### Instructions for completing the Fuel Material Analysis Information

This Information Collection Request (ICR) spreadsheet is intended to collect information about chemical analyses of fuels used fossil fuel burning power plants. Constituents of concern are: mercury, chlorine, fluorine, and metals, such as antimony, beryllium, cadmium, chromium, cobalt, lead, manganese, nickel, and selenium. to be used for one boiler of one facility but is designed to allow multiple (up to 4) fuel analyses at that specific boiler. This number of analyses would coincide with one boiler where emissions testing for all 4 HAP surrogates were being tested. Data for multiple boilers should be handled by using separate spreadsheets. Fields that are highlighted in yellow are required fields. Green highlighted cells should be filled using the drop

- down boxes, included. Gray fields are automatically filled from other fields.

Please name each resulting spreadsheet with the following naming convention: [FacilityID]_Unit_[BoilerID]_Fuels_Testing.xls (example: 8100_Unit_2_Fuels_Testing.xls).

Please refer to the following steps when using these spreadsheets.

1. Please enter the EIA Facility Code, Facility Name and Boiler ID of your boiler on the Boiler Information worksheet. 2. Please enter the test date on the Boiler Information worksheet. 3. Please choose the type of fuel being sampled using the drop

- down in the fuel column of the Boiler Information worksheet. If you choose "other", please provide a description of the fuel in the Other Fuel Description column. 4. Please provide the analysis method for each constituent in the Analysis Methods worksheet. For example: "ASTM D5865

- 04". 5. Please check the Units of Measure tables for HHV, Metals, and Cl/Fl in the Picklist worksheet (orange tab). If the units of measure that you plan to report are not found in the Units of measure table, please fill them in the blank, orange highlighted, cell in each table. This allows you to choose the units of measure in the Fuels Sample Results worksheet. 6. Select the HAPs Test Group (i.e., HAP surrogate) for which the tab's data reflects (o range highlighted cell) 7. Provide the Sample Number and Sample Date on the Fuels Sample Results worksheet. You must provide a minimum of 3 composite samples consisting of 3 combined grab samples each, but you are not limited to that number if you have collected more. 8. Provide the results of the analyses for each constituent requested. Use the drop

- down boxes to fill in the units of

measure.

### Information

This Information Collection Request (ICR) spreadsheet is intended to collect information about chemical analyses of fuels used fossil fuel burning power plants. Constituents of concern are: mercury, chlorine, fluorine, and metals, such as antimony, beryllium, cadmium, chromium, cobalt, lead, manganese, nickel, and selenium. This spreadsheet is intended to be used for one boiler of one facility but is designed to allow multiple (up to 4) fuel analyses at that specific boiler. This number of analyses would coincide with one boiler where emissions testing for all 4 HAP surrogates were being Fields that are highlighted in down boxes, included. Gray fields are

[FacilityID]_Unit_[BoilerID]_Fuels_Testing.xls (example: 8100_Unit_2_Fuels_Testing.xls).

1. Please enter the EIA Facility Code, Facility Name and Boiler ID of your boiler on the Boiler Information worksheet.

down in the fuel column of the Boiler Information worksheet. If you choose "other", please provide a description of the fuel in the Other Fuel Description column. 4. Please provide the analysis method for each constituent in the Analysis Methods worksheet. For example: "ASTM

5. Please check the Units of Measure tables for HHV, Metals, and Cl/Fl in the Picklist worksheet (orange tab). If the units of measure that you plan to report are not found in the Units of measure table, please fill them in the blank, orange highlighted, cell in each table. This allows you to choose the units of measure in the Fuels Sample Results worksheet. range highlighted cell)

. 7. Provide the Sample Number and Sample Date on the Fuels Sample Results worksheet. You must provide a minimum of 3 composite samples consisting of 3 combined grab samples each, but you are not limited to that number if you have

down boxes to fill in the units ofEIA

Facility Code Facility Name Boiler ID Fuel Type 1

628 Crystal River Unit 1 bitum inousFuel Type 2 Fuel Type 3 Other Fuel DescriptionEIA

Facility Code Facility Name Boiler ID Basis An alyte

628 Crystal River Unit 1 As Received Higher Heating Value 628 Crystal River Unit 1 As Received % Moisture 628 Crystal River Unit 1 As Received % Ash 628 Crystal River Unit 1 As Received % Sulfur 628 Crystal River Unit 1 Dry basis Higher Heating Value 628 Crystal River Unit 1 Dry basis % Ash 628 Crystal River Unit 1 Dry basis % Sulfur 628 Crystal River Unit 1 Dry basis Antim ony 628 Crystal River Unit 1 Dry basis Arsenic 628 Crystal River Unit 1 Dry basis Beryllium 628 Crystal River Unit 1 Dry basis Cadmium 628 Crystal River Unit 1 Dry basis Chlorine 628 Crystal River Unit 1 Dry basis Chromium 628 Crystal River Unit 1 Dry basis Cobalt 628 Crystal River Unit 1 Dry basis Fluorine 628 Crystal River Unit 1 Dry basis Lead 628 Crystal River Unit 1 Dry basis Manganese 628 Crystal River Unit 1 Dry basis Mercury 628 Crystal River Unit 1 Dry basis Nickel 628 Crystal River Unit 1 Dry basis SeleniumAn alysis M ethod for each Analyte

(example: ASTM D5865-04) ASTM D5865 ASTM D3173 ASTM D3174 ASTM D4239 ASTM D5865 ASTM D3174 ASTM D4239 ASTM D6357 ASTM D6357 ASTM D6357 ASTM D6357 ASTM D4208 ASTM D6357 ASTM D6357 ASTM D3761 ASTM D6357 ASTM D6357 ASTM D6722 ASTM D6357 ASTM D4606EIA Facility Code Facility

Name Boiler ID HAPs Test Group 628 Crystal River Unit 1 Mercury and non-mercury

metalic HAPs

Sample Number (minimum of 3 composite samples) Test Start Date (MM/DD/YYYY) Test Stop Date (MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units Run 1 3/23/2010 3/23/2010 12548.00 Btu/lb Run 2 3/23/2010 3/23/2010 12333.00 Btu/lb Run 3 3/24/2010 3/24/2010 12329.00 Btu/lb Fuel Testing ResultsMercury and non-mercury

metalic HAPs

% Moisture (as received) % A sh (as received) % Sulfur (as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Moisture (Dry Basis) % A sh (Dry Basis) 6.82 10.53 0.91 13466 Btu/lb 11.3 6.85 10.86 0.99 13240 Btu/lb 11.66 6.25 11.38 0.89 13151 Btu/lb 12.14% Sulfur

(Dry Basis) Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units An timony (Dry Basis) An timony

Units Arsenic (Dry

Basis) Arsenic Units 0.98 971 ppm 0.05 mg /g 0.96 mg /g 5.68 mg /g 1.06 1088 ppm 0.05 mg /g 1 mg /g 5.41 mg /g 0.95 810 ppm 0.05 mg /g 0.8 mg /g 5.08 mg /gBeryllium

(Dry Basis) Beryllium

Units Cadmium

(Dry Basis) Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) 2.53 mg /g 0.04 mg /g 17.94 mg /g 6.89 mg /g 17.2 2.59 mg /g 0.03 mg /g 18.5 mg /g 8.65 mg /g 17.7 2.25 mg /g 0.03 mg /g 19.24 mg /g 6.25 mg /g 17.29Manganese

Units Nickel (Dry

Basis) Nickel Units Selenium (Dry Basis) Selenium

Units Fluoride

(Dry Basis) Fluoride

Units Cobalt (Dry

Basis) Cobalt Units mg /g 14.23 mg /g 1.24 mg /g 104 ppm 7.78 mg /g mg /g 14.58 mg /g 3.79 mg /g 112 ppm 7.86 mg /g mg /g 24.52 mg /g 3.01 mg /g 134 ppm 7.72 mg /gEIA Facility Code Facility

Name Boiler ID HAPs Test Group 628 Crystal River Unit 1 Acid gas HAPs

Sample Number (minimum of 3 composite samples) Test Start Date (MM/DD/YYYY) Test Stop Date (MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units Run 1 3/24/2010 3/24/2010 12263.00 Btu/lb Run 2 3/25/2010 3/25/2010 12749.00 Btu/lb Run 3 3/25/2010 3/25/2010 12666.00 Btu/lb Fuel Testing Results% Moisture

(as received) % A sh (as received) % Sulfur (as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Moisture (Dry Basis) % A sh (Dry Basis) 6.18 11.9 0.9 13071 Btu/lb 12.68 5.56 9.54 0.82 13500 Btu/lb 10.1 5.36 9.89 0.83 13383 Btu/lb 10.45% Sulfur

(Dry Basis) Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units An timony (Dry Basis) An timony

Units Arsenic (Dry

Basis) Arsenic Units 0.96 987 ppm 0.05 mg /g 0.96 mg /g 6.75 mg /g 0.87 1704 ppm 0.04 mg /g 0.94 mg /g 3.68 mg /g 0.88 1872 ppm 0.03 mg /g 0.86 mg /g 3.3 mg /gBeryllium

(Dry Basis) Beryllium

Units Cadmium

(Dry Basis) Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) 2.1 mg /g 0.03 mg /g 22.38 mg /g 5.52 mg /g 16.79 2.7 mg /g 0.06 mg /g 15.87 mg /g 5.69 mg /g 15.04 2.38 mg /g 0.05 mg /g 14.16 mg /g 5.63 mg /g 13.92Manganese

Units Nickel (Dry

Basis) Nickel Units Selenium (Dry Basis) Selenium

Units Fluoride

(Dry Basis) Fluoride

Units Cobalt (Dry

Basis) Cobalt Units mg /g 14.36 mg /g 4.51 mg /g 104 ppm 7.54 mg /g mg /g 12.76 mg /g 3.06 mg /g 69 ppm 6.76 mg /g mg /g 10.51 mg /g 3.4 mg /g 50 ppm 6.21 mg /gEIA Facility Code Facility

Name Boiler ID HAPs Test Group 628 Crystal River Unit 1 Non-dioxin/furan organic HAPs

Sample Number (minimum of 3 composite samples) Test Start Date (MM/DD/YYYY) Test Stop Date (MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units Run 1 3/26/2010 3/26/2010 12255.00 Btu/lb Run 2 3/26/2010 3/26/2010 12432.00 Btu/lb Run 3 3/26/2010 3/26/2010 12494.00 Btu/lb Fuel Testing ResultsNon-dioxin/furan organic HAPs

% Moisture (as received) % A sh (as received) % Sulfur (as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Moisture (Dry Basis) % A sh (Dry Basis) 6.8 11.72 0.96 13149 Btu/lb 11.72 6.62 10.94 0.91 13313 Btu/lb 10.94 6.53 10.22 0.87 13367 Btu/lb 10.22% Sulfur

(Dry Basis) Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units An timony (Dry Basis) An timony

Units Arsenic (Dry

Basis) Arsenic Units 1.03 1890 ppm 0.06 mg /g 0.9 mg /g 4.9 mg /g 0.97 1505 ppm 0.05 mg /g 0.91 mg /g 5.22 mg /g 0.93 1330 ppm 0.04 mg /g 0.82 mg /g 4.51 mg /gBeryllium

(Dry Basis) Beryllium

Units Cadmium

(Dry Basis) Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis) 2.46 mg /g 0.02 mg /g 17.54 mg /g 5.7 mg /g 12.47 2.51 mg /g 0.03 mg /g 18.37 mg /g 5.66 mg /g 15.24 2.42 mg /g 0.01 mg /g 17.36 mg /g 7.74 mg /g 15.13Manganese

Units Nickel (Dry

Basis) Nickel Units Selenium (Dry Basis) Selenium

Units Fluoride

(Dry Basis) Fluoride

Units Cobalt (Dry

Basis) Cobalt Units mg /g 14.62 mg /g 4.52 mg /g 69 ppm 10.15 mg /g mg /g 14.91 mg /g 1.97 mg /g 77 ppm 9.24 mg /g mg /g 13.2 mg /g 2.72 mg /g 69 ppm 7.86 mg /gEIA Facility Code Facility

Name Boiler ID HAPs Test Group 628 Crystal River Unit 1

Sample Number (minimum of 3 composite samples) Test Start Date (MM/DD/YYYY) Test Stop Date (MM/DD/YYYY) Higher Heating Value (HHV) (as received) HHV Units Fuel Testing Results% Moisture

(as received) % A sh (as received) % Sulfur (as received) Higher

Heating Value (HHV) (Dry Basis) HHV Units % Moisture (Dry Basis) % A sh (Dry Basis)% Sulfur

(Dry Basis) Chlorine

(Dry Basis) Chlorine

Units Mercury

(Dry Basis) Mercury

Units An timony (Dry Basis) An timony

Units Arsenic (Dry

Basis) Arsenic UnitsBeryllium

(Dry Basis) Beryllium

Units Cadmium

(Dry Basis) Cadmium

Units Chromium

(Dry Basis) Chromium

Units Lead (Dry

Basis) Lead Units Manganese (Dry Basis)Manganese

Units Nickel (Dry

Basis) Nickel Units Selenium (Dry Basis) Selenium

Units Fluoride

(Dry Basis) Fluoride

Units Cobalt (Dry

Basis) Cobalt UnitsUnits of Measure Tables: Please do not modify these tables, except to add your own unit of measure to the

Fuel Units of Measure - HHV anthracite Btu/lb bitum inous Btu/gallon subbituminous lignite coal refuse (culm or gob) No.2 Fuel Oil (distillate) No.6 Fuel Oil (residual or bunker C) Units of Measure - Metals sy nfuel mg /g petroleum coke μg/g other mg /KgUnits of Measure Tables: Please do not modify these tables, except to add your own unit of measure to the orangehightlighted cell, if necessary

.

Units of Measure - Cl, Fl % ppm