p

e date noted below. 

Reference 287.54 

c. Physical Appearance 

County 

Indiana 

Number of Solid or Uquid Phases of Separation 

Une2 

10# 

No 

Describe each phase of separation.~~---------------; 

- 1 -
c. 

d. 

Address Une 1 

Address Une 1 

Address City Stai8 ZIP 

Municipality 

Title 

Phone 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

c. Facility 

Title 

Phone 

or 

181 gal 

d. waste shipped to processing or 0 cuyd 0 gal 

County Indiana 

0 {check one) 

Email Address 

UIIII'YIUI,GI year. 0 lb 0 ton {check one) 

0 ton {check one) 

-2 -
Form Submitted: D Form 26R 

0 Other (specify) 

Date Submitted: 

D I certify the information required In Section B-2, Chemical Analysis was supplied to the Department for the year 

_and has not changed. 

Form Submitted: 0 Form 26R 

D Other <specify> 

Date Submitted: 

D I certify the Information required In Section B-3, Process Description and Schematic, was supplied to the Department 

for the year_ and has not changed. 

Form Submitted: 0 Form 26R 

Date Submitted: 

Name of Responsible Official 

Bernhardt Kissel 

Signature 

0 Other (specify) 

Date 2-28-11 

-3-
WASTE GENERATION PROCESS 

Pit Water "Drill Fluids• 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and formation fluids. These fluids are brought to the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

Flowback: "Fracing Fluid" 

Flowback is produced from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the formation fractures. 

Production Fluid "Brine" 

During the production of natural gas, formation pressures bring remnant frac fluids, 

during the initial production phase, and formation fluids to the surface along with produced gas. 
Brine fluids are composited within the storage production tank or tank battery at each well site where gas production is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank{s) and added to the previously ejected and stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP 

permitted waste disposal facilities on different schedules determined by individual well 

characteristics. Grab samples of the composited fluids were obtained at the 

represented well pads directly frorr- the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of lost fluids. 

Sa~ples were obtained with bottle sets prepared at the laboratory which contained 

appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. 

Flowback samples were composited to the extent possible during the flowback process primarily during times where safety issues did not override sample collection 

requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and 

combined into a composite sample for analyses at the laboratory. On several wells, 

cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites. In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concer,ns usually limited the 

randomness of the composite sample and composite grid sample positions were varied 

to the extent possible. 

Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned 

and reused from well to well. 
Form 26R: Section 81e 

GENERATOR KNOWLEDGE 

All Form 26R Waste Forms have been compiled, and Mure testing has been 

scheduled, to obtain samples of each waste stream on a PAD by PAD basis. Sample 

analyses will be conducted every 5 years for each waste stream unless the process that 

generates any particular waste stream is substantially altered. 

Attached analytical results for this waste stream have been obtained from a similar 

waste stream producing waste from the same geologic formation as this 26R Report. 

Additionally, the mud mixtures, chemical formulations and drilling process utilized at this 

well PAD are substantially the same as those utilized at the well where the attached 

waste analyticals were generated. 
Well I. D.# (various) Well I.D.#.(various) 

-0-

'\/ 

-y-

~ /~, /1' I\ I 

\ / Well I. D.# (various) 

\ I ::b::: \ I // l 

\ I / \ I // 

\ I // 

. . \ I / 

Well I. D.# (various) \ I // 

\\/ / \ I / 

-o- / " r----

CJ / 

"/ ~o~-- Fl"'"'~~~; ( 

e>ft'oVo,~ . ~ Mobile Tank Truck 

~f'"o~·ho-'\ Ocu1\\~~~ 

- COUNTYB 

COUNTY A 

\tM~S :· ( 

Jls brine (TYP.) 

_ s:: Road Transport 

----- Landfill or 

0 

~ UJ 

:r: 

(.) 

CJ') 

z 

0 

~ 

t:2 

0 

Cl. 

(/) 

·~ 

1-

~~ Ill 

!!.l 

C) 

....... -

Tr~+~U\+ 'Pl(,V\t . I

LLI 

~ ~ 

~ 5 ~~ 

ote: 

Process producing waste: Gas well produced 

fluids (brines) are typically produced in 

conjuction with natural gas. These fluids 

are brought to the surface utilizing either 

,, mechanical or physical lift procedur.es. 

~ I! ~ :S~ ~ i5 i 

;;! ~ 

u 
... ·----ENVIRONMENTAL SERVICE I 

LABORATORIES,_ INC. SAMPLE REQUEST & CHAIN OF CUSTODY PAGE __ OF --+-

HEADQUARTERS: 

1803 Philadelphia St. 

Indiana, PA 15701 

(724) 463-TEST 

(724) 465-4209 

~ SOUTHERN DIVISION: 

1276 BentteyvHie Road 

Van Voorhis, PA 15366 

(724) 258-TEST D REC'D NOV -4 2009 

(724) 258-8376 

FOR INTERNAL LAB ORA TORY USE ONLY 

Sample Identification I ESL# 

lf,qJ{,gl/31 H-l t9~tD 

TRIP BLANK 09 

~1~1/ 

Composite 

Sample Type 

THE UNDERSIGNED PURCHASER HEREBY AGREES TO PAY SERVICE CHARGES ON ACCOUNTS OVER 31 DAYS OLD. 

Grab 

Time 

' lj 

Cj 15 

c:; ,,~ 

1. THESE SERVICE CHARGES WILL ACCRUE AT THE RATE OF 1 112% PER MONTH (11% PER ANNUM OR THE MAXIMUM ALLOWED BY LAW.) 

2. THE UNDERSIGNED PURCHASER AGREES TO PAY, IN THE EVENT HIS ACCOUNT BECOMES DEUNQUENT AND IS TURNED OVER TO AtN 

ATTORNEY FOR COLLECTION, REASONABLE ATTORNEY'S FEES PLUS ALL COURT AND ATTENDANT COLLECTION COSTS. 

~ to/3}~ 9..i'$".-49H? 

Matrix I 

ww I 

ww I 

ww I 

ww I 

ww I 

ww I 

ww I 

ww I 

ww I 

Water I 

# of Containers I Container Type 

Preurvalive 

1 I Plastic Liter 

none 

2 I Plastic Liter 

none 

1 I Plastic Liter 

HN03 

1 I Plastic Liter 

H:z$04 

(2) 1000 ml I Plastic Liter 

(3) 500 ml HN03 

1 I Amber Glass L 

HCI 

1 I Amber Glass L 

H2S04 

2 I Amber VOA Vials 

none 

2 I Amber VOA Vials 

HCI 

2 I f.mber VOA Vials 

HCI 

Project Notes: 

Company/Name: 

Samp1Bi:{Si9na~ ,/ /'!:ate/ Time ,.... 

/~e.. - -e> (l(~~~ 

I" 

0- g -oc [ \~ ~ Address: 

\~sRelinquished By: (Signature) Date/ Time 

CHAIN OF CUSTODY SEAL BROKEN: Yes _No 

,BY. (Sign.:tur;11 '-ID_ _ . /1 }JateJ Time N '-1.3 ~~ ~ /tJ-rf"'r·tJ9 

Received By. (SignaiJII) 7 Date/ Tlme 

Contact Person: 

~R~ece--I~~~~By.-.~(S~Ig-~~~~-.~,--------------~0-at-e~/~Tl~m-e----------~~Phone: 

Fax: 

8 - .I 

I Analysis Requested 

pH, SC, Chortde, Sulfate, / 

Alkalinity, Acidity, Bromide 

TSS, TDS, Dissolved Iron, 

Boron, BOO, MBAS Surfactants 

AI, As, Ba, Be, Cd, Cr, Co, Cu. Fe, Pb, Mg, 

Mn, Hg, Ni, Se, Ag, Sr, Zn, Li, Na, Ca, Mo, Hardnfss 

Nitrate+Nitrite, TKN, Ammonia, COO 

Gross Alpha, Gross Beta 

Radium 226, Radium 228 

Thorium, Uranium 

011 & Grease 

I Total Phenolics 

I Ethylene Glycol 

I Benzene, Toluene 

I Benzene, Toluene 

XTO ENERGY 

395 AIRPORT ROAD 

INDIANA, PA 15701 

MR. MIKE HAHN 

(724) 349-0600 

(724) 349-8489 

,, II '9t/,~ I Ll 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/812009 9:15AM 

10/8/2009 2:42 PM 

10/30/2009 

Analyte 

Acidity to pH=8.3 

Alkalinity to pH=4.5 

Biological Oxygen Demand 05 

Chemical Oxygen Demand 

Ammonia as N I Distilled 

Bromide 

Chloride 

Kjeldahl Nitrogen as N 

pH(SM) 

Sulfate ASTM 

Total Nitrate+ Nitrite as N 

Aluminum - ICP 

Arsenic-ICP 

Barium- ICP 

Beryllium- ICP 

Boron 

Cadmium - I~P 

Calcium- ICP 

Chromium- ICP 

Cobalt- ICP 

Copper- ICP 

Hardness 

Report of Analysis 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Ha118431 H 

? 

~~ 

Units 

. 7 

:;rt-k. 

Method RPL 

BF 10/11/2009 ND mg/1 as CaC03 SM2310B 2 

JS 10/1212009 175 mg/1 as CaC03 SM2320B 20 

szc 10/1212009 

6~.7 mg/1 SM5210B 2.0 

MAD 10/15/2009 1002.5 mg/1 SM5220D 500.0 

MAD 10/1912009 62.73 mg/1 )M4500NH3B & I 1.00 

AID 10121/2009 554.00 mg/1 Dl246-99 20.00 

BF 10/09/2009 51663.1 mg/1 SM4500ClC 1.0 

MAD 1 0/19/2{)09 33.1 mg/1 SM4500Norg-C,D 5.5 

LL 10/0812009 6.60 su SM4500H-B 0.01 

LMB 10/12/2009 ND mg/1 D516-02 5 

AJD 10/19/2009 ND mg/1 SM4500N03E 0.05 

GJT 1012112009 ND mg/1 200.7/6010 1.000 

GJT 10122/2009 ND mg/1 200.7/6010 1.000 

GJT 1012112009 388.800 mg/1 200.7/6010 0.500 

GJT 1012212009 ND mg/1 200.7/6010 0.500 

MAD 10126/2009 15.00 mg/1 SM4500B-B 12.50 

GJT 10122/2009 ND mg/1 · 200.7/6010 0.500 

GJT 10/22/2009 4248.800 mg/1 200.7/6010 50.000 

GJT 1012112009 ND mg/1 200.7/6010 0.500 

GJT 1012112009 ND mg/1 200.7/6010 0.500 

GJT 10/21/2009 ND mg/1 200.7/6010 0.500 I GJT ll0/23/20091 12192 mg/1 SM2340B 

Comments: Radiologicals done by Benchmark Analytical 

IND=Not Detected 

Note: DEP Certification #s 32-00382 

Data Qualffiers: 0 = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B = Analyte was detected in both sample and methods blank. x = User defined data qualifier. 
Report of Analysis 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 9:15AM 

10/8/2009 2:42 PM 

10/30/2009 

Analyte 

Iron- ICP 

Iron,Dissolved-ICP 

Lead-ICP 

Lithium - ICP 

Magnesium-ICP 

Manganese - ICP 

Mercury 

Molybedenum - ICP 

Nickel- ICP 

Selenium-ICP 

Silver-ICP 

Sodium- ICP 

Strontium - ICP 

Zinc- ICP 

Detergents, MBAS 

Ethylene Glycol 

Oil and Grease - HEM 

Phenolics, as Phenol 

Specific Conductance 

Total Dissolved Solids (TDS) 

Total Suspended Solids 

Radiologicals 

Analyst 

GJT 

GJT 

GJT 

GJT 

GJT 

GJT 

DMM 

GJT 

GJT 

GJT 

GJT 

GJT 

GJT 

GJT 

TL 

~etPeak 

CLM 

MAD 

LL 

CLM 

ALD 

enchmru 

Comments: Radiologicals done by Benchmark Analytical 

Note: DEP Certification #s 32-00382 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

10/21/2009 38.600 

10/21/2009 21.200 

10/21/2009 ND 

10/22/2009 72.500 

10/23/2009 384.400 

10/21/2009 4.000 

10/15/2009 ND 

10/21/2009 ND 

10/21/2009 ND 

10/21/2009 ND 

10/22/2009 ND 

10/22/2009 26743.000 

10/23/2009 720.700 

10/21/2009 ND 

10/09/2009 0.614 

10/20/2009 <25.000 

'1 0120/2009 ND 

10/13/2009 ND 

10/08/2009 112400 

10/14/2009 104800 

10/13/2009 472 

10/30/2009 * 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Hall8431 H 

Units 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1-

mg/1 

mg/1 

mgll 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mglkg 

mg/1 

mg/1 

uS/em 

mg/1 

mg/1 

mg/1 

Data Qualifiers: 0 = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

Method RPL 

200.7/6010 1.000 

200.7/6010 1.000 

200.7/6010 0.500 

200.7/6010 50.000 

200.7/6010 50.000 

200.7/6010 0.500 

245.1 0.0002 

200.7/6010 0.500 

200.7/6010 0.500 

200.7/6010 1.000 

200.7/6010 0.500 

200.7/6010 500.000 

200.7/6010 1.000 

200.7/6010 0.500 

SM5540C 0.200 

300.0M 25.000 

1664A 5.0 

420.1 0.500 

SM 2510B l 

SM2540C 25 

SM2540D 5 

RAD-CTDHS 0.000 

!ND=Not Detected 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. x = User defined data qualifier. 

Page 2 of 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

1) Benzene 

47) Toluene 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/812009 9:15AM 

10/812009 2:42PM 

10/30/2009 

Analyte 

Report of Analysis 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

RO 10/09/2009 26.40 

RO 10/0912009 ND 

Comments: Radiologicals done by Benchmark Analytical 

. ~ DEP Certification #s 32-00382 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Hall8431 H 

Units 

ug!L 

ugiL 

Data Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

Method RPL 

624/8260B 20.00 

624/8260B 20.00 

jND=Not Detected 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 
ADDRESS: 1803 Philadelphia St 

PHONE: 

FAA: 

Indiana, PA 15701 

(724) 463-8378 

(724) 465-4209 

09 29350 & 09 29510 

RECEIVED FOR LAB BY: DMB 

TEST REPORT 

DATE: 10/12fl009 10:00 

PO#: DAS1 0092009 

PWSID# 

Page2 of2 

SAMPLE: 09 29510 Lab 10: 09101656-002E Grab 

SAMPLED BY: David A. Stile Sampte TII'M 1010812009 9:15 

BDYit 

~ MOA Units 

Thorium < 0.0131 :t: 0.00 0 mgA. 

~ 

EPA200.8 

SAMPlE: 09 29510 Lab ID: 09101656-002A 

SAMPLED BY: David A. Stile Sample Time 1010812009 9:15 

!Hi Result 

~ Y2A Units 

~ 

Gross Alpha 1971 ;t 221.3 746.9 pCVL EPA900.0 

Gross Beta 228S ;t 140.7 682.4 pClll EPA900.0 ~ aDil!)til& Start Ana!vsls End Ana!vst • 1011~ 8:30 10/16109 GSR-CV --- Grab ~ Analysis Stat\ Ana!vG!s End ~ 10/13109 8:50 10116109 BP$-CV 10/13109 8:50 10115109 BP5-CV 

--------·· SAMPlE 09 29510 Lab 10: 09101656-002B Grab 

SAMPLED BY: Da\lld A. stile Sample Time 1010812009 9:15 

B.wt!l Yl!9!!!. 

Radlum-226 464.9 ;I; 15.84 

---··----

SAMPLE: 09 29510 

g 

59.4 

Units MdK!!! 

pCill EPA 903.0 

---

LabiD: 09101~ 

SAMPLED BY: Davicl A. Stile SampleTme 10108120099:15 

I@ 

Radium-228 

~ lJ.!ls;!d. MQ6 l.!!l!t! 

148.7 :t: 11.10 1-4.16 pCitL EPA904.0 

f&. 6nalys!s Start Matv* Encl ~ 

1011610911:15 10129109 BH-CV Gr.~b ,Mg. Analysis Start Ana!ysi9 End ~a: 

10121109 8:0~ 10/27109 NLB-CV 

··--·· ---- ···-----· --·· ·- . . . ···- SAMPLE: 09 29510 Lab 10: 09101658-0020 Grab 

SAMPLED BY: David A. Stile Sample Tme 1010812009 9:15 ~ Uranium 

Ur.~nlum 

Result 

< 13.13 

<8.93 

~ 

t 0.00 

:1: 0.00 

MDA !.!nl1§. 

0 ~II.. MS 

0 pCi/L 

~ 

EPA200.8 

EPA200.8 

MCL Anetvsis Start AnalYsis End ~ 

30 10/1910910:00 10123109 GSR..CV 

10/19/09 10:00 10123109 GSR-CV 

·---

.. ·-· 

REMARKS: 

The e~bove test procedures meet all the requirements of NELAC and relate only to these samples. 

• CV =Benchmark Ane~lytics, Inc. Center Valley, PA: SA"" Benchmark Ane~lytics, Inc. Sayre, PA 

MS Umit of Cletectlon increased dve to matrix interference 01nd spike recovery data 

MANAGER 

· ·--· ~trkL 

. ~ DATE: 1013012009 
Name: XTOEnergy 

Sample Start Date: 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 

10/8/2009 2:42PM 

10/12/2009 

Receipt Date: 

Report Date: 

Analyte 

1) Benzene 

47) Toluene 

Comments: 

DEP Certification #s 32-00382 

Report of Analysis 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

RO 10/0912009 ND 

RO 10/09/2009 ND 

09 29511 

Waste Water 

Grab 

NEW (Client) 

Trip Blank 

Units 

ug/L 

ug!L 

Method MDL 

624/8260B 1.00 

624/8260B 1.00 

IND=Not Detected 

Page 1 of 1 
General Reference 287.54 

Date Prepared/Revised 219111 

c. 

State 

PA 

First Name 

Ben 

Company Mailing Address Une 

Zip+4 

15701 

Ml 

opaque white/orange Odor 

Number of Solid or Uquld Phases of Separation 

EPA Generator 

Describe each phase ofseparation.~~---------------1 

a. 

- 1 -
c. 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

Phone 

d. waste shipped to processing or 

a. 

b. Facility Name 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

c. 

Title 

0 cuyd ~ gal D lb 

processing or disposal 

-2-

County Indiana 

steve@pabrine.com 

year. 

0 ton (check one) 

being utilized. 

County 

(check one) 

Oton (check one) 
Submitted: D Form 26R 

0 Other (specify) 

Date Submitted: 

0 I certify the information required In Section B-2, Chemical Analysis was supplied to the Deparbnent for the year 

_and has not changed. 

Form Submitted: 0 Form26R 

0 Other (specify) 

Date Submitted: 

0 I certify the information required In Section B-3, Process Description and Schematic, was supplied to the Deparbnent for the year __ and has not changed. 

Form Submitted: 0 Form 26R 

0 Other (specify) 

Date Submitted: 

Name of Responsible Official 

Bernhardt Kissel 

Signature Date 2-28-11 

-3-
GENERA TOR KNOWLEDGE 

All Form 26R Waste Forms have been compiled, and future testing has been 

scheduled, to obtain samples of each waste stream on a PAD by PAD basis. Sample 

analyses will be conducted every 5 years for each waste stream unless the process that 

generates any particular waste stream is substantially altered. 

Attached analytical results for this waste stream have been obtained from a similar 

waste stream producing waste from the same geologic formation as this 26R Report. 

Additionally, the mud mixtures, chemical formulations and drilling process utilized at this 

well PAD are substantially the same as those utilized at the well where the attached 

waste analyticals were generated. 
Brine fluids are composited within the storage production tank or tank battery at each well site where gas production is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tan-k trucks for disposal at various PaDEP 

permitted waste disposal facilities on different schedules determined by individual well 

characteristics. Grab samples of the composited fluids were obtained at the 

represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of 

lost fluids. 

Samples were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. 

Flowback samples were composited to the extent possible during the flowback process primarily during times where safety issues did not override sample collection 

requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and 

combined into a composite sample for analyses at the laboratory. On several wells, 

cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites. In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the 

randomness of the composite sample and cqmposite grid sample positions were varied 

to the extent possible. 

Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned 

and reused from well to well. 
onn 26R: Section B3a 

WASTE GENERATION PROCESS 

Pit Water "Drill Fluids" 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and fonnation fluids. These fluids are brought to 

the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are 

mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

Flowback: "Fracing Fluid" 

Flowback is produced from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the 

fonnation fractures. 

Production Fluid "Brine" 

During the production of natural gas, formation pressures bring remnant frac fluids, 

during the initial production phase, and fonnation fluids to the surface along with 

produced gas. 
-

Well I. D.# (various) 

'\/ 

-a-

/1' \ 

\ 

\ 

\ 

\ 

\ 

\ 

\ COUNTYB 

ote: . 

\ 

\ 

Process producing waste: Gas well produced 

fluids (brines) are typically produced" in 

conjuction wi.th natural gas. These fluids 

are brought to the surface utilizing either 

mechanical or physical lift procedur.es. 

/ 

/ 

COUNTY A 

Well I. D.# (various) 

\ I .::o/ 

/I I~ / 

/ 

/ 

/ 

/ 

Mobile Tank Truck 

_ s Road Transport 

(.') 

w 

~ :c 

(..) 

en 

z 

0 

~ 1-

~ 

0 

0.. 

en 

z 

~ 1-

~illf 

~~~I ii 

.! 

t ~ 

i I ~ I ~ 

~~ 

Landfi II or- ~ i § 

Trec..+o.t<A+ 'PIC4At .I! H 

~ I! ~ ~ ~~ 

;;;! 2 

u 
•w• ~- •• 

ENVIRONMENTAL SERVICE SAMPLE REQUEST & CHAIN OF CUSTODY LABORATORIES~ INC. PAGE __ OF 

1--

... HEADQUARTERS: 

~ SOUTHERN DIVISION: 8 1803 Philadelphia St. 1276 Bentleyville Road D Indiana, PA 15701 Van Voorhis, PA 15388 REC'D NOV -4 2009 - ..I 

(724) 463-TEST (724) 258-TEST 

(724) 465-4209 (724) 258-8376 .. 

FOR INTERNAL LABORATORY USE ONLY 

Sample Type 

Sample Identification ESL# Composite Grab Matrix # of Containers Container Type Analysis Requested 

Date on/off Time on/off Date Time · Preservative 

11141/, J?l/31 fl. 0!9: ~!() ---- ----- /0 /__./A \foNJ Plastic Liter pH, SC, Chorlde, Sulfate, / 

------ ------ t:'ft IS 1 

'~L""' none Alkalinity, Acidity, Bromide 

----- ----- lrt>~J:. ,., 1~ \foNJ Plastic Uter TSS, TDS, Dissolved Iron, 

--- ----- 1t:J I~ 2 none Boron, BOD, MBAS Surfactants 

~ 

------ 1/o«J:. \foNJ Plastic Liter AI, As, Sa, Be, Cd, Cr, Co, Cu, Fe, Pb, Mg, 

----- ------ It!> ~ ' 1.5 1 

HN03 Mn, Hg, Nl, Se, Ag, Sr, Zn, Li, Na, Ca, Mo, Hard ress 

----- ------ ~~ 17 '1 t5 \foNJ Plastic Liter 

----- ------ 10 1 Nitrate+Nitrite, TKN, Ammonia, COD 

H:z$04 

---- ------ v~tk (2) 1000 mL Plastic Liter Gross Alpha, Gross Beta 

~ ~ 'lo~ ' I~ \foNJ (3) 500 mL Radium 226, Radium 228 

!5o HN03 Thorium, Uranium 

----- ------- \foNJ Amber Glass L 

---- ----- 10 o8 Cj 15 1 Oil &Grease 

HCI 

----- ------ btrk \foNJ 1 Amber Glass L 

----- ------ /0 ~ 1:1> H2S04 

Total Phenolics 

----- ----- 'b8k ., 1'5 \foNJ 2 Amber VOA Vials 

----- ------ to none Ethylene Glycol 

. --- ----- 1ey 08/a 1~ ,, \foNJ 2 Amber VOA Vials 

' ~ 

-------- HCI 

Benzene, Toluene 

TRIP BLANK 09 ---- ------- ::::::::::-~ Water 2 :Amber VOA Vials 

'215"'11 ----- ------- HCI 

Benzene, Toluene 

THE UNOERSIGNEO PURCHASER HEREBY AGREES TO PAY SERVICE CHARGES ON ACCOUNTS OVER 31 llo'YS OLD. Project Notes: 

1. THESE SERVICE CHARGES WILL ACCRUE AT THE RATE OF 1 1/2% PER MONTH (18% PER ANNUM OR THE MAXIMUM ALLOWED BY lAW.) 

2. THE UNDERSIGNED PURCHASER AGREES TO PAY. IN THE EVENT HIS ACCOUNT BECOMES DEUNQUENT AND IS TURNED OVER TO ANY 

ATTORNEY FOR COLLECTION, REASONABLE ATTORNEY'S FEES PLUS ALL COURT AND ATTENDANT COLLECTION COSTS. 

A'_/ .J~-/ tok/~ 9 .. /$"~H? Company/Name: XTO ENERGY 

Sampl~ By: (Signature) Mate/ Tlme 

'( a d.#_ ~ ll'>~'i<'-o"r rl{~~{ . ~-~ { o -K-ocr ILf\~~ Address: 395 AIRPORT ROAD 

Relinquish~y: (SignatureJ.. Date/ Time ~cslgnU r-1£ .date/Tlme Nl/3 INDIANA, PA 15701 

1?'~ lo-g-cq ( Lf\ ~s- 'd:- ~, / /) -tf"',-t5J 7 

Relinquished By: (Signature) Date/ Tlme ltecelved By: cslgn811h.) I Date/ Tlme r. 

Contact Person: MR. MIKE HAHN 

Relinquished By: (Signature) Date/ Time Received By: (Sip!'") Date/ Tlme Phone: (724) 349-0600 ' 

CHAIN OF CUSTODY SEAL BROKEN: Yes No Fax: (724) 349-8489 

- I I . II '9'£~/ IJ 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

XTOEnergy 

395 Airport Road 

Indiana, P A 1570 1 

10/8/2009 9:15AM 

10/8/2009 2:42 PM 

l0/30/2009 

Analyte 

Acidity to pH=8.3 

Alkalinity to pH=4.5 

Biological Oxygen Demand 05 

Chemical Oxygen Demand 

Ammonia as N I Distilled 

Bromide 

Chloride 

Kjeldahl Nitrogen as N 

pH(SM) 

SulfateASTM 

Total Nitrate+ Nitrite as N 

Aluminum - ICP 

Arsenic-ICP 

Barium- ICP 

Beryllium - ICP 

Boron 

Cadmium - ICP 

Calcium - ICP 

Chromium- ICP 

Cobalt- ICP 

Copper- ICP 

Hardness 

Report of Analysis 

Analyst Analysis 

Date 

BF 10/11/2009 

IS 10/1212009 

szc 10/12/2009 

MAD 10/15/2009 

MAD 10/19/2009 

AID 10/21/2009 

BF 10/09/2009 

MAD 10/19/2009 

LL 10/08/2009 

LMB 10/12/2009 

AID 10/1912009 

GJT 10/21/2009 

GJT 10/22/2009 

GJT 10/21/2009 

GJT 10/22/2009 

MAD 10/26/2009 

GJT 10/22/2009 

GJT 10/22/2009 

GJT 10/21/2009 

GJT 10/21/2009 

GJT 10/21/2009 

GJT 10/23/2009 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Sample 

Result 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Hall8431 H 

? ;n.tc 4-

Units Method 

ND mgfl as CaC03 SM2310B 

175 mgfl as CaC03 SM2320B 

68.7 mgfl SM5210B 

1002.5 mgfl SM5220D 

62.73 mgfl sM4500NH3B&tt 

554.00 mgfl D1246-99 

51663.1 mg/1 SM4500ClC 

33.1 mg/1 SM4500Norg-C,D 

6.60 su SM4500H-B 

ND mg/1 0516-02 

ND mg/1 SM4500N03E 

ND mg/1 200.7/6010 

ND mg/1 200.7/6010 

388.800 mg/1 200.7/6010 

ND mg/1 200.7/601~ 

15.00 mg/1 SM4500B-B 

ND mg/1 . 200.7/6010 

4248.800 mg/1 200.7/6010 

ND mg/1 200.7/6010 

ND mg/1 200.7/6010 

ND mg/1 200.7/6010 

12192 mg/1 SM2340B 

RPL 

2 

20 

2.0 

500.0 

1.00 

20.00 

1.0 

5.5 

0.01 

5 

0.05 

1.000 

1.000 

0.500 

0.500 

12.50 

0.500 

50.000 

0.500 

0.500 

0.500 

1 

Comments: Radio1ogicals done by Benchmark Analytical JND=Not Detected 

Note: DEP Certification #s 32-00382 

Data Qualifiers: D = The reported value is from dilution. E "" Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 1 of 3 
Report of Analysis 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/812009 9:15AM 

10/8/2009 2:42 PM 

10/3012009 

Analyte 

Iron- ICP 

lron,Dissolved-ICP 

Lead-ICP 

Lithiwn - ICP 

Magnesiwn-ICP 

Manganese - ICP 

Mercury 

Molybedenwn - ICP 

Nickel- ICP 

Seleniwn-ICP 

Silver-ICP 

Sodiwn- ICP 

Strontiwn - ICP 

Zinc- ICP 

Detergents, MBAS 

Ethylene Glycol 

Oil and Grease - HEM 

Phenolics, as Phenol 

Specific Conductance 

Total Dissolved Solids (TDS) 

Total Suspended Solids 

Radiologicals 

Analyst 

GJT 

GJT 

GJT 

GJT 

GJT 

GJT 

DMM 

GJT 

GJT 

GJT 

GJT 

GJT 

GJT 

GJT 

TL 

MetPeak 

CLM 

MAD 

LL 

CLM 

ALD 

enchmru 

Comments: Radiologicals done by Benchmark Analytical 

Note: DEP Certification #s 32-00382 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

10121/2009 38.600 

1012112009 21.200 

10/21/2009 ND 

10122/2009 72.500 

10/23/2009 384.400 

1012112009 4.000 

10/1512009 ND 

1012112009 ND 

1012112009 ND 

10/2112009 ND 

10/2212009 ND 

1012212009 26743.000 

10/2312009 720.700 

10/21/2009 ND 

10/09/2009 0.614 

10/20/2009 <25.000 

·t0/20/2009 ND 

10/1312009 ND 

10/08/2009 112400 

10/14/2009 104800 

10/13/2009 472 

10/30/2009 * 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Hall8431 H 

Units 

mg/1 

mg/1 

mg/1 

mg/1 

mgllmg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mglkg 

mg/1 

mg/1 

uS/em 

mg/1 

mg/1 

mg/1 

Data Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

Method RPL 

200.7/6010 1.000 

200.7/6010 1.000 

200.7/6010 0.500 

200.7/6010 50.000 

200.7/6010 50.000 

200.7/6010 0.500 

245.1 0.0002 

200.7/6010 0.500 

200.7/6010 0.500 

200.7/6010 1.000 

200.7/6010 0.500 

200.7/6010 500.000 

200.7/6010 1.000 

200.7/6010 0.500 

SM5540C 0.200 

300.0M 25.000 

1664A 5.0 

420.1 0.500 

SM 2510B 1 

SM2540C 25 

SM2540D 5 

RAD-CTDHS 0.000 

IND=Not Detected 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. x = User defined data qualifier. 

Page 2 of 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

1} Benzene 

47) Toluene 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 9:15AM 

10/812009 2:42PM 

10/30/2009 

Analyte 

Report of Analysis 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

RO 10/09/2009 26.40 

RO 10/09/2009 ND 

Comments: Radiologicals done by Benchmark Analytical 

Note: DEP Certification #s 32-00382 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Hall8431 H 

Units 

ug!L 

ugiL 

Data Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

Method RPL 

624/8260B 20.00 

624/8260B 20.00 

JND=Not Detected 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B = Analyte was detected in both sample and methods blank. x = User defined data qualifier. 

Page 3 of 3 
PHONE: 

FAA: 

Indiana, PA 15701 

(724) 463-8378 

(724) 465-4209 

TEST REPORT 

PO#: OAS10092009 

PWSID# 

09 29350 & 09 29510 

RECEIVED FOR LAB BY: DMB DATE: 10/121200910:00 Page2 of2 

SAMPLE: 09 29510 Lab tO; 09101656-002E Grab 

SAMPLED BY: David A. Stl1e 

.nm B!!!!!t 

Thorium < 0.0131 

---

SAMPLE: 09 29510 

SAMPLED BY: David A. Stile 

IHt Result 

Gross .Alpha 1971 

Gross Beta 2286 

SAMPLE: 09 29510 

SAMPLED BY: David A Stile 

nml &at!l 

Radium-226 464.9 

SAMPLE: 09 29510 

SAMPLED BY: David A. Stile 

Sample Tltne 1010812009 9:15 

~ 

~ Yn!!! 

~ 

:t 0.00 0 mgll EPA200.8 

Lab ID: 09101656-002A 

Sample Time 10/0612009 9:15 

~ g Units 

~ 

:t22U 746.9 pCVl. EPA900.0 

t 140.7 682.4 pCIIL EPA900.0 

Lab 10: 09101656-0029 

Sample Tine 1010812009 9:15 

~ MQ.a Units .M!1tm. 

:t 15.84 59.4 pCiiL EPA 903.0 

Lab ID: 09101656-002C 

Sample T~me 1010812009 9:15 

I!S 

Radium-228 

~~ 

148.7 :t 11.10 

MQ6 

14.16 

l.!!llt! 

~ 

pCUL EPA 904.0 

ltQ. AQa!Y* start Analysis End AnalYst • 

10113109 8:30 10116109 GSR-CV 

---

Grab 

MQ!s Ana!ys!s Start Analysis End ~ 

10113109 a:so 10116109 BPs-cv 

10113109 8:50 10116109 BP~CV 

Grab 

M!d. Analysis Start AnalySis End ~ 

1011610911:15 10129109 BH-CV 

Grab 

m Analysis Start AnalysiS End &Wia! 

10121109 8:05 10/27109 NLB-CV 

··-----· ---·--- SAMPLE: 09 29510 Lab 10:· 0910165$-0020 Grab 

SAMPLED BY: David A. Stile Sample Tme 1010812009 9:15 

!U1 Result 

~ 

Uranium < 13.13 :t 0.00 

~nlum <8.93 :1: 0.00 

!@A !.!nl1l 

0 J.Jg/L 

0 pCiiL 

~ 

EPA200.8 

EPA200.8 

~ AnaMis Start Anatvsis End ~ 

30 10119109 10:00 10123109 GSR-CV 

10/19109 10:00 10123109 GSR-CV 

··--

.. 

·-· ·---·· ·--······-

REMARKS: 

The above test procedures meet all the requirements of NELAC and relate only to these samples. " CV .. Benchmark Analytics, Inc. Center Valley, PA; SA= Benchmark Analytics, Inc. Sayre, PA 

MS Umit of ctetectlon increased due to matrix interference and spike recovery data 

MANAGER 

. " ~md . . ... DATE: /0/3012009 
Name: XTOEnergy 

Sample Start Date: 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 

10/812009 2:42 PM 

10/12/2009 

Receipt Date: 

Report Date: 

Analyte 

1) Benzene 

47) Toluene 

Comments: 

DEP Certification #s 32-00382 

Report of Analysis 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

RO 10/09/2009 ND 

RO 10/09/2009 ND 

09 29511 

Waste Water 

Grab 

NEW (Client) 

Trip Blank 

Units 

ug/L 

ug/L 

Method MDL 

624/8260B 1.00 

624/8260B 1.00 

IND=Not Detected 

Paae 1 of 1 
General Reference 287.54 

Date Prepared/Revised 219111 

c. 

State 

PA 

First Name 

Ben 

Company Mailing Address Une 

Zip+4 

15701 

Ml 

opaque white/orange Odor 

Number of Solid or Uquld Phases of Separation 

EPA Generator 

Describe each phase ofseparation.~~---------------1 

a. 

- 1 -
c. 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

Phone 

d. waste shipped to processing or 

a. 

b. Facility Name 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

c. 

Title 

0 cuyd ~ gal D lb 

processing or disposal 

-2-

County Indiana 

steve@pabrine.com 

year. 

0 ton (check one) 

being utilized. 

County 

(check one) 

Oton (check one) 
Submitted: D Form 26R 

0 Other (specify) 

Date Submitted: 

0 I certify the information required In Section B-2, Chemical Analysis was supplied to the Deparbnent for the year 

_and has not changed. 

Form Submitted: 0 Form26R 

0 Other (specify) 

Date Submitted: 

0 I certify the information required In Section B-3, Process Description and Schematic, was supplied to the Deparbnent for the year __ and has not changed. 

Form Submitted: 0 Form 26R 

0 Other (specify) 

Date Submitted: 

Name of Responsible Official 

Bernhardt Kissel 

Signature Date 2-28-11 

-3-
GENERA TOR KNOWLEDGE 

All Form 26R Waste Forms have been compiled, and future testing has been 

scheduled, to obtain samples of each waste stream on a PAD by PAD basis. Sample 

analyses will be conducted every 5 years for each waste stream unless the process that 

generates any particular waste stream is substantially altered. 

Attached analytical results for this waste stream have been obtained from a similar 

waste stream producing waste from the same geologic formation as this 26R Report. 

Additionally, the mud mixtures, chemical formulations and drilling process utilized at this 

well PAD are substantially the same as those utilized at the well where the attached 

waste analyticals were generated. 
Brine fluids are composited within the storage production tank or tank battery at each well site where gas production is occurring. Each automatic or manual ejection of formation fluids is deposited into the tank(s) and added to the previously ejected and stored quantity. Tanks are emptied into tan-k trucks for disposal at various PaDEP 

permitted waste disposal facilities on different schedules determined by individual well 

characteristics. Grab samples of the composited fluids were obtained at the 

represented well pads directly from the storage tank drain ports. All drain ports had small "built in" containment and storage "buckets" capable of retaining small amounts of 

lost fluids. 

Samples were obtained with bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory. 

Flowback samples were composited to the extent possible during the flowback process primarily during times where safety issues did not override sample collection 

requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers and smaller aliquot portions at the laboratory or on the well location upon completion of the composite sampling process. Samples were distributed into bottle sets prepared at the laboratory which contained appropriate preservatives, as necessary, depending on the specific test run requested. All chain of custody and handling/holding time requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and 

combined into a composite sample for analyses at the laboratory. On several wells, 

cuttings from the vertical portion of the well bore were segregated from cuttings from the target Marcellus Formation and separate testing was completed on both sample composites. In some earlier cases during the utilization of open pits, composite samples were obtained from inactive drill pits. Safety concerns usually limited the 

randomness of the composite sample and cqmposite grid sample positions were varied 

to the extent possible. 

Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned 

and reused from well to well. 
onn 26R: Section B3a 

WASTE GENERATION PROCESS 

Pit Water "Drill Fluids" 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and fonnation fluids. These fluids are brought to 

the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are 

mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

Flowback: "Fracing Fluid" 

Flowback is produced from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the 

fonnation fractures. 

Production Fluid "Brine" 

During the production of natural gas, formation pressures bring remnant frac fluids, 

during the initial production phase, and fonnation fluids to the surface along with 

produced gas. 
-

Well I. D.# (various) 

'\/ 

-a-

/1' \ 

\ 

\ 

\ 

\ 

\ 

\ 

\ COUNTYB 

ote: . 

\ 

\ 

Process producing waste: Gas well produced 

fluids (brines) are typically produced" in 

conjuction wi.th natural gas. These fluids 

are brought to the surface utilizing either 

mechanical or physical lift procedur.es. 

/ 

/ 

COUNTY A 

Well I. D.# (various) 

\ I .::o/ 

/I I~ / 

/ 

/ 

/ 

/ 

Mobile Tank Truck 

_ s Road Transport 

(.') 

w 

~ :c 

(..) 

en 

z 

0 

~ 1-

~ 

0 

0.. 

en 

z 

~ 1-

~illf 

~~~I ii 

.! 

t ~ 

i I ~ I ~ 

~~ 

Landfi II or- ~ i § 

Trec..+o.t<A+ 'PIC4At .I! H 

~ I! ~ ~ ~~ 

;;;! 2 

u 
•w• ~- •• 

ENVIRONMENTAL SERVICE SAMPLE REQUEST & CHAIN OF CUSTODY LABORATORIES~ INC. PAGE __ OF 

1--

... HEADQUARTERS: 

~ SOUTHERN DIVISION: 8 1803 Philadelphia St. 1276 Bentleyville Road D Indiana, PA 15701 Van Voorhis, PA 15388 REC'D NOV -4 2009 - ..I 

(724) 463-TEST (724) 258-TEST 

(724) 465-4209 (724) 258-8376 .. 

FOR INTERNAL LABORATORY USE ONLY 

Sample Type 

Sample Identification ESL# Composite Grab Matrix # of Containers Container Type Analysis Requested 

Date on/off Time on/off Date Time · Preservative 

11141/, J?l/31 fl. 0!9: ~!() ---- ----- /0 /__./A \foNJ Plastic Liter pH, SC, Chorlde, Sulfate, / 

------ ------ t:'ft IS 1 

'~L""' none Alkalinity, Acidity, Bromide 

----- ----- lrt>~J:. ,., 1~ \foNJ Plastic Uter TSS, TDS, Dissolved Iron, 

--- ----- 1t:J I~ 2 none Boron, BOD, MBAS Surfactants 

~ 

------ 1/o«J:. \foNJ Plastic Liter AI, As, Sa, Be, Cd, Cr, Co, Cu, Fe, Pb, Mg, 

----- ------ It!> ~ ' 1.5 1 

HN03 Mn, Hg, Nl, Se, Ag, Sr, Zn, Li, Na, Ca, Mo, Hard ress 

----- ------ ~~ 17 '1 t5 \foNJ Plastic Liter 

----- ------ 10 1 Nitrate+Nitrite, TKN, Ammonia, COD 

H:z$04 

---- ------ v~tk (2) 1000 mL Plastic Liter Gross Alpha, Gross Beta 

~ ~ 'lo~ ' I~ \foNJ (3) 500 mL Radium 226, Radium 228 

!5o HN03 Thorium, Uranium 

----- ------- \foNJ Amber Glass L 

---- ----- 10 o8 Cj 15 1 Oil &Grease 

HCI 

----- ------ btrk \foNJ 1 Amber Glass L 

----- ------ /0 ~ 1:1> H2S04 

Total Phenolics 

----- ----- 'b8k ., 1'5 \foNJ 2 Amber VOA Vials 

----- ------ to none Ethylene Glycol 

. --- ----- 1ey 08/a 1~ ,, \foNJ 2 Amber VOA Vials 

' ~ 

-------- HCI 

Benzene, Toluene 

TRIP BLANK 09 ---- ------- ::::::::::-~ Water 2 :Amber VOA Vials 

'215"'11 ----- ------- HCI 

Benzene, Toluene 

THE UNOERSIGNEO PURCHASER HEREBY AGREES TO PAY SERVICE CHARGES ON ACCOUNTS OVER 31 llo'YS OLD. Project Notes: 

1. THESE SERVICE CHARGES WILL ACCRUE AT THE RATE OF 1 1/2% PER MONTH (18% PER ANNUM OR THE MAXIMUM ALLOWED BY lAW.) 

2. THE UNDERSIGNED PURCHASER AGREES TO PAY. IN THE EVENT HIS ACCOUNT BECOMES DEUNQUENT AND IS TURNED OVER TO ANY 

ATTORNEY FOR COLLECTION, REASONABLE ATTORNEY'S FEES PLUS ALL COURT AND ATTENDANT COLLECTION COSTS. 

A'_/ .J~-/ tok/~ 9 .. /$"~H? Company/Name: XTO ENERGY 

Sampl~ By: (Signature) Mate/ Tlme 

'( a d.#_ ~ ll'>~'i<'-o"r rl{~~{ . ~-~ { o -K-ocr ILf\~~ Address: 395 AIRPORT ROAD 

Relinquish~y: (SignatureJ.. Date/ Time ~cslgnU r-1£ .date/Tlme Nl/3 INDIANA, PA 15701 

1?'~ lo-g-cq ( Lf\ ~s- 'd:- ~, / /) -tf"',-t5J 7 

Relinquished By: (Signature) Date/ Tlme ltecelved By: cslgn811h.) I Date/ Tlme r. 

Contact Person: MR. MIKE HAHN 

Relinquished By: (Signature) Date/ Time Received By: (Sip!'") Date/ Tlme Phone: (724) 349-0600 ' 

CHAIN OF CUSTODY SEAL BROKEN: Yes No Fax: (724) 349-8489 

- I I . II '9'£~/ IJ 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

XTOEnergy 

395 Airport Road 

Indiana, P A 1570 1 

10/8/2009 9:15AM 

10/8/2009 2:42 PM 

l0/30/2009 

Analyte 

Acidity to pH=8.3 

Alkalinity to pH=4.5 

Biological Oxygen Demand 05 

Chemical Oxygen Demand 

Ammonia as N I Distilled 

Bromide 

Chloride 

Kjeldahl Nitrogen as N 

pH(SM) 

SulfateASTM 

Total Nitrate+ Nitrite as N 

Aluminum - ICP 

Arsenic-ICP 

Barium- ICP 

Beryllium - ICP 

Boron 

Cadmium - ICP 

Calcium - ICP 

Chromium- ICP 

Cobalt- ICP 

Copper- ICP 

Hardness 

Report of Analysis 

Analyst Analysis 

Date 

BF 10/11/2009 

IS 10/1212009 

szc 10/12/2009 

MAD 10/15/2009 

MAD 10/19/2009 

AID 10/21/2009 

BF 10/09/2009 

MAD 10/19/2009 

LL 10/08/2009 

LMB 10/12/2009 

AID 10/1912009 

GJT 10/21/2009 

GJT 10/22/2009 

GJT 10/21/2009 

GJT 10/22/2009 

MAD 10/26/2009 

GJT 10/22/2009 

GJT 10/22/2009 

GJT 10/21/2009 

GJT 10/21/2009 

GJT 10/21/2009 

GJT 10/23/2009 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Sample 

Result 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Hall8431 H 

? ;n.tc 4-

Units Method 

ND mgfl as CaC03 SM2310B 

175 mgfl as CaC03 SM2320B 

68.7 mgfl SM5210B 

1002.5 mgfl SM5220D 

62.73 mgfl sM4500NH3B&tt 

554.00 mgfl D1246-99 

51663.1 mg/1 SM4500ClC 

33.1 mg/1 SM4500Norg-C,D 

6.60 su SM4500H-B 

ND mg/1 0516-02 

ND mg/1 SM4500N03E 

ND mg/1 200.7/6010 

ND mg/1 200.7/6010 

388.800 mg/1 200.7/6010 

ND mg/1 200.7/601~ 

15.00 mg/1 SM4500B-B 

ND mg/1 . 200.7/6010 

4248.800 mg/1 200.7/6010 

ND mg/1 200.7/6010 

ND mg/1 200.7/6010 

ND mg/1 200.7/6010 

12192 mg/1 SM2340B 

RPL 

2 

20 

2.0 

500.0 

1.00 

20.00 

1.0 

5.5 

0.01 

5 

0.05 

1.000 

1.000 

0.500 

0.500 

12.50 

0.500 

50.000 

0.500 

0.500 

0.500 

1 

Comments: Radio1ogicals done by Benchmark Analytical JND=Not Detected 

Note: DEP Certification #s 32-00382 

Data Qualifiers: D = The reported value is from dilution. E "" Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 1 of 3 
Report of Analysis 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/812009 9:15AM 

10/8/2009 2:42 PM 

10/3012009 

Analyte 

Iron- ICP 

lron,Dissolved-ICP 

Lead-ICP 

Lithiwn - ICP 

Magnesiwn-ICP 

Manganese - ICP 

Mercury 

Molybedenwn - ICP 

Nickel- ICP 

Seleniwn-ICP 

Silver-ICP 

Sodiwn- ICP 

Strontiwn - ICP 

Zinc- ICP 

Detergents, MBAS 

Ethylene Glycol 

Oil and Grease - HEM 

Phenolics, as Phenol 

Specific Conductance 

Total Dissolved Solids (TDS) 

Total Suspended Solids 

Radiologicals 

Analyst 

GJT 

GJT 

GJT 

GJT 

GJT 

GJT 

DMM 

GJT 

GJT 

GJT 

GJT 

GJT 

GJT 

GJT 

TL 

MetPeak 

CLM 

MAD 

LL 

CLM 

ALD 

enchmru 

Comments: Radiologicals done by Benchmark Analytical 

Note: DEP Certification #s 32-00382 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analysis Sample 

Date Result 

10121/2009 38.600 

1012112009 21.200 

10/21/2009 ND 

10122/2009 72.500 

10/23/2009 384.400 

1012112009 4.000 

10/1512009 ND 

1012112009 ND 

1012112009 ND 

10/2112009 ND 

10/2212009 ND 

1012212009 26743.000 

10/2312009 720.700 

10/21/2009 ND 

10/09/2009 0.614 

10/20/2009 <25.000 

·t0/20/2009 ND 

10/1312009 ND 

10/08/2009 112400 

10/14/2009 104800 

10/13/2009 472 

10/30/2009 * 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Hall8431 H 

Units 

mg/1 

mg/1 

mg/1 

mg/1 

mgllmg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mglkg 

mg/1 

mg/1 

uS/em 

mg/1 

mg/1 

mg/1 

Data Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

Method RPL 

200.7/6010 1.000 

200.7/6010 1.000 

200.7/6010 0.500 

200.7/6010 50.000 

200.7/6010 50.000 

200.7/6010 0.500 

245.1 0.0002 

200.7/6010 0.500 

200.7/6010 0.500 

200.7/6010 1.000 

200.7/6010 0.500 

200.7/6010 500.000 

200.7/6010 1.000 

200.7/6010 0.500 

SM5540C 0.200 

300.0M 25.000 

1664A 5.0 

420.1 0.500 

SM 2510B 1 

SM2540C 25 

SM2540D 5 

RAD-CTDHS 0.000 

IND=Not Detected 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. x = User defined data qualifier. 

Page 2 of 
PHONE: 

FAA: 

Indiana, PA 15701 

(724) 463-8378 

(724) 465-4209 

TEST REPORT 

PO#: OAS10092009 

PWSID# 

09 29350 & 09 29510 

RECEIVED FOR LAB BY: DMB DATE: 10/121200910:00 Page2 of2 

SAMPLE: 09 29510 Lab tO; 09101656-002E Grab 

SAMPLED BY: David A. Stl1e 

.nm B!!!!!t 

Thorium < 0.0131 

---

SAMPLE: 09 29510 

SAMPLED BY: David A. Stile 

IHt Result 

Gross .Alpha 1971 

Gross Beta 2286 

SAMPLE: 09 29510 

SAMPLED BY: David A Stile 

nml &at!l 

Radium-226 464.9 

SAMPLE: 09 29510 

SAMPLED BY: David A. Stile 

Sample Tltne 1010812009 9:15 

~ 

~ Yn!!! 

~ 

:t 0.00 0 mgll EPA200.8 

Lab ID: 09101656-002A 

Sample Time 10/0612009 9:15 

~ g Units 

~ 

:t22U 746.9 pCVl. EPA900.0 

t 140.7 682.4 pCIIL EPA900.0 

Lab 10: 09101656-0029 

Sample Tine 1010812009 9:15 

~ MQ.a Units .M!1tm. 

:t 15.84 59.4 pCiiL EPA 903.0 

Lab ID: 09101656-002C 

Sample T~me 1010812009 9:15 

I!S 

Radium-228 

~~ 

148.7 :t 11.10 

MQ6 

14.16 

l.!!llt! 

~ 

pCUL EPA 904.0 

ltQ. AQa!Y* start Analysis End AnalYst • 

10113109 8:30 10116109 GSR-CV 

---

Grab 

MQ!s Ana!ys!s Start Analysis End ~ 

10113109 a:so 10116109 BPs-cv 

10113109 8:50 10116109 BP~CV 

Grab 

M!d. Analysis Start AnalySis End ~ 

1011610911:15 10129109 BH-CV 

Grab 

m Analysis Start AnalysiS End &Wia! 

10121109 8:05 10/27109 NLB-CV 

··-----· ---·--- SAMPLE: 09 29510 Lab 10:· 0910165$-0020 Grab 

SAMPLED BY: David A. Stile Sample Tme 1010812009 9:15 

!U1 Result 

~ 

Uranium < 13.13 :t 0.00 

~nlum <8.93 :1: 0.00 

!@A !.!nl1l 

0 J.Jg/L 

0 pCiiL 

~ 

EPA200.8 

EPA200.8 

~ AnaMis Start Anatvsis End ~ 

30 10119109 10:00 10123109 GSR-CV 

10/19109 10:00 10123109 GSR-CV 

··--

.. 

·-· ·---·· ·--······-

REMARKS: 

The above test procedures meet all the requirements of NELAC and relate only to these samples. " CV .. Benchmark Analytics, Inc. Center Valley, PA; SA= Benchmark Analytics, Inc. Sayre, PA 

MS Umit of ctetectlon increased due to matrix interference and spike recovery data 

MANAGER 

. " ~md . . ... DATE: /0/3012009 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

1} Benzene 

47) Toluene 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 9:15AM 

10/812009 2:42PM 

10/30/2009 

Analyte 

Report of Analysis 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

RO 10/09/2009 26.40 

RO 10/09/2009 ND 

Comments: Radiologicals done by Benchmark Analytical 

Note: DEP Certification #s 32-00382 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Hall8431 H 

Units 

ug!L 

ugiL 

Data Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

Method RPL 

624/8260B 20.00 

624/8260B 20.00 

JND=Not Detected 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B = Analyte was detected in both sample and methods blank. x = User defined data qualifier. 

Page 3 of 3 
Name: XTOEnergy 

Sample Start Date: 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 

10/812009 2:42 PM 

10/12/2009 

Receipt Date: 

Report Date: 

Analyte 

1) Benzene 

47) Toluene 

Comments: 

DEP Certification #s 32-00382 

Report of Analysis 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

RO 10/09/2009 ND 

RO 10/09/2009 ND 

09 29511 

Waste Water 

Grab 

NEW (Client) 

Trip Blank 

Units 

ug/L 

ug/L 

Method MDL 

624/8260B 1.00 

624/8260B 1.00 

IND=Not Detected 

Paae 1 of 1 
, 

a

d 

dentify the date 

prepared. The date on attached sheets needs to match the date noted below. 

General Reference 287.54 

Date Prepared/Revised 219/11 

Company Une2 

c. opaque white/orange Odor 

Number of Solid or Uquid Phases of Separation 

10# 

No 

Describe each phase of separation • ..:.:.:::~.=-----------------i 

- 1 -
Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

c. Facility Contact Name 

Title 

d. 

a. 

Phone 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

c. Facility Contact Name 

Title 

Phone 

County Indiana 

steve@pabrine.com 

(check one) 

for processing or disposal 

County 

to processing or disposal facility In the previous year. 

b. 

D cu yd D gal D lb D ton 

Volume of waste beneficially used in the un::vn.,u~ D cuyd 0 gal 

-2-

D ton (check one) 
Form Submitted: 0 Form 26R 

0 Other (specify) 

Date Submitted: 

0 I certify the Information required in Section B-2, Chemical Analysis was supplied to the Department for the year 

_and has not changed. 

Form Submitted: 0 Form26R 

0 Other (specify) 

Date Submitted: 

0 I certify the information required In Section B-3, Process Description and Schematic, was supplied to the Deparbnent for the year __ and has not changed. 

Form Submitted: 0 Form 26R 

0 Other (specify) 

Date Submitted: 

Name of Responsible Official 

Bernhardt Kissel 

Signature Date 2-28-11 

-3-
Form 26R: Section B1e 

GENERA TOR KNOWLEDGE 

All Form 26R Waste Forms have been compiled, and future testing has been scheduled, to obtain samples of each waste stream on a PAD by PAD basis. Sample analyses will be conducted every 5 years for each waste stream unless the process that generates any particular waste stream is substantially altered. 

Attached analytical results for this waste stream have been obtained from a similar waste stream producing waste from the same geologic formation as this 26R Report. 

Additionally, the mud mixtures, chemical formulations and drilling process utilized at this well PAD are substantially the same as those utilized at the well where the attached waste analyticals were generated. 
Brine fluids are composited within the storage production tank or tank battery at each 

well site where gas production is occurring. Each automatic or manual ejection of 

formation fluids is deposited into the tank{s) and added to the previously ejected and 

stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP 

permitted waste disposal facilities on different schedules determined by individual well 

characteristics. Grab samples of the composited fluids were obtained at the 

represented well pads directly from the storage tank drain ports. All drain ports had 

small "built in" containment and storage "buckets" capable of retaining small amounts of 

lost fluids. 

Samples were obtained with bottle sets prepared at the laboratory which contained 

appropriate preservatives, as necessary, depending on the specific test run requested. 

All chain of custody and handling/holding time requirements were met. In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot 

portions at the laboratory. 

Flowback samples were composited to the extent possible during the flowback process 

primarily during times where safety issues did not override sample collection 

requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers 

and smaller aliquot portions at the laboratory or on the well location upon completion of 

the composite sampling process. Samples were distributed into bottle sets prepared at 

the laboratory which contained appropriate preservatives, as necessary, depending on 

the specific test run requested. All chain of custody and handling/holding time 

requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and 

combined into a composite sample for analyses at the laboratory. On several wells, 

cuttings from the vertical portion of the well bore were segregated from cuttings from 

the target Marcellus Formation and separate testing was completed on both sample 

composites. In some earlier cases during the utilization of open pits, composite 

samples were obtained from inactive drill pits. Safety concerns usually limited the 

randomness of the composite sample and composite grid sample positions were varied 

to the extent possible. 

Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned 

and reused from well to well. 
Form 26R: Section B3a 

WASTE GENERATION PROCESS 

Pit Water "Drill Fluids" 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and formation fluids. These fluids are brought to 

the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are 

mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

Flowback: "Fracing Fluid" 

Flowback is produced from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the 

formation fractures. 

Production Fluid "Brine" 

During the production of natural gas, formation pressures bring remnant frac fluids, 

during the initial production phase, and formation fluids to the surface along with 

produced gas. 
Well I. D.# (~arious) Well I.·D.#.(various) 

'\\/ w -0 -y- /~, /1' 

I \ I 

\ / Well I. D.# (various) 

\ I ::H:. \ I // l 

\ I / \ I // 

\ I // 

. . \ I / 

Well I. D.# (various) \ 1 // 

'\\/ / \ I / 

-o- / " (/~~ <Qflo .. ;Q~; ~ Mobile Tank Truck 

~t-o~·ho" Ocv1\\j..~~ 

COUNTYB 

COUNTY A 

\OA\..s :· ( 

J1 S brine (1YP.) 

_ s:: Road Transport 

Landfill Or"' 

Tr-u....+~U\+ 'PlCAAt Note: 

Process producing waste: Gas well produced 

fluids (brines) are typically produced· in 

conjuction with natural gas. These fluids 

are brought to the surface utilizing either 

. mechanical or physical lift procedur_es. 

(.) 

~ UJ 

:I: 

~ z 

0 

~ 

~ 0 

0.. 

·W 

·~ 

1-

~~~~~~ l= 

~~ 

g~ I, - ~ § 

r lli 

~ I' 

I 

~a ! ~ l~ 

I i . 

~ 
~· ·· , _._ 

ENVIRONMENTAL SERVICE SAMPLE REQUEST & CHAIN OF CUSTODY LABORATORIES, INC. PAGE __ OF_ 

1--

.. HEADQUARTERS: SOUTHERN DIVISION: 

1803 Philadelphia Sl 

~ 1276 Bentleyville Road D 8 Indiana, PA 15701 Van Voorhis, PA 15366 REC'D NOV -4 2009 • .j 

(724) 463-TEST (724) 258-TEST 

(724) 465-4209 (724) 258-8376 

FOR INT'EIUIALlJJ.rORATOR'I'USE.cJR['y 

Sample Type 

Sample Identification ESL# Composite Grab Matrix # of Containers Container Type Analysis Requested 

Date on/off Time on/olf Date Time p,.•ervative 

1!14!1 ,~1/31 H0

l<:Jfll) ---- ----

/0 /_ -'· 

Plastic Liter pH, SC, Choride, Sulfate, / 

---- ---- ., Cjl' 1$ WN 1 

fOKLO none Alkalinity, Acidity, Bromide 

---- ----- It t>KJ:. ~ 1t WN 

Plastic Liter TSS, TDS, Dissolved Iron, 

---- ---- fCJ I~ 2 none Boron, BOD, MBAS Surfactants 

----- ----- lotSk 

Plastic Liter AI, As, Ba, Be, Cd, Cr, Co, Cu, Fe, Pb, Mg, 

---- ----- /0 ~ ' I.S WN 1 

HN03 Mn, Hg, Nl, Se, Ag, Sr, Zn, ll, Na, Ca, Mo, Hardne~s 

----- ---- ~~ ~ 'i t~ WN 

Plastic Liter 

---- ------ TO 1 Nitrate+Nilrite, TKN, Ammonia, COD 

H:zSO• 

----- ---- ~~~k (2) 1000 ml Plastic Liter Gross Alpha, Gross Beta 

~ ~ 101 

~ ' 15 WN (3) 500 ml Radium 226, Radium 228 

HN03 Thorium, Uranium 

---- ------ 15 WN Amber Glass L 

---- ~ TO oE cr 

1 011 &Grease 

HCI 

---- ------ b'gb WN 

Amber Glass L 

----- ~ /0 ' 1:1J 1 Total Phenolics 

H:zSO• 

----- ---

I he"- ~ WN 2 Amber VOA Vials 

---- ~ to I'S none Ethylene Glycol 

---- ---- ley tJ&/(f , 1~11' WN 2 Amber VOA Vials 

---- ~ HCI 

Benzene, Toluene 

TRIP BLANK t:J9 ---- ____...-- ~ ~ Water 2 : ~ber VOA Vials Benzene, Toluene 

'21~11 ---- ------ HCI 

THE UNDERSIGNED PURCH.\SER HEREBY AGREES TO PAY SERI/ICE CH.\RGES ON ACCOUNTS OVER 31 ~YS OLD. Project Notes: 

1. THESE SERVICE CH.\RGES WILL ACCRUE AT THE RATE OF 1 112% PER·MONTH (1~ PI!R ANNUM OR Tt1E MAXIMUM ALLOW1ED BY LAW.) 

2. THE UNDERSIGNED PURCH.\SER AOREES TO PAY, IN THE EVENT HIS ACCOUNT BECOMES DI!UNQUl!NT AN0 IS TURNED OVER TO A~ 

ATTORNEY FOR COLLECTION, REASONABLE ATTORNEY'S FEES PLUS ALL COURT AND ATTENDANT COLL.EcnQN COSTS. 

A'L .~/:d._ ton/~ 9 .. /$"..-"?b1 Company/Name: XTO ENERGY 

Sampl~ By: (Signature) ~ate/ Time 

~-~ IL(\~~ '1. ~ .d" /.- -:e::_ I r-;- ~-ocr I l{~ ~{ . r o- <?.-ocr Address: 395 AIRPORT ROAD 

Relinquish~: (Signatural, Date/ Time ~.BY:&V~ date/Time Ntt3 INDIANA, PA 15701 

~.--~ (o-g-cq ( Lft~S' Vl4 .. & / - ~, /f)-R'-tP9 

Relinquished By: (Signature) Dale/ Time ftecelved By: (Sigflel\ft) , Date/ Time 

Contact Person: MR. MIKE HAHN 

Relinquished By: (Signature) Date/ Time Received By: (Sign.ture) Date/ Time Phone: (724) 349-0600 

CHAIN OF CUSTODY SEAL BROKEN: Yes No Fax: (724) 34$9-8489 

- IJo./1 'j'{JJ J.l 
)

(

)

09 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/812009 9:15AM 

l 0/8/2009 2:42 PM 

10/30/2009 

Analyte 

Acidity to pH=8.3 

Alkalinity to pH=4.5 

Biological Oxygen Demand 05 

Chemical Oxygen Demand 

Ammonia as N I Distilled 

Bromide 

Chloride 

Kjeldahl Nitrogen as N 

pH(SM) 

Su1fateASTM 

Total Nitrate+ Nitrite as N 

Aluminum- ICP 

Arsenic-ICP 

Barium-ICP 

Beryllium - ICP 

Boron 

Cadmium - ICP 

Calcium - ICP 

Chromium - ICP 

Cobalt- ICP 

Copper-ICP 

Hardness 

Report of Analysis 

Analyst 

BF 

JS 

szc 

MAD 

MAD 

AJD 

BF 

MAD 

LL 

LMB 

AID 

GJT 

GJT 

GJT 

GJT 

MAD 

GJT 

GJT 

GJT 

GJT 

GJT 

GJT 

Sample ID#: 

Sample Type: 

Sample Source: 

09 29510 

Waste Water 

Grab 

Analysis 

Date 

10/1112009 

10/1212009 

10/1212009 

10/1512009 

10/1912009 

1012112009 

10/0912009 

10/1912009 

10/0812009 

10/1212009 

10/1912009 

1012112009 

10/2212009 

1012112009 

10/22/2009 

10/26/2009 

10/2212009 

10/22/2009 

10/21/2009 

10/2112009 

10/21/2009 

10/23/2009 

Sampler: 

Client Sample ID: 

NEW (Client) 

Hall843l H 

? :rue a\-

Sample Units Method 

Result 

NO mgll as CaC03 SM2310B 

175 mgll as CaC03 SM2320B 

68.7 mgll SM5210B 

1002.5 mgll SM5220D 

62.73 mgll :>M4500NH3B & [ 

554.00 mgll 01246-99 

51663.1 mg/l SM4500ClC 

33.1 mg/l SM4500Norg-C,D 

6.60 su SM4500H-B 

NO mg/l 0516-02 

NO mg/l SM4500N03E 

NO mg/l 200.7/6010 

NO mg/l 200.7/6010 

388.800 mg/l 200.7/6010 

NO mgll 200.7/6010 

15.00 mgll SM4500B-B 

NO mgll . 200.7/6010 

4248.800 mg/l 200.7/6010 

NO mgll 200.7/6010 

NO mgll 200.7/6010 

NO mg/l 200.7/6010 

12192 mgll SM2340B 

RPL 

2 

20 

2.0 

500.0 

1.00 

20.00 

1.0 

5.5 

O.ot 

5 

0.05 

1.000 

1.000 

0.500 

0.500 

12.50 

0.500 

50.000 

0.500 

0.500 

0.500 

1 

Comments: Radiologicals done by Benchmark Analytical 

IND=Not Detected 

Note: DEP Certification #Is 32-00382 

Data Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B = Analyte was detected in both sample and methods blank. x = user defined data qualifier. 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 9:15AM 

10/8/2009 2:42PM 

10/30/2009 

Analyte 

Iron- ICP 

Iron,Dissolved-ICP 

Lead-ICP 

Lithium - ICP 

Magnesiwn-ICP 

Manganese - ICP 

Mercury Molybedenwn - ICP 

Nickel-ICP 

Selenium-ICP 

Silver-ICP 

Sodium-ICP 

Strontium - ICP 

Zinc- ICP 

Detergents, MBAS 

Ethylene Glycol 

Oil and Grease - HEM 

Phenolics, as Phenol 

Specific Conductance 

Total Dissolved Solids (TDS) 

Total Suspended Solids 

Radiologicals 

Report of Analysis 

SamplelD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

GIT 1012112009 38.600 

GJT 10/21/2009 21.200 

GIT 1012112009 ND 

GIT 10/22/2009 72.500 

GIT 10123/2009 384.400 

GIT 10121/2009 4.000 

DMM 10/15/2009 ND 

GIT 10/21/2009 NO 

GIT 10/21/2009 NO 

GIT 10121/2009 NO 

GIT 10122/2009 NO 

GIT 10122/2009 26743.000 

GIT 10123/2009 720.700 

GIT 10/2112009 NO 

TL 10/09/2009 0.614 

IMetPw 10120/2009 <25.000 

CLM •1 012012009 ND 

MAD 10/13/2009 ND 

LL 10/08/2009 112400 

CLM 10/14/2009 104800 

ALD 10/13/2009 472 

enchmat 10/30/2009 * 

Comments: Radiologicals done by Benchmark Analytical 

Note: DEP Certification #s 32-00382 

09 29510 

WasteWater 

Grab 

NEW (Client) 

Hall8431 H 

Units 

mgfl 

mgfl 

mgfl 

mgfl 

mg/1-

mgfl 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mg/1 

mglkg 

·mg/1 

mg/1 

uS/em 

mg/1 

mg/1 

mg/1 

Data Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

Method RPL 

200.7/6010 1.000 

200.7/6010 1.000 

200.7/6010 0.500 

200.7/6010 50.000 

200.7/6010 50.000 

200.7/6010 0.500 

245.1 0.0002 

200.7/6010 0.500 

200.7/6010 0.500 

200.7/6010 1.000 

200.7/6010 0.500 

200.7/6010 500.000 

200.7/6010 1.000 

200.7/6010 0.500 

SM5540C 0.200 

300.0M 25.000 

1664A 5.0 

420.1 0.500 

SM2510B 1 

SM2540C 25 

SM2540D 5 

RAD-CTDHS 0.000 

\ND=Not Detected 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B = Analyte was detected in both sample and methods blank. x = User defined data qualifier. 
, 

ADDRESS: 1803 Philadelphia St 

PHONE: 

FAA: 

Indiana, PA 15701 

(724) 463-8378 

(724) 465-4209 

09 29350 & 09 29510 

RECEIVED FOR LAB BY: DMB 

TEST REPORT 

DATE: 10/121200910:00 

PAGE: 2of2 

PO#: DAS10092009 

PWSIO# 

Page2 Clf2 

SAMPLE: 09 29510 Lab 10: 091016fi6.002E Grab SAMPLED BY: David A. Stl1e Sample T.me 10/0812009 9:15 

Bm!l 

~ 

~ Y!l!!! 

Thorium < 0.0131 :t 0.00 0 mgiL 

Method 

EPA200.8 

W, 61la!Ys's Start Analysis End Analyst • 

10113/09 8:30 10/16109 GSR-CV 

·--- SAMPLE: 09 29510 Lab 10: 091016S6-002A Grab 

SAMPLED BY: David A. Stile Sample Time 1010812009 8:15 

Result 

~ Y2A Units 

~ 

EPA900.0 

EPA900.0 

1971 :t 221.3 746.9 pCIIl 

2285 t 140.7 682.4 pClll --·-- ----

SAMPLE: 09 29510 

SAMPLED BY: David A. stile 

:nm Bm!J1 

Radlum-226 464.9 

---··----

SAMPLE: 09 29510 

SAMPLED BY: DavieS A. Stile 

LabiO: 09101~ 

Sample nne 1010812009 9:15 

ll!g[t MQA Units Mdm 

:1: 1 5.84 59.4 pC~ EPA 903.0 

Lab 10: 09101656-002C 

Sample Tme 1010812009 9:15 

3m 

Redium-228 

~~MQ6~ 

148.7 :t 11.10 14.16 pCiiL EPA904.0 

MQb Al!atnis Slatt Analysis End ~ 

10/13109 8:50 10116109 BPS..CV 

10113m 8:50 10116109 BPS.CV 

--------· 

Grab 

fl4g. Analysis Start M!!tysl$ End ~ 

1011610911:15 10129109 BH-cv 

Glib 

G Analy!;is Start A!!atniS End ~n! 

10121109 8:05 10/27109 NLB-CV 

·-------· ------ SAMPLE: 09 29510 

SAMPLED BY: David A. Stile 

Lab ID:· 0910165~ 

Sample Tine 1010812009 9:15 

Grab 

!tit Result 

~ 

MDA 

~ 

~ 

MCL Anatvsls Start Anatnis End 6nilYi1.! 

Uranium < 13.13 f; 0.00 0 l!QIL MS EPA200.8 30 10119109 10:00 

Ur.~nlum <8.93 :1: 0.00 0 pCill. EPA200.S 10/19109 10:00 

· ·--··-· .. ·--··"··-

REMARKS: 

The above test procedures meet all the requirements of NELAC and relate only to these samples . 

.. CV =Benchmark An<!lytiCS, Inc. Center Valley, PA; SA= Benchmark An<~lytics, Inc. Sayre, PA MS Umit of detection increased duo to matrix interference and spike recovery csata 

MANAGER 

··--Wf!Jd -

. 

·-

DATE: 

10123109 GSR..CV 

10123109 GSR-CV 

·· ·---

1013012009 
(

)

ST FAX (724)

465

4209 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

1) Benzene 

47) Toluene 

XTOEnergy 

395 Airport Road 

Indiana, PA 15701 

10/8/2009 9:15AM 

10/8/2009 2:42PM 

10/3012009 

Analyte 

Report of Analysis 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

RO 10/09/2009 26.40 

RO 10/0912009 ND 

Comments: Radiologicals done by Benchmark Analytical 

. Note: DEP Certification #s 32-00382 

09 29510 

Waste Water 

Grab 

NEW (Client) 

Hall8431 H 

Units 

ug!L 

ugfL 

Data Qualifiers: D :::: The reported value is from dilution. E = Estimated value. S = Surro_gate out of control limits. 

Method RPL 

624/8260B 20.00 

624/8260B 20.00 

\ND=Not Detected 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. B = Analyte was detected in both sample ~nd methods blank. x = User defined data qualifier. 
i724)

463

TEST FAX (724)-465-4209 

Name: XTOEnergy 

Sample Start Date: 

395 Airport Road 

Indiana, PA 15701 

10/812009 

10/8/2009 2:42PM 

10/1212009 

Receipt Date: 

Report Date: 

Analyte 

1) Benzene 

47) Toluene 

Comments: 

DEP Certification #s 32-00382 

Report of Analysis 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

Analyst Analysis Sample 

Date Result 

RO 10/09/2009 ND 

RO 10/09/2009 ND 

09 29511 

Waste Water 

Grab 

NEW (Client) 

Trip Blank 

Units 

ug!L 

ug/L 

Method MDL 

624/8260B 1.00 

624/8260B 1.00 

fD=Not Detected 
each attached sheet as Fonn 26R, reference the Item number and Identify the date 

prepared. The date on attached sheets needs to match the date noted below. 

·General Reference 287.54 

Date Prepared/Revised 219/11 

c. Appearance 

County 

Indiana 

Number of Solid or Uquid Phases of Separation 

Une2 

10# 

Describe each phase of separation . .::!I.:~---------------; 

- 1 -
c. 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

Title 

Phone 

Name 

d. vn• .. •rr• .. of waste shipped to processing or 

b. Facility Name 

Address Une 1 

Address Une 1 Address City State ZIP 

Municipality 

c. Name 

Title 

Phone 

b. 

0 cu yd 181 gal 

to processing or disposal facility 0 cuyd 0 gal 0 lb 

0 gal 

-2-

County Indiana 

(check one) 

0 ton (check one) 
Fonn Submitted: 0 Form26R 

0 Other (specify) 

Date Submitted: 

0 I certify the information required In Section B-2, Chemical Analysis was supplied to the Department for the year 

_and has not changed. 

Form Submitted: 0 Form 26R 

0 Other {specify) 

Date Submitted: 

O I certify the Information required In Section ~. Process Description and Schematic, was supplied to the Department 

for the year __ and has not changed. 

Form Submitted: 0 Form 26R 

Date Submitted: 

Name of Responsible Official 

Bernhardt Kissel 

Signature 

0 Other (specify) 

Title EH & S ~ 2-28-11 

-3-
Brine fluids are composited within the storage production tank or tank battery at each 

well site where gas production is occurring. Each automatic or manual ejection of 

formation fluids is deposited into the tank(s) and added to the previously ejected and 

stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP 

permitted waste disposal facilities on different schedules determined by individual well 

characteristics. Grab samples of the composited fluids were obtained at the 

represented well pads directly from the storage tank drain ports. All drain ports had 

small "built in" containment and storage "buckets" capable of retaining small amounts of 

lost fluids. 

Samples were obtained with bottle sets prepared at the laboratory which contained 

appropriate preservatives, as necessary, depending on the specific test run requested. 

All chain of custody and handling/holding time requirements were met. In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot 

portions at the laboratory. 

Flowback samples were composited to the extent possible during the flowback process 

primarily during times where safety issues did not override sample collection 

requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers 

and smaller aliquot portions at the laboratory or on the well location upon completion of 

the composite sampling process. Samples were distributed into bottle sets prepared at 

the laboratory which contained appropriate preservatives, as necessary, depending on 

the specific test run requested. All chain of custody and handling/holding time 

requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and 

combined into a composite sample for analyses at the laboratory. On several wells, 

cuttings from the vertical portion of the well bore were segregated from cuttings from 

the target Marcellus Formation and separate testing was completed on both sample 

composites. In some earlier cases during the utilization of open pits, composite 

samples were obtained from inactive drill pits. Safety concerns usually limited the 

randomness of the composite sample and composite grid sample positions were varied 

to the extent possible. 

Pit water (drill fluid) is currently discharged to closed containment and is re-conditioned 

and reused from well to well. 
Form 26R: Section B3a 

WASTE GENERATION PROCESS 

Pit Water "Drill Fluids• 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and formation fluids. These fluids are brought to 

the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are 

mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

Flowback: "Fracing Fluid" 

Flowback is produced from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the 

formation fractures. 

Production Fluid "Brine" 

During the production of natural gas, formation pressures bring remnant frac fluids, 

during the initial production phase, and formation fluids to the surface along with 

produced gas. 
Well I. D.# (various) Well I.·D.#.(various) 

\\/ )J( ~0~ ~~~ 

COUNTY A 

I \ I 

\ / Well I. D.# (various) 

\ I ~()/ \ I /II' 

\ I / \ I // 

\ I // 

. \ I / 

Well I. D.# (various) \ 1 // 

\\/ / \ I / 

-a- ,_ " ,.....---

COUNTYB 

(/"I / ~o~-- FI.,..,L....\<. ~7 ( 

eot?o'to~ ~ Mobile Tank Truck 

'fr-ocSlvc.:\-toJ\ Ocu1\\~~~ \OAI-S : • ( 

]{ S brine (1YP.) 

ote: 

Process producing waste: Gas well produced 

fluids (brines) are typically produced· in 

conjuction with natural gas. These fluids 

are brought to the surface utilizing either 

mechanical or physical lift procedures. 

_ s Road Transport 

----Landfill or' 

Tre.u. + t..\ <.~·J '? l(AA t 

(.') 

~ ~ w 

:c 

() 

(/) 

z 

0 

~ 

~ 0 

0.. 

(/) 

·~ 

1-

~~ 

8~ ~ ..... - ~ ~ ~ 

~~ ~~ 

~ ~~ 

rn ~ 1 ~ :i~ .. ffi i 

~ I i 

s~ 
RICK BONAZZA 

RESOURCE MANAGEMENT SERVICES 

65 FENTON ROAD 

INDIANA, PA 15701 

RE: 26R Analysis 

Dear RICK BONAZZA: OrderNo.: G1012347 

Geochemical Testing received 1 sample(s) on 12/10/2010 for the analyses presented in the 

following report. 

There were no problems with the analyses and all QC data met NELAC, EPA, and laboratory 

specifications except where noted in the Case Narrative or Laboratory Results. 

If you have any questions regarding these tests results, please feel free to call. 

Sincerely, 

Timothy W. Bergstresser 

Director of Technical Services 

Page 1 of 6 

< 

& 

~ ~ X 

I 0. 56·00306 PA DEP 
REVISED REPORT (2/4/11): Sample description changed. 

The ethylene glycol analysis was subcontracted to Free Col. A copy of the subcontractor's laboratory 

report is enclosed with this Analytical Report. 

The radiological analysis was subcontracted to Pace Analytical. A copy of the subcontractor's 

laboratory report is enclosed with this Analytical Report. 

Legend: ND- Not Detected at the Quantitation Limit 

J - Indicates an estimated value. 

U - The analyte was not detected at or above the listed 

concentration, which is below the laboratory quantitation limit. 

B - Analyte detected in the associated Method Blank 

Q- Qualifier QL -Quantitation Limit OF- Dilution Factor 

S - Spike Recovery outside accepted recovery limits 

R - RPD outside accepted recovery limits 

E- Value above quantitation range 

** -Value exceeds Action Limit 

H - Method Hold Time Exceeded 

MCL- Contaminant Limit J.D. 56-00306 PA DEP 

Page 2 of 6 
Matrix: AQUEOUS 

Analyses Result 

INORGANIC NON-METALS 

Acidity to pH 8.2 240 

INORGANIC NON-METALS 

Alkalinity to pH 4.5 85 

PHYSICAL TESTS 

Specific Conductance 156000 

PH BY SM 4500 H+B 

Lab pH 5.90 

INORGANIC NON-METALS 

Total dissolved solids 150000 

PHYSICAL TESTS 

Total suspended solids 128 

INDICATOR ORGANIC PARAMETERS 

BOD 5-<lay 

Finish DatefTime 

REACTIVE CYANIDE 

Reactive cyanide 

350 

12/15/201012:55 

< 0.25 

INDICATOR ORGANIC PARAMETERS 

Chemical Oxygen Demand 5900 

INORGANIC NON-METALS 

Bromide 734 

Chloride 84300 

Sulfate < 100 

INORGANIC NON-METALS 

MBAS 0.057 

NOTES: 

Received Date: 12/10/2010 7:56:45 AM 

QL Q Units 

SM 2310B(4A) 

0 mg/L CaC03 

SM 18 23208 

5 mg/L CaC03 

EPA 120.1 

IJmhos/cm 

SM4500-H+B 

0 su 

SM 2540 C 

20 mg/L 

SM 2540D 

5 mg/L 

SM 5210 B 

60 mg/L 

0 mg/L 

SW846CH.7 

0.25 mg/Kg 

HACH 8000 

100 mg/L 

EPA300.0 

40.0 mg/L 

200 mg/L 

100 mg/L 

SM 5540C 

0.050 s mg/L as LAS 

DF 

60 

60 

Date Analyzed 

Analyst: LNW 

12116/2010 8:27:00 AM 

Analyst: LNW 

12/15120101 :43:00 PM 

Analyst: LNW 

12/15/2010 1 :43:00 PM 

Analyst: LNW 

12115/20101 :43:00 PM 

Analyst: KLS 

12/10/2010 10:02:00 AM 

Analyst: KLS 

1211012010 6:57:38 AM 

Analyst: MMR 

12110/2010 1:00:00 PM 

12110/20101 :00:00 PM 

Analyst: SAG 

12/15/2010 7:13:00 PM 

Analyst: MGV 

10 12115/2010 

Analyst: CAS 

200 12117/20106:54:00 PM 

200 12117/2010 6:54:00 PM 

50 12/16/2010 10:07:00 PM 

Analyst: MMR 

12/10/2010 10:05:00 AM 

S - Spike recovery indicates a possible matrix effect. The method is in control as indicated by the LCS. 

INORGANIC NON-METALS 

Ammonia Nitrogen - Distilled 98.2 

INORGANIC NON-METALS 

Nitrate - Nitrite 0.73 

INDICATOR ORGANIC PARAMETERS 

Phenolics < 100 

REACTIVE SULFIDE 

EPA 350.1 

5.00 

EPA 353.2 

0.05 

EPA420.1 

100 

SW846 CH.7 

Paae 3 of6 

mg/L as N 

mg/L as N 

IJg/L 

Analyst: SLY 

50 12/22/2010 11 :01 :48 AM 

Analyst: SLY 

12/16/2010 9:04:00 AM 

Analyst: SAG 

5 12/17/20101:11:00 PM 

Analyst: MMR 

1.0. 56-00306 PA DEP 
Matrix: AQUEOUS 

Analyses 

REACTIVE SULFIDE 

Reactive sulfide 

INORGANIC NON-METALS 

Total Kjeldahl Nitrogen 

INORGANIC METALS 

Iron, dissolved 

INORGANIC METALS 

Mercury 

INORGANIC METALS 

Aluminum Arsenic 

Barium Beryllium Boron 

Cadmium , 

Calcium 

Chromium 

Cobalt Copper 

Iron 

Lead Lithium 

Magnesium Manganese 

Molybdenum Nickel 

Selenium Silver Sodium Strontium 

Zinc 

Hardness (SM 2340B) 

INORGANIC METALS 

Thorium 

Uranium 

HERBICIDE ANALYSIS 

2,4,5-T 2,4-D 

Result 

0.90 

126 

108 

<0.20 

< 0.2 

< 0.02 

6960 

< 0.001 

16.1 

0.018 

14400 

0.04 

< 0.005 

< 0.01 

135 

< 0.04 

122 

1520 

5.94 

< 0.02 < 0.01 

< 0.02 

< 0.005 

37400 

3840 

0.11 

42100 

< 50.0 

< 50.0 

< 5.0 

< 20 

Received Date: 12/ 10/2010 7:56:45 AM 

QL Q Units 

SW846 CH.7 

0.25 mg/Kg 

EPA 351.2 

10.0 mg/L as N 

EPA 200.7 

0.05 mg/L 

SM 31128 

0.20 IJg/L 

EPA200.7 

0.2 

0.02 

10.0 

0.001 

1.00 

0.002 

10.0 

0.01 

0.005 

0.01 

0.05 

0.04 

10.0 10.0 

0.01 0.02 0.01 0.02 

0.005 

20.0 

5.00 

0.01 

100 

EPA 200.8 

50.0 50.0 

EPA 8151 

5.0 

20 

mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L 

mg/L mg/L mg/L mg/L 

mg/L 

mg/L mg/L mg/L mg/L mg/L 

mg/L mg/L mg/L mg/L mg/L CaC03 

IJg/L IJg/L IJg/L 

IJQIL 

DF 

10 

2 

1 

1000 

1 

20 

1 

100 

1 

2 

500 

100 

100 

500 

100 

50 50 

100 

100 

Date Analyzed 

Analyst: MMR 

12/13/20101:45:00 PM 

Analyst: SLY 

12/21/2010 2:36:03 PM 

Analyst: MS 

12/20/2010 1:43:00 PM 

Analyst: MS 

12114/2010 12:59:10 PM 

Analyst: MS 

12/21/2010 11 :26:00 PM 

12/16/2010 2:05:00 PM 

12/20/2010 1 :43:00 PM 

12/16/2010 2:05:00 PM 

12/17/2010 4:47:00 PM 

12/16/2010 2:05:00 PM 12/17/2010 4:42:00 PM 12/16/2010 2:05:00 PM 12/16/2010 2:05:00 PM 12/16/2010 2:05:00 PM 12/16/2010 2:05:00 PM 

12/21/201011:26:00 PM 12/17/2010 4:38:00 PM 

12117/2010 4:42:00 PM 12/16/2010 2:05:00 PM 

12/16/2010 2:05:00 PM 

12/16/2010 2:05:00 PM 

12/16/2010 2:05:00 PM 12/16/2010 2:05:00 PM 

12/17/2010 4:42:00 PM 

12/17/20104:38:00 PM 

12/16/2010 2:05:00 PM 

12/17/2010 4:42:00 PM 

Analyst: JEK 

12/20/2010 10:28:00 AM 

12/16/20101:09:00 PM 

Analyst: TEW 

12/17/2010 6:53:00 PM 12/17/2010 6:53:00 PM 

--·------------------·--------- ------------------------------·-·---- ---------------------------·-

-·-

I. D. 56-00306 PA DEP 

Paqe 4 of 6 
Q

Analyses 

HERBICIDE ANALYSIS 

Silvex 

Surr: 2,4-Dichlorophenyl acetic acid 

PESTICIDE ANALYSIS 

Chlordane 

Dieldrin 

Gamma BHC (lindane) 

Heptachlor epoxide 

Methoxychlor 

Toxaphene 

Surr: Decachlorobiphenyl 

Surr: Tetrachloro-m-xylene 

SEMI-VOLATILE COMPOUNDS 

2,4,5-Trichlorophenol 

2,4,6-Trichlorophenol 

2,4-Dinitrotoluene 

2-Methylphenol 

Hexachlorobenzene 

Hexachlorobutadiene 

Hexachloroethane 

Nitrobenzene 

Pentachlorophenol 

Pyridine 

3,4-Methylphenol 

Surr: 2,4,6-Tribromophenol 

Surr: 2-Fiuorobiphenyl 

Surr: 2-Fluorophenol 

Surr: Nitrobenzene-d5 

Surr: Phenol-d6 

Surr: p-Terphenyl-d14 

VOLATILE ORGANIC COMPOUNDS 

1 , 1-Dichloroethene 

1 ,2-Dichloroethane 

1 A-Dichlorobenzene 

Benzene 

Carbon Tetrachloride 

Chlorobenzene 

Methyl Ethyl Ketone 

Tetrachloroethane 

Toluene 

6:

5 AM 

Result 

< 5.0 

65.5 

< 5.0 

< 0.25 

< 0.25 

<0.25 

< 0.25 

< 10 

85.3 

71.5 

< 93 

< 93 

< 93 

< 93 

< 93 

< 93 

< 93 

< 93 

< 470 

< 470 

< 93 

74.8 

45.6 

61.5 

3.70 

63.7 

33.2 

QL Q Units 

EPA 8151 

5.0 

~ll 

28.5-130 %REC 

EPA8081 

5.0 

~g/l 

0.25 

~g/l 

0.25 

~g/l 

0.25 

~g/L 

0.25 

~g/l 

10 

~g/l 

5-156 %REC 

15.9-102 %REC 

EPA8270 

93 

~g/l 

93 

~g/l 

93 

~g/L 

93 

~g/l 

93 

~g/L 

93 

~g/L 

93 

~g/l 

93 

~g/l 

470 

~g/L 

470 

~g/l 

93 

~g/L 

5-137 %REC 

27.7-95.1 %REC 

5-104 %REC 

16-101 S %REC 

5-106 %REC 

25.4-133 %REC 

EPA8260 

< 1.0 1.0 

~g/l 

< 1.0 1.0 

~g/l 

< 1.0 1.0 

~g/l 

< 1.0 1.0 

~giL 

< 1.0 1.0 

~g/l 

< 1.0 1.0 

~g/L 

< 5.0 5.0 

~g/l 

<1 .0 1.0 

~g/l 

< 1.0 1.0 

~g/l 

Page 5 of6 

DF 

100 

100 

5 

5 

5 

5 

5 

5 

5 

5 

9.35 

9.35 

9.35 

9.35 

9.35 

9.35 

9.35 

9.35 

9.35 

9.35 

9.35 

9.35 

9.35 

9.35 

9.35 

9.35 

9.35 

Date Analyzed 

Analyst: TEW 

12/17/2010 6:53:00 PM 

12/17/2010 6:53:00 PM 

Analyst: TEW 

12/16/2010 10:08:00 PM 

12/16/2010 10:08:00 PM 

12/16/2010 10:08:00 PM 

12/16/2010 10:08:00 PM 

12/16/2010 10:08:00 PM 

12/16/2010 10:08:00 PM 

12/16/2010 10:08:00 PM 

12/16/2010 10:08:00 PM 

Analyst: JB 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

12/19/2010 5:39:00 PM 

Analyst: JAW 

12/14/2010 8:19:00 AM 

12/14/2010 8:19:00 AM 

12/14/2010 8:19:00 AM 

12/14/2010 8:19:00 AM 

12/14/2010 8:19:00 AM 

12/14/2010 8:19:00 AM 

12/14/2010 8:19:00 AM 

12/14/2010 8:19:00 AM 

12/14/2010 8:19:00AM 

I. D. 56-00306 PA DEP 
Analyses 

VOLATILE ORGANIC COMPOUNDS 

Trichloroethane 

Trichloromethane 

Vinyl Chloride 

Surr: 1 ,2-Dichloroethane-d4 

Surr: 4-Bromofluorobenzene 

Surr: Dibromofluoromethane 

Surr: Toluene-dB 

INDICATOR ORGANIC PARAMETERS 

Oil & Grease 

NOTES: 

Result 

< 1.0 

< 1.0 

< 1.0 

111 

101 

104 

105 

101 

QL Q 

EPA8260 

1.0 

1.0 

1.0 

70-130 

7Q-130 

70-130 

70-130 

EPA 1664 

5 J 

Units 

).19/l 

IJQ/L 

).19/L 

%REC 

%REC 

%REC 

%REC 

mgll 

DF 

1.02 

Date Analyzed 

Analyst: JAW 

12/14/2010 8:19:00 AM 

12114/2010 8:19:00 AM 

12114/2010 8:19:00 AM 

12/14/2010 8:19:00 AM 

12/14/2010 8:19:00 AM 

12/14/2010 8:19:00 AM 

12/14/2010 8:19:00 AM 

Analyst: JDH 

12/14/2010 8:42:00 AM 

J - Unable to obtain a stable weight within specified limits due to sample matrix. Value is estimated. 

VOLA TILE ORGANIC COMPOUNDS EPA 8015 Analyst: SUB 

Ethylene Glycol < 11 11 mgll 12/22/2010 

RADIOLOGICAL TESTING EPA900.0 Analyst: SUB 

· Gross Alpha 10200 +- 2251 3.00 pCill 12/18/2010 

Gross Beta 812 +- 782 4.00 pCi/L 12/18/2010 

RADIOLOGICAL PARAMETERS EPA 903.1 Analyst: SUB 

Radium 226 3854 +-717 1.00 pCi/L 12/28/2010 

RADIOLOGICAL PARAMETERS EPA904.0 Analyst: SUB 

Radium 228 784 +- 181 1.00 pCi/L 117/2011 

INORGANICS NON-METALS EPA9040 Analyst: GAK 

Corrosivity Characteristic 5.63 1.00 su 12/13/2010 

FLASH POINT EPA 1010 Analyst: RLL 

Flashpoint >200 10.0 OF 12/13/2010 

1.0. 56-00306 PA DEP 

Page 6 of 6 
prepared. The date on attached sheets needs to match the date noted below. 

General Reference 287.54 

Date Prepared/Revised 219111 

EPA Generator 

Ext 

c. Appearance 

- 1 -
a. 

b. 

c. 

d. 

a. 

b. 

c. 

d. 

a. 

Name 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

Phone 

Address Une 1 

Address Une 1 

Address City State ZIP 

Municipality 

Title 

Phone 

to processing or 0 cu yd 181 gal 

.. u •• u ..... of waste shipped to processing or 0 cuyd 0 gal 

Indiana 

Email Address steve@pabrine.com 

year. 0 lb 0 ton (check one) 

being utilized. 

Email Address 

previous year. 0 lb 0 ton (check one) 

0 ton (check one) 

-2-
Fonn Submitted: 0 Fonn 26R 

0 Other (specify) 

Date Submitted: 

0 I certify the infonnation required In Section B-2, Chemical Analysis was supplied to the Deparbnent for the year 

_and has not changed. 

Fonn Submitted: 0 Fonn 26R 

0 Other (specify) 

Date Submitted: 

0 I certify the lnfonnation required In Section B~. Process Description and Schematic, was supplied to the Deparbnent 

for the year_ and has not changed. 

Fonn Submitted: 0 Fonn 26R 

0 Other {specify) 

Date Submitted: 

Name of Responsible Official 

Bernhardt Kissel 

Signature Date 1 

-3-
Brine fluids are composited within the storage production tank or tank battery at each 

well site where gas production is occurring. Each automatic or manual ejection of 

formation fluids is deposited into the tank(s} and added to the previously ejected and 

stored quantity. Tanks are emptied into tank trucks for disposal at various PaDEP 

permitted waste disposal facilities on different schedules detennined by individual well 

characteristics. Grab samples of the composited fluids were obtained at the 

represented well pads directly from the storage tank drain ports. All drain ports had 

small "built in" containment and storage "buckets" capable of retaining small amounts of 

lost fluids. 

Samples were obtained with bottle sets prepared at the laboratory which contained 

appropriate preservatives, as necessary, depending on the specific test run requested. 

All chain of custody and handling/holding time requirements were met. In some cases, 

a larger sample was broken into appropriate sampling containers and smaller aliquot 

portions at the laboratory. 

Flowback samples were composited to the extent possible during the flowback process 

primarily during times where safety issues did not override sample collection 

requirements. 

Generally, a larger composite sample was broken into appropriate sampling containers 

and smaller aliquot portions at the laboratory or on the well location upon completion of 

the composite sampling process. Samples were distributed into bottle sets prepared at 

the laboratory which contained appropriate preservatives, as necessary, depending on 

the specific test run requested. All chain of custody and handling/holding time 

requirements were met. 

Drill cuttings were composite sampled during the drilling process at various times and 

combined into a composite sample for analyses at the laboratory. On several wells, 

cuttings from the vertical portion of the well bore were segregated from cuttings from 

the target Marcellus Fonnation and separate testing was completed on both sample 

composites. In some earlier cases during the utilization of open pits, composite 

samples were obtained from inactive drill pits. Safety concerns usually limited the 

randomness of the composite sample and composite grid sample positions were varied 

to the extent possible. 

Pit water (drill fluid} is currently discharged to closed containment and is re-conditioned 

and reused from well to well. 
Form 26R: Section B3a 

WASTE GENERATION PROCESS 

Pit Water "Drill Fluids" 

Remnant drill fluids are generated in the well bore during the penetration of the drill 

stem as it intercepts both ground water and formation fluids. These fluids are brought to 

the surface along with the drill cuttings, pieces of the intercepted rock strata, by the 

return flow system of the drilling process. 

Drill cuttings and drill fluids are isolated into separate waste streams. Cuttings are 

mixed with sawdust to absorb remnant fluid and loaded out for disposal at a landfill. 

Fluids are currently stored in closed containers to be processed for reuse. 

Flowback: "Fracing Fluid" 

Flowback is produced from all fluids that flow back to surface during the "hydrofracing" 

process which occurs under pressure and results in the setting of a propant within the 

formation fractures. 

Production Fluid "Brine" 

During the production of natural gas, formation pressures bring remnant frac fluids, 

during the initial production phase, and formation fluids to the surface along with 

produced gas. 
Well I. D.# (various) Well I.D.#.(various) 

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are brought to the surface utilizing either 

mechanical or physical lift procedur.es. 

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RICK BONAZZA 

RESOURCE MANAGEMENT SERVICES 

65 FENTON ROAD 

INDIANA, PA 15701 

RE: 26R Analysis 

Dear RICK BONAZZA: 

OrderNo.: G1012348 

Geochemical Testing received I sample(s) on 12/10/2010 for the analyses presented in the 

following report. 

There were no problems with the analyses and all QC data met NELAC, EPA, and laboratory 

specifications except where noted in the Case Narrative or Laboratory Results. 

If you have any questions regarding these tests results, please feel free to call. 

Sincerely, 

Timothy W. Bergstresser 

Director of Technical Services 
p

u

te

ed during analysis of this workorder, except if noted in this report. 

REVISED REPORT (2/4/11): Sample description changed. 

The ethylene glycol analysis was subcontracted to Free Col. A copy of the subcontractor's laboratory 

report is enclosed with this Analytical Report. 

The radiological analysis was subcontracted to Pace Analytical. A copy of the subcontractor's 

laboratory report is enclosed with this Analytical Report. 

Legend: ND -Not Detected at the Quantitation Limit 

J - Indicates an estimated value. 

U - The analyte was not detected at or above the listed 

concentration, which is below the laboratory quantitation limit. 

B - Analyte detected in the associated Method Blank 

Q- Qualifier QL -Quantitation Limit DF- Dilution Factor 

S- Spike Recovery outside accepted recovery limits 

R- RPD outside accepted recovery limits 

E - Value above quantitation range 

**-Value exceeds Action Limit 

H - Method Hold Time Exceeded 

MCL- Contaminant Limit 

J.D. 56-00306 PA DEP 
Matrix: AQUEOUS Received Date: 12/10/2010 8:26:06 AM 

------------------------------·-· - --· . -··· ····· -----

Ana!yses Result 

INORGANIC NON-METALS 

Acidity to pH 8.2 320 

INORGANIC NON-METALS 

Alkalinity to pH 4.5 <5 

PHYSICAL TESTS 

Specific Conductance 180000 

PH BY SM 4500 H+B 

Lab pH 4.26 

INORGANIC NON-METALS 

Total dissolved solids 189000 

PHYSICAL TESTS 

Total suspended solids 66 

INDICATOR ORGANIC PARAMETERS 

BOD 5-day 7 

Finish Date/Time 12/15/2010 12:55 

INDICATOR ORGANIC PARAMETERS 

Chemical Oxygen Demand 11000 

INORGANIC NON-METALS · 

Bromide 894 

Chloride 107000 

Sulfate < 100 

INORGANIC NON-METALS 

MBAS 0.23 

INORGANIC NON-METALS 

Ammonia Nitrogen - Distilled 122 

INORGANIC NON-METALS 

Nitrate • Nitrite 0.52 

INDICATOR ORGANIC PARAMETERS 

Phenolics < 100 

INORGANIC NON-METALS 

Total Kjeldahl Nitrogen 115 

INORGANIC METALS 

Iron, dissolved 87.3 

INORGANIC METALS 

QL Q Units 

SM 23108(4A) 

0 mg/L CaC03 

SM 18 23208 

5 mg/LCaC03 

EPA 120.1 

tJmhos/cm 

SM4500-H+B 

0 su 

SM 2540 C 

100 mg/L 

SM 2540D 

5 mg/L 

SM 5210 B 

3 mg/L 

0 mg/L 

HACH 8000 

100 mg/L 

EPA 300.0 

40.0 mg/L 

200 mg/L 

100 mg/L 

SM 5540C 

0.050 mg/L as LAS 

EPA 350.1 

5.00 mg/Las N 

EPA 353.2 

0.05 mg/L as N 

EPA420.1 

100 IJQ/L 

EPA 351 .2 

10.0 mg/L as N 

EPA 200.7 

0.05 mg/L 

SM 31128 

D F Date Analyzed 

Analyst: LNW 

12/16/2010 8:44:00 AM 

Analyst: LNW 

12/15/2010 4:49:00 PM 

Analyst: LNW 

12/15/2010 4:49:00 PM 

Analyst: LNW 

12/15/2010 4:49:00 PM 

Analyst: KLS 

5 12/10/2010 10:02:00 AM 

Analyst: KLS 

12/10/2010 6:57:40 AM 

Analyst: MMR 

3 12/10/2010 1:00:00 PM 

3 12/10/2010 1:00:00 PM 

Analyst: MGV 

10 12/15/2010 

Analyst: CAS 

200 12/17/2010 7:12:00 PM 

200 12/17/2010 7:12:00 PM 

50 12/16/2010 10:24:00 PM 

Analyst: MMR 

12/10/2010 10:05:00 AM 

Analyst: SLY 

50 12/22/2010 11 :02:56 AM 

Analyst: SLY 

12/16/2010 9:05:07 AM 

Analyst: SAG 

5 12/17/20101 :31 :00 PM 

Analyst: SLY 

10 12/21/20102:38:20PM 

Analyst: MS 

12/20/20101 :47:00 PM 

Analyst: MS 

----------------------------------------------------------

I.D. 56-00306 PA DEP 

n--- " _.r r 
Matrix: AQUEOUS Received Date: 12/10/2010 8:26:06 AM 

Analyses Result QL Q Units DF Date Analyzed 

INORGANIC METALS SM 31128 Analyst: MS 

Mercury <0.20 0.20 IJQ/L 12/14/20101:01:23 PM 

INORGANIC METALS EPA 200.7 Analyst: MS 

Aluminum 0.2 0.1 mg/L 12116/2010 8:17:00 PM 

Arsenic < 0.02 0.02 mg/L 12116/2010 8:17:00 PM 

Barium 9320 10.0 mg/L 1000 12129/2010 5:14:00 PM 

Beryllium < 0.001 0.001 mg/L 1 12/1612010 8:17:00 PM Boron 16.2 0.50 mg/L 10 12/2212010 1 :08:00 AM 

Cadmium O.o16 0.002 mg/L 12/16/2010 8:17:00 PM Calcium 20500 10.0 mg/L 100 1212212010 12:51:00 AM Chromium < 0.01 0.01 mg/L 12116/2010 8:17:00 PM Cobalt 0.747 0.005 mg/L 12/16/2010 8:17:00 PM Copper 0.02 0.01 mg/L 12116/2010 8:17:00 PM 

Iron 112 0.05 mg/L 12116/2010 8:17:00 PM 

Lead <0.02 0.02 mg/L 12/16/2010.8:17:00 PM Lithium 117 4.00 mg/L 200 12/29/2010 6:04:00 AM 

Magnesium 2220 10.0 mg/L 100 12/2212010 12:51:00 AM Manganese 6.70 0.01 mg/L 12116/2010 8:17:00 PM Molybdenum < 0.02 0.02 mg/L 12116/2010 8:17:00 PM 

Nickel < 0.01 0.01 mg/L 1211612010 8:17:00 PM 

Selenium < 0.02 0.02 mg/L 12116/2010 8:17:00 PM Silver < 0.005 0.005 mg/L 12116/2010 8:17:00 PM Sodium 57800 100 mg/L 500 12129/2010 6:00:00 AM Strontium 4590 0.50 mg/L 50 1212212010 12:56:00 AM 

Zinc < 0.01 0.01 mg/L 1211612010 8:17:00 PM 

Hardness (SM 2340B) 60200 100 mg/LCaC03 100 1212212010 12:51:00AM 

INORGANIC METALS EPA 200.8 Analyst: JEK 

Thorium < 50.0 50.0 IJg/L 50 12/20/2010 10:33:00 AM 

Uranium < 50.0 50.0 IJQ/L 50 12/16/20101:19:00 PM 

VOLATILE ORGANIC COMPOUNDS EPA 8260 Analyst: JAW 

Benzene < 1.0 1.0 IJQ/L 12/15/2010 10:56:00 AM 

Toluene < 1.0 1.0 IJQ/L 12/15/2010 10:56:00AM 

Surr: 1 ,2-Dichloroethane-d4 104 70-130 %REC 12115/2010 10:56:00AM 

Surr: 4-Bromofluorobenzene 109 70-130 %REC 12115/2010 10:56:00 AM 

Surr: Toluene-dB 103 70-130 %REC 12/15/2010 10:56:00 AM 

INDICATOR ORGANIC PARAMETERS EPA 1664 Analyst: JDH 

Oil & Grease <5 5 mg/L 1.02 12/13/2010 4:13:00 PM 

VOLATILE ORGANIC COMPOUNDS EPA 8015 Analyst: SUB 

Ethylene Glycol < 11 11 mg/L 1212212010 

I. D. 56-00306 PA DEP 

n--·- A _,c r 
Matrix: AQUEOUS 

Analyses 

RADIOLOGICAL TESTING 

Gross Alpha 

Gross Beta 

RADIOLOGICAL PARAMETERS 

Radium 226 

RADIOLOGICAL PARAMETERS 

Radium228 

Result 

4667 +- 1518 

4648 +- 832 

385 +-75.5 

904 +-194 

QL Q 

EPA900.0 

3.00 

4.00 

EPA 903.1 

1.00 

EPA904.0 

1.00 

Received Date: I2/I0/2010 8:26:06 AM 

Units DF Date Analyzed 

Analyst: SUB 

pCi/L 12/18/2010 

pCi/L 12118/2010 

Analyst: SUB 

pCi!L 12128/2010 

Analyst: SUB 

pCi/L 117/2011 

------------·--------·· -----------------------·--------------------------------------·-· -······· - -

I. D. 56-00306 PA DEP 

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