'.2540-PM-BWM0347Rev.1/2011•-DEPARTMENTOFENVIRONMENTALPROTECTIONCOMMONWEALTHOFPENNSYLVANIADEPARTMENTOFENVIRONMENTALPROTECTIONBUREAUOFWASTEMANAGEMENTFORM26RCHEMICALANALYSISOFRESIDUALWASTEANNUALREPORTBYTHEGENERATORThisfonnmustbefullyandaccuratelycompleted.AllrequiredinfonnationmustbetypedorlegiblyprintedInthespacesprovided.IfadditionalspaceIsnecessary,IdentifyRec:enn:KIeachattachedsheetasFonn26R,referencetheItemnumberandidentifythedateprepared.Thedateonattachedsheetsneedstomatchthedatenotedbelow.GeneralReference287.54DatePrepared/Revised219/11c.CountyIndianaColoropaquewhite/orangeOdorNumberofSolidorUquidPhasesofSeparation210#Describeeachphase- 1 -2540.PM-BWM0347
Rev. 1/2011 c. d. a. Address Line
1 Address Line
1 Address City State ZIP Municipality Facility Contact TIUe Phone Address Line
1 Address Line
1 Address City State ZIP Municipality c. Facility Contact Title Phone

to processing
or disposal facility In the 0 cuyd

0 gal
0 lb year. 0 lb -2-

0 ton

NIA Indiana (check one) {check one)2540-PM-BWM0347 Rev.112011 I certify, under penalty of law, that

I have personally examined and am familiar with the information submitted

In this Annual Report and all attached documents and that based upon my inquiry of those Individuals Immediately responsible for obtaining the Information,

I verify that the submitted Information

Is bue, accurate and complete
to the best of my knowledge.

I understand that the submission
of false Information herein Is made subject to the penalties of 18 Pa. C.S. §4904, relating to unsworn falsification
to authorities, which Include fine and Imprisonment Check the following,

If applicable:

. D

I certify the Information required
In Section B-1, General Properties was supplied
to the Department for the year _and has not changed. Form Submitted:

D Fonn 26R 0 Other {specify) Date Submitted: D

I certify the Information required
In Section B-2, Chemical Analysis was supplied
to the Department for the year _and has not changed. Form Submitted:

0 Fonn 26R 0 Other (specify) Date Submitted: D

I certify the Information required
In Section B-3, Process Description and Schematic, was supplied to the Department for the year_ and has not changed. Form Submitted:

0 Fonn 26R 0 Other (specify) Date Submitted:

-3-February

8, 2011 Form 26R: Section B2b WASTE SAMPLING METHODS

I· All samples were obtained as grab type samples with a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are composited within the storage production tank or tank battery at each well site where gas production

is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank{s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP permitted waste disposal facilities on different schedules determined
by individual well characteristics. Grab samples of the composited fluids were obtained
at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. **Sa~ples** were obtained with bottle sets prepared
at the laboratory which contained appropriate preservatives,

as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. Flowback samples were composited

to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory
or on the well location upon completion
of the composite sampling process. Samples were distributed into bottle sets prepared
at the laboratory which contained appropriate preservatives,
as necessary, depending
on the specific test run requested. All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process at various times and combined into a composite sample for analyses
at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed
on both sample composites.

In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness

of the composite sample and composite grid sample positions were varied to the extent possible. Pit water {drill fluid) is currently discharged

to closed containment and is re-conditioned and reused from well to well.I• February
9, 2011 Form 26R: Section 83a WASTE GENERATION PROCESS Pit Water "Drill Fluids" Remnant drill fluids are generated

in the well bore during the penetration
of the drill stem as it intercepts both ground water and formation fluids. These fluids are brought to the surface along with the drill **~ings,** pieces of the intercepted rock strata, by the return flow system of the drilling process. Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are mixed with sawdust to absorb remnant fluid aod loaded out for disposal at a landfill. Fluids are currently stored in closed containers
to be processed for reuse. Flowback: "Fracing Fluid" Flowback

is produced from all fluids that flow back to surface during the "hydrofracing" process which occurs under pressure and results
in the setting of a propant within the formation fractures. Production Fluid "Brine" During the production
of natural gas, formation pressures bring remnant frac fluids, during the initial production phase, and formation fluids to the surface along with produced gas.Well I. D.# (various) Well I.D.# . (various) \\/ \\/ -a- -aCOUNTY A ......**~.......** __,.I' \ I \ / Well I. D.# (various) \ I **-~/** \ I -0 \ /II' \ I / \ I // \ I / / . \ I / Well I.D.# (various) \ 1 // \\/ / \ I / -0- / "

- COUNTYB..... **~o---- ~**  **~** cr

**~I** Fl.,..,L ....\<, :; **=ovo~** Mobile Tank Truck **~t"o~vc** . .'tLot!\ Ocu **1t\~~~** l""\-..s ::( **J~**S brine (lYP.) Note: . Process producing waste: Gas well produced fluids (brines) are typically produced in conjuction wi.th natural gas. These fluids are brought to the surface utilizing either mechanical or physical lift procedures.

_s Road Transport ---- Landfill or**Tr~** +tv\

**~.,.J** 'P \GV\t

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**~** a; ;**~ ~** i=-\1- **•s~nNI\** .-NTAI .r. V1.,u. ,..VIE.,.

.• .... SERVICE LABORATORIES, INC. 1803 Philadelphia Street, Indiana, PA 15 701 (724)-463-TEST
FAX (724)-465-4209 Report of Analysis Name: Sample Start Date: Receipt Date: Report Date: Sample Site: XTOEnergy 395 Airport Road Indiana; PA 15701 2fl612009 11:00 AM 2!26fl009 12:43 PM 3fl1fl009 Bloom#8315 Analyte Acidity to pH=8.3 Alkalinity

to pH=4.5 Biological Oxygen Demand 05 Chemical Oxygen Demand Ammonia
as N I Distilled Chloride Kjeldahl Nitrogen
as N pH(SM) Sulfate (ASTM) Total Nitrate+ Nitrite as N Aluminum

- ICP Arsenic--ICP Barium -ICP Beryllium- ICP Boron Cadmium- ICP Calcium

- ICP Chromium

- ICP Cobalt-ICP Copper- ICP Hardness

Analyst MS MS MAD AID AID MS AID MS KM JFW GJT GJT GJT GJT ES GJT GJT GJT GJT GJT DRM Comments; Radiologicals done by Benchmark Analytical **~** DEP Certification

fls 3 2 -00382 Analysis Date 03/04/2009 03/03fl009 03/0212009 03/02/2009 03/0S/2009 03/05fl009 03/05/2009 03/20!2009 03/11/2009 03/04!2009 03/03/2009 03/04/2009 03/03/2009 03/03/2009 03/0312009 03/03/2009 03/0312009 03/0312009 03/0312009 03/03fl009 03/04/2009 Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID: Sample Result

09 06141 Waste Water Grab JW (Client) Bloom #8315 **~test** Units Method 189 mg/1 as CaC03 SM2310B 147 mg/1 as CaC03 SM2320B 148.1 mg/1 SM5210B 2702.5 mgll SM5220D 116.37 mgll )M4500NH3B & [ 90602.0 mgll SM4500ClC 127.7 mgll SM4500Norg-C,D 5.55
su SM4500H-B ND mg/1 0516-02 ND mg/1 SM4500N03E 1.600 mgiJ 200.7/6010 ND mg/1 200.7/6010 4918.800 mg/1 200.7/6010 ND mg/1 200.7/6010 6.40 mg/1 SM4500B-B NO mg/1 200.716010 10727.400 mg/1 200.7/6010 ND mg/1 200.7/6010 ND mg/1 200.7/6010 ND mg/1 200.7/6010 31695 mg/1 SM2340B MDL 1 20 2.0 500

. 0 4.11 1.0 53.2 0.01 s 0.05 1.000 1.000 0.500 0.500 2.50 0.500 50.000 0.500 0.500 0.500 1 jND=Not Detected Page
1 of3;;;;; f\rV_I_ **a~** \1M- ;:: N- ·=-= .... ., t.. **~ul** ..... t .. IAL SERVICE LABORATORIES, INC. 1803 Philadelphia S1reet, lndlanct PA 15 701 {724)-463-TEST
FAX (724}-465-4209 Report of Analysis Name: Sample Start Date: Receipt Date: Report Date: Sample Site: XTOEnergy 395 Airport Road Indiana, PA 15701 2!2612009 11:00 AM 2126!2009 12:43 PM 3(}.112009 Bloom#8315 Aoalyte Iron- ICP Iron,Dissolved-ICP Lead-ICP Lithium- ICP Magnesium-ICP Manganese

- ICP Mercury Nickel- ICP Seleniwn-ICP Silver-ICP Sodium-ICP Strontium

- ICP Zinc- ICP Osmotic Pressure Detergents, MBAS Ethylene Glycol Oil and Grease- HEM Phenolics,
as Phenol Specific Conductance Total Dissolved Solids (TDS) Total Suspended Solids Analyst OJT GJT GJT GJT DRM GJT DMM GJT GJT GJT GJT DRM GJT AID JFW MetPeak CLM AID JH MAD MAD Comments: Radiologicals done by Benchmark Analytical Note: DEP Certification
#Js 32-00382 SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analysis Sample Date Result 03/04fl009 112.900 03104fl009 73.800 03/03(}.009
ND 03/03/2009 94.000 03/04fl009 1192.000 03/0312009 12.100 03/06/2009
ND 03/03/2009
ND 03104fl009 ND 03/03/2009
ND 03/04/2009 35249.000 03/04/2009 2845.000 03/0412009
ND 03/02(}.009 4050 02127/2009 54.700 03/0912009 93.904 03/0412009 10.7 03/06/2009
ND 03/2312009 155133 03/02fl009 179100 03/02fl009
131

09 06141 WasteWater Grab 1W (Client) Bloom #8315 Brine test Units Method mg/1 200.7/6010 mg/l 200.7/6010 mg/1 200.7/6010 mgll 200.7/6010 mgll 200.7/6010 mg/1 200.7/6010 mgll 245.1 mgll 200.7/6010 mg/1 200.7/6010 mgll 200.7/6010 mg/1 200.7/6010 mgll 200.7/6010 mg/1 200.7/6010 mOslkg
OSP mgll SM5540C mglkg 300.0M mg/l 1664A rngll 420.1 uS/em SM2510B mg!l SM2540C mg/l SM2540D MDL 1.000 1.000 0.500 50.000 500.000 0.500 0.0020 0.500 1.000 0.500 500.000 10.000 0.500 1000 10.000 25.000 5.0 0.050
I 25 5 jND=Not Detected Page
2 of 3a= I\!• **--R~NlJit=NT-**

- ..... VI ..... u ... v ...... AL SERVICE LABORATORIES, INC. 1803 Philadelphia street, Indiana, PA 15 70

l (724)-463-TEST
FAX (724)-465-4209 Report of Analysis Name: Sample Start Date: Receipt Date: Report Date: Sample Site: Radiologicals 1) Benzene 47) Toluene XTOEnergy 395 Airport Road Indiana, PA 15701 2126/2009 11:00 AM 2126/2009 12:43 PM 3121fl009 Bloom ##8315 Analyte Analyst enchma RO RO Comments; Radiologicals done by Benchmark Analytical Note: DEP Certification

#s 32..()0382 SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analysis Sample Date Result 03/12/2009

• 03/04/2009 ND 03/0412009 ND

09 06141 Waste Water Grab IW (Client) Bloom #8315 Brine test Units Method nWl RAD-CTDHS ugiL 624/8260B ugiL 624/8260B MDL 0.000 20.00 20.00 FD=Not Detected Page
3 of3· ·, .. **~-** -VIRflNMt=NTA- .. N ...

I ............ ... .....

• • .... L SERVICE LABORATORIES, JNC. 1803 Philadelphia S1reet, Indiana, PA 15701 (724)-463-TEST
FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: Sample Site: I) Benzene 47) Toluene XTOEnergy 395 Airport Road Indiana, P A 1 5701 2/26/2009 2126/2009 1:47PM 3/S/2009 Bloom#8315 Analyte Note: DEP Certification
#s 32-00382 Report of Analysis Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO 03/04n.009
ND RO 03/04n.009
ND

09 06165 Waste Water Trip Blank MH(Ciient) Trip Blank Units ug/L ug/L Method 624/8260B 624/8260B MDL 1.00 1.00 Page
1 of 1

### MAR-16-2009 **0~:2S**

## PM 

# .

' 

# .. 0 

# · . LAB ID 

# #: 39-00401 SEND DATA TO: 

# NAME: Mike Moyer 

# BENCHMARK ANAL YTICS, INC. 4777 Saucon Creek Road Center 

# Valley. PA 18034-9004 PHONE (61 0) 974-8100 

# FAX (610) 974-8104 COMPANY: Environmental Service Laboratories,
Inc ADDRESS: 1803 Phlladafphia Strest PHONE: 

# FAX: Indiana, PA 15701 

# {124) 463-8378 (724) 485-4209 

# TEST REPORT 0906069,06351,06841,06638,06637,06840,06141 RECEIVED FOR LAB BY: DMB DATE: 03/08/2009 9:35

.

P.01 

# Work Order: 09030849 

# WO#: 09030849 

## PAGE:

1 of2 

# POl: PWSIDi#

Pqe
1 of2 SAMPLE:


# qa 08141 SAMPLED BY: DaYid A. Stilt

Lab

10: **O~B-007A** 

## S.mple Time 021281200911:00

Gl'lb 

# !!!l 

# BuWI Y.!l5ald. 

# Mea .u!!lll **~** 

## mi. 

# &lallllll §Jars **~1111911** 

# Et\11 aDIIltll..! Gloat Alpha 272.8 

## :t33U 1292 pOUL 

## EPA900.0 **~88:30** 

## D3/'1210t 

## BPS.CV Grote Beta 637.4

:t 

## 4&4.9 

## 11512 pCUt. 

## EPA900.0 03109109 8:30 

## 0311':'08 BPS.CV 

# -·--. -·· ·--
· -·····--·--- 

# --·-··

. 

# . ·····---··-·. 

# ·----- 

# -------

.. -.- 

# ....... REMARKS:

. The abcwe 

# teat procedures meet all the requirements

of NE:LAC and relate only 

# to these samples

. .. CV 

# = Benchmark Analytlcs, Inc. Center Valley, PA; SA= Benchmark 

# Analytios, loo. **Sa~re,**

# PA GER

_. _/' 

# .M 

# ~
DATe: 3//612009 MANA

- 

# ------·-----~-" **'L!....~-**

**·- --**  --
·· --" ·----- --· ·--- -·



# 7254CJ..PII-BWM0347 Rev.1/2011 **,,~~~.!!..** COMMONWEALTH

OF PENNSYLVANIA DEPAR111ENT
OF ENVIRONMENTAL PROTEC110N BUREAU OF WASTE MANAGEMENT FORM26R CHEMICAL ANALYSIS OF RESIDUAL WASTE ANNUAL REPORT BY THE GENERA TOR This fonn must be fully and accurately completed.
All required infonnation must be typed or legibly printed in the spaces provided.

If addiUonal space is necessary, identify Date each attached sheet as Fonn 26R, reference the item number and identify the date prepared. The date on attached sheets needs to match the

. date noted below. General Reference 287.54 Une
1 Company Mailing Address

2 State Zip+4 Phone PA 15701 724-349-0600 First Name

Suffix Ben

Mr. c.
Number of Solid or Uquld Phases of Separation

No Describe each phase of separation

. **.:..:.::~.=----------------;**

No - 1
-2540;-PM-BWM0347 Rev.1/2011 b. c. **~.** d. a. c. b.

A
processes as specified
in the instructions,

is attached. If portions

are a confidentiality claim, as described
in the instructions,

is attached. Address Une
1 Address Une
1 Address City State ZIP Municipality rltle Phone Contact Name Volume of waste shipped to processing
or D cu yd 181 gal D 1b steve@pabrine

. com (check one) processing
or being utilized. Facility Name Address Une
1 Address Line
1 Address City State ZIP Municipality Name Title Phone

Email Address waste If "Yes", list the general pennit number or approval number. Volume of waste beneficially used in the previous year. D cuyd
D gal D lb D ton - 2- (check one)

No N/A2549-PM-BWM0347 Rev.112011 I certify, under penalty of law, that

I have personally examined and am familiar with the Information submitted

In this Annual Report and all attached documents and that based upon my Inquiry of those Individuals Immediately responsible for obtaining the Information,

I verify that the submitted Information

Is true, accurate and complete
to the best of my knowledge.

I understand that the submission
of false information herein Ia made subject to the penalties of 18 Pa. C.S. §4904, relating to unsworn falsification
to authorities, which Include fine and Imprisonment Check the following,

if applicable: D

I certify the Information required
In Section B-1, General Properties was supplied to the Department for the year _and has not changed. Form Submltled:

D Form 26R D Other (specify) Date Submltt8d: D

I certify the Information required
In Section B-2, Chemical Analysis was supplied to the Department for the year _and has not changed. Form Submitted:

D Form26R D Other (specify) Date Submitted: 0

I certify the Information required
In Section B-3, Process Description and Schematic, was supplied to the Department for the year_ and has not changed. Form Submitted:

0 Form 26R Date Submitted: Name of Responsible Official Bernhardt Kissel Signature

0 Other (specify)

Shale Date 2-28-11 -3-February
8, 2011 Form 26R: Section 82b WASTE SAMPLING METHODS All samples were obtained as grab type samples with a composite function which was maximized but sometimes limited by prevailing safety, site specific rational and/or environmental concerns. Brine fluids are composited within the storage production tank or tank battery at each well site where gas production

is occurring. Each automatic
or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP permitted waste disposal facilities on different schedules determined
by individual well characteristics. Grab samples of the composited fluids were obtained
at the represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. Samples were obtained with bottle sets prepared
at the laboratory which contained appropriate preservatives,
as necessary, depending
on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. Flowback samples were composited

to the extent possible during the flowback process primarily during times where safety issues did not override sample collection requirements. Generally,

a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory
or on the well location upon completion
of the composite sampling process. Samples were distributed into bottle sets prepared
at the laboratory which contained appropriate preservatives,

as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. Drill cuttings were composite sampled during the drilling process at various times and combined into a composite sample for analyses
at the laboratory. On several wells, cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites.

In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the randomness

of the composite sample and composite grid sample positions were varied to the extent possible. Pit water (drill fluid) is currently discharged
to closed containment and is re-conditioned and reused from well to well.February9,2011Form26R:SectionB3aWASTEGENERATIONPROCESSPitWater"DrillFluids"Remnantdrillfluidsaregeneratedinthewellboreduringthepenetrationofthedrillstemasitinterceptsbothgroundwaterandformationfluids.Thesefluidsarebroughttothesurfacealongwiththedrillcuttings,piecesoftheinterceptedrockstrata,bythereturnflowsystemofthedrillingprocess.Drillanddrillfluidsareisolatedintoseparatewastestreams.Cuttingsaremixedwithsawdusttoabsorbremnantfluidandloadedoutfordisposalatalandfill.Fluidsarecurrentlystoredinclosedcontainerstobeprocessedforreuse.Flowback:"FracingFluid"Flowbackisproducedfromallfluidsthatflowbacktosurfaceduringthe"hydrofracing"processwhichoccursunderpressureandresultsinthesettingofapropantwithintheformationfractures.ProductionFluid"Brine"Duringtheproductionofnaturalgas,formation pressuresbringremnantfracfluids,duringtheinitialproductionphase,andformationfluidstothesurfacealongwithproducedgas.Well I. D.# (various) Well r... D.# . (various) '\/

**~**

-0 -y- /v, /1' I\ I \ / Well I. D.# (various) \ I ::::b/ \ I /II' \ I / \ I // \ I // . . \ I / Well I. D.# (various) \ 1 // '\/ / \ I ./ -0- / " ,-------. **u~ '<'OF!"'"'~~;**  **~oVd~** Mobile Tank Truck **~r--obl.vc..\1~.1\ Ocu'tt\~~~** 

- COUNTYB

COUNTY A \MI<.S ::( ,

**J~**5 brine (lYP.) Landfill Or'

_s Road Transport TrUA.+tv\(A+

**'Pl~t** Note: . Process producing waste: Gas well produced fluids (brines) are typically produced in conjuction wi.th natural gas. These fluids are brought to the surface utilizing either mechanical or physical lift procedur _es.

(.)**~**w:r:**~**z0**~ ~** 00..(/')**~**1-,illf**~~~I** ii..! **~ ~** **ill~~~~ ~** **~**;

**~**- le **~** Cl - r !!

**~**I!

:

**~ l~**  II. **~**r:o-

- .. **·=~~N-**

.. a;- --41 t:NVI
.... U ... tv. .. NT. ,. SERVICE LABORATORIES, INC. 1803 Philadelphia Street, Indiana, PA 15 701 (724)-463-lEST
FAX (724}-465-4209 Report of Analysis Name: Sample Start Date: Receipt Date: Report Date: Sample Site: XTOEnergy 395 Airport Road Indiana, PA
I 5701 2/2612009 11:00 AM 2/26/2009 12:43 PM 31'21fl009 Bloom#8315 Analyte Acidity to pH=8.3 Alkalinity

to pH=4.5 Biological Oxygen Demand 05 Chemical Oxygen Demand Ammonia
as N I Distilled Chloride Kjeldahl Nitrogen
as N pH(SM) Sulfate (ASlM) Total Nitrate +Nitrite
as N Aluminum

- ICP Arsenic-ICP Barium-ICP Beryllium

- ICP Boron Cadmium

- ICP Calcium

- ICP Chromium

- ICP Cobalt-ICP Copper- ICP Hardness

Analyst MS MS MAD AJD AID MS AID MS KM 1FW GIT GJT GJT GIT ES GJT GJT GJT GIT GJT DRM Comments: Radiologicals done by Benchmark Analytical !ie!!!;. DEP Certification
#Is 32..(){)3&2 Analysis Date 03104!2009 03/03/2009 03/0212009 03/0212009 03/05fl009 03/05f2009 03/05/2009 03/2012009 03/llf2009 03/0412009 03lo3/2009 03/04fl009 03/03/2009 03/03/2009 03/0312009 03/03f2009 03/0312009 03/03f2009 03/03/2009 03/03/2009 03/04/2009 SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Sample Result

09 06141 WasteWater Grab JW (Client) Bloom #8315 **~test** Units Method 189 mg/1 as CaC03 SM2310B I47 mg/1 as CaC03 SM2320B 148.1 mgll SMS210B 2702.5 mg/1 SM5220D 116.37 mg/1 **~M4500NH3B**

& [ 90602.0 mg/1 SM4500ClC 127.7 mg/1 SM4500Norg-C,D 5.55
su SM4500H-B ND mgll D516-02 ND mg/1 SM4500N03E 1.600 mg/1 200.7/6010 ND mg/1 200.7/6010 4918.800 mg/1 200.7/6010 ND mg/1 200.7/6010 6.40 mg/1 SM4500B-B ND mg/1 200.7/6010 10727.400 mg/1 200.7/6010 ND mg/1 200.7/6010 ND mgll 200.7/6010 ND mg/1 200.7/6010 31695 mg/1 SM2340B MDL 1 20 2.0 500.0 4.11 1.0 53.2 0.01 5 0.05 1.000 1.000 0.500 0.500 2.50 0.500 50.000 0.500 0.500 0.500 1 jND=Not Detected Page
1 of3- ·v --

.. ·· - N

- II: -- -- -----
-- -e- --- - tN

.. II<UI"M

... TAL · sERVICE LABORATORIES, INC. 1803 Philadelphia Street, Indiana, PA 15 701 (724)-463-TEST
FAX (724}-465-4209 Report of Analysis Name: Sample Start Date: Receipt Date: Report Date: Sample Site: XTOEnergy 395 Airport Road Indiana, PA 15701 212612009 11:00 AM 2126/2009 12:43 PM 3/27/2009 Bloom#831S Analyte Iron- ICP Iron,Dissolved-ICP Lead-ICP Lithimn- ICP Magnesium-ICP Manganese

- ICP Mercury Nickel- ICP Selenium-ICP Silver-ICP Sodium-ICP Strontium

- ICP Zinc- ICP Osmotic Pressure Detergents. MBAS Ethylene Glycol Oil and Grease- HEM Phenolics,
as Phenol Specific Conductance Total Dissolved SoJids (TDS) Total Suspended Solids Analyst OJT GJT GIT GJT DRM GIT DMM orr GJT GJT OJT DRM GJT AID JFW IMetPeak CLM AID JH MAD MAD Comments: Radiologicals done by Benchmark Analytical Note; DEP Certification
#s 32..00382 SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analysis Sample Date Result 03/04/2009 112.900 03/0412009 73.800 03/03/2009
ND 03/03/2009 94.000 03/04/2009 1192.000 03/0312009 12.100 03/06/2009
ND 03/03/2009
ND 03/0412009
ND 03/03/2009
ND 03/04/2009 35249.000 03/04/2009 2845.000 03/0412009
ND 03/02/2009 4050 02/27f1.009 54.700 03/09/2009 93.904 03/04f1.009 10.7 03/06/2009
ND 03/23/2009 155133 03/02f1.009 179100 03/02/2009

131

09 06141 WasteWater Grab 1W (Client) Bloom #831 5 Brine test Units Method mg/1 200.7/6010 mgll 200.7/6010 mgll 200.7/6010 mg.ll 200.7/6010 mgll 200.7/6010 mg.ll 200.7/6010 mg.ll 245.1 mg.ll 200.7/6010 mgll 200.7/6010 mgll 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mg/1 200.7/6010 mOslkg
OSP mg/1 SMS540C mglkg 300.0M mg/1 1664A mgll 420.1 uS/em SM2510B mgll SM2540C mgll SM2540D MDL 1.000 1.000 0
. 500 50.000 500.000 0.500 0.0020 0.500 1.000 0.500 500

. 000 10.000 0
. 500 1000 10.000 25.000 5.0 0.050 1 25 5 [NI>=Not Detected Page 2 of3e=N• ••RI)NftAa;N-

•

i ..... Vi ... ,...,. .... v ••• TAL SERVICE LABORATORIES, INC. 1803 Philadelphia S1reet, Indiana, PA 15 70

l (724)-463-TEST
FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: Sample Site: R.adiologicals 1) Benzene 47) Toluene XTOEnergy 395 Airport Road Indiana, PA 15701 212612009 11:00 AM 212612009 12:43 PM 3121fl009 Bloom ##8315 Analyte Report of Analysis SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result enchmw 03/1212009

"' RO 03/04/2009
ND RO 03/04/2009
ND Comments: Radiologicals done by Benchmark Analytical Note: DBP Certification
#s 32..00382

09 06141 Waste Water Grab JW (Client) Bloom #831 5 Brine test Units Method mg/1 RAD-CIDHS ug/L 624/8260B ug/L 624/8260B MDL 0.000 20.00 20.00 fD=Not Detected Page 3 of3ENVIRONMENTAL SERVICE LABORATORIES, JNC. 1 803 Philadelphia Street, Indiana, PA 15 701 (724)-463-TEST
FAX (724)-465-4209 Name: Sample Start Date: Receipt Date: Report Date: Sample Site: 1) Benzene 47) Toluene XTOEnergy 395 Airport Road Indiana, PA 15701 2/26/2009 2/26/2009 1:47PM 3/S/2009 Bloom#8315 Analyte Nota: DEP Certification
#s 32-00382 Report of Analysis SampleiD#: Sample Type: Sample Source: Sampler: Client Sample ID: Analyst Analysis Sample Date Result RO 03/04/2009
ND RO 03/04/2009
ND

09 06165 Waste Water Trip Blank MH (Client) Trip Blank Units ug/L ug/L Method MDL 624/82608 1.00 624/82608 1.00 IND=Not Detected Page
1 of 1

## MAR-16-2009 **0~:2~**

## PM 

# .. ...

, 

# .. LAB ID 

# #: 39-00401 SEND DATA TO: NAME: Mike Moyer 

# BENCHMARK ANAL YTICS, INC. 4777 Saucon Creek Road Center 

# Valley. PA 18034-9004 PHONE (610) 974-8100 **F~(610)974-8104** 

# COMPANY: Environmental Service Laboratories,
Inc 

# ADDRESS: 1803 PhUadafphia 

# Street Indiana, 

# PA 15701 

# PHONE: {124) 463-8378



# TEST REPORT FAX: (724) 455-4209 0906069,06351,06841,06638,06637,08840.06141 RECEIVED FOR LAB BY: DMB DATE: 03/08/2009 9:35

.

P.01 

# Work Order: 09030849 WO#: 09030849 

# PAGE:

1 or2 

# PO#: PWSIO#

PIIJO 

## 1 of2 SAMPLE:
C!8 08141 SAMPLED BY: David A. Stilt

Lab

10: 08030&4G-007A S.mple 

## Time 02/281200911:00

Grab 

# !!It 

# 8uWl Y!af!. 

# .MDa .u.!!IJl 

# .Malhml M.ttL 

## Mlll!lll 

# b!S A!lab!:lllliiKI &l!ll!ll! Gloat Alpha 272.9

:t 

## 338.4 12512 pOUt. 

## EPA900.0 03IOQic)t 

### 8:30 

# c311me BPS.CV 

# GroleBeta 837.4

:t 

### 4M.9 

## 11112 pCUL 

## EPA&OO.O 03109109 8:30 **0311~** 

## BPS.CV -·--. -·· ·-··----·---·--- --·--·

0 

# - ····---····-.

0 

# ·----- 

# ---------

.. 

# - .... 

# ·-· REMARKS:

. The above test 

## prooedures meet all the requirements

of NeLAC 

# and relate only 

# to these samples

. .. CV 

# = Benchmark Analytlca, 

# Inc. Center Valley, PA; SA 

# = Benchmark Analytios, 

# lno. Sayre, PA 

# "' ./- I'M 

# ~
DATe: 

## 3/1612009 MANAGER

_

# -----------~--**.l.!.....~-**

.. ·· --· --

· ·---

. ---- ---· ·--- --



# 7