November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC General Company and Facility Information

Instructions

Please complete this worksheet for your parent company and PVC production facility.

Parent Company General Information

Parent Company Name:

Address:

City:

Country: US

Size of Company (approximate number of employees including all subsidiaries, branches, and related establishments 

PVC Production Facility General Information

Facility Name:

Facility Address:

Facility City:

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: ~80

Houston

2801 Post Oak Boulevard

Westlake Chemical Corporation

270-395-3302

jhobby@westlake.com

Westlake PVC Corporation

230 Johnson Riley Road

Calvert City

Jimmy Hobby
ers (PVC) Production Process Wastewater

State: TX Zip Code: 77056

hes, and related establishments owned): 2000

State: KY Zip Code: 42029
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Treatment System Information Update

Instructions

2. Also complete the additional supplemental questions to Form C-1-c.

FORM C-1-c

PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER

Process Unit ID: P-1

Process Equipment ID: U-32

Wastewater Feed Rate (lb/hr): 60000

Feed Temperature (°F): 170

Feed Inlet Pressure (psia): 75

Liquid Loading Rate (liters/m2): 82

Steam Feed Rate (lb/hr): 3500

Steam to Feed Ratio (kg steam/liter of wastewater): 0.0583

Operating Temperature (°F): 220

Operating Pressure (psig): 2

Total Number of Stages:

Overall Calculated Tray Efficiency:

Stripping Factor: 0.999991

Flow configuration (countercurrent, cocurrent): countercurrent

Number of Actual Trays: 20

Column Height (meters): 10.6

Year Equipment Installed: 1979

Equipment Currently Regulated Under (cite regulations): 40 CFR 61 Sub F

1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included w

below.
mers (PVC) Production Process Wastewater

Form C-1-c Supplemental Questions

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, plea

ection 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous respons
 batch strippers: 27250 liters/hour

 liters

m design rate or capacity, please provide those values:

34000 liters/hour (max design)

 liters (max design)

eview those previous responses and update if necessary
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Stream Information

Instructions

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production fa

2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wa

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for e

Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System

1 3

P-1 W-9

P-1 W-7

Dryer Centrifuges

Thermal Oxidizer Scrubber 

2

PVC Process 

Unit ID Name of PVC Process Wastewater Stream

PVC Process 

Wastewater 

Stream ID
Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System

1 2 3 4 5 6

Min

P-1 U-32 Steam Stripping Continuous W-6 60000

Table 3. PVC Process Wastewater Destination Codes Table

Wastewater treatment system

Discharge without treatment by pipeline, sewer, or other conveyance to surface water

Discharge to POTW, no treatment

Discharge to PrOTW, no treatment

Zero discharge or alternative disposal method

Recycle to process

Other

Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment S

2 3

Min Max

PVC Process Wastewate

1

Process Wastewater Stream Flow Rate 

Source of Process Wastewater Stream (gallons per day)

Destination Description

PVC Process 

Wastewater 

Treatment 

System ID

PVC Process 

Unit ID

PVC Process 

Wastewater 

Stream ID

Is this 

process 

wastewater 

treatment 

system batch 

or continuous 

operation?

Type of Process 

Wastewater 

Treatment System

VC) Production Process Wastewater

hin the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process waste

VC production process wastewater treatment system.

ter treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC prod

tment System

4 5 6 7 8

Min Max Average

0 240000 65000 Estimated 365

7000 28800 14400 Estimated 365

Flow Rate 

Determination 

Method

PVC Process Wastewater Stream Flow Rate 

(gallons per day) Operating Days Per 

Year
7 8 9 10 11

Max Average

180000 100000 Measured 365 WWT

Code

WWT Provide name of the wastewater treatment system

SW Provide name of outfall

POTWRAW Provide name of POTW

PrOTWRAW Provide name of PrOTW

ZEROALT Describe method

RECYC Describe where in the process the stream is recycled

OTHER Describe

Wastewater Treatment System

4 5 6 7

Average

Flow Rate 

Determination 

Method

PVC Process 

Wastewater 

Treatment 

System ID

VC Process Wastewater Stream Flow Rate 

(gallons per day)

Flow Rate 

Determination 

Method

Operating Days 

Per Year

water Stream Flow Rate 

ons per day)

Process Wastewater Destination D

PVC Process 

Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Operating Days 

Per Year

eated by a PVC production process wastewater treatment system.

hat does not originate from the PVC production facility.

9 10

U-52, U-60, U-77, U-84 Process Dryers

C-4 Thermal Oxidizer Scrubber

Originating PVC Process 

Equipment ID

Originating PVC Process 

Equipment Description
12 13

Air Products WWT System Yes

e of the wastewater treatment system

ere in the process the stream is recycled

Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2

Associated Destination 

Information

(Refer to Table 3 below)

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the outlet of 

the PVC process wastewater 

treatment system and its 

destination?

11 12

WWT Air Products WWT System

WWT Air Products WWT System

PVC Process Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Associated Destination Information
able 1 and Column 11 of Table 2

14

If your response in Column 3 is "Other" then please provide a description of the process wastewaetr 

treatment system

13

Yes

Yes

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the 

originating PVC process equipment 

and its destination?
de a description of the process wastewaetr 
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system 

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID mu

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determinat

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the 

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method dete

5. Enter any notes or additional information relevant to the sampling or analysis.

Company

Facility

PVC Process Wastewater Treatment System ID

CAS No. HAP

107211 Ethylene glycol

67561 Methanol

75070 Acetaldehyde

50000 Formaldehyde

51285 2,4-dinitrophenol

98862 Acetophenone

117817 Bis(2-ethylhexyl) phthalate (DEHP)

123319 Hydroquinone

108952 Phenol

79345 1,1,2,2-tetrachloroethane

106990 1,3-butadiene

540841 2,2,4-trimethylpentane

71432 Benzene

108907 Chlorobenzene

Resin Type (suspension, dispersion, bulk, e

Stream Flow Rate (gallons per minu
67663 Chloroform

126998 Chloroprene

98828 Cumene

75003 Ethyl chloride (Chloroethane)

100414 Ethylbenzene

107062 Ethylene dichloride (1,2-Dichloroethane)

75343 Ethylidene dichloride (1,1-Dichloroethane)

74873 Methyl chloride (Chloromethane)

75092 Methylene chloride

110543 n-Hexane

108883 Toluene

71556 Methyl chloroform (1,1,1-Trichloroethane)

79005 1,1,2-Trichloroethane

108054 Vinyl acetate

593602 Vinyl bromide (1) 

75014 Vinyl chloride

75354 Vinylidene chloride (1,1-Dichloroethylene)

1330207 Xylenes (isomers and mixtures)

Note: For further informatio on the lab data qualifiers, please see the ETC and Trillium reports 

Note: The M107 VCM data result was an extrapolated value that was lower than the lowest calibra

standard value as per the Method.

Note: The reported value for "Xylenes (isomers and mixtures)" CAS 1330207 is the higher value of th

Xylene and o-Xylene results. The 1/27/13 sample value is the addition of the mp-Xylene and o-Xylene 

result numbers added together.

Note: Steam Stripper temperature data for 1/31/2013 is missing. The temperature information was tak

a local temperature gauge as there is no automated (DCS) point for this parameter

Note (1) Based on historical data for gases analyzed by SW-846 Method 8260B (SW-5030B Purge an

the method quantitation limit (MQL) for Vinyl Bromide is estimated to be 1 ug/L. Due to the fact 

calibration standards and verification standards were not readily available, estimated concentration

be reported for Vinyl Bromide. Estimated concentrations are calculated based on the closest Inte

Standard.

de and Copolymers (PVC) Production Process Wastewater

Analysis Data

steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (m

he stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

n type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID

ed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

e "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

pling or analysis.

Westlake Chemical Corporation

Westlake PVC Corporation

P-1

13-008-0229

Analysis Method Concentrati

on (ppmw)

Non-Detect?

SW-846-8015C 0.6 Y

SW-846-8015C 13.2 N

SW-846-8315A 0.275 N

SW-846-8315A 0.314 N

SW-846-8270D 0.00631 Y

SW-846-8270D 0.00729 Y

SW-846-8270D 0.0103 Y

SW-846-8270D 0.3 Y

SW-846-8270D 0.00349 Y

SW-846-8260B 0.00046 N

SW-846-8260B 0.00024 Y

SW-846-8260B 0.00045 Y

SW-846-8260B 0.00032 N

SW-846-8260B 0.00004 Y

Sample Date --> 01/07/13

esin Type (suspension, dispersion, bulk, etc.) --> Suspension

Stream Flow Rate (gallons per minute) --> 71

Flow Rate Determination Method --> Measured

Stream Temperature (degrees F) --> 140

Analysis Date --> 1/8/13-1/14/13

Lab Report ID -->

Lab Sample ID --> 93428
SW-846-8260B 0.0001 Y

SW-846-8260B 0.00033 Y

SW-846-8260B 0.00005 Y

SW-846-8260B 0.00012 Y

SW-846-8260B 0.00005 Y

SW-846-8260B 0.00028 Y

SW-846-8260B 0.00011 Y

SW-846-8260B 0.00023 Y

SW-846-8260B 0.00041 Y

SW-846-8260B 0.00167 Y

SW-846-8260B 0.00004 Y

SW-846-8260B 0.00013 Y

SW-846-8260B 0.00004 Y

SW-846-8260B 0.00006 Y

SW-846-8260B 0.001 TIC

EPA Method 107 2.8 Y

SW-846-8260B 0.00007 Y

SW-846-8260B 0.00012 Y

fiers, please see the ETC and Trillium reports 

trapolated value that was lower than the lowest calibration 

value as per the Method.

s and mixtures)" CAS 1330207 is the higher value of the mp

e value is the addition of the mp-Xylene and o-Xylene sample 

mbers added together.

2013 is missing. The temperature information was taken from 

ted (DCS) point for this parameter

yzed by SW-846 Method 8260B (SW-5030B Purge and Trap), 

yl Bromide is estimated to be 1 ug/L. Due to the fact that 

s were not readily available, estimated concentrations would 

oncentrations are calculated based on the closest Internal 

. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

 2 of the "Stream Info" worksheet.

e type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

centration (ppmw)" column.

13-010-0209

Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

0.6 Y

32.6 N

U 0.336 N UJ

UJ 0.39 N J

0.0631 Y

0.0729 Y

0.103 Y

UJ 0.3 Y UJ

0.0349 Y

0.00009 Y

0.00024 Y

0.00045 Y

0.00023 N J

0.00004 Y

1 2

01/08/13

Suspension

64

Measured Measured

140

1/11/13-1/15/13

93903
0.0001

Y

0.00033Y

0.00005Y

UJ 0.00012Y

0.00005Y

0.00028Y

0.00011Y

UJ 0.00023Y

0.00041Y

0.00167Y

0.00004Y

0.00013Y

0.00004Y

UJ 0.00006Y

0.001 TIC

U 2.8YU

0.00007Y

UJ 0.00012Y

13-010-0210 13-014-0204

Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

0.6 Y 0.6 Y

42.6 N 48.6 N

0.236 N UJ 0.248 N

0.275 N UJ 0.345 N

0.0631 Y 0.0631 Y

0.0729 Y 0.0729 Y

0.103 Y 0.103 Y

0.3 Y UJ 0.3 Y

0.0349 Y 0.0349 Y

0.00009 Y UJ 0.00055 N

0.00024 Y UJ 0.00024 Y

0.00045 Y UJ 0.00045 Y

0.00026 N J 0.00043 N

0.00004 Y UJ 0.00004 Y

3

01/09/13 01/10/13

Suspension Suspension

49 56

Measured Measured

128 113.25

1/11/13-1/17/13 1/14/13-1/17/13

93906 94532
0.0001

Y UJ 0.0001Y

0.00033Y UJ 0.00033Y

0.00005Y UJ 0.00005Y

0.00012Y 0.00012Y

0.00005Y 0.00005Y

0.00028YJ 0.00028Y

0.00011Y UJ 0.00011Y

0.00023Y UJ 0.00023Y

0.00041Y UJ 0.00041Y

0.00167Y UJ 0.00167Y

0.00004Y UJ 0.00004Y

0.00013Y UJ 0.00013Y

0.00004Y UJ 0.00004Y

0.00006Y UJ 0.00006Y

0.001 TIC 0.001 TIC

2.8YU 2.8Y

0.00012N 0.00007Y

0.00012Y UJ 0.00012Y

13-014-0205

Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

0.6 Y

31.3 N

UJ 4.62 N UJ

J 0.244 N UJ

0.0631 Y

0.0729 Y

0.103 Y

UJ 1.08 N JN

0.0349 Y

J 0.00009 Y UJ

0.00024 Y UJ

0.00045 Y UJ

J 0.00036 N J

0.00004 Y UJ

4 5

01/11/13

Suspension

71

Measured Measured

124.5

1/14/13-1/21/13

94533
0.00025

N UJ

0.00033Y UJ

0.00005Y UJ

0.00012Y

0.00005Y

0.00028YJ

0.00011Y UJ

0.00023Y UJ

0.00041Y UJ

0.00167Y UJ

0.00004Y UJ

0.00013Y UJ

0.00004Y UJ

0.00006Y UJ

0.001 TIC

U 2.8YU

0.00007Y

0.00012Y UJ

13-015-0211 13-015-0212

Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

0.6 Y 7.4 N

74.8 N 15.8 N

0.389 N J 1.53 N

0.299 N J 0.181 N

0.0595 Y 0.00631 Y

0.0706 N J 0.00729 Y

0.0973 Y 0.0103 Y

0.03 Y UJ 0.113 N

0.0329 Y 0.00349 Y

0.00009 Y 0.00009 Y

0.00024 Y 0.00024 Y

0.00045 Y 0.00045 Y

0.00024 N J 0.0003 N

0.00004 Y 0.00004 Y

6

01/12/13 01/13/13

Suspension Suspension

50 79

Measured Measured

144 105

1/16/13-1/22/13 1/16/13-1/22/13

94745 94749
0.0001

Y 0.0001Y

0.00033Y 0.00033Y

0.00005Y 0.00005Y

0.00012Y 0.00012Y

0.00005Y 0.00005Y

0.00028Y 0.00028Y

0.00011Y 0.00011Y

0.00023Y 0.00023Y

0.00041Y 0.00041Y

0.00167Y 0.00167Y

0.00004Y 0.00004Y

0.00013Y 0.00013Y

0.00004Y 0.00004Y

0.00006Y 0.00006Y

0.001 TIC 0.001 TIC

2.8YU 2.8Y

0.00007Y 0.00007Y

0.00012Y 0.00012Y

13-015-0213

Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

0.6 Y

33.9 N

J 0.617 N J

UJ 0.376 N J

0.00631 Y

0.00729 Y

0.0103 Y

JN 0.03 Y UJ

0.00349 Y

0.00009 Y

0.00024 Y

0.00045 Y

J 0.00039 N J

0.00004 Y

7 8

01/14/13

Suspension

68

Measured Measured

113.75

1/16/13-1/22/13

94750
0.0001

Y

0.00033Y

0.00005Y

0.00012Y

0.00005Y

0.00028Y

0.00011Y

0.00023Y

0.00041Y

0.00167Y

0.00004Y

0.00013Y

0.00004Y

0.00006Y

0.001 TIC

U 2.8YU

0.00007Y

0.00012Y

13-017-0208 13-017-0209 

Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

0.6 Y 0.6 Y

36.9 N 29.7 N

0.322 N J 3.34 N

0.407 N J 0.467 N

0.00316 Y 0.00316 Y

0.00365 Y 0.00751 N

0.00516 Y 0.00516 Y

0.015 Y UJ 0.015 Y

0.00175 Y 0.00175 Y

0.00009 Y 0.00009 Y

0.00024 Y 0.00024 Y

0.00045 Y 0.00045 Y

0.00004 Y 0.001 N

0.00004 Y 0.00004 Y

9

Suspension Suspension

01/15/13 01/16/13

75 75

Measured Measured

109.75 125.5

1/18/13-1/22/13 1/18/13-1/23/13

95319 95321
0.0001

Y 0.0001Y

0.00033Y 0.00033Y

0.00005Y 0.00005Y

0.00012Y 0.00012Y

0.00005Y 0.00005Y

0.00028Y 0.00028Y

0.00011Y 0.00011Y

0.00023Y 0.00023Y

0.00041Y 0.00041Y

0.00167Y 0.00167Y

0.00004Y 0.00004Y

0.00013Y 0.00013Y

0.00004Y 0.00004Y

0.00006Y 0.00006Y

0.001 TIC 0.001 TIC

2.8YU 2.8Y

0.00007Y 0.00007Y

0.00012Y 0.00012Y

13-018-0210

Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

0.6 Y

44.5 N

J 0.364 N

J 0.383 N

0.00316 Y

J 0.00365 Y J

0.00516 Y

UJ 0.015 Y UJ

0.00175 Y

0.00009 Y

0.00024 Y

0.00045 Y

U 0.0002 N J

0.00004 Y

10 11

Suspension

01/17/13

65

Measured Measured

128.5

1/21/13-1/23/13

95580
0.0001

Y

0.00033Y

0.00005Y

UJ 0.00012Y

0.00005Y

0.00028Y

0.00011Y

0.00023Y

0.00041Y

0.00167Y

0.00004Y

0.00013Y

0.00004Y

0.00006Y

0.001 TIC

U 2.8YU

0.00007Y

0.00012Y

13-021-0238 13-022-0208

Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

0.6 Y 0.6 Y

39.2 N 30.7 N

0.277 N 0.256 N

0.469 N 0.413 N

0.00631 Y 0.00631 Y

0.00729 Y 0.00729 Y

0.0103 Y 0.0103 Y

0.03 Y UJ 0.03 Y

0.00349 Y 0.00349 Y

0.00009 Y 0.00009 Y

0.00024 Y 0.00024 Y

0.00045 Y 0.00045 Y

0.00016 N J 0.00004 Y

0.00004 Y 0.00004 Y

12

01/18/13 01/19/13

Suspension Suspension

50 52

Measured Measured

140.25 134.75

1/21/13-1/25/13 1/22/13-1/28/13

95938 96111
0.0001

Y 0.0001Y

0.00033Y 0.00033Y

0.00005Y 0.00005Y

0.00012Y 0.00012Y

0.00005Y 0.00005Y

0.00028Y 0.00028Y

0.00011Y 0.00011Y

0.00023Y 0.00023Y

0.00041Y 0.00041Y

0.00167Y 0.00167Y

0.00004Y 0.00004Y

0.00013Y 0.00013Y

0.00004Y 0.00004Y

0.00006Y 0.00006Y

0.001 TIC 0.001 TIC

2.8YU 2.8Y

0.00007Y 0.00007Y

0.00012Y 0.00012Y

13-022-0209

Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

0.6 Y

35.3 N

0.529 N

0.461 N

0.00631 Y

0.00729 Y

0.0103 Y

UJ 0.03 Y UJ

0.00349 Y

0.00009 Y

0.00024 Y

0.00045 Y

0.00046 N J

0.00004 Y

13 14

01/20/13

Suspension

45

Measured Measured

131

1/22/13-1/28/13

96113
0.00019

NJ

0.00033Y

0.00005Y

0.00012Y

0.00005Y

0.00028Y

0.00011Y

0.00023Y

0.00041Y

0.00167Y

0.00004Y

0.00013Y

0.00004Y

0.00006Y

0.001 TIC

U 2.8YU

0.00007Y

0.00012Y

13-022-0210 13-024-0229

Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

0.6 Y 5.5 N

32.2 N 48.7 N

3.97 N 0.255 N

0.991 N 0.308 N

0.00631 Y 0.00631 Y

0.00729 Y 0.00729 Y

0.0103 Y 0.0103 Y

0.03 Y UJ 0.03 Y

0.00349 Y 0.00349 Y

0.00009 Y UJ 0.00009 Y

0.00024 Y UJ 0.00024 Y

0.00045 Y UJ 0.00045 Y

0.00012 N J 0.00024 N

0.00004 Y UJ 0.00004 Y

15

01/21/13 01/22/13

Suspension Suspension

52 51

Measured Measured

125.5 120

1/22/13-1/28/13 1/25/13-1/31/13

96115 96743
0.0001

Y UJ 0.0001Y

0.00033Y UJ 0.00033Y

0.00005Y UJ 0.00005Y

0.00012Y 0.00012Y

0.00005Y 0.00005Y

0.00028Y UJ 0.00028Y

0.00011Y UJ 0.00011Y

0.00023Y UJ 0.00023Y

0.00041Y UJ 0.00041Y

0.00167Y UJ 0.00167Y

0.00004Y UJ 0.00004Y

0.00013Y UJ 0.00013Y

0.00004Y UJ 0.00004Y

0.00006Y UJ 0.00006Y

0.001 TIC 0.001 TIC

2.8YU 2.8Y

0.00007Y 0.00007Y

0.00012Y UJ 0.00012Y

13-024-0208

Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

U 1.9 N U

25.5 N

3.63 N

0.14 N

0.00631 Y UJ

0.00729 Y

0.0103 Y

UJ 0.156 N JN

0.00349 Y UJ

0.00009 Y

0.00024 Y

0.00045 Y

J 0.001 N U

0.00004 Y

16 17

01/23/13

Suspension

70

Measured Measured

138.5

1/25/13-1/31/13

96745
0.0001

Y

0.00033Y

0.00005Y

0.00012Y

UJ 0.00005Y

0.00028Y

0.00011Y

0.00023Y

0.00041Y

0.00167Y

UJ 0.00004Y

0.00013Y

0.00004Y

0.00006Y

0.001 TIC

U 2.8YU

0.00007Y

UJ 0.00012Y

13-028-0202

Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

4.9 N U 4.1 N

26.9 N 34.3 N

1.01 N 0.135 N

0.277 N 0.218 N

0.00631 Y 0.00631 Y

0.00729 Y 0.00729 Y

0.0103 Y 0.0103 Y

0.03 Y UJ 0.0349 Y

0.00349 Y 0.00349 Y

0.00009 Y 0.00009 Y

0.00024 Y 0.00024 Y

0.00045 Y 0.00045 Y

0.001 N U 0.00004 Y

0.00004 Y 0.00004 Y

18

01/24/13 01/25/13

70 69

Suspension Suspension

Measured Measured

138.5 118.25

1/28/13-2/1/13 1/30/13-2/1/13

13-028-0201

97238 97241
0.0001

Y 0.0001Y

0.00033Y 0.00033Y

0.00005Y 0.00005Y

0.00012Y 0.00012Y

0.00005Y 0.00005Y

0.00028Y 0.00028Y

0.00011Y 0.00011Y

0.00023Y 0.00023Y

0.00041Y 0.00041Y

0.00167Y 0.00167Y

0.00004Y 0.00004Y

0.00013Y 0.00013Y

0.00004Y 0.00004Y

0.00006Y 0.00006Y

0.001 TIC 0.001 TIC

2.8YU 2.8Y

0.00007Y 0.00007Y

0.00012Y 0.00012Y

13-029-0214

Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

U 3.8 N U

31.8 N

J 0.278 N

J 0.476 N

0.00631 Y

0.00729 Y

0.0103 Y

UJ 0.03 Y R

0.00349 Y

0.00009 Y

0.00024 Y

0.00045 Y

0.00004 Y

0.00004 Y

19 20

01/26/13

60

Suspension

Measured Measured

117.75

1/29/13-2/4/13

97493
0.001

Y

0.00033Y

0.00005Y

0.00012Y

0.00005Y

0.00028Y

0.00011Y

0.00023Y

0.00041Y

0.00167Y

0.00004Y

0.00013Y

0.00004Y

0.00006Y

0.001 TIC

U 2.8YU

0.00007Y

0.00012Y

13-029-0215 13-030-0268

Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

1.7 N U 3.7 N

30.8 N 33.8 N

0.327 N 0.475 N

0.51 N 0.534 N

0.00631 Y 0.00631 Y

0.00729 Y 0.00729 Y

0.0103 Y 0.0103 Y

0.03 Y R 0.03 Y

0.00349 Y 0.00349 Y

0.00009 Y 0.00009 Y

0.00024 Y R 0.00024 Y

0.00045 Y R 0.00045 Y

0.00004 Y 0.00004 Y

0.00004 Y 0.00004 Y

21

01/27/13 01/28/13

Suspension Suspension

54 71

Measured Measured

125 129.25

1/29/13-2/4/13 2/1/13-2/4/13

97497 97820
0.0007

NJ 0.0001Y

0.00033Y 0.00033Y

0.00005Y 0.00005Y

0.00012Y 0.00012Y

0.00005Y 0.00005Y

0.00028Y 0.00028Y

0.00011YJ 0.00011Y

0.00023Y 0.00023Y

0.00041Y 0.00282N

0.00167Y 0.00167Y

0.00004Y 0.00004Y

0.00013Y 0.00013Y

0.00004Y 0.00004Y

0.00006Y 0.00006Y

0.001 TIC 0.001 TIC

2.8YU 2.8Y

0.00011N 0.00007Y

0.0007NJ 0.00012Y

13-030-0269

Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

U 3.9 N U

29.6 N

0.973 N

0.393 N

0.00631 Y

0.00729 Y

0.0103 Y

R 0.03 Y UJ

0.00349 Y

0.00009 Y

0.00024 Y

0.00045 Y

0.00012 N J

0.00004 Y

22 23

01/29/13

Suspension

48

Measured Measured

126.25

2/1/13-2/6/13

97824
0.0001

Y

0.00033Y

0.00005Y

0.00012Y

0.00005Y

0.00028Y

0.00011Y

0.00023Y

J 0.00234NJ

0.00167Y

0.00004Y

0.00013Y

0.00004Y

0.00006Y

0.001 TIC

U 2.8YU

J 0.00007Y

0.00012Y

2/4/13-2/16/13

13-032-0221 13-032-0222

Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

0.6 Y UJ 1 N

24.2 N J 27.1 N

0.462 N 0.255 N

0.375 N 0.35 N

0.00631 Y 0.00631 Y

0.00729 Y 0.00729 Y

0.0103 Y 0.0103 Y

0.03 Y UJ 0.03 Y

0.00349 Y 0.00349 Y

0.00009 Y 0.00009 Y

0.00024 Y 0.00024 Y

0.00045 Y 0.00045 Y

0.00004 Y 0.00014 N

0.00004 Y 0.00004 Y

24

01/30/13 01/31/13

Suspension Suspension

71 60

Measured Measured

109.5

2/4/13-2/16/13

98149 98151
0.0001

Y 0.0001Y

0.00033Y 0.00033Y

0.00005Y 0.00005Y

0.00012Y UJ 0.00012Y

0.00005Y 0.00005Y

0.00028Y 0.00028Y

0.00011Y UJ 0.00011Y

0.00023Y 0.00023Y

0.00167N 0.00041Y

0.00167Y 0.00167Y

0.00004Y 0.00004Y

0.00013Y 0.00013Y

0.00004Y 0.00004Y

0.00006Y 0.00006Y

0.001 TIC 0.001 TIC

2.8YU 2.8Y

0.00007Y 0.00007Y

0.00012Y 0.00012Y

13-035-0218

Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

UJ 0.6 Y UJ

J 33 N J

0.375 N

0.552 N

0.00631 Y

0.0173 N J

0.0103 Y

UJ 0.03 Y UJ

0.00349 Y

0.00009 Y

0.00069 N J

0.00045 Y

J 0.00019 N J

0.00004 Y

25 26

02/01/13

Suspension

60

Measured Measured

102.75

2/4/13-2/16/13

98375
0.0001

Y

0.00033Y

0.00005Y

0.00012Y

0.00005Y

0.00028Y

0.00011Y

0.00023Y

0.00041Y

0.00167Y

0.00004Y

0.00013Y

0.00004Y

0.00006Y

0.001 TIC

U 2.8YU

0.00007Y

0.00012Y

13-036-0225 13-036-0226

Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

0.6 Y 0.6 Y

21.8 N J 44 N

0.307 N 0.296 N

0.339 N 0.414 N

0.00631 Y 0.00631 Y

0.00729 Y 0.00729 Y

0.0103 Y 0.0103 Y

0.3 Y UJ 0.03 Y

0.00349 Y 0.00349 Y

0.00009 Y 0.00009 Y

0.00024 Y 0.012 Y

0.00045 Y 0.0225 Y

0.00004 Y 0.00004 Y

0.00004 Y 0.00004 Y

27

02/02/13 02/03/13

Suspension Suspension

65 44

Measured Measured

120 128.25

2/6/13-2/27/13 2/6/13-2/27/13

98741 98743
0.00022

NJ 0.0001Y

0.00033Y 0.00033Y

0.00005Y 0.00005Y

0.00012Y 0.00012Y

0.00005Y 0.00005Y

0.00028Y 0.00028Y

0.00011Y 0.00011Y

0.00023Y 0.00023Y

0.00041Y 0.00041Y

0.00167Y 0.00167Y

0.00004Y 0.00004Y

0.00013Y 0.00013Y

0.00004Y 0.00004Y

0.00006Y 0.00006Y

0.001 TIC 0.001 TIC

2.8YU 2.8Y

0.00007Y 0.00007Y

0.00012Y 0.00012Y

Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

2 N

J 21.4 N J

0.36 N

0.451 N

0.00631 Y

0.00729 Y

0.0103 Y

UJ 0.03 Y UJ

0.00349 Y

0.00009 Y

0.00024 Y

0.00045 Y

0.00004 Y

0.00004 Y

28 29

02/04/13

Suspension

55

Measured Measured

136

2/6/13-2/27/13

13-036-0227 

98745
0.0001

Y

0.00033Y

0.00005Y

0.00012Y

0.00005Y

0.00028Y

0.00011Y

0.00023Y

0.00041Y

0.00167Y

0.00004Y

0.00013Y

0.00004Y

0.00006Y

0.001 TIC

U 2.8YU

0.00007Y

0.00012Y

13-038-0244

Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

0.6 Y

34.3 N J

7.37 N

0.474 N

0.0631 Y

0.0729 Y

0.103 Y

3 Y UJ

0.0349 Y

0.00009 Y

0.00024 Y

0.00045 Y

0.00019 N J

0.00004 Y

30

02/05/13

Suspension

70

Measured

140.25

2/8/13-2/27/13

99370
0.0001

Y

0.00033Y

0.00005Y

0.00012Y

0.00005Y

0.00028Y

0.00011Y

0.00023Y

0.00041Y

0.00167Y

0.00004Y

0.00013Y

0.00004Y

0.00006Y

0.001 TIC

2.8YU

0.00007Y

0.00012Y

Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

31 32


Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

33


Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

34 35


Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

36


Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

37 38


Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

39


Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

40 41


Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

42


Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

43 44


Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

45


Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

46 47


Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

48


Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

49 50


Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

51


Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

52 53


Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

54


Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

55 56


Concentrati

on (ppmw)

Non-Detect? Note(s) Concentrati

on (ppmw)

Non-Detect?

57


Note(s) Concentrati

on (ppmw)

Non-Detect? Note(s)

58 59


Concentrati

on (ppmw)

Non-Detect? Note(s)

60