2540.PM-BWM0347 Rey.112Q11 **~pennsylvania** - OEIWitHEHI" Of' ENVIRONMENTAI.PRO'!ECTION COMMONWEALTH
OF PENNSYLVANIA **DEPAR~ENTOFE~RONMENTALPROTECTION** BUREAU OF WASTE MANAGEMENT FORM26R CHEMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT BY THE GENERA TOR This fonn must be fully and accurately completed.

must typed or legibly printed In the spaces **pro~ded.**

If additional space is necessary, identify each attached sheet as Fonn 26R. reference the item number and Identify the date prepared. The date on attached sheets needs to match the date noted below. Reference 287.54 c. Physical Appearance
County Indiana Number of Solid or Uquid Phases of Separation Une2

10# No Describe each phase of **separation.~~---------------;** - 1 -2540-PM-BWII0347
Rev 112011 c. d. Address Une 1 Address Une 1 Address City Stai8 ZIP Municipality Title Phone Address Une 1 Address Une 1 Address City State ZIP Municipality c. Facility Title Phone

or 181 gal d. waste shipped to processing or 0 cuyd
0 gal County Indiana 0 {check one) Email Address UIIII'YIUI,GI year. 0 lb 0 ton {check one) 0 ton {check one) -2
-254Q:PM:swMb347 Rev.112o11 I certify, under penalty of law, that

I have personally examined and am familiar with the Information submitted
In this Annual Report and all attached documents and that based upon my Inquiry of those Individuals Immediately responsible for obtaining the Information,

I verify that the submitted Information

Is true, accurate and complete to the best of my knowledge.

I understand that the submission
of false Information herein is made subject to the penalties of 18 Pa. C.S. §4904, relating to unsworn falsification
to authorities, which Include fine and Imprisonment Check the following,

if applicable: D

I certify the information required In Section B-1, General Properties was supplied to the Department for the year _and has not changed. Form Submitted:

D Form 26R 0 Other (specify) Date Submitted: D

I certify the information required In Section B-2, Chemical Analysis was supplied to the Department for the year _and has not changed. Form Submitted:

0 Form 26R D Other <specify> Date Submitted: D

I certify the Information required
In Section B-3, Process Description and Schematic, was supplied to the Department for the year_ and has not changed. Form Submitted:

0 Form 26R Date Submitted: Name of Responsible Official Bernhardt Kissel Signature

0 Other (specify)
Date 2-28-11 -3-i· February
9, 2011 Form 26R: Section 83a WASTE GENERATION PROCESS Pit Water "Drill Fluids• Remnant drill fluids are generated

in the well bore during the penetration
of the drill stem as it intercepts both ground water and formation fluids. These fluids are brought to the surface along with the drill cuttings, pieces of the intercepted rock strata, by the return flow system of the drilling process. Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. Fluids are currently stored in closed containers
to be processed for reuse. Flowback: "Fracing Fluid" Flowback
is produced from all fluids that flow back to surface during the "hydrofracing" process which occurs under pressure and results in the setting of a propant within the formation fractures. Production Fluid "Brine" During the production
of natural gas, formation pressures bring remnant frac fluids, during the initial production phase, and formation fluids to the surface along with produced gas.February
8, 2011 Form 26R: Section B2b WASTE SAMPLING METHODS

j. All samples were obtained as grab type samples with a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are composited within the storage production tank or tank battery at each well site where gas production

is occurring. Each automatic
or manual ejection of formation fluids is deposited into the tank{s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP permitted waste disposal facilities on different schedules determined by individual well characteristics. Grab samples of the composited fluids were obtained at the represented well pads directly frorr- the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. **Sa~ples** were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives,
as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. Flowback samples were composited
to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion
of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives,
as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process at various times and combined into a composite sample for analyses at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites.

In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concer,ns usually limited the randomness
of the composite sample and composite grid sample positions were varied to the extent possible. Pit water (drill fluid) is currently discharged
to closed containment and is re-conditioned and reused from well to well.February
9, 2011 Form 26R: Section 81e GENERATOR KNOWLEDGE

I• All Form 26R Waste Forms have been compiled, and Mure testing has been scheduled,
to obtain samples of each waste stream on a PAD by PAD basis. Sample analyses will be conducted every
5 years for each waste stream unless the process that generates any particular waste stream is substantially altered. Attached analytical results for this waste stream have been obtained from a similar waste stream producing waste from the same geologic formation as this 26R Report. Additionally, the mud mixtures, chemical formulations and drilling process utilized at this well PAD are substantially the same as those utilized at the well where the attached waste analyticals were generated.Well I. D.# (various) Well I.D.# . (various) '\/

**~** -0- -y- **/~,** /1' I\ I \ / Well I. D.# (various) \ I ::b::: \ I // l \ I / \ I // \ I // . . \ I / Well I. D.# (various) \ I // \\/ / \ I / -o- / " r---- / **~o~--** ( . **~** CJ "/ **Fl"'"'~~~; e>ft'oVo,~**  Mobile Tank Truck **~f'"o~·ho-'\ Ocu1\\~~~** 

- COUNTYB

COUNTY A **\tM~S** :· (Jls brine (TYP.)

_ s:: Road Transport ----- Landfill or

0 **~** UJ :r: (.) CJ') z 0 **~** t:2 0 Cl. (/) **·~** 1- **~~** Ill !!.l C) ....... - **Tr~+~U\+** 'Pl(,V\t . I

LLI **~ ~**  **~** 5 **~~** ote: Process producing waste: Gas well produced fluids (brines) are typically produced in conjuction with natural gas. These fluids are brought to the surface utilizing either ,, mechanical or physical lift procedur . es.

**~** I! **~ :S~**  **~** i5 i ;;!

**~**u

# . . .·----ENVIRONMENTALSERVICE I 

# LABORATORIES,_INC. SAMPLEREQUEST

# &CHAIN OFCUSTODY PAGE
__ OF 

# --+- HEADQUARTERS: 1803 Philadelphia St. Indiana, PA 15701 (724) 463-TEST (724) 465-4209 

# ~ SOUTHERN DIVISION: 1276 BentteyvHie Road Van Voorhis, PA 15366 (724) 258-TEST 

# D REC'D NOV -4 

# 2009 (724) 258-8376 

# FORINTERNAL LABORATORYUSEONLY Sample Identification 

# I ESL# 

# lf,qJ{,gl/31



# H-l **t9~tD**

TRIP BLANK 

# 09

**~1~1/** Composite SampleType

THE UNDERSIGNED PURCHASER HEREBYAGREES TO PAY SERVICE CHARGES ON ACCOUNTS OVER31 DAYSOLD
.

# Grab Time 

# ' lj Cj 

# 15 

# c:;

**,,~**

1
.THESE SERVICE CHARGES WILLACCRUE ATTHE RATE OF 1 112% PER MONTH (11% PERANNUMOR THE MAXIMUMALLOWED BY LAW
.) 2
.THE UNDERSIGNED PURCHASER AGREES TO PAY, INTHE EVENT HISACCOUNT BECOMES DEUNQUENTAND ISTURNEDOVERTOAtN

ATTORNEY FOR COLLECTION, REASONABLE ATTORNEY'S FEES PLUSALL COURTANDATTENDANTCOLLECTIONCOSTS.



# ~ **to/3}~** 9..i'$".-49H? Matrix 

# I


# ww I 

# ww I 

# ww I 

# ww I 

# ww I 

# ww I 

# ww I 

# ww I 

# ww I Water 

# I # ofContainers 

# I ContainerType Preurvalive 

# 1 

# I Plastic Liter none 

# 2 

# I Plastic Liter none 

# 1 

# I Plastic Liter HN03 

# 1 

# I Plastic Liter H:z$04 

# (2) 1000 ml 

# I Plastic Liter 

# (3) 500 ml HN03 

# 1 

# I AmberGlass L HCI 

# 1 

# I AmberGlass

# L H2S04 

# 2 

# I AmberVOAVials none 

# 2 

# I AmberVOAVials HCI 

# 2 

# I f.mberVOAVials HCI ProjectNotes:

Company/Name:



# Samp1Bi:{Si9na~ ,/ /'!:ate/ Time ,....



# /~e.. 

# - -e>



# (l(~~~ I" 0-

# g

# -oc [

**\~ ~**  Address:



# \~sRelinquished 

# By: (Signature) 

# Date/ Time CHAIN OFCUSTODYSEAL BROKEN: Yes _No ,BY. (Sign.:tur;11 

# '-ID
__ ./1 

# }JateJ Time 

# N

# '-1.3

**~~ ~**  /tJ-rf"'r·tJ9 Received By. 

# (SignaiJII) 

# 7 Date/ Tlme Contact Person:



# ~R~ece--I~~~~By.-.~(S~Ig-~~~~-.~,--------------~0-at-e~/~Tl~m-e----------~~Phone

**:** Fax: 

# 8

- .I


# I Analysis Requested pH, SC, Chortde, Sulfate, / Alkalinity, Acidity, Bromide TSS, TDS, Dissolved Iron, Boron, BOO, MBAS Surfactants AI, As, Ba, Be, Cd, Cr, Co, Cu. Fe, Pb, Mg, Mn, Hg, Ni, Se, Ag, Sr, Zn, Li, 

# Na, Ca, Mo, Hardnfss Nitrate+Nitrite, TKN, Ammonia, COO GrossAlpha, Gross Beta Radium 226, Radium 228 Thorium, Uranium

011 &Grease 

# I Total Phenolics 

# I Ethylene Glycol 

# I Benzene, Toluene 

# I Benzene,Toluene



# XTO ENERGY 395 AIRPORT ROAD INDIANA, PA 15701
MR. MIKE HAHN (724) 349-0600 (724) 349-8489

,, II



# '9t/,~

# I Lls:i\1\iig(lN!\iii=NTA

-LII: -· .. 1t' ...... **~** ..........

.,. ••

' SERVICE LABORATORIES/ INC. 1803 Philadelphia Street Indiana. PA 15 701 (724)-463-TEST
FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: XTOEnergy 395 Airport Road Indiana, PA 15701 10/812009 9:15AM 10/8/2009

2 : 42 PM 10/30/2009 Analyte Acidity to pH=8.3 Alkalinity
to pH=4.5 Biological Oxygen Demand 05 Chemical Oxygen Demand Ammonia
as N I Distilled Bromide Chloride Kjeldahl Nitrogen as N pH(SM) Sulfate ASTM Total Nitrate+ Nitrite as N Aluminum

- ICP Arsenic-ICP Barium- ICP Beryllium- ICP Boron Cadmium

- **I~P** Calcium- ICP Chromium- ICP Cobalt- ICP Copper- ICP Hardness Report of Analysis SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result

09 29510 Waste Water Grab NEW (Client) Ha118431
H ? **~~** Units

. 7 :;rt-k. Method RPL BF 10/11/2009 ND mg/1 as CaC03 SM2310B

2 JS 10/1212009
175 mg/1 as CaC03 SM2320B

20 szc 10/1212009 **6~.7** mg/1 SM5210B
2.0 MAD 10/15/2009 1002.5 mg/1 SM5220D 500

. 0 MAD 10/1912009 62.73 mg/1 )M4500NH3B

& I 1.00 AID 10121/2009 554.00 mg/1 Dl246-99 20.00 BF 10/09/2009 51663.1 mg/1 SM4500ClC

1.0 MAD

1 0/19/2{)09 33.1 mg/1 SM4500Norg-C,D

5 . 5 LL 10/0812009 6.60
su SM4500H-B

0 . 01 LMB 10/12/2009 ND mg/1 D516-02

5 AJD 10/19/2009 ND mg/1 SM4500N03E 0.05 GJT 1012112009 ND mg/1 200.7/6010 1.000 GJT 10122/2009 ND mg/1 200.7/6010 1.000 GJT 1012112009 388.800 mg/1 200.7/6010 0.500 GJT 1012212009 ND mg/1 200.7/6010 0.500 MAD 10126/2009 15.00 mg/1 SM4500B-B 12.50 GJT 10122/2009 ND mg/1

· 200.7/6010

0
. 500 GJT 10/22/2009 4248.800 mg/1 200.7/6010 50.000 GJT 1012112009 ND mg/1 200.7/6010 0.500 GJT 1012112009 ND mg/1 200.7/6010

0 . 500 GJT 10/21/2009 ND mg/1 200.7/6010 0.500 I GJT ll0/23/20091 12192 mg/1 SM2340B Comments: Radiologicals done by Benchmark Analytical

IND=Not Detected Note: DEP Certification
#s 32-00382 Data Qualffiers

: 0 = The reported value is from dilution

. E = Estimated value.

S = Surrogate out of control limits. R = Sample received out of holding time.
H = Sample analyzed out of holding time

. C = Sample received
in incorrect container

. B = Analyte was detected

in both sample and methods blank

. x = User defined data qualifier

.---- ___ .-..__ -- ------- ;-

I ii:'l JN 1\111-

I A =--
**~~~** ... ··-.......--

.. •:a --N--

I: - N v

I .... ....,...

I •
I 1f
I -

• •• ..L SERVICE LABORATORIES, INC. 1803 Philadelphia Street Indiana, PA 15701 (724)-463-TEST
FAX (724)-465-4209 Report of Analysis Name: Sample Start Date: Receipt Date: Report Date: XTOEnergy 395 Airport Road Indiana, PA 15701 10/8/2009 9:15AM 10/8/2009 2:42 PM 10/30/2009 Analyte Iron- ICP Iron,Dissolved-ICP Lead-ICP Lithium

- ICP Magnesium-ICP Manganese

- ICP Mercury Molybedenum

- ICP Nickel- ICP Selenium-ICP Silver-ICP Sodium- ICP Strontium

- ICP Zinc- ICP Detergents, MBAS Ethylene Glycol Oil and Grease

- HEM Phenolics,
as Phenol Specific Conductance Total Dissolved Solids (TDS) Total Suspended Solids Radiologicals
Analyst GJT GJT GJT GJT GJT GJT DMM GJT GJT GJT GJT GJT GJT GJT TL **~etPeak** CLM MAD LL CLM ALD enchmru Comments: Radiologicals done by Benchmark Analytical Note: DEP Certification
#s 32-00382
Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID: Analysis Sample Date Result 10/21/2009 38.600 10/21/2009 21.200 10/21/2009 ND 10/22/2009 72.500 10/23/2009 384.400 10/21/2009 4.000 10/15/2009 ND 10/21/2009 ND 10/21/2009 ND 10/21/2009 ND 10/22/2009 ND 10/22/2009 26743.000 10/23/2009 720.700 10/21/2009 ND 10/09/2009 0.614 10/20/2009 <25.000 ' 1 0120/2009 ND 10/13/2009 ND 10/08/2009 112400 10/14/2009 104800 10/13/2009 472 10/30/2009

*
09 29510 Waste Water Grab NEW (Client) Hall8431
H Units mg/1 mg/1 mg/1 mg/1 mg/1- mg/1 mg/1 mgll mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mglkg mg/1 mg/1 uS/em mg/1 mg/1 mg/1 Data Qualifiers:

0 = The reported value is from dilution.

E = Estimated value.

S = Surrogate out of control limits

. Method RPL 200.7/6010 1.000 200.7/6010 1.000 200.7/6010 0.500 200.7/6010 50.000 200.7/6010 50.000 200

. 7/6010

0 . 500 245.1 0.0002 200.7/6010 0.500 200.7/6010 0.500 200.7/6010 1.000 200.7/6010 0.500 200.7/6010 500.000 200.7/6010 1.000 200.7/6010 0.500 SM5540C 0.200 300.0M 25.000 1664A 5.0 420.1 0.500 SM 2510B

l SM2540C

25 SM2540D

5 RAD-CTDHS 0.000 !ND=Not Detected R = Sample received out of hold

i ng time.
H = Sample analyzed out of holding time

. C = Sample received
in incorrect container

. B = Analyte was detected
in both sample and methods blank

. x = User defined data qualifier.

Page 2 of&: N\/i **~nN** i\ • j;; **t~T** 4. e ..

I ....... ,....., ........ IJ ....... ,L SERVICE LABORATORIES, INC. 1803 Philadelphia Street, Indiana, PA 15 701 (724)-463-TEST
FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: 1) Benzene 47) Toluene XTOEnergy 395 Airport Road Indiana, PA 15701 10/812009 9:15AM 10/812009 2:42PM 10/30/2009 Analyte Report of Analysis Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO 10/09/2009 26.40 RO 10/0912009 ND Comments: Radiologicals done by Benchmark Analytical . **~** DEP Certification
#s 32-00382

09 29510 Waste Water Grab NEW (Client) Hall8431
H Units ug!L ugiL Data Qualifiers

: D = The reported value is from dilution.

E = Estimated value

. S = Surrogate out of control limits

. Method RPL 624/8260B 20.00 624/8260B 20.00 jND=Not Detected R = Sample received out of holding time

. H = Sample analyzed out of holding time

. C = Sample received
in incorrect container

. B = Analyte was detected
in both sample and methods blank.

X = User defined data qualifier.6 Vf V Y
f .. V YV 4V, .. ..., .&

. ... 4 .. Y,&. VV

t "'X..,.A.V "'X , . LAS 10 #: 39-00401 SEND OATATO: NAME: Mike Moyer BENCHMARK ANALYTICS, INC

. 4777 Saucon Creek Road Center Valley, PA 18034-9004 PHONE (610) 974-8100 FPJ<(610)974:8104 COMPANY: EnVIronmental Service laboratories, Inc ADDRESS: 1803 Philadelphia
St PHONE: FAA: Indiana, PA 15701 (724) 463-8378 (724) 465-4209 09 29350 & 09 29510 RECEIVED FOR LAB BY: DMB TEST REPORT DATE: 10/12fl009 10:00 Work Order: 09101656 WO#: 09101656 PAGE: 2of2 PO#: DAS1 0092009 PWSID# Page2 of2 SAMPLE: 09 29510

Lab 10: 09101656-002E Grab SAMPLED BY: David A. Stile Sampte TII'M 1010812009 9:15 BDYit **~** MOA Units Thorium

< 0
. 0131
:t: 0.00

0 mgA. **~** EPA200.8 SAMPlE: 09 29510

Lab ID: 09101656-002A SAMPLED BY: David A. Stile Sample Time 1010812009 9:15 !Hi Result **~** Y2A Units **~** Gross Alpha 1971
;t 221.3 746.9 pCVL EPA900.0 Gross Beta 228S

;t 140.7 682.4 pClll EPA900.0 **~** aDil!)til& Start Ana!vsls End Ana!vst

• **1011~** 8:30 10/16109 GSR-CV --- Grab **~** Analysis Stat\ Ana!vG!s End **~** 10/13109 8:50 10116109 BP$-CV 10/13109 8:50 10115109 BP5-CV --------

· · SAMPlE 09 29510

Lab 10: 09101656-002B Grab SAMPLED BY: Da\lld A. stile Sample Time 1010812009 9:15 B.wt!l Yl!9!!!. Radlum-226 464.9

;I; 15

. 84 ---

· ·---- SAMPLE: 09 29510

g 59.4 Units MdK!!! pCill EPA 903.0 --- LabiD: **09101~** SAMPLED BY: Davicl A. Stile SampleTme 10108120099:15 I@ Radium-228 **~** lJ.!ls;!d. MQ6 l.!!l!t! 148.7

:t: 11.10 1-4.16 pCitL EPA904.0 f&. 6nalys!s Start Matv* Encl **~** 1011610911:15 10129109 BH-CV **Gr.~b** ,Mg. Analysis Start Ana!ysi9 End **~a:** 10121109 **8:0~** 10/27109 NLB-CV ··--·

· ----

·· ·-----· --··

·-

. . .

· ·· - SAMPLE: 09 29510

Lab 10: 09101658-0020 Grab SAMPLED BY: David A. Stile Sample Tme 1010812009 9:15 **~** Uranium **Ur.~nlum** Result < 13.13 <8.93 **~** t 0.00 :1: 0.00 MDA !.!nl1§. 0 **~II..** MS 0 pCi/L **~** EPA200.8 EPA200.8 MCL Anetvsis Start AnalYsis End **~** 30 10/1910910:00 10123109 GSR..CV 10/19/09 10:00 10123109 GSR-CV ·---

.. ·-· REMARKS

: The **e~bove** test procedures meet all the requirements

of NELAC and relate only to these samples. • CV =Benchmark **Ane~lytics,** Inc
. Center Valley, PA
: SA"" Benchmark **Ane~lytics,** Inc
. Sayre, PA MS Umit of Cletectlon increased dve to matrix

i nterference 01nd spike recovery data MANAGER **~trkL** · · --·

.

**~**
DATE: 1013012009i= NV• **~tnN** lJi I= NT A i - I 'W Y 1 ..... ......,...

I 'tl I Y I - I 'tl II **~-** SERVICE LABORATORIES, INC. 1803 Philadelphia Street, Indiana, PA 15 70
l [724)-463-TEST
FAX (724)-465-4209 Name: XTOEnergy Sample Start Date: 395 Airport Road Indiana, PA 15701 10/8/2009 10/8/2009 2:42PM 10/12/2009 Receipt Date: Report Date: Analyte 1) Benzene 47) Toluene Comments: DEP Certification
#s 32-00382 Report of Analysis Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO 10/0912009 ND RO 10/09/2009 ND

09 29511 Waste Water Grab NEW (Client) Trip Blank Units ug/L ug!L Method MDL 624/8260B 1.00 624/8260B 1.00 IND=Not Detected Page
1 of 1COMMONWEAL
1M OF PENNSYLVANIA DEPARTMENT
OF ENVIRONMENTAL PROTECTION BUREAU OF WASTE MANAGEMENT FORM26R CHEMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT BY THE GENERA TOR must accurately completed. All must be typed or legibly printed in the spaces provided.

If additional space Is necessary, Identify each attached sheet as Fonn 26R, refenmce the item number and Identify the date prepared. The date on attached sheets needs to match the date noted below. General Reference 287.54 Date Prepared/Revised 219111 c.

State PA First Name Ben Company Mailing Address Une Zip+4 15701 Ml opaque white/orange Odor Number of Solid or Uquld Phases of Separation
EPA Generator Describe each phase **ofseparation.~~---------------1** a.

- 1 -2540-PM-BWM0347 Rev.1/2011 c. Address Une 1 Address Une 1 Address City State ZIP Municipality Phone d. waste shipped to processing or a. b. Facility Name Address Une 1 Address Une 1 Address City State ZIP Municipality c. Title

0 cuyd **~** gal D lb processing or disposal -2- County Indiana steve@pabrine.com year. 0 ton (check one) being utilized. County (check one) Oton (check one)2&40=PM=BWM0347 Rev. 112011 I certify, under penalty of law, that

I have personally eXamined and am familiar with the information submitted
In this Annual Report and all attached documents and that based upon my Inquiry of those lndMduals Immediately responsible for obtaining the Information,

I verify that the submitted Information

Is true, accurate and complete to the best of my knowledge.

I understand that the submission
of false Information herein is made subject to the penalties of 18 Pa. C.S. §4904, relating to unsworn falsification
to authorities; which Include fine and Imprisonment Check the following,

If applicable: 0

I certify the Information required
In Section B-1, General Properties was supplied to the Deparbnent for the year __ and has not changed. Form Submitted:

D Form 26R 0 Other (specify) Date Submitted: 0

I certify the information required In Section B-2, Chemical Analysis was supplied to the Deparbnent for the year _and has not changed. Form Submitted:

0 Form26R 0 Other (specify) Date Submitted: 0

I certify the information required In Section B-3, Process Description and Schematic, was supplied to the Deparbnent for the year __ and has not changed. Form Submitted:

0 Form 26R 0 Other (specify) Date Submitted: Name of Responsible Official Bernhardt Kissel Signature

Date 2-28-11 -3-February
9, 2011 Form 26R: Section B1e GENERA TOR KNOWLEDGE All Form 26R Waste Forms have been compiled, and future testing has been scheduled,
to obtain samples of each waste stream on a PAD by PAD basis. Sample analyses will be conducted every
5 years for each waste stream unless the process that generates any particular waste stream is substantially altered. Attached analytical results for this waste stream have been obtained from a similar waste stream producing waste from the same geologic formation as this 26R Report. Additionally, the mud mixtures, chemical formulations and drilling process utilized at this well PAD are substantially the same as those utilized at the well where the attached waste analyticals were generated.February
8, 2011 Form 26R: Section 82b WASTE SAMPLING METHODS

I · All samples were obtained as grab type samples with a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are composited within the storage production tank or tank battery at each well site where gas production

is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tan
- k trucks for disposal at various PaDEP permitted waste disposal facilities on different schedules determined by individual well characteristics. Grab samples of the composited fluids were obtained at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. Samples were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives,
as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. Flowback samples were composited
to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion
of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives,
as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process at various times and combined into a composite sample for analyses at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites.

In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness
of the composite sample and cqmposite grid sample positions were varied to the extent possible. Pit water (drill fluid) is currently discharged
to closed containment and is re-conditioned and reused from well to well.I • February
9, 2011 Fonn 26R: Section B3a WASTE GENERATION PROCESS Pit Water "Drill Fluids" Remnant drill fluids are generated

in the well bore during the penetration
of the drill stem as it intercepts both ground water and fonnation fluids. These fluids are brought to the surface along with the drill cuttings, pieces of the intercepted rock strata, by the return flow system of the drilling process. Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. Fluids are currently stored in closed containers to be processed for reuse. Flowback: "Fracing Fluid" Flowback
is produced from all fluids that flow back to surface during the "hydrofracing" process which occurs under pressure and results in the setting of a propant within the fonnation fractures. Production Fluid "Brine" During the production
of natural gas, formation pressures bring remnant frac fluids, during the initial production phase, and fonnation fluids to the surface along with produced gas.-

Well I. D.# (various) '\/ -a- /1' \ \ \ \ \ \ \ \ COUNTYB ote: .

\ \ Process producing waste: Gas well produced fluids (brines) are typically produced" in conjuction wi.th natural gas. These fluids are brought to the surface utilizing either mechanical or physical lift procedur . es.

/ /

COUNTY A Well I. D.# (various) \ I .::o/ /I**I~** / / / / / Mobile Tank Truck _ s Road Transport

(.')**~** w :c (..) en z 0**~** 1-**~** 0 0.. en z**~** 1-**~illf ~~~I**  ii .! t**~**

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# •w• **~-** 

# • •

# ENVIRONMENTALSERVICE SAMPLEREQUEST

# &CHAINOFCUSTODY

**LABORATORIES~**

# INC. PAGE __ OF 1--



# ... HEADQUARTERS:



# ~ SOUTHERN DIVISION: 

# 8 1803 Philadelphia St
. 1276 Bentleyville Road 

# D Indiana, PA 15701 Van Voorhis, PA 15388 

# REC'D NOV -4 

# 2009 - ..I 

# (724) 463-TEST (724) 258-TEST (724) 465-4209 (724) 258-8376 

# .. FORINTERNAL LABORATORYUSEONLY 

# SampleType Sample Identification ESL# Composite Grab Matrix 

# # ofContainers ContainerType Analysis Requested Date on/off 

# Time on/off 

# Date Time · Preservative 

# 11141/,J?l/31 

# fl. 

# 0!9:



# ~!()

# ---- ----- /0 /__./A \foNJ Plastic Liter pH,SC,Chorlde, Sulfate, /


# ------ ------ t:'ft

# IS 1

**'~L""'** 

# none Alkalinity, Acidity, Bromide 

# ----- -----

**lrt>~J:.**

# ,.,

**1~** \foNJ Plastic Uter TSS, TDS, Dissolved Iron, 

# --- ----- 1t:J

**I~** 2 none Boron, BOD,MBAS Surfactants



# ~ 

# ------ 1/o«J:. \foNJ Plastic Liter AI, 

# As, Sa, Be, Cd, Cr, Co, Cu, Fe, Pb, Mg,


# ----- ------ It!>



# ~

# ' 1.5 1 HN03 

# Mn, Hg, Nl, Se, Ag, Sr, Zn, 

# Li, Na, Ca, Mo, Hardress 

# ----- ------

**~~**17 

# '1 

# t5 \foNJ Plastic Liter 

# ----- ------ 10 1 Nitrate+Nitrite, TKN,Ammonia, COD H:z$04 

# ---- ------

**v~tk** (2) 1000 mL Plastic Liter GrossAlpha, Gross Beta



# ~ **~ 'lo~**  

# '

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# !5o HN03 Thorium, Uranium 

# ----- ------- \foNJ AmberGlass L 

# ---- ----- 10 

# o8 Cj 

# 15 1 Oil &Grease HCI



# ----- ------ btrk \foNJ 

# 1 AmberGlass L 

# ----- ------ /0



# ~ 

# 1:1> H2S04 Total Phenolics


# ----- ----- 'b8k 

# ., 1'5 \foNJ 

# 2 AmberVOAVials



# ----- ------ to none Ethylene Glycol



# . 

# --- ----- 1ey

# 08/a

**1~** 

# ,, \foNJ 

# 2 AmberVOAVials 

# '

**~** 

# -------- HCI Benzene, Toluene TRIP BLANK 

# 09 

# ---- ------- ::::::::::-

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# 2 :AmberVOAVials 

# '215"'11

# ----- ------- HCI Benzene, Toluene THE UNOERSIGNEO PURCHASER HEREBYAGREES TO PAY SERVICE CHARGES ONACCOUNTSOVER31 llo'YSOLD
. 

# ProjectNotes: 1
.THESE SERVICE CHARGES WILL ACCRUE ATTHE RATE OF 1 1/2% PER MONTH (18% PERANNUM ORTHE MAXIMUMALLOWED BYlAW
.) 2
.THE UNDERSIGNED PURCHASERAGREES TO PAY
. INTHE EVENT HISACCOUNT BECOMES DEUNQUENTAND ISTURNEDOVERTOANY

ATTORNEY FOR COLLECTION, REASONABLE ATTORNEY'S FEES PLUSALL COURTANDATTENDANT COLLECTIONCOSTS
. 

# A'_/



# .J~-/



# tok/~ 9..

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# XTO ENERGY

**Sampl~** 

# By: (Signature) 

# Mate/Tlme



# ~-~ **ILf\~~**



# '( 

# a d.#_

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# . 

# {o-K-ocr Address: 

# 395AIRPORT ROAD

**Relinquish~y:** (SignatureJ.. 

# Date/ Time



# ~cslgnU 

# r-1£ .date/Tlme 

# Nl/3 INDIANA, PA 15701



# 1?'~ lo-g-cq 

# (Lf\



# ~s- 

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# / /)-tf"',-t5J

# 7 Relinquished By: (Signature) 

# Date/ Tlme ltecelved By: cslgn811h.) 

# I Date/ Tlme 

# r. Contact Person: 

# MR. MIKE HAHN Relinquished

# By: (Signature) 

# Date/ Time Received By: (Sip!'") 

# Date/ Tlme Phone: 

# (724) 349-0600 

# ' CHAIN OF CUSTODYSEAL BROKEN: Yes No 

# Fax: (724) 349-8489


# - I

# I. II



# '9'£~/ 

# IJs: N\ii ti£-lt"\1 i\li &=NT A
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I 'tl II .... SERVICE LABORATORIES, INC. 1803 Philadelphia Street Indiana, PA 15 701 (724)-463-TEST
FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: XTOEnergy 395 Airport Road Indiana, P A 1570 1 10/8/2009 9:15AM 10/8/2009 2:42 PM l0/30/2009 Analyte Acidity to pH=8.3 Alkalinity
to pH=4.5 Biological Oxygen Demand 05 Chemical Oxygen Demand Ammonia
as N I Distilled Bromide Chloride Kjeldahl Nitrogen as N pH(SM) SulfateASTM Total Nitrate+ Nitrite as N Aluminum

- ICP Arsenic-ICP Barium- ICP Beryllium

- ICP Boron Cadmium

- ICP Calcium

- ICP Chromium- ICP Cobalt- ICP Copper- ICP Hardness Report of Analysis Analyst Analysis Date BF 10/11/2009 IS 10/1212009 szc 10/12/2009 MAD 10/15/2009 MAD 10/19/2009 AID 10/21/2009 BF 10/09/2009 MAD 10/19/2009 LL 10/08/2009 LMB 10/12/2009 AID 10/1912009 GJT 10/21/2009 GJT 10/22/2009 GJT 10/21/2009 GJT 10/22/2009 MAD 10/26/2009 GJT 10/22/2009 GJT 10/22/2009 GJT 10/21/2009 GJT 10/21/2009 GJT 10/21/2009 GJT 10/23/2009 SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Sample Result

09 29510 Waste Water Grab NEW (Client) Hall8431
H ? ;n.tc 4- Units Method ND mgfl as CaC03 SM2310B 175 mgfl as CaC03 SM2320B 68.7 mgfl SM5210B 1002.5 mgfl SM5220D 62.73 mgfl sM4500NH3B&tt 554.00 mgfl D1246-99 51663.1 mg/1 SM4500ClC 33.1 mg/1 SM4500Norg-C,D 6.60 su SM4500H-B ND mg/1 0516-02 ND mg/1 SM4500N03E ND mg/1 200.7/6010 ND mg/1 200.7/6010 388.800 mg/1 200.7/6010 ND mg/1 **200.7/601~** 15.00 mg/1 SM4500B-B ND mg/1

. 200.7/6010 4248.800 mg/1 200.7/6010 ND mg/1 200.7/6010 ND mg/1 200.7/6010 ND mg/1 200.7/6010 12192 mg/1 SM2340B RPL 2 20 2.0 500.0 1.00 20.00 1.0 5.5 0.01 5 0.05 1.000 1.000 0.500 0.500 12.50 0.500 50.000 0.500 0.500 0.500 1 Comments: Radio1ogicals done by Benchmark Analytical

JND=Not Detected Note: DEP Certification
#s 32-00382 Data Qualifiers

: D = The reported value is from dilution.

E "" Estimated value.

S = Surrogate out of control limits. R = Sample received out of holding time.
H = Sample analyzed out of holding time.
C = Sample received
in incorrect container

. B = Analyte was detected
in both sample and methods blank.
X = User defined data qualifier.

Page 1 of 3a; N\ii wi-1Ni\Ji i=NT 41 -
I 11 1r I 1'- **~**

I 11 I WI -I 11 II ... SERVICE LABORATORIES, INC. 1803 Philadelphia Street Indiana, PA 15 701 (724)-463-TEST
FAX (724)-465-4209 Report of Analysis Name: Sample Start Date: Receipt Date: Report Date: XTOEnergy 395 Airport Road Indiana, PA 15701 10/812009 9:15AM 10/8/2009 2:42 PM 10/3012009 Analyte Iron- ICP lron,Dissolved-ICP Lead-ICP Lithiwn

- ICP Magnesiwn-ICP Manganese

- ICP Mercury Molybedenwn

- ICP Nickel- ICP Seleniwn-ICP Silver-ICP Sodiwn- ICP Strontiwn

- ICP Zinc- ICP Detergents, MBAS Ethylene Glycol Oil and Grease

- HEM Phenolics,
as Phenol Specific Conductance Total Dissolved Solids (TDS) Total Suspended Solids Radiologicals
Analyst GJT GJT GJT GJT GJT GJT DMM GJT GJT GJT GJT GJT GJT GJT TL MetPeak CLM MAD LL CLM ALD enchmru Comments: Radiologicals done by Benchmark Analytical Note: DEP Certification
#s 32-00382 SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analysis Sample Date Result 10121/2009 38.600 1012112009 21.200 10/21/2009 ND 10122/2009 72.500 10/23/2009 384.400 1012112009 4.000 10/1512009 ND 1012112009 ND 1012112009 ND 10/2112009 ND 10/2212009 ND 1012212009 26743.000 10/2312009 720.700 10/21/2009 ND 10/09/2009 0.614 10/20/2009 <25.000 · t0/20/2009 ND 10/1312009 ND 10/08/2009 112400 10/14/2009 104800 10/13/2009 472 10/30/2009

*
09 29510 Waste Water Grab NEW (Client) Hall8431
H Units mg/1 mg/1 mg/1 mg/1 mgllmg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mglkg mg/1 mg/1 uS/em mg/1 mg/1 mg/1 Data Qualifiers:

D = The reported value is from dilution.

E = Estimated value.

S = Surrogate out of control limits. Method RPL 200.7/6010 1.000 200.7/6010 1.000 200.7/6010 0.500 200.7/6010 50.000 200.7/6010 50.000 200.7/6010 0.500 245.1 0.0002 200.7/6010 0.500 200.7/6010 0.500 200.7/6010 1.000 200.7/6010 0.500 200.7/6010 500.000 200.7/6010 1.000 200.7/6010 0.500 SM5540C 0.200 300.0M 25.000 1664A
5.0 420.1 0.500 SM 2510B

1 SM2540C

25 SM2540D

5 RAD-CTDHS 0.000 IND=Not Detected R = Sample received out of holding time

. H = Sample analyzed out of holding time

. C = Sample received
in incorrect container. B = Analyte was detected

in both sample and methods blank

. x = User defined data qualifier.

Page 2 ofs: N\i

i a;.;c-1 N 'Ji i= NT A
i -I '11 Y I I'-"-"

I 11 IW I-

I 11 II ,. SERVICE LABORATORIES, INC. 1803 Philadelphia Street, Indiana, PA 15 701 (724)-463-TEST
FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: 1} Benzene 47) Toluene XTOEnergy 395 Airport Road Indiana, PA 15701 10/8/2009 9:15AM 10/812009 2:42PM 10/30/2009 Analyte Report of Analysis SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO 10/09/2009 26.40 RO 10/09/2009 ND Comments: Radiologicals done by Benchmark Analytical Note: DEP Certification
#s 32-00382

09 29510 Waste Water Grab NEW (Client) Hall8431
H Units ug!L ugiL Data Qualifiers:

D = The reported value is from dilution.

E = Estimated value.

S = Surrogate out of control limits

. Method RPL 624/8260B 20.00 624/8260B

20

. 00 JND=Not Detected R = Sample received out of holding time. H = Sample analyzed out of holding time.
C = Sample received
in incorrect container. B = Analyte was detected
in both sample and methods blank.
x = User defined data qualifier.

Page 3 of 3**~V**
**T** 'VVT -VYV **~V**

• .. v
& **~ V~Y"** 

1 **"ZV~V" .u.&.:~.a.,v&.U~UUu~**  .nJ.,ru
.... **~ ~**  J.V-.:1 .1.1'" . , . LAB 10 #: 39 00401 SEND OATA TO: NAME: Mike Moyer BENCHMARK ANALYTICS

, INC. 4777 Saucon Creek Road.., Center Valley, PA 18034-9004 PHONE (610) 974-8100 **FPU<(610)97~8104** COMPANY: Environmental Service Laboratories, Inc ADDRESS: 1803 Philadelphia
St PHONE: FAA: Indiana, PA 15701 (724) 463-8378 (724) 465-4209 TEST REPORT
Work Order: 09101656 VVO#: 09101656 PAGE: 2of2 PO#: OAS10092009 PWSID# 09 29350 & 09 29510 RECEIVED FOR LAB BY: DMB DATE

: 10/121200910:00

Page2 of2 SAMPLE: 09 29510

Lab tO; 09101656-002E Grab SAMPLED BY: David A. Stl1e .nm B!!!!!t Thorium

< 0.0131 --- SAMPLE:
09 29510 SAMPLED BY: David A. Stile IHt Result Gross .Alpha 1971 Gross Beta 2286 SAMPLE: 09 29510 SAMPLED BY: David A Stile nml &at!l Radium-226 464.9 SAMPLE: 09 29510 SAMPLED BY: David A. Stile Sample Tltne 1010812009 9:15 **~ ~**  Yn!!! **~** :t 0.00

0 mgll EPA200.8 Lab ID: 09101656-002A Sample Time 10/0612009 9:15 **~**

g Units **~** :t22U 746.9 pCVl. EPA900.0 t 140.7 682

. 4 pCIIL EPA900.0 Lab 10: 09101656-0029 Sample Tine 1010812009 9:15 **~** MQ.a Units .M!1tm. :t 15.84 59.4 pCiiL EPA 903.0 Lab ID: 09101656-002C Sample **T~me** 1010812009 9:15 I!S Radium-228 **~~** 148.7

:t 11.10 MQ6 14.16 l.!!llt! **~** pCUL EPA 904.0 ltQ. AQa!Y* start Analysis End AnalYst

• 10113109 8:30 10116109 GSR-CV --- Grab MQ!s Ana!ys!s Start Analysis End **~** 10113109 a:so 10116109 BPs-cv 10113109 8:50 10116109 **BP~CV** Grab M!d. Analysis Start AnalySis End **~** 1011610911:15 10129109 BH-CV Grab m Analysis Start AnalysiS End &Wia! 10121109 8:05 10/27109 NLB-CV ·· -----

· ---
· --- SAMPLE: 09 29510

Lab 10:· 0910165$-0020 Grab SAMPLED BY: David A. Stile Sample Tme 1010812009 9:15 !U1 Result **~** Uranium

< 13.13
:t 0 . 00 **~nlum** <8.93

:1: 0.00 !@A !.!nl1l 0 J.Jg/L 0 pCiiL **~** EPA200.8 EPA200.8 **~** AnaMis Start Anatvsis End **~** 30 10119109 10:00 10123109 GSR-CV 10/19109 10:00 10123109 GSR-CV · · --

.. · -· ·---·

· ·--···

··
· - REMARKS

: The above test procedures meet all the requirements

of NELAC and relate only to these samples. " CV .. Benchmark Analytics, Inc. Center Valley, PA
; SA= Benchmark Analytics, Inc
. Sayre

, PA MS Umit of ctetectlon increased due to matrix interference and spike recovery data MANAGER **~md** .
"

.

.

. ..
DATE: /0/3012009&= NVi k¥C-i N 1\ii **~::NT** A i -
I .. Y I 1'- **~**

I 11 I Y I **~~~I** .. II ,. SERVICE LABORATORIES/ INC. 1803 Philadelphia Street, Indiana, PA 15 701 [724)-463-TEST
FAX (724)-465-4209 Name: XTOEnergy Sample Start Date: 395 Airport Road Indiana, PA 15701 10/8/2009 10/812009 2:42 PM 10/12/2009 Receipt Date: Report Date: Analyte 1) Benzene 47) Toluene Comments: DEP Certification
#s 32-00382 Report of Analysis SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO 10/09/2009 ND RO 10/09/2009 ND

09 29511 Waste Water Grab NEW (Client) Trip Blank Units ug/L ug/L Method MDL 624/8260B 1.00 624/8260B 1.00 IND=Not Detected Paae
1 of 1COMMONWEAL
1M OF PENNSYLVANIA DEPARTMENT
OF ENVIRONMENTAL PROTECTION BUREAU OF WASTE MANAGEMENT FORM26R CHEMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT BY THE GENERA TOR must accurately completed. All must be typed or legibly printed in the spaces provided.

If additional space Is necessary, Identify each attached sheet as Fonn 26R, refenmce the item number and Identify the date prepared. The date on attached sheets needs to match the date noted below. General Reference 287.54 Date Prepared/Revised 219111 c.

State PA First Name Ben Company Mailing Address Une Zip+4 15701 Ml opaque white/orange Odor Number of Solid or Uquld Phases of Separation
EPA Generator Describe each phase **ofseparation.~~---------------1** a.

- 1 -2540-PM-BWM0347 Rev.1/2011 c. Address Une 1 Address Une 1 Address City State ZIP Municipality Phone d. waste shipped to processing or a. b. Facility Name Address Une 1 Address Une 1 Address City State ZIP Municipality c. Title

0 cuyd **~** gal D lb processing or disposal -2- County Indiana steve@pabrine.com year. 0 ton (check one) being utilized. County (check one) Oton (check one)2&40=PM=BWM0347 Rev. 112011 I certify, under penalty of law, that

I have personally eXamined and am familiar with the information submitted
In this Annual Report and all attached documents and that based upon my Inquiry of those lndMduals Immediately responsible for obtaining the Information,

I verify that the submitted Information

Is true, accurate and complete to the best of my knowledge.

I understand that the submission
of false Information herein is made subject to the penalties of 18 Pa. C.S. §4904, relating to unsworn falsification
to authorities; which Include fine and Imprisonment Check the following,

If applicable: 0

I certify the Information required
In Section B-1, General Properties was supplied to the Deparbnent for the year __ and has not changed. Form Submitted:

D Form 26R 0 Other (specify) Date Submitted: 0

I certify the information required In Section B-2, Chemical Analysis was supplied to the Deparbnent for the year _and has not changed. Form Submitted:

0 Form26R 0 Other (specify) Date Submitted: 0

I certify the information required In Section B-3, Process Description and Schematic, was supplied to the Deparbnent for the year __ and has not changed. Form Submitted:

0 Form 26R 0 Other (specify) Date Submitted: Name of Responsible Official Bernhardt Kissel Signature

Date 2-28-11 -3-February
9, 2011 Form 26R: Section B1e GENERA TOR KNOWLEDGE All Form 26R Waste Forms have been compiled, and future testing has been scheduled,
to obtain samples of each waste stream on a PAD by PAD basis. Sample analyses will be conducted every
5 years for each waste stream unless the process that generates any particular waste stream is substantially altered. Attached analytical results for this waste stream have been obtained from a similar waste stream producing waste from the same geologic formation as this 26R Report. Additionally, the mud mixtures, chemical formulations and drilling process utilized at this well PAD are substantially the same as those utilized at the well where the attached waste analyticals were generated.February
8, 2011 Form 26R: Section 82b WASTE SAMPLING METHODS

I · All samples were obtained as grab type samples with a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are composited within the storage production tank or tank battery at each well site where gas production

is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tan
- k trucks for disposal at various PaDEP permitted waste disposal facilities on different schedules determined by individual well characteristics. Grab samples of the composited fluids were obtained at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. Samples were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives,
as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. Flowback samples were composited
to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion
of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives,
as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process at various times and combined into a composite sample for analyses at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites.

In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness
of the composite sample and cqmposite grid sample positions were varied to the extent possible. Pit water (drill fluid) is currently discharged
to closed containment and is re-conditioned and reused from well to well.I • February
9, 2011 Fonn 26R: Section B3a WASTE GENERATION PROCESS Pit Water "Drill Fluids" Remnant drill fluids are generated

in the well bore during the penetration
of the drill stem as it intercepts both ground water and fonnation fluids. These fluids are brought to the surface along with the drill cuttings, pieces of the intercepted rock strata, by the return flow system of the drilling process. Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. Fluids are currently stored in closed containers to be processed for reuse. Flowback: "Fracing Fluid" Flowback
is produced from all fluids that flow back to surface during the "hydrofracing" process which occurs under pressure and results in the setting of a propant within the fonnation fractures. Production Fluid "Brine" During the production
of natural gas, formation pressures bring remnant frac fluids, during the initial production phase, and fonnation fluids to the surface along with produced gas.-

Well I. D.# (various) '\/ -a- /1' \ \ \ \ \ \ \ \ COUNTYB ote: .

\ \ Process producing waste: Gas well produced fluids (brines) are typically produced" in conjuction wi.th natural gas. These fluids are brought to the surface utilizing either mechanical or physical lift procedur . es.

/ /

COUNTY A Well I. D.# (various) \ I .::o/ /I**I~** / / / / / Mobile Tank Truck _ s Road Transport

(.')**~** w :c (..) en z 0**~** 1-**~** 0 0.. en z**~** 1-**~illf ~~~I**  ii .! t**~**

i I**~** I**~ ~~**  Landfi II or-**~** i § Trec..+o.t<A+ 'PIC4At . I! H**~** I!**~ ~** **~~** ;;;! 2u

# •w• **~-** 

# • •

# ENVIRONMENTALSERVICE SAMPLEREQUEST

# &CHAINOFCUSTODY

**LABORATORIES~**

# INC. PAGE __ OF 1--



# ... HEADQUARTERS:



# ~ SOUTHERN DIVISION: 

# 8 1803 Philadelphia St
. 1276 Bentleyville Road 

# D Indiana, PA 15701 Van Voorhis, PA 15388 

# REC'D NOV -4 

# 2009 - ..I 

# (724) 463-TEST (724) 258-TEST (724) 465-4209 (724) 258-8376 

# .. FORINTERNAL LABORATORYUSEONLY 

# SampleType Sample Identification ESL# Composite Grab Matrix 

# # ofContainers ContainerType Analysis Requested Date on/off 

# Time on/off 

# Date Time · Preservative 

# 11141/,J?l/31 

# fl. 

# 0!9:



# ~!()

# ---- ----- /0 /__./A \foNJ Plastic Liter pH,SC,Chorlde, Sulfate, /


# ------ ------ t:'ft

# IS 1

**'~L""'** 

# none Alkalinity, Acidity, Bromide 

# ----- -----

**lrt>~J:.**

# ,.,

**1~** \foNJ Plastic Uter TSS, TDS, Dissolved Iron, 

# --- ----- 1t:J

**I~** 2 none Boron, BOD,MBAS Surfactants



# ~ 

# ------ 1/o«J:. \foNJ Plastic Liter AI, 

# As, Sa, Be, Cd, Cr, Co, Cu, Fe, Pb, Mg,


# ----- ------ It!>



# ~

# ' 1.5 1 HN03 

# Mn, Hg, Nl, Se, Ag, Sr, Zn, 

# Li, Na, Ca, Mo, Hardress 

# ----- ------

**~~**17 

# '1 

# t5 \foNJ Plastic Liter 

# ----- ------ 10 1 Nitrate+Nitrite, TKN,Ammonia, COD H:z$04 

# ---- ------

**v~tk** (2) 1000 mL Plastic Liter GrossAlpha, Gross Beta



# ~ **~ 'lo~**  

# '

**I~** \foNJ (3) 500 mL Radium 226, Radium 228 

# !5o HN03 Thorium, Uranium 

# ----- ------- \foNJ AmberGlass L 

# ---- ----- 10 

# o8 Cj 

# 15 1 Oil &Grease HCI



# ----- ------ btrk \foNJ 

# 1 AmberGlass L 

# ----- ------ /0



# ~ 

# 1:1> H2S04 Total Phenolics


# ----- ----- 'b8k 

# ., 1'5 \foNJ 

# 2 AmberVOAVials



# ----- ------ to none Ethylene Glycol



# . 

# --- ----- 1ey

# 08/a

**1~** 

# ,, \foNJ 

# 2 AmberVOAVials 

# '

**~** 

# -------- HCI Benzene, Toluene TRIP BLANK 

# 09 

# ---- ------- ::::::::::-

**~** Water 

# 2 :AmberVOAVials 

# '215"'11

# ----- ------- HCI Benzene, Toluene THE UNOERSIGNEO PURCHASER HEREBYAGREES TO PAY SERVICE CHARGES ONACCOUNTSOVER31 llo'YSOLD
. 

# ProjectNotes: 1
.THESE SERVICE CHARGES WILL ACCRUE ATTHE RATE OF 1 1/2% PER MONTH (18% PERANNUM ORTHE MAXIMUMALLOWED BYlAW
.) 2
.THE UNDERSIGNED PURCHASERAGREES TO PAY
. INTHE EVENT HISACCOUNT BECOMES DEUNQUENTAND ISTURNEDOVERTOANY

ATTORNEY FOR COLLECTION, REASONABLE ATTORNEY'S FEES PLUSALL COURTANDATTENDANT COLLECTIONCOSTS
. 

# A'_/



# .J~-/



# tok/~ 9..

**/$"~H?** Company/Name: 

# XTO ENERGY

**Sampl~** 

# By: (Signature) 

# Mate/Tlme



# ~-~ **ILf\~~**



# '( 

# a d.#_

**~ ll'>~'i<'-o"r**  **rl{~~{** 

# . 

# {o-K-ocr Address: 

# 395AIRPORT ROAD

**Relinquish~y:** (SignatureJ.. 

# Date/ Time



# ~cslgnU 

# r-1£ .date/Tlme 

# Nl/3 INDIANA, PA 15701



# 1?'~ lo-g-cq 

# (Lf\



# ~s- 

# 'd:-

**~,** 

# / /)-tf"',-t5J

# 7 Relinquished By: (Signature) 

# Date/ Tlme ltecelved By: cslgn811h.) 

# I Date/ Tlme 

# r. Contact Person: 

# MR. MIKE HAHN Relinquished

# By: (Signature) 

# Date/ Time Received By: (Sip!'") 

# Date/ Tlme Phone: 

# (724) 349-0600 

# ' CHAIN OF CUSTODYSEAL BROKEN: Yes No 

# Fax: (724) 349-8489


# - I

# I. II



# '9'£~/ 

# IJs: N\ii ti£-lt"\1 i\li &=NT A
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I 'tl II .... SERVICE LABORATORIES, INC. 1803 Philadelphia Street Indiana, PA 15 701 (724)-463-TEST
FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: XTOEnergy 395 Airport Road Indiana, P A 1570 1 10/8/2009 9:15AM 10/8/2009 2:42 PM l0/30/2009 Analyte Acidity to pH=8.3 Alkalinity
to pH=4.5 Biological Oxygen Demand 05 Chemical Oxygen Demand Ammonia
as N I Distilled Bromide Chloride Kjeldahl Nitrogen as N pH(SM) SulfateASTM Total Nitrate+ Nitrite as N Aluminum

- ICP Arsenic-ICP Barium- ICP Beryllium

- ICP Boron Cadmium

- ICP Calcium

- ICP Chromium- ICP Cobalt- ICP Copper- ICP Hardness Report of Analysis Analyst Analysis Date BF 10/11/2009 IS 10/1212009 szc 10/12/2009 MAD 10/15/2009 MAD 10/19/2009 AID 10/21/2009 BF 10/09/2009 MAD 10/19/2009 LL 10/08/2009 LMB 10/12/2009 AID 10/1912009 GJT 10/21/2009 GJT 10/22/2009 GJT 10/21/2009 GJT 10/22/2009 MAD 10/26/2009 GJT 10/22/2009 GJT 10/22/2009 GJT 10/21/2009 GJT 10/21/2009 GJT 10/21/2009 GJT 10/23/2009 SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Sample Result

09 29510 Waste Water Grab NEW (Client) Hall8431
H ? ;n.tc 4- Units Method ND mgfl as CaC03 SM2310B 175 mgfl as CaC03 SM2320B 68.7 mgfl SM5210B 1002.5 mgfl SM5220D 62.73 mgfl sM4500NH3B&tt 554.00 mgfl D1246-99 51663.1 mg/1 SM4500ClC 33.1 mg/1 SM4500Norg-C,D 6.60 su SM4500H-B ND mg/1 0516-02 ND mg/1 SM4500N03E ND mg/1 200.7/6010 ND mg/1 200.7/6010 388.800 mg/1 200.7/6010 ND mg/1 **200.7/601~** 15.00 mg/1 SM4500B-B ND mg/1

. 200.7/6010 4248.800 mg/1 200.7/6010 ND mg/1 200.7/6010 ND mg/1 200.7/6010 ND mg/1 200.7/6010 12192 mg/1 SM2340B RPL 2 20 2.0 500.0 1.00 20.00 1.0 5.5 0.01 5 0.05 1.000 1.000 0.500 0.500 12.50 0.500 50.000 0.500 0.500 0.500 1 Comments: Radio1ogicals done by Benchmark Analytical

JND=Not Detected Note: DEP Certification
#s 32-00382 Data Qualifiers

: D = The reported value is from dilution.

E "" Estimated value.

S = Surrogate out of control limits. R = Sample received out of holding time.
H = Sample analyzed out of holding time.
C = Sample received
in incorrect container

. B = Analyte was detected
in both sample and methods blank.
X = User defined data qualifier.

Page 1 of 3a; N\ii wi-1Ni\Ji i=NT 41 -
I 11 1r I 1'- **~**

I 11 I WI -I 11 II ... SERVICE LABORATORIES, INC. 1803 Philadelphia Street Indiana, PA 15 701 (724)-463-TEST
FAX (724)-465-4209 Report of Analysis Name: Sample Start Date: Receipt Date: Report Date: XTOEnergy 395 Airport Road Indiana, PA 15701 10/812009 9:15AM 10/8/2009 2:42 PM 10/3012009 Analyte Iron- ICP lron,Dissolved-ICP Lead-ICP Lithiwn

- ICP Magnesiwn-ICP Manganese

- ICP Mercury Molybedenwn

- ICP Nickel- ICP Seleniwn-ICP Silver-ICP Sodiwn- ICP Strontiwn

- ICP Zinc- ICP Detergents, MBAS Ethylene Glycol Oil and Grease

- HEM Phenolics,
as Phenol Specific Conductance Total Dissolved Solids (TDS) Total Suspended Solids Radiologicals
Analyst GJT GJT GJT GJT GJT GJT DMM GJT GJT GJT GJT GJT GJT GJT TL MetPeak CLM MAD LL CLM ALD enchmru Comments: Radiologicals done by Benchmark Analytical Note: DEP Certification
#s 32-00382 SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analysis Sample Date Result 10121/2009 38.600 1012112009 21.200 10/21/2009 ND 10122/2009 72.500 10/23/2009 384.400 1012112009 4.000 10/1512009 ND 1012112009 ND 1012112009 ND 10/2112009 ND 10/2212009 ND 1012212009 26743.000 10/2312009 720.700 10/21/2009 ND 10/09/2009 0.614 10/20/2009 <25.000 · t0/20/2009 ND 10/1312009 ND 10/08/2009 112400 10/14/2009 104800 10/13/2009 472 10/30/2009

*
09 29510 Waste Water Grab NEW (Client) Hall8431
H Units mg/1 mg/1 mg/1 mg/1 mgllmg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mglkg mg/1 mg/1 uS/em mg/1 mg/1 mg/1 Data Qualifiers:

D = The reported value is from dilution.

E = Estimated value.

S = Surrogate out of control limits. Method RPL 200.7/6010 1.000 200.7/6010 1.000 200.7/6010 0.500 200.7/6010 50.000 200.7/6010 50.000 200.7/6010 0.500 245.1 0.0002 200.7/6010 0.500 200.7/6010 0.500 200.7/6010 1.000 200.7/6010 0.500 200.7/6010 500.000 200.7/6010 1.000 200.7/6010 0.500 SM5540C 0.200 300.0M 25.000 1664A
5.0 420.1 0.500 SM 2510B

1 SM2540C

25 SM2540D

5 RAD-CTDHS 0.000 IND=Not Detected R = Sample received out of holding time

. H = Sample analyzed out of holding time

. C = Sample received
in incorrect container. B = Analyte was detected

in both sample and methods blank

. x = User defined data qualifier.

Page 2 of**~V**
**T** 'VVT -VYV **~V**

• .. v
& **~ V~Y"** 

1 **"ZV~V" .u.&.:~.a.,v&.U~UUu~**  .nJ.,ru
.... **~ ~**  J.V-.:1 .1.1'" . , . LAB 10 #: 39 00401 SEND OATA TO: NAME: Mike Moyer BENCHMARK ANALYTICS

, INC. 4777 Saucon Creek Road.., Center Valley, PA 18034-9004 PHONE (610) 974-8100 **FPU<(610)97~8104** COMPANY: Environmental Service Laboratories, Inc ADDRESS: 1803 Philadelphia
St PHONE: FAA: Indiana, PA 15701 (724) 463-8378 (724) 465-4209 TEST REPORT
Work Order: 09101656 VVO#: 09101656 PAGE: 2of2 PO#: OAS10092009 PWSID# 09 29350 & 09 29510 RECEIVED FOR LAB BY: DMB DATE

: 10/121200910:00

Page2 of2 SAMPLE: 09 29510

Lab tO; 09101656-002E Grab SAMPLED BY: David A. Stl1e .nm B!!!!!t Thorium

< 0.0131 --- SAMPLE:
09 29510 SAMPLED BY: David A. Stile IHt Result Gross .Alpha 1971 Gross Beta 2286 SAMPLE: 09 29510 SAMPLED BY: David A Stile nml &at!l Radium-226 464.9 SAMPLE: 09 29510 SAMPLED BY: David A. Stile Sample Tltne 1010812009 9:15 **~ ~**  Yn!!! **~** :t 0.00

0 mgll EPA200.8 Lab ID: 09101656-002A Sample Time 10/0612009 9:15 **~**

g Units **~** :t22U 746.9 pCVl. EPA900.0 t 140.7 682

. 4 pCIIL EPA900.0 Lab 10: 09101656-0029 Sample Tine 1010812009 9:15 **~** MQ.a Units .M!1tm. :t 15.84 59.4 pCiiL EPA 903.0 Lab ID: 09101656-002C Sample **T~me** 1010812009 9:15 I!S Radium-228 **~~** 148.7

:t 11.10 MQ6 14.16 l.!!llt! **~** pCUL EPA 904.0 ltQ. AQa!Y* start Analysis End AnalYst

• 10113109 8:30 10116109 GSR-CV --- Grab MQ!s Ana!ys!s Start Analysis End **~** 10113109 a:so 10116109 BPs-cv 10113109 8:50 10116109 **BP~CV** Grab M!d. Analysis Start AnalySis End **~** 1011610911:15 10129109 BH-CV Grab m Analysis Start AnalysiS End &Wia! 10121109 8:05 10/27109 NLB-CV ·· -----

· ---
· --- SAMPLE: 09 29510

Lab 10:· 0910165$-0020 Grab SAMPLED BY: David A. Stile Sample Tme 1010812009 9:15 !U1 Result **~** Uranium

< 13.13
:t 0 . 00 **~nlum** <8.93

:1: 0.00 !@A !.!nl1l 0 J.Jg/L 0 pCiiL **~** EPA200.8 EPA200.8 **~** AnaMis Start Anatvsis End **~** 30 10119109 10:00 10123109 GSR-CV 10/19109 10:00 10123109 GSR-CV · · --

.. · -· ·---·

· ·--···

··
· - REMARKS

: The above test procedures meet all the requirements

of NELAC and relate only to these samples. " CV .. Benchmark Analytics, Inc. Center Valley, PA
; SA= Benchmark Analytics, Inc
. Sayre

, PA MS Umit of ctetectlon increased due to matrix interference and spike recovery data MANAGER **~md** .
"

.

.

. ..
DATE: /0/3012009s: N\i

i a;.;c-1 N 'Ji i= NT A
i -I '11 Y I I'-"-"

I 11 IW I-

I 11 II ,. SERVICE LABORATORIES, INC. 1803 Philadelphia Street, Indiana, PA 15 701 (724)-463-TEST
FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: 1} Benzene 47) Toluene XTOEnergy 395 Airport Road Indiana, PA 15701 10/8/2009 9:15AM 10/812009 2:42PM 10/30/2009 Analyte Report of Analysis SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO 10/09/2009 26.40 RO 10/09/2009 ND Comments: Radiologicals done by Benchmark Analytical Note: DEP Certification
#s 32-00382

09 29510 Waste Water Grab NEW (Client) Hall8431
H Units ug!L ugiL Data Qualifiers:

D = The reported value is from dilution.

E = Estimated value.

S = Surrogate out of control limits

. Method RPL 624/8260B 20.00 624/8260B

20

. 00 JND=Not Detected R = Sample received out of holding time. H = Sample analyzed out of holding time.
C = Sample received
in incorrect container. B = Analyte was detected
in both sample and methods blank.
x = User defined data qualifier.

Page 3 of 3&= NVi k¥C-i N 1\ii **~::NT** A i -
I .. Y I 1'- **~**

I 11 I Y I **~~~I** .. II ,. SERVICE LABORATORIES/ INC. 1803 Philadelphia Street, Indiana, PA 15 701 [724)-463-TEST
FAX (724)-465-4209 Name: XTOEnergy Sample Start Date: 395 Airport Road Indiana, PA 15701 10/8/2009 10/812009 2:42 PM 10/12/2009 Receipt Date: Report Date: Analyte 1) Benzene 47) Toluene Comments: DEP Certification
#s 32-00382 Report of Analysis SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO 10/09/2009 ND RO 10/09/2009 ND

09 29511 Waste Water Grab NEW (Client) Trip Blank Units ug/L ug/L Method MDL 624/8260B 1.00 624/8260B 1.00 IND=Not Detected Paae
1 of 1**2~M-BWM0347**
Rev. 112011 . g pennsylvania • DEPARTMENT
OF ENVIRONMENTAL PROTEcnON COMMONWEALTH

OF PENNSYLVANIA **DEPARnMENTOF~RONMENTALPROTECTION** BUREAU OF WASTE MANAGEMENT FORM26R CHEMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT BY THE GENERA TOR typed or legibly printed In the spaces provided.

If additional space is necessary, Identify **llla~t:;;l:'d** each attached sheet as Fonn 26R, reference the Item number and identify the date prepared. The date on attached sheets needs to match the date noted below. General Reference 287.54 Date Prepared/Revised 219/11 Company Une2 c.
opaque white/orange Odor Number of Solid or Uquid Phases of Separation

10# No Describe each phase of separation

• **..:.:.:::~.=-----------------i** - 1
-254Q.PM-BWM0347 Rev. 1/2011 Address Une 1 Address Une
1 Address City State ZIP Municipality c. Facility Contact Name Title d. a. Phone Address Une
1 Address Une 1 Address City State ZIP Municipality c. Facility Contact Name Title Phone

County Indiana steve@pabrine.com (check one) for processing or disposal County to processing
or disposal facility In the previous year. b.

D cu yd D gal D lb D ton Volume of waste beneficially used in the **un::vn.,u~** D cuyd
0 gal -2-
D ton (check one)2540-PM-BWM0347
Rev. 112011 I certify, under penalty of law, that

I have personally examined and am familiar with the Information submitted
In this Annual Report and all attached documents and that based upon my Inquiry of those Individuals immediately 19Sponslble for obtaining the Information,

I verify that the submitted information

Is true, accurate and complete to the best of my knowledge.

I understand that the submission
of false information herein Is made subject to the penalties of 18 Pa. C.S. §4904, relating to unsworn falsification
to authorities, which Include fine and Imprisonment Check the following,

if applicable: 0

I certify the Information required In Section B-1, General Properties was supplied to the Department for the year _and has not changed. Form Submitted:

0 Form 26R 0 Other (specify) Date Submitted: 0

I certify the Information required in Section B-2, Chemical Analysis was supplied to the Department for the year _and has not changed. Form Submitted:

0 Form26R 0 Other (specify) Date Submitted: 0

I certify the information required In Section B-3, Process Description and Schematic, was supplied to the Deparbnent for the year __ and has not changed. Form Submitted:

0 Form 26R 0 Other (specify) Date Submitted: Name of Responsible Official Bernhardt Kissel Signature

Date 2-28-11 -3-February
9, 2011 Form 26R: Section B1e GENERA TOR KNOWLEDGE All Form 26R Waste Forms have been compiled, and future testing has been scheduled,
to obtain samples of each waste stream on a PAD by PAD basis. Sample analyses will be conducted every 5 years for each waste stream unless the process that generates any particular waste stream
is substantially altered. Attached analytical results for this waste stream have been obtained from a similar waste stream producing waste from the same geologic formation as this 26R Report. Additionally, the mud mixtures, chemical formulations and drilling process utilized at this well PAD are substantially the same as those utilized at the well where the attached waste analyticals were generated.February
8, 2011 Form 26R: Section B2b WASTE SAMPLING METHODS

I• All samples were obtained as grab type samples with a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are composited within the storage production tank or tank battery at each well site where gas production

is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank{s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP permitted waste disposal facilities on different schedules determined by individual well characteristics. Grab samples of the composited fluids were obtained at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. Samples were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives,
as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. Flowback samples were composited
to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion
of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives,
as necessary, depending

on the specific test run requested. All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process at various times and combined into a composite sample for analyses at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites.

In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness
of the composite sample and composite grid sample positions were varied to the extent possible. Pit water (drill fluid) is currently discharged
to closed containment and is re-conditioned and reused from well to well.i·February9,2011Form26R:SectionB3aWASTEGENERATIONPROCESSPitWater"DrillFluids"Remnantdrillfluidsaregeneratedinthewellboreduringthepenetrationofthedrillstemasitinterceptsbothgroundwaterandformationfluids.Thesefluidsarebroughttothesurfacealongwiththedrillcuttings,piecesoftheinterceptedrockstrata,bythereturnflowsystemofthedrillingprocess.Drillcuttingsanddrillfluidsareisolatedintoseparatewastestreams.Cuttingsaremixedwithsawdusttoabsorbremnantfluidandloadedoutfordisposalatalandfill.Fluidsarecurrentlystoredinclosedcontainerstobeprocessedforreuse.Flowback:"FracingFluid"Flowbackisproducedfromallfluidsthatflowbacktosurfaceduringthe"hydrofracing"processwhichoccursunderpressureandresultsinthesettingofapropantwithintheformationfractures.ProductionFluid"Brine"Duringtheproductionofnaturalgas,formationpressuresbringremnantfracfluids,duringtheinitialproductionphase,andformationfluidstothesurfacealongwithproducedgas.Well I. D.# **(~arious)** Well I. · D.# . (various) '\\/ w

-0 -y- **/~,** /1' I \ I \ / Well I. D.# (various) \ I ::H:. \ I // l \ I / \ I // \ I // . . \ I / Well I. D.# (various) \ 1 // '\\/ / \ I / -o- / " **(/~~** <Qflo .. **;Q~; ~**  Mobile Tank Truck **~t-o~·ho" Ocv1\\j..~~** 

COUNTYB

COUNTY A \OA\..s :· ( J1 S brine (1YP.)

_ s:: Road Transport Landfill Or"' **Tr-u....+~U\+** 'PlCAAt Note: Process producing waste: Gas well produced fluids (brines) are typically produced · in conjuction with natural gas. These fluids are brought to the surface utilizing either . mechanical or physical lift procedur _ es.

(.) **~** UJ :I: **~** z 0 **~ ~**  0 0.. · W **·~** 1- **~~~~~~** l= **~~ g~**  I, - **~** § r **~a**

**~** I' lli I ! **~ l~**  I i . **~**

# ~· **··** 

# ,_ ._

# ENVIRONMENTAL

# SERVICE SAMPLEREQUEST

# &CHAINOFCUSTODY 

# LABORATORIES,INC. PAGE 

# __ OF_1-- 

# .. HEADQUARTERS: SOUTHERN DIVISION: 1803 Philadelphia Sl



# ~ 1276 Bentleyville Road 

# D 

# 8 Indiana, PA 15701 Van Voorhis, PA 15366 

# REC'D NOV -4 

# 2009 • .j 

# (724) 463-TEST (724) 258-TEST (724) 465-4209 (724) 258-8376 FORINT'EIUIALlJJ.rORATOR'I'USE.cJR['y 

# SampleType Sample Identification ESL# Composite Grab Matrix # ofContainers ContainerType Analysis Requested Dateon/off 

# Timeon/olf 

# Date Time p,.•ervative 

# 1!14!1

**,~1/31** 

# H0 

# l<:Jfll)

# ---- ---- /0 /_ -'· PlasticLiter pH, SC, Choride, Sulfate, /


# ---- ---- ., Cjl'1$ WN 1 fOKLO 

# none Alkalinity, Acidity, Bromide 

# --------- It 

# t>KJ:.

**~**

# 1t WN Plastic Liter TSS, TDS, Dissolved Iron,


# ---- ---- fCJ

**I~** 2 none Boron, BOD, MBAS Surfactants



# ----- 

# ----- lotSk PlasticLiter AI, As, Ba, Be, Cd, Cr, Co, Cu, Fe, Pb, Mg, 

# ---- ----- /0



# ~

# ' I.S WN 1 HN03 

# Mn, Hg, Nl, Se, Ag, Sr, Zn, 

# ll, Na, Ca, Mo,

**Hardne~s**



# -----

# ----

**~~**

**~** 

# 'i

**t~** WN Plastic Liter


# ---- ------ TO 1 Nitrate+Nilrite, TKN, Ammonia, COD H:zSO•



# -----

# ----

**~~~k** (2) 1000 ml Plastic Liter GrossAlpha, Gross Beta



# ~ **~** 101



# ~

# ' 15 WN (3) 500 ml Radium 226, Radium 228 HN03 

# Thorium, Uranium


# ---- ------ 15 WN AmberGlass L


# ---- **~** 

# TO 

# oE 

# cr 1 011 &Grease HCI


# ---- ------ b'gb WN AmberGlass L



# ----- **~** 

# /0 

# ' 1:1J 1 Total Phenolics H:zSO•



# -----

# --- I 

# he"-

**~** WN 2 AmberVOAVials


# ---- **~** 

# to 

# I'S none Ethylene Glycol



# ---- 

# ---- ley tJ&/(f

# ,

**1~11'** WN 2 AmberVOAVials



# ---- **~** HCI Benzene, Toluene
TRIP BLANK 

# t:J9 

# ---- ____...--



# ~**~** Water 

# 2 :

**~ber**

# VOAVials Benzene, Toluene



# '21~11 

# ---- ------ HCI THEUNDERSIGNEDPURCH.\SERHEREBYAGREESTO PAY SERI/ICE

# CH.\RGESONACCOUNTSOVER 31



# ~YS

# OLD. 

# ProjectNotes: 1
.

# THESESERVICECH.\RGESWILLACCRUEATTHE RATE OF 

# 1

# 112% PER·MONTH

**(1~**

# PI!RANNUMORTt1E

# MAXIMUMALLOW1EDBY LAW
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# 2.

# THE UNDERSIGNEDPURCH.\SERAOREESTOPAY, INTHE EVENTHISACCOUNTBECOMES DI!UNQUl!NT

# AN0ISTURNEDOVERTO

**A~**



# ATTORNEYFORCOLLECTION, REASONABLEATTORNEY'S FEES PLUSALLCOURTANDATTENDANTCOLL.EcnQNCOSTS
. 

# A'L

**.~/:d._**



# ton/~ 9
.. /$"..-"?b1 Company/Name: 

# XTO ENERGY

**Sampl~** 

# By: (Signature)

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# Time



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# '1.

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# .d"/.- -:e::_ 

# Ir-;-



# ~-ocr I



# l{~**~{** . 

# r o-

# <?.-ocr Address: 

# 395AIRPORT ROAD

**Relinquish~:** 

# (Signatural, Date/ Time



# ~.BY:&V~ date/Time 

# Ntt3 INDIANA, PA 15701



# ~.--~ (o-g-cq 

# (

**Lft~S'** 

# Vl4 .. & / -

**~,** 

# /f)-R'-tP9 Relinquished By: (Signature) Dale/ Time 

# ftecelved By: (Sigflel\ft) 

# , Date/ Time ContactPerson: 

# MR. MIKE HAHN Relinquished By: 

# (Signature) Date/ Time Received By: (Sign.ture) Date/ Time Phone: 

# (724) 349-0600 CHAIN OF CUSTODYSEAL BROKEN: Yes No Fax: 

# (724) 34$9-8489



# - IJo./1 'j'{JJ

# J.l**S:N\/1~£-it\li\A~N**
i41 -·,.

y •• ,....,. .............. "• SERVICE LABORATORIES, INC. 1803 Philadelphia Street, Indiana, PA 15701 (724)-463-TEST
FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: XTOEnergy 395 Airport Road Indiana, PA 15701 10/812009 9:15AM l 0/8/2009 2:42 PM 10/30/2009 Analyte Acidity to pH=8.3 Alkalinity
to pH=4.5 Biological Oxygen Demand 05 Chemical Oxygen Demand Ammonia
as N I Distilled Bromide Chloride Kjeldahl Nitrogen as N pH(SM) Su1fateASTM Total Nitrate+ Nitrite as N Aluminum- ICP Arsenic-ICP Barium-ICP Beryllium

- ICP Boron Cadmium

- ICP Calcium

- ICP Chromium

- ICP Cobalt- ICP Copper-ICP Hardness Report of Analysis Analyst BF JS szc MAD MAD AJD BF MAD LL LMB AID GJT GJT GJT GJT MAD GJT GJT GJT GJT GJT GJT Sample ID#: Sample Type: Sample Source: 09 29510 Waste Water Grab Analysis Date 10/1112009 10/1212009 10/1212009 10/1512009 10/1912009 1012112009 10/0912009 10/1912009 10/0812009 10/1212009 10/1912009 1012112009 10/2212009 1012112009 10/22/2009 10/26/2009 10/2212009 10/22/2009 10/21/2009 10/2112009 10/21/2009 10/23/2009 Sampler: Client Sample ID: NEW (Client) Hall843l
H ? :rue a\- Sample Units Method Result NO mgll as CaC03 SM2310B 175 mgll as CaC03 SM2320B 68.7 mgll SM5210B 1002.5 mgll SM5220D 62.73 mgll :>M4500NH3B & [ 554.00 mgll 01246-99 51663.1 mg/l SM4500ClC 33.1 mg/l SM4500Norg-C,D 6.60
su SM4500H-B NO mg/l 0516-02 NO mg/l SM4500N03E NO mg/l 200.7/6010 NO mg/l 200.7/6010 388.800 mg/l 200.7/6010 NO mgll 200.7/6010 15.00 mgll SM4500B-B NO mgll

. 200.7/6010 4248.800 mg/l 200.7/6010 NO mgll 200.7/6010 NO mgll 200.7/6010 NO mg/l 200.7/6010 12192 mgll SM2340B RPL 2 20 2.0 500.0 1.00 20.00 1.0 5.5 O.ot 5 0.05 1.000 1.000 0.500 0.500 12.50 0.500 50.000 0.500 0.500 0.500 1 Comments: Radiologicals done by Benchmark Analytical

IND=Not Detected Note: DEP Certification
#Is 32-00382 Data Qualifiers:

D = The reported value is from dilution.

E = Estimated value.

S = Surrogate out of control limits. R = Sample received out of holding time.
H = Sample analyzed out of holding time.
C = Sample received
in incorrect container

. B = Analyte was detected
in both sample and methods blank.
x = user defined data qualifier.i=NVii1i-1Ni\Jii=NTAI -

I .. Y I 1'-........,..

I 11 I Y I -I 11 16 '-· SERVICE LABORATORIES, INC. 18 03 Philadelphia Street, Indiana, PA 15 701 (724)-463-TEST
FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: XTOEnergy 395 Airport Road Indiana, PA 15701 10/8/2009 9:15AM 10/8/2009 2:42PM 10/30/2009 Analyte Iron- ICP Iron,Dissolved-ICP Lead-ICP Lithium

- ICP Magnesiwn-ICP Manganese

- ICP Mercury Molybedenwn

- ICP Nickel-ICP Selenium-ICP Silver-ICP Sodium-ICP Strontium

- ICP Zinc- ICP Detergents, MBAS Ethylene Glycol Oil and Grease

- HEM Phenolics,
as Phenol Specific Conductance Total Dissolved Solids (TDS) Total Suspended Solids Radiologicals Report of Analysis SamplelD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result GIT 1012112009 38.600 GJT 10/21/2009 21.200 GIT 1012112009 ND GIT 10/22/2009 72.500 GIT 10123/2009 384.400 GIT 10121/2009 4.000 DMM 10/15/2009 ND GIT 10/21/2009 NO GIT 10/21/2009 NO GIT 10121/2009 NO GIT 10122/2009 NO GIT 10122/2009 26743.000 GIT 10123/2009 720.700 GIT 10/2112009 NO TL 10/09/2009 0.614 IMetPw 10120/2009 <25.000 CLM
•1 012012009 ND MAD 10/13/2009 ND LL 10/08/2009 112400 CLM 10/14/2009 104800 ALD 10/13/2009 472 enchmat 10/30/2009

* Comments: Radiologicals done by Benchmark Analytical Note: DEP Certification
#s 32-00382

09 29510 WasteWater Grab NEW (Client) Hall8431
H Units mgfl mgfl mgfl mgfl mg/1- mgfl mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mg/1 mglkg · mg/1 mg/1 uS/em mg/1 mg/1 mg/1 Data Qualifiers:

D = The reported value is from dilution.

E = Estimated value

. S = Surrogate out of control limits. Method RPL 200.7/6010 1.000 200.7/6010 1.000 200.7/6010 0.500 200.7/6010 50.000 200.7/6010 50.000 200.7/6010

0
. 500 245.1 0.0002 200.7/6010

0 . 500 200.7/6010 0.500 200.7/6010 1.000 200.7/6010

0 . 500 200.7/6010 500.000 200.7/6010 1.000 200.7/6010 0.500 SM5540C 0.200 300.0M 25.000 1664A 5.0 420.1 0.500 SM2510B

1 SM2540C

25 SM2540D

5 RAD-CTDHS 0.000 \ND=Not Detected R = Sample received out of holding time.
H = Sample analyzed out of holding time.
C = Sample received
in incorrect container. B = Analyte was detected
in both sample and methods blank.
x = User defined data qualifier

.4.Vt' UV, .. VVV .&.V

t .. .., **a'~** VcA-VV

t -,r.VcA-Y .. l:.AB ID #: 39-Q0401 SEND DATA TO: NAME: Mike Moyer BENCHMARK ANAL YTICS, INC. 4 777 Saucon Creek Road Center Valley, PA 18034-9004 PHONE (610) 974-8100 FflU<(610)974:8104 COMPANY: EnVironmental Service Laboratories, Inc ADDRESS: 1803 Philadelphia
St PHONE: FAA: Indiana, PA 15701 (724) 463-8378 (724) 465-4209 09 29350 & 09 29510 RECEIVED FOR LAB BY: DMB TEST REPORT DATE: 10/121200910:00

lt!JVVl. Work Order: 09101656 WO#: 09101656 PAGE: 2of2 PO#: DAS10092009 PWSIO# Page2 Clf2 SAMPLE: 09 29510

Lab 10: 091016fi6.002E Grab SAMPLED BY: David A. Stl1e Sample T.me 10/0812009 9:15 Bm!l **~ ~**  Y!l!!! Thorium

< 0.0131

:t 0.00

0 mgiL Method EPA200.8 W, 61la!Ys's Start Analysis End Analyst

• 10113/09 8:30 10/16109 GSR-CV ·--- SAMPLE: 09 29510

Lab 10: 091016S6-002A Grab SAMPLED BY: David A. Stile Sample Time 1010812009 8:15 Result **~** Y2A Units **~** EPA900.0 EPA900.0 1971

:t 221.3 746.9 pCIIl 2285

t 140

. 7 682.4 pClll --·-- ---- SAMPLE: 09 29510 SAMPLED BY: David A. stile :nm Bm!J1 Radlum-226 464.9 ---··---- SAMPLE: 09 29510 SAMPLED BY: DavieS A. Stile
LabiO: **09101~** Sample nne 1010812009 9:15 ll!g[t MQA Units Mdm :1: 1 5.84 59.4 **pC~** EPA 903.0 Lab 10: 09101656-002C Sample Tme 1010812009 9:15 3m Redium-228 **~~MQ6~** 148.7

:t 11.10 14.16 pCiiL EPA904.0 MQb Al!atnis Slatt Analysis End **~** 10/13109 8:50 10116109 BPS..CV 10113m 8:50 10116109 BPS.CV --------· Grab fl4g. Analysis Start M!!tysl$ End **~** 1011610911:15 10129109 BH-cv Glib G Analy!;is Start A!!atniS End **~n!** 10121109 8:05 10/27109 NLB-CV · -------

· ------ SAMPLE: 09 29510 SAMPLED BY: David A. Stile

Lab ID:
· **0910165~** Sample Tine 1010812009 9:15 Grab !tit Result **~** MDA **~ ~**  MCL Anatvsls Start Anatnis End 6nilYi1.! Uranium

< 13.13
f; 0.00

0 l!QIL MS EPA200.8

30 10119109 10:00 **Ur.~nlum** <8.93

:1: 0.00

0 pCill. EPA200.S 10/19109 10:00 · · --··-

·

..

· --·

· "··- REMARKS: The above test procedures meet all the requirements

of NELAC and relate only to these samples

. .. CV =Benchmark An<!lytiCS, Inc. Center Valley, PA; SA= Benchmark **An<~lytics,** Inc. Sayre, PA MS Umit of detection increased duo to matrix interference and spike recovery csata MANAGER Wf!Jd ··--

-
.

·-
DATE: 10123109 GSR..CV 10123109 GSR-CV ·· · --- 1013012009---- **---~-**
-- ------- **s;N\iiDONi\Ji~NT4**

CL -

I ... Y I i'-.....,...

I ... I Y I - I 11 II

' SERVICE LABORATORIES, INC. 1803 Philadelphia Street Indiana, PA 15 701 (724)-463-TEST
FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: 1) Benzene 47) Toluene XTOEnergy 395 Airport Road Indiana, PA 15701 10/8/2009 9:15AM 10/8/2009 2:42PM 10/3012009 Analyte Report of Analysis SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO 10/09/2009 26.40 RO 10/0912009 ND Comments: Radiologicals done by Benchmark Analytical . Note: DEP Certification
#s 32-00382

09 29510 Waste Water Grab NEW (Client) Hall8431 H Units ug!L ugfL Data Qualifiers:

D :::: The reported value is from dilution

. E = Estimated value

. S = Surro_gate out of control limits. Method RPL 624/8260B 20.00 624/8260B 20.00 \ND=Not Detected R = Sample received out of holding time

. H = Sample analyzed out of holding time

. C = Sample received
in incorrect container. B = Analyte was detected
in both sample **~nd** methods blank.
x = User defined data qualifier.-- -- --" - - -- --- -- - - i= NVi **~i"ONE\ii** !=NT 4. i - I "W Y I 1'- **~**
I 'WI Y I -I 'W II ,_ SERVICE LABORATORIES, INC. 1803 Philadelphia Street, Indiana, PA 15 701 i724)-463-TEST
FAX (724)-465-4209 Name: XTOEnergy Sample Start Date: 395 Airport Road Indiana, PA 15701 10/812009 10/8/2009 2:42PM 10/1212009 Receipt Date: Report Date: Analyte 1) Benzene 47) Toluene Comments: DEP Certification
#s 32-00382 Report of Analysis Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO 10/09/2009 ND RO 10/09/2009 ND
09 29511 Waste Water Grab NEW (Client) Trip Blank Units ug!L ug/L Method MDL 624/8260B 1.00 624/8260B 1.00 fD=Not Detected· 2540-PM-8WM0347 Rev.112011 **tF~'!.~~** COMMONWEALTH
OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WASTE MANAGEMENT FORM 26R CHEMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT BY THE GENERA TOR This fonn must be fully required must typed or legibly printed In the spaces provided.

If additional space Is necessary, Identify each attached sheet as Fonn 26R, reference the Item number and Identify the date prepared. The date on attached sheets needs to match the date noted below. · General Reference 287.54 Date Prepared/Revised 219/11 c. Appearance
County Indiana Number of Solid or Uquid Phases of Separation Une2

10# Describe each phase of separation

. **.::!I.:~---------------;** - 1 -2540-PM-BWM0347Rev.1/2011c.AddressUne1AddressUne1AddressCityStateZIPMunicipalityTitlePhoneNamed.vn•..•rr•..ofwasteshippedtoprocessingorb.FacilityNameAddressUne1AddressUne1AddressCityStateZIPMunicipalityc.NameTitlePhoneb.0cuyd181galtoprocessingordisposalfacility0cuyd0gal0lb0gal-2-CountyIndiana(checkone)0ton(checkone)2540-PM-BWM0347 Rev.1/2011 I certify, under penalty of law, that

I have personally examined and am familiar with the Information submitted
in this Annual Report and all attached documents and that baaed upon my Inquiry of those Individuals Immediately responsible for obtaining the lnfonnation,

I verify that the submitted Information

Is true, accurate and complete to the best of my knowledge.

I understand that the submission
of false infonnation herein is made subject to the penalties of 18 Pa. C.S. §4904, relating to unsworn falsification
to authorities, which Include fine and imprisonment Check the following,

If applicable: 0

I certify the lnfonnation required In Section B-1, General Properties was supplied to the Department for the year __ and has not changed. Fonn Submitted:

0 Form26R 0 Other (specify) Date Submitted: 0

I certify the information required In Section B-2, Chemical Analysis was supplied to the Department for the year _and has not changed. Form Submitted:

0 Form 26R 0 Other {specify) Date Submitted: O

I certify the Information required In Section **~.** Process Description and Schematic, was supplied to the Department for the year __ and has not changed. Form Submitted:

0 Form 26R Date Submitted: Name of Responsible Official Bernhardt Kissel Signature

0 Other (specify)
Title EH & S **~** 2-28-11 -3-February
8, 2011 Form 26R: Section 82b WASTE SAMPLING METHODS

I• All samples were obtained as grab type samples with a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are composited within the storage production tank or tank battery at each well site where gas production

is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP permitted waste disposal facilities on different schedules determined by individual well characteristics. Grab samples of the composited fluids were obtained at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. Samples were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives,
as necessary, depending on the specific test run requested

. All chain of custody and handling/holding time requirements were met. In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. Flowback samples were composited
to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion
of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives,
as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process at various times and combined into a composite sample for analyses at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites.

In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness
of the composite sample and composite grid sample positions were varied to the extent possible. Pit water (drill fluid) is currently discharged
to closed containment and is re-conditioned and reused from well to well.i · February
9, 2011 Form 26R: Section B3a WASTE GENERATION PROCESS Pit Water "Drill Fluids• Remnant drill fluids are generated

in the well bore during the penetration
of the drill stem as it intercepts both ground water and formation fluids. These fluids are brought to the surface along with the drill cuttings, pieces of the intercepted rock strata, by the return flow system of the drilling process. Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. Fluids are currently stored in closed containers
to be processed for reuse. Flowback: "Fracing Fluid" Flowback
is produced from all fluids that flow back to surface during the "hydrofracing" process which occurs under pressure and results in the setting of a propant within the formation fractures. Production Fluid "Brine" During the production of natural gas, formation pressures bring remnant frac fluids, during the initial production phase, and formation fluids to the surface along with produced gas.Well I. D.# (various) Well I. · D.# . (various) \\/ )J( **~0~ ~~~**  COUNTY A I \ I \ / Well I. D.# (various) \ I **~()/** \ I /II' \ I / \ I // \ I // . \ I / Well I. D.# (various) \ 1 // \\/ / \ I / -a- ,_ " ,.....---

COUNTYB / **~o~--** (

**~** (/"I FI.,..,L....\<.

**~7 eot?o'to~**  Mobile Tank Truck 'fr-ocSlvc.:\-toJ\ **Ocu1\\~~~** \OAI-S : • ( ]{ S brine (1YP.) ote: Process producing waste: Gas well produced fluids (brines) are typically produced · in conjuction with natural gas. These fluids are brought to the surface utilizing either mechanical or physical lift procedures.

_ s Road Transport ----Landfill or' Tre.u. + t..\

**<.~·J** '? l(AA t

(.') **~ ~**  w :c () (/) z 0 **~ ~**  0 0.. (/) **·~** 1- **~~ 8~**  **~** ..... - **~ ~**  **~ ~~**  **~~ ~**  **~~** rn **~** 1 **~ :i~**  .. ffi i **~** I i **s~**TESTING Environmental and Ene

r gy Analysis Friday, February 04, 2011 RICK BONAZZA RESOURCE MANAGEMENT SERVICES 65 FENTON ROAD INDIANA, PA 15701 RE: 26R Analysis Dear RICK BONAZZA: OrderNo.: G1012347 Geochemical Testing received

1 sample(s) on 12/10/2010 for the analyses presented in the following report. There were no problems with the analyses and all QC data met NELAC, EPA, and laboratory specifications except where noted in the Case Narrative or Laboratory Results. If you have any questions regarding these tests results, please feel free to call. Sincerely, Timothy W. Bergstresser Director of Technical Services Page
1 of 6

2005 N Center Ave Somerset PA 15501 814/443-1671 814/445

- 6666 FAX: 814/445-6729 **~** &

**~** <

X I 0. 56·00306 PA DEPGeochemical Testine CLIENT: Project: Lab Order: RESOURCE MANAGEMENT SERVICES 26R Analysis 01012347

Date: 04-Feb-11 CASE NARRATIVE No problems were encountered during analysis of this workorder, except if noted in this report. REVISED REPORT (2/4/11): Sample description changed. The ethylene glycol analysis was subcontracted

to Free Col. A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. The radiological analysis was subcontracted

to Pace Analytical.

A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. Legend

: ND- Not Detected
at the Quantitation Limit J - Indicates an estimated value. U - The analyte was not detected
at or above the listed concentration, which is below the laboratory quantitation limit. B - Analyte detected
in the associated Method Blank Q- Qualifier QL -Quantitation Limit OF- Dilution Factor S - Spike Recovery outside accepted recovery limits R - RPD outside accepted recovery limits E- Value above quantitation range ** -Value exceeds Action Limit H - Method Hold Time Exceeded MCL- Contaminant Limit

J.D

. 56-00306 PA DEP Page 2 of 6Laboratory Results Geochemical Testing

Date: 04-Feb-11 CLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES 01012347

Client Sample ID: HCPP Weli8421H RMS 3/12/8 Project: 26R Analysis Lab ID:

G 1012347-001 Matrix: AQUEOUS Analyses
Result INORGANIC NON-METALS Acidity to pH 8.2

240 INORGANIC NON-METALS Alkalinity
to pH 4.5

85 PHYSICAL TESTS Specific Conductance
156000 PH BY SM 4500 H+B Lab pH

5.90 INORGANIC NON-METALS Total dissolved solids 150000 PHYSICAL TESTS Total suspended solids

128 INDICATOR ORGANIC PARAMETERS BOD 5-<lay Finish DatefTime REACTIVE CYANIDE Reactive cyanide

350 12/15/201012

: 55 < 0.25 INDICATOR ORGANIC PARAMETERS Chemical Oxygen Demand

5900 INORGANIC NON-METALS Bromide

734 Chloride

84300 Sulfate

< 100 INORGANIC NON-METALS MBAS

0
. 057 NOTES:

Sampled By: Client Collection Date: 12/8/2010 2:50:00 PM Received Date: 12/10/2010 7:56:45 AM QL Q Units SM 2310B(4A) 0 mg/L CaC03 SM 18 23208 5 mg/L CaC03 EPA 120.1 IJmhos/cm SM4500-H+B 0 su SM 2540 C 20 mg/L SM 2540D 5 mg/L SM 5210 B 60 mg/L 0 mg/L SW846CH.7 0.25 mg/Kg HACH 8000 100 mg/L EPA300.0 40.0 mg/L 200 mg/L 100 mg/L SM 5540C 0.050

s mg/L as LAS DF 60 60 Date Analyzed Analyst: LNW 12116/2010 8:27:00 AM Analyst: LNW 12/15120101

: 43

: 00 PM Analyst: LNW 12/15/2010

1 : 43:00 PM Analyst: LNW 12115/20101

: 43:00 PM Analyst: KLS 12/10/2010
10

: 02:00 AM Analyst: KLS 1211012010

6
: 57:38 AM Analyst: MMR 12110/2010 1:00:00 PM 12110/20101

: 00:00 PM Analyst: SAG 12/15/2010

7
: 13:00 PM Analyst: MGV 10 12115/2010 Analyst: CAS 200 12117/20106

: 54:00 PM 200 12117/2010

6
: 54:00 PM 50 12/16/2010 10:07

: 00 PM Analyst: MMR 12/10/2010
10

: 05

: 00 AM S - Spike recovery indicates

a possible matrix effect

. The method
is in control as indicated by the LCS

. INORGANIC NON-METALS Ammonia Nitrogen

- Distilled

98

. 2 INORGANIC NON-METALS Nitrate

- Nitrite

0
. 73 INDICATOR ORGANIC PARAMETERS Phenolics

< 100 REACTIVE SULFIDE

EPA 350.1 5
. 00 EPA 353.2 0
. 05 EPA420.1 100 SW846 CH.7 Paae 3 of6 mg/L as N mg/L as N IJg/L Analyst: SLY 50 12/22/2010
11

: 01 :48 AM Analyst: SLY 12/16/2010

9
: 04:00 AM Analyst: SAG 5 12/17/20101:11:00
PM Analyst: MMR 1.0

. 56-00306 PA DEPLaboratoryResultsGeochemicalTestingDate:04-Feb-11--·--------·-···-··-·--------·-----·-------------CLIENT:LabOrder:RESOURCEMANAGEMENTSERVICES01012347ClientSampleID:HCPPWell8421HRMS3/12/8Project:26RAnalysisLabID:01012347-001Matrix:AQUEOUSAnalysesREACTIVESULFIDEReactivesulfideINORGANICNON-METALSTotalKjeldahlNitrogenINORGANICMETALSIron,dissolvedINORGANICMETALSMercuryINORGANICMETALSAluminumArsenicBariumBerylliumBoronCadmium,CalciumChromiumCobaltCopperIronLeadLithiumMagnesiumManganeseMolybdenumNickelSeleniumSilverSodiumStrontiumZincHardness(SM2340B)INORGANICMETALSThoriumUraniumHERBICIDEANALYSIS2,4,5-T2,4-DResult0.90126108<0.20<0.2<0.026960<0.00116.10.018144000.04<0.005<0.01135<0.0412215205.94<0.02<0.01<0.02<0.0053740038400.1142100<50.0<50.0<5.0<20SampledBy:ClientCollectionDate:12/8/20102:50:00PMReceivedDate:12/10/20107:56:45AMQLQUnitsSW846CH.70.25mg/KgEPA351.210.0mg/LasNEPA200.70.05mg/LSM311280.20IJg/LEPA200.70.20.0210.00.0011.000.00210.00.010.0050.010.050.0410.010.00.010.020.010.020.00520.05.000.01100EPA200.850.050.0EPA81515.020mg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/LCaC03IJg/LIJg/LIJg/LIJQILDF102110001201100125001001005001005050100100DateAnalyzedAnalyst:MMR12/13/20101:45:00PMAnalyst:SLY12/21/20102:36:03PMAnalyst:MS12/20/20101:43:00PMAnalyst:MS12114/201012:59:10PMAnalyst:MS12/21/201011:26:00PM12/16/20102:05:00PM12/20/20101:43:00PM12/16/20102:05:00PM12/17/20104:47:00PM12/16/20102:05:00PM12/17/20104:42:00PM12/16/20102:05:00PM12/16/20102:05:00PM12/16/20102:05:00PM12/16/20102:05:00PM12/21/201011:26:00PM12/17/20104:38:00PM12117/20104:42:00PM12/16/20102:05:00PM12/16/20102:05:00PM12/16/20102:05:00PM12/16/20102:05:00PM12/16/20102:05:00PM12/17/20104:42:00PM12/17/20104:38:00PM12/16/20102:05:00PM12/17/20104:42:00PMAnalyst:JEK12/20/201010:28:00AM12/16/20101:09:00PMAnalyst:TEW12/17/20106:53:00PM12/17/20106:53:00PM--·------------------·---------------------------------------·-·-------------------------------·--·-I.D.56-00306PADEPPaqe4of6Laboratory Results Geochemical Testing

Date: 04-Feb-11 CLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES 01012347

Client Sample ID: HCPP Weii8421H RMS 3/12/8 Project: 26R Analysis Lab ID: 01012347-001 Matrix: AQUEOUS Analyses HERBICIDE ANALYSIS Silvex Surr: 2,4-Dichlorophenyl acetic acid PESTICIDE ANALYSIS Chlordane Dieldrin Gamma BHC (lindane) Heptachlor epoxide Methoxychlor Toxaphene Surr

: Decachlorobiphenyl Surr

: Tetrachloro-m-xylene SEMI-VOLATILE COMPOUNDS 2,4,5- Trichlorophenol 2,4,6- Trichlorophenol 2,4-Dinitrotoluene 2-Methylphenol Hexachlorobenzene Hexachlorobutadiene Hexachloroethane Nitrobenzene Pentachlorophenol Pyridine 3,4-Methylphenol Surr

: 2,4,6-Tribromophenol Surr

: 2-Fiuorobiphenyl Surr

: 2-Fluorophenol Surr

: Nitrobenzene-d5 Surr

: Phenol-d6 Surr

: p-Terphenyl-d14 VOLATILE ORGANIC COMPOUNDS 1 , 1-Dichloroethene 1 , 2-Dichloroethane 1 A-Dichlorobenzene Benzene Carbon Tetrachloride Chlorobenzene Methyl Ethyl Ketone Tetrachloroethane Toluene

Sampled By: Client Collection Date: 12/8/2010

2 : 50:00 PM Received Date: 12/10/2010

7 : 56:45 AM Result < 5
. 0 65.5 < 5
. 0 < 0.25 < 0
. 25 <0

. 25 < 0
. 25 < 10 85

. 3 71.5 < 93 < 93 < 93 < 93 < 93 < 93 < 93 < 93 < 470 < 470 < 93 74

. 8 45

. 6 61.5 3
. 70 63

. 7 33

. 2 QL Q Units EPA 8151 5.0 **~ll** 28

. 5-130 %REC EPA8081 5
. 0 **~g/l** 0.25 **~g/l** 0
. 25 **~g/l** 0
. 25 **~g/L** 0
. 25 **~g/l** 10 **~g/l** 5-156 %REC 15

. 9-102 %REC EPA8270 93 **~g/l** 93 **~g/l** 93 **~g/L** 93 **~g/l** 93 **~g/L** 93 **~g/L** 93 **~g/l** 93 **~g/l** 470 **~g/L** 470 **~g/l** 93 **~g/L** 5-137 %REC 27.7-95.1 %REC 5 - 104 %REC 16-101

S %REC 5-106 %REC 25.4-133 %REC EPA8260 < 1
. 0

1 . 0 **~g/l** < 1
. 0

1
. 0 **~g/l** < 1 . 0 1.0 **~g/l** < 1
. 0

1 . 0 **~giL** < 1 . 0 1.0 **~g/l** < 1 . 0

1
. 0 **~g/L** < 5.0 5.0 **~g/l** <1

. 0

1 . 0 **~g/l** < 1.0 1.0 **~g/l** Page 5 of6

DF 100 100 5 5 5 5 5 5 5 5 9
. 35 9
. 35 9.35 9
. 35 9
. 35 9.35 9
. 35 9.35 9
. 35 9
. 35 9
. 35 9
. 35 9.35 9
. 35 9.35 9
. 35 9.35 Date Analyzed Analyst: TEW 12/17/2010

6
: 53

: 00 PM 12/17/2010 6:53:00 PM Analyst: TEW 12/16/2010
10

: 08

: 00 PM 12/16/2010 10:08

: 00 PM 12/16/2010
10

: 08

: 00 PM 12/16/2010 10:08

: 00 PM 12/16/2010 10:08:00 PM 12/16/2010 10:08

: 00 PM 12/16/2010 10:08

: 00 PM 12/16/2010 10:08

: 00 PM Analyst: JB 12/19/2010 5:39

: 00 PM 12/19/2010

5
: 39

: 00 PM 12/19/2010 5:39:00 PM 12/19/2010

5
: 39

: 00 PM 12/19/2010

5
: 39:00 PM 12/19/2010

5
: 39

: 00 PM 12/19/2010 5:39:00 PM 12/19/2010

5
: 39:00 PM 12/19/2010 5:39

: 00 PM 12/19/2010 5:39

: 00 PM 12/19/2010 5:39

: 00 PM 12/19/2010

5
: 39

: 00 PM 12/19/2010 5:39

: 00 PM 12/19/2010 5:39

: 00 PM 12/19/2010 5:39:00 PM 12/19/2010

5
: 39

: 00 PM 12/19/2010

5
: 39

: 00 PM Analyst: JAW 12/14/2010 8:19:00 AM 12/14/2010

8
: 19

: 00 AM 12/14/2010 8:19

: 00 AM 12/14/2010

8
: 19

: 00 AM 12/14/2010 8:19

: 00 AM 12/14/2010

8
: 19

: 00 AM 12/14/2010

8
: 19

: 00 AM 12/14/2010

8
: 19

: 00 AM 12/14/2010 8:19

: 00AM I. D . 56-00306 PA DEPLaboratory Results Geochemical Testing

Date: 04-Feb-11 CLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES 01012347

Client Sample ID: HCPP Wel18421H RMS 3/12/8 Project: 26R Analysis Lab ID:

G 1012347-001 Matrix: AQUEOUS Analyses VOLATILE ORGANIC COMPOUNDS Trichloroethane Trichloromethane Vinyl Chloride Surr

: 1 ,2-Dichloroethane-d4 Surr

: 4-Bromofluorobenzene Surr: Dibromofluoromethane Surr

: Toluene-dB INDICATOR ORGANIC PARAMETERS Oil & Grease NOTES:
Result < 1.0 < 1.0 < 1
. 0 111 101 104 105 101 QL Q EPA8260 1 . 0 1.0 1 . 0 70-130 7Q-130 70-130 70-130 EPA 1664 5 J Sampled By: Client Collection Date: 12/8/2010 2:50:00 PM Received Date: 12/10/2010 7:56:45 AM Units ).19/l IJQ/L ).19/L %REC %REC %REC %REC mgll
DF 1.02 Date Analyzed Analyst: JAW 12/14/2010

8
: 19:00 AM 12114/2010 8:19:00 AM 12114/2010

8
: 19

: 00 AM 12/14/2010 8:19:00 AM 12/14/2010

8
: 19

: 00 AM 12/14/2010 8:19

: 00 AM 12/14/2010

8
: 19

: 00 AM Analyst: JDH 12/14/2010

8
: 42

: 00 AM J - Unable to obtain
a stable weight within specified limits due to sample matrix

. Value is estimated

. VOLA TILE ORGANIC COMPOUNDS

EPA 8015
Analyst: SUB Ethylene Glycol

< 11

11 mgll 12/22/2010 RADIOLOGICAL TESTING EPA900.0
Analyst: SUB · Gross Alpha
10200 +- 2251 3.00 pCill 12/18/2010 Gross Beta

812 +- 782

4

. 00 pCi/L 12/18/2010 RADIOLOGICAL PARAMETERS

EPA 903.1
Analyst: SUB Radium 226

3854 +-717 1.00 pCi/L 12/28/2010 RADIOLOGICAL PARAMETERS EPA904.0
Analyst: SUB Radium 228

784 +- 181 1.00 pCi/L 117/2011 INORGANICS NON-METALS EPA9040
Analyst: GAK Corrosivity Characteristic

5.63 1.00
su 12/13/2010 FLASH POINT

EPA 1010 Analyst: RLL Flashpoint

>200

10

. 0 OF 12/13/2010 1.0

. 56-00306 PA DEP Page 6 of 6**2540-f~M-e\WGS4T** Rev.112011 **~pennsylvania** - DEFAA'IMEHT Of ENVIRONMENTAL PROTECTION COMMONWEALlli
OF PENNSYLVANIA DEPARTMENT OF ENVIRONMENTAL PROTECTION BUREAU OF WASTE MANAGEMENT FORM26R CHEMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT BY THE GENERA TOR must
required lnfonnation must be **~~~~=** typed or legibly printed In the spaces provided.

If additional space Is necessary, identify

I each attached sheet as Form 26R, reference the Item number and Identify the date prepared. The date on attached sheets needs to match the date noted below. General Reference 287.54 Date Prepared/Revised 219111

EPA Generator Ext c. Appearance

- 1 -2540-PM-BWM0347 Rev.1/2011 a. a. b. c. d. a. b. c. d. a. Name Address Une 1 Address Une
1 Address City State ZIP Municipality Phone Address Une
1 Address Une 1 Address City State ZIP Municipality Title Phone

to processing or 0 cu yd 181 gal .. u •• u ..... of waste shipped to processing or 0 cuyd
0 gal Indiana Email Address steve@pabrine.com year. 0 lb 0 ton (check one) being utilized. Email Address previous year. 0 lb 0 ton (check one) 0 ton (check one) -2-2540-PM-BWM0347 Rev. 112011 I certify, under penalty of law, that

I have personally examined and am familiar with the lnfonnation submitted
In this Annual Report and all attached documents and that based upon my Inquiry of those Individuals Immediately responsible for obtaining the infonnation,

I verify that the submitted Information

Is true, accurate and complete to the best of my knowledge.

I understand that the submission
of false infonnation herein is made subject to the penalties of 18 Pa. C.S. §4904, relating to unsworn falsification
to authorities, which Include fine and Imprisonment Check the following,

if applicable: 0

I certify the infonnation required In Section B-1, General Properties was supplied to the Deparbnent for the year _and has not changed. Fonn Submitted:

0 Fonn 26R 0 Other (specify) Date Submitted: 0

I certify the infonnation required In Section B-2, Chemical Analysis was supplied to the Deparbnent for the year _and has not changed. Fonn Submitted:

0 Fonn 26R 0 Other (specify) Date Submitted: 0

I certify the lnfonnation required In Section **B~.** Process Description and Schematic, was supplied to the Deparbnent for the year_ and has not changed. Fonn Submitted:

0 Fonn 26R 0 Other {specify) Date Submitted: Name of Responsible Official Bernhardt Kissel Signature

Date

1 -3-February
8, 2011 Form 26R: Section B2b WASTE SAMPLING METHODS

I• All samples were obtained as grab type samples with a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are composited within the storage production tank or tank battery at each well site where gas production

is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank(s} and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP permitted waste disposal facilities on different schedules detennined by individual well characteristics. Grab samples of the composited fluids were obtained at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. Samples were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives,
as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. Flowback samples were composited
to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion
of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives,
as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process at various times and combined into a composite sample for analyses at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Fonnation and separate testing was completed on both sample composites.

In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness
of the composite sample and composite grid sample positions were varied to the extent possible. Pit water (drill fluid} is currently discharged
to closed containment and is re-conditioned and reused from well to well.February9,2011·Form26R:SectionB3aWASTEGENERATIONPROCESSPitWater"DrillFluids"Remnantdrillfluidsaregeneratedinthewellboreduringthepenetrationofthedrillstemasitinterceptsbothgroundwaterandformationfluids.Thesefluidsarebroughttothesurfacealongwiththedrillcuttings,piecesoftheinterceptedrockstrata,bythereturnflowsystemofthedrillingprocess.Drillcuttingsanddrillfluidsareisolatedintoseparatewastestreams.Cuttingsaremixedwithsawdusttoabsorbremnantfluidandloadedoutfordisposalatalandfill.Fluidsarecurrentlystoredinclosedcontainerstobeprocessedforreuse.Flowback:"FracingFluid"Flowbackisproducedfromallfluidsthatflowbacktosurfaceduringthe"hydrofracing"processwhichoccursunderpressureandresultsinthesettingofapropantwithintheformationfractures.ProductionFluid"Brine"Duringtheproductionofnaturalgas,formationpressuresbringremnantfracfluids,duringtheinitialproductionphase,andformationfluidstothesurfacealongwithproducedgas.Well I. D.# (various) Well I.D.# . (various) ,,/

**~**

-0 -y- **/~,** /1' I\ I \ / Well I.D.# (various) \ I **:::b~** \ I //I \ I / \ I // \ I // . . \ I / Well I. D.# (various) \ I // '\/ / \ I / -o- / " ,---- / **~o----** ( . **~** ()" _..

**fl"""~~ ~~**  **~o'2o~** Mobile Tank Truck **~f"O~\X..·h~J\ Ocut\-\~~-:-** 

COUNTY A - COUNTYB \OAt,..S :: ( _ s Road Transport

0i UJ :c (.) en z 0 **~** 1- a:: 0 a.. (/) **·~** 1- **~~ J~**  5 brine (TYP.) Landfill o.- U . Trec..fO{<OAf ?lwJ · **~** j ;, Note: . Process producing waste: Gas well produced fluids (brines) are typically produced in conjuction with natural gas. These fluids are brought to the surface utilizing either mechanical or physical lift procedur . es.

**~ ~!**  rn **~ ~**  **~ l~**  I i . z**~**

### GEOCHEMICAL TESTING Environmental and Energy Analysis Friday, February 04, 2011 RICK BONAZZA RESOURCE MANAGEMENT SERVICES 65 FENTON ROAD INDIANA, PA 15701 RE: 26R Analysis Dear RICK BONAZZA: OrderNo.:

G1012348 Geochemical Testing received

I sample(s) on 12/10/2010 for the analyses presented
in the following report. There were no problems with the analyses and all QC data met NELAC, EPA, and laboratory specifications except where noted in the Case Narrative or Laboratory Results. If you have any questions regarding these tests results, please feel free to call. Sincerely, Timothy W. Bergstresser Director of Technical Services

2005 N Center Ave Somerset PA 15501 814/443-1671 814/445-6666 FAX

: 814/445-6729Geochemical Testin2 CLIENT: Project: Lab Order: RESOURCE MANAGEMENT SERVICES 26R Analysis GIOI2348

Date: 04-Feb-1

I CASE NARRATIVE No problems were encountered during analysis of this workorder, except if noted in this report. REVISED REPORT (2/4/11): Sample description changed. The ethylene glycol analysis was subcontracted

to Free Col. A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. The radiological analysis was subcontracted

to Pace Analytical.

A copy of the subcontractor's laboratory report is enclosed with this Analytical Report. Legend: ND -Not Detected at the Quantitation Limit J - Indicates an estimated value

. U - The analyte was not detected at or above the listed concentration, which is below the laboratory quantitation limit. B - Analyte detected in the associated Method Blank Q- Qualifier QL -Quantitation Limit DF- Dilution Factor S- Spike Recovery outside accepted recovery limits R- RPD outside accepted recovery limits E - Value above quantitation range **-Value exceeds Action Limit H - Method Hold Time Exceeded MCL- Contaminant Limit

J.D

. 56-00306 PA DEPLaboratory Results Geochemical Testing

Date: 04-Feb-11 ====================-

· -- CLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES G1012348

Client Sample ID: HCPP Well 8422H RMS2112/8 Project: 26R Analysis
Sampled By: Client Lab ID: GI012348-001 Collection Date: 12/8/2010

2 : 20:00 PM Matrix: AQUEOUS
Received Date: 12/10/2010 8:26:06 AM ---------

- --- -- --- ----- ---- ---·-·

- --
· . -··· ····
· -- --- Ana!yses
Result INORGANIC NON-METALS Acidity to pH 8.2

320 INORGANIC NON-METALS Alkalinity
to pH 4.5

<5 PHYSICAL TESTS Specific Conductance
180000 PH BY SM 4500 H+B Lab pH

4
. 26 INORGANIC NON-METALS Total
d
i ssolved solids 189000 PHYSICAL TESTS Total suspended solids

66 INDICATOR ORGANIC PARAMETERS BOD 5-day

7 Finish Date/Time 12/15/2010 12:55 INDICATOR ORGANIC PARAMETERS Chemical Oxygen Demand 11000 INORGANIC NON-METALS

· Bromide

894 Chloride
107000 Sulfate

< 100 INORGANIC NON-METALS MBAS

0.23 INORGANIC NON-METALS Ammonia Nitrogen

- Distilled

122 INORGANIC NON-METALS Nitrate

• Nitrite

0.52 INDICATOR ORGANIC PARAMETERS Phenolics

< 100 INORGANIC NON-METALS Total Kjeldahl Nitrogen

115 INORGANIC METALS Iron

, d

i ssolved

87

. 3 INORGANIC METALS

QL Q Units SM 23108(4A) 0 mg/L CaC03 SM 18 23208 5 mg/LCaC03 EPA 120.1 tJmhos/cm SM4500-H+B 0 su SM 2540 C 100 mg/L SM 2540D 5 mg/L SM 5210 B 3 mg/L 0 mg/L HACH 8000 100 mg/L EPA 300.0 40.0 mg/L 200 mg/L 100 mg/L SM 5540C 0.050 mg/L as LAS EPA 350.1 5
. 00 mg/Las
N EPA 353.2 0.05 mg/L as N EPA420.1 100 IJQ/L EPA 351

. 2 10.0 mg/L as N EPA 200.7 0.05 mg/L SM 31128

D F Date Analyzed Analyst: LNW 12/16/2010 8:44

: 00 AM Analyst: LNW 12/15/2010

4
: 49

: 00 PM Analyst: LNW 12/15/2010

4
: 49

: 00 PM Analyst: LNW 12/15/2010

4
: 49

: 00 PM Analyst: KLS 5 12/10/2010
10

: 02:00 AM Analyst: KLS 12/10/2010

6
: 57

: 40 AM Analyst: MMR 3 12/10/2010

1 : 00

: 00 PM 3 12/10/2010

1 : 00

: 00 PM Analyst: MGV 10 12/15/2010 Analyst: CAS 200 12/17/2010

7
: 12

: 00 PM 200 12/17/2010

7
: 12

: 00 PM 50 12/16/2010
10

: 24

: 00 PM Analyst: MMR 12/10/2010
10

: 05:00 AM Analyst: SLY 50 12/22/2010

11

: 02

: 56 AM Analyst: SLY 12/16/2010 9:05

: 07 AM Analyst: SAG 5 12/17/20101

: 31

: 00 PM Analyst: SLY 10 12/21/20102:38

: 20PM Analyst: MS 12/20/20101

: 47

: 00 PM Analyst: MS ---------------------------------------------------

- ----

- - I . D . 56-00306 PA DEP n---

" _.r rLaboratoryResultsGeochemicalTestingDate:04-Feb-1I··-----··-NOoO-----··--..··--···------CLIENT:RESOURCEMANAGEMENTSERVICESClientSampleID:HCPPWell8422HLabOrder:01012348RMS2/12/8Project:26RAnalysisSampledBy:ClientLabID:GIOI2348-00ICollectionDate:12/8/20102:20:00PMMatrix:AQUEOUSReceivedDate:12/10/20108:26:06AMAnalysesResultQLQUnitsDFDateAnalyzedINORGANICMETALSSM31128Analyst:MSMercury<0.200.20IJQ/L12/14/20101:01:23PMINORGANICMETALSEPA200.7Analyst:MSAluminum0.20.1mg/L12116/20108:17:00PMArsenic<0.020.02mg/L12116/20108:17:00PMBarium932010.0mg/L100012129/20105:14:00PMBeryllium<0.0010.001mg/L112/16120108:17:00PMBoron16.20.50mg/L1012/22120101:08:00AMCadmiumO.o160.002mg/L12/16/20108:17:00PMCalcium2050010.0mg/L100121221201012:51:00AMChromium<0.010.01mg/L12116/20108:17:00PMCobalt0.7470.005mg/L12/16/20108:17:00PMCopper0.020.01mg/L12116/20108:17:00PMIron1120.05mg/L12116/20108:17:00PMLead<0.020.02mg/L12/16/2010.8:17:00PMLithium1174.00mg/L20012/29/20106:04:00AMMagnesium222010.0mg/L10012/221201012:51:00AMManganese6.700.01mg/L12116/20108:17:00PMMolybdenum<0.020.02mg/L12116/20108:17:00PMNickel<0.010.01mg/L12116120108:17:00PMSelenium<0.020.02mg/L12116/20108:17:00PMSilver<0.0050.005mg/L12116/20108:17:00PMSodium57800100mg/L50012129/20106:00:00AMStrontium45900.50mg/L50121221201012:56:00AMZinc<0.010.01mg/L12116120108:17:00PMHardness(SM2340B)60200100mg/LCaC03100121221201012:51:00AMINORGANICMETALSEPA200.8Analyst:JEKThorium<50.050.0IJg/L5012/20/201010:33:00AMUranium<50.050.0IJQ/L5012/16/20101:19:00PMVOLATILEORGANICCOMPOUNDSEPA8260Analyst:JAWBenzene<1.01.0IJQ/L12/15/201010:56:00AMToluene<1.01.0IJQ/L12/15/201010:56:00AMSurr:1,2-Dichloroethane-d410470-130%REC12115/201010:56:00AMSurr:4-Bromofluorobenzene10970-130%REC12115/201010:56:00AMSurr:Toluene-dB10370-130%REC12/15/201010:56:00AMINDICATORORGANICPARAMETERSEPA1664Analyst:JDHOil&Grease<55mg/L1.0212/13/20104:13:00PMVOLATILEORGANICCOMPOUNDSEPA8015Analyst:SUBEthyleneGlycol<1111mg/L1212212010I.D.56-00306PADEPn--·-A_,crLaboratory Results Geochemical Testing CLIENT: Lab Order: RESOURCE MANAGEMENT SERVICES GIOI2348 Project: 26R Analysis Lab ID: G I 012348-00

I Matrix: AQUEOUS Analyses RADIOLOGICAL TESTING Gross Alpha Gross Beta RADIOLOGICAL PARAMETERS Radium 226 RADIOLOGICAL PARAMETERS Radium228
Result 4667 +- 1518 4648 +- 832 385 +-75.5 904 +-194 QL Q EPA900.0 3.00 4.00 EPA 903.1 1 . 00 EPA904.0 1.00 Date: 04-Feb-11 Client Sample ID: HCPP Well 8422H RMS 2112/8 Sampled By: Client Collection Date: I2/8/2010

2
: 20:00 PM Received Date: I2/I0/2010 8:26:06 AM Units
DF Date Analyzed Analyst: SUB pCi/L 12/18/2010 pCi/L 12118/2010 Analyst: SUB pCi!L 12128/2010 Analyst: SUB pCi/L 117/2011 ------------·--------·· -----------------------

·- --- -----------------------------

- ----·-· -······· - - I. D . 56-00306 PA DEP Page 5 of 5