess Emissions
Siskiyou 2.12 Equipment Breakdown (Siskiyou)

South

Coast 430 Breakdown Provisions

Tehama 4:17 Upset or Breakdown Conditions
Tuolumne 516 Upset and Breakdown Conditions
Ventura 32 Breakdown conditions; Emergency Variances

Yolo

Solano 5.2 Upset/Breakdown Conditions: Emergency

Variance50

Appendix 7 – Alternative Requirements for Enclosed Hexavalent Chromium Electroplating Facilities – Mass Emission Rate Calculation Procedure

Mass Emission Rate Should be calculated using the following equation:

MAMER = ETSA x K x 0.015 mg/dscm

Where:

MAMER = the alternative emission rate for enclosed hexavalent chromium electroplating tanks in mg/hr.

ETSA = the hexavalent chromium electroplating tank surface area in square feet(ft 2 ).

K = a conversion factor, 425 dscm/(ft 2 x hr).51

Appendix 8 – Surface Tension Procedure for a Stalagmometer

The stalagmometer must first be properly cleaned before being used for the first time and after a period of storage. Properly clean the stalagmometer using the following procedure:

1. Set up stalagmometer in stand in a fume hood.

2. Place a clean 150 mL beaker underneath the stalagmometer then fill with reagent grade concentrated nitric acid. Immerse bottom tip (approximately 1⁄2 “) of stalagmometer into the beaker.

3. Squeeze rubber bulb and pinch at the arrow up (1) position to collapse. Place bulb end securely on top end of stalagmometer. Carefully draw the nitric acid by pinching the arrow up (1) position until the level is above the top etched line.

4. Allow nitric acid to remain in stalagmometer for 5 minutes and then carefully remove the bulb allowing the acid to completely drain.

5. Fill a clean 150 mL beaker with distilled or deionized water. Using the rubber bulb per the instructions in Step #3, rinse and drain stalagmometer

with deionized or distilled water until the inside is “water break” free.

6. Fill a clean 150 mL beaker with alcohol. Again using the rubber bulb per Step #3, rinse and drain stalagmometer twice with alcohol and allow the stalagmometer to dry completely.

7. Take a sample of the solution to be tested and adjust the solution to room temperature. Measure the specific gravity and record reading.

8. Fill a clean 150 mL beaker with solution to be tested. Immerse bottom end of stalagmometer into the beaker. Fill the stag per instructions in Step #3, making sure that the solution level is above the top etched line.

9. Raise the stalagmometer so that the bottom end is completely out of solution. Remove bulb and immediately place a finger on the top end of the stalagmometer. Carefully use the finger to bring the solution level down to the top etched line. Do not release finger at this time.

10. “Wipe” the excess solution on the lower tip by touching it against the

side of the beaker.

11. Release fingertip to allow solution to drain and count number of drops

until the level reaches the bottom etched line.52 Calculations for Surface Tension

Surface tension (dynes/cm) = Sw * Nw * D

N * Dw

Sw = Surface tension of water at 25 o C or 77 o F (72.75 dynes/cm) Nw = water drop number etched on instrument D = measured specific gravity (g/ml) N = # of solution drops Dw = water density (1.0 g/mL)

PRECAUTIONS:

1. Make sure they stalagmometer is clean (no sludge or film) 2. No chips, cracks, etc 3. Vertical placement

4. No vibration 5. 20 drops per minute rate (10 dynes/cm)

6. Performance checked with water 7. Sample at room temperature

NOTE: Authority cited: sections 39600, 39601, 39650, 39658, 39659 , 39666, and 41511

, Health and Safety Code. Reference: sections 39650, 39658, 39659 , 39665, 39666, and 41511

, Health and Safety Code; and 40 CFR Part 63 Subpart N.

## Appendix B

Chronology of Meetings1 

## Appendix B Chronology of Meetings

Date Meeting

January 29, 2002 Diamond Bar Stakeholder Workgroup July 2, 2002 Conference call with California Air Districts
October 8, 2002 Conference call with California Air Districts
October 16, 2002 Meeting with Chemical Manufacturer
November 22, 2002 El Monte Stakeholder Workgroup
November 25, 2002 San Francisco Stakeholder Workgroup
December 17, 2002 Fresno Stakeholder Workgroup

October, 28, 2003 Conference call with Metal Finishing Association of

Southern California
November 13, 2003 Conference call with the Northern California Metal Finishing Association November 18, 2003 Conference call with California Air Districts
December 9, 2003 Fresno Stakeholder Workgroup
December 10, 2003 San Francisco Stakeholder Workgroup
December 11, 2003 El Monte Stakeholder Workgroup January 12, 2004 Conference call with California Air Districts November, 7, 2005 Meeting with SCAQMD staff in Diamond Bar
November 16, 2005 Conference call with California Air Districts January, 2006 Conference calls with Chemical Manufacturers April 13, 2006 Conference call with California Air Districts

May 3, 2006 Conference call with Metal Finishing Association of

Southern California May 10, 2006 Northern California Chrome Stakeholder Workgroup May 12, 2006 El Monte Stakeholder Workgroup
June 8, 2006 Environmental Stakeholder Teleconference
June 22, 2006 California Air Districts Teleconference
June 26, 2006 Chrome-plating Industry Teleconference
June 27, 2006 Diamond Bar Public Workshop
June 30, 2006 Northern California Chrome Public Workshop

## Appendix F

Results of Emission Testing ProgramPhase I – Test 1 & 2 Facility 1

1 Table VI-1 Sigma Plating Company, Inc. Hoist Line Decorative Chromium Plating Tank

Sampling Dates – January 9, 10, & 17, 2003

Sampling Location Plating Tank Exhaust
Sample Number SI-02 SI-03 SI-07 Sampling Date 1/9/2003 1/10/2003 1/17/2003

Plating Tank Data Totalizer (amp-hours) 12,468 9,080 4,634 Production Rate (amp-hrs/hr) 2,078 1,892 1,655

Stack Data
Temperature ( 0 F) 69 63 67 Velocity (ft/sec) 57 53 58
Static Pressure ("H 2 0) -4.4 -4.4 -4.4
Stack Area (sq. ft.) 0.994 0.994 0.994
Flow Rate (DSCFM) 3300 3100 3400
Moisture (% of v/v) 0.7 0.9 0.1

Sampling Data
Sampling Time (minutes) 360 288 168 Sample Volume (DSCF) 428.10 326.64 191.63 Chromium Data (ng/sample)

Total Chromium 3.5E+6 2.8E+6 1.9E+5

Hexavalent Chromium 1.4E+6 6.8E+5 7.8E+4
Isokinetic Rate (%) 104 106 98

EMISSIONS Concentration (ng/dscf)

Total Chromium 8.2E+3 8.6E+3 1.0E+3

Hexavalent Chromium 3.3E+3 2.1E+3 4.1E+3 Emission Rate (mg/hr)

Total Chromium 1600 1600 210

Hexavalent Chromium 660 390 83

Emissions Factors (mg/amp-hr) 1

Total Chromium 0.77 0.85 0.13

Hexavalent Chromium 0.32 0.21 0.05

DSCF means dry standard cubic feet. Standard conditions are 68 F and 29.92 inches Hg. DSCFM means dry standard cubic feet per minute.

1 Emissions Factors (mg/amp-hr) = Emission Rate (mg/hr) / Plating Tank Production Rate (amp-hrs/hr)Phase I – Test 1 & 2 Facility 1

2 Table VI-2 Sigma Plating Company, Inc. Hoist Line Decorative Chromium Plating Tank Mist Eliminator Sampling Dates – January 14, 15, & 16, 2003 Sampling Location Upstream

of Mist

Eliminator Downstream

of Mist

Eliminator Upstream

of Mist

Eliminator Downstream

of Mist

Eliminator Upstream

of Mist

Eliminator Downstream

of Mist

Eliminator

Test Number SI-04 1 SO-04 3 SI-05 SO-05 SI-06 SO-06 Sampling Date 1/14/2003 1/15/2003 1/16/2003

Plating Tank Data
Totalizer (amp-hrs) 6,059 3 8,874 9,002 Production Rate (amp-hrs/hr) 1,010 1,479 1,500

Stack Data

Temperature ( 0 F) 69 67 72 72 76 72
Velocity (ft/sec) 59 66 59 65 59 61
Static Pressure ("H 2 0) -4.4 -7.4 -4.4 -7.4 -4.4 -7.4

Stack Area (sq. ft.) 0.994 0.994 0.994 0.994 0.994 0.994
Flow Rate (DSCFM) 3400 3800 3400 3700 3400 3500
Moisture (% of v/v) 1.0 1.0 0.6 0.8 0.2 0.5

Sampling Data

Sampling Time (minutes) 360 360 360 360 360 360 Sample Volume (DSCF) 238.39 280.24 253.58 273.84 249.54 257.45 Chromuim Data (ng/sample)

Total Chromium 2.1E+6 2.4E+3 4.2E+4 7.0E+3 5.9E+3 5.5E+3

Hexavalent Chromium 9.5E+5 2.5+E3 2.9E+4 5.6E+3 3.2E+3 4.2E+3 Isokinetic Rate (%) 100.1 106.4 106.1 105.3 105.3 105.0

EMISSIONS Concentration (ng/dscf)

Total Chromium 8600 8.7 170 26 24 21

Hexavalent Chromium 4000 9.1 120 20 13 16 Emission Rate (mg/hr )

Total Chromium 1800 2.0 34 5.7 4.8 4.5

Hexavalent Chromium 820 2.1 24 4.6 2.6 3.5

Mist Eliminator Control Efficiency (%) 2

Total Chromium 99.9 83.2 6.3

Hexavalent Chromium 99.7 80.8

-- 3

Emission Factor (mg/amphr) 4

Total Chromium 1.78 2.0E-3 2.3E-2 3.9E-3 3.2E-3 3.0E-3

Hexavalent Chromium 0.81 2.1E-3 1.6E-2 3.1E-3 1.7E-3 2.3E-3
DSCF means dry standard cubic feet. Standard conditions are 68 F and 29.92 inches Hg. DSCFM means dry standard cubic feet per minute. 1 Hoist line operations were suspended for ~4 hours during Run 04. Emissions sampling runs were suspended for 2 of the 4 hours.

2 Efficiency = [(Inlet, SI – Outlet, SO) / Inlet, SI] * 100 3 Efficiency could not be calculated

4 Emissions Factors (mg/amp-hr) = Emission Rate (mg/hr) / Plating Tank Production Rate (amp-hrs/hr)Phase I – Test 1 & 2 Facility 1

3Phase I – Test 1 & 2 Facility 1

4 Table VI-3 Sigma Plating Company, Inc. Hoist Line Indoor Ambient Metals Sampling Dates – January 8 - 10 & 14 – 16, 2003

Sampling Dates 1/8/2003* 1/9/2003 1/10/2003 1/14/2003 1/15/2003 1/16/2003 Metals (ng/m 3 )

Total Chromium 1,836 131 391 346 285 157 Manganese 68 19 52 71 110 45

Iron 10,430 2,153 4,164 7,099 15,127 3,134

Nickel 3,090 271 695 1,010 1,243 430

Cobalt 1.8 <1 1.6 2 1.9 1.2 Copper 253 55 155 268 192 125

Zinc 472 80 231 395 320 146

Arsenic 1.1 <1 <1 2.2 1.9 <1

Strontium 23 5.3 19 22 23 14 Molybdenum 1.8 <1 2.1 3.9 25 3.2

Tin 44 5.3 11 16 11 30 Antimony 7.2 1.8 7.5 11 15 8

Lead 811 42 122 126 67 47

* January 8 was windy and dusty which may account for the higher

concentrations.Phase I – Test 3 Facility 2

5Phase I – Test 3 Facility 2

6Phase I – Test 4 Facility 3

7Phase I – Test 4 Facility 3

8 

### Table VI-II
Van Nuys Plating Company, Inc.
Indoor, Ambient Hexavalent Chromium Levels

Sample Number V-2A V-3A V-4A V-5A V-6A
Sample Date 4/9/2003 4/9/2003 4/10/2003 4/10/2003 4/11/2003

Sampling Time (minutes) 77 123 400 396 328
Volume Collected (Liters) 791.4 1264.1 4130.7 4128.6 3387.2

Cr (VI) collected (nanograms) 3.0 9.4 15.2 0.7 13.7

Concentration (ng/m^3) 3.8 7.4 3.7 0.7 4.1
Daily averages 5.6 2.2 4.1Phase II – Test 1 & 2 Facility 4

9 Table VI-1 Alta Plating Decorative Chromium Plating Tank Sampling Dates – January 27-29 & February 2-4, 2004

Sampling Location 40 dynes/cm Surface Tension 30 dynes/cm Surface Tension

Sample Number A-11 A-12 A-13 A-21 A-22 A-23
Sampling Date 1/27/2004 1/28/2004 1/29/2004 2/2/2004 2/3/2004 2/4/2004

Plating Tank Data
Totalizer (amp-hours) 183 537 393 390 382 383
Production Rate (amp-hrs/hr) 30.5 67.1 65.5 65.0 63.7 63.8

Freeboard (inches to overflow) * 5.8 -.4.5 4.0 - 4.2 4.0 - 4.0 4.75 - 5.0 4.0 - 4.5 4.5 - 4.9

Surface Tension (dynes/cm) * 39.3 – 39.9 40.7 – 39.3 40.1 – 39.7 30.8 – 28.9 30.5 – 28.9 29.2 – 28.4

Chromic Acid Conc. (oz/gal) 37.7 34.3 35.9 35.1 34.5 34.6

Bath Temperature ( o F) 110 110 109 104 109 109

Stack Data

Stack Temperature ( 0 F) 63 62 61 62 62 61

Velocity (ft/sec) 23 21 21 21 20 21

Static Pressure ("H 2 0) -0.28 -0.25 -0.25 -0.27 -0.25 -0.26

Stack Area (sq. ft.) 0.785 0.785 0.785 0.785 0.785 0.785

Flow Rate (DSCFM) 1102 983 984 972 958 982

Moisture (% of v/v) 1.0 1.0 0.9 1.0 1.2 1.0

Sampling Data

Sampling Time (minutes) 360 480 360 360 360 360
Sample Volume (DSCF) 390.14 485.60 378.17 353.49 349.45 359.83
Chromium Data (ng/sample)

Total Chromium 3110 4810 5220 1450 2860 1520

Hexavalent Chromium 2250 3330 3840 1113 2462 980

Isokinetic Rate (%) 101 105 109 103 104 104

EMISSIONS
Concentration (ng/dscf)

Total Chromium 7.97 9.90 13.8 4.10 8.18 4.23

Hexavalent Chromium 5.77 6.86 10.2 3.15 7.05 2.72
Emission Rate (mg/hr)

Total Chromium 0.53 0.58 0.82 0.24 0.47 0.25

Hexavalent Chromium 0.38 0.41 0.60 0.18 0.41 0.16

Emissions Factors (mg/amp-hr)**

Total Chromium 0.017 0.009 0.012 0.004 0.007 0.004

Hexavalent Chromium 0.012 0.006 0.009 0.003 0.006 0.003

DSCF & DSCFM means dry standard cubic feet and dry standard cubic feet per minute at 68 F and 29.92 inches Hg.

* Paired numbers show "start " - "end" of sample run results (i.e. Run A-11 started at 5.8 in. & 39.3 dyne/cm).Phase II – Test 1 & 2 Facility 4

10 ** Emissions Factors (mg/amp-hr) = Emission Rate (mg/hr) / Plating Tank Production Rate (amp-hrs/hr)

Sample Number: A-11-A A-12-A A-13-A Sample Date: 1/27/2004 1/28/2004 1/29/2004

Sampling Time (minutes) 226 422 310 Volume Collected (liters) 2260 4220 3100

Cr (VI) collected (nanograms) 160 120 32

Indoor Ambient Concentration (ng/m 3 ) 70 28 10

Sample Number: A-21-A A-22-A A-23-A Sample Date: 2/2/2004 2/3/2004 2/4/2004

Sampling Time (minutes) 353 313 350 Volume Collected (liters) 3530 3130 3500

Cr (VI) collected (nanograms) 63 50 33

Indoor Ambient Concentration (ng/m 3 ) 18 16 9.3 Table VI-2b Alta Plating Company

Indoor Ambient Hexavalent Chromium

30 dyne/cm Surface Tension

Table VI-2a Alta Plating Company

Indoor Ambient Hexavalent Chromium

40 dyne/cm Surface TensionPhase II – Test 1 & 2 Facility 4

11 Background Indoor Ambient Sampling Results: Facility 4

Sample Number: A-33-A A-32-A A-31-A** A-30-A Sample Date: 2/5/2004 2/6/2004 2/8/2004 2/9/2004

Sampling Time (minutes) 339 450 1747** 368 Volume Collected (liters) 3390 4500 17470 3680

Cr (VI) collected (nanograms) 270 190 69 210

Totalizer, amp-hours 130 182 ** 172

Indoor Ambient Concentration (ng/m 3 ) 79 41 3.9 57

* - These indoor ambient samples were collected after emissions sampling of the plating tank was completed and the plating tank capture hood removed.

** - Sample A-31-A was collected on a Sunday when Alta was not plating. However, the sampler failed to shut off automatically. It was shut down manually at 8:00 am Monday - after Alta began plating.

Ambient Results with Plating Tank Capture Hood Removed*

Table VI-2c Alta Plating Company

Indoor Ambient Hexavalent ChromiumPhase II – Test 3 Facility 5

12 Table VI-1 Sherm's Custom Plating Decorative Chromium Plating Tank Results Sampling Dates--March 9, 10, & 11, 2004 Sampling Location Chromium Plating tank Chromium

Plating tank Chromium

Plating tank Sample Date March 9, 2004 March 10, 2004 March 11, 2004 Sample Number S-1 S-2 S-3 Plating Tank Data Totalizer (amp-hours) 415 459 425 Production Rate (amp-hrs/hr) 69.2 76.5 81.7 Freeboard (inches to overflow)* 5.0-4.9 3.0-3.5 4.0-4.0 Chromic Acid Conc. (oz/gal) 34.2 32.6 Not Done Temperature (oF) 109.5 109.8 109.8 Surface Tension (dynes/cm)* 35.6-35.9 37.5-35.9 37.8-37.9

Stack Data Stack Temp. (oF) 75 75 72 Velocity (ft/sec) 19.49 22.19 20.33 Static Pressure ("H 2 O) -0.23 -0.29 -0.19 Stack Area (sq. ft.) 0.785 0.785 0.785 Flow Rate (DSCFM) 904 1030 943 Moisture (% of v/v) 1.1 0.6 1.0 Sampling Data Sampling Time (minutes) 360 360 312 Sampling Volume (DSCF) 330.08 360.50 295.40 Chromium Data (ng/sample)

Total Chromium 19,440 22,600 22,730

Hexavalent Chromium 19,413 21,490 23,693 Isokinetic Ratio(%) 103.9 99.6 102.9

EMISSIONS

Concentration (ng/DSCF)

Total Chromium 58.89 62.69 76.95

Hexavalent Chromium 58.81 59.61 80.21 Emission Rate (mg/hr)

Total Chromium 3.19 3.87 4.35

Hexavalent Chromium 3.19 3.68 4.54

Emission Factors (mg/amp-hr) **

Total Chromium 0.046 0.051 0.053

Hexavalent Chromium 0.046 0.048 0.056
DSCF means dry standard cubic feet at 68oF and 29.92" Hg. DSCFM means dry standard cubic feet per minute. *Paired values separated by a hyphen are "start-end" of day measurements.

**Emission Factor = Emission rate/Production rate.Phase II – Test 3 Facility 5

13 Table VI-2a Sherm's Custom Plating Indoor (PQ-100) Ambient Hexavalent Chromium Sampling Results

Ambient sampling during source testing with the hood in place

Sample Number: S1-A S2-A S3-A

Sample Date: 03/09/2004 03/10/2004 03/11/2004

Sampling Time (minutes) 300 335 300*

Volume Collected (liters) 3000 3350 3000

Cr (VI) Collected (nanograms) 200 130 190

Indoor Ambient Concentration (ng/m 3 ) 67 39 65

* Note: Difference between the annotated start and stop time does not equal 300 minutes. It is assumed the start time was written incorrectly since the sampling interval is read directly from the PQ-100.

Background Indoor Ambient Sampling Results: Facility 5

Table VI-2b Sherm's Custom Plating Indoor (PQ-100) Ambient Hexavalent Chromium Sampling Results

Ambient sampling after source testing with the hood removed

Sample Number: S11-A S12-A S13-A

Sample Date: 03/19/2004 03/20/2004 03/21/2004

Sampling Time (minutes) 393 417 340

Volume Collected (liters) 3930 4170 3400

Cr (VI) Collected (nanograms) 390 870 410

Indoor Ambient Concentration (ng/m 3 ) 100 210 120Phase II – Test 4 Facility 6

14 Table VI-2 Clovis Specialty Decorative Chromium Plating Tank Test Week 2 (Clovis2)

Sampling Dates – October 19-21, 2004

Sampling Location

Sample Number C21 C22 C23 Sampling Date 10/19/04 10/20/04 10/21/04

Plating Tank Data Totalizer (amp-hours) 331 382 360 Production Rate (amp-hrs/hr) 159 191 180
Freeboard (inches to overflow) * 4.375 4.875 4.375

Surface Tension (dynes/cm) 44.1 41.6 42.2

Chromic Acid Conc. (oz/gal) 30.2 30.2 30.2

Bath Temperature ( o F) 106 110 112

Stack Data

Stack Temperature ( 0 F) 68 67 63
Velocity (ft/sec) 20.68 20.40 19.84 Static Pressure ("H 2 0) -0.22 -0.22 -0.24

Stack Area (sq. ft.) 0.785 0.785 0.785
Flow Rate (DSCFM) 945 931 922
Moisture (% of v/v) 1.3 1.3 1.1

Sampling Data

Sampling Time (minutes) 125 120 120 Sample Volume (DSCF) 118.65 111.03 111.23 Chromium Data (ng/sample)

Total Chromium 20,990 12,960 18,670

Hexavalent Chromium 21,800 11,280 20,570
Isokinetic Rate (%) 102.9 101.9 103.1

EMISSIONS Concentration (ng/dscf)

Total Chromium 177 117 168

Hexavalent Chromium 184 102 185 Emission Rate (mg/hr)

Total Chromium 10.0 6.5 9.3

Hexavalent Chromium 10.4 5.7 10.2

Emissions Factors (mg/amp-hr)**

Total Chromium 0.063 0.034 0.052

Hexavalent Chromium 0.065 0.030 0.057

DSCF & DSCFM means dry standard cubic feet and dry standard cubic feet per minute at 68 F and 29.92 inches Hg.

* Measured at the start of the plating day.

** Emissions Factors (mg/amp-hr) = Emission Rate (mg/hr) / Plating Tank Production Rate (amp-hrs/hr)Phase II – Test 4 Facility 6

15 Background Indoor Ambient Sampling Results: Facility 6

Sample Number: C4-A C5-A C6-A C7-A Sample Date: 6/1/2004 6/2/2004 6/3/2004 6/4/2004

Sampling Time (minutes) 1,403 1,317 1,115 470 Volume Collected (liters) 14,030 13,068 11,150 4,653

Plating Tank Amp-hours 1 72 22 51

Cr (VI) collected (nanograms) 1700 3600 1500 2100

Indoor Ambient Concentration (ng/m 3 ) 120 280 130 460 (without Capture Hood) Table A1-1b Clovis Specialty

Indoor Ambient Hexavalent ChromiumPhase II – Test 4 Facility 6

16 Table A2-1a Clovis Specialty Plating – Test Week 2 Indoor (PQ-100) Ambient Hexavalent Chromium Sampling Results

(Ambient sampling on rectifier during source testing with capture hood in place.)

Sample Number: C20-RA C21-RA C22-RA C23-RA

Sample Date: 10/18/04 10/19/04 10/20/04 10/21/04

Sampling Time (minutes) 196 308 143 132

Volume Sampled (liters) 1960 3080 1430 1320

Cr (VI) Collected (ng/sample) 300 5000 470 1800

Indoor Ambient Concentration (ng/m 3 ) 150 1600 330 1300
This rectifier is next to the plating tank, but outside the source test capture hood.

Table A2-1b Clovis Specialty Plating – Test Week 2 Indoor (PQ-100) Ambient Hexavalent Chromium Sampling Results

(2 nd parallel ambient sampling during source testing with capture hood in place.)

Sample Number: C20-CA C21-CA C22-CA C23-CA

Sample Date: 10/18/04 10/19/04 10/20/04 10/21/04

Sampling Time (minutes) 188 308 139 **

Volume Sampled (liters) 1880 3050 1380 **

Cr (VI) Collected (ng/sample) 270 1700 700 810

Indoor Ambient Concentration (ng/m 3 ) 150 560 510 **
CA samples parallel RA samples above - away from the tank and rectifier, but in the same room. RA samples were collected at the same location as Week 1 indoor samples.

** Air Volume data not recorded. Indoor concentration can not be calculated.Phase II – Test 5 Facility 6

17 Table VI-3 Clovis Specialty Decorative Chromium Plating Tank Test Week 3 (Clovis 3)

Sampling Dates – May 24-25, 2005

Sampling Location

Sample Number C31 C32 C33 Sampling Date 5/24/05 5/25/05 AM 5/25/05 PM

Plating Tank Data Totalizer (amp-hours) 385 309 316 Production Rate (amp-hrs/hr) 192.5 154.5 158
Freeboard (inches to overflow) * 5 5/8 5 5/8 5 5/8

Surface Tension (dynes/cm) 36.6 32.7 22.1 (fume suppressant added before sampling) Chromic Acid Conc. (oz/gal) 25.0 25.0 25.0

Bath Temperature ( o F) 108 110 110

Stack Data

Stack Temperature ( 0 F) 91 86 92
Velocity (ft/sec) 19.8 18.6 18.9
Static Pressure ("H 2 0) -0.20 -0.21 -0.20

Stack Area (sq. ft.) 0.785 0.785 0.785
Flow Rate (DSCFM) 871 828 836
Moisture (% of v/v) 1.2 1.0 0.7

Sampling Data

Sampling Time (minutes) 120 120 120 Sample Volume (DSCF) 103 96.9 97.8 Chromium Data (ng/sample)

Total Chromium 19,800 14,284 18,390

Hexavalent Chromium 19,690 13,284 18,100 Isokinetic Rate (%) 101.2 100.0 99.8

EMISSIONS Concentration (ng/dscf)

Total Chromium 192 147 188

Hexavalent Chromium 191 137 185 Emission Rate (mg/hr)

Total Chromium 10 7.3 9.4

Hexavalent Chromium 10 6.8 9.3

Emissions Factors (mg/amp-hr)**

Total Chromium 0.052 0.047 0.059

Hexavalent Chromium 0.052 0.044 0.059

DSCF & DSCFM means dry standard cubic feet and dry standard cubic feet per minute at 68 F and 29.92 inches Hg.

* Measured at the start of the plating day.

** Emissions Factors (mg/amp-hr) = Emission Rate (mg/hr) / Plating Tank Production Rate (amp-hrs/hr)Phase II – Test 5 Facility 6

18 Table A3-1a Clovis Specialty Plating – Test Week 3 Indoor (PQ-100) Ambient Hexavalent Chromium Sampling Results

(Ambient indoor sampling on rectifier during source testing with capture hood in place.)

Sample Number: C30-RA C31-RA C32-RA C33-RA

Sample Date: 5/24/05 5/24/05 5/25/05 5/25/05

Sampling Time (minutes) 264 122 128 125

Volume Sampled (liters) 2640 1220 1280 1250

Cr (VI) Collected (ng/sample) 5837 1964 646 1069

Indoor Ambient Concentration (ng/m 3 ) 2,200 1,600 510 860

This rectifier is next to the plating tank, but outside the source test capture hood.

Table A3-1b Clovis Specialty Plating – Test Week 3 Indoor (PQ-100) Ambient Hexavalent Chromium Sampling Results

(Ambient indoor sampling during source testing with capture hood in place.)

Sample Number: C31-CA C32-CA C33-CA

Sample Date: 5/24/05 5/25/05 5/25/05

Sampling Time (minutes) 132 129 121

Volume Sampled (liters) 1320 1290 1210

Cr (VI) Collected (ng/sample) 1425 978 1067

Indoor Ambient Concentration (ng/m 3 ) 1,100 760 880

CA samples parallel RA samples above - away from the tank and rectifier, but in the same room. RA samples were collected at the same location as Clovis 1 indoor samples.Phase II – Test 6 Facility 6

19 Table VI-4 Clovis Specialty Decorative Chromium Plating Tank Test Week 4 (Clovis 4)

Sampling Dates – June 29-30, 2005

Sampling Location

Sample Number C41 C42 C43 Sampling Date 6/29/05 6/30/05 6/30/05

Plating Tank Data Totalizer (amp-hours) 356 299 345 Production Rate (amp-hrs/hr) 178 149.5 172,5
Freeboard (inches to overflow) * 4.5 4.0 4.0

Surface Tension (dynes/cm) 31.5 31.5 31.5

Chromic Acid Conc. (oz/gal) 28.2 28.2 28.2

Bath Temperature ( o F) 105.6 108.6 107.6

Stack Data

Stack Temperature ( 0 F) 87.5 87.5 95
Velocity (ft/sec) 21.6 19.0 19.8
Static Pressure ("H 2 0) -0.24 -0.17 -0.20

Stack Area (sq. ft.) 0.785 0.785 0.785
Flow Rate (DSCFM) 955 837 864
Moisture (% of v/v) 1.3 1.6 1.3

Sampling Data

Sampling Time (minutes) 120 120 120 Sample Volume (DSCF) 111 100 102 Chromium Data (ng/sample)

Total Chromium 40,860 14,900 29,290

Hexavalent Chromium 29,910 9,890 25,020
Isokinetic Rate (%) 99.3 102 101

EMISSIONS Concentration (ng/dscf)

Total Chromium 368 149 287

Hexavalent Chromium 269 99 245 Emission Rate (mg/hr)

Total Chromium 21 7.5 15

Hexavalent Chromium 15 5.0 13

Emissions Factors (mg/amp-hr)**

Total Chromium 0.12 0.050 0.086

Hexavalent Chromium 0.087 0.033 0.074

DSCF & DSCFM means dry standard cubic feet and dry standard cubic feet per minute at 68 F and 29.92 inches Hg.

* Measured at the start of the plating day.

** Emissions Factors (mg/amp-hr) = Emission Rate (mg/hr) / Plating Tank Production Rate (amp-hrs/hr)Phase II – Test 6 Facility 6

20 Sample Collection: JUNE 2005

Air Volume Cr(VI) Cr(VI) Plating Tank
Filter ID liters ng/ml ng recovered ng/liter ng/m 3 Total amp-hrs

C41-RA 1,330 98.68 1480 1.113 1113 356
C41-CA 1,320 206.81 3102 2.350 2350 "

C41-CAC 136 21.67 325 2.390 2390 "
C42-RA 1,570 46.91 704 0.448 448 299
C42-CA 1,540 122.14 1832 1.190 1190 "

42-CAC 171 "
C43-RA 1,200 63.13 947 0.789 789 345
C43-CA 1,190 101.59 1524 1.281 1281 "

C43-CAC 131 12.91 194 1.481 1481 "

extraction volume = ~15 ml.

-CAC sampler was located ~1 meter from CA sampler but sampled at 1 lpm instead of 10 lpm. -CA sampler was located behind and on the opposite side of the sampling hood. -RA sampler was located on the plating tank rectifier and next to the sampling hood.

(with Capture Hood over Plating Tank)

Table A4-1

Indoor Ambient Hexavalent Chromium Results Clovis Specialty Plating (Clovis 4) Test

Cr(VI)Phase II – Test 7 Facility 7

21 Table VI Walker’s Custom Chrome Chromium Plating Tank Sampling Dates – February 15-23, 2006

Sampling Location
Sample Number W-11 W-12 W-13 Sampling Date 2/15/06 2/16/06 2/17/06

Plating Tank Data Totalizer (amp-hours) 331 300 300 Production Rate (amp-hrs/hr) 165.5 75 75
Freeboard (inches to overflow) 4.75 4.5 5
Surface Tension (dynes/cm) 35.1 35.4 35.4
Chromic Acid Conc. (oz/gal) 34.8 34.8 34.8
Bath Temperature ( o F) 90-100 92-105 98-107

Stack Data
Stack Temperature ( 0 F) 65 61 61 Velocity (ft/sec) 19.2 20.2 21.6
Static Pressure ("H 2 0) -0.26 -0.24 -0.25
Stack Area (sq. ft.) 0.785 0.785 0.785
Flow Rate (DSCFM) 899 958 1000
Moisture (% of v/v) 0.7 0.5 0.9

Sampling Data
Sampling Time (minutes) 120 240 240 Sample Volume (DSCF) 110.56 233.10 235.72 Chromium Data (ng/sample)

Total Chromium 1700 5090 4680

Hexavalent Chromium 1262 3232 3610
Isokinetic Rate (%) 105 104 101

EMISSIONS Concentration (ng/dscm)

Total Chromium 543 771 701

Hexavalent Chromium 403 490 541 Emission Rate (mg/hr)

Total Chromium 0.83 1.25 1.19

Hexavalent Chromium 0.62 0.80 0.92

Emissions Factors (mg/amp-hr)

Total Chromium 0.0050 0.017 0.016

Hexavalent Chromium 0.0037 0.011 0.012

Standard Conditions = 68 o F and 29.92 in. Hg. DSCF = dry standard cubic feet. DSCM = dry standard cubic meter. DSCFM = dry standard cubic feet per minute.Appendix G: Hexavalent Chromium Content Contained in Dust Samples Collected from Chromium Plating Shops in San Diego County, 2002DateLocation% of TotalHex CrTotal CrSampledthat is Hexmg/kg8/20/2002within 2 feet from the side of thechrome plating tank near theemission collection vent ducts16%4,99030,4008/20/2002the corners of the back doors(entry and roll up garage doors)2%3.62245/23/2002on top of tank, within 1 foot infront of tank.37%33,00088,3005/23/2002near back north east door.N/A< 0.81,9205/23/2002near back north west door.N/A< 0.84,9205/23/2002in adjacent alley north of thefacility.N/A< 0.8237/25/2002within 5 feet in front of tank nearrectifier. Note: sample takenunderneath the woodenoperating flooring31%30,80098,8007/26/2002on tank, within 3 feet in front oftank.67%89,800135,0007/26/2002near roll up garage door in backof facility.N/A< 0.87726/28/2002within 2 feet in front of tank, ontop of 5 foot high DI? cylinder.25%39,200156,0001Appendix G: Hexavalent Chromium Content Contained in Dust Samples Collected from Chromium Plating Shops in San Diego County, 20026/28/2002within 2 feet behind tank. Note:no "outlet" sample was takensince smoke indicated changingair currents.34%23,90069,9006/18/2002on lip of tank, within 1 foot infront of tank, within 2 feet infront of tank (near activatortank).52%30,00058,0006/18/2002near back door of facility.N/A< 206,8306/25/2002within 3 feet to the right side oftank P7-4 (on cement floorinside paneling), within 3 feet infront right side of Tank P7-8.11%4073,7906/25/2002near (east?) door next tocomposite mesh pad.7%1722,4106/25/2002on surface within 2 feet of tankP7-13. Note: surface is two feethigher tank top of tank P7-13.0.1%8169,8007/9/2002within 6 feet in front of tank(near rinse tank), within 2 feet inthe side of tank, within 10 feetbehind tank. Note: sampletaken on lower cement flooringwhich is lower than the woodenoperating flooring.30%9,56031,4002Appendix G: Hexavalent Chromium Content Contained in Dust Samples Collected from Chromium Plating Shops in San Diego County, 20027/9/2002near roll up garage door on sideof facility.N/A< 0.81957/17/2002within 1 foot to the left of thetank on cement floor ofsecondary containment. Note:no elevated wooden operatingfloor at facility.22%8,16037,5007/10/2002within 1 foot in front of tank,within 5 feet in front of tank,within 1 foot behind tank.13%1,32010,1007/10/2002near front windows of facility,along south east wall ofpolishing room.N/A< 0.81827/16/2002on tank, within 2 feet in front oftank.31%28,70093,3007/16/2002near front door of facility.N/A< 0.83483

## Appendix H

Air Quality Modeling Parameters and ResultsAppendix H

Appendix H 1 

## Air Quality Modeling of Emissions from Shops with Chromium Plating Services

P repared by: Tony Servin, P.E.,

Planning and Technical Support Division, California Air Resources Board, California Environmental Protection Agency

Date: November 14, 2004



### Summary
It has been requested to evaluate the air quality impacts of emissions from shops with chromium plating services. The shops in this analysis vent emissions through forced ventilation (stacks) or natural ventilation (fugitive). The facilities with forced ventilation are grouped into four categories directly related to expected plume rise and amp-hour usage (low, medium, high, or horizontal). The facilities with natural ventilation are grouped into three categories dependent on the physical size of the shop (small, medium, or large). The dispersion of emissions is simulated with the latest version of the U.S. EPA air dispersion model ISCST3 (02035). The meteorological data used in the dispersion are collected from four locations throughout the state (Oakland, Fresno, San Diego, and Pasadena). In addition, a worst-case analysis is also simulated with screening meteorological conditions.

The analysis is based on a unit emission rate (1 g/s). Therefore, to obtain the estimated annual average concentration of hexavalent chromium in the air, the model results should be multiplied by the pollutant emission rate. Table S-1 shows a summary of the maximum chi/q 1 for the different shop types and screening meteorological conditions. The maximum chi/q is 1500 ( μ g/m 3 )/(g/s) for shops with horizontal stacks or small shops with fugitive ventilation. Details of the analysis, example calculations, and additional results with historical meteorological data are

described below.

1 Chi/q is the predicted concentration based on an emission rate of 1 g/s. The chi/q is multiplied by the actual emission rate (g/s) to obtain the downwind concentration ( μ g/m 3 ). This is possible because the downwind concentration is directly proportional to the emission rate as described in the ISCST3 air quality model.Appendix H

Appendix H 2 Table S.1 – Maximum (Screening) Annual Average Chi/Q ( μ g/m 3 )/(g/s) from Shops with Chromium Plating

Shop Distance Downwind

Type Size 20 m 30 m 40 m 50 m 100 m 200 m 500 m 1000 m

Low 310 340 300 190 64 12 4

Medium 140 140 130 84 47 12 4

High 72 89 88 69 43 11 3 Stack

Horizontal 1500 1300 1000 780 250 70 12 4

Small 1500 990 710 530 210 61 12 3

Medium 1000 700 520 430 190 59 12 3 Fugitive

Large 620 470 370 300 160 54 11 3

• Multiply by hourly emissions [annual inventory (g) / (3285 hrs/yr) / (3600 s/hr)] to obtain annual average concentration.

• A blank cell indicates no calculation because the plume is in the building wake or is

still aloft.



### Approach

Facilities (shops) that provide decorative and hard chromium plating services have the potential to emit hexavalent chromium. It has been requested by ARB’s Stationary Source Division to analyze the downwind dispersion of emissions from various shop configurations for chrome plating facilities. Data for 26 different shops with forced ventilation (stacks) and shops with natural ventilation (fugitive) in three sizes are provided by ARB’s Stationary Source Division (Appendix H-1). The data for the shops with stacks are summarized into four categories based on the potential for plume rise and amp-hour consumption (further details below).

The stack parameters and fugitive building parameters are input to the latest version of the U.S. EPA ISCST3 (Version 02035) air quality model to estimate downwind impacts. Urban dispersion coefficients are used in ISCST3. Receptor heights are set at 1.2 meters above ground level. Terrain is assumed to be flat. The meteorological data used in the dispersion are collected from four locations throughout the state (Oakland, Fresno, San Diego, and Pasadena). In addition, a worst-case analysis is also simulated with screening meteorological conditions.

The model results are presented as annual average chi/q, which are concentrations based on a unit emission rate (1 g/s). In this way, the model results may be scaled to represent annual average concentrations from any facility by multiplying the chi/q with the facility emission rate.



### Release Parameters - Stack Emissions

Stack data for shops with forced ventilation provided by SSD (Appendix H-1). These stack data are grouped in order to reduce the number of air dispersion modelAppendix H

Appendix H 3 runs. Since all stacks essentially emit at approximately ambient conditions, temperature is not considered for stratifying the data. Of the stack parameters with vertical stack releases, we calculate the stack height (feet) multiplied by the gas flow (cubic feet per second). These two parameters are directly used to estimate final plume rise in the air dispersion model and are related to estimating downwind concentration. Figure 1 shows the stratified data as a function of facility amp-hours.

Figure 1 – Height * Stack Flow vs Amp - Hours

The data shown in Figure 1 are stratified into four groups. Table 1 shows the four stratified groups.

Table 1 – Stack Data Stratified

Shop Group Plume Rise

Potential Amp Hours

A Low < 5,000,000 amp-hrs

B Medium 5,000,000 – 50,000,000 amp-hrs C High > 50,000,000 amp-hrs D Horizontal any amp-hrs with horizontal stack or raincap

Group D is for all stacks with horizontal releases or raincaps regardless of amphours. Plume rise is canceled when the stacks are horizontal or in the presence of a raincap for ambient temperature plumes. - 2,000 4,000 6,000 8,000 10,000 12,000 14,000

0 10,000,000 20,000,000 30,000,000 40,000,000 50,000,000 60,000,000 70,000,000 80,000,000 90,000,000

Amp-HrsFT-CFS

Group B (5e6 - 50e6 amp-hrs)

Group A (<5e6 amp-hrs) Group C (>50e6 amp-hrs)Appendix H

Appendix H 4 Mean stack conditions for the vertical stacks, groups A-C, are used for each group in Table 1 as inputs to the air dispersion model. Figure 1 also shows data that lie outside of the groups. These data are not used in the mean. As a result, the predicted downwind concentrations for groups A and B will be biased towards overestimation of the mean. Table 2 shows the mean stack parameters for the four groupings. The stack data for the 26 shops (Appendix H-1) are incomplete for all necessary parameters to estimate plume rise. Therefore the mean conditions calculated in Table 2 is based on data from the shops where all parameters are

available.

Table 2 – Stack Parameters

Parameter Group A Group B Group C Group D

Number of Facilities 4 3 3 4 Flow (cfs) 28 111 200 na Diameter (m) 0.32 0.66 0.92 0.81 Velocity (m/s) 10.4 12.2 8.5 0.001 Temperature (C) 24 24 24 24 Stack Height (m) 9.1 9.1 12.8 5.6 Building Height (m) 8.8 8.8 12.5 5.3 Building Length (m) 10 10 10 10
Note 1: Building length, width and height are used for building downwash. We assume all stacks are impacted by building downwash. Therefore, building height is one foot (0.3 m) below stack height and building length and width is assumed to be ten

meters. Note 2: Raincaps and horizontal stacks (group D) are treated differently by setting the exit velocity to 0.001 m/s, turning stacktip downwash off, and reducing the stack height by three times the stack diameter (OEHHA Air Toxics Hot Spots Program Risk Assessment Guidelines, Part IV, 2000).



### Release Parameters - Fugitive Emissions

Data for the shops with natural ventilation are provided by SSD (Appendix H-1). Table 3 shows a summary of the assumed release parameters for volume source releases in the dispersion model. The release parameters summarized in Table 3 reflect the lower range of the building dimensions in order to bias the predicted

concentrations towards overestimation.

Table 3 – Volume (Fugitive) Source Parameters

Parameter Group A-Vol (Small) Group B-Vol

(Medium) Group C-Vol

(Large)

Number of Facilities 14 42 11 Area Size (m 2 ) <279 279 – 929 929 – 2787 Modeled Length (m) 10 17 30 Release Height (m), H/2 2.5 2.5 2.5 Syo (m), L/4.3 2.3 4.0 7.0 Szo(m), H/2.15 2.3 2.3 2.3 20 m receptor distance (m) 25 28 35Appendix H

Appendix H 5 

### Meteorological Data

Meteorological data for this analysis are from four representative locations plus a screening analysis. Table 4 shows the latest consecutive five years of processed meteorological data, as recommended by the U.S. EPA Guideline on Air Quality Models. Shorter periods are used where longer periods are not available. The operating period for the chrome platers is 6 am to 3 pm. Therefore, Table 4 also includes a summary of meteorological conditions during normal operating hours. Appendix H-2 is the wind rose companion for Table 4.

Table 4 – Meteorological Data Summary

Oakland Fresno San Diego (Miramar) Pasadena screening

Period Winds 1960-1964 1985-1989 1967-1971 1981

Avg. Speed 4.5 m/s 3.1 m/s 2.8 m/s 1.6 m/s 24

hours Calms 11% 14% 17% 22%

Avg. Speed 4.5 m/s 2.9 m/s 3.1 m/s 1.6 m/s 6 am – 3 pm Calms 9% 13% 14% 16% Screening meteorological data

are restricted to

P-G stabilities A-D (daytime conditions only).

Screening meteorological data represents inputs used in the U.S. EPA SCREEN3 air dispersion model. Our application is limited to daytime hours, Pasquill-Gifford stabilities A through D, since it is assumed emissions occur within the time period of 6 am to 3 pm. To estimate annual averages from the screening 1-hour averages, we multiply by the scaling factors of 0.5 to obtain an eight hour average and then we multiply by 9/24 to obtain the annual average as described in the HARP User Guide, December 2003.



### Receptors

Receptors are placed at a minimum distance of 20 meters from the edge of building or stack. Polar receptors are used to plot the maximum downwind annual average concentration regardless of wind direction. Flagpole receptors set at 1.2 meters (4 ft.) above ground.Appendix H

Appendix H 6 

### Results Table 5 shows the annual average chi/q for screening conditions. As a result the chi/q in Table 5 are biased towards overprediction. Additional tables are provided below that show results with actual meteorological conditions for four locations in the state. The average emission rate (grams/second) should be multiplied by the chi/q to obtain the annual average concentration ( μ g/m 3 ). The average emission rate (grams/second) is based on nine hour days and 365 days per year. This is lower than the actual hourly emission rate during plating activity. However, since emissions may be distributed at any time throughout 6 am to 3 pm, we assumed the emissions are uniformly distributed over nine hours for modeling purposes.

Table 5 – Maximum (Screening) Annual Average Chi/Q ( μ g/m 3 )/(g/s) from Shops with Chromium Plating

Shop Distance Downwind

Type Size 20 m 30 m 40 m 50 m 100 m 200 m 500 m 1000 m

Low 310 340 300 190 64 12 4

Medium 140 140 130 84 47 12 4

High 72 89 88 69 43 11 3 Stack

Horizontal 1500 1300 1000 780 250 70 12 4

Small 1500 990 710 530 210 61 12 3

Medium 1000 700 520 430 190 59 12 3 Fugitive

Large 620 470 370 300 160 54 11 3

• Multiply by hourly emissions [annual inventory (g) / (3285 hrs/yr) / (3600 s/hr)] to obtain annual average concentration.

• A blank cell indicates no calculation because the plume is in the building wake or is

still aloft.

As an example for using Table 5, if the annual hexavalent chromium inventory for a shop is 0.1 lbs/yr, the maximum annual average concentration is estimated as

follows:

The chi/q results based on meteorological data from Oakland, Fresno, San Diego, and Pasadena are shown in Tables 6 through 9, respectively. The example calculation shown above should be used to convert the chi/q in Tables 6-9 to annual average concentrations. The results based on Pasadena meteorology, Table 9, show the highest chi/q. )/(3600)/(3285 )/(454 )/(1.0 )/( )/( 1500 0058.0 3

3 hrsy rhrs lbg yrlbs

sg mug

m g age AnnualAver

× × × = = μ

chi/q inventory conversion factorsAppendix H

Appendix H 7 Table 6 – Maximum (Oakland) Annual Average Chi/Q ( μ g/m 3 )/(g/s) from Shops with Chromium Plating

Shop Distance Downwind

Type Size 20 m 30 m 40 m 50 m 100 m 200 m 500 m 1000 m

Low 58 51 43 17 4.9 0.8 0.2

Medium 46 44 39 16 4.8 0.8 0.2

High 17 22 22 13 4.4 0.8 0.2 Stack

Horizontal 170 120 86 63 19 5.0 0.8 0.2

Small 180 110 70 50 17 4.7 0.8 0.2

Medium 140 83 58 45 17 4.7 0.8 0.2 Fugitive

Large 97 66 48 36 17 4.7 0.8 0.2

• Multiply by hourly emissions [annual inventory (g) / (3285 hrs/yr) / (3600 s/hr)] to obtain annual average concentration.

• A blank cell indicates no calculation because the plume is in the building wake or is

still aloft.

Table 7 – Maximum (Fresno)

Annual Average Chi/Q ( μ g/m 3 )/(g/s) from Shops with Chromium Plating

Shop Distance Downwind

Type Size 20 m 30 m 40 m 50 m 100 m 200 m 500 m 1000 m

Low 61 54 44 16 4.7 0.8 0.2

Medium 43 41 36 15 4.4 0.8 0.2

High 17 23 23 13 4.1 0.7 0.2 Stack

Horizontal 180 130 87 63 19 4.9 0.8 0.2

Small 180 110 70 50 17 4.7 0.8 0.2

Medium 140 83 58 45 17 4.7 0.8 0.2 Fugitive

Large 95 65 47 36 17 4.6 0.8 0.2

• Multiply by hourly emissions [annual inventory (g) / (3285 hrs/yr) / (3600 s/hr)] to obtain annual average concentration.

• A blank cell indicates no calculation because the plume is in the building wake or is

still aloft.Appendix H

Appendix H 8 Table 8 – Maximum (San Diego, Inland) Annual Average Chi/Q ( μ g/m 3 )/(g/s) from Shops with Chromium Plating

Shop Distance Downwind

Type Size 20 m 30 m 40 m 50 m 100 m 200 m 500 m 1000 m

Low 71 64 53 20 5.4 0.9 0.2

Medium 49 47 41 17 5.2 0.9 0.2

High 20 27 27 15 4.8 0.8 0.2 Stack

Horizontal 220 150 110 75 22 5.6 0.9 0.2

Small 220 130 85 60 20 5.3 0.9 0.2

Medium 220 100 71 54 20 5.3 0.9 0.2 Fugitive

Large 120 83 59 44 20 5.3 0.9 0.2

• Multiply by hourly emissions [annual inventory (g) / (3285 hrs/yr) / (3600 s/hr)] to obtain annual average concentration.

• A blank cell indicates no calculation because the plume is in the building wake or is

still aloft.

Table 9 – Maximum (Pasadena)

Annual Average Chi/Q ( μ g/m 3 )/(g/s) from Shops with Chromium Plating

Shop Distance Downwind

Type Size 20 m 30 m 40 m 50 m 100 m 200 m 500 m 1000 m

Low 130 120 100 38 11 1.7 0.4

Medium 52 53 50 28 9.6 1.7 0.4
High 25 38 39 25 9.0 1.6 0.4 Stack

Horizontal 470 320 220 150 43 11 1.8 0.4

Small 420 250 160 120 39 10 1.7 0.4

Medium 340 190 130 100 38 10 1.7 0.4 Fugitive

Large 230 150 110 81 38 10 1.7 0.4

• Multiply by hourly emissions [annual inventory (g) / (3285 hrs/yr) / (3600 s/hr)] to obtain annual average concentration.

• A blank cell indicates no calculation because the plume is in the building wake or is

still aloft.Appendix H-1

Appendix H 9 

### Appendix H-1

Chromium Plating Shop Physical Descriptions for

Emission Release Parameters Provided by ARB’s Stationary Source DivisionAppendix H-1

Appendix H 10 Chromium Plating & Anodizing Facilities Dispersion Modeling Parameters

There are two types of facilities that need to be modeled. Facilities with ventilation systems (49%), and facilities without ventilation systems (51%).

Ventilated facilities with stacks: Amp-hr distribution: Range Median Mean

500 – 83,000,000 1,000,000 8,000,000

Operating Parameter vary from continuous operation to the minimum of 4 hrs/day, 5 days/week

Facility Amp-hrs Stack height

(ft) Stack

diameter (in) Exit Velocity

(ft/sec) Temperature

( o F)

10,000 building height 10 X 15 26.56 78.5
35,000 25 11.5 X 14.5 18.1 82

200,000 25-Hor 34 21.5 78
225,000 26 13.5 43.2 73
1,100,000 building height 15 X 7.5 28.9 70
1,300,000 building height 19 1/2 X 26 13 85
1,400,000 30 28 58.7 69

2,200,000 ? 12 50.4 75
2,200,000 32 8 47.3 70
4,300,000 34 14 28 69
5,100,000 55 26 58.6 77
8,700,000 25 30.75 31.2 75

9,800,000 30 13.5 67 94
10,700,000 48 35 55
12,000,000 45 32 32.6 91
17,800,000 building+185'' 32 56.8 81
18,500,000 25-Hor 26 X 22 17.5 70
24,000,000 30 30 21.3 78
28,700,000 30-horizontal 27.75 X 39.75 23.75 78
30,500,000 25-Hor 26.75 X 21.75 21 60
34,000,000 Building +11' 24 16 84
62,000,000 40.5 34 32.9 75

39 39 40.83 78
73,500,000 50 39 18.5 64

50 39 13.5 64
79,000,000 36 36 33.7 70

South Coast Data: on stack height (64):

28 with 4.3 – 7.3m stack 30 with 7.3 – 15 m stack 5 with > 15m stackAppendix H-1

Appendix H 11 Unventilated Facilities:

Volume source we need building dimensions. The source has usually one tank.

Amp-hr distribution: Range Median Mean

120 – 10,000,000 70,000 470,000

Operating Parameter vary from 12 hrs/day, 7days/week to the minimum of 2 hrs/day, 5 days/week

SCAQMD building dimensions for 68 volume sources

14 with < 279 m 2

42 with 279 – 929 m 2

11 with 929 – 2,787 m 2Appendix H-2

Appendix H 12 

### Appendix H-2

Wind Roses and Modeling OutputsAppendix H-2

Appendix H 13

Figure B1 – Oakland Wind Rose (6 am – 3 pm)

Figure B2 – Oakland Wind Rose (All Hours)

DATE:

10/22/2004

W RPLOT View - Lakes Environmental Software WIND ROSE PLOT: Station # 23230, Oakland Airport COMMENTS:

All hours reporting.

PROJECT NO.: MODELER: COMPANY NAME: NORTH

SOUTH WEST EAST 4% 8% 12% 16% 20% DATA PERIOD:

1960-1964

Jan 1 - Dec 31

00:00 - 23:00

W I N D S P E E D ( m / s )

> = 5

. 4

3

. 3

- 5

. 4

1

. 8

- 3

. 3

0

. 5

- 1

. 8

C a l m s : 1 0

. 6 3 % AVG. WIND SPEED:

4.51 m/s CALM WINDS:

10.63% TOTAL COUNT:

43848 hrs. DISPLAY: Wind Speed Direction (blowing from) DATE:

10/22/2004

WRPLOT View - Lakes Environmental Software WIND ROSE PLOT: Station # 23230, Oakland Airport COMMENTS:

All hours reporting.

PROJECT NO.: MODELER: COMPANY NAME: NORTH

SOUTH WEST EAST 4% 8% 12% 16% 20% DATA PERIOD:

1960-1964

Jan 1 - Dec 31

06:00 - 14:00

W I N D S P E E D ( m / s )

> = 5

. 4

3

. 3

- 5

. 4

1

. 8

- 3

. 3

0

. 5

- 1

. 8

C a l m s : 8

. 7 9 % AVG. WIND SPEED:

4.47 m/s CALM WINDS:

8.79% TOTAL COUNT:

16443 hrs. DISPLAY: Wind Speed Direction (blowing from)Appendix H-2

Appendix H 14

Figure B3 – Fresno Wind Rose (6am – 3pm)

Figure B4 – Fresno Wind Rose (All Hours)

DATE:

10/22/2004

WRPLOT View - Lakes Environmental Software WIND ROSE PLOT: Station # 93193, Fresno Air Terminalt COMMENTS:

6 am to 3 pm hours reporting.

PROJECT NO.: MODELER: COMPANY NAME:

California Air Resources

Board NORTH

SOUTH WEST EAST 5% 10% 15% 20% 25% DATA PERIOD:

1985-1989

Jan 1 - Dec 31

00:00 - 23:00

W I N D S P E E D ( m / s )

> = 5

. 4

3

. 3

- 5

. 4

1

. 8

- 3

. 3

0

. 5

- 1

. 8

C a l m s : 1 4

. 3 1 % AVG. WIND SPEED:

3.08 m/s CALM WINDS:

14.31% TOTAL COUNT:

43824 hrs. DISPLAY: Wind Speed Direction (blowing from) DATE:

10/22/2004

WRPLOT View - Lakes Environmental Software WIND ROSE PLOT: Station # 93193, Fresno Air Terminalt COMMENTS:

All hours reporting.

PROJECT NO.: MODELER: COMPANY NAME: NORTH

SOUTH WEST EAST 3% 6% 9% 12% 15% DATA PERIOD:

1985-1989

Jan 1 - Dec 31

06:00 - 14:00

W I N D S P E E D ( m / s )

> = 5

. 4

3

. 3

- 5

. 4

1

. 8

- 3

. 3

0

. 5

- 1

. 8

C a l m s : 1 3

. 3 4 % AVG. WIND SPEED:

2.87 m/s CALM WINDS:

13.34% TOTAL COUNT:

16434 hrs. DISPLAY: Wind Speed Direction (blowing from)Appendix H-2

Appendix H 15

Figure B5 – San Diego (Miramar) Wind Rose (6am – 3pm)

Figure B6 – San Diego (Miramar) Wind Rose (All Hours)

DATE:

10/22/2004

WRPLOT View - Lakes Environmental Software WIND ROSE PLOT: Station # 93107, San Diego (Miramar) COMMENTS:

6am - 3pm hours reporting.

PROJECT NO.: MODELER: COMPANY NAME:

California Air Resources

Board NORTH

SOUTH WEST EAST 3% 6% 9% 12% 15% DATA PERIOD:

1967-1971

Jan 1 - Dec 31

00:00 - 23:00

W I N D S P E E D ( m / s )

> = 5

. 4

3

. 3

- 5

. 4

1

. 8

- 3

. 3

0

. 5

- 1

. 8

C a l m s : 1 6

. 9 0 % AVG. WIND SPEED:

2.80 m/s CALM WINDS:

16.90% TOTAL COUNT:

43824 hrs. DISPLAY: Wind Speed Direction (blowing from) DATE:

10/22/2004

WRPLOT View - Lakes Environmental Software W IND ROSE PLOT: Station # 93107, San Diego (Miramar) COMMENTS:

All hours reporting.

PROJECT NO.: MODELER: COMPANY NAME:

California Air Resources

Board NORTH

SOUTH WEST EAST 3% 6% 9% 12% 15% DATA PERIOD:

1967-1971

Jan 1 - Dec 31

06:00 - 14:00

W I N D S P E E D ( m / s )

> = 5

. 4

3

. 3

- 5

. 4

1

. 8

- 3

. 3

0

. 5

- 1

. 8

C a l m s : 1 4

. 4 4 % AVG. WIND SPEED:

3.10 m/s CALM WINDS:

14.44% TOTAL COUNT:

16434 hrs. DISPLAY: Wind Speed Direction (blowing from)Appendix H-2

Appendix H 16

Figure B7 – Pasadena Wind Rose (6am – 3pm)

Figure B8 – Pasadena Wind Rose (All Hours)

DATE:

10/22/2004

W RPLOT View - Lakes Environmental Software WIND ROSE PLOT: Station # 51122, Pasadena COMMENTS:

All hours reporting.

PROJECT NO.: MODELER: COMPANY NAME:

California Air Resources

Board NORTH

SOUTH WEST EAST 3% 6% 9% 12% 15% DATA PERIOD:

1981

Jan 1 - Dec 31

00:00 - 23:00

W I N D S P E E D ( m / s )

> = 5

. 4

3

. 3

- 5

. 4

1

. 8

- 3

. 3

0

. 5

- 1

. 8

C a l m s : 2 1

. 8 9 % AVG. WIND SPEED:

1.62 m/s CALM WINDS:

21.89% TOTAL COUNT:

8760 hrs. DISPLAY: Wind Speed Direction (blowing from) DATE:

10/22/2004

W RPLOT View - Lakes Environmental Software W IND ROSE PLOT: Station # 51122, Pasadena COMMENTS:

6am to 3pm hours reporting.

PROJECT NO.: MODELER: COMPANY NAME:

California Air Resources

Board NORTH

SOUTH WEST EAST 4% 8% 12% 16% 20% DATA PERIOD:

1981

Jan 1 - Dec 31

06:00 - 14:00

W I N D S P E E D ( m / s )

> = 5

. 4

3

. 3

- 5

. 4

1

. 8

- 3

. 3

0

. 5

- 1

. 8

C a l m s : 1 6

. 4 4 % AVG. WIND SPEED:

1.58 m/s CALM W INDS:

16.44% TOTAL COUNT:

3285 hrs. DISPLAY: Wind Speed Direction (blowing from)Appendix H-2

Appendix H 17 Modeling
Chrome Plating with a stack source, unit emission rate

q (g/s) days/week q (g/yr) q (lb/yr)

1 7 11,793,600 26,000

(m) (ug/m3) (ug/m3) (ug/m3)

Distance from edge of facility Fresno San Diego,

Inland Pasadena

20

Low n/a n/a n/a

Medium n/a n/a n/a
High n/a n/a n/a

Horizontal 180.00 220.00 470.00

30

Low 61.00 71.00 130.00

Medium 43.00 49.00 52.00 High 17.00 20.00 25.00

Horizontal 130.00 150.00 320.00

40

Low 54.00 64.00 120.00

Medium 41.00 47.00 53.00 High 23.00 27.00 38.00

Horizontal 87.00 110.00 220.00

50

Low 44.00 53.00 100.00

Medium 36.00 41.00 50.00 High 23.00 27.00 39.00

Horizontal 63.00 75.00 150.00

100

Low 16.00 20.00 38.00

Medium 15.00 17.00 28.00 High 13.00 15.00 25.00

Horizontal 19.00 22.00 43.00

200

Low 4.70 5.40 11.00

Medium 4.40 5.20 9.60 High 4.10 4.80 9.00

Horizontal 4.90 5.60 11.00

500

Low 0.80 0.90 1.70

Medium 0.80 0.90 1.70 High 0.70 0.80 1.60

Horizontal 0.80 0.90 1.80

1000

Low 0.20 0.20 0.40

Medium 0.20 0.20 0.40 High 0.20 0.20 0.40

Horizontal 0.20 0.20 0.40Appendix H-2

Appendix H 18 ISCST (Version 02035) Model Results In addition to the details in the figures, the following met. Data are used to estimate long term (annual) averages) These data are the latest available processed databases.Appendix H-2

Appendix H 19 Modeling
Chrome Plating with fugitive source, unit emission rate

q (g/s) hrs/day days/week q (g/yr) q (lb/yr)

1 9 7 11,793,600 26,000 |--------- period (annual) average ----

--------------------------- ---l

(m) (ug/m3) (ug/m3) (ug/m3) (ug/m3)

Distance from edge of facility Oakland Fresno San Diego,

Inland Pasadena

20

small 180.00 180.00 220.00 420.00

medium 140.00 140.00 220.00 340.00
large 97.00 95.00 120.00 230.00

30

small 110.00 110.00 130.00 250.00

medium 83.00 83.00 100.00 190.00
large 66.00 65.00 83.00 150.00

40

small 70.00 70.00 85.00 160.00

medium 58.00 58.00 71.00 130.00
large 48.00 47.00 59.00 110.00

50

small 50.00 50.00 60.00 120.00

medium 45.00 45.00 54.00 100.00
large 36.00 36.00 44.00 81.00

100

small 17.00 17.00 20.00 39.00

medium 17.00 17.00 20.00 38.00
large 17.00 17.00 20.00 38.00

200

small 4.70 4.70 5.30 10.00

medium 4.70 4.70 5.30 10.00
large 4.70 4.60 5.30 10.00

500

small 0.80 0.80 0.90 1.70

medium 0.80 0.80 0.90 1.70
large 0.80 0.80 0.90 1.70

1000

small 0.20 0.20 0.20 0.40

medium 0.20 0.20 0.20 0.40
large 0.20 0.20 0.20 0.40Appendix H-2

Appendix H 20 ISCST (Version 02035) Model Results In addition to the details in the figures, the following met. data are
used to estimate long term (annual) averages)
These data are the latest available processed databases.Appendix H-2

Appendix H 21 

### REFERENCE

ARB Compilation of Emission Testing Results from Chromium Plating and Chromic Acid Anodizing Facilities