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# OAR Box 1875 Prepped byOllie Stewart



### Document

Number: 

# 21 ) ll-E-3 9 Docket Number: 

# A-90-1 9

Printed 12/1/200811:12:45AM

Sheet 21 of 86P. 2 

## A-90-1 9 ll-E-3 9 A ^ ° sr<r,

__UNITE D STATE S ENVIRONMENTA LPROTECTIO N AGENCY NMK 7 ! Offic e ofAi rQualit yPlannin g an d Standard s * ^l ^ " Researc h Triangl e Park , Nort h Carolin a 2771 1 o

"< PRO^ ° 

# :,,VE"fiP''•'( I »«30, 9 9 2

## f' " DE CI8199 2'

MEMORANDU M SUBJECT : CMAand EPA/ES D Meetin g o f Novembe r 21 , 199 1 FROM : Ja n Meye r *>> ~ ^f^ ^

Standard s fyevelopmenl^J Branch , ES D (MD-13 ) TO : Docke t A-90-19 , Hazardou s Organi c NESHAP : Genera l

Informatio n an d Proces s Vent s I . Purpos e Representative s o f th e Chemica l Manufacturer' s Associatio n (CMA ) an d th e Environmenta l Protectio nAgency' s (EPA ) Emissio n Standard s Divisio n(ESD ) me t t o discus s progres s o nth e developmen t o f th e hazardou s organi c NESHA P (HON) . Th e discussio nfocuse d o n th e criteri a use d t o defin e regulator y alternative s an d th e procedur e use d t o determin e th e floo r fo r th e syntheti c organi c chemica l industry . Th e CMArequeste d thi s meetin g t o gai nsom e understandin g o f th e regulator yoption s unde r consideration . II . Plac e and Dat e o f Meetin g N . C Mutua l Buildin g Roo m110 8 Durham , N C 9:0 0 a.m . - 12:0 0 p.m . III . Attendee s Name Organizatio nPhon e # Ja nMeye r EPA/SD B 91 9 541-525 4 Laszl o Takac s Occidenta l Chemica l 71 6 286-310 3 Nanc yCookso nCMA20 2 887-124 1III . Attendee s (cont'd ) P. 3

IV . Name Am yMeyer s Chuc k Malloc h Pa t Mora n Davi d Gustafso n Norma nMorro w Jo e Woolber t Richar d Sigma n Jo e Houvi s Davi d Woodrin g Lesli e Evan s Bo bRosenstee l Annett e Stanle y Discussio n Organizatio n CMA Monsant o Rohm& Haa s Ky Do w Exxo n Texa s Eastma nCo . CMA Unio n Carbid e B P Chemical s EPA/CP B EPA/CP B CMA Phon e # 20 2 31 4 50 2 51 7 50 4 90 3 20 2 20 3 21 6 91 9 91 9 20 2 887-137 0 694-888 9 449-525 8 636-295 3 359-722 6 237-547 5 887-131 3 794-518 3 586-867 0 541-541 0 541-560 8 887-110 3

Th e material s use d i nth e meeting' s discussio nar e i n Attachmen t 1 . Ja n Meye r explaine d th e alternative s being considere d fo r contro l mor e stringen t than th e floo r an d th e basi s fo r th e criteri a use d t o defin e differen t contro l levels . Th e approac huse d t o identif yth e floo r componen t fo r eachkin d o f emissio n poin t wa s als o briefl ydescribed . i n th e discussio n o f th e regulatoryalternatives , i t wa s emphasize d tha t n o decisio n had bee nmad e an d i t wa s stil l possibl e tha t additiona l revision s t o th e alternative s coul d occur .P. 4

. /
• ATTACHMEN T 1 

# BASELIN E HA P EMISSION S

Storag e - Larg e Tank

s 2.5 %

Wastewate r35.7% Storag e - Smal l Tank s 0.1 % Storag e - Mediu m Tank s 0.1 % Transfe r0.1 %

Process Vents 61.5 %

Q C y

yFina l Contro l Option s for HO N Proces s Vent s P. 5

Existin gSource s Optio n

1 2 3 . 4 5 6 7 Emissio n

Reductio n Mg/y r HA P 228,19 0 233,55 6 236,17 7 236,79 0 237,04 7 237,40 1 237,60 1 Percen t

HA P Reductio n 9 1 9 3 9 4 9 4 9 5 9 5 9 5 Annua l

Cost , $1000/y r 57,11 4 65,93 9 73,88 0 77,46 3 79,65 9 85,25 6 106,33 0 Averag e

$/Mg 25 0 28 2 31 3 32 7 33 6 35 9 44 8 Incre .

$/Mg HA P

1,64 0 3,03 0 5,84 6 8,55 0 15,80 0 105,46 4 Baselin e emission s ar e 250,66 4 Mg/yr o f HAP . Floo r elemen t i s Optio n 1 . Optio n 1 - contro l vent s wit hc/ e o f <$1500/Mg .

contro l vent s wit hc/ e o f <$2000/Mg . <$5000/Mg . <$7500/Mg . <$10000/Mg . <$28,000/Mg . contro l al l vent s wit hHAP's . Optio n 2 - Optio n 3 - Optio n 4 - Optio n 5 - Optio n 6 - Optio n 7 -P. 6

Fina l Contro l Option s for HO N Proces s Vent s Ne w Source s Optio n

1 2 3 4 Emissio n

Reductio n Mg/yr HA

P 45,04 6 45,10 6 45,13 2 45,14 4 Percen t

HA P Reductio n 9 5 9 5 9 5 9 5 Annua l

Cost , $1000/y r 15,20 6 16,19 9 17,74 5 20,20 3 Averag e

$/M g 33 8 35 9 39 3 44 8 Incre .

$/M g

16,55 0 59,45 2 205,52 8 Baselin e emission s ar e 47,62 6 Mg/yr HA P Optio n 1 - Optio n 2 - Optio n 3 - Optio n 4 - c/ e <$11,000/Mg <$28,000/Mg <$100,000/Mg al l vent s wit hHAP's ,P. 7

Fina l Contro l Option s for HO N Wastewate r Existin gSource s Optio n
1 2 3 4 5 ' Emissio n

Reductio n Mg HAP/yr 112,81 0 127,00 0 127,65 0 129,08 5 129,45 0 Percen t

HA P Reductio n 7 7 8 7 8 3 8 9 8 9 Annua l

Cost , $l000/yr 30,80 0 80,40 0 84,60 0 112,30 0 177,20 0 Averag e

$/M g HA P 27 5 63 5 66 0 87 0 1,37 0 Incre .

$/M g HA P

3,50 0 6,44 0 19,39 0 178,30 0 Baselin e emission s ar e 145,58 5 Mg/yr o f HA P an d 529,92 0 Mg/yr o f VOC . Floo r elemen t i s no control . Optio n 1 - Optio n 2 - Optio n 3 - Optio n 4 - Optio n 5 - contro l stream s >1 0 1p man d >100 0 ppm

wVHAP contro l streams > 1 1p man d >50 0 ppm

wVHAP . contro l streams > 1 1p man d >20 0 ppm

wVHAP . contro l streams > 1 1p man d >10 0 ppm

wVHAP . contro l al l streams wit han yHAP .P. 8

Fina l Contro l Option s for HO N Wastewate r
Ne w Source s Optio n
1 2 3

. 4 Emissio n

Reductio n M g HAP/yr 17,79 0 24,17 0 24,27 0 24,59 5 Percen t

HA P Reductio n 6 4 8 7 8 8 8 9 Annua l

Cost , $1000/y r 6,40 0 16,50 0 17,20 0 33,70 0 Averag e

$/M g 36 0 68 5 71 0 1,37 0 Incre .

$/M g

1,59 5 6,99 0 49,98 0 Baselin e emission s ar e 27,66 0 Mg/yr o f HA P an d 100,68 5 Mg/yr o f VOC . Floo r elemen t i s Optio n 1 , whic hreflect s contro l requirement s o f Viny l Chlorid e NESHAP an d the Benzen e Wast e NESHAP . Optio n1 - Optio n 2 - Optio n 3 - Optio n 4 - contro l streams >1 0 ppm wver yvolatil e HAP . contro l streams >1 0 ppm wver yvolatil e HA

P an d stream s >50 0 ppm

wvolatil e HAP . contro l stream s >1 0 ppm wver yvolatil e HA

P an d stream s >20 0 ppm

wvolatil e HAP . contro l al l streams wit han yHAP .Fina l Contro l Option s for HO N Transfe r Existin gSource s P. 9

Optio n
1 2 Emissio n

Reductio n Mg HAP/yr 36 0 42 4 Percen t

HAP Reductio n 6 5 7 7 Annua l

Cost , $1000/yr 3,12 8 6,52 1 Averag e

$/M g 8,69 0 15,41 6 Incre .

$/M g

53,86 0 Baselin e emission s ar e 55 1 Mg HAP/yr Floo r elemen t i s Optio n 1 . Optio n 1 - Optio n 2 - contro l rack s loading liqui d HAP' s wit hv p > 1. 5 psi a an d throughpu t >0.1 7 millio ngallon s pe r ..-*• year . contro l al l rack s loading liqui d HAP's .P.1 0

Fina l Contro l Option s for HO N Transfe r
Ne w Source s Optio n

1 2 Emissio n

Reductio n Mg/yr 6 8 8 1 Percen t

HAP Reductio n 6 5 7 7 Annua l

Cost , $1000/yr 59 4 1,23 9 Averag e

$/M g 8,69 0 15,42 0 Incre .

$/M g

53,86 0 Baselin e emission s ar e 10 5 Mg HAP/yr . Floo r elemen t i s Optio n 1 . Optio n 1 - Optio n 2 - contro l rack s loading liqui d HAP' s wit hv p > 1. 5 psi a an d throughpu t >0.1 7 millio ngallon s pe r year . contro l al l rack s loading liquid s HAP's .P.1 1

Fina l Contro l Option s for HO N Storage Vessel s Existin gSources : 10,00 0 to 20,00 0 gallo ncapacity Optio n

1 2 3 Emissio n

Reductio n M g HAP/y r 5-3. 3 32 2 35 9 Percen t

HA P Reductio n 1 4 8 5 9 5 Annua l

Cost , $1000/y r 31 8 7,73 6 18,94 9 Averag e

$/Mg 6,00 0 23,95 0 52,78 0 Incre .

$/Mg

27,47 4 311,50 0 Baselin e emission s ar e 37 9 Mg/yr o f HAP . Floo r elemen t i s n o control . Optio n 1 - contro l tank s storing HAP' s wit hv p >11. 1 psia . Optio n 2 - contro l tank s storing HAP' s wit hv p >1. 9 psia . Optio n 3 - contro l al l tank s storing HAP's .

Existin gSources : 20,00 0 to 40,00 0 gallo ncapacity Optio n

1 2 3 Emissio n

Reductio n M g HAP/y r 32 7 40 9 41 0 Percen t

HA P Reductio n 7 0 8 8 88. 4 Annua l

Cost , $1000/y r 2,11 3 4,11 0 5 , 67 0 Averag e

$/Mg HA P 6,50 0 10,05 0 13,87 0 Incre. .

$/Mg HA P

24,40 0 7,800 , 00 0 ' Baselin e emission s ar e 46 4 Mg/yr o f HAP . Floo r elemen t i s optio n1 . Optio n 1 - contro l tank s storing HAP' s wit hv p >1. 9 psia . Optio n 2 - contro l tank s storing HAP' s wit hv p >0. 1 psia . Optio n 3 - contro l al l tank s storing HAP's .P.1 2

Fina l Contro l Options fo r HO N Storage Vessel s
Existin gSources : 40,00 0 gallo ncapacit

y an dgreate r Optio n

1 2 3 4 a Cos t dee r Emissio n

Reductio n Mg HAP/yr 1,70 0 4,77 6 8,62 9 8,64 4 aas e du e t o Percen t

HA P Reductio n 1 7 4 8 86. 6 86. 8 Annua l

Cos t $1000/yr 4,05 7 7,290 a 17,06 8 18,52 5 credit s fro

mcontrol l Averag e

$/M g HA P 2,39 0 1,52 6 1,97 8 2,14 3 in g severaJ Incre .

$/M g HA P

1,05 1 2,53 8 97,13 3

. larg e tanks . Baselin e emission s ar e 996 4 Mg/yr o f HA P Floo r elemen t i s Optio n 1 . Optio n 1 - contro l tank s storing HAP' s wit hv p >1. 9 psia . Optio n 2 - contro l tank s storing HAP' s wit hv p >0.7 5 psia . Optio n 3 - contro l tank s storing HAP' s wit hv p >0. 1 psia . Optio n 4 - contro l al l tank s storing HAP's .P.1 3

Fina l Contro l Option s for HO N Storage Vessel s
Ne w Sources : 10,00 0 t o 20,00 0 gallo ncapacity Optio n

1 2 Emissio n

Reductio n M g HAP/y r 6 1 6 8 Percen t

HA P Reductio n 8 5 9 4 Annua l

Cost , $1000/y r 1,47 0 3,60 0 Averag e

$/Mg 24,09 8 52,94 1 Incre .

$/Mg

304,28 6 Baselin e emission s ar e 7 2 Mg/yr o f HAP . Floo r elemen t i s optio n 1 . Optio n 1 - contro l tank s storing HAP' s wit hv p >1. 9 psi a Optio n 2 - contro l al l tank s storing HAP's .

Ne w Sources : 20,00 0 t o 40,00 0 gallo ncapacity Optio n

1 2 3 Emissio n

Reductio n M g HAP/y r 6 2 77. 6 77. 7 Percen t

HA P Reductio n 7 0 8 8 88. 4 Annua l

Cost , $1000/y r 39 5 76 6 1,06 0 Averag e

$/M g HA P 6,37 0 9,87 0 13,64 0 Incre .

$/Mg HA P

23,78 0 2,940 , 00 0 Baselin e emission s ar e 8 8 Mg/yr o f HAP . Floo r elemen t i s optio n 1 . Optio n 1 - contro l tank s storing HAP' s wit hv p >1. 9 psia . Optio n 2 - contro l tank s storing HAP' s wit hv p >0. 1 psia . Optio n 3 - contro l al l tank s storing HAP's .P.1 4

Fina l Contro l Option s for HO N Storage Vessel s

Ne w Sources : 40,00 0 gallo ncapacit

y an dgreate r Optio n
1 2 3 Emissio n

Reductio n Mg HAP/yr 55 8 1,64 0 1,64 2 Percen t

HA P Reductio n 2 9 8 7 8 7 Annua l

Cos t $1000/y r 1,76 0 2,55 5 2,79 0 Averag e

$/M g HA P 3,15 5 l,558 a 1,69 8 Incre .

$/M g HA P

73 4 116,50 0

a Cos t decreas e du e t o credit s fro mcontrolling larg e tank s wit h v p betwee n 0.7 5 an

d 0. 1 psia . Baselin e emission s ar e 189 3 Mg/yr o f HAP . Floo r elemen t i s Optio n1 . Optio n 1 - contro l tank s storing HAP' s wit hv p >0.7 5 psia . Optio n 2 - contro l tank s storing HAP' s wit hv p >0. 1 psia . Optio n 3 - contro l al l tank s storing HAP's. "